PROCESS FOR MANUFACTURING GLASSLIKE CARBON MATERIAL

Abstract: A process for manufacturing glasslike carbon material is disclosed in which a thermosetting resin, which exhibits hydro­ philic properties and is capable of containing a least 20% by weight of water and has a viscosity in the range of from 100 to 8000 cps (at 25°C), is carbonized and sintered in an inert at­ mosphere at a temperature of at least 800°C. A molded pro­ duct which is manufactured according to the invention pro­ cess and which is useful as a substrate for a magnetic head is also disclosed.

Description: PROCESS FOR MANUFACTURING GLASSLIKE CARBON MATERIAL BACKGROUND OF THE INVENTION The present invention relates to a process for manufacturing a glasslike carbon material. More particularly, it relates to a process for manufacturing glasslike carbon material which has an extremely smooth surface after being ground to provide specular surface, and to molded products produced. Generally, carbonization of a thermosetting resin in an invert atmosphere which resin has a three-dimensional reticular structure and which is insoluble as well as infusible results in a glasslike carbon material which prevents gas permeation, has a high degree of hardness and an isotropic structure. In addition to the characteristics found in conventional carbon materials such as light weight, good heat resistance, high electroconductivity, good corrosion resistanze, thermal conductivity, mechanical strength, sliding properties, etc., this glasslike carbon material has the additional characteristics of being homogeneous and free from carbon powder generation when used as a sliding material. This material has potential application in diversified areas such as electronics, nuclear power and space industries. Use of the present glasslike carbon material as the substrate of a magnetic head is being contemplated for these desirable characteristics. Higher sliding properties, good resistance to wear and better specular surface by grinding are some of the essential features required of magnetic head substrates. Furthermore, the use of the present glasslike carbon material in headsliders for m3netic heads is also being contemplated. e essential features required of it are lightness in weig;-; as well as higher sliding properties and ease in grinding for specular surface. Because of these characteristics, a glasslike carbon material can be used as substrates for both magnetic heads and headsliders. Microscopic observation of glasslike carbon materials according to the prior art reveals the presence of open pores and closed pores. The independent, i.e. not interconnected closed pcres present inside the material do not affect its performance to prevent gas permeation. When such a glasslike carbon material is ground for application in uses requiring the secular surface, these closed pores inside the material become open pores as a consequence of the grinding. This results ifl serious defects. In manufacturing thin fslm magnetic hezas, it is necessary to deposit metal on glass'ine carbon material by vaporization and sputtering, however due to the reasons mentioned above, it was not possible to obtain a specular surface by grinding which surface is suitable for vapor deposition of metal. In the manufacture of easily graphitized carbon material which is made of conventional raw materials such as pitch, the raw material becomes molten at one stage during carbonization, inevitably causing bubbles. In order to avoid this bubbling, carbonization under high pressure was attempted, reducing bubbles to a certain extent but not to an extent suff cient to prevent gas permeaticn. On the other hand, when phenol resin or furan with a higher carbonization yield is ued in carbonizing thermosetting resins, formation of substances with a lower boiling point such as water cannot be avoided in the step of obtaining a thermosetting substance, or a precursor thereof. Such substances will accumulate in the resin and create closed pores of a size exceeding the order of Hm. Pores are formed in thermosetting resin during its hardening process because of: (l) air taken into the resin before hardening, (2) substances with lower boiling points contained in the resin, unreacted components, and released water by condensation from the resin, (3) released water from condensation as a by-product from the hardening process, gas formed during decomposition, etc. Air contained preliminarily as mentioned in (1) above can be removed by a physical deforming procedure. Substances with lower boiling points contained in the resin, unreacted components and released water by condensation for the resin as in (2) can also be removed by heating under reduced pressure before hardening. However, released water from condensation at the time of hardening and the portion of gas formed during decomposition are extremely difficult to remove. This is especially so when a highly hydrophobic resin is used; a pool of water will be formed, which in turn will remain as large pores in the carbon material after its hardening carbonization. Based on repeated studies, the present inventor has successfully obtained a glass like carbon material which is substantially free from closed pores and therefore of problems in practical use by dissolving and dispersing in the base-resin those substances With a lower boiling point formed as by-products during the hardening. DETAILED DESCRIPtION OF THE INVENTION The present invention aims to provide a process for manufacturing a glasslike carbon material which is substantially free from pores, has a hard and tight structure and is capable of preventing gas permeation. According to the present invention, an initial condensate, which may contain 2Q wt% or more of water, is selected as a thermosetting composition for hardening procedure sufficient to impart to the composition a suitable degree of hydrophilic property in order to prevent a pool formation of released water during hardening. In a process for manufacturing giasslike carbon material by carbonizing andzor heating a thermosetting resin in an insert atmosphere at a temperature of at least 800 C, the present invention is characterized in the use of a thermosetting resin in the form of an initial condensate which may contain at least 2Q wt% of water In further detail the process of the present invention is characterized in that a pool of substances with boiling points lower is removed before the thermosetting resin hardens. In other words, the thermosetting resin in the form of initial condensate is imparted "before hardening" with a certain degree of hydrophllic properties for dissolving at least 20 wt% of water contained= therein in order to prevent substances with lower boiling points from being contained in the resin. As used herein, the term "initial condensate" according to the present invention means a resin which prior to hardening may contain a small arrount of raw material monomers and is a resin composítion with increased viscosity due to condensation. µ'Inert atmosphere" means an atmosphere which contains no oxygen but normally comprises at least one kind of gas selected from the group of helium, argon, nitrogen, hydrogen and a halogen (e.g. bromine, chlorine or fluorine), or an atmosphere under reduced pressure or in vacuum. The viscosity of the resin composition which is capable of containing at least 20 wt% of water in order to prevent formation of pores after hardening may differ depending on the type of the raw material resins employed, its degree of polymerization, blending ratio, etc. Results of studies by the present inventor indicate that a resin composition with a viscosity of from about 100 to about 8000 cps/25oC is sufficient in order to acnieve the objects of the invent ion. The process of the present invention, therefore, is characterized in that a thermosetting resin having the viscosity of from 100 to 8000 cps/250C and the hydrophilic property containing at least 20 wt% of water is hardened and then subjected to carbonization andfor heating in an inert atmosphere at 8000C or higher to obtain a glasslike carbon material. Even in the event hardening is commenced directly from the raw material monomer rather than from the initial