METHOD AND APPARATUS FOR THE PRODUCTION OF COMPOSITE SHEET MATERIAL AND A SHEET MATERIAL PRODUCED THEREBY

Abstract: A method and apparatus for the production of a composite sheet material and a material produced thereby are described, a typical product being a lightweight permanent or temporary form work sheet of accurate thickness and parallelism made from material including glass fibre reinforced cement. A base (10) or mould is moved through successive stations (13, 14, 15) at which uncured but curable material is deposited in layers (16, 18, 23) thereon. A t least the final layer (23) is consolidated by a local surface treatment with a vibratory screeder (17, 19, 24), the influence of which spreads through the material to promote intimate bonding together of the uncured layers (16, 18, 23). In a preferred form, the material comprises three layers (16, 18, 23), the first (16) and third (23) being of glass fibre reinforced cement and the central second layer (18) being of cementitious material including a lightweight aggregate such as hollow microspheres. The screeder (17, 19, 24) used on the top surface is accurately guided with respect to the base (10) or mould to provide an accurately controlled relationship between the faces of the finished sheet.

Description: Title: "Method and Apparatus for the production of composite sheet material and a sheet material produced thereby". Description of Invention This invention relates to a method and to an apparatus for the production of composite sheet material and to a sheet material produced thereby. The invention has been devised especially in relation to sheet material for use in formwork for casting concrete, as an alternative or substitute for the conventional thick plywood sheets used at present. These plywood sheets have the disadvantages that their life is relatively short, they are susceptible to swelling and splitting in the wet environment in which they are used, and the sheets need considerable support per unit area since wood is a relatively flexible material. In view of these disadvantages of plywood sheets, it has been proposed to use sheets of a material comprising glass-fibre reinforced cement (grc . Such sheets have good release properties when used as temporary formwork, are extremely stiff and strong and hence need less support than plywood for an equivalent permitted deflection, and are less susceptible to water damage than plywood. The sheets can be formed so as to provide a flat or alternatively a relief pattern surface on the concrete being cast. However, currently available grc sheets have certain disadvantages. They are much heavier than pl wood of the same thickness. grc is relatively expensive because of the need to use an alkali resistant form of glass fibre in the mix to prevent attack by the cementitious matrix. At present, grc sheets are laid down by a spraying process which is inherently likely to produce a slightly uneven top surface finish and so that thickness of the sheets tends to vary and the surface finish is often not even. The top surface of material has been rolled by hand to consolidate the material and then floated to produce a more or less flat surface but, in spite of the costly and time consuming nature of such hand finishing processes, the resulting sheets are still slightly non-uniform. When used in formwork, sheets are supported by wooden frameworks and it has often proved necessary to pack and shim the formwork extensively to achieve a satisfactory structure. The invention is not limited to the manufacture of sheet material for use in permanent or temporary formwork for concrete. It is also applicable to the manufacture of sheet material for other uses, for example as flooring or cladding or for other building purposes. It is an object of the present invention to provide a method and apparatus for the production of composite sheet material which are such that the thick¬ ness and surface finish of the material can be accurately controlled and the material can be produced less expensively than conventional grc sheets. It is a further object of the invention to produce a new or improved sheet material which is lighter in weight than conventional dense grc sheets. A particular aim of the invention is to produce such a sheet material suitable for use in formwork, in which the above mentioned disadvantages of currently available grc sheets are overcome or reduced. According to a first aspect of the invention there is provided a method of producing a composite sheet material comprising the steps of taking a mould or base, depositing thereon a first layer of a curable material in a viscous flowable state, depositing on the first layer a second layer of a curable material in a viscous flowable state, the first layer having sufficient strength in its uncured state to support the second layer, consolidating the second layer by localised applicaton of vibration to the surface thereof, and allowing the materials to cure, the materials being such that on curing the layers bond together. The expression "viscous flowable state" as used herein includes a condition in which the material is extremely viscous and can be caused to flow only under pressure or vibration. The method may include the additional step of depositing one or more further layers of a curable material in a viscous flowable state on the second layer, the layer deposited before the or each such further layer having sufficient strength in the uncured state to support said further layer, and consolidating the or each further layer by localised application of vibration to the surface