HERBICIDAL SULFONAMIDES

Abstract: Sulfonamide dervatives of the formula wherein R is H, halogen, nitro, CF₃, alkyl or alkoxy; R₁ is H, Cl or alkyl; R₂ is H or CH₃; L is Cl, Br, CN, OH or a variety of organic groups; R₈ is H, CH₃ or OCH₃; W is O or S; A is X is H, Cl, Br or various organic groups; Y is CH₃ or OCH₃; Z is N or optionally substituted CH; Y¹ is H, CH₃, OCH₃ or OCH₂CH₃; and Q is O or CH₂; and their salts, exhibit herbicidal and planth growth regulant activities. They may be formulated for use in conventional manner. The compound may be made e.g. by reacting a novel sulfonyl isocyanate of general formula with the appropriate 2-aminoheterocycle of formula A-NHR₈, or alternatively by displacing one or both chlorine atoms in the heterocyclic moiety of a novel sulfonylurea of general formula by the appropriate alkoxy groups. Further methods of preparation are also disclosed.

Description: Title HERBICIDAL SULFONAMIDES Background of the Invention This invention relates to o-aminosuifonylphenyl acetic acid derivatives which are useful as plant growth xegulants and herbicides. French Patent No. 1,468,747 discloses the following pare-substituted phenylsulfonamides, useful as antidiabetic agents: EMI1.1 where R = H, halogen, CF3 or alkyl. Logemann et al., Chem. Ab., 53, l80S2 g (1959), disclose a number of sulfonamides, including uracil derivatives and those having the formula: EMI1.2 wherein R is butyl, phenyl or EMI1.3 and R1 is hydrogen or methyl. When tested for hypoglycemic effect in rats (oral doses of 25 mg/100 g), the compounds in which R is butyl or phenyl were most portent. The others were of low potency or inactive. Wojciechowski, J. Acta. Polon. Pharm. 19, P. 121-5 (1962) lChem. Ab., 59 1633 e) describes the synthesir of N-[(2,6-dimethoxypyrimidin-4-yl)-aminocarbonyl]-4methylbenzenesulfonamide: EMI1.4 In U.S. Patent 4,127,405, the following compounds are taught to have herbicidal activity: : EMI2.1 and R6 are independently hydrogen, fluorine, chlorine, bromine, iodine, alkyl of 1-4 car bon atoms, alkoxy of 1-4 carbon atoms, nitro, trifluoromethyl, cyano, CH3S(O)n- or CH3CH2S(O)n-; R4 is hydrogen, fluorine, chlorine, bromine or methyl; R5 is hydrogen, fluorine, chlorine, bromine, methyl or methoxy; is hydrogen, fluorine, chlorine, bromine, alkyl of 1-2 carbon atoms or alkoxy of 1-2 carbon atoms; R8 is hydrogen, methyl, chlorine or bromine; and and are independently hydrogen, methyl, chlorine or bromine; W and Q are independently oxygen or sulfur; n is O, 1 or 2; x 4Rghydrogen, chlorine, bromine, methyl, ethyl, alkoxy of 1-3 carbon atoms, tri fluoromethyl, CH3S- or CS3OCE2-; ; and Z Z is methyl or methoxy; or their agriculturally suitable salts; provided that: (a) when R5 is other than hydrogen, at least one of R3, R4, R6 and R7 is other than hydrogen and at least two of R3, R4, R6 and R7 must be hydrogen; (b) when R5 is hydrogen and all of R3, R4, R6 and R7 are other than hydrogen, then all of R3, R4, R6 and R7 must be either chlorine or methyl; and. (c) when R3 and R7 are both hydrogen, at least one of R4, R5 or R6 must be hydrogen. In particular, the patent discloses orthosubstituted compounds wherein the substitution is C1-C4 alkyl. The presence of undesired vegetation causes substantial damage to useful crops, especially agricultural products that satisfy man's basic food needs, such as soybeans, corn, wheat and the like. The current population explosion and concomitant world food shortage demand improvements in the efficiency of producing these crops. Preventing or minimizing the loss of a portion of such valuable cropU-by killing, or inhibiting the growth of undesired vegetation is one way of improving this efficiency. A wide variety of materials useful for killing, or inhibiting (controlling) the growth of undesired vegetation is available; such materials are co=cnly 4 referred to as herbicides. The need exists, however, for effective herbicides that destsoy or control weeds while not significantly damaging useful crops. J. Heterocyclic Chemistry, 8, 947 (1971) discloses: EMI4.1 Chemische Berichte, 103, 1992 (1970) discloses: EMI4.2 Summary of the Invention This invention relates to novel compounds of Formula I and their agriculturally suitable salts, suitable agricultural compositions containing them, and their method of use as general and selective pre-emergence and post-emergence herbicides and as plant growth regulants. EMI5.1 wherein is CO2R10, CONR3R4, CN, Cl, Br, NR3R4, NR3R4R4', N(R4)C(O)R5, N(R4)C(O)NHR6, N(R4)C(O)OR7, S(O)nR7, OR9, SO2NR3R4, OH, OC(O)R11, OC(O)NHR12 or OC(O)OR13, R is H, F, Cl, Br, NO2, CF3, C1-C3 alkyl or C1-C3 alkoxy; R1 is H, Cl or C1-C4 alkyl; R2 is H or 3 is H, C1-C4 alkyl or OCH3; R4 is H or C1-C-4 alkyl; R3 and R4 can be taken together to form -(CH2)4-, -(CH2)5- or -(CH2CH@)2O; is H, CH3 or CH2CH3; R5 is C1-C4 alkyl optionally substituted with 1-3 atoms of F, Cl or Br, or C3-C4 alkenyl; R6 is H, C1-C4 alkyl or C3-C4 alkenyl; R7 is C1-C4 alkyl; R8 is H, CH3 or OCH3; R9 is C1-C6 alkyl, C3-C4 alkenyl, CH2CF3, CF2CF2H or C5-C6 cycloalkyl: : R10 is H, C1-C4 alkyl, C3-C4 alkenyl, CH2CH2Cl or CH2CH2OCH3, R11 is H. C1-C5 alkyl, C2-C3 alkenyl, C2-C3 alkynyl. , C3-C4 cycloalkyl, EMI6.1 C1-C4 alkyl substituted with 1-4 substituents selected from 0-3 F, 0-3 Cl or 0-3 Br, or C2-C3 alkenyl substituted with 1-3 C1; R12 is H, C1-C6 alkyl, C3-C4 alkenyl, C5-C6 cycloalkyl, EMI6.2 C5.C6 cycloalkyl substituted with CH3; R13 is C1-C6 alkyl or EMI6.3 R14 and R15 are independently H, NO2, CH3, Cl or OCH3; R16 is H, F, Cl, Br, C1-C3 alkyl, NO2, CN, S02CH3, OCH3, SCH3 or CF3; R17 is H, Cl or C1-C3 alkyl; R18 is H, CH3 or Cl; n is 0, 1 or 2: : A is EMI7.1 W is O or S; X is H, Cl, Br, CH3, CH2CH3, C1-C3 alkoxy, CF3, SCH3 or CH2OCH3; Y is CH3 or OCH3; Z is N, CH, CCI, CBr, CCN, CCH3. CCH2CH3, CCH2CH2Cl OR CCH2CH-CH2; is H, CH3, OCH3 or OCH2CH3; and Q is O or CH2; and their agriculturally suitable salts; provided that: (1) when R1 is Cl, then L is Cl or Br and R2 is H; (2) when n is 1, then W is O; (3) when L is CONR3R4, then Z is CH or N; (4) when R3 is OCH3, then R4 is CH3; (5) the total number of carbon atoms of R3 and R4 is five or less; (6) when W is S, then R8 is s; and (7) when L is So2NR3R4, then R3 and R4 are not H. Preferred Compounds Preferred in increasing order for their higher activity and/or more favorable ease of synthesis are: (1) compounds of the generic scope wherein Z is N, CH, CCI, CBr or CCH3; W is 0; and R8 is H or (2) compounds of the generic scope wherein L is OH; P is H; ; R1 and R2 are both CH3 P8 is H or CH3; EMI8.1 Z is CH or N; X and Y are independently CH3 or OCH3; and W is O; (3) compounds of Preferred (1) wherein L is C1, Br, NR3R4, +NR3R4R4', CO2R10, S(O)nR7, OR9, SO2NR3R4, OC(O)R11,OC(O)NHR12, OC(O)OR13; Z is CH or N; X is CH3 or OCH; R, R1, R2 are H; and when n is 1 or 2, z is CH; (4) compounds of Preferred(3)wherein EMI8.2 R8 is H; L is Cl, Br, NR3R4, CO2R10, S(O)nR7, OR9, SO2NR3R4, OH, OC(O)R11, OC(O)NHR12, OC(O)OR13; and R11, R12 and R13 are C1-C3 alkyl; (5) compounds of Preferred (4) wherein L is Cl, Br, NR3R4, CO2R10, S(O)nR7, OR9, SO2NR3R4 or OH; (6) compounds of Preferred (5) wherein R3 is C1-C3 alkyl or OCH3; R4 is CH3; R9 is C1-C4 alkyl; and R10 is CH3 or CH2CH3; (7) compounds of Preferred (6) wherein R7 and R9 are CH3; and (8) compounds of Preferred (7) wherein L is CO2R10, S(O)nR7 or OR9. Specifically preferred for their highest activity and/or most favorable ease of synthesis are: 2-(Dichloromethyl)-N-[(4-methoxy-6-methylpyrimidin-2 yl)aminocarbonyl[benzenesulfonamide; 2-(Dichloromethyl)-N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2-eDichloromethyl)-N'-t(4-methoxy-6-methyl-1,3,5¯ triazin-Z-yl)aminocarbonyl]benzenesulfonamide; 2-(Chloromethyl)-N-[(4,6-dimethoxy-1,3,5-triazin-2yl)aminocarbonyl]benzenesulfonamide; 2-(Chloromethyl)-N-[(6,6-dimethoxypyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2-(Chloromethyl)-N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2-(1-Chloroethyl)-N-[(4,6-dimethoxy-1,3,5-triazin2-yl)aminocarbonyl]benzenesulfonamide; 2-el^PyrrolidinyLmethylt-N-t(4,6-dimethoxypyrLmidin-2- yl]aminocarbonyl]benzenesulfonamide, hydrochloride; 2-(1-Pyrrolidinylmethyl)-N-[(4,6-dimthoxypyrimidin-2 yl)aminocarbonyl]benzenesulfonamide; 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl) aminosulfonyl]benzeneacetic acid, methyl ester; 2-[[(4,6-dimethylpyrimidin-2-yl)-aminocarbonyl] aminosulfonyl]benzeneacetic acid, methyl ester: 2-[[(4-methoxy-Ç-methylpyrimidin-2-yl)aminocarbonYla- aminosulfonyl]benzeneacetic acid, methyl ester 2-[[(4,6-dimethoxy-1,3,5-triazin-2-yl)-aminocarbonyl] aminosulfonyllbenzeneacetic acid, methyl ester; 2-[t(4-methoxy-6-methyl-1,3,5-tria2in-2-yl)amino- carbonyl]aminosulfonyl]benzeneacetic acid, methyl ester; 2-tE(4,6-dimethoxypyrimidin-2-yl)aminocarbonyll- aminosulfonyl]ben: :eneacetic acid, ethyl ester; 2-lLe4-methoxy-6-methylpyrimidin-2-ylEaminocarbonyll- aminosulfonyl]ben2eneacetic acid, ethyl ester; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 methoxymethyl)benzenesulfonamide; N-[(4-@ethoxy-6-methylpyrimidin-2-yl)aminocarbonyl]- 2-(methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triazin-2-yl)aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide; N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl) aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)-aminocarbonyl]2-(methoxyl)benzenesulfonamide; ; N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-2 (methylthiomethyl)benze)benzenesulfonamide; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] 2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triezin-2-yl)aminocarbonyl] 2-(methylthiomethyl)benzenesulfonamide; N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl] 2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 (methylsulfinylmethyl)benzenesulfonamide; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] 2-(methylsulfonylmethyl)benzenesulfonamide; ; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]2-(methylsulfinylmethyl)benzenesulfonamide N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylsulfonylmethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylsulfonylimethyl)benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2- (methylsulfonylmethyl)benzenesulfonamide; N-[(4,6-dimethoxypyrimidin-2-yl)-aminocarbonyl]-2 (butoxyrnethyl) benzenesulfonamide; N-1(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl3-2- (ethoxymethyl)benezenesulfonamide; N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (1-methylpropyloxymethyl)benzenesulfonamide; 2- t methylamino) sulfonylmethyl3 ^ 4, 6-dimethyl- pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; ; 2-ttDimethylamino)sulfonylmethyl]-N-[t4,6-dimethoxy- pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2-[(Dimethylamino)sulfonylmethyl]-N-[(4-methoxy 6-methylpyrimidin-2-yl)aminocarbonyl]benzene sulfonamide 2-t(DimethylaminoAsulfonylmethyll-N-{(4,4-dimethyl- 1,3,5-triazin-2-yl)aminocarbonyl]benzenesulfonamide; 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethoxy 1,3,5-triazin-2-yl)aminocarbonyl]benzenesuflonamide; 2-[(DimethylaminoXsulfonylmethyl3-N-[(4-methoxy-6- methyl-1,3,5-triazin-2-yl)aminocarbonyl]benzene sulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (hydroxymethyl) benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl3-2- (hydroxymethyl) benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl]aminocarbonyl]-2 (hydroxymethyl) benzenesulfonamide; N-t(4-methoxy-6-methylpyrimidin-2-yl)amlnocarbonyla-2- (hydroxymethyl) benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]-2 F (hydroxymethyl) benzenesulfonamide; and N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl] 2-(hydroxymethyl)benzenesulfonamide. This invention also relates to novel compounds of Formula II which are useful intermediates for the preparation of the herbicidal compounds of Formula I. EMI12.1 wherein R, R1, and R2 are as previously defined; Z is CH or N; n is O or 2; and L is as previously defined, provided that: -(1) L is not. OH; (2) when R3 is OCHJ, then R4 is CH3 and that R10 cannot be H; (3) when R1 is Cl, then L is Cl or Br and R2 is H; (4) when L is NR3R4, + NR3R4R4', or SO2NR3R4, then R3 or R4 cannot be H; (5) the total number of carbon atoms of P3 and R4 is five or less. is incntion also relates to novel compounds of Formula III which are useful intermediates for the preparation of the compounds of Formula I. EMI12.2 wherein R, R1, R2, R7 and R9 are as previously defined; n ist 0 or 2; L is Cl, Br. CO2R10, SO2NR3R4, S(O)nR7 or OR9, provided that: (1) when R1 is C1, then L is Cl or Br and R2 is H; (2) when L is SO2NR3R4, then R3 and R4 cannot be H; (3) when R3 is OCH3, then R4 isCH3; (4) R, cannot be H; and (5) n is O or 2. Detailed Description of the Invention As shown in Equation 1, the compounds of Formula I can be prepared by reacting an appropriate 2aminoheterocycle of formula IV with an appropriatel substituted sulfonyl. isocyanate of Formula III; wherein L is Cl, Br, CO2R10, SO2NR3R4, S(O)nR7, OR9; n is 0 or 2; R, R1, R2, R3, R4, R7, R8, R9, R10 and A being as previously defined; R3 R4 and R10 cannot be H Equation 1 EMI13.1 The reaction is best carried out in inert aprotic organic solvents such as methylene chloride, tetrahydro- furan or acetonitrile, at ambient pressure and tempera- ture. The mode of addition is not critical; however, it is often convenient to add the sulfonyl isocyanate to a stirred suspension of the aminoheterocycle. Since isocyanates usually are liquids, their addition is more easily controlled. The reaction is generally exothermic. In some cases, the desired product is insoluble in the warm reaction. medium and crystallizes from it in pure form. Products soluble in the reaction medium are isolated by evaporation of the solvent, trituration of the solid residue with solvents such as l-chloro- butane, ethyl ether or pentane and filtration. The intermediate sulfonyl isocyanate of Formula III can be prepared by reacting corresponding sulfonamides with phosgene in the presence of an alkl isocyanate such as butyl or cyclohexyl isocyanate at reflux in a solvent such as chlorobenzene, according to the procedure of H. Ulrich and A. A. Y. Sayigh, Newer Methods of Preparative Organic Chemistry, Vol. VI, p. 223-241, Academic Press, New York and London, W. Foerst, Ed. In cases where formation of the desired sulfonyl isocyanate is difficult by the above procedure, the preformed sulfonylurea from the reaction of butyl isocyanate with the appro- priate sulfonamide is treated with phosgene according to the above reference. Alternatively, the process of Ulrich and Saying can be imp-oved by the addition of a tertiary base to the reaction mixture as show: by Equation 2. Equation 2 EMI15.1 wherein L, R, R1, R2 are as described ir. Equation 1. III A mixture of the appropriate benzenesul- fonamide V, an alkyl isocyanate and a catalytic amount of l,4-dia:a[2..2,2.Ibicyclooctane (DA3CO) in xylene or other inert solvent of sufficien.ly high boiling point (e.g. > 135 ) is heated to approximately 135 . Phosgene is added to the mixture until an excess is present as indicated by a drop in the boiling point. (The mixture is heated further to drive off the excess phosgene). After the mixture is cooled and filtered to remove a small amount of insoluble by-products, the solvent and alkyl isocyanate are distilled in-vacuo leaving a residue which is the crude sulfonyl isocyanate III. Altervatively, the sulfonyl isocyanate of Formula III-may be prepared as showy in Equation 3 , by the method of Ulrich et al. [J. Org. Chem. 34, 3200 (1969) EMI16.1 wherein L, R, R1 and R2 are as described in Equation 1. The sulfonyl isocyanates of Formula III may afso be prepared, as shown in Equation 4, by phosgenation of the butyl ureas of Formula VI. Equation 4 EMI17.1 wherein L7 R, R1, P2, R3 and R4 are as previously described in Equation 1. The compounds of Formula VI are conveniently prepared by stirring a mixture of the sulfonamides, v, anhydrous potassium carbonate, and n-butyl isocyanate in acetone or methyl ethyl ketone at 25-80 until all of the isocyanate has reacted. The products are isolated by quenching in dilute mineral acid and recrystallizing the solid product. The compounds VI are treated with phosgene and a catalytic amount of DABCO in refluxing xylene or chlorobenzene in a manner analogous to that described in Equation 2. The preparation of these sulfonamides from sulfonyl chlorides with either ammonium hydroxide or anhydrous ammonia is widely reported in the literature, e.g. Crossley et al., J. Am. Chem. Soc., 60, 2223 (1938), and P. A. Rossy et al., J. O.-. Che:. 45, 617 (1980) for those examples containing a reactive functionality in the position ortho to the sulfonamide moiety, it is convenient to add the sulfonyl chloride to a measured quantity of ammonia (Sticn 5) in an inert solvent, e.g. tetrahydrofuran, ethyl acetate, etc., at low temperature (-78 to 00). Side reactions such as rin: formation, elimination, or condensation are thereby substantially avoided. Equation 5 EMI18.1 L' - C1, Br; and R, R1 and R2 being as previously defined. Certain sulfonyl chlorides are best prepared by chlorosulfonation of a substituted benzene according to the teaching of H. T. Clarke et al. Org. Synth. Coll. Vol. 1, 2nd Ed. 1941, p. 85. Other benzenesulfonyl chlorides are best made by diazotization of the appropriate aniline with sodium nitrite in HCl, followed by reaction of the diazonium salt with sulfur dioxide and cuprous chloride in acetic acid according to the tesching of H. L. Yale and F. - Sowinski, J. Org. Chem., 25, 1824 (1960) or R. A. Abramovitch J. Org. Chem., 43 1218 (1978). Anilines are obtained by reduction of the appropriate nitrobenzenes with iron powder in acetic acid as reported by D. C. Owsley and J. 3. Bloomfield, Synthesis, 118 (1977). The o-alkoxymethyl- or o-alkylthiomethylnitro- benzenes VII are prepared via "Williamson Synthesis according to Equations 6a or 6b. Equation 6 6a) EMI19.1 EMI19.2 "Williamson Synthesis" has been widely used for the preparation of ethers as reviewed by W. Theilbeimer, Syn. Methods of Oro. Chem., Vol. VII, P. 112. Procedure 6a is most useful when R7X' is a alkylthio or a primary alkoxy group, and R1 and R2 are both H. The reaction is carried out by mixing o-nitrobenzyl chloride and sodium methoxide or sodium alkylmercaptide (for preparation see Org. Syn., Coll. Vol. II, 345) in methanol under reflux or at room temperature, respectively. Procedure 6a is, however, not applicable in cases where R5X' is a branched alkoxy whose corresponding alkoxide anion is a stronger base than it is a nucleo phile, and/or either R1 or R2 or both are alkyl groups. In the presence of a strong base and/or an alkyl subestituent on o-nitrobenzyl chloride the base-catalyzed elimination rather than the desired SN2 displacement occurs, giving rise to 2,2'-dinitrostilbene or other .o-nitroalkenylbenzenes. In order to avoid these un desired reactions, a more general procedure, 6b, can be employed. The appropriate benzyl alcohol is first treated with base, such as sodium hydride, in an inert organic solvent, typically tetrahydrofuran or glyme, followed by displacement on an alkyl halide, as described by C. A. Brown and D. Barton, Synthesis, 434 (1974), and B. A. Stoochnoff and N. L. Benoiton, Tet. Lett., 21 (1973). Alternatively, o-alkoxymethyl or o-alkylthio methylbenzenesulfonyl chlorides, XII, can be obtained from an appropriately substituted c-hydroxy-o-toluene- sulfonicacid-a-sultone, X , via ring-opening reaction with an alkoxide or alkylmercaptide anion as depicted in Equation 7. Equation 7 7a) EMI20.1 Reaction 7a is closely related to the alkyl- ation of acyloxides and acetamide with sultones as disclosed by J. H. Helberger et al., Ann., 565, 22 (1943). Conversion of the sulfonic acid salt to the sulfonyl chloride is then carried out according to the teaching of Or@. Synthesis, Coll. Vol. IV, 846, 693. Benzenesulfonamides of Formula XTV can also be derived from compound XIII as illustrated in Equation 8. Equation 8 8a) EMI21.1 Preparation of o-sulfamylbenzoic acid esters, XIII, from saccharin or sulfobenzoic acid anhydride is well known in the art, e.g., B. Loev and M. Kormendy, J. Org. Chem. 27, 1703 (1962). The esters XIII, can be readily reduced to the ethers XTV with diborane in a suitable organic solvent, e.g., tetrahydrofuran, in the presence of fifteen folds of boron trifluorideetherate under reflux for 18 hours, as described by R. P. Graber and M. B. Meyers, J. Org. Chern. 26, 4773 (1961). The o-alkylsulfinyl- and o-alkylsulfonylmethyl benzenesulfonylureas are made from their corresponding - allthiomethlben2enesulfonylureas b means of peroxide oxidation. Reaction of the sulfide-sulfonylurea with aqueous hydrogen peroxide in acetic acia at roor temperature for half an hour affords exclusively the sulfoxidesulfonylurea. If the sulfide or sulfoxide is allowed to react for 72 hours under the same conditions, the sulfone is obtained. Oxidation for 20 hours often results in a mixture of both sulfoxide and sulfone, which can be readily separated by column chromatography and eluded with ethyl acetate. Sul fonylureas described above are generally stable under these reaction conditions. They will however, split into heterocyclicamine and o-alkylsulfonylbenzene sulfonamide if heated. A general procedure for peroxide oxidation of sulfides to sulfones can be four. in the paper by A. M. Van Arendonk and E. C. Kliderer, J. Am. Chem. Soc., 62, 3521 (1940) Substituted benzenesulfonyl chlorides containing an ortho o-haloalkyl group can be made by methods known in the art. a-Chloroalkyl- and dichloromethylbenzenesulfonyl chlorides can be made by contacting the corresponding alkylben:enesulfonyl chlorides with with dichlorine monoxide in an inert solvent, most conveniently in the temperature range 40-80 . The degree of chlorination is determined by the relative quantity of dichlorine monoxide employed, (F. D. Marsh, U.S. Pat. 4,226,783 issued October 7, 1980). EMI23.1 A series of standard functional group transformations may also be used as described (J. F. Kins, A. Hawson, B. L. Huston, L.J. Danks, and J. Komery, Can. J. Chem., 99, 943 (1971) for 2-(chloromethyl)- benzenesulfonyl chloride (Equation 9). Equation 9 EMI23.2 Benzylic bromination using N-bromosuccinimide is useful in the preparation of o-bromoalkylbenzene- sulfonyl chlorides (Equation 10). Equation 10 EMI23.3 (W. B. Renfrow and M. Devadoss, J. Crc. Chem., AO, 1525 (1975)] The sulfonamides of Formula Va can be prepared by the four step reaction sequence shown in Equation 11. Equation 11 EMI24.1 Va - wherein R, R1, R2, R3 and R4 are as defined in Equations 1-5, with the exception that R cannot be NO2. fn step Ila, the o-nitrobenzylsulfonyl chlorides of Formula xv , which are well-known in the art, are treated with an amine of Formula XVa in an inert organic solvent such as methylene chloride, ethyl ether or tetrahydrofuran at 0-500. The amine may be taken in excess to act as an acid acceptor; or, alternatively, a tertiary amine such as triethylamine or pyridine may be used as an acid acceptor. Tne by-product amine hydrochloride is filtered off or washed out of the solvent with water and the product isolated by evaporation of the solvent. The reduction described in step llb is accomplished by treating a solution oS the compounds of Formule XVI in solvent such as ethanol, ethyl acetate, or diglyme, in t pressure. vessel, with. 50-1000 pounds per square inch of. hydrogen at 25-150 in the presence. of a. hydrogenation catalyst such as 5-10% pelladium absrobed on carbon. When the theoretical amount of hydrogen has been absorbed, the solution is cooled and the catalyst is removed by filtration. The product is then isolated by evaporation of the solvent. In the case where R " NO27 the reduction of step lib can be accomplished using Ammonium sulfide or sodium hydrosulfide instead of catalytic hydrogenation. This typ of procedure is described in Organic Svnthesis Coll. Vol. III, pgs. 242-3, John Wiley and Sons, Inc., New York and London (1955), the disclosure of which is herein incorporated by reference. The diazotization and coupling with sulfur dioxide, described in step 110, is accomplished in the following manner. A solution of the aniline of Formula XVII in a mixture of concentrated hydrochloric acid and glacial acetic acid is treated with a solu tion of sodium nitrite in water at -5 to 0 . After stirring for 10-15 minutes at O to insure complete diazotization, this solution is added to A mixture of an excess bf sulfur dioxide, and a catalytic amount of cuprous chloride in glacial acetic acid at 0-5 . The temperature is kept at 0-5 for 1/4 to 1 hour then raised to 20-25 and held at that temperature for 2-4 hours. This solution is then poured into a large excess of ice water. The sulfonyl chloride products, XVII can be isolated by filtration or by extraction into a solvent such as ethyl ether or methylene chloride followed.by evaporation of the solvent. The anination described in step 11d is conveniently carried out by treating a solution of the sulfonyl chloride of Formula XVII with an excess of anhydrous ammonia in a solvent such as ethyl ether or methylene chloride at 0-25 . If the product sulfonamide, Va, is insoluble it may be isolated by filtration followed by washing out the salts with water. ff the product sulfonamide is soluble in the reaction solution, it may be isolated by filtering C'ef the precipitated ammonium chloride and evaporation of the solvent. Ammonium salts can be prepared by alkylation as described in Equation 12. Equation 12 EMI27.1 wherein X" is a nucleofugic group, e.g. Cl#, Br#, I#, Various amides, ureas and carbamates may be produced by well-known reactions of the primary or secondary amine XVIII (at least one of R3 and R4 is H) with the desired acyl chloride, carbamoyl chloride, or chloroformate (Equation 13): Equation 13 e.g. EMI27.2 The a-haloalkylbenzenesulfonyl chlorides as prepared in Equations 9 or 10 are converted to the sulfonamides as previously described. The :-haloalkylbenzenesulfonamides may be converted to other required intermediates for this invention by treatment with appropriate nucleophiles, e.g., acetate ion as described in Equation 15. Equation 15 EMI28.1 The compounds of Formula XIX are useful intermediates in the preparation of compounds of this invention. The synthesis of heterocyclic amines has been reviewed in 'The Chemistry of Heterocyclic Compounds'0 a series published by Interscience Publ., New York and London. 2-Aminopyrimidines are described by D. J. Brown in The Pyrimidines, Vol. XVI of this series. The 2-amino-l,3,S-triazines are reviewed by K. R. Huffman and in The Triazines of this sameseries. The synthesis of triazines are also described by F. C. Schaefer, U.S. Patent No. 3,154,547 and by K. R. Ruffman and F. C. Schaeffer, J. Org. Chem. 28, 1816-1821 (1963). The preparation of the aminoheterocycles described by the following formulae are prepared by, for Example, methods described in EP 15683 EMI29.1 The synthesis of heterocyclic amine derivatives has been reviewed in The Chemistry of Beterocylic Compounds", a. series published by Interscience Publ., New York and London. 2-Aminopyrimidines are described by D, J. Brown in "The Pyrimidines", Vol. XVI of the above series. 2-Amino-1,3,5-triazines can be synthesized according to the methods described by z. M. Smolin and L. Rapport in "s-Triazines and Derivatives Vol. XIII of the same series. The preparation of fused ring pyrimidine amines are disclosed in various publications, such as: Braker et al., J. Am. Chem. Soc., 69, 3072 (1947); Mitter and Bhattacharya, Quart. J. Ind. Chem. Soc. 152 (1927), Shrag and Hitchings, J. Org. Chem., 16, 1153 (1951); Svab et al., Coll. Czech Commun. 32, 1582 (1967). Compounds of Formula Tb are prepared by the reaction of about two equivalents of aqueous sodium hydroxide with the compounds of Formula I in which R10 is C1-C4, preferably methyl (Ia) , followed by acidification of the solution. This process is illustrated in Equation 16, wherein R, R1, R2, R8 and A are as previously defined. Equation 16 EMI30.1 The reaction is carried out over the course of 2-6 hours in water, by stirring the compound of Formula Ia with two equivalents of sodium hydroxide or potassium hydroxide at ambient temperature a The aqueous solution is then acidified with hydrochloric or sulfuric acid, which causes the compound of Formula Ib to precipitate out. It is then isolated by filtrate tion. Compounds of Formula are prepared by reacting an appropriately substituted compound of Formula I in which R10 is C1-C4 alkyl, preferably methyl (Ia) , with a dialkylaluminum-N-alkylamide derivative, as shown in Equation 17,wherein R, R1, R2, R3, R4, R8 and A are as previously defined. Equation 17 EMI31.1 Ic The intermediate alkylaminoaluminum compounds are prepared according to A. Basha, M. Lipton and S. W. Weinreb, Tetrahedron Letters, 4171 (1977) by reacting the trialkylaluminum, preferably trimethyl- aluminum, and the corresponding amine. The (CH3)2AL-NR3R4 intermediate is co-mingled with a suspension of the compound of Formula VIII in an inert solvent, preferably methylene chloride, and the mixture is refluxed for one to twenty-four hours. The product is isolated by adding aqueous hydrochloric acid to decompose the resulting complex, and then evaporating the methylene chloride phase. The desired. product can be further purified by recrystallization or column chromatography. Compounds of Formula Tc can be prepared by reacting an appropriately substituted sulfonamide of Formula Vb with the methylcarbamate of the appropriate aminoheterocycle XX in the presence of an equivalent amount of trimethylaluminum, as shown in Equation 5, wherein P, Rl, R2, R8 and A are as previously defined. Equation 18 EMI32.1 The reaction of Equation 18 is best carried out in an inert solvent such as methylene chloride at 10-45 and atmospheric pressure. The preferred mOd. of addition is to add the trimethylaluminium to a olu- tion or slurry of the sulfonamide Vb t a mildly exo- thermic reaction occurs accompanied by the evolution - of gas. The addition of the heterocyclic carbamate XXX) is then made and the mixture is stirred at ambient to reflux temperature for 6 to 48 hours. The addition of aqueous acid such as dilute hydrochloric or acetic acid removes organic salts from the product contained in the organic phase. Evaporation of the methylene chloride yields the crude product, which can be purified by recrystallization or column chromatography. Some of the compounds of Formula I can also be prepared by the method shown in Equation 19, using the novel intermediates of Formula II, wherein L, R, R1, R2, R3, R4 and R10 are as previously defined, and wherein Z is CH or N, and R12 is C1-C3 alkyl. 