THERMAL INSULATING MATERIAL

Abstract: A thermal insulating material comprising layers of thin walled hollow glass or plastic tubes (18) stacked together so that their longitudinal axes are perpendicular to the direction of heat flow. The tubes are preferably elliptical in cross-section with the larger axes of the ellipse also being aligned in a plane perpendicular to the direction of heat flow. The tubes may be sealed at each end or open; if sealed they may contain air or a low conductivity gas at atmospheric pressure or less than atmospheric pressure. In preferred embodiments the internal surface of the tubes are coated with a reflective material.

Description: THERMAL INSULATING MATERIAL Background of the Invention The present invention relates to thermal insulating material for use in construction of homes, factories and office buildings. More particularly, the present inventi relates to a thermal barrier comprising layers of thin walled hollow tubes stacked together so that their longitudinal axes are aligned in a plane perpendicular to the direction of heat flαω. Efficient utilization of thermal insulation continue to be one of the best methods of conserving energy and controlling heating and cooling costs. At the same time, the health and safety concerns associated with convention insulating materials, such as mineral fibers and plastic -foams, has raised serious questions about their long term applicability. E.g., recent discoveries point to the possibility that fiberglass of certain particle sizes may be carcinogenic in the same or similar manner as asbestos. In addition, the performance of mineral fibers is relative ly limited, with typical R-values being about 2.5 per inch The use of plastic foams, such as polyurethane , urea- formaldehyde and polystyrene, has also been criticized because of their dimensional instability and tendency to evolve their blowing gases and/or unreacted constituents, which significantly lowers their performance. Moreover, they are flammable and many generate poisonous or noxous gases as they burn. Efforts are underway tD improve this situation by developing new kinds of materials. One of these newly developed insulation materials utilizes packed glass microspheres coated with a reflective material and having a vacuum in the iπtersticial area between micro- spheres. The outer reflective coating is intended to minimize heat transfer by radiation; the vacuum in the intersticial area reduces heat transfer by gas conduction. SUBSTITUTE SHEET Although insulation materials made from these types of microspheres possess distinct advantages over commercially available materials, they also have several inherent disadvantages. For example, it has been found difficult, if not impossible, in many applications to maintain the vacuum in the iπtersticial area. This dramatically increases energy losses induced by gas conduction. It has also been found to be very difficult to deposit a relatively thin film of reflective material on the outer surface of the microspheres. Even where this has been accomplished, the coating wears at the area of point to point contact between microspheres. The point to point contact, in and of itself, increases heat transfer by solid conduction and the wearing of the reflective material necessarily increases heat transfer by radiation. More¬ over, the known methods of producing hollow glass micro- spheres, e.g., U.S. Patent Nos. 2,797,201 and 3,365,315, etc. have not been successful in producing products of relatively uniform size or uniform thin walls. This makes it difficult to produce insulation materials of controlled and predictable characteristics and quality. Another packed glass microsphere insulating material is taught in U.S. Patent No. 4,303,061. In that invention, thin walled hollow microspheres contain a vacuum and a reflective coating on the interior surface. The micro- sphere is formed from molten glass and the vacuum and reflective coating are put in place at the time the micro- sphere is made. According to the patent, all of these operations are conducted at the melting temperature of glass, about 2,000°F, an extremely high and difficult environment in which to carry out such procedures. To further compound this difficulty, glass evolves water at these temperatures. The water, in turn, can be reduced by the metals comprising the reflective coating to form hydrogen. Since hydrogen is an excellent conductor of heat this result can have a deleterious effect on the insulation property of the microspheres. Equally as important, at these temperatures it is extremely difficult to evenly deposit a reflective coating of the desired thickness on the interior surface of the microsphere. A need thus exists in the art for a thermal barrier which is not subject to the deficiencies of either the present commercially available materials or the packed glass microsphere technology, which can be readily manu¬ factured with predictable characteristics and quality, and which can be mass produced at prices attractive to the construction industry. Summary of the Present