SEED DRESSING ADDITIVE

Abstract: A dressing additive which comprises 10-80% by weight of an oil of vegetable, animal or mineral origin; 2-7% by weight of an emulsifier; 0-12% by weight of a dyestuff and up to 100% by weight of water.

Description: SEED DRESSING ADDITIVE Technical field This invention relates to dressing additives, more particularly to seed dressing additives. The invention is directed to a seed dressing additive which comprises an oil in order to adhere the active ingredient(s) responsible for the desired effect(s) onto the parts of the plant (seeds, tubers etc.) and to form a protecting coating. Background art The safety of plant cultivation is endangered by several diseases and pests (e.g. fungal diseases, insects, mammals etc.). The chewing of seeds and seedlings and the diseases of the growing plant constitute serious damages. The germinating seeds, the tubers and some lea ed plants are the most unprotected and any damages might become fatal. Some further diseases caused by the infection of the seed might appear on the crops (e.g. rust and mildew diseases of cereals) . In order to clear away the above serious damages and to ensure the foodstuff-demands of the population seed dressing (also called as dressing) " has been used for a long time. The essential feature of the said process is that the propagative organs of the plant are contacted with chemical substances (referred to furtheron as plant protecting agents or pesticides) which destroy the pests dwelling on the seed or in the vicinity thereof in the soil. The said plant protecting agents provide healthy seeds on one hand while on the other they kill the soil dwelling sucking - chewing pests. Other known plant protecting agents are adsorbed by the plant and provide protection to the plant for a shorter or long ' er period of_time. It is an essential feature of the seed dressing procedure that the propagative material and the plant protecting agent should get into contact for a prolonged period of time and the said contact should be maintained when the propagative material gets into the soil. Nowadays in seed dressing technology additives which promote the adhesion of the fungicide and enhance seed dressing are widespreadly used. The users particularly demand additives which posses high adhesive strength, colour intensively, dry rapidly and contain no active ingredient because only such additives are suitable for seed dressing wherein the economy in the use of materials is taken into consideration and the rate of application is adapted to the degree of infection. The known seed dressing methods are as follows: l) Wet seed dressing. The pesticide is suspended or - if possible - dissolved in water. The seeds are soaked in this mixture, thereafter filtered and dried. Thus a good connection is formed between the pesticide and the seeds but the amount of the active ingredient adhered is often lower than that required for the safe protection of the seeds. Further drawbacks are the complicated character of the process, the high labour demand and the costs of drying. For these reasons the said process is not used in practice any more. 2) Powder dressing. The object of this method is the elimination of the drawbacks of wet technology. The essence of the process is that the active ingredient is ground to a fine powder and a powdered additive is added which promotes adhesion. The process meets however serious difficulties. The powder is namely adhered only to the external surface of the propagating material and generally avoids the germ homozygotes. Therefore in the absence of moisture the substances capable of absorption can penetrate the seeds only after sowing under the effect of the humidity of soil. The adhesion to the dry seeds is weak and there ore the required amount of active ingredient can be applied only with difficulties. Moreover a great part of the pesticide dusts off during treatment, storage and transport of the seeds, consequently it can not exert the desired effect and constitutes health hazards to the handling staff as well. 3) Moistened seed dressing. From the active ingredient a suspension is prepared with such an amount of water which can be still absorbed by the seeds without increasing the moisture content during storage • over the still allowable limit. The object of this method is to