CARBOFURAN-CONTAINING PLANT PROTECTING COMPOSITIONS AND THE PREPARATION THEREOF

Abstract: Insecticidal compositions with improved plant growth accelerating properties, containing 1 to 50% by weight of 2,3-dihydro-2,2- dimethyl-7-benzofuranol methylcarbamate and 50 to 99 % by weight of a granular carrier prepared by partial hydrolysis of waste vegetable matter, such as corn cobs, corn stalks, wood pieces or sawdust derived from broad leaved trees, rice hulls, reeds or broken reeds. Conven­ tioned additives used in plant protecting compositions may also be present.

Description: Carbofuran-containing plant protecting compositions and the preparation thereof The invention relates to plant protecting compositions containing 2, 3-dihydro-2,2-diuiethyl-7- benzofuranol methylcarbamate (referred to below as carbofuran), together if desired with usual amounts of additives conventionally used in the manufacture of plant protecting compositions. The compositions according to the invention are characterized in containing 50 to 99 Va by weight of a carrier known per se, prepared bv a partial hydrolysis of vegetable aste matter, preferably corn cobs, corn stalks, wood pieces (e.g. choppings) or sawdust derived from broad leaved trees, rice hulls, reeds or broken reeds, and have improved plant growth accelerating properties. According to the invention the new compositions are prepared by coating and/or saturating the carrier with a solution or suspension of carbofurane, optionally adding further additives, and finally drying the composition. Hungarian Patent Specification No. 170,617 discloses carriers for plant p'rotecting compositions. These carriers can be prepared by hydrolysing agricultural waste matters and have favourable mechanical and sorption properties. Although certain components of these carriers mav be utilized by the plants, they are however absolutely inert with respect to the active ingredient of the plant protecting composition. It has been found that the insecticide carbofuran when applied for example to to-bacco or maize accelerates the growth and ripening of plants and increases the crop yield. This effect considerably exceeds what could have been expected imply as a consequence of the elimination or diminution of the damage done by insects [J. Econ. Entomol. 172, 64 (1971)]o The present invention is based on the surpris ing recognition that if the insecticidally active carbofuran is applied to the carrier disclosed in Hungarian Patent Specification No. 170,617 or prepared from other agricultural waste matter in an analogous way, the composition obtained shows a considarab higher plant growth accelerating activity than carbofuran alone. The increase of plant growth accelerating sotivlty is highly surprising since according to Hungarian Patent Specification referred to above the carriers employed "due to their composition and way of preparation can be considered as practically entirely inert with respect to biologically active compounds". On the other hand, it could not be expected either that the components of these carriers, which can be utilized by the plants in a very small ("catalytic") amount which is only a fraction of the amount required for traditional fertilization, exert such a favourable effect on the function of the organism of plants. It has been observed that as a result of treatment with the compositions according to the invention, the weight of the aboveground parts of plants in an early stage of their development increased considerably, thickening of the stalk was observable and the size of the leaves also increased. It was also observed that the leaf,green level of the tomato test plants and maize, wheat, tobacco and sugar beet in field trials had been increased, and accordingly visual observation clearly showed that the leaves were definitely greener than the untreated ones. It has also unexpectedly been found that carbofuran exerted a greater effect on the root growth when the carriers disclosed in the present invention were employed, and accordingly, the test plants had thicker9 raising and longer roots, and more capillary roots were developed. To illustrate the effect of the compositions according to the invention the composition prepared according to Example 1 was tested. For comparison tests were also made with a) plants treated with a solution of carbofuran b) plants treated with a known carbofuran-containing composition, and c) untreated plants The biological tests were carried out as follows: Pots having an area of 228 cm2 were filled with loamy garden soil up to 5 cm. The soil for different tests was obtained from different places. Tomato seeds of "Harrow" type were then placed on the surface of soil. The test materials and compositions were applied to the whole surface, directly onthe plants. a) Granules were homogenized with 3 cm2 washed river sand and were uniformlY sprinkled to the surface of the pots. b) When testing the active ingredient alone, the whole surface was treated with a saturated carbofuran solution containing 700 ppm of active ingredient by means of a dropping tube. The seeds were then covered with 50 cm3 (228 cm2, passed through a 1-3 mm screen) crumby soil. The pots were kept in a greenhouse at 18-250C, and a humidity of 60 to 90 % After 28 and 35 days, respectively the weight of 25 plants was measured and the mathematical average was calculated. 