Method for manufacturing agglomerates of fired pellets

Abstract: A method for manufacturing agglomerates of fired pellets comprising the steps of: the first pelletization step of adding and mixing fluxes to fine iron ores containing 30 to 95 wt.% of those of 0.125mm or less in particle size to form a mixture and to pelletize the mixture into green pellets; the second pelletization step of adding powder cokes containing 80 to 100 wt.% of those of 1 mm or less in paricle size to the green pellets, in amount of 2.5 to 4.0 wt.% to the fine iron ores, to prepare, through pelletization, green pellets coated with the powder cokes; and the sintering step of charging the green pellets coated with the powder cokes into a grate type sintering machine to manufacture the agglomerates of fired pellets. And furthermore, in another method for manufacturing agglomerated of fired pellets, fine iron ores containing 10 to 80 wt.% of those of 0.044mm or less in particle size and powder cokes containing 20 to 70 wt.% of those of 1mm or less in particle size are used.

Description: The present invention relates to a method for manufacturing agglomerates of fired pellets having different particle sizes fitted for materials used for a blast furnace or a direct reduction furnace, and more particularly, to conditions on materials used for manufacture of the agglomerates of fired pellets and conditions on pelletization of the materials. As materials used for a blast furnace or a direct reduction furnace, agglomerates of fired pellets, which are made from fine iron ores by pelletization and by sintering are well known. Consumption of these fired pellets are increasing in amount year by year, various research and development on these fired pellets has been performed. For example, a method is disclosed in a Japanese Patent Application Laid Open (KOKAI) No. 106728/86 to which a U.S. Patent Application Serial No. 769624 corresponds, wherein: (a) To fine iron ores mainly composed of those of 5mm or less in particle size, fluxes are added, and the fine iron ores are pelletized, as the first step pelletization, into green pellets; (b) the green pellets are coated on their surface, as the second step pelletization, with solid fuels such as powder cokes, powder chars, fine powder coals and powder oil cokes to prepare mini-pellets of 3 to 9mm in particle size, providing that the addition ratio of the solid fuels is 2.5 to 3.5 wt.% to the fine iron ores; (c) the mini-pellets are sintered, through a grate type sintering machine equipped with zones for drying, igniting, sintering and cooling, to prepare blocky agglomerates of mini-pellets; (d) the agglomerates of mini-pellets manufactured by sintering are composed of mini-pellets combined on their surface through work of calcium ferrite. This method, however, allows the following difficulties to remain still unsettled; (1) The yield is low, and, consequently, the productivity is low. (2) The strength of the agglomerates of mini-pellets is not satisfactory for the operation of a blast furnace and a direct reduction furnace. EP-A-0207654 is a post-published document and discloses a process of continuously manufacturing fired pellets according to which, to raw materials comprising iron ores, a powdery flux is added which comprises at least one of quick lime, slaked lime, limestone and dolomite, to form a mixture, and said mixture is formed into green pellets. In the next step, the surfaces of said green pellets are covered with a powdery solid fuel and the resulting pellets are finally sintered. According to a preferred embodiment, the surfaces of the firstly prepared green pellets are covered with a mixture of said powdery solid fuel and a powdery flux. However, there is no description and no indication to produce agglomerates of fired pellets having different particle sizes. AU-B-474.957 defines a process of making a coated pellet wherein a pellet is coated with a coke precursor and the coated pellet is heated under cooking conditions The coke precursor may comprise a coking coal in admixture with inerts (coke, coal charts, graphite). The process of producing the coated pellets does not comprise the steps of a first and a second pelletization. As can be taken from Example 1, pellets are formed after thoroughly mixing the iron or/and coal components. The layer of coal is provided by successive wettings and powder additions. In addition, the known process does not provide for a possibility for screening the green pellets (after the first pelletization) into separate groups according to their particle sizes. In US-A-4042375 a roasting process for the direct reduction of ores containing iron oxides is described. The core pellets are formed which consist essentially of finely ground ore and a solid carbonaceous material. The core pellets are then coated with a coke precursor and are heated in a substantially non-oxidizing atmosphere to cause the coke precursor to form a coke skin around the coke pellets. The coke precursor comprises from 5 to 25% of a halide salt chosen from the group consisting of chlorides, alkaline earth metal chlorides, fluorides and ammonium chlorides. The pellets may be made using normal pelletizing apparatus. In a typical pelletizing process the ore is pelletized with water to form green pellets, whereafter