SURFACTANT COMPOSITION HAVING IMPROVED FUNCTIONS

Abstract: The surfactant composition of the present inven­ tion, which comprises mono acyl glycero phospholipid(s) and one or more compounds selected from the group con­ sisting of polyglycerol fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters and gly­ cerol fatty acid monoesters as essential components, exhibits excellent acid- and salt-resisrances, perme­ ability, emulsification and dispersion capabilities and hydrophilicity. Further it is highly safe and can be appropriately applied to various products, in particu­ lar, food, cosmetics and pharmaceuticals.

Description: This invention relates to a surfactant composition for various products including food, cosmetics and pharmaceuticals. Polyglycerol fatty acids esters, which exhibit excellent biodegradability and are safe products widely employed in, for example, food and cosmetics as surfactants having various functions including emulsification, dispersion, solubilization, wetting and foaming abilities, since they can show surface activities of a wide range of hydrophile-lipophile balance (HLB) depending on the degree of polymerization and the type and number of the binding fatty acids. Among these polyglycerol fatty acid esters. however, hydrophilic ones having an HLB of 13 or above do not result in stable emulsions of edible fats and oils as such and are thus unsuitable although they are per se soluble in acidic aqueous solutions or aqueous solutions of inorganic salts. On the other hand, those having an HLB of 9 to 11 which are generally used for emulsifying, for example. edible fats and oils and liquid paraffin are unstable in acidic aqueous solutions and aqueous solutions of inorganic salts. Further polyglycerol fatty acid esters having an HLB of less than 9 are insoluble in acidic aqueous solutions and aqueous solutions of inorganic salts such as sodium chloride and inavailable in emulsifying edible fats and oils as such. The wetting, solubilization and dispersion capabilities, which are important properties of surfactants, of polyglycerol fatty acid esters are lower even in the case of hydrophilic ones than for other surfactants. For example, the permeation capabilities of same are lower than those of sucrose fatty acid esters and thus, much lower than those of polyoxyethylene alkylphenol ethers. Sucrose fatty acid esters, which exhibit an excellent biodegradability and are safe, are widely employed in, for example, food and cosmetics as surfactants having various functions such as emulsification dispersion, solubilization, permeation and foaming abilities since they can show surface activities of a wide range of HLB depending on the type and number of the fatty acids bound to sucrose. However sucrose fatty acid esters, which are nonionic surfactants, are readily precipitated in acidic aqueous solutions and aqueous solutions of inorganic salts. which lowers the surface activities thereof. Although sucrose fatty acid esters containing monoesters in an amount of almost 100%, in particular monoesters of short-chain or unsaturated fatty acids, are relatively stable in acidic aqueous solutions or aqueous solutions of inorganic salts, they are extremely expensive and can not be employed in practice. Thus most of the commercially available sucrose fatty acid esters have the disadvantage that they almost loose the surface activities at a pH value of 4 to 6 or at a common salt concentration of 1%. There are many aqueous solutions of, for example, food products having pH values or common salt concentrations within the ranges described above. Therefore the above disadvantage of sucrose fatty acid esters strictly limits their application. In addition, the permeation capability, i.e., wetting power, which is one of the surface activities, of a sucrose fatty acid ester having a high HLB is insufficient when compared with that of, for example, a polyoxyethylene alkylphenol ether. Sorbitan fatty acid esters are esters of one or more compounds selected from sorbitol, sorbitan and sorbide, the latter two being intramolecularly dehydrated products of the former, with a fatty acid. They can exhibit surface activities of a relatively lipophilic HLB depending on the type and number of the binding fatty acids. They are widely used in various products including food and cosmetics as surfactants, mainly as emulsifiers, which show excellent biodegradability and are approved as safe. However, sorbitan fatty acid esters generally show poor solubilities in water. In particular, they are apt to be readily precipitated in acidic aqueous solutions of, for example, a pH value of 5 to 6 or aqueous solutions of inorganic salts such as sodium chloride at a concentration of, for example, 1%, which lowers their surface activities. There are many aqueous solutions of, for example, food products having pH values or common salt concentrations within the ranges as defined above. Thus the above disadvantage of sorbitan fatty acid esters strictly limits their application. In addition, the wetting and dispersion capabilities, which are important surface activities, of sorbitan fatty acid esters are very poor. Glycerol fatty acid monoesters, which are natural surfactants present in living organisms, are produced through transesterification between fats or oils and glycerol or reactions between fatty acids and glycerol. Since these glycerol monoesters have simple structures, they can be readily purified to a high purity by distillation. Thus they are useful surfactants and available at a relatively low price. However, the glycerol monoesters are highly lipophilic and insoluble in water. Those containing a large amount of impurities including fatty acid soaps can be dispersed in hot water but cause phase separation at room temperature, which strictly limits their application. FR-A-2028018 discloses an emulsifying agent comprising 50 to 90 parts by weight of a mixture of monoglycerides and diglycerides of fatty acids having 16 to 22 carbon atoms, wherein said mixture contains 40 to 90 parts by weight of monoglycerides and has an iodine number of at most 10, in admixture with 50 to 10 parts by weight of partially hydrolysed phosphatides containing 2 to 15% by weight of lysophosphatides. It is the object of the present invention to provide a surfactant composition having improved properties including acid - and salt - resistances, wetting, emulsification and dispersion capabilities and hydrophilicity. Said object is achieved by a surfactant composition which comprises (A) partially deacylated glycerophospholipid(s) comprising at least 30% by weight, based on the total phosphatide content, of monoacyglycerophospholipid(s) and (B) one or more compounds selected from the group consisting of polyglycerol fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters and glycerol fatty acid monoesters, wherein the weight ratio of (B) to (A) is 10/90 to 95/5. Figure 1 shows the results of the surface activity test of Example 31, while Figure 2 shows the results of the surface activity test of Example 36. The monoacylglycerophospholipids, which are the first essential component (A) of the composition of the present invention, are preferably those having eight or more carbon atoms. In each monoacylglyoerophospholipid, the acyl group may be located in either α or β-position. As monoacylglycerophospholipids, natural ones in L-form and synthetic racemates may be used. It is known that natural monoacylglycerophospholipids are present in living organisms together with acylglycerophospholipids in, for example, lipids of cereals such as soybean, rapeseed and wheat and animal lipids. Monoacylglycerophospholipids may be further produced by hydrolyzing diacylglycero phospholipids present in animal lipids such as yolk or vegetable lipids such as soybean with phospholipase A-2 obtained from swine pancreatic juice of snake venom or phospholipase A-1 obtained from bacteria; removing the fatty acids thus formed with, for example, acetone; and purifying the residue by, for example, silica gel chromatography, if required (cf. Japanese Patent-Laid Open No. 13263/1971, No. 136966/1977 and No. 51853/1983). The monoacylglycerophospholipid thus obtained may be hydrogenated in an appropriate solvent in the presence of a catalyst such as nickel to thereby give a surfactant having a higher oxidation stability. It is described in J. Amer. Oil Chem. Soc., 886 - 888, Oct. 1981 that monoacylglycerophospholipids of various compositions can be obtained by changing the conditions under which the phospholipase A-2 is employed. Alternatively, monoaclylglycerophospholipids can be obtained from materials prepared by fractionating diacylglycerophospolipids by the use of a solvent such as ethyl alcohol, and/or water containing ethyl alcohol. Further methods for preparing monoacylglycerophospholipids such as the one for preparing phosphatidylcholine from yolk (cf. J. Biol. Chem., 188 , 471 - 476 (1951) as well as those for preparing phosphatidylcholine as described in Japanese Patent Publication No. 16/1985, No. 42655/1984, No. 123496/1982 and No. 23997/1981 can be applied to the present invention. Every natural monoacylglycerophospholipid mentioned above has a levo-rotatory optical activity and is safe when orally administered to animals (cf. J. Sci. Food and Agr., 32 , 451 - 458). The phospholipids as used in the present invention can be analyzed by, for example, thin layer chromatography, TLC - FID Analyser (Iatro - scan method) or high performance liquid chromatography. It is preferable that the monoacylglycerophospholipids (a) to be used in the present invention, which can be obtained by the methods as described above, substantially comprise monoacylphosphatidylcholine. The monoacylglycerophospholipids (a) may further contain monoacylphosphatidylethanolamine and a small amount of one or more monoacylphoslpholipids selected from monoacylphosphatidylinositol, monoacrylphosphatidic acid and monoacylphosphatidylserine. The monoacylglycerophospholipids (a) prepared from natural materials often contain diacylphosphatides (b) depending on the employed preparation processes. The desired effects can be achieved under strongly acidic conditions or at a high concentration of a salt as long as the content of the monoacylglycerophospholipids (a) is 30% by weight or above based on the total phospholipids, i.e., (a) + (b). However it is preferable that the content of the monoacylglycerophospholipids (a) is 40% by weight or above when the mono acyl glycero phospholipids contain phosphatidylcholine in a low amount, for example, 60% by weight or below. Now the fatty acid esters, which are another essential component of the composition of the present invention, will be described. As polyglycerol fatty acid esters which are one essential component of the composition of the present invention, mono-, di- or polyesters of polyglycerols having a degree of polymerization of 4 to 12 with saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms and mixtures thereof are preferable. Polyglycerol fatty acid esters comprising fatty acids having 11 or less carbon atoms exhibit a bitter taste and only limited effects by the addition of the monoacylglycerophospholipids of the present invention, e.g., the emulsification and dispersion capabilities can be achieved thereby. On the other hand, those comprising fatty acids having 23 or more carbon atoms are in general hardly available. A degree of polymerization of polyglycerol of less than 4 results in only insufficient hydrophilicity, while one of more than 12 is undesirable since a complicated polymerization is liable to occur in each molecule. Examples of the sucrose fatty acid esters constituting the second essential component of the composition of the present invention are mono-, di- or polyesters of saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms with sucrose and mixtures thereof. Sucrose fatty acid esters comprising fatty acids having 11 or less carbon atoms exhibit a bitter taste and only limited effects by the addition of the monoacylglycerophospholipids can be achieved. On the other hand, those comprising fatty acids having 23 or more carbon atoms are in general hardly available. Examples of the sorbitan fatty acid esters constituting the second essential component of the composition of the present invention are mono-, di- or polyesters of saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms with sorbitol, sorbitan and sorbide and mixtures thereof. Only limited emulsification effects by the addition of the monoacylglycerophospholipids can be achieved by the use of sorbitan fatty acid esters comprising fatty acids having 11 or less carbon atoms. On the other hand, those comprising fatty acids having 23 or more carbon atoms are in general hardly available. Examples of the glycerol fatty acid monoesters constituting the second essential component of the composition of the present invention are monoesters of saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms with glycerol and mixtures mainly comprising the monoesters and diesters. Glycerol fatty acid monoesters comprising fatty acids having 11 or less carbon atoms give a bitter taste and an insufficient emulsifying ability and thus hardly contribute to an improvement of the properties of the composition. On the other hand, those comprising fatty acids having 23 or more carbon atoms are in general hardly available. A glycerol fatty acid monoester comprising both monoesters and diesters preferably contain (70% by weight or more, still preferably 80% by weight or more, of the monoester. It is desirable to use a distilled product. The composition of the present invention comprises polyglycerol fatty acid ester(s), sucrose fatty acid ester(s), sorbitan fatty acid ester(s) and glycerol fatty acid monoesters and partially deacylated glycerophospholipid(s) (A) in a ratio of 10/90 to 95/5 on a