# Patent

## Title
High thermal budget magnetic memory

## Abstract

Semiconductor devices and methods for forming a semiconductor device are disclosed. The method includes forming a storage unit of a magnetic memory cell. A bottom electrode and a fixed layer are formed. The fixed layer includes a composite spacer layer disposed on the bottom electrode. The composite spacer layer includes a base layer and an amorphous buffer layer disposed over the base layer. A reference layer is disposed on the composite spacer layer. The amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation. At least one tunneling barrier layer is formed over the fixed layer. A storage layer is formed over the tunneling barrier layer and a top electrode is formed over the storage layer.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims the priority benefits of U.S. Provisional Application Ser. No. 62/133,491, filed on Mar. 16, 2015, and this application cross-references to U.S. patent application Ser. No. 15/057,107 and U.S. patent application Ser. No. 15/057,109, both filed on Feb. 29, 2016, and further cross-references to U.S. patent application Ser. No. 15/060,634 and U.S. patent application Ser. No. 15/060,647, both filed on Mar. 4, 2016, the disclosures of which are herein incorporated by reference in their entirety for all purposes.


BACKGROUND
A magnetic memory cell or device stores information by changing electrical resistance of a magnetic tunnel junction (MTJ) element. The MTJ element typically includes a thin insulating tunnel barrier layer sandwiched between a magnetically fixed layer and a magnetically free layer, forming a magnetic tunnel junction. The magnetization of the free layer can switch between first and second magnetization directions while the magnetization direction of the fixed layer is fixed in the first magnetization direction.
A fixed layer typically includes a hard layer and a reference layer separated by a spacer layer. The hard layer is used to pin the magnetization direction of the reference layer. It is important that the MTJ element has high tunnel magnetoresistance (TMR) and can sustain high processing temperatures, such as those employed in back-end-of-line (BEOL) complementary metal oxide semiconductor (CMOS) processing. However, conventional MTJ element tends to have TMR degradation when exposed to high temperatures.
In view of the foregoing, it is desirable to provide a MTJ element with improved TMR and enhanced thermal endurance and thermal budget. Furthermore, it is also desirable to provide a process for forming such MTJ elements which is cost effective and compatible with CMOS processing.
SUMMARY
Embodiments of the present disclosure generally relate to semiconductor devices and methods for forming a semiconductor device. In one embodiment, a method of forming a memory cell is disclosed. The method includes forming a select unit on a substrate. The select unit includes a transistor having a first source/drain (S/D) region, a second S/D region, and a gate between the first and second S/D regions. A dielectric layer is formed on the substrate covering the select unit. The dielectric layer includes storage pad coupled to the first S/D region. A storage unit is formed on the storage pad. Forming the storage unit includes forming a bottom electrode and forming a fixed layer on the bottom electrode. The fixed layer includes a composite spacer layer disposed on the bottom electrode and a reference layer disposed on the composite spacer layer. The composite spacer layer includes a base layer and an amorphous buffer layer disposed over the base layer. The amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation. At least one tunneling barrier layer is formed over the fixed layer. A storage layer is formed over the tunneling barrier layer. A top electrode is formed over the storage layer, and a bitline coupled to the top electrode layer is formed.
In another embodiment, a method of forming a storage unit of a magnetic memory cell is presented. The method includes forming a bottom electrode and forming a fixed layer on the bottom electrode. The fixed layer includes a composite spacer layer disposed on the bottom electrode and a reference layer disposed on the composite spacer layer. The composite spacer layer includes a base layer and an amorphous buffer layer disposed over the base layer. The amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation. At least one tunneling barrier layer is formed over the fixed layer. A storage layer is formed over the tunneling barrier layer and a top electrode is formed over the storage layer.
In yet another embodiment, a storage unit of a magnetic memory cell is disclosed. The storage unit includes a bottom electrode and a fixed layer disposed on the bottom electrode. The fixed layer includes a composite spacer layer disposed on the bottom electrode and a reference layer disposed on the composite spacer layer. The composite spacer layer includes a base layer and an amorphous buffer layer disposed over the base layer. The amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation. At least one tunneling barrier layer is disposed over the fixed layer. A storage layer is disposed over the tunneling barrier layer and a top electrode is disposed over the storage layer.
These and other advantages and features of the embodiments herein disclosed, will become apparent through reference to the following description and the accompanying drawings. Furthermore, it is to be understood that the features of the various embodiments described herein are not mutually exclusive and can exist in various combinations and permutations.



BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings, which are incorporated in and form part of the specification in which like numerals designate like parts, illustrate preferred embodiments of the present disclosure and, together with the description, serve to explain the principles of various embodiments of the present disclosure.
FIG. 1 shows simplified diagrams of parallel state and anti-parallel state of a bottom pinned perpendicular MTJ element of a magnetic memory cell.
FIG. 2 shows a schematic diagram of an embodiment of a magnetic memory cell.
FIG. 3 shows an array of magnetic memory cells.
FIG. 4 shows a cross-sectional view of an embodiment of a memory cell.
FIGS. 5a-5b show cross-sectional views of embodiments of a storage unit of a magnetic memory cell.
FIG. 6a-6l show cross-sectional views of an embodiment of a process for forming a memory cell.



