ELECTROLYTE SOLUTION OF QUATERNARY AMMONIUM SALT FOR ELECTROLYTIC CAPACITOR

Abstract: An electrolyte solution for use in an electrolytic capacitor comprises as a solute at least one quaternary ammonium salt of a carboxylic acid which selected from 5-40 wt % of (a) maleic acid and/or citraconic acid or (b) 7-30 aromatic carboxylic acid or (c) 1-40 wt % of a branched-­ chain aliphatic dicarboxylic acid, in (c) the salt has 11-­ 30 C atoms. The electrolyte solution has high electrical conduc­ tivity when used e.g. with Al foil electrodes. The solvent is aprotic, preferably an amide or lactone.

Description: The present invention relates to an electrolyte solution for an electrolytic capacitor, and more particularly to an electrolyte solution which has high electrical conductivity. The chemical or electrical properties of an electrolyte solution such as electrical conductivity and sparking voltage are the main factors which determine the properties of the electrolytic capacitors. A solution of an amine salt of maleic acid or phthalic acid in an aprotic organic polar solvent such as N,N-dimethylformamide or gamma-butyrolactone is used for low voltage electrolytic capacitors which have good low temperature characteristics. However, as the impedance of electrolytic capacitors has become lower, electrolyte solutions having higher electric conductivity have been desired. A solution of boric acid or ammonium borate in an ethylene glycol solvent has been used as an electrolyte solution for medium to high voltages because it has a high sparking voltage. As is well known, this electrolyte solution contains large amounts of water formed during esterification of ethylene glycol and boric acid, and large amounts of water vapor formed at temperature exceeding 100°C causes distortion in the appearance of the armoring case and reduces the electrical properties of the electrolytic capacitors. For this reason, it is impossible to use this electrolyte solution at a temperature over 100°C. To overcome this disadvantage, it was proposed to use an ammonium salt of a branched-chain aliphatic dicarboxylic acid where the water content is extremely small [Japanese Laid-Open Patent Application No. 45014/81 and Japanese Laid-Open Patent Application No. 27013/82 (corresponding to U.S. Patent 4,469,619)]. However, the above electrolyte solutions using a solvent composed mainly of ethylene glycol have a poor electric conductivity at low temperature. It may be possible to use an aprotic solvent such as N,N-dimethylformamide or gamma-butyrolactone having a broader freezing point-boiling point range than ethylene glycol together with the aforesaid ammonium salt of a branched-chain aliphatic dicarboxylic acid in order to improve the low temperature characteristics, but very little of these ammonium salts solve into such solvents. Japanese Laid-Open Patent Application No. 78522/84 (corresponding to U.S. Patent 4,473,864) discloses an electrolyte solution having high electric conductivity composed of a solution of a quaternary ammonium salt of a dibasic carboxylic acid HOOC(CH₂) n COOH (4 ≦ n ≦ 8) in amide solvents with 2 to 10% by weight of water. This electrolyte solution, however, is not fully satisfactory in electrical conductivity sparking voltage, and temperature range. The present inventors have made extensive investigations in order to find out a novel electrolyte solution having a higher electric conductivity, and have consequently found that quaternary ammonium salts of maleic acid and/or citraconic acid having an unsaturated double bond and high acidity show at least twice as high electrical conductivity as the quaternary ammonium salts of adipic acid, etc.; that quaternary ammonium salts of aromatic carboxylic acids also show higher electrical conductivity than the quaternary ammonium salt of adipic acid; and that for use in a medium to high voltage electrolyte solution, quaternary ammonium salts of branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total show high solubility in aprotic solvents and show relatively high electrical conductivity. According to this invention, there is provided an electrolyte solution for use in an electrolytic capacitor, said solution comprising as a solute at least one