DECORATIVE INLAID TYPES OF SHEET MATERIALS

Abstract: Decorative, inlaid sheet materials which incorporate a matrix layer of discreet, low aspect ratio resinous particles embedded in a resinous coating. The use of printed patterns which are visible beneath the adhesive matrix containing the particles constitutes a preferred embodiment of the invention. The sheet materials of this invention are real through-patterned inlaids which do not lose their pattern due to wear in use, and which offer unique design advantages and flexibility, as well as superior properties.

Description: DECORATIVE INLAID TYPES OF SHEET MATERIALS Field of the Invention The present invention relates to decorative inla sheet materials and the like. More particularly t invention is concerned with the use of polyvinyl chlori (hereinafter "PVC") polymerization agglomerates decorative particles and their application on floor a wall covering substrates to produce realistic inla patterns, utilizing heretofore unobtainable desi strategies and exhibiting superior properties. The particles can be spherical and, when such is th case, are hereinafter sometimes referred to as "pearls" These pearls can be random-si ted on the substrate applied in- geometrical patterns. Also disclosed is the us of mixes or blends containing transparent or partl transparent pearls allowing visible underprinting as further strategy for unique design variations. Background of the Invention Sheet materials, in particular sheet vinyl floorin products, made with chips or particulate material, ar commonly referred to as inlaids. These products an processes for their manufacture are well known in th floorcovering business and originate back to the earl linoleum times where through patterned floorcoverings based on linseed oil, cork dust and resins were develope by the industry. The process was later modified for vinyl. Vinyl inlaid floorcovering consists of coars colored particles, such as chips or dry blends, which ar "laid on" a substrate and then sintered by heat, or "lai in" a transparent liquid or solid matrix and fused b heat. The chips are produced from pre-gelled or fuse spread, calendered or extruded compounds cut int geometrically regular profiles or ground into randomly shaped particles. The dry blends are made by mixing fine PVC powder with plasticizer, filler and color pigments and heating above the PVC compound's softening temperature. The small origin particles "grow" and form a loose, porous, coarse, fluffy mass. Currently, to produce realistic inlaid patterns for sheet vinyl, conventional manu acturing procedures distribute the coarse particles on the substrate in different steps with the help of area-complementary stencils, followed by topcoating with a clear wearlayer. This method is complicated and can only be used to produce large geometric patterns. The inlaid floorcoverings are normally characterized as those which maintain their decorative appearance as the surface is worn or abraded away. This characteristic makes such products particularly suitable for use in light commercial areas where significant wear is encountered. Modern inlaids generally fall into two classifications: resilients and non-resilients. Resilients include a substantially continuous layer of foam and are usually made by incorporating solid particulate material into a plastis l coating, followed by gelling and fusing. Non-resilients do not contain a foam layer and usually are made by sintering and/or calendering, or otherwise compacting, particulate material. The non-resilient products commercially offered are those containing large (about 1/8 inch) square chips in a clear matrix and those containing small (about 0.004 inch ) dry blend resin particles made by sintering and/or cα pacting normal dry blend resins. It is believed tha the reason no products containing chips, granules, o particles of an intermediate particle size ( eg. ranging from about 0.004 inch to about 0.040 inch) are offered results from limitations inherent in current inlaid manufacturing technology, discussed more fully hereinafter. While construction of inlaid products by compaction from discreet chips or particles (normally of different colors) offers distinct styling opportunities, a significant premium is paid " in terms of expensive, cumbersome equipment. Furthermore, the nature of the process restricts the range of designs available. For example, in order to effect specific registered pattern definition, it is necessary to deposit chips of different colors in preselected areas on the sheet. This is difficult mechanically, and results in a slow cumbersome process which does not produce finely defined designs. Some of the inherent difficulties in current production techniques for non-resilient inlaids have been minimized by use of increasingly sophisticated materials and design techniques, such as using fine particle size, dry blend resins, printing over the surface of the resulting inlaid product, optionally, embossing, with and without application of a wearlayer. Unfortunately, whereas the use of the finer particle size preserves the specific characteristic of an inlaid product, ie. the pattern does not change as the product wears through, overprinting