BORATED REACTION PRODUCTS OF SUCCINIC COMPOUNDS AS LUBRICANT DISPERSANTS AND ANTIOXIDANTS

Abstract: Borated reaction products of alkenyl succinic com­ pounds, aryl amines and aminoalcohols are highly effective dispersant and antioxidant/anticorrosion additives for lubri­ cant compositions.

Description: This invention relates to borated nitrogen-containing reaction products and their use in lubricant compositions. More particularly, the reaction products are made by reacting alkenylsuccinic anhydrides or acids with an aminoalcohol and an aryl amine and thereafter borating. It is known that in the normal use of organic industrial fluids, such as lubricating oils, transmission fluids, bearing lubricants, power transmitting fluids and the like, the base medium is subjected to oxidizing conditions which may result in the formation of sludge, lacquers, corrosive acids and the like. These products are undesirable in the equipment in which the industrial fluid is used. The oxidation residues or heavy contaminants may interfere with the normal operation of the fluid, increase its viscosity, and even cause severe damage to the parts of the equipment themselves. In the lubrication of modern engines, particularly, oil compositions must be able to prevent acids, sludge and other solid contaminants from remaining near the moving metal parts. Poor piston travel and excessive engine bearing corrosion may result, unless the oil can prevent the sludge and oxidation products from depositing in the engine. Bearing corrosion is another serious problem in gasoline engines which operate at an oil temperature of about 150°C (300°F) or higher. The most desirable way of decreasing these difficulties is to add to the base organic fluid a detergent or dispersant additive capable of dispersing the solid particles to prevent them from interfering with the normal operation of the equipment, and leaving the metal surfaces relatively clean. Today, with modern equipment operating under increasingly strenuous conditions, it is desirable to develop new detergents (dispersants) which have improved dispersant properties, which are soluble in the fluid medium to which they are added, and which are themselves stable therein and which also impart antioxidation and anticorrosion properties thereto. U.S. Patent 4522736 discloses the unborated precursers of the present invention as dispersents and/or anticorrosion agents. This invention provides a product made by (a) reacting (i) a polyalkenylsuccinic compound with (ii) a diaryl amine of the formula ANHA¹ wherein A and A¹ are the same or different aromatic or aryl groups, or the substituted member thereof, having 6 to 50 carbon atoms; (b) reacting the product of (a) with an aminoalcohol of the formula (HOR¹) x N(H) y where R¹ is an alkylene group having 1 to about 6 carbon atoms, x is 1 to 3 and y is 0 to 2, their sum being 3; and (c) reacting the product of (b) with boric acid or a compound of the formula (R²O) p (BO₂) q Z u Y wherein R², Y and Z are hydrogen or alkyl groups of from 1 to 6 carbon atoms, p and u are 0 to 2 and q is 1 to 3. This invention further provides a lubricant composition comprising a major amount of a lubricant and a minor detergent/dispersant or antioxidation/anticorrosion amount of the above product. The substituents in A and A¹ may be an aliphatic group, preferably an alkyl group, containing from 1 to 44 carbon atoms. The aromatic group A and A¹ will preferably contain no more than 14 carbon atoms. Preferred specific amines are diphenylamine, phenyl-alphanaphthylamine and their alkylated derivatives. Substituent groups R and R¹ may be alkyl or aralkyl, or they may be a chloro group, an alkoxyl group or an acyloxy group. Preferably R and R¹ will have 1 to 12 carbon atoms and more preferably both R and R¹ will be selected from among t-octyl, t-dodecyl, di-t-dodecyl, t-butyl and di-t-butyl groups, R² may be, for example, methyl, ethyl, butyl, hexyl, octyl, decyl, dodecyl, pentadecyl, octadecyl or eicosyl group. The preferred alkanolamine is triethanolamine. The reactions can, broadly, be carried out over a wide range of temperatures from about 50°C to about 300°C in from about 0.5 hour to about 10 hours, depending on temperature and reactivity of the reactants. For specific reactions, the temperatures of reaction can be from about 50°C to about 250°C, preferably about 100°C to about 200°C for the reaction between the alkenylsuccinic compound and the diarylamine. When carrying out the reaction of the alkenylsuccinicdiarylamine product with the alkanolamine, the temperature will generally be from about 100°C to about 300°C, preferably