METHOD OF TREATING WASTE WATER AND EQUIPMENT THEREFOR

Abstract: In the method of treating high-concentration organic waste water in dependence upon microorganism, waste water is first anaerobically treated in an anaerobic operation tank (2) in dependence upon anaerobic bacteria groups and methane bacteria groups; in the second step, the waste water is further aerobically treated repeatedly in an aerobic operation tank (6), and an organic substance as hydrogen donor (raw waste water) is supplied to the aerobic operation tank before the succeeding aerobic treatment; in the third step, ozone treatment (8) is effected to decolor the treated water. Two seed bacteria culture tanks (4,9) for sludge bacteria and methane bacteria are provided separately to supply bacteria to the anaerobic operation tank for providing further reliable decomposition and denitrification of organic substance into methane and nitrogen gasses.

Description: The present invention relates to a method of treating waste water or sewage and equipment for realizing the method and more specifically to a waste water treatment method by which organic substances included in waste water can be decomposed in dependence upon microorganisms, that is, biological treat­ ment. As a method of treating high-concentration organic waste water represented by sewage discharged from homes or excrementitious matter (faeces and urine) discharged from barns, it has been conventional to adopt a method which combines a septic tank based upon mainly anaerobic treatment and an aerobic treatment tank disposed after the septic tank for realizing the trickling filter method, the activated sludge method or the contact aeration method, etc. In these methods, however, there exist the following problems. (1) Since a many-hour aeration is required, the power consumption is relatively great. (2) Dilution is required. (3) Maintenance and management are troublesome. (4) The treatment and disposal of the produced sludge is difficult. In addition, although a great amount of nitrogen, in particular, is included in the excrementitious matter, it is impossible to sufficiently eliminate the nitrogen on the basis of the conventional methods. Furthermore, a colored substance formed by bile coloring matter and mainly consisting of stercobilin is included in the excrementitious matter, and since it is impossible to eliminate this colored substance using conventional methods, this colored substance is included in the treated waste water. When this substance is discarded into rivers, the rivers are colored, thus resulting in water polution from the standpoint of the sense of sight. On the other hand, batch-type activated sludge methods have recently been highlighted, mainly in small-scale sewage treatment or operation equipment. In this method, waste water is introduced into a liquid mixed with activated sludge put in a treatment tank, and aeration, solid-liquid separation and supernatant outflow are effected in series in this treatment tank. This method has various advantages such that: (1) bulking (malsedimentation) will not occur; (2) this method is of an energy saving type; and (3) no high-­ degree operation technique is required. Furthermore, as compared with the conventional continuous treatment operation, it has been reported that the denitrification effect and the dephosphorization effect are high because aeration and sedimentation are repeated. In the batch type activated sludge method, however, the high effect of denitrification has only been reported on an empirical basis, and there exists no guarantee that the high denitrification effect can always be obtained whenever the equipment is actually operated. Furthermore, with respect to the structure of the equipment, since an overflow method cannot be adopted to flow out the supernatant waste water as in the usual continuous operation, an appropriate mechanism has so far been required. In the method of treating live sewage, livestock waste, etc., e.g. as is represented by the activated sludge method, biological treatment methods based upon the metabolic action of a microorganism group have mainly been adopted. To realize these methods, use has been made of the activated sludge method or biological membrane method, in which a mixed microorganism group is cultured collectively. However, recently, proposals have been made for a system in which a nitrification reaction is effected separately from the denitrification reaction. That is, in these methods, plural treatment tanks are provided for enhancing each peculiar reaction separately. This is bescause it is possible to realize a condition under which a reaction peculiar to an microorganism can readily be enhanced as much as possible, that is, the treatment system can be realized in natural fashion. In order to realize such a treatment system as described above, it is necessary to device a special structure for the treatment tank. However, it is difficult to obtain a treatment which meets the desired object in dependence upon only the tank structure. Further, organic substances in waste water can be decomposed by aerobically treating the waste water by the activated sludge for denitrification or dephosphorization, and there-­ after the treated waste water is discharged into rivers after disinfection by an antiseptic solution. However, in the case of excrementitious matter, colored substances formed by bile coloring matter mainly consisting of stercobilin are included in the finally treated waste water. Therefore, the treated and discharged waste water is colored, thus resulting in water pollution. With these problems in mind, therefore, it is the primary object of the present invention to provide a waste water treating method and an equipment by which the maintenance and management are simple, by which dilution is not required, by which nitrogen can be adequately eliminated as well as organic substances, and by which power or energy consumption can be economized. It is the other object of the present invention to provide a waste water treating method and an equipment by which the treated waste water can be decolored so as not to cause water pollution. In order to satisfy this object there is provided a method of treating organic waste water which contains nitrogen, the method comprising the following steps: (a) anaerobically treating the waste water in dependence upon a plurality of groups of anaerobic bacteria for the decomposition and denitrification of organic substances included in