# Patent

## Title
Golf ball

## Abstract

A golf ball includes a spherical core and a cover. The core includes an inner core, a mid core, and an outer core. A hardness H(C) is equal to or greater than a hardness H(B). A hardness H(E) is equal to or greater than a hardness H(D). An angle α is calculated by (Formula 1) from a thickness Y (mm) of the mid core, the hardness H(C), and the hardness H(D). An angle β is calculated by (Formula 2) from a thickness Z (mm) of the outer core, the hardness H(E), and the hardness H(F). Each of the angle α and a difference (α−β) between the angles α and β is equal to or greater than 0°. The golf ball has excellent flight performance upon a shot with a driver.

α=(180/π)*a tan [{H(D)−H(C)}/Y]  (Formula 1)

β=(180/π)*a tan [{H(F)−H(E)}/Z]  (Formula 2)

## Background
This application claims priority on Patent Application No. 2013-224040 filed in JAPAN on Oct. 29, 2013. The entire contents of this Japanese Patent Application are hereby incorporated by reference.
BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to golf balls. Specifically, the present invention relates to golf balls that include a core and a cover.
Description of the Related Art
Golf players' foremost requirement for golf balls is flight performance. In particular, golf players place importance on flight performance upon a shot with a driver. Flight performance correlates with the resilience performance of a golf ball. When a golf ball having excellent resilience performance is hit, the golf ball flies at a high speed, thereby achieving a large flight distance.
An appropriate trajectory height is required in order to achieve a large flight distance. A trajectory height depends on a spin rate and a launch angle. With a golf ball that achieves a high trajectory by a high spin rate, a flight distance is insufficient. With a golf ball that achieves a high trajectory by a high launch angle, a large flight distance is obtained. Use of a core having an outer-hard/inner-soft structure can achieve a low spin rate and a high launch angle.
Golf balls for which a hardness distribution of a core has been examined in light of achievement of various performance characteristics are disclosed in JP2012-223569 (US2012/0270680), JP2012-223570 (US2012/0270681), JP2012-223571 (US2012/0270679), and JP2012-223572 (US2012/0270678).
JP2012-223571 discloses a golf ball that includes a core having a three-layer structure. In the core, a first layer, a second layer, and a third layer are formed from the central point of the core toward the surface of the core. The hardness gradient of the third layer of the core is greater than the hardness gradient of the second layer. JP2012-223569, JP2012-223570, and JP2012-223572 also disclose similar golf balls. In the core of the golf ball disclosed in JP2012-223569, the hardness of the second layer at a boundary portion between the first layer and the second layer is less than the hardness of the first layer. In the core of the golf ball disclosed in JP2012-223570, the hardness of the third layer at a boundary portion between the second layer and the third layer is less than the hardness of the second layer. JP2012-223572 discloses a core in which the hardness of the second layer at a boundary portion between the first layer and the second layer is less than the hardness of the first layer and the hardness of the third layer at a boundary portion between the second layer and the third layer is less than the hardness of the second layer.
In recently years, golf players' requirements for flight performance have been escalated more than ever. A golf ball with which a large flight distance is obtained upon a shot with a driver without impairing excellent performance such as approach performance, feel at impact, and the like, is longed for. The inventors of the present invention have found that a hardness gradient in a specific region of a core contributes to an increase in a flight distance upon a shot with a driver, and have completed the present invention by optimizing the hardness distribution of the entire core.
An object of the present invention is to provide a golf ball having excellent flight performance.
SUMMARY OF THE INVENTION
A golf ball according to the present invention includes a spherical core and a cover positioned outside the core. The core includes an inner core, amid core positioned outside the inner core, and an outer core positioned outside the mid core. A JIS-C hardness H(C) at a point C present outward from a boundary between the inner core and the mid core in a radius direction by 1 mm is equal to or greater than a JIS-C hardness H(B) at a point B present inward from the boundary between the inner core and the mid core in the radius direction by 1 mm. A JIS-C hardness H(E) at a point E present outward from a boundary between the mid core and the outer core in the radius direction by 1 mm is equal to or greater than a JIS-C hardness H(D) at a point D present inward from the boundary between the mid core and the outer core in the radius direction by 1 mm. When an angle (degree) calculated by (Formula 1) from a thickness Y (mm) of the mid core, the hardness H(C), and the hardness H(D) is defined as an angle α and an angle (degree) calculated by (Formula 2) from a thickness Z (mm) of the outer core, the hardness H(E), and a JIS-C hardness H(F) at a point F located on a surface of the core is defined as an angle β:

α=(180/π)*a tan [{H(D)−H(C)}/Y]  (Formula 1); and

β=(180/π)*a tan [{H(F)−H(E)}/Z]  (Formula 2),

the angle α is equal to or greater than 0°, and a difference (α−β) between the angle α and the angle β is equal to or greater than 0°.

In the golf ball according to the present invention, a hardness distribution of the core is appropriate. The golf ball has excellent resilience performance. When the golf ball is hit with a driver, the ball speed is high. When the golf ball is hit with a driver, the spin rate is low. The highball speed and the low spin rate achieve a large flight distance. The golf ball has excellent flight performance.
Preferably, the angle β is equal to or greater than −20° but equal to or less than +20°.
Preferably, a ratio (Y/X) of the thickness Y of the mid core relative to a radius X of the inner core is equal to or greater than 0.5 but equal to or less than 2.0. Preferably, a ratio (Z/X) of the thickness Z of the outer core relative to the radius X is equal to or greater than 0.5 but equal to or less than 2.5.
Preferably, a ratio (S2/S1) of a cross-sectional area S2 of the mid core relative to a cross-sectional area S1 of the inner core on a cut surface of the core that has been cut into two halves is equal to or greater than 1.0 but equal to or less than 8.0. Preferably, a ratio (S3/S1) of a cross-sectional area S3 of the outer core relative to the cross-sectional area S1 on the cut surface of the core is equal to or greater than 2.5 but equal to or less than 12.5.
Preferably, a ratio (V2/V1) of a volume V2 of the mid core relative to a volume V1 of the inner core is equal to or greater than 2.5 but equal to or less than 20.0. Preferably, a ratio (V3/V1) of a volume V3 of the outer core relative to the volume V1 is equal to or greater than 10.0 but equal to or less than 57.0.
Preferably, the golf ball further includes a mid layer between the core and the cover. Preferably, the mid layer includes an inner mid layer and an outer mid layer positioned outside the inner mid layer. Preferably, the cover includes an inner cover and an outer cover positioned outside the inner cover.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a cross-sectional view of a golf ball according to one embodiment of the present invention; and
FIG. 2 is a graph showing a hardness distribution of a core of the golf ball in FIG. 1.



DESCRIPTION OF THE PREFERRED EMBODIMENTS
The following will describe in detail the present invention, based on preferred embodiments with reference to the accompanying drawing.
FIG. 1 is a partially cutaway cross-sectional view of a golf ball 2 according one embodiment of the present invention. The golf ball 2 includes a spherical core 4, a mid layer 6 positioned outside the core 4, a reinforcing layer 8 positioned outside the mid layer 6, and a cover 10 positioned outside the reinforcing layer 8. The core 4 includes an inner core 12, a mid core 14 positioned outside the inner core 12, and an outer core 16 positioned outside the mid core 14. On the surface of the cover 10, a large number of dimples 18 are formed. Of the surface of the cover 10, a part other than the dimples 18 is a land 20. The golf ball 2 includes a paint layer and a mark layer on the external side of the cover 10, but these layers are not shown in the drawing.
The golf ball 2 has a diameter of 40 mm or greater but 45 mm or less. From the standpoint of conformity to the rules established by the United States Golf Association (USGA), the diameter is preferably equal to or greater than 42.67 mm. In light of suppression of air resistance, the diameter is preferably equal to or less than 44 mm and more preferably equal to or less than 42.80 mm. The golf ball 2 has a weight of 40 g or greater but 50 g or less. In light of attainment of great inertia, the weight is preferably equal to or greater than 44 g and more preferably equal to or greater than 45.00 g. From the standpoint of conformity to the rules established by the USGA, the weight is preferably equal to or less than 45.93 g.
In the present invention, a JIS-C hardness H(A) at the central point A of the core 4, a JIS-C hardness H(B) at a point B inward from the boundary between the inner core 12 and the mid core 14 in a radius direction by 1 mm, a JIS-C hardness H(C) at a point C outward from the boundary between the inner core 12 and the mid core 14 in the radius direction by 1 mm, a JIS-C hardness H(D) at a point D inward from the boundary between the mid core 14 and the outer core 16 in the radius direction by 1 mm, a JIS-C hardness H(E) at a point E outward from the boundary between the mid core 14 and the outer core 16 in the radius direction by 1 mm, and a JIS-C hardness H(F) at a point F located on the surface of the core 4 are measured. The hardnesses H(A) to H(E) are measured by pressing a JIS-C type hardness scale against a cut plane of the core 4 that has been cut into two halves. The hardness H(F) is measured by pressing the JIS-C type hardness scale against the surface of the spherical core 4. For the measurement, an automated rubber hardness measurement machine (trade name “P1”, manufactured by Kobunshi Keiki Co., Ltd.), to which this hardness scale is mounted, is used.
FIG. 2 is a line graph showing a hardness distribution of the core 4 of the golf ball 2 in FIG. 1. The horizontal axis of the graph indicates the distance (mm) from the central point of the core 4 to each measuring point. The vertical axis of the graph indicates a JIS-C hardness at each measuring point. The distances and the hardnesses measured at the points A to F are plotted on the graph.
As shown in FIG. 2, the hardness H(C) is greater than the hardness H(B). In the core 4, the hardness of the mid core 14 at a boundary portion between the inner core 12 and the mid core 14 is greater than the hardness of the inner core 12. As further shown, the hardness H(E) is greater than the hardness H(D). In the core 4, the hardness of the outer core 16 at a boundary portion between the mid core 14 and the outer core 16 is greater than the hardness of the mid core 14. In other words, in the core 4, the hardness increases stepwise from its inner side toward its outer side in the radius direction. When the golf ball 2 that includes the core 4 is hit with a driver, the spin rate is low. The low spin rate achieves a large flight distance. The hardness H(B) and the hardness H(C) may be the same, and the hardness H(D) and the hardness H(E) may be the same.
In light of suppression of spin, the difference [H(C)−H(B)] between the hardness H(C) and the hardness H(B) is preferably equal to or greater than 3 and more preferably equal to or greater than 5. In light of durability, the difference [H(C)−H(B)] is preferably equal to or less than 20.
In light of suppression of spin, the difference [H(E)−H(D)] between the hardness H(E) and the hardness H(D) is preferably equal to or greater than 5 and more preferably equal to or greater than 8. In light of durability, the difference [H(E)−H(D)] is preferably equal to or less than 25.
In the present invention, an angle α is calculated by the following (Formula 1):

α=(180/π)*a tan [{H(D)−H(C)}/Y]  (Formula 1),

wherein Y is the thickness (mm) of the mid core 14.

In the present invention, an angle β is calculated by the following (Formula 2):

α=(180/π)*a tan [{H(F)−H(E)}/Z]  (Formula 2),

wherein Z is the thickness (mm) of the outer core 16.

