# Patent

## Title
Natural tourmaline anion fiber and filter and producing method

## Abstract

The present invention provides to a method of producing fiber from tourmaline anion fiber; of which, polypropylene or polyethylene chip, TPE and submicrometer tourmaline particle are prepared and then rolled into submicrometer tourmaline agglomerate through granulation by double screw; then, take submicrometer tourmaline agglomerate and polypropylene or polyethylene chip, of which the content of tourmaline agglomerate accounts for 1 ̃10% of gross weight, and TPE for 1 ̃40% of gross weight; tourmaline agglomerate and polypropylene or polyethylene are melted into composite fiber or filter material via spinning, such that the fiber or filter material can yield anion and present outstanding gas permeability and mechanical property.

## Background
BACKGROUND OF INVENTION
1. Field of the Invention
The present invention relates generally to a method of producing tourmaline anion fiber and filter material, and more particularly to a method of producing composite fiber from tourmaline, Thermoplastic Elastomer (TPE) and polypropylene or polyethylene, and then forming into filter material, such that the fiber can generate anion, and present outstanding permeability and mechanical property.
2. Description of Related Art
With growing industrialization and social progress, the human beings now meet the challenge of worsening environmental pollution and decreasing anion in atmosphere. And, owing to the transformation of living functions, the people now spend most of time in a limited indoor environment, where air filter is a key factor to ensure good air quality. Today, improving technologically air quality by filter materials without jeopardizing natural environment is one of most cost-effective ways. Therefore, high-tech textiles now become a focus of competition on international textile market, and also contribute much to the growth of textile industry. Anion-based textile products now raise a high priority concern of international textile industry thanks to a wide range of benefits, such as: accelerating blood circulation of human body, improving functional efficiency and physical status, supplementing microelement for the human body, generating far-infrared ray and stimulating recovery function of human cells.
There are three approaches to improve indoor air quality: improve ventilation, minimize indoor pollutants and utilize air cleaner units. For this purpose, differential pressure of filter materials must be lowered with a higher rate of ventilation. Also, filter efficiency shall be improved. An air cleaner unit comprises a cooler, a cleaner and a dehumidifier.
Indoor air filter is generally made of woven filler screen and non-woven filter screen. Woven filter screen can be cleaned and recycled, with lower differential pressure and filtering efficiency. Non-woven filter materials, made of multi-layer stacks, cannot be recycled with higher filtering efficiency and differential pressure. Differential pressure is a decisive factor to ventilation efficiency, rate of air change and horsepower of air conditioning. One purpose of the present invention is to improve filtering efficiency using woven filter screen with lower differential pressure.
Common filters could filtrate powder, but couldn't remove odor. To achieve this goal, anion generator and active carbon filter shall be generally required. Anion generator could generate ozone (O3), which must be less than 0.12 ppm with poor time efficiency, and also limited within 1 m. So, this generator is not suitable for indoor applications. Active carbon filter also has the problem of absorption saturation. Anion tourmaline, a natural mineral, is recognized as a “dust collector of the nature”. The second purpose of the present invention is to prepare a permanent deodorant fiber by adding submicrometer tourmaline into polypropylene fiber (environmental-friendly plastic).
Tourmaline is easy to absorb powder due to its thermoelectricity and piezoelectricity. The third purpose of the present invention is to identify if the permanent electric property is able to improve the filtering efficiency.
The fourth purpose of the present invention is to study the filters made of common fiber or other fibers, which neither contain extracted vegetable oil, nor yields volatile oil.
Currently, tourmaline or anion fiber technologies are often used to prepare fiber by combining tourmaline and rayon fiber in water solution, or prepare insoluble fiber by tourmaline and polyvinyl alcohol solution, or by combining titania, zinc oxide, zirconia, tourmaline, silicon oxide and aluminum oxide. Though tourmaline is contained in these common technologies, these patented fibers are made of different materials with varied methods. However, the efficiency of above-specified technologies shall be further verified due to absence of preferred embodiment.
SUMMARY OF THE INVENTION
The objective of the present invention is to provide a composite filter made of tourmaline, Thermoplastic Elastomer (IPE) and polypropylene or polyethylene, which enables the fiber to generate anion, and present outstanding permeability and mechanical property. Firstly, polypropylene or polyethylene chips, submicrometer tourmaline particles and TPE are mixed and prepared into submicrometer tourmaline agglomerate. Then, take submicrometer tourmaline agglomerate and polypropylene or polyethylene chips (the content of tourmaline agglomerate accounts for 1-10% of gross weight), and melt them into a composite fiber comprising submicrometer tourmaline/polypropylene or polyethylene.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is the comparison of Anion Release of Tourmaline with Different Contents under the same layer of the present invention;
FIG. 2 is the comparison of Action Release between the filters with different percentage of Content of Tourmaline and Multiple Layers of the present invention;
FIG. 3 shows the Analysis of Release Efficiency of Anion with Different Contents under the Same Layer of Submicrometer Tourmaline Polypropylene Filter Material of the present invention;
FIG. 4 shows the Analysis of Anion's Release Efficiency with Tourmaline Content less than 1% and under Multiple Layers of Submicrometer Tourmaline Polypropylene Filter Material of the present invention, and
FIG. 5 shows the Analysis of Anion's Release Efficiency Depending upon Content and Layers of Submicrometer Tourmaline Polypropylene Filter Materials.