6 repetitions were made. The results given correspond to the average of 6 x 25 = 150 measurements. The results are shown in the following Table. Table Composition Amount employed expressed Weight of seedlinug Weight of seedling in carbofuran on the 28th day on the 35th day [kg/ha] after tratment after treatment [g] %-age [g] %-age difference difference related to related to the control the control Composition according to Example 1 20 2 5.61 32 8.39 42 FURADANR 10 G 20 2 4.58 8 6.50 10 A saturated aqueous solution of carbofuran 2 5.46 28 7.05 19 Untreated control --- 4.24 0 5.90 0 The results clearly show that the weight of the seedlings treated with the compositions according to the invention considerably exceeds the weight of the plants treated with a carbofuran solution and of the untreated plants, and a marked weight increase could also be observed in comparison with the commercial carbofuran-containing composition FEC-Niagara FURADANR 10 G. It can also be seen that the difference between the plant growth acceleraz ing activity of the compositions according to the invention and of the latter composition, where quartz is used as a carrier, is greater than the difference related to the carbofuran solution. Since the quartz carrier is obviously inert with respect to the carbofuran active ingredient, the increase of the plant growth accelerating activity of carbofuran in the compositions according to the invention due to the carrier employed, is the sum of two factors: a) the carrier compensates the loss in activity related to the active ingredient alone, due to formulation; b) the carrier increases the activity in comparison with the active ingredient alone. The effect of the compositions according to the invention is due to the fact that the proteins, saccharides, carboxylic acids, furfurol various meso- and micro-nutrients in combination with carbofuran favourably influence the function of the plant organism. The carriers used in the compositions according to the invention are prepared from various vegetable waste matter , preferably corn cob, wood choppings or sawdust prepared from broad leaved trees, following the procedure described in Hungarian Patent Specification No. 170,617. More particularly, said vegetable waste matter is hydrolysed with steam, e.g, at 150 to 200 OC, and then granulated for example with a high-speed tube granulating equipment. In the cited Hungarian Patent Specification the carrier obtained is characterized as a carrier "of hydrolysed agricultural waste matter origin, which consists of 35 to 45 % bg weight of cellulose related to its dry substance content, saccharides and/or carboxylic acids, has a pH of between 1 and 7 measured in a 10 go aqueous suspension and a grain size of 0.1 to 10 mmt'. It should be noted, however, that according to the current results the composition of the carrier, especially if broad leaved trees are used as starting material, can also be slightly different. The carbofuran content of the compositions according to the invention is between 1 to 50 % by weight, preferably 5 to 10 @ by wei±bt, i.e. is in the same range as the carbofuran content of commercially available carbofuran-containing com positions The compositions can be prepared starting from an aqueous or organic solution or suspension of carbofuran. As organs solvents chloroform or petroleum can for example be used0 In addition to the active ingredient and the carrier the compositions can contain also further additives, such as adhesives, eOg. film-forming agents, etcO Further details of the invention are illustrated in the following Examples0 It is, however, not intended- to limit our invention to the Examples. Example 1 1360 kg /hour of corn cobs are hydrolysed with steam at 80 OC, under a pressure of 12 at. The corn cob has the following characteristics: grain size: 2 to 20 mm; water content; 20o8 %; volume weight: 199 g /lit pentose content related to dry substance: 33 %; lignin content related to dry substance: 30 %; cellulose content related to dry substance: 36 %; ash content related to dry substance: 1 %. 