POLYESTER COMPOSITIONS AND PROCESSES FOR MOULDING THEM

Abstract: Compositions comprising (i) thermoplastic polyester of aliphatic diol, and dicarboxylic acid, at least 95% mole of said acid being terephthalic acid and (ii) inert particulate nucleat­ ing agent further contain, as a crystallization promoter, (iii) oligomeric polyester of organic dicarboxylic acid having 2 to 8 carbon atoms and organic polyol and having a Flory Interac­ tion Patameter with said polyester below or equal to 0.2. The compositions are useful moulding compounds, the crystalli­ zation promoter enabling crystalline moulded products to be obtained at low mould temperatures. Moulding processes of the invention are carried out at less than 100°C mould temp­ eratures.

Description: POLYESTER COMPOSITIONS AND PROCESSES FOR MOULDING THEM This invention is concerned with polyester compositions and processes for moulding them. The field of this invention is the improvement of the crystallization rate and moulding behaviour of polyesters, in particular poly(alkylene terephthalate). The use of inert particulate nucleating agents to promote crystallization of poly(alkylene terephthalate) is very well known. Mold temperatures of at least 120C and optimumly 1400C in the case of poly(ethylene terephthalate) (PET) have generally been necessary for injection molded engineering applications. In the case of PET, because of its low rate of crystallization at desirable molding temperatures of less than 1000C, it has not attained widespread use as an engineering plastic. When PET is molded with conventional nucleating agents at temperatures below 100 C, it generally has poor physical properties, surface appearance and dimensional stability due to insufficient crystallization. Various attempts have been made to improve the crystallization rate of PET. For example, the use of poly(ethylene oxide) or poly(propylene oxide) having hydroxyl functionality has been suggested in combination with nucleating agents; however, this method is undesirable because the PET reacts with the hydroxyl functionality to give a resin with lower molecular weight and poorer physical properties. The use of low molecular weight inert organic solvents such as benzophenone and phthalate plasticizers such as dioctyl phthalate have been suggested, but the use of such plasticizers alone is not desirable because they cause processing difficulties due to their high volatility under drying or processing conditions for PET, and tend to migrate to the surface of a molded specimen. Solvents such as dibutyl tin dilaurate have been suggested, but these are toxic materials and would be undesirable. U.S. Patent 3,516,957 teaches poly(alkylene terephthalates) with "a small percentage of an ester of an organic acid having from 10 to 27 carbon atoms and an alcohol having from 1 to 10 carbon atoms, e.g., methyl stearate or pentaerythritol tetrastearate, with the "cojoint presence of a synergistic agent such as an alkali metal salt or alkaline earth metal salt of an organic acid having 10 to 25 carbon atoms, e.g., sodium stearate; talc, and asbestos". The Flory interaction parameter for pentaerithritol tetrastearate is 0.42, and for methyl stearate is 0.48. We have now found a process and composition which can be used to enable polyesters such as PET to be molded at mold temperatures below 100 C to obtain highly crystalline parts even in thin sections the crystallization rate of the polyester being enhanced in the composition to enable this. The composition aspect of the invention can further provide polyester molding compositions which do not need to contain highly volatile solvents which tend to migrate to the surface of moldings. The compositions of the invention comprise (i) thermoplastic polyester of aliphatic diol and dicarboxylic acid, at least 95 mole % of said acid being terephthalic acid, (ii) inert particulate nucleating agent, and (iii) oligomeric polyester as crystallization promoter, said oligomeric polyester being of organic dicarboxylic acid having 2 to 8 carbon atoms and organic polyol and having a Flory Interaction Parameter with said polyester (i) below or equal to 0.2. Although any linear thermoplastic polyester as described above can be used in the present invention, the preferred thermoplastic polyesters are PET or blends of PET with other thermoplastic polyesters. The invention is thus also applicable for example to poly(butylene terephthalate) (PBT), poly(hexylene terephthalate), poly(cyclohexylene terephthalate) and poly(cyclohexyl dimethylene terephthalate), or