MOLECULAR SIEVE COMPOSITIONS

Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO₂, AlO₂, SiO₂ and PO₂ framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous ba­ sis expressed by the formula: mR : (EL w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL w Al x P y Si z )O₂; "EL" 'represents at least one element capable of forming a framework oxide unit; and "w","'x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

Description: I. FIELD OF THE INVENTION The instant invention relates to a novel class of three-dimensional microporous crystalline molecular sieves, to the method of their preparation and to their use as adsorbents and catalysts. The invention relates to novel molecular sieves having at least one element capable of forming a framework oxide units, e.g., "ELO₂", with tetrahedral oxide units of aluminum (AlO - / 2), phosphorus (PO + / 2) and silicon (SiO₂). These compositions may be prepared hydrothermally from gels containing reactive compounds of silicon, aluminum and phosphorus and at least one additional element capable of forming a framework oxide unit, and preferably at least one organic templating agent which may function in part to determine the course of the crystallization mechanism and the structure of the crystalline product. II. BACKGROUND OF THE INVENTION Molecular sieves of the crystalline aluminosilicate zeolite type are well known in the art and now comprise over 150 species of both naturally occurring and synthetic compositions. In general the crystalline zeolites are formed from corner-sharing AlO₂ and SiO₂ tetrahedra and are characterized by having pore openings of uniform dimensions, having a significant ion-exchange capacity and being capable of reversibly desorbing an adsorbed phase which is dispersed throughout the internal voids of the crystal without displacing any atoms which make up the permanent crystal structure. Other crystalline microporous compositions which are not zeolitic, i.e. do not contain AlO₂ tetrahedra as essential framework constituents, but which exhibit the ion-exchange and/or adsorption characteristics of the zeolites are also known. Metal organosilicates which are said to possess ion-exchange properties, have uniform pores and are capable of reversibly adsorbing molecules having molecular diameters of about 0.6 nm (6Å) or less, are reported in U.S. Patent No. 3,941,871 issued March 2, 1976 to Dwyer et al. A pure silica polymorph, silicalite, having molecular sieving properties and a neutral framework containing neither cations nor cation sites is disclosed in U.S. Patent No. 4,061,724 issued December 6, 1977 to R.W. Grose et al. A recently reported class of microporous compositions and the first framework oxide molecular sieves synthesized without silica, are the crystalline aluminophosphate compositions disclosed in U.S. Patent No. 4,310,440 issued January 12, 1982 to Wilson et al. These materials are formed from AlO₂ and PO₂ tetrahedra and have electrovalently neutral frameworks as in the case of silica polymorphs. Unlike the silica molecular sieve, silicalite, which is hydrophobic due to the absence of extra-structural cations, the aluminophosphate molecular sieves are moderately hydrophilic, apparently due to the difference in electronegativity between aluminum and phosphorus. Their intracrystalline pore volumes and pore diameters are comparable to those known for zeolites and silica molecular sieves. In copending and commonly assigned US Patent application Serial No. 400,438, filed July 26, 1982, there is described a novel class of silicon-substituted aluminophosphates which are both microporous and crystalline. The materials have a three dimensions crystal framework of PO + / 2, AlO - / 2 and SiO₂ tetrahedral unites and, exclusive of any alkali metal or calcium which may optionally be present, an as-synthesized empirical chemical composition on an anhydrous basis of: mR : (Si x Al y P z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the moles of "R" present per mole of (Si x Al y P z )O₂ and has a value of from zero to 0.3; the maximum value in each case depending upon the molecular dimensions of the templating agent and the available void volume of the pore system of the particular silicoaluminophosphate species involved; and "x", "y", and "z" represent the mole fractions of silicon, aluminum and phosphorus, respectively, present as tetrahedral oxides. The minimum value for each of "x", "y", and "z" is 0.01 and preferably 0.02. The maximum value for "x" is 0.98: for "y" is 0.60; and for "z" is 0.52. These silicoaluminophosphates exhibit several physical and chemical properties which are characteristic of aluminosilicate zeolites and aluminophosphates. In copending and commonly assigned US Patent application Serial No. 480,738, filed March 31, 1983 there is described a novel class of titanium-containing molecular sieves whose chemical composition in the as-synthesized and anhydrous form is represented by the unit empirical formula: mR:(Ti x Al y P z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the moles of "R" present per mole of (Ti x Al y P z )O₂ and has a value of between zero and about 5.0; and "x", "y" and "z" represent the mole fractions of titanium, aluminum and phosphorus, respectively, present as tetrahedral oxides. In copending and commonly assigned US Patent application Serial No. 514,334, filed July 15, 1983, there is described a novel class of crystalline metal aluminophosphates having three-dimensional microporous framework structures of MO₂, AlO₂ and PO₂ tetrahedral units and having an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(M x Al y P z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the moles of "R" present per mole of (M x Al y P z )O₂ and has a value of from zero to 0.3; "M" represents at least one metal of the group magnesium, manganese, zinc and cobalt; "x", "y" and "z" represent the mole fraction of the metal "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. In copending and commonly assigned US Patent application Serial No. 514,335, filed July 15, 1983, there is described a novel class of crystalline ferroaluminophosphates having a three-dimensional microporous framework structure of FeO₂, AlO₂ and PO₂ tetrahedral units and having an empirical chemical composition on an anhydrous basis expressed by the formula mR:(Fe x Al y P z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the moles of "R" present per mole of (Fe x Al y P z )O₂ and has a value of from zero to 0.3; and "x", "y" and "z" represent the mole fraction of the iron, aluminum and phosphorus, respectively, present as tetrahedral oxides. The instant molecular sieve compositions are characterized in several ways as distinct from heretofore known molecular sieves, including the aforementioned ternary compositions. The instant molecular sieves are characterized by the enhanced thermal stability of certain species and by the existence of species heretofore unknown for binary and ternary molecular sieves. The instant invention relates to new molecular sieve compositions having at least one element other than silicon, aluminum and phosphorus where such element is capable of forming a framework oxide unit with AlO - / 2, PO + / 2, and SiO₂ tetrahedral oxide units. III. DESCRIPTION OF THE FIGURES FIG. 1 is a ternary diagram wherein parameters relating to the instant compositions are set forth as mole fractions. FIG. 2 is a ternary diagram wherein parameters relating to preferred compositions are set forth as mole fractions. FIG. 3 is a ternary diagram wherein parameters relating to the reaction mixtures employed in the preparation of the compositions of this invention are set forth as mole fractions. IV. SUMMARY OF THE INVENTION The instant invention relates to a new class of molecular sieves in which at least one element capable of forming a framework oxide unit is provided to form crystal framework structures of SiO₂, AlO - / 2, PO + / 2 and ELO n / 2 units wherein "EL" represents at least one element present as a framework oxide unit "ELO n / 2" with charge "n" where "n" may be -3, -2, -1, 0 or +1. These new molecular sieves exhibit ion-exchange, adsorption and catalytic properties and, accordingly, find wide use as adsorbents and catalysts. The members of this novel class of compositions have crystal framework structures of SiO₂, AlO - / 2, PO + / 2 and ELO n / 2 framework oxide units, where "n" is -3, -2, -1, 0 or +1, and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR : (EL w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL w Al x P y Si z )O₂ and has a value from zero to about 0.3; "EL" represents at least one element capable of forming a framework oxide unit as hereinafter described: and "w", "x", "y" and "z" represent the mole fractions of "EL", aluminum, phosphorus and silicon, respectively, present as framework oxide units. "EL" denominates the elements present in addition to aluminum, phosphorus and silicon and may be a single element or may be two or more elements such that the molecular sieves contain one or more framework oxide units "ELO n / 2" in addition to framework tetrahedral oxide units SiO₂, AlO - / 2 and PO + / 2. The molecular sieves of the instant invention will be generally referred to by the acronym "ELAPSO" to designate element(s) "EL" in an oxide framework of SiO₂, AlO - / 2, PO + / 2 and ELO n / 2 oxide units. Actual class members will be identified by replacing the "EL" of the acronym with the element(s) present as a ELO n / 2 oxide unit(s). For example "CoAPSO" designates a molecular sieve comprised of SiO₂, AlO - / 2, PO + / 2 and CoO -2 / 2 (and/or CoO -1 / 2 ) framework oxide units, and "CoZnAPSO" designates a molecular sieve having SiO₂, AlO - / 2, PO + / 2, CoO -2 / 2 (and/or- CoO -1 / 2 ) and ZnO -2 / 2 framework oxide units. To identify various structural species which make up each of the subgeneric classes, each species is assigned a number and is identified as "ELAPSO-i" wherein "i" is an integer. This designation is an arbitrary one and is not intended to denote structural relationship to another material(s) which may also be characterized by a numbering system. V. DETAILED DESCRIPTION OF THE INVENTION The instant invention relates to a new class of three-dimensional microporous crystalline molecular sieves in which at least one element capable of forming a framework oxide unit is provided to form crystal framework structures of SiO₂, AlO - / 2, PO + / 2 and ELO n / 2 framework oxide units wherein "EL" represents at least one element capable of forming a framework oxide unit "ELO n / 2" with charge "n" where "n" is -3, -2, -1, 0 or +1. These new molecular sieves exhibit ion-exchange, adsorption and catalytic properties and accordingly find wide use as adsorbents and catalysts. The ELAPSO compositions are formed with elements capable of forming framework oxide units in the presence of SiO₂, AlO - / 2 and PO + / 2 tetrahedral oxide units where element "EL" is at least one element capable of forming a three dimensional oxide framework in the presence of aluminum, phosphorus and silicon oxide units, and has a mean "T-O" distance in tetrahedral oxide structures of between 1.51 Angstroms and 2.06 Angstroms (1 Angstrom equals 0.1 nm), has a cation electronegativity between 523 kJ/g-atom and 1297 kJ/g-atom (125 kcal/g-atom and 310 kcal/g-atom) and is capable of forming stable M-O-P, M-O-Al or M-O-M bonds in crystalline three dimensional oxide structures where the "M-O" bond dissociation energy, D°, is greater than 246.9 kJ/mole (59 kcal/mole) at 298°K. The use of "M" in the aforementioned discussion on bond energies is one of convenience since the prior art has heretofore employed "M" to designate the element (EL) bonded to oxygen. For the purposes of discussion herein any reference to M-O-P, M-O-Al, M-O-M or M-O refers to the substitution of element(s) "EL" for the "M" designation. The "T-O" distance denominates the bond length of the "T-O" bond where "T" is element(s) "EL" occupying the tetrahedral cation site and is related to the Shannon/Prewitt crystal or ionic radii. Elements known to occur in tetrahedral coordination with oxygen are discussed in: Joseph V. Smith, "Feldspar Minerals", Springer-Verlag, Berlin, New York, Vol. I, pp. 55-65 and 106-113 (1974); R. D. Shannon, Acta. Cryst. , A32, p. 751 (1976); R. D. Shannon, C.T. Prewitt, Acta. Cryst. , B25, p. 925 (1969); and F. Donald Bloss, "Crystallography and Crystal Chemistry", Holt, Rinehart and Winston, Inc., New York, pp. 278-279 (1971). The "T-O" distance is calculated according to the procedures heretofore employed and as discussed in, R. D. Shannon. Acta Cryst. , A32, p. 751 (1976) and R. D. Shannon, C.T. Prewitt, Acta Cryst. , B25, p. 925 (1969), based, respectively, on the ionic and crystal radius of oxide ion, O²⁻, of 1.40 Angstroms and 1.26 Angstroms. The cation electronegtivity of element(s) "EL" is determined consistent with the procedure set forth in A. S. Povarennykh, "Crystal Chemical Classification of Minerals". Vol. I, translation from Russian by J. E. S. Bradley, Plenum Press, New York-London, p. 32 (1972). The bond dissociation energy of "M-O" is determined according to the procedures discussed in: V. I. Vedeneyev, L. V. Gurvich, V. N. Kondrat'Yev, V. A. Medvedev and Ye. L. Frankevich, "Bond Energies, Ionization Potentials and Electron Affinities," New York, St. Martins Press, English Translation, p. 29ff (1966); "The Oxide Handbook", 2nd Ed., G. V. Samsonov, ED., translation from Russian by R. K. Johnston, IFI/Plenum Data Company, pp. 86-90 (1982); and "Bond Dissociation Energies in Simple Molecules", B deB. Darwent, NSRSS-NBS 31, U.S. Dept. of Commerce, National Bureau of Standards, pp. 9-47 (1970). Further embodiments of the instant invention relate to the molecular sieves as above defined being characterized by element(s) "EL" characterized by at least one of the following criteria: (1) "EL" is characterized by an electronic orbital configuration selected from the group consisting of d⁰, d¹, d², d⁵ , d⁶, d⁷, or d¹⁰ where the small crystal field stabilization energy of the metal ligand "-OM" favors tetrahedral coordination of element EL ("EL" denominated here also as "M") with O²⁻, as discussed in "Inorganic Chemistry" J. E. Huheey, Harper Row, p. 348 (1978): (2) "EL" is characterized as capable of forming stable oxo or hydroxo species in aqueous solution as evidenced by a first hydrolysis constant, K₁₁, greater than 10⁻¹⁴, as discussed in "The Hydrolysis of Cations", C. F. Baes and R. E. Mesmer, John Wiley & Sons (1976): (3) "EL" is selected from the group of elements known to occur in crystal structure types geometrically related to the different silica modifications, quartz, cristobalite or tridymite, as discussed in E. Parthe, "Crystal Chemistry of Tetrahedral Structures", Gordon and Breach, New York, London, pp. 66-68 (1964); and (4) "EL" is an element which in its cation form is classified by Pearson, (J. E. Huheey, "Inorganic Chemistry", Harper & Row, p. 276 (1978)) as "hard or "borderline" acids which interact with the "hard" base O²⁻ to form more stable bonds than the cations classified as "soft" acids. In one embodiment of the invention element "EL" is preferably at least one element selected from the group consisting of arsenic, beryllium, boron, chromium, cobalt, gallium, germanium, iron, lithium, magnesium, manganese, titanium, vanadium and zinc. The relative amounts of silicon, aluminum, phosphorus and element(s) "EL" are expressed by the empirical chemical formula (anhydrous): mR : (EL w Al x P y Si z )O₂ where "w", "x", "y" and "z" represent the mole fractions of said element(s) "EL", aluminum, phosphorus, and silicon, respectively. When "EL" comprises two or more elements, "w" represents the mole fractions of said elements (EL₁, EL₂, EL₃, EL₄, etc.) and "w" equals the sum of "w₁", "w₂, "w₃", "w₄", etc., wherein "w₁", "w₂", "w₃", "w₄" and etc. represent the individual mole fractions of elements EL₁, EL₂, EL₃, EL₄ and etc. and each has a value of at least 0.01. The molecular sieves of the instant invention have three-dimensional microporous crystalline framework structures of ELO n / 2, AlO - / 2, PO + / 2 and SiO₂ framework oxide units having an empirical chemical composition on an anhydrous basis expressed by the formula: mR : (EL w Al x P y Si z )O₂ wherein "R" represents an organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL w Al x P y Si z )O₂ and has a value of zero to about 0.3; "EL" represents at least one element capable of forming a three dimensional oxide framework has a mean "T-O" distance in tetrahedral oxide structures of between about 1.51 Angstroms and about 2.06 Angstroms, has a cation electronegativity between about 125 kcal/g-atom to 310 kcal/g-atom and is capable of forming stable M-O-P, M-O-Al or M-O-M bonds in crystalline three dimensional oxide structures where the "M-O" bond dissociation energy, D°, is greater than about 59 kcal/mole at 298°K; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxide units. The use of "M" in the aforementioned discussion on bond energies is one of convenience since the prior art has heretofore employed "M" to dominate the element (EL) bonded to oxygen. For the purpose of discussion herein any reference to M-O-P, M-O-Al, M-O-M or M-O refers to the substitution of element(s) "EL" for the "M" designation. The mole fractions "w", "x" "y" and "z" are generally defined as being within the pentagonal compositional area defined by points A, B, C, D and E of the ternary diagram of FIG.1, said points A, B, C, D and E of FIG. 1 having the following values for "w", "x", "y", and "z": where "p" is an integer correspondig to the number of elements "EL" in the (EL w Al x P y Si z )O₂ constituent and is preferably an integer from one (1) to fourteen (14). In a preferred subclass of the ELAPSO molecular sieves the values of "w", "x", "y" and "z", where "w" is as above defined, in the above formula are within the tetragonal compositional area defined by points a, b, c and d of the ternary diagram which is FIG. 2, said points a, b, c and d representing the following values for "w", "x", "y" and "z"; where "p" is as above defined. While it is believed that the elements "EL", aluminum, phosphorus and silicon in the framework constituents are present in tetrahedral coordination with oxygen, i.e. as tetrahedral oxide units, it is theoretically possible that some fraction of these framework constituents are present in coordination with five or six oxygen atoms. The convenient reference herein to the framework oxide units are represented by formulae which indicate tetrahedral oxide units, although as above noted other than tetrahedral coordination may exist. It is not, moreover, necessarily the case that all the elements "EL" of any given synthesized product be part of the framework in the aforementioned types of coordination with oxygen. Some of each constituent may be in some as yet undetermined form. The ELAPSOs of this invention are useful as adsorbents, catalysts, ion-exchangers, and the like in much the same fashion as aluminosilicates have been employed heretofore, although their chemical and physical properties are not necessarily similar to those observed for aluminosilicates. ELAPSO compositions are generally synthesized by hydrothermal crystallization from a reaction mixture containing active sources of element(s) "EL", silicon, aluminum and phosphorus, preferably an organic templating, i.e., structure-directing, agent which is preferably a compound of an element of Group VA of the Periodic Table, and/or optionally an alkali or other metal. The reaction mixture is generally placed in a sealed pressure vessel, preferably lined with an inert plastic material such as polytetrafluoroethylene and heated, preferably under autogenous pressure at an effective temperature which is preferably between about 50°C and about 250°C, more preferably between 100°C and 200°C, until crystals of the ELAPSO product are obtained, usually an effective crystallization time of from several hours to several weeks. Generally, effective crystallization times of from about 2 hours to about 30 days are employed with typically from 4 hours to about 20 days being employed to obtain ELAPSO products. The product is recovered by any convenient method such as centrifugation or filtration. In synthesizing the ELAPSO compositions of the instant invention, it is preferred to employ a reaction mixture composition expressed in terms of molar ratios as follows: aR : (EL w Al x P y Si z )O₂ : bH₂O wherein "R" is an organic templating agent: "a" is the amount of organic templating agent "R" and has a value of from zero to about 6 and is preferably an effective amount within the range of greater than zero (0) to about 6; "b" has a value of from zero (0) to about 500, preferably between about 2 and about 300; "EL" represents at least one element, as herein before described, capable of forming a framework oxide unit, ELO n / 2, with SiO₂, AlO - / 2 and PO + / 2 tetrahedral oxide units; "n" has a value of -3, -2, -1, 0 or +1; and "w", "x", "y", "z" represent the mole fractions of element "EL", aluminum, phosphorus, and silicon respectively, and each has a value of at least 0.01. In a preferred embodiment the reaction mixture is selected such that the mole fractions "w", "x", "y", and "z" are generally defined as being within the pentagonal compositional area defined by points E, F, G, H, and I of the ternary diagram of Fig. 3. Points E, F, G, H, and I of Fig. 3 have the following values for "w", "x", "y", and "z": In the foregoing expression of the reaction composition, the reactants are normalized with respect to the total of "w", "x", "y", and "z" such that (w+x+y+z) = 1.00 mole , whereas in the examples the reaction mixtures may be expressed in terms of molar oxide ratios normalized to the moles of P₂O₅. This latter form is readily converted to the former form by routine calculations by dividing the number of moles of each component (including the template and water) by the total number of moles of elements "EL", aluminum, phosphorus and silicon which results in normalized mole fractions based on total moles of the aforementioned components. In forming reaction mixtures from which the ELAPSO molecular sieves are formed an organic templating agent is preferably employed and may be any of those heretofore proposed for use in the synthesis of conventional zeolite aluminosilicates. In general these compounds contain elements of Group VA of the Periodic Table of Elements, particularly nitrogen, phosphorus, arsenic and antimony, preferably nitrogen or phosphorous and most preferably nitrogen, which compounds also contain at least one alkyl or aryl group having from 1 to 8 carbon atoms. Particularly preferred compounds for use as templating agents are the amines, quarternary phosphonium and quaternary ammonium compounds, the latter two being represented generally by the formula R₄X⁺ wherein "X" is nitrogen or phosphorous and each R is an alkyl or aryl group containing from 1 to 8 carbon atoms. Polymeric quaternary ammonium salts such as [(C₁₄H₃₂N₂) (OH) ₂] x wherein "x" has a value of at least 2 are also suitably employed. The mono-, di- and tri-amines are advantageously utilized, either alone or in combination with a quaternary ammonium compound or other templating compound. Mixtures of two or more templating agents may either produce mixtures of the desired ELAPSOs or the more strongly directing templating species may control the course of the reaction with the other templating species serving primarily to establish the pH conditions of the reaction gel. Representative templating agents include: tetramethylammonium; tetraethylammonium; tetrapropylammonium; tetrabutylammonium ions; tetrapentylammonium ions; di-n-propylamine; tripropylamine; triethylamine; triethanolamine; piperidine; cyclohexylamine; 2-methylpyridine; N,N-dimethylbenzylamine; N,N-dimethylethanolamine; choline; N,N'-dimethylpiperazine; 1,4-diazabicyclo (2,2,2,) octane; N-methyldiethanolamine, N-methylethanolamine; N-methylpiperidine; 3-methylpiperidine; N-methylcyclohexylamine; 3-methylpyridine; 4-methylpyridine; quinuclidine; N,N'-dimethyl-1,4-diazabicyclo (2,2,2) octane ion; di-n-butylamine, neopentylamine; di-n-pentylamine; isopropylamine; t-butylamine; ethylenediamine; pyrrolidine; and 2-imidazolidone. Not every templating agent will direct the formation of every species of ELAPSO, i.e., a single templating agent may, with proper manipulation of the reaction conditions, direct the formation of several ELAPSO compositions, and a given ELAPSO composition can be produced using several different templating agents. The source of silicon may be silica, either as a silica sol or as fumed silica, a reactive solid amorphous precipitated silica, silica gel, alkoxides of silicon, silica containing clays silicic acid or alkali metal silicate and mixtures thereof. The most suitable phosphorus source yet found for the present process is phosphoric acid, but organic phosphates such as triethyl phosphate have been found satisfactory, and so also have crystalline or amorphous aluminophosphates such as the AlPO₄ compositions of U.S.P. 4,310,440. Organo-phosphorus compounds, such as tetrabutylphosphonium bromide do not, apparently, serve as reactive sources of phosphorus, but these compounds do function as templating agents. Conventional phosphorus salts such as sodium metaphosphate, may be used, at least in part, as the phosphorus source, but are not preferred. The preferred aluminum source is either an aluminum alkoxide, such as aluminum isoproproxide, or pseudoboehmite. The crystalline or amorphous aluminophosphates which are a suitable source of phosphorus are, of course, also suitable sources of aluminum. Other sources of aluminum used in zeolite synthesis, such as gibbsite, aluminum-containing clays, sodium aluminate and aluminum trichloride, can be employed but are not preferred. The element(s) "EL" can be introduced into the reaction system in any form which permits the formation in situ a of reactive form of the element, i.e., reactive to form a framework oxide unit of element "EL". Compounds of element(s) "EL" which may be employed include oxides, hydroxides, alkoxides, nitrates, sulfates, halides, carboxylates and mixtures thereof. Representative compounds which may be employed include: carboxylates of arsenic and beryllium; cobalt chloride hexahydrate, alpha cobaltous iodide; cobaltous sulfate; cobalt acetate; cobaltous bromide; cobaltous chloride; boron alkoxides; chromium acetate; gallium alkoxides; zinc acetate; zinc bromide; zinc formate; zinc iodide; zinc sulfate heptahydrate; germanium dioxide; iron (II) acetate; lithium acetate; magnesium acetate; magnesium bromide; magnesium chloride; magnesium iodide; magnesium nitrate; magnesium sulfate; manganese acetate; manganese bromide; manganese sulfate; titanium tetrachloride; titanium carboxylates; titanium acetate; zinc acetate; and the like. While not essential to the synthesis of ELAPSO compositions, stirring or other moderate agitation of the reaction mixture and/or seeding the reaction mixture with seed crystals of either the ELAPSO species to be produced or a topologically similar aluminophosphate, aluminosilicate or molecular sieve composition, facilitates the crystallization procedure. After crystallization the ELAPSO product may be isolated and advantageously washed with water and dried in air. The as-synthesized ELAPSO generally contains within its internal pore system at least one form of any templating agent employed in its formation. Most commonly this organic moiety, derived from any organic template, is present, at least in part, as a charge-balancing cation as is generally the case with as-synthesized aluminosilicate zeolites prepared from organic-containing reaction systems. It is possible, however, that some or all of the organic moiety may be an occluded molecular species in a particular ELAPSO species. As a general rule the templating agent, and hence the occluded organic species, is too large to move freely through the pore system of the ELAPSO product and must be removed by calcining the ELAPSO at temperatures of 200°C to 700°C to thermally degrade the organic species. In some instances the pores of the ELAPSO compositions are sufficiently large to permit transport of the templating agent, particularly if the latter is a small molecule, and accordingly complete or partial removal thereof may be accomplished by conventional desorption procedures such as carried out in the case of zeolites. It will be understood that the term "as-synthesized" as used herein does not include the condition of ELAPSO species wherein any organic moiety occupying the intracrystalline pore system as a result of the hydrothermal crystallization process has been reduced by post-synthesis treatment such that the value of "m" in the composition formula: mR : (M w Al x P y Si z )O₂ has a value of less than 0.02. The other symbols of the formula are as defined hereinabove. In those preparations in which an alkoxide is employed as the source of element(s) "EL", aluminum, phosphorous and/or silicon, the corresponding alcohol is necessarily present in the reaction mixture since it is a hydrolysis product of the alkoxide. It has not been determined whether this alcohol participates in the syntheses process as a templating agent. For the purposes of this application, however, this alcohol is arbitrarily omitted from the class of templating agents, even if it is present in the as-synthesized ELAPSO material. Since the present ELAPSO compositions are formed from AlO - / 2, PO + / 2, SiO₂ and ELO n / 2 framework oxide units which, respectively, have a net charge of -1, +1, 0 and "n", where "n" is -3, -2, -1, 0 or +1, the matter of cation exchangeability is considerably more complicated than in the case of zeolitic molecular sieves in which, ideally, there is a stoichiometric relationship between AlO - / 2 tetrahedra and charge-balancing cations. In the instant compositions, an AlO - / 2 tetrahedron can be balanced electrically either by association with a PO + / 2 tetrahedron or a simple cation such as an alkali metal cation, a cation of the element "EL" present in the reaction mixture, or an organic cation derived from the templating agent. Similarly, an ELO n / 2 oxide unit can be balanced electrically by association with PO + / 2 tetrahedra, a simple cation such as an alkali metal cation, a cation of the metal "EL", organic cations derived from the templating agent, or other divalent or polyvalent metal cations introduced from an extraneous source. It has also been postulated that non-adjacent AlO - / 2 and PO + / 2 tetrahedral pairs can be balanced by Na⁺ and OH⁻ respectively [Flanigen and Grose, Molecular Sieve Zeolites-I, ACS, Washington, DC (1971)]. The ELAPSO compositions of the present invention may exhibit cation-exchange capacity when analyzed using ion-exchange techniques heretofore employed with zeolitic aluminosilicates and have pore diameters which are inherent in the lattice structure of each species and which are at least about 3Å in diameter. Ion exchange of ELAPSO compositions will ordinarily be possible only after the organic moiety present as a result of synthesis has been removed from the pore system. Dehydration to remove water present in the as-synthesized ELAPSO compositions can usually be accomplished, to some degree at least, in the usual manner without removal of the organic moiety, but the absence of the organic species greatly facilitates adsorption and desorption procedures. The ELAPSO materials will have various degrees of hydrothermal and thermal stability, some being