the product, whether or not a wear layer is applied, essentially negates this characteristic because wearing through the print layer essentially destroys the pattern. This eliminates the product from commercial, high-use environments and limits its utility principally to styling effect in residential and related applications. Resilient inlaids are usually made by embedding ground plastic particulate material in a plastisol coating United States Patent 4, 212, 691 exemplifies such product and methods for their manufacture. As taught in thi patent, the thickness of the particles of the decorativ chips or flakes is stated to be from about 3 mils to abou 25 mils (eg. see column 7, lines 62-64). However, it i the length of the particle, ie. its largest dimension rather than thickness that is observed when viewing th pattern. That dimension is stated to be from about 50 t 5D0 mils at column 8, lines 17-18. It is to be noted tha the products disclosed all contain embedded chips or flake ground from plastic sheet stock, even when chips or flake from other stock materials are added (eg. see column 8 lines 4 et seq). These chips or flakes characteristicall have a high aspect ratio (ie. length/thickness). Thus, existing inlaid technology, although capabl of producing commercially satisfactory inlaid products, ha limitations and deficiencies. State of the art inlai technology for "chip" products first grinds the chips fro plastic sheets. This predefines the particle shape and i expensive. Furthermore, spherical particle shapes can no he made by the grinding techniques currently in use fo inlaids. Additionally, products formed by compacting o sintering dry blends have always shown limited particl distinction due to process limitations and availabl particle sizes. The particles tend to lose their identit due to agglomeration or lumping caused by the sinterin process. Purposes and Objects of the Invention It is, therefore, a principal purpose and object o this invention to provide heretofore unobtainable rea through patterned inlaids, offering unique desig advantages and flexibility, as well as superior properties. For example, wear resistance is significantly increased in comparison with leading commercially available inlaids. It is also a primary purpose and object of this invention to provide a novel process for producing such inlaids which is believed to be simpler and significantly less complicated than state-of-the-art inlaid production technology. Another purpose and object is to provide a process that in the main utilizes today's plastisol equipment and technology. Other principal purposes and objects of this invention will be apparent from the following discussion. Summary of the Invention The foregoing and other purposes and objects of this invention are accomplished by providing a decorative, inlaid floor or wall covering product which incorporates as the essential elements thereof (i) resinous particles having an aspect ratio significantly lower than those currently employed in inlaids commercially offered in the United States and a particle size, preferably falling within the range of from about 0.004 inch to about 0.040 inch, (ii) an adhesive matrix in which said particles are embedded, and (iii) a substrate which supports these and any other optional elements of the product, such as a substrate coating or sealant, a print layer, and a wear layer. Such optional elements will be discussed more fully hereinafter. In general the particles employed in this invention have an aspect ratio of no greater than about 2:1 and, preferably, no greater than about 1.5:1. Particles having an aspect ratio of about 1:1 and, in particular, spheroidal particles, are especially preferred because of the excellent results achieved therewith, as discussed more fully hereinafter. The use of particles which are essentially as thick as they are flat, ie. having a low aspect ratio, provides a product that will not lose its pattern due to wear in use, thus preserving the unique property which characterizes true inlaids. The use of printed patterns which are visible beneath the adhesive matrix containing the particles broadens the options available to the pattern designer and constitutes another embodiment of this invention. Exemplary is a decorative, inlaid floor or wall covering which comprises: a) a substrate, b) a printed layer, generally comprising a printable substrate coating or sealant, onto which is printed a pattern in an ink suitable for floor or wall covering applications, applied over and in contact with said substrate, and c) an adhesive matrix, overlaying said printed layer, and in contact therewith, in which are embedded the resinous particles, said matrix being sufficiently transparent or transluscent to permit the underprint to show through. Such product provides options for a wide variety of design strategies heretofore unobtainable with state-of-the-art sheet vinyl technology and constitutes a preferred embodiment of this invention. The inlaid products of this invention offer unique design advantages. Further, cost advantages can also be realized by utilizing raw materials which are believed to be unique to inlaid manufacture. For example, certain of the