METHOD FOR FIBER RETRIEVAL FROM AQUEOUS STREAMS

Abstract: An efficient method of continuously treating normally dilute aqueous solutions of cellulosic pulp which routinely flow from pulpmaking or papermaking process devices to effect separation and retrieval of small amounts of desirable fiber therefrom while letting small contaminants and un­ desirable fiber parts flow through to the sewer and also to effect retrieval of desirable fiber during periods of high fiber loading which result from upstream catastrophic failures by utilizing an open cell hydrophobic foam separation medium on a drum or belt filter. The foam medium has a thickness within the range of from one-eighth inch to two inches and a porosity within the range of from forty to eighty pores per lineal inch.

Description: Method And Apparatus For Fiber Retrieval From Aqueous Streams Background of the invention In the paper industry, a number of mechanical devices are used to separate fiber from water streams including: screens, vacuum filter drums and fourdrinier wires. Foam filters of the type disclosed in U.S. Patent Nos. 4,310,424 and 4,303,533, assigned to the same assignee as the instant invention, and U.S. Patent No. 4,212,737, also have been suggested for application to such streams but regeneration requirements of the foam filters heretofore have prevented such processes from producing desirable fiber consistency and volumetric flow in an efficient manner. These problems have been compounded because in addition to the normal leakage of fiber through the upstream process devices into the mechanical separation device or filter feed stream, occasional breaks and failures occur in the upstream devices which allow relatively large amounts of the pulp to enter the stream. Depending on the stream feeding the mechanical separation device, consistencies of cellulosic fiber in the normally dilute aqueous suspension of cellulosic pulp can increase to a range of from one-half percent (1/2%) to eight percent (8%) during upstream catastrophies. The result of such failures is that downstream equipment, which typically includes pumps, control valves, regulators and other flow control plumbing, which are not designed to handle a high consistency stream, will often eventually fail. Moreover, fiber which is desirable for further papermaking purposes will by-pass the separation process and be lost to the sewer. Accordingly, there has been an unfulfilled need for an efficient method of continuously treating normally dilute aqueous solutions of cellulosic pulp which routinely flow from the pulpmaking or papermaking process devices to effect separation and retrieval of small amounts of desirable high consistency fiber therefrom while letting small contaminants and undesirable fiber parts flow through to the sewer and also to effect retrieval of desirable high consistency fiber during periods of high fiber loading which result from upstream catastrophic failures. The present invention is an efficient method and apparatus of such versatility that it accomplishes this previously unfulfilled need. Brief description of the invention An efficient method of treating normally dilute aqueous suspensions of cellulosic pulp, which are occasionally highly loaded with fiber, to effect separation and retrieval of desirable fiber at high consistency from small contaminants and undesirable fiber parts in the suspension surprisingly has been discovered from observations and analysis of hydrophobic foam separation medium characteristics and behavior. In particular, the electrostatic and capillary behavior of open cell hydrophobic foam within certain thickness and porosity ranges has been determined to have the required separation versitility necessary efficiently to retrieve desirable fiber both routinely and during catastrophic loadings. When open cell hydrophobic foam separation media of thicknesses within the range of from one-eighth inch (1/8 ") to two inches (2") and porosities within the range of from forty (40) to eighty (80) pores per lineal inch (ppi) are used to provide a separation treatment on streams of dilute aqueous suspensions of cellulosic pulp with occasional high fiber loads, the advantageous versatility of the foam media provides efficient separation and retrieval of desirable fiber. This capability has been demonstrated on process sewer streams and is suited for use on various streams within the papermaking process such as on the weak black liquor stream; as a replacement for the brown stock washers (in the final stage where fiber consistency is raised) or as "deckers" for pulp thickening; in the bleachery sewer where it can be used to produce light pulp sheets or as a separate pretreatment step in the bleaching process to reduce chemicals required when excess bark, shives, dirt and other contaminants pass through the digesters and washers. It can be used any place there are diffusion