STRUCTURES OF PLASTICS MATERIAL

Abstract: Large fittings or other structures are made by rotationally moulding a first component 18 of polyethylene and joining cylindrical pups 20, 22, 24 of polyethylene to the component by butt fusion joints 26, 28, 30. The structure within the boundary 50 is irradiated with gamma radiation followed by post-heating to remove free radicals. The extremities of the pups are shielded to prevent irradiation. Their capability to be joined to polyethylene pipes 12, 14, 16 by butt-fusion joints 32, 34, 36 is unimpaired. The irradiation introduces cross-linking to give improved properties such as impact resistance and stress crack resistance and to bring the fitting within the specification for polyethylene pipe for natural gas distribution. The joints 26, 28, 30 are made using differential heating of the ends to be joined to compensate for differences in melt flow index. Alternatively, the component 18 is slightly irradiated to lower its MFI before pups are joined to it.

Description: The invention relates to methods of making structures of plastics material as defined in the pre-characterising part of claim 1. Such a method is known from US-A-4056421 which describes a method of making a structure of plastics material comprising irradiating a first part of the structure to introduce or increase cross-linking in said first part to improve a property or properties thereof, a second part or second parts of the structure being kept free of irradiation, so that the capability of said second part or each of said second parts to be joined by fusion to polymeric plastics material remains unimpaired. It is upon this disclosure that the preamble of claim 1 is based. The method relates to making a sleeve, especially a heat-shrinkable sleeve, for pipes. The method uses a very thin sheet of plastics material which is irradiated, while flat, and which is then severed into lengths and the opposite ends of each length are then welded together so that a sleeve is formed. The ends are joined by a lap-joint which is made in a press having two opposed heated platens between which the joint is formed. The sleeve is thus made as a one component structure. In DD-A-0152236 there is described a method making inter alia tube joints by butt welding together two tubes using hot-tool welding. The tubes are 26 millimetres in inside diameter and are made of polythene. The tubes are irradiated with an electron beam of energy 0.5 MeV. This leaves a non-cross-linked core of 2mm width which allows the tubes to be butt welded. The outer layer of the tubes is cross-linked as the result of irradiation. Such a method cannot be used to give the advantages of cross-linking throughout the material of the tubes. If irradiation (contrary to the teaching of the specification) were applied at sufficient energy to produce cross-linking throughout the entire thickness of the tubes then the tubes could not be welded together. The method, by contrast, of the present invention allows the advantage of cross-linking to be applied throughout the first part of a structure through the whole thickness of material, while leaving the ability of other parts to be joined by fusion to other polymeric plastics material unaffected. In particular, the welded join which is possible is a full thickness fusion joint suitable for use in natural gas distribution systems and not the welded joint described in DD-A-0152236 in which only the core of the pipe thickness is joined. The object of the invention is to provide an economically viable method of making structures of plastics material including inter alia fittings for use in natural gas distribution. This object is met by a method which is characterised in that said structure is a multi-component pipe fitting of polymeric plastics material which fitting is capable of being joined to a pipe of polymeric plastics material in the field by fusion, said fitting comprising - as a first component - a hollow body moulded rotationally from rotational moulding grade polymeric plastics material having a Melt Flow Index (MFI) of 1.5 or greater and formed with at least one annular body end portion having an outside diameter of hundreds of millimetres and a wall thickness of tens of millimetres and said fitting further comprising for each said body end portion, as a further component, a corresponding hollow pup formed by extrusion from extrusion grade polymeric plastics material having an MFI of 1.0 or less, said pup having at opposite ends thereof first and second annular pup end portions having an outside diameter and a wall thickness to match the annular body end portion to which it is joined, said method comprising the steps of: (i) forming an annular joint between each said body end portion and said first pup end portion of said corresponding pup under factory conditions by fusion thus forming a multi-component structure, said fusion step comprising heating the body to a first relatively higher temperature and the pup to a second relatively lower temperature said temperatures being chosen to compensate for the