Invention The present invention solves each of the foregoing problems by providing an insulation material comprising at least two layers of hollow, thin walled tubes positione such that their longitudinal axes are aligned in a plane perpendicular to the direction of heat flow. The array of tubes may be constructed of glass or plastic and are preferably joined together into a unitary structure. In a first alternative of the present invention, each of the tubes has an eliptical or flattened cross- section, with the larger cross-sectional dimension, referred to hereinafter for simplicity as the width, being aligned in a plane perpendicular to the direction of heat flow. The effect on R-value (the measure of the ability of the system to retain absorbed energy) is directly related to the degree that the tubes are flattened. Improvements have been noted in width to height (i.e., greater to lesser dimension) ratios for the tubes in excess of 1 and as high as width to height ratios of 6 or more . In another embodiment, the ends of the tubes are sealed and the interiors at least partially evacuated. T -k- This reduces convection caused heat transfer within the insulation material, i.e., fluid flow in the interior spaces of the tubes. In an alternative to this embodi¬ ment the ends of the tubes are also sealed and a low conductivity gas is introduced into the interiors. The low conductivity gas may be at atmospheric or reduced pressure. This also controls heat transfer by convection Examples of suitable low conductivity gases include xenon krypton, iodine, bromine, chlorine, hydrogen bromide, carbon disulfide, and halocarboπs, including freon types R.., Ri ? i R ?1 i and r, ? . All of these materials have thermal conductivities significantly lower than air. They are selected on the basis of their performance, cost and toxicity. Particularly preferred are xenon, krypton, iodine and the halocarboπs. In still another embodiment, the interior surface of the tubes are coated with a thin layer of reflective material such as aluminum, zinc, nickel, silver, gold, chromium, or copper. The coating reflects energy in the infrared spectrum and thus controls radiation generated heat transfer through the insulation. Drawing These and other features, aspects and advantages of the present invention will become more apparent upon consideration of the following description, appended claims and accompanying drawings wherein: Figure 1 is a horizontal cross-section of the part of a wall unit containing the thermal insulating material according to the present invention; and, Figure 2 is a vertical cross-section of a part of the wall unit taken along the line 2-2 of Figure 1. SUBSTITUTE SHEET Detailed Description of the Invention Referring now to Figures 1 and 2, the present invention 10 is shown in its environment of use, between the inner wall 12, outer wall 1 and stud 16 of a struc¬ ture. The present invention is a heat barrier comprising layers of thin walled tubes 1θ joined together and aligned in a plane perpendicular to the direction of heat flow, which is from one wall to the other of the structure. The individual tubes are constructed of either glass or plastic having a diameter of from about 1/8-inch to about 1-inch, preferably 1/ -inch to 3/ -iπch and a length of from about 1-inch to 6-iπches or more. Shorter, as opposed to longer, tubes are preferred to minimize the deleterious effect of a tube being punctured by a nail or otherwise damaged during use. I.e. , the insulating effect of an entire closed-ended tube can be lost if the tube is punctured. Similarly the insulating effect of an open- ended tube can be lost if the puncture shatters the tube. Thus, a nail damaging a ' shorter tube has less of a negativ effect on the overall integrity of the system than a nail puncturing a longer tube. The length to diameter ratio for the tube should be at least 1.5, preferably from about 2 to about 10 and most preferably from about 2 to about 8. The wall thickness for the tubes 18 should also be as thin as practicable to minimize heat transfer by conduc¬ tion. Preferred thicknesses are from about 0.005 inches to about 0.02 inches, with the practical limiting factors being structural integrity and the ability of the tubes to withstand the rigors of being formed into multilayered units and installation in a structure. Heat transfer by conduction and convection are also effected by the ratio of the diameter to the wall thickness of the tubes. It is preferred that this ratio be at least 50 and most pre¬ ferred that it be from about 50 to about 150. Glasses and plastics best suited for the present in¬ vention have a thermal conductivity expressed in 2 (BTU x inches) divided by (hour x feet x degrees F.) of 5 or less. They must also be able to maintain their structural integrity and be otherwise unaffected by temperatures of up to about 300°F. Suitable glasses include soda lime silica glasses and borosilicate glasses. Suitable plastics include polystyrene, chlorinated polyviπylchlαride, polypropylene, polybutyleπe terephtha- late, ABS, polysulfoπe, fluoriπated