# Patent

## Title
Electrochemistry of carbon subfluorides

## Abstract

Subfluorinated carbonaceous materials obtained through direct fluorination of graphite or coke particles are provided. One set of subfluorinated carbonaceous materials has an average chemical composition CFx in which 0.63<x≦0.95, 0.66<x≦0.95 or 0.7<x≦0.95. The subfluorinated carbonaceous materials are capable of electrochemical performance superior to commercial CF at relatively high rates of discharge.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation in part of U.S. application Ser. No. 11/422,564, filed Jun. 6, 2006, which claims the benefit of U.S. Provisional Application 60/724,084, filed Oct. 5, 2005 and is a continuation in part of U.S. application Ser. No. 11/253,360 filed Oct. 18, 2005, which also claims the benefit of U.S. Provisional Application 60/724,084, filed Oct. 5, 2005. This application is also a continuation in part of U.S. application Ser. No. 11/675,308 and International Application PCT/US2007/62243, both filed Feb. 15, 2007, both of which claim the benefit of U.S. Provisional Application 60/774,262, filed Feb. 16, 2006, 60/784,957, filed Mar. 21, 2006 and 60/784,960, filed Mar. 20, 2006. This application also claims the benefit of U.S. Provisional Applications No. 60/775,110, filed Feb. 21, 2006, 60/775,559, filed Feb. 22, 2006, and the United States Provisional Application entitled “Coke Based Subfluorinated Carbon Fluorides (CFx) Cathodes in Lithium Batteries”, to Yazami et al. filed Feb. 9, 2007. Each of these applications is incorporated by reference in its entirety to the extent not inconsistent with the disclosure herein.


BACKGROUND OF INVENTION
This invention is in the field of fluorinated carbon materials, in particular subfluorinated graphite and coke particles.
Fluorinated carbons are used commercially as a positive electrode material in primary lithium batteries. Fluorination of graphite allows intercalation of fluorine between the carbon layers. Li/CFx battery systems are known to be capable of delivery of up to 700 Wh/kg, 1000 Wh/l, at room temperature, and at a rate of C/100 (i.e., a battery current of a 1/100th that of the capacity of the battery per hour). (See, e.g., Bruce, G. Development of a CFx D Cell for Man Portable Applications. in Joint Service Power Expo. 2005; and Gabano, J. P., ed. Lithium Batteries, by M. Fukuda & T. Iijima. 1983, Academic Press: New York). Cathodes in these systems typically have carbon-fluoride stoichiometries typically ranging from CF1.05 to CF1.1. This cathode material, however, is known to be discharge rate limited, and currents lower than C/50 (battery current 1/50th that of the capacity of the battery divided by 1 hour) are often necessary to avoid cell polarization and large capacity loss. High electronic resistivity up to 1015 Ohm·cm of CFx is a potential cause of the observed discharge rate limitations, as there is a strong correlation between cathode thickness and performance; thicker cathodes tend to be more rate-limited. (See, e.g., V. N. Mittkin, J. Structural Chemistry, 2003, Vol. 44, 82-115, translated from Zhurnal Structunoi Khimii, 2003, Vol. 44, 99-138).
Other industrial applications of fluorinated carbons include use as solid lubricants or as reservoirs for very active molecular oxidizers such as BrF3 and ClF3.
In a lithium/CFx cell, the cell overall discharge reaction, first postulated by Wittingham (1975) Electrochem. Soc. 122:526, can be schematized by equation (1):

(CFx)n+xnLinC+nxLiF  (1)

Thus, the theoretical specific discharge capacity Qth, expressed in mAh·g−1, is given by equation (2):




  
    
      
        
          
            Q
            th
          
          ⁡
          
            (
            x
            )
          
        
        =
        
          
            x
            ⁢
            
              
            
            ⁢
            F
          
          
            3.6
            ⁢
            
              (
              
                12
                +
                
                  19
                  ⁢
                  x
                
              
              )
            
          
        
      
    
    
      
        (
        2
        )
      
    
  




where F is the Faraday constant and 3.6 is a unit conversion constant.

The theoretical capacity of (CFx)n materials with different stoichiometry is therefore as follows:
x=0.25, Qth=400 mAh·g−1; x=0.33, Qth=484 mAh·g−1; x=0.50, Qth=623 mAh·g−1; x=0.66, Qth=721 mAh·g−1; and x=1.00, Qth=865 mAh·g−1.
The reactivity of carbon allotropic forms with fluorine gas differs largely owing either to the degree of graphitization or to the type of the carbon material (Hamwi A. et al.; J. Phys. Chem. Solids, 1996, 57(6-8), 677-688). In general, the higher the graphitization degree, the higher the reaction temperature. Carbon fluorides have been obtained by direct fluorination in the presence of fluorine or mixtures of fluorine and an inert gas. When graphite is used as the starting material, no significant fluorination is observed below 300° C. From 350 to 640° C., two graphite fluorides, mainly differing in crystal structure and composition are formed: poly(dicarbon monofluoride) (C2F)n and poly(carbon monofluoride) (CF)n (Nakajima T.; Watanabe N. Graphite fluorides and Carbon-Fluorine compounds, 1991, CRC Press, Boston; Kita Y.; Watanabe N.; Fujii Y.; J. Am. Chem. Soc., 1979, 101, 3832). In both compounds the carbon atoms take the sp3 hybridization with associated distortion of the carbon hexagons from planar to ‘chair-like’ or ‘boat-like’ configuration. Poly(dicarbon monofluoride) is obtained at  ̃350° C. and has a characteristic structure, where two adjacent fluorine layers are separated by two carbon layers bonded by strongly covalent C—C bonding along the c-axis of the hexagonal lattice (stage 2). On the other hand, poly(carbon monofluoride) which is achieved at  ̃600° C. has a structure with only one carbon layer between two adjacent fluorine layers (stage 1). Graphite fluorides obtained between 350 and 600° C. have an intermediary composition between (C2F)n and (CF)n and consist of a mixture of these two phases (Kita, 1979, ibid.). The stage s denotes the number of layers of carbon separating two successive layers of fluorine. Thus a compound of stage 1 has a sequence of stacking of the layers as FCF/FCF . . . , and a compound of stage 2 has the sequence FCCF/FCCF . . . . Both poly(dicarbon monofluoride) and poly(carbon monofluoride) are known to have relatively poor electrical conductivity.
U.S. Pat. No. 3,536,532 to Watanabe et al. describes a primary cell including a positive electrode having as the principal active material a crystalline fluorinated carbon represented by the formula (CFx)n. where x is not smaller than 0.5 but not larger than 1. As described, the carbon is fluorinated by heating the reactor to the desired temperature then introducing fluorine. U.S. Pat. No. 3,700,502 to Watanabe et al. describes a battery including a positive electrode having as its active material an amorphous or partially amorphous solid fluoridated carbon represented by the Formula (CFx)n, wherein x is in the range of from greater than 0 to 1. U.S. Pat. No. 4,247,608 to Watanabe et al. describes an electrolytic cell including a positive electrode having as the main active material a poly-dicarbon monofluoride represented by the formula (C2F)n wherein n is an integer.
Lam and Yazami (Lam, P. et al., 2006, J. Power Sources, 153, 354-359) present results for sub-fluorinated graphite fluorides (CFx)n where 0.33<x<0.63.
Carbon-fluorine intercalation compounds have been also obtained by incorporating other compounds capable of acting as a fluorination catalyst, such as HF or other fluorides, into the gas mixture. These methods can allow fluorination at lower temperatures. These methods have also allowed intercalation compounds other than (C2F)n and (CF)n to be prepared (N. Watanabe et al., “Graphite Fluorides”, Elsevier, Amsterdam, 1988, pp 240-246). These intercalation compounds prepared in the presence of HF or of a metal fluoride have an ionic character when the fluorine content is very low (F/C<0.1), or an iono-covalent character for higher fluorine contents (0.2<F/C<0.5). In any case, the bonding energy measured by Electron Spectroscopy for Chemical Analysis (ESCA) gives a value less than 687 eV for the most important peak of the F1s line and a value less than 285 eV for that of the C1s line (T. Nakajima, Fluorine-carbon and Fluoride-carbon, Chemistry, Physics and Applications, Marcel Dekker 1995 p. 13).
SUMMARY OF THE INVENTION
The invention provides subfluorinated graphite and coke materials which can provide enhanced cathode performance at high discharge rates compared to conventional CF1 positive electrode active materials. These fluorinated materials are suitable for use in electrochemical devices such as primary batteries and secondary batteries. In particular, use of subfluorinated graphite and coke in lithium batteries can provide good battery performance at high discharge rates.
The subfluorinated carbonaceous materials of the invention are multicomponent materials having a fluorinated carbonaceous component and an unfluorinated carbonaceous component and/or a “lightly fluorinated” carbonaceous component in which fluorine is not strongly bound to carbon. The presence of an unfluorinated and/or a “lightly fluorinated” carbonaceous component can provide higher electrical conductivity than would be obtained for a material consisting solely of the fluorinated phases poly(dicarbon monofluoride), poly(carbon monofluoride) and combinations thereof.
In an embodiment, the subfluorinated graphite materials produced by the methods of the invention retain a greater amount of unfluorinated carbon, “lightly fluorinated” carbon, or a combinations thereof than materials of the same average F/C ratio produced with other types of fluorination processes known to the art. In an embodiment, the methods of the invention allow production of subfluorinated graphite materials having a fluorine to carbon ratio greater than 0.63 and less than or equal to 0.95.
In an embodiment, the invention provides a method for making a subfluorinated carbonaceous material, the method comprising the steps of:

    
    
        a. providing a carbonaceous material selected from graphite particles or coke particles;
        b. exposing the carbonaceous material to a flowing gaseous source of elemental fluorine;
        c. heating the carbonacous material to a selected reaction temperature, the selected temperature being between 330° C. and 600° C. for graphite particles and 300° C. and 500° C. for coke particles;
        d. maintaining the carbonaceous material at the selected temperature for sufficient time to obtain a subfluorinated carbonaceous material.

The methods of the invention are capable of producing subfluorinated graphite materials having the average chemical composition CFx wherein 0.33≦x≦0.95 and subfluorinated coke materials having the average chemical composition CFx wherein 0.18≦x≦0.95. In different embodiments, the subfluorinated material has an average chemical composition CFx in which 0.63<x≦0.95, 066≦x≦0.95, 0.7≦x≦0.95; or 0.7≦x≦0.9. In different embodiments, the amount of unfluorinated and “lightly fluorinated” carbon in the subfluorinated material is between 5% and 40%, between 5% and 37%, between 5% and 25%, between 10% and 20%, or about 15%.

    
    


In another embodiment, the invention provides a subfluorinated carbonaceous material made by the process of:

    
    
        a. providing a carbonaceous material selected from graphite particles and coke particles;
        b. exposing the carbonaceous material to a flowing gaseous source of elemental fluorine;
        c. heating the carbonaceous material to a selected reaction temperature, the selected temperature being between 330° C. and 600° C. for graphite particles and 300° C. and 500° C. for coke particles; and
        d. maintaining the carbon material at the selected temperature for sufficient time to obtain a subfluorinated carbonaceous material having an average chemical composition CFx where 0.63<x≦0.95.
    
    


The invention also provides subfluorinated graphite materials having an average chemical composition CFx in which 0.63<x≦0.95, wherein 13C nuclear magnetic resonance spectroscopy analysis of the subfluorinated graphite provides a spectrum comprising at least one chemical shift peak centered between approximately 100 and 150 ppm relative to TetraMethylSilane (TMS) and another chemical shift peak centered at approximately 84-88 ppm relative to TMS.
Furthermore, the invention also provides a subfluorinated coke material prepared by direct fluorination of coke having a coherence length Lc between 5 nm and 20 nm, the subfluorinated coke material having an average chemical composition CFx in which 0.63<x≦0.95. 13C nuclear magnetic resonance spectroscopy analysis of the subfluorinated coke provides a spectrum comprising at least one chemical shift peak centered between approximately 100 and 150 ppm relative to TetraMethylSilane (TMS) and another chemical shift peak centered at approximately 84-88 ppm relative to TMS.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows X-ray diffraction spectra for subfluorinated graphite materials with a range of F/C ratios.
FIG. 2. X-ray diffraction spectrum for a subfluorinated graphite material with an F/C ratio of 0.9. The labels above the peaks are the calculated d-spacings.
FIG. 3: 13C Magic Angle Spinning (MAS) Nuclear Magnetic Resonance (NMR) spectra for several subfluorinated graphite materials. (10 kHz)
FIG. 4: 13C NMR spectrum for a subfluorinated graphite material having an F/C ratio of 0.77.
FIG. 5: Plot of % Cgraphitic and % Csp3 versus the F/C ratio for several subfluorinated graphites synthesized at 390° C.
FIG. 6: Ragone plot for several subfluorinated graphites versus CF1.
FIG. 7. Discharge curve for subfluorinated graphite CF0.9.
FIG. 8: Discharge curve for subfluorinated graphite CF0.77.
FIG. 9: Discharge curve for subfluorinated graphite CF0.744.
FIG. 10: Discharge curve for subfluorinated graphite CF0.647.
FIG. 11: X-ray diffraction spectrum for a subfluorinated coke material with an F/C ratio of 0.36.
FIG. 12. X-ray diffraction spectrum for a subfluorinated coke material with an F/C ratio of 0.64.
FIG. 13. X-ray diffraction spectrum for a subfluorinated coke material with an F/C ratio of 0.86.
FIG. 14. X-ray diffraction spectrum for a subfluorinated coke material with an F/C ratio of 0.95.
FIG. 15: 13C Magic Angle Spinning (MAS) Nuclear Magnetic Resonance (NMR) spectra for several subfluorinated coke materials. (10 kHz)
FIG. 16: 13C NMR spectrum for a subfluorinated coke material having an F/C ratio of 0.73.
FIG. 17: Ragone plot for several subfluorinated coke materials versus CF1.
FIG. 18: Discharge curves for subfluorinated coke material CF0.97.
FIG. 19: Discharge curves for subfluorinated coke material CF0.87.
FIG. 20: Discharge curves for subfluorinated coke material CF0.63.