DETAILED DESCRIPTION OF THE INVENTION
A. Fiber of the Present Invention
Tourmaline anion man-made fiber primarily comprises submicrometer tourmaline particle, Thermoplastic Elastomer (TPE) and polypropylene or polyethylene, of which the diameter of fiber is 0.01 mm-3 mm, and particle size of submicrometer tourmaline is 1 micrometer-100 nm, and tourmaline particle accounts for 1-10% of fiber. Tourmaline's far-infrared radiation: 0.948 μm (3.48*102 w/m2), particle size distribution: D50 (average particle size: 493 nm). Moreover, the present invention permits to produce at least one layer of fluid filter material through aforementioned tourmaline anion man-made fiber. According to one preferred embodiment of the present invention, nano-silver grain can be added into above-specified material to yield immunity to bacteria. Of which, added nano-silver accounts for 0.5-5% of total fiber. According to another preferred embodiment of the present invention, microcapsule may be added into above-specified material. The microcapsule, which contains functional materials such as extracted vegetable oil, accounts for 0.5-5% of total fiber.
The production method of tourmaline anion man-made fiber in the present invention is to prepare a first material, which contains first polypropylene chip accounting for 70% ̃95% of gross weight with a molecular weight of 3.15×105 g/mole, or first polyethylene chip with a molecular weight of 1.5-2.5×105 g/mole (of which, the preferred embodiments are described in following tests based on first polypropylene accounting for 80% of first material) and submicrometer tourmaline particle accounting for 5% ̃30% of gross weight, as well as Thermoplastic Elastomer (IPE) or Ethylene Propylene Diene Monomer (EPDM) accounting for 1-40% of gross weight. The first material is rolled into agglomerate through mixing and granulation by double screw, and the second polypropylene chip with a molecular weight of 3.15×105 g/mole, or the second polyethylene chip with a molecular weight of 1.5 ̃2.5×105 g/mole is taken as the second material. Then, mix the agglomerate and the second material. Of which, the content of tourmaline agglomerate accounts for 1-10% of gross weight. Next, the agglomerate and second material are melted into fiber via spinning, cooling, thermal stretching and forming. The temperature of spinning ranges between 200 ̃300° C. (in the preferred embodiment of present invention, the temperature of spinning ranges between 200 ̃250° C. for polypropylene, and between 250-300° C. for polyethylene), extensibility 3 ̃8 times (6 times in the preferred embodiment of the present invention), thermal stretching temperature 100-160° C. (100° C. in the preferred embodiment of the present invention) and thermal forming temperature 70° C. ̃100° C.
The abovementioned melting and spinning is to heat up and melt polypropylene or polyethylene, and then force out from spinning nozzle into air for cooling and curling at a proper speed. Meanwhile, polypropylene or polyethylene is condensed to form fiber. Next, the fiber is stretched again to improve its mechanical property. The melting and spinning process is to force out spinnable polymer from spinning nozzle at a temperature over melting point, and enable it to be cooled and refined into threadlike material.
B. Fiber Filter Materials of the Present Invention
The production method of fiber filter materials in the present invention is to prepare the first material, which contains first polypropylene chip accounting for 70% ̃95% of gross weight with a molecular weight of 3.15×105 g/mole, or first polyethylene chip with a molecular weight of 1.5 ̃2.5×105 g/mole (of which, the preferred embodiments are described in following tests based on first polypropylene accounting for 80% of first material) and submicrometer tourmaline particle accounting for 5%-30% of gross weight, as well as Thermoplastic Elastomer (TPE) or Ethylene Propylene Diene Monomer (EPDM) accounting for 1 ̃40% of gross weight. The first material is rolled into agglomerate, and the second polypropylene chip with a molecular weight of 3.15×105 g/mole, or the second polyethylene chip with a molecular weight of 1.5 ̃2.5×105 g/mole is taken as the second material. Of which, the content of tourmaline agglomerate accounts for 1 ̃10% of gross weight. Next, the agglomerate and second material are melted for spinning, cooling, thermal stretching and forming into fiber. The temperature of spinning ranges between 200° C. ̃300° C. (in the preferred embodiment of present invention, the temperature of spinning ranges between 200 ̃250° C. for polypropylene, and between 250° C. ̃300° C. for polyethylene), extensibility 3 ̃8 times, thermal stretching temperature 100-160° C. (100° C. in the preferred embodiment of the present invention) and thermal forming temperature 70° C. ̃100° C. (90° C. in the preferred embodiment of the present invention). Next, submicrometer tourmaline/polypropylene or polyethylene fiber is reeled, and woven into submicrometer tourmaline/polypropylene or polyethylene fiber filter through a weaving machine (a steel shuttle in the present invention), of which the longitudinal density is 35 ̃50 thread/inch, latitudinal density 30 ̃40 thread/inch, and weaving width ≧65.
To guarantee antibacterial immunity, the fiber is mixed with nano-silver grain up to 1% of gross weight of fiber. The following test results show that this invention also presents excellent resistance to bacteria.
Furthermore, in order to validate other effects, the fiber of the preferred embodiment is added with microcapsule accounting for 1% of gross weight. The microcapsule contains functional materials such as extracted vegetable oil, so this invention could yield long-lasting fragrance as demonstrated in the following test.
C. Test of the Present Invention
a. The filter materials made of fiber (mainly based on polypropylene) have a stronger mechanical property, with the test results described below:
(1) Tension Strength: Table 1 shows the Test Results of Longitudinal Tension Strength of Submicrometer Tourmaline/Polypropylene Filter Materials (kgrcm2).













