Mixtures comprising silanol-terminated polydiorganosiloxane and processes

Abstract: Alkoxy-functional one-component RTV silicone rubber composition which is self-stable and fast-curing. The composition is formed by reacting a silanol-terminated polysiloxane polymer with an alkoxy-functional cross-linking agent in the presence of a condensation catalyst. The present invention lies in the use of silicon-nitrogen compounds and silicon-nitrogen polymers as scavengers for unendcapped hydroxy groups in the above polyalkoxy-functional RTV systems. A preferred silicon-nitrogen compound is hexamethyldisilazane.

Description: Background of the Invention The present invention relates to mixtures comprising silanol-terminated polydiorganosiloxanes, and more particularly, the present invention relates to scavengers for such mixtures. Early types of one-component RTV silicone rubber compositions are, for instance, disclosed in Ceyzeriat, U.S. Patent 3,133,891, and Bruner, U.S. Patent 3,035,016. Such patents disclose the use of acyloxy-functional silanes as cross-linking agents for such RTV compositions (RTV in this application refers to room temperature vulcanizable). The compositions of Ceyzeriat were packaged in a substantially anhydrous state and when exposed to atmospheric moisture cured to a silicone elastomer. It was highly desirable to make such compositions as noncorrosive as possible, to be self-bonding, to be shelf stable and to have a fast cure rate. While the Ceyzeriat and Bruner compositions were shelf stable and fast-curing, neverthless they had the disadvantage that they were somewhat corrosive and emit a somewhat pungent odor while curing. The US-A-3,243,404 relates to a silicon-nitrogen process aid and methods for making the same. The US-A-3,888,815 relates to a self-bonding RTV composition comprising an alkyl silicate and a nitrogen-functional silane. It was highly desirable to make such compositions self-bonding, so that they would bond to most substrates without the use of a primer. This resulted in a saving on labor costs. Examples of disclosures which relate to increasing the adhesiveness or self-bonding properties of the Ceyzeriat composition are, for instance, disclosed in Kulpa, U.S. Patent 2,961,161, Goossens, U.S. Patent 3,296,195, and Beers, U.S. Patent 3,428,930. A further example of acyloxy-functional RTV compositions can be, for instance, found in Beers, U.S. Patent 4,257,932 and other related patents. However, even the composition of Beers, U.S. Patent 4,257,932 which disclosed the use of a high carbon atom acyloxy-functional RTV, there resulted some discoloration of the metal on which the RTV was applied as a result of the fact that the composition released a high molecular weight acid when it cured (2-ethylhexanoic acid). Accordingly, it was highly desirable to make a one-component, non-corrosive RTV composition, comparable in shelf stability and curing properties to the Bruner and Ceyzeriat corrosive acyloxy-functional, one-component RTV systems. It was early known that two-component RTV compositions were noncorrosive since they relied on a cross-linking agent which released an alcohol upon curing. An example of a two-component RTV composition is, for instance, to be found in Nitzsche et al., U.S. Patent 3,127,363. The only trouble with the Nitzsche et al. composition was that it was two-component and required the additional labor step of taking the packages and mixing them together in the appropriate ratios and then quickly applying the composition to whatever form was desired in which it was to be cured. The composition had to be applied in a rapid manner since it had a very poor shelf life once it was mixed. Accordingly, such compositions were not altogether desirable. It was desired to make such compositions one-component because of the noncorrosive characteristics. Accordingly, an early disclosure of a one-component alkoxy-functional RTV system is to be found in Nitzsche et al., U.S. Patent 3,065,194. The difficulty with the Nitzsche et al., U.S. Patent 3,065,194 composition was that the composition had to be vigorously dried during preparation and had a very short shelf life. Early one-component alkoxy-curing systems are to be found in Brown et al., U.S. Patent 3,122,522, Brown et al., U.S. Patent 3,161,614 or U.S. Patent RE-29760, which disclosed polyalkoxy-terminated polymers. The difficulty with these polymers was that they did not cure at a sufficient rate, that is they were not fast-curing, and furthermore if they cured at all, had a very poor shelf life. It should be noted that the term "shelf life" in this application means that the composition, after it has been stored for periods of one month to one year after manufacture, will cure at about the same rate and to about the same degree of final cure as the composition that is cured immediately or a few days after manufacture. Accordingly, it was highly desirable to make such compositions shelf stable and be fast-curing. Examples of noncorrosive, one-component alkoxy-functional RTV systems which, in some cases, were commercialized are disclosed by Weyenberg, U.S. Patent 3,334,067, Cooper et al., U.S. Patent 3,542,901 and by Smith et al., U.S. Patent 3,689,454 and 3,779,986. These applications relied on the particular use of specific titanium chelate catalysts in place of a tin soap condensation catalyst to accelerate the cure of the composition. As stated previously, although some of the compositions disclosed in the above patents were commercialized, nevertheless, the compositions still did not have a sufficiently fast cure rate even with the specialized chelate catalysts and even then did not have a sufficient shelf life. A specific type of alkoxy-functional, one-component RTV system which has been commercialized and has a number of advantages in terms of noncorrosiveness and low modulus properties is to be found, for instance, in the disclosure of Beers, U.S. Patent 4,100,129 which is hereby incorporated by reference. The composition of this patent is noncorrosive, is low modulus and has self-bonding properties in view of the self-bonding additives incorporated into the composition. However, even the composition of this patent was not sufficiently fast-curing and did not have a sufficient shelf life, that is, after a period of six months, one year or more, the shelf life of the composition was poor. Examples of adhesion promoters that could be utilized with such a composition are, for instance, to be found disclosed in Mitchell et al., U.S. Patent 4,273,698 which is hereby incorporated by reference. All the patents referred to in this application are incorporated by reference into the present case. However good the self-bonding properties of the Beers composition are, it nevertheless still suffered from not having as good a shelf life as would be desired and not being as fast curing as would be desired. Accordingly, it was highly desirable to find a noncorrosive self-bonding RTV composition which was low modulus and was shelf stable and fast-curing. The above RTV systems that have been disclosed are alkoxy-functional and acyloxy-functional. There are also other types of functional one-component RTV systems. An example of an amine-functional RTV system is, for instance, to be found in disclosures of the following U.S. patents. Nitzsche et al., U.S. Patent 3,032,528; Hittmair et al., U.S. Patent 3,408,325; Nitzsche et al., U.S. Patent 3,923,736; Hittmair et al., U.S. Patent 3,464,951 There are also disclosed in various patents one-component amide-functional RTV systems, aminoxy-functional RTV systems, ketoxime-functional RTV systems, etc. Recently, there has been developed a one-component alkoxy-functional RTV system which is shelf stable and fast curing as disclosed in White et al., EP-A-0 069 256. Basically, the EP-A-0 069 256 discloses the production of a shelf-stable, fast-curing, one-component alkoxy-functional RTV system which is cured with a tin compound by having a scavenger in this system. The scavenger, which can be either a separate compound or part of the alkoxy-functional cross-linking agent, operates by absorbing all unbonded or free hydroxy groups in the RTV mixture so as to prevent the hydroxy groups from degrading and cross-linking the polymer mixture, thus deleteriously affecting its shelf life and curing properties. It is disclosed in this patent application that the scavenger may be amine-functional, that is, either the separate scavenger compound may be amine-functional or the combined cross-linking agent scavenger may be amine-functional. There is further disclosed that amine-functional accelerators may be utilized in the composition especially when the scavenger is enoxy-functional. Although certain simple types of amines are disclosed in this application, there is nowhere disclosed the utilization of silazanes and silyl-nitrogen polymers. The difficulty with the amine scavenger as disclosed in the. EP-A-0 069 256 is that while they are known, nevertheless they have to be specially prepared for the composition of said EP-A. On the other hand, silazanes like hexamethyldisilazane are readily available in any silicone manufacturing plant. More importantly, however, the amines of said EP-A, give a noticeable odor to the composition while on the other hand, hexamethyldisilazane imparts to the