plastics such as teflon, polycarbonates and nylon. In a preferred embodiment the tubes are flattened, i.e., eliptical in cross-section, with the larger cross- section dimension referred to herein as the width, being aligned in a plane perpendicular to the direction of heat flow through the structure. As used herein, references to diameters and dimensions for diameters for eliptical cross sectioned tubes means the direction perpendicular to heat flow, i.e., the width of such tubes. An increase in R-value (the measure of the ability of the system to retai absorbed energy) is noted with even minor increases in the ratio of the tube width to height or flattening ratio. Preferred flattening ratios are from about greater than 1 to about 6 and most preferred are from about greater than 1 to about . In another preferred embodiment the ends of the tubes are sealed and either partially or fully evacuated. This reduces heat transfer through the tube and thus through the insulation material by convection. A similar result is obtained when the tube is filled with a low conduc¬ tivity gas such as xenon, krypton, iodine, bromine, chlor¬ ine, hydrogen bromide, carbon disulfide, or a halocarbon. Combinations of gases may also be used and the pressure in the tubes can be at atmospheric or below. All of these materials have thermal conductivities significantly lower than air. Selection αf the particular gas or combination of gases to be used will be determined on the basis of SUBSTITUTE SHEET performaπce, cost and toxicity. The most preferred low conductivity gases are xenon, krypton, iodine and the halocarboπs . In a still further embodiment, the interior surfaces of the tubes 18 are coated with a thin layer of a material which will reflect infrared energy. Examples of suitable materials include aluminum, zinc, nickel, silver, gold, chromium or copper. By thin layer is meant angstrom range to prevent the reflective material from measurably adding to heat transfer by conduction. The reflective coating reduces heat transfer in the tubes and thus in the insulating material by radiation. The reflective coating can be applied to the tubes by the well known techniques of dipping, sputtering or vacuum metaliziπg. The tubes 18 are joined together, end-to-end, into rows and several rows are placed side-by-side to form a layer of tubes. The rows may be staggered so that the end of one tube does not reside in the same plane as the end of the tube in the adjacent row. Each layer may extend from about 4 feet to 6 or more feet in each direction. Layers of tubes are then stacked, one on top of the other to form the novel insulation material of the present invention. From about 2 to about 10 or more layers may be used, but typically from about 2 to about 5 layers will achieve a commercially desirable insulation effect. The tubes in each row and each layer and the individual layers may be sintered or glued together to then form unitary structure. The layers of tubes may be stacked in a rectangular configuration with the center lines of the tubes in each layer being aligned with the center lines of the tubes in the layers immediately above and below. Alternatively, the tubes may be stacked in a hexagonal configuration with the tubes in one layer being off-set from the tubes in the layers immediately above and below. Any other suitable configuration may also be used. SUBSTITUTE SHEET The following table shows the effect of the various embodiments of the present invention on thermal insulation performance as expressed in R-value. For purposes of comparison, fiberglass has an R-value of about 2.5 per inch. SUBSTITUTE SHEET SUMMARY - INSULATION EFFECTIVENESS OF CAPSULES Initial Lϋall Diameter Le ?* π M CD CD Flattening (2) Thickness (d) τ (L) d / a /D Ratio Conduc¬ R/Iπch Iπches(a) Inches Inches v , tivity 0.008 45 2 0 5 3 0.008 90 2 0 5 6 0.008 180 2 0 5 12 0.008 1.50 3.00 180 2 0 5 12 0.008 0.75 1.50 90 2 0 5 6 0.005 0.90 1.80 180 2 0 5 12 0.005 0.50 00 90 2 0 5 6 0.005 0.50 00 100 8 0 5 10 0.005 0.50 00 200 8 2 5 20 I 0.005 0.50 00 400 8 4 5 40 I 0.008 0.5D 00 125 4 2 5 10 0.005 0.50 00 200 4 2 5 16 C D ,008 0.50 4.00 125 4 2 4 12 !.5 0 005 0.50 4.00 200 4 2 4 2C ).0 0.008 0.50 8.00 125 8 2 4 12i.9 0.005 0.50 8.00 200 8 2 4 22.2 0.008 0.50 8.00 125 8 2 5 11 .1 0.005 0.50 8.00 200 8 2 5 17.8 0.015(5) 0.50 1.00 30 2 0 1.74 5. .70 0.015(6) 0.50 1.00 30 2 0 0.73 13. .70 0.005 0.50 1.00 90 2 0 5 1. .40(3) 0.005 0.50 1.00 90 2 0 5 1. .15(4) SUMMARY - INSULATION EFFECTIUENESS OF CAPSULES (1) A = wall thickness, X = tube width, Y = tube height (2) All tubes are made of glass, have a reflecting and Xenon in the interior, unless otherwise noted (3) Nat coated (< Contains air in the interior Tubes made from Teflon % (5) (6) Tubes made from polystyrene 3 α I ω m m -4 As this invention may be embodied in several forms without departing from the spirit or essential character thereof, the present embodiments are illustrative and not restrictive. The scope of the invention is defined by the appended claims rather than by the description preceding them, and all embodiments which fall within the meaning and range of equivalency of the claims are, therefore, intended to be embraced by those claims. SUBSTITUTE SHEET

