POLYVINYLACETATE BUBBLE GUM BASE COMPOSITION

Abstract: A bubble gum base composition containing a combina­ tion of two PVA polymeric materials, namely a low molecular weight component and a medium molecular weight com­ ponent along with an acetylated monoglyceride having a saponification value above about 400.

Description: The present invention relates to bubble gum base compositions and more particularly to bubble gum compositions that exhibit improved textural properties. Bubble gum compositions generally contain a water-insoluble gum base, a water-soluble flavouring liquid and water soluble sweeteners such as sucrose and corn syrup or in sugarless gum, sorbitol, mannitol and artificial sweeteners. Also incorporated within the gum base may be plasticizers or softeners to improve film forming ability, consistency and texture of the gum. The gum base generally contains a natural rubber gum base, a synthetic rubber gum base or mixtures thereof. Several deficiencies with conventional bubble gums have existed, noteably their tendency to be sticky, exhibit bitter taste when chewed, form inconsistent films when being blown so that uniform thick bubbles are not produced and become tight when chewed. Various efforts have been made to modify the well known bubble gum base formulations, by either the deletion of certain ingredients or the inclusion of other ingredients in each case requiring adjustment of the gum base to assure the maintenance of desired textural characteristics. In U.S. Pat. No. 3,984,574 a non-tacky chewing gum is disclosed which contains as the preferred elastomer a low molecular weight polyisobutylene (molecular weight of 6,000 to 12,000) and/or a higher molecular weight polyisobutylene (molecular weight of 40,000 to 120,000). It is also disclosed that other elastomers may be employed in place of or together with the polyisobutylene, namely, polyisoprene, a copolymer of isobutylene and isoprene, or the copolymer of butadiene and styrene. In addition, polyvinyl acetate (PVA) having a molecular weight of at least 2,000 is used in amounts up to 55% along with hydrogenated vegetable oil and animal fat added at a level of 5 to 50%. Mono and diglycerides of fatty acids are also present in amounts up to 10%. Calcium carbonate is added as a mineral filler to the various compositions proposed. This disclosure is consistent with the earlier prior art disclosing the essential presence of mineral fillers as one of the ingredients needed to obtain non-stick properties in gum compositions and is silent about the use of triacetin or acetylated monoglycerides. U.S. Pat. No. 4,352,822 discloses a non-styrene butadiene (non-SBR) composition by use of polyisobutylene elastomers to make a bubble gum having film forming characteristics. The elastomer gum base used a combination of essential ingredients including glyceryl triacetate and acetylated monoglyceride as plasticizers, a polyterpine resin as an anti-tack agent, polyethylene wax and various other conventional chewing gum additives. A hydrophilic-type detackifier is disclosed to be used in amounts of 5 to 60%. This agent is alleged to absorb saliva and become slippery when the gum is chewed. These materials are used even though it is known that they are incompatible with the elastomer and elastomer solvent. An example of a detackifier is a vinyl polymer, such as polyvinyl acetate, polyvinyl butyl ester and copolymers of vinyl esters and vinyl ethers having a molecular weight from about 2,000 to about 10,000 as disclosed in USP.4352822. U.S. Pat. No. 4,357,355 is directed to a non-stick bubble gum base composition that can contain non-SBR elastomers. In particular, the non-adhesive bubble gum base composition disclosed includes a high molecular weight vinyl polymer such as polyvinyl acetate or polyvinyl alcohol, together with an emulsifier, in combination with ingredients such as an elastomer, an oleaginous plasticizer, an elastomer solvent, mineral adjuvants, fatty acids, and others. The polyvinyl acetate employed has an average molecular weight of about 38,000 to about 94,000 which material is preblended with the gum base elastomers prior to incorporation of the remaining base ingredients. USP.4357355 specifically discloses the presence of 5 to 25% by weight of mineral adjuvants, such as calcium carbonate and talc. U. S. Pat. No. 4,387,108 is directed to a non-stick chewing gum composition which contains the following ingredients: Elastomer 8-30% Oleaginous Plasticizer 9-40% Mineral Adjuvants 10-15% Non-toxic Vinyl Polymer 16-32% Emulsifier 0.5-10% Elastomer Solvent 2.5-13% The vinyl polymer disclosed in USP.4387108 has a molecular weight of from 