LITE DEPALMA GREENBERG, LLC

Allyn Z. Lite 

Michael E. Patunas 

Mayra V. Tarantino 

Two Gateway Center, 12th Floor 

Newark, New Jersey 07102 

Telephone: (973) 623-3000 

Facsimile: (973) 877-3872 

alite@litedepalma.com 

mpatunas@litedepalma.com 

mtarantino@litedepalma.com 

Attorneys for Defendants Hanmi USA, Inc., 

Hanmi Pharmaceutical Co., Ltd., Hanmi Fine 

Chemical Co., Ltd., and Hanmi Holdings Co., 

Ltd.

UNITED STATES DISTRICT COURT 

DISTRICT OF NEW JERSEY 

ASTRAZENECA AB, AKTIEBOLAGET 

HÄSSLE, ASTRAZENECA LP, KBI INC., 

and KBI-E INC., 

 Plaintiffs and 

 Counterclaim Defendants, 

 v. 

HANMI USA, INC., HANMI 

PHARMACEUTICAL CO., LTD., HANMI 

FINE CHEMICAL CO., LTD, and HANMI 

HOLDINGS CO., LTD., 

 Defendants and 

 Counterclaim Plaintiffs. 

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Civil Action No. 3:11-CV-00760-JAP-TJB 

DECLARATION OF JERRY L. ATWOOD, Ph.D. 

I, Jerry L. Atwood, state and declare as follows: 

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Background 

1. I reside at 5704 Short Line Dr., Columbia, Missouri 65203. I hold a B.S. degree 

in Chemistry and Mathematics from Southwest Missouri State University (1964) and a Ph.D. in 

Chemistry from the University of Illinois (1968). 

2. I am Chairman of the Department of Chemistry at the University of MissouriColumbia. In 1999, I became Curators’ Professor at the University of Missouri-Columbia. I 

have been Chairman since 1994, when I came to the University as Professor. Before that, I was 

employed by the University of Alabama, where I successively held the titles of Assistant 

Professor, Associate Professor, Professor, and University Research Professor. 

3. I have been Co-Editor-in-Chief of the New Journal of Chemistry since 2005. 

From 1985 to 1998, I was Editor of the Journal of Chemical Crystallography. In 1999, I was 

named Consulting Editor for the Journal of Chemical Crystallography. I was Associate Editor 

of Chemical Communications from 1996 to 2005. From 1992 until 2000, I was Editor of 

Supramolecular Chemistry. From 1985 to 1993, I was Regional Editor for the Journal of 

Coordination Chemistry. I am co-Editor of the Inclusion Compounds book series (five 

volumes), Comprehensive Supramolecular Chemistry (ten volumes), and the Encyclopedia of 

Supramolecular Chemistry (2 volumes). I currently serve on the Editorial Boards of Crystal 

Growth & Design, Chemical Communications, the Journal of Coordination Chemistry, and 

Supramolecular Chemistry. I have published more than 660 articles in refereed journals. 

4. I have authored thirteen patents. I have taught more than 10,000 students in 

undergraduate University chemistry courses and I have taught and supervised graduate students 

(at both the Masters and Ph.D. level) with a primary emphasis on materials testing, organic 

synthesis, X-ray crystallography, and crystallization. I am an expert in the fields of materials 

testing, crystal growth, crystal engineering, X-ray crystallography, organic chemistry, and 

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polymer chemistry. I have consulted widely for industry, particularly in the fields of 

pharmaceutical chemistry and polymer chemistry. A copy of my curriculum vitae is provided as 

Exhibit “A”. 

Scope of Review 

5. I have reviewed U.S. Patent No. 5,714,504 (“the ‘504 patent”) and U.S. Patent No. 

5,877,192 (“the ‘192 patent”). I have reviewed the prosecution histories for these patents. I 

have also reviewed relevant portions of the Court’s prior claim construction decision in AZ v. 

