FUEL CELL

Abstract: A unit cell is formed by a plurality of sub-unit cells as a result of dividing each of the electrodes (2A, 2K) and electrolytic plate (1) into a plurality of parts. That is, the electrodes and the eletrolytic plate are each divided into two parts by electrolytic plate support portions (5A, 5K; 6A, 6K) projected from the surfaces of separators (3A, 3K). The support portions are pressed in contact with the end portions of the electrolytic plate so as to support the electrolytic plate and seal the reaction gas, preventing it from leaking. The electrolyte support portions of the separators can be pro­ vided with electrolyte supply paths (7; 50), through which the electrolyte is supplied and impregnated into the electrolytic plate. The electrolyte can be supplied via the apertures (8) provided in the separators, to the electrolyte supply paths.

Description: This invention relates to a fuel cell of the kind referred to in the pre-characterizing portion of patent claim 1. Such a fuel cell is known from Patent Abstracts of Japan, Vol. 7, No. 284 (E-217) (1429), 17. 12. 83. Generally, a plurality of unit cells are laid upon one another to form a fuel cell. A single unit cell is produced by holding an electrolytic plate (matrix) in which an electrolyte is impregnated, between a pair of electrodes (anode and cathode) and further holding them between a pair of separators. In order to produce a greater electric power by teh fuel cell, it is necessary to increase the effective areas of the electrodes of the unit cell and to stack a great number of unit cells. A fuel cell integrally formed by such electrodes, electrolytic plate and separators is proposed as disclosed, for example, in JP-A-58-216365, JP-A-58-220368, JP-A-59-27467 and JP-A-59-27468. If the electrodes, electrolytic plates and separators are simply increased in size for increasing the capacity of the unit cell, the following problems occur: One of the problems is that it is technically difficult to produce thin electrodes and electrolytic having a large area and smooth surfaces, thus their size being limited. Particularly, when the unit cells are stacked in terms of space effect, it is desired to use thinner electrodes and electrolytic plates. Secondly, electrodes and electrolytic plates having a larger area are weaker against mechanical impacts. That is, since the fuel cell is operated in a relative high-temperature atmospere, it is stressed by the temperature-change cycle with the result that cracks or crevices occured in the electrodes and electrolytic plates. Therefore, the reaction gas and the electrolyte leak via the cracks or crevices, shortening the life of the cell. Particularly, in the case of a Molten Carbonate Fuel Cell, the operating temperature reaches 650°C at which a thin electrolytic plate made of ceramics suffers a great stress detrimental to its strength. Thirdly, it becomes difficult to supply the electrolyte to the large-sized fuel cell. When the fuel cell is operated for a long period of time, the electrolyte is gradually consumed little by little so that the cell performance is reduced. Thus, in order to restore the cell performance to the initial state, it is necessary to supply the electrolyte completely. Also, it is difficult to uniformly impregnate all parts of the electrolytic plate of large size with the electrolyte and it takes a long time to do so. These problems limited the unit cells to a small size. Patent Abstracts of Japan, Vol. 7, No. 284 (E-217) (1429) disclose a fuel cell with a unit cell comprising: A matrix member impregnated with an electrolyte; a pair of electrodes disposed parallel to and in contact with said matrix member with the major faces thereof on either side of it, a pair of separators disposed on either side of and in contact with said matrix member and having said electrodes located in recesses on the sides contacting said matrix member, a pair of gas paths formed between said separators and said electrodes and supplied with a reaction gas, each separator of said pair of separators having matrix support portions provided at both ends in parallel with said gas paths, said support portions being pressed in contact with said matrix member so as to support said member, each of said separators has further at least one additional support portion projected on the inner surface of said separators between said support portions of both said ends to hold said matrix member, said additional support portion dividing said electrode so that said unit cell is formed by a plurality of electrode portions connected in parallel, said matrix member is formed by a plurality of members, each of which has both ends supported by said additional support portions of said separators. FR-A-15 30 364 shows a fuel cell wherein unit cells are additionally supported to make it possible to have larger area unit cells despite the fragility of the materials to be supported. SUMMARY OF THE INVENTION It is an object of this invention to provide a fuel cell including a unit cell capable of being large-sized for high power by solving the above problems. This object is accomplished with a fuel cell as claimed. Dependent claims are directed on features of preferred embodiments. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view of one embodiment of a unit cell of a fuel cell according to this invention. Fig. 2 is a perspective view of the separator of the unit cell in another embodiment according to this invention. Fig. 3 is a perspective view of the structure of the unit cell using the separator of Fig. 2. Fig. 4 is a perspective view of the separator of the unit cell of still another embodiment of this invention. Fig. 5 is a perspective view of the unit cell having the structure shown in Fig. 3, which is provided for the performance test. DESCRIPTION OF THE PREFERRED EMBODIMENTS Fig. 1 is a cross-sectional diagram of one embodiment of a unit cell according to the present invention. The unit cell includes an electrolytic plate 1 at the center, a pair of electrodes (anode and cathode) 2A and 2K on the opposite sides of the plate, a pair of separators 3A and 3K on the outsides of the electrodes and gas flow paths 4A and 4K provided between the electrodes 2A, 2K and the separators 3A, 3K so that reaction gases (fuel and oxidizer) flow in the paths. Although the gas flow paths can have various different cross-sectional shapes, this embodiment employs grooves formed by a plurality of ribs, as gas flow paths. In this embodiment, the reaction gases on the anode and cathode sides flow in the paths in a direction perpendicular to the sheet of the drawing. This type of the unit cell is the so-called parallel flow (or opposite flow) type. This invention is not limited to this type, but can be applied to the cross flow type as described later. At the opposite ends of the separators 3A, 3K are provided support end portions 5A, 5K which are projected to support the electrolytic plates by pressing. These support end portions 5A, 5K thus seal the electrolytic plates so that the electrolyte and reaction gases do not leak to the other electrode or to the exterior. This structure of the unit cell can generate a potential difference between the separators 3A and 3K and thus supply electric energy to the exterior. In order to produce the desired electric power, a number of unit cells shown in Fig. I are stacked. Thus, for saving space , electrodes are provided on both sides of each separator and used as anode and cathode electrodes of upper and lower unit cells as shown in Fig. 1. Also, at the centre of each separator 3A, 3K there is provided another projected electrolytic plate support portion 6A, 6K. The support portions 6A and 6K are attached to the opposite surfaces of the electrolytic plate 1. The electrolytic plate 1 is formed of two separate halves on the left and right sides of this support portion 6A, 6K, and similarly the electrode 2A, 2K is formed of two halves. Therefore, this unit cell is formed of two smaller parallel connected electrode portions. The performance of the unit cell is the same as long as it has equal electrode area even though the electrode is divided. If the unit cell is desired to be large-sized, the area of the separator 3A, 3K is increased, the support portion 6A, 6K is further added and each of the electrode and electrolytic plate is divided into two or more parts. Under these conditions, the strength of the electrode and electrolyte is not reduced. Even when the electrode is divided, and the electrolytic plate is not divided, the unit cell can withstand a mechanical stress because the central portion of the electrolytic plate is supported by the support portion 6A, 6K. In the embodiment of Fig. 1, a gap 7 is further provided between the two halves of the electrolytic plate 1 and used as an electrolyte dispersing path through which electrolyte is supplied to the electrolytic plate 1. The electrolyte flows through this dispersing path 7 in the direction perpendicular to the sheet of the drawing and diffusively permeates the electrolytic plate 1 from the sides of its left and right portions. This dispersing path 7 is communicated with the upper and lower adjacent ones through apertures 8 which are provided in the support portions 6A and 6K of the separators 3A and 3K. Therefore, the electrolyte can be smoothly supplied through the apertures and dispersing paths to the respective electrolytic plate. It is desirable to use an electrically insulating material on the surfaces of the apertures of the separators and of the electrolyte dispersing paths which the electrolyte is made in contact with, and to supply the electrolyte by the capillary force. The electrically insulating material may be powder or fiber of an oxide, carbide or nitride such as alumina, zirconia, titania, silicon carbide, lithium aluminate or silicon nitride. Fig. 2 shows a construction of a separator in another embodiment of a unit cell of this invention. Electrolytic plate support portions 20A and 20K are provided on the opposite sides of a separator 1`0 in the directions perpendicular to each other. In addition, a plurality of gas flow paths 30A, 30K are provided on both sides of each of the support portions 20A, 20K. The gas flow paths 30A and 30K provided on the opposite sides of the separator are