PROCESS FOR PRODUCING PROPYLENE-ETHYLENE BLOCK COPOLYMER

Abstract: A propylene-ethylene block copolymer in the presence of a catalyst comprises as main components, a solid titanium-containing catalytic component and an organoalu­ minum compound having the formula AIR 1 / mCl 3-m (R¹ represents a C₁₋₂₀ hydrocarbon moiety; and m is 3 ≧ m > 1.5) by producing a homopolymer of propylene or a propylene-ethylene copolymer by polymerizing propylene or both propylene and ethylene at a vapor phase propylene concentration of 90 mol % or higher based on the sum of propylene and ethylene in a first step and producing a propylene-ethylene block copolymer by copolymerizing propylene and ethylene at a vapor phase propylene concen­ tration of less than 90 mol % based on the sum of propylene and ethylene in the presence of the polymer resulted in the first step, and the catalyst in a second step which is characterized by newly adding an aluminum compound having the formula AIR 2 / nX 3-n (R² represents a C₁₋₂₀ hydrocarbon moiety; X represents a halogen atom and n is 1.5 ≧ n ≧ 0) to the components for the copolymerization in the second step.

Description: BACKGROUND OF THE INVENTION: FIELD OF THE INVENTION: The present invention relates to a continuous process for producing a propylene-ethylene block copolymer. More particularly, it relates to a continuous process for producing a propylene-ethylene block copolymer having excellent characteristics of cold shortness and high impact strength which are the same or superior to those of a propylene-ethylene block copolymer obtained by a batch system. DESCRIPTION OF THE PRIOR ART: It has been well-known to produce a propylene-ethylene block copolymer in order to improve an impact strength and a cold shortness over those of a homopolymer of propylene. In general, propylene is polymerized in the presence of a Ziegler-Natta catalyst composed by an organoaluminum compound and titanium trichloride or a titanium chloride supported by a magnesium compound in an inert liquid hydrocarbon or liquid propylene as a diluent in the first step; and copolymerizing propylene with ethylene in the presence of the propylene polymer produced in the first step to produce a block copolymer in the second step. The polymerization process can be a batch process and a continuous process. The batch process causes certain disadvantages because of relatively low productivity and economical disadvantage and indispensable dispersion of qunlities of the product In runs of the production. On the other hand, the continuous process docs not cause such disadvantages to be advantageous as an industrial process. In view of the quality of the product, the following disadvantages are found. When the first step and the second step are connected in series in the two step polymerization and propylene is polymerized in the first step and propylene and ethylene are copolymerized in the second step as the continuous process, the resulting block copolymer has inferior cold shortness and impact strength in comparison with those of the batch process and an ultimate elongation is lowered and fish-eyes are formed in the product. As a main reason why such disadvantages are caused, the following reason may be considered. When two or more reactors are connected in series to polymerize by the continuous process, it is considered to be the complete mixed condition in each reactor and to result in certain distribution of the residence time of the catalyst or the polymer containing -the catalyst in each reactor. When the residence time of the catalyst is short, the polymer having relatively low productivity of the polymer per unit of the catalyst (referring to as catalyst efficiency) is produced whereas when the residence time of the catalyst is long, the polymer having relatively high catalyst efficiency is produced. In each reactor, the polymer having low catalyst efficiency and the polymer having high catalyst efficiency are produced. As a result, the formulation of the total polymers has a broad distribution. Even though an average residence time in each reactor is set to give 159s of a content of the propylene-ethylene copolymer (referring to as EPR) in the second step, the resulting block copolymer contains polymer grains having zero % of EPR content and polymer grains having about 100t of EPR content as extreme expression. Among them, the polymer grains having relatively high EPR content do not disperse in the homopolymer of propylene to result in fish-eyes in the product. As a result, it is considered to give inferior cold shortness and impact strength. Various processes have been proposed to overcome the disadvantages in the continuous polymerization. The processes using many reactors have been proposed in Japanese Examined Patent Publication No. 25585/1978 and Japanese Unexamined Patent Publication No. 53990/1974. In such processes, a block copolymer having physical properties similar to those of the batch process can be obtained, however, it causes higher cost of construction of the apparatus depending upon increase of the reactors to be uneconomical and it causes complicated quality control of the product. It is preferable to reduce a number of the reactors. The process adding an electron donor in the copolymerization of propylene and ethylene in the second step has been proposed in Japanese Examined Patent Publication No. 19542/1969 and Japanese Unexamined Patent Publication No. 115417/1980. Thus, the process has not been effective according to the studies. The process for reducing a molecular weight of a propyleneethylene copolymer in the second step has been proposed in Japanese Unexamined Patent Publication No. 61278/1974. The process causes inferior impact strength of the product according to the studies. SUMMARY OF THE INVENTION: In accordance with the present invention, it provides a continuous process for producing a propylene-ethylene block copolymer in the presence of a catalyst comprising as main components, a solid titanium-containing catalytic component and an organoaluminum compound having the formula AIRmC13-m (R1 represents a C1 20 hydrocarbon moiety; and m is 3 > m > 1.5) by producing a homopolymer of propylene or a propylene-ethylene copolymer by polymerizing propylene or both propylene and ethylene at a vapor phase propylene concentration of 90 mol 96 or higher based on the sum of propylene and ethylene in a first step and producing a propyleneethylene block copolymer by copolymerizing propylene and ethylene at a vapor phase propylene concentration of less than 90 mol 96 based on the sum of propylene and ethylene in the presence of the polymer resulted in the first step, and the catalyst in a second step which is characterized by newly adding an aluminium compound having the formula AIRnêX3-n (R2 represents a C1-20 hydrocarbon moiety; X represents a halogen atom and n is 1.5 # n > 0) to the components for the copolymerization in the second step. BRIEF DESCRIPTION OF THE DRAWINGS: Figures 1 to 4 are diagrams for illustrating embodiments of the process of the present invention. Figure 1 shows a diagram illustrating intermittent feeding of a catalyst; and intermittent discharge of a polymer; Figures 2 to 4 respectively show flow diagrams employing a classification system. In Figure 1, the reference T1 designates a time for feeding a solid catalytic component in the first reactor in the first step; T2 designates a time for stopping discharge of a slurry of a polymer in the first reactor after feeding the solid catalytic component; and T3 designates a time for discharging the slurry of the polymer from the first reactor. A: reactors for polymerization of propylene; A1: first reactor for polymerization of propylene; A 2: second reactor for polymerization of propylene; B: liquid cyclone; B1: first liquid cyclone; B2: second liquid cyclone; C: hydraulic sedimentation classifier; D: reactor for copolymerization of propylene and ethylene; 1: catalyst-feed pipe; 2: propylene- feed pipe; 3, 3': slurry discharge pipe; 4, 4'; supernatant dischorge pipe; 5. 5': concentrated polypropylene slurry discharge pipe; 6: discharge pipe of hydraulic sedimentation classifier; 7: discharge pipe of hydraulic sedimentation classifier; 8: ethylene feed pipe; 9: propylene feed pipe; 10: halogenated aluminum compound feed pipe; 11: polymer discharge pipe. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS: The reason why the improved effect is attained by the addition of the specific aluminum compound in the second step of the process of the present invention is not clearly found and is considered as follows: The rate decrease with time of the copolymerization of propylene and ethylene in the second step is accelerated by the addition of the specific aluminum compound whereby an amount of polymer grains having relatively higher EPR content is reduced. Such effect is caused by accelerating the rate decrease with time of the copolymerization. The effect of the present invention is not found when only the average rate of the copolymerization is reduced without varying the degree of the rate decrease with time of the copolymerization by adding a poison to the catalyst such as an electron donor or the degree of the rate decrease with time of the copolymerization is reduced by adding an activating agent such as trialkylaluminum as described in the following references. The process of the present invention will be further illustrated. The catalyst system used in the present invention is obtained by using a solid titanium-containing catalytic component and an organoaluminum compound. The solid titanium-containing catalytic component can be the conventional support type catalytic component obtained by mixing a solid magncsium compound, a titanium tetrahalide and an electron donor and it is preferably a solid catalytic component made of titanium trichloride as a main component. The solid catalytic component made of titanium trichloride as a main component can be products obtained by reducing titanium tetrachloride with aluminum metal, hydrogen or an organoaluminum compound or grinding the product or mixing or pulverizing the product with an electron donor, and is especially a product having a content of an aluminum component as an atomic ratio of Al to Ti of 0.15 or less preferably 0.1 or less especially 0.02 or less and containing a chelating agent. The content of the chelating agent as a molar ratio of the chelating agent to titanium trichloride is 0.001 or more preferably 0.01 or more. As the typical examples, it is composed of titanium trichloride, an aluminum halide compound having the formula AIRp X3-p (R represents a C1-20 hydrocarbon moiety; X represents a halogen atom; and p is 0#p#2) (atomic ratio of Al to Ti of titanium thrichloride of 0.15 or less) and a chelating agent at a molar ratio of the chelating agent to the sum of the aluminum halide compound and titanium trichloride of 0.001 or more, for example, it has the formula TiC13- (AlRpx3-p)s t (R represents a C1-20 hydrocarbon mioety; X represents a halogen atom; p is 0 p < 2; C C represents a chelating agent; s