Method of color image formation

Abstract: A method for forming a color image is dis­ closed, which comprises imagewise exposing a multi­ layer silver halide color photographic material com­ prising a reflective support having provided thereon at least three silver halide emulsion layers different in color sensitivity, each of which separately contains at least one coupler selected from a specific combi­ nation of cyan, magenta, and yellow couplers, and processing the exposed material with a color develop­ ing solution containing substantially no benzyl alcohol for a period of not more than 2 minutes and a half. A color image excellent in color reproducibility and preservability can be obtained rapidly without using benzyl alcohol.

Description: FIELD OF THE INVENTION This invention relates to a method of color image formation using a silver halide color light-sensitive material. More particularly, it relates to a method of color image formation by which a color image can be formed in a reduced processing time without using benzyl alcohol by using a specific combination of color couplers. BACKGROUND OF THE INVENTION Silver halide color photographic materials generally comprise a support having provided thereon at least three silver halide emulsion layers, each of which is selectively sensitized so as to be sensitive to one of blue light, green light, and red light, respectively. For example, so-called color papers usually comprise a support having coated thereon a blue-sensitive emulsion layer, a green-sensitive emulsion layer, and a red-sensitive emulsion layer in this order, with auxiliary layers, e.g., intermediate layers, protective layers, being further provided, for example, between light-sensitive layers for prevention of color mixing, ultraviolet absorption. In these color photographic materials, a color image is formed by exposing the material containing yellow, magenta, and cyan couplers in the respective light-sensitive layer and subjecting the exposed material to color development processing with an aromatic primary amine developing agent. By the color development processing, a coupling reaction takes place between an oxidation product of the developing agent and each of the couplers to develop the respective color. It is desired that the couplers to be used have a coupling rate as high as possible and exhibit satisfactory color developability so as to provide high color densities within a limited development time. It is also demanded that the developed colors be distinct cyan, magenta, and yellow colors with reduced side absorptions so as to provide a color photographic image exhibiting satisfactory color reproducibility. Further, the color photographic image formed is required to have satisfactory preservability under various conditions. In order to meet this requirement, it is important that the developed colors of different hues are retarded from discoloration or color change and that the rates of discoloration are uniform as possible over the entire image area so that the color balance of the remaining color image may not be destroyed. In an attempt to solve these problems, so-called oil-soluble couplers have been proposed, which are incorporated into emulsion layers by dissolving in high-boiling or low-boiling organic solvents and emulsifying the solution. Use of the oil-soluble couplers is associated with a disadvantage that a color developing agent, because of its low lipophilic properties, hardly penetrates into oil droplets having dispersed therein the coupler, resulting in reduction of color density. Hence, various development accelerators which accelerate penetration of a developing agent into the oil droplets have hitherto been developed. Of these, benzyl alcohol produces a great effect to accelerate color development when added to a color developing solution and is currently employed widely for processing of color photographic light-sensitive materials, in particular color papers. Use of benzyl alcohol in a color developing solution needs solvents therefor, such as diethylene glycol, triethylene glycol, alkanolamines, due to its poor water solubility. However, since these solvents as well as benzyl alcohol per se have a high BOD or COD indicative of a pollution load, it is preferred to reduce the pollution load by eliminating benzyl alcohol. Besides, it takes time to dissolve benzyl alcohol even with the aid of the solvent. Therefore, in view of reduction of time and labor involved for the preparation of a color developing solution, exclusion of benzyl alcohol is desirable. Further, if benzyl alcohol is carried with light-sensitive material into a bleaching bath or a bleach-fixing bath subsequent to the developing bath, the carried-over benzyl alcohol not only causes formation of a leuco dye from a cyan coupler, which leads to reduction in color density, but also retards removal of developer components by washing, sometimes giving adverse influences on image preservability of the processed light-sensitive materials. From all these considerations, it is preferable to use no benzyl alcohol. On the other hand, while color development has conventionally been completed within 3 to 4 minutes, it has been demanded to shorten the processing time to cope with the recent users' need or rationalization in photofinishing laboratories. However, it is apparent that removal of benzyl alcohol as a development accelerator, combined with reduction of develop ment time would bring about serious reduction of color density. In order to solve this problem, efforts have been made by using a combination of various known color development accelerators, such as those disclosed in U.S. Patents 2,950,970, 2,515,147, 2,496,903, 2,304,925, 4,038,075, and 4,119,462, British Patents 1,430,998 and 1,455,413, Japanese Patent Application (OPI) Nos. 15831/78, 62450/80, 62451/80, 62452/80, 62453/80, 50536/83, and 162256/85 (the term "OPI" as used herein means "unexamined published application"), and Japanese Patent Publication Nos. 12422/76 and 49728/80. None of these efforts, however, succeeded to attain sufficient color densities. Methods of incorporating a color developing agent into color photographic light-sensitive materials are known, as described, e.g., in U.S. Patents 3,719,492, 3,342,559, and 3,342,597, and Japanese Patent Application (OPI) Nos. 6235/81, 16133/81, 97531/82, and 83565/82. However, these methods are not suitable as causing retardation of color development or fog formation. Methods of using a silver chloride emulsion, as disclosed in Japanese Patent Application (OPI) Nos. 95345/83, 232342/84, and 19140/85, are also unsuitable because gradation control is difficult. Various methods for not adding at all benzyl alcohol to a color developing solution or greatly reducing the amount of benzyl alcohol to be added to a color developing solution have been proposed. For example, Japanese Patent Application (OPI) Nos. 200037/82, 50536/83, 487555/84, 174836/84, 177553/84, 162256/85, 158444/85, 158446/85, 26338/85, 26339/85, 172042/85, and 31334/83 and Japanese Patent Publication No. 29461/74 disclose that a multilayer color light-sensitive material comprising a reflective support having provided thereon blue-sensitive, green-sensitive and red-sensitive silver halide emulsion layers having a yellow coupler, a magenta coupler, and a cyan coupler, respectively is processed with a color developing solution containing no benzyl alcohol or a small amount of benzyl alcohol. However, these prior art references merely describe that when processed with a color developing solution, the light-sensitive material must be processed for a developing time longer than two minutes and a half or that when processed within two minutes and a half, the light-sensitive material must be processed with a color developing solution containing a certain amount of benzyl alcohol. As set forth above, there has not been established a method of obtaining a satisfactory color image in a short time of not more than two minutes and a half by using a color developing solution at a pH of 12 or less, which contains substantially no benzyl alcohol. SUMMARY OF THE INVENTION One object of this invention is to provide a method of forming a color image, in which a color light-sensitive material containing oil-soluble couplers is processed with a color developing solution containing substantially no benzyl alcohol in a short processing time. Another object of this invention is to provide a method of forming a color image having satisfactory color reproducibility and image preservability. A further object of this invention is to provide a color image formation method which has a markedly reduced pollution load. It has now been found that the objects can be accomplished by a method of forming a color image, which comprises imagewise exposing a multilayer silver halide color photographic material Comprising a reflective support having provided thereon at least three silver halide emulsion layers different in colour sensitivity, each of which separately contains at least one of couplers represented by formula (I) wherein R₁ represents an aliphatic group, an aromatic group, a heterocyclic group, an aromatic amino group, or a heterocyclic amino group; R₂ represents an aliphatic group; R₃ represents a hydrogen atom, a halogen atom, an aliphatic group, an aliphatic oxy group, or an acylamino group; or R₂ and R₃ are taken together to form a 5- to 7-membered ring; Y₁ represents a halogen atom, or a group capable of being split off upon coupling with an oxidation product of a developing agent (such a group is hereinafter referred to as "split-off group") and R₁, R₂, or Y₁ may form a polymer including a dimer, at least one of the couplers represented by formula (IV-2) and (IV-3) wherein R¹¹ and R¹² each represents a hydrogen atom; a halogen atom a cyano group; R₁′, R₁′0-, R₁′SO-; R₁′-SO₂-, R₁′SO₂NH-, R₁′NH-, R₁′-S-, wherein R₁′ represents an aliphatic, aromatic, or heterocyclic group; a silyl group; a silyloxy group; a silylamino group; an imino group; a carbamoyl group; a sulfamoyl group; or a sulfamoylamino group; X₁ represents a halogen atom or a group capable of being split off upon coupling with an oxidation product of a developing agent; and R¹¹, R¹² or X₁ may be a divalent group, at which a bis-compound is formed, or a linking group via which a polymer chain and a coupler nucleus are linked; and at least one of the couplers represented by formula (V) wherein Y₅ represents a group capable of being split off upon coupling with an oxidation product of a developing agent; and Q represents a substituted or unsubstituted N-phenylcarbamoyl group; or Y₅ or Q may form a polymer including a dimer, and processing the exposed material with a colour developing solution containing an aromatic primary amine as a colour developing agent for a period of not more than 2 min and a half, wherein said silver halide emulsions each contain silver chlorobromide and the colour developing solution is free from benzyl alcohol. The couplers are preferably dispersed together with at least one of high-boiling organic solvents represented by formulae (A) to (E) shown below and having a dielectric constant of 4.00 (25°C, 10 kHz) or more. Formula (A) is represented by wherein W₁, W₂, and W₃ each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group. Formula (B) is represented by W₁ - COO - W₂ (B) wherein W₁ and W₂ are as defined above. Formula (C) is represented by wherein W₁, W₂, and W₃ are as defined above. Formula (D) is represented by wherein W₁ and W₂ are as defined above; W₄ represents W₁, OW₁, or S-W₁; and n represents an integer of from 1 to 5; when n = 2 or more, W₄'s may be the same or different. Formula (E) is represented by W₁ - O - W₂ (E) wherein W₁ and W₂ are as defined above, or W₁ and W₂ are taken together to form a condensed ring. It is preferable that at least one of the couplers represented by formulae (I) to (V) contains at least one of a carboxyl group either in the form of a free acid or in the form of a salt, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted sulfamoyl group, and a substituted or unsubstituted hydroxyphenyl group in its non-diffusible group or split-off group. The carboxyl group or hydroxyphenyl group is contained as a monovalent group, and the sulfonamido group or sulfamoyl group is contained as a monovalent or divalent group. The substituents for the hydroxyphenyl, sulfonamido, and sulfamoyl groups include those for R₁ hereinafter described. DETAILED DESCRIPTION OF THE INVENTION The term "aliphatic group" as used herein means a straight chain or branched chain or cyclic, and saturated or unsaturated aliphatic hydrocarbon group and embraces e.g. an alkyl group, an alkenyl group, an alkynyl group. Typical examples of the aliphatic group are methyl, ethyl, butyl, dodecyl, octadecyl, eicosenyl, isopropyl, t-butyl, t-octyl, t-dodecyl, cyclohexyl, cyclopentyl, allyl, vinyl, 2-hexadecenyl, and propargyl groups. In formulae (I) to (V), the coupling split-off group as represented by Y₁, Y₂, Y₃, Y₄, or Y₅ includes e.g. an aliphatic, aromatic, heterocyclic, aliphatic sulfonyl, aromatic sulfonyl, heterocyclic sulfonyl, aliphatic carbonyl, aromatic carbonyl, or heterocyclic carbonyl group that is bonded to the coupling active carbon atom via an oxygen, nitrogen, sulfur, or carbon atom; a nitrogen-containing heterocyclic group bonded to the coupling carbon atom via a nitrogen atom; a halogen atom; an aromatic azo group. The aliphatic, aromatic, or heterocyclic groups contained in these split-off groups are unsubstituted or substituted with one or more of groups (which may be the same or different) acceptable for R₁ as hereinafter described, which may be further substituted with the groups acceptable for R₁. Specific examples of the coupling split-off groups include a halogen atom (e.g., a fluorine atom, a chlorine atom, a bromine atom), a substituted or unsubstitued alkoxy group (e.g., an ethoxy group, a dodecyloxy group, a methoxyethylcarbamoylmethoxy group, a 3-(methanesulfonamido)propyloxy group, a carboxypropyloxy group, a methylsulfonylethoxy group), a substituted or unsubstituted aryloxy group (e.g., a 4-chlorophenoxy group, a 4-methoxyphenoxy group, a 3-sulfonamidophenoxy group, a 4-(N,N′-diethylsulfamoyl)phenoxy group, a 4-carboxyphenoxy group), an acyloxy group (e.g., an acetoxy group, a tetradecanoyloxy group, a benzoyloxy group), an aliphatic or aromatic sulfonyloxy group (e.g., a methanesulfonyloxy group, a toluenesulfonyloxy group), an acylamino group (e.g., a dichloroacetylamino group, a heptafluorobutyrylamino group), an aliphatic or aromatic sulfonamido group (e.g., a methanesulfonamino group, a p-toluenesulfonamino group), a substituted or unsubstituted alkoxycarbonyloxy group (e.g., an ethoxycarbonyloxy group, a benzyloxycarbonyloxy group), a substituted or unsubstituted aryloxycarbonyloxy group (e.g., a phenoxycarbonyloxy group), an aliphatic, aromatic, or heterocyclic thio group (e.g., an ethylthio group, a phenylthio group, a tetrazolylthio group), a substituted or unsubstituted carbamoylamino group (e.g., an N-methylcarbamoylamino group, an N-phenylcarbamoylamino group), a substituted or unsubstituted 5- or 6-membered nitrogen-containing heterocyclic group (e.g., an imidazolyl group, a pyrazolyl group, a triazolyl group, a tetrazolyl group, a 1,2-dihydro-2-oxo-1-pyridyl group), a substituted or unsubstituted imido group (e.g., a succinimido group, a hydantoinyl group), an aromatic azo group (e.g., a phenylazo group), and the like. Couplers containing a split-off group bonded via a carbon atom include bis-form couplers obtained by condensing 4-equivalent couplers using aldehydes or ketones. The split-off groups of the present invention may contain photographically useful moieties, such as e.g. a development inhibitor moiety, a development accelerator moiety. Preferred combinations of split-off groups in each of the formulae (I) to (V) will be described later. In formula (I), R₁ preferably represents an aliphatic group having from 1 to 36 carbon atoms, an aromatic group having from 6 to 36 carbon atoms (e.g., a phenyl group, a naphthyl group), a heterocyclic group (e.g., a pyridyl group, a 2-furyl group), or an aromatic or heterocyclic amino group (e.g., an anilino group, a naphthylamino group, a 2-benzothiazolylamino group, a 2-pyridylamino group). Substituents for these groups include an alkyl group, an aryl group, a heterocyclic group, an alkoxy group (e.g., a methoxy group, a 2-methoxyethoxy group), an aryloxy group (e.g., a 2,4-di-t-amylphenoxy group, a 2-chlorophenoxy group, a 4-cyanophenoxy group), an alkenyloxy group (e.g., a 2-propenyloxy group), an acyl group (e.g., an acetyl group, a benzoyl group), an ester group (e.g., a butoxycarbonyl group, a phenoxycarbonyl group, an acetoxy group, a benzoyloxy group, a butoxysulfonyl group, a toluenesulfonyloxy group), an amido group (e.g., an acetylamino group, an ethylcarbamoyl group, a dimethylcarbamoyl group, a methanesulfonamido group, an N,N-dibutylsulfamoyl group, a 3-(2,4-di-t-amylphenoxy)propylsulfamoyl group, a benzenesulfonamido group, a 2-butoxy-5-t-octylbenzenesulfonamido group, a dodecanesulfonamido group, a butylsulfamoyl group), a sulfamido group (e.g., a dipropylsulfamoylamino group), an imido group (e.g., a succinimido group, a hydantoinyl group), a ureido group (e.g., a phenylureido group, a dimethylureido group), an aliphatic or aromatic sulfonyl group (e.g., a methanesulfonyl group, a phenylsulfonyl group, a 2-butoxy-5-t-octylphenylsulfonyl group), an aliphatic or aromatic thio group (e.g., an ethylthio group, a phenylthio group), a hydroxyl group, a cyano group, a carboxyl group, a nitro group, a halogen atom, and so on. In formula (I), R₂ preferably represents an aliphatic group having from 1 to 20 carbon atoms, which may be substituted with the groups acceptable for R₁. In formula (I), R₃ preferably represents a hydrogen atom, a halogen atom (e.g., a fluorine atom, a chlorine atom, a bromine atom), or an aliphatic group having from 1 to 20 carbon atoms, an aliphatic oxy group having from 1 to 20 carbon atoms, or an acylamino group having from 1 to 20 carbon atoms (e.g., an acetamido group, a benzamido group, a tetradecaneamino group), each of which groups may be substituted by those groups enumerated for R₁. R₂ and R₃ in formula (I) may be taken together to form a 5- to 7-membered ring. The compounds of formula (I) embrace polymeric couplers including dimers formed at either one of R₁, R₂, R₃, and Y₁ in formula (I). In the dimers, these groups are mere bonds or divalent linking groups, e.g., an alkylene group, an arylene group, an ether group, an ester group, an amido group, and a combination thereof. In the oligomeric or polymeric couplers, these groups preferably constitute a polymer main chain or are bonded to a polymer main chain via a divalent linking group as enumerated above for dimers. The polymeric coupler may be a homopolymer solely comprising a monomer having the moiety represented by formula (I) or a copolymer comprising such a monomer and a non-color forming ethylenically unsaturated monomer, e.g., acrylic acid, methacrylic acid, methyl acrylate, n-butylacrylamide, a β-hydroxymethacrylate, vinyl acetate, acrylonitrile, styrene, crotonic acid, maleic anhydride, N-vinylpyrrolidone. R₁ represents more preferably a substituted or unsubstituted alkyl or aryl group. Preferred substituents for the alkyl group include a substituted or unsubstituted phenoxy group and a halogen atom, with substituents for the phenoxy group preferably including an alkyl group, an alkoxy group, a halogen atom, a sulfonamido group, a sulfamoyl group, and a carboxyl group. Particularly preferred aryl groups are phenyl groups substituted with at least one of a halogen atom, an alkyl group, a sulfonamido group, a sulfamoyl group, a carboxyl group, and an acylamino group. R₂ more preferably represents a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms. Substituents for the alkyl group preferably include an alkyloxy group, an aryloxy group, an acylamino group, an alkylthio group, an arylthio group, an imido group, a ureido group, an alkylsulfonyl group, and an arylsulfonyl group. R₃ more preferably represents a hydrogen atom, a halogen atom (with a fluorine atom or a chlorine atom being particularly preferred), and an acylamino group, with a halogen atom being most preferred. R₂ most preferably represents an alkyl group having from 2 to 4 carbon atoms (Formula I′ in claim 1). Y₁ preferably represents a hydrogen atom, and more preferably a chlorine atom. The above-described cyan couplers of formula (I) may be used either individually or in combinations of two or more thereof. As a magenta couplers, compounds represented by formulae (IV-2) and (IV-3) are preferred. The compounds represented by formulae (IV-2) and (IV-3) are 5-membered ring condensed nitrogen-containing heterocyclic couplers. The color-forming nucleus exhibits aromaticity isoelectronic to naphthalene, and has a chemical structure usually called azapentalene. Compounds of formulae (IV-2) and (IV-3) are 1H-pyrazolo[5,1-c][1,2,4]triazoles of the following formula (IV-2) and 1H-pyrazolo[1,5-b][1,2,4]triazoles of the following formula (IV-3) with 1H-pyrazolo[1,5-b][1,2,4]trazoles of the following formula (IV-3) being most preferred. In formulae (IV-2) to (IV-3), R¹¹, R¹², each represents a hydrogen atom; a halogen atom; a cyano group; R₁′, R₁′O-, R₁′SO-, R₁′-SO₂-, R₁′SO₂NH-, R₁′NH-, R₁′-S-, wherein R₁′ represents an aliphatic, aromatic, or heterocyclic group developing agent; a silyl group; a silyloxy group; a silylamino gorup; an imino group; a carbamoyl group; a sulfamoyl group; or a sulfamoylamino group. The nitrogen atom contained in these groups may have substituents as enumerated for R₁. X represents a halogen atom or a group capable of being split off upon coupling with an oxidation product of a developing agent; R¹¹, R¹² or X₁ may be a divalent group, at which a bis-compound is formed, or a linking group via which a polymer chain and a coupler nucleus are linked. R¹¹, R¹², each preferably represents a hydrogen atom, a halogen atom, R₁′, R₁′O-, R₁′CONH-, R₁′SO₂NH-, R₁′NH-, R₁′S-, R₁′NHCONH-, or R₁′OCONH-. X₁ preferably represents a halogen atom, an acylamino group, an imido group, an aliphatic or aromatic sulfonamido group, a 5- or 6-membered nitrogen-containing heterocyclic group bonded to the coupling site via a nitrogen atom, an aryloxy group, an alkoxy group, an arylthio group, or an alkylthio group. In formula (V), the N-phenylcarbamoyl group as represented by Q may have the phenyl moiety substituted with one or more of substituents (which may be the same or different) arbitrarily selected from the groups acceptable for the aromatic groups represented by R₁. Preferred groups for Q are represented by formula (VA) wherein G₁ represents a halogen atom or an alkoxy group; G₂ represents a hydrogen atom, a halogen atom, or a substituted or unsubstituted alkoxy group; and R¹⁴ represents a substituted or unsubstituted alkyl group. Substituents for G₂ or R¹⁴ in formula (VA) typically include an alkyl gorup, an alkoxy