novel products of the invention incorporate an adhesive matrix consisting essentially of a plastisol layer containing a high loading of transparent and/or transluscent and colored, spheroidal resinous particles, which, preferably, range in size from about O.004 inches to about 0.040 inches. When this matrix is applied over a printed pattern, a unique visual effect is produced. Such particles can be made in uniform controlled sizes by employing technology described in United States Patent 3, 856, 900, the entire contents of which are incorporated herein by reference. Alternatively, special large particle size dry blend resinous particles, either screened to the desired size ranges of this invention from oversized material obtained from normal production variations, or specially made particles in the desired size range, can be utilized . Another, and preferred, embodiment of this invention is a decorative, inlaid floor covering which comprises: a) a non-asbestos felt sheet substrate, b) a gelled, printable, plastisol coating over said substrate, c) one or more solvent based PVC-polyvinyl acetate copolymer inks applied to the sur ace of the plastisol layer, d) a gelled adhesive matrix, overlaying said plastisol/print layer, and in contact therewith, containing an effective amount of a homopolymer or a copolymer of vinyl chloride, in which are embedded discreet spherical and essentially spherical, gelled and resinous particles, at least some of which permit the underprint to show through, and wherein said particles are coarse PVC homopolymer or copolymer polymerization agglomerates, sized to between about 0.004-0.060 (preferably less than 0.040) inches, and, optionally. e) a fused, transparent, plastisol wearlayer as a top coat. General Description of the Invention The product is comprised of a base supporting material, which, optionally, may be precoated with a plastisol to enhance printability, a print layer offering decoration, and an adhesive matrix containing transparent and pigmented resin particles, which are preferably spherical or spheroidal. In one embodiment the resulting product has an additional coating on its top surface to enhance surface properties, such as gloss and the like, and insure there is no residual porosity resulting from the process of embedding the particulates in the adhesive matrix. The incorporation of particulate materials of such size and shape, and at the loadings herein described provides the retention of pattern as the product wears through characteristic of inlaid products. The incorporation of transparent particles allowing the underprint to show through, provides an additional dimension in design capability. The combination of a transparent or transluscent adhesive matrix loaded with transparent or transluscent and/or pigmented or colored particulate material and the use of rotogravure or other forms of print offering fine registered detail and definition, provide a product which is believed to be unique and a significant advance in the art. One of the advantages of this invention is that it employs ingredients and processing technology well known to those skilled in the art. Also, by employing a fluid plastisol as the matrix material binding the particles together, the product can be manufactured without the need for the high pressures or temperatures characteristic of the calendering or agglomeration steps of the prior art processes. This processing characteristic also distinguishes the subject process from those of the prior art which employ only dry blend resins, which are agglomerated through heat sintering. Substrate The substrate is a relatively flat fibrous or non-fibrous backing sheet material, such as a fibrous, felted or matted, relatively flat sheet of overlapping, intersecting fibers, usually of non-asbestos origin. The substrate can, if desired, be asbestos or non-asbestos felts or papers, woven or non-woven; knitted or otherwise fabricated textile material or fabrics comprised of cellulose, glass, natural or synthetic organic fibers, or natural or synthetic inorganic fibers, or supported or non-supported webs or sheets made therefrom or filled or unfilled thermoplastic or thermoset polymeric materials. These and other substrate or base materials are well known in the art and need not be further detailed here. Substrate Coating The substrate or base material, optionally, can be coated to improve the print quality of the substrate. Such coatings can be plastisols, organosols, lacquers, filled or unfilled latex coatings, or other coatings conventionally employed as preprint sealants in the manufacture of floor or wall covering products. As used herein, the term "plastisol" is intended to cover a relatively high molecular weight polyvinyl chloride resin dispersed in one or more plasticizers. The plastisol upon heating or curing forms a tough plasticized solid. For purposes of the present invention plastisol compositions are intended to include organosols, which are similar dispersed polyvinyl chloride resin materials that, in addition, contain one or more volatile liquids that are driven off upon heating. Those skilled in the art will appreciate that, in addition to the basic resin constituents, other