A NEW HERBICIDAL COMPOSITION, PROCESSES FOR ITS PRODUCTION AND ITS USE

Abstract: The invention relates to new herbicidal compositions consisting of one or more herbicidally active substances and one or more certain phospholipides in addition to stan­ dard vehicles, diluents, solvents and/or other inert auxilia­ ries, the ratio by weight of the herbicidally active substance or mixture of herbicidally active substances to pure phos­ pholipide or to the mixture of pure phospholipides amount­ ing to between 1 : 0.2 and 1 : 20. The invention also relates to processes for producing these compositions and to processes for controlling weeds and wild grasses using the new herbicidal compositions.

Description: A new herbicidal composition, processes for its production and its use This invention relates to a new herbicidal composition, to processes for its production and to its use. In order to reduce crop losses by weeds and wild grasses in the cultivation of useful plants, it is now essential to use chemical weed control preparations (herbicides). A large number of chemical substances have been used for controlling weeds and wild grasses. However, herbicides currently in use are still attended by some as yet unsolved problems. Chemical weed control preparations often have to be used in nigh concentrations and, as a result, can become a source of toxic pollution to the environment. The most important requirements which a weed control preparation has to satisfy include the highest possible selectivity ond activity with respect to the weeds and wild grasses for which it is intended, a minimal effect on the useful plants and minimal inter,ere-ce with tne biological environment. Accordingly, the selectivity of a herbicide has to meet stringent demands. In order to reduce pollution or the environment, the quantity of nerbicide required per hectare for controlling weeds and wild grasses should be kept as small as possible, although this often results in a loss of activity. Another requirement which has to be satisfied is ease of handling both during production and during application. It has now surprisingly been found that the quantity of herbicide per hectare of ultivated area required or controlling weeds and wild grasses can be reduced by up t 40 - 60% and, in some cases, by up to 80% providing tne herbicidally active substance or the mixture of several herbicidally active substants is used in conjunction wit:r a phospholipide from the grout comprising phosphatidy! choline, hydrogenated phosphatidyl cholines, phosphatidyl ethanolamine, N-acyl phosphatidyl ethanolamines, phosphatidyl inositol, phosphatidyl serine, lysolecithin and phosphatidyl glycerol or a mixture of several such phospholipides in a ratio by weight of from 1:0.2 to 1:20 without involving any risk of damage or harm to the useful plants. In addition to greater economy of the treatment, the new herbicidal compositions have the advantage that their disintegration, particularly in the useful plants, is accelerated with the result that no residues of herbicides are present in the useful plants at harvest time. By virtue of this rapid disintegration, the waiting times (weed control pending harvest) can also be shortened. Finally, the phospholipides are generally natural and, in every case, non-toxic products which, by virtue of their nature and properties, do not themselves cause any pollution of the environment or have any adverse effect upon the waiting time. Some of the phospholipides are of course even used in foods. To produce the new herbicidal compositions, the herbicides are mixed with the phospholipide(s) in a ratio by weight of from 1:0.2 to l:20, preferably in a ratio by weight of from 1:0.5 to 1:10 and, more preferably, in a ratio by weight of from 1:1 to 1:5. The weight of the phospholipide component is based on substantially pure phospholipide. Suitable phospholipides are, for example, the commercially available phosphatidyl cholines or phosphatidyl choline mixtures such as R Phospholipon 25 (25% of phosphatidyl choline, 25% of phosphatidyl ethanolamine and 20% of phosphatidyl inositol) PhospholiponR 55 (55% of phosphatidyl choline, 25% of phosphatidyl ethanolamine and 2% of phosphatidyl inositol3 R Phospholipon 80 (80% of phosphatidyl choline and 10% of phosphatidyl ethanolamine) R Phospholipon 100 (96% of phosphatidyl choline) R Phospholipon 100H (96% of hydrogenated phosphatidyl choline) phospholiponR 38 (38% of phosphatidyl choline, 16% of N-acetyl phosphatidyl ethanol amine and 4% of phosphatidyl ethanolamine). It is particularly preferred to use natural phosphatidyl cholines which may be produced by the processes described in the following patents: DE-PS No. 1,047,597, DE-PS No. 1, 053,199, DE-PS No. 1,617,679, DE-PS No. 1,617,680, German Patent Applications DE-OS No. 30 47 048, DE-OS No. 30 47 012 or DE-OS No. 30 47 011. Suitable N-acyl phosphatidyl ethanolamines are, in particular, those in which the acyl group emanates from saturated or olefinically unsaturated fatty acids containing zrom 2 to 20 carbon atoms, more particularly from saturated fatty acids containing from 2 to 5 carbon atoms or from. saturated or mono-olefinically unsaturated fatty acids containing 14, 16, 18 or 20 carbon atoms. Virtually any herbicide may be used as the herbicide. Thus, it is possible to use compounds from the group comprising photosynthesis inhibitors, breathing inhibitors, growth promoters, milose inhibitors and germination inhibitors. The following are particularly suitable examples: 1. phenoxy carboxylic acid derivatives corresponding to the following general formula EMI3.1 in which a) R1, R2 and R3 may be the same or different and represent H, CH3 or halogen, particularly chlorine, with the proviso that at most two radicals represent H, R4 represents H or CH3, n represents = 0 - 2, Y = O or S, X = 0, NH or S, R5 - where X = 0 - represents H, linear or branched C1-C12- alkyl, hydroxy alkyl, such as hydroxy ethyl, or alkali or alkaline-earth cations and, in particular, ammonium cations, i.e. salts of the acids with ammonia or organic amines, such as for example hydroxy ethyl amine or trihydroxy ethyl amine, or R5 - where X'= NH - represents H, NH2, phenyl optionally inhibited by 1 to 3 halogen atoms, heterocyclic groups such as, for example, 2-thiazolyl, or b) R1 and R3 represent H, R2 represents