DIRECTLY HEATED ROLLER FOR FUSE-FIXING TONER IMAGES

Abstract: The roller has a roller body (1) having a small heat capacity, a bonding layer (2) formed substantially uniformly on the outer peripheral surface of the roller body (1), a lower insulating layer (3) provided on the bonding layer (2); a heat generating layer (4) provided on the lower insulating layer (3) and having a ceramic materix and a metallic resis­ tance layer constituted by a metal dispersed in the ceramic matrix, the metallic resistance layer extending substantially continuously in the lengthwise direction of the roller, the heat generating layer (4) having substantially the same thermal expansion coefficient as the lower insulating layer (3), an upper insulating layer (5) provided on the heat gene­ rating layer (4), a protective layer (6) formed on the upper insulating layer (5) so as to prevent offset of the toner images, and an electrode layer (7) formed on each end of the roller and adapted to connect the heat generating layer (4) to an external power source.

Description: FIELD OF THE INVENTION This invention relates to fixing device for fixing toner images to paper or sheet in electrophotographic copiers and printers, particularly to improvement of heat fuse fixing roller (hereinafter referred to as heated roller). BACKGROUND OF THE INVENTION Electrophotographic copiers and printers make use of toners for developing electrostatic latent images. The developed images are fixed on sheets or the like members to form permanent visual images. Broadly, there are two types of method for fixing the developed images: namely, a method called "heat fuse-fixing" in which resin particles in the toner are heated and fused on the sheet, and a method called "pressure fuse-fixing" in which resin particles are fused by application of pressure. On the other hand, a device which is referred to as "heat roller fixing device" has been broadly used because of its superior characteristics, namely, stable fixing performance over a wide speed range of the developing machine, high thermal efficiency and safety. This device has a heated roller which is heated by a tungsten halogen lamp provided inside the roller. This constitution undesirably requires a large electric power consumption and long warming-up time. In addition, the roller temperature is lowered when many sheets are treated successively, because the heating output cannot well compensate for the temperature drop of the roller. Thus, shorter warm-up time, reduced electric power consumption and smaller temperature drop are important requisites for the heat roller. More practically, the warm-up time is preferably 30 seconds, more preferably 20 seconds or shorter, while the electric power consumption is preferably less than 1 kW, more preferably about 700 W or smaller. It is also preferred that the roller temperature is stably maintained at around 200°C. Another important requisite for the heat roller is that the roller exhibits a uniform temperature distribution over its entire surface. Generally, the heated roller tends to exhibit higher temperature at its mid portion than at its both axial ends. This tendency is increased particularly when the resistance film has a positive temperature coefficient, i.e., such a characteristic that the electric resistance is increased in accordance with a temperature rise. Namely, in such a case, the portion of the resistance film on the mid portion of the roller exhibits a greater resistance than the film portions on both axial ends of the roller, so that the electric current which flows from one to the other axial ends encounters a greater resistance at the mid portion of the roller, so that greater heat is generated at this portion of the roller thereby causing a further temperature at the mid portion of the roller. In order to attain a uniform temperature rise, therefore, it is preferred that the resistance film does not have large positive temperature coefficient. The resistance film could have a negative temperature coefficient, that is, such a characteristic that electric resistance decreases as temperature rises. In such a case, the heat generation is smaller at the mid portion of the roller than at both axial end portions of the same, contributing to the uniform temperature distribution along the axis of the roller. However, when the roller temperature is still low, the resistance film exhibits a very large electric resistance such as to restrict the flow of the electric current, so that an impractically long time is required for heating up the roller. Thus, the