IMPROVED IMPREGNATION CAPACITOR AND ELECTRODE FOIL THEREFOR

Abstract: An improved power capacitor dielectric system utilizes the combination of electrode foils (34,35) having a raised dimple pattern on their surfaces, and polypropylene film (36, 37) as the dielectric, the polypropylene film preferably having a texture pattern on one surface. The electrode foil (34,35) suitably comprises a sort annealed aluminum foil strip having a plurality of individual curvilinear surfaced dimple like pro­ jections and depressions from the plane of the foil, said pro­ jections and depressions being coterminous with the length and breadth of the useful foil surface in an electrical capacitor, said dimple-like projections being formed and spaced apart in a manner whereby there is a smooth essentially continuously curving foil surface leading from one dimple to an adjacent projection so that a point on the base of one dimple and a point on the adjacent base of a projection are essentially coincident.

Description: TIThE: IMPROVED IhlPREGNATION CAPACITOR AND ELECTRODE FOIL THEREFOR This invention relates to improved capacitor grade aluminum -foil -and to an improved capacitor including such2 and more particularly to a dielectric fluid filled capacitor structure wherein solid synthetic resin dielectric strips and foil electrode strips have mutually complementary roughened and patterned interface surfaces to stabilize their spaced relationship and to facilitate fluid penetration therebetween. Fluid impregnated capacitors made up of alternating electrode foil and synthetic resin film strips wound in a tight roll form have been difficult-e impregnate with dielectric fluids because although a capacitor roll is wound with a certain degree of looseness, defined as space factor, the fluid must not only penetrate into.the roll from the ends- thereof,- but must also perpetrate the interfaces between film strips which stick together, -and between-film and foil strips which also stick together. In order to overcome this well known and common problem, a a number of solutions have been proposed which relate to complex impregnation cycles and roughening of the foil and/or film surfaces by various surface disfiguration methods, including mechanical and chemical processes.such as foil embossing, abrading, and coating, and film etching. - - ;- - The problems associated with these solutions have been | numerous, ranging from poor overall fluid impregnation and electrical test results, undesirable increase of thickness of the capacitor roll without correlation to the required space factor of the capacitor, and poor economics because of the additional processing required. More importantly the reliability and repeatability of acceptable electrical tests for capacitors produced from the usual manufacturing processes have been deleteriously affected by these prior solutions. It has been discovered that the foregoing problems may be overcome or minimized by the winding together, in roll form, a special unique surface polypropylene film denoted "Hazy" film (TM General Electric Company) and a specially patterned- metal electrode foil surface. This combination, when used with preferred fluids facilitates fluid impregnation of a roll to provide an improved, more stable capacitor-of uniform space factor wherein a synthetic resin film such as polypropylene film is the sole dielectric between foil electrodes. This invention will be better understood when taken in connection with the following description and drawings in which: FIG. 1 'is an exaggerated illustration of a capacitor roll in partly unrolled form to show dielectric film and electrode foil relationships. FIG. 2 is an illustration of an electrical capacitor assembly utilizing a single capacitor roll of FIG. 1 FIG. 3 is an illustration of a high voltage power factor correction capacitor assembly utilizing a plurality of -- the capacitor rolls as shown in FIG. 1. FIG. 4 is a plan view of a section of foil electrode, showing a pattern layout of the electrode foil. ¸'- FIG. 5 is a cross sectional view, in line form, of the patterned electrode foil of FIG. 4. 4 FIG. 6 is an exaggerated illustration of the use od t pattern electrode foil and Hazy film in smooth toeroug g relationship as the sole dielectric in a capacitor. FIG. 7 is an Illustration of 4 modification of the embodiment of FIG 6 showing the use of two Hazy film strips in rough to rough surface relattonshtpv FIG 8 ts an Illustration of a modification of the embodiment of FIG. 7 showing the use of two Hazy film strips In smooth to smooth or head to head relationship. FIG. 9 Is an Illustration of a modification of FfG, 6 showing the use of three Hazy film strips in smooth to rough relationship, FIG 10 Is an Illustration of a folded foil modtfatlon of the embodiment of FIG. 6. PIG. 11 Is a schematic illustration of an electrode foil embossing roll apparatus mounted on a capacitor roll winding machine FIG. 12 is an illustration of a modification of the apparatus of FIG. .10. Description of the Invention Referring now to FIG. t there is illustrated a capacitor roll 10 In a partly unrolled form. Roll 10 Includes a pair of spaced metal foil strip electrodes 11 and 12 and Intermediate polypropylene film strips 13 and 14, Additional poiypropylene film strips 15 and 16 complete the roll so that pairs of polypropylene film strips are found between metal foil electrode strips throughout the roll. Tap straps 17 and 18 are inserted into the roll 10 to ite adjacent the electrode strips to serve as electrical connections for the electrodes. One or more capacitor rolls 10 are-inserted into an appropriate casing, the casing is filled with a dielectric fluid and the fluid is caused to penetrate and permeate the roll to. fill up the spaces between the windings of the roll as well as Into the polypropylene material itself. One such capacitor 19 is shown in FIG. 2 wherein a single roll 10 is included in a can or casing 20 filled with dielectric fluid 21 Cnot shown). Can 20 includes a pair of electrical terminals 22 and 23 to which taps 17 and 18 are connected. Cover 24, which is sealed to can 20, includes a small aperture Cnot shown) which is used to introduce fluid into the can 20 and is thereafter solder sealed as depicted by the solder 25. Another capacitor denoted a power capacitor 26 is illustrated tn FIG. 3 witch Is a capacitor to which this Invention is more parttcularly applicable, In FtGv 3 capacitor 26 Includes a plural- ity of rolls 10 whtch may Be arranged in an upper and lower rows as a two pack design, all of witch are immersed in fluld 21. Casing 20 may exceed 65.0 cm In height, and tube rolls 10 may be from about 10 tnches C25.4 cm) to 12 inches (30.5 cm) in length. Rolls 30 also include taps 17 and 18 which are joined together electrically and to terminals 27 and 28. Where a single pack design is utilized, the rolls are referred to as wide rolls and may be about 60 cm or greater In length. Taps 17 and 18 may be eliminated by use of an exposed foil construction where each electrode foil projects from -a respectIve end of the roll. The foil windings at each end are soldered together and then a connection is made to terminals 27 and 28, Because of the tightness of the windings of rolls 10 and the fact that the metal foil strip electrodes constitute essentially an impermeable lateral barrier, the fluid