19a) Equation 19 EMI33.1 EMI33.2 EMI33.3 Reaction Step(19a) In Reaction Step (19a), an aromatic sulfonamide S of Formula V is contacted with a heterocyclic isocyanate of Formula XV to yield a N-(haloheterocyclicaminocarbonyl)aromatic sulfonamide of Formula II. The heterocyclic isocyanates used in Reaction (19a) may be prepared according to methods described in Swiss Patent 579,062, U.S. Patent 3,919,228, U.S. Patent 3,732,223 and Anqew Chem. Int. Ed. 10, 402 (1976), the disclosures of which are herein incorporated by reference. The aromatic sulfonamide and the heterocyclic isocyanate are contacted in the presence of an inert organic solvent, for example, acetonitrile, tetraby- drofuran (THF), toluene, acetone or butanone. Optionally, a catalytic amount of a base, such as 1,4-diazabicyclol2.2.230ctane (DABCO), potassium carbonate, sodium hydride or potassium tert-butoxide, may be added to the reaction mixture. The quantity of base constituting a catalytic amount would be obvious to one skilled in the art. The reaction mixture is preferably maintained at a temperature of about 25 to 1109, and the product can generally be recovered by cooling and filtering the reaction mixture. For reasons of efficiency and economy, the preferred solvents are acetonitrile and TEF, and the preferred temperature range is about 60 to 8S C. Reaction Steps(lgb) and(19c) In Reaction Steps (19b) and (19c), one or two of the halogen atoms on the heterocyclic ring of the compound of Formula ii is displaced by a nucleophilic species. Generally this may be done by contacting the compound of Formula Ii either with alkanol, R12tH or with alkoxide, -OR12, where R12 is as defined above. Thus, in Reaction Step (lob) a compound mula II can be contacted with at least one equivalent of alkanol, Ri20H. This reaction is sluggish, however, and it is preferred to contact the compound of Formula II with at least two equivalents of alkoxide, OR12. The alkoxide can be provided in a number of ways: (a) The compound of Formula II can be suspended or dissolved in an alkanol solvent, R112OH, in the presence of at least two equivalents of alkoxide, OR12. The alkoxide can be added directly as alkali metal or alkaline earth. metal alkoxide or can be gen erated by the addition to the alkanol solvent of at least two equivalents of a: base capable of generating alkoxide from the solvent. Suitable bases include, but are not limited to, the alkali and alkaline earth metals, their hydrides and tert-butoxides. For example, when R12 is methyl, the compound of Formula II could be suspended or dissolved in methanol in the presence of two equivalents of sodium methoxide. Alternatively, two equivalents of sodium hydride could be used in place of the sodium methoxide. (b) The compound of Formula II can be suspended or dissolved in an inert solvent in the presence of at least two equivalents of alkoxide, ORI Suitable inert solvents include, but are not limited to, acetonitrile, TEF and dimethylformamide. The alkoxide may be added directly as alkali metal or alkaline earth metal alkoxide or may be generated from alkanol and a base as described in (a) above. For example, when R12 is methyl, the compound of Formula II could be suspended or dissolved in THF in the presence of two equivalents of sodium methoxide. Alternatively, two equiva lents each of methanol and sodium hydride could be used instead of sodium methoxide. For reasons of economy and efficiency, procedure (a) is the more preferred method. It should be noted that two equivalents of alkoxide are required for Reaction Step (19b) whereas only one equivalent of alkanol is needed for the same process. This difference is due to the reaction which is believed to occur between the alkoxide and the sulfonyl nitrogen of the sulfonamide of Formula II. When alkoxide is used, the first equivalent of alkoxide removes a proton from the sulfonyl nitrogen, and it is only the second equivalent which effects displacement of the halogen. As a result, two equivalents of alkoxide are required. The resulting salt must be acidified, e.g., with sulfuric, -*y=drochloric or acetic acid, to yield a compound of Formula XXI. Applicant, of course, does not intend to be bound by the mechanism described above. In Reaction Step (19c), a compound of Formula XVI is contacted with either one equivalent of methanol, or with two equivalents of methoxide, -OCH3. When methoxide is used, it may be provided in either of the methods described above in connection with Reaction Step (19b), and the resulting salt can be acidified to yield a compound of Formula XXII. When R12 = CH3, Reaction Steps (19b) and (19c) may be combined. Thus, a compound of Formula II may be contacted either with at least two' equivalents of methanol or with at least three equivalernts of methoxide. For a compound of Formula II, certain reaction conditions will favor displacement of only one of the chlorines. These conditions are the use of low temperatures and, when alkoxide is used, the slow addition of the stoichiometric amount of alkoxide or alkoxide-generating base to the medium containing the compound of Formula II. When alkoxide is used, both Reaction Steps (19b) and (19c) are preferably run at temperatures within the range of about -100 to 800C, the range of about 0 to 25 C being more preferred. Reaction Steps (19b)and (19c) are more sluggish when alkanol is used instead of alkoxide, and more drastic conditions are required for the reaction to go to completion. Thus, higher tem peratures, up to and including the boiling point of the alkanol itself, are required. As shown in Equation 20,compounds of Formula XXIII, in which R, R1, R2, L and A are as previously defined, are prepared by the reaction of an appropriately substituted sulfonamide, (V), with a heterocy- clic isothiocyanate of Formula XXIV. Equation 20 EMI38.1 The Reaction of Equation 20 is best carried out by dissolving or suspending the sulfonamide and isothiocyanate in a polar solvent such as acetone, acetonitrile, ethyl acetate or methyl ethyl ketone, adding an equivalent of a base such as potassium carbonate and stirring the mixture at ambient temperature up to the reflux temperature for one to twenty-four hours In some cases, the product precipitates from the reaction mixture and can be removed by filtration. The product is stirred in dilute mineral acid, filtered and washed with cold water. If the product does not precipitate from the reaction mixture it can be isolated by evaporation of the solvent, trituration of the residue wth dilute mineral acid. and filtering off the insoluble product. The heterocyclic isothipcyanates which are used in the procedure of Equation 20 are prepared, for example, according to the method of Japan Patent Application Pub: Kokai 51-143686, June 5, 1976, or that of W. Abraham and G. Barnikow, Tetrahedron 29, 691-7 (1973). Many of the compounds of Formula I may be pre pared as shown in Equation 21 by reaction of an appro priately substituted o-hydroxymethylbenzenesulfonyl- urea, Ia, with an appropriate acid chloride. A, R, R1, R2, R8, and R11 being as previously defined. Equation 21 EMI39.1 The reaction of Equation 21 is best carried out in inert aprotic solvents such as methylene chloride, tetrahydrofuran or acetonitrile at 0-800C. An excess of the acid chloride is used and at least one equivalent of a tertiary amine such as pyridine, triethylamine or 4-dimethylaminopyridine. Isolation is achieved by evaporation of solvent and recrystallization from suitable solvents such as l-chlorobutane, ethyl acetate or ethyl ether or by column chromatography over silica gel. Other compounds of Formula I maybe prepared as shown. in Equation 22 by- reaction of an appropriately substituted o-hydroxymethylbenzenesulfonylurea, Ia with an appropriate isocyanate A, R, R1, R2 R8 and R12 being as previously defined. Equation 22 EMI39.2 The reaction of Equation 22 is best carried out in inert aprotic solvents such as methylene chloride, tetrahydrofuran or acetonitrile at 0-80 C. An excess of the isocyanate is used and a catalyst such as dibutyltinidlaurate or 1,4-diaza(2,2,2-bicyclooctane (DABCO). Isolation is achieved by evaporation of solvent and recrystallization from suitable solvents such as l-chlorobutane, ethyl acetate or ethyl ether or by column chromatography over silica gel. Other compounds of Formula I may be prepared as shown in Equation 23 by reaction of an appropriately substituted o-hydroxymethylbenzenesulfonylurea, Ia with an appropriate chloroformate. A, R, , R2} R8 and being as previously defined. Equation 23 EMI40.1 The reaction of Equation 23 is best carried out in inert aprotic solvents such as methylene chloride, tetrahydrofuran or acetonitrile at 0-800C. An excess of the chlotocarbonate is used and at least one equivalent of a tertiary amine such as pyridine, triethylamine or 4-dimethylaminopyridine. Isolation is achieved by evaporation of solvent and recrystalli zation from suitable solvents such as l-chlorobutane, ethyl acetate or diethyl ether or by column chroma tography over silica gel. The preparation of compounds of Formula If where R1 = R2 = H; and R, R8 and A are as previously defined, may be carried out as shown in Equation 24. Equation 24 EMI41.1 The carboxylic acid, Ie, may be converted to the alcohol by reduction with 4-5 equivalents of borane-THF reagent in THF at ambient pressure and temperature for 4 to 18 hours. Isolation is achieved by drowning in dilute acid followed by extraction of the product with a solvent such as methylene chloride, ethyl acetate or ethyl ether. Evaporation of solvent and crystalliztion or column chromatography on silica gel affords. the pure alcohol If. The carboxylic acids, Ie , may be prepared by hydrolysis of the corresponding methyl esters as shown in Equation 25; R, R8 and A being as previously defined. Equation 25 EMI41.2 When A is a pyrimidine type structure, the methyl esters are best hydrolyzed by dissolving in a solution of 80 parts ethanol, 10 parts water and 10 parts potassium hydroxide. The mixture is stirred at ambient temperature for 18 hours followed by pouring into a large excess of water and acidifying to a pH of 2.0. The pure acid, VI, precipitates and is filtered and washed with water. When A is a triazine and X or Y is alkoxy, the hydrolysis is best performed by dissolving the ester in a solution of potassium t-butoxide in dimethyl sulfoxide at ambient temperature for two hours. Addition of a large volume of water followed by acidification to a pH of 2.0 precipitates the acid, Ie. The preparation of esters of Formula Tq is described in European Patent Application 7687. Compounds of Formula Tftay also be prepared by treatment of the carboxylic acids, Ie or the methyl esters, Ig , with lithium aluminum hydride by the procedures described by R. F. Nystrom and W. G. Brown, J. Am. Chem. Soc. 69, 2548 (1947) and R. B. Moffett, Organic Synthesis, Coll. Vol. 4, 834 (1963). Reduction of the esters with sodium bis (2-methoxyethoxy) aluminum hydride is described in M. ester and L. E. Fieser, Reagents for Organic Synthesis, John Wiley 6 Sons, New York, Vol. 5, P. 596 (1975). The preparation of compounds of Formula Ij where R1=H and R2-CH3 may be carried out as shown in Equation 26. Equation 26 EMI42.1 Compounds of Formula Ih are treated with one equivalent of lithium aluminum hydride (LAH) in a solvent such as ether, tetrahydrofuran or glyme at -2a--F- 250C for 1 to 6 hours. Next there is a successive dropwise addition of an equivalent number of ml of water as grams of LAH followed by an equal number of ml of 15% sodium hydroxide followed by 3 times that number of ml of water. This produces a dry granular precipitate of aluminum oxide which is easy to filter. The aqueous phase is then acidified with dilute acid and the product extracted with solvent such as methylene chloride, ethyl acetate or ethyl ether. Evaporation of solvent and crystallization or column chromatography on silica gel affords the pure alcohol, Ij. Compounds of Formula Ih are prepared by the reaction. shown in Equation 27 usinq an excess of methyl lithium with a carboxylic acid deriva tive of Formula Ie. Equation 27 EMI43.1 Compounds of Formula Te are restricted to structures in which the substituents R, Z, X and Y contain no displaceable halogens, NO2 or CN. An excess of methyl lithium in a suitable solvent such as diethyl ether, hexane, pentane or benzene is added to a solution or slurry of Ie in a similar solvent at temperatures between -100 and OOC. The mixture is allowed to warm to room temperature and stir for 30 minutes. Aqueous acid is then added and the compound Ih is extracted into a suitable solvent to free it from salts, followed by evaporation of the solvent. Purification is by chromatography on silicgael. Another procedure for the preparation of compounds of Formula Ij is the reaction of excess methyl lithium with the corresponding aldehyde Tk as shown in Equation 28. R, R8, A being as previously defined. Equation 28 EMI44.1 Compounds of Formula Tic are- restricted to structures in which the substituents R, Z, X and Y contain no displaceable halogens; NO2 or CN. An excess of methyl lithium in a suitable solvent such as diethyl ether, hexane, pentane or benzene is added to a solution or slurry of XI in a similar solvent at temperatures between -100 and OOC, The mixture is allowed to warm to room temperature and stir for 30 minutes. Aqueous acid is then added and the compound Ij is extracted into a suitable solvent to free it from salts followed by evaporation of the solvent. Purification is by chromatography on silica gel. Aldehydes of Formula Ik are prepared by the procedure of Equation 29. R, R9 and Rg being as previously defined. Equation 29 EMI45.1 Following the procedure of R. Xanayawa and T. Tokoroyama, a solution of sodium. bis(2-methoxy- ethoxy)aluminum hydride in THF is reacted with one equivalent of morpholine. To this solution at -400C is added. methyl ester of Formula Ig and the solution is allowed to wa= to 25 C. The product is isolated by addition of aqueous acid and extraction into ether or methylene chloride. Evaporation of solvent and crystallization or column chromatography on silica gel affords the pure aldehyde, Tg. Aldehydes of Formula IK may also be prepared from the esters of Formula Ig by treatment with diisobutylaluminum hydride according to procedures of E. Winterfeldt, Synthesis, 617 (1975). The preparation of compounds of Formula Im where R1=R2=CH3 may be prepared as shown in Equation 30. Equation 30 EMI46.1 Compounds of Formula Tm are prepared by the reaction of an excess of methyl lithium with acetophenones of Formula Ih. Compounds of Formula Ih are restricted to structures in which the substituents R, Z, X and Y contain no displaceable halogens, N02 or CN. All excess of methyl lithium in a suitable solvent such as diethyl ether, hexane, pentane or benzene is added to a solution or slurry of Tb in a similar solvent at temperatures between -100 and OOC, The mixture is allowed to warm to room temperature and stir for 30 minutes. Aqueous acid is then added and the compound Im is extracted into a suitable solvent to free t from salts followed by evaporation of the solvent. Purification is by chromatography on silica gel. Agriculturally suitable salts of compounds of Formula I are also useful herbicides and can be prepared in & number of ways known to the art. For example, metal salts can be made by treating compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, carbonate or hydride). Quaternary amine salts can be made by similar techniques. Salts of compounds of Formula I can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct treatment of an aqueous solution of a salt of a compound of Formula I (e.g., alkali metal or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water, e.g., a copper salt, and can be separated by filtration. Exchange may also be effected by pissing an aqueous solution of a salt of a compound of Formula I (e.g., an alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged. ln this method, the cation of the resin is exchanged for that of the original salt and the desired product is eluded from the column. This method is particularly useful when the desired salt is water soluble, e.g., a potassium, sodium or calcium salt. Acid addition salts, useful in this invention, can be obtained by reacting a compound of Formula I with a suitable acid, e.g-., p-toluenesulfonic acid, trichloroacetic acid or the like. The reader is referred to all references cited above for further information, which accordingly will not be repeated herein. In the following examples, all parts are by weight and temperatures in OC unless otherwise indicated. Example 1 2-(Dichloromethyl)-N-[(4-methoxy-6-methylmyrimidin-2-yl)aminocarbonyl]benzenesulfonamide o-Dichloromethylbenzenesulfonamide (2.40 g, 10 =ol) was treated with thionyl chloride (25 ml) and heated to reflux for 16 hrs. Volatiles were removed under vacuum and the residue was treated with thionyl chloride (20 ml) and refluxed for 22 hrs. Thionyl chloride was removed under vacuum, and two portions of dry toluene were added and evaporated in order to remove last traces of SOC12. The crude product in toluene (45 ml) was transferred to a threeneck flask, treated with dry pyridine (1.0 ml), and then treated slowly with phosgene such that a slow reflux was maintained while the internal temperature was held at ca. 70 for 1.0 hr. Excess phosgene was removed using a stream of dry nitrogen. IR of the crude residue showed only a trace NH stretch and featured a strong band at 2250 The crude isocyanate in dry acetonitrile (15 ml) was treated with 2-amino-4-methoxy-6-methyl pyrimidine (1.39 g, 10 mmol). The amine dissolved and a precipitate formed. The mixture was stirred for 56 hrs, filtered, and the solid was washed with ca. 3 ml acetonitrile to give 1.51 g of off-white solid, mp 183-185 C. 1H nmr: DMSO-d6 10.3 (brd s,NH), 8.25-7.58 (m, featuring singlet at 8.13) , 6.62 (s) 3.98 (s), 2.42 (s). Recrystallization from CHCl3 gave 0.89 g, mp 189-190 (dec.). Mass spec: measured 404.0083; calc'd for C14H14N404SC12 404.0110. Anal. Calc'd: C, 41.49; H, 3.48; N, 13.83 ound : C, 41.22; H, 3.21; N, 13.83 41.12 3.50 13.67 Example 2 2-(Dichloromethyl)-N-[(4m6-dimethylpyrimidin-2-yl) aminocarbonyl benzenesulfonamide 2-(Dichloromethyl)-benzenesulfonyl isocyanate, prepared from 10 mmol of sulfonamide as described in the synthesis of Example 1, was treated with acetonitrile and 2-amino-4,6-dimethylpyrimidine (1.23 g). The mixture was stirred at room temperature for 18 hrs, cooled, and filtered to provide 1.08 g of white solid, mp. 195-197 (Dec.) 1H nmr CDCl/DMSO-d6 10.53 (s.). 8.20-7.90 (m, featuring singlet at 8.00), 7.87-7.43 (m) 6.83 (s), 2.43 (s). ZR (nujol) featured bands at 1710 and 1600 cm Mass spectrum featured m/e 388.0174 (calc'd for C14H14Cl2N4O35 388.0163); 150.0627 (calc'd for C7H7N3 150.0667). Example 3 2-(Dichloromethyl)-N-[(4-methoxy-6-methyl-1,3,5 triazin-2-yl)-aminocarbonyl)benzenesulfonamide 2-(Dichloromethyl)benzenesulfonyl isocyanate prepared from 10 mmol of sulfonamide as described in the synthesis of Example 1, was treated with acetonitrile (15 ml) and 2-amino-4-methoxy-6-methyl-1,3,5- triazine (1.40 g). The mixture was stirred for 18 hrs. and filtered. The filtrate was evaporated and recrystallized from acetone to give 0.78 g of white solid, mp 168-169 (dec). Únmr #TMS DMSO-d6 8.377.50 (m, featuring singlet at -8.07), 7.00-6.17 (brds), 4.00 (s), 2.48 (s). IR (nujol) featured bands at 1720 and 1590 on-1 Mass spectrum featured 264.9367 (calc'd for c8B5cl2N03s 264.9367) and 140.0687 (calc'd for C5H8N4O 140.0697). Anal. Calc'd:C, 38.44; H, 3.23; N, 17.24 Found: C, 38.74; H, 3.13; N, 16.90 38.59; 3.11 17.04 - Example 4 2-(Chloromethyl)-N- E (4,6-dimethoxy-1,3,5-triazin- 2-yl)aminocarbonyl]benzenesulfonamide A solution of 4,6-dichloro-1,3,5-triazin-2-yl isocyanate (3.10 g, 16.2 mmol) in acetonitrile (15 ml) was contacted with 2-(chloromethyl)benzene sulfonamide (3.34 g, 16.2 mmol) and stirred for 20 hrs at 250. The mixture was heated at 50 for 2 hrs, cooled and filtered to provide 3.86 g, mp 162-170 , which was contacted with sodium methoxide (30 mmol) in methanol (60 ml) at 20-25 for 16 hrs. Water (100 ml) was added and the mixture was filtered and neutralized by addition of hydrochloric acid. Filtration and drying gave 2.20 g of white solid, mp 150-152 (dec.). 1H nmr TMS 11.0 (s), 8.30-7.50 (m), 5.23 (s), @@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@@ 4.03 (s). IR (nujol) featured absorption bands centered at 3200, 1720, 1610 and 1560 cm-Ú. Anal. Calc'd for C13H14N5ClO5S C, 40.26; X, 3.64; N, 18.06. Found C, 38.60; H, 3.62; N, 18.40. Example S 2-(Chloromethyl)-N-X(4,6-dimethoxY;vrimidin-2-yl)- aminocarbonyl]benzenesulfonamide A solution of 2-(chloromethyl-N-(butylamino- carbonyl)benzene sulfonamide (1.33 g, 4.38 mmol) and diazabicyclo[2.2.2]octane (5 mg) in xylene (12 ml) was heated at reflux and contacted in portions with phosgene (1.0 ml. condensed phase). After 2.0 hrs at reflux, the mixture was cooled to room temperature, decanted, and volatiles were removed to give 1.56 g of crude product. The IR spectrum of 2-(chloromethyl)- benzenesulfonyl isocyanate featured a strong band at 2250 cm-Ú. The crude sulfonyl isocyanate was contacted with acetonitrile (10 ml) and 2-amino-4,6-dimethoxy- pyrimidine (0.68 g, 4.4 mmol) and stirred for 16 hrs Filtration gave 1.18 g of white solid, mp 192.1930. The sample was dissolved in 0.5 N NaOH, filtered and pH adjusted to 6.5. The mixture was cooled and filtered and the solid washed with ice water and dried to give 0,90 g of white solid. 1H nmr #DMSO-d6 12.7 Cord s, 10.50 (s, 1H) 8.13-7.97 (m, 1H), 7.73-7.40 (m, 3H), 5.90 (s, 1H), 5.10 (s, 2H), 3.87 (s, 613). Anal. Calc'd: C, 43.47; X, 3.91; N, 14.48; S, 8.29 Found : C, 41.76; H, 3.82; N, 13.94; S, a. 23. Example 6 2-(Chloromethyl)-N-[(4,6-dimethyulpyrimdin-2-yl) aminocarbonyli benzenesulfonamide A mixture of 2-(chloromethyl)ben:ene sulfonamide (4.11 g, 20 mmol) and thionyl chloride (35 ml) was heated to reflux for 36 hrs. Thionyl chloride was removed under vacuum. The residue was contacted with toluene (100 ml) and pyridine (2 ml), heated to 70 , and treated in portions with phosgene (excess) for 2.0 hrs. The mixture was cooled, and the toluene-soluble portion was decanted and evaporated to give a residue which was treated with acetonitrile (15 ml) and 2amino-4,6-dimethylpyrimidine (1.70 g, 13.8 mmol). After 16 hrs, the solid was filtered and washed with acetonitrile to give 1.45 g of solid which was taken up in 1.0 N NaOH and filtered. The pH was adjusted to 6.0 with dilute hydrochloric acid and the solid was filtered and dried to provide 1.34 g of cream colored solid, mp 176.1770 (dec.). IR (KBr) featured absorption bands at 33402300, 1700 (strong), 1600, 1500, -1440, 1340 Example 7 2-(1-Chloroethyl)-N-[4,6-dimethoxy-1,3,5-triazin 2-yl)aminocarbonyl]benzenesulfonamide A solution of 4,6-dichloro-1,3,5-triazin-2-yl isocyanate (2.27 g, 11.9 mmol) in acetonitrile (20 ml) was contacted witch 2-(1-chloroethyl)benzenesulfonamide (2.61 g, 11.9 mmol) and stirred at 250 for 18 hrs. and at 50 for 2.0 hrs. Solvent was evaporated to give 4.95 g of residue. 1H nmr CDCl3 11.35 (s), 8.87 (s), 9.33 - 7.30 (m), 6.18 (q, J = 7Hz), 5.50 (s), 1.88 (d, J= 7 Hz). Mass Spectrum: observed 244.9915 (calc'd for C9H8O3NClS 244.9913), 163.9643 (calc'd for C3H2N4Cl2 16.9656). A solution of the above sulfonyl urea in methanol (20 ml) was contacted with a solution of sodium methoxide (36 mmol) in methanol (65 ml) at 0 for 3.0 hrs. Solvent was evaporated and the residue was taken up in water (120 ml), filtered, and pH was brought to 5.0 g with dilute HCl. The mixture was cooled and filtered and the solid was washed with the water and dried to give 3.52 g of white solid, mp 148-150 (dec.), 1H nmr (CD3)2CO 8.30-7.42 (m), 6.32 (q, J=7Hz), 4.08 (s), 2.93 (brds), 1.88 (d, J=7Hz). Mass spectrum shoved: 244.9912 (calc'd for C9H8O3NCl5 244.9913) 156.0616 (calc'd for C5H8O2N4 156.0647) Anal. Calc'd: C, 41.85; H, 4.01; N, 17.43 Found : C, 41.92; E, 4.05; N, 17.02 Example R 2-(1-Pyrrolidinylmethyl-N-[(4,6-dimethoxypyrimidin 2-yl)aminocarbonyl]benzenesulfonamide, hydrochloride A slurry of 2-(chloromethyl)-N-[(4,6-dimethoxy- pyrimidin-2-yl]aminocarbonyl]benzenesulfonamide (1.00 g) in dimethylformaide (5 ml) was contacted with pyrrolidine (0.45 ml) and stirred for 3.5 hrs. Volatiles were removed under vacuum and the residue was taken up in methanol. Solvent was removed and the water (15 ml) was added and the pH was adjusted to 6.0 by addition of dilute hydrochloric acid. Cooling and scratching produced a white solid which was collected and dried to give 488 mg, m.p. 117-123 A 400 mg sample was crystallized from acetonitrile to give 269 mg. m.p. 132-134 C. 1H nmr #CDCl, 13.0-11.0 (brds 2H), 8.63 (s, 1 NH), 8.37-8.20, 8.05-7.90, and 7.70-7.33 (m, 4H), 5.68 Is, 1H), 5.00 (s, 2H), 3.90 (s, 6H), 3.70-2.90 (n, 4H), 2.30- 1.90 (m, 4H). ZR (KBr) 3650-2200, 17.10, 1610, 1580, 1450, 1360, 1200, 1165 are major absorption bands. Anal. Found C, 44.99; H, 5.17, N, 14.56 Calc'd for C18H23N5O5S.HCl C, 47.21t H, 5.28; N, 15.30 Example 9 2-(1-Pyrrolidinylmethyl)-N-[(4,6-dimethoxypyrimidin2-yl)aminocarbonyl]benzenesulfonamide A slurry of 2-(chloromethyl)-N-[(4,6-dimethoxy- pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide (1.00 g) in dimethylformamide (5 ml) was contacted with pyrrolid ine (0.45 ml) and stirred for 2.5 hrs. Volatiles were removed under vacuum and the residue was washed several times with ether, taken up in methanol and treated drop wise with a ca.0.5 % solution of dry hydrochloric. acid in methanol to adjust the apparent pN to 6.5-7.0. Volatiles were again removed to provide 1.34 g. of glassy foam which was chromatographed on silica gel eluting with 2/1 ethyl acetate/methanol. Residues from the major fractions were taken up in warm chloro- form and evaporated. Addition of a small volume of -acetonitrile yielded, upon cooling and scratching, a total of 280 mg of white solid, up 138-140 (dec). 1H nmr #CDCl3 8.10-7.90 (m, 1H), 7.67-7.10 (m. 4H, featuring NH singlet at 7.57), 5.50 (s, 1H), 4.60 (s, 2H), 3.72 (s, 6H), 3.43-3.10 (m, 4H), 2.30-1.90 (m, 4H). IR (XBr) 3650-2300, 1660, 1600, 1450, 1370, 1280, 1150, and 1110 cm 1 were major absorption bands. Anal. Calc'd for C18H23N5O5S C, 51.29; H, 5.50; N, 16.62 Found: C, 50.40; H, 5.29; N, 15.86 Contacting a CDCl3 solution of the above compound with dry hydrochloric acid produced the same substance described in Example 8 as judged by H nmr and b spectral data. Example 10 2-(1-Chloroethyl)benzenesulfonyl chloride A solution of 2-ethylbenzenesulfonyl chloride (obtained by chlorosulfonation of ethylbenzene) (7.78 g) in carbon tetrachloride (5.0 ml) was contacted with a solution of dichlorine monoxide (82 mmol) in carbon tetrachloride (100 ml) and the mixture was heated in a closed system at 50.600 for 16 hrs. The mixture was dried MgSO4) and volatiles were removed under vacu-. The residue was kugelrohr distilled to give 7.63 g ow colcrless oil, bp 75-80 (0.15 mm). 1H nmr #CDCl3 8.20-7.35 (m). 6.13 (c, J-7H-), 1.90 (d, J=7Hz). Example 11 2-Dichloromethylbenzene sulfonaride A solution of o-methylbenzenesulfonyl chloride (7.97 g, 42 mmol) in CCl4 (10 ml) was contacted with a solution of C120 in CCl4 (108 ml, 96 mmol) and the mixture was heated at 50 for 23 hrs. The cooled solution was purged witb a stream of nitrogen dried (MgSO4), and evaporated to give 10.1 g of white.solid. 1H nmr: 8.43-7.47 (m, featuring 2 singlet at 7.82) The product sulfonyl chloride was dissolved in tetrahydrofuran (50 ml) and was added to a solution'of ammonia (2.7 ml at -780) in tetrahydrofuran (100 ml) at -780. The mixture was allowed to warm slow to 5 . Solvent was removed under vacuum, and the residue was take. up in CH2C12, washed with water, dried, and evaporated to give 8.3 g of solid. Recrystallization from CHCl3 gave 5.34 g of shiny plates, m.p. 131-132 . 1H nmr # acetone-d6 8.33-7.47 (m. featuring s at 8.00), 7.30-6.87-(brds). Mass spec: measured 238.9560. Cacl'd. for C7H7Cl2NO2S, 238.9574. Example 12 2-(Bromomethyl)benzenesulfonyl chloride A solution of toluenesulfonyl chloride (4.5 g, ca. 85/15 mixture of ortho/para isomers) in carbon tetra chloride (40 ml) was contacted with N-bromosuocinimide (4.3 g) and azobisisobutyronitrile (50 mg) and heated to reflux for 22 hrs. The cooled mixture was filtered and the solvent was evaporated to give 6.33 g of yellow oil. Kugelrohr distillation provided 4.31 g, b.p. 90 98 (0.2 mm). 1H nmr #CDCl3 8.46-7.25 (m), 5.0 (s, area 47), 4.58 (s, ares 12), 2.76 and 2.47 (singlets for unchanged toluenesulfonyl chloride contaminant). The ortho/para ratio of bromomethyl compounds was 80/20. Example 13 2-(Hydroxymethyl)benzenesulfonic acid, sodiur salt A solution of o-benzaldehyesulfonic acid, sodium salt (120 g) in water (2 1) was contacted in portions with sodium borohydride (21.6 g) and the solution was .stirred for 48 hrs , The pH of the solution was ad juster to 1. by addition oi hydrochloric acid. Water was removed under reduced pressure, and the residue was added to a large thimble and continuously extracted with ethanol. Concentration and cooling provided 1C2 of white solid, m.p. > 300 . Evaporation of the mother liquor gave an additional. 13.4 c of product. 1. H #DSS 8.10-7.85 (m), 7.77-7.26 (m). 5.13 (s), 4.70 (s) D20 l s-(Chloromethyl)benzenesulfonyl chloride 2-(Hydroxymethyl)benzenesulfonic acid, sodium salt (76 g) was contacted with phosphorus oxychloride (375 ml) and the stirred mixture was contacted in portions with phosphorus pentachloride (76 g). The mixture wa: heated at 60-70 for two days. Phosphorus oxychloride was removed under vacuum and the residue was contacted with toluene (700 ml) and decanted into water. The organic layer wac washed with water and brine, dried (MgSO4) and evaporated. The product was kugelrohr distilled 90-100 , 0.2 =m) to give 56 g of white solid, m.p. 43-45 . 1H nmr: #COCl2, 8.17-8.00 (m), 7.90 7.40 (m), 5.10 (s). 3 Example 15 2-(Chloromethyl)benzenesulfonamide A solution of ammonia (5.2 ml) in tetrahydrofuran (250 ml) at -70 was contacted rapidly with a solution of 2-(chloromethyl)benzenesulfonyl chloride (21.8 g) in tetrahydrofuran (125 ml). The stirred mixture was allowed to warm to 0 and volatiles were removed under vacuum. The residue was contacted with ethyl acetate and a small volume of water. The organic layer was dried (MgSO4) and evaporated to give 19.8 g of white solid, m.p. 156-157.5 . Recrystallization from toluene/ ethyl acetate gave a sample with m.p. 157-160 . 1H nmr #(CD3)2CO 8.16-7.35 (m), 6.75 brds), 5.20 (s), 3.08 (s). Example 16 2-(1-Chloroethyl)benzenesulfonamide A solution of ammonia (1.2 ml) in tetrahydrofuran (100 ml) at -70 was contacted rapidly with a solution of 2-(1-chloroethyl)benzenesulfonyl chloride (4.32 g, 18.1 mmol) in tetrahydrofuran (50 ml). The stirred mixture was allowed to warm to o and volatiles were removed under reduced pressure. The residue was taken up in ethyl acetate and washed with a small volume of water and brine. The dried (MgSC4) solution was evaporated to give 4.7 g of off white solid which was recrystallized from chloroform to give 3.13 c, m.p. 121 122 . 1H nmr #(CD3)2CO 8.25-7.30 (m), 6.93 (brds), 6.25 (q, J - 7Bz), 3.17 (s), 1.96 (d, J = 7Hz.) - Example 17 2-(Bromomethyl)benzenesulfonamide A solution of ammonia (1.0 ml) in tetrahydrofuran (50 ml) at -78 was contacted dropwise with a solution of a 60/40 mixture of 2-(bromomethyl)benzenesulfonyl chlorde/4-(bromomethyl)benzenesulfonyl chloride (4.52 g) in tetrahydrofuran (20 ml). The stirred mixture was allowed to warm to 0 and volatiles were removed in vacuo. The residue was contacted with water (50 ml) and extracted three times with ethyl acetate. Combined organic portions were washed with brine, dried, and evaporated to give 4.00 g of white solid. 1H nmr #(CD2)2CO 8.15-7.20 (m), 6.7-6.3 (m, NH), 4.95 (q, area 21V, 4.55 (s, area 18), consistent with a ca-. 60/40 mixture of 2-(bromomethyl)-/4-(bromomethyl)- benzenesulfonamides. The sample was fractionally recrystallized from chloroform, but without significant change in isomeric content. Example 18 A solution of -(chloromethyl)benzenesulfonamide (2.00 g, 10 mmol) in acetonitrile (20 ml) was contacted with pyrrolidine (1,6 ml, 20 mmol). After 1.0 hr at ambient temperature, the volatiles were removed under vacuum and the residue was treated with water (40 ml) and chilled. The resulting solid was pulverized, filtered, and dried to give 2.23 g of white solid, m.p. 110-112 . Anal. Found C, 55.14; H, 6.71; N, 11.40 54.66 6.49 11.49 Calc'd for C11H16N2O2S: C, 54.97; H, 6.71; N, 11.66 Example 19 2-(1-Pyrrolidinylmethyl)benzenesulfonamide, methyl iodide salt A solution of 2-(pyrrolidinomethyl)benzenesulfonamide (0.8 g) in acetonitrile (10 ml) was contacted with methyl iodide (3 ml) and heated to reflux for 2.0 hrs: Solvent was removed and the residue was treated with acetone and ether. The solid was filtered, digested with acetone (20 ml), chilled, and collected. There was obtained 1.00 g of white solid. 1E nmr #TMS 8.15-7.30 (m), 5.07 (s, 2H), 3.9-3.3 (m, 4H), 2.90 (5, 3H), 2.4-1.8 (m, 4H), Example 20 2-(Chloromethyl)-N-(butylaminocarbonyl)benzenesulfonamide A mixture of 2-(chloromethyl)benzenesulfonamide (13.2 g, 64 amol) and butyl isocyanate (7.0 g, 71 mmol) in xylene (80 ml) wascontacted with diazabicyclo[2.2.2]- octane (0.25 g) and heated to reflux for 5.0 hrs. Volatiles were removed under vacuum and the residue was treated with 0.5 N NaOB (200 ml) and extracted with ethyl acetate (75 ml). The aqueous layer was separated, chilled, acidified (pE 4) with hydrochloric acid, and ex tracted with ethyl acetate. The organic layer was washed with brine, dried (MgSO4), and evaporated to give 14.6 g of white solid. A sample was recrystallized from toluene to give m.p. 104-106 . 1H nmr #TMS 9.5-8.1 (brds), 8.05-7.10 (m), 6.28 (t, 3 n 2Hz), 4.91 (5), 3.25-2.95 (m), 1.70-0.70 (m). Example 21 Methvl o-Isocyanatosulfonvlbenzeneacetate A mixture of 22.9 g methyl o-aminosulfonylbenzeneacetate, 13.5 g n-butyl isocyanate, 15.2 g potassium carbonate and 250 ml methyl ethyl ketone was stirred and refluxed for three hours. The reaction mixture was cooled, poured into 1250 g of ice-water, and acidified to pH 1.5 with concentrated HC1. The product was filtered, washed and dried. The crude product was recrystallized from l-chlorobutane to yield 24.3 g of purified N-(n-butyl)sulfonylurea derivative of methyl o-isocyanatosulfonylbenzene- acetate, m.p. 164-166 (dec.). To 16.4 g of the above N-(n-butyl)sulfonylurea derivative was added 150 ml of xylene and 0.2 g DABCO. The mixture was stirred and heated until 30 ml of xylene had been distilled off. The distillation head was replaced with a dry-ice reflux condenser, and then phosgene was slowly passed into the reaction mixture, which was maintained at 130 8 , over about one hour. When no more phosgene was taken up, the mixture was heated at 132-133 under slow phosgene reflux for one hour longer. The reaction mixture was cooled to room temperature, filtered to remove some solids and concentrated in vacuo to yield 25.0 g of the desired sulfonyl isocyanate product as an oil. Example 22 Methyl 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl] amincsulfonvl]benzeneacetate The 25 g of methyl o-isocyanatosulfonylbenzeneacetate from Example 1 was dissolved in 150 ml dry acetonitrile, and 0.2 g DABCO was added. To the stirred solution at 270 was added all at once 7.6 g of 2-amino-4,6-dimethoxypyrimidine. The temperature rose rapidly to 420. The reaction mixture was then stirred and heated at 48-50 for two hours, and stirred at ambient temperature for a further sixteen hours. The product was recovered by filtration and dried; 16.3 g of the desired sulfonylurea was obtained, m.p. 193-1960 (dec.). The product absorbed in the IR at 1730, 1610 and 1570 cm-Ú It showed NMR absorption at d3.8 (s, 3H), methyl ester: d4.1 (s, 6H) , pyrimidine methoxyl groups; d4.3 (s, 2E), benzeneacetic group; #6.2 (s, 1H), pyrimidine ring hydrogen; d7.3-8.5 (m, 4H), aromatic hydrogens. Anal. Calcd. for C16H18N4O7S: C, 46.82; H, 4.42; N, 13.66; S, 7.81. Found: C, 46.9, 47.0; H, 4.4, 4.4; N, 14.0, 14.0; S, 8.3, 8.0. All data are consistent with the structure of the desired sulfonylurea. Example 23 2-[[(46-Dimethoxypyrimidin-2-ylEaminocwrbonyllamin sulfonvl] benzeneacetic acid 1.03 g of the product of Example 2 was added to a stirred solution of 0.5 g of commercial 50% aqueous sodium hydroxide mixed with 25 ml of water at ambient temperature. A clear solution was obtained after a few minutes. Stirring at ambient temperature was maintained for two hours. 2N hydrochloric acid was added dropwise to pH 2, causing the desired product to precipitate out. The solid product was filtered, washed and dried; 0.95 g was obtained, m.p. 173-1754 (dec.). The product absorbed in the IR at 1730, 1690, 1610 and 1580 cm-Ú. It showed NMR absorption at 4.0 (s, 6H), pyrimidine methoxyl groups; #4.1 (s, 2H) , ben zeneacetic group; # 5.9 (s, 1H), pyrimidine ring hydro- gen; d7.3-8.4 (m, 4H), aromatic hydrogens; 10.5 (s, 1H), carboxylic acid. The spectral data are consistent with the structure of the desired sulfonylurea. Example 24 Methyl 1-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]aminosulfonyl)benzeneacetate 2.3 g Methyl o-isocyanatosulfonylbenzeneacetate prepared as described in Example 1, and 0.03 g DABCO were dissolved in 30 ml dry acetonitrile. 