INJECTION MOLDING METHOD OF MANUFACTURING CONTAINER COVERS

Abstract: A method for manufacturing a cover for a can-like container providing improved peelability of a handle. The cover (3) is made by forming a second resin layer (58, 59) by injection molding on a multi-layer sheet (64) which oxygen, water, and the like cannot permeate. A thermally weldable first resin layer (66) is provided on the upper surface of the multi-layer sheet (64). The handle is formed by the second resin layer. A treatment is carried out for allowing the handle to be easily peeled off the multi-layer sheet to all or part of a region of the multi-layer sheet in contact with the underside of the handle.

Description: The invention relates to an injection molding method for manufacturing a readily openable can-like container's cover of the kind defined by the prechracterizing features of claim 1. A method of this kind is known from the US-A-4210618. This known method provides for an injection molding of the second outer resin layer on to a first inner resin layer, said second layer including an opening part having a handle which is made thicker than the peripheral part and provided with a gripping edge. The handle runs into a prong which likewise is formed with said thicker material. By this means said prong easily can pierce the first inner resin layer when the handle is forced upwardly. The handle itself, however, cannot be readily peeled off the peripheral part because it is strongly connected to it along its circumference via the resin material bridging said opening part with the peripheral part. In order to improve the openability of the opening part having the handle, a slot or groove may be formed in the cover between the opening part and the peripheral part so that the opening part is opend along said slot. However, the formation of the slot unavoidably lowers the moldability. In oder to overcome this difficulty, it is knwon from the Japanese Laid-Open Patent Application No. 39489/1977 to divide the slot into a plurality of parts, i.e., instead of one slot, so that a plurality of slots connected through bridges are formed to permit the smooth flowing of the molding material to maintain the moldabilty. However, it is obvious that the openabilty is lowered by said bridges. It is the object of the invention to provide an injection moding method of the kind defined by the precharacterizing features of claim 1, which allows the mulit-layer sheet and the outer resin layer including the opening part and the peripheral part to be strongly joined together, but the handle to be readily peeled off the multi-layer sheet. This object is attained with the characterizing features of claim 1. The invention is intended to provide a container's cover manufactured by simultaneous injection molding which is excellent both in moldability and in openability. A container's cover excellent in various characteristics such as moldability and openability can be successfully manufactured according an injection molding method in which, according to the invention, a second resin layer including an opening part having a handle and a peripheral part which are completely separated by a slot is formed by injection molding on one side of a multi-layer sheet which is fabricated by forming thermally meltable first resin layers on two or one side of a base material such as a metal foil, sheet or film which oxygen, water, etc. cannot permeate, in such a manner that at least one gate is used for formation of each of the opening part and peripheral part. In the following the advantages obtained by the method according to the invention will be described in more detail along the drawing. Fig. 1 is a perspective view showing a can-like container with a rectangular cover to which this invention relates; Fig. 2 is a perspective view showing a can-like container with a round cover to which the invention relates; Figs. 3, 5, 7, 9 are top views of different embodiments of container tops according to the invention; and Figs. 4, 6, 8, 10 are cross-sectional views of the covers of Figs. 3, 5, 7, 9 respectively. A can-like container to which the invention relates is shown in Fig. 1 and 2. Fig. 1 is a perspective view showing a can-like container having a side wall 1, a bottom 2 and a rectangular cover 3. Fig. 2 is also a perspective view showing a can-like container having a side wall 4, a bottom 6 and a round cover 6. In Figs. 3 and 4, reference numeral 3 designates the cover; 58, an opening part formed by the second resin layer; 59 a peripheral part formed by the second resin layer; and 60, a slot. The slot 60 is in the form of a closed ring as shown in Fig. 3, and therefore the opening part 58 is completely separated from the peripheral part 59 by the slot 60. Further in Figs. 3 and 4, reference numeral 11 designates a handle provided on the opening part 58; and 62, a cutting opening part 62 by a groove 63. In Fig. 4, reference numeral 64 designates a multi-layer sheet, which is manufactured by forming first resin layers 66 and 67 on both sides of a gas barrier type base material. The can-like container's cover 3 according to the invention is fixedly mounted on the side wall 1 of the can-like container as shown in Fig. 4. The rectangular cover 3 is opened as follows: When the handle 11 is raised with the finger tip inserted into groove 63, the handle 11 is peeled off the multi-layer sheet 64. As a result, the end 69 of the handle 1 goes inside the multi-layer