is 0.15 or less; and t is 0.001 or more). Beside the TiCl3 component, AIRp X3-p component and the chelating agent, it is possible to incorporate a small amount of iodine a titanium halide obtained by substituting part or whole of chlorine of TiCl3 by iodine or bromine, an inorganic solid as a support such as MgCl2 and MgO; a polyolefin powder such as polyethylene and polypropylene. The chelating agent Cican be ethers, thioethers, ketones, carboxylic acid esters, amines, carboxylic acid amides and polysiloxanes. It is especially preferable to use ethers or thioethers which can be the compounds having the formula R4-O-R5 or R4-S-R5 (R4 and R5 respectively represent hydrocarbon moieties having 15 or less of carbon atoms). AIRp X3-p can be AlCl3 or AIR Cl2. The solid titanium trichloride type catalytic complex can be easily produced (a) by precipitating it at 1500C or lower from a titanium trichloride-containing liquid obtained by dissolving a titanium trichloride in the presence of ether or thioether at 1500C or lower; or (b) by reducing titanium tetrachloride with an organoaluminum compound or an aluminum metal and treating the resulting titanium trichloride with a chelating agent or a halide compound which are disclosed in Japanese Examined Patent Publication No. 40348/1977, No. 3356/1978, No. 24194/1978, No. 28316/1979, No. 41040/1979, No. 8003/1980, No. 8451/1980, No. 8452/1980 and Japanese Unexamined Patent Publication No. 91794/1977, No. 12796/1978 and No. 116626/1980. Beside the processes (a) and (b), it is also possible to produce it by reducing titanium tetrachloride with an organoaluminum compound, and adding the ether to the resulting titanium trichloride at a molar ratio of the ether to TiCl3 of 0.5 - 5 and heating it at 50 - 1200C and separating the resulting solid as disclosed in Japanese Examined Patent Publication No. 27871/1979. On the other hand, the organoaluminum compounds used as a cocatalyst in the first and second step has the formula AIRmÚCl3-m (RÚ represents a C1-20 hydrocarbon moiety; m is 3#m > 1.5). When the solid titanium-containing catalytic component is a support type catalytic component using a solid magnesium compound as a support, it is preferable to AIR3Ú or a mixture of AIR3Ú and AIR2ÚCl On the other hand, in the case of the catalytic component made of TiCl3 as a main component, it is preferable to use AlR2Cl. It is possible to use diethylaluminum monochloride as R1 is ethyl group and m=2. It is, however, preferable to use the organoaluminum compound (R 1 is n-propyl or n-hexyl group). The specific aluminum compound added in the second step has the formula AlR2X n (R2 (R represents a C1-20 hydrocarbon moiety; X represents -a halogen atom especially chlorine atom and n is 1.5 # 2 0) . It is preferable to use AIR1.5êCl1.5, AlR2CI2 or a mixture thereof. In the typical aluminum compound, R2 can be methyl, ethyl, propyl, isopropyl, butyl, isobutyl, hexyl, octyl, decyl and dodecyl groups. In view of.easy availability and easy handling, it is preferable to use ethylaluminum dichioride (AIEtCl2). ethylaluminum sesquichloride (AIEt1.5Cl1.5) and a mixture thereof. It is also possible to use AlCl3, A ratio of the components in the solid titanium-containing catalytic component is usually a molar ratio of Ti : AIRmÚCl3-m of 1 : 1 100 preferably 1 : 2 - 40 and a molar of AIRmÚ3-m; AIRnêX3-n of 1 : 0.01 - 0.50 preferably 1 : 0.03 - 0.30. The specific aluminum compound added in the second step can be the aluminium compound itself and also can be n complex of the aluminum compound and nn electron donor or a mixture thereof. The electron donors can be compounds which are capable of forming a complex with the specific aluminum compound such as organic oxygen-containing compounds such as ethers, ketones, carboxylic acid, esters and alcohols, organic sulfur-containing compounds such as thioether, organic nitrogen-containing compounds such as amines and pyridines; organic silicon-containing compounds such as silanol, polysilanol and polysiloxane; and organic phosphorus-containing compounds such as phosphoric esters and phosphorous esters. Suitable organic oxygen-containing compounds can be diethyl ether, dipropyl ether, dibutyl ether, diamyl ether, dihexyl ether, dioctyl ether, didecyl ether, didodecyl ether, diphenyl ether, anisol, acetone, methyl ethyl ketone, methyl methacrylate, ethyl methacrylate, methyl benzoate, ethyl benzoate, phenyl acetate, methanol, ethanol and butanol. Suitable organic sulfur-containing compounds can be diethyl thioether, dipropyl thioether, dibutyl thioether, diamyl thioether, dihexyl thioether, dioctyl thioether and diphenyl thioether. Suitable organic nitrogen-containing compounds can be triethylamine, tripropylamine, tributylamine, trioctylamine, aniline and pyridine. Suitable organic silicon-containing compounds can be diphenylsilane diol; triphenylsilanol, trimethylsilanol, dimethylpolysiloxane, and diphenylpolysiloxane. Suitable organic phosphorus-containing compounds can be triethyl phosphite, triphenyl phosphite, triphenyl phosphine oxide and triphenyl phosphine. It is especially preferable to use an ether, a thioether or a carboxylic acid ester among them. An amount of the electron donor is not critical and is usually in a range of 0.1 to 5 mol. per mol. of the specific aluminum compound. The specific aluminum and the electron donor are preferably premixed in an inert hydrocarbon solvent and the resulting complex or mixture is fed in the second step. The condition of the mixing, the temperature and time for the mixing is not critical. In the process of the present invention, it is possible to use the catalytic component and the cocatalyst with an electron donor such as carboxylic esters, phosphorous esters and amines as a third component. When the third component is added, the content of the third component is selected to be a molar ratio of Ti : third component of 1: 0.01 - 10 preferably 1 : 0.05 - 2. The solid titanium-containing catalytic component used as the catalyst can be used in the polymerization without any treatment. It is preferable to use it after a pretreatment with a small amount of an olefin such as propylene or ethylene in the presence of an organoaluminum compound. The pretreatment is effective for improving a physical property of a slurry of a polymer such as bulk density. The pretreatment is carried out at a temperature lower than the polymerization temperature such as 20 - 600C to give a ratio of the polymer produced in the pretreatment to the solid catalytic component of 0.1 - 50 : 1 preferably 1 - 20 : 1 by weight. In the process of the present invention, for producing a propylene-ethylene block copolymer in the presence of a catalyst of the solid titanium-containing catalytic component and the organoaluminum compound ns main components, the polymerization is carried out in two stcps. The polymerization can be carried in an inert hydrocarbon diluent such as propane, butane, hexane, heptane, benzene and toluene or also in liquid propylene or in a vapor phase polymerization. In the first step , a homopolymerization of propylene or a copolymerization of propylene and ethylene at a vapor phase propylene concentration of 90 mol 9ú or more (propylene/sum of propylene and ethylene) (hereinafter, referring to as a homopolymerization of propylene) -is carried out in the presence of the solid titanium-containing catalytic component and the organoaluminum compound having the formula AIRmÚ3-m In general, the polymerization temperature and time are selected to give a ratio of the homopolymer of propylene to the final polymer products ranging from 70 to 95 wt.%. The polymerization temperature is usually in a range of 40 to 1000C preferably 50 to 800C. The polymerization temperature and a content of a molecular weight controlling agent are selected to give 1 - 150 of a melt flow index (referring to as MFI) of the homopolymer of propylene obtained in the first step. The molecular weight controlling agent can be hydrogen and dialkylzinc and preferably hydrogen. A concentration of hydrogen in the vapor phase (concentration of hydrogen to sum of propylene and ethylene) is usually in a range of about 1 - 30 mol %. In the second step, a copolymerization of propylene and ethylene is carried out in the presence of the homopolymer of propylene produced in the first step, the newly added aluminum compound having the formula AIRnêX3-n A concentration of propylene in the vapor phase is less than 90 mol % pl'efCrllbly in a tinge of 50 to 85 mol # which is the condition for producing a noncrystalline polymer as a by-produçt at the maximum degree and for improving the impact strength of the final polymer product at the maximum degree. The polymerization temperature and time are usually selected to give 5 - 30 wt.% of the content of the propylene-ethylene copolymer based on the final polymer product. When the content of the propyleneethylene copolymer is less than 5 wt.%, the effect for improving the impact strength is small whereas when it is more than 30 wt.%, the product has disadvantageously inferior bulk density and free flowability. The polymerization temperature is usually in a range of 25 - 700C preferably 25 - 650C. When it is higher than 700C, the resulting propylene-ethylene block copolymer has inferior free flow ability and coaggulation of polymer grains is disadvantageously caused. The polymerization temperature and the content of hydrogen as the molecular weight controlling agent are selected to give 0.1 or less of MFI of the propylene-ethylene copolymer. The concentration of hydrogen in the vapor phase is usually in a range of 0.5 to 30 mol %. When MFI is more than 0.1, the improvement of the impact strength is not satisfactory whereas when MFI is extremely small such as less than 10 7, the improvement of the impact strength is high, but the Barus effect in an injection molding is large to disadvantageously deteriorate a dimensional stability. The content of ethylene component in the final polymer product is preferably in a range of 2 to 30 wt.