NON-PRIMARY EXPLOSIVE DETONATOR AND INITIATING ELEMENT THEREFOR

Abstract: Non-primary explosive detonator comprising a hollow tube (1) with a closed end having a chamber containing a secondary explosive base charge (8), an opposite open end provided with or for the insertion of an igniting means (9, 15, 16), and an intermediate confinement adjacent said chamber and containing an initiating charge (7), a delay composition (6) optionally being present adjacent said initiating charge. The characteristic feature of the detonator is that the confinement contains a secondary explosive initiating charge (7), by which the current drawbacks in connection with primary explosive initiating charges are reduced, and that it is thin-walled and in the end towards said chamber is open or provided with a thin wall or an aperture (5) or a recess therefore, to accelerate the burning of said secondary explosive initiating charge to a shock wave that causes detonation of said secondary explosive base charge, and a hole (4) which permits ignition of said secondary explosive initiating charge via the igniting means (9). By the special design of the confinement the detonator is very versatile as compared to previously known non-primary explosive detonators. The invention also relates to a separate initiating element having the structure disclosed above for the confinement.

Description: Non-primary explosive detonator and initiating element therefor. Technical Field The*present invention relates to a detonator for use as an explosive device or for.setting off other explosives and mor specifically to a detonator of the non-primary explosive type. Furthermore, the detonator according to the present invention is of the type that comprises a hollow tube with a closed end having a chamber containing a secondary explo¬ sive base charge, an opposite open end provided with or for the insertion of an igniting means, and an intermediate confinement adjacent said chamber and containing an explo¬ sive charge for the initiation of a detonation of the secondary explosive base charge via said igniting means and optionally also via a delay composition. The novel and characteristic features of the detonator according to the invention are based on a special design of the confinement for the initiating charge and on the use of a secondary explosive as said initiating charge, which features impart to the detonator essential advantages as compared to detonators which utilize primary explosives as the initiating charge and also compared to prior non-primary explosive detonators. The invention also relates to a special initiating element for use in a non-primary explo¬ sive detonator of the above-mentioned type. Background of the Invention Up to now detonators of the above-mentioned type in commer- cial use are generally represented by pyrotechnic delay detonators which contain a small charge of a primary explo¬ sive placed in contact on one side with a pyrotechnic delay charge and on the other with a secondary explosive base charge, to effect the transition from a relatively slow non-violent chemical burning of the delay charge initiated by an igniting means such as an electrical fuse head to a detonation in said base charge. In this connection it should be noted that for practical purposes a primary explosive is defined as an explosive substance which can develop complete detonation from a flame or a conductive heating within a volume of a few cubic millimeters of the substance, even without any con¬ finement thereof. On the contrary, however, a secondary explosive can be initiated to detonate by a flame or a conductive heating only if present in very much larger quantities or within heavy confinement such as a heavy walled metal container, or by being exposed to mechanical impact between two hard metal surfaces. Examples of primary explosives are mercury fulminate, lead styphnate, lead azide and diazodinitrophenol or mixtures of two or more of these and/or other similar substances. Representa- tive examples of secondary explosives are pentaerythritol- tetranitrate (PETN) , cyclotrimethylenetrinitramine (RDX) , cyclotetramethylenetetranitramine (HMX) } trinitrophenylmethyl- nitramine (Tetryl) and trinitrotoluene TTNT) or mixtures of two or more of these and/or other similar substances. In a widely used method of producing a pyrotechnic delay detonator according to the prior art the required weight of secondary explosive for the base charge, typically about 600 mg, is first pressed into the bottom part of an outer metal shell having a closed bottom end. The required weight of primary explosive, typically about 300 mg or less, is then loosely filled into the shell on top of the base charge and compacted by pressing into the shell. Said primary explosive also contains a previously compacted pyrotechnic charge which is thus left with its upper end exposed and its lower end in close contact with the com¬ pacted primary explosive. When exposed to an igniting means such as a flame from an electric fusehead, from a NONEl^tube or from a detonating cord, inserted into the open end of the detonator shell, the pyrotechnic charge starts burning at a rate that is typically of the order of 2-10 cm/s. As soon as the burning pyrotechnic charge reaches the primary explosive there is a rapid transition from burning to detonation within said primary explosive. The resulting detonation in turn initiates detonation in the secondary explosive base charge. Conventional detonators of the above type have several serious disadvantages. These are primarily derived from the extreme sensitivity of the primary explosive to impact, friction or flame initiation. Some of said disadvantages are: 1. The presence of even a small charge of primary explosive makes a conventional detonator hazardous to handle because it is sensitive to mechanical deformation or impact, such as when accidentally bent or impacted at the region of the primary charge. 2. The manufacture of the primary explosive, the handling of the same and the shell filling opera¬ tions during manufacture of the detonator are risky operations which require extreme care and caution which in turn means costly operations and expensive plants. 