Energy-curable pressure-sensitive adhesives and process for producing pressure-sensitive adhesive stock

Abstract: A radiation-curable, pressure-sensitive-adhesive is formed of at least one monomer having a glass-­ transition temperature greater than about -25°C and an entanglement molecular-weight less than about 20,000; at least one monomer having a glass-transition temperature less than about -25°C and an entangle­ ment molecular-weight greater than about 20,000; and at least one tackifier monomer having a glass-­ transition temperature greater than -25°C and an entanglement molecular-weight of at least about 20,000 and present in an interpolymerized amount sufficient to form an interpolymer having a glass-­ transition temperature less than about -25°C and an entanglement molecular-weight greater than about 20,000. Cure is preferably by electron beam radiation, and a multifunctional monomer is preferably provided to improve shear, such monomer for example being pentaerythritol triacrylate, tetraethyleneglycol dimethacrylate or trimethylol propane trimethacrylate.

Description: The present invention relates to energy-curable pressure-sensitive adhesives and process for producing pressure-sensitive adhesive stock. More particularly, this invention is directed to curing by radiation, particularly electron-beam (EB) radiation, of pressure-sensitive, acrylic-based interpolymers containing an interpolymerized amount of tackifier monomers, as defined herein. U.S.-A-2,544,692 discloses copolymerization of an acrylic acid with minor amounts of a fumarate diester. Emulsion and bulk polymerization are stated as being feasible. A pressure-sensitive-adhesive product is disclosed. U.S.-A-2,642,414 discloses copolymers of esters of methacrylic acid, a saturated aliphatic monohydric alcohol, a maleinoid ester of a saturated aliphatic monohydric alcohol of from 4 to 14 carbon atoms, and certain organic acids. The maleinoid esters include dibutyl fumarate. The products of the reaction are disclosed to have utility in modifying the pour point of hydrocarbon oils. U.S.-A-4,220,744 discloses the use of two-stage bulk polymerization to form a viscous liquid containing interpolymerized amounts of dialkyl esters of fumaric or maleic acid. The curing of monomers as well as polymers to induce or improve pressure-sensitive properties is old in the art. Of relevance to the overall concept is U.S.-A-3,725,115. This patent discloses the preparation of pressure-sensitive adhesives by irradiating a hot-melt composition. The compositions disclosed are coated on release liners and subjected to electron-beam radiation of a dosage of from 6 to 8 megarad (60 to 80 kiloGray), leading to high peel strengths. The improved adhesive is then transferred to the face stock. U.S.-A-4,069,123 discloses the UV curing of homopolymers of alkyl esters of acrylic and methacrylic acids and of copolymers of such monomers with other comonomers, including C₁-C₄ alkyl half-esters of maleic and fumaric acids. The polymers are disclosed as being formed by bulk, solvent or emulsion polymerization. It has not been heretofore known to use C₁-C₃ lower alkyl diesters of unsaturated dicarboxylic acids in combination with energy curing, to enhance adhesive properties. This, in part, is the subject matter of the present invention. The present invention is now set out in the following description which is given by way of example only. According to the present invention there are provided hot-melt-coatable, radiation-curable acrylic polymers produced by interpolymerization of at least one first monomer having a glass-transition temperature (Tg) less than -25°C and an entanglement molecular-weight (Me) greater than 20,000; at least one second monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000; and at least one tackifier monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight greater than 20,000, the tackifier monomer being present in an amount of up to 30% by weight, preferably 5 to 30% by weight, of the total monomers present to provide a polymer having an entanglement molecular-weight greater than 20,000 and a glass-transition temperature less than -25°C. It is preferred that the tackifier monomer be an alkyl diester of an unsaturated dicarboxylic acid containing 4 carbon atoms in which each alkyl group independently contains from 1 to 3 carbon atoms. Isomeric alkyl acrylates and alkyl methacrylates may also be used as tackifier monomers. The acrylic polymers of the