weight basis. When it comprises component (A) in an amount of 5% or less, only limited effects of the present invention are achieved. On the other hand, a content of component (A) of 90% or above makes the composition undesirably expensive. When the composition of the invention comprises polyglycerol fatty acid ester(s) of an HLB of 11 or above, sufficient effects can be achieved even when the content of component (A) is relatively low. On the contrary, when polyglycerol fatty acid ester(s) have a low HLB and component (A) is contained in a proportion of 5 to 10%, the effects of the present invention can be observed in a relatively dilute aqueous solution of sodium chloride or at only a relatively high pH value in acidic solution. Therefore, it preferable that component (A) is contained in a proportion of 10% or above. When the composition of the present invention comprises polyglycerol fatty acid ester(s), the effects of the invention show little difference at contents of mono acyl glycero phospholipid(s) of approximately 60% or above. Thus it is generally preferable that the monoacylglycerophospholipid(s) are contained in a ratio of 40/60 to 90/10 (this ratio shows polyglycero fatty acid ester/monoacylglycerophospholipid), still preferably approximately 40/60 to 95/5 in the case of polyglycerol fatty acid ester having a high HLB. Generally speaking, the required amount of monoacylglycerophospholipid(s) decreases with an increase of the HLB of polyglycerol fatty acid ester(s). When the composition of the present invention comprises sucrose fatty acid ester(s), the effects of the present invention can be observed in a relatively dilute aqueous solution of common salt or at only a relatively high pH value in acidic solution at a content of component (A) of 5 to 10%. Therefore it is preferable that component (A) is contained in an amount of 10% or above. Similar to the case of polyglycerol fatty acid esters, the effects of the present invention show little difference at contents of monoacylglycerophospholipid(s) of approximately 60% or above in the case of sucrose fatty acid esters. Thus it is generally preferable the monoacylglycerophospholid(s) are contained in a ratio of approximately 40/60 to 90/10. Generally speaking, the required amount of monoacylglycerophospholipid(s) decreases with an increase of the HLB of sucrose fatty acid ester(s). When the composition of the present invention comprises sorbitan fatty acid ester(s), the effects of the present invention can be observed in a relatively dilute aqueous solution of sodium chloride or at only a relatively high pH value in acidic solution at a content of component (A) of 5 to 20%. Thus it is preferable that component (A) is contained in a proportion of 20% or above. Similar to the former cases, the effects of the present invention show little difference at contents of monoacylglycerophospholipid(s) of approximately 60% or above in the case of sorbitan fatty acid esters. Thus it is generally preferable that the monoacylglycerophospholipid(s) are contained in a ratio of approximately 40/60 to 80/20. Generally speaking, the required amount of monoacylglycerophospholipid(s) decreases with an increase of the HLB of sorbitan fatty acid ester(s). When the composition of the present invention comprises glycerol fatty acid monoester(s), the effects of the present invention can be observed in a relatively dilute aqueous solution of common salt or at a relatively high PH value in acidic solution at a content of component (A) of 5 to 10%. Thus It is preferable that component A is contained in a proportion of 10% or above. The ratio varies depending on the purpose. For example, when the composition is used for water-in-oil type and oil-in-water type emulsifications, ratios of approximately 80/20 (glycerol fatty acid monoester/component (A) to 90/10 and approximately 10/90 to 80/20 are preferable, respectively. When it is to be used under severe conditions such as at pH 3 or in a 10% by weight saline solution. a ratio of 10/90 to 70/30 is preferable. Under particularly severe conditions, for example, when corn oil is emulsified in soy sauce. a ratio of 10/90 to 50/50 is preferable. The composition of the present invention can be obtained by, for example, the following methods. 1) Component (A) and each fatty acid ester are formulated into an aqueous solution or an aqueous paste. 2) Each aqueous solution or aqueous paste as prepared above in 1) is further concentrated in vacuo to give a semisolid or solid products. 3) When both the component (A) and the fatty acid ester are solid, they are formulated into powders and mixed together. 4) Component (A) and each fatty acid ester are dissolved in a solvent such as an alcohol or hexane or a mixture thereof. 5) The solution obtained above in 4) is dried to give a powder or a paste. 6) In the case of some polyglycerol fatty acid esters and glycerol fatty acid monoesters, these materials are heated together with component (A) under stirring at the melting point or above to thereby melt these materials. The composition of the present invention may further contain other surfactants. It is preferable that the composition of the present invention also contains soluble proteins, peptides and polysaccharides since these materials enhance the emulsification, solubilization and dispersion capabilities of the former. The surfactant composition of the present invention can be applied to various products containing inorganic salts and/or organic acids. for example. soy sauce, worcester sauce, pickled vegetables such as salted ones and those pickled in soy sauce, fruit juices, fermented milk products such as yoghurt, dressing, mayonnaise, tsukudani, processed animal and fish meats and cosmetics. It is effective in emulsifying oily materials; solubilizing oily colorants, oil soluble vitamins and antioxidants such as BHA (a mixture of 2-tert-butyl-4-hydroxyanisole and 3-tert-butyl-4-hydroxyanisole) and BHT (2,6-di-tert-butyl-p-cresol); and dispersing cocoa powder, powdery precooked foods, spices such as powdery mustard or horseradish, fungicides such as butyl p-hydroxybenzoate and various powdery additives. Alternately the composition of the present invention may be dissolved in water or alcohols and the obtained solution is allowed to adhere to particles to be dispersed by immersing or spraying to thereby coat the particles with the solution, thus accelerating the dispersion of the powder. The following examples illustrate the present invention. Preparation of monoacylglycerophopholipid: Now the monoacylglycerophospholipids to be used in the present invention will be described in detail. Monoacylglycerophospholid A : Phospholipids containing 70% of diacylphosphatidylcholine are obtained from commercially available soybean phospholipids through precipitation with acetone and fractionation with aqueous ethanol. Then phospholipase A obtained from swine pancreatic juice (Lecitase 10-L,® mfd. by Novo) is added. The fatty acids thus formed are removed by the use of acetone and the residue is fractionated with an alcohol. After further fractionating by the use of a silicic acid column and an alcohol, the title material, which is a phosphatide comprising 94% of lysophosphatidylcholine and 3% of lysophosphatidylethanolamine, is obtained. Monoacylglycerophospholipid B : Starting from commercially available soybean phospholipids, the procedure as described in regard to monoacylglycerophospholipid A is followed to thereby give the title material which is a phosphatide comprising 95% of lysophosphatidylcholine and 2% of lysophosphatidylethanolamine. Monoacylglycerophospholipid C : Phospholipids containing 70% of diacylphosphatidylcholine are obtained by fractionating soybean phospholipids. Then Lecitase 10-L® is added and the fatty acids thus formed are removed. The residue is fractionated with an alcohol and purified to give the title material which is a phosphatide mainly comprising 56% of lysophosphatidylcholine and 13% of lyso phosphatidylethanolamine and containing 72% of monoacylglycerophospholipids in total. Monoacylglycerophospholipid D : Lecitase 10-L® is added to defatted phospholipids obtained by precipitating commercially available soybean phospholipids by the use of acetone. Then a phosphatide is extracted with a mixture of isopropyl alcohol and hexane and treated with acetone to thereby defat same. Then it is extracted with an alcohol to give the title material which is a phosphatide comprising 52% of lysophosphatidylcholine and 11% of lysophosphatidylethanolamine and containing 65% of monoacylglycerophospholipids in total. Monoacylglycerophospholipid E : Defatted phospholipids are obtained from soybean phospholipids through precipitation with acetone. Then Lecitase 10-L® is added and a phosphatide is extracted with a mixture of isopropyl alcohol and hexane and treated with acetone to thereby defat same. After extracting with an alcohol, the title material, which is a phosphatide mainly comprising 52% of lysophosphatidylcholine and 14% of lysophosphatidylethanolamine and containing 69% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipid F : Defatted phospholipids are obtained from soybean phospholipids through precipitation with acetone. Then Lecitase 10-L® is added thereto and a phosphatide is extracted with a mixture of isopropyl alcohol and hexane and treated with acetone to thereby defat same. After extracting with an alcohol, the title material, which is a phosphatide mainly comprising 45% of lyso phosphatidylcholine and 9% of lysophosphatidylethanolamine and containing 56% of monoacylglycerophospholipids in total, is obtained. Mono acyl glycero phospholipid G : Lecitase 10-L® is reacted with Lecinol 10-E® (mfd. by Nippon Surfactant Co., Ltd.; a hydrogenated phosphatide containing 81% of phosphatidylcholine and 9% of phosphatidylethanolamine and having an iodine value of 7) and the reaction mixture is treated in the same manner as described in the case of monoacylglycerophosphatide D. Thus the title material, which is a phosphatide mainly comprising 69% of lysophosphatidylcholine and 8% of lysophosphatidylethanolamine and containing 80% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipid H: Defatted phospholipids are obtained from soybean phospholipids through precipitation with acetone. Then Lecitase 10-L® is added thereto and a phosphatide is extracted with a mixture of isopropyl alcohol and hexane. After removing the solvent from the extract, fatty acids are removed therefrom by treating with acetone and the residue is further extracted with an alcohol. Thus the title material, which is a phosphatide mainly comprising 48% of lysophosphatidylcholine and 11% of lysophosphatidylethanolamine and containing 62% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipid J: Lecitase 10-L® is reacted with Lecinol 10 E® (mfd. by Nippon Surfactant Co., Ltd.; a hydrogenated phosphatide containing 81% of phosphatidylcholine and 9% of phosphatidylethanolamine and having an iodine value of 7) and the reaction mixture is treated in the same manner as described with regard to monoacylglycerophospholipid H. Thus the title material, which is a phosphatide mainly comprising 53% of lysophosphatidylcholine and 5% of lysophosphatidylethanolamine and containing 61% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipid K: Epicuron 200®, mfd. by Lucas Meyer containing 94% of phosphatidylcholine and prepared from soybean phospholipids is dispersed in water and reacted with lecitase 10-L®. After removing fatty acids with acetone, the title material, which is a phosphatide mainly comprising 38% of lysophosphatidylcholine and containing 39% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipid L: Soybean phospholipids are treated with acetone and then with ethanol and treated in the same manner as described with regard to monoacylglycerophospholipids B to thereby give a phosphatide containing 70% by weight of diacylphosphatidylcholine. This phosphatide is dispersed in water and reacted with Lecitase 10-L®. Fatty acids are removed from the reaction mixture by the use of acetone. Thus the title material, which is phosphatide mainly comprising 31% of lysophosphatidylcholine and 4% of lysophosphatidylethanolamine and containing 36% of monoacylglycerophospholipids in total, is obtained. Monoacylglycerophospholipids M: Soybean phospholipids are treated with acetone and reacted with Lecitase 10-L®. Then fatty acids are removed therefrom by adding acetone again followed by drying. Thus the title material, which is a phoshatide mainly comprising 24% of lysophosphatidylcholine and 8% of lysophosphatidylethanolamine and containing 37% of monoacylglycerophospholipids in total, is obtained. In the following Examples, the content (%) of monoacylglycerophospholipid(s) in each aqueous paste, which contained the composition of the present invention and was subjected to each test, is expressed on an absolute basis based on the total amount of the first and second components, i.e., polyglycerol fatty acid ester(s), sucrose fatty acid ester(s), sorbitan fatty acid ester(s) and glycerol fatty acid monoesters and the mono acyl glycero phospholipid(s). The term "phosphatide" as used herein means a composition containing monoacylglycerophospholipid(s) and diacylphosphatide(s), while the term "glycerol fatty acid ester" as used herein means a composition containing glycerol fatty acid monoester(s) and glycerol fatty acid diester(s). Example 1 Monoacylglycerophospholipid A and a polyglycerol fatty acid ester (Sun Soft Q-17-U® mfd. by Taiyo Kagaku Co., Ltd.; decaglycerol monooleate having an HLB of 15) were mixed at various weight ratios and each mixture thus obtained was formulated into an aqueous paste containing 50% by weight of the composition of the present invention. (1) Emulsification stability test on corn salad oil and aqueous solution of common salt 0.8 