PROCESS FOR THE PREPARATION OF RUBBER COMPOSITIONS HAVING A HIGH MODULUS OF ELASTICITY

Abstract: A rubber composition having a high modulus of elasticity is produced by drawing a mixture consisting essentially of a rubber matrix having dispersed therein fine particles of a high melting point isotactic polymer of an α-ethylenically unsatu­ rated compound (especially a poly-α-olefin), said polymer having a melting point of at least 150°C and said particles having an average particle size of 50 µm or less at a tempera­ ture no more than 65°C below said melting point and no more than 20°C above said melting point.

Description: "PROCESS FOR UHE PREPARATION O? RUBBER COMPOSITIONS HAVING A THIGH MODULUS OF SPASTICITY This invention relates to a process for preparing a rubber composition having a high modulus of elasticity by drawing, at a temperature within a specific range, a mixture consisting essentially of a rubber matrix containing a microdispersion of particles of a high melting point isotactic polymer of an z-ethylenically unsaturated hydrocarbon. Conservation of material resources and of energy have became important themes in the industrial world in recent years, as a result of which attention in the rubber industry has been directed to making the weight of articles lighter and enhancing performances of articles. For this purpose, in some specific fields, there have been desired vulcanized rubbers with a higher modulus of elasticity than that of generally used vulcanized rubbers but in which the physical properties of the vulcanized rubbers (other than the modulus of elasticity) are substantially the same as those of conventional vulcanized rubbers; moreover, it is desired that the rubber composition should have excellent processability in preparing rubber articles. A common method of increasing the modulus of elasticity of a vulcanized rubber is to mix a rubber with a material having a high modulus of elasticity (such as carbon black or a resin) in a powdery or fibrous form. However, the dispersibility of the highmodulus material in the rubber and the interfacial adhesion of the rubber and the high-modulus material are both unsatisfactory, and therefore, when stress is exerted on the vulcanized rubber, the interface of the rubber and the high-modulus material breaks down, resulting in a deterioration in the physical properties (such as tensile strength, tear resistance and flexing resistance) of the vulcanizate. For example, even polyisoprene rubber, which has the highest flexing resistance of all diene-type rubbers and is widely used for radial tires, has the problem that, when a large amount of carbon black is incorporated therein to increase the modulus of elasticity, the physical properties, particularly flexing resistance, of vulcanisates thereof decrease. A composition in which short fibers of a highly crystalline 1,2-polybutadiene are micro-dispersed in rubber is disclosed in Japanese Patent Application Kokai (i.e. as laid open to public inspection) No. 23150/80, but this composition, although having improved fracture resistance and reinforcing effect, still has unsatisfactory heat stability due to the high unsaturation of the highly crystalline 1,2-polybutadiene. We have now found that these defects of rubbers reinforced with conventional high-modulus materials may be eliminated when a mixture of a rubber and a high melting point isotactic polymer is processed under specific conditions by means of an appropriate processing machine such as a roll or an extruder. It is possible to produce commercially a rubber composition having an improved green strength and also showing, when vulcanized, a high modulus of elasticity and markedly improved fracture characteristics. According to the present invention, there is provided a process for producing a rubber composition having a high modulus of elasticity in which a mixture comprising a rubber matrix containing a microdispersion of particles of an isotactic polymer of an (-ethylenically unsaturated compound, said polymer having a melting point of at least 1500C and said particles having a particle size of 50 sum or less, is drawn at a temperature no more than 650C below said melting point and no more than 2000 above said melting point. The rubber used in this invention may be, for example, a polyisoprene rubber, polybutadiene rubber, styrene -butadi cne-rubb er, butadiene-p entadi ene- styrene rubber, ethylene-propylene rubber, isoprene-isobutylene rubber, butyl rubber, natural rubber and mixtures thereof 0 Of these, polyisoprene rubbers, polybutadiene rubbers, natural rubbers, and styrene-butadiene rubbers are preferred, polyisoprene and natural rubbers being most preferred. Particularly suitable polyisoprene rubbers are high-cis-1,4-polyisoprene rubbers with a cis-1,4 content of at least 90%. It is also possible to use mixtures of polyisoprene rubber and other types of rubber, for example, diene rubbers (such as polybutadiene rubber or styrene-butadiene rubber), ethylene-propylene rubber, butyl rubber or mixtures thereof. The diene rubbers are preferred because they easily covulcanize. The polyisoprene rubber content in the rubber mixture is preferably at least 50% because a content less than 50% tends to deteriorate the fracture characteristics of the product0 The isotactic polymer also used in this invention has a melting point (which may be determined as the peak temperature reached when scanning is effected at 200C/minute using a differential scanning calori meter) of at least 1500C, preferably at least 1600C. If the melting point of the polymer is less than ISOOC, it will melt under the vulcanization conditions of rubber and no satisfactory properties are obtained. Specific examples of such high melting point isotactic polymers which may be used in this invention include the following isotactic polymers : polypropylene; polyallylcyclopentane; polyallylcyclohexane; polyallylbenzene; poly(3-methyl-1-butene); poly(3cyclohexyl-1-butene); poly(4-phenyl-1-butene); poly (3-methyl-1-pentene); poly(3-methyl-1-pentene); poly (4-methyl-1-pentene); poly(3-methyl-1-hexene); poly (4-methyl-1-hexene) polyvinylcyclopentane; and copolymers of two or more 5t-ethylenically unsaturated compounds, such as a copolymer of propylene and allylbenzene or a copolymer of 3-methyl-1-butene and 1-butene. Of these, isotactic polypropylene and poly(4-methyl-1- pentene) are preferred. Poly(4-methyl-1-pentene) can be synthesized, for example, using a Ziegler-Natta catalyst composed of triethyl aluminum and titanium tetrachloride; its melting point is at least 200 C. Isotactic