quite remarkable in this regard, and will function as molecular sieve adsorbents and hydrocarbon conversion catalysts or catalyst bases. In the examples a stainless steel reaction vessel is utilized which is lined with an inert plastic material, polytetrafluoroethylene, to avoid contamination of the reaction mixture. In general, the final reaction mixture from which each ELAPSO composition is crystallized is prepared by forming mixtures of less than all of the reagents and thereafter incorporating into these mixtures additional reagents either singly or in the form of other intermediate mixtures of two or more reagents. In some instances the admixed reagents retain their identity in the intermediate mixture and in other cases some or all of the reagents are involved in chemical reactions to produce new reagents. The term "mixture" is applied in both cases. Further, unless otherwise specified, each intermediate mixture as well as the final reaction mixture was stirred until substantially homogeneous. X-ray patterns of reaction products are obtained by X-ray analysis using standard X-ray powder diffraction techniques. The radiation source is a high-intensity, copper target, X-ray tube operated at 50 Kv and 40 mA. The diffraction pattern from the copper K-alpha radiation and graphite monochromator is suitably recorded by an X-ray spectrometer scintillation counter, pulse height analyzer and strip chart recorder. Flat compressed powder samples are scanned at 2° (2 theta) per minute, using a two second time constant. Interplanar spacings (d) in Angstrom units are obtained from the position of the diffraction peaks expressed as 2ϑ where ϑ is the Bragg angle as observed on the strip chart. Intensities are determined from the heights of diffraction peaks after subtracting background, "I₀" being the intensity of the strongest line or peak, and "I" being the intensity of each of the other peaks. Alternatively, the X-ray patterns are obtained from the copper K-alpha radiation by use of computer based techniques using Siemens D-500 X-ray powder diffractometers, Siemens Type K-805 X-ray sources, available from Siemens Corporation, Cherry Hill, New Jersey, with appropriate computer interface. As will be understood by those skilled in the art the determination of the parameter 2 theta is subject to both human and mechanical error, which in combination, can impose an uncertainty of about ±0.4° (denotes plus or minus 0.4) on each reported value of 2 theta. This uncertainty is, of course, also manifested in the reported values of the d-spacings, which are calculated from the 2 theta values. This imprecision is general throughout the art and is not sufficient to preclude the differentiation of the present crystalline materials from each other and from the compositions of the prior art. In some of the X-ray patterns reported, the relative intensities of the d-spacings are indicated by the notations vs, s, m, w and vw which represent very strong, strong, medium, weak, and very weak, respectively. In certain instances the purity of a synthesized product may be assessed with reference to its X-ray powder diffraction pattern. Thus, for example, if a sample is stated to be pure, it is intended only that the X-ray pattern of the sample is free of lines attributable to crystalline impurities, not that there are no amorphous materials present. The molecular sieves of the instant invention may be characterized by their x-ray powder diffraction patterns and such may have one of the x-ray patterns set forth in the following Tables A through W, wherein said x-ray patterns are for both the as-synthesized and calcined forms unless otherwise noted: (ELAPSO-5) 2ϑ d(Å) Relative Intensity 7.2 - 7.7 12.28 - 11.48 m-vs 19.4 - 19.9 4.58 - 4.46 w-m 20.85 - 21.3 4.26 - 4.17 w-vs 22.1 - 22.6 4.02 - 3.93 m-vs 25.6 - 26.1 3.480 - 3.414 vw-m (ELAPSO-11) 2ϑ d(Å) Relative Intensity 7.8 - 8.2 11.19 - 10.85 m-s 9.0 - 9.8 9.83 - 9.03 vw-vs 12.8 - 13.6 6.92 - 6.51 vw-m 19.9 - 20.5 4.46 - 4.33 m-s 20.8 - 21.8 4.27 - 4.08 m-vs 22.0 - 22.6 4.04 - 3.93 m-vs 22.6 - 23.1 3.93 - 3.85 vw-vs 23.1 - 23.5 3.85 - 3.79 w-vs (ELAPSO-14) 2ϑ d(Å) Relative Intensity 8.6 - 8.9 10.3 - 9.93 vs 13.0 6.81 w 21.9 -22.2 4.06 - 4.00 w 25.4 3.51 w 27.5 3.24 w 29.7 3.01 w (ELAPSO-16) 2ϑ d(Å) Relative Intensity 11.3 - 11.6 7.83 - 7.63 w-vs 18.55 - 18.9 4.78 - 4.70 vm-m 21.85 - 22.2 4.07 - 4.00 m-vs 22.8 - 23.3 3.900 - 3.818 w-m 26.4 - 27.3 3.370 - 3.267 w-m 29.6 - 29.9 3.018 - 2.988 w-m (ELAPSO-17) 2ϑ d(Å) Relative Intensity 7.70 - 7.75 11.5 - 11.4 vs 13.4 6.61 s-vs 15.5 -15.55 5.72 - 5.70 s 19.65 -19.7 4.52 - 4.51 w-s 20.5 -20.6 4.33 - 4.31 vs 31.8 -32.00 2.812- 2.797 w-s (ELAPSO-18) 2ϑ d(Å) Relative Intensity 9.6 - 9.65 9.21 - 9.16 vs 15.5 -15.55 5.72 - 5.70 m 16.9 -17.1 5.25 - 5.19 m 20.15-20.25 4.41 - 4.39 m 20.95-21.05 4.24 - 4.22 m 31.8 -32.5 2.814- 2.755 m (ELAPSO-20) 2ϑ d(Å) Relative Intensity 13.8 - 14.2 6.42 - 6.23 m-vs 19.6 - 20.15 6.53 - 4.41 m 24.1 - 24.7 3.695 - 3.603 m-vs 27.9 - 28.6 3.198 - 3.121 w 31.3 - 32.05 2.861 - 2.791 w 34.35 - 35.0 2.610 - 2.601 w-m (ELAPSO-31) 2ϑ d(Å) Relative Intensity 8.4 - 9.5 10.53 - 9.31 w-s 20.2 - 20.4 4.40 - 4.35 m 22.0 - 22.1 4.040 - 4.022 m 22.5 - 22.7 3.952 - 3.92 vs 31.6 - 31.8 2.831 - 2.814 w-m (ELAPSO-33) 2ϑ d(Å) Relative Intensity 9.25 - 9.55 9.56 - 9.26 w-m 12.5 - 12.9 7.08 - 6.86 vs 16.9 - 17.3 5.25 - 5.13 w-m 20.45 - 20.9 4.34 - 4.25 w-m 23.85 - 24.25 3.73 - 3.67 w-m 26.05 - 26.35 3.42 - 3.38 w-m 27.3 - 27.6 3.27 - 3.23 vs (ELAPSO-33) 2ϑ d(Å) Relative Intensity 13.15 - 13.4 6.73-6.61 vs 18.05 - 18.35 4.91-4.83 m 18.4 - 18.6 4.82-4.77 m 26.55 - 26.7 3.36-3.34 m 32.0 - 32.1 2.80-2.79 m (ELAPSO-34) 2ϑ d(Å) Relative Intensity 9.3 - 9.8 9.51 - 9.03 m-vs 12.6 - 13.2 7.03 - 6.71 w-m 15.8 - 16.3 5.61 - 5.44 vw-m 20.25 - 21.2 4.39 - 4.19 w-vs 24.8 - 25.4 3.59 - 3.507 vw-m 30.0 - 30.9 2.979 - 2.894 vw-m (ELAPSO-35) 2ϑ d(Å) Relative Intensity 10.6 - 11.1 8.35 - 7.97 vw-vs 13.1 - 13.7 6.76 - 6.46 vw-vs 17.0 - 17.6 5.22 - 5.04 w-s 20.6 - 21.25 4.31 - 4.18 vw-m 21.6 - 22.3 4.11 - 3.99 m-vs 28.1 - 28.8 3.175 - 3.100 vw-m (ELAPSO-36) 2ϑ d(Å) Relative Intensity 7.45 - 8.0 11.14 - 11.05 vs 8.1 - 8.3 10.91 - 10.65 w-m 16.3 - 16.6 5.44 - 5.34 w-m 18.9 - 19.4 4.70 - 4.57 w-m 20.7 - 21.0 4.29 - 4.23 w-m (ELAPSO-37) 2ϑ d(Å) Relative Intensity 6.1 - 6.3 14.49 - 14.03 vs 15.5 - 15.7 5.72 - 5.64 w-m 18.5 - 18.8 4.80 - 4.72 w-m 23.5 - 23.7 3.79 - 3.75 w-m 26.9 - 27.1 3.31 - 3.29 w-m (ELAPSO-39) 2ϑ d(Å) Relative Intensity 9.2 - 9.6 9.61 - 9.21 m 13.1 - 13.5 6.76 - 6.56 m 17.8 - 18.4 4.98 - 4.82 w-m 20.8 - 21.3 4.27 - 4.17 m-vs 22.2 - 22.85 4.00 - 3.892 m-vs 26.4 - 27.05 3.376 - 3.296 w-m (ELAPSO-40) 2ϑ d(Å) Relative Intensity 7.5 - 7.7 11.79 - 11.48 vw-m 8.0 - 8.1 11.05 - 10.94 s-vs 12.4 - 12.5 7.14 - 7.08 w-vs 13.6 - 13.8 6.51 - 6.42 m-s 14.0 - 14.1 6.33 - 6.28 w-m 27.8 - 28.0 3.209- 3.187 w-m (ELAPSO-41) 2ϑ d(Å) Relative Intensity 13.6 - 13.8 6.51 - 6.42 w-m 20.5 - 20.6 4.33 - 4.31 w-m 21.1 - 21.3 4.21 - 4.17 vs 22.1 - 22.3 4.02 - 3.99 m-s 22.8 - 23.0 3.90 - 3.86 m 23.1 - 23.4 3.82 - 3.80 w-m 25.5 - 25.9 3.493- 3.44 w-m (ELAPSO-42) 2ϑ d(Å) Relative Intensity 7.15 - 7.4 12.36 - 11.95 m-vs 12.5 - 12.7 7.08 - 6.97 m-s 21.75 - 21.9 4.09 - 4.060 m-s 24.1 - 24.25 3.69 - 3.67 vs 27.25 - 27.4 3.273- 3.255 s 30.05 - 30.25 2.974- 2.955 m-s (ELAPSO-43) 2ϑ d(Å) Relative Intensity 12.3 - 12.95 7.20 - 6.83 m-vs 16.8 - 17.45 5.28 - 5.09 vw-w 21.45 - 21.85 4.145 - 4.071 m-vs 27.1 - 27.85 3.291 - 3.232 w-vs 32.4 - 33.2 2.763 - 2.699 vw-m (ELAPSO-44) 2ϑ d(Å) Relative Intensity 9.2 - 9.6 9.61 - 9.21 m-vs 15.9 - 16.3 5.57 - 5.44 vw-m 20.5 - 21.0 4.33 - 4.23 m-vs 24.3 - 25.1 3.66 - 3.548 w-m 30.5 - 31.1 2.931 - 2.876 vw-m (ELAPSO-46) 2ϑ d(Å) Relative Intensity 7.2 - 8.1 12.28 - 10.92 vs 12.9 - 13.6 6.86 - 6.51 vw 21.2 - 22.2 4.19 - 4.501 vw-m 22.5 - 23.45 3.95 - 3.793 vw-m 26.6 - 27.9 3.351 - 3.198 vw-m (ELAPSO-47) 2ϑ d(Å) Relative Intensity 9.4 - 9.6 9.41 - 9.21 vs 12.8 - 13.1 6.92 - 6.76 vw-m 16.0 - 16.3 5.54 - 5.44 vw-m 20.5 - 21.0 4.31 - 4.23 m-vs 24.6 - 25.3 3.613 - 3.526 vm-m 30.6 - 31.1 2.921 - 2.876 vw-m The following examples are provided to further illustrate the invention. IV. ELAPSO MOLECULAR SIEVE COMPOSITIONS The ELAPSO molecular sieves of the invention may be prepared having one or more elements present as framework oxide units such that the ELAPSO molecular sieves contain framework oxide units "ELO₂", ALO - / 2, PO + / 2 and SiO₂ where "EL" denominates at least one element capable of forming a framework oxide unit with AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units. The following ELAPSO molecular sieves are representative of molecular sieves prepared according to the instant invention: A. COBALT-ALUMINUM-PHOSPHORUS-SILICON-OXIDE MOLECULAR SIEVES: Molecular sieves containing cobalt, aluminum, phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the CoAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: (a) Alipro: aluminum isoproproxide; (b) CATAPAL: Trademark of Condea Corporation for pseudoboehmite; (c) LUDOX-LS: Trademark of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; (d) Co(Ac)₂: cobalt acetate Co(C₂H₃O₂)₂· 4H₂O; (e) CoSO₄: cobalt sulfate (CoSO₄· 7H₂O); (f) H₃PO₄: 85 weight percent phosphoric acid in water; (g) TBAOH: tetrabutylammonium hydroxide (25 wt % in methanol); (h) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH; (i) Pr₃N: tri-n-propylamine, (C₃H₇)₃N; (j) Quin: Quinuclidine (C₇H₁₃N); (k) MQuin: Methyl Quinuclidine hydroxide, (C₇H₁₃NCH₃OH); (l) C-hex: cyclohexylamine; (m) TEAOH; tetraethylammonium hydroxide (40 wt. % in water); (n) DEEA: diethanolamine; (o) TPAOH: tetrapropylammonium hydroxide (40wt.% in water); and (p) TMAOH: tetramethylammonium hydroxide (40 wt.% in water) Preparative Procedure The CoAPSO compositions were prepared by preparing reaction mixtures having a molar composition expressed as: eR:fCoO:hAl₂O₃:iP₂O₅:gSiO₂:jH₂O wherein e, f, h, i, g and j represent the moles of template R, cobalt (expressed as the oxide), Al₂O₃, P₂O₅ (H₃PO₄ expressed as P₂O₅), SiO₂ and H₂O, respectively. The values for e, f, h, i, g and j were as set forth in the hereinafter discussed preparative examples. The reaction mixtures were prepared by forming a starting reaction mixture comprising the H₃PO₄ and one half of the water. This mixture was stirred and the aluminum source (Alipro or CATAPAL) added. The resulting mixture was blended until a homogeneous mixture was observed. The LUDOX-LS was then added to the resulting mixture and the new mixture blended until a homogeneous mixture was observed. The cobalt source (Co(Ac)₂, Co(SO₄) or mixtures thereof) was dissolved in the remaining water and combined with the first mixture. The combined mixture was blended until a homogenous mixture was observed. The organic templating agent was added to this mixture and blended for about two to four minutes until a homogenous mixture was observed. The resulting mixture (final reaction mixture) was placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at a temperature (150°C, 200°C or 225°C) for a time. Alternatively, if the digestion temperature was 100°C the final reaction mixture was placed in a lined (polytetrafluoroethylene) screw top bottle for a time. All digestions were carried out at the autogeneous pressure. The products were removed from the reaction vessel cooled and evaluated as set forth hereinafter. The following examples are provided to further illustrate the invention and are not intended to be limiting thereof: Examples 1A to 31A CoAPSO molecular sieves were prepared according to the above described procedure and the CoAPSO products determined by x-ray analysis. The results of examples 1A to 31A are set forth in Tables I-A and II-A. Tables I-A and II-A also contain examples AA to EA wherein X-ray analysis of the reaction mixture product did not show CoAPSO products. In the Tables I-A and II-A, the reaction mixtures are described as the ratio of molar oxides: eR:fCoO:0.9Al₂O₃:0.9P₂O₅:gSiO₂:50H₂O where "e", "R", "f" and "g" are as above defined. Examples were prepared using this reaction mixture unless otherwise noted in Tables I-A to II-A. The values for "e", "f" and "g" are given in Tables I-A and II-A. Examples 32A to 61A Examples 32A to 61A were carried out using di-n-propylamine as the organic templating agent. The preparative procedure was as above described except that in examples 39A to 45A and 53A to 61A the preparative procedure was modified such that the cobalt acetate was added to the phosphoric acid and water, followed by addition of the aluminum source, silicon source and then the organic templating agent. The aluminum source in examples 32A to 45A, 60A and 61A was aluminum isoproproxide and in examples 46A to 59A the aluminum source was CATAPAL. The reaction mixtures for examples 32A to 61A are described in terms of the molar oxide ratios: ePr₂NH:0.2CoO:0.9Al₂O₃ :0.9P₂O₅ ;0.2SiO₂: 50H₂O where "e" is the moles of template Pr₂NH and where "e" was one (1) for examples 32A to 35A, 42A to 45A, 49A to 52A, 56A to 61A and "e" was two (2) for examples 36A to 41A, 46A to 48A, 53A to 55A. Examples FA, GA, HA and IA are reaction mixtures where X-ray analysis of the reaction products did not show CoAPSO products. Examples 32 to 61 and F, G, H, and I are set forth in Table III. Examples 62A to 83A Examples 62A to 83A were carried out according to the preparative procedure employed in examples 1A to 31A except that the organic templating agent was as TEAOH (tetraethylammonium hydroxide). The reaction mixtures for examples 62A to 83A were: 1.0TEAOH:fCoO:0.9Al₂O₃:0.9P₂O₅:gSiO₂:50H₂O wherein "f" was 0.2 except that "f" was 0.1 for examples 78A to 79A and was 0.05 for examples 80A to 83A; and g was 0.2 for examples 62A to 70A and was 0.6 for examples 71A to 83A. The reactive cobalt source was cobalt (II) sulfate for examples 62A to 70A and cobalt (II) acetate for examples 71A to 83A. The results of examples 62A to 83A are set forth in Table IV-A. Examples 84A to 106A Examples 84A to 106A were carried out according to the preparative procedure employed in examples 1A to 31A except the organic template was as is shown in Table V-A. The reaction mixture was: eR:f5CoO:0.9 Al₂O₃:0.9 P₂O₅:0.6 SiO₂:5O H₂O where "e" was one (1) except that "e" was 1.5 for examples 94A to 97A and "e" was 2.0 for example 104A. The results of examples 84A to 106A are set forth in Table V-A. Example 107A Samples of the products were subjected to chemical analysis. The chemical analysis for each product is given hereinafter with the example in which the CoAPSO was prepared being given in parenthesis after the designation of the CoAPSO species. (a) The chemical analysis for CoAPSO-11 (example 35A) was: Component Weight Percent Al₂O₃ 31.1 P₂O₅ 46.1 CoO 6.4 SiO₂ 3.5 Carbon 5.2 LOI 11.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.085 CoO; 0.305 Al₂O₃: 0.325 P₂O₅:0.058SiO₂; and a formula (anhydrous basis) of: 0.07R(Co 0.06 Al 0.47 P 0.46 Si 0.04 )O₂ (b) The chemical analysis for CoAPSO-11 (example 42A) was: Component Weight Percent Al₂O₃ 32.5 P₂O₅ 44.7 CoO 4.4 SiO₂ 1.4 Carbon 3.9 LOI 15.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.059 CoO; 0.319 Al₂O₃: 0.315 P₂O₅: 0.023 SiO₂; and a formula (anhydrous basis) of: 0.05R(Co 0.04 Al 0.47 P 0.47 Si 0.02 )O₂ (c) The chemical analysis for CoAPSO-20 (example 106A) was: Component Weight Percent Al₂O₃ 27.7 P₂O₅ 37.8 CoO 4.6 SiO₂ 10.0 Carbon 9.4 LOI 18.4 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.061 CoO: 0.272 Al₂O₃: 0.266 P₂O₅: 0.166 SiO₂; and a formula (anhydrous basis) of: 0.20R(Co 0.05 Al 0.42 P 0.41 Si 0.13 )O₂ (d) The chemical analysis of CoAPSO-31 (example 101A) was: Component Weight Percent Al₂O₃ 32.3 P₂O₅ 42.4 CoO 4.3 SiO₂ 3.8 Carbon 2.8 LOI 16.6 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.057 CoO; 0.317 Al₂O₃: 0.299 P₂O₅: 0.063 SiO₂; and a formula (anhydrous basis) of: 0.04R(Co 0.04 Al 0.47 P 0.44 Si 0.05 )O₂ (e) The chemical analysis for CoAPSO-34 (example 69A) was: Component Weight Percent Al₂O₃ 28.2 P₂O₅ 41.7 CoO 4.7 SiO₂ 1.1 Carbon 5.9 LOI 23.6 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.063 CoO; 0.277 Al₂O₃: 0.294 P₂O₅: 0.018 SiO₂; and a formula (anhydrous basis) of: 0.06R(Co 0.05 Al 0.45 P 0.48 Si 0.02 )O₂ (f) The chemical analysis of CoAPSO-34 (example 72A) was: Component Weight Percent Al₂O₃ 28.4 P₂O₅ 40.6 CoO 4.6 SiO₂ 2.2 Carbon 7.8 LOI 23.3 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.061 CoO; 0.279 Al₂O₃: 0.282 P₂O₅: 0.037 SiO₂; and a formula (anhydrous basis) of: 0.08R(Co 0.05 Al 0.46 P 0.46 Si 0.03 )O₂ (g) The chemical analysis for CoAPSO-34 (example 79A) was: Component Weight Percent Al₂O₃ 31.7 P₂O₅ 40.5 CoO 2.5 SiO₂ 3.4 Carbon 8.4 LOI 20.8 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.033CoO:0.311 Al₂O₃: 0.285 P₂O₅: 0.057S.io₂; and a formula (anhydrous basis) of: 0.09R(Co 0.03 Al 0.49 P 0.45 Si 0.05 )O₂ 0.09R(Co 0.03 Al 0.49 P 0.45 Si 0.05 )O₂ (h) The chemical analysis of CoAPSO-34 (example 81A) was: Component Weight Percent Al₂O₃ 32.0 P₂O₅ 39.6 CoO 1.2 SiO₂ 2.7 Carbon 6.4 LOI 22.8 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.016 CoO; 0.314 Al₂O₃: 0.279 P₂O₅: 0.045 SiO₂; and a formula (anhydrous basis) of: 0.07R(Co 0.01 Al 0.50 P 0.45 Si 0.04 )O₂ (i) The chemical analysis of CoAPSO-34 (example 83A) was: Component Weight Percent Al₂O₃ 33.8 P₂O₅ 40.6 CoO 1.6 SiO₂ 2.1 Carbon 6.6 LOI 21.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.021 CoO:O.332Al₂O₃:0.286 P₂O₅:O.035SiO₂; and a formula (anhydrous basis) of: 0.07R(Co 0.02 Al 0.53 P 0.46 Si 0.03 )O₂ (j) The chemical analysis of CoAPSO-34 (example 77A) was: Component Weight Percent Al₂O₃ 30.1 P₂O₅ 41.7 CoO 4.8 SiO₂ 2.6 Carbon 9.0 LOI 19.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.064 CoO; 0.295 Al₂O₃: 0.294 P₂O₅: 0.043 SiO₂;and a formula (anhydrous basis) of: 0.09R(Co 0.05 Al 0.46 P 0.46 Si 0.03 )O₂ (k) The chemical analysis of CoAPSO-34 (example 89A) was: Component Weight Percent Al₂O₃ 31.8 P₂O₅ 38.8 CoO 0.71 SiO₂ 2.2 Carbon 6.6 LOI 24.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.01 CoO; 0.312 Al₂O₃: 0.273 P₂O₅: 0.037 SiO₂; and a formula (anhydrous basis) of: 0.07R(Co 0.01 Al 0.51 P 0.45 Si 0.03 )O₂ where the value for cobalt is rounded off from 0.008. (l) The chemical analysis of CoAPSO-34 (example 90A) was: Component Weight Percent Al₂O₃ 32.4 P₂O₅ 39.3 CoO 0.66 SiO₂ 3.5 Carbon 7.2 LOI 23.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.009 CoO; 0.318 Al₂O₃: 0.277 P₂O₅: 0.058 SiO₂; and a formula (anhydrous basis) of: 0.08R(Co 0.01 Al 0.51 P 0.44 Si 0.05 )O₂ where the value for cobalt is rounded off from 0.007. (m) The chemical analysis of CoAPSO-35 (example 10A) was: Component Weight Percent Al₂O₃ 27.0 P₂O₅ 41.6 CoO 4.3 SiO₂ 4.3 Carbon 13.0 LOI 22.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.057 CoO; 0.265 Al₂O₃: 0.290 P₂O₅: 0.054 SiO₂; and a formula (anhydrous basis) of: 0.14R(Co 0.05 Al 0.43 P 0.48 Si 0.04 )O₂ (n) The chemical analysis of CoAPSO-36 (example 93A) was: Component Weight Percent Al₂O₃ 29.5 P₂O₅ 39.6 CoO 5.2 SiO₂ 6.6 Carbon 3.3 LOI 18.5 The above chemical analysts gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.069 CoO; 0.289 Al₂O₃: 0.279 P₂O₅: 0.110 SiO₂; and a formula (anhydrous basis) of: 0.03R(Co 0.05 Al 0.44 P 0.42 Si 0.08 )O₂ (o) The chemical analysis of CoAPSO-44 (example 19A) was: Component Weight Percent Al₂O₃ 26.3 P₂O₅ 36.3 CoO 4.5 SiO₂ 10.0 Carbon 13.2 LOI 22.6 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.06 CoO; 0.258 Al₂O₃: 0.256 P₂O₅: 0.166 SiO₂; and a formula (anhydrous basis) of: 0.18R(Co 0.05 Al 0.41 P 0.41 Si 0.13 )O₂ (p) The chemical analysis of CoAPSO-46 (example 36A) was: Component Weight Percent Al₂O₃ 31.4 P₂O₅ 31.5 CoO 6.2 SiO₂ 2.9 Carbon 4.2 LOI 27.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.08 CoO; 0.31 Al₂O₃: 0.22 P₂O₅: 0.05 SiO₂; and a formula (anhydrous basis) of: 0.06R(Co 0.07 Al 0.52 P 0.37 Si 0.04 )O₂ (q) The chemical analysis of CoAPSO-47 (example 104A) was: Component Weight Percent Al₂O₃ 22.7 P₂O₅ 39.8 CoO 8.2 SiO₂ 2.9 Carbon 11.4 LOI 25.2 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.109 CoO; 0.223 Al₂O₃: 0.280 P₂O₅: 0.048 SiO₂; and a formula (anhydrous basis) of: 0.16R(Co 0.09 Al 0.38 P 0.48 Si 0.04 )O₂ Example 108A EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction with SEM (scanning electron microscope) was carried out on clean crystals of CoAPSO products. Analysis of crystals having a morphology characteristic of the CoAPSO compositions noted hereinafter gave the following analysis based on relative peak heights: a) CoAPSO-11 (example 42A) : Average of Spot Probes Co 1.0 Al 8.0 P 10.0 Si 1.0 b) CoAPSO-20 (example 106A) : Average of Spot Probes Co 0.5 Al 8.0 P 7.5 Si 3.4 c) CoAPSO-34 (example 69A) : Average of Spot Probes Co 0.5 Al 8.0 P 10.0 Si 1.0 d) CoAPSO-35 (example 10A) : Average of Spot Probes Co 0.5 Al 9.0 P 7.5 Si 1.0 e) CoAPSO-36 (example 95A) : Average of Spot Probes Co 0.6 Al 9.1 P 9.4 Si 2.2 f) CoAPSO-44 (example 16A) : Average of Spot Probes Co 1.0 Al 8.0 P 8.0 Si 0.6 g) CoAPSO-47 (example 104A) : Average of Spot Probes Co 0.7 Al 8.4 P 9.2 Si 2.8 Example 109A Samples of the CoAPSO products were tested for adsorption capacities. The CoAPSO products were evaluated either in the as-synthesized form or were calcined in air or nitrogen, to remove at least part of the organic templating agent, as hereinafter set forth. The adsorption capacities of each calcined sample were measured using a standard McBain - Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum at 350°C prior to measurement. The McBain-Bakr data for the aforementioned calcined CoAPSO products were: a) CoAPSO-11 (example 61A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 106 -183 6.9 O₂ 3.46 744 -183 12.1 isobutane 5.0 740 24.2 3.9 cyclo-hexane 6.0 82 23.9 13.5 neopentane 6.2 741 25.3 3.6 H₂O 2.65 4.6 24.9 7.1 H₂O 2.65 19 24.8 21.0 The above data demonstrate that the pore size of the calcined product is about 6.0 Å. b) CoAPSO-20 (example 106A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 5 O₂ 3.46 744 -183 6.4 H₂O 2.65 4.6 23.3 10 H₂O 2.65 19 23.2 14 The above data demonstrate that the pore size of the calcined product is about 3.0Å. c) CoAPSO-31 (example 102A); Adsorbate Kinetic Diameter, A Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 105 -183 6.9 O₂ 3.46 741 -183 12.8 neopentane 6.2 739 23.5 5.8 H₂O 2.65 4.6 23.5 5.8 H₂O 2.65 20 24.0 15.9 The above data demonstrate that the pore size of the calcined product is greater than about 6.2Å. d) CoAPSO-34 (example 78A): The above data demonstrate that the pore size of the calcined product is about 4.3Å. e) CoAPSO-34 (example 89A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 105 -183 18.6 O₂ 3.46 741 -183 28.8 isobutane 5.0 108 23.9 9.9 n-hexane 4.3 742 23.3 1.2 H₂O 2.65 4.6 23.8 10.7 H₂O 2.65 20.0 24.0 30.1 f) CoAPSO-35 (example 8A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 103 -183 11.7 O₂ 3.46 731 -183 15.5 iso-butane 5.0 741 24.5 0.6 n-hexane 4.3 103 24.4 3.5 H₂O 2.65 4.6 24.4 14.3 H₂O 2.65 18.5 23.9 22.7 The above data demonstrate that the pore size of the calcined product is about 4.3Å. g) CoAPSO-44 (example 19A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 103 -183 24.8 O₂ 3.46 731 -183 31.4 n-hexane 4.3 103 24.4 7.4 isobutane 5.0 741 24.5 0.3 H₂O 2.65 4.6 24.4 27.8 H₂O 2.65 18.5 23.9 35.1 The above data demonstrate that the pore size of the calcined product is about 4.3Å. h) CoAPSO-47 (example 104A): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 4.1 O₂ 3.46 744 -183 4.9 isobutane 5.0 746 24.1 0.6 n-hexane 4.3 95 23.6 1.3 H₂O 2.65 4.6 23.3 9.6 H₂O 2.65 19 23.2 14.3 The above data demonstrate that the pore size of the calcined product is about 4.3Å. Example 110A (a) The as-synthesized CoAPSO-5 of example 76A was subjected to analysis by x-ray. The CoAPSO-5 product was characterized by the x-ray powder diffraction pattern of Table VII-A below: 2ϑ d,(Å) 100 x I/Io 7.4 11 .95 100 9.6 9.21 65 12.9 6.86 19 14.1 6.28 10 14.9 5.95 26 16.0 5.54 32 17.8 4.98 13 19.8 4.48 61 20.5 4.33 55 21.1 4.21 74 22.4 3.97 94 23.0 3.87 10 24.8 3.59 16 25.2 3.53 16 26.0 3.427 42 27.4 3.255 13 28.2 3.164 10 29.1 3.069 19 29.5 3.028 10 30.1 2.969 29 30.6 2.921 23 31.1 2.876 19 33.7 2.660 10 34.5 2.600 19 37.0 2.430 7 37.7 2.386 16 41.5 2.176 7 42.2 2.141 8 43.7 2.071 7 44.9 2.019 7 47.8 1.903 10 48.9 1.863 10 55.8 1.647 10 (b) CoAPSO-5, of example 21A was calcined in air at 600° for four hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table VIII-A below: 2ϑ d,(Å) I/Io x 100 7.4 11.95 100 12.9 6.86 22 14.8 5.99 13 19.7 4.51 39 20.3 4.37 83 21.0 4.23 74 21.4 4.15 99 22.4 3.97 74 22.9 3.88 35 24.4 3.65 13 25.9 3.440 30 27.1 3.290 17 28.1 3.175 26 29.0 3.079 26 30.1 2.969 30 33.7 2.660 13 34.6 2.592 22 35.6 2.522 26 37.0 2.430 13 37.8 2.380 13 42.8 2.113 13 43.8 2.067 9 47.8 1.903 9 55.8 1.647 9 (c) The species denominated herein as CoAPSO-5 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" are the mole fractions as above defined with reference to FIG. 1 or FIG. 2: and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table IX-A: 2ϑ d,(Å) Relative Intensity 7.3-7.5 12.11-11.79 m-vs 14.7-14.9 6.03-5.95 w-m 19.6-19.8 4.53-4.48 w-m 20.9-21.2 4.25-4.19 w-vs 22.3-22.4 3.99-3.97 m-vs 25.8-26.0 3.453-3.427 vw-m (d) The CoAPSO-5 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table X-A: 2ϑ d,(Å) I/Io x 100 7.3-7.5 12.11-11.79 32-100 12.7-12.9 6.97-6.86 2-22 14.7-14.9 6.03-5.95 10-26 19.6-19.8 4.53-4.48 7-39 20.9-21.2 4.25-4.19 19-100 22.3-22.4 3.99-3.97 25-94 24.4-24.8 3.65-3.59 2-16 25.8-26.0 3.453-3.427 6-41 29.0-29.1 3.079-3.069 3-26 29.9-30.1 2.988-2.969 3-30 33.5-33.7 2.667-2.660 2-13 34.4-34.6 2.607-2.592 4-22 36.8-37.0 2.442-2.430 2-13 37.5-37.8 2.398-2.380 3-16 41.4-41.5 2.181-2.176 1-7 42.2-42.8 2.141-2.113 1-13 43.7-43.8 2.071-2.067 0-9 44.9-45.0 2.019-2.014 1-7 47.5-47.8 1.914-1.903 3-10 55.6-55.8 1.653-1.647 1-10 Example 111 A (a) The as-synthesized CoAPSO-11 of example 42A was subjected to analysis by x-ray. The CoAPSO-11 product was characterized by the x-ray powder diffraction pattern of Table XI-A below: 2ϑ d,(Å) 100 x I/Io 7.9 11.19 32 9.3 9.51 72 12.3 7.20 16 13.1 6.76 24 15.6 5.68 32 16.2 5.47 12 18.2 4.87 16 18.9 4.70 12 20.3 4.37 40 21.0 4.23 100 22.1 4.02 56 22.5 3.95 60 22.7 3.92 72 23.1 3.85 68 24.6 3.62 20 26.3 3.389 28 28.2 3.164 16 28.5 3.132 24 29.4 3.038 20 29.6 3.018 16 29.9 2.988 16 31.3 2.858 16 32.6 2.747 24 34.0 2.637 16 36.3 2.475 12 37.6 2.392 20 39.3 2.292 12 42.8 2.113 8 44.8 2.023 8 50.5 1.807 12 54.4 1.687 12 (b) CoAPSO-11, of example 42A was calcined in air at 600° for 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table XII-A below: 2ϑ d,(Å) 100 x I/Io 8.1 10.92 70 9.5 9.31 83 13.1 6.76 26 13.5 6.56 30 15.8 5.61 56 18.5 4.80 17 19.2 4.62 13 20.2 4.40 sh 20.3 4.37 35 21.3 4.17 100 22.3 3.99 61 22.5 3.95 sh 23.0 3.87 65 23.4 3.80 52 24.3 3.66 17 25.1 3.548 17 26.5 3.363 30 26.6 3.351 sh 28.2 3.164 13 28.9 3.089 26 29.5 3.028 17 30.1 2.969 13 30.5 2.931 17 31.8 2.814 17 32.9 2.722 22 34.7 2.585 13 36.2 2.481 13 37.9 2.374 17 38.3 2.350 17 39.5 2.281 9 (c) The species denominated herein as CoAPSO-11 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XIII-A: 2ϑ d,(Å) Relative Intensity 7.9-8.1 11.19-10.92 m 9.3-9.5 9.51-9.31 m-s 21.0-21.3 4.23-4.17 vs 22.1-22.3 4.02-3.99 m 22.7-23.1 3.92-3.85 m 23.2-23.4 3.83-3.80 m (d) The CoAPSO-11 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XIV-A: Example 112-A (a) The as-synthesized CoAPSO-16 of example 4A was subjected to analysis by x-ray. The CoAPSO-16 product was characterized by the x-ray powder diffraction pattern of Table XV-A below: (b) The species denominated herein as CoAPSO-16 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XVI-A: 2ϑ d,(Å) Relative Intensity 11.4-11.6 7.76-7.63 w-s 17.2-17.4 5.16-5.10 m 18.7-18.9 4.75-4.70 vw-m 21.9-22.1 4.06-4.02 vs 23.1-23.3 3.85-3.82 m 26.8-27.0 3.326-3.302 m 29.8-29.9 2.998-2.988 w-m (c) The CoAPSO-16 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XVII-A: 2ϑ d,(Å) 100 x I/Io 11.4-11.6 7.76-7.63 11-79 17.2-17.4 5.16-5.10 66-80 18.7-18.9 4.75-4.70 7-53 21.9-22.1 4.06-4.02 100 23.1-23.3 3.85-3.82 21-24 26.8-27.0 3.326-3.302 23-28 29.0 3.079 14-18 29.5-29.7 3.028-3.008 4-15 29.8-29.9 2.998-2.988 15-29 32.7-32.9 2.739-2.722 3-9 34.5-34.7 2.600-2.585 9-13 37.8-38.0 2.380-2.368 6-9 40.0-40.2 2.534-2.243 1-9 44.3-44.6 2.045-2.032 2-9 48.5-48.7 1.877-1.870 8-13 49.5-49.7 1.841-1.834 8-11 51.5-51.7 1.774-1.768 6-11 52.5-52.7 1.743-1.737 6-7 54.9-55.1 1.672-1.667 1-6 Example 113A (a) The as-synthesized CoAPSO-20 of example 106A was subjected to analysis by x-ray. The CoAPSO-20 product was characterized by the x-ray powder diffraction pattern of Table XVIII-A below: 2ϑ d,(Å) 100 x I/Io 10.293 8.5942 7 12.078 7.3278 1 13.925 6.3595 46 14.376 6.1609 2 18.773 4.7268 2 19.738 4.4977 42 20.507 4.3307 3 22.093 4.0233 3 24.227 3.6735 100 26.363 3.3806 3 26.941 3.3094 3 28.052 3.1808 11 31.442 2.8451 11 31.759 2.8175 2 31.980 2.7985 2 34.523 2.5980 16 37.426 2.4029 1 40.075 2.2499 4 42.614 2.1215 4 47.3 1.922 4 51.8 1.765 8 (b) CoAPSO-20, of example 106A was calcined in air at 500° for one hour. The calcined product was characterized by the x-ray powder diffraction pattern of Table XIX-A below: 2ϑ d,(Å) 100 x I/Io 10.6 8.39 7 21.1 7.30 3 12.2 7.24 2 14.0 6.33 75 14.8 6.01 3 16.1 5.51 2 19.8 4.48 38 22.2 4.01 4 24.3 3.66 100 26.7 3.344 3 27.6 3.227 2 28.1 3.173 14 31.5 2.839 13 32.2 2.781 2 32.4 2.764 2 34.6 2.593 18 40.2 2.244 3 42.5 2.127 4 47.3 1.922 4 51.8 1.765 8 (c) The species denominated herein as CoAPSO-20 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XX-A: 2ϑ d,(Å) Relative Intensity 13.9-14.0 6.37-6.33 m 19.7-19.8 4.51-4.48 m 24.2-24.3 3.68-3.66 vs 28.0-28.1 3.187-3.175 w 31.4-31.5 2.849-2.840 w 34.5-34.6 2.600-2.592 w (d) The CoAPSO-20 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXI-A: Example 114A (a) The as-synthesized CoAPSO-31 of example 101A was subjected to analysis by x-ray. The CoAPSO-31 product was characterized by the x-ray powder diffraction pattern of Table XXII-A below: 2ϑ d,(Å) 100 x I/Io 8.5 10.35 58 17.1 5.19 5 18.4 4.82 2 20.3 4.38 42 21.1 4.20 4 22.1 4.03 28 22.7 3.93 100 23.2 3.83 2 25.2 3.537 4 25.7 3.464 3 28.0 3.187 12 29.8 3.000 6 31.8 2.816 20 35.2 2.549 9 36.2 2.482 2 37.2 2.417 2 37.7 2.386 2 38.3 2.352 2 39.4 2.288 3 39.7 2.271 2 40.3 2.239 2 45.3 2.002 2 46.8 1.943 2 48.7 1.869 2 51.7 1.768 4 (b) CoAPSO-31 of part (a) was calcined in air at 500° for 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXIII-A below: 2ϑ d,(Å) 100 x I/Io 8.5 10.36 73 14.8 5.99 4 17.1 5.19 10 18.4 4.81 4 20.3 4.37 56 21.4 4.15 3 22.1 4.03 47 22.7 3.93 100 23.4 3.80 3 25.2 3.530 6 25.7 3.464 7 28.0 3.184 15 29.8 2.300 10 31.0 2.885 2 31.8 2.813 31 35.2 2.548 10 36.3 2.476 5 37.3 2.409 3 37.7 2.385 3 38.3 2.348 3 39.4 2.287 4 39.7 2.270 3 40.3 2.237 3 46.7 1.944 5 47.6 1.910 3 48.7 1.868 3 49.3 1.849 2 51.7 1.768 6 (c) The species denominated herein as CoAPSO-31 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXIV-A: 2ϑ d,(Å) Relative Intensity 8.5-8.6 10.40-10.28 m 20.2-20.3 4.40-4.37 m 22.0-22.1 4.04-4.02 m 22.6-22.7 3.93-3.92 vs 28.0-28.1 3.187-3.175 w 31.7-31.8 2.823-2.814 m (d) The CoAPSO-31 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXV-A: 2ϑ d,(Å) 100 x I/Io 8.5-8.6 10.40-10.28 58-73 14.7-14.8 6.03-5.99 2-4 17.0-17.2 5.22-5.16 5-10 18.4-18.5 4.82-4.80 2-4 20.2-20.3 4.40-4.37 42-56 21.1-21.4 4.21-4.15 3-4 22.0-22.1 4.04-4.02 28-47 22.6-22.7 3.93-3.92 100 23.2-23.4 3.83-3.80 2-3 25.1-25.2 3.548-3.534 4-6 25.7-25.8 3.466-3.453 3-7 28.0-28.1 3.187-3.175 12-15 29.7-29.8 3.008-2.998 6-10 31.0-31.1 2.885-2.876 2-4 31.7-31.8 2.823-2.814 20-31 35.2-35.3 2.550-2.543 9-10 36.2-36.3 2.481-2.475 2-5 37.2-37.3 2.417-2.411 2-3 37.7-37.8 2.386-2.380 2-3 38.2-38.4 2.356-2.344 2-3 39.3-39.4 2.292-2.287 3-4 39.6-39.7 2.276-2.270 2-3 40.2-40.3 2.243-2.238 2-3 45.2-45.3 2.006-2.002 1-2 46.7-46.8 1.945-1.941 2-5 47.5-47.6 1.914-1.910 2-3 48.7-48.8 1.870-1.866 2-3 49.2-49.3 1.852-1.848 1-2 51.6-51.7 1.771-1.768 4-6 Example 115A (a) The as-synthesized CoAPSO-34 of example 90A was subjected to analysis by x-ray. The CoAPSO-34 product was characterized by the x-ray powder diffraction pattern of Table XXVI-A below: 2ϑ d,(Å) 100 x I/Io 9.6 9.22 100 12.9 6.84 11 14.2 6.26 10 16.1 5.51 35 18.1 4.92 15 20.7 4.29 62 22.3 3.98 3 23.2 3.84 4 25.3 3.522 17 26.0 3.430 14 27.7 3.217 2 28.5 3.136 3 29.7 3.010 4 30.7 2.914 25 31.3 2.855 16 31.8 2.817 3 34.5 2.597 6 36.3 2.473 3 39.8 2.263 3 43.3 2.090 3 43.6 2.075 3 47.6 1.911 2 47.8 1.904 3 49.2 1.853 5 51.1 1.786 3 53.4 1.716 3 54.7 1.678 2 (b) CoAPSO-34, of example 90A was calcined in air at 600° for 1 hour. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXVII-A below: 2ϑ d,(Å) 100 x I/Io 9.6 9.20 100 10.1 8.77 6 13.0 6.80 14 16.2 5.46 8 17.9 4.97 4 18.0 4.94 3 19.3 4.60 4 20.5 4.34 3 20.8 4.27 14 21.4 4.15 4 23.3 3.82 2 24.3 3.67 3 25.1 3.543 3 25.3 3.524 3 25.7 3.464 2 26.2 3.402 5 31.0 2.831 10 31.6 2.835 5 31.8 2.815 3 (c) The species denominated herein as CoAPSO-34 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions, being as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXVIII-A: 2ϑ d,(Å) Relative Intensity 9.4-9.8 9.41-9.03 s-vs 12.86-13.06 6.86-6.76 w 14.08-14.30 6.28-6.19 w-m 15.90-16.20 5.57-5.47 vw-m 20.60-20.83 4.31-4.26 w-vs 30.50-30.80 2.931-2.903 w-m (d) The CoAPSO-34 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXIX-A: 2ϑ d,(Å) 100 x I/Io 9.4-9.8 9.41-9.03 87-100 10.09-10.14 8.77-8.72 1-6 12.86-13.06 6.86-6.76 11-18 14.08-14.30 6.28-6.19 10-24 15.90-16.24 5.57-5.47 8-35 17.85-18.05 4.97-4.92 3-15 19.13-19.48 4.65-4.55 1-4 20.48-20.56 4.34-4.33 sh-3 20.60-20.83 4.31-4.26 14-100 21.41-22.35 4.15-3.98 3-4 23.18-23.31 3.84-3.82 2-3 24.25-24.53 3.67-3.63 0-3 25.13-25.29 3.543-3.520 3-17 25.72-25.98 3.464-3.430 3-14 26.06-26.19 3.414-3.402 5-9 27.73-27.80 3.217-3.209 2-16 28.30-28.46 3.153-3.136 3-9 29.50-29.68 3.028-3.010 4-14 30.50-30.80 2.931-2.903 12-25 31.04-31.33 2.881-2.855 7-16 31.60-31.79 2.831-2.815 3-5 34.40-34.53 2.607-2.597 5-6 36.20-36.32 2.481-2.473 3-8 38.40-38.60 2.344-2.332 3-5 39.70-39.83 2.270-2.263 3-4 43.10-43.28 2.099-2.090 sh-6 43.40-43.61 2.045-2.075 3-10 47.40-47.59 1.918-1.911 sh-2 47.77-47.80 1.904-1.903 3-10 49.17-49.20 1.853-1.852 5-10 49.90-50.40 1.828-1.809 0-11 51.13-51.20 1.786-1.784 3-10 53.20-53.39 1.722-1.716 3-10 54.60-54.70 1.681-1.678 2-7 55.80-55.90 1.647-1.645 2-10 Example 116A (a) The as-synthesized CoAPSO-35 of example 10A was subjected to analysis by x-ray. The CoAPSO-35 product was characterized by the x-ray powder diffraction pattern of Table XXX-A below: (b) CoAPSO-35, of example 10A was calcined in air at 500°C for two hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXXI-A below: 2ϑ d,(Å) 100 x I/Io 8.7 10.16 26 11.0 8.04 90 11.8 7.50 21 13.7 6.46 100 16.2 5.47 16 17.4 5.10 26 17.6 5.04 37 21.2 4.19 42 22.3 3.99 58 23.2 3.83 26 23.7 3.75 37 25.1 3.548 26 25.3 3.520 32 26.3 3.389 26 27.5 3.243 42 28.6 3.121 53 28.8 3.100 53 29.6 3.018 32 31.9 2.805 26 32.8 2.730 42 34.5 2.600 21 35.0 2.564 21 35.8 2.508 16 (c) The species denominated herein as CoAPSO-35 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXXII-A: 2ϑ d,(Å) Relative Intensity 10.9-11.0 8.12-8.04 m-vs 13.4-13.7 6.61-6.46 m-vs 17.3-17.4 5.13-5.10 m-s 20.9-21.2 4.25-4.19 m 21.9-22.3 4.06-3.99 m-vs 28.3-28.6 3.153-3.121 m (d) The CoAPSO-35 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXXIII-A: 2ϑ d,(Å) 100 x I/Io 7.9* 11.19 8 8.6-8.7 10.28-10.16 18-26 10.9-11.0 8.12-8.04 45-90 11.6-11.8 7.63-7.50 8-21 13.4-13.7 6.61-6.46 30-100 15.9-16.2 5.57-5.47 15-16 17.3-17.4 5.13-5.10 26-83 17.6-17.8 5.04-5.98 20-37 20.9-21.2 4.25-4.19 42-58 21.9-22.3 4.06-3.99 58-100 22.7-23.2 3.92-3.83 13-26 23.3-23.7 3.83-3.75 37-38 24.9-25.1 3.58-3.548 13-26 25.3 3.520 32 25.6-26.3 3.480-3.389 8-26 26.9-27.5 3.314-3.243 28-42 28.3-28.6 3.153-3.121 45-53 28.8-29.6 3.100-3.018 13-53 31.4-31.9 2.849-2.805 10-26 32.2-32.8 2.780-2.730 40-42 34.3-34.5 2.614-2.600 10-21 35.0-35.2* 2.564-2.550 8-21 35.8-35.9 2.508-2.501 8-16 37.8-37.9 2.380-2.374 5 39.4-39.5 2.287-2.281 5 41.9-42.0 2.156-2.151 8 42.6-42.7 2.122-2.118 10 44.6-44.7 2.032-2.027 8 47.8-47.9 1.903-1.900 8 48.6-48.7 1.873-1.870 8 49.8-49.9 1.831-1.828 10 51.2-51.3 1.784-1.781 10 55.6-55.7 1.653-1.650 8 Example 117A (a) The as-synthesized CoAPSO-36 of example 93A was subjected to analysis by x-ray. The CoAPSO-36 product was characterized by the x-ray powder diffraction pattern of Table XXXIV-A below: 2ϑ d,(Å) 100 x I/Io 7.3 12.11 7 8.0 11.12 100 8.2 10.74 29 9.2 9.65 4 12.9 6.86 5 13.6 6.52 8 13.7 6.48 8 15.9 5.57 14 16.5 5.38 42 18.4 4.83 6 19.1 4.64 37 20.8 4.27 49 21.6 4.12 7 21.8 4.09 22 22.1 4.03 28 22.6 3.94 29 23.0 3.86 9 24.0 3.71 9 27.3 3.267 20 27.7 3.226 7 28.4 3.148 13 28.7 3.116 5 29.2 3.063 12 30.4 2.940 7 32.1 2.792 12 34.9 2.571 12 (b) CoAPSO-36, of example 93A was calcined in air at 500° for one hour. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXXV-A below: 2ϑ d,(Å) 100 x I/Io 7.4 12.00 8 8.0 11.10 100 8.3 10.69 33 13.6 6.52 13 15.9 5.58 8 16.6 5.36 32 19.3 4.59 29 20.8 4.27 26 21.5 4.14 8 21.8 4.07 11 22.3 3.98 19 22.7 3.92 17 24.0 3.71 7 27.3 3.266 19 27.8 3.215 10 28.3 3.154 12 28.4 3.145 13 28.5 3.131 10 29.2 3.062 13 32.0 2.797 10 (c) The species denominated herein as CoAPSO-36 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXXVI-A: 2ϑ d,(Å) Relative Intensity 7.8-8.0 11.33-11.05 vs 8.2-8.3 10.78-10.65 m 16.4-16.6 5.40-5.34 m 19.0-19.3 4.67-4.60 m 20.7-21.0 4.29-4.23 m 22.3-22.6 3.99-3.93 w-m (d) The CoAPSO-36 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXXVII-A: 2ϑ d,(Å) 100 x I/Io 7.3-7.5 12.11-11.79 7-8 7.8-8.0 11.33-11.05 100 8.2-8.3 10.78-10.65 29-33 9.2-9.3 9.61-9.51 4-5 12.9-13.0 6.86-6.81 4-5 13.5-13.6 6.56-6.51 8-13 13.7 6.46 7-8 15.8-16.0 5.61-5.54 8-14 16.4-16.6 5.40-5.34 32-42 18.4 4.82 4-6 19.0-19.3 4.67-4.60 29-36 20.7-21.0 4.29-4.23 26-49 21.5-21.7 4.13-4.10 7-8 21.8-22.0 4.08-4.04 11-22 22.3-22.6 3.99-3.93 17-29 22.9-23.0 3.88-3.87 5-9 23.9-24.0 3.72-3.71 7-9 27.2-27.3 3.278-3.267 19-20 27.6-27.8 3.232-3.209 7-10 28.3-28.4 3.153-3.143 12-13 28.5-28.7 3.132-3.110 5-10 29.0-29.2 3.079-3.058 12-13 30.3-30.4 2.950-2.940 5-7 32.0-32.1 2.797-2.788 10-12 34.7-34.9 2.585-2.571 10-12 Example 118A (a) The as-synthesized CoAPSO-39 of example 45A was subjected to analysis by x-ray. The CoAPSO-39 product was characterized by the x-ray powder diffraction pattern of Table XXXVIII-A below: (b) The species denominated herein as CoAPSO-39 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3: "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXXIX-A: 2ϑ d,(Å) Relative Intensity 9.4-9.5 9.41-9.31 m 13.3-13.4 6.66-6.61 m 18.1-18.2 4.90-4.87 w-m 21.0-21.2 4.23-4.19 vs 22.4-22.5 3.97-3.95 m-s 26.4-26.5 3.376-3.363 m (c) The CoAPSO-39 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXXX-A: 2ϑ d,(Å) 100 x I/Io 9.4-9.5 9.41-9.31 31-43 13.3-13.4 6.66-6.61 22-30 18.1-18.2 4.90-4.87 16-31 21.0-21.2 4.23-4.19 100 22.4-22.5 3.97-3.95 53-80 26.4-26.5 3.376-3.363 28-29 26.9-27.0 3.314-3.302 6-13 28.1-28.2 3.175-3.164 13-15 28.6-28.7 3.121-3.11 10-25 29.4-29.5 3.038-3.028 13-18 30.2 2.959 13-15 32.7-32.8 2.739-2.730 17-22 34.2-34.3 2.622-2.614 12-16 34.5-34.6 2.617-2.592 6-10 36.2-36.3 2.481-2.475 6-8 37.6-37.9 2.392-2.374 16-17 39.4-39.5 2.287-2.281 9-11 42.9-43.0 2.108-2.103 8-9 44.6-44.8 2.032-2.023 6-9 48.5-48.6 1.877-1.873 5-6 51.4-51.6 1.778-1.771 5-6 54.5-54.6 1.684-1.681 9-10 55.4-55.6 1.658-1.653 5-6 Example 119A (a) The as-synthesized CoAPSO-44 of example 19A was subjected to analysis by x-ray. The CoAPSO-44 product was characterized by the x-ray powder diffraction pattern of Table XXXXI-A below: 2ϑ d,(Å) 100 x I/Io 4.8* 18.41 8 9.4 9.41 100 13.1 6.76 22 13.9 6.37 5 15.9 5.57 (sh) 16.2 5.47 37 17.4 5.10 5 19.0 4.67 9 20.8 4.27 72 21.8 4.08 17 22.7 3.92 9 23.1 3.85 9 24.4 3.65 49 26.2 3.401 31 27.8 3.209 11 29.0 3.079 sh 29.7 3.008 8 30.1 2.969 20 30.8 2.903 49 31.6 2.831 3 32.5 2.755 6 32.9 2.722 6 34.8 2.578 5 35.5 2.529 9 38.6 2.332 5 39.3 2.292 3 39.8 2.265 sh 40.0 2.254 6 42.2 2.141 5 42.6 2.122 5 43.7 2.071 3 44.4 2.040 3 46.2 1.969 3 47.3 1.922 3 48.2 1.888 12 48.7 1.870 8 50.3 1.814 15 52.0 1.759 5 53.8 1.704 9 54.8 1.675 3 (b) CoAPSO-44 of example 19A was calcined in air at 500° for 1.25 hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXXXII-A below: 2ϑ d,(Å) 100 x I/Io 8.9 9.94 20 9.3 9.51 100 12.9 6.86 24 14.0 6.33 5 15.8 5.61 sh 16.0 5.54 14 17.8 4.98 18 19.1 4.65 4 20.5 4.33 40 22.1 4.02 4 22.3 3.99 4 23.0 3.87 7 25.1 3.548 12 25.8 3.453 13 27.6 3.232 3 28.2 3.164 4 29.5 3.028 3 30.6 2.921 21 31.1 2.876 14 31.7 2.823 4 32.2 2.780 2 33.4 2.683 3 33.7 2.660 4 34.5 2.600 8 36.2 2.481 5 38.2 2.356 2 38.7 2.327 3 39.2 2.298 2 39.8 2.265 3 42.9 2.108 3 43.4 2.085 4 47.6 1.910 3 49.0 1.859 5 49.8 1.831 3 50.6 1.804 3 51.0 1.791 4 53.2 1.722 3 54.7 1.678 2 (c) The species denominated herein as CoAPSO-44 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXXXIII-A: 2ϑ d,(Å) Relative Intensity 9.3-9.5 9.51-9.31 vs 16.0-16.3 5.54-5.44 w-m 20.5-20.8 4.33-4.27 m 24.3-25.1 3.66-3.548 w-m 25.8-26.2 3.453-3.401 w-m 30.7-31.1 2.912-2.876 vw-m (d) The CoAPSO-44 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXXXIV-A: 2ϑ d,(Å) 100 x I/Io 4.8* 18.41 8 8.9 9.94 20 9.3-9.5 9.51-9.31 100 12.9-13.1 6.86-6.76 22-24 13.7-14.0 6.46-6.33 5-6 15.8-15.9 5.61-5.57 sh 16.0-16.3 5.54-5.44 14-37 17.4-17.8 5.10-4.98 5-18 18.9-19.1 4.70-4.65 4-9 20.5-20.8 4.33-4.27 40-72 21.8-22.1 4.08-4.02 4-17 22.3-22.7 3.99-3.92 4-9 23.0-23.1 3.87-3.85 7-9 24.3-25.1 3.66-3.548 12-49 25.8-26.2 3.453-3.401 13-31 27.6-27.8 3.232-3.209 3-11 28.2 3.164 4 29.0-29.5 3.079-3.028 sh-3 29.7-30.6 3.008-2.921 8-21 30.7-31.1 2.912-2.876 4-49 31.6-31.7 2.831-3.823 3-4 32.2 2.780 2 32.5-33.7 2.755-2.660 3-6 34.5-34.8 2.600-2.578 5-8 35.4-36.2 2.536-2.481 5-9 38.2-38.6 2.356-2.332 2-5 38.7-39.3 2.327-2.292 2-3 39.8-40.0 2.265-2.254 sh-3 42.2-42.9 2.141-2.108 3-5 43.4-43.7 2.085-2.071 3-4 44.4-46.2 2.040-1.965 3 47.3-47.6 1.922-1.910 3 48.1-49.0 1.892-1.859 5-12 49.8-50.3 1.831-1.814 3-15 50.6 1.804 3 51.0-52.0 1.791-1.759 4-5 53.2-53.8 1.722-1.704 3-9 54.7-54.8 1.678-1.675 2-3 Example 120A (a) The as-synthesized CoAPSO-46 of example 36 was subjected to analysis by x-ray. The CoAPSO-46 product was characterized by the x-ray powder diffraction pattern of Table XXXXV-A below: 2ϑ d,(Å) 100 x I/Io 6.6 13.39 11 6.9 12.81 7 7.2 12.28 12 7.7 11.48 100 12.5 7.08 7 13.1 6.76 5 13.3 6.66 6 13.5 6.56 4 15.0 5.91 4 15.4 5.75 5 16.1 5.51 3 16.8 5.28 6 17.4 5.10 4 17.5 5.07 5 19.9 4.46 5 20.6 4.31 5 21.0 4.23 4 21.4 4.15 sh 21.7 4.10 13 22.2 4.00 3 22.9 3.88 7 23.8 3.74 4 24.3 3.66 5 26.3 3.389 3 26.9 3.314 7 27.8 3.209 10 28.3 3.153 5 28.8 3.010 6 29.9 2.988 4 30.2 2.959 4 30.7 2.912 4 30.9 2.894 4 31.2 2.867 5 31.8 2.814 3 33.0 2.714 4 34.2 2.622 3 36.0 2.495 5 36.6 2.455 3 44.0 2.058 3 (b) The species denominated herein as CoAPSO-46 has a three-dimensional microporous crystal framework structure of CoO₂, AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXXXVI-A: 2ϑ d,(Å) Relative Intensity 6.5-6.7 13.60-13.19 w 7.2-7.4 12.28-11.95 w 7.6-7.8 11.63-11.33 vs 21.6-21.7 4.11-4.10 w 27.8-27.9 3.209-3.198 w (c) The CoAPSO-46 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table XXXXVII-A: 2ϑ d,(Å) 100 x I/Io 6.5-6.7 13.60-13.19 11 6.9-7.0 12.81-12.63 7 7.2-7.4 12.28-11.95 12 7.6-7.8 11.63-11.33 100 12.5-12.6 7.08-7.03 7 13.1-13.3 6.76-6.66 5 13.5-13.9 6.56-6.37 4 15.0-15.1 5.91-5.87 4 15.4 5.75 5 16.1 5.51 3 16.7-16.8 5.31-5.28 6 17.4-17.5 5.10-5.07 4 19.9-20.0 4.46-4.44 5 20.5-20.6 4.33-4.31 5 21.0 4.23 4 21.4 4.15 sh 21.6-21.7 4.11-4.10 13 22.1-22.2 4.02-4.00 3 22.8-22.9 3.90-3.88 7 23.8 3.74 4 24.2-24.3 3.68-3.66 5 26.3-26.4 3.389-3.376 3 26.8-26.9 3.326-3.314 7 27.8-27.9 3.209-3.198 10 28.3-28.4 3.153-3.143 5 28.8-28.9 3.010-3.089 6 29.8-29.9 2.998-2.988 4 30.2 2.959 4 30.7 2.912 4 30.9-31.0 2.894-2.885 4 31.2-31.3 2.867-2.858 5 31.8-31.9 2.814-2.805 3 32.8-33.0 2.730-2.714 4 34.2-34.3 2.622-2.614 3 35.9-36.0 2.510-2.495 5 36.5-36.6 2.462-2.455 3 44.0-44.1 2.058-2.053 3 Example 121A (a) The as-synthesized CoAPSO-47 of example 104A was subjected to analysis by x-ray. The CoAPSO-47 product was characterized by the x-ray powder diffraction pattern of Table XXXXVIII-A below: 2ϑ d,(Å) 100 x I/Io 9.4 9.37 94 12.9 6.88 16 13.8 6.40 9 16.0 5.55 40 17.5 5.06 14 18.9 4.69 6 20.6 4.32 100 21.8 4.08 11 22.4 3.97 4 23.0 3.87 12 24.6 3.62 38 25.9 3.443 22 27.6 3.230 11 29.5 3.030 6 30.6 2.926 42 31.5 2.844 3 33.1 2.707 3 34.5 2.602 9 35.7 2.518 7 38.4 2.345 4 39.6 2.275 4 42.5 2.128 4 47.6 1.910 4 48.5 1.877 11 50.3 1.815 7 52.3 1.749 2 53.2 1.721 5 53.9 1.700 3 54.3 1.690 3 (b) CoAPSO-47, of example 104A was calcined in air at 500° for 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern of Table XXXXIX-A below: 2ϑ d,(Å) 100 x I/Io 9.6 9.18 100 3.1 6.77 26 14.2 6.23 3 16.3 5.44 10 18.1 4.90 16 19.4 4.58 3 21.0 4.24 26 22.5 3.96 3 23.5 3.79 3 25.5 3.499 11 26.4 3.381 9 28.7 3.113 4 31.2 2.868 14 31.7 2.824 6 (c) The species denominated herein as CoAPSO-47 has a three-dimensional microporous crystal framework structure of CoO₂ AlO₂, PO₂ and SiO₂ tetrahedral units and has an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co w Al x P y Si z )O₂ where "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" per mole of (Co w Al x P y Si z )O₂ and has a value of from zero to about 0.3; "w", "x", "y" and "z" represent the mole fractions as above defined with reference to FIG. 1 or FIG. 2; and having in the as-synthesized or calcined form a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table LI-A: 2ϑ d,(Å) Relative Intensity 9.4-9.6 9.41-9.21 vs 12.8-13.1 6.92-6.76 w-m 16.0-16.3 5.54-5.44 w-m 20.6-21.0 4.31-4.23 m-vs 25.5-25.9 3.493-3.440 w-m 30.6-31.1 2.921-2.876 w-m (d) The CoAPSO-47 compositions for which x-ray powder diffraction patterns have been obtained to date have patterns which are characterized by the x-ray pattern of Table LII-A: 2ϑ d,(Å) 100 x I/Io 9.4-9.6 9.41-9.21 94-100 12.8-13.1 6.92-6.76 16-26 13.8-14.2 6.42-6.24 3-9 16.0-16.3 5.54-5.44 10-40 17.5-18.1 5.07-4.90 14-16 18.9-19.4 4.70-4.58 3-6 20.6-21.0 4.31-4.23 26-100 21.8 4.08 11 22.4-22.5 3.97-3.95 3-4 23.0-23.5 3.87-3.79 3-12 24.6 3.62 38 25.5-25.9 3.493-3.440 11-22 26.4 3.376 9 27.6 3.232 11 28.7 3.110 4 29.5 3.028 6 30.6-31.1 2.921-2.876 13-42 31.5-31.7 2.840-2.823 3-6 33.1 2.706 3 34.5 2.600 9 35.7 2.515 7 38.4 2.344 4 39.6 2.276 4 42.5 2.127 4 47.6 1.910 4 48.5 1.877 11 50.3 1.814 7 52.3 1.749 2 53.2 1.722 5 53.9 1.701 3 54.3 1.689 3 Example 122A In order to demonstrate the catalytic activity of the CoAPSO compositions, calcined samples of the CoAPSO products were tested for catalytic cracking by n-butane cracking. The n-butane cracking was carried out using a bench scale rector. The reactor was a cylindrical quartz tube 254 mm. in length and 10.3 mm. I.D. In each test the reactor was loaded with particles of the test CoAPSO's which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. Most of the CoAPSO had been previously calcined in air to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. In some instances, samples were calcined in situ . The feedstock was a helium-n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the CoAPSO compositions. The k A value (cm³/g min) obtained for the CoAPSO compositions are set forth, below. CoAPSO of Example No: Rate Constant (k A ) CoAPSO-11 (Ex. 50A) 1.0 CoAPSO-11 (Ex. 42A) 2.0 CoAPSO-11 (Ex. 42A) 1.9 CoAPSO-11 (Ex. 61A) 1.4 CoAPSO-31 (Ex. 102A) 2.1 CoAPSO-34 (Ex. 89A) 1.5 CoAPSO-34 (Ex. 89A) 8.7 CoAPSO-34 (Ex. 90A) 11.8 CoAPSO-34 (Ex. 83A) 28.1 CoAPSO-34 (Ex. 77A) 11.1 CoAPSO-35 (Ex. 10A) 1.0 CoAPSO-44 (Ex. 19A) 18.1 CoAPSO-46 (Ex. 36A) 2.4 CoAPSO-47 (Ex. 104A) 2.3 CoAPSO-44 (Ex. 19A) 2.7 CoAPSO-36 (Ex. 93A) 1.0 CoAPSO-34 (Ex. 83A) 4.1 CoAPSO-34 (Ex. 69A) 9.4 CoAPSO-34 (Ex. 79A) 5.2 CoAPSO-34 (Ex. 78A) 4.6 CoAPSO-34 (Ex. 81A) 3.3 B. MAGNESIUM-ALUMINUM-PHOSPHORUS-SILICON OXIDE MOLECULAR SIEVES Molecular sieves containing magnesium, aluminum, phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the MgAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: (a) Alipro: aluminum isoproproxide; (b) CATAPAL: Trademark of Condea for hydrated pseudo-boehmite; (c) LUDOX LS: Trademark of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; (d) Mg(Ac)₂: magnesium acetate tetrahydrate, Mg(C₂H₃O₂)·4H₂O; (e) H₃PO₄: 85 weight percent phosporic acid in water; (f) TBAOH: tetrabutylammonium hydroxide (40 wt. % in water); (g) Pr₂NH: di-n-propylamine; (h) Pr₃N: tri-n-propylamine; (i) Quin: Quinuclidine; (j) MQuin: Methyl Quinuclidine hydroxide (17.9% in water); (k) C-hex; cyclohexylamine; (l) TEAOH; tetraethylammonium hydroxide (40 wt. % in water). (m) DEEA: diethylethanolamine; (n) i-Pr₂NH: di-isopropylamine; (o) TEABr: tetraethylammonium bromide; and (p) TPAOH: tetrapropylammonium hydroxide (40 wt. % in water). Preparative Procedure The MgAPSO compositions were prepared by preparing reaction mixtures having a molar composition expressed as: eR:fMgO:hAl₂O₃:iP₂O₅:gSiO₂:jH₂O wherein e, f, g, h, i and j represent the moles of template R, magnesium (expressed as the oxide),SiO₂ Al₂O₃, P₂O₅ (H₃PO₄ expressed as P₂O₅) and H₂O, respectively. The values for e, f, g, h, i and j were as set forth in the hereinafter discussed preparative examples. The reaction mixtures were prepared by three procedures, designated hereinafter as Methods A, B and C, unless otherwise noted in the preparative examples. Method A was employed for examples 1B to 25B, 27B-30B, 39B-46B, 55B-57B, 61B, 63B-71B, 77B-85B and 87B-106B. Method B was employed for examples 31B-38B and 47B-54B. Method C was employed for examples 26B, 62B and 72-76B. The aluminum source was aluminum iso-propoxide except that CATAPAL was the aluminum source in examples 39B-55B and 58B-61B.. Method A The reaction mixture was prepared by mixing the ground aluminum source (Al-ipro or CATAPAL) with the H₃PO₄ and water on a gradual basis with occasional cooling with an ice bath. The resulting mixture was blended until a homogeneous mixture was observed. When the aluminum source was CATAPAL the water and H₃PO₄ were first mixed and the CATAPAL added thereto. The magnesium acetate was dissolved in portion of the water and was then added followed by addition of the LUDOX-LS. The combined mixture was blended until a homogenous mixture was observed. The organic templating agent was added to this mixture and blended until a homogenous mixture was observed. The resulting mixture (final reaction mixture) was placed in a lined (polytetrafluoroethylene)stainless steel pressure vessel and digested at a temperature (150°C or 200°C) for an effective time. Alternatively, if the digestion temperature was 100°C the final reaction mixture was placed in a lined (polytetrafluoroethylene) screw top bottle for a time. All digestions were carried out at the autogeneous pressure. The products were removed from the reaction vessel cooled and evaluated as set forth hereinafter. Method B When method B was employed the organic templating agent was di-n-propylamine. The aluminum source, silicon source and one-half of the water were first mixed and blended until a homogeneous mixture was observed. A second solution was prepared by mixing the remaining water, the H₃PO₄ and the magnesium acetate. This solution was then added to the above mixture. The magnesium acetate and H₃PO₄ solution was then added to the above mixture and blended until a homogeneous mixture was observed. The organic templating agent(s) was then added and the resulting reaction mixture digested and product recovered as was done in Method A. Method C Method C was carried out by mixing aluminum isopropoxide, LUDOX LS and water in a blender or by mixing water and aluminum iso-propoxide in a blender followed by addition of the LUDOX LS. H₃PO₄ and magnesium acetate were then added to this mixture. The organic templating agent was then added to the resulting mixture and digested and product recovered as was done in Method A. The following examples are provided to further illustrate the invention and are not intended to be limiting thereof. Examples 1B to 90B and AB to QB MgAPSO molecular sieves were prepared according to the above described Methods A, B and C by preparing reaction mixtures expressed as eR:fMgO:hAl₂O₃:iP₂O₅:gSiO₂:jH₂O wherein, e, f, h, i, g and j represent the moles of template R, magnesium (expressed as the oxide), Al₂O₃, SiO₂, P₂O₅ (H₃PO₃ expressed as P₂O₅), and H₂O respectively. The values for e, f, g, h and i for examples 1B to 90B are set forth in Table I-B to VI-B. The value of "j" was 50 in examples 1B to 84B and 87B-90B and was 75B in example 85B and was 71B in example 86B. Tables IB to VI-B also shows the temperature (°C) and time (hours) employed for digestion and indicates the final MgAPSO(s) formed. Examples AA to QB respresent reaction mixtures wherein crystalline MgAPSO products were not observed when the reaction products were subjected to X-ray analysis. The results of Examples AB to QB are set forth in Table VII-B. Examples 91B to 106B MgAPSO molecular sieves were prepared according to the procedures employed in examples 1B to 90B. The aluminum source was CATAPAL in examples 96B and 97B. The results of preparative examples 91B to 106B are set forth in Table VIII-B. Example 107B Samples of the MgAPSO products were subjected to chemical analysis. The chemical analysis for each of the analyzed products is given hereinafter: (a) The chemical analysis for the MgAPSO-5 of example 4B was: Component Weight Percent Al₂O₃ 31.3 P₂O₅ 45.4 MgO 2.8 SiO₂ 3.9 Carbon 5.0 LOI 13.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anydrous basis) of: 0.23 MgO: 1.00 Al₂O₃: 1.04 P₂O₅: 0.21 SiO₂: and a formula (anhydrous basis) of: 0.03R(Mg 0.05 Al 0.44 P 0.46 Si 0.05 )O₂ (b) The chemical analysis for MgAPSO-36 of example 5B was: Component Weight Percent Al₂O₃ 31.2 P₂O₅ 44.6 MgO 2.6 SiO₂ 8.6 Carbon 6.2 LOI 13.9 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.21 MgO; 1.00 Al₂O₃: 1.03 P₂O₅: 0.45 SiO₂;and a formula (anhydrous basis) of: 0.04R(Mg 0.05 Al 0.43 P 0.44 Si 0.10 )O₂ (c) The chemical analysis for the MgAPSO-46 of example 44B was: Component Weight Percent Al₂O₃ 30.1 P₂O₅ 38.4 MgO 4.1 SiO₂ 4.4 Carbon 10.6 LOI 22.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.34 MgO; 1.00 Al₂O₃: 0.92 P₂O₅: 0.25 SiO₂: and a formula (anhydrous basis) of: 0.11R(Mg 0.08 Al 0.45 P 0.41 Si 0.06 )O₂ (d) The chemical analysis of the MgAPSO-34 of example 63B was: Component Weight Percent Al₂O₃ 31.7 P₂O₅ 37.0 MgO 3.0 SiO₂ 2.9 Carbon 8.3 LOI 21.6 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.24 MgO; 1.00 Al₂O₃: 0.84 P₂O₅: 0.16 SiO₂; and a formula (anhydrous basis) of: 0.07R(Mg 0.06 Al 0.49 P 0.41 Si 0.04 )O₂ (e) The chemical analysis for the MgAPSO-34 of example 68B was: Component Weight Percent Al₂O₃ 29.8 P₂O₅ 40.4 MgO 2.3 SiO₂ 6.9 Carbon 10.4 LOI 21.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.20 MgO; 1.00 Al₂O₃: 0.97 P₂O₅: 0.39 SiO₂: and a formula (anhydrous basis) of: 0.08R(Mg 0.04 Al 0.44 P 0.43 Si 0.09 )O₂ (f) The chemical analysis of the MgAPSO-34 of example 74B was: Component Weight Percent Al₂O₃ 28.6 P₂O₅ 33.9 MgO 4.9 SiO₂ 3.7 Carbon 9.0 LOI 27.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.43 MgO: 1.00 Al₂O₃: 0.85 P₂O₅: 0.22 SiO₂: and a formula (anhydrous basis) of: 0.08R(Mg 0.10 Al 0.46 P 0.38 Si 0.05 )O₂ (g) The chemical analysis for the MgAPSO-35 of example 85B was: Component Weight Percent Al₂O₃ 28.3 P₂O₅ 42.7 MgO 2.8 SiO₂ 4.0 Carbon 9.8 LOI 19.6 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.37R:0.25 MgO; 1.0 Al₂O₃; 1.08 P₂O₅; 0.24 SiO₂; and a formula (anhydrous basis) of: 0.08(Mg 0.05 Al 0.43 P 0.47 Si 0.05 )O₂ (h) The chemical analysis for the MgAPSO-20 of example 101B was: Component Weight Percent Al₂O₃ 27.8 P₂O₅ 31.4 MgO 3.1 SiO₂ 15.2 Carbon 9.7 LOI 21.2 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.74R:0.28 MgO; 1.00 Al₂O₃: 0.81 P₂O₅: 0.93 SiO₂; and a formula (anhydrous basis) of: 0.15R(Mg 0.06 Al 0.41 P 0.34 Si 0.19 )O₂ (i) The chemical analysis for the MgAPSO-43 of example 97B was: Component Weight Percent Al₂O₃ 32.3 P₂O₅ 33.1 MgO 3.6 SiO₂ 8.2 Carbon 9.1 LOI 21.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.40R:0.28 MgO: 1.00 Al₂O₃: 0.74 P₂O₅: 0.43 SiO₂; and a formula (anhydrous basis) of: 0.10R(Mg 0.07 Al 0.48 P 0.35 Si 0.10 )O₂ (j) The chemical analysis for the MgAPSO-47 of example 104B was: Component Weight Percent Al₂O₃ 33.1 P₂O₅ 29.3 MgO 2.8 SiO₂ 7.7 Carbon 5.7 LOI 25.4 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.24R:0.21 MgO; 1.00 Al₂O₃: 0.64 P₂O₅: 0.39 SiO₂; and a formula (anhydrous basis) of: 0.06R(Mg 0.06 Al 0.51 P 0.33 Si 0.10 )O₂ Example 108B EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction with SEM (scanning electron microscope) was carried out on clear crystals from the products of examples. Analysis of crystals having a morphology characteristic of the MgAPSO products as prepared in the following referenced examples gave the following analysis based on relative peak heights: a) MgAPSO-5( Example 4B ): Average of Spot Probes Mg 3 Al 46 P 48 Si 3 b) MgAPSO-36( Example 5B ): Average of Spot Probes Mg 3 Al 40 P 48 Si 9 c) MgAPSO-46( Example 44B ): Average of Spot Probes Mg 5 Al 39 P 49 Si 6 d) MgAPSO-34( Example 63B ): Average of Spot Probes Mg 6 Al 44 P 45 Si 6 e) MgAPSO-34( Example 75B ): Average of Spot Probes Mg 6 Al 42 P 44 Si 8 f) MgAPSO-35( Example 80B ): Average of Spot Probes Mg 4 Al 41 P 51 Si 4 g) MgAPSO-47( Example 104B ): Average of Spot Probes Mg 2 Al 42 P 43 Si 13 Example 109B Samples of the MgAPSO products were evaluated for adsorption capacities in the as-synthesized form or were calcined in air or nitrogen, to remove at least part of the organic templating agent, as hereinafter set forth. The adsorption capacities of each as-synthesized or calcined sample were measured using a standard McBain - Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum at 350°C prior to measurement. The McBain-Bakr data for the selected MgAPSO products were: a) Example 4B (MgAPSO-5) : Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 13.2 O₂ 3.46 749 -183 15.5 Cyclohexane 6.0 57 23.4 7.9 neopentane 6.2 100 23.4 5.0 H₂O 2.65 4.6 23.2 16.0 H₂O 2.65 16.8 23.5 21.3 The above data demonstrate that the pore size of the calcined product is greater than about 6.2Å. b) Example 101B (MgAPSO-20) : Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 0.8 O₂ 3.46 750 -183 2.7 H₂O 2.65 4.6 23.2 16.5 H₂O 2.65 16.8 23.5 19.9 The above data demonstrate that the pore size of the calcined product is about 3.0Å. c) Example 63B (MgAPSO-34) : The above data demonstrate that the pore size of the calcined product is about 4.3Å. d) Example 84B (MgAPSO-35) : Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 6.7 O₂ 3.46 734 -183 9.2 isobutane 5.0 100 24 0.3 n-hexane 4.3 51 24 1.1 H₂O 2.65 4.6 23 11.5 H₂O 2.65 19.5 23 17.7 e) Example 91B(MgAPSO-35) : Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 11.2 O₂ 3.46 744 -183 14.0 isobutane 5.0 100 22.8 0.2 n-hexane 4.3 49 22.3 5.7 H₂O 2.65 4.6 23.1 16.1 H₂O 2.65 17.8 22.9 20.5 The above data demonstrate that the pore size of the calcined product is about 4.3Å. In addition, the data demonstrate that in part d) the template was not sufficiently removed by the calcination. f) Example 5B (MgAPSO-36 ): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 12.9 O₂ 3.46 734 -183 15.4 isobutane 5.0 100 24 5.2 cyclohexane 6.0 59 23.7 9.0 neopentane 6.2 100 24.5 5.5 H₂O 2.65 4.6 23 16.8 H₂O 2.65 20 23.6 23.5 The above data demonstrate that the pore size of the calcined product is greater than 6.2Å. g) Example 44B (MgAPSO-46) : Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 20.7 O₂ 3.46 734 -183 24.7 neopentane 6.2 100 24.5 8.4 isobutane 5.0 100 24 7.8 cyclo-hexane 6.0 59 23.7 11.9 H₂O 2.65 4.6 23 22.0 H₂O 2.65 20.0 23.6 27.4 The above data demonstrate that the pore size of the calcined product is greater than about 6.2Å. h) Example 104B (MgAPSO-47) : The above data demonstrate that the pore size of the calcined product is about 4.3Å. Example 110B (a) MgAPSO-5, as prepared to in example 4B, was subjected to x-ray analysis. MgAPSO-5 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-5 of part a) was calcined in air at 600°C for about 2.25 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-5 compositions are generally characterized by the data in Table IX-B below: 2ϑ d,(Å) Relative Intensity 7.2-7.4 12.28-11.95 m-vs 14.6-14.95 6.07-5.93 w-m 19.4-19.8 4.58-4.48 m 20.85-21.1 4.26-4.21 vw-vs 22.15-22.4 4.01-3.97 m-vs 25.6-25.95 3.480-3.434 m (d) The MgAPSO-5 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table X-B, below: 2ϑ d, (Å) 100 x I/Io 7.2-7.4 12.28-11.95 69-100 12.65-12.9 7.00-6.86 8-12 14.6-14.95 6.07-5.93 15-35 19.4-19.8 4.58-4.48 38-73 20.85-21.1 4.26-4.21 (sh)-100 22.15-22.4 4.013-3.969 48-100 24.4-24.05 3.648-3.583 0-14 25.6-25.95 3.480-3.434 23-44 28.7-29.1 3.110-3.069 12-20 29.65-30.15 3.013-2.964 15-21 33.4-33.75 2.683-2.656 2-11 34.2-34.65 2.622-2.589 11-19 36.6-37.0 2.455-2.430 0-4 37.4-37.8 2.405-2.380 5-11 40.6-40.7 2.222-2.217 0-1 41.1-41.6 2.196-2.171 0-3 41.85-42.4 2.159-2.132 3-4 42.6-43.05 2.122-2.101 0-3 43.2-43.5 2.094-2.080 0-2 44.6-45.0 2.032-2.015 0-2 45.3-45.6 2.002-1.989 0-2 46.1-46.35 1.969-1.959 0-1 47.2-47.75 1.926-1.905 4-6 50.4 1.811 0-1 50.9-51.1 1.794-1.787 0-3 51.6-51.9 1.771-1.762 0-4 52.2-52.4 1.752-1.746 0-1 55.2-55.8 1.664-1.648 0-4 Example 111-B (a) MgAPSO-11, as prepared to in example 17B, was subjected to x-ray analysis. MgAPSO-11 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-11 of part a) was calcined in air at 600°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-11 compositions are generally characterized by the data of Table XI-B below: 2ϑ d,(Å) Relative Intensity 9.0-9.6 9.83-9.21 vw-m 20.8-21.2 4.27-4.19 vs 22.0-22.4 4.04-3.97 vw-m 22.4-22.8 3.97-3.90 vw-vs 22.8-23.1 3.90-3.85 m (d) The MgAPSO-11 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XII-B, below: 2ϑ d,(Å) 100 x I/Io 7.8-8.15 11.33-10.85 sh-35 9.0-9.6 9.83-9.21 6-60 12.9-13.2 6.86-6.71 sh-22 15.4-15.9 5.75-5.57 sh-30 15.95-16.35 5.56-5.42 sh-3 18.7-19.1 4.75-4.65 0-4 20.0-20.5 4.44-4.33 sh-38 20.8-21.2 4.27-4.19 100 22.0-22.4 4.040-3.969 sh-72 22.4-22.8 3.969-3.900 sh-90 22.8-23.1 3.900-3.850 21-48 23.35 3.810 0-4 24.4-24.9 3.648-3.576 0-9 26.2-26.7 3.401-3.339 0-21 28.4-28.8 3.143-3.100 sh-17 29.3-29.5 3.048-3.028 0-6 29.6-30.0 3.018-2.979 0-17 31.2-31.7 2.867-2.823 0-15 32.4-32.8 2.763-2.730 0-18 33.8-34.5 2.652-2.600 9-13 35.7 2.515 0-3 36.1-36.8 2.488-2.442 0-11 37.5-37.9 2.398-2.374 0-17 39.15-39.6 2.301-2.276 0-3 40.25-40.75 2.241-2.214 0-1 41.2-41.4 2.191-2.181 0-1 41.8-42.1 2.161-2.146 0-4 42.8-43.2 2.113-2.094 0-5 44.5-44.9 2.036-2.019 0-4 50.3-50.7 1.814-1.801 0-3 54.4-54.6 1.687-1.681 0-3 Example 112B (a) MgAPSO-16, as prepared to in example 93B, was subjected to x-ray analysis. MgAPSO-16 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d,(Å) 100 x I/Io 8.6 10.30 13 10.95 8.10 36 11.45 7.73 64 13.3 6.66 24 15.85 5.60 6 17.25 5.14 50 17.75 4.99 9 18.7 4.74 45 20.4 4.35 35 20.75 4.28 10 21.1 4.21 26 21.55 4.12 sh 21.85 4.07 100 23.05 3.858 26 26.3 3.391 5 26.75 3.332 25 28.45 3.135 17 28.65 3.116 18 29.0 3.079 17 29.9 2.987 20 32.0 2.796 30 32.85 2.727 3 34.6 2.592 6 34.85 2.573 4 35.65 2.519 12 37.9 2.373 8 39.95 2.256 5 42.0 2.152 4 42.9 2.108 4 44.3 2.044 4 48.55 1.876 10 49.35 1.846 5 51.4 1.778 5 52.2 1.752 2 52.5 1.743 2 55.0 1.670 5 (b) A portion of the as-synthesized MgAPSO-16 of part a) was calcined in air at 600°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 I/Io 8.7 10.16 25 11.0 8.04 185 11.4 7.76 sh 13.6 6.51 200 17.5 5.07 50 18.7 4.75 10 21.2 4.23 45 22.2 4.004 100 22.8 3.900 15 23.7 3.754 30 25.1 3.548 15 26.4 3.376 15 27.3 3.267 40 28.7 3.110 65 29.0 3.079 sh 29.7 3.008 45 32.0 2.797 15 32.6 2.747 50 33.2 2.706 sh 34.6 2.592 10 35.6 2.522 5 (c) The MgAPSO-16 compositions are characterized by the data of Table XIII-B below: 2ϑ d,(Å) Relative Intensity 11.4-11.5 7.76-7.69 m 18.7-18.8 4.75-4.72 w-m 21.85-22.2 4.07-4.00 vs 22.8-23.3 3.900-3.818 w-m 26.75-27.3 3.332-3.267 w-m 29.7-29.9 3.008-2.988 w-m (d) The MgAPSO-16 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XIV-B, below: 2ϑ d,(Å) 100 x I/Io 11.5-11.5 7.76-7.69 sh-64 18.7-18.8 4.75-4.72 10-45 21.85-22.2 4.07-4.00 100 22.8-23.3 3.900-3.818 15-26 26.75-27.3 3.332-3.267 16-40 28.95-29.0 3.084-3.079 sh-17 29.7-29.9 3.008-2.988 9-45 32.8-33.2 2.730-2.968 sh-3 34.6-34.85 2.592-2.573 4-10 37.8-38.0 2.380-2.368 4-7 39.4-39.95 2.287-2.256 2-5 44.3-44.5 2.044-2.036 2-10 48.55-48.6 1.876-1.873 7-10 52.4-52.5 1.746-1.743 1-2 Example 113B (a) MgAPSO-20, as prepared in example 98B, was subjected to x-ray analysis. MgAPSO-20 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-20 of part a) was calcined in air at 600°C for about 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern of below: 2ϑ d,(Å) 100 x I/Io 14.15 7.27 100 20.05 4.43 20 22.45 3.964 4 24.6 3.616 54 28.5 3.132 15 32.0 2.799 10 35.0 2.564 10 (c) The MgAPSO-20 compositions are characterized by the data of Table XV-B below: 2ϑ d,(Å) Relative Intensity 13.8-14.2 6.42-6.23 m-vs 19.6-20.15 6.53-4.41 m 24.1-24.7 3.695-3.603 m-vs 27.9-28.6 3.198-3.121 w 31.3-32.05 2.861-2.791 w 34.35-35.0 2.610-2.601 w (d) The MgAPSO-20 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XVI-B, below: 2ϑ d,(Å) 100 x I/Io 13.8-14.2 6.42-6.23 42-100 19.6-20.15 4.55-4.41 22-43 21.95-22.45 4.050-3.964 3-7 24.1-24.7 3.695-3.603 56-100 27.9-28.6 3.198-3.121 11-15 31.3-32.05 2.861-2.791 10-12 34.35-35.0 2.610-2.601 10-16 37.2-37.35 2.417-2.408 1-2 39.9-40.0 2.260-2.253 3-4 42.4-42.55 2.130-2.124 5 47.15-47.3 1.927-1.921 4-5 51.55-51.7 1.772-1.768 8 Example 114B (a) MgAPSO-34, as prepared in example 68B, was subjected to x-ray analysis. MgAPSO-34 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-34 of part a) was calcined in air at 550°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 9.7 9.12 100 13.1 6.76 22 14.2 6.24 1 16.3 5.44 15 18.1 4.90 10 19.3 4.60 3 20.95 4.24 31 21.6 4.11 sh 22.4 3.969 3 23.35 3.809 3 25.35 3.513 11 26.3 3.389 10 28.5 3.132 4 30.0 2.979 sh 31.0 2.885 23 33.8 2.652 2 35.0 2.564 3 36.6 2.455 1 43.7 2.071 1 49.4 1.845 2 51.3 1.781 2 52.2 1.752 1 53.1 1.725 1 54.0 1.698 2 (c) The MgAPSO-34 compositions are characterized by the data of Table XVII-B below: 2ϑ d,(Å) Relative Intensity 9.3-9.7 9.51-9.12 vs 15.8-16.3 5.61-5.44 w-m 20.25-21.0 4.39-4.23 m-vs 25.7-26.3 3.466-3.389 vw-m 30.0-30.8 2.979-2.903 vw-m 30.9-31.4 2.894-2.849 w-m (d) The MgAPSO-34 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XVIII-B below. 