Check-in was smooth - I arrived at 9.30pm and Dario's father was very accommodating. The room was very nice and modern, complete with its own bathroom. Breakfast was offered in the morning with a choice of juices and milk along with Italian pastries. Although Dario's father did not speak much English, he was very helpful and friendly and tried his best to help us in any way. I would highly recommend this space to any traveller in Mestre!
P.S. The area going towards the house from the station feels a bit dodgy but exercise common sense and you should be fine!