# Patent

## Title
Methods for making reinforced refractory crucibles for melting titanium alloys

## Abstract

Methods for making a reinforced refractory crucible for melting titanium alloys including providing a form, applying a facecoat to the form, the facecoat having at least one facecoat layer, applying a backing about the facecoat, the backing having at least one backing layer, applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, or a combination thereof where the reinforcing element includes at least one composition selected from ceramic compositions, metallic compositions, and combinations thereof.

## Background
CROSS REFERENCE TO RELATED APPLICATIONS
This application claims priority to U.S. Provisional Application Ser. No. 60/914,935, filed Apr. 30, 2007, which is herein incorporated by reference in its entirety.


TECHNICAL FIELD
Embodiments described herein generally relate to methods for making reinforced crucibles suitable for melting titanium alloys. More particularly, embodiments herein generally describe methods for making reinforced refractory crucibles suitable for melting highly reactive titanium alloys, such as titanium aluminide.
BACKGROUND OF THE INVENTION
Turbine engine designers are continuously looking for new materials with improved properties for reducing engine weight and obtaining higher engine operating temperatures. Titanium alloys, and in particular, titanium aluminide (TiAl) based alloys, possess a promising combination of low-temperature mechanical properties, such as room temperature ductility and toughness, as well as high intermediate temperature strength and creep resistance. For these reasons, TiAl-based alloys have the potential to replace nickel-based superalloys, which are currently used to make numerous turbine engine components.
Vacuum induction melting is one method often used to make turbine engine components, such as airfoils, and generally involves heating a metal in a crucible made from a non-conductive refractory alloy oxide until the charge of metal within the crucible is melted down to liquid form. When melting highly reactive metals such as titanium or titanium alloys, vacuum induction melting using cold wall or graphite crucibles is typically employed. This is because melting and casting from ceramic crucibles can introduce significant thermal stress on the crucible, which can result in the crucible cracking. Such cracking can reduce crucible life and cause inclusions in the component being cast.
Moreover, difficulties can arise when melting highly reactive alloys, such as TiAl, due to the reactivity of the elements in the alloy at the temperatures needed for melting to occur. As previously mentioned, while most vacuum induction melting systems use refractory alloy oxides for crucibles in the induction furnace, alloys such as TiAl are so highly reactive that they can attack the refractory alloys present in the crucible and contaminate the titanium alloy. For example, ceramic crucibles are typically avoided because the highly reactive TiAl alloys can break down the crucible and contaminate the titanium alloy with both oxygen and the refractory alloy from the oxide. Similarly, if graphite crucibles are employed, the titanium aluminide can dissolve large quantities of carbon from the crucible into the titanium alloy, thereby resulting in contamination. Such contamination results in the loss of mechanical properties of the titanium alloy.
Additionally, while cold crucible melting can offer metallurgical advantages for the processing of the highly reactive alloys described previously, it also has a number of technical and economic limitations including low superheat, yield losses due to skull formation and high power requirements. These limitations can restrict commercial viability.
Accordingly, there remains a need for methods for making reinforced crucibles for use in melting highly reactive alloys that are more resistant to thermal stresses generated during the casting process and less likely to contaminate the alloy.
BRIEF DESCRIPTION OF THE INVENTION
Embodiments herein generally relate to methods for making reinforced refractory crucibles for melting titanium alloys comprising providing a form; applying a facecoat to the form, the facecoat having at least one facecoat layer; applying a backing about the facecoat, the backing having at least one backing layer; applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, or a combination thereof wherein the reinforcing element comprises at least one composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof.
Embodiments herein also generally relate to methods for making reinforced refractory crucibles for melting titanium alloys comprising providing a form; applying a facecoat to the form, the facecoat having at least one facecoat layer; applying a backing about the facecoat, the backing having at least one backing layer; applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, or a combination thereof wherein the reinforcing element comprises a configuration selected from the group consisting of a continuous fiber, a tape, a mesh, a chopped fiber, and combinations thereof.
Embodiments herein also generally relate to methods for making reinforced refractory crucibles for melting titanium alloys comprising providing a form; applying a facecoat to the form, the facecoat having at least one facecoat layer; applying a backing about the facecoat to produce a crucible mold, the backing having at least one backing layer; applying a stucco layer to each of the at least one facecoat layer and the at least one backing layer; applying a reinforcing element to at least a portion of the facecoat layer, the backing layer, the stucco layer, or a combination thereof wherein the reinforcing element comprises a composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof, removing the form from the crucible mold; and firing the crucible mold to produce the reinforced crucible for melting titanium alloys wherein the reinforcing element comprises a configuration selected from the group consisting of a continuous fiber, a tape, a mesh, a chopped fiber, and combinations thereof and wherein the reinforcing element is tailored to support particular stresses present in different regions of the crucible.
These and other features, aspects and advantages will become evident to those skilled in the art from the following disclosure.



