# Patent

## Title
Boiler tube having improved high temperature mechanical strength,

## Abstract

A permanently solderable palladium-nickel electroplated coating is formed on electrically conductive surfaces. The coating has a first alloy layer of 46 to 82 atomic percent palladium and 18 to 54 atomic percent nickel. This first layer is covered by a continuous second layer of 96 to 100 atomic percent metallic palladium and 0-4 atomic percent nickel. The second layer has a thickness of up to twenty angstroms. The second layer is formed by dipping the first layer in a solution of sulfuric or hydrochloric acid.

## Background
1. Field of the Invention

This invention relates to electrically conductive coated surfaces. More specifically, it refers to a permanently solderable palladium-nickel alloy coating on an electrically conductive substrate.

2. Description of the Prior Art

Gold platings are commonly used to protect electrical contacts from corrosion and at the same time maintain solderability properties and low electrical contact resistance at low loads. Unfortunately, gold platings are extremely expensive. Lower cost substitutes have been sought such as palladium-nickel alloys. A typical method of forming a palladium-nickel alloy on an electrically conductive substrate is set forth in U.S. Pat. No. 4,100,039. While known palladium nickel alloys provide a less expensive corrosion-resistant layer, they suffer from reduced solderability properties and increased electrical contact resistance at low normal loads.

I have discovered a palladium-nickel electroplated surface coating for an electrically conductive substrate that effectively protects the substrate from corrosion and at the same time is permanently solderable and exhibits reduced electrical contact resistance at low loads. My coating is an electrodeposited alloy layer about 0.1 to 1.5 micrometers thick of about 46 to 82 atmoic percent palladium and about 18 to 54 atomic percent nickel adhered to an electrically conductive substrate such as nickel, brass, copper or phosphor bronze. Over this layer is a continuous covering surface layer of about 96 to 100 atomic percent metallic palladium and about 0-4 atomic percent nickel. This surface layer has a thickness no greater than about twenty angstroms .ANG. or approximately 9 to 10 atomic layers.

The present invention may be best understood by those having ordinary skill in the art by reference to the following detailed description when considered in conjunction with the accompanying drawings in which:

FIG. 1 is a graph of Sample 1c in Example 1 having as the abscissa, the coating depth below the surface in angstroms and as the ordinate, the atomic percent metal species;

FIG. 2 is a graph of Sample 2a in Example 2 having as the abscissa, the coating depth below the surface in angstroms and as the ordinate, the atomic percent metal species; and

FIG. 3 is a graph of Sample 2b of Example 2 having as the abscissa, the coating depth below the surface in angstroms and as the ordinate, the atomic percent metal species.

The coating surface of this invention is prepared by first starting with a substrate such as a phosphor bronze wire which is electroplated in a bath containing 10 to 18 grams per liter palladium (II) ammine chloride, 5 to 11 grams per liter nickel ammine sulfate, a small amount of brightener such as sodium vinyl sulfonate, sodium allyl sulfonate or quaternized pyridine and 30 to 50 grams per liter ammonium sulfate or ammonium chloride.

The electroplating conditions require a temperature of about 35.degree. C. to 55.degree. C., a pH of about 7.5-9, a current density of about 5 to 25 amp/sq dm, and a vigorous agitation while the wire is in solution. A coating of palladium-nickel of about 0.1 to 1.5 micrometers thick is produced. The coating has a bulk content of 46-82 atomic percent palladium and the balance nickel.

I found that by treating the palladium-nickel surface with either sulfuric or hydrochloric acid, there is created an extremely thin, continuous layer of 96-100 atomic percent metallic palladium and 4-0atomic percent nickel on top of the electroplated coating of palladium-nickel alloy. The thickness of the palladium enriched surface layer is less than or equal to 20 .ANG., which is equivalent to about 9-10 atomic layers.

