PROTECTIVE COATINGS FOR THE HIGH TEMPERATURE ZONES OF ENGINES

Abstract: A method for producing, maintaining and/or repairing a protective coating on the surface of at least one component in a high temperature zone of an engine during operation thereof wherein selected additives are employed in the engin's fuel.

Description: HIGH TEMPERATURE COATINGS This invention provides a method for producing, maintaining and/or repairing a protective coating on an article exposed to high temperature atmospheres. Components used in high temperature environments, such as those encountered in the high temperature zones (e.g., combustion chambers, turbine sections and exhaust ports) of jet engines, rocket motors and the like, often must be protected from destructive reaction with oxygen and/or the products of fuel combustion. This is conventionally accomplished by coating the portion of the component exposed to the high temperature atmosphere with a non-reactive material such as a refractory oxide, carbide or silicate. Considerable effort is being expended in attempts to increase both the operating temperatures and service life of existing coatings. The principal barriers to improvements in performance of such coatings are loss of thickness resulting from volatilization and cracking and spalling of the coating caused by differences in thermal expansion between the coating and the coated surfaee. Damage to the protective coating of a component of an engine, if not immediately corrected, will result in loss of the component, which often causes loss of the engine, and ultimately loss of the vehicle powered by the engine. It is an objective of the invention to overcome the inadequacies of the prior art means for maintaining a protective coating on components of engines exposed to destructive, high temperature atmospheres0 It is another objective of the invention to provide means for repairing a damaged protective coating on components of engines exposed to destructive, high temperature atmospheres. It is yet another objective of the invention to provide means for producing and maintaining a protective coating on components of engines exposed to destructive, high temperature atmospheres. These and other objectives of the invention are achieved by adding selected compounds to the fuel to be used in an engine having or requiring a protective coating on the surfaces of at least one component of the engine in its high temperature zone. The selected compounds must be soluble in the fuel and, upon exposure to the high temperatures and oxidizing atmosphere of the engine combustion zone, must form other compounds which produce and/or sustain the protective coating on the engine component. Although the discovery is not bound by theory, it appears that the excess of oxygen known to be present during fuel combustion results in an atmosphere in which an aerosol of liquid droplets or a vapor of an oxygencontaining compound, for example oxides or mixed oxides, is created from the appropriate additive. The compound then deposits as a coating on the hot engine components0 The concentration of the fuel additive is controlled to attain the desired coating rate. Non-limiting examples of compounds that are suitable as fuel additives in the method of the invention are: silicon compounds, such as tetraethyl silane, propyltriethoxy silane and tetraphenyl silane; boron compounds, such as decarborane, o-carborane, trimethylborate and triethylborate; barium compounds, such as barium crown ether complexes r -. magnesium compounds, such as diphenyl magnesium etherate and the magnesium crown ether complexes; calcium compounds, such as calcium chloride dicyclohexyl crown etherate; and titanium compounds, such as the titanium crown ether complexes. When it is desired to maintain an existing protective coating on the surfaces of at least one component in the high temperature zone of an engine to shield the component from destructive reaction with the constituents in the atmosphere to which it is exposed during engine operation, the method of the invention involves introducing into the engine's fuel an effective amount of a soluble additive of a type required to sustain the protective coating. In the case where an existing protective coating on the exposed internal surfaces of at least one component of a high temperature zone of an engine is damaged, the coating may be repaired during engine operation by a method involving adding to the engine's fuel and effective amount of a soluble additive of a type required to repair the protective coating. When it is required to produce and maintain a protective coating on the surfaces of at least one component in a high temperature zone of an engine to shield the component from destructive reaction with the constituents in the atmosphere to which it is exposed during engine operation, the method involves introducing into the engine's fuel an effective amount of a soluble additive of a type required to produce and sustain the protective coating. The phrase "effective amount" as used in the specification and claims is defined as about the least quantity of fuel additive that is sufficient to accomplish the stated purpose. Utilization of a quantity of additive above a sufficient amount to accomplish the stated purpose results in an undesirable build-up of coating material in the engine. The required or effective amount of additive may be determined empirically by one skilled in the art. The following example will further describe the invention. It is understood that this example is provided to illustrate the practice of the invention and is not intended as limiting beyond the limitations imposed by the appended claims. Carbon-carbon composite components generally prepared by heat-treating a formed mixture of carbon or graphite fibers and phenolic, pitch (from coal tar, petroleum, PVC, etc.) or like polymers are well known in the art. Although durable at relatively high temperatures in neutral or reducing atmospheres, such composite components begin to fail because of oxidation at the temperatures generated in a jet engine. For this reason, carbon-carbon composite components exposed to such an environment require a protective coating. A coating of silicon carbide (SiC) has proven successful for protecting carbon-carbon composite engine components at moderately high temperatures. However, at higher operating temperatures and atmosEheric conditions found in the high temperature zone of a jet engine, the thickness of the SiC coating is observed to diminish to a point which causes failure of the composite component. This destruction is caused by volatilization of SiO2, which is formed as a thin layer by oxidation of the surface of the Sir layer exposed to the combustion products and excess oxygen. This SiO2 layer protects the underlying SiC coating until the layer is volatilized and a new layer of SiO2 is formed by oxidation of the outermost region of the SiC coating. This is a continuous process which ultimately results in destruction of the SiC coating and the composite component. To protect an SiC-coated carbon-carbon composite component of a turbine section of a jet engine during operation, an effective amount of a silicon-containing compound soluble in jet fuel, tetraethyl silane, is added to the fuel to maintain the SiO2 layer, thereby protecting the SiC coating of the component. The high temperature atmosphere of the combustion zone of the engine is strongly oxidizing and sio2 is therefore formed from the tetraethyl silane, and continuously replenishes the volatilized SiO2 on the surface of the SiC coating. The concentration of the additive is adjusted to obtain a low rate of deposition to ensure a replenishing and "self-healing" action. While the invention has been described in detail and with reference to a specific embodiment thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the scope and spirit thereof, and, therefore, the invention is not intended to be limited except as indicated in the appended claims.

Claims: CLAIMS 1. A method for providing, providing and maintaining, or repairing a protective coating on the exposed surfaces of at least one component in the high temperature zone of an engine during operation thereof characterized by introducing into said engine's fuel an effective amount of a soluble additive capable of being oxidized upon combustion of said fuel to form a compound of a type required to respectively provide, provide and maintain, or repair said protective coating. 2. A method according to claim 1, in which at least one component in the high temperature zone comprises a carbon-carbon composite component coated with silicon carbide characterized by the fact that the additive to the engine's fuel is a silicon-containing compound soluble in said fuel and capable of being oxidized to SiO2 when the fuel is combusted. 3. A method according to claim 2, characterized by the fact that the silicon-containing compound is tetraethyl silane. 4. A method according to claim 2 or 3, characterized by the fact that the component in the high temperature zone is a turbine section of a jet engine during operation thereof.

Inventors: PRESCOTT, ROGER
Applicants: GREAT LAKES CARBON CORPORATION
Application year: 1981
Main classification: C10L1
IPC codes: C10L10, F01D9, F01D5, F23R3, C10L1, F02C7, F01D25