The angle β is smaller than the angle α. This means that a hardness gradient formed in the outer core 16 is less than a hardness gradient formed in the mid core 14. The core 4 has excellent resilience performance. When the golf ball 2 that includes the core 4 is hit with a driver, the ball speed is high. The high ball speed achieves a large flight distance. The angle α and the angle β may be the same.
Preferably, the difference (α−β) between the angle α and the angle β is equal to or greater than 0°. In light of flight performance, the difference (α−β) is preferably equal to or greater than 10°, more preferably equal to or greater than 15°, and particularly preferably equal to or greater than 20°. In light of durability, the difference (α−β) is preferably equal to or less than 60°. Preferably, the absolute value of the angle α is greater than the absolute value of the angle β.
In light of suppression of spin, the angle α is preferably equal to or greater than 0°. The angle α is more preferably equal to or greater than 20° and further preferably equal to or greater than 30°. In light of durability, the angle α is preferably equal to or less than 60°.
From the standpoint that a ball speed is high upon hitting, the angle β is preferably equal to or greater than −20° but equal to or less than +20°. The angle β is more preferably equal to or greater than −15° but equal to or less than +15°, and further preferably equal to or greater than −10° but equal to or less than +10°.
The inner core 12 is formed by crosslinking a rubber composition. Examples of the base rubber of the rubber composition include polybutadienes, polyisoprenes, styrene-butadiene copolymers, ethylene-propylene-diene copolymers, and natural rubbers. In light of resilience performance, polybutadienes are preferred. When a polybutadiene and another rubber are used in combination, it is preferred if the polybutadiene is included as a principal component. Specifically, the proportion of the polybutadiene to the entire base rubber is preferably equal to or greater than 50% by weight and more preferably equal to or greater than 80% by weight. The proportion of cis-1,4 bonds in the polybutadiene is preferably equal to or greater than 40% and more preferably equal to or greater than 80%.
Preferably, the rubber composition of the inner core 12 includes a co-crosslinking agent. The co-crosslinking agent achieves high resilience performance of the inner core 12. Examples of preferable co-crosslinking agents in light of resilience performance include monovalent or bivalent metal salts of an α,β-unsaturated carboxylic acid having 2 to 8 carbon atoms. A metal salt of an α,β-unsaturated carboxylic acid graft-polymerizes with the molecular chain of the base rubber, thereby crosslinking the rubber molecules. Examples of preferable metal salts of an α,β-unsaturated carboxylic acid include zinc acrylate, magnesium acrylate, zinc methacrylate, and magnesium methacrylate. Zinc acrylate and zinc methacrylate are more preferred.
As a co-crosslinking agent, an α,β-unsaturated carboxylic acid having 2 to 8 carbon atoms and a metal compound may also be included. The metal compound reacts with the α,β-unsaturated carboxylic acid in the rubber composition. A salt obtained by this reaction graft-polymerizes with the molecular chain of the base rubber. Examples of preferable α,β-unsaturated carboxylic acids include acrylic acid and methacrylic acid.
Examples of preferable metal compounds include metal hydroxides such as magnesium hydroxide, zinc hydroxide, calcium hydroxide, and sodium hydroxide; metal oxides such as magnesium oxide, calcium oxide, zinc oxide, and copper oxide; and metal carbonates such as magnesium carbonate, zinc carbonate, calcium carbonate, sodium carbonate, lithium carbonate, and potassium carbonate. Metal oxides are preferred. Oxides including a bivalent metal are more preferred. An oxide including a bivalent metal reacts with the co-crosslinking agent to form metal crosslinks. Examples of particularly preferable metal oxides include zinc oxide and magnesium oxide.
In light of resilience performance, the amount of the co-crosslinking agent per 100 parts by weight of the base rubber is preferably equal to or greater than 20 parts by weight and more preferably equal to or greater than 25 parts by weight. In light of soft feel at impact, the amount of the co-crosslinking agent per 100 parts by weight of the base rubber is preferably equal to or less than 50 parts by weight and more preferably equal to or less than 45 parts by weight.
Preferably, the rubber composition of the inner core 12 includes an organic peroxide together with the co-crosslinking agent. The organic peroxide serves as a crosslinking initiator. The organic peroxide contributes to the resilience performance of the golf ball 2. Examples of suitable organic peroxides include dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, and di-t-butyl peroxide. In light of versatility, dicumyl peroxide is preferred.
In light of resilience performance, the amount of the organic peroxide per 100 parts by weight of the base rubber is preferably equal to or greater than 0.1 parts by weight, more preferably equal to or greater than 0.3 parts by weight, and particularly preferably equal to or greater than 0.5 parts by weight. In light of soft feel at impact, the amount of the organic peroxide per 100 parts by weight of the base rubber is preferably equal to or less than 2.0 parts by weight, more preferably equal to or less than 1.5 parts by weight, and particularly preferably equal to or less than 1.2 parts by weight.
Preferably, the rubber composition of the inner core 12 includes an organic sulfur compound. Examples of preferable organic sulfur compounds include monosubstitutions such as diphenyl disulfide, bis(4-chlorophenyl)disulfide, bis(3-chlorophenyl)disulfide, bis(4-bromophenyl)disulfide, bis(3-bromophenyl)disulfide, bis(4-fluorophenyl)disulfide, bis(4-iodophenyl)disulfide, bis(4-cyanophenyl)disulfide, and the like; disubstitutions such as bis(2,5-dichlorophenyl)disulfide, bis(3,5-dichlorophenyl)disulfide, bis(2,6-dichlorophenyl)disulfide, bis(2,5-dibromophenyl)disulfide, bis(3,5-dibromophenyl)disulfide, bis(2-chloro-5-bromophenyl)disulfide, bis(2-cyano-5-bromophenyl)disulfide, and the like; trisubstitutions such as bis(2,4,6-trichlorophenyl)disulfide, bis(2-cyano-4-chloro-6-bromophenyl)disulfide, and the like; tetrasubstitutions such as bis(2,3,5,6-tetrachlorophenyl)disulfide and the like; and pentasubstitutions such as bis(2,3,4,5,6-pentachlorophenyl)disulfide, bis(2,3,4,5,6-pentabromophenyl)disulfide, and the like. Other examples of preferable organic sulfur compounds include thionaphthols such as 2-thionaphthol, 1-thionaphthol, 2-chloro-1-thionaphthol, 2-bromo-1-thionaphthol, 2-fluoro-1-thionaphthol, 2-cyano-1-thionaphthol, 2-acetyl-1-thionaphthol, 1-chloro-2-thionaphthol, 1-bromo-2-thionaphthol, 1-fluoro-2-thionaphthol, 1-cyano-2-thionaphthol, 1-acetyl-2-thionaphthol, and the like; and metal salts thereof. The organic sulfur compound contributes to resilience performance. More preferable organic sulfur compounds are diphenyl disulfide, bis(pentabromophenyl)disulfide, and 2-thionaphthol.
In light of resilience performance, the amount of the organic sulfur compound per 100 parts by weight of the base rubber is preferably equal to or greater than 0.1 parts by weight and more preferably equal to or greater than 0.2 parts by weight. In light of resilience performance, the amount is preferably equal to or less than 3.0 parts by weight and more preferably equal to or less than 2.0 parts by weight.
The rubber composition of the inner core 12 may include a fatty acid or a fatty acid metal salt. It is thought that the fatty acid or the fatty acid metal salt contributes to formation of the hardness distribution of the core 4 by inhibiting formation of metal crosslinks by the co-crosslinking agent or cutting the metal crosslinks during heating and forming of the inner core 12. When a fatty acid or a fatty acid metal salt is added, a preferable amount thereof is equal to or greater than 0.5 parts by weight but equal to or less than 20 parts by weight, per 100 parts by weight of the base rubber.
A fatty acid metal salt is preferred from the standpoint that an appropriate hardness distribution is obtained. Examples of the fatty acid metal salt include potassium salts, magnesium salts, aluminum salts, zinc salts, iron salts, copper salts, nickel salts, and cobalt salts of octanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, and behenic acid. Zinc salts of fatty acids are particularly preferred. Specific examples of preferable zinc salts of fatty acids include zinc octoate, zinc laurate, zinc myristate, and zinc stearate.
For the purpose of adjusting specific gravity and the like, a filler may be included in the inner core 12. Examples of suitable fillers include zinc oxide, barium sulfate, calcium carbonate, and magnesium carbonate. Powder of a metal with a high specific gravity may be included as a filler. Specific examples of metals with a high specific gravity include tungsten and molybdenum. A particularly preferable filler is zinc oxide. Zinc oxide serves not only as a specific gravity adjuster but also as a crosslinking activator. The amount of the filler is determined as appropriate so that the intended specific gravity of the inner core 12 is accomplished.
According to need, various additives such as sulfur, an anti-aging agent, a coloring agent, a plasticizer, a dispersant, and the like are included in the inner core 12 in an adequate amount. Crosslinked rubber powder or synthetic resin powder may also be included in the inner core 12. The temperature for crosslinking the inner core 12 is generally equal to or higher than 140° C. but equal to or lower than 180° C. The time period for crosslinking the inner core 12 is generally equal to or longer than 10 minutes but equal to or shorter than 60 minutes.
The central hardness of the inner core 12 is the same as the aforementioned JIS-C hardness H(A) at the central point A of the core 4. The hardness H(A) is preferably equal to or greater than 30 but equal to or less than 75. The inner core 12 having a hardness H(A) of 30 or greater can achieve excellent resilience performance. In this respect, the hardness H(A) is more preferably equal to or greater than 35 and particularly preferably equal to or greater than 40. The inner core 12 having a hardness H(A) of 75 or less suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(A) is more preferably equal to or less than 73 and particularly preferably equal to or less than 70.
The JIS-C hardness H(B) at the point B inward from the boundary between the inner core 12 and the mid core 14 in the radius direction by 1 mm is preferably equal to or greater than 35 but equal to or less than 80. The inner core 12 having a hardness H(B) of 35 or greater suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(B) is more preferably equal to or greater than 40 and particularly preferably equal to or greater than 45. The inner core 12 having a hardness H(B) of 80 or less achieves excellent durability. In this respect, the hardness H(B) is more preferably equal to or less than 75 and particularly preferably equal to or less than 70.
Preferably, the hardness H(B) is greater than the hardness H(A). The inner core 12 contributes to formation of an outer-hard/inner-soft structure. In light of suppression of spin upon a shot with a driver, the difference [H(B)−H(A)] between the hardness H(B) and the hardness H(A) is preferably equal to or greater than 1 and more preferably equal to or greater than 3. In light of resilience performance, the difference [H(B)−H(A)] is preferably equal to or less than 10.
The radius X of the inner core 12 can be set as appropriate such that later-described conditions are met. In light of resilience performance, the radius X is preferably equal to or greater than 2.0 mm and more preferably equal to or greater than 5.0 mm. The radius X is preferably equal to or less than 12.0 mm.
A cross-sectional area S1 of the inner core 12 is measured on a cut plane of the spherical core 4 that has been cut into two halves. The cross-sectional area S1 can be set as appropriate such that later-described conditions are met. In light of resilience performance, the cross-sectional area S1 is preferably equal to or greater than 12 mm2 and more preferably equal to or greater than 78 mm2. The cross-sectional area S1 is preferably equal to or less than 450 mm2.
The volume V1 of the inner core 12 can be set as appropriate such that later-described conditions are met. In light of resilience performance, the volume V1 is preferably equal to or greater than 33 mm3 and more preferably equal to or greater than 520 mm3. The volume V1 is preferably equal to or less than 7200 mm3.
In light of feel at impact, the inner core 12 has an amount of compressive deformation of preferably 1.0 mm or greater, more preferably 1.2 mm or greater, and particularly preferably 1.3 mm or greater. In light of resilience performance, the amount of compressive deformation is preferably equal to or less than 4.0 mm, more preferably equal to or less than 3.5 mm, and particularly preferably equal to or less than 3.0 mm.
For measurement of the amount of compressive deformation, a YAMADA type compression tester is used. In the tester, the inner core 12 that is an object to be measured is placed on a hard plate made of metal. Next, a cylinder made of metal gradually descends toward the inner core 12. The inner core 12, squeezed between the bottom face of the cylinder and the hard plate, becomes deformed. A migration distance of the cylinder, starting from the state in which an initial load of 98 N is applied to the inner core 12 up to the state in which a final load of 294 N is applied thereto, is measured. A moving speed of the cylinder until the initial load is applied is 0.83 mm/s. A moving speed of the cylinder after the initial speed is applied until the final load is applied is 1.67 mm/s.
The mid core 14 is formed by crosslinking a rubber composition. As the base rubber of the rubber composition of the mid core 14, the base rubber described above for the inner core 12 can be used. In light of resilience performance, polybutadienes are preferred, and high-cis polybutadienes are particularly preferred.
The rubber composition of the mid core 14 can include the co-crosslinking agent described above for the inner core 12. Preferable co-crosslinking agents in light of resilience performance are acrylic acid, methacrylic acid, zinc acrylate, magnesium acrylate, zinc methacrylate, and magnesium methacrylate. The rubber composition further includes the metal compound described above for the inner core 12. Examples of preferable metal compounds include magnesium oxide and zinc oxide.
The rubber composition of the mid core 14 can include the organic peroxide described above for the inner core 12. Examples of preferable organic peroxides include dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, and di-t-butyl peroxide.
Preferably, the rubber composition of the mid core 14 can include the organic sulfur compound described above for the inner core 12. Preferable organic sulfur compounds are diphenyl disulfide, bis(pentabromophenyl)disulfide, and 2-thionaphthol. The rubber composition of the mid core 14 may include the fatty acid or the fatty acid metal salt described above for the inner core 12.
According to need, various additives such as a filler, sulfur, a vulcanization accelerator, an anti-aging agent, a coloring agent, a plasticizer, a dispersant, and the like are included in the rubber composition of the mid core 14 in an adequate amount. The temperature for crosslinking the mid core 14 is generally equal to or higher than 140° C. but equal to or lower than 180° C. The time period for crosslinking the mid core 14 is generally equal to or longer than 10 minutes but equal to or shorter than 60 minutes.
The JIS-C hardness H(C) at the point C outward from the boundary between the inner core 12 and the mid core 14 in the radius direction by 1 mm is preferably equal to or greater than 60 but equal to or less than 90. The mid core 14 having a hardness H(C) of 60 or greater can achieve excellent resilience performance. In this respect, the hardness H(C) is more preferably equal to or greater than 63 and particularly preferably equal to or greater than 65. The mid core 14 having a hardness H(C) of 90 or less suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(C) is more preferably equal to or less than 85 and particularly preferably equal to or less than 80.
The JIS-C hardness H(D) at the point D inward from the boundary between the mid core 14 and the outer core 16 in the radius direction by 1 mm is preferably equal to or greater than 65 but equal to or less than 95. The mid core 14 having a hardness H(D) of 65 or greater suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(D) is more preferably equal to or greater than 68 and particularly preferably equal to or greater than 70. The mid core 14 having a hardness H(D) of 95 or less achieves excellent durability. In this respect, the hardness H(D) is more preferably equal to or less than 90 and particularly preferably equal to or less than 85.
In light of suppression of spin upon a shot with a driver, the difference [H(D)−H(C)] between the hardness H(D) and the hardness H(C) is preferably equal to or greater than 0 and more preferably equal to or greater than 3. In light of durability, the difference [H(D)−H(C)] is preferably equal to or less than 15.
The thickness Y of the mid core 14 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the thickness Y is preferably equal to or greater than 1.0 mm and more preferably equal to or greater than 4.5 mm. The thickness Y is preferably equal to or less than 11.0 mm.
A cross-sectional area S2 of the mid core 14 is measured on a cut plane of the spherical core 4 that has been cut into two halves. The cross-sectional area S2 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the cross-sectional area S2 is preferably equal to or greater than 50 mm2 and more preferably equal to or greater than 270 mm2. The cross-sectional area S2 is preferably equal to or less than 680 mm2.
The volume V2 of the mid core 14 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the volume V2 is preferably equal to or greater than 800 mm3 and more preferably equal to or greater than 5400 mm3. The volume V2 is preferably equal to or less than 17500 mm3.
