ULTRAFAST ROASTED COFFEE

Abstract: Disclosed herein is a coffee product which when brewed is characterized by having a reduced bitterness and improved brew holding quality. The coffee product is produced by an ultrafast roasting process wherein a blend of green coffee beans is roasted to a specific color preferably using a fluidized bed roaster at temperatures of from about 550°F (288°C) to about 750°F (399°C) for 30 to 120 seconds. The roasted coffee is quenched with air or inert gas, and ground or flaked.

Description: ULTRAFAST ROASTED COFFEE Related Application This is a continuation-in-part application of Serial Number 516,414, filed July 22, 1983. Technical Field This invention relates to an improved coffee product having increased extractability which when brewed is characterized by reduced brew bitterness and improved brew holding quality on heating. This invention also relates to a method for the preparation of the improved coffee product. Background of the Prior Art In order to develop the aroma and flavor of the green coffee bean, the coffee must be roasted. Over the years various techniques of roasting coffee to improve the flavor, the extractability and the aroma have been developed. These include both batch processes where coffee is roasted in portions and then cooled or quenched, as well as continuous roasting processes where coffee is continuously fed to a roaster and cooling unit. The flavor and aroma developed in the coffee bean depend largely upon the color to which the green bean is roasted. Lighter roasted coffees generally have a milder flavor and aroma, while darker roasted coffees generally have a stronger or more hearty flavor and aroma. Each species of coffee bean also develops a different flavor when roasted. To achieve proper color development, the roasting process must be carefully controlled. Green coffee must be heated to a temperature above 300CF (149 C) for roasting to occur. In typical commercial processes the green coffee is roasted to a temperature from about 4000F (204to) to about 450 F (2320C) in a period of 3 to 15 minutes. The length of time the coffee is heated affects the product density, moisture content and extractability. A fast-roasted coffee. i.e. roasted in less than 5 minutes, is generally less dense than longer roasted beans because the cell structure of the bean is expanded to a greater degree. Fast-roasted coffees also generally provide a larger yield of brew solids, i.e. they are more extractable than coffee which is roasted more slowly. This is because the greater expansion of the coffee bean cell structure renders the internal coffee bean cell walls more porous, thus allowing easier entry of brewing water into the cells and easier egress of the dissolved brew solids out of the cells. One technique of fast-roasting coffee has been fluidized bed roasting wherein the coffee can be roasted at times of from about 30 seconds to 3 minutes. Canadian Patent 989,246, issued to Bergeron s Schlichter (1976) describes a coffee which has been air fluidized bed roasted in from 30 seconds to 3 minutes. The coffee beans are roasted at a bed temperature of 5500 to 6500F (2880 to 3430C) and air cooled. The coffee is then flaked to a thickness of 5 to 30 mils. This coffee was used for single serving brewing in a packet such as a tea bag. U.S. 4,169,164 issued to Hubbard et al. (1979), and U.S. 4,322,447 issued to Hubbard (1982) describe processes for roasting coffee in a fluidized bed roaster having 2-stages. In the '164 patent the coffee is partially roasted at 440cm to 4700F (2270 to 2430C) and then finished roasted at 5150 to 5450F (2680 to 2850C), to a dark brown color. In the '447 patent the beans are roasted at the same temperature in both stages, about 5500 to 5700F (2880 to 2990C). The beans are cooled to form a low density roasted coffee having high soluble yields. The roasting time is 3 to 4 minutes. Both of these coffees are said to havea increased extractability or higher yield of brew solids. With the advent of the automatic drip coffee maker, coffee is often held in both the home and the office on a warming plate for extended periods of time. During this holding time the coffee develops bitter off-flavors and burnt notes. This is partially due to the evaporation of the water and of volatile coffee aroma components during the long heating time, and also to chemical reactions between the brew components which occur during this prolonged heating. The discovery of a roast and ground coffee which would provide a brew which could be held for extended periods of time without a significant change in flavor is highly desirable. Surprisingly, it has been found that such a product can be prepared. The product is characterized by higher levels of sucrose, a higher ratio of 3-caffeoylquinic acid to caffeine, increased dry headspace aroma, increased extractability of the brew solids. and a lower ratio of quinic acid to 3-caffeoylquinic acid when compared to conventionally processed coffee. The brew obtained from this product is characterized by lower total acid levels, and more low molecular weight compounds in the brew solubles than conventional coffee brews. This unique coffee is prepared by processing a single grade or blend of grades of green coffee beans or green decaffeinated coffee beans under very carefully defined roasting, quenching and grinding conditions which results in less flavor degradation or volatilization. It is an object therefore of this invention to provide a cotfee product which upon brewing is less bitter and has a better holding quality than conventionally prepared coffees. It is a further object of this invention to provide a novel, ultrafast roasting process for the preparation of this coffee. These and other objects of this invention will become obvious from the description herein. Brief Summary of the Invention This invention relates to a roast and ground coffee product characterized by its thigh level of sucrose, higher ratio of 3-caffeoylquinic acid to caffeine, high extractability of brew solids, and low ratio of quinic acid to 3-caffeoylquinic acid. The coffee brew prepared from this product has more low molecular weight components in the coffee brew solubles than conventional coffee brews. The coffee brew of the present invention is characterized by reduced bitterness and improved holding quality. The process for preparing this coffee involves roasting a single grade, or preferably a blend of different grades of green coffee beans in from about 30 to about 120 seconds, at temperatures of from 5500F (2880C) to about 7500F (3990C), preferably in a fluidized bed roaster. The coffee is roasted to a Hunter "L" color of from about 19 to about 23 in such a way that the surfaces of the roasted coffee beans are not more than 10 Hunter II "L" units different in color from the average color throughout the beans. The roasted coffee is quenched with air or inert gas to a temperature less than 3000F (1490C) and then cooled with air or inert gas to from about 50 F (100C) to about 1000F (380C). The coffee is subsequently ground such that the overall color of the ground coffee is from about 19 to about 23 Hunter "L" units, or preferably flaked to an average thickness of about 0.01 to about 0.02 inches (.25 to .51 mm.) such that the overall color of the flaked coffee is from about 19 to about 25 Hunter "L" units. Description of the Figures Figure 1 depicts a liquid chromatogram of the coffee of the present invention when freshly brewed. Figure 2 depicts the chromatogram of Figure 1 between points A and B. Figure 3 depicts a liquid ch romatog ram of the decaffeinated coffee of the present invention when freshly brewed for the interval between points A and B as shown on Figure 1. Figure 4 depicts a liquid chromatogram of conventionally processed coffee when freshly brewed for the interval between points A and B as shown on Figure 1. Figure 5 depicts a liquid chromatogram of the coffee of the present invention after the brew has been heated for one hour for the interval between points A and B as shown on Figure 1. Figure 6 depicts a liquid chromatogram of the decaffeinated coffee of the present invention after the brew has been heated for one hour for the interval between points A and B as shown on Figure 1. Figure 7 depicts a liquid chromatogram of conventionally processed coffee after the brew has been heated for one hour for the interval between points A and B as shown on Figure 1. Definitions The terms "coffee" or "coffee product" as used herein comprise dry roast and ground coffee or dry roast, ground, and flaked coffee. The terms "coffee brew" or "coffee beverage" as used herein comprise liquid coffee as normally consumed after brewing of dry coffee with water. The term "3-caffeoylquinic acid" as used herein comprises the predominant isomer of chlorogenic acid. Other terms will be defined as used hereinafter. Detailed Description of the Invention Roast and ground coffee products presently available in the marketplace comprise various blends of different grades of coffee. The differing grades of coffee are classified in the art as low, intermediate and high. The low quality coffee are the Robustas, low grade Naturals such a Haiti XXX, Peru Natural, Salvadors, low grade Brazils, and low grade unwashed Arabicas such as the Ugandas, Indonesians, Ivory Coast, Dominican Republic, Ecuador, Resacas and Guatemalan TMS. They are generally described as having rubbery flavor notes and produce brews with strong distinctive natural flavor characteristics often noted as bitter. Suitable intermediate quality coffees are the Brazilian coffees such as Santos and Paranas, African Naturals, and brazil free from the strong Rioy flavor such as good quality Suldeminas. intermediate qualities are characterized as having bland, neutral flavor and aroma, lacking in aromatic and high notes, and are generally thought to be sweet