DETAILED DESCRIPTION OF THE INVENTION
In an embodiment, the invention provides subfluorinated carbonaceous materials obtained through direct fluorination of graphite or coke particles. Subfluorinated carbonaceous materials obtained through fluorination of graphite particles may also be referred to as subfluorinated graphites or subfluorinated graphite materials herein. Similarly, subfluorinated carbonaceous materials obtained through fluorination of coke particles may also be referred to as subfluorinated cokes or subfluorinated coke materials herein.
Coke is a carbonaceous material which is typically formed from petroleum or coal pitch. As is known in the art, the structure of coke materials depends on the heat treatment temperature of the material. In the temperature range above about 2100° C., coke converts to crystalline graphite. At lower temperatures, between about 1500° C. and about 2100° C., the carbon layers are disordered, with turbostratic stacking defects. At even lower temperatures, between about 700° C. and 1500° C., the structure can be described as having bent columns. The structure may be characterized by the coherence length Lc, which relates to the crystallite dimension in the c-direction and can be determined from X-ray diffraction analysis. The parameter La, which relates to the crystallite dimension in the a-direction, can be determined by Raman spectroscopy. Determination of these parameters is known to those skilled in the art. In an embodiment, coke suitable for use with the present invention has a coherence length Lc along the c-axis perpendicular to the carbon layers greater than about 5 nm and less than about 20 nm.
As used herein, the expression “subfluorinated carbonaceous material” refers to a multicomponent carbonaceous material having a fluorinated carbonaceous component in which at least some of the carbon is strongly bound to fluorine and an unfluorinated carbonaceous component and/or a “lightly fluorinated” carbonaceous component in which fluorine is not strongly bound to carbon. Multiphase subfluorinated carbonaceous materials may comprise a mixture of carbonaceous phases including, an unfluorinated carbonaceous phase (e.g., graphite or coke), a “lightly fluorinated” phase and one or more fluorinated phases (e.g., poly(carbon monofluoride (CF1); poly(dicarbon monofluoride) etc.). Subfluorinated carbonaceous materials include carbonaceous materials exposed to a fluorine source under conditions resulting in incomplete or partial fluorination of a carbonaceous starting material. Partially fluorinated carbon materials include materials in which primarily the exterior portion has reacted with fluorine while the interior region remains largely unreacted.
As used herein, fluorination of a material involves introduction of fluorine into the material. In the present invention, fluorination will typically involve formation of bonds between carbon and fluorine. As is known in the art, fluorine is capable of forming both ionic and covalent bonds with carbon. In some cases, C—F bonds have also been classified as intermediate in strength between ionic and covalent bonds (e.g. partially ionic, semi-ionic, semi-covalent). The fluorination method can influence the type of bonding present in the fluorination product.
In the present invention, the fluorinated carbon materials are produced by direct fluorination. In direct fluorination, at least some of the C—F bonds formed tend to be of higher energy and have a stronger, more covalent character than the C—F bonds obtained through low temperature fluorine intercalation. Fluorine-graphite intercalation compounds are expected to have carbon-fluorine bonding varying between the ionic and the semi-covalent depending on the fluorine content (Matsuo, Y. et al, 1995 Z. Anorg. Allg. Chemie, 621, 1943-1950). For example, Matsuo et al. (1995) classify XPS F1s spectral peaks at 687 eV, 685 eV and 683 eV, respectively, as semi-covalent, nearly ionic, and ionic. In contrast, the F1s peak in covalently bonded graphite fluoride is at 689.3-689.6 eV (Watanabe 1988 ibid.).
In one aspect of the invention, at least some of the carbon in the fluorination product is strongly bound to fluorine (covalently bound or nearly covalently bound to fluorine).
As used herein, a carbon-fluorine bond in the fluorination product is classified as nearly covalent if the bond has an energy greater than the energy of “semi-ionic” or “semi-covalent” carbon-fluorine bonds in graphite intercalation compounds of fluorine obtained through low temperature fluorination of graphite, but less than the typical energy of covalent carbon-fluorine bonds in poly(dicarbon monofluoride) (C2F)n or poly(carbon monofluoride) (CF)n.
In another aspect of the invention, the subfluorinated carbonaceous material comprises a “lightly fluorinated” carbonaceous component in which fluorine is not strongly bound to carbon. The F—C bond energy in such a carbonaceous component is less than that of a covalent or nearly covalent F—C bond.
The nature of the C—F bonding in the fluorination product may be determined by suitable analysis techniques. Such techniques are known to those of ordinary skill in the art, and include, but are not limited to, Fourier Transform Infrared Spectroscopy (FT-IR), Nuclear Magnetic Resonance Spectroscopy (NMR), X-Ray Photoelectron Spectroscopy (XPS) or Electron Spectroscopy for Chemical Analysis (ESCA). The extent of covalency in the C—F bonds can be assessed by comparison of the analysis results for the fluorination product to those obtained for a “standard” commonly accepted to have covalent C—F bonds. A match (within experimental error) between the analysis results for the fluorination product and those of the “standard” may be taken to indicate covalent bonding. The graphite fluorides poly(dicarbon monofluoride) (C2F)n and poly(carbon monofluoride) (CF)n are commonly accepted to have covalent C—F bonds.
As is known to the art, solid state 19F-NMR spectra having a chemical shift peak centered at about −190 ppm/CFCl3 indicate fluorine atoms covalently bonded to carbon atoms. As another example, solid state 13C-NMR spectra having a resonance present at a chemical shift of 84-88 ppm/TMS indicate carbon atoms covalently bound to fluorine atoms (Giraudet J.; Dubois M.; Guérin K.; Hamwi A.; Masin F.; J. Phys. Chem. Solids 2006, 67(5-6), 1100). Fourier Transform Infrared Spectroscopy (FT-IR) spectra showing vibration bands centered at about 1215 cm−1 are also indicative of covalent C—F bonds. In an embodiment, 13C-NMR analysis of the subfluorinated materials of the invention gives a spectrum which comprises a chemical shift peak centered at approximately 84-88 ppm relative to TMS, indicating carbon atoms strongly bound to fluorine atoms.
As is known to the art, solid state 13C-NMR spectra having a resonance present at a chemical shift of about 42 ppm/TMS indicate carbon atoms covalently bound to carbon atoms (sp3 hybridization) (Giraudet, 2006, ibid.). In an embodiment, 13C-NMR analysis of the subfluorinated graphite materials of the invention gives a spectrum which comprises a chemical shift peak centered at approximately 42 ppm relative to TMS, indicating carbon atoms strongly bound to other carbon atoms.
Solid state 13C-NMR spectra of fluorinated graphite material having a resonance present at a chemical shift of about 136 ppm/TMS has been interpreted as indicating “graphitic” sp2-type carbon atoms which are either non-fluorinated or in a low interaction with fluorine (Giraudet, 2006 ibid.). In addition, solid state 13C-NMR spectra of graphite material can display a resonance present at a chemical shift of about 119 ppm/TMS (Giraudet, 2006 ibid.). In an embodiment, 13C nuclear magnetic resonance spectroscopy analysis of the subfluorinated carbonaceous materials of the invention provides a spectrum comprising at least one chemical shift peak centered between approximately 120 and 140 ppm relative to TMS, indicating “graphitic” carbon either not bonded or only weakly bonded to fluorine. In one embodiment, an XRD spectrum of the subfluorinated graphite or coke comprises a substantial peak at 2θ approximately in the range 25.5-26.4 degrees, using Cu Kα radiation, corresponding to the graphite or coke (002) peaks. In another embodiment, an XRD spectrum of the subfluorinated graphite does not comprise a substantial peak at 2θ approximately in the range 26.3-26.4 degrees, using Cu Kα radiation.
The relative amount of graphitic carbon atoms (nonfluorinated and “lightly fluorinated” carbon) can be estimated through comparison of the areas of chemical shift peaks in a 13C-NMR spectra. In particular, the sum of the area of the peaks corresponding to nonfluorinated and “lightly” fluorinated carbon is divided by the sum of these peaks with the peak corresponding to carbon in strong interaction with fluorine and (if present) the peak corresponding to a strong carbon-carbon interaction. Additional peaks may be included in the denominator, as explained in Example 5, which relates to subfluorinated coke materials. If any peak is not clearly seen in the spectrum, it not included in the sum.