use of a resistance film having a negative temperature coefficient does not meet the demand for shortening of the warm-up time. The control of the temperature of the resistance film is conducted by a control circuit which judges the film temperature by sensing the electric current, and varying the electric current in accordance with the measured temperature so as to maintain a constant film temperature. The resistance film having a negative temperature coefficient reduces its resistance when the temperature becomes high. If the electric resistance of a circuit for supplying the electric power is increased due to an unexpected reason such as an insufficient contact of terminals or contacts in the circuit, the temperature control circuit erroneously judges that the resistance film temperature has come down and operates to supply greater electric current to the resistance film. From the view point of stability of the temperature control, therefore, it is preferred that the resistance film has a positive temperature coefficient. And when the temperature increases unnormally by an accident of relay short, the resistance film of negative temperature coefficient is rapidly heated since electric power increases on over-heating. Also, constant load is desired and it is preferred that the resistance value of the resistance film is as constant as possible. EP-A-0 147 170 discloses a directly heated roller for fuse-fixing toner images in accordance with the first part of claim 1. SUMMARY OF THE INVENTION It is an object of the invention to provide a directly heated roller for fume-fixing toner images which has a high durability and a uniform temperature distribution. This object is met by the roller characterised in claim 1. The upper insulating layer disposed between the heat generating layer and the outer protective layer not only provides good insulation even if the protective layer is damaged by hard objects entering the nip of the fixing device but also compensates for non-uniformity of heat generation caused by partial non-uniformities in the heat generating layer. In addition, the ceramic upper insulating layer prevents the heat generating layer from being destroyed by the resin protective layer. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a vertical sectional view of a directly heated roller; Fig. 2 is an enlarged view of an essential portion of the directly heated roller shown in Fig. 1; Figs. 3(a) and (b) are microphotographs of the structure of a heat generating resistance film incoroporated in the directly heated roller in accordance with the invention (X-X section and Y-Y section respectively); Fig. 4 is a microphotograph of the structure of a reference heat generating resistance film; Fig. 5 is a graph showing the relationship between the warm-up time and the thickness of the roller body; Fig. 6 is a graph showing the relationship between the warm-up time and the insulating layer; Fig. 7 is a heat cycle chart showing heat cycles employed in a heat cycle test; and Fig. 8 is a chart illustrating the film thickness distribution and the temperature distribution on the directly heated roller in accordance with the invention. DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring to Figs. 1 and 2, a bonding layer 2 is deposited substantially uniformly onto the outer peripheral surface of the roller portion of a cylindrical roller body 1. A lower insulating layer 3 is deposited on the bonding layer 2, and a heat generating layer 4 is formed on the lower insulating layer 3. An upper insulating layer 5 is formed on the heat generating resistance layer 4. Finally, a protective layer 6 is provided on the upper insulating layer 5. An electrode layer 7 is formed on the portion of the heat generating resistance layer 4 on each end portion of the roller 1. Thus, electricity is supplied to the heat generating resistance layer through the electrode layers 7 provided on both axial end portions of the roller body 1. The directly heated roller having the described construction, when incorporated in a copier or a similar machine, is journaled at its both ends by bearings for rotation. The directly heated roller is arranged to oppose a rubber roller such as to form therebetween a nip through which a sheet carrying a toner image is passed so that the toner images are fixed. Preferably, the heat generating resistance layer 4 is formed from a material having a composition containing l0 to 35 wt% of an Ni-Cr alloy and the balance substantially a ceramic material. The heat generating resistance layer 4 is