PROCESS FOR PRODUCTION OF AN ORGANIC AGRICULTURAL FERTILIZER AND FERTILIZER OBTAINED BY SAID PROCESS

Abstract: The process comprises the biological transformation of organic waste sludges both of domestic and industrial origin by means of the spontaneous fermentation, in heaps (2), of a mass (1) formed from said sludges and a mechanical substrate of wooden splinters having a high resistance to the biological attack. The heaps are periodically turned over in order to ventilate the mass and are of such sizes that, by means of the turning over, it is mantained a micro-aerobic fermentation with an oxygen content at the center of the heaps in the range from 0,1% to 0,5%. After a fermentation of about 60 days, the mass is screened in order to separate two components, one comprising the fertilizer and the other the mechanical substrate of wooden splinters, which are recy­ cled at the head of the process as a biological inoculum for the fermentation.

Description: "PROCESS FOF THE PRODUCTION OF AN ORGANIC AGRICULTU RAL FERTILIZER AND FERTILIZER OBTAINED BY SAID PRO CESS" The present invention relates to a process for the production of an organic agricultural fertilizer through biological transformation of organic waste sludges both of domestic and industrial origin. It is well known that in many industries, such as textile, dairy, confectionary, tannery and pharmaceutical industries, operations are effected originating organic sludges, that constitute wastes of the processings themselves or of the purification installations of the service waters. The domestic installations as well, in particular the purification installations for foul waters by means of biological depurators, produce a substantial quantity of residual organic sludges, that can in no way be used. The disposal of these industrial and domestic residual organic sludges represents a serious problem in that they are often polluting and can be charged with pathogenous germs and parasites. In order to solve this problem a U.S. process is known that performs an aerobic fermentation of the sludges by means of a forced ventilation. The sludges are collected on gratings under which are placed the fan, that force the air through the mass. Said process suffers however from serious drawbacks, the first of which is an unacceptable energetic and economic cost, due to the necessity of keeping continuously operating for weeks the fans. Furthermore such a process gives rise to an excessive oxygenation of the mass, equal or superior to 5*, causing the oxidation and the ensuing destruction of the most part of the organic substance contained in the sludges. At the end of said process, it is obtained in a low yield a residue, which can be used as a fertilizer, but having poor agronomical properties. After all, the air passing through the fermenting mass gets loaded with polluting gaseous products, and therefore has to be purified before the exhaust, with high additional costs. An object of the present invention is to realize a process for the production of an organic agricultural fertilizer through biologic transformation of domestic and industrial organic sludges devoid of the above-mentioned drawbacks. In particular it is aimed an economic process, with low energetic consumption, of relatively short duration, and fit to operate the transformation of any organic sludge without environmental pollution and to com ple-tely destroy the possible pathogenous germs, simultaneously producing an organic fertilizer having high agronomical properties. Said object is attained by the present invention in that it relates to a process for the production of an organic agricultural fertilizer by means of the biological transformation of organic sludges both of domestic and industrial origin, characterized in that it comprises sequentially: - a first step, in which said sludges are thoroughly mixed with a mechanical substrate formed from wooden splinters having a high resistance to the biological attack, and with a proper biological inoculum, the volume ratio between said sludges and said wooden splinters being equal or slightly less than 1; ; - a second step of spontaneous fermentation of the mass obtained in said first step, said mass being arranged in heaps having predetermined sizes, which are sheltered from the inclemency of the weather in a ventilated and at ambient temperature area, said mass being periodically ventilated turning said heaps over, the size of the latter and the frequency of the turning over being such as to produce a micro-aerobic fermentation of the mass, the oxygen content of- the mass, measured at the -center of each heap between two successive turning o- ver, remaining in the range from 0,1 and 0,5ffi; ; and - a third step of screening of the fermented mass, in order to separate it in two components, one comprising said organic agricultural fertilizer, and the second formed by said mechanical substrate of wooden splinters, the said third step being carried on after about 60 