HERBICIDAL HETEROCYCLIC SULFONAMIDES

Abstract: Sulfonylurea derivatives of formula wherein J is a pyrazole, thiophene or pyridine residue of defined structure; W is O or S; R₁ is H or CH₃; A is a mono- or bicyclic heterocyclic residue, e.g. pyrimidin-2-yl or triazinyl; and their agriculturally suitable salts, exhibit potent herbicidal activity. Some also exhibit a plant growth regulant action. The novel compounds may be made e.g. by reacting an appropriate sulfonyl isocyanate or isothiocyanate of formula JSO₂NCW with an appropriate aminoheterocycle HNR₁A.

Description: Background of the Invention This invention relates to novel ketone pyrazole, thiophene, and pyridine sulfonylurea herbicidal compounds, agriculturally suitable compositions thereof and a method of using them to control the growth of undesired vegetation. New compounds effective for controlling the growth of undesired vegetation are in constant demand. In the most common situation, such compounds are sought to selectively control the growth of weeds in useful crops such as cotton, rice, corn, wheat and soybeans, to name a few. Unchecked weed growth in such crops can cause significant losses, reducing profit to the farmer and increasing costs to the consumer. In other situations, herbicides are desired which will control all plant growth. Examples of areas in which complete control of all vegetation is desired are areas around railroad tracks and industrial storage areas. There are many products commercially available for these purposes, but the search continues for products which are more effective, less costly and environmentally safe. The "sulfonylurea" herbicides are an extremely potent class of herbicides discovered within the last few years. A multitude of structural variations exist within the class of herbicides, but they generally consist of a sulfonylurea bridge, -SO₂NHCONH-, linking two aromatic or heteroaromatic rings. EP-A95,925 which was published 7.12.83 discloses herbicidal sulfonylureas of formula wherein Q is, in part, R₁₀ is H, C₁-C₄ alkyl, C₃-C₄ alkenyl, C₃-C₄ alkynyl, CO₂R₂₄, SO₂NR₂₀R₂₁ or SO₂R₂₂; R₁₁ is H, C₁-C₃ alkyl, F, Cl, Br, NO₂, OR₁₆, CO₂R₂₄, S(O) m R₂₅ or SO₂NR₂₀R₂₁; provided that when R₁₀ is other than C₁-C₃ alkyl, then R₁₁ is H, Cl, OCH₃, NO₂, or CH₃; R₁₂ is H or CH₃; R₁₃ and R₁₄ are independently H, C₁-C₃ alkyl, OR₁₆, F, Cl, Br, NO₂, CO₂R₂₄, S(O) R₂₅ or SO₂NR₂₀R₂₁; provided that, when either of R₁₃ or R₁₄ is CO₂R₂₄, S(O) m R₂₅ or SO₂NR₂₀R₂₁, then the other is H, Cl, CH₃, OCH₃ or NO₂; and R₁₅ is H or CH₃. EP-A-87,780 (published 7.9.83) discloses herbicidal sulfonylureas of formula wherein A is H, C₁-C₈ alkyl or optionally substituted phenyl; B and C are independently H, halogen, NO₂, C₁-C₈ alkyl, arylalkyl, C₁-C₈ alkoxy, haloalkyl, CO₂R, CONR₁R₂, S(O) n R₃, SO₂NR₄R₅, or optionally substituted phenyl. ZA 83/3850 (published 28.11.83) discloses compounds of formula wherein Q is a five-membered, heterocyclic radical which is bound by way of a carbon atom and contains 2 or 3 heteroatoms and which may be optionally substituted by halogen, pseudohalogen, nitro, alkyl, hydroxyl, haloalkyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, amino, alkylamino, dialkylamino, alkylcarbonylamino, alkylcarbonyl, alkoxycarbonyl, alkoxyalkyl, alkylthiocarbonyl, carbamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsulfinyl, alkylsulfonyl, alkenyloxy or alkynyloxy; and groups such as phenyl, phenoxy or phenylthio, which are unsubstituted or substituted by halogen, nitro, cyano, alkyl, alkoxy, haloalkyl, alkylcarbonyl, alkoxycarbonyl or haloalkoxy; and also benzyl unsubstituted or substituted by halogen and/or alkyl. U.S. 4,127,405 and U.S. 4,169,719 disclose herbicidal thiophenesulfonamides, wherein the thiophene ring may be optionally substituted with CH₃, Cl or Br. U.S. 4,398,939 discloses herbicidal thiophenesulfonamides, wherein the thiophene ring is substituted with substituent groups selected from C₁-C₄ alkyl, C₃ alkenyl, OCH₃, NO₂, Cl, Br, SO₂N(C₁-C₃ alkyl)₂ or SO₂N(OCH₃)CH₃. U.S. 4,481,029 discloses herbicidal thiophenesulfonamides, wherein the thiophene ring is substituted with carboxylic acid, carboxylic ester and alkylcarbonyl groups or derivatives thereof. U.S. 4,441,910 discloses herbicidal thiophenesulfonamides, wherein the thiophene ring is substituted with the group represented by R₆S(O) n wherein R₆ is C₁-C₄ alkyl, C₃-C₄ alkenyl, cyclopentyl or cyclopropylmethyl. European Publication No. 13,480 (published July 23, 1980) discloses herbicidal pyridine-2-, -3- and -4-sulfonylureas, wherein the pyridine ring may be substituted by Cl, Br, F, C₁-C₄ alkyl, C₁-C₄ alkoxy, C₁-C₄ alkylthio, NO₂ or a carboxylic ester group. U.S. 4,456,469 (issued 29.6.84) discloses herbicidal pyridine-3-sulfonylureas substituted by C₁-C₆ alkyl-, C₃-C₆ alkenyl-, C₂-C₄ alkoxyalkyl- and C₅-C₆ cycloalkylsulfonyl groups. U.S. 4,518,776 (Swiss priority 19.7.82) discloses, in part, a process for the preparation of compounds of formula wherein R₁ is H, C₁-C₄ alkyl, halogen, NO₂, CN, NH₂, S(O) n C₁-C₄ alkyl, SO₂C₁-C₄ alkoxy, SO₂-di-C₁-C₄ alkylamino, CHO, CONH₂, DC₃-C₅ alkynyl, CODC₃-C₅ alkynyl, DC₁-C₄ alkyl, DC₃-C₅ alkenyl, COC₁-C₄ alkyl, CODC₁-C₄ alkyl or CODC₃-C₅ alkenyl; n is 1 or 2; D is O, S, NH or NC₁-C₄ alkyl; R₂ is H, halogen, CF₃, NO₂, C₁-C₄ alkyl or C₁-C₄ alkoxy; and A is O, S, NR₅ or -C=N-. U.S. 4.521,597 discloses, in part, a process for the preparation of compounds of formula wherein R₃ is H, halogen, NO₂, OCH₃ or CF₃; R₅ is H, F, Cl, Br, NO₂, C₁-C₅ alkyl, C₁-C₅ alkoxy, CF₃, S(O) m C₁-C₅ alkyl, COR₇ or SO₂NR₈R₉; Y is O, S or C(R₆)=N; and R₇ is H, C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkoxy, C₁-C₅ haloalkoxy, C₂-C₁₀ alkoxyalkoxy, C₃-C₅ alkenyloxy, C₃-C₅ alkynyloxy, phenoxy, benzyloxy, C₁-C₅ alkylthio or NR₈R₉. U.S. 4,549,898 discloses herbicidal sulfonylureas of formula wherein X is O, S, NR₄ or C(R₅)=N; Y is O or S; Z is O or S; E is N or CH; R₁ is H, C₁-C₄ alkyl, C₁-C₄ haloalkyl, C₁-C₄ haloalkoxy, C₁-C₄ alkoxy, halogen, C₁-C₄ alkylthio, NR₆R₇ or alkoxyalkyl containing not more than 4 carbon atoms; R₂ is H, C₁-C₃ alkyl, C₁-C₃ haloalkyl, halogen, NO₂, C₁-C₃ alkoxy, C(W)R₈, SO₂NR₆R₇, S(O) n -C₁-C₃ alkyl or COR₉; R₃ is H, halogen, C₁-C₃ alkyl, OCH₃ or CF₃; R₅ is H, NO₂, F, Cl, Br, CH₃, CF₃, S(O) n C₁-C₃ alkyl, COC₁-C₄ alkoxy or C₁-C₃ alkoxy; R₈ is H, C₁-C₆ alkyl, C₁-C₄ haloalkyl, C₃-C₆ cycloalkyl, C₄-C₇ cycloalkylalkyl or alkoxyalkyl containing not more than 4 carbon atoms; and W is O or NOR₁₀. Japanese Patent Application Number 58-70407 (SHO 59-219,281, laid open 10.12.84 discloses pyrazole-5-sulfonylureas of formula wherein A is H, lower alkyl or phenyl; B is H or lower alkyl; D is H, CO₂R or COAr, halogen, NO₂ or SO₂NR¹R²; and Ar is phenyl optionally substituted with halogen. U.S. 4,370,480 discloses herbicidal sulfonylureas of formula wherein R is H, C₁-C₂ alkyl, C₂-C₆ alkenyl, C₂-C₆ alkynyl; C₁-C₄ alkyl substituted with one to four substituents selected from 0-3 F, 0-3 Cl, 0-3 Br, 0-2 OCH₃, 0-1 cyano, 0-1 CO₂R ′ ₁ where R ′ ₁ is C₁-C₃ alkyl, CO₂R ′ ₁ , C₂-C₄ alkenyl substituted with 