A POLYURETHANE-FORMING COMPOSITION USEFUL FOR BACKING TEXTILES AND A PROCESS FOR PREPARING POLYURETHANE-BACKED TEXTILES

Abstract: Polyurethane-forming composition useful for backing textiles which comprises: (A) a first polyol which comprises a relatively high equivalent weight polyol containing an average of from 1.4 to 1.95 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls or a mixture thereof with at least one additional relatively high equivalent weight polyol containing at least 2.05 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls; (B) a relatively low equivalent weight compound having about 2 active hydrogen containing moieties per molecule; (C) a polyisocyanate and (D) a catalytic amount of a catalyst for the reaction of a polyol and a polyisocyanate, wherein the functionalities and proportions of components (A), (B), and (C) are such that the average functionality of the components together is from 1.97 to 2.03, and the composition has an isocyanate index of from 85 to 125. This invention is also a process for preparing a polyurethane-backed textile by coating the textile on one side with the above-described polyurethane-forming composition at a coating weight of from 1 to 300 ounces per square yard (0.03 to 10.2 kg/m<2>) and then heating the coated textile to a temperature of from 50 to 150<o>C until the polyurethane-forming composition is cured to a tack-free state.

Description: A POLYURETHANE-FORMING COMPOSITION USEFUL FOR BACKING TEXTILES AND A PROCESS FOR PREPARING POLYURETHANE-BACKED TEXTILES This invention relates to a polyurethane-forming composition useful for backing textiles and to a process for preparing polyurethane-backed textiles. Polyurethane backings are being increasingly used in preparing carpet and other textiles. The polyurethane backing improves the textile by adding bulk and stiffness, by securing pile fibers to the primary backing of the textile, by increasing the dimensional stability of the textile, and the like. The use of such polyurethane backings is described, for example in U.S. Patent No. 4,296,159 to Jenkines et al. The composition of the polyurethane-forming formulation used to prepare the textile backing is determined by at least three competing factors. First, the backed textile must display minimal tendency to curl or otherwise become distorted over time. Second, the backing must be as tack-free as possible, so that the textile does not stick to itself or other materials during storage and use. Third, the backing must strongly adhere to the substrate textile. It has been found that formulation mod¬ ifications which improve dimensional stability tend to increase tack and decrease the adhesion of the backing to the textile. Thus, the development of polyurethane textile backings has been characterized by compromising improvement in one of these properties for improvement in another. In addition to the problems in achieving optimal properties in the backed textile, application of the polyurethane to the textile has also proven difficult,. In commercial textile backing operations, there is very little latitude in processing parameters. It has been found that in these operations, small changes in any number of processing conditions could lead to inferior or unusable product. In particular, small changes in the isocyanate index (100 times the ratio of isocyanate equivalents to active hydrogen equivalents) could cause the production of inferior product. In addition, it has been found that con¬ ditions of humidity and moisture absorption by the fibers of the textile have substantial effect on the processing of the polyurethane composition, making the process even more difficult to control. Further, the reactivity of the composition must be carefully con¬ trolled to permit the composition to be formed into a layer and gauged to the proper coating weight, yet cure quickly thereafter. Accordingly, it would be desirable to provide a textile having a polyurethane backing which exhibits excellent dimensional stability, strong bonding to the substrate and low residual tack. In addition, it would be desirable to provide a polyurethane forming compo¬ sition which is more easily processed than polyurethane forming compositions which are conventionally employed to prepare textile backings and which provides the desired dimensional stability, tack and adhesion. In one aspect, this invention is a polyurethane- -for ing composition useful for backing textiles, which composition comprises: (A) a first polyol which comprises a relatively high equivalent weight polyol containing an average of from 1.4 to 1.95 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls (sometimes referred to herein as a "nominal diol") or a mixture thereof with at least one other relatively high equivalent weight polyol containing an average of at least 2.05 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls; (B) a