MODIFIED POLYESTER COMPOSITIONS

Abstract: Modified thermoplastic polyester compositions comprise (a) a poly-(1,4-butylene terephthalate) resin or polyester copolymer and, optionally, a poly(ethylene terephthalate) resin, (b) a modifier therefor comprising a combination of a selectively hydrogenation monoalkenyl arene-diene block copolymer resin and an aromatic polycarbonate, and (c) a mineral filler and, optionally, (d) a flame retardant. Modifier (b) and mineral filler (c) provide enhanced resistance to impact fracture, increased strength and improved resistance to heat distortion in articles molded from the compositions.

Description: Description Modified Polyester Compositions This invention relates to modified thermoplastic polyester compositions which are moldable articles of improved impact strength and thermal resistance. More particularly, the invention pertains to compositions of (a) a poly('l,4-butylene terephthalate) resin or a polyester copolymer resin and, option¬ ally, a poly(ethylene terephthalate) resin,which are modified with (b) an effective amount of a resinous combination compris- ing a selectively hydrogenated monoalkenyl arene-diene block copolymer and an aromatic polycarbonate and (c) a mineral filler and, optionally (d) a flame retardant. High molecular weight linear polyesters and copolyesters of glycols and terephthalic or iβophthalic acid have been available for a number of yeεrs. These are described inter alia in hinfield et al, U.S. 2,465,319 and in Pengilly, U.S. 3,047,539, incorporated herein by reference. These patents disclose that the polyesters are particularly advantageous as film and fiber formers. With the development of molecular weight control, the use of nucleating agents and two-step molding cycles, poly (ethylene terephthalate) has become an important constituent of injection moldable compositions. Poly(l,4-butylene tere¬ phthalate) , because of its very rapid crystallization from the melt, is uniquely useful as a component in such compositions. Workpieces molded from such polyester resins, alone or combined with reinforcements, in comparison with other thermoplastics, offer a high degree of surface hardness and abrasion resistance, high gloss, and lower surface friction. Stable polyblends of poly(l,4-butylene terephthalate) and poly(ethylene terephthalate) can be molded into useful unreinforced and reinforced articles. See For and Wa bach, U.S. 3,953,394, incorporated herein by reference. Block copolyesters containing units derived from poly(l,4-butylene terephthalate) and from an aromatic/aliphatic or aliphatic polyesters are also known. See, copending applica¬ tion U.S. Serial No. 752,325. filed December 20, " 1976, incorpor- ated herein by reference.- Such block copolyesters are useful per sε as molding resins and also in intimate combination with poly(l,4-butylene terephthalate) and/or poly(ethylene tere¬ phthalate) . It has been proposed to increase the impact strengths of polyesters by adding various modifiers. For example, Brinkmann et al in U.S. 3,591,659 disclose that a useful family of modifiers comprises polyalkyl acrylates, methacrylates and/or ethacrylates. Barron et al in U.S. 4,044 ,073 disclose that a useful impact modifier for such polyesters is an aromatic poly- carbonate. Schlichting et al in U.S. 4,022,748 disclose that a rubber-elastic graft copolymer having a glass temperature below -20 β C. is a useful modifier. Lane, U.S. 4,034,013, and Farnham et al, U.S. 4,096,202 disclose that useful impact modifiers comprise multiple stage polymers having a rubbery first stage and a hard final stage, preferably including units derived from alkyl acrylates, especially butyl acrylates. Baron et al in U.S. 4,034,016 (corres. German 2,650,870) disclose an impact modifier combination comprising a blend of a poly- urethane and an aromatic polycarbonate. Copending application Serial No. 870,679, filed January 19, 1978, discloses