%. In the continuous system, each different reactor is used for each of the steps. The reactor in the first step is connected in series to the reactor in the second step. In each step, a plurality of reactors can be used. In the first step, the polymerization can be carried out in two reactors which are serially connected. A complete mixing type reactor is usually used in the process of the present invention whereby certain constant distribution of residence times of the reaction products is caused. That is, the reaction mixture discharged from the first step contains the catalytic grains which are discharged by short-passing through the reactor without contributing to the polymerization; small polymer grains in unsatisfactory growth and high molecular weight and/or coarse polymer grains produced in a long residence time. The grains formed in the short-pass and the coarse grown grains cause formation of a gel in the copolymerization in the second step. The appearance of the product is in a shaped form is inferior and the cold shortness and the impact strength and the ultimate elongation may be deteriorated by them. In order to overcome the problem, the new addition of the specific aluminum compound in the second step is effective. In order to further improve the process, certain effective process is considered in view of chemical engineering. One of the improvements is to combine the feeding of the solid catalytic component and the discharge of the polymer under a specific condition. The other improvement is to employ a clas sification system. The improved feeding of the solid catalytic component and the improved discharge of the polymer will be illustrated as follows: In the first step, the solid titanium-containing catalytic component is intermittently fed into the reactor and the discharge of the polymer from the reactor is intermittently carried out. Referring to Figure 1, the operation will be illustrated. Figure 1 is a diagram for illustrating an embodiment of the present invention. The polymerization of propylene in the first step is carried out with two reactors and the copolymerization in the second step is carried out in one reactor to attain the slurry polymerization. In Figure 1, the feedings of sources; the feeding of the catalyst, the discharge of the slurry and the level of the slurry in the reactors are briefly shown. In Figure 1, the feeding of propylene, the feeding of hydrogen, the feeding of the second and third catalytic components in the first reactor, the feeding of additional propylene, the feeding of hydrogen, the discharge of a slurry in the second reactor in the first step and the feeding of ethylene, the feeding of additional hydrogen, the feeding of the catalytic component (Al compound) and the discharge of the slurry in the reactor for copolymerization in the second step are shown by horizontal linear arrow lines (long arrow). They show the feeding or discharge at substantially constant rates per unit of time. The feeding of the solid catalytic component in the first reactor in the first step is shown by lines drawn at interval (short arrow). They show that the catalyst is fed during the time shown by the lines drawn at interval. The discharge of the slurry in the same reactor is shown by the lines drawn at interval. They show that the slurry is discharged during the time shown by the lines drawn at interval. The triangular form of the levels in the first and second reactors in the first step show that the levels in the reactors are respectively increased and decreased depending upon the intermittent discharge of each slurry of the polymer. The horizontal line of the level in the reactor for copoiymerizntion in the second step shows the substantial unchange of the level in the reactor. In the first reactor in the first step, the operation from the stop of the discharge of the polymer from the reactor will be illustrated. When the discharge of the slurry of the polymer is stopped, tlie feeding of the dispersion of the solid titanium-containing catalytic component in a medium through the catalyst feeding line is immediately started. The amount of the feeding is to correspond to the amount of the polymerization in one cycle to the next feeding (the time shown as C in Figure 1). The feeding can be carried out by using a constant quantitative pump or also by directly compressing from the tank. The time required for the feeding of the solid catalytic component (the time shown as T1 in Figure 1) is preferably shorter and is depending upon the capacity of the supply pump and is usually in a range of 2 to 15 min. The discharge of the polymer from the first reactor in the first step is stopped during the time feeding the solid catalytic component (the time shown as T1 in Figure 1) and the following time ( the time shown as T2 in Figure 1). During the times, the solid catalytic component is not discharged from the first reactor and the polymer is grown to reach the predetermined catalitic efficiency. Therefore, the short-pass of the solid catalytic component to the reactor for copolymerization can be prevented. The time T2 is selected from the range of 5 to 50% of the total residence time of the components in the reactor for polymerization of propylene in the first step (when two reactors are used in the first step, the total of the residence times in the two reactors). The process of the present invention is the continuous process for producing a propyleneethylene block copolymer. Thus, in the case of the first step of using a plurality of reactors, the time T2 must be selected from the range shorter than the residence time in the first reactor in the first step. When the time T2 is shorter than 5% of the total residence time, the effect for the intermittent discharge of the polymer is not satisfactory whereas when it is longer than 50%, the effect is not further improved ntld on the other hand, the productivity per a capacity of the reactors is reduced to be unfavorable in an industrial process. The time T2 in the practical operation is 15 min. or longer preferably 20 min. or longer. The intermittent feeding of the solid catalytic component is to prevent the disadvantages caused by the short-pass. On the other hand, the second component of the catalyst (organoaluminum compound), the third component are homogeneously dispersed in the reaction system whereby it is unnecessary to intermittently feed these components and it is possible to continuously feed them. It is, however, possible to premix the first, second and third components of the catalyst out of the reactors and to feed them by the intermittent feeding for the first component. After the time T2 from the finish of the feeding of the solid catalytic component, the discharge of the polymer is restarted. The time required for the discharge (the time T3 in Figure 1) is not critical and is preferably equal to the time for stopping the discharge of the polymer in view of the operation. The velocity of the discharge is preferably set to be faster than the velocity for producing the polymer in the reactor and preferably by 1.5 to 3 times of the velocity for producing the polymer. The discharge of the polymer is stopped again after the predetermined time and the feeding of the solid catalytic component is restarted at substantially the same time. Propylene as the source and the medium are usually continuously fed at constant rates. In such case, the level in the first reactor in the first step (the level of powder in the case of the vapor phase polymerization) raises depending upon the stop of the discharge of the polymer and the level in the second reactor connected to the first reactor is lowered. During the discharge of the polymer, the level of the first reactor is lowered and the level of the second reactor is raised (see levels in Figure 1). The variation caused by the intermittent discharge of the polymer from the first reactor to the second reactor can be absorbed by the variation of the levels in the reactors whereby the discharge from the second reactor can be continuously carried out to maintain the stable operation. When the polymerization of propylene in the first step is carried out in only one reactor, the second reactor connected in series is the reactor for copolymerization in the second step. In such case, the variation of the ratio of the homopolymerization and the copolymerization as pulsation, is caused by the intermittent discharge of the polymer from the first reactor. Therefore, the operation is not easy. It is preferable to carry out the polymerization of propylene in the first step by using two or more reactors. In such case, the polymer of propylene grown in substantially constant grain size is continuously obtained from the second reactor in the first step and is fed into the reactor for copolymerization in the following second step. In the reactor for copolymerization of propylene and ethylene in the second step, the polymer continuously fed from the first step, the medium, the dissolved monomer, ethylene, propylene, the additional hydrogen, the additional aluminum halide compound are fed. One embodiment placing a classification system between the first step and the second step will be illustrated. In the process, the slurry of polypropylene is discharged from the reactor and is fed into a classification system. In the classifcation system, it is separated into a slurry of fine grains which will be returned to the reactor for polymerization of propylene and a slurry of course grains which will be fed into the following reactor for copolymerization of propylene and ethylene. In the classification system used in the process of the present invention it is possible to use a known classifier such as a liquid cyclone and it is preferable to use a classification system of a combination of a concentrator and hydraulic sedimentation classifier so as to effectively perform the classification. The operation of the use of the classification system of the combination of the concentrator and the hydraulic sedimentation classifier will be illustrated. The polypropylene produced in the first step is discharged from the reactor at a concentration of the slurry of 5 to 60 wt.% preferably 20 to 50 wt.%, and is fed into the concentrator. The slurry of polypropylene fed into the concentrator is separated into a concentrated slurry of polypropylene and a supernatant. The concentration of the concentrated slurry of polypropylene is controlled in a range of 5 to 75 wt.% preferably 20 to 70 wt.%. The concentration of the grains in the supernatant is preferably low and is usually 0.5 wt.% or lower especially in a range of 0.001 to 0.1 wt.