BENZAMIDINE GROUP COMPOUNDS AND AGRICULTURAL FUNGICIDAL COMPOSITIONS CONTAINING THE SAME

Abstract: Disclosed is a benzamidine group compound repre­ sented by the general formula (I): wherein R, X, m, Z, n and M are defined in the specification. The compound is useful for an agricultural fungicide.

Description: Benzamidine group compounds and agricultural fungicidal compositions containing the same This invention relates to a novel benzamidine group compound and also to a novel agricultural fungicidal composition containing the same as an active ingredient. Conventionally, various kinds of organomercury compounds, arsenic compounds, copper compounds and the like have frequently been employed for agricultural fungicides. However, these compounds have been revealed to have serious disadvantages such as residual pollution of soil, and toxicity or residual toxicity against man and beast, the use thereof has been limited. Furthermore, there have recently appeared drug-resistant fungi or bacteria in plant pests of various field crops, particularly in powdery mildew, gray mold, blast disease and sclerotium disease. Therefore, the effect on such plant pests by chemicals which have been employed for many years has been decreasing. For the reasons mentioned above, it has been desired to develop a new type of agricultural fungicides. As a result of the extensive studies on fungicidal effect of various compounds for th purpose of.developing a new agricultural fungicide, the present inventors have succeeded to synthesize a new benzamidine group compound and have found that they have an excellent fungicidal effect against plant pests parasitic on various field crops, and have accomplished this invention. An object of this invention is to provide a novel benzamidine group compound. Another object of this invention is to provide an agricultural fungicidal composition containing said benzamidine group compound as an active ingredient. The novel compound according to this invention is a benzamidine group compound represented by the general formula (I): EMI2.1 wherein R represents a lower alkyl group; X represents a halogen atom or a lower alkyl group; m represents an integer of 0, 1 or 2; Z represents an oxygen atom or a sulfur atom; n represents an integer of 1 or 2; when n is 1, M represents a lower alkyl group, a lower alkenvl group, a phenyl group of the formula EMI2.2 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and Q represents an integer of 0, 1, 2 or 3) or a benzyl group of the formula EMI2.3 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and Q represents an integer of 0, 1, 2 or 3); and when n is 2, M represents a metal selected from the group consisting of nickel, cobalt and zinc. More specifically, in a preferred embodiment, a benzamidine compound according to this invention is represented by the general formula (II): EMI3.1 wherein X, m and n, have the same meanings as defined in the formula (I), and when n is 1, M represents a lower alkyl group, a lower alkenyl group, a benzyl group or a halogenated benzyl group and when n is 2, M has the same meaning as defined in the formula (I). In the above general formula, as the lower alkyl group represented by k or M, there may be preferably mentioned a lower alkyl group having 1 to 4 carbon atoms such as methyl, ethyl,- n (-or i-)propyl, n-(i-, or tert-)butyl and the like. As the halogen atom represented by X or Y (a substituent on the benzyl group of the formula EMI3.2 represented by M), there may be mentioned any of chlorine, bromine, fluorine and iodine. As the lower alkenyl group represented by M, there may be preferably mentioned a lower alkenyl group having 3 to 5 carbon atoms such as allyl, butenyl and pentenyl and the like. In another preferred embodiment, a benzamidine compound according to this invention is represented by the general formula (III): EMI4.1 wherein R, X, m and Q have the same meanings as defined in the formula (I) and Y represents a lower alkyl group or a halogen atom. In the above general formula, the lower alkyl group represented by R, X or Y includes, for example, a lower alkyl group having 1 to 4 carbon atoms such as methyl, ethyl, n-(or i-)propyl, n-(i- or tert-)butyl and the like. As the halogen atom represented by X or Y, there may be mentioned any of chlorine, bromine, fluorine and iodine. In still another preferred embodiment, a benzamidine compound according to this invention is represented by the general formula (IV): EMI4.2 wherein R, X, m and Y have the same meanings as defined in the formula (I) and Q represents an integer of 0, 1 or 2. In the above general formula, as the lower alkyl group represented by R, X or Y, there may be preferably mentioned a lower alkyl group having 1 to 4 carbon atoms such as methyl, ethyl, n-(or i-)propyl, n-(i- or tert-)butyl and the like. As the halogen atom represented by X or Y, there may be mentioned any of chlorine, bromine, fluorine and iodine. As the lower alkoxy group represented by Y, there may be preferably mentioned a lower alkoxy group having 1 to 4 carbon atoms as methoxy, ethoxy, propoxy, butoxy and the like. Examples of the benzamidine compounds having the abovementioned general formula (I) according to this invention are listed in Table 1. Table 1 EMI6.1 <tb> Compound <SEP> -I <SEP> C2E, <SEP> Physical <tb> <SEP> No. <SEP> Structural <SEP> formula <SEP> property <tb> <SEP> N <SEP> c, <SEP> H, <tb> <SEP> -I <SEP> 02115 <tb> <SEP> 1 <SEP> 5 <SEP> C <SEP> = <SEP> N <SEP> - <SEP> C <SEP> - <SEP> S <SEP> - <SEP> CEs <SEP> n2 <tb> <SEP> 1 <SEP> II <SEP> D7L64O <tb> <SEP> S <tb> <SEP> 02 <SEP> C1 <tb> <SEP> 02115 <tb> <SEP> 2 <SEP> 0=N-0-S-C2115 <SEP> 5 <SEP> n <SEP> DO <SEP> 1.6 <SEP> 34 <tb> <SEP> S <tb> <SEP> 0,11 <tb> <SEP> 02115 <tb> <SEP> 3 <SEP> rN'\ffl'0=N-0-S-c3111(n) <SEP> n%8L6160 <tb> <SEP> J <SEP> II <tb> <SEP> S <tb> <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> 1 <SEP> 02115 <tb> <SEP> A <SEP> 4 <SEP> = <SEP> G; <SEP> i- <SEP> C <SEP> - <SEP> S <SEP> - <SEP> C5E <SEP> 2D016161 <tb> <SEP> S <tb> <SEP> 02115 <tb> <SEP> no <tb> <SEP> 5 <SEP> 0=N-01-S-04119(n) <SEP> n2Dd <SEP> 1.6102 <tb> <SEP> S <tb> <SEP> 02115 <tb> <SEP> I <SEP> 02115 <tb> <SEP> 6 <SEP> y <SEP> - <SEP> C <SEP> = <SEP> u' <SEP> -- <SEP> C: <SEP> -- <SEP> ! <SEP> 22od <SEP> C1 <SEP> HB <SEP> (i) <SEP> n96 <SEP> 1.6082 <tb> <SEP> S <tb> Table 1 (cont'd) EMI7.1 <tb> Compound <SEP> Structural <SEP> formula <SEP> Physical <tb> <SEP> No. <SEP> property <tb> <SEP> No <tb> <SEP> 7 <SEP> O <SEP> ,- <SEP> C <SEP> - <SEP> N <SEP> - <SEP> C- <SEP> S <SEP> - <SEP> CH2CH <SEP> = <SEP> CEO <SEP> aD <SEP> 1.6320 <tb> <SEP> S <tb> 8 <SEP> Cz <SEP> ;0;2R11;550112 <SEP> a, <SEP> I <tb> <SEP> 8 <SEP> e <SEP> N <SEP> < <SEP> C2Bs <SEP> n1D <SEP> 1.65G0 <tb> <SEP> S <tb> <SEP> '111 <tb> <SEP> C9h5 <tb> <SEP> 9 <SEP> \JC=N--S-Ce2- <SEP> L <SEP> li5 <tb> <SEP> 9 <SEP> ( <SEP> 9 <SEP> 0- <SEP> N <SEP> - <SEP> C- <SEP> S <SEP> -CF2 <SEP> e <SEP> -C1 <SEP> Dz <SEP> 7 <SEP> 1. <SEP> 647B <tb> <SEP> C2E3 <tb> <SEP> I <SEP> N < <SEP> 02H <SEP> 1 <SEP> dec <tb> <SEP> 10 <SEP> \,c=N-0- <SEP> S <SEP> Ni <SEP> 184 <tb> <SEP> 2 <SEP> -189t <tb> <SEP> S <tb> <SEP> I <SEP> CzRs <tb> <SEP> CtzH, <tb> <SEP> 11 <SEP> C <SEP> C <SEP> - <SEP> N <SEP> -C <SEP> - <SEP> S <SEP> Zn <tb> <SEP> II <SEP> 2 <SEP> 9698t <tb> <SEP> S <tb> <SEP> N <SEP> < cO211H: <SEP> dec. <tb> <SEP> 12 <SEP> S <SEP> Co <SEP> 0 <SEP> N <SEP> 2O4t <tb> <SEP> S <SEP> 2 <tb> Table 1 (cont'd) EMI8.1 <SEP> 