an impact modifier combination comprising a segmented block copolyester ■ and an aromatic polycarbonate. Copending application Serial No.957,801 , filed November 6,1978 under attorney's docket No. GE-809 (8CH-2752/2843/2855 +) discloses an impact modifier combination comprising a blend of a polyalkylacrylate and an aromatic polycarbonate. Gergen et al, U.S. 4,090,996 disclose - S an impact modifier combination comprising a selectively hydro- *genated monoalkenyl arene-diene block copolymer, and an engineer¬ ing thermoplastic, e.g., poly(aryl ether), poly(aryl εulfone) , polycarbonate, acetal, etc. All of the foregoing patents and the application are incorporated herein by reference. Although filled and/or reinforced modifications of the foregoing are described in the above-mentioned references, they lack one or more desirable attributes, when molded. It has now been discovered that such polyesters can be greatly improved in impact strength as molded as well as after- annealing and at -20 β F. , by intimately admixing therewith an impact improving modifier combination comprising a selectively hydrogenated monoalkenyl arene-diene block copolymer resin and an aromatic polycarbonate resin and a mineral filler. As will be shown hereinafter, compositions according to this invention have moderate shrink and reduced warp. They can be produced more readily in a variety of colors. As will also be shown, the new compositions of this invention can also be rendered flame-retardant. Description of the Invention. - According to this invention, there are provided thermoplastic compositions which are useful for molding, e.g., injection molding, compression molding, transfer molding, and the like, the compositions comprising: ( a ) a polyester comprising: (i) " a * poly(l,4-butylene terephthalate) resin; (ii) a blend of a poly(l,4-butylene terephthalate) resin and a poly- (ethylene terephthalate) resin; OMPI (iii) a block copolyester of poly(l,4- butylene terephthalate) and an aro¬ matic/aliphatic or aliphatic polyester; (iv) a blend of (iii) and a poly(ethylene terephthalate) resin; or (v) a blend of (iii) and a poly(1,4- butylene terephthalate) resin; (b) an impact modifier therefor comprising-a combination of: (i) a selectively hydrogenated monoalkenyl arene-diene block copoly.ner; and (ii) an aromatic polycarbonate resin, in an amount of up to 60 parts per 100 parts by weight of (a) and (b) together; and (c) an effective amount of a mineral filler therefor. The polyester resins (a) of the compositions of this invention are available commercially or can be prepared by known techniques such as by the alcoholysis of esters of terephthalic acid with ethylene glycols with the free acids or with halide derivatives thereof, and similar processes. These are described in U.S. 2,465,319, and U.S. 3,047,539, and elsewhere. As has been mentioned, preparation of the block copolyesters is des¬ cribed in Borman, Dolce and Kramer, U.S. Serial No. 752,325, filed December 20, 1976, and incorporated herein by reference. Illustratively, the high molecular weight polyesters will have an intrinsic viscosity of at least about 0.4 deciliters/ gram and preferably, at least 0.6 deciliters/gram as measured in a 60:40 phenol/tetrachloroethane mixture at 30 β C. Especially useful when high melt strength is important are branched high melt viscosity poly(l,4-butylene terephthalate) resins, which include a small amount of e.g., up to 5 mole percent based on the terephthalate units, of a branching component con- taining at least three ester forming groups. The branching component can be one which provides branching in the acid unit portion of the polyester, or in the glycol unit portion, or it can be a hybrid. Illustrative of such branching components are tri- or tetracarboxylic acids, εuch as trimesic acid, pyromelli- tic acid, and lower alkyl esters thereof, and the like, or prefer¬ ably, polyols, and especially