TELECOMMUNICATION CABLE FILLED WITH FOAMED POLYURETHANE COMPOSITION

Abstract: A polyurethane compound, particularly for use in water-­ blocking telecommunications cables, and formed from a mixture of hydroxy-terminated polybutadiene, an additional diol serving as a chain extend an isocyanate and water in the respective proportions (by weight) 100,0 to 20,5 to 50 and 0 to 2. The compound can be used both for solid filling and discrete blocking.

Description: WATER-BLOCKING COMPOUND FOR CABLES This invention relates to compounds, particularly for use in water-blocking telecommunications cables, i.e. protecting them against the longitudinal penetration of water as a result of damage to the cable sheath. It is well known that water may penetrate through the locally damaged sheath of a telecommunications cable and then propagate further longitudinally through the cable core between the insulated conductors, thus adversely affecting the electrical properties of the cable. This longitudinal water infiltration can be stopped or locally restricted by filling the interstices between the insulated conductors either completely or at regular intervals with a water-blocking material. The first is generally referred to as solid filling and the latter as discrete blocking. A material commonly used for water blocking of telecommunication cables is petroleum jelly which is relatively cheap but the use of this material introduces considerable problems in handling both at the filling stage and, later on, when the cable comes to be jointed. Other filling materials tend to be more expensive and do not show a substantial improvement in handling properties over petroleum jelly. It has already been proposed to use a polyurethane compound in place of petroleum jelly but none of the polyurethane compounds so far used has the advantages of the present invention, According to the present invention a polyurethane compound, particularly for use in water-blocking telecommunications cables, is characterized in that it is formed from a mixture of hydroxy-terminated polybutadiene, an additional diol serving as a chain extender, an isocyanae and water in the proportions 100, 0 to 20, 5 to 50 and 0 to 2 parts by weight respectively. In its preferred form, the compound comprises 100 parts by weight of hydroxy-terminated polybutadiene of approximate molecular weight 2800, approximately 5 parts by weight of 2-ethylhexane 1, 3 diol, approximately 20 parts by weight of diphenylmethane diisocyanate and approximately 0.5 parts by weight of water. Improved aging properties can be obtained by adding approximately 1 part by weight of an antioxidant. The compound can be used both for solid filling and discrete blocking. It is, however, particularly suited to the latter and a preferred method and apparatus for discrete water blocking, using the compound, will now be described. The equipment comprises an applicator tube through which the cable core passes after being helically wrapped with an unwoven polyester tape (trade mark REEMAY) and before the application of the polyethylene sheath using a conventional sheath extruder and a conventional cooling trough. The applicator tube has a radially extending inlet port fed from a mixing chamber. The blocking compound ingredients are supplied to the mixing chamber adjacent to the applicator tube through flexible tubes under the control of valves which are operated by compressed air. A valve in the inlet port is under the control of length-measuring equipment near the final take-up stand following the cooling trough. When the applicator valve is opened,the compound is forced by the pressure of the supply means to the mixing chamber through the REEMAY tape to fill the interstices in the core. Between each blocking operation, some compound is smeared on to the tape as it passes through the tube. The immediately following extrusion operation has two effects in that it accelerates the foaming and the curing (thermo-setting) of the blocking compound and also assists the smeared compound to impregnate the tape between the blocks thus preventing outward migration of the compound and providing a satisfactory base to receive the polyethylene extrusion. The method and apparatus for discrete water blocking thus outlined is more fully described in the specification of European Application No. 80200801.1 but it is to be understood that other methods of discrete water blocking can be used and that the compound is also suitable for solid filling. -Ata later stage in the cable formation, an outer water blocking operation may be carried out using a conventional moisture barrier of plastics/ metal foil laminate. Subsequently, the cable can be armoured and it has been found that the compound according to the invention can be usefully applied to fill the interstices between the armouring wires.

Claims: CLAIMS: 1. A polyurethane compound, particularly for use in water blocking telecommunications cables, characterized in that it is formed from a mixture of hydroxy-terminated polybutadiene, an additional diol serving as a chain extender, an isocyanate and water in the proportions 100, 0 to 20, 5 to 50 and 0 to 2 parts by weight respectively. 2. A compound as claimed in claim 1 characterized in that it contains 100 parts by weight of hydroxyterminated polybutadiene of approximate molecular weight 2800, approximately 5 parts by weight of 2-ethylexane 1,3 diol, approximately 20 parts by weight of diphenylmethane diisocyanate and approximately 0.5 parts by weight of water. 3. A compound as claimed in claim 2 also characterized in that it comprises approximately 1 part by weight of an antioxidant. 4. A method of blocking a telecommunications cable against the longitudinal ingress of water characterized in that¯-it¯includes the steps of injecting into the cable at regular intervals discrete blocking sections composed of the compound claimed in claim 1, 2 or 3 and subsequently heating the compound to cause it to expand and ensure complete filling of the interstices in the cable. 5. A method as claimed in claim 3 characterized in that the cable core is wrapped with an unwoven polyester tape, the compound is injected through the tape into the core and a polyethylene sheath is extruded over the tape, the heating of the compound being produced by the heat from the extrusion operation. 6. A telecommunications cable characterized in that its core is blocked against the longitudinal ingress of water by being filled with the compound claimed in claim 1, 2 or 3. 7. A telecommun¯mUions cable characterized in that its core is discretely blocked against the longitudinal ingress of water by means of the method claimed in claim 5. 8. A telecommunications cable as claimed in claim 7 characterized in that a moisture barrier in the form of a metal/plastics laminate is applied over the extruded sheath. 9. A telecommunications cable as claimed in claim.6, 7 or 8 characterized in that it is provided with an armouring layer whose interstices are filled with the compound claimed in claim 1 or 2.

Inventors: BURY, JOHN ROBERT IVOR, SIMPSON, WALTER ERIC
Applicants: INTERNATIONAL STANDARD ELECTRIC CORPORATION
Application year: 1981
Main classification: C08G18
IPC codes: C08G18, H01B7