and non-offensive. High grown coffees such as the good quality Arabicas and Colombians are characterized in terms of. natural flavor and aroma described as having "excellent body", "acid", "fragrant", "aromatic" and occasionally "chocolatey". Examples of typical high quality coffees are "Milds" often referred to as high grade Arabicas, and include among others Colombians, Mexicans, and other washed Milds such as strictly hard bean Costa Pica, Kenyas A and B, and strictly hard bean Guatemalans. Generally, roast and ground coffees contain a blend of all three classes of coffees. Blending is utilized to emphasize the desirable characteristics of each grade of coffee. Some strong body notes characteristic of the low grade coffees are desirable, as well as some fragrant and aromatic notes characteristic of high grown coffees. Intermediate grade quality coffees typically contribute to the overall taste impact and body ot the coffee. The coffee product of the present invention is prepared from a single grade, or preferably from a blend of grades of green coffee beans or green decaffeinated coffee beans. Processing Conditions The unique coffee of the present invention is prepared under carefully defined roasting, quenching, and grinding conditions. The particular processing parameters result in less flavor degradation or volatilization. Green coffee beans having an initial moisture content of from about 8% to about 14% by weight are metered into a roaster which is capable of forming a fluidized bed of green coffee beans. Suitable roasters for this purpose include the jetzonee roaster manufactured by Wolverine (United States) and the Probate roaster manufactured by Probat-Werke (Germany). Any fluidized bed roaster can be used. Any other roasting equipment which causes a rapid heating of the bean such as that achieved through fluidization can be used. The green coffee beans are then roasted in from about 30 to about 120 seconds, preferably in from about 45 to about 90 seconds and most preferably in from about 60 to about 75 seconds using air or another fluidizing heat exchange medium having a temperature of from about 5500F (2880C) to about 7500F (3990C) and preferably a temperature of from about 6000F (3160C) to about 6750F (3580C). In a preferred mode, air, which has been heated by contact with a natural gas or oil fired burner, is directed downward through tubes into a flowing stream of coffee beans onto a surface and reflected back upwards through the beans, thereby fluidizing and roasting the beans. The beans can also be mechanically agitated in addition to the agitation caused by the fluidizing gases. The green coffee is roasted to an average color of from about 19 to about 23 Hunter "L" units, preferably from about 20 to about 22 Hunter "L" units. The individual coffee beans must be roasted uniformly such that a color difference of about 10 Hunter "L" units or less, and preferably no more than about 3 Hunter "L" units, exists between the outer surfaces of the beans and the average color throughout the beans. Additionally, individual coffee beans of comparable grade and size must not vary in color from each other by more than about 10 Hunter "L" units, and preferably by not more than about 3 Hunter "L" units. This roast color criticality is usually measured on the roasted, quenched and cooled coffee beans prior to subsequent processing into a finished coffee product. The roasted coffee beans must be quickly quenched to keep the color from developing further. The roasted coffee beans are "quenched", i.e. the roasting process is stopped, by lowering the temperature of the beans to below about 3000F (14YC) in about 20 seconds. In a preferred mode, filtered air haviny a temperature of not more than about 1000F (380C) and preferably not more than about 800F (270C) is directed downward through tubes into a flowing stream of roasted coffee beans, thereby fluidizing and rapidly cooling, i.e. quenching them to below about 2700F (1320C) in about 10 seconds or less. The roasted and quenched coffee beans are further cooled to below about 1000F (380C) in not more than an additional 100 seconds and preferably in not more than an additional 50 seconds. It is critical to the production of the unique product described herein that the coffee be quenched using air or an inert gas such as nitrogen, carbon dioxide or helium. Water quenching, as and to the extent practiced in the industry, will not produce the unique product herein. In some instances, it may be desirable to increase the moisture level in the roasted coffee prior to subsequent processing. This may be desirable to control dust, static electricity and particle size distribution in subsequent grinding and conveying operations. If moisture is to be added to the roasted beans, it must be added after the beans are cooled to less than about 2000F (930C), and preferably to less than about 1600F (710C). During both roasting and cooling the preferred bed depth for the fluidized bed is from about 1 to about 4 inches (2.5 to 10.2 cm.). A suitable feed rate through a roaster would be of the order of from about 5500 to about 10,000 pounds of coffee/hour (2500 to 4525 kg. of coffee/hour). The level of fluidization during roasting is approximately 9 to 14 pounds (4 to 6 kg.) of hot air per pound (.454 kg.) of green coffee per minute, while that during quenching is approximately 15 to 20 pounds (7 to 9 kg.) of air per pound (.454 kg.) of roasted coffee per minute. The roasted coffee beans are then ground. Any conventional coffee grinder can be used. Depending upon the specific particle size distribution desired in the final product of the present invention, the coffee fractions can be ground to the particle size distributions or "grind sizes" traditionally referred to as "regular", "drip", or "fine" grinds. The standaras of these grinds as suggested in the 1948 Simplified Practice Recommendation by the*U.S. Department of Commerce (see Coffee Brewing Workshop Manual, page 33, published by the Coffee Brewing Center of the Pan American Bureau) are as follows: "Regular grind": Sieve (Tyler) Wt. % on iLl-mesh 33% on 28-mesh 55% through 38-mesh 12% "Drip grind": Sieve (Tyler) Wt. 96 on 28-mesh 73% through 28-mesh 27% "Fine grind": Sieve (Tyler) wt. % through 14-mesh 1008 on 28-mesh 708 through 28-mesh 30% Typical grinding equipment and methods for grinding roasted coffee beans are described, for example, in Sivetz s Foote, "Coffee Processing Technology", Avi Publishing Company, Westport, Connecticut, 1963, Vol. 1, pp. 239-250. The color of the final product, when ground, should be from about 19 to about 25 Hunter "L" units. For decaffeinated coffee the final product color is also from about 19 to about 25 hunter "L" units. The cooled roasted coffee beans can also be milled to provide a flaked coffee which has even greater extractability. In the step of roll milling the roast and ground coffee to produce a flaked coffee, it has been found important to control several processing variables: (1) coffee feed temperature, (2) roll surface temperature, (3) roll diameters, (4) static gap, (5) the roast and ground coffee feed moisture content, t6) feed rate, (7) roll peripheral surface speed, (8) roll pressure, and (9) the mill feed particle size distribution. The process of the present invention can be practiced with the aid of any of a variety of roll mills of various roll diameters capable of subjecting roast and ground coffee to mechanical compressing action and adapted to the adjustment of roll pressure, roll speed and roll temperature. Suitable mills are those having two parallel rolls such that coffee particles passed between the rolls are crushed or flattened into flakes. Normally, smooth or highly polished rolls will be employed as they permit ready cleaning; other rolls can, however, be employed if the desired flaking effects can be obtained. The temperature of roast and ground coffee when fed into the mill rolls should be about 350F (20C) to about 700F (210C). Maintenance of the coffee feed temperature along with maintenance of the roll surface temperature within the ranges given below insures that aroma losses during the roll miliing step are sufficiently reduced such that the resultant flaked coffee has an aroma level sufficient to provide the desired initial aroma level for flakes of all thicknesses. Control of the surface temperature of each roll has been found to be important to the provision of flaked roast and ground coffee of high extractability. Roll surface temperature, as used herein, is measured in degrees Fahrenheit and refers to the average surface temperature of each roll of the roll mill. The rolls can be operated at differential operating temperatures. However, operation under conditions of differential roll temperatures is not preferred. Best results are obtained when each roll is operated at the same temperature. The surface temperature of each of the respective rolls can be controlled in a known manner. This is usually accomplished by control of the temperature of a heat exchange fluid passing through the inner core of the rolls. Roll surface temperatures within the range of from about 500F (100C) to about 800F (270C), preferably between about 600F (160C) and about 700F (210C) are used herein. In general, higher roll surface temperatures produce flakes of roast and ground coffee which typically have undesirably low levels of aroma. Lower roll surface temperatures require elaborate cooling systems and therefore higher costs. The diameter of the mill rolls controls the angle of entry into the nip which in turn affects flake thickness and bulk density. Best results are obtained from mills having diameters in the range of from about 6 to about 30 inches (15 to 76 cm.). Examples of suitable mills which can be adapted in a known manner to operate within the parameters defined hereinbefore include any of the well-known