PROCESS FOR THE SYSTEMATIC TREATMENT OF EXHAUST GASES

Abstract: A process for the systematic treatment of exhaust gases which comprises the steps of; injecting a neutralizing absorbent into an exhaust gas to fix acidic gas components in the neutralizing absorbent; further injecting an auxiliary agent into the exhaust gas subsequent to the injection of the neutralizing absorbent and passing the exhaust gas through a filter which has been precoated with such an auxiliary agent as used above whereby the neutralizing absorbent and the auxiliary agent are permit­ ted to deposit as a layer on the precoated filter and are able to collect acidic gas components remaining in the exhaust gas and a dust; and blowing ammonia into the purified exhaust gas so that nitrogen oxides in the exhaust gas are reduced in the presence of a denitrating catalyst into nitrogen gas.

Description: BACKGROUND OF THE INVENTION : Field of the Invention This invention relates to a process for the systematic treatment of exhaust gases from municipal refuse incineration plants or other incinerators so as to remove acidic gases and dusts from the exhaust gases. Description of Related Art As is well known in the art, exhaust gases from municipal refuse incineration plants or other incinerators generally contain acidic gases such as sulfur oxides, hydrogen chloride, nitrogen oxides and the like, and dusts. The treatment of these acidic gases and dusts at one time involves many troubles. The sulfur oxides and hydrogen chloride in the acidic gases can be relatively readily fixed with neutralizing absorbents such as lime, but the nitrogen oxides are not removed. There is a process of reducing nitrogen oxides into harmless nitrogen gas in the presence of a denitrating catalyst while introducing ammonia. In this connection, however, when sulfur oxides coexist, side reactions take place, making it difficult to cause the reduction reaction of the nitrogen oxides to selectively proceed. In addi­ tion, when dusts deposit on the catalyst, deterioration of the catalyst is inconveniently facilitated. In order to carry out the removal of dusts, sulfur oxides and nitrogen oxides in separate apparatus, the cost of equipment and the operating cost become huge with a great economical burden. SUMMARY OF THE INVENTION : It is an object of the invention to provide a process for systematically treating an exhust gas containing various types of acidic gases and dusts by one system as will otherwise be treated by different processes. According to the present invention, there is provided a systematic treating process for exhaust gases which comprises the steps of; injecting a neutralizing absorbent into an exhaust gas to fix acidic gas components in the neutralizing absorbent; further injecting an auxiliary agent into the exhaust gas subsequent to the injection of the neutralizing absorbent and passing the exhaust gas through a filter which has been precoated with such an auxiliary agent as used above whereby the neutralizing absorbent and the auxiliary agent are permitted to deposit as a layer on the precoated filter and are able to collect acidic gas components remaining in the exhaust gas and a dust; and blowing ammonia into the purified exhaust gas so that nitrogen oxides in the exhaust gas are reduced in the presence of a denitrating catalyst into nitrogen gas. The neutralizing absorbent used in the process of the invention is an alkaline neutralizing absorbent which may be in the form of powder or a slurry, e.g. Ca(OH)₂, CaCO₃ or the like. The absorbent is preferably provided as a fine powder whose size is below l00 microns, preferably below 50 microns. The auxiliary agent is precoated on the filter so that dusts are prevented from directly contacting the filter in order to protect the filter and also to facilitate separa­ tion of the deposition layer from the filter. In addition, the deposition layer formed along with the neutralizing absorbent is imparted with air permeability. The auxiliary agent should satisfy the requirements of (l) a small bulk density, (2) good air permeability, (3) non-stickiness when absorbing moisture, and (4) a particle size of from l to l00 microns, preferably from l0 to 50 microns. Examples of the auxiliary agent include zeolite, alumina, diatomaceous earth, perlite, activated clay, kaolin, feldspar and quartz in the form of powders. These materials may be used singly or in combination. Of these powders, zeolite, diatomaceous earth and perlite are preferred. Our experiments reveal that the auxiliary powder is preferably added in an amount of not larger than 50 wt%, more preferably from l0 to 30 wt%, of the injected neutralizing agent. The amount of the neutralizing agents such as powders of Ca(OH)₂ and CaCO₃ and a slurry of Ca(OH)₂ should be not less than an equivalent of reaction with acidic gases other than nitrogen oxides contained in the exhaust gas. The denitrating catalyst is a denitrating catalyst for reduction including vanadium pentaoxide or titanium oxide and may be used by deposition on porous ceramics. BRIEF DESCRIPTION OF THE DRAWING : FIG. l is a schematic view of an apparatus of treating an exhaust gas for carrying out the process of the invention; and FIG. 2 is a schematic view showing another embodiment of the invention in which a denitrating device is changed in location. DESCRIPTION OF THE PREFERRED EMBODIMENTS: In the drawing, like reference numerals indicate like parts. In the figures, an exhaust gas ll is passed along the direction of the arrow through an exhaust gas pipe l. During the passage, a neutralizing absorbent A and an auxiliary agent B are supplied by injection and mixed in the pipe l, so that sulfur oxides and hydrogen chloride in the exhaust gas are fixed with the neutralizing absorbent A. The exhaust gas is subsequently passed into a filter-­ type dust collector 2. The filter in the dust collector has been applied with an auxiliary agent to form a protective layer on the filter surface, e.g. a bag filter surface. The neutralizing absorbent A, auxiliary agent B and dusts in the exhaust gas are caught with the protective layer and the filter to form a deposition layer. On passage of the exhaust gas through the deposition layer, sulfur oxides and hydrogen chloride remaining in the exhaust gas are finally collected with the unreacted neutralizing absorbent in the deposition layer. The exhaust gas from which the fulfur oxides, hydrogen chloride and dusts have been removed is passes into a nitrogen oxide eliminator 3 into which a reducing agent C such as ammonia is introduced. As a result, nitrogen oxides in the exhaust gas are reduced. The completely purified exhaust gas 22 is released as arrow 22. The deposition layer on the filter of the dust collector 2 is able to keep air permeability with the aid of the auxiliary agent dispersed in the layer, but after a certain period of time, the grown deposition layer is separated and discharged from a discharge device 4 located at the bottom of the dust collector 2. The present invention is more particularly described by way of example. Example An exhaust gas from a municipal refuse incinerator was treated under the following conditions according to the following manner of treatment. Treating conditons: Amount of incineration: l50 tons/day Amount of exhaust gas: 30,000 Nm³/hour Concentration of SOx: l00 ppm Concentration of HCl: l,000 ppm Concentration of NOx: l50 ppm Manner of treatment: The apparatus of FIG. l was used and slaked lime was blown as neutralizing absorbent A at a rate of l00 kg/hour. The residence time for the gas was 5 seconds. A mixture of diatomaceous earth and perlite at a mixing ratio by weight of 9:l was blown as auxiliary agent B at a rate of l0 kg/hour. The filter surface of the dust collector was uniformly precoated with the auxiliary agent B. Results: The exhaust gas at the outlet of the treating apparatus had a concentration of sulfur oxides not larger than l0 ppm, a concentration of hydrogen chloride not larger than 20 ppm, and a concentration of nitrogen oxides not larger than 20 ppm. The filter and the denitrating catalyst were not found to deteriorate and were recognized to stand long use.

