HYDROCARBON CONVERSION PROCESSES AND MODIFIED REFRACTORY OXIDES WHICH CAN BE USED IN SUCH PROCESSES

Abstract: Hydrocarbon conversion processes wherein hydrocar­ bons are contacted with hydrogen at hydroconversion conditions using a catalyst comprising at least one hydroge­ nating metal or compound thereof present on at least one refractory oxide which has been treated with from 0.1 to 30 %w, calculated on refractory oxide, of at least one reactive metal compound of Group 2a, 3a, 4a and or 4b of the Periodic Table of the Elements. Preferably, petroleum waxes are hydroisomerized using catalysts based on modified refractory oxides which have been prepared by impregnating them with at least one hydrocarbyl ammonium metallate and or compounds com­ prising at least one hydrocarbyl ammonium moiety and at least one reactive metal compound.

Description: HYDRCCARBON CCNVERSION PROCESSES AND K)DIFIED REFRACTORY OXIDES WHICH CN BE USED IN SUCH PROCESSES The present invention relates to catalytic hydrocarbon conversion processes as well as to the preparation of modified refractory oxides which suitably can be used therein. The present invention relates in particular to a process for the hydroiso merization of petroleum waxes using preferably catalysts based on modified refractory oxides prepared according to the present invention, as well as to lubricating oils thus obtained. It is knawn that refractory oxide supports which have been treated with metals having hydrogenating activity can be used in hydrocarbon conversion processes, for instance in the hydrogenation of petroleum waxes in order to increase the light- and thermal stability of such waxes. Although petroleum waxes can be converted into high or even extra high viscosity index lubricating oils, for which a high demand exists, considerable sacrifices have to be made with respect to the conversion rate of the petroleum waxes and unacceptably high reaction temperatures have to be used. It has now surprisingly been found that the use of certain refractory oxides treated with certain reactive metals as catalysts in hydrocarbon conversion processes gives excellent results; in particular, the disadvantages referred to hereinabae with respect to the conversion of petroleum waxes can be avoided. The invention relates to hydrocarbon conversion processes by contacting hydrocarbons with hydrogen at hydroconversion conditions using a catalyst comprising at least one hydrogenating metal or compound thereof present on at least one refractory oxide which has been treated with fran 0.1 to 30 %w, calculated on refractory oxide, of at least one reactive metal compound of Group 2a, 3a, 4a and/or 4b of the Periodic Table of the Elements. Reference is made to the "Handbook of Chemistry and Physics", 55th edition, CRC Press, Ohio, USA (1975) for the Periodic Table of the Elements. The invention relates in particular to a process for the hydroisomerization of petroleum waxes, wherein said waxes are contacted with hydrogen at hiydroisactization conditions using a catalyst comprising at least one hydrogenating metal or compound thereof present on at least one refractory oxide which has been treated with from 0.1 to 30 w, calculated on refractory oxide, of at least one reactive metal compound of Group 2a, 3a, 4a and/or 4b of the Periodic Table of the Elements. The present invention further relates to a process for the preparation of modified refractory oxides which comprises impregnating refractory oxides or mixtures thereof with at least one hydrocarbyl ammonium nratallate and/or compounds comprising at least one hydrocarbyl amrronium moiety and at least one reactive metal moiety of Group 2a, 3a, 4a and/or 4b of the Periodic Table of the Elements. Refractory oxides modified according to the present invention are preferably applied as starting materials for the preparation of catalysts which are used in particular in catalytic hydroconversion processes such as the (partial) dearomatization of kerosene and the hydroisomerization of petroleum waxes. It appears that reactive metals present in refractory oxide particles modified according to the process according to the present invention are bound to a rather large extent to the surface of the particles in mono- or multi-1Tlolecular layers. This is quite distinct for ready catalyst particles obtained by using well-known stabilizing methods for silica sols which comprise the treatment of such sols with very small amounts of a solution of a metallate; such catalysts appear to have metals or metal moieties throughout the body of the particles. Without wishing to be bound