METHOD AND APPARATUS FOR PREVENTING STRATIFICATION OF LIQUEFIED GASES IN A STORAGE TANK

Abstract: A technique for the storage of multi-component li­ quefied gases such as liquefied natural gases (LNG), li­ quefied petroleum gases (LPG) or the like which are different in composition, density or the like, and which therefore tend to stratify in a storage tank. The liquefied gas is introduced into the storage tank (3) in the form of a jet of liquefied gas 5 from a nozzle (6) near the tank bottom, at an angle of elevation in the range 60° to 90° and reaches or comes near to the free surface within the storage tank. By this means the introduced liquefied gas (5) mixes with the liquefied gas (4) previously existing in the storage tank and stratification is effectively prevented.

Description: METHOD AND APPARATUS FOR PREVENTING STRATIFICATION OF LIQUEFIED GASES IN A STORAGE TANK The present invention relates to a method for preventing any stratification of the liquefied gases within a storage tank, and more particularly the present invention relates to improvements in and relating to a method and apparatus for introducing liquefied gas into a storage tank whereby when the multi-component liquefied gases comprising different kinds of liquefied gas such as liquefied natural gas (LNG) or liquefied petroleum gas (LPG) are stored in the same storage tank, the liquefied gas already existing in the storage tank and the newly introduced liquefied gas are prevented from being formed into separate strata within the storage tank due to differences in composition, density, temperature or the like. With a multi-component liquefied gas, e.g., LNG, it is well known in the art that the gases of different origins differ in composition and density from one another and the same applies to those from the same origin but extracted on different days. When such a multi-component liquefied gas is introduced into a storage tank from a transport ship or the like, while there will be no problem if the storate tank is filled with the gases of the same composition (those of the same origin and the same extraction date), if the remaining quantity of the previously introduced gas is small so that the storage tank has a space in surplus and thus a new supply of liquefied gas of a different composition or temperature is introduced into the storage tank, the heavy and light gases do not mix together due to differences in density and these gases are formed into vertically separated strata. The formation of these strata may sometimes cause a dangerous phenomenon which is known as a roll over phenomenon. The roll over phenomenon is one in which when multicomponent liquefied gases which are different in composition and hence in density are contained in the same storage tank as mentioned previously, a stratum of higher density gas and a stratum of lower density gas will be formed as vertically separate strata; in the case of for example LNG liquefied at a very low temperature of -1620C, naturally there is a heat input through the outer walls of the storage tank so that due to the nature of the boundary surface of the vertically formed two strata that it is stable and its amount of heat transfer is small, the heat is accumulated in the lower stratum of the lower desntiy liquefied gas and the thus accumulated heat energy is rapidly dispersed in the form of evaporation of a large quantity of the liquid. As a result, there is the danger of the inner pressure exceeding the control range of the storage tank inner pressure and becoming higher than the designed limit pressure. The desity of LNG differs depending on the place of 3 origin, that is, the density of LNG from Alaska is 424 Kg/m3, that of LNG from Brunei is 473 Kg/m3 and so on. If such LNGs having different densities are introduced into the same storage tank, a vertical stratification will be caused by the differences in density and the above-mentioned roll over phenomenon may sometimes be caused. Thus, the usual practice to prevent this phenomenon has been such that LNG of different origins are stored in separate storage tanks and thus even the amount of the stored gas is as small as about one fifth of its holding capacity thus leaving a sufficient space in surplus, any LNG having a different composition and hence a different density will never be introduced into the storage tank. In other words, if the previously introduced liquefied gas is in excess of about 1/5 of the holding capacity of the storage tank, any other LNG having a different composition is not introduced into the storage tank and the remaining space is left unused. While this prevents the occurrence of any roll over phenomenon, the present situation is such that the number of storage tanks installed at a harbor or along the coast is in excess of the required number exceeding the actual holding capacity so that not only a vast plot of ground is required but also the cost amounts to a huge sum due to the installation of refrigerating equipment for maintenance of the facilities. Under these circumstances, as an anti-stratification measure, an attempt has heretofore been made such that when the amount of LNG contained in a storage tank is considerably less than its holding capacity, a filling nozzle is introduced into the LNG and LNG of a different composition is introduced to stir up and mix the two. The conventional filling nozzle used in this attempt has