washers, for example, on the dark pulp main process stream between the wash and screen devices. The real goal is to reclaim a fiber mat of desirable fiber and of high consistency and to permit the rest of the aqueous suspension of small contaminants and fiber parts to pass through the medium with a minimization or elimination of the need for foam medium regeneration. Comparative data with fourdrinier papermaking screen has shown the surprising results which are believed to be in part attributable to: (1) the minimization of hydraulic electrostatic attachment by triboelectricity of the small contaminants and undesirable fiber parts to open cell hydrophobic foam in the range of thickness of from 1/8" to 2" and the porosity range of from 40ppi to 80ppi; and (2) the capillary driving forces effected by open cell hydrophobic foam of this thickness and porosity range. The capillary action of the medium when used within the discovered advantageous parameters of thickness and porosity is best understood after considering factors discussed in an article by Anthony M. Schwartz in the Vol. 61, No. 1 edition of Industrial and Engineering Chemistry, entitled: "Capillarity Theory and Practice." The tribology and capillarity of 1/8" to 2 thick open cell hydrophobic foam with 40ppi to 80ppi porosity provides advantages which can be stated as follows: 1. Due to the openess of the foam, the feed stream can be filtered continuously at very low vacuum, (pressure differential), on the order of 0-10 inches of water as compared to the 140 inches of water vacuum required by typical papermaking process vacuum filters and four driniers. 2. Area flow rates through the foam medium of the invention are extremely high, up to thirty gallons per square foot per minute (30 gal./ft.2/min. or GFM) compared to the two to ten gallons per square foot per minute (2-10 gal/ ft.2/min. or GFM) typical of earlier foam separating media. 3. The hydrophobicity of the foam and the relatively small pore size result in the majority of desirable fiber remaining on the foam surface for retrieval without pre coating of the surface with a fiber mat as typically is necessary in papermaking filtration for fiber removal. 4. During catastrophic failure, the desirable fiber on the foam surface can be continuously retrieved in high con sistency form and stored for later use as wet lap or immediately returned to the process. The foam medium of the invention can be a thin layer of open cell compressible hydrophobic polyurethane with a thickness of from 1/8" to 2" and a nominal porosity of from 40 to 80 ppi. Manufacturer's tolerances on porosity typically are plus or minus ten percent (-10%). Other characteristics of the foam are as described in U.S. Patent Nos. 4,303,533 and 4,310,424. A distinct advantage of open cell hydrophobic foam is the efficiency provided by the cellular structure in regard to water "takeaway". Slow movement of filtrate results in inefficient use of subatmospheric pressure (vacuum) and is partially responsible for causing incomplete drainage of liquid from a pulp mat. This is explained in U.S. Patent No. 4,370,231. Hydrophobic foam in a porosity range of 40 ppi to 80 ppi and a thickness in a range of 1/8" to 2" has been found to provide excellent water take-away when compared to fourdrinier wire and thicker foam of greater ppi. The process and apparatus of the invention may include a rotating endless foam belt or drum cover subjected to a pressure differential on opposite sides thereof to produce a driving force for a feed stream. The feed stream is an aqueous suspension which under normal operating conditions contains small amounts of desirable fiber as well as undesirable small fiber parts and small contaminants of dirt and other materials. During catastrophic failure of upstream devices, high consistency fiber is present in the aqueous suspension. In one embodiment, the feed stream is introduced into a tank containing a rotating drum covered with the thin (1/8" to 2") foam medium of 40ppi to 80ppi porosity. Because of the pressure differential ( a P) on opposite sides of the medium, the tribology and the capillarity of the medium, the feed stream leaves the larger desirable fiber, which is the majority of fiber, on the foam surface and passes through the medium, carrying with it any small contaminants and undesirable fiber parts suspended therein. The stream, (filtrate), now separated from the desirable fiber, is withdrawn from the interior of the drum and reused in the papermaking system or discarded as waste in a sewer. The fiber is retrieved by being doctored or vacuumed off the surface of the foam or by a couch roll and returned to the process for reuse. Air or water showers or a vacuum device can be used to clean the surface of the foam prior to its reintroduction into the tank. Alternative embodiments of the process of the invention include the use of foam medium belt