METHOD FOR SEPARATING PLASTICS AND METAL FROM METALLIZED PLASTIC

Abstract: Plastics material metallized with a magnetically suscept­ able material, e.g chrome plated ABS, which has been com­ minuted (1, 2) and optionally subjected to a preliminary magnetic separation (3) to remove magnetisable particles, is cooled (5) to below the glass transition temperature of the plastics material end impacted (6) to form a powder disper­ sion of metal and plastics material. Metal particles are with­ drawn from the dispersion by magnetic separation (7, 9) which is preferably carried in two stages, the product of the first stage being graded (8) and the final stage (9) being carried out on tne smaller particle size fraction. The resulting plastics material can be used directly or filtered by extrusion through a screen.

Description: DESCRIPTION This invention relates to a method and apparatus for the Sep-atian of plastics and metal from mttallized plastics. Reclamation of materials from spent or otherwise normally discarded articles has obvious potential for financial as well as environmental benefit. Reclamation of plastic or metal from articles consisting of vital or plastic alone may not require a specialized approach. On the other hand, reclamation of metal, plastic or both from articles comprising intimately combined metal and plastic presents liberation and separation considerations. Several approaches have been proposed. See, for example, U.S. Patents 4,025,990; 4,020,992; 3,995,816; 3,990,641; 3,718,2d4; 3,666,185; 3,643,873; 3,527,414; 2,879,035; and 1,978,204. Generally, however, recovery of metallized plastic, such as chrome plated plastic, has not received, as far as know, particular attention. For example, the above patents typically provide recovery processes for scrap or other normally discarded articles in which there is "embedded or occluded" metal (e.g. U.S. Patent 2,879,005), or in which the metal is not expected to tenaciously adhere to the plastic (e.g. U.S. Patent 4,020,992 relates to bottle caps). (See, also, U Patents 1,978,204; 3,718,284; 3,995,816; and 4,025,990 which show tire recovery; and U.S. Patents 3,527,414 and 3,990,6W1 which show wire recovery). Moreover, in other instances focus is primarily on recovery of metal, e.g. U.S. Patents 3,885,744 and 3,443,873. Reclamation of plastic from metallized plastic presents especially difficult liberation aa well as separation problems. For example, metallized plastic is designed to resist breaking away of mttal from plastic. To this end, prior to Detallization such as plating, the plastic may be etched, abraded or otherwise treated to adhere tenaciously metal to plastic. Even after liberation of netal from plastic, however, separation can be further complicated by additional aspects of certain metallized plastic. For example, the metal may coniprise non-ferrous or essentially non-ferrous metal and even contain non- or substantially non-ferromagnetic metal (veg. copperJ layers. Still further, even low levels of minute particles can render reclaimed plastic unacceptable for return to higher uses, e.g., plating grade thermoplastic. Still other difficulties (e.g. handling of dust generation) that have been overcome in provision of the industrially suitable and economicalìy valuable process of this invention will be more apparent from the following disclosure. According to the present invention, there is provided a method for separation of netal and plastics from metallized plastics material comprising a plastics having a tenaciously adherent metal costing which is magnetically susceptable, which method comprises: : A. erposing pieces of said metallized plastics material to a temperature sufficiently below the glass transi tion temperature of said plastic to maintain its brittleness daring milling; B, impacting the cooled pieces to shatter them, pulverize substantially all of said plastic into a powder and form a plastics and metal dispersion having at least substantially metal particles therein; C. withdrawing from said dispersion a sufficient amount of said metal to provide a reusable plastics material, said withdrawal comprising exposing at least a portion of said dispersion to one or more magnetic