COMPOSITE UNSTRETCHED THERMO-DEFORMABLE PLASTICS FILM AND DEEPDRAWN CONTAINER SHAPED FROM SAID PLASTICS FILM

Abstract: Composite unstretched plastics film consisting of a polyolefin film (1) laminated by means of an intermediate primer (2) with a polyvinylidene chloride or vinylidene chloride copolymer (3), having a thickness of 6 to 6,5 µm, the polyolefin film having a thickness of 800 µm. Containers are obtained by deep-drawing said film.

Description: Composite unstretched thermo-deformable plastics film and deepdrawn container shaped from said plastics film. The invention relates to a composite unstretched thermodeformable plastics film, consisting of a polyolefin film laminated with a polyvinylidene chloride or a vinylidene chloride copolymer layer by means of an intermediate primer or adhesion layer. Packings or wrappings for spoilable products, for example food-stuffs, which products have to be consumable during a long period of time without any preserving agents being added thereto, should be of an optimum quality, especially as regards the gas density. Actually, the aforementioned packings or wrappings should have the same beneficial properties as tins or glass jars, to wit their oxygen and/or carbon dioxide permeability should be very low. In order to meet these requirements, a composite unstretched plastics film is already known, which consists ofa polypropylene film laminated with a polyvinylidene chloride or a vinylidene chloride copolymer layer by means of a polyurethan primer and subsequently being coated by a second polypropylene film . The structure of this known composite unstretched plastics film consists therefore, of a polyvinylidene chloride or vinylidene chloride copolymer layer being laminated at either side with polypropylene film. The polyvinylidene chloride or vinylidene chloride copolymer layer concerned has a thickness ranging from 8 to 20 trim. Such a coating with a polypropylene film at either side of the polyvinylidene chloride or vinylidene chloride copolymer layer, is essential, so as to avoid a delamination of the various layers of the composite unstretched plastics film when high temperatures are exerted, e.g. in case of a deformation or of sterilization by steam. Although the said composite unstretched plastics film has many attractive characteristics, its structure consisting of three layers, is unsatisfactory, as a structure of that type is rather expensive. Furthermore, the desired thickness of the polyvinylidene chloride or vinylidene chloride copolymer layer can only be obtained by repeatedly spreading a dispersion of the respective polyvinylidene chloride or the vinylidene chloride copolymer layer on the sides concerned. The present invention aims to provide a composite unstretched plastics film of the abovementioned type which does not present the disadvantages as mentioned hereinbefore. According to the invention this object is attained in that in a composite unstretched plastics film consisting of a polyolefin film laminated with a polyvinylidene chloride or vinylidene chloride copolymer layer by means of an intermediate primer or adhesion layer, the polyvinylidene chloride or vinylidene chloride copolymer layer has a thickness comprised between 5 to 7 pm. Actually, the surprising fact has emerged that a composite unstretched plastics film in accordance with the present invention possesses on the one hand sufficien gas barrier properties, whilst, on the other hand, the phenomenon cf delamination will not be exhibited while deforming the respective plastics film by deep-drawing or by sterilization. The respective polyvinylidene chloride or vinylidene chloride copolymer layer having a thickness ranging from 5 to 7 pm, can advantageously be applied in one single action, so causing the productive capacity of the relative composite unstretched thermo-deformable plastics film to be consilerubly accelerated. Notwithstanding the fact that t said polyvinylidene chloride or vinylidene chloride copolymer layer will become thinner when forming containers by deep-drawing composite unstretched plastics films of this type, the formed container obtained by deep-drawing, wi# have sufficient gas barrier properties, so that spoilable products, for instance a.o. food-stuffs, may be safely packaged in said container, without adding any preserving agents. The polyvinylidene chloride or vinylidene chloride copolymer layer preferably has a thickness of 6 to 6,5 sm. Although the thickness of the respective polyolefin film is not restricted to predetermined limits, a polyolefin film which has a thickness comprised between 250 and 1.800 tum and more preferably of 800 vm is recommended. As a polyolefin preferably polypropylene is employed. The composite unstretched plastics film, resulting from the use of a thickness of 6 to 6,5 pm for the respective polyvinylidene chloride or vinylidene chloride copolymer layer, is apt to be optimally thermo-deformable by deep-drawing. Although it is known in the art to coat polyethylene-coated paper with thin coatings of polyvinylidene chloride or vinylidene chloride copolymer, said paper materials are not subjected to deep-drawing operations. The respective polyvinylidene chloride or vinylidene chloride copolymer layer is preferably applied by means of gravure rollers which operation is also effectively used for applying the intermediate primer or adhesion layer. The present invention is likewise embodied in a deep-drawn container, obtained by using a composite unstretched plastics film material, consisting of a polyolefin film, laminated with a polyvinylidene chloride or vinylidene chloride copolymer layer, by means of a primer or adhesion layer, said polyvinylidene chloride or vinylidenechloride copolymer layer having a thickness of 5 to 7 Um. The present invention will be illustrated by way of example only, with respect to some embodiments in the accompanying drawing, wherein: Fig. 1 is a section through a composite film in accor dance with the invention, and Fig. 2 is a container formed by deep-drawing a composite film of the said type. EXAMPLE A polypropylene film 1 having a thickness of 800 pm is provided with a polyurethan primer layer 2, by means of a gravure roller. If desired, said polypropylene film may be subjected to a pretreatment known per se, in order to apply the aforementioned layer. After having completed the aforementioned operation, said gravure rollers apply a layer 3, consisting of polyvinylidene chloride or vinylidene chloride copolymer having a thickness of 6,5 ym, starting from a 907;f dispersion of polyvinylidene chloride. After having applied said polyvinylidene chloride or vinyl chloride dene copolymer layer a composite film is obtained as shown in fig. 1, said film having at 200C an oxygen permeability of 6,3 Ncm3.m#2.24 .atm. the oxygen permeability of the polypropylene film proper amounting to 184 Ncm3. 24h-1 -1 atm. By deepdrawing said composite unstretched plastics film at a temperature of about 1400C, a shaped container (see fig. 2) is obtained which possesses excellent gas barrier properties, so that a container of this type can be used for packaging spoilable products, such as foodstuffs, without adding any preserving agents. The oxygen permeability of a container of 400 cm having a surface of approximately 390 cm2, amounts to 0,126 Ncm3.24 h 1. 1 atm. . The obtained containers may be effectively sterilized. During a sterilization period of 30 min. at a temperature of 1150C no delamination phenomena will occur in the respective container. The foregoing describes a polypropylene film having a thickness of 800 um, but obviously, various film thicknesses may be employed, dependent upon the respective uses.