quaternary ammonium salt of a carboxylic acid and a solvent, characterised in that the acid in said salt is selected from (a) at least one of maleic acid and citraconic acid, (b) at least one of benzoic acid, hydroxybenzoic acid, resorcylic acid and phthalic acid, and (c) branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total, and in that the solvent is an aprotic solvent. The quaternary ammonium salts of the acids specified as (a) to (c) which are used as solutes in this invention show good solutibility in the solvent and high electrical conductivity, and when used together with solvents having a broad freezing point-boiling point range, constitute excellent electrolyte solutions for use in an electrolytic capacitor which can be used over a wide range of temperatures. Examples of the quaternary ammonium salts of maleic acid and/or citraconic acid, aromatic acids, and branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total used in this invention include aliphatic quaternary ammonium salts such as tetraethylammonium, tetrapropylammonium, tetrabutylammonium, methyltriethylammonium, methyltripropylammonium, methyltributylammonium, dimethyldiethylammonium, dimethyldipropylammonium, dimethyldibutylammonium, ethyltripropylammonium, ethyltributylammonium, diethyldipropylammonium, diethyldibutylammonium, triethylpropylammonium, triethylbutylammonium; alicyclic quaternary ammonium salts such as N,N-dimethylpyrrolidinium, N,N-dimethylpiperidinium, N-methyl-N-ethylpyrrolidinium, N-methyl-N-ethylpiperidinium, N,N-diethylpyrrolidinium, N,N-diethylpiperidinium, N,N-tetramethylenepyrrolidinium, N,N-pentamethylenepiperidinium; and aromatic quaternary ammonium such as N-ethylpyridinium or N,N′-dimethylimidazolium. In the quaternary ammonium salts of branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total used in this invention, specific examples of the branched-chain aliphatic dicarboxylic acids, include 1,5-nonanedicarboxylic acid, 1,6-decanedicarboxylic acid, 5,6-decanedicarboxylic acid, 1,7-decanedicarboxylic acid, 4,6-dimethyl-4-nonene-1,2-dicarboxylic acid, 4,6-dimethyl-1,2-nonanedicarboxylic acid, 1,7-dodecane-dicarboxylic acid, 5-ethyl-1,10-decanedicarboxylic acid, 6-methyl-6-dodecene-1,12-dicarboxylic acid, 6-methyl-1,12-dodecanedicarboxylic acid, 6-ethylene-1,12-dodecane-dicarboxylic acid, 6-ethyl-1,12-dodecanedicarboxylic acid, 7-methyl-7-tetradecene-1,14-dicarboxylic acid, 7-methyl-1,14-tetradecanedicarboxylic acid, 3-hexyl-4-decene-1,2-dicarboxylic acid, 3-hexyl-1,2-decanedicarboxylic acid, 6-ethylene-9-hexadecene-1,16-dicarboxylic acid, 6-ethyl-1,16-hexadecanedicarboxylic acid, 6-phenyl-1,12-dodecanedicarboxylic acid, 7,12-dimethyl-7,11-octadecadiene-1,18-dicarboxylic acid, 7,12-dimethyl-1,18-octadecanedicarboxylic acid and 6,8-diphenyl-1,14-tetradecanedicarboxylic acid. Solvents which are used to dissolve the quaternary ammonium salts of maleic acid and/or citraconic acid, the quaternary ammonium salts of the speified aromatic carboxylic acids and the quaternary ammonium salts of branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total include amides such as N-methylformamide, N-ethylformamide, N,N-dimethylformamide, N,N-diethylformamide, N-methylacetamide, N-ethylacetamide, N,N-dimethylacetamide, N,N-diethylacetamide and N-methylpyrrolidinone, lactones such as beta-butyrolactone, gamma-butyrolactone, gamma-valerolactone and delta-valerolactone, carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate, alcohols such as ethylene glycol, glycerin and methyl cellosolve, sulfolanes such as sulfolane and 3-methylsulfolane, nitriles such as 3-methoxypropionitrile, and phosphates such as trimethyl phosphate. These solvents may be used singly or in combination. Among these, solvents composed mainly of aprotic solvents such as amides and lactones are preferred, and particularly solvents composed mainly of gamma-butyrolactone are preferred for the following reasons. Gamma-butyrolactone has a broad freezing point-boiling point range and is less toxic. Gamma-butyrolactone also does not attack the sealing gaskets compared with amide solvents, and electrolytic capacitor using this solvent is hardly suffered serious damage from halogen ion generated from the washing