BRIEF DESCRIPTION OF THE DRAWINGS
While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the embodiments set forth herein will be better understood from the following description in conjunction with the accompanying figures, in which like reference numerals identify like elements.
FIG. 1 is a schematic perspective view of one embodiment of a crucible in accordance with the description herein;
FIG. 2 is a schematic perspective view of one embodiment of a form in accordance with the description herein;
FIG. 3 is a schematic cross-sectional view of one embodiment of a crucible mold in accordance with the description herein;
FIG. 4 is a schematic close-up view of a portion of a cross-section of the crucible mold of FIG. 3;
FIG. 5 is an elevated front view of one embodiment of a crucible mold with reinforcing elements positioned in an adjacent orientation in accordance with the description herein;
FIG. 6 is an elevated front view of one embodiment of a crucible mold with two reinforcing elements, each applied to a different layer of the crucible mold, in accordance with the description herein;
FIG. 7 is an elevated front view of one embodiment of a crucible mold with reinforcing elements positioned in a stacked orientation in accordance with the description herein; and
FIG. 8 is a schematic cross-sectional view of one embodiment of a crucible mold after the form has been removed and a topcoat applied in accordance with the description herein.



DETAILED DESCRIPTION OF THE INVENTION
Embodiments described herein generally relate to methods for making refractory crucibles suitable for melting titanium alloys. More specifically, embodiments described herein generally relate to methods for making reinforced refractory crucibles for melting titanium alloys comprising providing a form; applying a facecoat to the form, the facecoat having at least one facecoat layer; applying a backing about the facecoat, the backing having at least one backing layer; applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, or a combination thereof wherein the reinforcing element comprises at least one composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof.
While embodiments herein will generally focus on methods for making reinforced crucibles suitable for melting TiAl for use in making near net shape airfoils, the description should not be limited to such. Those skilled in the art will understand that the present embodiments may be used to make reinforced crucibles suitable for melting any titanium alloy for use in making any near net shape gas turbine component.
Turning to FIG. 1, embodiments herein relate to a refractory crucible 8 suitable for melting titanium alloys. Crucible 8 can have an interior 9 and can be made in accordance with the description herein below. To begin, a crucible mold can be made. As used herein “mold” refers to the unfired components that when fired under suitable conditions form crucible 8 of FIG. 1. To make a crucible mold, a form 10 can be provided, as shown in FIG. 2. While form 10 can comprise any material capable of removal from the crucible mold, in one embodiment, form 10 can comprise wax, plastic or wood, and may be hollow or solid. Moreover, form 10 can take any shape and have any dimension necessary to produce the desired interior of the crucible and may comprise a handle 12, or other like mechanism, for ease of handling.
As shown in FIGS. 3 and 4, a facecoat 16 comprising at least one facecoat layer 18, and optionally at least one stucco layer 20, can be applied to form 10. As used herein throughout, “at least one” means that there may be one or more than one and specific layers will be designated herein throughout as “first facecoat layer,” “second facecoat layer,” and the like. Since facecoat layer 18 can be exposed to the TiAl during the melting process, facecoat layer 18 should be inert to the reactive TiAl so as not to degrade and contaminate the alloy during melting. Therefore, in one embodiment, face coat layer 18 may comprise an oxide. As used herein throughout, “oxide” refers to a composition selected from the group consisting of scandium oxide, yttrium oxide, hafnium oxide, a lanthanide series oxide, and combinations thereof. Furthermore, the lanthanide series oxide (also known as “rare earth” compositions) may comprise an oxide selected from the group consisting of lanthanum oxide, cerium oxide, praseodymium oxide, neodymium oxide, promethium oxide, samarium oxide, europium oxide, gadolinium oxide, terbium oxide, dysprosium oxide holmium oxide, erbium oxide, ytterbium oxide, lutetium oxide, and combinations thereof.