DRL, as discussed below. I have reviewed a portion of a Declaration of Wayne Genck, Ph.D. in 

this case, dated October 7, 2011, as discussed below. I have reviewed portions of the Joint 

Claim Construction and Prehearing Statement filed in this case. I have also reviewed a few 

other specific items mentioned in my comments below. 

6. I have been asked to provide comments on the meaning to a person of ordinary skill 

in the art of certain claim terms of the ‘504 and ‘192 patents, pertaining to salt scope and optical 

purity issues, and have provided those comments below. I have not considered any claim 

construction issues other than those discussed below, and have not been asked to consider any 

other issues in this case. 

Credentials of One of Ordinary Skill in the Art 

7. I have reviewed paragraph 32 of Dr. Genck’s Declaration mentioned above, in which 

he stated: 

32. I have reviewed U.S. Patent No. 5,714,504 (“the ‘504 Patent” ( D.I. 86-2)) 

which is based on U.S. Patent Application No. 376,512 filed January 23, 1995 

(“the ‘512 application”), which references two prior applications filed in 1994 and 

1993. I have also reviewed the Patent Office prosecution history of the ‘504 

patent. It is my opinion that, at the time of these filings in the 1993-1995 time 

frame, one of ordinary skill in the art to which the patent pertains would have a 

Ph.D. in Chemistry, Chemical Engineering, Pharmaceutical Sciences or 

Pharmaceutical Engineering, or a B.S. and 2 – 5 years of experience with organic 

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synthesis, separation, purification, and crystallization techniques in the 

pharmaceutical industry. This experience should also include testing and 

analytical techniques such as differential scanning calorimetry, thermogravimetric 

analysis and X-ray powder diffraction analysis. 

8. Based on my background, education and experience over the past 40+ years, I am 

able to comment on the knowledge of such a person at the relevant time. In short, Dr. Genck’s 

view is reasonable, and I agree with it. I would also apply it to the ‘192 patent, which was filed 

April 11, 1997 and is related to the ‘504 patent. The qualifications and skill set of a person of 

ordinary skill in the art in 1993, 1995 or 1997 would have been the same. 

Issues Regarding “Salt” Scope In Both Patents 

“alkaline salt” -- ‘504 patent 

9. Each of claims 1, 6 and 7 of the ‘504 patent calls for an “alkaline salt” of (-)-

omeprazole. I am informed that Hanmi submits that this term should be construed as follows:

“Na+, Mg2+, Li+, K+, Ca 2+ or N+(R)4 salt” 

I agree that a person of ordinary skill in the art reading the ‘504 patent’s application as filed on 

January 23, 1995 (Application No. 376,512) would interpret “alkaline salt” as Hanmi has 

proposed. A number of reasons support this conclusion. 

10. The term “alkaline salt” is not defined in independent claims 1, 6 or 7. However, the 

specification is clear as to its meaning and expressly defines the term as the Na+

, Mg2+, Li+, K+, 

Ca 2+ or N+(R)4 salts. The ‘504 patent specification clearly and consistently states that the 

compounds of the invention are the five inorganic salts and one organic genus of salts of an 

enantiomer of omeprazole. First, the Abstract on the cover page of the patent states that “[t]he 

novel optically pure compounds Na+

, Mg2+, Li+, K+, Ca 2+ or N+(R)4 salts of [the enantiomers of 

omeprazole]” as well as processes for the making and using them, as well as intermediates, are 

the subject matter of the ‘504 patent. This statement limits the patent right out of the box. 

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11. Next, the “Detailed Description of the Invention” portion of the specification 

expressly defines salt scope as follows: 

The present invention refers to the new Na+

, Mg2+, Li+, K+, Ca 2+ and 

N+

(R)4 salts of the single enantiomers of omeprazole, where R is an 

alkyl with 1-4 carbon atoms, i.e. Na+

, Mg2+, Li+, K+, Ca 2+ and N+(R)4 

salts of (+)-5-methoxy-2-[[(4-methoxy-3,5-dimethyl-2-

pyridinyl)methyl]sulfinyl]-1H- benzimidazole and (-)-5-methoxy-2-

[[(4-methoxy-3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-1Hbenzimidazole, where R is an alkyl with 1-4 carbon atoms.” 

