LIGHT-SENSITIVE SILVER HALIDE PHOTOGRAPHIC MATERIAL

Abstract: A light-sensitive silver halide photographic material comprising a support and provided thereon at least one silver halide emulsion layer, wherein at least one layer of said silver halide emulsion layer contains a compound represented by general formula [I], (wherein Z represents a group of non-metallic atoms neces­ sary to complete a nitrogen-containing heterocyclic ring which may have a substituent; X represents a hydrogen atom or a substituent capable of being split off upon reaction with an oxidation product of a color developing agent; and R re­ presents a hydrogen atom or a substituent), said silver halide emulsion layer containing the compound of formula [I] further containing a metal complex having a quenching rate constant of singlet oxygen of more than 3 × 10⁷ M⁻¹. sec⁻¹, and a compound having the general formula [a-1] or [a-2]: (wherein R¹ and R² are independently selected from an alkyl group; R³ is selected from the group consisting of an alkyl group, a-NR′R″ group, a-SR′ group and a-COOR″ group, in which R′ is a mono-valent organic group and R″ is a hydrogen atom or a mono-valent organic group; and m is an integer of 0 to 3); (wherein R⁴ is selected from the group consisting of a hydrogen atom, a hydroxyl group, an oxy radical group, -SOR′ group, in which R′ is a mono-valent organic group, a -SO₂R″ group, in which R″ is a hydrogen atom or a mono-­ valent organic group; R⁵, R⁶, R 5, , R 6, are independently selec­ ted from an alkyl group; R⁷ and R⁸ are independently selected from the group consisting of a hydrogen atom and a -OCOR¹⁰ group, in which R¹⁰ is a mono-valent organic group, provided that R⁷ and R⁸ may be combined with each other to form a heterocyclic group; and n is an integer of 0 to 4).

Description: FIELD OF THE INVENTION The present invention relates to a light-sensitive silver halide photographic material, in particular to a light-sensitive silver halide material for color photography that possesses improved image stability to light. BACKGROUND OF THE INVENTION A conventional method of forming color images using a light-sensitive silver halide photographic material is based on the reaction of a photographic coupler with the oxidant of a color developing agent. The typical photographic couplers used for color reproduction are magenta, yellow and cyan. The typical color developing agents used are aromatic primary amines. Dyes such as azomethine dyes are formed through reaction of dye-forming couplers such as magenta- or yellow-dye-forming couplers with an oxidant of the aromatic primary amine color developing agent. Dyes such as indoaniline dyes are produced through reaction of the cyan coupler with an oxidant of the aromatic primary amine color developing agent. Among these dyes 5-pyrazolone, cyanoacetophenone, indazolone, pyrazolobenzimidazole, pyrazolotriazole couplers are used to form magenta dye images. In the past, 5-pyrazolone couplers have been used mainly as the magenta dye image-forming coupler. The dye images formed from 5-pyrazolone couplers are highly resistant to light and heat, but then color tone is not sufficient. Further, dyes of this class have an unnecessary spectrum absorption near 430 nm and the absorption spectrum of visible light near 550 nm is broad, which causes color turbidity, resulting in less clear photographic images. Couplers providing no such unnecessary absorption include 1H-pyrazolo [3,2-c]-s-triazole type couplers, 1H-imidazo [1,2-b]-pyrazole type couplers, 1H-b pyrazolo [1,5-b]-pyrazole type couplers, and 1H-b pyrazolo [1,5-d] tetrazole type couplers, which are disclosed in U.S. Patent No. 3,725,067, Japanese Patent Publication Open to Public Inspection No. 162548/1984, and Japanese Patent Publication Open to Public Inspection No. 171956/1984. The light stability of the color images formed by these couplers, however, is very low and, therefore, it has been considered in the art that the use of such couplers for light-sensitive material especially for color photographic papers, does not meet critical requirements of recording and preserving the original image. This has prevented the couplers from being used practically. To improve light resistance, use of phenol compounds or phenyl ether compounds as anti-oxidants has been proposed, for example in Japanese Patent Publication Open to Public Inspection (hereinafter referred to as Japanese Patent O.P.I. Publication) No. 125732/1984. This, however, has not provided a sufficient effect. On the other hand, use of a metal complex as the anti-fading agent has been presented in Japanese Patent O.P.I. Publications No. 99340/1981, 168652/1981 and 51834/1985. Application of the metal complex to dyes from certain types of pyrazolotriazole coupler can improve the light resistance; however, compounds providing relatively high light resistance are often accompanied by the disadvantage that non-exposed samples tend to result in increased fog with the lapse of time. Some compounds obtained from a metal complex, which cause less fogging during storage do not provide sufficient resistance to light. Thus it has been difficult to improve the light resistance of light-sensitive silver halide photographic materials while keeping resistance against fogging during storage when a pyrazolotriazole system magenta coupler and a metal complex are used in combination. SUMMARY OF THE INVENTION A primary object of the present invention is to provide a light-sensitive silver halide photographic material that possesses excellent color reproductibility of the magenta dye image and image fastness against light with decreased fogging during storage of the unexposed material. According to the present invention there is provided a light-sensitive silver halide photographic material comprising a support and provided thereon at least one silver halide emulsion layer, wherein at least one layer of said silver halide emulsion layer contains a compound represented by general formula [I], (wherein Z represents a group of non-metallic atoms necessary to complete a nitrogen-containing heterocyclic ring which may have a substituent; X represents a hydrogen atom or a substituent capable of being split off upon reaction with an oxidation product of a color developing agent; and R represents a hydrogen atom or a substituent), said silver halide emulsion layer containing the compound of formula [I] further containing a metal complex having a quenching rate constant of singlet oxygen of more than 3 x 10⁷ M⁻¹ sec⁻¹, and a compound having the general formula [a-1], (wherein R¹ and R² are independently selected from an alkyl group; R³ is selected from the group consisting of an alkyl group, a -NR′R″ group, a -SR′ group and a -COOR″ group, in which R′ is a mono-valent organic group and R″ is a hydrogen atom or a mono-valent organic group; and m is an integer of 0 to 3); or a compound having the general formula [a-2], (wherein R⁴ is selected from the group consisting of a hydrogen atom, a hydroxyl group, an oxy radical group, -SOR′ group, in which R′ is a mono-valent organic group, a -SO₂R″ group, in which R″ is a hydrogen atom or a mono-valent organic group; R⁵, R⁶, R⁵′, R⁶′ and R⁹ are independently selected from an alkyl group; R⁷ and R⁸ are independently selected from the group consisting of a hydrogen atom and a -OCOR¹⁰ group, in which R¹⁰ is a mono-valent organic group, provided that R⁷ and R⁸ may be combined with each other to form a heterocyclic group; and n is an integer of 0 to 4). DETAILED DESCRIPTION OF THE INVENTION The present invention is explained more in detail with reference to preferred embodiments: In formula [I], the substituent represented by R includes a halogen atom , an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro-compound residual group, a bridged hydrocarbon compound residual group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbomoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, an ureido group, a sulfamoyl amino group, an alkoxy carbonyl amino group, an aryloxy carbonyl amino group, an alkoxy carbonyl group, an aryloxy carbonyl group, an alkyl thio group, an aryl thio group, and a heterocyclic thio group. The preferable halogen atoms are chlorine and bromine, and chlorine is most preferable. The alkyl group represented by R is preferably one containing 1 to 32 carbon atoms; the alkenyl and alkenyl groups are preferably ones containing 2 to 32 carbon atoms; the cycloalkyl and cycloalkenyl groups are preferably ones containing 3 to 12 carbon atoms, in particular 5 to 7 carbon atoms; the alkyl, alkenyl and alkynyl groups may be straight-chained or branched. The alkyl, alkenyl, alkynyl, cycloalkyl, and/or cycloalkenyl groups may contain substituents [e.g., aryl, cyano, halogen atoms, heterocyclic rings, cycloalkyl, cycloalkenyl, spiro-compound residues and bridged hydrocarbon compound residues, as well as substituents substituted via a carbonyl group such as acyl, carboxyl, carbamoyl, alkoxy carbonyl and aryloxy carbonyl, and substituents substituted via hetero atoms {such as substituents attached via oxygen atoms including hydroxy, alkoxy, aryloxy, hetero ring oxy, siloxy, acyloxy and carbamoyloxy, substituents substituted via nitrogen atoms including nitro, amino (including di-alkyl amino), sulfamoyl amino, alkoxy carbonyl amino, aryloxy carbonyl amino, acyl amino, sulfon amide, imide and ureido, substituents attached via sulfur atoms including alkyl thio, aryl thio, heterocyclic thio, sulfonyl, sulfinyl and sulfamoyl, and substituents attached via phosphorus atoms including phosphonyl}]. The groups especially used include a methyl group, an ethyl group, an isopropyl group, a t-butyl group, a pentadecyl group, a heptadecyl group, a 1-hexyl nonyl group, a 1,1′-di-pentyl nonyl group, a 2-chlor-t-butyl group, a trifluoromethyl group, a 1-ethoxy tridecyl group, a 1-methoxy isopropyl group, a methane sulfonyl ethyl group, a 2,4-di-t-amyl phenoxy methyl group, an anilino group, a 1-phenyl isopropyl group, a 3-m-butane sulfon amido phenoxy propyl group, a 3-4′-{alpha-[4″ (p-hydroxy benzene sulfonyl) phenoxy] dodecanoyl amino} phenyl propyl group, a 3-{4′-[alpha-(2″,4″-di-t-amyl phenoxy) butane amide] phenyl}-propyl group, a 4-[alpha-(ochlor phenoxy) tetra decane amide phenoxy] propyl group, an aryl group, a cyclopentyl group, and a cyclohexyl group. The aryl group represented by R is preferably a phenyl group, which may contain one or more substituents (e.g., an alkyl group, an alkoxy group, and an acyl amino group). The aryl group especially used includes a phenyl group, a 4-t-butyl phenyl group, a 2,4-di-t-amyl phenyl group, a 4-tetradecane amide phenyl group, a hexa di-siloxy phenyl group, and a 4′-[alpha-(4″-t-butyl phenoxy) tetradecane amide] phenyl group. The heterocyclic group represented by R should preferably contain 5 to 7 ring members that may have been substituted or condensed. The heterocyclic group especially used includes 2-furyl, 2-thienyl, 2-pyrimidinyl, and 2-benzothiazolyl groups. The acyl group represented by R includes, e.g., an alkyl carbonyl group such as acetyl, phenyl acetyl, dedecanoyl and alpha-2,4-di-t-amylphenoxy butanoyl groups, and an aryl carbonyl group such as benzoyl, 3-pentadecyl oxy benzoyl and p-chlorbenzoyl groups. The sulfonyl group represented by R includes an alkyl sulfonyl group such as methyl sufonyl and dodecyl sulfonyl groups, and an aryl sufonyl group such as benzene sulfonyl and p-toluene sulfonyl groups. The sulfinyl group represented by R includes an alkyl sulfinyl group such as ethyl sulfinyl, octyl sulfinyl and 3-phenoxy butyl sulfinyl groups, and an aryl sulfinyl group such as phenyl sulfinyl and m-pentadecyl phenyl sulfinyl groups. The phosphonyl group represented by R includes an alkyl phosphonyl group such as a butyl octyl phosphonyl group, an alkoxy phosphonyl group such as an octyloxy phosphonyl group, an aryloxy phosphonyl group such as a phenoxy phosphonyl group, and an aryl phosphonyl group such as a phenyl phosphonyl group. The carbamoyl group represented by R, which may have been substituted by an alkyl group or an aryl group (preferably a phenyl group), includes, e.g., N-methyl carbamoyl, N,N-di-butyl carbamoyl, N-(2-pentadecyl octyl ethyl) carbamoyl, N-ethyl-N-dodecyl carbamoyl, and N-{3-(2,4-di-t-amyl phenoxy) propyl} carbamoyl groups. The sulfamoyl group represented by R, which may have been substituted by an alkyl group or an aryl group (preferably a phenyl group), includes, e.g., N-propyl sulfamoyl, N,N-di-ethyl sulfamoyl, N-(2-penta decyl oxy-ethyl) sulfamoyl, N-ethyl-N-dodecyl sulfamoyl, and N-phenyl sulfamoyl groups. The spiro-compound residue represented by R includes, e.g., spiro [3.3] heptan-1-yl. The bridged hydrocarbon compound residue represented by R includes, e.g., bicyclo[2.2.1]heptane-1-yl, tricyclo [3.3.1.1 3,7 ]decane-1-yl, and 7,7-dimethyl-bicyclo[2.2.1] heptane-1-yl. The alkoxy group represented by R, which may be substituted by the substituents for the alkyl group set forth above, includes, e.g., methoxy, propoxy, 2-ethoxy, pentadecyloxy, 2-dodecyloxy ethoxy, and phenethyloxy ethoxy groups. The aryloxy group represented by R includes, e.g., phenoxy, p-t-butyl phenoxy, and m-pentadecyl phenoxy groups. In that case, the aryl nucleus may have been substituted by substituents or atoms set forth above for the aryl group. The heterocyclic oxy group represented by R, which should be preferably a one containing a hetero ring having 5 to 7 ring members that may have a substituent, includes, e.g., 3,4,5,6-tetra-hydropiranyl-2-oxy and 1-phenyl tetrasol-5-oxy groups. The siloxy group represented by R, which may have been substituted by e.g. an alkyl group, includes tri-methyl siloxy, tri-ethyl siloxy and di-methyl butyl siloxy groups. The acyloxy group represented by R, which may contain one or more substituents, includes, e.g., alkyl carbonyloxy and aryl carbonyloxy groups. Especially, acetyloxy, alpha-chloracetyloxy and benzoyloxy groups can be used. The carbamoyloxy group represented by R, which may have been substituted by one or more alkyl and/or aryl groups, includes, e.g., N-ethyl carbamoyloxy, N,N-di-ethyl carbamoyloxy, and N-phenyl carbamoyloxy groups. The amino group represented by R, which may have been substituted by an alkyl group or an aryl group (preferably a phenyl group), includes, e.g., ethyl amino, anilino, m-chloranilino, 3-pentadecyloxy carbonyl anilino, and 2-chlor-5-hexadecane amide anilino groups. The acyl amino group represented by R, which may have one or more substituents, includes, e.g., alkyl carbonyl amino and aryl carbonyl amino groups (preferably a phenyl carbonyl amino group), especially acetoamido, alpha-ethyl propane amido, N-phenyl acetoamido, dodecane amido, 2,4-di-amyl phenoxy acetoamido, and alpha-3-t-butyl 4-hydroxy phenoxy butane amido groups. The sulfon amide group represented by R, which may have on or more substituents, includes alkyl sulfonyl amino and aryl sulfonyl amino groups, especially methyl sulfonyl amino, pentadecyl sulfonyl amino, benzene sulfon amide, p-toluene sulfon amide, and 2-methoxy-5-t-amyl benzene sulfon amide groups. The imide group represented by R, which may be of an open chain or ring and have one or more substituents, inclues, e.g., succinic acid imide, 3-heptadecyl succinic acide imide, phthalimide, and glutaric imide groups. The ureido group group represented by R, which may have been substituted by an alkyl group and/or an aryl group (preferably a phenyl group), includes, e.g., N-ethyl ureido, N-methyl-N-decyl ureido, N-phenyl ureido, and N-p-tolyl-ureido groups. The sulfamoyl amino group represented by R, which may have been substituted by an alkyl group and/or an aryl group (preferably a phenyl group), includes, e.g., N,N-di-butyl sulfamoyl amino, N-methyl sulfamoyl amino, and N-phenyl sulfamoyl amino groups. The alkoxy carbonyl amino group represented by R, which may have one or more substituents, includes, e.g., methoxy carbonyl amino, methoxy ethoxy carbonyl amino, and octadecyloxy carbonyl amino groups. The aryloxy carbonyl amino group, which have one or more substituents, includes, e.g., phenoxy carbonyl amoni and 4-methyl phenoxy carbonyl amino groups. The alkoxy carbonyl group represented by R, which may have one or more further substituents, includes, e.g., methoxy carbonyl, butyloxy carbonyl, dodecyloxy carbonyl, octadecyloxy carbonyl, ethoxy methoxy carbonyloxy, and benzyloxy carbonyl groups. The aryloxy carbonyl group represented by R, which may have on or more further substituents, includes, e.g., phenoxy carbonyl, p-chloro-phenoxy carbonyl, and m-penta decyloxy phenoxy carbonyl groups. The alkylthio group represented by R, which may have one or more further substituents, includes, e.g., ethylthio, dodecylthio, octa-decylthio, phenethylthio, and 4-phenoxy propylthio groups. The arylthio group represented by R, which may have one or more further substituents, should be preferably a phenylthio group including p-methoxy phenylthio, 2-t-octyl phenylthio, 3-octadecyl phenylthio, 2-carboxyl phenylthio, and p-acetoamine phenylthio groups. The hetero ring thio group represented by R should be preferably a hetero ring thio group that may have further condensed rings and/or substituents, including, e.g., 2-pyridyl thio, 2-benzothiazolyl thio and 2,4-di-phenoxy-1,3,5-triazole-6-thio groups. Substituents freed through their reaction with the oxidant of the coloring developing agent, indicated by X, include groups substituted via a halogen atom (chlorine atom, bromine atom or fluorine atom), as well as a carbon atom, an oxygen atom, a sulfur atoms or a nitrogen atom. The groups substituted via a carbon atom include carboxyl, hydroxy methyl and tri-phenyl methyl groups, as well as groups indicated by the formula: where R¹′ has the same meaning as R and Z′ has the same meaning as Z, and R²′ and R³′ are each independently a hydrogen atom or an aryl, alkyl and/or hetero ring group. The groups substituted via an oxygen atom include, e.g., alkoxy, aryloxy, hetero ringoxy, acyloxy, sulfonyloxy, alkoxy carbonyloxy, aryloxy carbonyloxy, alkyl oxalyloxy, and alkoxy oxalyloxy groups. The alkoxy group, which may have one or more further substituents, includes ethoxy, 2-phenoxy ethoxy, 2-cyano ethoxy, phenethyloxy, and p-chloro-benzyloxy groups. As the aryloxy group, a