1.2 g of 2-Amino-4-methoxy-6-methyl-1,3,5-triazine was added all at once to the stirred solution, which was heated for two hours at 50-55 , then for sixteen hours at ambient temperature. The reaction mixture was filtered and the solids obtained weed washed and dried (1.0 g). The solids, which were a mixture of the desired product ahd utxeacted 2-amino-4-methoxy-6- methyl-1,3,5-triazine were dissolved in 100 ml methylene chloride and washed with 0.3 N hydrochloric acid, which removed u-reacted aminotriazine. Evaporation of the methylenechloride yielded 0.7 g of the desired. sulfonylurea; mspX 162-165" (dec..). The product showed NMP absorption at #2.9 (s, 3H), triazine methyl; d3.9 (s, 3E), methyl ester; d4.35 (s, 2E), benzeneacetic group; d4.4 (s, 3H), triazine methoxyl; #7.4-8.6 (m, 4H) aromatic hydrogens, consistent with the structure of the desired sulfonylurea. Example 25 Ethyl 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl] aminosulfonyl]benzenacetate Following the procedure of Example 1, ethyl o-aminosulfonylbenzeneacetate was reacted with n-butyl isocyanate to form the N-(n-butyl)sulfonylurea deriva tive; m.p. 140-1420. Following the procedure of Example 1, the N-(n butyl)sulfonylurea derivative was reacted with phos- gene to form ethyl o-isocyanatosulfonylbenzeneacetate, an oil. 1.35 g of Ethyl o-isocyanatosulfonylbenzene acetate and 0.015 g of DA3CO were dissolved in 15 ml acetonitrile. 0.8 g of 2-Amino-4,6-dimethoxypyrimi- dine was added all at once, and the reaction mixture was stirred for sixteen hours at ambient temperature. The product was recovered by filtration; 1.2 g of the desired sulfonylurea was obtained, m.p. 168-1720 (dec.). The product showed NMR absorption at #1.1-1.4 (t, 3H), methyl group of ethyl ester; 64.2 (s, 6H) methoxyl groups of pyrimidine; #4.1-4.4 '(q, 2H), methylene of ethyl ester; #4.3 (s, 2H), methylene of benzene acetic group; d'6.3 (s, 1H), pyrimidine hydrogen; #7.4-8.4 (m, 4H), aromatic hydrogens, consistent with the structure of the desired sulfonylurea. Example 26 Methyl 2-[[(4,6-dichloropyrimidin-2-yl)aminocarbonyl] aminosulfonyl]benzeneacetate To 2.3 g of 2-(aminosulfonyl)benzeneacetic acid methyl ester in 30 ml of acetonitrile was added 1.5 g of anhydrous potassium carbonate and 1.6 g of 4,6-dichloropyrimidi-2-yl isocyanate. The mixture was stirred at room temperature for 6 hours, diluted with 250 g of water and acidified to a pH of about 4. The resulting solid was filtered and dried to yield 1.6 g of methyl 2-[[(4,6-dichloropyrimidin-2yl)aminocarbon yl]aminosulfonyl]benzeneacetate, a pale yellow solid, m.p. 115-118 C. It showed infrared absorption peaks at 1730, 1600 and 1560 cm and nuclear magnetic resonance peaks at 3.7 ppm, methyl ester group; 4.2 ppm, benzeneacetic group; 6.9 ppm, pyrimidin H; 7.4-7.6 ppm, aromatic hydrogens; consistent for the product. Example 27 Methyl 2-{1(4,6-dimethoxy-1,3,5-tria2in-2-yl)amino- thioxomethyl]aminosulfonyl]benzeneacetate To 1.1 g of 2-(aminosulfonyl)benzeneacetic acid methyl ester in 25 ml of ethyl methyl ketone was added 1.9 g of anhydrous potassium carbonate and 1.0 g of 2,4 dimethoxy-1,3,5-triazinyl-6-isothiocyanate. The mixture was stirred at room temperature for 24 hours and then diluted with 200 g of ice-water. The solution was acidified with dilute EC1 to a pH of about 4. The resulting product was filtered and dried to give 1.2 g of white solid, m.p. 164-1680C. It showed infrared absorption peaks at 1750, 1630 and 1570 rum 1 and nuclear magnetic resonance peaks at 3.9, 4.4, 4.5 and 7.6 ppm, consistent for the product. Example 28 2-[[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]aminosulfonyl]-N,N-tetramethylenebenzeneacetamide To 1.42 g of pyrrolidine in 100 ml of dry methylene chloride at room temperature was added 10 ml of commercial two molar trimethylaluminum in toluene. The temperature rose by 5 . After the resulting solution had been stirred for ten minutes, 4.1 g of the product of Example 2 was added portionwise over- five minutes. The reaction mixture was stirred and re fluxed for sixteen hours. 200 ml of water and 10 ml of concentrated hydrochloric acid was then added to the reaction mixture, the methylene chloride layer was separated, dried by addition of magnesium sulfate, and the solvent removed by distillation at reduced pres sure. The residue was a gum. Trituration of the gum with l-chlorobutane resulted in the formation of cry stals. The product was filtered, washed and dried, 3.8 g was obtained; m.p. 133-135 (dec.). The product absorbed in te IR at 1720, 1650, 1600 and 1550 cm . It showed NMR absorption at #2.1-2.5 (m, 4H), pyrrolidine hydrogens at positions 3 and 4; #3.7-4.1 (m, 4H), pyrrolidine hydrogens at positions 2 and 5; S4.1 (s, 6H), pyrimidine methoxyl groups, d4.6 (s, 2H), benzeneacetic group; #6.2 (s, 1H), pyrimidine ring hydrogen; #7.4-8.4 (m, 4H) aromatic hydrogens. The spectral data are consistent with the structure of the desired sulfonylurea. Example 29 o-Methylthiomethylnitrobenzene To a stirred solution of 10.8 g (0.2 mol) of esodium methoxide in 70 ml of methanol at room temperature was added dropwise 12 ml (10.8 g, 0.22 mol) of methyl mercaptan through a gas addition funnel connected to a dry--ice condenser. The resulting mixture was stirred at room temperature for 1 hour and then added dropwise to a stirred solution of 30.0 g (0.175 mole) of o-nitrobenzyl chloride in 120 ml of methanol over 1 hour, while the temperature rose to 400C. The reaction mixture( was then diluted with 300 ml of water, and extracted 3 times with methylene chloride. The methylene chloride extracts were washedwith dilute hydrochloric acid, dried, and concentrated to afford 38.6 g (96%) of yellow oil. NMR (CDC13)6: 1.97. (3E, s, CH3); 3.97 (2H, s, CH2); 7.3-8.1 (4H, m, 4 aromatic H's). Example 30 Q-MethylthiomethylaniZine Iron powder (60 g, 1.0 g-atom) was added slowly through a solid addition funnel to a solution of 53.5 g (0.29 mol) of o-methylthiomethylnitrobenzene in 210 ml of glacial acetic acid and 600 ml of absolute ethanol under reflux over a period of 45 minutes. The mixture was then refluxed for 3 hours. The iron powder was filtered off and the filtrate was diluted with 800 ml of water. The aqueous mixture was extracted twice with 200 ml ethyl acetate and twice with 2QO ml ether. The combined organic extracts were washed with water, dried and concentrated to yield 48 g (75% pure) of orange oil. NMR (CDC13)6: 1.90 (3H, s, CH3); 3.60 (2H, s, CH2); 5.72 (2H, bs, NE2); and 6.5-7.3 (4H, m, 4 aromatic H's). Example 31 o-Methylthiornethylbenzenesulfonyl chloride To a mixture containing 48 g (758 pure, 0.23 mol) of o-methylthiomethylaniline in 280 ml of acetic acid and 90 ml of concentrated hydrochloric acid at 0 was added a solution of 20 g (0.3 mol) of sodium nitrite in 50 ml of water. The resulting diazonium salt solution was then added through a dropping funnel to a mixture of 50 ml of sulfur dioxide and 12 g of cupric chloride in 140 ml of acetic acid and 140 ml of ether at 0 C. The mixture was allowed to stand at OOC overnight and then poured into 1 # of ice-water. Extraction with ether, washing, drying and evaporation of the solvent gave 26 g (50%) of red oil. NMR (CDCL3)#; 2.46 (3H, s, CE3); 4.67 (2H, s, CH2); 7,2-8.0 (4H, m, 4 aromatic H's); plus one equivalent of o-methyl thiomethylchlorobenzene; 2.07 (3H, s, CH3); 4.18 (2H, s, CH2); and 7.0-7.5 (aromatic H's). The product was used for the next step without further purification. Example 32 o-Methylthiomethylbenzenesulfonamide To a solution of 26 g (50% pure, 55 mmol) of o-methylthiomethylbenzenesulfonyl chloride in 250 ml of methylene chloride was added 4.5 ml of anhydrous ammonia at 0-5 over 1 hour, Stirring was continued at 0-5 C for 2 hours. The solid precipitate was filtered off and the filtrate was evaporated to dryness to afford 24.8 g of orange residue. The crude product was triturated in ether, resulting in light pink crystals: m.p. 119-1240C. NMR ICDCl3)6: 2.05 (3H, s, CH3); 4.18 (2, s, CH2); 6.72 (2H, bs, NH2); 7.2-7.8 (3H, m, aromatic H's, m-# p-); and 8.0 (lH, dd, aromatic H, o-). Example 33 o-Methylthiomethylbenzenesulfonyl isocyanate Phosgene (2.5 ml, 35 mmol) was added portionwise into a- nitrogen-purged mixture containing 6.8 g (31 mmol) of o-methylthiomethylbenzenesulfonamide, 0.1. g of DABCO, and 3.8 g (38 mmol) of n-butyl isocyanate in 60 ml of dry xylene, while the temperature was maintained at 130-1350C between additions. Stirring was continued. for 1. hour at 130-135 C. The mixture was cooled to room temperature and. the solid was filtered off under nitrogen. The filtrate was concentrated to yield 9.0 g (theo 7.6 g) of oil: IR cm 1 2240 (N=C=O), no NH at ca 3300. The oil was taken up in 90 ml of dry methylene chloride. Example 34 (N-(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2methylthiomethylbenzenesulfonamide A solution of o-methylthiomethylbenzenesul fonyl isocyanate in dry methylene chloride (15 ml of the above solution from Example 5, 5 mmol) was added with a syringe into a nitrogen-purged flask containing 0.6 g (5 mmol) of 2-amino-4,6-dimethyl pyrimidine and a trace of DABCO. The mixture was reflexed for 2 1/2 hours. The solvent was removed in-vacuo to yield 1.8 g of white solid: m.p. 173-1830C. The unreacted pyrimidine can be removed by washing with dilute hydrochloric acid. w NMR (DMSO-d6): 1.90 (3H, s, SCH3); 2.37 (6H, pyrimidine 4 . & 6-CH3 's); 4.08 (2H, s, CH2); 7.03 (1H, s, pyrimidine 5-H); 7.64 (3H, m, benzene H's, m- # p-); 8.16 (1H, m, benzene H, o-); 10.6 (1H, bs, SO2NHCONH); and SO2NHCONH not detectable. Example 35 [N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-2methylsulfinylmethylbenzenesulfonamide One ml of 30% aqueous hydrogen peroxide was added to a suspension of 0.5 g (1.4 mmol) of [N-[4,6- dimethylpyrimdinyl)aminocarbonyl]-o-methylthiomethylbenzenesulfonamide in 15 ml of glacial acetic acid at room temperature. The mixture turned clear in 10 minutes and was stirred for a further 30 minutes. It was then diluted with water and extracted with methylene chloride. The organic extracts were washed, dried and concentrated to give 0.5 g (1008) of white solid: m.p. 176-184 C. NMR (DMSO-D6)#: 2.40 (1H, s, pyrimidine 4- & 6-CH3's); 2.57 (3H, s, SCH3); 4.55 (2H, ABq, J=12 Hz, EMI71.1 7.02 (1H, s, pyrimidine 5-H); 7.6 (3H, m, benzene m- b p- H's); 8.18 (1H, m, benzene O-H); 10.5 (1H, bs, SO2NHCONH); and SO2NH not detectable. Example 36 [N-(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 methylsulfonylmethylbenzenesufonamide A mixture of 0.1 g (0.2 mmol) of [N-(4,6dimethylpyrimidinyl)aminocarbonyl-o-methylsulfinylmethylbenzenesulfonamide and 0.3 ml of 30% hydrogen peroxide in 5 ml of acetic acid was stirred at room temperature for 3 days. The resulting white solid precipitate was filtered to afford 30 mg of the desired product: m.p 222-225 C. NMR (DMSO-d6)#; 2.42 (6H, s, pyrimidine 4- # 6-CH3's); 2.94 (3H, s, SCH3); 5.10 (2H, s, CH2); 7.00 (1H, s, pyrimidine 5-H); 7.7 (3H, m, benzene m- & BR< p-H's); 8.1 (1H, m, benzene 0-H); 10.5 (1H, bs, SO2NHCONH); and SO2NH not detectable. Example 37 2-(1-Methylethoxymethyl)benzenesulfonamide To 4.9 g 2-(aminosulfonyl)benzoic acid, l-methylethyl ester in 37 ml BF3-Et20 at a temperature 0-10 was added over 45 min, 40 ml at 1 molar solution at BH3 in THF. The mixture was refluxed overnight. The resulting cloudy yellow solution was concentrated on a rotary evaporator, acidified with 10% HC1 diluted with 300 ml H20 and then extracted with three 100 ml portions of ether. The ether extracts wenedried with magnesium sulfate and then concentrated.to 4.1 g of wet solid. The product was further purufied to an oil by column chromatrography on silica with methylene chloride. NMR (=DC13)6: 1.20 (6H, (CH3)2); 3.72 (1H, -CH); 4.88 (2H, CH2); 7.2 (2H, MH2); and 7.3-79 (4H, aromatic) The product was converted to the corresponding sulfonylisocyanate by the procedure of Example 33. The resulting sulfonylisocyanate was used to prepare the corresponding sulfonylureas by the procedure of Example 34. Example 38 2-Nitrophenylmethyl carbamimidothioate hydrochloride A solution of 34.3 g of o-nitrobenzyl chloride and 15.2 g of thiourea in 250 ml of # 2B alcohol was refluxed for 1 1/2 hours. The solution was cooled to 60 and 250 ml of l-chlorobutane added. Further cooling to 200 yielded a precipitate which was filtered, washed with l-chlorobutane and dried at 650 to give 38.1 g of 2-nitrophenylmethyl carbamimidothioate hydrochloride, m.p. 190-192 . NMR (DMSO-d6)S: 4.85 (s, 1.8H, CH2); 7.4-8 (m, 4.2H, 4 aromatics); 9.7 (broad s, 4.OH, 4 NH's). Example 39 N,N-Dimthhl-2-nitrobenzenemethanesulfonamide To a slurry of 34.7 g of the compound of Example 1 in- 350 =1 of water was added 20.5 ml of liquid chlorine at 10-15 over a 45 minute period. After stirring an additional 15 minutes at 100, the precipitated sulfonyl chloride was filtered off and washed well with water. The wet sulfonyl chloride filter cake was suspended in 200 ml of ether and contacted with 18.-0 ml cf liquid dimethylamine at 5-15 ' After stirring at room temperature for 1 1/2 hours, the precipitate was filtered off and washed well with water, then l-chlorobutane. Oven drying at 600 overnight gave 15.9 g of N,N-dimethyl-2-nitrobenzenemethanesulfonamide, m.p. 129-132 . NMR (DMSO-d6)d: 2.7 (s, 6.2H, SO2NMe2); 4.8 (s, l.9H, -CH2-); 7.6-8.3 (m, 3-.9H, 4 aromatics). Anal. Calcd. for CgH12N204S: C, 44.28; H, 4.96; N, 11.47; S, 13.13. Found: C, 44.6 44.5; H, 4.8; N, 11.4; S, 13.3 4.7; 11.4 13.0. Example 40 N,N-Dimethyl-2-aminobenzenemethanesulfonamide ¯ In a pressure bottle, a mixture of 116 g of the product of Example 2, 1400 ml of 2-methoxyethyl ether and 10 g of 108 palladium on carbon was shaken at 1100 under 500 p.s.i. hydrogen until the hydrogen was no longer absorbed. The catalyst was filtered off and the filtrate stripped under reduced pressure to a volume of 200 ml. This residue was poured into 600 ml of ice and the precipitate filtered off and dried to give 84 g of crude product, m.p. 70-780. Recrystalli zation from N600 ml of l-chlorobutane gave 60.6 g of N,N-dimethyl-2-aminobenzenemethanesulfonamide, m.p. 92.1000. NMR (DMSO-d6)d: 2.7 (s, 5.8H, S02NMe2); 4.3 (s, 2.lH, CH2); 4.9-5.2 (broad s, 2.OH, NH2); 6.4-7.3 (m, 4.1H, 4 aromabics). Example 41 2-[(Dimethylamino)sulfonylmethyl]benzenesulfonamide To a solution of 53.± g of the product of Example 3 in a mixture of 225 ml of concentrated hydrochloric acid and 75 ml of glacial acetic acid was added a solution of 21.4 g of sodium nitrite in 70 ml of water at -5 to 00. The solution was stirred at 0 for 15 minutes, then poured into a mixture of 6 g of cuprous chloride, 48 ml of liquid sulfur dioxide in 300 ml of glacial acetic acid.at 0-5 . This mixture was stirred at 0 for 1 hour, then at 250 for 2 hours before being poured into 2 liters of ice-water. The precipitate was filtered and washed with water then suspended in 250 ml of ether and treated with 11.0 ml of liquid anhydrous ammonia at 5-150. After stirring at 250 for 30 minutes the precipitate was filtered off and washed well with ether then water.. Oven drying at 600 gave 40.2+ g of 2-[(dimethylamino)sulfonylmethyl]- benzenesulfonamide, m.p. lt5-1500. NMR (DMSO-d6)#: 2.7 (s, 6.0B, SO2NMe2); 4.8 (s, 1.8H, -CH2-); 7.2-8.1 (m, 6.2H, 4 aromatics + SO2NH2). Example 42 2-[(Dimethylamino)sulfonylmethyl]benzenesulfonyl isocvanate A solution of 14.0 g of the product of Example 4, 5.0 g of n-butyl isocyanate and 0.1 g of DABCO in 90 ml of mixed xylenes was heated to 1360. To this solution was added 3.6 ml of liquid phosgene over a 2 hour period to maintain the temperature between 1250 and 1360. The temperature was kept at 1300 for 1/2 hour after the addition. The solution was cooled, and filtered under a nitrogen atmosphere and concentrated at 60-700 in vacuo to give 16.0 g of crude 2-t(dime- thylamino)sulfonylmethyl]benzenesulfonyl isocyanate as a moisture sensitive oil. An infrared peak at 22Q0 cm 1 confirmed the presence of the -SO2NCO group. Example 43 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl)benzenesulfonamide A mixture of 2.6 g of the product of Example 5, 0,9 g of 2-amino-4,6-dimethoxypyrimidine and a few crystals of DABCO in 15 ml of dry acetonitrile was heated at 50-55 for 1 hour under a nitrogen atmosphere, then stirred overnight at room temperature. The precipitate was filtered off, washed with acetonitrile and dried to give 2.1 g of 2-[(dimethylanino)- sulfonylmethyhl]-N-[(4,6-dimthoxypyrimidin-2-yl)amino carbonylZbenzenesulfonamide, m.p. 172-176 . NMR (DMSO-d6)d: 2.8 (s, 6.3H, S02NMe2); 4.0 (s, 5.6H, Het-OCH3's); 5.0 (s, 2.OH, -CH2-); 6.1 (s, 0.8H, Het-H); 7.7-8.6 (m, 4.4H, 4 aromatics); 10.8 and 13.2 (broad singlets, NH's). Anal. Calcd. for C16H21N507S2: C, 41.80; H, 4.61; N, 15.24; S, 13.96. Found: C, 41.8; 42.2; H, 4,6; N, 16.1; S, 14.0. 4.5; 16.1; 14.3. Using the procedures and examples described above and choosing the appropriate aminoheterocycle and sulfonyl isocyanate or sulfonamide, the compounds described in Tables I-VI may be prepared. Example 44 N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2- carboxybenzenesulfonamide A mixture containing 5 g of N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide, 20 ml of ethanol, 2.5 mi of water and 2.5 g of potassium hydroxide was stirred at ar.ient temperature and pressure for 18 hours. The mixture was then diluted with 250 ml of water and 20 ml of concentrated hydrochloric acid was added with stirring. The precipitate was filtered and washed with water and dried to yield 4.85 g of the desired product, melting at 161-20C. The infrared absorption peaks at 3500, 3400 and 1700 cm 1 are consistent with the desired structure and the nuclear magnetic resonance absorption peaks at 3.95 ppm, S, 6H, OCH3 of pyrimidine; 5.8 ppm S, 1H, pyrimidine proton at position 5; and 7.6-8.3 ppm, M, 4E, aromatic protons, are consistent with the. desired structure. Example 45 N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (bydroxymethyl) benzenesul fonamide To a solution of 3.9 g of bl-t(4,6-dimethoxy- pyrimidin-2-yl)aminocarbonyl]-2-carboxybenzenesulfonamide in 100 ml of tetrahydrofuran was added 50 ml of a LM solution of borane, THF complex at 25 C. The mixture was stirred at 250C for 18 hours followed by addition of water and HCl. The mixture was extracted with methylene chloride and the de sired product crystallized from solution, 1.1 g 298 yield, m.p. 149-1500C. The infrared absorption peaks at 3300 cm 1 and 1720 cm 1 are consistent with the desired structure and the nuclear magnetic resonance absorption peaks at 3.95 ppm, S, 6H, OCH3 of pyrimidine; 4.9 ppm, S, 2H, benzyl protons; 5.9-ppm, S, 1H, pyrimidine proton at position 5; and 7.4-8.3 ppm, Multiplet, 4H, aromatic * s are consistent with the desired structure. Example 46 N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 methylcarbonylbenzenesul fonamide A mixture containing 0.85 g of N-[(4,6-dimethoxy- pyrimidin-2-yl') aminocarbonyl) -2-carboxybenzenesulfon- amide in 50 ml of anhydrous tetrahydrofuran was treated with 40 ml of 1.4 molar solution of methyl lithium (low halide, Aldrich) in ether at 250 under a nitrogen atmosphere. The mixture was stirred for 4 hours at 250 and was then poured into 500 ml of water con taining 10 ml of concentrated hydrochloric acid. The precipitated oil was extracted into methylene. chloride and the oil on evaporation of solvent was purified by preparative thin layer chromatography on silica gel (Analtec, 2000 micron, 20 x 20 plates) by elution with ethyl acetate/hexane in a one to one ratio. The isolated. product was recrystallized. from a l-chlorobutane and hexane mixture to give 0.l g, m.p. 126-8 . The infrared absorption showed a broadened carbons peak at 1710 cm-Ú, and the absence of the 3500 and 3400 or 1 peaks of the starting material. The nuclear magnetic resonance spectrum showed peaks at 2.6 ppm S, 3H, EMI79.1 4.0 ppm, S, 6H, CH3O of pyrimidine; 5.7 ppm S, 1H, pyrimidine proton at position 5; and 7.3-7.7 ppm and 8.0 ppm M, 4, aromatic, which are consistent with the desired structure. Example 47 N-[(4,6-Dimthoxypyrimidin-2-yl)aminocarbonyl]-2 (&alpha;-hydroxyethyl)benzenesulfonamide A mixture containing 1.0 g of N-[(4,6-dimethoxy- pyrimidin-2-yl) aminocarbonyl -2-rnethylcarbonylbenzene- sulfonamide in 50 ml of anhydrous THF is treated with 0.1 g of lithium aluminum hydride at 250 under a nitrogen atmosphere. The mixture is stirred for 4 hours at 250 and is then poured into 500 ml of water containing 10 ml of concentrated hydrochloric acid. The precipitated oil is extracted into methylene chloride and the solid on evaporation is purified by column chromatography on silica gel. Example 48 2-(Acetoxymethyl)benzenesulfonamide A mixture of 2-(chloromethyl)benzenesulfonamide (2.00 g), potassium acetate (6.0 g) and water (75 ml) was heated to reflux for 1.5 hour. The pH was adjusted to ca. 5.0 by addition of hydrochloric acid and the chilled mixture was filtered to give 1.05 of of shiny white solid, m.p. 131-133 . 'H Nt!R # (CD3)2CO 8.00-7.83 (M), 7.60-7.25 (M), 6.55 (brd s), 5.47 (s), 2.97 (brd s), 2.10 (s), consistent with the assigned structure. Example 49 2-(Acetoxymethyl)-N-[(4,6-dichloro-1,3,5-triazin-2 yl)aminocarbonyl]benzenesulfonamide A solution of 4,6-dichloro-1,3,5-triaxin-2-yl isocyanate (0.87 g, 4.5 mmol) in acetonitrile (9 ml) was treated with 2-(acetoxymethyl)benzene- sulfonamide (1.04 g, 4.5 mmol) and stirred for 16 hours. Volatiles were removed under vacuum to give a residue whose 'H NMR showed #(CD3)2CO, 8.05-7.80 (m, 1H), 7.65-7.27 (m, 3H), 6.45 (brd s, 1H), 5.50 (s, 2H), 2.10 (s, 3H), consistent with the assigned structure. Example 50 2-(Hydroxymethyl)-N-[(4,6-dimethoxy-1,3,5-triazin2-yl)aminocarbonyl]benzenesulfonamide The crude 2-(acetoxymethyl)-N-[(4,6-dichloro 1,3,5-triazinyl)aminocarbonylJbenzenesulfonamide was treated with methanol (10 ml.) and then with a solution of sodium methoxide (14 mmol) in methanol. The mixture was stirred at room temperature for 1.5 hour and evaported The residue was taken up in. water and filtered. The filtrate was acidified and filtered to give 0.45 g of gummy solid which was recrystallized from a chloroform/acetone mixture to give 115 mg of white solid, m.p. 146-148 (dec.). 'H NMR # DMSO-ds 12.2(brd s, 1H), 10.73 (s, 1H), 8.00-7.15 (m,4H) , 4.80 (s and N4.9-4.2 (brd s),3H) 3.90 (s, 6H), consistent with the assigned structure. Examplary compounds within structure I that can @e made by one or more of the described methods (Examples 1-50) are listed in Tables I-XXXIV. Table I EMI82.1 EMI82.2 <tb> <SEP> t <SEP> R <SEP> R <SEP> X <SEP> Y <SEP> - <SEP> ¯¯¯¯ <tb> <SEP> 1, <SEP> 12 <SEP> Z <SEP> :..(0C) <tb> <SEP> ca <SEP> . <SEP> H <SEP> H <SEP> C3 <SEP> C3 <SEP> CH <SEP> 176-1770 <tb> <SEP> Er <SEP> E <SEP> H <SEP> P. <SEP> C' <SEP> 3 <SEP> CH3 <SEP> CF <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> Cue,3 <SEP> CF. <tb> <SEP> H <SEP> H <SEP> H- <SEP> CH3 <SEP> CH3 <SEP> CH <tb> <SEP> e <tb> <SEP> X(C-3)3 <SEP> E <SEP> Y. <SEP> Y. <SEP> CY.3 <SEP> CH3 <SEP> CF <tb> <SEP> 0 <tb> <SEP> CF <tb> <SEP> H <SEP> H <SEP> H <SEP> H <SEP> CE.3 <SEP> CX3 <tb> <SEP> 0 <tb> .. <SEP> NXCOCH2CY.3 <SEP> H <SEP> H <SEP> SCH3 <SEP> CH3 <SEP> CF <tb> <SEP> 0 <tb> <SEP> .. <tb> <SEP> X(C2H)C06h.3 <SEP> H <SEP> fi <SEP> C1 <SEP> CF3 <SEP> C <tb> <SEP> XtCX3)2 <SEP> H <SEP> H <SEP> F. <SEP> CE <SEP> CCE <SEP> C'.-.3 <SEP> C <tb> <SEP> h'(CY,)(eZe) <SEP> H <SEP> H <SEP> H <SEP> CF3 <SEP> CF3 <SEP> cv <tb> <SEP> )'(C2H5)2 <SEP> H <SEP> H <SEP> H <SEP> CF3 <SEP> CF3 <SEP> C:-: <tb> <SEP> N(C3H7)2 <SEP> H <SEP> E <SEP> CF3 <SEP> CF3 <SEP> C;-: <tb> <SEP> H <SEP> H <SEP> X <SEP> E <SEP> C:-3 <SEP> CF3 <SEP> C:-: <tb> <SEP> uC.CE., <SEP> C <SEP> 3 <SEP> 3 <tb> Table 1 (cont'd) EMI83.1 <tb> <SEP> L <SEP> R <SEP> R1 <SEP> 2 <SEP> X <SEP> 2 <SEP> 2 <SEP> m <SEP> p <tb> t;(OC1:n) <SEP> C:-3 <SEP> :, <SEP> B <SEP> E <SEP> 3 <SEP> 3 <SEP> Cr. <tb> <SEP> CH <SEP> Cii <tb> <SEP> N <SEP> E <SEP> H <SEP> H <SEP> CH3 <SEP> CB3 <SEP> n <tb> <SEP> 2 <tb> h-P?CH.3 <SEP> , <SEP> H <SEP> H <SEP> H <SEP> CCH <SEP> (CH <SEP> CH3 <tb> NHC4H9 <SEP> H <SEP> H <SEP> H <SEP> 3 <SEP> 3 <SEP> CH3 <SEP> 3 <SEP> n: <tb> <SEP> 0 <tb> 'Z'CN2 <SEP> Cl <SEP> H <SEP> H <SEP> H <SEP> 3 <SEP> CF. <tb> <SEP> 0 <tb> liH' <SEP> CCL <SEP> H <SEP> H <SEP> ii <SEP> C-3 <SEP> ; <SEP> CF <tb> C1 <SEP> H <SEP> aj <SEP> H <SEP> CH3 <SEP> CH3 <SEP> CH <tb> C1 <SEP> H <SEP> CE2CP2CP3 <SEP> H <SEP> Csi3 <SEP> C}3 <SEP> CH <tb> C1 <SEP> H <SEP> n-C <SEP> W <SEP> H <SEP> C3 <SEP> C3 <SEP> CH <tb> Cl <SEP> H <SEP> Ii <SEP> CH3 <SEP> CH3 <SEP> C-C1 <tb> <SEP> 3 <tb> C1 <SEP> R <SEP> H <SEP> H <SEP> cue3 <SEP> OCH3 <SEP> CN <tb> Br <SEP> H <SEP> li <SEP> H <SEP> CH3 <SEP> QCH3 <SEP> CF <tb> U <SEP> H <SEP> H <SEP> CH3 <SEP> CN3 <SEP> OCH3 <SEP> CF <tb> C1 <SEP> E <SEP> H <SEP> H <SEP> OC.3 <SEP> OCs:3 <SEP> C.?. <SEP> lS:-lCi' <tb> N <SEP> H <SEP> S <SEP> H <SEP> OC'd, <SEP> a3 <SEP> C <tb> <SEP> N <SEP> H <SEP> H <SEP> 0CH3 <SEP> OCN3 <SEP> C- <SEP> 13E-I:3' <tb> N <SEP> ; <SEP> ) <SEP> H <SEP> OCE <SEP> C:-: <tb> Cl <SEP> H <SEP> H <SEP> Ci.3 <SEP> 0C-.3 <SEP> OCH <SEP> C*4 <tb> <SEP> 3 <SEP> 3 <tb> H <SEP> H <SEP> *3 <SEP> OC:--3 <SEP> OC.n.3 <SEP> Cr. <tb> <SEP> . <SEP> . <tb> <SEP> C1 <SEP> 5"C1 <SEP> H <SEP> H <SEP> CH3 <SEP> CH3 <SEP> ' <SEP> CH <tb> <SEP> C1 <SEP> 4-NC2 <SEP> H <SEP> H <SEP> C-.3 <SEP> 0 <SEP> oCH3 <SEP> CF <tb> <SEP> 4-No2 <SEP> N <SEP> H <SEP> CF <SEP> OCX3 <SEP> CF <tb> <SEP> C. <SEP> 4-C1 <SEP> H <SEP> H <SEP> OCH3 <SEP> OC- <SEP> C <tb> <SEP> 3 <SEP> 3 <tb> <SEP> Cl <SEP> N <SEP> Cl <SEP> B <SEP> C:-:3 <SEP> Cur.3 <SEP> CF <SEP> 19-197" <tb> <SEP> N <SEP> H <SEP> C1 <SEP> H <SEP> C-. <SEP> CF <tb> <SEP> C1 <SEP> N <SEP> . <SEP> C1 <SEP> H <SEP> OC--3 <SEP> CF3 <SEP> CH <SEP> ies-rsc <tb> <SEP> Cl <SEP> N <SEP> Cl <SEP> H <SEP> OC- <SEP> OC, <SEP> C <tb> <SEP> 3 <SEP> 3 <tb> Table I (continued) EMI84.1 <tb> L <SEP> R <SEP> 1 <SEP> P2 <SEP> X <SEP> Y <SEP> z <tb> <SEP> Ci <SEP> H. <SEP> H <SEP> H <SEP> CX3 <SEP> CX3 <SEP> S <tb> C' <SEP> H <SEP> H <SEP> H <SEP> CH.3 <SEP> OtE3 <tb> <SEP> C-I <SEP> N <SEP> N <SEP> H <SEP> N <SEP> CE <tb> <SEP> Ci <SEP> H <SEP> H <SEP> CH3 <SEP> CH3 <SEP> CE <SEP> <tb> <SEP> 3 <tb> <SEP> C: <SEP> H <SEP> N <SEP> CX3 <SEP> CH3 <SEP> =w3 <SEP> S <tb> C1 <SEP> H <SEP> H <SEP> H <SEP> 0CN3 <SEP> OCX <SEP> X <SEP> 150-15" <tb> <SEP> C1 <SEP> H <SEP> R <SEP> CH3 <SEP> 0CE3 <SEP> OC-.3 <SEP> S <SEP> 168-1500 <tb> <SEP> N <SEP> H <SEP> H <SEP> Cry.3 <SEP> Owe3 <SEP> OCr3 <SEP> X <tb> H <SEP> N <SEP> Ca3 <SEP> OCE3 <SEP> OCE3 <SEP> S <tb> cn <SEP> 4-N 2 <SEP> X <SEP> N <SEP> CE3 <SEP> C3 <tb> Cl <SEP> - <SEP> 4NO2 <SEP> Y. <SEP> N <SEP> CE3 <SEP> oCE3 <SEP> N <tb> Cl <SEP> 4%1 <SEP> N <SEP> N <SEP> 23 <SEP> '3 <SEP> h' <tb> 5-Cl <SEP> N <SEP> N <SEP> CE3 <SEP> Or,.3 <SEP> S <tb> S-Fr <SEP> N <SEP> N <SEP> 0CN3 <SEP> 0CE3 <SEP> X <tb> X <tb> <SEP> C1 <SEP> H <SEP> Cl <SEP> H <SEP> CH3 <SEP> O3 <SEP> N <tb> <SEP> Cl <SEP> B <SEP> C1 <SEP> N <SEP> 0CE3 <SEP> 3 <SEP> N <SEP> 16S-1690 <tb> <SEP> Cl <SEP> N <SEP> Cl <SEP> N <SEP> OCH, <SEP> OC <SEP> N <tb> Table 1 (continued) L R R1 R2 X Y 2C) OCH3 H H H CH3 CH3 CH 164-167 OCH3 H H H OCH3 CH3 CH 163-166 OCH3 H H H OCH3 OCH3 CH 171-176 SCH3 H H H CH3 CH3 CH 173-183 SCH3 H H H OCH3 CH3 CH 173-184 SCH3 H H H OCH3 OCH3 CH 165-181 S(O)CH3 H H H CH3 CH3 CH 176-18@ S(O)CH3 H H H OCH3 CH3 CH 142-15@ S(O)CH3 H H H OCH3 OCH3 CH 176-1@@ S(O)2CH3 H H H CH3 CH3 CH 222-225 S(O)2CH3 H H H OCH3 CH3 CH 195-198 S(O)2CH3 H H H OCH3 OCH3 CH 193-199 S(O)CH3 H CH3 H CH3 CH3 CH OCH3 H CH3 CH3 CH3 CH3 CH S(O)2CH3 H CH3 CH3 OCH3 OCH3 CH OCH2CH3 H H H CH3 CH3 CH 133-140 OCH2CH3 H H H OCH3 CH3 CH 124-130 OCH2CH3 H H H OCH3 OCH3 CH 122-127 SCH2CH3 H H H CH3 CH3 CH SCH2CH3 H H H OCH3 OCH3 CH S(O)C2H5 H H H OCH3 OCH3 CH S(O)2C2H5 H H H OCH3 CH3 CH OCH(CH3)2 H H H CH3 CH3 CH 165-171 OCH(CH3)2 H H H OCH3 CH3 CH 147-150 OCH(CH3)2 H H H OCH3 OCH3 CH 120-130 SCH(CH3)2 H H H CH3 CH3 CH S(O)CH(CH3)2 H H H CH3 CH3 CH O(CH2)3CH3 H H H CH3 CH3 CH 136-142 O(CH2)3CH3 H H H OCH3 CH3 CH 134-139 O(CH2)3CH3 H H H OCH3 OCH3 CH 116-121 OCH(CH3)CH2CH3 H H H CH3 CH3 CH 112-@@@ OCH(CH3)CH2CH3 H H H OCH3 CH3 CH 125-129 OCH(CH3)CH2CH3 H H H OCH3 OCH3 CH 114-@@@ Table I (continued) EMI86.1 <tb> <SEP> L <SEP> R <SEP> ¯Rt <SEP> RZ <SEP> 'VI <SEP> Y <SEP> 2 <SEP> m.P. <SEP> (CO) <tb> ¯ <SEP> ¯ <SEP> ¯ <SEP> ffi <SEP> R2 <SEP> ,---- <tb> <SEP> CH3 <SEP> N <SEP> B <SEP> U <SEP> Cue.3 <SEP> C3 <SEP> X <SEP> 123-1350 <tb> <SEP> 3 <SEP> H <SEP> N <SEP> B <SEP> Ooh3 <SEP> CH3 <SEP> ?; <SEP> 137-1400 <tb> <SEP> OCH3 <SEP> U <SEP> H <SEP> E <SEP> OCP3 <SEP> OCH3 <SEP> X <SEP> 138-1430 <tb> <SEP> 3 <SEP> N <SEP> U <SEP> U <SEP> CH3 <SEP> S <SEP> 162-l8oo <tb> <SEP> SC <SEP> 3 <SEP> M <SEP> N <SEP> H <SEP> OCH3 <SEP> CH3 <SEP> N <SEP> 141-150 <tb> <SEP> SCH3 <SEP> N <SEP> H <SEP> H <SEP> SOCH3 <SEP> OCH3 <SEP> N <SEP> 113-133 <tb> <SEP> s(O)CH3 <SEP> Y <SEP> H <SEP> N <SEP> 3 <SEP> CF3 <SEP> ; <SEP> 169-1720 <tb> <SEP> S <SEP> (O) <SEP> CH3 <SEP> H <SEP> H <SEP> N <SEP> OCH.3 <SEP> CH3 <SEP> N <SEP> 166-1710 <tb> <SEP> S(O)CH3 <SEP> H <SEP> H <SEP> H <SEP> OCH3 <SEP> O°H3 <SEP> N <SEP> 161-167 <tb> <SEP> S(O)2 <SEP> N <SEP> H <SEP> N <SEP> CH3 <SEP> CH3 <SEP> N <SEP> 212-2160 <tb> <SEP> S(0)2CH3 <SEP> H <SEP> )i <SEP> H <SEP> OCH3 <SEP> CH3 <SEP> s; <SEP> 185-1890 <tb> <SEP> S(O)2 <SEP> N <SEP> N <SEP> N <SEP> OCH3 <SEP> OCH3 <SEP> N <SEP> 189-1950 <tb> <SEP> CUR3 <SEP> H <SEP> CH3 <SEP> 0CH3 <SEP> cCH3 <SEP> N <tb> <SEP> H <SEP> e <SEP> H <SEP> CH3 <SEP> H <SEP> CH3 <SEP> N <tb> <SEP> StO)Ci3 <SEP> N <SEP> CH3 <SEP> 8 <SEP> OCE3 <SEP> CH.3 <SEP> N <tb> <SEP> 3 <SEP> OCE, <SEP> 3. <SEP> 3 <tb> <SEP> S(O)2CH3N <SEP> CH3 <SEP> H <SEP> OCH3 <SEP> CN3 <SEP> N <tb> <SEP> OCN23 <SEP> N <SEP> N <SEP> B <SEP> CH3 <SEP> CH3 <SEP> N <SEP> 118-124 <tb> <SEP> CCH2CH3 <SEP> H <SEP> H <SEP> OCH3 <SEP> OCF3 <SEP> N <SEP> 131-140= <tb> <SEP> 23 <SEP> SCH2CH3 <SEP> H <SEP> H <SEP> H <SEP> OCH3 <SEP> C? <SEP> N <tb> <SEP> 3(O)2CH23N <SEP> N <SEP> W <SEP> CE3 <SEP> CX3 <SEP> N <tb> <SEP> OCH(CH3)2 <SEP> H <SEP> H <SEP> H <SEP> CF3 <SEP> CH3 <SEP> N <SEP> 134-13. <tb> <SEP> OCH(CH,) <SEP> H <SEP> U <SEP> H <SEP> OCH3 <SEP> CH3 <SEP> N <tb> <SEP> OC-.H(CH3)2 <SEP> H <SEP> H <SEP> H <SEP> OCE3 <SEP> OCF3 <SEP> N <tb> <SEP> (O)CH(CH3)2 <SEP> (o) <SEP> CH <SEP> (CH3) <SEP> N <SEP> H <SEP> N <SEP> fi <SEP> OCF3 <SEP> CF3 <SEP> N <tb> <SEP> S(O)2CH(CH3)2 <SEP> H <SEP> H <SEP> H <SEP> OFF3 <SEP> CF3 <SEP> 3 <tb> <SEP> ra2) <SEP> 3as3 <SEP> H <SEP> H <SEP> H <SEP> CF3 <SEP> a3 <SEP> X <SEP> 98-105e <tb> <SEP> Orz)33 <SEP> N <SEP> H <SEP> OCU. <SEP> CF <SEP> N <SEP> 84-98C <tb> <SEP> 3 <SEP> 3 <tb> <SEP> O!Cfl,)3Cu.3 <SEP> N <SEP> H <SEP> N <SEP> OCR3 <SEP> OCH3 <SEP> N <SEP> 125-128 <tb> <SEP> .3 <tb> <SEP> N <SEP> 3 <SEP> R <SEP> B <SEP> S <SEP> CF3 <SEP> Cry.3 <SEP> N <SEP> 10-llOc <tb> <SEP> C-.3 <tb> <SEP> C,CXE2CH3 <SEP> H <SEP> B <SEP> H <SEP> OCF3 <SEP> 0C?3 <SEP> N <SEP> 112.1210 <tb> <SEP> .3 <tb> Table I (continued) EMI87.1 <tb> <SEP> L <SEP> R <SEP> 21 <SEP> < <SEP> X <SEP> y <SEP> Lm.p. <SEP> (OC) <tb> <SEP> 2 <SEP> j <SEP> II <SEP> Cli3 <SEP> S <SEP> CE3 <SEP> CN3 <SEP> S <tb> <SEP> OCHi <SEP> CT <SEP> 6-C: <SEP> N <SEP> N <SEP> Ch3 <SEP> OC}:3 <SEP> Cr <tb> <SEP> OCS2ct2 <SEP> 4-Br <SEP> H <SEP> N <SEP> Cr3 <SEP> OCY.3 <SEP> S <tb> <SEP> OCH.2Cm-C:2;2 <SEP> 6-N02 <SEP> N <SEP> <SEP> N <SEP> 3 <SEP> CH3 <SEP> CH3 <SEP> C <tb> <SEP> OCH;2C(C+3) <SEP> CX2 <SEP> 4 <SEP> Cy3 <SEP> P. <SEP> H <SEP> OCN2CN2C:-:3 <SEP> OCN3 <SEP> N <tb> <SEP> HH <SEP> H <SEP> E <SEP> H <SEP> m <SEP> CH3 <SEP> CE <tb> <SEP> H <SEP> 4 <SEP> H <SEP> E <SEP> H <SEP> CH3 <SEP> , <SEP> 0CH3 <SEP> N <tb> OCS2CY.(C.3) <SEP> 4-(cr:3)2CNO <SEP> H <SEP> H <SEP> OC?:3 <SEP> CH3 <tb> 0Cr3 <SEP> H <SEP> H <SEP> N <SEP> OCA3 <SEP> X3 <SEP> C <SEP> C <tb> <SEP> CO2CH3 <SEP> N <SEP> H <SEP> H <SEP> CH3 <SEP> CH3 <SEP> N <tb> <SEP> 3 <tb> <SEP> Co2CH3 <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> CH30 <SEP> CH <SEP> 194-19E"(dec) <tb> <SEP> cD2 <SEP> H <SEP> a <SEP> H <SEP> CH3 <SEP> CH3 <SEP> CH <SEP> 195-198"; ;dec) <tb> <SEP> =223 <SEP> H <SEP> H <SEP> H <SEP> 230 <SEP> CH3O <SEP> N <SEP> 182-1840 <SEP> (dec) <tb> <SEP> CO2C2H5 <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> CH3 <SEP> CH <tb> <SEP> CO2CS <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> w30 <SEP> CH <SEP> I68l700 <SEP> (dec) <tb> <SEP> CO <SEP> B <SEP> H <SEP> H <SEP> CH30 <SEP> 30 <SEP> N <tb> <SEP> OF <SEP> (23) <SEP> H <SEP> H <SEP> B <SEP> CH2CH3 <SEP> 23 <SEP> N <tb> <SEP> H <SEP> H <SEP> H <SEP> CN2CCN3 <SEP> CCH3 <SEP> N <tb> <SEP> CO2C2H5 <SEP> H <SEP> H <SEP> H <SEP> E3 <SEP> 30 <SEP> N <tb> <SEP> C3130 <SEP> H <SEP> H <SEP> 3O <SEP> Cm30 <SEP> CH <SEP> l74i770 <SEP> (dcc) <tb> <SEP> C02 <SEP> < 2 <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> cue30 <SEP> N <tb> <SEP> H <SEP> I3} <SEP> H <SEP> H <SEP> s <SEP> E <SEP> (=3 <SEP> (=30 <SEP> CH <SEP> US-1SO <SEP> O <tb> <SEP> C5D9(Q332 <SEP> B <SEP> H <SEP> H. <SEP> Cii30 <SEP> C830 <SEP> C8 <SEP> 1Ai <SEP> 15-1680(ec) <tb> <SEP> ( <SEP> H <SEP> 23 <SEP> 3 <SEP> (=3 <SEP> CH <SEP> 1621640 <SEP> (dcc) <tb> <SEP> C02H <SEP> H <SEP> H <SEP> H <SEP> cry30 <SEP> t23 <SEP> CH <SEP> 201-2090(dftc) <tb> <SEP> CD2fl <SEP> B <SEP> H <SEP> H <SEP> (=30 <SEP> (=30 <SEP> CH <SEP> 173-l75 <SEP> (dê <tb> <SEP> Co2H <SEP> H <SEP> H <SEP> H <SEP> (=30 <SEP> > 3 <SEP> N <SEP> 142-144 <SEP> (dec) <tb> <SEP> C0-"H <SEP> H <SEP> B <SEP> H <SEP> Cue30 <SEP> (=30 <SEP> N <SEP> 15: :-157 (dec) <tb> <SEP> L <SEP> H <SEP> (=3 <SEP> H <SEP> (=3 <SEP> (=0 <SEP> CH <tb> <SEP> CD <SEP> a3 <SEP> E <SEP> w3 <SEP> m3O <SEP> cS <tb> <SEP> Co2 <SEP> H <SEP> Q3 <SEP> H <SEP> (=30 <SEP> Cw30 <SEP> CH <tb> EMI88.1 <tb> <SEP> Table <SEP> I <SEP> (continued) <tb> L <SEP> RI <SEP> R2 <SEP> x <SEP> X <SEP> Y <SEP> Z <SEP> m.p,(OC) <tb> 02033 <SEP> H <SEP> CH3 <SEP> 3 <SEP> CH3 <SEP> Cm30 <SEP> N <tb> C 2CH3 <SEP> H <SEP> CH3 <SEP> H <SEP> CH3O <SEP> CH3O <SEP> N <tb> CD2CG3 <SEP> H <SEP> CH3CH2 <SEP> H <SEP> CH30 <SEP> Ci30 <SEP> CH <tb> 2 <SEP> 3 <SEP> H <SEP> ¯ <SEP> 4Hi <SEP> H <SEP> CH30 <SEP> CH30 <SEP> CH <tb> 02033 <SEP> H <SEP> CH3 <SEP> CH3 <SEP> Cue30 <SEP> aI <SEP> CH <tb> O02CH3 <SEP> i-F <SEP> H <SEP> H <SEP> CX30 <SEP> 0330 <SEP> CH <tb> 2CH3 <SEP> 4-ci <SEP> H <SEP> H <SEP> CH3O <SEP> Cg3 <SEP> N <tb> CO2CR3 <SEP> 4-Br <SEP> H <SEP> H <SEP> CX30 <SEP> CH30 <SEP> CH <tb> 02033 <SEP> 4 <SEP> CF3 <SEP> H <SEP> H <SEP> CH30 <SEP> CH3 <SEP> N <tb> o 2CH3 <SEP> 4-CX3 <SEP> H <SEP> H <SEP> CH30 <SEP> CH3 <SEP> N <tb> 02033 <SEP> 5 XE3 <SEP> H <SEP> H <SEP> CH30 <SEP> CH30 <SEP> CH <tb> C 2CH3 <SEP> 4 <SEP> H <SEP> 3B7 <SEP> E <SEP> CH30 <SEP> CH3 <SEP> N <tb> 032CH3 <SEP> S-CH.3CH2CH20 <SEP> H <SEP> H <SEP> C830 <SEP> Q30 <SEP> CH <tb> 02% <SEP> 3-a <SEP> H <SEP> H <SEP> CS30 <SEP> C83 <SEP> N <tb> CDfiH3 <SEP> H <SEP> H <SEP> H <SEP> 0330 <SEP> CH30 <SEP> CH <tb> 02% <SEP> s-a <SEP> H <SEP> H <SEP> CH30 <SEP> CH30 <SEP> N <tb> 0 <tb> C-N(CH3)2 <SEP> g <SEP> H <SEP> H <SEP> OCS3 <SEP> CH3 <SEP> N <tb> <SEP> 2 <tb> H <SEP> EI <SEP> H <SEP> H <SEP> CS3 <SEP> N <tb> <SEP> C2H5 <tb> OH <tb> 1/ <SEP> H <SEP> H <SEP> H <SEP> H <SEP> 033 <SEP> N <tb> C-N <tb> <SEP> CS2CH2CH3 <tb> 0 <tb> H <SEP> H <SEP> H <SEP> C% <SEP> C% <SEP> CH <tb> Ce <tb> EMI89.1 <tb> <SEP> Table <SEP> I <SEP> (continued) <tb> <SEP> P <SEP> h <SEP> R2 <SEP> X <SEP> Y <SEP> z <SEP> m.p.