# Patent

## Title
Adhesion and/or encapsulation of silicon carbide-based semiconductor devices on ceramic substrates

## Abstract

A SiC die with Os and/or W/WC/TiC contacts and metal conductors is encapsulated either alone or on a ceramic substrate using a borosilicate (BSG) glass that is formed at a temperature well below upper device operating temperature limits but serves as a stable protective layer above the operating temperature (over 1000° C., preferably >1200° C.). The glass is preferably 30-50% B2O3/70-50% SiO2, formed by reacting a mixed powder, slurry or paste of the components at 460°-1000° C. preferably about 700° C. The die can be mounted on the ceramic substrate using the BSG as an adhesive. Metal conductors on the ceramic substrate are also protected by the BSG. The preferred ceramic substrate is AIN but SiC/AIN or Al2 03 can be used.

## Background
RELATED APPLICATION DATA
This application is a continuation of copending U.S. patent application Ser. No. 10/016,578, filed Nov. 1, 2001, now U.S. Pat. No. 6,911,714, to be issued Jun. 28, 2005, which is a division of U.S. patent application Ser. No. 09/351,106, filed Jul. 6, 1999, now U.S. Pat. No. 6,319,757, issued Nov. 20, 2001, which claims priority from U.S. Provisional Application Ser. No. 60/092,039, filed Jul. 8, 1998.