Facecoat layer 18 may comprise a facecoat slurry made from a powder of the oxide mixed into a colloidal suspension. In one embodiment, the oxide powder may be a small particle powder having a size of less than about 70 microns, and in another embodiment, from about 0.001 microns to about 50 microns, and in yet another embodiment from about 1 micron to about 50 microns. The colloid can be any colloid that gels in a controlled fashion and is inert to TiAl, such as, for example, colloidal silica, colloidal yttria, colloidal alumina, colloidal calcium oxide, colloidal magnesium oxide, colloidal zirconium dioxide, colloidal lanthanide series oxides, and mixtures thereof. While any of the previously listed oxides can be used to make the facecoat slurry of facecoat layer 18, in one embodiment, the facecoat slurry may comprise yttrium oxide particles in a colloidal silica suspension, while in another embodiment, the facecoat slurry may comprise yttrium oxide particles in a colloidal yttria suspension. The composition of the facecoat slurry can vary, however, in general, the facecoat slurry may comprise from about 40% to about 100% of the oxide and from about 0% to about 60% of the colloid, by weight.
Once the facecoat slurry of facecoat layer 18 is prepared using conventional practices, form 10 may be exposed to the facecoat slurry using a method selected from the group consisting of dipping, spraying, and combinations thereof. Generally, once applied, facecoat layer 18 can have a thickness of from about 50 microns to about 500 microns, and in one embodiment from about 150 microns to about 300 microns, and in yet another embodiment about 200 microns.
While still wet, facecoat layer 18 may optionally be coated with a stucco layer 20, as shown in FIGS. 3 and 4. As used herein, “stucco” refers to coarse ceramic particles generally having a size greater than about 100 microns, and in one embodiment from about 100 microns to about 5000 microns. Stucco 20 can be applied to each facecoat layer to help build up the thickness of the crucible wall and provide additional strength. A variety of materials may be suitable for use as stucco layer 20, however, in one embodiment, the stucco may comprise a refractory material, such as, but not limited to, alumina or aluminosilicates, combined with an oxide, as defined herein. The ratio of the refractory material to the oxide in stucco layer 20 can vary, however, in one embodiment, stucco layer 20 can comprise from about 0% to about 60% of the refractory material and from about 40% to about 100% of the oxide, by weight. Stucco layer 20 may be applied to facecoat layer 18 in any acceptable manner, such as dusting for example. Generally, stucco layer 20 can have a thickness of from about 100 microns to about 2000 microns, and in one embodiment from about 150 microns to about 300 microns, and in yet another embodiment about 200 microns.
Facecoat layer 18, and optional stucco layer 20 can be air-dried and additional facecoat layers and stucco layers may be applied in the manner described previously, if desired, to complete facecoat 16. In the embodiments shown in FIGS. 3 and 4, first and second facecoat layers 18, and alternating stucco layers 20, are present, though those skilled in the art will understand that facecoat 16 may comprise any number of facecoat layers and stucco layers. While each facecoat layer 18 may comprise a different oxide/colloid mixture, in one embodiment, each facecoat layer 18 comprises the same oxide/colloid mixture. Once the desired number of facecoat layers 18 and stucco layers 20 have been applied, a backing 22 may then be applied.
Backing 22 can help provide additional strength and durability to the finished crucible 8. As such, backing 22 may consist of at least one backing layer 24, shown in FIG. 4, which can comprise a backing slurry including a refractory material selected from the group consisting of aluminum oxide, zirconium silicate, silicon dioxide, and combinations thereof, in a colloidal silica suspension. Specific layers may be designated herein throughout as “first backing layer,” “second backing layer,” and the like. As an example, in one embodiment, backing layer 24 may comprise a backing slurry made from aluminum oxide particles in a colloidal silica suspension. The composition of the backing slurry can vary, however, in general, the backing slurry may comprise from about 10% to about 40% of the refractory material and from about 60% to about 90% of the colloid, both by weight. Similar to the facecoat layers, each backing layer 24 may optionally comprise a stucco layer 20 adhered thereto, as shown in FIG. 4, which may be the same as or different from the stucco used previously to make the facecoat. Each backing layer 24, including the stucco, can have a thickness of from about 150 microns to about 4000 microns, and in one embodiment from about 150 microns to about 1500 microns, and in yet another embodiment about 700 microns.