blends of these materials. Thermoplastic polyesters which comprise structural units derived from terephthalic acid and up to 5 mole percent of other aromatic or aliphatic dicarboxylic acids such as isophthalic, naphthalene-2,6-dicarboxylic acid or adipic acid are also suitable. The alcohol component of the termoplastic polyester is preferably a single aliphatic diol but may also contain up to 30 mole percent of one or more other aliphatic diols. The invention is also applicable to polyesters derived from substituted acids such as hydroxy carboxylic acids in the amounts permitted above. Any two or more of these thermoplastic polyesters can be blended. For the sake of convenience hereafter these polyesters will be discussed largely in terms of PET or poly(alkylene terephthalate). The poly(alkylene terephthalate) polyesters used as starting compounds preferably have an intrinsic viscosity of 0.4 to 1.4 grams per deciliter, and more preferably 0.6 to 0.8 grams per deciliter. For these purposes, the intrinsic viscosity is measured before extrusion in a 1% solution of phenol and tetrachloroethane, 60 : 40 at 25 0C. The inert particulate nucleating agent can be talc, kaolin, calcium carbonate, aluminum oxide, titanium dioxide, silica and/or graphite. Suitable amounts of nucleating agent to be used include .01 to 5% by weight, based on poly(alkylene terephthalate). The nucleating agent is preferably a mixture of two or more inert particulate materials of which graphite is one. The oligomeric polyesters which have been found to be most useful in this invention have a preferred molecular weight, Mw, of 700 to 10,000. They must however have a Flory Interaction Parameter less than or equal to 0.2 with the poly(alkylene terephthalate), and be derived from organic dicarboxylic acid having 2 to 8 carbon atoms and organic polyol. The more preferred molecular weight is 900 to 5000, and when the acid is exclusively aliphatic, it is preferred that the oligomeric polyester have a molecular weight above 2000. Preferably the polyol is a glycol and has 2 to 15 carbon atoms. The oligomeric polyester can be terminated with either a fatty acid or an aliphatic alcohol preferably having 7 to 15 carbon atoms, or it can be unterminated. The oligomeric polyester can also include an aromatic glycol. The hydroxyl number of the oligomeric polyester should preferably be less than 50 mg/g and more preferably less than 10 mg/g to prevent degradation of the poly(alkylene terephthalate) during melt processing or long term use at elevated temperatures. One suitable method for preparation of suitable oligomeric polyesters is disclosed by VanHook in U.S. patent 3,284,399. Several particular highly preferred oligomeric polyesters are as follows: Decyl terminated {ethylene adipate/phthalate (1/1)) 2.0 Isodecyl terminated {ethylene adipate/phthalate (1/2))2.7 Octyl/decyl (1/1) terminated {ethylene adipate/phthalate) (1/2)) 2.2 C14 fatty acid terminated poly (propylene adipate) 2-ethyl hexyl terminated poly(butylene adipate) Poly{propylene adipate/phthalate (3/1)) t Mw = 1200 Poly{propylene adipate/isopVthalate (3/1)), Mw = 2000 The amount of oligomeric polyester which is generally used in the compositions is 0.1 to 10% by weight of the three components. Other additives may optionally be present in the compositions of the invention. Up to 50% by weight of the total composition of mineral fillers, fibrous reinforcement such as glass fibers, flame retardants, colorants, stabilizers, water scavengers, processing aids, and impact modifiers can be included. The impact modifiers used are preferably among the ones disclosed in Dutch patent application 77/06327; Australian 25992/77; U.S. patent 3,864,428; and/or U.S. patent 3,919,353. Furthermore, up to 8% of an aromatic polycarbonate prepared by the reaction of phosgene with 2,2 (4,4'-dihydroxydiphenyl)-propane(bis phenol A) can be included to improve the impact strength. Also, polyester-polyether elastomers can also be included in the composition as disclosed in our copending Application filed on the same date as this Application and claiming priority from U.S. Application 014405 filed 23 February 1979, the specification of which fully describes the suitable polyester-polyether elastomers. The compositions may be blended by tumbling the dry components together and melt blending by methods well known to those skilled in the art. The preferred method is extrusion on a single or twin screw extruder. It is surprising that the combination of oligomeric polyester and nucleating agent together