ADHESIVE COMPOSITIONS

Abstract: The random emulsion polymerisation product of a mixture of monomers in the presence of a chain transfer agent, in which the monomers comprise styrene, butadiene, α-methylstyrene and a copolymerisable carboxylic acid, has adhesive properties. It can be used as a single-component pressure-sensitive adhesive, e.g. as a coating on a suitable backing material.

Description: ADHESIVE COMPOSITIONS The invention relates to single component pressure-sensitive adhesive compositions based on styrene-butadiene containing polymers, and to products coated therewith. One major drawback of pressure-sensitive adhesive compositions based on styrene-butadiene containing polymers has been their poor adhesive strength upon application of pressure. The inability of these adhesives to readily flow and form a strong bond between materials during the short times for which pressure is applied limits the applications for which these adhesives can be empolyed. In particular, it was found that applications which require good adhesive strength and insensitivity to water, and yet require the adhesive to form a flexible bond, were foreclosed due to the inherent properties of the styrene-butadiene containing polymers available. Illustrative of the prior art are the following U. S. Patents, 3,535,153, 3,407,164, 4,102,835, 4,146,514 and 4,148,771. In these patents, it is pointed out that pressure-sensitive adhesives require a proper balance of the properties of tack, adhesive strength and cohesive strength. In order to improve this balance, styrene-butadiene-containing polymers in latex form have been compounded with emulsified tackifier resins. For example, U. S. Patent 4,189,419 teaches a pressure-sensitive adhesive composition comprising a tackifier and a carboxylated styrene-butadiene polymer. However, tackifier resins often are not compatible with the polymer, which condition leads to non-uniformity in bond strength of the adhesive. Furthermore, the combination of the emulsified tackifiers and latex may become unstable with time, and the adhesive may become ineffective at the temperatures at which the adhesive normally is used. Accordingly, there is a need for a pressure-sensitive adhesive where a strong yet flexible bond is desired as, for example, in bonding textiles in producing, say, disposable hospital bed-sheets. Such an adhesive also should be resistant to water and be capable of maintaining its adhesive and other physical properties for extended periods of time. Owing to the heat-sensitive nature of the substrates typically empolyed for these applications, the adhesive bonding should preferably be brought about at room temperatures. According to the present invention, an adhesive composition comprises the random emulsion polymerisation product of (i) a mixture of monomers comprising styrene, e.g., in an amount of from about 20 to about 58.9 parts by weight, butadiene, e.g. in an amount of from about 40 to about 78.9 parts by weight, a-methylstyrene, e.g. in an amount of from about 1 to about 5 parts by weight, and a carboxylic acid, e.g. from about 0.1 to about 5 parts by weight itaconic acid or methacrylic acid, or a mixture thereof;:and (ii) tertiary dodecyl mercaptan in an amount of from 1.35 to 1.55 parts by weight per 100 parts by weight of the mixture of monomers. These pressure-sensitive adhesive compositions can be considered as "single" component systems in that their excellent combination of properties is obtained without an added tackifier component. The peel strength properties, particularly, are comparable to the more expensive acrylic latices currently being used for the same application. As a feature of the invention, a novel and useful pressure-sensitive adhesive product is provided which comprises a backing material having the aforementioned adhesive composition coated thereon. These products exhibit a 900 peel strength of from about 2.5 to about 3.2 kN/m, when coated on a cotton backing and measured in an Instron machine at a cross-head speed of 5 cm/minute. Preparation of the emulsion polymerization product itself is effected in accordance with prior art