The continuous film, of 96-100% pure palladium achieved by treating with sulfuric or hydrochloric acid, which is only 20 .ANG. thick, cannot be desposited on any polycrystalline surface via electroplating or by vapor phase deposition techniques. It is well established that attempts to electroplate or vapor phase deposit coatings having a 20 .ANG. thick layer produce deposits of isolated islands of atoms and not a continuous layer such as produced by my acid treatment. The first continuous film that can be formed by electroplating or vapor phase processes has a thickness in the order of 150-1000 .ANG., contrasted to the 20 .ANG. thickness produced in my coating.

FIGS. 1 and 3 show the elemental composition profiles for acid-treated palladium-nickel alloy surfaces that are the fingerprint of this invention. These profiles are distinctly different from those of as plated bulk palladium-nickel surfaces that have been office-aged in an industrial environment such as that shown in FIG. 2. The office-aged surfaces contain substantial amounts of ionic nickel species, Ni.sup.2+ and, in some cases, ionic Pd.sup.2+ series which are present as oxides and chlorides. These aged surfaces do not pass the solderability tests and they exhibit high electrical contact resistance at low contact loads. After acid treatment according to the teachings of this invention, the surface consists of 96-100 atomic percent metallic palladium (Pd.sup.o) and a small amount, 4-0 atomic percent metallic nickel. The acid-treated surfaces exhibit excellent solderability and possess low electrical contact resistance (less than 22 m.OMEGA. at 10 grams normal force).

The extremely thin continuous palladium-rich layer of this invention is stable against destruction by oxidation to ionic species. It is also stable against destruction by diffusion of nickel to surface from bulk of the alloy. This stability is evidenced by no change in the composition of properties during a variety of aging treatments to which electronic components are subjected including the following: exceeding 28 months; for certification of electronic components; and component users.

Significant changes during aging are observed in the chemistry and performance of untreated palladium-nickel alloy coatings affecting their solderability and electrical performance.

The acid treating procedures used to produce the unique coatings of this invention are achieved by immersing electrolytically deposited palladium-nickel coatings in a static aqueous solution composed of 20 volume percent concentrated sulfuric acid for 30 seconds at ambient temperature. After treatment, the coating is rinsed thoroughly and allowed to dry.

Concentration ranges of 1 through 100 volume percent concentrated sulfuric acid may be used to achieve this invention. As concentrations of the sulfuric acid approach 1 volume percent in a static solution, treatment time must be lengthened to produce the unique coating surface, i.e., immersing electrolytically deposited palladium-nickel in a static aqueous solution of of 1 volume percent concentrated sulfuric acid for 30 minutes at ambient temperature.

Agitation has a significant effect on acquired dwell time in the treatment solution. With vigorous agitation, the invention can be achieved by immersing an electrolytically deposited palladium-nickel coating in a solution of 10 volume percent concentrated sulfuric acid for 0.4 sec. at ambient temperature.

Immersion of electrolytically deposited palladium-nickel in a static solution of 20 volume percent concentrated hydrochloric acid for 30 seconds at ambient temperature will also yield the described surface.

Not all acid solutions are useful in achieving this invention. Treatment with aqueous solutions such as 20 volume percent concentrated nitric acid, 50 volume percent glacial acetic acid, and 50 volume percent concentrated phosphoric acid yield surfaces which are not similar to those described in the invention.

X-ray Photoelectron Spectroscopy (XPS) technique, also referred to as Electron Spectroscopy for Chemical Analysis (ESCA), was used for chemical analysis of the surfaces of palladium-nickel alloy coatings. XPS analysis is based upon a determination of the binding energy for orbital electrons that are removed from the atoms at the surface when it is bombarded with soft x-rays. Binding energies of the emitted orbital photoelectrons indicate not only the elements that are present but also the valence state of the elements. Therefore, in XPS analysis of palladium-nickel alloy surfaces, it is possible to determine the atomic percent of the elements in the metallic or zero valence state (Pd.sup.o and Ni.sup.o species) and the atomic percent of the elements in positive ionic valence states (Pd.sup.2+ and Ni.sup.2+) that are present in compounds such as oxides and chlorides.

