Process for producing composite baked food products

Abstract: Fats and oils can be prevented from migration by using, when cakes are baked, a fat which contains 10% by weight or more of a disaturated­ monounsaturated mixed triglyceride wherein at least one fatty acid residue among the three constituent fatty acids thereof is a saturated fatty acid having 20 to 24 carbon atoms.

Description: This invention relates to a process for producing a composite baked food product which is obtained by embedding a baked food product comprising fats and oils as main ingredients in chocolate or cream, coating said baked food product with chocolate or cream, or inserting or dispersing chocolate or cream in said baked food product. It is known that baked cakes such as biscuits and cookies among various foods containing oleaginous ingredients appear to be coated with white powder or display white spots on the surface upon storage. Similar phenomena are observed in hard butter products including chocolates, confectionary coatings containing hard butter and chocolate coatings. It is further known that very marked whitening is observed on the surface of chocolate in a composite product where a hard butter product is contacted or combined with a baked food product such as a biscuit or a cookie, for example, those prepared by dispersing the former in the latter; coating the latter with the former; or inserting the former into the latter. This whitening on the surface of a baked cake or a composite baked cake, which is called blooming, not only spoils the appearance of the product but also softens the chocolate, so damaging the commercial value of the product. Although the detailed mechanism of this blooming in biscuits and chocolates has not been clarified yet, it is assumed to proceed in the following manner. Oleaginous ingredients contained in a biscuit are completely molten during baking. Solid fats crystallize during the subsequent cooling step. During cooling, the surface temperature is different from the internal one and thus nuclei of crystals are formed on the cooler surface. Since the cooling rate employed in the production of biscuits is very low, the crystalline solid fat ingredient within the biscuit will grow around the crystalline nuclei on the surface. A change in the temperature during storage further accelerates the growth of the crystals, which causes blooming on the surface of the biscuit. On the other hand, the separated liquid oil, which is localized within the biscuit, would migrate into an oil-absorptive material, if in contact therewith, and thus be absorbed therein. Thus the melting point of the oil-absorptive material is lowered, which softens it. Therefore the oleaginous ingredients of the biscuit are liable to suffer from melting caused by a temperature change, recrystallization and growth of crystals, which significantly lowers their resistance to blooming. Accordingly, it is believed that blooming of a food product such as a biscuit or a cookie or a hard butter product in contact therewith might be caused by the migration of particular oleaginous components of the product followed by the growth of crystals thereof. According to EP-A-027364, the problem of fat blooming in chocolate and other hard butter products is caused by the polymorphism of the fat crystals. EP-A-0196780 describes a fat blooming inhibitor which inhibits fat blooming when added to fats such as cacao butter by promoting the formation of micro-crystals. It is known that blooming of a hard butter product such as a chocolate per se can be inhibited to some extent by adding fats and oils other than cacao butter thereto. However there has been known no process for inhibiting the migration of particular oleaginous ingredients in a baked food product such as a biscuit or a cookie during the solidification step wherein the product at a high temperature is slowly cooled. In order to maintain the texture, flavour and appearance of a baked cake excellent for a prolonged period of time, it is required to minimize the migration of particular components of oleaginous ingredients of said baked cake, which would reduce the quality of the cake, during production and/or storage. We have examined the effects of various alkyl groups on the crystallizing behaviours of triglycerides in order to obtain fats and oils which would remain uniform and show no migration under such severe conditions as those employed in the production of a baked food product such as a biscuit or a cookie wherein a product at a high temperature, for example 60° C or above, is slowly cooled. As a result, we have found that a fat, which contains 10% by weight or more of a triglyceride of a particular composition, i.e., a disaturated-monounsaturated mixed triglyceride wherein at least one fatty acid residue among the three constituent fatty acids thereof is a saturated fatty acid having 20 to 24 carbon atoms, exerts an effect of inhibiting the migration of fats and oils for baked cakes, thus completing the present invention. According to the present invention we provide a process for producing a composite baked food product which is obtained by embedding a baked food product comprising fats and oils as main ingredients in chocolate or cream; coating said baked food product with chocolate or cream; or inserting or dispersing chocolate or cream in said baked food product, characterised in that the fat(s) contain 0.5 to 100% by weight of a migration inhibitor for fats and oils for baked food products comprising a fat which contains 10% by weight or more of a disaturated-monounsaturated mixed triglyceride wherein at least one fatty acid residue among the