A PROCESS FOR CLEANING CHLORINATED WATER AND AN APPARATUS FOR CARRYING OUT THE PROCESS

Abstract: A process and an apparatus for cleaning chlorinated water, preferably in a swimming pool, imply that the water is circulated through a vessel (1) in which the water is irradiated by a plurality of UV radiation lamps (9) emitting light at a wave length exceeding 300 nm. Before the water passes one or more UV radiation lamps (9) emitting light at a wave length exceeding 300 nm, it is irradiated by IFR radiation lamps (8) emitting light at a wave length in the range of 765 nm to 10 mu m. The water is simultaneously irradiated by UV radiation lamps (10) emitting light at a wave length in the range of 100-200 nm. Subsequently the water is irradiated preferably in a second vessel (2) by UV radiation lamps (11) emitting light at a wave length of 253.7 nm.

Description: Title: A Process for Cleaning Chlorinated Water and an Apparatus for Carrying Out the Process Technical Field The invention relates to a process for cleaning chlorinated water, preferably in a swimming pool, by circulating the water through a vessel while said water is irradiated by 5a plurality of UV radiation lamps emitting light at a wave length exceeding 300 nm. The invention relates furthermore to an apparatus for carrying out the process. Background Art lODanish Patent Specification No. 144,663 discloses a process and an apparatus for cleaning chlorinated water, whereby the water ' initially passes a plurality of heating units and is subsequently irradiated by a number of UV radia¬ tion lamps inter alia emitting light at a wave length 15 exceeding 300 nm. During late years increasing requirements have been pre¬ sented to the treatment of water so as to reduce the amount of bacteria, the inorganic pollution, and the occurrence of chloroamines and trihalogen methanes. D Description of the Invention It turned out that these requirements can be met by the process according to the invention, said process being characterised in that the water is irradiated by IFR radia¬ tion lamps before it passes the UV radiation lamps emitting 5 light at a wave length exceeding 300 nm , said IFR radiation lamps emitting light at a wave length in the range of 765 nm to lOμm, and that the water furthermore is irradiated both by UV radiation lamps emitting light at a wave length in the range of 100 to 200 nm, and by UV radiation lamps emitting light at a. wave length of 253.7 nm. As a result a process is provided which ensures a strong and fast extinction of bacteria, a disintegration of lumps of bacteria, a fast and strong disintegration of chloro- 5 amines while liberating nitrogen, a fast and strong removal of tr halogen methanes, a reduction of the content of organic material in the water, as well as an efficient utilization of the electric energy for the radiation lamps. The strong and fast extinction of the bacteria is partly 10 consequence of the disintegration of the lumps of bac¬ teria. Such lumps of bacteria result primarily from resi¬ dues from the flocculation occurring in connection with a mechanical filtration, from secretions and saliva of the bathing persons, from residues of coatings of biological 2.5 material getting loose in the pipe system or the filter, as well as from growth of bacteria in the filter system. The reduction of the water content of organic material appears as lower values for COD (chemical oxygen consump¬ tion) and TOC (total organic carbon) . 20The use of the IFR radiation lamps of wave lengths in the range of 765 nm to 10 μm turned out to provide a far-reach¬ ing radiation effect in the water and at the same time the electric energy used is well converted into heat in the water. Tests " have for instance shown that 96% of the elec- 25 trie energy are converted into heat. The water is according to the invention particularly ad¬ vantageously passed alternately several times past the IFR radiation lamps and the UV radiation lamps emitting light at a wave length exceeding 300 nm. 30The process according to the invention may furthermore be characterised by continuously irradiating the water by UV radiation lamps emitting light at a wave length in the range of 100-200 nm. In this manner certainty is obtained that the ability of the preceding lamps to disintegrate lumps of bacteria is completely utilised before the bac- teria are subjected to the particularly bactericidal wave length of 253.7 nm. The invention deals furthermore with an apparatus for cleaning chlorinated water and comprising a first vessel, in which the water passes from an inlet to an outlet, both the inlet and the outlet being connected to the pool, and whereby the vessel is provided with at least one UV radiation lamp emitting light at a wave length exceeding 300 nm. This apparatus is according to the invention char¬ acterised in that the vessel further comprises at least one IFR radiation lamp emitting light at a wave length in the range of 765 nm to 10 μm , the IFR radiation lamp being situated in front of the UV radiation lamp in the flow direction, that the vessel further comprises at least one UV radiation lamp emitting light at a wave length in the range of 100-200 nm, and that UV radiation lamps emitting light at a wave length of 253.7 nm are provided in connec¬ tion with the vessel and preferably in a separate second vessel situated after the first vessel in the flow direc¬ tion.. As a result a particularly advantageously operating appa¬ ratus for carrying out the process is obtained. It turned out that the apparatus inter alia ensured the effects in question and at the same time the necessary consumption of chlorine was reduced. Brief Description of the Drawings The invention will be described below with reference to the accompanying drawing, in which Fig. 1 is a side view of a preferred embodiment of an apparatus according to the invention, Fig. 2 is a top view of the embodiment of Fig. 1, Fig. 3 is a graphic view showing the effect versus the time of the apparatus on colibacteria when various radia¬ tion lamps are coupled, and Fig. 4 is a graphic view showing in two different operation states the measurements of the amount of bond chlorine at the inlet and outlet, respectively, of the apparatus. Description of the Preferred Embodiments of the Invention The apparatus according to the invention, shown in Figs . 