PROCESS FOR INCREASING THE WATER DISCHARGE OF WATER DELIVERING DRILLED WELLS

Abstract: Process for increasing the water discharge of water delivering drilled wells, which can be characterized in that into the filter section of the well weak acids with a dissociation constant being less, than Kd = 10<-3> are introduced. Afer a dwelling period of longer duration, expediently 10 to 48 hours, as well as compressing, flushing is performed by means of a scavenging pump. Thereafter the solution of sodium bicarbonate and/or sodium hypochlorite is introduced into the filter section. After a longer dwelling period, expediently one to thirty-six hours, flushing is performed by means of the scavenging pump. As weak acids with a dissociation constant being less than Kd = 10<-3> acetic acid, tartaric acid, citric acid, metaboric and/or tetraboric acid is used.

Description: Process for increasing the water discharge of water delivering drilled wells Technical field The invention relates to a process for increasing the water discharge of water delivering drilled wells in case of the decrease of the water dis¬ charge with wells having been exploited for a longer period, furtheron in case of new wells having been deepened with mud, for restoring i.e. increasing the water permeabi lity of the original rocks by reducing the well-resistance, by using a chemical treatment. Background art As it is a well known fact, the water discharge of the water delivering drilled wells depends in addition to the layer conditions on the mode 5 of the well formation, the age of the well, the methods of water production and on the quality of water. Themode of well formation includes the structural solutions to be applied, e.g. the piping, the o arrangement and construction of the filter, as well as the drilling methods and pumping with the purpose of cleaning being utmost important from the point of view of water discharge. The pumping serving for purification may decisively 5 influence the quality of well formation, which can be characterized numerically by the well- resistance. As it is known, the components of well-resistance a re the following: the dam effect, i.e. the changed resistance of the zone around o the well, the layer resistance, the filter resistance, the resistance resulting from the instrusta- tion, the resistance-surplus of a more or less turbulent stream - compared to the linear stream - at higher flow velocities and at least the flow resistance of 5 the piping in the well. By the application of the process according to the invention the increase of the water discharge can be achieved by the considerable decrease of the dam effect - the more, by converting it into an effect o with a different sign (achieving a lower resistance in the zone around the well, than the original one), by the reduction of the resistance resulting from incrustation and indirectly by the reduction of the resistance-surplus of the turbulent stream. 5 In course of well formation the optimal development of the zone around the well is of utmost importance. This represents an especially difficult task, when flush-dril I Ing is applied, since the mud is penetrating into the zone around the well in a depth of 1oto 5o cm o and reduces water permeability of the confining zone. Water permeability may be considerably decreased, it may even reach the fhousandth-fenthousandth of the original value. In accordance with the invent ion detrimental effects 5 of the mud can be eliminated by removing the mud increasing the layer resistance with a high efficiency from the infiltered zone and by increasing the original water permeability of the confining zone. It is a fact of common knowledge, that the resistance o of the zone around the filter can be reduced by pumping, for this purpose the so-called Mammoth pump or a compressor is used. The pumping method in itself is rarely yielding satisfactory results and in particular it used to be unsuccessful, when the infiltrate contains bentonϊte. In the majority of cases the reason for the insufficient effect of pumping is, that the pressure drop in the well is not entirely breaking up the conglomerated mud layer in the clogged zone around the filter, but only on certain places. The water streaming along the lowest resistance in the initially small channels 1o having been formed in such a manner - is forming more and more larger ducts resulting finally in the collapse of the layer. In this case the whole cleaning process is to be repeated. Incrustation, i.e. clogging * is caused by the 15 deposition of different compounds; said compounds contain mainly iron and calcium in form of