The average ratio of fluorine to carbon (F/C) may be used as a measure of the extent of fluorination. This average ratio may be determined through weight uptake measurements or through quantitative NMR measurements. When fluorine is not uniformly distributed through the wall thickness of the carbon material, this average ratio may differ from surface fluorine to carbon ratios as may be obtained through x-ray photoelectron spectroscopy (XPS) or ESCA.
Without wishing to be bound by any particular belief, fluorination of graphite and heat treated coke at relatively low temperatures is believed to result primarily in fluorination of the surface of the carbon material. The remainder of the carbon material remains unfluorinated. This surface fluorination may include formation of groups such as CF2, and CF3.
At higher temperatures, fluorination is believed to proceed past the surface of the material. In an embodiment, the fluorinated graphite product has some crystallographic similarities to a mixture of graphite fluorides (C2F)n and (CF)n. The average interlayer spacing may be intermediate between that of graphite poly(dicarbon monofluoride) and that of graphite poly(carbon monofluoride). In another embodiment, the fluorinated coke product has some crystallographic similarities to (CF)n.
In an embodiment, the subfluorinated carbonaceous material comprises a plurality of nanostructured particles; wherein each of the nanostructured particles comprise a plurality of fluorinated domains and a plurality of unfluorinated or “lightly” fluorinated domains. In the context of this description a “domain” is a structural component of a material having a characteristic composition (e.g., unfluorinated or fluorinated), phase (e.g., amorphous, crystalline, C2F, CF1, graphite, coke.), and/or morphology. Useful subfluorinated carbonaceous materials for positive electrode active materials comprise a plurality of different domains. Individual fluorinated, “lightly fluorinated” and unfluorinated domains preferably for some applications have at least one physical dimension (e.g., lengths, depths, cross sectional dimensions etc.) less than about 50 nanometers, and more preferably for some applications at least one physical dimension less than about 10 nanometers. Positive electrode active materials particularly useful for electrochemical cells providing high performance at low temperatures include nanostructured particles having fluorinated domains and unfluorinated or “lightly” fluorinated domains that are distributed throughout each nanostructured particle of the active material, and in some embodiments substantially uniformly distributed throughout each nanostructured particle of the active material. In some embodiments, fluorinated domains of particles of the positive electrode active material comprise a subfluorinated carbonaceous material having an average stoichiometry CFy, wherein y is the average atomic ratio of fluorine atoms to carbon atoms and is selected from the range of about 0.8 to about 1.0, and the unfluorinated domains of the particles of the positive electrode active material comprise a unfluorinated carbonaceous phase, such as graphite or coke.
The term “nanostructured” refers materials and/or structures have a plurality of discrete structural domains with at least one physical dimension (e.g., height, width, length, cross sectional dimension) that is less than about 1 micron. In this context, structural domains refer to features, components or portions of a material or structure having a characteristic composition, morphology and/or phase. Nanostructured materials useful as positive electrode active materials, particularly under high discharge rates and/or at low temperatures, include nanostructured composite particles having a plurality of fluorinated carbon domains and unfluorinated or “lightly fluorinated” carbon domains. In some embodiments, nanostructured materials of the present invention comprise a plurality of structural domains having different compositions, morphologies and/or phase intermixed on a very fine scale (e.g., at least smaller than 10's of nanometers).
Use of nanostructured subfluorinated carbonaceous particles as positive electrode active materials provides a number of benefits in electrochemical cells of the present invention. First, nanoscale intermixing of fluorinated and unfluorinated or “lightly” fluorinated domains in these particles results in high interfacial surface areas between the fluorinated and unfluorinated domains. This attribute provides good electronic and interface properties between these domains facilitating electron transfer, particularly at low temperatures. In addition, the presence of an appreciable unfluorinated or “lightly” fluorinated component in these particles enhances net electrode conductivity by providing nanoscale electrically conducting pathways in the electrode active material. Further, the distribution of nanoscale fluorinated domains in these materials provides an appreciable density of fluorinated domains having high fluorine ion loading exposed to the electrolyte, thereby resulting in a high interfacial surface area of fluorinated structural domains exposed to the electrolyte further enhancing the kinetics at the positive electrode.
Subfluorinated carbonaceous particles comprising positive electrode active materials in the present invention may have a wide range of physical dimensions, for example cross sectional dimensions ranging from about 100 nanometers to about 200 microns and lateral dimensions range from about 100 nanometers to about 500 microns. Optionally, carbonaceous particles useful in positive electrodes of the present electrochemical cells are porous. Optionally, carbonaceous particles useful in positive electrodes of the present electrochemical cells have large aspect ratios (Aspect ratio=(longitudinal physical dimensions (e.g., length)/(cross sectional physical dimension (e.g., diameter)), for example aspect ratios selected from the range of about 50 to about 1000. In some embodiments, carbonaceous particles useful in positive electrodes of the present electrochemical cells have a flake shapes and/or have a morphologies similar to unfluorinated graphite particles.
The fluorinated carbonaceous materials of the invention are prepared using a direct fluorination method, in which the graphite or coke particles are contacted with a gaseous source of elemental fluorine. The fluorination conditions (including mass of carbonaceous material, reaction temperature, reaction time, and fluorine flow rate) are selected to obtain the desired degree of fluorination of the carbon materials.
In an embodiment, the graphite or coke powder is uniformly spread on a nickel boat and introduced into a reactor. The reactor may be made of nickel, and have a horizontal setting. The reactor may be vacuum degassed prior to starting flow of fluorine gas. The reaction proceeds under fluorine dynamic flow (open reactor). (It is believed that if the reactor is closed (static reactor), the fluorination reaction becomes much slower.). The reactor is then heated. The reaction time is counted after the reactor reached the target temperature until the reactor heating is stopped. After the reactor cools down to the ambient temperature, excess (unreacted) fluorine may be evacuated under nitrogen flow until no trace of free fluorine is in the reactor.
In an embodiment, the reactor is heated at the rate between 0.5 degrees Celsius/minute and 5 degrees Celsius/minute. In an embodiment, the reactor is heated at the rate of 1 degrees Celsius/minute.
In different embodiments, the fluorination temperature for graphite particles may be between 330° C. and 600° C., between 375° C. and 550° C., or between 390° C. and 490° C. Weight loss due to volatile carbon-fluorine compounds is expected to occur at about 550° C.
In different embodiments, the fluorination temperature for coke particles may be between 300° C. and 550° C., between 350° C. and 450° C., or between 370° C. and 425° C. Weight loss due to volatile carbon-fluorine compounds is expected to occur at about 450° C.
In different embodiments, the time period is greater than 2 hours, between 2 and 40 hours, between 3 and 30 hours, between 4 and 20 hours, between 4 and 16 hours, between 4 and 12 hours, between 8 and 20 hours, between 8 and 16 hours, between 8 and 12 hours, or about 16 hours.
In an embodiment, the fluorination is conducted at atmospheric pressure with a gas mixture essentially consisting of F2 and inert gas. The percentage of fluorine in the mixture may be between 5% and 100%, between 10% and 90%, between 20% and 80%, between 20% and 60%, between 20% and 50% or about 20%.