1 <SEP> T <tb> <SEP> Compound <SEP> } <SEP> Structural <SEP> formula <SEP> µ <SEP> Physical <tb> <SEP> No. <SEP> -- <SEP> Structural <SEP> formula <SEP> X <SEP> property <tb> I <SEP> No. <tb> <SEP> 9 <SEP> S <SEP> i <SEP> Ni <SEP> 215 <SEP> 13 <SEP> 02115 <SEP> S2Ni <SEP> s=N-c <SEP> \c=N-0 <SEP> II <SEP> 20t <tb> OR3 <SEP> S <tb> <SEP> N <SEP> N < C2E5 <SEP> I <tb> <SEP> j <SEP> 14 <SEP> 1 <SEP> t <SEP> > <SEP> C= <SEP> N <SEP> - <SEP> C <SEP> - <SEP> S <SEP> ) <SEP> ZnSZn <SEP> | <tb> <SEP> 14 <SEP> (- <SEP> I <SEP> lap <tb> <SEP> 2 <tb> <SEP> 0113 <SEP> 5 <SEP> 1 <tb> <SEP> II <SEP> 0 <tb> <SEP> I <SEP> N' < 02115 <SEP> Ides. <tb> | <SEP> 15 <SEP> , <SEP> W <tb> <SEP> i <SEP> S <SEP> S2Ni <SEP> 2 <tb> <SEP> IS <SEP> 1 <SEP> ¸ <tb> <SEP> 0 <tb> <SEP> R3 <SEP> N < 02H5 <SEP> 1dec. <tb> <SEP> (ffi.0'=N-011 <SEP> S <SEP> 2 <SEP> Zn <SEP> 1 <SEP> 1 <SEP> ; <SEP> clISt <tb> <SEP> S <tb> <SEP> I <SEP> N < <SEP> S <tb> <SEP> Ni <tb> <SEP> I <SEP> 0qH <SEP> dec. <tb> <SEP> 17 <SEP> CH3-0=N-01-- <SEP> 200 <SEP> t <tb> <SEP> IS <SEP> S2Ni <tb> <SEP> N <SEP> 2 <SEP> e5 <tb> -02115 <SEP> dec. <tb> <SEP> 18 <SEP> C1130=N0ll <SEP> SZn <SEP> 11 <SEP> St <tb> <SEP> I <SEP> S <SEP> 21 <tb> Table 1 (cont'd) EMI9.1 <tb> Compound <SEP> Stxuctural- <SEP> formula <SEP> Physical <tb> <SEP> No. <SEP> Structurait <SEP> N <SEP> < <SEP> property <tb> <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> 021115 <SEP> deci <tb> <SEP> 19 <SEP> 0=N- <SEP> 0-S <SEP> Ni <SEP> - <SEP> 2 <SEP> 0 <SEP> 5 <SEP> t <tb> <SEP> ce <SEP> S <SEP> 2 <tb> <SEP> S <SEP> 2 <tb> <SEP> N <SEP> < <SEP> 02H5 <SEP> I <tb> <SEP> 1 <SEP> 02115 <SEP> dec. <tb> <SEP> 20 <SEP> 0=N-C- <SEP> N <SEP> - <SEP> 0- <SEP> S <SEP> ) <SEP> Zn <tb> <SEP> II <SEP> : <SEP> ilOt <tb> <SEP> V <SEP> CG <SEP> S <SEP> 2 <tb> <SEP> . <SEP> . <SEP> ¯ <tb> <SEP> 21 <SEP> (Cç <SEP> o <SEP> 0- <SEP> N <SEP> - <SEP> 0- <SEP> S <SEP> ss <SEP> no <SEP> dec. <tb> <SEP> 21 <SEP> 0--N-OS <SEP> Ni <tb> <SEP> 511 <SEP> 2 <SEP> 200 <SEP> t <tb> <SEP> IN < <SEP> oC221111: <tb> <SEP> 22 <SEP> X <SEP> 01=N-0- <SEP> S <SEP> Zn <SEP> dec. <tb> <SEP> t <SEP> S <SEP> 2 <tb> <SEP> 02115 <tb> <SEP> N <SEP> < <SEP> C2H5 <tb> <SEP> I <tb> <SEP> Il <SEP> c=w-c-s-y <SEP> S) <SEP> 6 <SEP> 63-6 <SEP> St <tb> <SEP> 0 <tb> <SEP> 02115 <tb> <SEP> N <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> 24 <SEP> \-N-0-S <SEP> 011 <SEP> lap <tb> <SEP> 4 <SEP> II <SEP> 3 <SEP> 55-57t <tb> <SEP> o <tb> Table 1 (cont'd) EMI10.1 <tb> <SEP> Physical <tb> <SEP> No. <SEP> | <SEP> Structural <SEP> formula <SEP> property <tb> <SEP> N <SEP> < <SEP> cho <SEP> 011 <tb> <SEP> 02R5 <tb> <SEP> 25--CC-S-( <SEP> nDlS626 <tb> <SEP> o <SEP> ert-C411q <SEP> I <tb> <SEP> 02115 <SEP> 011 <tb> <SEP> 26 <SEP> P-5 <SEP> o1=0211- <SEP> 3 <SEP> 1 <SEP> CHJ <tb> <SEP> s%) <SEP> C113 <tb> <SEP> o <tb> <SEP> I <SEP> N < 02115 <SEP> 0113 <tb> <SEP> 27 <SEP> !;01=;rn11;5 <SEP> C <SEP> n2oDLS99B <tb> <SEP> 0 <SEP> I <tb> <SEP> N <SEP> < 02115 <tb> 28 <SEP> C=N--CC-S- <SEP> nlDL5992 <tb> <SEP> II <SEP> 72--7aC <tb> <SEP> 0 <tb> <SEP> N <SEP> < <SEP> 11 <SEP> CH3 <SEP> <tb> <SEP> C2 <SEP> m.p <SEP> <tb> <SEP> 30 <SEP> 5 <SEP> I <SEP> C2Xs <SEP> 4 <SEP> m.p <tb> - <SEP> 0 <SEP> i-C3E7 <SEP> 105-107t <tb> <SEP> 0 <tb> Table 1 (cont'd) EMI11.1 <tb> I <SEP> I <tb> compounds <SEP> Structural <SEP> formula <SEP> i <tb> <SEP> No. <SEP> I <SEP> Structural <SEP> formula <SEP> property <tb> jL <SEP> < 02115 <tb> <SEP> j <SEP> 31 <SEP> lj <SEP> S <SEP> 0 <SEP> - <SEP> N <SEP> - <SEP> 0 <SEP> - <SEP> 8o <SEP> tert-% <SEP> H9 <SEP> | <SEP> n1D <SEP> 1.5885 <tb> <SEP> L <tb> <SEP> < <SEP> N <SEP> E <SEP> l <SEP> I <tb> <SEP> 02115 <SEP> C=N--CC-S <SEP> b <SEP> m. <SEP> l <SEP> lap <tb> <SEP> 32 <SEP> J,C1=N-01- <SEP> , <SEP> I <SEP> 8284t <tb> <SEP> i, <tb> <SEP> N <SEP> < <SEP> Cz <SEP> Ii, <tb> <SEP> 33 <SEP> 1C=N-011-SF <SEP> n2Dd <SEP> l <tb> <SEP> II <SEP> <tb> <SEP> No <SEP> (IL <SEP> I <tb> <SEP> 02115 <tb> <SEP> m.p <tb> <SEP> Y'C=N--CC-S <tb> <SEP> o <SEP> Ci <tb> <SEP> C2115 <tb> <SEP> N <SEP> H, <tb> <SEP> 35 <SEP> 01130=N-C-S <tb> II <SEP> CHss <SEP> 3 <SEP> G= <SEP> N <SEP> - <SEP> G <SEP> - <SEP> S <SEP> 4 <SEP> 61-63t <tb> <SEP> 0 <tb> <SEP> N < <SEP> C <SEP> a, <tb> <SEP> 02115 <tb> <SEP> 36 <SEP> Ci <SEP> C=N-C-S <SEP> m.p <tb> <SEP> <SEP> ¯ <SEP> 79¯81t <tb> <SEP> 0 <tb> Table 1 (cont'd) EMI12.1 <tb> <SEP> Physical <tb> Compound <SEP> - <SEP> Structural <SEP> formula <SEP> - <SEP> property <tb> <SEP> I <SEP> | <SEP> CH3 <SEP> N < <SEP> Cz <SEP> EI, <tb> <SEP> 02115 <tb> <SEP> I <SEP> 37 <SEP> 81 <SEP> b <SEP> I <tb> 137 <SEP> if <SEP> c <SEP> 52¯6QC <tb> <SEP> 0 <tb> N < <tb> <SEP> m.p <tb> <SEP> 02H5 <SEP> P <tb> <SEP> 38 <SEP> C-1 <SEP> t <SEP> 0 <SEP> <tb> <SEP> 38 <SEP> II <tb> <SEP> I0 <tb> <SEP> 39 <SEP> i <tb> cm, <SEP> 1 <tb> 39 <SEP> 39 <SEP> 1 <SEP> F---C=NN-CLS <SEP> I <tb> I <SEP> II <SEP> 85-87&commat; <SEP> I <tb> <SEP> I0 <SEP> S <tb> <SEP> I <SEP> fl0311? <tb> <SEP> 40 <SEP> 1 <SEP> > <SEP> n-C3H <SEP> |^lD <tb> C=N-C-S <tb> <SEP> I <SEP> II <SEP> -i <tb> <SEP> II <SEP> 0 <tb> <SEP> I <SEP> O <SEP> I <tb> <SEP> 41 <SEP> /\C1=N-C-8-CH- <SEP> lap <tb> <SEP> 1 <SEP> 41 <SEP> 4 <SEP> C <SEP> - <SEP> N <SEP> - <SEP> 0- <SEP> S <SEP> - <SEP> OE2- <SEP> O <SEP> 50-52t <tb> <SEP> 0 <tb> <SEP> IN < 02115 <tb> <SEP> G, <SEP> q5 <tb> 42 <SEP> O <SEP> - <SEP> C <SEP> - <SEP> N <SEP> - <SEP> 42 <SEP> S <SEP> - <SEP> CE7 <SEP> - <SEP> t <SEP> C-H3 <SEP> -CaJ <tb> <SEP> 0 <tb> Table 1 (cont'd) EMI13.1 <tb> <SEP> Physical <tb> <SEP> Compound <tb> <SEP> No. <SEP> Strutural <SEP> formula <SEP> poperty <tb> <SEP> 43 <SEP> C <SEP> C <SEP> = <SEP> N <SEP> - <SEP> C- <SEP> S <SEP> - <SEP> CH2 <SEP> o <SEP> mP <tb> <SEP> II <SEP> .6¯68t <tb> <SEP> 0 <tb> <SEP> 02115 <tb> <SEP> N <SEP> < <SEP> O2H5 <tb> <SEP> 44 <SEP> O <SEP> C <SEP> = <SEP> NCS- <SEP> CH2 <SEP> < <SEP> n25LSSSO <tb> <SEP> II <SEP> D <tb> <SEP> O <SEP> Cg <tb> <SEP> N <SEP> < <SEP> 025 <tb> <SEP> 1 <SEP> 02115 <tb> <SEP> 45 <SEP> NSOER,oOOEa <SEP> 1128D15820 <tb> <SEP> 'II <tb> <SEP> 0 <tb> <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> 02115 <tb> <SEP> 46 <SEP> 0=N-C11-S- <SEP> CH2tert-0411g <SEP> nod <SEP> 1.5815 <tb> <SEP> o <SEP> I <tb> N < <SEP> G2 <SEP> HI <SEP> C <tb> <SEP> 47 <SEP> I <SEP> | <SEP> < <SEP> 02115 <tb> <SEP> 47 <SEP> C <SEP> =N-- <SEP> G <SEP> -- <SEP> S <SEP> -- <SEP> CH2 <tb> <SEP> II <SEP> D <tb> <SEP> O <SEP> C <SEP> Ht <SEP> D <tb> <SEP> N <SEP> < <SEP> 02H5 <tb> <SEP> 02115 <tb> <SEP> 48 <SEP> \2- <SEP> C <SEP> =N <SEP> -- <SEP> C <SEP> -- <SEP> S <SEP> -- <SEP> CH2- <SEP> rHs <tb> <SEP> 0 <tb> Table 1 (cont'd) EMI14.1 <tb> <SEP> ¯ <SEP> Physical <tb> Compound <SEP> Structural <SEP> formula <SEP> µ <SEP> property <tb> <SEP> i <SEP> ¯¯ <tb> <SEP> 02Hs <tb> <SEP> 49 <SEP> : :0'=N0,ffl)S0R2 <SEP> 01 <SEP> n251.6015 <tb> <SEP> 49 <SEP> D <tb> <SEP> 0 <tb> <SEP> N <SEP> < <SEP> 011 <tb> <SEP> 02115 <tb> <SEP> 50 <SEP> 0=N-0-S-0112/\-0 <SEP> U-cl <SEP> u2D51.6077 <tb> <SEP> II <tb> <SEP> 0 <tb> <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> I <SEP> 02115 <tb> <SEP> 51 <SEP> (1 <SEP> --G <SEP> =N <SEP> -- <SEP> C <SEP> rLID91.5921 <tb> <SEP> 0 <tb> <SEP> ce <SEP> o <tb> <SEP> I <SEP> C2H5 <tb> <SEP> 52- <SEP> 0-0-S-OH2tert-C4119 <SEP> fez <SEP> nlD1.5793 <tb> <SEP> II <tb> <SEP> CHS <SEP> O <tb> N <SEP> < 02115 <tb> <SEP> C2H, <tb> <SEP> i-c-s-oE2 <SEP> t <SEP> tert-O.Hg <SEP> rlt91 <SEP> 5762 <tb> <SEP> II <SEP> 0 <tb> <SEP> C2H5 <tb> <SEP> N <SEP> < <SEP> C' <SEP> TLC <tb> <SEP> 54 <SEP> N <SEP> C1=N-011-S <SEP> 0112 <SEP> -/ffi.