EMI4.1 R4 and R5 have the same meaning as in a), R6 represents CH3, halogen or trifluoromethyl and m = 1 - 3. The substances are known compounds which are described in the following patents: US-PS No. 3,352,897, US-PS No. 2,390,942, DE-PS No. 915,876, DE-AS No. 11 15 515, FR-PS No. 1,222,916, GB-PS No. 822,199, GB-PS No. 573,477, DE-AS No. 11 24 296, GB-PS No. 1,041,982, CA-PS No. 570,065, US-PS No. 3,076,025. The, following are examples of compounds corresponding to general formula I: 4-chlorophenoxy acetic acid-N,O-methyl amide, 2,4-dichlorophenoxy acetic acid, 2,4-dichlorophenoxy acetic acid hydrazide, 2-methyl-4-chlorophenoxy acetic acid hydrazide, 2-chloro-4-fluorophenoxy acetic acid, 2-chloro4-fluorophenoxy acetic acid butyl ester, 4-chloro-2-methyl phenoxy acetic acid, 4-chloro-2-methyl phenoxy thioacetic acid, N- (2-chlorophenyl )-4-chloro-2-methyl phenoxy acetic acid amide, N- ( 3-trifluoromethyl-phenyl )-2, 4-dimethyl phenoxy acetic acid amide, 2,4-dimethyl phenoxy acetic acid, 2,4,5-trichlorophenoxy acetic acid, 2-(4-chlorophenoxy)propionic acid, 2-(2-methylphenoxy)-propionic acid, 2-(2methyl-4-chlorophenoxy)-propionic acid (mecoprop), 2-(2methyl-4-chlorophenoxy)-propionic acid-N-(trifluoromethylphenyl)-amide, 2-(2,4,5-trichlorophenoxy)-propionic acid (fenoprop), 2-[4-(2,4-dichlorophenoxy)-phenoxy]-propionic acid, 2-[4-(4-chlorophenoxy)-phenoxy]-propionic acid, 4-(4-chlorophenoxy)-butyric acid, 4-( 4-chloro-2-methylphenoxy) -- butyric acid (MCPB), 4-(2,4,5-trichlorophenoxy)-butyric- acid, but more particularly 2,4-dichlorophenoxy acetic acid (2,4-D) and its salts and esters, such as the sodium or ammonium salt, or salts with ethanol amine or triethanolamine, 2,4 ,5-trichlorophenoxy acetic acid (2,4,5-triphenac) and its salts and esters, which may be used in combination with a phospholipide in particular as a selective leaf herbicide for controlling dicotyledonous weeds such as, for example, knot-grasses, camomile and thistle in cereal crops, corn, rice, sugar cane or grassland. 2. Urea derivatives corresponding to the following general formula EMI5.1 in which R1 and R2 represent H, linear or branched C1-C4-alkyl, -cycloalkyl, halogen, particularly chlorine, trifluoromethyl, nitro, alkoxy, optionally halogen-substituted phenoxy, at most one of the groups R1 and R2 representing H, R3 represents H, CH3, C2H5, R4 represents H, cycloalkyl, C1-C4-alkyl, methoxy. The compounds corresponding to general formula II are known compounds and are described in the following patents: )US-PS No. 2,655,447, DE-PS No. 935,165, DE-PS No. 951,181, DE-OS No. 20 39 041, DE-OS No. 21 07 774, DE-OS No. 21 37 992, DE-OS No. 20 50 776, DE-PS No. 968,273, DE-OS No. 19 05 598. The following are examples of compounds corresponding to formula II: i3-phenyl-1,1-dimethyl urea (fenuron), l-(2-methyl-cyclohexyl)-3-phenyl urea (siduron), 3-(4-isopropyl-phenyl)-1,1-dimethyl urea' (isoproturon), 3-(4-t-butyl-phenyl)-1,1-dimethyl urea, 3-(4-chlorophenyl)-1,1-dimethyl urea (monuron ), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (diuron), N-(3,4-dichlorophenyl-N-diethyl urea, 1-n-butyl-l-methyl-3-(3,4-dichlorophenyl)-urea (neburon), N-(3-trifluoromethylphenyl)-1,1-dimethyl urea (fluometuron), 3-(3-chloro-4-methylphenyl)-1,1-dimethyl urea (chlortoluron), 3-(4-chlorophenyl)-1-methyl-1-(1-methyl-prop-2-ynyl)-urea (butoron), 1-(&alpha;,&alpha; ;-dimethylbenzyl)-3-(4-methylphenyl)-urea, 3-(3-chloro-4-methoxyphenyl)-1,1-dimethyl urea (metoxuron) 3-[(4-chlorophenoxy)-phenyl]-1,1-dimethyl urea (chloroxuran), 3-(4-chlorophenyl)-1-methoxy-l-methyl urea (monolinuron), 3-(4-bromophenyl)-1-methoxy-1-methyl urea (metobromuron), 3-(3,4-dichlorophenyl)-1-methoxy-1-methyl urea (linuron), 3-(3-chloro-4-bromophenyl)-1-methoxy-1-methyl urea (chlorbromuron), 3-[3-chloro-4-(chlorodifluoromethylthio)-phenyl]-1,1-dimethyl urea (thiochlormethyl), but more particularly 3-(4-isopropyl-phenyl )-l,l-dimethyl urea (isoproturon) or 3-(3 , 4-dichlorophenyl )-l-methoxy- l-methyl urea (linuron) which may be used in combination with phospholipides in particular as selective pre-emergence and post-emergence herbicides for controlling wild grasses such as, for example Alopercurus myosuroides, Apera spicaventi, Poa spp., Avena fatura, and annual weeds in winter wheat, winter barley and rye or weeds in vegetable plantations, orchards and vineyards. 3. Organic phosphorus and arsenic compounds, such as O,O-diisopropyl-S-[2-(phenylsulfonylamino)-ethyl]-dithiophosphate (bensulide), n-(phosphonomethyl)-glycine (glyphosate), salts of ethyl carbamoyl phosphoric acid, the disodium salt of methyl arsenic acid; dimethyl arsinic acid. 4. Alcohols and aldehydes, such as ethyl xanthogene disulfide, alcyl alcohol, acrolein. 5. Substituted alkane carboxylic acids such as, for example, monochloroacetic acid, N,N-diallyl chloroacetamide (allidochlor), 2,3,6-trichlorophenyl acetic acid (chlorfenac), benzamido-oxyacetic acid (benzadox), 4-chloro-2-oxobenzothiazolin-3-yl acetic acid (benazolin), N,N-dimethyl-2,2-diphenyl acetamide (diphenamid ), trichloroacetic acid, ethylene glycol-bis-(trichloroacetate), 2-chloro-3-(4-chlorophenyl)-propionic acid methyl ester (chlorphenprop)-, 2,2-dichloropropionic acid, -naphthyloxy-acetic acid methyl ester, 2- ( l-naphthyloxy)-propionic acid-N,N-dimethylamide (napromid). 6. Aromatic carboxylic acid derivatives corresponding to the following general formula EMI8.1 in which R1 to R5 may be the same or different and represent H, halogen, NH2, methoxy, -COOCH3, -COONH-naphthyl, NO2, at most four groups representing H, A represents -COOR6, -CONR7R8, -CSNR7R8, -COSR6, R6 represents H, alkali, alkaline-earth, alkyl, hydroxy alkyl, R7 represents H, alkyl, R8 represents H, alkyl, hydroxy alkyl, benzyl. The compounds corresponding to general formula 1II- are known compounds and are described for example in the following patents: US-PS No. +,027,248, GB-PS No. 987,253, US-PS No 3,534,098, US-PS No. 3,013,054, US-PS No. 3,081, 162, US-PS No. 2,923,634 and GB-PS No. 671,153. The following are examples of compounds corresponding to formula III: 2,6-di6hlorobenzonitrile (dichlorbenil), 2,6-dichlorobenzoic acid thioamide (chlorthiamid), N-(1,1-dimethylpropinyl)-3,5-dichlorobenzamide (propyzamid), 3-amino-2,5-dichlorobenzoic acid (chloramben), 3,6-dichloro-2-methoxybenzoic acid (dicamba), 2,3,6-trichlorobenzoic acid, dimethyl-2,3,5,6-tetrachloroterephthalate (chlorthal), N-(1-naphthyl)-phthalamidic acid (naptalam). 