In light of feel at impact, a sphere consisting of the inner core 12 and the mid core 14 has an amount of compressive deformation of preferably 3.0 mm or greater, more preferably 3.5 mm or greater, and particularly preferably 4.0 mm or greater. In light of resilience performance, the amount of compressive deformation is preferably equal to or less than 7.0 mm, more preferably equal to or less than 6.8 mm, and particularly preferably equal to or less than 6.5 mm.
For measurement of the amount of compressive deformation, a YAMADA type compression tester is used. In the tester, the sphere consisting of the inner core 12 and the mid core 14 which sphere is an object to be measured is placed on a hard plate made of metal. Next, a cylinder made of metal gradually descends toward the sphere. The sphere, squeezed between the bottom face of the cylinder and the hard plate, becomes deformed. A migration distance of the cylinder, starting from the state in which an initial load of 98 N is applied to the sphere up to the state in which a final load of 1274 N is applied thereto, is measured. A moving speed of the cylinder until the initial load is applied is 0.83 mm/s. A moving speed of the cylinder after the initial speed is applied until the final load is applied is 1.67 mm/s.
The outer core 16 is formed by crosslinking a rubber composition. As the base rubber of the rubber composition of the outer core 16, the base rubber described above for the inner core 12 can be used. In light of resilience performance, polybutadienes are preferred, and high-cis polybutadienes are particularly preferred.
The rubber composition of the outer core 16 can include the co-crosslinking agent described above for the inner core 12. Preferable co-crosslinking agents in light of resilience performance are acrylic acid, methacrylic acid, zinc acrylate, magnesium acrylate, zinc methacrylate, and magnesium methacrylate. The rubber composition further includes the metal compound described above for the inner core 12. Examples of preferable metal compounds include magnesium oxide and zinc oxide.
The rubber composition of the outer core 16 can include the organic peroxide described above for the inner core 12. Examples of preferable organic peroxides include dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, and di-t-butyl peroxide.
Preferably, the rubber composition of the outer core 16 can include the organic sulfur compound described above for the inner core 12. Preferable organic sulfur compounds are diphenyl disulfide, bis(pentabromophenyl)disulfide, and 2-thionaphthol. The rubber composition of the outer core 16 may include the fatty acid or the fatty acid metal salt described above for the inner core 12.
According to need, various additives such as a filler, sulfur, a vulcanization accelerator, an anti-aging agent, a coloring agent, a plasticizer, a dispersant, and the like are included in the rubber composition of the outer core 16 in an adequate amount. The temperature for crosslinking the outer core 16 is generally equal to or higher than 140° C. but equal to or lower than 180° C. The time period for crosslinking the outer core 16 is generally equal to or longer than 10 minutes but equal to or shorter than 60 minutes.
The JIS-C hardness H(E) at the point E outward from the boundary between the mid core 14 and the outer core 16 in the radius direction by 1 mm is preferably equal to or greater than 75 but equal to or less than 100. The outer core 16 having a hardness H(E) of 75 or greater can achieve excellent resilience performance. In this respect, the hardness H(E) is more preferably equal to or greater than 78 and particularly preferably equal to or greater than 80. The outer core 16 having a hardness H(E) of 100 or less suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(E) is more preferably equal to or less than 95 and particularly preferably equal to or less than 93.
The JIS-C hardness H(F) at the point F located on the surface of the core 4 consisting of the inner core 12, the mid core 14, and the outer core 16 is preferably equal to or greater than 75 but equal to or less than 100. The outer core 16 having a hardness H(F) of 75 or greater suppresses excessive spin upon a shot with a driver. In this respect, the hardness H(F) is more preferably equal to or greater than 78 and particularly preferably equal to or greater than 80. The outer core 16 having a hardness H(F) of 100 or less achieves excellent durability. In this respect, the hardness H(F) is more preferably equal to or less than 95 and particularly preferably equal to or less than 93. The hardness H(F) is measured by pressing a JIS-C type hardness scale against the surface of the core 4. For the measurement, an automated rubber hardness measurement machine (trade name “P1”, manufactured by Kobunshi Keiki Co., Ltd.), to which this hardness scale is mounted, is used.
In light of suppression of spin upon a shot with a driver, the difference [H(F)−H(E)] between the hardness H(F) and the hardness H(E) is preferably equal to or greater than −5 and more preferably equal to or greater than −2. In light of durability, the difference [H(F)−H(E)] is preferably equal to or less than 5.
In light of suppression of spin upon a shot with a driver, the difference [H(F)−H(A)] between the hardness H(F) and the hardness H(A) is preferably equal to or greater than 20 and more preferably equal to or greater than 24. In light of durability, the difference [H(F)−H(A)] is preferably equal to or less than 40.
The thickness Z of the outer core 16 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the thickness Z is preferably equal to or greater than 3.0 mm and more preferably equal to or greater than 5.0 mm. The thickness Z is preferably equal to or less than 12.0 mm.
A cross-sectional area S3 of the outer core 16 is measured on a cut plane of the spherical core 4 that has been cut into two halves. The cross-sectional area S3 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the cross-sectional area S3 is preferably equal to or greater than 380 mm2 and more preferably equal to or greater than 590 mm2. The cross-sectional area S3 is preferably equal to or less than 1020 mm2.
The volume V3 of the outer core 16 can be set as appropriate such that the later-described conditions are met. In light of resilience performance, the volume V3 is preferably equal to or greater than 13500 mm3 and more preferably equal to or greater than 18700 mm3. The volume V3 is preferably equal to or less than 30200 mm3.
In light of the resilience performance, the core 4 has a diameter of preferably 36.5 mm or greater, more preferably 37.0 mm or greater, and particularly preferably 37.5 mm or greater. The diameter is preferably equal to or less than 42.0 mm, more preferably equal to or less than 41.0 mm, and particularly preferably equal to or less than 40.2 mm. The core 4 has a weight of preferably 25 g or greater but 42 g or less.
In light of feel at impact, the core 4 has an amount of compressive deformation Dc of preferably 2.0 mm or greater and particularly preferably 2.5 mm or greater. In light of resilience performance of the core 4, the amount of compressive deformation Dc is preferably equal to or less than 4.8 mm and particularly preferably equal to or less than 4.5 mm. The amount of compressive deformation Dc of the core 4 is measured by the same measurement method as that for the amount of compressive deformation of the sphere consisting of the inner core 12 and the mid core 14.
With the golf ball 2 according to the present invention, excellent flight performance is achieved upon a shot with a driver by relatively controlling the hardness gradient of the mid core 14 and the hardness gradient of the outer core 16. An appropriate arrangement of the inner core 12, the mid core 14, and the outer core 16 contributes to optimization of a hardness distribution.
In light of suppression of spin upon a shot with a driver, the ratio (Y/X) of the thickness Y of the mid core 14 relative to the radius X of the inner core 12 is preferably equal to or greater than 0.5, more preferably equal to or greater than 0.6, and particularly preferably equal to or greater than 0.8. From the standpoint that a high ball speed is obtained, the ratio (Y/X) is preferably equal to or less than 2.0, more preferably equal to or less than 1.7, and particularly preferably equal to or less than 1.4.
In light of suppression of spin upon a shot with a driver, the ratio (Z/X) of the thickness Z of the outer core 16 relative to the radius X of the inner core 12 is preferably equal to or greater than 0.5, more preferably equal to or greater than 0.7, and particularly preferably equal to or greater than 0.9. From the standpoint that a high ball speed is obtained, the ratio (Z/X) is preferably equal to or less than 2.5 and more preferably equal to or less than 2.0.
In light of flight performance, the ratio (Y/Z) of the thickness Y of the mid core 14 relative to the thickness Z of the outer core 16 is equal to or greater than 0.25 but equal to or less than 3.0.
In light of suppression of spin upon a shot with a driver, the ratio (S2/S1) of the cross-sectional area S2 of the mid core 14 relative to the cross-sectional area S1 of the inner core 12 is preferably equal to or greater than 1.0, more preferably equal to or greater than 1.5, and particularly preferably equal to or greater than 2.0. From the standpoint that a high ball speed is obtained, the ratio (S2/S1) is preferably equal to or less than 8.0, more preferably equal to or less than 6.5, and particularly preferably equal to or less than 6.0.
In light of suppression of spin upon a shot with a driver, the ratio (S3/S1) of the cross-sectional area S3 of the outer core 16 relative to the cross-sectional area S1 of the inner core 12 is preferably equal to or greater than 2.5 and more preferably equal to or greater than 3.0. From the standpoint that a high ball speed is obtained, the ratio (S3/S1) is preferably equal to or less than 12.5, more preferably equal to or less than 12.0, and particularly preferably equal to or less than 11.5.
In light of flight performance, the ratio (S2/S3) of the cross-sectional area S2 of the mid core 14 relative to the cross-sectional area S3 of the outer core 16 is equal to or greater than 0.08 but equal to or less than 1.80.
In light of suppression of spin upon a shot with a driver, the ratio (V2/V1) of the volume V2 of the mid core 14 relative to the volume V1 of the inner core 12 is preferably equal to or greater than 2.5, more preferably equal to or greater than 3.0, and particularly preferably equal to or greater than 4.5. From the standpoint that a high ball speed is obtained, the ratio (V2/V1) is preferably equal to or less than 20.0, more preferably equal to or less than 19.0, and particularly preferably equal to or less than 18.5.
In light of suppression of spin upon a shot with a driver, the ratio (V3/V1) of the volume V3 of the outer core 16 relative to the volume V1 of the inner core 12 is preferably equal to or greater than 10.0, more preferably equal to or greater than 10.5, and particularly preferably equal to or greater than 11.0. From the standpoint that a high ball speed is obtained, the ratio (V3/V1) is preferably equal to or less than 57.0, more preferably equal to or less than 51.0, and particularly preferably equal to or less than 45.0.
In light of flight performance, the ratio (V2/V3) of the volume V2 of the mid core 14 relative to the volume V3 of the outer core 16 is equal to or greater than 0.04 but equal to or less than 1.25.
In the present invention, a resin composition is suitably used for the mid layer 6. Examples of the base polymer of the resin composition include ionomer resins, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyurethane elastomers, thermoplastic polyolefin elastomers, and thermoplastic polystyrene elastomers. A preferable base polymer is an ionomer resin. The golf ball 2 that includes the mid layer 6 including an ionomer resin has excellent resilience performance.
Examples of preferable ionomer resins include binary copolymers formed with an α-olefin and an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms. A preferable binary copolymer includes 80% by weight or more but 90% by weight or less of an α-olefin, and 10% by weight or more but 20% by weight or less of an α,β-unsaturated carboxylic acid. The binary copolymer has excellent resilience performance. Examples of other preferable ionomer resins include ternary copolymers formed with: an α-olefin; an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms; and an α,β-unsaturated carboxylate ester having 2 to 22 carbon atoms. A preferable ternary copolymer includes 70% by weight or more but 85% by weight or less of an α-olefin, 5% by weight or more but 30% by weight or less of an α,β-unsaturated carboxylic acid, and 1% by weight or more but 25% by weight or less of an α,β-unsaturated carboxylate ester. The ternary copolymer has excellent resilience performance. For the binary copolymer and the ternary copolymer, preferable α-olefins are ethylene and propylene, while preferable α,β-unsaturated carboxylic acids are acrylic acid and methacrylic acid. A particularly preferable ionomer resin is a copolymer formed with ethylene and acrylic acid or methacrylic acid.
In the binary copolymer and the ternary copolymer, some of the carboxyl groups are neutralized with metal ions. Examples of metal ions for use in neutralization include sodium ion, potassium ion, lithium ion, zinc ion, calcium ion, magnesium ion, aluminum ion, and neodymium ion. The neutralization may be carried out with two or more types of metal ions. Particularly suitable metal ions in light of resilience performance and durability of the golf ball 2 are sodium ion, zinc ion, lithium ion, and magnesium ion.
Specific examples of ionomer resins include trade names “Himilan 1555”, “Himilan 1557”, “Himilan 1605”, “Himilan 1706”, “Himilan 1707”, “Himilan 1856”, “Himilan 1855”, “Himilan AM7311”, “Himilan AM7315”, “Himilan AM7317”, “Himilan AM7318”, “Himilan AM7329”, “Himilan MK7337”, “Himilan MK7320”, and “Himilan MK7329”, manufactured by Du Pont-MITSUI POLYCHEMICALS Co., Ltd.; trade names “Surlyn 6120”, “Surlyn 6910”, “Surlyn 7930”, “Surlyn 7940”, “Surlyn 8140”, “Surlyn 8150”, “Surlyn 8940”, “Surlyn 8945”, “Surlyn 9120”, “Surlyn 9150”, “Surlyn 9910”, “Surlyn 9945”, “Surlyn AD8546”, “HPF1000”, and “HPF2000”, manufactured by E.I. du Pont de Nemours and Company; and trade names “IOTEK 7010”, “IOTEK 7030”, “IOTEK 7510”, “IOTEK 7520”, “IOTEK 8000”, and “IOTEK 8030”, manufactured by ExxonMobil Chemical Corporation. Two or more ionomer resins may be used in combination. An ionomer resin neutralized with a monovalent metal ion, and an ionomer resin neutralized with a bivalent metal ion may be used in combination.
An ionomer resin and another resin may be used in combination. In this case, in light of resilience performance, the ionomer resin is included as the principal component of the base polymer. The proportion of the ionomer resin to the entire base polymer is preferably equal to or greater than 50% by weight, more preferably equal to or greater than 65% by weight, and particularly preferably equal to or greater than 70% by weight.
A preferable resin that can be used in combination with an ionomer resin is a styrene block-containing thermoplastic elastomer. The styrene block-containing thermoplastic elastomer has excellent compatibility with ionomer resins. A resin composition including the styrene block-containing thermoplastic elastomer has excellent fluidity.
Another resin that can be used in combination with an ionomer resin is an ethylene-(meth)acrylic acid copolymer. The copolymer is obtained by a copolymerization reaction of a monomer composition that contains ethylene and (meth)acrylic acid. In the copolymer, some of the carboxyl groups are neutralized with metal ions. The copolymer includes 3% by weight or greater but 25% by weight or less of a (meth)acrylic acid component. An ethylene-methacrylic acid copolymer having a polar functional group is preferred.
For the purpose of adjusting specific gravity and the like, a filler may be included in the resin composition of the mid layer 6. Examples of suitable fillers include zinc oxide, barium sulfate, calcium carbonate, and magnesium carbonate. Powder of a metal with a high specific gravity may be included as a filler. Specific examples of metals with a high specific gravity include tungsten and molybdenum. The amount of the filler is determined as appropriate so that the intended specific gravity of the mid layer 6 is accomplished. According to need, a coloring agent such as titanium dioxide, a dispersant, an antioxidant, an ultraviolet absorber, a light stabilizer, a fluorescent material, a fluorescent brightener, and the like can be included in the mid layer 6.
In light of suppression of spin upon a shot with a driver, the mid layer 6 has a Shore D hardness Hm of preferably 35 or greater and more preferably 40 or greater. In light of feel at impact, the hardness Hm is preferably equal to or less than 80 and more preferably equal to or less than 76.
In the present invention, the hardness of the mid layer 6 is measured according to the standards of “ASTM-D 2240-68”. For the measurement, an automated rubber hardness measurement machine (trade name “P1”, manufactured by Kobunshi Keiki Co., Ltd.), to which a Shore D type hardness scale is mounted, is used. For the measurement, a sheet that is formed by hot press, is formed from the same material as that of the mid layer 6, and has a thickness of about 2 mm is used. Prior to the measurement, a sheet is kept at 23° C. for two weeks. At the measurement, three sheets are stacked.
In light of durability, the mid layer 6 has a thickness Tm of preferably 0.6 mm or greater and more preferably 0.8 mm or greater. In light of resilience performance, the thickness Tm is preferably equal to or less than 2.0 mm and more preferably equal to or less than 1.8 mm. Preferably, a sphere consisting of the core 4 and the mid layer 6 has a diameter of 39.1 mm or greater but 42.3 mm or less.
The mid layer 6 may be composed of two layers, namely, an inner mid layer and an outer mid layer positioned outside the inner mid layer. By the mid layer 6 being made into a two-layer structure, the hardness distribution of the entire ball is further precisely controlled. With the golf ball that includes the mid layer having a two-layer structure, a high ball speed is obtained upon a shot with a driver.
When the mid layer 6 is made into a two-layer structure including an inner mid layer and an outer mid layer, the thickness of the inner mid layer and the thickness of the outer mid layer are adjusted as appropriate such that the sum of the thicknesses of these two layers is equal to or greater than 0.8 mm but equal to or less than 2.0 mm.