produced from the above-mentioned material by arc-plasma spraying, such that the Cr-Ni alloy is dispersed so as to form in the ceramic material a metallic phase extending preferably in axial direction of the roller. When the Ni-Cr alloy content is below l0 wt%, the alloy is dispersed discontinuously, so that the metallic phase extending preferably in axial direction of the roller cannot be formed, with a result that the heat generating resistance layer exhibits a very large resistance. In addition, cracks are apt to be caused around the discontinuities of the heat generating resistance layer, as the roller is subjected to repeated thermal shocks during operation. On the other hand, when the Ni-Cr alloy content exceeds 35 wt%, the specific resistance of the heat generating layer is as low as 10⁻³ ohm-cm at the greatest, so that the layer 4 cannot materially serve as heat generating layer. In addition, the thermal expansion coefficient of the layer is increased to a level of 10 × 10⁻⁶/deg. which is too large as compared with that of the heat insulating layers sandwiching the heat generating resistance layer. Any Ni-Cr alloy ordinarily used as a heat-generating conductive means can be used as the Ni-Cr alloy in the heat generating resistance layer 4. However, in order to obtain a directly heated roller having a very short warm-up time, it is preferred that the Ni-Cr alloy contains 5 to 20 wt% of Cr and the balance substantially Ni, although some other additives in heat generating resistance layer and incidental elements are not excluded. The ceramic matrix of the heat generating resistance layer is preferably formed from Al₂O₃. It has been confirmed that when Al₂O₃ is used as the ceramic matrix, the Ni-Cr alloy can be well dispersed in the matrix in such a manner as to form a continuous lengthwise layer. Mixtures of Ni-Cr alloys and A1₂O₃ were molten and deposited on rollers to form respective layers of 100 µm by arc-plasma spraying method employing a gas such as Ar, H₂ or N₂. Figs. 3 and 4 show, respectively, the microphotos of structures of the layers having Ni-Cr alloy content of 20 wt% and 8 wt%, respectively. Fig. 3(a) and (b) are microphotographs of the structure of a heat generating resistance film (X-X section and Y-Y section of Fig. 1, respectively). From Fig. 3, it will be seen that, when the Ni-Cr alloy content is 20 wt%, preferably lengthwise extending phase layers (shown in white color) of Ni-Cr alloy are formed and dispersed in the ceramic matrix. The layers of Ni-Cr alloy electronically connect each other in the axial direction of the roller and form electrically continuous layers. Since the Ni-Cr alloy phase extends preferably in the axial direction within the ceramic matrix, the alloy permits the heat generating resistance layer to withstand repeated thermal shock and affords an adequate specific resistance which ranges between about 10⁻¹ and 10⁻² ohm-cm. On the other hand, the structure shown in Fig. 4 having Ni-Cr alloy content of 8 wt% is not a Ni-Cr alloy layer extending preferably in the axial direction, resulting in a large electric resistance and reduced durability against repeated thermal shocks. Such a heating material comprising 8 wt% Ni-Cr alloy is described in EP-A-0147170 as the only detailed example. Since the heat generating resistance layer 2 has a thermal expansion coefficient α of 6 × 10⁻⁶ to 10 × 10⁻⁶/deg., it is preferred that the insulating layers sandwiching this heat generating resistance layer have a thermal expansion coefficient of not smaller than 6 × 10⁻⁶/deg. Materials of insulating layer practically usable are: Al₂O₃, MgO, ZrO₂, MgAl₂O₄ (spinel), ZrO₂SiO₂, MnO.NiO, etc. Among these materials, the spinel MgAl₂O₄ is preferred because of high temperature preservation effect which in turn contributes to the shortening of the warm-up time of the roller. The lower insulating layer 3 electrically insulates the heat generating layer 4 from the roller body 1 and prevents transfer of heat from the resistance layer to the roller body. A too large thickness of the lower insulating layer 2 will result in a long warm-up time of the heated roller because of long time required for heating the lower insulating layer, while a too small thickness cannot provide sufficient electric insulation. For simultaneously satisfying both demands for shorter heating-up time and higher insulation, the thickness of the lower insulating layer preferably ranges between 200 and 500 µm, and most preferably about 300 µm. The upper insulating layer 5 serves to uniformize the temperature distribution