RTV composition a slight odor of ammonia. Be that as it may, there are other silyl-nitrogen compounds that can be utilized as scavengers for the compositions of EP-A-0 069 256 other than the ones disclosed in said EP-A which is the object of the present case. Other improvements over EP-A-0 069 256 are, for instance, to be found in DE-A-33 05 356. DE-A-33 05 356 discloses various types of additives that can be added to the compositions of EP-A-0 069 256 to make the composition low modulus. It is an object of the present invention to provide a process for producing a relatively inexpensive non-corrosive, one-component RTV composition which is shelf stable and fast curing and which does not have an objectionable odor This and other objects of the present invention are accomplished by means of the disclosures set forth herein and below. Summary of the Invention In accordance with the above objects, there is provided by the present invention a stable, one-package, substantially anhydrous and substantially acid-free, room temperature vulcanizable organopolysiloxane composition stable under ambient conditions in the substantial absence of moisture over an extended period of time and convertible to a tack-free elastomer as defined in claim 29. The silane scavenger for hydroxy-functional groups of said composition is selected from a silicon-nitrogen compound selected from the class consisting of (A) a silicone-nitrogen compound having the formula where Y is selected from R''' and R''₂N― and (B) a silicon-nitrogen polymer comprising (1) from 3 to 100 mole percent chemically combined structured units selected from units having and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula and mixtures thereof where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR″Si linkage, the free valences of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silazy unit are joined to a member selected from an R″ radical and (R″)₂N radical, and where the ratio of the sum of said R‴ radicals and said (R″)₂N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive R″ is a member selected from hydrogen and C (1-12) monovalent hydrocarbon radicals, and fluoroalkyl radicals, R''' is a member selected from hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive. The most preferred compound within the scope of the formula of the silicon-nitrogen compound is a silazane and more particularly hexamethyldisilazane. Other compounds within the scope of the formula may be utilized as scavengers in the instant case such as hydrogen-containing amines, as will be explained below. There is envisioned within the present invention that such scavengers are not mixed cross-linking agents scavenger compounds, but rather there is utilized a separate cross-linker and the silyl-nitrogen material is a separate compound which is added to that composition. Such scavengers may be utilized to prepare the composition in a number of ways as disclosed in EP-A-0 069 256, that is, all the ingredients may be mixed together at the same time with the scavenger mixed in along with the other ingredients. Thus in the preferred embodiment of the instant case, there is first added the cross-linking agent to the silanol-terminated diorganopolysiloxane polymer in the presence of a condensation catalyst. The preferred condensation catalyst for this prose is di-n-hexylamine. Other preferred condensation catalysts are as follows: diethylamine; dipropylamine, dibutylamine, cyclohexylamine, dioctylamine, guanidine, alkylguanidine diisopropylamine, diisobutylamine. Once the scavenger is added, that is, one of the silicon-nitrogen compounds disclosed above it absorbs all unend-capped hydroxyl groups. Then all the other ingredients may be added into the composition whereupon the scavenger will absorb the free hydroxy groups from such materials also. As a result of the preparation of the composition in this manner there will be prepared a composition which is substantially free of free hydroxy groups and as a result is shelf-stable and fast-curing; by shelf stable it is meant that it will have a rate of cure and degree of cure which is about the same six months or one year after it has been manufactured as it was after its manufacture and preparation. The silane-nitrogen scavengers for accomplishing this will be more fully explained below. Description of the Preferred Embodiment In the above formulas of the silicon-nitrogen compound and silicone-nitrogen polymer, the R″ and R‴ radicals may be selected from hydogen and any monovalent hydrocarbon radicals including fluoroalkyl radicals. Examples of the radicals from which the R″ and R‴ can be selected are, for instance, alkyl radicals such as methyl, ethyl, propyl, etc.; cycloalkyl radicals such as cyclohexyl, cycloheptyl, etc.; mononuclear aryl radicals such as phenyl, methylphenyl, ethylphenyl, etc.; alkenyl radicals such as vinyl, allyl, etc.; fluoroalkyl radicals such as 3,3,3,trifluoropropyl. Generally, the R″ and R‴ radicals may have from 1 to 12 carbon atoms and more preferably the radicals may have from 1 to 8 carbon atoms. In addition to the above described silicon-nitrogen materials, there are also included in the present invention, silicon-nitrogen materials having divalent hydrocarbon radicals attached to silicon atoms through silicon-carbon linkages. For example, also included among the silicon-nitrogen materials that can be employed in the practice of the invention, are arylensilazanes, such as phenylene silazanes, and alkylenesilazanes such as methylenesilazanes. In addition, various other silicon-nitrogen materials, containing divalent hydrocarbon radicals are also contemplated including copolymers and terpolymers such as silicon-nitrogen materials containing intercondensed siloxane units and silarylenesilazane units, intercondensed silazane units, silarylenesiloxane units, and siloxane units, etc. The silicon-nitrogen polymers that can be employed in the practice of the present invention include silicon-nitrogen polymers in the form of silazane/siloxane copolymers having at least 3 mole percent of chemically combined silazy units and up to 97 mole percent of combined siloxy units. Accordingly, the silazane polymers include cyclics consisting of chemically-combined units where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and R''₂N radicals per silicon atom in said silazane polymer. The definition of a silazane polymer includes linear polymers having at least one unit selected from of units and or R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and R''₂N radicals per silicon atom in said silazane polymer. Further silazane polymers which are included within the definition of the above polymers comprise linear polymers consisting essentially of units where R'' and R''' are defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and R''₂N radicals per silicon atom in said silazane polymer. In addition, the silazane polymers include polymers having at least one unit selected from units and where R'' and R''' are as previously defined to provide a ratio of 1.5 to 3 of the sum of the R''' and R''₂N radicals per silicon atom in said silazane polymer. In addition the silazane polymers comprise also polymers having units selected from where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and R''₂N radicals per silicon atom in said silazane polymer. The silazane/siloxane copolymers can also be in the form of cyclics and consist of chemically combined R'''₂SiO units and units where R″ and R‴ are as previously defined. Linear silazane-siloxane copolymers are also included where the mole percent of units can be as high as 97 mole percent with the balance of the units being selected from where R″ and R‴ are as previously defined to provide for a ratio of the sum of R‴ + R''₂N radicals per silicon of the silazane-siloxane copolymer from 1.5 to 3. Other linear silazanes that are included within the scope of the above formulas are ones having the formula where R'' and R''' are as previously defined, n is a positive whole number and is from 0 to 20 inclusive, and d is a whole number equal to 0 or 1 and where d is equal to 0 and n is equal to 3 to 7, inclusive. Illustrating the silazanes that can be employed in the practice of the present invention within the scope of the above formulas are hexamethylcyclotrisilazane, octamethylcyclotetrasiloxane, trimethyltriphenylcyclotrisilazane, trivinyltrimethylcyclotrisilazane, etc. Other silazanes within the scope of the above formulas are as follows: There can be phenyl, vinyl, 3,3,3-trifluoropropyl and various alkyl groups on middle Si atoms (ethyl, propyl, butyl). In addition to the silazanes of the above formulas, there is also included polysiloxanes having terminal silylamine units or silazane units as shown by the formula where R″ and R‴ are as defined previously, Z is a member selected from R″ and SiR'''₃ where R″ and R‴ and n are as defined previously. The polysiloxane compounds of the above formula may be prepared by taking ammonia or an amine and reacting it at a temperature within the range of between about 0° to 60°C. with a halogenated polysiloxane having the formula where R‴ and n are as defined above and X is a halogen radical such as chloro or bromo. If a terminal silazane radical is desired, for example, a molar amount of (R‴)₃Si X can be reacted along