phenoxy group is preferable, and the aryl group may have one or more further substituents. The aryloxy group includes, e.g., phenoxy, 3-methyl phenoxy, 3-dodecyl phenoxy, 4-methane sulfon amide phenoxy, 4-[alpha-(3′-pentadecyl phenoxy) butane amide] phenoxy, hexydecyl carbamoyl methoxy, 4-cyano phenoxy, 4-methane sulfonyl phenoxy, 1-naphthyloxy, and p-methoxy phenoxy groups. As the heterocyclic oxy group, a heterocyclic oxy group having 5 to 7 members is desirable, which can be a condensed ring or may have one or more substituents. The heterocyclic oxy group includes, e.g., 1-phenyl tetrazolyloxy and 2-benzothiazolyloxy groups. The acyloxy group includes, e.g., an alkyl carbonyloxy group such as acetoxy and butanoloxy groups, an alkenyl carbonyloxy group such as a cinnamoyloxy group, and an aryl carbonyloxy group such as a benzoyloxy group. The sulfonyloxy group includes, e.g., butane sulfonyloxy and methane sulfonyloxy groups. The alkoxy carbonyloxy group includes, e.g., ethoxy carbonyloxy and benzyloxy carbonyloxy groups. The aryloxy carbonyl group includes, e.g., a phenoxy carbonyloxy group. The alkyl oxalyloxy group includes, e.g., a methyl oxalyloxy group. The alkoxy oxalyloxy group includes, e.g., an ethoxy oxalyloxy group. As the groups substitued via sulfur atoms, there are, for example, alkyl thio, aryl thio hetero ring thio, and alkyloxy thio carbonyl thio groups. The alkyl thio group includes butyl thio, 2-cyano ethyl thio, phenethyl thio, and benzyl thio groups. The aryl thio group includes phenyl thio, 4-methane sulfon amide phenyl thio, 4-dodecyl phenethyl thio, 4-nonafluoropentane amide phenythyl thio, 4-carboxyl phenyl thio, and 2-ethoxy-5-t-butyl phenyl trio groups. The hetero ring thio group includes, e.g., 1-phenyl-1,2,3,4-tetrazolyl-5-chio and 2-benzothiazolyl groups. The alkyloxy thio carbonyl group includes, e.g., a dodecyloxy thio carbonyl thio group. The groups substituted via nitrogen atoms include, e.g., those represented by the formula: where R⁴′ and R⁵′ refer to a hydrogen atom, an alkyl group, an aryl group, a hetero ring group, a sulfamoyl group, a carbamoyl group, an acyl group, a sulfonyl group, an aryloxy carbonyl group, or an alkoxy carbonyl group; R⁴′ and R⁵′ may be combined, forming a hetero ring, but both of R⁴′ and R⁵′ cannot be a hydrogen atom. The alkyl group may be straight-chain or branched having preferably 1 to 11 carbons. The alkyl group may contain one or more substituents such as an aryl group, an alkoxy group, an aryloxy group, an alkyl thio group, an aryl thio group, an alkyl amino group, an aryl amino group, an acyl amino group, a sulfon amide group, an imino group, an acyl group, an alkyl sulfonyl group, an aryl sulfonyl group, a carbamoyl group, a sulfamoyl group, an alkoxy carbonyl group, an aryloxy carbonyl group, an alkyloxy carbonyl amino group, an aryloxy carbonyl amino group, a hydroxyl group, a carboxyl group, a cyano group, and a halogen atom. The alkyl group includes, e.g., an ethyl group, an octyl group, a 2-ethyl hexyl group, and a 2-chloro-ethyl group. The aryl group represented by R⁴′ and R⁵′ should be preferably a phenyl group or a naphthyl group having 6 to 32 carbons. The aryl group may contain one or more substituents such as those for an alkyl group indicated by R⁴′ or R⁵′ and an alkyl group. Preferred aryl groups are a phenyl group, a 1-naphthyl group, and a 4-methyl sulfonyl phenyl group. The heterocyclic group represented by R⁴′ or R⁵′ should be preferably one that has 5 to 6 ring members, may be a condensed ring, and may have one or more substituents, especially a 2-furyl group, a 2-quinolyl group, a 2-pyrimidyl group, a 2-benzothiazolyl group, and a 2-pyridyl group. The sulfamoyl group represented by R⁴′ or R⁵′ includes an N-alkyl sulfamoyl group, an N,N di-alkyl sulfamoyl group, an N aryl sulfamoyl group, and an N,N di-aryl sulfamoyl group. These alkyl and aryl groups may have the substituents set forth above for the alkyl and aryl groups. Preferred sulfamoyl groups are, a N,N di-ethyl sulfamoyl group, an N-methyl sulfamoyl group, an N-dodecyl sulfamoyl group, and an N-p-tolyl sulfamoyl group. The carbamoyl group represented by R⁴′ or R⁵′ includes an N-alkyl carbamoyl group, an N,N-di-alkyl carbamoyl group, an N-aryl carbamoyl group, and an N,N di-aryl carbamoyl group. These alkyl and aryl groups may contain the substituents set forth above for the alkyl and aryl groups. Preferred carbamoyl groups are an N,N-di-ethyl carbamoyl group, an N-methyl carbamoyl group, an N-dodecy carbamoyl group, an N-p-cyano phenyl carbamoyl group, and an N-p-tolyl carbamoyl group. The acyl group represented by R⁴′ or R⁵′ includes, e.g., an alkyl carbonyl group, an aryl carbonyl group, and a heterocyclic carbonyl group. The alkyl, aryl and heterocyclic groups may contain one or more substituents. Preferred acyl groups are a hexa-fluoro butanoyl group, a 2,3,4,5,6-penta-fluoro benzoyl group, an acetyl group, a benzoyl group, a naphthoel group, and a 2-furyl carbonyl group. The sulfonyl group represented by R⁴′ or R⁵′ includes an alkyl sulfonyl group, an aryl sulfonyl group, and a heterocyclic sulfonyl group, and may contain one or more substituents. Preferred sulfonyl groups are an ethane sulfonyl group, a benzene sulfonyl group, an octane sulfonyl group, a naphthalene sulfonyl group, and a p-chloro-benzene sulfonyl group. The aryloxy carbonyl group represented by R⁴′ or R⁵′ may contain the substituents set forth above for the aryl group, and includes, e.g., a phenoxy carbonyl group. The alkoxy carbonyl group represented by R⁴′ or R⁵′ may contain the substituents set forth above for the alkyl group. Preferred alkoxy carbonyl groups are a methoxy carbonyl group, a dodecyloxy carbonyl group, and a benzyloxy carbonyl group. The hetero ring formed by combination of R⁴′ and R⁵′ should be preferably one having 5 or 6 members, may be saturated or unsaturated, may or may not have aromatic characteristics, and may be a condensed ring. The hetero ring includes, e.g., an N-phthalimide group, an N-succinic acid imide group, a 4-N-urazolyl group, a 1-N-hydantoinyl group, a 3-N-2,4-di-oxo-oxazolidinyl group, a 2-N-1,1-di-oxo-3-(2H)-oxo-1,2-benzothiazolyl group, a 1-pyrrolyl group, a 1-prrolidinyl group, a 1-pyrazolyl group, a 1-pyrazolidinyl group, a 1-piperidinyl group, a 1-pyrrolinyl group, a 1-imidazolyl group, a 1-imidazolinyl group, a 1-indolyl group, a 1-iso-indolinyl group, a 2-iso-indolyl group, a 2-iso-indolinyl group, a 1-benzotriazolyl group, a 1-benzoimidazolyl group, a 1-(1,2,4-triazolyl) group, a 1-(1,2,3-triazolyl) group, a 1-(1,2,3,4-tetrazolyl) group, an N-morpholinyl group, a 1,2,3,4-tetra-hydro-quinolyl group, a 2-oxo-1-pyrrolidinyl group, a 2-1H-pyridone group, a phthaladione group, and a 2-oxo-1-piperidinyl group. The hetero ring group may have been substituted by an alkyl group, an aryl group, an alkyloxy group, an aryloxy group, an acyl group, a sulfonyl group, an alkyl amino group, an aryl amiono group, an acyl amino group, a sulfon amino group, a carbamoyl group, a sulfamoyl group, an alkyl thio group, an aryl thio group, an ureide group, an alkoxy carbonyl group, an aryloxy carbonyl group, an imide group, a nitro group, a cyano group, a carboxyl group, or a halogen atom. The nitrogen-containing heterocyclic ring formed by Z or Z′ includes a pyrazole ring, an imidazole ring, a triazole ring and a tetrazole ring. It may have the substituents set forth above for R. A substituent (for example the R substituents on a heterocyclic ring in the formula [I] or formula [II] to [VII] described later having the following part: (R″, X and Z″ are equivalent to R, X and Z, respectively) forms a so called bis-type coupler, which is of course included in the present invention. A ring formed by Z, Z′, Z″ or Z¹ may have other condensed rings (e.g., cycloalkene). For example, in the formula [V], R⁵ and R⁶ may have been condensed, and in the formula [VI], R⁷ and R⁸, forming a ring (e.g., cycloalkene or benzene). The formula [I] can be represented by the following formula [II] to [VII]. In the above formula [II] to [VII], R¹ to R⁸ and X have the same meanings as above R and X. The following formula [VIII] is most desirable: In the formula, R¹, X and Z are equivalent to R, X and Z in the formula [I], respectively. The magenta coupler represented by the formula [II] is most desirable among those represented by formula [II] to [VII]. A substituent on the heterocyclic ring in the formula [I] to [VIII] is desirable if R in the formula [I] and R¹ in formula [II] to [VIII] meet the following condition 1, more desirable if they meet following conditions 1 and 2, and most desirable if they meet all of the following conditions 1, 2 and 3. Condition 1: The base atom coupled directly to the heterocyclic ring is a carbon atom. Condition 2: Only one or no hydrogen atom is coupled to the carbon atom. Condition 3: The carbon atom is single-bonded to the adjacent atoms. The following formula [IX] provides the most desirable substituents on the heterocyclic ring. In the formula, R⁹, R¹⁰ and R¹¹ refer to a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro-compound residue, a bridged hydrocarbon compound residue, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an mino group, an acyl amino group, a sulfon amide group, an imide group, an ureido group, a sulfamoyl amino group, an alkoxy carbonyl amino group, an aryloxy carbonyl amino group, an alkoxy carbonyl group, an aryloxy carbonyl group, an alkyl thio group, an aryl thio group, or a heterocyclic thio group. At least two of R⁹, R¹⁰ and R¹¹ cannot be a hydrogen atom. Two of R⁹, R¹⁰ and R¹¹, e.g., R⁹ and R¹⁰, may be coupled to each other to form a saturated or unsaturated ring (e.g., cycloalkane, cycloalkene or hetero ring). Further, R¹¹ may be coupled to the ring to form a bridged hydrocarbon compound residue. The groups represented by R⁹ to R¹¹ may contain substituents. The actual groups represented by R⁹ to R¹¹ and their substituents include the substituents represented by R in formula [I]. The rings formed by coupling, e.g., R⁹ and R¹⁰ and the bridged hydrocarbon compound residues formed by R⁹ to R¹¹ and their substituents include cycloalkyl, cycloalkenyl and the hetero ring bridged hydrocarbon compound residues represented by R in the formula [I], and their substituents. In the formula [IX], it is desirable that: (i) two of R⁹ to R¹¹ are alkyl groups; and (ii) one of R⁹ to R¹¹, e.g., R¹¹, is a hydrogen atom, and the other two, e.g., R⁹ and R¹¹ are coupled to each other to form cycloalkyl along with the base carbon atom. Further, in (i), it is most desirable that two of R⁹ to R¹¹ are alkyl groups and the other is a hydrogen atom or an alkyl group. The alkyl and cycloalkyl groups may contain a further substituent. The preferred alkyl and cycloalkyl groups and their substituents include the alkyl and cycloalkyl groups represented by R in the formula [I] and their substituents. The substituents on the rings formed by Z in the formula [I] and those formed by Z¹ in the formula [VIII], and R² to R⁸ in formula [II] to [VI] should preferably be those expressed by the following formula [X]: Formula [X] -R¹-SO₂-R² where R¹ represents alkylene, and R² represents alkyl, cycloalkyl or aryl. The alkylene indicated by R¹ should generally have the straight chain part consisting of more than one carbon, more preferably 3 or 6 carbons, and be straight chained or branched. The alkylene may have a substituent. Possible substituents include those that R in the formula [I] as an alkyl group may have. A desirable substituent is phenyl. Preferred alkylenes indicated by R¹ are: The alkyl group represented by R² may be straight-chained or branch. Preferred alkyl groups are methyl, ethyl, propyl, iso-propyl, butyl, 2-ethyl hexyl, octyl, dodecyl, tetradecyl, hexa-decyl, octa-decyl, and 2-hexyl-decyl. The cycloalkyl group represented by R² is preferably one having 5 or 6 members like cyclohexyl. Alkyl and cycloalkyl groups represented by R² may have the substituents set forth above for R¹. The aryl group represented by R² includes, e.g., phenyl and naphthyl. The aryl group may have a substituent. The substituents include, e.g., straight-chained or branched alkyl, as well as those set forth above for R¹. If there are two substituents or more they may be the same or different from one another. The following formula [XI] provides a very desirable compound covered by the formula [I]. where R and X are equivalent to R and X in the formula [I], respectively, and R¹ and R² are equivalent to R¹ and R² in the formula [X], respectively. Presented below are preferred compounds used in the present invention. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 The above couplers can be produced by referring to Journal of the Chemical Society, Perkin, I (1977), 2047 to 2052, U.S. Patent No. 3,725,067, Japanese Patent O.P.I. Publications No. 99437/1984, 42045/1983, 162548/1984, 171956/1984, 33552/ 1985, 43659/1985, 172982/1985 and 190779/1985. The coupler provided by the present invention is suitably in the range of 1 x 10⁻³ mols to 1 mol, preferably in the range of 1 x 10⁻² to 8 x 10⁻¹ mols, per 1 mol of silver halide. Further, the coupler provided by the present invention can be used together with other magenta couplers. The metal complex used in the present invention has a quenching rate constant of singlet oxygen of not less than 3 x 10⁷ M⁻¹ . sec. The quenching rate constant of singlet oxygen can be determined by Rublane's method of measuring optical fading described in Journal of Physical Chemistry, 83, 591 (1979). The method consists of irradiating the same energy light onto a Rublane's chloroform solution and another chloroform solution obtained by mixing the above solution and a compound to be measured. Assuming that the initial concentration of the Rublane's solution is [R], the concentration of the compound to be measured is [Q], the Rublane concentration of the Rublane's solution after the test is [R]O,F, and the Rublane concentration of the mixed solution after the test is [R]Q,F, the quenching rate constant of singlet oxygen (kg) is: kq= 5.3X10⁷([R] Q F -[R] O F )+1.7X10⁴ℓn([R] Q F /[R] O F ) [Q] ℓn([R]/[R] Q F ) The metal complex used in the present invention is a compound whose singlet oxygen quenching rate constant defined by the above expression is not less than 3 x 10⁷ M⁻¹ . sec⁻¹, preferably not less than 1 x 10⁸ M⁻¹ . sec⁻¹. The central metal of such metal complex is preferably a transition metal, especially Fe, Co, Ni, Pd or Pt, most preferably Ni. Preferably, the metal complex should have one of the following formulae: [XII] to [XV]. In the above formulae, [XII], [XIII] and [XIV], M represents a metal atom. X¹ and X² independently represent an oxygen atom, a sulfur atom or -NR⁷ (R⁷ represents a hydrogen atom, an alkyl group, an aryl group or a hydroxyl group). X³ represents a hydroxyl group or a mercapto group. Y represents an oxygen atom or a sulfur atom. R³, R⁴, R⁵ and R⁶ independently represent a hydrogen atom, a halogen atom, a cyano group, or an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group coupled directly or via a coupling group having a valence of 2 to a carbon atom. At least one of the combinations of R³ and R⁴, and R⁵ and R⁶, may form a ring having 5- or 6- members together with carbon atoms coupled with each other. [In the above formula, R²¹, R²², R²³ and R²⁴ independently represent a hydrogen atom, a halogen atom, a hydroxy group, a cyano group, or an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group coupled directly or indirectly via a coupling group having a valence of 2 to a carbon atom on the benzene ring. R²¹ may be coupled to R²², R²² to R²³, R²³ to R²⁴ to form a ring having 6-members. R²⁵ represents a hydrogen atom, an alkyl group or an aryl group. A represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxy group. M represents a metal atom.] In the above formulae [XII], [XIII] and [XIV], X¹ and X² may be the same or different from each other. They can represent an oxygen atom, a sulfur atom, or -NR⁷ (R⁷ represents a hydrogen atom, an alkyl group (e.g. a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, a t-butyl group, an i-butyl group or a benzyl group), an aryl group (e.g. a phenyl group, a tolyl group or a naphthyl group) or a hydroxyl group. Preferably, they are an oxygen atom or a sulfur atom, especially an oxygen atom. X³ in the formula [XIV] represents a mercapto group, or, preferably, a hydroxyl group. Y in formulae [XII], [XIII] and [XIV] (in the formula [XIV], two Y's may be the same or different from each other) represents an oxygen atom or, preferably, a sulfur atom. R³, R⁴, R⁵ and R⁶ in formulae [XII], [XIII] and [XIV], which may be the same or different from each other, represent a hydrogen atom, a halogen atom (fluorine, chlorine, bromine or iodine), a cyano group, an alkyl group (e.g. a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a dodecyl group or a hexadecyl group, each of which may be straight chained or branched) bonded to a carbon atom directly or via a divalent linkage group [e.g. -O-, -S-, -NR⁷′-{R⁷′ represents a hydrogen atom, a hydroxyl group, an alkyl group (e.g. a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, a t-butyl group or an i-butyl group), or an aryl group (e.g. a phenyl group, a tolyl group or a naphthyl group)}, -OCO-, -CO-, -NHCO-, -CONH-, -COO-, -SO₂NH-, -NHSO₂-, or -SO₂-, an aryl group (e.g. a phenyl group or a naphthyl group), a cycloalkyl group (e.g. a cyclopentyl group or a cyclohexyl group), or a heterocyclic ring (e.g. a pyridyl group, an imidazolyl group, a furyl group, a thienyl group, a pyrrolyl group, a pyrrolidinyl group, a quinolyl group or a morpholinyl group). Of these groups, the groups formed along with a coupling group with a valence of 2 by the alkyl group, aryl group, cycloalkyl group or heterocyclic ring group coupled via the coupling group to a carbon atom include, e.g. an alkoxy group (e.g. a straight chained or branched alkyl oxy group such as a methoxy group, an ethoxy group, an n-butyl oxy group or an octyl oxy group), an alkoxy carbonyl group (e.g. a straight chained or branched alkyloxy carbonyl group such as a methoxy carbonyl group, an ethoxy carbonyl group or an n-hexadecyloxy carbonyl group), an alkyl carbonyl group (e.g. a straight chained or branched