BACKGROUND OF THE INVENTION
This invention relates generally to the adhesion and/or encapsulation of semiconductor devices or circuits on ceramic substrates, and more particularly to the adhesion and/or encapsulation of silicon carbide semiconductors with metal or alloy contacts and conductors, and metal circuits on AIN substrates.
SiC-based semiconductor devices possess tremendous advantages for high temperature and high power solid state electronics. In addition, these devices offer potential advantages for high frequency and logic circuit applications: e.g., power conversion (mixer diodes, MESFETs), and single chip computers (n-MOS, CMOS, bipolar transistors). Non-volatile random access memory SiC CCDs can hold charge for more than a thousand years thus, for example, making hard disks a thing of the past.
The potential maximum average power, maximum operating temperature, thermal stability, and the reliability of SiC electronics, for example, far exceeds Si or GaAs based electronics. The degree to which these advantages of SiC can be utilized, however, is presently constrained by the thermal stability and electrical properties of the metal/SiC junctions. The primary reasons for this are: (1) the power density of SiC devices is limited by the thermal stability of the ohmic contact junctions, and (2) substantial cooling is required to insure the stability of electrical contact junctions.
For a long time, researchers have been striving without success to develop electrical contacts to silicon carbide to overcome the aforementioned constraints. Until these constraints are removed, SiC devices/circuits offer only marginal, if any, advantages over Si and GaAs. Utilization of the full performance potential of SiC itself (for all devices), requires four types of performance-limiting electrical contacts: (1) ohmic to p-type SiC, (2) ohmic to n-type SiC, (3) rectifying to p-type SiC, and (4) rectifying to n-type SiC.
The value of SiC electronics lies in its potential to extend the capabilities of solid state electronics beyond what is possible with Si or GaAs. Thus, suitable electrical contact characteristics obtained in the laboratory—under low stress conditions—must not drift or degrade, due to changes at the metal/SiC junctions, under actual device operating conditions. This requires two additional attributes of metal/SiC electrical contacts. First, the contact metal must form a junction with SiC that is chemically stable to  ̃1000° C. (joule heating at high forward current densities in power SiC devices could easily cause metal/SiC junctions to reach such temperatures) or more. Second, the contact metal (or metallization structure) must act as a diffusion barrier to circuit and bonding metals (electrode metals) at the same temperatures. Metal/SiC electrical contacts demonstrated previously do not come close to meeting all these stability requirements.
Commonly-assigned U.S. Ser. No. 08/612,216 Filed Mar. 7, 1996 (counterpart PCT application PCT/US97/03497, filed Mar. 4, 1997), now U.S. Pat. No. 5,929,523, which is incorporated herein by reference, however, discloses contacts of all four types which have the requisite attributes. What is needed now is a suitable way to package SiC devices with Os and TiC/WC/W contacts and compatible conductive wires or lines on a suitable substrate, so as to be protected mechanically and chemically over a wide range of conditions. The current state of the art fails to meet this need.
Applicant has learned that a TiC contact on SiC does not, by itself, form a diffusion barrier to circuit or bonding metals. Appropriate circuit/bonding metals such as W, Pt, Au and Pd, form intermetallics with TiC. These solid state reactions change the composition of the electrical contact junction, thus degrading it.
In a recent study, Tong et. al. (Ref. 1) examined the feasibility of fabricating large area SiC substrates from CVD-grown SiC layers on Si(100) substrates via pressure bonding between two thermal oxide layers. The process of Tong et al is as follows: (1) chemical vapor deposition of SiC layer on Si(100), (2) thermal oxidation to form a thin layer of SiO2 on SiC layer, (3) fabrication of a separate Si wafer with thicker thermal oxide layer, (4) surface treatments to enhance the subsequent pressure bonding, (5) pressure induced bonding between two thermal oxide layers, (6) high temperature annealing to improve bonding characteristics by densification, (7) lapping (polishing) to remove the oxide layer from the wafer initially with SiC layer, and finally, (8) chemical etching of exposed Si wafer down to SiC layer.
In addition to the complexity of the process of Tong, et al, the bonding between two thermal oxides is undoubtedly hampered by surface roughness, trapped bubbles, outgassing from the thermal oxides, and a thermal expansion coefficient mismatch among Si, SiO2, and SiC (about 20%). Such problems become markedly more detrimental when the operating conditions become harsher. Moreover, Si itself is not suitable for the high temperature (over 250° C. and as high as 1150° C.). Harsh environment applications of SiC electronic devices, because of the thermal expansion mismatch, lower thermal conductivity, and lower melting temperature (1412° C.) of Si, will render the device structurally unstable.
In another bonding study (see Ref. 2), several systems-metals (Al, Ni, Ti, and W), polycrystalline silicon, phosphosilicate glass, and SiO2 have been employed to bond polycrystalline SiC slabs together. However, high temperature annealing (1150° C.) under some controlled ambient conditions (e.g. steam with 2% HCl) was required to achieve effective bonding. This anneal temperature is too high in that it exceeds the stability window of conventional Si devices. Problems associated with the surface roughness of the slabs (as in Ref. 3) arise as well. The bonding process using metallic layers at high temperatures can also lead to silicide formation. This is not suitable for SiC devices because, in the anticipated operating ranges (temperature and environment), the metal layer could become unstable and/or the metal layer will be consumed by the very bonding reaction with SiC which will change the characteristics of the SiC device.
In fact, this instability of a metal layer in contact with SiC at high temperatures has been an obstacle to the development of SiC devices that can fully exploit the advantageous properties of SiC for high temperature electronics. Similarly, the reaction bonding with the phosphosilicate glass poses the potential problem of phosphorous incorporation into SiC, which can change the electrical properties of the device. Thus, a need remains for a suitable SiC-to-substrate adhesion system.
