OPTICAL FILTER MADE OF INORGANIC MATERIAL FOR GREEN LIGHT

Abstract: An optical filter made of inorganic material for green light which transfers green light and absorbs all of the other colored lights can be realized by sticking an inorganic mix­ ture powder pasted by mixing with screen oil on a glass substrate and firing it, which mixture includes oxides of co­ balt and either of chrome and a combination of aluminum and chrome. The contrast of picture displayed on a display device can be extremely increased by reducing the reflec­ tion of incident ambient light without the reduction of bright­ ness on account of the application of the above optical filter onto the displaying screen.

Description: The present invention relates to an optical filter based on inorganic materials for green light, for use in combination with a display device consisting of a combination of plural kinds of displaying elements emitting different coloured lights respectively, and in particular to such an optical filter having high contrast based on antireflection with low reflectance of ambient light. Generally, it is required for various kinds of display devices, for instance, a cathode ray tube, a gas-discharge display panel and a low-velocity electron-beam fluorescent display panel, to increase not only the brightness but also the contrast of the display by lowering the reflectance of the display surface. Once the required level of brightness of the display has been obtained, it is occasionally possible to improve the quality of the display by increasing the contrast thereof. In order to lower the reflectance of the display surface in order to increase its contrast, the following various measures have been conventionally adopted. (i) A neutral density (ND) filter of absorbing type is adhered or combined to a surface of the display screen which is made of glass plate and the like. (ii) The light absorption of the display screen at a region thereof, at which the radiation spectral intensity of fluorescent material forming the display element is low, is increased by incorporating a rare earth compound, for instance, Nd₂0₃ into a material, for instance, glass forming a component of the display screen. (iii) The light absorption of the display screen is increased at the light wavelength which is unavailable for the display radiation region by mixing a pigment into the fluorescent material forming the display element. (iv) The absorption of ambient light is increased by adhering a black material on portions of the display element which consist of other than the fluorescent material. (v) Granular pigments adhered on the fluorescent material are employed as a filter. However, the above conventional measures for increasing the contrast have the following respective defects. The increase of contrast according to the application of the ND filter as mentioned in Item (i) is accompanied by decreased brightness. Although the result obtained by adding the rare earth element into glass described in Item (ii) is more favourable than the result obtained in Item (i), the luminous reflectance is not decreased, due to the high light transmittance of the added material around the wavelength of 555 mm. The mixing of the pigment into the fluorescent material as mentioned in Item (iii) is effective for a CRT display device having a very bright display. However, the use of such a pigment with other types of display devices which cannot afford to lose any brightness of display is difficult. Additionally the reduction in the defree of reflectance thereof seems to be no more than one half at most in practice. The sticking of black absorbing material on portions of the display not used to emit light as mentioned in Item (iv) is effective for all of the above display devices. However, this measure is only applicable as a subsidiary one. The sticking of granular pigments onto the fluorescent material to act as a filter is not useful in practice. This is because the edges of the granular particles increase reflection because of their tendency to scatter light. In addition, even a small gap between the front glass and the filter layer causes the reflection of light at the boundary thereof and hence results in the reduction of the contrast. U.S. 4 420 501 discloses the manufacture of a coloured screen comprising a glass sheet coated with a coloured layer. The screen is manufactured by applying a paint containing a mixture of amongst other ingredients Cr₂0₃ and Co0 and powdered glass frits to a glass sheet. The mixture is then fired at a temperature which reaches a maximum of 780 o C in order to fuse the frits together to produce the finished screen. Chemical Abstracts, Vol. 98, No. 12, ref. No. 94503q discloses a glass filter for improving the contrast in the range of 1.5-5. The filter is produced by adding inter alia Cr₂0₃ to a glass including inter alia Co0. U.S. 4 288 250 discloses a green filter glass for contrast enhancement in a CRT display device. The filter includes inter alia Cr₂0₃. However, there is no disclosure of using Co0 despite twenty or so possible other constituents being listed, and the filter is in the form of a unitary glass structure, without layers. Japanese Patent Laid-open Publication No. 59-36,280 discloses a colour display device employing an optical filter made of inorganic material which effectively increases the contrast of the display device, particularly a colour picture display device, by removing the above described conventional defects and hence by suppressing the reduction of the