thereof. In the performance of the me.thod, the mould or base may move continuously through a plurality of successive stations at which the layers are continuously deposited and consolidated. The surface of the second or of a further layer may be consolidated by means which are guided and orientated accurately relative to the base or mould, so as to give accurate control of the relationship between the faces of the sheet material produced. In a preferred method, three layers are deposited, the curable material of the first and third layers being glass fibre reinforced cement and that of the central second layer being cementitious and including a light¬ weight aggregate. Irrespective of the number of layers, it is preferred that the curable material of each layer comprises a curable constituent and one or more other constituents, all the layers having the same curable constituent to cause bonding together of the layers on curing. The curable constituent may be hydraulic cement or alternatively may be gypsum. The other constituents may include glass fibre or other fibrous reinforcements, lightweight aggregates such as hollow microspheres, air entraining agents, plasticisers, sand or fillers or any combination. Viewed from a further aspect, the invention comprises an apparatus for producing a composite sheet material comprising a support affording or supporting a base or mould, first depositor means for depositing a first layer of curable material in a viscous flowable state on the base or mould, second depositor means for depositing a second layer of a curable material in a viscous flowable state on the first layer, and vibratory means adapted to apply localised vibration to the surface of the second layer in order to consolidate it. The apparatus may additionally comprise one or more further depositor means for depositing one- or more further layers of curable material in a viscous flowable state on the second layer and further vibratory means adapted to apply localised vibration to the surface of the or each further layer in order to consolidate it. 0RE OMP The depositor means and the vibratory means may be disposed at successive stations and the mould or base may be arranged to move successively through the stations. In this case, one or more of the depositor means may comprise a spray head adapted to deposit a glass fibre reinforced hydraulic curable material and the spray head may be movably mounted at the associated station to traverse across the direction of movement of the mould or base. The or each screeding means of the apparatus may be guided and orientated accurately relative to the base or mould, whereby the relationship between the surfaces of the composite sheet produced is accurately controlled. Viewed from a further aspect, the invention also comprises a ' composite sheet material when made by the method set out above. The composite sheet material may comprise a matrix of cured hydraulic cement having three thickness zones defined by the presence of different other constituents within the matrix of adjacent zones, the outer zones including alkali resistant glass fibre as such another constituent and the inner zone including a lightweight aggregate as such another constituent, the opposite faces of the sheet material having an accurately controlled relationship. The invention will now be described in more detail by way of example only with reference to the accompanying drawings in which:- FIGURE 1 is an end elevational view of an apparatus for producing composite sheet material; FIGURE 2 is a diagrammatic end elevational view of a mould or base used in the production of the sheet material; FIGURE 3 diagrammatically illustrates the method of production of a sheet material having three layers; FIGURE 4 is an enlarged diagrammatic view of a screeding and consolidating stage in the process; FIGURE 5 is a cross-section through one form of sheet material embodying the invention and which may be produced by the process described with reference to Figures 2 to 4. The process to be described is carried out contin¬ uously or semi-continuously using a base or mould having the cross-section shown in Figure 2. This comprises a flat base plate 10 and a pair of side members 11 which are of L-shape in the drawings but which could comprise upright plates. The side members 11 are adjustable for height relative to the top surface of the base plate and have top guide edges 12 which control the positioning and orientation of a screeding bar to be described. Figure 3 shows diagrammatically the method by which a three-layer sandwich sheet of material (illustrated in Figure 5 ) is produced. The apparatus includes first, second and third depositor stations, spaced apart successively along the direction of travel A of the mould or base plate 10. At each successive depositor station, one layer of the composite sheet is laid. In the example to be described, the first layer 16 which is deposited at the first station 13 is a layer of glass fibre reinforced cement (grc). This is deposited in generally conventional manner by a spray head disposed OM at the station 13, the spray head being arranged to traverse across the base plate 10 from side to side as the base plate moves continuously in the direction of the arrow A beneath the depositor station 13. grc layer 16 is in a viscous but flowable condition. In order to provide a smooth surface and to ensure optimum compaction of the grc layer 16, a vibratory screeding bar 17 is used to screed the top surface of the grc layer. It is preferred that the screeding bar 17 is guided and orientated