present invention are radiation-curable. Electron-beam curing is presently preferred. Even though formed by bulk polymerization, the acrylic polymers exhibit properties which enable replacement of solvent-formed, acrylic pressure-sensitive adhesives. As indicated, the polymers produced in accordance with the present invention are controlled as to molecular properties by the tackifier monomer selected, in combination with the balance of the total monomer composition. The copolymers provided in accordance with the present invention comprise from 55% to 90% by weight based on the total weight of the monomers, of a first monomer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000; and up to 30% by weight, preferably from 5% to 30% by weight, based on the weight of total monomers, of at least one tackifier monomer; the balance comprising a second monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000. The preferred second monomers are unsaturated carboxylic acids, preferably acrylic acid. The preferred first monomers are alkyl acrylates, preferably 2-ethylhexyl acrylate and/or butyl acrylate. The presently preferred tackifier monomer is diethyl fumarate. Products are formed by directly or indirectly casting onto a face material, the adhesive as disclosed herein, preferably one including a multifunctional monomer as defined herein. The hot-melt application is preferred. Application from a solvent is also feasible. The cast adhesive is cured by radiation, preferably EB radiation. For EB radiation, the multifunctional monomer reduces the energy required to improve adhesive properties, and in any event will be used in an amount up to 200 kiloGray (kGy), preferably up to 100 kiloGray. Also according to the present invention, there is provided a process for the production of a pressure-sensitive adhesive stock, which process comprises: a) providing onto a substrate selected from a face material and a surface capable of transferring an adhesive layer to a face material, a coating of a pressure-sensitive adhesive (e.g a hot melt adhesive) comprised of an interpolymer formed of: at least one first monomer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000 and present in an amount of from 55% to 90% by weight based on the total weight of the monomers; at least one second monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000, said second monomer being present in an amount of up to 25% by weight based on the total weight of the monomers; and at least one tackifier monomer having a glass-transition temperature greater -25°C and an entanglement molecular-weight of at least 20,000, said tackifier monomer being present in an amount of up to 30% by weight, preferably 5 to 30% by weight, of the total monomers present to provide a hot-melt adhesive having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000; and b) subjecting the pressure-sensitive-adhesive layer to the action of radiation-energy crosslinking, to cause an increase in shear strength of the interpolymer. Preferred embodiments of the invention will now be described in more detail by way of example only with reference to the accompanying drawings, in which: FIG. 1 is a diagram of glass transiton temperature versus entanglement molecular-weight and graphically illustrates the regions occupied by the tackifier monomer(s), first monomers, second monomers, and rubber-forming polymers when amorphous, wherein: PI = Polyisoprene PB = Polybutadiene PDMS = Polydimethyl Siloxane PE = Polyethylene S = Styrene MMA = Methyl Methacrylate AA = Acrylic Acid VA = Vinyl Acetate MA = Methyl Acrylate EA = Ethyl Acrylate BA = Butyl Acrylate 2-MBA = 2-Methyl Butyl Acrylate 2-EHA = 2-Ethyl Hexyl Acrylate DBF = Dibutyl Fumarate t-BA = t-Butyl Acrylate MBM = Mono-Butyl Maleate β-CEA = β-Carboxy Ethyl Acrylate 2-HEA = 2-Hydroxy Ethyl Acrylate BMA = Butyl Methacryalte DMF = Dimethyl Fumarate DEF = Diethyl Fumarate DPF = Dipropyl Fumarate FIG. 2 shows the region in which a pressure-sensitive adhesive can be formulated using a first monomer, a second monomer, and a tackifier monomer in accordance with the present invention. FIGS. 3 and 4, respectively, show 180° peel and loop tack in Newtons per meter, as well as 70°C shear and room-temperature shear at 500g load and 1.27cm x 1.27cm overlap, in kiloseconds, for a pressure-sensitive adhesive provided in accordance with the present invention and containing 12 mole % diethyl fumarate, 78 mole % butyl acrylate, 10 mole % acrylic acid, and 