-N02 <SEP> (benzene) <tb> Table 1 (cont'd) EMI15.1 <tb> .Compound <SEP> Structural <SEP> 1 <SEP> Physical <tb> <SEP> -No. <SEP> Structural <SEP> formula <SEP> I <SEP> property <tb> <SEP> N < <tb> <SEP> I <SEP> 02115 <SEP> lap <tb> <SEP> 55 <SEP> O <SEP> 0-N <SEP> - <SEP> 0- <SEP> S <SEP> - <SEP> CEe <SEP> 13r <tb> <SEP> Il <SEP> J <SEP> II <SEP> J <SEP> 82-84t <tb> <SEP> 0 <tb> <SEP> ()2E5 <tb> 1 <SEP> 56' <SEP> ca <SEP> c, <SEP> lap <tb> <SEP> 2 <SEP> 1- <SEP> N <SEP> - <SEP> 0 <SEP> - <SEP> S <SEP> - <SEP> OE2 <SEP> < <SEP> - <SEP> 91-93t <tb> <SEP> 5 <SEP> r <SEP> <SEP> = <SEP> X <SEP> nD <SEP> 1 <SEP> 5778 <SEP> 1 <tb> <SEP> 0 <tb> <SEP> < <SEP> 0sh1(n) <tb> <SEP> cze-e <SEP> H7(n) <SEP> (n) <SEP> -\(IL <SEP> n111S8S8 <tb> <SEP> 0SOH2 <tb> <SEP> II <SEP> D <tb> <SEP> o <tb> <SEP> I <SEP> 04119(n) <tb> <SEP> 60 <SEP> 0=N- <SEP> 0-S- <SEP> C112\ <SEP> .2D1.5662 <tb> <SEP> II <SEP> U <tb> <SEP> 0 <tb> Table 1 (cont'd) EMI16.1 <tb> -Compound <SEP> Structural <SEP> formula <SEP> Physical <tb> No. <SEP> Structural <SEP> formula <SEP> I <SEP> property <SEP> S <tb> <SEP> No. <tb> <SEP> I <SEP> C11g(n) <tb> <SEP> C=--CC--S-2- <SEP> t <SEP> I <SEP> orE0(n) <SEP> < <tb> <SEP> - <SEP> II <SEP> U <tb> I <SEP> I <SEP> 0 <tb> <SEP> N < <SEP> O <tb> I <SEP> C4t9(n) <tb> <SEP> 62 <SEP> ¯1' <SEP> null.560:3 <tb> 62 <SEP> DA-0=N <SEP> I <SEP> C1120 <SEP> U <tb> <SEP> 0 <tb> <SEP> N <SEP> < <SEP> 02115 <tb> <SEP> 63 <SEP> 63 <SEP> t <SEP> F- <SEP> t <SEP> C <SEP> = <SEP> N <SEP> - <SEP> G- <SEP> S <SEP> - <SEP> CE; <SEP> 02115 <tb> <SEP> i <SEP> 61-62t <tb> The above listed benzamidine compounds Nos. 1 to 22 according to this invention can be prepared, for example1 by a method described below. As the first step, according to the following scheme, benzamidines and carbon do sulfide are reacted with each other in a concentrated (conc.) aqueous sodium hydroxide solution to synthesize a sodium amidinodithioate: EMI17.1 (wherein X and m have the same meanings as defined in the formula (II) or (I)). The reaction can be carried out in water or a diluted (dil.) aqueous alcoholic solution at a temperature of -5 to 400C. After isolation of the sodium amidinothioate from the reaction system or without the isolation, the thus obtained dithioate is then reacted with a halide such as a lower alkyl halide, a lower alkenyl halide, a (halogenated) benzyl halide and the like; or with a salt of a metal such as nickel, cobalt and zinc with a mineral acid such as hydrochloric acid, sulfuric acid, nitric acid and the like, at a temperature of 0 to 500C to synthesize various benzamidine compounds according to this invention. This reaction can be also carried out in water or a dil. aqueous alcoholic solution. The above listed benzamidine compounds Nos. 23 to 40 of the present invention can be easily prepared according to the following scheme by reacting benzamidines with S-phenyl chlorothioformate: EMI18.1 (wherein R, X, Y, m and Q have the same meanings as defined in above formula (III)). This reaction can be carried out at 0 to 600C in an organic solvent such as ethyl ether, benzene, toluene, dichloroethane, chloroform and the like, in the presence of a dehydrochloric acid agent such as pyridine, a tertiary amine, e.g., triethylamine and dimethylaniline, sodium hydroxide, potassium carbonate and the like. Sphenyl chlorothioformate may be used in an amount of 0.5 to 5 moles per mole of benzamidines and the dehydrochloric acid agent may be preferably used in an amount of 0.5 to 10 moles per mole of benzamidines. The above listed benzamidine compounds Nos. 41 to 63 of the present invention can be easily prepared according to the following scheme by reacting benzamidines with S-benzyl chlorothioformate: EMI18.2 EMI19.1 (wherein, R, X, Y, m and l have the same meanings as defined in above formula (IV)). This reaction can be carried out at O to 600C in an organic solvent such as ethyl ether, benzene, toluene, dichloroethane, chloroform and the like, in the presence of a dehydrochloric acid agent such as pyridine, a tertiary amine, e.g., triethylamine and dimethylaniline, sodium hydroxide, potassium carbonate and the like. Sbenzyl chlorothioformate may be used in an amount of 0.5 to 5 moles per mole of benzamidines and the dehydrochloric acid agent may be preferably used in an amount of 0.5 to 10 moles per mole of benzamidines. The synthesis of the compounds according to this invention will be explained in more detail by the following Synthesis. Synthesis 1. Synthesis of N,N-dethyl-N'-n-propyl- dithiocarboxybenzamidine (Compound No. 3) To a mixture of 5.0 g (0.028 mol) of N,N-diethylbenzamidine and 2.3 g (0.030 mol) of carbon disulfide was added 50 ml of water, and then 1.3 g (0.032 mol) of sodium hydroxide dissolved in 5 mA of water was added dropwise thereto under ice cooling with vigorous stirring. During the addition, the reaction mixture gradually turned orange. After stirring for further one hour, 3.5 g (0.024 mol) of n-propylbromide was added dropwise (the reaction mixture turned yellow) and stirring was continued for 30 minutes. The resultant reaction mixture was extract ed with 60 ml of chloroform and the extract was neu tralized with 2N hydrochloric acid, washed with water and dried over anhydrous sodium sulfate. Chloroform was--=emoved from the resultant extract under reduced pressure to give an oily substance. The oily substance was subjected to column chromatography (Wako-gel C-200) with use of benzene to isolate 4.3 g of the disired product having a refraction index of nD28 1.6160 as an orange oily substance. NMR spectrum (in deutero chloroform); 6 value (ppm): 1.0 (t, 3H, -SCH2CH2CH3) 1.1 # 1.5 (6H, -N-(CH2CH3)2) 1.7 (m, 2H, -SCH2CH2CH3) 3.1 (t, 2H, -SC112CH2CH3) 3.2 X 4.0 (4H, -N-(CH2CH3)2) 7.5 (5H, EMI20.1 Synthesis 2. Synthesis of N,N-diethyl-N'-benzyldithiocarboxybenzamidine (Compound No. 8) To a mixture of 5 g (0.028 mol) of N,N-diethylbenzamidine and 2.3 g (b.030 mol) of carbon disulfide was added 40 mQ of water, and 5 mA of aqueous solution containing 1.3 g (0.032 mol) of sodium hydroxide was then added dropwise slowly thereto under ice cooling with vigorous stirring. After stirring for one hour, 4.9 g (0.028 mol) of benzylbromide was added dropwise and stirring was further continued for one hour and half. The resultant reaction mixture was extracted with 60 mD of chloroform and the extract was neutralized with 2N hydrochloric acid, washed with water and dried over anhydrous sodium sulfate. Chloroform was removed from the extract under reduced pressure to give an oily substance. The oily substance was subjected to column chromatography (Wako-gel C-200) with use of benzene to isolate 27 the desired product having a refraction index of nd 1.6540 as an orange oily substance. NITER spectrum (in deutero chloroform); 6 value (ppm): 1.0 # 1.6 (6H, -N-(CH2CH3)2) 3.1 X 3.9 (4H, -N-(CH2CH3)2) 4.4 (S, 2H, EMI21.1 7.2#7.7 (10H, EMI21.2 Synthesis 3. Synthesis of nickel bis(N,N-diethyl benzamidine-N1-carbodithioate) (Compound No. 10) To an aqueous solution containing 2.1 g (0.05 mol) of sodium hydroxide dissolved in 3.2 mA of water was added 8.8 g (0.05 mol) of N,N-diethylbenzamidine, and 4.6 g (0.06 mol) of carbon disulfide was added dropwise thereto under room temperature with vigorous stirring, keep- ing the reaction temperature at 400C or lower. Crystals deposited after about 30 minutes were filtered with suction and the obtained crystal