group, an aryl group, an aryloxy group, an amino group, a dialkylamino group, a heterocyclic group (e.g., an N-morpholino group, an N-piperidino group, a 2-furyl group), a halogen atom, a nitro group, a hydroxyl group, a carboxyl group, a sulfo group, a sulfonamido group, a sulfamoyl group, an alkoxycarbonyl group. The split-off group Y₅ of formula (V) preferably includes groups represented by formulae (X) to (XVI). Formula (X) is represented by wherein R₂₀ represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group. Formulae (XI) and (XII) are represented by respectively, wherein R₂₁ and R₂₂ (which may be the same or different) each represents a hydrogen atom, a halogen atom, a carboxylic ester group, an amino group, an alkyl group, an alkylthio group, an alkoxy group, an alkylsulfonyl group, an alkylsulfonamido group, an arylsulfonamido group, a sulfamoyl group, an alkylsulfinyl group, a carboxyl group, a sulfo group, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted heterocyclic ring. Formula (XIII) is represented by wherein W₁ represents a non-metallic atomic group forming a 4- to 6-membered ring together with the moiety Of the groups represented by formula (XIII), preferred are those represented by formulae (XIV) to (XVI). Formula (XIV) is represented by wherein R₂₃ and R₂₄ each represents a hydrogen atom, an alkyl gorup, an aryl group, an alkoxy group, a sulfonamido group, a sulfamoyl group, a carboxyl group, an aryloxy group, or a hydroxyl group; and R₂₅ represents a hydrogen atom, an alkyl group, an aryl gorup, an aralkyl group, or an acyl group. Formula (XV) is represented by wherein R₂₃ and R₂₄ are as defined above; and W₂ represents an oxygen atom or a sulfur atom. Formula (XVI) is represented by wherein R₂₆ and R₂₇ each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or an acyl group. The cyan couplers of formula (I) can be synthesized by known methods, such as the methods described in U.S. Patents 2,423,730 and 3,772,002 for the cyan couplers of formula (I). The magenta couplers of formulae (IV-2), (IV-3), can be synthesized by the methods described in Japanese Patent Application(OPI) No. 162548/84. U.S. Patent 3,725,067, Japanese Patent Application (OPI) No. 171956/84, and Japanese Patent Application (OPI) No. 33552/85, respectively. The yellow couplers of formula (V) can be synthesized by the methods described, e.g., in Japanese Patent Application (OPI) No. 48541/79, Japanese Patent Publication No. 10739/83, U.S. Patent 4,326,024, Research Disclosure , No. 18053. Preferred examples of the above-described cyan couplers of formula (I); magenta couplers of formulae (IV-2) and (IV-3); and yellow couplers of formula (V) are shown below for illustrative purposes only, with compound numbers headed by C for cyan couplers, M for magenta couplers, and Y for yellow couplers: Incorporation of the couplers according to the present invention into emulsion layers is preferably carried out by dissolving the coupler in a high-boiling organic solvent and/or a low-boiling organic solvent, dispersing the coupler solution in an aqueous solution of gelatin or other hydrophilic colloid in a homogenizer at a high speed of stirring, and adding the dispersion to an emulsion layer. In order to ensure improvements in color developability, it is particularly preferable to use at least one of high-boiling organic solvents represented by the above-described formulae (A), (B), (C), (D), and (E) and having a dielectric constant of 4.00 or more at 25°C. It is also preferable to disperse the coupler solution in the presence of an anionic or nonionic surface active agent. Examples of such surface active agents to be used include anionic surface active agents having at least a sulfonic group and a long-chain aliphatic group. More specifically, and are preferably used independently or in combination. In formulae (A) to (E), substituents for the alkyl, cycloalkyl, alkenyl, aryl, and heterocyclic group as represented by W₁, W₂, and W₃ include linking groups composed of one or more groups selected from wherein R⁸ represents a di- to hexavalent group obtained by removing a hydrogen atom from a phenyl group, and -O-. The alkyl group as represented by W₁, W₂, W₃, or W₄ may be either straight chain or branched chain alkyl groups, including e.g. a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, a pentadecyl group, a hexadecyl group, a heptadecyl group, an octadecyl group, a nonadecyl group, an eicosyl group. Substituents acceptable for these alkyl groups include a halogen atom, a cycloalkyl group, an aryl group, and an ester group. Specific examples of the substituted alkyl group are halogen (F, Cl, Br)-substituted alkyl groups (e.g., -C₂HF₄, -C₅H₃F₈, -C₉H₃F₁₆, -C₂H₄Cl, -C₃H₆Cl, -C₃H₅Cl₂, -C₃H₅ClBr, -C₃H₅Br₂), cycloalkyl-substituted alkyl groups (e.g., aryl-substituted alkyl groups (e.g., substituents forming dibasic acid esters (e.g., -CH₂CH₂COOC₁₂H₂₅, -(CH₂)₄COOCH₂(CF₂)₄H, -(CH₂)₇COOC₄H₉, -(CH₂)₈COOC₄H₉), substituents forming lactic esters (e.g., substituents forming citric esters (e.g., substituents forming malic esters (e. g., -CH₂CH(OH)-COOC₆H₁₃), substituents forming tartaric esters (e.g., -CH(OH)CH(OH)COOC₈H₁₇, and the like. In the formula (E), the condensed ring formed by W₁ and W₂ includes an oxirane ring, an oxorane ring, and an oxane ring. The cycloalkyl group as represented by W₁, W₂, W₃, or W₄ includes e.g. The substituted cyclohexyl group as represented by W₁, W₂, W₃, or W₄ includes e.g. The aryl group as represented by W₁, W₂, W₃, or W₄ includes e.g. , and the substituted aryl group includes a substituted benzoic ester group, e.g., a phthalic ester group, e.g., an isophthalic ester group, a terephthalic ester group, a trimellitic ester group. The alkenyl group includes e.g. -C₄H₇, -C₅H₉, -C₆H₁₁, -C₇H₁₃, -C₈-H₁₅, -C₁₀H₁₉, -C₁₂H₂₃, -C₁₈H₃₅, and the substituted alkenyl group includes e.g. an alkenyl group substituted with a halogen atom (e.g., F, Cl, Br), -OC₈H₁₇, -OC₁₂H₂₅, -C₈H₁₅, -C₁₂H₂₃, -CH=CH-COOCH₂CHC₄H₉, The heterocyclic group as represented by W₁, W₂, W₃, or W₄ includes e.g. The high-boiling organic solvents which can be preferably used in the invention are those of formulae (A) to (E), more preferably those in which a total number of carbon atoms contained in W₁, W₂, W₃, and W₄ is about 8 or more, and having a dielectric constant of 4.00 or more, and more preferably 5.0 or more, at 25°C, and a viscosity of 20 cp or more at 25°C. By using high-boiling organic solvents having a dielectric constant and a viscosity of the above ranges, color developability can be improved surprisingly without impairing other characteristics, such as absorption of developed dyes. The reasons therefore are not clear, but it would be surmised that high-boiling organic solvents having a high dielectric constant show a large takeup of a color developing agent and that those having a medium viscosity weaken some adverse influences of couplers in oil droplets upon silver halides. The amount of the high-boiling organic solvent of formulae (A) to (E) to be used is arbitrarily selected depending on the kind and amount of couplers used. It is usually preferable that a weight ratio of the high-boiling organic solvent to the coupler is within a range of from 0.05 to 20. The high-boiling organic solvents of formulae of (A) to (E) according to the present invention may be used individually or in combinations thereof or, if desired, in combination with other conventionally known high-boiling organic solvents. Examples of the known high-boiling organic solvents to be used in combination include phosphoric esters, e.g., tricresyl phosphate, tri-2-ethylhexyl phosphate, 7-methyloctyl phosphate, tricyclohexyl phosphate, etc., phenolic solvents, e.g., 2,5-di-t-amylphenol, 2,5-di-sec-amylphenol. Specific but nonlimitative examples of the high-boiling organic solvents (S) represented by formulae (A) to (E) are shown below: (S-1) O=P(OC₄H₉- n )₃ (S-2) (S-3) O=P(OC₆H₁₃- n )₃ (S-4) (S-5) (S-6) O=P(OC₈H₁₇- n )₃ (S-7) (S-8) (S-9) (S-10) O=P(OC₉H₁₉- n )₃ (S-11) (S-12) O=P(OC₁₀H₂₁- n )₃ (S-13) (S-14) (S-15) (S-16) (S-17) (S-18) (S-19) (S-20) (S-21) (S-22) (S-23) (S-24) (S-25) (S-26) (S-27) (S-28) (S-29) (S-30) (S-31) (S-32) (S-33) (S-34) (S-35) (S-36) (S-37) (S-38) (S-39) (S-40) (S-41) (S-42) (S-43) (S-44) (S-45) (S-46) (S-47) (S-48) (S-49) (S-50) (S-51) (S-52) (S-53) (S-54) (S-55) (S-56) (S-57) (S-58) (S-59) (S-60) (S-61) (S-62) (S-63) (S-64) (S-65) (S-66) (S-67) In addition to the couplers of formulae (I) to (V), the light-sensitive materials of the invention may contain other functional materials, such as e.g. colored couplers, DIR couplers, diffusible dye forming couplers, DIR hydroquinones. The couplers according to the present invention can be added to light-sensitive materials in any optional amounts, but are usually used in an amount of from 0.01 to 10 mols, preferably from 0.1 to 1 mol, and more preferably from 0.2 to 0.5 mol, per mol of silver halide. The light-sensitive materials of the invention can contain an ultraviolet absorbent in any optional layer. The ultraviolet absorbent is preferably incorporated to one or both of upper and lower layers adjacent to a layer containing the coupler of the present invention. Examples of the ultraviolet absorbents which can be used in the present invention are recited in Research Disclosure , No. 17643, VIII-C. Preferred among them are benzotriazole derivatives represented by formula (XVII) wherein R₂₈, R₂₉, R₃₀, R₃₁, and R₃₂ (which may be the same or different) each represents a hydrogen atom or a substituent; and R₃₁ and R₃₂ may be cyclized to form a 5- or 6-membered carbon ring. The substituent as represented by R₂₈, R₂₉, R₃₀, R₃₁, or R₃₂ is selected from those enumerated for the aromatic groups as represented by R₁. Of these groups, those which may have any substituent may be substituted with the substituents described for R₁. The compounds represented by formula (XVII) can be used either individually or in combinations of two or more thereof. Typical examples of these compounds are shown below: Methods for synthesizing the compounds of formula (XVII) and additional examples of the compounds (XVII) are described e.g. in Japanese Patent Publication No. 29620/69, Japanese Patent Application Nos. 151149/75 and 95233/79, U.S. Patent 3,766,205, European Patent 57,160, Research Disclosure , No. 22519 (1983). High-molecular ultraviolet absorbents as described in Japanese Patent Application (OPI) Nos. 111942/83, 178351/83, 181041/83, 19945/84, and 23344/84 can also be used. A specific example of such high-molecular ultraviolet absorbents is given below as UV-20. Combinations of low-molecular ultraviolet absorbents and high-molecular ultraviolet absorbents may also be used. The above-described ultraviolet absorbent is dissolved in a high-boiling organic solvent and/or a low-boiling organic solvent, and the solution is dispersed in a hydrophilic colloid in the same manner as for couplers. The amount of the high-boiling organic solvent to be used is not particularly limited, but is usually up to 300% by weight based on the ultraviolet absorbent. Ultraviolet absorbents that are liquid at ambient temperature are used to advantage either individually or in combinations. When the combination of couplers according to the present invention is combined with the aforesaid ultraviolet absorbent of formula (XVII), preservability, particularly fastness to light, of developed dye images, particularly cyan images, can be improved. The ultraviolet absorbent is applied in an amount enough to impart light stability to