said green pellets are coated with a layer of coke precursor mixture. A second pelletization is not provided to effect coating by pelletizing. In fact, the coating is provided by successive wettings and powder additions. In addition, the step of screening the green pellets into separate groups according to their particle sizes is not described or suggested. JP-A-56163225 describes the production of lump steel. The raw materials are granulated in a first pelletizer and the pellets are transferred into a second pelletizer, where the green pellets are covered with coal and silica powder. Then, the pellets are sintered to obtain the lump steel. However, there is no description and no suggestion as to the screening of the green pellets into separate groups according to their particle sizes. It is an object of the present invention to provide a method for manufacturing agglomerates of fired pellets having different particle sizes, enabling the productivity to be good enough and the strength to be strong enough for the operation of a blast furnace and a direct reduction furnace. In accordance with the present invention, a method is provided for manufacturing agglomerates of fired pellets comprising the steps of: Adding fluxes including quick limes to fine iron ores, 30 - 95 wt.% of fine iron ores having a particle size of 0.125 mm or less, and the amount of quick limes being 1.0 to 2.5 wt.% based on the weight of fine iron ores; mixing the fluxes and fine iron ores to produce a mixture; pelletizing the mixture into green pellets; screening the green pellets having a particle size of 3 to 13 mm into at least two separate groups according to the particle size; separately adding powder cokes to each of the at least two separate groups of screened pellets in an amount of 2.5 to 4.0 wt.% based on the weight of the fine iron ores in the green pellets, 80 to 100 wt.% of the powder cokes having a particle size of 1 mm or less; pelletizing the at least two separate groups of screened green pellets and powder cokes to produce at least two groups of screened green pellets coated with powder cokes, the powder cokes being added to the at least two separate groups of screened green pellets such that a larger proportion by weight of powder cokes is added to green pellets having a larger particle size; charging the at least two groups green pellets coated with powder cokes into a grate type sintering machine; and sintering the green pellets coated with powder cokes into agglomerates of fired pellets, said agglomerates containing 0.5 to 5.0 wt.% of SiO 2 . The object and the other objects and advantages of the present invention will become more apparent from the detailed description to follow, taken in conjunction with the appended drawings. Fig. 1 is a graphic representation showing relation of blend ratio of 0.125mm or less fine iron ores contained in those used of 8mm or less in particle size, to reduction index of obtained agglomerates of fired pellets, according to a method of the present invention; Fig. 2 is a graphic representation showing relation of blend ratio of 0.125mm or less fine iron ores contained in those used of 8mm or less in particle size, to shatter index of the obtained agglomerates of fired pellets, according to the method; Fig. 3 is a graphic representation showing relation of blend ratio of lmm or less powder cokes contained in those, used for coating green pellets, of 5mm or less in particle size, to yield of the obtained agglomerates of fired pellets, according to the method; Fig. 4 is a graphic representation showing relation of blend ratio of 1mm or less powder cokes contained in those of 5mm or less in particle size, to productivity of the obtained agglomerates of fired pellets, according to the method; Fig. 5 is a graphic representation showing relation of quick lime addition amount to fine iron ores, to yield of the obtained agglomerates of fired pellets, according to the method; Fig. 6 is a graphic representation showing relation of quick lime addition amount to fine iron ores, to the shatter index, according to the method; Fig. 7 is a graphic representation showing relation of blend ratio of 5mm or less green pellets in particle size contained in those used, to the yield, according to the method; Fig. 8 is a graphic representation showing relation of blend ratio of 5mm or less green pellets contained in those used, to the productivity, according to the method; Fig. 9 is a graphic representation showing relation of blend ratio of 5mm or less green pellets contained in those used, to the shatter index, according to the method; Fig. 10 is a graphic representation showing relation of SiO 2 content in the obtained agglomerates of fired pellets, to reduction index of the obtained agglomerates of fired pellets, according to the method; Fig. 11 is a graphic representation showing relation of SiO 2 content in the obtained agglomerates of fired pellets, to reduction degradation index, according to the method; Fig. 12 is a graphic representation showing relation of SiO 2 content in the obtained agglomerates of fired pellets, to the shatter index according to the method; Fig. 13 is a graphic representation showing relation of SiO 2 content in the manufactured agglomerates of fired pellets, to the yield, according to the method; Fig. 14 is a schematic flow chart showing further another example of the process. Detailed description of the invention Now, the method for manufacturing fired pellets of the present invention will be described. 