1-3 Cl, C₃-C₆ cycloalkyl, C₅-C₆ cycloalkenyl, C₅-C₆ cycloalkyl substituted with substituents selected from 1-3 CH₃ or one of CH₃CH₂, Cl, OCH₃, C₄-C₇ cycloalkylalkyl, or a single bond; and T is O or NOR III / 1. Japanese Patent Application Number 84-273152 (Sho 86-151188, laid open July 9, 1986) discloses the following compound Still further herbicidal sulfonylureas are disclosed in EP-A-0 030 142; EP-A-0 046 677; EP-A-0 097 122; EP-A-0 101 407; EP-A-0 107 624; JP-A-61 151 188 and JP-A-60 78980. SUMMARY OF THE INVENTION This invention relates to novel compounds of Formula I, agriculturally suitable compositions containing them, and their method-of-use as general preemergence and/or postemergence herbicides or plant growth regulants. wherein R is H, C₁-C₃ alkyl, phenyl, SO₂NR a R b , C₁-C₂ haloalkyl, C₂-C₄ alkoxyalkyl, C₂-C₃ cyanoalkyl, C₂-C₄ alkylthioalkyl, C₂-C₄ alkylsulfinylalkyl, C₂-C₄ alkylsulfonylalkyl, CO₂C₁-C₂ alkyl, C₁-C₄ alkylcarbonyl, C₁-C₂ alkylsulfonyl, C₃-C₄ alkenyl, C₃-C₄ alkynyl or C₁-C₂ alkyl substituted with CO₂C₁-C₂ alkyl; R₁ is H or CH₃; R₂ is H, C₁-C₃ alkyl, C₁-C₃ haloalkyl, halogen, nitro, C₁-C₃ alkoxy, SO₂NR c R d , C₁-C₃ alkylthio, C₁-C₃ alkylsulfinyl, C₁-C₃ alkylsulfonyl, CN, CO₂R e , C₁-C₃ haloalkoxy, C₁-C₃ haloalkylthio, amino, C₁-C₂ alkylamino, di(C₁-C₃ alkyl)amino or C₁-C₂ alkyl substituted with C₁-C₂ alkoxy, C₁-C₂ haloalkoxy, C₁-C₂ alkylthio, C₁-C₂ haloalkylthio, CN, OH or SH; R a and R b are independently C₁-C₂ alkyl; R c is H, C₁-C₄ alkyl, C₂-C₃ cyanoalkyl, methoxy or ethoxy; R d is H, C₁-C₄ alkyl or C₃-C₄ alkenyl; or R c and R d may be taken together as -(CH₂)₃-, -(CH₂)₄-, -(CH₂)₅- or -CH₂CH₂OCH₂CH₂-; R e is C₁-C₄ alkyl, C₃-C₄ alkenyl, C₃-C₄ alkynyl, C₂-C₄ haloalkyl, C₁-C₂ cyanoalkyl. C₅-C₆ cycloalkyl, C₄-C₇ cycloalkylalkyl or C₂-C₄ alkoxyalkyl; R′ is C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkyl substituted with one or two R₃ groups, C₂-C₅ alkenyl, C₂-C₅ haloalkenyl, C₃-C₅ alkenyl substituted with one or two R₃ groups, C₃-C₅ alkynyl, C₃-C₅ haloalkynyl, C₃-C₅ alkynyl substituted with one or two R₃ groups, C₃-C₅ cycloalkyl, C₃-C₅ halocycloalkyl, C₃-C₅ cycloalkyl substituted with one or two R₄ groups, C₄-C₇ cycloalkylalkyl, C₄-C₇ halocycloalkylalkyl, C₄-C₇ cycloalkylalkyl substituted with one or two R₄ groups, phenyl or benzyl; R₃ is C₁-C₃ alkoxy, C₁-C₃ alkylthio, C₁-C₃ haloalkoxy, C₁-C₃ alkylsulfinyl, C₁-C₃ alkylsulfonyl, CN, NO₂, OH, OR₅ or di-(C₁-C₃ alkyl)amino; R₄ is C₁-C₃ alkyl, C₁-C₃ alkoxy, C₁-C₃ haloalkoxy, CN, NO₂, OH, OR₅ or di-(C₁-C₃ alkyl)amino; R₅ is SO₂CH₃, Si(CH₃)₃, C₂-C₃ alkylcarbonyl or CO₂C₁-C₂ alkyl; E is a single bond or CH₂; W is O or S; n is O or 1; n′ is 0 or 1; X is H, C₁-C₄ alkyl, C₁-C₄ alkoxy, C₁-C₄ haloalkoxy, C₁-C₄ haloalkyl, C₁-C₄ haloalkylthio, C₁-C₄ alkylthio, halogen, C₂-C₅ alkoxyalkyl, C₂-C₅ alkoxyalkoxy, amino, C₁-C₃ alkylamino, di(C₁-C₃ alkyl)amino or C₃-C₅ cycloalkyl; Y is H, C₁-C₄ alkyl, C₁-C₄ alkoxy, C₁-C₄ haloalkoxy, C₁-C₄ haloalkylthio, C₁-C₄ alkylthio, C₂-C₅ alkoxyalkyl, C₂-C₅ alkoxyalkoxy, amino, C₁-C₃ alkylamino, di(C₁-C₃ alkyl)amino, C₃-C₄ alkenyloxy, C₃-C₄ alkynyloxy, C₂-C₅ alkylthioalkyl, C₁-C₄ haloalkyl, C₂-C₄ alkynyl, azido, cyano, C₂-C₅ alkylsulfinylalkyl, C₂-C₅ alkylsulfonylalkyl, or N(OCH₃)CH₃; m is 2 or 3; L₁ and L₂ are independently O or S: R₆ is H or C₁-C₃ alkyl; R₇ and R₈ are independently C₁-C₃ alkyl; Z is CH or N; Z₁ is CH or N; Y₁ is O or CH₂; X₁ is CH₃, OCH₃, OC₂H₅ or OCF₂H; X₂ is CH₃, C₂H₅ or CH₂CF₃; Y₂ is OCH₃, OC₂H₅, SCH₃, SC₂H₅, CH₃ or CH₂CH₃; X₃ is CH₃ or OCH₃; Y₃ is H or CH₃; X₄ is CH₃, OCH₃, OC₂H₅, CH₂OCH₃ or Cl; and Y₄ is CH₃, OCH₃, OC₂H₅ or Cl; and their agriculturally suitable salts; provided that a) when X is Cl, F, Br or I, then Z is CH and Y is OCH₃, OC₂H₅, N(OCH₃)CH₃, NHCH₃,N(CH₃)₂ or OCF₂H; b) when X or Y is C₁ haloalkoxy, then Z is CH; c) X₄ and Y₄ are not simultaneously Cl; d) when W is S, then R₁ is H, A is A-1 and Y is CH₃, OCH₃, OC₂H₅, CH₂OCH₃, C₂H₅, CF₃, SCH₃, OCH₂CH=CH₂, OCH₂C≡CH, OCH₂CH₂OCH₃, CH(OCH₃)₂ or 1,3-dioxolan-2-yl; e) when the total number of carbons of X and Y is greater than four, then the number of carbons of R must be less than or equal to two: f) when J is J-1, J-2, J-3 or J-4 then R′ is other than phenyl; g) when J is J-5, J-6 or J-7 wherein E is a single bond, then R′ is other than C₁-C₅ alkyl, C₃-C₅ alkenyl, phenyl, benzyl, cyclopentyl or C₄-C₇ cycloalkylalkyl; h) when either or both of X and Y are OCF₂H then J is J-1, J-2, J-3, J-4, J-8, J-9, J-10 or J-11; and i) when A is A-7 and Z₁ is M, then J is J-1, J-2, J-3 or J-4 and R′ is C₃-C₅ cycloalkyl; j) when the total number of carbon atoms of X and Y is greater than four, then the total number of carbon atoms of R₂ and R′ must be less than or equal to 7. In the above definitions, the term "alkyl", used either alone or in compound words such as "alkylthio" or "haloalkyl", denotes straight chain or branched alkyl, e.g. methyl, ethyl, n -propyl, isopropyl or the different butyl and pentyl isomers. Alkoxy denotes methoxy, ethoxy, n -propyloxy, isopropyloxy and the different butyl isomers. Alkenyl denotes straight chain or branched alkenes, e.g., 1-propenyl, 2-propenyl, 3-propenyl and the different butenyl and pentenyl isomers. Alkynyl denotes straight chain or branched alkynes, e.g. ethynyl, 1-propynyl, 2-propynyl and the different butynyl and pentynyl isomers. Alkylsulfonyl denotes methylsulfonyl, ethylsulfonyl and the different propylsulfonyl isomers. Alkylthio, alkylsulfinyl, alkylamino, etc. are defined analogously to the above examples. Cycloalkyl denotes cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. The term "halogen", either alone or in compound words such as "haloalkyl", denotes fluorine, chlorine, bromine or iodine. Further, when used in compound words such as "haloalkyl" said alkyl may be partially halogenated or fully substituted with halogen atoms and said halogen atoms may be the same or different. Examples of haloalkyl include CH₂CH₂F, CF₂CF₃ and CH₂CHFCl. The total number of carbon atoms in a substituent group is indicated by the C i -C j prefix where i and j are numbers from 1 to 7. For example, C₁-C₃ alkylsulfonyl would designate methylsulfonyl through propylsulfonyl, C₂ alkoxyalkoxy would designate OCH₂OCH₃, C₂ cyanoalkyl would designate CH₂CN and C₃ cyanoalkyl would designate CH₂CH₂CN and CH(CN)CH₃. Compounds preferred for reasons of increased ease of synthesis and/or greater herbicidal efficacy are: 1. Compounds of Formula I wherein in addition the provisos (a) to (j) there is additionally the following proviso (k) when J is J-5, R₁ is H, R₂ is H, E is CH₂, A is A-1, X is OCH₃, Y is OCH₃ and Z is CH, then R′ is other than CH₃. 2. Compounds of Formula I where E is a single bond; and W is 0. 3. Compounds of Formula I where E is CH₂; and W is 0. 