SURFACTANT MIXTURE COMPOSITION

Abstract: A surfactant mixture composition comprising: (A) a sulfonic acid salt of a lower alkyl ester of a C₈ to C₂₂ saturated fatty acid; and (B) a sulfonic acid salt of a lower alkyl ester of a C₈ to C₂₂ unsaturated fatty acid, wherein the weight ratio (A/B) of the component (A) to the component (B) is 95/5 to 5/95. This surfactant mixture composition has the improved rins­ ing properties without decreasing the detergency characteristics.

Description: SURFACTANT MIXTURE COMPOSITION BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surfactant mixture composition. More specifically, it relates to a surfactant mixture composition in which the rinsing properties of a sulfonic acid salt of a lower alkyl ester of a saturated fatty acid are improved. 2. Description of the Prior Art Sulfonic acid salts of lower alkyl esters of saturated fatty acids, i.e., alpha-sulfo fatty acid ester salts, are surfactants having excellent detergency (i.e., detergent power) and hard-water resistance. However, alpha-sulfo fatty acid ester salts have disadvantages in that vigorous foaming occurs at a low concentration and, therefore, the rinsing properties are poor when they are incorporated into household detergents such as laundry detergents and dish-washing detergents, when compared with other conventional surfactants such as alpha-olefin sulfonates, alkylbenzene sulfonates, or sulfates of higher alcohols. As an improvement for the above-mentioned rinsing properties of alpha-sulfo fatty acid ester salts, Japanese Unexamined Patent Publication (Kokai) No. 53-97008 discloses the use of alpha-olefin sulfonates and sulfuric acid ester salts of alcohols combined with alpha-sulfo fatty acid ester salts. However, the rinsing properties of alpha-sulfo fatty acid ester salts were not satisfactorily improved as desired. Thus, it remains necessary that the above-mentioned disadvantages and problems of alpha-sulfo fatty acid ester salts should be fundamentally resolved. It is known that the rinsing properties, that is, the foaming at a low concentration of the surfactant are closely correlated to a critical micelle concentration (CMC) of the surfactants. When the CMC is low, a large amount of foam is likely to be formed at a low surfactant concentration and the rinsing properties become poor. Contrary to this, the foaming becomes less at a low surfactant concentration and, therefore, the rinsing properties are improved, as the CMC increases. It is expected that the increase in the CMC of the surfactants can be achieved by decreasing the hydrophobic nature of a hydrophobic group of the surfactant molecule or by increasing the hydrophilic nature of a hydrophilic group. However, when the hydrophobic nature of a hydrophobic group of the surfactant molecule is decreased or the hydrophilic nature of a hydrophilic group of the surfactant molecule is increased, the characteristics of the surfactants effecting the detergency of the surfactants such as foaming power, penetrating power, and solubilizing power are decreased. Accordingly, there is a demand in the art that the CMC of the surfactants is increased, and that the rinsing properties of the surfactants are improved, without decreasing the characteristics required for detergents. SUMMARY OF THE INVENTION Accordingly, the objects of the present invention are to eliminate the above-mentioned problems of the prior art and to provide a surfactant mixture composition containing a sulfonic acid salt of a lower alkyl ester of a saturated fatty acid and having remarkably improved rinsing properties without decreasing the detergency characteristics. Other objects and advantages of the present invention will be apparent from the following description. In accordance with the present invention, there is provided a surfactant mixture composition comprising: (A) a sulfonic acid salt of a lower alkyl ester of a C8 to C22 saturated fatty acid; and (B) a sulfonic acid salt of a lower alkyl ester of a C8 to C22 unsaturated fatty acid, wherein the weight ratio (A/B) of the component (A) to the component (B) is 95/5 to 5/95. DESCRIPTION OF THE PREFERRED EMBODIMENTS The component (A) used in the present invention is sulfonic acid salts of lower alkyl esters of C8 to C22 saturated fatty acids, preferably those having the lower alkyl groups with 1 to 6 carbon atoms. Of these sulfonic acid salts, those having fatty acid residues with 12 to 18 carbon atoms and lower alkyl groups with 1 to 3 carbon atoms are more preferably used in the present invention. The component (B) used in the present invention is sulfonic acid salts of lower alkyl esters of C8 to C22 unsaturated fatty acids, preferably