IMPROVEMENTS RELATING TO MANUFACTURE OF CASEINATES

Abstract: A method of manufacturing a caseinate including introducing a casein in particulate form entrained in air into a mixing vessel as a free falling cylindrical curtain. The curtain is then sprayed with an alkaline solution and the sprayed particles are allowed to fall over a downwardly extending path to a fluidised bed at the base of the mixing vessel. The particles are then heated in the fluidised bed with a stream of heated air, the sprayed particles are discharged from the bed and then reacted with water to produce a solution of caseinate. The method is particularly but not exclusively used to produce sodium caseinate.

Description: DESCRIPTION "Improvements Relating to Manufacture of Caseinates" This invention relates to the manufacture of caseinates, and, more particularly to the manufacture of sodium caseinate Heretofore, sodium caseinate has been manufactured by mixing a slurry of casein in water with sodium hydroxide then spray drying the resultant sodium casinate. U.K. Patent No. 1 544 304 (claiming priority from German Patent Application No.2 602 454) discloses a device for treating a pulverous or granular substance, which device comprises a vessel, which vessel is provided with means for introducing the substance to be treated into the upper end of the vessel in a vortical flow* a flow inlet for a substantially vertical downwardly flow¬ ing gas stream for entraining the substancej a plurality of nozzles for spraying the pulverous or granular sub¬ stance with a liquid, molten or vapourous substance; a second inlet at the base of the vessel for a counter- current stream of gasj a first outlet for gas free from sprayed pulverous or granular substance- and a second outlet for the sprayed pulverous or granular substance, the height of the vessel being such as to enable the sprayed pulverous or granular substance to be conveyed downwardly over a path of pre-determined length. It has now been foiind that a modified form of this device may be utilised to manufacture a caseinate, such as sodium caseinate, by introducing casein in particulate form entrained in air into the upper end region of a mixing vessel as a free-falling cylindrical curtain, spraying the falling curtain of casein particles with sodium hydroxide solution,allowing the sprayed casein particles to fall over a downwardly extending path of a predetermined length to a fluidised bed region at the base of the vessel and subjecting the sprayed casein particles to a stream of heated air for a predetermined time in the fluidised bed region, discharging the sprayed particles from the bed and the mixing vessel and reacting the discharged sprayed particles with water to produce a solution of sodium caseinate. The invention will now be described, by way of example, with reference to the accompanying diagrammatic drawing. As shown, a cylindrical mixing vessβl2 includes a domed upper region 4, a co-axial upper intermedidse portion 6 of larger diameter than the region 4 extending downwardly as a skirt 5 into a lower intermediate portion θ and a flat bottomed lower portion 10. A solid particle discharge head 12 is positioned centrally of the domed upper region 4 to produce a cylindrical curtain of casein particles free falling under the effect of gravity. Circumferentially spaced nozzles 14 supplied with air from a circumferential wind box 16 and sodium hydroxide solution from a ring header 18 produce sprays of droplets which mix intimately with the particles in the free fall¬ ing curtain. A diffuser plate 20 is positioned in the lower portion 10 and is supplied from below with air delivered to a plenum 22 through a duct 24. The air passes -£tJREΛ OMPI , WIPO upwardly through the diffuser plate 20 to effect fluidisation of particles in a bed superjacent the diffuser plate 20. On passing through the bed the air flows upwardly, together with air supplied to the spray nozzles 14 which has been carried downwardly to the base of the shirt 5, through the cylindrical space formed between the skirt 5 and the lower intermediate portion θ to a filtered collector 26 discharging through a duct 25. A stirrer 30 is positioned superjacent the diffuser plate 20 and a controlled discharge outlet 32 for particles is provided adjacent the diffuser plate 20. In operation, casein powder entrained in an air stream at a temperature of approximately 50 C or lower and having an average, particle size of 50 microns and all passing through a BSS sieve mesh 110 is discharged through the head 12 into the upper portion 4 of the mixing vessel 2 to form a free-falling cylindrical curtain. Air atomised sprays of 10% - 15% by weight sodium hydroxide solution droplets having a size range of between approxi¬ mately 60 and 100 microns and a temperature of approxi¬ mately 10 C. are directed through nozzles 14 toward the curtain and with continued downward movement powder mixed with the sodium hydroxide,droplets enters the fluidised bed formed superjacent the diffuser plate 20, fluidising air at about Θ0 C to effect drying being suppied through the duct 24. The motion of the fluidised bed is such that after about one to three minutes circu¬ lation, with stirring, in the fluidised bed, the particles move to the discharge outlet 32 for discharge as a powder. Water vapour and air from the bed and upper region of the vessel are discharged through the filtered collector 26 to the duct 24. The product powder is a mixture of sodium caseinate, casein and sodium hydroxide which, when dissolved in water, gives a solution of sodium casinate with a pH value in the range of between 6 and 8. It will be appreciated that other casinates, such as calcium caseinate, or mixture of caseinates, may be manufactured using the process by utilising suitable salts as reactant spray. Indeed, a variety of powders may be treated in the aforesaid particular manner. An average casein particle size smaller than 50 microns, for example of about 28 microns, may enhance the reaction but will, of course, require greater expenditure on grinding. Further, whilst the preferred range of concentration of sodium hydroxide is 10 to 15%,concentrations of between 5 and 25% are acceptable. It should be appreciated that the spray nozzles 14 • can be mounted so as to allow for alteration of the angle of declination and inclination of the nozzles and also to allow for alteration the angular displacement of the spray nozzles from the centre of the mixing vessel depending upon the type of caseinate or other powders introduced into the mixing vessel. Further it should also be appreciated that additional filter facilities can be provided to those of the filter collector 26. These additional filter facilities can be positioned adjacent to the mixing vessel so as to communicate with the fluidized bed region of the mixing vessel. P