accurately with respect to the base plate 10, for example by being arranged to bear on the side members 11 of the base plate 10. While the grc layer 16 is still in an uncured state, the base plate 10 passes under the second depositor station where another layer of material is deposited. In a preferred embodiment, this layer comprises a lightweight * "mortar" which comprises a slurry of water and cement binding together a lightweight aggregate. The lightweight mortar layer lb is laid in a viscous flowable state as hereinbefore defined. Some form of vibratory feed may be provided at the second station 14 to ensure continuous feeding of the layer lb directly onto the uncured grc layer 16. Shortly after the lightweight mortar layer lb has been deposited at the second station 14, it is screeded by means of a second vibratory screeding bar 19 which again is guided so as to be, for example, accurately parallel with the undersurface defined by the base plate 10. The screeding bar 19 is preferably vibrated trans¬ versely of the direction of movement of the mould, by means of a vibrator which is indicated at 20 in the enlarged view which forms Figure 4 of the drawings. -£ REΛ OMPI ~ - Although the grc layer 16 has not cured when the lightweight mortar layer 19 is laid on it, it must have sufficient strength in its uncured state to support the second layer. After the second depositor station, when the base plate 10 passes under the second screeding bar 19, some difficulties might be expected because of the relatively flowable condition of the underlying grc layer. One might expect that the grc layer 16 and the lightweight mortar layer lb would intermingle to an unacceptable extent under the influence of the vibratory screeding bar 19 or that the relatively flowable state of the layer 16 would prevent the layer lb from being acceptably consolidated and levelled. Surprisingly, we have found that the screeding can be performed whilst both the lightweight mortar layer lb and the grc layer 16 are in an uncured, flowable and wet condition, with considerable advantages. These advantages can be enhanced by the use of the type of mould shown in Figure 2 and described above. At the second depositor station, the side members 11 are raised to the dotted line position shown at 21, for example by means of suitable cams provided on the conveyor apparatus. The side members can then constrain the lightweight mortar and the grc to a region above the base plate 10 and prevent material being lost over the sides of the apparatus. In addition to preventing wastage, this enables a state of fluidisation to be built up in the grc substrate layer 16 when the two layers of the material pass under the screeding bar 19. To explain this phenomenon in more detail, reference should be made to Figure 4 of the drawings which illus¬ trates diagrammatically the region of the screeding bar 19. OMPI The mould base plate 10 is travelling in the direction of the arrow A as before and carries the grc layer 16 which, it will be recalled, is in an uncured condition of sufficient strength to support the second layer lb. The two layers pass under the screeding bar 19 which is vibrated in a direction transversely of . the direction of motion A. The material is constrained to the base plate 10 by means of the elevated side members in the position 21 and, in the region immediately beneath the screeding bar, the vibration of the screeding bar fluidises the cementitious binder of the material beneath it. ' The effect of the vibration is felt primarily immediately adjacent the underside of the screeding bar 19 but there is also a radially extending zone of influence which is indicated generally at 22 in the drawings by a series of part circular arcs. This zone of influence is of course part-cylindrical, extending right across the base plate 10. A certain amount of fluidisa¬ tion takes place within the zone of influence. This fluidisation causes the consolidation of the lightweight mortar lb and its intimate bonding to the wet substrate layer 16 of grc. The effect is confined to the zone of influence 22. In the regions of the layer 16 immediately before and after the zone of influence 22, the grc layer 16 retains its uncured strength to which reference has previously been made. The fluidised material of the layer 16 within the zone of influence 22 is therefore confined between the less strongly fluidised adjacent regions and, in spite of its relatively liquid state, cannot escape from the zone 22 because it is so constrained. Additionally, the material is constrained at the ends of the screeding bar 19 by the elevated side members 11. The upper layer lb is fluidised and consolidated by the action of the vibrating screeding bar 19. The vibrations are transmitted through the upper layer lb of the lower layer 16, creating in it a degree of fluidisation. Thus, a very good bond is obtained between the grc layer and the lightweight mortar layer so that the cement matrix is effectively continuous across the junction and only the other constituents differ. The upper surface is flat and smooth and, if the position and orientation of the screeding bar 19 is controlled by the side edges 12, this surface can be exactly parallel to the under surface of the sheet defined by the base plate 10, or otherwfse have an accurately defined relationship with the undersurface. Although the full advantages of the method may be achieved using the side members 11 to constrain the material at its edges, a satisfactory effect may be obtainable without the side members (except that the edges of the finished sheet