REMOVAL OF CATALYST REMNANTS FROM ETHENE/CO COPOLYMERS

Abstract: Process for removing the catalyst remnants from polymers of carbon monoxide with ethene and optionally also one or more other olefinically unsaturated hydrocarbons, which polymers have been prepared in the presence of an organic palladium phosphine catalyst, characterized in that a suspension of the polymer in an organic liquid is contacted with at least 0.25 mol of a bidentate ligand phosphine per gram atom of palladium present in the polymers, which phosphine has the general formula R¹R²-P-R-P-R³R⁴, wherein R¹, R², R³ and R⁴ represent hydrocarbon groups which may or may not be substituted with polar groups and R represents a bivalent organic bridging group containing at least two carbon atoms in the bridge.

Description: The invention relates to a process for the removal of catalyst remnants from ethene/CO copolymers. High molecular weight linear polymers of carbon monoxide and ethene in which the monomer units occur in alternating order (and which polymers therefore consist of units of the formula -CO-(C₂H₄)-) can be prepared in the presence of organic palladium phosphine catalysts. Application of these catalysts to a monomer mixture which, in addition to carbon monoxide and ethene comprises one or more other olefinically unsaturated hydrocarbons (A) with less than 20 carbon atoms leads to the formation of polymers with units of the formula -CO-(C₂H₄)- and similar or dissimilar units of the formula -CO-(A)- occurring randomly distributed within the polymer. The polymers so prepared have excellent mechanical properties; especially, very high strength, stiffness and impact resistance. The organic palladium phosphine catalysts are incorporated into the polymers and they cannot be completely removed therefrom by washing. The presence of palladium in the polymers is undesirable for two reasons. Firstly it poses problems in the processing of the generally high-melting polymers. This processing - for instance by injection moulding - is effected at a temperature at least 25°C above the melting point of the polymer. At those high temperatures the polymers are subject to thermal instability which is at least in part due to the presence of palladium catalyst remnants in the polymers. Discolouring and decomposition of the polymers results upon injection moulding. It has now been found that palladium remnants can be removed from the polymers contacting a suspension of the polymers in an organic liquid with certain organic phosphines. In order to achieve the desired objective, at least 0.25 mol of phosphine should be employed per gram atom of palladium present in the polymers. The phosphines that are eligible for this purpose are bidentate ligand phosphines of the general formula R¹R²-P-R-P-R³R⁴, wherein R¹, R², R³ and R⁴ represent hydrocarbon groups which may or may not be substituted with polar groups and R represents a bivalent organic bridging group containing at least two carbon atoms in the bridge. For the sake of brevity these phosphines will hereinafter be referred to as 'BDL' (bidentate ligand) phosphines. The present invention relates to a process for removing the catalyst remnants from polymers of carbon monoxide with ethene and optionally also one or more other olefinically unsaturated hydrocarbons, which polymers have been prepared in the presence of an organic palladium phosphine catalyst, characterized in that a suspension of the polymer in an organic liquid is contacted with at least 0.25 mol of a bidentate ligand phosphine (BDL phosphine) per gram atom of palladium present in the polymers, which phosphine has the general formula R¹R²-P-R-P-R³R⁴, wherein R¹, R², R³ and R⁴ represent hydrocarbon groups which may or may not be substituted with polar groups and R represents a bivalent organic bridging group containing at least two carbon atoms in the bridge. In the process according to the invention the quantity of BDL phosphine with which the polymer suspension is contacted should be at least 0.25 mol per gram atom of palladium present in the polymers. Preferably the quantity of BDL phosphine employed is 0.5-10, and in particular 1-3, mol per gram atom of palladium present in the polymers. The treatment of the polymer suspension with the BDL phosphine is preferably carried out at a temperature of 50-140°C and in particular at a temperature of 80-110°C. The organic liquid in the polymer suspension is preferably a lower alcohol, most preferred are methanol and ethanol. The groups R¹, R², R³ and R⁴ present in the