We arranged to meet Alessandro at the station before arriving. When we arrived in Venice he was a phone call away and hopped over to the train station to great us. He was friendly and informative and showed us to the apartment. He also took us for a quick walk around the local area showing us the little supermarket and recommending some places to grab a drink or food.
The apartment itself was amazing. Clean, airy and beautifully decorated.
The location was brilliant - it wasn't too touristy but close to some of the main attractions (Rialtto bridge, St Mark's Square, the Grand Canal etc), as well as being a stones throw from a vaporetto stop and some amazing restaurants. (Thank you for the recommendations!)
I can't recommend this enough. Thanks for helping to make our holiday so enjoyable!