Method for forming metal layer for a semiconductor device

Abstract: A method for forming a metal layer includes the steps of forming an insulation layer (62) having at least one step portion on a wafer (48, 61); and forming the metal layer (63) over the insulation layer. The metal layer is formed by depositing aluminium-based alloy by sputtering while the wafer is heated to a temperature higher than that which produces a solid solution in the aluminium-based alloy. As a result at the step portion, a good step coverage can be obtained and the surface of the aluminium alloy layer is planarized. At the same time, the method according to the present invention contributes to a prevention of deterioration in the quality of the layer by preventing the formation of a silicon rich layer adjacent the insulating layer with interferes with a subsequent patterning process. The method also enables the deposition process to be carried out at a later stage.

Description: The present invention relates to a technique for forming a metal layer and, more particularly, to a method for forming a metal layer by depositing aluminium (Al)-based alloy on a wafer by sputtering, and a semiconductor device formed by using that method. The metal layer forming technique according to the present invention can be widely used in the process of forming an electrical wiring for an integrated circuit (IC) or a large scale integration (LSI). Conventionally, an Al or Al-based alloy such as Al-1% by weight of silicon (Si), Al-2% by weight of copper (Cu), Al-1% by weight of Si-0.5% by weight of Cu, Al-1% by weight of Si-0.1% by weight of titanium (Ti), and the like are employed as the wiring materials for LSI's, since such alloys contribute to a decrease in the power dissipation, due to the low resistance thereof. The wiring layers using these alloys are usually formed by sputtering. Further, recent trends toward a higher integration and higher density of a semiconductor device, have led to the formation of a very steep step portion of a layer on which an Al wiring layer is formed. Therefore, considering, for example, a contact hole in the device, the ratio of the step height thereof to the width of the holes thereof is great. Accordingly, it is difficult to form an Al wiring layer having a good step coverage, i.e., a satisfactory degree of thickness, conforming to the shape of a layer thereunder. Solid State Technology, Vol. 22, No. 12, pages 66-72, 1979 shows the use of sputtering to deposit Al and Al-alloys for use as wiring layers in VLSI. A technique is known of piling a plurality of Al wiring layers as a multiple layer stack, development an even higher integration and higher density of a device. In this case, however, a problem arises in that, if the step coverage of an Al wiring layer is not good, an adverse influence is exerted upon the step coverage of an insulation layer to be formed thereupon and, furthermore, this adverse influence is extended to the step coverage of another Al wiring layer to be formed thereon, and thus it is difficult to obtain a multiple-layer wiring construction having a good shape. To cope with this problem, a metal layer must be deposited to obtain a planarized shape, particularly at a steep step portion, and thus obtain a good step coverage in the step portion. One proposed technique therefore, comprises forming an insulation layer having at least one step portion on the wafer; and forming said metal layer by depositing the aluminium-based alloy over the insulation layer while the wafer is heated. According to this method, since the surface of the wafer is heated, Al atoms deposited on the wafer can be easily moved on the surface thereof after the deposition process is completed, and as a result, the step coverage of the layer at the step portion can be improved. However, if the temperature of the wafer is too high, another problem arises as follows. When the temperature of the wafer is raised to a predetermined temperature and sputtering is effected, an admixture contained in the Al-based alloy, e.g., atoms of Si, Cu, and the like, precipitates in the vicinity of the interface between the Al wiring layer and the layer thereunder, e.g., a semiconductor layer, to such an extent that this precipitated admixture cannot be completely removed in a later process. Accordingly, this causes difficulties in, for example, a patterning of the Al wiring layer at the later stage, because it is technically difficult to remove both an unnecessary Al metal portion and the precipitated admixture such as Si, even if the patterning process is carried out by dry etching. Also as another technique of heating a wafer to form a wiring layer, a