PROCESS AND COMPOSITION FOR CONTROLLED NOURISHING OF AGRICULTURAL PLANTS

Abstract: Intensification of cultivation of agricultural plants and their controlled nourishing by a combination of a chemical treatment and a suitable cultivation technology. Agricultural plants are treated with a composition containing 2-chloro-ethane-phosphonic acid, microelements and additives, in a certain stage of their development, in the vegetative phase, nitrogen fertilizer is applied to the plants simultaneously with or prior to the chemical treatement and a fungicidal treatment is carried out, if desired the number of stocks is increased, nitrogen fertilizer is applied in more portions and other technological measures are employed to increase the efficiency of the compositions. The invention provides an excellent possibility for increasing the value of plants and the crop yield.

Description: PROCESS AND COMPOSITION FOR CONTROLLED NOURISHING OF AGRI¬ CULTURAL PLANTS The invention relates to a process and a com¬ position by which the cultivation of agricultural plants can be intensified and their nourishing can be controll¬ ed, 5 In the cultivation of agricultural plants the planified influence of the biological ' state of plants plays a more and more important role. There are numerous compositions " known for this purpose, including for example 2-chloroethane-phosphonic acid and derivatives thereof 0 as active ingredient, 2-Chloroethane-phosphonic acid is disadvan ageous in that if it is applied at a relatively lai;e stage and under bad weather conditions, for example in drought, there is a danger of overdosing, which may cause in certain cases a depression of plant growth and e a decrease of the crop yield. According to the Published German Patent Appli¬ cation 2.62.0, 223 a combination of 2-chloroethane-phosphonic acid and one -of the following compounds: N- [(trichloro- methyl)-thio] -phthalimide, cis-N- [(trichloromethyl)-thio] - -li-cyclohexene-l-dicarboximide, cis-N- [(1,1,2, 2-tetra- chloromethyl) -thioj —Ji-cyciohexene-l,2-dicarboxamide, iron- (III) -dϊmethyl-dithiocarbamate, manganese-ethylene-bis- -dithiocarbamate, zinc—ethylene-ureic acid ethylester and tetrachloroisophthalic acid dinitrile is employed to accelerate plant growth. In the Published German Patent Application 2,207.575 N,N-dimethyl-piperidinium salts and in the Published German Patent Application 61.^.10 a combination of N,N,N-trimethyl-N-2-chloroethyl-ainjiionium chloride and 2-chloroethyne-phosphonic acid is disclosed as plant growth accelerating agent. According to the Published German Patent Application the N,N-dimethyl-piperidinium salts of 2-chloroethane-phosphonic acid can also be employed as plant growth regulators, Certain synthetic planfc growth regulating agents, such as chlorocholine chloride, succinic acid dimethylhydrazide, maleic acid hydrazide , diphenylurea, 2, -dichlorobenzyl-tributyl-phosphonium chloride, phenoxy- 5 isobutyric acid, etc. are also k ow in the art. 2-Chloro- ethane-phos honic acid and its derivatives, e.g. anhydrides, esters, salts and acid chlorides in addition to their plant growth regulating e ect , according to the British Patent Speci ication 1.33^-.850 improve the resistance . ϊ-0 of cultivated plants against certain plant diseases. The preparation of 2-chloroethane-phosphonic acid is disclosed in the United States Patent Specifica¬ tion 3.787.^-86. The application of this compound is per¬ formed using an aqueous solution by which the whole sur- 15 face of plants or seadlings is wetted. The solution con¬ tains 10-5000 pp , in particular 100-LOOO ppm of active ingredient. According 1 to the state of art it Is generally- advantageous to add micro- and esoelements (e.g. calcium, 20 magnesium, iron, manganese, copper, zinc, molybdenum, cobalt and bor in the form of soluble salts or chelates) as leaf-fertilizers , since they improve the crop yield. It has further been found that the nutrients administered through the leaves affect the metabolism of plants direct¬ d ~~ J ly, which has particular advantages when the absorption of nutrients via the roots Is inhibited for some reason. The lack of microelements results in disorders in the vital process of plants. The supply of microelements should be in a good correlation with the various local circum- 30 stances , which is an important factor to be taken, into account when selecting the appropriate compositions and route of application. Generally spoken, it can be concluded that there are numerous attempts to keep the crop yield at a stable 35 high level by using various formulations and employing '•' different methods, but none of them could so far garantee full security. To gain a satisfactory control over the complicated vital processes of plants complex measures or active ingredient combinations having a complex effect 5 on the essential factors affecting the crop yields are require . The elimination of the fluctuation of crop yields and the increase of crop yields belong to the most important goals in the agriculture and require the har- 10 monization of a large number of different factors, such as improving of plant varieties, combining various chemical treatments, use of appropriate cultivation parameters, etc. The invention relates to a process and a composi- !