days from the beginning of said second step, when the temperature of the fermenting mass stabilises at a constant value between about 300 and 350C. The present invention further relates to an organic fertilizer for the manuring of soils, characterized in that it has the following analytical composition expressed, except for the mois ture, on the dry matter: min max Moisture % 35 50 pH 6 8 Ashes % - 60 Organic matter % 40 Total nitrogen % 2 5 Total phosphorus % 1 3 K % 0,1 ¯ Total humus % 4 8 Humic acids % on total humus 60 Fulvic acids % " " 40 Pb ppm - 500 Ni ppm 200 Cr ppm - 500 Cd ppm - 10 Cu ppm 1000 Zn ppm - 2500 Mn ppm - 1000 Fe % For a better understanding of the present invention, a non-limitative description of an embodiment will now be given with reference to the accompanying drawing, in which: figure 1 represents a qualitative graph of the course of the temperature of the fermenting mass; and figure 2 represents an operation of the process of the invention. With reference to figure 1, the process comprises the biological transformation of the sludges through the spontaneous fermentation of a mass 1 formed by the sludges and a proper mechanical substrate of a kind biocompatible with the micro organisms responsible fr the fermentation. The mass 1 is collected in neaps 2 naving predetermined sizes sheltered from the inclemency of the weather in a ventilated and at ambient temperature area, for example on an outdoor asphalted surface covered with a shed. According to the invention, the mass 1 is ventilated by the periodic turning over of each heap 2 carried on with proper mechanical means, for example a turning over machine 3 with belt (or cutter) which is advanced in direction of the arrow against the heap 2 so as to crumble it and then to build it up again imasdiately downstream of the machine 3. In this way at the end of the turning over the heap 2 is transferred in an opposite direction to that of the advancement of the turning over machine 3 by a preset length The size of tne heaps must be the following: length higher or equal to 10 m; width higher or equal to 3 m; and depth between 2 and 4 m. The mechanical substrate is formed, according to the invention, from wooden splinters ("chips") of hard and/or resinous woods, having therefore a high content (percent) of lignin and so a high resistance to the biological attack, which are mixed with the sludges at the rate of 50 or somewhat more by volume, and must have the following dimensions: length higher than 5 cms; width about 3 cms; and thickness about 0,5 cuts. The fermentation process of the mass 1 must last abu-ut 60 days and is discontinued when the temperature of the mass 1, measured at the center of the heap 2, stabilizes at a constant value in the range from 300 to 350C. In order to obtain the complete destruction of the possible parasites and pathogenous germs contained in the sludges without the oxidative destruction of the organic matter contained in the same, we have surprisingly found, after years of experimental studies, that the fermentation must be carried on in microaerobic conditions, keeping the moisture of the mass 1 equal or lower than 50e > ; ; therefore the oxygen content of the mass 1, measured at the center of the heap 2 between a turning over and the following, must be always in the range from about 0,1 to about O,fg and the CO2 content must be in the range from 19 to 20;. In these conditions there is no uprising of an anaerobic fermentation and instead in the mass 1 grow many micro-organisms, comprising among other the thermophile actinomyces and streptomyces and various strains of Coprinus, which find a proper support on the surface of the wooden splinters mixed with the sludges. The splinters moreover impart to the mass 1 a suitable porosity and consistence. In a preferred embodiment the turning over of the mass 1 are in number of three and are carried on respectively the first after about 7 days from the start of the fermentation; the second after about 15 days from the first turning over, and the third after about 20 days from the second turning over; the mass 1 is then left to rest in heaps for at least further 15 days after the third turning over. In such conditions the course of the temperature of the mass 1, noted experimentally, is as shown in the qualitative graph of figure 1 At the start of the fermentation step, the temperature of the mass 1 rises to values hither than 700C and then decreases in a manner approximately sinusoidaly damped, showing minima corresponding to each turning over and stabilising finally around 300C after the 50th-55th day. At the end of the fermentation of the mass 1, the starting sludges are completely transformed and have produced an organic fertilizer containing a certain quantity as well of the organic matter of the substrate formed by the wooden splinters. The latter are separated from the so obtained fertilizer by means of a screening operation of the mass 1, carried on for example with two vibrating