IMPACT-RESISTANT ETHYLENE-PROPYLENE BLOCK COPOLYMER AND PROCESS FOR PREPARING SUCH A BLOCK COPOLYMER

Abstract: Present invention pertains to a novel impact-resistant ethylene-propylene block copolymer, that at least consists of an at least almost completely homopolymeric propylene part and a copolymeric ethylene-propylene part, the weight ratio between the at least almost completely homopolymeric propylene part and the copolymeric ethylene-propylene part being between 4 : 1 and 9 : 1, that contains a total amount of 10-15 % (wt) ethylene groups, that has an Izod value measured according to ISO-R-180 at 296 K of at least 30 kJ/m², that has an E-modulus measured according to ASTM-D-790 at 296 K of at least 1000 N/mm² and that has a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 2.5-20 dg/min and to a process for preparing such an impact-resistant ethylene-propylene block copolymer.

Description: The invention relates to an impact-resistant ethylene-propylene block copolymer (C), comprising a homopolymeric propylene part, consisting of at least 98% (wt) of propylene groups and a copolymeric ethylene-propylene part, the weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part being from 4 : 1 to 9 : 1, which contains a total amount of 10 - 15 % (wt) ethylene groups, characterized in that its Izod value measured according to ISO-R-180 at 296 K is at least 30 kJ/m², preferably at least 40 kJ/m² and in particular at least 50 kJ/m², for instance 50-100 kJ/m², in that its E-modulus measured according to ASTM-D-790 at 296 K is at least 1000 N/mm², preferably at least 1100 N/mm² and in particular at least 1200 N/mm², for instance 1250-1500 N/mm², and in that its melt index measured according to ASTM-D-1238 at 503 K and 21.6 N is 2.5-20 dg/min, preferably 2.5-10 dg/min, particularly 2.5-8 dg/min. The ethylene content is measured by means of IR analysis of the polymer in melted condition. The Izod value is measured on an injection-moulded test sheet and the E-modulus on a compression-moulded test sheet with a thickness of 1.6 mm. An at least almost completely homopolymeric propylene part is understood to mean in this connection a part of the block copolymer consisting of at least 98 % (wt) of propylene groups. A copolymeric ethylene-propylene part is understood in this connection to mean a part of the block copolymer consisting of at least 90 % (wt) of substantially randomly distributed ethylene groups and propylene groups. This very special combination of a high impact resistance, as well as a high rigidity, along with good flow properties has so far been unknown for ethylene-propylene block copolymers. Block copolymers, similar to those of the invention are known from EP-A-94818 and EP-A-77532, but these prior art copolymers do not meet the impact properties in combination with the stiffness of the block copolymers of the present invention. The impact-resistant ethylene-propylene block copolymer according to the invention preferably contains 10⁶ parts by weight block copolymer at least 50 parts by weight of one or more zinc and/or cadmium compounds, calculated as zinc and/or cadmium atoms. Preference is given to the presence of zinc compounds. Very suitable zinc compounds in this connection are zinc stearate and zinc hexanoate. The invention also comprises a process for preparing an impact-resistant ethylene-propylene block copolymer (C) characterized in that in a first polymerization step a propylene prepolymer (A) is prepared consisting of at least 98 % (wt) of propylene groups, having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.5-10 dg/min, preferably 0.5-6 dg/min, in that in the presence of the propylene prepolymer (A) produced in the first polymerization step, ethylene and propylene are polymerized in a second polymerization step in such a manner that an ethylene-propylene block copolymer (B) is formed comprising a homopolymeric propylene part consisting of at least 98 % (wt) of propylene groups, and a copolymeric ethylene-propylene part, the weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part being from 4 : 1 to 9 : 1, which block copolymer (B) contains a total amount of 10-15 % (wt) ethylene groups and which has a melt index measured according to ASTM-D-1238 at 503 K and 21,6 N that is lower than the melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of the propylene prepolymer and which melt index is from 0.01 to 0.8 dg/min, preferably from 0.05 to 0.5 dg/min, and in that this ethylene-propylene block copolymer (B) is subsequently subjected to a kneading treatment consisting of one or more kneading operations, which