g of each paste, 40 g of corn salad oil and 60 ml of an 8% aqueous solution of common salt were emulsified in a turbotype homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 55°C and 12,000 rpmin for 5 min. The emulsion thus formed was introduced into a glass cylinder and stored in an incubator at 40°C under observation. In the composition comprising the polyglycerol fatty acid ester alone, 9% of an oily phase separated out after 30 days. On the other hand, in the compositions containing 5%, 10% and 40% of the monoacylglycerophospholipid, 5%, 3% and 2% of oily phases separated out respectively. (2) Emulsification stability test on corn salad oil and soy sauce 1 g of each paste, 50 g of corn salad oil and 50 g of "Koikuchi" soy sauce (having 15 wt% of sodium chloride; mfd by Kikkoman Co., Ltd.) were emulsified in a homogenizer (AM-8®) at 55°C and 13,000 rpmin for 6 min. The emulsion thus formed was introduced into a glass cylinder and stored in an incubator at 40°C under observation. In the composition comprising the polyglycerol fatty acid ester alone, 11% of an oily phase separated out after 30 days. On the other hand, in the compositions containing 5%, 10% and 40% of the monoacylglycerophospholipid, 7%, 4% and scarcely any oily phases separated out respectively. (3) β-Carotene solubilization test 1 g of each paste was dissolved in water to give a volume of 50 ml. 10 ml of the aqueous solution thus obtained and 10 mg of powdery β-carotene were introduced into a 30-ml test tube and shaken at 30°C for 42 h to thereby solubilize the β-carotene. The solubilized product was then centrifuged at 3,000 rpmin. To 2 ml of the supernatant, 8 ml of a mixture of chloroform and ethanol (1 : 4) was added and the absorbance of the resulting mixture was determined at 455 nm with a spectrometer, The composition comprising the polyglycerol fatty acid ester alone showed an absorbance of 0.041 while the one comprising the monoacylglycerophospholipid alone showed that of 0.372. On the other hand, the compositions comprising 10%, 25% and 50% of the monoacylglycerophospholipid showed absorbances of 0.394, 0.898 and 0.876, respectively. (4) Surface activity test 2.5 of each paste was dissolved in water to give a volume of 250 ml. The surface tension of the obtained aqueous solution was determined with a surface tension meter at 25°C (CBVP A-3®; mfd. by Kyowa Kagaku Co., Ltd.) and the permeation power wettability thereof was determined according to Kimura's canvas disc method at 25°C. The composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 33.4 mN/m (dyne/cm) and a permeation period wetting time of 15 min and 18 s. On the other hand, the compositions containing 5%, 10% and 40% of the mono acyl glycero phospholipids showed surface tensions of 33.1 mN/m (dyne/cm), 32.3 mN/m (dyne/cm) and 32.5 mN/m (dyne/cm), respectively, and permeation periods of 7 min and 6 s, 4 min and 6 s, and 2 min and 54 s, respectively. (5) Emulsification test on corn salad oil and grapefruit juice 1 g of each paste was dissolved in water to give a volume of 25 ml. 10 ml of the obtained aqueous solution, 20 ml of corn salad oil and 70 ml of reconstituted grapefruit juice (pH 3.3) were mixed and the obtained mixture was emulsified at 60°C in the same manner as described with regard to the emulsification stability test on corn salad oil and aqueous solution of common salt. The obtained emulsion was stored at 40°C under observation. In the composition comprising the polyglycerol fatty acid ester alone, 4% of an oily phase separated out after 30 days. On the other hand, in the compositions containing 10% and 20% of the monoacylglycerophospholipids, 1% and scarcely any oily phases separated out. Example 2 Monoacylglycerophospholipid A and a polyglycerol fatty acid ester having a HLB of 10 (SY Glyster SS-500 mfd. by Sakamoto Yakuhin CO., Ltd.; mainly comprising stearic acid and having a degree of polymerization of polyglycerol of 6 and having an HLB of 10) were mixed at various weight ratios and each mixture thus obtained was formulated into a 25% by weight aqueous paste. (1) Acid- and salt-resistance test 1 g of each paste was dissolved in water to give a volume of 25 ml. To one-part portions of the aqueous solution thus obtained, one-part portions of water, a 0.2 M phthalate buffer solution of pH 3 and a 20% aqueous solution of common salt were added to respectively give a control solution, an acidic solution and a saline solution and each solution was heated to 60°C for 10 min and allowed to stand, and the transmittance was determined at 720 nm after one day. In the composition comprising the polyglycerol fatty acid ester alone, the control solution showed a transmittance of 32% while the acidic and saline solutions showed a separation of the surfactant. In the composition comprising 20% of the monoacylglycerophospholipid, the control solution and the acidic solution showed transmittances of 94% and 82%, respectively. In the composition comprising 30% of the same, the control solution, the acidic solution and the saline solution showed transmittances of 98%, 95% and 81%, respectively. In the composition comprising 40% or more of the same, no difference was observed among the control, acidic and saline solutions. (2) Emulsification stability test on corn salad oil and aqueous solution of common salt By the use of 1.6 g of each paste, 40 g of corn salad oil and 59 ml of an aqueous solution of common salt, the procedure of Example 1 was followed. As a result, 14% of an oily phase separated out after 30 days in the composition comprising the polyglycerol fatty acid ester alone. On the other hand, 1% of an oily phase separated out in the composition comprising 10% of the monoacylglycerophospholipid while scarcely any separation was observed in the compositions comprising 40% or more of same. (3) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 1 was followed by use of 2 g of each paste, 50 g of corn salad oil and 55 g of "Koikuchi" soy sauce. In the composition comprising the polyglycerol fatty acid ester alone, 5% of an oily phase consequently separated out after 30 days. In the composition comprising 10% of the monoacylglycerophospholipid, 1% of an oily phase separated out while scarcely any separation was observed in the compositions comprising 20% or more of the same. (4) Emulsification test on corn salad oil and grapefruit juice The procedure of Example 1 was followed by the use of 2 g of each paste. In the composition comprising the polyglycerol fatty acid ester alone, 2% of an oily phase consequently separated out after 20 days. On the other hand, scarcely any separation was observed in the compositions comprising 10% or more of the same. Example 3 Monoacylglycerophospholipid A and a polyglycerol fatty acid ester of an HLB of 11 (SY Glyster MO-500 mfd. by Sakamoto Yakuhin Co., Ltd.; mainly comprising oleic acid and having a degree of polymerization of polyglycerol of 6) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Surface activity test 5g of each paste was dissolved in 200 ml of water and subjected to the same test as described in Example 1. As a result, the composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 35.0 mN/m (dyne/cm) and a permeation period of 18 min and 18 s. On the other hand, the compositions comprising 10%, 20% and 40% of the monoacylglycerophospholipid showed surface tensions of 33.9 mN/m (dyne/cm), 32.8 mN/m (dyne/cm) and 32.3 mN/m (dyne/cm), respectively, and permeation periods of 7 min and 12 s, 4 min and 54 s and 3 min and 24 s, respectively. Example 4 Monoacylglycerophospholipid D and Sun Soft Q-17-U® were mixed together at various weight ratios and each mixture thus obtained was formulated into a 50% by weight aqueous paste. (1) Surface activity test The procedure of Example 1 was followed. As a result, the composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 33.4 mN/m (dyne/cm) and a permeation period of 15 min and 20 s. On the other hand, the compositions comprising 6%, 13% and 29% of the monoacylglycerophospholipid showed surface tensions of 31.7 mN/m (dyne/cm), 30.2 mN/m (dyne/cm) and 29.6 mN/m (dyne/cm), respectively, and permeation periods of 4 min and 6 s, 2 min and 54 s and 2 min and 18 s, respectively. (2) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 1 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 11% of an oily phase separated out after 30 days. In the compositions comprising 6% and 2% of the monoacylglycerophospholipid, 6% and 13% of oily phases separated out while scarcely any separation was observed in the compositions comprising 29% or more of the same. (3) β-Carotene solubilization test The procedure of Example 1 was followed. As a result, the composition comprising the polyglycerol fatty acid ester alone showed an absorbance of 0.041. On the other hand, the compositions comprising 15% and 38% of the monoacylglycerophospholipid showed absorbances of 0.277 and 0.512, respectively. (4) Dispersion test on fine inorganic particles 1 g of each paste was dissolved in water to give a volume of 250 ml. 20 ml of the obtained aqueous solution and 1 g of a titanium white pigment were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the pigment in the solution. After adding 5 ml of a 30% aqueous solution of common salt, the mixture was shaken again and allowed to stand at room temperature under observing the dispersion and sedimentation condition. As a result, the composition comprising the polyglycerol fatty acid ester alone showed aggregation and sedimentation after 20 min regardless of the addition of the common salt solution. In contrast, thereto, the composition comprising 10% of the monoacylglycerophospholipid showed little sedimentation after 1h and the compositions comprising 24% or more of the same showed stable dispersion after 3h. A similar test was carried out by use of highly fine grains of calcium carbonate. As a result, the composition comprising the polyglycerol fatty acid ester alone immediately showed aggregation and sedimentation while the compositions comprising 15% or more of the monoacylglycerophospholipid showed a stable dispersion after 3h. (5) Emulsification test on corn salad oil and grapefruit juice The procedure of Example 1 was followed. As a result, the compositions comprising 6% or more of the monoacylglycerophospholipid showed scarcely any phase separation after 20 days while 2% of an oily phase separated out in the composition comprising no monoacylglycerophospholipid. Example 5 Monoacylglycerophospholipid F and SY Glyster MO-500 were mixed together at various weight ratios and each mixture thus obtained was formulated into a 50% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 1 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 2% of an oily phase consequently separated out. On the other hand, scarcely any separation was observed after a month in the compositions comprising 5.3%, 11% and 25% of the monoacylglycerophospholipid. (2) Surface activity test The procedure of Example 1 was followed. As a result, the composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 35.9 mN/m (dyne/cm) and a permeation period of 18 min and 18 s. On the other hand, the compositions comprising 5.3%, 11% and 25% of the monoacylglycerophospholipid showed surface tensions of 35.5 mN/m (dyne/cm), 34.9 mNm (dyne/cm) and 34.3 mN/m (dyne/cm), respectively, and permeation periods of 7 min and 12 s, 5 min and 6 s and 3 min and 10 s, respectively. Example 6 Monoacylglycerophospholipid G and Sun Soft Q-17-U® were mixed together at various weight ratios and each mixture thus obtained was formulated into a 50% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 1 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 11% of an oily phase separated out after 30 days and a number of giant oil droplets of several mm in diameter were observed in a creaming phase, suggesting that the emulsion was broken. In contrast thereto, 2% of an oily phase separated out in the composition comprising 17% of the monoacylglycerophospholipid and scarcely any separation was observed even after 1 month in the compositions comprising 26% or more of same. Example 7 60 parts by weight of SY Glyster MO-500 and 40 parts by weight of monoacylglycerophospholipid D were dissolved in 9000 parts by weight of ethanol. 50 g of the solution thus obtained was mixed with 500 g of a alkali treated cocoa powder containing 23% of fat in a Kenwood mixed under stirring and the resulting mixture was dried in vacuo and ground to thereby give an instant cocoa. 