SILANE ACETOACETARYLIDE DYES, COMPOSITE PIGMENTS OBTAINABLE THEREFROM, AND PROCESSES FOR PREPARING THE SAME

Abstract: There are described silane acetoacetarylide dyes, com­ posite pigments obtainable therefrom by grafting onto an inorganic substrate or support, and processes for preparing the same. The dyes have the general formula: wherein R, R₁ and R₂, which may be the same or different from one another, are a hydrogen atom, an alkyl or an alkoxyl group having up to 4 carbon atoms, a halogen, a nitro group, an acetyl(-COCH₃) group, or a carbamoyl (-CONH₂) group; n is 3, 4 or 5: q is 0 or 1; p and m are integers such that, when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R₃ is an alkyl group having up to 4 carbon atoms or a phenyl group; and R₄ is an alkoxy group having up to 4 carbon atoms. The composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastics and in printing inks.

Description: "SILANE ACETOACETARYLIDE DYES, COMPOSITE PIGMENTS OBTAINABLE THEREFROM, AND PROCESSES FOR PREPARING THE SAME" This invention relates to acetoacetarylide dyes containing, in chemical combination, a silane group. to the corresponding composite pigments obtainable therefrom by association with an inorganic solid substrate or support, and to processes for preparing such silane acetoacetarylide dyes and corresponding composite pigments. Whenever used in the following description, the term "composite pigment" means a pigmentary material comprising an acetoacetarylide dye containing a silane group. associated with an inorganic solid substrate or support. The association of the acetoacetarylide dye containing a silane group. or, briefly, silane acetoacetarylide dye. with the solid substrate or support, imparts a pigmentary nature to the dye itself. Such association is obtained by formation of chemical bonds (grafting) between the silane portion of the dye and the inorganic substrate or support. An aim of the present invention is to provide silane acetoacetarylide dyes, insoluble in water, capable of providing composite pigments having high pigmentary properties. Further aims of the invention are the preparation of the abovesaid dyes and pigments by means of simple and economic methods. The present invention in one aspect provides acetoacetarylide dyes containing a silane group of formula: EMI2.1 in which R, Rland R2, which may be the same as or different from one another. represent as hydrogen atom, an alkyl or an alkoxy group having up to 4 carbon atoms, a halogen, a nitro group. an acetyl (-COCH3) group, or a carbamoyl (-CONH2) group; n is 3, 4 or 5; q is 0 or 1; p and m are integers such that, when q is 0. p is 3 and m is 0. 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R3 is an alkyl group having up to 4 carbon atoms or a phenyl group; and R4 is an alkoxyl group having up to 4 carbon atoms. Such compounds according to the invention may be prepared. according to another aspect of the invention. by a process comprising reacting a silane compound of formula: EMI3.1 wherein n. R3, R4, q, m and p are as defined above, with the chloride of an acetoacetarylide sulphonic derivative of formula: EMI3.2 in which R, R1 and R2 are as defined above, in a substantially stoichiometric molar ratio of the silane (II) to the chloride (III), in a reaction medium comprising an organic solvent, at a temperature from 20 to 1000C, for 1 to 6 hours. The reaction may be optionally conducted in the presence of a hydrochloric acid-acceptor compound1 such as Na2CO3, NaHCO3, triethylamine or pyridine. As organic solvents there may be used. for example, xylene. toluene, chloro-, dichloro- and trichlorobenzenes, nitrobenzene and dioxane. The chlorides of formula (III) are preparable according to conventional methods1 for example by treating the corresponding sulphonic acetoacetarylide derivatives with an excess of PCl5 and POCl3 at temperatures of from 2 to 200C for 2-12 hours. The acetoacetarylide sulphonic derivatives are known products and can be prepared by means of diazo-coupling (diazo-copulation) of 3-nitro-4-aminobenzenesulphonic acid with known acetoacetarylide coupling (copulation) compounds of formula: EMI4.1 in which R, R and R2 are as defined above, for example acetoacetanilide, 2'-methyl-acetoacetanilide, 4'-chloro-acetoacetanilide, 2'-methoxy-acetoacetanilide, 22. 