brightness of display. The display device is formed from a combination of plural kinds of respectively different displaying elements. The contrast of the picture, which consists of coloured lights emitted by the displaying elements is increased almost four fold by employing an optical filter formed of substantially transparent inorganic glass through which the coloured lights are transmitted, in comparison with the contrast obtained without the optical filter, that is, the combination of three coloured filters of red, green and blue. Further, the use of the filters causes the brightness to be reduced by about 20%. An object of the present invention is to provide an optical filter made of inorganic material for green light which improves upon the performance of the optical filter described in Japanese Patent Laid-open Publication No. 59-36,280 by detailed investigation of inorganic materials and in depth product analysis. The investigations and trials have shown that certain inorganic materials, particularly if used in certain favourable ranges of composition ratios can be adopted not only for the conventional improvement of the contrast but also for increasing the colour saturation and further the colouring of substantially uncoloured radiation and hence, for instance, for the favourable application onto the high definition television gas-discharge display device. According to a first aspect, the present invention provides an optical filter based on inorganic materials for green light, comprising: a glass substrate, and a filter layer attached to said glass substrate, characterised in that the optical filter is produced by the steps of adhering a layer comprising glass powder meltable and becoming transparent at a temperature below 700 o C, cobalt oxide and chromic oxide to the glass substrate and firing at a temperature of 450 o C to below 700 o C. According to a second aspect, the present invention provides an optical filter based on inorganic materials for green light, comprising: a glass substrate, and a filter layer attached to said glass substrate, characterized in that the optical filter is produced by the steps of adhering a layer comprising glass powder meltable and becoming transparent at a temperature below 700 o C, potassium chromate or potassium dichromate, and a blue pigment having a spinel structure and formed of cobalt oxide and aluminium oxide to the glass substrate and firing at a temperature of 450 o C to below 700 o C. In the drawings: Figures 1 to 3 are graphs showing the characteristic curves of the transmittances of the optical filters for green, blue and red light according to the present invention respectively in comparison with other relevant characteristic curves; Figures 4(a) and 4(b) are a cross-section and a plan showing a gas-discharge display panel incorporating the optical filter of the present inventiton; Figure 5 is a diagram showing an idealised relation between the radiation spectrums of fluorescent materials used for the gas-discharge colour display panel and spectral transmittance characteristics of the respective primary colour filters according to the present invention; and Figures 6(a) and 6(b) are diagrams showing examples of the fixed display applied with the optical filters of the present invention respectively. In Figures 4 and 5, FG is a front glass plate, RG is a rear glass plate, CS is a cell sheet, Ph is a fluorescent material, DA is a display anode, C is a cathode, UV is ultravoilet radiation, RF is a filter for red light, GF is a filter for green light, BF is a filter for blue light, BM is a black matrix, RC is a cell for red light, GC is a cell for green light and BC is a cell for blue light. In Figure 1, the characteristic curve (G N ) of the transmission factor (τ) of the optical filter for green light according to the present invention is shown in comparison with the spectrum characteristics (G) and the visual sensitivity characteristic curve ( y ) of the display device to which the present invention may be applied and the transmission factor characteristic curve (G o ) of the optical filter for green light as described in Japanese Patent Laid-open Publication No. 59-36,280. As shown in Figure 1, the transmission factor is favourably improved in the desired region of the spectrum characteristics (G) of the fluorescent material for green light, whilst the transmission factor is decreased in other regions. As a result the contrast ratio for green light is improved by about one and a half times in comparison with that as attained in the above Japanese Patent Laid-open Publication. The process for manufacturing the optical filter according to the present invention and technical matters including the transparent glass material powder to be mixed with the colouring constituents of the layer, screen oils, filter materials and others required for the above manufacturing process will now be described. (I) Outline of the manufacture of the optical filter: The following is an example of the colouring constituents mixed with the coloured glass powder which is glazed onto a glass substrate at a temperature below 700 o C, so as to obtain a transparent green coloured glass. chromic oxide (Cr₂O₃) 0.5 to 6 parts by weight cobalt oxide (CoO) 0.5 to 6 parts by weight copper oxide (CuO) 0 to 6 parts by weight The layer comprising the above colouring constituents and a transparent glass powder is adhered to the surface of a glass substrate and fired at a temperature of from 450 o to 650 o C, so as to obtain the desired optical