Artifically flavoured edible oils or fats

Abstract: A partially encapsulated flavor is disclosed. Specific volatile components of the flavor which have offensive odors are encapsulated in an oil-insoluble material. The remaining, less volatile components are not encapsulated. This partially encapsulated flavor is particularly useful for flavoring foods such as edible oils and cooking oils. Also disclosed is a water-soluble flavorant in which specific volatile components having offensive odors are encapsulated in a water-insoluble material. The remaining less-volatile components are not encapsulated.

Description: FLAVOR COMPOSITION AND USE THEREOF IN FOODS This invention relates to food flavor compositions. Butters or margarines generally do not develop an unpleasant odor at room temperature or upon heating. Oleaginous materials which contain artificial butter flavors having the same ingredients as butter often develop an unpleasant odor at room temperature and also when heated. This is particularly true when these artificial butter flavors are used in a non-aqueous medium, for example, frying or grilling fats and cooking oils. The unpleasant aroma of these flavored goods is caused primarily by the volatilization of certain flavor components such as butyric acid, hexanoic acid and diacetyl which are either insoluble or only slightly soluble in oils. In butter or margarines, these volatile components are dissolved in the water portion of a water-in-oil emulsion, and thus are not as readily available for volatilization. The problem of unpleasant odour development in artificial butter flavors due to volatilization has long been recognized. U.S. 2,527,785, issued to Armstrong in 1950, attempts to solve this problem by incorporating the butyric acid as a non-volatile salt, for example, sodium butyrate. The flavor solution, however, has to be buffered to keep the salt from hydrolyzing. Others have tried to overcome the problem by encapsulating the total butter flavor using watersoluble encapsulating ingredients. However, when these encapsulated systems are added to edible oils, the flavored oils do not have a pleasant buttery aroma at room temperature. This unpleasant aroma problem is not limited to butter flavors. Artificial meat flavors also have volatile components which have unpleasant odors; for example, methyl mercaptan, dimethyl sulfide and hydrogen sulfide, a! well as volatile fatty acids. Surprisingly, it has been found that partial encapsulation of the flavor, i.e. encapsulation of specific volatile ingredients produces an artificially flavored oil which has a pleasant aroma at room temperature and at elevated temperatures. A full balanced flavor impression is achieved when foods contain;ng,the flavor are eaten. It is an object of this invention therefore to produce an artificial flavorant, particularly meat and butter flavors which have a pleasant aroma at room temperature and at cooking or grilling temperatures, when used in such foods as oils, shortenings, soups, stews, or gravies. It is another object of this invention to produce a flavored food which maintains a balanced flavor after cooking because the volatile components have not been lost. It is a further object of this-invention to produce a flavored food which has improved shelf stability. DETAILED DESCRIPTION OF TF1E INVENTION Artificial flavorants are made up of a number of ingredients or components. These components vary widely in their physical properties. Often, however, they are either water-soluble and substantially insoluble or slightly soluble in oil, or are conversely oil-soluble and substantially insoluble or slightly soluble in water. Therefore, many artificial flavors are either suspended in the oil or water matrix or emulsified therein using surface active agents. In some cases, the flavors are totally encapsulated in order to incorporate them into the oil or water medium. Certain food flavor components have low aroma thresholds, i.e. a very small amount produces a detectable odor. At specific low concentrations this detectable odor may be very pleasant. At high concentrations the aroma often has a'very different character. The combination of high volatility and low aroma threshold is particularly acute when the flavor como- nents have offensive or nauseating aromas at higher concentrations. The high volatility allows them to vaporize from the flavored food at a faster rate than the other less-volatile components. This causes the aroma above the flavored food to be less appetizing or pleasant since the concentration of the malodorous components is higher than in the unvolatilized flavor which was incorporated into the food. In addition, the flavor remaining in the food is not properly balanced since these volatile components contribute importantly to the full flavor compositon. The volatile flavorant components that are most often used in flavored food