POLYMERIC COMPOSITIONS SUITABLE FOR USE AS BITUMEN MODIFIERS AND BITUMINOUS COMPOSITIONS SO MODIFIED

Abstract: 1) Polymeric compositions, suitable for use as bitumen modifiers, comprising, by weight: a) 20-50% of an ethylene/propylene elastomeric copoly­ mer containing from 60 to 75% by weight of ethyl­ ene, and having a value of Mooney viscosity (ML 1+4) at 100°C higher than 5; b) 0-25% of polypropylene prevailingly constituted by isotactic macromolecules having an M.I. value high­ er than 1; c) 0-70% of substantially amorphous polypropylene, possibly in mixture with amorphous copolymers of ethylene with propylene, such component (c) having a total combined ethylene content lower than 60% by weight, and intrinsic viscosity (in tetralin at 135°C) lower than 2 dl/g; d) 0-25% of polyethylene having density comprised between 0.98 and 0.96 g/cm³, and having a value of M.I. higher than 5; e) 0-25% of an ethylene/vinyl acetate (EVA) copolymer containing from 60 to 95% by weight of ethylene, having a value of M.I. higher than 0.1, and with the condition that when component (c) is equal to zero, the component d and the component e are each present in an amount greater than 15% by weight, the sum of components from (a) to (e) being = 100. 2) Bituminous compositions comprising, in mixture, from 10% to 30% by weight, as referred to the total compo­ sition weight, of a polymeric composition as defined above.

Description: Background of the Invention 1. Field of the Invention The present invention relates to polymeric composi­ tions suitable to be used as agents for bitumen modifica­ tion, as well as to the so modified bituminous composi­ tions. 2. Description of the Prior Art The use is known of bituminous compositions, as sheaths, in the water-proofing of civil and industrial buildings. Such compositions are prevailingly constituted by bitumen of the distillate type, and generally contain modifier agents which improve their physical-mechanical characteristics - in particular, their resistance to high-temperature penetration and their low-temperature flexibility. Such agents are generally constituted by amorphous polypropylene (in amount of from 20 to 30% by weight), possibly in combination with amorphous or low-­ crystallinity olefinic copolymers having low molecular weight. The Present Invention The Applicant has found now that it is possible to confer to bitumens improved characteristics of low-tempe­ rature f!exibility and of strength to high-temperature penetration, by using a modifier agent consisting of a polymeric composition comprising, by weight: a) 20-50% of an ethylene/propylene elastomeric copolymer containing from 60 to 75% by weight of ethylene, and having a value of Mooney viscosity (ML 1+4)at 100°C higher than 5 and preferably comprised within the range of from 8 to 40; b) 0-25% of polypropylene prevailingly constituted isotactic macromolecules having M.I. greater than 1 and preferably comprised within the range of from 5 to 15; c) 0-70% of substantially amorphous polypropylene, pos­ sibly in mixture with amorphous copolymers of ethylene with propylene, such component (c) having a total combined ethylene content lower than 60% by weight, and intrinsic viscosity (in tetralin at 135°C) lower than 2 dl/g and preferably comprised within the range of from 0.1 to 1; d) 0-25% of polyethylene having density comprised between 0.98 and 0.96 g/cm³, and having a value of M.I. higher than 5 and preferably comprised within the range of from 10 to 30; e) 0-25% of an ethylene/vinyl acetate (EVA) copolymer containing from 60 to 95% by weight of ethylene, having a value of M.I. higher than 0.1, and preferably comprised within the range of from 0.5 to 200; with the condition that when component (c) is equal to zero, the component d and the component e are each pres­ ent in an amount greater than 15% by weight, the sum of components from (a) to (e) being = 100. The polymeric compositions as defined above can be used as modifiers for bitumen by mixing with this latter. Inert mineral fillers, such as silica, kaolin, micas, calcium carbonate etc., can be present in the mixture of bitumen with such modifiers, in amounts of up to 20% by weight as referred to the total mixture weight. The above said modifier compositions can be used in amounts comprised within the range of from 10 to 30%, but preferably of from 12 to 25% by weight, as referred to the total weight of the mixture with bitumen and possible fillers. An object of the present invention is hence consti­ tuted by the polymeric compositions suitable to be used as additives in bituminous compositions, comprising a mixture of components from (a) to (e) in the above indi­ cated proportions. A further object of the present invention is consti­ tuted by the bituminous compositions comprising from 10% to 30% by weight of the polymeric composition as defined above. The polymeric compositions of the present invention can be prepared in form of granules by mixing their components either in extruder, or in Banbury or roller mixer, at such temperatures as to allow such components to be intimately mixed in the mixture, and subsequent granulation. The bituminous compositions which are the further object of the present invention can be prepared by high-­ temperature mixing bitumen (possibly with the addition of inert mineral fillers such as for example kaolin, CaCO₃, SiO₂, mica) either with 10-30% by weight, with reference to the total weight of the bituminous composition, of the polymeric composition as defined above, or with the indi­ vidual components thereof, separately added in an alto­ gether equivalent amount. The ethylene/propylene copolymers [component (a)] can be prepared according to known methods. Among such copolymers those obtained by using high-yield catalysts, on the basis of titanium compounds, such as, e.g., those disclosed in USP No. 4,013,823 to the Applicant's name, are preferred. The following Examples are given to the purpose of illustrating the invention without however constituting a limitation thereof. (Comparative)Example 1 A bituminous composition is prepared by mixing, in a stainless-steel cylindrical container, at the temperature of 200°C, for 60 minutes and by blade stirrer (500 rpm): The characteristics of the bituminous composition are reported in Table I. Example 2 By operating as in Example 1 a bituminous composi­ tion is prepared, which is constituted by: The characteristics of the bituminous composition are reported in Table I. Example 3 By using a roller mixer a polymeric blend is pre­ pared, which is constituted by the same components as mentioned in Example 2, in the following proportions: The so-obtained blend is extruded and granulated. Eighteen parts by weight of such granulated blend are mixed at 190°C, for 60 minutes and under stirring (500 rpm) with 72 parts by weight of bitumen of the type used in Example 1 and 10 parts by weight of CaCO₃ A bituminous composition, the characteristics of which are reported in Table I, is thus obtained. Comparative Example 4 The bituminous composition is prepared as in Compa­ rative Example 1, with the difference that bitumen of type 80/100 is used. The characteristics of the mixture are reported in Table II. Example 5 In a cylindrical container of 500 cm³ of capacity the following components are blended at 190°C for 60 minutes under stirring (blade mixer, 500 rpm): (a) 17 pbw of amorphous polypropylene having /n/ = 0.3; (b) 3 pbw of isotactic polypropylene of Example 1; (c) 5 pbw of an ethylene/propylene copolymer, containing 34% by weight of propylene, and having Mooney viscosity (ML 1+4) at 100°C = 18 (pbw = parts by weight). Such blend is then added, together with 10 pbw of CaCO₃, to 65 pbw of bitumen of type 80:100 to obtain a bituminous composition, by operating as in Example 1. The characteristics of the so-obtained composition are reported in Table II. Example 6 The test of Example 5 is repeated by using an ethyl­ ene/propylene copolymer, containing 27% by weight of propylene, having Mooney viscosity (ML 1+4) at 100°C = 34, and adding to bitumen each polymeric component and the filler, separately from each other, thus eliminating the preliminary polymeric blend preparation step. The characteristics of the bituminous composition so obtained are reported in Table II.