3,000 to about 94,000 and includes PVA compounds having molecular weights of the order of 10,000 to 40,000 as well as 50,000 to 75,000. While the prior art compositions have been effective in making non-stick or tack-free bubble gums these formulations have either 1) used low molecular weight PVA in combination with other elastomers and fillers to aid film forming ability or 2) have employed high molecular weight PVA with modifying - expansion agents, such as triacetin, likewise in combination with other elastomers and fillers. The first type of formulations have not been fully effective, have not been consistent film formers and have separated into phases on storage, that is elastomer and elastomer solvent in one phase and the PVA and absorbed waxes and fats in another phase. In contrast, the second type of high molecular weight PVA formulations contained expansion agents to aid in film formation, and in particular triacetin. This plasticizer resulted in a bitter taste when the gum was chewed and upon chewing resulted in a tight chew causing inadequate bubble formation. EP-A-0066864 discloses chewing gum base formulations comprising: an elastomer, either an SBR or a non-SBR elastomer such as polyisobutylene; a plasticizer for the elastomer; a resin which may be polyvinyl acetate or a mixture of polyvinyl acetates of differing average molecular weights; and a plasticizer for the polyvinyl acetate which may be glyceryl triacetate, acetylated monoglyceride or preferably a combination thereof. A bubble gum base composition as well as a bubble gum composition have been discovered which have excellent initial and extended chew properties, form an essentially continuous film, maintain bubble shape after the bubble has been formed and resist ingredient separation. These aspects are accomplished without the use of a filler material, although fillers may be added if desired. The textural properties of the compositions according to the present invention have been unexpectedly produced from a unique combination of non-SBR elastomers, a combination of at least two different polyvinyl acetate polymeric materials and an acetylated monoglyceride which has a saponification value above 400 as defined below. According to a first aspect of the present invention there is provided a bubble gum base composition, which comprises by weight percent of the total composition: a) 0.5% to 30% non-SBR elastomer selected from synthetic gums, synthetic elastomers, natural gums, natural elastomers and mixtures thereof; b) a combination of two polyvinyl acetate polymeric materials selected from: (1) up to 14% of a polyvinyl acetate having a low molecular weight of 12,000 to 16,000; and (2) up to 35% of a polyvinyl acetate having a medium molecular weight from 35,000 to 55,000 and wherein the mole ratio of the low molecular weight polyvinyl acetate to the medium molecular weight polyvinyl acetate is from 1:2 to 1:45; c) 5% to 12% acetylated monoglyceride having a saponification value above 400; and d) the remainder of the composition being a material selected from elastomer solvents, emulsifiers, additional plasticizers, waxes and mixtures thereof. A preferred process for the preparation of a bubble gum base composition according to the first aspect of the invention comprises the steps of: i.) agitating the elastomer by mixing; ii) adding an elastomer solvent to the elastomer of step is to form a first mixture; iii) adding to the first mixture the polyvinyl acetate polymer materials to form a second mixture; and iv) adding to the second mixture the remainder of the ingredients, wherein all of the ingredients are mixed under agitation to form the bubble gum base composition. The elastomers useful in the present gum base composition include those non styrene butadiene rubber (non-SBR) elastomers normally included in gum bases. Illustrative elastomers include synthetic gums or elastomers such as polyisobutylene and isobutyleneisoprene copolymers; natural gums or elastomers such as chicle, natural rubber, jelutong, balata, guttapercha, lechi caspi, sorva or mixtures thereof. Among these, polyisobutylene, isobutylene-isoprene copolymer or mixtures thereof are preferred. A preferred elastomer is a polyisobutylene which has an average molecular weight of 45,000 to 68,000 (determined by the Flory method). Hard elastomers, that is those having a molecular weight around 1 million are not useable in this invention. The low molecular weight polyisobutylene component may be used as a single polyisobutylene material or as a combination of different polyisobutylene materials or as a combination of different polyisobutylene compounds provided each