commonly employed constituents can be present in the plastisol compositions in minor proportions. Such other constituents commonly include heat and light stabilizers, viscosity depressants, and/or pigments or dyes, the latter in order to contribute color to the polyvinyl chloride resin. Typically the substrate coating employed in the products of this invention is a resinous polymer composition, preferably, a polyvinyl chloride plastisol which is substantially uniformly applied to the substrate surface, for example by means of a conventional reverse roll coater or wire wound bar, eg. a Meyer Rod Coater, wherein the grooves provided by the wires assist in metering the flow of the plastisol. The particular means for applying the substrate coating to the surface of the substrate does not relate to the essence of the invention and any suitable coating means can be employed. Exemplary of other coating means are knife-over roll coater, rotary screen, direct roll coater and the like. The thickness of the resinous polymer composition or plastisol, as it is applied to the surface of the substrate, is substantially uniform, and is in the range of about 3 mils to about 30 mils, 30 mils to about 100 mils being especially preferred. The substrate can be thinner or thicker as may be required by the particular product application. Although the preferred and typical substrate coating is a polyvinyl chloride homopolymer resin, other vinyl chloride resins can be employed. Exemplary are a vinyl chloride-vinyl acetate copolymer, a vinyl chloride- vinylidene chloride copolymer, and copolymers of vinyl chloride with other vinyl esters, such as, vinyl butyrate, vinyl propionate, and alkyl substituted vinyl esters, wherein the alkyl moiety preferably is lower alkyl containing between about 1-4 carbons. Other suitable synethetic resins such as polystyrene, substituted polystyrene, preferably wherein the substituents are selected from the group consisting of alkyl C^-CJLQ, preferably C^-C^, aryl (preferably, C -C ^ ) , polyolefins such as polyethylene and polypropylene, acrylates and methacrylates, polyamides, polyesters, and any other natural or synethetic resin capable of being applied to the substrate or base coatings of this invention to provide a smooth and uniform surface and/or to improve the print quality of the substrate or base coating surface, are also applicable; provided such resin is otherwise compatible with the overall product composition and, therefor, within the principles of this invention. Thus, it is not essential that a plastisol always be used. Organosols and aqueous latices (aquasols and hydrosols) are also of use, employing as the dispersing or suspending media, organic solvents and water, respectively, rather than plasticizers, as in the case of a plastisol. Where the preferred plastisol is employed, typical of the the plasticizers which can be used are dibutyl sebacate, butyl benzyl sebacate, dibenzyl sebacate, dioctyl adipate, didecyl adipate, dibutyl phthlate, dioctyl phthlate, dibutoxy ethyl phthlate, butyl benzyl phthlate, dibenzyl phthlate, di (2-ethylhexyl) phthlate, alkyl or aryl modified phthalate esters, alkyl, aryl, or alkylaryl hydrocarbons, tricresyl phosphate, octyl diphenyl phosphate, dipropylene glycol dibenzoate, dibasic acid glycol esters, and the like. Other constituents of the resinous substrate coating can include a blowing or foaming agent such as azodicarbonamide (if a blowing or foaming procedure is desired), conventional stabilizers/ acce erators, initiators, catalysts, etc. , such as -zinc oleat dibasic lead phosphite, etc. , conventional heat or lig stabilizers, such as metallic soaps, etc. , UV absorber colorants, dyes or pigments, notably, titanium oxid solvents and diluents, such as methyl ethyl ketone, meth isobutyl ketone, dodecyl benzene, etc. , fillers, such clay, limestone, etc, viscosity modifiers, antioxidant baσteriostats and bacteriosides, and the like. Print Layer Suitable inks include those normally used in t manufacture of floor covering, preferably resilient flo covering. These include plastisol, solvent based syste and water based systems. Such systems can include chemical suppressant in those cases where the substrate t which the ink is to be applied is a foa able plastisol o organosol. Such suppressants are well known in the ar (eg. see U.S. Patent 3,293,094). Printing onto the substrate can be effected b rotogravure, lexigraphiσ, screen printing, or othe printing techniques conventionally employed in making floo αr wall covering products. Adhesive Layer The adhesive layer is normally a plastisol o organosol additonally containing a plasticizer system associated diluents, viscosity control aids an stabilizers. Those discussed above are exemplary. Whe underprinting is present, the adhesive would not normall contain colors or pigments which would render the adhesiv layer opaque. Although other homopolymers and copolymers of viny chloride, (ie. vinyl resins other than a plastisol or organosol) such as those discussed above, can also be employed, as a practical matter, current economics dictate the use of polyvinyl chloride plastisols of the type set forth in the examples hereinafter. Resinous Particles The