5'-dimethoxy-4µ-chloro-acetoacetanilide and 2'-methyl-4'-chloro-acetoacetanilide. As silane compounds of formula (II), those derived from amino-alkoxy-silanes, such as, for example, y-amino-propyl-triethoxysilane, 6-aminobutyl-phenyl-diethoxysilane, -aminopropyl-methyl-diethoxysilane and 6-amino-butyl-triethoxysilane have proved to be particularly suitable. Such amino-alkoxy-silanes are known compounds which are commercially available. However, they can be prepared, according to conventional tchniques, for example by reaction of the corresponding chloro-alkoxy-silanes with aliphatic amines. The silane acetoacetarylide dyes of formula (I) possess a fairly good solubility in organic solvents and do not possess, in themselves, pigmentary characteristics, although they exhibit a good tinting strength, bright shades from yellow-green to reddish-yellow and a good photostability. The silane acetoacetarylide dyes of formula (I) contain in their molecule silanolic groups and/or alkoxyl groups hydrolyzable to silanolic groups -Si(OH)3; are capable of both self-condensing, by reaction between the silanolic groups mentioned above, and chemically reacting with the surface hydroxyl groups of suitable inorganic substrates or supports, which condense with those of the dyes, with formation of stable chemical bonds (grafting) between the dye and the substrate, giving rise to a composite product having pigmentary characteristics. The abovesaid dyes are therefore preferably used in the preparation of composite pigments, according to a further aspect of the invention, comprising silane acetoacetarylide dyes of formula (I) grafted onto an inorganic substrate or support. Particularly suitable for being utilized in the preparation of composite pigments are the silane acetoacetarylide dyes of formula: EMI6.1 in which R,Rl, R2, R4 and m are as defined above. Inorganic substrates or supports particularly suited to obtain the pigmentary nature of the silane acetoacetarylide dyes of formula (I) are the following: TiO2, in its forms as gel, in the semicrystalline form, in the form of rutile or anatase TiO2, also of the commercial type, in which there may be present surface coatings comprising mixtures of one or more oxides selected from amongst SiO2, Al2O3, Tit ; furthermore there may be used physical (mechanical) mixtures of TiO with SiO2 and/or Al2O3, as well 2 as 5iO2 and/or Al203. The substrates or supports 2 are finely particulated. Owing to their superior characteristics, there are preferably employed mixed substrates of TiO2, SiO2 and/or Al 203 obtained by precipitation of SiO2 and/or Al2O3, also as alumino-silicates, onto particles of crystalline Tio2, according to conventional methods. In relation to the desired uses, hiding degree or power or tinting strength, the above-mentioned substrates or supports may be employed also in admixtures with one another. The specific surface area of such substrates or supports may vary over a wide range, from 5 to 500 m2/g. preferably from 10 to 200 m2/g. Composite pigments containing from 10 to 50% by weight of silane acetoacetarylide dye of formula (I) in the grafted form are particularly preferred due to their superior characteristics. According to a yet further aspect of the invention, a process for preparing the composite pigments comprising the silane acetoacetarylide dyes (I) grafted on the inorganic substrates or supports comprises reacting the selected substrate or support with the silane dye (I) in an inert organic solvent, at a temperature from 200C to the reflux temperature of the solvent, and separating the resulting product by filtration, and washing and drying it. The reaction is usually accomplished in a time of 2-12 hours, more preferably 4-8 hours, depending on the reaction temperature. Particularly advantageous results are obtained if the composite pigment, separated by filtration, is subjected to a dry heat-treatment in an oven for 4-8 hours at 60-1100C prior to washing. which washing is carried out in order to remove the ungrafted silane dye. To improve the condensation of the dye coating on the substrate or support it is possible to operate in the presence of catalysts such as LiOH, CF3COOH, lead acetate, and cobalt naphthenate. Further advantages are obtainable if the abovesaid process is carried out in the presence of a compound selected from