method is known in which a bias voltage of -500 to -1000 volts is applied to the wafer. According to this method, however, since the force of impact of Ar atoms incident on the wafer is very strong, A1 atoms once deposited on the wafer are resputtered therefrom, and the resputtered A1 atoms are deposited again. As a result, a drawback arises in that "roughness" occurs on the surface of the A1 wiring layer and a white turbidity appears thereon, resulting in a deterioration in the quality of the layer. According to a first aspect of this invention, a method for forming a metal layer by depositing an aluminium based alloy on a water by sputtering comprises forming an insulation layer having at least one step potion of the wafer; and forming said metal layer by depositing the aluminium-based alloy over the insulation layer while the wafer is heated; characterised in that the wafer is heated to a temperature higher than the temperature at which a solid solution is formed in the aluminium-based alloy. This technique provides a metal layer forming method which realizes a good step coverage at a step portion to make the surface of an A1 alloy layer substantially flat, while preventing a deterioration in the quality of the layer and so facilitating a subsequent patterning step based on a subsequent dry etching process. A particular embodiment of the present invention will now be described and contrasted with the prior art with reference to the accompanying drawings, in which:- Figure 1 is a sectional view illustrating an example of the step coverage in the construction of a typical A1 multiple-layer wiring; Figures 2A and 2B are sectional views illustrating examples of the step coverage for explaining an effect caused by sputtering with heating; Figure 3 is a sectional view illustrating an example of the step coverage for explaining a problem in the conventional art; Figure 4 is a view illustrating a constitution of the sputtering apparatus for implementing the metal layer forming method according to the present invention; Figure 5 is a graph illustrating an equilibrium diagram of the binary alloy (Al-Si); and, Figure 6 is a sectional view illustrating an example of the step coverage for explaining an effect obtained by a sputtering process using the apparatus shown in Figure 4. For a better understanding of the preferred embodiment, the problem in the conventional art will now be explained with reference to Figures 1 to 3. Figure 1 shows a sectional view of an example of the step coverage in the construction of a typical Al multiple-layer wiring. The construction is formed by sequentially depositing, on a semiconductor layer or substrate 11, a first insulation layer 12 of silicon dioxide (SiO₂), a first wiring layer 13 of Al, a second insulation layer 14 of phosphosilicate glass (PSG), and a second wiring layer 15 of Al. As shown in Figure 1, in the contact holes, represented by reference A, at which the first Al wiring layer 13 and the semiconductor layer 11 are electrically connected to each other, the coverage of the second Al wiring layer 15 is relatively poor. Namely, the connection of the second Al wiring layer 15 is very unsatisfactory because of the thinness of the layer 15 at the portions adjacent to the contact holes, i.e., the thin portion of the layer 15 is easily broken due to a migration of Al atoms over a long period of time, and thus the operational reliability of an LSI device is reduced. As a technique for coping with this drawback, a method is recommended in which the sputtering process is carried out while the temperature of a wafer is kept high. The effect obtained by sputtering with heating will be described hereinafter with reference to Figs. 2A and 2B. Figure 2A shows a sectional view of an example of the step coverage when heating is not carried out. In Fig. 2A, reference 21 denotes a semiconductor layer or substrate; reference 22 denotes an insulation layer of, e.g., SiO₂; and reference 23 denotes an Al wiring layer. The construction shown in Fig. 2A is part of a device formed on a wafer (not shown). As shown in Fig. 2A, where the heating is not applied to the wafer, little movement of the Al atoms deposited on the wafer occurs, and accordingly, the Al atoms remain in the positions at which they are deposited. As a result, the step coverage at the step portion becomes relatively poor. Conversely, referring to Fig. 2B which shows a sectional view of an example of the step coverage where the temperature of a heater (not shown) for heating the wafer is set at approximately 200°C, the shape of the Al wiring layer 23 at the step portion is improved. That is, when heating is applied to the wafer, Al atoms