must enter through the roll ends 29 CFIG. 1) and 30 CFIG.3 ). At this point, because of the elevated temperatures used in vacuum drying of the rolls as well as in the impregnation process, the overlapping polypropy lene fi-Om strip edges at the roll ends tend to seal together as wall as seal to.the electrode strips and swell tightly with adjacent strips when absorbing fluid, thus hindering the penetra tion of the fluid Rnto the roll, In the present invention the combination of Hazy polypropylene film strips and specially patterned metal foil strips provides a control led permeable spacer means and fluid penetration paths ;tnto the rolls 10 from the roll ends in a unique and economical manner. Hazy film is the subject of a U.S. patent application, serial no, 686,832 assigned to the same assignee as the present invention and, for example, U.K. Patent No. 1542671. As best described, Hazy film comprises polypropylene film obtained from a blown tube manufacturing process where tempera tures and speeds are controlled in such a manner that a polypro pylene stalk or tube emanating from an extruder has on its outer surface a continuous and coextensive uniform layer of predominately type irt crystal structures, often referred to as z crystals. Subsequent insufflation of the stalk into a bubble form results in surface discontinulties or craters sometimes defined as surface fibrils extending completely over one surface of the film. These ftbrtis may extend as much as 2 to 3 microns from the base film thickness. As described, the Hazy film of this invention therefore has one surface quite roughened and the opposite surface may be denoted as smooth or shiny. Roughness may be measured by ASTM test D24574O or Dl0003 although a measurement which considers the open space tn a rough surface space factor) is preferred. This irregular surface texture on the capacitor film strips in rolls 10 provides a space factor fn the form of fluid paths between a con ttguous foil electrode and a dielectric strip, or between contiguous dielectric strips to facilitate the penetration of fluid. Modified forts of Hazy film may be obtained from other film processes including the draft and tentering process and film casting process. However, within the realm of this invention other surface roughened films may be employed provided their surface roughness and space factor characteristics are reasonably similar to those of Hazy film, although Hazy film is most preferred. Hazy film has not only a high degree of surface irregularity, but aso a highly desirable high space factor. Space factor is a term describing the measured excess space for example between a measured volume of Hazy film strips superimposed on each other as compared with the measured volume of the same strips without any surface roughness. In other words, the roughness desired is related to a maximum peak to valley measurement over fewer peaks and valleys which would give a high space factor and high impreg nability) as compared to a maximum number of peaks and valleys of lesser dimensions which would give a lower space factor. With known film process conditions surface roughness may be empirically correlated-to space factor by measuring light transmission through the film, for example, as per ASTM D10003, and the measurement obtained is In terms of haze. The use of specially patterned foil electrodes, together with Hazy ftlm providers an improved tmpregnatable capacitor structure. Rustle capacitor electrodes may be foils of various metals, aluminum fotl ts the principle electrode material presently employed. Ordin- artly, these electrodes are about 0.20 to 0.24 mils thickness (5.0 to 6tl microns and are soft annealed aluminium. It has been known to roughen the surfaces of aluminum electrodes in capacitor rolls to facilitate impregnation of the roll by deformation1 etching, abrading, etc. U,S, Patent 3,746,953 is an example. Many such roughened electrode foils were found to have serious disadvantages in that the roughening processes formed trregular projections, sharp edges or caused some larger perforations of the foil leading to sharp edges, and sharp edges are areas of high voltage stress and corona discharge In a capacitor. Atso these sharp edges cause cutting of the adjacent polypropylene film which weakens the dielectric strength of the film at that point. A further disadvantage is that when foils were believed to require a high degree of roughness such as obtained from crimping and knurling processes, these roughened foils retained an . excessive space factor tun the roll. It has been discovered that an improved, uniquely patterned and preconditioned foil minimizes the foregoing impregnation and space factor problems. This foil preferably comprises a soft annealed aluminum foil strip having a plurality of individual curvilinear surfaced dimple like projections and depressions from the plane of the foil, said projections and depressions being coterminous with the length and breadth of the useful foil surface in an electrical capacitor, said dimple-like projections being formed and spaced apart in a manner whereby there is a smooth essentially continuously curving foil surface leading from one dimple to an adjacent projection so that a point on the base of one dimple and a point on the adjacent base of a projection are essentially coincident. Referring now to Fig. 4 there is illustrated a section of a foil strip electorde 11 showing an exaggerated embossed and raised pattern of dimple-like depressions 31 and proturberances 32 thereon. The raised dimple pattern is a pattern projecting equally and oppositely from both sides of the material and from the original thickness of the material so that the overall thickness is significantly greater than the original thickness. The dimple structure is more clearly illustrated in Fig. 5. Referring to Fig. 5 there is illustrated a cross-section, in line form, of the foil 11 of Fig. 4. In one form of this invention the 'dimples are identical to each other, have an ovate like cross section, and extend about 0.0025 inches (about 12.7 microns) from each side of the center lino of the fotl strip. Each dimple 6as a base diameter of less than about GtOl tnch Cahout 0,254 microns} and the dimple or base cen ters are spaced about 0.02 Inches apart about 0.508 microns) as illus- trated tn-PIG. 4. Each dimple may be described in preferred form as haying a circular base and progressively decreasing horizontal circular cross secttons terminating in a rounded or ovate form. The surfaces defining the dimples are smooth flowing curvilinear and tontinuous sur faces from one dimple, as a protuberance, to the next dimple as a depres- The, The. vertical cross section approximates an electrical sine wave form Vindicating that there are no sharp corners or interruptions in curva ture from the surface of one dimple to another. Other forms of cur vilinear bases and cross sections may be employed so long as no sharp corners or ridges are present The circular form described is pre ferred. This preference is based, in part, on the concept that the deformation of a foil strip to provide so many dimples may encompass a process which, in effect, smooths, polishes and work-hardens the foil to preconditton it for capacitor utilization. The foil, as 'described, is referred to as a full dimple pattern foil. By this full dimple