with the halogenated polysiloxane, at least equivalent to the moles of halogen radicals contained therein. It will, of course, be appreciated that amines of the formula H₂NR'' are utilized for forming the silazy chain-stopped polysiloxanes of the invention where R″ is as defined above, while in the case when materials are desired having terminal silyl amine radicals, amines, including amines of the above formula can be employed having at least one hydrogen available for reaction to produce the desired polysiloxane. The halogen chain-stopped polydiorganosiloxanes of the above formula can be made by conventional procedures such as by the controlled hydrolysis of a diorganodihalosilane, for example, dimethyldichlorosilane as taught in Patnode Patent 2,381,366 and Hyde Patents 2,629,726 and 2,902,507. Another procedure that can be employed involves equilibrating a mixture of a diorganodichlorosilane and a cyclic polydiorganosiloxane in the presence of a metal catalyst such as ferric chloride as shown in Sauer Patent 2,421,653. Although the various procedures utilized in forming the above polysiloxanes are not critical, generally it has been found desirable to maintain the halogen content of the resulting chain-stopped polysiloxane in the range of about 0.4 to about 35 percent, by weight, and preferably from about 5 to about 20 percent by weight. The halogen chain-stopped polysiloxane is preferably in the form of a chlorinated chain-stopped polydimethylsiloxane. Included among the amines which can be employed with the halogenated polysiloxanes are ammonia, methyl amine, aniline, dimethyl amine, ethylphenyl amine, methylethyl amine, etc. The process for producing the rest of the silazane compounds and silazane polymers is well known to a worker skilled in the art. The silicon nitrogen materials that can be employed as process aids in the practice of the present invention can be volatile liquids or gummy, resinous or crystalling solids, depending upon such factors as the molecular weight and the nature and average functionality of their respective chemically combined units. These silicon-nitrogen materials include for example, silyl amines, silazanes and fluid polymers consisting essentially of intercondensed siloxane units and silazane units terminated by triorganosiloxane units, polymers consisting essentially of intercondensed siloxane units with or without silazane units terminated by silyl amine units, etc. Typical of the methods that can be employed to make the materials that can be used in the present invention include the method shown by R. O. Sauer, et al., J.A.C.S., Vol. 68, 1946, p 241-44, and in Patent 2,462,635―Haber, 2,885,370―Groszos et al., 2,579,416, 2,579,417, and 2,579,418―Cheronis. Examples of the polymers containing intercondensed siloxane and silazane units, and polysiloxanes terminated by silyl amine units that are operable in the present invention are shown in Patent 2,503,919―Patnode, and 2,865,918―Hurwitz et al. Some of the silyl amines that can be employed in the practice of the invention are shown in Patents 2,429,883―Johannson, 2,807,635―Breedervelt et al., and 2,758,127―Goldschmidt et al., etc. Accordingly, the process for producing such polymers and compounds is well known. As an example, there is given here a process for preparing hexamethylcyclotrisilazane. This is prepared by taking dimethyldichlorosilane, adding it to a saturated solution of ammonia in benzene while agitating the mixture. During the subsequent addition of the dimethyldichlorosilane ammonia can be bubbled through the mixture while the temperature is maintained below 50°C. Additional ammonia was bubbled through the mixture until no further ammonium chloride is precipitated. The product can be recovered by stripping off the benzene under vacuum. Utilizing such a method, there can be obtained hexamethylchlotrisilazane as well as trisilazane. Similar methods can be employed to produce any of the above compounds for which formulas were given above. Fluoroalkyl-substituted silazane compounds can also be prepared by a similar method. The existence of such silyl-nitrogen compounds and silyl-nitrogen polymers as well as their methods of preparation is disclosed in U.S. Patent 3,243,404 to which a worker skilled in the art can refer to for more information. In addition to the foregoing silyl-nitrogen compounds and silyl-nitrogen polymers disclosed above, there can also be utilized in the instant invention as defined in claim 46 scavengers which are silyl amines of the formula where R²⁰ is a radical selected from C (1-8) monovalent hydrocarbon radicals and C (1-8) alkoxy radicals and fluoroalkyl radicals, and R'' is selected from hydrogen and a C (1-8) monovalent hydrocarbon radical, and g is a whole number that varies from 1 to 3, h is a whole number that varies from 0 to 2 and the sum of h + g does not exceed 3. Compounds coming within the scope of the above formula are, for instance, methyl di(methylamino)-silane, tris(methylamino)silane, methyl bis(diethylamino)silane as well as the following: tris(diethylamino)silane methylbis(dimethylamino)silane tri(ethylamino)silane ethyl di (methylamino)silane ethyl di (ethylamino)silane ethyl bis(dimethylamino)silane Such amines are disclosed in U.S. Patent 3,243,404 and can be produced by the methods disclosed in that patent. The silyl-nitrogen compounds and polymers are the most preferred in the instant compositions as scavengers, then the above amines can also be utilized as scavengers in the RTV composition of the instant case. The only difficulty with the hydride amines is that they do tend to liberate hydrogen upon standing and also they tend to impart the undesirable odor of amines to the RTV composition. However, if this is not a problem, then they can be tolerated in the instant composition. Preferably, the silyl-nitrogen compounds such as hexamethyldisilazane and the rest, are utilized in a concentration of 0.5 to 10 parts by weight per 100 parts of the base organopolysiloxane polymer. Examples of fluorosilicone silazane compounds within the scope of the above formulas are, for instance, compounds such as ones having the formulas [CF₃ CH₂ CH₂ (CH₃)₂ Si]₂NH [CF₃ CH₂ CH₂ (CH₃) Si NH]₃ [CF₃ CH₂ CH₂ (CH₃)₂Si]₂ N-CH₃ Accordingly, the preferred silyl-nitrogen compounds and polymers within the scope of the above formulas may be utilized in the instant invention. As stated previously, generally, preferably from 0.5 to 10 parts of the scavenger is used per 100 parts by weight of the silanol base polymer. Whether the base polymer is silanol-stopped or polyalkoxy-stopped as will be explained below, makes little difference in the concentration of the scavenger since the molecular weight of both compounds is approximately the same. More generally, the scavenger may be utilized in a concentration of 1 part to any concentration that is desired. It is not desirable to add too much of the scavenger since above 10 parts may detract from the cured physical properties of the composition. As will be explained below, it is generally desired to have at least 3% excess of the scavenger in the composition, that is, 3% excess over the amount necessary to absorb or endcap all the free hydroxy groups in the composition. The compositions with which the scavenger in the instant case may be utilized are varied but are specifically disclosed below and perhaps more generally in the EP-A-0 069 256, the DE-A-33 05 356 and elsewhere. As utilized hereinafter, the term "stable" as applied to the one-package silanol-terminated organopolysiloxane RTV's of the present invention means a moisture curable mixture capable of remaining substantially unchanged while excluded from atmospheric moisture and which cures to a tack-free elastomer after an extended shelf period. In addition, a stable RTV also means that the tack-free time exhibited by freshly mixed RTV ingredients under atmospheric conditions will be substantially the same as that exhibited by the same mixture ingredients exposed to atmospheric moisture after having been held in a moisture-resistant and moisture-free container for an extended shelf period at ambient conditions, or an equivalent period based on accelerated aging at an elevated temperature. As noted previously, the present RTV composition is substantially acid-free. The expression "substantially acid-free" with respect to defining the elastomer made from the RTV composition of the present invention upon exposure to atmospheric moisture means yielding by-products having a pKa of 5.5 or greater with 6 or greater preferred and 10 or greater being particularly preferred. The silanol-terminated polydiorganosiloxane has the formula where R is a C (1-13) monovalent substituted or unsubstituted hydrocarbon radical, which is preferably methyl, or a mixture of a major amount of methyl and a minor amount of phenyl, cyanoethyl, trifluoropropyl, vinyl, and mixtures thereof and n is an integer having a value of from about 50 to about 2500 with a cross-linking silane having hydrolyzable radicals attached to silicon. Preferably n varies so that the viscosity of the polymer varies from 60,000 to 200,000 centipoise at 25 C. Although the compositions may be expressed in terms of a silanol polymer, that is a silanol polymer with a cross-linking agent as will be explained below, and a scavenger of the