not been designed in consideration of mixing the liquefied gases having large differences in density and thus the jet of gas issued from the nozzle has failed to reach the free surface of the LNG within the storage tank thus making it impossible to stir up and mix the LNGs having large differences in density. Summary of the Invention. The present invention has been created to overcome the foregoing deficiencies in the prior art and it is the primary object of the present invention to prevent any stratification of multi-component system liquefied gases such as LNG or LPG within a storage tank due to differences in composition and also to prevent the occurrence of a roll over phenomenon. In accordance with one form of the present invention, the introduction of a multi-composition system liquefied gas into a storage tank is effected in such a manner that a jet stream of the introduced liquefied gas issues from near the tank bottom obliquely upwardly with a predetermined angle of elevation within the storage tank and reaches or comes near to the free surface. The angle of elevation or the issuing angle can be defined as an angle e made by the jet stream axis with the horizontal plane and this issuing angle is selected within a range of 600 < 0 < 900 as will be described later. In accordance with another form of the invention, the liquefied gas is introduced into the storage tank in the form of the obliquely upward jet of liquefied gas as a main jet and an additional secondary jet of liquefied gas in a relatively small quantity which is directed toward the tank bottom area from an issuing point lower than the main jet issuing point. The method involving the secondary jet of liquefied gas can be advantageously used particularly in cases where a newly introduced and issued liquefied gas is lower in density than the liquefied gas already existing in the storage tank. In this case, the issuing angle 0 of the main jet of liquefied gas is selected within a range 0 0 60 < o L 80 . 80 In accordance with one form of a filling apparatus according to the invention, a filling nozzle arranged inside a storage tank to create the obliquely upward jet of liquefied gas is hung down into the storage tank such that the nozzle injection axis is directed obliquely upward and this ascending vertical angle provides the previously mentioned issuing angle O. In accordance with another form of the apparatus, the filling nozzle hung down into the storage tank to create the obliquely upward jet of liquefied gas includes a main nozzle whose angle e of injection from its nozzle tip forms an elevation angle in the range of 600 < 0 < 900 and an auxiliary nozzle which is communicated with the main nozzle to direct a jet of liquefied gas of a relatively small quantity into the tank bottom area. In accordance with the method of this invention, with a storage tank for storing mult-component system liquefied gas such as LNG or LPG, liquefied gases of different densities can be introduced and issued into the tank. In this case, a filling nozzle having a predetermined injection or issuing angle in accordance with the invention is used and hung down into the liquefied gas previously stored in the storage tank so that a new supply of liquefied gas is introduced and issued into the storage tank through the filling nozzle. This has the effect of stirring up and mixing the fresh supply of liquefied gas issued from the filling nozzle and the previously stored liquefied gas at the time of the filling, with the result that the prevention of stratification is ensured even in the case of the multi-component system liquefied gases having large differences in density and the occurrence of the roll over phenomenon is prevented. Further, while, in the past, the introduction of any replenishing supply of liquefied gas of a different composition is avoided in order to prevent the occurrence of stratification and roll over phenomenon even if a storage tank has a surplus space, in accordance with the method of this invention the introduction of a new supply of liquefied gas having a different density is possible for replenishing purposes. Thus, the storage tank can be filled with such liquefied gases up to its holding capacity and effective utilization of the storage tank is ensured. Therefore, the present invention greatly contributes industrially. More specific embodiments of the invention, together with its functions and effects, will be readily understood from the detailed description taken in conjunction with the accompanying drawings. Brief Description of the Drawings. Figs. la and ib are schematic views of conventional filling nozzles. Fig. 2 is a schematic diagram showing the manner in which a jet of gas is issued from the filling nozzle of Fig. lb. Fig. 3 is a basic flow diagram showing the use of a filling nozzle according to the present invention. Fig. 4 is a diagram showing the flow conditions of the liquefied gases within a storage tank into which the liquefied gas having a different density is issued in accordance with the invention. Fig. 5 is a diagram showing the flow condition of the liquefied gas in a case where the issuing angle o < 600 Fig. 5b is a diagram showing the flow condition of the liquefied gas in another case where the issuing angle o 7 600. Fig. 6 is a diagram for explaining the formation of strata due to the differences in density of the gases. Fig. 7a is