sheet 64 to cut the latter. When, under this condition, the handle 11 is pulled, the multi-layer sheet 64 is cut along the slot 60 so that the opening part 58 of the cover is opened. In the container's cover according to the invention, the opening part 58 is completely separated from the peripheral part 59 by the slot 60; i.e., no bridge is provided between the parts 58 and 59. Therefore, the opening part 58 can be readily opened. This readily openable container's cover can be produced using an injection molding method of the invention. The method will be described with reference to Figs.3 and 4 . The opening part 58 and the peripheral part 59 are molded using respective gates. That is, the opening part 58 is independently molded using its gate, while the peripheral part 59 is also independently molded by using its own gate. The slot 60 is formed by the mold. At least one gate should be provided for molding the opening part 58, and similarly at least one gate should be provided for molding the peripheral part 59. The positions of the gates are indicated by reference characters 70(G1) and 71(G2) in Fig. 3 . That is, the opening part 58 is molded using the gate 70(G1), while the peripheral part 59 is molded using the gate 71(G2). In the injection molding method using a plurality of gates, the moldability is excellent and the injection molding operation can be achieved readily. Therefore, materials having a low moldability such as materials having small melting factors (MFR) or resins with fillers can be used in the injection molding method. As was described before, in the conventional method, it is necessary to take the moldability into consideration, i.e., it is necessary to select materials having a high fluidity, and it is difficult to use resins with fillers. However, these problems have been solved by the provision of the injection molding method according to the invention. Furthermore, in the molding method of the invention, the molding temperature and the injection pressure are considerably low, and the productivity (molding cycle) is high. In addition, in the invention, the slot is formed by the pushing action of the metal mold, and therefore it is preferable that the mold closing pressure is suitable for increasing the durability of the metal mold, preventing damage to the base material and preventing breakage of the slot. According to the invention, the mold closing pressure can be low. Depending on molding conditions, sometimes a product's corner material such as an aluminum foil may be broken in the mold during injection molding. However, such a problem can be eliminated by the low injection pressure employed with the invention. Accoring to the injection molding method of the invention, can-like container's covers having a high adhesion strength can be obtained as described above. Especially when a multi-layer sheet having thermally meltable first resin layers on its both sides is used, the first and second resin layers are in a molten state when molded, and are then welded together. Therefore, the resultant molding is high in adhesion strength and accordingly durable in the drop test. On the other hand, the cover may suffer from the problem that the handle is also welded to the multi-layer sheet so that it cannot be peeled off the multi-layer sheet. However, this problem can be solved by applying a treatment for allowing the handle to peel off the multi-layer sheet to the part of the multi-layer sheet with which the handle is in contact. An example of the treatment is to use printing ink to form a treatment layer as described above. Fig. 5 is an enlarged plan view of the round cover of Fig. 2, and Fig. 6 is an enlarged sectional view taken along line Y-Y′ in Fig. 5. In Figs. 5 and 6 , parts designated by the same reference numerals as those in Figs. 3 and 4 have the same functions, and their description will be omitted. The round cover is manufactured in the same manner as the rectangular cover in Figs. 3 and 4 , and can be readily opened. In Fig. 5 , 73(G3) designates the position of a gate for the opening part 58, and 74(G4) the position of a gate for the peripheral part 59. The opening part and the peripheral part are formed independently by using the respective gates G3 and G4. In order to clarify the effects of the above embodiments of the invention, Examples and Comparison Examples will now be described. Example 1 An injection molding machine IS-50A(30Z) made by Toshiba Co. was used to form the rectangular cover shown in Fig. 3. Used for the formation of the cover was a multi-layer sheet which was fabricated by forming ethylene propylene block copolymer (MFR 1.1, ethylene content 9 wt%) layers on both sides of a aluminum foil. The injection molding operation was carried out with the multi-layer sheet fixedly held in the metal mold by the robot. The two gates G1 and G2 shown in Fig.3 were used for molding. The slot was formed by the pushing action of the metal mold. The second resin layer, formed with the product "Shoaroma" manufactured by Showa Denko Co. (propylene ethylene block copolymer of NFR 10.0 g/10 min) was injected under cylinder temperature of 240°C and an injection pressure of 60 kg/cm². In the multi-layer sheet, the thicknesses of the outer first resin layer, the aluminum foil and the inner first resin layer were 30 microns, 15 microns and 70 microns, respectively. The second resin layer was formed on the outer resin layer to a thickness of 0.7 mm. The openability