# Patent

## Title
Process and apparatus for treatment of incinerator bottom ash and fly ash

## Abstract

A method for treatment of ash from incineration plants includes: collecting ash from an incinerator; feeding the collected ash and additional feed material to a gasification/vitrification reactor; vitrifying the ash and additional feed material in the gasification/vitrification reactor, to form a slag of molten material; allowing the slag to flow from the gasification/vitrification reactor and solidify outside the gasification/vitrification reactor; gasifying volatile components in the ash and the additional feed material; combusting syngas generated in the gasification/vitrification reactor in a secondary combustion zone in the gasification/vitrification reactor; and supplying products of the syngas combustion to the incinerator to augment the thermal environments of the incinerator. An apparatus used to practice the method is also provided.

## Background
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation of U.S. application Ser. No. 13/445,255, filed Apr. 12, 2012, entitled “Process and Apparatus for Treatment of Incinerator Bottom Ash and Fly Ash”, which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/517,064, filed Apr. 13, 2011, entitled titled “Process and Apparatus for Treatment of Incinerator Bottom Ash and Fly Ash”, both of which are incorporated herein by reference.


FIELD OF THE INVENTION
The invention relates to methods and apparatus for treating ash products of incineration for safe, economical disposal.
BACKGROUND
Typical fossil fuel power plants, and other incineration apparatus, such as waste incinerators, produce large amounts of bottom ash, left as residue in a combustor from the fuel combustion, and fly ash, exiting with gaseous combustion products in (flue gas) stack emissions. The ash products may contain substantial amounts of toxic matter, such as elemental metals, metal oxides, sulfur, and chlorine, considered hazardous to the environment. The ash composition often results in restrictions on the disposal of the ash and may require substantial expense in collecting and hauling the ash to a hazardous waste site which may be inconveniently located and have considerable deposit fees, and such a site itself remains an environmental hazard,
Suggestions have been made for processing ash by various treatments to a form intended to result in a reduced hazard with less expense of disposition. These have not been adopted to a large extent and there remains a need and desire for more effective and efficient treatment.
SUMMARY
In a first aspect, a method for treatment of ash from incineration plants includes: collecting ash from an incinerator; feeding the collected ash to a gasification/vitrification reactor; vitrifying the ash in the gasification/vitrification reactor, to form a slag of molten material; allowing the slag to flow from the gasification/vitrification reactor and solidify outside the gasification/vitrification reactor; gasifying volatile components in the ash; combusting syngas generated in the gasification/vitrification reactor in a secondary combustion zone in the gasification/vitrification reactor; and supplying products of the syngas combustion to the incinerator to augment the thermal environments of the incinerator. In another aspect, an apparatus includes an incinerator, a gasification/vitrification reactor, a first feed passage for transporting bottom ash from a bottom of the incinerator to the gasification/vitrification reactor, an incinerator exhaust gas fly ash recovery system, a second feed passage for transporting fly ash collected by the recovery system to the gasification/vitrification reactor, and a third passage for routing syngas generated in the gasification/vitrification reactor back to the incinerator.
In another aspect, an apparatus includes: an incinerator; a gasification/vitrification reactor; a first feed passage for transporting bottom ash from a bottom of the incinerator to the gasification/vitrification reactor; an interface connecting a secondary combustion zone in the gasification/vitrification reactor to the incinerator allowing products of syngas combustion produced in the gasification/vitrification reactor to flow directly to the incinerator; and an air inlet in the secondary combustion zone in the gasification/vitrification reactor.
In another aspect, an apparatus includes: an incinerator; a gasification/vitrification reactor; a first feed passage for transporting bottom ash from a bottom of the incinerator to the gasification/vitrification reactor; an interface connecting a secondary combustion zone in the gasification/vitrification reactor to the incinerator; and a burner or an igniter for igniting the syngas in the secondary combustion zone; wherein the secondary combustion zone is configured to allow products of syngas combustion produced in the gasification/vitrification reactor to pass from the secondary combustion zone into the incinerator.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a block diagram of an example ash treatment system.
FIG. 2 is a block diagram of another example ash treatment system.
FIG. 3 is a schematic illustration of some parts of an example ash treatment system.
FIG. 4 is a schematic illustration of some parts of another example ash treatment system.