to any particular theory, it is thought that the presence of reactive metals on the surface of catalyst (support) particles has an influence on their acidity, whilst maintaining and possibly improving their surface area and/or pore volume. For refractory oxides such as silica, which apparently lack sufficient acidity for application as catalyst support in processes where catalysts with moderate acidity are preferred (e.g. hydrogenation of kerosene), mcdification according to the process according to the invention provides a marked improvement in catalytic performance of such refractory oxides. Substantially non-crystalline refractory oxide particles which have a surface area of 100-600 mê/g are suitably used in the process according to the invention; preferred is a surface area of 200-500 m2/g. Refractory oxides which can be suitably used as starting materials in the preparation process according to the present invention comprise silica, alumina, magnesia, zirconia, titania, chrania, boria or mixtures thereof such as silica-alumina, silica- magnesia, alumina-magnesia and/or silica-zirconia. Preference is given to silica, in particular to silica with a pore volume of at least 0.5 ml/g from which excellent hydroconversion catalysts can be prepared. Small amounts of water may be tolerated in the refractory oxides used as starting material in the preparation process according to the present invention. For instance, for silica comprising particles this amount of water may be up to 12 %w, calculated on total weight. modified refractory oxide particles prepared according to the process of the invention generally exhibit a good resistance against crushing which is advantageous when these particles are used in a catalyst bed which has a substantial height (which may be 15 m or more in an upright reactor) or when a second layer of catalyst particles is placed upon this catalyst bed. Generally the modified refractory oxide particles have a bulk crushing strength (BCS) of 1-4 MPa and a side crushing strength (SCS) of more than 40 N; preferably the BCS is 1.5-4 MPa and the SCS is 50-200 N. Catalyst beds are often covered at their inlet by materials which are inert to the reaction, in order to facilitate even distribution of the feedstock, that is, to prevent or reduce channelling through the catalyst bed(s). Because such inerts may occupy a substantial portion of the reaction zone, e.g. up to 15 to 20% or more of the reaction zone volume, their presence adds to the capital expenditure of a catalytic hydroconversion process both for the reactor(s) and for the costs of the inerts which do not contribute in any significant manner to the desired conversion of the feedstock. The presence of layers of inert material can be avoided in hydrocanversion reactors when the catalyst employed therein is also capable of properly distributing the feedstock over the catalyst bed(s). Catalysts containing modified refractory oxides prepared according to the process of the present invention, and in particular substantially spherical particles, are eminently suitable for this purpose. The use of spherical particles, which moreover have a high abrasion strength, results not only in improved flaw distribution of feedstock but also in a reduced pressure drop over the catalyst bed (s), compared with the use of modified particles of a different shape. The term "spherical" as used herein refers to particles having both a true rounded shape and those generally spheroidal particles which do not pass perfectly rounded configurations. Procedures for preparing these particles are known in the art. For instance, , silica spheres can be prepared by a method comprising the initial preparation of a silica hydrogel by mixing an aqueous solution of an alkalimetal silicate with an aqueous solution of an acid, converting the hydrosol obtained into droplet form and gelling the droplets in a liquid which is not miscible with water. Optionally, the hydrogel obtained is then converted into a xerogel by reducing the alkalimetal content of the spherical silica hydrogel particles, followed by drying and calcining. Generally, use is made of refractory oxides comprising particles of which the smallest size is of fran 0.1-30 mm. Beds of refractory oxide catalyst particles of less than 0.1 irrn tend to plug more readily and are less effective in distributing feed across the initial contact layer of catalyst than beds of larger particles, whereas the use of particles of which the smallest size is above 30 mm results in catalysts having significantly lower activity per volume unit. Preferably use