resinous particles of this invention can be of various sizes and geometric shapes, spherical and essentially spherical, (sometimes referred to herein as "spheroidal") being especially preferred as having the low aspect ratios discussed herein required to obtain the desirable design effects this invention is capable of providing. Each transluscent or opaque particle can contain its own individual colorant, dye or pigment, provided that at least some of the particles must be sufficiently transparent or sufficiently transluscent, to permit the printing on the print layer to show through. Although decorative chips and flakes, such as those disclosed in U.S. Patent 4,212,691, can be employed, it is preferred to employ discreet spheroidal particles for enhanced visual effect of depth and improved wear characteristics. Illustrative of those spheroidal particles which are especially preferred are the particles and the methods for their manufacture taught in U. S. Patent 3, 856, 900. This procedure is particularly convenient for the production of relatively small plastisol beads or "pearls" having a particle size of generally about 0.030 inch or smaller. For smaller particles and those ranging up to about 0.40 inch, these can be obtained by screening the oversized particles from normal suspension grade resin production or by making special particle sizes, for example, in accordance with U.S. Patent 3,856,900. Particles in this size range are particularly useful for achieving certain desirable design effects. Such procedures are also capable of making smaller particle sizes, for example, ranging from about 0.015 inch to about 0.125 inch, (eg. see U.S. Patent 3,345,235), but in the case of spheroidal particles, the procedure of U. S. 3, 856, 900 is pre erred. Although spherical or essentially spherical particles are preferred, in general, the particles employed in this invention can have a wide variety of geometric shapes, provided that the aspect ratios of such particles fall within the ranges discussed herein. Exemplary of other geometric shapes are squares, triangles, circles, an uli, other polygons, etc, or irregular sizes and shapes, or a mixture of any or all of such shapes, including spheroidal. It has been found that the size of the particles employed in carrying out this invention have a pronounced effect on the results obtained. Use of relatively small particles, eg. ranging from about 150 microns (100 mesh) to about 600 microns (30 mesh) are most advantageous in producing the desired design effects. Particles, especially spheroidal particles, averaging about 600 microns (by microscopic observation) are especially preferred. The ratio of transparent to colored particles determines the visibility of the printed pattern underneath the resulting adhesive matrix. Generally, 50% or less, and preferably 0-30 %, transparent to colored particle loading is preferred. The amount actually used will, of course, depend upon the type of end-use application and design effect desired. Good results have even been achieved in the range of 0-lOX transparent to colored particle loading. Wearlayer The optional overcoat or wearlayer is preferably a plastisol of the same or similar type as that discussed above in connection with the resins employed in the substrate coat and the adhesive layer or matrix. The formulations generally include materials to enhance special specific properties, for example gloss, wear, stain resistance, and scuff resistance. Other resins suitable for use as a top coating can be employed. Exemplary are wear resistant polyurethanes, such as those described in U.S. Patent 4,087,400. Thus in another embodiment of this invention the decorative, inlaid floor or wall coverings comprise: a) a flexible mat substrate, b) a gelled, resinous print layer, applied over said substrate, the surface of which is printed with one or more inks suitable for use in the manufacture of floor or wall covering products, and c) an adhesive matrix, overlaying said print layer, containing an effective amount of a homopolymer or a copolymer of vinyl chloride, and in which are embedded resinous particles, at least some of which permit the underprint to show through, and d) an optional topcoating or wearlayer or wearlayers selected from the group consisting of a plastisol, a polyurethane resin or a suitable mixture of each. The following examples are intended to demonstrate preferred embodiments of this invention without limiting the scope thereof. In the following examples all parts and percentages are by weight. Example 1 Floor Covering with Overall Pattern Suitable for Commercial Uses A floor covering substrate sheet of conventional type^ non-asbestos felt (Tarkett Inc., Whitehall, Pa. ), approximately 32 mils thick, was bar coated (wire wound bar) with approximately 3 mils of a layer of white printa-ble ^ plastisol, the composition of which was as follows ! Parts by Weight PVC emulsion.: relative viscosity 2.05 70 (Occidental FPC 605) PVC extender: k value 60 30 (PLICLVXC M.