# Patent

## Title
Refractory ceramic material having a high solidus temperature, its manufacturing process and structural part incorporating said material

## Abstract

A refractory ceramic material possessing a solidus temperature between 2500° C. and 2800° C., having a compactness greater than 85%, and a microstructure such that the material is composite of: (a) hafnium dioxide HfO2 grains having a monoclinic structure (1); (b) hafnium dioxide HfO2 grains having a cubic structure (2) which is stabilized by yttrium oxide Y2O3, the yttrium oxide Y2O3 representing 0.5 mol % to 8 mol % relative to the total number of moles of hafnium dioxide HfO2; (c) closed pores (3); (d) non-interconnected open pores. The process of manufacturing the material and a structural part incorporating the material are also set forth.

## Background
TECHNICAL FIELD
The present invention relates to the field of oxide-based refractory materials, and relates in particular to a refractory material having a high solidus temperature, a process for manufacturing the same, and a structural part incorporating said material.
BACKGROUND ART
In a nuclear power plant, when a failure occurs in the means intended for the removal of residual power from the nuclear reactor, a loss in the cooling of nuclear fuel may be induced. In some circumstances, this loss may lead to partial or total core meltdown. The probability of such an accident, although extremely small, is not zero.
In order to prevent and manage the consequences of such an accident both on the population and the environment, a severe accident in a nuclear reactor core (in particular a Pressurized Water Reactor (PWR)) is simulated by melting sections of nuclear fuel rods that have previously been irradiated, in an induction furnace made of oxide-based refractory materials.
During such experiments, in which the temperature is varied (reaching up to 2600° C.) and the atmosphere is changed (for example, to neutral or oxidizing), the nuclear fuel behavior is studied, and fission products and actinides which are released are identified and analyzed.
The oxide-based refractory parts of the furnace must at least fulfill the following criteria:
mechanical strength up to a temperature of 2600° C.,
tightness to gases generated during the experiment,
chemical resistance to various types of atmosphere (in particular reducing, oxidizing, neutral, comprising air, water vapor),
chemical resistance to corrosion and/or high temperature ablation, which may be caused by baths consisting of oxides and metals, for a duration of at least 15 minutes. Such interactions are generated, for example, when the refractory material is brought into contact with the corium. The latter is magma which results from the high-temperature meltdown of the nuclear fuel, followed by a reaction of the molten fuel with its cladding and the structural elements of the nuclear reactor. Most often, it is composed of corrosive baths of oxides and metals, heated-up above their melting point or solidus temperature. These oxides are, in particular, uranium, zirconium and iron oxides.
In order to fulfill such criteria, until 2003, the refractory parts of these furnaces were manufactured from thorium dioxide ThO2, which oxide has a melting temperature of 3380° C.
However, since thorium dioxide ThO2 is radioactive, it is difficult to implement and attempts are being made to replace it by another non-radioactive refractory material which also fulfills the above criteria. One candidate material is hafnium dioxide HfO2.
Hafnium dioxide HfO2 has three crystalline structures, each of which has its own stability domain as a function of temperature and pressure. At atmospheric pressure, these domains are as follows:
below 1700° C.: monoclinic structure,
from 1700° C. to 2600° C.: quadratic structure,
from 2600° C. to 2810° C.: cubic structure,
above 2810° C.: liquid state.
Hafnium dioxide HfO2 has a melting point of 2810° C. and is also well known to withstand chemical interactions under heat. It therefore appears to be a good candidate for the replacement of thorium dioxide ThO2 as a refractory material used in the composition of furnace parts enabling the above-mentioned simulations to be carried out.
However, pure hafnium dioxide HfO2 has a major drawback in high temperature applications, in that, during thermal cycling (increasing/decreasing temperature), its allotropic transformation from the monoclinic phase to the quadratic phase is accompanied by a 3.4% shrinkage (or a volume expansion during the opposite transformation) between 1500° C. and 1800° C. As an unacceptable consequence of this large volume change, cracking of the refractory ceramic material consisting of hafnium dioxide HfO2 occurs.
From U.S. Pat. No. 5,681,784, it is known that this volume change may be prevented by stabilizing the hafnium dioxide HfO2 in its cubic phase (high temperature phase) by means of additives. For that purpose, to the hafnium dioxide HfO2 material, 8 mol % to 12 mol % yttrium oxide Y2O3 and 0.25% to 4% by weight of sintering aids, are added. The material thus obtained has a low solidus temperature (well below 2500° C.), which makes it inappropriate for use as a constituent refractory material in the above-mentioned simulation furnaces.
SUMMARY OF THE INVENTION
It is accordingly an object of this invention to provide a hafnium dioxide HfO2 based refractory ceramic material which does not crack during increasing and decreasing temperature cycling, which includes the range from 1500° C. to 1800° C.
A further object of this invention is to provide a hafnium dioxide HfO2 based refractory ceramic material having a solidus temperature greater than 2500° C.
An additional object of this invention is to provide a powder metallurgy process for the manufacture of such a refractory ceramic material and a structural part incorporating this material.
Therefore, an object of this invention is to provide a refractory ceramic material possessing a solidus temperature in the range between 2500° C. and 2800° C., having a compactness greater than 85%, and a microstructure such that the material is composite and comprises:
hafnium dioxide HfO2 grains having a monoclinic structure;
hafnium dioxide HfO2 grains having a cubic structure which is stabilized by yttrium oxide Y2O3, the yttrium oxide Y2O3 representing 0.5 mol % to 8 mol % relative to the total number of moles of hafnium dioxide HfO2;
closed pores;
non-interconnected open pores.
Advantageously, the solidus temperature of the refractory ceramic material obtained according to the process of this invention ranges between 2500° C. and 2800° C. The solidus temperature is that temperature below which the last liquid portions of the solidifying material have solidified. It is determined at atmospheric pressure.