-5 tion by which a controlled nourishment of agricultural plants can be solved with a satisfactory security and the capacity of plants for accomodation to the given soil, wheather and rainfall conditions can be improved. We have recognized that the compositions coti- ~ taining a combination of certain complexes of the salts of microelements, mesoelements , urea and 2-chloroeth.ane- -phosphonic acid or a derivative thereof effectively in¬ crease the crop yields of agricultural plants without exhibiting any harmful side-effect, such as depression, -3 etc, , can minimize the losses due to uncertain and variable cultivation conditions, show no toxicity and fit xvell into the conventional cultivation procedure. The effect of the compositions containing more active ingredients surpasses the effect shown by its components- separately, if the 0 compositions are applied, in certain stages of the develop¬ ment of the agricultural plants (in the vegetative phase), nitrogen artifical fertilizer is added simultaneously or before their application, they are combined -with a fungi¬ cidal treatment and, if desired, the number of stocks in 5 the row is increased, the quantity of nitrogen fertilizer - k ~ is partitioned., and optionally deep fertilization is performed. The compositions according to the invention contain a combination of the following components, in 5 an aqueous solution or suspension: a) 0.1 to 80 by mass of a combination of meso- and microelements (expressed, in the mass of elements) in the form of complexes of the salts of said meso- and imcroelements , which contains at least 1° 5.10~ J by mass of zinc, 5.10 by mass of bor, 1.10>"3 * fa by mass of copper-, —3 1.10 o by mass of magnesium, 1.10 by mass of iron, 1^ 1.10 by mass of finely divided sulfur; b) 0.01 *to 25 fo by mass of 2-chloroethane-phosphonic acid, esters or salts thereof; c) 1.0 to 20.0 a d by mass of urea. The complexes of the salts of microelements ~ are chelates, which can be prepared from said salts with citric acid, acetic acid, glycine, ethylenediamlnetetra- acetic acid and salts thereof, nitrilotriacetic acid and/or a mixture thereof, in a known manner. The total active ingredient concentration in the compositions 2 5 amounts to 1 to 95 o by mass. The pH of the aqueous com¬ positions is adjusted to 3.5 to 4.0, The finely divided sulfur, used as a mesoelement, has a grain size below 5 micro s, The compositions can be " prepared by more al- 30 ternative methods. According to a variant, the mono- chelates of the salts of microelements are first pre¬ pared, 2-chloroethane-phosphonic acid is added, the pH is adjusted to 2 to 2.1, sulfur and conventional addi¬ tives are added, the crude suspension obtained is dis- 35 persed In a colloidal mill or any other humid grinding - 3 ~ equipment, and as soon as the required dispersity grade is achieved, urea is added. According to another embodiment, to a solution of microelements and 2-chloroethane-phosphonic acid, the pH of which is adjusted to 2 to 2.5, sulfur, urea and the required additives are added prior to application. According to a third method, the chelates of microelements and 2-chloroethane-phosphonic acid are add¬ ed to a concentrated suspension of finely divided sulfur, the pH is adjusted to 2.1 to 2.5 and urea and further additives are added to the diluted, composition. According to a fourth method, 2-chloroethane- phosphonic acid is added to the chelates and the finely divided sl ur suspension, the pH -is adjusted to 2 to 2.5, and a portion of urea is added. The remaining portion of sulfur suspension and urea as well as the further addi¬ tives are added after the final dilution. According to a fifth method, the salt of micro¬ elements are added to the diluted," colloidal sulfur sus- pension, in the solution obtained complexes are formed, by adding the tetrasodium salt of ethylenediaminetetra- acetic acid, and the pH is adjusted to 6.5 to 7.0 by hydrochloric acid. To the diluted composition 2-chloro- ethane-phosphonic acid, colloidal sulfur suspension and urea are added, taking care that the pH should not exceed 4.5. Finally, the composition is supplemented with the conventional further additives. In addition to the above methods there are numerous further methods, by which the compositions ac- cording to the invention can be prepared. 2-Chloroethane-phosphonic acid is employed as an aqueous solution containing 4θ to 50 by mass of ac¬ tive ingredient. The sulfur suspension used, preferably contains 900 g./lit. of sulfur, in the form of a colloi- dal sulfur with a grain size below 5 microns. Suitable OMPI compositions include Sulfur 900 ¥ (Budapest! Vegyimiivek) , Thiovit (Sandoz AG) , Sofril (Rhone Poulenc), Kumulus S WP (BASF), etc. The microelements zinc, magnesium, bor, copper, iron are employed in a suitable form, for example as concentrated solutions containing glycine and./or nitric acid, but complexes with nitrilotriacetic acid are also suitable. Preferred representatives of the derivatives of 2-chloroe hane-phosphonIc acid include anhydride, acid chloride, mono-2-chloroeth l ester and further esters. Urea is employed as a concentrated aqueous solution or in the form of a crystalline, commertially available composition. Due to the acidic pH .of the compositions, preferably wetting agents with a pH of 2 to 4 are em¬ ployed. They are generally prepared by combining the following components: alkylbenzenesulfonic acidcalcium salt, alkylphenolpolyglycol ether and propyleneoxide- -eth leneoxide condensate. A suitable commertial product is for example Tensiofix B 7416. Combinations of ox- ethylated alkylphenolphosphate esters and alkyl benzene- sulfonic acid calcium salt are also suitable. The solid phase can generally be dispersed by the aid of mixtures of anionic and non-ionic additives. The compositions are preferably applied, to the plants by air, in an amount of 50 to 80 lit. hectare, but • for example in the case of grains conventional ground agricultural machines can also be employed, and. the amount of tank mixture is about 200 to 400 lit,/ha. The compositions according to the invention are particularly suitable for the controlled nourishment of agricultural plants, such as cereals, maize and sun- flower, OMFT In case of cereals the compositions are em¬ ployed about the "end of the period when the plants grow thick (in the F-g and J stage according to Keller- Baggiolini) , in an amount of 7 to 15 lit,/ha, using 0 to bO lit/ha, of tank mixture