the waste water; (b) further decomposing the organic substances by passing the anaerobically treated waste water through at least one biological contact zone composed of media including a plurality of groups of methane bacteria for generation of methane gas on the basis of decomposition action of the methane bacteria groups; (c) repeatedly aerating the anaerobically treated waste water by (c1) mixing the waste water with activated sludge; (c2) aerating the waste water mixed with sludge for effecting aerobic treatment in dependence upon aerobic bacteria groups included in the activated sludge; (c3) stopping the aeration and settling the sludge under aerobic conditions; (c4) mixing the treated water with organic substances including a hydrogen donor; and (c5) aerating again the mixed treated water again for elimination of the further organic substances in dependence upon aerobic bacteria groups; (d) settling the sludge for separation of supernatant liquid to be flowed out from above the sediment of the sludge; and (e) separately culturing anaerobic bacteria and methane bacteria and using them in steps a) and b) respective­ ly. The facultative anaerobic bacteria are cultured under anaerobic conditions on the basis of settled sludge, raw waste water and a culture liquid in a first seed bacteria culture tank, and the cultured sludge bacteria are used for anaerobically treating the waste water. The methane bacteria are cultured on the basis of raw waste water and a culture liquid in a second seed bacteria culture tank, and the cultured methane bacteria are intermittently supplied to the biological contact zone for generation of methane gas. The treated supernatant liquid is further ozone-treated for decolorization of the treated waste water. Part of the ozone-treated waste water is returned and anaerobically treated again as circulating treated waste water. An apparatus for treating waste water according to the present invention is set forth in claim 8 and preferred embodiments of the method and apparatus of the invention are set forth in claims 2 to 7 and 9 to 25 respectively. The features and advantages of the method of treating waste water and the apparatus therefor according to the present invention will be more clearly appreciated from the following description of the preferred embodiment of the invention taken in conjunction with the accompanying drawings in which like reference numerals designate the same or similar elements or sections throughout the figures thereof and in which: Fig. 1 is a model block diagram for assistance in explaining nitrification/denitrification reactions of various bacteria against organic nitrogen; Fig. 2 is a diagrammatic process diagram showing the process and the equipment of an embodiment of the present invention; Fig. 3 is a longitudinal diagrammatic view showing an anaerobic operation tank, and the first and second seed bacteria culture tanks; Fig. 4 is a longitudinal diagrammatic view showing an aerobic operation tank; Fig. 5 is a treatment process diagram in the aerobic operation tank; Fig. 6 is a longitudinal diagrammatic cross-sectional view showing an outflow mechanism of the aerobic operation tank; Fig. 7A is a longitudinal diagrammatic cross-sectional view showing an ozone treatment tank; Fig. 7B is a longitudinal diagrammatic cross-section al view showing an example of a combination between the aerobic operation tank and the ozone treatment tank; and Fig. 8 is a longitudinal diagrammatic cross-sectional view showing a seed sludge culture tank. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS To facilitate understanding of the biological treatment,a brief reference will be made to Fig. 1, by way of example, to the process by which organic nitrogen compounds such as protein is decomposed through nitrification reaction and denitrification reaction of various kinds of bacteria. In Fig. 1, the bacteria enclosed by frames are heterotrophy, and the bacteria other than those are autotrophy. Further, the reactions shown by dashed lines denote a nitrification reaction occuring under aerobic conditions, while those shown by dot-dashed lines denote a denitrification reaction occuring under anaerobic conditions. Denitrification reactions can be expressed stoichiometrically as follows: where the formula (1) corresponds to nitrous acid respiration and the formula (2) corresponds to nitric acid respiration, respectively. The (H₂) of these reactions is given by a hydrogen donor by way of the biological process in a respiration enzyme within bacteria, and almost all denitrification bacteria react with organic substances as hydrogen donors. With reference to the attached drawings, the method and equipment of the present invention will be described hereinbelow. The features of the present invention are (1) to provide an aerobic operation tank after an anaerobic operation tank; (2) to effect a two-stage aerobic treatment in the aerobic operation tank; (3) to a culture plural groups of bacteria in two separate tanks before being supplied to an anaerobic operation tank; (4) to provide a novel waste water outflow mechanism by a combination of a floating body and a flexible pipe in the aerobic operation tank; and (5) to effect ozone treatment before discharging the treated waste water into a river. Fig. 2 is a process diagram showing the method of this embodiment. On the basis of this drawing, the process of waste water treatment will be described in sequence. Further, the detail of each treatment process and the equipment used at each process will be described with reference to Figs. 3 and sequel. First, waste water discharged from a livestock house as for hogs A and including waste (excrements) and foul water is passed through a vibration bolter B to remove miscellaneous things such as feathers and feed dregs and then stored in a raw waste water (livestock sewage) storage tank 1. If fine miscellaneous things are not included in the waste water, it is possible to use a screen in place of the vibration bolter B. The raw waste water is fed from the raw waste water storage tank 1 to an anaerobic operation tank 2 through a measuring tank 11 at a constant flow rate or on the basis of overflow from the raw waste water storage tank 1 according to the amount of inflow quantity. The anaerobic operation tank 2 shown in detail in Fig. 3 effects denitrification reaction and methane fermentation in the sewage treatment process. The numeral 21 denotes an introduction chamber into which the