DETAILED DESCRIPTION
Embodiments of the present disclosure generally relate to memory cells or devices. In one embodiment, the memory cells are magnetoresistive memory cells. For example, the memory devices may be spin transfer torque magnetoresistive random access memory (STT-MRAM) devices. A magnetoresistive memory cell includes a magnetic tunneling junction (MTJ) storage unit. Such memory devices, for example, may be incorporated into standalone memory devices including, but not limited to, Universal Serial Bus (USB) or other types of portable storage units, or integrated circuits (ICs), such as microcontrollers or system on chips (SoCs). The devices or ICs may be incorporated into or used with, for example, consumer electronic products, or relate to other types of devices.
FIG. 1 shows a simplified cross-sectional view of an embodiment of a MTJ storage unit 110 of a magnetic or memory cell. The MTJ unit includes a MTJ element or stack 120 disposed between a bottom electrode 131 and a top electrode 132. The bottom electrode is proximate to the substrate on which the memory cell is formed while the top electrode is distal from the substrate.
The MTJ element includes a magnetically fixed layer 126, a tunneling barrier layer 127 and a magnetically free layer 128. As shown, the magnetic orientation of the magnetic layers is in a perpendicular direction. The perpendicular direction, for example, refers to the direction which is perpendicular to the surface of a substrate or perpendicular to the plane of the layers of the MTJ element. In one embodiment, the magnetically fixed layer is disposed below the magnetic free layer, forming a bottom pinned perpendicular MTJ (pMTJ) element. The perpendicular direction of the fixed layer is in a first perpendicular direction. The first perpendicular direction is shown to be in an upward direction away from the substrate. Providing the first perpendicular direction which is in a downward direction towards the substrate may also be useful. As for the magnetic orientation of the free layer, it may be programmed to be in a first or same direction as the fixed layer or in a second or opposite direction as the fixed layer.
For example, as shown by structure 111, the magnetic direction of the free layer is programmed to be in the second or anti-parallel direction to the fixed layer. The corresponding MTJ electrical resistance between the free layer 128 and the fixed layer 126 is denoted as RAP. Structure 112 illustrates that the magnetization of the free layer is programmed to be in the first or parallel direction to the fixed layer. The corresponding MTJ electrical resistance between the free layer 128 and the fixed layer 126 is denoted as RP. The resistance RAP is higher than the resistance RP.
As described, the magnetization directions of the magnetic layers of the MTJ elements are in the perpendicular direction which form a pMTJ element. Providing the MTJ element with horizontal or in-plane magnetization direction may also be useful to form an in-plane MTJ (iMTJ) element. For example, the magnetization direction may be in a horizontal or parallel direction to the surface of the substrate or magnetic layers. Furthermore, the MTJ element may be a top pinned MTJ element in which the free layer is disposed below the fixed layer. Other configurations of MTJ elements may also be useful.
FIG. 2 shows a schematic diagram of an embodiment of a memory cell 200. The memory cell is a non-volatile memory cell. For example, the memory cell may be a magnetoresistive memory cell. In one embodiment, the memory cell is a Spin Transfer Torque-Magnetoresistive Random Access Memory (STT-MRAM) cell. Other suitable types of memory cells may also be useful. The memory cell includes a magnetic storage unit 210 and a cell selector unit 240. The storage unit is coupled to the cell selector unit. For example, the storage unit and cell selector unit are coupled at a first cell node 239 of the memory cell. The storage unit 210, in one embodiment, is a magnetic storage unit and includes a pMTJ element 220. The pMTJ element may be similar to that described in FIG. 1. Other suitable types of MTJ elements may also be useful.
The pMTJ element includes first and second electrodes 231 and 232. The first electrode, for example, may be a bottom electrode while the second electrode may be a top electrode. Other configurations of electrodes may also be useful. In one embodiment, the top electrode of the storage unit is electrically connected to a bit line (BL). The bottom electrode of the storage element is connected to the first cell node 239.
The cell selector unit includes a selector for selecting the memory cell. The selector, for example, may be a select transistor. In one embodiment, the select transistor is a metal oxide semiconductor (MOS) transistor. In one embodiment the selector is a n-type MOS transistor. The select transistor includes first and second source/drain (S/D) terminals 245 and 246 and a gate or control terminal 244. The first S/D terminal may be referred to as a drain and the second S/D terminal may be referred to as the source. The S/D terminals, for example, are heavily doped regions with first polarity type dopants, defining the first type transistor. For example, in the case of a n-type transistor, the S/D terminals are n-type heavily doped regions. Other types of transistors or selectors may also be useful.
In one embodiment, the first terminal of the cell selector and first electrode of the storage unit are commonly coupled at the first cell node. For example, the first S/D terminal of the cell selector is coupled to the bottom electrode of the storage unit. For example, the drain terminal is coupled to the storage unit. The second or source terminal of the cell selector is coupled to a source line (SL). As for the gate terminal, it is coupled to a wordline WL.
FIG. 3 shows a schematic diagram of an embodiment of a memory array 300. The array includes a plurality of memory cells 200 interconnected. The memory cells may be similar to those described in FIG. 2. For example, the memory cells are MRAM cells, such as STT-MRAM cells. Common elements may not be described or described in detail. Other suitable types of memory cells may also be useful.
As shown, the array includes four memory cells arranged in a 2×2 array. For example, the array is arranged to form two rows and two columns of memory cells. Memory cells of a row are interconnected by a wordline (WL1 or WL2) while memory cells of a column are interconnected by a bitline (BL1 or BL2). A second S/D or source terminal is coupled to a source line (SL1 or SL2). As shown, the SLs are in the row or wordline direction. Other suitable cell configurations may also be useful. Although the array is illustrated as a 2×2 array, it is understood that arrays of other sizes may also be useful.
FIG. 4 shows a cross-sectional view of an exemplary embodiment of a device. The cross-sectional view, for example is along a second or bitline direction of the device. The device, as shown, includes a memory cell 400. The memory cell, for example, may be a NVM memory cell. The memory cell, in one embodiment, is a magnetoresistive non-volatile memory (NVM) cell, such as a STT-MRAM cell. The memory cell, for example, is similar to that described in FIG. 2. Common elements may not be described or described in detail.
The memory cell is disposed on a substrate 405. For example, the memory cell is disposed in a cell region of the substrate. The cell region may be part of an array region. For example, the array region may include a plurality of cell regions. The substrate may include other types of device regions (not shown), such as high voltage (HV) as well as logic regions, including low voltage (LV) and intermediate voltage (IV) device regions. Other types of regions may also be provided.
The substrate, for example, is a semiconductor substrate, such as a silicon substrate. For example, the substrate may be a lightly doped p-type substrate. Providing an intrinsic or other types of doped substrates, such as silicon-germanium (SiGe), germanium (Ge), gallium-arsenic (GaAs) or any other suitable semiconductor materials, may also be useful. In some embodiments, the substrate may be a crystalline-on-insulator (COI) substrate. A COI substrate includes a surface crystalline layer separated from a crystalline bulk by an insulator layer. The insulator layer, for example, may be formed of a dielectric insulating material. The insulator layer, for example, is formed from silicon oxide, which provides a buried oxide (BOX) layer. Other types of dielectric insulating materials may also be useful. The COI substrate, for example, is a silicon-on-insulator (SOI) substrate. For example, the surface and bulk crystalline layers are single crystalline silicon. Other types of COI substrates may also be useful. It is understood that the surface and bulk layers need not be formed of the same material.
Front-end-of-line (FEOL) processing is performed on the substrate. The FEOL process, for example, forms n-type and p-type devices or transistors on the substrate. The p-type and n-type device form a complementary MOS (CMOS) device. The FEOL processing, for example, includes forming isolation regions, various device and isolation wells, transistor gates and transistor source/drain (S/D) regions and contact or diffusion regions serving as substrate or well taps. Forming other components with the FEOL process may also be useful.