has a molecular weight within the range defined. The use of a combination of elastomers has been found beneficial to achieve a bubble gum composition having the desired elasticity and texture. The elastomer content employed is in an amount of 0.5 to 30%, and preferably 5 to 20% by weight of the bubble gum base composition. When the total amount of elastomer is below 0.5% the bubble gum base composition lacks elasticity, chewing texture, and cohesiveness whereas at amounts above 30% the composition is hard and rubbery. Polyvinyl acetate (PVA) is an essential ingredient in the bubble gum base compositions of this invention. The polyvinyl acetate used must comprise a combination of two different types of PVA. The first component is a low molecular weight material having a 12,000 to 16,000 mean average molecular weight. Such material will have a preferred viscosity of 14 to 16 seconds (ASTM D1200-82 using a Ford cup viscosity procedure). This low molecular weight component is used in amounts up to 14% by weight of the bubble gum base composition, and preferably from 5% to 12% by weight. The second PVA component is a medium molecular weight variety having a mean average molecular weight of 35,000 to 55,000. Such material will have a preferred viscosity of 35 to 55 seconds (ASTM designation D1200-82 using a Ford cup viscometer procedure.) This medium molecular weight component is used in amounts up to 35% by weight of the bubble gum base composition and preferably from 25% to 35% by weight. It has been found that the use of a blend of these two PVA components is essential to prepare a bubble gum base composition that results in a bubble gum composition that has good film forming properties and maintenance of a thick bubble shape. In addition to the required presence of these components, the components must also be present in a particular ratio. In particular the mole ratio of the low molecular weight PVA to the medium molecular weight PVA should be from 1:2 to 1:45. Lower amounts of low molecular weight component result in thicker films that are tight and unable to form effective bubbles. Higher amounts of low molecular weight component form thin bubble films that lack elasticity. As an optional embodiment of this invention, it is possible to employ small amounts of high molecular weight PVA in combination with the low and medium molecular weight components. The useable high molecular weight PVA may be used in amounts of 0 to 5% by weight of the bubble gum base composition and has a mean average molecular weight of 65,000 to 95,000. Amounts above 5% result in a tight gum chew character and an inability to form adequate bubble-films. In addition to the critical PVA constituents, it has been found essential to employ a particular mild plasticizer, namely an acetylated monoglyceride having a sponification value above approximately 400 and preferably between 430 and 470. Additionally the acetylated monoglyceride has a percent are acetylation above 90%, a hydroxyl value below 10 and a Reichert Meissl value above 150 (Food Chemical Codex(FCC) III/P508 and the revision by AOCS). Acetylated monoglycerides having lower sponification values are not effective in the formulations of this invention. Examples of unsuitable compounds include acetylated monoglycerides having sponification values of 278 to 292, 316 to 331, and 370 to 380. The use of this particular acetylated monoglyceride results in a plasticized bubble gum base composition that may be formed without use of known bitter PVA plasticizers, namely triacetin. The acetylated monoglycerides of this invention are used in amounts of 5% to 12% and preferably 7% to 10%. In addition to the foregoing essential ingredients, the bubble gum base compositions of this invention includes a variety of traditional ingredients selected from elastomer solvents, emulsifiers, plasticizers, waxes and mixtures thereof. The bubble gum base composition elastomer solvents aid in softening the rubber component. Such elastomer solvents may comprise methyl-,glycerol-or pentaerythritolesters of rosins or modified rosins, such as hydrogenated, dimerized or polymerized rosins or mixtures thereof. Examples of elastomer solvents suitable for use herein include the pentaerythritol ester of partially hydrogenated wood rosin, pentaerythritol ester of wood rosin, glycerol ester of partially dimerized rosin, glycerol ester of polymerized rosin, glycerol ester of tall oil rosin, glycerol ester of wood rosin and partially hydrogenated wood rosin and partially hydrogenated methyl ester of rosin: terpene resins including polyterpene and polymers of alpha-pinene or beta-pinene and mixtures thereof. The