formulas indicated above and as has been done in the summary of the invention, it can be expressed in other terms. The present invention is based on the discovery that stable, substantially acid-free, one-package, moisture curable silanol-terminated organopolysiloxane RTV compositions can be made by using a silanol terminated polydiorganosiloxane consisting essentially of chemically combined diorganosiloxy units of the formula such as a silanol-terminated polydiorganosiloxane of Formula (1), where R is as previously defined, with an effective amount of certain silane scavengers for chemically combined hydroxy radicals. In the silanol-terminated polydiorganosiloxane consisting essentially of chemically combined Formula (2) units, the presence of silicon bonded C (1-8) alkoxy radicals such as methoxy radical is not precluded. The hydroxy radicals which can be removed by the silane scavenger can be found in materials normally present in the RTV composition of the present invention, for example, trace amounts of water, methanol, silanol radicals on the silica filler (if used), the silanol polymer of Formula (1), or a silanol-terminated polymer having Formula (2) units. The silane scavenger is a separate compound of the formulas indicated above. Among the ingredients of the RTV compositions which are formed as a result of the use of the hydroxy scavenger is silanol-free polydiorganosiloxane, chain-terminated with two or three -OR¹ radicals. The silanol-free polydiorganosiloxane optionally can be combined with an effective amount of a cross-linking silane, as defined hereinafter, under substantially anhydrous conditions. The cross-linking polyalkoxysilane which can be utilized in combination with the scavenging silane has the formula where R¹, R² and b are as previously defined. The preferred condensation catalysts which can be used in the practice of the invention include metal compounds selected from tin compounds, zirconium compounds, and titanium compounds or mixtures thereof. Additional condensation catalysts which can be used are defined more particularly hereinafter. It is believed the reason the present scavenger functions to make the composition shelf stable is that they absorb free and end-capped hydroxy groups so that they cannot hydrolyze to cross-link and degrade the basic polyalkoxydiorganopolysiloxane polymer. If such cross-linking and hydrolysis does not occur, then the composition is shelf stable. If it does occur, and depending to the extent that it does occur, then the polymer will not only have poor shelf stability, it will not be very fast curing when it does eventually cure after it has been stored for some time such as a month or more. The use of the silane scavenger substantially eliminates undesirable water in the filler and silicone polymer, as well as residual moisture in the RTV composition during the shelf period. In determining what level of silane scavenger to use in the practice of the invention, the total hydroxy functionality of the RTV composition can be estimated. The total hydroxy functionality of the polymer can be determined by infrared analysis. In order to insure that an effective or stabilizing amount of scavenger is used to maintain the stability of the composition over an extended shelf period of six months or more at ambient temperature while in a sealed container, there can be used an additional amount of scavenger over that amount required to endstop the polymer. This excess of scavenger can be up to about 3% by weight, based on the weight of the polymer. The aforementioned 3% of scavenger by weight exceeds that amount required to substantially eliminate available hydroxy functionality in the polymer as a result of reaction between OH functionality and X radicals. In compositions which also contain filler and other additives, the additional amount of scavenger of Formulas (3) or (5) which is required is estimated by running a 48-hour stability check at 100 C. to determine whether the tack-free time remains substantially unchanged as compared to the tack-free time of the composition before aging measured under substantially the same conditions. In Formulas (1-3), R is preferably selected from C (1-13) monovalent hydrocarbon radicals, halogenated hydrocarbon radicals and cyano alkyl radicals, R¹ is preferably a C (1-8) alkyl radical or a C (7-13) aralkyl radical, R² is preferably methyl, phenyl, or vinyl. As disclosed in EP-A-0 069 256, additional amounts of amines and guanidines can be present as cure accelerators. Such amines and cure accelerators may be utilized with advantage to increase the cure rate with the compositions of the present invention, especially with the hydride amines of the present case. However, while such is desirable it is not strictly necessary and the scavengers of the present invention will substantially maintain the shelf-stability of the composition and maintain the cure rate of the composition if they are utilized in the quantities indicated above. It has been further found that improved cure rates can be achieved it minor amounts of amines, substituted guanidines, or mixtures thereof, are utilized as curing accelerators in the silanol compositions of the present invention. There can be used from 0.1 to 5 parts, and preferably from about .3 to 1 part of curing accelerator, per 100 parts of the silanol-terminated polymer of Formula (1), or which consists of chemically combined units of Formula (2), to substantially reduce the tack-free time (TFT) of the RTV composition of the present invention. This enhanced cure rate is maintained after it has been aged for an extended shelf period, for example, 6 months or more at ambient temperatures, or a comparable period under accelerated aging conditions. Its cure properties after the extended shelf period will be substantially similar to its initial cure properties, for example, tack-free time (TFT), shown by the RTV composition upon being freshly mixed and immediately exposed to atmospheric moisture. It appears that the curing accelerators described herein, in addition to decreasing the tack-free times of the RTV compositions of this invention, also provide a surprising stabilizing effect for particular RTV compositions catalyzed with certain condensation catalysts which exhibit a marked lengthening of tack-free time after accelerated aging. For this class of condensation catalysts, addition of amines, substituted guanidines and mixtures thereof described herein provide stable RTV compositions which exhibit a fast cure rate initially, that is less than about 30 minutes which remains substantially unchanged after accelerated aging. The RTV compositions of the present invention can cure to a depth of about 3mm (1/8") thickness within 24 hours. Durometer Hardness (Shore A) can then be determined and used to evaluate the cure of the compositions as shown in the examples. In an additional aspect of the present invention, there is provided a method of making a stable, one-package room temperature vulcanizable organo-polysiloxane composition which comprises agitating, under substantially anhydrous conditions, a room temperature vulcanizable material selected from (i) a mixture comprising on a weight basis (a) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of Formula (2), (b) 1 to 10 parts of the cross-linking silane of Formula (3), (c) 0 to 5 parts of curing accelerator selected from substituted guanidines, amines and mixtures thereof wherein, the condensation catalyst is added after the silanol-terminated polydiorganosiloxane and cross-linking silane are mixed, (d) an amount of silyl-nitrogen materials of the above formulas sufficient to scavenge available -OH in the RTV composition and provide up to 3% by weight excess, based on the weight of RTV composition, (e) an effective amount of a condensation catalyst. Radicals included within R of Formulas (1), (2) and (6) are, for example, aryl radicals and halogenated aryl radicals, such as phenyl, tolyl, chlorophenyl, naphthyl; aliphatic and cycloaliphatic radicals, for example, cyclohexyl, cyclobutyl; alkyl and alkenyl radicals, such as methyl, ethyl, propyl, chloropropyl, vinyl, allyl, trifluoropropyl: and cyanoalkyl radicals, for example, cyanoethyl, cyanopropyl, cyanobutyl. Radicals preferably included within R¹ are, for example, C (1-8) alkyl radicals, for example, methyl,- ethyl-, propyl, butyl, pentyl; C (7-13) aralkyl radicals, for example, benzyl; phenethyl; alkylether radicals such as 2-methoxyethyl; alkylester radicals, for example 2-acetoxyethyl; alkylketone radicals, for example 1-butan-3-onyl; alkylcyano radicals, for example 2-cyanoethyl. Radicals included within R² are the same or different radicals included within R radicals. In Formulas (1-3), where R, R¹, and R², can be more than 1 radical, these radicals can be the same or different. Some of the cross-linking polyalkoxysilanes included within Formula (3) are, for example, methyltrimethoxysilane; methyltriethoxysilane; ethyltrimethoxysilane; tetraethoxysilane; vinyltrimethoxysilane; etc. Among the curing accelerators which can be used in the practice of the invention are silyl substituted guanidines having the formula (Z) g Si(OR¹) 4-g (5) where R¹ is as previously defined, Z is a guanidine radical of the formula, R³ is divalent C (2-8) alkylene radical, R⁴ and R⁵ are selected