1.0 to 2.5 wt.% quick limes were added and mixed, as a flux, to fine iron ores containing 30 to 95 wt.% of those of 0.125mm or less in particle size. Subsequently, a mixture thus prepared, was pelletized, by means of a disc type pelletizer, into 3 to 13mm green pellets (the first pelletization). Further, powder cokes containing 80 to 100 wt.% of those of 1mm or less in particle size were added to the green pellets, in amount of 2.5 to 4.0 wt.% to the fine iron ores, and the green pellets were pelletized again, by means of a drum type pelletizer into the green pellets coated with the powder cokes (the second pelletization). The green pellets coated with the powder cokes were charged into a grate type sintering machine to manufacture agglomerates of fired pellets composed of fired pellets combined in plurality. Terms "Reduction index", "shatter index" and "reduction degradation index" herein contained, have meanings as defined herebelow throughout in this specification. (1) Reduction index (RI): The reduction index was measured by a method specified in JIS (Japanese Industrial Standards), which comprises: reducing the fired pellets in an amount of 500g charged into an experimental electric furnace by means of a reducing gas comprising 30 vol.% CO and 70 vol.% N 2 at a temperature of 900°C for 180 minutes, and measuring the reduction index of the fired pellets. (2) Shatter index (SI +5 ): The shatter index was measured by a method specified in JIS, which comprises: dropping the fired pellets in an amount of 20 Kg four times from a height of 2 m onto an iron plate, sieving the thus dropped fired pellets through a 5-mm mesh screen, and measuring the ratio of particles on the screen. (3) Reduction degradation index (RDI): The reduction degradation index was measured by a method specified by the Ironmaking committee of the Iron and Steel Institute of Japan, which comprises: reducing the fired pellets in an amount of 500g charged into an experimental electric furnace by means of a reducing gas comprising 30 vol.% CO and 70 vol.% N 2 at a temperature of 550°C for 30 minutes, receiving the thus reduced fired pellets in a drum, rotating the drum by 900 revolutions, sieving the.fired pellets taken out from the drum through a 3-mm mesh screen, and measuring the ratio of particles under the screen. Particle Size of Fine Iron Ores Particle size of fine iron ores will be described in detail herebelow. The following conception occurred to those engaged in research and development: (A) If blend ratio of powdery fine iron ores increases and fine iron ores to be used become smaller on average in particle size, then reduction index of fired pellets will be increased because many macro-pores are formed in each body of the fired pellets to be obtained when the fine iron ores are pelletized into green pellets. (B) If fluxes are added to fine iron ores and the fine iron ores are pelletized into green pellets, then agglomerates of fired pellets will be strengthened in their shatter index because the green pellets, thus pelletized into, become high both in strength and density. Based on this conception, an experiment was carried out wherein blend ratios of fine iron ores having various distribution of their particle sizes were varied to pelletize green pellets into agglomerates of fired pellets, and reduction indexes and shatter indexes of the agglomerates of fired pellets were checked. Fig. 1 of the drawing shows graphically relation of blend ratio of 0.125mm or less fine iron ores contained in those of 8mm or less in particle size, to reduction index of obtained agglomerates of fired pellets. Fig. 2 graphically shows relation of blend ratio of 0.125mm or less fine iron ores included in those of 8mm or less in particle size, to shatter index of the obtained agglomerates of fire pellets. As shown in Fig. 1, because macro-pores contained in each body of fired pellets increase as the blend ratio of 0.125mm or less in particle size are increasing, reduction index of the agglomerates of fired pellets is improved. When the blend ratio of fine iron ores is 30 wt.% or more, the reduction index is high enough to be well more than 75%. As shown in Fig. 2, if the blend ratio of 0.125mm or less fine iron ores is 30 wt.% or more, the density and strength of the green pellets are increased so high as to allow the shatter index of the obtained agglomerates of fired pellets to show more than 85%. However, if the blend ratio becomes 95 wt.% or more, green pellets get apt to be melted through excessive heating and to form glassy slag, this resulting in rapid deterioration of the shatter index. From the results of the experiment, it became apparent that if powder iron ores consisting of 30 to 95 wt.% of those of 0.125mm or less in particle size and of the rest of those more than 0.125mm are used, then the reduction index and the shatter index of the agglomerates of fired pellets will be preferably by far improved. The range of 50 to 95 wt.