in the case of cereal application and 200 to 350 lit./ha of tank mixture in the case of ground application. Treatment Is prefer¬ ably combined with the application of fungicides and insecticides. If desired, the treatment is repeated, immediately after the appearance of the second nodus of the plant (stage J according to eller-Bagglolini) , 20 to 30 mass parts of the N-fertilizer required is applied in autumn, while the remaining portion in spring, top dressing Is repeated 2-3-tirαes. In the case of short-stem wheat varieties 5-2.2 lit,/ha. , for intermediate stem ' lengths 7-14 lit,/ha. , for high lengths 8-15 lit./ha, doses are employed by air, applying 50 to 80 lit,/ha. of spray on the plants. Ground application is also possible. The treatment improves the ste strength. If the stems are short , the culture is thin (below 500 plan s/m ) and under dry weather conditions no second treatment is necessary, otherwise it is advis¬ able to repeat the treatment. A nutrient supply corre- sponding to the level of crop yield of the culture treated and a balanced nitrogen supply should be ensured. If herbicides with a hormone effect are em- •/• ployed, the herbicidal treatment should be carried out 8 days before or after the application of the regulator, In the latter case, about 70 _£ of the prescribed dose should be employed. In maize cultures, on soils having a good nutrient level the treatment should be carried out on 60 to 100-cm. plants, in a dose of 6-14 lit./ha. , using 250 to 350 lit,/ha, of tank mixture by air or 50 to 80 lit./ha. on the; ground. If the area is deep, with internal water and the soil ' is impermeable, maize should be treated in a 6θ-8θ-cm, stage, in a dose of 4-14 lit./ha. , preferably A nutrient supply corresponding to the crop yield level of the treated culture and a balanced nit¬ rogen supply should be ensured. The number of .stocks is about 65-120000 pieces/ha. , depending on the required level of crop yield and the moisture. 0 to θ parts of the required nitrogen fertilizer Is applied in autumn, and the remaining part in spring, 1m one or two portions. Top dressing is also performed. When choosing the most suitable variety and hybrid, those tolerating a more dense cultivation are preferred. Sunflower is treated in a 10-12-leaf stage (50-60 cm) by ground or aereal technique, using 250- 350 lit./ha. and 50-80 lit./ha. of tank mixture, res- pectively, as follo s: In case of hybrids with a short stem length 6-10 lit./ha. , for intermediate stem lengths 8-10 lit./ha. and for long-stem plants 10-15 lit./ha. doses of the composition are applied. A nutrient supply corresponding to the level of crop yield of the culture treated and a balanced nitrogen supply should be ensured. The total amount of nitrogen fertilizer required is applied in spring. The denseness of the plants should exceed the conventional va-lue by 10 to 25 , depending on the crop yield required. Accordingly, varieties and hybrids tolerating a more dense cultivation are preferred. The following technological conditions are required : - nutrient supply (macro- and microelements) corresponding to the desired crop yield, in a suitable quantity, quality, variety and timing; - deep ertilization, due to deep roots of plants ; - in case of maize and sunflower a 20-30 fo increase of plants, already at seeding, in case of cereals control of the period when the plants grow thick; - a proper selection of row and stock distance, since shorter plants require a smaller cul¬ tivation area; - motorization corresponding to the altered technology. Under the above conditions the average crop yields are increased by about 20-40 fo related to the control, and the nutritive value of the plants remains unchanged or even improves. . The increase of crop yields and the improve- ment of the quality of the crop is due to the following factors : - increase of the stamina of plants (resistance to lodging and. stem-breaking); - increase of drought tolerance, increase of the root surface an the depth of growth, acceleration of the mechanism of the res¬ piratory holes; - elimination of the harmful side-effects of nitrogen excess (loosening of tissues , lodging, susceptibility to plant diseases, etc.) as OIfFI a result of which the crop yield increasing and quality improving effects of nitrogen can be made use of; - the treated plants show and improved, re- 5 sistance to impermeable soils, which are temporarily covered by water; - due to the substantial root remedies the humus content of the soil can be preserved, or even increased; 0 - by improving the nutrient uptake capacity of the plants the nutrient supply can also be increased; - * the resistance to facultative parasites caus¬ ing necrosis is Increased (e.g.' various fungi); 5 - due to morphological grounds the plants show an Increased resistance to maize moth; - the quality and value of the products (e.g. beakery value, protein content, etc,) are substantially improved; _ nutrients can be better absorved through leaves ; - a more balanced plant culture is obtained; - the energy required to keep the treated plants in life is lower than usual; D - the efficiency of the photosynthesis is im¬ proved. The results obtained by the cultivation tech¬ nology according to the invention and the specific tech- ° nological steps are set forth in the following tables. OIvlPI Change of the nutritive value of wheat 8-10 days after treatment on soilra with a good and medium supply expressed in the average of 3 years Treatment N P it Na Mg Ca Cu Fθ Mn Zn B so Control - - - - - - - - - - - - 2-ohloro- in the strong decrease strong strong in- do- very strong do- strong decrease strong ethyl-phos- leaves decrease decrease increase crease crease strong decrease crease in- decrease phonic acid decrease crease c orresponding to the amount in the slight slight slight strong in- slight constant constant de- increase