ABRASIVE ARTICLE

Abstract: Vitrified abrasive articles, such as grinding wheels, have an inner core and an outer rim of differing compositions, but of substantially equal coefficients of thermal expansion. The core comprises a mixture of silicon carbide, alumina and vitrified bonding medium, and the rim comprises cubic boron nitride, alumina and vitrified bonding medium. A preferred composition for the prefired rim material is a mixture comprising about 10 to 70% by weight cubic boron nitride, about 5 to 60% alumina, and about 15 to 35% bonding medium; and a preferred prefired core composition comprises about 10 to 65% silicon carbide, 10 to 60% alumina, and 5 to 30% bonding medium. A bonding medium is described which is compatible with cubic boron nitride and in one embodiment has an oxide composition comprising about 71% silicon dioxide, 14% by weight boron oxide, about 5% by weight aluminum oxide, and about 10% by weight sodium oxide.

Description: This invention relates to vitrified abrasive articles, particularly to vitreous bonded cubic boron nitride abrasive articles having a core and a rim. It is known to use cubic boron nitride as an abrasive in grinding wheels. The cubic boron nitride preferred in the art has a zinc blend cubic structure with a resulting hardness approaching that of diamond. It is described in U.S.-A- 2,947,617 issued August 2, 1960 to Wentorf. Cubic boron nitride in the form of an abrasive grain referred to as "borazon", is manufactured by the General Electric Co. and is relatively expensive. Notwithstanding its high cost, however, cubic boron nitride is used for grinding metals and other hard materials and is incorporated into metal bonded, organic resin bonded, and vitreous bonded grinding wheels. In the grinding of metals and other hard materials, such as metal carbides, it is highly important that the grinding wheel be strong, resist thermal shock, resist mechanical shock, exhibit low wear, retain its shape, resist being loaded up by the material being ground (be free cutting), have good grinding efficiency and exhibit good metal removal rates. All of these attributes are of particular importance in a grinding operation such as the internal grinding of metal parts. It is, for example, particularly important that in an internal grinding operation, such as the grinding of a bore in a metal part, the grinding wheel maintain its shape and original dimensions for extended periods while exhibiting good strength, good grinding efficiency, and good metal removal rate. Excessive or uneven wear of the grinding wheel causes out of tolerance dimensions and undesirable alteration of the shape of the work piece. These requirements also apply in the contour grinding of metals with preshaped grinding wheels, which requires that the wheel retain its initial shape and dimen­ sions for long periods while having good grinding effi­ ciency and metal removal rate. Similarly, these require­ ments apply in varying degrees, to all types of grinding. For instance, critical retention of grinding wheel shape is not as important as in other types of grinding, but all grinding wheels must exhibit attributes which render them efficient and economical in use. The coefficient of thermal expansion for pre­ shaped grinding wheels used in either interior grinding operations or contour grinding operations must be known so that the grinding article can be intentionally under­ sized in a cold state, so that it will expand to the appro­ priate predetermined size from heat generated during use. Generally, the coefficient of thermal expansion for a grinding wheel consisting of several intimately mixed phases is related to the coefficient of expansion, weight fraction, bulk modulus, and density of each phase. The theoretical relation between these parameters and the average coefficient of thermal expansion are set forth in P.S. Turner "Thermal Expansion Stresses in Reinforced Plastics", J. Research Natl. Bur. Standards, 37[4] 239-50 (1946); RP 1745. One method of incorporating bonded cubic boron nitride in a grinding wheel is to use an organic resin. However, such wheels are not very satisfactory in strenuous, high precision grinding operations, such as internal or contour grinding, because they readily lose their shape and have poor resistance to the high temperature often encountered under strenuous grinding conditions. Examples of resin bonded cubic boron nitride grinding articles are described in U.S.-A-3,576,610 issued April 27, 1971 to Mathewson. Likewise, metal bonded cubic boron nitride grinding wheels have been fabricated, but they are expensive and consequently their use has been confined prin­ cipally to grinding very hard materials such as metal carbide cutting tool elements. Further, metal bonded cubic boron nitride wheels have a high coefficient of thermal expansion, and thus their size and dimensions tend to change during use at varying loads. Metal bonded wheels also have the undesirable quality of loading up with the material being ground, and generally exhibit poor cutting rates. Examples of metal bonded cubic boron nitride articles are disclosed in U.S.