7. Phenol derivatives corresponding to the following general formula EMI9.1 in which R1 to R5 may be the same or different and represent H, NO2, linear or branched C1-C4-alkyl, halogen, nitrile, trifluoromethyl, at most four groups representing H and R4 represents H, -COCH3, -CSOalkyl, -COCH2-Cl, -COQalkyl, -N=CH-aryl, phenyl optionally substituted by trifluoromethyl, nitro, alkyl, NH2, alkoxy, halogen. The compounds corresponding to general formula IV are known compounds and are described in the following patents: GB-PS No. 1,067,031, US-PS No. 2,192,197, GB-PS No. 1,096,037, DE-PS No. 1,088,757, US-PS No. 3,080,225, US-PS No. 3,652,645, DE-OS No. 14 93 512. The following are examples of compounds corresponding to general formula IV: 3,5-dibromo-4-hydroxybenzonitrile (bromoxynil), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), 6-methyl-2,4-dinitrophenol (DNOC), 2-sec-butyl-4,6-dinitrophenol (dinoseb), 3,5-dibromo-4-hydroxy benzaldehyde-p-(2,4-dinitrophenyl )- oxime (bromofenoxin), 2-sec-butyl-4,6-dinitrophenyl acetate (dinosebactat), 2,4-dichlorophenyl-4'-nitrophenyl ether (nitrofen), 5-( 2, 4-dichlorophenoxy )-2-nitrobenzoic acid methyl ester (bifenox), 2,4'-dinitro-4-trifluoromethyl diphenyl ether (fluorodifen), pentachlorophenol (PCP), 2,4-dinitro-3-methyl-6-tert.-butyl phenol acetate, 2,4-dinitro-6-sec-amyl phenol, 2,4,6-trichloro-4'-nitrodiphenyl ether, 3-methyl-4'-nitrodiphenyl ether, 2,4'-dinitro-4-trifluoromethyl diphenyl ether, 2, 4-dichlorophenyl--31 -methoxy-4' -nitrophenyl ether, but especially 2,4-dinitro-6-methyl phenol which may be used in combination with phospholipides in particular for controlling seed weeds such as, for example, chickweed, goose grass, camomile, knot-grass, speedwell, -dead nettle and corn marigold in cereal crops, corn or vineyards, optionally even in conjunction with a hormone herbicide, or pentachlorophenol or 2,4,6-trichlorophenyl-4'-nitrophenyl ether, particularly for controlling barnyard grass and bullrushes in paddy fields. 8. Anilines corresponding to the following general formula EMI10.1 in which R1 represents H, C1-C3 -alkyl or nitro, R2 represents H, halogen or NH2, R3 represents Cl-C3-alkyl, H, -CF3, -SO2CH3 or -SO2NH2, R4 represents H or C1-C3-alkyl, R5 represents H, NO2 or C1-C3-alkyl, R6 represents H, C1-C3-alkyl, Cl-C4-alkoxy methyl or cyclopropyl methyl and R7 represents linear or branched Cl-C5-alkyl or linear or branched C1-C7-acyl. The compounds corresponding to formula V are known compounds and are described in the following patents: US-PS No. 3,257,190, US-PS No. 3,546,295, US-PS No. 2,863, 752, DE-AS No. 11 66 547, US-PS No. 3,020,142, DE-AS No. 10 39 779, US-PS No. 3,442,945, GB-PS No. 1,164,160, DE-OS No. 22 41 408. The following are examples of compounds corresponding to formula V: N,N-dipropyl-2 , 6-dinitro-4-trifluoromethyl anilide (trifluralin), N-ethyl-N-butyl-2 , 6-dinitro-4-trifluoromethyl aniline (benfluralin), N-cyclopropyl-methyl-N-propyl-2,6-dinitro-4-trifluoromethyl aniline (profluralin), 3-diethylamino-2 , 4-dinitro-6-trifluoromethyl aniline (dinitramine), N-(l-ethylpropyl)-3,4-dimethyl-2,6-dinitroaniline (penoxyn), N,N-dipropyl-4-methylsulfonyl-2, 6-dinitroaniline (nitralin), 4-(dipropylamino)-3, 5-dinitrobenzenesulfonamide (oryzalin), N,N-dipropyl-2,6-dinitro-4-isopropyl aniline (ispropalin), N-isopropyl-a-chloracetanilide (propachlor), a,a-dimethyl valeryl-4-chloroanilide (monalid), N-(3-chloro-4-methylphenyl)-2-methyl valeric acid amide (pentanochlor), propionic acid-3, 4-dichloroanilide (propanil), 2,6-diethyl-N-(methoxymethyl )-2-chloroacetanilide (alachlor), 2, 6-diethyl-N- (butoxymethyl )-2-chloroacetanilide (butachlor), 2-(N-benzoyl-3 ,4-dichloroanilino)-propionic acid ethyl ester, but especially propionic acid-3,4-dichloroanilide (propanil). 9. Carbamates corresponding to the following general formula EMI11.1 in which R1 represents H, halogen, particularly chlorine, CH3 or NHCOOC2H5 and R2 represents H, linear or branched C1-C4-alkyl, halogen alkyl, halogen alkinyl, alkinyl, 3-(methoxycarbamoylfphenyl. The compounds corresponding to formula VI are known compounds and are described for example in the following patents: US-PS No. 3,334,989, DE-AS No. 11 59 432, DE-AS No. 11 88 588, US-PS No. 3,150,179, GB-PS No. 574,995, US-PS No. 2,695,226, DE-OS No. 15 67 151. The following are examples of compounds corresponding to formula VI: isopropyl-N-phenyl carbamate (propham), l-methyl-(ethylcarbamoylmethyl)-N-phenyl carbamate (carbetamid), isopropyl-N-(3-chlorophenyl)-carbamate (chlopropham), 4-chloro-2-butinyl-N- (3-chlorophenyl ) -carbamate (barban), methyl propargyl-N-(3-chlorophenyl)-carbamate (chlorbufam), methyl-N- ( 4-aminobenzene-sulfonyl ) -carbamate (asulam), 2, 6-di-tert-butyl-4-methylphenyl-N-methyl carbamate (terbucars , 3-methoxy carbonylamino-phenyl-N-(3-methylphenyl}-carbamate (phenmedipham), 3-ethoxy carbonylamino-phenyl-N-phenyl carbamate (desmedipham) but especially 'isopropyl-N-phenyl carbamate, 3-methoxy carbonylamino-phenyl-N-(3-methylphenyl)-carbamate or 3-ethoxycarbonylamino-phenyl-N-phenyl carbamate. 10. Triazines corresponding to the following general formula EMI12.1 in which R1 represents halogen, particularly chlorine, methylthio or methoxy, and R2 and R3 represent linear or branched C1-C3-alkyl optionally substituted by a nitrile group or azole group. The compounds corresponding to formula VII are known compounds and are described for example in the following patents: DE-OS No. 15 42 733, CH-PS No. 329, 277, CH-PS No. 337,019, DE-AS No. 16 70 528, DE-AS No. 11 86 070. The following are examples of compounds corresponding to formula VII: 2-azido-4-methylthio-6-isopropylamino-l '3, 3-triazine (aziprotryn), 2,4-bis-Cethylamino)-6-chloro-1,3,5-,triazine (simazin), 2-ethylamino-4-chloro-6-isopropylamino-1 , 3, 5-triazine (atrazine), 2-methylamino-4-methylthio-6-isopropylamino-1,3,5-triazine (desmetryne), 2-(4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino)-2-methylpropiononitrile (cyanzin), 2-ethylamino-4-tert.-butylamino-6-chloro-1,3,5-triazine (terbutylazin), 2-chloro-4,6-bis-(isopropylamino)-1,3,5-triazine (propazin), 2-ethylamino-4-methylthio-6-isopropylamino-1 , 3, 5-triazine (ametryne), 2-ethylamino-4-sec.