In an embodiment suitable for masses of coke up to about 5 g and masses of graphite up to about 40 g, the fluorine flow rate is between 0.5 and 2.0 g/fluorine per hour.
In different embodiments, the average particle size of the carbonaceous material is 2-200 microns, 5-50 microns, or 5-20 microns.
In other embodiments, the fluorination may be conducted at a pressure less than atmospheric pressure. In an embodiment, the fluorination may be conducted at pressures between 1 atm and 0.1 atm, or between 1 atm and 0.25 atm.
A suitable gaseous source of elemental fluorine will be known to one of ordinary skill in the art; an exemplary such source is a mixture F2 and a sufficiently inert gas. Suitable inert gases include, but are not limited to nitrogen, and argon. Preferably, only trace amounts of HF or other fluorides known to be fluorine intercalation catalysts are present in the gas mixture.
The subfluorinated carbonaceous material of the invention can be heat treated following fluorination.
The term “electrochemical cell” refers to devices and/or device components that convert chemical energy into electrical energy or electrical energy into chemical energy. Electrochemical cells typically have two or more electrodes (e.g., positive and negative electrodes) wherein electrode reactions occurring at the electrode surfaces result in charge transfer processes. Electrochemical cells include, but are not limited to, primary batteries, secondary batteries, lithium batteries and lithium ion batteries. General cell and/or battery construction is known in the art, see e.g., U.S. Pat. Nos. 6,489,055, 4,052,539, 6,306,540, Seel and Dahn J. Electrochem. Soc. 147(3) 892-898 (2000).
The term “capacity” is a characteristic of an electrochemical cell that refers to the total amount of electrical charge an electrochemical cell, such as a battery, is able to hold. Capacity is typically expressed in units of ampere-hours. The term “specific capacity” refers to the capacity output of an electrochemical cell, such as a battery, per unit weight. Specific capacity is typically expressed in units of ampere-hours kg−1. The theoretical specific capacity is referred to as Qth.
The term “discharge rate” refers to the current at which an electrochemical cell is discharged. Discharge current can be expressed in units of amperes. Alternatively, discharge current can be expressed “C/n” rate, where n is the number of hours theoretically needed to fully discharge the cell. For example, under C/5 rate and 3 C rate, the full discharge is expected to be reached in 5 hours and 20 minutes, respectively. Under a constant discharge current of intensity Ix, the theoretical discharge time td is given by Qth(x)=Ixtd. Ix is the discharge current intensity in units of current per unit weight (e.g. mA/g).
“Current density” refers to the current flowing per unit electrode area.
“Active material” refers to the material in an electrode that takes part in electrochemical reactions which store and/or deliver energy in an electrochemical cell. The present invention provides electrochemical cells having a positive electrode with a subfluorinated carbonaceous active material.
“Room temperature” refers to a temperature selected over the range of about 293 to 303 degrees Kelvin.
In the electrochemical devices of the invention, the subfluorinated carbonaceous materials are normally present in a composition that also includes a conductive diluent such as may be selected from, for example, acetylene black, carbon black, powdered graphite, cokes, carbon fibers, carbon nanotubes and metallic powders such as powdered nickel, aluminum, titanium, and stainless steel. The conductive diluent improves conductivity of the composition and is typically present in an amount representing about 1 wt. % to about 10 wt. % of the composition, preferably about 3 wt. % to about 8 wt. % of the composition. The composition containing the subfluorinated carbonaceous materials and the conductive diluent also, typically, contains a polymeric binder, with preferred polymeric binders being at least partially fluorinated. Exemplary binders thus include, without limitation, poly(ethylene oxide) (PEO), poly(vinylidene fluoride) (PVDF), a poly(acrylonitrile) (PAN), poly(tetrafluoroethylene) (PTFE), and poly(ethylene-co-tetrafluoroethylene) (PETFE). The binders, if present, represent about 5 wt. % to about 15 wt. % of the composition, while the subfluorinated carbonaceous material represent about 70 wt. % to about 90 wt. % of the composition, preferably about 75 wt. % to 85 wt. % of the composition.
The resulting subfluorinated carbonaceous material is then admixed with a conductive diluent and binder as described above, with the preferred weight ratios being about 70 wt/% to about 90 wt. %, more preferably about 75 wt. % to about 85 wt. % of subfluorinated carbonaceous material; about 1 wt. % to about 10 wt. %, preferably about 3 wt. % to about 8 wt. %, conductive diluent; and about 5 wt. % to about 15 wt. % binder.
Typically, the slurry formed upon admixture of the foregoing components is then deposited or otherwise provided on a conductive substrate to form the electrode. A particularly preferred conductive substrate is aluminum, although a number of other conductive substrates can also be used, e.g., stainless steel, titanium, platinum, gold, and the like. If the subfluorinated particles are elongated, they may be at least partially aligned during the deposition process. For example, shear alignment may be used to align the subfluorinated particles.
In still a further aspect of the invention, a method is provided for preparing an electrode for use in an electrochemical device, comprising the following steps:
preparing a subfluorinated carbonaceous material according to the methods of the invention;
mixing the subfluorinated material with a conductive diluent and a binder to form a slurry; and
applying the slurry to a conductive substrate.
In an embodiment, the invention provides an electrochemical device comprising a first electrode and a second electrode, and an ion transporting material disposed therebetween, wherein the first electrode comprises a subfluorinated carbonaceous material according to the present invention.
In a primary lithium battery, for example, the aforementioned electrode serves as the cathode, with the anode providing a source of lithium ions, wherein the ion-transporting material is typically a microporous or nonwoven material saturated with a nonaqueous electrolyte. The anode may comprise, for example, a foil or film of lithium or of a metallic alloy of lithium (LiAl, for example), or of carbon-lithium, with a foil of lithium metal preferred. The ion-transporting material comprises a conventional “separator” material having low electrical resistance and exhibiting high strength, good chemical and physical stability, and overall uniform properties. Preferred separators herein, as noted above, are microporous and nonwoven materials, e.g., nonwoven polyolefins such as nonwoven polyethylene and/or nonwoven polypropylene, and microporous polyolefin films such as microporous polyethylene. An exemplary microporous polyethylene material is that obtained under the name Celgard® (e.g., Celgard® 2400, 2500, and 2502) from Hoechst Celanese. The electrolyte is necessarily nonaqueous, as lithium is reactive in aqueous media. Suitable nonaqueous electrolytes are composed of lithium salts dissolved in an aprotic organic solvent such as propylene carbonate (PC), ethylene carbonate (EC), ethyl methyl carbonate (EMC), dimethyl ether (DME), and mixtures thereof. Mixtures of PC and DME are common, typically in a weight ratio of about 1:3 to about 2:1. Suitable lithium salts for this purpose include, without limitation, LiBF4, LiPF6, LiCF3SO3, LiClO4, LiAlCl4, and the like. It will be appreciated that, in use, a change in voltage causes generation of lithium ions at the anode and migration of the ions through the electrolyte-soaked separator to the subfluorinated carbonaceous material of the cathode, “discharging” the battery.
In an embodiment, the invention provides an electrochemical device wherein the device is a primary lithium battery in which the first electrode acts at the cathode, the second electrode acts at the anode and comprises a source of lithium ions, and the ion-transporting material physically separates the first and the second electrode and prevents direct electrical contact therebetween.