1432 kg/hour of a hydrolysate are obtained, which has the following properties: grain size: 0.02 to 2 mm; water content: 42 jó; wet volume weight: 500 g flit; furfurol content related to dry substance; 16 % lenin content related to dry substance: 35 d ciud cellulose content related to dry substance: 40 %. The hydrolysate is then granulated in 2 hight-speed knife tube granulating equipment, 612 kg of a granulate having a grain size of 0.1 to 1 mm are obtained. Further characteristics of the granulate are as follows. sorption capacity: 26.8 g/100 g (from a 1:1 mixture of xlene and gasoline oil) BET area: 2.4 mê/g. pE (in a 1C 5S aqueous suspension): 507 The carrier granules obtained are then placed in a cylinder having a diameter of 200 mm and height of 400 mm and a capacity and 9 kg. The bottom of the cylinder is a perforated plate and a dust filter bag is attached to its top. Air is blown through upwards from below. The carrier is fluidised with an air stream of 1.5 m/sec. 1 kg of carbofuran is dissolved in 6,8 kg of chloroform and the solution is sprayed onto the granulate. Air is blown through the system until chloroform is entirely evaporated. Carbofuran forms a uniform coating on the surface of the carriers The composi- tion obtained contains 10 % by weight of carbofuran Example 2 1200 kg of waste wood are hydrolysed with steam at 180 0C, under 12 atO The basic material has the following characteristics: grain size: 20 to 50 mm water content: 18 %; volume weight: 180 g/lit; pentose content related to dry substance: 22 %; lignin contentrelated to dry substance: 26 %; cellulose content related to dry substance: 42 %; ash content related to dry substance: 008 %. 1470 kg/hour of a hydrolysate are obtained, which has the following properties: grain size: 0o02 to 2 mm; water content: 52 %; wet volume weight: 500 g/llto; furfurol resin content related to dry substance: 10 %; lignin content related to dry substance: 30 %; cellulose content related to drg substance: 45 %; ash content related to dry substance: 1o2 %. The hydrolysate obtained is then granulated in a high-speed knife tube granulating equipments 620 kg of a granulate having a grain size of 0 1 to 10 mm is obtained. Purther characteristics of the granulate are as follows: sorption capacity: 78 g/100 g (from a 1:1 mixture of xylene and gasoline oil) BET area: 2.3 m2 Ig. ph: 3.6 Following the procedure described in Examplel a composition containing 10 % by weight of carbofuran is obtained. Example 3 2 kg of crystalline carbofuran are suspended in 3.0 kg of a hydrocarbon derivative having a low boiling point (petroleum) and the suspension is treated in a wet grinding apparatus until a stable suspension is obtained. The grain size of carbofuran in the paste obtained preferably is about 1 to 10 m Into a 100-lito concrete mixer 18 kg of a carrier granulate prepared according to Example 1 are weighed. 5 kg of the paste containing 40 go by weight of carbofuran are sprayed on the mixed carrier and petroleum is evaporated by inJecting hot air. A composition containing 10 by weight of carbofuran is obtained0 Example 4 2 kg of crystalline carbofuran are suspended in 3 kg of water Following the procedure described in Example 3, a composition containing 10% by weight of carbofuran is obtained.

Claims: CLAIMS 1. An insecticidal composition containing 1 to 50% by weight of 2,3-dihydro-2,2-dimethyl-7-benzofuranol methylcarbamate and 50 to 99 % by weight of a granular carrier prepared by partial hydrolysis of waste vegetable matter. 2. A composition as claimed in claim 1 in which the vegetable matter is corn cobs, corn stalks, wood pieces or sawdust derived from broad leaved trees, rice hulls, reeds or broken reeds. 3. A composition as claimed in claim 1 in which the vegetable matter is corn cobs or wood from broad leaved trees. 4. A composition as claimed in any one of the preceding claims in which the hydrolysis is effected with steam. 5. A composition as claimed in any one of the preceding claims which further contains one or more additives conventionally used in plant protecting compositions. 6. A process for the preparation of an insecticidal composition as claimed in claim 1, which comprises admixing an aqueous or organic solution or suspension of 2,3-dihydro-2,2-dimethyl-7-benzofuranol methylcarbamate with said carrier, and then drying the mixture

Inventors: ANGYAN, SANDOR, DETRE, TAMAS, KOVATS, FERENC, RACZ, ISTVAN, RADVANYI, ERZSEBET, SOS, JOZSEF
Applicants: CHINOIN GYOGYSZER ES VEGYESZETI TERMEKEK GYARA RT.
Application year: 1980
Main classification: A01N25
IPC codes: A01P7, A01N47, A01P21, A01N25, A01N57