residue was washed twice with 30 mQ portions of ethyl ether to give 11.8 g of sodium N,N-diethylbenzamidino-N'-dithioate as an yellow crystal. After dissolving 11.8 g (0.043 mol) of the thus obtained crystal in 200 mQ of water, was added 50 mS of an aqueous solution containing 5.6 g (0.022 mol) of nickel sulfate hexahydrate under room temperature with stirring. Deposited. crystals were combined, washed with water and dried at 800C under reduced pressure to give 9.3 g of the desired product having a decomposition temperature of 184 to 1890C as a common brick colored powdery crystal. Elemental analysis (for C12H 30N4S4Ni); H(%) C(%) N(%) S(%) Ni(%) Calculated: 5 39 51.34 9.98 22.8 10.4 Found: 5.28 49.84 9.63 21.4 10.8 Synthesis 4. Synthesis of zinc bis(N,N-diethylbenzamidino-N' -carbodithioate) (Compound No. 11) After dissolving 2.1 g (0.05 mol) of sodium hydroxide in 3.2 mG of water, 8.8 g (0.05 mol) of N,N-diethylbenz- amidine was added thereto and then 4.6 g (0.06 mol) of carbon disulfide was further added dropwise under room temperature with vigorous-stirring, keeping the reaction temperature at 400C or lower. Crystals deposited after 40 minutes were filtered with suction and washed twice with 30 mQ portions of ethyl ether after removing water thoroughly to give 12.1 g of sodium N,N-diethylbenzamidino-N'-dithioate as an yellow crystal. After dissolving 12.1 g (0.045 mol) of the thus obtained crystal in 200 mL of water, 50 mt of an aqueous solution containing 6.3 g (0.022 mol) of zinc sulfate heptahydrate was added dropwise thereto. Deposited crystals were combined, washed with water sufficiently and dried at 500C under reduced pressure to give 9.6 g of the desired product having a melting point of 96 to 980C as an yellow powdery crystal. Elemental analysis (for C24H30N4S4Zn); H(%) C(%) N(%) S(%) Zn(%) Calculated: 5.32 50.73 9.86 22.5 11.5 Found: 5.20 50.28 9.64 22.3 11.7 Synthesis 5. Synthesis of N,N-die'thyl-N1-phenylthio- carboxybenzamidine (Compound No. 23) To a mixture of 6 g (0.035 mol) of N,N-diethylbenzamidine and 4.0 g (0.039 mol) of triethylamine was added 150 mQ of toluene, and 30 mQ of a toluene solution containing 6.0 g (0.035 mol) of S-phenyl chlorothioformate was then added dropwise slowly thereto under cooling. The resultant reaction mixture was stirred for 30 minutes, allowed to rise to room-temperature and stirred-further for one hour. After completion of the reaction, cold water was added and the formed salt was dissolved and removed. The toluene phase of the thus obtained reaction mixture was subjected to treatment with 2N aqueous hydrochloric acid solution, followed by washing with water until the reaction mixture became neutral. After the toluene phase was dried over anhydrous magnesium sulfate, the solvent was removed to give a crude crystal. The thus obtained crude crystal was recrystallized from a mixture solvent of ethanol and--water to give 7.2 g of the desired product having a melting point of 63 to 650C as a colorless needle crystal. Elemental analysis (for C18E20ONzS); H(%) C(%) N(%) Calculated: 6.45 69.19 8.97 Found: 6.48 69.28 8.98 Synthesis 6. Synthesis of N,N-diethyl-N'-(p- bromophenyl) thiocarboxybenzamidine (Compound No. 32) To a mixture of 7.4 g (0.042 mol) of N,N-diethylbenzamidine and 4.7 g (0.046 mol) of triethylamine was added 180 mQ of benzene, and 50 mQ of a benzene solution con taining- lQ.5-g- (0.042 mol) of S-(p-bromophenyl)chloro- thioformate was then added dropwise thereto under ice cooling. The resultant reaction mixture was stirred for 40 minutes and further stirred at room temperature for 2 hours to complete the reaction. After dissolving and removing deposited salts with water, the mixture was treated with 2N hydrochloric acid. Then the benzene phase of the mixture was washed with water for neutralization, dried over anhydrous sodium sulfate and the solvent was removed to give a colorless crude crystal. The thus obtained crystal was recrystallized from a mixture solvent of ethyl ether and petroleum ether to give 10.0 g of the desired product having a melting point of 82 to 840C as a colorless needle crystal. Elemental analysis (for C18H19ON2SBr); H(%) C(%) N(%) Calvulated: 4.89 55.26 7.16 Found: 4.87 55.01 7.18 Synthesis 7. Synthesis of N,N-diethyl-N'-(p-tertbutylphenyl)thiocarboxybenzamidine (Compound No. 31) Into 200 mQ of toluene was dissolved a mixture of 12.7 g (0.072 mol) of N,N-diethylbenzamidine and 8.1 g (0.079 mol) of triethylamine, and 50 mR of a toluene solution containing 16.4 g (0.072 mol) of S-(p-tert-butylphenyl)- chlorothioformate was then added dropwise thereto under cooling. The resultant reaction mixture was stirred for 45 minutes, allowed to rise to room temperature and further stirred for 1.5 hours. Salts deposited with cold water were dissolved and removed, then the mixture was treated with 2N aqueous hydrochloric acid solution, followed by washing with water until the mixture became neutral. After the toluene phase of the mixture was dried over anhydrous magnesium sulfate, the solvent was removed on an evaporator to give an oily substance. The thus obtained oily substance was subjected to column chromatography (Wako-gel C-300) with use of a mixture solvent of 1 : 10 ethyIacetate-n-hexane (by volume ratio) to isolate 10.3 g of the desired product having a refraction index of nd18 1 5885 as an yellow viscous oily substance. d , Elemental analysis (for C22H280N2S); E ( %) C (%) N(%) Calculated: 7.66 71.70 7.60 Found: 7.58 71.26 7.17 Synthesis 8. Synthesis of N,N-diethyl-N'-benzylthio- carboxybenzamidine (Compound No. 41) To a mixture of 8.1 g (0.046 mol) of N,N-diethylbenzamidine and 5.1 g (0.05 mol) of triethylamine was added 150 mQ of toluene, and 10.0 g (0.046 mol) of S-benzyl chlorothioformate dissolved in 30 mi of toluene was then added dropwise slowly through a dropping funnel under cooling. During the addition, the reaction mixture was stirred vigorously. Stirring was continued for 3 hours after completion of addition and the reaction mixture was allowed to rise to room temperature and further stirred for one hour. After completion of reaction, deposited salts were filtered and removed, and the toluene phase of the filtrate was treated with 2N aqueous hydrochloric acid solution, followed by washing with water for neutralization. After the toluene phase was dried over anhydrous magnesium sulfate, the solvent was removed on an evaporator to deposit a crystal. The thus obtained crystal was recrystallized from a mixture solvent of ethyl ether and petroleum benzine and allowed to stand in a refrigerator overnight to give 12.8 g of the desired product having a melting point of 50 to 520C as a colorless prismatic crystal. Elemental analysis (for C19H22ON2S); H(%) C(%) N(%) Calculated: 6 79 69.90 8.58 Found: 6.88 70.04 8.52 Synthesis 9. Synthesis of N,N-diethyl-N1-benzylthio- carboxy-o-chlorobenzamidine (Compound No. 51) Into 200 mQ of toluene was dissolved a mixture of 6.1 g (0.031 mol) of trichloromethyl chloroformate and 5.5 g (0.044 mol) of benzyl mercaptan, and 12.4 g (0.123 mol) of triethylamine was then added dropwise thereto under ice cooling over 20 minutes. The reaction mixture was stirred for 2 hours to synthesize S-benzyl chlorothioformate. To the resultant reaction mixture was added dropwise 11.2 g (0.053 mol) of N,N-diethyl-o-chlorobenzamidine, then the mixture was stirred for one hour and allowed to stand at room temperature overnight. After the organic phase of the