2ϑ d,(Å) 100 x I/Io 9.3-9.7 9.51-9.12 99-100 12.6-13.1 7.03-6.76 11-25 13.8-14.3 6.42-6.19 0-24 15.8-16.3 5.61-5.44 13-56 17.8-18.2 4.98-4.87 5-28 19.1-19.4 4.65-4.58 0-3 20.25-21.0 4.39-4.23 22-100 22.2-22.5 4.004-3.952 0-6 22.8-23.4 3.900-3.802 0-6 24.9-25.4 3.576-3.507 6-27 25.7-26.3 3.466-3.389 6-29 27.4-28.0 3.255-3.187 0-4 28.2-28.8 3.164-3.100 0-4 29.0-29.6 3.079-3.018 0-6 30.0-30.8 2.979-2.903 0-34 30.9-31.4 2.894-2.849 16-30 32.2-32.4 2.780-2.763 0-4 33.8-34.5 2.401-2.600 0-15 34.6-35.0 2.592-2.564 0-4 36.0-36.6 2.495-2.456 0-4 38.4-39.0 2.344-2.309 0-2 43.0-43.7 2.103-2.071 0-3 44.6-45.0 2.032-2.015 0-1 47.2-47.6 1.926-1.910 0-4 48.3-49.4 1.884-1.845 0-6 50.2 1.817 0-2 50.7-51.4 1.801-1.778 0-4 51.3-51.5 1.781-1.774 0-2 52.9-53.1 1.731-1.725 0-4 54.1-54.6 1.695-1.681 0-4 55.5-55.9 1.656-1.645 0-4 Example 115B (a) MgAPSO-35, as prepared in example 85B, was subjected to x-ray analysis. MgAPSO-35 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-35 of part a) was calcined in air at 500°C for about 68 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-35 compositions are generally characterized by the data of Table XIXB below: 2ϑ d,(Å) Relative Intensity 10.6-11.1 8.35-7.97 m-vs 13.1-13.7 6.76-6.46 w-vs 17.0-17.6 5.22-5.04 m-s 20.6-21.2 4.31-4.19 vw-m 21.6-22.2 4.11-4.00 m-vs 28.1-28.8 3.175-3.100 m (d) The MgAPSO-35 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XX-B, below: 2ϑ d,(Å) 100 x I/Io 8.3-8.8 10.65-10.05 10-21 10.6-11.1 8.35-7.97 36-100 13.1-13.7 6.76-6.46 17-100 15.7-16.0 5.64-5.54 0-9 17.0-17.6 5.22-5.04 25-80 17.7-17.8 5.01-4.98 0-sh 20.6-21.2 4.31-4.19 sh-54 21.6-22.2 4.11-4.00 40-100 23.0-23.7 3.867-3.754 sh-27 24.6-25.2 3.619-3.534 5-8 25.8-26.4 3.453-3.376 0-8 26.6-27.3 3.351-3.267 10-16 27.1 3.290 sh-10 28.1-28.8 3.175-3.100 24-44 28.9-29.7 3.089-3.008 5-23 31.45-31.5 2.844-2.840 sh-7 31.9-32.4 2.805-2.763 19-37 32.4-32.7 2.763-2.739 sh 34.1-34.7 2.629-2.585 5-9 35.6-36.1 2.522-2.488 0-4 37.1-38.0 2.404-2.368 0-6 39.4-39.9 2.287-2.259 0-4 40.8-40.9 2.212-2.206 0-1 41.7-42.2 2.166-2.141 0-5 42.2-42.7 2.132-2.118 0-6 44.5-44.8 2.036-2.023 0-7 45.0-45.1 2.014-2.010 0-1 47.4-47.7 1.914-1.907 0-2 48.2-48.6 1.888-1.873 0-4 48.7-49.0 1.870-1.859 0-4 49.3-49.7 1.848-1.834 0-5 50.8-51.5 1.797-1.774 0-7 55.2-55.6 1.664-1.653 0-4 Example 116B (a) MgAPSO-36, as prepared in example 5B, was subjected to x-ray analysis. MgAPSO-36 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-36 of part a) was calcined in air at 500°C for about 2 hours and at 600°C for an additional 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 7.4 11.95 sh 7.9 11.19 100 8.2 10.78 sh 12.8 6.92 3 13.45 6.58 8 14.9 5.95 2 15.9 5.57 sh 16.5 5.37 24 19.3 4.60 38 19.75 4.50 sh 20.8 4.27 25 21.2 4.19 sh 21.8 4.08 sh 22.35 3.978 25 22.6 3.934 sh 23.0 3.867 sh 23.9 3.723 5 24.9 3.576 1 25.8 3.453 4 27.2 3.278 16 28.35 3.148 7 29.1 3.069 10 29.9 2.988 3 30.4 2.940 5 32.0 2.797 8 33.2 2.698 1 35.0 2.564 7 36.0 2.495 3 37.7 2.386 2 39.5 2.281 1 40.3 2.238 2 41.3 2.186 4 42.0 2.151 2 43.5 2.080 1 44.3 2.045 1 45.4 1.998 1 47.6 1.910 3 51.2 1.784 1 55.5 1.656 1 (c) The MgAPSO-36 compositions are generally characterized by the data of Table XXI-B below: 2ϑ d,(Å) Relative Intensity 7.8-8.0 11.33-11.05 vs 16.3-16.5 5.44-5.37 m 18.9-19.3 4.70-4.60 m 20.7-20.8 4.29-4.27 m 22.35 3.98 m (d) The MgAPSO-36 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXII-B below: 2ϑ d,(Å) 100 x I/Io 7.8-8.0 11.33-11.05 100 8.1-8.2 10.92-10.78 0-sh 13.45 6.58 6-8 15.7-15.9 5.64-5.57 sh 16.3-16.5 5.44-5.37 24-31 18.9-19.3 4.70-4.60 38-41 20.7-20.8 4.29-4.27 25-49 21.0 4.23 0-sh 21.55-21.8 4.12-4.08 sh 21.8-21.9 4.077-4.058 sh 22.35 3.978 25-42 22.8-23.0 3.900-3.867 (sh) 23.8-23.9 3.739-3.723 5-9 27.1-27.2 3.290-3.278 14-16 28.1-28.35 3.176-3.148 7-10 28.8-29.1 3.100-3.069 10-12 29.9-30.1 2.988-2.969 3-7 31.8-32.0 2.814-2.797 8-11 33.0-33.2 2.714-2.698 1-3 34.6-35.0 2.592-2.564 7-16 35.7-36.0 2.515-2.495 3-4 37.6-37.7 2.392-2.386 2-3 39.3-39.5 2.293-2.281 1 40.1-40.3 2.249-2.238 2-3 41.3 2.186 4 43.0-43.5 2.103-2.080 1-2 43.95-44.3 2.060-2.045 1-2 45.2-45.4 2.006-1.998 1 46.6 1.949 0-1 47.3-47.6 1.922-1.910 3 48.8 1.867 0-1 51.1-51.2 1.787-1.784 1-2 53.7 1.707 0-2 55.3-55.5 1.661-1.656 1-3 Example 117B (a) MgAPSO-39, as prepared in example 55B, was subjected to x-ray analysis. MgAPSO-39 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The MgAPSO-39 compositions are generally characterized by the data of Table XXIII-B below: 2ϑ d,(Å) Relative Intensity 9.2-9.6 9.61-9.21 m 13.1-13.5 6.76-6.56 m 17.8-18.3 4.98-4.85 m 20.8-21.3 4.27-4.17 m-vs 22.2-22.8 4.00-3.90 vs 30.0-30.3 2.979-2.950 w-m (c) The MgAPSO-39 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXIV-B below. 2ϑ d,(Å) 100 x I/Io 9.2-9.6 9.61-9.21 20-53 13.1-13.5 6.76-6.56 25-53 17.8-18.3 4.98-4.85 23-34 20.8-21.3 4.27-4.17 70-100 22.2-22.8 4.004-3.900 97-100 26.8-27.05 3.326-3.296 3-4 28.0-28.2 3.191-3.175 0-4 28.6-28.8 3.121-3.100 sh-17 29.4-29.8 3.038-2.998 13-20 30.0-30.3 2.979-2.950 17-29 32.4-32.8 2.763-2.730 10-16 33.9-34.2 2.644-2.622 sh-11 36.7-36.85 2.448-2.439 0-2 37.8-38.1 2.380-2.362 5-9 40.7-41.0 2.217-2.201 0-5 43.0-43.4 2.103-2.085 0-2 45.0 2.014 0-1 46.2-46.3 1.966-1.961 0-2 47.2-47.3 1.926-1.922 0-1 48.5-48.85 1.877-1.864 4-5 49.0-49.5 1.859-1.841 0-3 51.0-51.5 1.791-1.778 3-5 52.1-52.4 1.755-1.746 0-4 54.2-54.6 1.692-1.681 0-2 Example 118B (a) MgAPSO-43, as prepared in example 92B, was subjected to x-ray analysis. MgAPSO-43 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-43 of part a) was calcined in air at 500°C for about 1 hour and at 600°C for about 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 6.95 12.73 30 8.15 10.87 47 12.95 6.83 35 17.4 5.10 10 21.45 4.14 100 23.2* 3.832 44 28.15 3.167 25 (c) The MgAPSO-43 compositions are generally characterized by the data of Table XXV-B below: 2ϑ d,(Å) Relative Intensity 12.3-12.95 7.20-6.83 m-vs 17.3-17.45 5.13-5.09 w 21.45-21.6 4.15-4.12 m-vs 27.6-27.75 3.232-3.215 m 33.05-33.2 2.710-2.699 w (d) The MgAPSO-43 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXVI-B below: 2ϑ d,(Å) 100 x I/Io 12.3-12.95 7.20-6.83 35-100 15.15-15.5 5.85-5.37 2-4 17.3-17.45 5.13-5.09 12 19.7-19.85 4.51-4.47 3-5 21.45-21.6 4.15-4.12 49-100 24.35-24.5 3.653-3.635 2 26.7-26.85 3.336-3.319 7-9 27.6-27.75 3.232-3.215 39-50 28.05-28.2 3.182-3.165 18-25 28.55-28.75 3.126-3.107 5-6 33.05-33.2 2.710-2.699 8-12 35.8-35.9 2.510-2.502 3-4 45.4-45.55 1.997-1.991 3 51.1-51.2 1.788-1.785 4 52.0-52.25 1.759-1.750 1-2 53.0-53.1 1.728-1.725 3-4 53.7-53.95 1.707-1.700 2 Example 119B (a) MgAPSO-44, as prepared in example 88B, was subjected to X-ray analysis. MgAPSO-44 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-44 of part (a) was calcined in air for 2.5 hours at 500°C and then for 0.25 hour at 600°C. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-44 compositions are generally characterized by the data of Table XXVII-B below: 2ϑ d,(Å) 100 x I/Io 9.2-9.45 9.61-9.37 vs 15.9-16.1 5.57-5.50 m 17.2-18.0 5.16-4.93 vw-m 20.5-20.75 4.33-4.28 m-vs 24.3-25.0 3.663-3.562 w-m 30.5-31.0 2.931-2.885 w-m (d) the MgAPSO-44 compositions for which x-ray powder diffraction data have been obtained to date have pattens which are characterized by the x-ray powder diffraction shown in Table XXVIII-B below: 2ϑ d,(Å) 100 x I/Io 9.2-9.45 9.61-9.37 100 12.8-13.0 6.92-6.81 11-35 13.6-14.0 6.51-6.33 2-4 14.5-14.6 6.11-6.07 0-5 15.9-16.1 5.57-5.50 20-36 17.2-18.0 5.16-4.93 7 18.8-19.0 4.72-4.67 7-53 20.5-20.75 4.33-4.28 58-100 21.7-21.8 4.10-4.08 0-18 22.3-22.6 3.986-3.934 sh 23.0-23.3 3.867-3.817 8 24.3-25.0 3.663-3.562 17-58 25.8-26.15 3.453-3.406 10-18 27.5-27.8 3.243-3.209 1-12 28.2 3.175 0-3 29.6-29.8 3.018-2.998 0-sh 29.7-30.5 3.008-2.931 4-15 30.5-31.0 2.931-2.885 16-48 31.4-31.6 2.849-2.831 sh-1 32.2-32.5 2.780-2.755 1-5 32.7-33.2 2.739-2.698 sh-3 34.8 3.578 0-1 35.3-36.0 2.543-2.495 3-6 36.8 2.442 0-1 38.4-38.6 2.344-2.338 0-1 39.0-39.1 2.309-2.304 0-1 39.6-40.0 2.276-2.254 0-1 42.0-42.2 2.151-2.141 0-6 43.3-43.6 2.090-2.076 0-2 46.5 1.953 0-1 47.1-47.5 1.929-1.914 0-5 48.0-48.2 1.895-1.888 0-8 48.5-48.8 1.877-1.866 0-5 50.0-50.8 1.824-1.797 4-10 51.6-51.8 1.771-1.765 0-1 53.0-53.8 1.728-1.704 4-10 54.3-54.6 1.689-1.681 0-2 Example 120B (a) MgAPSO-46, as prepared in example 44B, was subjected to x-ray analysis. MgAPSO-46 was determined to have a characteristic x-ray powder difffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-46 of part (a) was calcined in nitrogen at 500°C for about 1.75 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-46 compositions are generally characterized by the data of Table XXIX-B below: 2ϑ d,(Å) Relative Intensity 7.2-8.1 12.28-10.92 vs 21.2-21.8 4.19-4.08 w-m 22.5-23.0 3.952-3.867 vw-m 26.6-27.2 3.351-3.278 vw-w 28.5-29.0 3.132-3.079 vw-w (d) The MgAPSO-46 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXX-B below: 2ϑ d, (Å) 100 x I/Io 6.5-6.9 13.60-12.81 3-10 7.2-8.1 12.28-10.92 100 9.8-10.3 9.03-8.59 0-1 12.4 7.14 0-4 12.9-13.5 6.86-6.56 2-8 13.5-14.0 6.56-6.33 3-8 14.8-15.2 5.99-5.83 1-9 15.2-15.8 5.83-5.61 (sh)-5 16.5-17.6 5.37-5.04 3-11 17.3-17.4 5.13-5.10 0-1 19.7-20.2 4.51-4.40 (sh)-5 20.3-20.7 4.37-4.29 4-9 21.2-21.8 4.19-4.08 10-36 22.5-23.0 3.952-3.867 6-20 23.7-24.4 3.754-3.648 3-11 25.0-25.5 3.562-3.648 0-1 26.6-27.2 3.351-3.278 4-17 27.5-27.9 3.243-3.198 3-12 28.0-28.4 3.255-3.143 sh-2 28.5-29.0 3.132-3.079 4-15 29.6-30.2 3.018-2.959 1-4 30.9-31.4 2.894-2.849 2-6 31.6-32.0 2.831-2.797 1-3 32.6-33.4 2.747-2.683 1-2 33.95-34.4 2.640-2.607 1-4 35.7-36.2 2.515-2.481 2-6 36.3-37.0 2.475-2.430 0-2 37.0-37.6 2.430-2.392 0-1 37.9-38.4 2.374-2.344 0-1 39.5-40.2 2.281-2.243 0-1 40.7-41.3 2.217-2.186 0-1 43.7-44.3 2.071-2.045 0-1 45.8-46.4 1.981-1.957 0-1 47.3-47.9 1.922-1.899 0-1 49.2-49.3 1.852-1.848 0-1 49.9-50.5 1.828-1.807 0-1 51.2-51.9 1.784-1.762 0-1 52.1-52.6 1.755-1.740 0-1 Example 121-B (a) MgAPSO-47, as prepared in example 104B, was subjected to x-ray analysis. MgAPSO-47 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized MgAPSO-47 of part a) was calcined in air at 500°C for about 1.75 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The MgAPSO-47 compositions are generally characterized by the date of Table XXXI-B below: 2ϑ d,(Å) Relative Intensity 9.5-9.65 9.33-9.17 vs 12.85-13.05 6.89-6.79 vw-m 16.0-16.2 5.54-5.46 w-m 20.6-20.85 4.32-4.26 m-s 24.75-25.3 3.598-3.526 vw-m 30.55-30.95 2.925-2.889 w-m (d) the MgAPSO-47 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXXII-B below: 2ϑ d,(Å) 100 x I/Io 9.5-9.65 9.33-9.17 100 12.85-13.05 6.89-6.79 7-20 13.9-14.2 6.36-6.25 3-7 16.0-16.2 5.54-5.46 14-41 17.65-18.0 5.03-4.92 4-11 19.0-19.3 4.67-4.60 2-3 20.6-20.85 4.32-4.26 33-89 21.9-22.3 4.06-3.98 2-7 23.0-23.3 3.866-3.819 3-11 24.75-25.3 3.598-3.526 8-22 25.85-26.2 3.444-3.400 7-18 27.6-28.0 3.229-3.188 2-7 27.95-28.5 3.190-3.132 1-4 29.5-29.95 3.030-3.983 2-5 30.55-30.95 2.925-2.889 13-36 30.9-31.4 2.891-2.849 sh 31.4-31.5 2.849-2.837 0-3 32.4 2.763 0-1 33.25 2.695 0-3 34.4-34.8 2.606-2.575 3-7 34.95 2.567 0-1 35.8-36.55 2.510-2.459 1-4 38.5 2.338 0-2 39.1-39.65 2.305-2.273 0-4 39.6-39.7 2.275-2.270 0-4 42.5-42.8 2.126-2.115 0-3 43.3-43.8 2.091-2.067 0-2 47.6-47.7 1.911-1.907 0-3 48.7-49.3 1.870-1.848 1-7 50.4-51.1 1.810-1.787 1-5 51.7 1.768 0-1 52.45 1.745 0-1 53.3 1.719 0-2 54.1 1.695 0-1 54.7 1.681 0-1 55.9 1.645 0-2 Example 122B In order to demonstrate the catalytic activity of the MgAPSO compositions, calcined samples of MgAPSO products were tested for catalytic cracking of n-butane using a bench-scale apparatus. The reactor was a cylindrical quartz tube 254mm. in length and 10.3mm. I.D. In each test the reactor was loaded with particles of the test MgAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The MgAPSO samples had been previously calcined in air or nitrogen to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium-n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the MgAPSO compositions. The k A value (cm³/g min) obtained for the MgAPSO compositions are set forth, below, in Table XXX-B: MgAPSO Prepared in Example No. Rate Constant (k A ) MgAPSO-35 80B 2.6 MgAPSO-34 63B 4.1 MgAPSO-35 82B 0.9 MgAPSO-36 5B 18.0 MgAPSO-46 44B 7.3 MgAPSO-47 104B 1.7 C. IRON-ALUMINUM-PHOSPHORUS-SILICON-OXIDE SIEVES Molecular sieves containing iron, aluminum phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the FeAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: (a) Alipro: aluminum isopropoxide, Al(OCH(CH₃)₂)₃; (b) LUDOX-LS: LUDOX-LS is the trademark of Du Pont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; (c) CATAPAL: trademark for hydrated aluminum oxide containing about 75 wt. % Al₂O₃ (pseudo-boehmite phase) and about 25 wt. percent water. (c) Fe(Ac)₂: Iron (II) acetate; (d) FeSO₄: Iron (II) sulfate hexahydrate; (e) H₃PO₄: 85 weight percent phosphoric acid in water; (f) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; (g) TBAOH: 40 weight percent aqueous solution of tetrabutylammonium hydroxide; (h) Pr₂NH: di-n-propylamine ((C₃H₇)₂NH); (i) Pr₃N: tri-n-propylamine ((C₃H₇)₃N); (j) Quin: Quinuclidine (C₇H₁₃N); (k) MQuin: Methyl Quinuclidine hydroxide (C₇H₁₃NCH₃OH); (l) TMAOH: tetramethylammonium hydroxide pentahydrate; and (m) C-hex: cyclohexylamine. Examples 1C to 16C a) Examples 1C to 8C were carried out to demonstrate the preparation of FeAPSO-34 and FeAPSO-5. The reaction mixtures were prepared by grinding the aluminum isopropoxide in a blender followed by slowly adding the H₃PO₄ solution with mixing. A solution/dispersion of iron acetate in water was added and then the LUDOX-LS was added. The organic templating agent was then added to this mixture, or in some cases one-half of this mixture, and the mixture blended to form a homogeneous mixture. The number of moles of each component in the reaction mixture was as follows: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.2 FeO 0.2 TEAOH 1.0 H₂O 50 Each reaction mixture was sealed in a stainless steel pressure vessel lined with polytetrafluoroethylene and heated in an oven at a temperature (see Table I-C), time (see Table I-C) and at the autogeneous pressure. The solid reaction product was recovered by filtration, washed with water and dried at room temperature. The products were analyzed and the observed FeAPSO products reported in Table I-C. b) Examples 9C to 16C were carried out to demonstrate the preparation of FeAPSO-11 and FeAPSO-5. The reaction mixtures were prepared by grinding the aluminum iso-propoxide in a blender followed by addition of a solution/dispersion of Iron (II) acetate. H₃PO₄ was added to this mixture and the resulting mixture blended to form a homogeneous mixture. LUDOX-LS was added to this mixture except that in examples 13C to 16C the LUDOX-LS was added with the H₃PO₄. The resulting mixtures were blended until a homogeneous mixture was observed. Organic templating agent was added to each mixture and the resulting mixtures placed in a stainless steel pressure vessel lined with polytetrafluoroethylene and heated, washed and the product recovered as in part a) of this example. The products were analyzed and the observed FeAPSO products reported in Table I-C. The number of moles of each component in the reaction mixture was as follows: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.2 FeO 0.2 Template 1.0 H₂O 50 c) Two reaction mixtures, designated Examples AC and BC in Table I-C, did not show FeAPSO products when analyzed by X-ray. Examples AC and BC followed the same procedure employed for Examples 5C and 6C. Examples 15C to 19C Examples 15C to 19C were carried out according to the general preparative procedure employed for examples 7C to 14C with examples 15C to 18C following the procedure employed for examples 7C to 10C and example 19C following the procedure followed for examples 11C to 14C. The reactive source of iron was Iron (II) sulfate instead of Iron (II) acetate. The temperature and time for the crystallization (digestion) procedure are set forth in Table II-C. The number of moles of each component in the reaction mixtures for examples 15C to 18C was as follows: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.6 FeO 0.2 Pr₃N 1.5 H₂O 50 The number of moles of each component in the reaction mixture of example 19C was as follows: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.2 FeO 0.2 Pr₃N 1.0 H₂O 50 The products were subjected to analysis by x-ray and the observed FeAPSO products reported in Table II-C. Examples 20C-27C Examples 20C-27C were carried out according to the general preparative procedure employed for examples 1C to 8C using the following number of moles of each component in the reaction mixture: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.2, 0.6 FeO 0.2 Template 1.0 H₂O 50 The temperature and time for the crystallization procedure and the observed FeAPSO products are reported in Table III-C. Examples 28C and 29C Examples 28C and 29C were carried out according to the procedure of examples 13C to 16C, except that Iron (II) sulfate, was employed as the reactive iron source instead of Iron (II) acetate. The number of moles of each component in the reaction mixture for each example was as follows: Component Moles Al₂O₃ 0.8 P₂O₅ 1.0 SiO₂ 0.4 FeO 0.4 Template 2.0 H₂O 83 Examples CC and DC followed the procedure for Examples 28C and 29C. X-ray analysis of the reaction products did not show FeAPSO products. The temperature and time for the crystallization procedure and the observed FeAPSO products are reported in Table IV-C. Examples 30C to 43C Examples 30C to 43C were carried out according to the procedure employed for examples 1C to 8C except that in examples 30C and 31C the aluminum source was CATAPAL and in examples 33C to 36C and 43C a seed crystal of a topologically similar molecular sieve was employed. The number of moles of each component in the reaction mixture in examples 30C to 43C was: Component Moles Al₂O₃ 0.9 P₂O₅ 0.9 SiO₂ 0.2 FeO 0.2 Template 1.0 H₂O 50 The template, temperature, time for the crystallization procedure and the observed FeAPSO products are reported in Table V-C. Example 44C (a) Samples of FeAPSO products were calcined at 600°C in air for 2 hours to remove at least part of the organic templating agent, except that FeAPSO-5 and FeAPSO-11 were calcined for 2.25 hours. The example in which the FeAPSO was prepared is indicated in parenthesis. The adsorption capacities of each calcined sample were measured using a standard McBain-Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum at 350°C prior to measurement. The McBain-Bakr data for the FeAPSO compositions are set forth hereinafter. (b) FeAPSO-5 (example 12C): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 9.7 O₂ 3.46 734 -183 11.6 neopentane 6.2 100 24.5 3.8 cyclohexane 6.0 59 23.7 5.7 H₂O 2.65 4.6 23.9 10.7 H₂O 2.65 20.0 23.6 19.2 The above data demonstrate that the pore size of the calcined product is greater than 6.2Å. (c) FeAPSO-11 (example 10C): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 7.6 O₂ 3.46 734 -183 9.2 neopentane 6.2 100 24.5 0.2 cyclohexane 6.0 59 23.7 4.2 H₂O 2.65 4.6 23.9 10.8 H₂O 2.65 20.0 23.6 16.7 The above data demonstrate that the pore size of the calcined product is about 6.0Å. (d) FeAPSO-20 (example 31C): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 1.5 O₂ 3.46 749 -183 8.5 H₂O 2.65 4.6 23.2 22.7 H₂O 2.65 16.8 23.5 30.0 The above data demonstrates that the pore size of the calcined product is about 3.0Å. (e) FeAPSO-31 (example 34C): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 6.8 O₂ 3.46 749 -183 11.6 neopentane 6.2 100 23.4 3.6 cyclohexane 6.0 57 23.4 6.9 H₂O 2.65 4.6 23.2 6.5 H₂O 2.65 16.8 23.5 21.3 The above data demonstrates that the pore size of the calcined product is greater than about 6.2Å. (f) FeAPSO-46 (example 38C): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 100 -183 2.6 O₂ 3.46 749 -183 11.7 neopentane 6.2 100 23.4 1.1 cyclohexane 6.0 57 23.4 6.4 H₂O 2.65 4.6 23.2 7.2 H₂O 2.65 16.8 23.5 13.0 The above data demonstrates that the pore size of the calcined product is greater than about 6.2Å. Example 45C Samples of FeAPSO products were subjected to chemical analysis as follows: (a) The chemical analysis for FeAPSO-5 (example 12C) was: Component Weight Percent Al₂O₃ 32.2 P₂O₅ 45.4 FeO 4.7 SiO₂ 1.9 Carbon 4.9 LOI 14.6 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.14R:0.21 FeO; 1.0 Al₂O₃: 1.01 P₂O₅: 0.10 SiO₂; and a formula (anhydrous basis) of: 0.03R (Fe 0.05 Al 0.46 P 0.47 Si 0.02 )O₂ (b) The chemical analysis of FeAPSO-11 (example 10C) was: Component Weight Percent Al₂O₃ 33.2 P₂O₅ 48.8 FeO 4.5 SiO₂ 2.4 Carbon 5.1 LOI 9.8 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.22R:0.19FeO; 1.0 Al₂O₃; 1.06 P₂O₅; 0.08 SiO₂; and a formula (anhydrous basis) of: 0.05(Fe 0.04 Al 0.45 P 0.48 Si 0.03 )O₂ (c) The chemical analysis of FeAPSO-20 (example 31C) was: Component Weight Percent Al₂O₃ 29.1 P₂O₅ 42.0 FeO 4.8 SiO₂ 2.5 Carbon 7.6 LOI 19.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.55R;0.23FeO; 1.0 Al₂O₃; 1.04 P₂O₅; 0.15 SiO₂; and a formula (anhydrous basis) of: 0.12(Fe 0.05 Al 0.45 P 0.47 Si 0.03 )O₂ (d) The chemical analysis of FeAPSO-31 (example 34C) was: Component Weight Percent Al₂O₃ 34.7 P₂O₅ 45.3 FeO 4.2 SiO₂ 1.6 Carbon 3.4 LoI 12.9 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.14R:0.17FeO; 1.0 Al₂O₃; 0.94 P₂O₅; 0.08 SiO₂; and a formula (anhydrous basis) of: 0.03(Fe 0.04 Al 0.49 P 0.45 Si 0.02 )O₂ Example 46C EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction-with SEM (scanning electron microscope) was carried out on clear crystals of FeAPSO products of the hereinafter designated examples. Analysis of crystals having a morphology characteristic of FeAPSO-5, FeAPSO-11, FeAPSO-20, FeAPSO-31, FeAPSO-34 and FeAPSO-46 gave the following analysis based on relative peak heights: a) FeAPSO-5 (example 12C) : Average of Spot Probes Fe 0.02 Al 0.44 P 0.52 Si 0.02 b) FeAPSO-11 (example 10C) : Average of Spot Probes Fe 0.03 Al 0.42 P 0.52 Si 0.03 c) FeAPSO-20 (example 31C) : Average of Spot Probes Fe 0.04 Al 0.42 P 0.49 Si 0.05 d) FeAPSO-31 (example 34C) : Average of Spot Probes Fe 0.01 Al 0.44 P 0.48 Si 0.06 e) FeAPSO-34 (example 3C) : Average of Spot Probes Fe 0.04 Al 0.43 P 0.45 Si 0.07 f) FeAPSO-46 (example 38C) : Average of Spot Probes Fe 0.05 Al 0.40 P 0.43 Si 0.12 Example 47C (a) FeAPSO-5, as prepared in example 12C, was subjected to x-ray analysis. FeAPSO-5 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized FeAPSO-5 of part a) was calcined in air at a temperature beginning at 500°C and ending at 600°C over a period of 2.25 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 7.4 11.95 100 7.9 11.19 sh 8.45 10.46 35 12.85 6.89 18 14.8 5.99 8 15.5 5.72 13 16.4 5.40 2 17.0 5.22 5 19.75 4.50 31 20.2 4.40 14 21.1 4.21 33 21.4 4.15 sh 22.0 4.04 sh 22.45 3.960 83 23.8 3.739 1 24.8 3.59 2 25.1 3.548 2 25.95 3.434 31 27.0 3.302 2 27.9 3.198 3 29.05 3.074 14 30.05 2.974 22 31.5 2.840 29 31.65 2.827 5 34.55 2.596 15 35.0 2.564 3 36.1 2.488 1 37.0 2.430 4 37.8 2.380 8 38.2 2.356 2 39.2 2.298 2 40.2 2.151 2 42.3 2.137 2 43.0 2.103 1 43.8 2.067 2 45.2 2.006 2 46.6 1.949 2 47.7 1.907 4 51.6 1.771 4 55.6 1.653 2 (c) The FeAPSO-5 compositions are generally characterized by the data of Table VI-C below: 2ϑ d,(Å) Relative Intensity 7.3-7.5 12.11-11.79 m-vs 14.8-14.95 5.99-5.93 w-m 19.6-19.8 4.53-4.48 m 21.0-21.2 4.23-4.19 m 22.35-22.5 3.98-3.95 m-vs 25.8-25.95 3.453-3.434 w-m (d) The FeAPSO-5 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table VII-C, below: 2ϑ d,(Å) 100 x I/Io 7.3-7.5 12.11-11.79 55-100 12.8-13.0 6.92-6.81 7-18 14.8-14.95 5.99-5.93 17-27 19.6-19.8 4.53-4.48 24-60 21.0-21.2 4.23-4.19 27-53 22.35-22.5 3.98-3.95 38-100 24.7-24.85 3.604-3.583 0-6 25.8-25.95 3.453-3.434 15-68 28.85-29.05 3.095-3.074 6-24 29.8-30.05 2.998-2.974 9-27 33.45-33.7 2.679-2.660 2-10 34.4-34.55 2.607-2.596 8-17 36.9-37.0 2.436-2.564 1-7 37.65-37.9 2.389-2.374 4-13 41.4-41.6 2.181-2.171 0-4 42.1-42.3 2.146-2.137 0-4 42.6-43.1 2.122-2.099 0-4 43.5-43.8 2.080-2.067 0-4 44.9-45.2 2.019-2.006 0-7 47.6-47.7 1.910-1.907 0-5 51.3-51.6 1.781-1.771 0-4 55.4-55.6 1.658-1.653 1-6 Example 48C (a) FeAPSO-11, as prepared in example 10C, was subjected to x-ray analysis. FeAPSO-11 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d,(Å) 100 x I/Io 8.1 10.92 31 9.45 9.36 47 13.15 6.73 15 15.7 5.64 34 16.2 5.47 5 19.0 4.67 6 20.3 4.37 43 21.0 4.23 100 22.1 4.022 62 22.5 3.952 sh 22.65 3.926 61 23.1 3.850 86 24.7 3.604 10 26.4 3.376 25 28.2 3.164 sh 28.6 3.121 17 29.0 3.079 sh 29.5 3.028 7 31.5 2.840 9 32.7 2.755 19 33.6 2.667 2 34.1 2.629 9 36.3 2.415 6 37.7 2.386 14 39.2 2.298 5 42.9 2.108 5 44.7 2.027 6 50.6 1.804 5 54.7 1.678 5 55.5 1.656 3 (b) A portion of the as-synthesized FeAPSO-11 of part a) was calcined in air at 600°C for about 2.25 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 8.05 10.98 60 9.5 9.31 72 12.9 6.86 sh 13.1 6.76 20 13.7 6.46 3 14.7 6.03 3 15.9 5.57 55 16.1 5.51 sh 17.6 5.04 3 19.9 4.46 sh 20.3 4.37 28 21.3 4.17 100 21.9 4.06 sh 22.4 3.969 88 23.0 3.867 sh 23.4 3.802 70 24.0 3.708 3 24.4 3.648 5 25.0 3.562 4 25.8 3.453 7 26.5 3.363 20 27.7 3.220 5 29.0 3.079 sh 29.6 3.018 20 30.4 2.940 7 31.8 2.814 10 32.7 2.739 18 34.1 2.629 5 34.5 2.600 4 35.6 2.522 4 36.2 2.481 4 38.0 2.368 10 43.3 2.090 3 44.8 2.023 5 49.0 1.859 3 49.6 1.838 3 54.6 1.681 3 55.7 1.650 3 (c) The FeAPSO-11 compositions are generally characterized by the data of Table VIII-C below: 2ϑ d,(Å) Relative Intensity 8.05-8.1 10.98-10.92 m-s 9.4-9.5 9.41-9.31 m 21.0-21.3 4.23-4.17 vs 22.1-22.4 4.022-3.969 m-s 22.65-23.1 3.926-3.850 vw-m 23.1-23.4 3.850-3.802 m-s (d) The FeAPSO-11 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table IX-C, below: 2ϑ d,(Å) 100 x I/Io 8.05-8.1 10.98-10.92 30-80 9.4-9.5 9.41-9.31 47-78 13.05-13.2 6.78-6.71 13-24 15.7-15.9 5.64-5.57 33-54 16.15-16.3 5.49-5.44 0-6 18.9-19.05 4.70-4.66 0-6 20.2-20.4 4.40-4.35 30-43 21.0-21.3 4.23-4.17 100 21.9 4.06 sh 22.1-22.4 4.022-3.969 54-86 22.5-22.6 3.952-3.934 sh 22.65-23.1 3.926-3.850 sh-61 23.1-23.4 3.850-3.802 48-86 24.4-24.5 3.648-3.633 sh-6 24.7-24.9 3.604-3.576 0-10 26.4-26.5 3.376-3.363 15-25 28.6-28.8 3.121-3.100 17-19 28.9-29.0 3.079-3.089 sh 29.5-29.6 3.028-3.018 7-21 31.5-31.8 2.840-2.814 8-12 32.7-32.85 2.755-2.726 13-19 34.1-34.25 2.629-2.618 5-9 36.2-36.5 2.481-2.462 5-7 37.6-38.0 2.392-2.368 7-14 39.2-39.4 2.298-2.287 2-5 42.9-43.2 2.108-2.094 3-5 44.7-44.9 2.027-2.019 3-6 48.3-48.4 1.884-1.881 0-2 50.5-50.9 1.807-1.794 0-5 54.5-54.8 1.684-1.675 0-5 55.4-55.6 1.658-1.653 0-3 Example 49C (a) FeAPSO-16, as prepared in example 21C, was subjected to x-ray analysis. FeAPSO-16 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) The FeAPSO-16 compositions are generally characterized by the data of Table X-C below: 2ϑ d,(Å) Relative Intensity 11.3-11.4 7.83-7.76 m 18.55-18.75 4.78-4.73 m 21.85-22.0 4.07-4.04 vs 26.45-26.6 3.370-3.351 w-m 29.6-29.8 3.018-2.998 w-m (c) The FeAPSO-16 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XI-C, below: 2ϑ d,(Å) 100 x I/Io 11.3-11.4 7.83-7.76 38-63 18.55-18.75 4.78-4.73 31-63 21.85-22.0 4.07-4.04 100 22.9 3.883 sh-10 26.45-26.6 3.370-3.351 18-26 28.9-29.0 3.089-3.079 0-13 29.6-29.8 3.018-2.998 17-30 32.4-32.8 2.763-2.730 0-13 34.5-34.6 2.600-2.592 0-10 37.65-37.9 2.389-2.374 0-10 39.5-39.7 2.281-2.270 0-6 44.1-44.5 2.054-2.036 0-6 48.2-48.5 1.888-1.877 0-8 52.0-52.4 1.759-1.746 0-3 54.4-54.8 1.687-1.675 0-3 Example 50C (a) FeAPSO-20, as prepared to in example 31C, was subjected to x-ray analysis. FeAPSO-20 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d,(Å) 100 x I/Io 14.0 6.32 59 19.85 4.47 47 22.25 3.998 4 24.35 3.654 100 28.2 3.164 16 31.6 2.831 12 34.7 2.584 16 37.6 2.394 2 40.3 2.240 4 42.85 2.110 5 47.65 1.909 4 52.0 1.758 8 (b) A portion of the as-synthesized FeAPSO-20 of part a) was calcined in air heating the sample from 500°C to 600°C over a period of 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100 x I/Io 7.05 12.56 6 7.5 11.82 6 14.05 6.31 100 20.05 4.43 28 22.6 3.935 6 23.85 3.733 5 24.5 3.635 45 28.4 3.143 11 31.7 2.823 11 34.8 2.578 9 (c) The FeAPSO-20 compositions are generally characterized by the data of Table XII-C below: 2ϑ d,(Å) Relative Intensity 13.95-14.0 6.34-6.33 m-vs 19.8-20.0 4.48-4.44 m 24.3-24.5 3.663-3.633 m-vs 28.15-28.4 3.169-3.143 w 31.6-31.7 2.831-2.823 w 34.7-34.8 2.585-2.578 w (d) The FeAPSO-20 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XIII-C, below: 2ϑ d,(Å) 100 x I/Io 13.95-14.0 6.34-6.33 57-100 19.8-20.0 4.48-4.44 28-47 22.25-22.6 3.998-3.935 3-6 24.3-24.5 3.663-3.633 45-100 28.15-28.4 3.169-3.143 