separations. The invention also includes an apparatus for continuous reclamation of plastic from metallized plastic, which apparatus comprises: A. cooling means for exposure of pieces of said metallized plastic to a temperature sufficiently below the glass transition temperature of said plastic to maintain its brittleness during impact milling; B. impact means for ahattering said pieces, pulverising said plastic into a powder, and forming a plastic and metal dispersion having at least substantially metal 'particles dispersed therein, said milling means compri consequent liberation of metal from plastic has an optimal occurr- ence when impact of the cooled metallized pieces is against intermeshing impacting pegs in a centrifugal rotary impact mill operating at high speeds. More particularly and preferably, the intermeshing impacting pegs are rectilinear and arranged so as to receive a substantial portion of the pieces at least initially at an angle that deflects them at other pegs. Thus, as the pieces fly out from the centre of the rotary impact mill, they contact a plurality of impact pegs, are shattered and the plastic is pulverized. The metal then exists as at least substantially metal particles dispersed in plastic powder. Nearly all of the metal can then be removed Prom the pulverized plastic by withdrawal of the at least substantially metal particles therefrom. PrWferably, magnetic and particle size separations accomplish this withdrawal. Recycle of larger particles that are obtained by particle size separation enables further pulverization and consequent liberation of plastic and tal. Advantageously, the amount of particles thus recycled for further pulverization can be as low as 10% (or even less) by weight of the particles subjected to particle size separation. This invention permits reclamation of plastic from metal lized plastic even when the metal is essentially non-ferrous and even though it may comprise non-ferromagnetic metal (e.g. copper). The process of this invention as hereinafter described is especially suitable for reclamation and rejuvenation of ther-o- plastic polymer. For example, ABS (acrylonitrile-butadiene-styrene polymer) may be reclaimed or rejuvenated from metallize, e.g. plated, ABS. Other thermoplastic polymers also can be reclaimed or rejuvenated. Examples of such polymers include aryl polymers, such as polyphenyleneoxide < and polyolefins, such as polypropylene. Further, the thermoplastic polymers may be polymer blonds as well as blends with inorganic modifiers, e.g. fillers such as calcium carbonate. Other plastics that are crosslinked in via no degrees and metallized also may be substantially separated from meter in accordance with the invention. Moreover, this invention permits sing a centrifugal rotary impact mill having recti linear impacting pegs; C. agnetic separation means for separating said dspssslon into a magnetic fraction and a lesser magnetic fraction; D. material classifier means for withdrawing at least most by weight of the largest particles from said lesser magnetie fraction; E. high intensity magnetic separation means for separating the smaller particles of said lesser magnetic fraction into a reusable plastic and a magnetic fraction. In a preferred embodiment, this invention permits rejuvenation (i.e., return to functionally original state) of plastic from metallized plastic such as chrome plated plastic. Cryogenic comminution of prepared metallized pieces liberates metal from enough plastic to permit economically effective withdrawal (preferably by steps comprising certain magnetic and particle separations) of nearly all of the metal therefrom. This withdrawal of metal occurs even though the metal may be essentially non-ferrous and may include non-ferromagnetic metal (e.g. copper) layers. Preferably, a purification step (e.g. filtration of molten polymer) provides plastic that may be reused again in metallizing operations. Alternatively, a non-magnetic fraction obtained by magnetic separation after cryogenic comminution may be used for general-purpose applications. The liberation of metal from metallized plastic that permits efficient metal separation in accordance with the invention occurs optimally under special