of the rectangular cover thus manufactured is indicated in Table 1, and the injection moldability is shown in Table 2 . Table 3 indicates the results of comparison in molding conditions between Example 16 and Comparison Example 8 (described later). Example 2 The rectangular cover was made by injection molding in the same manner as that in Example 2 with the exception that, instead of "Shoaroma" MK411C, a resin prepared by adding calcium carbide 40% to that resin was used, and the cylinder temperature and the injection pressure were set to 260°C and 80 kg/cm², respectively. Similar to Example 2 , the openability and the injection moldability of the rectangular cover were evaluated. The results of evaluation are as indicated in Tables 1 and 2. Comparison Example 1 The injection molding operation was carried out by using the gate G1 in Fig. 3 . For this purpose, four bridges were formed in the slot 60 at intervals (each bridge having a width of 0.5 mm). The molding resin was injected in the same manner as that in Example 1 The results of the injection molding operation are as indicated in Tables 1 and 2 . The bridges made it difficult to open the cover. Although the cylinder temperature and the injection presssure were set to 280°C and 110 kg/cm², respectively, the moldability was lower than that of Example 1 or 2 . The results of comparison in molding conditions between Comparison Example 1 and Example 1 are indicated in Table 3. Comparison Example 2 The injection molding operation was conducted in the same manner as that in Comparison Example 1, with exception that, instead of the gate G1, the gate G2 was used. The results of the injection molding operation are indicated in Tables 1 and 2 . As in Comparison Example 1, the openability was low and the moldability also low. Example 3 A round cover as shown in Fig. 2 was formed in the same manner as that in Example 1 , with the exception that the gates G3 and G4 (in Fig. 5 ) were used and the cylinder temperature and the injection pressure were set to 240°C and 55 kg/cm², respectively. The results are as indicated in Table 1 and 2. Comparison Example 3 The injection molding operation was performed in the same manner as that in Comparison Example 1 , with the exception that one gate (G3) was used, four bridges 0.6 mm in width were formed in the slot 60, and the injection pressure was set to 100 kg/cm². The results are as shown in Tables 1 and 2. As is clear from the above-described Examples 1 , 2 and 3 , the covers of the invention could be opened readily without forming burrs along the edges of the opening part, and were excellent in moldability. The molding temperature and the injection pressure could be considerably low. Accordingly, the productivity (molding cyle) was high. In addition, even a material mixed with a filler low in moldability could be used. Thus, Examples 1 through 3 were clearly different from Comparison Examples 1 through 3. In the invention, the slot is formed by the pushing action of the metal mold, and therefore it is desirable that the mold closing pressure be low (the low mold closing pressure increasing the durability of the metal mold and preventing the breakage of the slot formed on the multi-layer sheet). The mold closing pressure was much lower than that in the Comparison Examples. Depending on the molding conditions, the aluminum foil may be broken at the corner in the metal mold during the injection. However, this problem can be eliminated by the low injection pressure as mentioned above. As is apparent from the above description, a can-like container's cover can be manufactured at relatively low cost by the method of the invention, and has the following excellent effects: (1) As the opening part (with the handle) and the peripheral part which are separated by the slot from each other are formed by using the respective gates, the injection molding operation can be achieved readily, and the multi-layer sheet inserted in the metal mold can be protected from being creased or damaged. (2) Because of the excellent moldability, the container's cover can be molded even with a material low in moldability. (3) The opening part (with the handle) and the peripheral part are isolated from each other by the closed-ring-shaped slot. Therefore, only the multi-layer sheet is cut in opening the cover. Thus, the container's cover of the invention is excellent in openability. (4) As the treatment layer for facilitating the peeling of the handle is provided, the handle can be readily peeled off the multi-layer sheet, and therefore the container's cover can be opened more readily. (5) The container's cover according to the invention is excellent in retort characteristics and with respect to food hygiene considerations. Therefore, the employment of the container's cover according to the invention allows the provision of a container which can preserve food for a long period of time. As is apparent from the above description, the cover according to the invention has excellent effects, and therefore it has a wide range of applications. Typically, the cover can be used for manufacturing the following containers: (1) Coffee cans, and soup cans (2) Edible (cooking) oil cans, and seasoning cans (3) Packing cans (4) Motor oil cans In the embodiments of the invention described above, in view of the openability of the can-like container's cover, the durability of the can-like container, the can breaking strength, and the fracture strength in the