METHOD FOR THE PREPARATION OF SYMMETRICAL MONOACETALS OF AROMATIC 1,2-DIKETONES STARTING FROM THE CORRESPONDING ALPHAHYDROXYKETONES

Abstract: The invention relates to a process for the production of symmetrical monoacetals of aromatic 1,2-diketones starting from the corresponding alphahydroxyketones and to their use as photoinitiators of polymerisation by ultraviolet radiations. According to the process of the invention, protection of the carbonyl group is not operated, and the aromatic alpha­ hydroxyketones react, in the first step of the reaction, with an halogenating agent in presence of N-substituted aliphatic amide or an aliphatic alcohol from 1 to 5 atoms and, in the sec­ ond step, with an alkaline metal alcoholate or an alcohol. If the carbonylic group is protected, the alphahydroxyketones are first converted into acetals or hydrazones and then into the pro­ ducts of the invention by means of oxidation or acetalisation.

Description: METHOD FOR THE PREPARATION OF SYMMETRICAL MONOACETALS OF AROMATIC 1,2-DIKETONES STARTING FROM THE CORRESPOND ING ALPHAHYDROXYKETONES. The invention relates to a new method for the production of the symmetrical monoacetals of 1,2-aromatic diketones starting from the corresponding alphahydroxyketones and their use for U.V. polymerisable systems. It is well known to people skilled in the art that mixtures of unsaturated monomers such as acrylic, vinylic, allylic, maleic, etc... and of unsaturated oligomers or polymers can be polymerised by irradiation with ultraviolet light in presence of chemical products which, under its influence, are able to generate radicals. Such mixtures can be employed advantageously in various fields of application, such as varnishes for wood and plastic materials, paper and carton coating, metal painting and preparation of inks and adhesives. Products able to induce the polymerization of unsaturated molecules under the influence of light are then called photoinitiators of polymerization and some of them have become industrially very interesting, because they have qnanttini yield characteristics (rate of polymerization for unit of absorbed energy), efficiency (lower amount of photoinitiator to obtain the desired characteristics), and da% storage stability not other wiso combined. Particularly monoacetals of aromatic 1,2-diketotles show ail these @vantass- and therefore they have found pratical use in various application fields. Such type of produels are already known in the scientifie literature and in patents (i.e. U.S.P. 2.995.573 and U.S.P. 3.715.293) and moreover industrial processes for their production have been developed. With regard to products like benzilmonoacetals, one of the proposed method (OLS 2.337.813) includes the acetalization of 1,2-aromatic dike-tones, possibly obtained by oxidation of the corresponding benzoins according to L.J?. Fieser et al (J. Org.Chem. 27 2247 (1962)), by means of dialkylsulfites in presence of acidic catalysts according to the findings of W. Woss (Annalen, 485 283 (1931)) reported on Houben Weyl, Methoden der Organischen Chemie (Ed. 1965, Band VI/3, Sauerstoffverbindungen I. Teil 3 pag. 228). A second method (OLS 2.616.588) includes the reaction between the same aromatic 1,2-diketones, an alkylating agent and an alkaline metal alcoholate, as an extension of the alkoxylation of tertiary carboxonium salts studied by E. Schmitz (Berichte, 91 410 (1958)) and reported on Houben Weyl, Methoden der organischen Chemie, (Ed. 1965) Band VI/3, Sauerstoffverbindungen I, Teil 3 - Pag.