filter. The glass substrate need not be flat. As another example of the layer mixture powder to be coloured in transparent green, a mixture of 1 to 40% by weight of a blue pigment which has spinel structure comprising cobalt oxide (CoO) and aluminum oxide (Al₂O₃), 54-98.5% by weight of the transparent glass powder, and 0.5 to 6% by weight of potassium chromate or potassium dichromate (K₂Cr₂O₇) as a colouring constituent is treated similarly as described above. As still another example of the glass mixture powder to be coloured in transparent green, a mixture of 1 to 20% by weight of a green pitment comprising cobalt oxide (Co0), chromic oxide (Cr₂0₃) and aluminum oxide (Al₂0₃), 74 to 99% by weight of the transparent glass powder, and 0 to 6% by weight of copper oxide (Cu0) is treated similarly as described above. (II) Transparent glass powder material: Any desired glass material can be employed as the transparent glass powder material, so long as it can be glazed onto the glass substrate at a temperature of below 700 o C, preferably below 600 o C, as a transparent glass layer for instance, the following descent of Pb0-Si0₂-B₂0₃-Zn0 can be employed. powdered silica 10.0 parts by weight red lead 64.4 parts by weight boric acid 30.2 parts by weight zinc oxide 3.0 parts by weight aluminium hydroxide 3.0 parts by weight potassium carbonate 3.3 parts by weight In addition, the other descents of Pb0-Si0₂-B₂0₃, Pb0-B₂0₃-Zn0, Bi₂0₃-Si0₂-B₂0₃ and lead-free glass containing no Pb0 and Bi₂0₃ can be employed also. Moreover, any other glass material containing at least one compound of R₂0 (R=Li, Na, K), Ba0, Ca0, Mg0, NaF, Ti0₂, Zr0₂, Al₂0₃ and P₂0₅ can also be employed. (III) Examples of screen oil: The following composition can be exemplified for the required screen oil. diethylene glycol monobutyl ether acetate 85 parts by weight terpineol 10 parts by weight ethylcellulose 4 parts by weight acrylic resin 1 part by weight In this connection, the ratio by weight between the above described glass powder material and screen oil can be favorably selected in a range of 2.5 to 5 parts to 1 part by weight. (IV) The method for sticking the filter materials: Screen printing is effected through screens of 100 to 400 mesh in response to the fineness of the pattern to be printed. In this connection, the black matrix and the like can be printed and fired together with the pattern to be printed. The above described various kinds of transparent glass pastes are uniformly applied onto glass substrates and then dried at a temperature of about 150°C or half-fired at a temperature of about 300 o C. Thereafter, the conventional positive or negative photoresist for removing the oxidized film is applied thereon and after the photomask is applied on the portions thereof to be removed or to be left through the etching, the exposure is effected thereon, and then, after the development, unnecessary portions thereof are removed by the etching liquid, for instance, of hydrofluoric acid descent. This etching process is repeated, if necessary, with regard to required plural colors. In this connection, it is also possible that the above described transparent glass paste consisting of glass powder material, after being mixed with photosensitive photoresist, is applied on the glass substrate, and then, after drying, the glass substrate applied with the glass paste is etched by the resist-developing liquid. As for the material of the photosensitive photoresist used for the etching procedure, various kinds of photoresists which are customarily employed for the production of semiconductor devices, other than polyvinyl alcohol and ammonium dichromate, which are usually adopted for the manufacture of conventional cathode ray tubes, can be employed. Similarly, as already employed for the application of fluorescent materials, some of chemicals present the selective adhesiveness in response to desired patterns under the application and the exposure. In the situation where the above described glass powder for the optical filter is applied on the patterns presented by these chemicals, the required patterns of glass powder adhering to the glass substrate can be readily obtained. So that, after the subsequent fixing and the removal of impurities, the required optical filter can be realized by firing. Next, various embodiments of the application of the optical filter according to the present invention will be individually described with regard to the respective operations and effects thereof hereinafter by referring to the accompanying drawings. Particularly with regard to the color display device necessitating the common application of those optical filters for red, green and blue lights, the operation and the effect of the common application of these three kinds of the optical filters according to the present application will be described by referring to Fig. 1 showing the performance of the optical filter for green light together with Figs. 2 and 3 showing those for blue and red lights respectively. First, with regard to a gas discharge display panel applied with these three kinds of optical filters, the cross-section thereof is shown in Fig. 4(a) and the plan thereof is shown in Fig. 4(b). In the structure of the matrix type gas discharge display panel as shown in Figs. 4(a) and 4(b), a cell sheet CS is sandwiched between a front glass plate FG and a rear glass plate RG. In the cell sheet SC, plural spaces provided for individually forming discharge cells are arranged in matrix, and fluorescent materials Ph are applied