high-concentration organic waste water such as livestock waste water, is introduced. The upper portion of this chamber is exposed to the atmosphere. At the liquid surface portion of this introduction chamber 21, a plurality of introduction pipes 22 having a large number of 4 to 5 mm dia. holes are mounted in such a way as to extend in the vertical direction. Since plural introduction pipes are provided, the scum produced at the liquid surface portion sticks on the circumferences of the introduction pipes, and the waste water flows downstream through between the introduction pipes 22 or through the holes formed in the introduction pipes 22. Therefore, the flow from the liquid surface portion to the bottom portion in the introduction chamber 21 is smooth downstream. The reference numeral 23 denotes an anaerobic treatment chamber whose bottom portion communicates with the bottom portion of the introduction chamber 21 and whose upper portion is airtightly closed. At the middle portion of the anaerobic treatment chamber 23, a partition 24 forming a zigzag path is provided to pass the waste water in the upward direction and then in the downward direction. In this embodiment, this partition wall 24 forms a first chamber 23a and a second chamber 23b in symmetrical positional relationship thereto in the drawing. The reference numeral 25 denotes an outflow chamber whose bottom portion communicates with the bottom portion of the anaerobic treatment chamber 23 and whose upper portion is open to the atmosphere. In this outflow chamber 25, there is provided an overflow portion 26 for the overflow of the waste water flowing in the upward direction from the bottom portion thereof, for instance, such as a V-notch shaped overflow portion 26 having a triangular upper edge for separating scum from the waste water. Each portion of the anaerobic operation tank 2 will now be described in further detail. In the second chamber 23b of the anaerobic treatment chamber 23, plural steps of biological contact zones 3a made of the media on which methane bacteria are attached and fixed are disposed at intervals in the upward direction. An aquifer 3b is formed between the two biological contact zones 3a. When the aquifer 3b is formed as described above, since buffer function is provided, it is possible to prevent the production of shorted stream flowing by shorting the biological contact zones 3a. As the medium for the biological contact zone 3a, it is preferable to use a material which can easily catch methane bacteria, for instance, such as a shell of surf clam, hog bone or porous ceramics. The above-mentioned biological contact zone 3a and the aquifer 3b are formed in the outflow chamber 25 in the same way. The biological contact zone 3a serves to heighten the contact efficiency between the methane bacteria and the waste water, and further serves to eliminate suspended solids in the waste water. In particular, these zones serve to prevent the generation of scum in the outflow chamber 25. In the top wall of the anaerobic chamber 23, a gas outlet 27 is formed as a gas extracting portion to let gas generated within the anaerobic treatment chamber 23 out of the tank 2. The as extracted therethrough is directed through a valve V₁ into a gas holder (not shown). Since the anaerobic treatment chamber 23 is closed in airhight manner and since the introdution chamber 21 and the outflow chamber 25 are exposed to the atmosphere, the gaseous phase pressure in the anaerobic treatment chamber 23 is determined on the basis of the difference in liquid surface level between the anaerobic treatment chamber 23 and the introduction/outflow chambers 21 and 25. Further more, since the liquid surface level of the latter can be adjusted according to the height of the overflow portion 26, the height in the outflow chamber 25 which exceeds the liquid surface level of the anaerobic treatment chamber 23 functions as a pressure regulating means which can adjust the pressure of the gaseous phase portion. Since the pressure in the gaseous phase portion is adjusted by the pressure regulating section, it is possible to control the pressure in the gaseous portion within an appropriate pressure range so as not to suppress the reaction of methane fermentation, that is, so that the pressure in the gaseous portion is not excessively high. In addition, when the gas produced within the anaerobic treatment chamber 23 is used, the gas pressure can automatically be adjusted at a constant level. Therefore, it is possible to effectively utilize the as without increasing the gas space or a dead space. Further, on the outside of the overflow portion 26, there is disposed a scum storage portion 28 for storing scum flowing beyond the overflow portion. The scum stored therein is appropriately removed through a scum extracting valve V₂. This scum storage portion 28 is further provided because scum flows beyond the overflow portion 26 after scum has been removed by the biological contact zones 3a. The reference numeral 29 denotes a outflow portion for flowing out the treated waste water flowing beyond the scum storage portion 28. Further, the symbols V₃ and V₄ shown in the drawing denote sludge extracting valves. In Fig. 3, the reference numeral 9 denotes a first seed bacteria culture tank in which a group of facultative anaerobic bacteria including anaerobic organic substance decomposition bacteria, anaerobic acid forming bacteria and denitrification bacteria is cultured with a culture liquid peculiar to these bacteria and the waste water to be treated in the anaerobic operation tank 2 as substrate. As the facultative anaerobic bacteria one has available excessive sludge or its concentrated sludge produced in an aerobic operation tank 6 (described later) disposed after the anaerobic operation tank 2. The sludge is fed to a first seed bacteria culture tank 9 by the pump P₁. In the drawing, the reference numeral 4 denotes a second seed bacteria culture tank in which the methane bacteria group is cultured with a culture liquid peculiar to the bacteria and the waste water to be treated as basic material. The operation of the above equipment will be described hereinbelow. A high-concentration organic waste water such as livestock house waste water, for instance is introduced from the upper portion of the introduction chamber 21, and then introduced through the introduction pipes 22, as a downstream flow, to the bottom portion of the introduction chamber 21. On the other hand, the facultative anaerobic