TABLE 1





Number

Tourmaline
Tourmaline
Tourmaline
Tourmaline
Tourmaline


of Test
No Fabric
Content 1%
Content 2%
Content 3%
Content 4%
Content 5%





















1
38.704
36.075
36.005
37.085
36.251
36.215


2
39.483
36.108
38.068
38.251
37.511
38.014


3
44.581
40.652
37.065
39.125
38.253
37.588


4
42.015
40.206
40.126
36.001
35.921
37.263


5
41.076
38.254
36.008
35.759
38.205
36.952


Average
41.1718
38.259
37.4544
37.2442
37.2282
37.2064


Value









As shown in Table 1 for composite filter materials containing tourmaline/polypropylene, the tension strength will decline gradually with the increase of longitudinal strength of tourmaline (from 41.17 kgf/cm2 to 37.21 kgfcm2). This is possibly because that rigid tourmaline powder is embedded into polypropylene fiber structure via melting and spinning, such that the rigidity of anion/polypropylene fiber is improved, but some anion generate particle in the fiber, which may impair the fiber strength. So, tension strength is lowered with growing amount of particle.

(2) Tensile Strength:
Table 2 shows the Influence of Submicrometer Tourmaline Content upon Tensile Strength of Polypropylene Filter Materials (kgfcm2).













TABLE 2





Number

Tourmaline
Tourmaline
Tourmaline
Tourmaline
Tourmaline


of Test
No Fabric
Content 1%
Content 2%
Content 3%
Content 4%
Content 5%





















1
21.886
23.728
22.765
21.345
22.706
22.086


2
23.725
19.174
21.129
22.349
20.609
20.308


3
26.816
24.627
21.764
22.047
21.086
21.117


4
21.314
18.032
21.796
19.449
21.625
20.598


5
22.108
24.499
22.229
23.603
21.855
21.717


Average
23.1698
22.012
21.9366
21.7586
21.5762
21.1652


Value









As shown in Table 2, submicrometer tourmaline allows a higher rigidity of polypropylene filter materials. In the event of particle interaction, tensile strength differs markedly with or without addition of anion. Therefore, tensile strength of filter materials will reduce with the increase of tourmaline content. In the case of tourmaline content of 1%, longitudinal tensile strength declines about 5%. In the case of tourmaline content of 5%, longitudinal tensile strength declines about 8.6%. According to t-test results, there is not remarkable influence with addition of 1-5% or without addition. Also, the content has no remarkable influence for analysis of variance. So, tensile strength is not affected with addition of tourmaline 1-5%.
(3) Test of Washing Fastness (Test Condition: Indoor humidity is 58%, and temperature 29° C.):