pattern, the total capacitor surface of the foil is Involved in the pattern and there are no intermediate significantly unreformed areas. The pattern is described as 100/100 or 120/120 tndicating that there are 200 or 240 dimples, respectively, for each linear inch (2.54 cmi of electrode foil. In other words, the curvilinear surfaces. are essentially continuous over the foil and not interrupted. In this connection the pattern may be extended to greater than 120/120, as conditions merit. It is preferred that each dimple, however, has the same general dimensions as an adjacent dimple so that a regular pattern is obtained with rows of dimples at right angles to each other. The full dimple pattern structure of this invention provides a maximum space between adjacent strips of aluminum foil and filin' - - dielectric strips with a minimum overall increase in space factor. g This texture its attained through the unique structure of the foil. As noted FIG. 5 the dome structure of the simples significantly - increases the tickness of the aluminium foil from an original of the tal thickness of about 0.22 mil (0.5.5 ) to approximatety 1 mil (25.0 ) Thts ts about five times the original thickness, a total thickness which if tncompressible or fixed could not be effectively .ut'ltzed in this Invention, It ts also a condition not ordinarily attained by means of etching, knurling or abrading an aluminum fotl strtp. At the same time the mechanical arch structure of dimples provides increasing or controlled resistance to crush 'tng and dimple erasure or leveling when winding the foil under roll tension into a capacitor roll. However it permits a sub stantial degree of desirable cushioning and leveling In the wind ing process so that tri spite of its orignal thickness the final capacitor roll is within design tolerances. A range of thickness would be an increase from about 2 to 5 times the original thickness, with a preferred thickness being about 2-3 times the original thickness. The metal electrode of this invention becomes a variable or flexible thickness spacer in the capacitor roll winding process as well as in the final capacitor. This flexible or variable thickness is correlated to those imposed forces found in a capacitor manufacturing process so that a desired degree of thickness is retained in the final capacitor. When in the roll, because of the smooth curving dimple profiles, there are no perforations or sharp edges which could penetrate the film dielectri^, or serve as stress concentration areas. Included in this discovery is a basic concept in embossed foil patterns for use in oil filled capacitors of the present invention, and the concept is twofold. First, there is a practical limitation on the peak to valleydimensions of the dimples because an exces siva dimension leads to a larger space factor, a condition which makes roll winding quite difficult and contributes to early electrical failure. The maximum peak to valley dimension also limits the number of dimples per unit of foil length. Secondly, the linear dimple peak to dimple peak dimension should be generally equal to the base diameter of the dimple, and in this manner, the number of dimples per unit length of foil is also limited. The above concept indicates that the pattern on the foil should be correlated to the space factor desired in the capacitor, a high space factor permitting greater dimple height but a lesser number of temples, and a lower space factor providing lesser dimple height, but more dimples per unit length. The important feature is that the sinusoidal pattern in both the length and width dimension and full foil involvement should be retained as close.as possible. ror the purpose of this invention, the capacitor space factor as set forth in the examples and In the claims is that space factor as measured in a capacitor after full swelling of the polypropylene film 5y the impregnating fluid. The bas0 \measurement for the capacitor space factor is the space factor of the Hazy polypropylene ftlm The patterned foil space factor is arbitrarily excluded. The space factor of a Hazy polypropylene film is the ratio of the theoretical, solid volum.e of a film strip as compared to its measured volume including a theoretical planar surface lying along the roughened surface. The ratio is given in percent of the solid volume so that a lOt space factor indicates a volume where the space is lQz dt the solid material. The film space factor is then increased by an amount representing the swel ling of the film by the fluid used at appropriate treat temperatures. The increased amount Is correlated to a probability curve which accomnodates the various tolerances in the manufacturing processes and materials, and a final design or capacitor space factor is determined which is larger than the measured film space factor as above- described. Space factor in the capacitors of this invention is critical to accommodate all the differences in dimensional tolerances of the materials and the different temperature coefficients of expansion of the materials, and the swelling of the materials by the fluids. Space factor Is necessary prior to fluid impregnation in order to have space available for the removal of water and other volatile materials when the capacitor is vacuum dried at elevated temperatures, as well as to meet the necessity of having space through which the impregnating fluid passes to essentially completely impregnate the capacitor roll. Space. factor should be uniform throughout the roll, t.e., there should be some minimum degree of space factor such as a mean or average space factor throughout the roll, and this space factor should be preserved and controlled throughout the winding process, and in the flattening process to flatten the capacitor as illustrated in FIG. l. The mere provision of rough adjacent film and foil surfaces to provide space for the ingress of fluid is not entirely sufficient for capacitor production. Too little space factor and too much space factor are to be avoided. Space alone can be gained in one respect by a more loose winding of the roll. However, there is a resulting loss of uniformity of the required space factor and a softer roll, both of which, because of the tension winding process and roll fiattening process provide critical areas for capacitor failure. The combination of patterned foil and Hazy film is a means to more favorably utilize the space factor of the Hazy film, and to adjustably control space factor in the capacitors as described in this invention. The amount of space factor obtainable from presently available Hazy polypropylene films, t.e., from about 3.0X to about 30%, fs generally insufficient or otherwise undesirable to serve as the total space factor requirement in, for example, power capacitors, and if available in the film is expected to:bP somewhat variable in the capacitor manufacturing process because of film swelling. Furthermore, the roughness on polypropylene film may not be entirely uniform and certain areas may have high roughness and others low roughness, a condition not correlated with variances in film and foil thickness and contributes to the problem of attaining a uniform space factor of some satisfactory degree throughout the capacitor roll. The complementary space factor control means is therefore the full dimple pattern foil of this invention