mixture was washed with water, 2N hydrochloric acid and water in turn and dried over anhydrous magnesium sulfate, the solvent was removed to give an oily liquid. The thus obtained oily liquid was subjected to column chromatography (Wako-gel C-300) with use of a mixture solvent of 15 : 1 toluene-ethyl acetate (by volume ratio) to isolate 4.7 g of the desired product having a refraction index of nd16 1.5921 as an orange oily substance. Elemental analysis (for ClgH2lON2SCQ), H(%) C(%) N ¯ Calculated: 5.87 63.23 7.76 Found: 6.54 62.98 7.42 When the benzamidine group compound according to this invention is to be applied as agricultural fungicides, the compound may be formulated for use to the preparations commonly employed as an agricultural fungicide, for example, dusts, granules, fine granules, wettable powders, emulsifiable concentrates, tablets, oily agents aerosol, fumigants and so on, with admixture of an inert solid carrier, inert liquid carrier or emulsifying dispersant. As the inert carrier, there may be mentioned, for example, talc, clay, kaoline, diatomaceous earth, white carbon, calcium carbonate, potassium chlorate, saltpeter, wood flour, starch, nitrocellulose, gum arabic, vinyl chloride, carbon dioxide, Fleon, propane, butane and so on. The agricultural fungicidal composition of this invention may also optionally be blended with any auxiliary agents for preparation, for example, spreaders, dispersing agents, emulsifying agents and the like as usually done in the art. Moreover, the agricultural fungicidal composition of this invention may also be admixed with herbicides, insecti cides, other agricultural chemicals, fertilizers, eg., urea, ammonium sulfate, ammonium phosphate, potassic fertilizers, soil conditioners and the like. The agricultural fungicidal compositions of this invention which may be formulated into various types of preparations as above, may be applied, for example, in a paddy or upland field at 1-5000 g, preferably 10-1000 g of the active ingredient per 10 ares for pre- or postemergency foliage spraying or soil drenching or spraying onto water to control diseases effectively. The fungicidal composition according to this invention shows excellent effect particularly upon powdery mildew of various field crops even in smaller amounts as compared with commercially available fungicidal compositions. In addition, the fungicidal composition according to this invention also has excellent effect upon such plant diseases as gray mold, anthracnose, blast disease, brown spot, bacterial soft rot, bacterial leaf blight, screlotium disease and canker (VaZsa matri). Furthermore, the fungicidal composition according to this invention shows extremely low phytotoxicity against field crops as well as extremely low toxicity against man and beast. Examples of the preparation of the present agricultural fungicidal composition are given below. All parts are given by weight hereinafter unless otherwise stated. Example 1. Emulsifiable concentrates (1) Twenty parts of N,N-diethyl-N1-methyldithiocarboxy- benzamidine (Compound No. 1), 5 parts of Toxanone (trade name of surfactant from Sanyo Kasei Kogyo K. K.) and 75 parts of xylene were homogeneously blended to give 100 parts of emulsifiable concentrates. (2) Twenty parts of N,N-diethyl-N'-(p-methylphenyl)thiocarboxybenzamidine (Compound No. 24), 5 parts of Toxanone (trade name of surfactant from Sanyo Kasei Kogyo K. K.) and 75 parts of xylene were homogeneously blended to give 100 parts of emulsifiable concentrates. (3) Twenty parts of N,N-diethyl-N1-benzylthiocarboxy- benzamidine (Compound No. 41), 5 parts of Toxanone (trade name of surfactant from Sanyo Kasei Kogyo K. K.) and 75 parts of xylene were homogeneously blended to give 100 parts of emulsifiable concentrates. Example 2. Wettable powders (1) Twenty parts of N,N-diethyl-N'-benzyldithiocarboxybenzamidine (Compound No. 8), one part of Demol EP powder (trade name of surfactant from Kao-Atlas Co., Ltd.), 20 parts of white carbon and 59 parts of the talc were homogeneously blended and pulverized to give 100 parts of wettable powders. (2) Twenty parts of N,N-diethyl-N'-(o-methylphenyl)thiocarboxybenzamidine (Compound No. 27), one part of Demol EP powder (trade name of surfactant from Kao Atlas Co., Ltd.), 20 parts of white carbon and 59 parts of talc were homogeneously blended and pulverized to give 100 parts of wettable powders. (3) Twenty parts of N,N-diethyl-N'-benzylthiocarboxy- o-chlorobenzamidine (Compound No. 51), one part of Demol EP powder (trade name of surfactant from Kao Atlas Co., Ltd.), 20 parts of white carbon and 59 parts of talc were homogeneously blended and pulverized to give 100 parts of wettable powders. Example 3. Dusts (1) Two parts of zinc bis (N,N-diethyl-p-methylbenz- amidino-N'-carbodithioate) (Compound No. 18) and 98 parts of talc were homogeneously blended to give 100 parts of dusts. (2) Two parts of N,N-diethyl-N'-(p-chlorophenyl)thio- carboxybenzamidine (Compound No. 29) and 98 parts of talc were homogeneously blended to give 100 parts of dusts. (3) Two parts of N,N-diethyl-N'- (p-nitrobenzyl) thio- carboxybenzamidine (Compound 54) and 98 parts of talc were homogeneously blended to give 100 parts of dusts. Example 4. Granules or tablets (1) Ten parts of zinc bis (N,N-diethyl-p-chlorobenz amidino-N1-carbodithioate) (Compound No. 22), 15 parts of starch, 72 parts of bentonite and 3 parts of sodium salt of lauryl alcohol sulfate were homogeneously blended and pulverized to give 100 parts of granules or tablets. (2) Ten parts of N,N-diethyl-N'-phenylthiocarboxy-pchlorobenzamidine (Compound No. 36), 15 parts of starch, 72 parts of bentonite and 3 parts of sodium salt of lauryl alcohol sulfate were homogeneously blended and pulverized to give 100 parts of granules or tablets. (3) Ten parts of N,N-di-n-butyl-N'-benzylthiocarboxybenzamidine (Compound No. 60), 15 parts of starch, 2 parts of bentonite and 3 parts of sodium salt of lauryl alcohol sulfate were-homogeneously blended and pulverized to give 100 parts of granules or tablets. Next, the effect of the agricultural fungicidal composition according to this invention will be explained more concretely by way of the following Experiments. The numbers of the test compounds correspond to those exemplified in the above table. Experiment 1 Effect on powdery mildew in cucumber Cucumber seedlings (variety: Sagamihanjiro-fushinari), planted one per 6 cm diameter plastic pot, were used as host plant-sat-the--stage of 15 days after sowing. Each host plant was treated with a diluted emulsifiable concentrate or wettable powder prepared in the same manner as in Example 1 or 2, respectively, and containing 1000 ppm of each of active compounds by spraying at a rate of 20 mQ per pot. After air-drying each host plant was inoculated with Sphaerotheca fuiiginea by spraying its spore suspension uniformly. The spore suspension had been previously prepared by brushing already infected cucumber leaves with a soft brush and letting the microorganism fall onto a petri dish, and diluting the conidia with distilled water to such a concentration that 10 conidia had been observed within the range of an optical microscope at 150 magnifications. The inoculated plant were kept in an air-conditioned and isolated glass greenhouse. Upon the emergence of the disease after about 10 days, the number of diseased spots on the first leaf was measured. The percent efficacy of each of active compounds was calculated according to the following equation. The results are shown in Table 2. EMI32.1 <tb> <SEP> Average <SEP> number <SEP> of <SEP> diseased <tb> <SEP> Percent <SEP> Efficacy <SEP> = <SEP> 1-spots <SEP> in <SEP> treated <SEP> groups <SEP> x <SEP> 100 <tb> Average <SEP> number <SEP> of <SEP> diseased <tb> <SEP> spots <SEP> in <SEP> untreated <SEP> groups <tb> Table 2 EMI33.