EXTRUSION LAMINATED PRODUCT

Abstract: An extrusion laminated product is described compris­ ing at least three layers, wherein at least one of the surface layers comprises polyvinilidene fluoride, and an adhesive layer which is provided between the surface layer and other thermoplastic resin layers comprises a polymer comprising at least one of methyl methacrylate and ethyl methacrylate as a major component or a composition containing said polymer as a main component and from 0.3 to 30 phr of an ultraviolet absorber.

Description: EXTRUSION LAMINATED PRODUCT The present invention relates to an intrusion laminated product having at least three thermoplastic resin layers. Polyvinylidene fluoride (hereinafter referred to as "PVDF" for brevity) is a resin having excellent weathering resistance and chemical resistance. However, PVDF has disadvantages, such as that (1) the production cost is very high since it is a fluorine-type resin; and (2) immediately after extrusion from an extruder crystal lization readily occurs due to its high crystallizability, resulting in formation of spherulites, and therefore PVDF sheets not orientated by stretching have poor transparency. In order to utilize the excellent properties of PVDF, it has been proposed to laminate a film of PVDF on other transparent commercially available resins. There are various methods of producing such laminated products. Of such methods, the simplest method is a method comprising coextruding the resins to provide a laminated product, and this method permits one-step production of laminated products. Such coextrusion to produce laminated films, for example, including a PVDF film is known as described, for example, in U.S. Patent 3,647,612, and PVDF can be laminated on, for example, polymethyl methacrylate (P} or polyvinyl chloride (PVC) by coextrusion. It is described, for example, in U.S. Patent 3,253,060, that PVDF and PMMA have particularly high compatibility with each other and can be uniformly mixed. In addition, it is described in British Patent 1,049,088 that other acrylic ester-type resins having structures similar to that of PMMA are compatible with PVDF. Therefore, the interface between the PVDF and acrylic ester-type resins is well bonded, and in laminating a PVDF layer on other resin layers, it is preferred to interpose therebetween an acrylic acid-type resin as an intermediate layer. An attempt has been made to produce sheets having good transparency by coextrusion and lamination of PVDF and other transparent thermoplastic resins using an acrylic ester-type resin layer comprising ethyl methacrylate-or methyl methacrylate as a main structural monomer as an intermediate layer. In this case, it is important to minimize formation of spherulites formed in the PVDF layer so as not to deteriorate the transparency. It is known that formation of spherulites is typically observed when molten resins are solidified at the temper ature near the crystallization temperature thereof. In order to-prevent such solidification at a temperature near the crystallization temperature, therefore, it is preferred that resins extruded from an extruder are rapidly cooled to temperatures much lower than the crystallization temperature. Thus, laminated products obtained by coextrusion are rapidly cooled from the surface side of PVDF where spherulites are most readily formed. However, when fluid-like resins extruded from an extruder are taken off, for example, through the surface of a cooling roll, vibration of fluid-like resins inevitably occurs, at least to some extent. Therefore, if the cooling roll is maintained at low temperatures such that solidification occurs just when the resin comes into contact with the cooling roll, the taken off sheet lacks flatness. Thus, the solidification time is preferably set so that the resin is cooled after it comes into close contact with the cooling roll. For this purpose, in the case of PVDF, the cooling roll is usually maintained at temperatures ranging from 60"C to 125"C. However, since the cooling temperature at taking off of the PVDF layer is limited, the formation of spherulites in the PVDF layer to a certain extent inevitably occurs. Furthermore, as the thickness of the PVDF layer increases, the cooling rate of PVDF in the interior of the layer reduces,resulting in the formation of large sized spherulites. Transparency is markedly reduced by the combination of an increase of thickness and