DETAILED DESCRIPTION
An apparatus and process is described in which either, or both, bottom ash and fly ash can be treated for disposition. In various embodiments, the process can include some or all of the steps of, for example, collecting fly ash from incinerator exhaust and bottom ash from an incinerator, feeding the collected fly ash and bottom ash to a gasification/vitrification reactor (GVR), optionally supplying an additional feed material other than the ash to the GVR, which feed material may be any material suitable for gasification such as municipal solid waste (MSW), refuse-derived fuel (RDF), biomass, coal, hazardous waste, medical waste, liquid waste streams of coal or other carbonaceous products, or a combination of any such materials, vitrifying the ash, and any other inert constituents in the feed material, in the GVR, to form a slag of molten material that includes a substantial amount (e.g., up to about 90% or more) of the hazardous material from the feed material, allowing the slag to flow from the GVR and solidify outside the GVR ready for safe disposition without environmental concerns, gasifying volatile components in the fly ash, bottom ash, and additional feed material, and routing any syngas generated in the GVR back to the incinerator where it can be combusted in order to augment the thermal environment of the incinerator.
Apparatus for performing the process may take a variety of forms among which are, as parts of an overall system in combination, an incinerator, a gasification/vitrification reactor (GVR), for example, a plasma gasification/vitrification reactor (PGVR), a first feed conduit for transporting bottom ash from the bottom of the incinerator to the GVR, an incinerator exhaust gas fly ash recovery system that may include one or more of a heat recovery steam generator (or boiler or heat exchanger), a scrubber, and a bag filter between the incinerator and an emission stack, and a second feed conduit for transporting fly ash collected by the recovery system to the GVR. The GVR can include a slag tap hole and an external slag receptacle can be provided for solidification of the slag.
Numerous variations in the process or apparatus can be included. For example, the bottom ash and the fly ash may be fed together, or separately, to the GVR and the ash may be fed with other feed material, or not. If a plasma gasification/vitrification reactor (PGVR) is used, the ash, and other material if used, may be fed through a charge door (or feed chute) above a carbonaceous bed of the PGVR or through a tuyere into the carbonaceous bed, either with or separate from a plasma torch plume. One apparatus that includes the injection of particulate material with a plasma torch plume is shown in U.S. Pat. No. 4,761,793, by Dighe, for a “Plasma Fired Feed Nozzle”, which is hereby incorporated by reference.
Embodiments include those in which gaseous products of the gasifier are supplied as a syngas to the incinerator and/or are supplied to a heat exchanger which may be interconnected with a heat recovery steam generator of the incinerator exhaust gas system.
Additional optional variations in the process and apparatus are described below, all of which are examples of the suitable techniques for ash treatment.
It is believed the described subject matter offers opportunities for improved, economical results in ash treatment. Among favorable aspects attainable are not only easier disposition of metal and other toxic constituents of ash because of a change of form (or vitrification), to solids from which those constituents are not likely to leach out of, but also the destruction of toxic materials such as dioxin and furan.
Referring to FIG. 1, a system is shown that includes an incinerator 10 and a gasification/vitrification reactor (GVR) 12. The incinerator 10 has a bottom ash outlet 13. A feed loop or passage in the form of a conduit 14 from the outlet 13 of incinerator 10 to the GVR 12 is provided for supplying bottom ash from the incinerator to the GVR.
The incinerator 10 includes an exhaust gas outlet 15 that is connected by a passage in the form of a conduit 16 to a fly ash recovery system 18 which, in this example, includes, in series, a heat recovery steam generator (or boiler) 20, a scrubber 22, and a bag filter 24 from each of which some fly ash is recovered from outlets 20a, 22a, and 24a respectively, of those individual components.
The steam generator 20 is shown with a supply of boiler feed water (BFW) and an outlet of steam (e.g., to be supplied to a turbine for power generation).
Fly ash, and incidental other matter, recovered from the outlets 20a, 22a, and 24a is combined together in a passage in the form of a conduit 26 that is connected to a passage in the form of a conduit 28 for supplying fly ash to the GVR 12. Some of the constituents collected from the outlets 20a, 22a, and 24a may exit the conduit 26 by a slip stream conduit 30 for further treatment and disposal outside the described system. It is usually intended to design and operate the system to maximize the amount of fly ash and related material from the conduit 26 fed to the GVR 12 via the conduit 28.
Recycling ash to the gasifier may still cause some volatile metals to go back up into the incinerator. Since not all metals can be removed in the slag, there may be a build-up of certain metals (e.g., mercury, lead, zinc and other) in the ash stream. A slip stream can be used to balance out such metals in the ash stream. The slip stream can have a much smaller mass than the original ash stream.
Some gaseous and other material from the incinerator exhaust 15 may pass through the fly ash recovery system 18 without being collected and such gaseous and other material can be exhausted as stack gas at an outlet 32. The scrubber 22 and bag filter 24, and/or possible other equipment, can provide sufficient collecting and cleaning of the emissions so the stack gas through outlet 32 is safe to discharge to the atmosphere. It is not necessary to discharge all carbon dioxide; any products of combustion can be usefully recycled back to the GVR 12 if desired.
The action of the GVR 12 results in significant destruction of toxic constituents of the fly ash streams from conduits 14 and 28, such as dioxin and furan, in addition to slag formation. Slag can be let out of the gasifier 12 through a bottom tap hole 12a when it is in a molten (or vitreous) form, and directed by a conduit 34 to a receptacle (not shown) for solidification. The solidified stag would contain major amounts of metal and other undesirable elements of the fly ash (as well as from the other feed material if used) treated in the GVR. Any slag formation process described herein may include the addition of fluxing agents to the GVR.
In addition, the example of FIG. 1 shows an upper outlet 12b of the GVR 10 for gaseous products of the GVR that can be fed through a conduit 36 as a syngas for combustion in the incinerator 10.
Tables 1 and 2 have data representative of the performance of the system shown in FIG. 1.