2 g of this instant cocoa was suspended in 100 ml of water and the period required for the sedimentation of the whole product was determined. As a result, the above cocoa required 3 min and 42 s for the sedimentation while a comparative product comprising the polyglycerol fatty acid ester alone required 17 min and 36 s. Example 8 Monoacylglycerophospholipid B and a polyglycero fatty acid ester having an HLB of 8 (SY Glyster MS-310 mfd. by Sakamoto Yakuhin Co., Ltd.; mainly comprising stearic acid and having a degree of polymerization of polyglycero of 4) were mixed at various weight ratios and each mixture thus obtained was formulated into an aqueous paste containing 25% by weight of solids. (1) Acid- and salt-resistance test The procedure of Example 2 was followed by the use of aqueous solutions prepared by dissolving 4 g of each paste in water to give a volume of 200 ml and the transmittance of each sample was determined at 720 nm. As a result, in the composition comprising the polyglycerol fatty acid ester alone, the control solution showed a transmittance of 8% and the acidic and saline solutions showed separation of the surfactant. On the other hand, in the composition comprising 30% of the monoacylglyceo phospholipid, the control, acidic and saline solutions showed transmittance of 82%, 75% and 79%, respectively. Little difference was observed among the transmittances of the control (87%), acidic and saline solutions in the compositions comprising 40% or more of same. (2) Emulsification stability test on corn salad oil and soy sauce 2 g of each paste, 50 g of corn salad oil and 56 g of "Koikuchi" soy sauce were emulsified in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 55°C and 13,000 rpmin for 6 min. The obtained emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 8 h and 40°C for 16 h. In the composition comprising the polyglycerol fatty acid ester alone, 8% of an oily phase consequently separated out after 30 days. On the other hand, 2% of an oily phase separated out in the composition comprising 10% of the monoacylglycerophospholipid and scarcely any separation was observed after 60 days in the compositions comprising 20% or more of same. (3) Surface activity test 4 g of each paste was dissolved in water to give a volume of 200 ml. The surface tension of the obtained aqueous solution at 25°C was determined by the use of a surface tension meter (CBVP A-3®, mfd. by Kyowa Kagaku Co., Ltd.) and the permeability (wetting time) of same was determined as a permeation period according to Kimura's canvas disc method at 25°C. As a result, the composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 36.9 mN/m (dyne/cm) and a permeation period of longer than 30 min. In contrast thereto, the compositions comprising 20% and 40% of the monoacylglycerophospholipid showed surface tensions of 31.2 mN/m (dyne/cm) and 30.8 mN/m (dyne/cm), respectively, and permeation periods of 4 min and 32 s and 3 min and 3 s, respectively. (4) Dispersion test on fine inorganic particles 2 g of each paste was dissolved in water to give a volume of 250 ml. 20 ml of the obtained aqueous solution and 1 g of a titanium white pigment were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the pigment in the solution. Then it was allowed to stand at room temperature under observing the dispersion and sedimentation condition. Further 5 ml of a 30% aqueous solution of common salt was added and the mixture was shaken again and allowed to stand under observing the dispersion and sedimentation condition. The composition comprising the polyglycerol fatty acid ester alone showed aggregation and sedimentation after 20 min regardless of the addition of the saline solution. In contrast thereto, the composition comprising 10% of the monoacylglycerophospholipid to which no saline solution was added showed little sedimentation after 1 h, while the compositions comprising 20% or more of the monoacylglycerophospholipid showed stable dispersion regardless of the addition of the saline solution. The same procedure was carried out by the use of highly fine grains of calcium carbonate. As a result, the composition comprising the polyglycerol fatty acid ester alone immediately showed aggregation and sedimentation. In the case where the saline solution was added, in particular, the addition of the polyglycerol fatty acid ester accelerated the aggregation and sedimentation compared with a saline solution containing no additive. In contrast thereto, the compositions comprising 20% or more of the monoacylglycerophospholipid showed stable dispersion after 2 h. Example 9 Monoacylglycerophospholipid B and a polyglycerol fatty acid ester having an HLB of 7 (SY Glyster TS-500 mfd. by Sakamoto Yakuhin Co., Ltd.; mainly comprising stearic acid and having a degree of polymerization of polyglycerol of 6) were mixed at various weight ratios and each mixture thus obtained was formulated into a 25% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and aqueous solution of common salt The procedure of Example 8 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 7% of an oily phase consequently separated out after 3 days. In the composition comprising 10% of the monoacylglycerophospholipid 1% of oily phase separated out after 3 days, but in the composition comprising 20% of the monoacylglycerophospholipid only 2% of oily phases separated out after 2 months. Scarcely any separation was observed in the composition comprising 30% or more of same. Example 10 Monoacylglycerophospholipid B and a polyglycerol fatty acid ester having an HLB of 4 (SY Glyster TS-310 mfd. by Sakamoto Yakuhin Co., Ltd.; mainly comprising stearic acid and having a degree of polymerization of glycerol of 4) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 8 was followed by the use of 2.5 g of each paste. As a result, the emulsion of the composition comprising the polyglycerol fatty acid ester alone was completely broken within 3 days. On the other hand, 10% of an oily phase separated out after seven days in the composition comprising 10% of the monoacylglycerophospholipid and scarcely any separation was observed after a month in the composition comprising 20% or more of same. Example 11 Monoacylglycerophospholipid E and SY Glyster MS-310 were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test The procedure of Example 8 was followed by the use of 5 g of each paste to thereby determine the transmittance of each sample at 720 nm. As a result, in the composition comprising the polyglycerol fatty acid ester alone, the control solution showed a transmittance of 8% while the acidic and saline solutions showed a separation of the surfactant. In the composition comprising 32% of the monoacylglycerophospholipid, the control, acidic and saline solutions showed transmittances of 75%, 62% and 45%, respectively. In the composition comprising 41% of same, the control, acidic and saline solutions showed transmittances of 80%, 74% and 67%, respectively. In the composition comprising 51% of same, the control, acidic and saline solutions showed transmittances of 86%, 82% and 82%, respectively, i.e., showing little differences. (2) Surface activity test The procedure of Example 8 was followed. As a result, the composition comprising the polyglycerol fatty acid ester alone showed a surface tension of 36.9 mN/m (dyne/cm), and the permeation period was longer than 30 min. In contrast thereto, the compositions comprising 15%, 32% and 51% of the monoacylglycerophospholipids showed surface tensions of 30.8 mN/m (dyne/cm), 29.4 mN/m (dyne/cm) and 29.5 mN/m (dyne/cm) respectively, and permeation periods of 8 min and 23 s, 3 min and 48 s and 2 min and 36 s, respectively. (3) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 8 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 8% of an oily phase separated out after 30 days. On the other hand, 1% of an oily phase separated out in the composition comprising 15% of the monoacylglycerophsopholipid while scarcely any separation was observed in the composition comprising 23% or more of same. (4) Dispersion test on fine inorganic particles The procedure of Example 8 was followed. As a result, the titanium white pigment showed aggregation and sedimentation after 20 min in the composition comprising the polyglycerol fatty acid ester alone regardless of the addition of the saline solution. In contrast thereto, the composition comprising 15% of the monoacylglycerophospholipid showed little sedimentation after 3 h without adding any saline solution and the compositions comprising 23% or more of same showed stable dispersion after 1 h with adding saline solution. The same test was carried out by the use of highly fine grains of calcium carbonate. In the composition comprising the polyglycerol fatty acid ester alone, aggregation and sedimentation were immediately observed. In the composition where the saline solution was added, in particular, the addition of the polyglycerol fatty acid ester accelerated the aggregation and sedimentation compared with a saline solution containing no additive. In the composition comprising 15% or more of the monoacylglycerophospholipid, a stable dispersion was observed after 2 h. In the composition comprising 32% or more of monoacylglycerophospholipid, a stable dispersion was observed after 2 h even in the presence of the saline solution. Example 12 Monoacylglycerophospholipid F and SY Glyster TS-500 were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 8 was followed. In the composition comprising the polyglycerol fatty acid ester alone, 7% of an oily phase separated out after 3 days. In the composition comprising 12% of the monoacylglycerophospholipid, 1% of an oily phase separated out after 1 month, while scarcely any separation was observed after two months in the compositions comprising 19% or more of same. Example 13 Monoacylglycerophospholipid A and a sucrose fatty acid ester having an HLB of 15 (Ryoto Sugar Ester S-1670®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; mainly comprising stearic acid) were mixed at various weight ratios and each mixture thus obtained was formulated into an aqueous paste containing 40% by weight of the composition of the present invention. (1) Acid- and salt-resistance test To 2.5g of each paste, water was added to give a volume of 100 ml. To one-part (by volume) portions of the aqueous solution thus formed. one-part (by volume) portions of a 0.2 M phthalate buffer solution (pH 3). a 20% aqueous solution of common salt and water were added to respectively give an acidic solution, a saline solution and a control solution and each solution was allowed to stand at room temperature for a day. In the composition comprising the sucrose fatty acid ester alone, the acidic and saline solutions immediately showed aggregation and sedimentation. In the compositions comprising 5 to 20% of the monoacylglycerophospholipid, milky turbidity slowly proceeded while little turbidity was observed in the compositions comprising 30% or more of same. In the composition comprising the sucrose fatty acid esters alone, the control solution showed a transmittance of 97% at 720 nm after one day while both of the acidic and saline solutions, wherein a precipitate was redispersed prior to the determination, showed a transmittance of 0%. In the composition comprising 30% of the monoacylglycerophospholipid, the acidic and saline solutions showed transmittances of 70% and 84%, respectively. In the composition comprising 40% of the same, the acidic and saline solutions showed transmittances of 92% and 97%, respectively. In the composition comprising 50% of the monoacylglycerophospholipid, the acidic and saline solutions showed transmittances of 97% and 99%. respectively. In the compositions comprising 30% or more of same, each control solution showed a transmittance of 99%. (2) Emulsification stability test on liquid paraffin and aqueous solution of common salt 1.25g of each paste containing 0.5g of the composition of the present invention, 35 ml of liquid paraffin and 65 ml of a 5% aqueous solution of common salt were emulsified with a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 45°C and 12,000 rpmin for 5 min. The obtained emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising the sucrose fatty acid ester alone, the separation of 2% by volume, based on the total emulsion system, of an oily phase required one day. On the other hand, in the compositions comprising 6%, 10%, 20%, 30% and 40% or more of the monoacylglycerophospholipid, 6, 12, 21, 35 and 45 days were required therefor, respectively. When 0.25g of the monoacylglycerophospholipid alone was added to give the same monoacylglycerophospholipid concentration as that of the composition of the present invention comprising 50% of the monoacylglycerophospholipid, 6 days were required therefor, showing that the combined use of the monoacylglycerophospholipid with the sucrose fatty acid ester improved the effects. (3) Emulsification stability test on corn salad oil and soy sauce 1.25g of each paste, 50g of corn salad oil and 56g of "Koikuchi" soy souce (mfd. by Kikkoman Co., Ltd.) were emulsified in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki co., Ltd.) at 55°C and 13,000 rpmin for 6 min. The emulsion thus formed was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising the sucrose fatty acid ester alone, the separation of 2% of an oily phase required 5 days and emulsified particles in the emulsified creamy phase aggregated and showed poor redispersibility when shaken. In contrast thereto, in the composition comprising 5% of the monoacylglycerophospholipid, 14 days were required therefor. In the compositions comprising 10% or more of same, 60 or more days were required therefor and the creamy phases showed excellent dispersibility thereafter. (4) Surface activity test 2.5g of each paste was dissolved in water to give a volume of 200 ml. The surface tension of the aqueous solution thus obtained was determined at 25°C by the use of a surface tension meter (CBVP A-3®, mfd. by Kyowa Kagaku Co., Ltd.) and the permeability of same was determined according to Kimura's canvas disc method at 25°C. As a result, the composition comprising the sucrose fatty acid ester alone showed a surface tension of 34.9 mN/m (dyne/cm) and a permeation period of 7 min and 12 s. On the other hand, the compositions comprising 5%, 10% and 50% of the monoacylglycerophospholipid showed surface tensions of 34.6 mN/m (dyne/cm), 34.3 mN/m (dyne/cm) and 32.6 mN/m (dyne/cm), respectively, and permeation periods of 5 min and 50 s, respectively, each showing a successive decrease. (5) β-Carotene solubilization test 2.5g of each paste was dissolved in water to give a volume of 100 ml. By the use of the aqueous solution thus obtained, the procedure of Example 1 was followed and the absorbance of each sample was determined at 455 nm with a spectrometer. As a result, the composition comprising the sucrose fatty acid ester alone showed an absorbance of 0.102. On the other hand, the compositions comprising 30%, 40% and 50% of the monoacylglycerophospholipid showed absorbances of 0.309, 0.371 and 0.418, respectively, suggesting that the β-carotene thus solubilized amounted three to four times as much as that of the