the formation of large sized spherulites. Therefore, in producing transparent laminated products having a PVDF layer as a surface layer, it is preferred to reduce the thickness of the PVDF layer as much as is practically possible. It is also known that in laminating a sheet having good weathering properties made of PVDF, polyvinyl fluoride CPVF) or the like, on a sheet having poor weathering properties, ultraviolet absorbers (hereinafter referred to as "UVA" for brevity) can be incorporated into the sheet of PVDF, PVF or the like to protect the underlying sheet having poor weathering properties from deterioration by ultraviolet rays. In the case of laminated sheets having a PVDF surface layer, it is considered to prevent the deterioration of underlying substrate sheets due to ultraviolet rays by incorporating UVA into the PVDF surface layer. However, the amount of UVA which can be uniformly mixed with PVDF is limited. For example, if the UVA is added in a large amount, phase separation occurs, deteriorating the transparency, and the UVA which bleeds to the surface of the PVDF surface layer may flow away by rainwater or evaporate. In the case of using the WA in an amount so as not to cause phase separation, it has been confirmed that if the thickness of the PVDF surface 'layer is greatly reduced to obtain a transparent laminated product as described above, the amount of the UVA contained in the PVDF layer is very small and as a result it becomes difficult to prevent the underlying resin layer from the deterioration by ultraviolett rays. The object of the invention is to provide a laminated product having a polyvinylidene fluoride film as at least one surface layer, which can maintain a good surface state even after being exposed to atmospheric conditions for a long period of time and at the same time, is at least substantially free from deterioration by ultraviolet rays. According to the invention, there is provided an extrusion laminated product comprising at least three thermoplastic resin layers, characterized in that at least one surface layer of the product comprises polyvinylidene fluoride, and in that an adhesive layer which is provided between the or each surface layer and the remainder of the thermoplastic resin layers comprises a polymer having either at least one of methyl methacrylate and ethyl methacrylate as a major component or a composition containing said polymer as a major component and from 0.3 to 30 phr of an ultraviolet absorber. Preferably, the or each surface layer comprising polyvinylidene fluoride additionally contains an ultraviolett absorber in an amount up to 3 phr. Preferably, the or each adhesive layer contains from 1 to 15 phr of an ultraviolet absorber. Only a limited number of polymers, such as polymethyl methacrylate and polyethyl methacrylate are now known to have compatibility with polyvinylidene fluoride, and it has previously been believed that the adhesion properties of the adhesive layer is deteriorated by the addition of a large amount of the WA thereinto. Surprisingly, the addition of the UVA to the adhesive layer does not deteriorate the adhesion properties thereof and does not cause the formation of bubbles during molding. Further, it has previously believed that ultraviolet rays would reach the interface between the PVDF layer and the adhesive layer, causing light deterioration around the interface of the adhesive layer, but it has now been confirmed that the extrusion laminated product has practically sufficient weathering resistance. For a better understanding of the invention and to show how the same may be carried into effect, reference will now be made, by way of example only, to a number of detailed examples of the invention in connection with the single Figure of the drawing which is a graph showing the relation between the thickness of a PVDV layer and the degree of transparency or haze. At least one surface layer of the laminated product according to the invention comprises a polyvinylidene fluoride resin. The polyvinylidene fluoride which can be used in the invention includes a vinylidene fluoride homopolymer, a copolymer comprising at least 70 mol of vinylidene fluoride and one or more comonomers copolymerizable therewith, such as tetrafluoroethylene, hexafluoropropylene, trifluoroethylene, ethylene trifluorochloroethylene or vinyl fluoride, and 2 composition comprising at least one of the above-described homopolymer