OPTICAL RECORDING MEDIUM

Abstract: An optical recording medium is disclosed, comprising a support having provided thereon a record­ ing layer containing a naphtholactam dye represented by formula: wherein K represents a substituted or unsubstituted aromatic amine residue; R represents a substituted or unsubstituted alkyl group, a substituted or unsub­ stituted cycloalkyl group, a substituted or unsub­ stituted aryl group, or a substituted or unsubstituted allyl group; Z⁻ represents an anion; ring A represents a substituted or unsubstituted naphthalene ring; and m represents 1 or 2. The recording layer can be formed by coating easily, has a high reflectance to provide a satisfactory contrast of recording, and exhibits excellent resistance to light.

Description: This invention relates to an optical recording medium. More particularly, it relates to an optical recording medium whose recording layer has a high reflectance and can be formed easily. Optical recording media using a laser beam, etc. including laser discs are capable of recording and preserving informations at high densities and reproducing the recorded informations easily. Laser discs generally comprise a disc base having provided thereon a thin recording layer, on which a laser beam condensed to a diameter of about 1 µm is irradiated to carry out high-density recording. Upon absorption of energy of the irradiated laser beams, the recording layer undergoes thermal changes, such as decomposition, evaporation, dissolution, and the like to thereby make a difference in reflectance between the irradiated areas and the non-irradiated areas. Reproduction of the recorded informations can be carried out by reading the difference of reflectance. Therefore, in order to effect high-density recording and precise reproduction, optical recording media are required to show efficient absorption of a laser beam having a specific wavelength used for recording and to highly reflect a laser beam having a specific wavelength used for reproduction. Various structures are known for this type of optical recording media. For example, Japanese Patent Application (OPI) No. 97033/80 (the term "OPI" as used herein refers to a "published unexamined Japanese patent application") discloses a support having provided thereon a single layer of phthalocyanine dyes. However, phthalocyanine dyes have disadvantages, such as low sensitivity, high decomposition points which lead to difficulty in vacuum deposition, and very low solubility in organic solvents which lead to difficulty in coating for formation of the recording layer. Japanese Patent Application (OPI) Nos. 83344/83 and 22479/83 disclose phenalene dyes and naphthoquinone dyes, respectively, to be coated as a recording layer. These dyes, though easy to evaporate in vacuo, show low reflectances. Low reflectances result in poor contrast in reflectance between the recorded areas and non-recorded areas, thus making it difficult to reproduce the recorded informations. In addition, Japanese Patent Application (OPI) Nos. 24692/84, 67092/84, and 71895/84 disclose recording layers comprising cyanine dyes. The cyanine dyes have an advantage of easy coating but are inferior in light resistance and undergo deterioration due to light for reproduction. One object of this invention is to provide an optical recording medium whose recording layer can easily be formed by coating. Another object of this invention is to provide an optical recording medium whose recording layer has a high reflectance to provide a satisfactory contrast of recording. A further object of this invention is to provide an optical recording medium having excellent resistance to light, particularly light for reproduction. These objects have been accomplished by providing a recording layer containing a naphtholactam light-absorbing dye having a specific chemical structure. The present invention relates to an optical recording medium comprising a support having provided thereon a recording layer containing a naphtholactam light-absorbing dye represented by formula (I): wherein K represents a substituted or unsubstituted aromatic amine residue; R represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted allyl group; Z⁻ represents an anion; ring A represents a substituted or unsubstituted naphthalene ring; and m represents 1 or 2. In formula (I), substituents for the alkyl, cycloalkyl, aryl or allyl group as represented by R include an alkoxy group, an alkoxyalkoxy group, an alkoxyalkoxyalkoxy group, an allyloxy group, an aryl group, an aryloxy group, a cyano group, a hydroxyl group, a tetrahydrofuryl group, and a halogen atom. Substituents for the naphthalene ring as represented by ring A include a halogen atom, a cyano group, a thiocyanate group, an alkyl group having up to 10 carbon atoms, an alkoxy group having up to 10 carbon atoms, an alkylamino group, an acylamino group, an amino group, and a