Col. 2, lines 42-49 (emphasis added). A person of ordinary skill in the art would take these 

statements at face value, and conclude that no other salt forms were contemplated at the time of 

filing. Clearly, in my judgment, because AstraZeneca defined the six named salt species as the 

present invention, and not simply examples of permissible salt species, the claim would be 

understood to match this express definition. 

12. The specification further identifies the Na+

, Ca 2+ and Mg2+ salts as “[p]articularly 

preferred” salts, and the Na+ and Mg2+ salts of omeprazole (according to compounds Ia and Ib) 

as the “[m]ost preferred salts according to the invention.” (col. 2, line 50 – col. 3, line 15). 

Beyond the most preferred Na+ and Mg2+ salts, the ‘504 patent states that the alkaline salts are 

limited to the six species disclosed: “alkaline salts of the single enantiomers of the invention 

are, as mentioned above, beside the sodium salts (compounds Ia and Ib) and the magnesium 

salts (compounds IIa and IIb) exemplified by their salts with Li+

, K+, Ca 2+ and N+(R)4, where R 

is an alkyl with 1-4 C-atoms.” (col. 5, lines 7-11). Because none of these other salts (Li+, K+, 

Ca 2+ and N+

(R)4 ) were actually “exemplified” in the sense of having been prepared and 

disclosed, the ‘504 patent clearly defined alkaline salts as the six species -- two that were made 

(see Examples 1-7) and four that were not. In light of the way the ‘504 patent specification was 

drafted, one of ordinary skill in the art would clearly understand that the term “alkaline salt” of 

claims 1, 6 and 7 of the ‘504 patent would be limited to the Na+

, Mg2+, Li+, K+, Ca 2+ and N+(R)4 

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salt species. No hint of any broader disclosure would have been recognized by the skilled 

artisan. 

13. The prosecution history of the ‘504 patent confirms that the construction of “alkaline 

salt” is limited to the Na+

, Mg2+, Li+, K+, Ca 2+ or N+(R)4 salts. According to the cover page of 

the ‘504 patent, the ’504 patent was filed as Application No. 376,512 (“the ’512 application”) 

on January 23, 1995 as a continuation-in-part of Ser. No. 08/256,174. There were 34 claims in 

the ’512 application as originally filed. (‘512 application, pp. 26-32.) Consistent with the scope 

of the original specification filed on January 23, 1995, most of the original claims of the ‘512 

application were directed to the six particular salt compounds of omeprazole’s enantiomers. 

(Claims to a heterocyclic intermediate and processes of preparing particular compounds were 

also present, but I do not consider them relevant to my analysis.) Original claim 1 of the ‘512 

application is representative: 

1. An optically pure enantiomeric compound comprising a Na+

, Mg2+, 

Li+

, K+, Ca 2+ or N+(R)4 salt of (+)-5-methoxy-2-[[(4-methoxy-3,5-

dimethyl-2-pyridinyl)methyl]sulfinyl]-1H- benzimidazole or (-)-5-

methoxy-2-[[(4-methoxy-3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-

1H- benzimidazole, wherein R is an alkyl with 1-4 carbon atoms. 

‘512 application, p. 26. None of claims 1-34 of the ‘512 application as originally filed 

generically claimed an “alkaline salt” of (-)-omeprazole; instead, all original claims on the 

enantiomeric compounds were directed to only these six salt species, or a subset of them (e.g., 

claim 30). ‘512 application at pages 26-32. This further supports my conclusions that the skilled 

artisan would not give broad play to the claim term “alkaline salt.” 

