A MULTI-LAYER CIRCUIT BOARD HAVING A LARGE HEAT DISSIPATION

Abstract: A multi-layer circuit board is disclosed which includes a plurality of AℓN ceramic layers piled up and combined as an integrated form and wiring layers interposed between the AℓN ceramic layers. The wiring layers are made of a mixture of tungsten and AℓN ceramic particles, the content of the AℓN ceramic particles being 0.5 to 2.0 wt.%. A plurality of through-holes are formed in the AℓN ceramic layers to interconnect the wiring layers formed at different levels.

Description: BACKGROUND OF THE INVENTION Field of the Invention: The present invention relates to a multi-layer circuit board used for mounting one or more semiconductor chips such as LSI's (Large Scale Integrated Circuits). Description of the Related Art: LSI chips having a high integration density and operable at high speed consume a large power and require a large heat dissipation for their mounting structure. Alumina ceramics has been proposed to be used as boards for mounting such LSI chips in A.J. Blodgett, Jr. "A Multi-layer Ceramic, Multi-chip Module", IEEE Proc. of Electronics Components Conference, 1980, pages 283 - 285 and in B.T. Clark and Y.M. Hill "IBM Multichip Multilayer Ceramic Modules for LSI Chips - Design for Performance and Density", IEEE Transactions on Components, Hybrids, and Manufacturing Technology, Vol. CHMT-3, No. 1, March 1980, PP 89 - 93. In accordance with, however, the recent progress of LSI's, a layer heat dissipation is being required for packaging structures of the LSI's and the thermal conductivity of alumina becomes insufficient for being used in such packaging structures. One of ceramic materials having an improved thermal conductivity is silicon carbide which is disclosed in Japanese patent application un-examined publication No. 57-180006. The silicon carbide has a resistivity of 1 to 10 ohm·cm which is still not enough to be used in the packaging structure. Beryllia ceramics is another material having a large thermal conductivity. It is, however, poisonous and is not suitable to be used in an electronic device. Recently, the use of aluminum nitride (AℓN) ceramics has been proposed by Y. Kurokawa, K. Utsumi and H. Takamizawa in a U.S. patent application serial No. 693,105 filed January 22, 1985 which was assigned to the same assignee as the present application. AℓN ceramics has characteristics generally suitable to be used in an electronic device, such as a large thermal conductivity and a high resistivity. However, Y. Kurokawa et al only suggested in the U.S. patent application to use the AℓN ceramics in a semiconductor device without any concrete example of such device. In applying the AℓN ceramics to a multi-layer circuit board, the inventors of the present invention have faced some difficulties. The multi-layer circuit board interposes wiring layers between laminated layers of AℓN ceramics. Since those layers are sintered at a high temperature, the wiring layers must endure the sintering process and refractory metals such as tungsten should be used therefor. However, refractory metals have a weak adhesion strength to the AℓN ceramics and their coefficients of contraction are different from the AℓN ceramics. Accordingly, the refractory metal wiring layers are apt to separate from the AℓN ceramic layers. Such separation deteriorates the heat dissipation efficiency of the multi-layer circuit board. SUMMARY OF THE INVENTION It is, therefore, a primary object of the present invention to provide a multi-layer circuit board having a high heat dissipation efficiency. It is another object of the present invention to provide a multi-layer circuit board using AℓN ceramics. The multi-layer circuit board according to the present invention includes a plurality of laminated layers of AℓN ceramics, and at least one metal wiring layer interposed between the AℓN ceramic layers, the metal wiring layer being made of refractory metal in which AℓN ceramic particles are uniformly dispersed. The AℓN ceramic layers and the metal wiring layer are adhered to one another by a sintering process. The refractory metal is preferably tungsten. The wiring layer involves AℓN ceramic particles in 0.5 to 2.0 wt.%. According to the present invention, the material of the metal wiring layer is a mixture of refractory metal and 0.5 to 2.0 weight percent AℓN ceramic particles. The AℓN ceramic particles in the metal wiring layer react with the AℓN ceramic layers in the sintering process to improve the adhesion strength between the metal wiring layer and the AℓN ceramic layers. The coefficient of contraction of the metal wiring layer is controlled by the content of AℓN ceramic particles and may have a value similar to that of the AℓN ceramic layer. As a result, the adhesion between the AℓN ceramic layers and the metal wiring layer is greatly improved and separation therebetween is suppressed and as a result, the heat dissipation efficiency is improved. The multi-layer circuit board of the present invention is suitable to mount LSI devices thereon. BRIEF DESCRIPTION OF THE DRAWINGS The above and further objects, features and advantages of the present invention will become more apparent from the following detailed description taken in conjunction with the accompanying drawings, wherein: Fig.1 is a perspective view of a preferred embodiment of the present invention; Fig.2 is a graph showing a relationship between an adhesion strength and a content of AℓN ceramic particles in a wiring layer; and Fig.3 is a graph showing a relationship between a ratio of the contraction coefficient of the wiring layer to that of the AℓN ceramic layer and a content of the AℓN ceramic particles in the wiring layer. DESCRIPTION OF THE PREFERRED EMBODIMENT The preferred embodiment shown in Fig. 1 comprises ten laminated AℓN ceramic layers 1 and seven wiring layers 2 interposed between the AℓN ceramic layers 1. The wiring layers 2 include signal lines and power lines. Through-holes 3 are formed in the AℓN ceramic layers 1 and filled with a metallic material to interconnect the wiring layers 2 in different levels. The metallic material is the same as that of the wiring layers 2 and made of a mixture of tungsten in 99.5 to 98 wt.