maintain the advantages of the wet and dry technologies with the possible strongest suppression of the drawbacks thereof. This object can be reached however only by a certain compromise. It is a particularly serious problem that after drying a significant amount of the plant protecting agent dusts off. Water soluble adhesives are used, to promote adhesion. These agents are dissolved in water and form colloides but increase the viscosity of the solution to such a large extent that a very thick, dense suspension is formed even if the said adhesive is used in high dilution. If, on the other hand, a small amount of adhesive is used the desired biological effect cannot be achieved because a significant part of the active ingredient and the pesticide dusts off during storage or sowing. According to prior art the following attempts have been made to overcome the above drawbacks and difficulties: l) Combined pesticides are put on the market which comprise the active ingredients of the seed dressing agent in a pre-determined ratio admixed in a plastic dispersion (e.g. Evershield, Buvishield products) . The active ingredient in adhered to the seeds by means of a film forming plastic material. The disadvantage of this process is that the composition of the active ingredients is not adapted to the particular infection to be overcome. Thus on one hand it is necessary to put on the market compositions adapted at least to the most important cultures whilde on the otherhand it causes wasteful consumption because a more effective and expansive agent must be used for the treatment of lower infections too. A further drawback is that the germinating strength is reduced and the seeds stick together. 2) Seed dressing agents have been elaborated which contain no active ingredient. These are solutions of natural (e.g. pine-resin, shellac) or synthetic resins formed with organic solvents (e.g. alcohol). The solutions are admixed with the suspension of the dressing agent and the mixture is applied onto the seeds. On seed dressing from the thus treated seeds the solvent and the excess of water must be removed by drying. The step of drying is to be carried out under constant moving of the seeds in order to avoid the sticking together thereof. This step is carried out by using special equipment. Such seed dressing methods are disclosed in European patent specification No. 0.010.630 (shellac is used as binding agent) , European patent specification No. 0.013.763 (vermiculite and orillanalate are used as coating agent) and Japanese patent application Kokai No. 2.631.032 (a maltotriase polymer is used as coating agent) . Disclosure of the invention The object of the invention is to provide seed dressing agents which eliminate the disadvantages of the known methods. The present invention is based on the recognition that uniform film coatings with good adhesive strength can be formed on the surface of a wide range of seeds with active ingredients and seed dressing agents the character and amount thereof being variable between broad limits by using a previously prepared emulsion of an oil of vegetable, animal or mineral origin as dressing auxiliary agent. The thus treated seeds and coatings do not undergo any changes during storage, packing, transport and sowing and there are dusting losses. The germination strength of the seeds is high and the protection corresponds to the value predicted on the basis of the degree of infection and the character and amount of the pesticide used. The seeds treated with the composition of the present invention do not require special treatment (e.g. drying) since the substances used merely adhere the active ingredient- to the seed but do not stick the seeds together. The seed dressing does not require a larger amount of moisture than the so- -called moistened method referred to above. After the termination of the operation the seed dressed product can be immediately packed and stored. The present invention enables the use of the optimal and most preferable formulation type and is consequently highly economical. Due to its character the auxiliary agent is compatible with the fungicide, insecticide, game alarming and other agents and a further additives. The present invention is based in the recognition that the adhesion of seed dressing agents can be carried O PI out not only with the