11-16 31.6-31.7 2.831-2.823 11-12 34.7-34.8 2.585-2.578 9-16 37.6 2.392 2-3 40.2-40.3 2.242-2.240 4 42.7-42.85 2.114-2.110 5 47.5-47.6 1.914-1.909 3-4 52.0 1.759 8 Example 51C (a) FeAPSO-31, as prepared in example 34C, was subjected to x-ray analysis. FeAPSO-31 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-synthesized FeAPSO-31 of part a) was calcined in air at 600°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The FeAPSO-31 compositions are generally characterized by the data of Table XIV-C below: 2ϑ d, (Å) Relative Intensity 8.5-8.6 10.40-10.28 w-s 20.2-20.4 4.40-4.35 m 21.1-21.2 4.21-4.19 w 22.0-22.1 4.040-4.022 m 22.6-22.7 3.934-3.917 vs 31.7-31.9 2.822-2.805 w-m (d) The FeAPSO-31 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XV-C below: 2ϑ d,(Å) 100 x I/Io 8.5-8.6 10.40-10.28 10-88 9.5-9.8 9.35-9.04 3-11 9.9 8.92 0-3 13.0-13.3 6.81-6.67 1-4 14.6-14.9 6.07-5.95 0-5 15.7-16.2 5.64-5.46 3-7 17.0-17.2 5.20-5.17 5-11 18.3-18.5 4.84-4.80 2-4 20.2-20.4 4.40-4.35 36-50 21.1-21.2 4.21-4.19 9-18 22.0-22.1 4.040-4.022 26-44 22.6-22.7 3.934-3.919 100 23.2-23.4 3.833-3.795 3-12 25.1-25.3 3.546-3.521 4-5 25.6-25.8 3.474-3.449 3-9 26.4-26.6 3.372-3.352 0-5 27.4-27.5 3.258-3.248 2-4 27.9-28.1 3.195-3.174 12-14 28.3 3.152 0-3 28.7-28.8 3.111-3.103 0-3 29.7-29.9 3.008-2.990 6-12 31.1 2.876 0-2 31.7-31.9 2.822-2.805 19-30 32.7-33.0 2.739-2.718 0-3 35.1-35.3 2.555-2.542 9-10 36.1-36.3 2.489-2.475 2-5 37.3-37.4 2.418-2.407 0-3 37.6-37.8 2.390-2.378 2-3 38.1-38.4 2.365-2.346 2-3 39.3-39.5 2.293-2.282 3-4 39.6-39.7 2.275-2.271 0-3 40.2-40.3 2.244-2.239 0-3 44.1 2.052 0-2 44.9 2.020 0-2 45.0-45.1 2.015-2.012 0-2 45.2-45.4 2.006-1.997 2-3 46.6-46.8 1.947-1.940 3-5 47.5-47.6 1.914-1.909 0-2 48.6-48.9 1.872-1.863 2-3 49.1-49.3 1.854-1.848 0-3 50.8-50.9 1.799-1.793 0-2 51.6-51.8 1.771-1.765 0-4 55.5-55.6 1.657-1.653 0-3 Example 52C (a) FeAPSO-34, as prepared in example 3C, was subjected to x-ray analysis. FeAPSO-34 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 7.3 12.1 5 9.35 9.5 100 12.7 7.0 10 14.0 6.3 8 14.8 5.99 2 15.9 5.57 32 17.9 4.96 7 19.6 4.53 3(sh) 20.4 4.35 50 22.3 3.99 6 22.9 3.88 2 25.1 3.548 10 25.7 3.466 11 27.5 3.243 2 28.2 3.164 2 29.4 3.038 2(sh) 30.4 2.940 19 31.1 2.876 12 34.4 2.607 4 36.2 2.481 2 39.5 2.281 2 43.3 2.090 3 47.5 1.914 2 48.9 1.863 3 51.0 1.791 2 53.0 1.728 2 54.5 1.684 1 (b) A portion of the as-synthesized FeAPSO-34 of part a) was calcined in air at 600°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d, (Å) 100 x I/Io 7.5 11.79 7 9.6 9.21 100 13.0 6.81 17 16.2 5.47 9 16.9 5.25 1 18.0 4.93 5 19.3 4.60 5 19.9 4.46 2 20.9 4.25 17 22.55 3.943 7 23.4 3.802 2 24.2 3.678 2 25.1 3.548 5 26.2 3.401 7 27.2 3.278 1 28.2 3.164 2 29.2 3.058 2 31.0 2.885 16 (c) The FeAPSO-34 compositions are generally characterized by the data of Table XVI-C below: 2ϑ d, (Å) Relative Intensity 9.35-9.7 9.46-9.12 vs 12.7-13.0 6.97-6.81 w-m 15.9-16.2 5.57-5.47 w-m 20.4-20.9 4.35-4.25 w-s 22.3-22.5 3.99-3.95 vw-s 25.7-26.2 3.466-3.401 vw-m (d) The FeAPSO-34 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XVII-C below: 2ϑ d, (Å) 100 x I/Io 9.35-9.7 9.46-9.12 100 12.7-13.0 6.97-6.81 10-25 13.9-14.1 6.37-6.28 2-11 15.9-16.2 5.57-5.47 9-47 17.6-18.0 5.04-4.93 5-16 18.9-19.3 4.70-4.60 0-5 20.4-20.9 4.35-4.25 17-89 22.3-22.5 3.99-3.95 4-88 22.9-23.4 3.88-3.80 2-8 24.8-25.3 3.59-3.52 5-18 25.7-26.2 3.466-3.401 7-32 27.5-27.6 3.243-3.232 0-5 28.0-28.4 3.187-3.143 1-3 29.4-29.6 3.038-3.018 0-4(sh) 30.4-30.6 2.940-2.922 0-28 31.0-31.2 2.885-2.867 2(sh)-17 32.4 2.763 0-1 34.4-34.6 2.607-2.592 0-13 35.9-36.3 2.501-2.475 0-3 39.5-39.6 2.281-2.276 0-3 43.3-43.4 2.090-2.085 0-4 47.5-47.6 1.914-1.910 0-5 48.6-49.1 1.873-1.855 0-7 50.6-51.1 1.804-1.787 0-3 53.0-53.2 1.728-1.722 0-3 54.5-54.6 1.684-1.681 0-1 Example 53C (a) FeAPSO-35, as prepared in example 27C, was subjected to x-ray analysis. FeAPSO-35 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 8.7 10.19 5 11.0 8.03 sh 11.4 7.77 51 13.5 6.57 9 16.0 5.55 3 17.4 5.09 28 17.9 4.95 5 18.65 4.76 50 21.0 4.22 15 21.9 4.06 100 22.9 3.885 9 23.45 3.793 8 25.1 3.548 3 26.5 3.365 25 27.15 3.285 7 28.6 3.118 16 28.9 3.091 (sh) 29.7 3.010 27 32.2 2.780 (sh) 32.5 2.754 13 34.6 2.591 7 37.8 2.381 10 44.1 2.053 3 48.25 1.886 8 51.6 1.774 1 52.15 1.754 2 54.5 1.684 3 (b) The FeAPSO-35 compositions are generally characterized by the data of Table XVIII-C below: 2ϑ d, (Å) Relative Intensity 10.9-11.1 8.12-7.97 vw-m 13.2-13.5 6.71-6.56 vw-w 17.2-17.4 5.16-5.10 w-m 21.85-22.0 4.07-4.04 vs 23.2-23.8 3.834-3.739 vw-m 32.0-32.25 2.797-2.776 vw-m (c) The FeAPSO-35 compositions are generally characterized by the x-ray powder diffraction pattern shown in Table XIX-C, below: 2ϑ d, (Å) 100 x I/Io 8.6-8.7 10.28-10.19 0-14 10.9-11.1 8.12-7.97 sh-38 13.2-13.5 6.71-6.56 7-19 15.8-16.2 5.61-5.47 1-6 17.2-17.4 5.16-5.10 11-41 17.75-17.9 5.00-4.95 sh-8 20.8-21.25 4.27-4.18 sh-15 21.85-22.0 4.07-4.040 100 23.2-23.8 3.834-3.739 0-20 24.9-25.1 3.576-3.548 0-3 26.9-27.15 3.314-3.285 0-15 28.5-28.65 3.132-3.114 sh-16 28.8-29.0 3.100-3.082 0-sh 32.0-32.25 2.797-2.776 sh-24 34.5-34.9 2.600-2.571 3-8 37.7-38.1 2.386-2.362 6-10 Example 54C (a) FeAPSO-44, as prepared in example 32C, was subjected to x-ray analysis. FeAPSO-44 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 7.5 11.80 670 9.5 9.29 94 12.95 6.83 70 14.95 5.92 132 16.15 5.48 30 17.4 5.10 7 19.0 4.67 7 19.8 4.48 326 21.0 4.23 332 21.8 4.07 34 22.45 3.963 631 23.1 3.850 7 24.5 3.635 100 24.7 3.604 40 26.0 3.425 193 27.15 3.283 30 28.05 3.180 19 29.05 3.075 110 30.1 2.966 137 30.9 2.894 40 33.0 2.714 7 33.65 2.664 37 34.6 2.591 105 35.55 2.525 128 37.0 2.430 28 37.65 2.389 82 42.3 2.137 23 42.55 2.125 17 43.7 2.072 15 45.1 2.011 14 47.75 1.904 36 51.6 1.77 17 52.0 1.758 16 55.8 1.647 19 (b) The FeAPSO-44 compositions are generally characterized by the data of Table XX-C below: 2ϑ d, (Å) Relative Intensity 9.5 9.31 m 12.95 6.83 m 16.15 5.49 vw 21.0 4.23 vs 24.5 3.631 m 30.9 2.894 w (c) The FeAPSO-44 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXI-C below: 2ϑ d, (Å) 100 x I/Io* 9.5 9.31 28 12.95 6.83 21 16.15 5.49 9 17.4 5.10 2 19.0 4.67 2 21.0 4.23 100 21.8 4.07 10 23.1 3.850 2 24.5 3.635 30 26.0 3.427 58 28.05 3.180 6 30.1 2.966 11 30.9 2.894 12 33.0 2.714 2 35.55 2.525 39 42.3 2.137 7 42.55 2.125 5 43.7 2.072 5 47.75 1.904 11 Example 55C (a) FeAPSO-46, as prepared in example 38C was subjected to x-ray analysis. FeAPSO-46 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 6.6 13.42 3 7.15 11.38 100 12.45 7.11 2 13.2 6.70 2 13.8 6.41 1 15.0 5.91 1 15.35 5.77 1 16.7 5.31 2 17.3 5.13 <1 19.9 4.47 1 20.6 4.31 3 21.65 4.11 7 22.9 3.885 4 24.3 3.660 3 25.2 3.534 <1 26.95 3.307 3 27.85 3.206 2 28.35 3.147 1 28.85 3.093 3 29.95 2.985 1 30.2 2.959 <1 30.95 2.889 <1 31.35 2.855 2 31.8 2.814 <1 33.05 2.711 1 34.4 2.606 1 36.05 2.490 3 36.7 2.448 <1 39.9 2.259 <1 41.25 2.188 <1 44.2 2.049 1 47.85 1.902 1 50.4 1.811 <1 51.7 1.768 <1 52.5 1.743 <1 (b) A portion of the as-synthesized FeAPSO-46 of part a) was calcined in air at 500°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d, (Å) 100 x I/Io 6.85 12.92 9 8.0 11.04 100 13.6 6.51 4 15.35 5.76 3 16.0 5.55 3 17.15 5.17 3 21.3 4.17 2 22.2 4.006 2 23.45 3.793 2 24.9 3.575 2 27.6 3.232 2 32.0 2.797 2 (c) The FeAPSO-46 compositions are generally characterized by the data of Table XXII-C below. 2ϑ d, (Å) Relative Intensity 6.6-6.8 13.39-13.00 vw 7.8-8.0 11.33-11.05 vs 13.2-13.6 6.71-6.51 vw 21.65-22.2 4.10-4.00 vw 22.9-23.45 3.883-3.793 vw 26.95-27.6 3.308-3.232 vw (d) The FeAPSO-46 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXIII-C below: 2ϑ d, (Å) 100 x I/Io 6.6-6.8 13.39-13.00 3-9 7.8-8.0 11.33-11.05 100 12.45-12.6 7.11-7.03 0-3 13.2-13.6 6.71-6.51 2-4 13.8-14.0 6.41-6.33 1-2 15.0-15.35 5.91-5.76 1-3 15.35-16.0 5.77-5.55 1-3 16.7-17.15 5.31-5.17 2-3 17.3 5.13 0-1 19.9-20.5 4.47-4.43 1-2 20.6-21.3 4.31-4.17 2-3 21.65-22.2 4.10-4.00 2-8 22.9-23.45 3.883-3.793 2-4 24.3-24.9 3.659-3.575 2-3 25.2 3.534 0-1 26.95-27.6 3.308-3.232 2-4 27.85-27.95 3.206-3.190 0-3 28.35-28.55 3.147-3.125 0-2 28.85-29.05 3.093-3.076 0-3 29.95-30.1 2.985-2.968 0-1 30.2 2.959 0-1 30.95 2.889 0-1 31.3-32.0 2.855-2.797 2 31.8-32.05 2.814-2.792 0-1 33.05 2.711 0-1 34.4 2.608 0-1 36.05-36.2 2.490-2.481 0-3 36.7 2.448 0-1 39.9 2.259 0-1 41.25 2.188 0-1 44.2-44.35 2.049-2.043 0-1 47.8-48.0 1.902-1.895 0-1 50.4 1.811 0-1 51.7 1.768 0-1 52.5 1.743 0-1 Example 56C In order to demonstrate the catalytic activity of the FeAPSO compositions, calcined samples of FeAPSO products were tested for the catalytic cracking of n-butane using a bench-scale apparatus. The reactor was a cylindrical quartz tube 254 mm. in length and 10.3 mm I.D. In each test the reactor was loaded with particles of the selected FeAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The samples had been previously calcined in air or nitrogen to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium and n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the FeAPSO compositions. The k A value (cm³/g min) obtained for the FeAPSO compositions are set forth, below, in Table XXIV-C: D. MANGANESE-ALUMINUM-PHOSPHORUS-SILICON-OXIDE MOLECULAR SIEVES. Molecular sieves containing manganese, aluminum, phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the MnAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: a) Alipro: aluminum isopropoxide; b) CATAPAL; Trademark of Condea Corporation for hydrated pseudoboehmite; c) LUDOX-LS: LUDOX-LS is the tradename of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; d) H₃PO₄: 85 weight percent aqueous phosphoric acid; e) MnAc: Manganese acetate, Mn(C₂H₃O₂)₂ · 4H₂O; f) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; g) TBAOH: 40 weight percent aqueous solution of tetrabutylammonium hydroxide; h) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH; i) Pr₃N: tri-n-propylamine (C₃H₇)₃N; j) Quin: Quinuclidine, (C₇H₁₃N); k) MQuin: Methyl Quinuclidine hydroxide, (C₇H₁₃NCH₃OH); l) C-hex: cyclohexylamine; m) TMAOH: tetramethylammonium hydroxide; n) TPAOH: tetrapropylammonium hydroxide; and o) DEEA: 2-diethylaminoethanol. Preparative Procedures The following preparative examples were carried out by forming a starting reaction mixture by adding the H₃PO₄ to one half of the quantity of water. This mixture was mixed and to this mixture the aluminum isopropoxide or CATAPAL was added. This mixture was then blended until a homogeneous mixture was observed. To this mixture the LUDOX LS was added and the resulting mixture blended (about 2 minutes) until a homogeneous mixture was observed. A second mixture was prepared using the manganese acetate and the remainder (about 50%) of the water. The two mixtures were admixed and the resulting mixture blended until a homogeneous mixture was observed. The organic templating agent was then added to the resulting mixture and the resulting mixture blended until a homogeneous mixture was observed, i.e., about 2 to 4 minutes. (The pH of the mixture was measured and adjusted for temperature). The mixture was then placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at a temperature (150°C or 200°C) for a time or placed in lined screw top bottles for digestion at 100°C. All digestions were carried out at the autogeneous pressure. The molar composition for each preparation will be given by the relative moles of the components of the reaction mixture with H₃PO₄ and MnAc are given respectively in terms of P₂O₅ and MnO content of the reaction mixture. The following examples are provided to further illustrate the invention and are not intended to be limiting thereof: Examples 1D to 64D MnAPSO molecular sieves were prepared according to the above identified procedure and the MnAPSO products determined by X-ray analysis. The results of examples 1D to 64D are set forth in Tables I-D to IV-D. Example 65D (a) Samples of the MnAPSO products were calcined in air or nitrogen to remove at least part of the organic templating agent of the product. The example in which a given MnAPSO product was prepared is given in parenthesis. The adsorption capacities of each calcined sample were measured using a standard McBain-Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum (less than 0.04 torr) at 350°C prior to measurement. The McBain-Bakr data for the aforementioned MnAPSO molecular sieves are set forth hereinafter:. (a) MnAPSO-5 (Example 31D): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 8.9 O₂ 3.46 750 -183 10.8 n-butane 4.3 504 23.0 4.4 cyclohexane 6.0 65 23.4 5.4 H₂O 2.65 4.6 23.0 8.1 H₂O 2.65 19.5 23.0 17.1 The above data demonstrate that the pore size of the calcined MnAPSO-5 product is greater than about 6.2Å. (b) MnAPSO-11 (Example 24D): The above data demonstrate that the pore size of the calcined MnAPSO-11 product is greater than about 6.0Å. (c) MnAPSO-20 (Example 46D): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 0.7 O₂ 3.46 744 -183 1.2 H₂O 2.65 4.6 23.3 9.0 H₂O 2.65 19 23.2 13.7 The above data demonstrate that the pore size of the calcined MnAPSO-20 product is greater than about 2.65Å and less than about 3.46Å. (d) MnAPSO-31 (Example 55D): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 105 -183 5.6 O₂ 3.46 741 -183 9.7 Neopentane 6.2 739 23.5 4.6 H₂O 2.65 4.6 23.8 5.8 H₂O 2.65 20 24.0 15.5 The above data demonstrate that the pore size of the calcined MnAPSO-31 product is greater than about 6.2Å. (e) MnAPSO-34 (Example 11D): The above data demonstrate that the pore size of the calcined MnAPSO-34 product is about 4.3Å. (f) MnAPSO-35 (Example 21D): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 103 -183 1.8 O² 3.46 731 -183 2.6 n-hexane 4.3 103 24.4 0.8 H₂O 2.65 4.6 24.4 9.9 H₂O 2.65 18.5 23.9 15.9 The above data demonstrate that the pore size of the calcined MnAPSO-35 product is about 4.3Å. (g) MnAPSO-44 (Example 64D): Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 18.2 O₂ 3.46 744 -183 20.1 n-hexane 4.3 95 23.6 1.3 isobutane 5.0 746 24.1 0.5 H₂O 2.65 4.6 24.8 22.7 H₂O 2.65 19 29.8 27.7 The above data demonstrate that the pore size of the calcined MnAPSO-44 product about 4.3Å. Example 66D Samples of the as-synthesized products of certain examples were subjected to chemical analysis. The example in which a given MnAPSO was prepared is noted in parenthesis. The chemical analysis for these MnAPSOs was as follows: (a) The chemical analysis for MnAPSO-5 (Example 31D) was: Component Weight Percent Al₂O₃ 31.8 P₂O₅ 46.4 MnO 4.1 SiO₂ 3.0 Carbon 5.2 LOI 14.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of; 0.058 MnO: 0.312 Al₂O₃: 0.327 P₂O₅: 0.050 SiO₂; and a formula (anhydrous basis) of: 0.05 R (Mn 0.04 Al 0.45 P 0.47 Si 0.04 )O₂ (b) The chemical analysis of MnAPSO-11 (Example 24D) was: Component Weight Percent Al₂O₃ 32.5 P₂O₅ 46.7 MnO 4.3 SiO₂ 2.1 Carbon 4.1 LOI 14.0 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.061 MnO; 0.319 Al₂O₃; 0.329 P₂O₅; 0.035 SiO₂; and a formula (anhydrous basis) of: 0.06 R (Mn 0.04 Al 0.46 P 0.47 Si 0.03 )O₂ (c) The chemical analysis for MnAPSO-20 (Example 46D) was: Component Weight Percent Al₂O₃ 27.3 P₂O₅ 39.6 MnO 4.6 SiO₂ 8.0 Carbon 8.4 LOI 19.4 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.065 MnO; 0.268 Al₂O₃: 0.279 P₂O₅: 0.133 SiO₂: and a formula (anhydrous basis) of: 0.18 R (Mn 0.05 Al 0.41 P 0.43 Si 0.10 )O₂ (d) The chemical analysis of MnAPSO-31 was: Component Weight Percent Al₂O₃ 31.8 P₂O₅ 43.8 MnO 3.2 SiO₂ 2.6 Carbon 2.9 LOI 16.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.058 MnO; 0.312 Al₂O₃; 0.309 P₂O₅; 0.043 SiO₂; and a formula (anhydrous basis) of: 0.04 R (Mn 0.04 Al 0.47 P 0.46 Si 0.03 )O₂ (e) The chemical analysis of MnAPSO-34 (Example 6D) was: Component Weight Percent Al₂O₃ 25.0 P₂O₅ 35.8 MnO 7.9 SiO₂ 11.6 Carbon 3.3 LOI 19.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.11 MnO 0.25 Al₂O₃; 0.19 P₂O₅; 0.19 SiO₂;and a formula (anhydrous basis) of: 0.04 R (Mn 0.09 Al 0.38 P 0.39 Si 0.15 )O₂ (f) The chemical analysis of MnAPSO-35 (Example 23D) was: Component Weight Percent Al₂O₃ 25.2 P₂O₅ 41.3 MnO 7.1 SiO₂ 4.2 Carbon 12.8 LOI 21.3 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.100 MnO; 0.247 Al₂O₃; 0.291 P₂O₅; 0.07 SiO₂; and a formula (anhydrous basis) of: 0.13 R (Mn 0.08 Al 0.40 P 0.47 Si 0.06 )O₂ (g) The chemical analysis of MnAPSO-36 (Example 59D) was: Component Weight Percent Al₂O₃ 27.7 P₂O₅ 37.2 MnO 4.6 SiO₂ 9.5 Carbon 3.0 LOI 19.6 The above chemical analysis gives an overall product composition in molar oxide ratios anhydrous basis) of: 0.065 MnO; 0.272 Al₂O₃; 0.262 P₂O₅; 0.158 SiO₂; and a formula (anhydrous basis) of: 0.03 R (Mn 0.05 Al 0.42 P 0.41 Si 0.12 )O₂ (h) The chemical analysis of MnAPSO-44 (Example 64D) was: Component Weight Percent Al₂O₃ 25.8 P₂O₅ 36.6 MnO 4.4 SiO₂ 9.7 Carbon 2.5 LOI 23.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.062 MnO; 0.253 Al₂O₃; 0.258 P₂O₅; 0.161 SiO₂;; and a formula (anhydrous basis) of: 0.04 R (Mn 0.05 Al 0.41 P 0.41 Si 0.13 )O₂ (i) The chemical analysis of MnAPSO-47 (Example 49D) was: Component Weight Percent Al₂O₃ 27.6 P₂O₅ 36.2 MnO 5.0 SiO₂ 5.7 Carbon 9.9 LOI 25.1 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.071 MnO; 0.271 Al₂O₃; 0.255 P₂O₅; 0.095 SiO₂; and a formula (anhydrous basis) of: 0.17 R (Mn 0.06 Al 0.44 P 0.42 Si 0.08 )O₂ Example 67D EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction with SEM (scanning electron microscope) was carried out on clear crystals from the products of certain examples, as identified in parenthesis hereinafter. Analysis of crystals having a morphology characteristic of each MnAPSO product gave the following analysis based on relative peak heights: a) MnAPSO-5 (Example 4D): Average of Spot Probes Mn 0.5 Al 8.0 P 9.5 Si 0.7 b) MnAPSO-11 (Example 24D): Average of Spot Probes Mn 1.0 Al 8.0 P 9.5 Si 1.5 c) MnAPSO-20 (Example 46D): Average of Spot Probes Mn 0.8 Al 8.2 P 9.4 Si 1.7 d) MnAPSO-34 (Example 6D): Average of Spot Probes Mn 1.3 Al 7.0 P 9.0 Si 1.5 e) MnAPSO-35 (Example 23D): Average of Spot Probes Mn 1.0 Al 7.0 P 10.0 Si 1.2 f) MnAPSO-36 (Example 59D): Average of Spot Probes Mn 0.8 Al 9.3 P 9.9 Si 1.6 g) MnAPSO-44 (Example 42D): Average of Spot Probes Mn 0.7 Al 9.0 P 10.0 Si 1.7 h) MnAPSO-44 (Example 64D): Average of Spot Probes Mn 1.1 Al 8.7 P 10.0 Si 5.6 i) MnAPSO-47 (Example 49D): Average of Spot Probes Mn 1.0 Al 9.0 P 9.5 Si 1.9 Example 68D (a) The MnAPSO-5, prepared in Example 31D, was subjected to x-ray analysis. The MnAPSO-5 was impure but the major phase was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 6.9 12.81 13 7.5 11.79 100 8.0 11.05 5 9.1 9.72 4 9.3 9.51 4 13.0 6.81 14 13.7 6.46 3 15.0 5.91 27 16.5 5.37 3 18.5 4.80 7 19.8 4.48 43 21.0 4.23 58 22.3 3.99 75 24.7 3.60 6 25.9 3.440 42 29.0 3.079 18 30.0 2.979 34 33.6 2.667 8 34.5 2.600 21 36.9 2.436 4 37.7 2.386 10 41.5 2.176 5 42.1 2.146 5 42.2 2.141 5 42.6 2.122 5 43.5 2.080 3 44.9 2.019 3 47.5 1.914 7 51.4 1.778 5 51.9 1.762 3 55.5 1.656 5 (b) A portion of the as-synthesized MnAPSO-5 of part a) was calcined in air at 500°C for about two (2) hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 7.4 11.95 100 7.8 11.33 4 12.9 6.86 25 15.0 5.91 21 16.5 5.37 3 16.7 5.31 3 17.5 5.07 5 19.8 4.48 40 21.2 4.19 40 22.5 3.95 43 26.0 3.427 30 29.1 3.069 11 30.1 2.969 35 33.7 2.660 5 34.6 2.592 19 37.1 2.423 4 37.9 2.374 6 42.5 2.127 4 43.1 2.099 3 46.0 1.973 3 47.9 1.899 5 55.8 1.647 4 (c) The species denominated herein as MnAPSO-5 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empiracal chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-5 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table V-D as follows: 2ϑ d,(Å) Relative Intensity 7.3 - 7.7 12.11 - 11.48 vs 14.7 - 15.1 6.03 - 5.87 m 19.6 - 19.9 4.53 - 4.46 m 20.8 - 21.3 4.27 - 4.17 m 22.1 - 22.6 4.02 - 3.93 m 29.8 - 30.2 2.998 - 2.959 m (d) All of the MnAPSO-5 compositions, both as-synthesized and calcined, for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table VI-D below: Example 69D (a) MnAPSO-11, as prepared in example 24D, was subjected to x-ray analysis. The MnAPSO-11 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 8.1 10.92 36 9.5 9.31 61 13.1 6.76 19 15.7 5.64 36 16.2 5.47 10 19.1 4.65 13 20.5 4.33 45 21.1 4.21 100 22.2 4.00 55 22.5 3.95 52 22.7 3.92 61 23.2 3.83 71 24.5 3.63 13 24.8 3.59 16 25.0 3.562 13 26.4 3.38 26 28.3 3.153 13 28.6 3.121 23 29.5 3.028 13 31.5 2.84 16 32.8 2.730 23 34.2 2.622 16 35.4 2.54 10 35.8 2.508 10 36.3 2.475 10 37.5 2.398 13 37.8 2.370 16 39.4 2.287 10 42.9 2.108 10 44.8 2.023 10 48.8 1.866 3 50.6 1.804 10 54.6 1.681 10 (b) A portion of the as-synthesized MnAPSO-11 of part a) was calcined in air at 600°C for about two (2) hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 8.1 10.92 33 9.8 9.03 60 11.8 7.50 13 12.8 6.92 27 13.5 6.56 13 14.8 5.99 sh 16.1 5.51 67 19.5 4.55 27 19.9 4.46 40 20.4 4.35 33 21.5 4.13 73 21.8 4.08 100 22.2 4.00 73 22.4 3.97 80 23.5 3.79 73 24.3 3.66 27 25.8 3.453 33 26.7 3.339 27 27.3 3.267 33 27.8 3.209 33 28.5 3.132 27 29.5 3.028 33 29.8 2.998 40 30.4 2.940 27 31.8 2.814 20 32.6 2.747 33 34.0 2.637 20 35.5 2.529 27 37.1 2.423 20 37.4 2.404 20 38.2 2.356 20 38.6 2.332 27 41.0 2.201 20 (c) The species denominated herein as MnAPSO-11 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-11 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table VII-D as follows: 2ϑ d,(Å) Relative Intensity 9.4 - 9.8 9.41 - 9.03 m 16.1 - 16.2 5.50 - 5.47 vw-m 21.0 - 21.5 4.23 - 4.13 m-vs 22.1 - 22.2 4.02 - 4.00 m 22.4 - 22.5 3.97 - 3.95 m-s 23.1 - 23.5 3.85 - 3.79 m (d) All of the MnAPSO-11 compositions, both as-synthesized and calcined, for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table VIII-D below: Example 70D (a) MnAPSO-16, as prepared in example 14D was subjected to x-ray analysis. The MnAPSO-16 was determined to have an x-ray powder diffraction pattern characterized by the following data: (b) A portion of the as-synthesized MnAPSO-16 of part a) was calcined in nitrogen at 600°C for about 2 hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 11.5 7.69 100 13.3 6.66 9 18.6 4.77 25 20.3 4.37 44 20.5 4.33 41 21.5 4.13 66 21.9 4.06 72 22.9 3.88 31 23.5 3.79 13 26.5 3.363 31 27.9 3.198 13 29.0 3.079 19 29.7 3.008 34 32.6 2.747 13 34.7 2.585 13 35.6 2.522 16 37.8 2.380 13 48.2 1.888 9 (c) The species denominated herein as MnAPSO-16 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-16 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table IX-D as follows: 2ϑ d,(Å) Relative Intensity 11.4-11.5 7.76-7.69 m-vs 18.6-18.7 4.77-4.75 m 21.9 4.06 m-vs 22.9-23.0 3.88-3.87 w-m 26.5-26.6 3.363-3.351 m 29.7-29.8 3.008-2.998 m (d) All of the MnAPSO-16 compositions, both as-synthesized and calcined, for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table X-D below: 2ϑ d, (Å) I/Io x 100 11.4-11.5 7.76-7.69 48-100 18.6-18.7 4.77-4.75 25-40 21.9 4.06 72-80 22.9-23.0 3.88-3.87 13-31 26.5-26.6 3.363-3.351 26-31 27.8-27.9 3.209-2.198 5-13 29.0 3.079 15-19 29.7-29.8 3.008-2.998 24-34 32.6 2.747 7-14 34.7 2.585 9-14 37.8 2.380 11-15 39.7 2.270 5-6 44.2 2.049 5-6 48.2-48.5 1.888-1.877 9-12 49.4 1.845 4-5 52.4 1.746 4-5 54.7 1.678 4-5 Example 71D (a) MnAPSO-20, as prepared in example 46D was subjected to x-ray analysis. The MnAPSO-20 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 14.0 6.35 49 19.8 4.49 43 22.1 4.02 3 23.7 3.75 1 24.3 3.67 100 28.1 3.177 13 31.5 2.842 11 34.6 2.595 16 37.5 2.400 2 40.1 2.247 4 42.7 2.118 4 47.4 1.917 4 51.8 1.764 7 (b) A portion of the as-synthesized MnAPSO-20 of part a) was calcined in air at 500°C for about 1 hour. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d,(Å) Relative Intensity 7.1 12.51 2 14.0 6.33 100 19.8 4.48 40 22.2 4.00 4 24.3 3.66 99 28.2 3.168 17 31.6 2.835 15 34.7 2.589 17 40.2 2.243 3 42.7 2.116 4 47.5 1.913 4 (c) The species denominated herein as MnAPSO-20 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-20 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XI-D as follows: 2ϑ d,(Å) Relative Intensity 13.904-13.998 6.3692 -6.3263 m-vs 19.723-19.818 4.5011-4.4918 m 24.223-24.329 3.6742-3.6584 vs 28.039-28.163 3.1822-3.1684 w 31.434-31.560 2.8458-2.8348 w 34.527-34.652 2.5976-2.5866 w (d) All of the MnAPSO-20 compositions, both as-synthesized and calcined for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XII-D below: 2ϑ d,(Å) I/Io x 100 13.904-13.998 6.3692-6.3263 49-100 19.723-19.818 4.5011-4.4918 40-43 22.091-22.200 4.0236-4.0041 3-4 24.223-24.329 3.6742-3.6584 99-100 28.039-28.163 3.1822-3.1684 13-17 31.434-31.560 2.8458-2.8348 11-15 34.527-34.652 2.5976-2.5886 15-17 34.413-27.465 2.2501-2.4004 2 40.071-40.207 2.2501-2.2428 3-4 42.627-42.730 2.1209-2.1160 3-4 47.383-47.519 1.9185-1.9134 3-4 51.790-51.840 1.7652-1.7636 7 Example 72D (a) MnAPSO-31, as prepared in example 54D was subjected to x-ray analysis. MnAPSO-31 was determined to have an x-ray powder diffraction pattern characterized by the followiang data: 2ϑ d, (Å) I/Io x 100 7.9 11.22 4 8.6 10.27 61 17.2 5.17 5 18.5 4.81 4 20.4 4.36 49 21.2 4.19 4 22.0 4.04 30 22.1 4.02 32 22.7 3.92 100 25.3 3.526 5 25.8 3.459 3 28.1 3.181 12 29.8 2.995 6 31.8 2.812 22 35.2 2.548 9 36.2 2.482 3 37.3 2.411 3 37.8 2.382 3 38.3 2.353 3 38.4 2.346 3 39.4 2.285 3 39.8 2.266 3 40.3 2.241 3 46.8 1.942 3 48.8 1.866 2 51.8 1.766 5 55.6 1.654 2 (b) A portion of the as-synthesized MnAPSO-31 of part a) was calcined in air at 500°C for about 1.5 hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 8.6 10.31 58 14.8 5.98 4 17.1 5.18 9 18.5 4.81 4 20.4 4.36 52 22.1 4.03 44 22.7 3.92 100 25.3 3.526 7 25.8 3.460 8 28.1 3.181 15 29.8 2.998 11 31.1 2.879 3 31.8 2.811 33 35.3 2.546 11 36.3 2.477 6 37.3 2.409 3 37.8 2.383 3 38.3 2.348 3 39.4 2.289 4 40.3 2.236 3 45.4 2.000 3 46.8 1.942 5 47.6 1.909 4 48.9 1.864 3 51.7 1.767 6 (c) The species denominated herein as MnAPSO-31 is a molecular sieve having a three dimensional microporous crystalline framework structure o MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-31 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XIII-D as follows: 2ϑ d,(Å) Relative Intensity 8.482 - 9.501 10.4240 - 9.3084 m 20.222 - 20.353 4.3913 - 4.3632 m 21.879 - 21.993 4.0622 - 4.0415 m 22.071 - 22.088 4.0272 - 4.0242 m 22.587 - 22.698 3.9364 - 3.9174 vs 31.724 - 31.836 2.8546 - 2.8108 m (d) All of the MnAPSO-31 compositions, both as-synthesized and calcined for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XIV-D below: Example 73D (a) MnAPSO-34, as prepared in example 11D was subjected to x-ray analysis. MnAPSO-34 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 9.6 9.21 100 12.9 6.86 17 14.2 6.24 15 16.1 5.51 33 18.1 4.90 23 20.6 4.31 69 22.3 3.99 10 23.1 3.85 8 25.2 3.534 25 25.8 3.453 19 27.5 3.243 10 28.4 3.143 10 29.5 3.028 10 30.5 2.931 27 31.2 2.867 23 33.8 2.652 8 34.3 2.614 12 36.3 2.475 8 43.0 2.103 6 43.5 2.080 6 47.5 1.914 6 48.9 1.863 8 50.9 1.794 6 53.0 1.728 6 55.7 1.650 6 (b) A portion of the as-synthesized MnAPSO-34 of part a) was calcined in nitrogen at 425°C for about 2 hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 9.6 9.21 100 13.0 6.86 25 14.1 6.28 5 16.2 5.47 15 17.9 4.96 15 19.1 4.65 5 20.8 4.27 37 22.2 4.00 5 22.4 3.97 5 23.2 3.83 7 25.2 3.534 15 26.0 3.427 12 27.7 3.220 4 28.3 3.153 5 29.7 3.008 4 30.7 2.912 17 31.3 2.849 11 32.4 2.763 3 34.6 2.592 5 36.2 2.481 4 38.8 2.321 3 39.8 2.265 3 43.1 2.099 3 43.6 2.076 3 47.8 1.903 1 49.0 1.859 3 51.0 1.791 3 53.3 1.719 4 54.6 1.681 3 (c) The species denominated herein as MnAPSO-34 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-34 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XV-D as follows: 2ϑ d,(Å) Relative Intensity 9.4 - 9.6 9.41 - 9.21 vs 15.9 - 16.2 5.57 - 5.47 m 20.4 - 20.8 4.35 - 4.27 m-vs 25.0 - 25.3 3.562 - 3.520 w-m 31.0 - 31.3 2.885 - 2.858 w-m 33.6 - 33.9 2.667 - 2.644 m (d) All of the MnAPSO-34 compositions, both as-synthesized and calcined for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XIV-D below: 2ϑ d,(Å) I/Io x 100 9.4 - 9.6 9.41 - 9.21 100 12.7 - 13.0 6.97 - 6.86 17-25 14.0 - 14.2 6.33 - 6.24 5-17 15.9 - 16.2 5.57 - 5.47 15-44 17.9 - 18.1 4.96 - 4.90 15-32 19.1 4.65 5 20.4 - 20.8 4.35 - 4.27 37-92 22.1 - 22.3 4.02 - 3.99 5-16 22.4 3.97 5 22.9 - 23.2 3.88 - 3.83 7-16 25.0 - 25.3 3.562 - 3.520 15-36 25.8 - 26.0 3.453 - 3.427 12-19 27.3 - 27.7 3.267 - 3.220 4-28 28.2 - 28.5 3.164 - 3.132 5-16 29.3 - 29.7 3.048 - 3.008 4-16 30.3 - 30.7 2.950 - 2.912 10-17 31.0 - 31.3 2.885 - 2.849 11-40 32.4 2.763 3 33.6-33.9 2.667-2.644 23-32 34.3-34.6 2.614-2.592 5-12 36.2-36.4 2.481-2.468 4-16 38.8 2.321 3 39.8 2.265 3 43.0-43.1 2.103-2.099 3-12 43.5-43.6 2.080-2.076 3-12 47.4-47.8 1.918-1.903 1-12 48.8-49.0 1.866-1.859 3-12 50.8-51.0 1.797-1.791 3-12 52.9-53.3 1.731-1.719 4-12 54.6 1.681 3 55.6-55.8 1.653-1.647 6-12 Example 74D (a) MnAPSO-35, as prepared in example 22D was subjected to x-ray analysis. MnAPSO-35 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 8.6 10.28 14 10.9 8.12 45 13.4 6.61 23 15.9 5.57 11 17.4 5.10 80 17.8 4.98 16 20.9 4.25 57 21.9 4.06 100 23.2 3.83 34 24.8 3.59 9 25.7 3.466 7 26.9 3.314 21 28.3 3.153 50 29.1 3.069 11 31.4 2.849 9 32.1 2.788 41 34.3 2.614 14 34.9 2.571 7 35.3 2.543 5 35.8 2.508 7 37.7 2.386 5 39.5 2.281 5 41.9 2.156 7 42.7 2.118 7 44.6 2.032 5 47.6 1.910 7 48.3 1.884 7 49.5 1.841 7 51.0 1.791 9 55.0 1.670 5 55.4 1.658 7 (b) A portion of the as-synthesized MnAPSO-35 of part a) was calcined in nitrogen at 500°C for about 2 hours. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 8.6 10.28 27 10.9 8.12 96 11.4 7.76 14 13.4 6.61 41 15.8 5.61 14 17.3 5.13 68 17.7 5.01 sh 20.8 4.27 64 21.9 4.06 100 23.3 3.82 32 24.8 3.59 23 25.7 3.466 18 26.9 3.314 27 28.3 3.153 59 29.1 3.069 23 31.4 2.849 18 32.2 2.780 46 34.2 2.622 18 34.8 2.578 14 35.8 2.508 9 41.9 2.156 9 42.5 2.127 9 44.6 2.032 9 47.4 1.918 9 48.2 1.888 9 49.4 1.845 9 51.0 1.791 14 55.2 1.664 9 55.7 1.650 9 (c) The species denominated herein as MnAPSO-35 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-35 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XVII-D as follows: 2ϑ d,(Å) Relative Intensity 10.8 - 11.0 8.19 - 8.04 m-vs 13.4 - 13.7 6.61 - 6.46 m-s 17.2 - 17.5 5.16 - 5.07 m-s 20.8 - 21.0 4.27 - 4.23 m 21.8 - 22.3 4.08 - 3.99 m-vs 28.2 - 28.7 3.164 - 3.110 m (d) All of the MnAPSO-35 compositions, both as-synthesized and calcined, for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XVIII-D below: Example 75D (a) MnAPSO-36, as prepared in example 59D was subjected to x-ray analysis. The MnAPSO-36 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 7.4 11.88 15 7.9 11.22 100 8.2 10.82 33 13.5 6.55 5 15.8 5.61 10 16.4 5.41 31 19.1 4.66 14 20.7 4.28 34 21.2 4.19 4 21.7 4.10 16 22.0 4.04 14 22.5 3.96 15 23.0 3.87 5 23.9 3.73 6 27.2 3.276 15 27.9 3.193 3 28.3 3.153 8 29.0 3.079 7 30.2 2.958 4 30.3 2.951 4 32.0 2.798 8 34.8 2.579 7 (b) A portion of the as-synthesized MnAPSO-36 of part a) was calcined in air at 500°C for about 1 hour. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 7.1 12.39 5 7.6 11.64 21 8.0 11.11 100 8.3 10.65 37 13.6 6.53 17 16.6 5.35 31 19.4 4.57 17 20.8 4.27 19 21.9 4.06 8 22.4 3.97 15 22.7 3.92 11 23.4 3.80 5 23.9 3.73 7 27.3 3.271 16 28.3 3.159 6 28.4 3.141 6 29.1 3.074 7 29.4 3.043 5 32.0 2.798 6 (c) The species denominated herein as MnAPSO-36 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , Al - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3: and "w", "x", "y" and "z" represent the mole fractions of manganese. aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-36 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XIX-D as follows: 2ϑ d,(Å) Relative Intensity 7.596 11.6382 m 7.628 - 7.981 11.5899 - 11.0771 vs 8.105 - 8.299 10.9084 - 10.6537 m 16.395 - 16.673 5.4066 - 5.3172 m 19.052 - 19.414 4.6580 - 4.5721 w 20.744 - 20.871 4.2819 - 4.2560 m (d) All of the MnAPSO-36 compositions, both as-synthesized and calcined for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XX-D below: Example 76D (a) MnAPSO-44, as prepared in example 64D was subjected to x-ray analysis. The MnAPSO-44 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 9.4 9.39 100 13.0 6.83 20 13.7 6.45 4 16.1 5.52 43 17.3 5.12 5 19.0 4.68 7 20.7 4.29 84 21.7 4.09 21 22.6 3.94 8 23.1 3.86 9 24.4 3.65 58 26.1 3.409 22 27.8 3.205 10 29.7 3.012 5 30.1 2.969 16 30.8 2.900 50 32.5 2.753 4 32.9 2.721 6 34.8 2.577 3 35.5 2.528 9 38.5 2.336 2 39.2 2.299 2 40.0 2.255 2 42.2 2.143 3 42.5 2.125 3 43.6 2.076 2 47.3 1.922 2 48.2 1.890 7 48.7 1.870 4 50.3 1.814 7 53.9 1.701 6 (b) A portion of the as-synthesized MnAPSO-44 of part a) was calcined in air at 500°C for about one (1) hour. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 9.6 9.21 100 13.1 6.79 26 14.2 6.26 3 16.2 5.46 12 18.0 4.93 18 19.3 4.60 3 20.9 4.25 28 22.3 3.99 3 23.4 3.80 3 25.3 3.526 13 26.3 3.387 9 28.5 3.137 3 28.6 3.123 4 29.9 2.990 2 30.0 2.976 2 30.6 2.921 3 31.1 2.875 7 31.8 2.811 2 32.1 2.791 2 35.1 2.560 3 (c) The species denominated herein as MnAPSO-44 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3: and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compositional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-44 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXI-D as follows: 2ϑ d,(Å) Relative Intensity 9.420 - 9.498 9.3883 - 9.3110 vs 16.062 - 16.131 5.5179 - 5.4944 m 20.715 - 20.790 4.2877 - 4.2725 s 24.396 - 24.424 3.6485 - 3.6444 m 26.143 - 26.184 3.4085 - 3.4032 m 30.833 - 30.853 2.8999 - 2.8981 m (d) All of the MnAPSO-44 compositions, both as-synthesized and calcined, for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XXII-D below: 2ϑ d, (Å) I/Io x 100 9.420-9.498 9.3883-9.3110 100 12.930-12.958 6.8468-6.8318 20 13.738 6.4458 4 16.062-16.131 5.5179-5.4944 43 17.329-17.396 5.1173-5.0975 5 18.950-18.998 4.6828-4.6713 7 20.715-20.790 4.2877-4.2725 84 21.709-21.743 4.0937-4.0873 21 22.366-22.583 3.9748-3.9372 8 23.061-23.101 3.8566-3.8501 9 24.396-24.424 3.6485-3.6444 58 26.143-26.184 3.4085-3.4032 22 27.837-27.881 3.2049-3.1999 10 29.661 3.0117 5 30.002-30.096 2.9783-2.9692 16 30.833-20.853 2.8999-2.8981 50 32.520-32.562 2.7532-2.7498 4 32.900-32.918 2.7223-2.7208 6 34.812 2.5770 3 35.516-35.534 2.5275-2.5263 9 38.536 2.3361 2 38.185 2.2989 2 39.991 2.2545 2 42.162-42.177 2.1432-2.1425 3 42.533-42.541 2.1254-2.1250 3 43.607-73.621 2.0755-2.0749 2 47.283 1.9224 2 48.157-48.177 1.8895-1.8888 7 48.640-48.697 1.8719-1.8698 4 50.303-50.307 1.8138-1.8137 7 53.885-53.887 1.7014-1.7013 6 Example 77D (a) MnAPSO-47, as prepared in example 49D was subjected to x-ray analysis. The MnAPSO-47 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d, (Å) I/Io x 100 4.8 18.44 1 9.4 9.38 100 12.9 6.89 5 13.9 6.40 3 16.0 5.56 9 17.5 5.06 4 18.9 4.69 3 20.5 4.32 30 21.8 4.08 4 22.4 3.98 1 22.9 3.88 3 24.6 3.61 11 25.9 3.445 7 27.6 3.234 2 27.9 3.199 1 29.5 3.033 2 30.5 2.930 10 30.8 2.901 7 31.5 2.845 1 33.2 2.700 1 34.4 2.604 2 34.8 2.576 1 35.7 2.516 2 38.4 2.343 1 39.2 2.297 1 39.6 2.277 1 42.4 2.132 1 43.3 2.091 1 47.6 1.911 1 48.6 1.874 5 50.3 1.813 2 53.2 1.722 1 54.0 1.698 1 (b) A portion of the as-synthesized MnAPSO-47 of part (a) was calcined in air at 500°C for about one (1) hour. The calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d, (Å) I/Io x 100 5.0 17.80 1 9.7 9.12 100 10.0 8.85 1 13.1 6.75 5 14.2 6.23 1 16.3 5.45 2 18.0 4.92 2 19.4 4.58 3 20.9 4.24 7 22.4 3.98 1 23.4 3.80 1 25.3 3.521 2 26.3 3.385 2 28.1 3.176 1 28.6 3.125 1 30.0 2.977 1 31.1 2.876 3 31.5 2.837 2 33.9 2.645 1 35.0 2.562 1 49.6 1.838 1 (c) The species denominated herein as MnAPSO-47 is a molecular sieve having a three dimensional microporous crystalline framework structure of MnO -2 / 2 , AlO - / 2, PO + / 2 and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Mn w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn w Al x P y Si z )O₂ and has a value of zero to about 0.3; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon respectively, present as tetrahedral oxide, said mole fractions being within the pentagonal compostional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compostional area defined by points a, b, c and d of FIG. 2, said MnAPSO-47 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXIII-D as follows: 2ϑ d,(Å) Relative Intensity 9.434 - 9.696 9.3746 - 9.1214 vs 15.946 - 16.276 5.5579 - 5.4457 vw 20.539 - 20.940 4.3242 - 4.2423 vw - m 24.643 3.6125 w 30.511 2.9297 w 30.820 - 31.096 2.9011 - 2.8759 vw (d) All of the MnAPSO-47 compositions, both as-synthesized and calcined for which x-ray power diffraction data have presently been obtain have patterns which are within the generalized pattern of Table XXIV-D below: Example 78D The catalytic activity of MnAPSO compositions, calcined samples of the MnAPSO products of Examples 11D, 21D, 25D, 31D, 49D, 55D, 59D and 64D were tested for catalytic cracking. The catalytic activity was determined using a reactor comprising a cylindrical quartz tube 254 mm. in length and 10.3 mm. I.D. In each test MnAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. Most of the MnAPSO samples had been previously calcined in air or nitrogen to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium- n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the MnAPSO compositions. The k A value (cm³/g min) obtained for the MnAPSO compositions are set forth, below, in Table XXV-D: MnAPSO Prepared in Example No.: Rate Constant (k A ) MnAPSO-5 31D 0.2 MnAPSO-11 25D 0.6 MnAPSO-20 46D 0.2 MnAPSO-31 55D 1.0; 0.5 MnAPSO-34 11D 3.1 MnAPSO-35 21D 0.1 MnAPSO-36 59D 0.3 MnAPSO-44 64D 1.5 MnAPSO-47 49D 1.7 E. TITANIUM-ALUMINUM-PHOSPHORUS-SILICON-OXIDE SIEVES Molecular sieves containing titanium, aluminum, phosphorus and silicon as framework tetrahedral oxides are prepared as follows: Preparative Reagents In the following examples the TiAPSO compositions were prepared using numerous regents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: a) Alipro: aluminum isopropoxide; b) LUDOX-LS: LUDOX-LS is the tradename of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; c) H₃PO₄: 85 weight percent aqueous phosphoric acid; d) Tiipro: titanium isopropoxide; e) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; f) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH. (g) Pr₃NH: tri-n-propylamine. (C₃H₇)₃N; (h) Quin: Quinuclidine. (C₇H₁₃N); (i) MQuin: Methyl Quinuclidine hydroxide, (C₇H₁₃NCH₃OH); and (j) C-hex: cyclohexylamine. Preparative Procedures The following preparative examples were carried out by forming a starting reaction mixture by adding the H₃PO₄ and the water. This mixture was mixed and to this mixture the aluminum isoproxide was added. This mixture was then blended until a homogeneous mixture was observed. To this mixture the LUDOX-LS was added and the resulting mixture blended (about 2 minutes) until a homogeneous mixture was observed. The titanium isopropoxide was added to the above mixture and the resulting mixture blended until a homogeneous mixture was observed. The organic templating agent was then added to the resulting mixture and the resulting mixture blended until a homogeneous mixture was observed, i.e., about 2 to 4 minutes. When the organic templating agent was quinuclidine the procedure was modified such that the quinuclidine was dissolved in about one half the water and accordingly the H₃PO₄ was mixed with about one half the water. (The pH of the mixture was measured and adjusted for temperature). The mixture was than placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at a temperature (150°C or 200°C) for a time or placed in lined screw top bottles for digestion at 100°C. All digestions were carried out at the autogeneous pressure. The molar composition for each preparation will be given by the relative moles of the components of the reaction mixture. H₃PO₄ and titanium isopropoxide are given respectively in terms of the P₂O₅ and TiO₂ content of the reaction mixture. All digestions were carried out at the autogeneous pressure. The products were removed from the reaction vessel cooled and evaluated as set forth hereinafter. Examples 1E to 30E TiAPSO molecular sieves were prepared according to the above described preparative procedure and the TiAPSO products determined by x-ray analysis. The results of examples 1E to 30E are set forth in Tables I-E and II-E. Example 31E Samples of the products of examples 4E, 6E, 15E, 24E and 30E were subjected to chemical analysis. The chemical analysis for each product is given hereinafter with the example in which the TiAPSO was prepared being given in parenthesis after the designation of the TiAPSO species. (a) The chemical analysis for TiAPSO-16 (Example 4E) was: Component Weight Percent Al₂O₃ 27.1 P₂O₅ 36.1 TiO₂ 6.8 SiO₂ 6.7 Carbon 12.0 Nitrogen 1.9 LOI 22.9 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.085 TiO₂ : 0.266 Al₂O₃ : 0.254 P₂O₅: 0.112 SiO₂; and a formula (anhydrous basis) of: 0.14R(Ti 0.07 Al 0.43 P 0.41 Si 0.09 )O₂ (b) The chemical analysis for TiAPSO-35 (Example 30E) was: Component Weight Percent Al₂O₃ 23.4 P₂O₅ 28.3 TiO₂ 17.6 SiO₂ 4.37 Carbon 11.3 Nitrogen 1.6 LOI 26.3 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.220 TiO₂ : 0.230 Al₂O₃ : 0.199 P₂O₅ : 0.073 SiO₂; and a formula (anhydrous basis) of: 0.12 R(Ti 0.19 Al 0.40 P 0.35 Si 0.06 )O₂ (c) The chemical analysis for TiAPSO-5 (Example 6E) was: Component Weight Percent Al₂O₃ 34.0 P₂O₅ 46.9 TiO₂ 3.0 SiO₂ 1.2 Carbon 5.8 Nitrogen 0.74 LOI 14.4 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.038 TiO₂ : 0.334 Al₂O₃ : 0.330 P₂O₅ : 0.020 SiO₂; and a formula (anhydrous basis) of: 0.054R(Ti 0.03 Al 0.48 P 0.48 Si 0.01 )O₂ (d) The chemical analysis of TiAPSO-11 (Example 15E) was: Component Weight Percent Al₂O₃ 35.8 P₂O₅ 49.0 TiO₂ 1.08 SiO₂ 3.3 Carbon 5.0 Nitrogen 1.0 LOI 10.5 The above chemical analysis gives an overall product composition in solar oxide ratios (anhydrous basis) of: 0.014 TiO₂ : 0.351 Al₂O₃ : 0.345 P₂O₅ : 0.055 SiO₂; and a formula (anhydrous basis) of: 0.07R(Ti 0.01 Al 0.48 P 0.47 Si 0.04 )O₂ (e) The chemical analysis for TiAPSO-34 (example 24E) was: Component Weight Percent Al₂O₃ 32.3 P₂O₅ 37.9 TiO₂ 0.4 SiO₂ 8.2 Carbon 9.8 Nitrogen 1.6 LOI 20.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.01 TiO₂ : 0.32 Al₂O₃ : 0.27 P₂O₅ : 0.14 SiO₂; and a formula (anhydrous basis) of: 0.103R(Ti 0.01 Al 0.48 P 0.41 Si 0.11 )O₂ Example 32E EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction with SEM (scanning electron microscope was carried out on clear crystals from the products of example 4E, 11E, 12E, and 21E. Analysis of crystals having a morphology characteristic of TiAPSO compositions gave the following analysis based on relative peak heights: a) TiAPSO-44/35 (Example 11E): Average of Spot Probes Ti 0.02 Al 0.97 P 0.94 Si 0.25 b) TiAPSO-16 (Example 4E): Average of Spot Probes Ti 0.38 Al 0.79 P 0.84 Si 0.33 c) TiAPSO-34/5 (Example 21E): Average of Spot Probes Ti 0.005 Al 0.85 P 1.00 Si 0.08 d) TiAPSO-11 (Example 12E): Average of Spot Probes Ti 0.12 Al 0.88 P 0.84 Si 0.07 Example 33E Samples of the TiAPSO products of examples 4E, 13E, and 6E were evaluated for adsorption capacities in the calcined form by calcination in air to remove at least part of the organic templating agent, as hereinafter set forth. The adsorption capacities of each calcined sample were measured using a standard McBain - Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum at 350°C prior to measurement. The McBain-Bakr data for the aforementioned calcined TiAPSO products were: a) TiAPSO-16 (Example 4E) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 102 -183 3.3 O₂ 3.46 744 -183 12.8 n-hexane 4.3 95 23.6 7.0 H₂O 2.65 4.6 23.3 13.4 H₂O 2.65 19 23.2 25.4 The above data demonstrate that the pore size of the calcined product is about 4.3 Å. b) TiAPSO-11 (Example 13E) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 101 -183 9.3 O₂ 3.46 736 -183 10.3 neopentane 5.0 742 23.0 1.1 cyclohexane 6.0 67 22.9 5.2 H₂O 2.65 4.6 22.4 12.4 H₂O 2.65 19 22.5 23.4 The above data demonstrate that the pore size of the calcined product is about 6.0 Å. c) TiAPSO-5 (Example 6E) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 101 -183 13.0 O₂ 3.46 736 -183 14.5 neopentane 6.2 742 23.0 4.9 cyclohexane 6.0 67 22.9 7.1 H₂O 2.65 4.6 22.4 14.7 H₂O 2.65 19 22.5 23.4 The above data demonstrate that the pore size of the calcined product is greater than 6.2 Å. Example 34E (a) TiAPSO-5 compositions, as referred to herein in both the as-synthesized and calcined forms, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table III below: 2ϑ d, (Å) Relative Intensity 7.3-7.5 12.11-11.79 s-vs 19.7-19.9 4.51-4.46 m 20.9-21.0 4.25-4.23 m-s 22.3-22.5 3.99-3.95 m-vs 25.8-26.1 3.453-3.411 m 28.9-29.1 3.089-3.069 w-m (b) TiAPSO-5 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are X-ray powder diffraction patterns characterized by Table IV-E below. 2ϑ d,(Å) 100 x I/Io 7.3-7.5 12.11-11.79 94-100 12.9-13.0 6.86-6.81 19-22 14.9-15.0 5.95-5.91 9-21 19.7-19.9 4.51-4.46 26-50 20.9-21.0 4.25-4.23 43-82 22.3-22.5 3.99-3.95 60-100 24.6-24.8 3.62-3.59 7-9 25.8-26.1 3.453-3.414 25-40 28.9-29.1 3.089-3.069 17-27 30.0-30.2 2.979-2.959 18-25 33.5-33.7 2.675-2.660 6-9 34.5-34.7 2.600-2.585 17-19 36.8-37.1 2.442-2.423 6 37.5-37.8 2.398-2.380 10-13 41.4-41.5 2.181-2.176 5-6 41.7-42.0 2.166-2.151 3-4 42.5-42.9 2.127-2.108 3-6 43.6-43.7 2.076-2.071 3-4 44.9-45.0 2.019-2.014 3-4 47.4-47.6 1.918-1.910 5-7 47.8-47.9 1.903-1.900 6-7 51.4-51.5 1.778-1.774 4-5 51.8-51.9 1.765-1.762 3-4 55.6 1.653 6 (c) A portion of the as-synthesized TiAPSO-5 of Example 6E was subjected to X-ray analysis. The TiAPSO-5 product was characterized by the x-ray powder diffraction pattern of Table V-E, below: (d) The TiAPSO-5 compositions of Example 6E was calcined at 600°C in air for 2.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern shown in Table VI-E, below: Example 35-E (a) TiAPSO-11, as referred to herein in both the as-synthesized and calcined forms, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table VII-E below: 2ϑ d,(Å) Relative Intensity 9.4-9.6 9.41-9.21 vw-m 19.9-20.5 4.46-4.33 m 21.0-21.8 4.23-4.08 vs 22.0-22.1 4.04-4.02 m-vs 22.4-22.6 3.97-3.93 m-s 22.7 3.92 m 23.1-23.4 3.85-3.80 m-vs (b) The TiAPSO-11 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern of Table VIII-E below: 2ϑ d,(Å) 100 x I/Io 8.0-8.1 11.05-10.92 23-59 9.4-9.6 9.41-9.21 sh-73 9.8 9.03 51 12.8-13.2 6.92-6.71 26-27 13.5-13.7 6.56-6.46 9-11 14.7-15.0 6.03-5.91 9-18 15.6-16.1 5.68-5.51 32-63 16.2-16.3 5.47-5.44 7-18 19.0-19.5 4.67-4.55 20-23 19.9-20.5 4.46-4.33 31-68 21.0-21.8 4.23-4.08 100 22.0-22.1 4.04-4.02 57-100 22.4-22.6 3.97-3.93 54-82 22.7 3.92 73 23.1-23.4 3.85-3.80 63-91 23.9-24.4 3.72-3.65 23 24.7 3.60 27 26.5-26.6 3.363-3.351 17-36 27.2-27.3 3.278-3.267 16-20 27.6-27.7 3.232-3.220 20-23 27.8-27.9 3.209-3.200 20-21 28.5-28.6 3.132-3.121 14-27 28.7 3.110 11-32 29.0-29.5 3.079-3.028 27-31 29.6-29.7 3.018-3.008 23-34 30.3-30.4 2.950-2.940 20-22 31.4-31.6 2.849-2.831 14-23 32.5-32.9 2.755-2.722 26-32 33.9-34.2 2.644-2.622 11-23 35.5-35.6 2.529-2.522 17-19 36.5 2.462 18 37.2-37.5 2.417-2.398 14-23 38.7-39.4 2.327-2.287 14-17 41.0 2.201 11 42.8 2.113 14 43.6 2.076 9 44.5-44.6 2.036-2.032 9-14 45.0 2.014 14 48.7-49.2 1.870-18.52 14 49.4 1.845 11 49.6 1.838 11 50.6 1.804 7-18 53.4 1.716 11 53.6 1.707 9 54.6-54.7 1.681-1.678 9-14 55.4-55.8 1.658-1.647 11-14 (c) A portion of the as-synthesized TiAPSO-11 of Example 13E was subjected to x-ray analysis. The TiAPSO-11 product was characterized by the x-ray powder diffraction pattern of Table IX-E, below: 2ϑ d,(Å) 100 x I/Io 8.1 10.92 59 9.4 9.41 73 13.2 6.71 27 15.0 5.91 18 15.7 5.64 50 16.3 5.44 18 19.0 4.67 23 20.5 4.33 68 21.0 4.23 100 22.1 4.02 73 22.6 3.93 82 22.7 3.92 73 23.2 3.83 91 24.4 3.65 23 24.7 3.60 27 26.5 3.363 36 28.5 3.132 27 28.7 3.110 32 29.0 3.079 27 29.5 3.028 23 31.4 2.849 23 32.9 2.722 32 34.2 2.622 23 36.5 2.462 18 37.5 2.398 23 39.4 2.287 14 42.8 2.113 14 44.6 2.032 14 45.0 2.014 14 48.7 1.870 14 50.6 1.804 18 54.7 1.678 14 55.4 1.658 14 (d) The TiAPSO-11 composition of Example 13E was calcined at 500°C in air for 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern shown in Table X-E, below: 2ϑ d,(Å) 100 x I/Io 8.1 10.92 23 9.6 9.21 sh 9.8 9.03 51 12.8 6.92 26 13.5 6.56 11 13.7 6.46 9 14.7 6.03 9 16.1 5.51 63 19.5 4.55 20 19.9 4.46 31 21.8 4.08 100 22.1 4.02 57 22.4 3.97 54 23.4 3.80 63 23.9 3.72 23 24.2 3.68 17 26.6 3.351 17 27.2 3.278 20 27.6 3.232 23 27.8 3.209 20 28.5 3.132 14 28.7 3.110 11 29.5 3.028 31 29.7 3.008 34 30.3 2.950 20 31.6 2.831 14 32.5 2.755 26 33.9 2.644 11 35.5 2.529 17 37.2 2.417 14 38.7 2.327 17 41.0 2.201 11 43.6 2.076 9 44.5 2.036 9 49.2 1.852 14 49.4 1.845 11 49.6 1.838 11 53.4 1.716 9 53.6 1.707 9 55.8 1.647 11 Example 36E (a) TiAPSO-16, as referred to herein in both the as-synthesized and calcined form, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XI-E below: 2ϑ d,(Å) Relative Intensity 11.4 7.75 m-vs 18.7 4.75 m 21.9-22.1 4.05-4.02 m-vs 26.4-26.5 3.370-3.363 m 29.6-29.8 3.018-3.002 m 29.9 2.984 m 30.1 2.971 m (b) The TiAPSO-16 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the X-ray powder diffraction pattern of Table XII-E below: 2ϑ d,(Å) 100 x I/Io 10.5 8.41 5 11.4 7.75 72-100 18.7 4.75 25-59 21.1 4.21 3 21.9-22.1 4.05-4.02 56-100 22.8-22.9 3.90-3.89 10-15 23.3 3.818 3 25.0 3.561 6 25.4-25.5 3.506-3.489 13-17 26.4-26.5 3.370-3.363 20-23 26.6 3.346 16 26.9-27.1 3.314-3.290 4-15 28.9-29.1 3.088-3.073 12-13 29.6-29.8 3.018-3.002 22-27 29.9 2.984 24 30.1 2.971 23 32.5-32.7 2.755-2.739 3-4 34.4-34.8 2.607-2.581 3-5 37.3-37.6 2.411-2.394 4-5 37.8-37.9 2.380-2.373 8-14 38.2-38.4 2.356-2.343 5 39.5 2.282 3-4 39.7-39.8 2.270-2.265 3-5 40.1 2.247 7 40.5 2.227 4 44.4 2.040 3 47.8-47.9 1.904-1.899 5 48.0-48.1 1.897-1.893 6-8 48.2-48.3 1.887-1.885 7-8 48.4-48.5 1.881-1.876 7-8 48.8 1.865 5-6 49.0 1.858 5 49.2 1.853 4 54.2 1.692 3 54.3 1.689 3 (c) A portion of the as-synthesized TiAPSO-16 of example 4E was subjected to x-ray analysis. The TiAPSO-16 product was characterized by the x-ray powder diffraction pattern of Table XIII-E, below: 2ϑ d, (Å) 100 X I/Io 11.4 7.75 72 18.7 4.74 59 22.1 4.02 100 22.9 3.89 11 25.3 3.521 15 26.4 3.376 13 26.6 3.346 16 26.9 3.314 15 29.1 3.073 13 29.8 3.002 22 29.9 2.984 24 30.1 2.971 23 34.8 2.581 3 37.6 2.395 5 37.9 2.371 14 38.4 2.343 5 39.5 2.282 4 39.7 2.270 5 40.1 2.247 7 40.5 2.227 4 47.8 1.904 5 48.1 1.893 8 48.2 1.887 8 48.5 1.876 8 48.8 1.865 6 49.0 1.858 5 49.2 1.853 4 (d) The TiAPSO-16 composition of part (c) was calcined at 500°C in air for 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern shown in Table XIV-E, below: 2ϑ d,(Å) 100 x I/Io 10.5 8.41 5 11.4 7.75 100 18.7 4.75 25 21.1 4.27 3 21.9 4.05 56 22.8 3.90 10 25.0 3.561 6 25.4 3.506 14 25.5 3.489 13 26.4 3.370 20 28.9 3.088 12 29.7 3.007 27 34.6 2.594 5 37.6 2.391 5 37.9 2.373 9 38.2 2.356 5 48.0 1.897 6 48.3 1.885 7 Example 37E (a) TiAPSO-34, as referred to herein in both the as-synthesized and calcined forms, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XV-E below: 2ϑ d,(Å) Relative Intensity 9.4-9.5 9.41-9.31 vs 12.9-13.0 6.86-6.81 w-m 16.0-16.2 5.54-5.47 w-m 20.5-20.8 4.33-4.27 m-vs 30.5-30.9 2.931-2.894 m 31.5-31.6 2.840-2.831 vw-m (b) The TiAPSO-34 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern of Table XVI-E below: 2ϑ d,(Å) 100 x I/Io 9.4-9.5 9.41-9.31 100 12.9-13.0 6.86-6.81 16-31 14.0-14.1 6.33-6.28 7-16 16.0-16.2 5.54-5.47 19-50 17.8-17.9 4.98-4.96 16-23 19.2 4.62 10 20.5-20.8 4.33-4.27 38-97 22.1-22.2 4.02-4.00 8-9 23.1-23.3 3.85-3.82 8-14 25.0-25.1 3.562-3.548 17-27 25.8-26.2 3.453-3.401 19-21 27.5-27.9 3.243-3.198 7-10 28.2-28.3 3.164-3.153 7-12 29.5-29.8 3.028-2.998 8-12 30.5-30.9 2.931-2.894 31-39 31.1-31.3 2.876-2.858 Sh-29 31.5-31.6 2.840-2.831 8-32 32.3-32.4 2.772-2.763 6-7 33.2 2.698 5 33.8 2.652 5 34.4-34.9 2.607-2.571 8-9 35.0 2.564 3 36.1-36.2 2.488-2.481 6-7 38.8 2.321 3 39.6-39.8 2.276-2.265 5-7 40.2 2.243 5 43.0 2.103 5 43.4 2.085 7 47.5 1.914 5 48.9-49.2 1.863-1.852 5-8 49.8 1.831 5 50.9-51.0 1.794-1.791 7-8 51.5-51.6 1.774-1.771 3-5 53.1-53.2 1.725-1.722 7-8 54.4-54.5 1.687-1.684 5-6 55.8-55.9 1.647-1.645 6-7 (c) A portion of the as-synthesized TiAPSO-34 of example 24E was subjected to x-ray analysis. The TiAPSO-34 product was characterized by the x-ray powder diffraction pattern of Table XVII-E below: 2ϑ d,(Å) 100 x I/Io 9.4 9.41 100 12.9 6.86 16 14.0 6.33 16 16.0 5.54 50 17.9 4.96 23 20.5 4.33 97 22.1 4.02 8 23.1 3.85 8 25.1 3.548 27 25.8 3.453 21 27.5 3.243 7 28.3 3.153 7 29.5 3.028 8 30.5 2.931 39 31.1 2.876 29 31.6 2.831 8 32.4 2.763 7 33.2 2.698 5 33.8 2.652 5 34.4 2.607 8 35.0 2.564 3 36.2 2.481 7 38.8 2.321 3 39.6 2.276 7 43.0 2.103 5 43.4 2.085 7 47.5 1.914 5 48.9 1.863 8 49.8 1.831 5 50.9 1.794 7 51.6 1.771 3 53.1 1.725 7 54.4 1.687 5 55.8 1.647 7 (d) The TiAPSO-34 compositions of example 24E was calcined at 500°C in air for 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern shown in Table XVIII-E, below: 2ϑ d,(Å) 100 x I/Io 9.5 9.31 100 13.0 6.81 31 14.1 6.28 7 16.2 5.47 19 17.9 4.96 16 19.2 4.62 10 20.8 4.27 38 22.2 4.00 9 23.3 3.82 14 25.0 3.562 17 26.2 3.401 19 27.9 3.198 10 28.2 3.164 12 29.8 2.998 12 30.9 2.894 31 31.3 2.858 sh 32.4 2.763 9 34.9 2.571 9 36.2 2.481 7 39.8 2.265 5 40.2 2.243 5 49.2 1.852 5 51.0 1.791 7 Example 38E (a) TiAPSO-35, as referred to herein in both the as-synthesized and calcined forms, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XIX-E below: 2ϑ d,(Å) Relative Intensity 10.9-11.1 8.12-7.97 m 13.3-13.7 6.66-6.46 m 17.3-17.4 5.13-5.10 w-m 20.8-21.1 4.27-4.21 m 21.9-22.2 4.06-4.00 m-vs 28.3-28.7 3.153-3.110 m (b) The TiAPSO-35 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern of Table XX-E below: 2ϑ d,(Å) 100 x I/Io 8.6-8.8 10.28-10.05 13-14 10.9-11.1 8.12-7.97 36-74 13.3-13.7 6.66-6.46 20-39 15.9-16.1 5.57-5.51 11-15 17.3-17.4 5.13-5.10 17-75 17.6-17.7 5.04-5.01 13-17 20.8-21.1 4.27-4.21 25-49 21.9-22.2 4.06-4.00 65-100 23.2-23.7 3.83-3.75 22-32 24.9-25.2 3.58-3.534 19-30 26.6-26.9 3.363-3.314 19-35 28.3-28.7 3.153-3.110 30-48 29.1-29.2 3.069-3.058 11-15 29.6-29.7 3.018-3.008 6-39 31.5-31.7 2.840-2.823 9-11 32.1-32.7 2.788-2.739 30-41 34.3-34.6 2.614-2.592 11-17 35.0-35.1 2.564-2.557 4-5 35.8-35.9 2.508-2.501 5-6 37.8-38.0 2.380-2.368 9-13 39.5 2.281 4-5 40.9 2.206 3-4 41.9 2.156 6 42.1-42.6 2.146-2.122 5-6 42.7 2.118 4-6 48.4-48.5 1.881-1.877 9-13 49.0 1.859 5-6 50.1 1.821 10-11 55.0-55.1 1.670-1.667 9-13 55.4-55.5 1.658-1.656 9-10 (c) A portion of the as-synthesized TiAPSO-35 of example 30E was subjected to x-ray analysis. The TiAPSO-35 product was characterized by the x-ray powder diffraction pattern of Table XXI-E below: (d) The calcined TiAPSO-35 compositions of example 2E was calcined at 600°C in air for 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern shown in Table XXII-E, below. 2ϑ d,(Å) 100 x I/Io 8.8 10.05 13 11.1 7.97 74 11.5 7.69 100 13.7 6.46 39 17.6 5.04 17 18.9 4.70 26 21.1 4.21 26 22.2 4.00 65 23.1 3.85 26 23.7 3.75 22 25.2 3.534 30 26.6 3.363 35 27.4 3.255 26 28.7 3.110 35 29.6 3.018 39 29.8 2.998 44 32.7 2.739 30 34.6 2.592 17 38.0 2.368 13 48.5 1.877 13 55.1 1.667 13 Example 39E (a) TiAPSO-44, as referred to herein in both the as-synthesized and calcined forms, have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table XXIII-E below: 2ϑ d,(Å) Relative Intensity 9.5 9.30 s 16.1 5.49 m 20.8 4.27 vs 22.0 4.05 m 24.5 3.63 m 30.9 2.893 m (b) The TiAPSO-44 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern of Table XXIV-E below: 2ϑ d,(Å) 100 x I/Io 9.5 9.30 83 11.0 8.06 45 13.0 6.79 24 13.4 6.62 30 13.9 6.40 3 16.1 5.49 51 17.4 5.11 48 19.0 4.66 5 20.8 4.27 100 21.1 4.22 36 22.0 4.05 77 22.7 3.92 7 23.2 3.83 19 24.5 3.63 52 26.2 3.400 20 27.0 3.307 11 27.9 3.195 10 28.6 3.123 28 29.8 3.000 6 30.3 2.954 14 30.9 2.893 57 31.7 2.820 6 32.2 2.771 30 32.6 2.745 5 33.1 2.708 4 35.0 2.567 4 35.7 2.519 11 38.7 2.328 3 42.1 2.145 4 42.6 2.122 5 43.7 2.073 4 47.4 1.920 3 48.2 1.888 12 48.8 1.867 8 51.5 1.775 6 54.1 1.696 7 (c) A portion of the as-synthesized TiAPSO-44 of Example 11E was subjected to X-ray analysis. The TiAPSO-44 product was characterized by the x-ray powder diffraction pattern of Table XXV-E, below: Example 40E In order to demonstrate the catalytic activity of the TiAPSO compositions, calcined samples of the TiAPSO products of Examples 6E, 13E, and 24E were tested for catalytic cracking of n-butane. The reactor was a cylindrical quartz tube 254 mm. in length and 10.3 mm. I.D. In each test the reactor was loaded with particles of the test TiAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The TiAPSO samples were calcined in air (TiAPSO-5 at 600°C for 2.5 hours; TiAPSO-11 at 600°C for 1.5 hours; and TiAPSO-34 at 500°C for 2 hours) to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium-n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromotography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the TiAPSO compositions. The k A value (cm³/g min) obtained for the TiAPSO compositions are set forth, below, in Table XXVI-E: TiAPSO k A TiAPSO-5 0.6 TiAPSO-11 0.5 TiAPSO-34 1.3 F. ZINC-ALUMINUM-PHOSPHORUS-SILICON-OXIDE SIEVES Molecular sieves containing zinc, aluminum, phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the ZnAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: a) Alipro: aluminum isopropoxide; b) LUDOX-LS: LUDOX-LS is the trade name of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; c) CATAPAL: Trademark of Condea Corporation for hydrated pseudoboehmite; d) H₃PO₄: 85 weight percent aqueous phosphoric acid; e) ZnAc: Zinc Acetate, Zn(C₂H₃O₂)₂·4H₂O; f) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; g) TBAOH: 40 weight percent aqueous solution of tetrabutylammonium hydroxide; h) TMAOH: Tetramethylammonium hydroxide pentahydrate, (CH₃)₄NOH·5H₂O; i) TPAOH: 40 weight percent aqueous solution of tetrapropylammonium hydroxide, (C₃H₇)₄NOH; j) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH; k) Pr₃N: Tri-n-propylamine, (C₃H₇)₃N; l) Quin: Quinuclidine, (C₇H₁₃N); m) C-hex: cyclohexylamine; and n) DEEA: diethylethanolamine, (C₂H₅)₂NC₂H₅OH. Preparative Procedure The ZnAPSO compositions were prepared by preparing reaction mixtures having a molar composition expressed as: eR:fZnO:gAl₂O₃:hP₂O₅:iSiO₂:jH₂O wherein e, f, g, h, i and j represent the moles of template R, zinc (expressed as the oxide), Al₂O₃, P₂O₅ (H₃PO₄ expressed as P₂O₅), SiO₂ and H₂O, respectively. The values for e, f, g, h, i and j were as set forth in the hereinafter discussed preparative examples where "j" was 50 in each example, and "e" was 1.0. The reaction mixtures were prepared by forming a starting reaction mixture comprising the H₃PO₄ and a portion of the water. This mixture was stirred and the aluminum source added. The resulting mixture was blended until a homogeneous mixture was observed. The LUDOX LS was then added to the resulting mixture and the new mixture blended until a homogeneous mixture was observed. The zinc source (zinc acetate) was dissolved in the remaining water and combined with the first mixture. The combined mixture was blended until a homogenous mixture was observed. The organic templating agent was added to this mixture and blended for about two to four minutes until a homogenous mixture was observed. The resulting mixture (final reaction mixture) was placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at an effective temperature for an effective time. All digestions were carried out at the autogeneous pressure. The products were removed from the reaction vessel cooled and evaluated as set forth hereinafter. Examples IF to 41F ZnAPSO molecular sieves were prepared according to the above described procedure and the ZnAPSO products determined by x-ray analysis. The results of preparative examples 1F to 41F are set forth in Tables I-F and II-F. The reactive zinc source was zinc acetate. The reactive aluminum source was Alipro. The reactive phosphorus source was H₃PO₄. the reactive silicon source was LUDOX-LS. The organic templating agents are set forth in Tables I-F and II-F. Example 42F Samples of the products of examples 4F, 17F, 24F, 33F, 35F and 39F were subjected to chemical analysis. The chemical analysis for each product is given hereinafter with the example in which the ZnAPSO was prepared being given in parenthesis after the designation of the ZnAPSO species. (a) The chemical analysis for ZnAPSO-5 (Example 4F) was: Component Weight Percent Al₂O₃ 31.3 P₂O₅ 45.7 ZnO 2.8 SiO₂ 5.7 Carbon 5.5 LOI 12.8 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.17R; 0.11 ZnO; 1.0 Al₂O₃; 1.05 P₂O₅; 0.31 SiO₂; and a formula (anhydrous basis) of: 0.04R (Zn 0.03 Al 0.44 P 0.47 Si 0.07 )O₂ (b) The chemical analysis for ZnAPSO-34 (Example 17F) was: Component Weight Percent Al₂O₃ 32.3 P₂O₅ 35.3 ZnO 2.8 SiO₂ 1.6 Carbon 5.0 LOI 26.7 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.16 R; 0.11 ZnO; 1.0 Al₂O₃; 0.79 P₂O₅: 0.08 SiO₂; and a formula (anhydrous basis) of: 0.04R (Zn 0.03 Al 0.54 P 0.41 Si 0.02 )O₂ (c) The chemical analysis for ZnAPSO-34 (Example 24F) was: Component Weight Percent Al₂O₃ 36.2 P₂O₅ 30.3 ZnO 3.8 SiO₂ 3.7 Carbon 5.2 LOI 24.0 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.15 R; 0.13 ZnO; 1.0 Al₂O₃; 0.60 P₂O₅: 0.07 SiO₂; and a formula (anhydrous basis) of: 0.04R (Zn 0.04 Al 0.57 P 0.34 Si 0.05 )O₂ (d) The chemical analysis of ZnAPSO-35 (Example 33F) was: Component Weight Percent Al₂O₃ 30.4 P₂O₅ 33.2 ZnO 5.6 SiO₂ 7.6 Carbon 10.1 LOI 22.1 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0. 