%. The ratio of the concentrated slurry of polypropylene to the supernatant is depending upon the property of the slurry of polypropylene and the property of the concentrator and is usually in'a range of 50 : 50 to 99 : 1 by weight. The concentrator used in the process of the present invention can be a liquid cyclone, a centrifugal separator, and a filter. The liquid cyclone is especially preferable because of easy operation in the continuous operation, compact and economical and small area of installation. When a plurality of the concentrators are connected in series to feed a supernatant of the first concentrator to the second concentrator, the concentration af grains in the supernitunt discharged from the second concentrntor can be further reduced to incrcuse the effect of classification by the hydraulic sedimentation classifier. It is unnecessary to consider a special form of the liquid cyclone. It is preferable to consider a size to give smaller grain sizes in the classification. A slurry feed pipe preferably has a diameter for a slurry feed linear velocity of 1 mlsec. or higher especially 3 mlsec. or higher. The liquid cyclone preferably has smaller diameter of an inner cylinder as far as a pressure loss is allowable. The concentrated slurry of polypropylene and the supernatant discharged from the concentrator are respectively fed to the upper part and the lower part of the hydraulic sedimentation classifier to countercurrently contact them in the classifier cylinder. The polypropylene sedimented by the countercurrent contact is discharged from the bottom of the classifier and is fed into the reactor for copolymerization of propylene and ethylene. The polypropylene remaining without the sedimentation is discharged from the upper part of the classifier and is returned to the reactor for polymerization of propylene. A ratio of the slurry returned to the reactor for polymerization of propylene to the slurry fed into the reactor for copolymerization of propylene and ethylene is in a range of 30 : 70 to 99 : 1 preferably 50 : 50 to 98 : 2 by weight. The hydraulic sedimentation classifier is not critical and preferablY has a ratio of a length of the cylinder to a diameter of 2 or more and has n tapered bottom connected to the lower part of the cylinder. The residence time of the slurry of polypropylene in the classifier is depending upon a capacity of the classifier and a rate of the discharge of the slurry of polypropylene in the hydraulic sedimentation and is usually 1 min. or longer preferably 3 min. or longer and is decided by the capacity of the classifier or the rate of discharge. Referring to the drawings, the operation will be illustrated. Figures 2 to 4 are now diagrams of one embodiment for producing a propylene-ethylene block copolymer of the present invention. Figure 2 is a flow diagram of the embodiment placing a classification system between the reactor for polymerization of propylene and the reactor for copolymerization of propylene and ethylene. Referring to Figure 2, the embodiment will be illustrated. A catalyst for polymerization of propylene is fed through the catalyst feed pipe (1) into the reactor for polymerization of propylene A and a liquid propylene is fed through the propylene feed pipe (2) into the reactor A to perform the polymerization of propylene. The resulting slurry of polypropylene is discharged from the reactor A and is fed through the slurry discharge pipe (3) to the liquid cyclone B. In the liquid cyclone B, it is separated into the concentrated slurry of polypropylene and the supernatant. The concentrated slurry of polypropylene is discharged from the bottom of the liquid cyclone B and is fed through the concentrated polypropylene slurry discharge pipe (5) to the upper part of the hydraulic sedimentation classifier C. On the other hand, the supernatant is discharged from the upper part of the liquid cyclone B and is fed through the supernatant discharge pipe (4) to the lower part of the hydraulic sedimentation classifier C. The concentrated slurry of polypropylene and the supernatant arc countcrcurrcntly ccntmctal in the classification cylinder of the hydralic sedimentation classifier C and the polypropylene sedimented by the contact is discharged from the bottom of the hydraulic sedimentation classifier C and is fed through the discharge pipe (7) to the reactor for copolymerization of propylene and ethylene D. On the other hand, the polypropylene rerraining(not sedimented) by the hydraulic sedimentation is discharged from the upper part of the hydraulic sedimentation classifier C and is returned through the discharge pipe (6) to the reactor for polymerization of propylene A. Into the reactor for copolymerization of propylene and ethylene D, the polypropylene obtained by the hydraulic sedimentation is fed and ethylene and if necessary, additional propylene are respectively fed through the ethylene feed pipe (8) and the propylene feed pipe (9) to perform the copolymerization of propylene and ethylene. In the process of the present invention, it is indispensable to feed the specific aluminum halide compound through the aluminum halide compound feed pipe (10) to the reactor for copolymerization of propylene and ethylene. The resulting propylene-ethylene block copolymer is discharged from the polymer discharge pipe (11) and is used as a product. Figure 3 is a flow diagram of the embodiment using two liquid cyclones connected in series in the classification system. The supernatant discharged from the first liquid cyclone B1 is fed to the second liquid cyclone B2. In the second liquid cyclone B2, the fine grains contained in the supernatant discharged from the first liquid cyclone B1 are further separated to obtain the supernatant which does not substantially contain polypropylene grains. The supernatant is fed through the supernatant discharge pipe (4') to the hydraulic sedimentation classifier C. When two liquid cyclones are used, a concentration of grains in the supernatant fed from the second liquid cyclone B2 to the hydraulic sedimentation classifier C is almost zero and the effect for classification in the hydraulic sedimentation classifier is increased. Thus, the fine grains of polypropylene fed to the reactor for copolymerization of propylene and ethylene can be extremely reduced. Figure 4 is a flow diagram of the embodiment polymerizing propylene in two reactors. In Figure 4, the references A, B, C, D, 1, 2, 3, 4 .... designate the identical parts shown in Figures 2 and 3. In this specification, the term "the rate decrease with tirre" rears to decrease or the phenomenon of decrease of the catalytic activity (polyrreriza- tion activity of catalyst), dependent upon time. The invention will be further illustrated by certain Examples and References which are provided herein for purpose of illustration only and are not intended to be limiting in any manner unless otherwise specified. In the Examples, the measurements are as follows. A melt flow index MFI (g./10 min.) is measured by ASTM D-1238-70 at 2300C under a pressure of 2.16 kg. as a rate of the extrusion. A brittle point temperature Tb(OC) is measured in the direction of flow of a molten resin (MD) and in the perpendicular direction (TD) pursuant to ASTM D-746 by using a specimen obtained by punching a flat sheet having a thickness of 2.0 mm. A first yield strength YS (kg. lcm2) and an ultimate elongation UE(%) are measured by a tensile test of a dumbbel specimen obtained by punching from a pressed sheet having a thickness of 1.0 mm pursuant to ASTM D-638-72. This is measured at 200C otherwise specified. An Izod impact strength (kg.cm/cm) is measured by using a notched rectangular specimen obtained by punching from a pressed sheet having a thickness of 5.0 mm pursuant to ASTM D-256. This is measured at 200C unless otherwise specified. A dart drop impact strength is measured by holding a flat plate having a thickness of 2 mm by a sample holder having n diameter of 65 mm at -400C a dart having a diameter of 1 inch is fallen from a height of 80 cm and showing a load for breaking 509Ó of specimens as an impact energy pursuant to ASTM D-1709. Fish-eyes are measured by bending a press sheet having a thickness of 1 mm nnd observing degree of fish-eyes and classifying it by tic following rating. EMI24.1 <tb> Rating <SEP> Fish-eyes <tb> <SEP> substantially <SEP> none <tb> <SEP> quite <SEP> small <tb> <SEP> A <SEP> small <tb> <SEP> X <SEP> many <tb> Fine gels which are not observed are counted by forming a film having a thickness of 30u by a die having a diameter of 100 mm and cutting the film in a size of 250 cm2 and counting a total number of fine gels by macrophotography. The number of the fine gels is shown by the following ratings. EMI24.2 <tb> Rating <SEP> Number <SEP> of <SEP> fine <SEP> gels <tb> <SEP> 0 <SEP> less <SEP> than <SEP> 50 <tb> <SEP> A <SEP> 50 <SEP> or <SEP> more <SEP> and <SEP> less <SEP> than <SEP> 300 <tb> <SEP> 'A <SEP> 300 <SEP> or <SEP> more <SEP> and <SEP> less <SEP> than <SEP> 2000 <tb> <SEP> ## <SEP> 2000 <SEP> or <SEP> more <tb> The stabilizers, the aluminum compounds and the electron donors used in the examples and references are shown as follows. EMI25.1 <tb> Stabilizer <tb> BHT <SEP> 2,6-di-t-butyl-p-cresol <tb> Irganox <SEP> pentaerythritol <SEP> tetrakis <SEP> [ <SEP> 3-(4-hydroxy-3,5-di-t- <SEP> <tb> <SEP> butylphenyl) <SEP> propionate] <SEP> (Ciba- <SEP> Geigy) <SEP> <tb> Aluminum <SEP> compound <tb> TEA <SEP> triethylaluminum <SEP> Al( <SEP> C <SEP> 2H <SEP> 5)3 <SEP> <tb> DEA <SEP> diethylaluminum <SEP> monochloride <SEP> Al(C <SEP> 2H5) <SEP> 2C1 <tb> DPA <SEP> di-n-propylaluminum <SEP> monochloride <SEP> Al( <SEP> n-C <SEP> 3H <SEP> 7) <SEP> 2C1 <SEP> <tb> EASC <SEP> ethylaluminium <SEP> sesquichloride <SEP> Al(C2H5)1.5Cl1.5 <tb> EADC <SEP> ethylaluminum <SEP> dichloride <SEP> Al(C2H5)C12 <tb> PADC <SEP> n-propylaluminum <SEP> dichloride <SEP> Al(n-C <SEP> 3H <SEP> 7) <SEP> Cl2 <SEP> <tb> BADC <SEP> i-butylaluminum <SEP> dichloride <SEP> Al(i-C4H9)Cl2 <SEP> <tb> Electron <SEP> donor <tb> DBE <SEP> di-n-butyl <SEP> ether <SEP> (n <SEP> C4Hg)2O <SEP> <tb> DOE <SEP> di-n-octyl <SEP> ether <SEP> (n-C8H17)20 <SEP> <tb> DPE <SEP> diphenyl <SEP> ether <SEP> (C6H5)20 <SEP> <tb> DBS <SEP> di-n-butyl <SEP> thioether <SEP> (n-C4H9)2S <SEP> <tb> DAE <SEP> di-i-amyl <SEP> ether <SEP> ((CH3) <SEP> 2CHCH2CH2j <SEP> 20 <SEP> <tb> MMA <SEP> methyl <SEP> methacrylate <SEP> CH2C(CH3)COOCH3 <SEP> <tb> EtOH <SEP> ethanol <SEP> C2H5OH <tb> The examples and references are shown in Tables 1 to 4 as follows: Table 1: Examples 1 - 14 Table 2: References 1 - 8 Table 3: Examples 15 - 28 Table 4: Examples 30 - 33 Preparation of Catalyst 1: (A) Preparation of solid titanium trichloride type catalytic complex: Into a 10 liter autoclave purged with nitrogen, 5.0 1. of n-hexane and 3.0 mol. of titanium tetrachloride were charged and 2.7 mol. of di-n-octyl ether was added. The mixture was stirred at 250C and a solution of 1.0 mol. of diethylaluminum monochloride in 0.5 1. of n-hexane was added dropwise to obtain a homogeneous solution of titanium trichloride in n-hexane in greenish black-brown color. The solution of titanium trichloride was heated to 950C. During the heating, a formation of purple precipitate of titanium trichloride was found. After stirring the reaction mixture at 950C for 1 hour, the precipitate was filtered and repeatedly washed with n-hexane to obtain fine powdery solid titanium trichloride type catalytic complex. An elemental analysis showed that the catalytic complex had the formula: TiCl3(AlCl3)0 003[ (n¯C8Hl7)2 ]0. 