alkyl carbonyl group such as an acetyl group, a valeryl group or a stearoyl group), an aryl carbonyl group (e.g. a benzoyl group), an alkyl amino group (e.g. a straight chained or branched alkyl amino group such as an N-butyl amino group, an N,N-di-butyl amino group or an N,N-di-n-octyl amino group), an alkyl carbamoyl group (e.g., a straight-chained or branched alkyl carbamoyl group such as an n-butyl carbamoyl group or a n-dodecyl carbamoyl group), an alkyl sulfamoyl group (e.g., a straight-chained or branched alkyl sulfamoyl group such as an n-butyl sulfamoyl group or a n-dodecyl sulfamoyl group), an alkyl acyl amino group (e.g., a straight-chained or branched alkyl carbonyl amino group such as an acetyl amino group or a palmitoyl amino group), an aryloxy group (e.g., a phenoxy group or a naphthoxy group), an aryloxy carbonyl group (e.g., a phenoxy carbonyl group or a naphthoxy carbonyl group), an aryl amino group (e.g., an N-phenyl amino group or an N-phenyl-N-methyl amino group), an aryl carbamoyl group (e.g., a phenyl carbamoyl group), an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group), and an aryl acyl amino group (e.g., a benzoyl amino group). R³, R⁴, R⁵ and R⁶ in formulae [XII], [XIII] and [XIV] may form a ring composed of 4 or 6 members along with a carbon atom to which at least one of combinations of R³ and R⁴, and R⁵ and R⁶ is coupled. The rings composed of 5 or 6 members formed along with a carbon atom to which at least of the combinations of R³ and R⁴, and R⁵ and R⁶ is coupled include, e.g., hydrocarbon and heterocyclic rings (e.g., a nitrogen containing 5- or 6-membered heterocyclic ring) having at least one unsaturated bond such as a cyclopentene ring, a cyclohexene ring or a benzene ring (containing a condensed benzene ring such as a naphthalene ring or an anthracene ring). The 5- or 6-membered ring can be provided with a substituent such as a halogen atom (fluorine, chlorine, bromine or iodine), a cyano group, an alkyl group (e.g., a straight-chained or branched alkyl group having 1 to 20 carbon atoms such as a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-octyl group, a t-octyl group or an n-hexadecyl group), an aryl group (e.g., a phenyl group or a naphthyl group), an alkoxy group (e.g., a straight-chained or branched alkyloxy group such as a methoxy group, an n-butoxy group or a t-butoxy group), an aryloxy group (e.g., a phenoxy group), an alkoxy carbonyl group (e.g., a straight-chained or branched alkyloxy carbonyl group such as an n-pentyloxy carbonyl group, a t-pentyloxy carbonyl group, an n-octyloxy carbonyl or a t-octyloxy carbonyl group), an aryloxy carbonyl group (e.g., a phenoxy carbonyl group), an acyl group (e.g., a straight-chained or branched alkyl carbonyl group such as an acetyl group or a stearoyl group), an acyl amino group (e.g., a straight-chained or branched alkyl carbonyl amino group including an acetamido group, or an aryl carbonyl amino group including a benzoyl amino group), an aryl amino group (e.g., an N-phenyl amino group), an alkyl amino group (e.g., a straight-chained or branched alkyl amino group such as an N-n-butyl amino group or an N,N-di-ethyl amino group), a carbamoyl group (e.g., a straight-chained or branched alkyl carbamoyl group such as an n-butyl carbamoyl group), a sulfamoyl group (e.g., a straight chained or branched alkyl sulfamoyl group such as an N,N-di-n-butyl sulfamoyl group or an N-n-dodecyl sulfamoyl group), a sulfon amide group (e.g., a straight-chained or branched alkyl sulfonyl amino group such as a methyl sulfonyl amino group, or an aryl sulfonyl amino group such as a phenyl sulfonyl amino group), a sulfonyl group (e.g., a straight-chained or branched alkyl sulfonyl group such as a mesyl group, or an aryl sulfonyl group such as a tosyl group), or a cycloalkyl group (e.g., a cyclohexyl group). The parts expressed by formulae [XII], [XIII] and [XIV] should preferably form a 5- or 6-membered ring along with an alkyl or aryl group represented by R³, R⁴, R⁵ and R⁶, or a carbon atom to which at least one of the combinations of R³ and R⁴, and R⁵ and R⁶ is coupled, and more preferably form a 6-membered ring along with a carbon atom to which the combinations of R³ and R⁴, and R⁵ and R⁶ are coupled, and most preferably form a benzene ring. In formulae [XII], [XIII] and [XIV], M represents a metal atom, which is preferably a transition metal atom, more preferably a nickel, copper, iron, cobalt, palladium or platinum atom, and most preferably a nickel atom. The compound which can be located at M as Z⁰ in the formula [XIII] is preferably an alkyl amine having a straight-chained or branched alkyl group, most preferably a di-alkyl amine or a tri-alkyl amine the total carbon count of the alkyl group being 2 to 36, or 3 to 24, including mono-alkyl amine such as butyl amine, octyl amine (e.g., t-octyl amine), dodecyl amine (e.g., n-dodecyl amine), hexadecyl amine or octanol amine; di-alkyl amine such as di-ethyl amine, di-butyl amine, di-octyl amine, di-dodecyl amine, di-ethanol amine or di-butanol anine; or tri-alkyl amine such as tri-ethyl amine, tri-butyl amine, tri-octyl amine, tri-ethanol amine, tri-butanol amine or tri-octanol amine. The preferred metal complex used in the present invention of formulae [XII], [XIII] and [XIV] possess the following formulae [XIIa], [XIIIa] and [XIVa]: In formulae [XIIa], [XIIIa] and [XIVa], M, X¹, X², X³, Y and Z⁰ have the same meaning as above. In these formulae, R¹¹, R¹², R¹³ and R¹⁴ refer to an alkyl group (e.g., a straight chained or branched alkyl group having 1 to 20 carbon atoms such as a methyl group, an ethyl group, an n-propyl group, an n-butyl group, an n-octyl group, a t-octyl group or an n-hexadecyl group); aryl group (e.g., a phenyl group or a naphthyl group); an alkoxy gropu (e.g., a straight chained or branched alkyloxy group such as a methoxy group, an n-butoxy group or a t-butoxy group); an aryloxy gruop (e.g., a phenoxy gorup); an alkoxy carbonyl group (e.g., a straight chained or branched alkyloxy carbonyl group such as an n-pentyloxy carbonyl group, a t-pentyloxy carbonyl group, an n-octyloxy carbonyl group or a t-octyloxy carbonyl group); an aryloxy carbonyl group (e.g., a phenoxy carbonyl group); an acyl group (e.g., a straight chained or branched alkyl carbonyl group such as an acetyl group or a stearoyl group); an acyl amino group (e.g., a straight chained or branched alkyl carbonyl amino group such as an acetamide group, or an aryl carbonyl amino group such as a benzoyl amino group); an aryl amino group (e.g., an N-phenyl amino group); an alkyl amino group (e.g., a straight chained or branched alkyl amino group such as an N-n-butyl amino group or an N,N-di-ethyl amino group); a carbamoyl group (e.g., a straight chained alkyl carbamoyl group such as an n-butyl carbamoyl group); a sulfamoyl group (e.g., a straight chained or branched alkyl sulfamoyl group such as an N,N-di-n-butyl sulfamoyl group or an N-n-dodecyl sulfamoyl group); a sulfon amide group (e.g., a straight chained or branched alkyl sulfonyl amino group such as a methyl sulfonyl amino group, or an aryl sulfonyl amino group such as a phenyl sulfonyl amino group); a sulfonyl group (a straight chained or branched alkyl sulfonyl group such as a mesyl group, or an aryl sulfonyl group such as a tosyl group); or a cycloalkyl group (e.g., a cyclohexyl group). m and n refer to any number from 0 to 4. Desirable among the compounds expressed by formulae [XIIa], [XIIIa] and [XIVa] are those having the formula [XIIIa]. Most desirable among the compounds expressed by the formula [XIIIa] are those having the formula [XIIIb]. In the formula [XIIIb], M, X¹, X², Y, R¹¹, R¹², m and n have the same meaning as above. R¹⁵, R¹⁶ and R¹⁷ refer to a hydrogen atom, an alkyl group (e.g., a butyl group, an octyl group or a stearyl group), or an aryl group (e.g., a phenyl group or naphthyl group). At least two of R¹⁵, R¹⁶ and R¹⁷ are an alkyl group or an aryl group. In the formula [XV], the halogen atoms represented by R²¹ R²², R²³ and R²⁴ are a fluorine atom, a chlorine atom, a bromine atom or an iodine atom. The alkyl groups represented by R²¹, R²², R²³ and R²⁴, which preferably have 1 to 19 carbon atoms, may be a straight chained or branched alkyl group, and may have a substituent. The aryl groups represented by R²¹, R²², R²³ and R²⁴, which preferably have 4 to 14 carbon atoms, may contain a substituent. The heterocyclic ring groups represented by R²¹, R²², R²³ and R²⁴, which are preferably 5- or 6-membered rings, may contain a substituent. The cycloalkyl groups represented by R²¹ R²², R²³ and R²⁴, which are preferably 5- or 6-membered ring groups, may contain a substituent. The 6-membered rings former by coupling of R²¹ and R²² include: The 6-membered ring formed by the combination of R²² and R²³ or R²³ and R²⁴ is preferably a benzene ring, which may contain a substituent or may be coupled to another compound. The alkyl groups represented by R²¹, R²², R²³ and R²⁴ include e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a t-butyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, a tetra-decyl group, a hexa-decyl group and an octa-decyl group. The aryl groups represented by R²¹, R²², R²³ and R²⁴ include, e.g., a phenyl group and a naphthyl group. The heterocyclic ring groups represented by R²¹, R²², R²³ and R²⁴ are preferably 5- or 6-membered heterocyclic ring groups containing at least one nitrogen, oxygen or sulfur atom as the hetero atom, including, e.g., a furyl group, a hydrofuryl group, a thienyl group, a pyrrolyl group, a pyrrolidyl group, a pyridyl group, an imidazolyl group, a pyrazolyl group, a quinolyl group, an indolyl group, an oxaxolyl group, and a thiazolyl group. The cycloalkyl groups represented by R²¹, R²², R²³ and R²⁴ include, e.g., a cyclopentyl group, a cyclohexyl group, a cyclohexenyl group, and a cyclohexadienyl group. The 6-membered rings formed by a combination of R²¹, R²², R²³ and R²⁴ include ) e.g., a benzene ring, a naphthalene ring, an iso-benzothiophene, an iso-benzofuran ring and an iso-indone ring. The alkyl groups, cycloalkyl groups and aryl groups, and the heterocyclic ring groups represented by R²¹, R²², R²³ and R²⁴ may be coupled to a carbon atom on the benzene ring via a coupling group having a valence of 2, e.g., an oxy-group (-O-), a thio-group (-S-), an amino group, an oxy-carbonyl group, a carbonyl group, a carbamoyl group, a sulfamoyl group, a carbamoyl group, a sulfonyl amino group, a sulfonyl group or a carbonyloxy group. The alkyl groups represented by R²¹, R²², R²³ and R²⁴ are, e.g., coupled to a carbon atom on the benzene ring via a coupling group having a valence of 2, providing an alkoxy group (e.g., a methoxy group, an ethoxy group, a butoxy group, a propoxy group, a 2-ethyl hexyloxy group, an n-decyloxy group, an n-dodecyloxy group or an n-hexa-decyloxy group); an alkoxy carbonyl group (e.g., a methoxy carbonyl group, an ethoxy carbonyl group, a butoxy carbonyl-group, an n-decyloxy carbonyl group or an n-hexa-decyloxy carbonyl group); an acyl group (e.g., acetyl group, a valeryl group, a stearoyl group, a benzoyl group or a toluoyl group); an acyloxy group (e.g., an acetoxy group or a hexadecyl carbonyloxy group); an alkyl amino group (e.g., an n-butyl amino group, an N,N di-ethyl amino group or a N,N-di-decyl amino group); an alkyl carbamoyl group (e.g., a butyl carbamoyl group, an N,N-di-ethyl carbamoyl group or an b-dodecyl carbamoyl group); an alkyl sulfamoyl group (e.g., a butyl sulfamoyl group, an N,N-di-ethyl sulfamoyl group or an n-dodecyl sulfamoyl group); a sulfonyl amino group (e.g., a methyl sulfonyl amino group or a butyl sulfonyl amino group); a sulfonyl group (e.g., a mesyl group or an ethane sulfonyl group); or acyl amino group (e.g., an acetyl amino group, a valeryl amino group, a palmitoyl amino group, a benzoyl amino group or a toluoyl amino group). The cycloalkyl groups represented by R²¹, R²², R²³ and R²⁴ are, e.g., coupled to a carbon atom on the ring via a coupling group with a valence of 2, providing an cyclohexyloxy group, a cyclohexyl carbonyl group, a cyclohexyloxy carbonyl group, a cyclohexyloxy carbonyl group, a cyclohexyl amino group, a cyclohexenyl carbonyl group, or a cyclohexenyloxy group. The aryl groups represented by R²¹, R²², R²³ and R²⁴ are, e.g., coupled to a carbon atom on the ring via a coupling group with a valence of 2, providing an aryloxy group (e.g., a phenoxy group or a naphthoxy group); an aryloxy carbonyl group (e.g., a phenoxy carbonyl group or a naphthoxy carbonyl group); an acyl group (e.g., a benzoyl group or a naphthoyl group); an anilino group (e.g., a phenyl amino group, an N-methyl anilino group or an N-acetyl anilino group); an acyloxy group (e.g., a benzoyloxy group or a toluoyloxy group); an aryl carbamoyl group (e.g., a phenyl carbamoyl group); an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group); an aryl sulfonyl amino group (e.g., a phenyl sulfonyl amino group or a p-tolyl sulfonyl amino group); an aryl sulfonyl group (e.g., a benzene sulfonyl group or a tolyl sulfonyl group); or an acyl amino group (e.g., a benzoyl amino group). The 6-membered rings formed by coupling of an alkyl, aryl, heterocyclic ring or cycloalkyl groups represented by R²¹, R²², R²³ and R²⁴, or a combination of R²¹ and R²², R²² and R²³ or R²³ and r²⁴ may be substituent by a halogen atom (e.g., chlorine, bromine or fluorine), a cyano group, an alkyl group (e.g., a methyl group, an ethyl group, an i-propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, a tetra-decyl group, a hexa-decyl group, a hepta-decyl group, an octa-decyl group or a methoxy ethoxy ethyl group), an aryl group (e.g., a phenyl group, a tolyl group, a naphthyl group, a chloro-phenyl group, a methoxy phenyl group or an acetyl phenyl group), an alkoxy group (e.g., a methoxy group, an ethoxy group, a butoxy gruop, a propoxy group or a methoxy ethoxy group), an aryloxy group (e.g., a phenoxy group, a tolyloxy group, a naphthoxy group or a methoxy phenoxy group), an alkoxy carbonyl group (e.g., a methoxy carbonyl group, a butoxy carbonyl group or a phenoxy methoxy carbonyl group), an aryloxy carbonyl group (e.g., a phenoxy carbonyl group, a tolyloxy carbonyl group or a methoxy phenoxy carbonyl group), an acyl group (e.g., a formyl group, an acetyl group, a valeryl group, a stearoyl group, a benzoyl group, a toluoyl group, a naphthoyl group or a p-methoxy benzoyl group), an acyloxy group (e.g., an acetoxy group or an acyloxy group), an acyl amino group (e.g., an acetamide group, a benzamide group or a methoxy acetamide gruop), an anilino group (e.g., a phenyl amino group, an N-methyl anilino group or an N-acetyl anilino group), an alkyl amino group (e.g., an n-butyl amino group, an N,N-di-ethyl amino group or a 4-methoxy-n-butyl amino group), a carbamoyl group [e.g., an n-butyl carbamoyl group, an N,N-di-ethyl carbamoyl group, an n-butyl sulfamoyl group, an N,N-di-ethyl sulfamoyl group, an n-ddodecyl sulfamoyl group or an N-(4-methoxy-n-butyl) sulfamoyl group], a sulfonyl amino group (e.g., a methyl sulfonyl amino group, a phenyl sulfonyl amino group or a methoxy methyl sulfonyl amino group), or a sulfonyl group (e.g., a mesyl group, a tocyl group or a methoxy methane sulfonyl group). The alkyl groups represented by R²⁵ and A, which may be straight chained or branched, may contain a substituent. These alkyl groups, excluding the carbon atoms on the substituent, comprise preferably 1 to 20 carbon atoms, including, e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, a tetra-decyl group, a hexa-decyl group, a hepta-decyl group, and an octa-decyl group. The aryl groups represented by R²⁵ and A may contain a substituent, and comprise preferably, excluding the carbon atoms on the substituent, 6 to 16 carbon atoms, including, e.g., a phenyl group, a tolyl group or a naphthyl group. They also may have two groups coupled via A. In the formula, M refers to a metal atom, being preferably a transition metal atom, more preferably Cu, Co, Ni, Pd, Fe or Pt, most preferably Ni. As A, the hydroxy group is desirable. Among the complexes represented by the above formula [XV], R should be preferably an alkyl, cycloalkyl, aryl or heterocyclic ring group attached via an oxy-, thio- or carbonyl group, a hydroxy group, or a fluorine atom, and at least one of the groups represented by R²², R²³ or R²⁴ is a hydrogen atom, a hydroxy group, an alkyl group or an alkoxy group. More preferably, R²⁵ is a hydrogen atom, and the total number of carbon atoms in the groups represented by R²¹, R²² or R² is not less than 4. specific metal complexes which can be used in the present invention include the following compounds: Sample metal complexes The metal complexes represented by above formulae [XII] to [XIV] can be produced by methods disclosed in the British Patent No. 858,890 and the West German OLS Patent No. 2,042,652. The metal complexes represented by the formula [XV] can be produced by the method described in E.G. Cox, F.W. Pinkard, W. Wa rdlaw and K.C. Webster, J. Chem. Soc., 1935, 459. The metal complexes used in the present invention, depending on its nature, should be used preferably in the range of 0.1 to 2 mols with respect to 1 mol of the magenta coupler represented by the formula [I], more preferably in the range of 0.5 to 1 mols. Presented below is a description of the compound represented by the formula [a-2]. In the present invention, the number of carbon atoms in the alkyl group represented by R⁴ in the formula [a] is 1 to 12, while the number of carbon atoms in the alkenyl or alkynyl group is 2 to 4. The organic groups (having a valence of 1) represented by R′ and R″ include, e.g., alkyl, alkenyl, alkynyl and aryl groups. The group represented by R⁴ is preferably a hydrogen atom, an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a chloro-methyl group, a hydroxy methyl group or a benzyl group), an alkyl group (e.g., a vinyl group, an aryl group or a iso-propenyl group), an alkynyl group (e.g., a ethynyl group or a provinyl group), or a -COR″ group. The group represented by R″ is preferably an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group or a benzyl group), an alkenyl group (e.g., a vinyl group, an aryl group or an iso-propenyl group), an alkynyl group (e.g., an ethynyl or a propynyl group), or an aryl group (e.g., a