HEATING ELEMENT MADE OF CARBON

Abstract: A heating element made of carbon, comprising a heating member including carbon powder and an insulating resin, the powder being kneaded with the resin, and a core member formed of an insulating material and having a higher fusing point than the heating member, the core member being disposed substantially centrally of the heating member.

Description: The present invention related to a process for making a heating element in a cable-like form with several coaxial layers, said layers comprising a core member of insulating plastics at the centre of the element, a conducting member formed around said core member and comprising electroconductive powder, and an outer insulating protecting layer surrounding said conducting member. Heating elements of this type are installed under road surfaces to be used for melting snow or under floors for heating purposes. The heating element of this type consumes less electricity than the known Nichrome wire, and the heating member per se has a temperature control function with the insulating resin repeating expansion and contraction with temperature variations thereby controlling an electric current flow. Therefore, in recent years this heating element is employed in floor heating and various other applications, and is marketed in planar and linear forms. However, the heating element commercially available heretofore has the disadvantage that the heating temperature greatly varies at locations of the heating element, failing to assure uniform heating. The present inventor has conducted various tests in search of the cause of such a drawback, and has found the cause in the construction of the heating element. The conventional heating element, taking one in linear form as shown in Fig. 5 of the accompanying drawings for example, comprises a solid heating member 2' having an about 4 mm diameter and peripherally coated with an insulating member 4' having an about 1 mm thickness. Such heating element l' usually is formed by extruding the heating member 2' and insulating member 4' together from an extruding machine and immediately cooling the same by cooling water or other means. It is observed that the cooling processes causes the composition of the heating member 2' to be non-uniform in the radial direction and even creates numerous holes A in the center. It has been found that, due to the non-uniformity in the composition of the heating member 2' and the presence of holes A, the electric resistance of the heating member 2' greatly varies from one point to another, which results in non-uniformity in its heating temperature. Even if a thermistor, for example, is incorporated to control the temperature, the unequal heating temperature results in "hot spots". This renders the use of the thermistor meaningless and lets arise safety problems. Such phenomenona occur with the planar heating element, too. Furthermore, in the case of a linear heating element l', expansion of the insulating member occuring with the heating elongates the heating element 1'. Where a plurality of heating elements 1' are juxtaposed, adjacent elongated heating elements tend to contact each other causing short circuits. A heating element made of graphite, comprising a heating member formed of graphite-powder and an insulating resin kneaded together, is know from DE-B- 1 765 622. Therein the heating member surrounds a core member formed of an insulating material and having a higher fusing point than the heating member. This publication does not describe an extrusion process. The main feature is to lay down an electroconductive layer by pumping a solution of fluid lacquer through a tube. The adherent fluid then is evaporated and leaves a conductive layer. This process, however, is very complicated, especially if a homogenous conducting layer is to be achieved. The adherence of the conducting layer to the inner wall of the tube is doubtful. Further, is it difficult to insert a core member without damaging the conductive layer. Further, a heating member formed of graphite or carbon powder is known by DE-A-2 342 657. This publication discloses only the use of heating members containing carbon powder and a resin, not an extrusion process The present invention intends to eliminate the disadvantages of the prior art by utilizing the above-noted new findings. The object of the invention is to provide a process for making a heating element made of carbon which is capable of securing a substantially uniform heating temperature throughout the heating element and which, when in a linear form, undergoes a minimal amount of elongation. In order to achieve this object, the process for making a heating element is characterized in that the core member, the conducting member and the protecting layer are formed in an extrusion process, thereby the conducting member being formed of a kneaded mixture of carbon powder and an insulating, extrudable resin, and the plastics material for the core member having a fusing point higher than that of said insulating resin employed in said conducting member. Since the insulating core member is placed in the heating member, the manufacturing mode where the heating member and the core member are extruded together from an extruding machine and are cooled immediately thereafter causes the non-uniformity of composition and voids only in the core member inside the heating member. The heating member disposed exteriorly remains quite uniform in composition and its electric resistance is substantially constant over various locations thereof. Furthermore, since this core member has a higher fusing point than the heating member, the core member itself becomes little elongated in spite of a temperature rise and acts to check elongation of the heating member which would otherwise be elongated by the temperature rise. As will be clear from the foregoing explanation, the heating element made according to this invention has a substantially constant electric resistance over various locations thereof has a substantially uniform heating power throughout, which facilitates its temperature control. Where the heating element is in linear form and a plurality of heating elements are arranged parallel to one another, their elongation is restrained to a maximum degree thereby to prevent contact between adjacent heating elements. Brief Description of the Drawings Figs. 1 to 3 show a heating element made of carbon which is made according to the present invention, in which Fig. 1 is a sectional view, Fig. 2 is a partly broken away plan view showing the heating elements as used in a panel heater, and Fig. 3 is a sectional view taken on line III-III of Fig. 2; Fig. 4 is a schematic plan view of the panel heater showing locations of temperature measurement; and Fig. 5 is a sectional view of a conventional heating element. Detailed Description of the Preferred Embodiments An embodiment of the invention will be described with reference to the drawings. Fig. 1 shows a section of a linear heating element 1 comprising a conventional heating member 2 formed of carbon powder and an insulating resin kneaded together and a core member 3 embedded centrally of the heating member 2. The core member 3 has a higher fusing point than the heating member 2 and is formed of an insulating material and more specifically of polypropylene, polyethylene or ceramics. The heating member 2 is peripherally coated with an insulating member 4 comprising polypropylene, polyethylene or the like, as necessary. The heating element 1 having the above construction may be manufactured relatively easily by extruding the core member 3, heating member 2 and insulating member 4 all together from an ordinary extruding machine. In this case it is of advantage from the manufacturing point of view if, as shown in Fig. 1, the heating member 2 and insulating member 4 have a substantially annular section and the core member 3 has a substantially circular section. However, it is not absolutely necessary for these member to have such sectional shapes. The shapes may be modified in various ways; for example, the core member 3 may have an elliptical or polygonal section and the heating member 2 may have an elliptical or polygonal hollow section. Figs. 2 and 3 show an example in which the above heating element 1 is employed in a panel heater. The panel heater comprises a box 5 formed of a metallic material and enclosing a ceramic bed 7 defining a total of three grooves 6, and the heating element 1 is fitted in each groove 6. The heating elements 1 are connected, in parallel with one another, to an AC source 9 through wires 8. Glass wool 10 is filled in a space inside the box 5. The heating elements 1 become hot when electrified as does the conventional heating element. However, since each of the heating elements 1 made according to this invention becomes hot substantially uniformly in a longitudinal direction thereof, a top surface of the box 5 naturally is heated substantially uniformly. Furthermore, the presence of core member 3 is effective to check elongation of the heating element 1, and there occurs no contact between the adjacent heating elements 1 which would cause a short circuit. In order to confirm the advantages of this invention comparative tests have been carried out on the conventional heating element shown in Fig. 5 and the heating element made according to this invention shown in Fig. 1, and the test results will be set forth hereinafter. The conventional heating element used in the tests comprised a heating member 2' having a 4 mm diameter and an insulating member 4' having a 1 mm thickness while the heating element of this invention used in the tests comprised the core member 3 having a 4 mm diameter and the heating member 2 having a 1 mm thickness. The latter included no heating element 4 since the heating element 4 was not absolutely necessary. Naturally, both heating elements had the heating members 2' and 2 identical to each other as far as the material per se is concerned. (Test 1) Both heating elements 1' and 1 were manufactured using an ordinary extruding machine, and each was cut to pieces of a 1,600 mm length. Fifty pieces each were taken as samples for comparison in electric resistance measurements. Both were manufactured with 1 ,500 ohms as the per piece standard. With the conventional heating element, 26 pieces had resistance values 1,000-1,200 ohms, 5 pieces 1,300-1,400 ohms, 11 pieces 1,400-1,500 ohms, 4 pieces 1,700-1,900 ohms and 4 pieces 2,000-2,300 ohms. With the heating element made according to this invention, on the other hand, 12 pieces had resistance values 1,480-1,500 ohms and 38 pieces 1,500-1,520 ohms. It may be understood from these results that the heating element made according to this invention is very stable in electric resistance, which means that the electric resistance is substantially uniform throughout locations in the longitudinal direction of the heating element. (Test 2) Three 1,600 mm long pieces of each of the heating elements 1' and 1 were placed in the box 5 as shown in Figs. 2 and 3, a 200 volt alternating current was sent thereto, and one hour later the surface temperatures of the two heating elements 1' and 1 were measured and compared by means of thermolabels. The temperatures were measured at points a to m in Fig. 4. The box 5 had 1,750 mm long sides, 120 mm short sides and a 15 mm height. The temperatures in the table are in the centigrade. It will be understood from these results how stable the heating temperatures are at the various locations longitudinally of the heating element made according to this invention. It has further been confirmed through this test that there is an outstanding difference in the amount of elongation between the two heating elements 1' and 1. The difference in the amount of elongation became clear one hour from the start of electrification. After the lapse of 24 hours from the start of electrification the conventional heating element began to deform due to the elongation at about 95°C and became overheated to about 120° C at deformed locations. However, the heating element made according to this invention did not show any deformation due to the elongation when the element was heated to about 100° C. The invention has been described taking the production of the linear heating element 1 for example, but the gist is applicable also to a planar heating element. In embodying the invention into the planar heating element, a core member may completely be embedded in a planar heating member or may be sandwiched between two adjacent planar heating members.