Isolation regions 480, for example, serve to isolate different device regions. The isolation regions may be shallow trench isolation (STI) region. To form STI regions, trenches are formed and filled with isolation material. A planarization process, such as chemical mechanical polishing (CMP) is performed to remove excess dielectric material, forming isolation regions. Other types of isolation regions may also be useful. The isolation regions are provided to isolate device regions from other regions.
Device wells (not shown), for example, serve as bodies of p-type and n-type transistors. Device wells are doped wells. Second type doped device wells serve as bodies of first type transistors. For example, p-type device wells serve as bodies of n-type transistors and n-type device wells serve as bodies of p-type transistors. Isolation wells may be used to isolate device wells from the substrate. The isolation wells are deeper than the device wells. For example, isolation wells encompass the device wells. The isolation wells are first type doped wells. For example, n-type isolation wells are used to isolate p-type device wells. Separate implants may be employed to form different doped device wells and isolation wells using, for example, implant masks, such as photoresist masks. The wells, for example, are formed after forming isolation regions.
Gates of transistors are formed on the substrate. For example, layers of the gate, such as gate dielectric and gate electrode are formed on the substrate and patterned to form the gates. The gate dielectric may be a silicon oxide layer while the gate electrode layer may be polysilicon. The gate electrode may be doped, for example, to reduce sheet resistance. Other types of gate dielectric and gate electrode layers may also be useful. The gate dielectric layer may be formed by thermal oxidation and the gate electrode layer may be formed by chemical vapor deposition (CVD). Separate processes may be performed for forming gate dielectrics of the different voltage transistors. This is due to, for example, different gate dielectric thicknesses associated with the different voltage transistors. For example, HV transistor will have a thicker gate dielectric than a LV transistor.
The gate layers are patterned by, for example, mask and etch techniques. For example, a patterned photoresist mask may be provided over the gate layers. For example, a photoresist layer is formed over the gate layers and lithographically exposed by using a reticle. The mask layer is developed, forming a patterned mask with the desired pattern of the reticle. To improve lithographic resolution, an anti-reflective coating (ARC) layer may be provided between the gate layer and resist mask layer. An anisotropic etch, such as a reactive ion etch (RIE) is used to pattern the gate layers to form the gates using the patterned mask layer.
Doped contact regions 445 and 446, such as source/drain (S/D) regions and well or substrate taps are formed in exposed active regions of the substrate after forming the gates. The contact regions are heavily doped regions. Depending on the type of transistor and well tap, the contact regions may be heavily doped n-type or p-type regions. For n-type transistors, the S/D regions are heavily doped n-type regions and for p-type transistors, the S/D regions are heavily doped p-type regions. For well taps, they are the same dopant type as the well.
A S/D region may include lightly doped diffusion (LDD) and halo regions (not shown). A LDD region is a lightly doped region with first polarity type dopants while the halo region is a lightly doped region with second polarity type dopants. For example, the halo region includes p-type dopants for a n-type transistor while the LDD region includes n-type dopants for n-type transistors. The halo and LDD regions extend under the gate. A halo region extends farther below the gate than a LDD region. Other configurations of LDD, halo and S/D regions may also be useful.
Dielectric spacers (not shown) may be provided on the gate sidewalls of the transistors. The spacers may be used to facilitate forming transistor halo, LDD and transistor S/D regions. For example, spacers are formed after halo and LDD regions are formed. Spacers may be formed by, for example, forming a spacer layer on the substrate and anisotropically etching it to remove horizontal portions, leaving the spacers on sidewalls of the gates. After forming the spacers, an implant is performed to form the S/D regions. Separate implants may be employed to form different doped regions using, for example, implant masks, such as photoresist mask. Well taps of the same dopant type as the S/D regions are formed at the same time.
As shown, the FEOL processing forms a cell region isolated by an isolation region 480, such as a STI region. The cell region is for a memory cell. Isolation regions may be provided to isolate columns of memory cells. Other configurations of isolation regions may also be useful. The cell region may include a cell device well (not shown). The cell device well, for example, serves as a body well for a transistor of the memory cell. The device well may be doped with second polarity type dopants for first polarity type transistors. The device well may be lightly or intermediately doped with second polarity type dopants. In some cases, a cell device isolation well (not shown) may be provided, encompassing the cell device well. The isolation well may have a dopant type which has the opposite polarity to that of the cell device well. For example, the isolation well may include first polarity type dopants. The isolation well serves to isolate the cell device well from the substrate. Well biases may be provided to bias the wells.
The cell device well may be a common well for the cell regions in the array region. For example, the cell device well may be an array well. The cell device isolation well may serve as the array isolation well. Other configurations of device and isolation wells may also be useful. Other device regions of the device may also include device and/or device isolation wells.
The memory cell includes a cell selector unit 440 and a storage unit 410. The FEOL processing forms the cell selector in the cell region. The cell selector unit includes a selector for selecting the memory cell. The selector, for example, may be a select transistor. In one embodiment, the select transistor is a metal oxide semiconductor (MOS) transistor. The transistor, as shown, includes first and second source/drain (S/D) regions 445 and 446 formed in the substrate and a gate 444 disposed on the substrate between the S/D regions. The first S/D region may be referred to as a drain region and the second S/D region may be referred to as a source region. The S/D regions, for example, are heavily doped regions with first polarity type dopants, defining the first type transistor. For example, in the case of a n-type transistor, the S/D regions are n-type heavily doped regions. Other types of transistors or selectors may also be useful.
As for the gate 444, it includes a gate electrode over a gate dielectric. The gate electrode may be polysilicon while the gate dielectric may be silicon oxide. Other types of gate electrode and gate dielectric materials may also be useful. A gate, for example, may be a gate conductor along a first or wordline direction. The gate conductor forms a common gate for a row of memory cells.
As discussed, a S/D region may include LDD and halo regions (not shown). Dielectric spacers (not shown) may be provided on the gate sidewalls of the transistors to facilitate forming transistor halo, LDD and transistor S/D regions. It is understood that not all transistors include LDD and/or halo regions.
After forming the cell selector unit and other transistors, back-end-of-line (BEOL) processing is performed. The BEOL process includes forming interconnects in interlevel dielectric (ILD) layers 490. The interconnects connect the various components of the IC to perform the desired functions. An ILD layer includes a metal level 494 and a contact level 492. Generally, the metal level includes conductors or metal lines 495 while the contact level includes contacts 493. The conductors and contacts may be formed of a metal, such as copper, copper alloy, aluminum, tungsten or a combination thereof. Other suitable types of metals, alloys or conductive materials may also be useful. In some cases, the conductors and contacts may be formed of the same material. For example, in upper metal levels, the conductors and contacts may be formed by dual damascene processes. This results in the conductors and contacts having the same material. In some cases, the conductors and contacts may have different materials. For example, in the case where the contacts and conductors are formed by single damascene processes, the materials of the conductors and contacts may be different. Other techniques, such as reactive ion etch (RIE) may also be employed to form metal lines.