three constituent fatty acids thereof is a saturated fatty acid having 20 to 24 carbons atoms; are used as the oleaginous ingredients of said baked food product. We also provide a baked food product obtained by the process defined in the preceding paragraph. The fat containing 10% by weight or more of a disaturated-monounsaturated mixed triglyceride wherein at least one fatty acid residue among the three constituent fatty acids thereof is a saturated fatty acid having 20 to 24 carbon atoms, which will be simply called "the fat for the present invention" hereinafter shows specific crystallizing properties. That is, when the fat for the present invention per se is dissolved in a liquid oil and then slowly cooled, it does not form macrocrystals similar to those which a disaturated-monounsaturated mixed triglyceride comprising stearic or palmitic acid forms, but is uniformly dispersed in the oil in the form of microcrystals to thereby form a dense network. Thus the dispersion becomes a gel-like solid and the migration of the liquid oil is inhibited thereby. In addition, the fat for the present invention exhibits a surprising effect of suppressing the crystallization of other solid fats. Thus triglycerides comprising stearic and palmitic acids, which have no effect of inhibiting migration per se, would exert a migration-inhibiting effect in the presence of the fat for the present invention. Therefore the fat for the present invention can exert the effect of inhibiting the migration of other fats and oils in an extremely small amount, i.e., 0.5% by weight or above, preferably 1% by weight or above. The fat for the present invention is characterized in that the presence of a long-chain saturated fatty acid residue having 20 to 24 carbon atoms might bring about the effect of inhibiting the migration of fats and oils. This effect might be further enhanced when the disaturated-monounsaturated mixed triglyceride has two saturated fatty acid residues each having 20 to 24 carbon atoms. However the above effect depends neither on the type of the unsaturated fatty acid constituting the unsaturated fatty acid residue nor on the binding position of the same. The fat for the present invention can be obtained by various methods which are not particularly restricted. For example, the following methods may be employed therefor. An extremely hardened oil obtained from fat(s) and/or oil(s) containing a large amount of unsaturated fatty acids having 20 to 24 carbon atoms, e.g., cruciferous oils such as high-erucic rapeseed oil or fish oil, behenic triglyceride and/or a composition thereof with other fat(s) and/or oil(s) are subjected to transesterification with fat(s) and/or oil(s) containing a large amount of unsaturated acids such as soybean, rapeseed, olive, safflower and cottonseed oils with the use of an alkali catalyst such as sodium methylate to give the fat for the present invention. Alternately, the fat for the present invention may be obtained by transesterifying a composition which comprises fat(s) and/or oil(s) containing a large amount of saturated fatty acid(s) having 20 to 24 carbon atoms and unsaturated fatty acid(s) or fat(s) and/or oil(s) containing a large amount of unsaturated fatty acid(s) and saturated fatty acid(s) having 20 to 24 carbon atoms with the use of lipase. The transesterified oil thus obtained may be refined and used as such as a migration inhibitor for fats and oils for baked cakes. Alternately, an enhanced effect can be achieved by fractionating the trisaturated triglyceride(s) and triunsaturated triglyceride(s) thus formed and concentrating the disaturated-monounsaturated mixed triglyceride(s) having 20 to 24 carbon atoms, if required. The fat for the present invention thus obtained can be used as such as a migration inhibitor for fats and oils for baked cakes. Further they can be introduced into other fat(s) and/or oil(s) in such a ratio as to give a content of the fat for the present invention of 0.5% by weight or more, preferably 0.5 to 100% by weight. As described above, the present invention relates to the application of the specific properties and behaviors of a disaturated-monounsaturated mixed triglyceride, wherein at least one fatty acid residue among the three constituent fatty acids thereof is a long-chain saturated fatty acid residue having 20 to 24 carbon atoms, as a migration inhibitor for fats and oils for baked cakes. Different from common solid fats comprising stearic and palmitic acids as main components, the fat for the present invention is in the form of a transparent waxy solid which has an excellent spreadability and properties similar to those of acetin fat. When dissolved in a liquid oil and then slowly cooled, it does not show any growth of crystals caused by concentrated solid fat components but is uniformly precipitated in the system in the form of microcrystals. Simultaneously, they form a network of the microcrystals which inhibits the separation of liquid oil components. These effects extend not only on the fat for the present invention per se but also over other solid fats and thus alter the crystallizing behaviors thereof. Thus common fats and oils also exert a migration-inhibiting effect in the presence of the fat for the present invention. In the case of composite baked cakes obtained by coating a baked cake such as a biscuit or a cookie with chocolate or cream, inserting or dispersing the latter in the former, or embedding the former in the latter, spotted discoloration on the surface and inside of the baked cake portion or whitening of the whole product is frequently observed during the storage or transportation of the cakes. These