PROCESS OF MANUFACTURING PRINTED WIRING BOARDS AND PRINTED WIRING BOARDS MANUFACTURED BY THE SAME

Abstract: A printed wiring board of this invention can be obtained by the steps of: making holes in the necessary portion of a copper-clad laminate; forming a catalytic layer on said hole walls and copper foil by pretreatment for electroless plating; forming an etching resist film on necessary lands and circuits; melting-off the copper foil and catalytic layer on the unnecessary portion of said copper-clad laminate by etching; melting-off or retaining said etching resist film; and forming an electroless copper plated film on said catalytic layer; or forming a solder resist film on the necessary portion before or after said electroless copper plated film is formed.

Description: Process of manufacturing printed wiring boS U U printed wiring boards manufactured by the same. 1. Field of the invention This invention relates to the process of manufacturing printed wiring boards suitably used for business, communication and electric machine and tools and printed wiring boards manufactured by the same. 2. Description of the Prior Art The conventional processes of manufacturing printed wiring boards called copper through-hole printed wiring boards have been roughly classified into two methods such as the subtractive process wherein the printed wiring board is made from the copperclad laminate and the additive process wherein the printed wiring board is made from the copper foil laminate-free catalyst included laminate. As examples of the former there are enumerated (1) the so-called tenting process which comprises the steps of making holes; plating through holes; thereafter copper plating said hole walls and copper foil to the thickness required for the hole wall by electrolysis; pouring ink in the hole walls for forming an etching resist film on necessary circuits; thereafter melting-off the copper foil on the unnecessary portion by etching; and then melting-off the etching resist film and (2) the modified process as disclosed in Japanese Laid-open Patent Application 13965/1979 which comprises the steps of making necessary circuits by etching; thereafter making holes; forming a pretreating layer on said hole walls and circuits by electroless plating; mechanically removing said pretreating layer on circuits; forming a solder resist film on the necessary portion; and thereafter forming an electroless plated film on the hole walls and necessary circuits; or making holes after the solder resist film is formed. And, as the example of the latter additive process there is cited (3) the process which comprises the steps of applying a bonding agent onto a catalyst included laminate; thereafter making holes; forming a permanent resist film on the portion other than circuits; then forming copper on the hole walls and circuits by electroless plating; and thereafter forming a solder resist film on the necessary portion. However, these conventional process include various shortcomings in the respects of quality and productivity. This will be explained concerning each example of the above mentioned process. The process example (1) is defective in that it takes a long period of time to remove the copper on the unnecessary portions by etching because the thickness of said copper, which comprises the thickness of copper foil and that of through-hole plating, is nearly twice that of copper foil, and therefore circuits must be undercut largely with the result of deteriorated dimensional accuracy. The process example (2) is defective in that since circuits are formed by etching, thereafter a layer is formed on the hole wall portions and solder resist film or on the copper foil-melted off, naked laminate by pretreatment for electroless plating, then the layer formed on circuits by pretreatment for electroless plating are mechanically removed and thereafter electroless plating is conducted, it is difficult to completely remove the layer formed by pretreatment for electroless plating and therefore the plated layer remaining on the unnecessary portions brings about short circuits or deteriorates the insulation resistance between circuits. And, the process example (3) is defective in that as there is necessity of using the special and expensive base material, namely the catalyst included laminate, it is not only expensive but also unsuitable for common use, and further as plating is made on permanent resist-formed circuits, the dimensional accuracy of circuits is inferior, that is this process is unsuitable for circuits being less than 0.5 mm in width and the formed circuits are liable to lack uniformity in width. SUMMARY SUMMARY OF THE INVENTION It is is an object of this invention to obtain a highly accurate and cheap printed wiring board which is capable of removing the above mentioned short-comings inherent in conven tional processes and completely freed from dangers of bad insulation resistance between circuits and short-circuit accidents without using any special base material at all. This object can be achieved by making holes in the necessary portion of a copper-clad laminate; forming a catalytic layer on said hole walls and copper foil by pretreatment for electroless plating; forming an etching resist film on necessary lands and circuits; melting-off the copper foil on the unnecessary portion by etching; then melting-off the etching resist film; and forming an electroless copper plated film on the catalytic layer formed on the hole wails, lands and circuits, or forming an electroless copper plated film on the catalytic film formed on the hole walls without melting-off the etching resist film. It is another object of this invention to obtain a printed wiring board which is capable of ensuring reliability for a long period of time by preventing circuits from bridging at the time of plating parts and/or protecting the surfaces of circuits and insulating material from moisture and the like. This object can be achieved by forming a solder resist film on the necessary portion before or after said electroless copper plated film is formed in the above mentioned process. The The other objects of this invention will be clearly understood from the subsequent explanation. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 to Fig. 8 are cross-sectional views illustrating the process of manufacturing a through-hole printed wiring board by sing this invention. DETAILED DESCRIPTION OF THE INVENTION One --xample of the process of manufacturing a printed wiring h¯-rd according to this invention will be explained hereinafar with reference to the accompanying drawings. Fir , holes 3 are made in the necessary portion of a convet-onal copper-clad laminate which comprises laminating a copper woil 2 on an insulating material 1 as shown in Fig. 1 (Fig. 2) - These holes may be perforated by using a drill or punch. -nen, a conventional pretreatment for electroless plating S performed. For example, this laminate is dipped in an alkali defatted liquid so as to clean the surfaces of copper foil and hole walls, thereafter is dipped in a 5 vol % hydrochloric acid aqueous solution to activate the copper foil surface, and then is dipped in an aqueous solution, the so-called catalizer, containing 15 g/± ionic concentration of dihydric tin comprising stannous chloride, palladium chloride and hydrochloric acid, 0.25 g/Q ionic concentration of dihydric palladium and 200 mQ/Q of concentrated hydrochloric acid so as to form a tin palladium colloid type catalytic layer 4 (Fig. 3). Then, the surface on which the catalytic layer 4 has been formed by adsorption is subjected to forced or natural drying so as to have a sufficient adhesive property for an etching resist film, and thereafter an etching resist film 5 is formed on the necessary portion (Fig. 4). In this instance, said etching resist may be either ink or a dry film, and its formation may be made by means of either a printing process or a photographic process. Thereafter, the copper foil on the unnecessary portion is melted-off with a solution comprising 400 g/Q of ferric chloride and 3 g/L of hydrochloric acid or the like (Fig. 5). In this instance, the catalytic layer adsorbed on the copper foil is completely removed simultaneously with melting-off of the copper foil by etching. Consequently, the catalytic layer formed by pretreatment for electroless plating does no longer exist on the surface of the copper foil-melted off insulating material 1, but the catalytic layer formed on the inside wall of the through hole is not removed and retained because it is adsorbed directly on the insulating plate. This is the most marked characteristic of this invention. Due to this, electroless plating may not deposit on anywhere other than the necessary portion during the subsequent circuit forming process and further any deterioration in insulation resistance may be caused no longer between the circuits. In this connection, it is to be noted that a known solution of ammonium persulfate or an alkali etchant may be used for etching purposes. Next, the etching resist film 5 having now become useless is melted-off in the usual manner by using trichlene or methylene dichloride (Fig. 6). Then, a solder resist film is formed on the necessary portion for preventing the circuits from bridging or protecting the surfaces of circuits and insulating material from steam and the like at the time of solder parts (Fig. 6'). This solder resist film has recently become indispensable for industrial printed wiring boards in order to secure the long reliability of printed wiring boards, and is regarded as important especially in the case of the so-called copper through-hole printed wiring board according to this invention. The solder resist is generally formed with an epoxy type ink, but may be formed with a liquid or dry photosensitive resin film. Next, it is preferable to dip the laminate in a 10% sulfuric acid solution and activate the catalytic layer 4 adsorptionformed on the surfaces of copper foil covering hole walls and necessary circuits by pretreatment for electroless plating so that the reactivity of electroless copper plating may be displayed perfectly in the succeeding step. Then, the laminate is dipped in an electroless copper plating bath so as to form an electroless copper plated film 7 on the wall surfaces of holes 3 in the catalytic layer 4 formed by electroless plating reaction and the surface of copper foil 2 on necessary circuits (Fig. 7'). One example of the bath composition and the plating condition of this electroless copper plating, will be given as follows. The following composition and condition may be used effectively for high-speed plating: Sodium ethylene diamine tetracetate 40 g/Q Copper sulfate (CuSO4 5H2O) 10 g/Q Paraformaldehyde 10 g/Q Sodium cyanide 100 ppm P 12 Temperature 60 C. And, the following composition and condition may be used effectively for low-speed plating: : Rochelle salt 40 g/Q Copper sulfate 10 gJQ Paraformaldehyde 15 g/Q Sodium hydroxide 8 g/Q Sodium cyanide 100 ppm Temperature 250C The thus obtained electroless copper plated film 7, as stated previously, is formed with a strong adhesive strength selectively only on the catalytic layer formed on the wall surface portions of holes 3, lands and circuits and therefore is never formed on the