% of powder iron ores of 0.125mm or less is more preferable. Powder Cokes Powder cokes to be added at the step of the second pelletization will now be explained about. The concept thereof was made as shown herebelow. (A) If particle size becomes relatively fine, powder cokes will be allowed to coat the surface of green pellets fully and uniformly. (B) If the green pellets are sintered, in good condition, in a sintering machine, improvement in yield and productivity of the fired pellets will be able to be attained. According to this way of thinking, an experiment was carried out, wherein green pelles were coated with various particle sizes of powder cokes and various blend ratios thereof to manufacture agglomerates of fired pellets, and shatter indexes and productivities of the agglomerates of fired pellets corresponding to the variation were checked. Fig. 3 graphically shows relation of blend ratio of 1mm or less powder cokes contained in those of 5mm or less in particle size, to the yield of the obtained agglomerates of fired pellets. Fig. 4 graphically shows relation of blend ratio of lmm or less powder cokes contained in those of 5mm or less in particle size, to the shatter index of the obtained agglomerates of fired pellets. In this experiment, fine iron ores having a particle size of 8mm or less were used. The green pellets were of 3 to 13mm in particle size, and the powder cokes were added in amount of 3.5 wt.%. As seen from Fig. 3, the more the blend ratio of 1mm or less powder cokes becomes, the better green pellets get coated and sintered, this resulting in improving the yield. If the blend ratio is 80 wt.% or more, the yield is high enough to show 75% or more. As seen from Fig. 4, the productivity also increases, as the blend ratio is going up. In the range of 80 wt.% or more of the blend ratio, the productivity is good enough to mark 1.5 T/H/M 2 or more. Consequently, the blending ratio of lmm or less powder cokes ranges preferably 80 to 100 wt.%. To further improve the yield and the productivity, it is more preferable to keep the blending ratio of lmm or less powder cokes in the range of 90 to 100 wt.%. The amount of powder cokes for coating the green pellets are recommended to be 2.5 to 4.0 wt.% to the amount of fine iron ores. If the amount of the powder cokes for coating is less than 2.5 wt.%, it is impossible to sinter the green pellets into fired pellets of high shatter index in a short time, namely, efficiency in sintering the green pellets in a sintering machine cannot be raised. Contrarily, if the amount of the powder cokes for coating is over 4.0 wt.%, the temperature at the time of sintering the green pellets rises excessively so high that the agglomerates of fired pellets become too dense in their texture. The Second Pelletization The reasons for a drum type pelletizer being preferably fitted for coating green pellets with powder cokes will be explained herebelow. In a pelletizer of drum type, its inclined drum rotates and, therefore, green pellets can be pushed out, almost equally regardless of thier particle sizes, through the end of the drum. Consequently, the green pellets are discharged almost without difference in their retention time in the pelletizer. Due to this performance, in a case, for example, that 3 to 13mm green pellets in particle size are coated with powder cokes, the green pellets are allowed to be successfully covered without dispersion of coating amount. Even in the case of using large size green pellets, there is no shortage of coating amount. Therefore, even in the lower layer portion where larger green pellets in particle size are easy to gather when charged into a sintering machine, the sintering works so well that there is no occurence of deterioration either in yield of the agglomerates of fired pellets, or in productivity due to prolonging sintering time. If powder cokes are coated with by means of a disc type pelletizer which is customarily used, time during which green pellets stay in the disc pelletizer is different, depending on their particle sizes. Due to the difference of the retention time, coating amount of power cokes per unit weight of green pellets are dispersed, and, thus, shortage of coating amount covering green pellets occurs. Owing to this, in the lower layer portion which is easy to allow large size green pellets to gather in charging them into the sintering machine, the sintering does not work well. This results in deterioration either in yield of the agglomerates fired pellets or in productivity thereof because of sintering time becoming longer. Addition of Quick Limes. According to the method of the present invention, fine iron ores were pelletized by use of a disc type pelletizer and only with addition of fluxes, and, thereafter, coating with powder cokes was made. From this performance, it became apparent that this method was so good for pelletization of fine iron ores that green pellets could be obtained from fine iron ores with addition of quick limes in small amount. But, owing to this addition amount being small, there remained the possibility of deteriorating the yield and the shatter index. In this connection, an experiment was carried out wherein various amount of quick limes were added to manufacture fired pellets by means of sintering green pellets pelletized through the addition of quick limes to fine iron ores. Fig. 5 graphically shows relation of quick lime addition amount to fine iron ores, to yield of the agglomerates of fired pellets. Fig. 6 graphically shows relation of quick lime addition amount to shatter index of the agglomerates of fired pellets. In this experiment, fine iron ores having a particle size of 8mm or less were used The green pellets were of 3 to 13mm in particle size, and powder cokes were added in amount of 3.5 wt.