4. Compounds of Preferred 2 where R₂ is H, C₁-C₃ alkyl, halogen, C₁-C₃ alkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, OCH₃, SO₂NHCH₃, SO₂N(CH₃)₂, S(O) n CH₃, CO₂CH₃, CO₂CH₂CH₃, OCF₂H, CH₂OCH₃ or CH₂CN; R is H, C₁-C₃ alkyl, phenyl, CH₂CF₃ or CH₂CH=CH₂; X is C₁-C₂ alkyl, C₁-C₂ alkoxy, Cl, F, Br, I, OCF₂H, CH₂F, CF₃, OCH₂CH₂F, OCH₂CHF₂, OCH₂CF₃, CH₂Cl or CH₂Br; and Y is H, C₁-C₂ alkyl, C₁-C₂ alkoxy, CH₂OCH₃, CH₂OCH₂CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂CH=CH₂, OCH₂C≡CH, OCH₂CH₂OCH₃, CH₂SCH₃, OCF₂H, OCF₂Br. SCF₂H, cyclopropyl, C≡CH or C≡CCH₃. 5. Compounds of Preferred 4 where R′ is C₁-C₄ alkyl, C₁-C₃ alkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, C₂-C₄ alkoxyalkyl, C₂-C₄ alkylthioalkyl, C₂-C₄ cyanoalkyl, C₂-C₄ alkenyl, C₂-C₃ alkenyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, C₃-C₄ alkynyl, C₃-C₅ cycloalkyl, C₃-C₅ cycloalkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br or cyclopropylmetnyl. 6. Compounds of Preferred 5 where A is A-1; n is O: X is CH₃, OCH₃, OCH₂CH₃, Cl or OCF₂H; and Y is CH₃, OCH₃, C₂H₅, CH₂OCH₃, NHCH₃, CH(OCH₃)₂ or cyclopropyl. 7. Compounds of Preferred 6 where R₁ is H; R₂ is H, Cl, Br, OCH₃ or CH₃; and R′is C₁-C₃ alkyl, C₁-C₃ alkyl substituted with 1 to 3 F, C₂-C₃ alkoxyalkyl, C₂-C₃ alkylthioalkyl, C₂-C₃ cyanoalkyl, C₂-C₃ alkenyl, propargyl, C₃-C₅ cycloalkyl or cyclopropylmethyl. 8. Compounds of Preferred 7 where J is J-1. 9. Compounds of Preferred 7 where J is J-2. 10. Compounds of Preferred 7 where J is J-3. 11. Compounds of Preferred 7 where J is J-4. 12. Compounds of Preferred 7 where J is J-5. 13. Compounds of Preferred 7 where J is J-6. 14. Compounds of Preferred 7 where J is J-7. 15. Compounds of Preferred 7 where J is J-8. 16. Compounds of Preferred 7 where J is J-9. 17. Compounds of Preferred 7 where J is J-10. 18. Compounds of Preferred 7 where J is J-11. 19. Compounds of Preferred 8 where R′ is C₁-C₃ alkyl. 20. Compounds of Preferred 8 where R′ is C₁-C₃ alkyl substituted with 1 to 3 F, C₂-C₃ alkoxyalkyl, C₂-C₃ alkylthioalkyl, C₂-C₃ cyanoalkyl, C₂-C₃ alkenyl, propargyl, C₃-C₅ cycloalkyl or cyclopropylmethyl. 21. Compounds of Preferred 8 where R′ is C₃-C₅ cycloalkyl. 22. Compounds of Preferred 3 where R is H, C₁-C₃ alkyl, phenyl, CH₂CF₃ or CH₂CH=CH₂; R₂ is H, Cl, Br, OCH₃ or CH₃; R′ is C₁-C₃ alkyl, C₁-C₃ alkyl substituted with 1 to 3 F, C₂-C₃ alkoxyalkyl, C₂-C₃ alkylthioalkyl, C₂-C₃ cyanoalkyl, C₂-C₃ alkenyl, propargyl, C₃-C₅ cycloalkyl or cyclopropylmethyl. n is O; A is A-1: X is CH₃, OCH₃, OCH₂CH₃, Cl or OCF₂H; and Y is CH3, OCH₃, C₂H₅, CH₂OCH₃, NHCH₃, CH(OCH₃)₂ or cyclopropyl. 23. Compounds of Formula I where J is J-1, J-2, J-3 or J-4; and R′ is C₁-C₅ haloalkyl, C₁-C₅ alkyl substituted with one or two R₃ groups, C₂-C₅ alkenyl, C₂-C₅ haloalkenyl, C₃-C₅ alkenyl substituted with one or two R₃ groups, C₃-C₅ alkynyl, C₃-C₅ haloalkynyl, C₃-C₅ alkynyl substituted with one or two R₃ groups, C₃-C₅ cycloalkyl, C₃-C₅ halocycloalkyl, C₃-C₅ cycloalkyl substituted with one or two R₄ groups, C₄-C₇ cycloalkylalkyl substituted with one or two R₄ groups, phenyl or benzyl. 24. Compounds of Formula I where J is J-5, J-6 or J-7. 25. Compounds of Formula I where when J is J-8, J-9, J-10 or J-11. Compounds of the invention specifically preferred for reasons of greatest ease of synthesis and/or greatest herbicidal efficacy are 4-(cyclopropylcarbonyl)-N-[(4,6-dimethoxy-pyrimidin-2-yl)aminocarbinyl]-1-methyl-1H-pyrazole-5-sulfonamide, m.p. 189-192°C (d); 4-(1-oxopropyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-methyl-1H-pyrazole-5-sulfonamide, m.p. 189-192°C(d), and 2-(cyclopropylcarbonyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-thiophenesulfonamide, m.p. 165-168°C. The compounds of this invention are highly active as preemergent and/or postemergent herbicides or plant growth regulants with selectivity on rice, corn, wheat, soybeans and barley. DETAILED DESCRIPTION OF THE INVENTION Synthesis Compounds of Formula I can be prepared by one or more of the procedures shown in Equations 1, 4, and 5. J, R₁,and A are as previously defined. The reaction of Equation 1 is best carried out in an inert aprotic organic solvent such as dichloromethane, 1,2-dichloroethane, tetrahydrofuran, or acetonitrile, at a temperature between 20° and 85°C. The order of addition is not critical; however, it is often convenient to add the sulfonyl isocyanate or a solution of it in the reaction solvent, to a stirred suspension of the amine. In some cases, the desired product is insoluble in the reaction solvent at ambient temperature and crystallizes from it in pure form. Products soluble in the reaction solvent are isolated by evaporation of the solvent. Compounds of Formula I then may be purified by trituration of the evaporation residue with solvents such as 1-chlorobutane or ethyl ether and filtration, by recrystallization from mixtures of solvents such as 1,2-dichloroethane, 1-chlorobutane and heptane or by chromatography on silica gel. Sulfonyl isocyanates (II, W is O) are known in the art and are prepared from the corresponding sulfonamides (IV) by one of the following two general methods. The sulfonamide IV is reacted with an alkyl isocyanate (e.g., n -butyl isocyanate) in a solvent whose boiling point is above 135°C, such as xylene. The reaction can optionally be carried out in the presence of a catalytic amount of 1,4-diaza[2.2.2]bicyclooctane (DABCO). The reaction mixture is heated to 135-140°C and held at that temperature for 5-60 minutes, after which phosgene is slowly added at such a rate that the temperature remains between 133 and 135°C. When the consumption of phosgene has ceased, the mixture is cooled and filtered to remove insoluble material. Finally, the solvent, alkyl isocyanate, and excess phosgene are evaporated, leaving the sulfonyl isocyanate (II). If desired, the alkyl isocyanate-sulfonamide adduct can be made and isolated before reaction with the phosgene. In this case the sulfonamide (IV), alkyl isocyanate, and anhydrous base (e.g, K₂CO₃) in a polar, aprotic solvent (e.g. acetone, butanone, or acetonitrile) are mixed and heated under reflux for 1 to 6 hours. The reaction mixture is then diluted with water, and the pH is adjusted to about 3 with acid (e.g. HCl, H₂SO₄). The adduct is filtered out and dried, and then reacted with phosgene as described above. This procedure modification is especially useful when sulfonamide (IV) is high melting and has low solubility in the phosgenation solvent. Sulfonyl isocyanates (II, W is O) can also be prepared by the following method. The sulfonamide (IV) is heated at reflux in an excess of thionyl chloride. The reaction is continued until the sulfonamide protons are no longer detectable in the proton magnetic resonance spectrum. From 16 hours to 5 days is typically sufficient for complete conversion to the thionylamide (V) (Equation 3a). The thionyl chloride is evaporated and the residue is treated with an inert solvent (e.g. toluene) containing at least one equivalent (typically 2-3 equivalents) of phosgene. A catalytic amount of pyridine (typically 0.1 equivalent) is added, and the mixture is heated to about 60-140°C, with 80-100°C preferred. Conversion to the isocyanate (II, W is O) is usually substantially complete within 15 minutes to 3 hours (Equation 3b). The mixture is then cooled and filtered, and the solvent is evaporated, leaving the sulfonyl isocyanate (II, W is O). Sulfonyl isothiocyanates (II, W is S) are known in the art and are prepared from the corresponding sulfonamides (IV) by reaction with carbon disulfide and potassium hydroxide followed by treatment of the resulting dipotassium salt VI with phosgene. Such a procedure is described in Arch. Pharm. 