phenomena seriously deteriorate the appearance of the product and make the same moldy to thereby damage the commercial value thereof. The migration inhibitor for fats and oils for baked cakes of the present invention is very effective in inhibiting the spotted discoloration and whitening of the composite baked cakes as described above. This effect is believed to be caused by the fact that the migration inhibitor of the present invention can inhibit the migration of fats and oils contained in the baked cake and chocolate or cream. Examples: To further illustrate the present invention, the following Synthetic Examples and Examples will be given wherein all % and parts are by weight. Synthetic Example 1 High-erucic rapeseed oil was hydrogenated to give an extremely hardened oil having an iodine value of 2 or below (fatty acid composition: 4.2% of palmitic acid, 42.2% of stearic acid, 5.6% of arachic acid and 47.3% of behenic acid). To 30 parts of this high-erucic rapeseed oil, 70 parts of rapeseed oil (fatty acid composition: 3.0% of palmitic acid, 1.7% of stearic acid, 57.1% of oleic acid, 21.9% of linolic acid, 12.7% of linolenic acid and 1.7% of erucic acid) was added and the resulting mixture was subjected to transesterification at 80°C for 30 minutes with the use of 0.1%, based on the oils, of sodium methylate as a catalyst. The transesterified oil thus obtained was washed with water, decolorized and deodorized in a conventional manner to give the product (1) of the present invention. Synthetic Example 2 To 50 parts of behenic triglyceride (fatty acid composition: 2.4% of stearic acid, 9.9% of arachic acid and 84.9% of behenic acid), 50 parts of olive oil (fatty acid composition: 10.9% of palmitic acid, 3.7% of stearic acid, 80.5% of oleic acid and 5.0% of linolic acid) was added and the resulting mixture was subjected to transesterification at 80° C for 30 minutes with the use of 0.1%, based on the oils, of sodium methylate as a catalyst. The transesterified oil thus obtained was washed with water, decolorized and deodorized in a conventional manner to give the product (2) of the present invention. Synthetic Example 3 4 ml/g of acetone was added to the transesterified oil obtained in Synthetic Example 2 and dissolved therein. Then the solution was cooled from 50° C to 30° C under stirring and a high-melting fraction thus precipitated, which comprised trisaturated triglycerides as the main component, was filtered out (yield: 15% based on the transesterified oil). The filtrate was further cooled to 10°C under stirring and the aimed fraction thus precipitated was collected. After distilling off the solvent from this fraction, the residue was deodorized in a conventional manner to give the product (3) of the present invention. Table 1 shows the iodine values, melting points and fatty acid compositions, which were determined by gas chromatography, of the products (1) to (3) of the present invention as obtained in the above Synthetic Examples 1 to 3. Table 2 shows the triglyceride compositions thereof, which were determined by silver nitrate-containing silica gel thin layer chromatography and gas chromatography. Example 1 The products (1) to (3) of the present invention as obtained in Synthetic Examples 1 to 3 were added to shortening for baked cakes, which had a melting point of 36° C and an iodine value of 54.3 and was free from any saturated fatty acids having 20 or more carbon atoms (fatty acid composition: 1.1% of lauric acid, 1.4% of myristic acid, 26.1% of palmitic acid, 5.8% of stearic acid, 63.7% of oleic acid including elaidic acid and 0.9% of eicosenoic acid), and the migration-inhibiting effect of each product was evaluated. In addition, the effect of extremely hardened high-erucic rapeseed oil was similarly evaluated for comparison. Evaluation of migration-inhibiting effect: The products (1) to (3) of the present invention and the extremely hardened high-erucic rapeseed oil for comparison were added to the shortening and dissolved therein. Each solution thus obtained was slowly cooled from 50° C to 30° C at a rate of 0.1° C/min and then stored at 30° C for 48 hours. After the storage, the lower part, i.e., 10 mm from the bottom of a sheet of filter paper (30 mm × 45 mm) was inserted into the sample and kept as such for additional one hour at 30° C. Then the filter paper was taken out and the solid fat adhering thereto were wiped off. Subsequently the amount of the fats and oils, which had migrated to the filter paper and absorbed therein, was determined. Results of Evaluation: The results are shown in Table 3. Table 3 obviously indicates that the amounts of the control 1-1 containing no product of the present invention and the oleaginous composition containing the comparative product absorbed in the filter paper were comparable to that of the liquid oil (100% rapeseed oil) in spite of the presence of crystals, since the precipitated crystals grew into macrocrystals and caused solid/liquid separation in the former cases. On the other hand, the fat compositions containing the products (1) to (3) of the present invention were hardly absorbed in the filter paper, which suggests that the migration of the fats and oils was sufficiently inhibited in these cases. It has been further clarified that the migration-inhibiting effect could be enhanced with an increase in the content of the product of the present invention. Example 2 Biscuits were produced with the use of shortening containing the products (1) to (3) of the invention as evaluated in Example 1 and extremely hardened high-erucic rapeseed oil (for comparison) and the surface of each biscuit was observed. Composition