relatively low equivalent weight com¬ pound having about 2 active hydrogen containing moi- eties per molecule; (C) a polyisocyanate and (D) a catalytic amount of a catalyst for the reaction of a polyol and a polyisocyanate, wherein the functionalities and proportions of com- ponents (A), (B), and (C) are such that the average functionality of the components together is from 1.97 to 2.03, and the composition has an isocyanate index of from 85 to 125. In another aspect, this invention is a pro¬ cess for preparing a polyurethane-backed textile by coating the textile on one side with the aforementioned polyurethane-forming composition at a coating weight of from 1 to 300 ounces per square yard (0.03 to 10.2 kg/m 2 ) and heating the coated textile at a temperature of from 50 to 150°C until the polyurethane-forming composition is cured to a tack-free state. The average functionality of the components is calculated by dividing the total equivalents of the functional groups being counted by the total number of moles of the components containing the functional groups. Applicants have found that with the use of a primary hydroxyl-containing polyol, and by strict control of the average functionality of the reactants, ■ a polyurethane textile backing is obtained which pro¬ vides excellent dimensional stability, very low residual tack and strong adhesion to the textile. In addition, it has been found that the use of the aforementioned composition provides for much greater latitude in processing conditions than previously known composi¬ tions. In particular, it has been found that the sensitivity of conventional textile backing compo- sitions to changes in humidity and isocyanate index is substantially reduced with the use of the present composition. Surprisingly, this composition also has desirable curing properties, even though it employs a polyol which is more reactive than those conventionally used. The polyurethane-forming composition employed to form the polyurethane textile backing comprises at least one nominal diol as described hereinafter, a chain extender as described herein, a polyisocyanate, and a catalyst. The reactive components in said formu¬ lation (by reactive components it is meant all active hydrogen containing materials and polyisocyanates) have an average functionality of from 1.97 to 2.03, prefer¬ ably from 1.98 to 2.02, and more preferably 1.99 to 2.01, For the purposes of this invention, "functionality" refers to the number of reactive moieties per molecule. For polyisocyanates, the functionality is equal, to the number of isocyanate groups per molecule. For polyols and chain extenders, the average functionality is equal to the number of hydroxyl, amine, mercaptan acid or other active hydrogen containing groups per molecule. The criticality of the average functionality of the reactive components is due, in part, to the fact that commercially available high equivalent weight polyols normally have an actual functionality which is less than their nominal functionality. For example, commercially available polyethers which are nominally "diols" in actuality have a significantly lower func¬ tionality, typically from 1.4 to 1.95. This difference between nominal and actual functionality is particu¬ larly common with polyether polyols, and especially in polymers of propylene oxide and butylene oxide. This difference in functionality has been found to adversely affect the properties of the polyurethane textile backing. Accordingly, the polyurethane forming compo¬ sition contains one or more reactive components having an average functionality greater than 2.00 to compen¬ sate for the difference in functionality in the nominal diol. The functionality and amount of the reactive component(s) having an average functionality greater than 2.00 are such that the average functionality of all components together is within the aforementioned ranges. The polyisocyanate may if desired have a functionality greater than 2.00. It is also possible to employ a low equivalent weight triol or triamine to increase the average functionality of the reactive components. However, it is preferred that the average functionality of the reactive components be increased by using in the composition a relatively high equi¬ valent weight polyol having an average of at least 2.05 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyl groups. The nominal diol used herein is a material having an average equivalent weight of from 500 to 5000, preferably from 750 to 2500 and more preferably from 750 to 2000. It has an actual functionality of from 1.4 to 1.95, preferably from 1.6 to 1.95, and at least 30 percent, preferably at least 50 percent and more preferably at least 60 percent of its hydroxyl groups are primary hydroxyl groups. Although a wide variety of materials can be used, the polyether polyols are preferred on the basis of performance