AN EASY TO OPEN PACKAGE AND A METHOD OF MAKING SAME

Abstract: An easy to open package wherein an article is sealed between upper and lower thermoplastic webs comprises a) an upper web having a contact surface of a first polymeric material b) a lower web having a contact surface of a second polymeric material, and c) a seal layer disposed between said surfaces and adhered to each of said opposite surfaces, the adhesive seal strength of the seal layer to the first and second surfaces being greater than its internal cohesive strength, said seal layer comprising i) a first poiymer having a relatively low melt flow index selected from the group consisting of ionomers and ethylene vinylacetate copolymers, and ii) a second polymer having a melt flow index substan­ tially higher than the first polymer and being selected from the group consisting of low density polyethylene, ethylene/­ vinyl acetate copolymers, and modified ethylenervinyl ace­ tate copolymers, whereby the second polymer is a low density polyethylene if the first polymer is an ethylene/­ vinylacetate copolymer.

Description: The invention relates to an easy to open package wherein an article is sealed between upper and lower thermoplastic webs, and to a method of making such package. More specifically the invention is directed to a package which is tightly sealed and will not be easily destroyed by the usual handling during shipment and storage but which may easily be opened by manually peeling apart the upper from the lower web of the package. A wide variety of products, especially food products like meat, sausages, cheese and the like are being offered in visually attractive packages made from two thermoplastic webs using the vacuum skin packaging, thermoforming or other processes. In a vacuum skin packaging process a product is placed on a support film or formed tray of relatively rigid material and, by differential air pressure, a heated film above the product is molded down upon and around the product and against the support, the space between the upper film and the support having been evacuated. The upper heated film forms a tight skin around the product and is sealed to the support. In the thermoforming process the upper thermoplastic web is sealed to the flange-like edges of the support using heated sealing bars or similar equipment. The problem that is encountered is that the heated film seals so strongly to the support that it is difficult to separate the two webs and to open the package. An easy to open package comprising two thermoplastic webs safely sealed together should be easily openable by manually pulling apart the two webs, normally starting from a point like a corner of the package where the upper web has purposely not been sealed to the support. In this manner the use of scissors, a knife or other devices to open the package can be avoided. The easy to open packages of the prior art are based on three different mechanisms. The first concept is being widely used in thermoformed, formfill-seal and also in vacuum skin packages. When opening the package the separation between the two thermoplastic webs occurs at the seal interface, i.e. between the two contact surfaces sealed to each other. The opening or peeling strength (force per given width) is therefore identical to the seal strength and may be controlled by appropriate choice of the chemical similarity or dissimilarity of the two sealed layers. It is a disadvantage of this type of easy opening mechanism that it is strongly effected by the conditions of the sealing process. Thus, too high sealing temperatures will result in a stronger seal so that in turn the package can no longer be easily opened. Further, the opening or peeling strength will widely differ for a series of packages and a rupture of the upper web may occur during opening when it is sealed too strongly to the support web. The second and more recent easy opening mechanism is currently being used in many applications, for instance for rigid thermoformed containers sealed with a flexible film where the sealed areas are relatively narrow. Basically the opening of the package is achieved through an initial breakage through the thickness of one of the sealing layers followed by delamination of this layer from the underlying support or film. A typical example is a system where both the first and the second seal layer are made from polyethylene and one of the seal layers is adhered to a polyamide surface. The low bond strength between the polyethylene and the polyamide permits the delamination to take place during opening of the package. When the delamination reaches the area of the packed product a second breakage through the sealing layer takes place. As a result the entire sealing layer of one of the two webs is separated from one of the webs and is left sealed to the opposite web. The opening strength is directly related