carbonates, oxydes, hydroxydes, sulfates and silicates. Due to biological effects, e.g. as a consequence of the activity of iron- and manganese bacteria 2o organic compounds may also deposit. The rate of incrustation is increasing in dependence of the age of the well, at the same time the mode of operation and the quality of water are also considerably influencing the rate of incrustation. The so-called 25. "ochre-formation" is of the largest extent, accordingly, it is to be considered as the most dangerous phenomenon; in course of this process iron compounds, mainly ferr ic( I I I )hydroxyde are segregated. According to our experiences, the o intensity of draw-off is playing an important role in ochre-formation. The partial or total turbulence arising with higher flow velocities considerably increases the rate of ochre-formation, whi le with wells being out of operation ochre-formation 5 usually could not be observed. In order to be able to eliminate the layer purifica¬ tion by means of pumping, mostly a treatment with hydro-chloric acid has been used (E. Bieske: Handbuch des Brunnenbaus, Berlin, 1965). Hydrochloric acid 5 dissolves the oxydes and carbonates and elution of the ferrous and calciferous deposits in form of chlorides from the filter zone becomes possible. However, treatment with hydrochloric acid may be disadvantageous in several cases, e.g. where the o relatively rapid and strong dissolving effect may result in the collapse of layers, in addition to this, due to its metal dissolving effect, hydro¬ chloric acid is highly damaging all the fittings made of iron. In spite of the known damaging effects, 5 Improvement of wells with a reduced water dis¬ charge is mostly performed by using hydrochloric acid (Technical Directives of the Office of Water Conservancy, 136/4-73/4.2). The layer purification with hydrochloric acid is causing corrosional o damages in the metal parts and in case of glassfϊbre- -reinforced synthetic casing pipes the risk is extraordinarily high and may lead to the early ageing of the well. Disclosure of Invention 5 In course of our examinations aiming the elimination of the disadvantageous features of the known processes serving for the increase of the water discharge of drilled wells, we have found, that the water discharge of the drilled wells can be increased with o a surprisingly good result - with a yield mostly surpassing the original one - by introducing weak acids into the filtering section, the dissociation constant of which is less, than K , = lo and after a longer dwelling period, expediently 1o to 48 hours 5 and compression, flushing by means of a scavenging OMPI pump is performed. Thereafter, the solution of sodium dicarbonate and/or sodium hypochlorite is introduced into the filtering section. After a longer dwelling period, expediently lasting 1 to 36 hours, repeated flushing is performed by means of the scaveng* i ng pump. The weak acids to be used in course of the process according to the invention, having a dissociation constant less than K . = 1o are the following: acetic 1o acid, citric acid, tartaric acid, metaboric acid and tetraboric acid, all are giving excellent results (Lengyel, Proszt, Szarvas: General and Organic Chemis-try, Budapest, 196o, pp. 198-2o1). Very weak acids, as e.g. orthobor icaci d, require a dwelling 5 period of several days- for yielding proper results. The advantageous effect of the weak acids may be explained probably by the fact that said acids dissolve far slower the carbonates and oxydes, than the hydrochloric acid, accordingly, they are o penetrating far deeper into the zones confining the filter. The slower dissolution is accompanied by a less vigorous gas formation, as a consequence, the danger of layer collapse is also less. The weak acids having been used in course of the 5 process according to the invention do not destruct the material of the filter and the pipes, the mechanical properties of the glassf i bre-rei nforced synthetic pipes are not deteriorated either. According to our experiences, the treatment o having the character of an alkaline reaction, i.e. using the sodium hypochlorite and/or sodium OMPI WIPO bicarbonate solutions after the treatment with the acids is highly increasing the efficiency of the process according to the invention, in the majority of cases a productivity far excessing the original one could be achieved. Best Mode of Carrying out the Invention The process according to the invention will be explained in details by the way of examples. Example 1 o The well having been started in 1938 with an initial water discharge of 18o 1/min (MALEV well I I ), with no yield at the start of the