and copolymer and one or more polymer having compatibility therewith. The polyvinylidene fluoride layer may contain an ultraviolet absorber ÙVA), a nucleus-forming agent, a plasticizer, and so forth, if desired. In particular, the addition of the FrA in an amount of from 0.1 to 3 phr in the PVDF layer is preferred from the standpoint of improving the weathering resistance, since the formation of stripe-like bubbles does not occur as long as the amount of the UVA is small. The upper limit for the thickness of the PVDF layer is nqt particularly limited. However, it can be seen from the Figure that when the thickness of the PVDF layer is in the range of 5 p or less, if the thickness slightly decreases, the hae (H, t) greatly decreases and also the degree of transparency is greatly improved. Therefore, considered only from the standpoint of transparency, the thickness is preferably 5 p or less. The most preferred thickness is 3 p or less. The lower limit for the thickness of the PVDF layer is also not particularly limited. However, when the thickness of the PVDF layer is less than 0.5 , it is too thin and the surface layer is easily worn out by slight friction. Furthermore, due to the thin surface layer the amount of the UVA which can be incorporated into the PVDF layer becomes very small, resulting in deterioration of the absorption effect of ultraviolet rays. In general, therefore, the thickness of the PVDF layer is preferably at least 0.5 p. An adhesive layer which c-an be used in the invention to bond the polyvinylidene fluoride outer layer and another thermoplastic resin layer is composed of a polymer comprising at least one of ethyl methacrylate and methyl methacrylate as a main structural monomer or a composition containing such a polymer as a major component Ce.g., at least about 50 wt%). Examples of the polymer for the adhesive layer are a methyl methacrylate homopolyme-r (hereinafter referred to as "PMMA" for brevity), an ethyl methacrylate homopolymer, a copolymer comprising at least 50 molt of at least one of methyl methacrylate and ethyl methacrylate and a monomer, e.g., alkyl methacrylate Cother than methyl methacrylate and ethyl methacrylate?; an alkyl acrylate such as methyl acrylate, ethyl acrylate or butyl acrylate; and so forth, and a composition containing at least one of the above-described homo- and copolymers. Preferred examples thereof. are homo- and copolymers consisting of the above-described monomers alone. More preferred examples are PANA, a copolymer of methyl methacrylate and methyl acrylate, and a copolymer of methyl methacrylate and butyl acrylate. The term "copolymer" as used herein its not limited to a random copolymer, but includes, for example, a graft copolymer. For example, a copolymer obtained by graft-polymerizing a monomer mixture composed mainly of methyl methacrylate onto acrylic saturated cross-linked rubber is preferably used. The WA which is incorporated into the adhesive layer may be any conventional WAs. Of those, benzotriazole type and benzophenone type UVAs are preferred. The lower limit for the amount of the tWA added varies depending on the degree of weathering resistance required and the thickness of the adhesive layer. For example, when the thickness of the adhesive layer is small and the amount of the UVA is small, ultraviolet rays reach underlying layers, causing the deterioration thereof. On the other hand, the upper limit for the amount of the UVA added varies depending on the compatibility of the UVA with the polymer which constitutes the adhesive layer. For example, when the compatibility is poor, if the amount of the UVA is increased, the adhesive layer peels off from the polyvinylidene fluoride layer. Thus the amount of the tWA added in the invention is from 0.3 to 30 phr, preferably'from 1 to 15 phr, and more preferably from 2 to 5 phr, based on the amount of polymer which constitutes the.adhesive layer. The thermoplastic resin layer which is bonded to the polyvinylidene fluoride layer via the adhesive layer may be made of any conventional thermoplastic resin. Of these conventional thermoplastic resins, resins having an impact resistance such as a polyvinyl chloride resin (hereinafter referred to as "PVC" for brevity), a polycarbonate resin (hereinafter referred to as "PC" for brevity), and an acrylonitrile-butadienestyrene resin (hereinafter referred to as "ABS" for brevity) are preferably used. The PVC which 