The XPS conditions for my investigation were as follows:

Type of X-Ray Radiation: MgK (1253.6 eV)

Accelerating voltage: 15 kV

Tube power setting: 300 Watts

Beam width at 1/2 maximum intensity: 4.5 .mu.m

Take-off angle: 50.degree.

In the calculation of the XPS surface chemistry for the samples of this invention, only the metal element components were considered. The binding energies of the photoelectrons used to determine the atomic percent of metal components for the palladium-nickel alloy surfaces are listed below: ELECTRON     BINDING ELEMENTAL     ORBIT        ENERGY COMPONENT     DESIGNATION  eV ______________________________________ Pd.sup.o      3d.sub.5/2   335 Pd.sup.2+     3d.sub.5/2   339 Ni.sup.o      2p.sub.3/2   852 Ni.sup.2+     2p.sub.3/2   855 ______________________________________

In the XPS analysis of palladium-nickel alloy coatings, the region being analyzed for nickel extends to a depth of over about 20 angstroms (.ANG.) below the surface because the nickel 2p.sub.3/2 electrons excited from depths greater than this do not have sufficient energy to escape from the coating. A depth below the surface of the palladium-nickel alloy of 20 .ANG. is equivalent to about 9 to 10 atomic layers. The thickness of the electrodeposited palladium-nickel alloy coatings under investigation ranged from 0.1 to 1.5 micrometers (.mu.m) which is equivalent to 1000-15,000 .ANG.. The XPS technique is ideally suited for the chemical analysis of thin regions at the surface of the palladium-nickel alloy coatings that determine their solderability and their electrical contact resistance, two of the most important properties of the coatings for electronic connector applications.

For selective samples, XPS chemistry profiles were obtained for the metal element components as a function of distance (X) below the original surface. The first step was to conduct an XPS analysis of the original surface layer which extends from X=0 to 20 .ANG.. Then, defined thicknesses of material were removed by argon ion sputtering and XPS analyses were conducted after each thickness removal step. The incremental thicknesses that were removed by sputtering in terms of distance (X) from the original surface were 12.5, 25, 50 and 100 .ANG.. In all cases, the region being analyzed extended to the depth of 20 .ANG. below the surface under analysis. Therefore, the compositional data input in XPS profiles such as those in FIGS. 1, 2 and 3 were plotted at locations 20 .ANG. below the surface being analyzed or at distances of 32.5, 45, 70 and 120 .ANG. below the original surface. FIG. 1 shows a typical XPS profile.

The conditions for argon sputter removal of material from palladium-nickel alloy surfaces were as follows:

Ion source: Argon gas

Ion acceleration voltage: 4 kV

Careful control of these conditions and the sputtering current resulted in a reproducible unform sputter removal rate of 22 .ANG./min on palladium-nickel alloy coatings.

The bulk palladium-nickel coating before acid treatment had significant amounts of Pd.sup.2+ and Ni.sup.2+ on its surface which prevents easy wetting by soldering. This is evidenced by only an 80% solder coverage. In order to achieve industry standard solderability approval, the solder coverage must be at least 95%. The use of state of the art solder fluxes such as Alpha 611 and 809 at room temperatures did not significantly reduce or remove Pd.sup.2+ or Ni.sup.2+ to the metallic species and therefore the solderability was not improved.

The following specific examples describe the invention in greater detail. All examples were carried out on copper alloy substrates, either a wire or disk, that had been subjected to conventional preplate treatments as practiced in the art and then electroplated with a pure nickel coating by a conventional nickel sulfamate plating process. The nickel undercoat prevents copper contamination of the plating bath but is not necessary to the practice of the invention.

All sufuric acid treatments except as otherwise noted consisted of immersion in a twenty volume percent sulfuric acid solution for thirty seconds at ambient temperature.