cyan dye images. As too a large amount of the ultraviolet absorbent is likely to cause yellowing of unexposed areas (white background) of color photographic light-sensitive materials, the ultraviolet absorbent is usually coated in an amount ranging from 1 x 10⁻⁴ to 2 x 10⁻³ mol/m², and preferably from 5 x 10⁻⁴ to 1.5 x 10⁻³ mol/m². In the case of ordinary color papers, the ultraviolet absorbent is incorporated in one or both, and preferably both, of the upper and lower layers adjacent to a cyan coupler-containing red-sensitive emulsion layer. When it is added to an intermediate layer between a green-sensitive layer and a red-sensitive layer, it may be co-emulsified together with a color mixing inhibitor. When it is added to a protective layer, another independent protective layer may be provided as an outermost layer. Such an outermost protective layer may contain a matting agent or an optional particle size, and the like. In order to furhter improve preservability of developed dye images, particularly yellow, cyan, and magenta dye images, various organic type and metal complex type discoloration inhibitors can be used. The organic discoloration inhibitors include e.g. hydroquinones, gallic acid derivatives, p-alkoxyphenols, p-hydroxyphenols. Examples of dye image stabilizers, stain inhbitors, or antioxidants are described in patents cited in Research Disclosure , No. 17643, VII-I to J. Examples of the metal complex type discoloration inhibitors are described in e.g. Research Disclosure , No. 15162. Heat- and light-fastness of yellow images can be improved by using a number of compounds belonging to phenols, hydroquinones, hydroxychromans, hydroxycoumarans, and hindered amines, and alkyl ethers, silyl ethers or hydrolyzable precursors thereof. Of these compounds, those represented by formulae (XVIII) and (XIX) shown below are particularly effective to improve fastness of yellow images to both light and heat. These compounds are effective to improve fastness of cyan images also. Formula (XVIII) is represented by wherein R₄₀ represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted heterocyclic group, or a substituted silyl group of formula wherein R₅₀, R₅₁, and R₅₂ (which may be the same or different) each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted aliphatic oxy group, or a substituted or unsubstituted aromatic oxy group, wherein the substituent is selected from those acceptable for R₁; and R₄₁, R₄₂, R₄₃, R₄₄, and R₄₅ (which may be the same or different) each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxyl group, an alkoxycarbonyl group, a mono- or dialkylamino group, an imino group, or an acylamino group. Formula (XIX) is represented by wherein R₄₆, R₄₇, R₄₈, and R₄₉ (which may be the same or different) each represents a hydrogen atom or an alkyl group; X represents a hydrogen atom, an aliphatic group, an acyl group, an aliphatic or aromatic sulfonyl group, an aliphatic or aromatic sulfinyl group, an oxy radical group, or a hydroxyl group; and A represents a non-metallic atomic group forming a 5-, 6-, or 7-membered ring. Specific but nonlimitative examples of the compounds of formula (XVIII) or (XIX) are shown below: The methods for synthesizing the compounds of formulae (XVIII) and (XIX) as well as additional specific examples of these compounds are described in British Patents 1,326,889, 1,354,313, and 1,410,846, U.S. Patents 3,336,135 and 4,268,593, Japanese Patent Publication Nos. 1420/76 and 6623/77, and Japanese Patent Application (OPI) Nos. 114036/83 and 5246/84. The compounds of formulae (XVIII) and (XIX) may be used individually or in combinations of two or more thereof or in combinations with other conventionally known discoloration inhibitors. The amount of the compound of formula (XVIII) or (XIX) varies depending on the kind of the yellow coupler to be used, but usually ranges from 0.5 to 200% by weight, and preferably from 2 to 150% by weight, based on the yellow coupler. It is preferable that the compound of formula (XVIII) or (XIX) be co-emulsified together with the yellow coupler of formula (V). While the aforesaid dye image stabilizers, stain inhibitors and antioxidants are also effective to improve preservability of magenta dyes obtained from the magenta couplers of formulae (IV-2) and (IV-3), compounds represented by formulae (XX), (XXI), (XXII), (XXIII), (XXIX), and (XXV) shown below are particularly preferred for their effect to improve preservability of the magenta dyes. Formula (XX) is represented wherein R₆₀ has the same meaning as R₄₀ in formula (XVIII); and R₆₁, R₆₂, R₆₄, and R₆₅ (which may be the same or different) each represents a hydrogen atom, an aliphatic group, an aromatic group, an acylamino group, a mono- or dialkylamino group, an aliphatic or aromatic thio group, an aliphatic or aromatic oxycarbonyl group, or -OR₆₀; R₆₀ and R₆₁ may be bonded together to form a 5- or 6-membered ring; and R₆₁ and R₆₂ may be bonded together to form a 5- or 6-membered ring. Formula (XXI) is represented by wherein R₆₀, R₆₁, R₆₂, R₆₄, and R₆₅ are as defined above; and n represents 0 or an integer of from 1 to 6. Formula (XXII) is represented by wherein R₆₀, R₆₁, R₆₄, and R₆₅ are as defined above. Formula (XXIII) is represented by wherein R₆₀, R₆₁, R₆₂, R₆₄, and R₆₅ are as defined above; and R₆₃ has the same meaning as R₆₀ to R₆₅. Formula (XXIV) is represented by wherein R₆₀ and R₆₁ are as defined above; X represents a divalent linking group; and m represents 0 or an integer of from 1 to 4. Formula (XXV) is represented by wherein R₆₁, R₆₂, R₆₃, and R₆₄ are as defined above; R₆₆ and R₆₇ (which may be the same or different) each represents a hydrogen atom, an aliphatic group, an aromatic group, or a hydroxyl group; R₆₈ represents a hydrogen atom, an aliphatic group, or an aromatic group; R₆₆ and R₆₇ may be taken together to form a 5- or 6-membered ring; and M represents Cu, Co, Ni, Pd, or Pt. In formulae (XX) to (XXV), the aliphatic group or aromatic group as represented by R₆₁, R₆₂, R₆₃, R₆₄, R₆₅, R₆₆, R₆₇, or R₆₈ may be substituted with the substituents acceptable for R₁. When n or m is 2 or more, two or more groups R₆₂ or R₆₁ may be the same or different. In formula (XXIV), typical example of X preferably include wherein R₇₀ represents a hydrogen atom or an alkyl group. R₆₁ in formula (XXV) preferably represents a group capable of forming a hydrogen bond. At least one of R₆₂, R₆₃, and R₆₄ is preferably a hydrogen atom, a hydroxyl group, an alkyl group, or an alkoxy group. A total number of carbon atoms contained in R₆₁, R₆₂, R₆₃, R₆₄, R₆₅, R₆₆, R₆₇, and R₆₈ is preferably 4 or more. Specific but nonlimitative examples of the compounds represented by formulae (XX) to (XXV) are shown below: The methods of synthesis and additional specific examples of these compounds are described in U.S. Patents 3,336,135, 3,432,300, 3,573,050, 3,574,627, 3,700,455, 3,764,337, 3,935,016, 3,982,944, 4,254,216, and 4,279,990, British Patents 1,347,556, 2,062,888, 2,066,975, and 2,077,455, Japanese Patent Application (OPI) Nos. 97353/85, 152225/77, 17729/78, 20327/78, 145530/79, 6321/80, 21004/80, 24141/83, and 10539/84, and Japanese Patent Publication Nos. 31625/73 and 12337/79. A reflective support which can be used in the present invention is a support which has heightened reflecting properties to make a dye image formed in a silver halide emulsion layer clearer. Such a reflective support includes a support having coated thereon a hydrophobic resin having dispersed therein a light reflecting substance, e.g., titanium oxide, zinc oxide, calcium carbonate, calcium sulfate, and a support made of such a light reflecting substance-containing hydrophobic resin per se . Examples of the reflective support are baryta paper, polyethylene-coated paper, polypropylene-based synthetic paper, and transparent supports having a reflective layer or containing a reflective substance, such as a glass sheet, polyester films, e.g., polyethylene terephthalate, cellulose triacetate, cellulose nitrate, polyamide films, polycarbonate films, polystyrene films, and the like. The support to be used can be selected appropriately from among them according to the end use. Photo-setting resins may also be used as support materials. The processing steps, i.e., image formation process, according to the present invention will be described below. According to the present invention, the color development processing is completed within a short processing time of 2 minutes and a half, and preferably in a processing time of from 30 to 130 seconds. The processing time herein referred to means a time of from the contact of a light-sensitive material with a color developing solution to the contact with a subsequent bath, and covers, therefore, the time for transfer between baths. The color developing solution which can be used in this invention contains no substantial benzyl alcohol. The term "no substantial benzyl alcohol" as used herein means that the content of benzyl alcohol in the color developing solution should be less than 1.0 ml per liter. The developing solution preferably contains not more than 0.5 ml/l of benzyl alcohol, and more preferably contains no benzyl alcohol at all. The color developing solution to be used preferably comprises an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. The color developing agent includes p-phenylenediamine compounds to advantage, which typically include 3-methyl-4-amino-N,N-diethylaniline, 3-methyl-4-amino-N-ethyl-N-β-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methoxyethylaniline, and sulfates, hydrochlorides, phosphates, p-toluenesulfonates, tetraphenylborates or p-(t-octyl)benzenesulfonates thereof, and the like- Among them, 3-methyl-4-amino-N-ethyl-N-β-hydroxyethylaniline and 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, particularly 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, are preferred. Aminophenol derivatives may also be used as a developing agent, such as e.g. o- or p-aminophenol, 4-amino-2-methylphenol, 2-amino-3-methylphenol, 2-hydroxy-3-amino-1,4-dimethylbenzene. In addition, color developing agents described in L.F.A. Mason, Photographic Processing Chemistry , 226-229, Focal Press (1966), U.S. Patent 2,193,015 and 2,592,364, and Japanese Patent Application (OPI) No. 64933/73 can also be employed. If necessary, these color developing agents may be used in combinations of two or more thereof. The processing temperature for color development preferably ranges from 30 to 50°C. From the standpoint of solution stability, etc., the color developing solution preferably has a pH of 12 or less, and more preferably 10.5 or less. The color developing solution to be used in the invention can contain various development accelerators other than the substantial amount of benzyl alcohol. Usable development accelerators include various pyrimidium compounds, other cationic compounds, cationic dyes (e.g., phenosafranine), and neutral salts (e.g., thallium nitrate, potassium nitrate) as described, e.g., in U.S. Patent 2,648,604, Japanese Patent Publication No. 9503/69, and U.S. Patent 3,171,247; nonionic compounds, such as polyethylene glycol and derivatives thereof, polythioethers, as described, e.g., in U.S. Patents 2,533,990, 2,531,832, 2,950,970, and 2,577,127; thioether compounds as described in U.S. Patent 3,201,242; and compounds described in Japanese Patent Application (OPI) Nos. 156934/83 and 220344/85. In carrying out development in a short time as in the present invention, not only a means for acceleration of development but also a means for