is made of particles of which the smallest size is from 0.5-10 mm. When the particles used are spheres the term "smallest size" refers, of course, to their diameters. Otherwise, e.g. for duib-bell sped particles, this term refers to the smallest distance fran one wall to an opposite wall of a particle. Mbdification of refractory oxides with reactive metal compounds can be suitably carried out either by impregnating the refractory oxides with a solution canprising a hydrocarbyl ammonium metallate or with at least two solutions comprising, respectively, one or more metal ccmpounds and a hydrocarbyl arrrriiium hydroxide. Preference is given to the use of a hydrocarbyl ammonium moiety ccmprising one or more alkyl groups with 1-4 carbon atoms, most preferably a tetramethyl ammonium moiety. Suitable reactive metal moieties comprise magnesium, aluminium, titanium and zirconium, which can be used separately or in combinations. When use is made of silica-comprising refractory oxides, aluminium is the preferred reactive metal moiety which is very suitably applied by impregnating the refractory oxide with a solution comprising tetramethyl ammonium aluminate. Other reactive metal moieties, such as zirconium and magnesium are preferably applied to the refractory oxides by impregnation with a solution ccmprising the nitrate(s) of the reactive metal(s) and subsequently with a solution comprising at least one hydrocarbyl anrroni hydroxide, preferably in such manner that the weight ratio of hydrocarbyl ammonium hydroxide to the appropriate refractory oxide(s) is from 0.01 to 1, preferably from 0.1 to 0.5. When using a hydrocarbyl artrtonium metallate, the amount thereof is calculated on basis of the equivalent amount of hydrocarbyl ammonium hydroxide. Also metal alkoxides such as titanium alkoxide (in particular titanium (IV) ethoxide) can be suitably applied to incorporate a metal into the refractory oxide(s). The impregnation of the refractory oxides may be carried out in one or more stages with one or more solutions by any method known in the art, e.g. dipping, soaking, ("wet") or "dry" impregnation, in which last method the volume of the impregnating solution used is about equal to the total pore volume of the refractory oxide particles to be impregnated. The impregnation treatment is suitably carried out at temperatures up to the boiling point of the solvent, preferably at temperatures of from 60-900C using aqueous solutions. The modified refractory oxides thus prepared suitably comr prise 0.1-10 %w, and preferably 1-7 bw, of reactive metals, cal culated as metal oxides and based on the total weight of the modified refractory oxides. It is thought that larger amounts of reactive metals could adversely affect the strength of the modified refractory oxide particles thus obtained. The modified refractory oxides are suitably subjected to a heat treatment after the (final) impregnation step or, alternatively, after more than one or after each impregnation step. The heat treatments comprise drying, suitably at temçeratures of from 50-2500C, and/or calcining steps, the latter being suitably carried out in air under atmospheric pressure at temperatures of from 250-10000C. With a tsc-step impregnation process, using for instance metal nitrates in the first step, it is preferred to calcine the metal-impregnated refractory oxides firstly at tewr peratures of from 250-4000C for 1-24 hours before carrying out the second impregnation step with a hydrocarbyl ammonium hydroxide. After the second impregnation step the modified refractory oxides are preferably subjected to a calcination treatment in air at temperatures of fran 400-8000C for 1-24 hours, in order to achieve the desired catalytic activity of the refractory oxides. At least one hydrogenating metal or metal ccmpound should be loaded on to the modified refractory oxides prepared according to the present invention, preferably after a heat treatment. Preferred metal ccmpounds comprise nitrates, oxides and/or sulphides. Of particular interest are catalytic composites comprising one or more metals of the groups 6 b and/or 8 of the Periodic Table of the Elements, and/or compounds thereof, such as itolybdenin, tungsten, d1raniiin, iron, nickel, cobalt, platinum, palladium, ruthenium, rhodium, osmium and iridium; the modified refractory oxides may be loaded with these metals or their compounds by means of any process for the preparation of catalysts known in the art, such as iirpreenation,ion-exchange or precipitation. Thus, modified refractory oxides prepared in accordance with the process of the present