-A-3,852,049 issued December 3, 1974 to Hibbs ey al., which teaches the fabrication of a vitreous nitride product having a metal filler. In the past, vitreous bonded cubic boron nitride grinding wheels have had limited success in commercial metal grinding operations. They have proved especially useful where the grinding wheel is subjected to high mechanical and thermal shock and is required to maintain its shape and dimensions over extended periods under strenuous grinding conditions. Typically, these wheels are formed by cold pressing a mixture of cubic boron nitride, silicon carbide, and bonding medium to form the desired article, and then vitrifying said article at elevated temperatures up to about 980°C (1800°F) to form the final product. The bonding medium is chosen to have a coefficient of thermal expansion substantially identical with the cubic boron nitride component to facilitate formation of the vitrified product. However, bond failure with a loss of the cubic boron nitride abrasive grain is the principal cause for the poor performance of vitreous bonded wheels under high thermal and mechanical shock grinding conditions. Additionally, vitreous bonded cubic boron nitride grinding wheels exhibit low grinding efficiency for many types of metal and often require relatively high grinding pressure or force to achieve grinding action thereby aggravating the problems associated with bond failure. Examples of compositions and methods for producing vitreous bonded cubic boron nitride abrasive articles are disclosed in U.S.-A- 3,986,847, issued October 19, 1976 to Balson, which teaches a method of producing a vitreous bonded grinding wheel having a sub­ stantially uniform distribution of cubic boron nitride throughout the article. While fabricated from expensive materials, Balson's wheel is free grinding, can grind at low grinding pressures, has good adhesion between the bond material and the cubic boron nitride so as to resist rapid or premature breaking out of the cubic boron nitride grain with subsequent rapid wear of the wheel and loss of its shape, is resistant to mechanical and thermal shock, and has good grinding efficiency. In light of the relatively high expense of cubic boron nitride, attempts have been made in the prior art to concentrate boron nitride in a wheel's grinding surface or rim. For instance, attempts have been made to attach cubic boron nitride material to the outer surface of a grinding wheel with an eopxy resin. This method has been less than satisfactory because of poor adhesion at high grinding pressures and the resulting high temperatures generated during use. Examples of these methods are disclosed in U.S.-A- 4,385,907 issued May 31, 1983 to Tomita, et al. Similarly, attempts have been made to form vitreous grinding articles with a higher concentration of cubic boron nitride at the article's grinding surface than in its core. Attempts to fabricate such articles have been unsuccessful because of the substantially different coefficients of thermal expansion of cubic boron nitride and other materials used in the articles' cores, such as silicon carbide, alumina, quartz, and other bonding media. Because of differing coefficients of thermal expansion, the rim and core sections of these vitreous articles typically separate during the cooling phase of production, or if separation is not pronounced, have high internal stresses generated at the interface between the rim and core components so that separation or cracking results during use. Consequently, a need exists for an efficient grinding wheel having a core made of less expensive materials and a continuous rim of vitreous bonded cubic boron nitride. A need also exists for a cost effective grinding article having differing rim and core compositions, which is not subject to separation or stresses at the interface between the rim and core. Further, a need exists for a cost effective wheel utilizing inexpensive material for its core, while providing all of the advantages of vitreous cubic boron nitride grinding articles such as resistance to mechanical and thermal shock, ability to be free grinding, and good metal removal rates. Yet a further need exists for a cold pressed product incorporating a rim and core as one body with subsequent firing providing a complete vitreous bonded body composed of two separate compositions. A further need exists for a vitreous glassy bonding medium that is compatible with cubic boron nitride to avoid rapid or premature breaking out of the boron nitride grain, and similarly compatible with a lower cost core composition to provide a totally integrated vitreous bonded article. According to the invention, there is provided a vitrified abrasive article having a core and a rim, wherein said core and rim have substantially equal co­ efficients of thermal expansion, said core comprising a mixture of silicon carbide, alumina and vitrified bonding medium; and said rim comprising a mixture of cubic boron nitride, alumina and vitrified bonding medium. The invention includes a method of making such a vitrified abrasive article, which comprises the steps of: (a) determining the weight percent cubic boron nitride, weight percent alumina and weight percent vitrified bonding medium to be employed in said abrasive article's rim; (b) calculating the coefficient of thermal expansion of said cubic boron nitride, alumina and vitrified bonding medium mixture; (c) calculating the weight percent silicon carbide, weight percent alumina and weight percent vitrified bonding medium to be employed to form a core material having a coefficient of thermal expansion substantially equal to that of the rim material; (d) mixing cubic boron nitride, alumina and bonding medium in said predetermined amounts to form a rim mixture; (e) mixing silicon carbide, alumina and bonding medium in said calculated amounts to form a core mixture; (f) pressing said core mixture with said rim mixture to form a green article wherein said rim mixture is located