PROCESS FOR THE CONCENTRATION OF FIBROUS MATERIALS

Abstract: Process for the concentration of fibrous material in a mixture thereof with non-fibrous material, by causing an aqueous suspension of said mixture to flow upwardly to bring about settling out of material of reduced fibre content and formation of a fibre-enriched fraction above it, which is then separated. In the process, the upward flow is made substantially non-turbulent, and is carried out with gas bubbles passing upwardly through the suspension, to increase the efficiency of separation of fibrous from non-fibrous material. The process is specially applicable to the concentration of fibres in the fibrous product (mineral wools) formed by disin­ tegrating silicate and like mineral melts, which commonly contain a relativnly high proportion of granular material ('shot').

Description: Process for the concentration of fibrous material This invention relates to the concentration of fibrous material in a mixture thereof with non-fibrous material. Such a mixture is for example formed when a stream of silicate or like mineral melt is disintegrated to form fibres Not all the melt becomes converted to fibres, and that which does not is present in the product (known as mineral wool) predominantly in the form of granules known as 'shot'. As much as 40E by weight or even more of the product may be constituted by shot; and because shot is abrasive, renders the product unpleasant to handle, and deleteriously affects certain important properties (for example, the capacity of the product to reinforce matrices and to reduce transmission of heat), the product is often treated to reduce its content of shot and thus to increase its concentration of fibre. However, because the density of mineral fibre is substantially the same as that of the associated non-fibrous material, separation of the two forms is a matter of considerable difficulty. One process of concentrating fibrous material in mineral wool or like product is described in US Patent Specification 3,865.315, and in this process an aqueous suspension of mineral wool, having a content of dispersed solids amounting to 0.25-2% by weight is fed continuously to the lower part of a tubular vessel and gently agitated therein by means of a stirrer rotating at 30-l00rpm. As the suspension rises in the vessel, the shot settles out under gravity because of its greater compactness, and it is drawn off from time to time by syphoning off the very bottom liquid layer. The upper liquid layer, whose solids content is correspondingly enriched in fibre, is poured or syphoned off. The fibre-enriched fraction thus separated can be treated direct to recover from it a fibrous product of improved properties, or can be subjected to further processing to increase still further the proportion of fibre in it. We have now found that the process just described can be made more efficient (in terms of increase in the ratio of fibre: non-fibre achieved per pass) by ensuring that the upward flow of aqueous suspension which causes disengagement of the non-fibrous from the fibrous material is substantially non-turbulent, and by passing gas bubbles upwardly through the suspension during its upward flow. Rotary stirring of the suspension is avoided, and by Keeping the flow non-turbulent, shot is not induced to move in a direction counter to the desired direction, which is downwards. The gas bubbles impart only highly localised agitation, and this assists disengagement of granular from fibrous material. Preferably, the upward non-turbulent flow of the aqueous suspension is produced by allowing the suspension to flow under gravity down a channel at the lower end of which it is diverted so as to flow upwardly around said channel. It is further preferred that the rate of upward flow of the aqueous suspension should be in the range 0.1-2cm per second. The aqueous suspension subjected to upward non-turbulent flow suitably has a solids content in the range 0.25-2.5% by weight. The invention will now be further described with reference to the accompanying drawing, which is a diagrammatic vertical section through a vessel in which the process can be carried out. The vessel 1 (suitably of diameter 1.2m) has a vertical cylindrical wall 2 (height 1.8m) and a conical bottom 3 (height 1.2m) whose extremity is connected to a receptacle 4 for separated shot. Disposed axially within the vessel is a pipe 5 forming a channel 6 for the delivery to the lower part of the vessel of aqueous suspension admitted (as indicated by the arrow) via a pipe 7. Within the conical bottom 3 of vessel 1 are a number of EMI3.1 tubes 8 by which air or other suitable gas inert to the suspension such as nitrogen, can be passed, via holes 