and commercially available roll mills such as those sold under the tradenames of Lehmann, Thropp, Ross, Farrell and Lauhoff. As used herein1 the term "mechanical static gap" represents that distance separating the two mill rolls along the line of nip while at rest and is typically measured in mills. One mil is equal to 0.001 inch. "Nip" is a term used in the art to define the length of surface contact between two rolls when the rolls are at rest. To illustrate, it can be thought of as a line extending the full length of two cylindrical rolls and defining the point or line of contact between two rolls. A special condition of roll spacing is "zero static gap" which is used herein to indicate that the two rolls are in actual contact with each other along the line of nip when the roll mills are at rest. Because of the deflecting action of the cotfee feed as it passes through the roll mill, the static gap setting must be less than the desired flake thickness. Suitable static gap settings range from 0 (i.e., from a zero gap setting) up to about 5 mils, 0.005 inch. Suitable flake thickness is from about 8 to about 25 mills, preferably from about 12 to about 20 mils. The feed rate into the roll mill is to be distinguished from the throughput rate of the roll mill. The feed rate to the roil mill is that amount of material per hour per inch of nip which is fed into the nip area. The throughput rate is the amount of material per hour per inch of nip that actually passes through the roll mill. when the feed rate exceeds the throughput rate, a condition occurs which is referred to in the art as "choke feeding". Conversely, when the feed rate falls below the theoretical throuyhput rate, the feed rate and throughput rate are the same. This condition is referred to in the art as "starve feeding". Starve feeding offers particular process advantages such as increased equipment life and increased process flexibility and is, therefore, the suitable mode of operation in the method of the present invention. Control of the peripheral surface speeds of the rolls has also been found to be important to the provision of the present flaked coffee. The roll peripheral surface speed is measured in feet per minute of roll surface circumference which passes by the nip. Generally, the roll mill should be operated at a roll speed of from about 470 ft./min. to about 1880 ft./min. (143 to 513 meters/min.), preferably from about 1050 ft./min. to about 1550 ft./min. (320 to 472 meters/min.). For a given set of roll mill operating conditions, the throughput rate, the roll peripheral surface speed and the thickness of the flaked coffee produced are closely related. In the production of flaked coffee of a specified thickness, the throughput rate is directly related to the roll peripheral surface speed. Thus, an increase in the roll peripheral surface speed allows an increase in the throughput rate in producing flakes of specified thickness. When a constant throughput rate is maintained (e.g., by controlling the feed rate), higher roll peripheral surface speeds produce thinner flakes and conversely, lower roll peripheral surface speeds produce thicker flakes. As the roll peripheral surface speeds increase to greater than about 1700 ft./min. (518 meters/min.), the production of undesirably high levels of fines begins to occur. !moreover, high peripheral surface speeds promote temperature increases which can alter and degrade the flavor of the roast and ground flakes produced chile peripheral surface roll speeds have been set forth in connection with operation of a roll mill to provide flaked coffee of improved extractability, it will be appreciated that optimal speeds will be determined in part by the other roll mill conditions such as the size of the rolls employed, the static gap setting, etc., as well as the physical and organoleptic properties desired in the flaked product. Roll pressure will also influence the nature of the coffee flakes obtained by the process of the present invention. Roll pressure is measured in pounds per inch of nip. To produce the present flaked coffee product in high yield, roll pressures should be within the range of from 150 Ibs./linear inch of nip to 4,000 Ibs./linear inch of nip (27 kg./cm. of nip to 714 kg./cm. of nip), and preferably within the range of from 1,000 Ibs./linear inch of nip to 2,000 Ibs./linear inch of nip (178 kg./cm. of nip to 357 kg./cm. of nip). In general, operable feed rates are directly related to the roll pressure. Thus, higher roll pressure allows a higher feed rate to the roll mill to produce a flake of specific thickness for otherwise equivalent operating conditions of the roll. Roll pressure can also be used to fine tune finished product density, e.g., lower roll pressure results in slightly lower density. The disadvantages of using higher roll pressures are primarily mechanical, e.g., more expensive equipment is needed to produce higher roll pressures. Conversely, at low roll pressures, the feed rate can drop below commercially desirable rates. The particle size distribution of the roll mill feed of roast and ground coffees has an effect on the particle size distribution of the resultant flaked coffee product of the present invention. A coarse mill feed particle size distribution causes the final flaked product to have a coarser particle size distribution than if the mill feed particle size distribution had been finer. Therefore, depending upon the specific particle size distribution desired in the final product, the coffee can be "ground" to meet the specifications. The ranges that are suitable for use and the preferred ranges for mill feed particle size distribution in this invention are: Preferred Sieve Size Weight % of Weight % of (U.S. Standard) the Composition the Composition remains on 12 40 - 80 45-55 through 12, 20 - 50 25-35 remains on 16 through 16, remains on 20 0 - 20 5-10 through 20, remains on 30 0 - 10 0-5 through 30 0 - 10 0-5 The Coffee Product The coffee product herein is characterized in having a higher level of sucrose, a higher ratio of 3-caffeoylquinic acid to caffeine, a greater extractability, more aroma, a lower ratio of quinic acid to 3-caffeoylquinic acid, and a lower density, than the same coffee product which is roasted to the same average color in 3 minutes or longer using either a conventional batch or a continuous roaster. The coffee product of the present invention contains a minimum of 0.5% by weight sucrose, and 0.3% if decaffeinatea, typically about 0.8%, and 0.5% if decaffeinated. In comparison, conventionally processed coffees have an average sucrose content of about 0.3% or less if undecaffeinated and is not detectable if decaffeinated. Sucrose is naturally present in green coffee beans and the higher level results because of less degradation during processing. The undecaffeinated coffee of the present invention has a minimum ratio of 3-caffeoylquinic acid to caffeine of 0.98, and the ratio is typically about 1.1. Conventional coffees have a ratio of about 0.84 to about 0.94. The caffeine content of the undecaffeinated coffee of the present invention is a minimum of 1.05% by weight. If the coffee has been decaffeinated, usually 97% by weight of the caffeine has been removed. The greater extractability of the coffee of the present invention is demonstrated by a higher level of brew solids in the brewed coffee. The claimed coffee, when brewed, typically has a brew solids from about 5% to about 259s higher than conventional coffees when brewed. In addition, the claimed coffee has a maximum ratio of quinic acid to 3-caffeoylquinic acid of 0.60, and the ratio is typically about 0.54. Conventional coffees have a ratio of about 0.76 or higher. The claimed coffee when decaffeinated likewise has a lower ratio of quinic acid to 3-caffeoylquinic acid than conventional decaffeinated coffees. The claimed coffee has more aroma on a per gram basis than conventionally processed coffees. The coffee product of the present invention has an aroma as determined by gas chromatography of about 25% to about 408 stronger than that of conventionally processed coffee. The decaffeinated coffee of the present invention has an aroma about 78% stronger than the leading commercially available decaffeinated coffee. The tamped density of the claimed coffee product when flaked ranges from about 0.350 g./cc. to about 0.410 g. icc. The tamped density of the claimed coffee when ground ranges from about 0.340 g./cc. to about 0.355g.icc. The coffee brew obtained from the product herein has lower total acidity, and more low molecular weight components in the coffee brew solubles than conventional coffee brews. The titratable acidity per 1% brew solids of the coffee brew of the present invention is a maximum of 4.7. That of conventional coffee brews is about 4.8 to about 5.8. For the decaffeinated coffee of the present invention the titratable acidity is about 3.5, comparable to other decaffeinated coffees. The higher level of lower molecular weight components in the coffee brew solubles of the claimed coffees as demonstrated by Figures 1 through 7 is consistent with its higher sucrose levels. Generally, low molecular weight compounds contribute more to fravor and aroma. The most important attributes of this coffee brew are reduced bitter flavor and better holding quality. Moreover, this coffee beverage, when held on heat for 1 hour is not significantly different in flavor than the same coffee beverage freshly brewed. This improved holding quality has been confirmed by expert taste panelists who found a greater degree of difference between the taste of freshly brewed and 1-hour old conventionally processed coffee than between freshly brewed and 1-hour old coffee of the present invention. The coffee brew of the present invention has a maximum degree of difference of 0.50, typically about 0.40. The degree of difference for conventional