on said article's outer surface; (g) drying said green article at a temperature of about 66°C (150°F) for from about 12 to 24 hours; and (h) heating said article to an elevated temperature for a period of time sufficient to form a vitrified product. The invention also includes a pressed green article comprising a core and rim, wherein said core comprises: (a) from about 10 to 65% by weight silicon carbide; (b) from about 10 to 60% by weight alumina; (c) from about 5 to 30% by weight bonding medium; (d) from about 1 to 2% by weight binder; and (e) from about 3 to 5% by weight water; and said rim comprises: (f) from about 10 to 70% by weight cubic boron nitride; (g) from about 5 to 60% by weight alumina; (h) from about 15 to 35% by weight bonding medium; (i) from about 1 to 2% by weight binder; and (j) from about 3 to 5% by weight water. The invention further includes a bonding medium compatible with cubic boron nitride, silicon carbide and alumina for use in forming a vitrified grinding article, said medium having an oxide composition comprising: about 71% by weight silicon dioxide; about 14% by weight boron oxide; about 5% by weight aluminum oxide; about 10% by weight sodium oxide. Broadly stated, a preferred composition for forming a cubic boron nitride rim on a silicon carbide core suitable for use in this invention comprises from about 10 to 70% by weight cubic boron nitride, from about 5% to 60% by weight alumina, and from about 15 to 35% by weight bonding medium. A preferred composition for forming cores useful in the present invention comprises from about 10 to 65% by weight silicon carbide, from about 10 to 60% by weight alumina, and from about 5 to 30% by weight bonding medium. The present invention provides a composition and method for forming a bonding medium which is compatible with, and can be used in, both the cubic boron nitride rim and silicon carbide core. In one preferred embodiment, the composi­ tion of the vitreous bond of the present invention has an oxide formulation comprising about 71% by weight silicon dioxide, about 14% by weight boron oxide, about 5% by weight aluminum oxide, and about 10% by weight sodium oxide. However, it will be understood that other bonding medium compositions may be employed. In alternative embodiments, the vitreous bond can also contain lithium oxide, magnesium oxide, calcium oxide, potassium oxide, barium oxide, zinc oxide, or beryllium oxide, for example. Said bonding medium can also include a binding material to permit grinding articles to be cold pressed to form solid "green" prefired articles that can be handled before vitrification without being damaged. In accordance with the method of the present in­ vention, the rim portion of the article is preferably prepared by admixing a uniform mixture of cubic boron nitride and alumina with water, and then combining the admixture with dry bonding medium to form a moist homogeneous granula mixture. Likewise, the core portion is preferably prepared by admixing a uniform mixture of silicon carbide and alumina with water and then combining the admixture with dry bonding medium to form a moist homogeneous granular mixture. The nitride-alumina and carbide-alumina mixtures are placed in a suitable mold with the nitride-alumina component located so as to form the grinding surface of the article and are cold pressed into the form of the desired grinding article. The article is then dried for a period of about 12 to 24 hours at a temperature of about 66°C (150°F), vitrified at elevated temperatures from about 870°C to about 1040°C, and cleaned and inspected to form the abrasive article of the present invention. In accordance with one aspect of the present invention, a composition is provided for forming an abrasive article having a complete vitreous bonded body composed of two separate compositions, wherein the grinding surface rim of said article is comprised of cubic boron nitride, alumina and vitrified bonding medium, and the core of said article is comprised of silicon carbide, alumina and vitrified bonding medium. The abrasive article formed in accordance with the present invention possesses all the advantages of a vitreous bonded cubic boron nitride article such as resistance to thermal shock, resistance to mechanical shock, low wear, retention of shape, resistance to being loaded up by the material being ground, high grinding efficiency, and a high metal removal rate, while being principally composed of low cost ingredients. Further, the vitreous article produced by the method of the present invention possess strength and resistance to mechanical shock superior to those of the vitreous article of the prior art. To form a complete vitreous bonded body composed of two separate compositions, the coefficient of thermal expansion for each composition must be substantially identical to avoid the generation of internal stresses, cracking, or separation during the article's cooling after vitrification. Generally, the average coefficient of thermal expansion for an article consisting of several intimately mixed phases is described by P.S. Turner in "Thermal Expansion Stresses in Reinforced Plastics," J. Research Natl. Bur. Standards, 37[4] 239-50 (1946) as: where: α = the expansion coefficient of the phase P = the weight fraction of the phase K = bulk modulus of the phase d = density of the phase. And for ingredients with approximately the same value for Poisson's ratio, K can be replaced by the modulus of elasticity, E, giving: For cubic boron nitride: a (Per °C) = 4.6 x 10⁻⁶ d = 3600 kg/m³ (0.130 lbs/in³) e = 6.8 x 10⁵ MPa (98.6 x 10⁶ psi) For silicon carbide; a (Per °C) = 4.7 x 10⁻⁶ d = 3360 kg/m³ (0.1213 lbs/in³) e = 4.82 x 10⁵ MPa (70 x 10⁶ psi) For aluminum oxide: a (Per °C) = 8.4 x 10⁻⁶ d = 3990kg/m³ (0.144 lbs/in³) e = 3.62 x 10⁵MPa (52.5 x 10⁶ psi) In one embodiment of the present invention, the composition of the vitreous bond comprises an oxide formulation of about 71% by weight silicon dioxide, about 14% by weight boron oxide, about 5% by weight aluminum oxide, and about 10% by weight sodium oxide. However, it will be further understood that bonding media can also be formulated to result in an oxide formulation also containing calcium oxide, magnesium oxide, lithium oxide, potassium oxide, barium oxide, zinc oxide, or beryllium oxide, for example and that for a typical bonding medium: a (Per °C) = 6.1 10⁻⁶ d = 2310 kg/m³ (0.0833 lbs/in³) e = 7.6 x 10⁴MPa (11 x 10⁶ psi) It will be further understood that for cubic boron nitride, silicon carbide, aluminum oxide, and most bonding media, Poisson's ratio K is approximately equal to the modulus of elasticity E, allowing application of equation (2) to calculate a. The following table sets forth examples of the optimum composition for the core material calculated from Turner's relationship as the weight fraction of cubic boron nitride in the rim increases. In accordance with the present invention, the composition of the green rim material comprises between about 10 to 70% by weight cubic boron nitride, between about 5 to 60% by weight alumina, and between about 15 to 35% by weight bonding medium. The composition of the green core material comprises from between about 10 to 65% by weight silicon carbide, between about 10 to 60% by weight alumina, and between about 5 to 30% by weight bonding medium. It will be understood that while the green rim and core compositions suffer various ignition losses during vitrification the composition of the vitrified product will be substantially identical to that of the green article, and consequently, Turner's relation is applied to the green rim and core compositions to determine the coefficient of thermal expansion for the vitrified rim and core materials. The preferred green rim composition contains about 39 % by weight cubic boron nitride, about 36% by weight alumina, and about 25% by weight bonding medium; and the preferred core composition comprises about 40% by weight silicon carbide, about 40% by weight alumina, and about 20% by weight bonding medium. This composition is preferred because of it's vitrified product's superior performance with most steels under most grinding conditions, however, it will be understood that for every grinding operation there may be a more optimum rim composition to yield superior results. It will be further understood that while the weight percent vitreous bond in either the rim or core may vary between about 5 to 35%, the amount of bond in the rim composition is dictated by the grinding application and the type of metal for which the wheel is specifically designed. For example, some metals require a "hard acting wheel" having a relatively high weight percent of vitreous bond, while other metals require a "soft acting wheel" having a relatively lower weight percent of bond. In utilizing the compositions in accordance with the present invention, the rim composition is formed by admixing particulate cubic boron nitride and particulate alumina with water to form a moist homogenous granular mixture. Generally, about 5 parts by weight water are admixed with about 75 parts by weight nitride - alumina mixture by hand use of a spatula, although a Glen mixer may be used. The bonding medium is dry mixed separately to form a uniform dry powder and said powder is blended with a binder. Generally, about 25 parts by weight dry bond medium are mixed with about 2 parts by weight binder. The preferred binder is sold under the trade name "Dextrin". The dry bond-binder blend is then admixed with the wet nitride-alumina mix by hand with care being taken to remove all lumps and other nonuniform particles. After a thorough mixing, the mixture is further mixed by passing it through a 60 mesh sieve several times in order to form a uniform mixture. The composition of the core section is formed by mixing suitable amounts of silicon carbide and alumina with water to form a moist homogenuous granula mixture. Generally, about 25 parts by weight carbide-alumina mixture are mixed with about one part by weight water in a Glen mixer. Subsequently, a suitable amount of the bond-binder blend is added in a dry form to the wet carbide-­ alumina mixture and is mixed thoroughly to assure that no lumps or other nonuniform particles remain. The mixture is further mixed by passing it through a 60 mesh screen several times to form a uniform mixture. It will be understood that the binder material is employed in both the rim and core compositions to allow these materials to be pressed into a green article that is resistant to damage prior to its vitrification. It will be further understood that to ensure easy and proper mixing of the components at least one part by weight water should be employed for about 10 parts by weight bonding medium in both the rim and core mixtures. The required amounts of core material and rim material are placed in a suitable mold and pressed to form the unfinished article. Generally, the green article will have a core composition comprising from between about 10 to 65% silicon carbide, from between about 10 to 60% alumina, from between bout 5 to 30% bonding medium, from