-263). Another advantage of this method is reported by R. Kuhn et al, Chem. Ber. 94 2258 (1961). The advantage of this second method in comparison to the first one is the possibility to obtain asymmetric acetals. The object of the present invention is to obtain noncyclic symmetrical monoacetals of aromatic 1,2-dike -tones, starting directly from the corresponding alphahydroxyketones, without any intermediate formation of the relative 1,2-diketones. It has been found that noncyclic symmetrical monoacetals of aromatic 1,2-diketones having the formula EMI2.1 wherein: -Ar1 and Ar2 represent, each independently, radicals of carbocyclic or heterocyclic aromatic @@@elel, equal or dif- ferent, which may also brine substituents such as halogen alkoxy3 (with 1 to 5 carbon atom chain), phenyl, alkyl; - R represents methyl, alkyl (having 2 to 5 carbon atom chain), alkenyl from 2 to 3 carboii atoms, trimthysilyl, or an alkyl bearing sustituents of tie type -OR1, -SR1, NR2R3 wherein R1, R2, R3ar represent, each independently, an alkyl from 1 to 3 carbon atoms; ; can be obtained by a simple method, generally applicable, with high yield and degree of purity, starting from the corresponding aromatic alphahydroxyketones having the formulas EMI3.1 wherein: - Ar1 and Ar2, each independently, have the same meaning as in formula I, without any intermediate formation of the relative aromatic 1,2-diketones, if the alpha hydroxyketones of formula II and III are reacted with suitable oxidizing agents, with or without the prote ction of the ketonic group according to the type of reagents to be employed. When the carbonyl protection is not used, it is possible to obtain, by the action of halogenating agents as halogens or sulfuril halides, intermediates of formula IV, which, without being isolated, are converted into products of formula I by suitable nucleophyles as alkaline alkoxylates: EMI3.2 wherein: - Ar1 and Ar2 have the same meaning as in the formula I; - X, Y may be: equal, and in sucha case, they represent an halogen radical, - different, and in such a case, they represent an halogen and respectively, an alkoxyl radical of the type - OR, in which R have the same meaning as in formula I Iii the case in which the carbonyl group is protected by converting it into an hydrazone or a symmetrical acetaor into other addition compounds containing halogens, products of the formula: : EMI4.1 may be obtained, which, without being isolated, are oxidized by the methods well known to the people skilled in the art, to products of formula EMI4.2 which, without being isolated, are further acetalized, if the formula V does not represent itself an acetal, in order to obtain the products of formula I. In the formulas V and VI: Ar1 and Ar2 have the same meaning as in the formula I and K, Z may be: - equal, and in such a case, they represent an halogen radical, alkoxyl - OR (wherein R has the same meaning as in formula I); - coincident, and in such a case, they represent a diazo or hydraono group; - different, and in such a case, they represent an halogen radical and an alkoxyl - OR (wherein R has the same mean ing as in formula I) respectively. Examples of aromatie alpha hydroxyketones are benzoin; symmetrical and asymmetric benzoins eventually substituited on the aromatie rings by alkyls, phenyls, halogens; 2-thenoin; 2-furoin; 2-pyridoin; 1-(2 pyridyl)-2-phenyl-2-hydroxyethanone; 1-phenyl-2-(2-pyri dyl)-2-hydroxyethanono; etc., and they are obtained by methods easily accessible in the literature. The alpiitihydroxyket ones preferred in this invention are those with symmetrical substituents such as benzoin, 2-thenoin, 2-furoin etc. By the method described in this invention, it is therefore possible to produce the monoacetals of aromatic 1,2-diketones, described by the formula I. Products obtained according to the invention may be advantageously employed as photoinitiators for the photopolymerization by U.V. light of polymerizable systems containing unsaturated compounds both monomeric and polymeric, particularly also in presence of mineral fillers, in spite of a decrease of the thermal stability generally induced by the sames in these mixtures and in presence of photoinitiators. Particularly the products obtained by the present invention may be advantageously employed in amounts of 0,1 to 10 per cent in systems based on styrenated polyesters and in acrylic systems, which are used as moulding and coating for wood, inks for silk-screen decoration and offset printing, inks for the preparation of adhesives, etc. Preferred amounts are between 0,5 and 5 per cent and are related to the number of