-butylamino-6-methoxy-1,3,5-triazine (secbumeton), 2-ethylamino-4-tert.-butylamino-6-methoxy-1,3,5-triazine (terbumeton), 2-methoxy-4,6-bis-(isopropylamino)-1,3,5-triazine (prometon), 2-ethylamino-4-tert.-butylamino-6-methylthio-1,3,5-triazine (terbutryne), 2-methylthio-4,6-bis-(isopropylamino)-1,3,5-triazine (prometryn), 2- ( 3-methoxypropylamino ) -4-methylthio-6-isopropylamino- 1,3,5-triazine (methoprotryne), but especially 2-(4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino!- 2-methylpropiononitrile), 11. Triazinones corresponding to the following general formula EMI13.1 in which R1 represents alkyl, substituted aryl or a cycloaliphatic radical, R2 represents NH2, -NH-alkyl or N=CH-alkyl and R3 represent C1-C4-alkyl, alkoxy or alkylthio. The compounds corresponding to formula VIII are known compounds and are described, for example in the following patents: US-PS No. 3,671,523, DE-OS No. 24 07 144 and US-PS No. 3,847,914. The following are examples of compounds corresponding to formula VIII: 4-amino-6-tert.-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin), 6-tert.-butyl-4-isobutylidene-amino-3-methylthio-1,2,4- triazin-5(4H)-one (isomethiozin), but especially 4-amino-3-methyl-6-phenyl-1,2,4-triazin5(4H)-one (metamitron). 12. Other herbicides which may be used include, for example, 3,6-epoxy cyclohexane dicarboxylic acid (endothal), S-ethyl-N,N-diethylthiocarbamate (ethiolat), S-ethyl-N,N-hexane methylene thiocarbamate (moliriat), S-ethyl-N,N-dipropyl thiocarbamate (EPTC), S-ethyl-N-ethyl-N-cyclohexyl thiocarbamate (cyclat), S-ethyl-N,N-diisobutyl thiocarbamate (butylat ), S-propyl-N,N-dipropyl thiocarbamate (vernolat), S-propyl-N-ethyl-N-butyl thiocarbamate (pebulat), 2-chloroallyl-N,N-diethyl dithiocarbamate (sulfallat), S-(2,3,3-trichloroallyl)-N,N-diisopropylthiocarbamat-e (trillat), S-2,3-dichloroallyl)-N,N-diisopropylthiocarbamate (diallat), S-(4-chlorobenzyl)-N,N-diethylthiocarbamate (benthiocarb), 1,3-dimethyl-1-(5-trifluoromethyl-1,3,4-thiodiazol-2-yl)- urea (thiazfluron), l-(5-ethylsulfonyl-l,3,4-thiadiazol-2-yl)-l,3-dimethyl urea (sulfodiazol), 2-oxo-l-imidazolidine carboxylic acid-N-isobutyl amide (isocarbamid), l-(benzothiazolyl)-l,3-dimethyl urea (methabenzthiazuron), 1, l-ethylene-2, 2' -dipyridylium dibromide (diquat), 1,1 1-dimethyl-4,4 '-dipyridylium dichloride (paraquat). The individual herbicides are used either on their own or in combination with other herbicides following the addition of phospholipides. The new herbicidal compositions may be applied by standard methods, for example as soil or leaf herbicides or as systemic herbicides or contact herbicides before or after sowing or after emergence, according to requirements. The new herbicidal compositions are used primarily for controlling weeds and wild grasses such as, for example, Alopeurus myosuroides, Bromus tectorum, Cyperus rotundus, Digitaria sanquinalis, Echinochlora crus galli, Ebeusine indica, Festuca ovina, Lolium perenne, Phleum protense, Setaria italica, Poa annua, Setaria viridis, Sorghum halepense, Abutilon theophrasti, Amaranthus retroflexus, Anthemis arvensis, Chenopodium album, Chrysanthemum segetum, Convolutus arvensis, Agropyron repens, Apera pica-venti, Arrhenaterum elastius bulbosum, Pennisetum clandestinum, Ischaemum rugosum, Rottboellia exaltata, Imperata cylindrica, Poa trivialis, Leptochloa iliformis, Setaria faberii, Galium aparine; ; Cirsium arvense, Atriplex spp., which hinder or are harmful to the cultivation of useful plants in one-crop systems. Examples of useful plants which may be protected against weeds and wild grasses are oats, barley, rice, millet, wheat, corn, sugar beet, cane sugar, potatoes, soya beans, cotton, tobacco, coffee, fruit, vegetables or vines. The new herbicidal compositions may be applied to the soil or to the plants by standard methods in the form of-dusting powders, scattering preparations, granulates or as aqueous preparations in the form of soluble concentrates, emulsifiable concentrates or dispersible concentrates. In most cases, the application of the herbicides requires vehicles or auxiliary substances to enable relatively small quantities of the active ingredient to be uniformly distributed over large areas. In addition to vehicles, it is possible to use diluents, wetting agents, stabilisers, gelating agents, evaporation accelerators, penetrating agents or extenders. Suitable vehicles are, for example, talcum, kaolin, bentonite, silica gel, lime or crushed rock. Further auxiliaries are, for example, surface-active compounds, such as soaps (fatty acid salts), fatty alcohol sulfonates or alkyl sulfonates. Gelatin, casein, albumin, starch or methyl cellulose may be used as stabilisers or protective colloids. To produce the new herbicidal compositions, the corresponding phospholipide is dissolved in a suitable solvent such as, for example, toluene, ethyl acetate, xylene, petrol, methanol or ethanol, or in mixtures of these solvents. The choice of the solvent will depend upon the solubility of the herbicide used. The herbicide or a commerically available herbicidal preparation is then dissolved in the phospholipide solution, optionally by heating. On completion of dissolution, the solvent is distilled off in vacuo while heating. The product thus obtained is then processed into standard marketable formulations, optionally by the addition of suitable inert auxiliaries, such as fillers, swelling agents, emulsifiers, wetting agents, propellents, or - in the production of granulates a disintegrating agent. In the production of granulates, the granulates may optionally be coated with phospholipides. The phospholipide coating has the advantage of better handling properties (improvement in odour, reduction in the aggressiveness of the chemical herbicide). The new herbicidal mixtures may also be prepared by dissolving or suspending the herbicide or a standard commercial herbicidal preparation, the phospholipide and the required auxiliaries together in a solvent or solvent mixture by heating and then distilling off the solvent(s) in vacuo. The mixture obtained in this way is immediately ready for use. In the case of herbidices which are soluble in water 6r water/alcohol mixtures, the herbicide is with advantage first dissolved in water or water/alcohol mixtures, after which the phospholipide or phospholipide mixture is processed to form a solution or