HIGH YIELD NITROGEN GAS GENERATORS

Abstract: A solid propellant nitrogen gas generator comprises a stoichiometric blend of sodium azide fuel and an oxidizer selected from the group consisting of sodium nitrite, sodium nitrate, sodium sulfate, and mixtures thereof.

Description: HIGH YIELD NITROGEN GAS GENERATORS Background of the Invention 1. Field of the Invention This invention relates to gas generators and is particularly directed to solid propellant gas generators for producing high yields ( > 50% by weight) of pure nitrogen gas. 2. Description of the Prior Art Previously developed gas generators for the production of nitrogen gas have employed sodium azide as the primary source of nitrogen in conjunction with a variety of solid oxidizers. Typical oxidizer examples are fluorocarbon polymers such as Viton A (U.S. Patent 3,977,924), Teflon (U.S.Patent 3,833,432), cupric oxide (German Patent 2,327,741) and numerous others. U.S. Patent 3,947,300 describes a propellant system in which sodium azide is used with the inorganic oxidants (chlorates, nitrates, chromates, and peroxides) in conjunction with flux promoting compounds such as silicon dioxide. A typical example (5:1:2 molar ratio of NaN3:NaN03:SiO2) would result in a 42.2 weight percent yield of nitrogen at a temperature of 20500K. All of the previous work has resulted in nitrogen gas yields of 20 to 45 weight percent, and propellant physical properties which are marginal in that small pieces of the pressed grains erode upon vibration of the containing vessel. This often results in erratic pressurization rates upon ignition of the propellant change. Utilizatfon of flux promoting compounds such as SiO2 also degrade physical properties, but also increase the flame temperature due to secondary chemical reactions such as: EMI2.1 The additional heat released from the secondary reactions must then be absorbed in a heat transfer media which adds to the complexity of the overall system. Summary of the Invention Accordingly, there is provided by the present invention a solid propellant gas generator for producing pure nitrogen gas, which comprises a stoichiometric blend of sodium azide, sodium nitrate, sodium nitrate, sodium sulfate and mixtures thereof. Objects of the Invention Therefore, It is an object of the present invention to produce pure nitrogen gas from a solid propellant gas generator. Another object of the present invention is to provide a solid propellant gas generator for producing pure nitrogen which has good physical properties. Yet another object of the present invention Is to provide a solid propellant nitrogen gas generator containing sodiun as its only metallic element. Still a further object of the present invention is to produce a solid propellant nitrogen gas generator which yields greater than 50 weight percent pure nitrogen gas. Yet another object of the present invention is to provide a solid propellant nitrogen gas generator having reduced flame temperature. Other objects, advantages and novel features of the present invention will become apparent from the following detailed description of the invention. Detailed Description of the Preferred Embodiments In accordance with the present invention there is provided a solid propellant gas generator for producing pure nitrogen gas. The propellant comprises a stoichiometric blend of sodium azide (NaN3) as the primary nitrogen source, and an oxidizing source selected from the group consisting of sodium nitrite (NaN02), sodium nitrate (NaN03), sodium sulfate (Na2S04), and mixtures thereof. The overall chemical reaction for the present pure nitrogen gas generator can be described by the molar equation EMI3.1 <tb> xNaNO2 <SEP> + <SEP> yNaNO3 <SEP> + <SEP> zNa2S04 <SEP> + <SEP> (3x+5y+8z)NaN3 <SEP> <tb> (2x+3y+4z)Na20 <SEP> + <SEP> zNa2S <SEP> + <tb> <SEP> Solid <SEP> Residue <SEP> Gas <tb> By way of example and not limitation, Table I illustrates the range of yields experimentally attained dependent upon the stoichiometry. GAS GENERATOR PERFORMANCE Flame Wt. Molar Ratios Temperature Yield x=O; y=O; z=l 11930 50.75 x=l; tyro; z=O 16430K 54.02 x=O; y=l; z=O 17420K 54.63 z=O; y=l; z=2 12750K 51.71 TABLE I It should be noted that although only four specific examples have been delineated, any quantities of reactants can be used in accordance with the overall equation described above. The physical properties of propellants produced from any ratio of x:y:z ranged from about 14,000 psi to about 20,000 psi crush strength for a 1/2"- by 1/2" cylinder. In contradistinction, propellants produced with materials such as SiO2, Fe203, and Teflon present only possessed crush strengths in the range of 3,000 psS to 6,000 psi. The nitrogen gas produced from the combustion of the propellants with varying ratios of x:y:z all was of 99.9% or higher purity. Obviously, many modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that, within the scope of the appended claims, the invention may be practiced otherwise than as specifically described. What is claimed and desired to be secured by Letters Patent of the United States is:

Claims: EMI5.1 1.. A solid propellant gas generator for producing pure nitrogen gas, comprises a stoichiometric blend of sodium azide, NaN3, and a compound selected from the group consisting of sodium nitrite, NaN02; sodium nitrate, NaN03; sodium sulfate, Na2S04; and mixtures thereof.

Inventors: ARTZ, GLEN DELBERT, FLANAGAN, JOSEPH EDWARD
Applicants: ROCKWELL INTERNATIONAL CORPORATION
Application year: 1981
Main classification: C01B21
IPC codes: C01B21, C06D5, B60R21