'can be used include a vinyl chloride homopolymer, a copolymer comprising at least 70 molt of vinyl chloride and one or more monomer copolymerizable therewith, and a composition composed mainly of at least one of the homo- and copolymers. The PVC may contain additives such as an impact resistance-increasing agent, a processing additive, and a filler. The PC which can be used is not limited to conventional polycarbonates, but includes various polycarbonates such as copolycarbonates, hete-ro-bond copolymers containing a carbonate bond and another bond in the main chain, and compositions composed mainly of the polycarbonates. The ABS which can be used includes a copolymer consisting essentially of acrylonitrile, styrene and butadiene, copolymers additionally containing other monomer) such as methyl methacrylate, and compositions composed mainly of such copolymer. A particularly preferred method of preparing the laminated product of the invention is an extrusion molding method which comprises laminating the layers in a multilayer molding die by a coextrusion procedure and extrusion molding the laminate. In addition, other conventional extrusion lamination methods, for example, a method which comprises melt extruding each resin and laminating and bonding the resulting layers outside a molding die by means of rolls or presses, can be used. The shape of the laminated product of the invention is not limited to a planar form, and the laminated product may be a tubular form, a corrugated form and so forth. The laminated product of the invention may be used alone or by laminating it on other substrates. The present invention will be now explained in greater detail by reference to the following Examples and Comparative Examples, but is not limited thereto. Unless otherwise indicated, all percentages, parts, ratios and the like are by weight. EXAtIPLES '1 TO 6 AND COWIPAR4TIVE EXA3IPLE 1 (1) Preparation of Material for Surface Layer To 100 parts of a vinylidene fluoride homopolymer having an inherent viscosity of 1.00 dl/g Cmeasured in a dimethylformamide solution having a concentration of 0.4 g/dl at 300C) were added 20 parts of an acryl resin (trade name "Acrypet H-70", produced by Mitsubishi Rayon Co., Ltd.) and 1.0 part by weight of 2- C2 ? -hydroxy-31 '5' -di-tert-butyiphenyl) -5 -chlorobenzo- triazole as an ultraviolet absorber. The resulting mixture was mixed with a blade blender for 30 minutes and extruded at 200"C to form pellets. C2) Preparation of Material for Adhesive Layer To 100 parts of the same acryl resin as used in C1) above was added the same ultraviolet absorber as used in (1) above in an amount of 0.2, 0.5, 3, 5, 10, 20 and 25 parts as shown in Table 1. Each of the resulting mixture was extruded at 1900C to form pellets. C3) Preparation of Material for Underlying Layer Amount (parts) Polyvinyl chloride (P = 700) 87 Impact resistance-increasing agent** 13 Tin octylate 2.5 Glycerin monostearate 0.5 Wax 0.2 P: Average degree of polymerization ** Prepared by graft polymerizing a monomer mixture consisting of 16.9 parts of styrene, 10.6 parts of methyl methacrylate and 0.09 part of divinyl benzene onto a cross-linked rubber copolymer prepared from 50 parts of butadiene, 15 parts of styrene and 0.65 part of divinylbenzene, and then further graft polymerizing a monomer mixture consisting of 7.5 parts of methyl 'methacrylate and 0.04 part of divinylbenzene onto the graft copolymer obtained in the firs graft polymerization. The above mixture was kneaded in a Henschel mixer at 1200C for 10 minutes to prepare the material for the underlying layer. Pellets obtained in ±1) were extruded using a 32 ° Cmm in diameter and hereinafter the same) extruder at 235 C, pellets obtained in (2) were extruded using a 25 ° extruder at 235 C, and the material obtained in C3) was extruded using a 90 extruder at 1950C. The resulting three layers were subjected to composite fluidization in a composite T die (1.3 m wide) for three layer coextrusion and extruded therefrom. The sheet thusprepared was drawn with a roll maintained at 70"C, cooled, and then was subjected to heat treatment under relaxation with a' roll maintained at 90"C to obtain a sheet consisting of a 2 p thick surface layer, a 4 p thick adhesive layer, and a 44 p thick underlying layer. Each sheet was measured in respect to total light transmittance (Tr), Yellow Index CYl), peeling-off of layers, and so forth both immediately after