40R; 0.23 ZnO: 1.0 Al₂O₃: 0.78 P₂O₅; 0.42 SiO₂; and a formula (anhydrous basis) of: 0.12R (Zn 0.06 Al 0.47 P 0.37 Si 0.10 )O₂ (e) The chemical analysis for ZnAPSO-44 (Example 35F) was: Component Weight Percent Al₂O₃ 27.5 P₂O₅ 31.1 ZnO 4.8 SiO₂ 10.6 Carbon 11.7 LOI 25.1 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.60 R; 0.22 ZnO; 1.0 Al₂O₃; 0.81 P₂O₅; 0.65 SiO₂; and a formula (anhydrous basis) of: 0.13R (Zn 0.05 Al 0.44 P 0.36 Si 0.15 )O₂ (f) The chemical analysis of ZnAPSO-47 (Example 39F) was: Component Weight Percent Al₂O₃ 30.4 P₂O₅ 32.6 ZnO 5.3 SiO₂ 6.5 Carbon 7.7 LOI 23.4 The above chemical analysis gives an overall product composition in molar oxide ratios of: 0.35 R; 0.22 ZnO; 1.0 Al₂O₃; 0.77 P₂O₅; 0.36 SiO₂; and a formula (anhydrous basis) of: 0.09R (Zn 0.05 Al 0.49 P 0.37 Si 0.09 )O₂ Example 43F EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjunction with SEM (scanning electron microscope was carried out on clear crystals from the products of examples 4F, 24F, 33F, 35F and 39F. Analysis of crystals having a morphology characteristic of the ZnAPSO products gave the following analysis based on relative peak heights: a) ZnAPSO-5 (Example 4F) : Average of Spot Probes Zn 1 Al 44 P 50 Si 5 b) ZnAPSO-34 (Example 24F) : Average of Spot Probes Zn 3 Al 45 P 46 Si 6 c) ZnAPSO-35 (Example 33F) : Average of Spot Probes Zn 5 Al 43 P 46 Si 6 d) ZnAPSO-36 (Example 4F) : Average of Spot Probes Zn 4 Al 42 P 50 Si 4 e) ZnAPSO-44 (Example 35F) : Average of Spot Probes Zn 2 Al 43 P 39 Si 16 f) ZnAPSO-47 (Example 39F) : Average of Spot Probes Zn 5 Al 42 P 44 Si 9 Example 44F Samples of the ZnAPSO products of examples 4F, 27F, 33F, 35F and 39F were for adsorption capacities evaluated in the as-synthesized form or were calcined in air or nitrogen, to remove at least part of the organic templating agent, as hereinafter set forth. The adsorption capacities of each calcined sample were measured using a standard McBain - Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum at 350°C prior to measurement. The McBain-Bakr data for the aforementioned calcined ZnAPSO products were: a) ZnAPSO-5 (Example 4F) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 11.0 O₂ 3.46 749 -183 14.9 neopentane 6.2 100 23.4 3.5 cyclohexane 6.0 57 23.4 7.4 H₂O 2.65 4.6 23.2 13.5 H₂O 2.65 16.8 23.5 17.5 The above data demonstrate that the pore size of the calcined product is greater than 6.2Å. b) ZnAPSO-34 (Example 27F) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 14.5 O₂ 3.46 725 -183 25.8 isobutane 5.0 100 22.8 0.8 n-hexane 4.3 98 23.3 13.3 H₂O 2.65 4.6 23.1 19.9 H₂O 2.65 17.8 23.1 30.1 The above data demonstrate that the pore size of the calcined product is about 4.3Å. c) ZnAPSO-35 (Example 33F) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 10.2 O₂ 3.46 725 -183 19.1 n-hexane 4.3 98 23.3 8.6 isobutane 5.0 100 22.8 0.8 H₂O 2.65 4.6 23.1 17.2 H₂O 2.65 17.8 23.1 26.3 The above data demonstrate that the pore size of the calcined product is about 4.3Å. d) ZnAPSO-44 (Example 35F) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 10.3 O₂ 3.46 745 -183 19.8 n-hexane 4.3 98 23.3 9.7 isobutane 5.0 100 22.8 0.8 H₂O 2.65 4.6 23.1 14.0 H₂O 2.65 17.8 23.1 24.0 The above data demonstrate that the pore size of the calcined product is about 4.3Å. e) ZnAPSO-47 (Example 39F) : Adsorbate Kinetic Diameter, Å Pressure (Torr) Temp (°C) Wt. % Adsorbed O₂ 3.46 99 -183 13.9 O₂ 3.46 725 -183 23.0 isobutane 5.0 100 23.8 0.7 n-hexane 4.3 98 23.3 7.8 H₂O 2.65 4.6 23.1 18.8 H₂O 2.65 17.8 23.1 27.0 The above data demonstrate that the pore size of the calcined product is about 4.3Å. Example 45F (a) ZnAPSO-5, as prepared in example 4F, was subjected to x-ray analysis. ZnAPSO-5 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 7.4 11.91 100 7.9 11.17 29 12.85 6.88 10 13.5 6.56 1 14.85 5.96 19 15.85 5.60 3 16.45 5.39 8 19.1 4.65 9 19.7 4.51 38 20.3 4.38 4 20.8 4.27 10 21.05 4.22 30 21.5 4.14 5 21.65 4.10 5 22.4 3.973 73 22.95 3.876 3 23.85 3.730 1 24.75 3.596 2 25.9 3.442 25 27.2 3.279 4 27.75 3.212 1 28.3 3.154 2 29.0 3.078 15 29.95 2.981 15 30.35 2.947 2 32.0 2.798 3 33.6 2.666 4 34.45 2.602 12 34.8 2.577 4 35.45 2.532 2 35.9 2.501 1 36.95 2.434 3 37.7 2.386 7 41.45 2.177 2 42.2 2.141 3 42.8 2.112 1 43.4 2.085 1 45.0 2.013 1 47.6 1.910 4 51.4 1.778 2 51.95 1.760 1 55.6 1.654 2 (b) A portion of the as-synthesized ZnAPSO-5 of part (a) was calcined in air at 500°C for about 0.75 hours and then in air at 600°C for about 1.5 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d, (Å) 100 x I/Io 7.45 11.91 100 7.85 11.23 21 8.2 10.79 7 12.9 6.87 20 13.45 6.57 3 14.9 5.95 6 16.5 5.37 5 19.35 4.58 5 19.75 4.49 24 20.3 4.38 10 20.7 4.29 4 21.1 4.21 28 21.4 4.14 11 22.4 3.962 69 22.75 3.907 5 24.85 3.584 2 26.0 3.430 24 27.25 3.275 4 27.45 3.252 2 27.8 3.207 2 28.15 3.168 3 28.35 3.146 2 29.1 3.068 16 30.1 2.970 14 33.7 2.658 3 34.6 2.592 13 35.45 2.532 4 37.05 2.427 3 37.85 2.378 6 42.4 2.132 2 47.8 1.903 2 51.5 1.774 3 55.8 1.647 1 (c) The ZnAPSO-5 compositions are generally characterized by the data of Table III-F below. 2ϑ d (Å) Relative Intensity 7.2-7.4 12.28-11.91 vs 19.4-19.8 4.58-4.48 m 21.0-21.2 4.23-4.19 m 22.3-22.5 3.971-3.952 m-s 25.7-26.0 3.466-3.427 w-m (d) The ZnAPSO-5 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table IV-F, below. 2ϑ d, (Å) 100 x I/Io 7.2-7.4 12.28-11.91 100 12.6-13.0 7.03-6.81 8-21 14.6-14.9 6.07-5.95 9-20 19.4-19.8 4.58-4.48 24-38 21.0-21.2 4.23-4.19 20-35 22.3-22.5 3.971-3.952 47-82 24.7-24.9 3.604-3.576 1-2 25.7-26.0 3.466-3.427 18-27 28.9-29.1 3.089-3.069 10-20 29.9-30.1 2.988=2.969 12-17 33.6-33.8 2.667-2.652 3-4 34.4-34.6 2.607-2.592 10-14 36.9-37.0 2.436-2.430 2-3 37.6-37.9 2.392-2.374 5-8 41.45 2.177 0-2 42.2-42.4 2.141-2.132 2-3 42.8 2.113 0-1 43.4 2.090 0-1 45.0 2.014 0-1 47.5-47.8 1.914-1.903 2-4 51.3-51.6 1.781 2-3 51.95 1.760 0-1 55.5-55.8 1.656-1.647 0-2 Example 46F (a) ZnAPSO-11, as prepared in example 10F was subjected to x-ray analysis. ZnAPSO-11 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-11 compositions are generally characterized by the data of Table V-F below. 2ϑ d (Å) Relative Intensity 9.35-9.45 9.44-9.35 m 13.15-13.35 6.67-6.63 m 21.1-21.25 4.21-4.19 s-vs 22.75-22.85 3.911-3.896 s-vs 23.15-23.3 3.839-3.819 w-m 26.8-26.9 3.327-3.313 w-m (c) The ZnAPSO-11 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table VI-F, below: 2ϑ d, (Å) 100 x I/Io 8.05-8.1 10.98-10.92 8-26 9.35-9.45 9.44-9.35 54-72 13.15-13.35 6.67-6.63 22-40 15.65-15.75 5.66-5.62 10-27 16.05-16.2 5.53-5.47 0-3 19.0 4.66 0-4 19.85 4.49-4.46 4-14 20.4-20.5 4.35-4.33 19-38 21.1-21.25 4.21-4.19 83-100 22.1-22.25 4.018-3.998 12-32 22.75-22.85 3.911-3.896 85-100 23.15-23.3 3.839-3.819 12-45 26.45-26.55 3.369-3.354 8-14 26.8-26.9 3.327-3.313 12-40 28.7-28.8 3.111-3.100 20-36 29.75-29.85 3.005-2.993 11-23 31.6-31.8 2.832-2.813 0-10 32.8-32.95 2.731-2.719 7-15 34.2-34.3 2.620-2.615 6-9 35.85-36.0 2.503-2.495 6-12 36.45-36.55 2.464-2.459 4-8 37.65-37.7 2.389-2.387 0-7 37.85 2.377 0-10 39.7 2.271 0-1 43.0-43.05 2.103-2.100 0-4 44.85-44.9 2.022-2.018 0-3 48.75-48.85 1.867-1.864 0-3 50.8-50.9 1.797-1.794 0-3 54.8 1.675 0-1 Example 47F (a) ZnAPSO-20, as prepared in example 29F, was subjected to x-ray analysis. ZnAPSO-20 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-20 compositions are generally characterized by the data of Table VII-F below: 2ϑ d, (Å) Relative Intensity 13.85-14.0 6.39-6.33 m 19.65-19.8 4.52-4.48 m 24.15-24.3 3.685-3.663 vs 28.0-28.15 3.187-3.170 w 31.35-31.5 2.853-2.840 w 34.5-34.65 2.600-2.589 w-m (c) The ZnAPSO-20 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table VIII-F, below: 2ϑ d, (Å) 100 x I/Io 13.85-14.0 6.39-6.33 45-47 19.65-19.8 4.52-4.48 40-41 22.0-22.15 4.040-4.013 2-3 24.15-24.3 3.685-3.663 100 28.0-28.15 3.187-3.170 12-13 31.35-31.5 2.853-2.840 11-12 34.5-34.65 2.600-2.589 16-20 37.35-37.5 2.408-2.398 2 40.0-40.2 2.254-2.243 4 42.55-42.7 2.125-2.118 4 47.35-47.5 1.920-1.914 5 51.75-51.9 1.767-1.762 8-9 Example 48F (a) ZnAPSO-31, as prepared in example 14F, was subjected to x-ray analysis. ZnAPSO-31 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-31 compositions are generally characterized by the data of Table IX-F below: 2ϑ d, (Å) Relative Intensity 8.4-8.5 10.53-10.40 m 20.2-20.3 4.40-4.37 m 21.3 4.171 w 22.0 4.036 m 22.5-22.6 3.952-3.934 vs 31.6-31.75 2.831-2.820 w-m (c) The ZnAPSO-31 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table X-F, below: 2ϑ d, (Å) 100 x I/Io 8.4-8.5 10.53-10.40 50-53 9.45-9.5 9.35-9.32 7-8 13.2-13.4 6.76-6.60 10-11 18.2-18.25 4.87-4.86 5-8 20.2-20.3 4.39-4.37 49-52 21.3 4.171 16-18 22.0 4.036 30 22.5-22.6 3.952-3.934 100 26.9-27.0 3.314-3.302 3-7 27.95-28.25 3.192-3.529 13-17 29.6-29.7 3.018-3.008 8-10 30.2-30.3 2.959-2.950 0-4 31.6-31.75 2.831-2.820 18-20 32.95 2.718 4-9 35.15-35.2 2.554-2.550 12 36.1-36.2 2.489-2.481 4-7 37.25-37.35 2.413-2.409 2-3 38.25 2.353 3 39.3 2.291 2 40.3 2.238 2 46.6-46.65 1.949-1.948 4-6 47.4-47.45 1.918-1.916 2-4 51.5 1.774 7 Example 49F (a) ZnAPSO-34, as prepared in example 24F, was subjected to x-ray analysis. ZnAPSO-34 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: 2ϑ d, (Å) 100 x I/Io 9.6 9.19 100 12.95 6.84 16 14.2 6.25 14 16.1 5.50 42 18.1 4.90 22 20.65 4.30 91 22.4 3.978 5 23.15 3.842 5 25.3 3.521 25 25.9 3.437 18 27.7 3.218 5 28.45 3.135 6 29.65 3.015 5 30.6 2.920 33 31.3 2.856 23 32.5 2.755 2 34.45 2.602 7 36.4 2.468 5 38.8 2.320 4 39.75 2.267 5 43.15 2.097 4 43.55 2.077 4 47.65 1.908 5 49.10 1.856 8 49.9 1.827 4 51.0 1.791 4 53.15 1.723 3 54.65 1.679 3 55.9 1.645 3 (b) A portion of the as-synthesized ZnAPSO-34 of part a) was calcined in air at 500°C for about 2 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d, (Å) 100 x I/Io 9.55 9.27 100 12.95 6.85 24 16.15 5.49 13 17.95 4.94 10 20.75 4.28 30 22.2 4.004 2 23.25 3.828 5 25.2 3.533 9 26.15 3.411 12 28.45 3.138 4 30.9 2.896 16 31.35 2.852 9 (c) The ZnAPSO-34 compositions are generally characterized by the data of Table XI-F below. 2ϑ d, (Å) Relative Intensity 9.4-9.8 9.41-9.03 m-vs 12.7-13.2 6.97-6.71 w-m 15.8-16.2 5.61-5.47 w-m 20.5-20.9 4.33-4.25 m-vs 25.0-25.3 3.562-3.520 vw-m 30.5-30.9 2.931-2.894 w-m (d) The ZnAPSO-34 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XII-F, below: 2ϑ d, (Å) 100 x I/Io 9.4-9.8 9.41-9.03 77-100 12.7-13.2 6.97-6.71 16-31 14.0-14.3 6.33-6.19 0-22 15.8-16.2 5.61-5.47 16-47 17.8-18.2 4.98-4.87 13-29 20.5-20.9 4.33-4.25 36-100 22.2-22.5 4.004-3.952 5.8 23.0-23.3 3.867-3.818 5-6 25.0-25.3 3.562-3.520 9-32 25.7-26.25 3.466-3.395 12-20 27.45-27.7 3.249-3.220 5-8 28.1-28.45 3.175-3.137 4-8 29.4-29.8 3.038-2.998 0-5 30.5-30.9 2.931-2.894 16-35 31.0-31.65 2.885-2.827 9-25 32.2-32.5 2.780-2.755 0-2 34.3-34.8 2.614-2.578 5-8 36.1-36.4 2.488-2.468 0-5 38.65-38.8 2.330-2.321 0-4 39.5-39.8 2.281-2.265 4-7 43.0-43.4 2.103-2.085 4 47.5-48.0 1.914-1.895 3-6 48.8-49.1 1.866-1.855 8-10 49.9 1.859 0-4 50.8-51.0 1.797-1.791 0-4 53.1-53.15 1.725-1.723 0-3 54.5-54.8 1.684-1.675 0-3 55.8-55.9 1.647-1.645 0-4 Example 50F (a) ZnAPSO-35, as prepared in example 33F. was subjected to x-ray analysis. ZnAPSO-35 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) A portion of the as-synthesized ZnAPSO-35 of part a) was calcined in air at 500°C for about 1.75 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d, (Å) 100 x I/Io 7.45 11.85 10 8.7 10.15 22 11.0 8.04 91 13.5 6.55 100 17.45 5.08 35 21.0 4.23 21 22.15 4.011 60 23.5 3.782 19 25.15 3.542 13 27.2 3.278 20 28.6 3.122 28 29.35 3.041 14 32.45 2.759 28 (c) The ZnAPSO-35 compositions obtained to date have patterns which are generally characterized by the data of Table XIII-F below. 2ϑ d, (Å) Relative Intensity 10.8-11.0 8.19-8.04 m-vs 13.30-13.5 6.66-6.56 m-vs 17.2-17.45 5.16-5.08 m 20.95-21.2 4.24-4.19 m 21.9-22.15 4.06-4.01 m-vs 32.0-32.5 2.797-2.755 m (d) The ZnAPSO-35 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XIV-F below: 2ϑ d, (Å) 100 x I/Io 8.6-8.7 10.27-10.16 18-22 10.8-11.0 8.19-8.04 43-91 11.35 7.80 0-4 13.30-13.5 6.66-6.56 39-100 15.8-15.9 5.61-5.57 0-10 17.2-17.45 5.16-5.08 35-75 17.8-17.9 4.98-4.96 0-sh 20.95-21.2 4.24-4.19 21-49 21.9-22.15 4.06-4.01 60-100 23.0-23.5 3.867-3.786 0-19 23.65 3.762 0-3 24.85-25.15 3.583-3.541 4-13 26.6-27.2 3.351-3.278 20-22 28.5-28.8 3.132-3.100 26-30 29.1-29.35 3.069-3.043 sh-14 32.0-32.5 2.797-2.755 28-43 34.55-34.9 2.596-2.571 0-9 35.7-35.8 2.515-2.507 0-5 37.75 2.382 0-5 39.35 2.889 0-4 42.1-42.35 2.146-2.134 0-6 43.0-43.2 2.103-2.094 0-4 48.5-48.7 1.877-1.870 0-11 49.35-49.4 1.847-1.845 0-8 51.4-51.6 1.778-1.771 0-7 55.3-55.4 1.661-1.658 0-6 Example 51F (a) ZnAPSO-36, as prepared in example 1F, was subjected to x-ray analysis. ZnAPSO-36 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-36 compositions obtained to date have patterns which are generally characterized by the data of Table XV-F below. 2ϑ d, (Å) Relative Intensity 7.45-8.0 11.14-11.04 vs 16.45-16.5 5.38-5.36 w-m 19.1-19.2 4.65-4.62 w-m 20.8-20.9 4.28-4.25 w-m 21.75-21.8 4.09-4.08 w 22.05-22.15 4.027-4.017 w (c) The ZnAPSO-36 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XVI-F below: 2ϑ d, (Å) 100 x I/Io 7.45-8.0 11.14-11.04 100 8.2-8.3 10.76-10.68 0-sh 13.55-13.6 6.53-6.50 3-4 15.85-15.95 5.60-5.56 10-12 16.45-16.5 5.38-5.36 18-31 19.1-19.2 4.65-4.62 19-22 20.8-20.9 4.28-4.25 17-39 21.75-21.8 4.09-4.08 10-17 22.05-22.15 4.027-4.017 14-17 23.0-23.05 3.865-3.859 3-4 23.85-24.0 3.728-3.707 3-6 27.25-27.35 3.273-3.260 9-15 28.3-28.4 3.152-3.142 6-9 30.1-30.4 2.970-2.940 4-6 31.95-32.1 2.803-2.788 6-11 33.2-33.6 2.698-2.665 1-2 34.75-34.9 2.580-2.572 7-10 35.85-35.95 2.504-2.497 2-6 37.75-37.8 2.384-2.380 2 40.15-40.4 2.246-2.232 1-3 41.45-41.5 2.180-2.176 1-2 42.2-42.3 2.142-2.137 0-2 51.4-51.45 1.779-1.776 2 54.0 1.697 0-1 55.4-55.8 1.658-1.648 1-2 Example 52F (a) ZnAPSO-39, as referred to in example 9F, was subjected to x-ray analysis. ZnAPSO-39 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-39 compositions are generally characterized by the data of Table XVII-F below. 2ϑ d, (Å) Relative Intensity 9.35-9.45 9.46-9.36 m 13.15-13.35 6.73-6.63 m 18.3-18.4 4.85-4.82 w-m 21.1-21.2 4.21-4.19 s-vs 22.75-22.85 3.909-3.892 s-vs 26.8-26.9 3.389-3.314 w-m (c) The ZnAPSO-39 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XVIII-F below: 2ϑ d, (Å) 100 x I/Io 9.35-9.45 9.46-9.36 60-72 13.15-13.35 6.73-6.63 22-40 18.3-18.4 4.85-4.82 16-40 21.1-21.2 4.21-4.19 83-100 22.75-22.85 3.909-3.892 85-100 26.8-26.9 3.389-3.314 12-40 28.2-28.3 3.164-3.153 5-8 28.7-28.8 3.110-3.100 19-20 29.7-29.8 3.008-2.998 11-32 30.1-30.2 2.979-2.959 11-25 32.8-32.95 2.730-2.718 8-12 34.5-34.65 2.600-2.589 5-6 36.45-36.5 2.465-2.462 4-12 37.85-38.1 2.377-2.362 3-10 40.6-40.95 2.222-2.204 0-4 Example 53F (a) ZnAPSO-43, as referred to in example 28F, was subjected to x-ray analysis. ZnAPSO-43 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) ZnAPSO-43 compositions are generally characterized by the data of Table XIX-F below: 2ϑ d, (Å) Relative Intensity 12.3-12.45 7.20-7.11 m-vs 16.8-16.95 5.28-5.23 vw-w 21.7-21.85 4.095-4.068 vw-m 26.95 -27.1 3.308-3.291 s-vs 32.4-33.55 2.763-2.751 w-m (c) The ZnAPSO-43 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XX-F below: 2ϑ d, (Å) 100 x I/Io 12.3-12.45 7.20-7.11 66-100 16.8-16.95 5.28-5.23 0-10 20.8-20.95 4.27-4.24 10-13 21.7-21.85 4.095-4.068 0-48 26.95-27.1 3.308-3.290 82-100 28.65-28.75 3.116-3.105 11-23 32.4-32.55 2.763-2.751 18-20 41.2 2.191 0-4 44.95-45.1 2.017-2.010 8-15 50.95-51.15 1.792-1.786 0-7 53.7-53.8 1.710-1.707 0-8 Example 54F (a) ZnAPSO-44 as prepared in example 34F, was subjected to x-ray analysis. ZnAPSO-44 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) A portion of the as-synthesized ZnAPSO-44 of part a) was calcined in air at 500°C for about 67 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The ZnAPSO-44 compositions are generally characterized by the data of Table XXI-F below: 2ϑ d, (Å) Relative Intensity 9.4-9.55 9.41-9.26 vs 12.9-13.05 6.86-6.78 vw-m 20.65-20.8 4.30-4.27 m 21.4-21.8 4.15-4.08 w-m 24.3-25.15 3.663-3.541 m 30.75-30.95 2.908-2.889 m (d) The ZnAPSO-44 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXII-F below: 2ϑ d, (Å) 100 x I/Io 9.4-9.55 9.41-9.25 100 12.9-13.05 6.86-6.78 8-34 13.6-14.05 6.51-6.30 3-5 16.0-16.2 5.54-5.47 14-21 17.25-17.95 5.14-4.94 0-6 18.95-19.05 4.68-4.66 0-5 20.65-20.8 4.30-4.27 35-52 21.4-21.8 4.15-4.08 18-32 22.55-22.65 3.943-3.926 4 23.15-23.25 3.842-3.826 5-10 24.3-25.15 3.663-3.541 22-47 26.1-26.25 3.414-3.395 8-14 27.7-28.4 3.220-3.143 7-9 29.8 2.998- 0-3 30.05-30.15 2.974 0-13 30.75-30.95 2.908-2.889 23-31 32.65-32.8 2.743-2.730 0-3 33.0 2.714 0-6 34.9 2.571 0-2 35.15 2.553 0-2 35.3-35.6 2.543-2.522 9-10 38.7 2.327-2.327 0-2 39.3-40.2 2.292-2.243 0-2 40.1 2.249 0-1 42.1-42.3 2.146-2.137 0-3 42.55 2.127 0-2 43.7 2.071 0-1 48.2 1.888 0-3 48.65-48.8 1.872-1.866 0-5 50.2-50.4 1.817-1.811 0-5 52.0 1.759 0-1 53.8-54.0 1.704-1.698 0-7 Example 55F (a) ZnAPSO-46, as referred to in example 8F was subjected to x-ray analysis. ZnAPSO-46 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) The ZnAPSO-46 compositions are characterized by the data of Table XXIII-F below: 2ϑ d, (Å) Relative Intensity 7.6-7.75 11.63-11.42 vs 13.1-13.35 6.76-6.63 w-m 21.5-21.6 4.13-4.12 w-m 22.6-22.85 3.934-3.896 m 26.75-27.0 3.333-3.302 w (c) The ZnAPSO-46 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXIV-F below: 2ϑ d, (Å) 100 x I/Io 6.5-6.7 13.60-13.19 7-10 7.6-7.75 11.63-11.42 100 10.2 8.67 0-1 13.1-13.35 6.76-6.63 10-20 13.7-13.8 6.46-6.41 4-5 14.9-15.0 5.95-5.91 4-5 15.2-15.35 5.83-5.77 5-7 16.6-16.8 5.34-5.28 7 17.35-17.5 5.11-5.07 0-1 19.7-20.0 4.51-4.44 2-3 20.3-20.5 4.37-4.33 6-11 21.5-21.6 4.13-4.12 18-21 22.6-22.85 3.934-3.896 32-58 23.9-24.05 3.723-3.700 2-3 25.1-25.3 3.548-3.520 0-1 26.75-27.0 3.333-3.302 10-12 27.7-28.0 3.220-3.187 3-4 28.2-28.3 3.175-3.152 2-3 28.6-28.9 3.121-3.089 8-11 29.7-29.9 3.008-2.988 6-9 31.0-31.15 2.885-2.870 3-4 31.6-31.8 2.831-2.813 0-1 32.8-33.2 2.730-2.706 3-4 34.15-34.4 2.626-2.607 2-4 35.8-36.0 2.508-2.495 3-4 36.45-36.55 2.464-2.459 2-3 37.3-37.7 2.410-2.386 0-2 39.7 2.271 0-1 40.9-41.1 2.206-2.196 0-1 43.85-44.1 2.065-2.054 0-1 46.1 1.969 0-1 47.4-47.7 1.918-1.908 0-1 49.7-49.8 1.834-1.831 0-1 51.4-51.7 1.778-1.768 0-1 52.2-52.45 1.752-1.745 0-1 Example 56F (a) ZnAPSO-47, as referred to in example 38F, was subjected to x-ray analysis. ZnAPSO-47 was determined to have a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth below: (b) A portion of the as-synthesized ZnAPSO-47 of part a) was calcined in air at 500°C for about 1.75 hours. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The ZnAPSO-47 compositions are characterized by the date in Table XXV-F below: 2ϑ d, (Å) Relative Intensity 9.45-9.65 9.35-9.17 vs 12.85-13.05 6.89-6.78 w-m 15.95-16.2 5.55-5.46 w-m 20.55-20.85 4.31-4.26 m-vs 25.9-26.2 3.439-3.399 w-m 30.55-31.0 2.925-2.885 w-m (d) The ZnAPSO-47 compositions for which x-ray powder diffracton data have been obtained to date have patterns which are characterized by the x-ray powder diffraction pattern shown in Table XXVI-F below: 2ϑ d, (Å) 100 x I/Io 9.45-9.65 9.35-9.17 93-100 12.85-13.05 6.89-6.78 17-25 13.85-14.15 6.39-6.26 3-7 15.95-16.2 5.55-5.46 10-42 17.45-18.0 5.09-4.93 2-11 20.55-20.85 4.31-4.26 27-100 21.85 4.07 0-7 22.95-23.3 3.867-3.816 4-11 24.75-25.2 3.600-3.533 8-21 25.9-26.2 3.439-3.399 16-29 27.6-28.55 3.231-3.126 3-10 27.9-28.0 3.196-3.188 0-3 29.45-29.8 3.031-2.998 2-5 30.55-31.0 2.925-2.885 18-49 30.9-31.4 2.894-2.849 sh 31.5 2.839 0-3 32.3 2.772 0-2 33.3 2.689 0-3 34.45-34.9 2.603-2.600 2-19 34.9 2.573 0-2 35.7-35.9 2.516-2.503 0-5 38.4-38.55 2.344-2.336 0-3 39.6-39.65 2.273 0-4 42.25-42.5 2.139-2.126 0-3 43.3 2.089 0-2 44.9 2.019 0-2 47.6 1.909 0-6 48.6-48.7 1.873-1.870 0-5 50.45-50.5 1.807 0-5 53.2-53.25 1.722-1.721 0-5 54.5 1.684 0-2 56.0 1.642 0-5 Example 57F In order to demonstrate the catalytic activity of calcined ZnAPSO compositions were tested for catalytic cracking of n-butane using a bench-scale apparatus. The reactor was a cylindrical quartz tube 254 mm. in length and 10.3 mm. I.D. In each test the reactor was loaded with particles of the test ZnAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The ZnAPSO samples had been previously calcined in air to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of the ZnAPSO compositions. The k A value (cm³/g min) obtained for the ZnAPSO compositions are set forth, below, in Table XXVII-F: ZnAPSO Prepared in Example No. Rate Constant (k A ) ZnAPSO-5 4F 1.5 ZnAPSO-34 24F 12.7 ZnAPSO-35 33F 1.0 ZnAPSO-44 35F 5.0 ZnAPSO-47 39F 5.6 G. COBALT-MANGANESE-ALUMINUM-PHOSPHORUS-SILICON-OXIDE SIEVES Preparative Reagents In the following examples the CoMnAPSO compositions were prepared using numerous regents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: a) Aiipro: aluminum isopropoxide; b) LUDOX-LS: LUDOX-LS is the tradename of DuPont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; c) H₃PO₄: 85 weight percent phosphoric acid; d) MnAc: Manganese acetate, Mn(C₂H₃O₂)₂ · 4H₂O; e) CoAc: Cobalt Acetate, Co(C₂H₃O₂)₂ · 4H₂O; f) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; and g) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH. Preparative Procedures The following preparative examples were carried out by forming a starting reaction mixture by adding the H₃PO₄ and one half of the quantity of water. To this mixture the aluminum isopropoxide was added. This mixture was then blended until a homogeneous mixture was observed. To this mixture the LUDOX-LS was added and the resulting mixture blended (about 2 minutes) until a homogeneous mixture was observed. A second mixture was prepared using manganese acetate and one half of the remaining water. A third mixture was prepared using cobalt acetate and one half of the remaining water. The three mixtures were admixed and the resulting mixture blended until a homogeneous mixture was observed. The organic templating agent was then added to the resulting mixture and the resulting mixture blended until a homogeneous mixture was observed. i.e. about 2 to 4 minutes. The pH of the mixture was measured and adjusted for temperature. The mixture was then placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at a temperature All digestions were carried out at the autogeneous pressure. EXAMPLES 1G to 4G CoMnAPSO molecular sieves were prepared according to the above identified procedure and the CoMnAPSO products determined by X-ray analysis. The results of examples 1G to 4G are set forth in Table I-G. Examples AG to FG in Table I-G represent reaction mixtures that did not show CoMnAPSO products when determined by X-ray analysis. Example 5G (a) Samples of the above prepared CoMnAPSO products, as identified in parenthesis, were calcined in air to remove at least part of the organic templating agent of the CoMnAPSO product. The adsorption capacities of each calcined sample were measured using a standard McBain-Bakr gravimetric adsorption apparatus. The samples were activated in a vacuum (less than 0.04 torr) at 350°C prior to measurement. The McBain-Bakr data were as follows: (b) CoMnAPSO-34 and CoMnAPSO-5 (Example 2G): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt.% Adsorbed Oxygen 3.46 105 -183 13.8 Oxygen 3.46 733 -183 18.5 Neopentane 6.2 742 23.8 2.6 Cyclohexane 6.0 65 23.7 4.6 n-hexane 4.3 93 23.4 5.0 H₂O 2.65 4.6 23.4 15.8 H₂O 2.65 19 23.7 23.6 (c) CoMnAPSO-5 and CoMnAPSO-11 (Example 4G): Example 6G Samples of the as-synthesized products of examples 2G and 4G were subjected to chemical analysis. The chemical analysis for these CoMnAPSOs was: (a) The chemical analysis for the product of example 2G was: Component Weight Percent Al₂O₃ 27.5 P₂O₅ 37.7 SiO₂ 4.98 CoO 4.3 MnO 5.2 Carbon 5.3 LOI 20.5 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.057 CoO:0.073 MnO:0.270 Al₂O₃:0.266 P₂O₅:0.083 SiO₂ and a formula (anhydrous basis) of: 0.055R (Al 0.420 P 0.414 Si 0.065 Co 0.044 Mn 0.057 )O₂ (b) The chemical analysis for the product of example 4G was: Component Weight Percent Al₂O₃ 26.6 P₂O₅ 37.6 SiO₂ 7.1 CoO 5.1 MnO 6.0 Carbon 1.91 LOI 17.9 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.068 CoO:0.085 MnO:0.261 Al₂O₃:0.265 P₂O₅:0.118 SiO₂ and a formula (anhydrous basis) of: 0.027R (Al 0.40 P 0.40 Si 0.089 Co 0.051 Mn 0.064 )O₂ Example 7G EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjuction with SEM (scanning electron microscope) was carried out on the products of examples 2G and 4G. Analysis of crystals having a morphology characteristic of each CoMnAPSO product gave the following analysis based on relative peak heights: (a) Example 2G (CoMnAPSO-5): Average of Spot Probes Al 0.81 P 0.98 Si 0.18 Co 0.10 Mn 0.17 (b) Example 2G (CoMnAPSO-34): Average of Spot Probes Al 0.82 P 0.93 Si 0.17 Co 0.03 Mn 0.03 (c) Example 4G (CoMnAPSO-5): Average of Spot Probes Al 0.93 P 0.71 Si 0.15 Co 0.05 Mn 0.07 (d) Example 4G (CoMnAPSO-11): Average of Spot Probes Al 0.81 P 0.95 Si 0.15 Co 0.03 Mn 0.05 Example 8G (a) CoMnAPSO-5, as prepared in example 1G, was subjected to x-ray analysis. The CoMnAPSO-5 was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d(Å) (I/Io)x100 7.5 11.84 67 9.5 9.29 100 12.9 6.89 11 14.1 6.29 7 14.9 5.93 14 16.0 5.54 22 18.0 4.93 10 19.8 4.49 19 20.6 4.32 51 21.1 4.22 40 22.4 3.96 28 25.2 3.530 12 29.1 3.071 6 29.5 3.024 3 30.1 2.968 10 30.5 2.928 16 31.3 2.862 11 33.7 2.659 3 34.5 2.601 4 34.6 2.591 5 37.8 2.383 6 47.7 1.905 3 48.9 1.863 2 49.9 1.828 2 50.9 1.794 2 55.8 1.647 2 (b) A portion of the as-synthesized CoMnAPSO-5 of example 2G was calcined in air at 600°C for one (1) hour. The calcined product was characterized by the following x-ray powder diffraction pattern: (c) The species CoMnAPSO-5 is a molecular sieve having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table II-G as follows: 2ϑ d(Å) Relative Intensity 7.4-7.5 11.95-11.84 m 12.9-13.1 6.89-6.76 w-m 14.9 5.93 vw-w 19.7-19.8 4.51-4.49 vw-w 20.9-21.3 4.26-4.17 m 22.4-22.5 3.97-3.95 m (d) All of the CoMnAPSO-5 compositions, both as-synthesized and calcined, for which x-ray powder diffraction data have been obtained have patterns which are within the generalized pattern of Table III-G, below: 2ϑ d(Å) (I/Io)x100 7.4 - 7.5 11.95 - 11.84 32 - 67 12.9 - 13.1 6.89 - 6.81 11 - 20 14.9 5.93 4 - 14 19.7 - 19.8 4.51 - 4.49 8 - 19 20.9 - 21.3 4.26 - 4.17 22 - 40 22.4 - 22.5 3.96 - 3.95 28 - 32 24.7 - 24.8 3.60 - 3.59 6 25.9 - 26.1 3.440 - 3.420 10 - 11 29.0 - 29.2 3.079 - 3.063 6 29.9 - 30.2 2.988 - 2.965 6 - 10 34.4 - 34.7 2.607 - 2.584 4 34.9 2.568 3 37.8 2.383 6 47.7 1.905 3 55.8 1.647 2 EXAMPLE 9G (a) The CoMnAPSO-11, prepared in example 3G, was subjected to X-ray analysis. The CoMnAPSO-11 was impure but the CoMnAPSO-11 was determined to have an X-ray powder diffraction pattern characterized by the following data: (b) A portion of the as-synthesized CoMnAPSO-11 of example 4G was calcined in air at 600°C for one (1) hour. The calcined product was characterized by the following X-ray powder diffraction pattern: c) The species CoMnAPSO-11 is a molecular sieve having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table IV-G as follows: 2ϑ d,(Å) Relative Intensity 9.5-9.6 9.31-9.21 m-vs 15.7-15.9 5.64-5.57 m-vs 20.3-20.4 4.37-4.36 m 21.1-21.2 4.21-4.19 m 22.1-22.5 4.02-3.95 m 23.2-23.4 3.83-3.80 vs (d) All of the CoMnAPSO-11 compositions both as-synthesized and calcined, for which x-ray powder diffraction data have presently been obtained have patterns which are within the generalized pattern of Table V-G, below: 2ϑ d,(Å) (I/Io)x100 8.1-8.2 10.88-10.85 46-68 9.5-9.6 9.31-9.19 68-95 13.1-13.2 6.77-6.73 24-45 15.7-15.9 5.64-5.58 49-91 16.3 5.44 9 19.0 4.67 9-10 20.3-20.4 4.37-4.36 49-66 21.1-21.2 4.21-4.19 30-37 22.1-22.5 4.02-3.96 31-62 22.7-22.8 3.92-3.91 28-29 23.2-23.4 3.83-3.80 100 24.7-24.8 3.60-3.59 10-14 26.4-26.6 3.376-3.346 16-40 28.1-28.2 3.175-3.163 9 28.7 3.113 25-26 29.2-29.5 3.061-3.024 8-28 31.5 2.838 8 32.7-32.8 2.739-2.732 2-27 32.9 2.719 31 34.2 2.622 2-11 36.2-36.4 2.481-2.468 2-9 37.6-37.9 2.392-2.374 2-3 Example 10G a) The CoMnAPSO-34, prepared in example 1G, was subjected to x-ray analysis. The CoMnAPSO-34 was impure but was the major phase and was determined to have an x-ray powder diffraction pattern characterized by the following data: 2ϑ d(Å) (I/Io)x100 7.5 11.84 67 9.5 9.29 100 12.9 6.89 11 14.1 6.29 7 14.9 5.93 14 16.0 5.54 22 18.0 4.93 10 19.8 4.49 19 20.6 4.32 51 21.1 4.22 40 22.4 3.96 28 25.2 3.530 12 29.1 3.071 6 29.5 3.024 3 30.1 2.968 10 30.5 2.928 16 31.3 2.862 11 33.7 2.659 3 34.5 2.601 4 34.6 2.591 5 37.8 2.383 6 47.7 1.905 3 48.9 1.863 2 49.9 1.828 2 50.9 1.794 2 55.8 1.647 2 b) A portion of the as-synthesized CoMnAPSO-34 of 2G was calcined in air at 600°C for one (1) hour. THe calcined product was characterized by the following x-ray powder diffraction pattern: 2ϑ d(Å) (I/Io)x100 7.5 11.84 32 9.6 9.20 100 13.0 6.81 20 14.9 5.93 4 16.2 5.48 8 18.0 4.93 6 19.3 4.60 3 19.8 4.49 8 20.9 4.26 22 21.2 4.20 26 21.5 4.13 3 22.5 3.96 32 23.4 3.81 3 25.3 3.520 7 26.1 3.420 11 26.2 3.396 7 28.5 3.129 3 29.2 3.063 6 30.2 2.965 6 31.0 2.881 11 31.5 2.840 7 34.7 2.584 4 34.9 2.568 3 38.0 2.368 2 (c) The species CoMnAPSO-34 is a molecular sieve having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table VI-G as follows: 2ϑ d,(Å) Relative Intensity 9.5-9.6 9.29-9.20 vs 12.8-13.0 6.92-6.81 w-m 16.0-16.2 5.54-5.48 vw-m 20.6-20.9 4.32-4.26 m 21.1-21.2 4.22-4.20 m 25.2-25.3 3.530-3.520 vw-w 31.0-31.5 2.881-2.840 w (d) All of the CoMnAPSO-34 compositions, both as-synthesized and calcined, for which x-ray powder diffraction data have been obtainehave patterns which are within the generalized pattern below: 2ϑ d(Å) (I/Io)x100 9.5-9.6 9.29-9.20 100 12.8-13.0 6.92-6.81 11-20 14.1 6.29 7-9 16.0-16.2 5.54-5.48 8-23 18.0 4.93 6-12 19.3 4.60 3 20.6-20.9 4.32-4.26 22-57 21.1-21.2 4.22-4.20 26-40 21.5 4.13 3 23.0-23.4 3.87-3.81 2-3 25.2-25.3 3.530-3.520 7-14 25.8-26.2 3.453-3.396 7-13 27.5 3.243 2 28.3-28.5 3.153-3.129 3-4 29.5 3.024 3 30.5 2.928 16-18 31.0-31.5 2.881-2.840 11-13 33.7-33.8 2.659-2.652 2-7 34.5-34.6 2.601-2.592 5 38.0 2.368 2 39.6 2.276 2 43.3 2.090 2 47.5-47.7 1.914-1.905 2-3 48.9-49.0 1.863-1.859 2-4 49.9 1.828 2 50.8-50.9 1.797-1.794 2-3 Example 15G In order to demonstrate the catalytic activity of the CoMnAPSO compositions, calcined samples of the products of examples 2G and 4G, were tested for catalytic cracking. The CoMnAPSO compositions were evaluated for n-butane cracking using a bench-scale apparatus. The reactor was a cylindrical quartz tube 254 mm. in length and 10.3 mm I.D. In each test the reactor was loaded with particles of the CoMnAPSO which were 20-40 mesh (U.S. std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The CoMnAPSO samples had been previously calcined in air to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium-n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. The pseudo-first-order rate constant (k A ) was calculated to determine the relative catalytic activity of each CoMnAPSO composition. The k A value (cm³/g min) obtained for the CoMnAPSO are set forth below: Product of Example No. Rate Constant (k A ) 2G 6.9 4G 0.8 H. COBALT-MANGANESE-MAGNESIUM-ALUMINUM-PHOSPHORUS-SILICONE-OXIDE SIEVES Molecular sieves containing coblat, manganese, magnesium, aluminum, phosphorus and silicon as framework tetrahedral oxide units are prepared as follows: Preparative Reagents In the following examples the CoMnMgAPSO compositions were prepared using numerous reagents. The reagents employed and abbreviations employed herein, if any, for such reagents are as follows: a) Alipro: aluminum isopropoxide; b) LUDOX-LS: LUDOX-LS is the tradename of Du Pont for an aqueous solution of 30 weight percent SiO₂ and 0.1 weight percent Na₂O; c) H₃PO₄: aqueous solution which is 85 weight percent phosphoric acid; d) MnAc: Manganese acetate, Mn(C₂H₃O₂)₂ · 4H₂O: e) CoAc: Cobalt Acetate, Co(C₂H₃O₂)₂ · 4H₂O: f) MgAc: Magnesium Acetate Mg(C₂H₃O₂) · 4H₂O; g) TEAOH: 40 weight percent aqueous solution of tetraethylammonium hydroxide; and h) Pr₂NH: di-n-propylamine, (C₃H₇)₂NH. Preparative Procedures The following preparative examples were carried out by forming a starting reaction mixture by adding the H₃PO₄ and one half of the quantity of water. To this mixture the aluminum isoproxide was added. This mixture was then blended until a homogeneous mixture was observed. To this mixture the LUDOX-LS was added and the resulting mixture blended (about 2 minutes) until a homogeneous mixture was observed. Three additional mixtures were prepared using cobalt acetate, magnesium acetate and manganese acetate using one third of the remainder of the water for each mixture. The four mixtures were then admixed and the resulting mixture blended until a homogeneous mixture was observed. The organic templating agent was then added to the resulting mixture and the resulting mixture blended until a homogeneous mixture was observed, i.e., about 2 to 4 minutes. The mixture was then placed in a lined (polytetrafluoroethylene) stainless steel pressure vessel and digested at a temperature for a time. All digestions were carried out at the autogeneous pressure. The molar composition for each preparation will be given by the relative moles of the components with H₃PO₄ be given as P₂O₅. EXAMPLES 1H to 4H CoMnMgAPSO molecular sieves were prepared according to the above identified procedure and the CoMnMgAPSO products determined by X-ray analysis. The results of preparative examples 1H to 4H are set forth in Table I-H. Examples AH, BH and CH of Table I-H did not contain a product identifiable by x-ray analysis. Example 5H Portions of the products of examples 3H and 4H were calcined in air at 600°C for 1.5 hour to remove at least part of the organic templating agent. The adsorption capacities of each calcined sample were measured using a standard McBain-Baker gravimetric adsorption apparatus. The samples were activated in a vacuum (less than about 0.04 torr) at 350°C prior to measurement. The McBain-Baker data for the CoMnMgAPSO products were: (a) Example 3H: (CoMnMgAPSO-34 and CoMnMgAPSO-5): Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt.% Adsorbed Oxygen 3.46 105 -183 6.0 Oxygen 3.46 733 -183 8.4 Neopentane 6.2 742 23.8 1.4 Cyclohexane 6.0 65 23.7 2.6 n-hexane 6.0 93 23.4 3.3 H₂O 2.65 4.6 23.4 7.3 H₂O 2.65 19 23.7 12.0 (b) Example 4H: (CoMnMgAPSO-11) Adsorbate Kinetic Diameter,Å Pressure (Torr) Temp (°C) Wt.% Adsorbed Oxygen 3.46 105 -183 2.9 Oxygen 3.46 733 -183 3.6 Neopentane 6.2 742 23.8 0.5 Cyclohexane 6.0 65 23.7 2.1 H₂O 2.65 4.6 23.4 4.1 H₂O 2.65 19 23.7 9.1 Example 6H Portions of the products of examples 3H and 4H were subjected to chemical analysis. The chemical analyses were as follows: (a) Example 3H : Component Weight Percent Al₂O₃ 21.5 P₂O₅ 40.3 SiO₂ 6.5 CoO 4.58 MnO 4.41 MgO 2.43 Carbon 6.9 LOI 18.3 The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.575R: 0.061 CoO: 0.062 MnO: 0.060 MgO: 0.211 Al₂O₃: 0.284 P₂O₅: 0.108 SiO₂ and a formula (anhydrous basis) of: 0.072R(Co 0.048 Mn 0.048 Mg 0.047 Al 0.33 P 0.44 Si 0.084 )O₂ The above chemical analysis gives an overall product composition in molar oxide ratios (anhydrous basis) of: 0.128R:0.08CoO:0.096MnO:0.070MgO:0.238Al₂O₃:0.294 P₂O₅:0.141S:O₂ and a formula (anhydrous basis) of: 0.0213R(Co 0.055 Mn .066 Mg 0.048 Al 0.33 P 0.41 Si 0.097 )O₂ Example 7H EDAX (energy dispersive analysis by x-ray) microprobe analysis in conjuction with SEM (scanning electron microscope) was carried out on clean crystals of products from examples 3H and 4H. Analysis of crystals having a morphology characteristic of CoMnMgAPSO-5, CoMnMgAPSO-11, and CoMnMgAPSO-34 gave the following analysis based on relative peak heights: (a) CoMnMgAPSO-5 : Average of Spot Probes Co 0.11 Mn 0.16 Mg 0.08 Al 0.55 P 1.0 Si 0.11 (b) CoMnMgAPSO-11 : Average of Spot Probes Co 0.09 Mn 0.06 Mg 0.11 Al 0.85 P 0.99 Si 0.38 (c) CoMnMgAPSO-34 : Average of Spot Probes Co 0.05 Mn 0.03 Mg 0.05 Al 0.81 P 1.0 Si 0.20 Example 8H (a) CoMnMgAPSO-5, as prepared to in example 3H, was subjected to x-ray analysis and was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-sythesized CoMnMgAPSO-5 of part (a) was calcined in air at 600°C for one (1) hour. The calcined product was characterized by the x-ray powder diffraction pattern below: (c) The species CoMnMgAPSO-5 is a molecular sieve having a three-dimensional microporous framework structure of CoO -2 / 2 , MnO- -2 / 2 , MgO -2 / 2 , AlO - / 2, PO + / 2, and SiO₂tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co t Mn u Mg v Al x P y Si z )O₂ wherein "R" represents an organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co t Mn u Mg v Al x P y Si z )O₂ and has a value of from zero to about 0.3; and "t", "u", "v", "x", "y", and "z", where "w" is the sum of "t + u + v", represent the mole fractions of cobalt, manganese, magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides, said mole fractions being within the pentagonal compositional area defined by points A, B, C, D and E of FIG. 1, more preferably by the tetragonal compositional area defined by points a, b, c, and d of FIG. 2, and having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table II-H: 2ϑ d,(Å) Relative Intensity 7.4-7.5 11.89-11.76 w-vs 14.9-15.0 5.96-5.90 vw-m 19.7-19.9 4.50-4.47 w 21.1-21.2 4.20-4.19 w-m 22.6 3.94 vw-m 29.9-30.2 2.987-2.956 vw-m (d) The CoMnMgAPSO-5 compositions for which x-ray powder diffraction data have been obtained have patterns which are characterized by the data of Table III-H below: 2ϑ d,(Å) 100xI/Io 7.4-7.5 11.89-11.76 15-100.0 12.8-13.1 6.90-6.79 16-19 14.9-15.0 5.96-5.90 6-30 19.7-19.9 4.50-4.47 16-19 21.1-21.2 4.20-4.19 10-35 22.6 3.94 5-37 25.8-26.1 3.454-3.414 18-32 29.0-29.2 3.079-3.060 4-8 29.9-30.2 2.987-2.956 7-59 30.5 2.930 28-37 34.4-34.7 2.608-2.582 11-14 37.8 2.382 4 45.1 2.010 3 46.3 1.962 5 48.7 1.870 6 Example 9H (a) CoMnMgAPSO-11, as prepared in example 4H was subjected to x-ray analysis. CoMnMgAPSO-11 was determined to have a characteristic x-ray powder diffraction pattern which contains the d-spacings set forth below: (b) A portion of the as-sythesized of part (a) was calcined in air at 600°C for one (1) hour. The calcined product was characterized by the x-ray powder diffraction pattern of below: 2ϑ d,(Å) 100xI/Io 8.1 10.95 31 9.6 9.23 43 13.0 6.80 30 15.8 5.60 37 20.2 4.40 27 21.3 4.18 100 22.3 3.99 65 23.0 3.87 36 23.4 3.80 50 24.4 3.65 11 26.3 3.392 25 28.3 3.157 83 28.9 3.090 17 29.1 3.067 11 32.8 2.734 19 34.3 2.614 12 37.9 2.373 12 39.0 2.309 15 39.3 2.294 14 44.8 2.025 16 44.9 2.021 17 (c) The species CoMnMgAPSO-11 is a molecular sieve having three-dimensional microporous framework structures of CoO -2 / 2 , MnO -2 / 2 , MgO -2 / 2 , AlO - / 2, PO + / 2, and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR: (Co t Mn u Mg v Al x P y Si z )O₂ wherein "R" represents an organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (Co t Mn u Mg v Al x P y Si z )O₂ and has a value of from zero to about 0.3; and "t", "u", "v", "x", "y", and "z", where "w" is the sum of " t + u + v ", represent the mole fractions of cobalt, manganese, magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides, said mole fractions being within the compositional area defined by points A, B, C, D and E of FIG. 1, more preferably by the compositional area defined by points a, b, c, and d of FIG. 2, and having a characteristic x-ray powder pattern which contains at least the d-spacings set forth in Table IV-H: 2ϑ d,(Å) Relative Intensity 9.5-9.6 9.35-9.23 m 15.7-15.8 5.66-5.60 m 21.1-21.4 4.21-4.15 m-vs 22.1-22.3 4.02-3.99 m 22.7 3.92 m-vs 23.3-23.4 3.82-3.80 m 28.3-28.7 3.157-3.110 m-s (d) The CoMnMgAPSO-11 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the data of Table V-H below: 2ϑ d,(Å) 100xI/Io 8.1-8.2 10.95-10.65 17-31 9.5-9.6 9.35-9.23 34-46 13.0-13.3 6.80-6.66 9-30 15.7-15.8 5.66-5.60 22-37 20.2-20.4 4.40-4.35 27-29 21.1-21.4 4.21-4.15 75-100 22.1-22.3 4.02-3.99 34-65 22.4 3.97 27 22.7 3.92 34-100 23.0-23.2 3.87-3.83 36-53 23.3-23.4 3.82-3.80 50-70 24.4-24.7 3.65-3.61 7-11 26.3-26.5 3.392-3.363 23-25 28.3-28.7 3.157-3.110 75-83 28.9 3.090 16 29.1-30.4 3.067-2.940 11-14 32.7-32.8 2.739-2.734 13-19 34.3 2.614 12 35.2 2.548 20 37.5-37.8 2.398-2.383 8 37.9 2.373 7-12 39.0 2.309 15 39.3-40.1 2.294-2.247 12-16 44.8-45.0 2.025-2.013 11-17 45.2 2.006 18 45.3 2.001 20 45.8 1.983 13 45.9 1.977 13 50.4 1.812 10 50.6 1.803 15 Example 10H (a) CoMnMgAPSO-34, as prepared in example 3H, was subjected to x-ray analysis. CoMnMgAPSO-34 was determined to have a characteristic x-ray powder diffraction pattern which contains ao least the d-spacings set forth below: (b) A portion of the as-synthesized CoMnMgAPSO-34 of part (a) was calcined in air at 600°C for one (1) hour. The calcined product was characterized by the x-ray powder diffraction pattern below: 2ϑ d,(Å) 100xI/Io 7.5 11.76 100 9.7 9.14 86 13.1 6.79 18 15.0 5.90 30 16.3 5.44 8 18.1 4.90 7 19.9 4.47 19 21.2 4.19 35 21.5 4.13 44 22.6 3.94 37 23.0 3.87 6 26.1 3.414 21 26.4 3.379 9 29.2 3.060 8 30.2 2.956 59 31.2 2.871 12 31.7 2.819 7 34.7 2.582 13 35.5 2.528 16 (c) The species CoMnMgAPSO-34 is a molecular sieve having a three-dimensional microporous framework structure of coO -2 / 2 , MnO -2 / 2 , MgO -2 / 2 , AlO - / 2, PO + / 2, and SiO₂ tetrahedral oxide units and have an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(Co t Mn u Mg v Al x P y Si z )O₂ wherein "R" represents an organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of Co t Mn u Mg v Al x P y Si z )O₂ and has a value of from zero to about 0.3; and "t", "u", "v", "x", "y", and "z", where "w" is the sum of " t + u + v ", represent the mole fractions of cobalt, manganese, magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides, said mole fractions being within the compositional area defined by points A, B, C, D and E of FIG. 1, more preferably by the compositional area defined by points a, b, c, and d of FIG. 2, and having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table VI-H: 2ϑ d,(Å) Relative Intensity 9.5-9.7 9.31-9.14 vs 16.0-16.3 5.54-5.44 m 20.5-21.2 4.33-4.19 m-s 21.5 4.13 m 25.2 3.534 m 30.2-30.5 2.960-2.930 m (d) The CoMnMgAPSO-34 compositions for which x-ray powder diffraction data have been obtained to date have patterns which are characterized by the data of Table VII-H below: 2ϑ d,(Å) 100xI/Io 9.5-9.7 9.31-9.14 100 12.8-13.1 6.90-6.79 13-19 14.1 6.28 12-14 16.0-16.3 5.54-5.44 31-46 18.0-18.1 4.93-4.90 21-28 19.2 4.62 5-12 20.5-21.2 4.33-4.19 61-92 21.5 4.13 44 22.4 3.97 4-25 23.0-23.1 3.87-3.85 4-6 25.2 3.534 21-28 25.8-26.1 3.453-3.414 13-32 26.4 3.379 9 27.6 3.237 4 28.4 3.142 4-5 29.5 3.025 4 30.2-30.5 2.960-2.930 21-37 31.2-31.3 2.871-2.863 14-25 31.7 2.819 7 32.4 2.767 15-26 34.4 2.608 5-11 35.5 2.528 16 36.3 2.473 4-5 38.8 2.323 6 39.6 2.276 5 43.3 2.088 5 47.2-47.5 1.924-1.916 4-7 48.9 1.863 4-6 51.0 1.791 4 53.0 1.728 4 53.1 1.726 4 Example 11H The catalytic activity of the CoMnMgAPSO compositions of examples 3H and 4H were evaluated in n-butane cracking using a bench-scale apparatus. The reactor was a cylindrical quartz tube 254 mm. in length an 10.3 mm. I.D. In each test the reactor was loaded with particles of the test CoMnMgAPSO's which were 20-40 mesh (U.S. Std.) in size and in an amount of from 0.5 to 5 grams, the quantity being selected so that the conversion of n-butane was at least 5% and not more than 90% under the test conditions. The CoMnMgAPSO samples were calcined in air at 600°C for 1.5 hours to remove organic materials from the pore system, and were activated in situ in the reactor in a flowing stream of helium at 500°C for one hour. The feedstock was a helium-n-butane mixture containing 2 mole percent n-butane and was passed through the reactor at a rate of 50 cc./minute. Analysis of the feedstock and the reactor effluent were carried out using conventional gas chromatography techniques. The reactor effluent was analyzed after 10 minutes of on-stream operation. From the analytical data the pseudo-first-order rate constants (k A ) were calculated and are set forth in Table VIII-H below: Product of Ex. No.: Rate Constant (k A ) 3H 8.8 4H 0.2 PROCESS APPLICATIONS The ELAPSO compositions of the instant invention exhibit novel surface selectivity characteristics which render them useful as catalysts or catalyst bases in a number of hydrocarbon conversion and oxidative combustion reactions. They can be impregnated or otherwise loaded with catalytically active metals by methods well known in the art and used, for example, in fabricating catalyst compositions having silica or alumina bases. Of the general class, those species having pores larger than about 4Å are preferred for catalytic applications. Among the hydrocarbon conversion reactions catalyzed by ELAPSO compositions are cracking, hydrocracking, alkylation for both the aromatic and isoparaffin types, isomerization including xylene isomerization, polymerization, reforming, hydrogenation, dehydrogenation, transalkylation, dealkylation, hydrodecyclization and dehydrocyclization. Using ELAPSO catalyst compositions which contain a hydrogenation promoter such as platinum or palladium, heavy petroleum residual stocks, cyclic stocks and other hydrocrackable charge stocks, can be hydrocracked at temperatures in the range of 205 °C to 440 °C (400°F to 825°F) using molar ratios of hydrogen to hydrocarbon in the range of between 2 and 80, pressures between 69 kPa to 24.1 MPa (10 and 3500 p.s.i.g.), and a liquid hourly space velocity (LHSV) of from 0.1 to 20, preferably 1.0 to 10. The ELAPSO catalyst compositions employed in hydrocracking are also suitable for use in reforming processes in which the hydrocarbon feedstocks contact the catalyst at temperatures of from about 370 to 540 °C (700°F to 1000°F), hydrogen pressures of from 100 to 500 p.s.i.g. (1 p.s.i.g. = 6.895 kPa), LHSV values in the range of 0.1 to 10 and hydrogen to hydrocarbon molar ratios in the range of 1 to 20, preferably between 4 and 12. These same catalysts, i.e. those containing hydrogenation promoters, are also useful in hydroisomerizations processes in which feedstocks such as normal paraffins are converted to saturated branched chain isomers. Hydroisomerization is carried out at a temperature of from about 93.5 to 315 °C (200°F to 600°F), preferably 150 to 288 °C (300°F to 550°F) with an LHSV value of from about 0.2 to 1.0. Hydrogen (H) is supplied to the reactor in admixture with the hydrocarbon (Hc) feedstock in molar proportions (H/Hc) of between 1 and 5. At somewhat higher temperatures, i.e. from about 343 to 540 °C (650°F to 1000°F), preferably 455 to 510 °C (850°F to 950°F) and usually at somewhat lower pressures within the range of about 15 to 50 p.s.i.g., the same catalyst compositions are used to hydroisomerize normal paraffins. Preferably the paraffin feedstock comprises normal paraffins having a carbon number range of C₇-C₂₀. Contact time between the feedstock and the catalyst is generally relatively short to avoid undesireable side reactions such as olefin polymerization and paraffin cracking. LHSV values in the range of 0.1 to 10, preferably 1.0 to 6.0 are suitable. The unique crystal structures of the present ELAPSO catalysts and their availability in a form having very low alkali metal content favor their use in the conversion of alkylaromatic compounds, particularly the catalytic disproportionation of toluene, ethylene, trimethyl benzenes, tetramethyl benzenes and the like. In the disproportionation process, isomerization and transalkylation can also occur. Group VIII noble metal adjuvants alone or in conjunction with Group VI-B metals such as tungsten, molybdenum and chromium are preferably included in the catalyst composition in amounts of from about 3 to 15 weight-% of the overall composition. Extraneous hydrogen can, but need not, be present in the reaction zone which is maintained at a temperature of from about 204 to 399 °C (400 to 750°F), pressures in the range of 100 to 2000 p.s.i.g. and LHSV values in the range of 0.1 to 15. Catalytic cracking processes are preferably carried out with ELAPSO compositions using feedstocks such as gas oils, heavy naphthas, deasphalted crude oil residua, etc., with gasoline being the principal desired product. Temperature conditions of 455 to 593 °C (850 to 1100°F), LHSV values of 0.5 to 10 and pressure conditions of from about 0 to 50 p.s.i.g. are suitable. Dehydrocyclization reactions employing paraffinic hydrocarbon feedstocks, preferably normal paraffins having more than 6 carbon atoms, to form benzene, xylenes, toluene and the like are carried out using essentially the same reaction conditions as for catalytic cracking. For these reactions it is preferred to use the ELAPSO catalyst in conjunction with a Group VIII non-noble metal cation such as cobalt and nickel. In catalytic dealkylation wherein it is desired to cleave paraffinic side chains from aromatic nuclei without substantially hydrogenating the ring structure, relatively high temperatures in the range of about 427 to 538 °C (800°-1000°F) are employed at moderate hydrogen pressures of about 300-1000 p.s.i.g., other conditions being similar to those described above for catalytic hydrocracking. Preferred catalysts are of the same type described above in connection with catalytic dehydrocyclization. Particularly desirable dealkylation reactions contemplated herein include the conversion of methylnaphthalene to naphthalene and toluene and/or xylenes to benzene. In catalytic hydrofining, the primary objective is to promote the selective hydrodecomposition of organic sulfur and/or nitrogen compounds in the feed, without substantially affecting hydrocarbon molecules therein. For this purpose it is preferred to employ the same general conditions described above for catalytic hydrocracking, and catalysts of the same general nature described in connection with dehydrocyclization operations. Feedstocks include gasoline fractions, kerosenes, jet fuel fractions, diesel fractions, light and heavy gas oils, deasphalted crude oil residua and the like any of which may contain up to about 5 weight-percent of sulfur and up to about 3 weight-percent of nitrogen. Similar conditions can be employed to effect hydrofining, i.e., denitrogenation and desulfurization, of hydrocarbon feeds containing substantial proportions of organonitrogen and organosulfur compounds. It is generally recognized that the presence of substantial amounts of such constituents markedly inhibits the activity of hydrocracking catalysts. Consequently, it is necessary to operate at more extreme conditions when it is desired to obtain the same degree of hydrocracking conversion per pass on a relatively nitrogenous feed than are required with a feed containing less organonitrogen compounds. Consequently, the conditions under which denitrogenation, desulfurization and/or hydrocracking can be most expeditiously accomplished in any given situation are necessarily determined in view of the characteristics of the feedstocks in particular the concentration of organonitrogen compounds in the feedstock. As a result of the effect of organonitrogen compounds on the hydrocracking activity of these compositions it is not at all unlikely that the conditions most suitable for denitrogenation of a given feedstock having a relatively high organonitrogen content with minimal hydrocracking, e.g., less than 20 volume percent of fresh feed per pass, might be the same as those preferred for hydrocracking another feedstock having a lower concentration of hydrocracking inhibiting constituents e.g., organonitrogen compounds. Consequently, it has become the practice in this art to establish the conditions under which a certain feed is to be contacted on the basis of preliminary screening tests with the specific catalyst and feedstock. Isomerization reactions are carried out under conditions similar to those described above for reforming, using somewhat more acidic catalysts. Olefins are preferably isomerized at temperatures of 260 to 482 °C (500°-900°F), while paraffins naphthenes and alkyl aromatics are isomerized at temperatures of 371 to 482 °C (700°-1000°F). Particularly desirable isomerization reactions contemplated herein include the conversion of n-heptene and/or n-octane to isoheptanes, iso-octanes, butane to iso-butane, methylcyclopentane to cyclohexane, meta-xylene and/or ortho-xylene to paraxylene, 1-butene to 2-butene and/or isobutene, n-hexene to isohexene, cyclohexene to methylcyclopentene etc. The preferred form of the catalyst is a combination of the ELAPSO with polyvalent metal compounds (such as sulfides) of metals of Group II-A, Group II-B and rare earth metals. For alkylation and dealkylation processes the ELAPSO compositions having pores of at least 5Å are preferred. When employed for dealkylation of alkyl aromatics, the temperature is usually at least 350°F and ranges up to a temperature at which substantial cracking of the feedstock or conversion products occurs, generally up to about 371 °C (700°F). The temperature is preferably at least 232 °C (450°F) and not greater than the critical temperature of the compound undergoing dealkylation. Pressure conditions are applied to retain at least the aromatic feed in the liquid state. For alkylation the temperature can be as low as 121 °C (250°F) but is preferably at least 177 °C (350°F). In the alkylation of benzene, toluene and xylene, the preferred alkylating agents are olefins such as ethylene and propylene.

Claims: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO₂, AlO₂, PO₂, SiO₂ oxide units and having an empirical chemical composition on an anhydrous basis expressed by the formula: mR:(EL w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL w Al x P y Si z )O₂ and has a value of from zero to 0.3; "EL" represents at least one element capable of forming a three dimensional oxide framework, "EL" is characterized as an element having a mean "T-O" distance in tetrahedral oxide structures between 0.151 nm and 0.206 nm (1.51 Angstroms and 2.06 Angstroms), "EL" has a cation electronegativity between 523 kJ/g-atom and 1297 kJ/g-atom (125 kcal/g-atom to 310 kcal/g-atom) and "EL" is capable of forming stable M-O-P, M-O-Al or M-O-M bonds in crystalline three dimensional oxide structures having a "M-O" bond dissociation energy greater than 246.9 kJ/mole (59 kcal/mole) at 298°K; and "w", "x", "y" and "z" represent the mole fractions of "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides said mole fractions being within the pentagonal compositional area defined by points A, B, C, D, and E of FIG. 1. Crystalline molecular sieves of claim 1 having three-dimensional microporous framework structures of ELO₂, AlO₂, SiO₂ and PO₂ tetrahedral oxide units and having an empirical chemical composition on an anhydrous basis expressed by the formula: mR : (EL w Al x P y Si z )O₂ wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL w Al x P y Si z )O₂ and has a value of from zero to 0.3; "EL" represents at least one element capable of forming a framework tetrahedral oxide and is selected from the group consisting of arsenic, beryllium, boron, chromium, cobalt, gallium, germanium, iron, lithium, magnesium, manganese, titanium, vanadium and zinc; and "w", "x", "y" and "z" represent the mole fractions of "EL", aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides said mole fractions being within the pentagonal compositional area defined by points A, B, C, D and E of FIG.1. The crystalline molecular sieves according to claim 1 wherein the mole fractions "w", "x", "y" and "z" are within the tetragonal compositional area defined by points a, b, c and d of FIG. 2. The crystalline molecular sieves of claim 1 or claim 2 wherein element "EL" is further characterized as having an electronic orbital configuration selected from the group consisting of d⁰, d¹, d², d⁵, d⁶, d⁷ and d¹⁰, where the small field crystal stabilization energy of the ligand "-OM", where "M" denominates element(s) "EL", favors tetrahedral coordination of element "EL" with O²⁻. The crystalline molecular sieves of claim 1 or 2 wherein "EL" is an element capable of forming stable oxo or hydroxo species in aqueous solution as evidenced by a first hydrolysis constant, K₁₁, greater than 10⁻¹⁴. The crystalline molecular sieves of claim 1 or claim 2 wherein element "EL" is known to occur in crystal structure types geometrically related to the different silicon modifications, quartz, cristobalite and tridymite. The crystalline molecular sieves of claim 1 or claim 2 wherein element "EL" in its cation form is classified by Pearson as "hard" or "borderline" acids which interact with the "hard" base O²⁻ to form more stable bonds than the cations classified as "soft" acids. The crystalline molecular sieves according to claim 2 wherein the mole fractions "w", "x", "y" and "z" are within the tetragonal conpositional area defined by points a, b, c and d of FIG. 2. The crystalline molecular sieves according to claim 2 wherein "EL" is at least 2 elements. The crystalline molecular sieves according to claim 2 wherein "EL" is at least 3 elements. The crystalline molecular sieves according to claim 2 wherein "EL" is at least 4 elements. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table A. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table B. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table C. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table D. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table E. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table F. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder. diffraction pattern which contains at least the d-spacings set forth in Table G. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table H. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table J. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table K. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffractions pattern which contains at least the d-spacings set forth in Table L. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table M. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table N. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table O. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table P. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table Q. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table R. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table S. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table T. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table U. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table V. The crystalline molecular sieves of claims 1 or 2 having a characteristic x-ray powder diffraction pattern which contains at least the d-spacings set forth in Table W. Crystalline molecular sieves according to claim 9, claim 10 or claim 11 wherein element "EL" is selected from the group consisting of beryllium, cobalt, gallium, iron, magnesium, manganese, titanium and zinc. Process for preparing crystalline molecular sieves having three-dimensional microporous framework structures which comprises providing at an effective temperature and for an effective time a reaction mixture composition expressed in terms of molar oxide ratios as follows: aR : (EL w Al x P y Si z ) : bH₂O wherein "R" is at least one organic templating agent: "a" is the amount of "R" and is zero or an effective amount greater than zero to 6; "b" has a value of from zero to 500, "EL" represents at least one element capable of forming a three-dimensional oxide, "EL" is characterized as an element having a mean "T-O" distance in tetrahedral oxide structures between 0.151 nm to 0.206 nm (1.51 Angstroms and 2.06 Angstroms), "EL" has a cation electronegativity between 523 to 1297 kJ/g-atom (125 kcal/g-atom to 310 kcal/g-atom) and "EL" is capable of forming M-O-P, M-O-Al or M-O-M bonds in crystalline three dimensional oxide structures having a "M-O" bond dissociation energy greater than 246.9 kJ/mole (59 kcal/mole) at 298°K; and "w", "x", "y" and "z" represent mole fractions, respectively, of "EL", aluminum and phosphorus and silicon in the (EL w Al x P y Si z )O₂ constituent, and each has a value of at least 0.01, whereby the molecular sieves of claim 1 or claim 2 are prepared. Process of claim 30 wherein "a" is an effective amount greater than zero to 6. Process according to claim 35 wherein the source of phosphorus in the reaction mixture is orthophosphoric acid. Process according to claim 35 wherein the source of phosphorus in the reaction mixture is orthophosphoric acid and the source of aluminum is at least one compound selected from the group of pseudo-boehmite and aluminum alkoxide. Process according to claim 38 wherein the aluminum alkoxide is aluminum isopropoxide. Process according to claim 35 wherein the source of silicon is silica. Process according to claim 35 wherein the source of "EL" is selected from the group consisting of oxides, hydroxides, alkoxides, nitrates, halides, sulfates, carboxylates, organometallic compounds and mixtures thereof. Process according to claim 35 wherein the organic templating agent is a quaternary ammonium or quaternary phosphonium compound having the formula R₄X⁺ wherein X is nitrogen or phosphorus and each R is an alkyl or aryl group containing from 1 to 8 carbon atoms. Process according to claim 35 wherein the organic templating agent is an amine. Process according to claim 35 wherein the templating agent is selected from the group consisting of: tetrapropylammonium ion; tetraethylammonium ion; tripropylamine; triethylamine; triethanolamine; piperidine; cyclohexylamine; 2-methyl pyridine; N,N-dimethylbenzylamine; N,N-dimethylethanolamine; choline; N,N-dimethylpiperazine; 1,4-diazabicyclo-(2,2,2) octane; N-methyldiethanolamine; N-methylethanolamine; N-methylpiperidine; 3-methylpiperidine; N-methylcyclohexylamine; 3-methylpyridine; 4-methylpyridine; quinuclidine; N,N'-dimethyl-1,4-diazabicyclo (2,2,2) octane ion; tetramethylammonium ion; tetrabutylammonium ion; tetrapentylammonium ion; di-n-butylamine; neopentylamine; di-n-pentylamine; isopropylamine; t-butylamine; ethylenediamine; pyrrolidine; 2-imidazolidone; di-n-propylamine; and a polymeric quaternary ammonium salt [(C₁₄H₃₂N₂)(OH)₂] x wherein x is a value of at least 2. Crystalline molecular sieves prepared by calcining the compositions of claim 1 or claim 2, at a temperature sufficiently high to remove at least some of any organic templating agent present in the intracrystalline pore system. Process for separating molecular species from admixture with molecular species having a lesser degree of polarity which comprises contacting said mixture of molecular species with a molecular sieve of claim 1 or claim 2 having pore diameters large enough to adsorb at least one of the more polar molecular species, said molecular sieve being at least partially activated whereby molecules of the more polar molecular species are selectively adsorbed into the intracrystalline pore system thereof. Process for separating a mixture of molecular species having different kinetic diameters which comprises contacting said mixture with a molecular sieve of claim 1 or claim 2 having pore diameters large enough to adsorb at least one but not all molecular species of said mixture, said molecular sieve being at least partially activated whereby at least some molecules whose kinetic diameters are sufficiently small can enter the intracrystalline pore system thereof. Process according to claim 46 wherein the more polar molecular species is water. Process for converting a hydrocarbon which comprises contacting said hydrocarbon under hydrocarbon converting conditions with a molecular sieve of claim 1 or claim 2. Process according to claim 49 wherein the hydrocarbon conversion process is cracking. Process according to claim 49 wherein the hydrocarbon conversion process is hydrocracking. Process according to claim 49 wherein the hydrocarbon conversion process is hydrogenation. Process according to claim 49 wherein the hydrocarbon conversion process is polymerization. Process according to claim 49 wherein the hydrocarbon conversion process is alkylation. Process according to claim 49 wherein the hydrocarbon conversion process is reforming. Process according to claim 49 wherein the hydrocarbon conversion process is hydrotreating. Process according to claim 49 wherein the hydrocarbon conversion process is isomerization. Process according to claim 57 wherein the isomerization conversion process is xylene isomerization. Process according to claim 49 wherein the hydrocarbon conversion process is dehydrocyclization. The crystalline molecular sieve according to claim 1 wherein "EL" represents arsenic. The crystalline molecular sieve according to claim 1 wherein "EL" represents beryllium. The crystalline molecular sieve according to claim 1 wherein "EL" represents boron. The crystalline molecular sieve according to claim 1 wherein "EL" represents chromium. The crystalline molecular sieve according to claim 1 wherein "EL" represents gallium. The crystalline molecular sieve according to claim 1 wherein "EL" represents germanium. The crystalline molecular sieve according to claim 1 wherein "EL" represents lithium. The crystalline molecular sieve according to claim 1 wherein "EL" represents vanadium.

Inventors: FLANIGEN, EDITH MARIE, LOK, BRENT MEI TAK, MARCUS, BONITA KRISTOFFERSEN, PATTON, ROBERT LYLE, VAIL, LAWRENCE DAVID, WILSON, STEPHEN THOMAS
Applicants: UOP
Application year: 1985
Main classification: C01B33
IPC codes: C01B37, C07C2, C07C4, C07C5, B01J29