299 , 174 (1966). Many of the compounds of Formula I can be prepared by the procedure shown in Equation 4. The reaction of Equation 4 is carried out by contacting phenylcarbamates or phenylthiocarbamates of Formula VI with aminoheterocycles of Formula III in an inert organic solvent such as dioxane or tetrahydrofuran at temperatures of about 20-100°C for a period of about one-half to twenty-four hours. The product can be isolated by evaporation of the reaction solvent and purified by methods previously described. Phenylcarbamates and phenylthiocarbamates of Formula VI can be prepared by the methods described, or modifications thereof known to those skilled in the art, in U.S. 4,443,243. Alternatively, many of the compounds of Formula I can be prepared by the method described in Equation 5. The reaction of Equation 5 can be carried out by contacting equimolar amounts of a sulfonamide of Formula IV with a heterocyclic phenylcarbamate or phenylthiocarbamate of Formula VII in the presence of a base such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), by methods analogous to those described in South African Patent Application 83/0441. The phenylcarbamates and phenylthiocarbamates of Formula VII can be prepared by methods, or modifications thereof known to those skilled in the art, described in South African Patent Application 82/5671 and South African Patent Application 82/5045. The sulfonamides IV of this invention may be prepared in a variety of ways some of which are described in Equations 6 through 15. For example, the 4-keto-5-sulfonamide isomer 1 may be prepared as outlined in Equation 6. Preparation of the intermediates such as bromide 2 may be found in EPA-95,925. Exposure of bromide 2 to nBuLi followed by addition of the resulting anion to cyclopropyl acid chloride affords the protected sulfonamide. Deprotection of the sulfonamide affords the desired sulfonamide 1 . Introduction of various R and R₂ groups to sulfonamides such as 1 may be accomplished in several ways. For example, the sequence in Equation 6 could also be performed on 3-chloro-1-methylpyrazole or 1,3-dimethylpyrazole affording 3 and 4 respectively. Chloride 3 may then be used to further elaborate R₂ as outlined in Equation 7. The N-substituent of compounds such as 1 , 3 , 4 and 5 may also be varied by applying the same sequence of reactions as outlined in Equation 6 to various N-substituted pyrazoles. For example, pyrazole may be alkylated with dimethylsulfamoylchloride to afford pyrazole 6. Pyrazole 6 is then converted to sulfonamide 7 as outlined in Equation 8. In the case where either R or R₂ are sensitive to nBuLi (i.e. R₂ is CO₂CH₃ or Br) then the lithiating reagent of choice is lithium diisopropylamide (LDA). Utilizing the same sequence as outlined in Equation 6 but substituting LDA for nBuLi affords sulfonamides such as 8. This is outlined in Equation 9. The isomeric 5-keto-4-sulfonamide pyrazoles may be prepared as outlined in Equations 10 and 11. In Equation 10 the sequential order of group introduction is reversed to that of Equation 6. The introduction of various R and R₂ groups may be accomplished in the same manor as previously described for the 4-ketoisomer in Equations 7, 8 and 9. An alternate synthesis of sulfonamides such as 9 is outlined in Equation 11. Oxidations of alcohols to ketones such as 12 to 9 are well known in the art. For further discussion pertaining to the oxidation of alcohols to ketones, see R. H. Cornforth, J. W. Cornforth and G. Popjak, Tetrahedron, 18 , 1351 (1962). The isomeric 3-keto-4-sulfonamide such as 13 may be prepared as outlined in Equation 12. In the above example of Equation 12, as before, minor variations of starting material allows for the introduction of different R and R₂ groups. The starting pyrazoles 14 or 15 may be prepared via the condensation of a hydrazine with a triketo species as outlined in Equation 13. The final pyrazole isomer of the invention such as sulfonamide 16 may be prepared as outlined in Equation 14. Again, as described previously, alteration of the starting material allows for the preparation of compounds such as 16 where R and/or R₂ may be varied. For example, utilizing phenylhydrazine and a chloronitrite results in pyrazole 20 and subsequently sulfonamide, 21. This is outlined in Equation 15. In all the above examples, substitution of cyclopropyl acid chloride with other acid chlorides would result in the corresponding ketones such as compounds 22 , 23 , 24 , 25 and 26 . For further details pertaining to the synthesis of pyrazoles see EP-A-87,780, South African Patent Application 833,350, EP-A-95,925 and T. L. Jacobs, "Heterocyclic compounds", R. C. Elderfield ed., Vol. 5, pp. 45-161, Wiley, New York, 1957. For further details pertaining to carbanions see J. Stowell, "Carbanions in Organic Synthesis", Wiley-Interscience, New York, 1979. Thiophene sulfonamides such as 27 may be prepared as outlined in Equation 16. Introduction of various R₂ groups on the thiophene ring may be accomplished in several ways. For example, the sequence in Equation 16 may also be performed on the 4-substituted analogs resulting in the corresponding sulfonamides such as 29 and 30 . The isomeric 2-thiophenesulfonamide such as 31 may be prepared as outlined in Equation 17. An alternate synthesis of sulfonamides such as 31 is outlined in Equation 18. The isomeric 3-thiophenesulfonamide such as 33 may be prepared as outlined in Equation 19. Introduction of various R₂ groups onto the thiophene ring may be accomplished by varying the starting material as previously described. Further details pertaining to the preparation and functional group manipulation of thiophenes may be found in U.S. Patent 4,481,029. Preparation of the pyridinesulfonamtdes of this invention, such as pyridine 36 may be carried out in a variety of ways. For example, Meerwein reaction of 37 followed by ortho lithiation affords sulfonamides such as 36 , as outlined in Equation 20. Prior to removal of the tert -butyl group it may be necessary to protect the ketone functionality as the ethylene ketal which may then be removed subsequently at a later time. The isomeric sulfonamide, 39 , may be prepared as outlined in Equation 21. The isomeric sulfonamide 40 may be prepared as outlined in Equation 22. Introduction of various substituents on the pyridine ring system as well as variation of R′ may be accomplished as described previously for the pyrazole system. For further details pertaining to the synthesis of pyridines see, E. Beritmaier, S. Gassenmann and E. Bayer, Tetrahedron 26 , 5907 (1970); B. Blank et al., J. Med. Chem. , 1, 1065 (1974); M. Mallet and G. Queguiner, Tetrahedron , 41 , 3433 (1985) and J. Delarge and C. L. Lapiere, Annales Pharm. France , 36 , 369 (1978). The synthesis of heterocyclic amines such