MERCURY ADSORBENT CARBONS AND CARBON MOLECULAR SIEVES

Abstract: The instant invention is directed to a nut shell carbon impregnated with from about 0.005 to about 15 percent, by weight, of sulfur, and a carbon molecular sieve, having a nitrogen diffusivity of less than 2600 × 10⁻⁸cm²/second, impregnated with from about 0.005 to about 15, preferably 0.01 to 10, most preferably 3 to 7, percent, by weight, of a mercury reactive material. The instant invention is also directed to a process for removing mercury vapor from gas streams comprising passing a gas stream containing mercury vapor into contact with a nut shell carbon impregnated with from about 0.005 to about 15 percent, by weight, of sulfur, and to a process for removing mercury vapor from gas streams which comprises passing a gas stream contain­ ing mercury vapor into contact with a carbon molecular sieve, having a nitrogen diffusivity of less than 2600 × 10⁻⁸cm²/second, impregnated with from about 0.005 to about 15 percent, by weight, of a mercury reactive material.

Description: "MERCURY ADSORBENT CARBONS AND CARBON MOLECULAR SIEVES" Background of the Invention Mercury vapor has been removed from gas streams by a number of different adsorbents. See for example, U.S. Patent 3,194,629 describing activated carbon impregnated with potassium triiodine or sulfur; U.S. Patent 3,876,393 describing activated carbon impregnated with sulfuric acid; U.S. Patent 3,193,987 describing activated carbon impregnated with silver or copper salts; and U.S. Patent 4,101,631 describing zeolites containing elemental sulfur. Generally, these adsorbents are only effective when relatively large concentrations of mercury are present and, each adsorbent has a lower limit, below which, mercury vapor is either inefficiently adsorbed or not adsorbed at all. It has been discovered that nut shell carbons and carbon molecular sieves impregnated with sulfur are effective adsorbents especially of very low concentrations of mercury vapor. It was also found that nut shell carbons and carbon molecular sieves impregnated with sulfur are less adversely affected by water and by temperature than the prior art adsorbents. Description of the Invention The instant invention is directed to a nut shell carbon impregnated with from about Q.005 to about 15 percent, by weight, of sulfur, and a carbon molecular sieve, having a nitrogen diffusivity of less than 2600x10 8 cm2/second, impregnated with from about 0.005 to about 15, preferably 0.01 to 10, most preferably 3 to 7, percent, by weight, of a mercury reactive material. The instant invention is also directed to a process for removing mercury vapor from gas streams comprising passing a gas stream containing mercury vapor into contact with a nut shell carbon impregnated with from about 0.005 to about 15 percent, by weight, of sulfur, and to a process for removing mercury vapor from gas streams which comprises passing a gas stream containing mercury vapor into contact with a carbon molecular sieve, having a nitrogen diffusivity of less than 2600x10 8 cm2/second, impregnated with from about 0.005 to about 15 percent, by weight, of a mercury reactive material. Nut shell carbons, impregnated with from 0.005 to 15 weight percent, preferably at least 0.01 weight percent, most preferably at least 3 weight percent of sulfur are useful adsorbents for removing mercury vapor from gas streams, especially at low level mercury vapor concentrations. The carbons are especially effective at mercury vapor concentrations, P, at a given pressure and temperature, defined as PC(4xlt 6)xPs, preferably P < (lx10 6)xPs, where P5 is the mercury vapor saturation pressure at the aforementioned given pressure and temperature. Likewise, carbon molecular sieves impregnated with from 0.005 to 15 weight percent, preferably 0.01 to 10 weight percent, most preferably from 3 to 7 weight percent of a mercury reactive material are useful adsorbents for removing mercury vapor from gas streams, especially at low level mercury vapor concentrations. The carbons are especially effective at mercury vapor concentrations, P, at a given pressure and temperature, defined as P < (4x10 )xP5, preferably P < (1x10 )xP5, where P5 is the mercury vapor saturation pressure at the aforementioned given pressure and temperature. Carbon molecular sieves are porous substrates with an open-network structure of controlled molecular dimension which may be used to separate mixtures of small molecules from larger molecules, based on a difference in molecular size or a difference in diffusivity rates. U.S. Patent 3,884,830, which is hereby incorporated by