Similar to the facecoat layers, each backing layer 24 may be applied using a method selected from the group consisting of dipping, spraying, and combinations thereof. While any number of backing layers 24 can be applied, in one embodiment, there may be from 2 to 40 backing layers. Each backing layer 24 may comprise the same composition of refractory material and colloid, each may be different, or they may comprise some combination in between. After applying the desired number of backing layers, and optional stucco layers, the resulting crucible mold 26 can be further processed.
It should be noted that in some cases it may be desirable to grade the stucco layers by altering particle size, layer thickness and/or composition as they are applied. As used herein, the term “grade,” and all forms thereof, refers to gradually increasing the strength of subsequently applied stucco layers by, for example, increasing the particle size of the stucco material, increasing the thickness of the stucco layer and/or utilizing increasingly stronger refractory material/colloid compositions as the stucco layer. Such grading can allow the stucco layers to be tailored to account for differences in thermal expansion and chemical properties of the various facecoat layers and backing layers to which they are applied. More specifically, grading the stucco layers provides differing porosities and can adjust the modulus of the crucible, which taken together, can help account for the differences in thermal expansion as previously discussed.
At any time during the construction of the crucible mold, at least one reinforcing element 14 may be applied to at least a portion of any one or more of facecoat layer 18, backing layer 24, or a stucco layer 20 thereof. In the embodiments of FIGS. 3, 4, 5 and 8, reinforcing element 14 is shown applied to a stucco layer 20 of facecoat 16. However, those skilled in the art will understand that this embodiment is for illustration purposes only and should not be used to limit the scope of the present description.
Reinforcing element may comprise anything capable of increasing the strength of the finished crucible and its resistance to thermal cracking in comparison to crucibles lacking such reinforcing elements. As used herein, “reinforcing element” refers to compositions applied to one or more layers of the crucible mold during construction, rather than to oxides, refractory materials and/or colloids present in the layers of the crucible mold that may react to form reinforcing materials during the firing the of the crucible mold, as explained herein.
While reinforcing element 14 may be made from any number of compositions, in one embodiment, reinforcing element 14 may comprise a composition selected from the group consisting of ceramic compositions, metallic compositions and combinations thereof. More specifically, reinforcing element 14 may comprise at least one ceramic composition selected from the group consisting of yttria, alumina, sapphire, nitride, yttrium aluminum garnet (YAG), silicon carbide (SiC), silicon aluminum oxinitride (such as SiAlONTM), silica, mullite (such as NEXTELTM), zirconia, zircon, zircar, and combinations thereof; at least one metallic composition selected from the group consisting of tungsten, tantalum, molybdenum, niobium, rhenium, alloys thereof, and combinations thereof. Additionally, reinforcing element 14 may comprise a combination of ceramic compositions and metallic compositions, known as cermets, which can include, but should not be limited to, alumina-50% molybdenum, alumina-90% molybdenum, alumina-50% tungsten, and alumina-90% tungsten, by volume.
Reinforcing element 14 may comprise any configuration capable of providing increased strength and resistance to thermal cracking to the finished crucible. In one embodiment, reinforcing element 14 may comprise a configuration selected from the group consisting of a continuous fiber, tape, mesh, chopped fiber, and combinations thereof. The dimensions of the configuration may vary, such as by width, thickness, weave, and the like, according to characteristics desired in the reinforcing element. However, in one embodiment, reinforcing element can have a thickness of less than about 2000 microns, and in another embodiment from about 100 microns to about 1000 microns.
