COLD-WATER SOLUBLE TAMARIND GUM, PROCESS FOR ITS PREPARATION AND ITS APPLICATION IN SIZING TEXTILE WARP

Abstract: A novel composition of crude tamarind kernel powder (TKP) is disclosed. The novel composition results from a process which makes TKP soluble in cold water; this process is not dependent on purification of TKP, but involves dissolving it in hot water and eva­ porating the resulting solution. The novel TKP compo­ sition has utility in textile, paper, and oilfield applica­ tions.

Description: COLD-WATER SOLUBLE TAMARIND GUM This invention relates to tamarind kernel powder (TKP). TKP is defined herein as tamarind kernel powder obtained from the seed kernels of the tree, Tamarindus indica (Linn), resulting from husking and milling of these seed kernels. TKP includes all of the constituents found in the tamarind seed kernel: polysaccharide (composed of uronic acid and the neutral sugars arabinoss, xylose, mannose, glucose, and galactose), protein, and any other cellular debris from the tamarind kernel seed. This TKP is crude and soluble in cold water (in the rare of 5-350c). TKP is dispersed in water and a solution obtained by boiling in most TKP applications where a purified product is not necessary such as in warp sizing, latex rubber, adhesives, and in the paper - and plywood industries. There exist in the art several purification methods for making a cold-water soluble product from TKP. U.S. 3,287,350 teaches the art of purifying TKP to obtain tamarind seed jellose (TSJ), the polysaccharide constituent of TKP. The process specifies bleaching of the coarsely ground tamarind seed kernels which are then dispersed in a 25-fold amount of water. After injection of steam, the solution is filtered and the TSJ precipitated by using a sulfate and alcohol. U.S. 3,3-99,189 teaches the art of making a cold-water soluble product from TKP by extracting the polysaccharide from tamarind seed kernels with isopropanol at N800C, the polysaccharide then being dispersed in a 25to 35-fold amount of water. Injection of steam and subsequent filtration yield a cold-watersoluble product which is recovered from solution by roll drying or precipitation with an organic solvent. SUtt'ARY OF TE.E INVENTION A process has now been found for producing a novel composition from unpurified tamarind kernel powder which is soluble in cold water. This novel product can be used for the same purposes as TKP. DETAILED DESCRIPTION OF THE INVENTION The prior art processes for preparing a cold-water-soluble tamarind product are based on separation (via precipitation and/or filtration) of the polysaccharide from the other constituents contained in TXP. The present invention teaches the art of preparing coldwater soluble tamarind gum (CWSTG) by a method which does not require purification. This product is similar in appearance and physical properties to TKP; however, its cold-water solubility is unexpected in view of the previously described TKP cold-water solubilization methods from which it may be inferred that the constituents of TKP other than the polysaccharide contribute to TKP's cold-water insolubility and must be removed in order to obtain a cold-water soluble tamarind product. The present invention, via its cold-water- solubilization process, produces a dry, crude TKP product containing all of the TXP constituents and exhibiting cold-water solubility. It is- understood by those in the art that TKP is a commercially available crude product which has trace impurities which vary from shipment to shipment. These impurities comprise metal -shavings, wood pulp,-cellulose from tamarind seed husks, and other plant parts and inorganic impurities. Many of these impurities are inherently insoluble in water and are excluded from the scope of this invention. CWSTG is made by mixing TKP in water at concentrations of 0.1 to 75%; heating this mix to a temperature of 35-1300C, and then drying (and optionally milling) the resulting CWSTG. The heating and drying steps can be combined, as in the drum drying process. The milling step is preferred so as to produce minute particles which readily hydrolyze. TKP subjected to this process exhibits cold-water solubility. As indicated this process does not require the addition of bleaching agents, or any precipitation and/or filtration steps to -yield CWSTG. The process conserves time of preparation, reduces reagent costs, and gives yields of approximately 100%. The constraints inherent in said process are governed by temperature, time, and pressure relationships; i.e., at lower temperatures, longer periods of time are required to develop full solubility. CWSTG can be defined in terms of the viscosity -of a solution prepared with cold water (i.e., 5-35 C. A CWSTG aqueous solution prepared by adding CWSTG powder to cold water and mixing under moderate shear (e.g., Lightnin Mixer at 80Q-1,000 rpm) for one hour develops a viscosity of greater than 10 cP (Brookfield LVF viscometer, spindle 1, 60 rpm) at a 1% concentration and greater than 1,000 cP (Brookfield LVF viscometer, spindle 3, 60 rpm) at 10% concentration. Heating of the TKP/water mix can be accomplished by various methods, including, but not limited to, infra-red irradiation, conven tional steam-heating, drum drying, and microwave heating. The temperature range necessary to achieve cold-water solubility is from 350C to just below degradation temperature of TKP; preferably 35-1300C. TKP held at lower temperatures requires a longer time for viscosity to develop and does not develop the same viscosity as TKP held at higher temperatures. The optimum temperature range is 70-1000C at atmospheric pressure. It is preferred that the TKP concentration range from 4% to 60%. A still more preferred range is 20% to 50%. In addition to the obvious convenience of use, CWSTG represents a substantial energy savings when compared to the standard method of using TKP. In final applications, use levels of TKP and CWSTG are below 10%. The optimum treatment range for preparing CWSTG is as high as 50%. So the total energy needed to heat the water for a C10% final solution of TKP vs CWSTG is at least five times higher for TKP. -Also, since many of the final end uses for- TKP and CWSTG require cold rather than hot water, a further savings is made since with CWSTG there is no hot solution which has to be cooled down to end-use temperatures. An application which utilizes the cold-water solubility of CWSTG is the warp sizing of textile fibers. In this application, CWSTG is made up into a solution of 3-78 solids-and applied. to the yarn to give an add-on level of approximately 6% based on the weight of the fiber. If either the nature of the processing or the-yarn itself requires a more plastic, or flexible, warp-size film, commonly used plasticizers such as glycerin can be added to the CWSTG size to produce the desired plastic level. Following the weaving operation the size can then be easily removed in a cold-water scour containing 2 g/l sodium carbonate and 1 g/l of a surfactant such as TERGITOLO 15-S-9. BTERGITOL is a registered trademark of Union Carbide Corp. The following examples, which are not intended to be limiting, further illustrate the processes of the invention and the novel dry composition, cold-water soluble tamarind gum. In the examples all viscosity measurements are at room temperature. EXAMPLE 1 TKP is dispersed in water to a concentration of 20%, heated to 950C for 10 minutes, then dried and milled. The resulting product is dissolved in water at 2POC and develops a viscosity of 35 cP at 1% concenration, measured on a Brookfield LVF viscometer, spindle 1, 60 rpm. EXAMPLE 2 TKP is dispersed in water at ambient temperature at a concentration of 40%. The resulting paste is drum dried with internal steam pressure at 40 psi, and then milled. The resulting product readily dissolves in ambienttemperature water and imparts a viscosity of 30 cP at 1% concentration, measured on a Brookfield LVF viscometer, spindle 1, 60 rpm. EXAMPLE 3 Comparisons of TKP vs CWSTG A 3% dispersion of TKP is made up by dispersing the TKP in water at room temperature. A solution of CWSTG as prepared in Example 1 is also made up as a 3% solution at room temperature. The viscosities of the dispersion and the solution are measured after 15 minutes of mixing at 1200 rpm on a Lightnin Mixer. The viscosity of the TKP is less than 2 cP as measured on a Brook field LVF viscometer, spindle 1, 60 rpm, compared with the viscosity of the CWSTG which is 400 cP as measured on the Brookfield LVF viscometer, spindle 3, 60 rpm. The respective viscosities are remeasured after 4 hours of mixing. The TKP imparts a viscosity of 10 cP whereas the OnSTG imparts a viscosity of 1,100 cP. These viscosities remain unchanged after 24 and 48 hours. EXAMPLE 4 TKP is srocessed according to the purification process detailed in U.S. 3,399,189 and compared to CWSTG as prepared by Example 2. Compositional analysis shows the following differences between the two gums: EMI7.1 <tb> <SEP> $ <SEP> Molar <SEP> Ratios <tb> <SEP> NEUTRAL <SEP> SUGARS <tb> <SEP> a <tb> <SEP> u <tb> <SEP> 0, <SEP> C, <tb> <SEP> S <SEP> v <SEP> m <SEP> to <tb> <SEP> 0, <SEP> ç <SEP> o <SEP> 0, <SEP> &commat; <SEP> o <tb> <SEP> 0, <SEP> s. <SEP> = <tb> <SEP> 0 <SEP> 0 <SEP> (0 <SEP> 0 <SEP> 0 <tb> <SEP> ffi <SEP> h <SEP> t <SEP> O <SEP> E <SEP> O <SEP> C, <tb> <SEP> dP <SEP> x <SEP> X <SEP> :E: <SEP> O <tb> CWSTG <SEP> 15.0 <SEP> 7-.5- <SEP> 7.0 <SEP> 31.0 <SEP> trace <SEP> 48.0 <SEP> -n4.0 <tb> Processed <tb> TKP <SEP> 7.0 <SEP> 9.0 <SEP> 5.0 <SEP> 36.0 <SEP> ¯¯ <SEP> 45.0 <SEP> 14.0 <tb>