constant in the com- roots in- in- im¬ increase crease in¬ crease crease position of crease crease crease crease E-xatπple 3 Composition in the cotι-> slight con- medium in¬ con- alight constant slight in¬ cons tant cons tant leaves stant in- stant crease si iint de¬ de¬ crease crease crease crease roots crease in¬ in¬ crease crease ctoase increase crease crease crease crease Table 2. The uncoliventional parameters in the cultivation of the most important culture plants technological Wheat Mai' o Sunflower measures εmcl, parameters T T I T stocks number/ha. 50-80 65-120 35-55 50-80 ear number (p/acre) '.00-600 600-950 fertilization quantity related to the conventional • grows grows grows fertilization in autumn (fh ) 60-70 20-30 60-75 0-*K> '|0 in spring ( ) 30-kθ 70-80 30-^0 100-60 60 100 spring fertilization (top dressing: number H of starter fertilization) 1-2 1 use of composition once 1-2 times once once s age of application II-M P-G J όs - -10 leaf k-9 pair of K-L st ge real leaves Rema d s : ± ) X = known technology T = according to the invention 2 ) x = phenologyca l Kollor-llaggioliui Rev. romande Agric, Vitic Arboric, 19 *1. 10/3/ 1-7-30 3) the limits depend also on the technology, plant variety, soil. The biological results obtained according to the invention are further illustrated by the following Examples. Preparation of compositions , Example 1 An aqueous suspension containing the necess¬ ary additives in addition to the active ingredients is prepared. The composition is generally applied by plane or ground technique, in 0 and 00 lit, of water, respec¬ tively. When applied as a tank mixture the composition can be supplemented with urea. The volume weight of the composition is adjusted to 1,65-1.70. Components " Concentration (v/w fo ) in the in a tank mixture composition (ground applica¬ tion) Zn 0.128 0.0060 B 0.024 0.0008 Cu 0.1 0.005 Mg 0.145 0.005 Fe 0.210 0.008 2-chloroethane- phosphonic acid. 0.500 0.025 elementary sulfur 66. 600 2.360 urea - 1.260 ethyleneglycol 3.600 0.13 Ultrasin NA 1.8 0.06 Rodopol 23 0.12 0.0044 Tensibfix XN6 0.5^ 0.020 - 14 - To prepare 1 lit. of the above composition 8.4 g. of citric acid and 25 ml. of a 96 fo acetic acid are employed. 2-chloroethane-phosphonic acid is added to the solution after the adde ion of the complex- orming acids, whereupon the pH of the solution is adjusted to 2-2.5 by ammonium hydroxide. Thereafter sulfur is added in a crude disperse form, followed by the addition of the further additives, and the final volume is made up to 1 l±t. The obtained .crude dispersion is dispersed in a colloidal mill or any other wet milling equipment until the grain size of sulfur is suitable. Example 2 An aqueous suspension having the following composition is prepared: Components Conceintratioci (v/w fo) in the in a tank mixture compos tion round applica¬ tion) Zn 1,15 0. .03 B 0.38 0. ,01 Cu 1.15 0. .03 Mg 0.72 0. ,02 Fe 1.18 0. .035 2-chloroethane- phosphon c acid 15.20 0. .500 elementary sulfur - 0 ,400 urea - 1. ,200 Ultrasin A - 0. -23 Tensiofix XH6 - 0. ,002 volume weight: 1. 31 υ ' - ^ OV? First the citric acid/acetic acid complexes of the microelements are prepared, as described in Example 1. Instead of the salts of the microelements zinc and iron an equivalent amount of Sequestren Na„Zn (powder, chelate formed with ethylenediamine-tetraacetic acid, contain¬ ing 6 mass fo of zinc) or Sequestren 330 Fe (containing 10 mass fo of iron) in the form of ethylenediamine-tetra¬ acetic acid chelate, Ciba Geigy, Switzerland) can also be employed. Thereafter 2-chloroethane-phosphonic acid is added to the composition, and the pH is adjusted to 2.1 by ammonium hydroxide. To the tank mixture the necess¬ ary amounts of sulfur (Sulfur 900 FW) and urea are added. Example 3 An aqueous suspension having the following composition is prepared: Components Concentration (w/w fo ) in the in a tank mixture composition (sround applica¬ tion) Zn 0.81 0.023 B 0.08 0.0023 Cu 0.54 0.015 Fe 0.63 0.020 -chloroethane- phosphonic acid. 7,23 0.21 elementary sulfur 31.60 0.90 urea - 0.17 Ultrasin NA 6. 9 0.17 Rodopol 23 0.47 0.13 Tensiofix XN6 1.0 0.28 volume weight: 1.3 - y-÷ j i To prepare 1 iir. of the above compositon 150 ml. of water are added to 456 ml. of an aqueous sulfur suspension, whereupon the citric acid/acetic acid com¬ plexes of the microelements are prepared as described in Example 1. As a co plexing agent 26.5 g. of citric acid, 80 ml. of a 96 fo acetic acid and 12.1 g. of ethylene- diamine-tetraacetic acid-sodium are employed, ∑nstead of the salts of iron and zinc the Sequestren compositions given in Example 2 may also be used. To the composition obtained 9k-.1 g. of 2-chloroethane-phosphonic acid are added, and the pH of the suspension is adjusted to 2,1-2,4 with aqueous ammonium hydroxide. The volume of the sus¬ pension is made up to 1 lit. with water, and in case of tank mixture the necessary urea is added separately. Example 4 An aqueous dispersion of the following com¬ position is prepared : - 17 - Components Concentration (w/wfo) in the in a tank mixture composition (ground, applica¬ tion) Zn 0, 8 0.015 B 0.16 0.004 Cu 0.42 0.011 Mg O.65 0.020 0 Fe 0.50 0.013 2-chloroethane- phosphonic acid 12.20 0.330 elementary sulfur 8.13 0.91 urea 16.30 1.20 5 Ultrasil NA 7,3 0.17 Rodopol 2 0.5 0.13 Tensio ix XN6 1.05 0.28 volume weight: 1.23 r) To prepare 1 lit. of the above composition 250 ml. of water are added to 110 ml. of an aqueous sulfur suspension, followed by the addition of the citric acid/ acetic acid complexes of the microelements. As a complex- ing agent 21 g. of citric aced, 64 ml. of a 96 f > acetic acid and 8.8 g. of ethylenediamine-tetraace ic acid- a are employed. Thereafter 150 g. of 2-chloroethane-phos- phonic acid is added, and the pH is adjusted to 2.0-2.1 by aqueous ammonium hydroxide. To the composition 200 g. of urea are added, and it is made up to 1 lit. with water. To a tank mixture sulfur and a further portion of urea are also added, to " ensure the required concentra ¬ tions. Example 5 An aqueous dispersion having the following composition is prepared: Components Concent ration (w/w f>) in the in a tank mixture composition round applica¬ tion) Zn 0. 