phenyl group or a tolyl group). The alkyl groups represented by R⁵, R⁶, R⁵′, R⁶′ and R⁹ are preferebly straight chained or branched alkyl groups having 1 to 5 carbon atoms, more preferably methyl groups. In R⁷ and R⁸, the organic groups (having a valence of 1) represented by R¹⁰ include, e.g., an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, an octyl group, a dodecyl group or an octa-decyl group), an alkenyl group (e.g., a vinyl group), an alkynyl group (e.g., an ethynyl group), an aryl group (e.g., a phenyl group or a naphthyl group), an alkyl amino group (e.g., an ethyl amino group), and an aryl amino group (e.g., an anilino group). The heterocyclic groups formed by R⁷ and R⁸ together include, e.g., where R¹⁴ refers to a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group. In the present invention, it is desirable that the compounds represented by the formula [a-2] have the following formula [a-2′]: R¹⁵ represents an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group or a benzyl group), an alkenyl group (e.g., a vinyl group, an aryl group or an iso-propenyl group), an alkynyl group (e.g., an ethynyl group or a propenyl group), or an acyl group (e.g., a formyl group, an acetyl group, a propionyl group, a butyryl group, an acryloyl group, a propioloyl group, a methacryloyl group or a crotonoyl group). R¹⁵ is more preferably a methyl group, an ethyl group, a vinyl group, an aryl group, a propynyl group, a benzyl group, an acetyl group, a propionyl group, an acryloyl group, a methacryloyl group, or a crotonoyl group. Specific examples of compounds of formula [a-2] include the following compounds: The compound represented by the formula [a] is preferably used in an amount of 0.1 to 2 mols with respect to 1 mol of the magenta coupler represented by the formula [I], more preferably 0.5 to 1 mols. The mole ratio of the metal complex to the compound represented by [a] is preferably 1:3 to 3:1. In the present invention the compound represented by the a formula [a-1] is used singly or together with a compound represented by the formula [a-2]. In the above formula, R¹ and R² refer to an alkyl group. R³ refers to an alkyl group, a -NR′R″ group, a -SR′ group (R′ represents an organic group having a valence of 1), or a -COOR″ group (R″ represents a hydrogen atom or an organic group having a valence of 1). m refers to any integer from 0 to 3. In the present invention, the alkyl groups represented by R¹ and R² in the formula (b) are preferably those having 1 to 12 carbon atoms, more preferably those having 3 to 8 carbon atoms branched at the alpha position. R¹ and R² are preferably a t-butyl group or a t-pentyl group. The alkyl group represented by R³ is straight chained or branched, being, e.g., a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, an octyl group, a nonyl group, a dodecyl group, or an octa-decyl group.. The alkyl may contain a substituent including a halogen atom, a hydroxyl group, a nitro group, a cyano group, an aryl group (e.g., a phenyl group, a hydroxy phenyl group or a 3,5-di-t-butyl-4-hydroxy phenyl group, a 3,5-di-t-pentyl-4-hydroxy phenyl group), an amino group (e.g., a di-methyl amino group, a d-ethyl amino group or a 1,3,5-tri-alizinyl amino group), an alkyloxy carbonyl group (e.g., a methoxy carbonyl group, an ethoxy carbonyl group, a propyloxy carbonyl group, a butoxy carbonyl group, a pentyloxy carbonyl group, an octyloxy carbonyl group, a nonyloxy carbonyl group, a dodecyloxy carbonyl group or an octa-decyloxy carbonyl group), an aryloxy carbonyl group (e.g., a phenoxy carbonyl group), a carbamoyl group (e.g., an alkyl carbamoyl group such as a methyl carbamoyl group, an ethyl carbamoyl group, a propyl carbamoyl group, a butyl carbamoyl group or a heptyl carbamoyl group, an aryl carbamoyl group such as a phenyl carbamoyl group, or a cycloalkyl carbamoyl group such as a cyclohexyl carbamoyl group), an isocyanuryl group, or a heterocyclic group such as a 1,3,5-tri-azinyl group. The amino group represented by R³ includes, e.g., an alkyl amino group such as a di-methyl amino group, a di-ethyl amino group or a methyl ethyl amino group; an aryl amino group such as a phenyl amino group or a hydroxyl phenyl amino group; a cycloalkyl amino group such as a cyclohexyl group; or a heterocyclic amino group such as a 1,3,5-tri-azinyl amino group or an iso-cyanuryl group. The organic groups with a valence of 1 represented by R′ and R″ include, e.g., an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, an amyl group, a decyl group, a dodecyl group, a hexa-decyl group or an octa-decyl group); an aryl group (e.g., a phenyl group or a naphthyl group); a cycloalkyl group (e.g., a cyclohexyl group); or a heterocyclic group (e.g., a, 1,3,5-tri-azinyl grop or an iso-cyanuryl grup). The organic groups may contain a substituent including, e.g., a halogen atom (e.g., fluorine, chlorine or bromine); a hydroxyl group; a nitro group; a cyano group; an amino group; an alkyl group (e.g., a methyl group, an ethyl group, an i-propyl group, a t-butyl group or a t-amyl gruop); an aryl group (e.g., a phenyl group or a tolyl gruop); an alkenyl group (e.g., an aryl group); an alkyl carbonyloxy group (e.g., a methyl carbonyloxy group, an ethyl carbonyloxy group or a benzyl carbonyloxy group); or an aryl carbonyloxy group (e.g., a benzoyloxy group). In the present invention, it is preferable that the compound expressed by the formula [a-1] has the structure as shown below. [In the formula, R¹¹ and R¹² refer to a straight chained or branched alkyl group having 3 to 8 carbon atoms, in particular a t-butyl group or a t-pentyl group. R¹³ refers to an organic group with a valence of k. k refers to any integer of 1 to 6.] The organic group with a valence of k represented by R¹³ includes, e.g., an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, an octyl group, a hexa-decyl group, a methoxy ethyl group, a chloromethyl group, a 1,2-di-bromoethyl group, a 2-chloroethyl group, a benzyl group or a phenethyl group; an alkenyl group such as an allyl group, a propenyl group or butenyl group; a poly-valent unsaturated hydrocarbon group such as ethylene, tri-methylene, propylene, hexa-methylene or 2-chloro-tri-methylene; an unsaturated hydrocarbon group such as glyceryl, di-glyceryl, penta-erythrityl or di-penta-erythrityl; an alicyclic hydrocarbon group such as a cyclopropyl group, a cyclohexyl group or a cyclohexenyl group; an aryl group such as a phenyl group, a p-octyl phenyl group, a 2,4-di-methyl phenyl group, a 2,4-di-t-butyl phenyl grup, a 2,4-di-t-pentyl phenyl group, a p-chloro-phenyl gruop, a 2,4-di-bromo-phenyl group or a naphthyl group; an arylene group such as a 1,2-, 1,3,- or 1,4-phenylene group, a 3,5-di-methyl-1,4-phenylene group, a 2-t-butyl-1,4-phenylene group, a2-chloro-1,4-phenylene group or a naphthylene group; or a 1,3,5-tri-substituted benzene group. In addition to the above groups, R¹³ may be an organic group having a valence of k coupled via an -O-, -S- or -SO₂ - group. More preferably, R¹³ is a 2,4-di-t-butyl phenyl group, a 2,4-di-t-pentyl phenyl group, a p-octyl phenyl group, a p-dodecyl phenyl group, a 3,5-di-t-butyl-4-hydroxyl phenyl group, or a 3,5-di-t-pentyl-4-hydroxyl phenyl group. k is preferably any integer of 1 to 4. In the present invention, the above formula [a-1] includes the following compounds: The compound represented by the formula [a-1] is preferably used in an amount of 0.1 to 2 mols, more preferably 0.5 to 1 mols, with respect to 1 mol of the magenta coupler represented by the formula [I]. As with a typical hydrophobic compound, a solid duffusion method, a latex diffusion method or an O/W emulsification diffusion method, for example, can be used to add the magenta coupler and metal complex used in the present invention, and the compounds represented by formulae [a-1] and/or [a-2] to silver halide sensitized photographic material. Of these methods, the appropriate one can be selected in accordance with the chemical structure of the hydrophobic compound, the coupler. The O/W emulsification diffusion method diffuses hydrophobic compounds such as couplers. The hydrophobic compound is dissolved in an organic solvent having a high boiling point (not less than 150 degrees C) using a low boiling point and/or water-soluble organic solvent if necessary; it is emulsified and diffused into a hydrophilic binder such as a gelatin containing solution using a diffusion means including an agitator, homogenizer, colloid mill, flow mixer or supersonic device; and then, is added into a hydrophilic colloid layer. A process may be incorporated which eliminates the dispersion or the low boiling point organic solvent on diffusion. Used as the high boiling point organic solvent are organic solvents having a boiling point of not less than 150 degrees C such as phenol derivatives, phthalic esters, phosphoric esters, citrates, benzoates, alkyl amides, fatty esters, and trimesic esters that do not react with the oxidant of the developing agent. In the present invention, the organic solvent having a high boiling point is preferably a compound having a dielectric constant of not more than 6.0 such as an ester including a phthalic ester or phosphoric ester, organic amide, ketone, or a hydrocarbon compound with a dielectric constant of not more than 6.0. Preferably, such a compound should have a dielectric constant of not less than 1.9 and a vapor pressure of not more than 0.5 mmHg at a temperature of 100 degrees C. More preferably, such compound is a phthalic ester or phosphoric ester in the organic solvent having a high boiling point. Further, the organic solvent having a high boiling point may consist of more than one material. The dielectric constants mentioned are those determined at a temperature of 30 degrees C. The phthalic ester that is preferably used in the present invention is shown by the following formula: In the above formula, R¹ and R² refer to an alkyl group, an alkenyl group, or an aryl group, provided that the groups represented by R¹ and R² have 8 to 32 carbon atoms more preferably 16 to 24 carbon atoms in total. In the present invention, the alkyl groups represented by R¹ and R² in the formula [C] may be straight chained or branched, being, e.g., a butyl group, a pentyl group, a hexyl gruop, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tri-decyl group, a tetra-decyl group, a penta-decyl group, a hexa-decyl group, a hepta-decyl group, or an octadecyl group. The aryl groups represented by R¹ and R² include, e.g., a phenyl group or a naphthyl group, and the alkenyl group includes, e.g., a hexenyl group, heptenyl group, or an octa-decenyl group. These alkyl, alkenyl and aryl groups may have one or more substituents. The substituents for the alkyl and alkenyl groups include, e.g., a halogen atom, an alkoxy group, an aryl group, an aryloxy group, alkenyl group, and an alkoxy carbonyl group. The substituents for the aryl group include, e.g., a halogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an alkenyl group, and an alkoxy crabonyl group. The phosphoric ester that is preferably used is expressed by the following formula [d]: In the above formula, R³, R⁴ and R⁵ refer independently to an alkyl group, an alkenyl group, or an aryl group, provided that the total carbon atom count is 24 to 54. The alkyl groups represented by R³, R⁴ and R⁵ in the formula [d] include, e.g., a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tri-decyl group, a tetra-decyl group, a penta-decyl group, a hexa-decyl group, a hepta-decyl group, an octa-decyl group, and a nondecyl group. The aryl groups include, e.g., a phenyl group and a naphthyl group. The alkenyl groups include, e.g., a hexenyl group, a heptenyl group and an octa-decenyl group. These alkyl, alkenyl and aryl groups may have one or more substituents. Preferably, R³, R⁴ and R⁵ are an alkyl group, being, e.g., a 2-ethyl hexyl group, an n-octyl group, a 3,5,5-tri-methyl hexyl group, an n-nonyl group, an n-decyl group, a sec-decyl group, a sec-dodecyl group, or a t-octyl group. The present invention covers, but is not limited to, the following typical organic solvents: Typical organic solvents These organic solvents are typically used in an amount from 5 to 100 weight percent, preferably 30 to 80 weight percent, with respect to the total amount of the metal complex and the compound represented by the formula [a-1] and/or [a-2]. The magenta coupler should preferably be dissolved in the same O/W as the metal complex and the compound represented by the formula [a-1] and/or [a-2]. An anionic, nonionic or cationic surface active agent can be used as the diffusion promoter to diffuse the hydrophobic compound including the coupler into the solvent having a high boiling point which may contain a low boiling point solvent. The light-sensitive silver halide photographic material provided by the present invention includes, e.g., a negative or positive color film and a color photographic paper, especially the latter for direct viewing. The light-sensitive silver halide photographic material can involve mono- and multi-color applications. For the substractive color process color reproduction, the light-sensitive silver halide photographic material has a structure comprising silver halide emulsion layers containing magenta, yellow and cyan couplers as the photographic dye-forming couplers, and non-sensitized layers, coated on a support in an appropriate layer order. The number of such layers and the layer order may be changed depending on the performance to be achieved. For the light-sensitive silver halide photographic multicolor material, a very desirable layer arrangement is such that a yellow dye image-forming layer, an intermediate layer, a magenta dye image-forming layer, an intermediate layer, a cyan dye image-forming layer, an intermediate layer, and a protective layer are arranged on the support in that order. As the silver halide emulsion for the silver halide sensitized photographic material, any of silver bromide, silver iodobromide, silver iodo-chloride, silver bromo-chloride and silver chloride can be used as silver halide. Silver halide grains to be used for the silver halide emulsion can be obtained by e.g. an acid method, a neutral method or an ammonia method. Such grains may be grown together, or after forming base grains. Forming base grains and growing grains may be made by the same method or by different methods. For the silver halide emulsion, halide ions and silver ions may be mixed with each other, or the former may be added to the latter or vice versa. Allowing for the critical growth rate of silver halide crystals, such grains may be developed by mixing halide and silver ions while controlling the pH and pAg in the mixing vessel. After growth, a conversion method may be used to change the halogen composition of the grains. The silver halide grain size, the grain shape, the grain size distribution, and the grain growth rate can be controlled using a silver halide solvent if necessary during production of the silver halide emulsion. To the silver halide grains to be used for the silver halide emulsion, metal ions can be added during the grain forming and/or growing process using a cadmium salt, zinc salt, lead salt, thallium salt, iridium salt or complex salt, rhodium salt or complex salt, iron salt or complex salt, to be incorporated inside the grains and/or on the grain surfaces. Further, under an appropriate reductive atmosphere, reductive sensitizing nuclei can be provided inside the grains and/or the grain surfaces. For the silver halide emulsion, unnecessary soluble salts may or may not be removed after termination of the growth of the silver halide grains. The method described in Research Disclosure No. 17643 can be used to remove the salts. For the silver halide grain to be used for the silver halide emulsion, its core and surface may be composed of one or more different materials. The silver halide grain to be used for the silver halide emulsion may be such that latent images are formed mainly on its usrface or mainly inside it. The silver halide grain to be used for the silver halide emulsion may consist of regular crystals or irregular bulb-like or tabular crystals. Such grains may have any {100} surface to {111} surface ratio. Further, such grains may have composite or combined crystals. The silver halide emulsion used in this invention may be composed of more than one kinf of silver halide emulsion. The silver halide emulsion can be chemically sensitized by a sulfur sensitizing method that uses a compound containing sulfur reactive with silver ions, and active gelatin, a selenium sensitizing method that uses a selenium compound, a reduction sensitizing method that uses a reductive material, and/or a noble metal sensitizing method that uses gold or other noble metal compounds. The silver halide emulsion can be sensitized optically over a desired wave length region by a dye known as a sensitizing dye in the photographic industry. A single sensitizing dye, or a plurality of sensitizing dyes may be used. A dye that has no sensitizing effect, or a sensitizer which absorbs substantially no visible light and enhances the sensitizing effect of a sensitizing dye may be contained in the emulsion along with the sensitizing dye. To the silver halide emulsion, a compound known as a fog inhibitor or a stabilizer in the photographic industry can be added during the manufacture of the sensitized material or the storage of such material, or during chemical maturing and/or on termination of chemical maturing and/or after termination of chemical maturing before application of the silver halide emulsion, to prevent fog from being produced during photographic processing and/or to stabilize photographic performance. As the binder (or protective colloid) for the silver halide emulsion, gelatin can be used; in addition, a hydrophilic colloid such as a monomeric or interpolymeric hydrophilic material including gelatin derivatives, a graft polymer containing gelatin, protein, sugar derivatives, and cellulose derivatives can be used. The photographic emulsion layer made of sensitized material that uses the silver halide emulsion, and the other hydrophilic colloid layers can be hardened using a hardener. The hardner should be preferably added in an amount sufficient to harden the