hitherto known adhesives and auxiliary agents but in the case of seeds having substantially lipophilic (waxy) surface also with oils which coat all parts of the plant. If the oil is applied in the form of fine drops dispersed in water - if necessary in the presence of a dyestuff dissolved in the aqueous phase - the active ingredient applied onto the seeds can completely exert the plant protecting activity without any losses. The additives of the present invention can be prepared by any known emulsifying method. The composition of the additive is as follows: Oil(s) 10-80 / °o by weight Emulsifier(s) 2-7 by weight Water ad 100 % by weight Dyestuff 0-12 / ° by weight According to the present invention there is also provided a process for the preparation of the said additives. One may preferably proceed as follows: The dyestuff component of the aqueous phase is dissolved in water or an aqueous mixture at 35--0 C under slow stirring. The oily layer comprising the dissolved emulsifier is separately prepared. The oily phase is added to the aqueous layer continuously within approximetely 1-10 minutes preferably by using an emulsifying stirrer having a high shear force (peripheral speed : 5-25 m/sec referred to furtheron as intensive stirring) . After the addition of the total amount of the oily phase the emulsion formed is stirred for a further period of 3-5 minutes. As dyestuff various water-soluble dyestuffs or dispersions thereof can be used (preferably foodstuff- -dyes or rodamine colorants) . As emulsifier generally non-ionic alkyl aryl polyglycol ethers and known oil emulsifiers can be used. The oils may be of vegetable, animal or mineral origin, e.g. paraffine oil, soya oil, sunflower oil, rape oil, fish oil5 preferably paraffine oil can be applied. Eight preferred embodiments of the present invention are summarized in the following Table: ' urα^ CM?. Aqueous phase 7 8 Dyestuffs: Erdbeerot 109/N 8 10 10 12 in % by weight Rouge VIF W 3002 10 Ostansinbrillantrot 8 H 613 Ro.damin B Water or Water 37- 0 40 0 38 4-2 4-0 33.5-38 50 aqueous mixtures Ethylene glycole - 17 2-5 in °/o by weight Tensiofix 821.2 °/o 5-2 5-7.5 I aqueous solution 03 I Oily phase Oils, in °/o Paraffine oil 5 30 5 4-5 5 4-5 by weight Soya oil Emulsifier, Triton X-4-5 5 in by weight Emulsogen M 100 100 100 100 100 100 100 100 Industrial applicability The advantage of the present invention ^ is that it is generally applicable for a wide range of active ingredients, provides an uniform film-coating having high adhesive strength, enables the use of pesticides duly adapted to the character and degree of infection and disease and is highly economical. Modes of carrying out the Invention Further details of the present invention are to be found in the Examples without limiting the scope of protection to the said Examples. ExamOle 1 1900 parts by weight of water are weighed in a 3 1 flask and 600 parts by weight of Erdbeerrot 109/N dyestuff are dissolved. 2250 parts by weight of paraffine oil are introduced into an other 3 1 flask and 250 parts by weight of Triton Y-4-5 emulsifier are added under intensive stirring. The two solutions prepared above are admixed in a colloidal mill (type Fryma MZ-80 R) . Example 2 1 00 parts by weight of water are weighed in a 3 1 flask and 600 parts by weight of Erdbeerrot 109/N dyestuff are dissolved. 2250 parts by weight of soya oil are introduced into an other 3 1 flask whereupon 250 parts by weight of Triton 2C- -5 emulsifier are dissolved under intensive stirring. The above two solutions are admixed in a colloidal mill (type Fryma MZ-80 R) . Example 5 2000 parts by weight of water are weighed in a 3 1 flask whereupon 500 parts by weight of Rouge VIF W 3002 dyestuff are dissolved. 2250 parts by weight of paraffine oil are introduced into an other 3 1 flask and 250 parts by weight of Triton X-4-5 emulsifier are added to the oil under intensive stirring. The above two solutions are admixed in a colloidal mill (Fryma MZ-80R) . Example 4- 1717 5 5 parts by weight of water (temperature 4-0 C°) are weighed in a 3 1 flask whereupon 32,5 parts by weight of Rhodamin BSA extra 1150 dyestuff are dissolved. 