LIQUID CRYSTAL DISPLAY ELEMENT

Abstract: A liquid crystal display element comprising a pair of sub­ strates, a pair of electrodes provided on the respective sub­ strates, at least one of which is transparent and a liquid crystal layer disposed between said substrates, the liquid crystal layer comprising a nematic liquid crystal, which exhi­ bits a positive dielectric constant anisotropy and contains an optically active substance, the liquid crystal molecule orienta­ tion direction in the liquid crystal layer is twisted in the range of 200° to 250° from the one substrate surface toward the other substrate surface so as to form a helical structure therein. A polyimide orientation film is provided between the electrodes and the liquid crystal layer. The polyimide orienta­ tion film is one made of polyimide prepared by reacting a diamine compound having a long-chain hydrocarbon group or a diamine compound having a trifluoromethyl group with a tetracarboxylic dianhydride and causes a pretilt angle of at least 3° relative to the nematic liquid crystal molecules. The liquid crystal display element of the present invention is free from a scattering domain.

Description: This invention relates to liquid crystal display elements employing a liquid crystal having a helical structure with a twist angle between the substrates in the range of 200 to 250°, and a particular orientation film which are free from scattering domains. In conventional liquid crystal elements of the so-called twisted nematic (TN) type, the liquid crystal molecule orientation is controlled by means of orientation films disposed on the substrates comprising the electrodes so as to be twisted by 90°. Silicon monoxide (SiO) films obtained by oblique evaporation, and polyimide-based materials have mainly been used as orientation films. However, with TN type liquid crystal elements, large-capacity displays cannot be realized because difficulties are encountered in attaining a great improvement in the time sharing characteristics. On the other hand, liquid crystal elements taking advantage of the so-called supertwisted birefringence effect (SBE) attained by orienting the liquid crystal molecules at a twist angle of 270° from one substrate to the other was reported at 1985 SID International Symposium held at Orlando FL. U.S.A. on April 30 - May 2 (SID 85 DIGEST, pp. 120 - 123) and is expected as a liquid crystal element which may find a new field of applications for liquid crystals. However, a liquid crystal element such as an SBE liquid crystal element in which the twisted angle of the liquid crystal modecules is e.g. 270°, much larger than 90° which is adopted in the conventional TN mode liquid crystal elements, cannot successfully be combined with the conventional orientation films causing a small tilt angle which was subjected to orientation treatment by rubbing, because such a combination brings about a scattering domain (a domain in which light is scattered), which leads to a poor display quality. Until now no way has been found to prevent occurrence of the scattering domain except for making the tilt angle of the liquid crystal molecules by the orientation film larger. Although oblique evaporation is a means for making the tilt angle larger, it is unsuited for mass production of such an orientation film. Therefore, the realization of a film made of an organic polymer capable of causing a tilt angle larger than that by the conventional orientation film has been an important task to be attained. In the conventional TN mode liquid crystal element which uses a nematic liquid crystal, the smaller the tilt angle caused by the orientation film, the better are the time sharing drive characteristics. Therefore, TN type liquid crystal elements have been prepared using orientation film materials causing a tilt angle of about 3° or less. However, in contrast to TN type liquid crystal elements, SBE type liquid crystal elements have the problem of occurrence of scattering domains due to a small tilt angle of the liquid crystal molecules caused by the orientation film. It is the object of the present invention to provide SBE type liquid crystal display elements in which the twist angle of the nematic liquid crystal molecule orientation from one substrate to the other is in the range of 200 to 250°, and in which an orientation film made of an organic polyemr is used for orienting the liquid crystal molecules which does not lead to the occurrence of scattering domains. The liquid crystal display element of the present invention comprises a pair of substrates, at least one of which is transparent, electrodes provided on the respective substrates, a liquid crystal layer disposed between the substrates comprising a nematic liquid crystal material which exhibits a positive dielectric constant anisotropy and contains an optically active substance, the liquid crystal