A palladium-nickel alloy coating 0.9 .mu.m thick was electrodeposited on nickel-plated copper alloy wire substrates using the following bath chemistry and plating conditions: Bath Chemistry Pd Concentration: 17 g/l as palladium (II) ammine chloride Ni Concentration: 10 g/l as nickel ammine sulfate Sodium vinyl    14 g/l sulfonate: Ammonium sulfate: 50 g/l Plating Conditions Temperature     37.degree. C. pH:             8.9 Current Density: 25 amp/sq dm Solution Agitation: Vigorous ______________________________________

The bulk electroplated palladium-nickel alloy on the wire contained 81 atomic percent palladium and 19 atomic percent nickel. The plated samples were then subjected to the treatments outlined in Table I. ______________________________________ 20 .ANG. Surface Layer Sam-             Composition ple  Treatment   (Atomic %)      Solderability Code History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 1a   Office       80    9    0    11   91 aged for 12 months in an industrial environment 1b   Office      100    0    0    0    99 aged for 12 months plus Sulfuric acid treatment 1c   Office      100    0    0    0    98 aged for 12 months Sulfuric acid treatment Office aged for 18 months in an industrial environment ______________________________________

After each treatment the surface chemistry was determined by XPS analysis and solderability was evaluated according to United States Military Standard 202, Method 208.

The original surface (X=0 to 20 .ANG.) of an electrodeposited palladium-nickel alloy coating aged for 12 months in an industrial office environment consisted of a mixture of Ni.sup.2+, Pd.sup.2+ and Pd.sup.o species. See XPS analysis for Sample 1a in Table I. The aged surface with these species failed the solderability dip test since solder coverage was less than 95% of the coating surface. Sulfuric acid treatment of the aged palladium-nickel alloy coating created a surface consisting of a continuous layer of pure metallic palladium (Pd.sup.o) and 99% coverage in the solderability test. See Sample 1b. The absence of nickel Ni.sup.2+ or Ni.sup.o species after sulfuric acid treatment indicates that the 100% pure metallic palladium layer is continuous.

The chemistry of the pure metallic palladium (Pd.sup.o) surface layer created by the sulfuric acid treatment was unchanged after 18 months of aging in an industrial office environment. There is no indication of diffusion of nickel from the bulk palladium-nickel alloy coating to the surface or of oxidation of the metallic palladium (Pd.sup.o) species to a Pd.sup.2+ species. See Sample 1c. The thickness of the stable, continuous, pure, metallic palladium layer on Sample 1c is only 20 .ANG. as indicated by the XPS chemistry profiles in FIG. 1.

Another set of palladium-nickel electroplated wires prepared in the same manner as the samples of Example 1 were subjected to the treatments outlined in Table II: ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment   (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 2a    Office     62     26   0    12    80 aged for 22 months in an industrial environment 2b    Office     99     0    1    0    100 aged for 22 months plus Sulfuric acid treatment ______________________________________

After the treatments, XPS chemistry profiles were obtained of the surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

XPS composition depth profiles for these samples appear in FIGS. 2 and 3. The office-aged (Sample 2a) sample which failed the solderability test has a surface with substantial amounts of Ni.sup.2+ and Pd.sup.2+ species and only 62 atomic percent metallic palladium (Pd.sup.o) as shown in FIG. 2. Sample 2b that was sulfuric acid treated after office aging passed the solderability test. It has a 20 .ANG. thick surface layer that is 99 atomic percent metallic palladium (Pd.sup.o) and one atomic percent metallic nickel (Ni.sup.o) as shown in FIG. 3.

A palladium-nickel coating 1.3 .mu.m thick having a bulk composition of 76 atomic % palladium and 24 atomic % nickel was electrodeposited on a nickel-plated copper alloy disk using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration:  18 g/l as palladium (II) ammine chloride Ni Concentration:  10 g/l as nickel ammine sulfate Sodium Allyl Sulfonate: 1.7 g/l Ammonium Sulfate:  50 g/l Plating Conditions Temperature:       55.degree. C. pH:                8.7 Current Density:   16 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table III. ______________________________________ 20 .ANG. Surface Layer Sam-             Composition ple  Treatment   (Atomic %)      Solderability Code History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 3a   Office       90    0    0    10   92 aged for 25 months in an industrial environment 3b   Office      100    0    0    0    98 aged for 25 months plus Sulfuric acid treatment ______________________________________

After the treatments, XPS chemistry profiles were obtained of the sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Sample 3a failed the solderability test whereas the sulfuric acid-treated Sample 3b passed the solderability test.