polypropylene can be obtained by polymerization with a Ziegler-Natta catalyst; it has a melting point of at least 1500C and contains at least 90% of isotactic polymer. An isolated isotactic polymer is particularly preferred Herafter, for simplicity, the polymer of an &alpha;-ethylenically unsaturated compound is referred to as a "poly-z-olefintl but it will be understood that this term, as used herein, includes within its scope polymers of all&alpha;-ethylenically unsaturated compounds, especially hydrocarbons, and not merely of &alpha;-olefins. The mixture consisting essentially of a rubber matrix having micro-dispersed therein particles of a high melting point isotactic poly-&alpha;-olefin with an average particle size of not more than 50 ym can be prepared according to any-wet or dry method, for example as follows (1) A high melting point isotactic poly --olefin is directly pulverized into particles having an average particle size of not more than 50 m and terse particles are directly mixed with rubber mechanically. (2) Fine particles of a high melting point isotactic poly-X-olefin with an average particle size of not more than 50 m are mixed with an organic solvent solution of rubber and uniformly dispersed in the solution, and the polymer mixture is then recovered from the dispersion obtained. (3) Fine particles of a high melting point isotactic poly olefin with an average particle size of not more than 1000 jim are mechanically mixed with rubber at a temp erature not lower than the melting point of said poly- o(-olefin. (4) A high melting point isotactic poly- t-olefin is swollen with an organic solvent and the swollen polymers subjected to a mechanical shearing force to form a dispersion of the polymer in the organic solvent; this dispersion is then mixed with an organic solvent solution of rubber in any way. (5) Fine particles of a high melting point isotactic poly--olefin with an average particle size of not more than 50 m are stirred in an organic solvent to form a suspension and this suspension is mixed with an organic solvent solution of rubber in any manner and the polymer mixture is recovered therefrom. (6) Powder or pellets of a high melting point isotactic poly-&alpha;-olefin and rubbers, both being solutions in organic solvents, are uniformly mixed, and the polymer mixture is then recovered. Any conventional rubber mixing technique may be employed for accomplishing the mixing in method (1) but the preferred mixing temperature is within the range of from 0 C to less than the melting point of the isotactic poly-&alpha;-olefin. The pulverized high melting point isotactic poly--olefin with an average particle size of not more than 50 m used in method (2) can be obtained by the pulverization method in which the powder or pellets of a high melting point isotactic poly-ck- olefin are added to and swollen with an organic solvent and the swollen material is heated by steaming while mechanically stirring it vehemently along with an aqueous solution of a surface active agent to remove the organic solvent or by the screening method in which an isotactic poly=4-olefin is polymerized with a Ziegler-Natta catalyst to give a finely divided slurry-like polymer and particles with particle sizes of not more than 50 Fm are selected therefrom. Particles having an average particle size of more than 50 ym are not well dispersed in rubber, and hence the physical properties of the produced rubber composition are inferior. Any known organic solvents capable of dissolving rubber may be used in this method, and the examples of said rubber solution are a rubber solution prepared by dissolving solid rubber in an organic solvent or a rubbery polymer solution obtained by polymerizing a monomer in an organic solvent. Such a rubbery solution may contain a terminator and/or an anti-aging agent, but this causes no problem when fine powder is mixed with the rubber solution. It is also possible to use a rubber solution diluted with a solvent. The solids concentration of the rubber solution is usually within the range of from 0-5 to 40% by weight, preferably from 1 to 20% by weight. The fine powder of the high melting point isotactic poly-9-olefin may be simply added in an amount sufficient to provide the desired content in the rubber composition. It is desirable to stir the rubber solution after adding-thereto the fine powder of the high melting point isotactic poly A-olefin as it permits more uniform dispersion of the particles. This stirring can be accomplished by any commonly used method such as by using a propellertype or turbine-type stirrer. Also, mixing and stirring may be performed under atmospheric pressure or under superatmospheric pressure at Co to 1300C. The mixing method (3) comprises mechanically mixing an isotactic poly-4-olefin and rubber at a temperature not lower than the melting point of said isotactic poly-&alpha;-olefin. "Mechanical mixing" refers to mixing and kneading operations using various types of processing machines such as an extruder, a kneader, or the like, whereby the isotactic poly-4-olefin is micro-dispersed in rubber. It is to be noted that the desired rubber composition cannot be obtained if a polymer having an average particle size of more than 1000 m is first mixed with rubber in a usually used form and then kneaded mechanically at a temperature not lower than the melting point of the polymer. To accomplish the mechanical mixing of an isotactic poly-&alpha;-olefin with rubber in a molten state to form a micro-dispersion of the polyolefin in rubber, it is necessary to use an isotactic poly-&alpha;-olefin having an average particle size of not more than 200 Fm. When rubber is mixed at a temperature that causes melting of the isotactic poly-g -olefin, the rubber viscosity becomes considerably lower than the viscosity at its ordinary processing temperature (50 - 1000 C) and hence the mixing effect is also accordingly lowered, so that it is necessary to use a previously finely divided isotactic poly-o(-olefin to make up for the lowered mixing effect. Usually, a polymer powder having an average particle size of from 10 to 200 fim is used. The mixing temperature is preferably between the melting point of the isotactic poly-&alpha;-olefin and a temperature 500 C higher than said melting point. It is further desirable to control the mixing temperature to not more than 250 0C in order to avoid deterioration of the rubber quality. Various methods are available for effecting the desired pulverization of the isotactic poly-o(-olefin, but it is commercially advantageods to employ a mechanical