TABLE 3








Addition
Prior
Average Value
Maintenance




of 
to 
after 
of 




Tourmaline
Test
Five Tests
Anion










1%
265
263
99%




2%
350
343
98%




3%
383
365
95%




4%
435
416
96%




5%
489
461
94%










Table 3 shows the Influence of Submicrometer Tourmaline Content upon Washing Fastness of Polypropylene Filter Materials (Ion/cc). As shown in Table 3, a good fastness is still maintained prior to or after test, so the amount of anion will not reduce due to washing.
(4) Analysis of Filter Efficiency:
Table 4 shows the filter Efficiency of Polypropylene Filter Materials Depending upon Content and Layers of Submicrometer Tourmaline (η) %.













TABLE 4





Layer of

Tourmaline
Tourmaline
Tourmaline
Tourmaline
Tourmaline


Filter
No Fabric
Content 1%
Content 2%
Content 3%
Content 4%
Content 5%







1st layer
30.120
35.875
39.012
41.543
42.687
42.987


2nd layer
61.000
68.174
70.705
71.849
72.149
73.123


3rd layer
76.000
82.569
83.713
84.013
84.987
85.125


4th layer
86.000
90.125
90.425
91.399
91.537
91.234


5th layer
95.000
97.562
98.536
98.674
98.371
98.574









According to the test results listed in Table 4, the filter efficiency of submicrometer tourmaline/polypropylene filter materials with the same layers will be improved with the increase of tourmaline content This is primarily owing to the fact that anion with slight amount of negative charge can absorb some free powder with positive charge, thus improving filter efficiency of air filter. As shown in Table 4, filter efficiency differs markedly with or without addition of anion (filter efficiency increases by 5.7%-12.8% with addition of 1%-5% tourmaline). But, “deep-layer filtration” effect is a most important influential factor.
(5) Analysis of Anion's Release Efficiency—Static Mode:
Under a static mode, the humidity is 58%, and temperature 28° C.
Table 5: shows the Analysis of Anion's Release Efficiency Depending upon Content and Layers of Submicrometer Tourmaline Polypropylene Filter Materials (Ion/cc).












TABLE 5





Addition
1st Layer
2nd Layer
3rd Layer
4th Layer
5th Layer


of
Filter
Filter
Filter
Filter
Filter


tourmaline
Screen
Screen
Screen
Screen
Screen




















1%
265
412
532
620
712


2%
350
523
652
734
825


3%
412
589
756
834
985


4%
465
652
852
935
1080


5%
489
712
867
973
1115









As shown in FIGS. 1 and 2, addition of both tourmaline and infiltration layers are influential factors, but layers are primary influential factors. Under the same layer but different contents, anion of submicrometer tourmaline polypropylene filter will release up to 265-489 Ion/cc In the case of content 1%, anion of submicrometer tourmaline polypropylene filter will release up to 265-712 Ion/cc, showing a difference of 223 Ion/cc. In the same volume of tourmaline, more layers will efficiently facilitate the release of anion.
Referring to FIGS. 1 and 2, maximum release content is 1115 Ion/cc, showing a moderate release of anion under a static mode; and the release content is rising slowly. Under a static mode, the curve becomes gentle in the case of tourmaline content 3-5%; addition of anion is not an important release factor in the excess of 3%.
(6) Analysis of Anion's Release Efficiency—Dynamic Mode:
Under a dynamic mode, the humidity is 64%, and temperature 29° C.
Table 6 Analysis of Anion's Release Efficiency Depending upon Content and Layers of Submicrometer Tourmaline Polypropylene Filter Materials (%).