TABLE 1







Startup Initial Condition














2

4
5



1
Fly ash
3
Gasifier
Fly ash slip



Bottom ash
Recirculation
Slag
Carryover
stream


Component
kg/day
kg/day
kg/day
kg/day
kg/day















S
132.50
136.20
94.66
174.04
0.00


Cl
152.50
429.00
20.12
561.38
0.00


Si
3725.0
678.00
4400.80
2.20
0.00


Al
1917.50
473.40
2387.55
3.35
0.00


Ca
4050.00
942.00
4598.63
393.37
0.00


Fe
857.50
49.80
904.49
2.81
0.00


Na
477.50
224.40
608.90
93.00
0.00


K
205.00
184.80
316.95
72.85
0.00


Mg
582.50
157.20
733.41
6.29
0.00


P
170.00
28.80
198.24
0.56
0.00


B
2.75
0.90
3.20
0.45
0.00


Mn
15.50
1.92
17.37
0.05
0.00


Pb
18.50
5.46
1.23
22.73
0.00


Cd
0.50
0.36
0.01
0.85
0.00


As
0.07
0.04
0.00
0.11
0.00


Hg
0.02
0.01
0.00
0.03
0.00


Zn
94.00
51.84
35.61
110.23
0.00


Cu
51.25
15.96
59.34
7.87
0.00


Cr
8.50
1.74
10.24
0.00
0.00


Se
0.01
0.00
0.01
0.00
0.00


Sn
215.00
13.20
215.99
12.21
0.00


Oxygen in
12323.90
2604.96
13400.15
1528.72
0.00


oxides



Total
25000.00
6000.00
28006.91
2993.09
0.00


PCCD/PCDF
160
320
0.012
1


(dixoins)


(ng/g)