2925 parts by weight of paraffine oil are introduced into a 5 1 flask and 325 parts by weight of Triton X-4-5 emulsifier are added under intensive stirring. The above two solutions are admixed in colloidal mill (type Fryma MZ-80 R) ; the solutions are introduced into the mill in the order of succession of their preparation. Example 5 Into a 3 1 flask 2222,5 parts by weight of water are weighed in whereupon 27,5 parts by weight of a liquid Rhodamin 2BU dyestuff are dissolved. Into a 5 1 flask 24-75 parts by weight of paraffine oil are introduced and 275 parts by weight of Triton X-4-5 are added under intensive stirring. The above two solutions are admixed in a colloidal mill (type Fryma MZ-80 R) . Example 6 Into a 3 1 flask 24-61,5 parts by weight of water (50 C ) are introduced and 38,5 parts by weight of liquid Rhodamin 2 Bϋ dyestuff are dissolved. Into an other 3 1 flask 2200 parts by weight of 50 C° paraffine oil are weighed in and 300 parts by weight of Product VM 20 emulsifier pre-heated to 60 C° are added under intensive stirring. The above two solutions are admixed in a colloidal mill (type Fryma MZ-80 R) in the order of succession of their preparation. Example 7 Into a 3 1 flask 1835 parts by weight of water are introduced and 50 parts by weight of liquid Rhodamin 2 BU dyestuff are dissolved. Into a 5 1 flask 2 2 parts by weight of paraffine oil are introduced and 3 5 parts by weight of Triton X-4-5 emulsifier are added under intensive stirring. The above two solutions are introduced into a colloidal mill (type Fryma MZ-80 R) in the order of succession of their preparation and admixed. • Example 8 1390 part by weight of water are weighed in a 3 1 flask and 110 parts by weight of liquid Rhodamin 2 BU dyestuff are dissolved. Into a 5 1 flask 3150 parts by weight of paraffine oil are introduced and 350 parts by weight of Emulsogen M emulsifier are added under intensive stirring. The above two solutions are admixed in a colloidal mill (type Fryma MZ-80 R) . TTUR 1) Dyestuffs Erdbeerot 109/N 2 °/o by weight of neucoccine (Les Colorants Wackherr) Rouge VIF W 3002 (56 % by weight of neucoccine) (Les Colorants Wackherr) Ostansinbrillantrot H 613 (food-dyestuff) Czechoslovakia Rhodamin B (70 tetraethyl rhodamine) Poland Rhodamin 2BU liquid (about 60 by weight of rhodamine derivatives) BASF Rhodamin BSA extr. 1150 (100 °/ by weight of tetraethyl rhodamihe Ugine Kuhlmann 2) Emulsifier Triton X-4-5 (coctyl phenol-polyethoxy-ethanol) Rohm and Hass Emulsogen M (fatty alcohol polyglycol ether) Hoechst Product VM 20 (fatty acid polyglycol ester) rυ 1 3) Pesticides Orthocid 50 WP (50 % by weight of Capton) chemical name of active ingredient: 1.2.3-6- -tetrahydro-N-(trichloro-rnethylthio)-phthalimide Chevron-BVM Apron 35 SD (35 °/° by weight of Metalaxil) chemical name of active ingredient: methyl-N- -(2-methoxy-acetyl)-N-(2.6-xyly1)-DL-alani a e Ciba-Geigy Example 9 In a round-bottomed flask 100 g of winter wheat are subjected to seed dressing , with the composition according to Example 1 and fungicidal and insecticidal plant protecting agents and the germination strength of the thus treated seeds is determined. Control: non- -treated winter wheat 9 °/° * Treatment dosage Germination °/o Additive according Plant protecting Water to the present agent invention 3 1/t ^ . 25 1/t 97 6 1/t - 25 1/t 95 3 1/t 4-0 . carbofu an suspension (FW) 4- 1/t 25 1/t 95 6 1/t 4-0 °/ carbofuran suspension (FW) 8 3 t 25 1/t 94- 3 1/t 25 carbendazim suspension (FW) 21/t 25 1/t 95 3 i/t 50 °/ benomyl wettable powder (WP) 2 kg/t . 25 1/t 93 Example 10 In a round-bottomed flask 100 g of winter wheat are subjected to seed dressing with the composition according to Example 2 and fungicidal or insecticidal plant p rotecting agents. The germination strength of the thus treated seeds is determined. Control: untreated winter wheat : 94- , Treatment dosage Germination, % o Additive according Plant protecting Water to the present agent invention 3 1/t 25 1/t 95 6 1/t - 25 1/t 96 3 1/t 4-0 / °o carbofuran 25 i/t 96 suspension 4- 1/t 6 1/t 4-0 % carbofuran 25 i/t 94- suspension 8 1/t 3 l/t 25 % carbendazim 25 i/t 95 suspension 2 1/t 3 l/t 50 °/o benomyl 25 i/t 98 wettable powder 2 kgΛ Example 11 The germination data of bean subjected to seed dressing with the composition according to Example 3 are as follows: Additive according Water Germination °/o to the present invention Control 94- 3 1/t 15 1/t 96 3 1/t 5 1/t 97 3 1/t 96 Example 12 On a MIST-O-MATIK type machine the following seeds are subjected to seed