whether or not there is a sufficient amount of space factor already present in the polypropylene film strips. The patterned foil serves as an adjustable cushioning means to provide the desired degree of space factor uniformly throughout the roll. The dimple structure requires an ever increasing force for flattening because of its unperforated dome structure and therefore adjusts itself to varying pressures or forces throughout the roll and in the roll winding process to retain the integrity of the design space factor. It is compressibly deformable and area selective over even a single dome, and more importantly, the total capacitor area of the foil is included in the pattern. This means that each dome supports the film 'so that the film does not touch the foil between domes to reduce the space factor r block fluid penetration, In the practice of this invention the Hazy film and full dimple attern fotl may be wound into a capacitor roll in various arrangements. kne preferred arrangenent uses only Hazy film as the dielectric material ;trips 13 through 56 between the foil electrodes 11 and 121 Such an brrangement is shown tn FIG. 6 in an exaggerated manner with the film md foil strips In spaced relation. Referring now to FIG. 6 the composite 33 comprises a pair of patterned or dimpled foils 34 and 35 and two intermediate Hazy . ftlm strips 36 and 37. In the commercial production of aluminum fotl one surface is usually quite smooth and shiny and the other surface ts referred to as a rough or matte surface. The foil rolling operation involves passing two superimposed foil strips between the rolls and the surface between strips becomes different, te*, rougher than the surface adjacent the rolls. It has been shown that the matte surface actually improves impregnation because of the additional space factor caused by the matte surface. Con sequently, as a further aid to impregnation the aluminum foils are positioned such that the smooth or shiny surface is adjacent the rough surface of the Hazy film, This is referred to as a smooth to rough relationship. Hazy film strips may have the required surface dtscontinuities or roughness on one or both sides. The Hazy film as described in detail herein has but one surface which ts rough. In this latter event when two polypropylene film strips are utilized, they are arranged in what is also referred to as a rough surface to a smooth surface relationship. In this manner each electrode foil strip has a smooth surface which is adjacent a rough surface of a Hazy film strip throughout the roll which facilitates more uniform impregnation of the roll. A further modification of the embodiment of FIG. 6 is villus trated in FIG. 7. In FIG. 7 the composite 38 comprises a pair of Hazy film strips 36 and 37 which are arranged in rough to rough surface relationship. In this arrangement one or both rough surfaces of the electrode foil strips may be adjacent a smooth film strip surface although it is preferred to have one reversed from the other, The i'mpregnatt.ng fluid ts-caused to permeate the rough surface areas between the film strtps and then to proceed laterally through the film strips into the areas between the film strips and the foti strips. Fluid also permeates this area from the roll ends along the electrode foil surfaces. . An additional mod1ftcatton is tllustrated In FIG. 8. Referring to FIG, 8 the composite 39 comprises a pair of dimpled electrode foils 34 and 35 separated by a pair of Hazy film strips 36 and 37 which are arranged in smooth to smooth surface relationship. In this modification the arrangement of the smooth and rough electrode foil strip surfaces is relatively unimportant although it is preferred to have one reversed with respect to the other. A further modification is illustrated in FIG. 9. Referring now to FIG. 9, the composite 40 comprises a pair of dimpled foils 34 and 35 separated by three Hazy film strips 36, 37 and 41. The film strips are all arranged in smooth to rough relationship as a preferred embodiment although there could be a mix of relationships. The electrode foil strips are arranged with a smooth -foil surface adjacent. a rough surface of a film strip. The use of three film strips of FIG, 9 instead of two film strips of FIG. 6 may provide an additional advantage of a higher dielectric strength capacitor. Obviously more than three film strips may be employed as well as a single film strip. - In some cases, and in any of the described embodiments, it may be desirable to fold over one edge of a foil electrode strip because of-tncreased stress at the foil edge. Electrode foil edges are usually referred to as. sharp edged, a condition obtained when the foils are slit to a given width. This slitting is usually accomplashed with a knife edge and the resultant electrode foil edge is sharp and sometimes irregular because of burr like projections which Become the sites for the commencement of corona As can be seen in FIG 6, a high voltage stress field is set up between electrode foil strips 34 and 35 at the roll ends 29 and 30, and any sharp edges or other discontinuities cause or support corona inception. These areas are more susceptible to corona discharge wben lower dielectric constant fluids are used, e,g,, fluids having a dielectric constant in the range of 2,0 to 3,0 as compared to fluids having a dielectric constant in the range of 2.0 to 3.0 as compared to fluids having a dielectric constant above about 3.0 such as the chlorinated.diphenyls and esters, because the flutds are under higher stresses id these areas, FIG. 10 represents an embodiment which minimizes these high stress effects. Referring now to FIG. 10, the composite 42 comprises a wider electrode strip 43 and a narrower electrode foil strip 44 which are positioned in opposed axial relationship to each other, and the electrode foils are sometimes referred to as an upper electrode foil 43 dnd a lower electrode foil 44. In such an arrangement the measured distance between the opposed electrode foil edges is increased. However, it is known that a narrowerefectrode causes 9 higher voltage stress in the area of the narrower electrode edge. As illustrated in FIG, 10, this narrower electrode foil 44 has a folded edge 45 running throughout the roll. This folded edge 45 presents a smooth rounded surface to the high stress area and reduces the field stress at the rounded surface. In addition the folded edge reduces the fluid film between the rolled edge and the adjacent polypropylene film strip, and accordingly reduces the likefibood of breakdown of lower dielectric constant fluid in this area. When folding an electrode foil at its edges it is important that the foil electrode also be folded at its beginning edge width and its terminating' edge width or other means be employed to reduce the stress at those locations. A folded edge between about 0.125 tench C0.3l75 cmi and 0.3 inch (0.l27 cm) will provide satisfactory results, and a range between 0.25 inch (0.635 cm) and Q..375 inch leo.95 cm) is preferred. An additional degree of space factor may be used to accortinodate the folded edge. Best results are attained in this invention, with or without a folded electrode foil, when the final space factor is equal to or greater than an amount which will permit total and unrestricted swelling of the polypropylene film by the fluid In the capacitor. In the usual