A device may include a plurality of ILD layers or levels. For example, x number of ILD levels may be provided. As illustrated, the device includes 5 ILD levels (x=5). Other number of ILD levels may also be useful. The number of ILD levels may depend on, for example, design requirements or the logic process involved. A metal level of an ILD level may be referred to as Mi, where i is from 1 to x and is the ith ILD level of x ILD levels. A contact level of an ILD level may be referred to as Vi-1, where i is the ith ILD level of x ILD levels.
The BEOL process, for example, commences by forming a dielectric layer over the transistors and other components formed in the FEOL process. The dielectric layer may be silicon oxide. For example, the dielectric layer may be silicon oxide formed by chemical vapor deposition (CVD). The dielectric layer serves as a premetal dielectric layer or first contact layer of the BEOL process. The dielectric layer may be referred to as CA level of the BEOL process. Contacts are formed in the CA level dielectric layer. The contacts may be formed by a single damascene process. Via openings are formed in the dielectric layer using mask and etch techniques. For example, a patterned resist mask with openings corresponding to the vias is formed over the dielectric layer. An anisotropic etch, such as RIE, is performed to form the vias, exposing contact regions below, such as S/D regions and gates. A conductive layer, such as tungsten is deposited on the substrate, filling the openings. The conductive layer may be formed by sputtering. Other techniques may also be useful. A planarization process, such as chemical mechanical polishing (CMP), is performed to remove excess conductive material, leaving contact plugs in the CA level.
After forming contacts in the CA level, the BEOL process continues to form dielectric layer over the substrate, covering the CA level dielectric layer. The dielectric layer, for example, serves as a first metal level M1 of the first ILD layer. The upper dielectric layer, for example, is a silicon oxide layer. Other types of dielectric layers may also be useful. The dielectric layer may be formed by CVD. Other techniques for forming the dielectric layer may also be useful.
Conductive lines are formed in the M1 level dielectric layer. The conductive lines may be formed by a damascene technique. For example, the dielectric layer may be etched to form trenches or openings using, for example, mask and etch techniques. A conductive layer is formed on the substrate, filling the openings. For example, a copper or copper alloy layer may be formed to fill the openings. The conductive material may be formed by, for example, plating, such as electro or electroless plating. Other types of conductive layers or forming techniques may also be useful. Excess conductive materials are removed by, for example, CMP, leaving planar surface with the conductive line and M1 dielectric. The first metal level M1 and CA may be referred as a lower ILD level.
The process continues to form additional ILD layers. For example, the process continues to form upper ILD layers or levels. The upper ILD levels may include ILD level 2 to ILD level x. For example, in the case where x=5 (5 levels), the upper levels include ILD levels from 2 to 5, which include via levels V1 to V4 and metal levels M2 to M5. The number of ILD layers may depend on, for example, design requirements or the logic process involved. The upper ILD layers may be formed of silicon oxide. Other types of dielectric materials, such as low k, high k or a combination of dielectric materials may also be useful. The ILD layers may be formed by, for example, CVD. Other techniques for forming the ILD layers may also be useful.
The conductors and contacts of the upper ILD layers may be formed by dual damascene techniques. For example, vias and trenches are formed, creating dual damascene structures. The dual damascene structure may be formed by, for example, via first or via last dual damascene techniques. Mask and etch techniques may be employed to form the dual damascene structures. The dual damascene structures are filled with a conductive layer, such as copper or copper alloy. The conductive layer may be formed by, for example, plating techniques. Excess conductive material is removed by, for example, CMP, forming conductors and contacts in an upper ILD layer.
A dielectric liner (not shown) may be disposed between ILD levels and on the substrate. The dielectric liner, for example, serves as an etch stop layer. The dielectric liner may be formed of a low k dielectric material. For example, the dielectric liner may be nBLOK. Other types of dielectric materials for the dielectric liner may also be useful.
The uppermost ILD level (e.g., M5) may have different design rules, such as critical dimension (CD), than the lower ILD levels. For example, Mx may have a larger CD than metal levels M1 to Mx−1 below. For example, the uppermost metal level may have a CD which is 2× or 6× the CD of the metal levels below. Other configurations of the ILD levels may also be useful.
As shown, S/D contacts are disposed in the CA level. The S/D contacts are coupled to the first and second S/D regions of the select transistor. Other S/D contacts to other S/D regions of transistors may also be provided. The CA level may include a gate contact (not shown) coupled to the gate of the select transistor. The gate contact may be disposed in another cross-section of the device. The contacts may be tungsten contacts while contact pads may be copper. Other types of contacts and contact pad may also be useful. Other S/D and gate contacts for other transistors may also be provided.
As described, metal lines are provided in M1. The metal lines are coupled to the S/D contacts. In one embodiment, a SL is coupled to the second S/D region of the select transistor. As for the first S/D region, it may be coupled to a contact pad or island in M1. The contact pads provide connections to upper ILD levels. The metal lines or contact pads may be formed of copper or copper alloy. Other types of conductive material may also be useful.
As for the upper ILD levels, for example, from 2 to 5, they include contacts in the via level and contact pads/metal lines in the metal level. The contacts and contact pads provide connection from M5 to the first S/D region of the select transistor.
A pad level (not shown) is disposed over the uppermost ILD level. For example, a pad dielectric level is disposed over Mx. In the case where the device includes 5 metal levels, the pad level is disposed over M5. The pad dielectric layer, for example, may be silicon oxide. Other types of dielectric materials may also be useful. The pad dielectric layer includes pads, such as bond pads or pad interconnects for providing external interconnections to the components. Bond pads may be used for wire bonding while pad interconnects may be provided for contact bumps. The external interconnections may be input/output (I/O), power and ground connections to the device. The pads, for example, may be aluminum pads. Other types of conductive pads may also be useful. A passivation layer, such as silicon oxide, silicon nitride or a combination thereof, may be provided over the pad level. The passivation layer includes openings to expose the pads.
A dielectric liner may be disposed between the uppermost metal level and pad level. The dielectric liner, for example, serves as an etch stop layer during via etch process and it may also serve as a diffusion barrier layer for, for example, copper (Cu) layer. The dielectric liner may be a low k dielectric liner. For example, the dielectric liner may be nBLOK. Other suitable types of dielectric materials for the dielectric liner may also be useful.
The storage unit 410 of the memory cell is disposed in a storage dielectric layer 450. The storage dielectric layer may be a via level of an ILD level. As shown, the storage dielectric layer is V1 of M2. Providing the storage dielectric layer at other via levels may also be useful. In other embodiments, the storage dielectric layer may be a dedicated storage dielectric layer and not part of an interconnect level. Other configurations of storage dielectric layer may also be useful. The storage unit 410 includes a storage element disposed between top and bottom electrodes, forming a pMTJ element. The storage element, in one embodiment, is a bottom pinned pMTJ storage element, such as that described in FIG. 1 and FIGS. 5a-5b as will be described later. Common elements may not be described or described in detail. In other embodiments, the MTJ element may be a top pinned or bottom pinned iMTJ element. Other configurations of MTJ elements may also be useful.
In one embodiment, the bottom electrode of the storage unit is coupled to a drain of the select transistor. For example, the bottom electrode is coupled to a contact pad in the M1 level and a via contact in the CA level. Other configurations of coupling the bottom electrode may also be useful. The top electrode is coupled to a BL. For example, the top electrode is coupled to the BL disposed in M2. The BL is along a bitline direction. As for the source of the select transistor, it is coupled to the SL. The SL, for example, may be in the first or wordline direction. Providing a SL in the second or bitline direction may also be useful. For example, a via contact in CA is provided to couple the source region to SL in M1. Providing SL in other levels may also be useful.