emulsion either by stirring or by the application of ultrasonic waves. The emulsifiers required, if any, may be added before or after this stirring operation. The emulsion or solution thus obtained is freed from the solvent mixture or from water in the usual way, for example by distillation, spray drying, freeze drying. The resulting product may be used as a dry product, optionally after the addition of auxiliaries and fillers. The product may also be re-emulsified or redissolved in water to which suitable auxiliaries have been added and used as a liquid product. EXAMPLE 1 Production of 1 litre of an emulsion concentrate (95 g/l) containing MCPA (2-methyl-4-chlorophenoxy acetic acid) as the active ingredient: 95 g of MCPA, 200 g of Phospholipon 55 in 100 ml of ethanol, 8 g of Tween 80, 2 g of Span 80 and 200 ml of ethanol are combined, dissolved while stirring and made up to 1 litre with Shellsol A. The effectiveness against dicotyledonous weeds of 1 kg of this formulation containing 95 g of MCPA/litre is equivalent to that of 1 kg of a standard commercial product containing 19a g/1. EXAMPLE 2 1 kg of a spraying powder (12.5%) containing linuron as its active ingredient is prepared by dissolving 125.0 g of linuron, 125.0 g of PhospholiponR55 in 100 ml of ethanol and 60.0 g of PEG 4000 while heating in 300 ml of ethanol and 100 ml of toluene. The resulting solution is homogeneously kneaded with 670 g of bentonite (colloidal), after which the product is dried, ground and sieved. 1 kg of this 12.5 % spraying powder is as effective against weeds in potato cultivation for example as 0.5 kg of a standard commercial product containing 50% of linuron. EXAMPLE 3 1 kg of a granulate (5%) containing naptalan as its active ingredient is prepared by dissolving 50 g of naptalan, 70 g of PhospholiponR80 in 70 ml of ethanol and 15 g of lignin sulfonate in solution in water in 350 ml of warm DMF and homogeneously kneading the resulting solution with 855 g of "precipitated calcium carbonate". The product is dried and ground and then mixed with 100 ml of a 10% gelatin solution, resulting in the formation of pellets. The quantity of gelatin may vary slightly according to the quality of the calcium carbonate. The pellets are dried in a fluidised bed granulator. 1 kg of this 5% granulate is as effective in controlling weeds in the cultivation of soya beans for example as a standard commercial product containing 10%of naptalan. EXAMPLE 4 1 litre of an emulsion concentrate (50 g/l) containing DNOC (2,4-dinitro-6-methyl phenol) is prepared as follows: 50 g of DNOC, 100 g of PhospholiponR55 in 150 ml of ethanol, 8 g of Tween 80, 2 g of Span 80 and 50 ml of Cellosolve are made up to 1 litre with Shellsol N and dissolved. 0.5 litre of this solution is as effective against broad-leaved weeds in the cultivation of cereals as 1 litre of a standard commercial formulation having the same concentration. EXAMPLE 5 1 litre of an emulsion concentrate (100 g/l) containing pentachlorophenol (PCP) as its active ingredient is prepared as follows: 100 g of PCP, 120 g of Phospholipon Tween 80, 2 g of Span 80, 30 g of Cellosolve and 200 ml of xylene are made up to 1 litre with Shellsol A and dissolved. 0.5 litre of this 10% solution is just as effective against weeds as 1 litre of a standard commercial formulation having the same concentration. EXAMPLE 6 1 litre of an emulsion concentrate (50 g/l) containing 2,4,6-trichlorophenyl-4'-nitrophenyl ether (CNP) as its active ingredient is prepared as follows: 50 g of CNP, 75 g of PhospholiponR55 in 50 ml of ethanol, 10 g of Marlowet IHF and 200 ml of xylene are made up to 1 litre with Shellsol A and dissolved 0.5 kg of this formulation used in the form of an emulsion in water is just as effective against weeds as 1 kg of a standard commercial product having the same concentration. EXAMPLE 7 1 litre of an emulsion spray (258) containing propanil (propionic acid-3,4-dichloroanilide) as its active ingredient is prepared as follows: 250 g of propanil, 250 g of phospholiponR80 in 250 ml of ethanol, 5 g of Tagat D, 5 g of Tegonuls 0 and 30 g of Cellosolve are made up to 1 litre with Shellsol A and dissolved. 0.5 litre of this formulation is just as effective against broad-leaved weeds, for example in the cultivation of potatoes, as 1 kg of a standard commercial product having the same concentration. EXAMPLE 8 1 kg of a spraying powder (14%) containing metamitron as its active ingredient is prepared as follows: 140 g-of metamitron, 160 g of Phospholipon 100 in 80 ml of ethanol, 8 g of Tween 80, 2 g of Span 80, 50 g of Cellosolve, 100 ml of propylene glycol and 1 litre of methanol are dissolved while heating. 400 ml of the resulting solution are kneaded with 650 g of bentonite (colloidal) and the resulting paste dried. This operation is repeated with quantities of 400 ml until the entire solution has been applied to the bentonite. The dry product is ground in the presence of 5 g of Aerosil. 1 kg of this spraying powder (14%) is just as effective against weeds growing in sugar beet as 0.4 kg of a standard commercial product containing 70% of metamitron. EXAMPLE 9 1 kg of a spraying powder (12.5%) containing cyanazin as its active ingredient is prepared as follows: 125g of cyanazin, 150 g of Phospholipon 80. in 50 ml of ethanol, 1 g of DONSS and 24 g of PEG 4000/6000 in solution in ethanol are dissolved in 400 ml of warm chloroform. The resulting solution is homogeneously mixed with 700 g ofbentonite (colloidal) and the resulting paste is dried and ground. 1 kg of this spraying powder (12.5%) is as effective against weeds and wild grass, for example in corn, as 0.5 kg of a standard commercial spraying powder containing 50% of cyanazin. EXAMPLE 10 1 litre of an emulsion concentrate (80 g/l) containing desmedipham as its active ingredient is prepared as follows: 80 g of desmedipham, 80 g of Phospholipon 80 in 80-ml of ethanol, 8 g of Tween 80, 2 g of Span 80, 100 ml of 1,2-propane diol and 100 ml of ethanol are made UF to 1 litre with Shellsol and dissolved. 1 litre of this formulation (concentration 80 g/l) is just as effective against dicotyledonous weeds in sugar beet as 1 litre of a standard commercial product containing 160 g/l of desmedipham. EXAMPLE 11 Production of 1 litre of an emulsion concentrate containing phenmedipham as its active ingredient: 80 g of phenmedipham, 100 g of Phospholipon 55 in 150 ml of ethanol, 2 g of lignin sulfonate, 30 g of Cellosolve and 150 g of propylene glycol are made up to 1 litre with cyclohexanone and dissolved. 