% and AℓN ceramic particles in 0.5 to 2.0 wt.%. On the surface of the upper-most AℓN ceramic layer, die pads '4 and bonding pads 5 are formed. LSI chips (not shown) are to be attached to the die pads 4 and electrodes on the LSI chips are to be connected to the bonding pads 5 by bonding wires (not shown). The thus connected LSI chips and the wiring layers 2 constitute an electronic circuit. For signal input and output, input/output pads 6 are formed on the surface of the lowest AℓN ceramic layer. The manufacturing process of the preferred embodiment shown in Fig.1 will be explained. Green sheets of AℓN ceramics are formed from a mixture of AℓN powder and CaC₂ powder. The CaC₂ powder is used to decrease the quantity of oxygen atoms in the sintered ceramics and thereby to increase thermal conductivity thereof. The AℓN powder, CaC₂ powder and organic solvent are mixed for 48 hours. An example of the organic solvent is polycaprolactam or polyacrylate, which is easily decomposed under a neutral atmosphere. The degree of viscosity of the mixture is controlled to a value of 3 to 7 Pas (3,000 to 7,000 cp). The mixture is applied to a casting machine to form green sheets each having a thickness of 10 to 200 µm. Thereafter, through-holes are opened in the green sheets by a punching method or by using a laser beam. The green sheets having the through-holes are subjected to a screen printing to selectively apply a paste including a mixture of tungsten powder and AℓN powder thereon to form wiring layers 2, die pads 4, bonding pads 5 and input/output pads 6 and to fill the through-holes 3. The AℓN powder is uniformly distributed in the paste. Ten green sheets subjected to the screen printing are laminated in a predetermined order, and then subjected to a thermal pressure. The laminated structure is cut into a desired dimension, heated at 400 to 600°C in a non-oxidizing atmosphere for a sufficient time to remove the solvent in the green sheets and the paste, and sintered at 1,400 to 2,000°C in a non-oxidizing atmosphere. After the sintering process, gold is plated on the surfaces of the die pads 4, the bonding pads 5 and the input/output pads 6. Referring to Fig. 2, the addition of AℓN ceramic particles to the wiring layer 2 brings about an increase in adhesion strength between the AℓN ceramic layers and the wiring layers. The improvement in the adhesion strength is sharp for the content of AℓN ceramic particles up to 2 wt.%. It is still remarkable for the content larger than 2 wt.%. In the wiring layer, with the content of AℓN ceramic particles larger than 10 wt.%, the resistivity becomes too high to be used in the circuit board. A ratio of the contraction coefficient of the wiring layer to that of the AℓN ceramic layer is also increased by addition of AℓN ceramic particles, as shown in Fig. 3. If this ratio is substantially different from unity "1", the wiring layers 2 would be separated from the AℓN ceramic layers 1 or the board would be broken to cause an open circuit in the cooling step after the sintering process. The preferable value of the ratio of the contraction coefficients is between "0.8" and "1.2" which is realized by the content of AℓN ceramic particle between 0.5 and 2.0 wt.%. In summary, the content of AℓN ceramic particles uniformly contained in the metal wiring layers 2 should be selected in a range of 0.5 to 2.0 wt.%. With the AℓN ceramic particles contained in the metal wiring layers in 0.5 to 2.0 wt.%, there is obtained a rigidly integrated multi-layer circuit board having no separation between AℓN ceramic layers and wiring layers. The heat dissipation efficiency is improved. The fine wirings in the multi-layer circuit board are safely maintained in the sintering process. The table shown below indicates other characteristics of the ceramic layers and the wiring layers. The resistivity of wiring layers increase by 3 to 11 µΩ.cm, compared to the wiring layers of tungsten alone. This increment, however, is small and does not damage the operation of the electrical circuit. The thermal conductivities of the AℓN ceramic layers are higher than the value of alumina which is about 17 W/mK. Thermal expansion coefficients of the AℓN ceramic layers are smaller than the value of alumina which is about 65 x 10 -7 /°C, and almost the same as 35 to 40 x 10 -7 /°C of silicon. The AℓN ceramic layers are mechanically stronger than alumina ceramic layer having a flexural strength of about 300 N/cm² (30 kg/cm²). Thus, AℓN ceramic layers have many features preferable to be used in a circuit board for mounting a semiconductor chip, and the present invention enables the practical application of the AℓN ceramic layers.

Claims: A multi-layer circuit board comprising a plurality of aluminum ceramic layers and at least one wiring layer formed between said aluminum ceramic layers, said aluminum ceramic layers and said wiring layer being integrated into a single circuit board, characterized in that said aluminum ceramic is aluminum nitride ceramic and said wiring layer is made of a mixture of refractory metal and 0.5 to 2.0 weight percent aluminium nitride ceramic particles.

Inventors: KUROKAWA, YASUHIRO, SHIMADA, YUZO, UTSUMI, KAZUAKI
Applicants: NEC CORPORATION
Application year: 1986
Main classification: H01L23
IPC codes: H05K1, H01L23, H05K3