Additionally, a single configuration may be applied, or more than one configuration may be applied, to the same layer, or different layers, of the crucible mold. If more than one reinforcing element is applied to the same layer, the reinforcing elements may be applied in an adjacent orientation, a stacked orientation, or some combination thereof, as described herein below. For instance, in one embodiment shown in FIG. 5, both a continuous fiber element and a mesh element may be applied to the same layer in an adjacent orientation. In another embodiment shown in FIG. 6, a mesh element and chopped fiber elements may be applied to different layers. In yet another embodiment shown in FIG. 7, a tape element and chopped fiber elements may be applied to the same layer in a stacked orientation.
Moreover, reinforcing element 14, the composition thereof, and the configuration thereof, may be selected to support particular stresses present in different regions of the crucible, such as the base region 30, the transition region 32 (i.e. the portion connecting base region 30 to lower region 34), the lower region 34 (i.e. the sides containing the titanium melt during casting), the upper region 36 (i.e. the sides above the titanium melt during casting) 34, and the pour lip region 38, as indicated generally in FIG. 5. In particular, as bending stresses may be significant in base 30, transition 32, and pour lip 36 regions, it may be desirable to utilize at least a mesh reinforcing element 14 in these regions, as shown in FIG. 5. Similarly, in the sides of the crucible (i.e. the upper 36 and lower 34 regions), hoop stresses will generally be the principal concern and thus, it may be desirable to utilize at least a continuous fiber reinforcing element 14 in such regions, as shown in FIG. 5. By specifically tailoring the reinforcing element to the particular regions of the crucible, thermal stress resistance can be optimized to help ensure the crucible maintains its integrity throughout the heating, melting, pouring, and cool-down phases.
Regardless of the composition or configuration of reinforcing element 14, the application thereof generally follows the same procedure. The at least one reinforcing element 14 may be applied about the selected layer, or layers, while the slurry is still wet. Applying reinforcing element 14 while the selected layer is still wet allows reinforcing element 14 to become secured to crucible mold 26. More particularly, as the selected layer of crucible mold 26 dries, reinforcing element 14 can adhere thereto. The application of reinforcing element 14 can include, but should not be limited to, wrapping or winding reinforcing element 14 about the selected layer(s) of crucible mold 26, as shown in FIGS. 5 and 7, or in the case of chopped fibers, pressing or dusting reinforcing element 14 in the desired location or locations about the selected layer of crucible mold 26, as shown in FIGS. 6 and 7. If more than one reinforcing element is used, and a stacked orientation is selected (see FIG. 7 for example), the previously described techniques can be employed to apply one reinforcing element over another. Those skilled in the art will understand that the reinforcing elements can be either selectively placed about at least a portion of a selected layer of the crucible mold, or alternately, about and entire selected layer of the crucible mold.
Crucible mold 26 may then be dried using conventional practices and form 10 may be removed. A variety of methods may be used to remove form 10 from crucible mold 26. As previously mentioned, form 10 may comprise wax and therefore may be removed by placing crucible mold 26 in a furnace, steam autoclave, microwave, or other like device, and melting form 10 leaving an open interior 9 in crucible mold 26, as shown in FIG. 8. The temperature required to melt form 10 from crucible mold 26 can generally be low and in one embodiment, can range from about 40° C. to about 120° C.