3. The drainage of poisonous water containing fulminate, lead or phenol from the process of manufacture of the primary explosive creates serious environmental pollutions if not controlled. Furthermore, as it is not allowed to transport the bulk primary explosive it is necessary for each detonator plant to set up its own primary explosive plant, which increases the number of polluted areas and also requires additio¬ nal investments for environmental protection. It is therefore an object of the present invention to eli¬ minate or minimize the above-mentioned risks, pollutions and high investments, which is accomplished by using instead of the primary explosive a secondary explosive as an ini- tiating charge for detonators of the type referred to above. It is true that more recently non-primary explosive detona¬ tors have been disclosed and patented but generally these new detonators have not come to any widespread general use due to certain disadvantages or limitations. Among such disadvantages and limitations are that generally these previously known non-primary explosive detonators are restricted with reference to the use of the igniting means and with reference to the wall thick- nesses of the detonator shell and the dimensions of the confinement for the secondary explosive initiating charge and that they are also generally relatively complex as to their structures which influences upon the manufacture as well as the operation thereof. As prior art related to non-primary explosive detonators or in connection therewith reference is made to the following patent specifications: US 3 212 439 discloses a blasting cap which contains secondary explosives only. The detonation of the secondary explosive is caused by another secondary explosive that is compressed and arranged in a confined enclosure in a steel tube having specific dimensions. This confined enclosure provides conditions under which an electrical ignitor ignites the secondary explosive. US 3 978 791 relates to a detonator device containing secondary explosives only. Also in this case a compressed secondary explosive, "donor secondary explosive", is utilized but together with an impactor disc, a portion of which is released and accelerated when said donor secondary explosive is initiated by a bridge wire. The disc strikes an acceptor secondary explosive with sufficient velocity to produce detonation of the acceptor secondary explosive. US 4 239 004 discloses a detonator device of a structure similar to that of US 3 978 791 but the device also con¬ tains a delay mixture charge that imparts to the device a time delay before the donor secondary explosive is initiat¬ ed. DE AS 1 646 340 discloses a detonator device for the ini¬ tiation of a non-sensitive explosive, which contains a fuse and a pyrotechnic time delay element and the essential fea¬ ture of the device is that it comprises a housing filled wi a secondary explosive and open at one end. The open end of the housing is facing the delay element of the other part of the device and removably attached thereto. US 3 724 383 (1973) relates to a new method of initiation of an explosive, viz. the use of a laser pulse that passes through a fiber optic bundle (9) and a focusing bead (4) to impinge upon a charge (11) of a secondary explosive which is set into low order detonation. A second secondary charge (10) is thereby set into low order detonation but as said second charge is loaded in a gradient of increasing density the velocity of the reaction increases very rapidly and a high order explosion is obtained. US 4 206 705 (1980) relates to an electrical initiator wherein polymeric solid sulfur nitride (SN) is utilized as the sole explosive initiating means thanks to its abili¬ ty to act as an explosive as well as to conduct electrical current. US 3 661 085 discloses a new electric initiator structure wherein the pyrotechnic or explosive mix contacts only selected portions of the bridge wire, which means a sub¬ stantially faster response time than that exhibited by con- ventional initiators. The explosive charges (primary and secondary charges) are those charges which are conventional¬ ly employed in such devices. Disclosure of The Present Invention As should be clear from the above-mentioned an object of the present invention is to provide a detonator which eliminates or at least reduces the disadvantages of the primary explosive detonators as well as eliminates or reduces the disadvantages of the previously known non- primary explosive detonators or at least offers a valuable alternative thereto. More specifically, there is provided by the present invention a simple design of a non-primary explosive detonator which is conducive to the transition of a secondary explosive from burning to detonation, which offers the advantage of being able to use to the fullest extent those parts and technological equipments which have previously been used in conventional detonators while using less expensive shell materials and explosives and avoiding the risks associated with the utilization of primary explosives. This in turn means a versatility of a non- primary explosive detonator which has hitherto not been possible in connection with the previously known and rather restricted non-primary explosive detonators. Thus, for instance the new detonator according to the present inven¬ tion is not as restricted as the known non-primary explo¬ sive detonators as to the choice of igniting means, second¬ ary explosives, shell materials and thicknesses, etc. Still another object of the present invention is to provide a detonator by which the time of the transition from ignition to detonation is shortened so as to ensure the delay accuracy of high precise detonators. These and additional objects of the detonator as well as the specific initiating element according to the invention will be readily under- stood by a person skilled in the art from the following more detailed description of the invention. The characteristic feature o the non-primary explosive detonat according to the present invention is that the confinement is thin-walled and contains a secondary explosive initiating charg that the end of the confinement towards said chamber is open or provided with a thin wall or an aperture or a recess for an aperture to accelerate the burning of the secondary explosive initiating charge to a shock wave that causes detonation of the secondary explosive base charge, and an access, preferably at the opposite end thereof, which permits ignition of said second ary explosive initiating charge via the igniting means, said access preferably being