Process for preparing modified diene polymer rubbers

Abstract: A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitro compound, a phosphoryl chloride compound of the formula: wherein R¹ to R⁴ are independently an alkyl group, and an aminosilane compound of the formula: wherein R⁵ to R⁷ are independently an alkyl group or an alkoxyl group, R⁸ and R⁹ are independently an alkyl group, and n is an integer, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-­ based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent. The modified diene polymers can be incorporated with usual rubber additives to provide rubber compositions for various purposes, and the cured products show an increased impact resilience and a reduced hardness at low temperatures.

Description: The present invention relates to a process for preparing modified diene polymers having an improved impact resilience and a low hardness at low temperatures; more particularly it relates to a process for preparing modified elastomeric polymers of conjugated diene compounds by introducing particular atomic groups to conjugated diene polymers, as well as a rubber composition containing them. Conjugated diene polymers such as polybutadiene and a styrene-butadiene copolymer have hitherto been used as rubbers for automobile tire treads. In recent years, from the viewpoint of demands in low fuel cost for automobiles and in running safety on snow and ice roads, rubber compositions having a low rolling resistance and a large grip force on ice and snow roads have been desired as rubbers for automobile tire treads. The rolling resistance is correlative to the impact resilience of polymers. The rolling resistance is decreased with increasing the impact resilience. On the other hand, it is known that the grip force on snow and ice roads is correlative to the hardness at low temperatures, and that the smaller the hardness at low temperatures, the larger the grip force on snow and ice roads. However, known rubber compositions are not satisfactory in these properties for practical use. Conjugated diene polymers and processes for preparing them are already known from US-A-3 322 738 and FR-A-2 251 567. According to the known processes conjugated diene compounds are polymerized in the presence of alkali metal-based catalysts and modified by introducing a nitro compound (e.g. nitromethane or nitrobenzene) and a phosphoryl chloride compound, respectively, as a terminating agent. However, the rubbery polymers obtained therefrom are not satisfactory in regard to their impact resilience and hardness at low temperatures. This also applies to the diene polymers known from US-A-3 244 664 which contain at least one silicon-containing terminal group which can be coupled and/or cured to provide polymers having a high tensile strenghth and a relatively low heat bild-up on flexing which can be prepared by reacting a polymer having active alkali metal end groups with a silicic compound such as silicon tetrahalides, silanes or siloxanes. Therefore, it is an object of the present invention to provide a process for modifying a conjugated diene polymer to improve its impact resilience and to lower its hardness under an atmosphere of low temperatures, and to provide a conjugatid diene rubber composition containing this conjugated diene polymer and having an improved impact resilience and a low hardness at low temperatures. It has now been found that the above object can be achieved according to the present invention by reacting an alkali metal-containing diene polymer with a particular amino silane compound as a modifier to thereby introduce a particular atomic group into the diene polymer. According to a first aspect of the present invention there is provided a process for preparing a modified diene polymer which comprises reacting an alkali metal-containing conjugated diene polymer with an aminosilane compound of the general formula as a modifier: wherein R⁵, R⁶ and R⁷ are an alkyl group or an alkoxyl group, R⁸ and R⁹ are an alkyl group, and n is an integer, said alkali metal-containaing conjugated diene polymer being a living polymer having an alkali metal end prepared by a polymerization of a conjugated diene monomer or a mixture of a conjugated diene monomer and an aromatic vinyl monomer in a hydrocarbon solvent in the presence of an alkali metal-based catalyst, or a diene polymer to which an alkali metal is introduced by an addition reaction of a diene polymer having conjugated diene units in the polymer chain and an alkali metal-based catalyst in a hydrocarbon solvent. Preferred embodiments of the process of the present invention are described in subclaims 2 to 5. According to a second aspect of the present invention there is provided a rubber composition comprising a rubber component which contains at least 10% by weight of a modified diene polymer as defined above and rubber additives. The rubber composition of the present invention has an improved impact resilience and a low hardness