preferably, tetrols, such as penta- erythritol, triols, εuch as trimethylolpropane; or dihydroxy carboxylic acids and hydroxydicarboxylic acids and derivatives , such as dimethyl hydroxyterephthalate, and the like. . The branched poly(l,4-butyiene terephthalate) resins and their preparation are described in Borman, U.S. 3,953,404; " incorporated herein by reference. - : Impact modifier (b) comprises a combination of (i) ε selectively hydrogenated monoalkenyl arene-diene block copolym≤ resin and (ii) an aromatic polycarbonate. The block copolymer resins(b)(i) can be made in known ways and they are available commercially from Shell Oil Company, under the trade designation Rraton, and from Phillips Chemical Co., under the trade designε- tion Solprene. Resins in U.S. 4,090,996 can be used, especial- ly those containing units in the linear ABA structure or in the radial A-B-A teleblock structure,derived from styrene and butadiene or isoprene. Especially preferably, the block copolymer will comprise a selectively hydrogenated block copolymer of styrene and butadiene, the butadiene having a - fr¬ i t 2 content of between about 357. and 55%. The polycarbonate resins (b) (ii) can be made in known ways and they are available commercially from sources, e.g.. General Electric Company, Pittεfield, Mass., U.S.A., under the trademark LEXAN. In 5. general, any of the aromatic polycarbonates described in Baron et al, U.S. 4,034,016 can be used, especially those including units .derived 'from bisphenol-A. The fillers will comprise mineral fillers, εuch as clay, mica, talc and the like and preferably clay, and especially that form of clay known as calcined kaolin. The fillers can be combined with reinforcing fillers, εuch as fibrous glass and the like. The fillers can be untreated, but preferably, they will be treated with silane or titanate coupling agents, etc. Especially preferred is kaolin clay surface treated with a silane coupling agent known as gamma a inopropyl triethoxysilane and sold by Union Carbide Corp., under the trade designation A-1100 (GAP). The coupling agent can be applied to the mineral filler by sev¬ eral means. It can be tumble blended, or it can be deposited, e.g., from solution in aqueous methanol. 0 The amount of the filler can vary widely depending on the formulation and needs of the particular composition. Preferably., however, 'the mineral filler will comprise from about 1 to about 907., preferably from about 2 to about 407. by weight of filler (c) and (a) and (b) , combined. Especially preferably 5 the filler will comprise less than about 35 by weight of the combination. It has further been found that even relatively minor amounts of the modifier (b) are effective in providing signifi¬ cant improvements in impact strength, and the like. In general, however, the modifier (b) will be present in amounts of at least about 1% by weight, preferably from about 2.5 to about 507. by weight of (a) and (b) . The ratio of block copolymer to aro¬ matic polycarbonate can vary widely, i.e., within the range of. 1 to 99 parts of the former to, correspondingly, 99 to 1 parts of the latter, but in general, from 60 to 40 parts of the block copolymer will be present for each 40 to 60 parts of the aro¬ matic polycarbonate per 100 parts by weight of (b) . The impact modified polyesters in combination with a filler can be rendered flame retardant with an effec¬ tive amount of a conventional flame retardant agent (d) . As s well known, flame retardants can be based on elementary : red phosphorus, phosphorus compounds, halogen and nitrogen compounds alone or preferably in further combination with ;- synergistε, such as antimony compounds. Especially useful are polymeric and oligo eric flame retardant agents comprising tetrabromobiεphenol-A carbonate units; see, for example, Wa bach, U.S. 3,833,685, which is incorporated herein by refer¬ ence. Other ingredients, εuch as dyes, pigments, drip retard¬ ants, and the like can be added for their conventionally employ- ed purposes. The compositions of this invention can be prepared by a number of procedures. In one way, the modifier and mineral ■ * Ϊ ET, OMFI /., WIPO filler or fire retardants is put into an extrusion compounder with resinous components to produce molding pellets. The modi¬ fier and mineral filler is dispersed in a matrix of the resin in the process. In another procedure, the modifier and mineral filler is mixed with the resins by dry blending, then either fluxed on a mill and comminuted, or then are extruded and chopped. The modifying agent and mineral filler can also be mixed with the resins and directly molded, e.g., by injec¬ tion or transfer molding techniques. It is always important to thoroughly free all of the ingredients; resin, modifier, mineral filler, and any optional, conventional additives from as much water as possible. In addition, compounding should be carried out to ensure that the residence time in the machine is short; the tem- perature is carefully controlled; the friction heat is utilized; and an intimate blend between the resin, the modifier and the filler is obtained. Although it is not essential, best results are obtained if the ingredients are pre-compounded, pelletized and then molded Pre-compounding can be carried out in conventional equipment. For example, after carefully pre-drying the polyester and modifier and the mineral filler, e.g., 4 hours at 250 β F. , a single screw vacuum vented extruder is fed with a dry blend of the ingredients, the screw employed having a long transi- tion section to ensure proper melting. On the other hand, a twin screw extrusion machine, e.g., a 53 m Werner Pfieiderer machine can be fed with resin and additives at the feed oort and O mineral down stream. In either case, a generally suitable machine temperature •will be about 450 to 560 β F. The pre-compounded composition can be extruded and cut up into molding compounds εuch as conventional granules, pellets, etc., by standard techniques. The composition can be molded in any equipment con¬ ventionally used for glass-filled thermoplastic expositions, e.g. , a Newbury type injection molding machine with conventional cylinder temperatures, e.g., 450-535 β F. and conventional mold temperatures, e.g., 130-200°F. The following examples illustrate the invention. They are set forth as .a further description but are not to be construed as limiting the invention thereto. In the data tables, the abbreviation "N.D." means not determined. All parts are by weight EXAMPLES 1 - 3 Dry blends of poly(l,4-butylene terephthalate) resin (PBT) , hydrogenated block copolymer of styrene and butadiene, aromatic polycarbonate of bisphenol-A and phosgene, mineral filler and mold release/stabilizer are compounded and extruded at 520 β F. in an extruder. The extrudate is pelletized and injection molded at 520 β F. (mold temperature 150 β F) . The formulations and physical properties are shown in Table 1. Table 1. - Compositions Comprising Polyester, Block Copolymer, Aromatic Polycarbonate and Cls Example Composition (parts by weight) Poly(l,4-butylene tere¬ phthalate fl ) i 47.6 Poly(1,4-butylene. tere¬ phthalate) Mi i ) 47.6 38.0 S-B-S Block copolymer ^ W 7.5 7.5 15 Aromatic polycarbonate^ '^ x ' 15.0 15.0 15 Satintone clay^ c ' 29.7 29.7 30 Mold/release stabilizers (to make 1007.) Properties Notched Izod impact,ft.lbs./in. 1/8" 1.83 2.18 1.14 Unnotched Izod impact,ft.lbs. 1/8" 42.5 43.4 15.7 Flexural strength, psi 13,010 12,890 10,404 Flexural modulus, psi 493,420 475,180 452,250 Tensile strength, psi 7,160 7,240 5,620 Elongation,7. 24 29 10.7 (a)(i) Valox 300, General Electric Co., melt viscosity 2,300 - 3,800 poise. (a) (ii) " Valox 315, General Electric Co., melt viscosity 7,250 - 9,000 poise (b)(i) Kraton G 1651, Shell Chemical Co., A-.