Claims: 1. A systematic treating process for exhaust gases which comprises the steps of; injecting a neutralizing absorbent into an exhaust gas to fix acidic gas components in the neutralizing absorbent; further injecting an auxiliary agent into the exhaust gas subsequent to the injection of the neutralizing absorbent and passing the exhaust gas through a filter which has been precoated with such an auxiliary agent as used above whereby the neutralizing absorbent and the auxiliary agent are permitted to deposit as a layer on the precoated filter and are able to collect acidic gas components remaining in the exhaust gas and a dust; and blowing ammonia into the purified exhaust gas so that nitrogen oxides in the exhaust gas are reduced in the presence of a denitrating catalyst into nitrogen gas. 2. A process according to Claim l, wherein said neutralizing absorbent is a powder or slurry of Ca(OH)₂, CaCO₃ or a mixture thereof. 3. A process according to Claim l, wherein said auxiliary agent is at least one member selected from the group consisting of zeolite, alumina, diatomaceous earth, perlite, activated clay, kaolin, feldspar, quartz and mixtures thereof in the form of powder.

Inventors: HORAGUCHI, MITSUHIRO C/O YOKOHAMA DOCKYARD &, KAIHARA, YUJI C/O YOKOHAMA DOCKYARD &, TOMIZAWA, SHIGECHIKA C/O YOKOHAMA DOCKYARD &, Horaguchi, Mitsuhiro c/o YOKOHAMA DOCKYARD &amp;, Kaihara, Yuji c/o YOKOHAMA DOCKYARD &amp;, Tomizawa, Shigechika c/o YOKOHAMA DOCKYARD &amp;
Applicants: MITSUBISHI JUKOGYO KABUSHIKI KAISHA
Application year: 1986
Main classification: B01D53
IPC codes: B01D53, F23J15, B01D37