those having lower alkyl groups with 1 to 6 carbon atoms. Of these sulfonic acid salts, those having fatty acid residues with 12 to 18 carbon atoms and lower alkyl groups with 1 to 3 carbon atoms are more preferably used in the present invention. Typical structures of the component (B) are as follows. Alkenyl monosulfonates EMI3.1 Alkenyl disulfonates EMI3.2 Hydroxy monosulfonates EMI3.3 wherein R and R' are independently alkyl or alkenyl groups, preferably those having 1 to 17 carbon atoms, M is a cationic ion, preferably an alkali metal such as sodium, potassium, and lithium an alkaline earth metal such as barium and magnesium, ammonium, and organic amine such as monoethanol amine, diethanol amine, and triethanol amine, and n is an integer of 0 to 15. Since the component (B) is a salt of a sulfonate of a lower alkyl ester of an unsaturated fatty acid, sulfonates containing no double bond such as the abovementioned hydroxy monosulfonates can be used as the component (B). However, the sulfonic acid salts of the unsaturated fatty acid esters of the component (B) preferably contain 50% by weight or more of a sulfonic acid salt of an unsaturated fatty acid ester having a double bond in view of the characteristics, particularly detergency, of the surfactants. As mentioned above, although the sulfonic acid salts of the component (B) include monosulfonic acid salts substituted with cne sulfonic group and polysulfonic acid salts substituted with two or more sulfonic groups such as disulfonic acid salts, the weight ratio of the monosulfonic acid salts to the polysulfonic acid salts is preferably 97/3 to 10/90-, more preferably 90/10 to 30/70. When the ratio of the monosulfonic acid salts to the polysulfonic acid salts is more than 97/3, the rinsing properties of the surfactants are not likely to be desirably improved. Contrary to this, when the above ratio is less than 10/90, the detergent characteristics such as the foaming power, penetrating power, and solubilizing power during washing are likely to be undesirably decreased. The weight ratio (A/B) of the component (A) to the component (B) in the present surfactant mixture composition should be 95/5 to 5/95, preferably 80/20 to 20/80, and more desirably 60/40 to 40/60. The desired improvements in the detergency, solubilizing properties, and rinsing properties can be achieved only when the components (A) and (B) are used together in the weight ratio of (A)/(B) = 95/5 to 5/95. The surfactant mixture composition according to the present invention can be prepared either by mixing the starting saturated fatty acid alkyl esters and the starting unsaturated fatty acid alkyl esters after the sulfonation or by first mixing the starting saturated and unsaturated fatty acid alkyl esters, followed by the sulfonation. Furthermore, unhardened or partially hardened products obtained during the purification processes of fatty acids or their salts from natural fats and oils can be effectively used as the starting mixtures. The sulfonation can be carried out by using, for example, a thin-film type sulfonation method or vessel type sulfonation method. As a sulfonating agent, any conventional sulfonating agent such as liquid S03 gaseous SO3 , oleum, or chlorosulfonic acid. The sulfonated products are then neutralized in any conventional manner by an alkaline agent to form the desired sulfonic acid salts. The salts of both the components (A) and (B) can be the alkali metal salts '(e.g., Na, K, and Li), alkaline earth salts (e.g., Mg and Ba), ammonium salts, and organic base salts (e.g., amine salts). When the surfactant mixture compositions according to the present invention are used as detergent compositions, other conventional ingredients for detergents such as inorganic builders (e.g., sodium sulfate, tripolyphosphate, sodium bicarbonate, alumino silicate, and potassium pyrophosphate), organic builders (e.g., sodium citrate, carboxymethyl cellulose, methyl cellulose, sodium polymaleate, and sodium polyacrylate), chelating agents (e.g., sodium nitrile triacetate and EDTA ), fluorescent brightening agents, and perfumes. According to the present invention, the surfactant mixture composition having a large solubility, excellent detergency characteristics, and excellent rinsing properties can be obtained by compounding the abovementioned components (A) and (B) in the specified ratio. EXAMPLES The present invention now will be further illustrated by, but is by no means limited to the following examples. Example 1 A 296 g (1 mole) amount Of methyl oleate was charged into a 1 liter four-necked glass flask. The flask was heated to a temperature of 80"C, A 240 g (3 moles) amount of SO3 diluted with