--A linear selectively hydrogenated εtyrene-butadiene-styrene block copolymer (b)(ii) LEXAN 105, General Electric Co. (c) Englehard Co., New Jersey U.S.A. treated with 0.137. by weight of A-1100, gatπmaaminopropyltriethoxysilane coupling agent O The compositions according to this invention exhibit excellent impact strength and- other properties. EXAMPLES 4 - 11 The general procedure of Example 1 is used to make compositions of poly(1,4-butylene terephthalate), S-B-S block copolymer, aromatic polycarbonate and clay. The formulations used and the properties obtained are set forth in Table 2. Table 2. - Compositions Comprising Polyester, Block Copolymer, Polycarbonate and Clays Example Composition(parta by weight) 4 5 6 7 Poly(l, -butylene terephthalate)^ a ) (HI) 42.3 37.3 53.5 53.5 S-B-S Block copolymer( b > ( > 11.3 11.3 11.3 5.0 Aromatic Polycarbonate^ '^ ' 11.3 11.3 5.0 11.3 (c) Clay 35.0 40.0 30.0 30.0 Mold release/stabilizer (to make 1007.) Propertieβ Distortion temp, under load, °F.at 2ι..' ( ngi 185 196 N.D. 182 Warpage, room temp. <1 <1 <1 <1 Warpage, 350°F., 30" 8.7 7.7 8.7 8.7 Notched Izod, ft.lbs./in. 1.52 1.32 1.65 1.52 Unnotched Izod,f .lbs./in. 24.3 22.6. 21.0 36.8 Flexural strength, psi 12,100 12,400 12,400 14,600 Flexural modulus, psi 537,000 593,000 494,000 563,000 Tensile strength, psi 6410 6410 6150 7940 7. elongation 15 22 23 21 Shrinkage, mils/in. 9.4 10.1 13.0 10.7 (a) (iii) Valox 310, General Electric Co melt viscosity 5,000 - 7.500 poise (b)(i) See Table 1 (b)(ii) Translink 445 Clay, Freep vt Kaolin (c) Lexan 105, General Electric Co. Table 2. - Compositions Comprising Polyester, Block (cont'd.) Copolymer, Polycarbonate and Clays Example Composition(parts by weight) 8 9 10 11 (a) (ill) Poly(l,4-butylene terephthalate) 59.9 47.3 47.3 47.3 S-B-S Block copolymer (b) (i) 5.0 11.3 7.5 15.0 Aromatic Polycarbonate^ ' ' ' 5.0 11.3 15.0 7.5 Clay (c - 29.9 30.0 30.0 30.0 Mold release/stabilizer(to make 1007.) Properties Distortion temp.under load,°F.at 264 psi N.D. N.D. 192 N.D. Warpage, room temp. <1 <1 <1 <1 0 Warpage, 350°F. , 30" 6.7 9.3 10.0 11.3 I Notched Izod, ft.lbs./In. 1.32 1.57 1.75 1.60 Unπotched Izod, ft.lbs./In. 34.0 36 49 27.5 Flexural strength, psi 14,500 12,300 14,200 10,500 Flexural modulus, psi 583,000 510,000 586,000 441.000 Tensile strength, psi 7840 6460 7360 5410. 7. elongation 19 2 23 29 Shrinkage, mlls/ln. 12.9 11.3 10.7 13.0 (a) (iii) Valox 310, General Electric Co., 5, 000 - 7, 500 poise (b)(i) See Table 1 (b)(ii) Transllnk 445 Clay, Freeport Kaolin (c) Lexan 105, General Electric Co. \ The compositions of this invention are seen to exhibit excellent impact εtrength, low warpage and low mold shrinkage. EXAMPLES 12 - 21 The general procedure of Example 1 is used to make compositions of poly(1,4-butylene terephthalate), -optionally, poly(ethylene terephthalate), S-B-S block copolymer, aromatic polycarbonate and several different mineral fillers. The formulations used and the properties obtained are set forth in Table 3. OMP Table 3. Compositions Comprising Polyesters, S-B-S Block Copolymers, Polycarbonates and Mineral Fillers Example Composition (parts by weight) 12 13 14 15 16 Poly(l, -butylene tere- phthalate)( a >( i:L1 ) Poly(l, -butylene tere¬ phthalate)(anil) 39.8 24.8 58.2 43.2 Poly(l,4-butylene tere¬ phthalate) a) (* • ) 47.3 Poly(ethylene terephthalate) -- 15 -- 15 -- S-B-S block copolymer(b)(1) 15 15 15 15 7.5 Aromatic polycarbonate'"'(H) 15 15 15 15 15.0 Translink clay -- -- -- -- 30.0 Santlntone clay' c ' 30 30 10 10 Suzorite mica (80S) Stabilizer/mold release (to make 1007.) Table 3. Compositions Comprising Polyesters, S-B-S Block. (cont'd.) Copolymers, Polycarbonates and Mineral Fillers Example Composition (part3 by weight) 17 18 19 20 21 The compositions have especially excellent impact strength, and poly(ethylene terephthalate) can replace at least part of the poly(1,4-butylene terephthalate). EXAMPLES 22 - 31 Impact modified, mineral filled compositions are prepared by the general procedure of Example 1. The formulations and results are set forth in Table 4. 