invention can be utilized advantageously as catalysts or ocmponents thereof in a variety of hydrocarbon conversion processes preferably in the presence of hydrogen. For instance, modified refractory oxides loaded with 0.1-2 % by weight of one or more noble metals of Group 8, calculated on the weight of the modified refractory oxides, are very suitable for use in processes where bifunctional catalysts (i.e. catalysts wherein acidity and hydrogenation activity have been balanced carefully) are needed. Preferred catalysts for use in hydrocarbon conversion processes according to the present invention such as the (partial) dearanatization of kerosine or the hydroisomerization of petroleum waxes comprise modified refractory oxides which have been loaded with fran 0.1 to 2% by weight of one or more noble metals of Group 8, in particular platinum, calculated on the weight of the treated refractory oxides. Sulphur-oontaining ccrpcends may be present in amounts of up to 100 ppmw in the hydrocarbons to be converted (e.g. kerosene or slack wax), without causing unacceptable loss of hydrogenation activity, when using the above-described catalysts. Also small amounts of nitrogen-containing ccmT w nds may be tolerated. A preferred catalyst for hydrocarbon conversion processes according to the present invention comprises platinum and/or palladium incorporated in silica spheres which have been impregnated with tetramethyl ammonium aluminate. Prior to their use in hydroconversion processes the catalysts are preferably activated by treatment with hydrogen at a tempe- rature from 1500C to 700 C, in particular for at least several hours at a temperature fran 3000C to 5000C and at at least atmospheric pressure. In general the reaction conditions applied in hydroconversion processes, such as the (partial) dearanatization of kerosene, comprise a temperature from l00-6000C, preferably 200-4000C; a pressure fram 1-300 bar, preferably 10-150 bar; a hydrogen feed rate from 50-2500 Nl/kg feed, preferably 100-1000 Nl/kg feed: and a space velocity fran 0.1-10 kg feed/l catalyst/hour, preferably 1-6 kg feed/l catalyst/hour. A reaction temperature for this type of hcoconversion processes exceeding 6000C is less desirable as it might cause considerable shortening of the catalyst life by increased formation of carbonaceous deposits thereon. Petroleum waxes contain normal and slightly branched paraffins of high molecular weight which solidify at ambient temperature. These waxes are usually obtained fran the heavier fractions of crude oils, suitably as a by-product during the preparation of lubricating oils. The wax obtained during the refining of various lubricating oil fractions is designated as distillate or residual slack wax, depending on the type of lubricating oil fraction fran which it is derived by dewaxing. The dewaxing treatment can be carried out in any manner known in the art, e.g. by means of a solvent. This latter process prD- vides for dissolving a wax-containing feedstock in an organic solvent and gradually chilling this feedstock to cause crystallization of the wax, which is subsequently separated from the solvent/oil mixture by filtration. Suitable solvents for this treatment are liquefied propane and butane, pentane, benzene, toluene, acetone, tone, methyl ethyl ketone and mixtures of one or more aromatic compounds with methyl ethyl ketone. Dewaxing is preferably carried out using a mixture of 40-60 parts by volume of methyl ethyl ketone and 60-40 parts by volume of toluene at a temçerature between -10 and -300C, the volume ratio of the solvent and oil being between 1 and 10. A preferred feed for the hydroisarerization process according to the invention consists of slack waxes obtained as by-products in the preparation of lubricating oils by hydrocracking. From the lubricating oil fractions obtained by hydrocracking such as a vacuum distillate, a deasphalted oil or a slack wax, lubricating oils are prepared by removing slack wax from these lubricating oil fractions. If desired this slack wax may be mixed with waxes obtained as by-product during conventional preparation of lubricating oils, before being applied as feed in the present process. Slack waxes possess a very high viscosity index, normally in the range of fran 140 to 200, depending i.a. on their oil content and on the starting material fran which they have been prepared. They are therefore eminently suitable for the preparation of lubricating oils with (extra) high viscosity indices, i.e. between 130 and 200, which products may serve for use as multigrade lubricating oils or as components of