11 (B) Pretreatment with propylene: Into a 20 liter autoclave purged with nitrogen, 12.5 1. of n-hexane was charged and stirred and 1.6 mol. of di-n-propylaluminum monochloride and the solid titanium trichloride type catalytic complex obtained by the step (A) were charged to give 250 g. of TiOl3 component. Then, the temperature in the autoclave was controlled to 300C and propylene gas was fed with stirring at the same temperature until polymerizing 1250 g. of propylene. The resulting precipitate was separated and repeatedly washed with n-hexanc to obtain n polypropylene-containing titanium trichloride. Preparation of Catalyst 2: (A) Preparation of solid titanium trichloride type catalytic complex: Into a 10 liter autoclave purged with nitrogen, 1.0 1. of n-hexane and 2.0 mol. of titanium tetrachloride were charged and the mixture was cooled to 50C and stirred and a solution of 4.0 mol. of ethylaluminum sesquichloride in 2.0 1. of n-hexane was added dropwise during 30 min. After the addition, the reaction mixture was stirred at 50C for 2 hours in aging and the resulting precipitate was repeatedly washed with n-hexane to obtain a reddish purple solid product. n-Hexane was added to give 3.0 1. and then 0.42 1. of diisoamyl ether was added to react them at 300C for 1 hour while stirring. The resulting precipitate was repeatedly washed with n-hexane and dried under a reduced pressure to obtain a brown product. Then, 8 mol. of titanium tetrachloride was added to the product to react them at 350C for 1.5 hours and the precipitate was repeatedly washed with n-hexane to obtain a purple solid titanium trichloride type catalytic complex. An elemental analysis showed that the catalytic complex has the formula: TiCl3- (AlC13) o 01[ (i-C5H1l) 2 ] 0.11 (B) Pretreatment with propylene: In accordance with the process of Preparation of catalyst 1 (B), the solid titanium trichloride type catalytic complex obtained in the step (A) was pretreated with propylene. EXAMPLE 1: Three reactors each equi with a stirrer which respectively had capacities of 170 1., 70 1. and 60 1. were connected in series and used for a continuous polymerization in two steps. In the first and second reactors, a homopolymerization of propylene was carried out. In the third reactor, a copolymerization of propylene and ethylene was carried out. Into the first reactor, liquid propylene; hydrogen at a content of 5.5 mol % as a vapor phase hydrogen concentration; the titanium trichloride obtained in the step (B) of Preparation of catalyst 1; dl-n-propylaluminum monochloride (DPA) at a molar ratio of 8 based on TiCl3; phenyl acetate at a molar ratio of 0.13 based on TiC13 were charged. A polymerization temperature in the first reactor was 700C and an average residence time (polymerization time) was 4.5 hours. The reaction mixture discharged from the first reactor was fed into the second reactor and additional liquid propylene and hydrogen at a content of 6 mol 9s as a vapor phase hydrogen concentration were also continuously fed. A polymerization temperature in the second reactor was 670C and an average residence time (polymerization time) was 1.6 hours. The reaction mixture discharged from the second reactor was fed into the third reactor and liquid propylene and ethylene were continuously fed to give 65 mol % of a vapor phase propylene concentration and a vapor phase hydrogen concentration was controlled to be 3 mol 96. Ethylaluminum dichloride (EADC) was charged to give a molar ratio of EADC/DPA of 0.08. A polymerization temperature in the third reactor wns 450C and an average residence time (polymerization time) was 1.5 hours. The reaction mixture discharged from the third reactor was flushed to purge the unreacted propylene and the polymer obtained by the polymerization was separated as a polymer powder and continuously treated at 1200C with propylene oxide gas. The resulting powdery product was admixed with 0.1 wt.% of BHT as an additive 0.1 wt.% of Irganox, 0.2 wt.% of dilaurylihiodipropionate and 0.2 wt.% of calcium stearate. The mixture was kneaded ut 22O0C by u uniaxlul extruding mciilne having an inner diameter of 40 mm and it was pressed to form a press sheet. Various physical properties of the product were measured. As a result, the fish-eyes was not substantially found as i) MFI was 2.3; the brittle point temperature Tb was -23. 20C; the ultimate elongation UE was 762%; the first yield strength YS was 265 kg/cm2 and the Izod impact strength was 11.5 kg.cm/cm. EXAMPLES 2 to 9: The homopolymerization of propylene was carried out in the first reactor and the second reactor under the same condition set forth in Example 1. Each copolymerization of propylene and ethylene in the third reactor was carried out by feeding each aluminum compound. The kind and amount of the aluminum compound are shown in Table 1. The polymerization condition in the third reactor was varied as shown in Table 1 so as to give the same ratio of the polymer produced in the third reactor. In accordance with the process of Example 1 except said modifi cntion, each polymerization and each kneading were carried out to produce each press sheet and various physical properties were measured. The rcsuits are shown in Table 1. REFERENCES 1 to 4: The homopolymerization of propylene was carried out in the first reactor and the second reactor under the same condition as set forth in Example 1. In a copolymerization of propylene and ethylene in the third reactor, any additive was not newly added in Reference 1; triethylaluminum (AlEt3) was added in Reference 2; methyl methacrylate (MMA) was added in Reference 3 and ethanol (EtOH) was added in Reference 4 at each content shown in Table 2. Each polymerization condition in the third reactor was varied as shown in Table 2 so as to give the same ratio of the polymer in the third reactor. In accordance with the process of Example 1 except said modification, each polymerization and each kneading were carried out to produce each press sheet and various physical properties were measured. The results are shown in Table 2. In accordance with the process of the present invention by adding a specific aluminum compound in the copolymerization of propylene and ethylene in the examples and the references, the block copolymers for products having less fish-eyes, low brittle point temperature as improved cold shortness; large ultimate elongation and high impact strength can be obtained. EXAMPLES 10 to 14: The reactors, each equipped with a stirrer used in Example 1 were used for a continuous polymerization in two steps. In the first and second reactors, a homopolymerization of propylene was carried out. In the third reactor, n copolymerization of propylene and ethylene was carried out. Into the first reactor; liquid propylene; hydrogen ut a content of 5.5 mol 96 as a vapor phase hydrogen concentration; the titanium trichloride obtained in the step (B) of Preparation of catalyst 2; diethylaluminum monochloride (DEA) at a molar ratio of 8 based on Tic3; phenyl acetate at a molar ratio of 0.2 based on TiCl3 were charged. A polymerization temperature in the first reactor was 700C and an average residence time (polymerization time) was 4.5 hours in the first reactor. The reaction mixture discharged from the first reactor was fed into the second reactor and additional liquid propylene and hydrogen at a content of 6 mol % as a vapor phase hydrogen concentration were also continuously fed. A polymerization temperature in the second reactor was 670C and an average residence time (polymerization time) was 1.6 hours. The reaction mixture discharged from the second reactor was fed into the third reactor and liquid propylene and ethylene were continuously fed to give 65 mol 96 of a vapor phase propylene concentration and a vapor phase hydrogen concentration was controlled to be 3 mol %. Each aluminum compound was charged. The kind and the amount of the aluminum compound are shown in Table 3. Each polymerization condition in the third reactor is shown in Table 3. The reaction mixture discharged from the third reactor was flushed to purge the unreacted propylene and the polymer obtained by the polymerization was separated as a polymer powder and continuously treated at 1200C with propylene oxide gas. The resulting powdery product was admixed with 0.1 wt.% of BHT as an additive 0.1 wt.% of"lrganox: 1010" 0.2 wt.9u of dilaurylthiodipropionate and 0.2 wt.% of calcium stearate. The mixture was kneaded at 2200C by a uniaxial extruding machine having an inner diameter of 40 mm for two times and it was pressed to form a press sheet. Various physical properties of the product were measured. The results are shown in Table 1. In accordance with the process of the present invention, fish-eyes, the brittle point Tb, the ultimate elongation UE and the Izod impact strength are remarkably improved. REFERENCES 5 and 6: In accordance with the process of Example 1 except varying the condition in the third reactor as shown in Table 2 without varying the conditions in the first and second reactors, each polymerization and each test were carried out. The results are shown in Table 2. REFERENCES 7 and 8: Three reactors, each equipped with a stirrer which respectively had capacities of 170 1., 70 1. and 60 1. were connected in series and a 5 1. vessel was placed between second and third reactors. These reactors and vessel were used for a continuous polymerization in two steps. In the first and second reactors, a homopolymerization of propylene was carried out as the first step under the same condition for the homopolymerization of propylcne in Example 1. The reaction mixture discharged from the second reactor was fed into a 5 1. vessel and AIEtC12 was charged to give a molar ratio of AIEtCl2/DPA of 0.08 in Reference 7 and 0.16 in Reference 8. A treating temperature in the 5 1. vessel was 670C and an average residence time (treating time) was 5 min. The reaction mixture discharged from the vessel was fed into a 60 1. third reactor and liquid propylene and ethylene were continuously fed to carried out a copolymerization of propylene and ethylene as the second step. The propylene concentration, the hydrogen conccntrntion and the polymerization temperature were respectively liLllt in 65 mol %, 3 mol % and 450C the same ns those of the copolymerization of propylene and ethylene in Example 1, however, an average residence time (polymerization time) was varied as shown in Table 2. The reaction mixture discharged from the third reactor was flushed and the product was treated and kneaded as set forth in Example 1 and various physical properties were measured. The results are shown in Table 2. In comparison with the examples adding AlEtCl2 in the third reactor in the copolymerization of propylene and ethylene in the second step, the fish-eye and the brittle point temperature of the products are inferior in References 7 and 8 reacting AlEtCl2 with a cocatalyst of DPA and adding the reaction product in the third reactor in the copolymerization of propylene and ethylene in the second step. The effect of the addition of AlEtCl2 was not found. In Reference 8, the ratio of the propyleneethylene copolymer to the final polymer product did not reach to 13 - 14% as the desired ratio. In the process of References 7 and 8, only the copolymerization rate in the second step is reduced and the rate decrease with time of the copolymerization is not accelerated. Therefore, the effect of the present invention could not be attained. In the 1process of the present invention, it is important to add the aluminum compound having the formula AIRnêX3-n directly in the copolymerization in the second step without previous mixing and reaction with a cocatalyst. Table 1 EMI34.1 <SEP> Exp. <SEP> 1 <SEP> Exp. <SEP> 2 <SEP> Exp. <SEP> 3 <SEP> Exp. <SEP> 4 <SEP> Exp. <SEP> 5 <tb> <SEP> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> EADC <SEP> EADC <SEP> EADC <SEP> EADC <SEP> EADC <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.08 <SEP> 0.04 <SEP> 0.16 <SEP> 0.25 <SEP> 0.35 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 