TABLE 6





Addition of







Tourmaline
1st layer
2nd layer
3rd layer
4th layer
5th layer







1%
1025
1695
2213
2732
2956


2%
1523
2573
3012
3325
3456


3%
1856
3212
3512
3759
3956


4%
1956
3512
3725
3856
4120


5%
1983
3603
3901
3921
4220









As listed in Table 6, both addition of tourmaline and infiltration layers are influential factors, but layers are primary influential factors.
FIG. 3 shows the Analysis of Release Efficiency of Anion with Different Contents under the Same Layer of Submicrometer Tourmaline Polypropylene Filter Material. As shown in FIG. 3, under the same layer but different contents, anion of submicrometer tourmaline polypropylene filter material will release up to 1025-1983 Ion/cc; with addition of 3%, anion release will rise towards a fixed value.
FIG. 4 shows the Analysis of Anion's Release Efficiency with Tourmaline Content less than 1% and under Multiple Layers of Submicrometer Tourmaline Polypropylene Filter Material. As shown in FIG. 4, in the case of content 1%, anion of different submicrometer tourmaline polypropylene filter materials will release up to 1025-2956 Ion/cc, and grows with the layers, showing a difference of 973 Ion/cc.
In the same volume of anion-based tourmaline, more layers will efficiently facilitate the release of anion.
FIG. 5 shows the Analysis of Anion's Release Efficiency Depending upon Content and Layers of Submicrometer Tourmaline Polypropylene Filter Materials. As shown in the curve of FIG. 5, the curve becomes gentle in the addition of tourmaline 3%-5%. In the excess of 3%, addition of tourmaline is not an important variance factor, as in the case of static mode. As shown in the curve of FIG. 5, the maximum release content is 4220 Ion/cc, showing that anion release in a dynamic mode caters for the needs of human health (1000 ̃2000 Ion/CC).
b. The filter materials made of fibers of the present invention have deodorant performance, with the test results described below:
By means of TEM 1467, the filter materials of the present invention are employed to measure the concentration of NH3 and CH3CHO, and then the removing rate for the concentration of CH3COOH. As listed in Table 7, the filter materials of the present invention present outstanding deodorization performance.
Table 7 shows the Deodorization Effect of Filter Materials of the Present Invention as per TEM 1467 Test Method.










TABLE 7





Item
NH3
CH3CHO
CH3COOH







Initial
24.00 PPM
8.00 PPM
0.20 PPM


concentration





Concentration after
10.00 PPM
2.00 PPM
0.08 PPM


30 minutes





Removing rate of
51.25%
71.25%
50.00%


multi pollution





Total removing rate
 60.9%









c. Test Results of Antibacterial Performance of Fiber Filter Materials of the Present Invention:











TABLE 8






0 Initial





Inoculation
Contact Time
Reduction(%)


TEST ITEM
(CFU/ml)
(1 hr later)
(1 hr later)







Staphylococcus
1.0 × 105
3.0 × 104
94.8(%)


aureus





Escherichia
2.1 × 105
1.6 × 103
99.2(%)


coli





Klebsiella
7.3 × 105
3.0 × 104
95.8(%)


pneumoniae



















TABLE 9







GROWTH-FREE
CONTACT



TEST ITEM
ZONE
INHIBITION








Staphylococcus aureus
 10 mm
100(%)



Escherichia coli
4.5 mm
100(%)



Klebsiella pneumoniae
3.5 mm
100(%)



Staphylococcus aureus
 12 mm
100(%)



Escherichia coli
  2 mm
100(%)









As listed in Table 8, the filter materials of the present invention present outstanding antibacterial performance In ASTM E 2149-01 test. As listed in Table 9, the filter materials of the present invention present outstanding antibacterial performance In AATCC 147 test.
d. Fragrance Retention Test of Fiber Filter Materials of the Present Invention:
As listed In Table 10, the filter materials of the present invention exhibit a 3-month fragrance retention. The test method is 6-Level Odor Strength Grading method. The values of test result indicate the Perception of the Odor Strength are:

    
    
        0: Odor less; 1: Odor which can be perceived eventually with effort; 2: Weak Odor which can be identified; 3: Odor which can be perceived easily; 4: Strong Odor; 5: Severe Odor.
    
    











TABLE 10






Test Results
Test Result


Test items
(Initial test)
(after 3 months test again)







Odor Faculty Evaluation
3.4
4.0









D. Features of the Present Invention
1. According to variance analysis of mechanical strength, addition of tourmaline filter screen will lead to slight change and moderate influence; also moderate influence upon longitudinal and latitudinal tensile strength; no influence upon tensile strength after test of variance, nor on air permeability.

2. In terms of washing fastness; addition of tourmaline is an important factor to washing fastness, but only has a moderate influence level: 94% ̃99% anion function is still maintained. The life span of polypropylene filter screen is about 3-5 years. The biggest difference with non-woven filter materials lies in: recycling, environmental-friendliness/energy conservation and higher economy in avoiding second pollution.

3. In terms of filter efficiency; tourmaline with negative charge will improve efficiently filter efficiency and absorb particle of 0.01 μm-5 μm via the help of “electrostatic adherence principle”. As compared to previous inertia collection of 0.5 μm particle, this efficiency is improved significantly. The filter efficiency and dust collection capacity are improved greatly due to “deep filtration”. Filtration layer is the most important influential factor of filter efficiency, which may reach 98.5%.