insert molding operation, it is desirable that the first resin layer of the multi-layer sheet be 100 microns or less in thickness, and the gas barrier type base material such as an aluminum foil be 50 microns or less, preferably 9 to 30 microns. If the thickness of the multi-layer sheet, especially the thickness of the metal foil (aluminum) is suitably selected in the invention, the can-like container can be completely incinerated. Recently much can pollution has occurred. However, with the can-like container of the invention, can pollution can be significantly reduced because the container of the invention can be completely incinerated if the thickness of the aluminum foil and the resin material of the multi-layer sheet are suitably selected. The heat energy required for incinerating the container is as low as 5000 to 6000 Kcal/kg. In other embodiments of the invention, in the second resin layer formed on the multi-layer sheet, the opening part and the peripheral part are completely separated by the slot. In this connection, it may be considered that when the container with the cover according to the invention is opened, the opening part may be carelessly disposed of. In order to prevent such, i.e., in order, to prevent the complete removal of the opening part from the cover, the opening part may be coupled to the peripheral part through coupling parts, namely, bridges, to the extent that the openability is not lowered. For instance, as shown in the embodiment of Fig. 24, the right-hand portion of the opening part 62 may be coupled to the peripheral part through the bridges. In the above-described molding method using a plurality of gates, the molding temperature and the injection pressure are considerably low, and the productivity (molding cycle) is high. In addition, in accordance with the above embodiments of the invention, the slot is formed by the pushing action of the metal mold, and therefore it is preferable that the mold closing pressure be low. That is, a low molding closing pressure is suitable for increasing the durability of the metal mold, preventing damage to the base material and preventing breakage of the slot. In Fig. 8 which is an enlarged sectional view taken along line X-X′ in Fig. 7, reference numeral 72 designates a treatment layer which is formed to allow the handle 11 to peel off the multi-layer sheet 64. In opening the container's cover, the treatment layer facilitates the peeling of the handle 11 from the multi-layer sheet 64. That is, the treatment layer in association with the slot 60 completely separating the opening part 58 from the peripheral part 59 functions to allow the cover to open more readily. Any treatment of the types described above may be employed. Fig. 9 is an enlarged plan view of a round cover of the present embodiment, and Fig 10 is an enlarged sectional view taken along line Y-Y′ in Fig. 9. In Figs. 9 and 10, parts designated by the same reference numerals as those in Figs. 7 and 8 have the same functions, and their description will be omitted. The round cover is manufactured in the same manner as the rectangular cover in Figs. 7 and 8 , and it is high both in adhesion strength and in impact resistance, and can be readily opened. In Fig. 9 , 93(G3) designates the position of a gate for the opening part 58, and 94(G4) the position of a gate for the peripheral part 59. The opening part and the peripheral part are formed independently by using the respective gates G3 and G4. In order to clarify the effects of the invention, further Examples and Comparison Examples will be described. Example 4 An injection molding machine IS-50A(30Z) manufactured by Toshiba Co. was used to form the rectangular cover shown in Fig. 3. A multi-layer sheet which ws fabricated by forming ethylene propylene block copolymer (I) (MFR 1.1, ethylene content 9 wt%) layers on both sides of an aluminum foil was used. Rubber group gravure printing ink was applied to the part of the multi-layer sheet which was to be covered by the handle. A robot was used to fixedly hold the thus-treated multi-layer sheet in the stripper plate of the metal mold. Under this condition, the injection molding operation was carried out. The two gates G1 and G2 shown in Fig. 7 were used for molding. The slot was formed by the pushing action of the metal mold. The second resin layer was formed by injecting propylene ethylene block copolymer (II) of MFR 10.0 g/10 min with a cylinder temperature of 240°C and an injection pressure of 60 kg/cm². In the multi-layer sheet, the thicknesses of the outer first resin layer, the aluminum foil and the inner first resin layer were 30 microns, 15 microns and 70 microns, respectively. The second resin layer was formed on the outer first resin layer to a thickness of 0.7 mm. The openability of the rectangular cover thus manufactured is indicated in Table 4, the peelability of the handle is indicated in Table 5, and the injection moldability is indicated in Table 6 . Table 7 indicates the results of comparison in molding conditions between Example 19 and comparison Example 11 (described below). Example 5 A rectangular cover was formed by injection molding in the same manner as that in Example 4 with the exception that, instead of the block copolymer (II), a resin prepared by adding calcium carbide 40% to the resin was used, and the cylinder temperature and the injection pressure were set to 260°C and 80 kg/cm², respectively. As in Example 4 , the openability of the cover, the