(0C) <tb> 01 <SEP> , > 2ç2 <tb> C-N <SEP> Q3L, <SEP> H <SEP> H <SEP> H <SEP> CN <SEP> 133-3150 <SEP> (dec.) <tb> <SEP> Ca2 < 2 <tb> Oft <SEP> CH2uCX2 <tb> C-N <SEP> CE2 <SEP> H <SEP> B <SEP> H <SEP> m <SEP> OCH <SEP> CH <tb> <SEP> 3 <tb> <SEP> CH2 <tb> O <SEP> QT,-C, <tb> <SEP> L <SEP> L\ <tb> C-N <SEP> O <SEP> H <SEP> H <SEP> H <SEP> n <SEP> mE <tb> <SEP> CE2 < 2 <tb> 0 <tb> CS(C2X,)2 <SEP> H <SEP> H <SEP> H <SEP> H <SEP> % <SEP> CH <tb> H <SEP> H <SEP> 'fZ: <SEP> H <SEP> CE <SEP> 033 <SEP> N <tb> H <SEP> fI <SEP> H <SEP> H <SEP> F <SEP> m <SEP> CH <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> H <SEP> H <SEP> COt <tb> 0 <tb> <SEP> I <SEP> H <SEP> H <SEP> H <SEP> H <SEP> . <SEP> CCC2CH2 <tb> <SEP> 0 <tb> <SEP> cea3 <SEP> g <SEP> E <SEP> E <tb> C <tb> c-N <SEP> (CE3) <SEP> H <SEP> H <SEP> H <SEP> A0 <SEP> C313 <SEP> CH <tb> 0 <tb> C-Nt3)2 <SEP> H <SEP> H <SEP> H <SEP> A0 <SEP> CH3O <SEP> N <tb> 0 <tb> C <SEP> (CH3) <SEP> 2 <SEP> H <SEP> H <SEP> 3 <SEP> 3 <SEP> Cm30 <SEP> CH <SEP> 155-157 <tb> 0 <tb> ,. <tb> C-NSH3 <SEP> H <SEP> H <SEP> H <SEP> CH30 <SEP> CH30 <SEP> CH <SEP> 178-180 <tb> Table II EMI90.1 EMI90.2 <tb> <SEP> - <SEP> R2 <SEP> R4 <SEP> j <SEP> R <SEP> % <SEP> II <SEP> 1 <SEP> p.(oO <tb> <SEP> R <SEP> h <SEP> R2 <SEP> R4 <SEP> W <SEP> 3 <SEP> <SEP> X <SEP> Y <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CR3 <SEP> H <SEP> CR30 <SEP> Cur30 <SEP> 20O-2030(d) <tb> B <SEP> H <SEP> H <SEP> a3 <SEP> 0 <SEP> CH <SEP> H <SEP> > 30 <SEP> t3 <SEP> 200-2050 <SEP> (d) <tb> <SEP> 3 <SEP> CR <tb> CH3 <SEP> H <SEP> CR3 <SEP> O <SEP> CR3 <SEP> H <SEP> CR3 <SEP> 3 <SEP> 209-2100 <SEP> (d) <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> Cur30 <SEP> H <SEP> Cho <SEP> Cur30 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CR3CR2 <SEP> H <SEP> Cur30 <SEP> a3 <tb> H <SEP> S <SEP> H <SEP> CR3 <SEP> O <SEP> CH3CR2CR2 <SEP> H <SEP> CR30 <SEP> Cur30 <tb> H <SEP> H <SEP> B <SEP> > 3 <SEP> 0 <SEP> (CR3)2CR <SEP> H <SEP> Cur30 <SEP> CR30 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> 53( > 2)3 <SEP> H <SEP> Cur30 <SEP> Cur30 <tb> H <SEP> H <SEP> H <SEP> CR3CR2 <SEP> O <SEP> CR3CR2 <SEP> H <SEP> Cur30 <SEP> CR± <tb> B <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CR3 <SEP> G <SEP> Cl <SEP> CR3O <tb> H <SEP> H <SEP> H <SEP> > 3 <SEP> 0 <SEP> > < <SEP> B <SEP> H <SEP> Br <SEP> CR3O <tb> H <SEP> H <SEP> H <SEP> > 3 <SEP> 0 <SEP> CR3 <SEP> H <SEP> CH3CH2 <SEP> CH3O <tb> H <SEP> H <SEP> H <SEP> w3 <SEP> O <SEP> > 3 <SEP> H <SEP> CR3O3O-CR3 <tb> H <SEP> H <SEP> H <SEP> w3 <SEP> 0 <SEP> cur3 <SEP> H <SEP> <SEP> CR3 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> S <SEP> CH3 <SEP> H <SEP> CF3 <SEP> Cur30 <tb> R <SEP> B <SEP> H <SEP> Q3 <SEP> S <SEP> cur3 <SEP> H <SEP> CR3S <SEP> > 30 <tb> H <SEP> H <SEP> H <SEP> > 3 <SEP> O <SEP> w3 <SEP> H <SEP> CR3C=H2 <SEP> a3 <tb> E <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> CR3 <SEP> H <SEP> w322 <SEP> CR30 <tb> Table III EMI91.1 R R1 R2 R4 W R3 R8 X Y Z m.p.( C) H H H CH3 O CH3 H CH3O CH3O CH 172-176 (d) H H H CH3 O CH3 H CH3O CH3 CH 181-183 (d) H H H CH3 O CH3 H CH3 CH3 CH 203-204 (d) H CH3 CH3 CH3 O CH3 H CH3O CH3O CH 3-Cl H H CH3 O CH3 H CH3O CH3O CH 4-Cl H H CH3 O CH3 H CH3O CH3O CH 6-Cl H H CH3 S CH3 H CH3O CH3O CH H H H CH3 O CH3 H H CH3 C-Cl H H H CH3 O CH3 H CH3 CH3 C-CN H H H CH3 O CH3 H CH3 CH3 C-CH3 H H H CH3 O CH3 H H CH3 C-CH3 H H H CH3 O CH3 H CH3 CH3 C-CH2CH3 H H H CH3 O CH3 CH3 CH3 CH3 CH Table IV EMI92.1 EMI92.2 <tb> <SEP> R <SEP> R1 <SEP> R2 <SEP> w <SEP> R8 <SEP> X <SEP> Y <SEP> : :..(0C) <tb> <SEP> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> CH3 <SEP> OCH3 <tb> <SEP> H <SEP> H <SEP> CH3 <SEP> O <SEP> H <SEP> CH3 <SEP> OCH3 <tb> <SEP> H <SEP> CH3 <SEP> CH3 <SEP> 0 <SEP> H <SEP> Oa3 <SEP> OcH3 <tb> 5-CH3 <SEP> H <SEP> H <SEP> O <SEP> H <SEP> C1 <SEP> Br <tb> H <SEP> CH3 <SEP> H <SEP> O <SEP> H <SEP> Cl <SEP> C1 <tb> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> SCH3 <SEP> OCE3 <tb> H <SEP> off <SEP> - <SEP> U <SEP> 0 <SEP> H <SEP> Br <SEP> OCE3 <tb> <SEP> /SC1I3 <tb> B <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> OCH <tb> <SEP> CE3 <tb> H <SEP> H <SEP> H <SEP> 0 <SEP> H <SEP> CF3 <SEP> C1 <tb> H <SEP> H <SEP> H <SEP> 0 <SEP> H <SEP> OC2Hg <SEP> C1 <tb> s <SEP> H <SEP> H <SEP> S <SEP> H <SEP> CR3 <SEP> CR3 <tb> H <SEP> H <SEP> H <SEP> S <SEP> H <SEP> CR3 <SEP> OCE3 <tb> H <SEP> 8 <SEP> H <SEP> S <SEP> H <SEP> OCH3 <SEP> OCH, <tb> H <SEP> H <SEP> H <SEP> 0 <SEP> CR3 <SEP> * <SEP> CR3 <tb> B <SEP> H <SEP> H <SEP> 0 <SEP> CH3 <SEP> CE3 <SEP> OCE3 <tb> H <SEP> H <SEP> H <SEP> O <SEP> CR3 <SEP> OCR3 <SEP> OCE3 <tb> H <SEP> H <SEP> H <SEP> O <SEP> OCH3 <SEP> CR3 <SEP> CR3 <tb> H <SEP> H <SEP> H <SEP> 0 <SEP> OCH3 <SEP> Gel3 <SEP> OCE3 <tb> H. <SEP> H <SEP> H <SEP> 0 <SEP> OCR3 <SEP> CE3 <SEP> OCE3 <tb> Table V EMI93.1 R R1 R2 W R8 X Y Z m.p. ( C) H H H 0 H 0CH3 OCH3 CH H H CH3 O H CH3@ OCH3@ CH H H CH3 O H OCH3 OCH3 CH H CH3 CH3 O H OCH3 OCH3 CH 4- Cl H H O H CH3 CH3 CH 6- Cl H H O H CH3 OCH3 CH 4- Cl H H O H OCH3 OCH3 CH 4- NO2 H H O H CH3 CH3 CH 4-OCH3 H H O H CH3 OCH3 CH 4- CF3 H H O H CH3 OCH3 CH H H H O H H CH3 CCl H H H O H CH3 CH3 C-CN H H H O H CH3 CH3 C-CH3 H H H O H CH3 CH3 C-CH2CH3 H H H O H H CH3 C-CH2CH2Cl H CH3 CH3 O H H OCH3 C-Cl H H H S H CH3 OCH3 CH H H H S H OCH3 OCH3 CH H H H O CH3 CH3 OCH3 CH H H H O CH3 OCH3 OCH3 CH H H H O OCH3 OCH3 OCH3 CH 4-CH3 H H O H OCH3 OCH3 CH H H H O H CH2OCH3 CH3 CH H H H O H SCH3 OCH3 CH Table VI EMI94.1 EMI94.2 <tb> <SEP> R <SEP> 21 <SEP> R2 <SEP> 11 <SEP> W <SEP> 8 <SEP> R8 <SEP> X <SEP> Y <SEP> ¯¯¯¯¯¯ <tb> H <SEP> H <SEP> s <SEP> H <SEP> o <SEP> H <SEP> OCE3 <SEP> oCX3 <tb> g <SEP> H <SEP> H <SEP> 43 <SEP> o <SEP> R <SEP> CH3 <SEP> OCE3 <tb> H <SEP> H <SEP> B <SEP> w23 <SEP> 0 <SEP> H <SEP> H3 <SEP> 3 <tb> B <SEP> H <SEP> H <SEP> a3 <SEP> 0 <SEP> H <SEP> Ca3 <SEP> CE3 <tb> H <SEP> H <SEP> H <SEP> CR2Cl <SEP> o <SEP> H <SEP> Ca3 <SEP> 03 <tb> H <SEP> H <SEP> H <SEP> CB;M'(B1 <SEP> 0 <SEP> E <SEP> CH3 <SEP> owe3 <tb> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> E <SEP> > 3 <SEP> OCE3 <tb> <SEP> Cl <tb> H <SEP> H <SEP> E <SEP> 0 <SEP> H <SEP> Cur3. <SEP> OCE3 <tb> <SEP> Cl <tb> E <SEP> H <SEP> H <SEP> O)-NO2 <SEP> 0 <SEP> H <SEP> OM3 <SEP> OCS3 <tb> H <SEP> 13 <SEP> H <SEP> 033 <SEP> 0 <SEP> H <SEP> CH20CH3 <SEP> 0033 <tb> H <SEP> H <SEP> H <SEP> Clig <SEP> O <SEP> H <SEP> s <SEP> Ca3 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> H <SEP> OCE3 <tb> H <SEP> H <SEP> H <SEP> 13 <SEP> 0 <SEP> H <SEP> Br <SEP> OCR3 <tb> H <SEP> H <SEP> H <SEP> -0320CR3 <SEP> O <SEP> H <SEP> 5033 <SEP> 033 <tb> <SEP> OCE3 <tb> H <SEP> H <SEP> E <SEP> < <SEP> O <SEP> E <SEP> 0033 <SEP> oa3 <tb> <SEP> OCa3 <tb> Table VII EMI95.1 EMI95.2 <tb> <SEP> R <SEP> h <SEP> 2 <SEP> R11 <SEP> W <SEP> R8 <SEP> y <SEP> z <SEP> m.p.(C) <tb> <SEP> H <SEP> H <SEP> H <SEP> H <SEP> 0 <SEP> H <SEP> CR3 <SEP> 033 <SEP> CR <tb> <SEP> H <SEP> 2 <SEP> B <SEP> w3 <SEP> <SEP> H <SEP> 23 <SEP> 0033 <SEP> CR <tb> <SEP> H <SEP> H <SEP> B <SEP> 33 <SEP> O <SEP> H <SEP> w3 <SEP> 0033 <SEP> CR <tb> <SEP> 6-Cl <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> =3 <SEP> OCH3 <SEP> a <tb> <SEP> H <SEP> H <SEP> H <SEP> > 3 <SEP> o <SEP> H <SEP> C1 <SEP> oZ3 <SEP> CR <tb> <SEP> H <SEP> - <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> B <SEP> 33 <SEP> 03- <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> SCR <SEP> OCE3 <SEP> COR <tb> <SEP> H <SEP> H. <SEP> H <SEP> S <SEP> CR3 <SEP> C <SEP> H <SEP> 23 <SEP> CR3 <SEP> cz <tb> <SEP> H <SEP> H <SEP> H <SEP> 033 <SEP> O <SEP> H <SEP> CR20033 <SEP> 0033 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> S. <SEP> OCH <SEP> CR <tb> <SEP> X <SEP> 3 <SEP> H <SEP> < -* <SEP> S <SEP> s <SEP> > 3 <SEP> OCI, <SEP> CR <tb> <SEP> S <SEP> H <SEP> H <SEP> CR3 <SEP> S <SEP> H <SEP> s <SEP> 0033 <SEP> CR <tb> <SEP> }R <SEP> a <SEP> H <SEP> < <SEP> S <SEP> H <SEP> OCR3 <SEP> OCE3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> S <SEP> H <SEP> 0033 <SEP> CR3 <SEP> CR <tb> <SEP> Cd3 <tb> 5-03 <SEP> H <SEP> H <SEP> 53 <SEP> S <SEP> H <SEP> 053 <SEP> a3 <SEP> COR <tb> <SEP> Qlg <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> S <SEP> H <SEP> OCH3 <SEP> CCH3 <SEP> CH <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> <SEP> CH3 <SEP> =3 <SEP> OCH3 <SEP> CH <tb> Table VIII EMI96.1 EMI96.2 <SEP> P <tb> R <SEP> RI <SEP> 2 <SEP> R12 <SEP> W <SEP> P8 <SEP> X <SEP> Y <SEP> m..(0C) <tb> H <SEP> II <SEP> H <SEP> H <SEP> O <SEP> H <SEP> CH3 <SEP> CH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> -CH3 <SEP> 0 <SEP> H <SEP> OCH3 <SEP> OCR3 <tb> <SEP> R <SEP> H <SEP> H <SEP> -CH2CH3 <SEP> 0 <SEP> H <SEP> CH3 <SEP> OCH3 <tb> <SEP> H <SEP> H <SEP> CR3 <SEP> CH3 <SEP> O <SEP> H <SEP> OCH3 <SEP> SOCH, <tb> 4wCF3 <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> H <SEP> OCH <SEP> OCH3 <tb> 44 <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> H <SEP> CH3 <SEP> OCH3 <tb> <SEP> 3 <SEP> 3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> O <SEP> H <SEP> C1 <SEP> OCH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> SCH3 <SEP> OCH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> 3 <SEP> 0 <SEP> H <SEP> CH20CB30CH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> H <SEP> H <SEP> CH3 <tb> <SEP> H <SEP> H. <SEP> H <SEP> O <SEP> H <SEP> R <SEP> OCH3 <SEP> OCR3 <tb> <SEP> s <SEP> H <SEP> H <SEP> ; & 0F <SEP> O <SEP> H <SEP> OCR3 <SEP> CR3 <tb> <SEP> C1 <tb> <SEP> H <SEP> H <SEP> H <SEP> b <SEP> C2H5 <SEP> O <SEP> H <SEP> OCH3 <SEP> OCR3 <tb> <SEP> CB <tb> <SEP> H <SEP> H <SEP> 2 <SEP> O <SEP> H <SEP> 3 <SEP> CH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CN <SEP> 0 <SEP> H <SEP> 0CN3 <SEP> CR3 <tb> <SEP> Br <SEP> > ¯s <SEP> ,CH3 <tb> <SEP> fl <SEP> H <SEP> H <SEP> \CE <SEP> <SEP> H <SEP> CR3 <SEP> 0CH3 <tb> <SEP> OCEx <SEP> 3 <SEP> ¯ <tb> <SEP> gH <SEP> C1 <SEP> 0 <SEP> H <SEP> cur3 <SEP> OCH3 <tb> <SEP> CR <tb> <SEP> /3 <tb> <SEP> R <SEP> H <SEP> H <SEP> BC <SEP> H2CoCR <SEP> O <SEP> H <SEP> cur3 <SEP> SOCH3 <tb> <SEP> CR3 <tb> <SEP> p <SEP> H <SEP> H <SEP> CH3 <SEP> S <SEP> H <SEP> OCEi3 <SEP> CCH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> O <SEP> =3 <SEP> n3 <SEP> CCH3 <tb> Table IX EMI97.1 EMI97.2 <tb> R <SEP> h <SEP> R2 <SEP> R12 <SEP> W <SEP> R8 <SEP> X <SEP> p <SEP> Z <SEP> m,P.(c) <tb> H <SEP> H <SEP> H <SEP> H <SEP> o <SEP> R <SEP> CH3 <SEP> OCH3 <SEP> COR <tb> H <SEP> H <SEP> H <SEP> -CR3 <SEP> 0 <SEP> H <SEP> CR3 <SEP> OCH, <SEP> CR <tb> H <SEP> H <SEP> H <SEP> CR=CR2 <SEP> 0 <SEP> H <SEP> CR3 <SEP> =3 <SEP> CR <tb> u <SEP> H <SEP> H <SEP> 4 <SEP> H <SEP> E <SEP> OCH3 <SEP> CR <tb> 4-F <SEP> H <SEP> H <tb> <SEP> O <SEP> H <SEP> OCH3 <SEP> CCH3 <SEP> CR <tb> <SEP> 44 <SEP> H <SEP> 3 <SEP> <SEP> E <SEP> a <SEP> n <tb> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> H <SEP> =3 <SEP> CR <tb> 4-N 2 <SEP> H <SEP> H <SEP> a3 <SEP> 0 <SEP> H <SEP> 0CR3 <SEP> coy3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> Br <SEP> Br <SEP> OCR3 <SEP> CR <tb> H <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> H <SEP> 0CR2Ca3 <SEP> cur3 <SEP> CH. <tb> <SEP> o <SEP> fZ <SEP> H <SEP> OCH(CR3)2 <SEP> CR3 <SEP> cH <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> Cr3 <SEP> 0C3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> E <SEP> > 3 <SEP> 0 <SEP> H <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> 0 <SEP> H <SEP> s <SEP> n <SEP> a3 <SEP> OCH3 <SEP> O <tb> <SEP> X <SEP> H <SEP> H <SEP> CR2-(CR2)4CH3 <SEP> O <SEP> s <SEP> G3 <SEP> 0cur3 <SEP> a <tb> <SEP> H <SEP> g <SEP> s <SEP> 42" <SEP> 3 <SEP> 0 <SEP> H <SEP> CR3 <SEP> =3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> < <SEP> o <SEP> H <SEP> OCR3 <SEP> SOCH3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> SO2CH3 <SEP> O <SEP> H <SEP> a3 <SEP> OCX3 <SEP> CR <tb> <SEP> N <SEP> N <SEP> H <SEP> S3 <SEP> 0 <SEP> o <SEP> H <SEP> OCR3 <SEP> SOCH3 <SEP> CR <tb> Table X EMI98.1 EMI98.2 <tb> <SEP> R <SEP> RI <SEP> P2 <SEP> R13 <SEP> W <SEP> R8 <SEP> X <SEP> Y <SEP> m.p.¯( C) <tb> <SEP> ii <SEP> H' <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> G3 <SEP> w3 <tb> <SEP> H <SEP> H <SEP> R <SEP> cur3 <SEP> - <SEP> 0 <SEP> H <SEP> CR3 <SEP> 0CR3 <tb> <SEP> H <SEP> B <SEP> H <SEP> 2CR3 <SEP> 0 <SEP> N <SEP> OCR.3 <SEP> OCz <tb> <SEP> H <SEP> H <SEP> H <SEP> 6 <SEP> H <SEP> E <SEP> oZ3 <SEP> ow3 <tb> <SEP> H <SEP> H <SEP> B <SEP> 0 <SEP> H <SEP> > 3 <SEP> 3 <tb> <SEP> s <SEP> a <SEP> w3 <SEP> Cur <SEP> 3 <SEP> 0 <SEP> H <SEP> w3 <SEP> 0CH3 <tb> <SEP> F <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> m3 <SEP> OCR3 <tb> <SEP> 4 <SEP> < <SEP> g <SEP> H <SEP> w3 <SEP> 0 <SEP> H <SEP> W3 <SEP> m3 <tb> H <SEP> H <SEP> H <SEP> CR <SEP> o <SEP> H <SEP> < <tb> H <SEP> B <SEP> H <SEP> (3)4CR3 <SEP> 0 <SEP> H <SEP> r3 <SEP> OCR3 <tb> H <SEP> H <SEP> H <SEP> +3 <SEP> O <SEP> H <SEP> r3 <SEP> OCR3 <tb> H <SEP> H <SEP> R <SEP> CH3 <SEP> S <SEP> H <SEP> OCH3 <SEP> OCH3 <tb> H <SEP> H <SEP> H <SEP> CH3 <SEP> S <SEP> CR3 <SEP> cur3 <SEP> OCH3 <tb> H <SEP> H <SEP> H <SEP> CH3 <SEP> S <SEP> OCH3 <SEP> CR3 <SEP> CR3 <tb> H <SEP> H <SEP> B <SEP> CR3 <SEP> <SEP> H <SEP> OCR <tb> 8 <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> E <SEP> OCR <SEP> n3 <tb> 43 <SEP> H.. <SEP> H <SEP> f <SEP> CR3 <SEP> 0 <SEP> H <SEP> OCR3 <SEP> =3 <tb> <SEP> H <SEP> H <SEP> E <SEP> CR3 <SEP> 0 <SEP> H <SEP> OCt(M3)2 <SEP> CR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> w3 <SEP> 0 <SEP> H <SEP> U3 <SEP> OCd3 <tb> Table XI EMI99.1 R R1 R2 R13 W R8 X Y Z m.p. ( C) H H H CH3 O H OCH3 OCH3 CH H H H CH2CH3 O H CH3 OCH3 CH H CH3 CH3 CH3 O H OCH3 OCH3 CH H H H CH3 O H H CH3 CCl H H H CH3 O H CH3 CH3 C-CN H H H CH3 O H H CH3 CCH3 H H H CH3 O H CH3 CH3 CCH2CH3 H H H CH3 O H H CH3 CCH2CH3 H H H CH3 O H CH3 CH3 C-CH2CH2Cl H H H CH3 O H H CH3 C-CH2CH-CH2 H H H CH2CH2CH3 O H OCH3 CH3 CH H H H CH3 O H CH3 OCH3 CH2 H H H CH3 O H OCH3 OCH3 CH2 H H H CH3 O OCH3 CH3 OCH3 CH2 Table XII EMI100.1 L R R1 R2 X Y Z OCH3 H H H CH3 CH3 CH OCH3 H H H OCH3 OCH3 CH SCH3 H H H CH3 CH3 CH SCH3 H H H OCH3 OCH3 CH S(O)CH3 H H H OCH3 OCH3 CH S(O)2CH3 H H H OCH3 OCH3 CH SCH3 H CH3 H OCH3 OCH3 CH S(O)2C2H5 H CH3 H OCH3 CH3 CH (S)CH2CH2CH3 H H H OCH3 CH3 N S(O)2CF3 H H H OCH3 CH3 N OCH3 H CH3 H OCH3 CH3 N SCH3 H CH3 H OCH3 CH3 N S(O)CH3 H CH3 H OCH3 CH3 N S(O)2CH3 H CH3 H OCH3 CH3 N Table XIII EMI101.1 EMI101.2 <tb> <SEP> L <SEP> S <SEP> t* <SEP> X <SEP> Y <SEP> Z <SEP> m.p.(oC) <tb> <SEP> L <SEP> K <SEP> RI <SEP> R2 <SEP> PS <SEP> t <SEP> x <SEP> Y <SEP> Z <SEP> m.p.(0C) <tb> C1 <SEP> H <SEP> N <SEP> H <SEP> CR3 <SEP> 0 <SEP> CH <SEP> CR3 <SEP> CR <tb> C1 <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CCR3 <SEP> CS3 <SEP> CN <tb> C1 <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> OCN3 <SEP> 3 <tb> C1 <SEP> H <SEP> H <SEP> H <SEP> CR <SEP> <SEP> a3 <SEP> CR3 <SEP> N <tb> C1 <SEP> H <SEP> H <SEP> X <SEP> CR3 <SEP> O <SEP> 23 <SEP> CCN3 <SEP> N <tb> <SEP> C1 <SEP> 3 <SEP> N <SEP> H <SEP> Cur3 <SEP> 0 <SEP> CO-3 <SEP> OCR3 <SEP> N <tb> <SEP> ,3 <SEP> a <SEP> H <SEP> H <SEP> CH3 <SEP> O <SEP> OC83 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> OCH3 <SEP> 'OCR3 <SEP> CR <tb> <SEP> H <SEP> H <SEP> H <SEP> ca3 <SEP> o <SEP> OCR3 <SEP> CEI3 <SEP> N <tb> <SEP> 0 <tb> <SEP> win3 <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> O <SEP> CCN3 <SEP> CR3 <SEP> N <tb> <SEP> O <tb> <SEP> n <tb> <SEP> Z <SEP> 3 <SEP> H <SEP> H <SEP> H <SEP> CR <SEP> 0 <SEP> OCH3 <SEP> OCR3 <SEP> 3 <tb> <SEP> 3 <tb> <SEP> Cl <SEP> H <SEP> H <SEP> H <SEP> H <SEP> S <SEP> CH3 <SEP> CR3 <SEP> COR <tb> <SEP> Cl" <SEP> H <SEP> H <SEP> H <SEP> OCH, <SEP> 0 <SEP> CH3 <SEP> CR3 <SEP> CR <tb> <SEP> OCC3 <SEP> H <SEP> H <SEP> H <SEP> E3 <SEP> O <SEP> CR3 <SEP> a3 <SEP> C <tb> <SEP> =3 <SEP> H <SEP> ai3 <SEP> H <SEP> CCH3 <SEP> <SEP> r3 <SEP> CCR3 <SEP> CR <tb> <SEP> SCR3 <SEP> H <SEP> CR3 <SEP> H <SEP> CCH3 <SEP> <SEP> CR3 <SEP> CH3 <SEP> COR <tb> <SEP> S <SEP> ( ) <SEP> 2Cz3 <SEP> H <SEP> H <SEP> H <SEP> X3 <SEP> 0 <SEP> OCR3 <SEP> CH3 <SEP> CH <tb> <SEP> H <SEP> H <SEP> H <SEP> H <SEP> =3CCH3 <SEP> 0 <SEP> CCR3 <SEP> CR3 <SEP> CR <tb> <SEP> SCE <SEP> H <SEP> H <SEP> H <SEP> ova3 <SEP> o <SEP> CCR3 <SEP> CR3 <SEP> CR <tb> Table XIV EMI102.1 m.p. R R1 R2 R4 W R3 R8 Y' Q ( C) H H H CH3 O CH3 H C2H5O O H H H CH3 O CH3 H CH3O O H H H CH3 O CH3 H CH3 O H H H CH3 O CH3O H CH3O O Table XV EMI103.1 EMI103.2 <tb> <SEP> R <SEP> h <SEP> h <SEP> 3 <SEP> w <SEP> R8 <SEP> T' <SEP> ¯¯¯¯¯¯ <tb> H <SEP> H <SEP> H <SEP> cur3 <SEP> 0 <SEP> B <SEP> Size <SEP> O <tb> IL <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> Ht <SEP> 0CH3 <SEP> 'O <tb> H <SEP> H <SEP> H <SEP> CR2013 <SEP> O <SEP> H <SEP> CR3 <SEP> 0 <tb> H <SEP> H <SEP> CR3 <SEP> CR3 <SEP> 0 <SEP> H <SEP> OUR3 <SEP> O <tb> H <SEP> CR3 <SEP> CR3 <SEP> CR3 <SEP> 0 <SEP> H <SEP> oa3 <SEP> O <tb> <SEP> a <SEP> H <SEP> CR3 <SEP> Q <SEP> H <SEP> OCR3 <SEP> 0 <tb> 4-C1 <SEP> H <SEP> H <SEP> w3 <SEP> 0. <SEP> H <SEP> m3 <SEP> 0 <tb> 4-CR3 <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> , <SEP> a <SEP> 'a <tb> 4 <SEP> CF3 <SEP> H <SEP> E <SEP> CR <SEP> 0 <SEP> H <SEP> CR3 <SEP> w <tb> 6-C1 <SEP> H <SEP> H <SEP> CR3. <SEP> 0 <SEP> H <SEP> > 3 <SEP> <tb> B <SEP> H <SEP> H <SEP> =3, <SEP> O <SEP> a.4 <SEP> O <tb> s <SEP> H <SEP> H <SEP> CR3 <SEP> O <SEP> H. <SEP> 52 <tb> H <SEP> H <SEP> H <SEP> cur3 <SEP> 0 <SEP> Th <SEP> Ci <SEP> CR2 <tb> H <SEP> 8 <SEP> H <SEP> w3 <SEP> 0 <SEP> H <SEP> G3 <SEP> CR,2 <tb> B <SEP> B <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> 0a3 <SEP> CR2 <tb> H <SEP> H <SEP> H <SEP> C2CR2 <SEP> CR3 <SEP> O <SEP> B <SEP> 0CH3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> OCH3 <SEP> O <tb> <SEP> E <SEP> B <SEP> H <SEP> CR3 <SEP> S <SEP> H <SEP> 53 <SEP> > 2 <tb> <SEP> s <SEP> H <SEP> H <SEP> cur3 <SEP> 0 <SEP> 03 <SEP> OCH3 <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> OCH3 <SEP> OCR3 <SEP> CR2 <tb> Ii <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> C2R5 <SEP> 0 <tb> <SEP> H <SEP> H <SEP> B <SEP> CR3 <SEP> 0 <SEP> H <SEP> OC285 <SEP> cur2 <tb> Table XVI EMI104.1 EMI104.2 <tb> <SEP> P <SEP> h <SEP> R2 <SEP> 12 <SEP> w <SEP> P8 <SEP> ?' <SEP> Q <SEP> m.p.('C) <tb> E <SEP> H <SEP> H <SEP> H <SEP> 0 <SEP> H <SEP> OCR3 <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> Cur3 <SEP> 0 <SEP> H <SEP> CR3 <SEP> 0 <tb> <SEP> H <SEP> 'H <SEP> H <SEP> CR3 <SEP> O <SEP> H <SEP> OCR3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> CR2CR'-CR2 <SEP> O <SEP> H <SEP> 0CH3 <SEP> O <tb> <SEP> H <SEP> H <SEP> B <SEP> 6 <SEP> 0 <SEP> H <SEP> CR3 <SEP> O <tb> s <SEP> H <SEP> CR3 <SEP> 53 <SEP> OH <SEP> 0CR3 <SEP> 0 <tb> H <SEP> CR3 <SEP> CR3 <SEP> CR3 <SEP> o <SEP> El <SEP> OCR3 <SEP> 0 <tb> B <SEP> H <SEP> H <SEP> Q3 <SEP> 0 <SEP> H <SEP> H' <SEP> o <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> H <SEP> CR2 <tb> H <SEP> 8 <SEP> H <SEP> CIT9 <SEP> H' <SEP> ci <SEP> CR <tb> CR3 <SEP> 0 <SEP> H <SEP> 2 <tb> H <SEP> s <SEP> H <SEP> CR3 <SEP> 0 <SEP> s <SEP> CR3 <SEP> > 2 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> S <SEP> H <SEP> ORE3 <SEP> 01 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> S <SEP> H <SEP> CR3 <SEP> cur2 <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CR3 <SEP> OCR3 <SEP> CR2 <tb> H <SEP> H <SEP> H <SEP> g3 <SEP> 0 <SEP> OCE3 <SEP> CR3 <SEP> o <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> OH <SEP> oc2s <SEP> o <tb> <SEP> H <SEP> H <SEP> H-CR2-(CR2)4CR3 <SEP> 0 <SEP> H <SEP> OCH3 <SEP> o <tb> <SEP> H <SEP> H <SEP> H <SEP> zSCH3 <SEP> 0 <SEP> B <SEP> CH3 <tb> EMI104.3 <tb> <SEP> CR <tb> H <SEP> H <SEP> G3 <SEP> <SEP> H <SEP> OCE3 <tb> <SEP> 3 <tb> <SEP> 3 <tb> Table XVII EMI105.1 L R R1 R2 Y' O R8 W CO2CH3 H H H CH3 O H O CO2C2H5 H CH3 CH3 CH3O O H O CO2CH3 H H H CH3 CH2 CH3 O CO2CH3 H H H CH3O O H S S(O)CH3 H H H CH3O O H O OCH(CH3)2 H H H CH3O O H O OC2H5 H H H CH3O H O SCH3 H H H CH3O O H CH2 Table XVIII EMI106.1 EMI106.2 <tb> R <SEP> RI <SEP> P2 <SEP> 11 <SEP> w <SEP> R8 <SEP> Y <SEP> Q <SEP> 4 <SEP> ¯¯¯¯¯¯ <tb> H <SEP> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> CR3 <SEP> o <tb> s <SEP> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> B <SEP> OCR3 <SEP> O <tb> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> CR3 <SEP> 0 <tb> H <SEP> t <SEP> H <SEP> cur3 <SEP> 0 <SEP> H <SEP> OCR3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> 'CR2CH3 <SEP> 0 <SEP> H <SEP> CR3 <SEP> 0 <tb> H <SEP> H <SEP> B <SEP> U3 <SEP> O <SEP> H <SEP> CR3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> Cr3 <SEP> 0 <SEP> H <SEP> OCR3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> CR2C1 <SEP> O <SEP> H <SEP> our3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> CR2CR-CR2 <SEP> O <SEP> H <SEP> OCR3 <SEP> O <tb> H <SEP> R <SEP> s <SEP> 6 <SEP> o <SEP> s <SEP> CR3 <SEP> 0 <tb> H <SEP> H <SEP> CR3 <SEP> CR3 <SEP> 0 <SEP> H <SEP> n3 <SEP> 0 <tb> H <SEP> CR3 <SEP> CR3 <SEP> 3 <SEP> 0 <SEP> R <SEP> oca; <SEP> o <tb> <SEP> H <SEP> H <SEP> s <SEP> CR3 <SEP> 0 <SEP> H <SEP> C1 <SEP> CH2 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> o <SEP> s <SEP> OCR3 <SEP> a- <SEP> <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> S <SEP> H <SEP> CR3 <SEP> 0 <tb> <SEP> X <SEP> s <SEP> H <SEP> CR3 <SEP> S <SEP> s <SEP> 03 <SEP> CR2 <tb> <SEP> H <SEP> H <SEP> H <SEP> CE3 <SEP> O <SEP> CR3 <SEP> CR3 <SEP> o <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> 0CR3 <SEP> cur3 <SEP> a2 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> CR3 <SEP> OCt3 <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> CF <SEP> O <SEP> R <SEP> C2Hs <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> Cl <SEP> o <SEP> H <SEP> OC2Hg <SEP> CE2 <tb> <SEP> H <SEP> H <SEP> E <SEP> 0 <SEP> z <SEP> H <SEP> a <SEP> > 3 <SEP> O <tb> <SEP> H <SEP> H <SEP> -CHCR2 <SEP> 0 <SEP> H <SEP> CR3 <SEP> 0 <tb> C2 <SEP> 5 <SEP> H <SEP> H <SEP> H <SEP> --CHCR2 <SEP> o <SEP> E <SEP> CH3 <SEP> 0 <tb> 4CR,3 <SEP> H <SEP> H <SEP> cur3 <SEP> 2 <SEP> R <SEP> H <SEP> a3 <SEP> CR2 <tb> H <SEP> H <SEP> H <SEP> O <SEP> H <SEP> CR3 <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> CE2CF3 <SEP> O <SEP> H <SEP> QX3 <SEP> d <tb> Table XIX EMI107.1 EMI107.2 <tb> <SEP> R <SEP> Pl <SEP> R8 <SEP> R5 <SEP> Q <SEP> O <tb> <SEP> c <tb> <SEP> N <SEP> CH <SEP> 3 <SEP> N <SEP> CN3 <SEP> O <SEP> C1 <tb> <SEP> E <SEP> E <SEP> H <SEP> H <SEP> CH'O <SEP> <SEP> C1 <tb> <SEP> 3 <tb> <SEP> Z <SEP> N- <SEP> N <SEP> H <SEP> C1 <SEP> 0 <SEP> C1 <tb> <SEP> H <SEP> H <SEP> H <SEP> N <SEP> H <SEP> E <tb> <SEP> H <SEP> H <SEP> R <SEP> H <SEP> CE. <SEP> 3 <SEP> CH2 <SEP> C1 <tb> H <SEP> E <SEP> N <SEP> CN3O <SEP> CH2 <SEP> C1 <tb> <SEP> H <SEP> Cl <SEP> N <SEP> H <SEP> CH3 <SEP> 0 <SEP> CN2 <tb> <SEP> H <SEP> H. <SEP> H <SEP> H <SEP> Ca3 <SEP> C <SEP> 3r <tb> <SEP> H <SEP> N <SEP> H <SEP> N <SEP> H <SEP> 0 <tb> <SEP> H <SEP> N <SEP> N <SEP> H <SEP> CH3 <SEP> C <tb> H <SEP> H <SEP> H <SEP> H <SEP> a3 <SEP> 0 <SEP> 2ECOCH3 <tb> <SEP> N <SEP> H <SEP> H <SEP> H <SEP> cox3 <SEP> 0 <SEP> SR.N'XCH <tb> H <SEP> H <SEP> H <SEP> H <SEP> CH3O <SEP> O <SEP> NHCH3 <SEP> 2 <tb> N <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <SEP> NCH,COHC <tb> Table XIX (continued) R R1 R2 R8 Y' O L H H H H CH3 O N(C2H5)CO2CH3 H H H H CH3 O NHCO2Et H H H H CH3 O Cl 4-F H H H CH3O CH2 Cl 4-Cl H H H CH3O CH2 Cl 4-Br H H H CH3O CH2 Cl 4-NO2 H H H CH3O CH2 Cl 4-CF3 H H H CH3O CH2 Cl 5-CH3 H H H CH3O CH2 Cl 4-CH(CH3)2 H H H CH3O CH2 Cl 4-OCH3 H H H CH3O CH2 Cl 5-OCH(CH3)2 H H H CH3O CH2 Cl H H H H OCH2CH3 CH2 Cl H H H H OCH2CH3 O Cl H H H CH3 CH3 CH2 Cl H H H CH3 OCH3 CH2 Cl H H H H CH3 O CH H H CH3 H CH3 O CH H H CH3 H OCH3 O OH H CH3 CH3 H CH3 O OH H H H H H CH2 OH H H H H Cl CH2 OH H H H H CH3 CH2 OH H H H H H O OH 4-CH3 H H H OCH3 O OH 5-OC2H5 H H H CH3 O OH 4-OCH2CH2CH3 H H H OCH3 O OH H H H CH3 CH3 O OH H H H CH3 OCH3 O OH H H H H OC2H5 O OH H H H H OC2H5 CH2 OH Table XX EMI109.1 EMI109.2 <tb> <SEP> R <SEP> h <SEP> P2 <SEP> 13 <SEP> W <SEP> R8 <SEP> ' <SEP> m.p. <SEP> (OC) <tb> <SEP> H <SEP> H <SEP> H <SEP> -CR3 <SEP> 0 <SEP> H <SEP> w3 <tb> <SEP> H <SEP> ' <SEP> o <SEP> X <SEP> (O <SEP> H <tb> <SEP> H <SEP> H <SEP> l <SEP> -CR2CR3 <SEP> O <SEP> H <SEP> CR3 <tb> <SEP> H <SEP> HH <SEP> 6 <SEP> O <SEP> X <SEP> CR3 <tb> <SEP> H <SEP> H <SEP> CR3 <SEP> CE3 <SEP> O <SEP> H <SEP> OCR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> B <tb> <SEP> B <SEP> H <SEP> H. <SEP> CR3 <SEP> 0 <SEP> 1 <SEP> Cl <tb> 4-OCiH5 <SEP> H <SEP> a <SEP> CR3 <SEP> O <SEP> E <SEP> 0CR3 <tb> <SEP> CR3 <tb> <SEP> a <SEP> H <SEP> E <SEP> S <SEP> a3 <SEP> <SEP> H <SEP> 0a3 <tb> <SEP> 3 <tb> <SEP> 4-CR3 <SEP> H <SEP> H <SEP> CH3 <SEP> OOH <SEP> OCR3 <tb> <SEP> 4 <SEP> U3 <SEP> H <SEP> H <SEP> cur3 <SEP> oG3 <tb> <SEP> B <SEP> H <SEP> H <SEP> a3 <SEP> S <SEP> H <SEP> OCH3 <tb> <SEP> H <SEP> H <SEP> H <SEP> a3 <SEP> o <SEP> CR3 <SEP> a3 <tb> <SEP> H <SEP> a3 <SEP> 0 <SEP> CH3 <SEP> 0 <SEP> CR3 <SEP> OCR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> =3 <SEP> OCH, <tb> Table XXI EMI110.1 EMI110.2 <tb> R2 <SEP> R, <SEP> R12 <SEP> W <SEP> R8 <SEP> yt <SEP> m-D-( C) <tb> <SEP> H <SEP> H <SEP> B <SEP> H <SEP> O <SEP> H <SEP> CR3 <tb> <SEP> H <SEP> H <SEP> -CR <SEP> 0 <SEP> H <SEP> OCR3 <tb> <SEP> H <SEP> H <SEP> B <SEP> -CR2CH3 <SEP> 0 <SEP> tI <SEP> CR3 <tb> <SEP> 0 <SEP> H <SEP> CR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH(CR3)2 <SEP> - <SEP> ' <SEP> OCR <tb> <SEP> H <SEP> s <SEP> B <SEP> CR2CRCR2 <SEP> ooh <SEP> 3 <tb> <SEP> b <SEP> H <SEP> H <SEP> OH <SEP> CR3 <tb> <SEP> fl <SEP> ' <SEP> H <SEP> CH3 <SEP> o <SEP> O <SEP> H <SEP> OCR3 <tb> <SEP> 3 <tb> <SEP> R <SEP> s <SEP> H <SEP> B <SEP> CR3 <SEP> oH <SEP> WI3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR <SEP> OH <SEP> H <tb> H <SEP> 8 <SEP> H <SEP> CS <SEP> O <SEP> H <SEP> O <SEP> B <SEP> C1 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR <tb> <SEP> CR3 <SEP> 0 <SEP> H <SEP> 3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> H <SEP> Q3 <tb> <SEP> Q3 <SEP> o <SEP> X <SEP> Q3 <tb> <SEP> H <SEP> H <SEP> E <SEP> CH3 <SEP> S <SEP> H <SEP> a3 <tb> <SEP> H <SEP> H <SEP> H <SEP> cur3 <SEP> S <SEP> H <SEP> OCR3 <tb> <SEP> 8 <SEP> H <SEP> B <SEP> CR3 <SEP> O <SEP> CR3 <SEP> CR3 <tb> <SEP> H <SEP> B <SEP> H <SEP> CR3 <SEP> <SEP> CR3 <SEP> OCR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> a3 <SEP> O <SEP> OCR3 <SEP> cur3 <tb> <SEP> 13 <SEP> H <SEP> H <SEP> CR3 <SEP> 0 <SEP> OCH3 <SEP> OCR3 <tb> <SEP> H <SEP> H <SEP> H <SEP> CR3 <SEP> o <SEP> m3 <SEP> OC2H5 <tb> <SEP> 3 <SEP> 0 <SEP> B <SEP> C2R5 <tb> s <SEP> H <SEP> H <SEP> -CH2-(CR2)4CR3 <SEP> O <SEP> s <SEP> 3 <tb> H <SEP> H <SEP> H <SEP> CR2CH-cH-CH3 <SEP> 0 <SEP> H <SEP> CR3 <tb> H <SEP> H <SEP> H <SEP> . <SEP> O <SEP> E <SEP> a3 <tb> Table XXII EMI111.1 R R1 R2 R11 W R8 Y' m.p. ( C) H H H H O H CH3 H H H H O H OCH3 H H H CH3 O H CH3 H H H CH3 O H OCH3 4-OC2H5 H H -CH-CH2 O H CH3 4-CH3 H H CH3 O H CH3 5-CH3 H H CH3 O H OCH3 5-NO2 H H CH3 O H OCH3 5-OCH3 H H CH3 O H OCH3 3-CF3 H H CH3 O H OCH3 5-Cl H H CH3 O H CH3 6-Cl H H CH3 O H CH3 Table XXIII EMI112.1 R R1 R2 W R8 Y' m.p.( C) H H H O H CH3 H H H O H OCH3 H H CH3 O H CH3 H H CH3 O H OCH3 H CH3 CH3 O H CH3 H H H O H OCH3 H H H O H H 5-CH3 H H O H OCH3 4-CH3 H H O H Cl 4-OCH2CH2CH3 H H O H OCH3 H H H S H CH3 H H H S H OCH3 H H H O CH3 CH3 Table XXIV EMI113.1 R R1 R2 R3 R4 W R8 Y' H H H CH3 CH3 O H CH3 H H H CH3 CH3 O H C2H5O H H H CH3 CH3 O H H H H H CH3 CH3 S H CH3O H CE3 CE3 CH3 CH3 O H CH30 3-Cl H H CH3 CH3 O H CH3O 4-Cl H H CH3 CH3 O H CH3O 5-Cl H H CH3 CH3 O H CH3O 6-Cl H H CH3 CH3 O H CH3O Table XXV EMI114.1 L R R1 R2 Y1 Q OCH3 H H H CH3O O SCH3 H H H CH3 0 S(O)CH3 H H H CH3O O S(O)CH2CH2CH2CH3 4-CH3CH2CH2 H H CH3 CH2 S(O)2C(CH3)2 5-(CH3)2CH H H CH3O CH2 Table XXVI EMI115.1 EMI115.2 <tb> L <SEP> R <SEP> R1 <SEP> R2 <SEP> R8 <tb> <SEP> L <SEP> - <SEP> P <tb> CO2CH3 <SEP> H <SEP> H <SEP> H <SEP> H <SEP> H <SEP> 0 <tb> C 2CH3 <SEP> H <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> 0 <tb> C 2CH3 <SEP> H <SEP> H <SEP> H <SEP> H <SEP> CH30 <SEP> 0 <tb> CO2CH3 <SEP> H <SEP> CR3 <SEP> H <SEP> H <SEP> CH3CH2O <SEP> 0 <tb> CO2CE3 <SEP> H <SEP> H <SEP> H <SEP> H <SEP> CE3 <SEP> S <tb> H <SEP> H <SEP> H <SEP> OCH2CE3 <SEP> H <SEP> 'MZCMC3 <tb> <SEP> 5-C1 <SEP> CH2 <SEP> CH3 <SEP> H <SEP> a <SEP> <SEP> 0 <tb> <SEP> H <SEP> CR3 <SEP> H <SEP> Cl <tb> E <SEP> E <SEP> CH3 <SEP> H <SEP> Cl <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> OCH3 <SEP> H <SEP> Cl <SEP> O <tb> <SEP> H <SEP> C1 <SEP> H <SEP> ' <SEP> CH3 <SEP> H <SEP> C1 <SEP> o <tb> <SEP> H <SEP> C1 <SEP> H <SEP> oa3 <SEP> K <SEP> C1 <SEP> 0 <tb> <SEP> H <SEP> H <SEP> K <SEP> E <SEP> OCH2CH3 <SEP> H <SEP> Cl <SEP> 0 <tb> <SEP> R <SEP> C1 <SEP> H <SEP> OCR2CE3 <SEP> H <SEP> C1 <SEP> 0, <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> H <SEP> Nu <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> H <SEP> N <SEP> cue3) <SEP> 3 <SEP> 0 <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> CH3 <SEP> z <SEP> NHCCH3 <SEP> C <tb> EMI116.1 EMI116.2 <tb> <SEP> L <SEP> R <SEP> P1 <SEP> ; ;2 <SEP> A <tb> <SEP> I <SEP> 2 <tb> <SEP> C}!1 <tb> <SEP> OCH3 <SEP> H <SEP> H <SEP> N <tb> <SEP> I <SEP> CH <tb> <SEP> N <SEP> sOCH <SEP> 3 <tb> <SEP> OCH <SEP> N <SEP> H <SEP> H <SEP> N <tb> <SEP> OCR3. <tb> <SEP> N <tb> <SEP> OCH3 <SEP> H <SEP> )f <SEP> H <tb> <SEP> .N3 <tb> <SEP> 2 <tb> <SEP> OCH3 <SEP> H <SEP> H <tb> <SEP> o <tb> <SEP> OCH3 <SEP> H <SEP> CR3 <SEP> N <SEP> R <tb> <SEP> 3 <tb> CCi), <SEP> H <SEP> CH3 <SEP> H <SEP> NCR3 <tb> <SEP> 3 <SEP> 0N <tb> <SEP> N <tb> Table XXVII (continued) EMI117.1 <tb> <SEP> L <SEP> R <SEP> R1 <SEP> R2 <SEP> A <tb> <SEP> 2 <tb> <SEP> h' <SEP> E3 <tb> <SEP> SCH3 <SEP> H <SEP> H <SEP> H <tb> <SEP> OCH3 <tb> <SEP> N3 <tb> <SEP> SCH3 <SEP> H <SEP> H <SEP> H <SEP> i0 <SEP> N <tb> <SEP> OCH3 <tb> <SEP> N4H3 <tb> <SEP> SCH3 <SEP> H <SEP> H <SEP> .H <tb> <SEP> SCH3 <SEP> H <SEP> H <SEP> 4 <SEP> H <SEP> Me2c.3 <tb> <SEP> CH2 <tb> <SEP> SCH3 <SEP> , <SEP> H <SEP> H <SEP> H <tb> <SEP> O <tb> <SEP> SCH3 <SEP> H <SEP> H <SEP> H <SEP> iNoH <SEP> 3 <tb> <SEP> OCH <SEP> 3 <tb> <SEP> 0 <SEP> Il <tb> <SEP> 0S11CH3 <SEP> H <SEP> H <SEP> H <SEP> I'goy t <tb> <SEP> 11 <tb> S(O)2CR3 <SEP> H <SEP> CH3 <SEP> CH3 <SEP> < QN <tb> <SEP> N <SEP> KOCr: : <tb> Table XXVIII EMI118.1 EMI118.2 <tb> <SEP> R2 <tb> R <SEP> R1 <SEP> R2 <tb> <SEP> L <tb> H <SEP> H <SEP> H <SEP> .OH <tb> H <SEP> H <SEP> CH3 <SEP> OH <tb> H <SEP> CH3 <SEP> CH3 <SEP> OH <tb> 5-e <SEP> CH3CH2 <SEP> H <SEP> OH <tb> 6-F <SEP> Ca3CE2CE2 <SEP> H <SEP> OH <tb> 3-Br <SEP> {Ca3 <SEP> ) <SEP> 2 <SEP> S <SEP> E <SEP> OH <tb> 5-NO2 <SEP> X <SEP> CZ3CH2CE2CS2 <SEP> g <SEP> OH <tb> 5 <SEP> cm3 <SEP> CE3CE2CHCS3 <SEP> H <SEP> OH <tb> H <SEP> H <SEP> OH <tb> 5- > 3Cz2C <SEP> H <SEP> s <SEP> OH <tb> 5-CE30 <SEP> H <SEP> H <SEP> OH <tb> SIICHCHOI <SEP> H <SEP> H <SEP> OH <tb> 5-CE3ChCE20- <SEP> H <SEP> H <SEP> ' <SEP> OH <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> OCH <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> OCCEa. <tb> Table XXVIII (continued) EMI119.1 <tb> R <SEP> R1 <SEP> R2 <tb> <SEP> f <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-CCH2CH3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-C-(CH2)4CH3 <tb> <SEP> o <tb> B <SEP> H <SEP> H <SEP> O-C-CH=CH2 <tb> <SEP> 0 <tb> E <SEP> E <SEP> R <SEP> O-C <tb> H <SEP> H <SEP> H <tb> <SEP> CH3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> 0-C <SEP> Q,H3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-C-OCH2CE3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> 0-C-OCH2CH2CH3 <tb> <SEP> 0 <tb> H <SEP> S <SEP> H <SEP> OC0(CH2)ACH3 <tb> Table XXIX EMI120.1 EMI120.2 <tb> <SEP> R <SEP> 1 <SEP> 2 <SEP> L <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> O-C-CH2CH=CH2 <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> O-C-C=C-H <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> O-C-CH2-C--C-H <tb> <SEP> O <tb> <SEP> E <SEP> z <SEP> R <SEP> O-Cg <tb> <SEP> 0 <tb> <SEP> E <SEP> H <SEP> H <SEP> O-Cm <tb> <SEP> 0 <SEP> ff0 <tb> <SEP> H <SEP> ' <SEP> H <SEP> H <tb> <SEP> H <SEP> H <SEP> H <SEP> O-C <SEP> -C1 <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> O-C-CH2C1 <tb> <SEP> 0 <tb> <SEP> H <SEP> H <SEP> H <SEP> 0-C' <SEP> -CF3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> R <SEP> O-C-C=C <SEP> (cm)2 <tb> <SEP> C1 <tb> <SEP> 0 <tb> <SEP> U <tb> <SEP> H <SEP> F <SEP> H <SEP> O-C-NHCH3 <tb> Table XXIX (continued) EMI121.1 <tb> R <SEP> R1 <SEP> P2 <SEP> L <tb> <SEP> L <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-C-NH(CE3)2 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-C-NH-CE(CH3)CH2CH3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> OC-NH-C <SEP> (CE3 <tb> <SEP> o <tb> H <SEP> H <SEP> H <SEP> O-C-NH- <SEP> (CH2) <SEP> 4CH3 <tb> <SEP> 0 <tb> <SEP> S <tb> H <SEP> H <SEP> E <SEP> O-C-NH-C1H <SEP> (CH2)3CH3 <tb> <SEP> CE3 <tb> <SEP> 0 <tb> H <SEP> - <SEP> H <SEP> H <SEP> O-C-NHCH2X=CH2 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> O-C-NH-CE-CH=CE2 <tb> <SEP> CH3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> I <SEP> O-C-NH <tb> H <SEP> H <SEP> H <tb> <SEP> 0 <tb> B <SEP> H <SEP> H <SEP> O-C-NN <tb> H <SEP> H <SEP> H <tb> <SEP> 0 <tb> <SEP> S <tb> H <SEP> H <SEP> H <SEP> O-C-OCR2(CH2)2CR3 <tb> <SEP> 0 <tb> H <SEP> H <SEP> H <SEP> -C: <SEP> (CE2) <SEP> sCE3 <tb> <SEP> 0 <tb> H <SEP> B <SEP> H <SEP> O-C-O <SEP> H <SEP> H <SEP> H <tb> Table XXX EMI122.1 R R1 R2 R3 R4 Z H H H CH3O CH3 CH H H H C2H5 CH3 CH H H H CH3 CH3 N H H H CH3O CH3 N H H H C2H5 CH3 N 3-Cl H H CH3 CH3 N 4-Cl H H CH3 CH3 N 5-Cl H H CH3 CH3 N 6-Cl H H CH3 CH3 N Table XXXI EMI123.1 EMI123.2 <tb> <SEP> P <SEP> R <SEP> R1 <SEP> h <SEP> z <tb> <SEP> C 2CH3 <SEP> H <SEP> H <SEP> H <SEP> N <tb> <SEP> 2CH3 <SEP> H <SEP> H <SEP> H <SEP> CH <tb> <SEP> : :2C2ES <SEP> H <SEP> CS3 <SEP> R <SEP> N <tb> <SEP> OCH3 <SEP> )1 <SEP> CM <tb> <SEP> 5O2CR3 <SEP> H <SEP> H <SEP> B <SEP> COR <tb> <SEP> OCH3 <SEP> H <SEP> H <SEP> H <SEP> N <tb> <SEP> SCH3 <SEP> H <SEP> s <SEP> H <SEP> N <tb> 3(O)2CH3 <SEP> H <SEP> H <SEP> E <SEP> N <tb> <SEP> SCH2CH2CEzcE3 <SEP> 4-CR3CR2CR2 <SEP> H <SEP> H <SEP> CR <tb> <SEP> SOCH3 <SEP> H <SEP> H <SEP> H <tb> <SEP> SCH3 <SEP> H <SEP> CR3CR2 <SEP> H <SEP> CR <tb> <SEP> C1 <SEP> H <SEP> H <SEP> H <SEP> CR <tb> <SEP> Cl <SEP> H <SEP> H <SEP> C1 <SEP> CR <tb> <SEP> Cl <SEP> 5-OCR3 <SEP> H <SEP> H <SEP> N <tb> <SEP> C1 <SEP> 6-CR3 <SEP> H <SEP> H <SEP> CR <tb> <SEP> N <SEP> O <SEP> H <SEP> H <SEP> H <SEP> CR <tb> Table XXXII EMI124.1 R R1 R2 R3 R4 H H H CH3 CH3 H H H C2H5 CH3 Table XXXIII EMI125.1 R R1 R2 R10 H H H CH3 H H H CH3CH2 H H H (CH@)@CH H H H CH3CH2CH2CH2 H H H CH2-CH-CH2 H CH3 H CH3 3-Cl H H CH3 4-NO2 H H CH3 4-CF3 H H CH3 3-CH3 H H CH3 4-CH3O H H CH3 5-F H E CH3CH2 5-Br H H CH3CH2 Table XXXIV EMI126.1 L R1 R2 R Cl H H H Cl Cl H H Br H H H Br Cl H H Cl H CH3 H Cl H H 5-NO2 Cl H H 6-Cl OCH3 H H CH3 OCH3 H CH3 CH3 SCH3 H H H SCH3 H H CH3 SCH3 H CH3 CH3 OCH2CF3 5-Cl H H Formulat ions Useful formulations.of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.18 to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid diluent(s). More specifically, they will contain these ingredients in the following approximate proportions: : Table XXXV Weight Percent * Active Ingredient Diluent (s) Surfactant(s) Wettable Powders 20-90 0-7 1-10 Oil Suspensions, 3-50 40-95 0-15 Emulsions, Solutions, (including Emulsifiable Concentrates) Aqueous Suspension 10-50 40-84 1-20 Dusts 1-25 70-99 0-5 Granules and Pellets 0.1-95 5-99.9 0-15 High Strength 90-99 0-10 0-2 Compositions * Active ingredient plus at least one of a Surfactant or a Diluent equals 100 weight percent. Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are some times ,desirable, and are achieved by incorporation into the formulation or by tank mixing. Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and CarrierS', 2nd Ed., Dorland Books, Caldwell, New Jersey, but other solids, either mined or manufac tured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are de scribed in Marsden, "Solvents Guide," 2nd Ed., Inter science, New York, 1950. 'Solubility under 0.1% is preferred for suspension concentrates; solution con centrates are preferably stable against phase separa tion at OOC, wMcCutcheon's Detergents and Emulsifiers Annua, MC Publishing Corp., Ridgewood, New Jersey, as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing no., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of addi tives to reduce foaming, caking, corrosion, microbio logical growth, etc. The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Patent 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning "agglomeration", Chemical Enoineering, December 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook', 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff. For further information regarding the art of formulation, see for example: H. M. Loux, U.S. Patent 3,235,361, February 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41; R. W. Luckenbaugh, U.S. Patent 3,309,192, March 14, 1967, Col. S, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 16)-164, 166, 167 and 169-182; H. Gysin and E. Knusli, U.S. Patent 2,891,855, June 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4; G. C. Klingman, "Weed Control as a Science", John Wiley & Sons, Inc. New York, 1961, pp. 81-96; and 3. D. Fryer and 5. A. Evans, "Weed Control Hand book", 5th Ed., Blackwell Scientific, Publications, Oxford, 1968, pp. 101-103. In the following examples, all parts are by weight unless otherwise indicated Example 51 Wettable Powder 2-1 [ (4,6-dimethowpyrimidin-2-yl) aminocarbonyl] amino- sulfonyl]benzeneacetic acid, methyl ester 80% sodium alkylnaphthalenesulfonate 2% sodium ligninsulfonate 2% synthetic amorphous silica 3% kaolinite 13% The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged. Exemple 52 Wettable Powder 2- t 1(4, 6-dimeFhylpyrimidin-2-yl) aminocarbonyl] amino sulfonyl]benzeneacetic acid, methyl ester 50% sodium alkylnaphthalenesulfonate . 2% low viscosity methyl cellulose 2% diatomaceous earth 46% The ingredients are blended, coarsely hammermilled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging. Example 53 Extruded Pellet 2-[[(4-methoxy-6-methylpyrimidin-2-yl)-aminocarbonyl] aminosulfonyllbenzeneacetic acid, methyl ester 25% anhydrous sodium sulfate 10% crude calcium ligninsulfonate 5% sodium alkylnaphthalenesulfonate 1% calcium/magnesium bentonite -59% The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled. Example 54 Wettable Powder 2-[[(4-methoxy-6-methyl-1,3,5-triazin-2-6l)aminocar bonyl)aminosulfonyl]benzeneacetic acid, methyl ester 208 sodium alkylnaphthalenesulfonate 4% sodium ligninsulfonate 4% low viscosity methyl cellulose 3% attapulgite 69% The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.9.S. No. 50 sieve (0.3 mm opening) and packaged. Example 55 Low Strength Granule 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]amino sulfonyl]benzeneacetic acid, ethyl ester 1% ,N,N-dimethylformamide 9% attapulgite granules 90% (U.S.S. 20-40 sieve) The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying' of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged. Example 56 Solution 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]amino sulfonyl]benzeneacetic acid, methyl ester, sodium salt 5% water ' 95% The salt is added directly to the pater with stirring to produce the solution, which may then be packaged for use. Example 57 Wettable Powder 2-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar bonyl] aminosulfonyl] benzeneacetic acid, methyl ester 90% dioctyl sodium sulfosuccinate 0,18 synthetic fine silica 9.9% The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged. Example 58 Wettable Powder 2-1 1 (4, 6-dimethowypyrinidin-2-yl) aminocarbonyl] amino- sulfonyllbenzeneacetic acid, ethyl ester 40% sodium ligninsulfonate 20% montmorillonite clay 40% The ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged. 2-[((4,6-dimethoxypyrimidin-2-yl)aminocarbonyl] aminosulfonyl)benzeneacetic acid, ethyl ester; 2-[((4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] aminosulfonyl]benzeneacetic acid, ethyl ester; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2methoxymethyl)benzenesulfonamide; N-[((4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]2-(methoxymethyl)benzenesulfonamide; N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)eminocarbonyl]-2-(methoxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide; N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-2 (methylthiomethyl)benzenesulfonamide; ; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]2-(methylthiomethyl)benzenesulfonamide; 2-(Dichloromethyl)-N-[(4-methoxy-6-methyl-1,3,5triazin-2-yl)aminocarbonyl]benzenesulfonamide; 2-(ChlOromethyl )-N-± ít, 6-d-4methoxy-1,3, 5-tria2in¯2¯ yl)aminocarbonyl]benzenesulfonamide; 2-(Chloromethyl)-N-[(4,6-dimethoxypyrimidin-2-yl) aminocarbonyl]benzenesulfonamide; 2-(Chloromethyl)-N-[(4,6-dimethylpyrimidin-2-yl) aminocarbonyl]benzenesulfonamide; 2-(1-Chloroethyl)-N-[(4,6-dimethyoxy-1,3,5-triazin 2-yl)aminocarbonyl]benzenesulfonamide; 2-(1-Pyrrolidinylmethyl)-N-[(4,6-dimethoxypyrimidin-2 yl)aminocarbonyl]benzenesulfonamide, hydrochloride; 2-(1-Pyrrolidinylmethyl)-N-[(4,6-dimethoxypyrimidin-2 yl)aminocarbonyl]benzenesulfonamide; 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl] aminosulfonyl] ben:eneacetic acid, methyl ester; 2-[[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl] aminosulfonyl)benzeneacetic acid, methyl ester; 2-I1(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]- aminosulfonyl]benzeneacetic acid, methyl ester; 2-[[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl] aminosulfonyl)benzeneacetic acid, methyl ester; 2-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino carbonyl]aminosulfonyl]benzeneacetic acid, methyl ester; 2. A compound of claim 1 wherein Z is N, CH, CC1, CBr or CCH3; W is 0; and R8 is H or CH3. 3. A compound of claim 1 wherein L is OH; R is H; ; R1 and R2 are both CH3 P5 is H or CH3 A is EMI135.1 Z is CH or N; X and Y are independently CH3 or OCH3; and W is 0. 4. A compound of claim 2 wherein L is C1, Brr NR3R4, +NR3R4R4', CO2R10, S(O)nR7, OR9, SO2NR3R4, OC(O)R11, OC(O)NHR12, OC(O)OR13; Z is CH Or N; X is CH3 or OCH3; R, R1, R2 are H; and when n is 1 or 2, Z is CR. 5. A compound of claim 4 wherein A is EMI135.2 R8 is H; L is Cl, Br, NR3R4, CO2R10, S(O)nR7, OR9, SO2NR3R4, OH,OC(O)R11, OC(O)NHR12, OC(O)OR13; and R11, R12 and R13 are C1-C3 alkyl 6. A compound of claim 5 wherein L is Cl, Br, NR3R4, CO2R10, S(O)nR7,OR9, SO2NR3R4 or OH. 7. A compound of claim 6 wherein R3 is C1-C3 alkyl or OCH3; R4 is CH3; R9 is C1-C alkyl; and P10 is CH3 or CH2CH3; 8. A compound of claim 7 wherein R7 and R9 are CH3. 9. A compound of claim 8 wherein L is CO2R10, S(O)nR7 or OR9. 10. A compound of claim 1 selected from: 2-(Dichloromethyl)-N-[(4-methoxy-6-methylpyrimi@in-2- yl)aminocarbonyl]benzenesulfonamide; 2-(Dichloromethyl)-N-[(4,6-Dimethylpyrimi@in-2-yl)- aminocarbonyl]benzenesulfonamide; is H, CH3 or Cl; n it O, 1 or 2: A is EMI136.1 W is O or S; X is H, Cl, Br, CE3, CH2CH3, C1-C3 alkoxy, CF3, SCH3 or CH2OCH3; Y is CH3 or OCH3; z is N, CH, CC1, CBr, CCN, CCH3, CCH2CH3, CCH2CH2Cl or CCH2CH=CH2; Y1 is H, CH3, OCH3 or OCH2CH3; and 9 is O or CH2; and their agriculturally suitable salts provided that: (1) when R1 is C1, then L is Cl or or and Rz is H; (2) when n is 1, then W is O; (3) when L is CONR3R4, then Z is CH or 'N; (4J when R3 is OCH3, then R4 is CH3; (5) the total number of carbon atoms of R3 and R4 is five or less; (6) when W is S, then R8 is H; and (7) when L is SO2NR3R4, then R3 and R4 are not H. #4' is H, CH3 or CH2CH3; #5 is C1-C4 alkyl optionally substituted with 1-3 atoms of F, Cl or Br, or C3-C4 alkenyl; R6 is H, C1-C4 alkyl or C3-C4 alkenyl; R7 is C1-C4 alkyl; R8 is H, CH3 or OCH3; R9 is C1-C6 alkyl, C3-C4 alkenyl, CH2CF3, CF2CF2H or C5-C6 cycloalkyl; R10 is H, C1-C4 alkyl, C3-C4 alkenyl, CH2CH2C1 or CH2CH2OCH3; R11 is H, C1-C5 alkyl, C2-C3 alkenyl, C2-C3 alkynyl, C3-C4 cycloalkyl, EMI137.1 C1-C4 alkyl substituted with 1-4 substituents selected from 0-3 F, 0-3 C1 or 0-3 Br, or C2-C3 alkenyl substituted with 1-3 Cl; R12 is H. C1-C6 alkyl, C3-C4 alkenyl, C5-C6 cycloalkyl EMI137.2 C5-C6 cycloalkyl substituted with CH3; R13 is C1-C6 alkyl or EMI137.3 R14 and R15 are independently H. NO2, CH2, Cl or OCH3; R16 is H, F. Cl. Br, C1-C3 alkyl. NO2, SO2CH OCH3, @ SCH3 or CF3; R17 is H, Cl or C1-C3 alkyl; Claims: 1. A compound selected from: EMI138.1 wherein is CO2R10, CONR3R4; CN, Cl, Br, NR3R4, NR3R4R4', N(R4)C(O)R5, N(R4)C(O)NHR6, N(R4)C(O)OR7, S'(O) nR7, ORg, S02NR3R4, OH,OC(O)R11, OC(O)NHR12 or OC(O)OR13; R is H, F, C1, Br, NO2, CF3, C1-C3 alkyl or C1-C3 alkoxy; R1 is H, Cl or C1-C4 alkyl; R2 is H or CH3 R3 is H, C1-C4 alkyl or OCH3; R4 is H or C1-C4 alkyl; R3 and R4 can be-taken together to form - (CH2)4-, -(CH2)5- or -(CH2CH2)2O; TEST G NUTSEDGE EMI139.1 EMI139.2 <tb> <SEP> Reponse <SEP> Rating <SEP> (after <SEP> 4 <SEP> weeks) <tb> <SEP> Rate <SEP> Preemerg. <SEP> Tuber <SEP> Soil <tb> <SEP> kg/ha <SEP> Soil <SEP> Surface <SEP> Spray <SEP> Incor@ <SEP> @@@@@@@@@@ <tb> 0.01 <SEP> 3G <SEP> 6G <SEP> 7G <SEP> 0 <tb> 0.03 <SEP> 7G <SEP> 7G <SEP> 8G <SEP> 0 <tb> 0.125 <SEP> 9G <SEP> 9G <SEP> 9G <SEP> 4C.7G <tb> Test G Purple nutsedge (Cyoerus rotundus) tubers were planted about 2 cm deep in Fallsington silt loam soil contained in 10 cm diameter plastic pots. Five tubers were planted in each pot. Compounds of this invention were dissolved in a non-phytotoxic diluent and sprayed at 569 1/ha in four methods of appiication: soil surface, tuber/soil, soil incorporated and post-emergence. The soil surface spray consisted of spraying the compound on the surface of the firmed covering soil. The tuber/soil spray consisted of spraying the compound on exposed tubers and subtending soil before adding the untreated covering soil. Soil incorporated treatment consisted in niixing the compound with the covering soil before using it to cover the tubers. The post-emergence treatment was sprayed on nutsedge foliage and the surrounding soil surface when nutsedge had emerged and- grown to a height of about 12 cm. Pots receiving the poft-emergence treatments were placed directly in the greenhouse. Pots receiving the other treatments were misted with about 0.3 cm water before being transferred to the greenhouse. Response ratings assessed after four weeks are recorded in Table G based on the same rating system as described in procedure A. Test F A test sample of compound 8 was formulated and applied directly to the water of simulated paddies, three days after transplanting of rice. The paddies were maintained in a greenhouse, and plant'response ratings were taken one week and four weeks after application. Water Rate, Rice Barnyardgass* Chestnut* Arrowhead* kg ai/ha 1 wk. 4 wks. 4 weeks -4 weeks 4 weeks 0.125 0 0 0 8G 0 0.5 0 0 0 lOC 6G * Echinochloa sp., Eleocharis sp., and Sagittaria sp., respectively. Reference to the table above indicates that rice tolerated the application of the test sample at 500 g ai/ha, whereas the important weed tin rice culture in some areas) water chestnut was completely controlled. Arrowhead, which also is an important weed in some rice culture areas, was partially controlled at the same application raze. TEST E Test samples were formulated and applied directly to the water of paddies three days after transplanting of Japonica rice. The paddies were maintained in a greenhouse, and plant response ratings were taken one and three weeks after application. EMI142.1 Barnyard-# Water# Rice Rice grass Chestnut Scirpu;* Treatment 1 Week 3 Weeks 3 Weeks 3 Weeks 3 Weeks S g/ha 0 0 5G 8G 0 20 g/ha 0 5G 8G 9G SG *Echinochloa sp., Eleocharis sp., and Scirpus sp., respectively. TABLE D (continued) EMI143.1 <tb> <SEP> (CHCl2 <tb> <SEP> SO2NHCCNH0 <SEP> N <tb> <SEP> 3 <tb> <SEP> 1 <tb> <SEP> Post-emergence <SEP> Pre-emergence <tb> Rate <SEP> ko/h <SEP> 0.5 <tb> <SEP> O.S <tb> <SEP> wheat <SEP> 0 <tb> <SEP> barl <SEP> tN <SEP> O <SEP> 1G <tb> <SEP> wild <SEP> oats <SEP> 0 <tb> <SEP> downy <SEP> bror..e <SEP> 1G <tb> <SEP> cheatzrass <SEP> 2G <SEP> , <SEP> 3C,4G <tb> <SEP> blackQrass <SEP> I <SEP> 2C <SEP> 6G <tb> <SEP> annual <SEP> bluegrass <SEP> 6C <SEP> . <SEP> SG <SEP> 5C, <SEP> 7G <tb> <SEP> green <SEP> foxtail <SEP> lOC <SEP> 4C <SEP> , <SEP> 7G <tb> <SEP> quackçrass <SEP> 2G <SEP> 7C <SEP> 7G <tb> <SEP> Italian <SEP> rye <SEP> rasps <SEP> 4C <SEP> 6G <SEP> 5G <tb> <SEP> rlpRut <SEP> brome <SEP> O <SEP> 2G <tb> <SEP> Russian <SEP> thistle <SEP> lOC <SEP> 1 <SEP> 5C,5G <tb> <SEP> tans <SEP> mustard <SEP> lOC <SEP> I <SEP> 9C,9G <tb> <SEP> s:artveed <tb> <SEP> timhill <SEP> mustard <SEP> I <SEP> lOC <SEP> 9C,9G <tb> <SEP> Kochia <SEP> ! <SEP> 1 <SEP> ic <SEP> I <SEP> 6G <tb> <SEP> shePherd <SEP> urse <SEP> 1 <SEP> 9C <SEP> 9G <tb> <SEP> false <SEP> ebar.o:: :ile <SEP> lec <SEP> sc, <SEP> 9G <tb> <SEP> black <SEP> nightshade <SEP> ¯ <SEP> 4C, <SEP> 6G <tb> <SEP> sallow <SEP> rocket <SEP> 1 <SEP> 9C <SEP> sc, <SEP> 9G <tb> <SEP> wild <SEP> mustard <SEP> loc <SEP> 9C <SEP> 9G <tb> <SEP> vild <SEP> buckwheat <SEP> 1 <SEP> SC <SEP> 6G <tb> TABLE D (continued) EMI144.1 <tb> <SEP> N3 <tb> <SEP> N <tb> <SEP> (X <SEP> 502NHCONHgO <SEP> N <tb> <SEP> CH3 <tb> <SEP> 1 <tb> <SEP> Post-emergence <SEP> Pre-cmegence <tb> <SEP> Rite <SEP> k <SEP> ha <SEP> 0.125 <SEP> 125 <tb> <SEP> wheat <SEP> 0 <tb> <SEP> I- <SEP> e,5- <SEP> =' <SEP> 0 <tb> <SEP> wild <SEP> oats <SEP> 0 <tb> F <SEP> dornv <SEP> breve <tb> <SEP> ceatprass <SEP> j <SEP> 0 <tb> <SEP> backErass <SEP> i <SEP> 4r,A <tb> <SEP> annual <SEP> bluc <SEP> I <tb> <SEP> e¯nrasr <SEP> 2G <SEP> 6G <tb> <SEP> Eteen <SEP> foxtail <SEP> 1 <SEP> 4C,4G <SEP> Zr.c;c: : <tb> <SEP> quacksrass <SEP> 0 <tb> <SEP> Italian <SEP> rve±rass <SEP> 2C,4G <tb> <SEP> ripgut <SEP> brone <SEP> 0 <tb> <SEP> Russian <SEP> thistle <SEP> lOC <tb> <SEP> tans" <SEP> mustard <SEP> lOC <tb> <SEP> smartweed <tb> <SEP> distill <SEP> mustard <SEP> lOC <tb> <SEP> Kochia <SEP> 1 <SEP> or <SEP> lOC <tb> <SEP> sherherdts <SEP> purse <SEP> E <SEP> lOC <tb> <SEP> false <SEP> chamor;ile <SEP> lOC <tb> <SEP> black <SEP> nightshade <SEP> <tb> <SEP> sellow <SEP> rocket <SEP> 1 <tb> <SEP> wild <SEP> mustard <SEP> lOC <tb> <SEP> wild <SEP> buckwheat <SEP> lOC <tb> TABLE D (continued) EMI145.1 <tb> <SEP> CRal <SEP> 2 <tb> <SEP> 2 <SEP> < <tb> <SEP> CR3 <tb> <SEP> i <SEP> Post-emergence <SEP> Prptoere <tb> <SEP> Ftrte <SEP> Ir/h <SEP> i <SEP> ¯ <SEP> 0.06 <SEP> 0.06 <tb> / <SEP> tL'neBt <SEP> r) <SEP> 0 <SEP> 1 <tb> ; <SEP> barlg-.- <SEP> I <SEP> r) <SEP> ¯0 <tb> <SEP> uir <SEP> oets <SEP> 0 <SEP> G <tb> <SEP> b2rl <SEP> v <SEP> .- <SEP> n <SEP> n <SEP> ¯¯ <tb> <SEP> Yi <SEP> 1 <SEP> o <SEP> é <SEP> S <SEP> o <SEP> F <SEP> ¯. <SEP> . <SEP> .. <SEP> 1 <SEP> G <tb> <SEP> do-".' <SEP> brore <SEP> 1 <SEP> r <SEP> n <tb> <SEP> chest <SEP> rass <SEP> . <SEP> n <tb> <SEP> blacktra <SEP> ss <SEP> 7C. <SEP> 3G <SEP> 3G <tb> <SEP> annual <SEP> bluegrass <SEP> nr, <SEP> G <SEP> 3C <SEP> 7C <tb> <SEP> green <SEP> foxtail <SEP> 1 <SEP> nr <SEP> 3G <tb> <SEP> quackgrass <SEP> rass <tb> <SEP> Italian <SEP> e <SEP> rass <SEP> 2G¯ <tb> <SEP> ri <SEP> ut <SEP> broke <SEP> 0 <tb> <SEP> Russian <SEP> thistle <SEP> 3 <SEP> nc <SEP> . <SEP> .. <SEP> 3c <SEP> . <SEP> 3G <tb> <SEP> tans <SEP> mustard <tb> <SEP> smartweed <SEP> 1 <SEP> no <tb> <SEP> &verbar;l <SEP> - <tb> <SEP> t*mhill <SEP> mustard <SEP> 1 <SEP> OC <SEP> iC <SEP> 9G <tb> <SEP> Kochia <SEP> ¯ <SEP> ¯ <SEP> wn <SEP> 7r. <SEP> RC <tb> <SEP> shePherd <SEP> ' <SEP> s <SEP> purse <SEP> 1 <SEP> nr <SEP> 1 <SEP> nr <tb> <SEP> false <SEP> chawo-ile <SEP> 1 <SEP> nr <SEP> . <SEP> 7r, <SEP> Rr <tb> <SEP> black <SEP> nirhtshate <SEP> ¯ <tb> <SEP> Yellov <SEP> rocket <SEP> nr <SEP> 1 <SEP> ne <tb> <SEP> slt <SEP> 1nustard <SEP> 1 <SEP> ny <SEP> . <SEP> qr, <SEP> R <SEP> ¯ <tb> <SEP> wild <SEP> buckwhcat <SEP> Rf-, <SEP> 7C. <SEP> vr <SEP> m°: <tb> TABLE D (continued) EMI146.1 <tb> <SEP> (SCFC12 <tb> <SEP> SO2NCO(C0 <SEP> N <tb> Post-emergence <SEP> Pre-eergence <tb> <SEP> Post-e2s <SEP> erènce <SEP> Pre-emergence <tb> <SEP> Rate <SEP> )t':'/?:a <SEP> o <SEP> O <SEP> 1; <tb> <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <tb> <SEP> wheat <tb> <SEP> 0 <tb> <SEP> wild <SEP> oats <SEP> n <tb> <SEP> dorm <SEP> bror <SEP> a <SEP> n <SEP> n <tb> <SEP> cfieatgrass <SEP> 6 <SEP> 0 <tb> <SEP> blacketass <SEP> ¯ <SEP> 3r <SEP> 2G <tb> <SEP> annual <SEP> bluce <SEP> 1G <tb> <SEP> gteen <SEP> fo¯xtaf <SEP> 9 <tb> <SEP> quackrass <SEP> ,,,9 <tb> <SEP> green <SEP> f <SEP> oxt <SEP> a <SEP> il <SEP> . <SEP> n <SEP> O <tb> <SEP> ¯quack$rass <SEP> n <SEP> O <tb> <SEP> Italian <SEP> r <SEP> C <SEP> rass <SEP> 0 <tb> <SEP> ripeut <SEP> broke <SEP> n <tb> <SEP> Russian <SEP> thistle <SEP> tnr <SEP> 0 <tb> <SEP> tansy <SEP> mustard <SEP> S <SEP> 7C, <SEP> 8G <tb> <SEP> smartweed <SEP> or <tb> <SEP> ihill <SEP> ustard <tb> <SEP> Kochia <SEP> ¯ <SEP> 7e <SEP> SC, <SEP> SG <tb> <SEP> shepherd <SEP> s <SEP> vurse <SEP> . <SEP> 1 <SEP> nr <SEP> z <tb> <SEP> false <SEP> ehamom.ile <SEP> ¯ <SEP> lne <SEP> . <SEP> 5C,EG <tb> <SEP> blactc <SEP> nithtshade <SEP> ¯ <tb> <SEP> vellow <SEP> roeket <SEP> . <SEP> . <SEP> 1°^ <SEP> I <SEP> OC <tb> <SEP> wild <SEP> mustard <SEP> ¯ <SEP> . <SEP> lno <SEP> 7C. <SEP> 7tG <tb> <SEP> wild <SEP> bucRuheat <SEP> ¯ <SEP> 6C <SEP> . <SEP> SG <SEP> 7 <SEP> C <SEP> ,1 <SEP> G <tb> Table D (continued) EMI147.1 <tb> <SEP> f"l'(OICX3 <SEP> 1 <tb> <SEP> solwntorrt <SEP> ( <tb> <SEP> 3 <tb> <SEP> 1 <tb> <SEP> Post-emergence <SEP> Pre-emergence <tb> <SEP> Rrt <SEP> kg,/hr <SEP> 0,06 <SEP> 0.0 <tb> 1 <SEP> heat <SEP> 6C,5G <SEP> 0 <tb> i <SEP> tLlg= <SEP> 8C,7G <SEP> 3C,7C <tb> <SEP> ui!C <SEP> ca¯=.e <SEP> 1-oc <SEP> ¯ <SEP> ¯6C,6¯G <tb> <SEP> do--\- <SEP> brort <tb> <SEP> 10C <SEP> 10C <tb> <SEP> fheatnrass <SEP> 1 <SEP> 10C' <SEP> 1 <SEP> OC <tb> <SEP> blakptacs <SEP> 1 <SEP> OC <tb> <SEP> 10C <tb> <SEP> annual <SEP> bluEtrasc- <SEP> 10C <SEP> 10C <tb> <SEP> gteeii <SEP> fcxtai: <SEP> 10C <SEP> 10r <tb> <SEP> qu-atkerass <SEP> 10C <tb> <SEP> Ita:fafi <SEP> spcerass <SEP> 1111 <tb> <SEP> .10t <SEP> i <SEP> 6C <SEP> ,7G <tb> <SEP> TiPEut <SEP> broc <SEP> I <SEP> 10C <SEP> i <SEP> 3C <SEP> r <tb> <SEP> Russian <SEP> thistle <SEP> 1 <tb> <SEP> 8C,7G <SEP> 6C <SEP> r <tb> <SEP> tansv <SEP> mustatd <SEP> 18C <tb> <SEP> I <SEP> loc <SEP> 1 <tb> <SEP> sartueed <SEP> , <SEP> ] <SEP> , <SEP> 1 <tb> <SEP> swartweed <SEP> ¯ <tb> <SEP> i:hill <SEP> mustard <SEP> loc <SEP> loc <tb> <SEP> Kochia <SEP> 4C <SEP> . <SEP> 5G <SEP> 3C, <SEP> 7G <tb> <SEP> herd'surse <SEP> lOC <SEP> ¯ <SEP> ,, <SEP> 9C <SEP> 9G <tb> <SEP> false <SEP> ehamom.ile <SEP> l <SEP> 7C <SEP> 5G <tb> <SEP> black <SEP> ni <SEP> htshade <SEP> 3C <SEP> . <SEP> SG <tb> <SEP> vell <SEP> rocket <SEP> . <SEP> 1 <SEP> 9C <SEP> , <SEP> 5G <tb> <SEP> wild <SEP> mustard <SEP> 1 <SEP> 9C <SEP> ¯ <SEP> 9C, <SEP> 9G <tb> <SEP> vild <SEP> buckwheat <SEP> 9C, <SEP> 8G <SEP> 4C <SEP> SG <tb> Table D (continued) EMI148.1 <tb> <SEP> C2SloaCN3 <tb> <SEP> So2t <SEP> 0e <tb> <SEP> 3 <tb> <SEP> Pos <SEP> t-emergeice <SEP> Prc-uPergence <tb> Ante <SEP> kqXha <SEP> O <SEP> 0.015 <SEP> O <SEP> . <SEP> 0.015 <tb> <SEP> ':heat <SEP> lC.lG <SEP> O <tb> <SEP> cheat <SEP> 3G <tb> wild <SEP> oats <SEP> 6C,4G <SEP> 2C,2G <tb> <SEP> do-r.' <SEP> broke <SEP> lOC <SEP> i <SEP> 3C <SEP> 7G <tb> <SEP> cheat <SEP> rasps <SEP> 8C, <SEP> 6G <SEP> 7C18G <tb> <SEP> 7C,8G¯ <tb> <SEP> blackgrars <SEP> 10C <SEP> - <SEP> 7C,7t <tb> <SEP> annua <SEP> bluerass <SEP> 3C,5G-ec <tb> <SEP> pree <SEP> foxtai <SEP> BC,7G <SEP> 3C¯, <SEP> 7G <tb> <SEP> qUaCkBTaSS <SEP> i <SEP> 8C,7G <SEP> ¯I <SEP> 5G <tb> <SEP> &verbar; <SEP> - <SEP> P <tb> <SEP> Italian <SEP> r,yegrass <SEP> 2C. <SEP> 3e <SEP> ¯ <SEP> 3G <SEP> rass <tb> <SEP> ripeut <SEP> braze <SEP> I <SEP> 3C <SEP> g <SEP> 4G <SEP> 2G <tb> <SEP> Russian <SEP> thistle <SEP> 7C,6G <SEP> 5C, <SEP> 4G <tb> <SEP> tans <SEP> mustard <SEP> -i <SEP> lOC <SEP> 9C,9G <tb> <SEP> smartweed <tb> <SEP> jimhil <SEP> mustard <SEP> 10C <SEP> 8C.8G <SEP> <tb> <SEP> [ocba <SEP> o <tb> 'sheoherd's <SEP> pursel <tb> <SEP> false <SEP> chamomile <SEP> 7 <SEP> 1 <tb> <SEP> bfack <SEP> nfRhtshadel <SEP> : <SEP> ,5G <tb> <SEP> black <SEP> ni <SEP> btshade <SEP> O <SEP> 2C <SEP> SG <tb> <SEP> ell <SEP> lox <SEP> rocket <SEP> l <SEP> OC <SEP> lOC <SEP> ¯ <SEP> 4C, <SEP> 4C,8G <tb> <SEP> vild <SEP> mustard <SEP> 10C <SEP> lOC <SEP> 7C,7G <tb> <SEP> wild <SEP> buckwheat <SEP> 7C <SEP> 6G <SEP> 3C <SEP> 4G <tb> <SEP> S <tb> Table D (continued) EMI149.1 <tb> <SEP> 3 <tb> <SEP> N <SEP> 3 <tb> <SEP> Post-eergence <SEP> Pre-emergence <tb> <SEP> / <SEP> Post-emergence <SEP> Pre-emergence <tb> RJ <SEP> J <SEP> e <SEP> ko <SEP> 0.06 <SEP> 0.06 <tb> <SEP> o <SEP> 1C,1G <tb> <SEP> wheat <SEP> 0 <SEP> C, <SEP> G <tb> <SEP> bar' <SEP> e <SEP> 3G <tb> <SEP> wild <SEP> oats <SEP> O <SEP> C,2G <tb> <SEP> do-..' <SEP> bro-..e <SEP> 2C <SEP> 2G <SEP> SC, <SEP> 4G <tb> <SEP> cheat <SEP> rasps <SEP> 5C, <SEP> 6G <SEP> EC, <SEP> 8G <tb> <SEP> blackrass <SEP> L <SEP> 7C <SEP> L <SEP> 8C <SEP> 1 <SEP> 7C,SG <tb> <SEP> annual <SEP> bluerras: <SEP> 2C <SEP> 3G <SEP> 4C,"C <tb> <SEP> preen <SEP> foxtail <SEP> 3C <SEP> 5G <SEP> 6C.7G <tb> <SEP> quackEross <tb> <SEP> LU <SEP> ¯ <SEP> 3C,4G <tb> <SEP> ftalian <SEP> tyegtasr <SEP> It <SEP> ¯ <SEP> 1C,6G <tb> <SEP> rlpEut <SEP> brotle <SEP> 2G <SEP> 1C.3G <tb> <SEP> Russian <SEP> thisrl- <SEP> 10C <SEP> 10C <tb> <SEP> tans <SEP> Eiustard <SEP> 10C <SEP> 1 <SEP> OC <tb> <SEP> snartvcd <tb> <SEP> smartweed <SEP> ¯ <tb> <SEP> imhill <SEP> mustard <tb> <SEP> Kochia <SEP> 7C,6G <tb> <SEP> shepherd's <SEP> purse <SEP> OC <tb> <SEP> false <SEP> charno: :'.iie <SEP> "C <SEP> 6G <tb> <SEP> black <SEP> nightshade <SEP> 2C,4G <SEP> Cm <SEP> C,7G <tb> <SEP> vellow <SEP> rocket <SEP> lOC <SEP> I <SEP> 9C,9G <tb> <SEP> wild <SEP> mustard <SEP> 1 <SEP> OC <SEP> lOC <SEP> 9C.9G <tb> <SEP> vild <SEP> buckwheat <SEP> 8C,7G <SEP> C,?G <tb> <SEP> s <tb> Table D (continued) EMI150.1 <tb> <SEP> t2 <SEP> 23 <SEP> m3 <tb> <SEP> t' <tb> <SEP> -- <tb> <SEP> Post-emergence <SEP> Pre-emergence <tb> <SEP> I <tb> h*J <SEP> k <SEP> /):a <SEP> 0.015 <SEP> 0.015 <tb> <SEP> cheat <SEP> 1 <tb> <SEP> bn¯tP', <tb> <SEP> wwild <SEP> oats <SEP> O <SEP> ,¯ <SEP> ¯ <SEP> 2C' <tb> <SEP> dow <SEP> rore <SEP> n <SEP> ZC <SEP> . <SEP> 3G <tb> <SEP> cheat <SEP> trass <SEP> O <SEP> 7C <SEP> 7G <tb> <SEP> black;rass <SEP> O <SEP> 7C. <SEP> 8G <SEP> ¯ <SEP> ¯ <tb> <SEP> annual <SEP> bluetrass <SEP> O <SEP> 2C, <SEP> 3G <tb> <SEP> çreen <SEP> foxtail <SEP> O <SEP> 3G <tb> <SEP> quackgr?ss <SEP> O <SEP> ¯ <SEP> 1G <tb> <SEP> Italian <SEP> reegrass <SEP> o <SEP> O <tb> <SEP> rigut <SEP> bronxe <SEP> O, <SEP> O <tb> <SEP> Russian <SEP> thistle <SEP> 3C.4G <SEP> O <tb> <SEP> tansv <SEP> mustard <SEP> ¯ <SEP> lOC <SEP> BC,SG <tb> <SEP> s=.artweed <SEP> ¯ <tb> <SEP> timhill <SEP> Dustard <SEP> lOC <SEP> ¯ <SEP> 4C, <SEP> 8G <tb> <SEP> Koehia <SEP> ZC, <SEP> 2G <SEP> 2G <tb> <SEP> shepherd <SEP> ' <SEP> s <SEP> purse <SEP> 5C <SEP> . <SEP> 4G <SEP> 7C, <SEP> 9G <tb> <SEP> false <SEP> chamot <SEP> le <SEP> C, <SEP> 4: <SEP> 2C. <SEP> 3G <tb> <SEP> black <SEP> nithtshade <SEP> (1 <SEP> 2: <SEP> 2G <tb> <SEP> vellow <SEP> rocket <SEP> 7 <SEP> . <SEP> 8C, <SEP> 9G <tb> <SEP> vild <SEP> mustard <SEP> 1 <SEP> no <SEP> 7c. <SEP> ?G <tb> <SEP> vild <SEP> buchheat <SEP> ¯ <SEP> vr <SEP> . <SEP> wn <SEP> 3G <tb> <SEP> i <tb> Table D (continued) EMI151.1 <tb> <SEP> 2st )CH3 <SEP> CB3 <tb> <SEP> S02NNCONH4i <tb> <SEP> - <SEP> .3 <tb> <SEP> / <SEP> Pott-eoerpence <SEP> Pre-energence <tb> Aste <SEP> kcXh <SEP> k <SEP> . <SEP> LOC; <SEP> 0.06 <tb> <SEP> wheat <SEP> 2G <SEP> 0 <tb> <SEP> bte. <SEP> C <SEP> ,6C <SEP> I <SEP> 0 <tb> <SEP> b <SEP> . <SEP> 7C <SEP> . <SEP> 6G <SEP> O <SEP> ¯ <tb> <SEP> uild <SEP> oats <SEP> 7 <SEP> 7G <SEP> o <tb> <SEP> do-'.' <SEP> broke <SEP> 6C <SEP> . <SEP> 7. <SEP> 2C <SEP> 3G <tb> <SEP> cheatzrass <SEP> 5 <SEP> 5C <SEP> . <SEP> 6G <SEP> I <SEP> 1C,3G <tb> <SEP> blackçrass <SEP> 2 <SEP> . <SEP> 2C <SEP> 3G <tb> <SEP> annual <SEP> bluegrass <SEP> iC <SEP> 2G <SEP> lC,5G <tb> <SEP> zree: <SEP> foxtail <SEP> IC <SEP> iG <SEP> 0 <tb> <SEP> quackgrass <SEP> 5C <SEP> . <SEP> 5G <SEP> 0 <tb> <SEP> Italian <SEP> T'e <SEP> rass <SEP> CC <SEP> Ot <SEP> 0 <tb> <SEP> ringut <SEP> bronze <SEP> 7 <SEP> 7G <SEP> 0 <tb> <SEP> Russian <SEP> thistle <SEP> 0 <SEP> 2G <tb> <SEP> tans" <SEP> mustard <SEP> 2C <SEP> 2G <SEP> SC,7G <tb> <SEP> smartveed <tb> <SEP> limhilf <SEP> mostard <SEP> ¯ <SEP> tC.6C <SEP> i <SEP> 3C,7G <tb> <SEP> Kochia <SEP> 1 <SEP> 2G <SEP> 3G <tb> <SEP> seoherd's <SEP> prurse <SEP> ,C,2G <SEP> 3C.8G <tb> <SEP> false <SEP> chamoile <SEP> ( <SEP> 1C.2G <SEP> I <SEP> se <tb> <SEP> b¯lack <SEP> niaht <SEP> 6 <SEP> 1C,2G <tb> <SEP> rella <SEP> rock <SEP> lr¯, <SEP> 2G <SEP> 7C, <SEP> 8G <tb> <SEP> bl?ck <SEP> nirhtshade <SEP> n <SEP> ¯ <SEP> lLaL <tb> <SEP> vello <SEP> roclcet <SEP> lr <SEP> )y <SEP> 7C <SEP> 8G <tb> <SEP> vild <SEP> mustard <SEP> C <SEP> . <SEP> 4G <SEP> 1C,4G <tb> <SEP> vild <SEP> buckwheat <SEP> --D <SEP> 2C,2G <tb> <SEP> l <tb> <SEP> w <SEP> -l <tb> <SEP> &verbar; <SEP> - <SEP> S <tb> Table D (continued) EMI152.1 <tb> <SEP> CR <tb> <SEP> < 2NHCON <SEP> N <tb> <SEP> mcor <tb> <SEP> OCH <tb> <SEP> Post-emergence' <SEP> Pre-emergence <tb> <SEP> R±:e <SEP> k <SEP> ns <SEP> 0.25 <SEP> 0.25 <tb> <SEP> wheat <SEP> 0 <SEP> <tb> <SEP> b <SEP> V <SEP> ¯ <tb> <SEP> id <SEP> oats <SEP> - <SEP> u <tb> <SEP> d-r?v <SEP> brcl-.e <SEP> u <SEP> 0 <tb> <SEP> cheathrass <SEP> u <SEP> 2G <tb> <SEP> It <tb> <SEP> blatkrasr <SEP> ILr4(1 <SEP> ZC <tb> <SEP> annual <SEP> bluegtas <SEP> 3GI <tb> <SEP> quack¯Frass <SEP> 0 <tb> <SEP> Italian <SEP> r"e±rass <tb> <SEP> ri <SEP> ut <SEP> bromine <tb> <SEP> Russian <SEP> thistle <SEP> LC <SEP> G <tb> <SEP> - <SEP> .P <SEP> s <SEP> s <tb> <SEP> tansv <SEP> mustard <SEP> i <SEP> C, <SEP> 2G <tb> <SEP> smarrveed <SEP> ¯ <tb> <SEP> imhill <SEP> mustard <SEP> I <SEP> C, <SEP> G <tb> <SEP> Kochia <SEP> , <SEP> G <tb> <SEP> sheoherd <SEP> 's <SEP> rse <SEP> ,'* <SEP> C, <SEP> G <tb> false <SEP> chamo:ile <SEP> v <tb> black <SEP> ni <SEP> htshade <SEP> 1C,L; <tb> <SEP> rr <SEP> - <SEP> T <SEP> r <tb> <SEP> yellow <SEP> rocket <SEP> , <SEP> 0 <tb> <SEP> wild <SEP> mustard <SEP> IUC <SEP> i <SEP> 3C,SG <tb> <SEP> - <SEP> r <SEP> . <SEP> Sw <tb> <SEP> wild <SEP> buckwheat <SEP> 1U, <SEP> tk <SEP> a <SEP> 1C,2G <tb> Table D (continued) EMI153.1 <tb> <SEP> < 02WHCONN <SEP> H0 <SEP> N <tb> <SEP> =3 <tb> <SEP> J <SEP> R <tb> <SEP> Post-tPergence <SEP> Pre-emergence <tb> &verbar; <SEP> - <SEP> <tb> hve <SEP> kc/ha <SEP> 0.25 <tb> <SEP> a <SEP> o <tb> <SEP> wheat <SEP> O <tb> <SEP> 1 <SEP> C, <SEP> G <tb> <SEP> wild <SEP> oats <SEP> O <SEP> G <tb> do' <SEP> bro-.. <SEP> SC,4G <SEP> C, <SEP> G <tb> <SEP> cheat <SEP> grass <SEP> 3C,7G <SEP> jC, <SEP> G <tb> <SEP> blackçrass <SEP> z <SEP> ¯ <SEP> 6G <SEP> C, <SEP> C <tb> <SEP> annual <SEP> bluerass <SEP> 3C,6C <SEP> rG <tb> <SEP> green <SEP> foxtail <SEP> '1C,1G <SEP> C, <SEP> C <tb> <SEP> uack <SEP> rass <SEP> O <SEP> C, <SEP> C <tb> <SEP> italian <SEP> pcrass <tb> <SEP> ripgut <SEP> btoe <SEP> 0 <SEP> 3C,4r, <tb> <SEP> Russfan <SEP> this <SEP> 10C <SEP> 1 <SEP> 3C,G <tb> <SEP> ta¯rrst <SEP> mustar <SEP> i <SEP> ¯ <SEP> 10C <SEP> I <tb> <SEP> siEattveed <SEP> I <SEP> - <SEP> I <SEP> IOC <tb> <SEP> i¯n; ;hir <SEP> mustard <SEP> i <tb> <SEP> Ko¯cfiia <SEP> ..j <SEP> 2C,3 <SEP> 9C,9G <tb> <SEP> shoterd <SEP> 's <SEP> 1Purse <SEP> / <SEP> g <tb> <SEP> Kochia <SEP> 2r, <SEP> 3Z <SEP> 8G <SEP> '-- <tb> <SEP> sherherd's <SEP> rurse <SEP> loc <SEP> - <SEP> sc, <SEP> 9G <SEP> - <tb> <SEP> false <SEP> chaomile <tb> <SEP> black <SEP> nightshade <SEP> lOC <SEP> 8C,4G <tb> <SEP> yellow <SEP> rocket <SEP> ¯ <SEP> lOC <SEP> C, <SEP> C <tb> <SEP> wild <SEP> mustard <tb> <SEP> Ys <SEP> ld <SEP> bùeW^hea <SEP> t <SEP> - <SEP> 1 <SEP> OC <SEP> BC, <SEP> 7G <tb> <SEP> &verbar; <tb> <SEP> - <SEP> 62 <tb> Table D EMI154.1 <tb> <SEP> 2 <SEP> H00 <tb> <SEP> =3 <tb> <SEP> Posr-emereence <SEP> Pe-cnergence <tb> ; ;Clrt <SEP> kg/h <SEP> 0.06 <SEP> O.OE <tb> 1 <tb> <SEP> 1 <SEP> <tb> <SEP> rheat <SEP> 0 <SEP> n <tb> <SEP> ild <SEP> oats <SEP> O <SEP> O <tb> <SEP> brrle- <SEP> r <SEP> o <SEP> I <SEP> 1C,2¯G <tb> <SEP> vil <SEP> aats <SEP> 0 <tb> <SEP> dorn\- <SEP> brct <SEP> i <SEP> le <SEP> f,ze <tb> <SEP> blackerass <SEP> 2G <SEP> 2C. <SEP> 3G <tb> <SEP> annual <SEP> bluetrass <SEP> G <SEP> So¯ <SEP> i <SEP> 5G <tb> <SEP> reen <SEP> foxtail <SEP> 0 <SEP> O <tb> <SEP> quacktrass <SEP> O <SEP> 1C <SEP> 3G <tb> <SEP> Italian <SEP> rvegrass <SEP> 2G <SEP> ¯ <SEP> 3G <tb> <SEP> ripgut <SEP> bro':'e <SEP> O <SEP> 2G <tb> <SEP> Russian <SEP> thistle <SEP> ' <SEP> ¯ <SEP> icc <tb> <SEP> tans <SEP> mustard <SEP> i¯ <SEP> icc <SEP> r <SEP> lOC <tb> <SEP> smartweed <tb> <SEP> imhi,ll <SEP> mustard <SEP> lOC <SEP> SC,5G <tb> <SEP> 0 <SEP> ucru <tb> <SEP> Kochia <SEP> 0 <SEP> O <SEP> . <SEP> . <SEP> 7G <tb> <SEP> shepherd <SEP> urse <SEP> lOC <SEP> 9G <tb> <SEP> I <tb> <SEP> false <SEP> chan.o:ile <tb> <SEP> black <SEP> nlQhtshade <SEP> 7C,8G <SEP> 3C,7G <tb> <SEP> vellow <SEP> rocket <SEP> 9C <SEP> . <SEP> 9G <SEP> 7C, <SEP> 8G <tb> <SEP> vild <SEP> sxustard <SEP> ¯ <SEP> , <SEP> 1OC <SEP> 9C, <SEP> 8G <tb> <SEP> vlld <SEP> buclsZheat <SEP> 7C <SEP> . <SEP> 7G <SEP> , <SEP> 4C, <SEP> 6G <tb> <SEP> s <tb> Test D Two ten-inch in diameter plastic pans lined with polyethylene liners were filled with prepared Fallsington silt loam soil. One pan was planted with sees of wheat (Triticum aestivum), barley (Horde@@ vulsate), wild oats (Avena fatua) , downy brome (Brotertorum), cheatgrass (Bromus secalinus), blackgrass (Alcoecurus myosuroides), annual bluegrass (Poa annua), green foxtail (Setaria viridis), Quackgrass (Acropyron repens), Italian Tyegrass (Lolium multi flctut) and ripgut brome (Bromus rigidus) The other pan was planted with seeds of Russian thistle (Salsole kali), tansy mustard (Descuraina pinnate), emertwees (Polygonue pennsylvanicum), tumble mustard (Sisyrbriet altissiu) kochia (kochia scopatia), schepherd's purse (Capsella bursa-pastoris), Matricaria inodera, black nightshade (Solanum niorum), yellow rocket (Barbares vulcaris), wild mustard (Brassica kaber) and wild buexcheat (Polypon@@ convolvulus). The above two pans were treated pre-emergence. At the same time two cens in which the above Giant species were growing were treated post-emergence. Plant height at the tim c' treatment ranged from 1-15 cm- depending on plant species. The compounds applied were diluted with a non- phytotoxic solvent and sprayed over-the-top of the pans. An untreated control and a solvent alone control were included for comparison. All treatments were maintained in the greenhouse for 2: days at which time the treatments were compared to the controls and the effects visually rated. in accordance with the rating system described for Test A. The recorded data are presented in Table D. The data indicate that certain compounds from within the scope of this invention have utility for weed control in cereal crops, such as wheat and barley. TABLE C (continued) EMI156.1 <tb> <SEP> CR2Cl <SEP> OCH3 <tb> <SEP> SO2NRCC <SEP> k) <tb> <SEP> =3 <tb> Aste <SEP> tZ <SEP> ¯ <SEP> O <SEP> .03 <SEP> O <SEP> . <SEP> 0.125 <tb> So'beans <SEP> lOG,6C <SEP> lOG, <SEP> C <tb> teu <SEP> etleaf <SEP> 6G <SEP> G, <SEP> f <SEP> <tb> Sesbania <SEP> lOG,3C <SEP> OG,9C <tb> Cassia <SEP> I <SEP> 3G,lC <SEP> SG, <SEP> C <tb> Cotton <SEP> 3G,lC <SEP> 4G,2C <tb> MorningElor+ <SEP> 5G <SEP> 5G, <SEP> C <tb> Alfalfa <SEP> ' <SEP> 5G,2C <SEP> 7G, <SEP> 3C <tb> 3fnsonveel <tb> Cocklebur <SEP> 4G <SEP> 3G,1C <tb> <SEP> Corn <SEP> ' <SEP> 5G,5H <SEP> 9G,SC <tb> <SEP> Crabgrass <SEP> 2G <SEP> 3G <SEP> C <tb> Rice <SEP> 5G <SEP> ¯ <SEP> 8G,3C <tb> Xutsedge <SEP> G <SEP> - <SEP> ¯46 <SEP> 7G,2C <tb> Barnxardgrass <SEP> SG,lC <SEP> 8G,ZC <tb> lEneat <SEP> 0 <SEP> 0 <tb> Giant <SEP> foxtail <SEP> 6G,lC <SEP> G, <SEP> C <tb> Wild <SEP> Oats <SEP> O <SEP> 0 <tb> <SEP> Scrhu: <SEP> 5G <SEP> lC <SEP> 7G <SEP> = <tb> TABLE C (continued) EMI157.1 <tb> <SEP> CHC1 <tb> <SEP> ol <SEP> P <SEP> 3 <tb> <SEP> so2mcOMa <tb> <SEP> CR3 <tb> <SEP> 0 <tb> Rate <SEP> k <SEP> /):a <SEP> 0. <SEP> 0.25 <tb> <SEP> Soybeans <SEP> lOG <SEP> 6C <SEP> lOG <SEP> 5 <tb> <SEP> Velvetleaf <SEP> lOG <SEP> 6C <tb> <SEP> Sesbania <SEP> 9C <tb> <SEP> Cassia <SEP> lOG <SEP> SC <tb> <SEP> Cotton <SEP> 9C <tb> <SEP> Xlorninzzlorx- <SEP> lOG <SEP> 7C <SEP> l:,nr <SEP> Qx <SEP> ¯ <tb> <SEP> Alfalf <SEP> a <tb> <SEP> 3i:s <SEP> onweec <tb> <SEP> Cocklebur <SEP> 10 <SEP> G <SEP> 9C <SEP> lOG <SEP> 8C <tb> <SEP> r <SEP> <SEP> i <tb> <SEP> Corn <tb> <SEP> Crabgrass <SEP> w <SEP> 3G, <SEP> 1C <SEP> 7 <tb> <SEP> Rice <SEP> 6G. <SEP> 1C <SEP> ;¯ <tb> <SEP> Nutsedge <SEP> , <SEP> 6G <SEP> 9G <tb> <SEP> Barnyardgrass <SEP> 6G <SEP> . <SEP> 3C <SEP> 8G <SEP> . <SEP> 3C <tb> <SEP> Uheat <SEP> 3G, <SEP> 2C <SEP> 7G, <SEP> 2C <tb> <SEP> Giant <SEP> Fox <SEP> tai <SEP> 4 <SEP> G <SEP> g <SEP> G <tb> <SEP> v <SEP> Oa <SEP> t <SEP> s <SEP> ., <SEP> 5G <SEP> 7 <SEP> G <SEP> . <SEP> 2 <SEP> C <tb> <SEP> Sorghu: <SEP> 9G <SEP> . <SEP> 3C <SEP> 1 <SEP> n <SEP> , <SEP> 7c <tb> <SEP> f <SEP> m <tb> q <tb> <SEP> s <SEP> 2 <tb> Table C Over-the-Top Soil/Foliage Treatment Compound 8 Rate kg/ha 0.06 0.25 Soybeans @ 3G,lC 6G,3C Velvetleaf 9G,4C lOG,8C Sesbania 9G,3C 10G,6C Cassia 10G,3C 10G, 8C Cotton 8G,3C 9G,4C Morningglory lOG,4C lOC Alfalfa 1C ' 1C Jimsonweed 1C 3G,1C Cocklebur 9G,3C lOG, 5C Corn O 0 Crabgrass 0 0 Rice 5G SG Nutsedge O 0 Barnyardgrass 0 Wheat O 0 Giant foxtail 0 1G Wild Oats O 1C Sorghum O 0 Table C (continued) EMI159.1 <tb> <SEP> 7MIS <SEP> (0)C5 <tb> <SEP> 502 <SEP> CONR <SEP> qNOf <tb> <SEP> W7 <tb> <SEP> OQ1 <tb> <SEP> 1 <tb> i2itr <SEP> k,-hr <SEP> 0.12 <SEP> 0.03 <tb> <SEP> I <SEP> 'p <tb> Sabcas <SEP> 10G.7C <SEP> Inr <SEP> c <tb> r!etlef <SEP> IOG,1C <SEP> 1 <SEP> 9C <SEP> , <SEP> SC <tb> SesSaia <SEP> 10G,8C <SEP> 10G,8C <tb> Cassia <SEP> IOG,7C <SEP> 9G, <SEP> 5C <tb> Cotton <SEP> 9G. <SEP> 55 <SEP> 9G,5C <tb> McrnincDlose <SEP> ' <SEP> ¯ <SEP> OG <SEP> 8C <SEP> 7 <SEP> lOG,SC <tb> Alfalfa <SEP> 9C <tb> Ji-son <SEP> ee' <SEP> 9G <SEP> . <SEP> 7C <SEP> SG <tb> Cocklebur <SEP> 1 <SEP> ne <SEP> 8n <SEP> 1 <SEP> OG <SEP> 7C <tb> <SEP> w <SEP> - <SEP> f <tb> Corn <SEP> 1 <SEP> OC <SEP> 9C <tb> Crabgrass <SEP> 7G.3C <SEP> 5G <tb> fiice <SEP> 7 <SEP> 9Gss <SEP> 3C <SEP> 9G,3C <tb> Nutsede <SEP> 1Qt <SEP> 9G <SEP> 3C <tb> Barns <SEP> ardgrass <SEP> loc <SEP> 9C <tb> "'.eat <SEP> 3G <SEP> 1 <SEP> G <tb> Giant <SEP> Foxtai <SEP> 10r <SEP> C <tb> Wild <SEP> Oats <SEP> lOC <SEP> - <SEP> F <tb> Sorghum <SEP> lOC <tb> Table C (continued) EMI160.1 <tb> <SEP> CI(IS01013 <SEP> I) <tb> <SEP> S02?HCONH <SEP> 04 <tb> <SEP> 1 <tb> R±:e <SEP> IrF/hr <SEP> 0.03 <SEP> , <tb> Sovbeans <SEP> lOG <SEP> 7C <tb> eive:leaf <SEP> 7G <tb> Sesbaria <SEP> a <SEP> 9G <SEP> 6C <tb> Cassia <SEP> lOG. <SEP> 7C <tb> Cottc?. <SEP> 8G, <SEP> 3C <tb> Vornin;lorw- <SEP> 9G <SEP> 4C <tb> lfa!f2 <SEP> 9C <tb> Jinsonveed <SEP> 7G, <SEP> 3C <tb> Cockie5¯r <SEP> 1 <SEP> OG <SEP> 6C <tb> Corn <SEP> 9G <SEP> 2C <tb> Crabgrass <SEP> O <tb> Rice <SEP> 'IC <tb> Eotredpe <SEP> 9G,4C <SEP> 1 <tb> Barnt-ardgtass <SEP> 8t <tb> Vheat <SEP> 0 <tb> Giant <SEP> Foxtail <SEP> 7G <SEP> 3C <tb> Wild <SEP> Oats <SEP> 1G <tb> Sor <SEP> bu: <SEP> 9G <SEP> 4 <tb> Test C (continued) EMI161.1 <tb> <SEP> ZIEXIS <SEP> (O) <SEP> CXJ <SEP> N <SEP> Cfl <tb> <SEP> 02NHCONH <SEP> npt <tb> <SEP> 3 <tb> Rit <SEP> kih <SEP> n <SEP> 7 <SEP> 0.03 <tb> <SEP> o?