between about 1 to 2% by weight binder, and from between about 3 to 5% by water; and a rim composition comprising from between about 10 to 70% by weight cubic boron nitride, from between about 5 to 60% alumina, from between about 15 to 35% bonding medium, from between about 1 to 2% by weight binder, and from between about 3 to 5% by weight water. The green article is dried for about 12 to 24 hours in a forced air dryer at about 66°C (150°F), is vitrified by firing at a predetermined rate to an elevated temperature between about 870 and 1040°C (1600° and 1900°F), which temperature is maintained for a period of time to allow vitrification, and is then slowly cooled. In accordance with the present invention, the unfinished abrasive article is vitrified by heating the article to a temperature of about 480°C (900°F) over a period of about eight hours, then raising the temperature to between about 870 and 1040°C (1600 and about 1900°F) in about 25 hours, holding the temperature at between about 870 and 1040°C (1600 to 1900°F) for about 6 hours, then cooling the article to about 760°C (1400°F) in about 6 hours, then further cooling the article to about 590°C (1100°F) in about 10 hours, the cooling to a temperature of about 38°C (100°F) over 18 hours. However, it will be understood that different time temperature profiles may be used to obtain satisfactory vitrification of green articles, and that large articles require both slow heating and cooling rates to prevent thermal cracking, while smaller articles can be heated and cooled at faster rates without the danger of cracking. Various advantages of the invention are apparent from the following examples and it will be understood that the following examples are presented to illustrate this invention and are not intended as any limitation thereof. EXAMPLE 1 A grinding article having a rim composition of 39% by weight cubic boron nitride, 36% by weight alumina and 25% by weight vitrous bond is desired. By the relation described by Turner, the coefficient of thermal expansion for such a rim composition is calculated to be 5.8 X 10⁻⁶ per °C. To form an abrasive article having a complete vitreous bonded body composed of two separate compositions, the core composition must have a coefficient of thermal expansion substantially equal to 5.8 X 10⁻⁶ per °C to avoid the generation of internal stresses, cracking, and/or separation of the rim and core at their interface during cooling after vitrification. Consequently, the coefficient of thermal expansion is set to be 5.8 X 10⁻⁶ per °C and using Turner's relationship the weight percents of silicon carbide, alumina and vitrous bond in the core are calculated to be 45.2%, 29.8% and 25% respectively. EXAMPLE 2 A grinding article having a rim composition of 39% by weight cubic boron nitride, 36% by weight alumina and 25% by weight vitrous bond is desired. The desired bonding medium has an oxide composition of about 71% by weight silicon dioxide, about 14% by weight boron oxide, about 5% by weight aluminum oxide, and about 10% by weight sodium oxide, and a coefficient of thermal expansion of 6.1 x 10⁻⁶ per degree C. By the relation described by Turner, the coefficient of thermal expansion for the rim composition is calculated. The core formulation is desired to have substantially equal amounts of silicon carbide and alumina, and applying the desired coefficient of thermal expansion to Turner's relation the core composition is calculated to be about 42.1% by weight silicon carbide, about 42.1% by weight alumina, and about 15.8% by weight vitreous bond. To form the rim portion of the desired article, the cubic boron nitride is thoroughly mixed in a dry state with the alumina. The boron nitride used is 170/200 grit ("Borozon 550") and the alumina is 180 grit. These materials are thoroughly admixed with water by hand with a pallet knife to form a paste. The bonding medium is mixed with dry Dextrin binder and the bond-binder powder is slowly added to the nitride-alumina paste with a pallet knife. The mixture is further mixed by passing it through a 60 mesh screen at least two times to form a uniform mixture comprised as follows: Cubic Boron Nitride 36.43% by weight Alumina 33.66% by weight Bonding medium 23.36% by weight Dextrin 1.87% by weight Water 4.68% by weight The core portion of the desired abrasive article is formed by thoroughly mixing the silicon carbide with the alumina in a dry state. The silicon carbide and alumina used are both 220 grit. Water is then admixed with the carbide-alumina mixture to form a paste. These materials are thoroughly mixed in a Glen mixer at 80 rpm for about 3 minutes. The bonding medium is mixed with dry Dextrin binder and the bond-binder powder is slowly added to the silicon carbide-alumina paste in the Glen mixer. The mixer is set at about 20 rpm, the mixing performed slowly to assure that no lumps or other unmixed material remain. When the dry bond-binder mixture is completely delivered to the Glen mixer all ingredients are then mixed at about 30 rpm for about 4 minutes, with care being taken to scrape down the sides of the bowl to assure thorough mixing. The mix is then screened through a 60 mesh screen at least two times to ensure thorough mixing to form a uniform mixture comprised as follows: Green Silicon Carbide 40.00% by weight Alumina 40.00% by weight Bonding medium 15.00% by weight Dextrin 1.50% by weight Water 3.50% by weight The rim and core mixtures are placed in a suitable mold located in a press with care being taken so that the rim mixture is located in the