14. On August 12, 1996, claim 1 and other original enantiomer claims were rejected 

based on prior art and for obviousness-type double patenting (based on the parent application, 

No. 256,174, which was pending at that time). August 12, 1996 Office Action. In a January 21, 

1997 Examiner interview summary record, the Examiner suggested that not all alkaline salt 

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forms of (-)-omeprazole would be encompassed within the scope of the claims, stating: “A 

pharmaceutical formulation for oral administration of pure solid state (-) enantiomer of 

omeprazole Na-salt may be allowable after reviewing the data in affidavit form. . . . The scope 

of the claim will depend on the data submitted.” (emphasis added). 

15. In a February 12, 1997 Amendment, AstraZenenca cancelled all of original claims 1-

34 and added new claims 35-44, which later issued as claims 1-10 of the ’504 patent. These 

new claims introduced the term “alkaline salt” for the first time, in contrast to the original 

claims discussed above which were limited to the six salts. February 12, 1997 Amendment. 

When it presented the new claim set in that Amendment, AstraZeneca did not point out where in 

the specification support existed to claim a broader genus of alkaline salts as opposed to the six 

salts defined in the specification as “the present invention.” As I have pointed out above, the 

specification does not describe any broader genus of “alkaline salts,” but only describes the six 

salt species. 

16. When it filed the February 12, 1997 Amendment, AstraZeneca also submitted a 

Declaration of Dr. Andersson. The Andersson Declaration reported on two clinical studies 

involving both the sodium salt and the magnesium salt of (-)-omeprazole. Based on the clinical 

studies reported in the Andersson Declaration, AstraZeneca argued that the sodium and 

magnesium salts of (-)-omeprazole unexpectedly exhibited a different and more advantageous 

pharmacokinetic profile than racemic omeprazole. These results were specifically attributed to 

the sodium and magnesium salts used in the clinical studies. The Examiner then allowed the 

pending claims on April 25, 1997. 

17. From the prosecution history, it is clear that AstraZeneca never made any arguments 

rebutting the Examiner’s statement in the interview summary that “[t]he scope of the claim will 

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depend on the data submitted.” Thus, the prosecution history as a whole confirms a claim scope 

that is no broader than the named species (based on “the data submitted” by the applicants), and 

is consistent with a straightforward reading of the ‘512 application as originally filed, which 

included not only a precise definition of salt scope, but also no hint that other salts were 

contemplated at the time of filing in 1995. 

18. I am aware of the fact that the new claim set presented during prosecution included 

dependent claims, now issued as claims 3 and 10 of the ‘504 patent, which were directed to the 

six salt species discussed above. I am also generally familiar with the doctrine of claim 

differentiation, as meaning that independent claims are usually broader in scope than the 

dependent claims. However, I am informed that, legally, claim differentiation is a rebuttable 

presumption. Here, I have no trouble concluding that the ‘512 application as filed in January 

1995 would “trump” the new claim set added later during prosecution. I note again in this 

regard that when it filed its replacement claim set, AstraZeneca never pointed out to the Patent 

Office precisely where in the ‘512 specification a concept of “alkaline salt” broader than the 

express definition of six salt species is disclosed. As I stated above, a person of ordinary skill in 

the art in the mid-1990’s would find no basis in the as-filed ‘512 application for any concept 

broader than the six salt species originally disclosed, which were expressly defined as “the 

present invention”. 

19. AstraZeneca’s proposed construction of alkaline salt as a “basic salt (here, a salt in 

which (-)-omeprazole is negatively charged) that is suitable for use in a pharmaceutical 

formulation” is unsupported. First, “suitable for use in a pharmaceutical formulation” does not 

relate to the scope of the salts. Neither the specification nor the prosecution history hints at 

such a definition. 

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20. Second, there is no support in the specification or prosecution history for “alkaline 

salt” being defined as any “basic salt.” The ‘512 patent application refers to six particular salt 

forms, and no others. 

