PROCEDURE FOR EXAMINING THE SURFACE QUALITY OF MATERIALS IN SOLID STATE OF AGGREGATION,AND MEANS FOR CARRYING OUT THE PROCEDURE

Abstract: Procedure for examining in materials in the solid state of aggregation, such as metals, their surface defects, surface cracks or equivalent, the properties of coatings or the surface quality of paper. A special application of the procedure of the invention is measurement of the thickness of the surface hardening layer of steel. With a view to preventing the rapid levelling out of the temperature differences produced on the surface of the material under examination, on the material (25) under examination is directed a pulsed light beam (21) in the visible light wavelength range, whereby at least part of said light beam (21) is absorbed on the surface of the material (25) under examination and causes elevation of the surface temperature of the material (25) under examination. The surface of the material (25) under examination that has been heated by effect of the periodic temperature variation produced emits a pulsed infra-red radiation (26), which is received with a means (27) sensitive to infra-red radiation.

Description: Procedure for examining the surface quality of materials in solid state of aggregation, and means for carrying out the procedure The present invention concerns a procedure for examination in materials in the solid state of aggregation, of their superficial defects, surface cracks or equivalent, of coating characteristics or the surface quality of paper. One particular object of the invention is a procedure for measurement of the surface hardening layer thick¬ ness of steel. The .invention also concerns a means for carrying out the procedure of .the invention. Detection of surface cracks is exceedingly important from the view- point of non-destructive materials testing e.g. in atomic power plants and in various motor and engine constructions, in shafts, bearings, etc. It is possible to detect surface cracks by a number of methods, of which may be mentioned, for instance, those which are based on infra-red radiation. Infra-red radiation belongs in that part of the radiant spectrum where the radiation wavelength starts at about 1 urn, extending up to about 10-20 pm. ' Infra-red radiation, or thermal radiation, has a wavelength so large that it is invisible to the human eye. Objects at room temperature emit into their surroundings thermal radiation of about 10 urn wavelength. The wavelength of visible light ranges from 0,4 pm up to about 0,8 pm, and it is thus understood that visible light is of substantially shorter wavelength. Optical microscopes make use of this visible spectrum. The optical icro- scope may also be called an image-forming apparatus, or camera. In image-forming apparatus of prior art an arrangement has been employed which uses a lens to form the image, in accordance with the principles of common lens optics, in the image plane. The lens must however be of a material which is transparent to the required thermal radiation, e.g. of germanium or silicon. Hereafter, an infra¬ red detector is disposed in the image plane and displaced according to a lattice pattern across the image plane, one image point at a time. For infra-red detector, one may use e.g. pyrometric detectors or other so-called infra-red semiconductor detectors. A detector of this type is, in its turn, electrically connected to an electronic amplifier which electronically amplifies, or in another way pro¬ cesses, the infra-red signal that is being received, so that an image resembling a TV screen presentation can be obtained on some kind of display tube. Such systems also exist in which the infra-red detector is stationary in the image plane, but the apparatus com¬ prises in addition to the lens optics, a complex mirror system which "sweeps" or "scans" the image one line at a time across the detector. All the image-forming systems now mentioned utilize the object's own static temperature as their source of infra-red radiation, and this is a drawback common to the image-forming systems of prior art. The object of the invention is to provide an improvement of the procedures known at present which serve the examination of surface quality of materials in the solid state. It is a detailed object of the invention, to provide a procedure enabling the material's surface to be examined at various depths under the surface of the material. ' ' The aims of the invention are achieved by a procedure which is mainly characterized in that on the material to be examined is directed a pulsed light beam in the visible light wavelength range, whereby part of said light beam at least becomes absorbed on the surface of the material under examination and causes elevation of the material surface temperatures, with the consequence that as a result of the periodic temperature variation thus produced, the heated surface of the material under examination emits pulsed infra¬ red radiation; and that the pulsed infra-red radiation emitted by the material under examination is received by the aid of a means which is sensitive to infra-red radiation. The other characteristic features of the procedure of the invention have been stated in claims 2 through 5. In claim 6 is presented a favourable embodiment of the invention, which enables the thickness of the surface hardening layer of steel to be measured rapidly and reliably. It is also an object of the invention, to provide a means for carrying out the procedure of the invention. The means of the in- vention, again, is mainly characterized in that the means comprises a laser light source, a means for pulsing the light beam emitted by the laser light source, a lens system for establishing the focal plane of the pulsed laser light beam on the surface of the material under examination, and an infra-red detector for observing the pulsed infra-red radiation emitted by the surface of the material. The characteristic features of the means of the invention have been stated in claims 8 and 9. It is possible with the procedure