peelability of the handle, and the injection moldability were evaluated. The results are indicated in Table 4, 5 and 6. Examples 6 through 16 The injection molding operations were carried out in the same manner as that in Example 4 with the exception that different multi-layer sheets and different printing inks (or treatment layers) were employed as indicated in Table 5 . the covers were evaluated for the peelability of the handle as indicated in Table 5. The evaluations of the cover formed by compression forming are also included in Table 5 . In the compression forming, a 50-ton press manufactured by Amino Press Co. was used. The multi-layer sheet indicated in Table 6 was inserted in the mold. Under this condition, the compression forming was carried out by supplying a molten second resin (propylene ethylene block copolymer of MFR 2.0 g/10 min). Comparison Example 4 The injection molding operation was carried out by using the gate G1 in Fig. 7 . For this purpose, four bridges were formed in the slot 60 at intervals (each bridge having a width of 0.5 mm). The molding resin was injected in the same manner as that in Example 4 . The results of the injection molding operation are as indicated in Tables 4 and 6. The bridges made it difficult to open the cover. Although the cylinder temperature and the injection pressure were set to 280°C and 110 kg/cm², respectively, the moldability was lower than that of Example 4 or 5. The results of comparison in molding conditions between Comparison Example 4 and Example 4 are indicated in Table 7. Comparison Example 5 An injection molding operation was conducted in the same manner as in Comparison Example 4, with the exception that, instead of the gate G1, the gate G2 was used. The results of the injection molding operation are indicated in Tables 4 and 6. Similar to Comparison Example 4 , both the openability and the moldability were low. Example 17 A round cover as shown in Fig. 9 was formed in the same manner as that in Example 4 with the exception that the gates G3 and G4 (Fig. 26) were used and the cylinder temperature and the injection pressure were set to 240°C and 55 kg/cm², respectively. The results are as indicated in Tables 4 , 5 and 6 . Comparison Example 6 An injection molding operation was performed in the same manner as that in Comparison Example 4, with the exception that one gate (G3) was used, four bridges 0.6 mm in width were formed in the slot 10, and the injection pressure was 100 kg/cm². The results are as shown in Tables 4 and 6. Comparison Examples 7 through 13 Different multi-layer sheets indicated in Table 5 were used, and the injection molding operations or the compression forming operations were carried out in the same manner as those in Examples 4 and 6 through 16 , except that no treatment for peeling the handle off the multi-layer sheet was applied. The container's covers thus manufactured were evaluated for the peelability of the handles as indicated in Table 5. Examples 18 and 19 , and Comparison Examples 14 through 17 A rectangular cover was formed in the same manner as that in Example 4 , except that a multi-layer sheet consisting of an outer resin layer 70 microns in thickness, an aluminum foil 15 microns in thickness and an inner resin layer 70 microns in thickness was used. The rectangular cover thus formed was welded to a container body consisting of a bottom and a side wall to form a sealed can-like container as shown in Fig. 1. A drop test was applied to the can-like container thus formed (Example 18 ). A round cover was formed in the same manner as that in Example 17, with the exception that a multi-layer sheet consisting of an outer resin layer 70 microns in thickness, an aluminum foil 15 microns in thickness, and an inner resin layer 70 microns in thickness was used. As in Example 18 , the round cover was used to form a sealed can-like container, and a drop test was applied to the container (Example 19). For comparison, the same multi-layer sheets and the same second resin layers were formed and were then bonded together by using an urethane adhesive to form a rectangular cover and a round cover, respectively. As in Examples 18 and 19 , sealed can-like containers were formed with these covers, and drop tests were carried out on the can-like containers (Comparison Examples 14 and 15 ). A sealed can-like container was formed using the rectangular cover with bridges formed using one gate as in Comparison Example 4 . Another sealed can-like container was formed by using the round cover which was fabricated in Comparison Example 6 . Drop tests were applied to these sealed can-like containers (Comparison Examples 16 and 17). The multi-layer sheets used were the same as those in Examples 18 and 19. The content of each rectangular can was about 350 cc in volume, and the content of each round can was about 250 cc. The results of these drop tests are as indicated in Tables 8 and 9 . As is apparent from Table 8, the sealed can-like containers according to the invention are high in impact resistance. It is considered that this effect is due to the facts that the resin layers are sufficiently welded to the aluminum foil by thermal molding, and that, as the molding closing pressure can be low, the aluminum foil is protected from damage when the slot is formed by the pushing action of the metal mold. As was described before, in Comparison Example 14 , the can-like container was formed by using a rectangular cover which was