“pharmaceutically acceptable salt” – ‘192 patent 

21. Independent claims 1, 2 and 12 call for (-)-omeprazole or a “pharmaceutically 

acceptable salt” thereof. I am informed that Hanmi submitted two claim constructions as 

follows: 

“Main” Construction based on “incorporated” ‘512 Spec’n: “Na+

, Mg2+, Li+, K+, Ca 2+ 

 or N+(R)4 salt”, 

“Alternative” Construction based on ‘192 Spec’n: “an acid or alkaline pharmaceutically 

acceptable non-toxic salt.” 

Joint Claim Construction Statement, Appendix D. 

22. “Pharmaceutically acceptable salt” is not per se defined in the ‘192 patent claims. 

The ‘192 patent specification, however, first refers to the parent ‘512 application’s disclosure of 

the salt forms of (-)-omeprazole: “[t]he description of the salt forms of the single enantiomers of 

omeprazole and the process of making the same is herein incorporated by reference to 

copending Ser. No. 08/376,512.” (‘192 patent, col. 1, lines 10-13 -- I note that the ‘512 

application issued as the ‘504 patent). While I am informed there may be a legal issue as to 

whether this was a sufficient “incorporation by reference” of the entire prior application or 

specific portions of it, in the following comments I have been asked to assume that the entire 

‘512 application was incorporated by reference into the ‘192 patent. 

23. Based on that assumption, an unusual situation is presented because the ‘192 patent 

would contain two distinct definitions of suitable salt scope. On the one hand, the particular 

“salt forms” of the ‘512 application, if incorporated into the ‘192 patent, would be understood to 

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be limited to the expressly described salt species (e.g., Na+

, Mg2+, Li+, K+, Ca2+ and N+(R)4 ), for 

the reasons I have provided above. 

24. On the other hand, despite the incorporation by reference of the parent ‘512 

application (which is restricted to six particular salts), the ‘192 specification went on to include 

an explicit definition of “pharmaceutically acceptable salt:” 

The term “pharmaceutically acceptable salt” refers to both acid and alkaline 

pharmaceutically acceptable non-toxic salts. 

‘192 patent, col. 4, lines 13-16. Thus, based on this explicit definition, one of ordinary skill in 

the art would understand the term should be construed as meaning “an acid or alkaline 

pharmaceutically acceptable non-toxic salt” in the ‘192 independent claims. Because 

AstraZeneca expressly defined “pharmaceutically acceptable salt” as “an acid or alkaline 

pharmaceutically acceptable non-toxic salt” in the ‘192 specification, in my view that definition 

would be considered dominant and controlling by a person of ordinary skill in the art. 

25. Thus, while the ‘192 patent’s specification (with reference to the parent ‘504 patent) 

is confusing, in my judgment the broader definition of “an acid or alkaline pharmaceutically 

acceptable non-toxic salt” in the ‘192 patent at col. 4, lines 13-16 cannot be ignored. Although I 

have never seen this type of situation, one of ordinary skill in the art would at least attempt to 

reconcile the apparent contradiction in the incorporated ‘512 application’s salt scope (“The 

present invention refers to the new Na+

, Mg2+, Li+, K+, Ca 2+ and N+(R)4 salts of the single 

enantiomers of omeprazole...”) with the ‘192 patent’s broader definition (“an acid or alkaline 

pharmaceutically acceptable non-toxic salt”), by combining them. On the assumption that the 

entire parent ‘512 application’s disclosure is incorporated by reference into the ‘192 patent, that 

disclosure pertains solely to the six species of alkaline salts, as discussed above. The 

“pharmaceutically acceptable salts” as defined in the ‘192 patent include both acid and alkaline 

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salts, and so the incorporated disclosure would be understood to pertain only to alkaline 

pharmaceutically acceptable salts, and not acidic species. Under a “combined” construction, the 

acid component would be broadly defined and the alkaline component would be restricted per 

the ‘504 patent’s definition. In my view, such a “combined” approach would be the only 

rational solution from the standpoint of one of ordinary skill in the art. 