-oeas <SEP> 10G.6r <SEP> 9G <SEP> ,5C <tb> <SEP> else:lef <SEP> ST: <SEP> 'lr <SEP> fG,3C <tb> <SEP> Sestaa <SEP> ¯8,3C <SEP> 5G.3C <tb> <SEP> CaJa <SEP> 8C,6C <tb> <SEP> C: <SEP> tc <SEP> 8G <SEP> . <SEP> br <SEP> 6G,3C <tb> <SEP> =miny!or <SEP> gG <SEP> dr <SEP> 9G,3C <tb> <SEP> falfa <SEP> BC <SEP> 7G,3C <SEP> ¯¯ <tb> <SEP> Jr,sontC <SEP> BG,4 <SEP> = <tb> <SEP> CcleLr <SEP> InGle <SEP> 9G, <SEP> 3C <tb> <SEP> Ccrn <SEP> 1 <SEP> 10r <SEP> 8G,5C <tb> <SEP> C:;le- <SEP> - <SEP> 1 <SEP> ni <SEP> gr <SEP> 9G. <SEP> 3C <tb> S <SEP> L <tb> <SEP> Ccrn <SEP> 1 <SEP> nc <SEP> SG, <SEP> 5s <tb> <SEP> Crab±rass <SEP> w <SEP> O <SEP> 0 <tb> <SEP> Rice <SEP> QC <SEP> Sc, <SEP> 3C <tb> <SEP> N"'sede <SEP> 3C <tb> <SEP> Barnnargrass <SEP> lOC <tb> <SEP> w > e t <SEP> ¯ <SEP> 7e <SEP> 2G <tb> <SEP> Giant <SEP> Foxtail <tb> <SEP> Wild <SEP> Oats <SEP> ¯ <SEP> 1 <SEP> ne <SEP> ¯ <SEP> 8G, <SEP> 4C <tb> <SEP> Sor <SEP> 5 <SEP> no <SEP> I <SEP> 9G, <SEP> 4C <tb> w <SEP> - <SEP> iL <tb> w <tb> Table C (continued) EMI162.1 <tb> <SEP> oC'I3 <tb> h:e <SEP> k-/):a <SEP> Q <SEP> ? <SEP> ) <SEP> 0.03 <tb> S6vbca-I <tb> <SEP> Ibc. <SEP> 7C <SEP> ' <SEP> ¯10C,6C <tb> t'tfoettlf <SEP> G.3C <SEP> 4C, <SEP> 2C <tb> <SEP> Scstanfa <SEP> IbC <SEP> 8C <SEP> 9G, <SEP> 3C <tb> <SEP> Cotton. <SEP> 8G. <SEP> 4C <tb> <SEP> =mir!br <SEP> OG <SEP> . <SEP> 3C <tb> hl'a'fa <SEP> ,¯ <SEP> SC <tb> Ji:sonee: <SEP> lOG <SEP> 6C <tb> Coc-lei <SEP> r <SEP> lOG <SEP> . <SEP> 7C <SEP> lOG, <SEP> 6C <tb> <SEP> Corn <SEP> SG. <SEP> 3C <SEP> , <SEP> SG, <SEP> 3C3C <tb> Crab-rass <SEP> 1 <SEP> SG <SEP> 5G. <SEP> 2C <tb> Rice <tb> l;ut <SEP> se <SEP> g <tb> <SEP> Barn.vard <SEP> brass <SEP> 9C <SEP> Sc. <tb> ; <SEP> - <SEP> Oe <SEP> o <tb> tant <SEP> re*tafl; <SEP> BG <SEP> .9 <SEP> C <tb> u?ld <SEP> Oacs <SEP> ou <SEP> 1 <SEP> r <tb> <SEP> Sorghum <SEP> i <SEP> 4C <tb> <SEP> &verbar; <tb> Table C (continued) EMI163.1 <tb> <SEP> r25( )C <SEP> 3 <SEP> CM <tb> <SEP> ¯ <SEP> CR3 <tb> <SEP> - <SEP> CR3 <tb> Rate <SEP> k <SEP> 0.03 <tb> hve <SEP> Xc/h <SEP> O <SEP> .12 <SEP> O <SEP> . <SEP> 03 <tb> <SEP> S <tb> <SEP> Sox <SEP> beans <SEP> 1H <SEP> iH <tb> el'eleaf <SEP> ¯ <SEP> 3G, <SEP> 1C <SEP> G, <SEP> C <tb> Sesaia <SEP> - <SEP> 1C <SEP> o <tb> Cassa <SEP> 3C <tb> Cc:to. <SEP> tC <SEP> 0 <tb> F:crr.irllorx <SEP> 7G,3C <SEP> G, <SEP> C <tb> Alfalfa <SEP> 3C <SEP> SC <tb> Jb:sorxswee¯ <SEP> 3G <tb> Cockl <SEP> ef <SEP> r <SEP> w <tb> Corn <SEP> 5G,3C <tb> Crabgrass <SEP> SG,lC <tb> Rice <SEP> 9,3C <SEP> G, <tb> Nutsedge <SEP> 4G. <SEP> 1C <tb> Rarns <SEP> rass <SEP> t;, <SEP> 3C <SEP> 3 <tb> ;'heat <SEP> 5G <tb> haat¯ <tb> CSant <SEP> To: <SEP> 8G, <SEP> 3C <SEP> 5G, <SEP> LC <tb> Sorehu <SEP> 9G <SEP> 4C <tb> <SEP> P <tb> Table C (continued) EMI164.1 <tb> <SEP> ccQ:2scM <tb> <SEP> tSO29MCONH SO <tb> <SEP> one <tb> Rate <SEP> *s/hF <SEP> .25 <SEP> 0.06 <tb> <SEP> Sovbea-.s <SEP> - <SEP> OG, <SEP> C <tb> 'tel'-etlea.' <SEP> G, <SEP> Sr <SEP> r <SEP> sG"C <SEP> C <tb> 5esar.ie <tb> Cassia <SEP> 5r <SEP> RG <SEP> 4C,7G <tb> Cc:to <SEP> 9.5C <SEP> 4G,2C <tb> =rninlor <SEP> : <SEP> 9.6C <SEP> PG,6C <tb> r:falfa <SEP> 9C <SEP> 8C <tb> Jit,sant;i <SEP> lal <tb> CockleSJr <SEP> 5.7e <SEP> 1G. <SEP> 5C <tb> Corn <SEP> 9G.9Y <SEP> TGI <SEP> gL <tb> Crpbrass <SEP> 8G <SEP> . <SEP> C <SEP> iG,C <tb> RSct <SEP> BG, <SEP> f <SEP> se <tb> ffutsedse <SEP> ¯ <SEP> fGIZf <SEP> 5G. <SEP> LC <tb> BsmvardIass <SEP> 1 <SEP> QC <SEP> IOC <tb> k?raat <SEP> 7C.213 <SEP> x;¯ <tb> harnvarc±tas <SEP> 1 <SEP> no <SEP> 1Ut <tb> Wtheat <SEP> 7G. <SEP> 2e <SEP> Ss <SEP> - <tb> Giant <SEP> Foxtail <tb> tw'ilt <SEP> Oats' <SEP> Qi^ <SEP> c <SEP> MFIR <tb> <SEP> Sor±h-u¯, <SEP> Qr <SEP> Cy <SEP> 9G, <SEP> 4C <tb> Table C (continued) EMI165.1 <tb> <SEP> t02 <SEP> HCoNH < OX <tb> <SEP> OeL3 <tb> Ra: :e <SEP> k <SEP> a <SEP> 0.25 <SEP> 0.0± <tb> <SEP> Soybeans <SEP> G <SEP> 6C <SEP> G, <SEP> C <tb> <SEP> aDeans <tb> <SEP> el'etleaf <SEP> j <SEP> ¯ <SEP> 9G <SEP> SC <SEP> - <SEP> 7G, <tb> <SEP> Sesbar.ia <SEP> 4C <SEP> 7G <SEP> t <tb> <SEP> Cassia <SEP> 8G,4C <SEP> IG,C <tb> <SEP> forran <SEP> j <SEP> 8G <SEP> ,5C <SEP> ,G13C <tb> <SEP> minfrlor <SEP> j <SEP> -9G <SEP> ,5C <SEP> /G <SEP> ,4C <tb> 'Aifalfa <SEP> 4C,9G <SEP> -4t,-4G--nsclit; <tb> <SEP> -ccrrnu <tb> <SEP> Cocklebwr <SEP> 1OG, <SEP> 5C <SEP> lOG" <SEP> 5C <SEP> lOG,5C <tb> <SEP> Corn <SEP> 8C.,8U <tb> <SEP> CraÅabrass <SEP> 6G, <SEP> 3C <SEP> 5G <tb> <SEP> Rice <SEP> 9G.6C <tb> <SEP> Nutsedge <SEP> 7G, <SEP> C <tb> <SEP> Barnvard <SEP> rass <SEP> ion <SEP> l <SEP> U <SEP> C <tb> <SEP> Wheat <SEP> 4 <SEP> G <tb> ntoxtai <SEP> <tb> <SEP> Wild <SEP> Oats <SEP> 7G,4C <SEP> G, <tb> <SEP> Sorghum. <SEP> 8G,SC <SEP> 8G, <tb> <SEP> 7 <SEP> w <tb> Test C (continued) EMI166.1 <tb> <SEP> CH&num;H <tb> <SEP> FH, <tb> <SEP> : <SEP> sowHccrrnOk <tb> <SEP> O <SEP> m3 <tb> <SEP> OCHJ <tb> <SEP> 1 <tb> Rtr <SEP> kE/h <SEP> n <SEP> nF, <SEP> u0 <SEP> ,, <tb> Sobcas <SEP> 1PG,BC <SEP> 10G.7C <tb> 'elve: <SEP> 1 <SEP> ea; <tb> Sestania <SEP> lOCF <SEP> ¯ <SEP> 1 <SEP> nc <tb> Casria <SEP> .n <SEP> G <SEP> . <SEP> p¯e <tb> Cotton <SEP> 10E <SEP> 7C <SEP> L!±L <tb> .','orni'n-:l <SEP> orx <tb> Alfalfa <SEP> C <SEP> r <tb> Jinsonveej <SEP> ¯ <SEP> C <SEP> 7y <tb> <SEP> Cocklebr <SEP> lOG, <SEP> 7 <tb> <SEP> 10G,7C <SEP> 1.7C <tb> Cotn <SEP> 8G,51: <SEP> ¯¯ <SEP> 8G. <SEP> 4' <tb> Crabrass <SEP> .1G <SEP> 1 <tb> Rice <SEP> ¯¯¯¯¯ <SEP> 8G,3C <SEP> bC <tb> utsedee <SEP> Te <SEP> ¯¯,,2G <tb> Barn'-ardrass <SEP> 7G <SEP> . <SEP> 3C <tb> 0 <tb> Giant <SEP> Foxtail <SEP> 4G <SEP> F <tb> Wild <SEP> Oats <tb> <SEP> Sorthu-. <SEP> , <SEP> 8G <SEP> . <SEP> C <SEP> n <tb> Table C (continued) EMI167.1 <tb> <SEP> 0CM <SEP> 3 <SEP> CH <tb> <SEP> tS <SEP> N <tb> <SEP> Sobea,c <SEP> lOG <SEP> 7C <SEP> lOG,4C <tb> <SEP> ssF <SEP> te <SEP> *v/h <SEP> O <SEP> . <SEP> 0 <SEP> 6 <SEP> O <SEP> . <SEP> 01 <SEP> 5 <SEP> ¯ <tb> <SEP> Sovbear.s <SEP> 1 <SEP> OG, <SEP> 7C <SEP> 1 <SEP> OG, <SEP> 4 <SEP> C <tb> <SEP> e!etleaf <SEP> 1 <SEP> OG, <SEP> 8C <SEP> 5G,1C <tb> <SEP> Sesbania <SEP> ¯ <SEP> lOG <SEP> . <SEP> 9C <SEP> ¯ <SEP> lOG,6C <tb> <SEP> Cassia <SEP> lOG <SEP> . <SEP> 7C <SEP> lOG, <SEP> 5C <tb> <SEP> Cotton <SEP> 6G <SEP> 3C <SEP> 5G, <SEP> 3C <tb> <SEP> .orningilorx <SEP> lOC <SEP> 6G <SEP> 2C <SEP> F <tb> <SEP> Alfalfa <SEP> 8C <SEP> 6G.3C <tb> <SEP> - <SEP> &commat; <tb> <SEP> J <SEP> son-ee¯ <SEP> ¯ <tb> <SEP> Cocklehr <SEP> r <SEP> lOG <SEP> 6c <SEP> SC <SEP> 3C <tb> <SEP> Corn <SEP> 8G, <SEP> SC <SEP> 8G, <SEP> SC <tb> <SEP> Crab±rass <SEP> O <SEP> O <tb> <SEP> Rice <SEP> lOG <SEP> . <SEP> 7C <SEP> 9G <tb> <SEP> Nutsedge <SEP> 3G.1C <SEP> 2G <tb> <SEP> Barnard <SEP> rass <SEP> C <SEP> SC <SEP> 3C <SEP> SC <tb> <SEP> Sloeat <SEP> ¯1 <SEP> O <SEP> O <tb> <SEP> Giant <SEP> Foxtail <SEP> 5G <tb> <SEP> ;'ild <SEP> Oats <SEP> 1C <SEP> O <tb> <SEP> SorRhum. <SEP> 8G. <SEP> 3U <SEP> 7G,3C <tb> r <SEP> 1 <tb> <SEP> 1 <tb> <SEP> v <tb> <SEP> w <SEP> l <SEP> <tb> Table C (continued) EMI168.1 <tb> <SEP> t <SEP> 2980NHiOt <tb> <SEP> 3 <tb> <SEP> I <tb> <SEP> 1 <tb> Rate <SEP> *v/ba <SEP> n <SEP> ha <SEP> 0.015 <tb> <SEP> Inr <SEP> nr <tb> Soo <SEP> beans <SEP> lOG, <SEP> 8C <SEP> 1 <SEP> OG <SEP> . <SEP> 8C <tb> elverleaf <SEP> lOC <tb> Sesbania <SEP> 10t <SEP> lOC <tb> Cassia <SEP> lOG <SEP> 8C <tb> Cotton <SEP> OG, <SEP> 6C <SEP> 9ç, <tb> Mornln6glorv <SEP> lOC <tb> Alfalfa <SEP> 8C <SEP> 7 <tb> J$ssonvee <SEP> ¯ <tb> Cocklebur <SEP> lOC <tb> Corn <SEP> 7G,5H <SEP> 6.5 <tb> Cribgiaos <SEP> 3G <SEP> 0 <tb> Rice <SEP> 9G <SEP> , <SEP> 5C <SEP> ¯.8 <SEP> G <SEP> , <SEP> I <SEP> C <tb> Nursedge <SEP> I <SEP> 9G,5C <SEP> 8G <SEP> . <tb> Nuesedge <SEP> 9G, <SEP> 5C <SEP> 8G <tb> Barnn7ardgrass <SEP> 3C18C <tb> Wheat <SEP> ¯ <SEP> 2G <SEP> ,1C <SEP> 7 <SEP> C <tb> Giant <SEP> Foxtail <SEP> 7G, <SEP> 2C <SEP> . <SEP> 7Ç <tb> ;'ilt <SEP> Oaes <SEP> O <SEP> n <tb> Sorghus; <SEP> 8G <SEP> . <SEP> 2C <SEP> 4f. <tb> Table C (continued) EMI169.1 <tb> <SEP> CH2001 <SEP> CHJ <tb> <SEP> sotHnCoNH--(O) <tb> <SEP> WI <tb> <SEP> 3 <tb> .=e <SEP> Irg/hr <SEP> 0.06 <SEP> O.D15 <tb> <SEP> SaDeans <SEP> 10G,9C <SEP> 10G,8C <tb> i <SEP> Veletleaf <SEP> 10C <SEP> 9C <tb> <SEP> Sesbania <SEP> 10C <SEP> I <SEP> 1 <SEP> OC <tb> <SEP> tarsia <SEP> 1G18C <SEP> IOG.7L <tb> <SEP> fottan <SEP> ¯9C <SEP> ¯9C <tb> <SEP> Y,ornin:Elor <SEP> 1 <SEP> OC <SEP> i <SEP> 10C <tb> <SEP> Alfalfa <SEP> 9G6C <SEP> I <SEP> .9G <SEP> ,6C,., <tb> <SEP> Yorninc±10rx <SEP> 9G, <SEP> 6C <SEP> + <tb> <SEP> Jinsanvee <SEP> i <tb> Cccklebur <SEP> 8G. <SEP> 3C <SEP> SG. <SEP> 3C <tb> <SEP> Corn <SEP> L <SEP> Sc <SEP> 8G <SEP> . <SEP> 4 <tb> <SEP> Crabgrass <SEP> 6G <SEP> ,1C <SEP> i <SEP> 3G <tb> <SEP> Rice <SEP> lOG, <SEP> 5C <SEP> 1 <SEP> G <SEP> SC <tb> <SEP> Ntsedge <SEP> 9G <SEP> 6C <SEP> 7G <tb> <SEP> BarnyardE,rass <SEP> 8G.4C <tb> <SEP> Wsheat <SEP> 8G <SEP> -2C <SEP> ¯6G, <SEP> ZC <tb> <SEP> Giant <SEP> Fostail <SEP> 8G <SEP> 6G. <SEP> 1C <tb> <SEP> ;'ild <SEP> Oats <SEP> S <SEP> 9G, <SEP> 3C <SEP> v <tb> <SEP> Soszhum. <SEP> 9G. <SEP> 3C <SEP> QG <SEP> . <SEP> ?C <tb> Test C EMI170.1 <tb> cn <SEP> oar <SEP> w <SEP> 502 <SEP> MH <tb> a <SEP> n <SEP> 06 <SEP> 0.015 <tb> <SEP> IOG15C <tb> <SEP> Sovveans <SEP> -rac <SEP> C <tb> <SEP> e:etleaf <SEP> 9C <SEP> C <tb> <SEP> SesLacia <SEP> lOC <SEP> OG, <SEP> C <tb> <SEP> Cassia <SEP> lOG <SEP> 7C <SEP> 1 <SEP> G, <SEP> C <tb> <SEP> Cotton <SEP> j <SEP> 9G.4C <SEP> 7G,3C <tb> <SEP> 10G,5C¯ <SEP> G <tb> <SEP> Alfalfa <SEP> 6G,2C <SEP> 2G <tb> <SEP> Ji:sn':eed <SEP> 3G, <SEP> 2C <tb> <SEP> Cockleb <SEP> 7C.lOG <SEP> 4G <tb> <SEP> Corn <SEP> ' <SEP> SG <SEP> 4': <SEP> G, <SEP> N <tb> <SEP> Gravrass <SEP> w <SEP> 3G,1C <SEP> C <tb> <SEP> Rice <SEP> ¯ <SEP> 8G, <SEP> 3C <SEP> G, <SEP> ''- <SEP> SG, <SEP> C <tb> <SEP> Nutsedge <SEP> SG,3C <SEP> 3G,2C <tb> <SEP> Barnoasdgrass <SEP> 8G,4C <SEP> bG <tb> <SEP> wheat <SEP> 6G <SEP> 1 <SEP> G <tb> <SEP> Giant <SEP> Foxtail <SEP> 3G <SEP> 1C <SEP> O <tb> <SEP> Wild <SEP> Oats <SEP> 7G <SEP> 2C <SEP> G <tb> <SEP> Sorghum <SEP> 8G <SEP> 4C <SEP> 8G, <SEP> 2C <tb> <SEP> E <tb> <SEP> S <SEP> i Test C Twenty-five em diameter plastic pots illiet with Fallsington silt loam were planted with soybeans, cotton, alfalfa, corn, rice, wheat, sorghum, velvetlea (Abutilon theophrasti), sesbanis (Sesbania exaltate), Cassia (Cassia tora), morningglory (Ioomoea heder acea), Jimsonweed (Datura stramonium), cocklebur (xantnium pennsylvanicum), erabgrass (Digitaria spo.), nutsedge (Cyoerus rotundus), barnyardgrass (Ethlon- chlos crusoalli), giant foxtail (Setaria faberii) @@@ wilo oats (Avena fatua). Approximately two wee < s after planting, the young plants and the soil arbusd the were sprayed overall with the test chemicals dissolve in a non-phytotoxic solvent. Two wee; < s after treatment, all species were compared to untreated controls and visually rated for response te treatment. The rating sytem was as described previously for Test A. The data are presented in Table Several of the compounds tested by this procedure are useful for the post-emergence control of weeds in whe at. TABLE B. (continued) EMI172.1 <tb> <SEP> PRE-EKERGENCE <SEP> 0N <SEP> FALLSZ?11GTON <SEP> SIT <SEP> LOAN <tb> <SEP> I <SEP> 3 <tb> <SEP> SOHCT]PH <SEP> <tb> <SEP> c <tb> <SEP> N <tb> l*e <SEP> kowhF <SEP> O. <SEP> 03 <SEP> 0.12z <tb> <SEP> Crabztsss <SEP> O <tb> <SEP> Ba <SEP> rnvar¯d¯slra <SEP> 0 <SEP> 4r: <tb> <SEP> Scrun <SEP> 4G <SEP> 7G.3n <tb> <SEP> ¯0 <SEP> n <tb> <SEP> Jofrnsonnsass <SEP> O <SEP> f.G. <SEP> tY <tb> <SEP> DalrisnraJf <SEP> ¯G <SEP> t <SEP> nF <tb> <SEP> Cit <SEP> faxtail <SEP> ¯0 <tb> <SEP> De' <SEP> liseraes <SEP> 6G <SEP> ¯ <SEP> 1 <SEP> nF <tb> <SEP> 6iant <SEP> f <SEP> ox <SEP> tai <SEP> l <SEP> 1 <tb> <SEP> K. <SEP> blue±rass <tb> <SEP> Cheatgress <SEP> O <SEP> n <tb> <SEP> SuDarbeet5 <SEP> O <SEP> n <tb> <SEP> fborn <SEP> O <SEP> wn <tb> <SEP> dustard <SEP> 4 <SEP> G <SEP> 1 <SEP> nx <tb> <SEP> Cocklebur <SEP> ¯ <SEP> O <SEP> n <tb> <SEP> pS <SEP> eed <SEP> ¯ <SEP> O <SEP> % <tb> <SEP> Nut <SEP> sed <SEP> te <SEP> ¯ <SEP> <SEP> n <tb> <SEP> Cotton <SEP> O <SEP> ¯¯ <SEP> ¯ <SEP> n <tb> <SEP> Morninze <SEP> losn <SEP> n <SEP> n <tb> <SEP> Cassia <SEP> ¯ <SEP> O <SEP> my <tb> Zueed <SEP> . <SEP> n <SEP> on <tb> AISL!:L <SEP> n <SEP> . <SEP> 7r: <tb> Ji-sont <SEP> eed <SEP> n <SEP> n <tb> <SEP> Sovbe2n¯ <SEP> n <SEP> - <SEP> ¯. <tb> <SEP> R¯ <SEP> c <SEP> e <SEP> <SEP> L <SEP> A <tb> <SEP> Uheat <SEP> n <SEP> n <tb> TABLE B (continued) EMI173.1 <tb> <SEP> PR--D,ERGENCE <SEP> OX <SEP> FA'LSI'.CTON <SEP> SILT <SEP> LOk'. <tb> <SEP> m <tb> <SEP> 8 <SEP> n <tb> <SEP> N <SEP> E <SEP> r <tb> <SEP> I <tb> <SEP> Cl <SEP> CS <tb> <SEP> U <SEP> OUS <tb> <SEP> - <SEP> -- <SEP> LI- <SEP> n <SEP> I <SEP> I <SEP> -n <SEP> 2r; <tb> <SEP> ke <SEP> kc/hr <SEP> 0.125 <SEP> 00 <SEP> 1 <tb> <SEP> 0 <SEP> -c-- <SEP> o <SEP> 1 <SEP> o <tb> : <SEP> CraScrate <tb> <SEP> 5 <SEP> 2r-va <SEP> =r' <SEP> rr <SEP> SG <SEP> ,3C <SEP> 1G. <SEP> fC <SEP> OI <SEP> 3G <tb> <SEP> Scth <SEP> 8G, <SEP> SH <SEP> fGISf! <tb> <SEP> ril <SEP> Dets <SEP> O <SEP> 1 <SEP> 0 <SEP> 0 <tb> <SEP> Jchnsonras <SEP> SG <SEP> 0 <SEP> 3G <tb> <SEP> Dellisrtc <SEP> O <SEP> ¯j <SEP> 3r- <SEP> 0 <SEP> 0 <tb> <SEP> Ciant <SEP> foxtall <SEP> SG <SEP> ¯i <SEP> 1(1F¯ <SEP> O <SEP> 0 <tb> <SEP> 0 <SEP> 0 <tb> <SEP> CheatKrass <SEP> 3G <SEP> 7n <SEP> 0 <SEP> O <SEP> 5G <tb> <SEP> Su4çarbeets <SEP> I <SEP> 5}! <SEP> F; <SEP> r <SEP> O, <SEP> 2G <tb> <SEP> Corn <SEP> BG, <SEP> 5H <SEP> aC, <SEP> 9C' <SEP> O <SEP> 2C <tb> <SEP> Mustard <SEP> loc <SEP> O <SEP> no^ <SEP> ¯ <SEP> <SEP> L <SEP> BG <SEP> 3C <tb> <SEP> fJustarr! <SEP> i <SEP> Ice <SEP> 0 <SEP> I <SEP> 2G <tb> <SEP> tC <SEP> 9c2. <SEP> et <tb> <SEP> CockTeSur <tb> <SEP> fipeed <SEP> 5G. <SEP> 5G <tb> <SEP> utsedne <SEP> 3G <SEP> cr <SEP> O <SEP> - <SEP> 7C- <tb> <SEP> 26ttdti <SEP> 8G¯ <SEP> ¯ <SEP> ¯ <SEP> oc <SEP> . <SEP> Ac <SEP> o <tb> <SEP> aaveed <SEP> 1 < <SEP> 1 <SEP> 1 <SEP> nr <SEP> 1 <SEP> 2G <tb> <SEP> 5'e <SEP> lvet <SEP> .9C <SEP> e <tb> <SEP> JiPsonx <SEP> weed <tb> <SEP> çYt5¯ <SEP> 8 <SEP> G <SEP> . <SEP> 5 <SEP> H <SEP> q <SEP> u <SEP> O <SEP> an <tb> <SEP> Ri <SEP> c <SEP> e <SEP> O <SEP> S <SEP> f <SEP> 4 <SEP> G <tb> <SEP> l:heat <SEP> n <SEP> n <SEP> O <SEP> 3G <tb> TABLE B (continued) EMI174.1 <tb> <SEP> PRE-EXERCE±CE <SEP> ON <SEP> FgLSlrUGTON <SEP> SILT <SEP> LOA: <tb> <SEP> 'G±02 <SEP> OCR <tb> <SEP> vsoPmMA <tb> <SEP> tlY <tb> <SEP> r <tb> amaze <SEP> k <SEP> fha <SEP> 0. <SEP> L <SEP> 0.0-' <SEP> 0.06 <SEP> 0.25 <tb> <SEP> Crabcr2ss <SEP> ¯ <SEP> 6G <SEP> 1 <SEP> 0 <SEP> 6G <SEP> L <SEP> 8G, <SEP> 6C <tb> <SEP> B rnx <SEP> s¯d <SEP> ± <SEP> ra <SEP> es <SEP> G <SEP> O <SEP> 9G, <SEP> 9s <SEP> 1 <SEP> OC <tb> <SEP> Scr <SEP> SG <SEP> -':- <SEP> 7G <SEP> H <SEP> lOC <SEP> lOE <tb> <SEP> 7 <SEP> 2: <SEP> ' <tb> <SEP> Jchns¯nrraes <SEP> H <SEP> 46, <SEP> O <SEP> ¯4 <SEP> G <SEP> C <SEP> jH¯ <SEP> 1 <SEP> S <SEP> G <SEP> . <SEP> ,9C <SEP> lOC <tb> <SEP> flalli <SEP> racs <SEP> G <tb> <SEP> Giant <SEP> foxtail <SEP> O <SEP> L <SEP> 1 <SEP> 10 <SEP> L <SEP> i <SEP> lOC <tb> <SEP> Xs <SEP> - <SEP> blueçrass <SEP> 5t; <SEP> ¯6C- <SEP> . <SEP> 3C <tb> <SEP> Chcatnsass <SEP> 4¯6 <SEP> . <SEP> 10 <SEP> 1OE <tb> <SEP> Sunarbeets <SEP> O <SEP> 5G <tb> <SEP> Corn <SEP> 1 <SEP> O <SEP> O <SEP> 1= <SEP> 1 <SEP> 3 <SEP> OF <SEP> I <SEP> ICC <tb> <SEP> Mustard <SEP> 9G, <SEP> 1 <SEP> 9G, <SEP> 8C <SEP> lOC <SEP> 1 <tb> <SEP> Cocklebur <SEP> 6G, <SEP> 3E <SEP> G <SEP> 6Ç <SEP> G <SEP> H <SEP> S <SEP> - <SEP> S <tb> <SEP> Pi <SEP> ±': :eed <SEP> - <SEP> - <SEP> - <SEP> <tb> <SEP> Nutstdee <SEP> ¯¯ <SEP> 10F <tb> <SEP> 96 <SEP> I <tb> <SEP> Cattbn <SEP> O <SEP> 9G¯¯I <SEP> 1 <SEP> OC <tb> fcm <SEP> inna <SEP> Idtv <SEP> 26 <SEP> SG <SEP> 30C <SEP> 1 <SEP> QC <tb> <SEP> a <SEP> 5 <SEP> s <SEP> I <SEP> a <SEP> O <SEP> 5G <SEP> 10C <SEP> I <SEP> 1 <SEP> Ot <SEP> i <tb> <SEP> Inaei <SEP> , <SEP> D <SEP> O <SEP> ioc <SEP> loc <SEP> ¯i <tb> <SEP> Vevet <SEP> Le¯af <SEP> O <SEP> oc <SEP> I <SEP> iC <SEP> i <tb> ¯JimsEveel <SEP> .O <SEP> 1 <SEP> 0 <SEP> .6G <SEP> OC <tb> ¯Socbcan <SEP> n <SEP> 0 <SEP> 9G.9C <SEP> 96, <tb> Rice <SEP> 5G <SEP> i <SEP> 6G <SEP> 1OFr <SEP> 1E <tb> 'meat <SEP> a <tb> <SEP> 4 <tb> Table B (continued) PRE-EMERGENCE ON FALLSINGTON SILT LOAM Compound 10 Compound 14 Rate kg/ha 0.03 0.12 0.06 0.25 Crabgrass 0 2G 0 3G Barnyardgrass 2G 5G 3G 5G, 3C Sorghum 3G, 2H 9G, 5H 8G, 5H 9G, 5H Wild Oats 2G 4G 4G 7G Johnsongtass 0 5G, 3H 5G, 3H 5G, 5H Dallisgrass 0 3G 3G 0 Giant foxtail 0 3G 3G,3H 7G,3H Ky. bluegrass 0 2G 4G 7G,3H Cheatgrass 3G 4G 5G,3C 7G,3C Sugarbeets 5G 7G,3H 8G,9C lOC Corn 0 2G 3G, 2C 6G, 2H Mustard 8G,8C 8G,8C 9G,9C lOC Cocklebur 0 3G 6G,3H 9G,9C Pigweed 7G 8G 5G, 3C 10C Nutsedge 0 0 7G 8G Cotton 3G 5G, 3H 3H 5H Morningglory 3G 6G 6G, 5H 6G, 5H Cassia 4G 4G 4G 7G Teaweed 0 3G 2G SG Velvetleaf 4G,3H 6G,5H 5G, 3H Jweed 0 5G, 5C 6G, 4C 7G, 7C Soybean 2G 0 .2G 5G, 3H Rice 4G 6G 7G,3H 8G,SH Wheat O 0 3G 5G Table B (continued) PRE-EMERGENCE ON FALLSINGTON SILT LOAM Compound 7 Compound 8 Compound 9 Rate kg/ha 0.06 0.25 0.25 0.12 Crabgrass O 0 0 0 Barnyardgrass 2G 3G 0 3G Sorghum 7G,5H 7G,5H 2G 0 Wild Oats 0 0 0 0 Johnsongrass 0 0 0 0 Dallisgrass 0 0 0 0 Giant foxtail 0 3G 0 0 Ky. bluegrass 0 4G 0 0 Cheatgrass 0 3G 0 0 Sugarbeets 0 7G 0 3G Corn O 0 0 0 Mustard 7G,3C 8G,6C 5G 4G Cocklebur 5G 7G,3H 0 0 Pigweed 0 8G,8C 3G 3G Nutsedge 4G 8G 0' 0 Cotton 4G 5G, 3H 0 0 Morningglory 3G 6G 0 0 Cassia 0 5G 3G 4G Teaweed O 0 3G 0 Velvetleaf 3G 6G,5H 3G 0 Jimsonweed 0 4G 0 0 Soybean 0 0 2G 0 Rice 4G 5G 0 0 Wheat O O 0. 0 Table B (continued) EMI177.1 <tb> <SEP> PRE <SEP> RGENCE <SEP> ON <SEP> fALLSZ':tfOZ; <SEP> SILT <SEP> LOAM. <SEP> SGI <SEP> L <tb> <SEP> sO2McONPI <tb> <SEP> 3 <tb> <SEP> Rs:e <SEP> n.vs <tb> <SEP> I <SEP> 0 <tb> <SEP> tra;r <SEP> a <SEP> e <tb> <SEP> -fZt'*iea <tb> <SEP> s.±. <SEP> ¯ <SEP> . <SEP> ¯w. <tb> <SEP> i <SEP> 2= <SEP> 4G <tb> <SEP> .Itrr=ross <SEP> 3G <SEP> <tb> i <SEP> 3llirtraL <SEP> o <tb> <SEP> o <tb> i <SEP> K. <SEP> bleras <SEP> 0 <tb> <SEP> 4G <tb> <SEP> Chcartra <SEP> fOC <tb> <SEP> suarbce <SEP> 0 <tb> : <SEP> Ccrr. <tb> <SEP> ustard <SEP> 9G,9C <tb> <SEP> fatkltjur <SEP> ¯ <SEP> 0 <tb> <SEP> liut <SEP> seire <SEP> 0 <tb> <SEP> Cotwor. <SEP> 4G, <SEP> 3r <tb> <SEP> "-rn <SEP> lor' <SEP> 4G <SEP> 2H <tb> <SEP> Cassw <SEP> a <SEP> 3G <tb> <SEP> T <SEP> Ca <SEP> 0 <tb> <SEP> Yelvet <SEP> I <SEP> ez' <SEP> , <SEP> 6G <tb> <SEP> Ji-scrveed <SEP> . <SEP> O <tb> <SEP> Soo <SEP> be <SEP> an <SEP> ¯ <SEP> . <SEP> <tb> <SEP> Rice <SEP> - <SEP> 6G <tb> Table B (continued) EMI178.1 <tb> <SEP> PRE <SEP> RCENC¯ <SEP> DS <SEP> TeL5 <SEP> i:GTON <SEP> SILT <SEP> LOM <SEP> SOIL <tb> <SEP> (O)CHJ <SEP> PCIIJ <tb> <SEP> W <tb> <SEP> 3 <tb> <SEP> I <SEP> S <SEP> z <SEP> 0 <SEP> . <SEP> k <SEP> 1 <SEP> /):a <tb> <SEP> ¯I <SEP> 9G.8C <tb> i <SEP> =rattass <SEP> 3G <tb> <SEP> g,,,, <SEP> ard <SEP> ua <SEP> ce <SEP> 7G <SEP> . <SEP> 8C <SEP> 10C <tb> <SEP> SCrt-k- <SEP> - <SEP> 10t <SEP> 10C <tb> <SEP> Jsrrass <SEP> 9 <SEP> Sc <SEP> lOC <tb> <SEP> ; <SEP> o <SEP> ii <SEP> s; <SEP> a <SEP> .e <SEP> .; <SEP> 9 <SEP> G <SEP> . <SEP> iot <tb> <SEP> Giant <SEP> foxtail <SEP> ¯ <SEP> 7G <SEP> 3H <SEP> lOC <tb> <SEP> 0 <SEP> . <SEP> bue:rae: <SEP> 7G <SEP> . <SEP> sc <SEP> 1 <SEP> OC <tb> <SEP> Cheatra.:s <tb> <SEP> Surarbee:s <SEP> 1OC <SEP> 1OC5 <tb> <SEP> Cclrr! <SEP> .6.5f <SEP> 1DC <tb> <SEP> ustar <SEP> 9C,9 <SEP> OC <tb> <SEP> Cocklrbr <SEP> 4C <SEP> 8t,5H <tb> <SEP> Pfpect' <SEP> BG.7C <SEP> 10C <tb> <SEP> Nutscdre <SEP> 4G <SEP> 10E <SEP> r <tb> <SEP> orSo <SEP> 4G <SEP> 6G,5H <SEP> <tb> <SEP> nrrnineor <SEP> G.3E <SEP> 8 <SEP> 5 <tb> <SEP> assfa <SEP> 7G <SEP> . <SEP> 4e <tb> <SEP> v <tb> <SEP> ffaveed <SEP> i <SEP> 6 <SEP> 6C <SEP> , <SEP> 5H <tb> <SEP> Vel <SEP> v <SEP> c <SEP> t <SEP> e <SEP> a,i <SEP> I <SEP> hr,¯ <SEP> W <SEP> 8C <SEP> , <SEP> 3H <tb> <SEP> Rice <SEP> a <SEP> 7r <SEP> 1 <SEP> lOC <tb> <SEP> tjhcat <SEP> 5G <tb> Table B (continued) EMI179.1 <tb> PREw <SEP> ERGENCE <SEP> 0N <SEP> teLSI"G-ON <SEP> SIL- <SEP> LOAM <SEP> SCIb <tb> <SEP> 0013 <tb> <SEP> CCIISOICAJ <SEP> oa <tb> <SEP> So2Nmico" <tb> <SEP> W <tb> <SEP> 3 <tb> <SEP> Ra:e <SEP> kcx <SEP> 0.03 <SEP> 0. <SEP> 12 <tb> <SEP> CraL.ra:c <SEP> | <SEP> 3G <SEP> I <SEP> 3G <tb> <SEP> De¯C <SEP> J <SEP> . <SEP> 8G,8C <tb> <SEP> cct <SEP> oc <SEP> I <SEP> loc <tb> <SEP> 2G <SEP> I <tb> <SEP> I <tb> <SEP> rs,--;-es <SEP> 7G.3 <SEP> - <SEP> I <SEP> ¯qg <SEP> C <tb> <SEP> Ca-: <SEP> fcxtai <SEP> 1 <SEP> SG <SEP> Sc.3r4 <tb> <SEP> K'. <SEP> bl.je:racc <SEP> i <SEP> 6G <SEP> I <SEP> G, <SEP> 7G. <SEP> 3C <tb> <SEP> Chea:trat.s <SEP> I <SEP> - <SEP> I <SEP> <tb> <SEP> Su:arbeets <SEP> I <SEP> lOC <SEP> loc <tb> <SEP> Cort <SEP> ; <SEP> 7GA5ii <tb> <SEP> custard <SEP> 0 <SEP> lOC <tb> <SEP> Cocklebur <SEP> I <SEP> 3G <tb> <SEP> Pigweed <SEP> 1 <SEP> 8G,8 <SEP> SG.SC <SEP> 9C <SEP> Rr <tb> <SEP> butsedre <SEP> I <SEP> 10F <SEP> lOE <tb> <SEP> Cottor <SEP> ! <SEP> 6G <SEP> . <tb> <SEP> nrrnrnrl <SEP> 4C,3H <SEP> ¯S. <tb> <SEP> tacclaa <SEP> 7G <SEP> .5 <SEP> Rr- <SEP> Fr <tb> <SEP> TeaveeJ <SEP> I <SEP> 3G- <SEP> 2C <SEP> I <SEP> mC <SEP> wU <SEP> . <tb> <SEP> Vcllvttleaf <SEP> fG <SEP> . <SEP> 9 <SEP> G¯ <SEP> u¯ <tb> <SEP> s1son:eeJ <SEP> I <SEP> 8G <SEP> .7C <SEP> 5c.c <SEP> I <tb> <SEP> Sovbea- <SEP> 1 <SEP> 6G. <SEP> 5H <SEP> 7r, <SEP> CFW <SEP> , <SEP> ,, <tb> <SEP> Rlce <SEP> ! <SEP> . <SEP> 7c <SEP> 1 <SEP> . <SEP> rnl <SEP> mC <tb> <SEP> lFllea2 <SEP> Q <SEP> ! <SEP> xr <tb> <SEP> l <SEP> l <SEP> Table B (continued) EMI180.1 <tb> <SEP> PRE-E'RCENCZ <SEP> ONNSItTL0M.SOIL <tb> <SEP> cH3 <tb> <SEP> 1 <tb> <SEP> · <tb> iZ1=r <SEP> q/hr <SEP> 0,03 <SEP> 0. <SEP> 17 <tb> h:e <SEP> iv/h <SEP> 0 <SEP> 03 <SEP> O.12 <tb> <SEP> Cratra <SEP> O <SEP> 3G <tb> <SEP> Bar-ar-je <SEP> 4G <SEP> 7C,8C <tb> <SEP> S-tEh- <SEP> 9¯G.9C <SEP> ¯ <SEP> .OC <tb> <SEP> ilC <SEP> C2:t <SEP> 3G <tb> <SEP> zhnsras <SEP> 4.2 <SEP> 9G.8C <tb> <SEP> Dalllsrras <tb> <SEP> tfanr <SEP> foxtail <SEP> 3G <SEP> 6G.3H <tb> <SEP> K. <SEP> bfuetacs <SEP> 5¯G <tb> <SEP> Cheatoras <SEP> Inr <tb> <SEP> cheatcrase <SEP> w <SEP> . <tb> <SEP> suearbeet <SEP> e <SEP> 7 <SEP> sic <SEP> lOC <tb> <SEP> Corn <SEP> O <SEP> 4G,3H <tb> <SEP> ustard <SEP> 9,qZ <SEP> 10C <tb> <SEP> Cockler <SEP> 4G <SEP> 7G <tb> <SEP> Pigved <SEP> 3C <SEP> 8G <tb> <SEP> Nut <SEP> scdr <SEP> e¯ <SEP> ¯ <SEP> ¯ <SEP> 4C <SEP> ¯ <SEP> 9C <SEP> , <SEP> 8E <tb> <SEP> Ccftat. <SEP> 3C <SEP> SC, <SEP> 3H <tb> <SEP> ncninnnlot <SEP> 46 <SEP> . <SEP> 3H <SEP> 7G,5H <tb> <SEP> assa <SEP> 2 <SEP> 6G.3C <tb> <SEP> f3v0 <SEP> 2r: <SEP> G,ZC <tb> <SEP> vrrlvetleke <SEP> 4E <SEP> 4CclK <tb> Soybean <SEP> 3(: <SEP> an <SEP> F <tb> <SEP> Riee <SEP> 6G <SEP> 8G,56 <tb> <SEP> SEeat <SEP> )r: <SEP> 4 <SEP> G <tb> Table B (continued) EMI181.1 <tb> <SEP> PRE-D:ERGEN;E <SEP> 0N <SEP> ALLSI.'CTON <SEP> SILT <SEP> LO'. <SEP> SOIL <tb> <SEP> SO <SEP> cH <tb> <SEP> sL <tb> <SEP> - <SEP> SO1WHCONHI <tb> <SEP> OCRJ <tb> ILre <SEP> Irg/t,r <SEP> 1 <SEP> 0.03 <SEP> 0.12 <tb> <SEP> Cra;rrs <SEP> O <SEP> +-0 <tb> <SEP> rcarltra <SEP> 4 <tb> <SEP> rct,aC <tb> <SEP> St-- <SEP> r0r <SEP> 9G,9C <tb> <SEP> - <SEP> z <SEP> or <SEP> ' <SEP> F <SEP> SG <tb> <SEP> J. <SEP> 2.nsencra <SEP> F <SEP> U <SEP> 7G <SEP> 3H <SEP> <tb> <SEP> 3a'- <SEP> Ta:: <tb> <SEP> Giant <SEP> foxtail <SEP> 5G <SEP> 7Gw <SEP> 3E <tb> <SEP> K=-, <SEP> blootracs <SEP> 6G <SEP> 7G, <SEP> SC <tb> - <SEP> C)'eatra.:: <tb> <SEP> Surarbcc <SEP> 8G.9 <SEP> 10C <tb> <SEP> Corr: <SEP> 3G <SEP> 9G, <SEP> 8C <tb> <SEP> ustard <SEP> ,oG,9C <SEP> 1 <SEP> OC <tb> <SEP> Cockltur <SEP> .6G. <SEP> 2C <SEP> 6G <SEP> , <SEP> SH <tb> <SEP> Pi <SEP> O <SEP> 6G <SEP> --tn <tb> <SEP> Nutse <SEP> 4 <SEP> G <SEP> 6G <SEP> 6G <SEP> e <tb> <SEP> Cottor. <SEP> 4C. <SEP> qu <SEP> 6G. <SEP> 5E <tb> <SEP> ne <SEP> rr: <SEP> in <SEP> PT <SEP> lat\' <SEP> 4 <SEP> E <SEP> ¯ <SEP> 3r <SEP> 8G <SEP> . <SEP> 5E <tb> <SEP> accia <SEP> 3r <SEP> 5G <SEP> . <SEP> 3r <SEP> i <tb> <SEP> raveec <SEP> tT: <SEP> C <SEP> I <SEP> SG <SEP> . <SEP> I <tb> <SEP> B1 <SEP> n <SEP> R <SEP> C <SEP> .'e' <SEP> qu <tb> L <SEP> 7C.5r <tb> <SEP> Scvbean <SEP> 4 <SEP> r,, <SEP> fW <SEP> 7 <tb> <SEP> 8C;.r <tb> <SEP> Yheat <SEP> )C. <SEP> wr: <tb> <SEP> L <tb> Table B (continued) EMI182.1 <tb> <SEP> FRE-D .ERCENCE <SEP> ON <SEP> FALLSI:GTON <SEP> SILT <SEP> LOAM <SEP> SOIL <tb> <SEP> yjcR7sa' <SEP> OCH <tb> <SEP> so2NHcON)(a <tb> <SEP> Nn <tb> <SEP> OCH <SEP> 3 <tb> <SEP> - <SEP> - <SEP> <tb> <SEP> Ra-e <SEP> *vWhv <SEP> 0.03 <SEP> 0.12 <tb> <SEP> Crarra:.C <SEP> 2G <SEP> -- <SEP> ¯ <SEP> ¯ <SEP> 6G <SEP> 3H <tb> <SEP> ci- <SEP> ra <SEP> e <SEP> C <SEP> SG <SEP> 5; <SEP> , <SEP> 9G, <SEP> 9c <tb> <SEP> S <SEP> --- <SEP> iCC <SEP> OE <tb> <SEP> SG <SEP> Pea <SEP> ra <SEP> s <SEP> 5G <SEP> 5G, <SEP> 5C <tb> <SEP> J-hnscn <SEP> ras; <SEP> 9G <SEP> 9C <SEP> iCc <tb> <SEP> ops <SEP> 7 <SEP> iscrass <SEP> SG <SEP> 8G, <SEP> SC <SEP> 4 <tb> <SEP> Via..: <SEP> foxtail <SEP> 8G <SEP> 5H <SEP> lOC <tb> <SEP> K. <SEP> . <SEP> bluezras. <SEP> 6G <SEP> 3C <SEP> lOC <SEP> 1 <SEP> OC <tb> <SEP> Cheat <SEP> rasps <SEP> 7C <SEP> lOt <tb> <SEP> Su <SEP> arbeets <SEP> 8G <SEP> r <SEP> 8c <SEP> 1OC <tb> <SEP> Corn <SEP> 6G, <SEP> 3H <SEP> 8G, <SEP> 8C <tb> <SEP> Mustard <SEP> lOC <SEP> lOC <tb> <SEP> Cocklebr <SEP> 4G <SEP> 7G, <SEP> 7C <tb> <SEP> Pieveed <SEP> 8G, <SEP> 5C <SEP> lOC <tb> <SEP> Nutse <SEP> e <SEP> 7G <SEP> lOC <tb> <SEP> ot <SEP> t <SEP> or. <SEP> ' <SEP> 6C <SEP> 3N <SEP> 5G <SEP> SN <tb> <SEP> -n <SEP> lor' <SEP> 6 <SEP> 6G, <SEP> H <SEP> , <SEP> SG <SEP> SH <tb> <SEP> Csl <SEP> e <SEP> ' <SEP> *' <SEP> 2 <SEP> 7 <SEP> G <SEP> . <SEP> CH <SEP> 8G, <SEP> 7C <tb> a <SEP> 8G. <SEP> 5H <tb> BILL <SEP> 8: <SEP> 8G. <SEP> SH <tb> <SEP> L <SEP> 8C. <SEP> SH <SEP> 9G. <SEP> 6e <tb> <SEP> Scvbean <SEP> F <SEP> 7G, <SEP> 5E <tb> <SEP> Rice <SEP> l <SEP> nF <SEP> 1 <SEP> nF <tb> <SEP> Whea <SEP> t <SEP> mç <SEP> %y <tb> Table B (continued) EMI183.1 <SEP> S <tb> <SEP> PRE-D:LRGENCE <SEP> ON <SEP> FELSICTO'; <SEP> SILT <SEP> Lok': <SEP> SOIL <tb> <SEP> yCWtS <tb> <SEP> sO2?(0ONNb <SEP> <tb> <SEP> N <tb> <SEP> 1 <tb> <SEP> Ra:e <SEP> k <SEP> /hs <SEP> 0.12 <tb> <SEP> Cra"-ras:. <SEP> 3 <tb> <SEP> ETLrrTTt <SEP> d <SEP> c <tb> <SEP> < *r;2¯- <SEP> Cf. <SEP> )S <SEP> .¯ <SEP> lOC <SEP> ¯¯ <tb> <SEP> fli <SEP> a:s <SEP> 5.C.. <SEP> 5e <tb> I*s-ttaE.B- <SEP> ST: <SEP> ¯ <SEP> 8f5i! <SEP> ¯ <tb> <SEP> 3a <SEP> IiSrrc <SEP> O <SEP> 4r: <tb> <SEP> Cfar.: <SEP> fcxtai: <SEP> 5G <SEP> 2G <tb> <SEP> .¯!uers <SEP> SG <SEP> i <tb> <SEP> fwheaterasm <SEP> lOE <tb> <SEP> Susatbcers <SEP> 6G <SEP> L <SEP> SC:sc.91: <SEP> ¯¯ <tb> <SEP> Corr: <SEP> ¯O <SEP> ¯ <SEP> 4C <tb> <SEP> ustar¯ <SEP> .9C, <SEP> 8 <SEP> 9G,8 <tb> <SEP> CocklelLLr <SEP> 3G <SEP> 5t <tb> <SEP> PiaueeC <SEP> bG <SEP> 8G <SEP> ¯¯ <tb> <SEP> NutseZre <SEP> SG <SEP> 7G <tb> <SEP> Cotran <SEP> Ic <SEP> 4G <tb> <SEP> ncniranfd+ <SEP> .2C <SEP> 8G. <SEP> gu <tb> <SEP> asla <SEP> 1G <SEP> 5G.3u <SEP> i <tb> <SEP> ;; <SEP> 7f <tb> <SEP> <tb> <SEP> lips <SEP> wr <SEP> Ç=U <tb> <SEP> Sos <SEP> bean <SEP> 4 <SEP> C <SEP> ¯ <SEP> FCS <SEP> Fw <tb> <SEP> R:ce <SEP> ¯. <SEP> whiG <SEP> 7r. <SEP> mu <tb> <SEP> ;hea <SEP> t <SEP> )y <SEP> 4 <SEP> C <tb> <SEP> -s <SEP> &verbar; <SEP> &verbar; <tb> m <tb> Table B (continued) EMI184.1 <tb> <SEP> PRE <SEP> ERGENCE <SEP> 0N <SEP> TALLSI.':GT0 <SEP> SILT <SEP> LOo <SEP> SOIL <tb> <SEP> H,OCH <tb> <SEP> (r)T <SEP> 3 <SEP> W <SEP> PO1 <tb> Rs:e <SEP> k <SEP> Iha <SEP> :O..l2 <tb> <SEP> CraXiraeX <SEP> O <SEP> 0 <tb> - <SEP> We <SEP> ç <SEP> cc. <SEP> 5G <tb> <SEP> 6G,3F. <SEP> I <SEP> SG,5:i <tb> -C <SEP> o <SEP> 4G <SEP> ¯ <SEP> 0 <tb> <SEP> 3cnsonfra <SEP> 0 <SEP> e <SEP> O <SEP> C <tb> <SEP> 3a' <SEP> lisçraeF <SEP> O <SEP> ; <tb> <SEP> Giant <SEP> oxti...i <SEP> O <tb> <SEP> Xv. <SEP> bfuenrazs <SEP> 3G <tb> <SEP> Chcatprass <SEP> O <tb> <SEP> SuarbeeTs <SEP> SG <SEP> 9C <SEP> . <SEP> Oc <tb> <SEP> Corr. <SEP> SG <SEP> 6. <SEP> 3?: <tb> mustard <SEP> 9G <SEP> 9C <tb> <SEP> Cockle5S:r <SEP> 7G <SEP> 6G, <SEP> - <SEP> SG-, <SEP> S <tb> <SEP> Pi.leed <SEP> 5G <tb> <SEP> NutscCre <SEP> 0 <tb> <SEP> Cottan <SEP> 'IG, <SEP> 3H <SEP> ¯8CF <tb> njnns!lot <SEP> , <SEP> BCISH <SEP> 9G,3C <tb> <SEP> Case <SEP> i <SEP> a <SEP> 9G <SEP> . <SEP> 4C <SEP> ' <SEP> G,6C <tb> <SEP> Tsuhed <SEP> 6C <SEP> ,3C <SEP> EC, <SEP> 3C <tb> <SEP> Velvct <SEP> c.af <SEP> ¯¯ <SEP> ,8 <SEP> C <SEP> . <SEP> 5H <SEP> 9C <SEP> . <SEP> 7C <tb> <SEP> Ji-soQwee <SEP> 7G. <SEP> 4C <SEP> 9t,7C <tb> <SEP> ±¯ <SEP> 7G. <SEP> an <SEP> 8G, <SEP> 5H <tb> <SEP> Rice <SEP> EC. <SEP> ¯ <SEP> 7G <tb> lwllea <SEP> t <SEP> O <SEP> O <tb> <SEP> 7 <tb> Table B (continued) EMI185.1 <tb> P±-D;ERGE};Cr <SEP> ON <SEP> FALLSI.'