filters and drum belt washers, the latter acting as the primary separating stage for a pulp dryer. The subject invention thus provides an on-stream continuously operating, separation device of small relative size and high capacity for recovery of continuing random fiber losses or of high consistency fiber pulp resulting from catastrophic failure of upstream operating equipment. The above is accomplished with a minimum vacuum at low total energy and capital costs. Brief description of the drawings Figure 1 is a schematic elevational view of a drum type of foam separation device of the invention with a doctor blade and cleaning showers. Figure 2 is a view similar to Figure 1 of a drum type of foam separation device of the invention with a couch roll. Figure 3 is a view similar to Figure 1 of a belt type of foam separation device of the invention. Figure 4 is a qualitative analysis and theoretical comparison of driving forces believed existent in the foam separation devices of Figures 1 and 2 and in a wire covered drum type pulp thickener. Figure 5 is a graph of area flow rate in gal./ft.2/min. (GFM) through the foam media of Figure 2 at foam porosities of 45ppi, 65ppi and 80ppi and various foam thicknesses from 1/8 inch to 2 inches. Figure 6 is a graph of peripheral speed of foam (ft./min) versus foam thickness in inches and illustrates minimum flow resistances for foam of 45ppi, 65ppi, 80ppi. Figures 7a, 7b, 7c show qualitatively the apparent total volume flow for 45ppi, 65ppi and 80ppi foam media, respectively, when used with the Figure 2 apparatus which includes an expressing couch roll. Detailed description of the illustrated embodiment Figures 1 to 3 illustrate foam media separation devices or filters for use on a pulp or paper process stream. The devices can advantageously be utilized to reclaim and thicken fiber in dilute streams with occasional high fiber loading in a manner to be described hereinafter. Like numerals identify like parts and elements in the various views. The separation and thickening device 10 of Figure 1 includes a rotary drum 12 having a thin layer of open cell resilient hydrophobic foam 14 in a thickness range of from 1/8 inch to 2 inches (1/8" to 2"), preferably approximately 1 inch (1"), and a porosity in the range of from 40 pores per lineal inch to 80 pores per lineal inch (40ppi to 80ppi), preferably in the range from 65ppi to 80ppi. Other characteristics of the foam are as described in U.S. Patent Nos. 4,303,533 and 4,310,424. The feed stream or pulp slurry is a normally dilute aqueous solution of cellulosic pulp which routinely flows from the pulpmaking or papermaking processes and which contains small amounts of desirable fiber and small contaminants and small undesirable fiber parts except during occasional periods when high fiber loads from upstream catastrophic failures are present. The feed stream is introduced into a tank 16 containing the rotary drum 12 by means of inlet pipe 18. The stream is filtered as it passes through the foam 14, leaving the majority of the larger desirable fiber 20 on the foam surface. The foam passes the majority of the contaminants and small fiber parts with the liquid filtrate 22 which flows from the drum interior through outlet pipe 24. The difference in height between the outer liquid level in tank 16 and the inner liquid level of filtrate 22 produces a pressure differ ential A P. The drum type separation device of Figure 1 is provided with any conventional retrieval device such as a doctor 26 or an air knife or vacuum takeaway which removes the fiber mat from the foam surface. Showers 28 can be used to clean the foam surface, if desired. In comparison with other drum filters, the separation device of Figure 1 offers the following advantages: 1. Significantly higher area flow rates of the nature of 15 to 30 gal./ft.2/min. compared to the 10 to 20 gal./ft.2/min. achievable with a standard or typical gravity decker or vacuum thickener; 2. Higher fiber consistencies of the nature of 12 to 18 percent compared to 12 percent maximum obtained with typical deckers or thickeners. These advantages are believed to result for reasons to follow. Various points on the periphery of the foam media 14 of drum 12 in Figure 1 are labelled A through E. From points A to B in Figure 1, capillary action resulting from the foam's cellular structure and gross driving forces due to the pressure differential combine to begin filtration and disposition of desirable fiber on the foam surface. From B to C filtration continues, though at a declining rate as the fiber thickens on the surface to a higher consistency and its resistance to flow increases. From C to D, filtration continues at a lower rate. From D to E, the macroscopic and capillary CNP again combine to aid in dewatering the fiber mat and maintain its integrity at the foam's surface. Between E and F, capillary action alone is responsible for water