METHOD OF MOULDING FIBRE REINFORCED RESIN MATRIX COMPOSITE MATERIAL

Abstract: Vacuum bag moulding of carbon-fibre-reinforced-­ plastics, sheet-form, heat-cured articles (41) net-to-size, with formed edges, e.g. buttstrap edges, is accomplished by providing mould periphery elements (20-23) of corresponding moulding edge profile (Figure 3) on the moulding face (11) of moulding tooling (12), with provision for sliding of periphery elements across the moulding face (11) during curing.

Description: This invention relates to a method of making a sheet-form article from fibre-reinforced resin matrix composite material comprising the steps of arranging the fibres and uncured resin in tooling which defines a more or less flat moulding face corresponding to the shape which it is desired that a face of the article should assume, covering the fibres and resin with a gas-tight membrane, reducing the gas pressure around the fibres and resin between the tooling and the membrane, and curing the resin at elevated temperature. Conventionally such articles are moulded over-size in the aforementioned tooling, the moulded articles being edge-trimmed to size subsequent to the moulding stage. U.S. Patent No. 4065340 of DICKINSON discloses a method of curing a reinforced resin laminate in a mould in which a cork dam is disposed around the laminate to prevent resin loss during the cure cycle. After vacuum curing, the final cured structure is machined to the desired contour, size and exterior configuration. However, the cork dam is not used to establish a desired finish shape and size or to establish the finished edge surface of the article after curing. U.S. Patent No. 4201823 of RUSSELL involves a process for curing a laminated sandwich structure including resin impregnated fibrous reinforcement material between two preformed plastic shells "having the configuration of the desired article." The two preformed shells establish the finish edge surface of the article after curing, and no periphery elements are used in the manner of the present invention. German Laid-Open Patent Application No. DE3242949 concerns a method of positioning cut-to-shape layers of fibre-reinforced material by use of a microfilm projector that projects precisely positioned outline images of successive layers of a laminated structure prior to the curing cycle. But in the method described therein there is no disclosure of any periphery elements being used to establish a finished edge surface. It has always been considered that the difficulties of allowing for thermal expansion exclude any possibility of moulding "net-to-size". There has, in addition, been a feeling that the mechanical properties of the moulded composite material may be relatively poor around the edge of the moulding, compared with the bulk properties away from the edge of the moulding. Trimming subsequent to moulding cuts away this suspect material. The trimming of mouldings after they have been cured is, however, an expensive process and can introduce unwelcome delamination of the trimmed edge. It is usually necessary to coat the trimmed edge, and this represents another unwelcome expense. It is one object of the present invention to avoid or ameliorate the above-mentioned disadvantages of the conventional moulding method. According to a first aspect of the present invention there is provided a method of making a sheet-form article as above, as a stage in the manufacture of a finished article which has an edge surface of a specified profile, characterised by the step of providing on the moulding face of the tooling at least two periphery elements of specified edge profile to define a mould cavity periphery of the desired shape and size, whereby the periphery elements serve both to contain the reinforcing fibres of the article and establish the finished size of the article, and also to establish during the moulding step, by virtue of the said edge profile, the said edge surface of the moulded article and the specified profile thereon, at least one of the periphery elements being carried on the moulding face in such a way that it can slide on the moulding face during the curing step. In the method of the invention the coefficient of thermal expansion of the material of construction of the tooling should be as close as possible to that of the resin from which the moulded article is formed. For the resins used in moulding carbon-fibre reinforced plastics (CFRP) aerostructural components, steel tooling has been found suitable in this respect, and has the additional advantage that it is relatively easy to fabricate. Nevertheless, it will normally be necessary, as explained below, to allow for thermal expansion and contraction by permitting some at least of the mould periphery elements to slide on the moulding face of the tooling, during the moulding operation. According to a second aspect of the invention there is provided tooling in which to mould, and cure at elevated temperature, a sheet-form article made from fibrereinforced resin matrix composite material, which tooling comprises a mould cavity on a moulding face of the tooling and is characterised in that the tooling includes at least one mould periphery element mounted on the moulding face of the tooling, to define part of the periphery of the mould cavity, in such a way that it can slide on the moulding face during the curing