conditions. More particularly, there is first sn exposure of metallized plastic pieces cfdesirably certain size to a temperature sufficiently below the glass transition temperature of the plastic to maintain its brittleness during il- ling. Additionally, this exposure differentially shrinks metal and plastic. Impact of the cooled pieces in a mill then shatters them, pulverizes the plastic, and thereby liberates plastic froc metal. It has been found that this cryogenic comminution and reclamation of metal by product that can provide further economic benefit. his invention is especially suitable for reclamation and reJuferstion of metallized plastic wherein the coating on the plastic comprises chrome plate As is known, such chrome plate may, for example, comprise one or more layers of nickel and copper with a final relatively thin layer of chromium. Plated ABS, for example is used commercially as automotive plastic in decorative mouldings, e.g. grills, headlight housings, trim strips and the like. These plated plastics may comprise nickel, copper and chromium wherein the nickel and copper are at about equal by weight and the chromium comprises much less. Thus, for example, in aqueous plating a typical plating grade ABS moulded object may be first etched (high or low chromic acid). Thereafter it is plated to provide a coating with, for example, metal thicknesses ranging about: strike nickel (0.2-5 tenths of a mil), copper (1-10 tenths of a mil), semi bright nickel (1-10 tenths of a mil), bright nickel (0.5-10 tenths of a mil), and chromium (0.2-5 hundredths of a mil). Moreover, other variations are well known, e.g., use of strike copper rather than strike nickel as well as use of bronzes. Plating to plastic ratios may vary widely but normally comprise between about 1-25 parts by weight metal per hundred parts by weight plastic. A preferred embodiment of the invention will now be described, by way of example only, with reference to the accompanying drawings, in which: Figure 1 illustrates schematically a preferred processing sequence including equipment therefore in which rejuvenation of plastic from large size metallized scrap, e.g. automotive grills, occurs. Figures 2, 3, 4, 5 and 6 illustrate graphically particle size distributions from various stages of the process. ReferrIng to Figure 1, there is shown a preferred embodiment of this invention. It is a generally closed system for recl & ation and rejuvenation of thermoplastic polymer from large size plated scrap, e.g. automotive grills ano headlamp housings. The system is equipped with solenoid valves for control of material flow through pneumatic lines from one stay to another. The material bins are equipped with level detectors. The pneumatic feed lines are equipped with blowers (Bi-B7), venturi loaders (YT,-VT7) and cyclones (C1-C7) that aid in efficient material flow In a preparatory stage workpieces to be processed in accordance with this system are conveyed as in the drawing to Shredder 1/G rinder 2 that comminutes them into pieces suitable for cryogenic grinding. Shredder 1 is particularly advantageous to shred large articles of scrap such as gills so as to reduce wear on Grinder 2. The ground pieces obtained from Grinder 2 preferably ace such that at least about 80% by weight (absent flaked off metal) pass through a sieve having an opening of about 10 millimeters. Larger ground pieces e.g, those retained on sieves with openings about 15 millimeters, may recuire more recycling due to insufficient pulverization during cryogenic comminution. The need for recycling is dependent upon factors such as cooling rate, other dimensions of pieces, amount of metal coating relative to plastic, nature of plastic and metal, impact ill design and peg dimensions and distribution, etc. For chrome plated thermoplastic in which the plastic comprises, for example, ABS and the metal comprises layered nickel, copper, and chrome, the scrap is preferably ground or otherwise prepared so that at least about 5 by weight of the pieces (absent flaked off metal) passes through a mesh having an opening of about 10 (more preferably 5) millimeters. Preferably, at least about 80% by weight additionally passes through a mesh about 15 