In light of feel at impact, the sphere consisting of the core 4 and the mid layer 6 has an amount of compressive deformation of preferably 1.7 mm or greater, more preferably 1.8 mm or greater, and particularly preferably 1.9 mm or greater. In light of resilience performance, the amount of compressive deformation of the sphere is preferably equal to or less than 4.0 mm, more preferably equal to or less than 3.6 mm, and particularly preferably equal to or less than 3.4 mm. The amount of compressive deformation of the sphere consisting of the core 4 and the mid layer 6 is measured by the same measurement method as that for the amount of compressive deformation of the sphere consisting of the inner core 12 and the mid core 14.
For forming the mid layer 6, known methods such as injection molding, compression molding, and the like can be used.
In the present invention, a resin composition is suitably used for the cover 10. Examples of the base polymer of the resin composition include ionomer resins, thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyurethane elastomers, thermoplastic polyolefin elastomers, and thermoplastic polystyrene elastomers. A preferable base polymer is a thermoplastic polyurethane elastomer. The thermoplastic polyurethane elastomer is flexible. The golf ball 2 that includes the cover 10 formed from the resin composition has excellent controllability. The thermoplastic polyurethane elastomer also contributes to the scuff resistance and the feel at impact of the cover 10.
The thermoplastic polyurethane elastomer includes a polyurethane component as a hard segment, and a polyester component or a polyether component as a soft segment. Examples of isocyanates for the polyurethane component include alicyclic diisocyanates, aromatic diisocyanates, and aliphatic diisocyanates. Two or more diisocyanates may be used in combination.
Examples of alicyclic diisocyanates include 4,4′-dicyclohexylmethane diisocyanate (H12MDI), 1,3-bis(isocyanatomethyl)cyclohexane (H6XDI), isophorone diisocyanate (IPDI), and trans-1,4-cyclohexane diisocyanate (CHDI). In light of versatility and processability, H12MDI is preferred.
Examples of aromatic diisocyanates include 4,4′-diphenylmethane diisocyanate (MDI) and toluene diisocyanate (TDI). Examples of aliphatic diisocyanates include hexamethylene diisocyanate (HDI).
Alicyclic diisocyanates are particularly preferred. Since an alicyclic diisocyanate does not have any double bond in the main chain, the alicyclic diisocyanate suppresses yellowing of the cover 10. In addition, since an alicyclic diisocyanate has excellent strength, the alicyclic diisocyanate suppresses damage of the cover 10.
Specific examples of thermoplastic polyurethane elastomers include trade names “Elastollan NY80A”, “Elastollan NY82A”, “Elastollan NY84A”, “Elastollan NY85A”, “Elastollan NY88A”, “Elastollan NY90A”, “Elastollan NY97A”, “Elastollan NY585”, “Elastollan XKP016N”, “Elastollan 1195ATR”, “Elastollan ET890A”, and “Elastollan ET88050”, manufactured by BASF Japan Ltd.; and trade names “RESAMINE P4585LS” and “RESAMINE PS62490”, manufactured by Dainichiseika Color & Chemicals Mfg. Co., Ltd.
A thermoplastic polyurethane elastomer and another resin may be used in combination. Examples of the resin that can be used in combination include thermoplastic polyester elastomers, thermoplastic polyamide elastomers, thermoplastic polyolefin elastomers, styrene block-containing thermoplastic elastomers, and ionomer resins. When a thermoplastic polyurethane elastomer and another resin are used in combination, the thermoplastic polyurethane elastomer is included as the principal component of the base polymer, in light of spin performance and scuff resistance. The proportion of the thermoplastic polyurethane elastomer to the entire base polymer is preferably equal to or greater than 50% by weight, more preferably equal to or greater than 70% by weight, and particularly preferably equal to or greater than 85% by weight.
According to need, a coloring agent such as titanium dioxide, a filler such as barium sulfate, a dispersant, an antioxidant, an ultraviolet absorber, a light stabilizer, a fluorescent material, a fluorescent brightener, and the like are included in the cover 10 in an adequate amount.
In light of flight performance, the cover 10 has a Shore D hardness Hc of preferably 10 or greater and more preferably 15 or greater. In light of controllability and feel at impact, the hardness Hc is preferably equal to or less than 55 and more preferably equal to or less than 50. The hardness Hc is measured by the same measurement method as that for the hardness Hm.
In light of flight performance and durability, the cover 10 has a thickness Tc of preferably 0.1 mm or greater and more preferably 0.3 mm or greater. In light of controllability and feel at impact, the thickness Tc is preferably equal to or less than 1.2 mm and more preferably equal to or less than 0.8 mm.
The cover 10 may be composed of two layers, namely, an inner cover and an outer cover positioned outside the inner cover. By the cover 10 being made into a two-layer structure, the hardness distribution of the entire ball is further precisely controlled. With the golf ball that includes the cover having a two-layer structure, excellent controllability and favorable feel at impact are obtained without impairing flight performance upon a shot with a driver.
When the cover 10 is made into a two-layer structure including an inner cover and an outer cover, the thickness of the inner cover and the thickness of the outer cover are adjusted as appropriate such that the sum of the thicknesses of these two layers is equal to or greater than 0.1 mm but equal to or less than 1.2 mm.
For forming the cover 10, known methods such as injection molding, compression molding, and the like can be used. When forming the cover 10, the dimples 18 are formed by pimples formed on the cavity face of a mold.
In light of feel at impact, the golf ball 2 has an amount of compressive deformation Db of preferably 1.9 mm or greater, more preferably 2.0 mm or greater, and particularly preferably 2.3 mm or greater. In light of resilience performance, the amount of compressive deformation Db is preferably equal to or less than 3.5 mm, more preferably equal to or less than 3.4 mm, and particularly preferably equal to or less than 3.3 mm. The amount of compressive deformation Db of the golf ball 2 is measured by the same measurement method as that for the amount of compressive deformation of the sphere consisting of the inner core 12 and the mid core 14.
In light of durability, the golf ball 2 that further includes the reinforcing layer 8 between the mid layer 6 and the cover 10 is preferred. The reinforcing layer 8 is positioned between the mid layer 6 and the cover 10. The reinforcing layer 8 firmly adheres to the mid layer 6 and also to the cover 10. The reinforcing layer 8 suppresses separation of the cover 10 from the mid layer 6. When the golf ball 2 is hit with the edge of a clubface, a wrinkle is likely to occur. The reinforcing layer 8 suppresses occurrence of a wrinkle to improve the durability of the golf ball 2.
As the base polymer of the reinforcing layer 8, a two-component curing type thermosetting resin is suitably used. Specific examples of two-component curing type thermosetting resins include epoxy resins, urethane resins, acrylic resins, polyester resins, and cellulose resins. In light of strength and durability of the reinforcing layer 8, two-component curing type epoxy resins and two-component curing type urethane resins are preferred.
A two-component curing type epoxy resin is obtained by curing an epoxy resin with a polyamide type curing agent. Examples of epoxy resins used in two-component curing type epoxy resins include bisphenol A type epoxy resins, bisphenol F type epoxy resins, and bisphenol AD type epoxy resins. In light of balance among flexibility, chemical resistance, heat resistance, and toughness, bisphenol A type epoxy resins are preferred. Specific examples of the polyamide type curing agent include polyamide amine curing agents and modified products thereof. In a mixture of an epoxy resin and a polyamide type curing agent, the ratio of the epoxy equivalent of the epoxy resin to the amine active hydrogen equivalent of the polyamide type curing agent is preferably equal to or greater than 1.0/1.4 but equal to or less than 1.0/1.0.
A two-component curing type urethane resin is obtained by a reaction of a base material and a curing agent. A two-component curing type urethane resin obtained by a reaction of a base material containing a polyol component and a curing agent containing a polyisocyanate or a derivative thereof, and a two-component curing type urethane resin obtained by a reaction of a base material containing an isocyanate group-terminated urethane prepolymer and a curing agent having active hydrogen, can be used. Particularly, a two-component curing type urethane resin obtained by a reaction of a base material containing a polyol component and a curing agent containing a polyisocyanate or a derivative thereof, is preferred.
The reinforcing layer 8 may include additives such as a coloring agent (typically, titanium dioxide), a phosphate-based stabilizer, an antioxidant, a light stabilizer, a fluorescent brightener, an ultraviolet absorber, an anti-blocking agent, and the like. The additives may be added to the base material of the two-component curing type thermosetting resin, or may be added to the curing agent of the two-component curing type thermosetting resin.
The reinforcing layer 8 is obtained by applying, to the surface of the mid layer 6, a liquid that is prepared by dissolving or dispersing the base material and the curing agent in a solvent. In light of workability, application with a spray gun is preferred. After the application, the solvent is volatilized to permit a reaction of the base material with the curing agent, thereby forming the reinforcing layer 8. Examples of preferable solvents include toluene, isopropyl alcohol, xylene, methyl ethyl ketone, methyl isobutyl ketone, ethylene glycol monomethyl ether, ethylbenzene, propylene glycol monomethyl ether, isobutyl alcohol, and ethyl acetate.
In light of suppression of a wrinkle, the reinforcing layer 8 has a thickness of preferably 3 μm or greater and more preferably 5 μm or greater. In light of ease of forming the reinforcing layer 8, the thickness is preferably equal to or less than 100 μm, more preferably equal to or less than 50 μm, and further preferably equal to or less than 20 μm. The thickness is measured by observing a cross section of the golf ball 2 with a microscope. When the mid layer 6 has concavities and convexities on its surface from surface roughening, the thickness is measured at a convex part.
In light of suppression of a wrinkle, the reinforcing layer 8 has a pencil hardness of preferably 4B or greater and more preferably B or greater. In light of reduced loss of the power transmission from the cover 10 to the mid layer 6 upon hitting the golf ball 2, the pencil hardness of the reinforcing layer 8 is preferably equal to or less than 3H. The pencil hardness is measured according to the standards of “JIS K5600”.
When the mid layer 6 and the cover 10 sufficiently adhere to each other so that a wrinkle is unlikely to occur, the reinforcing layer 8 may not be provided.
EXAMPLES
The following will show the effects of the present invention by means of Examples, but the present invention should not be construed in a limited manner based on the description of these Examples.
Example 1
A rubber composition was obtained by kneading 100 parts by weight of a high-cis polybutadiene (trade name “BR-730”, manufactured by JSR Corporation), 34.8 parts by weight of magnesium oxide (trade name “MAGSARAT 150ST”, manufactured by Sankyo Kasei Co., Ltd.), 28 parts by weight of methacrylic acid (manufactured by MITSUBISHI RAYON CO., LTD.), and 0.9 parts by weight of dicumyl peroxide (trade name “Percumyl D”, manufactured by NOF Corporation). This rubber composition was placed into a mold including upper and lower mold halves each having a hemispherical cavity, and heated at 170° C. for 25 minutes to obtain a spherical inner core with a diameter of 15.0 mm.
A rubber composition was obtained by kneading 100 parts by weight of a high-cis polybutadiene (the aforementioned “BR-730”), 25 parts by weight of zinc diacrylate (trade name “Sanceler SR”, manufactured by SANSHIN CHEMICAL INDUSTRY CO., LTD.), 5 parts by weight of zinc oxide, an appropriate amount of barium sulfate (manufactured by Sakai Chemical Industry Co., Ltd.), 0.7 parts by weight of dicumyl peroxide (the aforementioned “Percumyl D”), and 0.5 parts by weight of diphenyl disulfide (manufactured by Sumitomo Seika Chemicals Co., Ltd.). Half shells were formed from this rubber composition. The inner core was covered with two of these half shells. The inner core and the half shells were placed into a mold including upper and lower mold halves each having a hemispherical cavity, and heated at 170° C. for 25 minutes. A mid core was formed from the rubber composition. The diameter of the obtained sphere consisting of the inner core and the mid core was 24.0 mm. The amount of barium sulfate was adjusted such that the specific gravity of the mid core coincides with the specific gravity of the inner core.
A rubber composition was obtained by kneading 100 parts by weight of a high-cis polybutadiene (the aforementioned “BR-730”), 46.5 parts by weight of zinc diacrylate (the aforementioned “Sanceler SR”), 5 parts by weight of zinc oxide, an appropriate amount of barium sulfate (manufactured by Sakai Chemical Industry Co., Ltd.), 0.7 parts by weight of dicumyl peroxide (the aforementioned “Percumyl D”), 0.5 parts by weight of diphenyl disulfide (manufactured by Sumitomo Seika Chemicals Co., Ltd.), and 0.1 parts by weight of an anti-aging agent (trade name “H-BHT”, manufactured by HONSHU CHEMICAL INDUSTRY CO., LTD.). Half shells were formed from this rubber composition. The sphere consisting of the inner core and the mid core was covered with two of these half shells. The sphere consisting of the inner core and the mid core and the half shells were placed into a mold including upper and lower mold halves each having a hemispherical cavity, and heated at 170° C. for 25 minutes to obtain a core with a diameter of 40.1 mm. An outer core was formed from the rubber composition. The amount of barium sulfate was adjusted such that the specific gravity of the outer core coincides with the specific gravity of each of the inner core and the mid core and the weight of a golf ball is 45.4 g.
A resin composition was obtained by kneading 50 parts by weight of an ionomer resin (the aforementioned “Himilan 1605”), 50 parts by weight of another ionomer resin (the aforementioned “Himilan AM7329”), 4 parts by weight of titanium dioxide (manufactured by Ishihara Sangyo Kaisha, Ltd.), and an appropriate amount of barium sulfate (manufactured by Sakai Chemical Industry Co., Ltd.) with a twin-screw kneading extruder. The extruding conditions were a screw diameter of 45 mm, a screw rotational speed of 200 rpm, screw L/D of 35, and a die temperature of 160° C. to 230° C. The core was placed into a mold. The resin composition was injected around the core by injection molding to form a mid layer with a thickness of 1.0 mm.
A paint composition (trade name “POLIN 750LE”, manufactured by SHINTO PAINT CO., LTD.) including a two-component curing type epoxy resin as a base polymer was prepared. The base material liquid of this paint composition includes 30 parts by weight of a bisphenol A type solid epoxy resin and 70 parts by weight of a solvent. The curing agent liquid of this paint composition includes 40 parts by weight of a modified polyamide amine, 55 parts by weight of a solvent, and 5 parts by weight of titanium dioxide. The weight ratio of the base material liquid to the curing agent liquid is 1/1. This paint composition was applied to the surface of the mid layer with an air gun, and kept at 23° C. for 12 hours to obtain a reinforcing layer with a thickness of 10 μm.
A resin composition was obtained by kneading 100 parts by weight of a thermoplastic polyurethane elastomer (trade name “Elastollan NY84A10 Clear”, manufactured by BASF Japan Ltd.), 1.7 parts by weight of a mold release agent (trade name “Elastollan Wax Master VD”, manufactured by BASF Japan Ltd.), 4 parts by weight of titanium dioxide (manufactured by Sakai Chemical Industry Co., Ltd.), and 0.2 parts by weight of a light stabilizer (trade name “JF-90”, manufactured by Johoku Chemical Co., Ltd.) with a twin-screw kneading extruder under the above extruding conditions. Half shells were formed from this resin composition by compression molding. The sphere consisting of the core, the mid layer, and the reinforcing layer was covered with two of these half shells. The sphere and the half shells were placed into a final mold that includes upper and lower mold halves each having a hemispherical cavity and that has a large number of pimples on its cavity face. A cover was obtained by compression molding. The thickness of the cover was 0.3 mm. Dimples having a shape that is the inverted shape of the pimples were formed on the cover. The surface of the cover was polished. A clear paint including a two-component curing type polyurethane as a base material was applied to this cover with an air gun, and was dried and cured to obtain a golf ball of Example 1 with a diameter of 42.7 mm and a weight of 45.6 g.
Examples 2 to 53 and Comparative Examples 1 to 31
Golf balls of Examples 2 to 53 and Comparative Examples 1 to 31 were obtained in the same manner as Example 1, except the specifications of the core, the mid layer, and the cover were as shown in Tables 22 to 38 below. The rubber composition of the core is shown in detail in Tables 1 to 3 below. The specifications and the hardness distribution of the core are shown in Tables 5 to 21 below. The resin compositions of the mid layer and the cover are shown in detail in Table 4 below.
[Hit with Driver (W#1)]
A driver with a titanium head (trade name “XXIO”, manufactured by DUNLOP SPORTS CO. LTD., shaft hardness: S, loft angle: 10.0°) was attached to a swing machine manufactured by True Temper Co. A golf ball was hit under the condition of a head speed of 45 (m/s). The ball speed (m/s) and the spin rate (rpm) immediately after the hit were measured. Furthermore, the flight distance (m) from the launch point to the stop point was measured. The average value of data obtained by 10 measurements is shown in Tables 22 to 38 below. “Radius of sphere” in Tables 22 to 38 means the radius of consisting of the inner core and the mid core.