prevention of developer fog would be important subjects to consider. Antifoggants which are preferably applicable to the present invention include alkali metal halides, e.g., potassium bromide, sodium bromide, potassium iodide; and organic anti-foggants, such as nitrogen-containing heterocyclic compounds (e.g., benzotriazole, 6-nitrobenzimidazole, 5-nitrosoindazole, 5-methylbenzotriazole, 5-nitrobenzotriazole, 5-chlorobenzotriazole, 2-thiazolylbenzimidazole, 2-thiazolylmethylbenzimidazole, hydroxyazaindolizine), mercapto-substituted heterocyclic compounds (e.g., 1-phenyl-5-mercaptotetrazole, 2-mercaptobenzimidazole, 2-mercaptobenzothiazole), and mercapto-substituted aromatic compounds (e.g., thiosalicylic acid). Preferred of these are halides. It does not matter if these antifoggants are eluted from color light-sensitive materials during processing and accumulated in the developer. The color developing solution to be used in the invention can further contain various additives:- pH buffering agents, e.g., alkali metal carbonates, borates, or phosphates; preservatives, e.g., hydroxylamine, triethanolamine, compounds described in West German Patent Publication (OS) No. 2622950, sulfites, bisulfites; organic solvents, e.g., diethylene glycol; dye forming couplers; competing couplers; nucleating agents, e.g., sodium boron hydride; auxiliary developing agents, e.g., 1-phenyl-3-pyrazolidone; thickening agents; chelating agents, such as aminopolycarboxylic acids (e.g., ethylenediaminetetraacetic acid, nitrilotriacetic acid, cyclohexanediaminetetraacetic acid, iminodiacetic acid, N-hydroxymethylethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid, triethylenetetraminehexaacetic acid, and the compounds described in Japanese Patent Application (OPI) No. 195845/83), 1-hydroxyethylidene-1,1′-diphosphonic acid, the organic phosphonic acids described in Research Disclosure , No. 18170 (May, 1979), aminophosphonic acids (e.g., aminotris(methylenephosphonic acid), ethylenediamine-N,N,N′,N′-tetramethylenephosphonic acid), and phosphonocarboxylic acids (e.g., those described in Japanese Patent Application (OPI) Nos. 102726/77, 42730/78, 121127/79, 4024/80, 4025/80, 126241/80, 65955/80, and 65956/80, and Research Disclosure , No. 18170 (May, 1979); and the like. If desired, the color development bath may be divided into two or more, and the first or the last bath is replenished with a color developer replenisher to thereby make reductions in developing time and amount of the replenisher. After color development, silver halide color light-sensitive materials are usually subjected to bleaching. Bleaching may be carried out simultaneously with fixation (bleach-fix), or these two steps may be effected separately. Bleaching agents to be used include compounds of polyvalent metals, e.g., iron (III), cobalt (III), chromium (VI), copper (II), peracids, quinones, nitroso compounds. Examples of the bleaching agents are ferricyanides; bichromates; organic complex salts of iron (III) or cobalt (III), such as those formed with aminopolycarboxylic acids (e.g., ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, 1,3-diamino-2-propanoltetraacetic acid), or organic acids (e.g., citric acid, tartaric acid, malic acid); persulfates, manganates; nitrosophenol. Particularly preferred among them are potassium ferricyanide, sodium (ethylenediaminetetraacetato)iron (III), ammonium (ethylenediaminetetraacetato)iron (III), ammonium (triethylenetetraminepentaacetato)iron (III), and persulfates. (Ethylenediaminetetraacetato)- iron (III) complex salts are useful in both an independent bleaching bath and a bleach-fixing monobath. The bleaching bath or bleach-fixing bath may contain various acclerators, if desired. The accelerators to be used include a bromine ion, an iodine ion, as well as thiourea compounds as described in U.S. Patent 3,706,561, Japanese Patent Publication Nos. 8506/70 and 26586/84, and Japanese Patent Application (OPI) Nos. 32735/78, 36233/78, and 37016/78; thiol compounds as described in Japanese Patent Application (OPI) Nos. 124424/78, 95631/78, 57831/78, 32736/78, 65732/78, and 52534/79, and U.S. Patent 3,893,858; heterocyclic compounds as described in Japanese Patent Application (OPI) Nos. 59644/74, 140129/75, 28426/78, 141623/78, 104232/78, and 35727/79; thioether compounds as described in Japanese Patent Application (OPI) Nos. 20832/77, 25064/80, and 26506/80; quaternary amines as described in Japanese Patent Application (OPI) No. 84440/83; thiocarbamoyl compounds as described in Japanese Patent Application (OPI) No. 42349/84; and the like. Fixing agents to be used include e.g. thiosulfates, thiocyanates, thioether compounds, thioureas, a large amount of iodides, with thiosulfates being widely employed. Preservatives for the bleach-fixing bath or fixing bath preferably include sulfites, bisulfites, and carbonyl-bisulfite addition products. Bleach-fix or fixation is usually followed by washing with water. For the purpose of preventing sedimentation or saving water, a washing bath can contain various known compounds according to necessity. Such compounds include water softeners for preventing sedimentation, e.g., inorganic phosphoric acids, aminopolycarboxylic acids, organic phosphoric acids; bactericides or anti-molds for preventing growth of various bacteria, algae or fungi; hardeners, e.g., magnesium salts, aluminum salts; surface active agents for reducing a drying load or preventing unevenness, and the like. The compounds described in L.E. West, Photo. Sci. and Eng. , Vol. 9, No. 6 (1965) may also be added. In particular, addition of chelating agents and anti-molds is effective. Water saving can be achieved by carrying out washing in a multi-stage (e.g., 2 to 5 stages) countercurrent system. The washing step may be followed by or replaced with a multi-stage countercurrent stabilization step as described in Japanese Patent Application (OPI) No. 8543/82. The stabilizing step requires from 2 to 9 vessels arranged in a countercurrent system. The stabilizing bath contains various additives for image stabilization, such as buffering agents for film pH-adjustment (e.g., borates, metaborates, borax, phosphates, carbonates, potassium hydroxide, sodium hydroxide, aqueous ammonia, monocarboxylic acids, dicarboxylic acids, polycarboxylic acid), and formalin. If desired, the stabilizing bath can further contain water softeners (e.g., inorganic or organic phosphoric acids, aminopolycarboxylic acids, aminopolyphosphonic acids, phosphonocarboxylic acids), bactericides (e.g., Proxel®, isothiazolone, 4-thiazolylbenzimidazole, halogenated phenolbenzotriazoles), surface active agents, fluorescent brightening agents, hardeners. The stabilizing bath may furthermore contain, as film pH adjustors after processing, various ammonium salts, e.g., ammonium chloride, ammonium nitrate, ammonium sulfate, ammonium phosphate, ammonium sulfite, ammonium thiosulfate. Silver halide emulsions which can be used in the present invention include silver bromide, silver chlorobromide, silver chloride, silver iodobromide, and silver iodochlorobromide. The iodide content is preferably 2 mol% or less for the purpose of further accelerating the development. Silver chlorobromide emulsions containing 10 mol% or more of silver bromide are preferred. A silver bromide content exceeding 20 mol% but less than 90 mol% is preferred in order to obtain an emulsion having sufficient sensitivity without increasing fog. The use of silver chloride or silver chlorobromide having a silver chloride content of 90 mol% or more is particularly preferred because a high color density is obtained even when processed for a more shortened period. Silver halide grains to be used may have a homogeneous phase, a heterogeneous phase comprising a core and an outer shell or a multi-phase structure having a fusion structure, or a mixture thereof. The silver halide grains preferably have a mean grain size of from 0.1 to 2 µm, and more preferably from 0.15 to 1 µm, the mean grain size being a mean diameter of spherical or nearly spherical grains or a mean edge length of cubic grains, averaged based on the projected area. Grain size distribution may be either narrow or broad, but it is preferable to use a so-called mono-dispersed silver halide emulsion having not greater than 20%, and more preferably not greater than 15%, of a coefficient of variation of grain size (i.e., a quotient of a standard deviation of a size distribution curve divided by a mean grain size). In order to obtain desired gradation, two or more kinds of mono-dispersed silver halide emulsions (preferably those having a coefficient of variation within the above-recited range) being different in grain size can be mixed and coated as a single emulsion layer or they may be coated separately in two or more layers having substantially the same color sensitivity. Further, two or more kinds of poly-dispersed silver halide emulsions or a combination of a mono-dispersed emulsion and a poly-dispersed emulsion may be mixed or separately coated. The silver halide grains may have a regular crystal form, e.g., a cube, an octahedron, a dodecahedron, a tetradecahedron, or an irregular (e.g., spherical, tabular) crystal form, or a composite form thereof. In particular, a tabular grain emulsion containing at least 50%, based on the total projected area, of tabular grains having a ratio of length to thickness of 5 or more, and preferably 8 or more, can be employed. The emulsion may be a mixture of these various silver halide grains. The emulsion may be either of the surface latent image type which forms a latent image predominantly on the surface or of the internal latent image type which forms a latent image predominantly in the interior of grains. The photographic emulsions to be used in the invention can be prepared by known methods as described, e.g., in P. Glafkides, Chimie et Physique Photographique , Paul Montel (1967), G.F. Duffin, Photographic Emulsion Chemistry , Focal Press (1966), V.L. Zelikman et al, Making and Coating Photographic Emulsion , Focal Press (1964). In some detail, the emulsion can be prepared by any of the acid process, the neutral process, the ammonia process, and the like. The reaction between soluble silver salts and soluble halogen salts can be carried out by any of the single jet process, the double jet process, and a combination thereof. A so-called reverse mixing method, in which silver halide grains are formed in the presence of excess silver ions, may also be used. Further, a so-called controlled double jet method, in which a pAg of a liquid phase where silver halide grains are formed is maintained constant, can be adopted. According to this method, a silver halide emulsion having a regular crystal form and an almost uniform grain size can be obtained. In addition, an emulsion prepared by a so-called conversion method which involves a step of converting silver halide grains formed to those having a smaller solubility product by the end of the grain formation step, or an emulsion having undergone such conversion after the end of the grain formation step can also be employed. In the step of silver halide grain formation or physical ripening, e.g. a cadmium salt, a zinc salt, a lead salt, a thallium salt, an iridium salt or a complex salt thereof, a rhodium salt or a complex salt thereof, an iron salt or a complex salt thereof may be present in the system. The silver halide emulsion thus prepared is usually subjected to physical ripening, desalting, and chemical ripening prior to coating. In the precipitaiton, physical