bacteria group cultured in the first seed bacteria culture tank 9 is intermittently supplied by the pump P₂, and the waste water is mixed with this anaerobic bacteria group. Thereafter, the waste water flows in the upward direction from the bottom portion of the first chamber 23a of the anaerobic treatment chamber 23, overflows beyond the upper edge of the partition wall 24, passing through the biological contact zones 3a and the aquifers 3b alternately from the upper portion of the second chamber 23b and flows from the bottom portion to the upper portion in the outflow chamber 25. The methane bacteria group cultured in the second seed bacteria culture tank 4 are intermittently supplied to the biological contact zones 3a by the pump P₃. Therefore, when the waste water flows in accordance with the path as described above, the organic substance changes into low molecule substances and further denitrification reaction occurs in dependence upon the action of the anaerobic bacteria group. Thereafter, the low molecule organic substances such as the organic acids, alcohols, etc. are decomposed to produce gas such as methane gas and carbon dioxide in dependence upon the action of the methane bacteria group strick onto the biological contact zones 3a. The gas produced as described above is collected in the gas holder (not shown) through the gas outlet port 27 so as to be effectively available as fuel. Further, when the waste water is passed through the biological contact zones 3a, the suspended solids are eliminated to purify the waste water. If the waste water reaches the overflow portion 26 of the outflow chamber 25 under the treatment thus explained, the waste water is separated into scum and treated waste water. The treated waste water falls into the scum storage portion 28 to remove scum still included in the treated waste water, and then flows out through the outflow portion 29. When the waste water anaerobic operation tank 2 as described above is adopted, since organic substances are decomposed and denitrified by the anaerobic bacteria group at the first stage and by the methane bacteria group at the second stage, the decomposition of organic substances is enhanced; waste water can be treated well, and it is possible to effectively utilize the methane gas which is produced and collected. The waste water treated by the anaerobic operation tank 2 as described above is fed to a succeeding stage aerobic operation tank 6 through a bypass pipe continuously or after having accumulated once in a buffer tank (an adjustment tank) 61 intermittently. The former case (bypass) is referred to as continuous inflow type, while the latter case (adjustment tank) is referred to as batch inflow type. Fig. 4 shows the aerobic operation tank 6 and Fig. 5 shows the treatment process in the aerobic operation tank 6. The structure of the aerobic operation tank and the treatment process carried out therein will be described with reference to these drawings. In Fig. 4, the reference numeral 62 denotes a blower; 63 denotes diffuser means; 64 denotes mixture agitator means; M1 denotes a motor. In this aerobic operation tank 6, a mixture liquid of activated sludge is previously accomodated to form a base waste water level B.W.L. The waste water anaerobically treated in the anaerobic operation tank 2 is flowed in to a predetermined water level in the aerobic operation tank 6, and is agitated by the agitator means 64 to sufficiently mix the waste water and the activated sludge.Inthermore, the agitation process may be unnecessary if the waste water and actuated sludge are sufficiently mixed in the inflow process. Thereafter, the blower 62 is driven to discharge air via the diffuser means 63, by which the aerobic operation tank 6 is aerated for a predetermined hour. In this aeration process, the aerobic treatment is effected in dependence upon the aerobic bacteria group within the activated sludge, so that organic substance in the waste water is decomposed and the nitrification reaction progresses. After sufficient aeration, organic substances are sufficiently eliminated. After a sufficient nitrification, the aeration is stopped to settle the sludge. After the settled sludge has reached the anaerobic condition in this sedimentation process, an appropriate amount of a hydrogen donor such as raw waste water is intermittently flowed in from the raw waste water storage tank 1 into the aerobic operation tank 6. In the agitation process by the agitator means 64, the organic substances in the raw waste water are mixed with the sludge and the supernatant liquid. Here, the reason why the raw waste water is intermittently flowed in is to replenish organic substances as hydrogen donor as described later. The denitrification bacteria in the sludge take hydrogen from the organic substances via biological process of respiration enzyme in the agitation process, and the hydrogen is reacted with N0₃ - and N0₂ - included in the nitric acid and the nitrous acid formed in the aeration process to eliminate nitrogen by deoxidizing N0₃ - and N0₂ - into nitrogenous gas. Thereafter, aeration is effected again to eliminate the remaining organic substances in dependence upon the aerobic bacteria group and to nitrify ammonium component. Subsequently, the aeration is stopped to settle the sludge. Further, in Fig. 4, the symbol P1 denotes a sludge extracting pump; 65 denotes a manual valve. The sediment of sludge precipitated in the aerobic operation tank 6 is extracted by the pump P1, and fed into the seed sludge culture tank 9 or flowed out of the system by the manual valve 65 as excessive sludge. In the sludge extraction process, the appropriate sludge extraction is to such an extent that the sludge retention time (SRT) is from 30 to 50 days. The supernatant liquid in the aerobic operation tank 6 is flowed out by a outflow mechanism 7 described later and then fed to the succeeding step ozone treatment tank 8. As shown in Figs. 4 and 6, the outflow mechanism 7 comprises two floating bodies 71 floated on the liquid surface in the aerobic operation tank 6, a cover portion 72 attached to these floating body 71 and serving as a cylindrical filter portion having an open bottom end, a flexible pipe 73 having one end formed with a waste water inlet port and inserted into the cover portion 72 with an outer diameter a little smaller than an inner diameter of the cover portion 72, a metal fixture 74 for fixing the flexible pipe 73 to the cover portion 72, an outflow pump P4 connected