hydroxyl group. The substituted or unsubstituted aromatic amine residue as represented by K include residual groups of heterocyclic amines containing a nitrogen atom, an oxygen atom or a sulfur atom, residual groups of tetrahydroquinolines, and groups represented by formula: wherein X and Y each represents a hydrogen atom, an alkyl group, an acylamino group, an alkoxy group, or a halogen atom; and R² and R³ each represents a hydrogen atom, a substituted or unsubstituted alkyl group having up to 20 carbon atoms, a substituted or unsubstituted aryl group, a substituted or unsubstituted allyl group, or a substituted or unsubstituted cycloalkyl group. Substituents for the alkyl, aryl, allyl or cycloalkyl group as represented by R² or R³ include an alkoxy group, an alkoxyalkoxy group, an alkoxyalkoxyalkoxy group, an allyloxy group, an aryl group, an aryloxy group, a cyano group, a hydroxyl group, and a tetrahydrofuryl group. Anions represented by Z⁻ include I⁻, Br⁻, Cl⁻, ClO₄⁻, BF₄⁻, SCN⁻, PF₆⁻, SiF₆⁻, TiF₆⁻, wherein R⁶, which may be the same or different when multiple R⁶s are present , represents a hydrogen atom, an alkyl group having up to 6 carbon atoms, a halogen atom, or a dialkyl amino group; and n represents 0 or an integer of from 1 to 3. Preferred examples of anions carrying the group R⁶ are Further preferred examples of the anion Z⁻ are The naphtholactam dyes represented by formula (I) absorbs light in the wavelength region of from 600 to 900 nm and have a molecular absorption coefficient of from 10⁴ to 10⁵ cm⁻¹. Among the naphtholactam dyes of formula (I), the preferred are those represented by formula (II): wherein X and Y each represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, or an alkoxy group; R¹ represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted allyl group; R² and R³ each represents a hydrogen atom, a substituted or unsubstituted alkyl group having up to 20 carbon atoms, a substituted or unsubstituted aryl group, a substituted or unsubstituted allyl group, or a substituted or unsubstituted cycloalkyl group; R⁴ and R⁵ each represents a hydrogen atom, a halogen atom, a cyano group, a thiocyanato group, an alkyl group having up to 10 carbon atoms, an alkoxy group having up to 10 carbon atoms, an alkylamino group, an acylamino group, an amino group, or a hydroxyl group; Z⁻ represents an anion; and m represents 1 or 2. In formula (II), substituents for the alkyl, aryl, allyl, or cycloalkyl group as represented by R² or R³ include an alkoxy group, an alkoxyalkoxy group, an allyloxy group, an aryl group, an aryloxy group, a cyano group, a hydroxyl group, a tetrahydrofurfuryl group, and a halogen atom. In the definition of the residues in formulae I and II the terms "alkyl" and "acyl", whether used alone or as part of other groups such as alkoxy, alkylamino, or acylamino, preferably refer to groups having up to 20, more preferably up to 10 carbon atoms unless otherwise stated. In a similar way the terms "cycloalkyl" and "aryl" preferably refer to groups having up to 10 carbon atoms. The term "halogen" refers to fluorine, chlorine, bromine and iodine atoms. The more preferred of the naphtholactam dyes of formula (II) are those represented by formula (III): wherein X represents a hydrogen atom or a methyl group; R¹ represents an alkyl group having up to 8 carbon atoms, and preferably up to 5 carbon atoms, an alkyl group having up to 8 carbon atoms, and preferably up to 5 carbon atoms, which is substituted with an alkoxy group, preferably the one having up to 4 carbon atoms, an allyloxy group or a hydroxyl group, or an allyl group; R² and R³ each represents an alkyl group having up to 8 carbon atoms, an alkyl group having up to 8 carbon atoms which is substituted with an alkoxy group, preferably the one having up to 4 carbon atoms, an alkoxyalkoxy group, preferably the one having up to 4 carbon atoms, an allyloxy group, a hydroxyl group or a halogen atom, or an allyl group; R⁴ represents a hydrogen atom, a halogen atom, preferably a chlorine atom or a bromine atom, or a thiocyanato group; Z⁻ represents an anion; and m represents 1 or 2. The naphtholactam dyes represented by formula (II) can easily be prepared by condensing a compound represented by formula: wherein R¹, R⁴, R⁵, and Z⁻ are as defined for formula (II), with an aromatic aldehyde represented by formula: wherein X, Y, R²,R³, and m are as defined in formula (II). The naphtholactam dyes of formula (II) can also be prepared by reacting a compound represented by formula: wherein R¹, R², R³, R⁴, R⁵, X, Y, and m are as defined above; and Z⁻ represents I⁻, Br⁻, Cl⁻, ClO₄⁻, BF₄⁻, SCN⁻, PF₆⁻, SiF₆⁻, TiF₆⁻, with a compound represented by formula: Q⁻ · X⁺ wherein Q represents and X⁻ represents a cation, such as tetraalkylammonium, in a polar solvent under heating with stirring. The optical recording medium according to the present invention essentially comprises a support