unsaturated groups as well as to the types of monomers, pigments and stabilizers present in the system. Particularly suitable for the use above are the so solutions of the products obtained according to the present invention, in chlorinated aliphatic hydrocarbons or ethylenically unsaturated monomers. Infact these solutions offer the advantage of simple handling and of being easily incorporated, as they are liquids soluble in the photocurable systems. From the manufacturing point of view the advantage is due to tlic climination of the step necessary for the seprat1on of the final products by means of crystallization or other expensive methods. Moreover the solutions in chlorinated aliphatic hydrocarbons, and particularly that in dichlorometane, present a synergism for the photochemical activity, between the solvent and the solute. For the employment in photocurable mouldings and coatings, an amount of photoinitiator (as solid material dissolved in the aforementioned solvent) lower than that required to reach the same hardness or the same degree of curing with the pure product, is sufficient. The saving of solid photoinitiator can be up to 10 per cent by weight. The suggested concentrations of dissolved solid material are dependent on the solubility of the products, as obtained according to the present invention, and concentrations near the saturation are preferred. Suitable light sources for the curing of the coatings containing the products of formula I are medium-pressure and high-pressure mercury vapour lamps (eventually also pulsed lamps), with emission spectra between 200 and 600 nanometers. METHODS OF SYNTHESIS The products of formula I can be obtained according to the present invention, through one of the following methods of synthesis: Method A It relates to the mono or dihalogenation on the carbon atom adjacent to the carbonyl position of an alphahydroxyketone by using halogen, sulfuryl halides, N halogenoimides aid further substitution of halogens by alkoxyl radicals. a) When halogenation is performed in aprotic solvents, it is possible to obtain the germinal dihalides that are converted into products of formula I by treat ment with alkaline alcoholates: EMI7.1 In this case, preferred starting compounds are those in which Ar1 is the same as Ar2, because in such way no separation of structural isomers is necessary, al lowing high yields. The preferred reagents for the halogenation are sulfuryl chloride and chlorine, while the preferred alcoholates are sodium methylate or ethyla-te. The halogenation reaction proceeds with a particularly high rate and according to a surprisingly different pathway, when compared with the results of L. Fieser et al (J. Org.Chem., 27 2247 (1952)), if an aliphatic amide, preferably N,N-dimethylformamide is employed as solvent. The subsequent exchange with al kaline alcoholates is not difficult and is performed in an alcoholic solvent. This reaction has already been studied on acetophenones by N. De Kimpe (J. Org. Chem. 43 2933 (1978) and Synth.Comm. 9 575 (1979)). b) If the halogenation is performed in alcoholic solvent, an alphahalogeno-ether (hemiacetal halide) is obtained, which in presence of the same alcohol and an acid ca talyst gives an acetal: EMI7.2 The alphachlorethers are known intermediates in the preparation of acetales, through the reaction of -the diasoaloanes by alcohols and t-butylhypochlorite, as reported by H. Baganz, Angew. Chem. 78, 448 (1966)). Also in thi; case the reaction conditions are smooth, yields are high and the products are isolated with high degree of purity. Method B According to this method, the carbonyl group is firstly protected by conversion into an acetal or an bydrazone and then the alcoholic group is oxidized to ketone. a) Protection by acetalisation of the carbonyl. The alphahydroxyacetals are easily accessible through two reaction steps: firstly alphahydroxyketones are converted into monohalogenoketones by the action of a thionyl halide in presence of pyridine (A.M. Ward, J. Chem. Soc. 1541 (1929)) or more advantageously, by the action of an aqueous hydrogen halide, an or ganic solvent (which dissolves the product but is immiscible with water) and a phase transfer catalyst (D. Landini et al, Synthesis 430 (1975)). In the second step the reaction of the alphahalogeno ketones with two moles of an alkaline alcoholate gi ves, via an epoxyether, the alphahydroxyacetals: EMI8.1 The further oxidation into compounds of formula I is performed according to classical methods by means of reagents that don't cleave the acetal group, as, for example, the Sarett reagent (F. Nuet et al, Synth Commen. 