from hydrogen and C (1-8) alkyl radicals and g is an integer equal to 1 to 3 inclusive. In addition, alkyl substituted guanidines having the formula where R⁴ and R⁵ are as previously defined and R⁶ is a C (1-8) alkyl radical, also can be employed. Some of the silyl substituted guanidines included within Formula (5) are shown by Takago, U.S. Patents 4,180,642 and 4,248,993. In addition to the above substituted guanidines, there can be used various amines, for example, di-n-hexylamine, dicylohexylamine, di-n-octylamine, hexamethoxymethylmelamine, and silylated amines, for example, γ-amiopropyltrimethoxysilane and methyldimethoxy-di-n-hexylaminosilane. Methyldimethoxy-di-n-hexylaminosilane acts as both a scavenger and curing accelerator. The primary amines, secondary amines, silylated secondary amines are preferred, and secondary amines, and silylated secondary amines are particularly preferred. Silylated secondary amines such as alkyldialkoxy-n-dialkylaminosilanes and guanidines such as alkyldialkoxyalkylganidylsilanes which are useful as cure accelerators herein also act as scavengers and, in certain instances, as stabilizers in the compositions of this invention. The silanol-terminated diorganopolysiloxane of Formula (1) are well known to a worker skilled in the art and can be produced by various methods as disclosed in Lampe et al., U.S. Patent 3,888,815. Effective amounts of the condensation catalysts which can be used in the practice of the present invention to facilitate the cure of the RTV compositions are, for example, 0.001 to 1 part based on the weight of 100 parts of the silanol-terminated polydiorganosiloxane of Formula (1). There are included tin compounds, for example dibutyltindilaurate; dibutyltindiacetate; dibutyltindimethoxide; carbomethoxyphenyl tin tris-uberate; tin octoate; isobutyl tin triceroate; dimethyl tin dibutyrate; dimethyl di-neodeconoate; triethyl tin tartrate; dibutyl tin dibenzoate; tin oleate; tin naphthenate; butyltintri-2-ethylhexoate; tinbutyrate. The preferred condensation catalysts are tin compounds and dibutyltindiacetate is particularly preferred. Titanium compounds which can be used are, for example, 1,3-propanedioxytitanium bis(ethylacetoacetate); 1,3-propanedioxytitanium bis(acetylacetonate); diisopropoxytitanium bis(acetylacetonate); titanium naphthenate; tetrabutyltitanate; tetra-2-ethylhexyltitanate; tetraphenyltitanate; tetraoctadecyltitanate; ethyltriethanolaminetitanate. In addition beta-dicarbonyltitanium compounds as shown by Weyenberg U.S. Patent 3,334,067 can be used as condensation catalysts in the present invention. Zirconium compounds, for example, zirconium octoate, also can be used. Further examples of metal condensation catalysts are, for example, lead 2-ethylhexoate; iron 2-ethylhexoate: cobalt 2-ethylhexoate; manganese 2-ethylhexoate; zinc 2-ethylhexoate; antimony octoate; bismuth naphthenate; zinc naphthenate; zinc stearate. Examples of nonmetal condensation catalysts are hexylammonium acetate and benzyltrimethylammonium acetate. Various fillers and pigments can be incorporated in the silanol-terminated organopolysiloxane, such as for example, titanium dioxide, zirconium silicate, silica aerogel, iron oxide, diatomaceous earth, fined silica, carbon black, precipitated silica, glass fibers, polyvinyl chloride, ground quartz, calcium carbonate, etc. The amounts of filler used can obviously be varied within wide limits in accordance with the intended use. For example, in some sealant applications, the curable compositions of the present invention can be used free of filler. In other applications, such as employment of the curable compositions for making binding material on a weight basis, as much as 700 parts or more of filler, per 100 parts of organopolysiloxane can be employed. In such applications, the filler can consist of a major amount of extending materials, such as ground quartz, polyvinylchloride, or mixtures thereof, preferably having an average particle size in the range of from about 1 to 10 microns. The compositions of the present invention also can be employed as construction sealants and caulking compounds. The exact amount of filler, therefore, will depend upon such factors as the application for which the organopolysiloxane composition is intended, the type of filler utilized (that is, the density of the filler and its particle size). Preferably, a proportion of from 10 to 300 parts of filler, which can include up to about 35 parts of a reinforcing filler, such as fumed silica filler, per 100 parts of silanol-terminated organopolysiloxane is utilized. In the practice of the invention, the room temperature vulcanizable compositions can be made by agitating, for example stirring, a mixture of materials which can consist of the silanol terminated polydiorganosiloxane, which hereinafter will include Formula (1) or polymer consisting essentially of Formula (2) units along with the cross-linking silane of the above Formula (3), where the blending is performed in the substantial absence of atmospheric moisture. Thereafter the condensation catalyst and scavenging silane of the above formula is added also in the substantial absence of atmospheric moisture. As used hereinafter, the expressions "moisture-free conditions" and "substantially anhydrous conditions," with reference to making the RTV compositions of the present invention, mean mixing in a dry box, or in a closed container which has been subjected to vacuum to remove air, which thereafter is replaced with a dry inert gas, such as nitrogen. Experience has shown that sufficient scavenging silane of the above formulas should be utilized as previously defined. Temperatures can vary from about 0°C. to about 180°C. depending upon the degree of blending, the type and amount of filler. A preferred procedure for making the RTV composition of the present invention is to agitate under substantially anhydrous conditions, a mixture of the silanol terminated polydiorganosiloxane filler and an effective amount of the cross-linking silane sufficient to effect the substantial elimination of hydroxy functional radicals and to endcap the polymer. This "endcapping" procedure can require several minutes, hours, or even days, depending upon such factors as the nature of the X leaving group, the number of -OR¹ radicals on the cross-linking silane, etc. There can be added to the substantially silanol-free mixture, the condensation catalyst, the scavenging silane, or mixture thereof, along with other ingredients, for example, the curing accelerator and pigments. A stabilizing excess of the scavenging silane is used in the final stages of the mixing procedure in amounts previously defined. Irrespective of the above methods for making the instant RTV compositions, the preferred method for making the instant RTV compositions is to react the base silanol polymer of Formula (1) with the cross-linking agent of Formula (3) in the presence of an amine condensation catalyst as disclosed in the foregoing Cooper et al., U.S. Patent 3,542,901. The preferred amine catalyst which can be utilized for this purpose is, for instance, di-n-hexylamine. Once the polyalkoxy-terminated diorganopolysiloxane polymer is formed, then there can be added the scavenger in the foregoing quantitites indicated above and the other additives that are added to the composition such as fillers, self-bonding additives, etc. The scavenger will react with free hydroxy groups to substantially remove and endcap them so that they cannot degrade the polyalkoxy base polymer. Accordingly, the cure rate and the shelf stability of the composition will be maintained. The silazanes of the instant case are preferred over other scavenging compounds disclosed in the above formulas, since all of them are known compounds and the simplest ones are readily available to silicone manufacturers. Further, they do not impart objectionable odor to the composition and they are of relatively low cost to make. They also are very efficient water and methanol absorbers and will make the composition shelf stable and fast-curing even after it has been stored for a substantial period of time such as six months, one year, or more. There may be added various other additives to the above basic composition such as the adhesion promoters of DE-A-33 05 356. Further, the composition, in addition to self-bonding can be made low modulus, with advantageous physical properties as disclosed in the foregoing DE-A. However, the instant scavengers may be utilized with any of the basic compositions disclosed in EP-A-0 069 256. The only compositions that are disclosed in said EP-A that cannot be utilized in the instant case are compositions in which the scavenger and cross-linking agent is the same compound; that is, when a cross-linking agent has functionality in addition to alkoxy-functionality. In accordance with the instant invention, the scavenger of the instant case are additional compounds in addition to the cross-linking agents. It would be very difficult if not impossible to include the silicon-nitrogen functionality disclosed by the above formulas in the same compound. Accordingly, in the present case the scavenger compound is one of the compounds in the formulas shown above and is preferably a silazane compound which is a different compound from the cross-linking agent