Optionally, interior 9 of crucible mold 26 may then be washed with a colloidal slurry to form a topcoat 28, as shown in FIG. 8. Washing can generally involve applying a coating to the interior of the crucible using any method known to those skilled in the art, such as spraying, prior to firing the crucible. Topcoat 28 can have any desired thickness, however, in one embodiment, topcoat 28 has a thickness of up to about 500 microns, and in another embodiment from about 20 microns to about 400 microns. Topcoat 28 can comprise a colloidal slurry selected from the group consisting of yttria in a colloidal yttria suspension, yttria in a colloidal silica suspension, and combinations thereof. This topcoat can help further ensure that the crucible will remain inert with respect to the titanium alloy during melting.
The hollow crucible mold 26 can then be fired to higher temperatures. Firing crucible mold 26 can help provide additional strength to the finished crucible because during this heating process, the materials that make up the facecoat layers, stucco, and backing layers can interdiffuse with one another and sinter together. Initially, the crucible mold can be fired to a temperature of from about 800° C. to about 1400° C., and in one embodiment from about 900° C. to about 1100° C., and in one embodiment about 1000° C. This first firing can take place for any length of time needed to help burn off any remaining form material, as well as provide a limited degree of interdiffusion among the ceramic constituents of the crucible, which in one embodiment may be from about 0.5 hours to about 50 hours, in another embodiment from about 1 hour to about 30 hours, and in yet another embodiment about 2 hours. Next, the crucible mold can be fired to a temperature of from about 1400° C. to about 1800° C., and in one embodiment from about 1500° C. to about 1800° C., and in yet another embodiment from about 1600° C. to about 1700° C. This second firing can take place for any length of time needed to substantially complete the interdiffusion of the ceramic constituents, as well as cause a reaction of the colloid present in the facecoat oxide, which in one embodiment may be from about 0.5 hours to about 50 hours, in another embodiment from about 1 hour to about 30 hours, and in yet another embodiment about 2 hours. For example, colloidal silica can form silicates, while colloidal yttria can sinter with yttria particles present in the slurry of the facecoat.
Once firing is complete, the resulting crucible can be suitable for use in melting titanium alloys. While specific characteristics of crucible 8 can be altered or modified depending on the desired use, in one embodiment, crucible 8 can have an overall wall thickness, that includes all facecoat layers, stucco layers and backing layers, of at least about 3 mm, and in another embodiment at least about 6 mm, and in yet another embodiment from about 6.5 mm to about 40 mm. Wall thicknesses of greater than about 40 mm can lead to undesirably long high heating times. Similarly, the thickness ratio of the backing to the facecoat can, in one embodiment, be from about 6.5:1 to about 20:1. As above, thickness ratios greater than about 20:1 can result in undesirably long high heating times due to the thickness of the alumina backing layers.
Regardless of the specific construction, crucible 8 may be used to melt titanium alloys having a low interstitial level and a low ceramic inclusion content. In particular, TiAl can be melted in the crucible described herein using conventional melting and casting techniques known to those skilled in the art. The crucibles described herein are capable of use with such highly reactive alloys because the materials used to make the facecoat are inert to the reactive TiAl. In other words, the facecoat can be exposed to the TiAl during melting without degrading and contaminating the alloy. Moreover, the crucibles herein can be heated rapidly without cracking during any of the melting, pouring, casting and cooling stages of the vacuum induction melting cycle.
The net result of this improved crucible performance is that the crucible is more resistant to thermal stresses and the TiAl melted therein remains more pure and has improved fatigue life. As used herein, “pure” means that the alloy has an oxygen content of less than about 1200 ppm by weight, and includes less than about 500 ppm by weight of yttrium or silicon contaminates generated by the crucible during the melting process. Due to this improved purity, components made from the TiAl exhibit less cracking and fewer imperfections than those made from TiAl using current methods.
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to make and use the invention. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims.