Claims: 1. Polymeric compositions suitable for use as bitumen modifiers, comprising, by weight: a) 20-50% of an ethylene/propylene elastomeric copoly­ mer containing from 60 to 75% by weight of ethyl­ ene, and having a value of Mooney viscosity (ML 1+4) at 100°C higher than 5; b) 0-25% of polypropylene prevailingly constituted by isotactic macromolecules having M.I. greater than 1; c) 0-70% of substantially amorphous polypropylene, possibly in mixture with amorphous copolymers of ethylene with propylene, such component (c) having a total combined ethylene content lower than 60% by weight, and intrinsic viscosity (in tetralin at 135°C) lower than 2 dl/g; d) 0-25% of polyethylene having density comprised between 0.98 and 0.96 g/cm³, and having a value of M.I. higher than 5; e) 0-25% of an ethylene/vinyl acetate (EVA) copolymer containing from 60 to 95% by weight of ethylene, having a value of M.I higher than 0.1, and with the condition that when component (c) is equal to zero, the component d and the component e are each present in an amount greater than 15% by weight, the sum of components from (a) to (e) being = 100. 2. Compositions according to claim 1 wherein the compo­ nent (a) has Mooney Viscosity ML (1+4) at 100°C com­ prised between 8 and 40. 3. Composition according to claim 1 or 2 wherein the component (b) has M. I. values comprised between 5 and 15. 4. Compositions according to claims from 1 to 3 wherein the component (c) has values of intrinsic viscosity comprised between 0.1 and 1 dl/g. 5. Compositions according to claims from 1 to 4 wherein the component (d) has M.I. values comprised between 10 and 30. 6. Compositions according to claims from 1 to 5 wherein the component (e) has M.I. values comprised between 0.5 and 200. 7. Bituminous compositions comprising from 10 to 30% by weight relatively to the total weight of a polymeric composition according to one of claims from 1 to 5. 8. Bituminous compositions comprising from 50 to 90% by weight of bitumen, from 0 to 20% by weight of an inert mineral filler and from 10 to 30% by weight of one of polymeric compositions according to claims from 1 to 5.

Inventors: CIACCIA, VITTORIO, MILANI, FEDERICO
Applicants: MONTEDISON S.P.A.
Application year: 1986
Main classification: C08L95
IPC codes: C08L95