1 litre of this formulation (concentration 80 g/l) is just as effective against weeds in sugar beet as 1 litre of a standard commercial product containing 157 g/l of phenmedipham. EXAMPLE 12 Production of 1 litre of an emulsifiable concentrate containing propham as its active ingredient: 250 g of propham, 200 g of Phospholipon 55 in 200 ml of ethanol, 8 g of Tween 80, 2 g of Span 80, 20 g of Cellosolve and 100 ml of ethyl acetate are made up to 1 litre with isopropanol and dissolved. 0.5'litre of t-his formulation, as a pre-emergence herbicide, is just as effective against weeds as 1 kg of a standard commercial product having the same concentration. EXAMPLE 13 -Production of 1 litre of an emulsion concentrate containing mecoprop + 2,4-D as its active ingredient: 50 g of 2,4-D, 200 g of mecoprop, 250 g of Phospholipon 55 in 100 ml of ethanol, 50 g of Cellosolve, 50 g of 1,2propylene glycol, 8 g of Tween 80 and 2 g of Span 2 are mixed together and made up to 1 litre with ethanol. 1 litre of the resulting solution is as effective against dicotyledonous weeds in lawns and sports fields as 1 kg of a standard commercial product containing twice the quantities of 2,4-D and mecoprop. EXAMPLE 14 Production of 400 g of a spraying powder (40%) containing linuron as its active ingredient: 120 g of linuron, 120 g of Phospholipon R55, 1.5 g of Marlowet IHF, 52.5 g of dry glucose and 6.0 g of Bentone EW are homogenised in 1080 g of water using a suitable stirrer and the resulting suspension is spray-dried. 1 kg of this spraying powder (40%) is just as effective against weeds in the cultivation of potatoes as 2.2 kg of a standard commercial product containing 50% of linuron. EXAMPLE 15 Production of 1.15 kg of granulate (22%) containing naptalan as its active ingredient: Ingredients: 600 g of dry glucose, 100 g of Aerosil, 255 g of Phospholipon 38 in 64 g of isopropanol, 265 g of naptalan, 13 g of Marlowet IHF and 13 g of sodium lauryl sulfonate. The dry glucose and aerosil are initially introduced and mixed in a Eweka 2-kneader with a solution of Phospholipon in isopropanol heated to 600C. The naptalan, Marlowet IHF and sodium lauryl sulfonate are added to and homogeneously kneaded with the resulting mixture. The mixture is then granulated in an Alexander granulator (perforated cylinder diameter 2 mm product outlet) and dried for 2 hours at 600C in a recirculating air drying cabinet. Yield: 1.15 kg of granulate. 1 kg of this 22% granulate'is as effective in controlling weeds' in the cultivation of soya beans as 3.5 kg of a standard commercial product containing 10% of naptalan. EXAMPLE 16 Production of 1 litre of an emulsion concentrate (50 girl) containing DNOC (2,4-dinitro-6-methylphenol): 50 g of DNOC, 40 g of Phospholipon - 55, 8 g of Tween 80, 2 g of Span 80, 50 ml of cellulose, 250 ml of xylene, 100 ml of cyclohexanone and 40 g of N-(2-hydroxyethyl)hexanoic acid amide are made up to 1 litre with Shellsol N and dissolved. EXAMPLE 17 Production of 1 litre of an emulsion concentrate (60 g/13 containing 2,4,6-trichlorophenyl-4'-nitrophenyl ether (CNP) as its active ingredient: 60 g of CNP, 20 g of PhospholiponR55, 5 g of Marlowet IHF, 60 ml of isophorone, 200 ml of xylene and 20 g of N-(2-hydroxyethyl)-caproic acid amide are made up to 1 litre with Shellsol A and dissolved. 0.5 kg of this formulation used in the form of an emulsion in water is as effective against weeds as 1 kg of a standard commercial product having the same concentration. EXAMPLE 18 1 kg of an emulsion concentrate containing flampropmethy as its active ingredient is prepared as follows: 160 g of flampropmethyl, 160 g of PhospholiponR 55, 15 g of N-(2-hydroxyethyl)-caproic acid amide, 90 g of Cremophor EL and 170 g of isophorone are mixed and made up to 1 litre with a mixture of xylene and toluene. 0.5 kg of this concentrate diluted with water in the usual way are as effective against oat grass as 1 kg of the standard commercial product. This emulsion concentrate may also be applied by the ULV or LV technique when diluted with the same quantity of water. The resulting mixture is a clear solution whereas the commercial product diluted with the same quantity of water gives an inhomogeneous thick emulsion which cannot be sprayed. EXAMPLE 19 Production of 400 g of spraying powder (40%) containing metamitron as its active ingredient: 160 g of metamitron, 160 g of Phospholipon 38, 2 g of Marlowet IHF, 8 g of Bentone EW and 70 g of dry glucose are homogenised in 1 litre of water by means of a stirrer; for example of the Ultra-Turax type. The suspension thus obtained is spray-dried. The powder ¯obtained is a wettable powder. 1 kg of this spraying powder (40%) is just as effective against weeds in sugar beet as 1 kg of the usual commercial product containing 70% of metamitron. EXAMPLE 20 Production of 400 g of spraying powder (40%) containing cyanazin as its active ingredient: 160 g of cyanazin, 160 g of Phospholipon 38, 2 g of Marlowet IHF, 70 g of dry glucose and 8 g of Bentone EW are stirred into 1220 g of water and homogenised. The resulting mixture is subsequently spray-dried. 0.2 kg of this spraying powder (40%) is as effective against weeds and. wild grass in corn as 0.5 kg of a standard commercial spraying powder containing 50% of cyanazin. 'EXAMPLE 21 Production of 100 g of spraying powder (3%) containing chlorsulforon as its active ingredient: 12 g of chlorsulforon, 228 g of Phospholipon 38, 2.5 g of Marlowet IHF, 51.5 g of dry glucose and 6 g of Bentone EW are homogenised in 1080 g of water by means of a suitable stirrer and the suspension obtained is subsequently spray-dried. This spraying powder (3%) is as effective against weeds as 1 keg of a standard formulation containing 6% of chlorsulforon. EXAMPLE 22 A spraying powder containing chlortoluron is prepared in the same way as in Example 21 using the following ingredients: 12 g of chlortoluron, 228 g of PhospholiponR55, 2.5 g of Marlowet IHF, 51.5 g of dry glucose and 6 g of Bentone EW. EXAMPLE 23 Production of 1 kg of an emulsion concentrate containing 80 g/l of desmedipham and 80 g/l of phenmedipham as its active ingredients: 80 g of desmedipham, 80 g of phenmedipham, 160 g of PhospholiponR80, 230 g of toluene, 170 g of isophorone, 150 g of N-(2-hydroxyethyl)-caproic acid amide, 110 g of Cremophor EL and 20 g of PEG 600 are mixed to form an emulsion concentrate. 