ripening, or chemical ripening, known silver halide solvents can be used. Examples of usable silver halide solvents are ammonia, potassium thiocyanate, and thioethers and thione compounds as described in U.S. Patent 3,271,157, and Japanese Patent Application (OPI) Nos. 12360/76, 82408/78, 144319/78, 100717/79, and 155828/79. Removal of soluble silver salts from emulsions after physical ripening can be carried out by noodle washing, flocculation-sedimentation, or ultrafiltration. Chemical sensitization of the silver halide emulsion can be performed by sulfur sensitization using active gelatin or a compound containing sulfur capable of reacting with silver (e.g., thiosulfates, thioureas, mercapto compounds, rhodanines); reduction sensitization using a reducing substance (e.g., stannous salts, amines, hydrazine derivatives, formamidinesulfinic acid, silane compounds); noble metal sensitization using a metal compound (e.g., complex salts of gold as well as metals of Group III of the Periodic Table, e.g., Pt, Ir, Pd, Rh, Fe); or a combination thereof. Sulfur sensitization is preferred. The blue-sensitive, green-sensitive, or red-sensitive emulsion according to the present invention is obtained by spectrally sensitizing the respective layer with methine dyes or others so as to have the respective color sensitivity. Sensitizing dyes to be used include cyanine dyes, merocyanine dyes, complex cyanine dyes, complex merocyanine dyes, holopolar cyanine dyes, hemicyanine dyes, styryl dyes, and hemioxonol dyes. Particularly preferred are cyanine dyes, merocyanine dyes, and complex merocyanine dyes. Any of nuclei commonly utilized in cyanine dyes as a basic heterocyclic nucleus is applicable to these sensitizing dyes. Specific examples of the applicable nuclei include a pyrroline nucleus, an oxazoline nucleus, a thiazoline nucleus, a pyrrole nucleus, an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, an imidazole nucleus, a tetrazole nucleus, a pyridine nucleus; the above-described nucleus to which an alicyclic hydrocarbon ring is fused; and the above-described nucleus to which an aromatic hydrocarbon ring is fused, e.g., an indolenine nucleus, a benzindolenine nucleus, an indole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a benzoselenazole nucleus, a benzimidazole nucleus, a quinoline nucleus. These nuclei may have a substituent on thier carbon atoms. To the merocyanine dyes or complex merocyanine dyes is applicable a 5- to 6-membered heterocyclic nucleus having a ketomethylene structure, e.g., a pyrazolin-5-one nucleus, a thiohydantoin nucleus, a 2-thiooxazolidin-2,4-dione nucleus, a thiazolidin-2,4-dione nucleus, a rhodanine nucleus, a thiobarbituric acid nucleus. These sensitizing dyes may be used either individually or in combinations thereof. Combinations of sensitizing dyes are frequently used for the purpose of supersensitization. Typical examples of such combinations of sensitizing dyes are described in U.S. Patents 2,688,545, 2,977,229, 3,397,060, 3,522,052, 3,527,641, 3,617,293, 3,628,964, 3,666,480, 3,672,898, 3,697,428, 3,703,377, 3,769,301, 3,814,609, 3,837,862, and 4,026,707, British Patents 1,344,281 and 1,507,803, Japanese Patent Publication Nos. 4936/68 and 12375/78, and Japanese Patent Application (OPI) Nos. 110618/77 and 109925/77. The silver halide emulsions may further contain, in combination with the sensitizing dyes, dyes which do not per se have spectral sensitizing activity, or substances which do not substantially absorb visible light, but which do show supersensitizing effects. In order to avoid reduction of image sharpness, various anti-irradiation or anti-halation dyes can be employed. Typical examples of these dyes are described in Japanese Patent Publication Nos. 22069/64, 3504/68, 13168/68, 1419/76, 46607/76, 28085/78, 10059/80, 10060/80, 10061/80, 10187/80, and 10899/80, Japanese Patent Application (OPI) Nos. 145125/75 and 33104/80, U.S. Patent 3,647,460, and British Patent 1,338,799. In order to prevent color mixing, an intermediate layer containing a color mixing inhibitor may be provided between light-sensitive layers being different in color sensitivity. Typical examples of the color mixing inhibitor include alkylhydroquinones described in U.S. Patents 2,360,290, 2,419,613, 2,403,721, 3,960,570, and 3,700,453, Japanese Patent Application (OPI) Nos. 106329/74 and 156438/75, U.S. Patents 2,728,659, 2,732,300, and 3,243,294, and Japanese Patent Application (OPI) Nos. 9528/78, 55121/78, 29637/79, and 55339/85; hydroquinone sulfonates described in U.S. Patent 2,701,197 and Japanese Patent Application (OPI) No. 172040/85; aminohydroquinones described in Japanese Patent Application (OPI) No. 202465/84 and Japanese Patent Application Nos. 165511/85 and 296088/85; hydroquinones having electron-attractive substituents described in Japanese Patent Application (OPI) Nos. 43521/80, 109344/81, and 22237/82; and the like. In addition to these hydroquinone compounds, e.g., gallic acid amides, sulfonamidophenols may also be used. The present invention will now be illustrated in greater detail with reference to the following examples, but it should be understood that the present invention is not limited thereto. In these examples, all the percents are given by weight unless otherwise indicated. EXAMPLE 1 A paper support laminate with polyethylene on both sides thereof was coated with the following layers in the order listed to prepare a multi-layer color paper. The polyethylene layer on the side to be coated had dispersed therein titanium dioxide as a white pigment and ultramarine as a bruish dye. 1st Layer (Blue-Sensitive Layer): 2nd Layer (Color Mixing Preventing Layer): Gelatin 0.99 g/m² Color Mixing Inhibitor (G-2) 0.08 g/m² 3rd Layer (Green-Sensitive Layer): 4th Layer (Ultraviolet Absorbing Layer): 5th Layer (Red-Sensitive Layer): 6th Layer (Ultraviolet Absorbing Layer): 7th Layer (Protective Layer): Each of the coating compositions for the 1st to 7th layers was prepared as follows, taking that for the 1st layer as an instance:- In 27.2 ml of ethyl acetate and 7.9 ml of Solvent (S-25) were dissolved 19.1 g of Yellow Coupler (Y-35) and (4.4 g of Dye Image Stabilizer (B-18), and the resulting solution was emulsified and dispersed in 185 ml of a 10% aqueous gelatin solution containing 8 ml of 10% sodium dodecylbenzenesulfonate. Separately, a blue-sensitizing dye of formula shown below was added to a silver chlorobromide emulsion (silver bromide content: 80 mol%; silver content: 70 g/kg) in an amount of 7.0 x 10⁻⁴ mol per mol of silver chlorobromide to prepare 90 g of a blue-sensitive emulsion. The above prepared coupler dispersion and the silver chlorobromide emulsion were mixed, and the gelatin concentration was adjusted so as to result in the above-recited composition of the 1st layer. As a gelatin hardener in each layer, a sodium salt of 1-hydroxy-3,5-dichloro-s-triazine was used. Blue-Sensitizing Dye (for Blue-Sensitive Layer): (7.0 x 10⁻⁴ mol/mol of silver halide) Green-Sensitizing Dye (for Green-Sensitive Layer): (4.0 x 10⁻⁴ mol/mol of silver halide) (7.0 x 10⁻⁵ mol/mol of silver halide) Red-Sensitizing Dye (for Red-Sensitive Layer): (1.0 x 10⁻⁴ mol/mol of silver halide) The anti-irradiation dye used in each emulsion layer was shown below: For Green-Sensitive Layer: for Red-Sensitive Layer: The above prepared sample was designated as Sample 106. Samples 102 to 113 were prepared in the same manner as for Sample 106 except that the kind and amount of the coupler and the amount of the silver halide emulsion to be used in the 1st, 3rd, or 5th layer were changed as shown in Table 1 below. Yellow Coupler (a): Magenta Coupler (b): Cyan Coupler (c): Each of Samples 101 to 113 was exposed to light for 0.5 second at an exposure of 250 CMS using an optical wedge for sensitometry through a blue (B), green (G), or red (R) filter by means of a sensitometer (FWH Model manufactured by Fuji Photo Film Co., Ltd.; color temperature: 3,200°K). The exposed sample was subjected to Processing A or B according to the following procedure. Formulations of the processing solutions used are also described below. The procedure for Processing A and that for Processing B are equal except for using Developer A or Developer B, respectively. Processing Procedure: Formulation of Developer (A): Formulation of Developer (B): Formulation of Bleach-Fixing Bath: Photographic properties of the processed samples were evaluated in terms of relative sensitivity and maximum density (D max ). The relative sensitivity is a value relative to the sensitivity of each layer of the respective sample when processed according to Processing A for a developing time of 2 minutes, being taken as 100. The sensitivity is a relative value of a reciprocal of an exposure required for providing a density of a minimum density plus 0.5. The gradient is expressed in terms of a density difference between a sensitive point and a point higher than 0.5 in log E. The results obtained are shown in Table 2 below. It can be seen from Table 2 that the combinations of couplers according to the present invention show rapid progress of development even when processed with a color developing solution containing substantially no benzyl alcohol. To the contrary, Sample 113 using comparative couplers does not fulfil the object of the present invention due to serious delay in development when processed with a developing solution containing no benzyl alcohol. EXAMPLE 2 A paper support laminated with polyethylene on both sides thereof was coated with the following 1st to 11th layer to prepare Sample 201. The polyethylene layer on the side to be coated had dispersed therein titanium white as a white pigment and a trace amount of ultramarine as a bluish dye. 1st Layer (Antihalation Layer): Black colloidal silver 0.01 g/m² Gelatin 0.2 g/m² 2nd Layer (Low-Sensitive Red-Sensitive Layer): 3rd Layer (High-Sensitive Red-Sensitive Layer) : 4th Layer (Intermediate Layer): 5th Layer (Low-Sensitive Green-Sensitive Layer) : 6th Layer (High-Sensitive Green-Sensitive Layer) : 7th Layer (Yellow Filter Layer): 8th Layer (Low-Sensitive Blue-Sensitive Layer) : 9th Layer (High-Sensitive Blue-Sensitive Layer) : 10th Layer (Ultraviolet Absorbing Layer) : 11th Layer (Protective Layer): Gelatin 1.0 g/m² The compounds used in the sample preparation are as follows: *1: 5,5′-Dichloro-3,3′-di(3-sulfobutyl)-9-ethylthiacarbonylcyanine sodium salt *2: Triethylammonium 3-{2-{2-[3-(3-sulfopropyl)-naphtho(1,2-d)thiazolin-2-ylidenemethyl]-1-butenyl}-3-naphtho(1,2-d) thiazolino}propanesulfonate *3: 2,4-Di-t-hexylhydroquinone *4: Di-(2-hydroxy-3-t-butyl-5-methylphenyl)methane *5: 3,3,3′,3′-Tetramethyl-5,6,5′,6′-tetrapropoxy-1,1′-bisspiroindane *6: 5,5′-Diphenyl-9-ethyl-3,3′-disulfopropyloxycarbocyanine sodium salt *7: 2,4-Di-t-octylhydroquinone *8: Triethylammonium 3-[2-(3-benzylrhodanin-5-ylidene)-3-benzoxazolinyl]propanesulfonate *9: 2,4-Di-sec-octylhydroquinone *10: 5-Chloro-2-(2-hydroxy-3-t-butyl-5-t-octyl)-phenylbenzotriazole Comparative Sample 202 was prepared in the same manner as for Sample 201 except that the cyan coupler in the 2nd and 3rd layers, the magenta coupler in the 5th and 6th layers, and the yellow coupler in the 8th and 9th layers were replaced with Cyan Coupler (c), Magenta Coupler (b), and Yellow Coupler (a) as used in Sample 113 of Example 1. Each of Samples 201 and 202 was wedgewise exposed to light in a usual manner and processed according to Processing C shown below to obtain a color reversal image. Processing C: Each of the processing solutions used in Processing C had the following