%. As shown in Fig. 5, the more the addition amount of quick limes to fine iron ores increases, the better the yield of the obtained agglomeretes of fired pellets is improved. When the addition amount is 1.0 wt.% or more, the yield marks 75% or more. In the case that the addition amount is over 2.5 wt.%, it can be admitted that the yield becomes 85% or more, but the growth of the yield is smaller in proportion, i.e. the increase of quick lime addition amount, after all, extends aspects of demerits. As recongnized from Fig. 6, as the addition amount is going up, the shatter index increases. If the addition amount is 1.0 wt.% or more, the shatter index gets well over 85%. In the case that the addition amount is 2.5 wt.% or more, the shatter index becomes well over 90%, but the growth of shatter index is smaller in proportion. Judging from the results, to maintain the yield of the obtained agglomerates of fired pellets 75% level or more and, at the same time, the shatter index more than 85%, and still to allow the addition amount of quick limes to be as small as possible, it is preferable that the quick lime addition amount ranges 1.0 to 2.5 wt.%. Note that fluxes together with quick limes are, of course, added to fine iron ores so as to keep CaO/SiO 2 ratio 1.0 to 2.5. Particle Size of Green Pellets If blend ratio of small green pellets increases and green pellets to be used become relatively small, yield of agglomerates of fired pellets can be expected to be improved, since sintering of green pellets are well performed. But, if blend ratio of small green pellets become excessive, at the time of sintering, permeability among the green pellets is deteriorated so much that, owing to long time being required for the sintering, the productivity is deteriorated. Furthermore, because the green pellets are apt to be melted when excessively heated, they form glassy slag. Consequently, this results in deterioration of the shatter index. Beside that, this increases melted texture portion. Therefore, there further remains danger of deteriorating reduction index and reduction degradation index of the agglomerates of fired pellets. In this connection, an experiment was carried out, wherein particle sizes and blend ratios of green pellets were varied, and the green pellets were coated with powder cokes to manufacture agglomerates of fired pellets. Fig. 7 graphically shows relation of blend ratio of 5mm or less green pellets included in those used to yield of the obtained agglomerates of fired pellets. Fig. 8, also, graphically shows relation of blend ratio of 5mm or less.green pellets included in those used to productivity of the obtained agglomerates of fired pellets. Fig. 9, also, graphically shows relation of blend ratio of 5mm or less green pellets included in those used to shatter index of the agglomerates of fired pellets. In this experiment, 8mm or less fine iron ores in particle size were used and 3.5 wt.% powder cokes were added. As shown in Fig. 7, the more the blend ratio of 5mm or less green pellets in particle size increases, the better the sintering performance of the green pellets becomes, and, thus, the yield of the agglomerates of fired pellets is improved. If the blend ratio is 15 wt.% or more, the yield is 78% or more. The productivity is, as seen in Fig. 8, maintaining the level of 1.5 T/H/M 2 or more so far as the blend ratio of the green pellets is 40 wt.% or less, while the productivity goes down to less than 1.5 T/H/M 2 when the blend ratio is over 40 wt.%, since in this range, owing to deterioration of permeability, sintering time becomes long. With respect to the shatter index of the agglomerates of fired pellets, as shown in Fig. 9, the more the blend ratio of 5mm or less green pellets becomes, the more the shatter index is deteriorated, since glassy slag of the green pellets increase in proportion with the increase of the blend ratio. If the blend ratio is over 40 wt.%, the shatter index is less than 90%. Accordingly, in order to keep the yield 78% or more, the productivity 1.5T/H/M 2 level or more and the shatter index more than 90%, it is preferable to use green pellets consisting of 15 to 40 wt.% of 5mm or less green pellets in particle size and the rest of those of more than 5mm in particle size. 20 to 30 wt.