## Claims

1. A method for making a reinforced refractory crucible for melting titanium alloys, the crucible having at least one side region prone to hoop stresses and at least two regions that are separated by the side region and are prone to bending stresses, the method comprising:
forming a crucible mold on a form by:
applying a facecoat to the form;
applying at least one reinforcing element to at least a portion of the crucible mold defined by the facecoat layer, the backing layer, or a combination thereof, the at least one reinforcing element comprising a configuration selected from the group consisting of a continuous fiber, a tape, a mesh, and combinations thereof;
wherein the step of applying the at least one reinforcing element comprises applying a first reinforcing element to a first portion of the crucible mold that corresponds to the side region of the crucible and applying a second reinforcing element to a second portion of the crucible mold that corresponds to at least one of the two regions of the crucible that are separated by the side region, the first reinforcing element comprises a continuous fiber that is wrapped around the first portion of the crucible mold, and the second reinforcing element comprises a mesh that is wrapped around the second portion of the crucible mold;

firing the crucible mold.

2. The method of claim 1 comprising applying a stucco layer to each of the at least one facecoat layer and the at least one backing layer.

3. The method of claim 2 comprising applying the at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, the stucco layer, or combination thereof.

4. The method of claim 3 comprising applying the at least one reinforcing element to the entire facecoat layer, backing layer, stucco layer, or combination thereof.

5. The method of claim 1 wherein the at least one reinforcing element comprises at least one ceramic composition selected from the group consisting of yttria, alumina, sapphire, yttrium aluminum garnet, silicon carbide, silicon, aluminum oxinitride, mullite, zirconia, zircon, zircar, and combinations thereof.

6. The method of claim 1 wherein the at least one reinforcing element comprises at least one metallic composition selected from the group consisting of tungsten, tantalum, molybdenum, niobium, rhenium, alloys thereof, and combinations thereof.

7. The method of claim 1 wherein:
the facecoat has at least one facecoat layer comprising an oxide powder in a colloidal suspension, the oxide powder is selected from the group consisting of scandium oxide, yttrium oxide, hafnium oxide, a lanthanide series oxide, and combinations thereof, and the colloidal suspension is selected from the group consisting of colloidal silica, colloidal yttria, colloidal alumina, colloidal calcium oxide, colloidal magnesium oxide, colloidal lanthanide series oxides, and mixtures thereof; and
the at least one reinforcing element comprises at least one composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof.

8. The method of claim 1 comprising applying the first and second reinforcing elements in a manner selected from the group consisting of an adjacent orientation, a stacked orientation, or combinations thereof.

9. The method of claim 8 comprising applying more than one of the first or second reinforcing element to the first or second portions, respectively, of the crucible mold.

10. A method for making a reinforced refractory crucible for melting titanium alloys, the crucible having at least one side region prone to hoop stresses and base and pour lip regions that are separated by the side region and are prone to bending stresses, the method comprising:
providing a form;
applying a facecoat to the form;
applying a backing about the facecoat, the backing having at least one backing layer;
applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, or a combination thereof, the facecoat, the backing layer and the at least one reinforcing element defining a crucible mold;
removing the form from the crucible mold;
applying a colloidal topcoat to the crucible mold; and
firing the crucible mold;
wherein the at least one reinforcing element comprises a configuration selected from the group consisting of a continuous fiber, a tape, a mesh, and combinations thereof and the step of applying the at least one reinforcing element comprises applying a first reinforcing element to a first portion of the crucible mold that corresponds to the side region of the crucible and applying second reinforcing elements to second portions of the crucible mold that correspond to the base and pour lip regions of the crucible, the first reinforcing element comprises a continuous fiber that is wrapped around the first portion of the crucible mold, and the second reinforcing elements comprise meshes that are wrapped around the second portions of the crucible mold.