condensate, resins which uniormiy dissolve at least 20 wtt of water contained in them at the viscosity of from 100 to 8000 CpS/2r C can be used to obtain giasslike carbon materials according to the present invention. When the initial condensate is not capable of containing at least 2Q wt% of water, it becomes impossible to completely di-sperse and dissolve the substances with lower boiling prints in the base resin, or the by-pro ucts from hardening of the resin composition in the base resin. It is sufficIent for the thermosetting resin according to the present invention to contain at least 20 wtZ of water before the resin hardens, but it should preferably contain at least 30 wt% of water in order to that the substances with still lower boiling points can be more thoroughly dispersed and dissolved in the base resin. To determine if a resin is capable of containing water can be easily measured by adding water to the initial condensate until the condensate begins to become turbid and by estimating the water content. For those that have already been divided Into two layers, the resin layer can be separated and the water content can be determined. The initial condensate to be used in the present invention which is capable of containing at least 2Q wt% of water can be obtained by selecting among the types of available raw material resins, blending ratio, or by modification of the resin. The addition of certain modifying agents as described below may be easier. Examples of thermosetting resins used in the present invention include phenol resin, epoxy resin, unsaturated polyester resin, furan resin, urea resin, melamine resin, alkyd resin, xylen resin, etc. Resins which meet the requirements of the present invention can be used as they are, in the form of mixtures of two or more resins, by blending, or by modification of the resin itself. Most preferred is a modified furan resin. Besides the thermosetting resins such as renal resin, furan resin and the like as mentioned above, and natural substances with a higher yield of na=-rally produced carbons such as asphalt or pitch, other hydrophilic substances having a relatively higher yield of carbon such as lignin, cellulose, tragacanth gum, acacia, humic acid, various types of sugars, and the like can also be modified to obtain the thermosetting resin according to the present invention. One specific example of such a thermosetting resin is a resin composition having the viscosity of from 100 to 8000 cps at 250C comprising from 7Q to 100 parts by weight of compound A and from 0 to 3Q parts by weight of compound B, wherein A denotes one or more types of compounds selected from the group consisting of a monomer mixture, or a first monomer mixture containing either one or both of phenol and furfuryl alcohol, and formalin in the mole ratio of from 30:55 to 75:30, phenol resin, furan resin and phenol modified furan condensate. B denotes one or more types of compounds selected from the group consisting of a monomer mixture, or second monomer mixture containing either one or both of urea and melamine, and formalin in the mole ratio of from 30:55 to 75:30, and urea resin, and melamine resin. If the hardening is commenced directly from the raw material monomer rather than from the initial condensate, resins which uniformly dissolve at least 20 wt% of water contained therein at-the required viscosity of from 10Q to 8000 cps/250C can be used to obtain glasslike carbon material according to the present invention. In the above example, when a monomes mixture, or first monomer mixture containing toth of phenol and furfuryl alcohol, and formalin in a predetermined ratio is used as compound A, or when a phenol modified furan co-condensate is used as compound A, from 70 to 100 parts by weight of the compound A can be used. However, if a monomer mixture, or first monomer mixture containing either one of phenol or furfuryl alcohol, and formalin in a predetermined ratio is used as compound A, or in case a phenol resin or furan resin is used as compound A, it is preferable to use from 70 to 90 parts by weight of compound A and from 10 to 30 parts by weight of compound B. Also, in case a mixture of phenol and formalin is used as compound A, the ratio therebetween is preferably from 1:3 to 1:0.5, and in case a mixture of furfuryl alcohol and formal in is used as compound A, the ratio therebetween is preferably from 1:1 to 1:0. In case a mixture of urea and formalin is used as compound B, the ratio therebetween is preferably from 1:2 to 1:0.5, and in case a mixture of melamine and formalin is used as compound B, the ratio therebetween is preferably from 1:6 to 1:0.5 Another example of the thermosetting resins is a resin composition obtained by co-condenRing phenol, furfuryl alcohol and formalin and composed of from 15 to 40 of phenol, from 15 to .35 of furfuryl alcohol and from 30 to 55 formal in based on the mole ratio converted to monomer. A further example of the thermosetting resin is a resin composition having the viscosity of from 100 to 8000 cps at 250C comprising from 70 to 100 parts by weight of compound C, from 0 to 15 parts by weight of compound D, and from 0 to parts by weight of compound E, wherein the compound fi denotes one or more types of compounds selected from the group of a monomer mixture, or third monomer mixture containing either one or both of pnenol and furfuryl alcohol, and formal in in the mole ratio from 30:55 to 75:30, phenol resin, furan resin and phenol modified furan condensate. Compound D denotes one or more types of compounds selected from the group consisting of lignin, modified resin and modified cellulose, and compound E denotes one or more types of compounds selected from the group consisting of a monomer mixture, or a fourth monomer mixture containing either one or both of urea and melamine, and formalin in the mole ratio of from 30:55 to 75:30r urea resin and melamine resin. When the hardening is started directly from the raw material monomer rather than from the initial condensate, resins which unIformly dissolve at least 20 wt% of water contained therein at the required viscosity of from 100 to 8000 cps/250C can be used to obtain glasslike carbon material according to the present invention. In the above example, when a monomer mixture of both of phenol and furfuryl alcohol, and formal in in a predetermined ratio is used as compound C, or a phenol modified furan condensate is used as compound C, from 70 to 100 parts by weight of compound C can be used. However, in case the monomer mixture of either one of phenol and furfuryl alcohol, and formalin in a predetermined ratio is used as compound C, or in case phenol resin is used as compound C, it is preferable to use from 70 to 90 parts by weight of compound C and from 10 to 30 parts by weight of compounds D and E. - Also, when a mixture of phenol and formalin is used as compound C, the ratio therebetween Is preferably from 1:3.5 to 1: :0.5, and when a mixture of furfuryl alcohol and formal in is used as compound C, the ratio therebetween is preferably from 1:1.2 to 1:0. Likewise, when a mixture of urea and formalin is used as compound E, the ratio therebetween is preferably from 1:2 to 1:0.5, and when a mixture of melamine and formal in is used as compound E, the ratio therebetween is preferably from 1:6 to 1:0.5. Yet another example of a suitable thermosetting resin is a resin composition having the viscosity of from 100 to 8000 cps at 250C comprising from 70 to 100 parts by weight of compound F and from 0 to 30 parts by weight of compound G, wherein compound F denotes one or more types of compounds selected from the group consisting of a monomer mixture, or fifth monomer mixture containing either one or both of phenol and furfuryl alcohol, and formalin in the mole ratio of from 1:4 to l:0, phenol resin, furan resin and phenol modified furan condensate. Compound G denotes one or more types of compounds selected from the group consisting of lignin, modified resin and modified cellulose. When the hardening is commenced directly from the raw material monomer rather than from the initial condensate, resins which uniformly dissolve at least 20 wt% of water contained therein at the viscosity of from 100 to 8000 cps/250C