gives such improvement to the crystallization rate of poly/alkylene terephthalate), especially PET. It is particularly surprising to find that the high molecular weight oligomeric polyesters not only increase the crystallization rate of the poly/alkylene terephthalate), but they may actually increase it more than lower molecular weight organic solvents used at equal concentrations, contrary to the usual expectation for materials which perform as plasticizers. Normally, low molecular weight plasticizers show better compatibility and better performance than high molecular weight plasticizers in PVC. It is also surprising that further improvements to the crystallization behavior and moldability may be obtained using the combination of graphite and talc. Graphite has been named as a nucleating agent for PET by others, but it is surprising that it would cause a further improvement of the crystallization behavior of PET in the presence of another nucleating agent. In this Specification and Claims appropriate ester-forming or transesterifiable derivatives of acids and alcohols are intended to be embraced by the disclosure of the acids and alcohols themselves. For example, anhydrides may often be used instead of acids in the formation of esters. The following examples are presented to illustrate some em bodiments of the invention, the preparation of components thereof and some comparative compositions. All parts and percentages are by weight unless otherwise indicated. Examples Measurements of crystallization rates, percentage crystall inity, nucleation temperatures (Tn), and crystallization temperatures (Tc) were all performed by differential thermal analysis. Crystallization rates were determined isothermally at 1000C on quenched samples of molten PET. The rate of crystallization is expressed as crystallization half-time, t1/2' which is the time necessary for 50% of the polymer to crystallize. The degree of crystallinity of molded specimens was determined by the difference in area between melting endotherm and recrystallization exotherms according to equation 1: E x #A x #Tscale x Tscale %Crystallinity of PET = x 100 (1) #Hf(PET) x R x W x Wf(PET) where E is an instrument correction factor, AA is the differ- ence in areas, ATscale is the vertical temperature response, Tscale is the horizontal temperature scale, tHf(PET) is 27.0 cal/g., R is the heating rate, W is the sample weight and Wf (PET) is the weight fraction of PET in the sample. The nucleation temperature (Tn) was determined as the temperature where the recrystallization peak maximum occurred during 500C/ min. colling of a molten sample. The nucleation temperature is a measure of the efficiency of a nucleating agent. Higher numbers indicate greater efficiency. The crystallization temperature (Tc) was determined as the temperature where the recrystallization maximum occurred during 200C/ min. heating of a partly amorphous molded samples. Tc is a measure of oligomeric polyester efficiency; lower numbers indicate a greater enhancement of low temperature crystallization of the poly(alkylene terephthalate). Example 1 PET (49 parts) which an intrinsic viscosity of 0.62 and 30 parts 0,48cm (3/16") chopped glass fiber strand were dried under vacuum at 120 C for 12 hours. Twenty one parts of a copolymer core/shell impact modifier having a polymethyl methacrylate shell polymerized in the presence of, and grafted to, a core of polybutyl acrylate were dried under vacuum at 600C for 12 hours. The materials were mixed together and extruded in a 2.54cm (1") single screw extruder equipped with one vacuum vent and a nitrogen blanketed feed. The extrudate was pelletized and dried again under vacuum for 6 hours at 1200C. Extruded pellets were used to obtain the rates of crystallization, nucleation temperature, and injection molding of ASTM test specimens. The material was molded on a Newbury 42.53 g (1.5-oz.) reciprocating screw injection molder with a mold temperature of 100 C and a 45-second cycle. Molded specimens were used to determine physical properties, degree of crystallinity, and crystallization temperature. Example 2 A composition was prespared according to Example 1 with a mold temperature of 140 C and a 45-second cycle. Example 3 A composition prepared according to Example 1 with 3% octyl/ decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)} 2.2 as oligomeric polyester added. Example 4 A composition prepared according to Example 1 with 0.5% talc and 3% of the oligomeric polyester of Example 3 added. Example 5 PET, with an intrinsic viscosity