about 150°C to about 275°C. Times will run from about 1 hour or less to about 10 hours. The boration (reaction (c)) can be carried out in any convenient manner or sequence and under any conditions known in the art. The borating agent can be boric acid or a compound of the formula (R²O) p (BO₃) q Z u Y where R², Y and Z are hydrogen or alkyl groups of from 1 to about 6 carbon atoms, p and u are 0 to 2 and q is 1 to 3. The useful boronating compounds covered by the above formula include boric acid, metaboric acid, alkyl metaborates, alkyl boroxines, boroxine boroxides, and the like, as well as the alkyl borates. Preferably the boration is carried out in substantially stoichiometric ratios of reactants. The alkenyl group of the alkenylsuccinic compound, preferably the anhydride or the acid, can have a number average molecular weight of from about 360 to about 1800, i.e., it will have from 30 to 150 carbon atoms. They (the alkenyl groups) may be made by any method known to the art, as by the catalytic oligomerization of an olefin, such as one containing 2 to 10 carbon atoms. Further, the oligomer so produced can be reacted with maleic anhydride by well known methods (as by BF₃ catalysis) to give the alkenylsuccinic compound. While the reaction sequence has been disclosed to be reaction of (a) alkenylsuccinic compound and diarylamine, (b) reaction of product of (a) with an alkanolamine, and (c) thereafter boronating, the invention is not limited to that method sequence. For example, the alkanolamine may be reacted with the alkenylsuccinic compound, followed by reaction of the product thus obtained with the diarylamine or the product of (1) may be boronated prior to reacting with the aminoalcohol or the diarylamine. The same times and temperatures mentioned above for reactions involving diarylamine, hindered phenol or alkanolamine will generally apply in such reactions. Furthermore, all reactants can be mixed and reacted in one step, in which case the temparature again can be from about 50°C to about 300°C and the time from about 0.5 hour to about 10 hours. The reactants can be used in the range of about 0.1 to about 1.0 mole of diarylamine per mole of alkenylsuccinic compound and from about 0.1 to 1.2 moles of alkanolamine per mole of alkenylsuccinic compound. The preferred amounts of reactants are 1.0 mole of alkenylsuccinic compound, 1.0 mole of diarylamine and no more than about 0.6-.75 mole of the alkanolamine. The products of the invention are used in minor dispersant or anticorrosion amounts with a major proportion of a lubricating oil or grease. In general, this will amount to from about 0.05% to about 15% by weight of the total composition. Furthermore, other additives, such as other detergents, antioxidants, antiwear agents and the like may be present. These can include phenates, sulfonates, succinimides, zinc dithiophosphates, polymers, calcium and magnesium salts and the like. The lubricants contemplated for use with the products herein disclosed include mineral and synthetic hydrocarbon oils of lubricating viscosity, mixtures of mineral oils and synthetic oils, including mixtures. The synthetic hydrocarbon oils include long-chain alkanes such as cetanes and olefin polymers such as oligomers of hexene, octene, decene, and dodecene, etc. The products of this invention are especially effective in synthetic oils formulated using mixtures of synthetic hydrocarbon olefin oligomers and lesser amounts of hydrocarbyl carboxylic ester fluids. Other synthetic oils, which can be mixed with a mineral or synthetic hydrocarbon oil, include (1) fully esterified ester oils, with no free hydroxyls, such as pentaerythritol esters of monocarboxylic acids having 2 to 20 carbon atoms, trimethylolpropane esters of monocarboxylic acids having 2 to 20 carbon atoms, (2) polyacetals and (3) siloxane fluids. Especially useful among the synthetic esters are those made from polycarboxylic acids and monohydric alcohols. More preferred are the ester fluids made by fully esterifying pentaerythritol, or mixtures thereof with di- and tripentaerythritol, with an aliphatic monocarboxylic acid containing from 1 to 20 carbon atoms, or mixtures of such acids. Having described the invention with reference to its broader aspects, the following are offered to specifically illustrate it. It will be understood that the Examples are for illustration only and are not intended to limit the scope of the invention. Example 1 A mixture of 1800 grams (1.0 mol) polybutenyl succinic anhydride and 169 grams (1.0 mol) diphenylamine was stirred for three hours at 160°C. After cooling to 100°C, 112 grams (0.75 