00 I 00 000 25 05 45 Table 4. Compositions Comprising Polyester, Block Copolymer, (cont'd.) Polycarbonate and Mineral Filler Example Composition(parts by weight) 27 28 29 30 31 Poly(1, -butylene terephthalate( a ' 57.2 Poly(l,4-butylene terephtha- 47.3 47.3 Poly(l,4-bulytenβ • terephtha- late(a)(ii) 47.3 47.3 Block Copolymer . S-B-S linear( b >(i> ,. , 7.5 S-B-S radial eleblock^^ 1 ^,, 7.5 __ -- 7.5 S-B-S radial teleblock(b)(i) __ 7.5 7.5 -- Aromatic polycarbonate^ 0 ^ , 15.0 15.0 • 15.0 15.0 Aromatic polycarbonate c )„ Aromatic polycarbonate^ c ' 15.0 Translink 445 clay Minex 10 silicate O Satintone clay 29.7 29.7 29.7 29.7 29.7 ' Stabilizer/mold release (to make 1007.) Properties (Distortion temp.under load, °F.26 psi LNN..DD.. N.D. N.D. N.D. N.D. Warpage, room temp. <1 N.D. N.D. N.D. N.D. Warpage, 350°F./30" 6.3 N.D. N.D N.D N.D Notched Izod ft.lbs./In. 1.9 1.1 1.0 1.6 1.0 Unnotched Izod ft.lbs./In. 64 29 23 31 20 Flexural strength, psi 12,700 N.D. N.D. N.D. - N.D. Flexural modulus, psi 494,000 N.D. N.D. N.D. N.D. Tensile strength, psi 7085 7300 6850 7100 7650 7. elongation 36 12 12 20 7.5 Shrink, mils./in. N.D. N.D. N.D. N.D. N.D. r ~~~~ Valox 300 (b)(1) Kraton G- -1651 (c) Lexan 125 (a)(1) Valox 310 (b))i)' Solprene 512 (c)' Lexan 105 (a)(ii) Valox 295,General Electr • iicc CCoo. , (b)(1)" Solprene 414p (c)" Lexan 145 melt viscosity, 1200 - 1000 poise EXAMPLES 32 - 36 Impact modified, mineral filled compoεitions are prepared according to the general procedure of Example 1. The level of coupling agent on the clay iε varied to monitor its effect on ultimate properties, the formulations and reεults are set forth in Table 5. Table 5. Compositions Comprising Polyester, S-B-S Block Copolymer, Aromatic Carbonate, Clays and Coupling Agent Example Composition(parts by weight) 32. 11 34 35 Poly(1, -butylene terephthalate) a ) 47.4 47.3 47.3 .47.3 47.2 S-B-S Block Copolymer b ) * ■ > 7.5 .7.5 7.5 .7.5 7.5 Aromatic Polycarbonate( '' ' 15.0 15.0 15.0 15.0 15.0 Satintone Clay 29.7 29.7 29.6 29.6 29.6 Coupling agent: gammoaminopropyl- triethoxysilanet e ) 0.20 0.30 0.40 0.50 0.60 I Mold release/stabilizer to (to 1007. by Weight) Properties Notched Izod impact strength.ft.lbs/in. 1.4 1.5 1.6 1.8 1.7 Unnotched Izod impact strength.f .lbs./ 45 46 51 45 51 in. (8) Valox 300 (b)(1) Kraton G1651 (b)(ii) Lexan 145 (e) A-1100 Union Carbide The amount of coupling agent, based on clay, can be varied within the range of 0.66 to Z%-without materially affect¬ ing the impact strength. EXAMPLES 37-38 Fire retarded, Impact modified, mineral filled compositions are prepared by the general procedure of Example 1. The formulations and' results are set forth in Table 6. Table 6. Compositions Comprising Polyester, S-B-S Block Copolymer, Aromatic Carbonate, Clays, and Fire Retardant Example Composition (parts by weight) 37 38 Poly(1,4-butylene terephthalate) a ) 41.7 38.5 S-B-S Block Copolymer( )(i) 6.7 6.1 Aromatic Polycarbonate( e--- e) 13.3 12.2 Satintone Clay 24.7 29.6 Decabromodiphenylether 7.0 7.0 Antimony oxide 6.0 6.0 Stabilizer/mold release (to give 1007.) Properties Notched Izod, ft. lbs./in. 1.2 0.81 Unnotched Izod, ft.lbs./in. 13.1 9.1 I Flexural strength, psi 12,900 13,700 Flexural modulus, psi 20,000 590,000 e*> I Tensile strength, psi 7.300 7,500 Uh 94 Fla mability test 30 mil. sample V-0 V-0 (a) VALOX 315 resin (b)(1) Kraton G-l-51 (b)(ii) Lexan -24- Obviously, other modifications and variations of the present invention are possible in the light of the above teach¬ ings. For example, the mineral filled compositions can be rendered flame retardant, and the poly(1,4-butylene terephthalate) and/or poly(ethylene terephthalate) can be replaced with a copoly- eεter. It is therefore, to be understood that changes may be made in the particular embodiments described above which are within the scope of the invention as defined in the appended claims.