millimeters. From the Shredder 1/Grinuer 2, the ground pieces are preferably subjected to a magnetic separation. To this end, they are pneumatically conveyed preferably first to a vibratory fesder for Magnetic Separator 3. Magnetic Separator 3 is a permanent drum magnet and, advantageously, removers magnetically susceptable metal that may be flaked off luring the grinding operation, It is desirable, however, that the Magnetic Separator 3 be controlled to remove rather than magneticafly withdrawing them with consequent loss of plastic. Additionally, removal of large particles facilitates later magnetic and other separations. Magnetic Separators 9 provide a high intensity magnetic field through which the powder drops. Adjustment of the material splitters accomplishes removal of remaining magnetically susceptable materials. The splitters which are conzentionally included with such separators, allow variance in the amount of powder separated magnetically. Magnetic Separators 9 reduce the amount of metal in the powder desriably to below g by weight and in preferred operation to less than 1 by weight, e.g., O.c% by weight of the product. The above described process permits preparation of general purpose thermoplastic polymer that may be used alone or, blended with other polymer, if desired to even further reduce impurities. In operation of the preferred process of this invention, however, the non-magnetic fraction from Magnetic Separators 9 is passed to E xtruder 10 wherein it is made molten and passed through one or more screens (e.g. 20-200 mesh). The screens continuously change and filter out residual impurities. After such filtration, the thermoplastic polymer may be used as plating grade thermoplastic, without further blending, if desired. The screening during extrusion may be omitted in whole or, in part to yield thermoplastic polymer suitable as general moulding grade thermoplastic, especially if blended with other such material. The following examples include an illustration of this invention in certain of its preferred aspects and are not intended as necessarily limiting its scope. EXAMPLE I This example illustrates reclamation and rejuvenation of plastic from scrap consisting of chrome plated automotive grills, chrome plated headlamp housing, and other similar scrap. The process apparatus is in accordance with the Figure 1 Equipment and its operation is as follows: 1. Shredder 1 is Model 3CAX-304cE-V available from Blower high speeds (e.g. over 2000 RPM such as 2500-3500 RPM) using intermeshing rotor and stator optimally accomplishes such liberation with particle aizs as previously mentioned. In addition to shattering the pieces of metallized plastic, pulverization of the plastic into a powder thus occurs. Preferably, at least about 8 $ by weight of the plastic passes through a 3 mesh screen, more preferably, for example, chrome plated ABS an 8 mesh screen. Especially desirable liberation of metal occurs when at least about by weight of the plastic passes through a 12 mesh screen. The powder (with at least substantially metal particles dispersed therein) then can be conveyed pneumatically to Magnetic Separator 7 that is fed by a vibratory feeder. Magnetic Separator 7 can be the same as Magnetic Separator 3 except preferably without added rubber roll. At this stage the non-magnetic fraction pneuma tically transferred from Magnetic Separator 7 should d ear ably have about 95% by weight or greater, e .g. 98% by weight of the metal removed. An exposure to a magnetic field in a range of between about 1000 -2500 gauss is preferable for Magnetic Separator 7. If desired, the non-magnetic fraction from Magnetic Separator 7 may be transported directly to an extruder with appropriate screens (e,g. 20-60 mesh) to filter metal and provide reusable plastic, usually general purpose plastic. More preferably, however, the non-magnetic fraction is further fractionated as follows. The non-magnetic fraction is pneumatically conveyed preferably to a vibratory feeder for Material Classifier 8. Material Classifier 8 collects the amallest particles of Separators 9. Material Classifier 8 separates out larger particles e.g. larger than about 3, more preferably 10 to 20 mesh (normally