TABLE 1







Formulation of Core







(parts by weight)













Type
1
2
3
4
5
6
















BR-730
100
100
100
100
100
100


MAGSARAT 150ST
34.8
—
—
—
—
—


Methacrylic acid
28
—
—
—
—
—


Sanceler SR
—
25
25
30
38
38


Zinc oxide
—
5
5
5
5
5


Barium sulfate
—
*
*
*
*
*


Dicumyl peroxide
0.9
0.7
0.7
0.7
0.7
0.9


PBDS
—
—
—
—
—
0.3


DPDS
—
0.3
0.5
0.5
0.5
—


H-BHT
—
—
—
0.1
—
—





* Appropriate amount













TABLE 2







Formulation of Core







(parts by weight)













Type
7
8
9
10
11
12
















BR-730
100
100
100
100
100
100


MAGSARAT 150ST
—
—
—
—
—
—


Methacrylic acid
—
—
—
—
—
—


Sanceler SR
46.5
40
46.5
32.5
35
46


Zinc oxide
5
5
5
5
5
5


Barium sulfate
*
*
*
*
*
*


Dicumyl peroxide
0.7
0.7
0.7
0.9
0.9
0.7


PBDS
—
—
—
0.3
0.3
—


DPDS
0.5
0.5
0.5
—
—
0.5


H-BHT
0.1
0.1
0.1
—
—
0.2





* Appropriate amount






The details of the compounds listed in Tables 1 and 2 are as follows.
BR-730: a high-cis polybutadiene manufactured by JSR Corporation (cis-1,4-bond content: 96% by weight, 1,2-vinyl bond content: 1.3% by weight, Mooney viscosity (ML1+4(100° C.)): 55, molecular weight distribution (Mw/Mn): 3)
MAGSARAT 150ST: magnesium oxide manufactured by Sankyo Kasei Co., Ltd.
Sanceler SR: zinc diacrylate manufactured by SANSHIN CHEMICAL INDUSTRY CO., LTD. (a product coated with 10% by weight of stearic acid)
Zinc oxide: trade name “Ginrei R”, manufactured by Toho Zinc Co., Ltd.
Barium sulfate: trade name “Barium Sulfate BD”, manufactured by Sakai Chemical Industry Co., Ltd.
Dicumyl peroxide: trade name “Percumyl D”, manufactured by NOF Corporation
PBDS: bis(pentabromophenyl)disulfide manufactured by Kawaguchi Chemical Industry Co., Ltd.
DPDS: diphenyl disulfide manufactured by Sumitomo Seika Chemicals Co., Ltd.
H-BHT: dibutyl hydroxy toluene (anti-aging agent) manufactured by HONSHU CHEMICAL INDUSTRY CO., LTD.







TABLE 3







Formulation of Core (parts by weight)













Type
B1
B2
B3
B4

















Polybutadiene
100
100
100
—



Zinc diacrylate
16
18.5
36
—



Peroxide
3
3
3
—



Zinc oxide
5
5
5
—



Barium sulfate
20.7
19.6
11.9
—



Anti-aging agent
0.1
0.1
0.1
—



Pentachlorothiophenol
0.4
0.4
0.4
—



zinc salt



Himilan 1605
—
—
—
50



Himilan 1706
—
—
—
35



Himilan 1557
—
—
—
15



Trimethylol propane
—
—
—
1.1







* Appropriate amount






The details of the compounds listed in Table 3 are as follows.
Zinc diacrylate: a product of Nihon Jyoryu Kogyo Co., Ltd.
Anti-aging agent: trade name “Nocrac NS-6”, manufactured by Ouchi Shinko Chemical Industrial Co., Ltd.
Pentachlorothiophenol zinc salt: a product of Wako Chemical, Ltd.
Trimethylol propane: a product of Mitsubishi Gas Chemical Company, Inc.







TABLE 4







Formulations of Mid Layer and Cover







(parts by weight)












Type
a
b
c
A
B















Himilan 1605
50.0
—
—
—
—


Himilan 7329
50.0
—
34.5
—
—


Himilan 7337
—
—
27.5
—
—


NUCREL N1050H
—
—
16.0
—
—


Rabalon T3221C
—
—
22.0
—
—


Surlyn 8150
—
50.0
—
—
—


Surlyn 9150
—
50.0
—
—
—


Elastollan
—
—
—
100
—


NY84A10 Clear


Elastollan NY97A
—
—
—
—
100


Elastollan Wax
—
—
—
1.7
1.7


Master VD


Titanium dioxide
4
4
4
4
4


Barium sulfate
*
*
—
—
—


JF-90
—
—
—
0.2
0.2


Hardness
65
70
50
31
47


(Shore D)





* Appropriate amount






The details of the compounds listed in Table 4 are as follows.
NUCREL N1050H: an ethylene-methacrylic acid copolymer manufactured by Du Pont-MITSUI POLYCHEMICALS Co., Ltd.
Rabalon T3221C: a thermoplastic polystyrene elastomer manufactured by Mitsubishi Chemical Corporation
Titanium dioxide: a product of Ishihara Sangyo Kaisha, Ltd.
Barium sulfate: trade name “Barium Sulfate BD”, manufactured by Sakai Chemical Industry Co., Ltd.
JF-90: bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate (light stabilizer) manufactured by Johoku Chemical Co., Ltd.







TABLE 5







Configuration of Core













E1
E2
E3
E4
E5
















Inner core
1
1
1
1
1


Formulation


Radius X
7.5
7.5
7.5
7.5
7.5


(mm)


Area S1
177
177
177
177
177


(mm2)


Volume V1
1767
1767
1767
1767
1767


(mm3)


Mid core
3
3
3
3
3


Formulation


Thickness
4.50
4.50
4.50
4.50
4.50


Y (mm)


Radius of
12.0
12.0
12.0
12.0
12.0


sphere (mm)


Area S2
276
276
276
276
276


(mm2)


Volume V2
5471
5471
5471
5471
5471


(mm3)


Outer core
7
7
8
8
9


Formulation


Thickness
8.05
7.85
7.25
7.05
8.05


Z (mm)


Radius of
20.05
19.85
19.25
19.05
20.05


core (mm)


Area S3
811
785
712
688
811


(mm2)


Volume V3
26524
25524
22642
21720
26524


(mm3)


H(A)central
60
60
60
60
60


point (JIS-C)


H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
85
85
85
85
86


H(F) surface
85
85
85
85
84


(JIS-C)


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
10
10
10
10
11


H(F) − H(E)
0
0
0
0
−2


H(F) − H(A)
25
25
25
25
24
















TABLE 6







Configuration of Core













E6
E7
E8
E9
E10
















Inner core
1
1
1
1
1


Formulation


Radius X
7.5
7.5
7.5
7.5
7.5


(mm)


Area S1
177
177
177
177
177


(mm2)


Volume
1767
1767
1767
1767
1767


V1 (mm3)


Mid core
3
3
3
3
3


Formulation


Thickness
4.50
4.50
4.50
6.00
6.00


Y (mm)


Radius of
12.0
12.0
12.0
13.5
13.5


sphere (mm)


Area S2
276
276
276
396
396


(mm2)


Volume
5471
5471
5471
8539
8539


V2 (mm3)


Outer core
9
5
5
7
7


Formulation


Thickness
7.85
8.05
7.85
6.55
6.35


Z (mm)


Radius of
19.85
20.05
19.85
20.05
19.85


core (mm)


Area S3
785
811
785
690
665


(mm2)


Volume
25524
26524
25524
23456
22456


V3 (mm3)


H(A)central
60
60
60
60
60


point (JIS-C)


H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
86
84
84
85
85


H(F) surface
84
86
86
85
85


(JIS-C)


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
11
9
9
10
10


H(F) − H(E)
−2
2
2
0
0


H(F) − H(A)
24
26
26
25
25
















TABLE 7







Configuration of Core













E11
E12
E13
E14
E15
















Inner core
1
1
1
1
1


Formulation


Radius X
7.5
7.5
7.5
7.5
7.5


(mm)


Area S1
177
177
177
177
177


(mm2)


Volume
1767
1767
1767
1767
1767


V1 (mm3)


Mid core
3
3
3
3
3


Formulation


Thickness
6.00
6.00
6.00
6.00
6.00


Y (mm)


Radius of
13.5
13.5
13.5
13.5
13.5


sphere (mm)


Area S2
396
396
396
396
396


(mm2)


Volume
8539
8539
8539
8539
8539


V2 (mm3)


Outer core
8
8
9
9
5


Formulation


Thickness
5.75
5.55
6.55
6.35
6.55


Z (mm)


Radius of
19.25
19.05
20.05
19.85
20.05


core (mm)


Area S3
592
568
690
665
690


(mm2)


Volume
19574
18652
23456
22456
23456


V3 (mm3)


H(A) central
60
60
60
60
60


point (JIS-C)


H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
85
85
86
86
84


H(F) surface
85
85
84
84
86


(JIS-C)