pulverization method or a method in which a surfactant is added to the previously solvent-swollen poly-o(-olefin and then the mixture is pulverized under a mechanical shearing force and thereafter the solvent is evaporated to form the fine particles, or a method by which the olefin is first polymerized and the resulting particles having the desired sizes are separated out of the slurry polymer. As for the mixing time required for effecting the micro-dispersion of the isotactic poly-a-olefin in rubber, a time generally used for this type of mixing suffices, and there is usually no need of performing such mixing for a particularly long period of time. Also, in case of performing the mixing at a temperature not lower than the melting point of the isotactic poly-a-olefin used, it is desirable to add an anti-aging agent for preventing the heat deterioration of rubber. In this case, there may be conveniently used a commonly employed heat-proofing antiaging agent, and such an agent is preferably used in an amount of 0.5 to 5% by weight. In the mixing method (4), it is imperative to subject to a mechanical shearing force a high-melting isotactic poly-a-olefin which has been swollen with an organic solvent. By the term "subjecting to a mechanical shearing force" is meant stirring vehemently by a proper means such as a high-speed mixer to break the polymer into a fine particulate form. It should be noted that subjecting to a mechanical shearing force the polymer in the solid form results in no desired par tides having an average particle size of not more than 50 p which can be readily dispersed in rubber. It should be appreciated that the desired mixture can be obtained only when to a mechanical shearing force is subjected the polymer which has been swollen with an organic solvent and then the formed dispersion is mixed with a rubber solution. The high-melting isotactic poly-a-olefin swollen with an organic solvent may be a swollen polymer mixture obtained by polymerizing the olefin in an organic solvent with a Ziegler-Natta catalyst, or may be obtained by adding said poly-a-olefin in the form of powder or pellets to an organic solvent to swell the polymer with the solvent. The former method is more advantageous for industrial use because a solvent-swollen polymer is obtained upon the polymerization reaction and the latter method makes it possible to always obtain a swollen polymer even when a solvent used in the polymerization step is incapable of swelling the resulting polymer, and hence, is particularly advantageous in industry. As the means for subjecting to a mechanical shearing force, there may be used, for example, the toothed disc impeller blades to stir at a high speed or a grinder. Any of these means can divide the polymer into fine particles with an average particle size of not more than 50 . Although the temperature for such an operation is not critical, usually a temperature of 0 to 1000C may be conveniently used. Solvents such as hydrocarbons or halogenated hydrocarbons may be used as the organic solvent for swelling high-melting isotactic poly-a-olefins. The examples of said solvents are benzene, toluene, xylene, tetrahydronaphthalene, hexane, heptane, octane, cyclohexane, methylene chloride, ethylene dichloride, ethane tribromide, chlorobenzene, bromobenzene, o-dichlorobenzene and mixtures thereof. Among these solvents, hydrocarbon compounds having a boiling point of 1200C or less such as benzene, toluene, hexane, heptane and cyclohexane are particularly preferred in respect of solvent recovery. The "organic solvent-swollen state" refers to a state where a high-melting isotactic polya-olefin absorbs the solvent and is expanded, that is, a jelly-like or custard pudding-like state. The polymer concentration in the swollen polymer is usually 0.5 to 40% by weight, preferably 1 to 20% by weight. The rubber solution may be prepared by dissolving solid rubber in an organic solvent or may be formed by polymerizing a monomer in an organic solvent. The rubber polymer solution may contain a terminator and an antiaging agent or may be diluted with a solvent. The solids concentration in the rubber solution is usually within the range of 0.5 to 40% by weight, preferably 1 to 20% by weight. In the method (4), the mixing of the dispersion of a high-melting isotactic poly-a-olefin in an organic solvent with the rubber solution may be effected in an ordinary way, for example, by using a propeller type stirrer, a turbine type stirrer or a line mixer. As for the order of mixing, the high-melting isotactic poly-a-olefin dispersion in an organic solvent may be added to the rubber solution with stirring or the latter may be added to the former, or both of them may be added simultaneously to a vessel with stirring. The mixing temperature is not critical, but a temperature from 0 to 1000C may be conveniently used. The mixing time is not critical and may be sufficient enough to obtain a uniform mixture. According to the mixing method (5), the fine powder of a high-melting isotactic poly-a-olefin having an average particle size of not more than 50 p is suspended in an organic solvent and the suspension is mixed with a rubber solution, whereby the polymer is mixed uniformly with and dispersed in the form of fine particles in rubber. The fine powder of high-melting isotactic poly-a-olefin having an average particle size of not more than 50 V can be obtained either by a method by which a high-melting isotactic poly-a-olefin in the form of powder or pellets is added to and swollen with an organic solvent and the swollen polymer is mechanically stirred vehemently with an aqueous surfactant solution and then heated by steaming to remove the organic solvent (pulverization method), or by a method by which an isotactic poly-a-olefin is polymerized with a Ziegler-Natta catalyst to form a fine-powder polymer in the slurry form and the particles having sizes of not more than 50 p are separated therefrom (screening method). The high-melting isotactic poly-a-olefin used must be in the form of fine powder having an average particle size of not more than 50 ii. If the average particle size is more than 50 , the dispersibility of the polymer in rubber is low, and the physical properties of the rubber composition decrease. Organic solvents such as hydrocarbons and halogentated hydrocarbons may be used as the solvents usable for dispersing fine powder of a high-melting isotactic poly-a-olefin by stirring, and include specifically benzene, toluene, xylene, tetrahydronaphthatene, hexane, heptane, octane, cyclohexane, methyene