11. The method of claim 10 wherein the facecoat has at least one facecoat layer comprising an oxide powder in a colloidal suspension, the oxide powder is selected from the group consisting of scandium oxide, yttrium oxide, hafnium oxide, a lanthanide series oxide, and combinations thereof, and the colloidal suspension is selected from the group consisting of colloidal silica, colloidal yttria, colloidal alumina, colloidal calcium oxide, colloidal magnesium oxide, colloidal lanthanide series oxides, and mixtures thereof.

12. The method of claim 10 wherein the at least one reinforcing element comprises a composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof.

13. The method of claim 10 comprising:
applying a stucco layer to each of the at least one facecoat layer and the at least one backing layer; and
applying the first and second reinforcing elements in a manner selected from the group consisting of an adjacent orientation, a stacked orientation, or a combination thereof.

14. The method of claim 13 comprising applying the at least one reinforcing element to at least a portion of more than one of the facecoat layer, the backing layer, the stucco layer, or combinations thereof.

15. The method of claim 13 comprising applying the at least one reinforcing element to the entire facecoat layer, backing layer, stucco layer, or combination thereof.

16. A method for making a reinforced refractory crucible for melting titanium alloys, the crucible having at least one side region prone to hoop stresses and base and pour lip regions that are separated by the side region and are prone to bending stresses, the method comprising:
providing a form;
applying a facecoat to the form, the facecoat having at least one facecoat layer comprising an oxide powder in a colloidal suspension, the oxide powder selected from the group consisting of scandium oxide, yttrium oxide, hafnium oxide, a lanthanide series oxide, and combinations thereof, and the colloidal suspension selected from the group consisting of colloidal silica, colloidal yttria, colloidal alumina, colloidal calcium oxide, colloidal magnesium oxide, colloidal lanthanide series oxides, and mixtures thereof;
applying a backing about the facecoat to produce a crucible mold, the backing having at least one backing layer;
applying a stucco layer to each of the at least one facecoat layer and the at least one backing layer;
applying at least one reinforcing element to at least a portion of the facecoat layer, the backing layer, the stucco layer, or a combination thereof wherein the at least one reinforcing element comprises a composition selected from the group consisting of ceramic compositions, metallic compositions, and combinations thereof;
removing the form from the crucible mold;
applying a colloidal topcoat to the crucible mold; and
subjecting the crucible mold to a first firing at a temperature of about 800° C. to about 1400° C. followed by a second firing at a temperature of about 1400° C. to about 1800° C. to produce the reinforced crucible for melting titanium alloys;
wherein the at least one reinforcing element comprises a configuration selected from the group consisting of a continuous fiber, a tape, a mesh, a chopped fiber, and combinations thereof and wherein the at least one reinforcing element is tailored to support particular stresses present in the side, base and pour lip regions of the crucible by applying a first reinforcing element of the at least one reinforcing element to a first portion of the crucible mold that corresponds to the side region of the crucible and applying second reinforcing elements of the at least one reinforcing element to second portions of the crucible mold that correspond to the base and pour lip regions of the crucible, the first reinforcing element comprises a continuous fiber that is wrapped around the first portion of the crucible mold, and the second reinforcing elements comprise meshes that are wrapped around the second portions of the crucible mold.

17. The method of claim 16 comprising applying the at least one reinforcing element to the entire facecoat layer, backing layer, stucco layer, or a combination thereof.

18. The method of claim 16 comprising applying the first and second reinforcing elements in a manner selected from the group consisting of an adjacent orientation, a stacked orientation, or a combination thereof.