molecule orientation direction in the liquid crystal layer being twisted by a twist angle of 200 to 250° from the surface of one of the substrates toward the surface of the other substrate so as to form a helical structure, and a polyimide orientation film provided on the substrates with the electrodes; characterized in that the polyimide orientation film consists of a polyimide copolymer prepared by subjecting a diamine compound comprising a long-chain hydrocarbon group and a diamine compound comprising a trifluoromethyl group with a tetracarboxylic acid dianhydride to copolycondensation, or of a polyblend of such polyimide copolymers and is subjected to rubbing to cause a tilt angle of the liquid crystal molecules contiguous to the polyimide orientation film of at least 3°. US-A-4 494 824 discloses liquid crystal display devices comprising orientation films on the basis of an organic copolymer resin and particularly a polyimide-siloxane copolymer resin. The orientation of these films is controlled by rubbing treatment. Examples of diamine compounds having a long-chain hydrocarbon group are disclosed in column 5, second paragraph, of this document, however, there is no indication whether or not the resulting polyimide-siloxane copolymer resin films are suitable for causing a tilt angle of at least 3° after rubbing treatment. The above-mentioned diamine compound comprising a long-chain hydrocarbon group is selected from compounds represented by the general formula I X - (CH₂) n - X (I) wherein X is -NH₂ or -CONH-NH₂, and n is an integer of 8 to 13. The above-mentioned diamine compound comprising a trifluoromethyl group is preferably selected from compounds represented by the general formula II wherein X is Examples of such diamine compounds are: H₂N- (CH₂)₈ - NH₂ H₂N- (CH₂)₉ - NH₂ H₂N- (CH₂)₁₀ - NH₂ H₂N- (CH₂)₁₁ - NH₂ H₂N- (CH₂)₁₂ - NH₂ H₂N- (CH₂)₁₃ - NH₂ H₂N-NHCO - (CH₂)₈ - CONH-NH₂ H₂N-NHCO - (CH₂)₉ - CONH-NH₂ H₂N-HNCO - (CH₂)₁₀ - CONH-NH₂ H₂N-NHCO - (CH₂)₁₁ - CONH-NH₂ H₂N-NHCO - (CH₂)₁₂ - CONH-NH₂ H₂N-NHCO - (CH₂)₁₃ - CONH-NH₂ Examples of the tetracarboxylic acid dianhydride are: The polyimide copolymer may be prepared by using at least one further diamine compound selected from diaminodiphenyl ethers represented by the general formula III wherein n is 0 or 1 , and diaminosiloxanes represented by the general formula IV wherein Ar₁ is an alkylene or phenylene group, and Ar₂ is an alkyl or aryl group. Specific examples of compounds represented by the above general formula IV are: The polyimide orientation film is made of a polyimide copolymer obtained by subjecting the above-mentioned diamine compounds and the tetracarboxylic dianhydride to copolycondensation. Alternatively, the polyimide orientation film may be made of a polyblend of the respective polyimide copolymers obtained through copolycondensation. If necessary, a silane coupling agent may be added to the polymer. The occurrence of scattering domains is prevented through the selection of orientation films causing a tilt angle of the nematic liquid crystal molecules of at least 3°. In the liquid crystal elements of the present invention, in order to adjust the twist angle of the liquid crystal molecules at 200 to 250°, it is necessary to incorporate an optically active substance in the liquid crystal. The optically active substances may be those which are generally used. For example, an optically active substance such as S 811, S 996 or S 1082 (products of Merck, DE) or C-15 or CB-15 (products of British Drug Houses, GB) is preferably added to a nematic liquid crystal in an amount of 0.5 to 1% by mass, based on the nematic liquid crystal. The liquid crystal to be used in the present invention may be a nematic liquid crystal which is generally used in TN type liquid crystal elements. The above-mentioned orientation film may be formed on the substrates for the liquid crystal elements in the same manner as for the TN type elements, i.e., by methods such as immersion, spin coating, spray coating, and printing using the synthetic polyimide varnish. The formed film is subjected to rubbing to cause an intended tilt angle of the liquid crystal molecules contiguous to the film The orientation film as used according to the present invention may also be formed on an inorganic film made of SiO₂, Al₂O₃ or TiO₂. EXAMPLE As indicated in Table 1 a diamine compound having a long-chain hydrocarbon group as and a diamine compound having trifluoromethyl groups was copolycondensated with pyromellitic acid dianhydride in a solvent to obtain a polyamic acid varnish. The varnish thus obtained was applied on a substrate for a liquid crystal element and then baked at 250 °C to obtain an 80 nm thick polyimide film. Subsequently, in order to adjust the twist angle of the liquid crystal molecules at 250°, the upper and lower electrode substrates were subjected to rubbing