TEQ (ng/g)
1.5
3.7
0.0005
0.0064
















TABLE 2







Startup Initial Condition














2


5



1
Fly ash

4
Fly



Bottom
Recir-
3
Gasifier
ash slip



ash
culation
Slag
Carryover
stream


Component
kg/day
kg/day
kg/day
kg/day
kg/day















S
132.50
233.21
128.84
236.87
139.86


Cl
152.50
908.41
36.71
1024.21
544.79


Si
3725.0
425.12
4148.05
2.08
254.95


Al
1917.50
297.87
2212.26
3.10
178.64


Ca
4050.00
829.20
4494.72
384.48
497.28


Fe
857.50
32.86
887.60
2.76
19.70


Na
477.50
196.06
584.32
89.25
117.58


K
205.00
157.92
295.09
67.83
94.71


Mg
582.50
101.90
678.59
5.82
61.11


P
170.00
18.33
187.81
0.53
10.99


B
2.75
0.84
3.15
0.44
0.50


Mn
15.50
1.23
16.68
0.05
0.74


Pb
18.50
35.34
2.77
51.07
21.19


Cd
0.50
1.40
0.02
1.88
0.84


As
0.07
0.18
0.00
0.25
0.11


Hg
0.02
0.06
0.00
0.07
0.03


Zn
94.00
145.61
58.51
181.10
87.33


Cu
51.25
14.81
58.33
7.74
8.88


Cr
8.50
1.09
9.59
0.00
0.65


Se
0.01
0.00
0.01
0.00
0.00


Sn
215.00
15.98
218.62
12.36
9.58


Oxygen in
12323.90
2582.57
13380.05
1526.42
1548.82


oxides



Total
25000.00
5999.99
27401.70
3598.29
3598.30


PCCD/PCDF
160
~200
0.012
1
~200


(dixoins)


(ng/g)


TEQ (ng/g)
1.5
~2.3
0.0005
0.0064
~2.3









The tables show quantities of components at various locations in the system. Column numbers of the tables correspond to the single digits in FIG. 1. Column 1 refers to bottom ash from the incinerator 10 that passes through the conduit 14; column 2 refers to recirculated fly ash that passes through the conduit 28; column 3 refers to slag extracted out of the GVR through conduit 34; column 4 refers to GVR carryover (e.g., syngas) that passes through conduit 36; and column 5 refers to the slip stream from conduit 30. Table 1 shows the quantities under initial start-up conditions and Table 2 shows the quantities after the operation has reached an equilibrium condition. The quantities are listed in kilograms per day. Among the significant facts indicated by this data are that of a total ash output with metals and their oxides, plus S and Cl, of 25,000 kg/day in bottom ash and 65,000 kg/day in fly ash (i.e., a total of about 31,000 kg/day), at equilibrium the slag contains about 27,400 kg/day (or about 88%) of such materials in this example, leaving only a small amount in the slip stream to be otherwise disposed of.
Tables 1 and 2 also show that the dioxin and toxic equivalent (TEQ) content of the slip stream in column 5 is reduced from the quantities in the total ash quantities.
Some incinerators operate inefficiently, and leave a large amount of carbon in the bottom ash. By recycling the bottom ash and returning the gas produced in the gasifier over the grate of the incinerator, the incinerator temperature can be increased, thereby improving the carbon consumption within the incinerator itself.
FIG. 2 illustrates another example system. Like parts of the system of FIG. 2 are assigned the same reference numbers as in FIG. 1. Among the various differences from the system of FIG. 1 are: instead of supplying a syngas from a GVR 12 back to the incinerator 10, in FIG. 2 the ash is processed in a vitrification reactor (VR) 112. The energy used to vitrify the inert constituents may come from a fuel, from a waste stream having suitable energy content, and/or through the application of a plasma such as is used in a plasma vitrification reactor. This type of reactor can be operated under oxidizing conditions such that the gaseous output is flue gas. The flue gas output from an upper exit 112b passes to another ash recovery system 118 having a heat exchanger 120, a scrubber 122, and a bag filter 124 with ash, and possible other material, collected from the respective outlets 120a, 122a, and 124a going to a conduit 130 for withdrawal from the system and further treatment elsewhere. Gaseous effluent from the system 118 passes through a conduit 132 to a stack, along with gases in conduit 32 from the system 18. The heat exchanger 120 of the recovery system 118 has an inlet for boiler feed water (BFW) that is preheated by the VR emissions and then supplied to the heat recovery steam generator 20 of the recovery system 18.
In the system of FIG. 2, the reactor is used as a vitrifier that can fully combust any material within the vessel while slagging any ash component to the extent possible. Rather than recycling hot gas back to the incinerator, heat is recovered in a heat exchanger and used to heat boiler feed water that is used by the heat recovery steam generator 20. Then the output from the vitrifier is cleaned and exhausted. The system of FIG. 2 allows for customization of the clean-up equipment for the vitrifier exhaust gas flow (e.g., smaller size) and the specific metals/contaminants for the vitrifier exhaust gas stream. Overall, this may provide a better clean-up system, possibly with a lower emissions profile. In the system of FIG. 1, all gas from the gasifier is returned to the incinerator.
The system of FIG. 2 also differs from the system of FIG. 1 in that the fly ash collected by the fly ash recovery system 18 is supplied by a conduit 27 that is coupled to conduit 14, which has bottom ash from the incinerator 10, and the fly ash and bottom ash are supplied together to the VR 112.
Table 3 shows a stream summary showing an even greater diminishment in ash requiring additional treatment (hazardous waste disposal). The metals and oxides plus S and Cl, in slag from the VR, shown in column 3, amount of about 90% of those constituents in the ash as shown in columns 1 and 2 with correspondingly less ash for other treatment as shown in column 4. Additionally, the FIG. 2 system provides significantly reduced output amounts of dioxins and TEQ requiring other treatment. Of course, systems and processes as described herein may be usefully applied even without such results.