coffee brews is about 0.53 or greater. The characteristics of the coffee produced by the process herein and of the coffee brew prepared from it are summarized in Table I. All percents are by weight unless otherwise stated. Decaffeinated coffee has similar characteristics except for those involving caffeine or where noted. Table I Decaffeinated Component Coffee Coffee Sucrose, % Minimum of 0.5 Minimum of 0.3 Ratio of Minimum of 0.98 3-caffeoylquinic acid to caffeine Caffeine, % Minimum of 1.05 Ratio of quinic Maximum of 0.60 Maximum of 0.96 acid to 3-caffeoylquinic acid Extractability, brew Minimum of 0.93 Minimum of 0.70 solids, % Aroma 25% to 40% 78% stronger stronger than than conventional conventional Tamped density, 0.340 to 0.410 0.340 to 0.410 g./cc. Decaffeinated Component Coffee Brew Coffee Brew Titratable acidity, Maximum of 4.7 Average of 3.5 normalized Hold equality, degree Maximum of 0.50 Maximum of 0.50 of difference While not wishing to be bound by theory, it is believed that the higher level of sucrose and of 3-caffeoylquinic acid in the coffee are responsible for the less bitter quality and lower acidity level. By having a coffee which contains more 3-caffeoylquinic acid, it is indicative that the acid has not decomposed to quinic acid and phenols to the extent it has in coffee that has been processed in a conventional manner thereby producing bitter materials in the brew. Furthermore, caffeine, a known bitter substance, is found to be at lower levels in coffee brewed from this product. The higher level of low molecular weight materials is indicative of the presence of more sugars such as sucrose in the product. These sugars have not had a chance to polymerize, decompose to acid substances, or participate in reactions with amino acids (browning or Maillard reactions) to the same degree as occurs in conventional roasting methods. Additionally, the higher levels of these sugars may contribute to a milder tasting, less bitter beverage. Testing and Evaluation I. The following test was performed on the roasted, quenched, and cooled coffee beans prior to grinding or flaking, and also on the final ground or flaked product. A. Roast Color The Hunter Color scale values, utilized herein to define a preferred color of a ground or flaked coffee product, are units of color measurement in the Hunter Color system. That system is a well-known means of defining the color of a given material. A complete technical description of the system can be found in an article by R. S. Hunter, "Photoelectric Color Difference Meter", Journal of the Optical Society of America, Vol. 48, pp. 985-95, 1958. lJevices specifically designed for the measurement of color on the Hunter scales are described in U.S. Patent No. 3,003,388 to Hunter et al., issued October 10, 1961. In general, Hunter Color "L" scale values are units of light reflectance measurement, and the higher the value is, the lighter the color is since a lighter colored material reflects more light. In particular, in the Hunter Color system the "L" scale contains 100 equal units of division; absolute black is at the bottom of the scale (L = 0) and absolute white is at the top of the scale (L = 100). Thus in measuring Hunter Color values of the coffee of this invention, the lower the "L" scale value the darker the coffee. The "L" scale values described herein are also accurate means of defining the degree of roast necessary to produce a coffee which when ground or flaked gives a product within the "L" scale values herein described. Determination of optimum roasting conditions varies with the coffee employed but is within the skill of one knowledgeable in the field and can be determined after a few Hunter Color measurements of degrees of roast and comparison of the roasted and ground color values with the roasted ground and flaked color values. II. The following tests were performed on the ground or flaked coffee processed in accordance with this invention prior to brewing to prepare a coffee beverage. A. Sucrose Sucrose was determined using the method described in 6robust, Cereal Chem., 43, p. 35-43, 1966, as modified according to "Methods of Silylation", p. 182-184, Pierce Handbook and General Catalog, Pierce Chem. Co., Rockford, 111. (1978), with a detection limit of 0.2%. B. Caffeine and 3-Caffeoylquinic Acid The levels of caffeine and 3-caffeoylquinic acid in the coffee of the present invention were measured using liquid chromatography. Chromatography is a physical means of separating a mixture into its individual components which indicates the concentration of each. A sample is injected into a solvent carrier which enters a chromatographic column of small diameter packed with a uniform sized solid. Separation of the components of the sample results from a difference in the multiple forces by which the column materials tend to retain each of the components. The nature of the retention can be by adsorption, solubility, chemical bonding, polarity, or molecular filtration. Consequently, the components move through the column and emerge in the inverse order of their retention. Upon emerging from the column at the outlet port, the components enter a detector. The detector generates an electrical signal proportional to the concentration of each component which is integrated and charted, appearing as a peak or curve with an indication of the integration. Comparison of retention times of the peaks from the samples with known references can be used to identify sample components. The concentration of the component is determined by the integrated area under each peak or curve or the height of each peak or curve. A Beckman liquid chromatograph (Model 110), Beckman variable wavelength detector (Model 155), and a Spectra Physics recording integrator (Model 4100) were used. A mobile phase of 83.5% v/v (volume by volume) of 0.05 molar potassium hydrogen phosphate in distilled-deionized water, 158 viv methanol, 1% v/v acetonitrile, and 0.5% w/v (weight by volume) tetramethyl ammonium chloride, was employed with a Waters micro-Bondapak C18 reverse phase column, 3.9 mm. by 30 cm. It will be appreciated by those skilled in the art that C18 reverse phase columns from other manufacturers may be used ano that the mobile phase composition may have to be adjusted slightly to maintain the required separation. Detection was at 290 nm. and 0.1 absorption units full scale. Three grams of coffee were extracted with 50 ml. boiling distilled deionized water for five minutes. The extract was filtered through Whatman No. 4 paper, cooled to room temperature and diluted to 100 ml. with distilled deionized water. The diluted coffee extract was filtered through a 0.45 micron disposable filter and diluted 1:10 with the mobile phase previously described. A sample of 50 microliters was injected onto the reverse phase column with a mobile phase flow rate of 2.0 ml./min. Quantitation, on a weight percent basis, was accomplished by comparing peak heights to a calibration curve prepared from standard materials. A ratio of the concentration of 3-caffeoylquinic acid to caffeine was calculated. C. Bulk/Tamped Density Density was determined using the following method: One hundred grams of dry coffee was placed into a 500 ml. glass graduated cylinder. The cylinder was then vibrated for one minute using an FMC vibrator at setting Number 6. The density of the product was calculated by dividing the sample weight in grams by the sample volume in cubic centimeters. D. Extractability The enhanced extractability of the coffee of the present invention compared with prior art coffees as a reference is demonstrated by the following procedure: A drip coffee extraction is performed by charging 57.0 grams of coffee and 1860 ml. of 1950F (910C) water to a Bunn OL-20 12-cup coffee maker and allowing the coffee to be drip brewed. The brew is cooled to room temperature and analyzed for solids content by index of refraction. Brew solids were measured by refractive index using a Zeiss Model 71498 refractometer equipped with an L1 prism, wherein the sample temperature during measurement was maintained at 290C. The readings were correlated with readings of reference solutions of known brew solids content. E. Dry Headspace Aroma A suitable technique for measuring the coffee aroma of the coffee produced by the process of the invention is gas chromatography. The flame ionization gas chromatograph analytical measurement used herein measured the total content of organic compounds in a gas headspace or voidspace sample from packaged coffee on a scale of relative intensity. The scale was graduated in microvolt-seconds (referred to herein as "counts") which was a measure of the area under the intensity curve, and the result was reported as an integration of the total area under the curve in total microvolt-seconds ("total counts"). The chromatograph comprises two 6 feet (1.8 m.) empty stainless steel columns of 1/8-inch (0.3 cm.) diameter with type S restrictors housed in an oven section for isothermal temperature control. The column was not packed because the gas was not to be separated into individual compounds as commonly done in this type of analysis. A hydrogen flame detector was used at the outlet port. An electrometer received the output signal from the flame detector and amplified it into a working input signal for an integrator. The integrator both sent a display signal to a recorder to print out the response curve and electronically integrated the area under the curve. The gas sample was injected into a heated injection port, and was immediately swept into the column by a carrier gas flow. The detector ionized the sample and generated an electrical signal proportional to the concentration of the materials in the carrier gas. The ionized gases and carrier gas were then vented from the unit. A Carle gas chromatograph (Model 9701), and Hewlett Packard integrator (Model 3390A) were