57 0. 015 B 0. 13 0. 004 Cu 0. 4l 0. 011 Mg 0. 64 0. 020 Fe 0. 49 0. 013 2 -chloroe thane - phosphonic acid - 0. 33 e ' lementary sulfur 8 . 00 0. 91 urea - 1.20 - Ultrasin NA 4.80 0. 12 Rodopol 23 0.50 0. 013 Tensiofix XN6 ι. o4 0. 028 vo lume we igh t : 1.25 To prepare 1 lit. of the 'above composition 250 nil. water- are added to 110 ml. of an aqueous sulfur suspension, and the salts of the microelements are dis¬ solved in the suspension obtained. The salts of the micro ¬ elements are converted into the corresponding complexes by ethylenediamine-tetraacetic acid-Na. The pH is adjusted to 6.5 to 7.0 by hydrochloric acid of technical grade. To prepare a tank mixture to the necessary amount of 2-chloroethane-phosphonic acid the above sus¬ pension is added, followed by the addition the necessary amounts of colloidal sulfur and urea. The pH of the tank mixture is about 4.5. Biological Examples Example 6 The composition according to Example 3 w s employed, to increase the crop yield of autumn wheat. 4-9 lit./ha. doses of the composition were applied to the plants in the stage F-G and J, by spraying twice. Phosphorus and. potassium fertilizers should be applied, in autumn, in an amount corresponding to the de¬ sired crop yield, ∑n fields where the Zn and Cu concen- tration of soil is low, these and if desired, further microelements should be supplemented by a single ferti¬ lization, in an amount corresponding to the desired crop yield. If the Zn and. Cu concentration is extremely low, they can be supplemented also in spring by leaf-fertili- zation. About 20 to 30 fo of the nitrogen corresponding to the desired crop yield should be applied to the fields • as a basis-fertilizer. After papilionacea-e this treatment can be omitted, while after maize and sunflower the nit- rogen amount required to decompose the remaining organic materials is advantageously added in autumn. On impermeable and sandy soils, to avoid de- - nitrification and washing off, nitrogen is preferably applied in the autumn, in the form of urea, (nitrogen stabilizers are preferably also employed, e.g. }.-Serve, DOW Chemical, USA). The nutrient supply of the deeper layers of soil and. deep fertilization are of utmost importance. It is further important that the desired, crops yields can be increased, by 10 to 30 fo, preferably 20 to 2 % related to the usual levels. On good soil having a high nutrient concentration, when a variety providing a good, crop yield is selected, even a yield of 10 tones/ha. can be achieved for 950 stocks/m . The remaining portion of nitrogen fertilizer O- is applied in spring, as a top dressing. The first top dressing should, be carried out several days, before the start of the spring vegetation, depending on the number of stocks which have lived through the winter and the nitrogen supply of the soil: - in a thin culture (3-^.5 millions of stocks/ha. ) about 40 to 45 fo of the total calculated nitrogen amount should, be applied, depending on the nitrogen supply of the soilj - at a stock number- of 4,5 to 6.0 millions/ha, 35 to 4θ fo of the total nitrogen demand should be applied; - over a stock number of 6.0 millions/ha, 30-36 fo of the calculated nitrogen demand should be applied to the plants. The first chemical treatment with a composi¬ tion according to Example 3 should be carried out in the E-G stage according to Keller-Baggiolini, after the first top dressing, using 7-12, preferably 9-o lit. ha. of the composition (or a corresponding amount of active in¬ gredients). The composition can be applied to the plants by ground or areal technique as well, using 200-300 and 50- -90 lit./ha. tank mixture, respectively. The secon top dressing is performed in the stage I of the wheat development according to Keller- Baggiolini, before the second chemical treatment. By this second top dressing the remaining portion of the total nitrogen amount required, is applied. The second chemical treatment can be carried out directly after the appearance of the second nodus o wheat, when the small, opened ear of corn is about 1.5-2.0 cm. (according to Keller-Baggiolini in the J stage of wheat development) 4-9, preferably 5 lit./ha. doses are employed, For verieties with a short stem length only the first treatment is necessary. For varieties with a medium stem length, over 600 ear/m , in rainy weather, for rich soil with a good nitrogen supply two chemical treatments are necessary. In case of varieties with a long stem length the second, chemical treatment should, be omitted, only in extrem drought. The composition should be applied, by air, using 50-90 lit./ha. of a tank mixture but ground tech¬ niques can also be employed. It is very advantageous to carry out this treat¬ ment directly after a bigger rainfall. The third, top dressing is carried out in the K-L stage of the development of wheat (Keller-Baggiolini); taking into account the nitrogen supply, denseness and crop yield about 30-35 kg./ha. of nitrogen are employed, over the calculated value, if the nitrogen supply of the soil is not satisfactory for some reason. The plant protection is carried out according to modern agricultural techniques, corresponding to the situation and the number of weeds. If a hormon-like her¬ bicide is employed, the chemical weed-killing is per¬ formed 7 days before or_ after treatment with the composi¬ tion according to Example . If the herbicide treatment is carried out after the treatment with the composition of Example 3, about 70 fo of the usual herbicide dose should be employed. Protection against pathogenes, in