in the form of a hole allowing escape of reaction product gases formed at the burning of the second¬ ary explosive initiating charge. Thus, by the new design of the confinement containing the se¬ condary explosive initiating charge it has unexpectedly turned out to be possible to utilize such a great area of burning se¬ condary explosive within the initiating charge that the burning rate is increased to such a level as to create a strong shock wave leading to detonation of the base charge. This is even more unexpected as the confinement can contain a hole that per¬ mits escape of reaction product gases formed at the burning of the initiating charge, i.e. said hole means that energy is lost through the escape of said gases. The access can be a means allowing ignition of the secondary explosive of the initiating charge, e.g. an electric resistance wire, with or without a surrounding fusehead, buried within the confinement with elec¬ trical connectors sealingly penetrating the confinement wall. However, an access in the form of a hole simplifies ignition and also involves the benefit of being able to utilize any igniting means available within the detonator art. As was ment¬ ioned above this represents a major advantage as compared to currently known non-primary explosive detonators. That is, the structure of the confinement according to the present invent- ion makes it possible to make the hole for the igniting means as large as is necessary for the insertion thereof, in spite of the energy losses through said hole. Although ignition means such as a fusehead can be positioned immediately at, in or below the hole, it is suitable to provide an empty space somewhere above the hole to buffer pressure build-up or allow escape of some of the reaction gases from the initiation charge. The space can be positioned for example somewhere be¬ tween the hole and the ignition means such as immediately above the hole or above a delay element adjacent the hole. From the above-mentioned it can be gathered that the detonator according to the present invention is adapted for use of any known secondary explosive as the initiating charge which also means that the initiating charge may even be of the same secondary explosive as the base charge, if desired. Representative examples of secondary explosives to be used as the initiating charge, and as the base charge, are the above-mentioned secondary explosives PETN, RDX, HMX Tetryl and TNT but the invention is not in any way limited to these explosives only. To modify the reaction rate of the initiating charge it may also be desirable to add to these secondary explosives pyrotechnical materials, e.g. aluminium powder or potassium perchlorate, passivators, e.g. shellac, or surface activators, e.g. a stearate. According to an especially preferable embodiment, however, the secondary explosive for the initiating charge is PETN or RDX or a mixture of these two explosives. Moreover, said secondary explosive for the initiating charge is preferably extra fine as to particle size, i.e. finer than the explo¬ sive for the base charge, which e.g. means that the explo¬ sive for the initiating charge passes through a 250 mesh sieve (US Sieve Series) ^<0.06 mm) while the explosive for the base charge passes through a 150 mesh sieve («iJ<0.1 mm). The particle size can preferably be below 30 urn and most preferably below 20 um. Other preferable data for the explosive to be used as initiating charge are: specific surface 5000-7000 cm 2 /g; pressing density 1.2-1.6 g/cm 3 , preferably 1.3-1.6 g/cm . Said data can be accomplised in a physical, chemical or mechanical way. As to the base charge it is generally conventional with reference to the above-mentioned proper-- ties, but it may also sometimes be suitable to use as said base charge part of the above-mentioned specific composi¬ tion used for the initiating charge and part of a conven-. tional secondary explosive. According to an especially preferable embodiment of the invention there is also used, between the initiating charge within the confinement and the base charge, e.g. - , or the .thin walj, . , adjacent the aperture/anα outside said confinement, a secondary explosive-that is more loosely pressed than the initiating charge. Compared to the above-mentioned range of 1.2-1.6 g/cm this may mean a pressing density within the range of 0.8-1.1 g/cm 3, preferably around 1.0 g/cm3. This normally means that this intermediate charge of low den- sity will be surrounded by the initiation and base charges of higher density. Preferably the intermediate charge is better confined than the base charge. The end of the confinement facing the base charge is critical for the function of the initiating charge. This end can be entirely open for best transmission of the shock wave to the base charge-, which is possible if the remaining parts of the confinement are sufficient for transition into detonation of the deflagrating secondary explosive. This end can also be provided with a thin wall to increase confinement, cause shoc wave reflections with interferences and simplify manufacture. Since the wall also to some degree prevents shock wave trans¬ mission to the base charge, it should not be too thick and is preferably less than 3 mm and most preferably below 1 mm in thickness. The wall can be smooth and uninterrupted. It can also be provided with an aperture, or a weakening for an aperture, to thereby amplify a shock wave and allow also a weaky developed wave to penetrate the wall and cause ignitio of the base charge whereby the reliability will be improved. In either design of the wall, it is preferred for reliabilit reasons that the deflagration to detonation transition takes plase in the confinement at latest at the wall. With reference to the aperture of the confinement for the initiating charge the main purpose thereof, and its size relative to the size of the initiating charge, is to accelerate the burning of the initiating charge to such extent that the burning gases create a shock wave that causes detonation of the base charge. The cross-sectional area as well as the shape of said aperture cannot be exactly defined in general terms as these parameters are dependent on other factors such as the material and wall thickness of the confinement, types of secondary explosives, amounts and configurations thereof, etc., but now that the inventive idea has been disclosed the