kneading takes place in the presence of free radicals at a temperature of at least 450 K, preferably at 470-570 K. A similar treatment is known from (CA Vol 79 (1973) p. 55 no. 54505 t). However, this known treatment result in a deterioration of impact properties whereas in the special combination of polymerisation steps and treatment according to the present invention impact and stiffness properties are improved. The kneading treatment can be effected in various ways. It implies the exertion of mechanical forces on the starting ethylene-propylene block copolymer e.g. by means of a kneading and/or transport screw of e.g. extruding or injection-moulding equipment or by means of a rolling device. Preference is given to single-screw or multi-screw kneading, which kneading operation can be repeated more than once, and in which one or more of the kneading operations can be followed by extrusion. The duration of the kneading treatment is at least 1/4 minute, particularly at least 1 minute. If the kneading treatment consists of more than one kneading operation, there may be a longer period of time between two kneading operations. Thus in a first kneading operation a pre-product (for instance a granulate) can be prepared, subsequently be transported to another place and finally be processed in a second kneading operation according to the invention to form an end product according to the invention. The presence of free radicals in the process according to the invention can be realized in any suitable manner. A suitable manner consists in the addition, before and/or during the said kneading treatment, of a total amount of 10-20000 parts by weight of one or more peroxides per 10⁶ parts by weight starting ethylene-propylene block copolymer to the substance or substances subjected or to be subjected to the kneading treatment. Preference is given to using peroxides having at the average temperature of a kneading operation, a half-life value less than 1/5 of the duration of the relative kneading treatment. Suitable peroxides are di-(t-butylperoxyisopropyl)-benzene, 1,1-di-t-butylperoxy-3,3,5-trimethylcyclohexane, 1,1-di-t-butylperoxycyclohexane, t-butylperoxyisopropylcarbonate, t-butylperoxybenzoate, di-cumylperoxide, di-t-butylperoxide, 2,2-di-t-butylperoxybutane, di-benzoylperoxide, 2,5-di-methylhexane-2,5-di-t-butylperoxide and 2,5-di-methylhexyn-2,5-di-t-butylperoxide. Another suitable manner for realizing the presence of free radicals is the high-energy irradiation, for instance electron radiation or gamma radiation, of the starting ethylene-propylene block copolymer subjected or to be subjected to the kneading treatment, preferably in the almost complete absence of stabilizers, at a dose of 0.1-4 Mrad. All kinds of combinations of the use of peroxides and of the said irradiation are suitable as well. The kneading treatment according to the invention is preferably effected in whole or in part in the presence of at least 50 parts by weight of one or more zinc and/or cadmium compounds, calculated as zinc and/or cadmium atoms, per 10⁶ parts by weight starting ethylene-propylene block copolymer. Other additives, too, may be present or be added during this kneading treatment, for instance heat stabilizers, UV-stabilizers and nucleation agents. Very suitable fillers for ethylene-propylene block copolymers according to the invention are chalk, with by preference an average particle size of below 2 µm, and talcum, with by preference an average particle size of below 5 µm. Suitable are quantities of filler of below 25 % (wt). A higer weight percentage of filler quickly leads to very bad mechanical properties of the copolymer-filler mixture compared with the pure copolymer. The impact resistant ethylene-propylene block copolymers according to the invention are very suitable for use in car bumpers, so-called front ends, spoilers, so-called liners, motor car underside coats and wheel arch lining for motor cars. The invention is further elucidated by means of the following examples and the comparative experiment. Example I A homopolymeric propylene prepolymer having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 3,0 dg/min is produced. Subsequently ethylene and propylene are polymerized in the presence of this propylene prepolymer to form a powdery starting ethylene-propylene block copolymer with a weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part of 22 : 5, with a total content of ethylene groups of 11 % (wt) and with a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.45 dg/min. This starting ethylene-propylene block copolymer is then provided