mol) triethanolamine was added and the mixture stirred to about 225°C over a six hour period. After cooling to 75°C, a mixture of 186 grams (3.0 mols) of boric acid and 222 grams (3.0 mols) butylalcohol was added and the temperature raised to about 250°C over a six hour period. The final product was obtained by blowing with nitrogen and filtering. Example 2 A mixture of 1800 grams (1.0 mol) of polybutenylsuccinic anhydride and 169 grams (1.0 mol) of diphenylamine was stirred for three hours at 160°C. After cooling to 100°C, 112 grams (0.75 mol) of triethanolamine were added and the mixture stirred to 225°C over a six hour period. After blowing with nitrogen, the final product was obtained by filtration. Evaluation of Products Example 1, a product in accordance with this invention and Example 2, an unborated prior art compound were tested side by side under identical conditions in the C.R.C. L-38 Bearing Corrosion Test. CRC L-38 Engine Test The CRC L-38 Test is a single-cylinder gasoline engine test which measures oil oxidation and corrosion. The engine is fitted with copper lead inserts in the connecting rod bearing to permit evaluation of bearing corrosion protection. Operation is at elevated coolant and oil temperatures in order to promote oil oxidation and the formation of oxy-acids that are corrosive to these inserts. Oil performance is judged by the weight loss of the bearing inserts after test completion. The following results were obtained in this test: C.R.C. L-38 Bearing Corrosion Test Example No. Conc. Wt.% Bearing Wt. Loss in Mg. 40 Hours 80 Hours 120 Hours 1 4.2% 5 6 7 2 4.2% 219 - - The base oil composition comprised a blend of synthetic oils containing overbased calcium sulfonate, overbased calcium phenate, normal calcium sulfonate, zinc dithiophosphate and a hindered phenol antioxidant.

Claims: A product of reaction made by (a) reacting an alkenylsuccinic compound with an amine of the formula ANHA¹ wherein A and A¹ may be the same or different aromatic groups having from 6 to 50 carbon atoms followed by (b) reacting the product of (a) with an alkanolamine of the formula (HOR¹) x N(H) y wherein R¹ is an alkylene group having 1 to 6 carbon atoms, x is 1 to 3 and y is 0 to 2, their sum being 3, and (c) thereafter reacting the product of (b) with boric acid or a compound of the formula (R²O) p (BO₂) q Z u Y wherein R², Y and Z are hydrogen or alkyl groups of from 1 to 6 carbon atoms, p and u are 0 to 2 and q is 1 to 3. The product of claim 1 wherein the amine is selected from diphenylamine or phenyl-alpha-naphthylamine. The product of claim 1 wherein Ar and Ar¹ may each be independently substituted with a C₁ to a C₄₄ aliphatic group. The product of claim 1 wherein the alkanolamine is triethanolamine. The product of claim 1 wherein the succinic compound is selected from an alkenyl succinic acid and the anhydride thereof. The product of claim 1 wherein in the alkenylsuccinic compound the alkenyl portion has from 30 to 150 carbon atoms. The product of claim 1 wherein the alkenylsuccinic compound is polybutenylsuccinic anhydride, the polybutenyl having a number average molecular weight of about 1300, the secondary amine is phenyl-alpha-naphthylamine and the alkanolamine is triethanolamine. The product of claim 1 wherein the alkenylsuccinic compound is polybutenylsuccinic anhydride, the polybutenyl having a number average molecular weight of about 1700, the amine is diphenylamine and the alkanolamine is triethanolamine. The product of any one of claims 1-8 wherein reaction (a) is carried out at from 50°C to 250°C using from 0.1 to 1.0 mole of the amine per mole of acid or anhydride, and reaction (b) is carried out at from 100°C to 300°C using from 0.1 mole to 1.2 moles of amine reactant per mole of acid or anhydride used in (a). A lubricant composition comprising a major proportion of a lubricating oil or grease made therefrom and a minor dispersant and/or antioxidant/anticorrosion amount of the product of any one of claims 1-9. The composition of claim 10 wherein the amount of the product used is from 0.05 to 15% by weight based on the composition. The composition of claim 10 wherein the lubricant is a lubricating oil, a mineral oil, a synthetic oil or a mixture of mineral and synthetic oil. The composition of claim 10 wherein the lubricant is a grease. Use of a product according to any of claims 1 to 9 as an anticorrosion agent in lubricant compositions.

Inventors: ANDRESS, HARRY JOHN, JR., ASHJIAN, HENRY
Applicants: MOBIL OIL CORPORATION
Application year: 1987
Main classification: C07F5
IPC codes: C10M159, C10N30, C10N40, C10N60, C10N20, C10M133, C10N50