sensitized material to the extent that any additional hardener needs not be added to a processing liquid. But it is also possible to add a hardener to a processing liquid. A plasticizer can be added to enhance the flexibility of the silver halide emulsion layer made of sensitized material that uses the silver halide emulsion, and/or of the other hydrophilic colloid layers. Latex consisting of synthetic polymer not water-soluble or difficult to dissolve can be contained in the photographic emulsion layer to improve dimensional stability. For the emulsion layer of the silver halide sensitized photographic color material, a dye forming couler is used which forms dyes through a coupling reaction with the oxidant of the aromatic primary amine developer (e.g., a p-phenylene diamine derivative or an amino phenol derivative) in the color developing process. In general, the dye forming coupler is selected so that dyes which absorb light having given spectra are provided in respective emulsion layers. For a blue light sensitive emulsion layer, a yellow dye-forming is used; for a green light sensitive emulsion layer, a magenta dye-forming coupler; and for a red light sensitive emulsion layer, a cyan dye-forming coupler. Depending on the intended purpose, however, the silver halide sensitized photographic color material may be made in other ways. Typical cyan dye-forming couplers used in the present invention includes 2- or 4-equivalent couplers of the phenol or naphthol type, as described in e.g., U.S. Patent Nos. 2,306,410, 2,356,475, 2,362,598, 2,367,531, 2,369,929, 2,423,730, 2,474,293, 2,476,008, 2,498,466, 2,545,687, 2,728,660, 2,772,162, 2,895,826, 2,976,146, 3,002,836, 3,419,390, 3,446,622, 3,476,563, 3,737,316, 3,758,308 and 3,839,044, British Patent Nos. 478,991, 945,542, 1,084,480, 1,377,233, 1,388,024 and 1,543,040, and Japanese Patent O.P.I. Publication Nos. 37435/1972, 10135/1975, 25228/1975, 112038/1975, 117422/1975, 130441/1975, 6551/1976, 37647/1976, 52828/1976, 108841/1976, 109630/1978, 48237/1979, 66129/1979, 131931/1979 and 32071/1980. Preferably, the cyan dye forming coupler to be used for the silver halide emulsion has the following formulae [C-1] or [C-2]. In the formula, R¹ represents an alkyl group or an aryl group. R² represents an alkyl group, a cycloalkyl group, an aryl group, or a heterocyclic group. R³ represents a hydrogen atom, a halogen atom, an alkyl group, or an alkoxy group. R³ may form a ring together with R¹ (and the atoms attached to it). Z represents a hydrogen atom, or a group which is capable of being split off upon coupling reaction with the oxidant of an aromatic primary amine color developing agent. In the formula, R⁴ represents a straight chain or branched alkyl group having 1 to 4 carbon atoms. R⁵ represents a ballast group. Z is the same as Z in the formula [C-1]. Most preferably, R⁴ is a straight chain or branched alkyl group having 2 to 4 carbon atoms. the alkyl group represented by R¹ in the formula [C-1] is, e.g., a methyl, ethyl, isopropyl, butyl, pentyl, octyl, nonyl, or tri-decyl group, which can be branched. The aryl group is, e.g., a phenyl or naphthyl group. The groups represented by R¹ may contain one or more substituents. Typical substituents, e.g., for the phenyl group include a halogen atom (e.g., fluorine, chlorine or bromine), an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group or a dodecyl group), a hydroxyl group, a cyano group, a nitro group, an alkoxy group (e.g., a methoxy gruop or an ethoxy group), an alkyl sulfon amide group (e.g., a methyl sulfon amide group or an octyl sulfon amide group), an aryl sulfon amide group (e.g., a phenyl sulfon amide group or a naphthyl sulfon amide group), an alkyl sulfamoyl group (e.g., a butyl sulfamoyl group), an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group), an alkyloxy carbonyl group (e.g., a methyloxy carbonyl group), an aryloxy carbonyl group (e.g., a phenyloxy carbonyl group), an amino sulfon amide (e.g., an N,N-di-methyl amino sulfon amide group), an acyl amino group, a carbamoyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, a sulfo group, an aryloxy group, an alkoxy group, a carboxyl group, an alkyl carbonyl group, and an aryl carbonyl group. More than one of these substituents can be present on the phenyl group. The halogen atom represented by R³ is, e.g., fluorine, chlorine or bromine. The alkyl group is, e.g., a methyl group, an ethyl group, a propyl group, a butyl group, or a dodecyl group. The alkoxy group is, e.g., a methoxy group, an ethoxy group, a propyloxy group, or a butoxy group. R³ may form a ring along with R¹. The alkyl group represented by R² in the formula [C-1] uncludes a poly-fluoro alkyl group substituted e.g., by a methyl group, an ethyl group, a butyl group, a hexyl group, a tri-decyl group, a penta-decyl group, a heptadecyl group or a fluorine atom. The aryl group represented by R² is, e.g., a phenyl group or a naphthyl group, preferably a phenyl group. The heterocyclic group represented by R² includes, e.g., a pyridyl group or a furan group. The cyclo alkyl group represented by R² includes, e.g., a cyclopropyl group or a cyclohexyl group. The groups represented by R² may have one or more substituents. Typical substituents include, e.g., for the phenyl group a halogen atom (e.g., fluorine, chlorine or bromine), an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group or a dodecyl group), a hydroxyl group, a cyano group, a nitro group, an alkoxy group (e.g., a methoxy gruop or an ethoxy gruop), an alkyl sulfon amide group (e.g., a methyl sulfon amide gruop or an octyl sulfon amide group), an aryl sulfon amide group (e.g., a phenyl sulfon amide group or a naphthyl sulfon amide group), an alkyl sulfamoyl group (e.g., a butyl sulfamoyl group), an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group), an alkyloxy carbonyl group (e.g., a methyloxy carbonyl group), an aryloxy carbonyl group (e.g., a phenyloxy carbonyl group), an amino sulfon amide group, an acyl amino group, a carbamoyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, a sulfo group, an aryloxy group, an alkoxy group, a carboxyl group, an alkyl carbonyl group, and an aryl carbonyl group. More than one of these substituents may be present in a phenyl group. Preferred groups represented by R² include a polyfluoro alkyl group or a phenyl group, or a phenyl group having as substituents one or more halogen atoms, alkyl groups, alkoxy groups, alkyl sulfon amide groups, aryl sulfon amide groups, alkyl sulfamoyl groups, aryl sulfamoyl groups, alkyl sulfonyl groups, aryl sulfonyl groups, alkyl carbonyl groups, aryl carbonyl groups or cyano groups. Preferably, the cyan dye-forming coupler represented by the formula [C-1] herein has the following formula [C-3]. In the formula [C-3], R⁶ represents a phenyl group. The phenyl group may contain one or more substituents. Typical substituents that may be present include a halogen atom (e.g., fluorine, chlorine or bromine), an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group or a dodecyl group), a hydroxyl group, a cyano group, a nitro group, an alkoxy group (e.g., a methoxy group or an ethoxy group), an alkyl sulfon amide group (e.g., a methyl sulfon amide group or an octyl sulfon amide group), an aryl sulfon amide group (e.g., a phenyl sulfon amide group or a naphthyl sulfon amide group), an alkyl sulfamoyl group (e.g., a butyl sulfamoyl group), an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group), an alkyloxy carbonyl group (e.g., a methyloxy carbonyl group), and an aryloxy carbonyl group (e.g., a phenyloxy carbonyl group). More than one of these substituents may be present on a phenyl group. Preferred groups represented by R⁶ include a phenyl group, or a phenyl group having as substituents one or more halogen atoms (preferably fluorine, chlorine or bromine), alkyl sulfon amide groups (preferably o-methyl sulfon amide groups, p-octyl sulfon amide groups or o-dodecyl sulfon amide groups), aryl sulfon amide groups (preferably phenyl sulfon amide groups), alkyl sulfamoyl groups (preferably butyl sulfamoyl groups), aryl sulfamoyl groups (preferably phenyl sulfamoyl gruops), alkyl groups (preferably methyl groups or tri-fluoro-methyl groups), or alkoxy groups (preferably methoxy groups or ethoxy groups). R⁷ is an alkyl group or an aryl group. The alkyl group or aryl group may possess one or more substituents including, but not limited to, a halogen atom (e.g., fluorine, chlorine or bromine), a hydroxyl group, a carboxyl group, an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group or dodecyl group), an aralkyl group, a cyano group, a nitro group, an alkoxy group (e.g., a methoxy group or an ethoxy group), an aryloxy group, an alkyl sulfon amide group (e.g., a methyl sulfon amide group or an octyl sulfon amide group), an aryl sulfon amide group (e.g., a phenyl sulfon amide group or a naphthyl sulfon amide group), an alkyl sulfamoyl group (e.g., a butyl sulfamoyl group), an aryl sulfamoyl group (e.g., a phenyl sulfamoyl group), an alkyloxy carbonyl group (e.g., a methyloxy carbonyl group), an aryloxy carbonyl group (e.g.., a phenyloxy carbonyl group), an amino sulfon amide group (e.g., a di-methyl amino sulfon amide group), an alkyl sulfonyl group, an aryl sulfonyl group, an alkyl carbonyl group, an aryl carbonyl group, an amino carbonyl amide group, a carbamoyl group, and a sulfinyl group. More than one of these substituents may be present. Preferably, the group represented by R⁷ is an alkyl group when n₁ = 0, and an aryl group when n₁ is equal to or more than 1. More preferably, the group represented by R⁷ is an alkyl group having 1 to 22 carbon atoms when n₁ = 0 (preferably a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group or a dodecyl group), and, when n₁ is equal to or more than 1, a phenyl grup, or a phenyl group having as substituents one or more alkyl groups (preferably a t-butyl group, a t-amyl group or an octyl group), alkyl sulfon amide groups (preferably a butyl sulfon amide group, an octyl sulfon amide group or a dodecyl sulfon amide group), aryl sulfon amide groups (preferably a phenyl sulfon amide group), amino sulfon amide groups (preferably a di-methyl amino sulfon amide group), and/or alkyloxy carbonyl groups (preferably a methyloxy carbonyl group or a butyloxy carbonyl group). R⁸ represents a straight chain or branching alkylene group having 1 to 20 or 1 to 12 carbon atoms. R⁹ represents a hydrogen atom or a halogen atom (fluorine, chlorine, bromine or iodine), preferably a hydrogen atom. n₁ is 0 or a positive number, preferably 0 or 1. X represents a -O-, -CO-, -COO-, -OCO-, -SO₂NR-, NR′SO₂NR″-, -S-, -SO- or -SO₂ group having a valence of 2. R′ and R″ represent an alkyl gorup, which may possess one or more substituent(s). Preferably, X is a -O-, -S-, -SO- or -SO₂- group. Z has the same meaning as Z in the formula [C-1]. The straight chain or branched alkyl group having 1 to 4 carbon atoms represented by R⁴ in the formula [C-2] includes, e.g., an ethyl group, a propyl group, a butyl group, an iso-propyl group, an iso-butyl group, a sec-butyl group, or a tert-butyl group, which may contain substituent(s). The substituents include, e.g., an acyl amino group (e.g., a acetyl amino group) and an alkoxy group (e.g., a methoxy group). R⁴ is preferably an alkyl group having 2 to 4 carbon atoms. The ballast group represented by R⁵ is an organic group having such size and shape that provides coupler molecules with weight suffient to prevent the coupler from being diffused substantially to other layers from that layer in which it is present. The typical ballast groups include an alkyl or aryl group having 8 to 32 carbon atoms. These alkyl and aryl groups may contain substituent(s). The substituents for the aryl group include, e.g., an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a carboxyl group, an acyl group, an ester group, a hydroxy group, a cyano group, a nitro group, a carbamoyl group, a carbon amide group, an alkylthio group, an arylthio group, a sulfonyl group, a sulfon amide group, a sulfamoyl group, and a halogen atom. The substituents for the alkyl group include the same ones as for the aryl group other than an alkyl group. The most preferred ballast group is expressed by the following formula [C-4]. R¹⁰ represents a hydrogen atom, or an alkyl group having 1 to 12 carbon atoms. Ar represents an aryl group such as a phenyl group, which may contain substituent(s). The substituents include an alkyl group, a hydroxy group, and an alkyl sulfon amide group, most preferably a branched alkyl group such as a t-butyl group. In formulae [C-1], [C-2] and [C-3], the groups represented by Z which are freed through reaction with the oxidant of the aromatic amine developing agent are known to those skilled in the art. They improve its reactivity, or are freed from it to implement features such as development suppression, bleaching suppression and color correction in the coating layer or other layers containing the coupler inside the silver halide sensitized photographic color material. The typical groups inlcude, e.g., a halogen atom such as chlorine or fluorine, an optionally substituted alkoxy group, an aryloxy group, an arylthio group, a carbamoyloxy group, a sulfonyloxy group, a sulfon amide group, or a heteroylthio or heteroyloxy group. Most preferably, Z is a hydrogen or chlorine atom. For specific examples, see e.g., Japanese Patent O.P.I. Publication Nos. 10135/1975, 12034/1975, 130441/1975, 48237/1979, 146828/1976, 14736/1979, 37425/1972, 123341/1975 and 95346/1983, Japanese Patent Examined Publication No. 36894/1973, and U.S. Patent Nos. 3,476,563, 3,737,316 and 3,227,551. The following are typical cyan couplers expressed by the formula [C-1]. The following are the typical couplers expressed by the formula [C-2]. The couplers provided by the present invention are not limited t those. For this invention, the compound represented by the following formula [Y] is recommended as a yellow dye-forming coupler. where R¹¹ represents an alkyl group (e.g., a methyl group, an ethyl group, a propyl group, a butyl group or an aryl group (e.g., a phenyl group, p-methoxyphenyl), R¹² presents an aryl group, Y¹ represents hydrogen or a group capable of being split off during the process of the coupling reaction. The most desirable yellow dye-forming couplers are the compounds represented by the following formula [Y′]. where R¹³ represents a halogen, an alkoxy group or an aryloxy group, R¹⁴, R¹⁵ and R¹⁶ independently represent hydrogen, a halogen group, an alkyl group, an alkenyl group, an alkoxy group, an aryl group, an aryloxy group, a carbonyl group, a sulfonyl group, a carboxyl group, an alkoxycarbonyl group, a carbamyl group, a sulfone group, sulfamyl group, a sulfonamide group, an acylamide group, a ureido group or an amino group, and Y¹ is as defined above. These are described in e.g., the following patent publications: U.S. Patent Nos. 2,778,658, 2,875,057, 2,908,573, 3,227,550, 3,253,924, 3,265,506, 3,277,155, 3,341,331, 3,369,895, 3,384,657, 3,408,194, 3,415,652, 3,447,928, 3,551,155, 3,582,322, 3,725,072, 3,894,875, West German OLS Patent Nos. 1,547,868, 2,057,941, 2,162,899, 2,163,812, 2,213,461, 2,219,917, 2,261,361, 2,263,875, Japanese Patent Examined Publication Nos. 49-13576, 48-29432, 48-66834, 49-10736, 49-122335, 50-28834, and 50-132926. The following are some of the typical examples of the yellow color forming couplers represented by the formula [Y]. In this invention, an anti-fogging agent can be used to prevent the occurrence of color turbidity, deterioration of clarity and noticeable graininess resulting from the oxidant in a developing agent or the electron shift agent moving between emulsifying agent layers (between single color sensitivity layers) of a color film sensitized material. This anti-fogging agent can be applied either directly to the emulsifying agent layers themselves or to the interlayers provided between the adjacent emulsifying agent layers. The following compound represented by formula [HQ] is recommended as an anti-fogging agent to be used in this invention. where R³¹, R³², R³³, and R³⁴ independently represent hydrogen, halogen, an alkyl group, an alkenyl group, an aryl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkyl thio group, an aryl thio group, an acyl group, an alkyl acyl amino group, an aryl acyl amino group, an alkyl carbamoyl group, an aryl carbamoyl group, an alkyl sulfon amide group, an aryl sulfon amide group, an alkyl sulfamoyl group, an aryl sulfamoyl group, an alkyl sulfonyl group, a nitro group, a cyano group, an alkyl oxy carbonyl group, an aryl oxy carbonyl group, an alkyl acyl oxy group, or aryl acyl oxy group. In the above formula [HQ], the atoms or groups represented by R³¹, R³², R³³ and R³⁴ include such halogen atoms as fluorine, chlorine and bromine; and an alkyl group such as methyl, ethyl, n-propyl, i-propyl, n-butyl, t-butyl, n-amyl, n-octyl, n-dodecyl, and n-octadecyl; an alkyl group with 1 - 32 carbon atoms is most preferable. The alkenyl group can be, e.g., octenyl or oleyl; an alkenyl group with 2 - 32 carbon atoms is most preferable. The aryl group includes phenyl and naphthyl groups. The acyl group includes acetyl, octanoyl and lauroyl groups. The cycloalkyl, group includes cyclohexyl and cyclopentyl groups. The alkoxy group includes methoxy, ethoxy, and dodecyl groups; the aryloxy group, phenoxy group; the alkyl thio group, methyl thio, n-butyl and n-dodecyl thio groups; the aryl thio group, phenyl thio group; the alkyl acyl amino group, acetyl amino group; the aryl acyl amino group, benzoyl amino group; the alkyl carbamoyl group, methyl carbamoyl group; the aryl carbamoyl group, phenyl carbamoyl group; the alkyl sulfon amide group, methyl sulfon amide group; the aryl sulfon amide group, phenyl sulfon amide group, the alkyl sulfamoyl group, methyl sulfamoyl group; the aryl sulfamoyl group, phenyl sulfamoyl group; the alkyl sulfonyl group, methyl sulfonyl group; the aryl sulfonyl group, phenyl sulfonyl group; the alkyl oxy carbonyl group, methyl oxy carbonyl group; the aryl oxy carbonyl group, phenyl oxy carbonyl group; the alkyl acyl oxy group, acetyl oxy group; the aryl acyl oxy group, benzoyl oxy group. Some of these groups can contain substituents, which include alkyl, aryl, aryl oxy, alkyl