BIS(BETA-PENTABROMOPHENOXYETHYL) SUCCINATE, A FLAME RETARDANT FOR ABS

Abstract: The di-ester of beta-pentabromophenoxyethanol and succinic acid, bis(beta-pentabromophenoxyethyl) succinate, is prepared by mono-ethoxylating pentabromophenol with ethylene oxide, then esterifying the resulting pentabro­ mophenoxyethanol with succinic acid. The di-ester is a flame retardant for ABS.

Description: BIS (BETA-PENTABROMOPHENOXYETHYL) SUCCINATE, -A FLAME RETARDANT FOR ABS Description This invention is directed to bis(beta-pentabrcmo- phenoxyethyl) succinate and to a method for its prepara- tion. The compound is particularly useful as a flame retardant for ABS. Highly brominated compounds such as the tetrabromo- phenyl ethers and perbrominated biphenyl compounds are well-known flame retard ants for a variety of thermoplastic resins. Although the flame retarding behavior of such compounds is adequate for many materials the tendency to migrate and to be exuded from the resin during processing, particularly where the compounds are employed at high concentrations in the resin, are distinct disadvantages. Methods in the art for overco- ing the tendency of flame retardants to migrate during processing have included incorporating the brominated moiety into a polymeric structure, such as by grafting a bromine-containing molecule onto an existing substrate, by directly brominating the substrate or by copolymerizing a suitable bromine-containing monomer in the preparation of the thermoplastic. As an alternative, flame retardant molecules have been sought which possess an appropriate combination of solubility in the thermoplastic resin, adequate stability at resin processing temperatures, and sufficient ability to retard burying without resort to an inordinately high concentration in the resin. As will be appreciated by those skilled in the art, the great proliferation of compounds available for use as flame retardants has come about in part because no single compound possesses a balance of these characteristics that is adequate for use in every thermoplastic resin. Most flame retardant compounds are known to be useful in a very limited class of thermoplastic resins, and the search for compounds having more effective balance of characteristics continues. This invention is directed to a new flame retardant for ABS resins, and more particularly to bis(beta-pentabromophenoxyethyl) succinate, a compound having the following structure: EMI2.1 This compound, a di-pentabromophenoxyethyl ester of succinic acid, is thermally stable at temperatures well above the bçxzatures employed for melt processing ABS resins, is readily dispersible for maximum effectiveness in flame retardance, and has a lower tendency to migrate due to its high molecular weight and solubility in the resin. The flame retardant compound of this invention is the di-ester of beta-pentabromophenoxyethanol and succinic acid, bis (beta-pentabromophenoxyethyl) succinate. It may be prepared by the ethoxylation of pentabromophenol a commercially available compound, with ethylene oxide to provide beta-pentabromophenoxyethanol. The ester is prepared by esterifying two moles of the beta-pentabromophenoxyethanol with succinic anhydride. Di-esters of pentabromophenoxyethanol are unknown in the art. The corresponding succinate of pentachlorophenoxyethanol is disclosed in U. S. 3,123,580 as a plasticizer for PVC and polystyrene, however the synthesis disclosed is arduous and has not been applied or suggested for preparation of the compound of the instant invention. ABS resins are flame retarded when compounded with bis(beta-pentabromophenoxyethyl) succinate. The compound of this invention is somewhat more effective than many brominated compounds, imparting self-extinguishing characteristics to ABS resins at reduced concentrations. When compunded with a conventional synergist such as antimony oxide, substantial flame retardance results when as little as 10 wt% of the brominated compound of this invention is present, and amounts above about 12 wt% are effective in providing self-extinguishing compositions. Conventional brominated flame retardants will be employed in larger amounts, and frequently amounts as great as 25 wt%, are needed to provide self-extinguishing compositions. The ABS resins that are usefully flame retarded by the compound of this invention are widely available commercially and include graft copolymers of acrylonitrile and styrene on a diene homopolymer or copolymer rubber substrate. Also included are the variety of analogous resins wherein all or a portion of the styrene component may be replaced with other vinyl arom-atic monomers such as alpha methyl styrene and the like, and those wherein all or a portion of the acrylonitrile is replaced with methacrylonitrile, methylmethacrylate (MABS and MBS) and the like. Further analogs including the graft copolymers of styrene and acrylonitrile or the like on an acrylate rubber substrate are also useful. Although the ABS resins are described as graft copolymer resins, a variety of analogs are known wherein a rigid copolymer such as SAN or a methylmethacrylate-acrylonitrile-styrene copolymer is blended with a rubbery polymer such as a high rubber content styrene-acrylonitrile-butadiene (ABS) graft copolymer. As used herein, the term ABS is thus intended to incorporate the wide variety of engineering thermoplastic resins recognized in the art as ABS resins. The invention will be better understood by consideration of the following examples. Example 1. Synthesis of beta-pentabromophenoxyethanol. Into four one-pint citrate bottles were placed 180 ml deionized water, 2.3 g (.057m) NaOH, and 22 g (.045m) pentabromophenol. A magnetic stirring bar was added to each, and nitrogen was bubbled into each of the bottles for 3 min. The bottles were then sealed, contents were stirred while liquid ethylene oxide (12 ml) was injected into each bottle through the seals in 2 ml portions over a 5 1/2 hr. period. The mixtures were stirred at room temperature for an additional 17 hers. The bottles were opened and the combined solid product was collected by filtration. The white product was washed twice with deionized water, dried in a vacuum oven at 760C to constant weight, then recrystallized from 850 ml toluene to give 39 g of pentabromophenoxyethanol ethanol, m.p. = 163do. Example 2. Synthesis of bis(beta-pentabromophenoxyethyl) succinate. A 250 ml, three-necked round-bottom flask equipped with a thermometer, Dena-Stark trap and magnetic stirrer was charged with 175 ml dry toluene and heated in an oil bath to 70"C. Dry beta-pentabromophenoxyethanol (32 gr, 0.06M) was charged to the flask, followed by 3 gr (0.03M) dry succinic anhydride and, as an acid catalyst, 4 drops of concentrated sulfuric acid. The reaction mixture was heated to reflux. After ca.0.5 ml (0.03M) water was collected by azeotropic distillation in the Dean-Stark trap, the reaction mixture was cooled to room temperature and then chilled for one hour. The product separated and was collected by filtration, washed twice with 100 ml cold toluene and dried to a constant weight at 70"C under vacuum. Yield 30 gr (0.05M, 83%), m.p. = 194 C. The structure of the product as bis(beta-(penta bromophenoxy)ethyl) succinate was confirmed by carbon13 NMR (in pyridine d5) and IR. The elemental analysis results were in agreement with the proposed product. Calculated for bis(beta-pentabromophenoxyethyl) succinate (C20H12Br10O6) %C=20.94, %H=1.05, %Br=69.64; found: %C=20.97, %H=1.04, %Br=69.55. Examples 3-6. Flame-retarded ABS Compositions. The flame retardant of Example 2 was compounded with ABS, antimony oxide and various lubricants and additives to demonstrate the flame retardant character of such compositions. the blends, summarized in Table I, were formed by combining the indicated materials in a Brabender Plasticorder fitted with a mixing head at 350'F, cooling the samples, then compression molding at 350-F to provide test specimens. The compositions and flame retardance test results are summarized in Table I. Table I. Flame Retarded ABS Blends Ex. No.: 3 4 5 6 Compositions ABS(1) pbw 100 100 100 100 FR(2) pbw 18 24 24 17 FR wt% 14.9 18.7 17.8 13.8 Sb2O3 pbw 6.7 4 4 6.4 Other pbw 5(3) - 5(7) Lubricants pbw .8(4) 0.5(5) 2(6) Properties Lor(8) - 29.1 26.9 UL-94(9) V-O V-O V-O V-O Ave. burn, sec. 0.8 0 0 Max. burn, sec. 2 0 0 1. ABS = Cycolac 201 ABS from Borg-Warner Chemicals, Inc. 2. FR = bis(beta-pentabromophenoxyethyl) succinate (Example 2) 3. 5 parts chlorinated polyethylene from Dow Chemical Co. 4. 0.8 parts magnesium stearate lubricant 5. 0.5 parts Acrawax C lubricant from Glyco Chemicals, Inc. 6. 2 parts barium stearate lubricant 7. 5 parts, includes 1 pbw magnesium oxide and 4 pbw Titanium dioxide. 8. LOI = limiting oxygen index 9. UL-94 = vertical burn, with ave. and maximum burn times in seconds. It will be apparent that excellent, self-extinguishing flame retardance character is imparted to ABS when compounded with bis(beta-pentabromophenoxyethyl) succinate. The composition of Example 4 had a notched impact value of 1.1 ft lbs/in notch and a heat distortion temperature at 264 psi of 171'F,, demonstrating that the ABS compositions containing the flame retardant of this invention are neither embrittled nor greatly plasticized thereby. The invention disclosed will be seen to be the di-ester of beta-pentabromophenoxyethanol and succinic acid, bis(beta-pentabromophenoxyethyl) succinate and a method for its preparation comprising the steps of ethoxylating pentabromophenol with ethylene oxide to provide beta-pentabromopheoxyethanol, then esterifying the ethanol compound with succinic anhydride.