as those represented by Formula III has been reviewed in "The Chemistry of Heterocyclic Compounds," a series published by Interscience Publ., New York and London. Aminopyrimidines are described by D. J. Brown in "The Pyrimidines," Vol. XVI of the series mentioned above which is herein incorporated by reference. The 2-amino-1,3,5-triazines of Formula III, where A is A-1 and Z is N, can be prepared according to methods described by E. M. Smolin and L. Rapaport in "s-Triazines and Derivatives," Vol. XIII. Pyrimidines of Formula III, where A is A-1 and Y is an acetal or thioacetal substituent, can be prepared by methods taught in European Patent Application no. 84,224 (published July 27, 1983). Pyrimidines of Formula III, where A is A-1 and Y is cyclopropyl or OCF₂H can be synthesized according to the methods taught in United States Patent 4,515,626 and United States Patent 4,540,782, respectively. Compounds of Formula III, where A is A-2 or A-3, can be prepared by procedures disclosed in United States Patent 4,339,267. Compounds of Formula III, where A is A-4, can be prepared by methods taught in United States Patent 4,487,626. Additional references dealing with the synthesis of bicyclic pyrimidines of formula III, where A is A-2, A-3, or A-4 are Braker, Sheehan, Spitzmiller and Lott, J. Am. Chem. Soc. , 69 , 3072 (1947); Mitler and Bhattachanya, Quart. J. Indian Chem. Soc. , 4 , 152 (1927); Shrage and Hitchings, J. Org. Chem. , 16 , 1153 (1951); Caldwell, Kornfeld and Donnell, J. Am. Chem. Soc. , 63 , 2188 (1941); and Fissekis, Myles and Brown, J. Org. Chem. , 29 , 2670 (1964). Compounds of Formula III, where A is A-5, can be prepared by methods taught in United States Patent 4,421,550. Compounds of Formula III, where A is A-6, can be prepared by methods taught in the United States Patent 4,496,392. Compounds of Formula III, where A is A-7 can be prepared by methods taught in EP-A-125,864. Agriculturally suitable salts of compounds of Formula I are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by contacting compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, carbonate or hydroxide). Quaternary amine salts can be made by similar techniques. Salts of compounds of Formula I can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct contact of an aqueous solution of a salt of a compound of Formula I (e.g., alkali or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water and can be separated by filtration. Exchange may also be effected by passing an aqueous solution of a salt of a compound of formula I (e.g., an alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged for that of the original salt and the desired product is eluted from the column. This method is particularly useful when the desired salt is water-soluble, e.g., a potassium sodium or calcium salt. Acid addition salts, useful in this invention, can be obtained by reacting a compound of Formula I with a suitable acid, e.g., p -toluenesulfonic acid, trichloroacetic acid or the like. The preparation of the compounds of this invention is further illustrated by the following specific examples. Unless otherwise indicated, temperatures are in degrees centigrade. Example 1 Preparation of 4-cyclopropylcarbonyl-1-methyl-5-pyrazole t-butyl sulfonamide To a cooled -78°C, solution of n-BuLi (3.7 g, 57.2 mmol) in approximately 350 ml of tetrahydrofuran is added 1-methyl-4-bromo-5-pyrazole t-butylsulfonamide (7.5 g, 25.4 mmol) dropwise. The solution is stirred for 15 minutes and then added via cannula to freshly distilled cyclopropyl acid chloride (6 g, 57.2 mmol) cooled to -78°C. The resulting solution was quenched with brine, separated, dryed and concentrated in vaccuo . The resulting oil was flash chromatographed (50:50 (v/v)) ethylacetate-hexane to afford 2.7 g of a white solid, m.p. 113-115°C. Example 2 Preparation of 4-cyclopropylcarbonyl-1-methyl-5-pyrazolesulfonamide To a stirring solution of trifluoroacetic acid was added 4-cyclopropyl-1-methyl-5-pyrazole t-butylsulfonamide. The solution was stirred overnight at room temperature. The reaction mixture was concentrated in vaccuo and the resulting solids were triturated with n -butylchloride, m.p. 125-127°C; NMR (200 MHz, CDCl₃) 1.1 (m, 2H), 1.3 (m, 2H), 2.4 (m, 1H), 4.2 (s, 3H), 6.4 (br. s, 2H), 8.07 (s, 1H). Example 3 Preparation of 4-(Cyclopropylcarbonyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-methyl-1H-pyrazole-5-sulfonamide To a stirring mixture of the sulfonamide from Example 2 (175 mg, 0.76 mmol) and the phenylcarbamate of 4,6-dimethoxy-2-aminopyrimidine (210 mg, 0.76 mmol) in 3 ml of acetonitrile was added diazobicycloundecane (116 mg, 0.76 mmol). The solution was stirred for approximately 10 minutes. Acidification of the reaction mixture and filtration of the resulting solids afforded 300 mg of the desired compound m.p. 189-192°C NMR (200 MHz, CDCl₃) 1.0 (m, 2H), 1.1 (m, 2H), 2.4 (m, 1H), 4.0 (s, 6H), 4.35 (s, 1H), 5.80 (s. 1H), 7.4 (br. S, 1H), 8.05 (s, 1H), 12.9 (s, 1H). Example 4 Preparation of 4-Acetyl-1-methyl-1H-pyrazole-5-sulfonamide To a stirring solution of n -BuLi (3.7 g, 57.2 mmol) in 350 mL of tetrahydrofuran cooled to -95°C is added 4-bromo-1-methyl-1H-pyrazole-5- t -butylsulfonamide (7.5 g, 25.4 mmol). The solution is cannulated into a stirring solution of acetyl chloride (76.2 mmol) cooled to -78°C. The reaction is stirred for 1/2 hour at -78°C then quenched with saturated sodium chloride. The organic layer is separated, dried and concentrated. The resulting crude oil was added to CF₃CO₂H and allowed to stir for 24 hours. The acid was removed under vacuum and the resulting oil was flash chromatographed. The resulting solid, m.p. 153-162°C, was mostly the closed hemiaminal, which was used directly in the next reaction. Example 5 Preparation of 4-Acetyl-N-[(4,6-dimethoxy-2-pyrimidinyl)aminocarbonyl]-1-methyl-1H-pyrazole-5-sulfonamide To a mixture of the hemiaminal from Example 4 (200 mg, 0.98 mmol), the phenyl carbamate of 4,6-dimethoxy-2-aminopyrimidine (271 mg, 0.98 mmol) 3 mL of acetonitrile, and DBU (212 mg, 0.98 mmol) was added. The reaction was diluted with 3 mL of water and 3 mL of 5% hydrochloric acid. The resulting solids were collected to afford 200 mg of a white solid, m.p. 179-182°C; NMR (200 MHz, CDCl₃) δ 2.46 (s, 3H), 4.06 (s, 6H), 4.37 (s, 3H), 5.81 (s, 1H), 7.4 (br.s, 1H), 7.9 (s, 1H) and 13.0 (br.s, 1H); IR (KBr) 1730 cm⁻¹. Example 6 Preparation of N-(1,1-Dimethylethyl)-1-methyl-4-(1-oxobutyl)-1H-pyrazole-5-sulfonamide To a solution of n -BuLi (2.1 g, 33.7 mmol) cooled to -78°C in 250 mL of tetrahydrofuran is added the t -butyl protected 4-bromo-1-methyl-5-pyrazolesulfonamide (4.5 g, 15.2 mmol). The solution is then added to butyric anhydride (2.9 g, 18.2 mmol) at -78°C. Standard work-up afforded 4.4 g of an oil which was a mixture of the desired product and debrominated starting material. This material was not purified, but used as is in the next reaction. Example 7 Preparation of 1-Methyl-4-(1-oxobutyl)-1H-pyrazole-5-sulfonamide The mixture from the previous Example 6 (3.9 g) was added to CF₃CO₂H (TFA) and