particular mildew, fusarium and. rusts should, be carried, out with - special care. On fields, where wheat is cultivated in more subsequent years, a Benomyl-containing tank mixture or any other fungicide generally used for this purpose should, be employed, when the plants grow thick. The necessary fungicide and insecticide treat¬ ments can be carried, out simultaneously with the composi- tion of Example 3. It is, however, advisable to inves- - o o — tigate before admixture, whether the various components are freely admissible. The results are illustrated in Table 3 - Table 3 Increase in crop yields of autumn wheat Variety Treated Control area (ha) average area (ha) average crop crop yield. yield, (tones/ha) (tones/ha) Szava 3+3 7.23 3+3 6.10 GK-Szege 3+3 7.30 3+3 5.60 - Example 7 The composition according to Example 3 was employed, to increase the crop yield of autumn barley. The barley was treated in the stages F-G and J, using the pre- scribed doses. The P and K fertilizers were applied in an amount corresponding to the desired crop yield, as a basic fertilizer. On fields, where the soil has a low Zn and Cu concentration, these and further necessary micro- elements should, be supplemented, simultaneously with the basic fertilization, in an amount harmonized with the desired crop yield. If the soil has a great Zn and Cu deficiency, the demand of plants can be met in spring¬ time, in the form of leaf-fertilization. 20-30 f> of nitrogen necessary to achieve the desired crop yield, is applied also as a basic fertilizer. After papilionaceae this treatment can be omitted, but after maize or sun lower a nitrogen amount required to decompose the remaining organic materials, should, also be added in autumn. G1 H On impermeable or sandy soils, due to the dan¬ ger of denitrification and. washing off, nitrogen is pre¬ ferably applied, in autumn, in the form of urea (the use of nitrogen stabilizers, e.g. N-Serve, DOW Chemical, USA 5 is advisable). The deeper layers of soil should, preferably have a good nutrient supply, which can be improved, by deep fertilization. In this manner crop yields exceeding the conventional results by 10-30 fo, preferably 20-35 fo 10 can be achieved. On rich soils, using carefully selected varieties, ensuring a good, yield, even crop yields ex¬ ceeding the above limits can be achieved. The remaining portion of nitrogen is applied in spring, as a top dressing. -3 The first top dressing should be carried out several days before the start of the spring vegetation, depending on the number of stocks which have lived through the winter, and the nitrogen supply of the soil: - in a thin culture (3-4.5 millions of stocks/ha.) 0 about 40-45 o of the total calculated nit¬ rogen amount should be applied, depending on the nitrogen supply of the soil; - at a stock number of 4.5 to 6.0 millions/ha. 35 to 40 fo of the total nitrogen demand 5 should be applied; - over a stock number of 6.0 millions/ha. 30 to 3 fo of the calculated, nitrogen demand should be applied to the plants. The first chemical treatment with a composi- ° tion according to Example 3 should, be carried out in the E - G stage according to Keller-Baggiolini, after the first top dressing, using 8-12, preferably 8-9 lit./ha. of the composition (or a corresponding amount of active ingredients). The composition can be applied to the plants by ground, technique or by air as well, using 200-300 and OI-£? 50-90 lit./ha. tajik mixture, respectively. The second top dressing is performed in the I stage of barley development , according to Keller-Bag¬ giolini, before the second chemical treatment. By this second top dressing the remaining portion of the total nitrogen amount required is applied. The second chemical treatment with the compo¬ sition according to Example is carried out directly after the appearance of the second nodus of barley, when the small, opened ear of corn is about 2.0 to 2.5 cm (stage J according to Keller-Baggiolini). 4-10, prefer¬ ably 5-6 lit./ha, doses are employed, using 50 to 90 lit./ha. of tank mixture when applied by air. When spraying the .soil should be humid enough. It is therefore advantageous to carry out the treat¬ ment after a bigger rainfall. The third top dressing is carried out in the ' K- stage of development (Keller-Baggiolini) : taking into account the nitrogen supply, denseness and crop yield about 30-35 kg./ha, of nitrogen are employed, over the calculated value, if the nitrogen supply of the soil is not satisfactory for some reason. Plant protection is carried t according to modern agricultural methods, corresponding to the situa- tion and the number of weed ' s. If a herbicide is employed, the chemical weed- -killing is performed 7 days before or after the treatment with a composition according "to Example 3* If the herbicide treatment is carried out after the treatment with the com- position of Example 3. about 70 fo of the tisual herbicide dos should be employed from a hormon-like herbicide. Protection against pat ogenes, in particular mildew should be carried out with special care. The necessary fungicide and insecticide treat- ments can be carried out simultaneously with the chemical treatments. It is, however, advisable to establish before admixture, that the various components are free¬ ly admiscible. The results are shown in Table 4. Table 4 Increase in crop yield.s of autumn barley Variety Treated. Control area (ha) average area (ha) average crop crop yield. yield (tones/ha) (tones/ha) early "Ko polti" 3+3 8.50 50 6.20 X x = barley has shown a strong lodging Example 8 A composition according. to Example 3 was em¬ ployed to increase the crop yield of maize. Maize was treated with a 9 lit./ha. dose of the composition in a 10-leaf stage. The number of stocks was adjusted to The crop yield can be adjusted to 7-17 tones, depending on the stock number, variety or hybrid, fer¬ tility of the soil and the employed cultivation tech¬ nology. As a basic fertilizer P and K fertilizers are used in an amount, corresponding to the desired, crop yield. They are applied, in autumn. On fields -with a me¬ dium Zn and Cu supply or a low Zn and. Cu concentration due to the N-Cu and P-Zn ion antagonism, Zn and. Cu is supplemented, parallel with the basic ertilization. 