Furthermore, by “closed pores” are meant pores which do not communicate with the surface of the material, and by “open pores”, pores which communicate with the surface of the material, these open pores having moreover the particular characteristic of not being interconnected.
One of the fundamental characteristics of the refractory ceramic material according to this invention is the particular quantity of yttrium oxide Y2O3 it contains, namely a quantity of 0.5 mol % to 8 mol % relative to the total number of moles of hafnium dioxide HfO2 (both monoclinic and cubic). This quantity results in the material being a composite, that is, comprising hafnium dioxide HfO2 in two distinct crystalline phases which are homogeneously distributed within the entire volume of the material, namely a phase comprising grains having a cubic structure (stabilized by yttrium oxide Y2O3) and a phase comprising grains having a monoclinic structure.
Due to this composite nature, the material is only partially stabilized by the formation of a solid solution having a cubic structure.
This has the advantage of both i) avoiding the above-mentioned volume expansion and ii) preserving a solidus temperature as high as possible, and as close as possible to the melting temperature of pure hafnium dioxide HfO2, while avoiding the addition of sintering aids during the manufacture of the material, which may lower its useful working temperature.
In addition, the refractory ceramic material according to this invention has a compactness of more than 85%, and is thus a sufficiently dense material to have an appropriate mechanical strength, in particular up to 2600° C., and to confine as well as possible the gases generated, for example, during the above-mentioned simulation experiments.
Since compactness is the counterpart of porosity, the porosity of the refractory ceramic material of this invention is 15% or less. The measurement unit of compactness or porosity is in volume percent. Porosity can be accounted for by both open pores and closed pores.
Advantageously, a large proportion of the pores of the refractory ceramic material of this invention are closed.
Thus, preferably, the closed pores represent 1% to 15% of the volume of this material. As for the open pores of the material, these represent less than 3%, preferably less than 1%, and still more preferably about 0.5%, of the volume of the material. These open pores are not interconnected, so that, for such pores, they do not extend throughout the refractory ceramic material. Optionally, part or all of the closed pores in the refractory ceramic material is not interconnected.
The closed nature of a large proportion of pores, as well as the fact that the open pores are not interconnected, enhances the gas tightness of the refractory ceramic material according to this invention and increases chemical resistance to gases and liquids by reducing the available exchange surface.
A further object of this invention is to provide a powder metallurgy process for the manufacture of the refractory ceramic material according to this invention, comprising the consecutive steps of:
(i) obtaining a dry mixture of a hafnium dioxide HfO2 powder and an yttrium oxide Y2O3 powder, each of these oxides being mixed in the molar proportions in which it is found in the ceramic material,
(ii) step of granulation by pelletization of the dry mixture under stirring in order to obtain a granulated mixture, this granulation step comprising the spraying, into the dry mixture, of an aqueous solution comprising, relative to the weight of the dry mixture, 5% by weight of polyvinyl alcohol (PVA) having a molecular weight in the range between 50000 and 90000 g/mol and 5% by weight of polyethylene glycol (PEG) having a molecular weight in the range between 180 and 420 g/mol,
(iii) drying of the granulated mixture and then filling of a mold with said granulated mixture,
(iv) uniaxial pressing of the granulated mixture in order to obtain a compact mixture, this pressing comprising the application of a plateau shaping stress of 20 MPa to 50 MPa, preferably 30 MPa, and
(v) sintering of the compact mixture in order to obtain the refractory ceramic material.
The PVA and PEG comprised in the aqueous solution act as a binder and a plasticizer, respectively. They are removed by pyrolysis during the temperature rise to the sintering temperature.
Generally, the homogeneous distribution of a small amount of one powder within another is a delicate problem. This problem is even more complicated because the dry mixture of the present invention comprises two powders with rather different densities (namely, density of pure HfO2=9.68 g·cm−3; density of pure Y2O3=5 g·cm−3).
However, it is very important to obtain a dry mixture wherein both of these powders are homogeneously distributed, since an increase in the Y2O3 content in any area of the material may generate stresses rendering this material inappropriate for sintering and, after sintering, may produce a heterogeneous material and cause a large decrease in the solidus temperature within this area, and therefore, embrittlement of the entire ceramic material, imposing its use at temperatures lower than those expected.
The inventors have found that a step of granulation by pelletization alone, combined with the specific aqueous solution according to this invention, allows a granulated mixture to be produced wherein, on the one hand, the HfO2 and Y2O3 powders are distributed homogeneously, and on the other hand, the dense granules have both sufficient mechanical strength to be manipulated and a deformation ratio enabling flattening to be carried out during the pressing step. According to this invention, by “granulation by pelletization” is meant a process wherein an organic suspension is sprayed onto a spinning ceramic powder within a slanted rotating table.
After drying, the obtained granulated mixture is sintered in order to obtain a refractory ceramic material according to this invention, which is both a composite (that is, the hafnium dioxide HfO2 grains are of two types, namely grains of a monoclinic structure and of a cubic structure stabilized by yttrium oxide Y2O3), and homogeneous (these grains being distributed homogeneously throughout the entire volume of the material).
This material undergoes no cracking and a large proportion of its porosity is of the closed type. Without being bound to any particular theory, this unexpected closed porosity may be attributed to the Kirkendall effect, which is specific to the HfO2—Y2O3 combination. This is even more surprising because, in spite of the significant amount of plasticizer contained in the aqueous solution (namely 5% by weight of polyethylene glycol), the ceramic material obtained by the process according to this invention is nonetheless sufficiently dense, with a measured compactness greater than 85%.
Further objects, features and advantages of the invention will become more apparent from the following description, which is non-limitative and given for the purpose of illustration.