can be used to obtain a glasslike carbon material according to the present invention. The above example, if a phenol modified furan co-condensate is used as compound F, from 70 to 100 parts by weight of the compound F can used. However, if a phenol resin or furan resin is used as compound F, it is preferable to use from 70 to 90 parts by weight of compound F and from 10 to 30 parts by weight of compound G. Also, in case a monomer mixture containing either one of phenol and furfuryl alcohol and formalin is used, it is preferable to use from 70 to 90 parts by weight of the compound F and from 10 to 30 parts by weight of the compound G to form the resin composition. Furthermore, in case a mixture of phenol and formalin is used as a monomer mixture, the ratio therebetween is preferably from 1:4 to 1:0.5, and in case a mixture of furfuryl alcohol and formalin is used as monomer mixture, the ratio therebetween is preferably from 1:1.3 to 1:0. As is apparent from the requirement that the resin compositions have a viscosity of from 100 to 8000 cps at 250C during composition, the above mentioned resins are not in the solid state but occur in the fluid state, or substantially in the state of the initial condensate. In place of formalin, a formaldehyde polymer may be used for making the above mentioned resin compositions. Fillers can also be added during the practice of the present invention. Examples of suitable fillers include various carbon materials including, thermosetting resins such as carbon materials made from polyacrylnitrile, cellulose, rayon, pitch, iignin, phenol, fur n, epoxy, alkyd, unsaturated polyester, xylen as well as various graphites, carbon blacks and the like. These fillers can be used in any form such as fibers, particles, powders or as mass. A molded product made from the glasslike carbon material according to the present invention is characterized in that the pores contained in the glasslike carbon material are 0.1 vm or less in diameter and the ground surface of said product has specular structure. The glasslike carbon material according to the present invention is a carbon which is difficult to graphitize, has an isotropic structure and prevents gas permeation. These properties can be confirmed by a conventional method such as X-r y diffraction, Raman spectroscopy or the like. The number of pores contained in glasslike carbon material can be measured and obtained by microscopic observation of the ground surface, such as optical microscopes or scanning electron microscopes or the like. The glasslike carbon material according to the present invention is substantially free from pores and exhibits an excellent sliding property because of only a few pores on the surface. If vapor deposition or sputtering deposition occurs on molded products which are made from a conventional glasslike carbon material, the deposited film will be easily exfoliated. In contrast, with the molded products made from the glasslike carbon material according to the present invent ion, the deposited film is not easily exfoliated. As already seen in the foregoing, molded products made from a glasslike carbon material according to the present invention have excellent properties which other conventional products do not exhibit. One of the characteristics of the glasslike carbon material according to the present invention is that the diameter of the pores on the inside thereof is 0.1 vm or less, while with respect-to conventional glasslike materials, there exist 1000 cps. or more of pores which are 0.1 vm or more in diameter per 1 mm2. This means that in a conventional process, it was impossible to obtain a suitable glasslike carbon material which is free from pores of o m or more in diameter. The glasslike material according to the present invention may include from 1 to 10 cps. of pores in the range of from 0.1 to 0.5 lm in diameter per 1 mm2 on its surface or sectional areas. From a practical view point, such a glasslike carbon material can be regarded as being substantially pore-free when compared with conventional glasslike materials. In manufacturing molded products using such a glassllke carbon material which is substantially free from pores, conventional methods can be employed, such as, cutting, planing or grinding. Otherwise, precursors of the glasslike carbon materials, orF material in the state before it is sintered into a glasslike carbon material, can be molded into the desired shapes and thereafter sintered into molded products. Using these procedures, molded products having the width of O.1 mm2 or more can be molded into any desired shape or configuration such as a sheet, mass, board, various molded parts and the like. Also, molded products according to the present invention can be made into a specular surface by conventional methods, for example grinding the surface using aluminum powder. An illustration of molding is as follows: the thermosetting resin according to the present invention is charged in a mold of a predetermined shape before hardening depending on the use of rolded products. After being molded into predetermined shapes according to various molding methods, the molded precursor material is subjected to carbonization and sintering in an inert atmosphere at a temperature of 8000C or higher, preferably 10000C or higher and more preferably 12000C or higher to obtain the desired molded products made from the glasslike carbon material. The time required for carbonization and sintering can be conveniently determined dependIng on the sintering temperature employed. When the heating temperature is below 80a C, the resin will not be sufficiently carbonized, resulting in a higher pore ratio making it difficult to impart the required physical and performance properties to the glasslike carbon material. As described above, the use of a thermosetting resin as the starting material which is capable of containing at least 20 wtt of water in an initial condensate stage enables one to proceed with hardening while these substances also present with lower boiling points are thoroughly dispersed and dissolved in the base resin. This is extremely advantageous in obtaining a glasslike carbon material which is substantially free from pores and of manufacturing problems in practical use. Particularly since the resulting glasslike carbon material does not have pores in its inside structure, the process according to the present invention can be used for manufacturing an extremely thin film manufacturing substrate by vapor deposition of thin film or sputtering deposition. Its secular surface property allows for a process for manufacturing a thin film supporting body--used as a magnetic head substrate or a head slide. The material may also be used as sliding members having good resistance against wear which are useful for regular precise electronic parts. The invention also includes a method for manufacturing an electronic material in view of the prevailing tendency of higher integration and higher density. Furthermore, the glasslike carbon material obtained according to the process of the present invention can also be used as a fuel battery separator. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 illustrates a perspective view of a model substrate for a magnetic head made of the material according to the present invention, Figure 2 is a photograph of a ground surface of a conventional glasslike carbon material by a scanning electron micrograph. Figure 3 is a photograph of a ground surface of a glass like carbon material according to the invention by a scanning electron micrograph. DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be more clearly understood with reference to the following examples. However, it is to be understood that the invention is by no means to be limited to the specific examples. The term "part" or "parts" as used hereinafter in the examples mean part or parts by weight unless otherwise specified. Example 1 500 parts of furfuryl alcohol and 480 parts of 92% paraformaldehyde were agitated to dissolve at 80 C and added dropwise with a liquid mixture containing 520 parts phenol, 8.8 parts sodium hydroxide and 45 parts water under agitation. After the addition, the mixture was reacted for 3 hours at 80 C. A mixed solution containing 80 parts phenol, 8.8 parts sodium hydroxide and 45 parts water was further added and reacted for 4.5 hours at 80 C. After cooling to 30 , the reaction system was neutralized with 70% paratoluensulfonic acid. After dehydrating the neutralized substance under reduced pressure to remove 15Q parts water, 500 parts furfuryl alcohol was added. The obtained resin had the viscosity of 680 cps at 25 C. The capacity of the resin to hold water -was measured to be 38%. To the resin composition there was added 3.5 parts of liquid solution of hardening agent containing paratoluensulfonic 2C' dr water and glycol (weight ratio 7:2:1). The solution was agitated or 10 minutes and charged Into a 3 mm2 thick rectangular mold and defoamed under reduced pressure. It was heated for 3 hours at a temperature between 50 and 600C and further at 900C for two days. A plate of hardened resin thus obtained was introduced into a tubular furnace, heated to 1200 C at a rate of 10çC/hr under a nitrogen stream, maintained at said temperature for 2 hours, and cooled to obtain a glasslike carbon material. The glasslike carbon material was ground with an abrasive paper of {500--+8000 and the- surface pore structure and the pore diameter of the ground material were observed by a scanning electron microscope. The broken surface evidently had a glasslike structure. The pore diameter was in the range of from Q.05 to 0.01 vm or less. Example II 106 parts lignin (manufactured by Rorreaaard A.S. under the commercial name Ultragine NA), 100 parts 37% formalin, 100 parts furfuryl alcohol and 10 parts benzoic acid were mixed and reacted for 6 hours at 100 C. The resulting resin had a viscosity of 820 cps and was soluble in water. A glasslike carbon material was obtained in the same manner as in Example I by hardening and carbonization. The surface pore structure of the inner surface was observed. The broken surface had a glasslike structure and the pore diameter was from 0.05 to 0.01 vm or less. Example III A mixture of modified furan resins according to Examples I and II in the ratio of 1:1 was prepared before the resins hardened. The viscosity of the mixture was 750 cps. Hardening and carbonization identical to those of Example II were conducted to obtain glasslike carbon material. The surface pore structure of the inner surface was observed. The broken surface had glasslike structure and the pore diameter was from 0.02 to 0.01 pm or less. The following comparative examples are not according to the invention. Comparative Example I 5 parts of an aqueous solution of 0.011 N-HC1 were added to 100 parts furfuryl alcohol and the mixture was reacted for 6 hours at 1000C then dehydrated under reduced pressure. The initial condensate of furfuryl alcohol thus obtained had a water content of 0.638 and a viscosity of 39 Q cps. The capacity of the resin to hold water was found to be approximately 4%. A glasslike carbon material was obtained in the same manner as in Example I by hardening and carbonization. The surface pore structure of the inner surface was observed. The broken surface had glasslike structure, but numerous pores about 0.5 ijm in diameter were found. Comparative Example II A reaction system comprising 100 parts furfuryl alcohol, 25 parts 85% paraformaldehyde added with 10 parts benzoic acid and 0.1 part 93% NaOH was reacted for 11 hours at 110 C. The resin obtained had a viscosity of 350 cps. The capacity of the resin to hold water was found only to be 158. A glasslike carbon material was obtained in the same manner as in Example I by hardening and carbonization. The surface pore structure of the ground inner surface was observed. The broken surface had glasslike structure, but numerous pores greater than 1.0 vm in diameter were found. Example IV A mixture of 500 parts of furfuryl alcohol, 480 parts of 92% paraformaldehyde and 50 parts ion exchanged water was heated to 800C under agitation and added dropwise with a liquid mixture containing 520 parts phenol, 8.8 parts sodium hydroxide and 45 parts water. During the addition, the temperature was maintained at 80 C. After the addition, the mixture was agitated for 3 hours to mature and added dropwise with a mixture of 80 parts phenol, 45 parts water and 8.8 parts sodium hydroxide. After the additIon, it was reacted for 2 hours at 80 C.- After cooling to 70 C, it was further added dropwise with 63 parts melamine and 160 parts of a 37% formaldehyde liquid solution, and reacted for 5 hours at 70 C. Then the liquid was cooled to room temperature and neutralized with 70% paratoluensulfonic acid. After dehydrating the neutralized substance under reduced pressure to remove 250 parts water, 500 parts furfuryl alcohol was added. The obtained resin had the viscosity of 2700 cps at 25 C. The capacity of the resin to hold water was measured to be at least 35%. The resin was added with 4.5 parts of liquid solution of hardening agent containing paratoluensulfonic acid, water and glycol (weight ratio 7:2:1), agitated sufficiently, charged into a 3 srL2 thick rectangular mold and defoamed under reduced pressure. It was heated for 3 hours at a temperature between 50 and 600C and further at 900C for seven days. A plate of hardened resin thus obtained was introduced into a tubular furnace, heated to 12000C at a rate of 10 C/hr under a nitrogen stream, maintained at said temperature for 2 hours, then cooled to obtain a glasslike carbon material. The glasslike carbon material was ground with an abrasive paper of &num;500-&num;8000 and the surface pore structure of the inner surface and the pore diameter of the ground material were observed by a scanning electron microscope. The ground surface did have pores but only a few per 1 mm2. The: pore diameter was in the range from 0.1 to 0.5 um. No pores greater in diameter than the above were observed. Example V 500 parts furfuryl alcohol and 480 parts of 928 paraformaldehyde were agitated to dissolve at 800C and added dropwise with a liquid mixture containing 520 parts phenol, 8.8 parts sodium hydroxide and 45 parts water under agitation. After the addition, the mixture was reacted for 3 hours at 800C and added further with a mixed solution containing 80 parts phenol, 8.8 parts sodium hydroxide and 45 parts water. The resultant was reacted for 4.5 hours. After cooling to room temperature with water, the reaction was neutralized and then mildly acidified (pH 7.5) with 70% paratoluensulfonic acid. The solution was heated to 800C again and added dropwise with 135 parts of a 37% formalin liquid solutIon and 100 parts of a 502 urea liquid solution. After maturing for 1 hour, It was dehydrated under reduced pressure to remove approximately 250 parts water and added with 500 parts furfuryl alcohol. The obtained resin had the viscosity of 2200 cps at 25 C. The water content capable of being held was measured to be at least 30%. The resin composition thus obtained was hardened and carbonized in the same manner as in Example I to obtain a glasslike material. The surface pore structure of the inner surface was observed in the same manner as in Example I. The ground surface had a glasslike structure. There were less than 10 pores in the: range from 0.1 um to 0.5 um in diameter per 1 mm2. No pores greater in diameter than the above were found. Example VI 100 parts phenol were added with 15t parts cf a 37% liquid solution of formaldehyde and 15 parts lignin under agitation, and added further with 5 parts of a 10% hydroxide liquid solution under agitation. The mixture was heated to 800C and reacted for 2 hours at said temperature. Thereafter, the solution was cooled to 70 C, added with 9 parts melamine and 25 parts of a 378 liquid solution of formaldehyde and reacted, again maintaining the temperature at 70 C. After cooling to room temperature, the solution was neutralized and then mildly acidified with 85% lactic acid. The resultant is dehydrated under reduced pressure to remove 120 parts water. The obtained resin composition had a viscosity of 4800 cps at 25 C. The water content of the resin capable of being held was measured to be at least 30%. The resin composition was added with 4.5 parts of a lIquid solution of hardening agent containing paratoluensulfonic