elastomer solvent may be employed in an amount ranging from 2% to 18% and preferably 7% to 12% by weight of the bubble gum base composition. Amounts below 2% cause unacceptable chew characteristics. Amounts above 18% cause a soft product to be formed which results in a product which sticks to the face. Useful emulsifiers which may be optionally included in the compositions this invention include glyceryl monostearate, lecithin, fatty acid monoglycerides, diglycerides, propylene glycol monostearate and mixtures thereof. Glyceryl monostearate is most preferred. When emulsifiers are absent, the composition has poor stability and less acceptable texture relative to the compositions of the invention including an emulsifier. It is believed that the emulsifier aids in bringing the normally immiscible constituents together in such a way that they form a single finely dispersed stable system. The emulsifier improves hydrophilic character. The emulsifier is employed in amounts of 2% to 10% and preferably 4% to 8% by weight of the base. It has been found that some emulsifiers conventionally used result in the formation of unacceptable base formulations. Exemplary non-useable emulsifiers include glyceryl triacetate. The bubble gum base composition preferably employs a wax material. Waxes have been found to soften the rubber elastomer mixture and improve elasticity of the chew character. The waxes employed are preferably micro-crystalline wax, natural wax, petroleum wax, paraffin wax and mixtures thereof. Useful amounts are from 5% to 18% by weight and preferably from 7% to 12% by weight of the gum base composition. The waxes employed herein preferably have a melting point above approximately 77°C (170°F) in order to obtain a consistent chew property. Use of waxes having lower melting points increases tackiness. A variety of traditional ingredients such as additional plasticizers or softeners may optionally be added. Such materials are optional and not essential in the present formulation. Such materials include hydrogenated vegetable oils, lanolin, stearic acid, sodium stearate, potassium stearate, glycerine and the like and mixtures thereof. Such materials when incorporated into the gum base obtain a variety of desirable textures and consistency properties. These individual materials are generally employed in amounts of 6% to 20% by weight and preferably in amounts of from 9% to 17% by weight of the bubble gum base composition. Because of the low molecular weight of these compounds, they are able to penetrate the fundamental structure of the base making it plastic and less viscous. A unique feature of the compositions according to the present invention is their ability to form cohesive products without the use of filler-texturizing agents. Such agents have been described in the prior art as necessary to impart good lubricant and flavour release properties to non-stick gum base products. Because of applicants unique combination of ingredients the compositions according to the invention are prepared in the essential absence of filler-texturizing agents. The ability to prepare a PVA containing bubble gum without the essential presence of a filler is unexpected. Prior PVA formulations required the presence of a filler to lend cohesiveness to the base to avoid phase separation of the elastomer/elastomer solvent from the PVA and absorbed oils and waxes. In the absence of the filler this separation has been noted to occur almost immediately upon completion of preparing the normal base compositions. Once the bubble gum base composition according to the present invention is prepared and is ready for blending into a bubble gum composition, the optional filler-texturizing agent may be added in an amount up to 40% by weight. The manner in which the constituents of the bubble gum base compositions are blended is not critical and is performed using standard techniques and equipment known to those skilled in the art. In a typical embodiment the elastomer composition is agitated with an elastomer solvent and/or plasticizer(s), and/or emulsifiers for a period of about 1 minute to about 30 minutes. Once initial mixing is complete the PVA components are blended into the first mixture. While it is not essential it is preferred to add the medium molecular weight PVA prior to addition of the low molecular weight component. In this manner uniform blending can be achieved without the creation of isolated pockets of PVA within the elastomer. The remaining bubble gum base composition constituents may now be added in bulk, incrementally or stepwise while the resulting mixture is blended for a further equivalent period of time. The