.1CTO?: <SEP> SILT <SEP> LOM <SEP> SOIL <tb> <SEP> CnlOCH <tb> <SEP> 502NScONNiO <tb> <SEP> N <tb> <SEP> OCN3 <tb> <SEP> Ante <SEP> Of <SEP> /h <SEP> 1 <SEP> 0¯n3 <SEP> 1 <SEP> Q.12 <tb> <SEP> Crarras:. <SEP> . <SEP> 6G <tb> <SEP> 9a <SEP> r-,t. <SEP> ard <SEP> rr <SEP> az <SEP> c <SEP> 4G <tb> <SEP> iu.n <tb> <SEP> Scrt- <SEP> I <SEP> 10C <tb> <SEP> .9G.9C <tb> <SEP> ilC <SEP> 3ac,e <SEP> .6 <SEP> G., <SEP> 2C <SEP> 6G, <SEP> 4C <tb> <SEP> Jt.nsctracs <SEP> I <SEP> 6G <SEP> 'IG, <SEP> 3H <tb> <SEP> lisrtas <SEP> 0 <SEP> G <tb> <SEP> tirnt <SEP> foxtai <SEP> I <SEP> O <SEP> .frG <tb> <SEP> ¯ <SEP> 7G, <SEP> 6C <SEP> 8G,9C <tb> <SEP> Chearracp <SEP> i <SEP> O <SEP> 6G,¯3C <tb> <SEP> Suarbees <SEP> I <SEP> .. <SEP> TOC <SEP> 1DC <tb> <SEP> Cor <SEP> -] <SEP> ¯7C5Y <SEP> ,, <SEP> 8G.9C <tb> <SEP> Cocklebur <tb> <SEP> Pipveed <SEP> OE <SEP> OE <tb> <SEP> N¯utsede <SEP> 5G <SEP> 7G <tb> <SEP> Cottor: <SEP> B. <SEP> 58 <SEP> i <SEP> 9G <SEP> .3C <SEP> I <tb> <SEP> Hcmfnnnlar <SEP> SG <SEP> 4GBC¯ <SEP> i <tb> <SEP> cfi2 <SEP> 9G.3r <SEP> ] <SEP> 9G. <SEP> Rr <tb> <SEP> Tuc3 <SEP> 7G <SEP> .7C <SEP> aG, <SEP> e <tb> <SEP> Velvezeaf <SEP> 9G, <SEP> ¯C <SEP> I <SEP> 9r: <SEP> .5r¯ <tb> <SEP> ¯Jisoreed <SEP> 9G,9 <SEP> 1 <SEP> fnr <tb> <SEP> an <SEP> 8G. <SEP> SH <SEP> ¯ <tb> <SEP> Rice <SEP> 6Gj <SEP> 3c <SEP> ¯ <SEP> 7n <SEP> An <tb> <SEP> Sllea <SEP> v <SEP> O <SEP> rf: <tb> <SEP> &verbar; <tb> <SEP> i <tb> Ho <tb> Table B (continued) EMI186.1 <tb> <SEP> PRf-EIRCEtiCI <SEP> Oh' <SEP> fATLSI:fTOI; <SEP> SLt <SEP> LOA?: <SEP> SOIL <tb> <SEP> PR±-EXERGENCE <SEP> Or; <SEP> F' <SEP> SI8:GTOri <SEP> SIL: <SEP> LOS: <SEP> 9IL <tb> <SEP> m23 <SEP> w <SEP> 3 <tb> <SEP> 02Nl{COWHSO <SEP> cn3 <tb> <SEP> 502NNcoN?I0 <SEP> N <tb> <SEP> -Cw <tb> I <SEP> <tb> <SEP> T <SEP> 7 <tb> <SEP> Rtc <SEP> t <SEP> 0.03 <SEP> 0.1¯2 <tb> <SEP> 1 <tb> <SEP> CraL <SEP> taC <SEP> n <SEP> tr <tb> <SEP> '*ltX <SEP> O-e <SEP> : <SEP> 7G <SEP> 4C <tb> <SEP> tr: <SEP> ')r <SEP> AI <tb> <SEP> Do <SEP> 1' <SEP> scrs <tb> <SEP> ia-.t <SEP> faxtas <SEP> 0 <SEP> n <SEP> 2G <tb> <SEP> K:. <SEP> b!uecta-ce <SEP> 4n, <SEP> ro <SEP> 8G, <SEP> SC <tb> <SEP> CheatzraXs <SEP> n <SEP> 5G <tb> <SEP> uarbeeTs <SEP> Q <SEP> r, <SEP> lOC <tb> <SEP> O:rr. <SEP> wS <SEP> 7G <SEP> 3H <tb> <SEP> Custard <SEP> r <SEP> nn <SEP> lOC <tb> <SEP> Cockt3ur <SEP> 6G <SEP> ¯ <SEP> 6G, <SEP> 3N <tb> <SEP> P <SEP> eed <SEP> Br: <SEP> 9G <SEP> ¯¯ <SEP> 6 <SEP> G, <SEP> 9C <tb> <SEP> utsed <SEP> e <SEP> n <SEP> SG <tb> <SEP> Cotton <SEP> ¯ <SEP> 7G, <SEP> 5H <tb> <SEP> } <SEP> -n <SEP> 1cr' <SEP> 6G <tb> <SEP> a.sie <SEP> iz <SEP> I <SEP> BG <SEP> ¯ <tb> <SEP> SR <SEP> II' <SEP> ¯¯¯¯¯ <tb> <SEP> Vetver <SEP> 1 <SEP> eax <SEP> ?C <SEP> L <SEP> ¯ <tb> <SEP> Ji-sor,vee <SEP> A&num;; <SEP> 9G <SEP> . <SEP> 9C <tb> <SEP> Sovbran <SEP> 1 <SEP> ar¯ <tb> <SEP> RI <SEP> c <SEP> e <tb> <SEP> ;heat <SEP> n <SEP> 3G <SEP> S <tb> <SEP> i <SEP> u <SEP> <tb> <SEP> s <tb> Table B (continued) EMI187.1 <tb> <SEP> PRE-D:ERGENCE <SEP> ON <SEP> FssLSI':GTON <SEP> SILT <SEP> LOX': <SEP> 5011 <tb> <SEP> QIIOCR, <tb> <SEP> PCR <SEP> , <tb> <SEP> 3 <tb> h:e <SEP> 25/k <SEP> . <SEP> 0-03 <SEP> .¯¯ <SEP> 0.12 <tb> <SEP> CrakirasF <SEP> 2G <SEP> qr <SEP> . <SEP> --n" <tb> <SEP> E <SEP> a-^ <SEP> a-d <SEP> cra <SEP> e <SEP> c <SEP> 7r; <SEP> , <SEP> ¯ <SEP> , <SEP> 1 <SEP> nr <SEP> ' <SEP> - > ¯ <tb> <SEP> Soro <SEP> tc: <SEP> ;S <SEP> 1 <SEP> nr <tb> <SEP> Jo <SEP> ee <SEP> rast <SEP> ar. <SEP> r <tb> Da' <SEP> li <SEP> seraeF <SEP> n <SEP> . <SEP> q <tb> Giar <SEP> t <SEP> f <SEP> ox <SEP> ta <SEP> i <SEP> I <SEP> f) <SEP> vr., <SEP> vr <tb> <SEP> };-s- <SEP> bluearass <SEP> ar, <SEP> sC. <SEP> , <SEP> 1 <SEP> nr <SEP> , <SEP> ". <SEP> ¯ <tb> <SEP> Cheatçrase <SEP> %y <SEP> , <SEP> vr. <SEP> rn <SEP> ¯ <tb> <SEP> Sucarbee <SEP> e <SEP> qr <SEP> qr <SEP> 1OC <SEP> ,,¯ <tb> <SEP> Cors <SEP> . <SEP> wy <SEP> AG <SEP> . <SEP> 9C <tb> Husta-d <SEP> 1 <SEP> nr <SEP> lOC <SEP> w <tb> <SEP> Coekl <SEP> evcr <SEP> 4 <SEP> C <SEP> 7G <tb> <SEP> Pi2veed, <SEP> t <SEP> nv <SEP> 10°¯ <tb> <SEP> iutsedPe <SEP> ?r. <SEP> = <tb> <SEP> Cottor. <SEP> sr. <SEP> 7G. <SEP> qU <tb> M: <SEP> rn <SEP> i <SEP> n <SEP> e <SEP> ± <SEP> 1 <SEP> orv <SEP> n <SEP> x <SEP> . <SEP> ¯ <SEP> LCL <tb> <SEP> C? <SEP> 5 <SEP> e <SEP> i <SEP> 2 <SEP> p <SEP> n. <SEP> q <SEP> (: <SEP> . <SEP> RC <SEP> ¯ <tb> <SEP> leaveeJ <SEP> A <SEP> r <SEP> 7tw <tb> Velvet <SEP> 1 <SEP> eat <SEP> Ax <SEP> wu <SEP> ¯ <SEP> q <tb> <SEP> J <SEP> a <SEP> s <SEP> ° <SEP> ed <SEP> s <SEP> C <SEP> 7 <SEP> Q <SEP> r <SEP> g <tb> <SEP> Sovbear. <SEP> 3 <SEP> C, <SEP> ? <SEP> sU <SEP> 7G <SEP> . <SEP> RS <tb> <SEP> Riee <SEP> SG4C <SEP> 1 <SEP> no <tb> ;'hea <SEP> t <SEP> m <SEP> ¯ <SEP> ,¯ <SEP> r <SEP> t <tb> <SEP> w <tb> Table B(continued) EMI188.1 <tb> <SEP> PRE-a:RGENCE <SEP> ON <SEP> FALLSI.'.'GTON <SEP> SILT <SEP> LOX\: <SEP> SOIL <tb> <SEP> cnlocR, <tb> <SEP> SO2 <SEP> NM <SEP> cOMM <tb> <SEP> OCt3 <tb> <SEP> r <SEP> <tb> <SEP> o.ol <SEP> .1 <SEP> 0.03 <SEP> 1 <SEP> 0.12 <tb> <SEP> traLrls <SEP> -$ <tb> <SEP> 0 <SEP> I <SEP> 7G,3C <tb> 'I <SEP> '-'-r-:: <SEP> 7G <SEP> 5 <SEP> 9G,8C <SEP> G <SEP> 9C <tb> <SEP> 2G <SEP> 7G <SEP> 3H <SEP> ioc <SEP> lOC <tb> 5G <SEP> SG <SEP> t <SEP> 5G. <SEP> 3C <tb> <SEP> cscrtas <SEP> I <SEP> 3G <SEP> F <SEP> o <SEP> SGe <SEP> SH <SEP> 9G <SEP> SC <tb> <SEP> oa'li5;-ese <SEP> 2G <SEP> .2G <SEP> I <SEP> 3G <SEP> SG <SEP> SC <tb> <SEP> Giant <SEP> foxtal <SEP> 3G <SEP> 1 <SEP> 3G <SEP> ¯ <tb> <SEP> Kv. <SEP> blue-ras: <SEP> i <SEP> 7G <SEP> i <SEP> 7G,5EJ <SEP> 7G <SEP> SC <SEP> I <tb> <SEP> Cheatzrass <SEP> - <SEP> ; <SEP> 7G <SEP> I <SEP> OF <SEP> 7G <tb> <SEP> Suarbeets <SEP> EG <SEP> 1 <SEP> OC <SEP> 7 <SEP> 1 <SEP> ioc <SEP> loc <tb> <SEP> Corr. <SEP> O <SEP> 7G <SEP> I <SEP> 7G, <SEP> SR <tb> <SEP> custard <SEP> 8G <SEP> 7 <SEP> 7C <SEP> 9G <SEP> S <SEP> 8C <SEP> lOC <tb> <SEP> Cocklebur <SEP> 0 <SEP> ¯9 <SEP> I <SEP> 3G <SEP> 8 <tb> <SEP> pizveed <SEP> 3G <SEP> 10E <tb> <SEP> Nutsedge <SEP> O <SEP> O <SEP> 5G <tb> <SEP> Cotton <SEP> n <SEP> o <SEP> 7G, <SEP> 3H <SEP> 8G <SEP> a <tb> <SEP> 330tni <SEP> nnn <SEP> 1 <SEP> otv <SEP> 3G <SEP> i <SEP> 3G <SEP> 6G <SEP> oC <tb> <SEP> Cassia <SEP> 4 <SEP> 1 <SEP> tjG <SEP> 9¯G <SEP> , <SEP> 6 <SEP> C <SEP> 9 <SEP> - <SEP> . <SEP> Rr <tb> <SEP> Trac-ced <SEP> D <SEP> ..3G5¯G <SEP> 'ly, <SEP> C <tb> <SEP> Verves <SEP> 1 <SEP> eaf <SEP> n <SEP> )Cv <SEP> GG <SEP> QC <SEP> or <tb> <SEP> -' <SEP> o <SEP> w.ed <SEP> A <SEP> Q <SEP> tc: <SEP> 8C;. <SEP> 8C <SEP> mi <SEP> sr <SEP> a <tb> <SEP> Sovbean <SEP> n <SEP> m: <SEP> 7G <SEP> . <SEP> SH <SEP> or. <SEP> Rr <tb> <SEP> Rice <SEP> %y <SEP> 7 <SEP> 7G <SEP> . <SEP> RT; <SEP> 8G. <SEP> 7C <SEP> 1 <SEP> nr <tb> <SEP> Aeat <SEP> n <SEP> n <SEP> SG. <SEP> 3C¯ <SEP> rr <SEP> r <tb> <SEP> v <tb> Table B EMI189.1 <SEP> r <SEP> <tb> -PRE-EERGENCE <SEP> 0N <SEP> ALLSI'.;CTo'.- <SEP> SILT <SEP> LOAM <SEP> SOIL <tb> <SEP> CH <SEP> 20CX <SEP> ss <tb> <SEP> SOtnHCONH <tb> <SEP> cn <tb> <SEP> 0 <SEP> ,D <SEP> 3 <SEP> 0 <SEP> , <SEP> L2 <tb> <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> <tb> : <SEP> =ratrasf <SEP> 4C <SEP> -tp <SEP> r <tb> <SEP> ErrrrCta¯c <SEP> ¯ <SEP> ¯8G,5u <SEP> ¯¯1. <SEP> OC <tb> <SEP> SCr;TL' <SEP> 9t.9C <SEP> ¯ <SEP> 10E <tb> <SEP> llf <SEP> ra:e <SEP> 1 <SEP> 2r;. <SEP> Tt: <SEP> 9G, <SEP> 9C <tb> <SEP> g <SEP> s:r:.rasF <SEP> EG. <SEP> 4e <SEP> EG <SEP> .]C <tb> <SEP> "a1l <SEP> i <SEP> s <SEP> : <SEP> - <SEP> 2 <SEP> F <SEP> e <SEP> ) <SEP> G <SEP> , <SEP> . <SEP> . <SEP> 7G, <SEP> 7 <tb> <SEP> Giant <SEP> fcxraf! <SEP> 23 <SEP> G <tb> <SEP> Sv. <SEP> buc <SEP> ra:.c. <SEP> lC <tb> <SEP> Cheatrrass <SEP> 8G <SEP> 1OE <tb> <SEP> Sura-beet <SEP> s <SEP> 9G <tb> <SEP> frn <SEP> 1 <SEP> fjC, <SEP> Zy <SEP> ¯ <SEP> ¯¯eG,9C <tb> <SEP> .Y.usznrC <SEP> . <SEP> .10C <SEP> 14C <tb> <SEP> Cakrebur <SEP> 1 <SEP> 5C <SEP> 7C <tb> <SEP> Piguted¯¯ <SEP> ¯ <SEP> ¯i <SEP> 9G <SEP> .9 <SEP> OE <tb> <SEP> lf <SEP> scEe <SEP> I <SEP> 5G <SEP> ¯¯¯¯ <SEP> 56, <SEP> 9G <tb> <SEP> Ccttor: <SEP> 4t.32! <SEP> 8G <tb> <SEP> V;minPlorv <SEP> 3G <SEP> i <SEP> 7G <tb> <SEP> lla <SEP> Ls <SEP> ia <SEP> . <SEP> ;¯ <SEP> 9G. <SEP> 8C <tb> <SEP> fuet? <SEP> I <SEP> 5r <SEP> 7G. <SEP> 3C <tb> <SEP> v <SEP> ve <SEP> tleaf <SEP> Rr- <SEP> 5 <SEP> i <SEP> 9C. <SEP> 8r <tb> <SEP> i=saree <SEP> 61; <SEP> fG <tb> <SEP> j¯sCrtveecX <SEP> sC <SEP> 7G <SEP> ¯ <tb> <SEP> v <SEP> keaZ <SEP> 71: <SEP> a <tb> <SEP> Rice <SEP> 1 <SEP> nF <SEP> 1 <SEP> nr <tb> <SEP> MeaP <SEP> N <SEP> r <SEP> , <SEP> 7r. <SEP> vr <tb> <SEP> 1 <tb> <SEP> w <tb> <SEP> 4 <tb> Twenty-eight days after treatment, the plants .. were evaluated and visually rated for response to the chemical treatments utiliing the rating system described previously for Test A. The data are summarized in Table 8. Test B Two plastic bulb pans were filled with ferti lized and limed Fallsington silt loam soil. One pan was planted with corn, sorghum, Kentucky bluegrass and several grassy weeds. The other pan was planted with cotton, soybeans, purple nutsedge (Cyoerus rotundus), and several broadleaf weeds. The following grassy and broadleaf weeds were planted: crabgrass (Dioitaria sanouinalis), barnyardgrass (Echinochloa crusqualli) wild oats (Avena fatua), johnsongrass (Sorohum halepense), dallisgrass (Pasoalum dilatatum), giant fox tail (Setaria faberii), cheatgrass (Bromus secalinus), mustard (erassica arvensis), cocklebur (Xanthium pensylvanicum) , pigweed (Amaranthus retroflexus),* morningglory (Ioomoea hederacea), cassia (Cassia tora), teaweed (Sida soinosa), velvetleaf (Abutilon theophrasti), and jimsonweed (Oatura stramonium). A 12.5 cm diameter plastic pot was also filled with pre pared soil and plantedwith rice and wheat. Another 12.5 cm pot was planted with sugarbeets. The above four containers were treated pre-emergence with several test compounds within the scope of the invention. Table A (continued) EMI192.1 <tb> I <tb> <SEP> NON <tb> <SEP> z <tb> <SEP> z <tb> <SEP> z <tb> 1 <tb> <SEP> =e <tb> <SEP> w <SEP> w <tb> <SEP> kn'ha <SEP> 0.1 <tb> <SEP> POST <SEP> RGB'CE <tb> <SEP> ':SH <SEP> 3:; <SEP> 8D, <SEP> G <SEP> . <SEP> 6Y <SEP> ' <SEP> 1111111 <tb> <SEP> C3TTOX <SEP> 5C.9G <tb> <SEP> MO-FIXG <SEP> CLOY" <SEP> 6C <SEP> 9G <tb> <SEP> COC};L'3';-t <SEP> . <SEP> 7 <SEP> 4C <SEP> . <SEP> 9G <tb> <SEP> CASS <SEP> L <SEP> 2C, <SEP> 7G <tb> <SEP> !f <SEP> TSEN-E <SEP> 5G <tb> <SEP> CRA3GRA±S <SEP> 1C <tb> <SEP> Wx <SEP> GUYS <SEP> 2C, <SEP> 9H <tb> <SEP> WILD <SEP> OATS <SEP> tR;SS <SEP> S <SEP> 2 <SEP> C <tb> <SEP> C <tb> <SEP> CORE' <SEP> ¯ <SEP> C, <SEP> H <tb> <SEP> SOYBEi <SEP> C, <SEP> G <tb> <SEP> RICE <SEP> C, <tb> <SEP> S0RG"'-. <tb> <SEP> PRL <SEP> RGENCE <tb> <SEP> .TOXIN" <SEP> GLORY <SEP> 2C <SEP> 9G <tb> <SEP> COCKLE3UR <SEP> i <SEP> 2C <SEP> SR <tb> <SEP> CASSIA <SEP> 1 <SEP> 2C,3R <tb> <SEP> N'L:TSEDCE <SEP> 4G <tb> <SEP> CA3CRASS <SEP> C <tb> <SEP> BrtRSTARD <SEP> GRASS <SEP> C,3G <tb> <SEP> It;fLD <SEP> OATS <tb> <SEP> W?EAT <tb> <SEP> CORDi <SEP> 7 <tb> <SEP> sO <SEP> g <SEP> Hc <SEP> w <SEP> 7H <tb> <SEP> fisCE <SEP> bC <SEP> 9G <tb> , <SEP> CORGEr. <SEP> , <SEP> , <tb> Table A (continued) EMI193.1 <tb> <SEP> (0) <SEP> (0) <tb> <SEP> 1 <SEP> tno <SEP> cno <tb> <SEP> S <SEP> Q <SEP> NN <tb> <SEP> z <SEP> sH <SEP> z <tb> <SEP> 0 <SEP> 0 <tb> z <tb> <SEP> kg!ha <SEP> 0.4 <SEP> 0.1 <tb> / <SEP> PCSf-EtSStE <tb> <SEP> BUS)7: <SEP> BEh' <SEP> I-rv <SEP> 3C,86,6Y <tb> ; <SEP> CO'fTO <SEP> 9C,5G <tb> <SEP> nT1;IStCLOR't' <SEP> h <SEP> 6e,96 <tb> <SEP> COCLT3L <SEP> 4r,9G <tb> <SEP> CASIIrSEi----1 <SEP> ZC,3G <tb> <SEP> LTfSE3ZE <SEP> r96---I <SEP> 4G <tb> <SEP> CRBjitSS <SEP> i--T9 <tb> <SEP> Birl'AL=iUSS <SEP> I <SEP> ,, <SEP> ! <SEP> 9H <tb> <SEP> L'ILD <SEP> O;ITS <tb> <SEP> I <SEP> 1C <tb> <SEP> ¯ <SEP> LLIT <SEP> I <tb> <SEP> COL <SEP> a <SEP> c <tb> <SEP> SCIjTcLi <SEP> I <SEP> 2C,9G <tb> <SEP> RICE <SEP> ) <SEP> 9C <tb> <SEP> SORtIi'LY. <SEP> ,7H <SEP> I <SEP> 3C,9G <tb> <SEP> PR-rxcn-cr <SEP> -? <tb> <SEP> I <tb> <SEP> nO'ifl:SfLORT <SEP> ' <SEP> I <SEP> sc: <SEP> se <tb> I <SEP> ? <SEP> I <tb> <SEP> COCLfR <SEP> 9H <SEP> 2C <SEP> <tb> i <SEP> CASIA <SEP> I <SEP> 9G <SEP> 3C <SEP> i <tb> i <SEP> NCTSEDC't <SEP> i <SEP> 3G <tb> <SEP> CABCiUSS <SEP> j <SEP> ZC, <SEP> 7G <SEP> 1C <tb> <SEP> BEWAFCASS <SEP> i <SEP> ZC,9 <SEP> f! <SEP> IC <tb> <SEP> ulLD <SEP> ATS <SEP> 2C,6C <SEP> 0 <tb> <SEP> 70 <tb> 1 <tb> <SEP> SORGt'.' <SEP> 1C,9 <SEP> C1 <tb> Table A (continued) EMI194.1 l <SEP> <tb> <SEP> R <SEP> Q <SEP> o <SEP> R <tb> <SEP> c <SEP> = <SEP> c <SEP> = <tb> :: <SEP> sz <SEP> rin <tb> <SEP> C: <SEP> C. <tb> Z <SEP> 2 <SEP> z <SEP> e <tb> <SEP> * <SEP> sums <tb> <SEP> - <SEP> 2 <tb> <SEP> 6; <tb> <SEP> 6; <SEP> 6; <tb> <SEP> 0.1 <SEP> '|'s <SEP> O. <SEP> ì, <SEP> O.1 <SEP> 0.4 <tb> <SEP> * <SEP> . <SEP> <tb> <SEP> BTSii <SEP> '.'.. <SEP> e <SEP> 1 <tb> <SEP> ,YtL <SEP> SC,9, <SEP> f <SEP> 1D¯G, <SEP> Sf! <tb> <SEP> 1e,3., <SEP> 4f' <SEP> ec <tb> <SEP> :tl:=;fLtj <SEP> ! <SEP> rOG,7C <SEP> DC <tb> <SEP> 3C,¯9 <SEP> 1Cf <SEP> sC <tb> <SEP> CIE=.r. <SEP> r <SEP> 4u <SEP> s= <tb> <SEP> i <SEP> 3r <SEP> r <SEP> G <tb> <SEP> CSST,t.f <tb> <SEP> C <SEP> r <SEP> 3 <tb> <SEP> 2C,9H <SEP> 7G,5" <SEP> V <tb> <SEP> 9C <SEP> lOG,9C <tb> <SEP> lC,SG <SEP> 9C <SEP> 1 <SEP> SG,3C <tb> <SEP> C, <SEP> 7C <tb> <SEP> S <SEP> p <SEP> Po; <tb> <SEP> 1 <SEP> ti; <SEP> VC <SEP> I <SEP> -6t <tb> <SEP> O..' <SEP> Vz.p <SEP> sr. <tb> <SEP> CAcTli. <SEP> 1 <SEP> BG <SEP> ¯ <SEP> G <SEP> -1 <tb> <SEP> ?* <SEP> Ju¯ <SEP> 1DE <SEP> bG <SEP> 3y <SEP> <tb> <SEP> Citt,ft <SEP> 5C <SEP> J <SEP> 4 <SEP> 5C <SEP> I <tb> <SEP> ..:AZASS <SEP> 2C, <SEP> 8 <SEP> Cr <SEP> 8r <tb> <SEP> &commat; <SEP> - <SEP> <tb> <SEP> 7G <SEP> O1'TS <SEP> (7G <SEP> 6C <tb> <SEP> , <SEP> COFE <SEP> .5G,Z <tb> <SEP> SOl <SEP> ; <SEP> ¯ <SEP> 6 <SEP> c; <SEP> 7 <SEP> 3rr <SEP> o¯ <SEP> ¯ <SEP> ¯ <tb> <SEP> RICE <SEP> IGE <SEP> -'' <SEP> 7G <SEP> 4 <tb> <SEP> 1C,-9GI <SEP> II <tb> Table A (continued) EMI195.1 <tb> <SEP> I <tb> <SEP> Q: <SEP> X <SEP> o-R <tb> o <SEP> r <SEP> I <SEP> u. <SEP> r! <SEP> C <tb> C <SEP> c <tb> <SEP> 5 <SEP> | <SEP> c <SEP> c' <tb> <SEP> = <SEP> Th0=. <tb> <SEP> Mo <tb> <SEP> ¯ <SEP> n <SEP> - <SEP> ± <SEP> n <tb> <SEP> r. <tb> <SEP> 0.4 <SEP> C).4 <SEP> 1 <SEP> 4 <SEP> O <SEP> .4 <SEP> | <SEP> 0.4 <tb> <SEP> T=fI3T <tb> <SEP> BUSH <SEP> BEAN <SEP> ¯ <SEP> 9 > . <SEP> 6u. <SEP> f <SEP> 9C <SEP> 7C <tb> <SEP> 5t3 <SEP> 9m <SEP> f <SEP> 9 <SEP> -s <SEP> 9 <tb> <SEP> <SEP> lQC <SEP> !, <SEP> loc <SEP> lOC <tb> <SEP> C-. <SEP> -.?r-I:::r <SEP> 9- <SEP> 'a <tb> <SEP> f.r.3=r <SEP> i <SEP> 9t <SEP> 1 <SEP> 9 <SEP> 1C <tb> <SEP> S,f2:T <SEP> tC,46 <SEP> I¯ <SEP> 9C <SEP> CI <tb> <SEP> C'tr. <SEP> 5 <SEP> r,z.5I <SEP> I <SEP> Itt <SEP> 0 <tb> <SEP> .LSiL; <SEP> I <SEP> L7 <SEP> I <tb> <SEP> 8t <SEP> - <SEP> 3C. <SEP> 6i. <SEP> 0 <tb> <SEP> 0 <tb> <SEP> Ct <SEP> 3E'.9C <SEP> 5s¯ <SEP> , <SEP> ¯ <SEP> 2C,3r. <tb> <SEP> LLlr <tb> <SEP> 5C,9G <SEP> se <SEP> 7C <tb> <SEP> vru <SEP> Ct <tb> <SEP> I-S3kV <SEP> C <SEP> 10C <SEP> ZL' <tb> <SEP> PI-CE;;=I <tb> <SEP> rS?::SSLO <SEP> 9S <SEP> 9f. <tb> <SEP> L <SEP> CO-}.5 <SEP> ri.',. <SEP> 9G <SEP> , <SEP> , <SEP> 9H <SEP> 6G, <SEP> fC <tb> <SEP> CO=LS'-'T. <SEP> 9G <SEP> 9H <SEP> 6C,5C <tb> <SEP> CA5EI <SEP> 9G <SEP> 1 <SEP> 4t,9C- <SEP> 5C <SEP> I <tb> <SEP> FfSST <SEP> 9G <SEP> 1OV <SEP> O <tb> <SEP> CTe <SEP> S;F,i <SEP> S <SEP> 8C <SEP> 3;,7G <SEP> 0 <tb> <SEP> TtAU;IUSS <SEP> 5C,9h' <SEP> i <SEP> jC <SEP> ,9H <SEP> 3 <SEP> i <tb> <SEP> ILD <SEP> OfS <SEP> 3,9C <SEP> i <SEP> 2C,9G <SEP> 1 <SEP> 0 <tb> <SEP> rF,x <SEP> 9G <SEP> i <SEP> 2C,9G <SEP> 0 <SEP> 1 <tb> <SEP> tOR\; <SEP> 9G <SEP> 9i <SEP> I <SEP> 3C <tb> <SEP> -SOY]iO <SEP> 5E, <SEP> < 9n <SEP> ¯¯ <SEP> 2C <tb> <SEP> ZC <tb> <SEP> SC, <SEP> 9h <SEP> T <SEP> 10 <SEP> -- <SEP> 4G <SEP> G <tb> Table A (continued) EMI196.1 <tb> <SEP> CH,OH <tb> <SEP> 0:MR <tb> <SEP> N <tb> <SEP> S02NBC} <SEP> -I <SEP> 0, < <tb> <SEP> 4 <SEP> ,OCa3 <tb> <SEP> 3 <tb> <SEP> kg/ha <SEP> O <SEP> 05 <tb> I <SEP> 005 <tb> <SEP> P0ST-E"EGtCE <tb> I <SEP> BaSHBIIS <tb> I¯COTfO\" <SEP> .2CI <SEP> 7¯G. <SEP> 6Y <tb> <SEP> MORNINGZORY <SEP> 1C <tb> <SEP> ORfGCLOXI <SEP> 1C <tb> <SEP> COCKLEBR <SEP> a <tb> <SEP> XLTSEDGE <SEP> ¯O <SEP> o <tb> <SEP> C,RABGRASS <SEP> 2G <tb> <SEP> BARTARDGRASS <SEP> O <tb> <SEP> WILD <SEP> OATS <SEP> O <tb> <SEP> 'iLAT <SEP> O <tb> <SEP> , <SEP> CORaN <tb> <SEP> SON'B2N <SEP> 1C, <SEP> 6H <tb> <SEP> RICE <SEP> - <SEP> - <SEP> - <SEP> 1C, <SEP> 4G <SEP> - <SEP> '' <tb> <SEP> SORGHU!d <SEP> 2C, <SEP> 9H <tb> <SEP> PRE <SEP> ERG=CE <tb> <SEP> MORXI'.lGGLORY <SEP> 2 <SEP> C <tb> <SEP> COCXLEBUR <SEP> O <SEP> ¯ <tb> <SEP> CtSSIA <SEP> 1C <SEP> - <SEP> <tb> <SEP> SUTS <SEP> ±DGE <SEP> ¯ <SEP> O <SEP> ¯ <SEP> . <SEP> ¯ <tb> <SEP> C2ABGRASS <SEP> O <tb> <SEP> BARNARDGVSS <SEP> 2C, <SEP> 7H <SEP> ¯ <SEP> ¯ <tb> <SEP> WID <SEP> OATS <SEP> O <tb> <SEP> WHEAI <SEP> O <tb> <SEP> CORS <SEP> 9H <SEP> - <SEP> ' <SEP> -- <SEP> <tb> <SEP> SOYB > X <SEP> --- <SEP> 2C, <SEP> 3H <tb> <SEP> RICE <SEP> 1C <tb> <SEP> SORZ^i <tb> Table A (continued) EMI197.1 <tb> <SEP> I <tb> <SEP> v <tb> <SEP> CR2OH <tb> <SEP> OCR <tb> <SEP> 0 <SEP> N <tb> <SEP> S02NHC5H <SEP> 04 <tb> <SEP> OwH3 <tb> <SEP> kg/ha <SEP> O. <SEP> Q5 <tb> <SEP> POST-aERb <SEP> E <tb> <SEP> BUSH <SEP> BEY.' <SEP> SC, <SEP> CD, <SEP> Y <tb> <SEP> COTTOT <SEP> r <SEP> 4H, <SEP> 8G <tb> <SEP> MORfC;CLORY <SEP> 2G <tb> <SEP> tCICLEB'iR <SEP> 5C, <SEP> 9G <tb> <SEP> CASSIA <SEP> 5C <SEP> 9G <tb> <SEP> hTSEDGf <SEP> 1C:r <SEP> 9G <tb> <SEP> NUTSDGE <SEP> 1C, <SEP> 9G <tb> <SEP> CRABGRASS <SEP> 3G <SEP> --¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯ <tb> <SEP> BALWGPASS <SEP> 3C, <SEP> 9H <tb> <SEP> ilzD <SEP> OATS <tb> <SEP> ¯ <SEP> k?i'LAT <SEP> O <tb> <SEP> CORN' <SEP> -'' <SEP> C, <SEP> H <tb> <SEP> SOiBW <SEP> 9c <tb> <SEP> RICE <tb> <SEP> SORGHEw <SEP> iC, <SEP> 9 <tb> <SEP> PRE-ERCn'CE <tb> <SEP> PRE-BERG='CE <tb> <SEP> MOtNI: :GGLQRX <SEP> ¯ <SEP> SG <tb> <SEP> COCKLE8UR <SEP> ' <SEP> 9H <tb> <SEP> CASSIA <SEP> 1C, <SEP> 8G <tb> <SEP> Bt'TSEDGE <SEP> 10E <tb> <SEP> CRABCRASS <SEP> C <tb> F <SEP> BARAARDGSS <SEP> 2C, <SEP> H <tb> r2ILD <SEP> OATS <SEP> 8 & <tb> <SEP> - <SEP> 6 & <SEP> o <tb> <SEP> CORN <SEP> 1C, <SEP> H <tb> <SEP> SOYBEAN <SEP> 2C, <SEP> 8 <SEP> H <tb> <SEP> RICE <SEP> 1 <SEP> OE <SEP> '' <SEP> - <SEP> <tb> CH"'.4 <SEP> C <SEP> G <tb> Table A (continued) EMI198.1 <tb> <SEP> T0: <tb> <SEP> XsSt <tb> <SEP> 0 <tb> <SEP> 2N <SEP> F! <SEP> N <tb> ks <SEP> 0.05 <SEP> O <SEP> O;OUZOS <tb> PCSSlfEStf <tb> PC;-- <SEP> w¯NiE <tb> <SEP> L <SEP> 9D <SEP> 9G <SEP> 6Y <SEP> 1 <SEP> 3C <SEP> 9G <SEP> 6Y <tb> <SEP> .; <SEP> 2C, <SEP> 3H <SEP> I <SEP> 0 <tb> <SEP> w <SEP> ;0RE- <SEP> 6B,5G <SEP> lOc <tb> <SEP> 3C <SEP> 9G <SEP> I <SEP> iC <SEP> 2G <tb> <SEP> -Co <SEP> . <SEP> 2C <SEP> C <tb> <SEP> X-::S-D <SEP> -¯ <SEP> 1C, <SEP> 9G <SEP> I <tb> <SEP> 2C,5G <SEP> 2C, <SEP> 5G <SEP> I <SEP> 0 <tb> <SEP> A3i <SEP> sir <SEP> 0 <tb> <SEP> \ <SEP> ! <SEP> O^¯ ' <SEP> H <SEP> I <tb> <SEP> G <SEP> ZC, <SEP> 0 <tb> <SEP> 503; <SEP> 9C <tb> <SEP> RC't <SEP> rC <SEP> a <tb> <SEP> SbR;E <SEP> 9G <SEP> IG <tb> PRf-ERCEfT <SEP> i <SEP> <tb> <SEP> o <tb> PRE-a.VRG=CE <tb> <SEP> MOtS <SEP> GGLOR' <SEP> 8G <SEP> qG <SEP> ¯ <tb> <SEP> OCKLEB:R <SEP> = <SEP> qG <SEP> .. <tb> <SEP> CASIA <SEP> ¯ZC, <SEP> 8G <SEP> 1C <SEP> i <tb> <SEP> h'lEICf <SEP> 8G <SEP> 0 <SEP> I <tb> <SEP> CT9BSRASS <SEP> 2C,5C <SEP> 0 <tb> <SEP> BARTARD¯GRASS <SEP> tC, <SEP> 8H <SEP> ¯ <SEP> IC <SEP> i <SEP> 3 <SEP> I <tb> <SEP> VtJ, <SEP> OAfS <SEP> "" <SEP> 6G <SEP> 0 <SEP> I <tb> <SEP> LL, <tb> <SEP> YHXT <SEP> 1C,3G <SEP> o <tb> <SEP> SOYBEAN <SEP> 9R <SEP> 2H <tb> <SEP> RICE <SEP> SC <SEP> 9H <SEP> 1C,4G <tb> 9G <SEP> - <SEP> 9G <SEP> ,¯ <SEP> ¯3C <SEP> H <tb> Table A (continued) EMI199.1 <tb> <SEP> - <SEP> - <SEP> 0 <tb> <SEP> tir <SEP> fÏ-; <SEP> ss <tb> <SEP> - <SEP> -'-' <SEP> C <SEP> - <SEP> C. <tb> <SEP> N <SEP> - <SEP> ti <tb> <SEP> C: <SEP> : <SEP> 0: <tb> <SEP> - <SEP> N <SEP> - <SEP> <tb> <SEP> o <SEP> o <SEP> 2c <tb> <SEP> 'a <tb> <SEP> 0 <SEP> 01 <SEP> 1 <tb> <SEP> n <tb> <SEP> k-L1hS <SEP> 0.05 <SEP> 0.05 <SEP> o <SEP> 45 <tb> <SEP> 2SI-r1SfrStr <tb> <SEP> 5S <SEP> 9G <SEP> 6Y <SEP> I <SEP> C <SEP> 4S <SEP> 9G <SEP> 6Y <tb> <SEP> 2C,5G <SEP> 4G <SEP> 1 <SEP> 3C <SEP> 4S, <SEP> 9G, <SEP> 3H <tb> <SEP> w <SEP> OR" <SEP> lC,7G <SEP> 2C, <SEP> G <SEP> 4C,9G <tb> <SEP> I'V <tb> <SEP> 3G, <SEP> -- <SEP> 6 <tb> <SEP> fftS=.t. <SEP> 3C <tb> <SEP> fSEf-T <SEP> O <SEP> 1C,BG <SEP> : <SEP> C,8S <tb> <SEP> ti3fSsS <SEP> o <SEP> 2G <SEP> 7G <tb> <SEP> BL11 <SEP> Pc;JIS <SEP> 5 <SEP> 0 <SEP> 7H <SEP> gH <tb> <SEP> cLT <SEP> 0,5 <SEP> 9 <SEP> 0 <SEP> C,4C <tb> <SEP> Lt.T <SEP> O <SEP> 9 <SEP> ZG <tb> <SEP> 5C:5=; <SEP> 1C, <SEP> 9G <SEP> 1C, <SEP> UG <SEP> r <tb> <SEP> RICE <SEP> <tb> <SEP> SORC'clS, <SEP> ORGw:.. <tb> <SEP> 1 <tb> <SEP> PR¯-2rfiGEN'CE <tb> <SEP> Y.ORN <SEP> LORE' <SEP> 8G <SEP> I--- <SEP> S <tb> <SEP> OC <SEP> LEX';fi <SEP> , <SEP> 9H <SEP> 9H <SEP> - <SEP> < <tb> <SEP> CASilA <SEP> 1C <SEP> O <SEP> m <tb> <SEP> N-; <SEP> . <SEP> SEDGt <SEP> <SEP> 5G <SEP> 9 <SEP> G <tb> <SEP> BAP:IACCKSS <SEP> 1C <SEP> ¯ <SEP> 3C, <SEP> 6G <SEP> 1C, <SEP> 9H <tb> <SEP> 'ILD <SEP> OATS <SEP> ¯ <SEP> O <SEP> 1C, <SEP> SG <SEP> 8G <SEP> ''-' <tb> <SEP> ç <SEP> O <SEP> 3G <SEP> ¯ <SEP> 8G <tb> <SEP> COR:; <SEP> lC, <SEP> 3G <SEP> 2C,6 <SEP> G <SEP> g <SEP> ¯ <SEP> ¯ <tb> <SEP> SO] <SEP> 3G <SEP> 1C, <SEP> 1H <SEP> 9H <tb> <SEP> RICE <SEP> 2C <SEP> ¯ <SEP> 3C, <SEP> 7G <SEP> - <SEP> 4C <SEP> . <SEP> 9H <tb> miL <SEP> 2C, <SEP> 8G <SEP> ¯ <SEP> 1C, <SEP> 8G <SEP> 2C, <SEP> 9H <tb> Table A (continued) EMI200.1 <tb> <SEP> ci <SEP> o <SEP> O <SEP> C <SEP> I <tb> <SEP> -," <tb> <SEP> --N <SEP> - <SEP> - <SEP> - <SEP> - <SEP> - <SEP> <tb> <SEP> - <SEP> 0 <SEP> 0 <SEP> <SEP> o <SEP> ;n <tb> <SEP> ooft·00 <tb> <SEP> .05 <SEP> .05 <SEP> .05. <tb> <SEP> ?:T <SEP> I-- <SEP> -- <tb> ¯51 <SEP> ¯- <SEP> ¯ <SEP> ¯ <SEP> , <SEP> 6., <SEP> 9G <SEP> . <SEP> Sy <SEP> 7C, <SEP> 4C. <SEP> . <SEP> 6y <SEP> 2C <SEP> . <SEP> 5G, <SEP> 6Y <SEP> ¯ <tb> <SEP> Blf <SEP> ES <SEP> rt'' <SEP> 1 <SEP> 6S.9G.F;Y, <SEP> 2.9r,..6Y <SEP> 1 <SEP> ZC,5G,6Y¯ <SEP> ¯ <tb> <SEP> e <SEP> : <SEP> i <SEP> .7G <SEP> TCSG <SEP> 1C,1H <tb> <SEP> i3SI.u3fOK1' <SEP> i <SEP> 2C <SEP> 6C <SEP> 1C. <SEP> fG <SEP> 2C19G <tb> <SEP> COSbLTE <SEP> 3C.9H <SEP> 1C, <SEP> 9G, <SEP> ZC,SC <tb> <SEP> CAcFl.t. <SEP> i <SEP> 2C.5G <SEP> 3C, <SEP> 3¯G <SEP> IC <tb> <SEP> X,,STL-E <SEP> 1 <SEP> 4G <SEP> I <SEP> 1C,7G <SEP> 0 <tb> <SEP> Ci;StiE <SEP> . <SEP> r¯8F <SEP> I <SEP> 1,.5G <SEP> 0 <tb> <SEP> :-9-ES <SEP> Z:2t <SEP> ,9H <SEP> 0 <tb> <SEP> I <SEP> OASS <SEP> 2G <SEP> ¯ <SEP> ¯i¯0¯ <tb> <SEP> 1G'0 <SEP> 0 <tb> <SEP> Cr; <SEP> 1U,9G <SEP> 3P <SEP> r <SEP> -C,eH <tb> <SEP> --I- <SEP> leL <tb> <SEP> 3C,9G¯ <SEP> ¯ <SEP> C <SEP> 2C,8G <tb> <SEP> RZC <SEP> ] <SEP> BG <SEP> 12C18G <tb> <SEP> SORB;11 <SEP> 3C,9H <SEP> i <SEP> 3C,9G <SEP> LIU <tb> <SEP> PRt <SEP> RG5Ct <SEP> .. <tb> <SEP> PR¯f-ET,ERGEtf3 <SEP> IH.7G <tb> <SEP> noRE.;L¯o¯ <SEP> .Ic <tb> <SEP> CSICI <SEP> .9W <SEP> SI1 <tb> <SEP> 2C. <SEP> 6G <SEP> 2C, <SEP> 3G <tb> <SEP> ht'fSEC¯ <SEP> 1C, <SEP> IG <SEP> 9-G <SEP> - <tb> <SEP> cRscr44ss <SEP> ¯rc, <SEP> SG <SEP> ¯1C: <SEP> O <tb> <SEP> BAiCYCD¯GA¯ZS¯ <SEP> 2C, <SEP> gH <SEP> 3C, <SEP> 9H <SEP> IC,IG <SEP> i <tb> <SEP> u'fLD <SEP> OAfS <SEP> 2C¯, <SEP> 8G¯ <SEP> 2C,7G <SEP> 0 <tb> <SEP> YHLAT <SEP> 1C,8G <SEP> SG <SEP> O <tb> <SEP> tOiC; <SEP> 2C,9G <SEP> 2¯t,7G <tb> <SEP> SOY3tAN <SEP> 9H <SEP> SG <SEP> ic <tb> <SEP> R1CE <SEP> 4C,9H <SEP> 2C <tb> <SEP> t <SEP> &num; <tb> H <SEP> 2 <tb> Table A (continued) EMI201.1 <tb> <SEP> p' <SEP> -"'-p' <tb> <SEP> - <SEP> p' <tb> <SEP> 7 <SEP> f <tb> <SEP> -p' <SEP> o <tb> <SEP> 0 <tb> <SEP> 0 <SEP> "' <SEP> U <SEP> p' <SEP> 0 <tb> <SEP> -S <SEP> iU <SEP> 6 <SEP> Ï <tb> <SEP> -N <SEP> E <SEP> 0 <SEP> : <tb> <SEP> a <SEP> 0-' <SEP> 0',' <SEP> N <tb> <SEP> C <tb> <SEP> % <SEP> % <SEP> -¯ <tb> <SEP> ,h <SEP> V1 <tb> <SEP> .05 <SEP> .05 <SEP> .05 <tb> i <SEP> F <tb> L <SEP> p=5f-P:I'rtLi=f <SEP> i <tb> <SEP> BUSH <SEP> BE;.; <SEP> '-' <SEP> - <SEP> 9C <SEP> 9C <SEP> re- <SEP> sc <SEP> -- <SEP> 0 <tb> <SEP> COTTO'.: <SEP> 9C <SEP> 1 <SEP> 9C <SEP> C, <SEP> H <tb> <SEP> lOC <SEP> ORï <SEP> l <SEP> or <SEP> 1 <SEP> 9C <SEP> C, <tb> <SEP> 9C <SEP> - <SEP> 9C <SEP> ' <SEP> 9C <SEP> C, <SEP> F <tb> <SEP> SC,9G <SEP> 5C,9G <tb> <SEP> N <SEP> 5¯¯&commat;.- <SEP> 2C, <SEP> 8G <SEP> 2C, <SEP> 8G, <SEP> 5N <SEP> 1C, <SEP> -¯¯ <tb> <SEP> lC <SEP> BC <SEP> ACv <SEP> 1C, <SEP> 2G <SEP> 1C <tb> <SEP> 3c,9}3 <SEP> lC,3G <SEP> , <SEP> xl <tb> <SEP> i'12 <SEP> 0- <SEP> ' <SEP> 4G <SEP> ou <tb> <SEP> 0 <SEP> O <SEP> o <tb> Co: <SEP> U, <SEP> 5U,SG <SEP> - <SEP> 2C,9 <tb> <SEP> s0:3=w: <SEP> 4C. <SEP> it, <SEP> , <tb> <SEP> 51cr <SEP> 6G <SEP> ¯11111 <tb> <SEP> 501U <SEP> HZ <SEP> 2U <SEP> . <SEP> 9G <SEP> 1 <SEP> C <SEP> . <SEP> 7G <SEP> 2C, <SEP> 9G <tb> <SEP> nOhi'l!:CtLOR'i <SEP> se <SEP> 9G <SEP> 0 <tb> --nrtrB"R <SEP> 9H <SEP> 9H0 <tb> <SEP> cssrA <SEP> 3C,9G <SEP> i <SEP> 2C,9G <SEP> IC <tb> <SEP> )n'fSEZ)Cf <SEP> 6G <SEP> se <SEP> o <tb> <SEP> CRABCiUSS <SEP> 1C <SEP> 1CG <SEP> IC <tb> <SEP> BAR4iARDCASS <SEP> 2C, <SEP> 8H <SEP> Cr <SEP> 8H <SEP> 1C,5G <tb> <SEP> Yfll) <SEP> OATS <SEP> 5C <SEP> i <SEP> IC,c; <SEP> -C17G <tb> -mLir <SEP> ZG <SEP> 7 <SEP> o <SEP> G <tb> - <SEP> tOR <SEP> 9G <SEP> 7 <SEP> ZC,P <SEP> H.7G <tb> <SEP> CORS <SEP> - <SEP> - <SEP> 9G <SEP> ZC,9E <SEP> SC, <SEP> 7G <SEP> -- <tb> <SEP> SOYBEAN <tb> <SEP> SH <SEP> 8H <SEP> 6G <tb> <SEP> 9G <SEP> 2C <SEP> . <SEP> 9G <SEP> 2C. <SEP> 8G <tb> Table A (continued) EMI202.1 <tb> <SEP> ,C" <SEP> o <SEP> n <tb> <SEP> a" <SEP> 8^Ï <tb> <SEP> "I <tb> <SEP> -a" <tb> <SEP> 0 <SEP> a" <SEP> 0 <SEP> 0 <tb> ON"' <SEP> tÏ <SEP> U <tb> <SEP> N <SEP> <tb> <SEP> C-NA? <tb> <SEP> kg'h± <SEP> .05 <SEP> .05 <SEP> .05 <tb> <SEP> BE <SEP> hz <SEP> .05 <SEP> .05 <SEP> ,05 <tb> <SEP> PCS-9 <SEP> E <tb> <SEP> HUSH <SEP> mS <SEP> 9C <SEP> gC <SEP> 9C9c <tb> <SEP> COTTO.': <SEP> 6C <SEP> . <SEP> 9G <SEP> 9C <SEP> 6C <SEP> 9G <tb> <SEP> Yv <SEP> 3C,7G <SEP> 3C <SEP> 7G <SEP> SC, <SEP> 9G <tb> <SEP> CQGE;:rx <SEP> R <SEP> so <SEP> 9C <SEP> / <SEP> 9C <tb> <SEP> CoSS.A <SEP> 3C <SEP> 9G <SEP> C. <SEP> G <SEP> 2C, <SEP> 9G <tb> <SEP> W:-..sEnC.. <SEP> 9C <SEP> YC <SEP> 9C <tb> <SEP> CRA3G.tiSS <SEP> . <SEP> 2C <SEP> 5G <SEP> C, <SEP> G <SEP> 1C, <SEP> 3G <tb> <SEP> Bkc3CrES <SEP> ! <SEP> 6C,9H <SEP> -9C <SEP> 4C,9fi <tb> <SEP> flD <SEP> OI;S <SEP> i <SEP> 9H <SEP> ZCISG <SEP> 0 <tb> <SEP> 1 <SEP> 2C,9G <SEP> ZC,4G <SEP> - <SEP> 0 <tb> <SEP> COIi'; <SEP> 3C,9G <SEP> 5U,9G <SEP> -i <SEP> 2U <SEP> 9G <tb> <SEP> 5OYBZA: <SEP> 2C,9G,5X <SEP> purse <SEP> I <SEP> 4C,9G <tb> <SEP> RICE <SEP> I <SEP> 3C,9G <SEP> 4 <SEP> a <SEP> C,9G <tb> <SEP> SORCR <SEP> U, <SEP> 9G <SEP> is, <SEP> 9G <SEP> 1V, <SEP> G <tb> <SEP> PRE-ZXERGEN <SEP> CE <tb> <SEP> MOP;I'.JGG7 <SEP> ORE' <SEP> g <SEP> G <SEP> 9 <SEP> G <SEP> 9 <SEP> G <SEP> <tb> <SEP> OC):LEBVR <SEP> 9H <tb> <SEP> CASSIA <SEP> 7 <SEP> . <SEP> 9G <SEP> 2C, <SEP> 9G <SEP> 2C, <SEP> 9G <tb> <SEP> Nt'TSDGE <SEP> lOE <SEP> lOE <SEP> lOE <tb> <SEP> CRA3GRASS <SEP> 1C. <SEP> 4G <SEP> 2C <SEP> . <SEP> 6G <SEP> 2C <SEP> . <SEP> 6G <tb> <SEP> BAP.ARDGRASS <SEP> ¯2C, <SEP> 2 <SEP> ¯6Cs <SEP> ¯C.9X <SEP> Ii <tb> <SEP> SOYBEAN <SEP> 2C,3G <SEP> 9H <SEP> 9H <tb> <SEP> 03EAT <SEP> 9G <SEP> 2C <SEP> . <SEP> 9G <SEP> 2C <SEP> . <SEP> 7G <tb> <SEP> CORX <SEP> 1C <SEP> . <SEP> 9G <SEP> 9H <SEP> 2U, <SEP> 9G <tb> <SEP> SOYBzN <SEP> 2C, <SEP> 3G <SEP> 9H <SEP> 9H <tb> <SEP> RICE <SEP> 2C <SEP> 10E <SEP> 9H <SEP> 4C,9H <tb> <SEP> SOR!;} <SEP> .' <SEP> SC <SEP> G <SEP> 9G <SEP> 3C <SEP> . <SEP> OH <SEP> 2C <SEP> 9G <tb> Table A (continued) EMI203.1 <tb> <SEP> p" <SEP> p" <SEP> p" <SEP> p" <tb> <SEP> 8: <SEP> " <tb> <SEP> C <SEP> p"o <SEP> C <tb> <SEP> p" <SEP> U: <tb> <SEP> a <SEP> N <SEP> : <SEP> ON <SEP> EN <tb> <SEP> a.o <tb> ks <SEP> 'ha <SEP> 0.4 <SEP> 0.35 <SEP> .05 <tb> <SEP> POS <SEP> . <SEP> -a.--AvS <SEP> E <tb> ¯i3CSri <SEP> ¯Qr; <SEP> 95.9G.4Y <SEP> 3C,7G,6Y <SEP> 2C <SEP> . <SEP> EG, <SEP> SY <tb> <SEP> CCTO': <SEP> lt.2G <SEP> 0 <SEP> 2C <tb> <SEP> 3f <SEP> SSGiOS' <SEP> fC <SEP> 4G <SEP> r <SEP> tt <SEP> 3G <SEP> ¯ <tb> <SEP> 0 <SEP> 4G <SEP> 4 <tb> <SEP> CASZ; <SEP> O <SEP> 0 <SEP> 9 <tb> <SEP> rcTSE3ST <SEP> O <SEP> rO <SEP> 0 <tb> <SEP> CR5tSS <SEP> 0 <SEP> i <SEP> 3G <SEP> I <SEP> D <tb> <SEP> BATiG'iSf <tb> <SEP> IC.ZH <SEP> 1¯H <SEP> 0 <tb> <SEP> L <SEP> 07i <SEP> ¯ <SEP> O <SEP> i <SEP> O <SEP> j <SEP> O <tb> <SEP> 0 <SEP> 0 <tb> <SEP> COi <SEP> 2C,9H <SEP> r <SEP> 2 <SEP> 1C,St <tb> <SEP> SH <SEP> 7 <SEP> 4H <tb> <SEP> SOBE <SEP> [ <SEP> 1H <tb> <SEP> RICE <SEP> tt,9H <SEP> 2t <tb> <SEP> SORCH'L <SEP> ZC, <SEP> i <SEP> 1C.6" <tb> IPRT-MTRCCtT <tb> <SEP> HORSr: :CfLDR'i <tb> <SEP> 1C <SEP> O <SEP> .0 <tb> <SEP> COCXLS <SEP> O <SEP> 0 <SEP> 0 <tb> <SEP> CAS <SEP> S <SEP> rA <SEP> 0 <SEP> 0 <tb> <SEP> M'fS23CT <SEP> o <SEP> 0 <tb> <SEP> 0 <SEP> 0 <tb> <SEP> CRABGiL9SS <SEP> 0 <SEP> ¯0 <SEP> D <tb> <SEP> 3A?.'YARDGRASS <SEP> lC, <SEP> 2H <SEP> IC <tb> <SEP> WILD <SEP> OATS <tb> <SEP> UHEA'I <SEP> I <SEP> o <SEP> o <SEP> o <tb> <SEP> COR <SEP> I <SEP> 2C,8)1: <SEP> sH <SEP> G <tb> <SEP> SOYBAS <SEP> 2C <SEP> 1C <SEP> Ic <tb> <SEP> RICE <SEP> 0 <SEP> 3G <tb> <SEP> SORGE > ' <SEP> 1C, <SEP> 7G <tb> Table A (continued) EMI204.1 <SEP> <tb> <SEP> sY=ZY t <SEP> EYr <SEP> zOte <SEP> Yt <SEP> e <tb> <SEP> 37 <tb> <SEP> - <SEP> <tb> <SEP> d' <SEP> N <tb> <SEP> N <SEP> 'NO <SEP> N <tb> <SEP> 0·J <SEP> <tb> kg1ha <SEP> .05 <SEP> .05 <SEP> 0.4 <tb> <SEP> kgtha <SEP> .05 <SEP> .05 <SEP> 0 <SEP> 4 <tb> <SEP> PC;-* <SEP> -o;.E <tb> <SEP> BUSH <SEP> 13Ei; <SEP> 3C <SEP> 9G <SEP> 6': <tb> <SEP> CCTT <SEP> 0.': <SEP> 2C <SEP> . <SEP> 9G <SEP> o¯ <SEP> 2C, <SEP> 2R <SEP> . <SEP> 7G <tb> <SEP> N3?.'.'INuGLOWi <SEP> 6C <SEP> 9G <SEP> 2C <tb> <SEP> COCI:LEEA <SEP> 6C <SEP> . <SEP> 9G <SEP> U <SEP> ic <tb> <SEP> CASSl;r <SEP> > <SEP> g <SEP> U <SEP> 1C <SEP> IC¯¯¯¯¯¯¯¯ <tb> h"L'ffE35f, <SEP> u <tb> <SEP> CRA3GR <SEP> '.5S <SEP> 2G <tb> <SEP> B'YAPGRA.S <SEP> lC,4H <tb> <SEP> UIID <SEP> OA75 <SEP> 0 <SEP> ¯0 <SEP> D <tb> <SEP> 0 <SEP> 0 <tb> <SEP> COIZS <SEP> - <SEP> 2C <SEP> 9G <SEP> O <SEP> O <SEP> C,9H <tb> <SEP> SOYBEA:; <SEP> 2C,9G <SEP> O <SEP> lC,6H <tb> <SEP> RICE <SEP> - <SEP> ' <SEP> ¯ <SEP> o <SEP> . <SEP> .¯ <SEP> C, <SEP> 8 <SEP> G <tb> <SEP> SORGE <SEP> C, <SEP> G <SEP> 0 <SEP> iC, <SEP> 9n <tb> <SEP> PRE-EXERG <SEP> I <SEP> ¯ <SEP> ¯ <SEP> CE <tb> <SEP> NOI'.;GCLORY <SEP> r <SEP> 1OE <SEP> 2C,6H <tb> <SEP> OCXLEBLR <SEP> 2C <SEP> 9H <SEP> = <SEP> O <SEP> .. <tb> <SEP> CASSIA <SEP> 5C.9G <SEP> 0 <SEP> SC <tb> <SEP> NvTsEDCE <SEP> 5G <SEP> 0 <tb> <SEP> CRABGRASS <SEP> O <SEP> O <tb> <SEP> BAR.ARDCRASS <SEP> ¯ <SEP> 7H <SEP> 0 <SEP> C <tb> <SEP> WIZ <SEP> OATS <SEP> O <SEP> o <SEP> O <tb> , <SEP> WHEAT <SEP> o <SEP> o <SEP> - <SEP> u <SEP> <tb> <SEP> CORN <SEP> - <SEP> 3C, <SEP> 9G <SEP> O <SEP> 2C <SEP> , <tb> <SEP> SOYBEAN <SEP> 2C, <SEP> 8H <SEP> 7 <SEP> 1C, <SEP> 3G <tb> <SEP> RICE <SEP> - <SEP> 2C <SEP> . <SEP> SG <SEP> C <SEP> . <SEP> MG <tb> <SEP> SORGHE .' <SEP> 2C <SEP> . <SEP> 9H <SEP> O <SEP> ZC <SEP> o <SEP> iH <tb> Table A (continued) EMI205.1 <tb> <SEP> 5.' <SEP> ," <tb> <SEP> r <SEP> NY <tb> <SEP> N <SEP> = <tb> <SEP> r <SEP> -" <SEP> z <tb> <SEP> - <SEP> - <SEP> 0 <tb> <SEP> ZN <tb> <SEP> - <SEP> <SEP> a <tb> <SEP> 1 <tb> <SEP> l(E'h <SEP> .05 <SEP> .05 <SEP> .05 <tb> <SEP> I <SEP> I <tb> <SEP> 1C <SEP> 1 <SEP> C <SEP> 9D <SEP> 9D <SEP> 9G <SEP> 6Y <SEP> 9C <tb> COTTO.': <SEP> 2C, <SEP> X <SEP> 2C, <SEP> 3H, <SEP> 8G <SEP> 3C,9G <tb> ¯¯Q <SEP> 2H <SEP> 2H <SEP> 2C,9G <SEP> 3C,9G <tb> <SEP> CQ.} <SEP> R <SEP> ¯ <SEP> 2C <SEP> 2 <SEP> 4C, <SEP> 9G <SEP> 6C,9G <tb> <SEP> CASS:n <SEP> 2C <SEP> 3C,8G <SEP> óC <SEP> 9G2COSH <tb> <SEP> 2C <SEP> 9G <SEP> 5C,9G <SEP> 5cl <SEP> 9¯G <SEP> - <SEP> C, <SEP> G <tb> <SEP> Crit <SEP> O <SEP> SG <SEP> 3C,SH <tb> <SEP> 0 <SEP> 1 <SEP> 3C,9H <SEP> 3C,9H <tb> <SEP> WI <SEP> OATS <SEP> o <SEP> C, <SEP> G <tb> <SEP> wav¯ <SEP> O <SEP> w <SEP> 5 <SEP> C, <SEP> 3G <SEP> G <tb> <SEP> CORN <SEP> 2C <SEP> . <SEP> 7H <SEP> 2U, <SEP> G <tb> <SEP> SOf'Bi; <SEP> 5H <SEP> C,9G <SEP> C,9 <tb> <SEP> RICE <SEP> 5G <SEP> 1C, <SEP> ZC <SEP> , <tb> <SEP> SORtfit'?: <SEP> 2C, <SEP> 9H <SEP> 9H <SEP> 2 <SEP> 9G <SEP> 2C, <SEP> H <tb> PRE-E".ERENCE <tb> <SEP> NORNINGCLORY <SEP> 6G <tb> <SEP> COCKLE3E'R <SEP> I <SEP> 9H <SEP> i <SEP> 9H <SEP> 9E <SEP> 9H <tb> <SEP> CASSIA <SEP> 2C.5H <SEP> i <SEP> 1C, <SEP> 9G <SEP> 9G <tb> <SEP> NrTSEDCE <SEP> 2G <SEP> 9G <SEP> 1 <SEP> OE <tb> <SEP> CRA3'RASS <SEP> O <SEP> 3G <SEP> L <SEP> 2C <SEP> SG <tb> <SEP> 3ERSN <SEP> AD MSS <SEP> 1H <tb> <SEP> 4C¯, <SEP> 9G <SEP> 3C,9H <SEP> 1 <tb> <SEP> 1C,9G <tb> <SEP> COE1 <SEP> 2C,8H <SEP> 1 <SEP> IOH <SEP> 2C <SEP> ,9H <tb> <SEP> SOYBLAS <SEP> 2C <SEP> i <SEP> 9H <SEP> 9H <tb> <SEP> 3103 <SEP> LC,C <SEP> I <SEP> 2C,8G <SEP> 4C,8H¯ <tb> <SEP> R$CZ <SEP> C <SEP> t <SEP> 7fflG <SEP> ¯ <SEP> 2C, <SEP> 8G <SEP> 4C, <SEP> 8H <tb> <SEP> SORCt <SEP> C, <SEP> H <SEP> 2C, <SEP> 9H <SEP> 2C, <SEP> 8H2C <SEP> SR <tb> Table A (continued) EMI206.1 <tb> <SEP> 5 <SEP> 5 <SEP> =r' <SEP> -,"' <SEP> 4.' <tb> <SEP> C <SEP> cr <SEP> n <SEP> <tb> <SEP> 0ffQc <tb> <SEP> x <SEP> T <tb> z <SEP> I <SEP> . <SEP> == <tb> <SEP> LZ <tb> <SEP> all <tb> <SEP> N <SEP> N <SEP> C <tb> C <SEP> 0 <SEP> tr. <SEP> C <tb> <SEP> C <SEP> C <SEP> | <SEP> C <SEP> N <tb> <SEP> 'Dro= <tb> <SEP> O. <SEP> O.L <tb> <SEP> kb <SEP> 0.P' <SEP> O.L <tb> <SEP> LfFf-L;=f <tb> <SEP> 9C,6. <SEP> P3 <tb> <SEP> - <SEP> 4C <SEP> lt.2E <tb> <SEP> C <SEP> ff <SEP> ': <SEP> 9C <SEP> 9t <SEP> 3C.3.9; <tb> <SEP> v:T1:==-TrCf <SEP> ¯ <SEP> 10f <SEP> 1 <SEP> Of <SEP> (rC,4; <tb> <SEP> 10C <SEP> : <SEP> 9f <SEP> 1 <SEP> C, <SEP> 9G <SEP> <tb> <SEP> -trZ= <SEP> 6f.9 <SEP> ,4f <SEP> 2t,LE <tb> <SEP> l;;¯ <SEP> bC,9 <SEP> 6C <SEP> . <SEP> 9-- <SEP> I <SEP> 2C <tb> <SEP> 2C.7G <SEP> s <SEP> ,e <SEP> C <SEP> 2C. <SEP> 1C <tb> <SEP> 9C <SEP> I <SEP> 9C <SEP> { <SEP> LCb9H <tb> <SEP> ..'