and avail- ability. Polymers of propylene oxide which are at least partially end-capped with ethylene oxide are particularly preferred. In a preferred embodiment, an additional polyol having an average of at least 2.05 hydroxyl groups per molecule is used in order to increase the average functionality of the reactive components to the desired range. Except for the higher functionality, the preferred polyol for this purpose is as described with respect to the nominal diol. In particular, at least 30 percent, preferably at least 50 percent, of the hydroxyl groups of the additional polyol are primary hydroxyls. Preferably, this additional polyol has an average functionality of from 2.4 to from 3.0, more preferably from 2.5 to 2.95. When such an additional polyol is employed, it is preferred that it have an equivalent weight which is similar to that of the nominal diol, i.e. their respective equivalent weights differ by 25 percent or less. The nominal diol can be prepared in known manner by reacting an alkylene oxide with a suitable polyhydric initiator compound. The alkylene oxide is preferably a C 2 -C 4 alkylene oxide, with propylene oxide being preferred. Suitable initiators for the nominal diol include diols such as ethylene glycol, diethylene glycol, propylene glycol, 1,2-butane diol, 1,3-butane diol, 1,4-butane diol, p,p'-isopropylidine diphenol, and mixtures thereof. Other compounds having two active hydrogen atoms such as, for example, water, methyl amine, ethyl a ine, methyldiethanol amine, and piperazine can also be used as the initiator compound. The additional polyol is advantageously prepared in analogous manner using as an initiator a compound having from 3 to 8, preferably about 3 active hydrogen atoms, such as, for example, glycerine, tri- ethanolamine, diethanolamine, ethanolamine, or amino- ethylpiperazine A relatively low (i.e. 31-250) equivalent weight compound which contains two moieties which contain active hydrogen atoms is used herein as a "chain extender" component (B). Suitable as the chain extender are glycols such as, for example, ethylene glycol, propylene glycol, 1,3-propane diol, 1,4-butane diol, dipropylene glycol, diethylene glycol, bisiso- propyl aniline, triethylene glycol, tetraethylene glycol, tripropylene glycol, tetrapropylene glycol, heptapropylene glycol, and mixtures thereof. Diamines, particularly aromatic diamines such as phenylene diamine, toluene diamine, and diethyltoluene diamine are also useful. In addition, poly(alkylene oxide) diols having an equivalent weight of 250 or less can also be used. The chain extender is generally employed in an amount sufficient to increase the rate of cure of the polyurethane-forming composition and/or to increase the physical properties thereof relative to a similar composition prepared in the absence of the low equi¬ valent weight diol. Generally from 5 to 50, preferably from 5 to 30 parts of the chain extender are used per 100 parts of the relatively high equivalent weight polyols (i.e. the nominal diol and additional polyol, if any) component (A). The polyurethane-forming composition further comprises a polyisocyanate, component (C). Such poly- isocyanate is preferably substantially difunctional but as discussed hereinbefore may have a higher func¬ tionality in order that the reactive components together have an average functionality within the ranges described herein. By "substantially difunc¬ tional", it is meant that the polyisocyanate has an average functionality of from 1.8 to 2.1, preferably from 1.95 to 2.05. The polyisocyanate can be aliphatic or aromatic, but aromatic polyisocyanates are generally preferred on the basis of cost and availability. Suitable polyisocyanates include, for example, 2,4-toluenediisocyanate, xylenediisocyanate, 2,4'- and/or 4,4 * -diphenylmethanediisocyanate, p-phenyl- enediisocyanate, naphthalenediisocyanate, dianisodine diisocyanate, hexamethylene diisocyanate, l-methyl-2,- 6-diisocyanatocyclohexane, l-methyl-2,4-diisocyanat- ocyclohexane, p,p ■ -dicyclohexylmethanediisocyanate, and mixtures thereof. The 2,4'- and/or 4,4'-dipheny- lmethanediisocyanate may contain minor amounts of polymeric derivatives thereof as long as the average functionality of the reactive components is within the aforementioned ranges. Isocyanate-terminated prepolymers and quasi- -prepolymers can also be used as the polyisocyanate herein. Such prepolymers are prepared by reacting an excess of a polyisocyanate with a polyol or chain extender as described herein, or with other polyols or chain extenders. In addition, a prepolymer or quasi- -prepolymer can be formed for use in this invention by reacting a polyisocyanate with all or a portion of one or more of the nominal diol, additional polyol or chain extender used in the polyurethane forming composition of this invention. This prepolymer or quasi-prepolymer can then be reacted with