Claims: Claims 1. Composite unstretched thermo-deformable plastics film consisting of a polyolefin film laminated with a polyvinylidene chloride or a vinylidene chloride copolymer layer by means of an intermediate primer or adhesion layer, chatacterized in that the polyvinylidene chloride or the vinylidene chloride copolymer layer has a thickness comprised between to 7 Um. 2. Composite unstretched thermo-deforinable plastics film, in which the said polyvinylidene chloride or vinylidene chloride copolymer layer has a thickness of 6 to 6,5 pm. 3. Composite unstretched thermo-deformable plastics film, in accordance with claims 1 or 2, in which the polyolefin film consists of an unstretched polypropylene film. 4. Composite unstretched thermo-deformable plastics film according to any or more of the preceding claims, in which the polyolefin film consists of an unstretched polypropylene film, having a thickness ranging from 250 to 1800 pm, and more preferably of 800 ym. 5. Composite unstretched thermo-deformable plastics film according to any one or more of the preceding claims, in which the respective polyvinylidene chloride or vinylidene chloride copolymer layer is applied by means of gravure rollers. 6. Conposite unstretched thermo-deformable plastics film according to any one or more of the preceding claims, in which the said primer or adhesion layer is applied by means of grovure rollers. 7. Deep-drawn shaped container, the said container being obtained by deep-drawing a composite unstretched plastics film consisting of a polyolefin film, laminated with a polyvinylidene chloride or vinylidene chloride copolymer layer by means of an intermediate primer or adhesion layer, the polyvinylidene chloride or vinylidene chloride copolymer layer having a thickness of 5 to 7 pm and more preferably of 6 to 6,5 pm.

Inventors: HAASBROEK, THOMAS JEAN, NIJMAN, MARINUS
Applicants: WAVIN B.V.
Application year: 1980
Main classification: B29C17
IPC codes: B65D65, C08J7, B29C51, B32B27