chloride, ethylene dichloride, ethane tribromide, chlorobenzene, bromobenzene, odichlorobenzene and mixtures thereof. Among them, the hydrocarbon compounds having a melting point of 1200C or less such as benzene, toluene, hexane, heptane, cyclohexane and the like are particularly preferred from thre viewpoint of solvent recovery. Any organic solvent capable of dissolving rubber may be used as the solvent for dissolving rubber in said method, and this solvent may not necessarily be the same as used for dispersing an isotactic poly-a-olefin mentioned above, though it is commercially mo-re advantageous to use the same organic solvent. The term 11suspension11 referred to herein means a state in which the fine particles of polymer in the unswollen state or a slightly swollen state are diluted with and suspended in a solvent, and where the solvent merely acts as a diluting and dispersing medium. The concentration of the polymer suspended is usually within the range of 0.1 to 25% by weight, preferably 0.1 to 10% by weight. Such a suspension can be obtained by mechanically mixing and stirring the fine powder of a highmelting isotactic poly-a-olefin in an organic solvent. For avoiding flocculation of the fine particles and for maintaining a good condition cf dispersion, it is recommendable to stir the polymer at a high-speed, for example, by means of toothed disc impeller blades or to vehemently stir it by means of, for example, Homomixer MV-H (manufactured by Tokushu Kika kogyo) at a rate of 2,000 r.p.m. or more. Though the temperature condition for said operation is not critical, the operation is usually conducted at a temperature of 0 to 100"C. The rubber solution used in this method may be prepared by dissolving solid rubber in an organic solvent or may be a rubber polymer solution formed by polymerizing a monomer in an organic solvent. Said rubber polymer solution may contain a termination and an anti-aging agent or may be diluted with a solvent. The solids concentration in the rubber solution is usually within the range of 0.5 to 40% by weight, preferaly l to 20% by weight. The mixing of the high-melting isotactic poly a-olefin suspension in an organic solvent with the rubber solution may be accomplished in a usual way, for example, by using a propeller-type or turbine-type stirrer. For efficient mixing, it is recommended to use a high-speed stirrer such as mentioned with respect to the suspension reparation. As for the order of mixing, the rubber solution may be added to the suspension of a high-melting isotactic poly-&alpha;-olefin with stirring or the latter may be added to the former with stirring, or both of them may be added simultaneously to a vessel with stirring. The mixing te-mperature is not critical and a temperature of 0 to 1()00C may usually be used. The mixting time is not critical and may be sufficient enough to obtain a uniform mixture. The average particle size.. of the isotactic poly-a-olefin particles $hoB9d be not more than 50 p, preferably not more than 4Q p in this. invention. If the average particle size is more than. 50 , no satisfactory dispersion in rubber is provided, so that the desired properties are not obtained by drawing and the obtained rubber composition is poor in processability. According to the mixing method (6), a solution of powder or pellets of a high. melting isotactic polya-olefin in an organic solvent and a solution of rubber in an organic solvent are uniformly mixed with each other and a polymer mixture is recovered from the resulting solution mixture. In this case, the form of the high-melting isotactic poly-a-olefin is not necessarily a fine powder having an average particle size of not more than 50 ii, and the powder pellets as obtained in the production of the isotactic poly-aolefin may be used as it is. The solvent in which the high-melting isotactic poly-a-olefin is dissolved to form a solution includes the solvents mentioned as to the mixing method (4). The concentration of the polya-olefin solution is 0.5 to 40% by weight, preferably 1 to 20% by weight. The rubber solution may be obtained by dissolving the rubber in the organic solvent or by polymerizing the monomer in the organic solvent. The rubber solution may contain a terminator or an antiaging agent or may be diluted with a solvent. The concentration of the rubber solution is 0.5 to 40% by weight, preferably 1 to20% by weight. The method of mixing the two includes a method by which an isotactic poly-a-olefin is added to a rubber solution, or rubber is added to an isotactic poly-a-olefin solution, or the two are added at the same time to an organic solvent, and the resulting solution is stirred or a method by which an isotactic poly-c-olefin solution is blended with a rubber solution. In the case of the last method, the isotactic poly-a-olefin may be added to the rubber solution, or the rubber solution may be added to the isotactic poly-a-olefin solution, or alternatively, the two solutions may be added to a vessel simultaneously. In this case, the two solvents are not always the same, but it is advantageous that the solvents are the same. In order to keep the poly-a-olefin well dispersed in the rubber, it is necessary to coagulate the rubber while keeping the resulting solution uniform to recover the polymer mixture. That is to say, even if the poly-aolefin is dissolved in an organic solvent by heating, it is not desirable to precipitate the polymer by cooling. The mixture consisting essentially of a rubber matrix having micro-dispersed therein particles of a high-melting isotactic poly-a-olefin having a melting point of at least 1500C, said particles having an average particle size of not more than 50 , as produced by any of the above-mentioned various methods, is subjected to drawing at a temperature between the temperature 650C lower, preferably 55"C lower, than said melting point and the temperature which is 200C higher than said melting point, and the temperature of the drawn mixture is returned to an ordinary rubber processing temperature, followed by mixing with necessary additives such as inorganic filler, softener, plasticizer, coloring matter, anti-aging agent, curing agent, accelerator, and the like, and then vulcanizing and molding. Alternatively, additives such as inorganic filler, softener, plasticizer, coloring matter, anti-aging agent, and the like may be first mixed with the mixture of rubber and a high-melting isotactic poly-a-olefin and the resulting mixture may then be drawn at a temperature in the above-defined range, followed by further addition of a vulcanizing agent and an