and which is preferably added after the polyalkoxy-terminated diorganopolysiloxane base polymer is formed. The examples below are given for purposes of illustrating the present invention. They are not given for any purpose of setting limits and boundaries to the instant invention. All parts are by weight. Example 1 To 100 parts of methyldimethoxy endcapped dimethylpolysiloxane polymer of 2500 mPa·s (centipoise) viscosity at 25°C. containing .6% by weight of di-n-hexylamine was added 15 parts of cyclo-octamethyltetrasiloxane treated fumed silica to give a base composition. To this base composition there was added various catalyst compositions. The compositions of such catalysts (A) (B) and (C) are as follows: Catalyst A contained 0.5 or 1.0 parts of bis(dimethylamino)methylvinylsilane (A) along with 0.23 parts of dibutyl tin diacetate per 100 parts of base compound and 4.37 parts of a 100 mPa·s (centipoise), at 25°C, trimethylsilyl stopped polydimethylsiloxane fluid per 100 parts of base compound. Catalyst B contained 1.0 or 1.5 parts of methyl tris(dimethylamino)silane (B) per 100 parts of base compound along with 0.23 parts of dibutyl tin diacetate per 100 parts of base compound and 4.37 parts of a 100 mPa·s (centipoise), at 25°C, trimethylsiloxy endstopped fluid per 100 parts of base compound. Catalyst C contained 1.0 or 1.5 parts of dimethylaminotrimethylsilane (C) per 100 parts of base compound along with 0.23 parts of dibutyltin diacetate per 100 parts of base compound and 4.37 parts of a 100 mPa·s (centipoise), at 25°C., trimethylsiloxy endstopped fluid per 100 parts of base compound. Following the mixing, the material was placed in sealed metal tubes and stored at 100°C. Periodically the tubes were removed and checked for tack-free time (TFT) at 25 ± 3°C (77° ± 5°F) and 50 ± 5% relative humidity. Table I lists the results. Formulation Initial (TFT) Min.) 24 hrs. 100°C. 48 hrs. 100°C. Parts A/100 pts. base 0.5 25 gelled ----- 1.5 30 30 30 Parts B/100 pts. base 1.0 25 20 gelled 1.5 25 15 20 Parts C/100 pts. base 1.0 25 No Cure ----- 1.5 25 25 20 As the results of Table I indicate, the amino silanes impart good shelf stability to the alkoxy-functional one-component RTV system. Example 2 Hexamethyldisilazane offers the advantage of being readily available and since it is difunctional with respect to nitrogen can react with two equivalents of chemically combined hydroxy groups to generate one equivalent of by-product. Thus less amine by-product is generated per given amount of methanol, water, or silanol scavenged. In addition, such silazane is desirable as a scavenger since the odor it imparts to the RTV composition is a slight odor of ammonia. To 100 parts of methyldimethoxy stopped polydimethylsiloxane polymer of 150,000 mPa·s (centipoise) at 25°C. containing .6% by weight of di-n-hexylamine as a result by which it was made, there was added 16 parts of an octamethylcyclotetrasiloxane (D₄) treated fumed silica filler along with 10 parts of a trifunctional fluid, containing 20 mole percent of monomethylsiloxy units, 76 mole percent of dimethylsiloxy units and 4 mole percent of trimethylsiloxy units. In the base composition there was also added 20 parts of a trimethylsiloxy endstop dimethylpolysiloxane polymer having a 100 mPa·s (centipoise) viscosity at 25°C. To 100 parts of this base composition there was added various amounts of hexamethyldisilazane shown in Table II below along with .76 parts of a trimethylsiloxy endstop dimethylpolysiloxane polymer fluid having a 100 mPa·s (centipoise) viscosity at 25°C. This mixture was stirred for fifteen minutes at which time 4.6 parts of a 5% solution of dibutyltindiacetate in a trimethylsiloxy endstop dimethylpolysiloxane fluid having 100 mPa·s (centipoise) viscosity at 25°C. was added to produce the RTV system. All the trimethylsiloxy endstop dimethylpolysiloxane fluids disclosed above have a silanol content of anywhere from 500 to 1500 parts per million as a result of the manner in which they were made. Further, in these examples, the tack-free time of the samples was tested initially and after accelerated aging. The tack-free time is a measure of the shelf stability and the curing ability of the polymer initially and after it has been aged. The tack-free time test is carried out as follows. A sample of the RTV is placed on a clean dry surface to a depth of about 6 mm (about 0,25 inch) and exposed to an atmosphere of 25 ± 3°C (77 ± 5°F.) and 50 ± 5% relative humidity. The tack-free time is the time required for the surface to become tack-free to a light touch of the finger. The results are set forth in Table II below. Hexamethyldisilazane (HMDZ) as Scavenger Formulation Initial TFT (Min.) Useful Range 24 hrs. 100°C. 72 hrs. 100°C. Parts HMDZ/pts. base 0.3 45 55 gelled 0.5-5.0 0.67 45 55 25 As the results of Table II indicate, hexamethyldisilazane even in low concentrations produces a shelf-stable composition, that is while at .33 parts per 100 parts of base it is ineffective, at .67 parts it produced a substantially shelf-stable composition. Such materials may be utilized at a concentration as stated previously of anywhere from 0.5 to 10 parts and more preferably from .5 to 5 parts per 100 parts of diorganopolysiloxane base polymer, and those amounts impart to the RTV composition and particularly, to the polydiorganopolysiloxane polymer shelf stability and good curing properties. Example 3 To 100 parts of a methyldimethoxy stopped polydimethylsiloxane polymer of 150,000 mPa·s (centipoise) at 25°C. containing 0.6% by weight of di-n-hexylamine was added 15 parts of a cyclotetrasiloxane treated silica filler to make an RTV base. To 100 parts of this base was added 7.8 parts of a solution containing 1.2 parts of hexamethyldisilizane, 2 parts of methyltrimethoxy silane and 4.6 parts of a 5% solution of dibutyltindiacetate in a 100 mPa·s (centipoise) trimethylsiloxy endstopped fluid. Following the mixing, the material was placed in sealed metal tubes and stored at 100°C. Periodically the tubes were removed, cooled and checked for tack-free time at 25 ± 3°C (77 ± 5°F.) and 50 ± 5% relative humidity. Table III lists the results. Tack-free Time vs. Time at 100°C. Time at 100°C. (hrs.) TFT (Min.) 0 40 24 40 48 25 Example 4 A base was prepared as in Example 2. To 100 parts of the base was added 3 parts of a solution containing 1 part of methyltrimethoxysilane and 2 parts of hexamethyl disilazane. Immediately after mixing, 2 parts of a second solution was added containing 1 part of aminoethylaminopropyltrimethoxy silane and 1 part of a 23 percent solution of dibutyl tin diacetate in a 50 mPa·s (centipoise), at 25 °C. trimethylsiloxy endstopped dimethylpolysiloxane fluid. Again, this material was aged at 100°C. in sealed metal tubes and periodically removed, cooled and tested for tack free time at 25 ± 3°C (77 ± 5°F.) and 50 ± 5% relative humidity. Table IV lists the results. Tack-free Time vs. Time at 100°C. Time at 100°C.(hrs.) TFT (min.) 0 10 24 10 48 10 Example 5 To 100 parts of a methyldimethoxy stopped polydimethylsiloxane polymer of 150,000 mPa·s (centipoise) at 25°C. containing 0.6 percent by weight di-n-hexylamine was added: 160 parts of a stearic acid treated calcium carbonate filler, 3 parts of a cyclotetrasiloxane treated fumed silica filler: 35 parts of a 100 mPa·s (centipoise) trimethylsiloxy dimethylpolysiloxane endstopped fluid containing 500-1500 ppm silanol; 10 parts of a trifunctional fluid containing 20 mole percent of monomethylsiloxy units, 76 mole percent dimethylsiloxy units, and 4 mole percent trimethylsiloxy units; and 0.2 parts of a trimethylolpropane propylene glycol ether to form a base compound. To 100 parts of this base compound was added 4.075 parts of a catalyst solution containing 2.5 parts of a hexamethyldisilazane, 0.5 parts of methyltrimethoxy silane, 1 part of aminoethylaminopropyltrimethoxy silane and 0.075 parts of dibutyltindiacetate. The results are in Table V below. Tack-free Time vs. Time at 100°C. Time at 100°C. (hrs.) TFT (Min.) 0 20 24 45 48 45 Example 6 There was prepared a Base Composition X comprising 100 parts of a mixture A having in it 100 parts of a silanol-terminated dimethylpolysiloxane polymer having a viscosity of 150,000 mPa·s (centipoise) at 25°C.; 160 parts of stearic acid treated calcium carbonate sold under the name Hydrocarb 95T which is the trade name of OMYA, Inc. of Proctor, Vermont; 10 parts of a highly trifunctional polysiloxane fluid containing 20 mole percent of mono-methylsiloxy units, 76 mole percent of dimethylsiloxane units and 4 mole percent of trimethylsiloxy units, and having a silanol content of .5 weight percent silanol; 35 parts of a trimethylsiloxy terminated dimethylpolysiloxane linear fluid having a viscosity of 100 mPa·s (centipoise) at 25°C. and 3 parts of octacyclotetrasiloxane treated fumed silica having a surface area of 200 meters square per gram. To 100 parts of this mixture A there was added .2 parts of acetic acid, .4 parts of di-n-hexylamine and 2.7 parts of methyltrimethoxysilane. The mixing was carried out under substantially anhydrous conditions. The resulting Composition X, once formed, was heated at 110°C. for fifteen minutes under substantially anhydrous conditions to form the polyalkoxy-terminated dimethylpolysiloxane linear polymer having a viscosity of about 