former case. 2-ml portions of the centrifuged supernatant were added to 2-ml portions of water, an 8% aqueous solution of common salt and a solution of a pH value of 4 to respectively give a control solution, a saline solution and an acidic solution. As a result, in the composition comprising 30% of the monoacylglycerophospholipid, both the acidic and saline solutions showed a slight turbidity. On the other hand, the solutions showed stable solubilization in the compositions comprising 50% of same. (6) Dispersion test 1.25g of each paste was dissolved in water to give a volume of 250 ml. 5 ml of the aqueous solution thus obtained and 50 mg of fine particles of β-carotene were introduced into a 15-ml test tube and shaken vertically to thereby disperse the particles in the solution. Then the stability of the obtained dispersion and the packing volume of the sedimented grains, which were densely packed and showed a primary dispersion to some extent, suggesting that no aggregation occurred, were observed. Immediately after shaking, all samples including those comprising no monoacylglycerophospholipid showed excellent dispersion and a dense precipitate. One day later, the better dispersion and a precipitate of better qualities were observed in a sample comprising a higher amount of the monoacylglycerophospholipid. To 2-ml portions of each dispersion, 2-ml portions of water, an 8% aqueous solution of common salt and a 0.2 mol phthalatebuffer solution of a pH value of 4 were added to respectively give a control solution, a saline solution and an acidic solution. Thus, in the composition comprising the sucrose fatty acid ester alone, both of the acidic and saline solutions immediately showed sedimentation. In the composition comprising 30% of the same, the dispersion was significantly stable and the composition comprising 40% of same showed a stability comparable to that of the control solution. Example 14 Monoacylglycerophospholipid C and a sucrose fatty acid ester having an HLB of 14 (Ryoto Sugar Ester P-1570®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd; mainly comprising palmitic acid) were mixed together at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test To 5g of each paste, water was added to give a volume of 100 ml. By the use of the aqueous solution thus formed, acidic solutions (pH 3 and pH 5) and a 10% aqueous solution of common salt, the procedure of Example 13 was followed. As a result, the composition comprising the sucrose fatty acid ester alone immediately showed a milky turbidity, while the milky turbidity slowly proceeded in the other samples. The transmittance determined after 1 day of the control solution of the composition comprising the sucrose fatty acid ester alone was 96%, while those of the compositions comprising 20% or above of same were 98%. Both of the acidic and saline solutions of the composition comprising the sucrose fatty acid ester alone showed a transmittance of 0%, when determined after redispersing the precipitate. On the other hand, that of the composition comprising 42% was 64% (pH 5) while those of the compositions comprising 52% of same were 28% (pH 3), 51%(saline) and 82%(pH 5). (2) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 13 was followed by the use of 2.5g of each paste, 50g of corn salad oil and 54g of "Koikuchi" soy sauce. The obtained emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising the sucrose fatty acid ester alone, the separation fo 2% of an oily phase required 6 days. On the other hand, a month or more was required therefor in the compositions comprising 15% or more of the monoacylglycerophospholipid, while little separation was observed in the compositions comprising 30% or more of same. Example 15 Monoacylglycerophospholipid A and a sucrose fatty acid ester having an HLB of 11 (Ryoto Sugar Ester S-1170®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; Mainly comprising stearic acid) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test The procedure of Example 14 was followed by the use of acidic solutions of pH 3 and pH 5 and a 10% aqueous solution of common salt. As a result, only the composition comprising the sucrose fatty acid ester alone immediately showed a milky turbidity. The transmittance at 720 nm determined after 1 day of the control solution of the composition comprising the sucrose fatty acid ester alone was 57%. The control solution of the composition comprising 20% of the monoacylglycerophospholipid showed a transmittance of 90%, while the compositions comprising 40% or more of same showed 99% thereof. Both the acidic and saline solutions of the composition comprising the sucrose fatty acid ester alone showed a transmittance of nearly 0%. In contrast thereto, the composition comprising 30% of the monoacylglycerophospholipid showed a transmittance of 62% (pH 5), the composition comprising 40% of same showed transmittances of 32% (saline) and 91% (pH 5), the composition comprising 50% of same showed transmittances of 52% (pH 3), 84% (saline) and 94% (pH 5) and the composition comprising 60% of same showed transmittances of 88% (pH 3), 99% (saline) and 96% (pH 5). (2) Emulsification stability test on corn salad oil and soy sauce Similar to Example 14, an emulsion of each paste, corn salad oil and "Koikuchi" soy sauce was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising the sucrose fatty acid ester alone, a creamy phase aggregated accompanied by the loss of flowability and 25% of an oily phase separated out after 1 month. On the other hand, 2% of an oily phase separated out in the composition comprising 10% of the monoacylglycerophospholipid while little separation was observed after 1 month in the composition comprising 20% or more of same. Example 16 Monoacylglycerophospholipid C and Ryoto Sugar Ester S-1170® were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test The procedure of Example 14 was followed by the use of an acidic solution (pH 5) and a 10% aqueous solution of common salt. The control solutions of the compositions comprising 24% and 37% or more of the monoacylglycerophospholipid showed transmittances at 720 nm of 88% and 91%, respectively, after 1 day. The acidic and saline solutions of the composition comprising 52% of the same showed transmittances of 60% and 35%, respectively. (2) Emulsification stability test on corn salad oil and soy sauce Similar to Example 14. an emulsion of each paste, corn salad oil and "Koikuchi" soy sauce was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising 11% of the monoacylglycerophospholipid, 1% of an oily phase separated out after 1 month. In contrast thereto, little separation was observed in the compositions comprising 24% or more of same. Example 17 Monoacylglycerophospholipid D and Ryoto Sugar Ester S-1670® were mixed at various weight ratios and each mixture thus obtained was formulated into a 25% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 13 was followed except that 2g of each paste was used. The emulsion of the paste, corn salad oil and "koikuchi" soy sauce thus obtained was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, scarcely any separation of any oily phase was observed after 1 month. (2) Surface activity test 10g of each paste was dissolved in water to give a volume of 500 ml. The surface tension and permeability of the obtained aqueous solution at 25°C were determined each in the same manner as described in Example 13. The composition comprising the sucrose fatty acid ester alone showed a surface tension of 34.6 mN/m (dyne/cm) and a permeation period of 7 min and 12 s. In contrast thereto, the compositions comprising 6%, 12% and 29% of same showed surface tensions of 34.4 mN/m (dyne/cm), 34.0 mN/m (dyne/cm) and 31.1 mN/m (dyne/cm), respectively, and permeation periods of 4 min and 42 s, 3 min and 24 s and 2 min and 15 s, respectively. (3) Emulsification stability test on grapefruit juice and corn salad oil 1g of each paste was dissolved in water to give a volume of 50 ml. 50 ml of the aqueous solution thus obtained, 50 ml of resonstituted grapefruit juice (pH 3.31) and 25 ml of corn salad oil were mixed and the mixture was emulsified and stored in an incubator at 40°C in the same manner as described in regard to emulsification stability test on corn salad oil and soy sauce in Example 13, to thereby observe the stability of the emulsion with the elapse of time. In the composition comprising the sucrose fatty acid ester alone, a creamy phase aggregated accompanied by the loss of the flowability and separation of an oily phase began after 6 days. In contrast thereto, no separation was observed after 21 days and a creamy phase was highly flowable and readily dispersed again, in the composition comprising 10% of the monoacylglycerophospholipid. (4) β-Carotene solubilizaiton test 1g of each paste was dissolved in water to give a volume of 25 ml. The absorbance of the aqueous solution thus obtained was determined at 455 nm with a spectrometer, similar to Example 13. As a result, the composition comprising the sucrose fatty acid ester alone showed an absorbance of 0.102, while the compositions comprising 18%, 30% and 39% of the monoacylglycerophospholipid showed absorbances of 0.154, 0.181 and 0.256, respectively, showing an increase in the amount of the solubilized β-carotene. In the composition comprising 30% of the monoacylglycerophospholipid, the saline and acidic solutions showed a somewhat milky turbidity. On the other hand, the composition comprising 39% of same showed stable solubilization. (5) Dispersion test on fine inorganic particles 1g of each paste was dissolved in water to give a volume of 125 ml. 20 ml of the aqueous solution thus obtained and 1g of a titanium white pigment were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the pigment in the solution. After adding 5 ml of a 30% aqueous solution of common salt, the mixture was shaken again and allowed to stand at room temperature under observing the dispersion and sedimentation condition. As a result, the composition comprising the sucrose fatty acid ester alone immediately showed aggregation and sedimentation. In contrast thereto, the compositions comprising 12% or more of same showed stable dispersion after 3 h. Example 18 Monoacylglycerophospholipid F and Ryoto Sugar Ester S-1670® were mixed at various weight ratios and each mixture thus obtained was formulated into a 25% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce Similar to Example 17, an emulsion comprising each paste, corn salad oil and "Koikuchi" soy sauce was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, scarcely any separation of an oily phase was observed after 1 month. (2) Emulsification stability test on Grapefruit juice and corn salad oil Similar to Example 17, 50 ml of a 0.5% aqueous solution, 50 ml of grapefruit juice (pH 3.31) and 50 ml of corn salad oil were mixed. Then the obtained mixture was emulsified at 60°C in the same manner as described in Example 13 and stored at 40°C to thereby observe the stability thereof with the elapse of time. In the composition comprising the sucrose fatty acid ester alone, a creamy phase aggregated and lost the flowability and separation of an oily phase began after 6 days. In contrast thereto in the composition comprising 10% of the monoacylglycerophospholipid, no separation of any oily phase was observed after 21 days and the creamy phase was highly flowable and readily dispersed. Example 19 Monoacylglycerophospholipid D and Ryoto Sugar Ester S-1170® were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce Similar to Example 14, an emulsion comprising each paste, corn salad oil and "Koikuchi" soy sauce was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, in the composition comprising 12% of the monoacylglycerophospholipid, 1% of an oily phase separated out after 1 month. On the other hand, the compositions comprising 18% or more of same showed scarcely any separation. (2) Surface activity test 5g of each paste was dissolved in water to five a volume of 200 ml. The surface tension and permeability of the aqueous solution thus obtained were determined at 25°C each in the same manner as described in Example 13. As a result, the composition comprising the sucrose fatty acid ester alone showed a surface tension of 34.9 mN/m (dyne/cm) and a permeation period of 26 min and 42 s. In contrast thereto, the compositions comprising 12%, 20% and 29% of same showed surface tensions of 32.1 mN/m (dyne/cm), 31.4 mN/m (dyne/cm) and 31.0 mN/m (dyne/cm), respectively, and permeation periods of 4 min and 36 s, 3 min and 54 s and 3 min and 36 s, respectively. (3) Emulsification stability test on juice and corn salad oil 1 g of each paste was dissolved in water to give a volume of 40 ml. By the use of the aqueous solution thus obtained, grapefruit juice and corn salad oil were emulsified in the same manner as described in Example 17. The resulting emulsion was stored at 40°C and the stability of same was observed with the elaspe of time. As a result, in the composition comprising the surcrose fatty acid ester alone, a creamy phase aggregated and lost the flowability and an oily phase began to separate on the third day and amounted to 6% after 21 days. In contrast thereto, the compositions comprising 10% or more of the monoacylglycerophospholipid showed no separation after 21 days and the creamy phases thereof were highly flowable and readily redispersed. Example 20 Monoacylglycerophospholipid G and Ryoto Sugar Ester S-1670® were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Emulsification stability test on corn salad oil and soy sauce Similar to Example 14, an emulsion comprising each paste, corn salad oil and "Koikuchi" soy sauce was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, 1% of an oily phase separated out after 1 month in the composition comprising 5% of the monoacylglycerophospholipid, while scarcely any separation was observed in the compositions comprising 10% or more of the same. Example 21 Six parts by weight of Ryoto Sugar Ester S-1170® and 4 parts by weight of monoacylglycerophospholipid D were dissolved in 90 parts by weight of ethanol. 