removal from the fiber mat. These forces are analyzed in the middle column of Figure 4 where they are compared to a typical wire covered gravity decker in the column to the far right in Figure 4. The unique aspects of the foam separator or thickener of the invention can thus be noted as stated below. The capillary action associated with the foam's structure does not exist to any appreciable extent in the wire covered thickener. This lack of capillary driving forces in the wire adversely affects the total driving forcethrough- out the process and thus reduces the capability for high flow rate. The inherent resistance to flow of the typical thickener wire is higher than that of the foam within the disclosed porosity and thickness ranges, and these ranges due to their porosity and their void volume provide increased fluid takeaway and driving force throughout the process over that obtained in wire covered thickeners. The separation device 110 of Figure 2 includes a couch roll 126 which removes the fiber mat and which squeezes the foam 114 down to within approximately 1/8 inch of the drum 112 at peripheral location F. The separation device 110 thus has a macroscopic driving force at point F which adds to the total driving force and results in the expression of filtrate 122 through the foam. The qualitative comparison of separation device 110 to separation device 10 and to a typical wire covered gravity can be made by comparing the first column in Figure 4 with the other columns. Since the wire has no compressibility as compared to the foam, the impact of the pressurized couch roll is significantly less if it were to be used with wire in a typical wire covered pulp dewatering device. The removal of water from the foam structure by compression at point F frees a high volume of foam for additional water removal, this does not occur with the wire covering. Therefore, the consistency of the fiber will be higher with the Figure 2 foam thickener. Figure 3 illustrates a foam belt filter 210, and embodiment which utilizes a foam separation medium 214 having the proper porosity and thickness rotationally driven about rotating members 212a and 212b. The schematic drawing of device 210 shows that a feed stream tank 216 deposits a feed stream on foam belt 214 and a vacuum draws filtrate 222 into a reservoir 223 for removal through outlet pipe 224. The fiber mat 220 is retrieved by a doctor 226 from the surface of belt 214. Showers 228 may be provided to clean the belt surface after retrieval. Foam parameters which include the effective range of thickness and porosity are shown in Figure 5 to give the various apparent area flow rates in gallons per square foot per minute (gal./ft.2/min. or GFM) for a Figure 2 type of device. These show that a porosity in excess of 65ppi gives greater expected flow rates than a 40 or 45 ppi foam. Moreover, it has been found in this situation that fiber consistency increases with increasing thickness and decreasing pore sizes. The increase in consistency with greater thickness is believed, at least in part, to be a function of the increased capillarity and cell volume available for water transfer. The analysis of area flow rate versus foam thickness indicates that a maximum area flow rate exists at approximately one inch ( thickness. This maximum is also seen in Figure 6 when evaluating peripheral speed of a drum type foam separating device required to reach a given flow rate versus foam thickness. Since a reduced peripheral speed is equivalent to a lower resistance to flow, the least resistance is present in the one inch (1") foam. Additionally, the lowest resistance in Figure 6 is seen with the coarsest foam, 45ppi. There appears to be no real trend between the 65 and 80 ppi foam. It should be noted that the 45 ppi foams used in this analysis were from a "softer" formulation than the 65 and 80 ppi foams, which were somewhat stiffer. Figures 7a, 7b and 7c are prepared from data developed on a Figure 2 device which included a couch roll for retrieval. It is believed other retrieval methods which remove fiber from the foam would show qualitatively similar results. Theoretically, one would expect the highest flow rates, or lowest resistances, to occur with the thinnest foams due to the lower inherent resistance. This is, in fact, true in the Figure 2 system but the impact is masked by the volume of liquid which is introduced by expression with the couch roll 126. Figure 7c depicts the process for the 80ppi foam, as an example. The apparent volumetric flow is the actual filtrate flow per unit area removed from the filter each minute. The volume expressed is the calculated volume of liquid forces out of the foam by the retrieval means, i.e., couch roll 126, each minute. Therefore, the actual volumetric flow through the foam is the difference between the apparent flow and the expressed flow. As can be seen in Figure 7c, the actual volumetric flow through the foam does decrease with increasing thickness, as expected. These results suggest that continued removal of liquid from the foam increases both the volumetric flow out of the system and the maximum fiber consistency which can be obtained. Table I Dilute Softwood Pulp Aqueous Suspension (PH: Approx. 