LIVESTOCK FEED OF HIGH NUTRIENT VALUE, AND THE PROCESS AND APPARATUS FOR ITS PRODUCTION FROM WASTE VEGETABLE MATERIALS

Abstract: A feed of high energy content and rich in proteins, fatty acids and carbohydrates is prepared for livestock use by treating waste materials consisting essentially of cellulose, hemiceliulose and lignin, with a complex solution which induces a natural selection of the microbic flora normally present in the straw, and thus triggers guided and controlled fermentation processes. The production of the new livestock feed has required the provision of a new apparatus in which the section used for mixing the cellulose materials with the fermentation solution in constant predetermined proportions is original.

Description: LIVESTOCK FEED OF HIGH NUTRIENT VALUE, AND THE PROCESS AND APPARATUS FOR ITS PRODUCTION FROM WASTE VEGETABLE MATERIALS This invention relates to a new livestock feed of high nutrient value1 and the process and apparatus for its production from waste vegetable materials. More precisely, the invention relates to a new livestock feed obtained from straw, maize stalks and other vegetable products of high cellulose and lignin content which are unusable or usable only to a small extent in livestock feeding, by means of a new guided and controlled physical-chemical-biochemical process which induces fermentation which is initially microaerobic and then takes place under strictly anaerobiosis conditions, these latter being ensured by the blanket of CO2 which forms above the mass as the fermentation gets underway. The new process induces and causes maximum activation of the prevalently cellulolytic endogenous flora, this flora being perfectly compatible with ruminant animal flora and therefore able to subsequently act as a booster therefor. In addition, the new process leads to natural enrichment in substances which are highly useful for animals, at the expense of fibrous materials of low natural digestibility. The invention also relates to a new apparatus specifically suitable for production of the new feed. Cattle fodder is known to be generally derived from specific crops, of which the entire above-ground part of the plants and in certain cases also their below-ground part are administered to the animals in the fresh or preserved state. Because of the continuous development of livestock breeding, those areas intended for fodder crops are highly inadequate and difficult to cultivate to a level which satisfies the increasing need. There are also a great many crops intended for human feeding, such as whest, maize, barley and the like, which after harvesting the useful part leave large masses of vegetable residue which in practice cannot be used under high conversion conditions for livestock feeding and/or which are partly disposed of by burning. On this basis, it is easy to imagine the great interest in a process which enables livestock feeding requirements to be satisfied, without using new areas to be subtracted from human feeding. Reference will be made hereinafter for simplicity to the processing of straw, but this term is intended to also include vegetable residues deriving from cereals, any other fibrous material of vegetable origin either alone or in mixture, maize stalks and the like. The process according to the present invention comprises the following essential stages: 1 - Preparing the straw into pieces having a length not exceeding 7 mm. This mechanical treatment enables the cellulose and lignin macromolecules to be split, so facilitating their successive chemical attack. In addition it leads to a large degree of rupture of the cell wall, with consequent release of the endocellular content. The endocellular content represents the initial medium for triggering the fermentation. 2 - Impregnating the finely ground straw with a solution having the following composition for 100 kg of processed straw: a) water 200 - 300 litres b) KMnO4 0.25 - 0.35 g c) FeSO4.7E20 40 - 60 g d) CuS04.5H20 8 - 12 g e) dicalcium phosphate 250 - 500 g f) molasses 1 - 5 kg g) urea 1.5 - 3.5 kg The overall purpose of said solution is to trigger and feed a straw fermentation process, which induces natural selection of the microbic flora normally present in said straw, mainly favouring the cellulolytic fraction and all those fermentation processes which lead to nutrient products such as proteins, amino acids, carbohydrates, fatty acids and the like. Each of the components of the aforesaid solution has a specific function in the process. Specifically, it has been found that the inorganic salts (b), (c), (d) intervene in the selection of the microbic flora to catalyse and regulate the fermentation processes which it is desired to induce and facilitate. A deficiency or excess of one or more of the said mineral salts makes the progress of the fermentation uncontrollable, in that it favours microorganism strains which are different from those useful for the purposes of the invention. If the process according to the present invention is proceeding normally, then the temperature curve of the processed mass should be bell-shaped up to 55 - 65 C. When the temperature of the mass again falls to about 40 C, the process is to be considered terminated. The purpose of the water is to soak and swell the pectins, and weaken the physical cellulose, hemicellulose and lignin bonds, so facilitating their subsequent lysis. In addition, the water makes available in the biomass the cellular content which emerges from the cells broken down by the mechanical straw trituration treatment, which is indispensable to the selective microflora process. The urea (g) releases ammonia, which has a double purpose: initially, its action is chemical in splitting the ligninhemicellulolytic bonds; later, it supplies the nitrogen necessary for the