BDL phoshine preferably contain 6 to 14 carbon atoms. Particularly preferred are BDL phosphines in which the groups R¹, R², R³ and R⁴ are phenyl groups or alkyl-substituted phenyl groups The bivalent organic bridging group R preferably contains three carbon atoms in the bridge. Examples of suitable BDL phosphines are 1,3-bis(di-p-tolylphosphine)propane, 1,3-bis(diphenylphosphine)propane and 2-methyl-2-(methyldiphenylphosphine)-1,3-bis(diphenylphosphine)propane. Preference is given to either one of the latter two BDL phosphines. In the process according to the invention the product obtained is a polymer having a reduced palladium content and therefore improved thermal stability. In addition, a palladium-containing solution is obtained from which the palladium compound that is formed in the process according to the invention can be separated. By the decomposition of this compound the palladium can be recoverd and subsequently be used again for the preparation of the palladium phosphine composition which is used as the catalyst in the polymerization. The separation of the palladium compound from the palladium-containing solution can be carried out by contacting the solution with a strongly acidic ion exchanger. Instead of the above-described, rather cumbersome route by which fresh catalyst can be prepared by separation, decomposition and synthesis from the palladium compound present in the solution, the present invention provides a much simpler way of attaining the object aimed at. For, the palladium compound present in the solution can be converted into active catalyst by contacting the solution with an oxidant. The preferred quantity of oxidant used therein depends on the quantity and the type of BDL phosphine employed in the process according to the invention. If use is made of a bisphosphine, such as 1,3-bis(diphenylphosphine)propane, the quantity of oxidant preferably amounts to 0.5-1.5 gram equivalents and in particular 0.75-1.25 gram equivalents per mol of BDL phosphine used. If a trisphosphine, such as 2-methyl-2-(methyldiphenylphosphine)-1,3-bis(diphenylphosphine)-propane is employed, the quantity of oxidant preferably amounts to 1-3 gram equivalents and in particular 1.5-2.5 gram equivalents per mol of BDL phosphine used. The term 'gram equivalent of oxidant' is used in this connection to designate a quantity of oxidant which corresponds with 1 gram atom of oxygen. Eligible oxidants are, amongst others, peroxides, hydroperoxides and oxygen. After treatment with an oxidant, the solution can at once be used for the preparation of an additional amount of polymer. If the reduction of the palladium content of the polymer obtained in the process according to the invention is considered insufficient, the process can be repeated once or several times. To this end the polymer, after having been separated from the palladium-containing solution, is again allowed to suspend in fresh organic liquid, upon which the suspension is again contacted with a BDL phosphine. As indicated hereinbefore, the process according to the invention relates to polymers prepared by using an organic palladium phosphine compound as the catalyst. Examples of such catalysts are alkylphosphine and arylphosphine complexes of palladium, such as bis(tributylphosphine)PdCl₂, bis(triphenylphosphine)PdCl₂, π-allyl(triphenylphosphine)PdCl and tetrakis(triphenylphosphine)Pd. For the preparation of the present polymers there is a strong preference for the use of catalysts belonging to a class which will be described hereinafter. These catalysts, which possess a much higher activity than those mentioned above, comprise a palladium compound, an anion of an acid with a pKa of less than 2, with the proviso that the acid is not a hydrohalogenic acid, and a BDL phosphine. For the sake of brevity these catalysts will hereinafter be referred to as 'BDL' (bidentate ligand) catalysts. In the preparation of the polymers it is preferred to use a BDL catalyst comprising a palladium salt of a carboxylic acid, in particular palladium acetate. Examples of suitable acids with a pKa of less than 2 (determined in aqueous solution at 18°C) are sulphonic acids, such as methanesulphonic acid, trifluoromethanesulphonic acid and para-toluenesulphonic acid, and carboxylic acids, such as trichloroacetic acid difluoro acetic acid and trifluoroacetic acid. p-Toluenesulphonic acid and trifluorocetic acid are preferred. In the BDL catalyst the anion of the acid with a pKa of less than 2 preferably occurs in a quantity of from 0.5 to 200, and in