acid, water and glycol weight ratio 7:2:1), agitated sufficiently, charged into a 3 mm2 thick rectangular mold and defoamed under reduced pressure. Then it was heated for 3 hours at a temperature of between 500C and 600C and further heated at 900C for two days. A plate of hardened resin thus obtained was introduced into a tubular furnace, heated to 1200 C at rate of 10 C/hr under a nitrogen stream, maintained at said temperature for 2 hours, and cooled to obtain a glasslike carbon material. The glasslike carbon material was ground with an abrasive paper of &num;500-&num;8000 and the surface pore structure of the inside surface and the pore diameter of the ground material were observed by a scanning electron microscope. There were onl a few pores on the ground surface per 1 mm2. The pore dIameter was in the range of from 0.1 !m to 0.5 vm. No pores greater in diameter than the above were found. Example VII A mixture of 500 parts of furfuryl alcohol (manufactured by Kao-Quaker) and 483 parts of 80% paraformaldehyde (manufactured by Wako Junyaku) and 305 parts of lignin (manufactured by Borregaad A.S. under the commercial name Ultragine NA) were heated to 800C under agitation and added dropwise with a liquid mixture containing 524 parts carbolic acid (manufactured by Mitsui Toatsu K.K.), 54 parts of a 16% aqueous solution of sodium hydroxide under agitation. After the addition, the mixture was allowed to mature for 3 hours at 80 C. A mixed solution containing 81 parts carbolic acid and 54 parts of 16% sodium hydroxide was further added and matured for 2 hours at 80 C. After cooling to room temperature, the react ion system was subjected to neutralization or mold acidification (pH 7.5) with 70% paratoluensulfonic acid. The liquid was heated to 800C again and added with 12Q parts of a 37% liquid solution of formalin and 90 parts of a 50% liquid solution of urea. After being matured for 1 hour, it was dehydrated under reduced pressure to remove 290 parts water and 50Q parts furfuryl alcohol were added. The obtained resin had a viscosity of 2900 cps at 25 C. The water content of the resin capable of being held was measured to be at least 35%. A glassllke carbon material was obtained in the same manner as in Example I by hardening and carbonizing the resin. The surface pore structure of the inner surface and the pore diameter of the ground material were observed in the same manner as in Example 1. The ground surface had glasslike structure. There were fewer than 10 pores per 1 mm2. The pore diameter was in the range of from 0.1 vm to 0.5 um. No pores greater in diameter than the above were observed. Example VIII A mixture of 500 parts furfuryl alcohol, 483 parts of 80% paraformaldehyde and 200 parts of lignin was heated to 80or. Then, the mixture was added dropwise with a mixture of 524 parts carbolic acid and 54 parts of 16% sodium hydroxide liquid solution under agitation at 80 C. After dropping, it was allowed to mature for 3 hours at 80 C. Next 8' parts of carbolic acid and 54 parts of sodium hydroxide liquid solution were added dropwise and matured for 2 hours while maintaining said temperature. Thereafter, the liquid temperature was lowered to 700C and 63 parts of melamine and 160 parts of a 37% formaldehyde liquid solution were added. After reacting for 5 hours at a temperature of 70 C, the solution was cooled to room temperature. The solution was neutralized with a 70% liquid solution of paratoluensulfonic acid, dehydrated under reduced pressure to remove 250 parts water and 500 parts of furfuryl alcoholvwere added. The obtained resin had a viscosity of 3800 aps at 25 C. The water content capable of being held was measured to be at least 35%. A glasslike carbon material was obtained in the same manner as in Example I by hardening and carbonizing of the resin. The surface pore structure of the inside ground surface of the glasslike material was observed in the same manner as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores per 1 mm2, and the pore diameter was found to be in the range of from 0.1 Um to O.5 vm. No pores greater in diameter than the above were observed. Example IX A mixture fo 500 parts furfuryl alcohol (manufactured by Rao-QuakRr), 483 parts of 80t paraformaldehyde (manufactured by Wako Junuaku) and 305 parts lignin (manufactured by Borregaad A.S. under the commercial name Ultragine NA) was heated to 800C under agitation. The mixture was added dropwise with a mixed liquid solution containing 524 parts carbolic acid (manufactured by Mitsui Toatsu K.K.) and 54 parts of a 168 liquid solution of sodium hydroxide under agitation. The temperature was maintained at 80 C during the reaction. After dropping, the reactant was matured for 3 hours while being maintained at a temperature of 8Q C. Thereafter, it was added dropwise with a mixed liquid solution of 81 parts carbolic acid and 54 parts of a 16% liquid solution of sodium hydroxide and allowed to mature for 2 hours at a temperature of 80 C. The solution was cooled to room tempera- ture and neutralized with 70% paratoluensulfonic acid. Then it was dehydrated under reduced pressure to remove 150 parts water, and added with 480 parts furfuryl alcohol. The obtained resin composition had a viscosity of 6500 cps at 250C and the water content capable of being held was 41%. The obtained resin composition was added with 4.5 parts of a liquid solution of a hardening agent containing paratoluensulfonic acid, water and glycol (weight ratio 7:2:1), agitated sufficiently and charged in a rectangular mold 3 mm2in thickness and defoamed under reduced pressure. Thereafter, it was heated for 3 hours at a temperature in the range of from 500C to 600C and maintained heated for 10 days at 90 C. The obtained rectangular shaped hardened resin was introduced into a tubular furnace and heated to 1200 C at a rate of 10 C/hr under a nitrogen stream. After maintaining said temperature for 2 hours, it was cooled for obtaining a glasslike material. The obtained glasslike carbon material was ground with an abrasive paper of &num;500-&num;8000 and the surface pore structure of the inside ground surface and the pore diameter of the ground material were observed by a scanning electron microscope. There were only a few pores per 1 mm2 on the ground surface. The pore diameter was in the range of from 0.lem to 0.5 pm. No pores greater in diameter than the above were observed. Example X 100 parts carbolic acid was added with 157 parts of a 37% liquid solution of formaldehyde with 20 parts of lignin, and added further with 5 parts of 10% liquid solution of sodium hydroxide. The mixtured solution was reacted under agitation for 2 hours at 80 C. After it was cooled to room tempera turn, it was neutralized with 5.5 parts of 85% lactic acid and dehydrated to remove 120 parts water under reduced pressure. The obtained resin composition had a viscosity of 3200 cps at 25 C. A glasslike carbon material was obtained by hardening and carbonization as in Example II. The surface pore structure of the inside ground surface of the glasslike carbon material was observed as in Example II. The ground surface had glasslike structure. There were fewer than 10 pores thereon per 1 mm2. The pore diameter was in the range of O .1 Lm to 0.5 vm. No pores greater in diameter than the above were observed. Example XI 30 parts lignin, 100 parts of 378 formalin, 100 parts furfuryl alcohol and 10 parts benzoic acid were mixed together and reacted for 6 hours at 100 C. The obtained resin composition had a viscosity of 520 cps and the water content capable of being held was at least 30%. A glasslike carbon material was obtained by hardening and carbonizing of the resin as in Example I. The surface pore structure of the inside ground surface of the resin were observed as in Example I. The ground surface has a glasslike structure. There were fewer than 20 pores thereon per 1 mm2. The pore diameter was in the range of from o m to 0.5 wm. No pores greater in diameter than the above were observed. Comparative Example III 100 parts furfuryl alcohol were added with 5 parts of a liquid solution of 0.01N-EC1 and the mixture was reacted for 6 hours at 1000C and dehydrated under reduced pressure. The initial condensate of furfuryl