% of 5mm or less is more preferable. SiO 2 Content in Agglomerates of Fired Pellets Fine iron ores may be pelletized by use of a disc type pelletizer and only with addition of fluxes, and, thereafter, coating with powder cokes is made, and, resultantly, this method is good for the pelletization enough to form good spherical green pellets. Therefore, from the performance of this method, it was found that, during the process of sintering green pellets, SiO 2 contained in fine iron ores and CaO contained in fluxes reacted each other, although the SiO 2 content was small, to form slag and thereby to allow the fine iron ores to one another be combined and well agglomerated. In this connection, agglomerates of fired pellets of various SiO 2 contents were manufactured experimentally from green pellets which had been prepared from fine iron ores having various SiO 2 contents. In this experiment, relations of SiO 2 content in agglomerates of fired pellets, respectively, to reduction index, reduction degradation index, yield, and shatter index were pursued. Fig. 10 graphically shows relation of SiO 2 content in obtained agglomerates of fired pellets to their reduction index. Fig. 11 graphically shows relation of SiO 2 content in the obtained agglomerates of fired pellets to their reduction degradation index. Fig. 12 graphically shows relation of SiO 2 content in the obtained fired pellets to their shatter index. Fig. 13 graphically shows relation of SiO 2 content in the obtained agglomerates of fired pellets to their yield. The reduction index of the agglomerates of fired pellets, as shown in Fig. 10, goes down as the SiO 2 content in the agglomerates of fired pellets is increasing. The reduction index, however, maintains the level higher than 80% in the SiO 2 content range of 0.5 to 5.0 wt.%. If the SiO 2 content is over 5.0 wt.%, the reduction index remarkably goes down. The reduction degradation index of the agglomerates of fired pellets, as seen from Fig. 11, shows good mark of less than 30 % in the SiO 2 content range of 0.5 to 5.0 wt.%. If the SiO 2 content is less than 0.5 wt.%, the reduction degradation index is deteriorated, while if the SiO 2 content is over 5.0 wt.%, the reduction degradation index becomes worse over 30%. Furthermore, as shown in Fig. 12, the shatter index of the agglomerates of fired pellets keeps the level enough to be more than 85% also in the SiO 2 content range of 0.5 to 5.0. wt.%. If the SiO 2 content is less than 0.5 wt.%, the shatter index rapidly declines. With respect to the yield of the agglomerates of fired pellets, as shown in Fig. 13, the yield increases as the SiO 2 content is going up, and the yield satisfies the level of being well more than 75% even in the SiO 2 content range of 0.5 to 5.0 wt.%. If the SiO 2 content is lowered less than 0.5 wt.%, the yield rapidly declines. Judging from these results, in order to keep the reduction index of more than 80% and the reduction degradation index of 30% or less without deterioration of the yield and the shatter index, the SiO 2 content of the agglomerates of fired pellets ranges from 0.5 to 5.0 wt.%. 1.0 to 4.0 wt.% of the SiO 2 content is preferable. With specific reference to Fig. 14 of the drawings, the method of the present invention will now be described in detail : In Fig. 14, referential numeral 1 denotes a mixer of drum type, 3 a first pelletizer of disc type, 4a and 4b, each, second pelletizers of disc type and 5 screen device. In this experiment, green pellets pelletized into by first pelletizer.3, are screened into two groups, depending on particle sizes, so as to allow powder cokes to be added, by weighing an addition amount, more to a group of larger green pellets and to be mixed therewith through each of second mixers 4a and 4b. This is to allow a group composed of larger green pellets in particle size to be well coated. Fine iron ores of 8mm or less in particle size and fluxes are introduced into the first mixer and mixed to form a mixture. The mixture is introduced into first pelletizer 3 and pelletized with water addition into green pellets of 3 to 13mm in particle size. Subsequently, the green pellets are screened by screen device 5 in groups, for example, one group consisting of larger green pellets more than 7mm to 13mm or less in particle size and another group of smaller green pellets 3mm and more to 7mm or less. The green pellets of the larger size group are transferred into second pelletizer 4a, and the green pellets of the other group into second pelletizer 4b. The green pellets respectively sent, are coated, on their surface, with powder cokes again added thereto in each of second pelletizer 4a and 4b. In second pelletizer 4a and 4b, powder cokes are prepared in amount of 2.5 to 4.0 wt.% of green pellets totally to be coated, and are added to green pellets of the larger size group more than those of the other group by means of giving weight differently to addition amounts of the powder cokes to each of the two groups. This weighing is performed in such a manner as, for example, when 3.5 wt.% powder cokes are totally added to the green pellets, those of 4.0 to 4.5 wt.% of the green pellets of the larger size group are added thereto, namely the addition amount is weighed as much as 0.5 to 1.0 wt.% larger than the total addition amount in wt.%. Thus, owing to the larger addition amount, the green pellets of the larger size group can be coated satisfactorily and well, on their surface, with the powder cokes by means of second pelletizer 4a. In this case, to the powder cokes for coating the green pellets of the larger size group, if appropriate, 0.5 to 1.0 wt.