to the bond strength between the seal layer and the adjacent film layer and accordingly it depends primarily on the chemical similarity or dissimilarity of the two materials. However, the coextrusion conditions such as pressure, temperature and time of contact between the molten materials have also a major effect on the final bond strength between the two layers. The above described prior art easy opening systems are all based on an "adhesive failure" that takes place either at the seal interface between the two seal layers or through delamination of the seal layer from the corresponding underlying web. The systems are characterized by an opening strength which is not constant and can be either too low (which may lead to an inadvertent opening of the package) or too high (making it difficult to manually open the package). The opening strength of the known systems is significantly affected by the production conditions, the packaging machine conditions, and the environmental conditions (mainly temperature) during the packaging process and storage. Finally, easy to open packages are known in which the opening occurs through a cohesive failure mechanism which differs distinctly from the above described mechanisms using an adhesive failure opening mode. In this latter system the easy opening feature is achieved by internal rupture of a thin seal layer which during opening of the package breaks along a plane parallel to the layer itself. According to EP-B-15472 the cohesive failure of the seal layer is achieved by adding to the sealing composition solid particles of a size between 0.2 and 20 µm in an amount up to 25 % by weight. This additive weakens the internal strength of the seal layer so that a cohesive break of the seal layer can occur during the opening operation. US-A-4 469 754 proposes a heat seal composition for flexible film packages whereby the rupture of the peelable seals is preferably a cohesive failure in the heat seal composition itself. The disclosed heat seal composition comprises certain terpolymers together with ionomer resins in a specific ratio, the carboxylic groups of the two polymers being partly neutralized with zinc or magnesium ions which are coated onto the substrate packaging material. EP-A-3635 is directed to a different problem: It describes a self-welding packaging film which is used as upper and lower web. The seal layer is applied to both webs and a strong seal is obtained when contacting the two seal layers and heat sealing the films. There is no indication that the compositions described for the seal layer of the self-welding packaging film would be suitable as seal layer in an easy to open package showing cohesive break within the seal layer. Further, it is not disclosed to use modified ethylene/vinyl acetate copolymers having a high melt flow index. As shown below in comparative example A a modified ethylene/vinyl acetate copolymer with a low melt flow index is not suitable for an easy to open package. It is an object of the present invention to provide a package which is safely sealed and may be subjected to normal handling conditions during shipment and storage without inadvertent rupture but which provides at the same time easy to open characteristics , i.e. in which the two webs may be manually peeled apart applying a relatively low and constant force during the opening operation. The easy opening system should be based on internal rupture of a thin seal layer obtained from a sealing composition which provides a readily controllable broad range of cohesive strength values. It is a further object to provide a method of producing such package in a simple manner using existing conventional equipment. According to the invention the easy to open package with an article being sealed between upper and lower thermoplastic webs comprises an upper web of a first polymeric material and a lower web of a second polymeric material, and a seal layer disposed between and adhered to each of the opposite surfaces of the two webs, the adhesive seal strength of the seal layer to the first and second surfaces being greater than its internal cohesive strength, whereby when the upper and lower webs are peeled apart manually the seal layer separates due to internal cohesive failure and portions of the seal layer are left on the first and second surfaces. The seal layer is therefore characterized by comprising i) an ionomer having a melt flow index of less than 5, and ii) a modified ethylene/vinyl acetate copolymer having a substantially higher melt flow index, said melt flow indices of the two polymers in the seal layer differing by at least 10 when measured under the conditions E of ASTM D 1238. The high sealability to the two thermoplastic webs results in a strong seal which guarantees the pack integrity during handling. The low internal cohesive strength of the thin seal layer provides a