less than 25% by weight of all particles, preferably less than 1 6 by weight). The large particles desirably are pneumatically conveyed back to Cryogenic Feeder 5 for reprocessing. The particles screened out by Material Classifier 8 for recycle are most preferably those on about a 12 mesh or greater screen. While Material Classifier 8 could be omitted, its use advantageously provides an ability to recycle larger particles, if present, that often contain higher amounts of metal pieces by weight. The amcunt used varies to some extent, for example, on feed rate of metallized piects, on amblent climatie conditions and on length of equipment operation. Pieces of metallized plastic (which preferably have been previously ground and subjected to magnetic separation as indicated above) are desirably augered through Cryogenic Feeder 5 by a screw that has cutout flights to promote contact with the cryogenic fluid. The cryogenic fluid, as mentioned, cools the pieces of metallized plastic as they pass through Cryogenic Feeder 5 jifto Impact Mill 6. When temperature sensors within Cryogenic Feeder 5 report temperature elevation above a certain levels (e.g. -1500F) solenoid valves open and adult cryogenic fluid, preferably liquid nitrogen, into Cryogenic Feeder 5. At :s8t one solenoid preferably permits admission of liquid nitrogen at the end of Cryogenic Feeder 5 nearest Impact Mill 6. Another solenoid preferably permits admission of liquid nitrogen into the closed chute between Cryogenic Feeder 5 and Impact Mill 6. Thus, the cryogenic fluid travels with the cooled pieces of metallized plastic into Impact Mill 6. This cryogenic fluid cools Impact Mill 6 during operation. When liquid nitrogen is employed as the cryogenic fluid, its temperature (in the liquid state) ranges at most up to about -320 F. Accordingly, it vapourizes upon contact with warmer surfaces within Cryogenic Feeder 5, Impact Mill 6 and the chute therebetween. Flow of the pieces of metallized plastic along with rotation of Impact Mill 6 draws the vapour through Impact Mill 6 and into Bin 7. Venting of Bin 7 relieves pressure of the expanding vapour passing through Impact Mill 6. Venting of Bin 7 to Shredder 1/Grinder 2 (as shown in Figure 1) additionally aids grinding therein. Moreover, venting of Bin 7 enables better control of pneumatic transport of materials through the system. Impact of the pieces of Impact Mill 6 liberates metal from plastic. As can be understood, this liberation stage is an important feature. It has been found that centrifugal impacting at caly hagnly magnetically susceptable material to avoid excessive @crotessing lossen of plestic. This is accomplished, for example, by @@apping the drum with rubber coating of preferably less than about 2.5 cm thick, e.g. 0.65 cm. the drum speed is preferably about 20-60 such as about 40 @pm. the magnetic portion from Magnetic Separator 3 may further be reprocessed, if desired, but comprise a nearly all m'ta)a The non-magnetic effluent of Magnetic Separator 3 is then preferably pneumatically conveyed to Silo 4 for storage and to permit regulation of material flow through the rest of the process From Silo 4, pieces of metallized plastic (i.e., pieces remaining after grinding and magnetic withdrawal of metal by Magnetic Separator 3) are pneumatically conveyed toCryogenic Feeder 5. Cryogenic Feeder 5 permits their contact with a temperature substantially below the glass transition temperature of the plastic. The precise temperature chosen will vary depending on factors such as thickness and type of thermoplastic; thickness and type of metal; impact mill design and speed; and economics chosen, e.g. amount of recycle of insufficiently pulverized pieces tolerated. The cooling is readily accomplished by conventional means, e.g. by exposure to liquid nitrogen or other fluid cryogenic substance. Advantageously, the cryogenic fluid may be conserved by intermittant introduction into the Cryogenic Feeder 5. Thus, a temperature sensor in Cryogenic Feeder 5 may be used to activate solenoids that admit, for example, liquid nitrogen to maintain desired temperature range. Normally, the amount of liquid nitrogen or other cryogenic fluid used is by weight well below