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
10
10
11
11
9


H(F) − H(E)
0
0
−2
−2
2


H(F) − H(A)
25
25
24
24
26
















TABLE 8







Configuration of Core













E16
E17
E18
E19
E20















Inner core Formulation
1
1
1
1
1


Radius X (mm)
7.5
5.0
5.0
5.0
5.0


Area S1 (mm2)
177
79
79
79
79


Volume V1 (mm3)
1767
524
524
524
524


Mid core Formulation
3
3
3
3
3


Thickness Y (mm)
6.00
5.00
5.00
5.00
5.00


Radius of sphere(mm)
13.5
10.0
10.0
10.0
10.0


Area S2 (mm2)
396
236
236
236
236


Volume V2 (mm3)
8539
3665
3665
3665
3665


Outer core Formulation
5
7
7
8
8


Thickness Z (mm)
6.35
10.05
9.85
9.25
9.05


Radius of core (mm)
19.85
20.05
19.85
19.25
19.05


Area S3 (mm2)
665
949
924
850
826


Volume V3 (mm3)
22456
29573
28573
25691
24770


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
84
85
85
85
85


H(F) surface (JIS-C)
86
85
85
85
85


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
9
10
10
10
10


H(F) − H(E)
2
0
0
0
0


H(F) − H(A)
26
25
25
25
25
















TABLE 9







Configuration of Core













E21
E22
E23
E24
E25















Inner core Formulation
1
1
1
1
1


Radius X (mm)
5.0
5.0
5.0
5.0
5.0


Area S1 (mm2)
79
79
79
79
79


Volume V1 (mm3)
524
524
524
524
524


Mid core Formulation
3
3
3
3
3


Thickness Y (mm)
5.00
5.00
5.00
5.00
7.00


Radius of sphere(mm)
10.0
10.0
10.0
10.0
12.0


Area S2 (mm2)
236
236
236
236
374


Volume V2 (mm3)
3665
3665
3665
3665
6715


Outer core Formulation
9
9
5
5
7


Thickness Z (mm)
10.05
9.85
10.05
9.85
8.05


Radius of core (mm)
20.05
19.85
20.05
19.85
20.05


Area S3 (mm2)
949
924
949
924
811


Volume V3 (mm3)
29573
28573
29573
28573
26524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
86
86
84
84
85


H(F) surface (JIS-C)
84
84
86
86
85


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
11
11
9
9
10


H(F) − H(E)
−2
−2
2
2
0


H(F) − H(A)
24
24
26
26
25
















TABLE 10







Configuration of Core













E26
E27
E28
E29
E30















Inner core Formulation
1
1
1
1
1


Radius X (mm)
5.0
5.0
5.0
5.0
5.0


Area S1 (mm2)
79
79
79
79
79


Volume V1 (mm3)
524
524
524
524
524


Mid core Formulation
3
3
3
3
3


Thickness Y (mm)
7.00
7.00
7.00
7.00
7.00


Radius of sphere(mm)
12.0
12.0
12.0
12.0
12.0


Area S2 (mm2)
374
374
374
374
374


Volume V2 (mm3)
6715
6715
6715
6715
6715


Outer core Formulation
7
8
8
9
9


Thickness Z (mm)
7.85
7.25
7.05
8.05
7.85


Radius of core (mm)
19.85
19.25
19.05
20.05
19.85


Area S3 (mm2)
785
712
688
811
785


Volume V3 (mm3)
25524
22642
21720
26524
25524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
85
85
85
86
86


H(F) surface (JIS-C)
85
85
85
84
84


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
10
10
10
11
11


H(F) − H(E)
0
0
0
−2
−2


H(F) − H(A)
25
25
25
24
24
















TABLE 11







Configuration of Core













E31
E32
E33
E34
E35















Inner core Formulation
1
1
1
1
1


Radius X (mm)
5.0
5.0
5.0
5.0
5.0


Area S1 (mm2)
79
79
79
79
79


Volume V1 (mm3)
524
524
524
524
524


Mid core Formulation
3
3
3
3
3


Thickness Y (mm)
7.00
7.00
8.50
8.50
8.50


Radius of sphere(mm)
12.0
12.0
13.5
13.5
13.5


Area S2 (mm2)
374
374
494
494
494


Volume V2 (mm3)
6715
6715
9782
9782
9782


Outer core Formulation
5
5
7
7
8


Thickness Z (mm)
8.05
7.85
6.55
6.35
5.75


Radius of core (mm)
10.05
19.85
20.05
19.85
19.25


Area S3 (mm2)
811
785
690
665
592


Volume V3 (mm3)
26524
25524
23456
22456
19574


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
84
84
85
85
85


H(F) surface (JIS-C)
86
86
85
85
85


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
9
9
10
10
10


H(F) − H(E)
2
2
0
0
0


H(F) − H(A)
26
26
25
25
25
















TABLE 12







Configuration of Core













E36
E37
E38
E39
E40















Inner core Formulation
1
1
1
1
1


Radius X (mm)
5.0
5.0
5.0
5.0
5.0


Area S1 (mm2)
79
79
79
79
79


Volume V1 (mm3)
524
524
524
524
524


Mid core Formulation
3
3
3
3
3


Thickness Y (mm)
8.50
8.50
8.50
8.50
8.50


Radius of sphere(mm)
13.5
13.5
13.5
13.5
13.5


Area S2 (mm2)
494
494
494
494
494


Volume V2 (mm3)
9782
9782
9782
9782
9782


Outer core Formulation
8
9
9
5
5


Thickness Z (mm)
5.55
6.55
6.35
6.55
6.35


Radius of core (mm)
19.05
20.05
19.85
20.05
19.85


Area S3 (mm2)
568
690
665
690
665


Volume V3 (mm3)
18652
23456
22456
23456
22456


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
75
75
75
75
75


H(E) (JIS-C)
85
86
86
84
84


H(F) surface (JIS-C)
85
84
84
86
86


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
5
5
5
5
5


H(E) − H(D)
10
11
11
9
9


H(F) − H(E)
0
−2
−2
2
2


H(F) − H(A)
25
24
24
26
26
















TABLE 13







Configuration of Core













E41
E42
E43
E44
E45















Inner core Formulation
1
1
1
1
1


Radius X (mm)
7.5
7.5
7.5
7.5
7.5


Area S1 (mm2)
177
177
177
177
177


Volume V1 (mm3)
1767
1767
1767
1767
1767


Mid core Formulation
4
4
4
4
4


Thickness Y (mm)
4.50
4.50
4.50
4.50
4.50


Radius of sphere(mm)
12.0
12.0
12.0
12.0
12.0


Area S2 (mm2)
276
276
276
276
276


Volume V2 (mm3)
5471
5471
5471
5471
5471


Outer core Formulation
7
7
8
8
9


Thickness Z (mm)
8.05
7.85
7.25
7.05
8.05


Radius of core (mm)
20.05
19.85
19.25
19.05
20.05


Area S3 (mm2)
811
785
712
688
811


Volume V3 (mm3)
26524
25524
22642
21720
26524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
73
73
73
73
73


H(D) (JIS-C)
73
73
73
73
73


H(E) (JIS-C)
85
85
85
85
86


H(F) surface (JIS-C)
85
85
85
85
84


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
10
10
10
10
10


H(D) − H(C)
0
0
0
0
0


H(E) − H(D)
12
12
12
12
13


H(F) − H(E)
0
0
0
0
−2


H(F) − H(A)
25
25
25
25
24
















TABLE 14







Configuration of Core













E46
E47
E48
E49
E50















Inner core Formulation
1
1
1
1
1


Radius X (mm)
7.5
3.0
3.0
10.0
10.0


Area S1 (mm2)
177
28
28
314
314


Volume V1 (mm3)
1767
113
113
4189
4189


Mid core Formulation
4
4
4
4
4


Thickness Y (mm)
4.50
9.00
10.50
2.00
3.50


Radius of sphere(mm)
12.0
12.0
13.5
12.0
13.5


Area S2 (mm2)
276
424
544
138
258


Volume V2 (mm3)
5471
7125
10193
3049
6117


Outer core Formulation
9
7
7
7
7


Thickness Z (mm)
7.85
7.85
6.35
7.85
6.35


Radius of core (mm)
19.85
19.85
19.85
19.85
19.85


Area S3 (mm2)
785
785
665
785
665


Volume V3 (mm3)
25524
25524
22456
25524
22456


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
73
73
73
73
73


H(D) (JIS-C)
73
73
73
73
73


H(E) (JIS-C)
86
85
85
85
85


H(F) surface (JIS-C)
84
85
85
85
85


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
10
10
10
10
10


H(D) − H(C)
0
0
0
0
0


H(E) − H(D)
13
12
12
12
12


H(F) − H(E)
−2
0
0
0
0


H(F) − H(A)
24
25
25
25
25
















TABLE 15







Configuration of Core













E51
E52
R1
R2
R3















Inner core Formulation
1
1
1
1
10


Radius X (mm)
7.5
7.5
7.5
7.5
—


Area S1 (mm2)
177
177
177
177
—


Volume V1 (mm3)
1767
1767
1767
1767
—


Mid core Formulation
4
4
2
2
—


Thickness Y (mm)
1.00
9.00
4.50
4.50
—


Radius of sphere(mm)
8.5
16.5
12.0
12.0
—


Area S2 (mm2)
50
679
276
276
—


Volume V2 (mm3)
805
17049
5471
5471
—


Outer core Formulation
7
7
6
6
—


Thickness Z (mm)
11.35
3.35
8.05
7.85
—


Radius of core (mm)
19.85
19.85
20.05
19.85
20.05


Area S3 (mm2)
1011
383
811
785
—


Volume V3 (mm3)
30190
13945
26524
25524
—


H(A) central point
60
60
60
60
65


(JIS-C)







H(B) (JIS-C)
63
63
63
63
—


H(C) (JIS-C)
73
73
70
70
—


H(D) (JIS-C)
73
73
72
72
—


H(E) (JIS-C)
85
85
73
73
—


H(F) surface (JIS-C)
85
85
88
88
88


H(B) − H(A)
3
3
3
3
—


H(C) − H(B)
10
10
7
7
—


H(D) − H(C)
0
0
2
2
—


H(E) − H(D)
12
12
11
11
—


H(F) − H(E)
0
0
5
5
—


H(F) − H(A)
25
25
28
28
23
















TABLE 16







Configuration of Core













R4
R5
R6
R7
R8















Inner core Formulation
10
1
1
1
1


Radius X (mm)
—
7.5
7.5
7.5
7.5


Area S1 (mm2)
—
—
—
—
—


Volume V1 (mm3)
—
—
—
—
—


Mid core Formulation
—
11
11
11
11


Thickness Y (mm)
—
—
—
—
—


Radius of sphere(mm)
—
—
—
—
—


Area S2 (mm2)
—
—
—
—
—


Volume V2 (mm3)
—
—
—
—
—


Outer core Formulation
—
—
—
—
—


Thickness Z (mm)
—
—
—
—
—


Radius of core (mm)
19.85
20.05
19.85
19.25
19.05


Area S3 (mm2)
—
—
—
—
—


Volume V3 (mm3)
—
—
—
—
—


H(A) central point
60
60
60
60
60


(JIS-C)
—
—
—
—
—


H(B) (JIS-C)
—
63
63
63
63


H(C) (JIS-C)
—
71
71
71
71


H(D) (JIS-C)
—
—
—
—
—


H(E) (JIS-C)
—
—
—
—
—


H(F) surface (JIS-C)
88
88
88
88
88


H(B) − H(A)
—
—
—
3
3


H(C) − H(B)
—
—
—
8
8


H(D) − H(C)
—
—
—
—
—


H(E) − H(D)
—
—
—
—
—


H(F) − H(E)
—
—
—
—
—


H(F) − H(A)
28
28
28
28
28
















TABLE 17







Configuration of Core













R9
R10
R11
R12
R13















Inner core Formulation
1
1
1
1
1


Radius X (mm)
7.5
7.5
5.0
5.0
5.0


Area S1 (mm2)
177
177
79
79
79


Volume V1 (mm3)
1767
1767
524
524
524


Mid core Formulation
2
2
2
2
2


Thickness Y (mm)
6.00
6.00
5.00
5.00
7.00


Radius of sphere(mm)
13.5
13.5
10.0
10.0
12.0


Area S2 (mm2)
396
396
236
236
374


Volume V2 (mm3)
8539
8539
3665
3665
6715


Outer core Formulation
6
6
6
6
6


Thickness Z (mm)
6.55
6.35
10.05
9.85
8.05


Radius of core (mm)
20.05
19.85
20.05
19.85
20.05


Area S3 (mm2)
690
665
949
924
811


Volume V3 (mm3)
23456
22456
29573
28573
26524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
70
70


H(D) (JIS-C)
72
72
72
72
72


H(E) (JIS-C)
83
83
83
83
83


H(F) surface (JIS-C)
88
88
88
88
88


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
7
7


H(D) − H(C)
2
2
2
2
2


H(E) − H(D)
11
11
11
11
11


H(F) − H(E)
5
5
5
5
5


H(F) − H(A)
28
28
28
28
28
















TABLE 18







Configuration of Core













R14
R15
R16
R17
R18















Inner core Formulation
1
1
1
1
1


Radius X (mm)
5.0
5.0
5.0
7.5
7.5


Area S1 (mm2)
79
79
79
177
177


Volume V1 (mm3)
524
524
524
1767
1767


Mid core Formulation
2
2
2
4
4


Thickness Y (mm)
7.00
8.50
8.50
4.50
4.50


Radius of sphere(mm)
12.0
13.5
13.5
12.0
12.0


Area S2 (mm2)
374
494
494
276
276


Volume V2 (mm3)
6715
9782
9782
5471
5471


Outer core Formulation
6
6
6
5
5


Thickness Z (mm)
7.85
6.55
6.35
8.05
7.85


Radius of core (mm)
19.85
20.05
19.85
20.05
19.85


Area S3 (mm2)
785
690
665
811
785


Volume V3 (mm3)
25524
23456
22456
26524
25524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
70
70
70
73
73