necessary or optimum dimensions and shape of the aperture can easily be established by a person skilled in the art by routine experimental work. According to a preferable embodiment of the invention,, however, the cross-sectional area of the aperture is substantially less than the average cross- sectional area of the secondary explosive initiating chaTge, as this means a very rapid and accurate detonation of the base charge. While referring to the above discussion as to the exact dimensions of the aperture a typical ratio between the cross-sectional area of the aperture to that of the secondary explosive initiating charge is from about 1:2,5 to 1:4 although it may sometimes also be preferable to utilize a ratio that is less than 1:5. In the case of circular cross-sectional areas the above- mentioned ratios correspond to the ratios as to diameters of from about 1:1.6 to 1:2 and less than about 1:2.3, respectively. Furthermore, a complete aperture need not necessarily be present from the beginning as the invention works also if said aperture is created during the operation of the detonator. That is, according to another embodiment < of the detonator it contains a recess only for the aper- ture to be formed but still the main function of the detonator is based on the shock wave generated during the burning of the initiating charge which in turn means that the recess leaves typically a thin sheet or similar which is burst by the accelerated gases. Although it is possible that the column of secondary explo¬ sive, when seen in the detonation direction, has a smaller diameter of about the aperture size after the wall, it is preferred that the diameter increases again after the aper- ture, preferably to about the same diameter as before the wall. It is also preferred that the wall in which the aper¬ ture is formed is short and preferably only of the above mentioned wall thickness so that the aperture forms a short restriction in the explosive column. The. length of the initiation charge up to the wall or the length of the open-ended confinement is suitably sufficient for transition into detonation of the burning secondary explo¬ sive. The necessary length is quite short in the present design and can be kept below 50 mm, is suitably between 3 and 25 mm and preferabl ^between 5 and 20 mm. Also the dia- _ meter of the charge can be kept small such as below 15 mm and preferably also below 10 mm. According to another especially preferable embodiment of the detonator according to the invention the confine¬ ment containing the secondary explosive initiating charge is an element that is not integral with the shell of the detonator tube but is separate from said tube. This embodiment offers great advantages as compared to the prior art as in this way the initiating charge can be manufactured and handled completely separate from the detonator up to the use thereof. a long enough duration to ensure that the initiating ch starts burning, then a special flame-conducting pyrotech composition capable of being ignited by the weak igniti means and also capable of igniting the initiating charg to start burning may be placed in contact with the expo surface of the initiating charge. Such a flame-conductin pyrotechnic composition may also be placed between a de lay element and the exposed surface of the initiating charge if the delay charge composition itself is not ab to initiate the initiating charge to start burning. According to yet another embodiment of the detonator ac ing to the invention, in the case when the confinement represented by a separate element, said element compris a shell which may contain said hole and is open at the site end thereof, and a separate cap or disk which fits into said open end and contains- said wall, aperture or re In this way for instance the manufacture of the element can be facilitated economically by using existing tech¬ nology and equipment. Preferably the cup or disc is kep fixed against the shell, e.g. by being slightly oversiz in relation to the inner diameter of the shell. Although the exact or desired configuration of the apert is determined by a person skilled in the art from case t case a preferable cross-sectional area of the aperture o recess may be a circular one. Moreover, it has been foun to be especially preferable for the aperture or recess t include a surface of revolution, especially in the form of a hemisphere, a cone or a paraboloid. Yet another essential feature of the detonator claimed i that it enables the use of a thin-walled confinement or element, such as below 2 mm and even below 1 mm in thick ness, as well as the use of a similar thin-walled hollow tube. This results in a large burning area of initiating charge. The special design of the confinement with said wall o aperture results in a reflection of the weak shock wave accompanying the burning which additionally increases the shock pressure. The proviso for these features is that the confinement is of a strong material, for instance of steel. However, the detonator shell can be made of a very cheap material such as paper or plastic. A preferred wall thickness of the steel confinement part, which may con¬ tain the hole is within the range of 0.5 - 1 mm, especial¬ ly 0.5 - 0.6 mm. For that part of a steel confinement which contains fΕe/a'perture or recess therefor a preferred wall thickness is within the range of 0.3 - 0.25 mm for said aperture part and 0.08 - 0.15 mm for said recess part, respectively. The wall oraperture part can be designed in a weaker material than steel since it represents a small fract¬ ion only of the confinement and since axial confinement is supported by the explosive charges. From the above disclosure it can also be seen that the detonator can also include a delay substance or composi¬ tion. As is obvious to a person skilled in the art delay in this connection means time delay and the delay composi- tion can be any of those delay compositions which are uti¬ lized in the detonator field, e.g. a mixture of finely ground ferrosilicoπ or silicon, red lead and burning speed regulators. According to a preferable embodiment of the in¬ vention the delay composition is incorporated into the con- finement or the separate initiating element which for in¬ stance means that a separate initiating element can be manu¬ factured which contains the initiating charge as well as the delay composition for an easy incorporation