to the other end of the flexible pipe 73 via an outflow pipe 75 so as to suck the treated waste water through the water inlet port, and a manual valve 76 and a motor driven valve 77 disposed on both the sides of the outflow pump P4, respectively, as discharge valves. In the discharge mechanism 7 as described above, the flexible pipe 73 is always filled with the treated waste water other than the outflow process. Therefore, when the outflow pump P4 is driven in the outflow process, the supernatant water is sucked up through the opening end of the cover portion 72, passed through the water inlet port of the flexible pipe 73, and then flowed out toward the outside as the treated waste water. Where the outflow mechanism as shown is used, since the supernatant liquid can be sucked at the position below the liquid surface level, the scum flotation on the liquid surface level will not be sucked. Further, since the waste water is sucked up through a space formed between the cover portion 72 and the flexible pipe 73, solid substances such as sludge can be eliminated, thus resulting in an advantage such that the pie will not be clogged. Further, the outflow speed of the supernatant waste water can be adjusted by the valves 76 and 77. In the drawing (Fig. 4), the symbol H.W.L. denotes the high limit waste water level. Further, the quantity of raw waste water supply can be determined as follows: In the nitric acid respiration, since the amount of the theoretical oxygen demand (ThOD) corresponding to hydrogen donor 5(H₂) is stoichiometrically 5(0), the amount of 12.5% ThOD can be calculated as the amount of theoretically doped hydrogen. The assumption is made that ThOd = B0D₅, B0D₅ of 2.86 kg is necessary to denitrify N0₃ of 1 kg. Therefore, it is possible to determine this amount of supply on the basis of the raw waste water treating condition. An ozone treatment tank 8 disposed after the anaerobic operation tank 6 will be described with reference to Fig. 7A. In Fig. 7A, the numeral 81 denotes a waste water tank. The waste water treated in the aerobic operation tank 6 is supplied through a waste water supply path 81a connected to the bottom portion of this waste water tank 81. The reference numeral 82 denotes a circulation waste water path, whose outlet is open to near the bottom portion of the waste water tank 81 and whose inlet is open to the waste water tank 81 at a position higher than that of the outlet. An ejector pump P5 is provided in this circulation waste water path 82. The numeral 83 denotes an ozone gas generator. Ozone gas is jetted into the ejector pump P5 when a compressor 84 is driven. Further, the outlet of the circulation waste water path 82 is so disposed that the treated waste water ejected from the outlet is flowed upward along the tangential line direction of a circle having a diameter a little smaller than the inner diameter of the waste water tank 81. The numeral 85 denotes an outflow communication path, which extends from above in the downward direction and then bends so as to go up with the outlet opened to the atmosphere. The numeral 86 denotes a top wall portion, and an air-tightly closed space 87 is formed between the wall portion 86 and the liquid surface. The numeral 88 denotes an overflow portion; 88a denotes a receiver portion. The treated waste water flowing through the communication path 85 flows into the receiver portion 88a beyond the overflow portion 88. The numeral 89 denotes an ozone gas treating section. The ozone gas filling the closed space 87 is introduced through the exhaust path 86a connected to the top wall portion 86 and treated in such a way as to be absorbed by an absorbent or deoxidization into oxygen by a reducing agent. The reason why the ozone gas is treated is that ozone gas exerts a harmful influence upon the human body when exhausted into the air as it is. In the above ozone treatment tank 8, the waste water treated in the aerobic operation tank 6 is continuously supplied into the tank 81 from the bottom portion thereof through the outflow supply path 81a. The waste water flows up in the waste water tank 81, and art of the treated waste water circulates in the circulation waste water path 82. On the other hand, the ozone gas generated from the ozone gas generator 83 is jetted by the ejector pump P5, together with the waste water sucked through the circulation waste water path 82, from the outlet of the circulation waste water path 82 into the waste water tank 81 along the tangential line of a circle determined by the inner diameter of the waste water tank 81. By this, the ozone gas goes up in spiral fashion along the inner wall of the waste water tank 81 in contact with the inflow waste water. While the inflow waste water is in contact with the ozone gas, untreated organic substances are treated and in addition the colored substances are eliminated and further the inflow waste water is sterilized (disinfected). The ozone-treated waste water flows from the upper portion of the waste water tank 81 into the communication path 85, flowing once downward and then upward, and then drops in the receiver portion 88a after having overflowed beyond the overflow portion 88, before being discharged in the river as treated waste water. Further, the ozone gas flowing upward in the waste water tank 81 fills the closed space 87, and enters into the ozone gas treating section 89 through the exhausted path 86a, thereafter being exhausted into the atmosphere after the absorption and/or deoxidization treatment. Part of the treated wasted water in the ozone treatment tank 8 is returned by the circulation pump P6 to the introduction chamber 21 of the anaerobic operation tank 2 as circulating treated waste water. When the treated waste water is circulated as described above, since art of the treated waste water is further anaerobically treated by the anaerobic operation tank 2, it is possible to further enhance the denitrification effect. In the present invention, even where no ozone treatment tank 8 is provided for ozone treatment, it is possible to obtain a high denitrification effect in the same way by returning part of the treated waste water from the aerobic operation tank 6 to the introduction chamber 21 as circulating treated waste water. In order to supply the waste water from the aerobic operation tank 6 to the ozone treatment tank 8, it may be possible to connect the outflow mechanism 7 of the aerobic operation tank 6 and the ejector pump P5 of the ozone treatment tank 8 