thio, cyano, acyl oxy, alkoxy carbonyl, acyl, sulfamoyl, hydroxy, nitro, amino and heterocyclic groups. Among those compounds represented by the formula [HQ], the compounds represented by the following formula [HQ′] are most preferably used. where R³⁵ and R³⁶ independently represent a hydrogen atom or an alkyl, alkenyl, aryl, acyl, cycloalkyl, or heterocyclic group, provided that R³⁵ and R³⁶ do not represent hydrogen atom at the same time. In the above formula [HQ′], the alkyl group represented by R³⁵ and R³⁶ includes methyl, ethyl, n-propyl, i-propyl, n-butyl, n-amyl, i-amyl, n-octyl, n-dodecyl, n-octadecyl; an alkyl group with 1 - 32 carbon atoms is most preferable. The alkenyl group includes octenyl and oleyl groups; an alkenyl group with 2 - 32 carbon atoms is especially preferable. The aryl group includes phenyl and naphthyl groups. The acyl group includes acetyl, octanoyl and lauroyl groups. The cycloalkyl group includes cyclohexyl and cyclopentyl groups. The heterocyclic group includes imidazolyl, furyl, pyridyl, triazinyl, and thiazolyl groups. It is further preferred that the groups represented by R³⁵ and R³⁶ in the above formula [HQ′] have a total of 8 or more carbon atoms and can provide non-diffusion characteristics. The following are some of the examples of the compounds represented by the above formula [HQ]. These compounds are described in publications such as Research Disclosure, Volume 176 (1978), VII-I of Section 17643. For the light-sensitive silver halide photographic material of this invention, an image stabilizer can be utilized to prevent deterioration of color images. Preferable image stabilizers for use in this invention include those presented below in formulas [A] - [H], [J] and [K]. where R¹ represents a hydrogen atom, or an alkyl, alkenyl, aryl, or heterocyclic group; R², R³, R⁵ and R⁶ independently represent a hydrogen atom, halogen atom, or a hydroxy, alkyl, alkenyl, alkoxy or acyl amino group; R¹ refers to an alkyl, hydroxy, aryl or alkoxy group. R¹ and R² may combine with each other to form a 5- or 6-membered ring, where R⁴ is a hydroxy group or an alkoxy group. R³ and R⁴ may also combine to form a 5-membered hydrocarbon ring, where R¹ represents alkyl, aryl or a heterocyclic group, with the exception of the case where R¹ represents hydrogen atom and R⁴ a hydroxy group. In the above formula [A], R¹ represents a hydrogen atom, an alkyl, alkenyl, aryl or heterocyclic group; the alkyl group may be a straight-chain or branched alkyl group such as a methyl, ethyl, propyl, n-octyl, tert-octyl or hexadecyl group. The alkenyl group represented by R¹ includes an allyl, hexenyl or octenyl group. The aryl group represented by R¹ includes a phenyl or naphthyl group. The heterocyclic group represented by R¹ includes tetrahydropyranyl and pyrimidyl. These groups can have one or more substituents. For example, alkyl group having substituents includes benzyl and ethoxymethyl; an aryl group having substituents includes methoxyphenyl, chlorphenyl, 4-hydroxy-3, and 5-dibutylphenyl. In the formula [A], R², R³, R⁵ and R⁶ independently represents a hydrogen atom, halogen atom, or a hydroxy, alkyl, alkenyl, aryl, alkoxy or acyl amino group. Further, the alkyl, alkenyl and aryl groups in this formula include those alkyl, alkenyl and aryl group represented by R¹. The halogen atom may be fluorine chlorine, and bromine. The alkoxy group may be a methoxy group or ethoxy group. The acyl amino group is represented by R′CONH-, where R′ includes an alkyl group (e.g. methyl, ethyl, n-propyl, n-butyl, n-octyl, tert-octyl, benzyl), alkenyl group (e.g., allyl, octynyl, oleyl), aryl group (e.g., phenyl, methoxyphenyl, naphthyl) or heterocyclic group (e.g., pyridyl, pyrimidyl). Also, in the above formula [A], R⁴ represents an alkyl, hydroxy, aryl or alkoxy group. The alkyl group and the aryl group in this formula include the same alkyl and aryl groups represented by R¹. The alkenyl group represented by R⁴ includes the same alkoxy group represented by R², R³, R⁵ and R⁶. R¹ and R² may together form, with a benzene ring, a chroman, coumaran or methylene dioxybenzene ring. R³ and R⁴ may together form, with a benzene ring, an indane ring. These rings can have one or more substituents (e.g., alkyl, alkoxy, aryl). Also, R¹ and R², or R³ and R⁴ may together form spiro compound using one of the atoms in the ring as a spiro atom. Also, R² and R⁴ may be divalent forming a connecting group to form a bis group. Among such compounds, preferable compounds are the bis-indane compounds having 4 RO- groups (R refers to an alkyl, alkenyl, aryl or heterocyclic group). The most preferable compounds are ones represented by the formula [A-1] below. where R represents an alkyl group (e.g. methyl, ethyl, propyl, n-octyl, tert-octyl, benzyl, hexadecyl), an alkenyl group (e.g. aryl, octenyl, oleyl), an aryl group (e.g. phenyl, naphtyl), or a heterocyclic group (e.g. tetrahydropyranyl, pyrimidyl). R⁹ and R¹⁰ independently represent a hydrogen atom, a halogen atom (e.g. fluorine, chlorine, bromine), an alkyl group (e.g. methyl, ethyl, n-butyl, benzyl), an alkoxy group (e.g. aryl, hexenyl, octenyl), or an alkoxy group (e.g. methoxy, ethoxy, benzyloxy). R¹¹ represents a hydrogen atom, an alkyl group (e.g. methyl, ethyl, n-butyl, benzyl), an alkenyl group (e.g. 2-propenyl, hexenyl, octenyl), or an aryl group (e.g. phenyl, methoxyphenyl, chlorophenyl, naphthyl). The compound represented by the above formula [A] also includes those compounds described in such publications as U.S. Patent Nos. 3,935,016, 3,982,944 and 4,254,216, Japanese Patent O.P.I. Publication Nos. 21004/1980 and 145530/1979, British Patent Nos. 2,077,455 and 2,062,888, U.S. Patent Nos. 3,764,337, 3,432,300, 3,574,627 and 3,573,050, Japanese Patent O.P.I. Publication Nos. 152225/1977, 20327/1978, 17729/1978, and 6321/1980, British Patent No. 1,347,556, British Patent (open to public inspection) No. 2,066,975, Japanese Patent Examined Publication Nos. 12337/1979, and 31625/1973, U.S. Patent No. 3,700,455. The compounds represented by formula [A] are used preferably in an amount of 5 to 300 mol % for magenta couplers, and more preferably 10 to 200 mol %. The following are some of the typical examples of compounds represented by the formula [A]: In the formula R¹ and R⁴ independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, cyclo alkyl group, or alkoxy carbonyl group, R² represent a hydrogen atom, alkyl group, alkenyl group, aryl group, acyl group, cyclo alkyl group, or heterocyclic group, and R³ represents a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, aryloxy group, acyl group, acyloxy group, sulfon amido group, cyclo alkyl group, or alkoxy carbonyl group. These groups may be each substituted. The substituents include, e.g., an alkyl group, alkenyl group, alkoxy group, aryl group, aryloxy group, hydroxy group, alkoxy carbonyl group, aryloxy carbonyl group, acyl amino group, acyloxy group, carbamoyl group, sulfon amido group, and sulfamoyl group. R² and R³ may together form a 5- or 6-membered ring. The rings formed with the benzene ring include, e.g., a chroman ring and methylene dioxy benzene ring. Y represents the group of atoms required to form a chroman or a coumarane ring. The chroman or coumarane ring may be substituted by e.g. a halogen atom, alkyl group, cycloalkyl group, alkoxy group, alkenyl group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, or hetero ring, may form a spiro ring. Of the compounds represented by formula [B], the compounds especially useful for the invention are covered by fomulae [B-1], [B-2], [B-3], [B-4], and [B-5]. R¹, R², R³, and R⁴ in formulae [B-1], [B-2], [B-3], [B-4], [B-5] have the same meanings as in the formula [B], and R⁵, R⁶, R⁷, R⁸, R⁹, and R¹⁰ independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, hydroxy group, alkenyl group, alkenyloxy group, aryl group, aryloxy group, or heterocyclic ring. Furthermore, R⁵ and R⁶, R⁶ and R⁷, R⁷ and R⁸, R⁸ and R⁹, and R⁹ and R¹⁰ may together form a hydrocarbon ring, and the rings may be substituted by one or more alkyl group. In the formulae [B-1], [B-2], [B-3], [B-4], and [B-5], particularly useful compounds are those in which R¹ and R⁴ are a hydrogen atom, alkyl group, alkoxy group, hydroxy group, or cycloalkyl group, and R⁵ , R⁶ , R⁷ , R⁸ , R⁹ , and R¹⁰ are a hydrogen atom, alkyl group, or cycloalkyl group. The compounds represented by formula [B] include those listed in Tetrahedron, 1970, vol. 126, P. 4743 ~ 4751, Japan Chemical Society Journal, 1972, No. 10, P. 0987 ~ 1990, chem. Lett., 1972 (4), P. 315 ~ 316, and Japanese Patent O.P.I. Publication No. 139383/1980, and can be synthesized in accordance with the methods stated therein. The compounds represented by formula [B] are preferably used in an amount of 5 ~ 300 mol % for magenta couplers relative to the emulsions of the invnetion, and more preferably, 10 ~ 200 mol %. The following are typical examples. R¹ and R² in the formula independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, or alkoxy carbonyl group. These groups may be each substituted. The substituents include, e.g., a halogen atom, alkyl group, alkenyl group, alkoxy group, aryloxy group, hydroxy group, alkoxy carbonyl group, aryloxy carbonyl group, acyl amino group, carbamoyl group, sulfon amido group, and sulfamoyl group. Y represents the groups of atoms required to form a dichroman or dicoumarane ring along with benzen ring. The chroman or coumarane ring may be substituted by e.g. a halogen atom, cyclo alkyl group, alkoxy group, alkenyl group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, or heterocyclic group, and may form a spiro ring. Of the compounds represented by formula [C] or [D], the compounds particularly useful for the invention are covered by formulae [C-1], [C-2], [D-1], and [D-2]. R¹ and R² in formulae [C-1], [C-2], [D-1], and [D-2] have the same meanings as in the formulae [C] and [D], and R³, R⁴, R⁵, R⁶, R⁷, and R⁸ independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, hydroxy group, alkenyl group, alkyl group, alkoxy group, hydroxy group, alkenyl group, alkenyloxy group, aryl group, aryloxy group, or heterocyclic group. Furthermore, R³ and R⁴, R⁴ and R⁵, R⁵ and R⁶, R⁶ and R⁷, and R⁷ and R⁸ may together form a hydrocarbon rings, and the rings may be substituted by one or more alkyl group. In the formulae [C-1], [C-2], [D-1], and [D-2], particularly useful compounds are those where R¹ and R² are a hydrogen atom, alkyl group, alkoxy group, hydroxy group, or cycloalkyl group, and R³, R⁴, R⁵, R⁶, R⁷, and R⁸ are a hydrogen atom, alkyl group or cycloalkyl group. The compounds represented by formulae [C] and [D] include those disclosed in Japan Chemical Society Journal, Part C, 1968. (14), P. 1937 ~ 18, Journal of the Society of Synthetic Organic Chemistry Japan 1970, 28(1), P. 60 ~ 65, Tetrahedron Letters, 1973. (29), P. 2707 ~ 2710, and can be synthesized in accordance with the methods stated therein. The use of the compounds represented by the formulae [C] and [D] is preferably 5 ~ 300 mol % for magenta couplers, and more preferably, 10 ~ 200 mol %. The following are the typical examples. R¹ in the formula represents a hydrogen atom, alkyl group, alkenyl group, aryl group, acyl group, cycloalkyl group, or heterocyclic group, R³ represents a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, cycloalkyl group or alkoxy carbonyl group. R² and R⁴ independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, acyl group, acyl amino group, sulfon amido group, cycloalkyl group, or alkoxy carbonyl group. These groups may each be substituted by one or more substituents. The substituents include, e.g., an alkyl group, alkenyl group, alkoxy group, aryl group, aryloxy group, hydroxy group, alkoxy carbonyl group, aryloxy carbonyl group, acyl amino group, and sulfamoyl group. R¹ and R² may together form a 5- or 6-membered ring. In that case, R³ and R⁴ independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, or alkoxy carbonyl group. Y represents the group of atoms required to form chroman or coumarane ring. The chroman or coumarane ring may be substituted by a halogen atom, alkyl group, cyclo alkyl group, alkoxy group, alkenyl group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, or heterocyclic group, and may form spiro ring. Of the compounds represented by formula [E], the compounds especially useful for the invention are covered by formulae [E-1], [E-2], [E-3], [E-4], and [E-5]. R¹, R², R³, and R⁴ in formulae [E-1] to [E-5] have the same meanings as in the formula [E], and R⁵, R⁶, R⁷, R⁸, R⁹, and R¹⁰ independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, hydroxy group, alkenyl group, alkenyloxy group, aryl group, aryloxy group, or heterocyclic ring. R⁵ and R⁶, R⁶ and R⁷, R⁷ and R⁸, R⁸ and R⁹, and R⁹ and R¹⁰ may together form a hydrocarbon ring, and the rings may be substituted by one or more alkyl groups. In the formula [E-1] to [E-5], particularly useful compounds are those where R¹, R², R³, and R⁴ are a hydrogen atom, alkyl group, or cycloalkyl group, R³ and R⁴ are a hydrogen atom, alkyl group, alkoxy group, hydroxy group, or cycloalkyl group, and R⁵, R⁶ , R⁷ , R⁸ , R⁹ , and R¹⁰ are a hydrogen atom, alkyl group, or cycloalkyl group. The compounds represented by formula [E] include those listed in Tetrahedron Letters, 1965. (8), P. 457 ~ 460, Japan Chemical Society Journal, Part C, 1966. (22), P. 2,013 2,016, and Zh. Org. Khim., 1970, (6), P. 1,230 ~ 1,237, and can be synthesized in accordance with the methods stated therein. The compounds represented by formula [E-1] are preferably used in an amount of 5 ~ 300 mol % for magenta couplers, and more preferably, 10 ~ 200 mol %. The following are examples. R¹ in the formula represents a hydrogen atom, alkyl group, alkenyl group, aryl group, acyl group, cycloalkyl group, or heterocyclic group, and R² represents a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, cycloalkyl group, or alkoxy carbonyl group. R³ represents a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, acyl group, acyl amino group, sulfon amido group, cycloalkyl group, or alkoxy carbonyl group. R⁴ represents a hydrogen atom, alkyl group, alkenyl group, alkoxy group, alkenyloxy group, hidroxy group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido group, or alkoxy carbonyl group. These groups may be each substituted. The substituents include, e.g., an alkyl group, alkenyl group, alkoxy group, aryl group, aryloxy group, hydroxy group, alkoxycarbonyl group, aryloxy carbonyl group, acyl amino group, carbamoyl group, sulfon amido group, and sulfamoyl group. R¹ and R² may together form a 5- or 6-membered ring. In that case, R³ and R⁴ represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, acyl group, acyl amino group, acyloxy group, sulfon amido gruop, or alkoxy carbonyl group. Y represents the groups of atoms required to form a chroman or a coumarane ring. The chroman or the coumarane ring may be substituted by a halogen atom, alkyl group, cycloalkyl group, alkoxy group, alkenyl group, alkenyloxy group, hydroxy group, aryl group, aryloxy group, or heterocyclic ring, and may form spiro ring. Of the comounds represented by formula [F], the compounds especially useful for the invention are covered by formuale [F-1], [F-2], [F-3], [F-4], and [F-5]. where R¹, R², R³, and R⁴ of the Formula [F] are the same as those in the formula [F], and R⁵, R⁶, R⁷, R⁸, R⁹, and R¹⁰ indicate a hydrogen atom, halogen atom, alkyl group, alkoxy group, hydroxy group, alkenyl group, alkenyloxy group, aryl group, aryloxy group, or heterocyclic group, respectively. In addition, R⁵ and R⁶, R⁶ and R⁷, R⁷ and R⁸, and R⁸ and R⁹ may together form a hydrocarbon ring. This ring may be substituted by one or more alkyl groups. Two R 's in the formulas [F-3], [F-4], and [F-5] may or may not be indentical. In the formulas [F-1], [F-2], [F-3], [F-4], and [F-5], the compounds where R¹, R², and R³ are a hydrogen atom, alkyl group, and cycloalkyl group, respectively, and R⁴ is a hydrogen atom, alkyl group, alkoxy group, hydroxy group, or cycloalkyl group, and R⁵, R⁶, R⁷, R⁸, R⁹, and R¹⁰ are a hydrogen atom, alkyl group, or cycloalkyl group, are particularly useful. The compounds of formula [F] may be compound described in Tetrahedron Letters 1970, vol 26, page 4743 to 4751, the Japanese Chemical Society Journal 1972, No. 10, page 1987 to 1990, the Synthesis 1975, vol 6, page 392 to 393, and the Bul Soc, Chim, Belg 1975, vol 84(7), page 747 to 759, and can be synthesized in accordance with the methods set forth in these publications. Preferably, the usage of the compound of the formula [F] is 5 to 300 mol percent for the magenta coupler, more preferably 10 to 200 mol percent. The typical examples of the compounds of the formula [F] include: where R¹ and R³ in the formula independently indicate a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, hydroxy group, aryl group, aryloxy group, acylamino group, acyloxy group, sulfon amide group, cycloalkyl group, or alkoxy carbonyl group. R² indicates a hydrogen atom, halogen atom, alkyl group, alkenyl group, hydroxy group, aryl group, acyl group, acylamino group, acyloxy group, sulfon amide group, cycloalkyl group, or alkoxy carbonyl group. Each of the groups shown above may be substituted. The substituent may be e.g. an alkyl, alkenyl, alkoxy, aryl, aryloxy, hydroxy, alkoxy carbonyl, aryl oxycarbonyl, acyl amino, carbamoyl, sulfon amide, and sulfamoyl group. R² and R³ may together form a 5- or 6-membered hydrocarbon ring. This ring may be substituted by a halogen atom, alkyl, cycloalkyl, alkoxy, alkenyl, hydroxy, aryl, aryloxy group, or hetero cyclic group. Y indicates a group of atoms required to form indane ring. The indane ring may be substituted by a halogen atom, alkyl, alkenyl, alkoxy, cycloalkyl, hydroxy, aryl, aryloxy group, or hetero ring group, and may form a spiro ring. Of the compounds of the formula [G], the compounds especially useful for the invention are those shown in the formulas [G-1] to [G-3]. where R¹, R², and R³ in the formulas [G-1] to [G-3] are the same as those in the formula [G], and R⁴, R⁵, R⁶, R⁷, R⁸, and R⁹ independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, alkenyl group, hydroxy group, aryl group, aryloxy group, or hetero ring group. R⁴ and R⁵, R⁵ and R⁶, R⁶ and R⁷, R⁷ and