of 0,62 was dried under vacuum at 120 C for 12 hours. The material was extruded on a 2.03cm (0.8") twin-screw extruder equipped with two vacuum vents and a nitrogen blanketed feed. The extrudate was pelletized and dried again under vacuum for 6 hours at 1200C. Extruded pellets were used to obtain the rates of crystallization and for injection molding of ASTM test specimens. A Newbury 42.53 g (1.5-oz.) reciprocating screw injection molder was used with a mold temperature of 1000C and a 45second cycle. Molded specimens were used to determine physical properties, degree of crystallinity, and crystallization temperature. Example 6 A composition prepared according to Example 5 with 1.6% talc and 5.1% of oligomeric polyester octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2) 2.2 added. Example 7 A composition prepared according to Example 5 with 30% of the core/shell graft copolymer impact modifier defined in Example 1 added. Example 8 A composition prepared according to Example 5 with 28.62 of the' core/shell graft copolymer impact modifier defined in Example 1, 1.1% talc, and 3.68 oligomeric polyester octyl/ decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)) 2.2 added. Examples 1 - 8 in Table I show the advantages of adding both an oligomeric polyester and a nucleating agent to PET, impact-modified PET, and impact-modified, glass-reinforced PET. The crystallization half-time decreases and percent crystallinity of the PET increases without the loss of impact strength or tensile strength when the oligomeric polyesters were added. In addition, the nucleation temperature increases when a nucleating agent was added. The lowest tri/2 values were observed when the nucleating agent and oligomeric polyester were both added. TABLE I Mold Nucleation t1/2 % Crystalline Notched Izod Tensile Example Temp. Temp. (min.) 60-Mil 125-Mil (ft.- Strength No. ( C) ( C) at 100 C plaque Plaque Nm/cm 1b/in) 106Nm-2 (psi) 1 100 177 100 18 36 1,12 (2.1) 98.6 (14,300) 2 140 177 100 36 -- 1.07 (2.0) 97.22 (14,100) 3 100 176 50 -- 38 1.07 (2.0) 96.53 (14,000) 4 100 191 16 26 35 0.91 (1.7) 95.84 (13,900) 5 100 -- 43 -- 29 0.27 (0.5) 49.64 (7,200) 6 100 -- 2.4 -- 39 0.16 (0.3) 64.81 (9.400) 7 100 -- 88 -- 29 1.23 (2.3) 34.47 (5,000) 8 100 -- 13 -- 37 0.8 (1.5) 29.65 (4,300) Example 9 A composition prepared according to Example 1 with 0.7% talc and 0.7% graphite added. Example 10 A composition prepared according to Example 1 with 0.5% graphite and 3% oligomeric polyester oligomeric polyester octyl/ decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)} 2.2 added. Example 11 A composition prepared according to Example 1 with 0.5% talc, 0.5E graphite, and 3% oligomeric polyester octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)) 2.2 added. Example 12 A composition prepared according to Example 5 with 0.8% talc, 0.8% graphite, and 5.1% of oligomeric polyester octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)} 2.2 added. Example 13 A composition prepared according to Example 5 with 28,6% all acrylic core/shell graft copolymer impact modifier 3 in Example 1, o.6% talc, o.6% graphite, and 3.6% oligoneri polyester oligomeric polyester octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)) added. Examples 9 - 13 in Table II show the effect of graphite on the crystallization behavior and physical properties C. compositions. The effect of graphite on the crystallizat@@@ half time, t1/2, is particularly surprisnng. A comparison of Examples 4, 6, and 8 with similar compositions in xes 11, 12, and 13, respectively, reveals that added graphite lowers the t1/2 in every instance. TABLE II Mold Nucleation t1/2 %Crystalline Notched Izod Tensile Example Temp. Temp. (min.) 60-Mil 124-Mil (ft.- strength No. ( C) ( C) at 100 C Plaque Plaque Nm/cm 1b/in) 106Nm-2 (psi) 9 100 192 60 -- 31 1.17 (2.2) -10 100 189 17 -- 39 1,07 (2.0) 95.84 (1,3,900) 11 100 197 13 31 33 1.01 (1.9) 93.77 (13,600) 12 100 -- 2.1 -- 37 0.16 (0.30 66.19 (9,600) 13 100 -- 5.3 -- 36 0.75 (1.4) 31.72 (4,600) Example 14 A composition prepared according to Example 1 with 5% oligomeric polyester octyl/decyl (1/1 molar) terminated methylene adipate/phthalate (1/2)) 2.2, 0.75% talc, and 0.75% graphite added. Example 15 A composition prepared according to Example 1 with 5% dibutyl phthalate, 0.75% talc, and 0.75% graphite added. Example 16 A composition prepared according to Example 1 with 5% dimethyl phthalate, 0.75E talc, and 0.75% graphite added. Example 17 A composition prepared according to Example 1 with 3% oligomeric polyester octyl/decyl (1/1 molar terminated {ethylene adipate/phthalate (1/2)) 2.2, 0.75% talc, and 0.758 graphite added. Example 18 A composition prepared according to Example 1 with 3% MW = 4200 g/mol oligomeric polyester poly(propylene adipata), 0.75% talc, and 0.75% graphite added. Example 19 A composition prepared according to Example 1 with 3% Dow Corning 200 poly(dimethyl siloxane) silicone fluid, 07% talc, and 0.75% graphite added. Example 20 A composition prepared according to Example 1 except that a mixture of 17.58 by weight of an MBS impact modifier cor. sitting of a butadiene-styrene copolymer rubbery core onto which was grafted methyl methacrylate and 3.5% of bisphenci A-polycarbonate was substituted for the 21% impact modifier defined in Example 1. Example 21 A composition prepared according to Example 20 with 3.5% oligomeric polyester octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)} 2.2, 0.75% talc, and 0.75% graphite added. Example 22 A composition prepared according to Example 20 with 3.5% oligomeric polyester 2-ethylhexyl terminated poly(butylene adipate) with Mw = 3500 g/mole, 0.75% talc, and 0.75% graphite added. Example 23 A composition prepared according to Example 20 with 3.5% oligomeric polyester C16-Cl8 fatty acid terminated poly(propylene adipate) with Mw = 3400, 0.75% talc, and 0.75% graphite added. Example 24 A composition prepared according to Example 20 with 3.5% epoxidized glycerol tri(linoleate), 0.75 talc, and 0.7 graphite added. Example 25 A composition prepared according to Example 20 with 3.5% of 2-ethylhexyl terminated poly(propylene sebacate) with Mew = 7400, 0.75% talc, and 0.75% graphite added. Example 26 A composition prepared according to Example 20 with 3.5% of C6-C10 alcohol terminated poly(butylene adipate) with Mw - 5000, 0.75% talc, and 0.75% graphite added. Example 27 A composition prepared according to Example 20 with 3.58 of C14 fatty acid terminated poly(propylene adipate) with Nw = 2200 g/mole, 0.75% talc, and 0.75% graphite added. Example 28 A composition prepared according to Example 20 with 3.5% of C6-C10 alcohol terminated poly(propylene adipate) with Mw = 4200 g/mole, 0.75 talc, and 0.75% graphite added. Examples 14 - 28, in Table III, show the importance of using an oligomeric polyester with good compatibility with the PET to obtain high crystallization rates and low crystallization temperatures (tic) Compatibility is defined by the Flory interaction parameter for the interaction of oligomeric polyester and PET. The Flory interaction parameter was calculated from the Hildebrand solubility parameter for the oligomeric polyester and the PET by assuming the solubility parameter for PET to be 6 = 9.85, as shown in Moore et al, Polymer, 2, 315 (1961). The following is used to calculate Flory interaction parameter: EMI15.1 where XAB is the Flory interaction parameter, Vo is the molar volume per repeat unit in the polymer, dA and 6B are the Hildebrand solubility parameters for the oligomeric polyester and poly(alkyleneterephthalate), R is the gas constant, and T is the absolute temperature. Hildebrand solubilit ara- meters may be calculated by the method of Small, J. App' Chem., 3, 71(1953). Hildebrand solubility parameters can also be found in the literature, and the values used in this specification are either literature or measured values. Low Flory values indicate increased compatibility between the oligomeric polyester and the PET. In addition to demonstzat- ing the need for low Flory interaction parameters better ^ oligomeric polyester and poly(ethylene terephthalate) t'j'.f' data in Table III shows that high values for T are obtained c when aliphatic carboxylic acids with 10 carbon atoms are used as the major carboxylic acid portion of the oligomeric polyester. TABLE III No. of Carbon Oligomeric Atoms in Flory Example Polyester Carboxylic Interaction t1/2 No. Added Acid Function Parameter (min) TC( C) 14 5 8/6 0.011 8.5 N.O* 15 5 8 0.043 12.3 129 16 5 8 0.140 21.0 130 17 3 8/6 0.011 11.5 123 18 3 6 0.043 20.5 19 3 0 0.830 45.0 130 20 0 - - 100 136 21 3.5 8/6 0.011 3.5 124 22 3.5 6 0.105 - 130 23 3.5 5 0.042 - 127 24 3.5 18 0.433 - 142 25 3.5 10 0.116 - 142 26 3.5 6 0.027 - 130 27 3.5 6 0.11 4.8 126 28 3.5 6 0.043 *Not observed - sample was completely crystallized as no @. Example 29 A composition prepared according to Example 1 with 7% decabromobiphenyl oxide and 3% antimony trioxide added. Example 30. A composition prepared according to Example 1 with 7% decabromobiphenyl oxide, 3% antimony oxide, 0.5* talc, 0.5 graphite, and 3% oligomeric