screensserially arranged, and during which a portion of the wooden splinters is crumbled, due to the mechanical stresses, and goes to form a part of the end product. Then the fertilizer so obtained is stocked, in bulk or sacked. Before stocking, the end product can be subjected to drying to lower its moisture from about 50?to to about 35P. This can be conveniently done through thermal drying with combustion of bio-gas, which can be produced in a known way from organic wastes and/or from a portion of the sludges themselves used for the production of the fertilizer. Por a proper course of the above mentioned process, the sludges used as a raw material must have the average analytical properties tabulated in Table I. All the values presented in Table I are expressed on the dry matter, except for the moisture. TABLE I ANALYTICAL PROPERTIES OF THE SLUDGES min max Moisture % 50 85 pH 3,5 8,5 Ashes% 15 50 Organic matter % 50 85 Total nitrogen % 2 9 Total phosphorous % 0,5 2 0,1 Pb ppm - 500 Ni ppm - 200 Cr ppm - 500 Cd ppm - 10 Cu ppm - 1000 Zn ppm - 2500 Mn ppm - 1000 Fe % 5 According to the values shown in Table are suited to be treated with the process of the invention the industrial sludges produced by the following industries: textile, dairy, confectionary, tannery, pharmaceutical; and further the domestic sludges (residues of the installations for the biological depuration) and the decantation sludges (coming from the primary depuration of the water for the water systems). There can be treated with the process of the invention also sludges having originally a composition different from that shown in Table I, provided they are mixed each other and/or added with lignocellulosic residues (such as paper mill sludges) till tiring the composition of the mixture of sludges so obtained in the range of values shown in Table I. Small additions of lignocellulosic residues act anyhow as a coadjuvant for the development of the fermentation, even when the sludges composition is correct. In order to assure that the fermentation of the mass 1 proceeds so as to obtain the desired end product, it is necessary not only to control the fermentation parameters ( oxygen %, CO2 *, temperature and moisture), but make sure that since the start the fermentation is produced by the growth of the most suited micro-organisms, such as for example the above-mentioned tnermophile mycetes. To this end, according to the invention, the mass 1 is prepared by means of a mixing operation immediately preceding the fermentation step in heaps 2, during which the sludges, having a composition according to Table I, are thoroughly mixed, in a proper way, for example by means of turning over machines or concrete mixers, with said mechanical substrate formed from wooden splinters and with a proper biological inoculum. According to the invention the biological inoculum is formed by a weight portion of the substrate wooden splinters, which portion comprises the wooden splinters separated from the end product by means of the screening operation of the mass 1 at the end of the fermentation, as previously described. In fact, according to the invention, the described process is cyclic and comprises a step of recycle of the wooden splinters separated from the fertilizer by means of the screening of the fermented mass 1. These are recovered and transferred to the head of the process (upstream of the mixing o- peration), where they are mixed with other fresh wooden splinters and new sludges, initiating in the latter the fermentation. It is indeed obvious that the chips separated from the end product at the end of tne fermentation are loaded with colonies of microorganisms, well developed and active. Therefore, by mixing said chips with fresh sludges, it is produced an immediate attack of the latter. Further we have surprisingly found that the micro-organisms carried by the chips are able to interrupt at the very beginning the possible developmento of undesired micro-organisms. Essentially, the wooden splinters or chips are used, besides as a mechanical substrate, in the same way as a catalyst that, completed the reaction, is separated from the end product in order to be reused to convert a new quantity of starting material. As said previously, during tne process of tne invention, the wooden splinters undergo a loss of organic matter, which is degraded by the biological attack and by the mechanical crumbling of the wood and which passes into the fermenting sludges and the end product. This loss corresponds to about 1/4 of the initial weight of the support wooden splinters. Consequently to the splinters that are recycled to the head of the process, it is necessary to add fresh splinters to make up for the loss. Therefore the mechanical substrate which is added to the sludges to produce the mass t, must have the following composition in weight: - 1/4 of wooden splinters formed by cuttings produced from the chipping of trees (for example by means of shredding machines provided