on inner walls of these spaces for discharge cells, meanwhile display anodes DA and cathodes C are provided on tops and bottoms of these spaces respectively. Gas discharges are individually generated in these cell spaces between the display anodes DA and the cathodes C and hence the fluorescent materials Ph are excited and radiated by the ultraviolet rays UV emitted by these gas discharges. The fluorescent materials Ph are separately applied for respectively radiating in red (R), green (G) and blue (B). So that, respective discharge cells are separately called as R cells, G cells and B cells. In the gas discharge display panel according to the present invention, each of R cells, G cells and B cells arranged similarly as in the conventional panel are individually covered by respective filters RF, GF and BF provided for selectively respective colored lights on the rear surface of the front glass plate FG. Each of these respective color filters RF, GF and BF are formed of inorganic glass materials which can endure the high temperature heat treatment of the sealing process with frit glass of the panel glass plate which are heated for one hour at the adhering temperature of 430 o C. These color filters can be formed, for instance, by printing the aforesaid glass paste on the rear surface of the front glass plate FG. The color filters added onto the displaying side of the display element of the gas discharge display device according to the present invention as described above make the respective colored lights emit from those display elements without loss, as well as prevent the disturbing colored lights, which have the wavelengths residing outside the same range as the desired colored lights emitted from the respective display elements and included in the ambient light incident upon the respective display elements, from reflecting by absorbing these disturbing colored lights. Thus, these color filters are necessarily formed to absorb all of disturbing lights other than the transferring colored lights. In addition, these color filters should be made transparent, since the ambient light incident upon these filters should not be reflected and scattered therefrom. In the situation where these color filters having the respective performances as described above are arranged over all of the respective display elements the colored lights emitted from the discharge cells forming respective display elements, for instance, the green light emitted from the G cell can be derived from the display panel through the respective color filter, for instance, through the green filter GF substantially without any loss. Further, the G component of the incident ambient light passes through the green filter GF and is reflected from the white fluorescent materials inside the discharge cell and again passes through the green filter, and hence derived also from the display surface. However, the B and the R components of the incident ambient light are, even if reflected by the white fluorescent materials Ph inside the G cells, absorbed twice through the green filters GF, and, as a result, extremely attenuated with the evident level difference from the green lights emitted from the G cells. Consequently, even though the ambient light is incident upon the display surface, the high contrast display can be attained. This situation of display is just the same with regard to the B cell covered by B filter and the R cell covered by R filter. In this connection, in the embodiment as shown in Figs. 4(a) and 4(b), the black lattice consisting of black absorbing material, that is, so-called black matrix BM is provided between each discharge cells, so as to lower the reflectance outside the range of radiation from the display surface unconditionally and hence to further increase the high contrast based on the effect of the color filter accompanying with each discharge cells. Next, examples of relative radiation spectrum of fluorescent materials Ph applied onto each discharge cell RC, GC and BC composed as mentioned above and the transmittance τ of each of the colour filters RF, GF and BF are shown in Figs. 3, 1 and 2 respectively. In these examples as shown in these drawings, each one of the primary colored radiation components are taken out approximately with the transmittance of 80%, meanwhile the reflected components other than primary color components of the incident ambient light are attenuated substantially to the zero level. As a result, in the situation where the numbers of each one of the discharge cells RC, GC and BC are the same with each other, the overall luminous reflectance of the exemplified display device is lowered below 0.8²×1/3, that is, about 10%. The idealized curves of the performances as shown in Figs. 1 to 3 are shown in Fig. 5, although the practical performances are far from these idealized curves. The practical performances obtained from the present embodiment are shown in Figs. 1 to 3 in comparison with those obtained from the aforesaid previously disclosed color filters. Similar data of these performances obtained on various conditions of the cell structure including that mentioned above are indicated in Table 1. As is apparent from Table 1, the decrease of brightness in the situation where the discharge cell is accompanied with the color filter is slight, while the contrast is increased by six times of that obtained without the accompanied color filter and by more than four times that obtained with the gray filter having no color selectivity. In addition, as is apparent from