. <SEP> CATC <SEP> 0 <SEP> C. <SEP> .. <SEP> C,fr: <tb> <SEP> 0 <SEP> C. <SEP> C <tb> <SEP> 3r,4E <tb> <SEP> S;t: <SEP> C,9C <SEP> I <SEP> 10C¯ <tb> <SEP> E:=E <SEP> 3t.9G <SEP> 6E.9Y <tb> <SEP> PLIU <SEP> I <tb> <SEP> 53kSY. <SEP> 1C, <SEP> 9G <SEP> 9C <SEP> I <SEP> L,Ya <tb> <SEP> I <tb> <SEP> P3T-LL.IESr;ft <tb> <SEP> IT3SLCI'T <SEP> 10C <SEP> Lt,gf <tb> <SEP> 9 <SEP> 9 <SEP> se <tb> <SEP> CS= <SEP> 6C,9C <SEP> C,9G <SEP> 2C <tb> <SEP> )cfETSf <SEP> 10E <SEP> OE: <SEP> o <tb> <SEP> ZC,7C <tb> <SEP> 2C,SC <SEP> OstS <SEP> 5C,8G <SEP> 8G <SEP> 9rv <tb> <SEP> ';riEAT <SEP> 0 <SEP> 9G <tb> <SEP> CO <SEP> 5Cq9H <SEP> 9H <SEP> 10 <SEP> ZC, <tb> <SEP> 50YL9 <SEP> 9H <SEP> gH <tb> <SEP> RICE <SEP> 1 <SEP> 10e <SEP> Ç <SEP> r. <tb> <SEP> i <SEP> 10E <SEP> rn <SEP> C, <SEP> In <tb> Table A (continued) EMI207.1 <tb> <SEP> n <SEP> cl <SEP> o <tb> <SEP> Lr <SEP> N <SEP> C <tb> <SEP> ¯------ <SEP> - <SEP> <tb> ¯ <SEP> O.L <SEP> Q.L <SEP> O.L <tb> <SEP> s, <SEP> c^,. <SEP> - <SEP> SC <SEP> 6 <SEP> ! <SEP> 6C <SEP> M <SEP> 6C <SEP> v <SEP> , <SEP> G <SEP> 6C <SEP> (E, <SEP> 6Y <SEP> 9 <tb> <SEP> c¯ <SEP> % <SEP> 3c <SEP> 5; <SEP> ! <SEP> 7C.95 <SEP> 6C <SEP> 9Z <tb> ' <SEP> v,- <SEP> 3C <SEP> . <SEP> e:-: <SEP> I <SEP> lOC <SEP> 5C <SEP> 9 <tb> <SEP> CC: <SEP> - <SEP> 3C. <SEP> z <SEP> µ <SEP> 6C <SEP> 99 <SEP> ¯ <SEP> 5C <SEP> 9w <tb> <SEP> Css <SEP> S <SEP> A <SEP> ic <SEP> | <SEP> C <SEP> 7C <SEP> 6C <SEP> 8' <tb> <SEP> ;r¯,r <SEP> 2C,6J <SEP> i <SEP> 2C <SEP> i <SEP> S-. <tb> <SEP> Cr-. <SEP> - <SEP> IC <SEP> 7C <SEP> ss <SEP> 7G <SEP> SC <SEP> 9c <tb> :.:A'..C.C <SEP> e <SEP> c,- <SEP> I <SEP> 9P. <SEP> 9C <tb> <SEP> - <SEP> Cw-- <SEP> LC, <SEP> 5- <SEP> 1 <SEP> 2C <tb> <SEP> 2C.C. <SEP> 0 <SEP> 7C. <SEP> 3C <SEP> 6C <tb> <SEP> cc.: <SEP> j <SEP> 2C,5G <SEP> 3t <SEP> 9C <SEP> SC <SEP> 9Z <tb> <SEP> CC: <SEP> 3E <SEP> 1 <SEP> 2C,4C <tb> <SEP> ¯ <SEP> Lt. <SEP> 3E, <SEP> 2C,9G <SEP> 3C,9C <tb> <SEP> Bs <SEP> 5t,9t <SEP> 3C,SG <SEP> 5C, <SEP> 9G <tb> <SEP> lt,9t <SEP> R <SEP> . <SEP> 9¯ <SEP> 2Cs8v <tb> <SEP> ' <SEP> tFr¯Fwtjl,?s;t <tb> <SEP> 8?:. <SEP> ¯87d <SEP> ¯ <SEP> ¯ <SEP> SC <tb> <SEP> lOr <SEP> . <SEP> lOr. <SEP> ¯ <SEP> ' <SEP> 9H <tb> <SEP> CASSq'A <SEP> 2C,5C <SEP> 6Cs9G <SEP> SC.8C <tb> <SEP> :':TsZC? <SEP> 2C, <SEP> 8r. <SEP> lOE <SEP> lOE <tb> <SEP> iS <SEP> 5C, <SEP> C, <SEP> ) <SEP> C.9C <tb> <SEP> t2NtA9PA <SEP> so <SEP> 6C,9H <SEP> 5C,9H. <tb> <SEP> ufD <SEP> OrS <tb> <SEP> -3f <SEP> .6H <SEP> -3C. <SEP> 4G <tb> <SEP> - <SEP> tDR" <tb> <SEP> "-Vt; <SEP> 6ii <tb> <SEP> 4F. <SEP> I: <SEP> I <SEP> lul <tb> <SEP> i <SEP> x <SEP> c <SEP> .'a <tb> Table A (continued) EMI208.1 <tb> <SEP> p <tb> <SEP> G <SEP> Cj <SEP> C <SEP> U <tb> <SEP> zoT <SEP> 2rOr <SEP> c <tb> <SEP> T <tb> <SEP> f <tb> <SEP> C <SEP> t <SEP> n <SEP> == <tb> <SEP> Z <SEP> El <SEP> N <tb> <SEP> -tì. <SEP> z <SEP> ; <SEP> -, <tb> 0 <SEP> Lr <SEP> C <SEP> Lr <tb> <SEP> Lr.= <SEP> N <SEP> LI <tb> <SEP> . <SEP> tE <SEP> t¯ <tb> <SEP> - <SEP> -- <SEP> - <SEP> <tb> <SEP> E,; <SEP> t <SEP> O.L <SEP> 1 <tb> <SEP> t- <SEP> t'% <tb> <SEP> r <SEP> v <SEP> o <tb> <SEP> s- <SEP> ?C <SEP> --,¯^ <SEP> 3n <SEP> 6C,6Y.C <SEP> 2C,E''9w <tb> <SEP> C-.TTr': <SEP> ; <SEP> l <SEP> 3; <SEP> C. <SEP> 9; <SEP> 3C,5r <tb> <SEP> w <SEP> .'%,..::. <SEP> lH <SEP> F <SEP> x <SEP> 2C. <SEP> jG <tb> <SEP> CTTf- <SEP> i <SEP> C,95 <SEP> r <SEP> LC,4f- <SEP> 7c. <SEP> bv <tb> <SEP> fb2f=.r. <SEP> 0 <SEP> I <SEP> Lt <SEP> <tb> <SEP> SSITI <SEP> I(j <SEP> u <tb> <SEP> ft,z.fr.ff <SEP> I <SEP> 1! <SEP> se <tb> <SEP> Ci <tb> <SEP> W <SEP> - <SEP> ' <SEP> G,. <tb> <SEP> i <SEP> Ct <SEP> O <tb> <SEP> - <SEP> e <SEP> 6 <tb> <SEP> O <SEP> .-. <tb> <SEP> i <SEP> 1E- <SEP> J <SEP> 2C.7X,SZ <SEP> 2C.5X, <tb> <SEP> 0 <SEP> 2C.7G <SEP> 9C <tb> <SEP> Sw <SEP> / <SEP> O <SEP> J <SEP> IC,6v <SEP> 1C,6 <tb> <SEP> fL.Eurrrl <SEP> 1 <tb> <SEP> tlL=:;=fLCII <SEP> ' <SEP> t <SEP> 9C <SEP> 7G <tb> <SEP> tGtLTf-TP <SEP> i <SEP> 4 <tb> <SEP> CIZffA <SEP> 6 <SEP> i <SEP> Bt <SEP> C <tb> ; <SEP> hTSC <SEP> Ob <SEP> CI <tb> <SEP> cE <SEP> uss <SEP> - <SEP> o <tb> <SEP> E <SEP> e <SEP> e <SEP> 2cs <SEP> 7E <SEP> 6r; <tb> -----l1------OATS <SEP> 0 <tb> <SEP> co,--; <SEP> w <SEP> c <SEP> s <SEP> }:. <SEP> ,r. <tb> <SEP> SD'9 <SEP> - <SEP> . <SEP> . <SEP> 1X. <SEP> jF; <SEP> -- <SEP> --' <tb> <SEP> 711 <SEP> CS <SEP> . <SEP> X <tb> JICJ <SEP> I <SEP> 3C <tb> Table A (continued) EMI209.1 <tb> <SEP> h <SEP> n <SEP> h <tb> <SEP> U <SEP> ; <SEP> tcn <SEP> w <tb> <SEP> C:-, <SEP> > <SEP> : <tb> <SEP> = <SEP> = <tb> <SEP> z <SEP> L: <SEP> = <SEP> z <SEP> <tb> <SEP> C <SEP> N <SEP> N <SEP> I <SEP> N <SEP> L; <tb> -"p <SEP> C <SEP> Ov. <tb> <SEP> Li, <SEP> N <tb> <SEP> I <SEP> o <tb> <SEP> w <tb> <SEP> out <SEP> E <SEP> .2 <SEP> <SEP> µ <SEP> 4 <SEP> ¯ <SEP> ¯ <SEP> O.r, <SEP> O. <tb> <SEP> i <SEP> 3f <SEP> .6,7C <SEP> 9C <tb> <SEP> C. <SEP> 3C,3,6 <SEP> 5 <SEP> 9C <tb> <SEP> I <SEP> 5C,9 <SEP> .-'. <SEP> 3 < 9S <SEP> 1 <tb> <SEP> I <SEP> 3C.6; <SEP> I <SEP> 5C,4G <SEP> C <tb> <SEP> 3C <SEP> ', <SEP> A <SEP> 3C <SEP> 2C.6; <SEP> i <tb> <SEP> S <SEP> ¯,,S <SEP> cr--r <SEP> r <SEP> <tb> <SEP> lf,5C <SEP> 9C- <SEP> 7 <SEP> g; <SEP> 7 <tb> <SEP> '.:kZ.Z.t±.S5 <SEP> 5; <SEP> 9; <tb> <SEP> CA.. <SEP> j <tb> <SEP> W-r <SEP> C, <tb> <SEP> t3:'; <SEP> lt.5EL1,4ef <tb> <SEP> i <SEP> Sc; <SEP> 1C,2G <SEP> 6C.Sc <tb> <SEP> B. <SEP> S <SEP> 2C,ov <SEP> b <SEP> v <SEP> D <tb> <SEP> I <tb> <SEP> [ <SEP> 55 <SEP> LL,b3 <SEP> JLY <tb> <SEP> f;r¯ > D,, > ; <SEP> s <tb> <SEP> P; <SEP> f <SEP> - <SEP> L <SEP> 5 <SEP> P <SEP> ;C <SEP> =f <SEP> I <SEP> I <tb> <SEP> se <SEP> <tb> <SEP> CATCSS <SEP> 3C,7E <SEP> 4C,9W <SEP> 5C <tb> <SEP> r. <SEP> TSED <SEP> 9S <SEP> 10¯ <SEP> 10-- <SEP> ¯ <SEP> <tb> <SEP> CK <SEP> SS <SEP> 2C,6G <SEP> 5C9v <SEP> tCs <tb> <SEP> ¯ <SEP> 2C, <SEP> 9E <SEP> 6C, <SEP> 5:- <SEP> 4 <SEP> 5G <tb> <SEP> ;'1' <SEP> n <SEP> OA-S <SEP> 3C,5G <SEP> C,94 <SEP> C, <tb> <SEP> ;,r.LT <SEP> 9 > <SEP> 3C, <SEP> 9 > <SEP> - <SEP> 9 <tb> <SEP> C5r <SEP> ; <SEP> 2C <SEP> 9k <SEP> 10}d <tb> <SEP> I <SEP> 505 <SEP> h9.; <SEP> 2C <SEP> 25. <SEP> 85. <tb> <SEP> d <SEP> - <SEP> d <tb> <SEP> ¯R; <SEP> CE <SEP> IQL <SEP> 1U; <SEP> . <SEP> " <SEP> ¯ <tb> <SEP> S <SEP> Fr.¯.¯ <SEP> ' <SEP> 2Cs9v <SEP> 7(;,9r <SEP> ' <SEP> or <SEP> ,9h <tb> Table A (continued) EMI210.1 <tb> <SEP> z <SEP> ZVZ <SEP> Z <tb> <SEP> x <tb> <SEP> 7. <SEP> c <tb> <SEP> = <tb> <SEP> V. <SEP> 0 <tb> 'it <SEP> NL'i <SEP> NI <SEP> c <tb> <SEP> 01 <SEP> ion <tb> <SEP> - <SEP> - <SEP> <tb> <SEP> CL. <SEP> O.L. <tb> <SEP> 9C <SEP> 9- <SEP> I <SEP> 9 <tb> <SEP> 9C <SEP> 4t <SEP> 1 <SEP> 41 <tb> <SEP> CT':: <SEP> 7C <SEP> µ- <SEP> ¯ <tb> <SEP> ICC <SEP> 18r <SEP> 1 <SEP> lOC <SEP> t <SEP> }Q' <SEP> 1 <SEP> 1:': <tb> <SEP> C=LfZ? <SEP> 1 <SEP> 9C <SEP> I <SEP> 9C <SEP> 10s <tb> <SEP> lOC <SEP> eC <SEP> 3t <tb> <SEP> c <SEP> 9C <SEP> 1 <SEP> 5; <SEP> 2C,6 <tb> <SEP> j.::.:AZ.Z..±.t.. <SEP> lOC <SEP> 1C. <tb> <SEP> :r= <SEP> CfT <SEP> 5Cs5 <SEP> ( <SEP> C,4t <SEP> 2C <tb> <SEP> t=GC. <tb> <SEP> CC.' <SEP> lOC <SEP> /i, <SEP> 9C <tb> <SEP> 9C <SEP> 9C <SEP> 5C <SEP> | <SEP> 9C <SEP> 5; <SEP> 9C <tb> <SEP> lOC <SEP> 1 <SEP> lOC <SEP> C <tb> <SEP> svA-Vs <SEP> lOC <SEP> ioc <SEP> C <tb> <SEP> P <SEP> t <SEP> r¯o <SEP> r <SEP> . <tb> <SEP> M <SEP> - <SEP> j <SEP> 9C <tb> <SEP> COTifT <SEP> 9 <SEP> 1 <SEP> 9t <SEP> ss <tb> <SEP> C5S;A <SEP> 5t,4t <SEP> ( <SEP> Zt.9t <SEP> 1C,9t <tb> <SEP> I <SEP> hTSr3:f <SEP> 10E <SEP> t,9G <SEP> gC <tb> <SEP> C'cr.3SfS <SEP> 2t,BC <SEP> ) <SEP> 3C,B= <SEP> 9C,5C <tb> <SEP> EI.*i3:iilS <SEP> 6C.9R <SEP> 5C.9ii <SEP> 3C.99 <tb> <SEP> flC <SEP> OATS <SEP> bC,9 <SEP> 5C,9 <SEP> 1C,8, <tb> <SEP> i <SEP> vI <SEP> 9G <SEP> 1C,9G <SEP> -C <tb> <SEP> t0it; <SEP> 9ii <tb> I <SEP> SOW <SEP> 9H <SEP> 9H <SEP> ; <SEP> in <tb> <SEP> X:Ct <SEP> 1 <SEP> 1 <SEP> 0¯ <SEP> 10E <SEP> L <tb> <SEP> W": <SEP> lOr <SEP> i <SEP> Sn <SEP> n <tb> Table A (continued) EMI211.1 <tb> <SEP> n <SEP> r <SEP> c <SEP> r <SEP> n <SEP> n <tb> <SEP> XE <SEP> W, <SEP> > <tb> <SEP> T <SEP> &num;r0zX <SEP> t <SEP> vE <tb> <SEP> = <SEP> = <tb> <SEP> c: <SEP> O: <SEP> z <SEP> w <tb> <SEP> 5= <SEP> t= <SEP> c¯ <SEP> = <tb> <SEP> HL: <tb> <SEP> C <SEP> c <SEP> 0 <SEP> L; <SEP> a <tb> <SEP> - <SEP> tU <tb> <SEP> = <SEP> m <SEP> N <SEP> V) <SEP> h <tb> <SEP> kE <SEP> ()rc7 <SEP> (Dro= <tb> <SEP> 0,' <SEP> 0.'. <SEP> 1 <tb> ¯¯ <SEP> . <SEP> . <SEP> 9C <SEP> t <tb> <SEP> CT. <SEP> gC <SEP> I <SEP> 9C <SEP> j <SEP> 9C <tb> <SEP> .'...-.. <SEP> ::.:,?.c?r.: <SEP> lOC <SEP> I <SEP> 10 <SEP> lOC <tb> <SEP> 9C <SEP> 1 <SEP> l <SEP> lOC <SEP> lOC <tb> <SEP> CA:.: <SEP> i <SEP> A <SEP> g; <SEP> z <SEP> 9C <SEP> I <SEP> 9C <tb> <SEP> 9C <SEP> 9C <SEP> 9C <tb> - <SEP> tzI5r,tt <SEP> bt.9u <tb> <SEP> 1CI¯ <SEP> OC <SEP> 4 <tb> <SEP> f" <SEP> tA, <SEP> 4; <SEP> 9C <SEP> bL.r <tb> <SEP> 4C <SEP> se <SEP> 9 <tb> <SEP> St: <SEP> ¯ <SEP> 9e <SEP> 9t <SEP> 9 <tb> <SEP> StF-r <SEP> 1 <SEP> 9; <SEP> 9C <SEP> I <SEP> se <tb> <SEP> I <tb> <SEP> r.==I <SEP> 9; <SEP> 9C <SEP> 4t <tb> <SEP> sse- <SEP> i <SEP> se <SEP> TPi <SEP> 1 <SEP> 5 <tb> <SEP> Tf-LSFSC;¯TI¯II <SEP> -1 <tb> <SEP> 9; <SEP> ¯4C <SEP> I <SEP> 4i <tb> <SEP> Yr, <SEP> 4u <SEP> I <SEP> 4n <tb> ¯ <SEP> CAS--fi3-l <SEP> 3C,9G <SEP> 1 <SEP> IC,U <tb> <SEP> 10f <tb> <SEP> ¯ <SEP> tC. <SEP> gC <SEP> ZC,SC <tb> <SEP> a <SEP> 2 <SEP> OASS <SEP> EC, <SEP> 9H <SEP> C--) <SEP> 9i! <SEP> 6C,oH <SEP> ¯ <SEP> lC,9 <tb> <SEP> 4L: <SEP> 10H <SEP> 7 <SEP> lOii <SEP> 9G <tb> <SEP> lOE <SEP> 1 <SEP> OE <SEP> 10E <SEP> 9zi <tb> <SEP> SOE <SEP> 9H <SEP> :1 <tb> <SEP> low <SEP> F <tb> <SEP> S <SEP> O <SEP> .R <SEP> : <SEP> 1 <SEP> F <SEP> 10-: <SEP> n <SEP> ¯ <tb> Table A (continued) Compound Compound Compound 19 20 21 0.4 0.4 0.4 POST-EMERGENCE Bush bean 4C,7G,6Y 9C 4S,5G,6Y Cotton 2C, 3H 5C,9G 4C,7G Morningglory 1C 9C 2C,5G Cocklebur 1C lOC 2C Cassia 3C 4C,8G 2C Nutsedge 0 3G 0 Crabgrass 2C 1C O Barnyardgrass 3C,7H 2C,6H 0 Wild Oats 3G 0 0 Wheat 2G 0 0 Corn 2C,6H 2C,9H 0 Soybean 3C, 5G 9C 2C Rice 2C,6G 1C,3G 0 Sorghum 2C,7H 2C,5G 0 PRE-EMERGENCE Morningglory 8G 9G 5G Cocklebur 5H 9H 0 Cassia 5G 5C,SG . O 0 Nutsedge 3G 8G 10E Crabgrass 1C O 1C Barnyardgrass 2C,7H 2G 1C Wild Oats 8G 0 0 Wheat 5G O 0 Corn 2C,7G 2C,6G 1C Soybean 1C,1H 2C,6H 0 Rice 2C,8G 1C, 3G 0 Sorghum 2C,8H 2C,8H 0 Table A (continued) Compound Compound Compound Compound 15 16' 17 18 .05 0.4 0.4 0.4 POST-EMERGENCE Bush bean 1C,6Y 4C,7G,6Y 9C 2H,6F Cotton 2C 2C,2H 4C,8G 1H Morningglory 3B,8G 0 1C 0 Cocklebur 3C,6G 2C,6G 3C,9G 0 Cassia 2C 2C 3C,5G 0 Nutsedge 1C O 4G 0 Crabgrass O 0 2C 0 Barnyardgrass 0 0 1C,5G 1C Wild Oats 0 0 0 0 Wheat O 0 0 0 Corn O O 1C O Soybean 1C O 1C,3H 0 Rice 0 2G 5G 2C Sorghum 1C 1C 1C,5H 1C PRE-EMERGENCE Morningglory 2C,5G 0 6G 0 Cocklebur 2C,SG 5H 8R 0 Cassia 1C 4G 2C,5G 0 Nutsedge 10E 0 9G 0 Crabgrass 2G 0 2C 0 Barnyardgrass 2G 2G 3C 1C Wild Oats 0 0 1C 0 Wheat O O 1C O Corn 2C,2G 2C,4G 3C,6H 0 Soybean 0 1C 2C 0 Rice 2C 1C,5G 9H 0 Sorghum 2G 4G 2C,8H 0 Table A (continued) Compound Compound Compound Compound 11 12 13 14 Rate kg/ha .05 .05 0.4 0.4 POST-EMERGENCE Bush bean 9D,9G,6Y 9C 7C,9G 6C,9G Cotton 4C, 9G 5C, 9G 5C, 9G 5C, 9G Morningglory 9C lOC 3C, 8H 9C Cocklebur 9C lOC 9C 9C Cassia 3C,5G 5C, 9G 9C 5C,8G Nutsedge O 0 2C, 8G 7G Crabgrass 1C O 2C 2C, 5G Barnyardgrass 1C 1C 2C, 5H 3C, 9H Wild Oats O O 1C 2C, 5G Wheat O 0 O 1C, 5G Corn 1C 2C,5H 2C, 6H 2U,9G Soybean 5C, 8G 5C, 9G 6C, 9G 6C, 9G Rice 1C, 4g 1C, 6G 3C, 8G 5C, 9G Sorghum O 1C,6G 2C,8H 2C,8G PRE-EMERGENCE Morningglory 9G 5C, 9G 7G 9G Cocklebur 9H 9R 9H 9H Cassia 8g 3C, 8G 2C, 8G 8G Nutsedge 8G lOE lOE 10E Crabgrass 3G 2G 1C 3G Barnyardgrass 1C 1C 2C, 6H 2C, 8H Wild Oats O 1C 3G 8G Wheat 0 2G 0 8G Corn 1C, 6G 1C, 8G 2C, 8G 2C, 9G Soybean 2C,3H 2C,SH 0 1C, 3H Rice 5G 1C, 7G 10E 10E Sorghum 1C, 4G 2C, 9H 2C, 9G 5C, 9H Table A Compound Compound Compound Compound 7 8 9 10 Rate kg/ha .05 0.4 0.4 0.4 POST-EMERGENCE Bush bean 9C 9C 9D,9G,6Y 9D,9G,6Y Cotton 5C,9G 3C,9G 2U,6C,9G 10C Morningglory 3C,8H 9C 5C,9G 9C Cocklebur 5C,9H 9C 5C,9G 5C,9H Cassia 6C,9G 3C,7G 2C,6G 5C,9G Nutsedge 3C,9G 1C 9G 3C,9G Crabgrass 4G 0 lOC 9C Barnyardgrass 4e 1C,2H 3C,9H 9C Wild Oats 0 0 6C,9G 5C,9G Wheat 0 0 9C 6C,9G Corn 2C,8H 0 1C,9G 5U,9G Soybean 2C,9G lOC 2C,8G 9C Rice 5C,9G 2G 4C,9G 9C Sorghum 9G 3G 9C 5U,9C PRE-EMERGENCE Morningglory 9G 9G 5C,9G 9C,9G Cocklebur 9H 9H 9H 9H Cassia. 8G 8G 9G 1C,9G Nutsedge lOE 2G lOE 10E Crabgrass 5G 1C 1C,7G 2C,9G Barnyardgrass 3C,5G 3C 2C,9H 3C,9H Wild Oats 6G 0 5C,9H 3C,9H Wheat SG O 9H 9H Corn 8G 7G 9H lOH Soybean 1H 7H 8H 8H Rice 10E 9H 10E 10E Sorghum 9G 6G 10H 5C,9H Table A (continued) Compound S Compound 6 Rate kg/ha 0.1 2 2 POST-EMERGENCE Bush bean 3G 2C,9G 0 Cotton 1C 2C,1H 0 Morningglory 1C,9H 2C 0 Cocklebur 1C 1C O Cassia 0 2G 0 Nutsedge O 1C,5G 0 Crabgrass O 0 % Barnyardgrass O 0 0 Wild Oats 0 0 0 Wheat O 0 0 Corn O 0 0 Soybean 1C O 0 Rice O 0 0 Sorghum 1C 1C,3G O PRE-EMERGENCE Morningglory 1C 3C,8G 0 Cocklebur O 9H 0 Cassia 0 2C 0 Nutsedge 0 SG 4G Crabgrass 0 2C 5G Barnyardgrass 0 2C,6G 1C,3G Wild Oats 0 4G 0 Wheat 2G 2G 0 Corn 1C 2C,8H 2C,4G Soybean 1C 1H 1H Rice 2C SC 1C Sorghum 2C 3C,7G 2C,5G Table A (continued) Compound 3 Compound 4 Rate kg/ha 0.1 2 0.1 . 2 POST-EMERGENCE Bush bean 5C,9G,6Y 5C,9G,6Y 2C,SG,6Y 3C,7G,6Y Cotton 3C, 3H, 7G 5C,7G 3C,3H 3C,4H Morningglory 3C, 8H 6C, 9G 2C, 4H 3C, 4G Cocklebur 3C,9H 4C,9G 1C 1C Cassia 3C 3C, 5G 1C 1C Nutsedge 2C,6G 3C,8G 2G 0 Cr abgrass 0 2C,5G 0 0 Bzrnyardgrass 1C,6H 4C, 9H O 1C Wild Oats O 1C,6G 0 0 Wheat 0 3G 0 0 Corn 2C, 5H 2C, 9H 0 1C, 4G Soybean 2C, 8G, 5X 2C, 8G 1C, G 1C, 4G Rice 1C,2G 3C,7G 0 2G Sorghum 3C,9H 3C,9G 0 2C,4G PRE-MERGENCE Morningglory 3C,SH 9G 1C 4C,9G Cocklebur 9H 9H 0 2C Cassia 3C,3H 2C,8G 2C 2C Nutsedge 2C,6G 10E 1C 8G Crabgrass 2C 2C, 8G 2G 4G Barnyardgrass 2C, 6G 5C, 9H 1C 6G Wild Oats 2C,6G 4C,8G 0 4G Wheat 2C 1C,7G 2G 0 Corn 3C,8H 9G 1C, 6G 9G,2C Soybean 3C, 6H 9H 1C 1H, 1C Rice 3C,7G 9H 1C, 4G 2C Sorghum 5C, 8H 4C, 9H 1C, 3G 9G, 3C -Table A Compound 1 Compound 2 Rate kg/ha 0.1 2 0.1 2 POST-EMERGENCE Bush bean 5C,9G,6Y 4C,9G,6Y 1C,4G,6Y 4S,9G,6Y Cotton 5C,9G 5C,8G 1C 5C,8G Morningglory 4C,9H SC,9G 2C,5G 3C,6G Cocklebur 3C,9G 4C,9G 0 1C Cassia 3C,7H 3C,6G 1C 1C Nutsedge 1C,9G 1C,9G 0 1C,5G Crabgrass 1C,3G 8G 0 0 Barnyardgrass 3C,9H 9C 0 0 Wild Oats 0 0 0 0 Wheat O 0 ' 0 0 Corn 2C,7H 5U,9C 0 0 Soybean 3C,9G 4C,9G 1C,1H 2C,4G Rice 1C,5G 8G 0 2G Sorghum 5C,9G 9C 0 1C,2G PRE-EMERGENCE Morningglory 2C,5H 9G 0 3C,6G Cocklebur 1C,3H 9H 0 6G Cassia 6C <RTI ID=218.3> 3C,8G 0 2C Nutsedge lOE lOE O 3G Crabgrass 1C 2C,8G 0 0 Barnyardgrass 3C,8H 5C,9H 0 1C,2G Wild Oats 1C 3C,7G 0 3G Wheat 1C 4G 0 4G Corn 2C,9H 9H 0 3C,9H Soybean 3C,SH 9H 0 2C,3G Rice 2C,6G lOE 0 ,3G Sorghum 2C,9G 5C,9H 0 3C,8G Compound 19 EMI219.1 Compound 20 EMI219.2 Comoound 21 EMI219.3 Compound 15 EMI220.1 Compound 16 EMI220.2 Comoound 17 EMI220.3 Compound 18 EMI220.4 Compound 11 EMI221.1 Compound 12 EMI221.2 Compound 13 EMI221.3 Compound 14 EMI221.4 Compound 7 EMI222.1 Compound 8 EMI222.2 Compound 9 EMI222.3 Compound 10 EMI222.4 Compound 4 EMI223.1 Compound 5 EMI223.2 Compound 6 EMI223.3 Compound 1 EMI224.1 Compound 2 EMI224.2 Compound 3 EMI224.3 Test A Seeds of crabgrass (Digitaria spp.), barnyardgrass (Echinochloa crusgalli), wild oats (Avena fatua), cassia (Cassia tora) , morningglory (Icomoea sp.), cocklebur (Xanthium spp.), sorghum, corn, soybean, rice, wheat and nutsedge tubers (Cyperus rotundus) were planted in a growth medium and treated pre-emergence with the chemicals dissolved in a nonphytotoxic solvent. At the same time, cotton having five leaves (including cotyledonary ones), bush beans with the second trifoliate leaf expanding, crabgrass and barnyardgrass with two leaves, wild oats with one leaf, cassia with three leaves (including cotyledonary ones), morningglory and cocklebur with four leaves (including the cotyledonary ones), sorghum and corn with three leaves, soybean with two cotyledonary leaves, rice with two leaves, wheat with two leaves, and nutsedge with three to five leaves were sprayed. Treated plants and controls were maintained in a greenhouse for sixteen days, then all species were compared to controls and visually rated for response to treatment. The ratings, shown in Table A, are based on a numerical scale extending from 0 = no injury, to 10 = complete kill. The accompanying descriptive symbols have the following meanings: C s chlorosis/necrosis; D = defoliation; E r emergence inhibition; G = growth retardation; H = formative effects; S s albinism; U w unusual pigmentation; 6F r delayed flowering; and 6Y 3 flower buds abscised. diphenylacetamide (diphenamide); 2,4-dichlorophenoxyacetic acid (2,4-d) (and closely related compounds); 4-chloro-2-butynyl-3-chlorophenylcarbamate (baran); 5-(2,3-dichloroally)diisopropylthiocarbamate (diallate); 5-(2,3,3-trichloroally)diisopropylthiocarbamate (triallate); 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquat methyl sulfate); methyl 2-[4-(2,4-dichlorophenoxy)phenoxylpropanoate (diclofop methyl); 4-amino-6-tertbutyl-3-(methylthio)-1,2,4-triatin-5(4H)one (metrlbuzin); 3-(3,4-dichlorophenyl)-1-methoxy-1-methylures (linuron); 3-isopropyl-1H-2,1,3-benzothiodiazin4(3H)-one-2,2-dioxide (bentazon); o,o,o-triflucro2,6-dinitro-N,N-dipropyl-p-toluidine (trifluralin); 1,1'-dimethyl-4,4'-bipyridinium ion (paraquat); menosodium methanearsonate (MSMA); 2-chloro-2', 6'diethyl (methoxymethyl) acetanilide (alachlor); and 1,1-dimethyl-3-(o,o,o-trifluoro-m-tolyl)uras (fluometuron), and 5-[2-chloro-4-(trifluoromethyl) phenoxy-2-nitrobenzoic acid, methyl ester (acifluorfen, methyl). The activity of these compounds was discovered in greenhouse tests. The test procedures are described and the data shown below. Utility The compounds of the present invention are active herbicides. The have utility for broadspectrum pre and/or post-emergence weed control in areas where com plete control of all vegetation is desired, such as around fuel storage tanks, ammunition depots, industrial storage areas, oil well sites, drive-in theaters, around billboards, highway and railroad structures. By properly selecting rate and time of application, compounds of this invention may be used to modify plant growth beneficially, and also selectively centrol weeds in crops such as wheat and barley. The precise amount of the compound of Formula I to be use: in any given situation will vary according to the particular end result desired, the amount cf feliage present, the weeds to be controlled, the seil type, the formulation and mode of application, westher conditions, etc. Since so many variables play a rele, it is net possible to seate a rate of application suitable for all situations, Broadly speaking, the compounds of this invention are used at levels of about 0.001 to 20 kg/ha with a preferred range of 0.01 to 10 kg/ha. In general, the higher rates of application from within this range will be selected for adverse conditions or where extended persistence in soil is desired. The compounds of Formula I may be combined with other herbicides and are particularly useful in combination with ureas such as 3-(3,4-dichlorophenyl)-1,1-dimethylurea (diuron); the triazines such as 2-chloro-4-(ethyl- amino)-6-(isopropylamino)-s-triazine (atrazine); the uracils such as 5-bromo-2-sec-butyl-6-methyluracil (bromacil); N-(phosponomethyl)glycine (glyphosate); 3-cyclohexyl-1-methyl-6-dimethylamino-s-triazine2,4(1H,3H)-dione (hexazinone); N,N-dimethyl-2,2 Example 79 Granule N- [ (4,6-Dimethoxy-l,3,5-triazin-2-yl)- aminocarbonyl) -2- (hydroxymethyl) benzenesulfonamide 80% wetting agent 18 crude ligninsulfonate salt (containing 5-20% of the natural sugars) 105 attapulgite clay 9% The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidiza- tion and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water constant is reduced to the desired level, generally less than 1t. The material is then discharged, screened to the desired size range, gener ally 14-100 mesh (1410-149 microns), and packaged for use. Example 80 Wettable Powder N-[ (4, 6-Dimethoxy-l, 3, 5-triazin-2-yl) aminocarbonyl]-2-(hydroxymethyl) benzenesulfonamide 40% sodium ligninsulfonate 20% montmorillonite clay The ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged. ¯¯¯¯¯¯¯¯¯¯ Example 77 Oil Suspension N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)amino carbonyl] - 2- (hydroxymethyl) - benzenesulfonamide 25% polyoxyethylene sorbitol hexaoleate 5% highly aliphatic hydrocarbon oil 705 The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water. Example 78 Aqueous Suspension N-[(4,6-Dimethoxypyrimidin-2-yl) zminocarbonyl0-2-(hydroxymethyl) benzenesulfonamide 40% polyacrylic acid thickener 0.3% dodecylphenol polyethylene glycol ether 0.5% sodium phosphate 1% monosodium phosphate 0.5% polyvinyl alcohol 1.0s Water 56.78 The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size Example 74 High Strength Concentrate 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethox 1,3,5-triazin-2-yl)aminocarbonyl]benzene sulfonamide 99% silica aerogel 0.58 synthetic amorphous silica 0.5% The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a <RTI ID=230.3> U.S.S. No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary. Example 75 Wettable Powder 2-[(Dimethylaminc)sulfonylmethyl]-N-[(4-methoxy-6 methyl-1,3,5-triazin-2-yl)-aminocarbonyl] benzenesulfonamide 90% dioctyl sodium sulfosuccinate 0.1Z synthetic fine silica 9.9% The ingredients are blended and ground in a ha=ner-mill to produce particles essentially all be low 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged. Example 76 Oil Suspension 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethoxy pyrimidin-2-yl) aminocarbonyl] benzene sulfonamide 35% blend of polyalcohol carboxylic esters and oil soluble petroleum sulfonates 6% xylene 59E The ingredients are combined and ground together- in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water.

Claims: Example 72 Wettable Powder 2-[(Dimethylamino)sulfonylmethyl]-N-[(4-methoxy-6 methyl-1,3,5-triazin-2-yl)aminocarbonyl] benzenesulfonamide 20% sodium alkylnaphthalenesulfonate 4% sodium ligninsulfonate 4% low viscosity methyl cellulose 3% attapulgite 69% The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essen- tially all below 100 microns, the material is re blended and sifted through a U.S.S. No. 50 sieve (0.3 =n opening) and packaged. Example 73 Low Strangth Granule 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethoxy 1,3,5-triazin-2-yl)aminocarbonyl] benzenesulfonamide 1% N,N-dimethylformamide 9% attapulgite granules 90% (U.S.S. 20-40 sieve) The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a shost period and then the granules are packaged. -The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cocl and the packaged. Example 70 Dust N-[(4,6-dimethoxypyrimidin-2-yl]aminocarbonyl] 2-(methylthiomethyl)benzene sulfonamide 10% attapulgite 10% Pyrophyllite 80% The active ingredient it blended with attapulgite and then passed through a hammer mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous. Example 71 Wettable Powder 2- r tDimethylamino3 suifonylmethyl]-N- [ (4-methoxy-6- methylpyrimidin-2-yl)aminocarbonyl] benzenesuflonamide 50% sodium alkylnaphthalenesulfonate 2% low viscosity methyl cellulose 25 diatomaceous earth 465 The ingredients are blended, coarsely hammer- milled and then air-milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging. may be crushed to pass a V.S.S. No. 20 sieve (0.54 mm openings). The granules held on a U.S.S. No. 40 sieve 10.42 mm openings) may be packaged for use and the fines recycled. Example 67 Oil Suspension N-[(4,6-dimethyl-1,3,5-triazin-2-yl) aminocarbonyl]-2-(methoxymethyl)ben zenesulfonamide 25% polyoxyethylene sorbitol hexaoleate 5% highly aliphatic hydrocarbon oil 70% The ingredients are ground together in 2 sand mill until the solid particles have been reduced to under about 5 microns. The resulting tick suspension ra, be applied directly, but preferably after being extended with oils or emulsified in water. Example 68 Solution N-[(4-methoxy-6-methylpyrimidin-2-yl) aminocarbonyl]-2-(methylthiomethyl) benzenesulfonamide , 'sodium salt 5% water 95% The salt is- added directly to the water with stirring to produce the solution, which may then be packaged for use. Example 69 Low Strength Granule N-[(4,6-dimethoxypyrimidin-2-yl) aminocarbonyl]-2-(methylthio methyl)benzenesulfonamide 0.1% attapulgite granules 99.9% (U.S.S. 2-40 mesh) Example 64 Wettable Powder N-[(4-6-dimethylpyrimidin-2-yl)aminocarbonyl] 2-(methoxymethyl)benzenesulfonamide 80% sodium alkylnaphthalenesulfonate sodium ligninsulfonate 2% synthetic amorphous silica 3% kaolinite 135 The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns and then reblended. Example 65 Granule wettable powder of Example 64 5% attapulgite granules 95% (U.S.S. 20-40 mesh; 0.84-0.42 mm) A slurry of wettable powder containing #25@ solids is sprayed on the surface of attapulgite granules in a double-cone blender. The granules are dried and packaged. =xa..ple 66 Extruded Pellet N-[(4,6-dimethoxypyrimidin-2-yl)amino carbonyl]-2-(methoxymethyl)benzene sulfonamide 25% anhydrous sodiun sulfate 10% crude calcium ligninsulfonate 5% sodium alkylnaphthalenesulfonate 18 calcium/magnesium bentonite 598 The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extrouded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets Example 62 Granule 2- (dichloromethyl). -N-! [4-methoxy-6-methylpyrimidin- 2-yl)-aminocarbonyl]benzenesulfonamide 80% wetting agent 1% crude ligninsulfonate salt (continaing 10% 5-20% of the natural sugars) attapulgite clay 9% The ingredients are blended and milled to rpass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is con tinued, optionally-with heat, until the water con stant is reduced to the. desired level, generally less than 1%. The material is then dischared, screened to then desired size range, generally 14-100 mesh (1410-149 microns), and packaged for use. Example 63 High-Strength Concentrate 2-(dhcloromethyl)-N-[(4,6-dimethylpyrimidin 2-yl)-mainocarbonyl]benzenesulfonamide 99% silica aerogel 0.5% synthetic amorphous silica 0.5% The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S.No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary. Example 59 Wettable Powder 2- (dichloromethyl) E (4-methoxy-6-methylpyrimidin-2- yl)aminocarbonyl]benzenesulfonamide 50% sodium alkylnaphthalenesulfonate 2% low viscosity methyl cellulose 2% diatomaceous earth 46% The ingredients are blended, coarsely hammermilled and then air-milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging. Example 60 Granule wettable powder of Example 59 - 5% attapulgite granules (U.S.S. 20-40 mesh; 0.84-0.42 mm) A slurry of wettable powder containing # 25% solid's is sprayed on the surface of attapulgita granules in a double-cone blended. The granules are dried and packaged. Example 61 Aqueous Suspension 2- (dichloromethyl) -N- [(4, 6-dimethylpyrimidin-2-yl) - aminocarbonyl] benzene sulfonamide 40% polyacrylic acid thickener 0.3% dodecylphenol polyethylene glycol ether 0.5% disodium phosphate 1% monosodium phosphate 0.5% polyvinyl alcohol 1% water 56.79 The ingredients are blended and ground together in a sand mill to produce particles¯ wssentially of under 5 microns in size. N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino carbonyl]-2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl] 2-(methylthiomethyl)benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 (methylsulfinylmethyl)benzenesulfonamide; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] 2-(methylsulfinylmethyl)benzenesulfonamide; N-[(4-Methoxy-6-methylpyrimidin-2-yl)aminocarbonyl] 2-(methylsulfinylmethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylsulfinylmethyl)benzenesulfonamide; N-[(4,6-Dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (methylsulfinylmethyl)benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 (methylsulfonylmethyl)benzenesulfonamide; N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (butoxymethyl)benzenesulfonamide; ; N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (ethoxymethyl)benezenesulfonamide; N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2 (1-methylpropyloxymethyl)benezencsulfonamide; 2-[(Dimethylamino)sulfonylmethyl]-N-[(4,6-dimethyl pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2- [ (Dimethylamino) sulfonylmethyl] -N- I (4, 6-dimethOxy- Pyrimidin-2-yl)aminocarbonyl]benzenesulfonamide; 2-[(Dimethylamino)sulfonylmethyl]-N-[(4-methoxy 6-methylpyrimidin-2-yl)aminocarbonyl]benzene sulfonamide; 2-t(Dimethylamino)sulfonylmethyll-N-1(4,6-dimethyl- 1,3,5-triazin-2-yl) aminocarbonyll benzenesulfonamide; 2-[ (Dimethylamino)sulfonylmethyl]-N-[ (4,6-dimethoxy- 1,3,5-triazin-2-yl)aminocarbonyl]benzenesulfonamide; ; 2-[(Dimethylamino)sulfonylmethyl]-N-[(4-methoxy-6 methyl-1,3,5-triazin-2-yl)aminocarbonyl]benzene sulfonamide; N-[(4, 6.-Oimethoxypyrimidin-2-yl) aminocarbonyl] -2 (hydroxymethyl)benzenesulfonamide; N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2 (hydroxymethyl)benzenesulfonamide; N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2 (hydroxymethyl) benzenesulfonamide; N- I (4-methoxy-6-methylpyrimidin-2-yl) aminocarbonyl3 -2- (hydroxymethyl) benzenesulfonamide; N-[(4,6-Dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]-2 (hydroxymethyl) benzenesulfonamide; and N-[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]2-(hydroxymethyl)benzenesulfonamide; -and'agriculturally suitable salts thereof. 11. A compound of claim 1 wherein R, R1 and R2 are as defined in claim 1, W is O, R8 is H, A is EMI239.1 where Q, X, Y and Z are as defined in claim 1 and Y is H, CH3 or OCH3; and Is is C02R10, CONR3R4 or CN, where R10 is C1-C4 alkyl; and R3 and R4 are independently H or C1-C4 alkyl. 12. A compound of claim 1 wherein: R is as defined in claim 1; R1 is H or CH3;p R2 is H or CH3; L is SO2NR3R4 where R3 and R4 are as; defined in claim 1; R8 is H; W is 0; and A is defined in claim 11. 13. A compound of claim 1 wherein: R is as defined in claim 1; R1 is H or C1-C4 alkyl; R2 is H or CH3; R8 is H; L is S(O) nR7 or OR9; R7 and n are as defined in claim 1; R9 is C1-C4 alkyl, C3-C4 alkenyl; A is as defined in claim 11; and W is 0. 14. A compound of claim 1 wherein R is as defined in claim 1; R1 and R2 are independently H or CH3; R8 is H; L is OH, OC(O)R11, OC(O)NHR12 or OC(O)OR13; W is 0; and A is as defined in claim 11. 15. A compound of claim 1 wherein: R, R1 and R2 are as defined in claim 1; L is Cl, Br, NR3R4, NR3R4R4', N(R4)C(O)R5 N(R4)C(O)NHR6 or N(R4)C(O)R7; R8 is H; W is 0; and A is as defined in claim 11. 16. A compound selected from EMI240.1 wherein R, P1, and R2 are as previously defined in claim 1; Z is CH or N; n is O or 2; and L is as previously defined in claim 1, provided that: (1) L is not OR; (2) when R3 is OCH3. then P4 is CH3 and that R10 cannot be H; (3) when R1 is Cl, then L is Cl or Br and P2 is H; (4) when L is NR3R4, NR3R4R4', or SO2NR3R4, then R3 or R4 cannot be H; (5) the total number of carbon atoms of R3 and R4 is five or less. 17. A compound selected from EMI241.1 wherein A, R1, R2, R7 and Rg are as previously defined in ciaiin I; n is O or 2; L is Cl, Br, CO2R10, SO2NR3R4, S(O)nR7 or OR9, provided that: (1) when R1 is Cl, then L is C1 or Br and R2 is H; (2) when L is SO2NR3R4, then R3 and R4 cannot be H; (3) when R3 is OCH3, then R4 is CH3; (4) R10 cannot be H; and (5) n is O or 2. 18. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a herbicidal composition and at least one of the following: Surfactant, solid or liquid diluent, characterised in that said herbicidal compound comprises a compound of any of claims 1 to 15. 19. A method for controlling the growth of undesired vegetation by applying to the locus of such vegetation an effective amount of a herbicidal compound, characterised in that said herbicidal compound comprises a compound of any of claims 1 to 15. 20. A method for regulating the growth of plants by applying to the locus of said plants an effective but' substantially non-phytotoxic amount of a plant growth regulant, characterised in that said plant growth regulant comprises a compound of any of claims 1 to 15. 21. A process for preparing a compound of claim 1 which comprises: (a) reacting together EMI242.1 wherein L is Cl, Br, CO2R10, SO2NR3R4, S(O)nR7, OR9; n is O or 2; R, R1, R2, R3, R4, R7, R8, R9, R10 and A are bs defined in claim 1 except that R3, R4 and R10 cannot be H; (b) oxidising a compound of claim 1 wherein n is O or 1 to a compound wherein n is 1 or 2; (c) hydrolyzing a compound of claim 1 wherein R10 is C1-C4 alkyl to a compound wherein R10 is H; (d) reacting a compound of claim 1 wherein L is CO2R10 (where R10 is C1-C4 alkyl) with a dialkylallsminum-N- alkylamide derivative of general formula (Alk) 2A1-NR3R4 wherein R3 and R4 are as defined in claim I and Alk is an alkyl group, to obtain a compound of claim 1 wherein L is C(O)NR3P4; ; (e) reacting an appropriately substituted sulfonamide of general formula EMI243.1 with the methylcarbamate of the appropriate aminoheterocycle of general formula EMI243.2 wherein R, R1, R2, R8 t L and A are groups as defin.ed in claim 1 inert under the reaction conditions; (f) displacing one or both chlorine atoms in the heterocyclic moiety of a compound of general formula EMI243.3 (wherein R, R,, R2 and L are as defined in claim 1 and Z is N or CH), by alkoxy groups within the definitions of X and Y in claim 1; ; (g) reacting together compounds of general formulae EMI243.4 wherein R, R1, R2r L and A are as defined in claim 1, to obtain a compound of claim 1 wherein W is S; (h) reacting a compound of claim 1 wherein L is OH with EMI244.1 wherein R11 is as defined in claim 1, to obtain a compound of claim 1 wherein L is OC(O)R11; (i) reacting a compound of claim 1 wherein L is OH with an isocyanate of general formula R12NCO wherein P12 is. as defined in claim 1, to obtain a compound of claim 1 wherein L is OC(O)NHR12; ; (j) reacting a compound of claim 1 wherein L is OH with a chloroformate of general formula EMI244.2 wherein-R13 is as defined in claim 1, to obtain a campound of claim 1 wherein L is OC (O) OR13 (k) reducing a compound of general formula EMI244.3 or an ester thereof to obtain a compound of claim 1 wherein R1 and R2 are H and R, R8 and A are as defined in claim 1; (1) reducing a ketone of general formula EMI244.4 wherein R, P8 and A are. as defined in claim 1, to obtain a compound of claim 1 wherein R1 is H, R2 is CH3 and L is OH; or reacting said ketone with methyl lithium to obtain a compound of claim 1 wherein R1 and R2 are CH3 and L is OH, the substituent groups containing no displaceable halogen, NO2 or CN; or (m) reacting a compound of general formula EMI245.1 wherein R, P8 and A are as defined in claim 1, with the proviso that they contain no displaceable halogens, N02 or CN, with methyl lithium to obtain a compound of claim 1 wherein R1 is H, R2 is CH3 and L is OH.

Inventors: FARNHAM, WILLIAM BROWN, LEVITT, GEORGE, PETERSEN, WALLACE CHRISTIAN, SAUERS, RICHARD FRANK, SCHWING, GREGORY WAYNE
Applicants: E.I. DU PONT DE NEMOURS AND COMPANY
Application year: 1981
Main classification: C07D239
IPC codes: C07D239, A01N47, C07D295, C07D251, C07D521