at low temperatures. The term "alkali metal-containing conjugated diene polymer" as used herein means a diene polymer wherein an alkali metal is bonded to the diene polymer end or ends, obtained by polymerizing a conjugated diene monomer or a mixture of the diene monomer and other monomers copolymerizable with the diene monomer in the presence of an alkali metal-based catalyst; and a diene polymer obtained by addition of an alkali metal to a diene polymer having units of a conjugated diene in the polymer chain which has been previously prepared without being bound to the polymerisation method, for example, by a solution polymerization method or an emulsion polymerization method. The diene polymers used in the present invention include, for instance, homopolymers or copolymers of conjugated diene monomers such as 1,3-butadiene, isoprene, 1,3-pentadiene (piperylene), 2,3-dimethyl-1,3-butadiene, 1-phenyl-1,3-butadiene and 1,3-hexadiene, and copolymers of the conjugated diene monomers and other monomers copolymerizable therewith, e.g. aromatic vinyl compounds such as styrene, m- or p-methylstyrene, p-t-butylstyrene, α-methylstyrene, vinyltoluene, vinylnaphthalene, divinylbenzene, trivinylbenzene and divinylnaphthalene; usaturated nitrile compounds such as acrylonitrile; acrylic acid esters and methacrylic acid esters; and vinylpyridine. Representative examples of the diene polymers are, for instance, polybutadiene rubber, polyisoprene rubber, butadiene-isoprene copolymer and butadiene-styrene copolymer. The diene polymer wherein an alkali metal is bonded to the diene polymer end or ends is, as mentioned above, that obtained by a polymerization using an alkali metal-based catalyst, and is a living polymer having an alkali metal on at least one end of the polymer chain in the stage prior to terminating the polymerization. For instance, the living diene polymer can be prepared by a known living anionic polymerization method wherein monomer or monomers are polymerized in the presence of an alkali metal-based catalyst such as an organolithium initiator in a hydrocarbon solvent. Generally used chemicals such as alkali metal-based catalysts, polymerization solvents, randomizers and controlling agents for the microstructure of conjugated diene units can be used in the preparation of the living diene polymers. The polymerization manner is not particularly limited. The alkali metal addition diene polymer is prepared from diene polymers obtained by polymerizing the conjugated diene monomer or a mixture thereof with other copolymerizable monomers in a usual polymerization manner, e.g. a solution polymerization using an alkali metal-based catalyst, an alkaline earth metal-based catalyst or a Ziegler catalyst, or an emulsion polymerisation using a redox catalyst. Representative examples of the starting diene polymers are, for instance, polybutadiene rubber, polyisoprene rubber, butadiene-styrene copolymer rubber, butadiene-isoprene copolymer rubber, polypentadiene rubber, butadiene-piperylene copolymer rubber, and butadiene-propylene alternate copolymer. An alkali metal is introduced into the diene polymers by an addition reaction of the diene polymers and alkali metal-based catalysts. The addition of the alkali metal to the diene polymers is carried out by usually adopted methods. For instance, the diene polymer is reacted with a usual alkali metal-based catalyst in a hydrocarbon solvent in the presence of a polar compound such as an ether compound, an amine compound or a phosphine compound at a temperature of 30° to 100°C for 10 min to 10 h , especially 10 min to 60 h. The amount of the alkali metal-based catalyst is usually from 0.1 to 10 mmol per 100 g of the diene polymer. When the amount is less than 0.1 mmol, the impact resilience is not improved. When the amount is more than 10 mmol, a side reaction such as crosslinking or severance of the polymer occurs, thus resulting in no contribution to improvement of impact resilience. The amount of the polar solvent is usually from 0.1 to 10 mol, preferably from 0.5 to 2 mol, per mol of the alkali metal-based catalyst. The alkali metal-based catalyst used in the living polymerization and the addition reaction includes, for instance, lithium, sodium, potassium, rubidium and cesium metals, hydrocarbon compounds of these metals, and complexes of these metals with polar compounds. Lithium or sodium compounds having 2 to 20 carbon atoms are preferable as the catalyst. Representative examples thereof are, for instance, ethyllithium, n-propyllithium, iso-propyllithium, n-butyllithium, sec-butyllithium, t-octyllithium, n-decyllithium, phenyllithium, 2-naphthyllithium, 2-butylphenyllithium, 4-phenyl-butyllithium, cyclohexyllithium, 4-cyclopentyllithium, 1,4-dilithio-butene-2, sodium naphthalene, sodium biphenyl, potassium-tetrahydrofuran complex, potassium diethoxyethane complex, and sodium salt of α-methylstyrene tetramer. The catalysts may be used alone or as an admixture thereof. The