difference in MFI's; (ii) shielding each said second pup end portion against the effect of gamma radiation, leaving the remainder of said structure unshielded; (iii) exposing the whole of said remainder of said structure including each said joint to gamma radiation to produce cross-linking within said remainder thereby to enhance the resistance thereof to slow crack growth; said second pup end portion affording capability for said pup to be joined to said pipe in the field by fusion as aforesaid. The above object is alternatively met by a method which is characterised in that said structure is a multi-component pipe fitting of polymeric plastics material which fitting is capable of being joined to a pipe of polymeric plastics material in the field by fusion, said fitting comprising as - a first component - a hollow body moulded rotationally from rotational moulding grade polymeric plastics material having a Melt Flow Index (MFI) of 1.5 or greater and formed with at least one annular body end portion having an outside diameter of hundreds of millimetres and a wall thickness of tens of millimetres and said fitting further comprising for each said body end portion as a further component a corresponding hollow pup formed by extrusion from extrusion grade polymeric plastics material having an MFI of 1.0 or less, said pup having at opposite ends thereof first and second annular pup end portions having an outside diameter and a wall thickness to match the annular body end portion to which it is joined, said method comprising the steps of: (i) subjecting said body before joining said pup or pups thereto to a preliminary exposure to gamma radiation to lower the MFI thereof so that said index approaches that of the or each pup; (ii) forming an annular joint between each said body end portion and said first pup end portion of said corresponding pup under factory conditions by fusion thus forming a multi-component structure, said fusion step comprising heating the body and the pup to a common temperature; (iii) shielding each said second pup end portion against the effect of gamma radiation, leaving the remainder of said structure unshielded; (iv) exposing the whole of said remainder of said structure including each said joint to gamma radiation to produce cross-linking within said remainder thereby to enhance the resistance thereof to slow crack growth said second pup end portion affording capability for said pup to be joined to said pipe in the field by fusion as aforesaid. Typically, for example, the structure is a fitting intended to be joined to plastics material in the form of pipe. Examples of the method and embodiments of structures so made will now be described by way of example with reference to the accompanying drawings in which: Figure 1 is a diagrammatic side-elevation of one such embodiment in the form of a T-fitting shown in use forming part of a pipe system; and Figure 2 is an enlarged scrap sectional view through one of the joints in the fitting at II in Figure 1. The drawings show part of a distribution pipe system for natural gas in which a T-fitting 10 having three limbs is joined to pipe lengths 12, 14, 16. The fitting 10 and the pipes 12, 14, 16 are made of for example, extrusion grade polyethylene. The fitting 10 comprises four components namely: a hollow T-shaped component 18, which is made by rotational moulding polyethylene of rotational moulding grade, and three hollow cylindrical pups 20, 22, 24 each being a short length of extrusion grade polyethylene which is suitable for joining to the material of the pipes 12, 14, 16 by fusion. The pups and the pipes both have outside diameters of typically 500 millimetres and wall thickness of 30mm. Each pup is some 500mm long and the length of the component 18 is some 1000mm between the pups 20, 22. The overall vertical dimension of the component 18 is seen in the positive shown in Figure 1 is some 725mm. The fitting 10 is therefore relatively large. The pups 20, 22, 24 are joined to the component 18 by respective butt fusion joints at 26, 28, 30 and the pipes 12, 14, 16 are similarly joined to the pups at respective joints 32, 34, 36. At each joint upset material is displaced during the jointing process to form internal and external beads. Figure 2 shows the joint at 28 on an enlarged scale, the internal and external beads 40, 42 being shown. In one form of the method the fusion joints between the components 18 and the pups 20, 22, 24 are made in the factory using apparatus in which there are two plates heated to different temperatures against which the component and pup are forced to heat their ends. The temperature difference is for example 20°-50°C and is chosen to compensate as far as possible for the different melt flow indicies (MFI's) of the two materials, that of the component 18 being relatively higher. Once the ends are heated sufficiently the plates are removed and the ends are forced together. The MFI is expressed as grammes/10 minutes at 190° Centigrade under a load of 2.16 kilogrammes. The MFI is a measure of the viscosity of the molten