26. My views that the acid component should not be ignored are supported by the 

Court’s statements in AZ v. DRL, where AstraZeneca previously asserted that “pharmaceutically 

acceptable salt” in the ‘192 claims encompassed both acid and alkaline species. The Court’s 

decision states: 

13. “pharmaceutically acceptable salt 

This term appears in claims 1, 2, 7–9 and 12. Astra contends that this term should 

be construed to mean “both acid and alkaline nontoxic ionic compound.” DRL 

contends that this term need not be construed and the ordinary meaning as 

understood by those of ordinary skill in the art should apply. However, if 

construction is required, DRL proposes that the phrase be construed as “a salt that 

is suitable for use in a pharmaceutical formulation.” 

Once again, Astra's basis for its proposed construction of this term is nowhere 

addressed in Astra's claim construction papers. The Court, therefore, accepts 

DRL's argument that this term need not be construed. 

Page *62. Although it is unclear why AstraZeneca could not point the Court to the specific 

definition at column 4, lines 13-16 of the ‘192 patent, AstraZeneca clearly urged a position then 

that is contradictory to what I am informed is its position here -- the “acid” part of the definition 

can simply be ignored. 

Issues Regarding Optical Purity In Both Patents 

 “(-)-enantiomer of 5-methoxy-2[[(4-methoxy-3,5-dimethyl-2- 

pyridinyl)methyl]sulfinyl]-1H-benzimidazole” – ‘504 patent independent claims 1, 6 

and 7 and “optically pure” – dependent claim 2 

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27. Each of independent claims 1, 6 and 7 of the ‘504 patent expressly recites a salt of 

the “(-)-enantiomer of 5-methoxy-2[[(4-methoxy-3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-1Hbenzimidazole.” I am informed that Hanmi asserts that the quoted term should be construed as 

follows: 

 “(-)-omeprazole” or the “(-)-enantiomer of omeprazole” [“(-)-omeprazole” is also known 

as “(S)-omeprazole”]. 

I agree that a person of ordinary skill in the art reading the ‘504 patent’s application as filed on 

January 23, 1995 would interpret this claim term as Hanmi has proposed. Again, a number of 

reasons support this conclusion. Below, I address what I understand to be AstraZeneca’s 

contentions seeking to have specific, numerical optical purity limitations included as part of the 

construction. I also address here the claim term “optically pure” in claim 2 of the ‘504 patent 

because they are intertwined. 

28. In AZ v. DRL, the Court noted that: 

The claims at issue expressly require the alkaline salts of the (-)-enantiomer of 

omeprazole. ‘504 patent, col. 14, lines 6-10. By focusing a person skilled in the 

art on the enantiomer, Astra asserts that the claims obviously require some level 

of optical purity. Indeed, a person of ordinary skill in the art would know that 

“[t]he ‘(-)’ denotes that the compound has some level of optical purity.” 

Pages *18-19. The Court’s recognition of the well known ‘(-)’ symbol in the compound’s name, 

as denoting one of the enantiomers as opposed to the racemate or the other enantiomer, is 

consistent with Hanmi’s proposed construction – “(-)-omeprazole or the (-)-enantiomer of 

omeprazole.” 

29. The Court went on to construe compounds of the ’504 patent independent claims 1, 

6 and 7 as having “high optical purity” of “at least 94% enantiomeric excess” (e.e.), basically 

agreeing with AstraZeneca’s position (pages *19-21). The Court then considered the term 

“optically pure” in dependent claim 2, and also adopted AstraZeneca’s position: “essentially 

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free of the (+)-enantiomer of omeprazole” and “at least 98% enantiomeric excess (e.e.)” (pages 

*21-23). 

30. With due respect, the ‘504 patent’s specification and prosecution history do not 

support adding numerical limitations to any of the ‘504 claims (or the ‘192 claims, as discussed 

below), despite AstraZeneca’s apparent prior arguments which appeared to persuade the Court’s 

constructions. 