mold to form the outside surface of the desired grinding wheel, and are pressed to form a green wheel of the desired shape and size. The green wheel is set on a ceramic batt and placed in a drying oven overnight at about 66°C (150°F). After drying, the wheel is fired at a temperature of about 38°C (100°F), said temperature being raised to about 480°C (900°F) over a 8 hour period, raised to about 950°C (1750°F) in about 25 hours and held constant at about 950°C (1750°F) for about 6 hours, cooled to about 760°C (1400°F) in 6 hours cooled to about 590°C (1100°F) in 10 hours, and further cooled to 38°C (100°F) in about 18 hours. The vitrified wheel is hand reamed using an abrasive maul, trued under wet grinding conditions and inspected for cracks. EXAMPLE 3 An abrasive article having a rim composition of 58% by weight cubic boron nitride, 14.5% by weight alumina and 27.5% by weight vitrous bond is desired. The bonding medium has an oxide composition of about 71% by weight silicon dioxide, about 14% by weight boron oxide about 5% by weight aluminum oxide, and about 10% by weight sodium oxide, and a coefficient of thermal expansion of 6.1 x 10⁻⁶ per degree C. Using Turner's relation the coefficient of thermal expansion for the rim formulation is calculated and the resulting core formulation is about 63% by weight silicon carbide, about 21% by weight alumina, and about 16% by weight vitreous bond. The green rim material is formed by mixing the appropriate amounts of cubic boron nitride, alumina, bonding medium, dextrin, and water in accordance with the procedure set forth in example 2 to yield the following composition: Cubic Boron Nitride 53.94% by weight Alumina 13.45% by weight Bonding medium 25.63% by weight Dextrin 1.86% by weight Water 5.12% by weight The green core material is formed by mixing the appropriate amounts of green silicon carbide, alumina, bonding medium, dextrin, and water in accordance with the procedure in example 2 to form the following composition: Green Silicon Carbide 60.00% by weight Alumina 20.00% by weight Bonding medium 15.00% by weight Dextrin 1.50% by weight Water 3.50% by weight The rim and core materials are placed in a mold located in a press and are pressed to form a green wheel as described in Example 2. The green wheel is fired, cooled, reamed, trued, and inspected in accordance with a procedure set forth in Example 2 to yield a vitrified grinding wheel. EXAMPLE 4 A grinding article having a rim composition of 19% by weight cubic boron nitride, 56.5% by weight alumina and 24.5% by weight vitrous bond is desired. The bond medium has an oxide composition of about 71% by weight silicon dioxide, about 14% by weight boron oxide, about 5% by weight aluminum oxide, and about 10% by weight sodium oxide, and a coefficient of thermal expansion of 6.1 x 10⁻⁶ per degree C. Using Turner's relation, the coefficient of thermal expansion of the rim composition is calculated and the core composition is determined to be about 23% by weight silicon carbide, about 52.5% by weight alumina, and about 24.5% vitreous bond. The rim material is formed by mixing cubic boron nitride, alumina, vitreous bond, dextrin, and water in the appropriate amounts pursuant to the procedure set forth in Example 2 to yield the following composition: Cubic Boron Nitride 17.88% by weight Alumina 52.72% by weight Bonding medium 22.93% by weight Dextrin 1.87% by weight Water 4.60% by weight The green core material is formed by mixing silicon carbide, alumina, vitreous bond, dextrin and water in the appropriate amounts as per the procedure set forth in Example 2, yielding the following composition: Silicon Carbide 21.61% by weight Alumina 49.00% by weight Bonding medium 22.91% by weight Dextrin 1.87% by weight Water 4.61% by weight The rim and core compositions are placed in a suitable mold located in a press and pressed to form a green wheel. The green wheel is then fired, cooled, reamed, trued, and examined in accordance with the procedure set forth in Example 2 to yield a vitrified grinding wheel. EXAMPLE 5 A grinding article having a rim composition of about 39% by weight cubic boron nitride, about 36% by weight alumina, and about 25% by weight vitreous bond is desired. A bonding medium is chosen to have an oxide composition of about 52.5% by weight silicon dioxide, about 36.3% by weight boron oxide, about 1.0% by weight aluminum oxide, about 2.9% by weight calcium oxide, and about 7.3% by weight sodium oxide, having a coefficient of thermal expansion of about 6.3 x 10⁻⁶ per degree C. The corresponding core composition is 42.1% by weight silicon carbide, 42.1% by weight alumina, and 15.8% by weight vitreous bond as per Turner's relation. The green rim material is formed by mixing appropriate amounts of cubic boron nitride, alumina, bonding medium, dextrin and water pursuant to the procedure set forth in Example 2. Likewise, the green core material is formed by mixing silicon carbide, alumina, bonding medium, dextrin and water pursuant to the procedure set forth in Example 2. The green rim and core materials are placed in a suitable mold located in a press and pressed to form a green wheel. The green wheel is fired in accordance with the procedure set forth in Example 2 with the exception that the maximum firing resulting article is cooled, reamed, trued, and inspected to yield a vitrified grinding article having a rim composition of about 39% by weight cubic boron nitride, about 36% by weight alumina and about 25% by weight vitrous bond. EXAMPLE 6 Five vitrified grinding wheels were fabricated