The prior art also has not developed a material and/or process which forms a stable, insulating, and adherent high-temperature (T>1000° C.) encapsulation layer on SiC devices and their related components (metallization on SiC die and AlN package substrate, connecting wires, and die insulating material).
For low-temperature electronic devices, the encapsulation layer is readily formed using many different materials and processes. In the 1970's a ceramic system, known as “CERATAB” packaging, was used. (Ref. 4) In more recent years, the encapsulation materials have been silicone with ceramic fillers (Ref. 5), epoxy resins (Ref. 6) and plastics (Ref. 7). A more exotic approach to encapsulation consists of alternating layers of polyamide and ceramic. (Ref. 8) Organic encapsulation materials do not function at high temperatures. The high temperature ceramic materials suffer from high porosity and brittleness problems even if the material itself satisfies the requirement for electrical insulation and high temperature stability.
A recent patent discusses a fabrication process for a ceramic material which consists of zirconia or hafnia powder suspended (encapsulated) in crystalline cordierite (mixture of MgO, CaO and Y2O3) glass-ceramic materials. (Ref. 9) Although this patent states that it is suitable in packaging LSI circuits, the process as described, is not in fact, suitable for encapsulating integrated circuits because the fabrication temperature is too high (840° C.<T<950° C.) for completed Si devices and circuits to withstand. The use must be for fabricating ceramic substrates (on which encapsulated chips are mounted) because the zirconia and/or hafnia would strengthen the cordierite. In another application, phosphosilicate glass was used to encapsulate InP:Fe. (Ref. 10) The phosphorous in this latter process was found to migrate from the encapsulation layer into InP:Fe.
For packaging SiC, the same problem would exist and would change the electrical properties of the devices. A suitable encapsulation material and/or process for the anticipated operating ranges of SiC devices does not exist. Such a need never existed before the advent of “stable” high temperature SiC electronic devices. Now such a need exists, and no prior encapsulation material and method is known to be suitable.
REFERENCES
1. Q. Y. Tong, U. Gosele, C. Yuan, A. J. Steckl, and M Reiche, J. Electrochem. Soc. 142, 232 (1995).
2. P. K. Bhattacharya, Int. J. Electronics 73, 71 (1992).
3. T. Kamijoh, H. Takano and M. Sakuta, Jour. Appl. Phys., Vol. 55, (1984) 3756-3759.
4. J. Jablonski and W. Bielawski, Electronicka, No. 5, 221 (1972).
5. C. P. Wong and R. McBride, IEEE Transactions on Components, Hybrids and Manufacturing Technology 16 (8), 868 (1992).
6. R. Hunadi and N. Bilow, Proceedings of International SAMPE Symposium and Exhibition: 1st International SAMPE Electronic Conference-Electronic Materials and Processes (Santa Clara, Calif., 1987) pg. 397.
7. C. P. Wong, Materials Chemistry and Physics 42, 25 (1995); J. A. Emerson, Proceedings of InterSociety Conference on Thermal Phenomena in the Fabrication and Operation of Electronic Components (Los Angeles, Calif. 1988) pg. 190.
8. M. Tudanca, R. G. Luna, A. Fraile, J. Triana, J. M. Gonzalez, I. Vincueria, and C. Dominguez, Proceedings of 42nd electronic Components and Technology Conference, 120 (San Diego, Calif., 1992) pg. 120.
9. R. W. Adams Jr., D. R. Clark, L. L. Rapp, and B. Schwartz, Ausz. Eur. Patentanmeld. I 4(5) 426 (1988).
10. T. Kamijoh, H. Takano, and M. Sukuta, J. Appl. Phys. 55(10) 3756(1984).
SUMMARY OF THE INVENTION
One object of the invention is to provide a suitable adhesion material and method for adhering an SiC chip to a ceramic package substrate for high temperature operation.
Another object is to provide an encapsulation material and method suitable for packaging SiC chips and associated contacts and conductors either alone or with circuitry on a ceramic substrate for stable high temperature operation.
The process and system of the present invention, overcomes the problems associated with the prior art devices as previously described herein by providing a semiconductor device having at least one silicon carbide-containing layer which can be deployed in extreme thermal environments, while at the same time maintaining stable I/O electrical contact with the device. Without this technology, lateral SiC devices (which require back-side electrical isolation) cannot be deployed in environments of high temperature, or rapid temperature changes.
This can be accomplished by providing a means of deploying SiC devices and circuits and thin film thermocouples and transducers in harsh thermo-chemical environments. More specifically, a stable, electrically insulating hermetic seal can be formed over the SiC-containing layer with electronic devices and related components (metallizations, wires, etc. on the SiC-containing layer and on any underlying substrate). Therefore, this invention satisfies a long standing need for a non-conductive encapsulant that protects circuit components built on or around SiC-based thin film sensors and circuits. It constitutes a high temperature, non-corrosive environment encapsulant for circuitry based on and around the SiC-containing layer. The thermal and mechanical stability of the resulting hybrid structure does not limit the thermo-chemical or mechanical stresses to which devices including the SiC-containing layer can be subjected.
Furthermore, it is an object of this invention to provide a means of deploying SiC devices in harsh environments, by formation of a stable, insulating bond between SiC electronic devices and underlying ceramic substrates, such as AlN. The substrate is preferably polycrystalline AlN but can be monocrystalline AlN, or a layer of AlN deposited on a SiC substrate.
This encapsulation method can also be used to package devices and circuits on aluminum oxide substrates (Al2O3). For example, platinum resistive thin film devices on aluminum oxide can be encapsulated using the same composition and process. The need for such adhesives and processes arises from the packaging requirements for various SiC devices under development worldwide, as the performance potential of the SiC devices is expected to extend the operating windows in temperature (caused by external temperature as well as by high-current-induced heating) and chemical environments.