perpendicular to each other. Therefore, this separator is called the cross flow type separator. Moreover, projected support end portions 40A and 40K are respectively provided on both edges of each of the opposite sides of the separator 10 in parallel with the gas flow paths on each side. These support end portions are pressed in contact with the end portions of the electrolytic plate, thus sealing it. The central support portions 20A and 20K divide the unit cell into two sub-unit cells. A groove is also provided in the surface of each of the central support portions 20A, 20K and support end portions 40A, 40K. These grooves are called electrolyte distribution grooves. The electrolyte distribution grooves 50 in the opposite surfaces of the separator 10 are communicated with each other through apertures 8 which are bored through the separator 10. Fig. 3 shows the condition in which the separator 10 shown in Fig. 2 is mounted with electrodes and an electrolyte plate. The electrode 2A, 2K is also divided into two parts on both sides of the support portion 20A, 20K in the same way as in Fig. 1, and the electrolyte plate 1 is divided into two parts by the support portion 20A, 20K. The support portions 20A, 20K, support end portions 40A, 40K and electrolytic plate 1 are made in intimate contact with one another so that the reaction gases didn't leak to the outside. Holes 70 are provided in the portions where the electrolytic plate 1 is made in contact with the support end portions 40A, 40K. These holes 70 are connected to the apertures 8 of the separator 10. The electrolyte is supplied through the apertures 8 to the electrolyte dispersion grooves 50 and to the electrolyte dispersion path 7, from which it is diffusely permeated into the electrolytic plate 1. When one of the pile of Fig. 3 is laid on another, one unit cell is formed between the upper and lower separators. Fig. 4 shows the construction of still another embodiment of the separator. This separator 11 has three electrolytic plate support portions on each surface. Thus, each of the electrode and the electrolytic plate is divided into three parts. In Fig. 4, like elements corresponding to those in Fig. 2 are identified by same reference numerals. 21A and 21K represent electrolytic plate support portions. When three electrodes and three electrolytic plates are mounted to each surface of the separator 11, to produce one pile, and when two piles are laid on each other, one unit cell can be formed between the upper and lower separators. This unit is formed of three electrode portions. Thus, according to this embodiment, a large unit cell as compared with that shown in Fig. 3 can be produced without increase of the electrodes and electrolytic plate. If this embodiment is further modified so that the number of the support portions is increased, the unit cell can be further enlarged, enabling the power capacity of the fuel cell to be increased. The actual performance of the unit cell according to this invention will be described with reference to the experimental results for evaluation. Fig. 5 shows a unit cell formed for evaluation test by stacking two piles one of which is shown in Fig. 3, on each other. This unit cell is a cross flow type cell formed of two electrode portions. Since we tried to evaluate one unit cell, no electrode was provided on the outsides of the upper and lower separators 12A and 12K. Therefore, only on one side (inner side) of the separator 12A, 12K are provided the gas flow path 30A, 30K support portion 20A, 20K, and the support end portion 40A, 40B shown in Fig. 2. Apertures 8 are provided only at the centre of the separators and communicated with the electrolytic dispersion path 7. In Fig. 5, like elements corresponding to those in Fig. 3 are identified by the same reference numerals. 80 represents an electrolyte injector, 81 a heater, and 82 an electrolyte. The electrolyte 82 heated to a certain temperature by the heater 81 was supplied by the injector 80 via a pipe 83 and via the hole 70 and aperture 8 to the electrolyte dispersion path 7. The separator 12A, 12K of 600 mm square was made of SUS 316. The anode 2A was formed of two nickel electrodes of 220 x 600 mm and the cathode 2K was formed of two nickel oxide electrodes of 220 x 600 mm. The electrolytic plate 1 was formed of a lithium aluminate base of 280 x 600 mm, 1 mm thick. The electrolyte 82 contained 53 weight % of carbonate (lithium carbonate: potassium carbonate = 62 : 38 mol ratio) and was supplied from the central portion of the cell and impregnated into the electrolytic plate 1. An electrically insulating material, lithium aluminate powders, was filled into the electrolyte supply hole and the electrolyte distribution path. An anode gas of 80% H₂ - 20% CO₂ mixture and a cathode gas of 15% O₂ - 30% CO₂ - 55% N₂ mixture were supplied to the gas flow paths 30A and 30K. The operating temperature was 650°C. The experimental results were that the cell voltage was initially 0.73V at current density of 150 mA/cm², after 100 hours 0.71V at 150 mA/cm² and after 200 hours 0.63V at 150 mA/cm², but after supply of electrolyte of 35 mℓ, increased to 0.72V at 150 mA/cm².