reference, describes the manufacture of an activated carbon molecular sieve. Carbon molecular sieves have been prepared from a variety of substrates by a number of different manufacturing processes. Examples include anthracite coal (U.S. Patent 3,222,412); coke or coconut shells, elevated temperatures and pore blocking by carbon deposition (U.S. Patent 3,801,513); vinylidene chloride copolymers (U.S. Patent 4,046,709); and bituminous coal or coconut shells, elevated temperatures and an inert atmosphere (U.S. Patent 2,556,859). The preferred substrates are coal and nut shells. Carbon molecular sieves may also be defined in the present invention as having a nitrogen diffusivity of less than 2600x10-8 cmê/second, preferably 1x10-8 cm2/second to 2600x10 8 cm2/second, more preferably 10x10 8 cm2/second to 2600x10 8 cm2/second, and most preferably 10x10 8 cm2/second to 300x10 cm /second, prior to impregnation. The removal of mercury vapor from the aforementioned gas streams with the impregnated nut shell carbons or with the impregnated carbon molecular sieves may be accomplished in any manner available to the skilled artisan. Generally, the gas stream is contacted with a quantity of the sulfur impregnated nut shell carbons or mercury reactive material impregnated carbon molecular sieves. This may be accomplished in one or more adsorbent beds, through which the mercury vapor laden gas is passed. There may also be employed additional mercury adsorbents, such as mercury reactive material containing zeolite and/or the carbon described in U.S. Patent 3,194,629. These adsorbents are commercially available from Union Carbide Corporation and Calgon Carbon Corporation respectively. In preferred embodiments of the instant invention, the mercury-vapor-laden gas stream is brought into contact with an activated coal-based carbon or zeolite molecular sieve impregnated with a mercury reactive material and subsequently passing the mercury stream through the nut shell carbon or carbon molecular sieve impregnated with a mercury reactive material. Examples of the mercury reactive materials which may be used include oxidizing agents and amalgamating metals. Examples of oxidizing agents include: S; Fecal3; sulfides, such as CuS, AgS; Ski3; KIO3; NaOCl; MnO2 and PbC12. Examples of metals include: gold, silver, tin and copper. Gas streams contemplated to come within the scope of this invention include: natural gas streams, industrial gas streams contaminated with mercury, such as hydrogen gas from a chlor-alkali plant, furnace stack gases, battery disposal incinerator gases and the like; hydrogen purification streams and the like; air, hydrocarbon gases, carbon dioxide, carbon monoxide, oxygen, nitrogen and the like. Any nut shell char may be used, preferably coconut shell or babassu nut chars. The char may be activated or unactivated. An example of an activated coconut shell char commercially available includes GRC-II and of an unactivated coconut char (carbon molecular sieve), CMX-1, both manufactured by Calgon Carbon Corporation. Any nut shell char may be used in the present invention. The nut shell char is prepared merely by heating the shells at a temperature sufficient to char (i.e. carbonize) the shells. Reduced oxygen conditions are necessary to prevent complete burning. The charred shells are generally crushed and screened to the desired mesh size. Mesh size is not a critical factor. U.S. sieve sizes of from 3x6 to 50x100 may be employed. The char may, optionally, be activated by the presence of steam, carbon dioxide or oxidizing agents. Charring and activation are described in U.S. Patent 3,884,830, which is hereby incorporated by reference. Any carbon molecular sieve may be used. Examples include CMX-1, GRC-II and MSC-V, manufactured by Calgon Carbon Corporation. CMX-1 is a non-activated carbon molecular sieve. GRC-II and MSC-V are slightly activated carbon molecular sieves. The carbons or molecular sieves may be impregnated with sulfur in any convenient manner. For example, solid elemental sulfur and granular carbon may be admixed and heated at about 150 C. Additional heating at about 1500C or above for from 10 to 90 minutes causes complete impregnation of the sieve pores by the sulfur. Alternatively, the sulfur may be dissolved in a solvent such as carbon disulfide, and the solvent contacted with the carbon. Typical methods include spraying, dipping, and the like. Excess solution is removed by decanting or filtering and the sieve is dried. Drying may be accomplished at room temperature, or at elevated temperatures. Vacuum may also be employed to aid in removing solvent. The carbons