50 g of the solution thus obtained was mixed with 500 g of a alkali treated cocoa powder, which contained 23% of fat in a Kenwood mixer under stirring. Then the resulting mixture was dried in vacuo and ground to give an instant cocoa product. 2 g of this instant cocoa was suspended on 100 ml of water. The whole powder required 3 min and 42 s for sedimentation. In the case of a comparative cocoa powder prepared by the use of the sucrose fatty acid ester alone, 17 min and 36 s was required therefor. Example 22 Monoacylglycerophospholipid B and a sucrose fatty acid ester having an HLB of 7 (Ryoto Sugar Ester S-770®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; mainly comprising stearic acid) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test 2.5 g of each paste was added to water to give a volume of 100 ml. To one-part (by volume) portions of the aqueous solution thus obtained, one-part (by volume) portions of a 0.2 M phthalate buffer solution (pH 3), a 20% aqueous solution of common salt and water were added to give an acidic solution, a saline solution and a control solution, respectively. Each solution thus formed was heated to 60°C for 10 min and allowed to cool at room temperature. As a result, in the composition comprising the sucrose fatty acid ester alone, the acidic and saline solutions immediately showed aggregation and precipitation. In the compositions comprising 10 to 60% of the monoacylglycerophospholipid, a milky turbidity proceeded slowly, while little turbidity was observed in the compositions comprising 70% or more of same. In the composition comprising the sucrose fatty acid ester alone, the control solution showed a transmittance of 42% at 720 nm after 1 day, while both the acidic and saline solutions, wherein formed precipitate was redispersed prior to the determination, showed a transmittance of 0%. In the composition comprising 40% of the monoacylglycerophospholipid, the control and saline solutions showed transmittance of 96% and 59%, respectively. In the compositions comprising 60% of same, the control, acidic and saline solutions showed a transmittance of 99%, 51% and 94%, respectively. (2) Emulsification stability test on liquid paraffin and aqueous solution of common salt 2.5 g of each paste, 35 ml of liquid paraffin and 65 ml of a 5% aqueous solution of common salt were emulsified in a turbo type homogenizer (AM-8® mfd. by Nippon Seiki Co., Ltd.) at 45°C and 12,000 rpmin for 5 min. The emulsion thus formed was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., at 20°C for 12 h and at 35°C for 12 h. As a result, the separation of 2% by volume, based on the total emulsion system, of an oily phase required 1 day for the composition comprising the sucrose fatty acid ester alone. On the other hand, for the compositions comprising 10%, 20%, 30% and 50% of the monoacylglycerophospholipid, 10 days, 17 days, 28 days and 42 days were required therefor, respectively. When 0.25 g of the monoacylglycerophospholipid alone was added, i.e., giving the same concentration of the monoacylglycerophospholipid in the composition of the present invention comprising 50% of the monoacylglycerophospholipid, 6 days were required therefor, showing that the combined use of the monoacylglycerophospholipid with the sucrose fatty acid ester improved the effects. (3) Emulsification stability test on corn salad oil and soy sauce 2.5 g of each paste, 50 g of corn salad oil and 56 g of "Koikuchi" soy sauce were emulsified in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co.,Ltd.) at 55°C and 13,000 rpmin for 6 min. The emulsion thus obtained was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 8 h and 40°C for 16 h. As a result, for the composition comprising the sucrose fatty acid ester alone, the separation of 2% of an oily phase required 4 days, the emulsified particles in a creamy phase aggregated and showed poor redispersibility by shaking and the emulsion was broken after 21 days. In contrast thereto, the compositions comprising 10% and 20% or more of the monoacylglycerophospholipid required 14 days and 60 days or longer therefor, respectively. The creamy phases showed excellent redispersibility thereafter in the latter cases. (4) Surface activity test 5 g of each paste was dissolved in water to give a volume of 200 ml. The surface tension of the aqueous solution thus obtained was determined at 25°C by the use of a surface tension meter (CBVP A-3®, mfd. by Kyowa Kagaku Co., Ltd.) while the permeability thereof was determined as a permeation period at 25°C according to Kimura's canvas disc method. As a result, the composition comprising the sucrose fatty acid ester alone showed a surface tension of 34.8 mN/m (dyne/cm) and a permeation period longer than 30 min. In contrast thereto, the compositions comprising 20% and 40% of the monoacylglycerophospholipid showed surface tensions of 31.6 mN/m (dyne/cm) and 30.9 mN/m (dyne/cm), respectively, and permeation periods of 6 min and 48 s and 4 min and 59 s, respectively. Example 23 An emulsification stability test on corn salad oil and soy sauce was carried out in the same manner as described in Example 22, by the use of a 20% by weight aqueous paste of a composition comprising 30 parts by weight of monoacylglycerophospholipid B and 70 parts by weight of a sucrose fatty acid ester having an HLB of 9 (Ryoto Sugar Ester S-970®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; mainly comprising stearic acid). As a result, the separation of 2% of an oily phase required seven days for the composition comprising the sucrose fatty acid ester alone. The emulsified particles in a creamy phase aggregated and showed no redispersibility by shaking and the emulsion was broken after 21 days in this case. In contrast thereto, in the compositions comprising the monoacylglycerophospholipid, no separation was observed after 60 days and the creamy phases showed excellent redispersibility. The same procedure was repeated except that the soy sauce was replaced by reconstituted orange juice (pH 3.5). As a result, the separation of 2% of an oily phase required 35 days for the composition comprising the sucrose fatty acid ester alone. On the other hand, no separation was observed after 60 days and the creamy phases showed excellent redispersibility for the compositions comprising the monoacylglycerophospholipid. Example 24 An emulsification stability test on corn salad oil and soy sauce was carried out in the same manner as described in Example 22 by the use of a 20% by weight aqueous paste of a composition comprising 30 parts by weight of monoacylglycerophospholipid B and 70 parts by weight of a sucrose fatty acid ester having an HLB of 5 (Ryoto Sugar Ester S-570®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; mainly comprising stearic acid). As a result, in the composition comprising the sucrose fatty acid ester alone, 2% of an oily phase separated out after four days and the emulsion was broken after 15 days. In contrast thereto, in the compositions comprising the monoacylglycerophospholipid, only 1% of an oily phase separated out after 60 days. The same procedure was repeated except that the soy sauce was replaced by reconstituted orange juice (pH 3.5). As a result, in the composition comprising the sucrose fatty acid ester alone, 2% of an oily phase separated out after eight days and the emulsion was broken after 21 days. In contrast thereto, the compositions comprising the monoacylglycerophospholipid showed no separation after 60 days. Example 25 Monoacylglycerophospholipid E and a sucrose fatty acid ester having an HLB of 5 (Ryoto Sugar Ester S-570®, mfd. by Mitsubishi Kasei Shokuhin Co., Ltd.; mainly comprising stearic acid) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. By the use of these paste, an emulsification stability test on corn salad oil and soy sauce was carried out in the same manner as described in Example 22. As a result, the composition comprising 11% by weight of the monoacylglycerophospholipid was inferior to that comprising 15% by weight of same in the redispersibility and homogeneity fo the creamy phase, although little separation was observed in both cases. As a matter of course, scarcely any separation was observed in the compositions comprising 15% by weight or more of the same. Example 26 Monoacylglycerophospholipid E and Ryoto Sugar Ester S-770® were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. 60 g of each paste, 600 g of rapeseed oil and 400 g of "Koikuchi" soy sauce were stirred vigorously under heating to thereby pre-emulsify the mixture. Then the mixture was homogenized with a homogenizer (15 M-8 BA®, mfd. by Manton Gaulin Manufacturing Co.) by applying pressures of 29420 kPa (300 Kg/cm²) and 1961 kPa (20 Kg/cm²) at the first and second valves, respectively, at 40°C twice to thereby give an emulsion. The obtained emulsion was allowed to stand at 40°C for 60 days under observing the emulsification stability of same. In the composition comprising the sucrose fatty acid ester alone, 5% of an oily phase separated out after 2 days. On the other hand, only a trace amount of an oily component separated out in the composition comprising 11% of the monoacylglycerophospholipid. In the compositions comprising 23% and 41% of same, no oily phase separated out and creaming-up proceeded slowly, showing excellent redispersibility. 5 g of each paste was dissolved in water to give a volume of 200 ml. The surface tension and permeability of the aqueous solution thus obtained were determined at 25°C each in the same manner as described in Example 22. The composition comprising the sucrose fatty acid ester alone showed a surface tension of 34.8 mN/m (dyne/cm) and a permeation period longer than 30 min. In contrast thereto, the compositions comprising 15%, 31.5% and 51% of the monoacylglycerophospholipid showed surface tensions of 31.5 mN/m (dyne/cm), 29.6 mN/m (dyne/cm) and 29.8 mN/m (dyne/cm), respectively, and permeation periods of 9 min and 53 s, 4 min and 25 s and 2 min and 23 s, respectively, showing improved surface activities. 1 g of each paste was dissolved in water to give a volume of 100 ml. 20 ml of the aqueous solution thus obtained and 1 g of a titanium white pigment or highly fine grains of calcium carbonate were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the particles in the solution. After adding 5 ml of a 30% aqueous solution of common salt, the mixture was shaken again and allowed to stand at room temperature under observing the dispersion and sedimentation condition. In the composition comprising the sucrose fatty acid ester alone, both dispersions immediately showed aggregation and sedimentation. On the other hand, in the compositions comprising 23% or more of the monoacylglycerophospholipid, each dispersion was stable even after 3 h. Example 27 Monoacylglycerophospholipid F and Ryoto Sugar Ester S-970® were mixed together at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. By the use of these paste, an emulsification stability test on corn salad oil and soy sauce was carried out in the same manner as described in Example 22. In the composition comprising the sucrose fatty acid ester alone, the separation of 2% of an oily phase required 7 days and the emulsion was broken after 21 days. In contrast thereto, the compositions comprising 12% or more of the monoacylglycerophospholipid, oily phase scarcely separated out after 60 days. Those comprising 19% or more of same showed excellent redispersibility. Example 28 Monoacylglycerophospholipid B and sorbitan monostearate (Emasol S 10-F®, mfd. by Kao Co., Ltd.) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test To 1 g of each paste, water was added to give a volume of 100 ml. To one-part (by volume) portions of the aqueous solution thus obtained, one-part (by volume) portions of a 0.2 M phthalate buffer solution (pH 3), a 20% aqueous solution of common salt and water were added to give an acidic solution, a saline solution and a control solution, respectively. These solutions were heated to 60°C for 10 min and allowed to cool indoor. In the composition comprising the sorbitan fatty acid ester alone, the dispersions in water thus formed immediately shown aggregation and precipitation under the acidic condition or in the presence of the salt. In the compositions comprising 10 to 30% of the monoacylglycerophospholipid, a milky turbidity proceeded slowly while little increase in the turbidity was observed, i.e., showing almost the same transmittance as those of the controls, in the compositions comprising 40% or more of same. The transmittance at 720 nm of the control dispersion of the composition comprising the sorbitan fatty acid ester alone determined immediately after the preparation was 0.4% and a precipitate was observed therein after allowing it to stand for 1 day. The transmittances of the control, acidic and saline solutions of the composition comprising 40% of the monoacylglycerophospholipid determined after 1 day were 44%, 40% and 29%, respectively. On the other hand, those of the control, acidic and saline solutions of the composition comprising 50% of same were 62%. 