which otherwise does not become uniform due to the uniformity of heat generation caused by the partial ununiformity of heat generating resistor, and serves also to ensure sufficient electric insulation of the roller surface. The layer 5 may protect the resistance layer 4 when other material comes in the nip of the fixing device. The upper insulating layer also prolongs the warm-up time when its thickness is too large, while impairs the electric insulation when its thickness is too small. The preferred range of thickness of the upper insulating layer 5 is 30 to 200 µm, more preferably about 100 µm. The roller body was usually made of a high-strength aluminum alloy (5056), in order to meet a demand for high formability, as well as uniform and quick heating characteristics. The directly heated roller of the invention, however, has a body 1 which has a small heat capacity. Preferably, the material of the roller body 1 has a thermal expansion coefficient which approximates that of the ceramic. From this point of view, the roller body 1 of the roller in accordance with the invention is made of iron or an iron alloy. As is well known, soft iron exhibits a thermal expansion coefficient value of 10 × 10⁻⁶/deg. which is the smallest among those of metals. To shorten the warm-up time, it is preferred to reduce the thickness of the roller body. In the case of conventional halogen lamp device using aluminum pipe, it is difficult to reduce the thickness of the aluminum pipe because it cannot stand bending stress caused fixing pressure because bending strength of aluminum pipe(5056) is less than 1/2 of soft iron at 200°C. Thinning the thickness of the heating roller will be explained, assuming the following heat analytical model for temperature rising process of heating roller: Hc: average heat capacity of heating roller delta-Hs: average heat leakage from surface delta Hcon: average heat leakage by heat conduction Hc is needed for calculating necessary heat value heating a heated roller to 200°C. Hc can be separated to heat capacity of metal portions (roller body and bonding film) and heat capacity of ceramic portions including heat generating layer. These are referred to as Hcm and Hcc, respectively. Delta-Hs includes heat-leakage from surface by convention and radiation. Since these change according to temperature, average value is used as delta-Hs. Similarly, delta-Hcon is average value. Delta-Hcon means leakage to other machine parts through journals. Total heat necessary until warm-up is shown by equations: Q=200Hc + delta-Hs·t + deℓta-Hcon·t----(l) t: heating time until warm-up when supply heat per unit time is W, Q=W·t------------------------------(2) From equations (1) and (2), warm-up time t becomes t=200Hc/(W-delta-Hs - delta-Hcon)------(3) Delta-Hs and delta-Hcon slightly change according to time t but they can be negligible. To shorten warm-up time t, it is apparent that heat capacity is made small or that heat leakage is made small. The reduction of heat capacity can be accomplished by thinning each layer and thickness of roller body or by changing materials. Materials change has some difficulty but thinning the thickness is easier. With respect to heat leakage, convection and radiation from surface cannot be prevented. Leakage to journals can be prevented by using bearings having low thermal conductivity or reducing cross section of the journals. Using roller body with low thermal conductibity may reduce the leakage. From this point of view, steel or soft iron is preferable to aluminum alloy as roller body, since steel or soft iron has lower conductivity and is workable to thin thickness. It is also possible to form the roller body 1 in a cylindrical form which has a small thickness of 2 mm or less, preferably 1 mm or less, so as to reduce the heat capacity. The bonding film 2 bonds the lower insulating layer 3 to the surface of the roller body 1. Ni-Cr-Mo alloy, Ni-Al alloy, Ni-Cr alloy or the like is suitably used as the material of the bonding surface. When such a material is plasma-sprayed on the surface of the roller body 1, it generates heat by itself and is partially oxidized to form an oxide which effectively enhances the strength of bonding with the ceramic. Amongst these materials of the bonding film, powdered Ni coated on the surface thereof with Aℓ and Mo is used most preferably. The protective layer 6 coats the surface of the upper insulating layer 5, in order to improve the anti-offset characteristics of the toner images and also for the purpose of insulating the surface of the