PROCESS FOR FORMING A CERAMIC-LIKE INSULATION

Abstract: An improved insulation of a coil for electric apparatus is disclosed in which an insulated wire is wound to form a coil (18) which is them impregnated with an impregnant comprising a suspension of an organosilicon compound and a synthetic fluoro-mica in an organic solvent, followed by curing. A fluoro-compound vaporized from the synthetic fluoro-mica in the high temperature is combined with a siloxane decomposed from the organosilicon compound thereby to provide a ceramic formation.

Description: An improved insulation of a coil for electric apparatus This invention relates to an insulation of a coil for electric apparatus useful in an atmosphere of high temperatures above 3000C. Heretofore, an insulation of a coil for rotary electric apparatus and the like has been formed by placing an insulating layer of tapes or sheets mainly consisting of synthetic resin or natural mica along an inner surface of a slot adapted to receive the coil, accommodating the conductive coil of an insulated and wound wire into the slot with mounting of a wedge and then impregnating the resultants with an impregnant of a suspension of a natural laminated mica in a solvent of organo-silicon compound thereby to fill up gaps formed between the coil and the insulating layer as well as the inner gaps of the coil per se. In such the insulation, however, the organo-silicon compound is thermally degradated in an atmosphere of an elevated temperature above 300 C with undesired loss of the bonding ability between the filled insulating medium and the insulating layer and thus with reduction of the mechanical and dielectric strengths. A general object of the invention is to eliminate the disadvantage of the conventional insulation described hereinbefore and to achieve an improvement thereof by providing an insulation of coil which may be used in an atmosphere of an elevated temperature above 300 C with negligible reduction of the mechanical and dielectric strengths. To achieve the foregoing object, an insulation of a coil for the electric apparatus according to the invention is characterized in that an insulated wire is wound to form a coil which is then impregnated with an impregnant consisting of a suspension of an organosilicon compound and a synthetic fluoro-mica in an organic solvent followed by curing and that a fluoro-compound vaporized from said synthetic fluoro-mica in an atmosphere above 3000C is combined with a siloxane decomposed from said organosilicon compound thereby to provide a ceramic formation. The coil of the insulated wire may be a coil for an electric motor or a coil for an electric transformer. The impregnated and cured material of the impregnant may be preheated to not lower than 3000C to provide a ceramic formation or made into a ceramic formation when used in an atmosphere of an elevated temperature of not lower than 300 C. Further, the impregnant is prepared by suspending small pieces of synthetic fluoro-mica having a length of not more than 5 nm with a diameter of 0.1 to 5 m in a solvent of organosilicon compound in a weight ratio of not less than 1 : 1 together with an organic solvent. The organic solvent may be of a mixed solvent of xylene, butylcellosolve and cellosolve acetate. The insulation of the coil for the electric apparatus according to the invention is substantially comprised of an iron core, a slot formed in the iron core, an insulating sheet for earth of a double sided laminated mica sheet which is circumferentially placed in the slot, an interphase insulating sheet of a laminated mica plate, conductive coils placed in the insulating sheet with separation through an insulating sheet and a wedge member for supporting the elements. The conductive coils may preferably be coated with nickel. Other objects and advantages of the invention will become obvious after considering the detailed description of the invention in connection with the preferred embodiments thereof shown in the accompanying drawings. One way of carrying out the invention is described in detail below with reference to drawing which illustrate preferred embodiments, in which : Figure 1 shows a sectional side view of an insulation of a coil for the electric apparatus according to the present invention. In the drawing , an insulation of a coil for the electric apparatus according to the invention is comprised of an iron core 10, a slot 12 formed in the iron core 10, an insulating sheet for earth of a sided laminated mica sheet 14 which is circumferentially placed in the slot 12, an interphase insulating sheet of a laminated mica plate 16, conductive coils 18, 18 placed in the insulating sheet 14 with separation through an insulating sheet 16 and a wedge member 20. The conductive coils are preferrably made of copper wire, the surface of which is coated with nickel for protection from the thermal oxidation. An impregnant 22 may be prepared by suspending small pieces of synthetic fluoro-mica having a length of not more than 5 nm with a diameter of 0.1 to 5 Vm in a solvent of organosilicon compound in a weight ratio of not less than 1 : 1 together with an organic solvent such as a mixed solvent of xylene, butylcellosolve and cellosolve acetate, followed by impregnation and curing. Thus impregnated and cured material is further heated to not lower than 3000C or used in the atmosphere of an elevated temperature not lower than 300 C, thereby to vaporize some fluoro-compound such as SiF4, KF and the like, from the synthetic fluoro-mica, which is combined with siloxane derived from the organosilicon compound thereby to provide a ceramic formation. Now referring to an embodiment of an insulation of the coil for 22 KW motor, the iron core into the slot 12 of which are inserted the insulating sheet for earth 14, the interphase insulating sheet 16, the conductive coil 18 and the wedge member 20 is preheated at l200C to remove moisture of each material. Thereafter, the iron core is cooled to 40 - 500C and is then immersed in the organosilicon solvent containing the suspended synthetic fluoro-mica for approximately 10 minutes for subsequent driness in air for about one hour and thereafter heat-dried at about 800C for two hours. Further, driness takes place at about l200C for 2 hours to remove the solvent and then heated at not lower then 2000C for 2 hours with curing. The following table shows the comparison of the invented coil with an insulated coil impregnated with TEFRON (trade mark) material, showing the fact that the heat-resistant coil with the TEFRON material to 4000C for about 1300 hours after exposed reduces greatly the dielectric strength of insulation with loss of the function of the apparatus, whereas no reduction of the dielectric strength may be seen in the insulated coil according to the invention as compared with the originals, even after exposed to 4000C for 1400 hours. ( Unit : KV ) EMI4.1 <tb> Insulated <SEP> Coil <tb> <SEP> Invented <SEP> Coil <SEP> with <SEP> TEFRON <SEP> Material <tb> <SEP> After <SEP> use <SEP> After <SEP> use <tb> <SEP> Initial <SEP> at <SEP> After <SEP> Initial <SEP> atAfter <tb> <SEP> for <SEP> 1400 <SEP> hrs. <SEP> for <SEP> 1300 <SEP> hrs. <tb> <SEP> Dielectric <SEP> Strength <SEP> 3.95 <SEP> 3.92 <SEP> 3.45 <SEP> 1.04 <tb> <SEP> between <SEP> phases <tb> <SEP> Dielectric <SEP> Strength <SEP> 3.80 <SEP> 4.32 <SEP> 4.80 <SEP> 0.90 <tb> <SEP> for <SEP> earth <tb> As described hereinbefore, in accordance with the invention the coil is impregnated with the impregnant having suspended the synthetic fluoro-mica in the solvent of the organo-silicon compound which is then cured. In the atmosphere of high temperature, the fluoro-compound vaporized from the synthetic fluoro-mica is combined with the siloxane decomposed from the organosilicon compound thereby to provide the ceramic formation, thus resulting in the excellent properties in the mechanical and dielectric strength of the insulation as well as the absence of thermal degradation in the high temperature. Especially in the insulation of the coil for the rotary electric apparatus, the impregnation within the slot may be adequately ensured due to the small particle size of the synthetic fluoro-mica so that any failure or damage of the insulated coil through vibration or impact may be avoided. While the insulation of the conductive coil for the rotary electric apparatus has been described hereinbefore with reference to the appended drawing, it will still be appreciated that the invention should not be limited thereto but applicable to the insulation of the conductive coil for a transformer and the like, and that the impregnation may be performed by spraying, application, molding or others in lieu of the immersion employed in the embodiment. Without further elaboration, the foregoing will so fully illustrate the invention that others may, by applying the current or future knowledge, readily adapt the same for use under various conditions of service.