and means of the invention to observe e.g. surface cracks or fissures of metal specimens, the properties of various coatings, to examine printing paper for its surface quality, and to measure e.g. the thickness of the surface hardening layer of steel. The advantage of the procedure of the invention lies in the fact that there is no need to touch the speci¬ men, instead of which the surface to be measured is swept over with a laser light beam. The invention is based on the changes in thermal properties of the specimen surface and on observation of the temperature rise, occurring e.g. at a crack, with the aid of the infra-red detector. The temperature rise on the surface is caused in a controlled manner with a laser light beam, whereat the light beam is absorbed by the specimen surface and is converted to heat. It is thus understood that the present invention is based on a - phenomenon which may be termed the photothermic phenomenon. This implies the heating effect caused by light. If the situation is considered wherein a light beam chopped at a given frequency impinges on the surface of the specimen under examination, it is noted that part of this light is dispelled by scattering, while part of the light is absorbed on the surface of the specimen, and is converted to heat. The conversion to heat takes place within a few nanoseconds. The heat pulse thus produced is diffused, in accordance with the laws of physics, partially in under the specimen surface, but part of the heat remains on the surface of the specimen, whereby the specimen surface temperature increases. The temperature increase of the specimen surface is primarily dependent on the light power and on the light absorption properties and thermal properties of the specimen surface. The thermal properties include, in the first place, thermal conductivity, specific heat and density. Since the incoming light is pulsed at a given frequency, the specimen surface is also heated at the same pulse frequency. It is obvious that if the light beam has been focussed to constitute a small punctiform dot on the specimen surface, the surface too will be heated at exactly the same point. Depending on the thermal properties of the specimen surface, the periodic heating of the surface is different at different points of the surface. If the heating is observed or monitored with the aid of some kind of detector, a "thermal map" of the surface can be obtained. The temperature elevation of the specimen surface may well be several degrees Centigrade over the room temperature if a laser with sufficient power is used. The use of laser is particularly easy since the light beam of a laser is easy to direct and since it is easy to focus its light beam with even one single lens. A good idea of the temperature elevation is obtained through the information that for instance a one-watt argon laser will burn a hole through paper. If the light of the argon laser is furthermore focussed, the temperature rise may become very high indeed. However, the tempera¬ ture rise is greatly influenced by the thermal properties of the object. Therefore, paper for instance may catch fire owing to the poor thermal conductivity of paper, while e.g. a steel plate of 5 mm thickness appears to be heated hardly at all. In every case, this conversion of visible light into a heat pulse is the so-called photo- thermic phenomenon. The periodic temperature rise of the specimen's surface temperature can be observed, or monitored, in various ways, for instance with pyroelectric infra-red detectors, which comprise an electronic ampli¬ fication circuit tuned to the same frequency as the modulation frequency of the incoming laser light. Hereby the detector can only see the photothermic signal caused by the light pinpoint, and it will attenuate any other, spurious, temperature variations. The central idea of the present invention is indeed that the temperature variations are observed without touching the specimen with an infra¬ red detector. The periodic temperature variation is produced in the specimen in a controlled manner at the desired point by means of a laser operating on a visible light wavelength. The use of the photothermic infra-red microscope e.g. in the search for cracks is specifically based on the fact that the sharp edge of the crack is more strongly heated than its surroundings because at the crack the heat cannot disperse similarly as in an intact area. If the laser beam is made to scan in lattice fashion over the speci- men, one line or point at a time, an image resembling that on a TV screen is obtained on a display tube of the crack. The total radiation quantity emitted into the hemisphere by a so- called absolutely black ' body is, according to Stefan-Boltzmann's law:- = p (T 4 - T Q 4 ) (a) In formula (a), T stands for the temperature of the body, T for the environment temperature, and p is the so-called Stefan-Boltzmann constant. This radiation law can be applied to approximate the thermal radiation emitted e.g. by a metal surface and by a crack therein. At a thermal discontinuity, such as a crack, the amount of radiation thus increases in proportion to the fourth power of the temperature, thereby causing a good radiation contrast against the background in the image formed.by the camera. It has however been found in measure¬ ments that were carried out that the temperature rises are fairly small, as a rule only some 2 degrees Centigrade, whereby the per cent change of temperature is on the order of about 1% only, with the consequence that the increase in amount of radiation is nearly linear at a crack. Other thermal changes, or discontinuities, on the surface of the specimens also affect the infra-red radiation that is generated. Experiments have shown that for instance the surface hardening layer of steel is a poorer heat conductor than the non-hardened surface, and the thickness of the hardened layer can be assessed from the magnitude of the photothermic infra-red signal. In practical applications, the signal delivered by the infra-red detector