2% by weight pentaerythritol triacrylate (PETA) at various dosage levels in kiloGray (kGy). Such an adhesive is applied to a facestock at a coating weight of about 47 g/m². FIGS. 5 and 6 compare the properties of the EB-cured composition, with and without the use of PETA (2%), for a polymer of the same monomer composition but differing in molecular properties (e.g. molecular weight). Coating weight is about 36 g/m². The present invention is directed to the use of uncommon tackifier monomers to provide radiation-curable, preferably electron-beam-curable, acrylic pressure-sensitive adhesives in which a tackifier monomer is effectively used to control the glass-transition temperature and entanglement molecular-weight of the polymer produced. The polymers formed in accordance with the present invention are preferably prepared by bulk polymerization and are typically applied as hot-melt adhesives, although solvent-casting techniques may also be used. Certain adhesive properties, such as high-temperature shear, are enhanced by radiation curing, preferably electron-beam (EB) curing, the necessary level of which is reduced by the presence of a multifunctional monomer. The polymers formed in accordance with the present invention comprise, in addition to the tackifier monomer, at least one first monomer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000, and at least one second monomer having glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000. The combination provides greater latitude as to polymer properties, as compared with two-component monomer systems. "Entanglement molecular-weight" as used herein is defined in Viscoelastic Properties of Polymers , 3rd Ed., John Ferry, John Wiley and Sons, 1981, incorporated herein by reference, and can be calculated using the formula: where: M = molar weight of group N = number of main chain carbon atoms per group V = group contribution to molar volume The formula, M, N, and V are explained and supported in detail in Computer Aided Design of Polymers and Composites , D. Kaeble, Marcel Dekker, Inc., 1985, pgs. 116 to 121. By "tackifier monomer" there is meant herein a monomer which, if homopolymerizable, would polymerize to a polymer which does not have pressure-sensitive adhesive properties and which has a glass-transition temperature greater than -25°C and an entanglement molecular-weight greater than 20,000. The monomers include lower alkyl diesters of unsaturated dicarboxylic acids in which the alkyl group contains up to 3 carbon atoms, acrylic acid esters of branched alcanols (e.g. t-butyl acrylate), and lower alkyl methacrylates (e.g. butyl methacrylate). The tackifier monomer is provided in an amount determined by the physical properties of the desired hot-melt, pressure-sensitive adhesives, typically in an amount of up to 30% by weight, preferably from 5% to 30% by weight, based on the total weight of the monomers. Diesters of unsaturated dicarboxylic acids useful as tackifier monomers are those in which the unsaturated carboxylic-acid-group contains 4 carbon atoms and in which each alkyl-diester group independently contains from 1 to 3 carbon atoms. Diesters of fumaric acid are preferred, with diethyl fumarate being most preferred. Also useful are acrylates such as tert-butyl acrylate, isopropyl acrylate and the like, and methacrylates such as normal or tert-butyl methacrylates and the like. Various functional monomers such as hydroxy ethyl acrylate, beta-carboxy ethyl acrylate, fumaric acid, itaconic acid and the like, may also be included. "First monomers" as used herein are monomers having a glass-transition temperature less than -25°C and an entanglement molecular-weight of greater than 20,000. Included are butyl acrylate, 2-methylbutyl acrylate, 2-ethylhexyl acrylate and the like, as well as the higher alkyl esters of unsaturated dicarboxylic acids containing 4 carbon atoms, such as dibutyl fumarate and the like. Butyl acrylate and/or 2-ethylhexyl acrylate are preferred. Their concentration is from 55% to 90% by weight, based on the total weight of the monomers. "Second monomers" as used herein are monomers which have a glass-transition temperature greater than -25°C and an entanglement molecular-weight of less than 20,000, and include, among others, some alkyl methacrylates such as methyl methacrylate; copolymerizable vinyl unsaturated monomers such as vinyl acetate; styrenic monomers such as styrene and the like; and unsaturated carboxylic acids such as acrylic