Claims: Process for making a heating element (1) in a cable-like form with several coaxial layers, said layers comprising a core member (3) of insulating plastics at the centre of the element, a conducting member (2) formed around said core member (3) and comprising electroconductive powder, and an outer insulating protecting layer (4) surrounding said conducting member (2), characterized in that the core member (3), the conducting member (2) and the protecting layer (4) are formed in an extrusion process, thereby the conducting member (2) being formed of a kneaded mixture of carbon powder and an insulating, extrudable resin, and the plastics material for the core member (3) having a fusing point higher than that of said insulating resin employed in said conducting member (2). Process according to claim 1, characterized in that the extruded heating element (1) is immediately cooled after extrusion. Process according to claim 1 or 2, characterized in that the core member (3) consists of polypropylene or polyethylene. Process according to claim 1 - 3, characterized in that the core member (3) has a substantially circular section, while the conducting member (2) has a substantially annular section. A panel heater characterized in that a plurality of heating elements (1) produced according to the process of claims 1 - 4, are disposed in a box and connectable in parallel with a power supply.

Inventors: TAKEDA, JUNICHI
Applicants: JAPAN UNICARBON CO., LTD., NAKABISHI KENSETSU CO., LTD.
Application year: 1986
Main classification: H05B3
IPC codes: H05B3