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <tb> <SEP> 1 <SEP> 100 <SEP> # <SEP> none <tb> <SEP> 2 <SEP> " <SEP> " <tb> <SEP> 3 <SEP> " <SEP> " <tb> <SEP> 4 <SEP> " <SEP> " <tb> <SEP> 5 <SEP> " <SEP> " <tb> <SEP> 6 <SEP> " <SEP> " <tb> <SEP> 7 <SEP> " <SEP> " <tb> <SEP> 8 <SEP> " <SEP> " <tb> <SEP> 9 <SEP> " <SEP> " <tb> <SEP> 10 <SEP> " <SEP> " <tb> <SEP> 11 <SEP> " <SEP> " <tb> <SEP> 12 <SEP> " <SEP> " <tb> <SEP> 13 <SEP> " <SEP> " <tb> <SEP> 14 <SEP> v <SEP> <tb> <SEP> 15 <SEP> " <SEP> " <tb> <SEP> 16 <SEP> g <SEP> I <SEP> <tb> <SEP> 17 <SEP> " <SEP> " <tb> <SEP> 18 <SEP> " <SEP> " <tb> <SEP> 19 <SEP> " <SEP> " <tb> <SEP> 20 <SEP> " <SEP> " <tb> <SEP> 21 <SEP> &num; ; <SEP> x <SEP> <tb> <SEP> 22 <SEP> " <SEP> " <tb> Table 2 (cont'd) EMI34.1 <tb> Test <SEP> Compound <SEP> No. <SEP> Efficacy <SEP> (%) <SEP> Phytotoxicity <tb> <SEP> 23 <SEP> 100 <SEP> none <tb> <SEP> 24 <SEP> " <SEP> " <tb> <SEP> 25 <SEP> " <SEP> " <tb> <SEP> 26 <SEP> " <SEP> " <tb> <SEP> 27 <SEP> " <SEP> " <tb> <SEP> 28 <SEP> " <SEP> " <tb> <SEP> 29 <SEP> " <SEP> " <tb> <SEP> 30 <SEP> " <SEP> " <tb> <SEP> 31 <SEP> " <SEP> " <tb> <SEP> 32 <SEP> " <SEP> " <tb> <SEP> 33 <SEP> " <SEP> " <tb> <SEP> 34 <SEP> " <SEP> " <tb> <SEP> 35 <SEP> " <SEP> " <tb> <SEP> 36 <SEP> " <SEP> " <tb> <SEP> 37 <SEP> " <SEP> " <tb> <SEP> 38 <SEP> " <SEP> " <tb> <SEP> 39 <SEP> " <SEP> " <tb> <SEP> 40 <SEP> " <SEP> " <tb> Table 2 (cont'd) EMI35.1 Test <SEP> Compound <SEP> Efficacy <SEP> (%) <SEP> Phytotoxicity <tb> No. <tb> <SEP> 41 <SEP> # <SEP> 100 <SEP> none <tb> <SEP> 42 <SEP> <SEP> v <SEP> v <SEP> <tb> <SEP> 43 <SEP> " <SEP> " <tb> <SEP> 44 <SEP> t <SEP> <SEP> t <SEP> <tb> <SEP> 45 <SEP> " <SEP> " <tb> <SEP> 46 <SEP> " <SEP> " <tb> <SEP> 47 <SEP> 1 <SEP> 1 <SEP> <tb> <SEP> 48 <SEP> I <SEP> a <SEP> <tb> <SEP> 49 <SEP> " <SEP> " <tb> <SEP> 50 <SEP> " <SEP> " <tb> <SEP> 51 <SEP> " <SEP> " <tb> <SEP> 52 <SEP> <SEP> 1 <SEP> 1 <SEP> <tb> <SEP> 53 <SEP> <SEP> 1 <SEP> 1 <SEP> <tb> <SEP> 51 <SEP> " <SEP> " <tb> <SEP> 55 <SEP> " <SEP> " <tb> <SEP> 56 <SEP> " <SEP> " <tb> <SEP> 57 <SEP> " <SEP> " <tb> <SEP> 58 <SEP> " <SEP> " <tb> <SEP> 59 <SEP> " <SEP> " <tb> <SEP> 60 <SEP> 42 <SEP> I <tb> <SEP> 61 <SEP> " <SEP> " <tb> <SEP> 62 <SEP> " <SEP> " <tb> <SEP> 63 <SEP> " <SEP> " <tb> Experiment 2. Effect on powdery mildew in cucumber at low concentrations Experiments were conducted according to the method in Experiment 1, except that 20 mQ of each of diluted emulsifiable concentrates or wettable powders prepared in the same manner as in Example 1 or 2, respectively, and containing 200 ppm, 100 ppm or 50 ppm of each of active compounds was sprayed per groups. The percent efficacy was calculated according to the same manner as in Experiment 1. The results are shown in Table 3. Table 3 EMI37.1 <tb> <SEP> Efficacy <SEP> (%) <tb> <SEP> Test <SEP> Concentration <SEP> Concentration <SEP> Concentration <tb> Compound <tb> <SEP> Compound <SEP> of <SEP> Active <SEP> of <SEP> Active <SEP> of <SEP> Active <tb> No. <SEP> Of <SEP> Active <SEP> Of <SEP> Active <SEP> Of <SEP> Active <tb> <SEP> Ingredient <SEP> Ingredient <SEP> Ingredient <tb> <SEP> 200 <SEP> ppm <SEP> 100 <SEP> ppm <SEP> 50 <SEP> ppm <tb> <SEP> 1 <SEP> 90 <SEP> 81 <SEP> 60 <tb> <SEP> 2 <SEP> 100 <SEP> 93 <SEP> 82 <tb> <SEP> 3 <SEP> # <SEP> 96 <SEP> 86 <SEP> 65 <tb> <SEP> 4 <SEP> # <SEP> 100 <SEP> 89 <SEP> 65 <tb> <SEP> 5 <SEP> 100 <SEP> 88 <SEP> 60 <tb> <SEP> 6 <SEP> 1 <SEP> 92 <SEP> 88 <SEP> 70 <tb> <SEP> 7 <SEP> 92 <SEP> 86 <SEP> 65 <tb> <SEP> 8 <SEP> 94 <SEP> 84 <SEP> 46 <tb> <SEP> 9 <SEP> # <SEP> 100 <SEP> 88 <SEP> 67 <tb> <SEP> 10 <SEP> 100 <SEP> 100 <SEP> # <SEP> 91 <tb> <SEP> 11 <SEP> 100 <SEP> 100 <SEP> 92 <tb> <SEP> 12 <SEP> 100 <SEP> 98 <SEP> # <SEP> 89 <tb> <SEP> 13 <SEP> 100 <SEP> 96 <SEP> # <SEP> 78 <tb> <SEP> 14 <SEP> 100 <SEP> 100 <SEP> 99 <tb> <SEP> 15 <SEP> 100 <SEP> 97 <SEP> 88 <tb> <SEP> 16 <SEP> 100 <SEP> 100 <SEP> 84 <tb> <SEP> 17 <SEP> 100 <SEP> 100 <SEP> 87 <tb> <SEP> 18 <SEP> 100 <SEP> 100 <SEP> 61 <tb> <SEP> 19 <SEP> 100 <SEP> 100 <SEP> 84 <tb> <SEP> 20 <SEP> 100 <SEP> # <SEP> <SEP> 98 <SEP> 83 <tb> <SEP> 21 <SEP> 100 <SEP> 100 <SEP> 83 <tb> <SEP> 22 <SEP> # <SEP> 100 <SEP> 92 <SEP> 68 <tb> Table 3 (cont'd) EMI38.1 <tb> <SEP> Rfficacy <SEP> (%) <tb> <SEP> Test <SEP> Concentration <SEP> Concentration <SEP> Concentration <tb> Compound <SEP> of <SEP> Active <SEP> of <SEP> Active <SEP> . <SEP> of <SEP> Active <tb> <SEP> No. <SEP> Ingredient <SEP> Ingredient <SEP> Ingredient <tb> <SEP> 200 <SEP> ppm <SEP> 100 <SEP> ppm <SEP> 50ppm <tb> <SEP> 23 <SEP> 100 <SEP> 100 <SEP> 00 <tb> <SEP> 24 <SEP> J <SEP> 96 <SEP> 84 <tb> <SEP> 25 <SEP> 1 <SEP> 94 <SEP> <SEP> J <SEP> <tb> <SEP> 26 <SEP> v <SEP> 100 <SEP> 93 <tb> <SEP> 27 <SEP> " <SEP> " <SEP> 97 <tb> <SEP> 28 <SEP> " <SEP> " <SEP> 100 <tb> <SEP> 29 <SEP> " <SEP> 98 <SEP> 87 <tb> <SEP> 30 <SEP> X <SEP> <SEP> 100 <SEP> 95 <tb> <SEP> 31 <SEP> " <SEP> 98 <SEP> 86 <tb> <SEP> 32 <SEP> X <SEP> <SEP> 100 <SEP> 99 <tb> <SEP> 33 <SEP> w <SEP> <SEP> x <SEP> <SEP> 100 <tb> <SEP> 34 <SEP> x <SEP> x <SEP> <SEP> 99 <tb> <SEP> 35 <SEP> <RTI ID=38.9> w <SEP> " <SEP> 96 <tb> <SEP> 36 <SEP> " <SEP> 95 <SEP> 87 <tb> <SEP> 37 <SEP> <SEP> <SEP> 100 <SEP> 100 <tb> <SEP> 38 <SEP> " <SEP> " <SEP> " <tb> <SEP> 39 <SEP> 94 <SEP> 78 <SEP> 52 <tb> <SEP> 40 <SEP> # <SEP> 86 <SEP> - <SEP> <SEP> 60 <SEP> 41 <tb> Table 3 (cont'd) EMI39.1 <tb> <SEP> Test <SEP> Concentration <SEP> Concentration <SEP> Concentration <tb> Compound <SEP> of <SEP> Active <SEP> of <SEP> Active <SEP> of <SEP> Active <tb> <SEP> No. <SEP> Ingredient <SEP> Ingredient <SEP> Ingredient <tb> <SEP> 00 <SEP> ppm <SEP> 100 <SEP> ppm <SEP> 50 <SEP> ppm <tb> <SEP> 41 <SEP> 100 <SEP> 100 <SEP> 98 <tb> <SEP> 42 <SEP> " <SEP> " <SEP> 100 <tb> <SEP> 43 <SEP> " <SEP> " <SEP> " <tb> <SEP> 44 <SEP> " <SEP> " <SEP> " <tb> <SEP> 45 <SEP> 5 <SEP> 9 <SEP> 98 <SEP> <tb> <SEP> 46 <SEP> " <SEP> " <SEP> 83 <tb> <SEP> 47 <SEP> " <SEP> <SEP> 98 <SEP> 79 <tb> <SEP> 48 <SEP> " <SEP> <SEP> 80 <SEP> 70 <tb> <SEP> 49 <SEP> " <SEP> 100 <SEP> 100 <tb> <SEP> 50 <SEP> w <SEP> 96 <SEP> 72 <tb> <SEP> 51 <SEP> " <SEP> 100 <SEP> 100 <tb> <SEP> 52 <SEP> 1 <SEP> 98 <SEP> 80 <tb> <SEP> 53 <SEP> " <SEP> 96 <SEP> 70 <tb> <SEP> 54 <SEP> " <SEP> 71 <SEP> 52 <tb> <SEP> 55 <SEP> 1 <SEP> # <SEP> <SEP> 78 <SEP> 62 <tb> <SEP> 56 <SEP> , <SEP> <SEP> 100 <SEP> 92 <SEP> <tb> <SEP> 63 <SEP> " <SEP> " <SEP> 98 <tb> Control* <SEP> 86 <SEP> 41 <SEP> 23 <tb> *: N,N-diethyl-N'-ethylthiocarboxybenzamidine Experiment 3. Effect on canker in apple Apple tree (variety: Fuji) was used as host plants. Branches at the stage of one year after germination having a length of 7 cm which had been cut from the apple tree were immersed for 10 minutes in a diluted emulsifiable concentrate or wettable powder prepared in the same manner as in Example 1 or 2, respectively, and containing 1000 ppm of each of active compounds. After air-drying, the branch bark having a diameter of 5 mm was punched at the central portion thereof with a heated cork borer and the thus punched portion of the branch was-inoculated with a spore suspension of VaDsa mali which had been previously cultivated on a PDA medium (spore concentration: 5 x 106/ml). After inoculation, the host plants were kept at a temperature of 250C and a relative humidity of 70 % for 10 days. The number of diseased spots emerged was culculated and the percent efficacy of each of active compounds was calculated according to the same manner as in Experiment 1. The results are shown in Table 4. Table 4 EMI41.