the remainder of those com¬ ponents to form the desired textile backing. In essence, this last technique involves conducting a two-step, rather than a one-step polymerization reaction. Also suitable are the corresponding polyiso- thiocyanates, including isothiocyanate-terminated prepolymers. The polyisocyanate is employed in an amount sufficient to provide the polyurethane-forming compo¬ sition with an index of from 85 to 125. The isocyanate index is 100 times the ratio of isocyanate equivalents to active hydrogen equivalents in the polyurethane- -forming composition. An advantage of this invention is that the isocyanate index can be varied to compensate for water which may be absorbed by the textile being coated. In many cases, the textile contains somewhat hygroscopic fibers. The water in these fibers competes with the polyols and chain extender to react with the polyisocyanate, causing a loss in properties. Accord¬ ingly, it is preferred to adjust the polyisocyanate index to compensate for the absorbed water, or to adjust the water content of the fiber to a level which permits the use of a desired isocyanate index. Most generally, the textile has a water content of from 0 to 6, preferably from 2 to 4, percent by weight. For a textile containing 2 percent water, using a composition with an average functionality of 2.00, an isocyanate index of from 105 to 112 is preferred, and from 105 to 110 is especially preferred. Using the same composition, but with 3 percent water in the textile, a preferred isocyanate index is from 110 to 120 and from 110 to 115 is more preferred. Using the same composition, but with 4 percent water in the textile, a preferred iso- cyanate index is from 112 to 125, and a more preferred index is from 113 to 120. At lower water contents, a lower isocyanate index, i.e. from 100 to 110 is pre¬ ferred, and at higher water contents, an even higher isocyanate index is preferred. Within the preferred and more preferred ranges the combination of properties of adhesion to the textile, low tack and high dimen¬ sional stability is maximized. As the average func¬ tionality of the composition becomes higher or lower than 2.00, the preferred isocyanate index ranges become smaller. When the average functionality of the compo¬ sition is outside the range of from 1.97 to 2.03, the processing latitude becomes extremely small. In a preferred embodiment, therefore, the isocyanate index and the water content of the textile being coated are chosen together to achieve the optimal properties in the coated textile. The water content of the textile is readily manipulated by heating, or treating with steam or humid air, if desired. A catalyst, component (D), is employed in curing the polyurethane-forming composition. Suitable catalysts include, for example, tertiary amines, organo- metallic compounds, particularly metal carboxylates, and mixtures thereof. Particularly suitable catalysts include, for example, di-n-butyltin bis(mercaptoacetic acid isooctyl ester), dimethyltin dilaurate, dibutyl- tindilaurate, stannous octoate, lead octoate, ferric- acetylacetonate, bismuth carboxylates, triethylene- diamine, N-methyl morpholine, and mixtures thereof. The catalyst is advantageously employed in an amount such that a relatively rapid cure to a tack-free state is obtained. Preferably, the composition contains from 0.001 to 0.5 part by weight of the organometallic catalysts, and from 0.01 to 3 parts by weight of the tertiary amine catalysts per 100 parts of the poly¬ urethane-forming composition. Other optional materials may also be employed in the polyurethane-forming composition. Although it is preferred that the textile backing be non-cellular, a blowing agent such as water, a low boiling halo- genated alkane or an inert gas can be employed if a cellular backing is desired. Frothing techniques such as are described in U.S. Patent No. 3,821,130 are preferred when a cellular material is desired. In addition, antioxidants, pigments, smoke suppressants, flame suppressing agents such as dibromoneopentyl glycol, decabromodiphenyl oxide, tris(dichloropropyl)- phosphate, polyammonium phosphate, beta-chloroethyl phosphonate ester, chloro-phosphate ester, and polymers and copolymers of vinyl chloride and vinylidene chloride are useful herein. The polyurethane-forming composition prefer¬ ably contains an inorganic filler, primarily to provide bulk thereto. Suitable such fillers include, for example, milled glass, calcium carbonate, alumina trihydrate, talc, bentonite, antimony trioxide, kaolin, barytes, wollastonite, either as obtained or as treated with fatty acids or organotitanates, and mixtures thereof. Such fillers are generally employed in an amount from 0 to 500, preferably from 50 to 400, parts by weight per 100 parts by weight of isocyanate reactive compounds employed in the composition. In preparing a polyurethane-backed