Claims: Claims 1. An insulation of a coil for an electric apparatus characterized in that an insulated wire is wound to form a coil (10) which is then impregnated with an impregnant comprising a suspension of an organosilicon compound and a synthetic fluoro-mica in an organic solvent followed by curing and that a fluoro-compound vaporized from said synthetic fluoro-mica in an atmosphere above 3000C is combined with a siloxane decomposed from said organosilicon compound, thereby to provide a ceramic formation. 2. An insulation of a coil for an electric apparatus as claimed in Claim 1, wherein the coil of the insulated wire is a coil for an electric motor. 3. An insulation of a coil for an electric apparatus as claimed in Claim 1, wherein the coil of the insulated wire is a coil for an electric transformer. 4. An insulation of a coil for an electric apparatus as claimed in Claims 1 to 3, wherein the impregnated and cured material of the impregnant is preheated to not lower than 3000C to provide a ceramic formation. 5. An insulation of a coil for an electric apparatus as claimed in Claims 1 to 3, wherein the impregnated and cured material of the impregnant is made into a ceramic formation when used in an atmosphere of an elevated termperature of not lower than 300 C. 6. An insulation of a coil for an electric apparatus as claimed in Claim 1, wherein the impregnant is prepared by suspending small pieces of synthetic fluoro-mica having a length of not more than 5 nm with a diameter of 0.1 to 5 um in a solvent of organosilicon compound in a weight ratio of not less than 1 : 1 together with an organic solvent. 7. An insulation of a coil for an electric apparatus as claimed in Claim 6, wherein the organic solvent is a mixed solvent of xylene, butylcellosolve and cellosolve acetate. 8. An insulation of a coil for an electric apparatus as claimed in Claim 1, wherein an iron core (10), a slot (12) formed in said iron core (10), an insulating sheet for earth of a double-sided laminated mica sheet (14) which is circumferentially placed in the slot (12), an interphase insulating sheet of a laminated mica plate (16), conductive coils (18) placed in the insulating sheet (14) with separation through the interphase insulating sheet (16) and a wedge member (20) for supporting the elements are provided. 9. An insulation of a coil for an electric apparatus as claimed in Claim 1, wherein conductive coils (18) are coated with nickel.

Inventors: MIYAZAKI, HARUO C/O YASUKAWA ELECTRIC MFG., OSHIYAMA, TSUTOMU C/O YASUKAWA ELECTRIC MFG., YAMASAKI, YASUAKI C/O YASUKAWA ELECTRIC MFG.
Applicants: NIKKISO CO., LTD.
Application year: 1981
Main classification: H01F5
IPC codes: H01B3, H02K3, H01F41