constant opening strength of the package through breakage of this seal layer which splits during the opening operation, portions of the seal layer being left on the opposing surfaces of the two webs without impairing the visual appearance of the opened package or the product. Preferably the resistance of the seal layer to peeling from the surface of the upper or lower web is about 500 g/25 mm width stronger than the internal cohesive strength of the seal layer in order to provide for cohesive failure and to avoid delamination . The resistance of the seal layer to peeling from said surfaces may be about 1000 to 1500 g/25 mm width while the internal cohesive strength of the seal layer is preferably in the range of about 200 to 1000 and most preferably between 300 and 600 g/25 mm 20 width. The two polymers should not only have a different melt flow index but should also be chemically different in order to obtain the desired weakening of the internal structure of the seal layer. The difference between the melt flow indices of the first polymer and of the second polymer in the polymer blend for the seal layer will be at least 10 and more preferably more than 20 when measured under the conditions E of ASTM D 1238. Suitable first polymers for the seal layer blend are polymeric materials having a low melt flow index of less than 5 and more preferably less than 2. Examples are ionomeric resins such as acid-modified polyethylene with an acid content of up to 10% by weight and a high degree of ion linking (Na). Such polymers are commercially available under the trade name SURLYN® (DuPont). The second polymer in the seal layer blend has a melt flow index which is preferably 20 or higher. Examples for suitable polymers are acid modified ethylene/vinyl acetate copolymers such as BYNEL® (DuPont). Normally the blend comprises a major proportion of the first polymer and a minor proportion of the second polymer. Preferably the blend comprises about 10 to 50, especially 20 to 30% by weight of the second polymer (based on the blend). The two polymers are blended by thoroughly mixing them in powder form and then melt extruding the blend onto one or both webs of the package. Apparently the polymer having a high melt flow index is highly dispersed in the polymer having a low melt flow index and thereby weakens the internal cohesion of the seal layer. The total thickness of the seal layer is advantageously in the range of about 5 to 15 µm . A relatively thin seal layer is preferred since this will result in a rather smooth breakage due to cohesive failure parallel to the seal layer plane. A thicker layer may allow the breakage to occur in different zones or planes of the seal layer so that loose strips and rough surfaces are formed. As stated above it is important to achieve a relatively strong adhesion between the seal layer and the upper and lower web of the package, respectively. Accordingly the innermost layer of the two webs should be such that it provides good adhesion to the seal layer. Normally the seal layer will only be provided on one of the two webs and if this is carried out in a coextrusion process a thin support film for the polymer blend forming the seal layer will preferably be used; this support film will at the same time serve to promote the adhesion between the seal layer and the underlying web. The contact surface of the opposite web should also be provided with a top layer showing good adhesion to the seal layer. Alternatively it is possible to provide this adhesion promoting layer on top of the seal layer so that the former will only come into contact with the second web when the sealing operation is carried out. As stated above the present invention provides particular benefits when used in vacuum skin packages but its applicability is not restricted thereto. It is also useful in thermoforming, form fill seal and other packages. The chemical composition and structure of the two thermoplastic webs forming the package is not critical, provided that the adherence between the seal layer of the invention and the contact surface of the thermoplastic webs is sufficiently strong so that during opening of the package no delamination will occur. Mono- or multiply webs may be used as they are known to the expert skilled in the packaging art. The thermoplastic webs may also be oriented and/or irradiated in order to provide heat shrink properties. The following examples serve to further illustrate the invention which, however, is not limited thereto. Examples 1 and 2 and comparative examples A to D In order to have identical conditions for the comparison of the behaviour of the seal layer, all other structural characteristics and process parameters were held identical or constant, respectively. The seal layer was in all cases provided on the bottom web and tested in a vacuum skin packaging process using a CRYOVAC® vs 44 