present bubble gum base composition may be formulated into a variety of bubble gum compositions, ie. products, utilizing standard procedures and equipment. A bubble gum composition may be prepared by combining conventional ingredients such as sweeteners, flavours, colourants and the like, with the bubble gum base composition. The amount of bubble gum base composition employed will vary depending on such factors as the type of bubble gum base composition used, consistency desired and other components used to make the final bubble gum composition product. In general, amounts from 5% to 45% by weight of the final bubble gum composition are acceptable with preferred amounts of 15% to 25% by weight being useable. The sweetening agent may be selected from a wide range of materials including water-soluble agents, water-soluble artificial sweeteners, and dipeptide based sweeteners, including mixtures thereof. Without being limited to particular sweeteners, representative illustrations encompass: A. Water-soluble sweetening agents such as monosaccharides, disaccharides, and polysaccharides such as xylose, ribose, glucose, mannose, galactose, fructose, dextrose, sucrose, maltose, partially hydrolyzed starch, or corn syrup solids and sugar alcohols such as sorbitol, xylitol, mannitol and mixtures thereof. B. Water-soluble artificial sweeteners such as the soluble saccharin salts, i.e., sodium or calcium saccharin salts, cyclamate salts, acesulfam-K and the like, and the free acid form of saccharin. C. Dipeptide based sweeteners such as L-aspartyl-L-phenylalanine methyl ester and materials described in U.S. Pat. No. 3,492,131 and the like. In general, the amount of sweetener will vary with the desired amount of sweeteners selected for a particular bubble gum composition. This amount will normally be 0.001% to 90% by weight when using an easily extractable sweetener. The water-soluble sweeteners described in category A above, are preferably used in amounts of 25% to 75% by weight, and most preferably from 50% to 65% by weight of the final bubble gum composition. In contrast, the artificial sweetener described in categories B and C are used in amounts of 0.005% to 5.0% and most preferably 0.05% to 2.5% by weight of the final bubble gum composition. These amounts are ordinarily necessary to achieve a desired level of sweetness independent from the flavour level achieved from flavour oils. Flavouring agents well known to the bubble gum art may be added to the bubble gum compositions of the present invention. These flavouring agents may be chosen from synthetic flavouring liquids and/or oils derived from plants leaves, flowers, fruits and so forth, and combinations thereof. Representative flavouring liquids include: spearmint oil, cinnamon oil, oil of wintergreen (methylsalicylate) and peppermint oils. Also useful are artificial, natural or synthetic fruit flavours such as citrus oil including lemon, orange, grape, lime and grapefruit and fruit essences including apple, strawberry, cherry, pineapple and so forth. The amount of flavouring agent employed is normally a matter of preference subject to such factors as flavour type, base type and strength desired. In general, amounts of 0.05% to 2.0% by weight of the final bubble gum composition are usable with amounts of 0.8% to 1.5% being preferred. The bubble gum compositions are prepared by conventional methods. An illustrative process involves first melting the bubble gum base composition at a temperature from 70° to 120°C and mixing the bubble gum base composition in a kettle with a liquid softener and/or a emulsifier for 2 to 8 minutes. To this mixture 2/3 to 3/4 of the sugar ingredients and colours are added and mixing is continued for 1 to 4 minutes. To this mixture the remaining sugar ingredients are added and while mixing is continued, the flavouring agent is slowly added. Mixing is maintained for 1 to 4 minutes. To this mixture a humectant can be added and mixing is continued for 1 to 4 minutes. The bubble gum compositioned is then discharged from the kettle and formed into its desired shape such as strips, slabs, chunks, ball ropes and/or centre-filled. The following examples are given to illustrate the invention. All percentages given throughout the specification are based upon weight unless otherwise indicated, percentages of bubble gum base composition components are by weight of the bubble gum base composition, whereas bubble gum composition components are by weight of the final bubble gum composition. EXAMPLE 1 Inventive Runs I, II and III Comparative Run A This example demonstrates the formation of bubble gum base compositions, three of which are