and a recording layer and, if desired, may further comprise a subbing layer on the support and a protective layer on the recording layer. The support to be used may be either transparent or opaque to a laser beam used. Any of supports usually employed for this type of recording media, such as glass, plastics, paper, metal plates or foils may be used, with plastics being preferred from various respects. The plastics to be used include acrylic resins, methacrylic resins, vinyl acetate resins, vinyl chloride resins, nitrocellulose, polyethylene resins, polypropylene resins, polycarbonate resins, polyimide resins, and polysulfone resins. The recording layer of the optical recording medium of the invention has a thickness of from 10 nm (100 Å) to 5 µm, and preferably from 50 nm (500 Å) to 3 µm. The recording layer can be formed by a commonly employed thin film formation techniques, such as a vacuum deposition process, a sputtering process, a doctor blade coating process, a casting process, a spinner coating process, or a dip coating process. In the formation of the recording layer, a binder may be simultaneously used in a naphtholactam type light absorbing dyes. Usable binders include polymers, such as polyvinyl alcohol, polyvinylpyrrolidone, nitrocellulose, celloluse acetate, polyvinyl butyral, or polycarbonate. The recording layer preferably contains at least 1% by weight of the naphtholactam dye based on the polymer binder. In the case of coating the recording layer by the above-described doctor blade coating process, casting process, spinner coating process, dip coating process, and particularly spinner coating process, a solvent for coating is employed. Suitable solvents to be used include those having a boiling point of from 120° to 160°C, e.g., bromoform, dibromoethane, tetrachloroethane, ethyl cellosolve, xylene, chlorobenzene, and cyclohexanone. In the case of film formation by the spinner coating process, a rotational speed preferably ranges from 500 to 5,000 rpmin, and the spin-coated layer may be heated or treated with a solvent vapor, if necessary. For the purpose of ensuring stability or light resistance of the recording layer, the recording layer may contain, as a singlet state oxygen quencher, a transition metal chelate compound, e.g., acetylacetonato chelates, bisphenyldithiol, salicylaldehyde oxime chelates, and/or bisdithiol-α-diketone. The recording layer according to the present invention may further contain other dyes in addition to the naphtholactam dyes of formula (I), such as naphtholactam dyes other than those of the present invention, indophenol dyes, triarylmethane dyes, azo dyes, cyanine dyes, and/or squalilium dyes. The recording layer of the optical recording medium according to the present invention may be provided on either a single side or both sides of a support. Recording on the optical recording medium of the invention can be performed by irradiating the recording layer provided on one or both sides of the support with a laser beam, and preferably a semiconductor laser beam, condensed to a diameter of about 1 µm. The laser irradiation induces thermal deformation of the recording layer due to energy absorption, such as decomposition, evaporation, or melting to thereby effect recording. Reproduction of the thus recorded information can be carried out by irradiating a laser beam to read a difference in reflectance between the area where such a thermal deformation has taken place and the area where no thermal deformation has taken place. The laser beams which can be used for recording and reproduction include laser beams of N₂, He-Cd, Ar, He-Ne, ruby, semiconductors, or dyes. Of these, semiconductor laser beams are preferred in view of their lightweight, small size, and ease on handling. This invention will now be illustrated in greater detail with reference to the following examples, but it should be understood that they are not intended to limit the present invention. EXAMPLE 1 Synthesis of Naphtholactam Dye: To a mixture of 250 g of glacial acetic acid and 50 g of acetic anhydride were added 39.0 g of a compound of formula: and 19.1 g of a compound of formula: and the mixture was heated at 100 to 105°C for 4 hours with stirring. After completion of the reaction, the reaction mixture was cooled to room temperature, and poured into 1.5 liters of water containing 16.0 g of sodium perchlorate, followed by stirring at room temperature for 8 hours. The formed crystals were collected by filtration and dried to obtain 45 g of a naphtholactam dye having the following formula as a dark green crystals. A chloroform solution of this dye showed a λ max of 740 nm. Production of Optical Recording Medium: One gram of the naphtholactam dye as above prepared was dissolved in ethyl cellosolve, followed by filtration through a filter of 0.22 µm. 2 ml of thus obtained solution was dropped on a substrate of polycarbonate resin