particular of from 1.0 to 100, equivalents per gram atom of palladium. In the BDL catalysts the BDL phosphine preferably occurs in a quantity of 0.1-2, and in particular of 0.9-1.1, mol per mol of palladium compound. As for the type of BDL phosphine used in the BDL catalysts, the same preferences apply as stated hereinbefore for the BDL phosphine used in the process according to the invention. The quantity of BDL catalyst used in the preparation of the polymers may vary within wide ranges. Per mol of olefinically unsaturated hydrocarbon to be polymerized a quantity of BDL catalyst is employed which preferably comprises from 10⁻⁷ to 10⁻³, and in particular from 10⁻⁶ to 10⁻⁴, gram atom of palladium. The preparation of the polymers using a BDL catalyst is preferably carried out at a temperature of 20-150°C and a pressure of 1-200 bar and in particular at a temperature of 30-100°C and a pressure of 20-100 bar. The process according to the invention relates to the removal of catalyst remnants from polymers of carbon monoxide with ethene and optionally also one or more other olefinically unsaturated hydrocarbons. The latter olefinically unsaturated hydrocarbons preferably have the general formula CHR₁=CHR₂, wherein the groups R₁ and R₂ together contain fewer than 18 carbon atoms and either one of the groups R₁ and R₂ is a hydrocarbon group, while the other is hydrogen or also a hydrocarbon group. In the latter case R₁ and R₂ may together form part of a cyclic structure, as in the monomers cyclopentene and cyclohexene. In so far as the groups R₁ and R₂ are hydrocarbon groups, preference is given to alkyl groups. Especially preferred are monomers in which either one of the groups R₁ and R₂ is hydrogen, while the other is an alkyl group and more specifically a methyl group. In the mixture to be polymerized the molar ratio of the olefinically unsaturated hydrocarbons relative to carbon monoxide preferably is 10:1-1:5 and in particular 5:1-1:2. The polymers to which the process according to the invention relates are normally prepared by contacting the monomers at elevated temperature and pressure with a solution of the catalyst in an organic liquid in which the polymers are insoluble. Suitable organic liquids are lower alcohols, such as methanol and ethanol. During the polymerization the polymer is obtained in the form of a suspension in the organic liquid. After the desired level of polymerization is reached, the polymerization is usually terminated by cooling and releasing the pressure. The polymer can be isolated from the suspension by filtration, washing and drying. The process according to the invention can be carried out by re-suspension of a polymer thus prepared and by contacting this suspension with the BDL phosphine. However, the BDL phosphine should preferably be added to the polymer suspension during the polymerization, at the moment of achieving the desired level of monomer conversion, for the polymerization is terminated by this addition. Example 1 (for comparison) A carbon monoxide/ethene copolymer was prepared as follows. 200 ml Methanol was introduced into a mechanically stirred autoclave of 300 ml capacity. The air present in the autoclave was expelled therefrom by pressurizing the autoclave with carbon monoxide until a pressure of 50 bar was reached, then releasing the pressure and repeating this treatment twice over. After the contents of the autoclave had been brought to 85°C, a 1:1 carbon monoxide/ethene mixture was introduced under pressure until a pressure of 55 bar was reached. Subsequently a catalyst solution was introduced into the autoclave, consisting of: 12 ml methanol, 0.02 mmol palladium acetate, 0.02 mmol 2-methyl-2-(methyldiphenylphosphine)-1,3-bis(diphenylphosphine)propane and 0.04 mmol para-toluenesulphonic acid. The pressure was maintained at 55 bar by introducing under pressure a 1:1 carbon monoxide/ethene mixture. After 2 hours the polymerization was stopped by cooling the reaction mixture down to room temperature and releasing the pressure. The copolymer was filtered off, washed with 200 ml methanol and dried at 70°C. 21 g Copolymer with a palladium content of 95 ppmw was obtained, which means that 95% of the palladium present in the catalyst had remained behind in the copolymer. Example 2 A carbon monoxide/ethene copolymer was prepared in substantially the same way as in Example 1, except that the polymerization was terminated after 2 hours by pumping into the autoclave a solution of 0.04 mmol 2-methyl-2-(methyldiphenylphosphine)-1,3-bis(diphenylphosphine)propane