development of the cellulolytic microflora and the fermentation processes, with the formation of nitrogenated compounds which are highly useful for livestock feeding. The purpose of the molasses (f) is to supply immediately available energy which is necessary for triggering the fermentation. The fermentation is subsequently sustained by the sugars which originate from the cellulose and hemicellulose lysis. The purpose of the dicalcium phosphate is to buffer the solution against the ammonia, and represents a feed supplement which remains as such in the final fodder mass. 3 - Fermentation In general, the product can be used between the 10th and 25th day of fermentation, but preferably after 12-20 days. The table (Table 1) given hereinafter shows the most significant components of the product expressed as a perccntage by weight of dry substance on the 12th and 20th day from the beginning of the fermentation process. The final product normally contains 70-75% of moisture. In reality, the product can be used after only 48 hours of fermentation if warm Water at 500C is used, if the urea is used in its minimum quantity, and if the phosphates are used in their maximum quantity. From the given data it is apparent that a cellulose mass which up to the present time could hardly be used as an animal feed has been converted into a mass of high nutrient value by means of a "guided" fermentation process using induced selection of the microbic flora normally present in the processed cellulose mass. TABLE 1 Mean values referred to the dry substance 12 days 20 days Total nitrogenated substances % 7 - 11 7 - 11 Lipids % 0.4 - 0.9 0.6 - 1 Fibre % 33 - 39 30 - 36 Ash % 5 - 10 5 - 10 Extractable non-nitrogenated % 54.6 - 39.1 57.4 - 42.0 Metabolisable energy Kcal 2300 2300 Other characteristic values x s. c.v. x s. c.v. Acetin acid % 4.50 0.2973 6.60 4.72 0.6502 13.77 Butyric acid % 0.75 0.2124 28.00 1.12 0.0400 92.82 Propionic acid % 0.35 0.1003 28.65 0.49 0.2831 57.70 Volatile fatty acids % 5.60 - - 6.33 - Lactic acid % 0.80 0.4975 62.18 0.52 0.4753 91.40 Total fatty acids % 6.40 - - 6.85 - pH 7.0 0.8081 11.45 7.41 0.6852 9.24 x = mean s. = standard deviation c.v. = variation coefficient A particularly interesting aspect of the present invention is the possibility of using spent sugarbeet pulp, distillery wash, rotted apples and grape skins, with their entire moisture content as a partial or total replacement for the processed water. This alternative of the new process goes some way to solving the large problems inherent in spent sugarbeet pulp, by avoiding the high energy consumption required to dry it, and the heavy investment required by purification plants. The use of spent sugarbeet pulp and the like in place of water means that the mixing must obviously be carried out by suitable apparatus. As initially stated, a second subject matter of the present invention is the apparatus for producing the new fodder mass. The overall structure of this apparatus, its component parts and its operation will be more apparent with reference to the accompanying drawings. In the various drawings, the same parts are indicated by the same reference numerals. Figure 1 is a plan view of the apparatus. Figure 2 is a side view in the direction A. Figure 3 is a side view in the direction B. The figures show diagrammatically the following parts: (1) a pneumatic or mechanical variable speed feeder; (2) a knife shredder or equivalent; (3) a breaking and grinding mill with mechanical or pneumatic conveying systems; the mill is also provided with a fan for raising the ground straw to subsequent apparatus, including silos; (4) a decantation cyclone for the ground product; (5) a container for the ground product, comprising internally a breakdown wheel or equivalent system; (6) rotary or equivalent level indicators; (7) a metering extractor for the straw, of screw type or an equivalent mechanical or pneumatic system; (8) a fluidising rotary valve or equivalent; (9) an electric motor-driven fan for mixing the product and conveying it to the subsequent apparatus; ; (10) a turboatomiser or equivalent mechanical system for distributing liquids and ground straw; (11) a fermentation silo; (12) a control panel; (13) a liquid microdispenser; (14) a liquid dispenser; (15) a liquid pump; (16) a continuous mixer; (17) a flow meter. The apparatus enables any fibrous material of vegetable origin to be processed and subsequently fermented. Again, reference will be made for simplicity only to the processing of straw, but this term is intended to include any waste vegetable material. The following operations are carried out in practice: a) the straw is loaded into the variable speed feeder (1). The feed speed is adjusted either manually or automatically, according to the rate at which the processed mass is loaded into the silo. b) The straw undergoes a first physical change in the shredder (2) and mill (3), where it is reduced to a mass of fragments having a length of between 0.1 and 7 mm. c) The ground straw is fed to storage. The mass is conveyed from the mill into the decanting cyclone (4), from which it passes by gravity into the collection buffer tank (5) in which the quantity of straw present is controlled by the level indicators (6), preferably of rotary type, which when the tank is too full transmit a signal to the mill to temporarily halt it, and when the tank is too empty transmit a signal to the metering extractor unit (7), in order to halt it temporarily. d) The ground straw is metered by means of the extractor (7) and conveyed by an electric motor-driven fan (9), which is fitted with a straw inlet valve (8), so as to allow automatic control of the ratio of weight of cellulose material to the air volume, and thus to allow the formation of a homogeneous constant stream of