according to the invention and one which is not (comparative Run A). To a preheated kettle is added an elastomer which is mixed for 3 minutes under high shear until the mass reaches a temperature of 88°C (190°F). To this mass is added an elastomer solvent and mixing is continued for 5 minutes. To this first mixture is added in sequence while mixing is the remaining ingredients including a medium molecular weight PVA, a low molecular weight PVA, waxes, additional plasticizer and an acetylated monoglyceride having a sponification value above 400. The final mass is blended for about 30 minutes. The final temperature should range from 71°C to 99°C (160°F to 210°F). The molten mass is discharged from the kettle and put into coated pans. The bubble gum base composition is allowed to cool and harden before depanning. The ingredients used are recited in Table I. EXAMPLE 2 INVENTIVE RUNS IV, V AND VI COMPARATIVE RUN B This example demonstrates the formation of bubble gum compositions according to this invention using the bubble gum base compositions of Example 1. Bubble gum compositions are prepared with the ingredients recited in Table 1. The bubble gum compositions were prepared by first melting the bubble gum base compositions at a temperature from 70°C to 100°C and mixing the bubble gum base composition in a kettle with an emulsifier (lecithin) and corn syrup. Mixing is continued for approximately 2 minutes to obtain a homogenous mixture. To this mixture is added the remaining ingredients of Table II and mixing is continued for approximately 7 minutes. The bubble gum compositions are discharged from the kettle and formed into chunks and conditioned to room temperature. In order to evaluate the bubble gum compositions they were subjected to test panel studies with multiple panelists. The results demonstrated that the bubble gum compositions according to this invention exhibited better bubble formation, non-stick-to-face properties, enhanced chew character and flavour taste (that is lack of bitterness) than the comparative composition (run B). EXAMPLE 3 INVENTIVE RUNS VII AND VIII COMPARATIVE RUNS C AND D. This example demonstrates the formation of bubble gum base compositions using the procedure of Example 1 using different amounts of PVA. The bubble gum base compositions are set forth in Table III and were made into bubble gum compositions using the method of Example 2. Comparative Run C produced a product having a tight rubbery chew which exhibited bitterness upon chewing. Comparative Run D produced a thin film that was unable to form a good bubble. Inventive Runs VII and VIII exhibited good bubble formation, no tightness and no bitterness when chewed. EXAMPLE 4 COMPARATIVE RUNS E, F AND G. This example demonstrates the formation of bubble gum base compositions using the procedure of Example 1 using acetylated monoglycerides having different sponification values. The bubble gum base compositions are set forth in Table IV and were made into bubble gum using the method of Example 2. All of these Comparative Runs formed products that were unacceptable. All had tight chew and were unable to form a bubble.

Claims: A bubble gum composition, which comprises in weight percent of the total composition: a) a 0.5 to 30% non-styrene butadiene rubber (non-SBR) elastomer selected from synthetic gums, synthetic elastomers, natural gums, natural elastomers and mixtures thereof; b) a combination of two polyvinyl acetate (PVA) polymeric materials selected from 1) up to 14% of a polyvinyl acetate having a low molecular weight of 12,000 to 16,000, and 2) up to 35% of a polyvinyl acetate having a medium molecular weight of 35,000 to 55,000, wherein the mole ratio of the low molecular weight polyvinyl acetate to the medium molecular weight polyvinyl acetate is from 1:2 to 1:45; c) 5% to 12% acetylated monoglyceride having a saponification value above 400; and d) the remainder of the composition being a material selected from elastomer solvents, emulsifiers, additional plasticizers, softeners, waxes and mixtures thereof. A bubble gum base composition according to claim 1, wherein the elastomer is present in an amount of 5% to 20%. A bubble gum base composition according to claim 1 or 2, wherein the low molecular weight PVA is present in an amount of 5% to 12%. A bubble gum base composition according to any one of claims 1 to 3, wherein the medium molecular weight PVA is present in an amount of 25% to 35%. A bubble gum base composition according to any preceding claim, which further includes from 0 to 5% of a polyvinyl acetate having a high molecular weight in the range of 65,000 to 95,000. A bubble gum base composition