with bladed discs); - 3/4 of wooden splinters coming from the mechanical substrate of a mass 1, which has already fermented, which splinters are separated from the end product of the degradation of the sludges by means of screening. The analytical properties of the fertilizer obtained. with the described process, starting from sludges having the composition according to Table I, are presented in Tables II and III, where all the values, except the moisture, are expressed on the dry matter. TABLE II ANALYTICAL PROPERTIES OF THE END PRODUCT min max Moisture % 35 50 'pH 6 8 Ashes % - 60 Organic matter % 40 Total nitrogen % 2 5 Total phosphorous % 1 3 0,1 Total humus % 4 8 Humic acids % on total humus 60 Fulvic acids % " " N 40 Pb ppm - 500 Ni ppm - 200 Cr ppm - 500 Cd ppm - 10 Cu ppm 1000 Zn ppm - 2500 Mn ppm - 1000 Fe % 5 - III DISTRIEUTION OF MUSIC MATTER IN FRACTIONS WITH DIFFERENT MOLECULAR MASS min max Molecular mass C5000 (* on tot. humus) 25 5000-10000 " " " 30 40 10000-100000 " " " " 5 20 > 100000 I1 n n 15 40 The organic fertilizer obtained with the described process results homogeneous, and incorporated in the soil increases its volume and the porosity. Several test of manuring carried on soils for agricultural cultivation and in nursery have shown that it presents gDod general agronomical properties. Furthermore it is especially rich in nitrogen and iron salts and has a content in humus with high molecular mass, and thence sufficient to increase the exchange capacity of the manured soils in a way to assure a complete utilization of the nitroen present in the manure. The manure obtained with the described process is davoid of parasites and/or pathogenous germs, and on the contrary is rich in micro-organisms suited to develop the growth of the cultivations. It further contains organic sutstatces similar in composition and quantity with those normally present in fruitful soils and assures therefore a "natural" manuring lending itself to the regeneration of unfruitful soils. The process of the invention enables consequently to obtain a new and valuable organic manure and in the same time to solve economically and without energetic waste the problem of the disposal of both domestic and industrial organic sludges, without pollution and damages for the environment. It will be now described an example of the preparation of the organic manure according to the invention. 45000 kgs of sludges having an average composition as shown in Table I and a consistency equal to 3 1000 kg/m3 are mixed with 13500 kg of wooden splinters obtained from woods of broadleaf trees having densities in the range from 300 to 320 kg/m ; said wooden splinters are subdivided as follows: 3400 kgs of fresh chips obtained shredding logs by means of a rotating cutter; and 10100 kgs of recycled wooden splinters (chips), that have been separated through screening from 48000 kgs of a fermentation product having the pt- perties presented in Tables II and III and ob tamed with the process of the invention. It is obtained a mass of 58500 kgs which is subjected to fermentation in an outdoor surface under a shed, collected in a Substantially parallelepiped heap having dimensions equal to 10 x 3 z 3 m. Already after 1 day the temperature of the mass at the center of. the heap rises over 400C and attains 7500 on the fourth day. After seven days the mass is turned over with a belt turning over machine and the temperature decreases to 400C, and rises again to 550C within further eight days. The oxygen content at the center of tne heap is 0,3. On the 21th day is carried on a second turning over, being the temperature lowered to 350C. It rises again to 5000 while the moisture fluctuates between 45% and 509, and descends to 32 C before the third turning over, carried on after 6 weeks from the start of the fermentation. Then the temperature rises again to 4C O and then descends spontaneously stabilising, between the 55th and the 60th day, to 300 C. After 6C days the fermentation is complete, the mass is screened separating two fractions formed the first by 10000 kgs of wooden splinters, that are collected and utilized for the fermentation of further sludgas, and tne second by 4b500 kgs of a product having the following properties (expressed, except for the moisture, on the dry product). Moisture 46 Ashes 40* Organic matter 55% Iron 4% pH 7 Total humus 7% Humic acids 70% Fulvic acids 30%