machine. The machine conditions were as follows: The bottom web consisted of a semi-rigid structure comprising a calendered rigid polyvinyl chloride sheet (200 µm) laminated to a two ply sealing layer film (total thicknes 33 µm ) produced by hot blown coextrusion and consisting of a support film of ethylene/vinyl acetate copolymer (vinyl acetate content 3%) having a thickness of 25 µm and a seal layer of the polymer blend to be tested having a thickness of 8 µm. As the top web a flexible coextruded film was used with a contact surface of an ionomeric resin (SURLYN® 1702 of Dupont) having a thickness of 19 µm . Both irradiated and non-irradiated top webs were tested. The test results are summarized in the following table 1 in which structures according to the present invention are designated with numbers 1 and 2 while comparative structures are designated A to D. Each quoted result of the packaging opening strength is the average of 9 samples. Before being tested the samples (width 25 mm) were stored for at least 2 hours at room temperature after the packaging process on the CRYOVAC®VS 44 machine. The tests were run on an Acquati dynamometer at a testing speed of 80 cm/min. The raw materials used in the tests tabulated in table 1 are listed and described in table 2. The above results show that the desired seal layer having low internal cohesive strength is not obtained when two polymers are blended, the melt flow indices of which do not differ by at least 10 (tests A and B) that the internal cohesive strength is also too great if the two polymers are chemically too similar, e.g. are ethylene/acrylic acid and ethylene/vinyl acetate copolymers (tests C and D). On the other hand, excellent results are obtained when the seal layer blend comprises two polymers of sufficiently different melt flow index provided that the two polymers are chemically also different (examples 1 and 2). Normally the proportion of the second polymer having the higher melt flow index will not exceed 30% by weight (based on the polymer blend). combinations, e.g. that of example 1, are operable in a broad range of 50 to 90% by weight of the first polymer and 10 to 50% by weight of the second polymer. Compositions comprising more than 30% by weight are useful as peelable seal layer for packages produced via conventional thermoforming, i.e. manufactured with thermoforming machines utilizing hot sealing bars, frames or plates. A blend of DuPont SURLYN® 9520 (from 50% up to 70% b.w.) and DuPont BYNEL®1124 (from 30% up to 50% by weight) is useful as peelable sealing layer, that offers an easy peeling performance, similar to the one achievable with the blend based on DuPont SURLYN®1601 and DuPont BYNEL® resins. The attached drawings serve to further illustrate the invention. Figures 1 to 3 illustrate schematically the opening mechanism of one embodiment of a package according to the invention. Figure 4 is a graph comparing the opening strength required to open a conventional package and the easy to open package of the invention. Figure 1 shows the sealing of a package according to the present invention comprising an upper web 1 and a lower web 2. The upper web consists of a thermoplastic multiply film 11 of which the innermost layer 12 consists of a thin (about 20 µm ) layer of an ionomeric resin to promote the adhesion to the seal layer. The lower web 2 consists of an outer layer 21 which may be of flexible or rigid polyvinyl chloride. The contact surface opposed to the upper web is provided with a layer 22 of an ethylene/vinyl acetate copolymer serving as a support film for the thin seal layer in the coextrusion process in which a very thin layer of the polymer blend for the seal layer would otherwise be difficult to handle. The thin (about 8 µm ) seal layer 23 is provided on the inner contact surface of the lower web 2. Upon sealing of the two webs to form a package the seal layer 23 will strongly adhere to the inner contact surface 12 of the upper web. When tearing the package open as illustrated in figure 2 by peeling the upper web 1 apart from the lower web 2 the break does not occur along the seal interface (dotted line 31) but rather within the seal layer 23 so that a portion 32 thereof sticks to the upper web while the remainder 33 is left on the lower web 2, compare also figure 3 showing the two webs after complete separation from each other. Figure 4 represents a graph in which the opening strength in kg/25 mm width has been plotted against the sample length in mm. Curve a represents a conventional "easy to open" package in which the break occurs due to adhesive failure. It is obvious that the necessary opening strength is relatively high and not constant over the sample length. Curve b for a package of the present invention shows that the required opening strength is much lower and essentially constant over the entire length of the samples.