into a de¬ tonator tube. Alternatively a normal delay element, e.g. containing a delay composition column in a thick-walled metal cylinder, can be positioned above the initiating elemen According to another aspect of the invention there is also claimed the above-mentioned separate initiating element and the characterizing features of said element are that it com¬ prises a casing containing a secondary explosive initiating charge and optionally a delay composition, the casing being thin-walled and in the end intended to be positioned towards the base charge being open or provided with a thin wall or an aperture, or a recess for an aperture, for the accelerat- ion of burning of said secondary explosive initiating charge to a shock wave that causes detonation of the secondary ex¬ plosive base charge, and a hole, preferably at the opposite end thereof, which permits ignition of the secondary explo¬ sive initiating charge via the igniting means. The especially preferable embodiments of the. initiating ele¬ ment according to the invention have already been disclosed and discussed above in connection with the detonator and need not be repeated here. Thus, the essential features of said embodiments are those features which are claimed in claims dependent on the initiating element claim. Drawings The detonator and the initiating element according to the invention as well as the functioning thereof will now be de¬ scribed more in detail in connection with the drawings, in which: Fig. 1 is a cross-sectional view of one embodiment of a detonator according to the invention; Fig. 2 schematically shows the function of the detonator shown in Fig. 1 ; Figures 3-6 are cross-sectional views of different embodi¬ ments of the initiating element according to the invention without any delay compositions; Figures 7-9 are cross-sectional views of other embodiments of the initiating element according to the invention with delay compositions;incorporated; Figures 10a-10f show cross-sectional views of different embodiments of caps or disks of the initiating element according to the invention; Fig. 11a is a cross-sectional view of another embodiment of a detonator according to the invention without any delay composition; Fig. 11b is a cross-sectional view of another embodiment of the detonator according to the invention with a sepa¬ rate delay composition; Fig. 12a is a cross sectional view of yet another embodiment of the detonator according to the invention without any delay composition; Fig. 12b is a cross-sectional view of another embodiment of the detonator according to the invention with a delay com¬ position and with an initiating element of the type shown in Fig. 9; and Fig. 13 is a cross-sectional view of still -another embodi¬ ment of the detonator according to the invention. Firstly, it should be noted that for all drawing Figures, for an easy understanding thereof, similar reference nu e- rals are utilized for similar parts of the detonator and elements, respectively, in spite of the fact that said parts may differ from each other as to configuration, placings, etc. This also means that the presence and function ing-, of each separate part will not be repeated in connec- tion with each Figure as the necessary information can still be easily gathered by a person skilled in the art. The figures show the preferred embodiment of the initiating ele¬ ment in which the access is a hole and in which the end facin the base charge is equipped with a wall having an aperture, The artisan will understand how these features can be changed in accordance with the alternatives described. More specifically, Figure 1 shows a detonator comprising a hollow tube 1 with a closed end and an open end, the closed end containing a chamber with a secondary explosive base charge 8. In this connection, it should be noted that the term chamber is not to be read literally, i.e. the chamber may well be a space only for the base charge, the open end of said space being later restricted by the ini¬ tiating charge to be described below. At the open end of the tube 1 there is a plastic plug 10 containing an ignit¬ ing means, in this case an electric fusehead 9. Adjacent to the secondary base charge 8 the tube 1 contains the new initiating element according to the invention which com¬ prises a casing consisting of two parts, viz. an open-end¬ ed shell 2 and fitted into its open end a smaller cap 3. Within the casing there is a secondary explosive initiating charge 7 at the end thereof towards the base charge 8 and a delay mixture 6 at the opposite end of the casing. The shell 2 contains a hole 4 intended for ignition via the igniting means 9 and for the escape of gases formed at the burning of the initiating charge 7. The cap 3 contains an aperture 5 towards the base charge 8 for the accelera-H tion of the burning of the initiating charge 7 to a shock wave causing detonation of the base charge 8. The functioning of the detonator shown in Fig. 1 is schema-. tically shown in Figure 2. Thus, Fig 2 shows the transition from the burning of the initiating charge 7 in the initiat¬ ing element to a shock wave after the ignition of the deto¬ nator. When exposed to the flame from the electric fuse hea 9 the pyrotechnic charge 6 starts burning at a relatively slow, non-violent rate. When the burning reaches the top of the initiating charge 7, the pressure from the burning sharply increases, some energy, losses occurring due to the leakage of gases G from the hole 4 and other energy losse also taking place as a result of the plastic deformation of the shell 2. On one hand, however, the energy losses are co pensated for by the accelerated burning of the initiating charge 7, and on the other hand the gases formed are still confined by the deformed shell 2, which in turn means that the pressure in the burning region still continues to rise so as to violently accelerate the burning to the formation of a weak shock wave. This weak shock wave becomes very intense after having reached the aperture 5 in the cap 3 wherein reflection of the shock wave takes place. The gases passing through the aperture 5.also get accelerated owing to the contracted section of the aperture 5, the pulse outp from the aperture 5 therefore producing a strong shock wave W in the top part of the base charge 8 which causes the required detonation of the base charge. From the above-mentioned it is understood that