Claims: CLAIMS 1. A thermoplastic composition comprising: (a) a polyester composition comprising: (i) a poly(l,4-butylene terephthalate) resin; (ii) a blend of a poly(1,4-butylene terephthalate) resin and a poly¬ ethylene terephthalate) resin; (iii) a block copolyester of poly- (1,4-butylene terephthalate) and an aromatic/aliphatic or aliphatic polyester; (iv) a blend of (iii) and a poly(ethylene terephthalate) resin; or (v) a blend of (iii) and a poly(1,4- butylene terephthalate) resin; (b) an impact modifier therefor comprising a a combination of: (i) a selectively hydrogenated monoalkenyl arene-diene block copolymer resin; and (ii) an aromatic polycarbonate resin, in an amount of up to 60 parts per 100 parts by weight of (a) and (b) together; and (c) an effective amount of a mineral filler therefor. 2. A composition as defined in Claim 1 wherein the impact modifier (b) is present in an amount of at least about. 1.0 parts by weight per 100 parts by weight of (a) and (b) together. 3. A composition as defined in Claim 1 wherein the modifier (b) is present in an amount of from about 2.5 to about 50 parts by weight per 100 parts by weight of (a) and (b) together. 4. A composition aε defined in Claim 1 wherein the mineral filler (c) comprises calcined kaolin clay. 5. A composition as defined in Claim 4 wherein said clay filler is a silane coupling agent surface-treated clay. 6. A composition as defined in Claim 1 wherein said mineral filler iε present in an amount of from about 1 to about 60 parts by weight per 100 parts by weight of (a), (b) and (c) together. 7. A composition aε defined in Claim 1 wherein each said polyester in component (a) has an intrinsic viscosity of at least about 0.4 deciliters/gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane at 30 C C. 8. A composition as defined in Claim 7 wherein each said polyester in component (a) has an intrinsic viscosity of at least about 0.6 deciliters per gram when meaεured in a εolu- tion in a. 60:40 mixture of phenol and trichloroethane at 30°C. 9. A composition as defined in Claim 1 wherein in components (a) (i) , (a) (ii) and (a) (v) , said poly(1, -butylene terephthalate) resin is linear or branched. 10. A composition as defined in Claim 9 wherein said branched polyester is a high melt viscosity (1,4-butylene tere¬ phthalate) resin which includes a small amount of a branching component containing at least three ester forming groups. 11. A composition as defined in Claim 1 wherein in said block copolymer resin component (b) (i) , the monoalkenyl arene is styrene and the conjugated diene is butadiene or iεo- prene. 12. A composition as defined in Claim 11 wherein said block copolymer has a ABA linear structure. 13. A composition aε defined in Claim 12 wherein said block copolymer is a selectively hydrogenated block co¬ polymer of styrene and butadiene, said butadiene having a 1,2 content of between about 35Z and 557.. 14. A composition as defined in Claim 11 wherein said block copolymer has a radial ABA teleblock structure. * - 15. A composition as defined.in Claim 1 wherein said aromatic polycarbonate resin includes units derived from bisphenol-A. 16. A composition as defined in Claim 1 which also includes (d) a flame-retardant amount of a flame retarding agent. 