We stayed here for one night before our flight in the evening on the next day. The private room & bathroom was in a house near the Mestre train station. Everything was clean and we had everything we need. If you're a light sleeper, bring some ear plugs because there's a motorway nearby. The next morning we went for breakfast at Pasticceria La Partenopea and then headed to the island by train, which only took around 10mins. There are loads of trains throughout the day that head to Venice and also the last train back is quite late. We left our luggage at Left Luggage inside the train station (closes at 8pm) and went to the airport with an ATVO bus, which was very close to the house, too. This would be a good location to stay in for a longer trip, too, and it's very good value for money.