Claims: I cla im : 1. A thermal insulating material comprising at least two layers of thin walled hollow tubes, each layer having at least two rows of such tubes, each such tube having a diameter of from about 1/8-iπch to about 1-inch and a length to diameter ratio of at least about 1.5 to about 10. 2. A thermal insulating material as defined in Claim 1 wherein the tubes have a diameter to wall thick¬ ness ratio of at least about 50 to about 150. 3. A thermal insulating material as defined in Claim 1 wherein the tubes have an eliptical cross- section and a flattening ratio of greater than 1 to about 6. 4. A thermal insulating material as defined in Claim 1 wherein the tubes are sealed at each end and at least partially evacuated. 5. A thermal insulating material as defined in Claim 1 wherein the tubes are sealed at each end and the interiors contain a low conductivity gas. 6. A thermal insulating material as defined in Claim 5 wherein the pressure in the tubes is less than atmospheric. 7. A thermal insulating material as defined in Claim 5 wherein the low conductivity gas is selected from the group consisting of xenon, krypton, iodine, bromine, chlorine, hydrogen bromide, carbon disulfide and halocarbons. 8. A thermal insulating material as defined in Claim 1 wherein the internal surface of the tubes are coated with a reflective material. 9. A thermal insulating material as defined in Claim 8 wherein the reflective coating is selected from the group consisting of aluminum, zinc, nickel, silver, gold, chromium, and copper. TITUTE SHEET 10. A thermal insulating material as defined in Claim 1 wherein each tube has a length of from about 1-iπch to about 6-inches. 11. A thermal insulating material as defined in Claim 1 wherein the tubes have a wall thickness of from about 0.005 inches to about 0.02 inches. 12. A thermal insulating material as defined in Claim 1 wherein there are from 2 to about 10 layers of tubes . 13. A thermal insulating material as defined in Claim 12 wherein the tubes have a diameter to wall thickness ratio of at least about 50 to about 150, an eliptical cross-section, and contain a gas selected from the group consisting of xenon, iodine, krypton and halocarboπs . 14. A thermal insulating material as defined in Claim 12 wherein at least one surface of the tubes are coated with a material which will reflect infrared energy and the tubes have a wall thickness of from about 0.005 inches to about 0.02 inches. 15. A thermal insulating material as defined in Claim 1 wherein the tubes are constructed of material selected from the group consisting of glasses and plastics having a thermal conductivity of less than about 5. 16. A heat barrier for use in structures comprising from about 2 to about 10 layers of thin walled tubes, each layer having at least 2 rows of such tubes, each such tube having a wall thickness of from about 0.005 inches to about 0.02 inches, a length of from about 1-inch to about 6-iπches, an eliptical cross-section wherein the width dimension is from about 1/8-iπch to about 1-inch, a length to width ratio of from about 1.5 to about 10 and a width to wall thickness ratio of from about 50 to about 150. 17. A heat barrier as defined in Claim 16 wherein the tubes are sealed at each end and contain a low cαπductivity gas. 18. A heat barrier as defined in Claim 17 wherein the internal pressure of the tubes is less than atmospheric. 19. A heat barrier as defined in Claim 16 ' herein the tubes are sealed at each end and the internal pressure of the tubes is less than atmospheric. 20. A heat barrier as defined in Claim 16 wherein the internal surface of the tubes are coated with a reflective material. 21. A thermal insulating material comprising at least 2 layers of thin walled tubes, each such layer having at least 2 rows of such tubes, each such tube having its internal surface coated with a material which reflects infrared energy. 22. A thermal insulating material as defined in Claim 21 wherein the tubes are at least partially evacuated. 23. A thermal insulating material as defined in Claim 21 wherein the tubes contain a low conductivity gas. 24. A thermal insulating material as defined in Claim 23 wherein the low conductivity gas is selected from the group consisting of xenon, krypton, iodine, bromine, chlorine, hydrogen bromide, carbon disulfide and halαcarboπs. 25. A thermal insulating material as defined in Claim 21 wherein the coating is selected from the group consisting of aluminum, zinc, nickel, gold, silver, chromium and copper. 26. A thermal insulating material as defined in Claim 21 wherein the length to diameter ratio of the tubes is from about 1.5 to about 10 and the diameter to wall thickness ratio is from about 50 to about 150.

Inventors: SIMKO FRANK A JR, SIMKO, FRANK, A., JR.
Applicants: SIMKO FRANK A JR, SIMKO, FRANK, A., JR.
Application year: 1986
Main classification: B32B3
IPC codes: B32B3, E04B1