9 about 0.5mm diameter in the tubes, to bubble up through aqueous suspension flowing upwardly around the channel 6 once conical bottom 3 has been filled Surrounding the upper rim of vessel 1 is a coaxial trough 20 into which aqueous suspension enriched in fibre following its upward flow in the vessel overflows and from which it can be recovered via exit pipe 21. In concentrating the fibre in a typical commercially available mineral wool formed from a silicate melt and containing about 45% by weight of shot1 the following procedure can be adopted. An unopened bale of the mineral wool is crushed in a press (pressure about 1 MPa) to shorten the average fibre length to a value in the range 1 - 10mum. The bale is then broken up without any substantial further reduction in fibre length, and the resulting material is made into a mobile slurry of solids content 10% by weight by adding it with vigorous stirring to an aqueous solution containing 0.1t by weight of surface active agent. Conveniently, the surfactant is a cationic long-chain-alkyl substituted imidazoline, such as that which has been used for many years to coat glass fibres to improve their dispersibility in aqueous media when making them up into glass fibre tissue. The mobile slurry is prepared in a vat equipped with a ribbon mixer to break down the bulk of any residual fibre of length greater than lOmm. The slurry is transferred from the vat to a tank in which, with continuous stirring, it is diluted to form an aqueous suspension of solids content 18 by weight1 with a fibre; non-fibre ratio about 1.25:1. This suspension is pumped via pipe 7 into the upper part of pipe 5 in vessel 1 and allowed to flow under gravity down channel 6 into the conical bottom 3 of the vessel. Having filled the conical bottom of the vessel the aqueous suspension flows upwardly around channel 6, the rate of feed via pipe 7 being adjusted so as to produce a rate of non-turbulent upward flow of about 5mm per second. During this upward flow, there are passed upwardly through the suspension air bubbles which issue from the holes 9 in the tubes 8. This reduces the tendency for the rising fibres to form persistent clumps as they become progressively disengaged from shot during their upward passage in the vessel. Shot sinking to the bottom of the vessel is run off from time to time into the receptacle 4. It is found to be substantially free from fibre, and has a preponderance of coarse particles, such as are likely to damage separation equipment when they move at higher velocities than are here developed. The aqueous suspension overflowing into the trough 20 is recovered via exit pipe 21 and will usually have a fibre: non-fibre weight ratio greater than 5:1. For mineral wools with irregular shot, the ratio will usually be about 10:1; for mineral wools with regular, spherical shot, the ratio will usually be about 20:1. The aqueous suspension issuing from exit pipe 21 can be dewatered to about 50% water content by any convenient means (e.g. with the use of a centrifuge). It can, if desired, then be dried to a moisture content below about 5t by weight. Alternatively, the aqueous suspension issuing from exit pipe 21 can be fed to a hydrocyclone, preferably as described in our patent application JKA/2 filed on the same day as this application, to increase still further the proportion of fibre in it.

Claims: CLAIMS 1. Process for the concentration of fibrous material in a mixture thereof with non-fibrous material, by causing an aqueous suspension of said mixture to flow upwardly to bring about settling out of material of reduced fibre content and formation of a fibre-enriched fraction above it, which is then separated in which process said upward flow is substantially non-turbulent and is carried out with gas bubbles passing upwardly through the suspension. 2. Process according to claim 1, in which upward non-turbulent flow of said aqueous suspension is produced by allowing the suspension to flow under gravity down a channel at the lower end of which it is diverted so as to flow upwardly around said channel. 3. Process according to claim 1 or 2. in which the rate of upward non-turbulent flow of said aqueous suspension is in the range 0.1-2 cm per second. 4. Process according to any one of claims 1 to 3, in which the solids content of said aqueous suspension is in the range 0.25-2.5% by weight. 5. Process according to any one of claims 1 to 4, applied to the concentration of fibre obtained from mineral melt in a mixture thereof with non-fibrous mineral melt material.

Inventors: ATKINSON, ALAN WILLIAM, STEER, ADRIAN MICHAEL
Applicants: T&N MATERIALS RESEARCH LIMITED
Application year: 1981
Main classification: C03B37
IPC codes: C03B37, D01G9