1.5 <SEP> 1.2 <SEP> 2.2 <SEP> 4.0 <SEP> 6.0 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 2.5 <SEP> 2.5 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 13.5 <SEP> 13.4 <SEP> 13.5 <SEP> 13.4 <SEP> 11.5 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> (%) <tb> <SEP> Final <SEP> Polymer <SEP> Product. <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.3 <SEP> 2.2 <SEP> 2.3 <SEP> 2.1 <SEP> 2.1 <tb> <SEP> Fish-eye <SEP> # <SEP> # <SEP> # <SEP> # <SEP> <SEP> # <tb> <SEP> Brittle <SEP> point <SEP> temp. <SEP> ( C) <SEP> -23.2 <SEP> -15.4 <SEP> -24.5 <SEP> -25.1 <SEP> -24.8 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 762 <SEP> 736 <SEP> 781 <SEP> 776 <SEP> 795 <tb> UE <SEP> (%) <tb> <SEP> First <SEP> yield <SEP> strength <SEP> 265 <SEP> 263 <SEP> 268 <SEP> 260 <SEP> 275 <tb> YS <SEP> (kg/cmê) <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 11.5 <SEP> 11.8 <SEP> 10.5 <SEP> 12.5 <SEP> 10.2 <tb> <SEP> (kg.cm/cm) <tb> Table 1' EMI35.1 <tb> <SEP> Exp. <SEP> 6 <SEP> Exp. <SEP> 7 <SEP> Exp. <SEP> 8 <SEP> Exp. <SEP> 9 <SEP> Exp. <SEP> 10 <tb> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> EASC <SEP> EASC <SEP> PADC <SEP> BADC <SEP> EADC <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.08 <SEP> 0.35 <SEP> 0.10 <SEP> 0.10 <SEP> 0.08 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 1.3 <SEP> 5.5 <SEP> 1.5 <SEP> 1.5 <SEP> 1.5 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 2.5 <SEP> 3 <SEP> 3 <SEP> 3 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 13.6 <SEP> 12.5 <SEP> 13.4 <SEP> 13.3 <SEP> 13.1 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> (%) <tb> <SEP> Final <SEP> Polymer <SEP> Product. <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.1 <SEP> 2.4 <SEP> 2.1 <SEP> 2.2 <SEP> 2.1 <tb> <SEP> Fish-eye <SEP> # <SEP> # <SEP> <SEP> # <SEP> # <SEP> <SEP> # <tb> <SEP> Brittle <SEP> point <SEP> temp. <SEP> ( C) <SEP> -12.5 <SEP> -20.8 <SEP> -22.6 <SEP> -18.4 <SEP> -21.4 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 688 <SEP> 766 <SEP> 758 <SEP> 745 <SEP> 785 <tb> <SEP> UE <SEP> (%) <tb> <SEP> First <SEP> yield <SEP> strength <SEP> 260 <SEP> 265 <SEP> 262 <SEP> 267 <SEP> 253 <tb> <SEP> YS <SEP> (kg/cmê) <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 12.3 <SEP> 10.8 <SEP> 11.8 <SEP> 10.7 <SEP> 11.2 <tb> <SEP> (kg.cm/cm) <tb> Table 1' EMI36.1 <tb> <SEP> Exp. <SEP> 11 <SEP> Exp. <SEP> 12 <SEP> Exp. <SEP> 13 <SEP> Exp. <SEP> 14 <tb> <SEP> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> EADC <SEP> EASC <SEP> EASC <SEP> BADC <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.16 <SEP> 0.08 <SEP> 0.20 <SEP> 0.08 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> (0C) <SEP> <tb> <SEP> Polymerization <SEP> time <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 3 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 13.0 <SEP> 13.4 <SEP> 13.5 <SEP> 13.0 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> (%) <tb> <SEP> Final <SEP> Polymer <SEP> Product <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.2 <SEP> 2.4 <SEP> 2.2 <SEP> 1.9 <tb> Fish-eye <SEP> 0 <SEP> O <SEP> <SEP> 0 <tb> <SEP> Brittle <SEP> point <SEP> temp. <SEP> ( C) <tb> <SEP> -25.6 <SEP> -14.3 <SEP> -18.8 <SEP> -17.7 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elonga,tion <SEP> 780 <SEP> 754 <SEP> 788 <SEP> 775 <tb> <SEP> UE <SEP> (%) <tb> <SEP> First <SEP> yicld <SEP> strcngth <SEP> 254 <SEP> 248 <SEP> 246 <SEP> 262 <tb> <SEP> YS <SEP> (KG/cmê) <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 12.2 <SEP> 13.1 <SEP> 12.7 <SEP> 9.5 <tb> <SEP> (kg.cm/cm) <tb> Table 2 EMI37.1 <tb> <SEP> Ref. <SEP> 1 <SEP> Ref. <SEP> 2 <SEP> Ref. <SEP> 3 <SEP> Ref. <SEP> 4 <tb> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> none <SEP> TEA <SEP> MMA <SEP> EtOH <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0 <SEP> 0.2 <SEP> 0.2 <SEP> 0.2 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 1.1 <SEP> 0.55 <SEP> 1.1 <SEP> 1.5 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 3 <SEP> <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 13.9 <SEP> 13.5 <SEP> 13.4 <SEP> 13.5 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> (%) <tb> Final <SEP> Polymer <SEP> Product <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.1 <SEP> 2.2 <SEP> 2.0 <SEP> 2.3 <tb> <SEP> Fish-eye <SEP> X <SEP> X <SEP> X <SEP> X <tb> <SEP> Brittle <SEP> point <SEP> temp.( C) <SEP> -5.1 <SEP> -4,7 <SEP> -8:5 <SEP> -4.2 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 486 <SEP> 426 <SEP> 467 <SEP> 409 <tb> <SEP> UE <SEP> (%) <SEP> <tb> <SEP> First <SEP> yicld <SEP> strength <tb> <SEP> YS <SEP> (kg!cm2) <SEP> 263 <SEP> 270 <SEP> 266 <SEP> 264 <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 9.0 <SEP> 8.2 <SEP> 8.4 <SEP> 9.2 <tb> <SEP> (kg.cm/cm) <tb> Table 2' EMI38.1 <SEP> Ref. <SEP> 5 <SEP> Ref. <SEP> 6 <SEP> Ref. <SEP> 7 <SEP> Ref. <SEP> 8 <tb> <SEP> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> none <SEP> TEA <SEP> EADC <SEP> EADC <tb> <SEP> AIRnêCl3-n/AIRnÚCl3-m <SEP> 0 <SEP> 0.2 <SEP> 0.08 <SEP> 0.16 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerisation <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 1.1 <SEP> 0.6 <SEP> 1.7 <SEP> 2.2 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 3 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> Ratio <SEP> of <SEP> polymer <SEP> (3rd <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <SEP> 13.4 <SEP> 13.0 <SEP> 13 <tb> <SEP> (%) <tb> <SEP> Final <SEP> Polymer <SEP> Product <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.1 <SEP> 2.4 <SEP> 2.2 <SEP> 3.3 <tb> <SEP> Fish-eye <SEP> X <SEP> <SEP> X <SEP> X <tb> <SEP> Brittle <SEP> point <SEP> temp.( C) <tb> <SEP> -4.6 <SEP> -3.8 <SEP> -7.5 <SEP> -8.6 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 495 <SEP> 415 <SEP> 525 <tb> <SEP> UE <SEP> <SEP> t%) <SEP> <tb> <SEP> First <SEP> yield <SEP> strength <tb> <SEP> YS <SEP> (kg/cmê) <SEP> 261 <SEP> 256 <SEP> 255 <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 8.0 <SEP> 7.6 <SEP> 10.2 <tb> <SEP> (kg.cm/cm) <tb> EXAMPLE 15: The homopolymerization of propylene was carried out in the first reactor and the second reactor under the same condition set forth in Example 1. The reaction mixture discharged from the second reactor was fed into the third reactor and liquid propylene and ethylene were continuously fed to give a propylene concentration of 65 mol 96 in the vapor phase and a hydrogen concentration in the vapor phase was controlled to give 3 mol %. A toluene solution of a complex of aluminum trichloride (AlCl3) and butyl ether (DBE) (1 : 1) was fed to give a molar ratio of AlCl3 lDPA of 0.08. In accordance with the process of Example 1 except said modification, the polymerization and the kneading were carried out to produce a press sheet and various physical properties were measured. The results are shown in Table 3. EXAMPLES 16 to 23: The homopolymerization of propylene was carried out in the first reactor and the second reactor under the same condition set forth in Example 1. Each copolymerization of propylene and ethylene in the third reactor was carried out by feeding a mixture of each aluminum compound and each electron donor. The kinds and the amounts of the aluminum compound and the electron donor are shown in Table 3. The polymerization condition in the third reactor was varied as shown in Table 3 so as to give the same ratio of the polymer produced in the third reactor. In accordance with the process of Example 15, except said modification, each polymerization and each kneading were carried out to produce cach press sheet and various physical properties were measured. The results are shown in T;tblo 3. EXAMPLES 24 to 28: The reactors, each equipped with a stirrer used in Example 1 were used for a continuous polymerization in two steps. In the first and second reactors, a homopolymerization of propylene was carried out. In the third reactor, a copolymerization of propylene and ethylene was carried out. Into the first reactor, liquid propylene; hydrogen at a content of 5.5 mol % as a vapor phase hydrogen concentration; the titanium trichloride obtained in the step (B) of Preparation of catalyst 2; diethylaluminum monochloride (DEA) at a molar ratio of 8 based on TiCl3; phenyl acetate at a molar ratio of 0.2 based on TiCl3 were charged. A polymerization temperature in the first reactor was 700C and an average residence time (polymerization time) was 4.5 hours in the first reactor. The reaction mixture discharged from the first reactor was fed into the second reactor and additional liquid propylene and hydrogen at a content of 6 mol 9s as a vapor phase hydrogen concentration were also continuously fed. A polymerization temperature in the second reactor was 670C and an average residence time (polymerization time) was 1.6 hours. The reaction mixture discharged from the second reactor was fed into the third reactor and liquid propylene and ethylene were continuously fed to give 65 mol % of a vapor phase propylene concentration and a vapor phase hydrogen concentration was controlled to be 3 mol %. The compounds shown in Table 3 were continuously charged. The kinds and the amounts of the compounds are shown in Table 3. Each polymerization condition in the third reactor is shown in Table 3. The reaction mixture discharged from the third reactor was flushed to purge the unreacted propylene and the polymer obtained by the polymerization was separated as a polymer powder and continuously treated at 1200C with propylene oxide gas. The resulting powdery product was admixed with 0.1 wt.% of BHT as an additive 0.1 wt.% of Irganox, 0.2 wt.% of dilaurylthiodipropionate and 0.2 wt.