disc having a diameter of 130 mm which had been grooved to a depth of 70 nm (700 Å) and a width of 0.7 µm, and coated by a spinner at 800 rpmin, followed by drying at 60°C for 20 minutes. For film thickness measurement, a glass plate was separately coated with the coating solution under the same conditions as above, and the film thickness was measured by means of Talystep® (Rank Taylor Hobson KK) and was found to be 65 nm (650 Å). The coated film exhibited its absorption maximum at a wavelength of 790 nm and a broad peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of 1 µm was irradiated on the coated film at an output of 6 mW, clear-outlined pits having a width of about 1 µm and a pit length of about, 2 µm were formed. The carrier level/noise level ratio (C/N ratio) of the pits was 52 dB. The coating film exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLE 2 A naphtholactam dye of the formula shown below was synthesized in the same manner as described in Example 1. A chloroform solution of the dye had a λ max of 740 nm. One gram of the naphtholactam dye thus obtained was dissolved in 50 g of dibromoethane, followed by filtration through a filter of 0.22 µm. 2 ml of the resulting solution was dropped on a substrate of methyl methacrylate resin (hereinafter referred to as PMMA) disc having a diameter of 120 mm which had been grooved to a depth of 70 nm (700 Å) and a width of 0.7 µm and coated by a spinner at 1200 rpmin, followed by drying at 60°C for 10 minutes. The film thickness was measured in the same manner as in Example 1 and was found to be 70 nm (700 Å). The coating film showed its absorption maximum at 790 nm with a broad peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of about 1 µm was irradiated on the coated film at an output of 6 mW, clear-outlined pits having a width of about 1 µm and a pit length of about 2 µm were formed. The C/N ratio or the pits was 48 dB. The coating film showed satisfactory light resistance and resistance to reproducing light. EXAMPLE 3 Synthesis of Naphtholactam Dye: To 50 ml of N,N-dimethylformamide were added 6.48 g of a dye having formula: and 6.20 g of a compound of formula: and the mixture was heated at 90 to 100°C for 3 hours. After cooling, the reaction mixture was poured into 300 ml of water, and the mixture was stirred at room temperature for 1 hour. The thus precipitated crystals were collected by filtration and dried to obtain 10.20 g of dark green crystals represented by the formula shown below. A chloroform solution of the product had a λ max of 745 nm. Production of Optical Recording Medium: One gram of the naphtholactam dye as above prepared was dissolved in 50 g of tetrachloroethane, and the solution was filtered through a filter of 0.2 µm. 2 ml of the resulting solution was dropped on a substrate of PMMA disc having a diameter of 130 mm which had been grooved to a depth of 70 nm (700 Å) and a width of 0.7 µm and coated thereon by a spinner at 800 rpmin, followed by drying at 60°C for 20 minutes. The film thickness was measured in the same manner as in Example 1 and was found to be 70 nm (700 Å). The coated film exhibited its absorption maximum at 790 nm with a broad peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of 1 µm was irradiated on the coated film at an output of 6 mW, clear-outlined pits having a width of about 1 µm and a pit length of about 2 µm were formed. The C/N ratio of the pits was 52 dB. The coated film exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLES 4 TO 95 In the same manner as described in Example 1, naphtholactam dyes shown in Table 1 were synthesized. The wavelength of the absorption maximum of each of the resulting dye in its chloroform solution was as shown in Table 1. Each of the resulting dyes was coated on a substrate of grooved polycarbonate resin disc in the same manner as in Example 1. The wavelength of the absorption maximum of the coating film was as shown in Table 1. When a semiconductor laser beam having a center wavelength of 830 nm was irradiated on the coated film, clearly outlined pits were formed. The thus formed recording layer had a high reflectance, high sensitivity, and an excellent C/N ratio, and exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLES 96 TO 184 In the same manner as described in Example 3, naphtholactam dyes shown in Table 2 were synthesized. Each of the resulting naphtholactam dyes was coated on a substrate of grooved PMMA disc in the same manner as in Example 1 to form a coated film. The wavelength of the maximum absorption of the coated film was shown in Table 2. When a laser beam having a center wavelength of 830 nm was irradiated on the coated film, clear-outlined pits were formed. The coated film had a high reflectance, high sensitivity, and an excellent C/N ratio and exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLE 185 To a mixture of 250 g of glacial acetic acid and 50 g