tetra-alkoxy-silanes having up to 4 carbon atoms in each alkoxy group. such as Si (OCH3)4, or vinyl-triethoxy-silane H2C - CH-Si-(OC2H5)3, or alkyl-ortho-titanates, such as Ti(OC4Hg)4, in an amount ranging approximately from 0.1:1 to 1:1 by weight in respect of the dye of formula (I), with which they form insoluble copolymers, which are particularly suitable for coating the substrate. As inert organic solvents. it is possible to use, for example, benzene, toluene, xylenes, nitrobenzene, chloro-benzenes, dioxane, dimethylformamide and acetonitrile. The preparation process of the invention is particularly suitable for obtaining intensely coloured pigments having a high tinting strength, even in the presence of inorganic substrates or supports having a low specific surface area, such as for example highly hiding TiO2. The composite pigments of the present invention may have a composition varying over a wide range, depending on the nature, granulometry and specific surface area of the substrate particles and in relation to the tinting strength desired for the pigment. Granulometric analysis of a composite pigment according to the invention shows that the organic portion is essentially distributed on the surface of the inorganic substrate particles. X-ray diffractometric analysis reveals that the composite pigment particles exhibit crystallinity which is characteristic of the substrate, while the grafted acetoacetarylide coating is of an amorphous nature. The acetoacetarylide pigments of the present invention, due to their composite nature achieved by chemical bonds between the organic silane component and the inorganic component. neither give rise to crystallization phenomena, nor change their crystalline form when in contact with aromatic solvents. even under hot conditions. Furthermore, pigmentary compositions based on solvents, such as those used for the printing inks, do not cause sedimentation phenomena, not even after prolonged storing. The abovesaid pigments exhibit excellent pigmentary characteristics, are insoluble in common organic and aqueous solvents, exhibit excellent stability to migration in polyvinyl chloride (PVC), to over-painting in stove alkyl enamel and to acid or alkaline treatments. Such pigments possess a good photostability and a good tinting strength, and are stable to heat both when obtained in the transparent form and at increasing hiding degrees. Therefore they are conveniently employed in painting products. for air and stove enamels, in the pigmentation of plastics such as PVC, polystyrene, polyethyleneterephthalate, etc., and in printing inks, according to conventional applicative techniques. The mechanical and/or thermal treatments employed in the above-mentioned conventional techniques do not substantially modify the pigmentary characteristics of the composite pigments of the present invention. The composite pigments exhibit the substantial advantage of being composed of an inorganic support or substrate, which is inexpensive and is capable of imparting excellent pigmentary properties, in particular the desired hiding degree and an excellent resistance to solvents, on which substrate a silane acetoacetarylide dye, characterized by a good photostability, high tinting strength and shade purity, is grafted. In general, the composite pigments according to the invention may be suitably used for colouring paints, air and stove enamels, printing inks, and plastics materials. The invention will be further described with reference to the following illustrative examples. In the examples, all parts and percentages, unless otherwise specified, are by weight. EXAMPLE 1 10 parts of an acetoacetarylide sulphonic derivative of formula: EMI12.1 were reacted with 11.35 parts of PCl5 in 110 parts of POC13, at a temperature below 50C for 2 hours and successively for 12 hours at room temperature. 30 parts of dichlorobenzene were added; the chloride of the sulphonic derivative obtained was filtered, washed with dichlorobenzene. and then with xylene and petroleum ether. 