1 litre of this formulation having an active ingredient concentration of 160 gYl is just as effective against dicotyledonous weeds in sugar beet as 1.8 litres of a standard commercial product having the same concentration of active ingredients. EXAMPLE 24 Production of 1 kg of a spraying powder (40%) containing simazin as its active ingredient: 400 g of simazin, 400 g of Phospholipon 38, 5 g of Marlowet IHF, 175 g of dry glucose and 20 g of bentone EW are homogenised with 3600 g of water and the resulting mixture is spray-dried. 1 kg of this formulation is just as effective against dicotyledonous weeds in coffee plantations as 1.9 kg of a commercial product having a simazin concentration of 50%. EXAMPLE 25 Production of 1 kg of an emulsifiable concentrate containing Propham as its active ingredient: 170 g of propham, 150 g of Phospholipon 38, 120 g of toluene, 120 g of xylene, 160 g of isophorone, 160 g of N-(2-hydroxyethyl)-heptanoic acid amide, 100 g of PEG 600 and 30 g of monodiglyceride are combined and converted by stirring into a concentrate. 0.6 kg of this formulation as a pre-emergence herbicide is just as effective against weeds as 1 kg of a standard commercial product having the same concentration of propham. EXAMPLE 26 Production of 100 g of an emulsion concentrate containing diclofopmethyl as its active ingredient: 16 g of dichlofopmethyl, 16 g of Phospholipon 38, 16 g of N-(2-hydroxyethyl)-caproic acid amide, 8 g of Cremophor EL, 12 g of toluene and 16 g of cyclohexanone are mixed together. The solution obtained is suitable for application by the ULV or LV technique when diluted with 100 g of water. EXAMPLE 27 Production of 400 g of a spraying powder (45%) containing methabenzthiazuron as its active ingredient: 180 g of methabenzthiazuron, 140 g of Phospholipon 38, 2 g of marlowet IHF, 8 g of Bentone EW and 70 g of dry glucose are made into a suspension by stirring into 1220 g of water using a suitable stirrer, for example of the Ultraturax type. The resulting powder is a spraying powder which when diluted with water gives the required spray mix. 1 1 kg of this spraying powder (45%) is as effective against weeds in a spring wheat field as 1.2 kg of the usual commercial product containing 704 g of methabenzthiazuron. EXAMPLE 28 Production of 400 g of a spraying powder (40%) containing glyphosat as its active ingredient: 160 g of glyphosat, 160 g of Phospholipon 38, 2 g of Marlowet IHF, 8 g of Bentone EW and 70 g of dry glucose are stirred into 1200 g of water and homogenised. The resulting suspension is spray-dried. As a total herbicide, 1 kg of this product in the form of a 40% spraying powder has the same effect as 2 kg ofa standard commercial product containing 48% of glyphosat. In the following Application Examples, the commercial products containing the active ingredient referred to by its generic name were used as the active ingredient. EXAMPLE 29 Comparison test with cyanazin The use of cyanazin for controlling weeds (couch grass, white goosefoot, black bindweed) in corn. The cyanazin was used in its standard commercial form, namely Blanchol referred hereinafter as herbicide C. Test Herbicide (mixture) Weed damage Corn damage No. in % in % 1 herbicide C 4.0 kg/ha 95 25 2 herbicide C 4.0 kg/ha 95 90 + rustica oil 5.0 kg/ha 3 herbicide C 4.0 kg/ha 95 5 + phospholipide 4.0 kg/ha Test Herbicide(mixture) Weed damage Corn damage No. in % in % 4 herbicide C 2.0 kg/ha 70 90 + rustica oil 5.0 kg/ha 5 herbicide C 2.0 kg/ha 95 5 + phospholipide 4.0 kgZha 6 herbicide C 4.0 kg/ha 95 5 + phospholipide 2.0 kg/ha 7 herbicide C 2.0 kg/ha 85 5 + phospholipide 2.0 kg/ha EXAMPLE 30 Comparison tests with isoproturon For controlling foxtail grass, winter wheat fields are treated with various mixtures and the percentage weed destruction is measured. Test Mixture % destruction of No. foxtail grass 1 isoproturon (75%) 2 kg/ha .100% 2 isoproturon (75%) 1 kg/ha 0% 3 phospholipide 6 kg/ha 0% 4 isoproturon (75%) 1.5kg/ha 100% + phospholipide 6 kg/ha 5 isoproturon (75) 1 kg/ha 100% + phospholipide 6 kg/ha EXAMPLE 31 Comparison test with metamitron The use of metamitron for weed control in sugar beet after emergence Test Mixture Weed damage in % No. 1 metamitron (70%) 2.5 kg/ha 20% only moderate activity, weeds slightly damaged Test Mixture Weed damage in % No. 2 metamitron (70%) 5.0 kg/ha 90% weeds damaged apart from goose grass 3 metamitron (70%) 2.5 kg/ha 90% + phospholipide 2.5 kg/ha weeds damaged apart from goose grass 4 metamitron (70%) 2.5 kg/ha 92% + phospholipide 5.0 kg/ha 5 metamitron (70%) 5.0 kg/ha 90% + phospholipide 2.5 kg/ha 6 metamitron (70%) 5.0 kg/ha 96% + phospholipide 5.0 kg/ha all weeds damaged, including goose grass 7 phospholipide 5.0 kg/ha 0% no visible damage

Claims: CLAIMS 1. ' A herbicidal composition, characterised in that it consists of a) one or more herbicidally active substances and b) one or more phospholipides from the group comprising phosphatidyl choline, hydrogenated phosphatidyl cholines, phosphatidyl ethanolamine, N-acyl phosphatidyl ethanol amines, phosphatidyl inositol, phosphatidyl serine, lysolecithin and phosphatidyl glycerol in a ratio by weight of a:b of from 1:0.2 to 1:20 in addition to standard vehicles, diluents, solvents, propellents and/or other inert auxiliaries. 2. A herbicidal composition as claimed in Claim 1, characterised in that constituents a) and b) are present in a ratio by weight of from 1:0.5 to 1:10. 3. A herbicidal composition as claimed in Claim 1 or 2, characterised in that constituents a) and b) are present in a ratio by weight of from 1:1 to 1:5. 4. A herbicidal composition as claimed in one or more of Claims 1 to 3, characterised in that phosphatidyl choline is used as the phospholipide. 