150,000 mPa·s (centipoise) at 25°C. To this base Composition X there was added under substantially anhydrous conditions 1.0 parts of aminoethylaminopropyltrimethoxysilane as the adhesion promoter, .3 parts of dibutyl tin diacetate and 2.7 parts of a silazane derivative identified in Table VI below. Table VI below indicates the tack-free time of the composition after the composition was cured for 24 hours at room temperature and after it had been accelerated heat-aged at 100°C. for 72 hours. There is also indicated the Short A, Durometer, the percent Elongation and the Tensile Strength of the samples in Table VI. As the results in Table VI indicate, the cyclic trisilazane was considerably superior in shelf stability to the hexamethylsilazane. Example 7 There was prepared a base Composition Z comprising 100 parts by weight of a dimethoxymethylsilyl-terminated polydimethylsiloxane polymer having a viscosity of 150,000 mPa·s (centipoise) at 25°C. which had in it .5 parts of di-n-hexylamine as a condensation catalyst. To this mixture, there was added 220 parts of the stearic acid treated calcium carbonate of Example 6; 2.5 parts of carbon black; 35 parts of a trimethylsiloxy-terminated dimethylpolysiloxane polymer having a viscosity of 100 mPa·s (centipoise) at 25°C., 10 parts by weight of a highly trifunctional fluid containing 3 mole percent of trimethylsiloxy mono-functional units, 20 mole percent of methylsiloxy tri-functional units, and 77 mole percent of dimethyl difunctional siloxy units having a silanol content of .5 weight percent and a viscosity of 50 mPa·s (centipoise) at 25°C. To this there was added .2 parts of a thixotrope which is a polyether sold under the trade name UCON-1145 by Union Carbide Corporation, Connecticut. The above base Composition Z was mixed under substantially anhydrous conditions. To 100 parts of this base Composition Z there was added the various ingredients in the amounts indicated in Table VII below under substantially anhydrous conditions. The cyclotrisilazane had the same formula as the silazane cyclotrisilazane in Example 6 above. Sample A Sample B Base Composition Z 100 100 Methyltrimethoxysilane 0.5 0.5 Aminoethylaminopropyltrimethoxysilane 1.0 1.0 Dibutyltindiacetate 0.07 0.07 Hexamethyldisilazane 2.5 --- Silazane Trimer --- 2.5 The physical properties of the A column mixture of Table VII and the B column mixture of Table VII are indicated in Table VIII below. There is given below in Table VIII both the physical properties and the tack-free time after the sample had been cured for 24 hours at room temperature and after accelerated aging for 48 hours at 100°C. The results are set forth in Table VIII below. Sample A Sample B Tack-free time, minutes 12 17 Shore A, hardness 30 30 Tensile Strength, N/mm²(psi) 1,25(179) 1,23(175) Elongation, % 380 275 50% modulus, N/mm²(psi) 0,44(63) 0,48(68) 75% modulus, N/mm²(psi) 0,53(76) 0,55(79) 100% modulus, N/mm²(psi) 0,62(89) 0,64(92) Accelerated Aging 48 hrs./100°C. Shore A, hardness 36 38 Tensile Strength, N/mm²(psi) 1,85(264) 1,63(233) Elongation, % 330 310 50% modulus N/mm²(psi) 0,49(70) 0,52(74) 75% modulus N/mm²(psi) 0,64(91) 0,65(93) 100% modulus N/mm²(psi) 0,79(113) 0,78(111) In Table VIII the 50%, 75% and 100% Modulus is the Modulus of the sample at those present elongations of the samples. As the data in Table VIII indicates, samples A and B had comparable physical properties. However, the cyclic silazanes generally is hypothesized and more specifically it is known that the cyclic trisilazane has two main advantages over the linear hexamethyldisilazane. Thus, the hexamethyldisilazane appears to inhibit the cure of the composition when the total RTV composition is applied to a high moisture-containing surface such as moist concrete, cement, or other masonry surfaces. This inhibition may also be experienced under high-temperature, high-humidity atmospheric conditions. Accordingly, under those conditions when the RTV composition is to be used, it is desirable that the scavenger in the system be a cyclic silazane, specifically a cyclic trisilazane or cyclictetrasilazane or that there be at least some cyclicsilazane in the composition. The other advantage of the cyclic silazanes over the linear silazanes that has been noticed at least with the cyclictrisilazane is that the modulus of the cured composition does not vary with the thickness of the layer of the cured RTV composition. On the other hand, with linear silazanes and specifically with hexamethyldisilazane it has been noted the thicker the section of the RTV composition, the lower the modulus and the thinner the layer of RTV composition that is applied, the higher the modulus of the cured composition. Accordingly, if this variation is a factor, then the cyclictrisilazanes should be present at least in some quantities as a scavenger in the RTV compositions of the present case. In all other cases, it appears the linear silazanes and the cyclicsilazanes behave in similar manners to give the composition the properties that have been specified above.

Claims: A method of making a one-package and substantially acid-free room temperature vulcanizable composition curable to the solid elastomeric state, which method comprises agitating under substantially anhydrous conditions at a temperature in the range of from 0°C to 180°C, a room temperature vulcanizable material selected from a mixture comprising (A) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula (2) (B) from 1 to 10 parts of an alkoxy-functional cross-linking silane of the formula (3) (C) optionally 0,1 to 5 parts of a curing accelerator selected from substituted guanidines, amines and mixtures thereof, and (D) a stabilizing amount of silane scavenger for hydroxy functional groups, selected from a silicon-nitrogen compound having the formula where Y is selected from R''' and R''₂N― and a silicon-nitrogen polymer comprising (1) from 3 to 100 mole percent chemically combined structural units selected from units having the formula and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula and mixtures thereof, where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and an SiNR''Si linkage, the free valences of said silicone atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silazy unit are joined to a member selected from an R'' radical and (R'')₂N radical, and where the ratio of the sum of said R''' radicals and said (R'')₂N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, and R'' is a member selected from hydrogen and monovalent hydrocarbon radicals, and fluoroalkyl radicals, R''' is a member selected from hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive, (E) an effective amount of a condensation catalyst, where R is selected front C (1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R¹ is a C (1-8) aliphatic organic radical selected from alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals, or a C (7-13) alkaryl radical, R² is a C (1-13) monovalent substituted or unsubstituted hydrocarbon radical, where the curing accelerator (C) is added before or with the scavenger (D). The method of claim 1 where there is present from .5 to 10 parts by weight of the silicon scavenger per 100 parts by weight of the organopolysiloxane. The method of claim 1 wherein the silazane polymers include cyclic silazanes of chemically combined units, where R'', R''' are as previously defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silazane polymer. The method of claim 1 wherein the silazane polymer comprises linear polymers having at least one unit selected from units and units where R'', R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said polymer. The method of claim 1 wherein the silazane polymers comprise linear polymers consisting essentially of units where R'' and R''' are as defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and (R'')₂N radicals per silicone atom in said polymer. The method of claim 1 wherein the silazane polymers comprise polymers having at least one unit selected from units and units where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said polymer. The method of claim 1 wherein the silazane polymer is a polymer having units selected from where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silicon polymer. The method of claim 1 wherein the nitrogen-siloxane compounds are copolymers with up to 97 mole percent of units and units selected from where R'' and R''' and c are as previously defined to provide for a ratio of the sun, of R''' + (R'')₂N radicals per silicon atom of said silazane-siloxane copolymer of from 1.5 to 3. The method of claim 1 wherein the nitrogen-siloxane compounds are cyclics consisting of chemically combined (R''')₂SiO units and units where R'' and R''' are as previously defined. The method of claim 1 wherein the silazane-siloxane compounds are linear and cyclic silazanes having the formula where R'' and R''' are as previously defined, where n is a positive whole number and is 0 to 20, inclusive, and d is a whole number equal to 0 or 1, and where d is equal to 0, n is equal to 3 to 7, inclusive. The method of claim 1 wherein the silazane-siloxane compound is a polysiloxane having the formula where R'', R''' and n are as defined previously and Z is a member selected from R'' and ―Si(R'''). The method of claim 1, 2 or 3 wherein the