formed by using one gate in such a manner that the slot had four bridges, and in Comparison Example 15 , the can-like container was formed by using a round cover which was also formed by using one gate in such a manner that the slot had four bridges. In each of the above-described Examples 16 and 17, the injection pressure was high and the mold closing pressure was also high (see Table 6). Therefore, the aluminum foil was damaged, being strongly pressed by the metal mold, with the result that the can-like container was low in impact strength. Examples 20 through 26 Sealed can-like containers with rectangualr covers were fabricated in the same manner as that in Example 18 except that multi-layer sheets different in outer resin layer, aluminum foil and inner resin layer thicknesses as indicated in Table 11 were used. The containers thus fabricated were tested for can breaking strength and openability. The test results are as listed in Table 10: Examples 26 through 30 Rectangular covers were formed in the same manner as that in Example 18 except that multi-layer sheets different in aluminum foil thickness as indicated in Table 11 were used. The relationships between the thickness of the aluminum foil and the completeness of incineration, aluminum foil breakage, and openability were obtained as indicated in Table 11: The aluminum foil thickness is an important factor affecting the ability to completely incinerate the can, its openability and the aluminum foil breakage. However, if the aluminum foil is at least 9 microns in thickness, then it can sufficiently block the permeation of oxygen, water, etc. The thickness of the first resin layer somewhat affects the openability of the container's cover. However, if the aluminum foil thickness is 50 microns or less, then the container's cover can be easily opened. Aluminum blocks more than 60 microns in diameter cannot easily be completely incinerated. It has been confirmed that if the aluminum foil thickness is further decreased, then the aluminum foil is liable to be broken at its edge portions during insertion molding, but such trouble will not occur if its thickness is 9 microns or more. As is apparent from the above description, according to the invention, can-like containers are manufactured at a relatively low cost, and the can-like containers thus manufactured have the following excellent effects: (1) The opening part (with the handle) and the peripheral part are isolated from each other by the closed-ring-shaped slot. Therefore, only the multi-layer sheet is cut in opening the cover. Thus, the container's cover of the invention is excellent in openability. (2) As the treatment layer for facilitating the peeling of the handle is provided, the handle can be readily peeled off the multi-layer sheet, and therefore the container's cover can be opened more readily. (3) In the case where the second resin layer is formed by using one gate in such a manner that it has the bridges over the slot, the injection pressure is unavoidably high, as a result of which the aluminum foil of the multi-layer sheet is damaged, and the can-like container is low in impact resistance. However, in the above embodiments of the invention, both the opening part (including the handle) and the peripheral part separated by the slot are molded using at least one gate. Therefore, the injection molding operation can be achieved readily, and the multi-layer sheet inserted in the metal mold can be protected from being creased or damaged. Accordingly, the can-like container having the container's cover according to the invention shows a high impact resistance in the drop test. (4) Because of the excellent moldability, the container's cover can be molded even with a material having a low moldability. (5) The container's cover according to the invention is excellent in retort characteristics and food hygiene. Therefore, the employment of the container's cover according to the invention allows the provision of a container which can preserve food for a long period of time.

Claims: An injection molding method for manufacturing a readily openable can-like container's cover (3; 6), wherein said cover is made by forming first and second resin layers of a multi-layer sheet (64), a second outer resin layer including an opening part (58) having (58) a handle (11) and a peripheral part (59) formed by injection molding, characterized in that the opening part (58) and the peripheral part (59) of said second layer are completely seperated by a slot (60) and formed by injection molding on one side of said multi-layer sheet (64) which is fabricated by forming thermally meltable first resin layers on both sides of a base material which oxygen, water, and the like cannot permeate, in such a manner that at least one gate 70, 73, 90, 93; 71, 74, 91, 94 is used for the formation of said opening part and said peripheral part of said second layer respectively. The method according to claim 1, characterized in that a treatment for allowing said handle (11) of the opening part (58) to readily peel off said multi-layer sheet is applied to all or part of the portion of said multi-layer sheet with which said handle makes contact. The method according to claim 1, characterized in that said base material is an aluminium foil.

Inventors: MIYAUCHI, OTOHIKO, SUZUKI, TAKASHI, YASUDA, TETSUO, YOTSUYANAGI, JUNJI
Applicants: SHOWA DENKO KABUSHIKI KAISHA
Application year: 1984
Main classification: B29C45
IPC codes: B29C45