multigrade lubricating oils. In general the reaction conditions applied in hydroiscrrer- ization processes comprise a temperature in the range of from 250 to 4500C, preferably of from 275 to 4000C; a pressure in the range of from 10 to 250 bar, preferably of from 50 to 150 bar; a hydrogen feed ratio in the range of from 100 to 2500 Nl/kg feed, preferably of from 200 to 2000 Nl/kg feed; and a space velocity in the range of fran 0.1 to 5 kg feed/l catalyst/hour, preferably of from 0.5 to 4 kg feed/l catalyst/hour. A reaction temperature substantially exceeding 4500C is less desirable in hydroisomerization processes as it might cause considerable shortening of the catalyst life by increased formation of carbonaceous deposits thereon. The hydrogen to be employed in the catalytic conversion processes may be pure or in the form of hydrogen-containing gases. The gases employed should preferably contain more than 50% by volume of hydrogen. Very suitable are, for example, hydrogencontaining gases obtained in the catalytic reforming or steam-reforming of gasoline fractions, and mixtures of hydrogen and light hydrocarbons. Any excess of hydrogen-containing gas is advantageously recycled, possibly after the previous removal of undesired components therefrom. The invention is illustrated by the following Examples. EXE 1 Different refractory oxides were prepared as follows. A Silica spheres with a diameter of 1.5-2 rtrn, a pore volume of 0.64 ml/g and a specific surface area of 257 rn2/g were pre-dried at 2000C for 2 hours. An aluminium nitrate-con taining solution was prepared by dissolving 71 g of Al (No3) 3 in 50 ml of water, and was subsequently used to impregnate 70 g of the pre-dried silica spheres for 1 hour at ambient temperature. After evaporation of water for 1 hour at 600C, the impregnated silica spheres were dried in air for 2 hours at a temperature of 1500C and were subsequently calcined in air at 5000C for 2 hours. B A quantity of 100 g of pre-dried silica spheres with a pore volume of 0.74 ml/g and a specific surface area of 294 mê/g was impregnated with an aqueous solution of tetramethyl ammonium aluminate obtained by mixing an aqueous solution of 24 g of aluminium chloride with 388 ml of tetramethyl artrronjum hydroxide (10 %v) in a nitrogen atmosphere. The impregnation was carried out at a temperature of 70"C for 2 hours in a nitrogen atmosphere and subsequently for a further 16 hours at ambient temperature. The resulting modified silica spheres were firstly dried at 1000C for 1 hour, then at 2000C for 3 hours and subsequently calcined in air at 6000C for 3 hours. The calcined spheres obtained contained 5.1 % w alumina, (based on the total weight of the spheres); the pore volume was 0.65 ml/g and the specific surface area 346 m2/g. The modified silica-comprising spheres prepared in accordance with the invention thus show a significant increase in surface area, compared with the silica spheres used as starting material. E Silica spheres with a diameter of 1.5-2 mm, a pore volume of 1.48 ml/g and s specific surface area of 320 in2/g were pre-dried for 2 hours at 200 OC. A magnesium nitrate containing solution was prepared by dissolving 95.4 g of magnesium nitrate in 126 ml of water at ambient temperature and subsequently used to impregnate 35 g of the pre-dried silica spheres for 1 hour at ambient temperature. After evaporation of water for 1 hour at 60 "C, the impregnated silica spheres were dried in air for 2 hours at a temperature of 150 "C and were subsequently calcined in air at 500 "C for 2 hours. The calcined spheres contained 22 %w magnesia (based on the total weight of the spheres). F A quantity of 50 g of pre-dried silica spheres having a pore volume of 0.74 ml/g and a specific surface area of 294 m2/g was impregnated with a solution of 136.3 g of magnesium nitrate in 125 ml of water for 1 hour at ambient temperature. After evaporation of water the product was dried for 2 hours at 250 OC and thereafter calcined for 2 hours at 500 OC. The spheres were then impregnated with 50 ml of tetramethyl ammonium hydroxide (10 %v). The impregnated spheres were kept at 110 OC for 2 hours, then 2 hours at 200 OC and 1 hour at 270 OC during the drying stage. They were finally calcined for 3 hours at 700 OC. EX¯MPLE 2 On basis of the refractory oxides of Example 1 a number of noble metal-containing catalysts was prepared. Preparation of catalyst A'. A quantity of 78 g of treated silica spheres as prepared under A of Example 1 was impregnated with a solution of 1.22 g of platinum nitrate in 100 rnl of water at ambient temperature for 30 