Figs. 1 to 3, the above various performances obtained according to the present invention are further favorable and available for the monochromatic display device, which is arranged such as, in the structure as shown in Figs. 4(a) and 4(b), only one kind of fluorescent material and color filter are employed, or, otherwise the direct radiation of gas discharge is available without any fluorescent material. As for well known examples of the discharge gas the radiation of which is directly available for display, neon for reddish orange, krypton for green and argon for blue can be exemplified. In this situation, it is necessary to somewhat increase the density of those color filters. This increase of density can be attained by raising the temperature or increasing the film thickness. Further speaking in detail about the above mentioned embodiment, the color filters made of transparent inorganic material according to the present invention are arranged to entirely cover all of the discharge cells by being sticked on the rear surface of the front glass plate as shown in Figs. 4(a) and 4(b). In this situation as shown in those drawings, the display electrodes are arranged on the primary color filters RF, GF and BF sticked on the rear surface of the front glass plate FG by being deposited thereon in the manner such as well known. That is, good conductor metallic materials, for instance, Ni, Au, Ag, Cu, Cu-Aℓ, Cr-Cu-Cr are deposited thereon by spattering, ion-plating, plating and the like, and further, if necessary, are applied with the etching for forming those electrodes together with lead conductors similarly customarily performed. When those electrode materials formed as described above are fired, it is feared that the metallic materials of those electrodes deposited on the color filters are diffused into the materials forming those filters and hence the performances of those color filters are deteriorated. So that, it is preferable that a diffusion preventing layer is deposited between those materials or that metallic materials which can be fired at a possibly low temperature are selectively employed for those electrodes. As for the etching effected for forming those electrodes in the situation where those color filters are made of materials readily affected by the etching, it is required that those filter materials be protected by being covered with any transparent layer for obstructing the etching liquid, which layer can be preferably formed of dielectric materials, for instance, CaF₂ and Ta₂O₅ , customarily used for providing the color separating filter deposited inside the face plate of the single tube type color television camera tube. In this connection, it is a matter of course that the above exemplified gas discharge display panel can be made similar as conventionally well known, except for that mentioned above. Next, examples of a display device other than gas discharge display panels, for instance, the cathode ray tube to be applied with the present invention will be described hereinafter. As for arranging the aforesaid primary color filters inside the face plate of the cathode ray tube, particularly the color cathode ray tube according to the present invention, it is favorable to provide the filter materials thereon by coating and etching processes similar as effected for arranging fluorescent material dots thereon, since it is difficult to arrange those filters only by the aforesaid printing process on the basis of the fact that the face plate of the cathode ray tube is not flat similarly as described above and that the pitch of the arranged fluorescent material dots is distinctly smaller than that of discharge cells in the above described gas-discharge display panel. Accordingly, the aforesaid colored glass material for the primary color filter is uniformly coated into a thin layer overall of inner surface of the face plate, and, after drying or half firing, the photoresist is deposited overall of this thin layer of glass material. Thereafter, just similarly as for forming the fluorescent dots, those layers are exposed by the light source disposed at the deflection center of the electron beams through the shadow mask, and then the etching is applied, so as to leave the colored glass material only on the positions to be arranged with the primary color filters. These processes of coating and etching of the colored glass materials are repeated with regard to respective primary colors, and further as for the black matrix, the similar process as for forming the fluorescent layer is carried out, and then the firing thereof is performed. Thereafter, the conventional process for forming the fluorescent layers, and, as a result, the situation where the absorbing type color filters made of transparent inorganic material for transferring respective primary color lights are arranged overall of respective primary color fluorescent dots can be obtained. Next, an example of low velocity electron beam type fluorescent display panel applied with the present invention will be described hereinafter. In the application of the present invention onto the display panel of this type, similarly as in the aforesaid gas-discharge display panel, first the colored glass filters having the desired shapes are sticked on the front glass plate, and then the transparent electrode layers are deposited thereon and further, the fluorescent layers having the desired shapes provided for the excitation of the low velocity electron beam are deposited thereon. Behind the front glass plate arranged