alcohol thus obtained Zad a water content of only 0.63% and a viscosity of 390 cps. The maximum water content thereof was measured to be about 4%. A glasslike carbon material was obtained in the same manner as in Example I by hardening and carbonization. The surface pore structure of the Inner ground surface was observed as in Example I. The ground surface had glasslike structure. However, there were from 103 to 104 pores sections about 0.5 vm in diameter. Comparative Example Iv A mixture of 10 parts furfuryl alcohol and 25 parts of 858 paraformaldehyde was added to 10 parts benzoic acid and 0.1 parts 93% sodium hydroxide; the mixture was reacted for 11 hours at 510 C. The obtained resin had the viscosity of 350 cps. The maximum water content thereof was measured to be about 15%. A glasslike carbon material was obtained as in Example I by hardening and carbonization. The surface pore structure of the inside ground surface thereof was observed as in Example I. The ground surface had glasslike structure but numerous pores about 0.1 um or more in diameter were observed. Example XII 500 parts furfuryl alcohol and 480 parts of 92% paraformaldehyde were agitated and reacted at 80 C. The mixture was added dropwise with a liquid mixture containing 520 parts phenol, 8.8 parts sodium hydroxide and 45 parts water under agitation. After dropping, it was reacted for three hours at 80 C. It was further added with a solution mixture of 80 parts phenol, 8.8 parts sodium hydroxide and 45 parts water and reacted for 4.5 hours at 80 C. The solution mixture was cooled to 300C and neutralized with 708 paratoluensulfonic acid. Thereafter it is dehydrated under reduced pressure to remove 150 parts water and 500 parts furfuryl alcohol were added. The resin composition thus obtained was a composition consisting of phenol(PhOH), furfuryl alcohol(FFA) and formalin(F) in the mole ratio of 22:32:46 after being converted to monomer. The resin had the viscosity of 680 ops at 250C and the water content thereof was 38%. Composition, viscosity and water content of the resin composition are shown in Table I. The resin composition thus obtained was added with 3.5 parts of a liquid solution of hardening agent containing paratoluensulfonic acid, water and glycol (weight ratio 7:2:1). After being sufficiently agitated, the mixture was charged into a 3 mm2 thick rectangular mold and defoamed under reduced pressure. Thereafter the resin was heated for 3 hours at a temperature in a range of from 50 to 60*C and further heated for two days at 90 C. The obtained rectangular shaped hardened resin was introduced into a tubular furnace and heated to 1200 C at a rate of 10 C/hr under a nitrogen stream and maintained for 2 hours. Thereafter it was cooled to obtain a glasslike carbon material. The glass like carbon material was ground with an abrasive sheet 500-c80Q0 and the surface pore structure of the ground inside surface and the pore diameter were observed by a scanning electron microscope. The ground surface had an apparently glasslike structure, and the pore diameter was in the range of from 0.05 vm to 0.01 um or less. Example XIII 500 parts furfuryl alcohol (manufactured by Kao-Quaker) and 483 parts of 92% paraformaldehyde (manufactured by Mitsui Toatsu K.K.) were put into a four-neck flask and heated to 800C under agitation. The mixture was added dropwise with a mixture of 525 parts carbolic acid (manufactured by Mitsui Toatsu K.K.) and 54 parts of a 16.5% liquid solution of sodium hydroxide for 6 hours at 80 C. During the react ion under dropping, the paraformaldehyde was sublimed but the mixture was kept agitated and dissolved. After dropping, it was further reacted for 3 hours. Thereafter, a solution consisting of a mixture of 80.5 parts phenol and 54 parts of 16.5% sodium hydroxide were added dropwise under agItation. After reacting it was matured for 2 hours at 80 C, it was cooled to room temperature and then neutralized with 50.8parts of a 70% liquid solution of paratoluensulfonic acid. Then it was dehydrated to remove about 150 parts water under reduced pressure and 400 parts furfuryl alcohol were added. The resin composition thus obtained was a composition consisting of phenol, furfuryl alcohol and formalin in the mole ratio of 20:29.5:50.5 after being converted to monomer. The resin had a viscosity of 1750 cps at 250C and the water content thereof was 31%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 m-to 0.5 -um; no pores greater in diameter than the above were observed. Example XIV Phenol and furfuryl alcohol were cocondensed in the mole ratio of 32:32:36 after being converted to monomer. The obtained resin composition has a viscosity of 1600 cps at 250C and was capable of holding 30% water. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 m to 0.5 vm; no pores greater in diameter than the above were observed. Example XV Phenol, furfuryl alcohol and formalin were co-condensed in the mole ratio of 24:20:55 after being converted to monomer. The obtained resin composition had a viscosity of 4250 cps at 250C and the water content there was 35%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores thereon per 1 mm2. She pore diameter was in the range of from 0.1 va to O.5 um; no pores greater in diameter than the above were observed. Example XVI Phenol, furfuryl alcohol and formalin were co-condensed in the mole ratio of 29:26:45. The obtained resin composition had a viscosity of 1800 cps at 250C and the water content there was 30%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 Jm to 0.5 vm; no pores greater in diameter than the above were observed. Example XVII Phenol, furfuryl alcohol and formalin were co-condensed in the mole ratio of 25.5:36.5:38. The obtained resin composition had a viscosity of 320 cps at 250C and the water content there was 35%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. The ground surface had a glasslike structure. There were fewer than 10 pores thereon per 1 mm2; no pores greater in diameter than the above were observed. Comparative Example V Phenol, furfuryl alcohol and formaii-n were co-cc-.densed in the mole ratio of 19:41:40. The obtained co-condensate had a viscosity of 420 cps at 250C and the water content thereof was 26%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said cocondensate. The surface pore structure of the inside ground surface was observed as in Example I. There were about 20 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 Um to 0.5 vm. Comparative Example VI Phenol, furfuryl alcohol and formalin were co-condensate in the mole ratio of 50:15:35. The obtained co-condensate had the viscosity of 2700 cps at 25 C, and the water content thereof was 18%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said cocondensate. The surface pore structure of the inside ground surface was observed as in Example I. There were about 103 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 vm to O.5 wm. There were also large pores of 0.5 um ore more in diameter. Comparative Example VII Phenol and formal in was co-condensed in the mole ratio of 30:70 after being converted to monomer. The obtained co-condensate had a viscosity of 3200 ops at 25eC., and the water content thereof was 198. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said cocondensate. The surface pore structure of tte inside ground surface was observed as, in Example I. Numerous pores about 1 m in diameter or more were found Comparative Example VIII Furfuryl alcohol and formalin were cocondensed in the mole ratio of 59:41 after being converted to monomer. The obtained co-condensate had a viscosity of 350 cps and the water content thereof was 15%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said co- condensate. The surface pore structure of the inside ground surface was observed as in Example I. Numerous pores of about l- > m or more in diameter were found. Comparative Example IX Furfuryl alcohol by itself was condensed; the resin has a viscosity of 390 ops at 250C and the water content thereof was 48. A glasslike carbon material was obtained as in Example I by hardening and carbonizing said resin. The surface pore structure of the inside ground surface was observed as in Example I. Numerous pores about 1 um or more in diameter were found. TABLE I Composition* Vis- Water (Mole Ratio) cosity Content PhOH FFA F cps Example 12 22 32 46 680 38 13 20 29.5 50.5 1750 31 14 32 32 36 1600 36 15 25 30 55 4250 35 16 29 26 45 1800 30 17 25,5 36.5 38 320 36 Comparative 5 19 41 40 420 26 Example 6 5G 15 35 2700 18 7 30 0 70 3200 19 8 0 59 41 350 15 9 0 100 0 390 4 * PhOH = phenol FFA = furfuryl alcohol F = formalin Comparative Example X The maximum water content of HITA fuzan VF302 (furfuryl alcohol/furfuryl condensate, viscosity of 200 cps at 25 C) was obtained as- follows: after being vigorously mixed with about an equal quantity of water, it was left as it was and precipitated resin produced on the bottom was taken out for sampling. The water content was measured by the Karl-Fischer technique and was found to be 3.9%. A glasslike carbon material was obtained as in Example I by hardening and carbonizing. The surface pore structure of the inside ground surface was observed as in Example I. There were about 102 to 105 pores thereon per 1 mm2. The pore diameter was in the range of from 0.1 vm to 3 um. An acceptable sputtering film could not be obtained on this substrate because of its poor adherence; the film was exfoliated when it was annealed. The glass like carbon material obtained as in Example I & II and Comparative Example I & II was cut into the shape and size as shown in Fig. 1. The object was to prepare a model substrate 1 by gradually grinding its surface A to be slid against a recording medium while surface B was provided with a thin film from coarse to fine finish for a specular surface using an abrasive paper &num;15000. Observation of the surface R with the specular finish as in Example I using a scanning electron microscope indicated that there were no pores greater than 0.5 vm in diameter; those pores found were less than 0.01 vm in diameter. In order to evaluate the friction property of the model substrate 1 with a magnetic recording medium, the dynamic friction property of the surface A of the substrate 1 with a co-deposited -Fe O coated film, with Ni-P plated thin film and with a Co-Cr sputtering thin film was measured using a friction test apparatus. The surface A (sliding surface) of the substrate 1 and the film surface of the magnetic recording medium were observed visually. The results are shown in Table 2. The friction test apparatus used in the measurement is suitable for measuring dynamic friction properties of an object under conditions simulating actual use and is described in the Japanese Patent Application Disclosure 55-128142, the disclosure of which is hereby incorporated by reference. TABLE 2 ----------------------------------------------------------------------------------------------------------- Model substrate film of recording coefficient of sliding surface film surface medium dynamic friction of substrate ----------------------------------------------------------------------------------------------------------- Example I Co&gamma;-Fe2O3 film 0.16 good good Ni-P plated film 0.11 good good Co-Cr sputtering 0.11 good good film ------------------------------------------------------------------------------------------------------------ Example II Co&gamma;-Fe2O3 film 0.15 good good Ni-P plated film 0.10 good good Co-Cr sputtering 0.10 good good film ------------------------------------------------------------------------------------------------------------- Comp. Example I Co&gamma;-Fe2O3 film 0.25 good film exfoliated Ni-P plated film 0.25 good film exfoliated Co-Cr sputtering 0.25 good film exfoliated film ------------------------------------------------------------------------------------------------------------- Comp. Example II Co&gamma;-Fe2O3 film 0.28 good film exfoliated Ni-P plated film 0.26 good film exfoliated Co-Cr sputtering 0.26 good film exfoliated film -------------------------------------------------------------------------------------------------------------- Test Example II The glasslike carbon material obtained in Examples I to XI and Comparative Examples I to IV was cut Into the shape and size as shown in Pig. 1 to prepare a model substrate 1 by gradually grinding of surface A to be held in sliding contact with a recording medium. Surface B was provided with a thin film from coarse to fine finish for a specular surface using an abrasive paper &num;1500. Observation of the surface B with the specular finish as in Examples IV, VI & IX using a scanning electron microscope indicated that there were no pores greater than 0.5 um in diameter and that the pores found were less than 0.01 um in diameter. The model substrate 1 was sectioned along the line C-C' shown in the Fig. 1. The surface B of one of the sections was provided with a thin film 1 vm in thickness of Co-Zr-Nb alloy by sputtering. Surface 3 of the other section was provided with a thin film 0.3 m in thickness of Co-Zr-Nb alloy by sputtering. These thin films were heated in a revolving magnetic field. After heating the coercive force (Hc) of the respective thin films was measured using a vibration-type magnetic measurement apparatus for soft magnetic thin films. The results are shown in Table 3. An attempt was made to test the glasslike carbon material obtained in the Comparative Examples reported above. However, the target head could not be obtained as the sputtered film exfoliated during heating. TABLE 3 Model Substrate Magnetic Cohesion of film* Magnetic characteristics film thickness film thickoess 1.0 m 0.3 m ------------------------------------------------------------------------------------------------ Example I 0.08 0.2 good Example II 0.08 0.3 good Comp.** Example I not measurable not measurable inferior Comp. Example II not measurable not measurable inferior Example IV 0.08 0.2 good Example V 0.08 0.3 good Example VI 0.08 0.2 good Example VII 0.08 0.3 good Example VIII 0.08 0.2 good Example IX 0.08 0.2 good Example X 0.08 0.3 good Example XI 0.08 0.3 good Comp. Example III not measurable not measurable inferior Comp. Example IV not measurable not measurable inferior *Unit: OE ** Comparative Example Test Example III The glasslike carbon material obtained in Examples XII to XVII and Comparative Example V to IX was cut into the shape and size as shown in Fig. 1 to prepare a model substrate 1 by gradually grinding its surface A to be held in sliding contact with a recording medium. Surface B to be provided with a thin film from coarse to fine finish for a specular surface using an abrasive paper +1500. Observation of the surface B with specular finish as in Example XII using a scanning electron microscope indicated that there were no pores greater than 0.5 Lm in diameter and that the pores founded were less than 0.01 um in diameter. The model substrate 1 was sectioned along the line C-C' as in Fig. 1. Surface B of one of the sections was provided with a thin film of 1 um in thickness of a Co-Zr-Nb alloy by sputtering. Surface B of the other section was provided with a thin film of 0.3 m in thickness of a Co-Zr-Nb alloy by sputtering. These thin films were heated in a revolving magnetic field. After heating, the coercive force (etc) of respective thin films was measured using a vibration-type magnetic measurement apparatus for soft magnetic films. Those films which have good magnetic characteristics show a smooth H-B curve, whole those which have inferior magnetic characteristics show a line of discontinuity having stepping H-B curve. The status of the sputtered film and an evaluation of the magnetic characteristics are shown in Table 4. TABLE 4 Sputtered Magnetic Film Characteristics Example XII good good Example XIII good good Example XIV good good Example XV good good Example XVI good good Example XVII good good *Corn. Example V fair good Corn. Example VI inferior inferior Corn. Example VII inferior inferior Corn. Example VIII inferior inferior Corn. Example IX inferior inferior *Comparative examples Discussion of the test results: As is clear from tables 2 to 4, the characteristics of the glasslike carbon materials according to the present invention show smaller magnetic cohesion and excellent magnetic characteristics compared with those obtained in accordance with the methods of the comparative examples.