agent for solder flux which will be transmitted through a closure. The amount of the quaternary ammonium salt dissolved in the solvent is below the saturation concentration, preferably 5 to 40% by weight based on the total weight of the electrolyte solution when the quaternary ammonium salt is the quaternary ammonium salt of maleic acid, and/or citraconic acid or the aromatic carboxylic acid. In the case of the quaternary ammonium salt of a branched-chain aliphatic carboxylic acid having 11 to 30 carbon atoms in total, its concentration in the solvent is 1 to 40% by weight based on the total weight of the electrolyte solution, and the sparking voltage of the resulting solution can be made higher as the concentration is lower. The equivalent ratio of the acid to the base in the salt dissolved in the electrolyte solution is usually from 1/1 to 4/1. The mole ratio of the acid to the base is from 1/1 to 4/1 for monocarboxylic acids, from 0.5/1 to 2/1 for dicarboxylic acids, from 0.33/1 to 1.33/1 for tricarboxylic acids, and from 0.25/1 to 1/1 for tetracarboxylic acids. For example, the quaternary ammonium salt of maleic acid or phthalic acid requires 0.5 to 2 moles of the acid per mole of quaternary ammonium, but the most preferred electric conductivity can be obtained when 1 mole of the acid is used for 1 mole of quaternary ammonium. The quaternary ammonium salt of benzoic acid requires 1 to 4 moles of the acid per mole of quaternary ammonium, but the most preferred electric conductivity is obtained when 1 mole of the acid is used for 1 mole of quaternary ammonium. The quaternary ammonium salt of a carboxylic acid used in this invention can be obtained, for example, by neutralizing the carboxylic acid with an aqueous solution of a quaternary ammonium hydroxide, evaporating water under reduced pressure, recrystallizing the resulting product from methanol or acetone, and drying the product in vacuum. The electrolyte solution of this invention can also be prepared by adding the carboxylic acid and an aqueous solution of quaternary ammonium hydroxide to the solvent, and dehydrating the resulting solution. The electrolyte solution comprises at least one of quaternary ammonium salts of maleic acid and/or citraconic acid, quaternary ammonium salts of specified aromatic carboxylic acid and quaternary ammonium salts of branched-chain aliphatic carboxylic acids having 11 to 30 carbon atoms in total and the solvent. But to prevent electrolytic corrosion, reduce leakage current, and absorb hydrogen gas, various auxiliary solutes such as phosphoric acid derivatives and nitrobenzene derivatives may be added. Furthermore, boric acid derivatives, for example, may be added to increase sparking voltage of medium to high voltage electrolyte solutions. The following Examples and Comparative Examples illustrate the present invention more specifically. In the single drawing, curve A represents the changes of the electric conductivity of the electrolyte solution in Example 28 with temperature, and B shows the changes of the electric conductivity of the electrolyte solution obtained in Comparative Example 10 with temperature. The abbreviations used in tables appearing hereinafter have the following meanings. GBL: Gamma-butyrolactone DMF: N,N-Dimethylformamide MPN: 3-Methoxypropionitrile TMP: Trimethyl phosphate PC: Propylene carbonate EG: Ethylene glycol EXAMPLE 1 Monotetraethylammonium maleate was dissolved in a concentration of 20% by weight in gamma-butyrolactone as a solvent to form an electrolyte solution. The electrolyte solution had an electric conductivity of 13.7 mS/cm at 25°C which was more than twice that of the electrolyte solution containing an amine salt (obtained in Comparative Example 1) or the electrolyte solution containing an adipic acid salt (obtained in Comparative Example 4). When a constant current of 2 mA/cm² was applied to one set of plus and minus smooth aluminum foils in the electrolyte solution, the voltage at which spark was generated was 83 V. EXAMPLES 2 TO 6 Example 1 was repeated except that N,N-dimethylformamide (Example 2), propylene carbonate (Example 3), a mixture of gamma-butyrolactone and ethylene glycol (80:20 by weight percent) (Example 4), 3-methoxypropionitrile (Example 