acid and methacrylic acid. Acrylic acid is preferred, and is normally present in an amount of from 1% by weight to 15% by weight or less, based on the total weight of the monomers. The radiation-curable, hot-melt, pressure-sensitive polymers prepared in accordance with the present invention, in order to be useful as pressure-sensitive adhesives, must have a net effective glass-transition temperature of from about 30°C to 70°C below the use-temperature. For purposes of the instant invention, for the adhesive to be pressure-sensitive at ambient temperature (about 25°C), the criterion is that the polymers must have a glass-transition temperature of less than about -25°C, and the additional criterion is that the entanglement molecular-weight be greater than 20,000. Fig. 1 shows some of the tackifier monomers, first monomers, and second monomers in the regions in which they fall relative to each other. The lower-left-hand quadrant shows zones occupied by monomers which normally lead to the formation of amorphous rubbers, and as such are not included in the invention. As the polymers produced in accordance with the instant invention are radiation-curable by any suitable means, EB curing is preferably used to improve adhesive properties, particularly shear. The dosage levels for EB curing may be up to about 200 kiloGray (kGy), preferably up to about 100 kGy, and are materially reduced by inclusion of a multifunctional monomer. For EB cure, weight-average molecular-weight should be at least about 100,000. Ultraviolet radiation and gamma radiation may also be used, but are more costly and therefore less desired than EB curing. "Multifunctional monomers" as used herein means monomers having 2 or more pendant acrylate or methacrylate groups which enable crosslinking of the cast adhesive coating in the production of pressure-sensitive adhesive stock, tapes, labels and the like. Illustrative monomers include pentaerythritol triacrylate (PETA), triethyleneglycol diacrylate, triethyleneglycol dimethacrylate, trimethylol propane trimethacrylate, trimethylol propane triacrylate, tripropyleneglycol diacrylate, tripropyleneglycol dimethacrylate, 1,3-butyleneglycol dimethacrylate, tetraethyleneglycol dimethacrylate and the like. The concentration of multifunctional monomer may be up to 8% by weight, more preferably from 1% to 5% by weight, based on the total weight of the monomers of the hot-melt adhesive. Its inclusion enables the lowering of the energy dosage required to improve shear, particularly elevated-temperature shear. In production, the curable polymer is hot-melt-coated directly onto the facestock, or onto a transfer surface then applied to the facestock. The latter is preferred where uniformity of the adhesive coat is desired. EB-cure is then utilized to raise shear. The presently preferred compositions of the instant invention contain, on an interpolymerized basis, from 5% to 30% by weight diethyl fumarate; from 55% to 95% by weight butyl acrylate; and from 2% to 20% by weight acrylic acid, and include multifunctional monomers to reduce the energy required to induce crosslinking by EB radiation. Radiation-curable, preferably EB-curable, acrylic polymers may be produced in accordance with the present invention, by bulk and solvent polymerization using a free radical catalyst. Bulk polymerization is preferred for economy. With reference now to Fig. 2, there is shown a system for a first monomer (F), a second monomer (S), and a tackifier monomer (T). If only the first and second monomers were employed, the resultant polymers would have properties limited by the line F-S. By adding the third component T, there is created the shaded region of polymer properties, rather than the line F-S. Accordingly, the ability to control the glass-transition temperature and entanglement molecular-weight became flexible, which controllability remained unchanged during EB curing. In general, increase of the glass-transition temperature, in the shaded region, at constant entanglement molecular-weight results in an increase in shear, while an increase in entanglement molecular-weight in that region at constant glass-transition temperature results in a higher tack and lower shear, for a constant molecular-weight of the polymer produced. The addition of more components or functional monomers to the system will create quadrinary or higher points defining different zones within the shaded regions of pressure-sensitive adhesives. Figs. 3, 4, 5 and 