Claims: Claims 1. A process for manufacturing a glasslike carbon arterial comprising carbonizing and sintering in an inert atmosphere at a temperature of at least 8000C a thermo setting resing, characterized in that a thermosetting resin is used which is capable of containing at least 20% by weight of water when said resin is in the state of an initial condensate before hardening and producing a glasslike carbon material. 2. The Process according to claim 1, characterized in that the thermosetting resin is a resin composition having a viscosity of from 100 to 8000 cps/250C comprising: from 70 to 100 parts by weight of at least one compound selected from the group consisting of a first monomer mixture, phenol resin, furan resin and phenol modified furan co-condensate, and from 0 to 30 parts by weight of at least one compound selected from the group consisting of a second monomer mIxture, urea resin and melamine resin. 3. The process according to claim 2, characterized in that said first monomer mixture contains phenol and formalin in the mole ratio of from 1:3 to 1:0.5. 4. The process according to claim 2, characterized in that said first monomer mixture contains furfuryl alcohol and formalin in the mole ration of from 1:1 to 1 0. 5. The process according to claim 2, characterized in that said first monomer mixture contains both phenol and furfuryl alcohol, and formalin in the mole ratio of from 30:55 to 75:30. 6. The process according to one of the claims 2 to 5, characterized in that said second monomer mixture contains urea and formalin in the mole ratio of from 1:2 to 1:0.5. 7. The process according to one of the claims 2 to 5, characterized in that said second monomer mixture contains melamine and formalin in the mole ratio of from 1:6 to 1:0.5. 8. The process according to one of the claims 2 to 5, characterized in that said second monomer mixture contains both urea and melamine, and formalin in the mole ratio of from 30:55 to 75:30. 9. The process according to claim 1, characterized in that said thermosetting resin is a resin composition obtained by co-condensing from 15 to 40 of phenol, from 15 to 35 of furfuryl alcohol and from 30 to 55 of formal in based on the mole ratio converted to monomer. 10. The process according to claim 1, characterized in that said thermosetting resin is a resin composition having a viscosity of from 100 to 8000 cps at 250C comprising: from 70 to 100 parts by weight of at least one com- pound selected from the group consisting of a third monomer mixture, phenol resin, furan resin and phenol modified furan co-condensate; from 0 to 15 parts by weight of at least one compound selected from the group consisting of lignin, modified resin and modified cellulose, and from 0 to 15 parts by weight of at least one compound selected from the group consisting of a fourth monomer mixture, urea resin and melamine resin. 11. The process according to claim 10, characterized in that said third monomer mixture contains phenol and formal in in the mole ratio of from 1:3.5 to 1:0.5. 12. The process according to claim 10, characterized in that said third monomer mixture contains furfuryl al cohol and formalin in the mole ratio of from 1:1.2 to 1:0. 13. The process according to claim 10, characterized in that said third monomer mixture contains both phenol and furfuryl alcohol, and formalin in the mole ratio of from 30:55 to 75:30. 14. The process according to one of the claims 10 to 13, characterized in that said fourth mixture contains urea and formalin in the mole ratio of from 1:2 to 1:0.5. 15. The process according to one of the claims 10 to 13, - characterized in that said fourth monomer mixture contains melamine and formalin in the mole ratio of from 1:6 to 1:0.i. 16. The process according to one of the claims 10 to 13, characterized in that said fourth monomer mixture contains both urea and melamine, and formalin in the mole ratio of from 30:55 to 75:30. 17. The process according to claim 1, characterized in that said thermosetting resin is a resin composition having a viscosity of from 100 to 8000 cps at 250C comprising: from 70 to 100 parts by weight of at least one com pound selected from the group consisting of a fifth monomer mixture, phenol resin, furan resin and phenol modified furan co-condensate; and from 0 to 30 parts by weight of at least one compound selected from the group consisting of lignin, modified resin and modified cellulose. 18. The process according to claim 17, characterized in that said fifth monomer mixture contains phenol and formal in in the mole ratio of from 1:4 to 1:0.5. 19. The process according to claim 17, characterized in that said fifth monomer mixture contains furfuryl al cohol and formalin in the mole ratio of from 1:1.3 to 1:0. 20. The process according to claim 17, characterized in that said fifth monomer mixture includes both phenol and furfuryl alcohol, and formalin in the mole ratio of from 1:4 to 1:0. 21. A molded product made from a glasslike carbon material having minute pores therein, characterized in that said pores are no larger than 0.1 Am in diameter. 22. The molded product according to claim 21, characterized in that it has a ground specular surface.

Inventors: IMAMURA, TETSUYA, KISHINE, NOBUYUKI, YAMAUCHI, MICHIHIDE
Applicants: KAO CORPORATION
Application year: 1984
Main classification: C01B31
IPC codes: C01B31, G11B5, C04B35