The subject invention includes a method for the protective encapsulation of a SiC-containing substrate and/or the adhesion of a SiC-containing substrate and an underlying ceramic package substrate. This method comprises encapsulating a SiC-containing semiconductor substrate having a first and second major surface. It also can comprise encapsulating the SiC substrate on an underlying insulative package substrate (preferably polycrystalline AlN but suitably monocrystalline AlN or a layer of AlN or SiC ceramic or other compatible bulk substrate materials), having a first and second major surface. At least one of the first and second major surface of the SiC-containing semiconductor substrate can be coated with a stable encapsulating layer which protects said semiconductor device from mechanical degradation and from thermal degradation at temperatures above at least about 1000° C., preferably at temperatures above at least about 1200° C. Furthermore, at least one of the first and second major surface of said SiC-containing semiconductor substrate can be bonded with a bonding material to at least one of the first and second major surface of said underlying package substrate. This bonding material is preferably and advantageously the same material as the encapsulating material. The bonded SiC-containing substrate-underlying ceramic substrate assembly or structure can be formed at temperatures of about 700° C., but, once formed, is stable to the above described temperatures, i.e., at temperatures above at least about 1000° C., preferably up to temperatures above 1200° C.
The stable encapsulating layer is preferably formed by rapidly ramping the temperature of the assembly up to about 700° C. Any metallic circuitry located on the silicon carbide-containing layer or the ceramic substrate is protected against the effects of substantial oxidization/reduction thereof by formation of the stable encapsulating layer. Also, the SiC device bonded to the AlN substrate will be protected against the effects of thermal shock temperature changes from ambient down to −200° C., and up to at least about 1100° C. by the stable encapsulating layer. Preferably, the coefficient of thermal expansion of the stable encapsulating layer is near the coefficient of thermal expansion of the carbide-containing semiconductor substrate. The carbide-containing semiconductor substrate preferably comprises contacts of WC and TiC, and/or Os, with conductors formed of any one of W, Au, Pd, Pt/Au.
The stable encapsulating layer is a form of glass which will protect the surfaces and structures of the carbide-containing semiconductor substrate from mechanical degradation and from thermal degradation at temperatures to a range of at least about 1000° C., and preferably about 1200 to 1250° C. Preferably, the glass employed in this invention is a borosilicate glass (“BSG”), and more preferably, the composition of the BSG comprises 30 to 50% by weight % of B2O3 and 70 to 50% by weight of SiO2. In any case, the stable encapsulating layer will in general protect metal contacts and circuits on any one of a silicon carbide, and oxide and nitride insulators, as well as metal circuitry on the ceramic substrate.
In the preferred form of the invention, the stable encapsulating layer is formed by applying an unreacted powdery material to one of the first and second major surface of the silicon carbide-containing semiconductor substrate, and heating the unreacted powdery material to a temperature at which it will form the stable encapsulating layer. Moreover, the stable encapsulating layer can be formed at a temperature of less than about 700° C., but once reacted is stable through the operating range of the SiC device, including temperatures substantially exceeding the formation temperature. The preferred powdery materials are a mixture of precursors for borosilicate glass, preferably B203 powder and SiO2 powder, 325 mesh size. The powder mixture can be applied dry or in a water dispersion or paste (with a brief pre-heat to drive off the liquid).
It is also a desirable feature of the stable encapsulating layer that, when the bond is formed, the encapsulating material be non-invasive with respective to the carbide-containing semiconductor substrate. Desirably, the stable encapsulating layer is preferably formed at a temperature of less than 1000° C., and retains high viscosity to at least about 1200° C., and is immune to thermal shock to at least about 1100° C., and is electrically insulating. The BSG encapsulant meets this constraint.
In the preferred form of the present invention, the SiC-containing semiconductor substrate is an SiC die and the underlying substrate is polycrystalline AlN. The expansion coefficients of AlN and SiC components are nearly identical in this SiC/AlN structure, and that of the BSG encapsulant is close enough to both SiC and AlN so as to avoid separation or cracking over a wide temperature range.
A method is also provided for the adhesion of a SiC-containing substrate to an underlying ceramic substrate, preferably AlN. The bonding or adhesive material generally comprises a similar composition to the stable encapsulating material discussed above, i.e., preferably a borosilicate glass, and more preferably a glass comprising 30 to 50 weight % of B2O3 and 70 to 50 weight % of SiO2. The bonding material is preferably formed, as described above, by applying an unreacted powdery material, preferably in paste form, to one of the first and second major surface of said ceramic substrate, placing that surface against one of the surfaces of the SiC die, and heating the unreacted powdery material to at least its bonding temperature, a preferred temperature of about 700° C. within a range of 460° C. to 1000° C.
The foregoing and other objects, features and advantages of the invention will become more readily apparent from the following detailed description of a preferred embodiment of the invention which proceeds with reference to the accompanying drawings.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a cross-sectional diagram of a semiconductor device having at least one silicon carbide-containing layer bonded to an underlying ceramic substrate made according to the present invention.
FIG. 2 is a cross-sectional diagram of a ceramic substrate having a silicon carbide-containing layer bonded to it and an encapsulating coating layer coated thereon according to the present invention.
FIG. 3 is a perspective view of a thermally sensitive SiC resistor mounted in a flip chip manner on an AlN die and encapsulated according to the present invention.



DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
The need for thermally stable ohmic and rectifying electrical contacts to n-type and p-type SiC and its solution described in commonly-assigned to pending U.S. patent application Ser. No. U.S. Ser. No. 08/612,216 Filed Mar. 7, 1996 (counterpart PCT application PCT/US97/03497, filed Mar. 4, 1997), now U.S. Pat. No. 5,929,523, incorporated by reference herein. Osmium (Os) contacts exhibit the following properties:

    
    
        1. Metal/SiC junction stable to over 1000° C.,
        2. Protects its junction with SiC from circuit and bonding metal diffusion (forms an electrically transparent diffusion barrier) to >1000° C., and either
        3. Forms an ohmic electrical contact to p-type SiC, or
        4. Forms a rectifying (Schottky) contact to n-type SiC.
    
    


Osmium (Os) forms a rectifying (Schottky) metal junction on n-type SiC semiconductor surfaces, which remains abrupt and firmly attached to at least 1050° C. On P-type SiC, the Os layer forms an ohmic contact with the lowest specific contact resistance of now possible with ohmic contacts to p-type SiC. Stable, low resistance, p-type ohmic contacts are the key to development of all SiC bipolar high temperature power electronics.
Similarly tungsten/tungsten carbide (W/WC) forms an electrically transparent diffusion barrier (ETDB) for TiC electrical contacts to SiC; (both p- type and n-type) where, the ETDB exhibits the following properties:

    
    
        1. ETDB/TiC junction is stable to over 1000° C.,
        2. Protects its junction with TiC from circuit and bonding metal diffusion to over 1000° C.; thereby, also protecting the TiC/SiC junction.
    
    