stirred for 4.5 hours. Removal of the TFA afforded a brown oil. Flash chromatography (15:85 EtOAC:hexane (v/v)) yielded 1.0 g of a white solid, m.p. 97-99°C. NMR (200 MHz, CDCl₃) δ 0.97 (t, 3H), 1.67 (m, 2H), 2.83 (t, 3H), 4.19 (s, 3H), 6.40 (br.s, 2H) and 7.91 (s, 1H). Example 8 Preparation of N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-methyl-4-(1-oxobutyl)-1H-pyrazole-5-sulfonamide To a mixture of sulfonamide (150 mg, 0.61 mmol) and the phenyl carbamate of 4-methyl-6-methoxy-2-aminotriazine (158 mg, 0.61 mmol) in 3 mL of acetonitrile is added DBU (93 mg, 0.61 mmol). The solution is diluted with 3 mL of H₂O and 3 mL of 5% HCl, and the resulting solids are collected, m.p. 174-176°C. NMR (200 MHz, CDCl₃) δ 0.88 (s, 3H), 1.68 (m, 2H), 2.7 (s, 3H), 2.79 (t, 2H), 4.19 (s, 3H), 4.33 (s, 3H), 7.7 (br.s. 1H), 7.9 (s, 1H) and 12.9 (br.s, 1H). Example 9 Preparation of 2-(cyclopropylcarbonyl)-N-(1-1-dimethylethyl)-3-thiophenesulfonamide To a stirring solution of n -BuLi (6.6g, 102 mmol) in 300 ml of tetrahydrofuran is added the t-butyl protected 3-thiophenesulfonamide (10.0g, 45.7 mmol). The solution was warmed to -30°C and then recooled to -78°C. The solution was cannulated into a mixture of cyclopropane carbonylic acid chloride (5.7g. 51.7 mmol) in 50 ml of tetrahydrofuran @ -78°C. The reaction was quenched with brine, separated and dryed over magnesium sulfate, concentration of the organic in vaccuo afforded 17g of anvil. Flash chromatography (25:75 EtCAC/hexane (v/v)) afforded 44 g of the desired product. NMR (200MHz, CDC₃) δ 1.26 (m, 13H), 2.5 (m, 1H), 6.5 (br. S, 1H), 7.5 (d, 1H), 7.67 (d, 1H): Example 10 Preparation of 2-(cyclopropylcarbonyl)-N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-3-thiophenesulfonamide To a stirring solution of sulfonamide (300 mg, 1.3 mmol), the phenylcarbamate of 4,6-dimethoxy-2-aminotriazine (358 mg, 1.3 mmol) in 5 ml of acetonitrile was added DBU (197 mg, 1.3 mmol). The same work up as in example 5 afforded 390 mg of the desired product. m.p. 146-148°C, NMR (200 mHz, CDCl₃) δ, 1.1 (m,2H), 1.3 (m,2H), 2.5 (m,1H), 4.1 (S,6H), 7.5 hr,s,1H), 7.6 (d,1H), 7.9 (d,1H), 12.3 (s,1H): Using the procedures from Equations 1 to 22 and Examples 1 to 10 the compounds of Tables I to XV can be prepared. Formulations Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions: Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing. Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, New Jersey, but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0°C. "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, New Jersey, as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc. The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Patent 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering , December 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff. For further information regarding the art of formulation, see for example: H. M. Loux, U.S. Patent 3,235,361, February 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41; R. W. Luckenbaugh, U.S. Patent 3,309,192, March 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182; H. Gysin and E. Knusli, U.S. Patent 2,891,855, June 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4; G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96; and J. D. Fryer-and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103. In the following Examples, all parts are by weight unless otherwise indicated. Example 11 The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged. Example 12 The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging. Example 13 Example 14 The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled. Example 15 The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged. Example 16 The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water content is reduced to the desired level, generally less than 1%. The material is then discharged, screened to the desired size range, generally 14 to 100 mesh (1410 to 149 microns), and packaged for use. Example 17 The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged. Example 18 The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size. Example 19 The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use. Example 20 The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening). Thhe concentrate may be formulated further if necessary. Example 21 The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen (0.3 mm opening) and then packaged. Example 22 The ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged. Example 23 The ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water. Example 24 The active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous. Example 25 The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water. Example 26 The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged. Example 27 The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged. Example 28 The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging. Example 29 Example 30 The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged. Example 31 The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size. Example 32 The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary. Example 33 The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged. Example 34 The ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water. Example 35 The active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous. Utility Test results indicate that the compounds of the present invention are highly active preemergent or postemergent herbicides or plant growth regulants. Many of them have utility for broad-spectrum pre- and/or post-emergence weed control in areas where complete control of all vegetation is desired, such as around industrial storage areas, parking lots, drive-in theaters, around billboards, highway and railroad structures. Some of the compounds have utility for selective weed control in crops such as wheat, barley, rice, soybeans and corn. Alternatively, the subject compounds are useful to modify plant growth. The rates of application for the compounds of the invention are determined by a number of factors, including their use as plant growth modifiers or as herbicies, the crop species involved, the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general terms, the subject compounds should be applied at levels of around 0.001 to 10 kg/ha, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, for plant growth modification or for situations where only short-term persistence is required. The compounds of the invention may be used in combination with any other commercial herbicide, examples of which are those of the triazine, triazole, imidazolinone, uracil, urea, amide, diphenylether, carbamate and bipyridylium types as well as other sulfonylureas. They are particularly useful with the following herbicides. The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedures and results follow. Test A Seeds of crabgrass ( Digitaria spp.), barnyardgrass ( Echinochloa crusgalli ), giant foxtail ( Setaria faberi ), wild oats ( Avena fatua ), cheatgrass ( Bromus secalinus ), velvetleaf ( Abutilon theophrasti ), morningglory ( Ipomoea spp.), cocklebur ( Xanthium pennsylvanicum ), sorghum, corn soybean, sugarbeet, cotton, rice, wheat, barley and purple nutsedge ( Cyperus rotundus ) tubers were planted and treated preemergence with the test chemicals dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were treated with a soil/foliage application. At the time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings, summarized in Table A, are based on a numerical scale extending from 0 = no injury, to 10 = complete kill. The accompanying descriptive symbols have the following meanings: C = chlorosis/necrosis B = burn D = defoliation E = emergence inhibition G = growth retardation H = formative effect U = unusual pigmentation X = axillary stimulation S = albinism 6Y = abscised buds or flowers Test B Postemergence Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge ( Cyperus rotundus ) tubers, crabgrass ( Digitaria sanguinalis ), sicklepod ( Cassia obtusifolia ), jimsonweed ( Datura stramonium ), velvetleaf ( Abutilon theophrasti ), lambsquarters ( Chenopodium album ), rice ( Oryza sativa ) and teaweed ( Sida spinosa ). The second pot was planted with green foxtail ( Setaria viridis ), cocklebur ( Xantium pensylvanicum ), morningglory ( Ipomoea hederacea ), cotton ( Gossypium hirsutum ), johnsongrass ( Sorghum halepense ), barnyardgrass ( Echinochloa crusgalli ), corn ( Zea mays ), soybean ( Glycine max ) and giant foxtail ( Setaria faberi ). The third pot was planted with wheat ( Triticum aestivum ), barley ( Hordeum vulgare ), wild buckwheat ( Polgonum convolvulus L.), cheatgrass ( Bromus secalinus L.), sugarbeet ( Beta vulgaris ), wild oats ( Avena fatua ), viola ( Viola arvensis ), blackgrass ( Alopecurus myosuroides ), and rape ( Brassica napus ). The plants were grown for approximately fourteen days, then sprayed postemergence with the chemicals dissolved in a non-phytotoxic solvent. Preemergence Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge tubers, crabgrass, sicklepod, jimsonweed, velvetleaf, lambsquarters, rice and teaweed. The second pot was planted with green foxtail, cocklebur, morningglory, cotton, johnsongrass, barnyardgrass, corn, soybean and giant foxtail. The third pot was planted with wheat, barley, wild buck-wheat, cheatgrass, sugarbeet, wild oat, viola, blackgrass and rape. The three pans were sprayed preemergence with the chemicals dissolved in a non-phytotoxic solvent. Treated plants and controls were maintained in the greenhouse for 24 days, then all rated plants were compared to controls and visually rated for plant response. Response ratings are based on a scale of 0 to 100 where 0 = no effect and 100 = complete control. A dash (-) response means no test. Response ratings are contained in Table B. Test C Sixteen cm diameter Wagner pots, equipped with a stoppered drain opening near the bottom of the side wall, were partially filled with Woodstown sandy loam. About 1500 mls of water were added to each pot to bring the water level to a point 3 cm above the soil surface. Japonica and Indica rice seedlings were transplanted as described in Test E. Also, a number of barnyardgrass ( Echinochola crusgalli ) seeds were added to each pot. At the same time, seedlings or tubers of the following species were transplanted into the muddy soil: water plantain ( Alisma trivale ), Scirpus ( Scirpus mucranatus ), and Cyperus ( Cyperus difformis ). The weed species selected for this test are of economic importance in major rice-growing areas. The chemical treatments were applied directly to the paddy water after being formulated in a nonphytotoxic solvent within hours after transplanting of two additional species: water chestnuts ( Eleocharis spp. ) and arrowhead ( Sagittaria latifolia ). Shortly after treatment, the drain hole was opened to drop the water level by 2 cm. Water was then added to restore the water level to its original height. The following day the draining and refilling process was repeated. The pots were then maintained in the greenhouse. Rates of application and plant response ratings made 21 days after treatment are summarized in Table C. In the subsequent tables, LS is used as an abbreviation for leaf stage. Test D The soybeans were planted in large 25 cm-diameter pots of soil, 6 to 10 plants per pot. The other plant species were planted in 15 cm-diamter pots of soil. Carn, because of its importance as a rotational crop, was by itself in one container, 3 to 5 plants per pot. The weed species used in this test were all of major economic importance in soybean-growing regions. They were planted 3 to 4 species per pot, each confined to a separate quadrant of the soil surface. The following species were included in the screen: barnyardgrass Echinochloa crus-galli giant foxtail Setaria faberi green foxtail Setaris virdis johnsongrass Soghum halepense fall panicum Panicum dichotomiflorum purple nutsedge Cyperus rotundus signalgrass Brachiaria platyphylla crabgrass Digitaria sanguinalis velvetleaf Abutilon theophrasti jimsonweed Datura stramonium hemp sesbania Sesbania exaltata sicklepod Cassia obtusifolia cocklebur Xanthium pensylvanicum ivyleaf morningglory Ipomoea hederacea purslane Portulaca oleracea pigweed Amaranthus retroflexus lambsquarter Chenopodium album teaweed Sida spinosa bindweed Convolvulus arvensis For the post-emergence phase of the test, crop and weed species were planted two to three weeks before application so that they were present as young plants at the time of treatment. Plantings for the pre-emergence phase were made on the day before, or on the day of treatment. Approximate planting depths were: corn and soybeans - 3 to 4 cm; morningglory, cocklebur and nutsedge - 2.5 to 3 cm; velvetleaf, sicklepod and sesbania - 2 cm; all other species - 0.5 cm. The test chemicals were dissolved/suspended in a non-phytotoxic solvent in concentrations required to obtain the desirec rate of application. The solutions or suspensions were then applied as soil/foliage sprays to the young plants (post-emergence phase) and to the soil surfaces of the freshly planted containers (pre-emergence phase). Application was made utilizing an automatic spray machine at a spray volume of 500 liters per hectare. Immediately after treatment, the containers were transferred to a greenhouse and subsequently watered on a demand basis, taking care not to wet the foliage of the plants in the post-emergence phase of the test.