Claims: 1. A method of manufacturing a caseinate including introducing casein in particulate form entrained in air into the upper end region of a mixing cessel as a free-falling cylindrical curtain, spraying the falling curtain of casein particles with an alkaline solution, allowing the sprayed particles to fall over a downwardly extending path of pre-determined length to a fluidised bed region at the base of the mixing vessel and subjecting the particles to a stream of heated air for a pre-determined time in the fluidised bed region, discharging the sprayed particles from the bed and the mixing vessel and reacting the discharged sprayed particles with water to produce a solution of caseinate. 2. A method manufacturing a caseinate as claimed in Claim 1, wherein the casein particles have an average particle size of 50 microns with all the particles passing through a BSS sieve mesh of 110. 3 A method of manufacturing a caseinate as claimed in Claim 1 ot Claim 2, wherein the alkaline solution has a concentration of between 5% and 25% by weight. 4. A method of manufacturing or casinate as claimed in Claim 3, wherein the alkaline solution has a con¬ centration of between 10% and 15% by. weight. 5. A method of manufacturing a caseinate as claimed in any preceding claim, wherein the alkaline solution is discharged through atomising nozzles giving droplet sizes of between 60 and 100 microns. 6. A method of manufacturing a caseinate as claimed in any preceding claim, wherein the stream of heated air supplied to the fluidised bed region is at a temperature of approximately 80°C. 7. A method of manufacturing a caseinate as claimed in any preceding claim, wherein the dwell time of the sprayed particles in the bed is between one and three minutes. 8. A method of manufacturing a caseinate as claimed in any preceding claim, wherein the alkaline solution is of sodium hydroxide and the sprayed particles when dissolved in water give a solution of sodium casinate with a pH value in the range of between 6 and 8. 9. A method of manufacturing a caseinate substantially as hereinbefore described with reference to the accompanying drawing . g JREA OMPI

Inventors: CARTWRIGHT W
Applicants: CARTWRIGHT W, PETERS CLAUDIUS LTD, CLAUDIUS PETERS LTD
Application year: 1981
Main classification: A23J3
IPC codes: A23J3, B01J2