The electrically transparent diffusion barrier (ETDB) shields TiC/SiC junctions from electrode metals to 1150° C., and forms a metallurgical junction with TiC that remains firmly attached and is stable to 1150° C.
These contacts enable fabrication of SiC devices and circuits that will not degrade, or become unstable, under all strain conditions (thermal, electric field, mechanical) for which SiC itself can perform as a semiconductor device. They remove all restrictions imposed by metal contacts on the thermal operating envelope of SiC solid state device technology. In particular, they provide rectifying (Schottky) junctions and ohmic contacts that will withstand sustained exposure to temperature as high as 1150° C., and electron migration effects at high electric fields.
Based on the foregoing developments, a family of high temperature/power semiconductor devices can be produced which satisfy a number of unmet commercial needs. One immediate application is thermal sensors. The SiC devices contacts can be used to make junction or resistive thermistors, that measure temperatures to 1922° F. (>1050° C.), and 2100° F. (1150° C.). This development permits SiC thermistors to compete, for the first time, with thermocouples, oxide resistors and pyrometers in the temperature range of 300° F. to 2100° F. (150° C. to 1150° C.). It also enables the manufacture of hostile environment transducers, operable at temperatures above 460° F. (238° C.).
Other SiC devices that can now be made include Schottky diodes, PN diodes and transistors as either discrete devices or as components of integrated circuits. Importantly, this technology opens up many potential applications in the power conditioning and conversion field, such as power rectifiers for converting AC power to clean DC power. N—SiC Schottky rectifiers could handle powers nearly as high as the best Si PN junction rectifiers, and PN junction SiC rectifiers could replace vacuum tubes. Other types of devices include bipolar transistors, thyristors, MOSFETs, MESFETs, IGBTs, and mixer diodes for use in communications, as well as digital and analog to digital electronics.
All solid state semiconductor devices require one, or more, of the four electrical contacts discussed above. The invention of PCT/US97/03497 (now U.S. Pat. No. 5,929,523) makes all four of these electrical contacts possible, and facilitates connection to the devices to metal conductors including tungsten, platinum, palladium, gold, and platinum/gold and palladium/gold, especially tungsten which readily oxidizes at high temperature.
Protective encapsulation and adhesion of a SiC-containing substrate containing such devices, contacts and conductors, and an underlying substrate also containing metal conductors, can be provided employing the method of the present invention. Typically, this method comprises providing a carbide-containing semiconductor substrate having a first and second major surface and an underlying substrate having a first and second major surface. A bonding material is also preferably employed to bond at least one of the first and second major surface of the SiC-containing substrate to at least one of the first and second major surface of the underlying substrate. The bonded SiC-containing substrate-underlying substrate structure is formed without substantial mechanical or thermal degradation. Then, at least one of the first and second major surface of the SiC-containing semiconductor substrate is coated with a stable encapsulating layer which protects the semiconductor device from mechanical degradation and from thermal degradation. Preferably, both the encapsulating and bonding functions are performed using a single encapsulating-bonding material. For example, it has been discovered that a single glass compound, borosilitate glass (BSG), can be employed which provides the dual functionality by serving both as the encapsulating and bonding material.
The adhesive and encapsulation mixture is preferably initially composed of finely ground and mixed powders of the unreacted constituent oxides capable of forming the glass material. It can be applied to the area requiring adhesion of encapsulation as a dry powder, or as a slurry. In slurry form, all vaporizable slurry constituents (e.g. water) should be baked off before performing the forming process. The process is thermally activated by melting the B2O3 at T=460° C. The rate at which the glass forms is dependent on the ratio of B2O3 to SiO2 in the unreacted mixture, how well the powders are mixed, and the formation temperature employed. Rate is increased by more B2O3, finer and better mixed powder, and higher temperatures.
The reaction from a powder or slurry to a solid glass is irreversible. Once formed, at temperatures of 460° C. up to 1000° C. (preferably 700° C.) the glass will not revert back to its original powdery or slurry state, nor will it melt even at temperatures well over 1000° C., e.g. 1200° C.
The reacting glass layer typically interacts adhesively with the surfaces it contacts. For instance, the above-described glass material can bond with nitride surfaces in accordance with a parabolic rate limiting reaction. The reaction region thickness is quite thin, and is composed of oxides, and in some instances nitrides. It remains stable and electrically insulating once formed. The encapsulant or adhesion layer can also bond with SiC surfaces by forming an oxide (parabolic rate limited). Bonds can also be formed with SiC through an intermediate Si layer on the SiC surface. This intermediate layer is formed by oxidizing the Si layer and possibly some of the SiC surface, fusing with oxides with which it is in contact, and thereby forming a non-reactive, protective coating over metals and metal carbides.
EXAMPLE 1
As depicted in FIG. 1, a bonding material 10, comprising borosilicate glass (composition=30 to 50 weight % B2O3+70 to 50 weight % SiO2), was produced and was employed as a high temperature, shock immune adhesive to bond an SiC wafer 20 to AlN die 30. The resulting structure is a SiC semiconductor on ceramic substrate 50.
The bonding material 10 was initially composed of finely ground and mixed powders of: (a) unreacted constituent oxides, or (b) reacted mixture. The adhesive was applied to one of the bonding surfaces (preferably the bottom side of the SiC wafer) as a dry powder, but can also be applied in the form of a slurry. In slurry form, all vaporizable slurry constituents (e.g. water) should be baked off before performing the bonding process.
The surfaces to be bonded (at least one of them coated with the dried adhesive) were placed together, and shift pressure was applied. The process is thermally activated by transferring the assembly from ambient air to an oven preheated to a range of 700° C. to 800° C. This step ramped the temperature of the assembly up quickly (a few seconds at most), from ambient to over 700° C. Reaction can be activated at temperatures as low as 600° C. for unreacted constituent powders, to temperatures above 1000° C. for already reacted powders. Using a fast temperature ramp allows this reaction to be done in ambient air. The BSG reacts and protects metals before they can oxidize. Longer thermal reaction processes can be used if done in an oxygen free atmosphere.
Adhesive-AlN bonding occurs by chemical reaction. The reaction region thickness is quite thin, and is composed of oxides and perhaps nitrides. It remains stable and electrically insulating once formed.
Adhesive-SiC bonding can be accomplished by one of three methods:
1. The adhesive is in contact with SiC surface so that the “bond” is formed by oxidizing the SiC surface.
2. The adhesive is in contact with a thin Si layer on the SiC surface so that the bond is formed by oxidizing the Si layer and possibly some of the SiC surface.
3. The adhesive is in contact with a native grown oxide on the SiC surface so that the bond is formed by fusion between the adhesive and the native SiC oxide.
The completed preferred die bond structure 50 is shown in FIG. 1, and in encapsulated form in FIG. 2. Unique features of this structure 50 include that: (a) it responds to mechanical and thermal stress as though it was a single piece, and (b) it is stable up to temperatures of at least about 1100° C.
The structure 50 exhibited a high degree of thermal shock resistance. More specifically, the thermal shock resistance of structure 50 is thought to occur because: (a) the expansion coefficients of AlN die 30 and SiC 20 wafer are nearly identical, (b) the expansion coefficient of the bonding material 10 is not much different from that of the AlN die or SiC wafer, and (c) heat can be introduced into, or extracted from, the bonding material 10 at an extremely rapid rate because of the high thermal conductivities of SiC wafer 20 and AlN die 30.
EXAMPLE 2
The protective attributes of the stable encapsulating layer of this invention were experimentally determined, as follows:
Referring now to FIG. 2, a portion of a tungsten (W) wire 70, which oxidizes easily, was connected to a metal bond pad 52 on an ohmic contact on the SiC chip and to the metal bond pad 72 on the AlN substrate. The assembly 50 as well as the wire 70 and pads 52, 54, 72 were then encapsulated within an encapsulating layer 80, on the AlN die 30, following the temperature ramping procedure described in Example 1. Then the encapsulated assembly was heated to 1200° C. in air for 30 minutes. As a control, a portion of the tungsten wire 70 was not encapsulated by encapsulating layer 80. In general, elemental tungsten forms two types of oxides WO2 (purple) and WO3 (yellow). The result of this experiment was as follows: (1) the exposed portion of the tungsten wire 20 was oxidized and formed a yellow, non-conductive powder (WO3), (2) the encapsulated portion of the tungsten wire 20 remained grayish-silver (elemental, apparently unoxidized W) and its conductivity remained unchanged, no apparent reaction occurred between the tungsten wire 70 and either the encapsulating layer 80 on atmospheric oxygen.
Next, the AlN/encapsulant/SiC structure 60 after formation thereof was inserted into liquid nitrogen, left in the liquid nitrogen for about 10 minutes, and then removed therefrom. No changes were observed in the mechanical properties of the structure 60. Finally, the above AlN/encapsulant/SiC structure 60 was placed in an 850° C. furnace for 30 minutes, the temperature was increased to 1150° C. for 30 minutes, the temperature was lowered to 850° C. for 30 minutes, and then structure 60 was removed from the furnace. No change in the mechanical properties of the structure were observed.
FIG. 3 is a perspective view of an assembly similar to that of FIG. 2, showing the SiC die 20 mounted in a “flip chip” configuration, connected directly to bonding pads 72, 74 on the AlN die 30 and covered by BSG encapsulant 80. Thus, the SiC wafer 20 can be adhered to a ceramic substrate such as AlN die 30, using BSG as an adhesive, or using BSG as an encapsulant, or both.
Having described and illustrated the principles of the invention in a preferred embodiment thereof, it should be apparent that the invention can be modified in arrangement and detail without departing from such principles. We claim all modifications and variation coming within the spirit and scope of the following claims.