in 10 ml of methanol. After the temperature had been brought down to room temperature and the pressure had been released, the copolymer was filtered off (yield: 150 ml of filtrate), washed with 200 ml of methanol and dried at 70°C. 21 g Copolymer having a palladium content of 37 ppmw was obtained, which means that only 37% of the palladium present in the catalyst had remained behind in the copolymer. The 150 ml of filtrate obtained from the filtration of the copolymer was then re-introduced into the autoclave. In this case the air present in the autoclave was not expelled. Therefore, the autoclave contained 1 bar of air. After the contents of the autoclave had been brought to 85°C, a 1:1 carbon monoxide/ethene mixture was introduced under pressure until a pressure of 55 bar was reached. The pressure was maintained at 55 bar by introducing under pressure a 1:1 carbon monoxide/ethene mixture. It was observed that in the course of one hour the rate of polymerization went up from 0 to 4.5 g/hour. This latter value corresponds with the original activity of the palladium catalyst. After some time the activity gradually disappeared, which was caused by the excess of oxygen present in the autoclave in relation to phosphine (150 ml of air in the autoclave 30 ml of oxygen 1 mmol of oxygen; this is a 25-fold excess to the 0.04 mmol of phosphine that was added). By ¹³C-NMR analysis it was found that the carbon monoxide/ethene copolymers prepared according to Examples 1 and 2 had a linear alternating structure and consisted of units of the formula -CO(C₂H₄)-. The copolymers had a melting point of 257°C. Of Examples 1 and 2 only Example 2 is an example according to the invention. Example 1 falls outside the scope of the invention and has been included for comparison. Example 2 clearly demonstrates that a significant reduction of the palladium content of the polymers can be achieved with the process of this invention, and in addition, that after the process of the invention has been applied and the purified polymer has been filtered off from the suspension, there remains a filtrate from which an active catalyst solution can be prepared in a simple way.

Claims: Process for removing catalyst remnants from polymers of carbon monoxide with ethene and optionally also one or more other olefinically unsaturated hydrocarbons, which polymers have been prepared in the presence of an organic palladium phosphine catalyst, characterized in that a suspension of the polymer in an organic liquid is contacted with at least 0.25 mol of a bidentate ligand phosphine (BDL phosphine) per gram atom of palladium present in the polymers, which phosphine has the general formula R¹R²-P-R-P-R³R⁴, wherein R¹, R², R³ and R⁴ represent hydrocarbon groups which may or may not be substituted with polar groups and R represents a bivalent organic bridging group containing at least two carbon atoms in the bridge. Process as claimed in claim 1, characterized in that the polymer suspension is contacted with 0.5-10 mol of the BDL phosphine per gram atom of palladium present in the polymers. Process as claimed in claim 1 or 2 characterized in that the polymer suspension is contacted with the BDL phosphine at a temperature of 50-140°C. Process as claimed in any one or more of claims 1 to 3, characterized in that the organic liquid in which the polymer is held in suspension is a lower alcohol, such as methanol or ethanol. Process as claimed in any one of claims 1 to 4 characterized in that groups R¹, R², R³ and R⁴ are phenyl groups or alkyl-substituted phenyl groups. Process as claimed in any one of claims 1 to 5, characterized in that the bivalent organic bridging group R contains three carbon atoms in the bridge. Process as claimed in claim 6, characterized in that the BDL phosphine is 1,3-bis(diphenyl-phosphine)propane or 2-methyl-2-(methyl-diphenylphosphine)-1,3-bis(diphenylphosphine)propane. Process as claimed in any one of claims 1-7, characterized in that after having been contacted with the BDL phosphine, the polymer is separated from the suspension, that the palladium compound present in the remaining solution is converted into active catalyst by contacting the solution with an oxidant and that the catalyst solution thus obtained is employed for the preparation of an additional amount of polymer.

Inventors: DOYLE, MICHAEL JOHN, VAN BROEKHOVEN, JOHANNES ADRIANUS MARIA
Applicants: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Application year: 1986
Main classification: C08G67
IPC codes: C08F6, C08G67