Claims: A fuel cell with a unit cell comprising: a matrix member (1) impregnated with an electrolyte; a pair of electrodes (2A, 2K) disposed parallel to and in contact with said matrix member with the major faces thereof on either side of it, a pair of separators (3A, 3K; 10; 11; 12A, 12K) disposed on either side of and in contact with said matrix member and having said electrodes located in recesses on the sides contacting said matrix member (1), a pair of gas paths (4A, 4K; 30A, 30K) formed between said separators and said electrodes and supplied with a reaction gas, each separator of said pair of separators having matrix support portions (5A, 5K; 40A, 40K) provided at both ends in parallel with said gas paths, said support portions being pressed in contact with said matrix member (1) so as to support said member (1), each of said separators (3A, 3K; 10; 11; 12A, 12K) has further at least one additional support portion (6A, 6K; 20A, 20K; 21A, 21K) projected on the inner surface of said separators between said support portions of both said ends to hold said matrix member, said additional support portion (6A, 6K; 20A, 20K; 21A, 21K) dividing said electrode so that said unit cell is formed by a plurality of electrode portions connected in parallel, said matrix member (1) is formed by a plurality of members, each of which has both ends supported by said additional support portions (6A, 6K; 20A, 20K; 21A, 21K) of said separators (3A, 3K; 10; 11; 12A, 12K) characterized in that said fuel cell is a molten carbonate fuel cell, said separators (3A, 3K; 10; 11; 12A, 12K) and said support portions (5A, 5K; 6A, 6K; 20A, 20K; 21A, 21K; 40A, 40K) are formed in one united body in each separator (3A, 3K; 10; 11; 12A, 12K), at least said additional support portions (6A, 6K; 20A, 20K; 21A, 21K) are provided with apertures (8) bored through said support portions on both surfaces of each said separators (3A, 3K; 10; 11; 12A; 12K) and provided with flow paths (7; 50) in a longitudinal direction of said matrix member (1), which flow paths (7; 50) are connected with said apertures (8), whereby said electrolyte is supplied to said matrix member (1) through said apertures (8) and said flow paths (7; 50). A fuel cell according to claim 1, wherein said additional support portions (6A, 6K; 20A, 20K; 21A, 21K) are provided on both surfaces of each of said separators (3A, 3K; 10; 11; 12A, 12K). A fuel cell according to claim 1, wherein said pair of gas paths (4A, 4K) in which said reaction gas flows are provided in parallel. A fuel cell according to claim 1, wherein said pair of gas paths (4A, 4K; 30A, 30K) in which said reaction gas flows are provided perpendicular to each other.

Inventors: IWASE, YOSHIO, OKABE, SIGERU, OKADA, HIDEO, TAKEUCHI, MASATO, TAMURA, KOHKI
Applicants: HITACHI, LTD.
Application year: 1986
Main classification: H01M8
IPC codes: H01M8