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <tb> <SEP> 1 <SEP> 52 <SEP> none <tb> <SEP> 7 <SEP> 60 <tb> <SEP> 8 <SEP> 64 <SEP> K <SEP> <tb> <SEP> 9 <SEP> 60 <SEP> K <SEP> <tb> <SEP> 10 <SEP> 58 <SEP> " <tb> <SEP> 11 <SEP> 50 <SEP> " <tb> <SEP> 12 <SEP> 52 <SEP> " <tb> <SEP> 41 <SEP> 56 <SEP> n <SEP> <tb> <SEP> 42 <SEP> 61 <SEP> " <tb> <SEP> 43 <SEP> 52 <tb> <SEP> 45 <SEP> 70 <SEP> <SEP> w <SEP> <tb> <SEP> 51 <SEP> 56 <SEP> " <tb> <SEP> 54 <SEP> 64 <SEP> " <tb> <SEP> Control <SEP> * <SEP> 50 <SEP> 1 <SEP> <tb> *: Topsin M; 1,2-bis(3-methoxycarbonyl-2 thioureido) benzene. Experiment 4. Effect on powdery mildew in Tobacco Tobacco seedlings (variety: MC-1), planted one per 12 cm diameter unglazed pot, were used as host plants at the stage of 4 to 5 leaves. Each host plant was treated with a diluted emulsifiable concentrates or wettable powders prepared in the same manner as in Example 1 or 2, respectively, and containing 500 ppm of each of active compounds by spraying at a rate of 50 mQ per pot After air-drying, each host plant was inoculated with Erysiphe cichoracearum by spraying its spore suspension uniformly. The spore suspension had been previously prepared in the same manner as in Experiment 1. The inoculated plants were kept at 250C in an airconditioned and isolated greenhouse. Upon the emergence of the disease after about 14 days, the number of diseased spots on the leaves was counted and the percent efficacy was calculated according to the same manner as in Experiment 1. The results are shown in Table 5. Table 5 EMI43.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytitixicity <tb> <SEP> No. <SEP> (%) <tb> <SEP> 1 <SEP> # <SEP> 100 <SEP> none <tb> <SEP> 2 <SEP> 100 <SEP> " <tb> <SEP> 3 <SEP> 98 <SEP> 1 <tb> <SEP> 4 <SEP> 100 <SEP> a <SEP> <tb> <SEP> 5 <SEP> 100 <SEP> " <tb> <SEP> 6 <SEP> 100 <SEP> X <SEP> <tb> <SEP> 7 <SEP> 100 <SEP> a <SEP> <tb> <SEP> 8 <SEP> 100 <SEP> " <tb> <SEP> 9 <SEP> 96 <SEP> " <tb> <SEP> 10 <SEP> 100 <SEP> " <tb> <SEP> 11 <SEP> 100 <SEP> " <tb> <SEP> 12 <SEP> 100 <SEP> K <SEP> <tb> <SEP> 13 <SEP> 100 <SEP> <SEP> 1 <SEP> <tb> <SEP> 14 <SEP> 100 <SEP> <SEP> <SEP> <tb> <SEP> 15 <SEP> 100 <SEP> " <tb> <SEP> 16 <SEP> 100 <SEP> 1 <tb> <SEP> 17 <SEP> 98 <SEP> " <tb> <SEP> 18 <SEP> 95 <SEP> <SEP> 1 <SEP> <tb> <SEP> 19 <SEP> 100 <SEP> 1 <tb> <SEP> 20 <SEP> # <SEP> 100 <SEP> v <SEP> <tb> <SEP> 21 <SEP> 100 <SEP> v <SEP> <tb> <SEP> 22 <SEP> 100 <tb> Table 5 (cont'd) EMI44.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <SEP> <tb> <SEP> 23 <SEP> 100 <SEP> none <tb> <SEP> 24 <SEP> " <SEP> " <tb> <SEP> 25 <SEP> " <SEP> " <tb> <SEP> 26 <SEP> " <SEP> " <tb> <SEP> 27 <SEP> " <SEP> " <tb> <SEP> 28 <SEP> " <SEP> " <tb> <SEP> 29 <SEP> " <SEP> " <tb> <SEP> 30 <SEP> " <SEP> " <tb> <SEP> 31 <SEP> " <SEP> " <tb> <SEP> 32 <SEP> " <SEP> " <tb> <SEP> 33 <SEP> 1 <SEP> 1 <SEP> <tb> <SEP> 34 <SEP> " <SEP> " <tb> <SEP> 35 <SEP> " <SEP> " <tb> <SEP> 36 <SEP> " <SEP> " <tb> <SEP> 37 <SEP> " <SEP> " <tb> <SEP> 38 <SEP> " <SEP> " <tb> <SEP> 39 <SEP> 90 <SEP> r <SEP> <tb> <SEP> 40 <SEP> 88 <SEP> " <tb> Table 5 (cont'd) EMI45.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <SEP> Phytotoxicity <tb> <SEP> 41 <SEP> 100 <SEP> none <tb> <SEP> 42 <SEP> " <SEP> " <tb> <SEP> 43 <SEP> " <SEP> " <tb> <SEP> 44 <SEP> " <SEP> " <tb> <SEP> 45 <SEP> " <SEP> " <tb> <SEP> 46 <SEP> " <SEP> " <tb> <SEP> 47 <SEP> " <SEP> " <tb> <SEP> 48 <SEP> " <SEP> " <tb> <SEP> 49 <SEP> " <SEP> " <tb> <SEP> 50 <SEP> " <SEP> " <tb> <SEP> 51 <SEP> a <SEP> <SEP> I <SEP> <tb> <SEP> 52 <SEP> ' <SEP> I <SEP> I <tb> <SEP> 53 <SEP> " <SEP> " <tb> <SEP> 54 <SEP> " <SEP> " <tb> <SEP> 55 <SEP> " <SEP> " <tb> <SEP> 56 <SEP> " <SEP> " <tb> <SEP> 57 <SEP> 70 <SEP> I <SEP> <tb> <SEP> 58 <SEP> 68 <SEP> v <SEP> <tb> <SEP> 59 <SEP> 80 <SEP> " <tb> <SEP> 60 <SEP> 65 <SEP> I <tb> <SEP> 61 <SEP> 90 <SEP> t <SEP> <tb> <SEP> 62 <SEP> 50 <SEP> s <SEP> <tb> <SEP> 63 <SEP> 100 <SEP> <SEP> s <SEP> <tb> Experiment 5. Effect on sheath blight in rice plant Rice seeds (variety: Nihonbare) were sown, 10 to the pot, in a series of 6 cm diameter plastic pots and grown to the 4 to 5 leaf stage. A diluted emulsifiable concentrate or wettable powder prepared in the same manner as in Example 1 or 2, respectively, and containing 500 ppm of each of active compounds by spraying at a rate of 20 mQ per pot. After air-drying, each host plant was inoculated with the inoculum. The inoculum had been previously prepared by cultivating Pellicularia sasaki on a ban medium for about 14 days, inoculating the inoculum diluted with unhulled rice at the portion adjacent the ground and kept in a conditioned inoculation chamber (a temperature of 250C and a relative humidity of 80 %) to emerge the disease. Seven to ten days after inoculation, diseased spots emerged on leaves was measured to calculate the number of leaves (nl n7) at various degree of disease according to the following evaluation standard. O: no infection observed (number of leaves: n1) 1: slight infection observed (number of leaves: 2: diseased spots of less than (number of leaves: n3) 1 cm observed 3: diseased spots-of less than (number of leaves: n) 2 cm observed 4: diseased spots of less than (number of leaves: n5) 5 cm observed 5: diseased spots of less than (number of leaves: n6) 10 cm observed 6: diseased spots of more (number of leaves: n7) than 10 cm observed The percent efficacy of each of active compounds was calculated, based on the above observation, according to the following equation. The result are shown in Table 6. Percent Efficacy = {1 - treated groups (0 x n1 + 1 x untreated groups 0 x n1 + 1 x n2 + 2 x n3 + 3 x n4 + 4 x n5 + 5 x n6 + 6 x n7} x 100 n2 + 2 x n3 + 3 x n4 + 4 x n5 + 5 x n6 + 6 x n7 Table 6 EMI47.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <tb> <SEP> 42 <SEP> 90 <SEP> none <tb> <SEP> 45 <SEP> 87 <SEP> " <tb> <SEP> 51 <SEP> 100 <SEP> " <tb> <SEP> 53 <SEP> 95 <SEP> " <tb> <SEP> 54 <SEP> 89 <SEP> " <tb> <SEP> 56 <SEP> 90 <SEP> " <tb> Experiment 6. Effect on brown spot in rice plant (Helminthosporium leaf spot) Rice seeds (variety: Nihonbare) were sown, 10 to the pot, in 6 cm diameter plastic pots and grown to the 4 to 5 leaf stage. Each host plants was treated-with a diluted emulsifiable concentrate or wettable powder each prepared in the same manner as in Example 1 or 2, respectively, and containing 500 ppm of an active compound, at a rate t"' 20 mQ per pot. After air-drying, the host plants were inoculated with Cochliobolue miyabeanus which had been cultivated in a rice straw extract medium at 280C for 10 days and adjusted to such a concentration that 10-- 15 conidia had been observed within the range of an optical microscope at 150-magnifications. The inoculated plants were kept at 270C, more than 95 % relative humidity in an inoculation chamber for two days. The number of diseased spots appeared on the upper two leaves was measured and the efficacy of each of active compounds was calculated according to the similar method as in Experiment 1. The results are shown in Table 7. Table 7 EMI49.1 <tb> Test <SEP> Compound <SEP> Efficacy <SEP> Phytotoxicity <tb> <SEP> No. <SEP> (%) <tb> <SEP> 41 <SEP> 75 <SEP> none <tb> <SEP> 43 <SEP> 89 <SEP> " <tb> <SEP> 45 <SEP> # <SEP> 80 <SEP> <SEP> <tb> <SEP> 47 <SEP> 92 <SEP> " <tb> <SEP> 49 <SEP> # <SEP> 87 <SEP> K <SEP> <tb> <SEP> 51 <SEP> 98 <SEP> <SEP> J <SEP> <tb> <SEP> 76 <SEP> " <tb>