used. Nitrogen pressure in the column was approximately 20 psig (1.4 kg.lsq. cm.). Air pressure of 15 psig (1.0 kg./sq. cm.) was used to flush out the detector. An oven temperature of 1100C was used and maintained to keep the volatiles vaporized. The hydrogen was supplied from a gas cylinder regulated at 20-25 Ibs. psig (1.4-1.8 kg./sq. cm.). Each peak was measured in counts, the counts being first measured by the flame detector and then both integrated and recorded. The number of counts for a particular component was directly proportional to the number of milligrams of that component in the vapor sample. The counts for all peaks generated by a sample were added to obtain a total peak area. This was divided by the sample size to calculate aroma per gram of coffee. The gas chromatograph detector response was precisely calibrated as follows: A standard gas mixture of 0.508 methane in nitrogen by weight was used to set the flame ionization response. Prior to analyzing the samples, a 0.25 ml. sample of gas was obtained from a gas cylinder. The gas sample was at a pressure of 4.0 psig (.3 kg./sq. cm.). The gas sample was syringed into the inlet port of gas chromatograph while adjusting the hydrogen flow, until an area reading of 65,000 + 1000 was obtained. This procedure was repeated until the desired area reading was obtained. The sample must be vacuum packed for at least 3 days at 750 + 50F (24QC + 30C) before sampling. The container was placed in an air-tight box supplied with a source of inert gas such as N2. The vacuum-sealed canister of coffee was punctured to remove the vacuum, then re-sealed and allowed to equilibrate at least four hours at 750 + 50F (240C + 30C) to allow aroma phase equilibration. After equilibration, a 0.25 ml. sample of the aromatic atmosphere of the canister headspace/voidspace was taken again using the same type of syringe as used for the standard methane sample. The gas sample was then injected into the inlet port of the gas chromatograph. The counts were displayed on the chromatogram. The total peak area was divided by the sample size to calculate aroma per gram of coffee. F. Ratio of Quinic Acid to 3-Caffeoylquinic Acid The levels of quinic acid and 3-caffeoylquinic acid in the coffee of the present invention were measured by gas chromatography. A I Hewlett Packard gas chromatograph (Model 5880) with flame ionization detector was used with a 25 m. by 0.20 mm. internal diameter fused silica capillary column coated with a liquid phase of CP-Sil-5 CB (Chrompack, Inc.). Separation of the components of the sample resulted from differences in the multiple forces by which the liquid phase coated on the inner walls of the capillary column tended to retain each of the components. The components moved through the column and emerged in the inverse order of their retention. Upon emerging from the column the separated components entered the flame ionization detector where an electrical signal is generated, recorded and integrated by a Hewlett Packard Model 1000-3357 laboratory automation system. Comparison of retention times of coffee samples with known reference materials was used to identify components. The concentration of the component was related to the integrated area under each peak or curve in units of millivolt-seconds or counts. Samples of coffees were prepared by extracting 2.5 g. with 25 ml. of dimethylsulfoxide for 60 minutes while heating at 900C in a water bath. The extract was filtered through a 0.5 micrometer filter. One milliliter of filtrate was mixed with 1.0 ml. of Tri-Sil Concentrate (Pierce Chemical Co.) which contained 1.0 mg. n-pentacosane as an internal standard. This reaction was carried out for 30 minutes at 500C, and resulted in formation of the trimethylsilyl ethers of the quinic and 3-caffeoylquinic acids. The ethers of the acids were more readily analyzed by gas chromatography than the underivatized acids. One microliter of the derivatized sample extract was injected into the chromatograph. Oniy 1 part in 90 of this actually entered the chromatographic column. The areas of the peaks from quinic acid and 3-caffeoylquinic acid were measured by the Hewlett Packard lab automation system. Quantitation, on a weight percent basis, was accomplished by comparing peak areas to a calibration curve prepared from standard materials. A ratio of the concentration of 3-caffeoylquinic acid to caffeine was calculated. Ill. The following tests were performed on the coffee of the present invention after brewing. For each brewing 47 grams of the coffee of Example 1 was added to the basket of a Bunn Model OL 20 coffee maker containing a paper filter. The basket was placed into position in the coffee maker and 1860 ml. of water added to the coffee maker. The water was heated to 1900F to 2000F (880C to 930C) and flowed through the coffee. The volume of coffee brew generated was from about 1720 ml. to about 1760 ml in each brewing. A. Titratable Acidity Titratable acidity was measured as the milliliters of 0.1 normal sodium hydroxide required to titrate a sample of 100 grams of coffee brew to a pH of 7. After brewing, the coffee brew was cooled and 100 grams weighed into a beaker. An initial pH reading was noted and the sodium hydroxide added slowly from a burette with stirring of the sample to a pH of 7. A Corning Model 130 pH meter was employed with a Corning Model 139-394 (476051) electrode. The sodium hydroxide measurement was normalized to account for variations in brew solids present by dividing the milliliters of sodium hydroxide by the percent by weight brew solids in the sample. This normalized value represented the measure of total acid per 1% of soluble coffee solids. B. Molecular Weight of tirew Solubles The brew of the coffee of the present invention has been found to have more low molecular weight solubles than conventionally processed coffees using liquid chromatography. This increase of lower molecular weight components is consistent with the higher sucrose levels of the presently claimed coffee. Also, low molecular weight compounds generally contribute more to flavor and aroma. Samples of the brews, both fresh and held, were analyzed. The freshly brewed coffees, 450 ml. of each, were placed in a carafe and held on a Bunn Model WX-2 warmer for 1 hour. After rediluting to 450 ml. to compensate for evaporation loss, samples of the brews were analyzed for their molecular weight distribution in the same manner as the fresh brews. A Varian liquid chromatograph (Model 5000), Waters differential refractometer (Model R401), and Pederson recorder (Model 370 MR) were used with two duPont Zorbax PSM60 size exclusion columns each 25 cm. by 6.2 mm. inner diameter connected in series. Commercially available gel-based columns covering a molecular weight ranging approximately 100 to 50,000, such as a Toyo Soda TSK-PW (Toyo Soda hifg. Co. Ltd., Tokyo, Japan), may be substituted to achieve these separations. The mobile phase was Milli-Q water (water purified in a Milli-Q Purification Unit available from Millipore Corp. of Bedford, MA) at a flow rate of 1.0 ml./min. The retention time of the peaks indicates the relative molecular weight of the soluble components in the coffee brews, longer retention times correspond to lower molecular weights. Coffee brews were prepared at approximately equivalent brew solids from conventionally processed coffees and the coffee of the present invention as previously described using distilled water. Samples of each were filtered through a 0.45 micrometer filter. Samples of 25 microliters each were injected into the chromatograph. Peak height is related to the quantity of the molecular weight species. A specific peak does not necessarily represent the level of a single component, but instead represents the cumulative level of all components having molecular weights of that retention time. The coffee samples were compared on the basis of the heights of the various peaks. C. Expert Taste Panel The ultrafast roasted coffee was brewed in a Bunn OL-20 12-cup coffee maker, as previously described. A portion of the brew (about 450 ml.) was placed in a Bunn glass carafe and placed on the burner of a preheated Bunn (OL-20 or WX-2) warming plate maintained at about 4500F + 25 F (2320C + 14 C) surface temperature, and held on heat for approximately 1 hour. The "held" coffee beverage was removed from the warmer and cooled in the carafe using a water bath, to about 1630F (73cm). A "fresh' brew of the same coffee beverage was prepared and cooled to 1630F (730C). The two beverages were tasted by a panel of 15 experts, using the duo-trio panel technique. In this panel method the panelists were given 3 cups -- one standard cup and two unidentified test samples. One of the two test samples was the same as the stanciard cup. Panelists were requested to determine which of the two test cups was not the standard cup, i.e. the odd cup. After the panelist has made this determination, a degree of difference indicating µ the magnitude of difference between the standard and odd cup was indicated using the following scale; 0.2 The flavor of the test sample was not distinguishable from the flavor of the standard. 0.3 The flavor of the test sample was very close to the flavor of the standard, and it was difficult to distinguish from the standard. 0.5 The flavor of the test sample was slightly different from the flavor of the standard. 0.8 The flavor of the test sample was moderately different from the flavor of the standard, and would have been picked as being different from the standard even if flavored by itself. 