products are carboxyl compounds, i.e. aldehydes and ketones; polycarbonyls; carboxylic acids; carboxylic acid derivatives such as esters; organosulfhydryl compounds and organic sulfides; heterocycles; and lactones. Specifically, those which have been identified as being volatile malodorous flavor components at higher concentrations are the lower carboxylic acids, diketones, medium chain length aldehydes, sulfurcontaining compounds, and the heterocycles. As used herein, "volatile malodorous flavor component" means the ingredient of a total flavor which has an offensive odor, i.e. unpleasant, sulfury, nauseating, pungent, repulsive, etc. at higher concentrations. The lower carboxylic acids which are generally offensive in odor are those containing up to six carbon atoms. For example, formic (methanoic), acetic(ethanoic), propionic (propanoic), butyric (butanoic), and caproic (hexanoic) acids have particularly unpleasant aromas. The sulfur-containing compounds are notorious for their unpleasant and offensive aromas (rotten egg). However, small amounts of these components are important in the production of full-bodied meat-like, cheese and onion flavors. These compounds include hydrogen sulfide, methyl mercaptan and ethyl ercaptan, as well as the lower alkyl and alkenyl sulfides, disulfides and trisulfides, e.g. dimethyl sulfide, dimethyl disulfide, methylpropyl disulfide methylpropyl trisulfide, allylpropenyl disulfide, allylpropenyl trisulfide, propylpropenyl disulfide, propylpropenyl trisulfides, etc. Heterocyclic compounds containing one or more sulfur or nitrogen atoms also have malodors, yet are used effectively in flavor compositions. For example, 1,3-dithiolane has a sweet, sulfury odor reminiscent of degrading onions, yet it can be used in chocolate and coffee flavors as well. Pyrazines and substituted pyrazines are also importat nut and potato flavor components. Diacetyl is a key component in-butter flavors, and yet it is a volatile malodorous substance. The medium chain length aldehydes, i.e. those having from 4 to 8 carbon atoms, are also characterized by unpleasant aromas at higher concentrations. The aromas range from a chocolatey aroma to an animal smell. Surprisingly, it has been found that to. over- come the malodor associated with these volatile components, and to produce a pleasant smelling, storagestable, good-flavored product, only the volatile malodorous components need be encapsulated in a material which is not soluble in the food. Thus, the total flavor composition which is to be added to an edible fat or oil composition is comprised of volatile malodorous flavor components encapsulated in an oil-insoluble encapsulating agent and lessvolatile and/or oil-soluble flavor components which are not encapsulated. Preferably, the oil-insoluble encapsulating agent will b water-soluble. In general, the volatile malodorous flavor components utilized in flavoring edible fats or oils will be insoluble or slightly soluble in oil and therefore water-soluble. Therefore, the most important advantage derived from this partial encapsulation of the flavor material is that these volatile and malodorous flavor and aroma components are released only when water is added externally. Water provides a vehicle for the release of the flavors as the water-soluble colloidal encapsulating agent and volatile flavor components begin to disperse upon contact with water. The rate and completeness of flavor release are enhanced, it is believed, by abrasive forces resulting from water-flavor particle interaction. Fried potatoes or fried eggs are specific examples of foods which may be so prepared and which may have a noted flavors carrythrough. Physical fracture caused by spreading the oil or fat or by frying foods in it, as well as in nasti- cation also contributes to the flavor release. Encapsulation with materials which undergo a pressure release of the encapsulated material as well as pH and heat release can also be utilized herein. As noted above, when the artificial flavor or flavoring components are added to an edible oil, it is essential that the encapsulating material be oil-insoluble, and preferably water-soluble. Water solubility ensures ready release of the flavor components when the encapsulated particles are moistened or dispersed in water. The normal source of water will be foods being fried, baked, cooked or grilled or otherwise prepared in flavor-enriched shortening. The saliva in the.mouth is also a source of water which will release the flavor components. The preferred encapsulating agents used in this invention are natural gums. The preferred encapsulating gum is dextrin. Dextrin is an intermediate product formed by the hydrolysis of starches. Industrially, it is made by the treatment of various starches with dilute acids or by heating dry starch. The yellow or white powder granules are soluble in water; insoluble in alcohol and ether. The