need to be trimmed). The first two layers of the material have thus been laid and the material passes under the third station 15, where a further grc layer 23 is added, again using a transversely moved spray head similar to that provided at the station 13. The further grc layer 23 is screeded by means of a further screeder bar 24 which operates in a precisely similar manner to the screeder bar 19. It will be appreciated that the zone of influence of the screeder bar 24 may or may not extend through to the lowermost layer 16 but that it will primarily promote intimate bonding of the layers lb and 23 of lightweight mortar and grc respectively. The three-layer sheet material emerging from the zone of influence of the screeding bar 24 continues along the conveyor system and is allowed to cure. An advantage of the process outlined is that, since the materials are wet when the three layers are superposed and since the cement matrix extends throughout the sheet material, all the layers cure together and hence there is no problem of different curing stages causing separation of the layers or curling of the sheet material. The process described above is for the manufacture of a three-layer sheet material of sandwich construction, faced with grc. By using different materials, other types of sheet can be produced, for example, a sheet in which a substrate of lightweight mortar has a single facing sheet of grc. The method can clearly be extended to provide other types of sandwich or multiple sandwich material. It may or may not be necessary to provide vibratory screeding at each stage of the process. It will also be appreciated that the vibratory screeding bar 17 could be omitted from the apparatus shown although this does enable the first layer to be laid in a viscous condition and to be thoroughly consolidated. Figure 5 shows part of a composite sheet of material which is produced by the method, operation of which was described with reference to Figures 2 to 4 of the drawings. This sheet material is only one example of various materials which can be produced using the method and has been developed specifically for use as a formwork for the casting of concrete. It may be used either as a temporary formwork, which is removed leaving the concrete surface exposed, or as a permanent formwork which is left in place after the concrete has set. The material shown includes three layers 16, lb, 23- The central core layer lb which occupies about two thirds of the thickness of the sheet is made of a lightweight mortar and this core is faced on each of its opposed faces by a layer of glass fibre reinforced cement having a thickness about one sixth that of the sheet. Each grc facing layer is made by spraying and consolidating a mixture of chopped alkali-resistant glass fibre of the type marketed under the Registered Trade Mark CEMFIL, together with a slurry of Portland cement, fine aggregate such as sand and water. By way of example, the ratio of cement, sand and water in the slurry may be 30 : 15 : 9 and we have found that the desirable quantity of glass fibre to be introduced into this slurry is approximately 5% by weight of the slurry. Proportions may vary according to the type of cement or fine aggregate used, or other factors. Alternative fine aggregates are crushed limestone or PFA (pulverised fuel ash): The core is formed from a lightweight mortar which includes 100 parts cement, between 50 and 200 parts water and between 50 and 300 parts of PFA CENOSPHERES by weight. PFA CENOSPHERES are an example of a lightweight aggregate and comprise small hollow gas-containing microspheres which add to the volume of the cement without adding substantially to its weight. When cured, the cement matrix effectively forms a skeleton structure surrounding the bubbles. We have found that a useful composition is one part by weight of cement to one part by weight of CENOSPHERES with between 0.65 and 1.1 parts by weight, (say 0.75 parts by weight) of water. However, the proportion of CENOSPHERES to be added can be varied between one half the weight of cement to three times the weight of cement. At the lower end of this range, both the strength and the density of the composition are quite high. At the upper end of the range, the density is extremely low compared with solid cement but the strength is also somewhat reduced. j O Other forms of microspheres can be used instead of the cenospheres, or foamed plastics beads may be substituted. It may be desirable to produce a fire resistant material, in which case the use of organic materials may be objectionable and an inorganic light¬ weight aggregate may be preferred. To improve the strength, some fibrous reinforcement may be added, for example alkali-resistant glass fibre or various types of synthetic plastics fibres. The quantity of water to be used may vary consider¬ ably with the ^ quantity of lightweight aggregate because, for example, PFA CENOSPHERES have a very high surface to weight-ratio and ' tend to adsorb a considerable quantity of water onto their surfaces, reducing the amount of free water which can be used for hydrating the cement. In addition to the CENOSPHERES, air may be incorpor¬ ated in the mix by the use of an air entraining additive. In addition, or alternatively, a plasticiser may be added. This enables the water content to be reduced. The action of some plasticisers is also time related and, for example, a very viscous mix incorporating a plasticiser may be quite flowable for a certain length of time but will undergo a pseudo-setting process after a time delay. This effect may be used with