polymerization reaction and the alkali metal addition reaction for preparing the alkali metal-containing conjugated diene polymers are carried out in a hydrocarbon solvent, or in a solvent which does not destroy the alkali metal-based catalysts, e.g. tetrahydrofuran, tetrahydropyran or dioxane. The hydrocarbon solvent is suitably selected from aliphatic hydrocarbons, aromatic hydrocarbons and alicyclic hydrocarbons. Hydrocarbons having 2 to 12 carbon atoms are particularly preferred as the solvent. Preferable examples of the solvent are, for instance, propane, n-butane, iso-butane, n-pentane, iso-pentane, n-hexane, cyclohexane, propene, 1-butene, iso-butene, trans-2-butene, cis-2-butene, 1-pentene, 2-pentene, 1-hexene, 2-hexene, benzene, toluene, xylene, and ethylbenzene. The solvents may be used alone or as an admixture thereof. The alkali metal-containing diene polymer prepared by the living polymerization or the addition reaction is reacted with an aminosilane compound of the following general formula as a modifier: wherein R⁵, R⁶ and R⁷ are an alkyl group or an alkoxyl group, R⁸ and R⁹ are an alkyl group, and n is an integer. In the aminosilane compound of the above general formula the alkyl or alkoxyl groups R⁵ to R⁷ are usually those having 1 to 20 carbon atoms, and the alkyl groups R⁸ and R⁹ are usually those having 1 to 20 carbon atoms. The integer n is usually from 1 to 20. Representative examples of the aminosilane compound are, for instance, 3-dimethylaminomethyl-trimethoxysilane, 3-dimethylaminoethyltrimethoxysilane, 3-dimethylaminopropyltrimethoxysilane, 3-dimethylamino-butyltrimethoxysilane, 3-dimethylaminomethyldimethoxy-methylsilane, 3-dimethylaminoethyldimethoxymethylsilane, 3-dimethylaminopropyldimethoxymethylsilane, 3-dimethyl-aminobutyldimethoxymethylsilane, 3-dimethylaminomethyl-triethoxysilane, 3-dimethylaminoethyltriethoxysilane, 3-dimethylaminopropyltriethoxysilane, 3-dimethylaminopropyltriethoxysilane, 3-dimethylaminomethyldiethoxymethylsilane, 3-dimethylaminoethyldiethoxymethylsilane, 3-dimethylaminopropyldiethoxymethylsilane and 3-dimethylaminobutyldiethoxymethylsilane, 3-dimethylaminopropyl-diethoxymethylsilane is particularly preferable. The aminosilane compound modifiers may be used alone or as an admixture thereof. The amount of the modifier is usually from 0.05 to 10 moles, preferably 0.2 to 2 moles, per mole of the alkali metal-based catalyst used in the living polymerization or alkali metal addition reaction for the production of the alkali metal-containing diene polymers. The reaction between the modifier and the alkali metal-containing diene polymer proceeds rapidly. Accordingly, the reaction temperature and the reaction time can be selected from the wide ranges. In general, the reaction is effected at a temperature of from room temperature to 100°C for several seconds to several hours (about 3 s to about 6 h). Contacting the alkali metal-containing diene polymer with the modifier is sufficient for the reaction. Usually, the alkali metal-containing diene polymer dissolved in a solvent is mixed with the modifier. For instance, the modification of diene polymers is conducted by a process wherein monomer or monomers are polymerized in a hydrocarbon solvent using an alkali metal-based catalyst, and to the resulting polymer solution is added a prescribed amount of the modifier; or a process wherein a diene polymer solution is subjected to the alkali metal addition reaction, and after the completion of the addition reaction, the modifier is subsequently added to the reaction mixture and the reaction is effected. However, the process for reacting the polymer with the modifier is not limited to these processes. Thus, the aminosilane compounds are introduced into the polymer chain end or into the polymer chain. After the completion of the reaction, the modified diene polymer is coagulated from the reaction mixture (solution) by known methods as applied in the preparation of rubbers by a usual solution polymerization, for example, by an addition of a coagulant to the reaction mixture or by a steam coagulation. The coagulation temperature is not particularly limited. The drying of the polymer crumbs separated from the reaction system can also be effected by usual methods as used in the preparation of usual synthetic rubbers, for example, by a hand dryer or a dryer of extrusion type. The drying temperature is not particularly limited. The modified conjugated diene polymers prepared according to the present invention are improved in impact resilience and hardness at low temperatures as compared with nonmodified diene polymers and differently modified diene polymers. Accordingly, the modified diene polymers are particularly suitable for use in automobile tires. Further, they can also be used as raw material rubbers for various industrial purposes such as boot and shoe bottom, floor material and vibration-proof rubber. The modified diene polymers can be incorporated with usual rubber additives to provide