1.2 This test sample was very different in flavor from the standard. The degree of difference (hereinafter L)OU) for the panel was obtained by taking a sum of the DOD's assigned by the panelists. Panelists who incorrectly identified the "odd" cup were automatically assigned a DOD of 0.2 in calculating the overall DOD for the panel. The sum was then divided by the number of panelists participating. The result was the DOD of the panel. A lower degree of difference determined by the panel correlates with increased similarity of the products tested. Conventionally roasted coffee and the ultrafast roasted product described herein were tested using this expert taste panel procedure. The degree of difference obtained for the ultrafast roasted coffee pane ("fresh" versus "held" beverage) was lower than that of the conventionally roasted coffee. This indicates that the ultra fast roasted coffee tasted closer to fresh after being held than did the conventionally roasted coffee, and therefore had a better holding quality. The following examples are specific embodiments of the present invention but are not intended to limit it. All percentages are by weight unless otherwise stated. Example I Example I illustrates the ultrafast roast method of the present invention. One thousand Ibs. (454 kg.) of high-grade green coffee beans, 600 Ibs. (272 kg.) of intermediate grade green coffee beans, and 400 Ibs. (181 kg.) of low-grade green coffee beans were thoroughly mixed together to form a high quality blend of green coffee beans. This green coffee blend was roasted in a 1 ft. (.3 meter) wide by 18 ft. (5.5 meters) long Jetzon particle oven. The green coffee blend was fed into the roaster using a volumetric screw feeder at a rate of 1,500 Ibs./hr. (680 kg./hr.). The temperature of the air used to fluidize and roast the green coffee beans was maintained at 6150F (324 OC). The pressure of the hot air in the plenum above the fluidizing tubes was maintained at 5 inches (13 cm.) of water (gauge pressure). The vibrating solid pan conveyor which transported the coffee beans through the roasting zone was operated at 170 rpm. An adjustable height barrier at the exit end of this conveyor was set to attain an average bean residence time inside the roasting zone at 60 seconds. An unfluidized bed depth of 3/4 inch (2 cm.) was observed where the green coffee entered the roasting zone. The roasted coffee blend exiting the roast zone was fed by gravity immediately into a Jetzone air cooler having a vibrating solid pan conveyor 1.5 ft. (0.5 meter) wide and 5 ft. (1.5 meters) long. Filtered ambient air at a temperature of 740F (230C) was delivered to a plenum above the fluidizing tubes at a pressure of 2.5 in. (6 cm.) of water (gauge pressure). The vibrating solid pan conveyor which conveyed the coffee beans through the cooling zone was operated at 160 rpm. An adjustable height barrier at the exit end of this conveyor was set to attain an average bean residence time inside the cooling zone of 60 seconds. Roasted beans exiting the cooling zone were observed to be at 850F (290C). Water was atomized onto these 850F (290C) roasted coffee beans at a rate sufficient to raise their average moisture level from their inherent level of about 3.5% to about 4.0%. Physical analysis of this roasted coffee blend showed a whole bean bulk density of 0.350 g./cc., a moisture content of 4.0%, an average color of the surface of the beans of 20 Hunter " L" units and an average color ot a finely ground sample of the beans of 22 Hunter "L" units. Visual Inspection revealed no apparent scorching of the coffee bean tips and good bean to bean color uniformity. The above-roasted blend of coffees was ground in a Gump pilot grinder. A sample of the ground coffee was taken for analysis. A sieve screen analysis indicated that 50% by weight remained on a No. 12 U.S. Standard sieve, 30% by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 10% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 5% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 5% by weight passed through a No. 30 U.S. Standard sieve. The above coarse ground roast coffee was starve-fed by feeding a cascade of the particles into the rolls of a Ross two-roll mill set at zero gap, each roll being of about 18 in. (46 cm.) diameter. The feed rate was about 300 tbs./hr./in. ( 54 Jhr. Icm. ) of nip, while the roll pressure was adjusted to provide a pressure of 350 Ib. lin. (62 kg. 1cm.) of nip. Each roll was operated at a peripheral surface speed of about 1400 ft./min. (427 m./min.) and at an average roll surface temperature of about 750F (24 C). The flaked coffee particles dropping from between the rolls were mechanically conveyed into a hopper. A sample of the flaked coffee was taken for analysis. A sieve screen analysis showed that 5% by weight remained on a No. 12 U.S. Standard sieve, 15% by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 15% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 20% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 45% by weight passed through a No. 30 U.S. Standard sieve. The flaked coffee product was characterized by an average flake thickness of .015 inch (.04 cm.) in the following manner: 100 grams of flaked coffee product were poured onto a circular No. 12 U.S. Standard sieve and were agitated by a Ro-Tap sieve shaker (manufactured by U.S. Tyler Co., Mentor, Ohio) for three minutes. The flaked coffee which passed through the No. 12 sieve was thereafter similarly screened using a No. 16 U.S. Standard sieve. From the portion remaining on the No. 16 sieve, ten representative flakes were selected for flake thickness measurement. Each of the ten representative flakes was measured for thickness using a Starrett Model 1010-E gauge manufactured by L. S. Starrett Co. The ten flake thickness measurements were averaged to give the average flake thickness. Analysis of the coffee is detailed in Example V. Example II Example II illustrates the preparation of a decaffeinated flaked coffee using the ultra fast roast method of the present invention. One thousand pounds (454 Kg.) of the high quality blend of green coffee of Example I were decaffeinated. Nine hundred fifty pounds of this decaffeinated green coffee were roasted in the Jetzone particle oven of Example 1. The green coffee blend was fed into the roaster using the volumetric screw feeder of Example 1 at a rate of 900 Ibs./hr. (409 (Kg./hr.). The temperature of the air used to fluidize ant roast the decaffeinatec green coffee beans was maintained at 6170F (3250L). The pressure of the hot air in the plenum above the fluidizing tubes was maintained at 3.1 inches (7.9 cm.) of water (gauge pressure). The vibrating solid pan conveyor which transported the coffee beans through the roasting zone was operated at 267 rpm. The adjustable height barrier at the exit end of the conveyor was set to attain art average bean residence time inside the roasting zone of 58 seconds. An unfluidized bed depth of 0.25 inch (.66 cm.) was observed where the green coffee entered the roasting zone. The roasted coffee beans exiting the roasting zone were fed by gravity immediately into the cooler of Example I. Filtered ambient air at a temperature of 450F (70C) was delivered to a plenum above the fluidizing tubes at a pressure of 2.5 inches (6.4 cm.) of water (gauge pressure). The vibrating solid pan conveyor which transported the coffee beans through the cooling zone was operated at 185 rpm. The adjustable height barrier at the exit end of the conveyor was set to attain an average bean residence time inside the cooling zone of about 60 seconds. Roasted beans exiting the cooling zone were observed to be at about 1160F (470C). Physical analysis of the roasted decaffeinated coffee blend showed a bulk density of about 0.35 g./cc., a moisture content of 3. 4%, and an average color of a finely ground sample of beans of 20 Hunter it "L" units. Visual inspection revealed no apparent scorching of the coffee bean tips and good bean-to-bean color uniformity. The above roasted blend of decaffeinated coffees was ground in the Gump pilot plant grinder of Example I. A sample of the ground coffee was taken for analysis. A sieve screen analysis indicated that 24% by weight remained on a No. 12 U.S. Standard sieve, 378 by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 27% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 8% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 4% by weight passed through a No. 30 U.S. Standard sieve. The above coarse ground roasted decaffeinated coffee was starve-fed by feeding a cascade of the particles into the rolls of the Ross two-roll mill of Example I set at zero gap, each roll being of about 18 inches (46 cm.) diameter. The feed rate was about 320 Ibs.lhr.linch (57 kg./hr./cm.) of nip, while the roll pressure was adjusted to provide a pressure of 850 Ibis. /inch (150 Kg./cm.) of nip. Each roll was operated at a peripheral surface speed pf about 1400 ft. imin. (427 m./min.) and at an average roll surface temperature of about 750F (240C). The flaked coffee particles dropping from between the rolls were mechanically conveyed into a hopper. A sample of the flaked decaffeinated coffee was taken for physical analysis. A sieve screen analysis indicated that 2% by weight remained on a No. 12 U.S. Standard sieve, 14% by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 21% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 19% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 448 passed through a No. 30 U.S. Standard sieve. The flaked coffee product was characterized by an average flake thickness of 0.016 inch (0.04 cm.) in the same manner as for Example I. Analysis of the coffee is detailed in Example V. Example Ill Example Ill iliustrates the preparation of a flaked coffee using a known fast-roasting process. Eight hundred fifty pounds (386 Kg.) of the high quality blend of green coffee beans of Example I were roasted in the Jetzone particle oven of Example I. The green coffee blend was fed into the roaster using the volumetric screw feeder of Example I at a rate of 715 Ibs./hr. (325 kg./hr.). The temperature of the air used to fluidize and roast the green coffee beans was maintained