silicon-nitrogen compound is hexamethyldisilazane. The method of claim 1 wherein the silicon-nitrogen compound is octamethylcyclotetrasilazane. The method of claim 1 wherein the silicon-nitrogen compound has the formula [CF₃ CH₂ CH₂ (CH₃)₂ Si]₂ NH. The method of claim 1 wherein the silicon-nitrogen compound has the formula [CF₃ CH₂ CH₂ (CH₃)SiNH]₃. The method of claim 1 wherein the silicon-nitrogen compound is [CF₃ CH₂ CH₂ (CH₃)₂ Si]₂N-CH₃. A method in accordance with claim 1 or 2, where the silane scavenger is hexamethylcyclotrisilazane. A method in accordance with claim 2 wherein the silane scavenger is hexamethyldisilazane and the cross-linking silane (B) is methyltrimethoxysilane. A method of making a one-package and substantially acid-free room temperature vulcanizable composition curable to the solid elastomeric state, which method comprises agitating under substantially anhydrous conditions at a temperature in the range of from 0°C to 180°C, a room temperature vulcanizable mixture comprising: (A) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula (B) 1 to 10 parts of cross-linking silane of the formula (C) optionally 0,1 to 5 parts of a curing accelerator selected from substituted guanidines, amines and mixtures thereof; and (D) a stabilizing amount of a silane scavenger for hydroxy functional groups which is a silyl amine of the formula where R'' is a radical selected from hydrogen, C (1-8) monovalent hydrocarbon radicals, R²⁰ is selected from C (1-8) monovalent hydrocarbon radicals, C (1-8) alkoxy radicals and fluoroalkyl radicals and g is a whole number that varies from 1 to 3, h is a whole number that varies from 0 to 2 and the sum of g + h does not exceed 3; and (E) an effective amount of a condensation catalyst, where R is selected from C (1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R¹ is a C (1-8) aliphatic organic radical selected from alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals, or a C (7-13) alkaryl radical, R² is a C (1-13) monovalent substituted or unsubstituted hydrocarbon radical, b is a whole number equal to 0 or 1, where the curing accelerator (C) is added before or with the scavenger(D). The method of claim 19 adding to the organopolysiloxane mixture a stabilizing amount of the silyl amine (D) and thereafter adding the effective amount of condensation catalyst. A method in accordance with claim 1, 19 or 20 using an effective amount of dibutyltindiacetate as the condensation catalyst. The method of claim 19 or 20, wherein the silicon scavenger is methyl di(methylamino)silane. The method of claim 19 or 20, wherein the silane scavenger is tris(methylamino)silane. The method of claim 19 or 20, wherein the silane scavenger is methyl bis(diethylamino)silane. A method in accordance with claim 1 or 19, where R, R¹ and R² are methyl. A method in accordance with claim 1 or 19, where the curing accelerator is selected from silylated guanidine and alkyl guanidine. A method in accordance with claim 1 or 19, where the cross-linking silane is methyltrimethoxysilene. A method in accordance with claim 1 or 19, where the condensation catalyst is a tin compound. A mixture comprising (A) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula (2) (B) 1 to 10 parts of a cross-linking silane of the formula (3). (C) optionally 0,1 to 5 parts of a curing accelerator selected from substituted guanidines, amines and mixtures thereof, (D) a stabilizing amount of a silane scavenger for hydroxy functional groups selected from a silicon-nitrogen compound having the formula where Y is selected from R''' and R''₂N― and a silicon-nitrogen polymer comprising (1) from 3 to 100 mole percent chemically combined structural units selected from units having the formula and (2) from 0 to 97 mole percent chemically combined structural units represented by the formula and mixtures thereof where the silicon atoms of said silicon-nitrogen polymer are joined to each other by a member selected from an SiOSi linkage and a SiNR''Si linkage, the free valances of said silicon atoms other than those joined to oxygen to form a siloxy unit and nitrogen to form a silazy unit are joined to a member selected from an R'' radical and (R'')₂N radical, and where the ratio of the sum of said R''' radicals and said (R'')₂N radicals to the silicon atoms of said silicon-nitrogen polymer has a value of 1.5 to 3, inclusive, where R'' is a member selected from hydrogen and monovalent hydrocarbon radicals, and fluoroalkyl, R''' is a member selected from hydrogen, monovalent hydrocarbon radicals and fluoroalkyl radicals, and c is a whole number equal to 0 to 3, inclusive, and (E) an effective amount of a condensation catalyst, and where R is selected from C (1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R¹ is a C (1-8) aliphatic organic radical selected from alkyl, alkylether, alkylester, alkylketone and alkylcyano radicals, or a C (7-13) aralkyl radical, R² is a C (1-13) monovalent substituted or unsubstituted hydrocarbon radical, b is a whole number equal to 0 or 1. The composition of Claim 29,wherein there is present from 0,5 to 10 parts by weight of the silicone scavenger per 100 parts by weight of the organopolysiloxane. The composition of Claim 29, wherein the silazane polymers include cyclic silazanes of chemically combined units where R'', R''' are as previously defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silazane polymer. The composition of Claim 29, wherein the silazane polymer is a linear polymer having at least one unit selected from units and units where R'', R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silazane polymer. The composition of Claim 29, wherein the silazane polymer is a linear polymer consisting essentially of units where R'' and R''' are defined to provide for a ratio of 1.5 to 3.0 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silicone polymer. The composition of Claim 29, wherein the silazane polymer is a polymer having at least one unit selected from units and units where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silazane polymer. The composition of Claim 29, wherein the silazane polymer is a polymer having units selected from where R'' and R''' are as previously defined to provide for a ratio of 1.5 to 3 of the sum of the R''' and (R'')₂N radicals per silicon atom in said silazane polymer. The composition of Claim 29, wherein the silizane compounds are copolymers with up to 97 mole percent of units and units selected from where R'' and R''' and c are as previously defined to provide for a ratio of the sum of R''' + (R'')₂N radicals per silicon atom of said siloxane copolymer of from 1.5 to 3. The composition of Claim 29, wherein the siloxane compounds are cyclics consisting of chemically combined (R''')₂SiO units and units where R'' and R''' are as previously defined. The composition of Claim 29, wherein the silicon nitrogen compounds are linear and cyclic silazanes having the formula where R'' and R''' are as previously defined where n is a positive whole number and is 0 to 20, inclusive, and d is a whole number equal to 0 or 1, and where d is equal to 0, n is equal to 3 to 7, inclusive. The composition of Claim 29, where the silicon nitrogen compound is a polysiloxane having the formula where R'', R''' and n are as defined previously and Z is a number selected from R'' and ―Si(R''')₃. The composition of Claim 29, wherein the silicon nitrogen compound is hexamethyldisilazane. The composition of Claim 29, wherein the silicon nitrogen compound is hexamethylcyclotrisilazane. The composition of Claim 29, wherein the silicon-nitrogen compound is octamethylcyclotetrasilazane. The composition of Claim 29, wherein the silicon-nitrogen compound has the formula [CF₃ CH₂ CH₂ (CH₃)₂Si]₂ NH The composition of Claim 29, wherein the silicon-nitrogen compound has the formula [CF₃ CH₂ CH₂ (CH₃) Si NH]₃ The composition of Claim 29, wherein the silicon-nitrogen compound is [CF₃ CH₂ CH₂ (CH₃)₂Si]₂N-CH₃. A mixture comprising (i) 100 parts of a silanol-terminated polydiorganosiloxane consisting essentially of chemically combined units of the formula (ii) 1 to 10 parts of a cross-linking silane of the formula (iii) optionally 0,1 to 5 parts of a curing accelerator selected from substituted guanidines, amines and mixtures thereof, (iv) a stabilizing amount of a silane scavenger for hydroxy functional groups which is a silyl amine of the formula where R'' is a radical selected from hydrogen C (1-8) monovalent hydrocarbon radicals, R²⁰ is selected from C (1-8) monovalent hydrocarbon radicals C (1-8) alkoxy radicals and fluoroalkyl radicals, and g is a whole number that varies from 1 to 3, h is a whole number that varies from 0 to 2 and the sum of g + h does not exceed 3, (v) an effective amount of a condensation catalyst, and where R is selected from C (1-13) monovalent substituted or unsubstituted hydrocarbon radicals, R¹ is a C (1-8) aliphatic organic radical selected from alkyl, alkylether, alkylester, alkylketone, and alkylcyano radicals, or a C (1-13) aralkyl radical, R² is a C (1-13) monovalent substituted or unsubstituted hydrocarbon radical, b is a whole number equal to 0 or 1.

Inventors: DZIARK JOHN JOSEPH, DZIARK, JOHN JOSEPH
Applicants: GEN ELECTRIC, GENERAL ELECTRIC COMPANY
Application year: 1982
Main classification: C08L83
IPC codes: C08L83, C08K5