deposited on the wafer can be easily moved toward the step portion, as shown by arrow marks, and accordingly, collected in the step portion. As a result, the step coverage at the step portion becomes better than that of Fig. 2A. Note, when the sputtering process is carried out while the wafer is heated, an admixture contained in the Al-based alloy, e.g., atoms of Si, Cu, and the like, precipitates in the vicinity of the interface between the Al wiring layer 23 and the semiconductor layer 21. However, the amount of atoms precipitated near the interface at the heater temperature of approximately 200°C is within a permissible amount, i.e., at which the precipitated atoms of Si, Cu, and the like can be completely removed during a patterning process carried out at a later stage. Therefore, in this case (Fig. 2B), no problem arises with respect to the precipitation of the admixture. The problem caused by the precipitation of the admixture arises when the temperature of the wafer is raised to a temperature higher than a predetermined temperature at which the above amount of precipitation is permissible. This problem will be explained with reference to Fig. 3. Figure 3 shows a sectional view of an example of step coverage when the temperature of the heater is set at approximately 400°C. When the sputtering process is carried out in the above state, an admixture of Si contained in the Al alloy precipitates in an amount exceeding the permissible amount, as shown in Fig. 3 in the form of particles indicated by hatched circles. The precipitated atoms of Si cannot be completely removed in the subsequent process, as explained before, and as a result, the precipitated admixture of Si causes a deterioration in the quality of the Al wiring layer, and over a long period of time, exerts an adverse influence upon the function of a semiconductor device including the Al wiring layer. A preferred embodiment of the present invention will now be described with reference to Figs. 4 to 6. Figure 4 illustrates a constitution of the sputtering apparatus for implementing the metal layer forming method according to the present invention. Referring to Fig. 4, reference 41 denotes a vacuum container having an opening at one side, a heater block 42 is held by a block holding member 43 fixed to the container 41 by screws. The heater block 42 is formed of copper, which has a good thermal conductivity, and a thermocouple 44 and eight annularly arranged cartridge type heaters 45 are embedded therein. Reference 46 denotes a heater controller, which regulates the temperatures of each of the cartridge heaters 45 to a constant temperature, in accordance with the temperature of the heater block 42 detected by the thermocouple 44. In the present example, the constant temperature is set at 600°C. The heater block 42 has a through hole in the central portion thereof, and argon (Ar) gas supplied from an external source is introduced, via a flow regulating valve 47, through the through hole of the block 42 into the vacuum container 41. Reference 48 denotes a semiconductor wafer, which is held by a pair of holding members 50 mounted on a corresponding tray 49 and arranged at a predetermined position, i.e., opposite to the end face, of the heater block 42, from which Ar gas is delivered. The arrangement of the wafer 48 is performed by a carrying system (not shown). A target 51 consisting of binary alloy of Al-1%Si is provided in an opening at the side of the vacuum container opposite to the wafer 48. The target 51 is held via an insulation member 52 by a target holding member 53, which is fixed to the vacuum container 41 by screws, and as a result, the opening is sealed. Also, the target 51 is connected to a direct current (DC) power source 54 having a voltage of -400 to -500 V, a current of 15 to 20 A, and a power of 7 to 10 kW, and the holding member 53 is grounded commonly with the vacuum container 41. Reference 55 denotes a magnet, which forms an annular magnetic field area for confining electrons in the vicinity of the surface of the target 51. Reference 56 denotes a motor for rotating the magnet 55 so that the magnitude of the magnetic field is made uniform over the whole surface of the target. The operation of the magnet 55 causes the surface of the target 51 to be biased to a high negative potential and, accordingly, a high density plasma state is realized, resulting in an improvement in the speed of the forming of a layer. Reference 57 denotes a conductance regulating valve, which regulates the gas pressure within the vacuum container 41 to a predetermined value. Gas within the container is evacuated with cryopump (not shown) through the valve 57. The sputtering