R⁸, and R⁸ and R⁹ may together form a hydrocarbon ring, and in addition the hydrocarbon ring may be substituted by an alkyl group. In the formulas [G-1] to [G-3], the compounds where R¹ and R³ are a hydrogen atom, alkyl group, alkoxy group, hydroxy group, or cycloalkyl group, and R² is a hydrogen atom, alkyl group, hydroxy group, or cycloalkyl, and R⁴, R⁵, R⁶, R⁷, R⁸, and R⁹ are a hydrogen atom, alkyl group, or cycloalkyl group, are especially useful. Preferably, the usage of the compound of the formula [G] is 5 to 300 mol percent for the magenta coupler, more preferably 10 to 200 mol percent. Typical examples of the compounds of formula [G] include: R¹ and R² in the formula represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, aryl group, acyl group, acyl amino group, acyloxy group, sulfon amide group, cyclo alkyl group, or alkoxy carbonyl group. R³ represents a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkoxy group, hydroxy group, aryl group, aryloxy group, acyl gruop, acyl amino group, acyloxy group, sulfon amide group, cyclo alkyl group, or alkoxy carbonyl group. Each of the groups listed above may be substituted by other groups, e.g. an alkyl group, alkenyl group, alkoxy group, aryl group, aryloxy group, hydroxy group, alkoxy carbonyl group, aryloxy carbonyl group, acyl amino group, carbamoyl group, sulfon amide group, sulfamoyl group. R¹ and R², and R² and R³ may together form a 5- or 6-membered hydrocarbon ring. This hydrocarbon ring may be substituted by a halogen atom, alkyl group, cycloalkyl group, alkoxy group, alkenyl group, hydroxy group, aryl group, aryloxy group, or hetero ring group. Y represents the group of atoms required to form an indane ring. This indane ring may be substituted by a substituent which can be present on the hydrocarbon ring. Furthermore, it may form a spiro ring. Of the compounds expressed by the formula [H], the compound especially useful in the invention are those of the formulas [H-1] to [H-3]. R¹, R², and R³ in the formulas [H-1] to [H-3] are the same as those in the formula [H]. R⁴, R⁵, R⁶, R⁷, R⁸, and R⁹ independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, hydroxy group, alkenyl group, aryl group, aryloxy group, or hetero ring group. R⁴ and R⁵, R⁵ and R⁶, R⁶ and R⁷, R⁷ and R⁸, and R⁸ and R⁹ may together form a hydrocarbon ring. Furhtermore, the hydrocarbon ring may be substituted by one or more alkyl groups. In the formulas [H-1] to [H-3], the compounds where R¹ and R² are hydrogen atom, alkyl group, or cycloalkyl group, and R³ is hydrogen atom, alkyl group, alkoxy gruop, hydroxy group, or cycloalkyl group, and R⁴, R⁵, R⁶, R⁷, R⁸, and R⁹ are hydrogen atom, alkyl group, or cycloalkyl group, are especially useful. The compound expressed by the formula [H] can be manufactured in accordance with e.g., U.S. Patent No. 3,057,929, Chem. Bar. 1972, 95(5), page 1673 to 1674 and Chemistry Letters, 1980, page 739 to 742. Preferably, the usage of a compound expressed by the formula [H] is 5 to 300 mol percent for magenta coupler, more preferably 10 to 200 mol percent. Typical examples of the compounds expressed by the formula [H] include: (In the formula, R¹ represents an aliphatic group, cycloalkyl group, or aryl group, and Y represents a non-metallic group required to form a 5- to 7-membered heterocyclic ring together with the nitrogen atom. If the non-metallic group contains at least two hetero-atoms these are not adjacent to each other.) The aliphatic group represented by R′ includes a saturated alkyl group which may have a substituent and an unsaturated alkyl group which may have a substituent. Saturated alkyl groups include a methyl gruop, ethyl group, butyl group, octyl group, dodecyl group, tetradecyl group, hexadecyl group, and unsaturated alkyl groups include an ethenyl group and propenyl group. The cycloalkyl group represented by R¹ includes a 5- or 7-membered cycloalkyl group which may have a substituent, for example cyclopentyl group or cyclohexyl. The aryl group represented by R¹ includes a phenyl group and a naphthyl group, which may have a substituent. The substituent for the aliphatic group, cycloalkyl group, and aryl group represented by R¹ includes an alkyl group, aryl group, alkoxy group, carbonyl group, carbamoyl group, sulfamoyl group, sulfon amide group, carbonyloxy group, alkyl sulfonyl group, aryl sulfonyl group, hydroxy group, hetero ring group, alkylthio group, and arylthio group. Furthermore, these substituents may have one or more substituents. In the formula [J], Y represents the non-metallic atoms required to form 5- to 7-membered heterocyclic ring together with the nitrogen atom. When least two hetero atoms are present they must not be adjacent to each other. In the heterocyclic ring of the compound expressed by the formula [J], if all of the hetero atoms are adjacent to one another, the compound cannot act as a magenta dye image stabilizer. The 5- to 7-membered heterocyclic ring of the compound expressed by the formula [J] may have one or more substituents, e.g. an alkyl group, aryl group, acyl group, carbamoyl group, alcoxy carbonyl group, sulfonyl group, sulfamoyl group. Furthermore, they may have one or more substituents. Preferably, the 5- to 7-membered heterocyclic ring is a saturated one. A benzene ring may be condensed to the heterocyclic ring; formation of a spiro ring is permitted. Preferably, the usage of the compound expressed by the formula [J] is 5 to 300 mol percent for the magenta coupler expressed by the formula [I] of the invention herein, more preferably 10 to 200 mol percent. Typical examples expressed by the formula [J] include: Of the compounds expressed by the formula [J], piperazine compounds and homopiperazine compounds are recommended in particular, and those expressed by the following formula [J-1] or [J-2] are more preferable. R² and R³in the formula independently represent a hydrogen atom, alkyl group, or aryl group. However, R² and R³ cannot both be hydrogen. R⁴ to R¹³ independently represent a hydrogen atom, alkyl group, or aryl group. R² and R³ in the formula [J-1] and [J-2] independently a represent a hydrogen atom, alkyl group, or aryl group. The alkyl group represented by R² and R³ includes a methyl group, ethyl group, butyl group, octyl group, dodecyl group, tetradecyl group, hexadecyl group, octadecyl group. The aryl group represented by R² or R³ includes a phenyl group. The alkyl or aryl group represented by R² or R³ may have a substituent, e.g. a halogen atom, alkyl group, aryl group, alkoxy group, aryloxy group, or heterocyclic ring group. Preferably, the number of total carbon atoms for R² and R³ (including substituents) is 6 to 40. R⁴ to R¹³ in the formulas [J-1] or [J-2] represent a hydrogen atom, alkyl group, or aryl group. The alkyl group represented by R⁴ to R¹³ includes a methyl group and an ethyl group. The aryl group represented by R⁴ to R¹³ includes a phenyl group. Typical examples of the compound of formula [J-1] or [J-2] are the piperazine compounds (J-1) to (J-30) and homopiperazine compounds (J-51) to (J-62). R¹ in the formula represents an aliphatic group, cycloalkyl group, or aryl group and Y represents a hydrocarbon group with a valence of 2 required to form a 5- to 7-membered heterocyclic ring together with the nitrogen atom. R², R³, R⁴, R⁵, R⁶, and R⁷ independently represent a hydrogen atom, aliphatic group, cycloalkyl group, or aryl group. R² and R⁴, and R³ and R⁶, can form a single bond and may form an unsaturated 5- to 7-membered heterocyclic ring together with Y. If Y is a single bond, R⁵ and R⁷ bond to each other to form a single bond and may form an unsaturated 5-membered heterocyclic ring together with the nitrogen atom and Y. If Y is not a single bond, R⁵ and Y, R⁷ and Y, or Y itself forms an unsaturated bond and may form an unsaturated 6- or 7-membered heterocyclic ring together with the nitrogen atom and Y. The aliphatic group represented by R¹ includes a saturated alkyl group which may have a substituent, and an unsaturated alkyl group which may have a substituent. Saturated alkyl groups include a methyl group, ethyl gruop, butyl group, octyl group, dodecyl group, tetradecyl group, and hexadecyl group. Unsaturated alkyl groups include an ethenyl group and propenyl group. The cycloalkyl group represented by R¹ includes a 5- to 7-membered cycloalkyl group which may have a substituent, e.g. cyclopentyl and cyclohexyl. The aryl group represented by R¹ includes a phenyl group and a naphthyl group, which may have substituent. The substituent for the aliphatic group, cycloalkyl group, and aryl group represented by R¹ includes an alkyl group, aryl group, alkoxy group, carbonyl group, carbamoyl group, acyl amino group, sulfamoyl group, sulfon amide, carbonyloxy group, alkylsulfonyl group, aryl sulfonyl group, hydroxy group, hetero ring group, alkylthio group, arylthio group. Furthermore, they may have substituents. Y in the formula [K] represents a hydrocarbon radical with a valence of 2 or a single bond, required to form a 5- to 7-membered heterocyclic ring together with the nitrogen atom. If Y, however, is a single bond, R⁵ and R⁷ may together form a single bond and may form an unsaturated 5-membered heterocyclic ring. If Y is a hydrocarbon radical with a valence of 2 or a methylene group, R⁵ and Y or R⁷ and Y may form an unsaturated bond to form an unsaturated 6-member heterocyclic ring. If it is an ethylene group, R⁵ and Y, R⁷ and Y, or Y itself may form an unsaturated bond to form an unsaturated 7-membered heterocyclic ring. Furthermore, the hydrocarbon group with a valence of 2 represented by Y may have a substituent, e.g. an alkyl group, carbamoyl group, alkyloxy carbonyl group, acyl amino group, sulfon amide group, sulfamoyl group, aryl group, and hetero ring group. R², R³, R⁴, R⁵, R⁶, and R⁷ in the formula [K] independently represent a hydrogen atom, aliphatic group, cycloalkyl group, or aryl group. The aliphatic group represented by R² to R⁷ inlcudes a saturated alkyl group which may have a substituent, and unsaturated alkyl group which may have a substituent. Saturated alkyl groups include a methyl group, butyl group, octyl group, dodecyl group, tetradecyl group, and hexadecyl group. Unsaturated alkyl groups include an ethenyl group and a propenyl group, Cycloalkyl groups represented by R² to R⁷ include a 5- to 7-membered cycloalkyl group which may have a substituent, e.g. cyclopentyl group and a cyclohexyl group. Aryl groups represented by R² to R⁷ include a phenyl group and a naphthyl group which may have one or more substituents. The substituent for the aliphatic group, cycloalkyl group, and aryl group includes an alkyl group, aryl group, alkoxy group, carbonyl group, carbamoyl group, acyl amino group, sulfamoyl group, sulfon amide group, carbonyloxy group, alkylsulfonyl group, arylsulfonyl group, hydroxy group, hetero ring group, and alkylthio group. The compound of the formula (K), is preferably unsaturated. The usage of the compound of formula (K) is generally 5 to 300 mol percent, for magenta coupler of the formula (I), more preferably 10 to 200 mol percent. Typical examples of the compounds of the formula (K) include: A protective layer, intermediate layer or any other hydrophilic colloidal layer of the sensitized material of the present invention may contain an ultraviolet absorbent to prevent fogging caused when the sensitized material is electrically charged due to friction for example, and to prevent images from deteriorating when exposed to ultraviolet rays. The color sensitized material using a silver halide emulsion of the present invention may have an auxiliary layer or layers such as a filter layer, antihalation layer and/or anti-irradiation layer. Each of these layers and/or emulsion layer may contain a dye which will flow out from the color sensitized material or bleached during developing. A matting compound may be added to the silver halide emulsion layer and/or any other hydrophilic colloidal layer of the silver halide sensitized material for the purpose of reducing the gloss of the sensitized material, enhancing the retouchability, and preventing one sensitized material from sticking to another. A lubricant may be added to reduce the friction by sliding of the sensitive material of the invention. An anti-static agent may be added to the light sensitive material of the invention to prevent if from being charged with static electricity. Such an anti-static agent may be used in the anti-static layer on the side having no emulsion support, or in an emulsion layer and/or in any protective colloidal layer other than the emulsion layer on the side having an emulsion support. A variety of surface-active agents can be used in the photographic emulsion layer and/or any other hydrophilic colloidal layer of the material to improve the coating property, prevent static charge, enhance the sliding property, disperse emulsification, prevent sticking and improve the photographic properties (such as accelerated development, intensification, and sensitization). The light sensitive material incorporates a support which can be, for example, baryta paper or paper laminated with, say, alpha-olefin polymer, synthetic paper or any other similar flexible reflective support, a film consisting of semi-synthetic or synthetic high-molecular cellulose acetate, cellulose nitrate, polystyrene, polyvinylchloride, polyethylene terephthalate, polycarbonate or polyamide, or a rigid body such as glass, metal or ceramics. The silver halide sensitive material may have the surface of its support subjected to corona discharge, ultraviolet irradiation or flaming, as appropriate, and then be applied directly or via one or two coats amined at enhancing the adhesion, anti-static property, dimensional stability, wear resistance, hardness, anti-halation property, friction and/or any other characteristics of the material. In the coating of the silver halide emulsion, a thickening agent may be used for improving its coating properties. The most useful coating technique is either extrusion or curtain coating which allows a simultaneous coating of two or more different layers. The sensitive material can be exposed to light using electromagnetic waves having a spectrum to which the material itself is sensitive. The light source to which the sensitive material can be exposed may be natural light (sunshine) or any other known light emitted from the fluorescent substance excited by a tungsten lamp, fluorescent lamp, mercury lamp, xenon arc lamp, carbon arc lamp, xenon flash lamp, cathode-ray flying spot, laser, light-emitting diode, electron rays, X-rays, gamma-rays, or alpha-rays. The exposure time may of course be 1 millisecond to 1 second as with an ordinary camera, but may be shorter than 1 millisecond, for example, 100 microseconds to 1 microsecond with a cathode-ray tube or xenon flash lamp, or longer than 1 second. The sensitive material may be exposed continuously or intermittently. The silver halide material can generate color images through a color developing method known to those who are skilled in the art. The aromatic amine-based coloring developing agents used to develop colors in the present invention include those developing agents widely known in various color photographing processes in the industry. These agents generally contain an aminophenol-based or p-phenylenediamine-based derivative. Such a compound is normally used in the form of a salt, for example a hydrochloride or sulfate, because of its higher stability than in the free form. The compound is used with concentrations of, typically, 0.1-30g, preferably 1-15g, per liter of coloring developing agent. Aminophenol-based developing agents inlcude, for example, o-aminophenol, p-aminophenol, 5-amino-2-hydroxytoluene, 2-amino-3-hydroxytoluene, and 2-hydroxy-3-amino-1,4-dimethylbenzene. Especially useful aromatic amine-based coloring agents are N,N′-dialkyl-p-phenylenediamine-based compounds, in which the alkyl group and phenyl group may be substituted by any substituent; for example, N,N′-diethyl-p-phenylenediamine hydrochloride, N-methyl-p-phenylenediamine hydrochloride, 2-amino-5-(N-ethyl-N-dodecylamino)-toluene, N-ethyl-N-β-methanesulfonamidethyl-3-methyl-4-aminoaniline sulfate, N-ethyl-N-β-hydroxyethylaminoaniline,4-amino-3-methyl-N,N′-diethylaniline, and 4-amino-N-(2-methoxyethyl)-N-ethyl-3-methylaniline-p-toluene sulfonate. The coloring developing agent may contain various additives which are normally used in the color developing process, for example an alkaline compound such as sodium hydroxide, sodium carbonate or potassium carbonate, alkaline metal sulfite, alkaline metal bisulfite, alkaline metal thiocyanate, alkaline metal halide, benzylalcohol, a water softening agent or thickening agent as appropriate. The pH-value of such a coloring developing agent is, normally, 7 or more, and most typically, from 10 to 13. The coloring developing process is followed by a treatment using an agent having a fixing capability. If the processing agent having such a fixing capability is a fixing solution, bleaching takes place before the fixing process. The bleaching agent used in the bleaching process is usually an organic metal complex salt, which not only oxidizes the metal silver generated by developing and reduces it to silver halide but also develops any uncolored portion of the coloring agent. It is usually constituted of iron, cobalt, copper or other metal ions coordinated with an organic acid such as an aminopolycarbonic acid, oxalic acid or citric acid. The most preferable organic acid used to form such metal complex salts is polycarbonate or aminopolycarbonate. It may be, e.g., an alkali metal salt, ammonium salt or water-soluble amine salt. Examples include: [1] ethylenediaminetetraacetic acid [2] nitrilotriacetic acid [3] iminodiacetic acid [4] ethylenediaminetetraacetic acid disodium salt [5] ethylenediaminetetraacetic acid tetra (trimethyl-ammonium) salt [6] ethylenediaminetetraacetic acid tetrasodium salt [7] nitrilotriacetic acid sodium salt The bleaching agent contains the above-mentioned organic metal complex salt and may contain a variety of additives. A preferable additive is an alkali halide or ammonium halide, for example a rehalogenating compound including potassium bromide, sodium bromide, sodium chloride or ammonium bromide, or a metal salt