with 0,05 % (wt) zinc stearate, 0,05 % (wt) calcium stearate, 0.1 % (wt) Irganox B 225 (a trade name and trade product of Ciba-Geigy) and 0,012 % (wt) di-(t-butylperoxyisopropyl)-benzene calculated in respect of the final mixture. The starting ethylene-propylene block copolymer (B) provided with these additives is subsequently kneaded in a single-screw kneader at 513 K for 1,5 minutes and then extruded to form granulate. This granulate has an Izod value measured according to ISO-R-180 at 296 K of 57.1 kJ/m² , an E-modulus measured according to ASTM-D-790 at 296 K of 1340 N/mm², and a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 3.1 dg/min. Example II A homopolymeric propylene prepolymer having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.63 dg/min is produced. Subsequently ethylene and propylene are polymerized in the presence of this propylene prepolymer to form a powdery starting ethylene-propylene block copolymer with a weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part of 22 : 4, with a total content of ethylene groups of 11 % (wt) and with a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.26 dg/min. This starting ethylene-propylene block copolymer is then provided with 0.05 % (wt) zinc stearate, 0.05 % (wt) calcium stearate, 0.1 % (wt) Irganox B 225 (a trade mark and trade product of Ciba-Geigy) and 0.032 % (wt) di-(t-butylperoxyisopropyl)-benzene calculated in respect of the final mixture. The starting ethylene-propylene block copolymer provided with these additives is subsequently kneaded in a single-screw kneader at 513 K for 1.5 minutes and then extruded to form granulate. This granulate has: an Izod value measured according to ISO-R-180 at 295 K of 62.0 kJ/m², an E-modulus measured according to ASTM-D-790 at 296 K of 1160 N/mm², and a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 3.3 dg/min. Comparative experiment A homopolymeric propylene prepolymer with a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 13.6 dg/min is produced. Subsequently ethylene and propylene are polymerized in the presence of this propylene prepolymer to form a powdery starting ethylene-propylene block copolymer with a weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part of 49 : 10, with a total content of ethylene groups of 11 % (wt) and with a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 2.9 dg/min. This starting ethylene-propylene block copolymer is subsequently provided with 0.05 % (wt) zinc stearate, 0.05 % (wt) calcium stearate, 0.1 % (wt) Irganox B 225 (a trade name and trade product of Ciba-Geigy) calculated in respect of the final mixture. The starting ethylene-propylene block copolymer provided with these additives (now without peroxide) is subsequently kneaded in a single-screw kneader at 513 K for 1.5 minutes and then extruded to form granulate. This granulate has: an Izod value measured according to ISO-R-180 at 296 K of only 12.5 kJ/m², an E-modulus measured according to ASTM-D-790 at 296 K of 1420 N/mm², and a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 3.0 dg/min.

Claims: Impact-resistant ethylene-propylene block copolymer (C), comprising a homopolymeric propylene part, consisting of at least 98% (wt) of propylene groups, and a copolymeric ethylene-propylene part, the weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part being from 4 : 1 to 9 : 1, which contains a total amount of 10-15 % (wt) ethylene groups, characterized in that its Izod value measured according to ISO-R-180 at 296 K is at least 30 kJ/m², in that its E-modulus measured according to ASTM-D-790 at 296 K is at least 1000 N/mm² and in that its melt index measured according to ASTM-D-1238 at 503 K and 21.6 N is 2.5-20 dg/min. Impact-resistant ethylene-propylene block copolymer according to claim 1, characterized in that the said melt index is 2.5-8 dg/min. Process for preparing an impact-resistant ethylene-propylene block copolymer (C), characterized in that in a first polymerization step a propylene prepolymer (A) is prepared consisting of at least 98 % (wt) of propylene groups, having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.5-10 dg/min, in that in the presence of the propylene prepolymer (A), produced in the first polymerization step ethylene and propylene are polymerized in a second polymerization step in such a manner that an ethylene-propylene block copolymer (B) is formed comprising a homopolymeric propylene part, consisting of at least 98% (wt) of propylene groups, and a copolymeric ethylene-propylene part, the weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part being from 4:1 to 