5. A herbicidal composition as claimed in one or more of Claims 1 to 4, characterised in that one or more compounds from the following groups is used as the herbicidally active substance: 1. phenoxy carboxylic acid derivatives corresponding to the following general formula EMI30.1 in which a) R1, R2 and R3 represent H, CH3 or halogen with the proviso that at most 2 radicals represent H, R4 represents H or CH3, n = 0-2, Y represents 0 or S X represents O, NH or S and R5 - where X = 0 - represents H, linear or branched C1-C12 - alkyl, hydroxy alkyl, an alkali or alkaline-earth cation or an ammonium cation of an organic amine or R5 - where X = NH - represents H, -NR2, phenyl optionally substituted by 1 to 3 halogen atoms or a heterocyclic group, or b) R1 and R3 represent H, R2 represents EMI31.1 R4 and R5 have the same meaning as in a) and R6 represents CH3, halogen or trifluoromethyl and n = 1 - 3; 2. urea derivatives corresponding to the following general formula EMI31.2 in which R1 and R2, which may be the same or different, represent H, linear or branched C1-C4-alkyl, cycloalkyl, halogen, trifluoromethyl, nitro, alkoxy, optionally halogensubstituted phenoxy, at most one of the groups R1 and R2 representing H, R3 represents H, CH3 or C 2H5 and R4 represents H, cycloalkyl, Cl-C4-alkyl or methoxy; 3. herbicidally active organic phosphorus or arsenic compounds; 4. herbicidally active alcohols or aldehydes; 5. herbicidally active substituted alkane carboxylic acids; 6, aromatic carboxylic acid derivatives corresponding to the following general formula EMI32.1 in which R1 to R5, which may be the same or different7 represent H, halogen, NH2, methoxy, -COOCH37 -COONH-, naphthyl or -NO2, at most four of the groups R1 to R5 representing H, A represents - COOR67 -CONR7R8, -CSNR7R8 or -COSR6 where R6 represents H, alkali, alkaline-earth., alkyl or hydroxy alkyl, R7 represents H or alkyl and R8 represents H, alkyl, hydroxy alkyl or benzyl; 7. phenol derivatives corresponding to the following general formula EMI32.2 in which R1 to R5, which may be the same or different, represent H, NO2, linear or branched C1-C4 -alkyl, halogen, nitrile or trifluoromethyl, at most four of the groups R1 to R5 representing H, and R4 represents H, -COCH3, -CSO-alkyl, -COCH2Cl, -COO-alkyl, -N=CH-aryl or phenyl optionally substituted by trifluoromethyl, nitro, alkyl, NR2, alkoxy and/or halogen; 8. anilines corresponding to the following general formula EMI33.1 in which R1 represents H, C1-C3-alkyl or nitro, R2 represents H, halogen or NH2, R3 represents C1-C3-alkyl, H, CCF3, -SO2CH3 or -SO2NH2, R4 represents H or C1-C3-alkyl, R5 represents H, NO2 or C1-C3-alkyl, R6 represents H, C1-C3-alkyl, Cl-C4-alkoxy methyl or cyclopropyl methyl and R7 represents linear or branched C1-C 5-alkyl or linear or branched C1-C5-acyl; ; 9. carbamates corresponding to the following general formula EMI33.2 in which R1 represents H, halogen, CH3 or -NHCOOC 2H5 and R2 represents H, linear or branched C1-C4-alkyl, halogen alkyl, halogen alkinyl or 3-(methoxycarbamoyl)-phenyl; 10. triazines corresponding to the following general formula EMI34.1 in which R1 represents halogen, methylthio or methoxy and -R2 and R3, which may be the same or different, represent linear or branched C1-C3-alkyl optionally substituted by a nitrile group or azole group; 11. triazinones corresponding to the following general formula EMI34.2 in which R1 represents an alkyl group, a substituted aryl group or a cycloaliphatic radical, R2 represents NH, -NH-alkyl or -N=CH-alkyl and R3 represents C1-C4-alkyl, alkoxy or alkylthio; 12. other herbicides such as, for example, 3,6- epoxy cyclohexane dicarboxylic acid, S-ethyl-N,N methyl thiocarbamate, S-ethyl-N,N-hexane methylene thiocarbamate, S-ethyl-N,N-dipropyl thiocarbamate, S-ethyl N-ethyl-N-cyclohexyl thiocarbamate, S-ethyl-N,N-diisobutyl thiocarbamate, S-propYl-NN-dipropyl thiocarbamate, S-propyl N-ethyl-N-butyl thiocarbamate, 2-chloroallyl-N,N-diethyl dithiocarbamate, S-(2,3,3-trichloroallyl)-N,-diisopropyl thiocarbamate, S-(2,3-dichloroallyl)-N,N-diisopropyl thio carbamate, S- ( 4-chlorobenzyl )-N,N-diethyl thiocarbamate, 1,3-dimethyl-1-(5-trifluoromethyl-1,3,4-thiadiazol-1-yl)- urea, l-(5-ethylsulfonyl-l,3,4-thiadiazol-2-yl)-l,3-dimethyl urea, 2-oxo-l-imidazolidine carboxylic acid-N-isobutyl amide, l-(benzothiazolyl)-l,3-dimethyl urea, 1,1-ethylene-2,2'- dipyridylium dibromide, l,l'-dimethyl-4,4'-dipyridylium dichloride. 6. Herbicidal compositions as claimed in one or more of Claims 1 to 5, characterised in that one or more compounds from the group comprising the following compounds is used as the herbicidally active substance: 2,4-dichlorophenoxy acetic acid or a salt or ester thereof, 2,4,5-trichlorophenoxy acetic acid or a salt or ester thereof, 3- (4-isopropyl-phenyl ) -1, 1-dimethyl urea, 3- (3, 4-dichlorophenyl )-l-methoxy-l-methyl urea, 2,4-dinitro-6-methylphenol, pentachlorophenol, 2,4, 6-trichlorophenyl-4 '-nitrophenyl ether, propionic acid-3, 4-dichloroanilide, isopropyl-N-phenyl carbamate, 3-methoxy carbonylaminophenyl-N- ( 3-methylphenyl ) -carbamate, 3-ethoxy carbonylaminophenyl-N-phenyl carbamate, 2-(4-ethylamino-6-chloro-1,3,5-triazin-2-ylamino)-2-methyl propiononitrile, 4-amino-3-methyl-6-phenyl-1 ,2,4-triazin-5(4H)-one. 7. The use of the compositions claimed in one or more of Claims 1 to 6 for controlling weeds and wild grasses. 8. A process for producing the herbicidal compositions claimed in one or more of Claims 1 to 6, characterised in that the phospholipide is dissolved in an organic solvent or solvent mixture and the herbicide is dissolved in the resulting solution, optionally by heating and/or stirring, after which the solvent or solvent mixture is removed in vacuo and the mixture obtained is converted into a standard formulation by the addition of standard fillers and auxiliaries. 9. A process for producing the herbicidal compositions claimed in one or more of Claims 1 to 6, characterised in that the herbicidets) is dissolved or suspended in an organic solvent with one or more phospholipides and optionally together with standard fillers and auxiliaries, after which the solvent is removed. 10. A process for producing the herbicidal compositions claimed in one or more of Claims 1 to 6, characterised in that one or more water-soluble or alcohol-soluble herbicides is/are dissolved in water or water/alcohol mixtures together with one or more phospholipides by stirring and/or gentle heating and/or by the application of ultrasonic waves, after which the solvents is/are removed.

Inventors: ETSCHENBERG, EUGEN, DR., GHYCZY, MIKLOS, DIPL.-CHEM., DR., OSTHOFF, HEINRICH, DR.
Applicants: A. NATTERMANN & CIE. GMBH
Application year: 1982
Main classification: A01N57
IPC codes: A01N39, A01N57