formulation. Formulation of First Developer: Formulation of Color Developer: Formulation of Bleach-Fixing Bath: The same procedure as described above was repeated except that benzyl alcohol was excluded from the formulation of the color developer (hereinafter referred to as Processing D). Each of the resulting reversal images was determined for maximum density (D max ) to red, green, or blue light. The results obtained are shown in Table 3. It can be seen from Table 3 that the sample according to the present invention provides sufficient maximum densities irrespective of whether a color developer contains benzyl alcohol or not, while the comparative sample undergoes reduction in density particularly when processed according to Processing D in which no benzyl alcohol is used. EXAMPLE 3 Samples 302, 303 and 305 were prepared in the same manner as for Samples 110, 112 and 113 of Example 1, respectively, except that:- (i) The silver chlorobromide emulsion in the 1st layer (blue-sensitive layer) was replaced with the same silver amount of a cubic silver chlorobromide emulsion having a silver bromide content of 4 mol% and a mean grain size of 0-95 µm. (ii) The amount of the blue-sensitizing dye to be used in the 1st layer was decreased to 5.5 x 10⁻⁴ mol per mol of silver. (iii) The silver chlorobromide emulsion in the 3rd layer (green-sensitive layer) was replaced with the same silver amount of a cubic silver chlorobromide emulsion having a silver bromide content of 57 mol% and a mean grain size of 0.55 µm. And, (iv) the silver chlorobromide emulsion in the 5th layer (red-sensitive layer) was replaced with the same silver amount of a cubic silver chlorobromide emulsion having a silver bromide content of 35 mol% and a mean grain size of 0.45 µm. Samples 307 and 308 were prepared in the same manner as for Samples 302 and 303, respectively, except for replacing Yellow Coupler (Y-23) used in Samples 302 and 303 with Yellow Coupler (Y-36). Each of Sampels 302 to 308 was exposed to light for 0.2 second at an exposure of 250 CMS using an optical wedge for sensitometry through a blue (B), green (G), or red (R) filter by means of a sensitometer (FWH Model manufactured by Fuji Photo Film Co., Ltd.; color temperature: 3.200°K). The exposed sample was subjected to Processing E or F according to the following procedure. Formulations of the processing solutions used are also described below. The procedure for Processing E and that for Processing F are equal except for using Developer E or F, respectively. Processing Procedure: Formulation of Developer (E): Formulation of Developer (F): Formulation of Bleach-Fixing Bath: Photographic properties of the processed samples were evaluated in the same manner as described in Example 1. The sensitivity of each layer of the respective sample when processed according to Processing E for a developing time of 100 seconds was taken as standard (100). The results obtained are shown in Table 4. AS can be seen from Table 4, the combination of the couplers according to the present invention exhibits excellent performances when processed in a color developer containing no benzyl alcohol and, in particular, for a reduced developing time. To the contrary, the comparative combination of couplers shows low sensitivity and low color densities. EXAMPLE 4 Samples 402 to 408 were prepared in the same manner as for Samples 302 to 308 of Example 3, respectively, except that the silver chlorobromide emulsion to be used in the 3rd layer (green-sensitive layer) was replaced with the same silver amount of a silver chlorobromide emulsion having a silver bromide content of 10 mol% and a mean grain size of 0.54 µm and that the silver chlorobromide emulsion to be used in the 5th layer (red-sensitive layer) was replaced with the same silver amount of a silver chlorobromide emulsion having a silver bromide content of 10 mol% and a mean grain size of 0.44 µm. Each of the resulting samples was sensitometrically exposed to light in the same manner as in Example 3 and then processed in the same manner as in Example 3 except for using Color Developer (G) (Processing (G)) or Color Developer (H) (Processing (H)) having the following formulation. Formulation of Developer (G): Formulation of Developer (H): Photographic properties of the processed samples were evaluated in the same manner as described in Example 1. The sensitivity of each layer of the respective sample when processed according to Processing (G) for a developing time of 100 seconds was taken as standard (100). The results obtained are shown in Table 5 below. It is clear from the foregoing results that in the light-sensitive materials according to the present invention, a high density can be obtained even when processed in a further reduced developing time with a color developing solution containing no benzyl alcohol. EXAMPLE 5 A paper support laminated with polyethylene on both sides thereof was coated with the following 1st to 7th layers in this order to prepare a multilayer color paper. The polyethylene layer on the side to be coated had dispersed therein titanium dioxide as a white pigment and ultramarine as a bluish dye. 1st Layer (Blue-Sensitive Layer): 2nd Layer (Color Mixing Preventing Layer): Gelatin 0.99 g/m² Color Mixing Inhibitor(*a) 0.08 g/m² 3rd Layer (Green-Sensitive Layer): 4th Layer (Ultraviolet Absorbing Layer): 5th Layer (Red-Sensitive Layer): 6th Layer (Ultraviolet Absorbing Layer): 7th Layer (Protective Layer): Note: *a: Each of the coating compositions was prepared in the same manner as described in Example 1 except for using the following spectral sensitizing dyes. Blue-Sensitizing Dye (for Blue-Sensitive Layer): (7.0 x 10⁻⁴ mol/mol of silver halide) Green-Sensitizing Dye (for Green-Sensitive Layer): (4.0 x 10⁻⁴ mol/mol of silver halide) Red-Sensitizing Dye (for Red-Sensitive Layer): (1.0 x 10⁻⁴ mol/mol of silver halide) The above prepared sample was designated as Sample 501. Samples 505 to 509 and 512 were prepared in the same manner as for Sample 501 except that the kind and amount of the coupler and the amount of the silver halide emulsion to be used in the 1st, 3rd, or 5th layer were changed as shown in Table 6. Each of Samples 501 to 512 was exposed to light for sensitometry under the same conditions as used in Example 1 and then subjected to Processing (I) using Color Developer (I) or Processing (J) using Color Developer (J) according to the following procedure. Formulations of the processing solutions used are also described below. Processing Procedure: Formulation of Developer (I): Formulation of Developer (J): Formulation of Bleach-Fixing Bath: Formulation of Rinsing Bath: The thus processed samples were evaluated for maximum density (D max ), minimum density (D min ), and relative sensitivity. The sensitivity of each sample when processed by Processing I was taken as standard (100). The results obtained are shown in Table 7. It is apparent from Table 7 that the light-sensitive materials according to the present invention exhibit excellent color developing properties without undergoing serious fog formation even when processed in a reduced developing time with a color developing solution containing no benzyl alcohol; while the comparative sample shows considerable reduction in relative sensitivity and maximum density when processed under such conditions. EXAMPLE 6 Each of Samples 505 and 512 of Example 5 was exposed to light for sensitometry and development-processed in the same manner as described in Example 5 except for replacing Developer (J) with Developer (K) having the following formulation (the processing using Developer (K) is designated as Processing (K)). Formulation of Developer (K): Photographic properties of the thus processed samples were evaluated in the same manner as in Example 5. The results obtained are shown in Table 8 below. As can be seen from Table 8, the samples in accordance with the present invention exhibit excellent color developing properties with less fog even when rapidly processed with a color developing solution 5 containing no benzyl alcohol; whereas the comparative sample undergoes serious reduction in relative sensitivity and maximum density when processed under such conditions. EXAMPLE 8 Each of Samples 501 and 512 as prepared in Example 5 was exposed to light for 0.5 second at an exposure of 250 CMS using an optical wedge for sensitometry through a blue (B), green (G), or red (R) filter by means of a sensitometer (FWH Model manufactured by Fuji Photo Film Co., Ltd.; color temperature: 3,200°K). The exposed sample was subjected to Processing O or P according to the following procedure. Formulations of the processing solutions used are also described below. The procedure for Processing O and that for Processing P are equal except for using Developer (O) or Developer (P), respectively. Processing Procedure: The washing was carried out in a countercurrent manner of three tanks by the direction of Washing (4) to Washing (1). Formulation of Color Developer Formulation of Bleach-Fixing Bath: Formulating of Washing Solution: Ion-exchanged water (containing not more than 3 ppm of each of calcium and magnesium) Each of the thus processed samples was subjected to preservation testing at a temperature of 80°C and at a relative humidity of 70% for 50 days. Where the density of yellow (D Y ), magenta (D G ), or cyan (D R ) of each sample had been 1.0 before the testing, the change in density as well as the change in D B in the fog density (Dmin) region were evaluated. The results obtained are shown in Table 11 below. It can be understood from Table 11 that in the rapid processing, an image obtained by processing with a color developing solution containing no benzyl alcohol is superior in fastness to humidity and heat to that obtained by processing with a color developing solution containing benzyl alcohol. Further, the former is excellent in image preservability such that yellow staining in the Dmin portion is less. Probably, this is because the carried amount of e.g. a developing agent, in a color developing solution by benzyl alcohol and the removal of unnecessary substances such as the developing agent in subsequent processings are insufficient. Thus, it can be understood that the method of color image formation according to the present invention gives rise to excellent color formation less in fog, excellent color image preservability less in staining in the white portion (i.e., less in yellow staining), and good color reproducibility with high chroma. As described above, the present invention makes it possible to substantially eliminate benzyl alcohol from a developing solution to thereby alleviate a pollution load, reduce the time and labor for the preparation of a developing solution, and prevent density reduction due to formation of a leuco compound from a cyan dye. The present invention further makes it possible to rapidly process a large number of color prints having improved color reproducibility, thereby markedly increasing productivity. According to the present invention, even when development processing is carried out in a reduced time using a color developing solution containing substantially no benzyl alcohol, the resulting color image does not undergo great reduction of color density and has low fog. Further, with respect to image preservability, when rapid processing with a color developing solution containing substantially no benzyl alcohol according to the present invention is applied, the amount of residual processing chemicals is reduced whereby good image preservability reveals.