used in Examples 1 through 11 are described in Table I. TABLE I Hg Vapor Removal Limit (Wg/m3) 20 - 250C Carbon Ambient Pressure BPLta .071 CMX-la .0016 GRC-IIa .0018 Babassu Nut .0040 *Comparison aManufactured by Calgon Carbon Corporation EXAMPLES Example 1 - Preparation of CMX-1 Coconut char was fed to an enclosed drive-belt furnace at 30 pounds per hour. The furnace temperature was 1800 F and the furnace residence time was 30 minutes. A constant nitrogen purge, countercurrent to feed flow, was maintained at 25 standard cubic feet per minute (SCFM). The atmosphere was maintained at less than 500 ppm oxygen. To calculate a test gas (e.g. oxygen, nitrogen, etc.) diffusivity value, the dead volume of a sample cell containing about 10 grams of carbon sieve was determined by helium expansion. The test gas was then expanded into the re-evacuated sample cell from a one-liter reference cell. Knowing the dead volume, adsorption (loading) of any test gas was monitored by the change in pressure of the system. These values combined with an equilibrium loading value calculated for a sieve sample after one hour (at STP) allowed the determination of a relative loading value (Lt/Le). Lt was the test gas loading value of a sieve sample at a given time, for example 30 seconds, and Le was the test gas loading value of a sieve sample at equilibrium. The gas diffusivity value (D) of a sieve sample was then calculated for the test gas by solving the simplified equation for diffusion into a sphere: EMI8.1 where D = gas diffusivity value t = time in seconds Ro = mean particle radius of a carbon sieve (0.05125 cm) See: R. L. Dedrick and R. B. Beckmann, "Kinetics of Adsorbtion by Activated Carbon from Dilute Aqueous Solution", Physical Adsorption Processes and Principles, L. N. Canjar and J. A. Kostecki, eds., Vol. 63, American Institute of Chemical Engineers, New York (1967); P. L. Walker, Jr., L. G. Austin and S. P. Nandi, "Activated Diffusion of Gases in Molecular Sieve Materials", The Chemistry and Physics of Carbon, P. L. Walker, Jr., ed., Vol. 2, Marcel Dekker, Inc., New York (1966) and J. Crank, "The Mathematics of Diffusion", 2nd Ed., Clarendon Press, Oxford (1975). Determination of oxygen and nitrogen diffusivity values allowed for calculation of the oxygen/nitrogen selectivity ratio: S = DO2/DN2. A carbon sieve having the following physical characteristics was produced: (A) oxygen diffusivity 693 x 10-8 cm/sec2 (B) oxygen/nitrogen selectivity 7.19 ratio (C) oxygen equilibrium volume STP gas 6.7 cc/g carbon (D) oxygen equilibrium volume STP gas 4.3 cc/cc bed volume carbon (E) apparent density g/cc 0.64 Example 2 The carbon of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 C for 90 minutes. A dry air stream, having an inlet mercury concentration of 17,900 g/m3 was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 420C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .005 g/m . The results are presented in FIGURE 1. Example 3 The carbon of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 0C for 45 minutes and at 1700C for an additional 45 minutes. A dry air stream, having an inlet mercury concentration of 30,800 Wg/m3 was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 460C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .012 g/m . The results are presented in FIGURE 1. Example 4 The carbon of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 10 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 1500C for 90 minutes. A dry air stream, having an inlet mercury concentration of 22,709 g/m3 was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 44 0C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .014 pg/m3. The results are presented in FIGURE 1. Example 5 The carbon of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 10 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 0C for 45 minutes and at 165 C for an additional 45 minutes. A dry air stream, having an inlet mercury concentration of 21,200 Wg/m3 was passed through a column containing the sulfur impregnated coconut char, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 44 0C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .008 Wg/m3. The results are presented in FIGURE 1. Example 6 Dry air, having a high mercury vapor concentration, was passed through the carbon of Example 1 impregnated with sulfur (5 percent sulfur loading, impregnated at 1500C for 90 minutes heating time) at ambient pressure and temperatures of 20 0C and 42 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flowrate of the air was 23 ft/min. The above procedure was repeated at 18 0C and 420C with the