Claims: CLAIMS 1. A cold-water-soluble dry from of crude tamarind kernel powder which, when hydrated at 5-35 C, imparts a viscosity of greater than 10 cP (Brookfield LVF, spindle 1, 60erpm) in a 1% sol ution 2. A cold-water-soluble form of crude tamarind kernel powder which, when hydrated at 5-35 C, imparts a viscosity of greater than 1,000 cP (Brookfield LVF, spindle 3, 60 rpm) in a 10% solution. 3. A process for preparing cold-water-soluble tamarind gum that comprises: (a) mixing TKP in water at a concentration by weight of 0.1 to 75%; (b) heating the water to 35-130 C until the tamarind gum dissolves; and (c) drying the resultant solution. 4. A process as claimed in claim 3 in which the TKP concentration in step (a) is 20-50% by weight and the water in step (b) is heated to 70-100 C. 5. h process as claimed in Claim 3 or in which the heating and drying of steps (b) and (c) are combined in a single operation. 6. A process as claimed in any one of. claims 3 to 5 including the additional step of (d) milling the product of step (c). 7. Cold-water-soluble tamarind gum produced by-a process as claimed in any one of claims 3 to 6. 8. A cold-water soluble warp size comrrisin a concentration of cold-water-soluble tamarind gum in water. 9. A process for the sizing of textile warp, characterised in that a 3-7% aqueous solution of cold-water-soluble tamarind gum is used.

Inventors: RACCIATO, JOSEPH S.
Applicants: MERCK & CO. INC.
Application year: 1979
Main classification: C08B37
IPC codes: C08B37, C08L5, D06M15