about 2 times the amount of pieces processed, preferably below about equal parts by weight. By i@termittant introduction of liquid nitrogen or other such fluid into ryogenic Feeder 5, with appropriate temperature sensing feed back, # steady state amount of nitrogen may be as low as about 0.2 times @@ weight the amount of pieces being processed at desirable reed ra es, e.g. 500 kg/hr or more A typical range is between about 0,, - 0.6 nitrogen parts per one part metallized plastic Application Co. The Shredder operates at maximum RPN. 2. Gr¯ntler 2 it Model 2437 Series 5000 Granulator avail able from Entroleter Corporation. Grinder 2 operates at maximum RPM. 3. Magnetic Separator 3 is Model HFCC Permanent Magnetic Dum available from Eriez Magnetics. It has a 15 x 24 inch roll with one quarter inch rubber wrap. Magnetic Separator 3 operates at about 40 RPM. 4. Cryogenic Feeder 5 is Cryogrind Model 6C Screw Conveyor available from Air Products and Chemicals, Inc. Nitrogen weight feed rate averages between about 0.3 0.6 per weight of pieces conveyed. Temperature in Cryogenic Feeder 5 ranges between about -2000F #50 F during continuous operation. 5. Impact Mill 6 is Series 30 Heavy Duty Adjustable Impact Mill utilizing a M3S2 Rotor design available from Entoleter Corporation. The mill has intermeshing rotor and stator pegs. The pegs are rectilinear of the following dimensions; Rotor --¸" L. by ¸" W. by I" E; Stator --1/4" L, by ¸" W. by 1 " H. The pegs are arranged so that two opposing corners or each peg lie on a straight line drawn through the centre d the mill. (For further information on mills as Impact Mill 6, reference may be made to Centrimill Bulletin CM-100/2 of Entroleter Corporation). Impact Mill 6 operates at 3000 RPM. 6. Magnetic Separator 7 is a model like Magnetic Separator 3 except it does not have rubber wrap. Magnetic Separator 7 operates at 40 RPM. 7. Material Classifier is Model C-362-V-36't diameter available from Eriez Magnetics. Material Classifier 8 operates such that particles that retained on a 12 mesh return to Cryogrind Feeder 5. 8. Magnetic Separators 9 are 800 - 1200 watt induced Magnetic Roll Separators available from riez Magnetic. 9. Extruder 10 is a six inch single acrew extruder with continuoas screen changer. The screen changer is an 8 inch Berlyn screen changer adapted to the Si > ; anch extruder. The screen continuously passes through the extruding polymer. Cooling at the periphery alloys the polymer to act as a seal. The screen retains sufficient heat, however, to slide through the extrud ing polymer. The screens are 20 and 60 mesh. 10. The venturis are models available from Process Control Corporation with adjustable throat. Each uses a centrifugal fan source. As seen by the drawing, a cyclone at the discharge separates material from an air stream which is ducted back to close the system. Ii. Vibrator Feeders are models available from Lriez Magnetics. The chrome plated scrap comprises about 15 parts by weight metal for each 100 parts by weight ABS. The chrome plate comprises strike nickel (one tenth of a mil); copper (7 tenths of a mil); semi-bright nickel (5 tenths of a mil); bright nickel (3 tenths of a mil); and chromium (one hundredth of a mil). The ABS grills and other pieces are chrome plated in an automotive automate chrome plating operation and constitute scrap. The scrap weights vary mostly from 0.2 to 3 kg. The system is electrically connected to operate automatically. It is self purging. The system is turned on with following sequence. Nitrogen exhaust fan starts for ventilation. The nitrogen start is activated manually. This energizes nitrogen supply solenoids and temperature controllers. This allows nitrogen to be fed to Cryogenic Feeder 5 solenoids. Cryogenic Feeder 5 and Impact Mill 6 solenoids are activated allowing nitrogen to enter Cryogenic Feeder 5. Ready light comes on when temperature drops below 100 F. The automated sequence button is turned on manually after activation of ready light. This energizes all rotary bin level switches, bin level light , impact mill oil mist, healer for Impact Kill 6 starter and Impact Mill 6 starter motor. The starts motor energizes Magnetic Separators 9. After 30 second delay