step. It is convenient to refer hereinafter to the mould periphery elements attached to the mould face as "periphery bars" or "periphery plates". In accordance with the invention, the periphery of a mould cavity of the desired shape can be delineated exclusively by two or more periphery bars or plates, or by a combination of one or more of the periphery bars or plates together with periphery surfaces integral with the mould face. In either case, the tooling is such as to define the physical size of the article, to prevent bleeding of resin out of the mould cavity, and produce a moulded article with an edge section precisely as required in the finished article, maintaining exact size repeatability through subsequent components, with a full complement of the reinforcing fibres extending all the way up to the edges of the moulded article, but at the edges covered by the resin matrix and not exposed as at a trimmed oversize edge. As a direct result of the capability of curing a composite component net-to-size, there is the additional important benefit of the ability to cure certain component edge sections not previously possible with the 'oversize' approach. One example is a "buttstrap" edge i.e. a built in edge coaming. Thus, an integrally cured access panel landing can be provided, in which the landing, that is, the support edge for the entire periphery of an access panel, is of the integral buttstrap type. Periphery bars and plates are as a rule made from the same material as the tooling "skin" which defines the moulding face. They can be secured against movement across the tool skin by locating elements, for example, studs, pins or pads welded to, or threadably engaged with, the tool skin. In a case where the periphery element is required to slide on the moulding face during curing, the locating elements which are holding it can be removed prior to cure. Alternatively, provision can be made for limited sliding movement during the cure, between the periphery element and its locating elements. For a better understanding of the present invention, and to show more clearly how the same may be carried into effect, reference will now be made, by way of example, to the accompanying drawings, in which: Figure 1 is a perspective view of steel tooling on which may be moulded a double-curvature sheet-form article which is to form part of the circumference of a larger generally cylindrical article; Figures 2 to 5 are scrap sections taken from Figure 1 along the correspondingly numbered section lines indicated thereon; Figure 6 is a section showing schematically lay up of fibres in the composite material to be moulded; and Figures 7 and 8 are further sections similar to those of Figures 2 to 5. The tooling 10 shown in Figure 1 is based on a moulding face surface 11 formed from a large steel sheet 12, backed by circumferential 13 and transverse 14 backing members to maintain the desired shape of the moulding face surface 11. Caster wheels 16 are provided for mobility. On the mould surface 11 there are provided four elements 20,21,22,23 to define the size and edge profile of a mould cavity 17 approximately 2m in length and 1m in width. Only three of the elements can be seen in Figure 1. Figure 2 shows how the element 20 is fixed to the sheet 12 by a plurality of threaded studs 24 which engage with a corresponding thread in blind bores 25 in the sheet 12. The element 21 on the opposite side of the mould cavity 17 is similarly fixed to the sheet 12. As for the element 22, Figure 3 shows that it has a stepped edge profile consisting of a step 30 linking an inside edge 31 and an outside edge 32. It is held to the sheet 12 by studs 33 in the same way as the elements 20 and 21. The opposite edge (not visible) of the mould cavity 17 is defined by the element 23 which has the simple edge profile of elements 20 and 21. Figure 4 shows a further periphery element 35 which has the dimensions of an inspection hatch which is to be provided in the moulded article. It has a periphery 36 which exhibits a stepped edge similar to that of the edge element 22. The element 35 is held to the sheet 12 by two studs 37 in apertures 38 in the element 35 and blind threaded bores 39 in the sheet 12, as explained above. The apertures can, if desired, be made oversize as shown, in which case the studs 37 can be left in place during the curing step. In use of the tooling the mould cavity 17 is filled progressively with layers 40 of carbon fibre material which are conveniently already resin-impregnated and in the so-called "pre-preg" form. Figure 6 shows in schematic form an arrangement of individual pre-preg layers 40 at a location such as along the stepped edge of the element 22 as shown in Figure 3. The step 30 on the periphery bar 22 defines a flat lip 130 in the cured composite article 41 extending between an outer edge 132 of the article and an inner edge 131. Such an edge is called an "integral buttstrap" edge. As shown in Figures 3 and 6, an increased number of pre-preg layers 40 at the edge generates a shoulder 42 in the cured article. The layers can conveniently be trimmed to size, before placement in the mould cavity by use of a template or, after placement by running a scalpel along the inside edge of the periphery surfaces of the mould cavity, that is to say, by using the periphery elements as a template. The form of the article