a diagram similar to Fig. 5a but using two of the filling nozzle of Fig. 5a. Fig. 7b is a diagram similar to Fig. 5b but using two of the filling nozzle of Fig. 5b. Fig. 8 is a graph showing the relation between the issuing angle of the filling nozzle and the height of jet stream. Figs. 9 and 10 are schematic perspective views showing preferred forms of the filling nozzle used with the present invention. Description of the Preferred Embodiments. Prior to a detailed description of the invention, the prior art will be described briefly with reference to Figs. 1 and 2. In Figs. 1a and ib showing conventional filling nozzles, numeral 1 designates a filling nozzle and numeral 2 designates the issuing direction or the axis of injection from each nozzle tip. Fig. 2 shows by the dotted lines the behavior of the jet of gas resulting when a second LNG 5 of a different composition is introduced through the filling nozzle of Fig. ib which is hung down into a storage tank 3 storing a first LNG 4 which was introduced preliminarily. As will be seen from Fig. 2, due to the issuing angle of the conventional filling nozzle being directed in a horizontal direction parallel to the bottom surface of the storage tank 3, while the gases may be stirred up and mixed together in cases where the initial depth of the first LNG 4 is small or the density difference of the introduced second LNG 5 is relatively small, the jet of gas issued from the nozzle tip 2 cannot reach or come near to the free surface of the previously stored first LNG 4 if the initial depth is large or the density difference is large. Thus, in such a case, when the second LNG is introduced into the storage tank, the stirring and mixing of the upper and lower gases cannot be effected satisfactorily and the formation of strata is still unavoidable. Fig. 3 shows a flow diagram for explaining a basic example of the method according to the invention, in which LNG is introduced into a storage tank 3 from an LNG transport ship 7 via a filling line pipe 8. More specifically, a filling nozzle 6 is hung down into the preliminarily stored LNG 4 in the storage tank 3 and LNG 5 having a different density is introduced into the storage tank 3 via the filling nozzle 6. In this case, from the standpoint of improving the effect of this invention it is desirable to arrange a pressure pump 9 in the line pipe 8 so as to increase the feeding rate of the LNG 5. Numeral 15 designates a submerged pump for delivering the gas to the outside of the storage tank 3. The principle of preventing stratification of the multicomponent system liquefied gases in a storage tank in accordance with the invention will now be described. Where the storage tank already contains a first multi-component liquefied gas such as LNG in an amount corresponding to about 1/5 to 2/3 of its holding capacity and thus there is still a surplus space, if a second LNG which is different in composition or density from the first LNG within the storage tank is introduced into the tank, that is, if the density p of the second liquefied gas is different from the density Ph of the first liquefied gas which was previously stored in the storage tank, as shown in Fig. 4, the second liquefied gas of the density pre p swallows up the first liquefied gas of the density Ph so that the first and the second liquefied gases are stirred up and mixed during the introduction. If the injection angle O of the filling nozzle 6 is less than 600, as shown in Fig. 5a, the angle of jet is too small so that the resulting jet of gas may fail to reach or come near to the free surface or the jet of gas may strike against the side walls of the storage tank with the resulting deterioration of the swallow-up, thus deteriorating the effect of the nozzle. In other words, if the issuing angle is not proper, there is the disadvantage of causing a density distribution in the following manner. For instance, where the densities Pc and ph are p < ph and the initial depth of the first liquefied gas with the higher density ph is relatively small, if the issuing angle O of the second liquefied gas with the density Pc has an elevation angle of less than 600, the jet stream of the second liquefied gas decreases its flow velocity in the first liquefied gas and thus the second liquefied gas is partially distributed within the storage tank without sufficiently swallowing up the first liquefied gas. As a result, the gases are stored in such a manner that the lighter second liquefied gas floats to the surface and the introduction and filling of the second liquefied gas is completed without the second liquefied gas being sufficiently mixed with the heavier first liquefied gas as shown in Fig. 6 upon completion of the introduction. Thus, the densities Pc and Ph result in the formation of a density distribution Q and this results in the formation of strata. In accordance with the present invention, the issuing angle from the nozzle tip of the filling nozzle is selected 600 < 0, and Fig. 5b shows the manner of mixing resulting from the use of the filling nozzle in accordance with this intention of the invention. It is also shown that where a plurality of the filling nozzles are used as in the cases of Figs. 7a and 7b, if the issuing angle is o < 600 as in the cases of Figs. 5a and 5b, the resulting mixing effect is insufficient and that an excellent mixing effect is ensured 0 with the intended issuing