other unnecessary portions at all. Fig. 7' shows the board prepared through the steps which have been described up to here, that is the finished printed wiring board according to this invention. In this connection, it is to be noted that the solder resist film may be formed prior to the electroless plating as shown in Fig. 6' and finished as shown in Fig. 7', but said film may be formed after the electroless plating has been applied as shown in Fig. 7 and thereafter finished as shown in Fig. 7'. When the solder resist film 6 is needless, electroless plating may be applied directly onto the board as shown in Fig. 6, and the same may be finished as shown in Fig. 7. In this instance, the etching resist film 5 may be subjected to electroless copper plating treatment without being melted-off. In this case, the etching resist film 5 is retained on the circuits and lands, and consequently the electroless copper plated film is formed only on the catalytic layer 4 exposed on the hole wall portion (Fig. 7"). This etching resist film is melted-off in the usual manner after the electroless copper plated film has been formed (Fig. 8). However, this etching resist film 5 may be retained as shown in Fig. 7" without being melted-off. This permits the etching resist film 5 to remain on the circuits and lands, and said remaining film 5 performs the same operation as the solder resist film 6, thereby protecting the circuits and lands from moisture and the like. When comparing the printed wiring board obtained according to this invention with those obtained according to the conventional manufacturing processes in respect of the performance and cost, the results obtained therefrom can be summarized as shown in the following table. EMI8.1 <tb> <SEP> Our <SEP> Conventional <SEP> processes <tb> <SEP> process <SEP> Example <SEP> Example <SEP> Example <tb> <SEP> (1) <SEP> (2) <SEP> (3) <tb> Base <SEP> material <SEP> used <SEP> cheap <SEP> cheap <SEP> cheap <SEP> expensive <tb> Time <SEP> required <SEP> for <SEP> short <SEP> short <SEP> short <SEP> | <SEP> long <tb> manufacturing <tb> Probable <SEP> minimum <SEP> 0.1 <SEP> mm <SEP> O.3 <SEP> mm <SEP> | <SEP> O.2 <SEP> mm <SEP> | <SEP> 0.5 <SEP> mm <tb> circuit <SEP> width <tb> Intercircuit <SEP> insu- <SEP> lol2¯1ol3212 <SEP> 13 <SEP> Q12 <SEP> -13 <SEP> 7 <SEP> 8 <SEP> 12 <SEP> 13 <tb> <SEP> lation <SEP> resistance <SEP> 10 <SEP> -10 <SEP> fl <SEP> 10 <SEP> -10 <SEP> # <SEP> 10 <SEP> -10 <SEP> # <SEP> 10 <SEP> -10 <tb> Danger <SEP> of <SEP> short <tb> <SEP> circuits <SEP> none <SEP> none <SEP> exist <SEP> exist <tb> Soldering <SEP> rate <SEP> i <SEP> 100% <SEP> 80% <SEP> 80% <SEP> 60% <tb> Solder <SEP> resist <tb> <SEP> forming <SEP> accuracy <SEP> easy <SEP> easy <SEP> difficult <SEP> easy <tb> It is needless to say that this invention is concerned with the process for manufacturing through holes and circuits with an electroless copper plated film, but said through holes and circuits may be formed by using electroless nickel plating.

Claims: 'What is claimed is: 1. A process of manufacturing a printed wiring board comprising the steps of: making holes in the necessary portion of a copper clad laminate; forming a catalytic layer on said hole walls and copper foil by pretreatment for electroless plating; forming an etching resist film on necessary lands and circuits; meltingoff the copper foil on the unnecessary portion by etching; melting-off the etching resist film; and forming an electroless copper plated film on the catalytic layer formed on the hole walls, lands and circuits. 2. A process as claimed in Claim 1 wherein said electroless copper plated film is formed on the catalytic layer formed on the hole walls after etching has been effected and without melting-off the etching resist film. 3. A process as claimed in Claim 2 wherein the etching resist film is melted-off after the electroless copper plated film has been formed. 4. A process as claimed in any one of Claim 1 to Claim 3 wherein a solder resist film is formed on the necessary portion before or after the electroless copper plated film has been formed. 5. A process as claimed in any one of Claim 1 to Claim 4 wherein an electroless nickel plated film is formed in place of the electroless copper plated film. 6. A printed wiring board which is obtained by making holes in the necessary portion of a copper-clad laminate; forming a catalytic layer on said thole walls and copper foil by pretreatment for electroless plating, forming an etching resist film on necessary lands and circuits; melting-off the copper foil on the unnecessary portion by etching; melting-off the etching resist film; and forming an electroless copper plated film on the catalytic layer formed on the hole walls, lands and circuits. 7. A printed wiring board as claimed in Claim 6 which is obtained by forming said electroless copper plated film on the catalytic layer formed on the hole walls after etching has been effected and without melting-off the etching resist film. 8. A printed wiring board as claimed in Claim 7 wherein the etching resist film is melted-off after the electroless copper plated film has been formed. 9. A printed wiring board as claimed in any one of Claim 5 to Claim 8 wherein a solder resist film is formed on the necessary portion before or after the electroless copper plated film has been formed. 10. A printed wiring board as claimed in any one of Claim 6 to Claim 9 wherein an electroless nickel plated film is formed in place of the electroless copper plated film.

Inventors: NISHIHARA, HARUO, SUZUKI, YOSHIAKI
Applicants: KANTO KASEI CO., LTD.
Application year: 1982
Main classification: H05K3
IPC codes: H05K3