LOW TEMPERATURE MELTING BINARY GLASSES FOR LEVELING SURFACES OF INTEGRATED CIRCUITS CONTAINING ISOLATION GROOVES

Abstract: An integrated circuit structure comprises a plurality of islands of semiconductor material (16-1 through 16-5) each island being separated from adjacent islands by a groove formed in annular shape around said island to laterally define the dimensions of each such island, an oxide (12, 14 and 15) formed over the surface of said grooves (13-1 through 13-6) and selected glass (15) deposited on said oxide (14) in the grooves and over the top surface of said device, said glass having the property that it melts and flows at a temperature beneath the temperature at which dopants in the islands of semiconductor material substantially redistri­ bute, said selected glass (15) having a substantially flat top surface thereby to give said structure a substantially flat top surface.

Description: LOW TEMPERATURE MELTING BINARY GLASSES FOR LEVELING SURFACES OF INTEGRATED CIRCUITS CONTAINING ISOLATION GROOVES BACKGROUND OF THE INVENTION Field of the Invention This invention relates to integrated circuits fabricated using glass isolation techniques and in particular to an integrated circuit fabricated using such techniques wherein the surface of the glass formed in the isolation grooves is substantially flat. Description of the Prior Art The use of oxide for isolating islands of semiconductor material in which are formed active devices is well-known. Thus, United States Patent No. 3,648,125 on an invention of Peltzer discloses the basic oxide isolation technique now commonly employed in the manufacture of high density fast integrated circuits. Two problems with prior art oxide isolated structures of the types disclosed in the '125 patent are 1) the grown oxide encroaches into the active regions of the devices, and 2) the interconnection of the active devices becomes more difficult due to surface irregularities in the isolating oxide. Thus in the standard oxide isolation technique wherein a groove is formed in epitaxial silicon and the resulting exposed silicon is oxidized, a "bird-beak" is well-known to form at the intersection between the semiconductor material in which active devices are to be formed and the oxide isolation regions. While in most oxide isolated semiconductor devices manufactured prior to the filing date of this specification, this bird-beak is not an insurmountable problem, as the active devices become smaller, this birdbeak becomes a greater hindrance to the achievment of high yields. SUMMARY OF THE INVENTION It is a general object of this invention to provide an improved method and structure for isolating islands of semiconductor in which active devices are formed. This and other objects are attained in accordance with one aspect of the invention, by the method of forming an isolated semiconductor structure comprising: forming active devices or selected components in to-be-formed islands of semiconductor material, each island being separated from adjacent islands by an annular shaped band of semiconductor material in which are formed no active devices or selected components, said active devices or selected components being formed by placing selected dopants in said to-be-formed islands to form selectively doped regions in said islands; etching grooves in the surface of the semiconductor material so as to remove a portion of each annular shaped band in which no active devices were formed, thereby to create a plurality of islands of semiconductor material, each island containing active devices or selected components; oxidizing the semiconductor material exposed by said grooves to form an oxide layer of selected thickness over the surface of said grooves; depositing a selected glass over the top surface of said device, said glass having the property that it melts and flows at a temperature beneath that temperature at which said dopants in the islands of semiconductor material substantially redistribute; and heating the resulting structure to flow said glass to form a substantially flat surface over the top of said device. Another aspect of the invention includes an integrated circuit structure comprising: a plurality of islands of semiconductor material, each island being separated from adjacent islands of semiconductor material by a groove formed in an annular shape around said island, each island containing active devices or selected components of the to-be-formed circuit formed by placing selected dopants in regions of each island; grooves formed in the surface of the semiconductor material in annular shape around each such island, thereby to laterally define the dimensions of each such island; an oxide formed over the surface of said grooves and said islands of semiconductor material; a selected glass deposited on said oxide in the grooves and over the top surface of said device, said glass having the property that it melts and flows at a temperature beneath the temperature at which the dopants in the islands of semiconductor material substantially redistribute, said selected glass having a substantially flat top surface thereby to give said structure a substantially flat top surface. DESCRIPTION OF THE DRAWINGS Figures la through le show cross-sectional views of a semiconductor wafer at sequential steps in the process of this invention. Figure 2 shows in cross-section an integrated circuit structure, including interconnects on the top surface of the structure, manufactured in accordance with this invention. DETAILED DESCRIPTION OF THE INVENTION While this invention will be described in conjunction with the drawings, it should be understood that this invention can be employed in structures other than those shown for illustrative purposes in the drawings. Thus, this description is illustrative only and is not intended to limit the scope of The invention. As shown in Figure la, semiconductor wafer 10 comprises a semiconductor substrate 11 (only a portion of which is shown for illustrative purposes only) on which has been formed a layer of oxide 12 over the top surface of the wafer. Prior to the formation of oxide 12, wafer 10 has been subjected to the standard processing techniques for the formation of active devices within the semiconductor material 11. These devices typically