As for the gate of cell selector, it is coupled to a WL. The WL, for example, is along a wordline direction. The bitline and wordline directions are perpendicular to each other. As shown, the WL is disposed in M3. The WL may be coupled to the gate by contact pads in M2 and M1 and via contacts in V2 and V1 (not shown). Other configurations of coupling the WL to the gate may also be useful. For example, the WL may be disposed in other metal levels.
In general, lines which are parallel in a first direction may be formed in the same metal level while lines which are in a second direction perpendicular to the first may be formed in a different metal level. For example, WLs and BLs are formed in different metal levels.
As described, the storage dielectric layer 450 is disposed in V1 in between M1 and M2. It is understood that providing other configurations of storage dielectric layers may be also useful.
FIG. 5a shows a cross-sectional view of an embodiment of a magnetic storage unit 510a of a magnetic cell. In one embodiment, the storage unit includes a bottom pinned MTJ stack or element 520 disposed between bottom and top electrodes 531 and 532. In one embodiment, the MTJ element is a pMTJ element. The pMTJ stack or element includes a fixed layer 526, a free layer 528, and a tunneling barrier layer 527 separating the fixed layer from the free layer. The fixed layer, tunneling barrier layer and the free layer form the MTJ element 520. A capping layer 580 is disposed over the free layer. As shown, the fixed layer is disposed below the free layer, forming the bottom pinned MTJ element.
The top and bottom electrode layers may be formed of a conductive material. In one embodiment, the top and bottom electrode may be formed of Ta. Other suitable types of electrodes may also be useful. For example, Ti, TaN, TiN or a combination of different electrode materials, including Ta, may also be useful. Furthermore, it is understood that the top and bottom electrodes need not be of the same material. A thickness of the electrode layers may be about 1 to 100 nm. The electrodes may be formed by physical vapor deposition (PVD). Other deposition techniques may also be useful.
The various layers of the MTJ element will be described. For example, the various layers will be described from the bottom electrode up to the top electrode for a bottom pinned MTJ element.
In one embodiment, the fixed layer is disposed on the bottom electrode. The fixed layer is a fixed layer stack which includes a base layer 560, a synthetic antiferromagnetic (SAF) layer 570 and a reference layer 568. In one embodiment, a spacer layer 578 is provided between the SAF layer and the reference layer.
The base layer, for example, serves as a seed layer. The seed layer serves as a base for the SAF layer. For example, the seed layer provides a proper template for magnetic layer to form proper crystalline phase after annealing. In one embodiment, the seed layer may be Ta or Pt or any combination of metal multilayers. Other suitable types of seed layers may also be useful. In one embodiment, the base layer may be a composite seed layer having multiple layers. For example, the base layer may include a wetting layer and a seed layer over it. The seed layer includes multiple layers, such as a bilayer. The seed layer may include multiple bilayers. The base layer may be a base layer as described in, for example, U.S. patent application Ser. No. 15/057,107 and U.S. patent application Ser. No. 15/057,109, both filed on Feb. 29, 2016, which are herein incorporated by references for all purposes. The base layer may be formed by PVD.
The SAF layer 570 is formed over the base layer 560. The SAF layer, in one embodiment, is a composite SAF layer with multiple layers to form a SAF layer stack. In one embodiment, the SAF layer includes first and second hard layers 572 and 576 separated by a coupling layer 574. The first and second hard layers are antiparallel (AP) layers. The first AP layer may be referred to as AP1 and the second AP layer may be referred to as AP2. AP1 and AP2 have opposite perpendicular magnetization directions. For example, AP1 may have an upward perpendicular magnetization direction while AP2 may have a downward perpendicular magnetization direction. Other configurations of opposite magnetization directions for AP1 and AP2 may also be useful.
An AP layer may be a bilayer. In one embodiment, the AP layer may be multilayers of cobalt/platinum (Co/Pt), cobalt/nickel (Co/Ni) or cobalt/palladium (Co/Pd). Other types of AP layers may also be useful. The bilayers of AP1 and AP2 may be the same type of bilayers. Providing different bilayers for AP1 and AP2 may also be useful.
As for the coupling layer, it serves to promote Ruderman-Kittle-Kasuya-Yosida (RKKY) coupling. The coupling layer, in one embodiment, is a ruthenium (Ru) layer. Providing other types of coupling layers may also be useful. The various layers of the SAF layer may be formed by PVD.
As discussed, a spacer layer 578 is provided between the second AP layer 576 and reference layer 568. The spacer layer, for example, serves as a texture breaking layer. The spacer layer facilitates a different texture for the reference layer. For example, the spacer layer enables the reference layer to have a different texture from that of the SAF or hard layer. For example, the spacer layer enables the reference layer to be amorphous or crystalline when deposited. In one embodiment, the spacer layer facilitates the reference layer to achieve a body-centered cubic (BCC) structure along the (001) orientation. In addition, the spacer layer serves as a diffusion barrier between the reference and SAF layers. For example, the spacer layer serves as a diffusion barrier for B atoms from the reference layer.
The spacer layer is a composite spacer layer having multiple layers. In one embodiment, the spacer layer is a Mo-based composite spacer layer. For example, the spacer layer is a Mo/X composite layer. The Mo serves as a base layer of the composite Mo/X spacer layer. For example, the Mo is disposed on the surface of the SAF layer, such as AP2. The Mo base is crystalline and serves as a diffusion barrier.
As for X, it includes a buffer layer. In one embodiment, the buffer layer is a metal layer M. For example, X=M, resulting in a spacer layer Mo/M. The buffer layer M should be sufficiently thin to produce a BCC structure of the reference layer along the (001) orientation. The buffer layer also couples the reference layer ferromagnetically with the SAF layer, such as AP2. Providing the reference layer having a BCC structure along the (001) orientation results in a high TMR. For example, the buffer layer M serves as a template for the reference layer to have high TMR. The buffer layer may include Ta, V, FeV, TaN or MoN. Other types of metals M, which promotes BCC structure of the reference layer along the (001) orientation may also be useful. For example, the composite spacer layer Mo/M may be Mo/Ta, Mo/V, Mo/TaN, Mo/FeV or Mo/MoN.
In another embodiment, X includes multiple layers. For example, X is a bilayer which includes a coupler layer C and a buffer layer M (X=C/M). For example, the spacer layer is a Mo/C/M composite spacer layer. In such case, Mo is the base layer, C is the intermediate layer and M is the top layer. The coupler layer C, in one embodiment, is a magnetic layer. The coupler layer is ferromagnetically weak which acts as a paramagnetic layer to promote strong magnetic coupling between the SAF and reference layers. For example, C promotes strong magnetic coupling between AP2 and the reference layer. The coupler layer, for example, may be Co, Fe or Ni. Other types magnetic coupler layer may also be useful. For example, the composite spacer layer Mo/C/M may be Mo/Co/Ta, Mo/Co/V, Mo/Co/TaN or Mo/Co/FeV.
The various layers of the spacer layer may be formed by PVD. The thickness of the Mo layer may be about 1-12 Å. As for the buffer layer M, it may be about 1-5 Å and is amorphous. In the case of FeV, it may be about 1-20 Å. As for the coupler layer C, it may be about 1-6 Å. Other suitable thicknesses may also be useful.
The reference layer 568, in one embodiment, is a magnetic layer. The reference layer, for example, is a cobalt-iron-boron (CoFeB) layer. Other suitable types of magnetic reference layers may also be useful. In one embodiment, the reference layer is deposited by, for example, PVD. The reference layer is deposited as an amorphous layer. Depositing the layer as an amorphous layer enhances TMR when it is subsequently recrystallized. For example, a post anneal is performed on the MTJ stack. The reference layer should be sufficiently thick without sacrificing the perpendicular magnetic anisotropy (PMA). The thickness of the reference layer, for example, may be about 5 to 13 Å thick. Forming the reference layer using other suitable techniques or processes as well as other suitable thicknesses may also be useful.
The tunneling barrier layer 527 which is disposed over the fixed layer may be a magnesium oxide (MgO) layer. Other suitable types of barrier layers may also be useful. The tunneling barrier layer may be formed by PVD. The thickness of the tunneling barrier layer may be about 8-20 Å. Preferably, the thickness of the tunneling barrier layer is about 1-12 Å. Other forming techniques or thicknesses for the tunneling barrier layer may also be useful.