according to any preceding claim 1 to 5, wherein the acetylated monoglyceride is present in an amount of 7% to 10%. A bubble gum base composition according to any preceding claim, wherein the acetylated monoglyceride has a saponification value between 430 and 470. A bubble gum base composition according to any preceding claim, which is provided with an elastomer solvent present in an amount of 2% to 18% and is selected from pentaerythritol ester of partially hydrogenated wood resin, glycerol ester of partially dimerized rosin, glycerol ester of polymerized rosin, glycerol ester of tall oil rosin, glycerol ester of wood resin and partially hydrogenated wood rosin and partially hydrogenated methyl ester of rosin; terpene resins including polyterpene and polymers of alphapinene or beta-pinene and mixtures thereof. A bubble gum base composition according to claim 8, wherein the elastomer solvent is present in an amount of 7% to 12%. A bubble gum base composition according to any preceding claim, which is provided with an emulsifier present in an amount of 2% to 10% and selected from glycerol monostearate, lecithin, fatty acid monoglycerides, diglycerides, propylene glycol monostearate and mixtures thereof. A bubble gum base composition according to claim 10, wherein the emulsifier is present in an amount of 4% to 8%. A bubble gum base composition according to any preceding claim, which is provided with a wax which has a melting point above 77°C (170°F), is present in an amount of 5% to 18% and is selected from microcrystalline wax, natural wax, petroleum wax, paraffin wax and mixtures thereof. A bubble gum base composition according to claim 12, wherein the wax is present in an amount of 7% to 12%. A bubble gum base composition according to any one of claims 1 to 13, which is provided with an additional plasticizer which is present in an amount of 6% to 20% and is selected from hydrogenated vegetable oils, partially hydrogenated vegetable oils, hydrogenated animal fats, partially hydrogenated animal fats, cocoa butter and mixtures thereof. A bubble gum base composition according to claim 14, wherein the vegetable oils are selected from soybean oil, cottonseed oil, corn oil, peanut oil, palm oil and mixtures thereof, the animal fats are selected from tallow, lard and mixtures thereof. A bubble gum base composition according to claim 14 or 15, wherein the additional plasticizer is present in an amount of 9% to 17%. A bubble gum composition containing a bubble gum base composition according to any one of claims 1 to 16. A bubble gum composition according to claim 17, which further contains a flavouring agent. A bubble gum composition according to claim 18, wherein the flavouring agent is present in an amount of 0.05% to 2.0% by weight. A bubble gum composition according to claim 18 or 19, wherein the flavouring agent is selected from natural or synthetic flavouring agents. A bubble gum composition according to claim 20, wherein the flavouring agents is selected from peppermint oil, spearmint oil, cinnamon oil, oil of wintergreen, bubble flavour, fruit flavours and mixtures thereof. A bubble gum composition according to any one of claims 17 to 21, wherein the bubble gum base composition is present in an amount of 15% to 45% by weight. A bubble gum composition according to any one of claims 17 to 22, which additionally contains a material selected from natural or synthetic gums, sweetening agents, colouring agents and mixtures thereof. A bubble gum composition according to claim 23, wherein the sweetening agent is selected from water-soluble sweetening agents, water-soluble artificial sweeteners, dipeptide based sweeteners and mixtures thereof. A process for preparing a bubble gum base composition according to any one of claims 1 to 16, which comprises admixing the ingredients a) to d). A process for preparing a bubble gum composition according to claim 25 which process comprises the steps of: i) agitating the elastomer by mixing; ii) adding an elastomer solvent to the elastomer of step i) to form a first mixture; iii) adding to the first mixture the polyvinyl acetate polymer materials to form a second mixture; and iv) adding to the second mixture the remainder of the ingredients, wherein all of the ingredients are mixed under agitation to form the bubble gum base composition. A process according to claim 26, wherein the medium molecular weight polyvinyl acetate is mixed into the first mixture prior to addition of the lower molecular weight polyvinyl acetate.

Inventors: CHERUKURI, SUBRAMAN R., MANSUKHANI, GUL
Applicants: WARNER-LAMBERT COMPANY
Application year: 1987
Main classification: A23G3
IPC codes: A23G4