to be moulded can include features of shape not determined exclusively by the mould surface 11 and the periphery elements 20 to 33. Figure 5, for example, shows how a strengthening stiffener flange 50 can be incorporated in the article 41 by laying pre-preg layers under and around a lower former 51 and then bringing an upper former 52 into mating relationship with the lower former 51 for moulding of the pre-preg layers between the two formers 51 and 52 and between each former and the mould surface 11 of the tooling 12. After trimming and laying up of the pre-preg layers in the mould cavity, the studs 24,33 and 37 are removed so that all the periphery elements can slide over the surface 11 in response to any stresses induced by thermal expansion or contraction during the subsequent curing step. A gas-tight membrane, that is, a so-called "vacuum bag", is laid over the tool skin. The space beneath the membrane is evacuated, to achieve across the membrane a pressure differential calculated to press the layers of fibre material firmly down into the mould cavity. Provided that the periphery bars are matched carefully to the tool surface, there should be no substantial loss of resin from the mould cavity past the bars, although some insignificant leakage, with consequent formation of "flash" may occur. After this compaction step, the resin is cured under vacuum by placing the tooling 10 in an autoclave and bringing it up to resin curing temperature. The cured article is of the required size and has a sharply defined edge of precisely the required section. As appropriate, use can be made of location pads, welded to the tool skin 12, to abut the surfaces of the periphery elements which face outwards from the mould cavity 17, and define the orientation of the elements on the tool skin 12, relative to the mould cavity 17. Welded studs and pads are appropriate for tool sheets 10 up to 9 mm thick. For sheets thicker than this, use can be made, as shown in Figs. 2,3 and 4, of location screws and pins extending through an apertures in periphery elements, to engage threadably with blind bores in the sheet. If the bores are not blind, vacuum integrity will be lost and there is a danger of escape of resin downwardly through the bores. The thickness of the bars (perpendicular to the moulding surface 12), along their inside edge at the periphery of the mould cavity 17, should be no greater than the desired thickness of the moulded component at its periphery. Otherwise, as shown in Figure 7, there can occur an undesirable upwardly projecting lip 55 on the periphery of the moulded article 41. The optimum arrangement is shown in Fig. 8 where the thickness X of the constant thickness periphery bar 20 is exactly the same as the thickness Y of the moulded article 41, and there is no resin lip corresponding to the lip 55 of Fig. 7. If the desired final thickness of the edge of the moulded article is smaller than will provide a periphery bar with sufficient physical strength during its expected life, the bar can be chamfered down, over a distance of about 10-15 mm, from the thickness necessary for its sufficient physical strength to a reduced thickness at the inwardly facing edge of the periphery bar, where its thickness must be no greater than the required thickness of the edge of the moulded article. The width of the periphery bar is arbitrary and may change with application, but experience suggests that the optimum width of the periphery bars in the plane of the tool surface 12 is about 32mm, and that the centres of any fixing studs and screws which extend through the bars should be closer to the outside edge of the bars than to the edge which defines the periphery of the mould cavity. Most preferably, the line should be about 22 mm from the mould cavity periphery. When designing moulds for large components, care must be taken to allow for the difference in the co-efficient of thermal expansion of the tooling and the composite material of the article being moulded. Both the tool skin and the uncured composite are raised from ambient temperature to the curing temperature which is typically 177°C. As a result, the composite is cured at a size larger than defined by the periphery bars at ambient temperature, and so the dimensions of the mould cavity at ambient temperature must be adjusted to compensate for this expansion. Carbon fibre resin composite (CFRP) articles do not contract, during their fall in temperature from autoclave curing temperature to room temperature, as much as might be indicated by the thermal expansion coefficient of the resin system used. Damage to the moulded article by the build-up of contraction stresses in periphery bars during cooling to ambient temperature can be avoided by removing prior to cure the locating pins of at least one set of opposing periphery bars. This allows the freed bars to "float", that is, to slide across the surface of the tooling as they remain in contact with the edge of the moulded article. Alternatively, the bars are held to the tool surface 12 by fixing means which allow limited sliding movement of the bars over the surface 12. It will often be the case, in practice, that the optimum choice of tooling for any small shaped article will lie with a combination of peripheral surfaces integral with a mould skin, and periphery bars which can slide over the tool surface 12.