a rubber composition and cured in a usual manner to provide cured products. The modified diene polymer prepared according to the present invention may be used alone or in combination with other known rubbers. Examples of the other rubbers are, for instance, emulsions-polymerized styrene-butadiene copolymer, rubbers prepared by solution polymerization using an anionic polymerization catalyst, and a Ziegler catalyst, e.g. polybutadiene rubber, styrene-butadiene copolymer rubber, polyisoprene rubber and butadiene-isoprene copolymer rubber, and natural rubber. One or more of these rubbers are selected according to the purposes. It is necessary that the rubber component contains at least 10 % by weight, preferably at least 20 % by weight, of the modified diene polymer. When the amount of the modified diene polymer is less than 10 % by weight, the improvement in the impact resilience cannot be expected. The Mooney viscosity (ML₁+₄100°C) of the modified diene polymer is usually from 10 to 200, preferably from 20 to 150. When the Mooney viscosity is less than 10, the mechanical properties such as tensile strength are poor. When the Mooney viscosity is more than 200, the processability or workability is lowered since the compatibility with other rubbers is poor, and consequently the mechanical properties of the cured rubbers are lowered. All or a part of the rubber component may be used as an oil extended rubber. The rubber composition of the present invention is prepared by mixing the rubber component with various additives using a mixing machine such as a roll mill or a Banbury mixer. The additives used are not particularly limited, and are selected from additives usually used in the rubber industry, e.g. a curing system using sulfur, stearic acid, zinc oxide, a curing accelerator such as thiazole accelerator, thiuram accelerator or sulfenamide accelerator, and/or an organic peroxide; a reinforcing agent such as HAF carbon black, ISAF carbon black or other various grades of carbon blacks, or silica; a filler such as calcium carbonate or talc; and other additives such as process oil, processing assistant and antioxidant. The kinds and amounts of the rubber additives to be used are selected according to the purposes of the rubber composition, and are not particularly limited in the present invention. The present invention is more spcifically described and explained by means of the followingExamples in which all percents and parts are by weight unless otherwise noted. Example 1 A 10 liter stainless steel polymerization vessel was washed, dried and replaced with nitrogen, and it was charged with 1,000 g of 1,3-butadiene, 4,300 g of n-hexane, 40 millimoles of ethylene glycol diethyl ether and 6.0 millimoles of n-butyllithium dissolved in n-hexane. The polymerisation was carried out at 50°C for 1 hour with stirring. After the completion of the polymerization, 4.1 millimoles of 3-dimethylaminopropyldiethoxymethylsilane was added to the reaction mixture. After conducting the reaction for 30 minutes with stirring, 10 ml of methanol was added and the reaction mixture was further stirred for 5 minutes. The reaction mixture was then taken out from the polymerization vessel. To the reaction mixture was added 5 g of 2,6-di-t-butyl-p-cresol (Sumilizer® BHT), and a large portion of n-hexane was evaporated followed by drying under reduced pressure at 60°C for 24 hours. The produced polymer had a Mooney viscosity of 85 and a vinyl content of 70 %. Comparative Example 1 The procedure of Example 1 was repeated except that 3-dimethylaminopropyldiethoxymethylsilane was not used. The produced polymer had a Mooney viscosity of 85 and a vinyl content of 70 %. Example 2 A 10 liter stainless steel polymerization vessel was washed, dried and replaced with nitrogen, and it was charged with 1,000 g of 1,3-butadiene, 4,300 g of n-hexane, 40 millimoles of ethylene glycol diethyl ether and 4.4 millimoles of n-butyllithium dissolved in n-hexane. The polymerization was carried out at 50°C for 1 hour with stirring. After the completion of the polymerization, 4.4 millimoles of 3-dimethylaminopropyldiethoxymethylsilane was added to the reaction mixture. After conducting the reaction for 30 minutes with stirring, 10 ml of methanol was added and the reaction mixture was further stirred for 5 minutes. The reaction mixture was then taken out from the polymerization vessel. To the reaction mixture was added 5 g of 2,6-di-t-butyl-p-cresol (Sumilizer® BHT), and a large portion of n-hexane was evaporated followed by drying under reduced pressure at 60°C for 24 hours. The produced polymer had a Mooney viscosity of 85, a styrene content of 25 % and a vinyl content of 40 %. Comparative Example 2 The procedure of Example 2 was repeated except that 3-dimethylaminopropyldiethoxymethylsilane was not used. The produced polymer had a Mooney viscosity of 85, a styrene content of 25 % and a vinyl content of 40 %. Example 3 and Comparative Example 3 A 10 liter stainless steel