of acetic anhydride were added 40.2 g of a compound of formula: and 17.5 g of a compound of formula: and the mixture was heated at 100 to 105°C for 4 hours while stirring. After completion of the reaction, the reaction mixture was cooled to room temperature. The reaction mixture was then poured into 1.5 liters of water containing 16.0 g of sodium perchlorate, and the mixture was stirred at room temperature for 8 hours. The thus precipitated crystals were collected by filtration and dried to obtain 53.0 g of a naphtholactam dye of the formula shown below as dark green crystals. A chloroform solution of the dye had a λ max of 800 nm. One gram of the naphtholactam dye as above obtained was dissolved in 50 g of dibromoethane, followed by filtration through a filter of 0.22 µm. The resulting solution (2 ml) was coated on a substrate of grooved PMMA disc in the same manner as in Example 2 to form a coating film having a thickness of 70 nm (700 Å). The coated film had a λ max of 820 nm with a brood peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of 1 µm was irradiated on the coated film at an output of 6 mW, clearly outlined pits having a width of about 1 µm and a pit length of about 2 µm were formed. The C/N ratio of the pits was 52 dB. The coated film exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLE 186 In the same manner as described in Example 185, a naphtholactam dye of the formula shown below was synthesized. A chloroform solution of the dye had a λ max of 795 nm. One gram of the naphtholactam dye as above prepared and 1.5 g of nitrocellulose ("RS-20" produced by Daicel Chemical Industries, Ltd.) were dissolved in 50 g of ethyl cellosolve, and the solution was filtered through a filter of 0.22 µm. 3 ml of the resulting solution was dropped on a substrate of polycarbonate resin disc having a diameter of 120 mm which had been grooved to a depth of 65 nm (650 Å) and a width of 0.7 µm and coated by a spinner at 1,500 rpmin, followed by drying at 60°C for 10 minutes. The coated film has a thickness of 70 nm (700 Å) as measured in the same manner as in Example 1. The coated film exhibited maximum absorption at 810 nm of wavelength with a broad peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of 1 µm was irradiated on the coated film at an output of 6 mW, clearly outlined pits having a width of about 1 µm and a pit length of about 2 µm were formed. The thus formed recording layer had a C/N ratio of 51 dB and exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLE 187 A naphtholactam dye of the formula shown below was synthesized in the same manner as in Example 3. A chloroform solution of the dye had a λ max of 800 nm. One gram of the naphtholactam dye as above prepared was dissolved in 50 g of dibromoethane, followed by filtration through a filter of 0.22 µm. 2 ml of the resulting solution was dropped on a substrate of PMMA disc having a diameter of 120 mm which had been grooved to a depth of 70 nm (700 Å) and a width of 0.7 µm and coated by a spinner at 650 rpmin, followed by drying at 60°C for 10 minutes. The film thickness was 80 nm (800 Å) as measured in the same manner as in Example 1. The coated film had a λ max of 820 nm with a broad peak width. When a semiconductor laser beam having a center wavelength of 830 nm and a beam diameter of 1 µm was irradiated on the coated film at an output of 6 mW, clearly outlined pits having a width of about 1 µm and a pit length of about 2 µm were formed. The recording layer thus formed had a C/N ratio of 51 dB and exhibited satisfactory light resistance and resistance to reproducing light. EXAMPLES 188 TO 278 In the same manner as in Example 185, naphtholactam dyes shown in Table 3 were synthesized. The wavelength of the absorption maximum of each of the resulting dyes in its chloroform solution was as shown in Table 3. Each of the dyes was coated on a substrate of grooved PMMA disc in the same manner as in Example 185 to form a recording layer. When a semiconductor laser beam having a center wavelength of 830 nm was irradiated on the recording layer, clearly outlined pits were formed. The recording layer had a high reflectance, high sensitivity, and an excellent C/N ratio and exhibited satisfactory light resistance and resistance to reproduced light. EXAMPLES 279 TO 365 In the same manner as described in Example 187, naphtholactam dyes shown in Table 4 were synthesized. Each of the resulting naphtholactam dyes was coated on a substrate of grooved PMMA disc in the same manner as in Example 187 to form a coated film. The wavelength of the maximum absorption of the coated film was shown in Table 4. When a laser beam having a center wavelength of 830 nm was irradiated on the coated film, clear-outlined pits were formed. The coated film had a high reflectance, high sensitivity, and an excellent C/N ratio and exhibited satisfactory light resistance and resistance to reproducing light.