sulfur impregnated carbon of Example 1 being replaced with Union Carbide 1/16 mole sieve (a sulfur impregnated zeolite mercury adsorbent). Results (FIGURE 2) obtained at 420C show the mercury vapor removal limit of the sulfur impregnated zeolite (0.008 Wg/m3) to be inferior to that of the sulfur impregnated Example 1 carbon (.003 Wg/m3). It should also be noted that the removal limit of the carbon molecular sieve does not appear to be highly dependent on the mercury partial pressure. Results (FIGURE 33 obtained at lower temperatures (18 and 20 C) show the Union Carbide mole sieve (at 18 C) to be ineffective due to very poor mercury vapor removal kinetics. The sulfur impregnated coconut char has a mercury vapor removal limit of less than .002 Wg/m3 at a nearly equivalent temperature (20 C). Example 7 Dry air, having a high mercury vapor concentration, was passed through a column containing the carbon of Example 1 impregnated with sulfur (5 percent sulfur loading, impregnated at 150 C, followed by heating at 150 0C for 90 minutes) at a linear flowrate of 23 ft/min. Pressure and temperature were ambient. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. This procedure was repeated with H2O saturated air replacing the dry air. The H2O saturated air stream had been passed through the column for 16 hours before analysis was performed. Both of the above procedures were repeated with sulfur impregnated GRC-II (15 percent w/w sulfur, impregnated at 150 C followed by heating at 150 0C for 90 minutes) replacing the sulfur impregnated coconut char described above. GRC-II is an activated coconut shell-based carbon. As expected, the mercury vapor removal limit is the same for both carbons (FIGURE 4) for dry adsorber beds. As may be seen in FIGURE 4, the mercury vapor removal limit of the sulfur impregnated GRC-II is affected by adsorbed H2O, while that of the sulfur impregnated coconut char is less severely affected due to its pore size being so constricted as to inhibit easy adsorption of H Example 8 The carbon of Example 1 was sprayed with an aqueous solution of ferric chloride (14 g of FeC136H2O, 100 ml of H2O, 700 g CMX-1). The resulting damp carbon was air dried several days. The impregnated carbon was placed in a column through which mercury vapor saturated air was passed at 20 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results are presented in FIGURE 5. Example 9 The carbon of Example 1 was sprayed with an aqueous solution of potassium triiodide (19.0 g KI, 8.5 g 12, 300 cc H2O, 700 g CMX-1). The resulting damp carbon was air dried several days. The impregnated carbon was placed in a column through which mercury vapor saturated air was passed at 20 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results are presented in FIGURE 6. Example 10 Calcined babassu nut char (10x30 mesh, calcined at 950 C) was mixed at 150 C with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 0C for 90 minutes. Dry air, having a high mercury vapor concentration, was passed through the sulfur impregnated calcined babassu nut char at 20 C and ambient pressure. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results (FIGURE 7) show the mercury vapor removal limit of the sulfur impregnated MSC-V to be 0.004 g/m . Example 11 (Comparison Example) Dry air, having a high mercury vapor concentration, was passed through BPL, a coal-based activated carbon, [ impregnated with 15 percent (w/w) sulfur, manufactured by Calgon Carbon Corporation, Pittsburgh, Pennsylvaniaj at 24 C and ambient pressure. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results (FIGURE 8) show the mercury vapor removal limit of BPL to be 0.071 g/m3 under these conditions. The carbons used in Examples 12 through 24 are shown in Table II. TABLE II Hg Vapor Removal Limit ( /m ) 2G - 250C Nitrogen Diffusivity Carbon Ambient Pressure (x10-8 cm2/second) BPL*a .071 2786 Bergbaub .025 2.14 CMX-1a .0016 59.3 MSC-Va .004 2527 GRC.IIa .0018 2200 Babassu Nut .0040 170 *Comparison (not a molecular sieve) aManufactured by Calgon Carbon Corporation. bManufactured by Bergbau Forshung. EXAMPLES Example 12 The carbon molecular sieve of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent tw/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 C for 90 minutes. A dry air stream, having an inlet mercury concentration of 17,900 g/m was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 42 0C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .005 Wg/m3. The results are presented in FIGURE 9. Example 13 The carbon molecular sieve of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 C for 45 minutes and at 170 