TABLE 3







Stream Summary















4



1
2
3
Ash For



Bottom ash
Fly ash
Slag
Treatment


Component
kg/day
kg/day
kg/day
kg/day














S
132.50
136.20
94.65
174.05


Cl
152.50
429.00
20.12
561.38


Si
3725.0
678.00
4400.67
2.33


Al
1917.00
473.40
2387.63
3.27


Ca
4050.00
942.00
4598.45
393.55


Fe
857.50
49.80
904.45
2.85


Na
477.50
224.40
608.87
93.03


K
205.00
184.80
316.93
72.87


Mg
582.50
157.20
733.38
6.32


P
170.00
28.80
198.24
0.56


B
2.75
0.90
3.20
0.45


Mn
15.50
1.92
17.37
0.05


Pb
18.50
5.46
1.23
22.73


Cd
0.50
0.36
0.01
0.85


As
0.07
0.04
0.00
0.11


Hg
0.02
0.01
0.00
0.03


Zn
94.00
51.84
35.61
110.23


Cu
51.25
15.96
59.34
7.87


Cr
8.50
1.74
10.24
0.00


Se
0.01
0.00
0.01
0.00


Sn
215.00
13.20
222.84
5.36


Oxygen in oxides
12323.90
2604.96
13400.57
1528.30


Total
25000.00
6000.00
28013.82
2986.18


PCCD/PCDF
160
320
0.012
1


(dixoins) (ng/g)