% of calcium stearate. The mixture was kneaded at 2200C by a uniaxial extruding machine having an inner diameter of 40 mm and it was pressed to form a press sheet. Various physical properties of the product were measured. The results are shown in Table 3. In accordance with the process of the present invention, fish-eyes, the brittle point Tb, the ultimate elongation UE and the Izod impact strength are remarkably improved. Table 3 EMI42.1 <SEP> Exp. <SEP> 15 <SEP> Exp. <SEP> 16 <SEP> Exp. <SEP> 17 <SEP> Exp. <SEP> 18 <SEP> Exp. <SEP> 19 <tb> <SEP> Third <SEP> reactor <tb> Kind <SEP> 2 <SEP> AlCl2, <SEP> AlCl2, <SEP> AlCl2, <SEP> AlCl2, <SEP> AlCl2, <tb> <SEP> Electron <SEP> donor <SEP> DBE <SEP> DBE <SEP> DOE <SEP> DOE <SEP> DPE <tb> <SEP> (molar <SEP> ratio) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 2) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 1 <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.08 <SEP> 0.05 <SEP> 0.15 <SEP> 0.25 <SEP> 0.35 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 1.5 <SEP> 1.3 <SEP> 2.2 <SEP> 4.0 <SEP> 6.0 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 2.5 <SEP> 2.5 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <SEP> 13.6 <SEP> 13.5 <SEP> 13.6 <SEP> 13.7 <SEP> 11.5 <tb> <SEP> (%) <tb> <SEP> Final <SEP> Polymer <SEP> Product <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.2 <SEP> 2.5 <SEP> 2.7 <SEP> 2.5 <SEP> 2.6 <tb> <SEP> Fish-eye <SEP> # <SEP> # <SEP> <SEP> # <SEP> <SEP> # <SEP> # <tb> <SEP> Brittle <SEP> point <SEP> temp. <SEP> ( C) <SEP> -21.4 <SEP> -17.2 <SEP> -25.2 <SEP> -24.2 <SEP> -25.4 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 785 <SEP> 745 <SEP> 788 <SEP> 782 <SEP> 826 <tb> <SEP> UE <SEP> (%) <tb> <SEP> First <SEP> yield <SEP> strength <SEP> <SEP> 267 <SEP> 259 <SEP> 263 <SEP> 254 <SEP> 275 <SEP> <tb> <SEP> YS <SEP> (kglcm2) <SEP> <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 10.8 <SEP> 12.8 <SEP> 11.2 <SEP> 13.4 <SEP> 11.9 <tb> <SEP> (kg.cm/cm) <tb> Table 3' EMI43.1 <SEP> Exp. <SEP> 20 <SEP> Exp. <SEP> 21 <SEP> Exp. <SEP> 22 <SEP> Exp. <SEP> 23 <SEP> Exp. <SEP> 24 <tb> <SEP> Third <SEP> reactor <tb> Kind <tb> <SEP> AIRnêCl3-n <SEP> AlCl3. <SEP> AlCl3. <SEP> EADC. <SEP> EADC. <SEP> AlCl3. <tb> <SEP> Electron <SEP> donor <SEP> MMA <SEP> DBS <SEP> DBE <SEP> DBE <SEP> DAE <tb> <SEP> (molar <SEP> ratio) <SEP> (1 <SEP> :2) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 0.5) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 1) <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.08 <SEP> 0.35 <SEP> 0.10 <SEP> 0.10 <SEP> 0.06 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> <SEP> 1.2 <SEP> 5.5 <SEP> 1.5 <SEP> 1.5 <SEP> 1.5 <SEP> <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 2.5 <SEP> 3 <SEP> 3 <SEP> 3 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 14.2 <SEP> 11.8 <SEP> 13.7 <SEP> 13.6 <SEP> 13.3 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> s <SEP> <tb> <SEP> Final <SEP> Polymer <SEP> Product <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.4 <SEP> 2.4 <SEP> 2.3 <SEP> 2.1 <SEP> 2.4 <tb> <SEP> Fish-eye <SEP> # <SEP> <SEP> # <SEP> # <SEP> <SEP> # <tb> <SEP> Brittle <SEP> point <SEP> temp.(0C) <SEP> -14.8 <SEP> -22.0 <SEP> -20.2 <SEP> -17.8 <SEP> -22.3 <SEP> <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 655 <SEP> 772 <SEP> 748 <SEP> 732 <SEP> 776 <tb> <SEP> UE <SEP> (%) <tb> <SEP> First <SEP> yield <SEP> strength <SEP> 268 <SEP> 224 <SEP> 258 <SEP> 268 <SEP> <tb> <SEP> YS <SEP> (kglem2) <SEP> <SEP> 258 <SEP> 274 <SEP> 258 <SEP> 262 <SEP> 255 <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 13.5 <SEP> 9.8 <SEP> 11.2 <SEP> 11.0 <SEP> 10.4 <tb> <SEP> (kg.cm/cm) <tb> Table 3' EMI44.1 <tb> <SEP> Exp. <SEP> 25 <SEP> Exp. <SEP> 26 <SEP> Exp. <SEP> 27 <SEP> Exp. <SEP> 28 <tb> Third <SEP> reactor <tb> <SEP> Kind <tb> <SEP> AIRnêCl3-n <SEP> AlCl3. <SEP> AlCl3. <SEP> EADC <SEP> EADC <tb> <SEP> Electron <SEP> donor <SEP> DAE <SEP> DAE <SEP> DBE <SEP> DOE <tb> <SEP> (molar <SEP> ratio) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 2) <SEP> (1 <SEP> : <SEP> 1) <SEP> (1 <SEP> : <SEP> 1) <tb> <SEP> AIRnêCl3-n/AIRmÚCl3-m <SEP> 0.15 <SEP> 0.06 <SEP> 0.18 <SEP> 0.06 <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temp. <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 45 <tb> <SEP> ( C) <tb> <SEP> Polymerization <SEP> time <SEP> 2.2 <SEP> 1.5 <SEP> 2.2 <SEP> 1.5 <tb> <SEP> (hr.) <tb> <SEP> Vapor <SEP> phase <SEP> hydrogen <SEP> 3 <SEP> 3 <SEP> 3 <SEP> 3 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Vapor <SEP> phase <SEP> propylene <SEP> 65 <SEP> 65 <SEP> 65 <SEP> 65 <tb> <SEP> concentration <SEP> (mol <SEP> %) <tb> <SEP> Ratio <SEP> of <SEP> polymer <SEP> (3rd <SEP> 13.2 <SEP> 13.2 <SEP> 13.5 <SEP> 13.4 <tb> <SEP> reactor) <SEP> to <SEP> total <SEP> yield <tb> <SEP> (%) <tb> Final <SEP> Polymer <SEP> Product. <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.3 <SEP> 2.2 <SEP> 2.1 <SEP> 2.1 <tb> <SEP> Fish-eye <SEP> # <SEP> # <SEP> <SEP> # <SEP> # <tb> <SEP> Brittle <SEP> point <SEP> temp. <SEP> ( C) <SEP> -23.1 <SEP> -15.6 <SEP> -21.4 <SEP> -14.3 <tb> <SEP> Tb <SEP> (MD) <tb> <SEP> Ultimate <SEP> elongation <SEP> 775 <SEP> 725 <SEP> 766 <SEP> 752 <tb> <SEP> UE <SEP> (%) <tb> <SEP> First <SEP> yield <SEP> strength <SEP> 259 <SEP> 245 <SEP> 246 <SEP> 258 <tb> <SEP> YS <SEP> (kg/cmê) <tb> <SEP> Izod <SEP> impact <SEP> strength <SEP> 11.4 <SEP> 14.5 <SEP> 11.9 <SEP> 9.9 <tb> <SEP> (kg.cm/cm) <tb> EXAMPLE 29: Three reactors, each equipped with a stirrer which respectively had capacities of 170 1., 70 1. and 60 1. were connected in series and used for a continuous polymerization in two steps. In the first and second reactors, a homopolymerization of propylene was carried out. In the third reactor, a copolymerization of propylene and ethylene was carried out. Into the first reactor, liquid propylene (12.7 kg.lhr); hydrogen (2.1 g/hr) at a content of 5.5 mol % as a vapor phase hydrogen concentration; diethylaluminum monochloride (DEA) at a molar ratio of 8 based on TiCl3 (0.33 g./ hr); phenyl acetate at a molar ratio of 0.13 based on TiCl3 were charged. A polymerization temperature in the first reactor was 700C. The feeding of the solid catalytic component of titanium trichloride treated with propylene (Preparation of catalyst 1) and the discharge of the slurry of polymer were carriedout to set in 60 min./cycle as follows: The feeding of the solid catalytic component dispersed in n-hexane was started by a pump just after stop of the discharge of the slurry of polymer. The time required for the feeding including the operation time is 5 min. and the stop of the discharge of the slurry of polymer was continued for 25 min. During the time, the level in the reactor increased for 25% to the original level. Then, the discharge of the slurry of polymer was started and continued at a constant rate of 50 1. Ihr. for 30 min. Thus, the level was changed to the original level in the reactor. Then, the discharge of the slurry of polymer was stopped and the feeding of the solid catalytic component was started and the same operation was repeated. The slurry of polymer which was intermittently discharged from the first reactor was fed inlo the second reactor and additional liquid propylene and hydrogen at n content of 6 mol % as a vapor phnse hydrogen concentration were also continuously fed. A polymerization temperature in the second reactor was 670C and average residence times were respectively 4 hours in the first reactor and 1.5 hours in the second reactor as a total of 5.5 hours. The slurry of polymer was continuously discharged from the second reactor and fed into a reactor for copolymerization in the second step and liquid propylene (0.5 kg./hr.) and ethylene (1.5 kg./hr.) were continuously fed to give 60 mol % of a vapor phase propylene concentration and a vapor phase hydrogen concentration was controlled to be 3 mol %. Ethylaluminum dichloride (EADC) was charged to give a molar ratio of EADC/DEA of 0.14. A polymerization temperature in the third reactor was 400C and an average residence time was 2 hours. The slurry of polymer was continuously discharged at a rate of 23.8 l./hr. so as to maintain substantially constant level. The slurry of polymer discharged was flushed to purge the unreacted propylene and the product was treated with propylene oxide gas and dried to obtain a powdery copolymer. The copolymer had an average ratio of the homopolymer to the copolymer of 84 : 16. The product was admixed with 0.2 wt.% of BHT as a stabilizer and pelletized by using an uniaxial extruding machine having an inner diameter of 40 mm at 2000C and then, it was sheeted in a form of a flat sheet having a thickness of 2 mm by a small injection molding machine. Various physical properties of the product were measured. As a result, MFI was 2.2; and any formation of gel was not found in vision and brittle point temperatures were -250C in MD direction and -210C in TD direction and a Dart drop impact strength at -400C was 310 kg.cm. EXAMPLE 30: A reactor having a capacity of 1.6 m and a reactor having a capacity of 0.6 m3 were connected through a classification system in series. The classification system is a combination of a liquid cyclone (a ratio of length to diameter of 2 and a ratio of taper part to diameter of 3) and a hydraulic sedimentation classifier (a ratio of length to diameter of 7 and a ratio of bottom taper part to diameter of 1.2). The first reactor was used for a homopolymerization of propylene and the second reactor was used for a copolymerization of propylene and ethylene to continuously produce a propylene-ethylene block copolymer. (See Figure 2) Into the first reactor, liquid propylene, hydrogen and the catalyst were continuously fed to perform a bulk polymerization. The catalyst was a combination of polypropylene-containing titanium trichloride obtained in Preparation of catalyst 1 and diethylaluminum chloride at a molar ratio of diethylaluminum chloride to TiCl3 of 3. A polymerization temperature was 700C and a polymerization pressure of 33 kg./cm2G and a vapor phase hydrogen concentration was 5.5 mol % and an average residence time was 4 hours. The level was controlled to maintain in a 3 volume of 1 m A slurry of polypropylene discharged from the reactor for polymerization of propylene had a polymer concentration of about 45 wt.%. The slurry was fed by a pump at a rate of about 5 m3/HR to a liquid cyclone. From the upper part of the cyclone, a supernatant having a grain concentration of about 0.002 wt.% was discharged. From the bottom of the cyclone, a concentrated slurry having a solid concentration of about 53 wit.% was discharged. The supernatant was fed to the lower part of the hydraulic sedimentation classifier at a rate of 1.0 m /HR and the concentrated slurry was fed to the upper part of the classfier at a rate of 4.0 m3/HR. The slurry discharged from the classifier had a solid concentration of about 45 wt.% and was returned at a rate of 4.75 m3)HR to the first reactor (reactor for polymerization of propylene) and the slurry discharged from the bottom of the classifier had a solid concentration of about 45 wt.% and was fed at a rate of 0.25 m3/HR to the second reactor (reactor for copolymerization). A ratio of the slurry (fine grains-containing slurry) returned to the first reactor to the slurry (coarse grain slurry) fed into the second reactor was 95 : 5 by weight. Into the reactor for copolymerization, ethylene, liquid propylene and hydrogen were fed at a vapor phase propylene concentration of 60 65 mol gb and a hydrogen concentration to the sum of ethylene and propylene of 3 mol %. Ethylaluminum dichloride was continuously fed at a molar ratio of ethylaluminum dichloride to diethylaluminum chloride charged in the first reactor of 0.08. A polymerization temperature was 450C and an average residence time was 1.5 hr. and a polymerization pressure was kept in 30 kg. /cm2G. The propylene-ethylene random copolymer was produced at a ratio of the copolymer to the final polymer product of 13.5 wt.%. The resulting slurry of polymer was flushed to purge the unreacted propylene and the product was treated with methanol gas and dried to produce a powdery polymer at a productivity of about 69 kg. /HR. The resulting polymer was admixed with 0.2 wt.