case polypropylene films as described will swell n capacitors-such as those in the following example, in the range of about 10 to 182 by volume when using the noted fluids, It is important that ingress and egress of a fluid in a capacitor, or in the polypropylene film, or t the intervening spaces not be restricted by a limitation of ttim swelltng, Many capacitor fluids may be effectively employed in this inyention. Included are esters, hydrocarbons, and synthetic fluids sucfi as the alkanes and biphenyls. The dielectric constant of these fluids may vary from about 2.5 to greater than about 5. The stress on the dielectric system is shared in proportion to the dielectric constants of the materials. Higher dielectric constant fluids shift more stress to the film. With a dielectric constant of polypropylene film of about 2.5, the lower dielectric constant fluids will be more highly stressed, and corona conditions at the roll edges may be worsened. Included among these fluids are alkyl benzene, alkyl naphthalene, alkyl biphenyl, alkyl polyphenyl, alkylaryl ethers and alkyl substjtuted derivatives thereof, diaryl alkanes tnd alkyl substituted derivatives thereof, and diaryl ethers and alkyl substituted derivatives thereof, wherein said alkyl groups and alkanes have from 1 to about 20 carbon atoms, said aryt radicals are phenyl, napthyl, biphenyl, or polyphenyl, and said polyphenyls include from 3 to about 5 phenyl groups. One fluid employed in this invention is diary alkane Cphenyl zylyl ethane) cammercially available as Nisseki Condenser oil S (PXE) from Nippon Oil Company, Japan. Another specific fluid is monoisopropyl biphenyl (MIPB) which is a carefully blended mixture of the meta and para substituted biphenyl derivatives. MIPB is represented by EMI15.1 having formula C15ti16 and a molecular weight of 196.3. Monotsopropyl btpbenyl is commerctally available from MonS nto U*S*, and others, as are various mixtures of mono di qnd other tsopropyl biphenyls Other and higher dielectric constant fluids include the cfilorsEenzenes, chlorodiphenyl oxides, and the mixtures of esters and chlorinated aromatic compounds Impregnation of the capacitors of this invention may follow the usual practices associated with polypropylene film capacitors, for example, as disclosed and claimed in U.S. Patent 3,363,156. It is preferred however, to utilize a lower temperature drying and evacuation process in the range of about30.-710bC, preferably 90-110 C and less than about 60 microns of Mg pressure, anda filling process where the capacitor is at 30-80 C, and the fluid is at 30-50 C, Subsequently, the capacitors may be placed in an oven and their tempera tures elevated into a range between about 400C and 100 C, and prefer ably between about 60 to 900C for as much as 40 hours. The following examples are typical of the excellent results following the teachings of this invention. The capacitor space factor used were in the range of from about 5S to about 8X. Hazy film roughness varied from about 10% to 30% space factor of the polypropylene film only. The fluids used were PXE (Fluid A) which was purchased from Nippon Chemical Company as Nisseki Con denser Oil S and contained about 97% phenyl zylyl ethane with the balance a mixture of isomers, and MIPB (Fluid B) which was pur chased from Tanatex Company as Sure-Sol 250. In each case the fluid was carefully refined to high purity and about 0.6 - 0.8X by weight of an epoxide such as ERL 4221-(ccrtrnercially available from Union Carbide Company U.S.) and from about O.O1X to 0.10% 6y weight of an antioxidant material such as 2, 6-di-t-butyl-p- cresol were added thereto. EXAMPLE I A number of capacitors were assembled in accordance with the structure of FIGS. 3, 5 and 6 following the preferred practices set forth. The capacitor rolls were 10.62 inches (26.97 cm) In length and ccn1prised patterned aluminum foil electrodes of about 0.22 mil C5.6 micron thickness with 100 dimples 50/50 per inch C2.54 cm) and two sheets of Hazy polypropylene film having about 10S to 30Y space factor, one strip having a thickness of 0.70 mil C18 microns and the other 1.0 mil (25.4 microns). Each capacitor was on the order of about 26 inches (66.0 cm) in height. The assembled capacitors were oven dried at a temperature in the range of 850C to 1000C and a vacuum of less than 60 microns Hg. for about 26 hours. The capacitors were then allowed to cool to the range from about 500 to 800 C, and the impregnating fluid at a temperature of about 400 to 500 C was introduced into the capacitor under vacuum. After filling, the capacitors are placed in an oven and the temperature raised to from about 65 C to 850 C. After stabilization at temperature, the capacitors were left to soak In the oven for about 20 hours after which temperature is reduced to room temperature, This soaking was repeated second time for an additional 20 hours. Thereafter the capacitors were brought to room temperature, sealed and given certain electrical tests DIV is discharge inception voltage also known as corona start voltage, and the values given are the averages of three readings. DEV is discharge extinction voltage, also known as corona extinction voltage. Dissipation factors %DF or tan 8 (loss angle) and Is given as a watts loss percentage. The results show repetitive excellent capacitors as follows; albeit that the design and test criteria of these capacitors are inordinately severe. Diel. DIV DEV DIV DEV Thick- Diel. Test #f DIV DEV 250 250 1000 1000 ness A Volts Volts Roll Av Av Hrs Hrs Hrs Hrs T C 35.O 1680 7 f 3100 2600 25 35.0 1680 7 f 3200 2500 25 35.0 1680 7qf 3300 2600 25 35.0 1680 7f 3100 2500 25 43.0 1990 4 f 3700 3000 25 3200 2700 80 43.0 1990 4Jtf 3000 2400 25 3400 1990 3400 3100 80 43.0 l990 4 f 4 f 3000 3700 3300 25 4250 2200 3400 2700 .80 43.0 1990 4f 3900 3200 3800 3500 25 5200 4300 3300 3000 80 Datel DIV DEV DIV DEV Thick. Diel. Test "cf DIY DEV 250 250 1000 1000 ness it Volts Volts Roll Av Av Wrs Firs Hrs - Hrs T C 1990 4vtf 3600 3000 3200 3100 25 3600 3100 3000 2700 25 3700 3100 3600 3400 25 3500 3000 3800 3400 25 As can be seen from the above data, these capacitors were subject to severe voltage stress and show very high and stable and repeti tive DIV and DN values. When the noted units were placed on rated voltage for life testing, a first retest occurred at 250 hours, indicating that no units had failed and no significant changes had occurred. Life testing was then continued for a total of 1000 hours, and a retesting occurred on representative units from each example. The DIV and DEV values remained satisfactory with an overall improvement. Dissipation factor and capacitance tests showed excellent values with dissipation factor improving with time, i.e., 120 of rated voltage for 1000 hours and being about 0,01% at 85 C. ''EXAMPLE-Il A further group of seven capacitors were made in accordance with the foregoing Example I, using a roll width of 22.5 inches (57.15 cm). The dielectric thickness was one-sheet of 0.7 mil (18 micronl and one sheet of 1.0 mil t25.4 micron. These capacitors were rated 52j4f and 75 KVAR, with 1990 volts on the dielectric system across the foils. These capacitors were put on a life test at voltages ranging from 2350 to 3600 volts and temperatures rang ing from room temperature to 700 C. All capacitors so tested survived in excess of 500 hours at the higher