Claims: An optical recording medium comprising a support having provided thereon a recording layer containing a naphtholactam dye represented by formula (I): wherein K represents a substituted or unsubstituted aromatic amine residue; R represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted allyl group; Z⁻ represents an anion; ring A represents a substituted or unsubstituted naphthalene ring; and m represents 1 or 2. An optical recording medium as in claim 1, wherein said naphtholactam dye is a compound represented by formula (II): wherein X and Y each represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, or an alkoxy group; R¹ represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted allyl group; R² and R³ each represents a hydrogen atom, a substituted or unsubstituted alkyl group having up to 20 carbon atoms, a substituted or unsubstituted aryl group, a substituted or unsubstituted allyl group, or a substituted or unsubstituted cycloalkyl group; R⁴ and R⁵ each represents a hydrogen atom, a halogen atom, a cyano group, a thiocyanate group, an alkyl group having up to 10 carbon atoms, an alkoxy group having up to 10 carbon atoms, an alkylamino group, an acylamino group, an amino group, or a hydroxyl group; Z⁻ represents an anion; and m represents 1 or 2. An optical recording medium as in claim 1, wherein said naphtholactam dye is a compound represented by formula (III): wherein X represents a hydrogen atom or a methyl group; R¹ represents an alkyl group having up to 8 carbon atoms, an alkoxyalkyl group, an allyloxyalkyl group, an allyl group, or a hydroxyalkyl group; R² and R³ each represents an alkyl group having up to 8 carbon atoms, an alkoxyalkyl group, an alkoxyalkoxyalkyl group, an allyloxyalkyl group, an allyl group, a hydroxyalkyl group, or a halogenoalkyl group; R⁴ represents a hydrogen atom, a halogen atom, or a thiocyanato group; Z⁻ represents an anion; and m represents 1 or 2. An optical recording medium as in claim 1, 2 or 3, wherein the anion as represented by Z⁻ is I⁻, Br⁻, Cl⁻, ClO₄⁻, BF₄⁻, SCN⁻, PF₆⁻, SiF₆⁻, TiF₆⁻, wherein R⁶, which may be the same or different when multiple R⁶s are present, represents a hydrogen atom, an alkyl group having up to 6 carbon atoms, a halogen atom, or a dialkyl amino group; and n represents 0 or an integer of from 1 to 3. An optical recording medium as in claim 3, wherein R¹ is an alkyl group having up to 5 carbon atoms, an alkyl group having up to 5 carbon atoms which is substituted with an alkoxy group having up to 4 carbon atoms, an allyloxy group, or a hydroxyl group, or an allyl group. An optical recording medium as in claim 3, wherein R² and R³ each is an alkyl group having up to 8 carbon atoms, an alkyl group having up to 8 carbon atoms which is substituted with an alkoxy group having up to 4 carbon atoms, an alkoxyalkoxy group having up to 4 carbon atoms, an allyloxy group, a hydroxyl group, or a halogen atom, or an allyl group. An optical recording material as in claim 3, wherein R⁴ is a hydrogen atom, a chlorine atom, a bromine atom, or a thiocyanato group. An optical recording medium as in claim 1, 2 or 3, wherein Z⁻ is I⁻, Br⁻, Cl⁻, ClO₄⁻, BF₄⁻, SCN⁻, PF₆⁻, SiF₆⁻ or TiF₆⁻. An optical recording medium as in claim 1, 2 or 3, wherein Z⁻ is wherein R⁶ is a hydrogen atom, or an alkyl group having up to 4 carbon atoms. An optical recording medium as in claim 1, 2 or 3, wherein Z⁻ is wherein R⁶, which may be the same or different when multiple R⁶s are present, represents a hydrogen atom, an alkyl group having up to 4 carbon atoms, a chlorine atom, or a dialkyl amino group having up to 4 carbon atoms; and n represents 0 or an integer of from 1 to 3. An optical recording medium as in claim 10, wherein Z⁻ is

Inventors: KUROSE, YUTAKA, MAEDA, SHUICHI, OZAWA, TETSUO
Applicants: MITSUBISHI KASEI CORPORATION
Application year: 1986
Main classification: G11B7
IPC codes: G11B7, C09B23