4.38 parts of the chloride thus obtained were reacted in 80 parts of xylene with 2.33 parts of y-aminopropyltriethoxysilane and with 1 part of triethylamine. for 12 hours at room temperature and for 2 hours at 900C. After filtering at ambient temperature, hot washing with 50 parts of a mixture of water and ammonium hydrate (3;1) and successively with water and final drying, an intensely yellow coloured powder was obtained. which. on analysis, gave the following results: C = 45 %; H = 4.8 t; N = 12.8 t; Si = 5 %. Elemental analysis and the I.R. spectroscopic analysis revealed that the powder corresponded to the silane dye of formula: EMI13.1 This dye may be present in part also in an oligomeric form, through the formation of siloxane bonds I I -Si-O-Si-between the silanol functions -Si (OH) I 1 3 present in the molecule. EXAMPLE 2 A silane acetoacetarylide composite pigment was prepared by using a mixed inorganic substrate of TiO2. SiO2 and A1203, prepared as follows: 100 parts of TiO2 were dispersed, under mechanical stirring, in 1 liter of water and the resulting dispersion was then heated to 600C. After a 15-minute stirring, 210 ml of a sodium silicate solution (titre: 365.47 parts/l of Sio2) were added and successively there were added, in about 3 hours, about 200 ml of a solution of aluminium sulphate (titre: 60 parts/l of Al203). The addition was stopped when the slurry pH reached a value of 6. The slurry was stirred for 1 hour, then the product was filtered, washed with water in order to remove the soluble salts, and finally dried at a temperature of 700C. The dry product was crushed and then ground in an automatic mortar. A white powder having the following composition was obtained: TiO2=43.4%;SiO2= 35.1%;Al2O3=7.15%;H2O=14.53%, and having a specific surface area, determined by a "Sorptometer", of 120 m2/g. an effective specific gravity of 2.74 g/ml, an apparent specific gravity of 0.69 g/cc, a percentage porosity of 7.45 and a total porosity of 1.06 ml/g. The silane acetoacetarylide composite pigment was prepared by introducing 1 part of the dye obtained in example 1 and 2 parts of the substrate obtained as described hereinabove, into a reactor containing 20 ml of dimethylformamide (DMF), 20 ml of xylene and 0.5 parts of aqueous HC1 (1:3). The reaction mixture was heated to reflux temperature for 6 hours. Successively it was evaporated to 1/3 of the volume, was replenished with xylene and was further refluxed for 2 hours. After cooling to ambient temperature, the reaction mixture was filtered, and the resulting cake was washed with n-heptane and treated in an oven at llO"C overnight. After hot washing with a mixture of 50% DMF/xylene and drying, there was obtained a composite pigment consisting of an intensely yellow-green coloured powder, which, on analysis, was found to be composed of 71% of inorganic ashes. This powder proved to be particularly stable to treatment, even under hot conditions, with organic solvents or with water. In applications in stove alkyd enamel and in polyvinyl chloride, it yielded yellow-coloured products with a green shade, having a good tinting strength. an excellent hiding power, and an excellent stability to overpainting, to migration and to sunlight, when present in mass or diluted with TiO2. The powdered composite pigment was found. on X-ray diffractometric analysis, under CuK a 1.5418 radiation, to consist of particles having the crystallinity typical of TiO2 rutile, while no crystalline band of SiO2, of A1203 and of the acetoacetarylide coating was visible, which1 therefore, proved to be amorphous. EXAMPLE 3 0.8 parts of the dye obtained in example 1 were introduced into a reactor with 70 parts of water and 4.2 ml of sodium silicate solution (titre in SiO2: 365.47 parts/l). The suspension was heated to 600C and, under stirring, it was additioned, in 3 hours, with 4 ml of an aluminium sulphate solution (titre in Al 203 : 60 parts/l), maintained at 600C for 1 hour and then cooled down to ambient temperature. After filtration, the resulting cake was washed with water to neutral pH, was dried in an oven at 1100c overnight, then repeatedly washed with hot water and finally dried. A yellow powder with green shades was obtained which, on analysis, was found to be composed of 70% of inorganic ashes. The composite pigment, on X-ray analysis, was found to consist of amorphous particles. The powder. in applications in stove enamel and in polyvinylchloride, provided perfectly transparent yellow products. having excellent stability and photostability. EXAMPLES 4-15 By reacting y-aminopropyl-triethoxysilane with various chlorides of acetoacetarylide