materials. The pipes are jointed to the pups in the field using a similar method but only a single plate is necessary as the materials of the pipes and pups are identical. Typically the MFI of the rotational moulding grade polyethylene of the component 18 is between 1.5 and 10 but may be as high as 20 for example. By contrast the MFI of the extrusion grade polyethylene of the pups is 0.2 or less but may be as high as 1.0 say. This implies a major discrepancy in the viscosities of the molten materials at the ends against the heating plate, which has made it impracticable to butt joint the ends under field conditions. The wall thickness of the component 18 may be equal throughout to that of the pups but alternatively the end portions of the limbs of the component 18 are of reduced thickness equal to the wall thickness of the pups while the remainder of the component 18 has a greater wall thickness. After the pups have been joined to the component 18 in the factory, the resulting multi-component structure is partly exposed to gamma radiation. The outermost halves of the pup components 20, 22, 24 are not exposed to the radiation. The remainder of the structure, that is the parts within the boundary 50 shown in Figure 1, is irradiated. The irradiation is performed in a water bath or with a blanket of nitrogen covering the structure to prevent oxidation. Forced nitrogen flow may be used during irradiation and during a period of heating after irradiation if such heating is used. It is preferred to use post-heating to 80°-90° to remove free radicals resulting from the irradiation stage. During cooling of the structure the nitrogen blanket persists but forced flow is no longer necessary. The dose of radiation given to the structure is selected to be sufficient to convert for example between 10% and 80%, of the polyethylene to insoluble gel structure in which cross-linking is present. This enhances the resistance to slow crack growth and therefor the overall performance characteristics of the fitting can thus be brought for example within British Gas plc's 1986 specification, for polyethylene pipes and fittings. The dose, for example, may be 200-300 kilo Grays. Materials of the so-called pro-rad kind can be incorporated in the rotational moulding grade polyethylene to alter the effect of the radiation. Anti-rad material can be incorporated in the pups in addition or as an alternative to the use of the pro-rad material. Other properties than those mentioned can, of course, be introduced or enhanced by irradiation depending on the application for which the structure is intended. It is preferred to check the structure as follows: after fusion and before irradiation, the external bead 42 (Figure 2) at each joint 26, 28, 30 is machined off and examinations are carried out to determine whether any slits are present in the joints. After irradiation, the internal bead 40 (Figure 2) is machined off and each of the joints 26, 28, 30 is tested for the proportion of gel formed. As an alternative, indicators can be used which give an indication of the irradiation dose. The joining of unirradiated end portions of the pups by butt fusion to polyethylene pipes is unimpaired. This can be checked by machining off samples from the ends of the pups and conducting an MFI test. In a modification of the method, the component 18 is exposed to a minor dose of radiation before the pups 12, 14, 16 are jointed to the component 18. Such a radiation dose is typically for example 10-30 kGy, approximately one tenth of the total dose. It does not improve the stress crack resistance but it lowers the MFI of the component 18 to a value the same as or close to that of the pups. When the pups are joined to the component 18 only a single heater plate needs to be used, engaged at opposite sides by the pup and the limb of the component 18. After the pups are joined, the structure is irradiated but the dose is adjusted to take account of the preliminary dose already given to the component 18. In other modifications (not shown) instead of using butt joints it is possible to use socketed joints or electro-fusion joints which are irradiated in a manner similar to that already described. The invention is not limited to the manufacture of T-fittings nor is it limited to structures for use in gas pipe systems. For example, structures for use in water supply and process installations can be made using the method. In addition to T-fittings, structures which can be made include Reducers, Reducer T-fittings, Short Bends, Valves, Flanged fittings, Pipes and Pressure Vessels. The method described above enables relatively economical methods such as rotational moulding, for example, to be used to form a structure or part of it, after which the desired property or properties can be introduced or enhanced. However, the joining capability of the material remains unimpaired. The invention is applicable to polymeric materials other than polyethylene e.g. polyethylene co-polymers and polyvinyl chloride. Also, the components of the structure need not all be made of the same material.