0C for an additional 45 minutes. A dry air stream, having an inlet mercury concentration of 30,800 g/m was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 46 0C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .012 g/m . The results are presented in FIGURE 9. Example 14 The carbon molecular sieve of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 10 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 1500C for 90 minutes. A dry air stream, having an inlet mercury concentration of 22,700 A/m3 was passed through a column containing the above-described sulfur impregnated CMX-1, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 440C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .014 Wg/m . The results are presented in FIGURE 9. Example 15 The carbon molecular sieve of Example 1 was mixed, at 150 C, with a sufficient quantity of sublimed elemental sulfur to provide a 10 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 150 C for 45 minutes and at 1650C for an additional 45 minutes. A dry air stream, having an inlet mercury concentration of 21,200 g/m was passed through a column containing the sulfur impregnated coconut char, at a linear velocity of 23 ft/min. The column and inlet air stream were maintained at a temperature of 440C and ambient pressure. A contact time of 8 seconds was sufficient to reduce the mercury vapor concentration to .008 Wg/m3. The results are presented in FIGURE 9. Example 16 Dry air, having a high mercury vapor concentration, was passed through the carbon molecular sieve of Example 1 impregnated with sulfur (5 percent sulfur loading, impregnated at 150 0C for 90 minutes heating time) at ambient pressure and temperatures of 200C and 42 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flowrate of the air was 23 ft/min. The above procedure was repeated at 18 C and 42 0C with the sulfur impregnated carbon molecular sieve of Example 1 being replaced with Union Carbide 1/16 mole sieve (a sulfur impregnated zeolite mercury adsorbent). Results (FIGURE 10) obtained at 42 C show the mercury vapor removal limit of the sulfur impregnated zeolite (0.008 g/m ) to be inferior to that of the sulfur impregnated Example 1 carbon (.003 g/m3). It Itshould also be noted that the removal limit of the carbon molecular sieve does not appear to be highly dependent on the mercury partial pressure. Results (FIGURE 11) obtained at lower temperatures (18 and 20 C) show the Union Carbide mole sieve (at 18 C) to be ineffective due to very poor mercury vapor removal kinetics. The sulfur impregnated coconut char has a mercury vapor removal limit of < .002 Wg/m3 at a nearly equivalent temperature (20 C). Example 17 Dry air, having a high mercury vapor concentration, was passed through a column containing the carbon molecular sieve of Example 1 impregnated with sulfur (5 percent sulfur loading, impregnated at 150 C, followed by heating at 150 C for 90 minutes) at a linear flowrate of 23 ft/min. Pressure and temperature were ambient. Ports situated along the length of the column were sampled. to determine the mercury vapor concentration in the air after known contact times with the adsorbent. This procedure was repeated with H2O saturated air replacing the dry air. The H2O saturated air stream had been passed through the column for 16 hours before analysis was performed. Both of the above procedures were repeated with sulfur impregnated GRC-II (15 percent w/w sulfur, impregnated at 1500C followed by heating at 1500C for 90 minutes) replacing the sulfur impregnated coconut char described above. GRC-II is a coconut shell-based carbon. GRC-II is an activated carbon. As expected, the mercury vapor removal limit is the same for both carbons (FIGURE 12) for dry adsorber beds. As may be seen in FIGURE 12, the mercury vapor removal limit of the sulfur impregnated GRC-II is severely affected by adsorbed H2O, while that of the sulfur impregnated coconut char is less severely affected due to its pore size being so constricted as to inhibit easy adsorption of H2O. Example 18 The carbon molecular sieve of Example 1 was sprayed with an aqueous solution of ferric chloride (14 g of FeC136H2O, 100 ml of H2O, 700 g CXX-1). The resulting damp carbon was air dried several days. The impregnated carbon was placed in a column through which mercury vapor saturated air was passed at 20 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results are presented in FIGURE 13. Example 19 The carbon molecular sieve of Example 1 was sprayed with an aqueous solution of potassium triiodide (19.0 g KI, 8.5 g I2, 300 cc H2O, 700 g CMX-1). The resulting damp carbon was air dried several days. The impregnated carbon was placed in a column through which mercury vapor saturated air was passed at 20 C. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results are presented in FIGURE 14. Example 20 MSC-V (a commercial slightly-activated, coal-based, molecular sieve carbon, manufactured by Calgon Carbon Corporation, Pittsburgh, Pennsylvania) was mixed at 150 0C with a sufficient quantity of sublimed elemental sulfur to provide a 5 percent (w/w) sulfur loading until the mixture was uniforja. This mixture was then heated at 150 C for 90 minutes. Dry air, having a high mercury vapor concentration, was passed through the sulfur impregnated MSC-V at 20 C and ambient pressure. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results (FIGURE 16) show the mercury vapor removal limit of the sulfur impregnated MSC-V to be 0.004 pg/m3. Example 2 1 Bergbau molecular sieve, a coal-based carbon molecular sieve (manufactured by Bergbau Forshung), was mixed at 150 0C with â sufficient quantity of sublimed elemental sulfur to provide 5 percent (w/w) sulfur loading until the mixture was uniform. This mixture was then heated at 1500C for 90 minutes. Dry air, having high mercury vapor concentration, was passed through the sulfur impregnated Bergbau molecular sieve at 200 C and ambient pressure. Ports situated along the length of the column were sampled to determine the mercury vapor concentration in the air after known contact times with the adsorbent. The linear flow rate of the air was 23 ft/min. Results (FIGURE 18, upper line) show the mercury vapor removal kinetics of this sulfur impregnated carbon to be extremely slow. A mercury vapor removal limit was not reached within the column length. When the inlet mercury vapor concentration was reduced (FIGURE 18, lower line) the mercury vapor removal kinetics were further slowed. A mercury vapor removal limit appears to be reached at valued slightly less than .025 g/m3 for any practicle contact time.

Claims: WHAT IS CLAIMED IS: 1. A nut shell carbon impregnated with from about 0.005 to about 15 percent, by weight, of sulfur. 2. A process for removing mercury vapor from gas streams comprising passing a gas stream containing mercury vapor into contact with a nut shell carbon impregnated with from about 0.005 to about 15 percent, by weight, of sulfur. 3. The process of Claim 2, wherein the initial mercury vapor level, P, at a given pressure and temperature, is at a concentration defined as P < (5.5x10-6)xPs, where Ps is the mercury vapor saturation pressure at said given pressure and temperature. 4. A process for removing mercury vapor from gas streams, comprising sequentially contacting the gas stream with: (a) an activated coal-based carbon impregnated with a mercury reactive material and (b) a nut shell carbon impregnated with from 0.005 to about 15 percent, by weight, of a mercury reactive material. 5. A process for removing mercury vapor from gas streams, comprising sequentially contacting the gas stream with: (a) a zeolite molecular sieve impregnated with a mercury reactive material and (b) a nut shell carbon impregnated with from 0.005 to about 15 percent, by weight, of a mercury reactive material. 6. A carbon molecular sieve, having a nitrogen diffusivity of less than 2600x10 8 cm2/second, impregnated with from about 0.005 to about 15 percent, by weight, of a mercury reactive material. 7. A process for removing mercury vapor from gas streams which comprises passing a gas stream containing mercury vapor into contact with a carbon molecular sieve, having a nitrogen diffusivity of less than 2600x10 8 cm2/second, impregnated with from about 0.005 to about 15 percent, by weight, of a mercury reactive material. 8. The process of Claim 7, wherein prior to contacting the gas stream with said mercury reactive impregnated carbon molecular sieve, said gas stream is first brought into contact with a carbon impregnated with a mercury reactive material. 9. The process of Claim 7, wherein prior to contacting the gas stream with said mercury reactive impregnated carbon molecular sieve, said gas stream is first brought into contact with a zeolite molecular sieve impregnated with a mercury reactive material. 10. The process of Claim 7, wherein the initial mercury vapor concentration, P, at given pressure and temperature, defined as P < (5.5x10 )xP5, where Ps is the mercury vapor saturation pressure at said given pressure and temperature.

Inventors: GEBHARD, ROBERT S., GREENBANK, MICHAEL, MATVIYA, THOMAS M.
Applicants: CALGON CARBON CORPORATION
Application year: 1984
Main classification: B01J20
IPC codes: B01D53, B01J20