one of the preferred features of the invention is that the forced acceleration of the burning is allowed to take place in a non-closed confinement allowing escape of some reaction product gases and possibly deformation of the casing wall. This in turn for instance means that a relatively thin- walled casing can be utilized allowing a relatively large cross-sectional burning area of the initiating charge. In Figures 3-6 there are disclosed different embodiments of the initiating element according to the invention, no time delay composition being used within the element. The embodi¬ ment shown in Fig. 3 is similar to that of Fig. 1, the only difference being that said delay composition is not present. Figure 4 differs from Figure 3 in that the cap 3 is turned in the opposite direction as compared to that of Fig. 3, the walls of the open-ended shell 2 being extended beyond the cap 3 to form an open-ended tubular space between the cap 3 and the base charge 8. In last-mentioned tubular space there is also preferably used a charge of the secondary explosive 7 but having a lower density than that of the initiating charge 7 within the initiating element, Examples of useful densities in this respect are mentioned on p.9. Figure 5 shows an element in the form of a closed casing 2, the cap 3 having been replaced by a disk 3 within said casing 2, In this special case the aperture 5 is present in said disk 3. Figure 6 shows a casing similar to that of Fig. 5 but with¬ out any internal disk 3, the aperture 5 instead being made through the wall of casing 2. Figures 7-9 represent other embodiments of the initiating elements which elements also contain delay compositions. Thus, the element shown in Fig. 7 can be compared to that of Figure 5 but with a delay composition 6 present within the casing 2 at the end thereof adjacent the hole 4. The element shown in Figure 8 is similar to the elements of Fig. 3 and 4 and the only major difference relative to the elements of last-mentioned figures is that a delay composi¬ tion 6 is present within the casing 2. Figure 9 represents an element with a special design of the shell 2 which combines the functions of a delay element and an initiating element. Figure 10a-10f represent different embodiments of the cap or disk 3. Fig. 10a shows a cap 3 of the type that has al¬ ready been shown in Fig. 1 with an aperture 5 through the wall of the cap 3. The cap shown in Fig. 10b differs from that of 10a through the fact that the bottom end of the cap 3 contairis a recess 5 -only. Thus, the cap 3 of Fig. 10b contains a thin wall adjacent the recess 5. . Figures 10c-10f show disks, for instance of a metal or a plastics material, with apertures 5 having different confi- gurations and cross-sectional areas. The disk shown in Fig. 10c contains an aperture 5 the cross-section of which is circular. Fig. 10d shows a disk 3 with an aperture 5 con¬ taining a surface of revolution in the form of a hemisphere while the disks according to Figures 10e and 10f are si i- lar to that of Fig. 10d but with a surface of revolution in the form of a cone and a paraboloid, respectively. Although a preferable cross-sectional area of the recess is a circular one said area can also.be rectangular, rhombic or any combinations of two or more of these sections. Figure 11a shows an. instantaneous electric detonator with a shell 1a of paper. Thus, it should be noted that one of the advantages of the invention is that no particular requi ments are to be set forth for the strength of the outer she which for instance means that the shell may be made of glass aluminium, steel, any alloy, paper or plastic. The bottom end of the shell 1a is closed with sulphur or a plastic plug 13. The connection of the shell 1a with the electric - fusehead 9 has been realized by a crimped linking of a metal sleeve 14 with the plastic plug 10. Fig. 11b shows a delay electric detonator filled with an outer secondary explosive base charge 8 at the bottom of the outer shell 1a, followed by in turn an instantaneous initiating element 2 and a delay composition 6, between which there is a flame-conducting polytechnic composition 12 to accomplish a reliable ignition of the secondary explosive 7 within the initiating element 2. Figure 12a shows a non-electric detonator without any delay composition which, detonator is ignited by a low energy cord or a NONEL tube 15. The shell 1b is of a plastics material. Figure 12b is a metal-shelled non-electric delay detonator with, an initiating element similar to that al¬ ready shown in Fig» 9. Figure 13 shows a secondary explosive blasting cap fixed with a safety fuse 16, and where the flame-conducting pyrotechnic composition 12 is incorporated into the ini¬ tiating element 2. Examples EXAMPLE 1 A bras-shelled detonator similar to that shown in Fig. 1 was manufactured. The bottom end of the detonator was filled with 650 mg of RDX as a base charge, and 300 mg of RDX and 250 mg of a pyrotechnic delay composition containing silica powder and red lead were filled into the steel-shelled initiating element. Upon initiation of the electric fusehead the base charge of the detonator detonated and caused a hole with a diameter of 12 mm: in a 5 mm thick lead plate placed in contact with the bottom surface of the detonator. EXAMPLE 2 Ten aluminium-shelled detonators were manufactured with the same amounts of explosives as in Example 1 but with PETN instead of RDX in the initiating element. Their times from electric initiation to detonation upon initiation were 160 ms (milliseconds), 157 ms, 155 ms, 159 ms, 163 s, 164 161 ms, 166 ms, 154 ms and 167 ms, respectively. EXAMPLE 3 An aluminium-shelled detonator with the same volume of explosives as the one from Example 1 but with HMX instead of RDX in the initiating element was manufactured. Another difference relative to Example 1 was that a low energy tube was used instead of an electric fusehead. Into this detona¬ tor there was inserted an ANFO cartridge with, a diameter of 32 mm with a charge of 200 mg, and then another similar cartridge was placed along the axial direction with ' a dis¬ tance of 60 mm to the bottom end of the first cartridge. The ANFO formula was diesel 4, sawn chips 4/ammonium nitrate 92. Upon initiation of the NONEL tube the detonator and the cartridge detonated. EXAMPLE 4 A steel-shelled detonator of the type shown in Figure 13 was manufactured and filled with 600 mg of