10 83 (1980) or the Cornforth or the Snatzke reagent (Ber. 94 729 (1961)), in an inert solvent al room temperature, Other reagents may be potassium permanganate (J. Am. C01iern. Soc. 81 633 (1959)) or potassium-2-nitropropane. EMI9.1 The oxidation may be also achieved with less tradi tional methods for instance, by means of the phase transfer catalysis. In such way sodium hypochlorite is used as oxidizing agent, the organic product is dis solved in methyl one chloride and the phase transfer catalyst is a quaternary ammonium salt. Some examples of oxidations carried on alcohols or benzylic type amines are already known in the litera ture (G.A. Lee, Te.Le. 20 1641-1644 (1976)). b) When the hydrazonic protection is used, firstly the alpha hydroxyketone is reacted by hydrazine under con ditions that give the alphahydroxymonohydrazone deri vative and this is subsequently oxidized giving an al phadiazoketone that, by further treatment by t-butil hypochlorite in alcoholic solvent, gives compounds of formula I: EMI9.2 The oxidation of the hydrazono to the diazo group may be performed in homogeneus phase by an organic peracid (Belg.P. 802.112) or through phase transfer catalysis (J.R. Adamson et al, J. Cliem. Soc Pekin Trans. I, 2090 (19y5)), separately or simultaneously to the oxidation of the hydro yl group gccording to the method described in seetion B.a). The conversion of the diazoketone into an acetal of the 1,2-diketone is very easily accomplished with high yields and gives very pure products; examples of such conversions are already known for aliphatic alphadia zoketones and for alphadiazoacetophenones (DBP 1.254.138). Alternatively the alphahydroxyketones may be obtained through the oxidation of the corresponding hydroxyhydra zones to hydroxydiazo derivatives, subsequent acetali zation to alphahydroxyacetals and final oxidation of the hydroxyl to the ketonic group. Furthermore and preferably, the oxidations of different oxidizable groups may be carried out simultaneously and the isolation of the alphadiazoketone is not required as a preliminary step in the production of the monoacetals of the 1,2-diketones of formula I. EXAMPLE Method A Example 1 2,2-dichloro-1, 2-diphenylethanone 6,6 g (90 mmol) of N,-dimethylformamide are dropwise added to 50 ml (d= 1,67, 618 mmol) of stirred sulfurylchloride at 14-150C, out of moisture. While stirring 65 g (306 mmol) of benzoin are added portionwise and the reaction mixture is left without stirring and heated at 40-430C for further 45 minutes. The mixture is chilled in ice and 21 g of glacial acetic acid diluited with 12,7 g of water is added followed by 35 g of water. The reaction product is extracted with toluene and the organic layer washed with water and neutralized with sodium bicarbonate. Evaporation of solvent under reduced pressure gives 73,8 g (91%) as crystalline solid. It could be directly employed for the further reaction step. A little amount is purified by silica gel column chrom3to- graphy using petroleum ether benzene (75/25 by weight) as eluent. After evaperation of the eluent, a white crystalline solid is obts-':.ned which melts at 590C and has a cljlo- rine content of 26,6% (calc. 26.8%). The infrared spectrum shows characteristie bands at 1705 cm-1 (C-O), 1220, 735 and 695 cm-1. Example 2 2,2-dimethoxy-1,2-diphenylethanone 73,8 g (0,278 mol) of the product obtained in the example 1 are dissolved in 500 ml of methanol and dropwise treated at 5-60C with a solution of 37,6 g (0,696 mol) so dium methylate dissolved