5), or trimethyl phosphate (Example 6) was used respectively instead of the gamma-butyrolactone. The electric conductivity and sparking voltage of the electrolyte solution were measured, and the results are shown in Table 1. EXAMPLES 7 TO 10 Example 1 was repeated except that monotetrapropylammonium maleate (Example 7), monotetrabutylammonium maleate (Example 8), mono-N-methyl-N-ethylpyrrolidinium maleate (Example 9), or ditetraethylammonium maleate (Example 10) was used instead of monotetraethylammonium maleate. The electric conductivity and sparking voltage of the electrolyte solution were measured, and the results are shown in Table 1. EXAMPLE 11 Example 1 was repeated except that monotetraethylammonium citraconate was used instead of monotetraethylammonium maleate. The resulting electrolyte solution had an electric conductivity of 11.8 mS/cm, and a sparking voltage of 86 V. COMPARATIVE EXAMPLES 1 TO 3 Monotriethylammonium maleate was dissolved in a concentration of 20% by weight in gamma-butyrolactone (Comparative Example 1), N,N-dimethylformamide (Comparative Example 2) or propylene carbonate (Comparative Example 3) as a solvent to form an electrolyte solution. The electric conductivity of the electrolyte solution was measured, and the results are shown in Table 2. It is seen that in any of these solvents, the quaternary ammonium salts used in this invention show much higher electric conductivity. Comparative Example Solvent Solute (20% by weight) Electric Conductivity (25°C) (mS/cm) 1 GBL Monotriethylammonium maleate 4.2 2 DMF as in Comparative Example 1 12.8 3 PC as in Comparative Example 1 3.4 EXAMPLE 12 Tetraethylammonium benzoate was dissolved in a concentration of 20% by weight in gamma-butyrolactone as a solvent to form an electrolyte solution. The electrolyte solution had an electric conductivity of 8.4 mS/cm at 25°C, and a sparking voltage of 133 V when a constant current of 2 mA/cm was applied to one set of plus and minus smooth aluminum foils in the electrolyte solution. EXAMPLES 13 TO 15 Example 12 was repeated except that monotetraethylammonium phthalate (Example 13), monotetraethylammonium trimellitate (Example 14), or ditetraethylammonium pyromellitate (Example 15) was used instead of the tetraethylammonium benzoate. The electric conductivity and the sparking voltage of the electrolyte solution were measured, and the results are shown in Table 3. EXAMPLES 16 TO 18 Example 12 was repeated except that N,N-dimethylformamide (Example 16), 3-methoxypropionitrile (Example 17) or trimethyl phosphate (Example 18) was used instead of gamma-butyrolactone. The electric conductivity of the electrolyte solution was measured, and the results are shown in Table 3. COMPARATIVE EXAMPLE 4 Example 1 was repeated except that monotetraethylammonium adipate was used instead of the monotetraethylammonium maleate. The electric conductivity and sparking voltage of the electrolyte solution were measured, and the results are shown in Table 4. COMPARATIVE EXAMPLES 5 TO 8 Monotetraethylammonium adipate was dissolved in a concentration of 20% by weight in N,N-dimethylformamide (Comparative Example 5), 3-methoxypropionitrile (Comparative Example 6), trimethyl phosphate (Comparative Example 7) or propylene carbonate (Comparative Example 8) as a solvent. The electric conductivity and sparking voltage of the electrolyte solution were measured, and the results are shown in Table 4. COMPARATIVE EXAMPLE 9 Example 12 was repeated except that triethylammonium benzoate was used instead of the tetraethylammonium benzoate. The resulting electrolyte solution had a poor electric conductivity of 0.8 mS/cm. EXAMPLES 19 TO 24 Example 12 was repeated except that tetraethylammonium salicylate (Example 19), tetraethylammonium p-nitrobenzoate (Example 20), tetraethylammonium o-nitrobenzoate (Example 21), tetraethylammonium o-toluate (Example 22), tetraethylammonium o-anisate (Example 23) or tetraethylammonium gamma-resorcylate (Example 24) was used instead of the tetraethylammonium benzoate. The electric conductivity of the resulting electrolyte solution was measured, and the results are shown in Table 5. EXAMPLE 25 Monotetraethylammonium 6-ethyl-1,16-hexadecanedicarboxylate was dissolved in a concentration of 