The free or storage layer 528 is disposed over the tunneling barrier layer 527. The storage layer is a magnetic layer. In one embodiment, the storage layer may be a CoFeB layer. The storage layer may be a single layer or a composite layer. The thickness of the storage layer may be about 10-20 Å to maintain the PMA. In the case of a composite free layer, it may include a magnetic/non-magnetic/magnetic stack. The magnetic layer may be CoFeB while the non-magnetic layer may be Ta. Other types of magnetic or non-magnetic layers may also be useful. The thickness of the non-magnetic layer is thin to avoid magnetic decoupling of the magnetic layers of the composite storage layer. The storage layer may be formed by, for example, PVD. Other techniques for forming the storage layer or thicknesses may also be useful.
A capping layer 580 is provided over the storage layer. The capping layer, for example, serves to minimize the top electrode diffusion through the tunneling barrier or magnetic layers. The capping layer, for example, may be a Ru layer or a Ta layer. Providing a composite capping layer may also be useful. For example, the capping layer may include Ru and Ta layers. Other configurations of capping layers may also be useful. The capping layer may be formed by, for example, PVD.
As described, the spacer layer is a composite spacer layer which promotes a BCC structure of the reference layer in the (001) orientation. In addition, diffusion of B from the reference layer is reduced. Furthermore, the composite spacer layer increases coupling between the SAF and reference layers. This results in a MTJ element with high TMR and a high thermal budget.
FIG. 5b shows a cross-sectional view of another embodiment of a magnetic storage unit 510b of a magnetic memory cell. In one embodiment, the storage unit includes a bottom pinned MTJ stack or element 520 disposed between bottom and top electrodes 531 and 532. The MTJ element is similar to that described in FIG. 5a. Common elements may not be described or described in detail.
The MTJ element includes a fixed layer 526, a free layer 528, and a tunneling barrier layer separating the fixed layer from the free layer. The fixed layer is disposed below the free layer, forming the bottom pinned MTJ element. A capping layer 580 is disposed over the free layer. The fixed layer, tunneling barrier layer, and free layer form the MTJ element.
In contrast to the MTJ element of FIG. 5a, the MTJ element of FIG. 5b includes first and second tunneling barrier layers 527a and 527b. This configuration produces a dual tunneling barrier pMTJ element. In one embodiment, the free layer 528 is disposed in between the first and second tunneling barrier layers 527a and 527b. The tunneling barrier layers, for example, may be MgO tunneling barrier layers. Other suitable types of tunneling barrier layers may also be useful. It is also understood that the tunneling barrier layers need not be the same. As for the other layers of the MTJ element, they are the same or similar.
The second tunneling barrier enhances anisotropy of the storage layer, increasing thermal stability. Additionally, the second tunneling barrier reduces the damping effect of the storage layer, reducing switching current.
As described, the MTJ element is a bottom pinned pMTJ element. The MTJ element may also be a bottom pinned iMTJ element. In other embodiments, the MTJ element may be a top pinned MTJ element.
FIGS. 6a-6l show cross-sectional views of an embodiment of a process 600 for forming a device. The process includes forming a memory cell. The memory cell, for example, may be a magnetic random access memory (MRAM) cell. The memory cell, for example, is the same or similar to that described in FIG. 2 and includes an MTJ element as described in FIGS. 5a-5b. Common elements may not be described or described in detail.
The cross-sectional views, for example, are along the bit line direction. Although the cross-sectional views show one memory cell, it is understood that the device includes a plurality of memory cells of, for example, a memory array. In one embodiment, the process of forming the cell is highly compatible with CMOS logic process. For example, the cell can be formed simultaneously with CMOS logic devices (not shown) on the same substrate.
Referring to FIG. 6a, a substrate 605 is provided. The substrate, for example, is a semiconductor substrate, such as a silicon substrate. The substrate may be a lightly doped p-type substrate. Providing an intrinsic or other types of doped substrates, such as silicon germanium (SiGe), germanium (Ge), gallium arsenide (GaAs) or any other suitable semiconductor materials, may also be useful. In some embodiments, the substrate may be a crystalline-on-insulator (COI) substrate. A COI substrate includes a surface crystalline layer separated from a bulk crystalline by an insulator layer. The insulator layer, for example, may be formed of a dielectric insulating material. The insulator layer, for example, includes silicon oxide, which provides a buried oxide (BOX) layer. Other types of dielectric insulating materials may also be useful. The COI substrate, for example, is a silicon-on-insulator (SOI) substrate. For example, the surface and bulk crystalline layers are single crystalline silicon. Other types of COI substrates may also be useful. It is understood that the surface and bulk layers need not be formed of the same material.
The substrate is processed to define a cell region in which a memory cell is formed. The cell region may be part of an array region. For example, the array region may include a plurality of cell regions. The substrate may include other types of device regions, such as a logic region. Other types of regions may also be provided.
Isolation regions 680 are formed in the substrate. In one embodiment, the isolation regions are shallow trench isolation (STI) regions. Other types of isolation regions may also be useful. The isolation regions are provided to isolate device regions from other regions. The isolation regions may also isolate contact regions within a cell region. Isolation regions may be formed by, for example, etching trenches in the substrate and filling them with a dielectric material, such as silicon oxide. A planarization process, such as chemical mechanical polish (CMP), is performed to remove excess dielectric material, leaving, for example, STI regions isolating the device regions.
A doped well or device well 608 is formed. The well, for example, is formed after forming the isolation regions. In one embodiment, the well serves as a well for the select transistors of the selector unit. The well, for example, is a second polarity type doped well. The second polarity type is the opposite polarity type of the transistor of the cell selector unit. In one embodiment, the device well is a p-type well for a n-type cell select transistor, such as a metal oxide semiconductor field effect transistor (MOSFET). The device well serves as a body of the select transistor.
In one embodiment, an implant mask may be employed to implant the dopants to form the doped well. The implant mask, for example, is a patterned photoresist layer. The implant mask exposes regions of the substrate in which the second polarity wells are formed. The device well may be lightly or intermediately doped with second polarity type dopants. For example, the device well may have a dopant concentration of about 1E15 to 1E19/cm3. Other dopant concentrations may also be useful. The well, for example, may be a common device well for the array.
The process may include forming other wells for other device regions. In the case where the wells are different polarity types or dopant concentrations, they may be formed using separate processes, such as separate mask and implants. For example, first polarity typed doped wells, wells of different dopant concentrations as well as other wells may be formed using separate masks and implant processes.
As shown in FIG. 6b, gate layers are formed on the substrate. The gate layers, in one embodiment, include a gate dielectric layer 642 and a gate electrode layer 643 thereover. The gate dielectric layer, for example, may be a silicon oxide layer. The gate dielectric layer may be formed by thermal oxidation. As for the gate electrode layer, it may be a polysilicon layer. The gate electrode layer may be formed by chemical vapor deposition (CVD). Other suitable types of gate layers, including high k dielectric and metal gate electrode layers, or other suitable techniques for forming gate layers may also be useful.