A palladium-nickel coating 0.8 .mu.m thick having a bulk composition of 70 atomic percent palladium and 30 atomic percent nickel was electrodeposited on a nickel-plated copper alloy disk using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration: 11.8 g/l as palladium (II) ammine chloride Ni Concentration: 5.2 g/l as nickel chloride Quaternized Pyridine: 600 ppm Ammonium Chloride: 30 g/l Plating Conditions Temperature:      50.degree. C. pH:               8.5 Current Density:  5 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table IV. ______________________________________ 20 .ANG. Surface Layer Sam-             Composition ple  Treatment   (Atomic %)      Solderability Code History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 4a   Office       83    0    0    17   93 aged for 28 months in an industrial environment 4b   Office      100    0    0    0    99 aged for 28 months plus Sulfuric acid treatment ______________________________________

After treatment, XPS chemistry profiles were obtained of the sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Sample 4a failed the solderability test whereas the acid-treated Sample 4b passed.

A palladium-nickel coating 0.8 .mu.m thick having a bulk composition of 55 atomic percent palladium and 45 atomic percent nickel was electrodeposited on a nickel-plated copper alloy disk using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration: 10 g/l as palladium (II) ammine chloride Ni Concentration: 6 g/l as nickel chloride Quaternized Pyridine: 600 ppm Ammonium Chloride: 30 g/l Plating Conditions Temperature:    50.degree. C. pH:             7.5 Current Density: 5 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table V. ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment  (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 5a    Aged at     69    0    0    31   89 125.degree. C. for 50 hrs. in air and Office aged for 28 months in an industrial environment 5b    Aging      100    0    0    0    99 treatment of 5a plus Sulfuric acid treatment ______________________________________

After the treatment, XPS chemistry profiles were obtained of the sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Sample 5a failed the solderability test whereas the acid-treated Sample 5b passed.

A palladium-nickel coating 1.3 .mu.m thick having a bulk composition of 46 atomic percent palladium and 54 atomic percent nickel was electrodeposited on a nickel-plated copper alloy disk using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration: 17 g/l as palladium (II) ammine chloride Ni Concentration: 11 g/l as nickel ammine sulfate Sodium Vinyl Sulfonate 2.8 g/l Ammonium Sulfate: 50 g/l Plating Conditions Temperature:    48.degree. C. pH:             8.0 Current Density: 8.7 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table VI. ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment  (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 6a    Aged in    56     0    0    44    80 steam for 1 hr. as per Military Standard 202, Method 208 6b    Steam      98     0    0     2   100 aged as per Military Standard plus Sulfuric acid treatment ______________________________________

After the treatments, XPS chemistry profiles were obtained of the sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Sample 6a failed the solderability test whereas the acid-treated Sample 6b passed.

A palladium-nickel alloy coating 0.9 .mu.m thick having a bulk composition of 81 atomic percent palladium and 19 atomic percent nickel was electrodeposited on nickel-plated copper alloy wire using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration: 17 g/l as palladium (II) ammine chloride Ni Concentration: 10 g/l as nickel ammine sulfate Sodium Vinyl Sulfonate: 1.4 g/l Ammonium Sulfate: 50 g/l Plating Conditions Temperature:    37.degree. C. pH:             8.9 Current Density: 25 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table VII. ______________________________________ 20 .ANG. Surface Layer Sam-             Composition ple  Treatment   (Atomic %)      Solderability Code History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 7a   Office      96     0    4    0    100 aged for 24 months in an industrial environment plus Sulfuric acid treatment 7b   Office      96     0    4    0     99 aged for 24 months in an industrial environment plus Sulfuric acid treatment plus Steam aging for 1 hr. as per Military Standard 202, Method 208 ______________________________________

After the treatments, XPS chemistry profiles were obtained of the sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Both sulfuric acid-treated samples passed the 95% minimum solder coverage criterion. Steam aging of one sample after sulfuric acid treatment according to the Military Standard did not change its palladium-rich composition or its ability to pass the solderability criterion.