H(D) (JIS-C)
72
72
72
73
73


H(E) (JIS-C)
83
83
83
84
84


H(F) surface (JIS-C)
88
88
88
86
86


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
7
7
7
10
10


H(D) − H(C)
2
2
2
0
0


H(E) − H(D)
11
11
11
11
11


H(F) − H(E)
5
5
5
2
2


H(F) − H(A)
28
28
28
26
26
















TABLE 19







Configuration of Core













R19
R20
R21
R22
R23















Inner core Formulation
1
1
1
1
1


Radius X (mm)
7.5
7.5
3.0
3.0
10.0


Area S1 (mm2)
177
177
28
28
314


Volume V1 (mm3)
1767
1767
113
113
4189


Mid core Formulation
4
4
4
4
4


Thickness Y (mm)
4.50
4.50
9.00
10.50
2.00


Radius of sphere(mm)
12.0
12.0
12.0
13.5
12.0


Area S2 (mm2)
276
276
424
544
138


Volume V2 (mm3)
5471
5471
7125
10193
3049


Outer core Formulation
6
6
6
6
6


Thickness Z (mm)
8.05
7.85
7.85
6.35
7.85


Radius of core (mm)
20.05
19.85
19.85
19.85
19.85


Area S3 (mm2)
811
785
785
665
785


Volume V3 (mm3)
26524
25524
25524
22456
25524


H(A) central point
60
60
60
60
60


(JIS-C)







H(B) (JIS-C)
63
63
63
63
63


H(C) (JIS-C)
73
73
73
73
73


H(D) (JIS-C)
73
73
73
73
73


H(E) (JIS-C)
83
83
83
83
83


H(F) surface (JIS-C)
88
88
88
88
88


H(B) − H(A)
3
3
3
3
3


H(C) − H(B)
10
10
10
10
10


H(D) − H(C)
0
0
0
0
0


H(E) − H(D)
10
10
10
10
10


H(F) − H(E)
5
5
5
5
5


H(F) − H(A)
28
28
28
28
28
















TABLE 20







Configuration of Core













R24
R25
R26
R27
R28















Inner core Formulation
1
1
1
B1
B4


Radius X (mm)
10.0
7.5
7.5
5.0
5.0


Area S1 (mm2)
314
177
177
79
79


Volume V1 (mm3)
4189
1767
1767
524
524


Mid core Formulation
4
4
4
B2
B2


Thickness Y (mm)
3.50
1.00
9.00
8.00
8.00


Radius of sphere(mm)
13.5
8.5
16.5
13.0
13.0


Area S2 (mm2)
258
50
679
452
452


Volume V2 (mm3)
6117
805
17049
8679
8679


Outer core Formulation
6
6
6
B3
B3


Thickness Z (mm)
6.35
11.35
3.35
6.85
6.85


Radius of core (mm)
19.85
19.85
19.85
19.85
19.85


Area S3 (mm2)
665
1011
383
707
707


Volume V3 (mm3)
22456
30190
13945
23559
23559


H(A) central point
60
60
60
47
49


(JIS-C)







H(B) (JIS-C)
63
63
63
52
49


H(C) (JIS-C)
73
73
73
55
55


H(D) (JIS-C)
73
73
73
62
62


H(E) (JIS-C)
83
83
83
77
77


H(F) surface (JIS-C)
88
88
88
88
88


H(B) − H(A)
3
3
3
5
0


H(C) − H(B)
10
10
10
3
6


H(D) − H(C)
0
0
0
7
7


H(E) − H(D)
10
10
10
15
15


H(F) − H(E)
5
5
5
11
11


H(F) − H(A)
28
28
28
41
39
















TABLE 21







Configuration of Core











R29
R30
R31













Inner core Formulation
2
1
1


Radius X (mm)
7.5
7.5
7.5


Area S1 (mm2)
177
177
177


Volume V1 (mm3)
1767
1767
1767


Mid core Formulation
3
3
12


Thickness Y (mm)
4.50
4.50
4.50


Radius of sphere(mm)
12.0
12.0
12.0


Area S2 (mm2)
276
276
276


Volume V2 (mm3)
5471
5471
5471


Outer core Formulation
7
4
9


Thickness Z (mm)
7.90
7.90
7.90


Radius of core (mm)
19.9
19.9
19.9


Area S3 (mm2)
785
785
785


Volume V3 (mm3)
25524
25524
25524


H(A) central point
70
60
60


(JIS-C)





H(B) (JIS-C)
72
63
63


H(C) (JIS-C)
70
70
73


H(D) (JIS-C)
75
75
72


H(E) (JIS-C)
85
73
86


H(F) surface (JIS-C)
85
73
84


H(B) − H(A)
2
3
3


H(C) − H(B)
−2
7
10


H(D) − H(C)
5
5
−1


H(E) − H(D)
10
−2
14


H(F) − H(E)
0
0
−2


H(F) − H(A)
15
13
24
















TABLE 22







Configuration of Ball and Results of Evaluation













Ex. 1
Ex. 2
Ex. 3
Ex. 4
Ex. 5















Core







Type
E1
E2
E3
E4
E5


Angle α (°)
48.0
48.0
48.0
48.0
48.0


Angle β (°)
0.0
0.0
0.0
0.0
−14.0


Difference (α − β)
48.0
48.0
48.0
48.0
62.0


Ratio (Y/X)
0.6
0.6
0.6
0.6
0.6


Ratio (Z/X)
1.1
1.0
1.0
0.9
1.1


Ratio (S2/S1)
1.6
1.6
1.6
1.6
1.6


Ratio (S3/S1)
4.6
4.4
4.0
3.9
4.6


Ratio (V2/V1)
3.1
3.1
3.1
3.1
3.1


Ratio (V3/V1)
15.0
14.4
12.8
12.3
15.0


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2250
2300
2350
2400
2230


(W#1)Speed (m/s)
75.7
75.5
75.9
75.7
75.6


(W#1)Flight(m)
258.8
256.0
257.9
256.0
258.8
















TABLE 23







Configuration of Ball and Results of Evaluation
















Comp.
Comp.



Ex. 6
Ex. 7
Ex. 8
Ex. 1
Ex. 2















Core







Type
E6
E7
E8
R1
R2


Angle α (°)
48.0
48.0
48.0
24.0
24.0


Angle β (°)
−14.3
14.0
14.3
31.8
32.5


Difference (α − β)
62.3
34.1
33.7
−7.9
−8.5


Ratio (Y/X)
0.6
0.6
0.6
0.6
0.6


Ratio (Z/X)
1.0
1.1
1.0
1.1
1.0


Ratio (S2/S1)
1.6
1.6
1.6
1.6
1.6


Ratio (S3/S1)
4.4
4.6
4.4
4.6
4.4


Ratio (V2/V1)
3.1
3.1
3.1
3.1
3.1


Ratio (V3/V1)
14.4
15.0
14.4
15.0
14.4


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2280
2280
2330
2200
2250


(W#1)Speed (m/s)
75.4
75.6
75.4
75.2
75.0


(W# Flight(m)
256.0
257.9
256.0
253.3
250.5
















TABLE 24







Configuration of Ball and Results of Evaluation














Comp.
Comp.
Comp.
Comp.
Comp.
Comp.



Ex. 3
Ex. 4
Ex. 5
Ex. 6
Ex. 7
Ex. 8

















Core








Type
R3
R4
R5
R6
R7
R8


Angle α (°)
—
—
—
—
—
—


Angle β (°)
—
—
—
—
—
—


Difference
—
—
—
—
—
—


(α − β)


Ratio (Y/X)
—
—
—
—
—
—


Ratio (Z/X)
—
—
—
—
—
—


Ratio (S2/S1)
—
—
—
—
—
—


Ratio (S3/S1)
—
—
—
—
—
—


Ratio (V2/V1)
—
—
—
—
—
—


Ratio (V3/V1)
—
—
—
—
—
—


Mid layer


Inner mid layer
a
a
a
a
a
a


Thickness
1.0
1.0
1.0
1.0
1.8
1.8


(mm)


Outer mid layer
—
—
—
—
—
—


Thickness
—
—
—
—
—
—


(mm)


Cover


Inner cover
A
A
A
A
A
A


Thickness
0.3
0.5
0.3
0.5
0.3
0.5


(mm)


Outer cover
—
—
—
—
—
—


Thickness
—
—
—
—
—
—


(mm)


Ball


characteristics


Db (mm)
2.3
2.3
2.3
2.3
2.3
2.3


(W#1)
2350
2400
2250
2300
2350
2400


Spin (rpm)


(W#1)
74.9
74.7
75.2
75.0
75.4
75.2


Speed (m/s)


(W#1)
246.9
246.0
252.4
251.5
251.5
249.6


Flight (m)
















TABLE 25







Configuration of Ball and Results of Evaluation













Ex. 9
Ex. 10
Ex. 11
Ex. 12
Ex. 13















Core







Type
E9
E10
E11
E12
E13


Angle α (°)
39.8
39.8
39.8
39.8
39.8


Angle β (°)
0.0
0.0
0.0
0.0
−17.0


Difference (α − β)
39.8
39.8
39.8
39.8
56.8


Ratio (Y/X)
0.8
0.8
0.8
0.8
0.8


Ratio (Z/X)
0.9
0.8
0.8
0.7
0.9


Ratio (S2/S1)
2.2
2.2
2.2
2.2
2.2


Ratio (S3/S1)
3.9
3.8
3.3
3.2
3.9


Ratio (V2/V1)
4.8
4.8
4.8
4.8
4.8


Ratio (V3/V1)
13.3
12.7
11.1
10.6
13.3


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2150
2200
2250
2300
2130


(W#1)Speed (m/s)
75.4
75.2
75.6
75.4
75.3


(W#1)Flight (m)
256.9
254.2
256.0
254.2
256.9
















TABLE 26







Configuration of Ball and Results of Evaluation
















Comp.
Comp.



Ex. 14
Ex. 15
Ex. 16
Ex. 9
Ex. 10















Core







Type
E14
E15
E16
R9
R10


Angle α (°)
39.8
39.8
39.8
18.4
18.4


Angle β (°)
−17.5
17.0
17.5
37.4
38.2


Difference (α − β)
57.3
22.8
22.3
−18.9
−19.8


Ratio (Y/X)
0.8
0.8
0.8
0.8
0.8


Ratio (Z/X)
0.8
0.9
0.8
0.9
0.8


Ratio (S2/S1)
2.2
2.2
2.2
2.2
2.2


Ratio (S3/S1)
3.8
3.9
3.8
3.9
3.8


Ratio (V2/V1)
4.8
4.8
4.8
4.8
4.8


Ratio (V3/V1)
12.7
13.3
12.7
13.3
12.7


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2180
2180
2230
2100
2150


(W#1)Speed (m/s)
75.1
75.3
75.1
74.9
74.7


(W#1)Flight(m)
254.2
256.0
254.2
251.5
248.7
















TABLE 27







Configuration of Ball and Results of Evaluation













Ex. 17
Ex. 18
Ex. 19
Ex. 20
Ex. 21















Core







Type
E17
E18
E19
E20
E21


Angle α (°)
45.0
45.0
45.0
45.0
45.0


Angle β (°)
0.0
0.0
0.0
0.0
−11.3


Difference (α − β)
45.0
45.0
45.0
45.0
56.3


Ratio (Y/X)
1.0
1.0
1.0
1.0
1.0


Ratio (Z/X)
2.0
2.0
1.9
1.8
2.0


Ratio (S2/S1)
3.0
3.0
3.0
3.0
3.0


Ratio (S3/S1)
12.1
11.8
10.8
10.5
12.1


Ratio (V2/V1)
7.0
7.0
7.0
7.0
7.0


Ratio (V3/V1)
56.5
54.6
49.1
47.3
56.5


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2200
2250
2300
2350
2180


(W#1)Speed (m/s)
75.5
75.3
75.7
75.5
75.4


(W#1)Flight(m)
257.9
255.1
256.9
255.1
257.9
















TABLE 28







Configuration of Ball and Results of Evaluation
















Comp.
Comp.



Ex. 22
Ex. 23
Ex. 24
Ex. 11
Ex. 12















Core







Type
E22
E23
E24
R11
R12


Angle α (°)
45.0
45.0
45.0
21.8
21.8


Angle β (°)
−11.5
11.3
11.5
28.5
26.9


Difference (α − β)
56.5
33.7
33.5
−4.6
−5.1


Ratio (Y/X)
1.0
1.0
1.0
1.0
1.0


Ratio (Z/X)
2.0
2.0
2.0
2.0
2.0


Ratio (S2/S1)
3.0
3.0
3.0
3.0
3.0


Ratio (S3/S1)
11.8
12.1
11.8
12.1
11.8


Ratio (V2/V1)
7.0
7.0
7.0
7.0
7.0


Ratio (V3/V1)
54.6
56.5
54.6
56.5
54.6


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2230
2230
2280
2150
2200


(W#1)Speed (m/s)
75.2
75.4
75.2
75.0
74.8


(W#1)Flight(m)
255.1
256.9
255.1
252.4
249.6
















TABLE 29







Configuration of Ball and Results of Evaluation













Ex. 25
Ex. 26
Ex. 27
Ex. 28
Ex. 29















Core







Type
E25
E26
E27
E28
E29


Angle α (°)
35.5
35.5
35.5
35.5
35.5


Angle β (°)
0.0
0.0
0.0
0.0
−14.0


Difference (α − β)
35.5
35.5
35.5
35.5
49.5


Ratio (Y/X)
1.4
1.4
1.4
1.4
1.4


Ratio (Z/X)
1.6
1.6
1.5
1.4
1.6


Ratio (S2/S1)
4.8
4.8
4.8
4.8
4.8


Ratio (S3/S1)
10.3
10.0
9.1
8.8
10.3


Ratio (V2/V1)
12.8
12.8
12.8
12.8
12.8


Ratio (V3/V1)
50.7
48.7
43.2
41.5
50.7


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2150
2200
2250
2300
2130


(W#1)Speed(m/s)
75.4
75.2
75.6
75.4
75.3


(W#1)Flight (m)
256.9
254.2
256.0
254.2
256.9
















TABLE 30







Configuration of Ball and Results of Evaluation
















Comp.
Comp.