9:1, which block copolymer (B) contains a total amount of 10-15 % (wt) ethylene groups and which has a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N that is lower than the melt index measured according to ASTM-D-1238 at 503K and 21.6 N of the propylene prepolymer (A) and which melt index is from 0.01 to 0.8 dg/min, and in that this ethylene-propylene block copolymer (B) is subsequently subjected to a kneading treatment consisting of one or more kneading operations, which kneading treatment takes place in the presence of free radicals at a temperature of at least 450 K. Process according to claim 3, characterized in that in the first polymerization step a propylene prepolymer (A) is produced having a melt index of 0.5-6 dg/min measured according to ASTM-D-1238 at 503 K and 21.6 N. Process according to claim 3 or 4, characterized in that in the second polymerization step a ethylene-propylene block copolymer (B) is produced having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.05-0.5 dg/min. Process according to claim 3-5, characterized in that before and/or during the said kneading treatment 10-20000 parts by weight of one or more peroxides per 10⁶ parts by weight ethylene-propylene block copolymer (B), is added to the substance or substances subjected or to be subjected to the kneading treatment. Process according to any one of claims 3-6, characterized in that the ethylene-propylene block copolymer (B), subjected or to be subjected to the kneading treatment, is subjected to high-energy irradiation, with a preferred irradiation dose of 0.1-4 Mrad. Article wholly or partly made from an impact-resistant ethylene-propylene block copolymer (C) according to any one of claim 1 or 2. CLAIMS FOR THE CONTRACTING STATE AT: Process for preparing an impact-resistant ethylene-propylene block copolymer (C), characterized in that in a first polymerization step a propylene prepolymer (A) is prepared consisting of at least 98 % (wt) of propylene groups, having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.5-10 dg/min, in that in the presence of the propylene prepolymer (A) produced in the first polymerization step ethylene and propylene are polymerized in a second polymerization step in such a manner that an ethylene-propylene block copolymer (B) is formed comprising a homopolymeric propylene part, consisting for at least 98% (wt) of propylene groups, and a copolymeric ethylene-propylene part, the weight ratio between the homopolymeric propylene part and the copolymeric ethylene-propylene part being from 4:1 to 9:1, which block copolymer (B) contains a total amount of 10-15 % (wt) ethylene groups and which has a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N that is lower than the melt index measured according to ASTM-D-1238 at 503K and 21.6 N of the propylene prepolymer (A) and which melt index is from 0.01 to 0.8 dg/min, and in that this ethylene-propylene block copolymer (B) is subsequently subjected to a kneading treatment consisting of one or more kneading operations, which kneading treatment takes place in the presence of free radicals at a temperature of at least 450 K. Process according to claim 1, characterized in that in the first polymerization step a propylene prepolymer (A) is produced having a melt index of 0.5-6 dg/min measured according to ASTM-D-1238 at 503 K and 21.6 N. Process according to claim 1 or 2, characterized in that in the second polymerization step an ethylene-propylene block copolymer (B) is produced having a melt index measured according to ASTM-D-1238 at 503 K and 21.6 N of 0.05-0.5 dg/min. Process according to claim 1-3, characterized in that before and/or during the said kneading treatment 10-20000 parts by weight of one or more peroxides per 10⁶ parts by weight ethylene-propylene block copolymer (B) is added to the substance or substances subjected or to be subjected to the kneading treatment. Process according to any one of claims 1-4, characterized in that the ethylene-propylene block copolymer (B) subjected or to be subjected to the kneading treatment is subjected to high-energy irradiation, with a preferred irradiation dose of 0.1-4 Mrad. Impact-resistant ethylene-propylene block copolymer (C) prepared according to a process according to any one of claims 1-5. Article wholly or partly made from an impact-resistant ethylene-propylene block copolymer (C) according to claim 6.

Inventors: KISTERS, MATHIJS JOSEPH M.G., REPIN, JOHANNES FREDERICUS
Applicants: STAMICARBON B.V.
Application year: 1984
Main classification: C08F297
IPC codes: C08L53, C08L51, C08K5, C08J3, C08L23, C08F297, C08L77, C08L101