INSULATED WIRES

Abstract: An insulated wire with greatly impoved scrape abrasion re­ sistance is distinguished by a flexible thermoplastic PVC com­ position containing an impact modifying agent such as styrene/­ butadiene/acrylonitrile terpolymer or styrene/butadiene/meth­ acrylate terpolymer.

Description: INSULATED WIRES This invention relates to insulated wires suitable for use in internal wiring of electrical and electronic. equipment, motor vehicles, conduit installations in buildings and for other purposes. Thermoplastic compositions based on flexible PVC (by which is meant homopolymers and/or copolymers of vinyl chloride compounded with at least one plasticiser) are widely used for the insulation of such wires and give excellent service in most applications. For some applications, however, superior abrasion resistance is required, and in such cases crosslinked PVC compounds or other relatively expensive materials have been specified, or a greater insulation thickness or reduced flexibility reluctantly accepted. The present invention provides wires insulated with flexible PVC that have improved abrasion resistance without crosslinking and may in some cases meet scrape abrasion specification requirements applicable to crosslinked PVC-insulated wires. In accordance with the invention, an electric wire is insulated with a thermoplastic flexible PVC comprising: at least one homopolymer or copolymer of vinyl chloride; at least one plasticiser therefor; and at least one additive selected from the class of impact modifying agents in an amount effective to raise substantially the number of scrapes to failure when the wire is subjected to a scrape abrasion test. Impa-ct modifying agents are well-known and widely used in 'rigid' PVC composition (i.e. compositions with no, or very little, plasticiser) in which they reduce the tendency to shatter on impact and it has been suggeste2'that they might also be added to flexible PVC compositions. The best known and preferrred impact modifying agents are ternary copolymers of styrene, butadiene and either acrylonitrile or methacrylate, suitable materials being sold by Borg-Warner Limited under the designation Blendex. These preferred impact modifying agents are effective in amounts ranging from about 2 to about 10% by weight of the entire flexible PVC composition. A preferred range is 4-7%. The plasticiser or plasticisers may be selected from dialkyl phthalates, trialkyl trimellitates, phosphate plasticisers, polymeric plasticisers and other known classes; conventional amounts can be used. The flexible PVC composition may also include fillers (e.g. clay, calcium carbonate), pigments, lubricants (e.g. calcium stearate, paraffin wax), stabilisers (e.g. lead phthalate), flame retardants (e.g. antimony trioxide alone or mixed with zinc borate). EXAMPLE 1: A flexible equipment wire of nominal cross-section 0.5 mm2, made up of 7 fine round wires is insulated to a radial thickness of 0.3 mm with a flexible PVC composition as follows: p h r weight% PVC homopolymer: 100 58.6 (K-value 69-71) plasticiser: Triallyl trimellitate (Bisoflex TL79T) 33.5 19.6 impact modifying agent: styrene/butadi ene/ acrylonitr il e copolymer (Blendex 310S) 11 6-.45 filler: clay (Polestar 501) 5.51 3.2 lubricants: calcium stearate paste 1 0.6 paraffin wax 0.5 0.3 stabiliser: lead phthalate (Dythal paste) 13.5 7.9 flame retardant: antimony trioxide (Timonox) 5.51 3.2 EXAMPLE 2: This was similar to Example 1 except that the flexible PVC composition had the formulation: p h r weight PVC homopolymer: 100 57.1 (K-value 69-71) plasticiser: a polymeric adipate (Diolpate 195) 37.8 21.6 impact modifying agent: styrene/butadienel acrylonitrile copolymer (Blendex 310S) 11.11 6.35 filler: clay (Polestar 501) 5.56 3.18 lubricants: calcium stearate paste 1.11 0.63 paraffin wax 0.56 0.32 stabiliser: lead phthalate (Dythal paste) 13.33 7.62 flame retardant: antimony trioxide (Timonox) 5.56 3.18 When tested for resistance to scrape abrasion in accordance with British Standard BSG 212 except that the loading was increased to 7N, a measurement of about 360 double strokes was obtained in each of the Examples. This should be compared with a requirement for 300 double strokes for an equivalent crosslinked PVC insulated wire of this size.

Claims: CLAIMS 1. An electric wire insulated with a thermoplastic flexible PVC comprising: at least one homopolymer or copolymer of vinyl chloride; at least one plasticiser therefor; and at least one additive characterised in that the additive is selected from the class of impact modifying agent and is present in an amount effective to raise substantially the number of scrapes to failure when the wire is subjected to a scrape abrasion test. 2. A wire as claimed in Claim 1 in which the impact modifying agent is a ternary copolymer of styrene, butadiene and acrylonitrile. 3. A wire as claimed in Claim 1 in which the impact modifying agent is a ternary copolymer of styrene, butadiene and a methacrylate. 4. A wire as claimed in Claim 2 or Claim 3 in which the flexible PVC composition contains about 2 to about 10% by weight of the impact modifying agent. 5. A wire as claimed in Claim 2 or Claim 3 in which the flexible PVC composition contains about 4 to about 7% by weight of the impact modifying agent.

Inventors: SAWYER, DUDLEY NOEL
Applicants: BICC PUBLIC LIMITED COMPANY
Application year: 1985
Main classification: H01B3
IPC codes: C08L27, H01B3, C08L55, C08L51, C08L21