62% and 63%, respectively. (2) Emulsification stability test on corn salad oil and soy sauce 2.5 g of each paste, 50 g of corn salad oil and 56 g of "Koikuchi" soy sauce were emulsified in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 55°C and 13,000 rpmin for 6 min. The emulsion thus formed was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 8 h and 40°C for 16 h. As a result, most of the oily component separated out after 2 days in the composition comprising the sorbitan fatty acid ester alone. In contrast thereto, only 5% and 3% of an oily phases separated out after 7 days and two months, respectively, in the compositions comprising 10% and 20% of the monoacylglycerophospholipid. Those comprising 30% or more of same showed scarcely any separation. (3) Surface activity test 5 g of each paste was dissolved in water to give a volume of 200 ml. The surface tension of the aqueous solution thus obtained was determined at 25°C with a surface tension meter (CBVP A-3®, mfd. by Kyowa Kagaku Co., Ltd.) while the permeability of same was determined at 25°C as a permeation period according to Kimura's canvas disc method. As a result, the composition comprising the sorbitan fatty acid ester alone showed a surface tension of 46.4 mN/m (dyne/cm) and a permeation period of more than 1 h. On the other hand, those comprising 30% and 50% of the monoacylglycerophospholipid showed surface tensions of 31.9 mN/m (dyne/cm) and 30.8 mN/m (dyne/cm), respectively, and permeation periods of 6 min and 3 s and 3 min and 16 s, respectively. The permeation period of a sucrose fatty acid ester (Ryoto Sugar Ester S-1670®), which has the highest permeability among all nonionic surfactants approved as food additives in Japan, was 7 to 8 min. Example 29 By the use of monoacylglycerophospholipid B and sorbitan monooleate (Span-80®, mfd. by Kao Co., Ltd.), mixtures of the sorbitan fatty acid ester and monoacylphospholipid at ratios of 80/20 and 60/40 were prepared and each mixture was formulated into a 20% by weight aqueous paste. An emulsification stability test on corn salad oil and soy sauce was carried out by the use of these pastes in the same manner as described in Example 28. For the composition comprising the sorbitan fatty acid ester alone, the emulsion was immediately broken. On the other hand, in the composition comprising 20% of the monoacylglycerophospholipid, 2% and 5% of an oily phase separated out after 1 month and 2 months, respectively. In the composition comprising 40% of same, only 2% of an oily phase separated out after 2 months. The same procedure was repeated except that the soy sauce was replaced by reconstituted orange juice. As a result, 2% and 30% of an oily phase separated out after 5 days and 1 month, respectively, in the composition comprising the sorbitan fatty acid ester alone. In contrast thereto, scarcely any separation was observed in the compositions comprising 20% or more of the monoacylglycerophospholipid after 2 months. Example 30 Monoacylglycerophospholipid D and Emasol S-10-F® were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test The procedure of Example 28 was followed. As a result, the control solution of the composition comprising the sorbitan fatty acid ester alone showed a transmittance of 0.4% at 720 nm after 1 day. When allowed to stand, the solution showed precipitation. The control and acidic solutions of the composition comprising 22% of the monoacylglycerophospholipid showed transmittances of 21% and 13%, respectively. The control, acidic and saline solutions of the composition comprising 39% of same showed transmittances of 42%, 32% and 15%, respectively. The control, acidic and saline solutions of the composition comprising 49% of the same showed transmittances of 62%, 61% and 62%, respectively. (2) Emulsification stability test on corn salad oil and soy sauce The procedure of Example 28 was followed. As a result, most of the oily component separated out after 2 days in the composition comprising the sorbitan fatty acid ester alone. On the other hand, scarcely any separation was observed in the composition comprising 14% of the monoacylglycerophospholipid. In this case, emulsified particles aggregated within a creamy phase and the redispersibility was somewhat poor. However, the compositions comprising 22% or more of same showed scarcely any separation and stable emulsification. (3) Emulsification stability test on corn salad oil and orange juice The procedure of Example 29 was followed. As a result, scarcely any separation of an oily phase was observed after 2 months in the compositions comprising 14% or more of the monoacylglycerophospholipid, although those containing approximately 22% of the monoacylglycerophospholipid showed a somewhat poor redispersibility of the creamy phases. However, those comprising 30% or more of the monoacylglycerophospholipid showed excellent redispersibility. (4) Dispersion test on fine inorganic particles 2 g of each was dissolved in water to give a volume of 200 ml. 20 ml of the aqueous solution thus obtained and 1 g of a titanium white pigment were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the pigment in the solution. Then it was allowed to stand at room temperature under observing the dispersion and sedimentation condition. The composition comprising the sorbitan fatty acid ester alone showed aggregation and sedimentation after 20 min. In contrast thereto, the composition comprising 22% of the monoacylglycerophospholipid showed scarcely any sedimentation and stable dispersion after 1 h. Example 31 Monoacylglycerophospholipid B and a glycerol fatty acid monoester containing 97% of the monoester (Emulsy MS®, mfd. by Riken Vitamin Co., Ltd.; mainly comprising stearic acid) were mixed at various weight ratios and each mixture thus obtained was formulated into a 20% by weight aqueous paste. (1) Acid- and salt-resistance test Water was added to each paste to give a 1% aqueous solution. To one-part (by volume) portions of the obtained aqueous solution, one-part (by volume) portions of a 0.2 M phthalate buffer solution (pH 3), a 20% aqueous solution of common salt and water were added to give an acidic solution, a saline solution and a control solution, respectively. Each solution was heated to 60°C for 10 min and then allowed to cool at room temperature. In the composition comprising the glycerol fatty acid monoester, no dispersion in water was observed, because it was insoluble or nondispersible in water. On the other hand, in the compositions comprising 10 to 30% of the monoacylglycerophospholipid, a milky turbidity proceeded slowly. Those comprising 40% or more of same showed little or substantially no turbidity. After cooling, the control, acidic and saline solutions of the composition comprising 40% of the monoacylglycerophospholipid showed transmittances at 720 nm of 96%, 59% and 91%, respectively, while the control, acidic and saline solutions of the composition comprising 50% of same showed transmittances at 720 nm of 98%, 97% and 99%, respectively. (2) Emulsification stability test on liquid paraffin and aqueous solution of common salt 2.5 g of each paste, 35 ml of liquid paraffin and 70 ml of a 5% aqueous solution of common salt were emulsified in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 45°C and 12,000 rpmin for 5 min to give a oil-in-water emulsion. This emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. In the composition comprising the glycerol fatty acid monoester alone, emulsification was impossible and an oily phase separated out immediately. In the composition comprising 20% of the monoacylglycerophospholipid, 4 days were required for the separation of 2% by volume of an oily phase. In this case, the oily phase could be redispersed by shaking after creaming. In the composition comprising 10% of the monoacylglycerophospholipid, 4% of an oily phase separated out after 1 day, although it could be redispersed by shaking. Separately, 0.15 g and 0.05 g of the monoacylglycerophospholipid alone, i.e., giving the same concentrations of the monoacylglycerophospholipid as those comprising 30% and 10% of the monoacylglycerophospholipid, were added. Thus 22% of an oily phase separated out after 20 days in the former (0.15 g) case, while 13% of an oily phase separated out after 1 day in the latter (0.05 g) case, showing that the combined use of the monoacylglycerophospholipid with the glycero fatty acid monoester improved the effects. (3) Emulsification stability test on corn salad oil and soy sauce 2.5 g of each paste, 50 g of corn salad oil and 56 g of "Koikuchi" soy sauce were emulsified together in a turbo type homogenizer (AM-8®, mfd. by Nippon Seiki Co., Ltd.) at 55°C and 13,000 rpmin for 6 min. The obtained emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, an oily phase immediately separated out and emulsification was impossible in the composition comprising the glycerol fatty acid monoester alone. The composition comprising 20%, 30% and 50% or more of the monoacylglycerophospholipid showed emulsification stabilities, as expressed by the amounts of separated oily phases after 30 days, of 7%, 2% and nearly 0%, respectively. (4) Surface activity test To each paste, water was added to give an aqueous solution of 0.5% in concentration. The surface tension of the obtained aqueous solution was determined at 25°C with a surface tension meter (CBVP A-3®, mfd. by Kyowa Kagaku Co., Ltd.) and the permeability thereof was determined according to Kimura's canvas disc method at 25°C. Fig. 1 shows the results wherein - O - O - represents the permeation period while - X - X - represents the surface tension. In the composition comprising the glycerol fatty acid monoester alone, each determination was impossible since it was insoluble in water. Fig.1 obviously shows that the combined use of the monoacylglycerophospholipid and the glycerol fatty acid monoester exhibits synergistic effects. (5) β-Carotene solubilization test 5 g of each paste was dissolved in water to give a volume of 100 ml. 10 ml of the aqueous solution thus obtained and 10 mg of powdery β-carotene were introduced into a 30-ml test tube and shaken therein at 30°C for 42 h to thereby solubilize the β-carotene. The solubilized matter was then centrifuged at 3000 rpmin. To 2 ml of the obtained supernatant. 8 ml of a mixture of chloroform and ethanol (1 : 4) was added and the absorbance of the resulting mixture was determined at 455 nm with a spectrometer. The composition comprising the monoacylglycerophospholipid alone showed an absorbance of 0.581 while the compositions comprising 85% and 70% of the monoacylglycerophospholipid showed absorbances of 0.543 and 0.411, respectively. (6) Dispersion test on fine inorganic particles 1 g of each paste was dissolved in water to give a volume of 100 ml. 20 ml of the aqueous solution thus obtained and 1 g of a titanium white pigment were introduced into a Nessler tube and vigorously shaken vertically to thereby disperse the pigment in the solution. Then the dispersion was allowed to stand under observing the sedimentation condition. 5 ml of a 30% aqueous solution of common salt was further added and the mixture was shaken again and allowed to stand at room temperature under observing the dispersion and sedimentation condition. As a result, in the composition comprising the monoacylglycerophopsholipid alone, aggregation and sedimentation were immediately observed regardless of the addition of the saline solution. In contrast thereto, the compositions comprising 10 to 20% of the monoacylglycerophospholipid showed sedimentation after 1 h when the saline solution was added. However no sedimentation was observed in those cases wherein no saline solution was added. The compositions comprising 90%, 75% and 30% of the monoacylglycerophospholipid showed no sedimentation regardless of the addition of the saline solution. The same test was carried out by the use of highly fine grains of calcium carbonate. As a result, the composition comprising the monoacylglycerophospholipid alone rather accelerated the aggregation and precipitation. However, the compositions comprising 30 to 70% of same showed stable dispersion regardless of the addition of the saline solution. Example 32 Monoacylglycerophospholipid H and Emulsy MS® at various weight ratios were dissolved in ethanol and the ethanol was distilled off in vacuo to thereby give solid products. Each solid product thus obtained was ground to give a composition in the form of grains. (1) Oil solubility test 2 g of each composition was dissolved in liquid paraffin (Carnation Oil, mfd. by Witco Chemical Corp.) under heating and stirring. As a result, the composition comprising the monoacylglycerophospholipid alone was completely insoluble therein. On the other hand, the compositions comprising the glycerol fatty acid ester and monoacylphospholipid at a ratio exceeding 30/70 (glycerol fatty acid monoester and monoacylglycerophospholipid at a ratio exceeding 39/61) were highly soluble therein. In the compositions comprising the glycerol fatty acid ester in a lower amount than the one as defined above, the solubility increases with an increase in the content of the glycerol fatty acid ester. A comparative solubilization test was carried out by the use of a composition comprising 10% of polyglycerol fatty acid ester having an HLB of 15 (Sun Soft Q-17-U®) and 90% of glycerol fatty acid monoester. However, the comparative composition was insoluble therein. (2) Surface activity test The surface tension and permeability of each composition were determined in the same manner as described in Example 31. In the composition comprising the glycerol fatty acid ester alone, a determination was impossible since it was insoluble in water. As a result, the composition comprising the monoacylglycerophospholipid alone showed a surface tension of 30.9 mN/m (dyne/cm) and a permeation period of 58 s. On the other hand, the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 15/85, 3070 and 45/55 showed surface tensions of 30.6 mN/m (dyne/cm), 30.7 mN/m (dyne/cm) and 30.3 mN/m (dyne/cm), respectively, and permeation periods of 63 s, 99 s and 185 s, respectively. The composition comprising these materials at ratio of 70/30 showed a surface tension of 28.5 mN/m (dyne/cm). (3) Emulsification stability test on corn salad oil and soy sauce 0.5 g of each composition comprising 50% or more of the monoacylglycerophospholipid was dissolved in 5 ml of water, while 0.5 g of each composition comprising 40% or less of same was dissolved or dispersed in an oil or fat followed by adding 5 ml of water thereto. By the use of each aqueous composition thus obtained, 50 g of corn salad oil and 56 g of "Koikuchi" soy sauce, an emulsion of the corn salad oil and the soy sauce was obtained in the same manner as described in Example 31. Then the emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature to 20°C for 12 h and to 35°C for 12 h. As a result, an oily phase immediately separated from an aqueous phase of the composition comprising the glycerol fatty acid monoester alone. 