polyester octyl/decyl (1/1 molar) terminated (ethylene adipate/phthalate (1/2)} 2.2 were added. Examples 29 and 30, in Table IV, show that rendering the composition flame resistant does not decrease the effect of the oligomeric polyester and nucleating agents on the crystallization half-time of the poly(ethylene terephthalate). TABLE IV % Crystalline from Mold Example No. 60 mil Plaque t1/2 (min.) 29 37 100 30 44 16 Example 31 (comparative) Four compositions prepared in accordance with Example 1 containing 0.5% talc and with 2% or 5% of pentaerithritol tetrastearate and 2% or 5% octyl/decyl (1/1 molar) terminated {ethylene adipate/phthalate (1/2)} 2.2 ("oligomeric") were compared, and the rsts reported in the following Table V. These examples show the advantage of tnis invention over the use of pentaerythritol tetrastearate (1PETS11). TABLE V &num; of Carbon Atoms in Flory t@@ T carboxylic Interaction 1/2 w Additive Amount acid function Parameter (min) @C PETS 2% 18 0.42 > 100 133 PETS 5% 18 0.42 40 133 Oligomeric 2% 8/6 0.011 16.5 126 Oligomeric 5% 8/6 0.011 9.5 120

Claims: Claims: 1. A composition comprising (i) thermoplastic polyester of aliphatic diol and dicarboxylic acid, at least 95% mole of said acid being terephthalic acid, (ii) inert, particulate nucleating agent, and (iii) as crystallization promoter, oligomeric polyester of organic dicarboxylic acid having 2 to 8 carbon atoms and organic polyol, and having a Flory Interaction Parameter with said polyester below or equal to 0.2. 2. A composition as claimed in Claim 1 wherein said polyester comprises: poly(ethylene terephthalate), poly(propylene terephthalate), poly(butylene terephthalate), poly (hexylene terephthalate), poly(cyclohexylene terephthalate), and/or poly(cyclohexyl dimethylene terephthalate). 3. A composition as claimed in any preceding Claim wherein said polyester comprises: poly(ethylene terephthalate) having an intrinsic viscosity of 0.4 to 1.4 grams/deciliter meats before extrusion in a 1% solution of phenol and tetrachl@@: ethane 60 : 40 at 25 C. 4. A composition as claimed in Claim 3 wherein said intrinsic viscosity is 0.6 to 0.8. 5. A composition as claimed in any preceding Claim wherein said inert, particulate nucleating agent is talc, kaolin, calcium carbonate, aluminum oxide, titanium dioxide, silica, and/or graphite. 6. A composition as claimed in any preceding Claim wherein said nucleating agent is a mixture of at least two individual nucleating agents, one of which is graphite. 7. A composition as claimed in any preceding Claim further including a core/shell impact modifier, Disphenol A polycarbonate, glass fiber reinforcement and/or flame retardant. 8. A composition as claimed in any preeiS Claim where said oligomeric polyester is derived from dicarboxylic arct, aliphatic glycol, and has a molecular weight, Np7 of 700 to 10,000. 9. A composition as claimed in any preceding Claim wherein said oligomeric polyester is of a polyol having two hydroxyl groups and 2 to 15 carbon atoms. 10. A composition as claimed in any preseding Claim wherein said oligomeric polyester is terminated with an aliphatic alcohol or acid having 7 to 15 carbon atoms. 11. A composition as claimen in any f@eseding Claim wherein said oligomeric polyester comprises octyl/d@cyl (lfl) te minated {ethylene adipate/phthalate (1/2), @. @. 2-ethy@ hexyl terminated poly(butylene adipate) and poly{propylene adipate/isophthalate (3/1)}, MW = 2000, and. @@ isodecyl terminated {ethylene adrpate/phthalate (1/2) ; 2.7. 12. A composition as claimed in Claim 8 w@erein said @@ meric polyester is fatty acid terminated or alcohol terminated. 13. A composition as claimed in Claim 8 derived from di carboxylic acid, aliphatic glycol, and areratic glycol 14. A composition as claimed in Claim 8 w@@rein said d carboxylic acid is a mixture of aliphatic x d aromatic dicarboxylic acids. 15. A composition as claimed in Claim 5 wherein the ta? has an average particle size of les than microns. 16. A composition as claimed in Claim 5 or 6 wherein the graphite has an average particle size of less than or equal to 5 microns. 17. A composition as claimed in Claim 8, 9, 10, 12 or 13 wherein said organic dicarboxylic acid is exclusively aliphatic and the oligomeric polyester has a molecular weight of above 2000. 18. A moulding process wherein a composition as claimed in any preceding Claim is moulded at a mould temperature below 1000C.

Inventors: WORK, WILLIAM JAMES
Applicants: ROHM AND HAAS COMPANY
Application year: 1980
Main classification: C08L67
IPC codes: C08L67, C08K3