TEQ (ng/g)
1.5
3.7
0.0005
0.0064









Various features of the system of FIG. 2 may be applied individually to a system such as that of FIG. 1, as well as together in combination as shown in FIG. 2.
The scrubbers 22 and 122 of the above described systems may be arranged so their inputs, from a source (not shown) in addition to the components 20 and 120, respectively, include amounts of scrubbing agents such as lime and activated carbon.
Additional aspects of the systems that may be varied include: variations in reactor inputs of external feed materials, whether or not with the use of plasma torches; or variations in the amount of input air or oxygen to the reactor (e.g., to get more or less complete stoichiometric combustion), including: for a system such as that of FIG. 1 intended to produce a syngas for the incinerator 10, sub-stoichiometric amounts of air, oxygen, or both, that may be supplied (or allowed in) to the reactor 12, while more complete, stoichiometric, quantities can be present in the reactor of a system such as that of FIG. 2 for producing flue gas. In other embodiments, air, oxygen, or both, can be supplied to the vitrification reactor, wherein the amount of oxygen exceeds a stoichiometric amount.
In another embodiment, the system may be arranged with optionally operated conduits and valves so the same system can be operated in either a syngas mode or a flue gas mode when desired.
In addition to, or instead of, supplying syngas output from a GVR to an incinerator, as shown in FIG. 1, the syngas may have different downstream applications, e.g., for producing any one or more of heat, steam, power, and liquid fuels.
For optional operation in a flue gas mode, an additional burner may be provided in the top (e.g., the upper volume) of the reactor, for combusting syngas produced in the lower portion of the reactor, while adding air or oxygen, or both, to the syngas.
Any such production of flue gas from syngas may also be performed by sending the syngas to a combustor external to the GVR.
The ash recovery system 118 of FIG. 2 is an example of a dedicated gas cleanup system which may be used for either flue gas or syngas cleanup to remove fly ash, unreacted carbon, volatile metals, sulfur and chlorine species that may be present.
Any products of a cleanup system, such as system 118, may be introduced back into any incinerator (or GVR) in addition to, or instead of, released directly as stack gas to the atmosphere.
The system of FIG. 2 integrates the steam system from a boiler/heat exchanger on the vitrification reactor side with the steam system of the incinerator. The vitrification reactor steam system recovers some additional energy that would not otherwise be recovered. Carbon from the bottom ash and fly ash is combusted in the vitrification reactors and the energy is recovered as heat. This heat can be converted to steam and combined with the steam system of the incinerator for power production.
It will be apparent that further modifications, and combinations of modifications, of the described systems may be practiced as well. For example, in any system of either FIG. 1 or 2, and the mentioned variations, the reactor can be directly attached to the incinerator or can be free standing and connected with the incinerator by any needed conduits (which may be any form of passageways, e.g., in the form of metal ductwork or piping or masonry).
FIG. 3 shows a generalized schematic of an example system in which an incinerator 210 is combined, or integrated, with a reactor 212 that is close by, with a feed chute 213 for bottom ash from the incinerator having a feed leg 214 directly coupled to the reactor. In one embodiment, the illustrated ash feed chute apparatus 213 can include an internal diverter spool piece (not shown) for optional use, such as to divert ash from the reactor 212 when the reactor is shut down. FIG. 3 additionally shows a syngas exit 212b from the reactor 212 that has a direct connection with structure of the incinerator 210 at an interface 236.
The apparatus shown in FIG. 3 can be used for treatment in the reactor 212 of bottom ash from the incinerator 210 (normally of a much larger quantity than the fly ash likely to be produced by the incinerator). The apparatus of FIG. 3 could be further modified for fly ash treatment, such as according to FIG. 1 or 2. FIG. 4 shows a modification of FIG. 3 with a feed port 228 for introducing fly ash into the reactor 212. Using the example of FIGS. 3 and 4, certain conduits of FIGS. 1 and 2 can be replaced with other types of passages for delivering ash of additional materials to the reactor.
Some of the features of the apparatus of FIG. 3 that are present (or are optionally provided) are that air (oxygen) for the incinerator 210 and the reactor 212, facilitated by their close proximity, may come from the same air blower source (not shown). That would include air for gasification in the GVR 212 and also any air for other purposes such as GVR syngas combustion, if desired, and plasma torch gas or shroud gas, if used.
FIG. 3 shows the example reactor 212 that includes an inlet 238 into its upper region for syngas combustion air. Such a location can also be provided, optionally, with a burner (or igniter) for the syngas, to be used when desired. An upper part of the reactor 212 is referred to as a syngas secondary combustion zone in this example.
FIG. 3 shows an example reactor 212 that is a plasma GVR with plasma torches 240 for directing a plasma plume into a bottom section of the GVR (which would normally have a carbonaceous bed within it).
The reactor 212 also has an additional feed material inlet (nozzle or tuyere) 242 for any feed material in addition to the bottom ash from the incinerator 210. The additional feed material may be among any of those previously mentioned, or otherwise desired to be provided, including such things as medical waste, coke (or other carbonaceous) additions, and various mixtures of feed materials.
At the bottom of the reactor 212 is a tap hole 212a for slag output that flows through a conduit 234 to some receptacle. While a variety of reactor types may be used in the described systems, ones that stand out are plasma GVRs to gasify and/or vitrify the ash. Of particular interest are plasma GVRs of the type having a stationary bed of carbonaceous material (e.g., metallurgical coke or other carbon) in a bottom section of a vertical reactor structure with tuyeres for plasma torches and for possible inlet air, other gases and/or particulate solids. Particular examples of suitable plasma GVRs, and also the providing of carbonaceous beds that may include substantial amounts of carbon not from fossil fuels, can be found in U.S. Patent Application Publication No. 2010/0199557, Aug. 12, 2010, by Dighe et al., entitled “Plasma Gasification Reactor”; U.S. Patent Application Publication No. 2012/00061618, Mar. 15, 2012, by Santoianni et al.; and U.S. patent application Ser. No. 13/199,813, filed Sep. 9, 2011, by Gorodetsky et al., all of which are incorporated by reference herein for their descriptions of plasma GVRs, gasification systems, and their operation.
Additional PGVRs and their various uses are described in, for example, U.S. Pat. No. 7,632,394 by Dighe et al., issued Dec. 15, 2009, entitled “System and Process for Upgrading Heavy Hydrocarbons”; and U.S. Patent Application Publication No. 2009/0307974 by Dighe et al., entitled “System and Process for Reduction of Greenhouse Gas and Conversion of Biomass”; which are incorporated by reference herein for their descriptions of PGVRs and methods practiced with them.
While various embodiments of the invention have been described herein, it should be apparent, however, that various modifications, alterations and adaptations to those embodiments may occur to persons skilled in the art with the attainment of some or all of the advantages of the present invention. The disclosed embodiments are therefore intended to include all such modifications, alterations and adaptations without departing from the scope of the present invention as set forth in the appended claims.