Referring to FIG. 6c, the gate layers are patterned to form a gate 644 of the select transistor of the select unit. Patterning the gate layers may be achieved using mask and etch techniques. For example, a soft mask, such as a photoresist may be formed over the gate electrode layer. An exposure source may selectively expose the photoresist layer through a reticle containing the desired pattern. After selectively exposing the photoresist layer, it is developed to form openings corresponding to locations where the gate layers are to be removed. To improve lithographic resolution, an anti-reflective coating (ARC) may be used below the photoresist layer. The patterned mask layer is used to pattern the gate layers. For example, an anisotropic etch, such as reactive ion etch (RIE), is used to remove exposed portions of the gate layers. Other types of etch processes may also be useful. The etch transfers the pattern of the mask layer to the underlying gate layers. Patterning the gate layers forms the gate of the select transistor. The gate, for example, may be a gate conductor along a first or word line direction. A gate conductor forms a common gate for a row of memory cells. It is understood that gates of the memory cells of the array may be formed.
Referring to FIG. 6d, an implant is performed to first and second S/D regions 645 and 646 on sides of the gate. The implant, for example, implants first polarity type dopants to form first polarity type S/D regions. An implant mask (not shown) may be used to form the first polarity type S/D regions in the substrate. In one embodiment, the implant forms heavily doped first polarity type S/D regions in the substrate adjacent to the gates. The first polarity type dopants, for example, include n-type dopants. The implantation process to form the first polarity type S/D regions may be performed together while forming first polarity type S/D regions in other device regions (not shown) on the same substrate as well as first polarity type contact regions. The S/D regions, for example, include dopant concentration of about 5E19 to 1E21/cm3. Other dopant concentration may also be useful.
A lightly doped (LD) extension implant may be performed to form LD extension regions (not shown) of the S/D regions. The LD extension implant may be performed prior to forming the S/D regions. An implant mask may be used to form the LD extension regions. To form the LD extension regions, first polarity type dopants are implanted into the substrate. The first polarity type dopants, for example, include n-type dopants. In one embodiment, the implant forms LD extension regions in the substrate adjacent to the gates. For example, the LD extension regions extend slightly under the gates and are typically shallower than the S/D regions. The LD extension regions, for example, include dopant concentration of about 1E18 to 5E19/cm3. Other dopant concentrations may also be useful. In some embodiments, a halo region may also be formed. The halo region may be formed at the same time as the LD extension region. After forming the LD extension regions, sidewall spacers (not shown) may be formed on sidewalls of the gate followed by forming the S/D regions.
Separate implants for second polarity type S/D and extension regions may be performed. The second polarity type implants form S/D and extension regions for second polarity type transistors in other device regions as well as second polarity type contact regions.
Referring to FIG. 6e, a dielectric layer 6901 is formed on the substrate, covering the transistor. The dielectric layer, for example, serves as a dielectric layer of an ILD layer. For example, the dielectric layer serves as a PMD or CA level of an ILD layer. The dielectric layer, for example, is a silicon oxide layer. Other types of dielectric layers may also be useful. The dielectric layer may be formed by CVD. Other techniques for forming the dielectric layer may also be useful. A planarizing process may be performed to produce a planar surface. The planarizing process, for example, may include CMP. Other types of planarizing processes may also be useful.
In one embodiment, contacts 693 are formed in the dielectric layer 6901 as shown in FIG. 6f. The contacts, for example, connect to contact regions, such as S/D regions and gate (not shown). Forming the contacts may include forming contact vias in the dielectric layer to expose the contact regions. Forming the contact vias may be achieved using mask and etch techniques. After the vias are formed, a conductive material is deposited to fill the vias. The conductive material, for example, may be tungsten. Other types of conductive materials may also be useful. A planarization process, such as CMP, is performed to remove excess conductive material, leaving contact plugs in the contact vias.
In FIG. 6g, a dielectric layer 6902 is formed over the substrate, covering the lower dielectric layer 6901. The dielectric layer 6902, for example, serves as a metal level of an ILD layer. In one embodiment, the dielectric layer serves as M1 level of the ILD layer. The dielectric layer, for example, is a silicon oxide layer. Other types of dielectric layers may also be useful. The dielectric layer may be formed by CVD. Other techniques for forming the dielectric layer may also be useful. Since the underlying surface is already planar, a planarizing process may not be needed. However, it is understood that a planarization process, such as CMP, may be performed if desired to produce a planar surface.
In FIG. 6h, conductive or metal lines 695 are formed in the dielectric layer 6902. The conductive lines may be formed by damascene technique. For example, the upper dielectric layer may be etched to form trenches or openings using, for example, mask and etch techniques. A conductive layer is formed on the substrate, filling the openings. For example, a copper or copper alloy layer may be formed to fill the openings. The conductive material may be formed by, for example, plating, such as electro or electroless plating. Other types of conductive layers or forming techniques may also be useful. In one embodiment, a source line SL is formed to connect to the source region 646 of the transistor while other interconnects, such as interconnect pad 697 formed in M1 is coupled to the drain region 645. The SL, for example, may be along the wordline direction. Providing SL in the bitline direction may also be useful. As for the interconnect pad, it may serve as a storage pad. Other conductive lines and pads may also be formed.
As shown in FIG. 6i, the process continues to form a storage unit of the memory cell. In one embodiment, the process forms various layers of a storage unit with a pMTJ element. The various layers 612 are formed on the dielectric layer 6902. The layers may include layers as described in FIG. 5a or 5b. The layers may be formed by PVD or other suitable deposition techniques. The deposition technique may depend on the type of layer. The layers are patterned to form a storage unit 610 with a pMTJ element, as shown in FIG. 6j. Patterning the layers may be achieved using an anisotropic etch, such as RIE, with a patterned mask layer. Other suitable techniques for forming the MTJ element may also be useful.
Referring to FIG. 6k, a storage dielectric layer 6903 is formed over the MTJ storage unit. The dielectric layer covers the storage unit 610. The storage dielectric layer, for example, is a silicon oxide layer. The storage dielectric layer may be formed by, for example, CVD. Other types of storage dielectric layers or forming techniques may also be useful. A planarization process is performed to remove excess dielectric material to form a planar surface. The planarization process, for example, is CMP. As shown, the storage dielectric layer is disposed above the surface of the storage unit. For example, the storage dielectric layer includes V1 and M2 levels.
In FIG. 6l, a conductive or metal line is formed in the dielectric layer in M2. For example, a bitline BL is formed in M2 of the dielectric layer, coupling the storage unit. Other metal lines may also be formed. The metal lines in M2 may be formed using a dual damascene technique.
Additional processes may be performed to complete forming the device. For example, the processes may include forming additional ILD levels, pad level, passivation level, pad opening, dicing, assembly and testing. Other types of processes may also be performed.
As described, the storage unit is formed in V1 and BL is formed in M2. Forming the storage unit and BL in other ILD levels, such as in an upper ILD level, may also be useful. In the case where the storage unit is provided in an upper ILD level, contact and interconnect pads may be formed in the intermediate ILD levels to connect to the storage unit. The contact and interconnect pads may be formed using dual damascene techniques.
In addition, a metal wordline may be provided in a metal layer above the gate. The metal wordline, for example, may be coupled to the gate of the select transistor. The metal wordline may be provided in M1 or other metal levels. For example, the metal wordline may be parallel with the SL. Also, as described, the various components are disposed in specific via or metal levels. It is understood that other configurations of the memory cell may also be useful. For example, the components may be disposed in other metal or via levels.
The present disclosure may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The foregoing embodiments, therefore, are to be considered in all respects illustrative rather than limiting the invention described herein. Scope of the invention is thus indicated by the appended claims, rather than by the foregoing description, and all changes that come within the meaning and range of equivalency of the claims are intended to be embraced therein.