sulphonic derivatives, according to the manner described in example 1. there were prepared 12 silane acetoacetarylide dyes having the formula: EMI17.1 in which. for each dye. the meanings and the bond position of substituents R, R1 and R2, when they were other than hydrogen, are indicated in Table 1. By successively reacting. according to the manner of examples 2 and 3, the silane dyes with the various inorganic substrates indicated in Table 1, 12 yellow pigments. both transparent and hiding, having excellent pigmentary characteristics, were obtained. TABLE 1 EMI18.1 <tb> <SEP> Dyes <tb> Examples <SEP> Substrates <tb> <SEP> of <SEP> formula <SEP> (VI) <tb> R <SEP> R1 <SEP> R2 <tb> <SEP> 4 <SEP> - <SEP> - <SEP> - <SEP> TiO2 <SEP> - <SEP> SiO2 <SEP> - <SEP> Al2O3 <tb> <SEP> 5 <SEP> - <SEP> - <SEP> - <SEP> SiO2 <SEP> - <SEP> Al2O3 <tb> <SEP> 6 <SEP> 2-OCH3 <SEP> - <SEP> - <SEP> SiO2 <SEP> - <SEP> Al2O3 <tb> <SEP> 7 <SEP> 2-OCH3 <SEP> - <SEP> - <SEP> TiO2 <SEP> - <SEP> SiO2 <tb> <SEP> 8 <SEP> 2-Cl <SEP> - <SEP> - <SEP> TiO2 <SEP> - <SEP> SiO2 <tb> <SEP> 9 <SEP> 2-Cl <SEP> - <SEP> - <SEP> SiO2 <tb> <SEP> 10 <SEP> 4-Cl <SEP> - <SEP> - <SEP> SiO2 <tb> <SEP> 11 <SEP> 2-OCH3 <SEP> 5-OCH3 <SEP> 4-Cl <SEP> TiO2 <SEP> - <SEP> SiO2 <SEP> - <SEP> Al2O3 <tb> <SEP> 12 <SEP> 2-OCH3 <SEP> 5-OCH3 <SEP> 4-Cl <SEP> SiO2 <SEP> - <SEP> Al2O3 <tb> <SEP> 13 <SEP> 2-OCH3 <SEP> 4-OCH3 <SEP> - <SEP> SiO2 <tb> <SEP> 14 <SEP> 4-CONH2 <SEP> - <SEP> - <SEP> SiO2 <tb> <SEP> 15 <SEP> 2-CH3 <SEP> 4-Cl <SEP> - <SEP> SiO2 <tb> EXAMPLE 16 (Application in PVC) In a rotary-arm mixer there were mixed, at 70"C: 1.0 part of the pigment obtained according to example 2 and previously ground. 100 parts of polyvinyl chloride (PVC) in powder form, 1.5 parts of calcium stearate for exerting a complexing and a stabilizing action, 3.0 parts of epoxydized soybean oil. 0.5 parts of lubricant (a mixture of glycerides from C16 to C36)' 2.0 parts of Tit2. The resulting mixture was then treated at 1800C in a three-cylinder refiner until there was obtained complete dispersion of the pigment in order to obtain a sheet exhibiting a brilliant, highly hiding yellow-green colour, having a good shade intensity, a good stability to sunlight, a good tinting strength, a good stability to heat and an excellent stability to migration. EXAMPLE 17(Application in enamels) 5.0 parts of the pigment obtained according to example 2 were mixed by grinding with 95.0 parts of a fluid carrier having the following composition: 22% of alkyd resin. 19% of melamine resin, 59% of xylene. Homogenizing was carried out in a ball mill by grinding the mixture in the presence of porcelain balls of 10 mm diameter, for a 24-hour period. The resulting enamel was applied onto a surface to be painted, and was allowed to dry overnight, whereafter it was kept in an oven at 1200-1250C for 30 minutes. A brilliant yellow-green painting having excellent hiding power, stability to sunlight and to over-painting, and with a good tinting strength was obtained. With a view to obtaining a paint exhibiting a lighter shade and having a higher hiding power, 1 part of an enamel obtained as described hereinbefore was further diluted with 9 parts of a stove synthetic white enamel (10% of TiO2) having the following composition: 30% of alkyd resin, 27% of melamine resin, 33% of xylene, 10% of TiO2. Homogenizing was accomplished in a ball mill by grinding the mixture in the presence of porcelain balls of 10 mm diameter, for a 24-hour period. The resulting cut enamel was applied onto the surface to be painted, was allowed to dry overnight and then kept in an oven at 120-125QC for 30 minutes. A light yellow-green paint having excellent general stabilities and a high hiding power was thus obtained. EXAMPLE 18 (Application in polystyrene) 0.04 g of the pigment obtained according to example 2 and previously ground were added to 100 g of polystyrene (EDISTIR NA. a Montedison registered trade-mark) previously dried and then calendered at 1600C for 5 minutes. The dyed material was cut and successively crushed in a gear apparatus. To evaluate the shade. tinting strength and thermostability. mouldings were carried out in a CARVER press at 2000C and at 2600C. Thus, a moulded article exhibiting a hiding yellow shade. characterized by a good thermostability and a good photostability, was obtained.