## Claims

1. A SiC semiconductor device comprising:
a semiconductor substrate comprising silicon carbide having a first surface and a second surface, the substrate including a first doped region adjacent the first surface;
a first conductive layer comprising metallic osmium (Os) contacting the first surface to form a first contact having an electronic interface to the first doped region; and
an encapsulating insulative coating layer formed onto at least one of the first and second major surfaces of said silicon carbide-containing semiconductor substrate which protects said semiconductor device from mechanical degradation and from thermal degradation at temperatures above at least about 1000° C.

2. A SiC semiconductor device according to claim 1 in which the first doped region is doped n-type and the first contact forms a Schottky junction.

3. A SiC semiconductor device according to claim 1 in which the First doped region and a second doped region and intervening portions of the substrate are doped n-type, the first contact forms a Schottky junction and the second contact forms an ohmic junction, so that the device acts as a Schottky diode.

4. A SiC semiconductor device according to claim 1 in which the first and second regions are doped to a first dopant type and an intervening portion of the substrate is doped to an opposite dopant type to form a first pn junction at an interface adjoining the first region and a second pn junction at an interface adjoining the second region.

5. A SiC semiconductor device according to claim 1 in which the first region is doped to a first dopant type and the second region is doped to a second, opposite dopant type, and an intervening portion of the substrate is doped to form a first pn junction at an interface adjoining the first region, a second pn junction at an interface adjoining the second region and a third pn junction within the intervening portion.

6. A SiC semiconductor device according to claim 1 including a layer of a protective metal covering the Os first conductive layer, selected from a group of conductive metals that is protective of the Os layer against oxidation and adapted to bond to an osmium surface.

7. A SiC semiconductor device according to claim 1 including a layer of a protective metal selected from a group consisting of Pt, Pd, W, Au, PtAu, Ti, Zr, Hf, V, Cr. Fe, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Ag, Ta, Re, Ir.

8. A SiC semiconductor device according to claim 1 including a second doped region adjacent one of the first and second surfaces and a second conductive layer which comprises metallic osmium (Os) forming a second contact having an electronic interface to the second doped region.

9. A SiC semiconductor device according to claim 8 in which the first and second regions and intervening portions of the substrate are doped p-type so that the first contact and the second contact each form an ohmic junction and the device acts as a resistive device.

10. A SiC semiconductor device according to claim 8 in which the first and second regions and an intervening portion of the substrate are doped p-type so that the first contact and the second contact each form an ohmic junction and a gate structure overlies the intervening portion of the substrate so that the device acts as field effect transistor.

11. A SiC semiconductor device according to claim 8 in which the first and second regions of the substrate are doped p-type so that the first contact and the second contact each form an ohmic junction, and an intervening portion of the substrate is doped n-type to form a pn junction with at least one of said first and second regions.

12. A SiC semiconductor device according to claim 8 in which the first and second regions are doped p-type and the intervening portion is doped n-type and a contact coupled to the intervening portion comprises a material which forms an ohmic contact therewith so that the device is operable as a bipolar transistor.

13. A device according to claim 1 including a ceramic substrate having first and second major surfaces, and
an adhesive layer adhering one of the major surfaces of the silicon carbide substrate to one of the major surfaces of the ceramic substrate,
the adhesive layer being stable to over 1000° C.