than rated voltages thus showing the improved capabilities of the dielectric system. EXAMPLE III Further groups of capacitors of various voltage ratings were made up In accordance with Example I and tested. Item #6 was a wide roll 22.5 inches (57.15 cm)* The others were 11.25 inches (28.75 cmi. The pad voltage, i.e., the voltage across the elec trode foils ranged from 7800 to 1990 volts. The dielectric thickness between the electrode foils ranged from 1.5 mil thickness C38.Jt ) to 1.7 mil thickness (43 ). The overall space factor for the total capacitor roll design was in the range of 20% to 30% before impregnation. The results show repetitiveness and certainty of the capacitors made in accordance with the present invention. Volts DF0 Overvoltage 60 hrs 120% Rated V Units KvAR (Rated) 85 C Tested Survived Failed 36 200 9960 021 36 36 0 48 200 14400 018 9 9 0 30 200 7620 021 9 9 0 30 200 7620 025 7 7 0 27 200 12470 015 EXAMPLE IV Several capacitors were made up along the lines of those in Example It The capacitors had rolls of lt,25 inches (28.75cm) in length and 4 f capacity. The capacitors were rated at 1990 volts across the foils. As per FIG. 8 one inside foil had each edge folded over far 0.375 inch (0.95 cm). Electrical tests on these capacitors indicate a marked increase in DIV and DEV values as compared to unfolded designs. EXAMPLE V In this example, special test capacitor units were made up of 15 inch (38.1 cm) rolls with patterned foil having 120/l20 dimples per inch as described with respect to FIG. II. Capacitor space factor was between 5% and 10%. The rolls were'designed for 1670 volts. One sheet of 0.65 mil film (l6.5 > 4) with 5% to 10% space factor and one sheet of 0.7 mil film Cl7.7c) with 5% to lOX space factor were used in the dielectric system as illustrated in FIGS. 3, 5 and 6. Impregnation followed the practices of Example I. The above capacitor units were given corona start voltage tests ranging from -400 C to 250C and exceed 180% of rated voltage. Tests were made for corona extinction voltage which was found to be about l6OZ of rated voltage, both values being excellent for all film capacttors. The use of the full dimple patterned foil of this invention and Hazy film facilitates, lends assurance to the lmpregn'ation of an all film capacitor and represents an improvement in the jmpreg- nation process. The use, in combination of Hazy film and atterned foil lends the requisite assurance and repetitiveness of the results and each supports and complements the other in areas where the other may be deficient. By this means the desirably high values of DEV, for example, are sustained. fhe combination moderates the impregnation parameters which have become so severe for all film capacitors, and provides a structure widely adaptable to various impregnation processes including those of the manifold fill and flood fill kinds, Poly- propylene film, as well as other synthetic resin films, may be easily produced with some degree of surface roughness less than or exceeding the preferred Hazy film of this invention, for example, less than about 5,0, The pattern foil of this invention will provide its unique spacer results over the total range of surface roughness of the synthetic resin film from about 5*0X to greater than 30.0S The space factors of the dimpled foil may be correlated with the space factors of the film in a higher to lower relation ship or lower to higher, as the case may be. The preferred ranges are from about 5,OI to 30.0% space factor for the film, and a foil thickness of about 2 to about 5 times the original thickness. Examination of the full dimple pattern foil removed from assembled capacitors shows areas of minimum and few areas of maximum thickness indicating that the foil conforms to the available space and pres sures where the spaces are due to haze variations, mismatched tolerances, or uneven winding. Such examinations also indicate that the smaller dimples, with a greater number per inch are quite resistant to erasure and persevere to a high degree during the manu facturing process. Examination has also shown that excessive erasure indicates more dimple height than necessary. Consquently, dimple densities above about 100/100 are preferred. Most of the capacitors in the foregoing examples were high voltage power factor correction capacitors. Such capacitors may be rated above about 600 Volts AC to above about 13,800 volts AC, and their dielectric systems are under a high voltage Stress, These capacitors are rated in KVAR (kilovolt ampere reactance) from about 50 KVAR to 4QQ tVAR and above. It ts in these capacitors that the present invention is most applicable and desirable. While it is eminently desirable to use Hazy film in this invention because of the assuredness it lends to the space factor it provides, a satisfactory all film capacitor can be produced solely with the full dimple pattern foil of this invention, particularly the narrow width roll capacitors. However, there are instances where it would appear that either the patterned foil of this invention or the Hazy film will provide improved results. Their use together sometimes masks the contribution of one over the other, which, as before mentioned might be attributable to thetr complementary functions The following Examples provide some indication of the individual contributions of patterned foil and Hazy film. EXAMPLE VI Tn this example the capacitor construction and treatment were similar to those of Example I except that the capacitor rolls were of narrow design 10.62 inches wide (26.9-mm) and relatively smooth filmy e.g., low space factor (LS) are included. High space factor Hazy film tHS1 had an averaga space factor of about 20X. Capacitor space factor was about 5%. The voltage rating of the dielectric was moderate, i.e., about 1200 volts. DC Is Direct Current, AC is Alternattng Current, Vr is rated voltage. The capacitors were rated at 7960 volts and 200 KVAR, DC AC 250 Hrs DC Film 6.5 x Vr 3 x'Vr 6.25 x Vr - 6.25 x Vr LS 1/6 0/3 0/3 1/3 HS 3/6 0/3 0/3 0/3 EXAMPLE VII In this example, duplicate sets of all polypropylene film capacitors were made up where only difference was one group included patterned foil and the other did not. Test results are as follows indicating that pattern foil provides superior results. Capacitor Test Volts T No, Tested No. Failed Time Mrs. Plain foil 660 AC 80 18 4 ,1700 Patterned Foil - - - 660 AC 80 20 0 1700 One of the maJor reasons for the wide range of applicability of the full dimple pattern foil is the smoothness and cushioning effect of the dimple structure. Other projections or depressions formed by crimping, punching, knurling, or by sand blasted rolls . cause sharp edge projections in the foil and many tears and punctures, all of which are highly disadvantageous in a high voltage highly stressed all film capacitor because of corona as described. The dimple or mound shape of the depressions and projections of the patterned foil of this invention utilize smooth flowing surfaces defining geometric ovate shapes which are extremely resistant to total deformation or crushing. These dimples project equidistantly from both sides of the plane of the foil and form a geometric or regular and repeating pattern of equidistantly spaced dimples and rows as illustrated. The pattern is continuous and cotenminous with the active foil surface in