HERBICIDAL COMPOSITION

Abstract: A herbicidal composition comprising, as active ingredients, a compound represented by the following formula I: and at least one compound selected from 2-chloro-4-­ ethylamino-6-isopropylamino-1,3,5-triazine (common name: atrazine), 2-chloro-4-(1-cyano-1-methylethylamino)-6-­ ethylamino-1,3,5-triazine (common name: cyanazine), α-chloro-2′6′-diethyl-N-methoxymethylacetanilide (common name: alachlor) or 2-chloro-N-(2-ethyl-6-methylphenyl)-N-­ (2-methoxy-1-methylethyl)acetamide (common name: metolachlor). The composition according to the invention can control completely annual weeds as well as perennial weeds at a lower dose without having phytotoxicity on corn.

Description: This invention relates to a herbicidal composition comprising, as active ingredients, a compound represented by the following formula I which is hereinafter referred to as Compound (I),: and at least one compound selected from 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine (common name: atrazine) or 2-chloro-4-(1-cyano-1-methylethylamino)-6-ethylamino-1,3,5-triazine (common name: cyanazine). By researches and developments of herbicides over many years, various chemicals have been put to practical use and these herbicides have contributed to labor-saving in works for controlling weeds or improvements of productivity of crops in agriculture and horticulture. Even in these days, developments of novel chemicals having more excellent herbicidal characteristics are demanded. Particularly, while a herbicide for agriculture and horticulture is desired to control only target weeds selectively at a lower dose without having phytotoxicity on crops, the existing chemicals do not necessarily satisfy this requirement. Compound (I) disclosed in JP-A-85 208 977 exhibits an excellent herbicidal effect at a lower dose as compared with herbicides of the prior art, and yet has high safety to crops such as corn, wheat, etc. Also, it exhibits excellent effect not only to annual grass weeds and annual broad leaf weeds but also exhibits potent effectiveness to perennial weeds, and therefore its usefulness is of great value. Further, atrazine and cyanazine, which are known in the art, are used for annual grass weeds such as barnyardgrass (Echinochloa crus-galli), Green foxtail (Setaria Viridis), Large crabgrass (Digitaria sanguinalis), etc., and annual broad leaf weeds in higher doses as compared with Compound (I). As a consequence, broad leaf weeds and perennial weeds which are resistant to these chemicals and can be controlled with difficulty by these chemicals are increasing, and therefore improvement thereof has been desired. SUMMARY OF THE INVENTION The present inventor has made studies in order to increase the herbicidal effect of Compound (I), and consequently found that by incorporating Compound (I) with atrazine or cyanazine, which have been conventionally used, the herbicidal effects of the respective compounds can be obtained not only additively, but also a synergistic weed killing effect appears, to accomplish the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS This synergistic effect is great and, by use of the composition according to the present invention, annual weeds as well as perennial weeds, can be completely controlled at a lower dose without having phytotoxicity on corn, and therefore usefulness of this invention is great. Also, by use of a mixture described above, it becomes possible to reduce the dose of atrazine or cyanazine, to be used which are contained in the composition of the present invention and usefulness of the present invention is very high. Further, the herbicidal composition of the present invention has also its effect by treatment either before or after emergence of weeds, and therefore a high effect can be obtained even by soil treatment or treatment of both callus and soil. Also, it is useful for various crops in addition to corn, and it is applicable for control of various weeds in other fields of agriculture and horticulture such as cultivated fields and fruit gardens and non-crop lands such as athletic fields, vacant lands, forest lands, tank yards, railroad edges, etc., and it can exhibit a great economical effect in controlling weeds. The composition according to the present invention generally contains 0.001 to 50 parts by weight of Compound (I) per one part by weight of atrazine or cyanazine, although it may differ depending on the relative activities of the respective components. In many cases, the best advantage of the mixed herbicides of the present invention can be obtained when the proportion of Compound (I) is lower than that of the other herbicide, for example, Compound (I) is used in an amount of 0.001 to 0.5 parts by weight per 1 part by weight of atrazine or cyanazine. The dose of the mixture to be applied, which may depend on a large number of factors such as the kinds of species of target plants of which growth is to be inhibited, may be generally suitably 0.01 to 10 kg/ha as an active ingredient. Those skilled in the art can determine easily an appropriate use rate according to a standardized conventional test without carrying out a lot of experiments. The composition of the present invention should be preferably used in the form of a composition comprising the active ingredients mixed with a carrier comprising a solid or liquid diluent. The composition may preferably further contain a surfactant. In using the composition of the present invention as a herbicide, the composition may generally be used by mixing it with a suitable carrier, for example, a solid carrier such as clay, talc, bentonite, diatomaceous earth, etc., or a liquid carrier such as water, alcohols (methanol, ethanol, etc.), aromatic hydrocarbons (benzene, toluene, xylene, etc.), chlorinated hydrocarbons, ethers, ketones, esters (ethyl acetate, etc.), acid amides (dimethylformamide, etc.). The composition may optionally contain an emulsifying agent, a wetting agent, a dispersant, a binder, a penetrant, a spreader, a stabilizer, etc. and can be put to practical use in any form of preparation such as emulsifiable concentrate, soluble concentrate, wettable powder, dust, granule, suspension concentrate, etc. The synergistic herbicidal effect of the herbicide mixture may be explained as follows. That is, individual active compounds may exhibit respective defects in herbicidal activity in many cases. In such a case, when the herbicidal activity obtained by combination of two kinds of active compounds becomes greater than the simple sum of the respective activities of the two kinds of the compounds (expected activity), this is called synergistic action. The activity expected from a specific combination of two kinds of herbicides can be calculated as follows (see Colby, S. R. Calculating synergistic and Antagonistic Response of Herbicide combinations, "Weed", Vol. 15, P. 20 to 22, 1967) α: the percent inhibition of growth by herbicide A at a Kg/ha; β: the percent inhibition of growth by herbicide B at b Kg/ha; E: the expected percent inhibition of growth by herbicides A + a at a + b Kg/ha. Thus, when the observed response is greater than expected, the combination is synergistic. The present invention is described in more detail by referring to the following examples, but the compounds, amounts of preparations, forms of preparations, etc., in the present invention are not limited only to these examples. In examples, all the "part(s)" mean part(s) by weight. The above components are mixed and pulverized homogeneously to prepare a wettable powder. The above components are mixed and pulverized homogeneously to prepare a wettable powder. The above components are mixed homogeneously to prepare a flowable. The above components are mixed homogeneously to prepare a flowable. Test example: Herbicidal effect test by soil treatment In a plastic box having a length of 30 cm, a width of 30 cm and a depth of 10 cm, there was placed a sterile upland soil. Respective seeds of Green foxtail (Setaria Viridis), Velvetleaf (Abutilon theophrasti), Redroot pigweed (Amaranthus retroflexus) and corn (Zea mays) were sown in spots, and further tubers of Yellow nutsedge (Cyperus esculentus) were planted followed by covering soil to about 1.0 cm over the seeds. The next day, before emergence of weeds of the plants, herbicides were sprayed evenly in such a manner that the amount of active ingredient of each chemical reaches the predetermined proportion. In spraying, the wettable powder or the flowable suitably prepared according to the formulation examples described above, were diluted with water and sprayed by means of a small sprayer. Four weeks after spraying, fresh weight of aerial part of the respective weeds were measured and a control rate (%) was determined by the following formula. Table 1 shows the results of the tests in which Compound (I), atrazine and cyanazine were used singly, and Table 2 shows the results of the tests in which Compound (I) was mixed with the respective chemicals. As is apparent from the above results, the composition of the present invention does not merely yield the sum of the respective activities of Compound (I) and the above herbicide known in the art, but possesses a greater synergistic herbicidal activity. Further, it can control selectively and completely the target weeds at a low dose.