vibratory feeder to Separator 9 starts along with the blower below Bin 10. Thine starte Material Gàssift.er 8. After 10 second de3ay, the vibratory feeder to Classifier 8 starts. This starts the blower belch Bin 4. This starts Magnetic Separator 7. This starts the fan below Bin 7. This starts Cryofeeder 5 control start and the blower below Bin 9. This starts the blower below Silo 4. This starts the blower below Bin 3. This start a Magnetic Separator 3. This starts the blower below Grinder 2. This starts Shredder 1 and Grinder 2. This starts after 90 seconds conveyance of scrap to system. Material flow into Shredder I ie at between about 900 - 1000 kg/hr. Particle samples are taken from various stages in the process after continuous operation. Sieve analysis shows: 1. The Silo has particles that have an average particle size of about 5 ms. (i.e. 50% by weight would pass through a 5 mm mesh screen). 80% by weight of the particles are between 3 - 8 mm. Figure 2 shows their particle distribution as weight percent against log of particle size. 2. Magnetic Separators 7 draw off metal particles to have an average particle size of about 1.8 millimeters, (i.e. half by weight would pass through a screen with 1.8 millimeter opening). About 90% by weight are less than about 3.5 millimeters. Since the metal particles are not spherical and, moreover, easily deformed, the above are approximations. Figure 3 shows their particle distribution weight percent against log of particle size. 3, Particles returned by Material Classifier 8 have an average size of about 3.2 millimeters. 90; are larger than 1.2 millimeters. Figure 4 shows their particle size distribution as weight present against particle size. 4. The non-magnetic fraction from Magnetic Separators 9 have an average particle aize of about 0.6 millimeters. 909 by weight passes through a 16 mesh screen. Figure 5 shows their particle size distribution as weight percent against log of particle size. Figure 6 shows an approximation of particle size versus weight fraction for (n) metallized plastic before Impact Mill 6 (curve A); (2) metal after Impact Will 6 (curve B); and (3) ABS after Impact Mill 5 (curve C). Analysis by a sple from the non-magnetic fraction, from Magnetic Separators 9 it: by weight in one case 0.85 #0.1% metal; in another case 1.05% #0.1% metal. After extrusion through continuous screen changer cf Extruder 10, results show 0.4% +0.1% metal by weight. Samples of ABS extrudate from Extruder 10 exhibit properties shown in Table 1 TABLE 1 A. Specific Gravity (ASTM-D-792) 1.06 B. Tensile Strength 0.2"/min. (ASTM-D-638) 42.7MPa C. Flexural Strength 0.05"/min. Spar 2"; 1/8" bar (ASTM-D-790) 77.9Pa D. Flexural Modulus 0.05"/min Span 2" 1/8"bar (ASTM-D-790) 2715.2MPa F. Notched izod Impact 1/8" bar (ASTM-D-256) 0.112J/mm F. Deflection Temperature (ASTM-D-648) at 66 psi as rec. 96 C at 264 psi as rec. 90 C G. Rockwell "R" Hardness (ASTM-D-785) 111 H. Modulus Elasticity in Tension 2321 .4MPa I. Ash by weight Other samples are moulded and plated to yield new chrome plated grills. The new chrome plated grills exhibit acceptable properties for use as automotive chrome plated grills, EXAMPLE 2 The procedures of Example 1 are followed except the temperatures in Cryogenic Feeder 5 is -175 F #50 F. Results are deemed similar. EXAMPLE 3 The procedures of example 2 are followed except that the pieces entering Cryogenic Feeder 5 are slightly larger on the average, i.e. about 53 by weight would pass through a 7 mm screen. Results are deemed to be desirable. EXAKFLE 4 The procedures of Example 1 are followed except that samples are taken before extrusion through Extruder 10. The samples are blended and conventionally extruded with 50 by weight ABS of general purpose character to form pellets. Properties of samples moulded from the pellets are acceptable for reuse of the blend as general purpose ABS. EXAMPLE 5 The procedures of Example 2 are followed except that chrome plated Noryl thermoplastic replace the chrome plated ABS. Results are deemed to be desirable. EXAMPLE 6 The procedurea of ExemEle 1 are followed except that chrome plated polypropylene replace the pieces of the chrane plated ABS. Results are deemed to be desirable.