advantage in making the composite sheet. The composite sheet material described, particu¬ larly when vibratory • screeding is used in its manufacture, forms a cohesive sheet with hard and rigid facings which may have any desired surface finish, the core of the material being light in weight and the entire material having a continuous cementitious matrix, only the aggregate or reinforcement differing between the layers. The thickness of the sheet and parallelism of OMPI the faces can also be controlled by the means described above. Such a material is extremely useful for formwork as a substitute or alternative for plywood. It is provided with strength and rigidity by its grc facings and the weight is reduced by the lightweight mortar substrate or core, compared with conventionally available solid grc. In the example described, there are no large air voids in the material so that it is of homogeneous composi¬ tion and strength throughout. This is achieved by use of the vibratory streeding method, combined with the use of CENOSPHERES to provide the lightweight core. Where air entraining agents are used, it has been found that the vibratory screeding does not prevent the entrainment of air. Referring more specifically to the apparatus shown in Figure 1 of the drawings, the base plate 10 and side members 11 have already been referred to. These are mounted oh a carriage 25 which is provided with a plurality of wheels 26 running on tracks 27. The tracks run beneath a plurality of stations, of which the station 13 is illustrated. At this station, there is an overhead trans¬ verse rail 2b carrying the spray head 29 previously referred to for depositing the grc material on the base plate 10. The spray head traverses from side to side across the direction of movement of the carriage 25, along the overhead transverse rail 2b. Immediately beyond the position at which the spray is laid down, the material forming the first layer 16 is screeded by the screeder bar 17 which is fitted with a vibrator 30. The screeder bar 17 is loosely mounted in slotted brackets 31 and is arranged to ride on the side members 11 of the base plate to control the thickness and parallelism of the layer 16 as described above. It will be noted that this takes place irrespective of any slight rocking or irregular movement of the carriage 25 on the tracks 27. The remaining stations of the apparatus are similar to the station 13 described above, with the exception that the spray head 29 may be replaced by depositor means for other types of material which do not require to be sprayed, for example the lightweight cementitous mortar referred to above. It will be appreciated that many modifications may be made to the apparatus and to the method and composition described above, without departing from the scope of the invention. Such modifications, to produce different types of material for different purposes will be readily apparent to those skilled in the art, on the basis of the foregoing description. An alternative to using chopped glass fibre to reinforce the facing layer(s) is the use of glass fibre mat of a woven or non-woven type. In this case a thin layer of viscous slurry is laid, the mat is unrolled onto this layer and a further slurry may then be added. It is believed that, where such a facing is laid as in initial layer, it may be sufficient to add a core layer and then consolidate both simultaneously by vibratory screeding. Of course, fibres other than glass, for example metal or plastics fibres, might alternatively or addition¬ ally be used in any of the layers. If desired the lateral constraint can be supplied by edge strips which remain part of the finished sheet and which are only temporarily secured to the mould. The invention is likely to prove particularly useful in adding a layer to a core or substrate of cementitious material which is not reinforced with fibres, because, in an uncured condition, such materials tend to be more flowable than fibre reinforced materials. The invention enables a fibre reinforced material to be deposited and consolidated on the surface of an unreinforced material without the need for preliminary curing of the unreinforced material and its consequent disadvantages. O

Claims: CLAIMS : 1. A method for producing composite sheet material comprising the steps of taking a mould or base, deposit¬ ing thereon a first layer of a curable material in a viscous flowable state, depositing on said first layer a second layer of a curable material in a viscous flowable state, the first layer having sufficient strength in its uncured state to support the second layer, consolidating the second layer by localised applicaton of vibration to the surface thereof, and allowing the materials to cure, the materials being such that on curing the layers bond together. 2. A method according to Claim 1 which includes the additional steps of depositing one or more further layers of a curable material in a viscous flowable state on said second layer, the layer deposited before the or each such further layer having sufficient strength in the uncured state to support said further layer; and consolidating the or each further layer by localised application of vibration to the surface thereof. 3. A method according to Claim 1 or Claim 2 wherein the mould or base continuously moves through a plurality of successive stations at which said layers are continuously deposited and consolidated. 4. A method according to Claim 3 wherein the surface of the second layer or of a further layer is consolidated by means guided and orientated acurately relative to the base or mould. 