is carried to a so-called phase lock amplifier, which forms the product of the signal received and of a reference signal obtained directly from the laser light beam. Of course, the use " of phase detection in optical measurements is a technology known in itself in the art. It is often difficult in practice to make both the laser beam and the infra-red detector scan a given surface, and therefore often the preferred procedure is to place the specimen itself on a micrometer table, which is moved by the aid of a suitable photomechanical control means in the focal plane of the focussed laser light, one point at a time, while at the same time the image dot on the screen display moves in synchronism with said mechanical displacement. A micrometer table of this kind is often called an x/y table. In this way a two-dimensional image is obtained in the display of the thermal properties of the specimen surface. Depending on the amount of dis¬ placement in relation to the image dot displacement in the display, a magnification such as is desired can be obtained. If the specimen moves through 1 mm for instance, while the image dot moves 10 mm, the magnification will then be xlO. It is also possible by regulating the frequency of the light chopper or intensity modulator, to regulate the depth of penetration of the heat pulse and thereby for instance to assess the depth of layer thicknesses or the size of subsurface defects. It should be noted that the heat pulse is propagated in accordance with the diffusion laws , which is known in itself from physics. When analyzing a metallic BU R OM surface, the frequency of about 10 Hz has proved quite well usable. In the procedure and means of the invention, visible light is trans¬ formed into invisible infra-red radiation through a photothermic phenomenon, and therefore for instance a carbon dioxide laser cannot be employed, which radiates light at 10,7 pm, that is, infra-red radiation; in such case the incident laser light is scattered and directly reflected into the infra-red detector, rendering impossible e.g. the detection of cracks. Likewise, heating of the specimen surface e.g. -by means of electrical resistances fails to produce the desired result because then the temperature rise is static, and it is not possible to use in the electronic amplifier any amplifier tuned to a given frequency. It is also a fact that in static heating no observable temperature differences are created at cracks for instance, because the temperature differences level out rapidly. The invention shall* be described in detail with reference to a favourable embodiment of the invention, presented in the figures of the attached drawing, but to which the invention is not meant to be exclusively confined. Fig. 1 presents, in schematic elevational view, the principle of the measuring procedure of the invention. Fig. 2 shows, in schematic elevational view, the construction of a photothermic infra-red camera and microscope according to the in¬ vention. As shown in Fig. 1, the incident modulated laser light 10 heats periodically the desired point on the surface of the specimen 11, and the infra-red radiation 12 emitted by the heated spot of the specimen is observed by the aid of a suitably mounted infra-red detector 13. In front of the infra-red detector 13 has been placed a germanium window 14, which transmits heat radiation only and reflects away any visible light. In Fig. 2, the light beam 21 from a light source 20, most usually a laser, passes through a light chopper 22 operating at an adjustable frequency, or through an intensity modulator, to the focussing lens 23, in the focal plane of which the specimen 25 has been placed, to be movable by action of an electrically, controlled x/y table 24. The modulated infra-red radiation 26 emitted by the surface of the specimen 25 which has been heated by the light beam 21 is collected with the infra-red detector 27, which has been connected over an amplifying and detection apparatus 28 to a CRT display 29. In the CRT display 29, the image dot moves in synchronism with the dis- placement of the electrically controlled x/y table 29 in a lattice pattern, one line at a time. Naturally, the CRT display 29 may as well be replaced with e.g. a recorder or another output instrument. In front of the infra-red detector 27 there is often a germanium window 39 to make sure that nothing but the thermal infra-red light 26 can enter the detector 27 - not any visible light. If visible light could enter the detector 27, there would be the risk that the detector 27 is heated so that erroneous signals would be obtained. As menti.oned already, the light absorbing * capacity of the surface of the specimen 25 may vary also with varying colour of the surface. Often, however, conditions are such that e.g. the surface of metals is rather homogeneously coloured. If variations of colour occur, as is the case in geological specimens for instance, they can be separately taken into account. There are several types of light intensity modulator. The simplest is a cogwheel, between the teeth of which the light beam 21 passes through, whereby the light beam 21 will be interrupted by each "tooth. If the cogwheel is fitted with an electric motor with adjustable speed, this makes available a "light intensity modulator operating at an adjustable frequency". So-called x/y tables 24 performing lattice-type motions are available in a number of different types. The x/y tables 24 consist of micro- meter tables where the micrometer knob is rotated by a small step motor, the step magnitude being electrically controllable. Such an x/y table 24 with electric motor 31 has also been depicted in Fig. 2. The step size may be e.g. 1 pm and the total displacement, e.g. about 20 mm. In the foregoing only the principle of the invention has been presented, and one advantageous embodiment thereof. It is obvious to a person skilled in the art that the invention may be modified in numerous ways within the scope of the inventive idea, presented in the claims following below.