dressing with the_ composition according to Example 3 ° Batch size : 100 kg of seeds. Seed Treatment Germination, °> before after treatment treatment Muscat melon Additive of the invention 4- 1/t Water 5-6 1/t 96 97 Marrowfat pea Additive of the invention 6 1/t 88 93 Water 1.6 1/t 50 / °o by weight of captan seed dressing agent 1.8 kg/t Carrot Additive of the invention 15 1/t 81 83 Water 9.9 1/t 50 °/o by weight of captan seed dressing agent 5-1 kg/t Example 13 Babarocon Maxidor bean (Phasseolus vulgaris) is subjected to seed dressing with the composition according to Example 3 against diseases occuring in the germination period. Amount of seeds : 150 kg/ha Sowing : on the 18th May 1981 Depth of sowing 5-6 cm OMPI Row and root distance : 4-5 x 3 cm S Plot size : 10 x 1000 m Number of replicates : 2 Method of seed dressing : wet seed dressing with 6 1/t of water time : the 16th April 1981 Time of evaluations : 21th May, 8th June and 6th July 1981. The results are summarized in the following Table: Treatment Infection of seeds, °/o Dosage Fusarium Colletotrichum kg/agent/t lindemuthianum seeds Orthocid 50 WP 2.0 3 5 + additive 3.0 Orthocid 50 WP 3.0 4- 10 Untreated control — 9 27 It appears from the above data that as a result of the use of the additive of the present invention the dose of Orthocid 5 WP (wettable powder comprising 50 °> by weight of Captan) can be decreased by 1 kg/t and no phytotoxical symptoms are observed. Example 14- In the district of Jajhalom (state farm Szerencs) bean of the Oxy Amidor species (Phaseolus vulgaris) is subjected to seed dressing with the composition according to Example 3 against diseases of the germination period. Amount of seeds : 166 kg/ha- Time of sowing : 12th May 1981 Depth of sowing : 4—5 cm Row and root distance : 4-5 x 3-4 cm Plot size : 2 Method of seed dressing : wet seed dressing with 7.01 of water/t time : 11th May 1981 Evaluation : in laboratory : 21st May 1981 field experiments : 22nd May and 10th June 1981, in the, cotyledonary phenophase of the bean at a height of 5-1 cm, with a row distance of 10 x 2 m per plot Laboratory results : Treatments Dose Number of infected seeds ; No 1 kg/t Fusarium Botrytis 3 Penici1-5 Eecteria spp. spp. lium . spp. Orthocid 50 WP 2.0 4 + additive 3-0 Orthocid 50 WP 3-0 4 (standard) Untreated 7 4 7 1 on the basis of 200 seeds per treatment 2 in a Papavize type medium 3 after incubation in a wet cell. O Field results Treatments Dose . Infection, % kg/t Fusarium Bolrvtiis Penicilli.um Bacterium spp. spp . Orthocid 50 WP 2.0 0.5 2.0 - 1.5 + additive 3 1 0 Orthocid 50 WP 3.0 1.0 2.0 - 3.0 (standard) Untreated - 3.5 2.0 1.5. 3.5 No phytotoxical symptoms are observed. When treatment is carried out with the composition of the present invention a stable, durable, uniform coating is formed on the surface of the seeds which does not cause environmental pollution. Thus the amount of the plant protecting agent can be reduced by 1 kg/to. Example 15 In the state farm of Dany hybride sorghum of the NK-101 species (Sorgum vulgare var. Saccharatum) is subjected to seed dressing with the composition according to Example 3 against diseases occuring in the germination period. Amount of seeds : 15 kg/ha Time of sowing : 19th May 1981 Depth of sowing : 4- cm Row distance : 50 cm Plot size : 0.6 ha Number of replicates : 2 Method of seed dressing : wet seed dressing with 10 1 of water/t Time of seed dressing : 14th May 1981 Evaluation : 12th and 23rd June 1981, in two-leaf stage of the sorghum and subsequently at a height of 15-20 cm the number of the shot-plants is counted on an area of 10 x 20 m on each plot. Treatment Dose Plant No/m kg/t . 12.06.81 23.06.81 I. II. average I. II. average repetition repetition Orthocid 50 WP 2 8.49 9 - 58 9.03 10.63 10.30 10.45 + additive 3 Orthocid 50 WP 2 8.05 8.10 8.07 10.20 10.53 10.36 (standard) Dithane M45 2 7 - 53 9 - 31 8.42 9.48 9.45 9.46 (standard) Control 7. CO 5 - 94 6.47 7.24 7.33 7-23 No phytotoxical symptoms are observed. The number of the shot plants is the highest when seeds coated with the composition of the present invention are used. Example 16 In the state farm of Szabadszentkiraly pea of species "Csoda" (Pisum sativum) is subjected to seed dressing with the composition according to Example 3 against diseases occuring in the germinating period. Amount of seeds : 