10-11; Temp.: Approx. 940 - 1060 F.) TSS = ppm Separation Gal/Ft2/Min Feed Filtrate' % Fiber Medium GEM GFM RPM Ft./Min. TSS TSS Consist. 1/2" 45ppi 41 17.6 1.2 4.08 412 51 11.1 1" 45ppi 41 16.1 1.0 3.67 340 1 11.9 2" 45ppi 44 17.8 1.0 4.19 408 63 14.3 1/8" 65ppi 40 15.7 2.0 6.41 381 69 13.2 1/2" 65ppi 41 18.5 1.6 5.44 474 59 13.6 1" 65ppi 41 18.9 1.4 5.13 370 74 14.9 2" 65ppi 43 16.5 1.5 6.28 558 15 17.0 1/8" 80ppi 42 17.4 1.7 5.45 625 92 12.7 1/2" 80ppi 40 18.0 1.5 5.10 539 96 14.9 1" 80ppi 44 18.7 1.5 5.50 531 19 15.6 2" 80ppi 44 17.5 1.3 5.45 595 30 18.0 Fourdrinier 42 17.5 2.0 6.28 611 - 14.5 Wire Table I shows typical values obtained from various foam separation media on a Figure 2 device. The foam porosities ranged from 45 to 80ppi and the thickness from 1/8 inch to 2 inches. Fourdrinier wire, which is much more expensive to use and which has greater takeaway and retrieval problems than foam, is also shown. The feed stream for this table was made up using softwood fiber in an aqueous suspension with a PH in the range of approximately 10 to 11.4 and a temperature of approximately 940 to 1060 F. The "GPM" column is gallons per minute; "GFM" is gallons per square foot per minute; "RPM" is revolutions per minute of the drum; "ft./min.11 is peripheral speed in feet per minute; "Feed TSS" is the feed stream total suspended solids in parts per million (ppm); "Filtrate TSS" is in parts per million (ppm); and, "% Fiber Consist is of the recovered fiber from the medium surface (1% equals 10,000 ppm). The vacuum for Tables I, II and III, and IV was approximately 7 to 9 inches (water). Feed stream differences are because the material was drawn from the made up stock at different times with different settling and other factors having occurred and the instantaneous samples taken may have been of an insufficient number to give a true average. Table II Main Pulp Mill Process Sewer of 502 to 898 ppm Fiber (LPH: Approx. 10.4-10.8; Temp: Approx. 990 F.) TSS=ppm Separation ca1/Ft2 /Min Feed Filtrate % Fiber Medium GEM ¯M RPM Ft./Min. TSS TSS Consist. In 60ppi 20 10.5 2.4 8.82 813 65 10.6 2" 40ppi 25 9.5 1.0 4.19 521 60 10.3 Table III Alkaline Bleach Sewer of 286 tp 336 ppm Fiber (PH: Approx. 11.2-11.5; Temp.: Approx. 1130 F.) TSS = ppm Separation Cal/Ft2 /Min Feed Filtrate % Fiber Medium GEM GFM RPM Ft. /Min. TSS TSS Consist. 2" 60ppi 25 9.5 .7 2.93 286 22 10.6 1" 40ppi 25 10.5 .3 1.26 336 0 7.9 The actual recovered fiber from the pulp mill sewer stream of Table II had the following analysis: RUN Fiber Content: 1" 60 ppi 2" 40 ppi % Hardwood 31 NA % Softwood 69 NA Freeness: 688 744 Viscosity: 40.0 30.3 Permanganate No.: 21.3 19.2 Fiber Length: % + 20: 57.4 41.6 % + 35: 20.3 22.4 % + 65: 10.3 14.0 % + 150: 3.1 5.8 % - 150: 8.9 16.2 The actual recovered fiber from the bleach plant sewer stream of Table III had the following analysis: BOTH RUNS Fiber Content: % Hardwood 93 % Softwood: 7 Freeness: 637 Viscosity: 25.6 Brightness: 56 Permanganate No.: 2.1 Fiber Length: % + 20 3.2 % + 35 38.8 % + 65 24.3 % + 150 7.4 - -150 26.3 Subsequent to the preparation of the Table I, II and III data for this specification, it was determined through recalibration of the flow meter that the flow rate (GPM and GFM) data presented in Tables I, II and III and Figures 5, 6, 7a, 7b and 7c were understated by 37%. This in no way changes the results or conclusions contained in this specification, but rather enhances the effectiveness of the separation method. Table IV Alkaline Bleach Sewer of 178 to 374 ppm Fiber (pH: Approx. 10.3; Temp: Approx. 1190 F; RPM: 2.5; Ft./Min.: 9.2) Separation Time GFM Feed Filtrate % Fiber Medium (Hrs) GEM (Gal. /Ft 2 /Min. ) TSS TSS Consist. 1 n 65 ppi 1.5 59 26.6 360 32 1.2 42 63 27.9 294 80 1.5 98 62 27.4 178 8 0.5 115 62 27.4 374 76 1.1 140 69 30.5 312 26 0.6 The experimental results which are presented in Table IV were obtained principally to demonstrate time consistency of the system at high flow rates and efficent suspended solids removal. The fiber consistency was not controlled to obtain high levels in these experiments. Recovery of suspended solids from the pulp mill bleach plant sewer systems of Tables II, III and IV using the foam filter typically exceeds 90%, including substantially 100% of the desirable long fiber. This is significant because these streams typically handle between 6.7 and 20.5 tons of fiber per day. Recovered fiber consistencies were good and analysis of the recovered fiber, including freeness, viscosity, permanganate number, and fiber length, were all in the normal range for desirable long fiber.