BRIEF DESCRIPTION OF THE DRAWINGS
This invention also includes two appended Figures, which are explained in the following examples.
FIGS. 1A, 1B, 1C and 1D illustrate micrographs of the refractory ceramic materials of this invention obtained using a Scanning Electron Microscope (SEM) in the back-scattered electron mode.
FIG. 2 illustrates an Energy Dispersive Spectrometer mapping of a refractory ceramic material according to this invention, as well as a SEM reference micrograph in the backscattered electron mode.
FIG. 3 shows a Table listing different characteristics (in particular with regard to the microstructure) of refractory ceramic materials according to this invention.
FIG. 4A shows a secondary electron SEM micrograph of a refractory ceramic material according to this invention (with a magnification factor of 55). FIG. 4B is an enlargement of the upper left portion of FIG. 4A.
FIGS. 5A and 5B illustrate secondary electron SEM micrographs for refractory ceramic materials according to this invention, which have been subjected to a treatment permitting some of their microstructural characteristics to be revealed.



DETAILED DESCRIPTION OF THE INVENTION
1—Powder Metallurgy Process for the Manufacture of Refractory Ceramic Materials Comprising 1 mol % Y2O3.
1.1—Dry Mixing of the HfO2 and Y2O3 Powders
In order to make an HfO2 refractory ceramic material comprising 1 mol % Y2O3, 99.93 g of an HfO2 powder and 1.07 g of a Y2O3 powder, representing 99 mol % and 1 mol % of the final mixture, respectively, were mixed together.
The hafnium dioxide HfO2 powder available from CEZUS (France), had the following characteristics:
Purity=99.9% by weight.
Specific surface (BET)=12.99 m2/g.
Dense particle size (BET)=47.6 nm, calculated from the specific surface assuming the grains to be spherical.
Average grain size=2 μm, as measured by a wet process with a laser granulometer after adding ammonium polymethacrylate as a dispersant (marketed under the brand name DARWAN C).
Crystal system: mostly monoclinic (density=9.7 g·cm−3).
The specific surface (BET) and the dense particle size (BET) were determined by nitrogen adsorption according to the ISO 9277:1995 standard established according to the Brunauer-Emmett-Teller (so-called BET) method.
The main chemical elements forming impurities (in ppm by weight relative to hafnium dioxide HfO2) were as follows:















Al < 100



Ca < 25



Cd < 20



Mo < 20



Na < 20



Ni < 100



Co < 20



Cr < 20



Cu < 100



P < 20



Pb < 20



Sn < 20



Fe < 100



Mg < 20



Mn < 0



Ti < 100



V < 20










The yttrium oxide Y2O3 powder, available from PIDC (USA), had the following characteristics:
Purity=99.999% by weight.
Density=5.01 g·cm−3 
Specific surface (BET)=2.38 m2/g.
Dense particle size (BET)=0.5 μm, as calculated based on the specific surface and assuming the grains to be spherical.
Average grain size=3 μm, as measured by a wet process with a laser granulometer after adding DARWAN C as a dispersant.
The powders were mixed in the dry state by means of a non-specific ceramic powder mixer (here, of type Turbula®) for a minimum time period of 20 minutes.
1.2—Step of Granulation by Pelletization
To perform the step of granulation by pelletization of the dry mixture of powders, stirring was maintained within a slanted rotating table while gradually spraying into the dry mixture of powders an aqueous solution comprising polyvinyl alcohol (PVA) having a molecular weight in the range between 50000 and 90000 g/mol and polyethylene glycol 300 (PEG 300), the sprayed quantities of PVA and PEG each representing 5% by weight based on the weight of the dry mixture of powders.
According to this invention, PEG 300 is a polyethylene glycol having a molecular weight in the range between 285 and 315 g/mol.
1.3—Drying
The obtained granulated mixture was dried in an oven at 50° C. until the granules were dry which, in the present case, corresponds to a period of 20 minutes. A drying temperature in the range between 40° C. and 60° C. may also be appropriate. This avoids excessive hardening of the binder (PVA), which would make the granules incompressible during the pressing step.
1.4—Screening
The granulated and dried mixture obtained by a “dry process” in the previous steps was then introduced into an automatic screening machine to be subjected to a double screening operation so that it contains only granules with a size in the range between 60 and 250 μm. This granule size is sufficiently large for its flow properties to permit correct filling of the mold. Also, it is small enough for the granules not to induce flaw during the pressing operation, such as a local lack of the mixture which may lead to the appearance of a macropore, which would be impossible to remove during sintering.
1.5—Pressing
To produce a compact mixture, the mixture of granulated powders was introduced into a pellet-shaped mold. The pressing die was 25 mm in diameter. The mold was made of steel. Care was taken to fill the mold slowly so that filling was as complete as possible, thus avoiding the occurrence of defects which would be impossible to remove during sintering. The mixture of granulated powders was then subjected to the following pressing cycle during which the compacting pressure underwent the following changes:
a pressure increase at a rate of 0.1 MPa/s up to a shaping stress plateau (or pressure plateau) of 30 MPa, which was maintained for 2 minutes, followed by
a decrease in the 30 MPa shaping stress plateau at a rate of 0.1 MPa/s down to atmospheric pressure.
Alternatively, the pressure increase may be carried out according to at least one rate in the range between 0.1 and 1 MPa/s, the shaping stress plateau may be at least 20 MPa and in any case should not reach values much in excess of 50 MPa (for example, as high as 100 MPa) so as to prevent any cracking of the material after sintering, the shaping stress plateau may be maintained for a duration in the range from 60 s to 180 s, and may be decreased at a rate in the range between 0.1 and 1 MPa/s down to atmospheric pressure.
After this pressing step, a compact pellet 13 mm in diameter and 2 mm in thickness was obtained.
Preferably, the structural parts according to this invention have a geometry such that they have a material thickness of 10 mm or less in at least one considered cross-sectional plane so as to facilitate removal of the binder and/or plasticizer during the sintering step.
1.6—Sintering.
The compact pellet was sintered in air according to the following cycle: an increase in temperature at a rate of 5° C./min up to a temperature of 1600° C., which was maintained at this value for 1 hour, followed by a decrease in temperature at the natural cooling rate of the furnace.
Various sintering cycles under an air atmosphere were tested to assess the influence of the temperature and the time plateau on compactness and open porosity. Thanks to these tests it was possible to determine that another sintering cycle, which may also be appropriate, comprises the heating of the compact mixture to a temperature in the range between 1550° C. and 1650° C., for a duration in the range between 30 minutes and 90 minutes. If such conditions are not fulfilled, an open porosity ratio which is unsuitable for the containment of gases might be obtained.
Moreover, through other tests it was shown that for the same sintering cycle, the larger the yttrium oxide Y2O3 content, the smaller the sintering shrinkage and the higher the temperature at which the compact pellet begins to densify (900° C. for a pure HfO2 pellet as opposed to 1200° C. for a HfO2 pellet comprising 8 mol % Y2O3).
Advantageously, the solidus temperature of the refractory ceramic material of this invention must be in the range between 2500° C. and 2800° C. To obtain this material with sufficient compactness, it is therefore expected that a high sintering temperature should be applied, which will in any case be much larger than the upper bound that can be reached by standard sintering furnaces which, in general, never exceed 1700° C. to 1800° C.
Even though other furnaces may generate temperatures in excess of 1800° C., they generally work under a neutral or reducing atmosphere and have rarely been developed in this industry. These furnaces most often use heating elements and refractory materials made of carbon. However, carbon interacts with hafnium dioxide HfO2, thus making the use of such furnaces inappropriate for sintering a mixture of powders comprising HfO2.
Unexpectedly, although the sintering step according to this invention comprises the heating at temperatures in the vicinity of 1600° C., it nevertheless makes it possible to obtain a sufficiently compact ceramic material with a large closed porosity ratio. This also allows standard furnaces to be employed.
1.7—Machining-Grinding.
In order to make a structural part for a simulation furnace, the refractory ceramic material pellet obtained in the previous step was machined into a spur shape.
Machining did not generate any cracking in the material.
2—Powder Metallurgy Process for the Manufacture of the Refractory Ceramic Powders Comprising 3 mol %, 5 mol % and 8 mol % Y2O3.
HfO2-based refractory ceramic materials comprising 0.5%, 3%, 5% and 8% Y2O3, respectively, were manufactured according to the same process as in Example 1, except that the Y2O3 powder quantities involved in the mixing step (i) were adapted in order to obtain the desired molar proportions in the ceramic material.
3—Microstructure of the Refractory Ceramic Materials Comprising 1 mol %, 3 mol %, 5 mol % and 8 mol % Y2O3.
3.1—Derivation by X-Ray Diffraction of the Volume Fraction of Material Occupied by Hafnium Dioxide HfO2 Grains Having a Monoclinic or Cubic Structure.
The volume fractions of the monoclinic and cubic phases within the material were determined.
The principle used for that purpose is to obtain an X-ray diffraction spectrum and to compare the strength of line 111 of the cubic phase with the sum of the strengths of the 1 and −1 combination lines of the monoclinic phase.
Nevertheless, the strengths of these lines were corrected in order to separate the peaks of these cubic and monoclinic phases, which are located within close angular domains.
Since hafnium dioxide HfO2 has a similar diffraction pattern to that of zirconia ZrO2, this correction was based on zirconia data according to the research work of D. L PORTER and A. H HEURE (Journal of American Ceramist Society, 1979, 62 (5-6), 298-305).
These authors have shown (by taking into account the multiplicity factor and the linear absorption coefficient) that the volume fraction Vm of the monoclinic phase in zirconia stabilized by magnesia MgO could be written as:

Vm=(1.6031×Im(11−1))/(1.6031×Im(11−1)+Ic(111)),

where Im(11−1) and Ic(111) designate the strengths of the X-ray diffraction lines of the monoclinic and cubic phases, respectively.
By analogy with the research work of PORTER et al., the volume fraction occupied by hafnium dioxide HfO2 grains having monoclinic and cubic structures was thus determined for the refractory ceramic materials comprising 1%, 3%, 5% and 8% Y2O3 prepared in the above examples, by measuring the strengths of the X-ray diffraction lines of the hafnium dioxide HfO2 monoclinic and cubic phases.
Table 1 summarizes these results. It also shows the volume fraction that the cubic phase should theoretically occupy according to the HfO2—Y2O3 phase diagram taken from the document by N. ISUPOVA et al., “The HfO2-Y2O3 system in the region rich in hafnium dioxide, Inorganic material, 1969, 11, no 5, 1658-1661.”












TABLE 1










% cubic,



Mol % Y2O3
% monoclinic
% cubic
theoretical









1%
90%
10%
 0%



3%
61%
39%
13%



5%
57%
43%
50%



8%
37%
63%
87%










Unexpectedly, in spite of what is shown by the HfO2 Y2O3 phase diagram, the volume fraction occupied by the hafnium dioxide HfO2 grains having a cubic structure is greater, relative to that which was theoretically expected, for refractory ceramic materials comprising 1% and 3% Y2O3, and smaller for refractory ceramic materials comprising 5% and 8% Y2O3. Thus, the refractory ceramic material according to this invention is a material which is not in thermodynamic equilibrium. Advantageously, this allows stabilization to be achieved by means of the hafnium dioxide HfO2 grains whose cubic structure is appropriately adjusted, that is in such a way that the refractory ceramic material according to this invention has a sufficiently high solidus temperature without suffering from cracking during a cooling phase including a transition through a temperature of about 1700° C.
3.2—Distribution Throughout the Material of Hafnium Dioxide HfO2 Grains Having Monoclinic and Cubic Structures.
The refractory ceramic materials of the above example were analyzed by means of a SEM in the backscattered electron mode. The micrographs corresponding to the refractory ceramic materials comprising 8%, 5%, 3% and 1% Y2O3 are shown in FIGS. 1A, 1B, 1C and 1D respectively. In the micrographs thus obtained, the grey level is inversely proportional to the average atomic number of the chemical element analyzed. Yttrium oxide Y2O3 contained in the stabilized cubic hafnium dioxide HfO2 phase (2) thus corresponds to the dark grey areas.
Without being bound to any particular theory, the presence of the stabilized cubic hafnium dioxide HfO2 phase (2) surrounding at least one closed pore (3) suggests that the Kirkendall effect is involved. This effect is caused by the difference between the diffusion rates of the two cations, yttrium Y3+ and hafnium Hf4+, within the cubic phase and causes the volume occupied before sintering by the Y2O3 grains to be replaced at the end of sintering by a pore. When the agglomeration of several pores (5) is not taken into account, it may be seen that the closed pores have an average size of 3 μm (preferably in the range between 1 μm and 10 μm, thus corresponding to the average size the yttrium oxide Y2O3 powder grains may have, which size may be determined by laser granulometry, as mentioned above).
3.2.1—Refractory Ceramic Materials Comprising 3 mol %, 5 mol % and 8 mol % Y2O3.
For materials comprising 8%, 5% and 3% Y2O3, the grains of the cubic hafnium dioxide HfO2 phase (2) stabilized by 3 mol % to 8 mol % yttrium oxide Y2O3 undergo segregation since they are distributed mainly around at least one closed pore (3). Thus, within the monoclinic hafnium dioxide HfO2 (1), they form inclusions (4), each of which comprises at least this closed pore (3).
Taking for example the material comprising 8% Y2O3, this segregation is confirmed by the mapping carried out using an Energy Dispersive Spectrometer, as shown in the pictures in the upper portion of FIG. 2.
The pictures in the upper left and right portions of FIG. 2 show the distribution of the hafnium and yttrium elements within this material, respectively. Based on these two pictures, it is thus possible to confirm the homogeneity of the distribution of hafnium dioxide HfO2, and the segregation of yttrium oxide Y2O3, which is the element doping and stabilizing the grains in the cubic hafnium dioxide HfO2 phase (2), in the form of inclusions.