RDX at the botto thereof, 200 mg of PETN in the initiating element and 80 mg of a flame-conducting pyrotechnic composition containing ferrosilicon and red lead. Upon the initiation of the deto¬ nator by a safety fuse the base charge detonated and a fuse with a length of 20 m, the end of which was lapped over the detonator, got a complete detonation too. EXAMPLE 5 A paper-shelled detonator was manufactured and filled with 650 mg of RDX at the bottom end thereof and with 220 mg of HMX in the initiating element and without any pyrotechnic composition. The detonator was lapped at Dne end thereof with a fuse having a length of 1,2 m, the latter being fill with RDX in an amount of 13 g per meter. Upon initiation of the NONEL tube the base charge of the detonator detonated and the fuse was initiated too. The data recorded by an electric timer showed that the propagation time for the detonation with a distance of one meter between the two points of the fuse was 142,3 microseconds, which is equiva¬ lent to a detonation velocity of 7027,4 m/s. EXAMPLE 6 Ten paper-shelled detonators as shown in Figure 11b were manufactured, and the base charges and secondary explosive initiation charges thereof were the same as in Example 2, with the addition of 100 mg of a flame-conducting pyro¬ technic composition 12 and a 300 mg delay charge consist¬ ing of a pyrotechnic material containing ferrosilicon and red lead- The delay times recorded upon initiation were 533 ms, 536 ms, 531 ms, 557 s, 563 ms, 540 ms, 565 ms, 551 ms, 567 ms and 543 ms, respectively. EXAMPLE 7 Detonators were prepared having an outer aluminium cap tube with a length of 62 mm, a wall thickness of 0.5 mm and an interior diameter of 6.5 mm. The tube contained a base charge of 450 mg of RDX compacted to a density of about 1.5 g/cm 3 and an initiating element similar to the design shown in Figure 4 with a steel shell of 17 mm length, an outer diameter of 6.5mm, a wall thickness of o.6 mm and an upper hole of 2.5 mm diameter. The shell contained in its upper part a 200 mg initiating charge of about 5-15 μm size PETN powder compacted by a press force of 133 kg to a density of about 1.4 g/cm and below this charge a 200 mg intermediate charge of the same PETN powder compacted by a pressure force of 70 kg to a density of only about 1.0 g/cm 3 . Between the initiating charge and the intermediate charge a cup was inserted having an outer diameter of about 5.4 mm, a mate¬ rial thickness of about 0.5 mm, an aperture recess of 2.9 mm diameter and about 0.1 mm thickness. The entire cup u being pressed as an integral structure from aluminium sheet. The detonators were ignited by an electrical fusehead above the initiating element hole. Detonation was obtained in all four tested samples. EXAMPLE 8 Example 7 was repeated but using a cup with a wall thickness of 0.5 mm aluminium without an aperture or weakening. Two detonations out of two were obtained. EXAMPLE 9 Example 7 was repeated but using a cup prepared from 0.1 mm brass sheet and having no aperture. Two detonations out of two tests were obtained. EXAMPLE 10 Example 7 was repeated but using a cup prepared from 0.25 mm soft steel sheet and having no aperture. Two detonations out o two tests were obtained. EXAMPLE 11 Example 7 was repeated but using a cup prepared from 1.1 mm aluminium sheet and having no aperture. Two detonations out of two were obtained. EXAMPLE 12 Example 7 was repeated but using a cup prepared from 2.8 mm aluminium sheet and having no aperture. One detonation out of one tested was obtained. EXAMPLE 13 Example 7 was repeated but without any cup or wall between initiating charge and intermediate charge. Six detonations out of six tested were obtained. EXAMPLE 14 The initiating elements of example 7, comprising initiating charge, intermediate charge and an aluminium cup with an aperture recess in a 0.5 mm wall, were ignited separately from the exterior tube and base charge of the detonator. Four out of four initiating elements detonated.

Claims: CLAIMS 1. A non-primary explosive detonator comprising a hol¬ low tube (1) with a closed end having a chamber containing a secondary explosive base charge (8) , an opposite open end provided with or for the insertion of an igniting means (9,15, 16), and an intermediate confinement adjacent said chamber and containing an initiating charge (7), a delay composition (6) optionally being present adjacent said initiating charge, the secondary explosive base charge being arranged to detonate by activating the igniting means to ignite said initiating charge optionally via said delay composition, characterized in that the confinement is thin-walled and contains a secondary explo¬ sive initiating charge (7), that the end of the confinement towards said chamber is open or provided with a thin wall or an aperture (5) , or a recess for an aperture to accelerate the burning of said secondary explosive initiating charge to a shock wave that causes detonation of said secondary explosive base charge, and an access (4) preferably at the opposite end thereof, which permits ignition of said secondary explosive initiating charge via the igniting means (9,15,16). 2. A detonator according to claim 1, characterized in that the thin wall at the end of the confinement has a thick¬ ness below 3 mm or preferably below 1 m. 3. A detonator according to claim 1, characterized in that the access is a hole (4). » 4. A detonator according to claim 3, characterized in that a delay element is provided above the hole (4) . 5. A detonator according to claims 3 or 4, character¬ ized in that a space is provided allowing escape of reaction product gases formed at the burning of the secondary explosive initiating charge. 6. A detonator according to claim 1, characterized in that the access is an electric heating wire buried in the confinement with conductors sealingly penetrating the con¬ finement wall. 7. A detonator according to claim 1 or 3, character¬ ized in that the confinement is provided with an aperture (5) , or a recess for an aperture (5) , at the end thereof towards said chamber, and a hole (4), preferably at the opposite end thereof, which permits escape of reaction product gases formed at the burning of the secondary explosive initiating charge. 