textile, the uncured polyurethane-forming composition is applied to one side of the textile and subsequently cured. The coating may, if desired, be formed into a layer and partially cured before contacted with the textile as long as curing has not progressed to a tack-free state before such contact is made. Application of the poly¬ urethane-forming composition is advantageously per¬ formed in a manner which effects sufficient penetration of the composition into the fibers of the textile so that a strong bond is formed on curing. A doctor blade or similar apparatus is suitable for this purpose. The coating weight of the backing is suitably from 1 to 300, preferably from 10 to 200, more preferably from 15 to 100 ounces per square yard suitably from 0.03 to 10.2 kg/m 2 , preferably fr 0.3 to 6.8 kg/m 2 , more preferably 1.7 to 3.4 kg/m 2 . Curing is achieved by heating the coated textile to a temperature of from 50 to 150°C until the polyurethane-forming composition is cured to a tack-free state. Heating coils, microwave heaters, infrared lamps, convection areas and the like are suitable to heat the composition to the proper cure temperature. A wide variety of woven, knitted and other textiles can be used in this invention. The textile preferably used herein comprises at least one backing material (a primary) and a pile or facing material which is attached the the backing. The most preferred textiles are floor and wall coverings and carpet or carpet tiles in particular. The preferred carpet comprises a woven or nonwoven primary backing, such as a jute, polypropylene, polyethylene, nylon, polyester. polyacrylate backing, to which is ' attached on one side a pile. The pile generally comprises yarns such as wool, nylon, polyester, acrylic, cotton, polypropylene, polyethylene, or blends thereof, or similar materials. These yarns are woven or tufted through the primary backing, fusion bonded or otherwise adhered thereto, knitted, or otherwise attached to said primary backing. The textile may also contain a secondary woven or nonwoven backing material if desired. The use of such secondary backings is known to further improve the dimensional stability of the textile. In addition, the polyurethane backing may itself be overcoated with other polymer layers, particularly a frothed or foamed polyurethane cushion, a microcellular or noncellular polyurethane or rubber (natural or synthetic) backing, a scrim or similar layer. The following examples are provided to illus¬ trate the invention but are not intended to limit the scope thereof. All parts and percentages are by weight unless otherwise indicated. Example 1 In this Example, Polyol A is a 2000 molecular weight polyether having an average functionality of 1.94, prepared by reacting dipropylene glycol with propylene oxide to a molecular weight of 1760, followed by reaction with ethylene oxide to a molecular weight of 2000. Approximately 65 percent of the hydroxyl groups in Polyol A are primary hydroxyl groups. Polyol B is a 3000 molecular weight polyether having an average functionality of 2.56, prepared by reacting glycerine with propylene oxide to a molecular weight of 2750, followed by reaction with ethylene oxide to a molecular weight of 3000. Approximately 50 percent of its hydroxyl groups are primary hydroxyl groups. In a suitable container are blended 75 grams of polyol A, 10 grams of polyol B, 15 grams of dipro- pylene glycol, 100 grams alumina trihydrate and 105 grams calcium carbonate. This polyol mixture has an average functionality of 2.00. To this mixture are added about 63 grams of a 4,4'-diphenylmethane diiso¬ cyanate prepolymer having an equivalent weight of about 181 (index =110), 1.0 gram of a 2 percent ferric acetyl- acetonate solution in a poly(propylene oxide) and 0.005 gram of a dimethyltinbis(mercaptoacetic acid isoctyl ester) catalyst. The prepolymer has an average func¬ tionality of 2.00. After thorough mixing, the resulting blend is doctored onto a commercial grade level nylon loop carpet having a woven polypropylene primary. The carpet is previously conditioned so that the nylon fibers in the carpet contain 2 percent by weight water. The coating weight is 32 ounces/square yard. The coated carpet is cured for six minutes in an oven maintained at 120°C. The resulting carpet is here- inafter designated Sample No. 1. Sample No. 2 is prepared in like manner except that the carpet is conditioned so that its nylon fibers contain 3 percent by weight of water. Sample No. 3 is also prepared in like manner, except that the nylon fibers in the carpet contain 4 percent by weight water. Sample Nos. 4 to 6 are prepared in the same manner as Sample Nos. 1 to 3, respectively, except 85 parts of Polyol A and 0 parts Polyol B are used. This polyol mixture has an average functionality of 1.98. Sample Nos. 7 to 9 are prepared in the same manner as Sample Nos. 1 to 3, except that 65 