The pictures in the lower left and right portions of FIG. 2 show the mapping obtained by means of an Energy Dispersive Spectrometer for elemental oxygen, and, as a reference, a backscattered electron SEM picture of the material comprising 8% Y2O3, respectively.
3.2.2—Refractory Ceramic Materials Comprising 1 mol % Y2O3.
For the materials comprising 1% Y2O3 (for which, typically, the cubic hafnium dioxide HfO2 grains are stabilized by 0.7 mol % to 1.5 mol % yttrium oxide Y2O3), the cubic hafnium dioxide HfO2 grains are homogeneously distributed throughout the volume of the ceramic material. The agglomeration of several pores (5) has virtually disappeared from the material.
The distribution is homogeneous in that it is not possible to detect any segregation or inclusions (4) of the cubic hafnium dioxide HfO2 phase (2), by means of a backscattered electron SEM picture, within the phase consisting of monoclinic hafnium dioxide HfO2 (1). This results in an increase of the cracking resistance during increases/decreases in temperature between 1500° C. and 1800° C.
As a result of this excellent homogeneity in the microstructure of the material, the latter does not contain areas in which the yttrium oxide Y2O3 is locally more concentrated than within the rest of the material. In other words, the 0.7 mol % to 1.5 mol %, preferably, the 1 mol % yttrium oxide Y2O3 content is observed in practice throughout the volume of the material. This has the advantage that the solidus temperature is nearly the same throughout the material, namely of the order of 2800° C., and that it does not decrease locally due to a higher yttrium oxide Y2O3 content, which would generate hot spots acting as sources of mechanical brittleness in the material.
4—Characteristics of Refractory Ceramic Materials Comprising 1 mol %, 3 mol %, 5 mol % and 8 mol % Y2O3.
4.1—Measurement of Compactness.
In order to determine compactness, the calculation explained below for the refractory ceramic material manufactured according to Example 2 and comprising 5 mol % Y2O3 was performed as follows:
1) The density of the hafnium dioxide HfO2 cubic phase comprising 5 mol % Y2O3 (this phase being referred to in the following calculation as the “cubic solid solution”) was computed on the basis of the data disclosed in the above-mentioned document by N. ISUPOVA. The authors of this document have shown that the lattice parameter of hafnium dioxide HfO2 in its cubic phase varies with the Y2O3 percentage and calcination temperature.
Based on this document, the crystallographic quantities of the cubic solid solution resulting from calcination at 1600° C. may be estimated. The lattice parameter of the cubic solid solution is thus estimated to be 5.105 Å. Therefore, the volume of a lattice unit is: Vlattice 5%=(5.105 10−10)=1.3304 10−28 m3.
The authors have also found that the cubic solid solution had a fluorite type of structure of formula (Hf(1-2x)Y2x)O(2-x). This structure has a number of repeating units Z=4.
Moreover, since 100 moles of the cubic solid solution contain 5 mol % Y2O3, then x=0.05 moles.
For the cubic solid solution, the molar weight (5% molar W), the weight of a lattice unit (5% w), and the density are therefore computed as follows:

5% molar W=(1−2x)WHf+2×WY+(2−x)W0=(1−(2×0.05))×178.5)+(2×0.05×88.9)+(2−0.05)×16=200.74 g/mol  i)

5% w=5% molar W/Avogadro's number=200.74/6.023 1023=3.33 10−22 g  ii)

5% density=(5% w×Z)/V(cm3)=(3.33 10−22×4)/1.3304 10−22=10.01 g·cm−3  iii)

2) The theoretical density of each material was then computed by deriving the respective contributions of the densities of the monoclinic (Dm=9.68 g. m−3) and cubic (Dc=10.01 g·cm−3) hafnium dioxide HfO2 phases as a function of the volume fraction that each phase occupies within the material.
The computation based on the values listed in Table 2 is as follows:

Density (HfO2/HfO2+5% Y2O3)=(Vm×Dm)+(Vc×Dc)=9.84 g·cm−3








TABLE 2







HfO2 + 5 mol % Y2O3 sintered at 1600° C. for 1 h









Cubic phase


Monoclinic phase
for 5 mol % Y2O3










Volume fraction
Density
Volume fraction
Density


(Vm)
(Dm)
(Vc)
(Dc)





56.8%
9.68 g · cm−3
43.2%
10.01 g · cm−3







Total density = 9.84 g · cm−3









3) The compactness of the cubic solid solution was computed by deriving the ratio of the theoretical density determined according to point 2, to the density measured according to the usual geometry-based method:

compactness=(8.78/9.84)×100=90.8%.