1 and 2 comprises a first vessel 1 and a second vessel 2 situated successively in a pipe system in the flow direc¬ tion of the water. This pipe system extends from an inlet 3 to an outlet 4 via a pump 5 and the two vessels 1 and 2. As illustrated the water flows into the bottom of the first vessel 1 and then upwards into the top of said first vessel. Subsequently, the water flows into the top of the second vessel 2 through a connecting piece 6 and then downwards and out at the bottom to the outlet 4 through a pipe 7. The first vessel 1 is provided with a number of IFR radia¬ tion lamps (infrared radiation lamps) 8 situated above one another so as to extend radially in a manner not de- scribed more detailed into the vessel transverse to the flow direction of the water. These IFR radiation lamps emit light at a wave length in the range of 765 nm to 10 μm. UV radiation lamps 9 are correspondingly provided, said lamps projecting radially inwards and emitting light at a wave length exceeding 300 nm. Thus the UV radiation lamps extend transverse to the flow direction of the water too . The first vessel 1 is furthermore provided with a plurality of UV radiation lamps 10 emitting light at a wave length in the range 100 to 200 nm. These UV radiation lamps 10 are mounted in the top of the first vessel 1 and extend axially downwards in a manner not described more detailed through the vessel 1 to the immediate vicinity of the bottom thereof. As illustrated in Fig. 2 the UV radiation lamps 10 are substantially equally spaced from the central axis of the round cylindrical vessel 1. In the top of the second vessel 2 a plurality of UV radia¬ tion lamps 11 are mounted, said lamps emitting light at a wave length of 253.7 nm. These UV radiation lamps 11 extend axially downwards through the second vessel 2 to the imme- diate vicinity of the bottom thereof and are circled about the axis thereof. Furthermore a single lamp extending coaxially with the axis of the vessel 2 is provided. In the shown preferred embodiment of the invention the two vessels 1 and 2 are of a diameter of about 30 cm and a height of about 1 m. The latter implies that the radia¬ tion lamps 8 and 9 are of a length of about 30 cm, and the radiation lamps 10 and 11 are of a length of about 1 m. By this apparatus the water is initially pumped by mesans of the pump 5 through the vessel 1 and subsequently through the vessel 2 at the same time as it passes alter¬ nately the IFR radiation lamps emitting light at a wave length in the range 765 nm to 10 μm and the UV radiation lamps emitting light at a wave length exceeding 300 nm . At the same time the water is continuously irradiated by the UV radiation lamps emitting light at a wave length in the range 100 nm to 200 nm. Upon this irradiation the water flows through the connecting piece 6 into the second vessel 2, where it is subjected to a strong radiation by the UV radiation lamps emitting light at a wave length of 253 . 7 nm . In order to illustrate the effects of the apparatus a number of tests employing various sets of lamps have been carried out. These tests revealed a water flow of the following values measured at the inlet of the apparatus: pH =- 7.2 Free chlorine — 0.6 mg/1 Bound chlorine =• 0.2 mg/1 The flow velocity of the water = 24 ^/h Flow period =• 40 sec. Below a number of tests A-E has been described in greater details, the two first A and B being comparison tests em¬ ploying equipment with the same starting data as mentioned above . Test A The water was filtrated through a "Millipore" filter of the type HA 0.45 μm. The amount of germs at 21° C was determined by agar plate counting and incubation for 72 hours. The amount of germs at 37°C was determined on blood agar (5% calf blood) and incubation at 37" C for 24 hours. Eosinmethylene blue agar (EMB) incubated at 37°C for 24 hours was used for the test for coliform bacteria. Suspect colonies on EMB were examined in McConkey bouillon, partly at 37 β C and partly at 44 β C for possible development of acid and air. Cetrlmld agar incubated at 42°C_for 72 hours was used for the test for Ps aeroginosa. At the inlet of this apparatus between 50 and 200 bacte¬ ria/100 ml were measured, and at the outlet of the appara¬ tus between 5 and 10 bacteria/100 ml were measured. Test B For this test an apparatus, like the one described in the above Danish Patent Specification No. 144,663 was used, but the UV radiation lamps emitting light at wave lengths exceeding 300 nm and of 253.7 nm being turned off. Thus only the heating units were turned on. At the inlet of this apparatus between 50 and 200 bacte¬ ria/100 ml were measured, and at the outlet of the appara¬ tus between 50 and 200 bacteria/100 ml were measured. Test C In an apparatus like the one shown in Figs . 