6 show the effect of the use of a multifunctional monomer as the crosslinking aid to EB curing for the system 12 mole-percent diethyl fumarate, 78 mole-percent butyl acrylate, and 10 mole-percent acrylic acid. The polymer of Figs. 3 and 4 had a weight-average molecular-weight (Mw) of 267,000 and a ratio of weight-average molecular-weight (Mw) to number-average molecular-weight (Mn) of 24.9. As for Figs. 5 and 6, Mw was 266,000, and Mw/Mn was 11.1. EB curing and use of a multifunctional monomer as a crosslinking agent tended to reduce peel but increase shear. With reference to Fig. 4, room-temperature (RT) shear was greater than 24 hours for all dosages of EB cure. Figs. 5 and 6 also show the effect of non-use of a multifunctional monomer, i.e., even at higher dosage levels there was higher peel and tack but lower shear, compared to the use of a multi-functional monomer. The range of room-temperature shear for a given EB dosage with PETA addition is also shown in FIG. 6. The following Examples and Controls further illustrate the present invention. Viscosity (n) is always before cure. Example 1 and Control I There were formed by bulk polymerization, hot-melt adhesives based on diethyl fumarate and dibutyl fumarate. In each instance, the first monomer was butyl acrylate and the second monomer was acrylic acid. Table I shows peel-tack-shear performance after curing of the adhesive (Ex. 1) with 50 kGy for a system containing 2% by weight PETA, following application of the adhesive mixture at a coating level of 50 g/m² onto a release liner at 150°C, then laminating the coated release liner to a face material of 2 mil (0.05 mm) Mylar. A polymer system containing dibutyl fumarate was used as Control I. The substrate was stainless steel. As can be seen with almost equivalent concentrations of monomers, the diethyl fumarate provides an adhesive of improved properties, compared to dibutyl fumarate, at comparable melt viscosities. Example 2 and Control II A hot-melt pressure-sensitive adhesive was formed by bulk polymerization, and contained 15.7% by weight diethyl fumarate, 78.8% by weight butyl acrylate, 5.5% by weight acrylic acid, and had a glass-transition temperature of -41°C and an entanglement molecular-weight of 28,000. There was established the ability by EB cure to duplicate the characteristics (i.e., glass-transition temperature and calculated entanglement molecular-weight) of an acrylic based solution polymer. Testing results are shown in Table II. The solution polymer (Control II), after removal of the solvent by drying, had a melt viscosity at 150°C/2 sec⁻¹ of 800 Pa·s. The solution polymer was then chemically crosslinked. Examples 3 and 4 and Controls III and IV This study was to compare the pressure-sensitive adhesive performance of the invention vs. U.S.-A-4,220,744 as illustrated by its examples. The identification of the Examples and Controls (Examples from the '744 patent) are summarized in Table III. There was used dibutyl fumarate (DBF) and dioctyl fumarate (DOF), instead of diisobutyl fumarate and di-n-octyl fumarate, as the latter are unavailable in the United States. Use of a high level of initiator and no acid, gave very low melt viscosity, e.g., 1 Pa·s polymers. The hot melts of the invention contained acrylic acid and also had a viscosity at least ten times as high, e.g., from 10 to 100 Pa·s at 150°C/2 s⁻¹. Pressure-sensitive-adhesive performance of the Examples and Controls was evaluated after compounding each of them with 2% PETA and 600 ppm, of an anti-oxidant. The compounded hot melts were coated on a release liner at about 50 g/m² coat weight, laminated with a 2-mil (0.05 mm) Mylar, and EB-cured at 200 kv through the Mylar, at various dosages from 10 through 500 kGy. Adhesive properties were tested using stainless-steel panels. The 180° peel adhesion and loop-tack values were measured at 12 in/min.