accelerator, and then vulcanizing and molding. This alternative process gives the same results as the first-mentioned process. The term "drawing" used herein means a treatment by which the rubber composiiton is subjected to a mechanical shearing force above the temperature at which isotactic poly-a-olefin begins to soften by a suitable means such as roll, calender, extruder with die or the like, to orientate the isotactic poly-a-olefin in the composition. The greater the degree of said orientation, the higher the molulus of elasticity of the product becomes. It is, therefore, desirable to process the composition under such conditions that a high shearing force, that is, a large processing strain is given, and usually, it is commercially advantageous to employ a roll, calender, extruder with a die or the like. If the drawing temperature is more than 65"C lower than the melting point of the isotactic poly-aolefin used, it is unable to properly orientate the particles because the isotactic poly-a-olefin is not softened even if the drawing is performed under the conditions giving a large processing strain, so that there cannot be obtained a rubber composition with a high modulus of elasticity. On the other hand, if drawing is performed at a temperature more than 200C higher than the melting point of the isotactic poly-a-olefin, the orientated isotactic poly-a-olefin is annealed to make it impossible to produce the intended effect of orientation, and hence, it is impossible to obtain a molded article with a high modulus of elasticity. Thus, drawing is preferably performed at a temperature between 1100 and 1800C in the case of polypropylene. Specifically, the polyisoprene rubber containing the polypropylene having an average particle size of 50 p or less obtained any method is passed through 3-inch rolls having a slit of 0.1 mm at 20 r.p.m. at a rubber temperature of 1600C. When an extruder is used to draw the particles, the polyisoprene containing polypropylene having an average perticle size of 50 V or less is extruded through an extruder with the dies having a slit of 0.1 mm and a width of 50 mm at a rubber temperature of 1600C. The mixing ratio of a high-melting isotactic poly-a-olefin in the rubber composition is not critical, but in order to obtain a vulcanized rubber having a high modulus of elasticity (indicated in 100% tensile stress) as well as excellent tear and flexing resistance, the isotactic poly-a-olefin content in the rubber composition is preferably within the range of 2 to 40% by weight, more preferably 3 to 25% by weight. If the polya-olefin content is less than 2% by weight, the product tends to be inferior in modulus of elasticity, and if said poly-a-olefin content exceeds 40% by weight, the processability of the composition tends to be poor. The rubber composition obtained according to the process of this invention may be applied to practical uses either alone or in admixture with other rubbers. Said other rubbers include polyisoprene rubber, polybutadiene rubber, styrene-butadiene rubber, ethylene-propylene rubber, butyl rubber, natural rubber, etc., and diene rubbers are most preferred for use in combination with the rubber composition of this invention. The rubber composition produced according to the process of this invention has a high green strength in the unvulcanized state and, when vulcanized, shows a high modulus of elasticity and excellent fracture characteristics such as high flex-crack resistance, so that it finds a wide scope of applications of rubber. This invention is described in further detail below referring to Examples, which are merely by way of illustration and not by way of limitation. Example 1 Twenty parts by weight of toluene was added to one part by weight of isotactic polypropylene having a melting point of 1650C (Noblene produced by Mitsubishi Yuka Co., Ltd.) and the mixture was heated to form a solution. After air cooling, the resulting swollen polymer was stirred by a high-speed mixer (13,000 r.p.m.) for 15 minutes to impart a shearing force thereto, thereby pulverizing the polymer. To a predetermined amount of the mixture obtained was added a predetermined amount of an n-hexane solution (solids concentration: 10% by weight) of IR2200 (polyisoprene rubber produced by Japan Synthetic Rubber, cis-1,4 content: 98%, ML 4: 82) while mixing by a propeller 1+4 stirrer, said predetermined amount of an n-hexane solution being such that the polypropylene content became 10% by weight, and the mixture was stirred for a further 30 minutes. This mixture was poured into a large amount of methanol containing a small quantity of 2,6-di-t-butylp-cresol to be solidified. The average particle size of the polypropylene particles in the rubber composition thus obtained was 0.28 . The solidified product was drawn at a roll temperature of 1600C and, after cooling to 800C, compounded with the additives according to the recipe shown in Table 1, followed by vulcanization and molding. The properties of the product obtained are shown in Table 3. Table 1 Polymer 100 parts by weight Carbon black (ISAF) 50 * Aromatic oil (JSR AROMA) 10 Zinc oxide 5 Stearic acid 1 ** Anti-aging agent (@@@-NA) @ Vulcanization accelerator CZ*** 1.5 " Sulfur 2.5 Vulcanization conditions: 145 C, 25 min. Note: * High aromatic extender oil ** N-phenyl-N' -isopropyl-p-phenylenediamine *** N-cyclohexyl-2-benzothiazylsulfenamide Example 2 The procedure of Example l was repeated, except that the roll temperature for the drawing operation was changed to 1300C. Example 3 The procedure of Example 1 was repeated, except that the roll temperature for the drawing operation was altered to 1700C. Examples 4 and 5 The procedure of Example 1 was repeated, except that the polypropylene content was altered to 58 and 15% by weight, respectively. Example 6 One part by weight of 2,2'-methylenebis(4methyl-6-t-butyl-phenol) (anti-aging agent) was added to 100 parts by weight of a mixture consisting of 10% by weight of polypropylene powder having an average particle size of 35 ii and 90% by weight of IR-2200, and they were mixed by using an extruder (25 mm f) at 2000C. This mixture was drawn at a roll temperature of 1600C and then subjected to compounding and vulcanization according to the recipe shown in Table 2. Table 2 A mixture of polymer and 100 parts by weight 2,2'-methylene-bis(4-methyl-6 t-butylphenol) (100:1 by weight) Carbon balck (ISAF) 50 Aromatic oil (JSR AROMA) 10 n Zinc oxide 5 1I Stearic acid 1 Anti-aging agent (810-NA) 1 Vulcanization accelerator CZ 1.5 Sulfur 2.5 Vulcanization conditions: 145 C, 25 min. Example 7 