5. A method according to any preceding claim wherein the first layer is consolidated before the second layer is deposited thereon. OMPI 6. A method according to any preceding claim wherein consolidation of one or more layers is combined with screeding. 7. A method according to any preceding claim wherein the layers are confined to the region of the base or mould by side walls provided on the base or mould. 8. A method according to any preceding claim wherein the curable material of each layer comprises a curable constituent and one or more other constituents, all the layers having the same curable constituent to cause bonding together of the layers on curing. 9. A method according to Claim 8 wherein the curable constituent is hydraulic cement. 10. A method according to Claim b wherein the curable constituent is gypsum. 11. A method according to Claim b wherein one or more layers includes fibres as such another constituent. 12 A method according to Claim 11 wherein the fibres are of glass. 13- A method according to Claim b wherein one or more layers include a lightweight aggregate as such another constituent. 14. A method according to Claim 13 wherein said layer or layers additionally include a fibrous reinforcement as • such another constituent. 15. A method according to Claim 13 or Claim 14 wherein said layer or layers include an air entraining agent as such another constituent. 16. A method according to any one of Claims 13 to 15 wherein said layer or layers include a plasticiser as such another constituent. 17. A method according to Claim 1 which includes the additional steps of depositing a third layer of curable material in a viscous flowable state on said second layer, the second layer having sufficient strength in the uncured state to support said third layer, and consoli¬ dating the third layer by localised application of vibration to the surface thereof, the first and third layers being of the same curable material which is different from- the curable material of the second layer. 18. A method according to Claim 17 wherein the curable material of the first and third layers is glass fibre reinforced cement and that of the second layer is cementitious and includes a lightweight aggregate. 19. An apparatus for the production of a composite sheet material, the apparatus comprising a support affording or supporting a mould or base, first depositor means for depositing a first layer of curable material in a viscous flowable state on the mould or base, second depositor means for depositing a second layer of a curable material in a viscous flowable state on the first layer, and vibratory means adapted to apply localised vibration of the second layer in order to consolidate it. 20. Apparatus * according to Claim 19 and additionally comprising one or more further depositor means for depositing one or more further layers of curable material in a viscous flowable state on the second layer and further vibratory means adapted to apply localised vibration to the ' surface of the or each further layer in order to consolidate it. 21. Apparatus according to Claim 19 or Claim 20 wherein depositor means and vibratory means are disposed at successive stations, and the mould or base is arranged to move successively through said stations. 22. Apparatus according to any one of Claims 19 to 21 wherein additional vibratory means are provided, adapted to apply localised vibration to the surface of the first layer before the second layer is deposited thereon. 23. Apparatus according to any one of Claims 19 to 22 wherein the or each vibratory means is a vibratory screeding means. 24. Apparatus according to any one of Claims 19 to 23 wherein the base or mould has side walls to confine the layers to the region of the base or mould. 25. Apparatus according to any one of Claims 19 to 23 wherein one or more of said depositor means comprises a spray head adapted to deposit a glass fibre reinforced hydraulic curable material. 26. Apparatus according to Claim 25 and Claim 21 wherein the or each spray head is movably mounted at the associated station to traverse across the direction of movement of said mould or base. 27. Apparatus according to Claim 23 and Claim 21 wherein the or each screeding means is guided and orientated accurately relative to the base or mould whereby the relationship between the surfaces of the composite sheet is accurately controlled. 28. A composite sheet material when made by the method * of any one of Claims 1 to 17. U 29. A composite sheet material comprising a matrix of cured hydraulic cement having three thickness zones defined by the presence of different other constituents within the matrix of adjacent zones, the outer zones including alkali resistant glass fibre as such another constituent and the inner zone including a lighweight aggregate as such another constituent, the opposite faces of the sheet material having an accurately controlled relationship. 30. A method of producing a composite sheet material • substantially as hereinbefore described with reference to and as illustrated in Figures 1 to 4 of the accompany¬ ing drawings. 31. An apparatus for producing a composite sheet material substantially as hereinbefore described with reference to and as illustrated in Figures 1 to 4 of the accompanying drawings. 32. A composite sheet material substantially as herein¬ before described with reference to and as illustrated in Figure 5 of the accompanying drawings. ϋTυREΛi.- OMPI

Inventors: CROSS S
Applicants: CROSS S, TARMAC IND HOLDINGS LTD
Application year: 1980
Main classification: B28B1
IPC codes: B28B1, B28B5