roller. Preferably, the protective layer 6 is formed from a PEA (tetrafluoroethyleneperfluoroalkylvinyl ether copolymer resin) at a thickness of 30 µm. Experiment l Three pieces of cylindrical roller bodies (300 mm long and 35 mm of outer diameter) of soft iron, having thicknesses of 0.6 mm, l.0 mm and l.5 mm respectively, were prepared. On the surface of each roller body were formed by a plasma spraying process an Ni-4%Aℓ-2%Mo alloy bonding layer of 25 µm thick, a lower MagAl₂O₄ insulating layer of 300 µm thick, a heat generating resistance film of 70 µm made of a mixture of an Ni-Cr alloy (80 wt%Ni-20 wt%Cr) and Al₂O₃ (alloy content 20 wt%), and an MgAl₂O₃ upper insulating layer of 100 µm thick in turn. After securing the electrodes to both ends of the heat generating resistance film, a PFA protective layer was formed on the upper insulating layer, thus completing the directly heated roller. A plasma spray apparatus used in this experiment comprised a gun body having a central path for flowing an operation gas, e.g. argon. A part of the path was enclosed by an anode, and a rod-type cathode was mounted in the path. A path for supplying powder mixtures to be sprayed was open to the central path near a nozzle opening. While the argon was flowing through the central path of the gun, plasma arc was provided between the anode and the cathode. The electrical voltage applied was 50 to l00V. The arc turned the argon into a high-temperature plasma jet which was more than 5000°C. Powders to be sprayed were supplied through the side path into the plasma formed in the central path. The roller was rotating to form uniform deposited layer on it while the roller was placed at the distance of l0 cm from the plasma jet. When the Ni-Aℓ-Mo alloy plasma-sprayed layer was deposited, the spraying condition was as follows: Arc current: 500 A Arc voltage: 70V DC Powder Supply Rate: 25 ℓb/hr When the insulating MgA ₂0₄ layer was deposited, the spraying condition was as follows: Arc current: 500 A Arc voltage: 80V DC Powder Supplying Rate: 6 ℓb/hr When the heat generating resistance film was deposited, the spraying condition was as follows: Arc current: 500 A Arc voltage: 80V DC Powder Spraying Rate: 6 ℓb/hr Electric current was supplied to each roller that it produces a power of 900 Watts, and the period of time required for heating the roller surface up to 200°C was measured as the warm-up time. As will be seen from Fig. 5, the warm-up time was 40 seconds for a roller having roller body thickness of l.5 mm, and 30 seconds and 22 seconds, respectively, when the roller body thickness was 1.0 mm and 0.6 mm. It will be seen that the directly heated roller of the invention has a very short warm-up time. In comparison with halogen lamp fixing device with aluminum pipe, roller body thickness of less than 2 mm results of shorter warm-up time. Thickness of less than 1 mm drastically shortens the warm-up time. But, thickness of less than 0.4 mm cannot stand fixing pressure and is difficult to produce. Experiment 2 Directly heated rollers were prepared in the same way as Experiment 1, with the thickness of the lower insulating layer varied as 100 µm, 300 µm and 500 µm. Electric current was supplied to the rollers such that it produces power of 900 Watts and the period of time required for heating the roller surfaces up to 200°C was measured as the warm-up time. As will be seen from Fig. 6 which shows the result of the measurement, the warm-up time is shortened as the roller body thickness is reduced and as the insulating layer thickness is reduced. But, 100 µm shows poor electric insulating and more than 500 µm causes long warm-up time. Experiment 3 The directly heated roller having the roller body thickness of 0.6 mm employed in Experiment 1 was subjected to a repetitional heat cycle test. In this test, the heating roller was held in contact with a rubber roller of a diameter substantially the same as that of the heating roller, while being rotated at a peripheral speed of 200 mm/sec. The heat cycle test was conducted by applying the roller to repetitional heat cycles as shown in Fig. 7. The heat roller in accordance with the invention showed no breakdown of the resistance layer and no deterioration in the electric characteristics, even after continuous 2600 heat cycles. Experiment 4 A continuous heat-rotation test was carried out by using a fixing unit of the same type as that used in Experiment 3. Neither breakdown of the resistance layer nor deterioration in the electric characteristics were observed after 650-hour operation at the maximum