14. A device according to claim 13 in which the coating layer is borosilicate glass.

15. A device according to claims 14 in which the adhesive layer is borosilicate glass and the ceramic substrate includes a layer of AIN, SiC/AIN or Al2O3.

16. A SiC semiconductor device comprising:
a semiconductor substrate comprising silicon carbide having a first surface and a second surface, the substrate including a first doped region adjacent the first surface;
a first conductive layer comprising a first contact metal layer on the first surface to form a first contact having an electronic interface to the first doped region, the first conductive layer including:
a titanium carbide (TiC) layer contacting the second surface;
a tungsten carbide (WC) layer covering the titanium carbide (TiC) layer; and
a layer consisting essentially of elemental tungsten contacting the tungsten carbide (WC) layer; and
an encapsulating insulative coating layer formed onto at least one of the first and second major surface of said silicon carbide-containing semiconductor substrate which protects said semiconductor device from mechanical degradation and from thermal degradation at temperatures above at least about 1000° C.

17. A SiC semiconductor device according to claim 16 in which the first region is doped n-type, and the first contact forms an ohmic junction.

18. SiC semiconductor device according to claim 16 including a layer of a bonding metal contacting the tungsten layer, selected from a group of conductive metals that is adapted to bond to a tungsten surface.

19. A SiC semiconductor device according to claim 16 including a layer of a bonding metal contacting the tungsten layer, the bonding metal being selected from a group consisting of Pt, Pd, W, Au, PtAu, V, Ti, Zr, Hf, Cr, Fe, Ni, Cu, Nb, Mo, Te, Ru, Rh, Ag, Ta, Re, Jr.

20. SiC semiconductor device according to claim 16 in which the first region is doped p-type, and the first contact forms a rectifying junction.

21. A SiC semiconductor device according to claim 16 including a second doped region adjacent one of the first and second surfaces and a second conductive layer which comprises:
a titanium carbide (TiC) layer on the one surface;
a tungsten carbide (WC) layer on the titanium carbide (TiC) layer; and
a metallic tungsten (W) layer on the tungsten carbide (WC) layer.

22. A SiC semiconductor device according to claim 21 in which the first and second regions and intervening portions of the substrate are doped n-type so that the first contact and the second contact each form an ohmic junction and the device acts as a resistive device.

23. A SiC semiconductor device according to claim 21 in which the first and second regions are doped n-type and a contact is coupled to an intervening portion of the substrate, the contact including a gate structure overlying the intervening portion so that the device is operable as a field effect transistor.

24. A SiC semiconductor device according to claim 21 in which the first and second regions are doped n-type and a contact is coupled to an intervening portion of the substrate, the contact including a conductive layer contacting a surface of the intervening portion so that the device is operable as a transistor.

25. A SiC semiconductor device according to claim 24 in which the intervening portion of the substrate is doped p-type so that the device is operable as a bipolar transistor.

26. A SiC semiconductor device according to claim 24 in which the intervening portion of the substrate is doped n-type so that the device is operable as a MESFET.

27. A SiC semiconductor device according to claim 24 including a gate contact structure comprising a third conductive layer overlying an insulative layer to form an insulated gate over the intervening portion so that the device acts as a field effect transistor.

28. A device according to claim 16 including a ceramic substrate having first and second major surfaces, and
an adhesive layer adhering one of the major surfaces of the silicon carbide substrate to one of the major surfaces of the ceramic substrate,
the adhesive layer being stable to over 1000° C.

29. A device according to claim 28 in which the coating layer is borosilicate glass.

30. A device according to claims 29 in which the adhesive layer is borosilicate glass and the ceramic substrate includes a layer of AIN, SiC/AIN or Al2O3.

31. A packaged SiC device which comprises:
a SiC die having a silicon carbide-containing layer;
a contact forming an electrical connection to an electronic device formed by at least one doped region in the SiC die, the contact comprising an electrically transparent diffusion barrier (ETDB) on the silicon carbide containing layer;
a package substrate comprising a layer of SiC/AIN;
a metal conductor on the package substrate connected to the contact; and
a borosilicate glass layer adhering and interfacing the SiC die to the package substrate.

32. A packaged device according to claim 31 which further comprises a borosilicate glass layer which encapsulates the SiC die and the metal conductor on the package substrate.

33. A device according to claim 32 in which the SiC die is mounted on the package substrate in a flip chip configuration, in which the contact on the silicon carbide-containing layer is connected directly to a bonding pad on the package substrate.

34. A device according to claim 33 in which the electronic device comprises one of a resistive device, a diode, a field effect transistor or a bipolar transistor.

35. A device according to claim 31 in which the electronic device comprises one of a resistive device, a diode, a field effect transistor or a bipolar transistor.