Claims: CLAIMS 1. The di-ester of beta-pentabromophenoxyethanol and succinic acid. 2. A method for preparing the di-ester of betapentabromophenoxyethanol and succinic acid comprising the steps of ethoxylating pentabromophenol with ethylene oxide in the presence of an aqueous caustic to provide beta-pentabromophenoxyethanol with one mole of succinic anhydride in the presence of an acid catalyst. 3. The method of Claim 2 wherein said esterifying step is carried out in a non-aqueous solvent. 4. The method of Claim 2 wherein the esterifying step is carried out with azeotropic distillation of water. 5. A method for preparing the di-ester of betapentabromophenoxyethanol and succinic acid comprising the steps of monoethoxylating pentabromophenol with ethylene oxide in the presence of an aqueous caustic, isolating the resulting beta-pentabromophenoxyethanol, combining said beta-pentabromophenoxyethanol with succinic anhydride in a 2:1 molar in a non-aqueous solvent and in the presence of an acidic catalyst, refluxing said mixture and removing water by azeotropic distillation, thereby esterifying said mixture to provide bis(beta-pentabromophenoxyethyl) succinate. 6. A flame-retarded composition comprising an ABS resin and a flame-retarding amount of bis(beta-pentabromophenoxyethyl) succinate. 7. A flame-retarded composition comprising from 90 to 60 wt% of an ABS and correspondingly from 10 to 40 wt% bis(beta-pentabromophenoxyethyl) succinate. 8. The composition of Claim 7 further comprising a synergist for bromine-containing flame retardants. 9. The composition of Claim 7 further comprising antimony oxide 10. The composition of Claim 7 further comprising from 3 to 15 parts by weight antimony oxide per hundred parts by weight ABS.

Inventors: HALPERN, YUVAL
Applicants: BORG-WARNER CHEMICALS INC.
Application year: 1983
Main classification: C07C69
IPC codes: C08K5, C07C43