A palladium-nickel alloy coating 0.9 .mu.m thick was electrodeposited on nickel-plated copper alloy wire using the following bath chemistry and plating conditions: Bath Chemistry Pd Concentration: 17 g/l as palladium (II) ammine chloride Ni Concentration: 10 g/l as nickel ammine sulfate Sodium Vinyl Sulfonate: 1.4 g/l Ammonium Sulfate: 50 g/l Plating Conditions Temperature:    37.degree. C. pH              8.9 Current Density 25 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were then subjected to the treatments outlined in Table VIII. ______________________________________ 20 .ANG. Surface Layer Sam-              Composition     Solderability ple  Treatment    (Atomic %)      (% Code History      Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ Coverage) ______________________________________ 8a   Aged for      27    40   0    33    80 24 mos. in an industrial environment 8b   Aged for     100    0    0    0    100 24 mos. in an industrial environment plus Sulfuric acid treatment 8c   Aged for     100    0    0    0    095 24 mos. in an industrial environment and treated with 100 volume % H.sub.2 SO.sub.4 for 30 sec at ambient temperatures 8d   Aged for     100    0    0    0    096 24 mos. in an industrial environment and treated with 1 volume % H.sub.2 O.sub.4 for 30 sec at ambient temperatures ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples.

Sample 8a failed the solderability test whereas all the sulfuric acid-treated samples passed.

Samples 8c and 8d demonstrate the effect of acid concentration on surface characteristics. Sample 8c was treated in 100 volume percent sulfuric acid for 30 seconds and was found to pass the solderability criterion. Sample 8d was treated in 1 volume percent sulfuric acid for 30 minutes and also demonstrated acceptable solder coverage.

Another set of palladium-nickel electroplated wires prepared in the same manner as the samples of Example 8 were subjected to the treatments outlined in Table IX: ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment  (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 9a    Aged for   27     40   0    33   80 24 mos. in an industrial environment 9b    Aged for   92      0   0    08   85 24 mos. in an industrial environment and treated with 50% H.sub.3 PO.sub.4 for 30 sec. at ambient temperature ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples. Both samples failed the solderability test.

Another set of palladium-nickel electroplated wires prepared in the same manner as the samples of Example 8 were subjected to the treatments outlined in Table X: ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment  (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 10a   Aged for   27     40   0    33   80 24 mos. in an industrial environment 10b   Aged for   88      0   0    12   75 24 mos. in an industrial environment and treated with 50% glacial acetic acid for 30 sec. at ambient temperature ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples. Both samples failed the solderability test.

Another set of palladium-nickel electroplated wires prepared in the same manner as the samples of Example 8 were subjected to the treatments outlined in Table XI: ______________________________________ 20 .ANG. Surface Layer Composition Sample Treatment  (Atomic %)      Solderability Code  History    Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 11a   Aged for   27     40   0    33   80 24 mos. in an industrial environment 11b   Aged for   90      0   0    10   90 24 mos. in an industrial environment and treated with 20% HNO.sub.3 for 30 sec at ambient temperature ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples. Both samples failed the solderability test.

Another set of palladium-nickel electroplated wires prepared in the same manner as the sample of Example 8 were subjected to the treatments outlined in Table XII: ______________________________________ 20 .ANG. Surface Layer Sam-              Composition     Solderability ple  Treatment    (Atomic %)      (% Code History      Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ Coverage) ______________________________________ 12a  Aged         27     40   0    33   80 in an industrial environment for 24 mos. 12b  Aged         52     26   0    22   85 in an industrial environment for 24 mos., treated in RMA flux per MIL-STD-202, Method 208, and rinsed in denatured ethanol 12c  Same as      38     26   0    36   50 12b except steam aged after ethanol rinse ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaluated on a set of replicate samples. All three samples failed the solderability test.