conveyed material. An aqueous solution of KiTh04 and an aqueous solution of CUS04 FeSO4, molasses and urea are prepared separately, and a water supply is made available. The KMnO4 solution is fed by the microdispenser (13), the solution of the remaining components is fed by the dispenser (14), and the water is fed by the pump (15), all suitably controlled so that in the continuous mixer (16) a homogeneous solution forms in which the components are present within the previously fixed limits. The solution according to the invention is pumped from the mixer (16), through the flow meter (17) and to the turboatomiser (10), by means of the pumping assembly (13), (14), (15). e) The straw is mixed with the solution. The continuous stream of ground straw reaches the turboatomiser (10) simultaneously with the treatment solution. The turboatomiser (10) also comprises a rotating cap which facilitates the uniform mixing of the solid with the liquid in the required proportions. This system also ensures that the impregnated mass is uniformly distributed and collected in the underlying silo. f) The mass contained in the silo is fermented. The progress of the fermentation in the silo can be followed either by temperature probes which measure the temperature inside the mass at various times and thus enable the temperature time curve to be determined, or by withdrawing samples of the fermenting mass at determined times and measuring the significant parameters of Table 1. When fermentation has finished, the temperature of the product is about 400C, It has also been found that if the head requirements allow it, the apparatus elements C4), (5), (6), (7), (8), (9) are no longer essential to ensure the conveying of the grouni straw mass to the silo (11), and instead said mass can be fed into the silo through the turboatomiser (10) directly by means of the fan present in the mill (3). The premixed treatment solution reaches the turboatomiser (10) as already stated. In a further simplification of the process, in particular for batch operation, the continuous mixer (16) can be dispensed with, and the individual solutions fed directly to the turboatomiser (10). A practical example is described hereinafter in order to make the process according to the present invention more easily reproducible, but without limiting the scope of its application in any way. iiZE E Having switched on the various controls of the electrical panel (12), the machine is put into the automatic operating mode. The bales of straw are loaded onto the feeder (1) and fed into the mill (3) by way of the shredder (2). When the level indicator (6) feeds an input signal to the electrical panel, this has the effect of starting the extraction mechanism (7) the fluidising rotary valve (8), the electric motor-driven conveying fan (9), and the pump assembly (13), (14), (15), which for every 100 kg of straw feeds 230 kg of water containing 3.15 kg of molasses, 2.60 kg of urea, 0.05 kg of FeSO4, 0.01 kg of CuSO4, 0.270 kg of dicalcium phosphate and 0.003 kg of KMnO4 to the turboatomiser (10) by way of the continuous mixer (16). The turboatomiser (10) provides for uniformly distributing the mixture (ground straw-fermentation solution), which is left to ferment for thirteen days. After this time, a sample is withdrawn, and on analysis gives the following results, expressed with reference to the dry substance: - total nitrogenated substances 7.6% - lipide 0.5% - fibre 38.4% - ash 8.2% - extractable non-nitrogenated 45.3% - acetic acid 4.10% - butyric acid 0.66% - propionic acid total fatty acids 5.31 ph 6.9

Claims: PATENT CLAIMS 1. A livestock feed of high nutrient value containing absorbable nitrogenated substances, C2-C4 aliphatic acids, lactic acid, lipids and absorbable carbohydrates, which is prepared by fermenting waste vegetable materials of high cellulose and lignin content, by means of the guided and controlled activation of the endogenous cellulolytic microbic flora 2. A process for producing a livestock feed of high nutrient value from waste vegetable materials of high cellulose and lignin content, characterised in that: a) the vegetable material is ground into pieces having a length not exceeding 7 mm; b) the ground material is impregnated with a solution having the following composition per 100 kg of treated material: water 200 - 300 litres EMnO4 0.25 - 0.35 g FeSO4. 7H20 40 - 60 g CuS04.5H20 8 - 12 g dicalcium phosphate 250 - 500 g molasses 1 - 5 kg urea 1.5 - 3.5 kg c) the mass is left to ferment for 2-25 days, preferably for 12-20 days. 3. A process as claimed in claim 2, wherein the fermentation can be considered satisfactory for using the product on livestock after two days, if water is used at 50 C, urea is used in the minimum stated quantity, and phosphates are used in the maximum stated quantity. 4. An apparatus for producing a livestock feed of high nutrient value from waste vegetable materials, characterised by comprising essentially a feeder (1) for the vegetable material, a shredder (2) for this latter, a mill (3) provided with a fan for raising the material, a turboatomiser (10) for uniformly impregnating the vegetable material with the fermentation solution, a pump-dispenser unit (13), (14), (15) for the solution, and a silo (11) for the fermentation. 5. An apparatus as claimed in claim 4, wherein if the head requirements are such as to impose it, the following components are also present: a cyclone (4) for decanting the ground material, a container (5) for the ground material, level indicators (6), a metering extractor for the vegetable material (7), a rotary valve (8), and an electric motor-driven fan (9).

Inventors: DRAGO, DOMENICO, ROSSI, CARLO
Applicants: ALFA STRAW INTERNATIONAL S.R.L.
Application year: 1982
Main classification: A23K1
IPC codes: C12N1, A23K1