## Claims

1. A method for treatment of ash from incineration plants, the method comprising:
collecting ash from an incinerator;
feeding the collected ash to a gasification/vitrification reactor;
vitrifying the ash in the gasification/vitrification reactor, to form a slag of molten material;
allowing the slag to flow from the gasification/vitrification reactor and solidify outside the gasification/vitrification reactor;
gasifying volatile components in the ash;
combusting syngas generated in the gasification/vitrification reactor in a secondary combustion zone in the gasification/vitrification reactor; and
supplying products of the syngas combustion to the incinerator to augment the thermal environments of the incinerator.

2. The method of claim 1, further comprising:
feeding additional feed material to the gasification/vitrification reactor, wherein the additional feed material comprises at least one of municipal solid waste (MSW), RDF, biomass, coal, hazardous waste, medical waste, liquid waste streams of coal or other carbonaceous products, or a combination thereof.

3. The method of claim 1, wherein the ash comprises:
bottom ash and the fly ash fed into the gasification/vitrification reactor together or separately.

4. The method of claim 1, wherein the ash is fed through a charge door or feed chute above a carbonaceous bed of the gasification/vitrification reactor.

5. The method of claim 1, wherein the ash is fed through a tuyere into a carbonaceous bed of the gasification/vitrification reactor.

6. The method of claim 1, wherein air or oxygen is fed into the secondary combustion zone in the gasification/vitrification reactor.

7. The method of claim 1, wherein the molten slag includes hazardous material from the additional feed material.

8. The method of claim 7, wherein the molten slag includes up to about 90% of the hazardous material from the additional feed material.

9. The method of claim 1, further comprising:
supplying sub-stoichiometric amounts of air, oxygen, or both, to the gasification/vitrification reactor.

10. The method of claim 1, wherein the products of syngas combustion flow into the incinerator in a direction opposite to the movement of the ash.

11. An apparatus comprising:
an incinerator;
a gasification/vitrification reactor;
a first feed passage for transporting bottom ash from a bottom of the incinerator to the gasification/vitrification reactor;
an interface connecting a secondary combustion zone in the gasification/vitrification reactor to the incinerator; and
a burner or an igniter for igniting syngas in the secondary combustion zone;
wherein the secondary combustion zone is configured to allow products of syngas combustion produced in the gasification/vitrification reactor to pass from the secondary combustion zone into the incinerator.

12. The apparatus of claim 11, further comprising:
an air inlet in a secondary combustion zone of the gasification/vitrification reactor to the incinerator.

13. The apparatus of claim 11, further comprising:
an incinerator exhaust gas fly ash recovery system; and
a second feed passage for transporting fly ash collected by the recovery system to the gasification/vitrification reactor.

14. The apparatus of claim 13, wherein the incinerator exhaust gas fly ash recovery system comprises one or more of:
a heat recovery steam generator; a boiler; a heat exchanger; a scrubber; and a bag filter, between the incinerator and an emission stack.