Claims: WHAT IS CLAIMED IS: 1. An efficient method of treating normally dilute aqueous suspensions of cellulosic pulp occasionally containing high pulp loads to improve pulp consistency and retrieve desirable fiber which includes maximizing volumetric flow of the suspension through an open cell hydrophobic foam separation medium to effect maximum mechanical separation of desirable fiber from the suspension and from small contaminants and undesirable fiber parts therein while minimizing hydraulic electrostatic attach ment to the separation medium of the small contaminants and undesirable fiber parts, said method comprising: : providing an open cell hydrophobic foam separation medium of a thickness of from one eighth inch to two inches and a porosity in excess of forty pores per lineal inch, subjecting said foam separating medium to a pressure differential and to a stream of said normally dilute aqueous suspension of cellulosic pulp occasionally containing high pulp loads thereby creating a flow of aqueous suspension including any small contaminants and undesirable fiber parts into and through said medium and a mat of desirable fiber on the surface of said medium, retrieving said desirable fiber from the surface of said medium. 2. The method of claim 1 in which the porosity is within the range of forty pores per lineal inch to eighty pores per lineal inch. 3. The method of claim 1 wherein the stream to which the foam medium is subjected contains fiber in excess of one hundred seventy-eight parts per million. 4. The method of claim 1 in which the foam thickness is between one-half and two inches. 5. The method of claim 1 in which the foam thickness is substantially one inch. 6. The method of claim 1 in which the foam element is rotated. 7. The method of claim 1 in which the foam element is mounted on a drum. 8. The method of claim 7 in which the retrieving is performed by means including a couch roll. 9. The method of claim 7 in which the pressure differ ential is created by a foam medium mounted on a drum within a feed stream. 10. The method of claim 7 in which the drum is rotated at a peripheral speed no faster than nine and one-half feet per minute. 11. The method of claim 1 in which the foam medium is a rotating filter belt. 12. An efficient method of treating dilute aqueous sus pensions of cellulosic pulp occasionally containing high pulp loads to improve pulp consistency which includes maximizing volumetric flow of the suspension through a rotating endless compressible hydrophobic open cell foam separation medium to effect maximum mechanical separation of desirable fiber from the suspension and from small contaminants and undesirable fiber parts therein while minimizing hydraulic elec trostatic attachment to the separation medium of the small contaminants and undesirable fiber parts, said method comprising: : providing a rotating endless compressible hydrophobic open cell foam separation medium of a thickness of less than two inches and a porosity of more than forty pores per lineal inch, subjecting a portion of said rotating foam separating medium to a stream of said dilute aqueous suspension of cellulosic pulp under pressure thereby creating a flow of aqueous suspension including small contaminants and undesirable fiber parts into and through said medium portion and a mat of desirable fiber on the surface of said medium portion, removing said medium portion from said stream, compressing said portion of said separating medium by means of a couch roll to retrieve said desirable fiber from the surface of said medium portion, and to express said aqueous suspension including small contaminants and undesirable fiber parts which remain in the separating medium through said medium as expressate, continuing to subject additional portions of said foam separating medium to said stream under pressure while continually removing and com pressing other medium portions and retrieving desirable fiber. 13. The method of claim 12 in which the foam medium has a porosity within the range of from forty to eighty pores per lineal inch and a thickness of from one eighth inch to two inches thickness.

Inventors: FREMONT, HENRY A., STIFFLER, MARY C.
Applicants: CHAMPION INTERNATIONAL CORPORATION
Application year: 1984
Main classification: B01D33
IPC codes: D21D5, D21C9, B01D33