## Claims

1. A method of forming a memory cell comprising:
forming a select unit on a substrate, wherein the select unit comprises a transistor having
a first source/drain (S/D) region,
a second S/D region, and
a gate between the first and second S/D regions;

forming a dielectric layer on the substrate covering the select unit, wherein the dielectric layer includes storage pad coupled to the first S/D region;
forming a storage unit on the storage pad, wherein forming the storage unit comprises
forming a bottom electrode,
forming a fixed layer on the bottom electrode, wherein the fixed layer comprises
a composite spacer layer disposed on the bottom electrode, wherein the composite spacer layer comprises
a base layer, and
an amorphous buffer layer disposed over the base layer, and

a reference layer on the composite spacer layer, wherein the amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation,

forming at least one tunneling barrier layer over the fixed layer,
forming a storage layer over the tunneling barrier layer, and
forming a top electrode over the storage layer; and

forming a bitline coupled to the top electrode layer.

2. The method of claim 1 wherein:
the fixed layer further comprises a hard layer disposed on the bottom electrode;
the base layer is disposed on the hard layer and the base layer comprises Mo; and the
amorphous buffer layer disposed over the base layer is a metal layer (M), forming a composite spacer layer Mo/M and the amorphous buffer layer serves as a template for the reference layer to have a body-centered cubic (BCC) crystalline structure in the (001) orientation.

3. The method of claim 2 wherein the metal layer comprises a metal material that serves as a template for the reference layer to have high tunnel magnetoresistance (TMR).

4. The method of claim 3 wherein the metal layer M comprises Ta, V, FeV, TaN or MoN.

5. The method of claim 2 wherein the hard layer comprises Co/Pt bilayer and the reference layer comprises CoFeB layer.

6. The method of claim 2 wherein forming the composite spacer layer further comprises forming a coupling layer (C) in between the base layer and buffer layer, wherein the coupling layer provides strong coupling between the hard layer and the reference layer.

7. The method of claim 6 wherein the amorphous buffer layer disposed over the base layer is a metal layer (M), forming a composite spacer layer Mo/C/M.

8. The method of claim 7 wherein the coupling layer is a magnetic layer which is ferromagnetically weak which acts as a paramagnetic layer to promote strong magnetic coupling between the hard layer and the reference layer.

9. The method of claim 8 wherein the magnetic layer of the coupling layer includes Co, Fe or Ni.

10. The method of claim 6 wherein the hard layer comprises Co/Pt bilayer and the reference layer comprises CoFeB layer.

11. The method of claim 1 wherein the tunneling barrier layer comprises first and second tunneling barrier layers and wherein the storage layer is formed in between the first and second tunneling barrier layers.

12. A method of forming a storage unit of a magnetic memory cell comprising:
forming a bottom electrode;
forming a fixed layer on the bottom electrode, wherein the fixed layer comprises
a composite spacer layer disposed on the bottom electrode, wherein the composite spacer layer comprises
a base layer, and
an amorphous buffer layer disposed over the base layer, and

a reference layer on the composite spacer layer, wherein the amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation;

forming at least one tunneling barrier layer over the fixed layer;
forming a storage layer over the tunneling barrier layer; and
forming a top electrode over the storage layer.

13. The method of claim 12 wherein:
the fixed layer further comprises a hard layer; and
the composite spacer layer is disposed on the hard layer and serves as a diffusion barrier between the reference and hard layers.

14. The method of claim 12 wherein:
the base layer comprises Mo; and
the amorphous buffer layer disposed over the base layer is a metal layer (M), forming a composite spacer layer Mo/M and the amorphous buffer layer serves as a template for the reference layer to have a body-centered cubic (BCC) crystalline structure in the (001) orientation.

15. The method of claim 14 wherein the metal layer comprises a metal material that serves as a template for the reference layer to have high tunnel magnetoresistance (TMR).

16. The method of claim 13 wherein forming the composite spacer layer further comprises forming a coupling layer between the base layer and buffer layer, wherein the coupling layer provides strong coupling between the hard layer and the reference layer.

17. The method of claim 16 wherein the coupling layer is a magnetic layer which is ferromagnetically weak which acts as a paramagnetic layer to promote strong magnetic coupling between the hard layer and the reference layer.

18. A storage unit of a magnetic memory cell comprising:
a bottom electrode;
a fixed layer disposed on the bottom electrode, wherein the fixed layer comprises
a composite spacer layer disposed on the bottom electrode, wherein the composite spacer layer comprises
a base layer, and
an amorphous buffer layer disposed over the base layer, and

a reference layer on the composite spacer layer, wherein the amorphous buffer layer serves as a template for the reference layer to have a desired crystalline structure in a desired orientation;

at least one tunneling barrier layer disposed over the fixed layer;
a storage layer disposed over the tunneling barrier layer; and
a top electrode disposed over the storage layer.

19. The storage unit of claim 18 wherein:
the fixed layer further comprises a hard layer;
the base layer is disposed on the hard layer and the base layer comprises Mo; and
the amorphous buffer layer disposed over the base layer is a metal layer (M), forming a composite spacer layer Mo/M and the amorphous buffer layer serves as a template for the reference layer to have a body-centered cubic (BCC) crystalline structure in the (001) orientation.

20. The storage unit of claim 19 wherein the composite spacer layer further comprises a coupling layer disposed between the base layer and buffer layer, wherein the coupling layer provides strong coupling between the hard layer and the reference layer.