procedures, e.g. the process described in Bovey et al. Emulsion Polymerization, 1955, Interscience Publishers, Inc., New York, P. 325. This book is incorporated by reference herein for its disclosure of typical processing conditions for the preparation of styrene-butadiene containing polymers. The compositions of the present invention differ from the teachings of this reference, however, in two important ways, first by the inclusion of the alpha-methyl styrene monomer constituent, within the range stated, and secondly by the inclusion of the stated range of tertiary dodecyl mercaptan, both of which improve the ability of the resulting compositions to flow at ambient temperatures under pressure, and both of which also improve the peel strength of the compositions making them specially adaptable for use as pressure-sensitive adhesives for fibrous materials, paper, wood, metal and plastics. The critical presence of the alpha-methyl styrene in providing a significant improvement in the peel strength and pressure-flow properties of pressure-sensitive adhesives is surprising and unexpected. While the amount of alpha-methyl styrene in the composition may vary, it is preferred to include from about 1 to about 5, more preferably from about 2 to about 3, parts by weight in the monomer mixture. For many pressure-sensitive adhesive applications, which are intended to be utilized under ambient temperature conditions, it has been found that levels of styrene of from about 20 to about 58.9 parts by weight, and levels of butadiene of from about 40 to about 78.9 parts by weight are preferred. Having styrene present above this preferred range will result in a less-flowing adhesive composition whereas having styrene present below this range will result in a composition having low peel strength. More preferably, styrene will be present in an amount of from about 35 to about 55 parts, and butadiene will be present in an amount of from about 43.9 to about 63.9 parts. In general, by varying the ratio of butadiene and styrene within these preferred ranges, pressure-sensitive adhesive compositions having different peel strengths, suitable for a variety of applications, are achieved. The polymerization mixture includes one or more copolymerizable carboxylic acids, in an amount which suitably ranges from about 0.1 to about 5 parts by weight, preferably from about 2 to about 3 parts by weight, of the monomer mixture. While any of the copolymerizable carboxylic acids known to the art for improving the adhesive and cohesive strength of styrene-butadiene containing polymers can be employed, it is preferred to employ itaconic or methacrylic acids or a mixture of both. To effect the desired random emulsion polymerization, it is necessary to include a chain transfer agent in the reaction mixture. Preferably, tertiary dodecyl mercaptan is used for this purpose. In the best mode, it is present in an amount of from about 1.35 to about 1.55 parts by weight per 100 parts by weight of the monomer mixture. As mentioned, the pressure-sensitive adhesive composition of the invention may be characterized as being a single component composition wherein the polymerization product itself functions as the adhesive. However, if desired, other ingredients may be added to the adhesive composition. For example, to improve the stability of the resulting compositions against degradation, additives known in the art for controlling various types of degradation e.g. UV stabilizers, antioxidants, etc., can be included in the final adhesive composition as desired. The following examples are presented for the purpose of further illustrating and explaining the present invention and are not to be taken as limiting in any regard. EXAMPLE 1 - TEST PROCEDURE A 0.1 mm Mylar film (18 cm x 18 cm) is coated uniformly with a 0.025 mm layer of Elmer's Glue and a cotton strip (18 cm x 18 cm) is placed on it immediately. The coated-cotton strip then is air-dried for 24 hours and then coated with the adhesive composition (1 mm draw-down bar), air dried for 20-24 hours at 24.4 + 1.1 C and 50 + 3% relative humidity, pressed in a Carver press with another cotton