minutes. After evaporation of water the product was dried at 1500C and subsequently calcined in air at 500eC for 2 hours. The resultant catalyst (A') contains 0.8 % by weight of platinum, calculated on the weight of the modified silica spheres. Preparation of catalyst B'. A quantity of 35 g of modified silica spheres as prepared under B of Example 1 was co-impregnated with 45 ml of an aqueous solution comprising 281 mg of H2PtC16.6H20, 299 mg of PdClz and 2.4 ml HC1 (38 %v), whereafter water was evaporated and the product was dried at 1200C and subsequently calcined in air at 5000C for 3 hours. The resultant catalyst (B') contains 0.31 %w of platinum and 0.50 %w of palladium, both calculated on the weight of the modified silica spheres as prepared under B of EXample 1. Preparation of catalyst C'. A quantity of 35 g of silica spheres used as starting material under B of Example 1 was impregnated in the same manner as catalyst (B'). The resultant catalyst (C') contains 0.29 %w of platinum and 0.53 w of palladium, calculated on the weight of the silica spheres. Preparation of catalyst D'. A quantity of 70 g of pre-dried silica spheres used as starting material under A of Example 1 was impregnated with a solution of 10.95 g of Pt (NH3)4(OH)2 in 1 1 of water for 48 hours after which the product was washed with water, dried at 1500C and subsequently calcined in air at 5000C for 2 hours. The resultant catalyst (D') contains 0.9 % by weight of platinum, calculated on the weight of the silica spheres. Preparation of catalyst E' A quantity of 22 g pre-dried silica spheres as prepared under E of Example 1 was impregnated with a solution of 2.66 g of Pt (NH3) 4 2 in 70 ml of water (containing 6.67 w of platinum) for 1 hour after which the water was evaporated for 2 hours at 60 OC and the product calcined for 2 hours at 400 OC. The resultant catalyst (E') contains 0.8 % by weight of platinum, calculated on the weight of the silica spheres. Preparation of catalyst F' A quantity of 50 g pre-dried silica spheres as prepared under F in Example 1 was impregnated with a solution of 6.05 g Pt(NH3)4(0H)2 in 100 ml of water (containing 6.67 %w of platinum) for 30 minutes at arrient temperature. After evaporation of water the product was dried for 2 hours at 150 OC and then calcined for 2 hours at 400 "C. The resultant catalyst (F') contains 0.84 8 by weight of platinum, calculated an the weight of the silica spheres. EXAMPLE 3 Catalytic hydrogenation of kerosene. Evaluation of the catalysts A'-D' of Example 2 was based on the results of experiments performed in trickle flow units. The kerosene feed to be hydrogenated, which was entirely or substantially in the liquid phase, was trickled downwardly co-urrently with the hydrogen-containing gas through the fixed catalyst beds. The units were equipped with 100 ml reactors operated in once-through mode and contained 15 g of catalyst particles diluted with 50 g of silicium carbide particles with a diameter of 0.2 mm. Before being used for the catalytic hydrogenation of kerosene, the catalysts A', B', C' and D' were activated by treatment with hydrogen in the hydrocconversion reactor at a temperature of 3800C, a pressure of 30 bar and a hydrogen feed rate of 1200 Nltkg feed for 16 hours. After this activation treatment the temperature of the reactor was adjusted to the level required to obtain 80% by volume de-aromatization of the kerosene feed (further indicated as: Activity, T80%) with the use of, respectively, catalysts A', B', C' and D'. The results of the experiments are given in Table I hereinafter. The kerosene used as feed contained 16.1 % by volume of aromatic compounds and 12 pppw of sulphur. Further hydrogenation reaction conditions were: total pressure : 30 bar space velocity : 5.0 g of kerosene/g of catalyst/hour hydrogen feed rate : 400 Nl/kg feed The product stream was analysed by means of refractive index measurements. TABLE I Experiment No. Catalyst Activity, T80%(0C) 1 A' 288 2 B' 248 3 C' ¯ 280 (unstableJ 4 D' 307 From the results shown it is clear that the modification of silica with tetramethyl ammonium aluminate results in a considerably more active catalyst (B') in comparison with catalysts (A',C',D') which have not been modified by the process according to the present invention. Evaluation of the catalysts E' and F' of Example 2 was carried out in the same manner as described for catalysts A'-D', but in 30 ml reactors containing 15 g of catalyst particles diluted with an equal volume of silicium carbide particles with a diameter of 0.2 rtrn. The kerosene feed contained 16.1 % by volume of