angle of 60 < 0 in accordance with the invention. Where a first liquid having a uniform density is contained in a storage tank and a second liquid having a higher density is issued into the first liquid upwardly with an angle 0, the resulting issuing height h is determined in accordance with the nozzle jet diameter, the density difference and the flow rate with the angle e as a parameter. As a result, the height h can be said to be directly proportional to a quantity H having a unit of length and determined in accordance with three physical quantities including the nozzle jet diameter, the density difference and the flow rate and it has been confirmed experimentally by the inventors, etc., that its proportionality constant C varies with the angle 0 as shown in Fig. 8. It will be seen from the experimental results in Fig. 8 that the rate of rise in the height of jet increases with increase in the angle 0 when the angle 0 is in the range from 0 to 600, that the rate of rise remains substantially constant when the angle 0 is in the range from over 600 to 800 and that the rate of rise decreases when the angle 0 reaches 900. Thus, the most desirable range of O is from over 600 to 800 and the effect of the nozzle deteriorates when the angle 0 reaches 900. Thus, in order to achieve the desired effect of the invention it is necessary that the angle 0 is in the range of 600 < 0 < 900. This can be conceived to be attributable to the fact that the efficiency of mixing in the vertical direction increases with increase in the height of jet of gas. Fig. 9 is a schematic perspective view of a filling nozzle which is suitable for use in performing a first embodiment of the method according to the invention. In the Figure, numeral 12 designates a filling nozzle proper, and 10 nozzle jet tips whose issuing angle has an elevation angle in the range 600 < o < 900 for the previously mentioned reasons. Fig. 10 is a schematic perspective view of another filling nozzle which is suitable for use in performing a second embodiment of the method according to the invention In the Figure, numeral 13 designates a filling nozzle proper, and 14 a main nozzle whose issuing angle has an elevation angle o of 600 < e < 900 for the reasons mentioned previously. Numeral 11 designates an auxiliary nozzle which is made integral with the main nozzle 14 and communicating with the lower part thereof. Then, in accordance with the present invention the issuing angle o of the filling nozzle is selected in the range 600 < 0 < 900 for the reasons that if the angle 0 is 0 less than 60 , the value of the previously mentioned pro- portionality constant C becomes insufficient so that the resulting jet of gas fails to reach or come near to the surface of the liquefied gas or the jet of gas directly strikes against the side walls of the storage tank thus failing to expect the desired stirring and mixing effect, 0 and that if the angle 8 is 90 or over, the height of gas jet becomes as low as when the angle 0 is less than 600 Thus, the most desirable angle 0 is in the range from 600 to 800. On the other hand, the auxiliary nozzle 11 is provided for the reason that if the density of the LNG introduced preliminarily into the storage tank is higher than that of the LNG which is introduced later, there is the possibility of the higher density LNG being detained in the tank bottom portion thus causing the formation of strata, and this possibility is prevented by the auxiliary nozzle 11.

Claims: What is claimed is: 1. A method of introducing and issuing a multi-component system liquefied gas into a storage tank, characterized by the step of introducing said multi-component system liquefied gas into said storage tank such that said liquefied gas is issued obliquely upwardly within said storage tank from near the bottom portion thereof with a predetermined angle of elevation in the range from over 600 to less than 900 and thereby forming a jet of said liquefied gas which reaches or comes near to a free surface. 2. A method according to claim 1, wherein said jet is formed in another liquefied gas previously existing in said storage tank. 3. A method according to claim 1, wherein a secondary jet of said introduced liquefied gas is formed simultaneously with said primary jet of said introduced liquefied gas, said secondary jet being relatively small in quantity and directed toward a bottom area of said storage tank from a position lower than the issuing point of said primary jet. 4. An apparatus for introducing and issuing a multi-component system liquefied gas into a storage tank, characterized by filling nozzle means disposed within said storage tank such that said nozzle means has its axis of injec tion directed obliquely upwardly to form an angle of elevation which is over 600 and less than 900. 5. An apparatus according to claim 4, wherein said nozzle means comprises a main nozzle whose axis of injection is directed obliquely upwardly to form an angle of 0 0 elevation which is over 60 and less than 90 , and an auxiliary nozzle formed to communicate with a lower part of said main nozzle to direct a jet of relatively small quantity of said liquefied gas toward a bottom area of said storage tank.

Inventors: ISHIWATARI, TAKEO, MISAWA, ROKURO, SASAKI, YASUCHIYO, SHINGO, TAKAO
Applicants: NIPPON KOKAN KABUSHIKI KAISHA
Application year: 1981
Main classification: F17C6
IPC codes: F17C13, F17C6