% binder can be added in advance, thereby to allow the powder cokes to stick harder to and coat better the green pellets on their surface. On the other hand, owing to the less amount of powder cokes initially being allocated to the group of green pellets of smaller size, the amount of powder cokes gets short when the green pellets are coated by second pelletizer 4b. But, those green pellets of smaller size are easy to allow heat to reach upto their center when sintered. Consequently, throughout sintering process, in spite of the small addition amount of the powder cokes, the green pellets can be well sintered, thanks to aid of surplus amount of powder cokes charged together with the green pellets both of larger and smaller size into a sintering machine. Thus, the shortage in amount of the powder cokes is by no means disadvantageous. In addition, the green pellets of the smaller size group can be easily coated with the powder cokes by mixing without such strong stirring as employed in pelletization. Of course, should it be necessary, the short coating amount of the powder cokes can be made up for as follows: (a) The green pellets of the smaller size group discharged from second pelletizer 4b are allowed to be put together with those of the larger size discharged to a belt-conveyer for transfer. (b) During the transfer process by the belt-conveyer, the green pellets of the smaller size group are allowed to be given slight vibration and thereby to be further coated with surplus of powder cokes discharged together with the green pellets of the larger size group. Green pellets are presently screened into two groups depending on their particle size. Of course, the green pellets can be divided into three groups or more of particle size, to coat the green pellets with powder cokes added. The second pelletizer of disc type used can be also alternated by that of drum type. Example 1 To powdery fine iron ores and coarse grain iron ores, quick limes of 2.7 wt.% as a flux and binder was added and mixed therewith to form a mixture. The obtained mixture was pelletized into green pellets of 3 to 13mm in particle size with water content of 8 to 9 wt.%. The powdery fine iron ores and coarse grain iron ores were blended so as to allow their ratio of 0.125mm or less in particle size to be varied. Table 1 shows particle size distribution of the powdery fine iron ores, Table 2 chemical composition of the powdery fine iron ores, Table 3 particle size distribution of the coarse grain iron ores, Table 4 chemical composition of the coarse grain iron ores, Table 5 blend ratio of 0.125mm or less powdery fine iron ores in particle size composed of the powdery fine and coarse grain iron ores, Table 6 particle size distribution of the quick limes and Table 7 particle size distribution of the green pellets. Next, to the green pellets, powder cokes composed of particle sizes as shown in Table 8 were added and the green pellets were coated, through pelletization, with the powder cokes. Subsequently, the green pellets were charged into an endless grate type sintering machine to be laid in 400mm thickness on the grate of the sintering machine. The green pellets thus laid, were moved through zones for drying, igniting and sintering in order, to form fired pellets. The large and blocky agglomerates of fired pellets thus formed were discharged from the sintering machine and then crushed by a crusher. The crushed agglomerates of fired pellets were screened to remove those agglomerates less than 3mm in particle size from the crushed agglomerates. Thus, blocky agglomerates composed of combined fired pellets in plurality with the maximum particle size of about 50mm, and agglomerates composed of a single fired pellet of 3 to 13mm in particle size were manufactured. In comparison of Examples of the present invention with Controls, the reduction indexes and the shatter indexes of the manufactured agglomerates of fired pellets are shown in Table 9. Those agglomerates of fired pellets of Test Nos. 1 to 5 as Examples having 30 to 95 wt.% blend ratio of 0.125mm or less fine iron ores in particle size, all, show good marks of their reduction indexes and shatter indexes. Compared with these results, the other agglomerates of fired pellets of Test Nos. 6 and 7, as Controls, having blend ratios other than 30 to 95 wt.% of 0.125mm or less fine iron ores show that their reduction indexes and shatter indexes are inferior to those of Test Nos. 1 to 5. (wt.%) 0.044mm or less Over 0.044mm to 0.125mm Over 0.125mm to 0.5mm Over 0.5mm 63.86 31.07 4.48 0.59 (wt.%) T.Fe SiO 2 Al 2 O 3 CaO MgO FeO 67.80 0.81 0.63 0.04 0.40 0.09 (wt.%) T.Fe SiO 2 Al 2 O 3 CaO MgO FeO 59.47 5.60 1.80 1.80 1.78 4.40 Test Nos. Blend Ratio of 0.125mm or Less (wt.%) Examples 1 30 2 40 3 60 4 80 5 95 Controls 6 20 7 100 (wt.%) 0.125mm or Less Over 0.125mm to 0.5mm Over 0.5mm to 1 mm Over 1mm 16.2 20.0 18.3 45.5 (wt.%) 3mm or More to 5mm Over 5mm to 7mm Over 7mmm to 9mm Over 9mm to 10mm Over 10mm to 13mm 7 35 39 11 8 (wt.%) 0.1mm or less Over 0.1mm to 0.5mm Over 0.5mm to 1mm Over 1mm 21.83 66.75 10.52 0.90 Test Nos. Reduction Index (%) Shatter Index SI +5 (%) Examples 1 76.9 85.4 2 80.7 88.3 3 83.2 90.7 4 85.0 91.4 5 84.2 90.6 Controls 6 69.8 77.1 7 84.7 80.3 Example 2 To fine iron ores consisting of 40 wt.% powdery fine powder iron ores and 60 wt.% coarse grain iron ores, quick limes of 2.7 wt.% were added and mixed therewith to form a mixture. The mixture thus obtained, were pelletized into green pellets of 3 to 13mm in particle size with water content of 8 to 9 wt.