Claims: Claims 1. Procedure for examining in materials in the solid state of aggregation, such as metals, their surface defects, surface cracks or equivalent, the properties of coatings or the surface quality of paper, characterized in that on the material (25) to be examined is directed a pulsed light beam (21) in the visible light wavelength range, whereby at least part of said light beam is absorbed on the surface of the material (25) under examination and causes a rise of the surface temperature of the material (25) under examination, whereby the surface of the material (25) under examination which has been heated through the effect of the periodic temperature variation emits pulsed infra-red radiation (26), and that the pulsed infra-red radiation (26) emitted by the material (25) under examination is received with a means (27) sensitive to infra-red radiation. r 2. Procedure according to claim 1, characterized in that the material (25) under examination is moved in the x/y plane in a lattice pattern, whereby the pulsed light beam (21) heats the material (25) under examination by light dots, and that the pulsed infra-red radiation (26) emitted by the material (25) under examination is received with a means (27) sensitive to infra-red radiation, one light dot at a time, whereby an image of the thermal properties of the surface of the material (25) under examination is obtained, one point at a time. 3. Procedure according to claim 1, characterized in that the material (25) under examination is kept stationary and with the pulsed light beam (21) the surface of the material (25) under examination is scanned, one point at a time, and that the pulsed infra-red radiation (26) emitted by the material (25) under examination is received with a means (27) sensitive to infra-red radiation, whereby an image of the thermal properties of the surface of the material (25) under examination is obtained, one point at a time. 4. Procedure according to claims 1-3, characterized in that as pulsed light beam (21) is used a pulsed laser light beam which is so focussed that the material (25) under examination is located in the focal plane of the laser light beam. 5. Procedure according to claims 1-4, characterized in that the intensity modulation frequency of the pulsed light beam (21) is changed as desired with a view to regulating the depth of pene¬ tration of the thermal pulse generated on the surface of the material (25) under examination. 6. Procedure for measuring the thickness of the surface hardening layer of steel, characterized in that on the material (25) under examination is directed a pulsed light beam (21) in the visible light wavelength range, whereby at least part of said light beam (21) is absorbed on the surface of the material (25) under examination and causes elevation of the surface temperature of the material (25) under examination, whereby the surface of the material (25) under examination that has been heated as a result of the pπodic temperature variation produced emits pulsed infra-red radiation (26) , and that the pulsed infra-red radiation (26) emitted by the material (25) under examination is received with a means (27) sensitive to infra-red radiation. 7. Means for carrying out a procedure according to claim 1,2,3,4,5 or 6, by the aid of which in materials in the solid state of aggre¬ gation, such as metals, their surface defects, surface cracks or equivalent, the properties of coatings, the surface quality of paper or the surface hardening layer thickness of case-hardened steel is e ' xamined, characterized in that the means comprises a laser light source (20), a means (22) for pulsing the light beam (21) from the laser light source (20), a lens system (23) for producing the focal plane of the pulsed laser light beam (21) on the surface of the material (25) under examination, and an infra-red detector (27) for observing the pulsed infra-red radiation (26) emitted by the surface of the material (25) under examination. 8. Means according to claim 7, characterized in that the infra-red detector (27) has been connected over a phase-sensitive amplifier (28) and a detector means to a CRT display (29) . -$URΞ_4^ 9. Means according to claim 7, characterized in that the means comprises a table means (24) for the material (25) under examination, and that the table means (24) has been arranged to be movable in the x/y plane in a lattice pattern, one point at a time.

Inventors: LEINA J, LUUKKALA M
Applicants: LEINA J, LUUKKALA M, VALMET OY
Application year: 1981
Main classification: G01N21
IPC codes: G01B11, G01J5, G01N21, G01N25