in accordance with the composition and method set forth in Example 2, and five bars having dimensions of 5.9mm by 13.65mm by 25.4mm (0.234 inches by 0.5375 inches by 1.00 inch) were cut from the cores of the wheels. The bars were broken in three point bending on an Instron Universal Testing machine at a rate of 1.27mm (0.05 inches) per minute. The breaking loads were recorded and used to calculate the strength of each bar. Likewise, similar bars were cut from cores of a commercially available vitreous bonded cubic boron nitride grinding wheel and were broken, the breaking point load recorded and used to calculate the strength of the core of the commercially available material. The results of these tests are set forth below: In comparing the data reflected in the above table, it is seen that the average breaking strength of the vitrified core of the present material is 58.2 MPa (8449 psi) while the average breaking strength of the vitrified core material of the prior art is 37.7 MPa (5473 psi), reflecting that the core material of the present invention is about 54% stronger than the core material of the prior art. EXAMPLE 7 A vitreous bonded cubic boron nitride grinding wheel was made according to the composition and method set forth in Example 3, and was compared in grinding tests to a commercially available vitreous bonded cubic boron nitride grinding wheel in the surface grinding of M2 steel hardened to Rockwell C58 hardness. The test condi­ tions were as follows: Wheel size: 152.4 x 6.35 x 31.75mm (6 x 0.25 x 1.25 inches) Work size: 76.2 x 152.4mm (3 x 6 inches) Wheel speed: 3600 r.p.m. Table speed: 15.24m (50 ft) per minute Coolant: a solution of 15% commercially available water soluble oil and 85% water Downfeed: .0254mm (0.001 inch) per pass The present invention's vitreous bonded cubic boron nitride grinding wheel's volumetric efficiency was 493, and the commercially available vitreous bonded cubic boron nitride grinding wheel's volumetric efficiency was about 72, where "volumetric efficiency" is the ratio of the amount of steel removed to the amount of grinding wheel removed. EXAMPLE 8 A vitreous bonded cubic boron nitride grinding wheel is made in accordance the composition and method set forth in Example 3, and was compared to a commercially available vitreous bonded cubic boron nitride grinding wheel in the surface grinding of T15 steel hardened to Rockwell C68 hardness. The wheel size and tests conditions were the same as recited in Example 7. The present invention's vitreous bonded cubic boron nitride grinding wheel's volumetric efficiency of 108, and the commercially available wheel's efficiency was about 50. EXAMPLE 9 A vitreous bonded cubic boron nitride grinding wheel was made in accordance to the composition and method set forth in Example 5, and was compared to a commercially available vitreous bonded cubic boron nitride grinding wheel in the surface grinding of M2 steel hardened to Rockwell C58 hardness. The wheel size and test conditions were the same as set forth in Example 7. The present invention's vitreous bonded cubic boron nitride grinding wheel's volumetric efficiency was 178, and the commercially available wheel's volumetric efficiency was about 72. EXAMPLE 10 A vitreous bonded cubic boron nitride grinding wheel was made in accordance to the composition and method of Example 5, and was compared to a commercially available vitreous bonded cubic boron nitride wheel in the surface grinding of T15 steel hardened to Rockwell C63 hardness. The wheel size and test conditions were the same as set forth in Example 7. The present invention's vitreous bonded cubic boron nitride grinding wheel's volumetric efficiency was 63, and the commercially available grinding wheel's volumetric efficiency was about 50. EXAMPLE 11 A vitreous bonded cubic boron nitride grinding wheel was made in accordance to the composition and method of Example 2, and was compared to commercially available concentrational grinding wheels in the internal plunge grinding of gas turbine combustion housings. The following conditions were employed: Wheel size: 152.4 x 19.05 x 25.4mm (6 x 0.75 x 1.00 inches) Work size: 304.8mm (12.00 inch) inner diameter Wheel speed: 2591 surface metres (8500 surface feet) per minute Coolant: Commercially available water soluble oil Metal Removal: 8.89mm (0.350 inches) The average grinding time was reduced from 5 hours for the conventional vitrified grinding wheel to 20 minutes for the vitrified cubic boron nitride grinding wheel of the present invention. EXAMPLE 12 A vitrified bonded cubic boron nitride grinding wheel was made in accordance with the composition and method of Example 2, and compared to commercially available vitreous bonded cubic boron nitride grinding wheels in the internal bore grinding of M50 steel hardened to Rockwell C62 hardness. The following conditions were employed: Wheel size: 63.5 x 11.33 x 15.88mm (2.5 x 0.446 x 0.625 inches) Work size: 101.6 ID by 15.88mm width (4.00 ID by 0.625 width inches) Wheel speed: 2896 surface metres (9500 surface feet) per minute Coolant: Commercially available water soluble oil The vitreous bonded cubic boron nitride grinding wheel of the present invention decreased the grinding cycle time from approximately 3.2 minutes to 2.75 minutes, produced a better surface finish and better size control with no heat generation. While the present invention has been described with respect to preferred embodiments, it will be understood that the invention is capable of numerous rearrangements, modifications and alterations.

