HARD MAGNETIC MATERIAL

Abstract: The invention relates to new hard magnetic materials which have an intermetallic compound of tetragonal crystal structure of the ThMn₁₂ type. The intermetallic compound has the gross formula ZA(Me I 1-x Me II x )₁₂, wherein ZA is a rare earth metal from the group Sm, Er, Tm. Me I is Fe, Co or a mixture of the two, Me II is Ti, V, Cr or Si and x = 0.1 - 0.35, , preferably 0.12 - 0.33.

Description: The invention relates to a hard magnetic material which comprises at least a rare earth metal and a transition metal chosen from the group consisting of iron and cobalt. Known materials of this type are, for example, materials which comprise a rare earth metal, iron or a mixture of iron and cobalt and boron, said material comprising a fine crystalline phase of a tetragonal crystal structure of substantially the composition (RE)₂(Fe,Co)₁₄B. A known compound of this type is Nd₂Fe₁₄B. This compound has particularly good magnetic properties. It is the object of the present invention to provide hard magnetic materials of good magnetic properties which do not comprise boron. It has been found in practice that poisonons boron compounds can easily be formed in the manufacture of the known boron-containing materials. It has been found that this object can be achieved by materials of the type mentioned in the opening paragraph which according to the invention comprise an intermetallic compound of the gross formula RE(Me I 1-x Me II x )₁₂, wherein RE is one or more rare earth metals from the group formed by samarium, erbium and thullium, Me I is Fe, Co or a mixture of Fe and Co, and Me II is Ti, V, Cr, Si, W or Mo, x being between 0.1 and 0.35, said compound having a tetragonal crystal structure of the ThMn₁₂ type. When x is smaller than 0.1 or larger than 0.35 the desired compound is obtained to an insufficient extent. x is preferably between 0.12 and 0.33. The said rare earth metals can partly be replaced by other rare earth metals including lanthanum and yttrium without the magnetic properties being adversely influenced thereby essentially while certain properties can be improved thereby such as the magnetisation. In this manner, generally up to 50 at% can be replaced. The said compositions in general have a high magnetic remanance and energy product and a Curie temperature above 200°C (473 K). The compositions in general have a higher resistance to corrosion than compositions comprising (RE)₂(Fe,Co)₁₄B-type compounds. The intrinsic coercive force at room temperature is sufficiently high for practical applications. The saturation magnetisation at room temperature may be more than 100 emu/g. The invention is based on the gained recognition of the fact that, although intermetallic compounds RE Fe₁₂ with the tetragonal ThMn₁₂-structure are not known, the ThMn₁₂ structure type is sufficiently stabilized upon substitution of a part of the Me I metal by other elements Me II in certain relatively small quantities, so that stable intermetallic compounds can be obtained having suprisingly good hard magnetic properties. The said ThMn₁₂-crystal type is described in an article by J.V. Florio, R.E. Rundle and A.I Snow in Acta Cryst. 5 pp. 499-457 (1952). Permanent magnetic materials can be obtained by melting, for example, by arc melting the desired elements in the relative quantities indicated by the above mentioned gross formula, or in relative quantities which are chosen to be so that after crystallization the intermetallic compound of the desired crystal structure is substantially obtained, thereby taking into account any evaporation losses during melting. The invention will now be described in greater detail with reference to the ensuing specific examples : EXAMPLE 1 : A hard magnetic material of the composition Sm(Fe 0.83 V 0.17 )₁₂ was prepared by melting in an argon atmosphere the elements of this composition in the relative quantities: samarium: 24.2% by weight, iron 64.1% by weight and vanadium 11.7% by weight. Some excess samarium is present at the start of the melting to compensate for evaporation losses during melting. After cooling and solidifying a body comprising fine crystallites of the desired crystal structure (ThMn₁₂-type) was obtained. The anisotropy field at 20°C was at least 80 kilo Oersted. This corresponds to the value which is found for Nd₂Fe₁₄B. The compounds in which RE = Sm have an easy axis of magnetization parallel to the crystallographic C-axis. The Curie temperature is 610 K. Other compositions such as Er(Fe 0.83 V 0.17 )₁₂ and Tm(Fe 0.83 V 0.17 )₁₂ were prepared in the same way. They have the same ThMn₁₂ structure, good magnetic properties and a Curie temperature of 505 and 496 K respectively. EXAMPLE 2 : Hard magnetic materials of various compositions Sm(Fe 1-x Cr x )₁₂, wherein x was varied between 0.12 and 0.17 were prepared. They all contained crystallites of the ThMn₁₂-structure. EXAMPLE 3 : A hard magnetic material of the composition Sm(Fe 0.415 Co 0.415 Si 0.17 )₁₂ was prepared by melting a mixture of the elements. A body comprising fine crystallites of the ThMn₁₂-structure was obtained.

Claims: A hard magnetic material comprising at least a rare earth metal and at least an element from the group formed by iron and cobalt, characterized in that the material comprises an intermetallic compound of the gross formula Re(Me I 1-x Me II x )₁₂, wherein RE is one or more rare earth metals from the group consisting of samarium, erbium and thullium (Sm, Er, and Tm), Me I is Fe, Co or a mixture of Fe and Co, and Me II is Ti, V, Cr, Si, W or Mo, x being between 0.1 and 0.35, said compound having a tetragonal crystal structure of the ThMn₁₂-type. A hard magnetic material as claimed in Claim 1, characterized in that the said rare earth metals are replaced up to 50 at% by one or more other rare metals including lanthanum and yttrium. A hard magnetic material as claimed in Claim 1, characterized in that x is between 0.12 and 0.33. A hard magnetic material as claimed in Claim 1, characterized in that RE = Sm, Me I = Fe and Me II = V. A hard magnetic material as claimed in Claim 4, characterized in that it has the composition Sm(Fe 0.83 V 0.17 )₁₂. A hard magnetic material as claimed in Claim 1, characterized in that it has the composition Sm(Fe 1-x Cr x )₁₂, wherein x = 0.1 - 0.35, preferably 0.12 - 0.33. A hard magnetic material as claimed in Claim 1, characterized in that RE = Sm, Me I = Fe, Co and Me II = Si. a hard magnetic material as claimed in Claim 7, characterized in that it has the composition Sm(Fe 0.415 Co 0.415 Si 0.17 )₁₂.

Inventors: BUSCHOW, KURT HEINZ JUERGEN, DE MOOY, DIRK BASTIAAN, VAN MENS, REINOUD, Buschow, Kurt Heinz Jürgen
Applicants: N.V. PHILIPS' GLOEILAMPENFABRIEKEN
Application year: 1987
Main classification: H01F1
IPC codes: C22C19, C22C38, H01F1