-50) Di(2-ethy_ hexyl) phthalate 30 Butyl, benzyl phthalate 30 Tiiani-uπr dioxide 5 Crystalline calcium carbonate 80 Barium-zinc type stabilizer 3 (IRGASTAB BZ 530) After gelling against a heated chromium drum at 300°F. , the resulting smooth surface is gravure printed on a flat print press using Series 125 inks from American Inks, Incr. » After drying in warm air at about 140°F. , an adhesive layer about 10 mils thick was applied by drawdown bar and an excess of premixed plastisol pearls (produced in Example 3 and having the composition set forth hereinaf er), about half of which were transparent and the remainder colored, were evenly distributed on the surface of the wet, tacky adhesive layer from a vibrating pan -17- (SYNTRON vibrator manufactured by FMC Corp. ) . The composi¬ tion of the adhesive mix was: Parts by Weight PVC dispersion: relative viscosity 2.05 70 (Occidental FPC 6458) PVC extender: k value 60 30 (PLIOVIC M-50) Butyl benzyl phthlate 25 Di-isononyl phthlate 25 Stabilizer, barium-zinc type 4 (SYNPRON 1665) The composition of the pearl particles was: Parts by Weight Colored Transparent Suspension grade PVC resin: k value 65 100 100 (PEVIK0N S658 GK) Butyl benzyl phthalate 40 40 Stabilizer, barium-zinc type 4 4 (SYNPRON 1665) Titanium dioxide 5 Color-pigment 5 (Purchased blend of red iron oxide, yellow iron oxide and carbon black dispersed in di(2-ethyl-hexyl) phthalate) The PEVIK0N S65S GK resin had an aspect ratio of about 1 (the particles were round) and the particle size was found by microscopic observation to average about 600 microns (approximately 30 mesh). Screen analysis was as follows: Mesh '/. Retained 28 (589 microns) 68.0 65 (208 " ) 25.2 100 (147 " ) 1.4 Thru 100 mesh 5.4 The excess pearls, which were not wetted by the adhesive coating and embedded therein were blown away by a gentle air stream. The resultant grainy matrix was then gelled by contacting the coated side against a heated chromium drum (350°F. ) and smoothed between a rubber pressure roller and the drum surface. The thickness of the matrix containing the adhesive coat (10 mils) and the embedded pearls (approximately 20 mils) was 30 mils. The surface of the matrix was then bar coated using a_ drawdown bar with a transparent plastisol wearlayer having the following composition: Parts by Weight Dispersion grade PVC, relative viscosity 2.05 100 (Occidental FPC 6458) Xsobutyric acid and glycol ester of benzoic acid 56 (Monsanto SANITIZER S-377 plasticizer) Stabilizer, barium-zinc type 5 (SYNPRON 1665) Epoxidized soybean oil 5 Kerosene 2 Brookfield Viscosity: -1200 cps The wearlayer was fused in a hot air oven at about 300°F. for 3.5 minutes and then embossed between a cooled embossing roll and a rubber pressure roll. The resultant wearlayer has a thickness of about 15 mils. The wear characteristics of the decorative inlaid product thereby produced are set forth in the following Table I and compared with leading competitive products. • 19 - TABLE I TABER ABRASION Run on Taber Abrasion Model #505 using H-18 wheels Product Wt. Loss Thickness Initial Wt % Wear-out Wear-out 4"X4" Smpl Caliper 1000 cycles Point Point PRODUCT (σ ) (mils) (α) (cycles) (mils) TARKETT Residential 21.3014 92 .0803 36, 000 36 Commercial 22.3489 83 .0919 60, 500 45 ARMSTRONG "Crowne Corlon" 46.0910 75 .2294 22, 500 42 "Designer Solarian" 28.2392 88 .2696 27, 500 60.5 "Solarian Supreme II" 28.7303 92 .3131 3,000 5 C0NG0LEUM "Innovation" 17.2543 72 .0905 8, 000 10 F0RB0 "Smaragd" 18.1629 56 .0416 24, 000 27 Exa ple 2 Residential Floorcovering with Registered Printed and Embossed Patterns (Chemically Embossed) A floorcovering substrate sheet of conventional type non-asbestos felt (Tarkett Inc., Whitehall, Pa. ) approximately 32 mils thick was coated with a foamable plastisol the composition of which was as follows: Parts by Weight PVC dispersion: k value 65 70 (Occidental FPC 605) PVC extender resin: k value 60 30 (PLI0VIC M-50) Di(2-ethylhexyl) phthlate 28 Butyl benzyl phthlate 15 Texanol isobutyrate (TXIB) 15. Titanium dioxide 10 Azodicarbonamide 2.5 Kerosene 4 Zinc oxide 1.5 Viscosity: 2500 cps The coated substrate is then pregelled in a hot oven at 275°F " . for 2.5 minutes. The surface is then gravure printed on a flat bed press using inks having the same composition as those of Example 1 except that the inks used to cover the plate printing the valley areas of the pattern ( ie. the grouts) contain additionally 140 parts benzotria- zole, a chemical suppressant, to inhibit in these selected areas the expansion of the foamable plastisol. After drying the print, an adhesive layer having the same composition as that of Example 1 was applied by a drawdown bar. Premixed colored and transparent pearls, in the same ratio Example 3, were evenly distributed, gelled and smoothed as described in Example 1. The thickness of the resulting matrix containing the pearls (15 mils ) embedded in the adhesive (5 mils ) was about 20 mils. Approximately 10 mils of a transparent wearlayer having the same composition as that of Example 1 was applied with a drawdown bar. The resulting product was then fused and expanded (ie. foamed) in a hot air oven at 380°F. for 3 minutes. The floorcovering produced shows a relief structure (embossing) in register with the printed areas. The decorative inlaid product thereby produced has an overall thickness of about 82 mils and exhibited excellent wear and design characteristics. Example 