A mixture consisting of 10% by weight of polypropylene powder having an average particle size of 30 ii and 90% by weight of IR2200 was compounded with the additives according to the recipe of Table 1 at a roll temperature of 1600C and then drawn at the same temperature, followed by vulcanization and molding. The results of measurement of the properties of the obtained product are shown in Table 3. Example 8 The procedure of Example 6 was repeated, except that the IR2200 was replaced by NR1 (natural rubber, RSS No. 1). The results are shown in Table 3. Example 9 The procedure of Example 6 was repeated, except that the IR2200 was replaced by a mixture (70/30 by weight) of IR2200 and BROl (BROl being a polybutadiene rubber produced by Japan Synthetic Rubber, cis-l,4 content: 97%, ML1000C: 44). The results are shown in 1+4 Table 3. Comparative Examples 1 and 2 The procedure of Example 1 was repeated, except that the roll temperature for drawing was changed to 800C and 200 C, respectively. The results of measurement are shown in Table 3. Comparative Examples 3 and 4 IR2200 alone or a 90/10 (wt%) IR2200/carbon (ISAF) mixture was drawn at a roll temperature of 1600C and cooled to 800C, and by using them as the polymer in Table l, compounding and vulcanization were performed according to the recipe shown in Table 1. The property values of the products determined are shown in Table 3. Comparative Example 5 The procedure of Example 7 was repeated, except that the average particle size of polypropylene was altered to 210 p. The results are shown in Table 3. Comparative Examples 6 and 7 NRtl alone or a 90/10 (wt%) NR4l/carbon (ISAF) mixture was drawn at a roll temperature of 1600C and then cooled to 800C, and by using them as the polymer in Table 1, compounding and vulcanization were carried out according to the recipe of Table 1. The results of the measurement of physical properties are shown in Table 3. Comparative Example 8 A mixture of 90 parts by weight of 1R2200/BR0l = 70/30 (by weight) and 10 parts by weight of carbon (ISAF) was drawn at a roll temperature of 160"C, and after cooling to 800C, it was used as the polymer in Table 1 and subjected to compounding and vulcanization according to the recipe of Table 1. the product propeties are shown in Table 3. Example 10 Twenty parts by weight of toluene was added to one part by weight of poly(4-methyl-l-pentene) having a melting point of 235"C (a product by ICI- Corp.) and heated to form a solution. After air-cooling, the swollen polymer was stirred by a high--speed mixer (13,000 r.p.m.) for 15 minutes to impart a shearing force to the polymer, thereby pulverizing the same. A predetermined amount of the mixture thus obtained was added to a predetermined amount of an nhexane solution of IR2200 (solids concentration: 10% by weight) while stirring the mixture by a propeller stirrer, said predetermined amount of an n-hexane solution being such that the poly(4-methyl-l-pentene) content became 10% by weight, followed by stirring for 30 minutes. This mixture was poured into a large excess of methanol containing a small quantity of 2,6-di-t-butylp-cresol to be solidified. The average particle size of poly(4-methyl-l-pentene) in the rubber composition was 32 p. The solidified matter was drawn at a roll temperature of 200"C, cooled to 80 C- and then compounded and vulcanized according to the recipe shown in Table 1. The properties of the product as measured are shown in Table 4. Examples 11 and 12 The same procedure as in Example 10 was repeated, except that the content of poly(4-methyl-l- pentene) was changed to 7.5% and 15% by weight, respectively. The results are shown in Table 4. Example 13 One part by weight of 2,2'-methylenebis(4methyl-6-t-butylphenol) was added to 100 parts by weight of a mixture of 108 by weight of poly(4-methyl-lpentene) powder having an average particle size of 30 ij and 90% by weight of IR2200 and they were kneaded by means of an extruder (25 mm f) at 2300C. This mixture was drawn at a roll temperature of 2000C and then compounded and vulcanized according to the recipe shown in Table 2. The results of measurement of properties of the product are shown in Table 4. Example 14 The same procedure as in Example 13 was repeated, except that the IR2200 was replaced by R1 (natural rubber, RSS No. 1). The results are shown in Table 4. Cpmparative Example 9 The same procedure as in Example 10 was repeated, except that the roll temperature was changed to 800C, to obtain the results shown in Table 4. Comparative Example 10 One part by weight of 2,2'-methylenebis(4methyl-6-t-butylphenol) was added to a mixture consisting of 10% by weight of poly(4-methyl-l-pentene) powder having an aveage particle size of 230 p and 90% by weight of IR2200 and they were kneaded at a roll temperature of 2000C. This mixture was drawn at a roll temperature of 2000C and compounded and vulcanized according to the recipe of Table 2, to obtain the results shown in Table 4. Table 3 EMI31.1 <tb> <SEP> Average <SEP> Drawing <tb> <SEP> particle <SEP> tempera <tb> <SEP> Base <SEP> Propylene <SEP> size1) <SEP> Mixing <SEP> ture <tb> <SEP> rubber <SEP> (wt%) <SEP> () <SEP> <SEP> method2) <SEP> ( C) <SEP> <tb> Example <tb> <SEP> Wet <tb> <SEP> 1 <SEP> IR2200 <SEP> 10 <SEP> 0.28 <SEP> process <SEP> 160 <tb> <SEP> 2 <SEP> n <SEP> <SEP> n <SEP> <SEP> 0.32 <SEP> n <SEP> 130 <tb> <SEP> 3 <SEP> " <SEP> " <SEP> 0.34 <SEP> " <SEP> 170 <tb> <SEP> 4 <SEP> n <SEP> <SEP> 5 <SEP> 0.28 <SEP> " <SEP> 160 <tb> 5 <SEP> " <SEP> 15 <SEP> 0.28 <SEP> " <SEP> 160 <tb> <SEP> Dry <tb> <SEP> 6 <SEP> " <SEP> 10 <SEP> 35 <SEP> process <SEP> 160 <tb> <SEP> 7 <SEP> n <SEP> n <SEP> 30 <SEP> " <SEP> 160 <tb> <SEP> 8 <SEP> NR&num; ;1 <SEP> " <SEP> 35 <SEP> " <SEP> 160 <tb> <SEP> 9 <SEP> IR2200/ <tb> <SEP> BR01 <SEP> " <SEP> 35 <SEP> " <SEP> 160 <tb> Cop. <tb> Examples <tb> <SEP> Wet <tb> <SEP> 1 <SEP> IR2200 <SEP> 10 <SEP> 0.34 <SEP> process <SEP> 80 <tb> <SEP> 2 <SEP> " <SEP> " <SEP> 0.28 <SEP> 11 <SEP> 200 <tb> <SEP> 3 <SEP> " <SEP> - <SEP> - <SEP> - <SEP> 160 <tb> <SEP> 4 <SEP> " <SEP> 10 <SEP> - <SEP> - <SEP> 160 <tb> <SEP> Dry <tb> <SEP> 5 <SEP> " <SEP> 10 <SEP> 210 <SEP> process <SEP> 160 <tb> <SEP> 6 <SEP> NR&num; ;1 <SEP> - <SEP> - <SEP> - <SEP> 160 <tb> <SEP> 7 <SEP> " <SEP> 10 <SEP> - <SEP> - <SEP> 160 <tb> <SEP> 8 <SEP> IR2200/ <tb> <SEP> BR01 <SEP> 10 <SEP> - <SEP> - <SEP> 160 <tb> Table 3 (Cont'd) EMI32.1 <tb> 100% <SEP> tensile <SEP> 3008 <SEP> tensile <SEP> Tensile <SEP> Elonga- <SEP> | <SEP> Flexing <tb> stress <SEP> stress <SEP> strength <SEP> tion <SEP> resist <tb> <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (%) <SEP> ance@@ <tb> <SEP> 95 <SEP> 220 <SEP> 255 <SEP> 530 <SEP> 135* <tb> <SEP> 86 <SEP> 189 <SEP> -253 <SEP> 520 <SEP> 140* <tb> <SEP> 93 <SEP> 215 <SEP> 260 <SEP> 535 <SEP> 134* <tb> <SEP> 71 <SEP> 168 <SEP> 265 <SEP> 600 <SEP> 176* <SEP> <tb> <SEP> 112 <SEP> 232 <SEP> 248 <SEP> 390 <SEP> 198* <tb> <SEP> 94 <SEP> 210 <SEP> 260 <SEP> 540 <SEP> 136* <tb> <SEP> 87 <SEP> 190 <SEP> 250 <SEP> 550 <SEP> 140* <tb> <SEP> 94 <SEP> 212 <SEP> 265 <SEP> 560 <SEP> 134* <tb> <SEP> 76 <SEP> 173 <SEP> 225 <SEP> 420 <SEP> 120** <tb> <SEP> 50 <SEP> 142 <SEP> 278 <SEP> 650 <SEP> 130* <tb> <SEP> 51 <SEP> 140 <SEP> 269 <SEP> 640 <SEP> 132* <tb> <SEP> 26 <SEP> @ <SEP> <SEP> 94 <SEP> 256 <SEP> 660 <SEP> 204* <tb> <SEP> 49 <SEP> 160 <SEP> 227 <SEP> 350 <SEP> 100* <tb> <SEP> 40 <SEP> 120 <SEP> 155 <SEP> 330 <SEP> 110* <SEP> <tb> <SEP> 26 <SEP> 95 <SEP> -258 <SEP> 670 <SEP> 203* <tb> <SEP> 49 <SEP> 158 <SEP> 225 <SEP> 400 <SEP> 98* <tb> <SEP> 47 <SEP> 149 <SEP> 205 <SEP> 390 <SEP> 100** <tb> Note: (1) The average particle size was measured microscopically and indicated by the mean value from 10 samples. (2) Mixing of polyisoprene rubber or rubber com posed principally of polyisoprene rubber and a high-melting isotactic poly-a-olefin. (3) Evaluation value of flexing resistance was determined in the following way: * crack length in Comparative Example 4(10,000 runs)/crack length in each specimen (10,000 runs) x 100 ** crack length in Comparative Example 8(10,000 runs)/crack length in each specimen (10,000 runs-) x 100 Table 4 EMI34.1 <tb> <SEP> Poly(4- <SEP> Average <SEP> Drawing <tb> <SEP> Base <SEP> methyly- <SEP> particle <SEP> Mixing <SEP> tempera- <SEP> <tb> <SEP> rubber <SEP> l-pentene) <SEP> sizel) <SEP> method2) <SEP> ture <tb> <SEP> (wt%) <SEP> <tb> Example <tb> <SEP> Wet <tb> <SEP> 10 <SEP> IR2200 <SEP> 10 <SEP> 32 <SEP> process <SEP> 200 <tb> <SEP> 11 <SEP> " <SEP> 7.5 <SEP> 32 <SEP> " <SEP> 200 <tb> <SEP> 12 <SEP> n <SEP> 15 <SEP> 32 <SEP> " <SEP> 200 <tb> <SEP> Dry <tb> <SEP> 13 <SEP> n <SEP> 10 <SEP> 30 <SEP> process <SEP> 200 <tb> <SEP> 14 <SEP> NR&num;1 <SEP> " <SEP> 32 <SEP> " <SEP> 200 <tb> Comp. <tb> Examples <tb> <SEP> Wet <tb> <SEP> 9 <SEP> IR2200 <SEP> 10 <SEP> 32 <SEP> process <SEP> 80 <tb> <SEP> Dry <tb> <SEP> 10 <SEP> n <SEP> <SEP> n <SEP> 230 <SEP> process <SEP> 200 <tb> Table 4 (Cont'd) EMI34.2 <tb> 100% <SEP> tensile <SEP> 300% <SEP> tensile <SEP> Tensile <SEP> Elonga- <SEP> <tb> stress <SEP> stress <SEP> strength <SEP> tion <SEP> Flexing <tb> <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (%) <SEP> resistance@@ <tb> <SEP> 99 <SEP> 181 <SEP> 241 <SEP> 440 <SEP> 304* <tb> <SEP> 68 <SEP> 160 <SEP> 250 <SEP> 460 <SEP> 310* <tb> <SEP> 115 <SEP> | <SEP> 196 <SEP> 232 <SEP> 390 <SEP> 511* <tb> <SEP> 97 <SEP> 178 <SEP> 238 <SEP> 440 <SEP> 300* <tb> <SEP> 98 <SEP> 179 <SEP> 245 <SEP> 450 <SEP> 305* <tb> <SEP> 60 <SEP> 157 <SEP> 238 <SEP> 450 <SEP> 302* <tb> <SEP> 46 <SEP> 135 <SEP> 165 <SEP> 340 <SEP> 212* <tb> Note: l), 2) and 3) and * and ** have the same meanings as in Table 3. Example 15 In 2 kg of toluene were dissolved by heating 90 g of IR2200 and 10 g of pellets of polypropylene having an average particle size of 3 mm and the resulting hot polymer solution was then poured into a large amount of methanol containing a small amount of 2,6-di-t-butyl-p-cresole to recover the polymer. The polymer thus obtained was dried in vacuo for 24 hrs. The average particle size of the polypropylene in the rubber composition obtained was 0.48 p. This rubber composition was drawn by means of a roll at 1500C, and compounded with the compounding agents according to the recipe in Table 1, and then vulcanized. The physical properties of the vulcanizate are shown in Table 5. Example 16 Poly(4-methyl-l-pentene) swollen with toluene in a proportion of 20 parts by weight per part by weight of the polymer was stirred at a high rate revolution (10,000 rpm.) in an aqueous solution of potassium salt of rosin acid, and thereafter steamed to remove the solvent. In this case, the potassium salt of rosin acid was used in an amount of 3 g per g of the poly(4-methyl1-pentene). The powder thus obtained was recovered and dried. The average particle size was 20 . The powder was added to n-hexane solvent at a concentration of 1.5% by weight, and a solution of polyisoprene (it2200) in hexane (solids content: 10% by weight) was added to the above suspension while stirring and dispersing by a high-speed mixer (10,000 rpm.). The resulting mixture was added to a large amount of methanol containing a small amount of 2,6-di-t-butyl-pcresole to coagulate the rubber. The poly(4-methyl-lpentene) was 10 % by weight. The rubber composition thus coagulated was dried for 24 hrs in vacuo, and then drawn by means of a roll at 2000C. According to the recipe in Table 1, compounding and vulcanization were carried out and then the physical properties of the vulcanizate were measured to obtain the results shown in Table 15. Example 17 The fine powder of poly(4-methyl-l-pentene) obtained in Example 16 was added to a hexane solution of polyisoprene (IR2200) and the mixture was stirred. In the same manner as in Example 16, the mixture was coagulated and dried, thereafter compounded and vulcanized. The poly(4-methyl-l-pentene) content was 10% by weight. The physical properties of the vulcanizate are shown in Table 5. Example 18 The same procedure as in Example 1 was repeated, except that a toluene solution of poly butadiene (BROl produced by Japan Synthetic Rubber Co., Ltd.) was substituted for the hexane solution of IR2200. The drawing temperature was 1500C, and the vulcanization time was 30 minutes. Though the rubber was BR, a high modulus rubber was obtained. Example 19 To 100 parts by weight of the rubber composition of Example 6 was added 1 part by weight of 2,2'-methylene-bis(4-methyl-6-t-butyl-phenol), and the mixture was kneaded and drawn by means of an extruder with a T-die (25 mm &num;, lip space 0.1 mm) at 1700C. The drawn product was compounded according to the recipe of Table 2 and then vulcanized. The results of measurement are shown in Table 5. Example 20 To 100 parts by weight of a mixture of 10% by weight of polypropylene powder having an average particle size of 210 p and 90% by weight of IR2200 was added 1 part by weight Of 2,2'-methylene-bis(4methyl-6-t-butyl-phenol) (anti-aging agent), and the resulting mixture was kneaded by means of an extruder (25 mm ) at 2000C. The particle size of the polypropylene in the rubber composition after the kneading was 36 p. The kneaded mixture was drawn at a roll temperature of 