2% of an oily phase separated out after 15 days in the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 50/50. On the other hand, no separation was observed in the compositions comprising the two materials at ratios of 30/70 to 10/90. (4) Dispersion test on fine inorganic particles. By the use of a 0.2% aqueous solution of each composition, the dispersibilities of titanium white pigment and highly fine grains of calcium carbonate were determined in the same manner as described in Example 31. In the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 10/90 to 50/50, to which no saline solution was added, the titanium white pigment showed scarcely any precipitation. In the compositions comprising the same at ratios of 60/40 to 90/10, a stable dispersion was observed although precipitation slowly proceeded. When the saline solution was added, no change was observed in the former cases while the dispersabilities were slowly lowered in the latter cases. In the composition comprising the glycerol fatty acid ester and phosphatide at ratios of 10/90 to 80/20, to which no saline solution was added, the highly fine grains of calcium carbonate showed excellent dispersion after 2 h. When the saline solution was added thereto, a slight decrease in the dispersabilities was observed in the compositions comprising the same at ratios of 60/40 to 80/20. (5) β-Carotene solubilization test By the use of a 1% aqueous solution of each composition, β-carotene was solubilized in the same manner as described in Example 31. As a result, the composition comprising the phosphatide alone showed an absorbance at 455 nm of 0.924. On the other hand, the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 20/80 and 30/70 showed absorbances of 0.763 and 0.529, respectively. Example 33 Monoacylglycerophospholipid B and a distilled glycerol monoester of unsaturated fatty acid (Emulsy MO®, mfd. by Riken Vitamin Co., Ltd.; mainly comprising linoleic acid and having an iodine value of 76) were dissolved in ethanol in the same manner as described in Example 32. After distilling off the ethanol in vacuo, a semisolid composition was obtained. (1) Emulsification stability test on corn salad oil and soy sauce By the use of each composition, an emulsion of corn salad oil and "Koikuchi" soy sauce was prepared in the same manner as described in Example 32. The obtained emulsion was introduced into a glass cylinder and stored in an incubator while periodically changing the temperature, i.e., 20°C for 12 h and 35°C for 12 h. As a result, an oily phase immediately separated from an aqueous phase in the composition comprising the glycerol fatty acid monoester alone. In the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 70/30 to 50/50, the stabilities gradually increased. In the composition comprising the materials at a ratio of 50/50, 2% of an oily phase separated out after 30 days. On the other hand, no separation was observed after 30 days in the compositions comprising same at ratios of 30/70 to 10/90. (2) Emulsification stability test on corn salad oil and orange juice The procedure as described in Example 31 with regard to the emulsification stability test on corn salad oil and soy sauce was followed except that the soy sauce was replaced by reconstituted orange juice (pH 3.5). In the composition comprising the glycerol fatty acid monoester alone, the emulsion was immediately broken and an oily phase separated out. In contrast thereto, in the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 70/30 to 50/50, the degree of separation of oily components gradually decreased. In the compositions comprising same at ratios of 50/50 to 10/90, scarcely any separation was observed. Example 34 By the use of monoacylglycerophospholipid E and Emulsy MS®, compositions were prepared in the same manner as described in Example 32. (1) Acid- and salt-resistance test To 1 g of each composition, water was added to give a volume of 100 ml. By the use of the aqueous solution thus obtained, the procedure of Example 31 was followed. As a result, the control, acidic and saline solutions of the composition comprising the phosphatide alone showed transmittance at 720 nm of 97%, 84% and 95%, respectively. On the other hand, the control, acidic and saline solutions of the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 20/80 showed transmittances of 99%, 98% and 93%, respectively. The control, acidic and saline solutions of the composition comprising same at a ratio of 30/70 showed transmittances of 99%, 96% and 98%, respectively. Example 35 By the use of the monoacylglycerophospholipid E and Emulsy MO®, compositions were prepared in the same manner as described in Example 33. (1) Acid- and salt-resistance test By the use of a 0.5% aqueous solution of each composition, the prodecure relating to the acidic solutiuon of Example 31 was followed. As a result, the control and acidic solutions of the composition comprising the phosphatide alone showed transmittances at 720 nm of 97% and 84%, respectively. The control and acidic solutions of the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 10/90 showed transmittances of 99% and 92%, respectively. While the control and acidic solutions of the composition comprising same at a ratio of 50/50 showed transmittances of 91% and 86%, respectively. (2) Emulsification stability test on corn salad oil and soy sauce An emulsification stability test on corn salad oil and soy sauce was carried out in the same manner as described in Example 33. As a result, 4% of an oily phase separated out after 30 days in the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 70/30. In contrast thereto, the compositions comprising same at ratios of 50/50 to 10/90 showed scarcely any separation, suggesting high stabilities. (3) Emulsification stability test on corn salad oil and orange juice An emulsification stability test on corn salad oil and reconstituted orange juice was carried out in the same manner as described in Example 33. As a result, the emulsion was immediately broken in the composition comprising the glycerol fatty acid ester alone. 2% of an oily phase separated out after 30 days in the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 60/40. On the other hand, the compositions comprising same at ratios of 50/50 to 10/90 showed scarcely any separation after 30 days, suggesting high stabilities. Example 36 Monoacylglycerophospholipid J and Emulsy MS were mixed both in the form of powders to give compositions of various weight ratios. (1) Surface activity test By the use of a 0.5% aqueous solution of each composition, the surface tension and permeability both at 30°C were determined in the same manner as described in Example 31. Fig. 2 shows the result. Example 37 Monoacylglycerophospholipid K and Emulsy MS® were blended together and dissolved in ethanol. After distilling off the ethanol in vacuo, compositions of various weight ratios were obtained. (1) Surface activity test By the use of a 0.5% aqueous solution of each composition, the surface tension at 25°C was determined in the same manner as described in Example 31. As a result, the composition comprising the phosphatide alone showed a surface tension of 36.4 mN/m (dyne/cm). On the other hand, the compositions comprising the glycerol fatty acid ester and phosphatide at ratios of 10/90, 20/80, 30/70, 40/60, 50/50, 60/40 and 70/30 showed surface tensions of 34.6 mN/m (dyne/cm), 32.9 mN/m (dyne/cm), 31.7 mN/m (dyne/cm), 31.6 mN/m (dyne/cm), 31.9 mN/m (dyne/cm), 32.4 mN/m (dyne/cm) and 33.3 mN/m (dyne/cm), respectively. Example 38 Monoacylglycerophospholipid E was mixed with a glycerol fatty acid ester composition containing 88% of glycerol fatty acid monoesters, which was obtained by blending an undistilled glycerol fatty acid ester of hardened beef tallow (Sun Soft 2500®, mfd. by Taiyo Kagaku Co., Ltd.) containing 51% of glycerol fatty acid monoesters with Emulsy MS® at a ratio of 2 : 8, to obtain compositions in the same manner as described in Example 32. (1) Acid- and salt-resistance test Water was added to each composition to give a 1% aqueous solution. By the use of the obtained solution, the procedure of Example 31 was followed. After cooling, the control and acidic solutions of the composition comprising the phosphatide alone showed transmittances at 720 nm of 97% and 84%, respectively. The control and acidic solutions of the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 10/90 showed transmittances of 96% and 85%, respectively. The control and acidic solutions of the composition comprising same at a ratio of 20/80 showed transmittances of 91% and 89%, respectively. The control and acidic solutions of the compositions comprising same at a ratio of 30/70 showed transmittances of 88% and 84%, respectively. Example 39 Seven parts by weight of monoacylglycerophospholipid L and three parts by weight of Emulsy MS® were blended and the mixture was heated in water to thereby give a 20% by weight aqueous paste. To 5 g of the obtained paste, water was added to give 200 ml of a solution. Then the surface tension of this solution was determined at 25°C while the permeability thereof was determined according to the canvas disc method at 25°C as described in Example 31. As a result, it showed a surface tension of 29.8 mN/m (dyne/cm) and a permeation period of 7 min and 17 s. When compared to the composition comprising the phosphatide alone, i.e., having a surface tension of 33.6 mN/m (dyne/cm) and a permeation period of 12 min and 45 s, an improvement was observed. Example 40 Monoacylglycerophospholipid M and Emulsy MS® were mixed to give composition in the same manner as described in Example 33. Water was added to each composition to give a 0.5% aqueous solution. Then the acid-resistance of the obtained solution was determined in the same manner as described in Example 31. After cooling, the control and acidic solutions of the composition comprising the glycerol fatty acid ester and phosphatide at a ratio of 10/90 showed transmittances of 67% and 68%, respectively, while the control and acidic solutions of the composition comprising the same at a ratio of 20/80 showed transmittances of 60% and 61%, respectively.

Claims: A surfactant composition which comprises (A) partially deacylated glycerophospholipid(s) comprising at least 30% by weight, based on the total phosphatide content, of monoacylglycerophospholipid(s) and (B) one or more compounds selected from the group consisting of polyglycerol fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters and glycerol fatty acid monoesters, wherein the weight ratio of (B) to (A) is 10/90 to 95/5. The surfactant composition of claim 1, wherein said compound(s) (B) are selected from mono-, di- and polyesters of saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms with polyglycerol, sucrose, glycerol and polyols selected from sorbitol, sorbitan and sorbide. The surfactant composition of claim 1, wherein said monoacylglycerophospholipid(s) (A) comprises monoacylphosphatidylcholine as the main component and simultaneously contains monoacylphosphatidylethanolamine as well as one or more monoacylglycerophospholipids selected from the group consisting of monoacylphosphatidylinositol, monoacylphosphatidic acid and monoacylphosphatidylserine. The surfactant composition of claim 2, wherein said polyglycerol fatty acid ester(s) are selected from the group consisting of mono-, di- and polyesters of polyglycerol having a degree of polymerization of 4 or above with saturated and/or unsaturated fatty acids having 12 to 22 carbon atoms. The surfactant composition of claim 1, wherein said compounds (B) are polyglycerol fatty acid esters, and said ratio of said compound(s) (B) and said monoacylglycerophospholipid(s) (A) in said partially deacylated glycerophospholipids(s) is 40/60 to 95/5 on a weight basis. The surfactant composition of claim 5, wherein said polyglycerol fatty acid esters are polyglycerol fatty acid esters which have an HLB of 11 or above. The surfactant composition of claim 1, wherein said compounds (B) are selected from the group consisting of polyglycerol fatty acid esters and sucrose fatty acid esters, and said ratio of said compounds (B) and said monoacylglycerophospholipid(s) (A) in said partially deacylated glycerophospholipid(s) is 40/60 to 90/10 on a weight basis. The surfactant composition of claim 7, wherein said polyglycerol fatty acid esters are polyglycerol fatty acid esters which have an HLB of less than 11. The surfactant composition of claim 1, wherein said compounds (B) are sorbitan fatty acid esters, and said ratio of said compounds (B) and said monoacylglycerophospholipid(s) (A) in said partially deacylated glycerophospholipid(s) is 40/60 to 80/20 on a weight basis. The surfactant composition of claim 1, wherein said compounds (B) are glycero fatty acid monoesters, and said ratio of said compounds (B) and said monoacylglycerophospholipid(s) (A) in said partially deacylated glycerophospholipid(s) is 10/90 to 90/10 on a weight basis.

Inventors: FUJITA, SATOSHI, NAKAI, EIJI, NOIKE, AKIRA
Applicants: ASAHI DENKA KOGYO KABUSHIKI KAISHA, NIPPON SHOJI KABUSHIKI KAISHA
Application year: 1987
Main classification: B01F17
IPC codes: A61K8, A61Q19, B01F17