300 kg/ha Time of sowing : 7th April 1981 Depth of sowing : 6-7 cm Plot size : 0.65 ha (1625 x 4 m) Method of seed dressing : wet seed dressing with 9 1 of water/t. Evaluation 21st April 1981 - seeds 12th May 1981 - complete shooting, cotyledonary stage 29th May 1981 - plant height of 15-20 cm. Treatment Dose Infection of seeds Root number kg/t lusarium Asccchyta 12th May 29th May spp. S PP- No./m. cαr±rol Nθy-t_ ccπtroL Additive + 3.0 Orthocid 502.0 2 8.75 88.65 16.5 205.25 P Orthocid 503.0 6 9 11.0 111.45 12.5 156.25 P Untreated 7 9.87 ICO 8.0 100 control No phytotoxical symptoms are observed. In the treatment carried out with the additive of the present invention + Orthocid 50 WP the stem (root) number is higher by 0 % and 106.25 than that of standard treatment obtained with Orthocid 50 WP and the control, respectively. The detectable Fusarium spp. (2.0) and Ascochyta sp. (2.0) infection of the dressed seeds is significantly lower than that of the standard (6.0 and 9.0 respectively) or the untreated control (7.0 and 9.0, respectively). Example 17 In the farmer's agricultural co-operative of erecsend pea of the Allround species (Pisum sativum) is subjected to seed dressing with the composition according to Example 3. Amount of seeds : 3 0 kg/ha Time of sowing : 27th March 1981 Time of shooting : 6th-10th April 1981 Plot size : 0.3 ha Number of replicates : 2 Method of seed dressing : wet seed dressing with 7.01 of water/t Time of seed dressing : 20th March 1981 Laboratory test is carried out by germinating twice 100 seeds each. Laboratory test Composition Dose Fusarium Aspergillus Penicillium Rhizopus Bacterial GermLna- kg/t spp. spp. spp. spp. infection tio Seed dressing additive + 3. Orthocid 50 WP 2,0 0.0 0.0 0.0 0.0 1.5 95.5 Orthocid 50 WP 3.0 0.0 1.5 o.o 0.5 2.0 94.0 1 rυ Untreated — 1.5 5.5 14.5 1.5 1.5 93.0 1 on the basis of tests carried out twice with 100 seeds each, Example 18 In the farmer's agricultural co-operative of Szabadszentkiraly pea of the " elvedon Wonder" species is subjected to seed dressing with the additive according to Example 3 against diseases occurring in the germination period. Amount of seeds : 300 kg/ha Time of sowing : 7th April 1981 Depth of sowing : 6-7 cm Plot size : 0.65 ba (1625 x 4 m) Method of seed dressing : wet seed dressing carried out with 7«01 of water/t Time of seed dressing : 3^d April. Time of evaluation : 21st April - seeds 12th May - cotyledonary stage 24th May - at plant height of 15-20 cm Treatment Dose Infection of seeds, °/o 12th May Root number 29th May kg/t . Fusarium Ascochyta No./m. control No./m. control spp. spp. Apron 35 SD + 2.0 + 2.0 5.0 12.5 126,64 13.5 168.75 + additive 3.0 Orthocid 0 WP (standard) 3.0 6.0 9.0 11.0 111.45 12.5 156.25 r Untreated - control 7.0 9.0 9.87 100 8.0 100.0 No phytotoxical symptoms are observed. As a result of seed dressing carried out with Apron + additive the root number becomes significantly higher than that of the control (68.75 °/°) . Simultaneously the growth of fungi on the surface of the seeds is strongly decreased. On seeds treated with the composition of the present invention Fusarium spp. fungi is grown at a rate of 2.0 % while on the untreated control at 7 .

Claims: What we claim is: 1. Dressing additive w h i c h c o m p r i s e s 10-80 by weight of an δil of • vegetable, animal or mineral origin; 2-7 °/o by weight of an emulsifier; 0-12 % by weight of a dyestuff and up to 100 °/o by weight of water. 2. Composition according to Claim 1 w h i c h c o m p r i s e s 20-60 °/o by weight of an oil. 3. Composition according to Claims 1 and 2 w h i c h c o m p r i s e s a vegetable oil, preferably soya oil. 4. Composition according to Claims 1 and 2 w h i c h c o m p r i s e s an animal oil, preferably fish oil. 5. Composition according to Claims 1 and 2 w h i c h c o m p r i s e s an oil of mineral origin, preferably paraffine oil.

Inventors: ANGYAN SANDOR, KARSAI JOZSEF, KIS GYOERGY, KOVATS FERENC, MARMAROSI KATALIN, PETROCZI ISTVAN, RACZ ISTVAN, SOS JOZSEF, SZEGOE ANDRAS, ANGYAN, SANDOR, KARSAI, JOZSEF, KIS, GYOERGY, KOVATS, FERENC, MARMAROSI, KATALIN, PETROCZI, ISTVAN, RACZ, ISTVAN, SOS, JOZSEF, SZEGOE, ANDRAS
Applicants: CHINOIN GYOGYSZER ES VEGYESZET, CHINOIN GYOGYSZER- ES VEGYESZETI TERMEKEK GYARA R.
Application year: 1984
Main classification: A01N25
IPC codes: A01C1, A01N25