strip on top of the adhesive at room temperature at from 6.9 to 124 MPa in increments of 6.9 MPa, holding the strip at each increment for 5 seconds, and finally for 15 seconds at 124 MPa. Strips of 2.5 cm width are cut from the samples thus prepared and tested on an Instron for delamination (on the same day) at a cross-head speed of 5 cm/minute and a chart speed of 5 cm/minute on the 9 kg load scale. In preparing the pressure-sensitive adhesive products according to the invention, it will be understood that while any suitable backing material may be used, it is preferred to use fibrous material, e.g. cotton, rayon, paper, non-woven fabrics, polyester, and other plastics, etc. Also the test may be carried out on the above backing materials without gluing them onto Mylar film. EXAMPLE 2 This example describes the preparation of an improved random emulsion polymerization product according to the present invention, prepared from styrene, butadiene, alpha-methyl styrene, itaconic acid, methacrylic acid and tertiary dodecyl mercaptan. Accordingly, a reaction mixture is prepared by sequentially charging the materials shown in Table 1 into a 4.5 litre high pressure kettle equipped with a mechanical stirrer, thermometer, pressure gauge and three charging inlets. Table 1 Number Ingredient Amount (g) 1 Water-distilled 935.1 2 Kemplex - 100 2.2 3 Itaconic acid 18.0 4 MB-45 (Monawet MB-45 - surfactant- 5.33 diisobutyl sodium succinate) 5 Seed Latex (800-43-CS, a small 57.1 particle size carboxy lated styrene-butadiene latex from GAF with 42% solids) 6 Water-distilled 50.0 7 Ammonium Persulfate 2.4 8 Water-distilled 200.0 9 Sodium Hydroxide (20%) 18.0 10 Ammonium Persulfate 3.6 11 MB-45 21.3 12 Styrene 576.0 13 Butadiene 573.6 14 Methacrylic acid 8.4 15 Tertiary-dodecyl mercaptan 17.4 16 Alpha-methyl styrene 24.0 Specifically, ingredient Numbers 1 through 5 are charged at room temperature into a 4.5 litre pressure reactor, alternately evacuated and repressurized with nitrogen three times while agitating at 300 rpm. Then the temperature of the contents is raised to 820C, and a solution of number 7 in number 6 is added. Then numbers 8 through 11 and numbers 12 through 16 are added separately and continuously to the reactor during a period of 4 hours. After the addition has been completed, the temperature is incresed to 880C and the contents are held at this temperature for 2 hours. Fifteen minutes before the end of this period, 4.8 g of 70% t-butyl hydroperoxide in 5 g isopropyl alcohol and 10 g distilled water are added followed by the addition of 1 g of the antioxidant erythorbic acid in 10 g distilled water. The reaction mass is then cooled and discharged. The properties of the resultant polymerization product are given in Table 2 below, which data includes the 900 peel strength, measured under test conditions stated in Example 1 for a pressure-sensitive adhesive product comprising a cotton backing which is coated with the adhesive composition. TABLE 2 % Solids 49.25% pH 4.85 Particle diameter (Dn) 1770 A Surface Tension 51.9 dynes/cm Brookfield Viscosity 50.0 cps. #3 at 30 rpm 900 peel strength 2.8 - 3.0 kN/m Tg (by TMA-penetration) -150C EXAMPLE 3 This example describes the preparation of an emulsion polymerization product having the same composition as in Example 2, but made in the absence of the surface active agent ingredients numbers 4 and 11. The resulting polymer is less sensitive to moisture than that of Example 2. TABLE 3 Number Ingredient Amount (g) 1 Distilled water 935.1 2 Kemplex-100 2.2 3 Itaconic Acid 18.0 4 Seed latex (GAF 800-43-CS) 57.1 42% solids 5 Distilled water 50.1 6 Ammonium Persulfate 2.4 7 Distilled water 200.0 8 Sodium hydroxide (20% solution) 18.0 9 Ammonium Persulfate 3.6 10 Styrene 576.0 11 Butadiene 573.6 12 Methacrylic acid 8.4 13 Tertiary Dodecyl Mercaptan 17.4 14 Alpha-Methyl Styrene 24.0 Ingredient numbers 1 through 4 are charged at room temperature into a 4.5 litre pressure reactor, alternately evacuated and repressurized with nitrogen three times while agitating at 300 rpm. Then the temperature of the contents is raised to 820C, and a solution of number 6 in 5 is