at 490by to 5000F (2540C to 2600C). The pressure of the hot air in the plenum above the fluidizing tubes was maintained at 3 inches (7.6 cm.) of water (gauge pressure). The vibrating solid pan conveyor which transportea the coffee beans through the roasting zone was operated at 168 rpm. The adjustable height barrier at the exit end of the conveyor was set to attain an average bean residence time inside the roasting zone of 194 seconds . An unfluidized bed depth of 5/8 inch (1.6 cm.) was observed where the green coffee entered the roasting zone. The roasted coffee blend exiting the roast zone was fed by gravity immediately into the Jetzone air cooler of Example I. Filtered ambient air at a temperature of 490F (90C) was delivered to a plenum above the fluidizing tubes at a pressure of 2.5 in. (6 cm.) ot water (gauge pressure). The vibrating solid pan conveyor which conveyed the coffee beans through the cooling zone was operated at 143 rpm. The adjustable height barrier at the exit end of the conveyor was set to attain an average bean residence time In side the cooling zone of about 60 seconds. Roasted beans exiting the cooling zone were observed to be at about 840F (290C). Physical analysis of this roasted coffee blend showed a bulk density of about 0.364 g . /cc., a moisture content of 2.7%, and an average color of a finely ground sample of beans of 21 hunter "L" units. Visual inspection revealed no apparent scorching of the coffee bean tips and good beanto-bean color uniformity. The above-roasted blend of coffees was ground in the Gump pilot grinder of Example I. A sample of the ground coffee was taken for analysis. A sieve screen analysis indicated 18% by weight remained on a No. 12 U.S. Standard sieve, 3496 by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 28% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 10% passed through a No. 20 U.S. Standard sieve and remained on a No., 30 U.S. Standard sieve, and 10% by weight passed through a No. 30 U.S. Standard sieve. The above coarse grouna roast coffee was starve-fed by feeding a cascade of the particles into the rolls of the Ross two-roll mill of Example I set at zero gap, each roll being of about 18 in. (46 cm.) diameter. The feed rate was about 280 lbs./hr./in. (50 kg.ihr./cm.) of nip, while the roll pressure was adjusted to provide a pressure of 680 Ib./ln. (122 kg./cm.) of nip. Each roll was operated at a peripheral surface speed of about 1400 ft. /min. (427 m./min.) and at an average roll surface temperature of about 750F (240C). The flaked coffee particles dropping from between the rolls were mechanically conveyed into a hopper. A sample of the flaked coffee was taken for analysis. A sieve screen analysis indicated 1% by weight remained on a No. 12 U.S. Standard sieve, 10% by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 19% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve, 18% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 52% by weight passed through a No. 30 U.S. Standard sieve. The flaked coffee product was characterized by an average flake thickness of 0.016 inch (.04 cm.) in the same manner as for Example I. Analysis of the coffee is detailed in Example V. Example IV Example IV illustrates the preparation of a flaked coffee using a conventional batch roasting process. Six hundred pounds (272 kg.) of the high quality blend of green coffee of Example I were roasted in a Jabez-Burns Co. Thermalo batch roaster to an average color of 22 Hunter "L" units in about 14 minutes total roast time. The roasted beans were quenched with about 10 gallons (38 liters) of water and cooled to about 850F (290C) in a stirred forced air cooler. Physical analysis of this roasted coffee blend showed a whole bean bulk density of 0.410 g./cc., a moisture content of 4.0%, an average color of the surface of the beans at about 22 Hunter "L" units and an average color of a finely ground sample of the beans of 22.3 Hunter "L" units. Visual inspection revealed no apparent scorching of the coffee beans tips and good bean-to-bean color uniformity. The above roasted blend of coffees was ground and milled in the same manner as that described in Example I. The flaked coffee particles droppiny from between the mill rolls were mechanically conveyed into a hopper. A sample of the flaked coffee was taken tor analysis. A sieve screen analysis indicated that 10% by weight remains on a No. 12 U.S. Standard sieve, 18% by weight passed through a No. 12 U.S. Standard sieve and remained on a No. 16 U.S. Standard sieve, 20% by weight passed through a No. 16 U.S. Standard sieve and remained on a No. 20 U.S. Standard sieve,20% by weight passed through a No. 20 U.S. Standard sieve and remained on a No. 30 U.S. Standard sieve, and 32% by weight passed through a No. 30 U.S. Standard sieve. The flaked product is characterized by an average flake thickness of 0.015 inch (.04 cm.) using the same measurement technique as that described in Example I. Analysis of the coffee is detailed in Example V. Example V Example V illustrates the properties of the coffee of the present invention compared to conventionally processed coffee. The coffees of Examples I, II, Ill and 1V, a commercially available coffee believed to have been conventionally processed in a manner similar to Example Ill, and a commercially available decaffeinated coffee, were analyzed for sucrose, ratio of 3-caffeoylquinic acid to caffeine, caffeine content, ratio of quinic acid to 3-caffeoylquinic acid, tamped density, extractability, and aroma using the methods previously described. A coffee brew was prepared by brewing 47 grams of coffee with 1860 ml. of water in a Bunn Model OL 20 coffee maker containing a paper filter. The water was heated to 1900F to 2000F (880C to 930C) and flowed through the coftee. The volume of coffee brew generated was about 1740 ml. The coffee brew was analyzed for titratable acidity, and molecular weight component distribution using the methods previously described. The resulting data are summarized in Tables II and Ill and Figures 1 through 7. Figure 1 illustrates a liquid size-exclusion chromatogram for the coffee of the present invention for sizing of molecular components. The species exit the columns in order from highest to lowest molecular weights. Thus the species with the highest molecular weights exit the columns first and appear at the left side of Figure 1. Species with the lower molecular weights exit the columns last and appear on the right side of Figure 1. The high molecular weight portions of the chromatograms for the coffee of the present invention and for conventionally processed coffees are similar in appearance. Figures 2 through 7 therefore represent that portion between points. A and B of the chromatograms wherein low molecular weight components such as sugar are represented. Figure 2 represents the low molecular weight portion of the chromatogram of Figure 1 for the coffee of the present invention of Example I when freshly brewed. Figure 3 represents the low molecular weight portion of a chromatogram for the decaffeinated coffee of the present invention of Example II when freshly brewed. Figure 4 represents this portion of a chromatogram for the conventionally processed coffee ot Example IV when freshly brewed. Comparison of Figures 2 and 3 with 4 demonstrates that the coffee brew of the present invention has a higher level of low molecular weight components. The change in peak heights does not necessarily represent an increase in the level of a single component, but instead represents a change in the level of all components having molecular weights within that range. Figures 5, 6 and 7 represent the low molecular weight portion of chromatograms for the coffees of Examples I, II and IV, respectively, after the brew has been held heated for one hour. Comparison of Figures 5 and 6 with 7 demonstrates that the coffee brew of the present invention retains this higher level of low molecular weight components after heating for one hour. The change in peak heights does not necessarily represent an increase in the level of a single component, but instead represents a change in the level of all components having molecular weights within that range. TABLE II Example I Example III Example IV Coffee Coffee Coffee (Uitra-fast (Conventional (Conventional Commerclal Component roast) fast roast batch roast) Coffee Coffee Sucrose, % 0.8 0.3 0.3 0.3 Ratio of 3-caffeoyl- 1.15 0.94 0.91 0.84 quinic acid to caffeine Caffeine, % 1.3 1.4 1.4 1.4 Ratio of quinic acid to 0.54 0.64 0.76 0.78 3-caffeoyl quinic acid Extractability 0.96 0.91 0.80 0.77 (brew solids, %) Aroma, counts/g. 61 54 43 Aroma as a percentage 142% 126% 100% of Example IV Tamped density, 0.400 0.409 0.430 0.361 g./cc. Coffee Brew Titratable acidity 4.7 4.7 4.9 4.9 Table III Example II, Decaffeinated Commercial Component Coffee (Uitra-fast roast) Decaffeinated Coffee Coffee Caffeine (%) 0.07 0.04 Sucrose (%) 0.7 lower than detection limits Ratio of quinic acid to 0.88 1.02 3-caffeoylquinic acid Extractability (brew solids, %) .80 .64 Aroma (counts/gm.) 57 32 Aroma as a percentage of 178% 100% commercial coffee Tamped density (g./cc.) .392 .384 Coffee Brew Titratable Acidity 3.5 3.5 Example VI Example VI illustrates the Improved holding quality of the coffee brew prepared from the coffee and decaffeinated coffee products of the present invention. The coffee of the present invention processed as in Examples I and 11, a coffee processed conventionally as in Example IV, and a commercial coffee believed to have been conventionally processed in a manner similar to Example 111 were each brewed as in Example V and subjected to expert panel evaluation for taste when freshly brewed and after holding on a warming plate for one hour using the method previously described. The results of a series of hold quality tests indicate the following degree of differences. The ultrafast