Similar computations were carried out for the 1 mol %, 3 mol % and 8 mol % Y2O3 refractory ceramic materials (manufactured according to Examples 1 and 2 above) as well as for the corresponding materials containing 0 mol % and 0.5 mol % Y2O3. The compactness values (referred to as C1) thus determined are given in Table 3 shown in FIG. 3.
4.2—Measurement of Other Characteristics
Other characteristics were determined for the ceramic materials prepared according to the previous examples. The results are summarized in Table 3 shown in FIG. 3. They were obtained as follows.
As explained above, porosity is the complement of compactness (noted C1) as computed in the previous examples (both quantities being expressed as percentages by volume of material). The porosity is then determined by subtracting the compactness from the total volume of the refractory ceramic material according to this invention.
Moreover, the porosity is of two different types: open or closed. Open porosity is measured according to a method known to those skilled in the art such as the immersion method carried out using a vacuum chamber. Its subtraction from the total porosity leads to the closed porosity value.
As for the non-interconnected nature of the open porosity of the refractory ceramic material according to this invention, this is assessed qualitatively based on methods known to those skilled in the art, which demonstrate the non-traversing nature of such pores.
Among those methods, is a tightness test such as the bubbling test. This test consists in immersing a material sample, such as a tube having one closed end, into a water container. Air is then blown under pressure into the tube with its closed end upwards. If the open porosity “traverses” the material, air will pass through the tube's wall until air bubbles form on its outer surface. However, if the open pores are not interconnected, the tube is airtight and no air bubbles will form.
Another method consists in cutting several cross-sections of the material and checking, from a picture taken with a secondary electron SEM, whether the open pores in this material are interconnected. As an example, FIGS. 4A and 4B show such a SEM picture of a cross-section of a refractory ceramic material according to this invention comprising 3 mol % Y2O3. These clearly show that the pores reaching the surface of the material (open pores) are not interconnected. This method may also be used to determine whether closed pores are interconnected or not.
Compactness C2 was also measured. This corresponds to the material's compactness after reaching a temperature of 1800° C. It was determined according to the methodology explained in point 4.1, after the ceramic materials had been maintained at a temperature of 1800° C. for 30 minutes and then allowed to cool down at the natural cooling rate of the furnace. It was not measured for the 0.5% ceramic material.
The difference between the compactness values C1 and C2 makes it possible to determine the magnitude of the volume difference of the ceramic material during a cooling phase including a transition through a temperature of about 1700° C.
Finally, no cracking was observed in the ceramic materials comprising 3 to 8% Y2O3. The observed cracking of the 1% Y2O3 ceramic material was quite superficial. Cracking only appeared on pellet edges, no cracking being detected through optical microscopy.
In particular, it appears from the different characteristics given in Table 3 of FIG. 3 that:

    
    
        The refractory ceramic materials according to this invention comprising 3 mol % to 8 mol % Y2O3 may have a porosity in the range between 8% and 15% and a closed porosity in the range between 7% and 15%. Open porosity is generally about 0.5%.
        The refractory ceramic materials according to this invention comprising 3 mol % to 5 mol % Y2O3 may have a porosity in the range between 8% and 11% and a closed porosity in the range between 7% and 11%. Open porosity is generally about 0.5%.
        The refractory ceramic materials according to this invention comprising 0.7 mol % to 1.5 mol % Y2O3 may have at least one of the following characteristics: a porosity in the range between 4% and 6%, a closed porosity in the range between 1% and 5%, an open porosity in the range between 0.5% and 2% which increases when the number of Y2O3 moles decreases, a compactness of 96% to 97%, and cubic hafnium dioxide HfO2 grains occupying between 5% and 18% of the volume of said ceramic material.
    
    


Moreover, preferably, the microstructure of the refractory ceramic materials according to this invention which comprise 0.5 mol % to 8 mol % yttrium oxide Y2O3 is such that:

    
    
        the hafnium dioxide HfO2 grains with a monoclinic structure have an elongated shape and/or an average size in the range between 1 μm and 3 μm,
        the hafnium dioxide HfO2 grains with a cubic structure stabilized by yttrium oxide Y2O3 have a symmetrical shape with a square cross-section and/or an average size in the range between 3 μm and 15 μm.
    