In another embodiment, the subfluorinated carbonaceous material is utilized in a secondary battery, i.e., a rechargeable battery such as a rechargeable lithium battery. In such a case, the cations, e.g., lithium ions, are transported through a solid or a gelled polymer electrolyte—which also serves as a physical separator—to the subfluorinated electrode, where they are intercalated and de-intercalated by the subfluorinated material. Examples of solid polymer electrolytes include chemically inert polyethers, e.g., poly(ethylene oxide) (PEO), poly(propylene oxide) (PPO), and other polyethers, wherein the polymeric material is impregnated or otherwise associated with a salt, e.g., a lithium salt such as those set forth in the preceding paragraph. Examples of gelled polymer electrolytes include polyvinylene difluoride (PVDF) homo- or co-polymer impregnated or otherwise associated with a non-aqueous electrolyte such as those set forth in the preceding paragraph.
In another embodiment, the invention provides an electrochemical device, wherein the device is a secondary battery in which the second electrode comprises a source of ions of a metal selected from Groups 1, 2, and 3 of the Periodic Table of Elements and the ion-transporting material comprises a solid polymer electrolyte that permits transport of said metal cations and physically separates the first and second electrodes.
In still a further aspect of the invention, a rechargeable battery is provided that includes:
a first electrode comprising a subfluorinated carbonaceous material, the electrode capable of receiving and releasing cations of a metal selected from Groups 1, 2, and 3 of the Periodic Table of the Elements;
a second electrode comprising a source of the metal cations; and
a solid or a gelled polymer electrolyte that permits transport of the metal cations and physically separates the first and second electrodes.
Exemplary discharge profiles of Li/subfluorinated graphite cells are shown in FIGS. 7-10 and exemplary profiles of Li/subfluorinated coke cells are shown in FIGS. 18-20. These cells exhibit a characteristic plateau corresponding to the formation of LiF according to Equation 1. The value of the plateau voltage depends upon the discharge rate. The discharge profiles of these cells differ depending on the fluorine to carbon ratio of the subfluorinated material. In general, the higher F/C, the higher the discharge capacity, as indicated by Equation 2.
Subfluorinated carbonaceous materials can show reduced over-potential for low discharge times as compared to fully fluorinated materials. This is related to the decrease of electrical conductivity of the sample when the fluorinated parts progress i.e. the decrease of pristine carbon amount in the sample.
In addition, cells including Li and subfluorinated carbonaceous material can display improved performance as compared to commercial Li/CF cells at higher discharge rates (e.g. at or above 1 C) and higher power densities. The latter can be seen by referring to a Ragone plot of energy density (Wh/kg) versus the square root of power density. As seen in FIGS. 6 and 17, both subfluorinated graphites and subfluorinated cokes can outperform CF1 at higher power densities.
In an embodiment, once the electrochemical cell is assembled, it may be “pre-discharged” before being put into actual use. The pre-discharge step involves discharging from 1%-5% of the capacity of the cell. Pre-discharge of the cell can eliminate the initial voltage delay before establishment of the voltage plateau which is seen in the characteristic discharge profile of a Li/subfluorinated carbonaceous material cells.
In the following examples, efforts have been made to ensure accuracy with respect to numbers used (e.g., amounts, temperature, etc.) but some experimental error and deviation should be accounted for. Unless indicated otherwise, temperature is in degrees C. and pressure is at or near atmospheric. All solvents were purchased as HPLC grade, and all reagents were obtained commercially unless otherwise indicated.
Example 1
Synthesis of Subfluorinated Graphite
Graphite ((10 to 30 grams, quantity, M, of Natural Graphite of Madagascar 7.5 μm or Artificial Graphite 15-20 μm distributed on a nickel plate, 0.2 g/cm2) was placed into the nickel reactor (4 liter), and dried under vacuum at room temperature during 2 hours. Then, fluorine gas (99.90% purity) was introduced up to 1 atmosphere and after, using open system reactor, fluorine was flowed with controlled rate (FL g/hour). Afterward, the temperature was regularly increased (1° C./min) to the final temperature T (° C.) and was maintained during H hours. At the end of the reaction, the furnace was cooled to room temperature. Next, the excess of fluorine was evacuated under dry nitrogen flow during 3 hours. (Note: F/C molar ratios of the subfluorinated graphites were measured by the weight uptake method.)
Synthesis of CF0.63
Graphite mass M=30 g
Fluorine flow rate FL=2 g/hour
Reaction time H=17 hours
Reaction temperature T=390° C.
Synthesis of CF0.74
Graphite mass M=30 g
Fluorine flow rate FL=2 g/hour
Reaction time H=19 hours
Reaction temperature T=390° C.
Synthesis of CF0.77
Graphite mass M=30 g
Fluorine flow rate FL=2 g/hour
Reaction time H=20 hours
Reaction temperature T=390° C.
Synthesis of CF0.71
Graphite mass M=13 g
Fluorine flow rate FL=1 g/hour
Reaction time H=14 hours
Reaction temperature T=490° C.
Synthesis of CF0.71
Graphite mass M=13 g
Fluorine flow rate FL=1 g/hour
Reaction time H=31 hours
Reaction temperature T=390° C.
Synthesis of CF0.74
Graphite mass M=30 g
Fluorine flow rate FL=2 g/hour
Reaction time H=17 hours
Reaction temperature T=490° C.
Synthesis of CF0.85
Graphite mass M=30 g
Fluorine flow rate FL=2 g/hour
Reaction time H=20 hours
Reaction temperature T=490° C.
Example 2
Characterization of Subfluorinated Graphites
FIG. 1 shows X-ray diffraction spectra for a subfluorinated graphite materials with range of F/C ratios. The spectra show peaks characteristic of a fluorographite matrix at 2θ between approximately 10 and 15 degrees and between approximately 40 and 45 degrees. A peak at 2θ=26.3, which is the position characteristic of the (002) graphite peak, is clearly observed for CF0.34, CF0.48 and CF0.57. The X-ray diffraction (XRD) powder patterns were obtained using a diffractometer with Cu(Kα) radiation (λ=1.5406 Å). The spectra plot intensity (counts) vs. 2θ.
FIG. 2 shows an enlarged view of an X-ray diffraction spectrum for a subfluorinated graphite material with an F/C ratio of 0.9. The spectrum shows peaks characteristic of a fluorographite matrix at 2θ of approximately 13 degrees (002) and approximately 41 degrees (100). Additional peaks are located at 2θ of approximately 28 degrees (004) and 75 degrees (110). The labels above the peaks are the calculated d-spacings (e.g the label 6,628 corresponds to a spacing of 6.628 Angstroms). The spacings (d) calculated are 6.628 Angstroms for (002), 3.258 Angstroms for (004), 2.201 Angstroms for (100) and 1.273 Angstroms for (110). No peak is observed at 2θ=26.3, which is the position characteristic of the (002) graphite peak. The (hkl) Miller indexes relate to a hexagonal symmetry of the subfluorinated graphite material crystal structure and of graphite. The d-value of 6.628 Angstroms of the (002) line is the average d-spacing between the fluorinated carbon layers.
FIG. 3 shows 13C Magic Angle Spinning (MAS) Nuclear Magnetic Resonance (NMR) spectra for several subfluorinated graphite materials. (10 kHz). The subfluorinated graphite materials were synthesized at a reaction temperature of 390° C. The dotted lines overlaid on the spectra indicate the characteristic positions of peaks for diamond-like sp3-hybridized carbon atoms (at 42-43 ppm/TMS) and carbon in strong interaction with fluorine (C—F) (at about 88 ppm/TMS), and the observed positions attributed to graphite-like sp2-hybridized carbon atoms (CG) (at about 120 ppm/TMS) and carbon atoms in weak interaction with fluorine (C—F) (at about 140 ppm/TMS).
FIG. 4 shows a 13C NMR spectrum for a subfluorinated graphite material having an F/C ratio of 0.9. In FIG. 4, the peak attributed to diamond-like sp3-hybridized carbon atoms has been labeled C and the peak attributed to carbon in strong interaction with fluorine (C—F) has been labeled B. The combination of peaks A and A′ is associated with the contribution of graphite-like sp2-hybridized carbon atoms and carbon atoms in weak interaction with fluorine (C—F). Peak A is more closely associated with carbon atoms in weak interaction with fluorine while peak A′ is more closely associated with graphite-like sp2-hybridized carbon atoms. In order to quantify the relative areas of the peaks, the data was normalized with a Lorentzian function and deconvoluted (Origin 7.5 software, OriginLab). The result is shown by the dashed lines in FIG. 4. The sum of the area of deconvoluted peaks A and A′ divided by the sum of the area of deconvoluted peaks A, A′, B and C is 19%. Similar area ratios for A and A′, respectively, are 8% and 11%.
Table 1 shows data obtained for CF1 and subfluorinated graphites with F/C ratios of 0.65, 0.77, and 0.9. FIG. 5 is a plot of the percent of graphitic carbon and sp3 type carbon versus F/C ratio derived from the spectra in FIG. 3.