in 150 ml of methanol. The mixtu re is left at room temperature for 16 hours and then neu tralized to pH 7-8 by acetic acid, the solid is filtered off and the solvent is removed under reduced pressure. The residue is taken up with 45,2 g of methylenchloride and is-filtered yielding a solution containing 67,8 g (95%) of the title product which can be directly employed in photo polymerisable systems. A little amount of the solution is evaporated to dry ness giving crystalline white solid that melts at 62-630C and shows infrared absorption bands at 2940, 1695 (C=O) 1240, 1115, 1065, 700 cm 1. A little amount is hydrolised in water by heating at 60-700C with a trace of hydrochloric acid giving a yellow crystalline solid identified as ben zil (2-keto-1,2-diphenylethanone m.p. 94-960C) and 24,5 g of methanol per 100 g of analyzed product (calc. 25%). Method B Example 3 2,2-dimethoxy-1,2-diphenylethanol 106,1 g (0,5 mol) of benzoin are suspended in 53 g (0,67 mol) of pyridine and dropwise treated at 15-400C with 79,5 g (0,66 mol) of thionylchloride. After 1 hotir the reaction mixture is cooled to 100C and treated with 265 of ice giving a solid that is separated by filtration atid dried under vacium. A litti'( amount is ciaracterized after crystalliza- tion from getreleum ether obtaiging a white crystalline solid that molts at 67-68 C and shows infrared absorption bands at 1695 (C=O), 1450, 1210, 850, 735, 690 and 675, -1 545 cm The solid is then dissolved in 460 ml. of methanol and treated at 20-30 C with; 81 g (1,5 mol) of sodium methylate dissolved in 325 ml of methanol. After 2 hours at room temperature the mixture is neutralised to pH 7-8 by acetic acid, the solid is filtered off and the solvent removed under reduced pressure. The residue weighs 122,7 g (95%); it is a viscous oil with little tendency to crystallization and shows infrared absorption bands at 294-0, 1450, 1115, 1060, 700 cm and no carbon absorption. Example 4 2,2-dimethoxy-1,2-diphenylethanone The product obtained in the example 3 (122 g, 0,472 mol) is dissolved in 150 ml N,N-dimethylformamide and dropwise added to a solution of 70 g (0,70 mol) of chromic anhydride dissolved in 700 ml of N,N-dimethylformamide. The reaction mixture is cooled at 200C and treated with 1 ml 98% of sulfuric acid. After 16 hours the mixture is extracted with 300 ml of toluene and the organic layer washed with water and acqueous sodium bicarbonate. After evaporation of the solvent the residue (109 g, 90%) is taken up with 163 s of styrene giving a 40% solution, which can be directly employed in photopolymerisable systems. Example 5 2-diazo-1,2-diphenylethanone 3,2 g (100 mmol) of anhydrous hydrazine are added to a stirred suspension of 21,2 g (100 mmol) of benzoin in 100 ml of methylenechloride. After treating at 60-800C for 30 minutes the reaction mixture is chilled and diluited with 100 ml of water. An addition is made under efficient stirring of 0.68 g (2 mmol) of tetrabutylammonium bisulfate, 2 ml 1% iodine solution in methylene chloride, and, slowly in 2 hours at 0-10 C 47,7 ml (105 mmol) 38% peracetic acid, toghether with a 15% NaOJ-I solution to control the pTI at 9-10. After 2 hours 52 g (105 mmol) of 15% sodium hypochlorite solution is added. After further 2 hours of stirring tlle aqueous p phase is discharged and the organic one is washed, dried on anhydrous sodium sulfate and the solvent removed under vacuum at 400C max, yielding 17,8 g (80%') of the title compound. A little amount of this product is crystallized from petroleum ether for the characterisation, giving a yellow crystalline solid that melts at 76-780C and shows infrared absorption bands at 2070 (diazo), 1620 (C=O), 1360, 1240, 850, 755, 710, 690, 640 cm 1. Example 6 2,2-dimethoxy-1,2-diphenylethanone 22,2 g (100 mmol) of the product obtained in the example 5 are dissolved in 100 ml of methanol and dropwise treated under stirring at -150C with 11,95 g (110 mmol) t-butylhypochlorite. After stirring for 30 minutes (meanwhile the temperature rises to 0 C) the reaction mixture is neutralized with 5,9 