    


These microstructural characteristics may in particular be determined from SEM pictures of the material according to this invention, after processing according to a method known to those skilled in the art such as polishing followed by thermal or chemical etching at the grain boundaries. FIGS. 5A and 5B show such pictures for the refractory ceramic materials according to this invention comprising 8 mol % and 5 mol % yttrium dioxide Y2O3, respectively. They clearly show some of the above-mentioned microstructural characteristics for hafnium dioxide HfO2 grains having a monoclinic (1) and a cubic (2) structure stabilized by yttrium oxide Y2O3.
The ceramic materials comprising 1 mol % (in practice, from 0.7% to 1.5%) Y2O3 were found to be of particular interest because they combine a high solidus temperature, a possibly large closed porosity, a good cracking strength, a high compactness and a small volume expansion when cooled below 1800° C. Their high compactness (and therefore density) also results in these materials having better mechanical strength, in particular up to a temperature of 2600° C.
From the above, it clearly appears that the microstructure of a refractory ceramic material having a compactness greater than 85% endows it with properties making it suitable for use in the composition of structural parts of furnaces for the study of the behavior of a nuclear fuel during a core meltdown accident in a nuclear reactor. In particular, such a material does not undergo cracking during temperature increase/decrease cycles which include the range from 1500° C. to 1800° C., and has a solidus temperature greater than 2500° C.
More generally, such a material may also enter the composition of devices for high temperature thermal analyses such as devices for Thermo-gravimetric Analysis (TGA), Differential Thermal Analysis (DTA) or a dilatometer.

## Claims

1. A refractory ceramic material possessing a solidus temperature between 2500° C. and 2800° C., having a compactness greater than 85%, and a microstructure such that said material is composite and comprises:
hafnium dioxide HfO2 grains having a monoclinic structure (1);
hafnium dioxide HfO2 grains having a cubic structure (2) which is stabilized by yttrium oxide Y2O3, said yttrium oxide Y2O3 representing 0.5 mol % to 8 mol % relative to the total number of moles of hafnium dioxide HfO2;
closed pores (3);
non-interconnected open pores.

2. The refractory ceramic material according to claim 1, characterized in that said open pores represent less than 3% of the volume of said ceramic material.

3. The refractory ceramic material of claim 2, wherein the open pores represent less than 1 percent of the volume of the ceramic material.

4. The refractory ceramic material of claim 2, wherein the open pores represent less than 0.5 percent of the volume of the ceramic material.

5. The refractory ceramic material according to claim 2, characterized in that said cubic hafnium dioxide HfO2 is stabilized by 3 mol % to 8 mol % yttrium oxide Y2O3 in order to form inclusions (4), each comprising at least one closed pore (3), within said monoclinic hafnium dioxide HfO2.

6. The refractory ceramic material according to claim 2, characterized in that the grains of said cubic hafnium dioxide HfO2 are stabilized by 0.7 mol % to 1.5 mol % yttrium oxide Y2O3.

7. The refractory ceramic material according to claim 1, characterized in that said cubic hafnium dioxide HfO2 is stabilized by 3 mol % to 8 mol % yttrium oxide Y2O3 in order to form inclusions (4), each comprising at least one closed pore (3), within said monoclinic hafnium dioxide HfO2.

8. The refractory ceramic material according to claim 7, characterized in that said cubic hafnium dioxide HfO2 is stabilized by 3 mol % to 5 mol % yttrium oxide Y2O3.

9. The refractory ceramic material according to claim 8, characterized in that said closed pores have an average size of 3 μm.

10. The refractory ceramic material according to claim 8, characterized in that said grains of monoclinic hafnium dioxide HfO2 occupy from 37% to 61% of the volume of said ceramic material.

11. The refractory ceramic material according to claim 7, characterized in that said closed pores have an average size of 3 μm.

12. The refractory ceramic material according to claim 7, characterized in that said grains of monoclinic hafnium dioxide HfO2 occupy from 37% to 61% of the volume of said ceramic material.

13. The refractory ceramic material according to claim 1, characterized in that the grains of said cubic hafnium dioxide HfO2 are stabilized by 0.7 mol % to 1.5 mol % yttrium oxide Y2O3.

14. The refractory ceramic material according to claim 13, characterized in that said material has a compactness of 96% to 97%.

15. The refractory ceramic material according to claim 13, characterized in that said cubic hafnium dioxide HfO2 is stabilized by 1 mol % yttrium oxide Y2O3.

16. The refractory ceramic material according to claim 9, characterized in that the grains of said cubic hafnium dioxide HfO2 occupy 10% of the volume of said ceramic material.

17. The refractory ceramic material according to claim 16, characterized in that said material has a solidus temperature of about 2800° C.

18. The refractory ceramic material according to claim 15, characterized in that said material has a solidus temperature of about 2800° C.

19. The refractory ceramic material according to claim 15, characterized in that the grains of said cubic hafnium dioxide HfO2 are homogeneously distributed throughout the volume of said ceramic material.

20. The refractory ceramic material according to claim 15, characterized in that the grains of said cubic hafnium dioxide HfO2 are homogeneously distributed throughout the volume of said ceramic material.

21. A structural part comprising the refractory ceramic material according to claim 1.