aromatic compounds, 12 ppmw of sulphur and 20 ppuw of nitrogen. The results are given in Table II. TABLE II Experiment No. Catalyst Activity, T80%( C) 5 E' 303 6 F' 275 Fran Table II it will be clear that the catalyst based on the modified refractory oxide according to the present invention (F') is considerably more active than catalyst E' which has not been modified by the preparation process according to the present invention. EXAMPLE 4 Two platinum-containing catalysts (G and H) were prepared as follows. G Silica spheres with a diameter of fram 1.5-2 mn, a pore volume of 0.74 ml/g and a specific surface area of 294 m2/g were pre-dried at 2000C for 3 hours. A quantity of 100 g of pre-dried silica spheres was impregnated with 388 ml of an aqueous solution comprising 39 g of tetramethyl ammonium aluminate at ambient temperature for 3 hours in a nitrogen atmosphere and subsequently kept in an autoclave for a further 16 hours at ancient temperature. The treated silica spheres were dried at 2000C for 3 hours and subsequently calcined in air at 6000C for 3 hours. The calcined spheres obtained contained 5.1 %w aluminium, calculated as A1203 (based on the total weight of the spheres); the pore volume was 0.65 ml/g and the specific surface area 346 m2/g. A quantity of 35 g of the calcined spheres was impregnated with a solution of 373 mg of H2PtC16 and 2.4 ml of HC1 (38 %v) in 43 ml of water, after which water was evaporated at 600C and the product was dried at 1500C and subsequently calcined in air at 5000C for 2 hours. The resultant catalyst G contains 0.4 %w of platinum, calculated on the weight of calcined, platinum-free spheres. H Preparation of a comparative catalyst. A quantity of 70 g of pre-dried silica spheres, with a pore volume of 0.64 ml/g and a specific surface area of 257 m2/g was exchanged with a solution of 10.95 g of Pt (NH3) 4 2 in 1 1 of water for 48 hours after which the product was washed with water, dried at 1500C and subsequently calcined in air at 5000C for 2 hours. The resultant catalyst H contains 0.9% by weight of platinum, calculated on the weight of the pre-dried silica spheres. EI(AMPI;E 5 Catalytic hydroisanerization of slack wax. Catalysts G and H as described in Example 4 were evaluated on the basis of the results of experiments performed in trickle flow units. The slack wax feed to be hydroisccarized, which was entirely or substantially in the liquid phase, was trickled downwardly co-currently with the hydrogen-containing gas through the fixed catalyst beds. The units were equipped with 100 rnl reactors cperated in once-through mode and contained 25 g of catalyst particles diluted with 73 g of silicium carbide particles with a diameter of 0.2 nrn. Before being used for the catalytic hydroisomerization of slack wax, the catalysts G and H were activated by treatment with hydrogen in the hydroisomerization reactor at a temperature of 4500C, a pressure of 140 bar and a hydrogen feed rate of 1000 Nl/kg feed for 16 hours. After this activation treatment the temperature of the reactor was adjusted to the level required to obtain 70 w conversion of the slack wax feed (further indicated as: Activity, T70%) with the use of, respectively, catalysts G and H. The slack wax used as feed contained 26 %w oil, 2.3 pFmW of sulphur and < 1 pprw of nitrogen and was obtained as by-product during the preparation of extra high viscosity index lubricating oils. The results of the experiments are given in Table III hereinafter. Further hydroisomerization reaction conditions were: Total pressure : 140 bar Space velocity : 2.0 kg of slack wax/l of catalyst/hour Hydrogen/feed rate: 1000 Nl/kg feed The product stream was analysed by means of low resolution NMR and gas/liquid chromatography. "Selectivity, S70%" indicated in Table III below is defined as: oil in product - oil in feed (%w) oil selectivity = x 100 wax in feed - wax in product (%w) at 70 %w conversion of slack wax. TABLE III Experiment No. Catalyst Activity, T70%( C) Selectivity, S70%(%w) 7 G 342 59 8 H > 400 * *) Because of the inactivity below 4000C of catalyst H the level of 70 %w conversion of slack wax was not attained. The viscosity indices of lubricating oils obtained by fractionating the product from Experiment No. 7 amounted to 154 156. From the results given in Table III it is clear that catalyst G obtained by treatment of silica with tetramethyl ammonium a laminate is considerably more active than catalyst H which has been prepared in a conventional manner. Catalyst G also exhibits excellent selectivity for the preparation of high viscosity index lubricating oils.