a capacitor. The use of the dimple pattern provides an added safety factor to the capacitors of this invention and a more reliant capacitor with respect to many minor abnormalities which may occur in capacitor operation. DC dielectric tests indicate an increased dielectric strength. Preferably the dimpling process is carried out on the winding machine used to wind the capacitor rolls. The major advantage of this procedure is that it obviates the necessity of rewinding the patterned foil on a roll for subsequent winding into a capacitor roll. Such winding and rewinding exposes the dimples to potential damage, principally by crushing. The practice of using foil tension to drive the embossing rolls lends consistency and uniformity to the dimples and the pattern. The improved foil of this invention comprises a combination of defonmtng the full area of the foil and polishing or physically worming the foil tn selected areas which are coterminous 'over the fotl surface. Thins Improved foil may be produced in two more important processes which may be described with reference to FIGS. 11 and 12. In both instances an aluminum foil, U.S. Grade 1143 is used. This Is a comnercial desfgnation of a soft annealed foil of 90.43+Y purity. Referring now to FIG. II, a capacitor roll winding machine 46 has suitably mounted thereon an embossing apparatus 47. In apparatus 47, a roll 48 is a steel roll having on its surface 49 a protruding dimple pattern containing the desired number of dimples per inch, preferably above about 100. Each dimple structure is of the same general structure as described with respect to the dimples of FIGS. 4 and 5 and all dimple heights are preferably the same. A second roll 50 is mounted on machine 46 in parallel relationship with roll 48. The outer surface of roll 50 is a hard but resilient material. This material may be a plastic or rubber like material and excellent results have been obtained with a hard rubber of about 60-80 durometer hardness. Roll 50 is biased against embossing roll 48 by means of suitable biasing or spring means 51. The aluminum foil 37 is pulled from a supply roll 52, and from between rolls 48 and 50 by the driver or capacitor winding roll 53. 'Other supply rolls deliver the other foil electrode and polypropylene dielectric strips to the capacitor roll 53. The depth of penetration of the protruding dimple of the embossing roller 49 into the rubber material of roll 50 falls in the range of from about 0.2 mil (5.0 t ) to about 1.0 inil. (25. > ). Conse- quently when starting with an aluminum foil thickness of from about 5.0 to 6.0 microns thickness, the final thickness of the embossed foil 37 is in the- range of from about 2-5 times the original thick ness of the aluminum foil. Space factors for all film capacitors of this invention (unimpregnated) where part of the space factor is taken up .by textured or hazy surfaced polypr-opylene film indicates that the dimple pattern of this invention should fall in the range of from about 100/100 dimples per inch C2,54 cm) of foil length to. about 500/500 dimples per inch (2.54 cm) of foil length. The embossed pattern which is impressed in the foil by this process, is, in cross section, a sinusoidal pattern as illustrated in FIG. 5 in that the individual dimples are close to each other, press into the resilient roll surface to provide a rounded dimple tip, and the resilient material of the roll 50 is pressed up slightly into the area between adjacent dimples. In this connec tion the full depth of the dimples on the embossing roller 48 is not attained in this embossing process. The dimple height may be on the order of 50.0 or more yet the penetration is limited to a fraction thereof. Consequently the embossing process alters the original plane of the foil and a dimple protuberane Is also generated on the side of the foil opposite the raised dimple pattern surface. Consequently, in cross section an unassumed plane passes through the center of the dimples and the FIG. 5 cross sectional illustration or sinusoidial pattern is obtained. Distance between centerlines of adjacent dimples is about 0.008 inch (200, < ). Again the full foil surface is involved in the embossing dimple pattern because the dimples are fully formed and the original plane of the foil has been faltered. Uith more than 14,000 dimples per square inch, the foil surface and the outer surfaces of the dimple tips are being worked, polished and smoothed, and slight apertures or tear edges and other - irregularities of the foil are also smoothed, for more effective foil operation electrically, The foil of this invention is defined as preconditioned foil because of the worktrig and poliahing of es sentially the total foil surface, and in particular, the working and hardening of the dimple tips which press into the polypropylene film dielectric. Tests indicate that a dimple concentration of 120/120 dimples per inch foil, together with the FIG. 11 process is superior to lesser dimple concentration and the FIG. 12 process in many respects. and is thus preferred, There ts less leveling of the dimples, and easi-er roll winding, yet the resilient spacer concept is preserved. A preferred range of dimples starts above about 100/100 with an upper limit being the upper practical limitations of foil working, preserving distinct patterns maintaining a desirable depth of the pattern. Ordinarily this upper limit is about 500/500 dimples per inch. With increasing numbers of dimples, the overall thickness of the finished foil may be somewhat less than two times the original thickness. However, by changing roll winding techniques and tension, the resilient spacer concept is preserved. The process and apparatus of the noted copending DiNicola et al application as illustrated in FIG. 12 herein may also be used to provide the foil of this invention. Referring now to FIG. 12, the dotted outlines is that of a capacitor roll winding machine 46 with a foil pattern apparatus 54 suitably attached. Apparatus 54 comprises a pair of embossing rolls 55 and 56 which are mounted for rotation on machine 46. Each roll surface is made of steel and is precision etched or engraved to provide moundlike projections thereon. In the alternative, either or both rolls may be of non metallic materials such as hardened plastics or rubbers. The roll surfaces, precisely assembled with appropriate adjustment devices, are brought into mating engagement with each other so that the projections of one roll interfit between projections on the mating roll. External gearing couples the rolls to each other to maintain alignment. In cross section the roll projections defined mound like projections slightly in mesh with the same projections on the opposite roll. The rolls may b adjustable to vary their spaced apart distance to provide a dimple structure in the foil of about 0.0025 inches (about 63.5 microns) from the top of a dimple to the plane of the foil. In the adjustment of the rolls 55 and 06 there is a clearance which is sitnificantly greater than the foil thickness so that only a part of a dimple on the roll protrudes into the foil. The FIG. 12 apparatus does not provide the kind of preconditioning obtained from the FIG. 11 process because the dimple tips are not engaged on the outer surface by an opposing surface by an opposing surface which would work, smooth, and polish the' metal.