g (110 mmol) of sodium methylate dissolved in 20 ml of methanol. The solid is filtered off and the solvent evaporated under reduced pressure, yielding 25,1 g (98%) of the title compound as a white crystalline solid with the same characteristics reported for the product obtained in the example 2. Example 7 2,2-diethocy-1,2-diphenylethanone It is obtained by the same procedure described in the example 6, substftuiting arihydrous ethanol for methanol. The prodact shows m.p. at 60-61 C and infrared absorption bands at 1690 (C-O), 1230, 1110, 1050, 940, 760, 700 cm Example 8 Use of the products in photopolymerisoble systema. a) Polyester based lacouer 2,0 g (As dry material) of one of the products obtained in the examples 2,4,6,7 are added to a mixture prepared from: 80 g ortophatalic unsaturated polyester (viscosity 1000-1200 cps at 250 C, acidity number 30, reactive monomer content 32%o) 20 g styrene b) Acrylic based lacquer 5 g (as dry material) of one of the products obtained in the examples 2,4,6,7 are added to a mixture prepared from: 50 g epoxyacrylic oligomer (viscosity about 10000 cps at 200 C, acidity number 5) 50 g poliethylenglycol diacrylate. Various characteristics are evaluated on the mixtures thus obtained: - shelf life (dark storage stability) as gelification time in thermostatic oven at 60 C, - degree of curing after deposition on a glass plate as 200 microns (wet) layer and subsequent irradiation with a medium pressure mercury vapor lamp (200 watt/inch 80 wattXcX at a distance of 4 inches(10 cm). The comparison is made between the products of the present invention and benzoin isobutylether as refe rence The results are reported in the following table: SYSTEM POLYESTER ACRYLIC 2,2-dimethoxy benzoin- 2,2-dimethoxy- benzoin -1,2-diphenylethanone -isobutylether 1,2-diphenylethanone -isobutylether Photoinitiator content (as percent of dry material) 2 2 5 5 Shelf life at 60 C (days) 6 4 5 5 Irradiation time (number of pass under the lamp) 4 4 6 6 Sward hardness after 10 minutes 30 24 28 tacky after 1 hours 46 36 38 not measurable scratch resistance good moderate good - Example 9 Photopolymerisable mixtures are prepared as in the example 8, nsing however a 60% solution of 2,2-dimethoxy-1,2-diphenylethanone in methylene chloride as photoinitiator and the pure dry product as reference. The cha- racteristics evaluated on the liquid mixtures and on dry film after exposure to the ultraviolet light are reported in the following table: SYSTEM POLYESTER ACRYLIC Photoinitiator 2,2-dimethoxy-1,2-diphenylethanone Used product pure solid 60% solut. Pure solid 60% solut. in CH2Cl2 in CH2Cl2 Amount of used product (g) 2,00 3,10 2,00 3,25 Shelf life at 60 C (days) 6 6 5 5 Erradiation time (number of pass under the lamp) 4 4 6 6 Sward hardness after 10 minutes 30 30 28 28 after 1 hour 46 46 38 38 Scratch resistance good good good good

Claims: CLAIMS: 1. A process for the production of symmetrical monoace tals of aromatic 1,2-diketones of formula EMI18.1 wherein: - Ar1 and Ar2 represent, each independently, radicals of carbocyclic or heterocyclic aromatic nuclei, equal or different, which may also bring substituents, as halogen, alkoxyl (with 1 to 5 carbon atom chain), phe nyl, alkyl; - R represents methyl, alkyl (with 2 to 5 carbon atom chain), alkenyl having 2 to 3 carbon atoms, trimethyl silyl, or an alkyl bearing substituents of the type -OH1, -SH1, -NR2R3 wherein R1, R2, R3 represent, each independently, an alkyl having 1 to 3 carbon atoms; starting from the corresponding aromatic alpha hydroxyketones of formulas: EMI18.2 wherein: - Ar1 and Ar2 have tre aforementioned meaning, characterized by the fact that no intermediate aromatic 1,2diketonos, tie symmetrical acetals of which are represented by the formula I, are formed, and that, by means of the used reagents, the products of formula IV may be obtained a-- intermediates when the carbon group is not protected EMI18.3 wherein: Ar1 and Ar2 have the same meaning as in formula I and X and Y may be: : - equal, and in such a case, they represent an halo gen radical, - different, and