%. Subsequently, the green pellets were screened into two groups i.e. one group of green pellets of 3 to 7mm in particle size and another group of those of over 7 to 13mm. And then, powder cokes were added separately in amount as much as shown in Table 10 to green pellets of each of the two groups so as to allow the added amount, by means of weighing, to the larger size group to be more than to the smaller size group, and the green pellets were coated on their surface, through pelletization by a disc type pelletizer, with the powder cokes. For comparison, to the green pellets of the larger size group and to those of the smaller size group power cokes were added without weighting, and the green pellets of each of the groups. The powdery fine iron ores, the coarse grain iron ores, the quick limes and the powder cokes used in this Example were same as those used in Example 1. Blend ratios of powder cokes to green pellets were checked, and the results are shown in Table 11. Next, the green pellets were charged into an endless grate type sintering machine to be laid in 400mm thickness on the grate of the sintering machine, and then, were trnasfered through the drying, igniting and sintering zone in order, to sinter agglomerates of fired pellets. The yields and productivity of the obtained fired pellets are shown in Table 12. As seen from Table 11, in Test Nos. 8 and 9 as Examples of the present invention, powder cokes were added so as to allow the addition amount, by weighing, to the green pellets of the over 7 to 13mm to be larger size group, and consequently, the blend ratios of the powder cokes to the larger size green pellets by wt.% becomes larger. That is to say, the larger size green pellets whose coating must be taken care of were well coated with the powder cokes. Thanks to this, as shown in Table 12, the yields and the productivities of the obtained agglomerates of fired pellets of Test Nos. 8 and 9 as Examples of the present invention, attain good marks. In comparison, as seen from Table 11, in Test Nos. 10 and 11, as Control, powder cokes were added to the green pellets without weighing, the blend ratios of the larger size green pellets are lower, i.e. the larger size green pellets whose coating must be taken care of are coated with the powder cokes in small amount. Due to this, the yields as well as the productivities of the manufactured agglomerates fired pellets in Test Nos. 10 and 11 are found only to be of low marks, as shown in Table 12. Test Nos. Powder Cokes Addition in Screened Groups Total Addition Amount (wt.%) 3mm or More to 7mm Over 7 to 13mm Examples 8 1.6 4.0 3.0 9 2.6 5.0 4.0 Controls 10 3.0 3.0 3.0 11 4.0 4.0 4.0 Test Nos. 3mm or More to 7 Over 7 to 13mm Examples 8 1.57 3.05 9 2.55 3.88 Controls 10 2.95 2.04 11 3.93 2.97 Test Nos. Yield (%) Productivity (T/H/M 2 ) Examples 8 83.44 1.66 9 87.98 1.71 Controls 10 73.13 1.35 11 79.62 1.47

Claims: A method for manufacturing agglomerates of fired pellets comprising the steps of adding fluxes including quick limes to fine iron ores, 30 - 95 wt.% of fine iron ores having a particle size of 0.125 mm or less, and the amount of quick limes being 1.0 to 2.5 wt.% based on the weight of fine iron ores; mixing the fluxes and fine iron ores to produce a mixture; pelletizing the mixture into green pellets; screening the green pellets having a particle size of 3 to 13 mm into at least two separate groups according to the particle size; separately adding powder cokes to each of the at least two separate groups of screened pellets in an amount of 2.5 to 4.0 wt.% based on the weight of the fine iron ores in the green pellets, 80 to 100 wt.% of the powder cokes having a particle size of 1 mm or less; pelletizing the at least two separate groups of screened green pellets and powder cokes to produce at least two groups of screened green pellets coated with powder cokes, the powder cokes being added to the at least two separate groups of screened green pellets such that a larger proportion by weight of powder cokes is added to green pellets having a larger particle size; charging the at least two groups green pellets coated with powder cokes into a grate type sintering machine; and sintering the green pellets coated with powder cokes into agglomerates of fired pellets, said agglomerates containing 0.5 to 5.0 wt.% of SiO 2 . The method of claim 1 wherein the step of screening the green pellets into at least two groups includes screening the green pellets into a first group of green pellets having a particle size of 3 to 7 mm and a second group of green pellets having a particle size of 7 to 13 mm. The method of claim 1 wherein the powder cokes are added in an amount of 2.5 to 4 % by weight based on the total weight of the green pellets, and wherein 0.5 to 1 weight-% more than the amount of 2.5 to 4 weight-% of powder cokes, based on the total weight of the green pellets, is added to the group of screened green pellets having a larger particle size.

Inventors: NODA HIDETOSHI, SAKAMOTO NOBORU, YANAKA HIDEOMI, NODA, HIDETOSHI, SAKAMOTO, NOBORU, YANAKA, HIDEOMI, Noda, Hidetoshi, c/o Patent &amp; License and Quality, Sakamoto, Noboru, c/o Patent &amp; License and Quality, Yanaka, Hideomi, c/o Patent &amp; License and Quality
Applicants: NIPPON KOKAN KK, NIPPON KOKAN KABUSHIKI KAISHA
Application year: 1987
Main classification: C22B1
IPC codes: C22B1