molding and also after allowed to stand in a sunshine weatherometer for 2,500 hours. The results are shown in Table 1. The total light transmittance (Tr) was determined by the ratio of 1/1o wherein 1o was the intensity of 500 to 600 mp incident light and I was the intensity of average transmitted light, which were measured using a spectrophotometer Ca product of Hitachi Corp.). The Yellow Index (YI) was measured according to JIS 7103 (JIS refers to Japanese Industrial Standard). For all the sheets; the formation of stripe-like bubbles and the peeling-off of layers were not observed. TABLE 1 Amount of Immediately Ultraviolet after After 2,500 Hours Absorber Molding in Weatherometer in Adhesive Layer Tr YI Tr YI (phr) (%) (%) Comparative 0.2 85 3.4 77 20 Example 1 Example 1 0.5 84 3.5 80 11 2 2 3 85 3.5 82 7 3 3 5 84 3.5 82 5 " 4 10 83 3,5 82 4 " 5 20 83 3.5 82 4 " 6 25 83 3.6 82 4 EXAMPLES 7 TO 11 AND COMPARATIVE EXAMPLES 2 TO 3 (1) Preparation of Material for Surface Layer To 100 parts of the same vinylidene fluoride homopolymer as was used in Example 1 were added 20 parts of PMMA and an ultraviolet absorber in amounts of 0, 0.5, 1, 2, 3, 5, and 7 parts, as shown in Table 2, and the resulting mixture was processed in the same manner as in Example 1 to form pellets. As the ultraviolet absorber, 2-hydroxyoctoxybenzophenone was used. C2) Preparation of Material for Adhesive Layer The same pellets as prepared in Example 4 except that the 'same ultraviolet absorber as used in (1) above was used. (3) Preparation of Material for Underlying Layer The same PVC material as prepared in Example 1 was used. The above prepared materials were subjected to composite extrusion under the same conditions as in Example 1 to obtain a composite sheet having the same thickness and construction as in the sheet obtained in Example 1. The physical properties of the sheet were measured in the same manner as in Example 1. The results obtained are shown in Table 2. T A B L E 2 After 2,500 Hours Amount of Formation of Immediately in Weatherometer Ultraviolet Voids in after Peeling Absorber in Stripe-Like Molding Tr YI Off of Surface Layer Bubbles Tr YI Layers (%) (%) Example 7 0 None 83 3.4 82 4.0 Partially observed " 8 0.5 do 83 3.4 82 3.9 Not observed " 9 1 do 83 3.5 83 3.9 do " 10 2 do 83 3.5 83 3.8 do " 11 3 do 83 3.5 83 3.8 do Comparative Partially 5 82 3.6 82 3.7 do Example 1 formed " 2 7 Formed 82 3.6 82 3.7 do EXAMPLE 12 The same procedure of Example 10 was repeated except that polycarbonate ("Panlight F-125", a product of Teijin Kasei Co., Ltd.) was used as a material for the underlying layer and was extruded at 290 C from a 90 ° extruder. Immediately after the molding, the Tr was 87% and YI was 5.8, and after being allowed to stand in a sunshine weatherometer for 2,500 hours, the Tr was 86% and YI,.was 6.8. REFERENCE EXAMPLE Laminated products were prepared by coextruding PVC (# = 700) as a substrate, PMMA ("ACRYPET HR-70", a product of Mitsubishi Rayon Co., Ltd.) as an intermediate layer, and PVDF (ninh = 0.90 dl/g) for a surface layer, wherein the thickness of the intermediate layer was 20 , the total thickness of the laminated product was 1,000 , and the thickness of the PVDF surface layer was varied, viz., .O u 5 u, 10 , and 20 w. These laminated products were cooled with cooling rolls maintained at 800C to produce laminated sheets. Parallel light transmittance and haze of each sheet were measured. The results obtained are shown in Figure 1. It was clarified from Figure 1 that the light transmittance and haze are remarkably improved when the thickness of the PVDF surface layer was 5 or less. EXAMPLE 13 (1) Preparation of Material for Surface Layer To 100 parts of a vinylidene fluoride homopolymer having an inherent viscosity of 1.00 dl/g (measured in a dimethylformamide solution having a concentration of 0.4 g/dl at 300C) were added 40 parts of an acryl resin (the same PIZZA as used in Reference Example) and 0.3 part of 2-(21-hydroxy-31,51-di-tert- butylphenyl)-5-chlorobenzotriazole as an ultraviolet absorber. The resulting mixture was mixed with a Henschel blender for. 15 minutes and extruded at 205"C to form pellets. (2) Preparation of Material for Adhesive Layer A mixture of 100 parts of the same acryl resin as used in (1) above and 12.5 parts of the same ultraviolet light absorber as used in C1) above was extruded at 195 C to form pellets. C3) Preparation of Material for Substrate