0-40 of the total N-demand should, be ap¬ plied, as a basic fertilizer, either in the form of urea or as ammonium nitrate. (On the basis of soil investi¬ gations also other nitrogen fertilizers can be em¬ ployed. ) After maize or sunflower it is advisable to carry out a basic ertilization with nitrogen in autumn. 5 Deep fertilization has an important role, too. The remaining portion (100-60 fo) of the nit¬ rogen fertilizer can be applied in one portion, in spring. To ensure a continuous nitrogen supply nitrogen stabilizators (e.g. 5f-serve) are preferably employed. 0 i is advisable to apply the spring nitrogen in two portions , a larger portion before sowing and the remaining portion when the maize plants are 50-70 cm. high. Maize is treated with the composition accord- -3 ing to Example 3. taking into account the type of the soil, the nutrient supply of soil, plant variety or hybrid, stock number and the desired crop yield, in a dose of 5-12 lit./ha. , preferably 6-8 lit./ha. , in a 5-10-leaf stage. The treatment is always combined with the use of a 46 fo urea, in an amount of kg./ha. Treatment can be performed by air or by ground techniques. The uniform distribution is an important re- quirement. 5 The results obtained are illustrated, by Table 5« Table 5 Increase in the crop yield of maize Variety Treated Control 0 area (ha) average area (ha) average yield yield (tones/ha.) (tones/ha.) MV-580 0.5 8.20 1.0 6.4θ X 5 x = seriously infected, with Fusarium OMPI Example 9 The composition according to Example 3 was used to increase the crop yield, of sunflower. 50-6θ-cm. sunflower plants were sprayed, with a dose of 11 lit./ha, 5 Stock number is adjusted to 50000-80000/ha. The desired crop yield can be between 2.5 and 4.5 tones, depending on the stock number, variety or hybrid, fertility of the soil and. the cultivation tech¬ nology employed. 0 Basic fertilization (P and K) is applied in autumn, in an amount corresponding to the desired crop yield. As a spring basic fertilizer nitrogen is ap¬ plied in a dose of 80-150 kg./ha. of active ingredient, ^ depending on the nitrogen supply of the soil and the de¬ sired, crop yield. If nitrogen supply is poor or the de¬ sired crop yield, is high, 150 kg./ha. amounts are used. On impermeable soils nitrogen is preferably employed in the form of urea or as ammonium nitrate. Chemical treatment with the composition ac¬ cording to Example 3 is performed on 50-6θ cm. high sun¬ flower plants (4-9 pairs of developed leaves), in a dose of 5-11 lit./ha. by air or by ground technique. It is important to ensure a uniform distribution of the tank -> mixture. Treatment is carried out by applying nitrogen in an amount of 5 kg./ha. , preferably in the form of urea and 1-2- lit. of a sulfur composition in the form of sul- ate (e.g. Fitohor 325) or 2 kg. or lit. or a composi- tion containing elementary sulfur, simultaneously in the form of a tank mixture. The results are set forth in Table 6. Table 6 Increase in the crop yield of sunflower Variety Treated Control area (ha) average area (ha) average yield yield (tones/ha.) (tones/ha.) Sorem 80 3 2.40 ' 60 1.70 2+2 2.60 6 1.80 Example 10 The composition according to Example 5 was used to increase the crop yield, of autumn barley. Plants were treated in the stages F-G and J, with a dose of 10 lit./ha. twice. Otherwise the procedure described in Example 7 was followed. The results obtained are summarized in Table 7« Table 7 Increase of crop yield of autumn barley Variety Treated Control area (ha) average area (ha) average yield yield (tones/ha. ) (tones/ha. ) "Kompolti" early 100 6.6θ X 6 5. 0 X x = the control plants lodged, in the middle of May, the treated ones at the beginning of June Example 11 The composition according to Example 5 was em¬ ployed to increase the crop yield of autumn wheat. Szava and. GK-Szeged. varieties were treated in a dose of 2 x 8 lit,/ha. , Partizanka in a dose of 2 x 9 lit./ha. , MV-8 first with a dose of 9 lit./ha. and then 8 lit./ha. , in stages F-G and J. Otherwise the procedure described, in Example 6 was followed. The results are shown in Table 8. Table 8 Increase in crop yield, of autumn wheat Variety Treated Control area (ha) average area (ha) average yield. yield, (tones/ha.) (tones/ha.) Szava 43 8.20 ιo4 6.80 35 8.80 1 6.90 T-6 8.50 • 2 5.80 x GK-Szeged 8 8.30 40 7.10 Partizanka 11 7.30 8 5.^0 MV-8 32 7.25 • 17 5.20 3 + 3 9.50 6 6.80 x = the plants lodged, in early May Example 12 The composition according to Example 3 was em¬ ployed to increase the crop yield of maize. Maize plants were treated in a 10-leaf stage, using a 12 lit./ha. dose Otherwise the procedure described, in Example 8 was fol- lowed. The results obtained are shown in Table 9. Table 9 Increase in crop yield of maize Variety Treated. Control area (ha. ) average area (ha. ) average yield. yield (tones/ha. ) (tones/ha. ) Pionir - 30 - Table 9 (continuation) Variety Treated Control area (ha. ) average area (ha. ) average yield. yield (tones/ha. ) (tones/ha. ) 3+3+3 9.70 111 8.90 3+3+3 71 Pionir 3780 3 8.80 6 8.20 U-530 x 1+1 9.60 42 9.10 JX-92 1+1 10.30 9.60 Pionir 3732 3+3 13.40 57 10.40 x = harvesting with combine Example 13 By the composition according to Example 3 50-60 cm. sunflower plants were treated in a dose of 11 lit,/ha. Otherwise the procedure described in Example 9 was followed. The results obtained are shown in Table 10. Table 10 Increse in crop yield of sunflower Variety Treated Control area (ha. ) average area (ha. ) average yield, yield (tones/ha. ) (tones/ha. ) NSH-27 2+2 2.70 20 1.80 2+2 2.40 28 1.70 Iregi striped 1+1 2.60 40 1.90 o:α > ι Example l4 Autumn wheat was treated, with the composi¬ tion according to Example 5 in a stage defined, in the previous examples. For comparison in a test only 2- -chloroethane-phosphonic acid was employed., in a dose corresponding to the composition according to Example 5. The results obtained are shown in Table 11. Table 11 Effect of a composition according to the invention on the increase in crop yield, of autumn wheat Treatments Dose Time of spraying Average (lit./ha.) 1. 