parts of Polyol A and 20 parts of Polyol B are used. This polyol mixture has an average functionality of 2.02. Each of the Samples are evaluated for adhesion to the substrate by measuring, using a tensile tester, the force required to pull one tufted loop from the primary of the control substrate. Results are reported in Table I. All tuft lock results are reported as an average of from 3 to 5 pulls. Higher values indicate superior adhesion. Dimensional stability is measured by thoroughly wetting a 2" x 6" (50.8 mm x 152.4 mm) portion of each Sample and holding one end down on a flat surface with the other end free. Edge curl is measured as the rise in centimeters of the free end of each sample from the underlying surface after 2 hours. Low values are preferred. The cohesive bond (tackiness) of the coating is measured by placing two portions of the coated carpet back to back, while still hot from curing the backing and compressing them to 60 percent of their original thickness for 1 hour at 70°C. The force required to separate the two portions is then measured. Low values are preferred. The results of the evaluation of the Samples are found in Table No. 1. Table No. 1 Sample No. 4 8 Average functionality 1 2.00 2.00 2.00 1.98 1.98 1.9 ' 8 2.02 2.02 2.02 % moisture in yarns 2 3 4 2 3 4 2 3 4 coating weight, 32.0 32.0 31.6 32.0 32.0 32.7 32.5 31.7 32.6 oz/yd 2 (kg/m 2 ) (1.08) (1.08) (1.07) (1.08) (1.08) (l.ir) (1.10) (1.07) (1.11) tuft lock, pounds 21.2 20.4 17.4 19.5 19.1 17.5 22.1 22.3 20.9 (N) (94.3) (90.7) (77.4) (86.7) (85.0) (77.8) (98.3) (99.2) (93.0) edge curl, cm 1.9 0.8 0.5 1.5 0.3 0.2 3.8 1.5 1.3 cohesive bond pounds " , 1.2 2.6 2.0 4.6 2.9 2.6 0.9 0.5 1.0 (N) (5.3) (11.6) (8.9) (20.5) (12.9) (11.6) (4.0) (2.2) (4.4) 1 Average number of functional groups per molecule of blended composition of Polyol A, Polyol B, chain extender, and polyisocyanate. The foregoing data illustrates the inter¬ dependence of average functionality, isocyanate index and moisture content in the textile. In Sample 2, the isocyanate index is optimized for the moisture content of the textile, and a coated textile having excellent tuft lock, very low tack and very low edge curl is obtained. In Sample 1, a lower water content but identical isocyanate index still provides a coated textile having excellent properties, but the edge curl is slightly higher than in Sample 2. The higher mois¬ ture content in Sample 3 causes a significant decrease in tuft lock. This is easily corrected by use of a higher isocyanate index. In Samples 4-6, the lower functionality makes it harder to optimize the properties of the coated textile at a 110 index. All are marginal in tuft lock, and Sample No. 4 is marginal in cohesive bond (residual tack). In all of these cases, a higher index provides superior properties. In Samples 8 and 9, excellent properties are obtained at a 110 index. In Sample 7, the edge curl is higher than preferred, but this is easily improved by reducing the isocyanate index. Example 2 A study of the effects of average function¬ ality of the polyurethane-forming composition on pro¬ cessing latitude is conducted by preparing a large sampling of polyurethane-backed textiles using the general procedure described in Example 1. A first set of samples is made using a polyurethane-forming com¬ position having an average functionality of 2.00. In this first set of samples, one-third are prepared using a textile containing 2 percent by weight water, one-third are prepared with a textile containing 3 percent by weight water and the rest are prepared using a textile containing 4 percent water. At each water content, the isocyanate index is varied in order to determine the range of isocyanate index which could be used to obtain a coated textile having a tuft lock of at least 20 pounds (89 N), an edge curl of less than 3 centimeters and a cohesive bond of less than 5 pounds (22 N) . The study is then repeated using polyurethane-forming compo¬ sitions having average functionalities of 1.98 and 2.02. The results of this testing are as reported in Table 2 following. Table 2 Average Water Content Isocyanate Functionality in Textile Index Range 2.00 2% 105-112 2.00 3% 110-120 2.00 4% 112-125 1.98 2% 108-112 1.98 3% 113-120 1.98 4% 114-125 2.02 2% 104-108 2.02 3% 109-112 2.02 4% 110-114 The data in Table 2 illustrate the increase in processing latitude which results from controlling the average functionality of the polyurethane-forming composition. Those samples prepared from a 2.00 func¬ tional composition provide desirable properties over a wider isocyanate index range than those prepared using the 1.98 or 2.02 functional compositions. The optimal isocyanate index ranges decrease even more as the functionality is further increased or decreased. The use of secondary hydroxyl-terminated polyethers provides a substantially smaller optimal isocyanate index range.