Claims: 1. A method for separation of metal and plastics from metallized plastics material comprising a plastics material having a tenaciously adherent metal coating which is magnetically susceptable, which method comprises: A. exposing pieces of said metallized plastics material to a temperature sufficiently below the glass transition temperature of said plastic to maintain its brittleness during milling; B impacting the cooled pieces to shatter them, pulverize substantially all of said plastic into a powder and form a plastics and metal dispersion having at least substantially metal particles therein; C. withdrawing from said dispersion a sufficient amount of said metal to provide a reusable plastics material said withdrawal comprising exposing at least a portion of said dispersion to one or more magnetic separations. 2, A method in accordance with Claim 1, wherein one of the magnetic separations comprises exposing at least most by weight of the smallest particles of said powder to a high intensity magnetic separation. 3. A method in accordance with Claim 2 therein said high intensity magnetic separation provides a non-magnetic fraction comprising one percent by weight metal or less. 4. A method tn accordance with Claim 2 or Claim 3 therein said petal coating comprises a layer of non-ferromagnetic metal. 5. A method in accordance with any one of Claims 1 to 4 therein the material from which metal has been withdrawn is melted and the molten material is filtered through one or more screens. 6. A method in accordance with any one of Claims 1 to 4 wherein the plastics material comprises & thermoplastic material. 7. A method in accordance with Claim 6 wherein said metallized plastics material comprises chrome plated ABS. 8. A method in accordance with any one of Claims 1 to 7 wherein the cooled pieces are impacted against rectilinear impacting pegs in a rotary impact mill. 9. A method in accordance with any one of Claims 1 to 8 wherein prior to impacting, at least about 50; by weight of said pieces of metallized plastics material can pass through a screen with a 10 mm opening and at least about 80% by weight of said pieces can pass through a 15 mill meter opening. 10. A method in accordance with any one of Claims 1 to 9 wherein the plastics materia' is pulverized so that at least about 80% by weight can pass through an 8 mesh screen. 11. A method in accordance with any one of Claims 1 to 9 wherein the metal is withdrawn from the dispersion by magnetically separating the dispersion into a magnetic fraction and a lesser magnetic fraction; withdrawing from said lesser magnetic fraction at least most of thc particles that pass through a 10 mesh screen to form a smaller particle fraction; and magnetically separating said smaller particle fraction into a magnetic fraction and a second ltesser magnetic fraction, said second lesser magnetic portion containing about 1. by weight or metal or less. 12. A method in accordance with any one of Claims 1 to 11 wherein said pieces of m-tallized plastics material are ground and exposed to a magnetic field to remove magnetic material therefrom prior to cooling. 13. A method in accordance with any one of Claims 1 to 12 therein at least about ss by weight of said pieces of metallized plastics material can pass through screen with a 5 millimeter opening prior to iapacting. 14. An apparatus for continuous reclamation of plastic from metallized plastic, which apparatus comprises: A. cooling means for exposure of pieces of said metall ized plastic to a temperature sufficiently below the glass transition temperature of said plastic to main tain its brittleness during impact milling; B. impact means for shattering said pieces, pulverizing said plastic into a powder, and forming a plastic and metal dispersion having at least substantially metal particles dispersed therein, said milling means comprising a centrifugal rotary impact mill having rectilinear impacting pegs; C. magnetic separation means for separating said disper sion into a magnetic fraction and a lesser magnetic fraction; D. material classifier means for withdrawing at least most by weight of the largest particles from said lesser magnetic fraction; ; E. high intensity magnetic separation means for separat ing the smaller particles of said lesser magnetic fraction into a reusable plastic and a magnetic fraction. 15. An apparatus in accordance with Claim 14, which further comprises means to comminute scrap metallized plastic into ground pieces of metallized plastic, and magnetic separation means to separate said ground pieces into a magnetic fraction and said pieces of metallized plastic. 16. An apparatus in accordance with Claims 14 or 15 which. comprises means to extrude said reusable plastic through one or more screens.

Inventors: ANKLIN, RICHARD THOMAS, GALL, RICHARD LEE, MENDE, WILLIAM BENEDICT
Applicants: FORD FRANCE SOCIETE ANONYME, FORD MOTOR COMPANY, FORD MOTOR COMPANY LIMITED, FORD-WERKE AKTIENGESELLSCHAFT
Application year: 1979
Main classification: B03B9
IPC codes: B03B9