roasted coffee of the present invention (Example I) had an average degree of Jifference of 0.41 between the fresh brew and the same coffee held one hour. This repre- sented an average of 8 expert panel tests of 15 experts each. The ultrafast roasted decaffeinated coffee of the present invention (Example II) had an average degree of difference of 0.39 between the fresh brew and the same coffee held one hour. This represented an average of 4 expert panel tests of 10 experts each. The conventionally processed batch coffee of Example IV had an average degree of difference of 0.53 between the fresh brew and the same coffee held one hour. This represented an average of 7 expert panel tests of 15 experts each. The commercial coffee believed to have been conventionally processed in a manner similar to Example lil had an average degree of difference of 0.56 between the fresh brew and the same coffee held one hour. This represented an average of two expert panel tests of 18 experts each. A lower degree of difference correlated with increased similarity of the fresh and one-hour old coffee. These results indicated that the ultrafast roasted coffee and ultrafast roasted decaffeinated coffee of the present invention, after each being held for one hour on heat, tasted closer to fresh than did the conventionally processed coffee and the commercial coffee. Thus, the coffee and decaffeinated coffee products of the present invention have improved holding quality. Example VII Example VII illustrates the less bitter flavor of the coffee brew prepared from the coffee product of the present invention. The coffee product of the present invention processed as in Example I, a coffee processed conventionally as in Example IV, and conventionally roasted competitive products, commercially available, were tested for flavor. Commercial coffee C is believed to have been conventionally processed in a manner similar to Example Ill. The coffees were brewed as in Example V using tap water, except that the amount of coffee varied as shown in Tables IV and V. The amount of coffee used to prepare the coffee brew was such that the resulting beverages would have approximately the same brew solids. In the Fresh Coffee Panels all coffees were compared when freshly brewed. In the "Held" Coffee Panels the coffee beverage of the present invention (coffee of Example 1) in an amount of 1500 ml. (10 cups) was held on the warmer of the coffee maker for one hour. This "held" coffee was tested against commercial coffees A, B and C and the cottee of Example IV when freshly brewea. A blind paired comparison test method was conducted employiny 100 persons for each panel. The non-expert panelists were asked to taste two cups of unidentified coffees. They were allowed to add condiments (creamer, sugar, or artificial sweetener) as they normally would, but were required to add the same amounts to each cup. Panelists were also requested to sip water before and after tasting the coffees to clean their taste buds. After tasting the two test coffees, panelists completed a questionnaire indicating which coffee was preferred and which product was considered less bitter. The results of the panel testing were tabulated to indicate the total percentage of panelists preferring each coffee, and the total percentage of panelists that found one of the test coffees to be less bitter than the other test coffee. The tabulated results are summarized in Tables IV and V. Thus, in the fresh coffee panel 56% of the panelists preferred the coffee of the present invention to coffee A, 62% to coffee B, and b9 to coffee C. The coffee of the present invention was rated as less bitter than coffee A by 62% of the panelists, as less bitter than coffee B by 54% of the panelists, and as less bitter than coffee C by 56% of the panelists. In the "held" coffee panel, the coffee of the present invention after held on heat for 1 hour was preferred by 66% of the panelists to freshly brewed coffee A, by 53% of the panalists to freshly brewed coffee B, by 58% of the paneliB 7,freshly brewed coffee C, and by 64% of the panelists to freshly brewed coffee of Example IV (same blend of coffee beans but batch roasted in conventional manner). The presently claimed "held" coffee was evaluated as less bitter by 67% of the panelists when compared to freshly brewed coffee A, 62% of the panelists when compared to freshly brewed coffee B, 67% of the panelists when compared to freshly brew coffee C, and 60% of the panelists when compared to freshly brewed coffee of Example IV. Table IV Fresh Coffee Panel % of Panel % of Panel Brew usage preferring indicating less level (g.) overall bitter taste Coffee of Example 1 47 56 62 Commercial Coffee A 76 44 38 Coffee of Example 1 40 62 54 Commercial Coffee B 57 38 46 Coffee of Example I 47 56 56 Commercial Coffee C 57 44 44 Table V "Held" Coffee Panel 96 of Panel 96 of Panel Brew usage preferring indicating less level (g.) overall bitter taste Coffee of Example I 47 66 67 Commercial Coffee A 76 34 33 Coffee of Example I 40 53 62 Commercial Coffee B 57 47 38 Coffee of Example I 47 58 67 Commercial Coffee C 57 42 33 Coffee of Example I 47 64 60 Coffee of Example Ill 57 36 40

Claims: 1. A process for preparing a coffee product comprising: (1) roasting green coffee beans in a fluidized bed roaster in from about 30 seconds to about 120 seconds at temperatures of from about 5500F (2880C) to 7500F (3990C) to a color of from about 19 to about 23 Hunter II "L" units, wherein the surfaces of the roasted beans are not more than 10 Hunter it "L" units different in color from the average color throughout the beans; (2) air quenching the roasted coffee to a temperature of less than 3000F (1490C); (3) grinding the quenched and cooled coffee in a manner such that the overall color of the ground coffee is from about 19 to about 23 Hunter "L" units. 2. A process according to Claim 1 wherein the coffee is roasted at a temperature of from about 6000F (3160C) to about 6750F (3580 C) and at a time of from about 45 seconds to about 90 seconds. 3. A process according to Claim 2 wherein the Hunter "L" unit color of the roasted beans and the overall Hunter "L" unit color of ground coffee are from about 19 to about 22, and the surfaces of the roasted coffee beans are not more then 3 Hunter "L" units different in color from the average color throughout the beans. 4. A process according to Claim 1 wherein the level of fluidization during roasting is from about 9 to about 14 pounds (4 to 6 kg.) of hot air per pound (.454 kg.) of green coffee per minute, and the level of fluidization during quenching is from about 15 to about 20 pounds (7 to 9 kg.) of air per pound (.454 kg.) of roasted coffee per minute. 5. A process according to Claim 1 wherein the quenching is done by an inert gas and the roasted coffee is quenched to below about 3000F (1490C) in about 20 seconds. 6. A process according to Claim 1 which comprises the additional step of spraying water onto the beans after they have been cooled to below about 2000F (930C). 7. A process according to Claim 1 wherein step (3) comprises milling the quenched and cooled coffee into flakes. 8. A process according to Claim 7 wherein the overall color of the flaked coffee is from about 19 to about 25 Hunter t'L" units. 9. A process according to Claim 7 wherein the mechanical static gap of the roll mills is from 0 to about 5 mils during flaking of the coffee. 10. A process according to Claim 9 wherein the roll speed is from about 470 ft./min. to about 1880 ft./min. (143 to 513 meters/min.), the roll pressure is from about 150 Ibs./linear inch of nip to 4000 Ibs./linear inch of nip (27 to 714 kg./cm. of nip), and the feed rate of the coffee is set to achieve starve feeding. 11. A process according to Claim 10 wherein the mill feed particle size distribution comprises: (a) from about 40% to about 80% by weight of the composition remains on U.S. Standard sieve size 12; (b) from about 20% to about 50% by weight of the composition passes through U.S. Standard sieve size 12 and remains on 16; (c) from about 0% to about 20% by weight of the composition passes through U.S. Standard sieve size 16 and remains on 20; (d) from about 0% to about 20% by weight of the composition passes through U.S. Standard sieve size 20 and remains on 30; (e) from about 0% to about 10% by weight of the composition passes through U.S. Standard sieve size 30. 12. A product made according to Claim 1, 6, 7, 10 or 11. 13. An improved roast coffee product comprising roast and ground, flaked, decaffeinated roast and ground, or decaffeinated flaked coffee which when brewed generates a coffee brew having reduced bitterness and improved holding quality. 14. The coffee of Claim 13 wherein the sucrose level is a minimum of .5% by weight. 15. The coffee of Claim 13 wherein the ratio of 3-caffeoylquinic acid to caffeine is a minimum of 0.98. 16. The coffee of Claim 13 wherein the ratio of quinic acid to 3-caffeoylquinic acid is a maximum of 0.60, the tamped density is from about 0.34 to about 0.41 g./cc., and the extractability as percent weight of brew solids is a minimum of about 0.93. 17. The decaffeinated coffee of Claim 13 wherein the ratio of quinic acid to 3-caffeoylquinic acid is a maximum of 0.96, and the extractability as percent weight of brew solids is a minimum of 0.70. 18. The coffee of Claim 14 wherein after brewing the resulting coffee brew has a maximum one-hour hold quality degree of difference of 0.50. 19. The coffee of Claim 18 wherein the coffee brew has a maximum titratable acidity of 4.7, and has a higher level of low molecular weight components in the brew solubles than brews prepared from conventionally processed coffees.

Inventors: FRUHLING, ROBERT JOSEPH, HARRIS, MARVA BRADLEY, KUSSIN, RICHARD FRED, PRICE, SANKEY EUGENE
Applicants: THE PROCTER & GAMBLE COMPANY
Application year: 1984
Main classification: A23F5
IPC codes: A23F5