Claims: 1. A polyurethane-forming composition useful for backing textiles, which composition comprises: (A) a first polyol which comprises a rela¬ tively high equivalent weight polyol containing an average of from 1.4 to 1.95 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls or a mixture thereof with at least one additional relatively high equivalent weight polyol containing an average of at least 2.05 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls; (B) a relatively low equivalent weight com¬ pound having about 2 active hydrogen containing moi¬ eties per molecule; (C) a polyisocyanate and (D) a catalytic amount of a catalyst for the reaction of a polyol and a polyisocyanate, wherein the functionalities and proportions of com¬ ponents (A), (B), and (C) are such that the average functionality of the components together is from 1.97 to 2.03, and the composition has an isocyanate index of from 85 to 125. 2. The composition of Claim 1 wherein component (A) comprises a poly(propylene oxide) which is at least partially end-capped with ethylene oxide. 3. The composition of Claim 2 wherein component (C) comprises 2,4'- and/or 4,4'-diphenyl- methanediisocyanate or derivative or prepolymer thereof. 4. The composition of Claim 3 wherein component (B) comprises propylene glycol, dipropylene glycol, ethylene glycol or diethylene glycol. 5. The composition of Claim 2 further comprising (E) an inorganic filler. 6. A process for preparing a polyurethane- -backed textile by coating the textile on one side with a polyurethane-forming composition which comprises: (A) a first polyol which comprises a rela¬ tively high equivalent weight polyol containing an average of from 1.4 to 1.95 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls or a mixture thereof with at least one additional relatively high equivalent weight polyol containing at least 2.05 hydroxyl groups per molecule, of which at least 30 percent of the hydroxyl groups are primary hydroxyls; (B) a relatively low equivalent weight com¬ pound having about 2 active hydrogen containing moieties per molecule; (C) a polyisocyanate and (D) a catalytic amount of a catalyst for the reaction of a polyol and a polyisocyanate, wherein the functionalities and proportions of com¬ ponents (A), (B), and (C) are such that the average functionality of the components together is from 1.97 to 2.03, and the composition has an isocyanate index of from 85 to 125, the coating weight being from 1 to 300 ounces per square yard (0.03 to 10.2 kg/m 2 ) and then heating the coated textile to a temperature of from 50 to 150°C until the polyurethane-forming com- position is cured to a tack-free state. 7. The process of Claim 6 wherein said textile comprises a primary backing material having a pile attached to one side thereof. 8. The process of Claim 6 wherein the textile, prior to coating, has a water content of 2 percent by weight and the isocyanate index is from 105 to 112. 9. The process of Claim 6 wherein the textile, prior to coating, has a water content of 3 percent by weight and the isocyanate index is from 110 to 120. 10. The process textile of Claim 6 wherein the textile, prior to coating, has a water content of 4 percent by weight and the isocyanate index is from 112 to 125.

Inventors: KELLEY DON H, MOBLEY LARRY W, KELLEY, DON, H., MOBLEY, LARRY, W.
Applicants: DOW CHEMICAL CO, THE DOW CHEMICAL COMPANY
Application year: 1986
Main classification: B32B27
IPC codes: B32B5, B32B27, C08G18, D06M13, D06M15, D06N3