Claims: Claims: 1. A benzamidine group compound represented by the general formula (I): EMI50.1 wherein R represents a lower alkyl group; X represents a halogen atom or a lower alkyl group; m represents an -integer--of 0,1 or 2; Z represents an oxygen atom or a sulfur atom; n represents an integer of 1 or 2; when n is 1, M represents a lower alkyl group, a lower alkyl group, a phenyl group of the formula EMI50.2 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and l represents an integer of 0, 1, 2 or 3) or a benzyl group of the formula EMI50.3 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and l represents an integer of 0, 1, 2 or 3); and when n is 2, M represents a metal selected from the group consisting of nickel, cobalt and zinc. 2. The benzamidine group compound according to Claim 1, wherein said compound is represented by the general formula (II): EMI50.4 wherein X, m and n have the same meanings as defined in Claim 1, and when n is 1, M represents a lower alkyl group, slower alkenyl group, a benzyl group or a halogenated benzyl group, and when n is 2, M has the same meaning as defined in Claim 1. 3. The benzamidine group compound according to Claim 2, wherein said lower alkyl group represented by X or M has 1 to 4 carbon atoms;said halogen atom represented by X or Y on the benzyl group of the formula EMI51.1 represented by M is chlorine, bromine, fluorine or iodine; and said lower alkenyl group represented by M has 3 to 5 carbon atoms. 4. The benzamidine group compound according to Claim 3 wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl-N'-n-propyldithiocarboxybenzamidine, (2) N,N-diethyl-N'-benzyldithiocarboxy- benzamidine, (3) Nickel bis (N,N-diethylbenzamidino-N carbodithioate), (4) Zinc bis(N,N-diethy1benzamidino-N' - carbodithioate) and (5) Cobalt bis(N,N-diethylbenzamidino N'-carbodithioate). 5. The benzamidine group compound according to Claim 1, wherein said compound is represented by the general formula (III): EMI51.2 wherein R, X, m and Q have the same meanings as defined in Claim 1, and Y represents a lower alkyl group or a halogen atom. 6. The benzamidine group compound according to Claim 5 wherein said lower alkyl group represented by R, X or Y has 1 to 4 carbon atoms; and said halogen atom represented by X or Y is chlorine, bromine, fluorine or iodine. 7. The benzamidine group compound according to Claim 6, wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl-N'-phenylthio- carboxybenzamidine, (2) N,N-diethyl-N'-(p-bromophenyl) thiocarboxybenzamidine and (3) N,N-diethyl-N'-(p-tertbutylphenyl)thiocarboxybenzamidine. -8. The benzamidine group compound according to Claim 1, wherein said compound is represented by the general formula (IV): EMI52.1 wherein R, X, m and Y have the same meanings as -defined in Claim 1, and Q represents an integer of 0, 1 or 2. 9. The benzamidine group compound according to Claim 8 wherein said lower alkyl group represented by R, X or Y has 1 to 4 carbon atoms; said halogen atom represented by X or Y is chlorine, bromine fluorine or iodine; and said lower alkoxy group represented by Y has 1 to 4 carbon atoms. 10. The benzamidine group compound according to Claim 9 wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl-Nl-benzylthio- carboxybenzamidine and (2) N,N-diethyl-N'-benzylthio- carboxy-o-chlorobenzamidine. 11; An agricultural fungicidal composition which comprises as an active ingredient, a benzamidine group compound represented by the general formula (I): EMI53.1 wherein R represents a lower alkyl group; X represents a halogen atom or a lower alkyl group; m represents an integer of 0, 1 or 2; Z represents an oxygen atom or a sulfur atom; n represents an integer of 1 or 2; when n is 1, M represents a lower alkyl group, a lower alkenyl group, a phenyl group of the formula EMI53.2 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and Q represents an integer of 0, 1, 2 or 3) or a benzyl group of the formula EMI53.3 (in which Y represents a lower alkyl group, a halogen atom, a lower alkoxy group or a nitro group and Q represents an integer of 0, 1, 2 or 3); and when n is 2, M represents a metal selected from the group consisting of nickel, cobalt and zinc. 12. The agricultural fungicidal composition according to Claim 11, wherein said compound is represented by the general formula (II): EMI54.1 wherein X, m and n, have the same meanings as defined in Claim 11, and when n is 1, M represents a lower alkyl group, a lower alkenyl group, a benzyl group or a halogenated benzyl group and when n is 2, M has the same meaning as defined in Claim 11. 13. The agricultural fungicidal composition according to Claim 12, wherein said lower alkyl group represented by X or M has 1 to 4 carbon atoms; said halogen atom represented by X or Y on the benzyl group of the formula EMI54.2 represented by M is chlorine, bromine, fluorine or iodine; and said lower alkenyl group represented by M has 3 to 5 carbon atoms. 14. The agricultural fungicidal composition according to Claim 13, wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl N' -n-propyldithiocarboxybenzamidine, (2) N,N-diethyl-N' benzyldithiocarboxybenzamidine, (3) Nickel bis(N,N- diethylbenzamidino-N '-carbodithioate), (4) Zinc bis (N,N diethylbenzamidino-N'-carbodithioate) and (5) Cobalt bis (N, N-diethylbenzamidino-N' -carbodithioate). 15. The agricultural fungicidal composition according to Claim 11, wherein said compound is represented by the general formula (III): EMI55.1 wherein R, X, m and Q have the same meanings as defined in Claim 11, and Y represents a lower alkyl group or a halogen atom. 16. The agricultural fungicidal composition according to Claim 15, wherein said lower alkyl group represented by R, X or Y has 1 to 4 carbon atoms; and said halogen atom represented by X or Y is chlorine, bromine, fluorine or iodine. 17. The agricultural fungicidal composition according to Claim 16, wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl N'-phenylthiocarboxybenzamidine, (2) N,N-diethyl-N1 (p-bromophenyl) thiocarboxybenzamidine and (3) N,N diethyl-N' - (p-tert-butylphenyl) thiocarboxybenzamidine. 18. The agricultural fungicidal composition according to Claim 11, wherein said compound is represented by the general formula (IV): EMI55.2 wherein R, X, m and Y have the same meanings as defined in Claim 11, and Q represents an integer of 0, 1 or 2. 19. The agricultural fungicidal composition according to Claim 18, wherein said lower alkyl group represented by R, X or Y has 1 to 4 carbon atoms; said halogen atom represented by X or Y is chlorine, bromine fluorine or iodine; and said lower alkoxy group represented by Y has 1 to 4 carbon atoms. 20. The agricultural fungicidal composition according to Claim 19, wherein said benzamidine group compound is selected from the group consisting of (1) N,N-diethyl N'-benzylthiocarboxybenzamidine and (2) N,N-diethyl-N'benzylthiocarboxy-o-chlorobenzamidine.

Inventors: IIDA, SEIJI C/O CENTRAL RESEARCH LABORATORIES, NAGAI, HIROFUMI C/O CENTRAL RESEARCH LABORATORIES, YORIE, TAKASHI C/O CENTRAL RESEARCH LABORATORIES
Applicants: UBE INDUSTRIES, LTD.
Application year: 1983
Main classification: C07C155
IPC codes: C07C333