1600C, and compounded and vulcanized according to the recipe of Table 2. Comparative Example 11 In the same manner as in Example 18, BROl alone was drawn, compounded and vulcanized. Comparative Example 12 Without drawing the rubber composition of Example 18, the rubber composition was compounded and vulcanized. The modulus of elasticity was elevated, but was still lower than that in the case where drawing was effected. In addition, the resistance to crack of said vulcanizate was inferior to that in the case where drawing was effected. Table 5 EMI39.1 <tb> <SEP> Average <tb> <SEP> PP <SEP> or <SEP> TPX <SEP> particle <SEP> Mixing <SEP> 2) <tb> Example <SEP> No. <SEP> Base <SEP> rubber <SEP> cont. <SEP> (%) <SEP> size <SEP> ( , <SEP> method <tb> <SEP> 15 <SEP> IR2200 <SEP> PP** <SEP> 10 <SEP> 0.48 <SEP> Wet <tb> <SEP> 16 <SEP> IR2200 <SEP> TPX* <SEP> 10 <SEP> 20 <SEP> Wet <tb> <SEP> 17 <SEP> IR2200 <SEP> TPX* <SEP> 10 <SEP> 20 <SEP> | <SEP> - <SEP> Wet <tb> <SEP> 18 <SEP> BR01 <SEP> PP** <SEP> 10 <SEP> 0.28 <SEP> Wet <tb> <SEP> 19 <SEP> IR2200 <SEP> PP** <SEP> 10 <SEP> 35 <SEP> | <SEP> Dry <tb> <SEP> 20 <SEP> IR2200 <SEP> PP** <SEP> 10 <SEP> 36 <SEP> Dry <tb> Comp. <SEP> Ex.11 <SEP> BR01 <SEP> - <SEP> - <SEP> <tb> <SEP> " <SEP> " <SEP> 12 <SEP> BR01 <SEP> PP** <SEP> 10 <SEP> 28 <SEP> Wet <tb> Table 5 (Cont'd) EMI40.1 <tb> <SEP> Resistance <SEP> 3) <tb> Drawing <SEP> M100 <SEP> M300 <SEP> 2 <SEP> TB <SEP> EB <SEP> to <SEP> crack <tb> temp.( C) <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (kg/cm2) <SEP> (%) <SEP> growing <tb> <SEP> 150 <SEP> 95 <SEP> 215 <SEP> 260 <SEP> 540 <SEP> 139 <tb> <SEP> 200 <SEP> 92 <SEP> 178 <SEP> 240 <SEP> 440 <SEP> 306 <tb> <SEP> 200 <SEP> 89 <SEP> 173 <SEP> 238 <SEP> 460 <SEP> 310 <tb> <SEP> 150 <SEP> 73 <SEP> 198 <SEP> 198 <SEP> 300 <SEP> 1,000 <SEP> 4) <tb> <SEP> 170 <SEP> 89 <SEP> 210 <SEP> 250 <SEP> 540 <SEP> 137 <tb> <SEP> 160 <SEP> 91 <SEP> 204 <SEP> 257 <SEP> 540 <SEP> 134 <tb> <SEP> 150 <SEP> 26 <SEP> 110 <SEP> 156 <SEP> 390 <SEP> 2,000 <SEP> 4) <tb> <SEP> 60 <SEP> 170 <SEP> 190 <SEP> 320 <SEP> 5,000 <SEP> 4) <tb> Note: * TPX: Poly(4-methyl-l-pentene) ** PP: Polypropylene 1), 2) and 3) are the same as in Table 3. 4) The number of repetitions until the test specimen was completely cracked by means of De Mattia flexing tester.

Claims: CLAIMS: 1. A process for preparing a rubber composition in which a mixture comprising a rubber matrix containing a micro-dispersion of particles of an isotactic polymer of an &alpha;-ethylenically unsaturated compound, said polymer having a melting point of at least 150 0C and said particles having an average particle size of not more than 50 m, is drawn at a temperature no more than 65 0C below said melting point and no more than 20 C above said melting point. 2. A process according to Claim 1, wherein said isotactic polymer is an isotactic polypropylene, polyallycyclopentane, polyallylcyclohexane, polyallylbenzene, oly(3-methyl-l-butene), poly(3-cyclohexyl-l-butenc), poly(4-phenyl-l-bubene), poly(3-methyl-l-pentene), poly (4-methyl-1-pentene), poly(3-methyl-1-hexene), poly (4-metnyl-l-hexene), polyvinylcyclopentane, copolymer of oronylene and allylbenzene or copolymer of 3-methyl-lbutene and 1-butene. 3. A process according to Claim 1, wherein said isotactic polymer is isotactic polypropylene or poly (4-methyl-1-pentene). 4. A process according to Claim 1, 2 or 3, wherein the rubber is one or ore of polyisoprene rubber, polybutadiene rubber, styrene-butadiene rubber, butadiene-pentadiene-styrene rubber, ethylene-propylene rubber, isobutylene-isoprene rubber, and natural rubber. 5. A process according to Claim 1, 2 or 3, wherein the rubber is polyisoprene rubber or a mixture thereof with another rubber. 6. A process according to Claim 5, wherein the polyisoprene is a high-cis-l,4-polyisoprene rubber with a cis-l,4 content of at least 90% or a natural rubber. 7. A process according to any one of Claims 1 to 6, wherein the starting mixture is prepared by directly pulverizing the isotactic polymer into fine powder with an average particle size of not more than 50 ym and mixing said fine powder with the rubber. 8. A process according to any one of Claims 1 to 6, wherein the starting mixture is prepared by mixing a fine powder of the isotactic polymer having an average particle size of not more than 50 DIm with an organic solvent solution in rubber, uniformly dispersing said fine powder in the solution and then recovering a polymer mixture therefrom. 9. A process according to any one of Claims I to 6, wherein the starting mixture is prepared by mechanically mixing a fine powder of isotactic polymer having an average particle size of not more than 1000)us with the rubber at a temperature not lower than the melting point of said polymer. 10. A process according to any one of Claims 1 to 6, wherein the starting mixture is prepared by subjecting the isotactic polymer, swollen with an organic solvent, to a mechanical shearing force to form a dispersion of the polymer in an organic solvent, mixing the dispersion with a rubber solution in an organic solvent, and then recovering a polymer mixture from the mixed solution. 11. A process according to any one of Claims 1 to 6, wherein the starting mixture is prepared by stirring a fine powder of the isotactic polymer having an average particle size of not more than 50 fm in an organic solvent to form a suspension, mixing said suspension with an organic solvent solution of rubber and recovering a polymer mixture therefrom. 12. A process according to any one of Claims 1 to 6, wherein the starting mixture is prepared by mixing powder or pellets of the isotactic polymer and rubber, both in the form of solutions in organic solvents, and then recovering a polymer mixture from the resulting solution. 13. A process according to any one of Claims 1 to 12, wherein the drawing is performed by subjecting the mixture to a mechanical shearing force. 14. A process according to Claim 13, wherein the isotactic polymer is isotactic polypropylene and the drawing is performed at a temperature between 110 C and 180 0C. 15. A process according to any one of Claims 1 to 14, wherein the isotactic polymer content in the rubber composition is from 2 to 40% by weight. 16. A process according to any one of Claims 1 to 14, wherein the isotactic polymer content in the rubber composition is from 3 to 25% by weight.

Inventors: GOTO, KOHEI, IKEDA, HIROHARU, SHIMOZATO, YASUYUKI, YAMAMOTO, KAZUHIKO NIHON GOSEIGOMU
Applicants: JAPAN SYNTHETIC RUBBER CO., LTD.
Application year: 1981
Main classification: C08L21
IPC codes: C08L21