PHOTO-CURABLE COMPOSITION

Abstract: A photo-curable composition having a high photosensitivity which comprises a photopolymerizable monomer and, as a photopolymerization initiatiation system, an aromatic ketone and an amine, characterized in that at least a portion of said monomer and/or said amine is an amine having an acryloyl or methacryloyl group in the molecule.

Description: The present invention relates to a photo-curable composition. More particularly, it relates to a photo­ curable composition improved in photosensitivity which comprises a photopolymerizable monomer and a photopolymeri­ zation initiation system comprising an aromatic ketone and an amine. In general, photo-curable compositions comprise photopolymerizable monomers and photopolymerization initiators, frequently with polymeric materials. Among various photopolymerization initiators usable in such photo-curable compositions, there is known a photopolymeri­ zation initiation system comprising an aromatic ketone and an amine. This initiation system is frequently used because of such a meritorious property that its polymerization initiation is hardly inhibited by oxygen. However, said initiation system requires the use of an amine in a large amount for sufficient photopolymerization initiation, and as the result, the hardness of the cured resin composition is not adequate so that some roughness is produced at the surface and also the resolving power is lowered. In order to overcome said drawbacks as seen in conventional photo-curable compositions comprising an aromatic ketone and an amine as the photopolymerization initiation system, an extensive study has been made. For example in Japanese patent application 77/129512 photo curable coating compositions are described containing in aromatic ketone (benzyl) and to an amine containing one methacryloyl group. It has now been found that the use of specific amines having two acryloyl or methacryloyl groups in said initiation system can more hardly accept the unfavor­ able influence of oxygen than the use of other amines and rather results in acceleration of the polymerization by oxygen. In any event, the photosensitivity of a photo­ curable composition is highly enhanced by the use of said specific amine in combination with an aromatic ketone so that the curing can be achieved within a shorter period of time. Advantageously, said specific amine has two acryloyl or methacryloyl groups and is itself photopolymerizable. Thus, said specific amine itself participates in photopoly­ merization and does not remain in its monomeric form after light exposure so that the surface characteristics of the cured resin composition is not deteriorated. According to this invention, there is provided a photo-curable composition having a high photosensitivity which comprises a photopolymerisable monomer and as photopolymerisation initiator system, an aromatic ketone and an amine characterized in that at least a portion of said monomer and/or said amine is an amine of the formula: wherein R¹, R² and R³ are each a hydrogen atom, a (C₁-C₃) alkyl group or a group of either one of the following formulas: wherein R and R′ are each a hydrogen atom or a methyl group, m is an integer of 1 to 4 and n is an integer of 2 and 3, but two of R¹, R² and R³ are each a group of either one of the formulas (1) and (2). As the photopolymerizable monomer in the photo­ curable composition of the invention, there may be employed any one chosen from various polymerizable compounds having an ethylenic double bond, of which typical examples are methyl acrylate, ethyl acrylate, n-propyl acrylate, beta­ hydroxyethyl acrylate, beta-hydroxypropyl acrylate, poly­ ethylene glycol monoacrylate, polypropylene glycol mono­ acrylate, polyethylene glycol diacryate, polypropylene glycol diacrylate, methoxypolyethylene glycol monoacrylate, ethoxypolyethylene glycol monoacrylate, glycerol diacrylate, pentaerythritol diacrylate, trimethylolpropane triacrylate, tetramethylolmethane tetraacrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, beta-hydroxyethyl methacrylate, beta-hydroxypropyl methacrylate, polyethylene glycol monomethacrylate, polypropylene glycol monometh­ acrylate, polyethylene glycol dimethacrylate, polypropylene glycol dimethacrylate, methoxypolyethylene glycol mono­ methacrylate, ethoxypolyethylene glycol monomethacrylate, glycecol dimethacrylate, pentaerythritol dimethacrylate, trimethylolpropane trimethacrylate, tetramethylolmethane tetramethacrylate, acrylammide, N-methylolacrylamide, n-­ butoxymethylacrylamide, isobutoxyacrylamide, n-t-butyl acrylamide, methylenebis (acrylamide), ethylenebis­ (acrylamide), propylenebis (acrylamide), methacrylamide, N-methylolmethacrylamide, n-butoxymethylmethacrylamide, isobutoxymethacrylamide, n-t-butylmethacrylamide, methylene­ bis (methacrylammide), ethylenebis (methacrylamide), propylene­ bis (methacrylamide), etc. One or more of these monomers are usable in the photo-curable composition of this invention. The photopolymerization initiation system comprises an aromatic ketone and an amine in combination. Any compound having an aromatic ring and a ketonic group within the molecule is usable as the aromatic ketone, of which examples are benzophenone, acetophenone, fluorenone, thioxanthone and anthraquinone. Further, these compounds may optionally be substituted with any substituent such as a cyano group, a nitro group, a methoxy group or a sulfonic group. One or more chosen from these aromatic ketones may be employed. As the amine, there may be used any conven­ tional amine such as dimethanolamine, diethanolamine, and triethylamine. One or more of these amines are usable. As stated above, it is characteristic in the photo-curable composition of the invention that at least a portion of the photopolymerizable monomer and/or the amine in the photopolymerization initiation system is an amine having a acryloyl or methacryloyl groups. In other words, said polymerizable monomers and/or said conventional amines may be partly or totally replaced by amines containing two acryloyl or methacryloyl groups. When the acryloyl or methacryloyl group-containing amine is used as one of the photopolymerizable monomers, it can simultaneously play a role as an essential component in the photopolymerization initiation system. Likewise, the acryloyl or methacryloyl group-containing amine used as an essential component in the photopolymerization initiation system can simultaneously play a role of the photopolymerizable monomer. The acryloyl or methacryloyl group-containing amine is represented by the formula: wherein R¹, R² and R³ are each a hydrogen atom, a C₁-C₃ alkyl group (e.g. methyl, ethyl, n-propyl, isopropyl) or a group of either one of the following formulas: wherein R and R′ are each a hydrogen atom or a methyl group, m is an integer of 1 to 4 and n is an integer of 2 and 3, but two of R¹, R² and R³ is a group of either one of the formulas (1) and (2). Specific examples are N,N-di (acryloyloxyethyl) ethylamine, di (methacryloyloxyethyl) methylamine, N-,N-di (methacryloyl­ oxyethyl) ethylamine, etc. Among them, particularly preferred are those of the formula (I) wherein two of R¹, R² and R³ are either one of the formulas (1) and (2). These specific amines are per se known or may be prepared by per se known methods. In addition to the above essential components, the photo-curable composition comprises frequently a polymeric material, of which examples are partially saponified poly­ vinyl acetates, cellulose derivatives, polyethylene oxide, sodium polyacrylate, polyamides, etc. The weight proportion of (a) the photopolymeriz­ able monomer, (b) the photopolymerization initiation system comprising the aromatic ketone and the amine and (c) the polymeric material is usually about 100 : 0.001 - 10 and 0­ 300. The molar proportion of (b-1) the aromatic ketone and (b-2) the amine in the photopolymerization initiation system is about 1 : 1 - 30. The above weight proportion as well as the molar proportion are applicable to the case wherein said monomer and/or said amine are partly or totally replaced by said acryloyl or methacryloyl group-containing amine. When the amine in the photopolymerization initiation system is totally replaced by the acryloyl or methacryloyl group-containing amine and any other amine is not used, the weight proportion of (a) the photopolymeriz­ able monomer, (b) the photopolymerization initiation system and (c) the polymeric material is preferred to be about 0­ 500 (particularly 50 - 150) : 100 : 0 - 800 (particularly 20 - 400), and the molar proportion of (b-1) the aromatic ketone and (b-2) the amine in the photopolymerization initiation system is favored to be about 1 : 5 - 500 (parti­ cularly 1 : 15 - 100). The photo-curable composition of the invention may further comprise any conventional additives such as poly­ merization inhibitors (e.g. 2,6-di-t-butyl-p-cresol, hydro­ quinone, p-methoxyphenol) and dyestuffs (e.g. Rose Bengal, Eosine, Methylene Blue, Malachite