4. Under a static mode: if tourmaline is added to 3%, anion release is slowed, but not exceeds 1000 ion/cc. It can be seen that, tourmaline cannot bring its function into full play in the case of absence of vapor and temperature difference, wind rate fluctuation and frictional effect in a static mode.

6. Under a dynamic mode: both addition of tourmaline and filtration layers are important factors to release, but layers are primary influential factors. When tourmaline is added to 3%, anion release is slowed down. Given the fact of internal vapor and temperature difference of cooler, wind rate fluctuation and frictional effect, as well as thermoelectricity and piezoelectricity of anion for H3O2−, anion release in a dynamic mode caters for the needs of human health (1000-2000 ion/cc). A release of 1000-4220 ion/cc is maintained.

Although the invention has been explained in relation to its preferred embodiment, it is to be understood that many other possible modifications and variations can be made without departing from the spirit and scope of the invention as hereinafter claimed.

## Claims

1. A natural tourmaline anion fiber consisting of:
submicrometer tourmaline particles,
a thermoplastic elastomer (TPE),
a polypropylene with a molecular weight of 3.15×105 g/mole or a polyethylene with a molecular weight of 1.5×105 to 2.5×105 g/mole,
optionally nano-silver grains, and
optionally microcapsules containing a functional material, wherein:
the diameter of said fiber is from 0.01 mm to about 3 mm,
the particle size of said submicrometer tourmaline particles is from 1 μm to 100 nm, and
the amount of said submicrometer tourmaline particles in said fiber is from 1 to 10% by weight, based on the total weight of said fiber contents.

2. The fiber of claim 1, wherein said fiber comprises a polyethylene with a molecular weight of from 1.5×105 to 2.5×105 g/mole.

3. The fiber of claim 1, wherein said fiber comprises a polypropylene with a molecular weight of 3.15×105 g/mole.

4. The fiber of claim 1, wherein said fiber comprises from 0.5 to 5% by weight nano-silver grains based on the total weight of said fiber contents.

5. The fiber of claim 1, wherein said fiber comprises from 0.5 to 5% by weight microcapsules based on the total weight of said fiber contents, wherein said microcapsules contain functional material.

6. The fiber of claim 5, wherein said functional material is an extracted vegetable oil.

7. The fiber of claim 6, wherein said extracted vegetable oil provides a long-lasting fragrance.

8. The fiber of claim 1, wherein the amount of said TPE in said fiber is from 1 to 40% by weight based on the total weight of said fiber contents.

9. The fiber of claim 1, wherein said TPE comprises Ethylene Propylene Diene Monomer (EPDM).

10. A filter, which is made of at least one layer of fiber, wherein the fiber consists of:
submicrometer tourmaline particles,
a thermoplastic elastomer (TPE),
a polypropylene with a molecular weight of 3.15×105 g/mole or polyethylene with a molecular weight of 1.5×105 to 2.5×105 g/mole,
optionally nano-silver grains, and
optionally microcapsules containing a functional material, wherein:
the diameter of said fiber is from 0.01 mm to 3 mm,
the particle size of submicrometer tourmaline particles is from 1 μm to 100 nm, and
the amount of said submicrometer tourmaline particles in said fiber is from 1 to 10% by weight, based on the total weight of said fiber contents.

11. The filter of claim 10, wherein said fiber comprises from 0.5 to 5% weight nano-silver grains, based on the total weight of said fiber contents.

12. The filter of claim 10, wherein said fiber comprises from 0.5 to 5% by weight microcapsules, based on the total weight of said fiber contents, wherein said microcapsules contain a functional material.

13. The filter of claim 10, wherein said functional material is an extracted vegetable oil.

14. The filter of claim 13, wherein said extracted vegetable oil provides a long-lasting fragrance.

15. The filter of claim 10, wherein said fiber comprises a polyethylene with a molecular weight of from 1.5×105 to 2.5×105 g/mole.

16. The filter of claim 10, wherein said fiber comprises a polypropylene with a molecular weight of 3.15×105 g/mole.

17. The filter of claim 10, wherein said filter is made of 2, 3, 4 or 5 layers of fiber.

18. The filter of claim 17, wherein said filter is made of 5 layers of said fiber.

19. The filter of claim 10, wherein the amount of said TPE in said fiber is from 1 to 40% by weight, based on the total weight of said fiber contents.

20. The filter of claim 10, wherein said TPE comprises Ethylene Propylene Diene Monomer (EPDM).