Claims: Claims for the following Contracting States : AT, BE, CH, DE, FR, GB, GR, IT, LI, LU, NL, SE A herbicidal composition comprising, as active ingredients, a compound represented by the following formula I: and at least one compound selected from 2-chloro-4-ethylamino-6-isopropylamino-l,3,5-triazine (common name: atrazine), or 2-chloro-4(1-cyano-1-methylethylamino)-6-ethylamino-1,3,5 -triazine (common name: cyanazine). The herbicidal composition according to claim 1 which contains 0.001 to 50 parts by weight of the compound represented by formula I per one part by weight of atrazine or cyanazine. The herbicidal composition according to claim 2 which contains 0.001 to 0.5 part by weight of the compound represented by formula I per one part by weight of atrazine or cyanazine. Claims for the following Contracting State : ES A process for preparing a herbicidial composition, characterized by combining of, as active ingredients, a compound represented by the following formula and at least one compound selected from 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine (common name: atrazine), or 2-chloro-4(1-cyano-1-methylethlyamino)-6-ethylamino-1,3,5-triazine (common name: cyanazine). A process according to claim 1, characterized in that 0.001 to 50 parts by weight of the compound represented by formula I are combined with 1 part by weight of atrazine or cyanazine. A process according to claim 2, characterized in that 0.001 to 0.5 part by weight of the compound represented by formula I are combined with 1 part by weight of atrazine or cyanazine.

Inventors: IKAI, TAKASI
Applicants: NISSAN CHEMICAL INDUSTRIES LTD.
Application year: 1987
Main classification: A01N47
IPC codes: A01N43, A01N47, A01P13