METHOD OF RECOVERING METAL VALUES

Abstract: A method of recovering metal values selected from gold, silver, copper and nickel from an activated carbon support having one or more of these values adsorbed thereon in the form of an alkaline earth metal ionic complex, the metal value forming part of the anionic portion thereof, including the steps of contacting the support with a pre-treatment reagent, followed by desorbing the metal values from the support with water having a low concentration of metal cations such as deionised water, the method being characterised by the pre­ treatment reagent which is a mixture of an organic solvent such as an alcohol or a ketone and an alkali metal cyanide or hydroxide solution.

Description: METHOD OF RECOVERING METAL VALUES THIS invention relates to metal value recovery, in particular to the recovery of gold, silver, nickel or copper metal values from solution. A method of recovering the above metals from supports on which they are adsorbed as complexes is covered by U.S. patent No 3,970,737. According to this method, the metal values are desorbed after pretreatment by contacting the support with water of low metal cation concentration. The water preferably has a low-multi-charged cation (e.g. alkaline earth metal cation) concentration. Concentrations less than 300 ppm, preferably less than 100 ppm, are preferred. In other words the water is relatively pure and has a low ionic strength. Suitable waters are for example distilled, deionised and otherwise softened waters. The above method has particular application to metal values in the form of cyanide ionic complexes, the metal value forming the anionic portion of the complex. Any suitable adsorbent support may be used, carbon, particularly activated carbon, being preferred. It is also disclosed that when the cation associated with the complex is an alkaline earth metal, the complex is adsorbed on to the support very much more strongly than when the cation is an alkali metal, particularly when the complex is a gold cyanide one. Accordingly, if the cation of the complex is an alkaline earth metal, particularly calcium, the support is preferably pre-treated with an alkali metal salt solution pricr to water desorption. Our S.A Patent No 76/4204 describes and claims an improved pre-treatment solution selected from the group of an alkali metal cyanide solution, an alkali metal hydroxide solution and a mixture thereof. According to the present invention, a pre-treatment reagent for an elution process as described above comprises a mixture of an organic solvent and an alkali metal salt and/or hydroxide solution. Thus, the invention provides a method of recovering metal values selected from gold, silver, copper and nick21 from a carbon support having one or more of these values adsorbed thereon in the form of an alkaline earth metal ionic complex, the metal value forming part of the anionic portion thereof, including the steps of contacting the support with a pre-treatment reagent, followed by desorbing the metal values from the support with water having a low concentration of metal cations characterised in that the pre-treatment reagent is a mixture of: (a) an organic solvent, and (b) a solution selected from the group of an alkali metal cyanide solution, an alkali metal hydroxide solution and a mixture thereof. The organic solvent may be an alcohol such as isopropyl alcohol or a ketone such as acetone. Generally, the organic solvent will be present in an amount of from 1 to 10, typically 5, percent by volume of the pre-treatment reagent. An exampl F of a suitable solution for the reagent is one containing an alkali metal 'cyanide concentration in the range 1 to 10 percent by weight and an alkali metal hydroxide concentration in the range 0,1 to 20 percent by weight. An example of another suitable solution for the reagent is an alkali metal hydroxide solution of concentration 0,1 to 20 percent by weight. The pre-treatment will generally be about a half to one bed volume. The pre-treatment is followed, as mentioned above, by the water elutio in the manner described in the above mentioned patents. It has been found that metal values, particularly gold and silver values, can be eluted from activated carbon absorbents at high elution rates and using relatively small volumes of eluant. Consequently, the eluant contains a high metal concentration which is advantageous, particularly for subsequent electrowinning processes. A number of experiments have been carried out using the pre-treatment reagent of the invention. The results thereof are illustrated graphically by the attached Figures 1 to 3: Figure 1: This graph illustrates the elution of gold and silver from an activated carbon. The carbon was loaded with gold and silver from a cyanide leach solution which had a high base metal content. The loaded carbon contained 1,9 percent by weight gold and 0,5 percent by weight silver. The pre-treatment reagent contained 95 volume percent cyanide solution (5% NaCN!O,SaOH) and 5 voluie percent isopropyl alcohol. The extent of pre-treatment was one bed volume. The eluant was deionised water and the elution rate was 2 bed volumes per hour. Figures 2 and 3: These graphs illustrate the elution of gold and silver from an activated carbon which was pre-treated with a number of pre-treatment reagents. The gold and silver was adsorbed on to the carbon from a cyanide leach solution which contained a low concentration of base metals. The loaded carbon contained about 4 percent by weight gold and about 0,5 percent by weight silver. The pre-treatment was one bed volume. The eluant wTs deionised water and the elution rate was 2 bed volumes per hour. On these graphs the lines A,B and C represent the results obtained with the following pre-treatment reagent: A : 95 vol % of a solution containing 0,5% NaOH and 5% NaCN and 5 vol % of isopropyl alcohol. B : A solution containing 10%NaCN and 1% NaOH. C : 95 vol % of a solution containing 2,5% NaCN and 0,25% NaOH and 5 vol % isopropyl alcohol.

Claims: CLAIMb:- 1. A method of recovering metal values selected from gold, silver, copper and nickel from a carbon support having one or more of these values adsorbed thereon in the form of an alkaline earth metal ionic complex, the metal value forming part of the anionic portion thereof1 including the steps of contacting the support with a pre-treatment reagent, followed by desorbing the metal values from the support with water having a low concentration of metal cations characterised in that the pre-treatment reagent is a mixture of: (a) an organic solvent, and (b) a solution selected from the group of an alkali metal cyanide solution, an alkali metal hydroxide solution and a mixture thereof. 2. A method according to claim 1 wherein the organic solvent is present in the mixture in an amount of 1 to 10 percent by volume. 3. - A method according to claim 1 wherein the organic solvent is present in the mixture in an amount of 5 percent by volume. 4. A method according to any one of the preceding claims wherein the organic solvent is an alcohol or a ketone. 5. A method according to claim 4 wherein the alcohol is isopropyl alcohol or the ketone is acetone. 6. A method according to any one of the preceding claims wherein the solution contains an alkali metal cyanide of concentration in the range 1 to 10 percent by weight and an alkali metal hydroxide of concentration in the range 0,1 to 20 percent by weight. 7. A method according to any one of claims 1 to 5 wherein the solution is an alkali metal hydroxide solution of concentration 0,1 to 20 percent by weight. 8. A method according to any one of the preceding claims wherein the carbon support is activated carbon. 9. A method according to any one of the preceding claims wherein the water having a low concentration of metal cations is deionised, distilled or othersJise softened water.

Inventors: DAVIDSON, RAYMOND JOHN, VERONESE, VITTORIO
Applicants: ANGLO AMERICAN CORPORATION OF SOUTH AFRICA LIMITED
Application year: 1979
Main classification: C22B3
IPC codes: C22B3, C22B23, C22B7, C22B15, C22B11