Claims: A method for forming a color image, which comprises imagewise exposing a multi-layer silver halide colour photographic material comprising a reflective support having provided thereon at least three silver halide emulsion layers different in color sensitivity, each of which separately contains at least one of the couplers represented by formula (I) wherein R₁ represents an aliphatic group, an aromatic group, a heterocyclic group, an aromatic amino group, or a heterocyclic amino group; R₂ represents an aliphatic group; R₃ represents a hydrogen atom, a halogen atom, an aliphatic group, an aliphatic oxy group, or an acylamino group; or R₂ and R₃ are taken together to form a 5- to 7-membered ring; Y₁ represents a halogen atom, or a group capable of being split off upon coupling with an oxidation product of a developing agent; and R₁, R₂, or Y₁ may form a polymer including a dimer; at least one of the couplers represented by formula (IV-2) and (IV-3) wherein R¹¹ and R¹² each represents a hydrogen atom; a halogen atom a cyano group; R₁′, R₁′0-, R₁′SO-, R₁′-SO₂- R₁′SO₂NH-, R₁′NH-, R₁′-S-, wherein R₁′ represents an aliphatic, aromatic, or heterocyclic group; a silyl group; a silyloxy group; a silylamino group; an imino group; a carbamoyl group; a sulfamoyl group; or a sulfamoylamino group; X₁ represents a halogen atom or a group capable of being split off upon coupling with an oxidation product of a developing agent; and R¹¹, R¹² or X₁ may be a divalent group, at which a bis-compound is formed, or a linking group via which a polymer chain and a coupler nucleus are linked; and at least one of the couplers represented by formula (V) wherein Y₅ represents a group capable of being split off upon coupling with an oxidation product of a developing agent; and Q represents a substituted or unsubstituted N-phenylcarbamoyl group; or Y₅ or Q may form a polymer including a dimer, and processing the exposed material with a colour developing solution containing an aromatic primary amine as a colour developing agent for a period of not more than 2 min and a half, wherein said silver halide emulsions each contain silver chlorobromide and the colour developing solution is free from benzyl alcohol. The method of claim 1, wherein said at least one coupler represented by formula (I) is a coupler represented by formula (I′) wherein R₁ represents an aliphatic group, an aromatic group, an aromatic amino group, or a heterocyclic amino group; R′₂ represents an alkyl group having 2 to 4 carbon atoms; R₃ represents a hydrogen atom, a halogen atom, an aliphatic group, an aliphatic oxy group, or an acylamino group; Y₁ represents a halogen atom or a group capable of being split off upon coupling with an oxidation product of a developing agent; and R₁ or Y₁ may form a polymer including a dimer. The method of claim 1, wherein the couplers are dispersed in the presence of at least one of high-boiling organic solvents represented by formula (A) wherein W₁, W₂, and W₃ each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group, high-boiling organic solvents represented by formula (B) W₁ - COO - W₂ (B) wherein W₁ and W₂ are as defined above, high-boiling organic solvents represented by formula (C) wherein W₁, W₂, and W₃ are as defined above, high-boiling organic solvents represented by formula (D) wherein W₁ and W₂ are as defined above; W₄ represents W₁, OW₁, or S-W₁; and n represents an integer of from 1 to 5, and high-boiling organic solvents represented by formula (E) W₁ - 0 - W₂ (E) wherein W₁ and W₂ are as defined above, or W₁ and W₂ are taken together to form a condensed ring, and said high-boiling organic solvents represented by formulae (A) to (E) have a dielectric constant of 4.00 or more as measured at 25°C and 10 KHz. The method of claim 1, wherein at least one of the couplers represented by formulae (I), (IV-2), (IV-3) and (V) contains, in a nondiffusing group or split-off group thereof, at least one of a free carboxyl group, a carboxyl group in the form of a salt, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted sulfamoyl group, and a substituted or unsubstituted hydroxyphenyl group. The method of claim 3, wherein said high-boiling organic solvents represented by formulae (A) to (E) have a dielectric constant of 5.0 or more as measured at 25°C and 10 KHz and a viscosity of 0,02 Pa.s (20 cp) or more as measured at 25°C. The method of claim 1, wherein the color photographic material comprises a reflective support having thereon a blue-sensitive silver halide emulsion layer associated with at least one of couplers represented by formula (V), a green-sensitive silver halide emulsion layer associated with at least one of couplers represented by formula (IV-2) and (IV-3) and a red-sensitive silver halide emulsion layer associated with at least one of couplers represented by formula (I). The method of claim 1, wherein the silver halide has a regular crystal form. The method of claim 7, wherein the silver halide is cubic. The method of claim 1, wherein the silver halide predominantly forms a latent image on the surface thereof upon exposure to light. The method of claim 1, wherein the color photographic material further contains benzotriazole derivatives represented by formula (XVII): wherein R₂₈, R₂₉, R₃₀, R₃₁, and R₃₂, which may be the same or different, each represents a hydrogen atom or a substituent; and R₃₁ and R₃₂ may be cyclized to form a 5-or 6- membered carbon ring. The method of claim 1, wherein the color photographic material further contains at least one dye-image stabilizing compound represented by formulae (XVIII) and (XIX): wherein R₄₀ represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted heterocyclic group, or a substituted silyl group of formula wherein R₅₀, R₅₁, and R₅₂, which may be the same or different, each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted aliphatic oxy group, or a substituted or unsubstituted aromatic oxy group; and R₄₁, R₄₂, R₄₃, R₄₄, and R₄₅, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, a hydroxyl group, an alkoxycarbonyl group, a mono- or dialkylamino group, or an acylamino group; wherein R₄₆, R₄₇, R₄₈, and R₄₉, which may be the same or different, each represents a hydrogen atom or an alkyl group; X represents a hydrogen atom, an aliphatic group, an acyl group, an aliphatic or aromatic sulfonyl group, an aliphatic or aromatic sulfinyl group, an oxy radical group, or a hydroxyl group; and A represents a non-metallic atomic group forming a 5-, 6-, or 7-membered ring. The method of claim 1, wherein the color photographic material further contains at least one compound represented by formulae (XX), (XXI), (XXII), (XXIII), (XXIV), and (XXV): wherein R₆₀ represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted heterocyclic group, or a substituted silyl group of formula wherein R₅₀, R₅₁, and R₅₂, which may be the same or different, each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, a substituted or unsubstituted aliphatic oxy group, or a substituted or unsubstituted aromatic oxy group; and R₆₁, R₆₂, R₆₄, and R₆₅, which may be the same or different, each represents a hydrogen atom, an aliphatic group, an aromatic group, an acylamino group, a mono- or dialkylamino group, an aliphatic or aromatic thio group, an aliphatic or aromatic oxycarbonyl group, or OR₆₀; R₆₀ and R₆₁ may be bonded together to form a 5- or 6-membered ring; and R₆₁ and R₆₂ may be bonded together to form a 5- or 6-membered ring; wherein R₆₀, R₆₁, R₆₂, R₆₄, and R₆₅ are as defined above; and n represents 0 or an integer of from 1 to 6; wherein R₆₀, R₆₁, R₆₄, and R₆₅ are defined above; wherein R₆₀, R₆₁, R₆₂, R₆₄, and R₆₅ are as defined above; and R₆₃ has the same meaning as R₆₀ to R₆₅; wherein R₆₀ and R₆₁ are as defined above; X represents a divalent linking group; and m represents 0 or an integer of from 1 to 4; wherein R₆₁, R₆₂, R₆₃, and R₆₄ are as defined above; R₆₆ and R₆₇, which may be the same or different, each represents a hydrogen atom, an aliphatic group, an aromatic group, or a hydroxyl group; R₆₈ represents a hydrogen atom, an aliphatic group, or an aromatic group; R₆₆ and R₆₇ may be taken together to form a 5- or 6-membered ring; and M represents Cu, Co, Ni, Pd, or Pt. The method of claim 1, wherein the silver halide emulsion is a mono-dispersed silver halide emulsion having a coefficient of variation of grain size of not greater than 20 %. The method of claim 13, wherein the silver halide emulsion is a mono-dispersed silver halide emulsion having a coefficient of variation of grain size of not greater than 15 %. The method of claim 1, wherein the aromatic primary amine compound is a p-phenylenediamine derivative. The method of claim 15, wherein the p-phenylenediamine derivative is 3-methyl-4-amino-N-ethyl-N-β-hydroxyethylaniline or 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline. The method of claim 1 wherein the processing time is from 30 to 130 s.

Inventors: AOKI KOZO FUJI PHOTO FILM CO L, FURUSAWA GENICHI FUJI PHOTO FI, FURUTACHI NOBUO FUJI PHOTO FIL, HIROSE TAKESHI FUJI PHOTO FILM, NAKAZYO KIYOSHI FUJI PHOTO FIL, AOKI, KOZO FUJI PHOTO FILM CO., LTD., FURUSAWA, GENICHI FUJI PHOTO FILM CO., LTD., FURUTACHI, NOBUO FUJI PHOTO FILM CO., LTD., HIROSE, TAKESHI FUJI PHOTO FILM CO., LTD., NAKAZYO, KIYOSHI FUJI PHOTO FILM CO., LTD.
Applicants: FUJI PHOTO FILM CO LTD, FUJI PHOTO FILM CO., LTD.
Application year: 1987
Main classification: G03C7
IPC codes: G03C7, G03C1