comprise emitter, collector and base regions of bipolar transistors if the structure represents a bipolar device or comprise source, drain and channel regions if the structure comprises an MOS device. The principles of this invention are equally applicable to MOS and bipolar processing techniques and thus the description is not intended to limit the invention to use with one or the other of these types of devices. The active devices are formed in the surface of substrate 11 in the to-be-formed islands 16-1 through 16-5 of semiconductor material leaving regions 11-1 through 11-6 between the to-be-formed islands of semiconductor material. No active devices are to be formed in regions 11-1 through 11-6 shown in cross-section in Figure la. It should be understood that a typical island, such as island 16-2, in which active devices have been formed, is surrounded on all sides by regions such as regions 11-1 through 11-6 as shown in cross-section in Figure la so as to be laterally isolated from the adjacent to-be-formed islands 16 of semiconductor material. The five islands 16-1 through 16-5 are merely five of a plurality of such islands formed in a given device and thus are merely illustrative as to number and not limiting. Following the fabrication of the active devices in the to-be-formed islands 16 of semiconductor material, grooves are etched between the islands using standard silicon etching techniques. Typically, the grooves are formed to a depth of approximately 1-2 microns using an acid or plasma etch well-known in the semiconductor arts. For wet etching of silicon a nitride mask of a type wellknown in the semiconductor arts is used. The to-be-formed islands 16 of active semiconductor material are covered by oxide 12, a nitride layer (not shown) and photoresist which protects these islands from the etch. Following the formation of grooves 13-1 through 13-6, the structure is thermally oxidized in a well-known manner to form a thin thermal oxide layer 14 of approximately 1000-2000 angstroms over the surfaces of the grooves. Other oxide thicknesses can be employed if desired. The resulting structure is shown in Figure lc. After thermal oxide layer 14 is formed on wafer 10, the binary glass 15 of this invention is deposited over the top surface of this structure to both fill grooves 13-1 through 13-6 and to form additional glass 15 on top of islands 16-1 through 16-5. This structure is illustrated schematically in Figure ld. In accordance with this invention the binary glass comprises a mixture of oxide of germanium and of oxide of silicon and typically comprises a binary GeO2 -SiO2 glass co-deposited using chemical vapor deposition at a temperature of 3500C to 5000C from a silane-germane source in an oxygen environment. This glass is formed to a selected thickness, typically approximately 1-3 microns. Following the deposition of glass 15, the structure is heated to a temperature in the range of 6500C to 10000C. The glass melts and flows into the grooves 13-1 through -13-6 to yield a structure as shown in Figure le wherein glass 15 fills grooves 13-1 through 13-6 to provide a substantially flat top surface 15a. Because the glass melts at less than 9500C, the dopants in the islands 16-1 through 16-5 are not substantially affected by this heating and glass flow step and the electrical characteristics of the device remain unaltered when the glass is melted and flowed below this temperature. Actually, the structure can be heated to 10000C for short periods of tizzy less than ten (10) minutes because at 10000C the dopants only begin to move after about ten (10) minutes. Figure 2 illustrates a portion of the structure shown in cross-section in Figure le wherein additional interconnects 17a, 17b and 17c have been formed over the reflowed glass filling grooves 11-4, 11-5 and 11-6. Interconnect 17b contacts an active region formed in island 16-4 through via 18b opened through oxide layers 12 and 14 and connects this active region to an active region formed in island 16-5 through via 18c opened through oxide layers 12 and 14. Interconnect 17c connects an active region formed within island 16-5 contacted through opening 18d in oxide layers 12 and 14 to another active region or a contact pad. Interconnect 17a connects an active region formed in island 16-4 and contacted through via 18a to another active region formed in another island or to a contact pad. In one embodiment, wafer 10 comprises a substrate 11 of silicon material processed in a standard manner to form active devices within selected regions 16-1 through 16-5 (Figure la) of the structure. Oxide layer 12 is formed on the top surface of wafer 10 in a standard, well-known manner. A layer of silicon nitride (not shown) is formed over oxide layer 12 in a standard well-known manner and is used to mask and thus protect those regions of silicon material 16-1 through 16-5 in which are formed active regions. Grooves are then etched using a standard silicon etch comprising, for example, a mixture of hydrofluoric, acetic, and nitric acid and then the resulting grooved silicon is further oxidized to form oxide layer 14 using well-known oxidation techniques. Oxide layer 14 is formed typically at a temperature of 9000C, sufficiently below the temperature at which diffusion takes place to prevent substantial change in the electrical properties of the active devices formed in islands 16-1 through 16-5. The binary glass of this invention is then formed as described above over the top surface of the device and the structure is heated to a temperature of about 9500C to melt and reflow this binary glass so as to form a substantially flat top surface. Vias 18a through 18c are opened in the top surface of the oxide layers 12 and 14 anagIass15 in a standard well-known manner using photoresist masking techniques and a selected etchant (such as buffered hydrofluoric acid) and then interconnect lead structures are formed in a well-known manner over the top surface of the device from a selected conductive material, typically aluminum. This invention has been described in conjunction with one embodiment. It will be apparent to those skilled in the art that other embodiments of this invention and other materials will be suitable for use in accordance with the principals of this invention.