% of BHT and was pelletized by using a uniaxial extruding machine having an inner diameter of 40 mm and was sheeted to form a flat sheet having a thickness of 2 mm and a size of 100 x 100 mm by a small injection molding muchine. The final polymer product had a melt flow index of 2.5 (melt flows index of the copolymer of 0.001) and a brittle point temperature of -250C in MD direction and -170C in TD direction and a Dart drop impact strength of 275 kg.cm. Any formation of gel was not found in vision of the flat sheet. The fine gel was evaluated by the tester to find only 40 gels. EXAMPLE 31: The systems of Example 30 were used. In accordance with the process of Example 30 except controlling a molar ratio of ethylaluminum dichloride to diethylaluminum monochloride charged in the first reactor to 0.16 and varying an average residence time to 1.8 hours so as to give a ratio of the copolymer to the final polymer product of 13.5 wt.% a polymerization and tests were carried out. The results are shown in Table 4. EXAMPLE 32: The systems of Example 30 were used. In accordance with the process of Example 30 except charging ethylaluminum sesquichloride instead of ethylaluminum dichloride at a molar ratio of ethylaluminum sesquichloride to diethylaluminum monochloride charged in the first reactor of 0.21 and varying an average residence time to 1.8 hours so as to give a ratio of the copolymer to the final polymer product of 13.5 wt.% a polymerization and tests were carried out. The results are shown in Table 4. EXAMPLE 33: In accordance with the process of Example 30. the rate of the discharge of the slurry of polypropylene from the first reactor was reduced to 1.2 m3/llR and the liquid cyclone and the hydralic sedimentation classifier were replaced to similar devices having each capacity of 1/2 and the average residence time in the first reactor was varied to 2 hours. A supernatant having a grain concentration of about 0.01 wt.% was discharged from the upper part of the liquid cyclone at a rate of 0.6 m3/HR and a concentrated slurry having a solid concentration of 42.4 wt.% was discharged from the bottom of the liquid cyclone at a rate of 0.6 m3/HR. The supernatant was fed to the lower part of the hydraulic sedimentation classifier and the concentrated slurry was fed to the upper part of the classifier. The slurry discharged from the upper part of the classifier had a solid concentration of about 30 wt.% and was returned to the first reactor (reactor for polymerization of propylene) at a rate of 0.7 m /HR. The slurry discharged from the bottom of the classifier had a solid concentration of 30 wt.% and fed into the second reactor (reactor for copolymerization) at a rate of 0.5 m31 HR. A ratio of the slurry returned to the first reactor (fine grains-containing slurry) to the slurry fed to the second reactor (coarse grain slurry) was 58 : 42 by weight. In accordance with the process of Example 30 except controlling ethylaluminum dichloride to give a molar ratio of ethylaluminum dichloride to diethylaluminum monochloride charged in the first reactor of 0. 16 and varying a polymerization temperature to 400C so as to give a ratio of the copolymer to the final polymer product of 14 wit.8, a copoly merization was carried out in the reactor for copolymerization to obtain a powdery polymer at a productivity of 84 kg./HR and tests were carried out. The results are shown in Table 4. Table 4 EMI51.1 <tb> <SEP> Exp. <SEP> 30 <SEP> Exp. <SEP> 31 <SEP> Exp. <SEP> 32 <SEP> Exp. <SEP> 33 <tb> Condition <SEP> of <SEP> classification: <tb> <SEP> flow <SEP> rate <SEP> of <SEP> 3 <SEP> (m3/HR) <SEP> 5 <SEP> 5 <SEP> 5 <SEP> 1.2 <tb> <SEP> solid <SEP> concentration <SEP> of <SEP> 3 <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 30 <tb> <SEP> (wt.%) <SEP> <tb> <SEP> flow <SEP> rate <SEP> of <SEP> 4 <SEP> (m3/HR) <SEP> <SEP> 1.0 <SEP> 1.0 <SEP> 1.0 <SEP> 0.6 <tb> <SEP> solid <SEP> concentration <SEP> of <SEP> 4 <SEP> 0.002 <SEP> 0.002 <SEP> 0.002 <SEP> 0.01 <tb> <SEP> (wt. <SEP> %) <tb> <SEP> flow <SEP> rate <SEP> of <SEP> 6 <SEP> (m /HR) <SEP> 4.75 <SEP> 4.75 <SEP> 4.75 <SEP> 0.7 <tb> <SEP> flow <SEP> rate <SEP> of <SEP> 7 <SEP> (m /HR) <SEP> 0.25 <SEP> 0.25 <SEP> 0.25 <SEP> 0.5 <tb> <SEP> ratio <SEP> flow <SEP> rate <SEP> 6/7 <SEP> (wt:ratio) <SEP> 95/5 <SEP> 95/5 <SEP> 95/5 <SEP> 58/42 <tb> Condition <SEP> of <SEP> copolymerisation: : <tb> <SEP> Additional <SEP> aluminum <SEP> halide <tb> <SEP> Kind <SEP> EADC <SEP> EADC <SEP> EASC <SEP> EADC <tb> <SEP> Amount <SEP> 0.08 <SEP> 0.16 <SEP> 0.21 <SEP> 0.16 <SEP> <tb> <SEP> (molar <SEP> ratio) <tb> <SEP> Polymerization <SEP> temperature <SEP> 45 <SEP> 45 <SEP> 45 <SEP> 40 <tb> <SEP> ( C) <tb> <SEP> Residence <SEP> time <SEP> (HR) <SEP> 1.5 <SEP> 1.8 <SEP> 1.8 <SEP> 1.5 <tb> <SEP> Ratio <SEP> of <SEP> copolymer <SEP> to <SEP> 13.5 <SEP> 13.5 <SEP> 13.5 <SEP> 14 <tb> <SEP> final <SEP> polymer <SEP> (wt.%) <tb> <SEP> Productivity <SEP> (kg. <SEP> /HR) <SEP> 69 <SEP> 69 <SEP> 69 <SEP> 84 <tb> Result: <tb> <SEP> MFI <SEP> (g/10 <SEP> min.) <SEP> 2.5 <SEP> 2.3 <SEP> 2.2 <SEP> 2.2 <tb> <SEP> Tb <SEP> MD <SEP> direct. <SEP> ( C) <SEP> -25 <SEP> -25 <SEP> -24 <SEP> -29 <tb> <SEP> TD <SEP> direct. <SEP> ( C) <SEP> -17 <SEP> -19 <SEP> -17 <SEP> -15 <tb> <SEP> Dart <SEP> drop <SEP> impact <SEP> strength <SEP> 275 <SEP> 310 <SEP> 280 <SEP> 250 <tb> <SEP> (kg.cm) <tb> <SEP> Fine <SEP> gels <SEP> O <SEP> O <SEP> 0 <SEP> O <SEP> <tb> Figure 1: * 1: First step polymerization of propylene * 2: Second step copolymerization * 3: First reactor * 4: Second reactor * 5: Propylene feed * 6: Hydrogen feed * 7: Catalyst 2nd and 3rd component feed * 8: Solid catalytic component feed * 9: Slurry discharge * 10: Level * 11: Additional propylene feed * 12: Additional hydrogen feed * 13: Slurry discharge * 14: Level * 15: Ethylene feed * 16: Additional hydrogen feed * 17: Catalyst Al comp. feed * 18: Slurry discharge * 19: Level

Claims: CLAIMS: 1) In a continuous process for producing a propyleneethylene block copolymer in the presence of a catalyst comprising as main components, a solid titanium-containing catalytic component and an organoaluminum compound having the formula AlR m1Cl3m (R1 represents a C1 20 hydrocarbon moiety; and m is 3 > L m > 1.5) by producing a homopolymer of propylene or a propylene-ethylene copolymer by polymerizing propylene or both propylene and ethylene at a vapor phase propylene concentration of 90 mol % or higher based on the sum of propylene and ethylene in a first step and producing a propylene ethylene block copolymer by copolymerizing propylene and ethylene at a vapor phase propylene concentration of less than 90 mol % based on the sum of propylene and ethylene in the presence of the polymer resulted in the first step, and the catalyst in a second step which is characterized by newly adding an aluminum compound having the formula AIRnêX3-n (Rê represents a C1-20 hydrocarbon moiety: X represents a halogen atom and n is 1.5 2 n ' 0) to the components for the copolymerization in the second step. 2) The process for producing the block copolymer according to Claim 1 wherein said solid titanium-containing catalytic component comprises titanium trichloride, an aluminum halide compound having the formul;i AlR3X p 3-p (R represents n C1-20 hydrocarbon moiety; X represents a halogen atom: and p is 0 5p 5 2) at an atomic ratio of Al to Ti of titanium trichloride of 0.15 or less; and a chelating agent at a molar ratio of the chelating agent to titanium trichloride of 0.001 or more. 3) The process for producing the block copolymer according to Claim 1 wherein said solid titanium-containing catalytic component is obtained by precipitation at 1500C or lower from a liquid containing titanium trichloride dissolved in the presence of an ether or thioether. 4) The process for producing the block copolymer according to Claim 1 wherein said solid titanium-containing catalytic component is obtained by reducing titanium tetrachloride with an organoaluminum compound or aluminum metal and treating the resulting solid titanium trichloride by a chelating agent treatment and a halide treatment. 5) The process for producing the block copolymer according to Claim 1 wherein a molar ratio of said aluminum compound added in the second step to said organoaluminum compound used in the first steps in a range of 0.01 to 0.50. 6) The process for producing the block copolymer according to Claim 1 wherein said aluminum compound is added in a form of a complex with an electron donor in the second step. 7) The process for producing the block copolymer according to Claim 1 wherein said aluminum compound is added in a form of a mixture of said aluminum compound and an electron donor in the second step. 8) The process for producing the block copolymer according to Claim 1 wherein said solid titanium-containing catalytic component is intermittently fed in the first step and the polymer is intermittently discharged from the first step and a time for stop of the intermittent discharge of the polymer is from substantially the same as the initiation of the feeding of said solid titanium-containing catalytic component to 5 to 50% of the residence time of the components in the first step after the finish of the feeding of said catalytic component in the first step. 9) The process for producing the block copolymer according to Claim 1 wherein the polymerization in the first step is carried out in two or more reactors connected in series. 10) The process for producing the block copolymer according to Claim 9 wherein said solid titanium-containing catalytic component is intermittently fed in the first reactor and the polymer is intermittently discharged from the first reactor and the time for stop of the intermittent discharge of the polymer is from substantially the same as the initiation of the feeding of said catalytic component to 5 to 50% of the residence time of the components after the finish of the feeding of said catalytic component in the first step. 11) The process for producing the block copolymer according to Claim 1 wherein a classification system is provided between the first step and the second step. 12) The process for producing the block copolymer according to Claim 11 wherein said ciassfication system is a concentrator. 13) The process for producing the block copolymer according to Claim 11 wherein said classification system is a combination of a concentrator and a hydraulic sedimentation classifier. 14) The process for producing the block copolymer according to Claim 12 wherein said concentrator is a liquid cyclone. 15) The process for producing the block copolymer according to Claim 13 wherein said hydraulic sedimentation classifier has a form of a cylindrical part and a tapered bottom connected to the lower part of the cylindrical part. 16) The process for producing the block copolymer according to Claim 11 wherein a ratio of a slurry returned from said classification system to the first step to a slurry fed to the second step is in a range of 30 : 70 to 99 : 1 by weight.

Inventors: GOKO, NOBUAKI, GOTOH, JUNICHI, HASUO, MASAYOSHI, KAWASHIMA, RIICHIRO, KITADA, HISASHI, MARUYAMA, YASUO, MATUDA, YUKIMASA, NISHIHARA, YASUHIRO, SUGA, YOSHINORI, TAKASHIMA, RYOKICHI, UEHARA, YUMITO, YAMAMOTO, HIDETOSHI
Applicants: MITSUBISHI CHEMICAL INDUSTRIES LIMITED
Application year: 1982
Main classification: C08F297
IPC codes: C08F297