3 The plastisol spherical "pearls" used in the foregoing examples were prepared using the following ormulations: Parts by Weight Colored Transparent Suspension grade PVC resin, coarse: k value 65 (PEVIC0N S658 GK) 100 100 Butyl benzyl phthalate 40 40 Earium-zinc stabilizer 4 4 ( SYNPRON 1665) Titanium dioxide 5 - - Color-pigment 5 — In preparing the colored and transparent plastisol composition, the PVC resin (at 70°F. ) was charged to a high intensity mixer running at 3500 RPM and mixed until the batch temperature reached 160°F. (about 10 minutes). The speed of the mixer was then reduced to 500 revolutions per minute and the pigment pastes, plasticizer and stabilizer were added slowly over a period of about 5 minutes. The speed was then increased to 2000-3000 rpm and the material mixed until the batch temperature reached 260°F. (approximately 15 minutes additional). The speed was then reduced to 500 RPM and the material was mixed until the batch temperature cooled to 70-9Q°F. (about 30 additional minutes). The pearls produced were essentially spherical, dry and free running; did not exceed 0.60 inch in diameter, and had a particle size distribution range of .004 to .040. The following table summarizes the process parameters employed: Equipment: High intensity mixer 2.6 gal. volume 3 lbs, loading Elapsed Time Temperature Speed Min. Degrees F. Rev/Min O ~70 3500 10 160 500 pigments, plasti¬ cizer and stabi¬ lizer added 15 260 2000-3000 30 500 cooling 60 -70 Examples 1 and 2 demonstrate decorative, inlaid floor coverings which constitute highly preferred embodiments of this invention and which comprise: a) a substrate sheet of conventional type non-asbestos felt, b) a gelled, thin, white, or tinted, printable plastisol coating over said substrate, prepared from effective amounts of a formulation comprising: - an emulsion type PVC, preferably having a relative viscosity about 2.5, - a PVC extender, preferably having a k value about 60, - a plasticizer, preferably a phthlate such as di(2-ethylhexyl) phthlate or butyl benzyl phthalate, - a pigment, preferably titanium dioxide, - crystalline calcium carbonate, and - a barium-zinc type stabilizer σ) a print layer of one or more inks made from effective amounts of a formulation comprising: - a PVC-PVAc resin copolymer. - one or more pigments, - a solvent, preferably consisting essentially of methyl ethyl ketone and xylene, and - a dispersion aid; d) a gelled adhesive layer made from effective amounts of a formulation comprising: - a PVC dispersion, preferably having a relative viscosity about 2.5, - a PVC extender, preferably having a k value about 60, - a plasticizer, preferably butyl benzyl phthalate or di-isononyl phthalate, and - a barium-zinc type stabilizer, and e) a mixture of gelled, transparent and colored pearls, wherein the pearls are about 50% transparent and about 50% colored, evenly distributed on the adhesive layer, prepared from effective amounts of a formulation comprising: - a PVC suspension resin, preferably coarse and having a k value about 65, - a plasticizer, preferably butyl benzyl phthalate, - a barium-zinc stabilizer, and, optionally, - a pigment or a color selected from the group consisting of red oxide, yellow oxide, chrome yellow, molybdate orange, carbon black, titanium oxide, quinanthrone red, phthallo blue and phthallo green. Although the forgoing discussion describes this invention in terms of floor or wall covering products, this invention is intended to encompass any covering including, but not necessarily limited to, floor or wall covering, which incorporates a matrix layer of discreet, low aspect ratio resinous particles embedded in a resinous coating. While the invention has been described with respect to certain embodiments thereof, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.

Claims: WHAT IS CLAIMED IS: 1. In a decorative, inlaid floor or wall covering comprising a layer containing resinous particles and a substrate which supports said layer, the improvement which comprises, either substituting for or applying in addition to said layer, a matrix layer which consists essentially of discreet, low aspect ratio resinous particles, embedded in a resinous coating, incorporated in said product in a configuration wherein said low aspect ratio particles are visible in use. 2. A decorative, inlaid floor or wall covering which comprises: a) a substrate, b) a printed layer applied over said substrate, and c) an adhesive matrix, overlaying said printed layer, in which are embedded resinous particles, at least some of which permit the underprint to show through. 3. The product of Claim 1 wherein the substrate is a flexible mat. 4. The product of Claim 1 wherein the substrate is a non-asbestos felt sheet. 5. The product of Claim 2 wherein the print layer is a gelled, resinous layer, the surface of which has been printed with an ink suitable for use in the manufacture of floor or wall covering products. 6. The product of Claim 2 wherein the adhesive matrix contains a major amount of a homopolymer or copolymer of vinyl chloride. 7. The product of Claim 2 wherein the adhesive matrix is applied only in selected areas to give a pattern. 