nitrogen gas to 5% by volume was then introduced into the flask over 120 minutes while stirring to prepare a sulfonated mixture. A 80.4 g (158 based on the sulfonated mixture) amount of methanol and 30.6 g (2% in terms of H202 based on the sulfonated mixture) of 35% hydrogen peroxide were added to the sulfonated mixture obtained above. Thus, the sulfonated mixture was bleached at a temperature of 800C for 60 minutes. The resultant mixture was neutralized by a 10% aqueous sodium hydroxide solution. The mixture was heated at a temperature of 950C to 1000C for 2 hours to thermally decompose sultone. Thus, sodium sulfonate of methyl oleate was obtained. The ratio cf the monosulfonate to the polysulfonate determined by an electrophoretic ion determination apparatus was 30/70. On the other hand, methyl stearate having an iodine value of 0.02 was sulfonated, bleached, and neutralized in the same manner as described above. Thus, sodium sulfonate of methyl stearate (i.e., sodium alpha-sulfo stearate) was obtained. The sodium sulfonate of methyl oleate (i.e., component B) and the sodium sulfonate of methyl stearate (i.e., component A) obtained above were mixed together in the ratio listed in Table 1. The CMC, foaming property, penetrating power, and solubilizing capability of the resultant surfactant mixture, the foaming degree at an ordinal washing concentration, a surfactant concentration at which a foaming height becomes zero, and the solubility of the surfactant mixture were determined as follows: Solubilizing capability: a yellow-OB solubilizing method, at 400C for 48 hours CMC: A yellow-OB method at '400C Penetrating power: A canvas disc method (1 cm square), at a concentration of 10 mbl/liter at 400C Foaming property: Foaming height was deter mined by a Ross & Miles method at 400C Solubility: Crystal precipitation temperature was determined at a temperature decreasing rate of 1 C/min in a 19 aqueous ethylene glycol solution (ethylene glycol/water = 1/1) Table 1 Run No. 1*1 2 3 4 5*1 Component B/component A 100/0 80/20 50/50 30/70 0/100 Characteristics CMC (m mole/l) 3.0 1.2 1.0 0.8 0.1 Foaming height (mm) 20 85 135 135 110 Penetrating power (l/sec) 0.18 0.15 0.10 0.07 0.04 Solubilizing capability 2.5 3.9 4.1 4.4 4.5 (mole/mole x 102) Solubility Crystallization temp. less than ( C) -20 C -10 C 0 to -5 C 5 to 10 C 18 to 20 C Rinsing Surfactant concentration property at which foaming height 0.1 0.05 0.01 0.008 0.0005 become zero (m mole/l) *1: Comparative example Example 2 The rinsing properties of the mixture of the sulfonate of methyl stearate and the sulfonate of methyl oleate prepared in Example 1 were evaluated in a commercially available washing machine. The test conditions were as follows: Amount of detergent: 40 g/Water 30 liters Water temperature: 250C Washing matter: Naturally soiled eight cotton shirts Table 2 RunNo. 1 2*1 Detergent Sulfonate of 10 wt% 20 wt% composition methyl stearate Sulfonate of 10 wt% 0 methyl oleate Sodium sulfate balance balance Foam height during washing (mm) 15 - 20 15 - 20 Rinsing First time Foam height of Foam height of properties 2 - 3 nin 5 - 10 (Entire surface) (Entire surface) Second time Foam height of Foam height of less than 1 mm 3 - 5 Itm (Partially) (Entire Surface) Third time No substantial Foam height of foam residue 1 - 3 mm (Entire surface) *1: Comparative example

Claims: CLAIMS 1. A surfactant mixture composition comprising: (A) a sulfonic acid salt of a lower alkyl ester of a C8 to C22 saturated fatty acid; and (B) a sulfonic acid salt of a lower alkyl ester of a C8 to C22 unsaturated fatty acid, wherein the weight ratio (A/B) of the component (A) to the component (B) is 95/5 to 5/95. 2. A surfactant mixture composition as claimed in claim 1, wherein 50% by weight pr more of the component (B) is a sulfonic acid salt of a lower alkyl ester of a cog 8 to C22 unsaturated fatty acid having a double bond in the molecule thereof. 3. A surfactant mixture composition as claimed in claim 1, wherein the weight ratio of a monosulfonic acid salt to a polysulfonic acid salt in the sulfonic acid salt of the lower alkyl ester of the C8 to 022 unsaturatd fatty acid of the component (B) is 97/3 to 10/90. 4. A surfactant mixture composition as claimed in claim 1, wherein the weight ratio of the component (A) to the component (B) is 80/20 to 20/80. 5. A surfactant mixture composition as claimed in claim 1, wherein the lower alkyl groups in the lower alkyl esters of the components (A) and (B) are those having 1 to 6 carbon atoms.

Inventors: KITANO, KYOZO, NAGANO, KATSUMASA, SEKIGUCHI, SHIZUO
Applicants: LION CORPORATION
Application year: 1984
Main classification: C11D1
IPC codes: C11D1