Claims: A method of making a structure of plastics material comprising irradiating a first part of the structure to introduce or increase cross-linking in said first part to improve a property or properties thereof, a second part or second parts of the structure being kept free of irradiation, so that the capability of said second part or each of said second parts to be joined by fusion to polymeric plastics material remains unimpaired characterised in that said structure is a multi-component pipe fitting (10) of polymeric plastics material which fitting is capable of being joined to a pipe (12,14,16) of polymeric plastics material in the field by fusion, said fitting comprising - as a first component - a hollow body (18) moulded rotationally from rotational moulding grade polymeric plastics material having a Melt Flow Index (MFI) of 1.5 or greater and formed with at least one annular body end portion having an outside diameter of hundreds of millimetres and a wall thickness of tens of millimetres and said fitting (10) further comprising for each said body end portion - as a further component - a corresponding hollow pup (20,22,24) formed by extrusion from extrusion grade polymeric plastics material having an MFI of 1.0 or less, said pup (20,22,24) having at opposite ends thereof first and second annular pup end portions having an outside diameter and a wall thickness to match the annular body end portion to which it is joined, said method comprising the steps of: (i) forming an annular joint between each said body end portion and said first pup end portion of said corresponding pup (20,22,24) under factory conditions by fusion thus forming a multi-component structure (10), said fusion step comprising heating the body (18) to a first relatively higher temperature and the pup (20,22,24) to a second relatively lower temperature said temperatures being chosen to compensate for the difference in MFI's; (ii) shielding each said second pup end portion against the effect of gamma radiation, leaving the remainder of said structure (10) unshielded; (iii) exposing the whole of said remainder of said structure (10) including each said joint to gamma radiation to produce cross-linking within said remainder thereby to enhance the resistance thereof to slow crack growth; said second pup end portion affording capability for said pup (20,22,24) to be joined to said pipe (12,14,16) in the field by fusion as aforesaid. A method according to claim 1, said fusion step comprising using a socketed joint to join the or each pup (20,22,24) to the body (18). A method of making a structure of plastics material comprising irradiating a first part of the structure to introduce or increase cross-linking in said first part to improve a property or properties thereof, a second part or second parts of the structure being kept free of irradiation, so that the capability of said second part or each of said second parts to be joined by fusion to polymeric plastics material remains unimpaired characterised in that said structure is a multi-component pipe fitting (10) of polymeric plastics material which fitting is capable of being joined to a pipe (12,14,16) of polymeric plastics material in the field by fusion, said fitting comprising as a first component a hollow body (18) moulded rotationally from rotational moulding grade polymeric plastics material having a Melt Flow Index (MFI) of 1.5 or greater and formed with at least one annular body end portion having an outside diameter of hundreds of millimetres and a wall thickness of tens of millimetres and said fitting (10) further comprising for each said body end portion - as a further component - a corresponding hollow pup (20,22,24) formed by extrusion from extrusion grade polymeric plastics material having an MFI of 1.0 or less, said pup (20,22,24) having at opposite ends thereof first and second annular pup end portions having an outside diameter and a wall thickness to match the annular body end portion to which it is joined, said method comprising the steps of: (i) subjecting said body (18) before joining said pup or pups (20,22,24) thereto to a preliminary exposure to gamma radiation to lower the MFI thereof so that said index approaches that of the or each pup (20,22,24); (ii) forming an annular joint between each said body end portion and said first pup end portion of said corresponding pup (20,22,24) under factory conditions by fusion thus forming a multi-component structure (10), said fusion step comprising heating the body (18) and the pup (20,22,24) to a common temperature; (iii) shielding each said second pup end portion against the effect of gamma radiation, leaving the remainder of said structure (10) unshielded; (iv) exposing the whole of said remainder of said structure (10) including each said joint to gamma radiation to produce cross-linking within said remainder thereby to enhance the resistance thereof to slow crack growth said second pup end portion affording capability for said pup (20,22,24) to be joined to said pipe (12,14,16) in the field by fusion as aforesaid. A method according to claim 3, said fusion step comprising using an electro-fusion fitting to join the or each pup (20,22,24) to the body (18).

Inventors: BOWMAN, JEREMY ARCHIBALD, GREIG, MARTYN JOHN
Applicants: BRITISH GAS PLC
Application year: 1987
Main classification: B29C71
IPC codes: B29C41, B29C65, B29C71, B29D23, B29C35