Layer Amount (parts) Polyvinyl chloride CP = 1,000) 100 Plasticizer Cdioctyl phthalate) 30 Plasticizer (tricresyl phosphate) 10 Octyl tin maleate 2 Wax -0.15 UVA (the same as in Example 1) 0.5 The above mixture was blended with a Henschel mixer at 1200C for 10 minutes to prepare the material for the adhesive layer. Pellets obtained in (1) were extruded from a 32 ° extruder at 2350C, pellets obtained in (2) were extruded from a 25 extruder at 235 C, and the material obtained in (3) was extruded from a 90 extruder at 1950C.' The resulting three layers were subjected to composite fluidization in a three layer composite T die, cooled by means of rolls maintained at 800C, drawn, and then was subjected to relax heat treatment by means of rolls maintained at 950C to obtain a sheet consisting of a 2 p thick surface layer, a 4 thick intermediate layer, and a 44 p thick substrate Ctotal thickness, 50 ). Total light transmittance CTr, t) of the sheet was 93% immediately after molding and 91% after being allowed to stand in a sunshine weatherometer (a product of Suga Testing Machine Co., Ltd.) for 2,500 hours. Further, peeling-off of layers in the form of blisters between the layers was not observed. EXAMPLES 14 TO 18 (1) Preparation of Material for Surface Layer In the same manner as in Example 13, 1 part of an ultraviolet absorber was added to 100 parts of a vinylidene fluoride homopolymer, and the resulting mixture was then processed to form pellets. In this case, 2-hydroxy-4-octoxybenzophenone was used as the ultraviolet absorber, and PMMA was not used. Preparation of Material for Adhesive Layer In the same manner as in Example 13 except that 10 parts of the same ultraviolet absorber as used in C1) above, pellets were prepared. (3) Preparation of Material for Substrate Layer The same PVC mixture as used in Example 13 was used. Coextrusion was performed under the same conditions as in Example 13 to produce a 0.5 p/5 /44.5 u sheet (Example 14), a 2 p/5 p/43 p sheet CExample IS), a 5 /5 /40 p sheet (Example 16), an 8 p/5 /37 p sheet CExample 17), and a 13 p/5 /32 u sheet (Example 18), with the constructions noted being that of surface layer thickness/adhesive layer thickness/substrate layer thickness. Total light transmittance CTr, t) of each sheet was measured in the same manner as in Example 13. The results obtained are shown in Table 3. TABLE 3 Tr %) immediately AfteT 2,500 Thickness of after Hours in Surface Layer Molding Weatherometer () Example 14 0.5 94 92 " 15 2 93 91 " 16 5 91 89 " 17 8 88 86 18 13 86 85 Briefly summarized, therefore, the invention provides an extrusion laminated product comprising at least three layers, wherein at least one surface, layer comprises a polyvinylidene fluoride resin, preferably containing an ultraviolet absorber (WA) in an amount up to 3 phr (parts by weight per hundert parts by weight of resin and hereinafter the same), and an adhesive layer between the polyvinylidene fluoride outer layer and another thermoplastic resin layer comprises a polymer prepared from at least one of ethyl methacrylate and methyl methacrylate as a major ingredient or a composition containing the polymer as a major component (e.g., at least about 50 wt%) and from 0.3 to 30 phr of an ultraviolet absorber. While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.

Claims: Claims: 1. An extrusion laminated product comprising at least three thermoplastic resin layers, characterized in that at least one surface layer of the product comprises polyvinylidene fluoride, and in that an adhesive layer which is provided between the or each surface layer andthe remainder of the thermoplastic resin layers comprises a polymer having either at least one of methyl methacrylate and ethyl methacrylate as a major component or Åa composition containing said polymer as -a major component and from 0.3 to 30 phr of an ultraviolet absorber. 2. An extrusion laminated product as in Claim 1, characterized in that the or each surface layer comprising polyvinylidene fluoride additionally contains an ultraviolet absorber in an amount up to 3 phr. 3. An extrusion laminated product as in Claim 1 or 2, characterized in that the or each adhesive layer contains from 1 to 15 phr of an ultraviolet absorber.

Inventors: AKATSU, MASAMICHI, ENDOH, HIROYUKI, NAKADAI, TAKESHI, SASAKI, TOHRU
Applicants: KUREHA KAGAKU KOGYO KABUSHIKI KAISHA
Application year: 1982
Main classification: B32B27
IPC codes: B32B27