Claims: CLAIMS 1. Process for the conversion of hydrocarbons, wherein hydrocarbons are contacted with hydrogen at hydroconversion conditions using a catalyst comprising at least one hydrogenating metal or cccpound thereof present on at least one refractory oxide which has been treated with fran 0.1 to 30 Fw, calculated on refractory oxide, of at least one reactive metal conpcund of Group 2a, 3a, 4a and/or 4b of the Periodic Table of the Elements. 2. Process according to claim 1, wherein petroleum waxes are contacted with hydrogen at hydroisomerization conditions. 3. Process according to claim 1, wherein kerosene is contacted with hydrogen at dearanatization conditions. 4. Process according to any one of the preceding claims, wherein use is made of catalysts comprising as refractory oxides silica, alumina, magnesia, zirconia, titania, crania, boria or catinations thereof. 5. Process according to claim 4, wherein use is made of catalysts camprising silica with a pore volume of at least 0.5 ml/g and a specific surface area of from 100 to 600 m2/g. 6. Process according to any of the preceding claims, wherein use is made of substantially spherical catalyst particles. 7. Process according to any of the preceding claims, wherein use is made of catalysts ccmprising treated refractory oxides containing fram 0.1 to 10 %w of reactive metal(s), calculated as metal oxides and based on refractory oxide. 8. Process according to claim 7, wherein use is made of catalysts comprising refractory oxides treated with reactive metal moieties comprising magnesium, aluminium, titanium and/or zirconium. 9. Process according to claim 2 or any one of claims 4-8, wherein the petroleum waxes used as feed are slack waxes obtained as by-product during the preparation of lubricating oils. 10. Process according to claim 9, wherein slack waxes used as feed are obtained as by-product in the preparation of lubricating oils by hydrocracking. 11. Process according to claim 2 or any one of claims 4-10, which is carried out at a temperature in the range of fran 250 to 450 OC, a pressure in the range of fran 10-250 bar, a space velocity in the range of fran 0.1 to 5 kg feed/l catalyst/hour and a hydrogen/feed ratio in the range of from 100 to 2500 N1 H2/kg feed. 12. Process according to claim 2 or any one of claims 4-11, wherein one or more lubricating oil fractions are isolated from the hydrosiomerization product obtained. 13. Process as claimed in claim 2 or any one of claims 4-12, substantially as hereinbefore defined with reference to Examples 4 and 5. 14. Process for the preparation of modified refractory oxides which comprises impregnating refractory oxides or mixtures thereof with at least one hydrocarbyl ammonium metallate and/or compounds thereof with at least one hydrocarbyl ammonium moiety and at least one reactive metal moiety of Group 2a, 3a, 4a and/or 4b of the Periodic Table of the Elements. 15. Process according to claim 14, wherein use is made of a hydrocarbyl ammonium moiety comprising one or more alkyl groups with 1-4 carbon atoms. 16. Process according to claim 14 or 15, wherein refractory oxides are impregnated with a solution comprising the nitrate(s) of one or more of the reactive metal(s) and subsequently with a solution comprising at least one hydrocarbyl ammonium hydroxide. 17. Process according to claim 16, wherein use is made of hydrocarbyl amronium hydroxide and refractory oxides in a weight ratio of fran 0.01 to 1, and preferably fran 0.1 to 0.5. 18. Process according to claim 15, wherein refractory oxides are impregnated with a solution comprising tetramethyl annionium aluminate. 19. Process as claimed in any one of claims 14-18, substantially as hereinbefore described with reference to Example 1. 20. modified refractory oxides whenever prepared according to a process as claimed in any one of claims 14-19. 21. Process for the preparation of catalysts, wherein modified oxides according to claim 20 are loaded with one or more metals of the Groups 6b and/or 8 of the Periodic Table of the Elements, and/ or ccmpounds thereof. 22. Process according to claim 21, substantially as described hereinbefore with reference to Example 2. 23. Catalysts whenever prepared according to a process as claimed in claim 21 or 22.

Inventors: LEVAVASSEUR, JACQUES ANDRE, LUCIEN, JACQUES PIERRE, NEEL, EMMANUEL EMILE ALFRED, REINALDA, DONALD, Levavasseur, Jacques André
Applicants: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
Application year: 1984
Main classification: C10G45
IPC codes: C10G45, B01J37