encapsulating agent-flavorant mixture are generally blended in the proportion of 1 to 200 parts of encapsulating agent to 1 part of flavor components. The preferred ratio is 2 to 60 parts of encapsulating - agent to one part of flavorant. While each of the volatile malodorous components can be encapsulated separately, it is preferred that they be encapsulated as a mixture. This provides for a more uniform flavor delivery. Any conventional encapsulating technique can be used. The preferred method utilizes a spraydrying technique to prepare solid particles containing entrapped volatile components of the total flavor or aroma. The volatile components of the flavor are first thoroughly mixed in a water solution of a water-soluble protective coating material such as gelatin, gum arabic, starch or dextrin. This mixture is then sprayed into a column of heated air or gases, which evaporates the water. It is believed that the dry particles resulting from this process comprise a shell or capsule of dry colloid in which the flavoring material is embedded o encapsulated in the form of minute droplets. The flavoring material may also be absorbed into the coating material. This procedure permits the volatile flavor components to be put into a solid, highly watersoluble form which easily lends itself to blending with a wide variety of other ingredients, while also offering protection against evaporation of the volatile components. The partially encapsulated flavors can be added to any edible fat or oil, such as plastic shortenings, liquid shortenings; salad oils, ege- table oils, margarine oils and edible triglycerides, in general. The edible fats and oils can be hydrogenated or unhydrogenated, and can contain mixtures of animal and vegetable fats and oils. Preferably, the encapsulated flavor components and other components of the flavor are incorporated into the edible fats or oils at temperatures of from about 500F to 15GOF and in quantities within the range of from-about 0. 001do to 5% based on the edible fat or oil weight. Any suitable method can be used to add the flavor to the edible fat or oil ingredient. When added to plastic shortenings, the total flavor can be conveniently added in conjunction with the plasticizing operation. It is important that sufficient mixing occurs so that the encapsulated particles as well as the other flavor components are uniformly dispersed and suspended in the edible fats or oils The mixing ad manufacturing procedures are adjusted so that the particle size of the final encapsulated flavoring particle is 420 microns or less. Preferably, the particles will be about 1 to 300 microns in size, more preferably from 50 to 100 microns in size. The actual particle size will depend upon the type of edible fat or oil used. Larger or smaller particles and more or less dense particles tend to migrate or separate out in liquid shortenings and oils under storage conditions. Particle size in plastic shortenings is not critical, as particle suspension is not a problem. For a total flavor composition that is to be used in a water or aqueous medium, such as soups or gravies, the volatile malodorous components can be encapsulated in a water-insoluble encapsulating agent. The encapsulated materials are released by friction, pressure, changes in pH, or heat. One such encapsulating agent which is particularly useful for releasing the flavor on heating is a fat hardstock. This hardstock encapsulating layer can be any natural or synthetic edible monoglyceride, diglyceride, or triglyceride material with a melting point in the range of from about 1000F to about 1600F. Thus, most of the vegetable oils and most animal fats, which have been thoroughly hydrogenated, i.e. to an Iodine Value of 8 or less, are suitable because the melting point of such products is about 1200F or higher. Among such materials are hydrogenated oils of the following substances: cottcnseed, olive, corn, peanuts, soybeans, animal fats of hogs, cattle, and sheep; e.g., lard, oleo oil, oleo stock, oleostearin, tallow and the like. Some natural fats are sufficiently hard to require neither hydrogenation nor fractionation, e.g. some of the vegetable butters such as Chinese vegetable tallow. However, in general, the melting point of the hardstock which is used as the encapsulating agent should not be below about 100OF and, depending upon the amount of flavoring dissolved therein and to the extent to which it will lower the melting point of the finished flavor particles, a minimum melting point of i200F may be required. A preferred method for producing the flavor particles encapsulated by hardstock is by spray cooling, i.e. by prilling, a dispersion of volatile flavor components in the melted shortening. In this prilling process the melted dispersion of the flavoring material and shortening is forced through a nozzle whereby it is atomized and formed into microscopic