8. The product of Claim 1 wherein the low aspect resinous particles are a blend selected from the group consisting of colored and non-colored transparent, transluscent and opaque particles having an aspect ratio less than about 2:1. 9. The product of Claim 8 wherein said particles are essentially spherical, plasticized polyvinyl chloride particles having an aspect ratio of about 1. 10. A decorative, inlaid floor or wall covering which comprises: a) a flexible mat substrate, b) a gelled, resinous print layer, applied over said substrate, the surface of which is printed with one or more inks suitable for use in the manufacture of floor or wall covering products, and c) an adhesive matrix, overlaying said print layer, containing an effective amount of a homopolymer or a copolymer of vinyl chloride, and in which are embedded resinous particles, at least some of which permit the underprint to show through. 11. The product of Claim 10 wherein the particles a blend of transparent, transluscent and opaque particles can be colored or non-colored. 12. The product of Claim 10 wherein said particles essentially spherical, plasticized polyvinyl chloride particl 13. The product of Claim 10 wherein the substrate non-asbestos felt sheet. 14. The product of Claim 10 wherein the resinous p layer is a gelled, foamed or foamable layer and at least on the inks is a suppressant ink. 15. The product of Claim 10 wherein the adhe matrix is applied in selected areas to give a pattern. 16. The product of Claim 10 wherein the particles discreet, spherical and coarse PVC, homopolymer or copoly polymerization agglomerates, sized between about 0.004-0. inches. 17. The product of Claim 10 wherein the adhe matrix is coated with at least one additional wearlayer. 18. A decorative, inlaid floor covering w comprises: a) a non-asbestos felt sheet substarte, b) a gelled, printable, plastisol coating over said substrate, c) one or more solvent based PVC/PVAc inks, applied to the surface of the plastisol layer, d) a gelled adhesive matrix, overlaying said plastisol/print layer, containing an effective amount of an homopolymer or a copolymer of vinyl chloride, in which are embedded discreet, spherical, gelled resinous particles, at least some of which permit the underprint to show through, and wherein said particles are coarse PVC homopolymer or copolymer polymerization agglomerates, sized to between about 0.004-0.040 inches, and e) a fused, transparent, plastisol wearlayer as a top coat. 19. The product of Claim 18 wherein the printable, platisol coating is made from effective amounts of a formulation comprising: a) an emulsion type PVC, b) a PVC extender, c) one or more phthalate plasticizers, d) a whitening or a tinting agent, and e) a stabilizer. 20. The product of Claim 18 wherein the ink is made from effective amounts of a formulation comprising: a) a PVC-PVAc copolymer resin, b) one or more pigments, c) one or more solvents, and d) a dispersion aid. -30- 21. The product of Claim 20 additionally comprising benzotriazole and wherein the plastisol is foamable. 22. The product of Claim 18 wherein the adhesive matrix is prepared from effective amounts of a formulation comprising: a) a dispersion grade PVC, b) a PVC extender, c) one or more phthalate plastizers, and d) a stabilizer. 23. The product of Claim 18 wherein the resinous particles are colored and transparent pearls evenly distributed within the adhesive matrix. 24. The product of Claim 18 wherein the particles and the adhesive matrix are gelled. 25. The product of Claim 18 wherein the top coat wearlayer is prepared from effective amounts of a formulation comprising: a) a dispersion grade PVC, b) one or more organic acid esters, σ) a stablizer, d) epoxidized vegetable oil, and e) kerosene. 26. A decorative, inlaid floor covering which comprises: a) a substrate sheet of conventional type non-asbestos felt, b) a gelled, thin, white, or tinted, printable plastisol coating over said substrate, prepared from effective amounts of a formulation comprising: an emulsion type PVC, relative viscosity about 2.5, a PVC extender, k value about 60, di ( 2-ethylhexyl) phthalate, - butyl benzyl phthalate, titanium dioxide, crystalline calcium carbonate, and a barium-zinc type stabilizer c) a print layer of one or more inks made from effectiv amounts of a formulation comprising: a PVC-PVAc resin copolymer, - one or more pigments, a solvent consisting essentially of methyl ethyl ketone and xylene, and a dispersion aid; d) a gelled adhesive layer made from effective amounts of a formulation comprising: - a PVC dispersion, relative viscosity about 2.5, a PVC extender, k value about 60, butyl benzyl phthalate, di-isonαnyl phthalate, and a barium-zinc type stabilizer; e) a mixture of gelled, transparent and colored pearls, evenly distributed on the adhesive layer, prepared from effective amounts of a formulation comprising: - a PVC suspension resin, coarse, k value about 65, butyl benzyl phthalate, a barium-zinc stabilizer, and, optionally, titanium dioxide, and a color or a pigment.

Inventors: LUSSI EDWARD FRANZ, SMITH THOMAS GEORGE, LUSSI, EDWARD, FRANZ, SMITH, THOMAS, GEORGE
Applicants: TARKETT INC, TARKETT, INC.
Application year: 1986
Main classification: B32B5
IPC codes: D06N7