at the corresponding angles. A spacer was then disposed between the substrates to assemble a liquid crystal cell having a gap of 8µm. A mixture of a nematic liquid crystal having a positive dielectric constant anisotropy and composed mainly of a biphenyl liquid crystal, an ester cyclohexane (ECH) liquid crystal and a phenylcyclohexane (PCH) liquid crystal comprising 0.5% by weight of the optically active substance S 811 (product of Merck) was then introduced into the gap by means of vacuum to form a liquid crystal display element. Thereafter, the absorption axes of the upper and lower polarizing plates were adjusted to examine whether or not scattering domains (domains where light is scattered) occured. The tilt angle caused by the above-prepared orientation film was determined using a biphenyl liquid crystal E-7 (a product of British Drug Houses) by the customary rotational method with a He-Ne laser. The results are shown in Table 1. COMPARATIVE EXAMPLE 1 4,4'-diaminodiphenyl ether as listed in Table 2 was polycondensated with pyromellitic acid dianhydride in a solvent to obtain a polyamic acid varnish. The varnish thus obtained was applied on a substrate for a liquid crystal element and then baked at 250 °C to obtain an 80 nm thick polyimide film. Using the above-obtained orientation film, a liquid crystal display element was formed in substantially the same manner as in the above EXAMPLE, and the same tests were conducted on the element. The results are shown in Table 2. COMPARATIVE EXAMPLE 2 4,4'-bis (p-aminophenoxy)-2,2-diphenylpropane as listed in Table 2 was polycondensated with isophthaloyl chloride in a solvent to obtain a polyamide varnish. The varnish thus obtained was applied on a substrate for a liquid crystal element and then baked at 200 °C to obtain a 60 nm thick polyimide film. Using the above-obtained orientation film, a liquid crystal display element was formed in substantially the same manner as in the above EXAMPLE, and the same tests were conducted on the element. The results are shown in Table 2. As is apparent from Tables 1 and 2, the liquid crystal element according to the present invention was free of scattering domains, whereas the liquid crystal elements obtained according to the Comparative Examples did show scattering domains. As is apparent from the foregoing description, the SBE-mode liquid crystal elements according to the present invention are suitable for mass production. The liquid crystal display elements of the present invention can be advantageously used as optical modulating elements and for large scale displays.

Claims: A liquid crystal display element comprising a pair of substrates, at least one of which is transparent, electrodes provided on the respective substrates, a liquid crystal layer disposed between the substrates comprising a nematic liquid crystal material which exhibits a positive dielectric constant anisotropy and contains an optically active substance, the liquid crystal molecule orientation direction in the liquid crystal layer being twisted by a twist angle of 200 to 250° from the surface of one of the substrates toward the surface of the other substrate so as to form a helical structure, and a polyimide orientation film provided on the substrates with the electrodes, characterized in that the polyimide orientation film consists of a polyimide copolymer prepared by subjecting a diamine compound comprising a long-chain hydrocarbon group and a diamine compound comprising a trifluoromethyl group with a tetracarboxylic acid dianhydride to copolycondensation, or of a polyblend of such polyimide copolymers and is subjected to rubbing to cause a tilt angle of the liquid crystal molecules contiguous to the polyimide orientation film of at least 3°. The liquid crystal display element according to claim 1, characterized in that the diamine compound comprising a long-chain hydrocarbon group is selected from compounds represented by the general formula I X - (CH₂) n - X (I) wherein X is -NH₂ or -CONH-NH₂, and n is an integer of 8 to 13, and the diamine compound comprising a trifluoromethyl group is selected from compounds represented by the general formula II wherein X is The liquid crystal display element according to claim 1 or 2, characterized in that the polyimide copolymer is prepared by using at least one further diamine compound selected from diaminodiphenyl ethers represented by the general formula III wherein n is 0 or 1, and diaminosiloxanes represented by the general formula IV wherein Ar₁ is an alkylene or phenylene group, and Ar₂ is an alkyl or aryl group.

Inventors: ERA, SUSUMU, FUJISAKI, KOOJI, HANAWA, YASUO, IWASAKI, KISHIRO, KANDO, YASUHIKO, KITAMURA, TERUO, MUKOH, AKIO, NAKATA, TADAO, NARAHARA, TOSHIKAZU, NUMATA, SHUNICHI, YOKOKURA, HISAO
Applicants: HITACHI, LTD.
Application year: 1987
Main classification: G02F1
IPC codes: G02F1, C08G73