Claims: 1. A vitrified abrasive article having a core and a rim, wherein said core and rim have substantially equal coefficients of thermal expansion, said core comprising a mixture of silicon carbide, alumina and vitrified bonding medium; and said rim comprising a mixture of cubic boron nitride, alumina and vitrified bonding medium. 2. A vitrified abrasive article according to claim 1, wherein said core comprises: (a) from 10 to 65% by weight silicon carbide; (b) from 10 to 60% by weight alumina; and (c) from 5 to 30% by weight vitrified bonding medium; and said rim comprises: (d) from 10 to 70% by weight cubic boron nitride; (e) from 5 to 60% by weight alumina; and (f) from 15 to 35% by weight vitrified bonding medium. 3. A vitrified abrasive article according to claim 2, wherein the core comprises: (a) about 42% by weight silicon carbide; (b) about 42% by weight alumina; and (c) about 16% by weight vitrified bonding medium; and the rim comprises: (d) about 39% by weight cubic boron nitride; (e) about 36% by weight alumina; and (f) about 25% by weight vitrified bonding medium. 4. A vitrified abrasive article according to claim 1,2 or 3, wherein said vitrified bonding medium comprises either (1) about 71% by weight silicon oxide; about 14% by weight boron oxide; about 5% by weight aluminum oxide; and about 10% by weight sodium oxide; or (2) about 53% by weight silicon oxide; about 36% by weight boron oxide; about 3% by weight calcium oxide; about 1% by weight aluminum oxide; and about 7% by weight sodium oxide. 5. A method of forming a vitrified abrasive article according to claim 1, comprising the steps of: (a) determining the weight percent cubic boron nitride, weight percent alumina and weight percent vitrified bonding medium to be employed in said abrasive article's rim; (b) calculating the coefficient of thermal expansion of said cubic boron nitride, alumina and vitrified bonding medium mixture; (c) calculating the weight percent silicon carbide, weight percent alumina and weight percent vitrified bonding medium to be employed to form a core material having a coefficient of thermal expansion substantially equal to that of the rim material; (d) mixing cubic boron nitride, alumina and bonding medium in said predetermined amounts to form a rim mixture; (e) mixing silicon carbide, alumina and bonding medium in said calculated amounts to form a core mixture; (f) pressing said core mixture with said rim mixture to form a green article wherein said rim mixture is located on said article's outer surface; (g) drying said green article at a temperature of about 66°C (150°F) for from about 12 to 24 hours; and (h) heating said article to an elevated temperature for a period of time sufficient to form a vitrified product. 6. A method according to claim 5, wherein said bonding medium is mixed with a binder material to allow said core and rim mixtures to be pressed to form a green article that is resistant to damage prior to firing. 7. A method according to claim 5 or 6, wherein said heating step comprises heating the dry green article to a temperature of from about 870° to 1040°C (1600° to 1900°F) for a period of time sufficient to form a vitrified product. 8. A method according to claim 5,6 or 7, wherein said heating step comprises: heating the dry green article to a temperature of about 480°C (900°F) in about 8 hours; raising said temperature from about 480°C (900°F) to about 950°C (1750°F) in about 25 hours; holding said temperature substantially equal to about 950°C (1750°F) for about 6 hours; lowering said temperature from about 950°C (1750°F) to about 760°C (1400°F) in about 6 hours; lowering said temperature from about 760°C (1400°F) to about 590°C (1100°F) in about 10 hours; and lowering said temperature from about 590°C (1100°F) to about 40°C (100°F) in about 18 hours. 9. A bonding medium compatible with cubic boron nitride, silicon carbide and alumina for use in forming a vitrified grinding article, said medium having an oxide composition comprising: about 71% by weight silicon dioxide; about 14% by weight boron oxide; about 5% by weight aluminum oxide; about 10% by weight sodium oxide. 10. A pressed green article useful for forming a vitrified grinding article as claimed in claim 2, said green article comprising a core and rim, wherein said core comprises: (a) from about 10 to 65% by weight silicon carbide; (b) from about 10 to 60% by weight alumina; (c) from about 5 to 30% by weight bonding medium; (d) from about 1 to 2% by weight binder; and (e) from about 3 to 5% by weight water; and said rim comprises: (f) from about 10 to 70% by weight cubic boron nitride; (g) from about 5 to 60% by weight alumina; (h) from about 15 to 35% by weight bonding medium; (i) from about 1 to 2% by weight binder; and (j) from about 3 to 5% by weight water. 11. A pressed green article useful for forming a vitrified grinding article according to claim 1, said green article comprising a core and rim, wherein said core comprises: (a) about 40% by weight silicon carbide; (b) about 40% by weight alumina; (c) about 15% by weight bonding medium; (d) about 2% by weight binder; and (e) about 3% by weight water; and said rim comprises: (f) about 36% by weight cubic boron nitride; (g) about 34% by weight alumina; (h) about 23% by weight bonding medium; (i) about 2% by weight binder; and (j) about 5% by weight water.

Inventors: MAKHLOUF, MAKHLOUF M., SCHUSTER, THOMAS R.
Applicants: ABRASIVE INDUSTRIES, INC.
Application year: 1987
Main classification: B24D3
IPC codes: B24D3, B24D18