of biscuit (sugar batter method): wheat flour 48% shortening 20% sugar 20% water 12%. Storage of biscuit and observation of the surface thereof: The biscuits baked in a conventional manner were taken out of an oven and allowed to cool at room temperature for one hour. Then they were sealed in a bag and stored at room temperature. After allowing the biscuits to stand at 5° C for one hour, the surface of each biscuit was observed with the naked eye. Results of evaluation: The results are shown in Table 4. Table 4 obviously indicates that biscuits containing the control 2-1, which had no saturated fatty acid residue having 20 or more carbon atoms, and those containing the comparison product, which contained a saturated fatty acid residue having 20 or more carbon atoms but was not in the form of a mixed triglyceride, showed whitening on the surface within two weeks. In contrast thereto, the surface of the biscuits containing the products of the present invention having a migration-inhibiting effect were maintained in an excellent condition for a prolonged period of time. It has been further clarified that the surface condition could be improved with an increase in the content of the product of the invention. Example 3 Composite baked cakes were produced by coating the biscuits baked in Example 2 with a chocolate and then stored in the same manner as the one described in Example 2. The surface of the chocolate coating of each composite baked cake was observed with the naked eye after storing the same for given periods, i.e., one week, two weeks, one month, two months and four months. Composition of chocolate: bitter chocolate 35% powdery sugar 51% cacao fat 13.6% lecithin 0.3% perfume 0.1%. Results of observation: The results are shown in Table 5. Table 5 indicates that the chocolate per se showed blooming, i.e., slightly whitening after storing the same for two months. This blooming was accelerated in the cases of the biscuits comprising shortening free from any disaturated-monounsaturated mixed triglycerides having saturated fatty acid residue(s) having 20 to 24 carbon atoms, i.e., the control 3-1 and the comparison product. In contrast thereto, this phenomenon was considerably inhibited in the biscuits containing the products (1) to (3) of the present invention. Example 4 Composite baked cakes were produced by coating the biscuits baked in Example 2 with a chocolate containing the product (3) of the present invention as prepared in Synthetic Example 3 in an amount of 5% based on the oleaginous ingredients. The obtained composite baked cakes were stored in the same manner as the one described in Example 3 and the surface of the chocolate coating of each product was observed. Composition of chocolate: Amount (%) Oleaginous material (%) bitter chocolate 35 (oil: 52%) 18.2 powdery sugar 51 - cacao fat 12 12.0 product (3) of invention 1.6 1.6 (5.03% in total oleaginous ingredients) lecithin 0.3 perfume 0.1 The results are shown in Table 6. The incorporation of the product (3) of the present invention was effective in inhibiting the blooming (whitening) of the chocolate per se. Therefore chocolate-coated biscuits maintaining excellent properties upon prolonged storage can be obtained by adding the fat for the present invention to the biscuits and the chocolate. Effects of the Invention: The migration inhibitor for fats and oils for baked cakes of the present invention shows specific crystallizing behaviors which are never observed in commonly known fats and oils. That is, when slowly cooled in a liquid oil, it does not show any growth of crystals but uniformly solidifies to thereby inhibit the migration of the liquid oil. Further the product of the present invention affects the crystallizing behaviors of other solid fats and imparts a migration-inhibiting effect thereto. Thus the product of the present invention can exert the migration-inhibiting effect in an amount as small as 0.5%, preferably 1% or more. These effects of the product of the present invention makes it available not only in inhibiting the whitening of the surface of a baked cake such as a biscuit or a cookie, but also in suppressing the influence of said baked cake on oleaginous products contacting therewith, e.g., chocolate chips dispersed therein or chocolate or cream coating thereof or inserted therein. Furthermore, the product of the present invention inhibits the blooming of a chocolate product per se. Therefore baked cakes such as biscuits and cookies, chocolate products and composite baked cakes containing the product of the present invention can maintain excellent properties upon prolonged storage.

Claims: A process for producing a composite baked food product which is obtained by embedding in chocolate or cream a baked food product comprising fats and oils as main ingredients, coating such a baked food product with chocolate or cream, or inserting or dispersing chocolate or cream in such a baked food product, characterized in that the fat(s) and oil(s) which form the oleaginous ingredients of the baked food product contain 0.5 to 100% by weight of a migration inhibitor for fats and oils of baked food products comprising a fat which contains 10% by weight or more of a disaturated-monounsaturated mixed triglyceride, in which at least one fatty acid residue among the three constituent fatty acids thereof is a saturated fatty acid having 20 to 24 carbon atoms. A baked food product produced by the process of claim 1.

Inventors: NAKANO AKIRA, NOMURA MASAKI, NAKANO, AKIRA, NOMURA, MASAKI
Applicants: KAO CORP, KAO CORPORATION
Application year: 1987
Main classification: A21D2
IPC codes: A23G1, A23G3, A23D9, A21D2