Alessandro's b&b was absolutely charming and quite close to the Venezia S. Lucia train station, about a five to ten minute walk. I only stayed for an evening but I wish I had been able to stay longer. Alessandro is a charming host. He welcomed me with wine and plenty of advice on places to eat and things to do. The breakfast he provides is absolutely amazing. He also was very accommodating in allowing me to leave my luggage for several hours after checkout while I explored Venice. The room was very comfortable and the AC was such a relief in the summer heat. I will definitely stay here again if I return to Venice!