as shown in Fig. 7B. That is to say, in the case of the embodiment shown in Fig. 7B, a motor driven valve 78 and an additional manual valve 79 are provided for the outflow pipe 75 of the outflow mechanism 7, and the outflow pipe 75 is connected to the circulation path 82 through a T-shaped connection pipe 82b. The numeral 82a denotes a motor-driven valve. In such a construction as described above, since the waste water from the aerobic operation tank 6 is directly ozone-treated in the ejector pump P5, it is possible to further enhance the ozone treatment effect and to further reduce the degree of color in the treated waste water. Here, the supply of anaerobic bacteria group used in the anaerobic operation tank 2 will be described. In Fig. 2, the sludge extracted from the aerobic operation tank 6 and the raw waste water from the raw waste water tank 1 are fed into the seed sludge culture tank 9 to culture the sludge with the raw waste water as a culture fluid under anaerobic condition. The cultured facultative anaerobic bacteria (including denitrification bacteria) are intermittently supplied to the anaerobic operation tank 2. Fig. 8 shows an example of the seed sludge culture tank 9. A waste water agitator means 92 is provided in the culture chamber 91. The sludge cultured by this culture chamber 91 is supplied to the anaerobic operation tank 2 by the pump P2 together with the culture fluid. Further, in the case where the supply amount of the sludge is large, it is preferable to design a multiple tank structure, that is, to further provide culture chambers 92 to 94 as shown in Fig. 8 in order to obtain both the effects of buffer tanks and concentration tanks, without simply increasing the volume of the culture chamber. In Fig. 8, the numerals 95 to 97 denote communication path members, whose upper portion is open so as to facilitate the flow of the culture fluid and sludge. In the case of the multiple tank structure as described above, a pump (not shown) is provided for each culture chamber to supply the seed sludge into the anaerobic operation tank 2. According to the method of supplying the seed sludge to the anaerobic operation tank 2 by providing the seed sludge culture tank 9 as described above, a high denitrification effect is obtained, and further more the sludge extracated from the aerobic operation tank 6 can be utilized effectively. In the above description, the larger the volume of the anaerobic operation tank 2, the higher the treatment effect will be. However, if the tank 2 is large in volume, since the anaerobic tank is inevitably increased in size, it is appropriate to set the hydraulic retention time to about 5 days. Further more, with respect to each process control of the aerobic operation tank 6, although it is possible to implement a previously time-determined sequence control, it is also possible to adopt a control which determines the timing of each process on the basis of the waste water quality standard such as the oxidization reduction potential or the pH level. The latter method can be expect ed to provide an effective treatment. Further more, in the embodiment, when bacteria which can decompose decomposition-resistant substances such as PCB, ABS, etc. are screened and then used as seed bacteria or seed sludge, it is possible to biologically treat PCB or ABS. As described above, in the present invention, waste water is first anaerobically treated by anaerobic bacteria group and methane bacteria group in the anaerobic operation tank; is then aerobically treated in the aerobic operation tank; is subsequently anaerobically treated by supplying organic substance serving as hydrogen donor into the waste water under anaerobic conditions; and is then aerobically treated again. Therefore, it is possible to treat a high concentration organic waste water without dilution, to sufficiently decompose the organic substances, to obtain high denitrification effect, and thus to perform a good waste water treatment. In addition, since the control of the amount of dissolved oxygen is unnecessary as in the activated sludge method, the maintenance and management are simple. Further more, the method of the present invention is energy-saving because continuous aeration is unnecessary. Moreover, since the treatment by methane bacteria is utilized in the anaerobic tank, it is possible to expect a methane collecting effect. In additon, methane collecting effect is not expected, it is possible to treat organic waste water of low concentration. Further, when the water treated by the aerobic tank is further treated by ozone as in the ozone treatment tank, it is possible to disinfect the treated waste water and to eliminate colored substances, thus preventing the occurrence of water pollution. As described above, according to the present invention, since a two-stage batch method is adopted such that waste water is first aerobically treated and then anaerobically treated by supplying organic substances in the waste water as hydrogen donor under anaerobic conditions, and is then aerobically treated again, it is possible to adequately eliminate nitrogen included in nitric acid and nitrous acid formed by the aerobic treatment. The organic substances remaining after anaerobic treatment can be decomposed by the next-stage aerobic treatment. Therefore, it is possible to effect good sewage treatment. Therefore, since it is possible to use raw waste water as hydrogen donor in the anaerobic treatment, the running cost can be reduced. Moreover, in the equipment according to the present invention, it is possible to suitably realize the method of present invention by the above-mentioned equiment. Further more, since an outflow mechanism is used in which the floating bodies and the flexible pipe are combined with each other, it is possible to always suck the water from near the liquid surface level in spite of a simple mechanism. Therefore, since only the supernatant can be flowed out and the sucking pressure is constant irrespective of the liquid surface level, it is possible to smoothly outflow the treated waste water from the aerobic operation tank without clogging of the filter section. In addition, according to the present invention, since microorganism groups are cultured separately as seed bacteria group in correspondence to the object of the sewage treatment tanks, and supplied to the sewage treatment tanks, it is possible to enhance the sewage treatment function and to obtain a stable microorganism metabolic action.