Claims: CLAIMS 1. A process for the production of an organic agricultural fertilizer through biological transformation of organic waste sludges both of domestic and industrial origin, characterized in that it comprises sequentially: - a first step, in which said sludges are thoroughly mixed with a mechanical substrate formed from wooden splinters of woods having a high re-qistance--to other biological attack, and with a proper biological inoculum, the volume ratio between said sludges and said wooden splinters being equal or slightly less than 1; ; - a second step of spontaneous fermentation of the mass (1) obtained in said first step, said mass being arranged in heaps (2) having predetermined sizes, which are-sheltered from the inclemency of the weather in a ventilated and at ambient temperature area, said mass (1) being periodically ventilated by means of turning over of said heaps (2), the size of the latter and the frequency of the turning over being such as to produce a micro-aerobic fermentation of the mass (1), the oxygen content of the mass, measured at tne center of each heap (2) between two successive turning o ver, remaining in the range from 0,1* to 0,5%; and - a third step of screening of the fermented mass (1), in order to separate it in two components, one comprising said organic agricultural fertilizer, and the second formed by said mechanical substrate of wooden splinters, the said third step being carried on after about 60 days from the beginning of said second step, when the temperature of the fermenting mass (1) stabilises at a constant value between about 300 and 50 C. 2. A process according to claim 1, characterized in that it comprises a fourth step of recycling said wooden splinters, separated from said fertilizer by means of the third step, at the head of said first step, said proper biological inoculum comprising a weight fraction of said mechanical substrate of wooden splinters, said fraction being formed by the wooden splinters separated from said fertilizer during said third step and recycled through said fourth step. 3. A process according to claim 2, characterized in that said mechanical substrate has, at the start of said first step, the following composition in weight: - 1/4 of wooden splinters formed by cut tings produced from the chipping of trees; - 3/4 of wooden splinters formed by said weight fraction separated through said third step and recycled through said fourth step; said mechanical substrate undergoing during said second and third steps a biological and mechanical attack, which involves a weight loss of organic matter e qual to about 1/4, the organic matter lost by said mechanical substrate going first into said fermenting sludges and then into said fertilizer. 4. A process according to anyone of the preceding claims, characterized in that said wooden splinters are obtained from hard and/or resinous woods containing a high percentage of lignin, and have the following properties - thickness about 0,5 cms - width about 3 cms - length higher than 5 cms. 5. A process accordin 3 anyone of the preceding claims, characterized in that said organic sludges comprise lignocellulosic residues and have the following analytical properties expressed, except for the moisture, on the dry matter: min max Moisture % 50 85 pH 3,5 8,5 Ashes % 15 50 Organic matter % 50 85 Total nitrogen % 2 9 Total phosphorous % 0,5 2 0,1 Pb ppm - 500 Ni ppm - 200 Cr ppm 500 Cd ppm 10 Cu ppm - 1000 Zn ppm - 2500 Mn ppm - 1000 Fe % 5 6. A process accordin; anyone of the preceding claims, characterized in that said second step comprises the following operations: - preparation of a plurality of said heaps (2) having an height between about 2 and 4 m, a length higher or equal to 10 m and a width higher or equal to 3 m; - a first turning over of said heaps (2) after about 7 days from the start of said second step; - a second turning over of said heaps (2) after about 15 days from the firat turning o- ver; a third tuning over of said heaps (2) after about 20 days from the second turning over; and - rest of said fermenting mass (1) in heaps (2) for at least further 15 days from the third turning over. 7. A process accordin Janyone of the preceding claims, characterized in that it comprises a fifth step of drying of said fertilizer obtained after said third step, in order to lower the moisture content of the latter from about 50 to about 35%. 8. Organic agricultural fertilizer for manuring soils, characterized in that it has the following analytical composition, expressed, except for the moisture, on the dry matter: min Moisture % 35 50 pH 6 8 Ashes % - 60 Organic matter % 40 Total nitrogen % 2 5 Total phosphorous % 1 3 K % 0,1 ¯ Total humus % 4 8 Humic acids % on total humus 60 Fulvic acids % " " ,' 40 Pb ppm 500 Ni ppm - 200 Cr ppm - 500 Cd ppm - 10 Cu ppm - 1000 Zn ppm - 2500 Mn ppm - 1000 Fe % 5 9. An agricultural fertilizer according to claim 8, characterized in that the humic substances contained in the same have the following distribution in fractions with different molecular mass: min max Molecular mass < 5000 (% on tot. humus) 25 5000-10000 n l " 30 40 10000-100000 t n 5 20 > 100000 n " It 15 40 10. An agricultural fertilizer according to either of claims 8 or 9, characterized in that it comprises products of the biological transformation of organic waste sludges, produced by the process according-to anyone of the claims 1 to 7.

Inventors: JODICE, ROBERTO
Applicants: IPLA - ISTITUTO PER LE PIANTE DA LEGNO E L'AMBIENTE S.P.A.
Application year: 1983
Main classification: C05F9
IPC codes: C05F9, C05F17