Claims: A method of making a sheet-form article from fibre-reinforced resin matrix composite material comprising the steps of arranging the fibres and uncured resin in tooling which defines a more or less flat moulding face corresponding to the shape which it is desired that a face of the article should assume, covering the fibres and resin with a gas-tight membrane, reducing the gas pressure around the fibres and resin between the tooling and the membrane, and curing the resin at elevated temperature, characterised in that the method is a stage in the manufacture of a finished article which has an edge surface of a specified profile, and includes the step of providing on the moulding face of the tooling at least two periphery elements of specified edge profile to define a mould cavity periphery of the desired shape and size, both to contain the reinforcing fibres of the article and establish the finished size of the article, and also to establish during the moulding step, by virtue of the profile of an edge surface of each mould periphery element, the said edge surface of the moulded article and the specified profile thereon, at least one of the periphery elements being carried on to the moulding face in such a way that it can slide on the moulding face during the curing step. A method as claimed in claim 1 characterised in that the fibres are of carbon and the tooling is of steel. A method as claimed in claim 1 or 2, characterised in that at least one of the mould periphery elements is integral with the moulding face. A method as claimed in claim 1, 2 or 3 characterised in that the specified profile of the finished article includes a buttstrap edge. A method as claimed in any one of the preceding claims and characterised by the step of trimming to size the fibres arranged in the tooling, by the use of the periphery elements as a template. A method as claimed in any one of the preceding claims characterised in that the periphery elements are secured against movement across the moulding face by locating elements which are fixed to, and protrude from, the skin of the tooling. A method as claimed in any one of the preceding claims characterised in that at least some of the locating elements are studs which extend through apertures in the periphery elements. A method as claimed in claim 7 characterised in that the said apertures are over-size, to allow limited lateral sliding movement of the periphery elements defining the apertures over the moulding face during the curing step. A method as claimed in claim 7 including the step of removing the said studs prior to the step of curing. Tooling (10) in which to mould, and cure at elevated temperature, a sheet-form article (41) made from fibre-reinforced resin matrix composite material, the tooling comprising a mould cavity (17) on a moulding face (11) of the tooling and being characterised in that the tooling includes at least one mould periphery element (20-23) mounted on the moulding face (11) of the tooling, to define part of the periphery of the mould cavity (17), in such a way that it can slide on the moulding face during the curing step. Tooling as claimed in claim 10 characterised in that the periphery element (20-23) includes through apertures (38) and the moulding face has protruding from it locating studs (24,33,37) one extending through each said aperture to secure the periphery element to the moulding face. Tooling as claimed in claim 11 characterised in that the locating studs are removable so that they can be removed after moulding and prior to curing. Tooling as claimed in claim 11 characterised in that a clearance is provided between the locating studs and the circumference of the apertures (38) through which they extend, to allow limited sliding of the periphery elements relative to the locating studs during curing. Tooling as claimed in any one of claims 10 to 13 characterised in that at least one (22) of the mould periphery elements defines a stepped part (30) of the periphery of the mould cavity (17) for moulding at said stepped part a buttstrap edge (130) of the sheet-form article (41). Tooling as claimed in any one of claims 10 to 14 characterised in that the tooling includes at least one periphery element (35) which corresponds to that of an access aperture to be provided in the moulded sheet-form article (41), and in that an access panel aperture with an integral buttstrap landing (36) and edge is formed during the process of moulding the sheet-form article.

Inventors: MEGARRY, THOMAS JOSEPH
Applicants: SHORT BROTHERS PLC
Application year: 1986
Main classification: B29C67
IPC codes: B29C37, B29C39, B29C70, B29C33, B29K105, B29C43, B29K101, B29D7, B32B37