5% by weight in gamma-butyrolactone as a solvent to form an electrolyte solution. This electrolyte solution had an electric conductivity at 25°C of 2.0 mS/cm and a sparking voltage of 355 V when a constant current of 4 mA/cm² was applied to one set of plus and minus smooth aluminum foils in the electrolyte solution. EXAMPLES 26 TO 30 Example 25 was repeated except that the concentration of the solute was changed to 2%(Example 26), 10% (Example 27), 20%(Example 28), 30%(Example 29) or 40% (Example 30) by weight. The electric conductivity and sparking voltage of the electrolyte solution were measured, and the results are shown in Table 6. EXAMPLE 31 Example 25 was repeated except that N,N-dimethylformamide was used instead of gamma-butyrolactone. The electric conductivity and the sparking voltage of the resulting electrolyte solution are shown in Table 6. EXAMPLE 32 Monotetraethylammonium 3-hexyl-1,2-decanedicarboxylate was dissolved in a concentration of 20% by weight in gamma-butyrolactone as a solvent to form an electrolyte solution. Its electric conductivity and sparking voltage are shown in Table 6. EXAMPLES 33 AND 34 Example 32 was repeated except that monotetraethylammonium 7,12-dimethyl-7,11-octadecadiene-1,18-dicarboxylate (Example 33) or monotetraethylammonium 6,8-diphenyl-1,14-tetradecanedicarboxylate (Example 34) was used instead of the monotetraethylammonium 3-hexyl-1,2-decanedicarboxylate. The electric conductivity and sparking voltage of the electrolyte solution are shown in Table 6. COMPARATIVE EXAMPLE 10 Ammonium 6-ethyl-1,16-hexadecanedicarboxylate was dissolved in a concentration of 20% by weight in ethylene glycol as a solvent to form an electrolyte solution. The electric conductivity of the electrolyte solution is shown in Table 6. COMPARATIVE EXAMPLE 11 Ammonium 6-ethyl-1,16-hexadecanedicarboxylate (5% by weight) was added to gamma-butyrolactone as a solvent, and the mixture was heated. The compound partly did not dissolve, and the resulting product was unsuitable for use as an electrolyte solution. EXAMPLE 35 Changes in the electric conductivities of the electrolyte solutions obtained in Example 28 and Comparative Example 10 with temperature were measured, and are shown in the Drawing. The electrolyte solution of this invention (Example 28) had much higher electric conductivity than the electrolyte solution of Comparative Example 10, and did not freeze even at -50°C.

Claims: An electrolyte solution for use in an electrolytic capacitor, said solution comprising as a solute at least one quaternary ammonium salt of a carboxylic acid and a solvent, characterised in that the acid in said salt is selected from (a) at least one of maleic acid and citraconic acid, (b) at least one of benzoic acid, hydroxybenzoic acid, resorcylic acid and phthalic acid, and (c) branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total, and in that the solvent is an aprotic solvent. An electrolyte solution as claimed in Claim 1, wherein the solvent is γ-butyrolactone. An electrolyte solution as claimed in Claim 1 or 2, wherein at least one of (a) and (b) is used as the solute. An electrolyte solution as claimed in Claim 1 or 2, wherein at least one of (c) is used as the solute. An electrolyte solution as claimed in Claim 3, wherein the concentration of the solute is in the range of 5 to 40% by weight. An electrolyte solution as claimed in Claim 4, wherein the concentration of the solute is in the range of 1 to 40% by weight. An electrolyte solution as claimed in any preceding claim, wherein the mole ratio of the acid to the base in the salt is substantially 1/1. Use of an electrolyte solution for medium to high voltages of at least 100 V in an electrolytic capacitor, said solution comprising as a solute at least one quaternary ammonium salt of a carboxylic acid and a solvent, characterised in that the acid in said salt is selected from branched-chain aliphatic dicarboxylic acids having 11 to 30 carbon atoms in total, and in that the solvent is an aprotic solvent.

Inventors: MORI, SHOICHIRO MITSUBISHI PETROCHEMICAL CO. LTD., UE, MAKOTO MITSUBISHI PETROCHEMICAL CO. LTD.
Applicants: MITSUBISHI PETROCHEMICAL CO., LTD.
Application year: 1986
Main classification: H01G9
IPC codes: H01G9