17. A composition as defined in Claim 16 wherein component (d) comprises a brominated diphenyl ether. AMENDED CLAIMS (received by the International Bureau on 29 April 1980 (29.04.80) 1. A thermoplastic composition comprising: (a) a polyester composition comprising: (i) a poly(l,4-butylenε terephthalate) resin; (ii) a blend of a poly(l, -butylene terephthalate) resin and a poly¬ ethylene terephthalate) resin; (ill) a block copolyester of poly- (1,4-butylene terephthalate) and an aromatic/aliphatic or aliphatic polyester; (iv) a blend of (iii) and a pol (ethylene terephthalate) resin; or (v) a blend of (iii) and a poly(1,4- butylene terephthalate) resin; (b) an impact modifier therefor comprising a a combination of: (i) a selectively hydrogenated monoalkenyl arene-diene block copolymer resin; and (ii) an aromatic polycarbonate resin, in an amount of up to 60 parts per 100 parts by weight of (a) and (b) together; and (c) an effective amount of a mineral filler therefor. 2. . A composition as defined In Claim 1 wherein the impact modifier (b) is present In an amount of at least about 1.0 parts by weight per 100 parts by weight of (a) and (b) together. 3. A composition aε defined in Claim 1 wherein the modifier (b) is present in an amount of from about 2.5 to about 50 parts by weight per 100 parts by weight of (a) and (b) together. OM 4. A composition aε defined in Claim 1 wherein the mineral filler (c) comprises calcined kaolin clay. 5. A composition aε defined in Claim 4 wherein said clay filler is a silane coupling agen,t surface-treated clay. 6. A composition as defined in Claim 1 wherein said mineral filler iε present in an amount of from about 1 to about 60 parts by weight per 100 parts by weight of (a)', (b) and (c) together. 7. A composition as defined in Claim 1 wherein each said polyester in component (a) has an intrinsic viscosity of at least about 0.4 deciliters/gram when measured in a solution in a 60:40 mixture of phenol and trichloroethane at 30°C. 8. A composition as defined in Claim 7 wherein each said polyester in component (a) has an intrinsic viscosity of at least about 0.6 deciliters per gram when measured in a solu ¬ tion in a 60:40 mixture of phenol and trichloroethane at 30°C. 9. A composition as defined in Claim 1 wherein in components (a) (i) , (a) (ii) and (a)(v) , said polyd,4-butylene terephthalate) resin iε linear or branched. 10. A composition aε defined in Claim 9 wherein said branched polyester is a high melt viscosity (1,4-butylene tere¬ phthalate) resin which includes a small amount of a branching component containing at least three ester forming groups. 11. A composition as defined in Claim 1 wherein in said block copolymer resin component (b) (i) , the monoalkenyl arene iε styrene and the conjugated diene is butadiene or iso- prene. 12. A composition as defined in Claim 11 wherein said block copolymer has a ABA linear structure. 13. A composition as defined in Claim 12 wherein said block copolymer is a selectively hydrogenated block co- polymer of styrene and butadiene, said butadiene having a 1, 2 content of between about 35% and 55%. 14. A composition as defined in Claim 11 ■ wherein said block copolymer has a radial ABA teleblock structure. 15. A composition as defined in Claim 1 wherein said aromatic polycarbonate resin includes units derived from bisphenol-A. 16. A composition as defined in Claim 1 which also includes (d) a flame- retardant amount of a flame retarding agent. 17. A composition as defined in Claim 16 wherein component (d) comprises a brominated diphenyl ether. 18. A composition as defined in Claim 1 wherein the mineral filler is clay, mica or talc.

Inventors: DIECK R, WAMBACH A
Applicants: GEN ELECTRIC, GENERAL ELECTRIC CO
Application year: 1979
Main classification: C08L67
IPC codes: C08K3, C08K9, C08L67