(30.5 cm/min.) crosshead speed. Creep resistance at room temperature (or RT shear) was tested with 1/2 x 1/2 in² (or 1.27cm x 1.27cm) lapping samples with a 1000g load. Pressure-sensitive-adhesive performance of the hot melts is summarized in Table IV. It is observed in Table IV that the materials made by following the '744 patent had zero cohesive strength (i.e., 0.0 @ 1000 g RTS) and very weak adhesion properties (i.e., 180° peel and loop tack) with a cohesive mode of failure. In comparison, the hot melts of the invention had good adhesion properties with a panel mode of failure and also with good cohesive strength. Description Fumarate Component/Composition, by Weight Wt % Initiator (Vazo 67 ) Viscosity @150°C/2 sec⁻¹ Example 3 DEF (DEF/BA/AA) 15/80/5 0.30 (DDM=0.1%) 78 Pa.S Example 4 DEF (DEF/BA/AA) 20/75/5 0.30 (DDM=0.1%) 52 Pa.S Control III DBF (DBF/BA) 10/90 2.50 0.8 Pa.S Control IV DOF (DOF/2-EHA) 12/88 1.08 1.6 Pa.S Adhesive Performance Description EB Dosage (kGy) PSA Performance 180° Peel (N/m) Loop Tack (N/m) 1000 g RTS (ks) Example 3 10 630 630 19.0 30 516 533 -- 50 446 534 3.4 Example 4 10 980 1068 0.1 30 831 884 1.4 50 656 893 6.5 Control III 10 18 88 0 30 48 184 0 50 79 262 0 Control IV 10 44 158 0 30 79 236 0 50 91 245 0 N/m = Newtons per meter ks = kilosecond

Claims: A radiation-curable pressure-sensitive adhesive comprising a copolymer formed of: at least one interpolymerized first monomer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000 and present in an amount of from 55% to 90% by weight based on the total weight of the monomers; at least one interpolymerized second monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000, said second monomer being present in an amount up to 25% by weight based on the total weight of the monomers; and at least one interpolymerized tackifier monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight of at least 20,000, the tackifier monomer being present in an amount of up to 30% by weight, preferably 5 to 30% by weight, of the total monomers present to form an interpolymer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000. A pressure-sensitive adhesive according to claim 1 in which the tackifier monomer comprises a compound selected from lower alkyl diesters of an unsaturated dicarboxylic acid containing 4 carbon atoms in which each alkyl group contains from 1 to 3 carbon atoms, for example diethyl fumarate, acrylic acid esters of branched alcanols, and lower alkyl methacrylates. A pressure-sensitive adhesive according to claim 1 or claim 2, in which the first monomer is selected from the group consisting of 2-ethylhexyl acrylate and butyl acrylate. A pressure-sensitive adhesive according to claim 1, 2 or 3, in which the second monomer is an unsaturated carboxylic acid, for example acrylic acid, and if acrylic acid is chosen, it is for example present in an amount of from 1% to 25% by weight based on the total weight of the monomers. A pressure-sensitive adhesive according to any of claims 1 to 4, which additionally contains up to 8% by weight of the total monomers, of a multifunctional monomer, for example 1 to 5% by weight thereof, said monomer having two or more pendant acrylate or methacrylate groups which enable cross-linking of a cast coating of the adhesive. A pressure-sensitive adhesive according to claim 1 or claim 2, which additionally contains 1% to 5% by weight of the total monomers, of a multifunctional monomer and the first monomer is selected from 2-ethylhexyl acrylate and butyl acrylate. A pressure-sensitive adhesive according to claim 1, wherein the first monomer is an alkyl acrylate selected from 2-ethylhexyl acrylate and butyl acrylate, the second monomer includes acrylic acid and the tackifier monomer includes diethyl fumarate. A pressure-sensitive adhesive according to claim 7, which additionally contains up to 8% by weight of the total monomers, of an interpolymerized multifunctional monomer as defined in Claim 5, for example 1 to 5% by weight thereof. A pressure-sensitive adhesive according to any of claims 1 to 6 or to claim 8, in which the multifunctional monomer is selected from pentaerythritol triacrylate, tetraethyleneglycol dimethacrylate, and trimethylol propane trimethacrylate. A pressure-sensitive adhesive according to any of claims 1 to 6 or to claim 7, 8 or 9, in which the adhesive is in layer form and is radiation-cured, for example is in layer form applied as a hot-melt, and is electron-beam cured. A radiation-cured pressure-sensitive adhesive layer produced from the adhesive according to claim 1, wherein the first monomer includes an alkyl acrylate selected from 2-ethylhexyl acrylate and butyl acrylate, the second monomer includes acrylic acid, and the tackifier monomer includes diethyl fumarate, the adhesive further including a multifunctional monomer as defined in claim 5, present in an amount of up to 8% by weight of the total monomers, for example from 1% to 5% by weight of the total monomers. A pressure-sensitive adhesive according to claim 11, in which the multifunctional monomer is selected from