Claims: 1. A method of treating organic waste water which contains nitrogen, the method comprising the following steps: (a) anaerobically treating the waste water in dependence upon a plurality of groups of anaerobic bacteria for decomposition and denitrification of organic substances included in the waste water; (b) further decomposing the organic substances by passing the anaerobically treated waste water through at least one biological contact zone composed of media including a plurality of groups of methane bacteria for generation of methane gas on the basis of decomposition action of the methane bacteria groups; (c) repeatedly aerating the anaerobically treated waste water by (c1) mixing the waste water with activated sludge; (c2) aerating the waste water mixed with sludge for effecting aerobic treatment in dependence upon aerobic bacteria groups included in the activated sludge; (c3) stopping the aeration and settling the sludge under aerobic conditions; (c4) mixing the treated water with organic substances including a hydrogen donor; and (c5) aerating again the mixed treated water again for elimination of the further organic substances in dependence upon aerobic bacteria groups; (d) settling the sludge for the separation of supernatant liquid to be flowed out from above the sediment of the sludge; and (e) separately culturing anaerobic bacteria and methane bacteria and using them in steps a) and b) respective­ ly. 2. The method of treating waste water as set forth in claim 1, wherein art of the aerobically treated water is returned and anaerobically treated again as circulating treated waste water. 3. The method of treating waste water as set forth in claim 1 or claim 2, wherein facultative anaerobic bacteria are cultured under anaerobic conditions on the basis of the sediment of sludge, raw waste water and a culture liquid in a first seed bacteria culture tank, and the cultured sludge bacteria are used for anaerobically treating the waste water in step a). 4. The method of treating waste water as set forth in any one of the preceding claims, wherein methane bacteria are cultured on the basis of raw waste water and a culture liquid in a second seed bacteria culture tank, and the cultured methane bacteria are intermittently supplied to the biological contact zone for the generation of methane gas. 5. The method of treating waste water as set forth in any one of the preceding claims, which further comprises the step of bringing the separated supernatant liquid into contact with ozone gas for decolorization of the treated water. 6. The method of treating waste water as set forth in claim 5, wherein part of the ozone-treated water is returned and anaerobically treated again as circulating treated water. 7. The method of treating waste water as set forth in any one of the preceding claims, wherein the hydrogen donor mixed with anaerobically treated waste water is a raw waste water. 8. An apparatus for treating waste water, comprising: (a) a source (1) of waste water including organic substances containing nitrogen; (b) an anaerobic tank (2) having a flow path connected to the waste water source (1) for receiving a supply of the waste water from the waste water source, the flow path having an outlet (29); (c) means (9, P₂) for supplying anaerobic bacteria into the flow path at a first position (21) for anaerobically treating the waste water; (d) at least one biological contact zone (3a) provided in the flow path at a second position downstream of the first position; (e) a bacteria culture tank (4) for culturing methane bacteria; (f) means (P₃) for supplying the cultured methane bacteria from the bacteria culture tank (4) to the biological contact zone (3a) to further anaerobically treat the waste water passing through the biological contact zone; (g) an aerobic tank (6) following the outlet (29) of the flow path of the anaerobic tank (2) for receiving a supply of the waste water from the anaerobic tank, the aerobic tank containing activative sludge including aerobic bacteria for aerobically treating the waste water discharged from the anaerobic tank; (h) means (7) for discharging the treated waste water from the aerobic tank (6). 9. The apparatus as claimed in claim 8, wherein the bacteria culture tank (4) contains a culture liquid peculiar to the methane bacteria, the bacteria culture tank having a connection to a supply of the waste water from the waste water source (1). 10. The apparatus as claimed in claim 9, wherein the cultured methane bacteria supplying means (9, P₂) includes means (P₃) for supplying the cultured methane bacteria intermittently to the biological contact zone (3a). 11. The apparatus as claimed in any one of the preceding claims 8 to 10 which includes a bacteria culture tank (9) for culturing the anaerobic bacteria to be supplied into the flow path at the first position. 12. The apparatus as claimed in any one of the preceding claims 8 to 11 which includes means for recirculating the treated waste water from the aerobic tank into the anaerobic tank. 13. The apparatus as claimed in any one of the preceding claims 8 to 12 which includes means (64) provided in the aerobic tank for agitating the waste water with the activative sludge at predetermined time intervals and means (62, 63) for introducing air into the aerobic tank at predetermined time intervals. 