2. crop yield (tones/ha. ) Control - 6.7 -chloroethane- phosphonic acid 3-0 April May 6 6. 6 ccoommppoossiittiion aaccccoorrddiinngg to 9.0 April 3 May 6 ' 7.6 Example 5 Example 15 The growth of maize was examined, .inder the effect of 2-chloroethane-phosphonic acid alone or in a composition according to Example » The results ob¬ tained, are shown in Table 12. Table 12 Effect of a composition according, to the invention on the growth of maize Treatments Dose Time of Average Remark (lit./ha. ) spraying crop yieId (tones/ha. ) Control - 9.6 2-chloroethane- phosphonic acid. 3.0 June 18 9.8 the stock number was 105 thousands when using the composi¬ tion of Example 5 and 85 thousands for the control Composition of Example 5 11.5 June 18 11.9 The trial was performed on plots of 3 hectares , in one repetition. Example 16 The effect of the composition according to Example 4 on the crop yield of sun lower was compared to the effect of an equivalent dose of 2-chloroethane- -phosphonic acid. Sunflowers were sprayed with the cor¬ responding compositions in a stage described in the pre¬ vious example.. The results obtained are shown in Table 13, OMPI Table 13 The effect of a composition according to the invention on the crop yield, of sunflower Treatments Dose Time of Average (lit./ha.) spraying crop yield (tones/ha. ) Control — - 18 . 5 2-chloroethane- phosphonic acid. 3. 0 June 14 20. 4 composition of Example 4 8. 0 June 14 24. 6 The trials were performed, on plots of 3 hec¬ tares, in two repetitions.

Claims: Claims 1. Composition for controlled nourishing of agricultural plants, in particular cereals, maize and 5 sunflower and for the intensification of their cultiva¬ tion, which comprises in an aqueous solution or suspen¬ sion a combination of a) O.1 to 80 by mass of a mixture of esό- and microelements in the form of the complexes of their 10 salts, expressed, in elements, which contains at least , 5.10 fo by mass of bor, 1.10~ J fo by mass of copper, 1.10 fo by mass of magnesium, 1.1.0 fo by mass of iron, • 1.10 fo by mass of inely di id.ed. sulfur; b) ' 0.01 to 25 o by mass of 2-chloroethane-phosphonic acid . or esters or salts thereof; and 20 c) 1.0 to 20.0 fi by mass of urea, in a total amount of 1.0 to 95.0 fo by mass, in admixture with additives suitable for the lotation and/or dis¬ persion of the solid, phase and wetting agents. 2. A composition according to claim 1, which com- ^ prises as complexes of the salts of microelements metal chelates,- preferably monochelates. 3. A composition as claimed, in claim 1 or claim 2, which comprises chelates prepared, from micro¬ element salts by citric acid, acetic acid, -glycine, 3° ethylenediaminetetraacetic acid or salts thereof * nit- rilotriacetic acid and/or mixtures thereof. 4. A composition as claimed in 1, in which the pH of the aqueous composition is below 4.0. 5. A composition as claimed in claim 1, in 35 which the grain size of the finely divided sulfur is OMPI below 5 microns. 6. A composition as claimed, in claim 1, in which the additives suitable for dispersing are acidic and preferably are alkylbenzenesulfonic acid salts, ^ alkylphenol-polyglycol ethers or ethyleneoxide-propylene- oxide condensates. 7. A process for the controlled nourishment of agricultural plants , preferably cereals , maize and sunflower and for the intensification of their cultiva- tion, which comprises treating the agricultural plants with a composition according to any one of claims 1 to 6, in the vegetative phase, in a determined stage of development, adding nitrogen and carrying out a fungicidal treatment simultaneously with or prior to the cemical treatment, if desired,, increasing the stock number of the plants to be cultivated and dividing the total quantity of nitrogen fertilizer to more portions and optionally carrying out a deep fertilization. 8. A process as claimed -in claim 7 for the cultivation of wheat or autumn barley, in which 20-30 mass parts of the nitrogen fertilizer to be employed are added, in autumn, while the remaining part is applied in spring, top dressing is repeated two-three-times , plants are treated with any one of the compositions according to claims 1 to 6 in a stage E-G and J (accord¬ ing to Keller-Baggiolini) once or twice, preferably in combination with a fungicidal and. insecticid.al treat¬ ment. 9. A process as claimed, in claim 7 for the cultivation of maize, in which 0-4θ mass parts of the nitrogen fertilizer are applied, in autumn and the remain¬ ing portion in spring, the stock number is increased, to 65-120 thousand/ha, , top dressing is carried out and maize is treated with a composition according tα.any one of claims 1 to 6 in a 5-10-leaf stage. y E ϋ^ 10. A process as claimed, in claim 7 for the cultivation of sunflower, in which the total amount of the nitrogen fertilizer is applied to the soil in spring, the stock number is increased by 10-25 & and the plants are treated, with composition according to any one of claims 1 to 6 in a stage, when they have 4 to 9 pairs of leaves.

Inventors: CSANYI ROZA, DIENES LAJOS, INCZEDY PETER, KARSAI JOZSEF, CSANYI, ROZA, DIENES, LAJOS, INCZEDY, PETER, KARSAI, JOZSEF
Applicants: BUDAPESTI VEGYIMUEVEK
Application year: 1983
Main classification: A01N59
IPC codes: A01N25, A01N41, A01N47, A01N55, A01N57, C05C9, C05D9