apparatus shown in Fig. 4 does not form a feature of the present invention, and therefore a detailed explanation of the operation thereof will be omitted. The wafer 48 is heated by the heater block 42, i.e., concretely, heated by thermal contact with the Ar gas introduced via the through hole of the block 42. When the sputtering process is started, the material of the target 51, i.e., Al-1%Si, is deposited on the wafer 48 by the sputtering, and the temperature of the wafer then rises. The rise of the temperature of the wafer 48 depends upon both the temperature produced by the heat from the heater block 42 and that produced by the heat due to the deposition of atoms. When the heater temperature is set at approximately 600°C, the measured values of the temperature of the wafer 48 are indicated in the following table. Figure 5 is a graph illustrating an equilibrium diagram of the binary alloy (Al-Si) with respect to the temperature. In Fig. 5, the hatched region indicated by reference P represents a solid solution region, in which Si atoms are brought to the state of a solid solution in the Al matrix. In the region of the lower side of the solid solution region, i.e., the region of the low temperature side, Si atoms precipitates in the Al matrix. Therefore, in the present example (Al-1% by weight of Si), the state of the Al-Si alloy changes at approximately 525°C. That is, an admixture of Si is deposited in the Al solid at a temperature lower than 525°C, but it is brought to the state of an absolutely solid solution in the Al solid at a temperature higher than 525°C. Referring to the above Table and the graph in Fig. 5, in the present embodiment, the temperature of the wafer during the sputtering process rises from the time that the sputtering is started, i.e., the state (460°C) in CASE-2 to the state (570°C) in CASE-4. Therefore, Si atoms in the films deposited on the wafer are brought to the state of an absolutely solid solution in the Al solid. Figure 6 illustrates an example of the step coverage obtained when Si atoms are brought to the state of a solid solution. Comparing the sectional view at the heater temperature of approximately 600°C in Fig. 6 with that at the heater temperature of approximately 400°C in Fig. 3, representing a conventional example, it will be appreciated that the shape of the Al wiring layer 63 at the step portion in Fig. 6 is flatter than the corresponding shape in Fig. 3 although the former is a little different from the latter, and that an admixture of Si does not precipitate in the form of coarse particles in the vicinity of the interface between the Al wiring layer 63 and the semiconductor layer 61, because a re-dissolution and quick freezing of the admixture of Si are effected in the Al solid in a solid-phase state. As explained above, by heating the wafer to a temperature higher than the temperature at which solid solution is formed in the Al alloy, i.e., 525°C in the present example, to form an Al wiring layer, the shape of the layer at the step portion can be planarized, and since the admixture does not precipitate in the form of coarse particles in the vicinity of the interface, a patterning process based on a subsequent dry etching can be facilitated. Also, the surface of the Al wiring layer formed at the step portion is relatively smooth. Furthermore, the Al wiring layer is stable with respect to a subsequent heating process at 450°C to 500°C and thus a deterioration in the quality of the layer can be prevented.

Claims: A method for forming a metal layer by depositing an aluminium-based alloy on a wafer by sputtering, comprising: forming an insulation layer (62) having at least one step portion on the wafer (48,61); and forming said metal layer (63) by depositing the aluminium-based alloy over the insulation layer while the wafer is heated; characterised in that the wafer (48,61) is heated to a temperature higher than the temperature at which a solid solution is formed in the aluminium-based alloy. A method as set forth in claim 1, wherein the aluminium-based alloy is a binary alloy and contains 1 percent by weight of silicon and the lower limit value is approximately 525°C. A method as set forth in any preceding claim, wherein the wafer is heated to at least 525°C by heat produced by a heater (42) and heat generated due to a deposition of aluminium atoms on the wafer.

Inventors: HASHIZUME KOUZI FUJITSU DAI NA, INOUE MINORU HAINESU MIZONOKUC, HASHIZUME, KOUZI FUJITSU DAI 11 NAKAHARA RYO, INOUE, MINORU HAINESU MIZONOKUCHI 213
Applicants: FUJITSU LTD, FUJITSU VLSI LTD, FUJITSU LIMITED, FUJITSU VLSI LIMITED
Application year: 1987
Main classification: H01L21
IPC codes: H01L21, C23C14