14. The apparatus as claimed in any one of the preceding claims 8 to 13 which includes means for introducing waste water from the waste water source (1) into the aerobic tank (6). 15. The apparatus as claimed in any one of the preceding claims 8 to 14, wherein the treated waste water dis­ charging means includes a floating body (71) floating on the waste water in the aerobic tank (6), a flexible pipe (73) secured on the floating body (71) to have an inlet positioned below the level of the waste water in the aerobic tank (6), and a filter (72) provided on the flexible pioe for preventing contaminants from reaching the flexible pipe. 16. The apparatus as claimed in claim 15, which includes an ozonizing tank (8) connected through the treated waste water discharging means (7) to the aerobic tank, means (81a; 82b) for supplying the treated waste water through the treated waste water discharging means (7) into the ozonizing tank (8), and means (83, P₅) for introducing ozone gas into the ozonizing tank (8) to ozonize the treated waste water. 17. The apparatus as claimed in either one of the receding claims 15 or 16, which includes means (P₆) for returning a part of the waste water from the ozonizing tank into the anaerobic tank (2). 18. The apparatus as claimed in any one of the preceding claims 15 to 17, wherein the ozone gas introducing means includes a source of ozone gas (83) for supplying ozone gas under a pressure, a circulation conduit (82) having an inlet opening into the ozonizing tank and an outlet opening into the ozonizing tank, and an ejector pump (P₅) provided in the circulation conduit, the ejector pump having an inlet connected to the ozone gas source (83) for injecting the ozone gas unter a high pressure to circulate the waste water through the circulation conduit (82). 19. The apparatus as claimed in claim 18, wherein the treated waste water discharging means (7) is connected to the circulation conduit (82) at a position upstream of the ejector pump (P₅). 20. The apparatus for treating waste water as set forth in claim 8, wherein said aerobic tank (6) comprises: (a) a tank for receiving a raw waste water serving as hydrogen donor and a waste water anaerobically treated by said anaerobic tank (2); (b) aerating means (62, 63) for diffusing air into said tank; (c) agitating means (M₁, 64) for agitating liquid in said tank (6); (d) pump means (P₁) for extracting sludge settled in said tank; and (e) a supernatant liquid outflow mechanism (7). 21. The apparatus for treating waste water as set forth in claim 21, wherein said supernatent liquid outflow mechanism comprises: (a) a floating body (71) floated on the liquid surface of said tank; (b) a flexible pipe (73) having one end provided with a suction port and attached to said floating body (71); (c) a filter (72) provided at said suction port to remove solid substances; and (d) an outflow pump (P₄) and an outflow valve (75) each connected to the other end of said flexible pipe (73). 22. The apparatus for treating waste water as set forth in claim 8, which further comprises an ozone treatment tank (81) for treating the waste water flowed out of said aerobic tank (6) by ozone to decolor the treated waste water. 23. The apparatus for treating waste water as set forth in claim 22, wherein said ozone treatment tank (8) comprises: (a) a treatment tank (81) from a bottom portion of which waste water to be ozone-treated is supplied; (b) ozone gas supply means (83, P₅) for blowing ozone gas to or near a bottom of said treatment tank (81); (c) an outflow communication path (85) so formed as to communicate with the atmosphere on a top portion (86) of said treatment tank (81) in order to flow out waste water which has been ozone-treated in said treatment tank; (d) a top wall (86) provided at a top of said treatment tank so as to form an air-tightly closed space (87) in relation to a liquid surface of said treatment tank; (e) an exhaust path (86a) provided at said to wall to exhaust ozone gas in said treatment tank; and (f) an exhausted ozone gas treating section (89) provided at said exhaust path (86a). 24. The apparatus for treating waste water as set forth in claim 23, wherein said ozone gas supply means comprises: (a) a circulation waste water path (82) for treated waste water, whose outlet is open to or near the bottom of said treatment tank (81) and whose inlet is open into said treatment tank (81) at a position higher than that of the outlet; (b) an ejector pump (P₅) provided at this circulation water path (82); and (c) ozone gas producing means (83) for jetting ozone gas into said ejector pump (P₅). 25. The apparatus for treating waste water as set forth in claim 24, wherein waste water to be ozone-treated is supplied to said ejector pump (P₅) so as to be mixed with jetted ozone gas in said ejector pump (P₅).

Inventors: FUJIU, MASAO, IWAHORI, KEISUKI
Applicants: KABUSHIKI KAISHA MEIDENSHA
Application year: 1986
Main classification: C02F3
IPC codes: C02F1, C02F3