Claims: 1. Compounds of Formula I wherein R is H, C₁-C₃ alkyl, phenyl, SO₂NR a R b , C₁-C₂ haloalkyl, C₂-C₄ alkoxyalkyl, C₂-C₃ cyanoalkyl, C₂-C₄ alkylthioalkyl, C₂-C₄ alkylsulfinylalkyl, C₂-C₄ alkylsulfonylalkyl, CO₂C₁-C₂ alkyl, C₁-C₄ alkylcarbonyl, C₁-C₂ alkylsulfonyl, C₃-C₄ alkenyl, C₃-C₄ alkynyl or C₁-C₂ alkyl substituted with CO₂C₁-C₂ alkyl; R₁ is H or CH₃; R₂ is H, C₁-C₃ alkyl. C₁-C₃ haloalkyl, halogen, nitro. C₁-C₃ alkoxy, SO₂NR c R d , C₁-C₃ alkylthio, C₁-C₃ alkylsulfinyl, C₁-C₃ alkylsulfonyl, CN, CO₂R e , C₁-C₃ haloalkoxy, C₁-C₃ haloalkylthio, amino, C₁-C₂ alkylamino, di(C₁-C₃ alkyl)amino or C₁-C₂ alkyl substituted with C₁-C₂ alkoxy, C₁-C₂ haloalkoxy, C₁-C₂ alkylthio, C₁-C₂ haloalkylthio, CN, OH or SH; R a and R b are independently C₁-C₂ alkyl; R c is H, C₁-C₄ alkyl, C₂-C₃ cyanoalkyl, methoxy or ethoxy; R d is H, C₁-C₄ alkyl or C₃-C₄ alkenyl; or R c and R d may be taken together as -(CH₂)₃-, -(CH₂)₄-, -(CH₂)₅- or -CH₂CH₂OCH₂CH₂-; R e is C₁-C₄ alkyl, C₃-C₄ alkenyl, C₃-C₄ alkynyl, C₂-C₄ haloalkyl, C₁-C₂ cyanoalkyl, C₅-C₆ cycloalkyl, C₄-C₇ cycloalkylalkyl or C₂-C₄ alkoxyalkyl: R′ is C₁-C₅ alkyl, C₁-C₅ haloalkyl, C₁-C₅ alkyl substituted with one or two R₃ groups, C₂-C₅ alkenyl, C₂-C₅ haloalkenyl, C₃-C₅ alkenyl substituted with one or two R₃ groups, C₃-C₅ alkynyl, C₃-C₅ haloalkynyl, C₃-C₅ alkynyl substituted with one or two R₃ groups, C₃-C₅ cycloalkyl, C₃-C₅ halocycloalkyl, C₃-C₅ cycloalkyl substituted with one or two R₄ groups, C₄-C₇ cycloalkylalkyl, C₄-C₇ halocycloalkylalkyl, C₄-C₇ cycloalkylalkyl substituted with one or two R₄ groups, phenyl or benzyl; R₃ is C₁-C₃ alkoxy, C₁ -C₃ alkylthio, C₁-C₃ haloalkoxy, C₁-C₃ alkylsulfinyl, C₁-C₃ alkylsulfonyl, CN, NO₂, OH, OR₅ or di-(C₁ -C₃ alkyl)amino; R₄ is C₁-C₃ alkyl, C₁-C₃ alkoxy, C₁-C₃ haloalkoxy, CN, NO₂, OH, OR₅ or di-(C₁-C₃ alkyl)amino; R₅ is SO₂CH₃, Si(CH₃)₃, C₂-C₃ alkylcarbonyl or CO₂C₁-C₂ alkyl; E is a single bond or CH₂; W is O or S: n is O or 1: n′ is 0 or 1; X is H, C₁-C₄ alkyl, C₁-C₄ alkoxy, C₁-C₄ haloalkoxy, C₁-C₄ haloalkyl, C₁-C₄ haloalkylthio, C₁-C₄ alkylthio, halogen, C₂-C₅ alkoxyalkyl, C₂-C₅ alkoxyalkoxy, amino, C₁-C₃ alkylamino, di(C₁-C₃ alkyl)amino or C₃-C₅ cycloalkyl; Y is H, C₁-C₄ alkyl, C₁-C₄ alkoxy, C₁-C₄ haloalkoxy, C₁-C₄ haloalkylthio, C₁-C₄ alkylthio, C₂-C₅ alkoxyalkyl, C₂-C₅ alkoxyalkoxy, amino, C₁-C₃ alkylamino, di(C₁-C₃ alkyl)amino, C₃-C₄ alkenyloxy, C₃-C₄ alkynyloxy, C₂-C₅ alkylthioalkyl, C₁-C₄ haloalkyl, C₂-C₄ alkynyl, azido, cyano, C₂-C₅ alkylsulfinylalkyl, C₂-C₅ alkylsulfonylalkyl, or N(OCH₃)CH₃; m is 2 or 3; L₁ and L₂ are independently O or S; R₆ is H or C₁-C₃ alkyl; R₇ and R₈ are independently C₁-C₃ alkyl; Z is CH or N; Z₁ is CH or N; Y₁ is O or CH₂; X₁ is CH₃, OCH₃, OC₂H₅ or OCF₂H; X₂ is CH₃, C₂H₅ or CH₂CF₃; Y₂ is OCH₃, OC₂H₅, SCH₃, SC₂H₅, CH₃ or CH₂CH₃; X₃ is CH₃ or OCH₃; Y₃ is H or CH₃; X₄ is CH₃, OCH₃, OC₂H₅, CH₂OCH₃ or Cl; and Y₄ is CH₃, OCH₃, OC₂H₅ or Cl; and their agriculturally suitable salts; provided that a) when X is Cl, F, Br or I, then Z is CH and Y is OCH₃, OC₂H₅, N(OCH₃)CH₃, NHCH₃,N(CH₃)₂ or OCF₂H; b) when X or Y is C₁ haloalkoxy, then Z is CH; c) X₄ and Y₄ are not simultaneously Cl; d) when W is S, then R₁ is H, A is A-1 and Y is CH₃, OCH₃, OC₂H₅, CH₂OCH₃, C₂H₅, CF₃, SCH₃, OCH₂CH=CH₂, OCH₂C≡CH, OCH₂CH₂OCH₃, CH(OCH₃)₂ or 1,3-dioxolan-2-yl; e) when the total number of carbons of X and Y is greater than four, then the number of carbons of R must be less than or equal to two; f) when J is J-1, J-2, J-3 or J-4 then R′ is other than phenyl; g) when J is J-5, J-6 or J-7 wherein E is a single bond, then R′ is other than C₁-C₅ alkyl, C₃-C₅ alkenyl, phenyl, benzyl, cyclopentyl or C₄-C₇ cycloalkylalkyl; h) when either or both of X and Y are OCF₂H then J is J-1, J-2, J-3, J-4, J-8, J-9, J-10 or J-11; and i) when A is A-7 and Z₁ is N, then J is J-1, J-2, J-3 or J-4 and R′ is C₃-C₅ cycloalkyl; j) when the total number of carbon atoms of X and Y is greater than four, then the total number of carbon atoms of R₂ and R′ must be less than or equal to 7. 2. Compounds of Claim 1 where E is a single bond; and W is O. 3. Compounds of Claim 1 where E is CH₂; and W is O. 4. Compounds of Claim 2 where R₂ is H, C₁-C₃ alkyl, halogen, C₁-C₃ alkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, OCH₃, SO₂NHCH₃, SO₂N(CH₃)₂, S(O) n CH₃. CO₂CH₃, CO₂CH₂CH₃, OCF₂H, CH₂OCH₃ or CH₂CN; R is H, C₁-C₃ alkyl, phenyl, CH₂CF₃ or CH₂CH=CH₂; X is C₁-C₂ alkyl, C₁-C₂ alkoxy, Cl, F, Br, I, OCF₂H, CH₂F, CF₃, OCH₂CH₂F, OCH₂CHF₂, OCH₂CF₃, CH₂Cl or CH₂Br; and Y is H, C₁-C₂ alkyl, C₁-C₂ alkoxy, CH₂OCH₃, CH₂OCH₂CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂CH=CH₂, OCH₂C≡CH, OCH₂CH₂OCH₃, CH₂SCH₃, OCF₂H, OCF₂Br, SCF₂H, cyclopropyl, C≡CH or C≡CCH₃. 5. Compounds of Claim 4 where R′ is C₁-C₄ alkyl, C₁-C₃ alkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, C₂-C₄ alkoxyalkyl, C₂-C₄ alkylthioalkyl, C₂-C₄ cyanoalkyl, C₂-C₄ alkenyl, C₂-C₃ alkenyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br, C₃-C₄ alkynyl, C₃-C₅ cycloalkyl, C₃-C₅ cycloalkyl substituted with 1 to 3 halogen atoms selected from 1 to 3 Cl, 1 to 3 F or 1 Br or cyclopropylmethyl. 6. Compounds of Claim 5 where A is A-1; n is O; X is CH₃, OCH₃, OCH₂CH₃, Cl or OCF₂H; and Y is CH₃, OCH₃, C₂H₅, CH₂OCH₃, NHCH₃, CH(OCH₃)₂ or cyclopropyl. 7. Compounds of Claim 6 where R₁ is H; R₂ is H, Cl, Br, OCH₃ or CH₃; and R′ is C₁-C₃ alkyl, C₁-C₃ alkyl substituted with 1 to 3 F, C₂-C₃ alkoxyalkyl, C₂-C₃ alkylthioalkyl, C₂-C₃ cyanoalkyl, C₂-C₃ alkenyl, propargyl, C₃-C₅ cycloalkyl or cyclopropylmethyl. 8. Compounds of Claim 7 where J is J-1, J-2, J-3 or J-4. 9. Compounds of Claim 8 where R′ is C₁-C₃ alkyl substituted with 1 to 3 F, C₂-C₃ alkoxyalkyl, C₂-C₃ alkylthiolalkyl, C₂-C₃ cyanoalkyl, C₂-C₃ alkenyl, propargyl, C₃-C₅ cycloalkyl or cyclopropylmethyl. 10. A compounds of Claim 1 which is 4-(cyclopropylcarbonyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbinyl]-1-methyl-1H-pyrazole-5-sulfonamide. 11. A compound of Claim 1 which is 4-(1-oxopropyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-methyl-1H-pyrazole-5-sulfonamide. 12. A compound of Claim 1 which is 2-(cyclopropylcarbonyl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-thiophenesulfonamide. 13. An agriculturally suitable composition for controlling the growth of undesired vegetation or for use as a plant growth regulant comprising an effective amount of a compound of any of Claims 1 to 12 and at least one of the following: surfactant, solid, or liquid diluent. 14. A composition of Claim 13 comprising a compound of Claim 10, 11, or 12 or an agriculturally suitable salt thereof. 15. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of any of claims 1 to 12. 16. A method of Claim 15 wherein the compound of Claim 10, 11, or 12 is applied or an agriculturally suitable salt thereof. 17. A method for regulating the growth of plants which comprises applying to the locus of such plants an effective but substantially non-phytotoxic amount of a plant growth regulant selected from coupounds of any of Claims 1 to 12. 18. A process for the preparation of a compound of claim 1 which comprises: (a) reacting a sulfonyl isocyanate or isothiocyanate of formula JSO₂N=C=W or a phenyl carbamate or thiocarbamate of formula with an aminoheterocycle of formula (b) reacting a sulfonamide of formula JSO₂NH₂ with a heterocyclic phenyl carbamate or thiocarbamate of formula wherein J, A, R₁ and W are as defined in claim 1. 19. Compounds of formulae JSO₂N=C=W JSO₂NH₂ and wherein J and W are as defined in claim 1.

Inventors: WEXLER BARRY ARTHUR
Applicants: E.I. DU PONT DE NEMOURS AND COMPANY
Application year: 1987
Main classification: C07D403
IPC codes: C07D521, A01N47, C07D333, C07D491, C07D231, C07D403