or chelating agent. Also, the bleaching agent can contain a pH buffering agent such as borate, oxalate, acetate, carbonate or phosphate, or alkylamine, polyethylene oxide or any other compound normally known for addition to a bleaching agent. Furthermore, the fixing solution or bleaching/fixing solution may contain one or more pH buffering agents comprising various sulfites such as ammonium sulfite, potassium sulfite, ammonium bisulfite, potassium bisulfite, sodium bisulfite, meta-ammonium bisulfite, meta-potassium bisulfite or meta-sodium bisulfite, or various types of salts such as boric acid, borax, sodium hydroxide, potassium hydroxide, sodium carbonate, sodium bisulfite, sodium bicarbonate, potassium bicarbonate, acetic acid, sodium acetate or ammonium hydroxide. For processing with a bleaching/fixing replenisher being added to the bleaching/fixing solution (bath), the solution (bath) may contain a thiosulfate, thiocyanate or sulfite, or a replenisher to which such a salt is added. According to the present invention, the bleaching/fixing solution bath or the tank storing its replenisher may be subjected to a blast of air or oxygen to enhance the degree of activation of the bleaching/fixing solution. Another way to achieve the same purpose is to add an oxidizer such as hydrogen peroxide, bromate or persulfate, as appropriate. As indicated above, the light-sensitive silver halide photographic material of the present invention provides excellent reproduction of magenta color images, improved fastness of the dye image against light and a lower incidence in fog of an unexposed sample with lapse of time. The present invention is further illustrated with reference to the following Examples. However, of course, the invention is not limited to these examples. Example 1 A support comprising a polyethylene-covered paper was coated with a silver halide emulsion containing a control magenta coupler to a build-up of 4 mg/dm², green-sensitive silver chloride/bromide emulsion to a build-up of 4 mg/dm² in terms of silver, dioctyl phathalate as a solvent for coupler to a build-up of 4 mg/dm² and gelatin to a build-up of 16 mg/dm². The sample thus prepared is hereinafter referred to as Sample 1. Then Samples 2 to 28 were prepared in the same manner as Sample 1 except that in these samples the combination of coupler, metal complex and compound of formula [a-1] or [a-2] as shown in Table 1 was used in place of the control magenta coupler in the silver halide emulsion layer, and that the coated amount of silver in Samples 5 to 28 was 2 mg/dm². In the Example the metal complex and the compound of formula [a-1] or [a-2] were incorporated in the Samples after being dissolved in the solvent together with the coupler. After being exposed to green light through an optical wedge in a sensitometer (Model KS-7, a product of Konishiroku Photo Industry Co., Ltd.), the individual samples were subjected to the following processes: <Standard processes (temperature and time)> [1] Color development (38°C, 3′30″) [2] Bleach-fixing (33°C, 1′30″) [3] Rinsing 25-30°C, 3′ [4] Drying 75-80°C, about 2′ Each of the samples thus prepared was subjected to light resistance tests, as follows: <Light resistance test> Each sample was exposed to sunshine for 30 days in an underglass outdoor exposure table. Its green densities before and after the fading test were measured. The formula used to obtain the magnitude of fading (fading ratio) by light is as follows: Fading ratio = (D₀ - D)/D₀ x 100 (%) where D₀ is the density before fading by light and D is the density after fading by light. The results are shown in Table 1. Note: The amount of addition of the metal complex and the compound of [a-1] or [a-2] was 0.5 moles per 1 mole of magenta coupler. In the table, "Comp." refers to "comparative sample" and "Inv." means "sample according to the present invention". The chemical structure of the Control coupler is as follows: It is found from the data listed in Table 1 that a magenta coupler combined with the metal complex and a compound represented by formula [a-1] or [a-2] provides a significantly enhanced light resistance, especially to the magenta dye which is formed from the magenta coupler represented by formula [I]. In addition, since the magenta dye formed from the coupler represented by formula [I] has a small secondary absorption, it can be confirmed that the samples in accordance with the present invention have excellent color reproduction capabilities. Example 2 A support comprising a polyethylene-covered paper was coated with the following layers in sequence to form a multicolor light-sensitive silver halide photographic material: First layer: Blue-sensitive silver halide emulsion layer As a yellow coupler, the first layer was coated with a-pivalyl-a-(1-benzyl-2,4-dioxy-imidalyzin-3-il)-2-chloro-5-[r-(2,4-di-t-amylphenoxy) butylamide]-acetoanilide to a build-up of 8 mg/dm², blue-sensitive silver chloride/bromide emulsion to a build-up of 3 mg/dm² in terms of silver, 2,4-d-t-butylphenol-3′,5′-di-t-amyl-4′-hydroxybenzoate to a build-up of 3 mg/dm², dioctylphthalate to a build-up of 3 mg/dm² and gelatin to a build-up of 16 mg/dm². Second layer: Intermediate layer The second layer was coated with gelatin to a build-up of 4 mg/dm². Third layer: Green-sensitive silver chloride/bromide emulsion layer The third layer was coated with the above-mentioned magenta coupler 44 to a build-up of 4 mg/dm², green-sensitive silver chloride/bromide emulsion to a build-up of 2 mg/dm² in terms of silver, dioctylphthalate to a build-up of 4 mg/dm² and gelatin to a build-up of 16 mg/dm². Foruth layer: Intermediate layer As an ultraviolet absorbent, the fourth layer was coated with 2-hydroxy-3′,5′-di-t-amylphenyl)-benzotriazol to a build-up of 3 mg/dm², 2-(2′-hydroxy-3′,5′-di-t-butyl-phenyl)-benzotriazol to a build-up of 3 mg/dm², dioctylphthalate to a build-up of 4 mg/dm² and gelatin to a build-up of 14 mg/dm². Fifth layer: Red-sensitive silver chloride/bromide emulsion layer As a cyan coupler, the fifth layer was coated with 2,4-dichloro-3-methyl-6-[a-(2,4-di-t-amylphenoxy) butylamide]-phenol to a build-up of 1 mg/dm², 2-(2,3,4,5,6-pentafluorophenyl) acylamino-4-chloro-5-[a-(2,4-di-tert-amylphenoxy) pentylamide] to a build-up of 3 mg/dm², dioctylphthalate to a build-up of 2 mg/dm² and red-sensitive silver chloride/bromide emulsion to a build-up of 3 mg/dm² in terms of silver. Sixth layer: Intermediate layer As an ultraviolet absorbent, the sixth layer was coated with 2-(2′-hydroxy-3′,5′-di-t-amylphenyl)-benzotriazol to a build-up of 2 mg/dm², 2-(2′-hydroxy-3′,5′-di-t-butylphenyl)-benzotriazol to a build-up of 2 mg/dm², dioctylphthalate to a build-up of 2 mg/dm² and gelatin to a build-up of 5 mg/dm². Seventh layer: Protective layer The seventh layer was coated with gelatin to a build-up of 9 mg/dm². The sample thus prepared is named sample 29. Then a magenta coupler, metal complex and compound represented by formula [a-1] or [a-2] (the amount of the metal complex and the compound represented by formula [a-1] or [a-2] was 0.5 mol for one mol of coupler) were added in the combination shown in Table 2. Following that, samples 30 to 56 similar to sample 29 but not subjected to such addition were prepared. The samples were subjected to the same exposure test as conducted with Example 1. Each of the samples then underwent light resistance measurements as with Example 1. In addition, each of the samples was tested for an increase in the time-dependent fogging value during storage in the following manner: <Time-dependent fogging value increase test> Each coated sample was stored in a thermostatic oven which was maintained at 77 degrees C without humidifying for six days. Following that, the sample was checked for the green light reflection density of the white portion. The increased density of fogging value was assumed to be equal to the difference of green light reflection density of the white portion before storage in the thermostatic oven from that after storage in the oven. The result is shown in Table 2. From the data listed in Table 2, it is apparent that, if a metal complex is added to the magenta coupler layer (sample 30), increased light resistance is achieved but the increase in the fogging value of the sample during raw storage becomes significantly high. It is also found that, if a compound represented by formula [a-1] or [a-2] is added to the magenta coupler layer (Sample 31 and 32), the increase in the fogging value during storage becomes negligible but lower light resistance results. By contrast, samples 33 to 56 of the subject invention provide significantly higher light resistance while giving a very low increase in the fogging value during storage. Example 3 Sampels 57 to 73 similar to Samples 33 and 34 of Example 2 were prepared. The differences are that the new samples had the metal complex and organic solvent listed in Table 3 added to the magenta coupler layer, and that an anti-oxidant (0.5 mol for one mol of coupler) or a compound represented by formula [a-1] and [a-2] were added in combination. Each of the samples thus prepared was subjected to light resistance tests and fogging value measurements as with Example 2. The result is shown in Table 3. (Notes) 1. Chemical Structure of Comparative Metal Complex is: (Singlet Oxygen Quenching Rate Constant: 2.2 x 10⁷ M⁻¹ sec⁻¹) 2. In Table 3, as the organic solvent DOP refers to dioctyl phthalate, DNP to dinonyl phthalate, TNP to trinonyl phosphate, DELA to diethyllauric acid amide and DM to dimethyl phthalate, respectively. As is apparent from the results listed in Table 3, Samples 57 to 70 and 73 of the subject invention have significantly higher light resistance and a very little increase in the fogging value of the samples during storage. Samples 57 to 70 using an anti-oxidant as another additive and sample 73 using a compound represented by formula [a-1] and [a-2] in combination provide synergistically improved light resistance. A comparison among smaples 33, 34 and 57 to 64 teaches that higher light resistance is obtained where an organic solvent having a lower dielectric constant is employed.

Claims: 1. A light-sensitive silver halide photographic material comprising a support and provided thereon at least one silver halide emulsion layer, wherein at least one layer of said silver halide emulsion layer contains a compound represented by general formula [I], (wherein Z represents a group of non-metallic atoms necessary to complete a nitrogen-containing heterocyclic ring which may have a substituent; X represents a hydrogen atom or a substituent capable of being split off upon reaction with an oxidation product of a color developing agent; and R represents a hydrogen atom or a substituent), said silver halide emulsion layer containing the compound of formula [I] further containing a metal complex having a quenching rate constant of singlet oxygen of more than 3 x 10⁷ M⁻¹. sec⁻¹, and a compound having the general formula [a-1] or [a-2]: (wherein R¹ and R² are independently selected from an alkyl group; R³ is selected from the group consisting of an alkyl group, a - NR′R″ group, a - SR′ group and a - COOR″ group, in which R′ is a mono-valent organic group and R″ is a hydrogen atom or a mono-valent organic group; and m is an integer of 0 to 3); (wherein R⁴ is selected from the group consisting of a hydrogen atom, a hydroxyl group, an oxy radical group, -SOR′ group, in which R′ is a mono-valent organic group, a -SO₂R″ group, in which R″ is a hydrogen atom or a mono-valent organic group; R⁵, R⁶, R⁵′, R⁶′ are independently selected from an alkyl group; R⁷ and R⁸ are independently selected from the group consisting of a hydrogen atom and a -OCOR¹⁰ group, in which R¹⁰ is a mono-valent organic group, provided that R⁷ and R⁸ may be combined with each other to form a heterocyclic group; and n is an integer of 0 to 4). 2. The light-sensitive silver halide photographic material of claim 1, wherein said substituent for R in formula [I] is selected from the group consisting of a halogen atom, on alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro compound residual group, a bridged hydrocarbon compound residual group, an alkoxy group, an aryloxy group, a heterocyclicoxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, on aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an arylthio group and a heterocyclicthio group. 3. The light-sensitive silver halide photographic material of claim 1 or 2, wherein X in formula [I] is selected from the group consisting of a hydrogen atom, a halogen atom and an organic group having a carbon atom, an oxygen atom, a sulfur atom, a nitrogen atom or phosphorus atom through which said organic group is connected with the remainder of the compound. 4. The light-sensitive silver halide photographic material of claim 3, wherein X in formula [I] is selected from the group consisting of a halogen atom, an alkoxy group, an aryloxy group, a heterocyclicoxy group, an acyloxy group, a sulfonyloxy group, an alkoxycarbonyloxy group, on aryloxycarbonyloxy group, an alkyloxalyloxy group, an alkoxyoxalyloxy group, an alkylthio group, an arylthio group, a heterocyclicthio group, an alkyloxythiocarbonylthio group, a group represented by the formula (wherein R₄′ and R₅′ independently represent a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, a sulfamoyl group, a carbamoyl group, an acyl group, a sulfonyl group, an aryloxycarbonyl group and an alkoxycarbonyl group provided that R₄′ and R₅′ are not simultaneously hydrogen atoms and R₄′ and R₅′ may combine with each other to form a nitrogen-containing heterocyclic group), a carboxyl group, a hydroxymethyl group, a triphenylmethyl group and a group represented by the following formula, (wherein R¹′ is defined to be the same as R, Z′ is the same as defined for as Z, and R²′ and R³′ are independently selected from the group consisting of a hydrogen atom, an aryl group, an alkyl group and a heterocyclic group.). 5. The light-sensitive silver halide photographic material of any one of claims 1 to 4, wherein said nitrogen-containing heterocyclic ring in formula [I] is selected from the group consisting of a pyrazole ring, an imidazole ring, a triazole ring and a tetrazole ring provided that the above groups may have the same substituent as defined for R in formula [I]. 6. The light-sensitive silver halide photographic material of any one of claims 1 to 5, wherein said compound represented by general formula [I] is a magenta dye-forming coupler. 7. The light-sensitive silver halide photographic material of claim 6, wherein said magenta dye forming coupler is selected from a compound represented by formula [VIII]: (wherein R¹′, X and Z¹ have the same meaning as R, X and Z in formula [I]). 8. The light-sensitive silver halide photographic material of claim 6, wherein said magenta dye forming coupler is selected from a compound represented by formulae [II] to [VII]: (in the above formulae R¹ to R⁸ respectively have the same meaning as R in formula [I] and X has the same meaning as in formula [I]). 9. The light-sensitive silver halide photographic material of claim 6, wherein said magenta dye forming coupler is a compound represented by formula [XI]: (wherein R and X respectively have the same meaning as in formula [I], R¹ is an alkylene group and R² is selected from the group consisting of an alkyl group, a cycloalkyl group and an aryl group). 10. The light-sensitive silver halide photographic material of any one of claims 1 to 9, wherein said metal complex has a quenching rate constant of singlet oxygen of more than 1 x 10⁸ M⁻¹. sec⁻¹. 11. The light-sensitive silver halide photographic material of any one of claims 1 to 10, wherein said metal complex is selected from a compound represented by formulae [XII] to [XV]: in formulae [XII] to [XV], M represents a metal atom; X¹ and X² are independently selected from an oxygen atom, a sulfur atom and a -NR⁷- group, in which R⁷ is selected from the group consisting of a hydrogen atom, an alkyl group, an aryl group and a hydroxyl group; X³ is selected from the group consisting of a hydroxyl group and mercapto group; Y is selected from an oxygen atom and a sulfur atom; R³, R⁴, R⁵ and R⁶ are independently selected from the group consisting of a hydrogen atom, a halogen atom, a cyano group, on alkyl group an aryl group, a cycloalkyl group, a heterocyclic group, an alkyl group which connects with the carbon atom of the formulae through a divalent group, an aryl group which connects with the carbon atom of the formulae through a divalent group, a cycloalkyl group which connects with the carbon atom of the formulae through a divalent group and a heterocyclic group which connects with the carbon atom of the formulae through a divalent group provided that either R³ and R⁴ or R⁵ and R⁶ may be combined with each other to form a 5-membered or 6-membered ring together with the carbon atom to which R³ and R⁴ or R⁵ and R⁶ are commonly connected; Z⁰ is a compound which is capable of being a ligand to M or a residual group thereof; R²¹, R²², R²³ and R²⁴ are independently selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, an alkyl group which connects with the carbon atom of the formulae through a divalent group, an aryl group which connects with the carbon atom of the formulae through a divalent group, a cycloalkyl group which connects with the carbon atom of the formulae through a divalent group and a heterocyclic group which connects with the carbon atom of the formula through a divalent group provided that either R²¹ and R²², R²² and R²³ or R²³ and R²⁴ may be combined with each other to form a 6-membered ring; R²⁵ is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; and A is selected from a hydrogen atom, an alkyl group, an aryl group and a hydroxyl group). 12. The light-sensitive silver halide photographic material of claim 11, wherein M is a transition metal atom. 13. The light-sensitive silver halide photographic material of claim 11 or 12, wherein M is selected from nickel, copper, iron, cobalt, palladium and platinum. 14. The light-sensitive silver halide photographic material of claim 13, wherein M is nickel.

Inventors: NISHIJIMA, TOYOKI, ONODERA, KAORU
Applicants: KONICA CORPORATION
Application year: 1987
Main classification: G03C7
IPC codes: G03C7