in this case they represent an halo gen radical and, respectively, alkoxyl radical of the type -OR, wherein R has the same meaning as in formula I, and products of formula V, when the carbonyl group is protected: EMI19.1 wherein: Ar1 and Ar2 have the same meaning as in formula I and Z and K may be: : - equal, and, in such a case, they represent an halo gen radical, alkoxyl - OR (wherein R has the same meaning as in formula I); - coincident, and, in such a case, they represent a diazo or hydrazono group; - different, and, in such a case, they represent an halogen radical and an alkoxyl of the type - OR (wherein R has the same meaning as in formula I), respectively. 2. A process according to -claim 1, characterized by The fact that Ar1 and Ar2 are equal carbocyclic or hetero cyclic aromatic nuclei. 3. A process according to claims 1 and 2, characterized by the fact that Ar1 and Ar2 are equal carbocyclic aromatic nuclei. 4. A process according to claims 1,2,3, characterized by t} ] e fact that, In odor r to obtain the products of for mula I starting fron the products of formula II, witiout protection of the carbonyl group, products of formala IV are obtained as intermediates. 5. A proess according to claims 1,2,3, and 4, characte rized by the fact that in the first step of the re action an halogenating agent is employed together with a secondary aliphatic amide or an alipliati al cohol having 1 to 5 carbon atoms, and in the second step an alkaline alcoholate on an alcohol is used. o. A process according to claims from 1 to 5, characte rized by the fact that, as halogenating agent, sul- furylchloride is employed in presence of N,N-dimethyl- formamide and, as alcoholate, sodium methylate or ethylate is used. 7. A process according to claims from 1 to 3, characte rized by the fact that, to obtain the products of formula I starting from the products of formula III via protection. of the carbonyl group, compounds of formula V are obtained as intermediates. 8. A process according to claims 1,2,3 and 7 characte rized by the fact that as a means to protect the car bonyl group a conversion of the products of formula III into acetals or into hydrazones represented by formula IV Is operated, which are then oxidized and acetalised if necessary. 9. A process according to claims 1,2,3,7 and 8, characte rized by the fact that, as oxidizing agents the Snatzke reagent (chromic anhydride in N,N-dimethyl-formamide) in methylene chloride, or organic peracids or sodium hypochlorite ti in mixed so'vents (water - methylene chlo ride) in presence of phase transfer catalysts are used. 10. A process according to claims 1,2,3,7,8 and 9, chara cterised by the fact tliat the acetalization performed on the alpha diazoketenes represented by the formula TV is carried out in rethanol or methanol in presence of t-bntylhypochlorite. 11. The compounds obtained by the processes according to claims from 1 to 10. 12. Use of symmetrical monoacetals of 1,2-aromatic diketones of formula I, obtained according to claims from 1 to 10, alone or in nlixtule with other photoinitiators, in sy stem based on ethylenically unsaturated monomers and pre polymers, curable by irradiation with ultraviolet light. 13. Use of symmetrical monoacetals of aromatic 1,2-diketones of formula l, obtained according to claims from 1 to 10, characterized by the fact that without isolating the pu re products, the solutions in chlorinated aliphatic hydro carbons or ethylenically unsaturated monomers, according to claim 12 is used. 14. Use of the solutions of the symmetrical monoacetals of aromatic 1,2-diketones of formula I in chlorinated ali phatic hydrocarbons, for the photocuring of system based on ethylenically unsaturated monomers and prepolymers, by irradiation with ultraviolet light. 15. A composition consisting of 60% solution of 2,2-dime thoxy-1,2-diphenylethanone in methylene chloride.

Inventors: CADONA', LUCIANO, LI BASSI, GIUSEPPE
Applicants: F.LLI LAMBERTI S.P.A.
Application year: 1983
Main classification: C07C49
IPC codes: C07C45, C08F2, G03F7, C07C43, C07C49