TABLE 1






A Peak

A′ Peak

B Peak

C Peak




Position
A Area
Position
A′ Area
Position
B Area
Position
C Area


CFx
(ppm)
Ratio
(ppm)
Ratio
(ppm)
Ratio
(ppm)
Ratio







CF0.65
130
54% 
102
13%
87
23%
46
10%


CF0.77
131
7%
116
 8%
84
51%
43
34%


CF0.9
138
8%
121
11%
89
60%
49
21%


CF1
n/a
n/a
n/a
n/a
85
94%
44
 6%









Example 3
Electrochemical Properties of Subfluorinated Graphite
For the electrochemical tests, the positive electrodes were composed of subfluorinated carbonaceous material, a conductive material and a binder. The positive electrode was then mounted in a two electrode cell where the electrolyte was composed of a 1 mol·L−1 solution of LiBF4 dissolved in propylene carbonate (PC) and dimethyl ether (DME). A microporous polyethylene or polypropylene film containing the electrolyte was sandwiched between the graphite fluoride electrode and a lithium metal foil.
FIG. 6 shows a Ragone plot of energy density versus the square root of power density. Subfluorinated graphites CF0.90, CF0.77 and CF0.744 have significantly higher energy densities than CF for power densities greater than 625 W/kg.
FIGS. 7-10 show discharge profiles for subfluorinated graphites CF0.9, CF0.77, CF0.744, and CF0.647, respectively. The electrode thicknesses were approximately 80 microns, 40 microns, 40 microns and 120 microns, respectively.
Example 4
Synthesis of Subfluorinated Coke
Coke (quantity, M, is 2 grams distributed on nickel boat) was placed into the nickel reactor (1 liter), and dried under vacuum at room temperature during 2 hours. Then, fluorine gas (99.90% purity) was introduced up to 1 atmosphere and after, using open system reactor, fluorine was flowed with controlled rate (FL g/hour). Afterward, the temperature was regularly increased (1° C./min) to the final temperature T (° C.) and was maintained during H hours. At the end of the reaction, the furnace was cooled to room temperature. Next, the excess of fluorine was evacuated under dry nitrogen flow during 1 hours. (Note: F/C molar ratios of the subfluorinated cokes were measured by the weight uptake method.)
It was observed that Coke is more reactive than graphite or carbon nanotubes, for example: at 390° C. during 16 hours with F2, FL=1 g/hour, MWCNT gives CF0.09 (small fluorinated), graphite forms CF 0.7 but CF1.13 is formed with coke.
Combustion Reaction (Final Mass Decreasing) CF1.3 Product
Coke mass M=2 g
Fluorine flow rate FL=2 g/hour
Reaction time H=4.5 hours
Reaction temperature T=400° C.
Synthesis of CF0.5
Coke mass M=2 g
Fluorine flow rate FL=1.8 g/hour
Reaction time H=3 hours
Reaction temperature T=400° C.
Synthesis of CF0.40
Coke mass M=2 g
Fluorine flow rate FL=0.5 g/hour
Reaction time H=12 hours
Reaction temperature T=370° C.
Synthesis of CF0.19
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=12 hours
Reaction temperature T=350° C.
Synthesis of CF0.57
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=6 hours
Reaction temperature T=390° C.
Synthesis of CF0.73
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=7.5 hours
Reaction temperature T=390° C.
Synthesis of CF0.63
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=6.5 hours
Reaction temperature T=390° C.
Synthesis of CF0.87
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=8.5 hours
Reaction temperature T=390° C.
Synthesis of CF0.91
Coke mass M=2 g
Fluorine flow rate FL=1.2 g/hour
Reaction time H=9.5 hours
Reaction temperature T=390° C.
Example 5
Characterization of Subfluorinated Coke
FIGS. 11-14 show x-ray diffraction spectra for a subfluorinated coke materials with F/C=0.36, 0.64, 0.86, and 0.95, respectively. The spectrum shows peaks for fluorinated phases at 2θ equal to approximately 13 degrees, 41 degrees, 43.5 and 44.4 degrees, a peak for a coke phase at 2θ equal to approximately 25.8 degrees, and peaks for the silicon reference at 2θ equal to approximately 28.4 and 47.3 degrees. The height of the peak associated with the coke phase decreases with increasing F/C, as expected.
Table 2 gives typical XRD diffraction results for a CFx material with F/C=0.65 (10°<2θ<50°, Cu Kα) with diffraction peaks assignment. In Table 2, FWHM is the full width at half maximum. The crystallite size calculated by the Scherrer equation gives here Lc=7.5 nm for the coke material using the (002) line of coke at 2θ=25.83 degrees.













TABLE 2









d-




CF0.65
Pos.
Height
FWHM
spacing
Rel. Int.
Peak


Peak #
[°2Th.]
[cts]
[°2Th.]
[Å]
[%]
Assignment





















1
12.8679
336.9
2.619
6.87412
4.19
002 CFx


2
25.8331
751.55
1.2271
3.44605
9.35
002 coke


3
28.4425
8034.08
0.1383
3.13554
100
111 Si


4
40.9818
75.25
1.7746
2.20049
0.94
100 CFx


5
43.5464
31.73
1.8638
2.07665
0.39
101 CFx


6
44.4171
69.68
0.3421
2.03794
0.87
102/006








CFx


7
47.3045
4407.04
0.1603
1.92006
54.85
220 Si





FWHM = full width at half maximum






FIG. 15 shows 13C Magic Angle Spinning (MAS) Nuclear Magnetic Resonance (NMR) spectra for several subfluorinated coke materials. (10 kHz). The dotted lines overlaid on the spectra indicate the characteristic positions of peaks for diamond-like sp3-hybridized carbon atoms (at 42-43 ppm/TMS) and carbon in strong interaction with fluorine (C—F) (at about 88 ppm/TMS), and the observed positions attributed to graphite-like sp2-hybridized carbon atoms (CG) (at about 120 ppm/TMS) and carbon atoms in weak interaction with fluorine (C—F) (at about 140 ppm/TMS).
FIG. 16 shows an NMR spectrum for a subfluorinated coke material with F/C=0.73. The deconvoluted peaks are shown with dashed lines. In contrast to the NMR spectra for subfluorinated graphites, distinct peaks for unfluorinated carbon and carbon in weak association with fluorine are not seen. Therefore, only one peak was fitted in this area (shown as A in FIG. 16). Two additional peaks at lower chemical shift values, B′ and D are also seen. Table 3 shows normalized values of the peak areas.












TABLE 3









Peak(s) A/A′
Peak B
Peak B′
Peak D
















Peak

Peak

Peak

Peak




Position
Area
Position
Area
Position
Area
Position
Area


Material
(ppm)
Ratio
(ppm)
Ratio
(ppm)
Ratio
(ppm)
Ratio





CF0.97 (Coke)
n/a
n/a
78
51%
77
40%
−59
 9%


CF0.73 (Coke)
139
 2%
78
59%
68
22%
−60
17%


CF0.64 (Coke)
109
34%
77
48%
64
13%
−57
 5%


CF0.57 (Coke)
113
41%
78
33%
90
16%
−54
10%









Example 6
Electrochemical Properties of Subfluorinated Coke
For the electrochemical tests, the positive electrodes were composed of subfluorinated carbonaceous material, a conductive material and a binder. The positive electrode was then mounted in a two electrode cell where the electrolyte was composed of a 1 mol·L−1 solution of LiBF4 dissolved in propylene carbonate (PC) and dimethyl ether (DME). A microporous polyethylene or polypropylene film containing the electrolyte was sandwiched between the graphite fluoride electrode and a lithium metal foil.
FIG. 17 shows a Ragone plot of energy density versus the square root of power density. Subfluorinated cokes CF0.64 and CF0.84 have significantly higher energy densities than CF for power densities greater than 900 W/kg.
FIGS. 18-20 show discharge profiles for subfluorinated coke material CF0.97, CF0.87, and CF0.63, respectively.
Table 4 presents electrochemical data for subfluorinated Coke Materials. In Table 4, <e> is the average discharge voltage under a fixed discharge rate, Q=achieved discharge capacity (mAh/g) and E=achieved energy density (Wh/kg).