as described above, the grid electrodes, the electron beam generator and the like are provided similarly as in the conventional panel of this type. The present invention can be widely applied also onto the display devices of various types other than those described above, including the flat face type cathode ray tube display device, the letter and figure display device and the like, in which device a plurality of light-emitting or light-controlling elements, for instance, so-called EL, namely, electro-luminescent elements, light-emitting diodes, liquid crystal display device are arranged in matrix or in segments with regard to plural color tones, with the similar operational effects as described above. As described above in detail, in the monochromatic display device, the absorbing type color filter made of transparent inorganic material according to the present invention is uniformly or selectively applied with regard to a single color on the front or the rear surface of the front glass plate, meanwhile, in the multicolor display device, these color filters are arranged separately for respective colors overall of front sides of display elements, so as to transfer all of colored lights emitted from the multicolor display device substantially without any transmission loss and to absorb all of unnecessary components of the incident ambient light with the extremely increased high contrast. However, the conventional method for preventing the reflection of the ambient light as described earlier can be adopted in common in the manner as described as follows, with the extremely distinct effect for the increase of contrast. Similarly as in the conventional color cathode ray tube display device, to the front glass plate of the display device applied with the composition of the present invention is rear earth elements, for instance, Nd₂O₃, so as to facilitate the further increase of operational effect obtained by the color filter according to the present invention. In addition, in the situation where the present invention is applied onto the color cathode ray tube display device, when the pigment is mixed into the fluorescent materials employed therefor, so as to absorb colored lights in the range other than that to be displayed, the operational effect of the color filter according to the present invention can be further increased. On the other hand, the average reflectance of each one of the display elements can be reduced to 10% or less so that a reflectance of about 5% on the surface of the front glass plate becomes extremely significant in comparison with the conventional display device. Accordingly, the front surface of the front glass plate of the display device applied with the composition of the present invention can be applied with the low reflection coating with remarkable effect. The low reflection coating applied on the color glass filter reduces the reflection therefrom, so that the output radiation therefrom indicates a little increase. In this connection, this low reflection coating can be effected in the last stage of the manufacturing process of the display device according to the present invention. However, it is preferable that, in the step wherein the process for manufacturing the front glass plate is finished by fixing the color filters of the present invention to the display anodes and others on the rear surface thereof, this low reflection coating is applied on the front surface thereof. In this situation, the coating material is affected by the heating procedure at about 430°C included in the frit glass treating process for sealing the front and the rear glass plates with each other, so that it is preferable also to employ a heat-resisting coating material which can endure the high temperature as described above. The optical filter according to the present invention can be utilized for color filters to be arranged in front of the display device, as well as for the display of figures and the like on a glass plate, various kinds of shades, various kinds of decorations and others and further for various kinds of optical devices. A picture having monochromatic half tone can be reproduced by superposing a picture printed with black glass paste upon the monochromatic filter according to the present invention. The color filter of the present invention can be applied for displaying a fixed picture as well as for a stained glass like use. A combination of tri-primary color filters available of the above use will be exemplified as follows. Plural rows of minute color filters having comparatively small areas are arranged as shown in Fig. 6(a), so as to present the half tone by controlling the transmittance or the reflectances of those minute color filters. As for the source of the picture to be displayed, a video signal used, for instance, for television broadcasting is adopted, which signal is stored in a frame memory. The video signal derived from the frame memory at an appropriate speed is applied for preparing an original manuscript and further a screen. In this step, the video signal has been sampled in response to the color arrangement as shown in Fig. 6(a), with the derivatives in response to the densities to be presented through the screen. These densities, that is, the deviations are controlled, for instance, by the area occupied with the black glass paste, as shown in Fig. 6(b). In the situation where the fixed picture reproduced through the above screen is viewed with the light passing therethrough, the saturation of the color of the color glass