Claims: WHAT IS CLAIMED IS: 1. The method of forming an isolated semiconductor structure comprising: forming active devices or selected components in to-be-formed islands of semidonductor material, each island being separated from adjacent islands by an annular shaped band of semiconductor material in which are formed no active devices or selected components, said active devices or selected components being formed by placing selected dopants in said to-be-formed islands to form selectively doped regions in said islands; etching grooves in the surface of the semiconductor material so as to remove a portion of each annular shaped band in which no active devices were formed, thereby to create a plurality of islands of semiconductor material, each island containing active devices or selected components; oxidizing the semiconductor material exposed by said grooves to form an oxide layer of selected thickness over the surface of said grooves; characterized by depositing a selected glass over the top surface of said device, said glass having the property that it melts and flows at a temperature beneath that temperature at which said dopants in the islands of semiconductor material substantially redistribute; and heating the resulting structure to flow said glass to form a substantially flat surface over the ton of said device. 2. The method of Claim 1 characterized in that said step of depositing a selected glass over the top surface of said device comprises depositing a binary glass comprising a mixture of oxide of germanium and of oxide of silicon. 3. The method of Claim 2 characterized in that said step of depositing said binary glass comprises depositing a binary GeO2/5i02 glass using chemical vapor deposition at a temperature in the range of 350 0C 0 to 500 C from a silant/germane source in an oxygen environment. 4. The method of Claim 2 or 3 characterized in that said binary glass is formed to a selected thickness between approximately 1-3 microns. 5. The method of any one of Claims 1-4 characterized in that said step of heating the resulting structure to flow said glass comprises heating said resulting structure to a temperature in the range of 6500C to 10000C. 6. The method of Claim 5 characterized in that said step of heating the resulting structure comprises the step of heating said resulting structure to a temperature of less than 950 0C to flow said glass to form a substantially flat surface over the top of said device. 7. The method of any previous claim characterized in that said semiconductor material comprises silicon. 8. The method of any previous claim characterized in that said step of etching grooves in the surface of the semiconductor material comprises etching grooves using a mixture of hydrofluoric, acetic and nitric acid thereby to remove a portion of each annular shaped band in which no active device is formed, thereby to create a plurality of islands of semiconductor material, each island containing active devices or selected components. 9. The method of any previous claim characterized by the additional step of forming on the substantially flat surface over the top of said device a plurality of openings through the selected glass and through said underlying oxide material and forming a selected interconnect pattern of conductive material over the top surface of said device so as to interconnect selected ones of said active devices or selected components. 10. The structure formed by the method of Claim 1. 11. An integrated circuit structure comprising: a plurality of islands of semiconductor material, each island being separated from adjacent islands of semiconductor material by a groove formed in an annular shape around said island, each island containing active devices or selected components of the to-be-formed circuit formed by placing selected dopants in regions of each island; grooves formed in the surface of the semiconductor material in annular shape around each such island, thereby to laterally define the dimensions of each such island; an oxide formed over the surface of said grooves and said islands of semiconductor material; characterized by a selected glass deposited on said oxide in the grooves and over the top surface of said device, said glass having the property that it melts and flows at a temperature beneath the temperature at which the dopants in the islands of semiconductor material substantially redistribute, said selected glass glass having a substantially flat top surface thereby to give said structure a substantially flat top surface. 12. Structure as in Claim 11 characterized in that said structure includes vias formed through said glass and said oxide to contact selected ones of said active devices and components formed in said islands of semiconductor material and conductive interconnect material formed in a selected pattern on the top surface of said glass to contact selected ones of said active regions or selected components through said vias, thereby to interconnect selected ones of said active devices or selected components into a circuit.

Inventors: LEHRER, WILLIAM I., PIERCE, JOHN M.
Applicants: FAIRCHILD CAMERA & INSTRUMENT CORPORATION
Application year: 1982
Main classification: H01L21
IPC codes: H01L21, H01L23