polymerization vessel washed and dried was charged with 500 g of a styrene-butadiene copolymer (Mooney viscosity 51, styrene content 25 %, vinyl content 40 %) and 4,300 g of n-hexane, and the copolymer was dissolved with stirring. To the vessel were added 6.4 millimoles of n-butyllithium dissolved in n-hexane and 6.4 millimoles of tetramethyl-ethylenediamine, and the reaction was carried out at 70°C for 1 hour. To the vessel was then added 6.4 millimoles of 3-dimethylaminopropyldiethoxymethylsilane, and the reaction was carried out for 30 minutes with stirring. After adding 10 ml of methanol to the vessel, the mixture was further stirred for 5 minutes. The reaction mixture was then taken out from the vessel. To the reaction mixture was added 5 g of 2,6-di-t-butyl-p-cresol (Sumilizer® BHT), and a large portion of n-hexane was evaporated followed by drying under reduced pressure at 60°C for 24 hours. The obtained polymer had a Mooney viscosity of 51. Also, the nonmodified copolymer, namely the styrene-butadiene copolymer (Mooney viscosity 51, styrene content 25 %, vinyl content 40 %), was used in the following measurement of physical properties (Comparative Example 3). Using the polymers obtained in Examples 1 to 3 and Comparative Examples 1 to 3, the preparation of compounded rubbers, curing thereof and measurement of physical properties of the cured products were made as follows. Preparation of compounded rubber and physical properties of cured rubber A compounded rubber was prepared by mixing each of the polymers obtained in Examples 1 to 3 and Comparative Examples 1 to 3 with rubber additives on mixing rolls according to the recipe shown in Table 1. It was then press-cured at 160°C for 30 minutes. The impact resilience (rebound resilience) of the cured rubber was measured at 60°C using a Lüpke resilience tester. The hardness (JIS A hardness) of the cured rubber was measured at -20°C according to JIS K 6301. The results are shown in Table 1. From the results shown in Table 1 it is understood that the polymers prepared according to the present invention have a vey high impact resilience and a very low hardness at low temperatures as compared with the polymers prepared in the same manner except for no use of the modifier and the polymers having the same Mooney viscosity but prepared without using the modifier. In addition to the ingredients used in the Examples, other ingredients can be used in the Examples as set forth in the specification to obtain substantially the same results.

Claims: A process for preparing a modified diene polymer which comprises reacting an alkali metal-containing conjugated diene polymer with an aminosilane compound of the formula: wherein R⁵, R⁶ and R⁷ are an alkyl group or an alkoxyl group, R⁸ and R⁹ are an alkyl group, and n is an integer, said alkali metal-containing conjugated diene polymer being a living polymer having an alkali metal end prepared by a polymerization of a conjugated diene monomer or a mixture of a conjugated diene monomer and an aromatic vinyl monomer in a hydrocarbon solvent in the presence of an alkali metal-based catalyst, or a polymer to which an alkali metal is introduced by an addition reaction of a diene polymer having conjugated diene units in the polymer chain and an alkali metal-based catalyst in a hydrocarbon solvent. The process of Claim 1, wherein said modifier is used in an amount of 0.05 to 10 moles per mole of said alkali metal-based catalyst used in the preparation of said alkali metal-containing conjugated diene polymer. The process of Claim 1 or 2, wherein said alkali metal-based catalyst is a member selected from the group consisting of an alkali metal, an alkali metal hydrocarbon compound and a complex of an alkali metal with a polar compound. The process of Claims 1-3, wherein said alkali metal-containing conjugated diene polymer is in the form of a solution in a hydrocarbon solvent. The process of Claims 1-4, wherein the reaction of the alkali metal-containing conjugated diene polymer and the modifier is carried out at a temperature of from room temperature to 100°C. A rubber composition comprising a rubber component containing at least 10 % by weight of a modified diene polymer prepared according to the process of claim 1 and rubber additives, said modified diene polymer being a conjugated diene polymer modified by reacting an alkali metal-containing conjugated diene polymer selected from the group consisting of a conjugated diene polymer having an active metal end and an alkali metal addition product of a conjugated diene polymer with an aminosilane compound of the formula: wherein R⁵, R⁶ and R⁷ are an alkyl group or an alkoxyl group, R⁸ and R⁹ are an alkyl group, and n is an integer.

Inventors: IMAI AKIO, SEKI TOMOAKI, TAKAO HIROYOSHI, TSUJI MITSUJI, IMAI, AKIO, SEKI, TOMOAKI, TAKAO, HIROYOSHI, TSUJI, MITSUJI
Applicants: SUMITOMO CHEMICAL CO, SUMITOMO CHEMICAL COMPANY, LIMITED
Application year: 1987
Main classification: C08C19
IPC codes: C08C19