Claims: CLAIMS: 1. An acetoacetarylide dye containing a silane group. characterized by having the formula: EMI22.1 in which R. R1 and R2, which may be the same as or different from one another. represent a hydrogen atom, an alkyl or an alkoxyl group having up to 4 carbon atoms. a halogen, a nitro group. an acetyl (-COCH3) group. or a carbamoyl (-CONH2) group; n is 3. 4 or 5: q is O or 1; p and m are integers such that, when q is 0. p is 3 and m is 0. 1, 2 or 3, and when q is 1, p is 2 and m is 0. 1 or 2; R3 is an alkyl group having up to 4 carbon atoms or a phenyl group; and R4 is an alkoxyl group having up to 4 carbon atoms. 2. A silane acetoacetarylide dye as claimed in claim 1, characterized by having the formula: EMI22.2 in which R. R1, R2, R4 and m are as defined in claim 1. 3. A process for preparing an acetoacetarylide dye according to claim 1, characterized by comprising reacting a silane compound of formula: EMI23.1 in which n, R3, R4, q, m and p are as defined in claim 1, with a chloride of an acetoacetarylide sulphonic derivative of formula: EMI23.2 in which R, R1 and R2 are as defined in claim 1, in a substantially stoichiometric molar ratio of the silane (II) to the chloride (III), in a reaction medium comprising an organic solvent, at a temperature from 20 to 1000C. for 1 to 6 hours. 4. A process as claimed in claim 3, characterized in that the reaction is carried out in the presence of a hydrochloric acid- acceptor compound. 5. A process as claimed in claim 4, characterized in that the hydrochloric acid-acceptor compound is selected from Na2C03, NaHCO3, triethylamine and pyridine. 6. A process as claimed in any of claims 3 to 5, characterized in that the aminoalkoxysilane of formula (II) is selected from y-aminopropyl-triethoxysilane, 6-aminobutyl-phenyl-diethoxysilane, y-aminopropyl-methyl-diethoxysilane, and 6-aminobutyl-triethoxysilane. 7. A process as claimed in any of claims 3 to 6, characterized in that the organic solvent is selected from xylene, toluene, chloro-, dichloro- and trichloro-benzenes, nitrobenzene and dioxane. 8. A composite pigment characterized by comprising a silane acetoacetarylide dye as claimed in claim 1 or 2, grafted onto a solid inorganic substrate or support. 9. A composite pigment as claimed in claim 8, characterized in that the inorganic substrate or support is selected from TiO2 gel, semicrystalline TiO2, rutile TiO2 and anatase TiO2; mixtures of TiO2 with SiO2 and/or A1203;SiO2 and/or Al203;and mixtures thereof; the said substrate or support being optionally finely particled and having a specific 2 surface area of from 5 to 500 m /g. 10. A composite pigment as claimed in claim 8 or 9, characterized by containing from 10 to 50% by weight of silane acetoacetarylide dye in grafted form. 11. A process for preparing a composite pigment according to claim 8, characterized by comprising reacting the inorganic substrate or support with a silane acetoacetarylide dye of formula (I) in an inert organic solvent, at a temperature from 200C to the reflux temperature of the solvent, and separating the pigment by filtration followed by washing and drying. 12. A process as claimed in claim 11, characterised in that the composite pigment, separated by filtration. is subjected to a dry-heat treatment in an oven at 600-1100C for 4 to 8 hours prior to washing. 13. A process as claimed in claim 11 or 12, characterized in that the reaction is conducted in the presence of a catalyst selected from LiOH, CF3COOH, lead acetate and cobalt naphthenate. 14. A process as claimed in any of claims 11 to 13, characterized in that the reaction is conducted in the presence of a compound selected from tetra-alkoxysilanes containing up to 4 carbon atoms in each alkoxy group, vinyltriethoxysilane and alkylorthotitanates, in a weight ratio with respect to the dye (I) of from 0.1:1 to 1:1. 15, A paint, air enamel, stove enamel, printing ink, or plastics material, when coloured with a composite pigment as claimed in any of claims 8 to 10.

Inventors: BORNENGO, GIORGIO, CARLINI, FILIPPO MARIA, MARANZANA, GIORGIO, MARRACCINI, ANTONIO, PASQUALE, ANTONIO
Applicants: MONTEDISON S.P.A.
Application year: 1984
Main classification: C09B69
IPC codes: C09B43, C09B67, C09B69, C09C3