1 and 2 only the IFR radiation lamps emitting light at wave lengths in the range 765 nm to 10 μm were turned on. At the inlet of this apparatus between 100 and 200 bacte¬ ria/100 ml were measured, and at the outlet of the appara¬ tus an overgrowth of bacteria corresponding to an uncount- able number of bacteria/100 ml were measured. Test D In the same apparatus the following lamps were turned on: 1. IFR radiation lamps emitting light at a wave length in the range 765 nm to 10 μm. 2. An UV radiation lamp emitting light at a wave length of 253.7 nm. At the Inlet of this apparatus between 50 and 200 bacte¬ ria/100 ml were measured, and at the outlet of the appara¬ tus between 300 and 500 bacteria/100 ml were measured. The above perhaps surprising rise in number of bacteria is not due to an actual growth but on the contrary to a strong disintegration of lumps of bacteria by the IFR radiation lamps. If the content of chlorine was consider¬ ably increased the bacteria would be extinguished but a number of negative effects arises as a consequence of the rise of allergy-causing and noxious organic chlorine com¬ pounds . Test E In the apparatus the following lamps were turned on: 1. The-IFR radiation lamps emitting light at a wave length In the range 765 n to 10 μm. 2. UV radiation lamps emitting light at a wave length in the range 100 and 200 nm. 3. UV radiation lamps emitting light at a wave length exceeding 300 nm. -• UV radiation lamps emitting light at a wave length of 253.7 nm. At the Inlet of this apparatus between 50 and 200 bacte¬ ria/100 ml were measured, and at the outlet of the appara¬ tus almost 0 bacteria/100 ml were measured. By the apparatus according to the invention less chlorine was added but the same electric energy was used, and a total extinction of germs was obtained unlike other tests. An essential feature is that by using IFR radiation lamps emitting light at a wave length in the range 765 nm to 10 μm instead of heating units like the apparatus of the above Danish Patent Specification, a very far-reaching radiation effect was obtained in the water at the same time as the electric energy used was converted into heat in the water. By a controlled test of 1 m 3 water an energy absorption of 96% was measured. Fig. 3 is a graphic view resulting from tests on the appa¬ ratus and showing the effect of the apparatus on water containing a predetermined amount of colibacteria through addition of such bacteria. Thus the various curves show the amount of colibacteria/ml water as function of the time upon starting of the apparatus. Each curve shows the apparatus in the following operation phases, the water at the inlet containing 0.06 mg of free chlorine/1 (H0C1+0C1" at pH 7.2) : 1. All the lamps of the apparatus were turned on. 2. The UV radiation lamps 10 emitting light at a wave length in the range of 100 nm to 200 nm were turned off while all the other lamps were turned on. 3. Only the UV radiation lamp 11 was turned on. 4. All the lamps were turned off and instead the addition of chlorine was increased to such an extent that the amount of free chlorine was 3 mg of free chlorine (HOCl+OCl " at pH 7.2)/l. 5. Only the UV radiation lamp emitting light at a wave length in the range of 100 nm to 200 nm was turned on, and 6. only the IFR radiation lamp 8 emitting light at a wave length in the range of 765 nm to 10 μm was turned on. A conventional chlorination of usual bathing water implies that after a reaction period of 10 in. the so-called "break-point' r is reached at an administration of 12 parts by weight of chlorine to 1 part by weight of ammonia (con- 5 sidered to be nitrogen) . When the same type of bathing water furthermore Is Irradiated in accordance with the process of the invention, the "break-point" is reached already after 40 sec. at an adminis ration of only 6 parts by weight to 1 part by weight of ammonia (considered to lObe nitrogen). The necessary period of 40 sec. corresponds to a passage through the apparatus. This result is only obtained provided all the lamps are turned on, whereas a turning off of merely one or more types of lamps implies that the apparatus has no effect at all. 15 Fig. 4 is a graphic view showing measurements of the amount of bound chlorine at the inlet (the X-axis) of the appara¬ tus and the outlet (the Y-axis) of the apparatus at various starting amounts. The two sets of measurements illustrate two operation phases of the apparatus: 0 1. Only the UV radiation lamps 9 and 10 emitting light at wave lengths exceeding 300 nm and of 253.7 n , respec¬ tively, were turned on. 2. All the radiation lamps of the apparatus were turned on. 25 These tests show that the apparatus ensures a considerable reduction of the amount of bound chlorine and consequently a strong decomposition of for instance chloroamines into nitrogen and hydrochloric acid. By the use of the process and the apparatus according to 30 the invention in connection with swimming pools a consider¬ able reduction of the content of trihalogen methanes, a lower amount of potassium permanganate, and a lower TOC ' value have been demonstrated. As far as for instance tri- halogen methanes are concerned tests with all the lamps turned on have shown a considerable reduction, whereas only a variation in production of trihalogen methanes appears when other combinations of lamps turned on are used. The good effect is presumably due to a correlation between the extensive removal of organic material and disintegration of for instance chloroform. A test measuring on the apparatus revealed the following values: Trihalogen methane inlet ! L87 Mg/1 outlet 0 Mg/1 KMnO, inlet 8. .38 mg/1 outlet 1. .93 mg/1 TOC inlet 4, .28 mg/1 outlet 1. .05 mg/1 FTU* inlet 0, .25 outlet 0. ,25 *FTU (formazine turbidity units) is a turbidity measuring measured by the amount of formazine added to completely pure crystal-clear water until water of the same turbidity like the bathing water is obtained. The invention has been described with reference to a pre.- ferred embodiment. Many modifications may, however, be carried out without thereby deviating from the scope of protection. According to a preferred embodiment the IFR radiation lamps are used as a 35 Ω resistance in the elec¬ tric circuit including the UV radiation lamps emitting light at a wave length exceeding 300 nm . As a result an economically advantageous control of the UV radiation lamps in question is ensured.