TABLE 4





x
Discharge
<e> (V)
Q (mAh/g)
(Wh/kg)



















1.2
C/20
2.33
875
1892



C/10
2.19
841
1707



C/5
2.14
779
1686



C/2
2.10
634
1321



1C
1.42
245
305


1.14
C/20
2.37
821
1847



C/10
2.36
800
1811



C/5
2.34
796
1754



C/2
2.08
711
1421



1C
1.03
344
320


1.09
C/20
2.35
810
1835



C/10
2.32
782
1750



C/5
2.22
787
1676



C/2
2.18
739
1556



1C
1.65
461
701



2C
0.86
266
202


1.03
C/20
2.48
1062
2173



C/10
2.38
1013
2296



C/5
2.32
111
1685



C/2
2.06
590
1237



1C
1.67
572
874



2C
1.25
489
526


1.01
C/20
2.43
856
1969



C/10
2.41
833
1908



C/5
2.34
850
1906



C/2
2.01
748
1428



1C
1.84
562
809



2C
1.68
156
48


0.97
C/20
2.39
803
1847



C/10
2.33
838
1825



C/5
2.28
720
1581



C/2
1.97
710
1388



1C
1.63
480
745



2C
1.28
390
408


0.87
C/20
2.46
820
1956



C/10
2.36
721
1653



C/5
2.27
729
1602



C/2
1.98
631
1200



1C
1.99
608
1158



2C
1.51
268
378


0.63
C/20
2.42
730
1467



C/10
2.37
723
1696



C/5
2.37
692
1673



C/2
2.17
520
1057



1C
2.07
491
1015



2C
1.79
253
435


0.37
C/20
2.55
454
1109



C/10
2.43
416
970



C/5
2.37
390
886



C/2
2.21
334
707



1C
2.00
326
616



2C
1.72
203
327



5C
1.13
91
85


0.18
C/20
2.58
501
1317



C/10
2.48
423
1024



C/5
2.42
384
901



C/2
2.34
371
842



1C
2.15
336
729



2C
2.05
241
505



5C
1.56
93
123









Statements Regarding Incorporation by Reference and Variations
All references throughout this application, for example, patent documents including issued or granted patents or equivalents; patent application publications; unpublished patent applications; and non-patent literature documents or other source material; are hereby incorporated by reference herein in their entireties, as though individually incorporated by reference, to the extent each reference is at least partially not inconsistent with the disclosure in this application (for example, a reference that is partially inconsistent is incorporated by reference except for the partially inconsistent portion of the reference).
Any appendix or appendices hereto are incorporated by reference as part of the specification and/or drawings.
Where the terms “comprise”, “comprises”, “comprised”, or “comprising” are used herein, they are to be interpreted as specifying the presence of the stated features, integers, steps, or components referred to, but not to preclude the presence or addition of one or more other feature, integer, step, component, or group thereof. Separate embodiments of the invention are also intended to be encompassed wherein the terms “comprising” or “comprise(s)” or “comprised” are optionally replaced with the terms, analogous in grammar, e.g.; “consisting/consist(s)” or “consisting essentially of/consist(s) essentially of” to thereby describe further embodiments that are not necessarily coextensive.
The invention has been described with reference to various specific and preferred embodiments and techniques. However, it should be understood that many variations and modifications may be made while remaining within the spirit and scope of the invention. It will be apparent to one of ordinary skill in the art that compositions, methods, devices, device elements, materials, procedures and techniques other than those specifically described herein can be applied to the practice of the invention as broadly disclosed herein without resort to undue experimentation. All art-known functional equivalents of compositions, methods, devices, device elements, materials, procedures and techniques described herein are intended to be encompassed by this invention. Whenever a range is disclosed, all subranges and individual values are intended to be encompassed as if separately set forth. This invention is not to be limited by the embodiments disclosed, including any shown in the drawings or exemplified in the specification, which are given by way of example or illustration and not of limitation. The scope of the invention shall be limited only by the claims.
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## Claims

1. A subfluorinated graphite material having an average chemical composition CFx in which 0.63≦x≦0.95, and comprising
i) carbon strongly bound to fluorine and carbon weakly bound to fluorine or
ii) carbon strongly bound to fluorine, carbon weakly bound to fluorine and unfluorinated carbon,
wherein the relative amount of unfluorinated carbon and carbon weakly bound to fluorine is greater than or equal to 5% and less than 37% and 13C nuclear magnetic resonance spectroscopy analysis of the subfluorinated graphite material provides a spectrum comprising a chemical shift peak centered from 130 to 150 ppm relative to TMS, a chemical shift peak centered at 84 to 89 ppm relative to TMS, and a chemical shift peak centered at 43 to 49 ppm relative to TMS.

2. The subfluorinated graphite material of claim 1, wherein 0.66≦x≦0.95.

3. The subfluorinated graphite material of claim 2, wherein 0.7≦x≦0.95.

4. The subfluorinated graphite material of claim 1, wherein the spectrum comprises a chemical shift peak centered at approximately 140 ppm relative to TMS.

5. The subfluorinated graphite material of claim 1, wherein the relative amount of unfluorinated carbon and carbon weakly bound to fluorine is greater than or equal to 10% and less than or equal to 20%.

6. An electrochemical device comprising an anode, a cathode, and an ion-transporting material therebetween, wherein the cathode comprises a subfluorinated graphite material according to claim 1.

7. The electrochemical device of claim 6, wherein 0.66≦x≦0.95.

8. The electrochemical device of claim 7, wherein 0.7≦x≦0.95.

9. The electrochemical device of claim 6, wherein the relative amount of unfluorinated carbon and carbon weakly bound to fluorine is greater than or equal to 10% and less than or equal to 20%.

10. An electrochemical device of claim 6, wherein the 13C NMR spectrum comprises a chemical shift peak centered at approximately 140 ppm relative to TMS.

11. The device of claim 6, wherein the anode comprises a source of ions of a metal selected from Groups 1, 2, and 3 of the Periodic Table of Elements.

12. The device of claim 11, wherein the ions are lithium ions.

13. The electrochemical device of claim 6, wherein an x-ray diffraction spectrum of the subfluorinated graphite does not comprise a substantial peak at 2θ in the range 26.3-26.4 degrees, using CuKα radiation.

14. The electrochemical cell of claim 6, wherein the subfluorinated graphite material is present in a composition containing a conductive diluent and a binder, the subfluorinated graphite material representing about 70 wt % to about 90 wt % of the composition.

15. A method for making a subfluorinated carbonaceous material, the method comprising the steps of
a. providing graphite particles;
b. exposing the graphite particles to a flowing gaseous source of elemental fluorine;
c. heating the graphite particles to a selected reaction temperature, the selected temperature being between 330° C. and 600° C., wherein the average size of the particles is between 2 microns and 200 microns; and
d. maintaining the graphite particles at the selected temperature for a time between 2 hours and 30 hours to obtain a subfluorinated graphite material having an average chemical composition CFx in which 0.63<x≦0.95 and comprising
i). carbon strongly bound to fluorine and carbon weakly bound to fluorine or
ii) carbon strongly bound to fluorine, carbon weakly bound to fluorine and unfluorinated carbon,

wherein the relative amount of unfluorinated carbon and carbon weakly bound to fluorine is greater than or equal to 5% and less than 37% and 13C nuclear magnetic resonance spectroscopy analysis of the subfluorinated graphite material provides a spectrum comprising a chemical shift peak centered from 130 to 150 ppm relative to TMS, a chemical shift peak centered at 84 to 89 ppm relative to TMS, and a chemical shift peak centered at 43 to 49 ppm relative to TMS.

16. The method of claim 15, wherein the graphite particles are held at the selected temperature for a time between 8 and 20 hours.