Green). Preparation of the photo-curable composition can be carried out by admixing the above essential and optional components, if necessary, with water or any appropriate organic solvent. The photo-curable composition thus prepared can be used itself as a photo-curable ink or a photo-curable paint or molded into any optional shape to use as a photo-curable printing plate. Practical and presently preferred embodiments of the invention are illustratively shown in the following Examples and Comparative Examples, wherein part(s) are by weight unless otherwise indicated. Comparative Example 1 A photo-curable composition comprising the following materials was dried to make a photosensitive printing plate of 0.4 mm thick: On the photosensitive printins plate, a Kodak step tablet No. 2 (21 steps) and then a polyethylene tere­ phthalate film were placed in order, and the resulting piled product was placed under reduced pressure to make sure their close contacts, followed by irradiation with a high pressure mercury lamp (ORC Polymer Printer 3000) of 500 mj/cm². The resulting cured plate was developed with water to remove uncured monomer. The resultant cured plate showed curing up to the 16th step. Example 1 In the same manner as in Comparative Example 1 but using N,N-di (methacryloyloxyethyl) methylamine instead of N,N-di­ ethylaminoethyl methacrylate, the operation was effected. The resultant cured plate showed curing up to the 18th step. Reference Example 1 Preparation of N,N-di (methacryloyloxyethyl) methylamine:­ To a 15% tetrahydrofuran solution of diethanol­ methylamine (1 mol), triethylamine (2 mol) as a catalyst was added, and a 10% tetrahydrofuran solution of methacryloyl chloride (2 mol) in 10% tetrahydrofuran solution was dropwise added thereto while stirring. Since the reaction proceeded with heat generation, occasional cooling with ice was effected. After completion of the dropwise addition, the reaction mixture was further stirred for about 30 mintes, and the precipitated salt was eliminated by filtr­ ation. The filtrate was concentrated under reduced pressure, and the residue was purified by silica gel column chromatography using benzene as a developing solvent to give N,N-di (methacryloyloxyethyl) methylamine. The characteristic values in the NMR spectrum are as shown below: 4.20 (doublet) =CH₂ (4H); 5.68 (triplet) -CH₂O (4H); 7.22 (triplet) -NCH₂- (4H); 7.62

Claims: 1. A photo-curable composition having a high photosensitivity which comprises a photopolymerizable monomer and, as a photopolymerization initiatiation system, an aromatic ketone and an amine, characterized in that at least a portion of said monomer and/or said amine is an amine of the formula: wherein R¹, R² and R³ are each hydrogen atom, a (C₁-C₃) alkyl group or a group of either one of the following formulas: wherein R and R′ are each a hydrogen atom or a methyl group, m is an integer of 1 to 4 and n is an integer of 2 and 3, but two of R¹, R² and R³ are each a group of either one of the formulas (1) and (2). 2. The composition according to claim 1, which comprises further a polymeric material. 3. The composition according to claim 1, wherein the amine in the photopolymerization initiation system is totally replaced by the acryloyl or methacryloyl group-­ containing amine. 4. The composition according to claim 1, wherein the weight proportion of the monomer and the photopolymeri­ zation initiation system is 100 : 0.001 - 10. 5. The composition according to claim 4, wherein the molar proportion of the aromatic ketone and the amine in the photopolymerization initiation system is 1 : 1 - 30. 6. The composition according to claim 1, wherein the weight proportion of the monomer and the photopolymeri­ zation initiation system is 0 - 500 : 100. 7. The composition according to claim 6, wherein the molar proportion of the aromatic ketone and the amine in the photopolymerization initiation system is 1 : 5 - 500. 8. The composition according to claim 1 wherein the amine according to formula I is N,N-di (methacryloyloxy (C₁-C₃) alkyl) (C₁-C₃) alkylamine. 9. The composition according to claim 1 wherein the amine according to formula I is N,N-di (methacryloyloxyethyl) methylamine. 10. The composition according to claim 1 wherein the amine according to formula I is N,N-di (methacryloyloxyethyl) ethylamine.

Inventors: KAWABATA, MASAMI, KIMOTO, KOICHI, SHIROTA, YASUHIKO, TAKIMOTO, YASUYUKI
Applicants: NIPPON PAINT CO., LTD.
Application year: 1986
Main classification: C08F2
IPC codes: G03F7, C08F2