8. A detonator according to claim 1, characterized in that the confinement containing the secondary explosive ini¬ tiating charge (7) is an element (2,3) separate from the hollow tube. 9. A detonator according to claim 1 or 8, charact¬ erized in that the cross-sectional area of the aperture or recess (5) is substantially less than the average cross-sectio¬ nal area of the secondary explosive initiating charge (7), the ratio between said areas preferably being from about 1:2.5 to 1:4. 10. A detonator according to claim 2, characterized in that the cross-sectional area of the hole (4) is substantially less than the average cross-sectional area of the secondary explosive initiating charge (7) , the ratio between said areas preferably being from about 1:2.9 to 1:6.3. 11. A detonator according to anyone of claims 8-10, characterized in that the element separate from the hollow tube comprises a shell (2) which contains said hole (4) and is open at its opposite end, optionally having a separate cap or disk (3) which fits into said open end and contains said thin wall or said aperture or recess (5) . 12. A detonator according to anyone of the preceding claims, characterized in that the cross-sectional area of the aperture or recess (5) is circular. 13. A detonator according to anyone of the preceding claims, characterized in that the aperture or recess (5) in¬ cludes a surface of revolution in the form of a hemisphere, a cone or a paraboloid. 14. A detonator according to anyone of the preceding claims, characterized in that it contains a secondary explo¬ sive charge between the confinement and the base charge, which charge has a lower density than said initiating charge, said lower density preferably being within the range of 0.8-1.1 15. A detonator according to anyone of the preceding claims, characterized in that the : confinement is a thin-walled element of such a strong material, e.g. steel, that deformat¬ ion without bursting can take place during the burning of the secondary explosive initiating charge. 16. A detonator according to anyone of the preceding claims, characterized in that the confinement contains also the delay composition (6). 17. A detonator according to anyone of the preceding claims, characterized in that the secondary explosive initiat¬ ing charge comprises PETN or RDX or a mixture thereof. 18. A detonator according to anyone of the preceding claims, characterized in that the secondary explosive initiat¬ ing charge has a particle size of less than 250 mesh « less 2 than 0.06 mm), a specific surface of abo )Uu1t 5000-7000 cm /g and a pressing density of about 1.2-1.6 g/cm 3' 19. A detonator according to anyone of the preceding claims, characterized in that it contains a flame-conducting pyrotechnic composition in contact with said secondary explosive initiating charge. 20. An initiating element for use in a non-primary ex¬ plosive hollow tube detonator containing a secondary explosive base charge (8) to be detonated, optionally via a delay com¬ position (6) by activating an igniting means (9,15,16), charact¬ erized in that it comprises a casing (2,3) containing a secon¬ dary initiating charge (7) and optionally a delay composition (6), the casing being thin-walled and in the end intended to be positioned towards the base charge is open or provided with a thin wall or an aperture (5), or a recess for an aperture, for the acceleration of burning of said secondary explosive initiating charge to a shock wave that causes detonation of said secondary explosive base charge, and a hole (4), prefer¬ ably at the opposite end thereof, which permits ignition of said secondary explosive initiating charge via the igniting means (9,15,16). 21. An initiating element according to claim 20, characterized in that the cross-sectional area of the aperture or recess (5) is substantially less than the average cross- -sectional area of the secondary explosive initiating charge (7) , the ratio between said areas preferably being from about 1:2.5 to 1:4. 22. An initiating element according to claim 20 or 21, characterized in that the access is a hole and that the cross- -sectional area of the hole (4) is substantially less than the average cross-sectional area of the secondary explosive ini¬ tiating charge (7), the ratio between said areas preferably being from about 1:2.0 to 1:6.3. 23. An initiating element according to anyone of claim 20-22, characterized in that it comprises a shell (2) which contains said access and is open at its opposite end, optional ly having a separate cap or disk (3) which fits into said open end and contains said thin wall or said aperture or recess (5) 24. An ' initiating element according to claim 23, char¬ acterized in that the walls of the shell (2) are extended beyon the initiating charge to form an open-ended tubular space be¬ tween the initiating charge and the base charge (8), said spac preferably being intended for a secondary explosive charge 'having a lower density than the initiating charge. 25. An initiating element according to anyone of claim 20-23, characterized in that the cross-sectional area of the aperture or recess (5) is circular. 26. An initiating element according to anyone of claim 20-25, characterized in that the aperture or recess (5) includ es a surface of revolution in the form of a hemisphere, a cone or a paraboloid. 27. An initiating element according to anyone of claim 19-26, characterized in that it is a thin-walled element of such a strong material, e.g. steel, that deformation without bursting can take place during the burning of the secondary explosive initiating charge. 28. An initiating element according to anyone of claim 19-27, characterized in that the secondary explosive initiat¬ ing charge comprises PETN or RDX or a mixture thereof. 29. An initiating element according to anyone of claim 19-28, characterized in that the secondary explosive initiatin charge has a particle size of less than 250 mesh (^ less than 0.06 mm), a specific surface of about 5000-7000 cm /g and a 7 pressing density of about 1.2-1.6 g/cm . 30. An initiating element according to anyone of claims 19-29, characterized in that it contains a fla e- -conducting pyrotechnic composition in contact with said secondary explosive inititing charge.

Inventors: GUOWEN HU, QUICHENG WANG, TIANRUI XU, XIANQUAN LI, XIQIN ZHANG, GUOWEN, HU, QUICHENG, WANG, TIANRUI, XU, XIANQUAN, LI, XIQIN, ZHANG
Applicants: CHINA METALL IMP & EXP CORP, CHINA METALL SAFETY TECH INST, NITRO NOBEL AB
Application year: 1985
Main classification: C06C7
IPC codes: C06C7, F42B3, F42C19