temperature of 220°C, thus proving the superiority of the heated roller of the invention. In the case of a copier which fixes images on l2 sheets of A-4 size paper per minute, it takes about 200 hours for fixing images on l50,000 sheets which is the number guaranteed. It will be seen that the heated roller of the invention can withstand the use for a long period of time which is about 3 times as long as the guaranteed period. Experiment 5 There were prepared cylindrical roller bodies made of soft iron and having a length of 240 mm, an outer diameter of 35 mm, and a thickness of 0.6 mm. On the surface of the cylindrical bodies were plasma-sprayed a bonding film of Ni-Al-Mo alloy having a thickness of 25 µm, a lower insulating layer of MgA1₂0₃ having a thickness of 300 µm, and an exothermic resistance film of about 70 µm in thickness including Ni-A1 alloy of 20% and the balance Al₂O₃, in turn. However, in the roller (A) the resistance film is made to have a thickness of 65-70 µm which film is made to have a substantially uniform thickness in the range from the end of the roller to the center thereof, while in a roller B the resistance film is made to have a thickness of 55 µm at both ends thereof and another thickness of 70 µm at the center thereof. Onto each of these resistance films were plasma-sprayed an upper insulating layer having a thickness of 100 µm and a protective layer of PFA in turn, whereby directly heated rollers were produced. After an elapse of 20 minutes from the commencement of feeding electric power to the resultant rollers, there were measured temperature distributions thereof which are shown in the lower part of Fig. 8. As apparent in Fig. 8, in the roller (A) the temperature of the center portion thereof is high and the temperature of the end portions is extremely low, while in the roller (B) the temperature distribution thereof is in the same level.

Claims: A directly heated roller for fuse-fixing toner images, comprising a roller body (1) having a small heat capacity; a bonding layer (2) formed substantially uniformly on the outer peripheral surface of said roller body (1), a lower heat insulating layer (3) provided on said bonding layer (2), a heat generating layer (4) provided on said lower heat insulating layer (3) and having a ceramic matrix and a metallic phase dispersed therein so as to form a metallic resistance layer wherein the metallic phase extends preferably in the axial direction of the roller, said heat generating layer (4) having substantially the same thermal expansion coefficient as said lower heat insulating layer (3), a protective layer (6) formed over said heat generating layer (4) so as to prevent offset of said toner images, and an electrode layer (7) formed on each end of said roller to connect said heat generating layer (4) to an external power source, characterized by an upper heat insulating layer (5) provided between said heat generating layer (4) and said protective layer (6) and consisting essentially of an oxide or a mixture selected from Al₂O₃, MgO, ZrO₂, MgAl₂O₄, ZrO₂.SiO₂ and MnO.NiO. The roller of claim 1, wherein said heat generating layer (4) includes 10 to 35 wt% of an Ni-Cr alloy. The roller of claim 2, wherein said Ni-CR alloy essentially consists of 5 to 20 wt% of Cr and the balance substantially Ni. The roller of claim 2 or 3, wherein said ceramic is Al₂O₃. The roller of any of claims 1 to 3, wherein said heat insulating layers (3, 5) have thermal expansion coefficient which is not smaller than 6 × 10⁻⁶/°C. The roller of claim 5, wherein said lower heat insulating layer (3) has a thickness ranging between 200 and 500 µm. The roller of claim 6, wherein said lower heat insulating layer (3) has a thickness of about 300 µm, while said upper heat insulating layer (5) has a thickness of about 100 µm. The roller of any of claims 5 to 7, wherein said lower heat insulating layer (3) is made of an oxide selected from Al₂O₃, MgO, ZrO₂, MgAl₂O₄, ZrO₂.SiO₂, and MnO.NiO. the roller of any of claims 1 to 8, wherein the roller body (1) is made of iron or iron alloy. The roller of any of claims 1 to 9, wherein the wall thickness of said roller body (1) is not greater than 2 mm, preferably not greater than 1 mm. The roller of any of claims 1 to 10, wherein said bonding layer (2) is made of a material selected from Ni-Al-Mo alloy, Ni-Al alloy and Ni-Cr alloy, and is partially oxidized.

Inventors: IIMURA, TSUTOMU, SHIBATA, RYOICHI, TAKADA, YUKIHARU
Applicants: HITACHI METALS, LTD.
Application year: 1987
Main classification: G03G15
IPC codes: H05B3, G03G15