Another set of palladium-nickel electroplated wires prepared in the same manner as the samples of Example 8 were subjected to the treatments outlined in Table XIII: ______________________________________ 20 .ANG. Surface Layer Sam-             Composition ple  Treatment   (Atomic %)      Solderability Code History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (% Coverage) ______________________________________ 13a  Aged        27     40   0    33   80 in an industrial environment for 24 mos. 13b  Aged        6      54   0    40   75 in an industrial environment for 24 mos., treated in a strongly activated flux per MIL-STD 202, Method 208, and rinsed in denatured ethanol 13c  Same as     0      60   0    40   45 13b except steam aged after ethanol rinse ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG. and the solderability was evaulated on a set of replicate samples. All samples failed the solderability test.

A palladium-nickel alloy coating 0.9 .mu.m thick was electrodeposited on nickel-plated copper alloy disk using the bath chemistry and plating conditions set forth below: Bath Chemistry Pd Concentration: 17 g/l as palladium (II) ammine chloride Ni Concentration: 11 g/l as nickel ammine sulfate Sodium Vinyl Sulfonate: 2.8 g/l Ammonium Sulfate: 50 g/l Plating Conditions Temperature:    48.degree. C. pH              8.0 Current Density: 8.70 amp/sq dm Solution Agitation: Vigorous ______________________________________

The plated samples were than subjected to the treatments outlined in Table XIV: ______________________________________ 20 .ANG. Surface Layer m.OMEGA. Composition     Contact Sample Treatment   (Atomic %)      Resistance Code  History     Pd.sup.o Pd.sup.2+ Ni.sup.o Ni.sup.2+ (10 g load) ______________________________________ 14a   Office      88     0    0    12   4.70 aged for 4 mos. in an industrial environment 14b   Office      56     0    0    44   9.44 aged for 4 mos. in an industrial environment plus steam aging per MIL-STD 202, Method 208 14c   Office      99     0    1     0   1.69 aged for 4 mos. in an industrial environment plus sulfuric acid treatment 14d   Office      99     0    1     0   1.96 aged for 4 mos. in an industrial environment plus sulfuric acid treatment plus steam aging per MIL-STD 202, Method 208 ______________________________________

After the treatments, XPS chemistry profiles were obtained of sample surfaces to a depth of 120 .ANG.. The contact resistance was evaluated on a set of replicate samples per Military Standard 1344, Method 3002 with the following details: Normal Load:       10 grams force Test Current:      10 mA DC Open Circuit Voltage: 20 mV DC maximum ______________________________________

The sulfuric acid-treated samples 14c and 14d have a low point contact resistance similar to that of a gold electroplated contact surface.

## Claims

secured by Letters Patent is:

1. A permanently solderable article comprising a palladium-nickel electroplated coating on an electrically conductive substrate said coating having atomic percent nickel adhered to the substrate and a second continuous layer covering said first layer of 96 to 100 atomic percent metallic palladium and 0-4 atomic percent nickel, the second layer having a thickness up to twenty angstroms.

2. The article according to claim 1 wherein the second layer has an electrical contact resistance at low loads of less than two m.OMEGA. at 10 grams normal force.

3. The article according to claim 1 wherein the substrate is wire.

4. The article according to claim 1 wherein the substrate is phosphor bronze alloy.

5. The article according to claim 1 wherein the substrate is nickel plated copper base alloy.

6. The article according to claim 1 wherein the first alloy layer is 0.1 to 1.5 micrometers thick.

7. A process for obtaining a permanently solderable palladium-nickel coating on an electrically conductive substrate comprising immersing the substrate in an electroplating bath consisting of (1) palladium II ammine chloride, (2) nickel ammine sulfate or nickel chloride, (3) a brightener selected from the group consisting of sodium vinyl sulfonate, sodium allyl sulfonate and quaternized pyridine and (4) ammonium sulfate or chloride, at a temperature between 35.degree.-55.degree. C., a pH of 7.5 to 9, a current density of 5 to 25 amp/sq dm, with vigorous agitation to form a plated surface, and thereafter immersing the plated surface in a static aqueous solution of sulfuric or hydrochloric acid.