Claims: CLAIMS 1. An electrical capacitor grade aluminum foil comprising a soft annealed aluminum foil strip having a plurality of individual curvilinear surfaced dimple like projections and depressions from the plane of the foil, said projections and depressions being coterminous with the length and breadth of the useful foil surface in an electrical capacitor, said dimple-like projections being formed and spaced apart in a manner whereby there is a smooth essentially continuously curving foil surface leading from one dimple to an adjacent projection so that a point on the base of one dimple and a point on the adjacent base of a projection are essentially coincident. 2. The invention as recited in claim 1 wherein said electrodes are aluminum and said embossed dimples are in the range of 0.00125 in. (3.13 ) to 0.0037 (9.5we in height and whose bases are in the range of 0.01 in. (2.54 ) to 0.02 in. (5.08A) in diameter. 3. A process of manufacturing an embossed capacitor grade aluminum foil electrode which comprises, (a) providing a pair of embossing rolls with dimple projections on their surfaces, (b) mounting said embossing rolls so that they are freely rotatable, and adjustable towards each other. (c) adjusting the said embossing rolls so that the dimples on one roll interfit with the dimples on the other roll, (d) positioning a strip of aluminum foil between and engaging said rolls, (e) and driving said rolls solely by means of drawing said aluminum foil between the said rolls to provde an embossed pattern of dimples on said foil. 4. In an electrical capacitor including a casing with electrical terminals thereon and one or more capacitor rolls in said casing and connected to the terminals and a dielectric fluid in the casing and impregnating the roll, the combination of (a) said roll comprising a pair of spaced metallic electrode foil strips and a dielectric therebetween consisting solely of a synthetic resin material and comprising at least one synthetic - resin strip, (b) said electrode foil strips having a full pattern of continuous uniform dimple-like structures coterminou-sly on the surface thereof. (c) said dimple-like structures providing a full thickness which is about 2 to 10 times the original thickness before winding in said roll, (d) said resin strip comprising polypropylene and having one of its surfaces of a roughened texture to provide a film space factor above about 3.0%, and (e) said fluid being selected from the class consisting of esters and hydrocarbons. 5. The invention as recited in claim 4 wherein the number of dimples is above about 100 per inch of foil length and the dimple heights are substantially equal to their base diameter. 6. The invention as recited in claims 4 - 5 wherein said fluid comprises an ester as one component. 7; The invention as recited in claims 4 - 5 wherein said fluid comprises a hydrocarbon. 8. Tilte invention as recited in claim 7 wherein said dielectric comprises a pair of polypropylene film strips, each of which has one roughened surface and one smooth surface and arranged so that one rough surface is adjacent a smorth surface. 9. The invention as recited in claims 7 - 8 wherein said hyrdrocarbon comprises phenyl zylyl ethane. 10. The invention as recited in claims 7 - 8 wherein said hydrocarbon comprises an isopropyl biphenyl. 11. Ln an electrical capacitor as claimed in claim 4 the combinatn on of (a) said roll comprising a pair of spaced aluminum foil electrodes and a dielectric there between consisting solely of synthetic resin z:nd comprising a pair of adjacent polypropylene film strips each of which has surface mrregularities on one surface thereof, said mrregularities providing a film space factor of between about 10% and 30%. (b) said electrode foil strips having a full dimple pattern on each surface of very small closely spaced dimples coterminously on the surfaces thereof, (c) said dimples providing a foil thickness which ns-between 2 and 5 times the original thickness of 0.25 mil (6 ) of the foil before winding in said roll. 12. The invention as recited in claim 11 wherein the space factor of the assembled and impregnated capacitor is between about 5% and 10W. 13. The invention as recited in claims 11 - 12 wherein said dimples are arranged in an essentially continuous pattern of between about 100 and 500 dimples per linear inch (2.54 cm) of electrode foil. 14. The invention as recited in claims 11 - 12 wherein said aluminum foil electrodes have one smooth and one matte surface and they are arranged in the roll so that one smooth surface faces a matte surface and a film strip has its rough surface adjacent a smooth surface of an adjacent foil strip. 15. The invention as recited in claims 11 - 14 wherein said dimples have had their internal and external surfaces smoothed by the interaction of steel dimple on a roll indentig the foil into a plastic roll in sliding relationship caused by pulling the foil from between the said rolls. 16. A high voltage power factor correction capacitor rated between 50 and 400 KVAR. comprising, (a) a casing with electrical terminals thereon and one or more capacitor rolls in said casing and connected to said terminals. (b) a dielectric fluid in said casing and impregnating said rolls, (c) said rolls comprising a pair of spaced aluminum foil electrode strips-wivh a synthetic resin strip threbetween, (d) said synthetic resin s-trip having irregularities -thereon in the form of a hazy surface to provide a film space factor of between about 10% and 30%, (e) said electrode strips having a regular pattern of raised dimples on each of their opposing surfaces coterminously therewith with from about 100 to about 500 dimples per inch (2.54 cm) of foil length on each surface thereof. (f) the height of said dimples and the base diameters of said dimples being generally equivalent. (g) said dimples providing an increased foil thickness between about 2 and 5 times the original foil thickness of less than about 0.25 mil (6z).

Inventors: DINICOLA, NICOLA GUSTINO, NEWCOMB, GEORGE RAYMOND, PASTIR, ROBERT VICTOR, WRIGHT, WILLIAM JERRY
Applicants: GENERAL ELECTRIC COMPANY
Application year: 1979
Main classification: H01G4
IPC codes: H01G4, H01G13