filter is increased. Meanwhile, in the situation where this fixed picture is viewed with the light reflected therefrom, the above saturation is decreased through the diffusing plane having a high reflectance, which is disposed on the filters and otherwise can be sticked upon the glass substrate. In this connection, it is possible also that the black glass paste as shown in Fig. 6(b) is printed directly or through the diffusing plane on the glass substrate and fired and thereafter combined with the color filters, so as to facilitate the display of colored picture, which can be changed by changing the picture drawn with the black glass paste only. The poster consisting of this colored picture based on the combination of the color filter and the monochromatic picture may be permanently preserved and hence applicable for the high grade of fine arts and further valuable for a commercial display on its basis of durability against the ultraviolet rays, high temperature and high humidity. As is apparent from the above description, the optical filter made of inorganic material according to the present invention can substantially reduce the reflectance of the display surface of various kinds of color display devices by the application thereof, substantially without decrease of the display brightness. So that, it is possible to substantially increase the contrast of displayed picture thereon in comparison with that in the conventional device by preventing the reflection of incident ambient light, and otherwise to reduce the load of the display device by lowering the display brightness in the situation where the required contrast is maintained. Accordingly, even when the radiation efficiency of the display device is not so high, it is possible to obtain the excellent picture display with high contrast as well as to lower the sensitivity of the flicker interference by facilitating the low brightness display. As a result, the low field speed scanning of a displayed picture can be realised. Particularly in the situation where the composition of the present invention is applied onto a gas discharge display panel, the disturbing components of the radiation other than the required color components thereof can be absorbed and removed through the color filters according to the present invention, even if the radiation from the filler gas can be directly viewed, so that a decrease of the color purity in the displayed picture can be obviated. As a result, it is beneficial to employ gases for instance, Ne, which cannot be employed for the gas discharge because of the direct view of the radiation therefrom, although the high brightness radiation can be obtained therefrom. In this connection, the constituents of the color filters according to the present invention consist only of inorganic materials at least in the situation where these filters are practically used. So that, the deterioration of performances which is caused by the light exposure, and further the impurities including the undesired gases are scarcely generated, even in the situation where those materials are sealed in the gaseous space of the gas discharge display panel. Consequently, according to the present invention, it is possible to obtain various evident effects such that the life of the gas discharge display panel is not inferiorly affected at all.

Claims: An optical filter based on inorganic materials for green light, comprising: a glass substrate, and a filter layer attached to said glass substrate, characterised in that the optical filter is produced by the steps of adhering a layer comprising glass powder meltable and becoming transparent at a temperature below 700 o C, cobalt oxide and chromic oxide to the glass substrate and firing at a temperature of 450 o C to below 700 o C. An optical filter based on inorganic materials for green light, comprising: a glass substrate, and a filter layer attached to said glass substrate, characterized in that the optical filter is produced by the steps of adhering a layer comprising glass powder meltable and becoming transparent at a temperature below 700 o C, potassium chromate or potassium dichromate, and a blue pigment having a spinel structure and formed of cobalt oxide and aluminium oxide to the glass substrate and firing at a temperature of 450 o C to below 700 o C. An optical filter according to claim 1, wherein said layer comprises: 0.5-6 parts by weight of chromic oxide, 0.5-6 parts by weight of cobalt oxide, and 0-6 parts by weight of copper oxide. An optical filter according to claim 1, wherein said layer consists of: 1-20% by weight of a green pigment comprising cobalt oxide, chromic oxide and aluminium oxide, 74-99% by weight of the glass powder, and 0-6% by weight of copper oxide. An optical filter according to claim 2, wherein said layer consists of: 1-40% by weight of a blue pigment having a spinel structure and formed of cobalt oxide and aluminum oxide, 54-98.5% by weight of the glass powder, and 0.5-6% by weight of potassium chromate or potassium dichromate. An optical filter according to any preceding claim wherein said layer is fired at a temperature of 450 o C-650 o C.

Inventors: KITAMURA, NARITOSHI OKUNO CHEMICAL IND. CO., LTD., MORITSU, YUKIKAZU OKUNO CHEMICAL IND. CO., LTD., SAKAI, TETSUO, WADA, MASATOSHI OKUNO CHEMICAL IND. CO., LTD.
Applicants: NIPPON HOSO KYOKAI, OKUNO CHEMICAL INDUSTRIES CO., LTD.
Application year: 1985
Main classification: C03C17
IPC codes: G02B5, H01J11, C03C3, C03C14, H01J9, C03C4, H01J17, C03C17, H01J29, H01J5, G09F9, C03C8