Claims: An easy to open package wherein an article is sealed between upper and lower thermoplastic webs comprising a) an upper web having a contact surface of a first polymeric material b) a lower web havin a contact surface of a second polymeric material, and c) a seal layer disposed between said surfaces and adhered to each of said opposite contact surfaces, the adhesive seal strength of the seal layer to the first and second surfaces being greater than its internal cohesive strength, characterized in that the seal layer comprises i) an ionomer having a melt flow index of less than 5, and ii) a modified ethylene/vinyl acetate copolymer having a substantially higher melt flow index, said melt flow indices of the two polymers in the seal layer differing by at least 10 when measured under the conditions E of ASTM D 1238. A package according to claim 1 in which the resistance of the seal layer to peeling from said surfaces is about 500 g/25 mm width stronger than the internal cohesive strength of the seal layer. A package according to claim 1 in which the resistance of the seal layer to peeling from said surfaces is about 1000 to 1500 g/25 mm width while the internal cohesive strength of the seal layer is about 200 to 1000 g/25 mm width. A package according to claims 1 to 3 in which the melt flow indices of the two polymers in the seal layer differ by more than 20 when measured under the conditions E of ASTM D 1238. A package according to anyone of claim 1 to 4 in which the seal layer has a total thickness in the range of about 5 to 15 µm. An easy to open package according to anyone of claims 1 to 5 in which the seal layer material is adhered to one or both of the opposite contact surfaces of said two webs by being coextruded therewith or laminated thereto and the seal layer is formed by sealing the two webs with their opposite surfaces by a vacuum skin packaging, a thermoforming or other process. A method of making a readily peelable seal in an easy to open package by disposing a seal layer between two opposite polymeric surfaces or two thermoplastic webs forming the package, the adhesive strength of the seal layer to each surface being greater than the internal cohesive strength of the layer, characterized in that the seal layer comprises a) an ionomer having a melt flow index of less than 5 and b) a modified ethylene/vinyl acetate copolymer having a substantially higher melt flow index, said melt flow indices of the two polymers in the seal layer differing by at least 10 when measured under the conditions E of ASTM D 1238. The method according to claim 7 comprising the steps of a) providing on one or both contact surfaces of the thermoplastic webs a sealing material layer by coextrusion or lamination of the web and the sealing material, and b) sealing the two webs by a heat sealing process thus forming the seal layer between said thermoplastic The method of claim 8 in which the heat sealing of the thermoplastic webs is accomplished by a vacuum skin packaging or a thermoforming or other process. A seal layer for an easy to open package comprising a) an ionomer having a melt flow index of less than 5 and b) a modified ethylene/vinyl acetate copolymer having a substantially higher melt flow index, said melt flow indices of the two polymers in the seal layer differing by at least 10 when measured under the conditions E of ASTM D 1238. A seal layer according to claim 10 in which the melt flow indices of the two polymers in the seal layer differ by at least 20 when measured under the conditions E of ASTM D 1238. A seal layer according to anyone of claims 10 to 12 in which the seal layer has a total thickness in the range of about 5 to 15 µm. A thermoplastic web for use in making an easy to open package, said web comprising a mono- or multilayer thermoplastic film or sheet having an outer contact and sealing surface layer comprising a) an ionomer having a melt flow index of less than 5 and b) a modified ethylene/vinyl acetate copolymer having a substantially higher melt flow index, said melt flow indices of the two polymers in the seal layer differing by at least 10 when measured under the conditions E of ASTM D 1238. A thermoplastic web according to claim 13 in which the melt flow indices of the two polymers in the seal layer differ by at least 20 when measured under the conditions E of ASTM D 1238. A thermoplastic web according to anyone of claims 13 or 14 in which the seal layer has a total thickness in the range of about 1 to 15 µm. A thermoplastic web according to anyone of claims 13 to 15 in which on top of the seal layer there is provided a layer of a material promoting the adhesion to the contact surface of the other web.

Inventors: BOTTO, PAOLO, FRESCHI, CLAUDIO, OREGLIA, AURELIO
Applicants: W.R. GRACE & CO.-CONN. (A CONNECTICUT CORP.)
Application year: 1986
Main classification: B32B7
IPC codes: B65D75, B32B27