process, was subjected to a frad.itϊonal treatment for 48 hours by using a Mammoth-pump and a compressor. As a 5 result of the treatment a water discharge of 12o 1/minute could be obtained. Thereafter, through the pipe penetrating to the filter concentrated acidic acid in a quantity of 1o kg was introduced Into the well; in the following operational phase, o through the closed well-head, air pressure of 3 to 5 bar was produced for four hours by means of a compressor; after a pressure-free period lasting an hour, a pressure of 7 bar and of the duration of six hours was applied onto the well. After having 5 scavenged the well with the pump for an hour, loo litres of commercially available hypo-solution were introduced into the well; after a dwelling period of eight hours cleaning was performed by means of the scavenging pump. After a treatment with chemicals o the water discharge of the well could be incresed to 9oo 1/mϊnutes, amounting to the fivefold of the original yield and to the seven and half-fold of the value having been obtained by the traditional pumping process. SUB: ■ t_≥_c.T Example 2 Into the well having been started in 1938, with an original water discharge of 14oo 1 /minute, the concentrated aquaeous solution of 15 Kg tartaric acid was introduced through the pipe penetrating to the filter. After a dwelling period of 24 hours and compressing, flushing by means of a scavenging pump was performed, thereafter the solu¬ tion of sodium bicarbonate (5 kg sodium bicarbonate • 1o have been diluted with 4o litres water) was introduced into the filter zone. After a dwelling period of six hours scavenging was performed. After the chemical treatment the water discharge of the well amounted to 175o 1/mϊnute, being by 25 % 5 higher, than the original yield. Example 3 Into a 4o years old well of the depth of 3oo m with no water discharge at all, into the filter zone the solution of citric acid ( 3o kg citric o acid have been dissolved in 2oo I water) introduced. After a dwelling period of 36 hours and compressing, flushing was performed .by means of a scavenging pump and 1oo liters commercially available hypo- -solution were introduced into the well. After a 5 dwelling period of eight hours, scavenging pumping was performed. As a consequence of the chemical treatment the water discharge amounted to 6oo 1/minute, equalling about to the double of the original yield. o Example 4 Into a well of the depth of 15o m, having been deepened with mud and with a water discharge of 19o 1/minute, following the traditional treatment, SUBS _.._. ϋ"_ t2x i" » the solution of tetraboric acid (1 kg tetraboric acid has been dissolved in 2o I warm water) was introduced into the well. After a dwelling time of 48 hours and compressing, flushing by means of the scavenging pump was performed, thereafter 5 kg sodium bicarbonate having been dissolved in 4o I water were introduced into the filter zone. After two hours of compressing and the following cleaning with the scavenging pump the water dis¬ charge amounted to 28o 1/mϊnute, equalling to nearly one and a half of the water discharge having been measured prior to the chemical treatment. 2 H __ _ SHEET

Claims: Cla ims 1. Process for increasing the water dis¬ charge of water delivering drilled wells by using a chemical treatment, c h a r a c t e r i z e d in that into the filter section of the well weak acids are introduced, the dissociation constant of which is less, than K , = 1o and after a dwelling period of longer duration, expediently 1o to 48 hours, as well as compressing, flushing is performed by means of a scavenging pump, thereafter the soluion of 1o sodium bicarbonate and/or sodium hypochlorite is introduced into the filter section; after a dwelling time of longer duration, expediently 1 to 36 hours, flushing is performed by means of a scavenging pump. 2. Process as claimed in claim 1, 5 c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than K , = 1o acetic acid is used. 3. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid o with a dissociation constant being less than K , = 1o tartaric acid is used, d 4. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than 5 K . = 1o citric acid is used. 5. Process as claimed in claim 1, c h a r a c t e r i z e d in that as a weak acid with a dissociation constant being less than 1o -3 etaboric acid and/or tetraboric acid o s used

Inventors: GOEMOERY PAL, HEGEGUES JANOS, KISS FERENC, SIMON ATTILA, GOEMOERY, PAL, HEGEGUES, JANOS, KISS, FERENC, SIMON, ATTILA
Applicants: GENERALIMPEX MAGYAR KULKERESKE, GENERALIMPEX
Application year: 1981
Main classification: E03B3
IPC codes: B01D29, C09K8, E03B3