Claims: Claims : 1. A process for cleaning chlorinated water, preferably in a swimming pool, by circulating the water through a vessel (1, 2) while said water is irradiated by a plurality of UV radiation lamps (9) emitting light at a wave length 5 exceeding 300 nm, c h a r a c t e r i s e d in that the water is irradiated by IFR radiation lamps (8) before it passes the UV radiation lamps (9) emitting light at a wave length exceeding 300 nm, said IFR radiation lamps (8) emitting light at a wave length in the range of 765 nm 0 to 10μm r and that the water furthermore is irradiated both by UV radiation lamps (10) emitting light at a wave length In the range of 100 to 200 nm, and by UV radiation lamps (11) emitting light at a wave length of 253.7 nm. 2. A process as claimed in claim 1, c h a r a c t e r- 5 i s e d by alternately passing the water several times past the IFR radiation lamps (8) and the UV radiation lamps (9) emitting light at a wave length exceeding 300 nm. 3. A process as claimed in claim 1 or 2, c h a a c¬ t e r i s e d by continuously irradiating the water by 20 UV radiation lamps (11) emitting light at a wave length in the range of 100-200 nm. 4. A process as claimed in claim 1, 2 or 3, c h a r ¬ a c t e r i s e d by not Irradiating the water by UV radiation lamps (11) emitting light at a wave length of 25253.7 nm until it has passed all the other radiation lamps. 5. A process as claimed in claim 1, 2, 3 or 4, c h a r a c t e r i s e d in that the UV radiation lamps (10) emitting light at a wave length in the range of 100- 200 nm preferably emit light at a wave length in the range 30of 110-120 n . 6. An apparatus for cleaning chlorinated water and com¬ prising a first vessel (1) , in which the water passes from an inlet (3) to an outlet (4) , both the inlet and the outlet being connected to the pool, and whereby the 5 vessel (1) is provided with at least one UV radiation lamp (9) emitting light at a wave length exceeding 300 nm, c h a r a c t e r i s e d in that the vessel (1) further comprises at least one IFR radiation lamp (8) emitting light at a wave length in the range of 765 nm to 10 10 μm, the IFR radiation lamp being situated in front of the UV radiation lamp (10) in the flow direction, that the vessel (1) further comprises at least one UV radiation lamp (10) emitting light at a wave length in the range of 100-200 nm, and that UV radiation lamps (11) emitting 15 light at a wave length of 253.7 nm are provided in connec¬ tion with the vessel (1) and preferably In a separate second vessel (2) situated after the first vessel (1) in the flow direction. 7. An apparatus as claimed in claim 6, c h a r a c - o e r i s e d by the first vessel (1) including several IFR radiation lamps (8) and UV radiation lamps (9) emitting light at a wave length exceeding 300 nm, said IFR radiation lamps and said UV radiation lamps being situated in alter¬ nate succession in the flow direction. 5 8. An apparatus as claimed in claim 7, c h a r a c ¬ t e r i s e d in that the IFR radiation lamps (8) and the UV radiation lamps (9) emitting light at a wave length exceeding 300 nm extend transverse to the flow direction of the water through the vessel (1) , whereas the UV radia- 0 tion lamps (10) emitting light at a wave length in the range of 100-200 nm extend along the flow direction of the water inside the same area as the first-mentioned radiation lamps .

Inventors: KAAS POVL, KAAS, POVL
Applicants: KAAS POVL, KAAS, POVL
Application year: 1987
Main classification: C02F1
IPC codes: C02F1