pantaerythritol triacrylate, tetraethyleneglycol dimethacrylate, and trimethylol propane trimethacrylate. A process for the production of a pressure-sensitive adhesive stock, which process comprises: a) providing onto a substrate selected from a face material and a surface capable of transferring an adhesive layer to a face material, a coating of a pressure-sensitive adhesive (e.g a hot melt adhesive) comprised of an interpolymer formed of: at least one first monomer having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000 and present in an amount of from 55% to 90% by weight based on the total weight of the monomers; at least one second monomer having a glass-transition temperature greater than -25°C and an entanglement molecular-weight less than 20,000, said second monomer being present in an amount of up to 25% by weight based on the total weight of the monomers; and at least one tackifier monomer having a glass-transition temperature greater -25°C and an entanglement molecular-weight of at least 20,000, said tackifier monomer being present in an amount of up to 30% by weight, preferably 5 to 30% by weight, of the total monmers present to provide a hot-melt adhesive having a glass-transition temperature less than -25°C and an entanglement molecular-weight greater than 20,000; and b) subjecting the pressure-sensitive-adhesive layer to the action of radiation-energy crosslinking, to cause an increase in shear strength of the interpolymer. A process according to claim 13 in which the pressure-sensitive adhesive is applied as a hot melt and is electron-beam cured either on the transfer surface prior to contact with the face material or when the pressure-sensitive adhesive is in contact with the face material. A process according to claim 13 or claim 14, in which the tackifier monomer is selected from the lower alkyl diesters of an unsaturated dicarboxylic acid containing 4 carbon atoms in which each alkyl group contains from 1 to 3 carbon atoms, for example diethyl fumarate, and acrylic acid esters of branched alcanols. A process as claimed in claim 13, 14 or 15, in which the first monomer is selected from 2-ethylhexyl acrylate and butyl acrylate. A process according to claim 13, 14, 15 or 16, in which the second monomer comprises an unsaturated carboxylic acid, for example acrylic acid, and if acrylic acid is chosen, it is for example present in an amount of from 1% to 25% by weight based on the total weight of the monomers. A process according to any of claims 13 to 17, in which there is present in the pressure-sensitive adhesive, when subject to cure, a multifunctional monomer in an amount of up to 8% by weight of the total monomers of the adhesive, for example 1 to 5% by weight. A process according to any of claims 13 to 18, wherein step (b) is performed using electron beam radiation to cause cross-linking. A process according to claim 19, wherein the first monomer includes an alkyl acrylate selected from the group consisting of 2-ethylhexyl acrylate and butyl acrylate; said second monomer includes acrylic acid and is present in an amount of up to 25%, for example up to 20% by weight based on the total weight of the monomers; the tackifier monomer includes diethyl fumarate, and the adhesive further comprises at least one multifunctional cross-linking monomer as defined in claim 5 present in an amount up to 8% by weight, for example 1 to 5% by weight based on the total weight of the monomers; the process involving subjecting the pressure-sensitive-adhesive layer to the action of electron-beam radiation to cause cross-linking, said electron-beam radiation being provided in an amount up to a level of 200 kiloGray and sufficient to cause an increase in shear strength of the interpolymer. A process according to claim 20, in which the pressure-sensitive adhesive is electron-beam cured prior to contact with the face material, or when in contact with the face material. A pressure-sensitive adhesive according to claim 18, 19, 20 or 21, in which the multifunctional monomer is selected from pentaerythritol triacrylate, tetraethyleneglycol dimethacrylate, and trimethylol propane trimethacrylate.

Inventors: BORDOLOI BINOY K, OZARI YEHUDA, PLAMTHOTTAM SEBASTIAN S, VAN HAM ROBERT, BORDOLOI, BINOY K., OZARI, YEHUDA, PLAMTHOTTAM, SEBASTIAN S., VAN HAM, ROBERT
Applicants: AVERY DENNISON CORP, AVERY DENNISON CORPORATION
Application year: 1987
Main classification: C08F246
IPC codes: C09J201, C09J7, C09J133, C09J4, C08F246, C08F222