Ex. 30
Ex. 31
Ex. 32
Ex. 13
Ex. 14















Core







Type
E30
E31
E32
R13
R14


Angle α (°)
35.5
35.5
35.5
15.9
15.9


Angle β (°)
−14.3
14.0
14.3
31.8
32.5


Difference (α − β)
49.8
21.6
21.2
−15.9
−16.5


Ratio (Y/X)
1.4
1.4
1.4
1.4
1.4


Ratio (Z/X)
1.6
1.6
1.6
1.6
1.6


Ratio (S2/S1)
4.8
4.8
4.8
4.8
4.8


Ratio (S3/S1)
10.0
10.3
10.0
10.3
10.0


Ratio (V2/V1)
12.8
12.8
12.8
12.8
12.8


Ratio (V3/V1)
48.7
50.7
48.7
50.7
48.7


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2180
2180
2230
2100
2150


(W#1)Speed (m/s)
75.1
75.3
5.1
74.9
74.7


(W#1)Flight(m)
254.2
256.0
254.2
251.5
248.7
















TABLE 31







Configuration of Ball and Results of Evaluation













Ex. 33
Ex. 34
Ex. 35
Ex. 36
Ex. 37















Core







Type
E33
E34
E35
E36
E37


Angle α (°)
30.5
30.5
30.5
30.5
30.5


Angle β (°)
0.0
0.0
0.0
0.0
−17.0


Difference (α − β)
30.5
30.5
30.5
30.5
47.5


Ratio (Y/X)
1.7
1.7
1.7
1.7
1.7


Ratio (Z/X)
1.3
1.3
1.2
1.1
1.3


Ratio (S2/S1)
6.3
6.3
6.3
6.3
6.3


Ratio (S3/S1)
8.8
8.5
7.5
7.2
8.8


Ratio (V2/V1)
18.7
18.7
18.7
18.7
18.7


Ratio (V3/V1)
44.8
42.9
37.4
35.6
44.8


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2100
2150
2200
2250
2080


(W#1)Speed (m/s)
75.3
75.1
75.5
75.3
75.2


(W#1)Flight(m)
256.9
254.2
256.0
254.2
256.9
















TABLE 32







Configuration of Ball and Results of Evaluation
















Comp.
Comp.



Ex. 38
Ex. 39
Ex. 40
Ex. 15
Ex. 16















Core







Type
E38
E39
E40
R15
R16


Angle α (°)
30.5
30.5
30.5
13.2
13.2


Angle β (°)
−17.5
17.0
17.5
37.4
38.2


Difference (α − β)
47.9
13.5
13.0
−24.1
−25.0


Ratio (Y/X)
1.7
1.7
1.7
1.7
1.7


Ratio (Z/X)
1.3
1.3
1.3
1.3
1.3


Ratio (S2/S1)
6.3
6.3
6.3
6.3
6.3


Ratio (S3/S1)
8.5
8.8
8.5
8.8
8.5


Ratio (V2/V1)
18.7
18.7
18.7
18.7
18.7


Ratio (V3/V1)
42.9
44.8
42.9
44.8
42.9


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin(rpm)
2130
2130
2180
2050
2100


(W#1)Speed (m/s)
75.0
75.2
75.0
74.8
74.6


(W#1)Flight(m)
254.2
256.0
254.2
251.5
248.7
















TABLE 33







Configuration of Ball and Results of Evaluation













Ex. 41
Ex. 42
Ex. 43
Ex. 44
Ex. 45















Core







Type
E41
E42
E43
E44
E45


Angle α (°)
0.0
0.0
0.0
0.0
0.0


Angle β (°)
0.0
0.0
0.0
0.0
−14.0


Difference (α − β)
0.0
0.0
0.0
0.0
14.0


Ratio (Y/X)
0.6
0.6
0.6
0.6
0.6


Ratio (Z/X)
1.1
1.0
1.0
0.9
1.1


Ratio (S2/S1)
1.6
1.6
1.6
1.6
1.6


Ratio (S3/S1)
4.6
4.4
4.0
3.9
4.6


Ratio (V2/V1)
3.1
3.1
3.1
3.1
3.1


Ratio (V3/V1)
15.0
14.4
12.8
12.3
15.0


Mid layer







Inner mid layer
a
a
b
b
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
c
c
—


Thickness (mm)
—
—
0.8
0.8
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.3
0.5
0.3
0.5
0.3


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2300
2350
2400
2450
2280


(W#1)Speed (m/s)
75.8
75.6
76.0
75.8
75.7


(W#1)Flight(m)
257.9
255.1
256.9
255.1
257.9
















TABLE 34







Configuration of Ball and Results of Evaluation














Comp.
Comp.
Comp.
Comp.



Ex. 46
Ex. 17
Ex. 18
Ex. 19
Ex. 20















Core







Type
E46
R17
R18
R19
R20


Angle α (°)
0.0
0.0
0.0
0.0
0.0


Angle β (°)
−14.3
14.0
14.3
31.8
32.5


Difference (α − β)
14.3
−14.0
−14.3
−31.8
−32.5


Ratio (Y/X)
0.6
0.6
0.6
0.6
0.6


Ratio (Z/X)
1.0
1.1
1.0
1.1
1.0


Ratio (S2/S1)
1.6
1.6
1.6
1.6
1.6


Ratio (S3/S1)
4.4
4.6
4.4
4.6
4.4


Ratio (V2/V1)
3.1
3.1
3.1
3.1
3.1


Ratio (V3/V1)
14.4
15.0
14.4
15.0
14.4


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.3
0.5
0.3
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2330
2300
2350
2250
2300


(W#1)Speed (m/s)
75.5
75.4
75.2
75.3
75.1


(W#1)Flight(m)
255.1
253.3
250.5
252.4
249.6
















TABLE 35







Configuration of Ball and Results of Evaluation













Ex. 47
Ex. 48
Ex. 49
Ex. 50
Ex. 51















Core







Type
E47
E48
E49
E50
E51


Angle α (°)
0.0
0.0
0.0
0.0
0.0


Angle β (°)
0.0
0.0
0.0
0.0
0.0


Difference (α − β)
0.0
0.0
0.0
0.0
0.0


Ratio (Y/X)
3.0
3.5
0.2
0.4
0.1


Ratio (Z/X)
2.6
2.1
0.8
0.6
1.5


Ratio (S2/S1)
15.0
19.3
0.4
0.8
0.3


Ratio (S3/S1)
27.8
23.5
2.5
2.1
5.7


Ratio (V2/V1)
63.0
90.1
0.7
1.5
0.5


Ratio (V3/V1)
225.7
198.6
6.1
5.4
17.1


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.5
0.5
0.5
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2450
2350
2250
2150
2500


(W#1)Speed (m/s)
75.7
75.5
75.3
75.1
75.8


(W#1)Flight(m)
254.2
254.2
254.2
254.2
254.2
















TABLE 36







Configuration of Ball and Results of Evaluation














Comp.
Comp.
Comp.
Comp.



Ex. 52
Ex. 21
Ex. 22
Ex. 23
Ex. 24















Core







Type
E52
R21
R22
R23
R24


Angle α (°)
0.0
0.0
0.0
0.0
0.0


Angle β (°)
0.0
32.5
38.2
32.5
38.2


Difference (α − β)
0.0
−32.5
−38.2
−32.5
−38.2


Ratio (Y/X)
1.2
3.0
3.5
0.2
0.4


Ratio (Z/X)
0.4
2.6
2.1
0.8
0.6


Ratio (S2/S1)
3.8
15.0
19.3
0.4
0.8


Ratio (S3/S1)
2.2
27.8
23.5
2.5
2.1


Ratio (V2/V1)
9.6
63.0
90.1
0.7
1.5


Ratio (V3/V1)
7.9
225.7
198.6
6.1
5.4


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.5
0.5
0.5
0.5


Outer cover
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Ball







characteristics







Db (mm)
2.3
2.3
2.3
2.3
2.3


(W#1)Spin (rpm)
2200
2400
2300
2200
2100


(W#1)Speed (m/s)
75.4
75.2
75.0
74.8
74.6


(W#1)Flight(m)
254.2
248.7
248.7
248.7
248.7
















TABLE 37







Configuration of Ball and Results of Evaluation













Comp.
Comp.
Comp.
Comp.




Ex. 25
Ex. 26
Ex. 27
Ex. 28
Ex. 53















Core







Type
R25
R26
R27
R28
E2


Angle α (°)
0.0
0.0
41.2
41.2
48.0


Angle β (°)
23.8
56.2
58.1
58.1
0.0


Difference (α − β)
−23.8
−56.2
−16.9
−16.9
48.0


Ratio (Y/X)
0.1
1.2
1.6
1.6
0.6


Ratio (Z/X)
1.5
0.4
1.4
1.4
1.0


Ratio (S2/S1)
0.3
3.8
5.8
5.8
1.6


Ratio (S3/S1)
5.7
2.2
9.0
9.0
4.4


Ratio (V2/V1)
0.5
9.6
16.6
16.6
3.1


Ratio (V3/V1)
17.1
7.9
45.0
45.0
14.4


Mid layer







Inner mid layer
a
a
a
a
a


Thickness (mm)
1.0
1.0
1.0
1.0
1.0


Outer mid layer
—
—
—
—
—


Thickness (mm)
—
—
—
—
—


Cover







Inner cover
A
A
A
A
A


Thickness (mm)
0.5
0.5
0.5
0.5
0.3


Outer cover
—
—
—
—
B


Thickness (mm)
—
—
—
—
0.2


Ball







characteristics







Db (mm)
2.3
2.3
2.4
2.4
2.3


(W#1)Spin (rpm)
2450
2150
2100
2100
2000


(W#1)Speed (m/s)
75.3
74.9
74.8
74.8
75.5


(W#1)Flight(m)
248.7
248.7
251.1
251.5
257
















TABLE 38







Configuration of Ball and Results of Evaluation











Comp.
Comp.
Comp.



Ex. 29
Ex. 30
Ex. 31















Core






Type
R29
R30
R31



Angle α (°)
48.0
48.0
−10



Angle β (°)
0.0
0.0
−20



Difference (α − β)
48.0
48.0
30



Ratio (Y/X)
0.6
0.6
0.6



Ratio (Z/X)
1.0
1.0
1.0



Ratio (S2/S1)
1.6
1.6
1.6



Ratio (S3/S1)
4.4
4.4
4.4



Ratio (V2/V1)
3.1
3.1
3.1



Ratio (V3/V1)
14.4
14.4
14.4



Mid layer






Inner mid layer
a
a
a



Thickness (mm)
1.0
1.0
1.0



Outer mid layer
—
—
—



Thickness (mm)
—
—
—



Cover






Inner cover
A
A
A



Thickness (mm)
0.5
0.5
0.5



Outer cover
—
—
—



Thickness (mm)
—
—
—



Ball






characteristics






Db (mm)
2.3
2.3
2.3



(W#1)Spin (rpm)
2450
2500
2250



(W#1)Speed (m/s)
75.5
75.6
75.2



(W#1)Flight(m)
253.3
253.3
252.4









As shown in Tables 22 to 38, with the golf ball of each Example, excellent flight performance is exerted upon a shot with a driver. From the results of evaluation, advantages of the present invention are clear.
The golf ball according to the present invention can be used for playing golf on golf courses and practicing at driving ranges. The above descriptions are merely illustrative examples, and various modifications can be made without departing from the principles of the present invention.

## Claims

1. A golf ball comprising a spherical core and a cover positioned outside the core, wherein
the core includes an inner core, a mid core positioned outside the inner core, and an outer core positioned outside the mid core,
a JIS-C hardness H(C) at a point C present outward from a boundary between the inner core and the mid core in a radius direction by 1 mm is equal to or greater than a JIS-C hardness H(B) at a point B present inward from the boundary between the inner core and the mid core in the radius direction by 1 mm,
a JIS-C hardness H(E) at a point E present outward from a boundary between the mid core and the outer core in the radius direction by 1 mm is equal to or greater than a JIS-C hardness H(D) at a point D present inward from the boundary between the mid core and the outer core in the radius direction by 1 mm, and
when an angle (degree) calculated by (Formula 1) from a thickness Y (mm) of the mid core, the hardness H(C), and the hardness H(D) is defined as an angle α and an angle (degree) calculated by (Formula 2) from a thickness Z (mm) of the outer core, the hardness H(E), and a JIS-C hardness H(F) at a point F located on a surface of the core is defined as an angle β:


α=(180/π)*a tan [{H(D)−H(C)}/Y]  (Formula 1); and



β=(180/π)*a tan [{H(F)−H(E)}/Z]  (Formula 2),


the angle α is equal to or greater than 0°, and
a difference (α−β) between the angle α and the angle β is equal to or greater than 0°,
wherein the inner core, the mid core, and the outer core comprise different thermoset rubber compositions.

2. The golf ball according to claim 1, wherein the angle β is equal to or greater than −20° but equal to or less than +20°.

3. The golf ball according to claim 1, wherein
a ratio (Y/X) of the thickness Y of the mid core relative to a radius X of the inner core is equal to or greater than 0.5 but equal to or less than 2.0, and
a ratio (Z/X) of the thickness Z of the outer core relative to the radius X is equal to or greater than 0.5 but equal to or less than 2.5.

4. The golf ball according to claim 1, wherein
a ratio (S2/S1) of a cross-sectional area S2 of the mid core relative to a cross-sectional area S1 of the inner core on a cut surface of the core that has been cut into two halves is equal to or greater than 1.0 but equal to or less than 8.0, and
a ratio (S3/S1) of a cross-sectional area S3 of the outer core relative to the cross-sectional area S1 on the cut surface of the core is equal to or greater than 2.5 but equal to or less than 12.5.

5. The golf ball according to claim 1, wherein
a ratio (V2/V1) of a volume V2 of the mid core relative to a volume V1 of the inner core is equal to or greater than 2.5 but equal to or less than 20.0, and
a ratio (V3/V1) of a volume V3 of the outer core relative to the volume V1 is equal to or greater than 10.0 but equal to or less than 57.0.

6. The golf ball according to claim 1, further comprising a mid layer between the core and the cover.

7. The golf ball according to claim 6, wherein the mid layer includes an inner mid layer and an outer mid layer positioned outside the inner mid layer.

8. The golf ball according to claim 1, wherein the cover includes an inner cover and an outer cover positioned outside the inner cover.