added. Then numbers 7 through 9 and numbers 10 through 14 are added separately and continuously to the reactor during a period of 4 hours. After the addition has been completed, the temperature is increased to 880C and the contents are held at this temperature for 2 hours. Fifteen minutes before the end of this period, 4.8 g of 70% t-butyl hydroperoxide in 5 g isopropanol and 10 g distilled water are added followed by the addition of 1 g erythorbic acid in 10 g distilled water. The reaction mass is then cooled and discharged. The properties of the resultant polymerization product are given in Table 4 below, which data includes the 900 peel strength measured under test conditions stated in Example 1 and using the same backing as in Example 2. TABLE 4 % Solids 49.03% pH 4.2 Surface Tension 63.2 dynes/cm 900 peel strength 2.8 kN/m Brookfield Viscosity 50 cps (#3 at 30 rpm) EXAMPLE 4 The same ingredients and procedure as in Example 2 are followed, the only difference being ingredient number 1 wherein 735.1 g are charged instead of 935.1 g. This change provides a latex having a higher solids content, and, when tested according to Example 1, gives 900 peel strengths which are slightly higher. The properties of this polymerization product are given in Table 5. TABLE 5 % Solids 53.10% pH 4.30 Surface Tension 58.1 dynes/cm 900 peel strength 3.0 - 3.2 kN/m Brookfield Viscosity 50 cps (#3 at 30 rpm) EXAMPLE 5 This example describes the preparation of a polymerization product by the same procedure and having the same components as in Example 2. The amounts of three of the ingredients of Example 2 are varied and listed below, the numbers corresponding to the numbers of the ingredients in Example 2. 1. Distilled Water 735.1 g 12. Styrene 552.0 g 16. Alpha-Methyl Styrene 48.0 g The properties of the resulting polymerization product are listed below in Table 6. TABLE 6 % Solids 52.5% pH 4.4 Surface Tension 55.9 dynes/cm Brookfield Viscosity 50 cps (#3 at 30 rpm) 900 peel strength 2.5 kN/m

Claims: CLAIMS 1. The random emulsion polymerisation product of a mixture of monomers in the presence of a chain transfer agent, in which the monomers comprise styrene, butadiene, a-methylstyrene and a copolymerisable carboxylic acid. 2. A polymerisation product according to claim 1, wherein the chain transfer agent comprises tertiary-dodecyl mercaptan, preferably in an amount of from 1.35 to 1.55, e.g. 1.45, parts by weight per 100 parts by weight of the monomer mixture. 3. A polymerisation product according to claim 1, or claim 2, wherein the monomer mixture comprises, per 100 parts by weight thereof, from 20 to 58.9,preferably 35 to 55, parts by weight styrene and from 40 to 78.9, preferably 43.9 to 63.9, parts by weight butadiene. 4. A polymerisation product according to any preceding claim, wherein the monomer mixture comprises, per 100 parts by weight thereof, from 1 to 5, preferably 2 to 3, parts by weight a-methylstyrene. 5. A polymerisation product according to any preceding claim, wherein the copolymerisable carboxylic acid is itaonic and/or methacrylic acid, preferably in an amount of from 0.1 to 5 parts by weight per 100 parts by weight of the monomer mixture. 6. A polymerisation product according to any preceding claim, wherein the monomer mixture consists of styrene, butadiene and relatively minor amounts of a-methylstyrene and copolymerisable carboxylic acid. 7. A pressure-sensitive adhesive product which comprises a backing carrying a coating of a polymerisation product according to any preceding claim. 8. An adhesive product according to claim 7, wherein the backing is a fibrous or plastic(s) material. 9. An adhesive product according to claim 8, wherein the backing is cotton or polyester. 10. An adhesive product according to any of claims 7 to 9, which exhibits a 900 peel strength of from about 2.5 to about 3.2 kN/m at a cross-head speed of 5 cm/min.

Inventors: BARABAS, EUGENE S., GROMELSKI, STANLEY J., MALLYA, PRAKASH, WOTIER, EDWARD J. C/O NAT. STARCH AND CHEM. CORP.
Applicants: POLYSAR INTERNATIONAL S.A.
Application year: 1981
Main classification: C08F236
IPC codes: C08F236, C09J109, C09J7, C09J125