drops. These drops are allowed to solidify while being cooled, for example, by a cooling gas such as cold air. An especially preferred method of cooling is spraying the atomized droplets into a fibre drum containing dry ice. This spraying into a cold temperature zone causes the atomized, blended composition to coagulate and form discrete micro scopic, encapsulated flavor particles. These single encapsulated flavor materials are thn collected, Other fats with melting points below 980F, such as coconut oil and cocoa butter, can also be used herein as encap & lating materials. These fats melt in the mouth and release the encapsulated materials and thus, obviating the requirement that the food be heated. The non-encapsulated components and the encapsulated volatile malodorous components of the flavor are then dispersed or mixed with the other ingredients of the food. This mixing can be done by any conventional method, so long as the temperature is knept below that of the melting point of the encapsulating agent. The mixing should be such that the total flavor is homogeneously blended into the food's aqueous media. The particle size of the encapsulated flavorant should be such that it remains suspended in the food for the shelf-life of the product. Other components can also be present in the flavored oils or flavored aqueous foods of this invention. These materials include salts, spices, oleoresins, natural flavorants, and soluble artificial flavorants. The partially encapsulated flavor compositions prepared herein can be utilized in any type of prepared food and are not limited to flavored oils and flavored soup or gravy mixes. For example, these materials can be incorporated into any number of prepared foods and mixes, from which the flavor volatilizes. These include meat sauces for pasta dishes, texturized vegetable proteins, dips for vegetabls and snack foods, oil-based sour cream dressings and dessert toppings, water-based fruits, etc. BEST MODES OF PRACTICING THE INVENTION EXAMPLE I Parts of Flavor Butanoic acid 5.8 Hexanoic acid 1 Octanoic acid 6.8 Decanoic acid 41.4 Deltadecalactone 4.4 Gamma dodecalactone 1.4 Deltadodecalactone 10.4 Diacetyl 2.2 The butanoic acid, hexanoic acid and diacetyl are encapsulated in the dextrin using a standard spray-drying technique. The encasulatcd materials and the other flavor components are then mixed with partially hydrogenated soybean oil at about room temperature in a Hobart mixer. The amount of dextrin ih the final flavored oil is 240 ppm (.024t), the total amount of flavor components in the oil is 244 ppm (.024%). A butter-flavored oil having a pleasant aroma is produced. When these same flavor ingredients are added to the oil without encapsulating the hexanoic acid, butanoic acid and diacetyl, the oil has an acrid aroma even at room temperature. When eggs and hashed browned potatoes are fried in the oil prepared in Example I, they have a buttery taste.

Claims: CLAIMS 1. A flavor composition characterized hy;- (a) volatile malodorous flavor material encapsulated in an oil- or water- insoluble encapsulating agent; and (b) other non-encapsulated flavor materials. 2. A composition according to Claim 1 characterized in that said volatile malodorous flavor material is selected from the group consisting of lower carboxylic acids, diketones, medium chain aldehydes, sulfur.-containing compounds, heterocycles, and mixtures thereof. 3. A composition according to Claim I or 2 characterized in that said oil-insoluble encapsulating agent is watersoluble. 4. A composition according to Claim 3 characterized in that said volatile malodorous flavor material is selected from the group consisting of diketones, lower carboxylic acids and mixtures thereof. 5. A composition according to Claim 3 or 4 characterized in that said encapsulating agent is a natural gum. 6. A butter flavor composition according to any of Claims 3 to 5 characterized by: (a) a water-soluble encapsulated mixture of diacetyl, butanoic acid, and hexanoic acid; and (b) a mixture of deltadodecalactone, octanoic acid and decanoic acid. 7. An edible food characterized by edible fat or oil and a flavor composition according to any of Claims 3 to 6. 8. A composition according to Claim 1 or 2 characterized in that said water-insoluble encapsulation material is fat-soluble. 9. A composition according to Claim 8 characterized in that said volatile malodorous flavor material is selected from the group consisting of medium chain aldehydes, sulfur-containing compounds, lower carboxylic acids, and mixtures thereof. 10. A composition according to Claim 8 or 9 characterized in that said fat-soluble encapsulating agent is hardstock having an iodine value of 8 or less.

Inventors: JAPIKSE, CORNELIS HENDRIKUS, MILLISOR, DANIEL HERMAN, ROSEKRANS, DAVID DELAITTRE
Applicants: THE PROCTER & GAMBLE COMPANY
Application year: 1980
Main classification: A23L1
IPC codes: A23L1