31. The ‘504 patent expressly defines two levels of optical purity -- “optically pure” and 

“very high optical purity:” 

With the expression “optically pure Na+

 salts of omeprazole” is meant the (+)-

enantiomer of omeprazole Na-salt essentially free of the (-)-enantiomer of 

omeprazole Na-salt and the (-)-enantiomer essentially free of the (+)-enantiomer, 

respectively. 

* * * 

Because it is possible to purify optically impure or partially pure salts of the 

enantiomers of omeprazole by crystallization, they can be obtained in very high 

optical purity, namely ≥99.8% enantiomeric excess (e.e.) even from an optically 

contaminated preparation. 

Col. 3, lines 31-36 and 43-48 (emphasis added). The ‘504 specification makes clear that the 

term “optically pure” means “the (-)-enantiomer essentially free of the (+)-enantiomer.” Col. 3, 

lines 31-36 . It also makes clear that “very high optical purity” means ≥99.8% e.e.” Col. 3, lines 

43-48. AstraZeneca chose to limit the highest level of optical purity numerically and, while the 

‘504 specification disclosed certain Examples as preferred embodiments, no claim of the ‘504 

patent recites or requires “very high optical purity.” 

32. On the other hand, AstraZeneca could have, but did not, limit the definition of 

“optically pure” in the ‘504 claims numerically. (I refer to AstraZeneca’s U.S. Patent 

6,875,872, which has the same specification as the ‘504 patent.) Instead, the ‘504 patent’s 

express definition at col. 3, lines 31-36 avoided any numerical lower limit. Thus, the working 

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Examples in the ‘504 patent had to have formed the basis for AstraZeneca’s prior arguments 

calling for a definition with a numerical limitation. But read in context, the Examples beginning 

in column 6 are merely illustrative -- as the term “Example” itself means -- and I see no basis 

for including any e.e. % reported as a lower limit of optical purity in the Examples in the claims. 

In fact, the ‘504 specification prefaces the Examples with the following unambiguous statement: 

The invention is illustrated by the following examples using preferred 

procedures for the preparation of optically pure sodium salts and magnesium 

salts. 

‘504 patent, col. 6, lines 26-28 (emphasis added). While Examples of 98% e.e. are reported, a 

conclusion that “optically pure” in claim 2 requires a minimum of 98% e.e. would be contrary 

to the express definition in the specification (“essentially free of” at col. 3, lines 31-36), as well 

as the suggestion at col. 6, lines 26-28 that “non-preferred” procedures could yield lower optical 

purity values, and still be within the scope of the claims. 

33. Accordingly, one of ordinary skill in the art would understand that the term 

“optically pure” in claim 2 would be given its express definition in column 3 -- “the (-)-

enantiomer essentially free of the (+)-enantiomer” (‘504 patent at col. 3, lines 31-36). I see no 

basis in the patent or prosecution history for limiting claim 2 to 98% e.e., as that would be based 

on preferred embodiments of the Examples. 

34. If dependent claim 2 is not limited numerically, clearly no basis exists for 

AstraZeneca to have urged in the prior AZ v. DRL case, or now, that independent claims 1, 6 

and 7 of the ‘504 patent should require any specific lower limit of optical purity. Yet, in AZ v. 

DRL, the Court accepted AstraZeneca’s position that Example 12 provides a basis for a 

minimum optical purity of 94% e.e. However, a skilled artisan would recognize that the 

working Examples cannot limit claim scope for the reasons set forth above. Moreover, even if 

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they could, Example 12 provides no support for the subject matter of claims 1, 6 and 7. Those 

claims are directed to alkaline salts of (-)-omeprazole, whereas Example 12 forms the free base 

or neutral (i.e., non-salt) form of (-)-omeprazole. Indeed, Example 12 illustrates the final stage 

of what is characterized as a novel process of making the enantiomers. The ‘504 patent states 

that “The present invention in a further aspect provides a novel method for preparing the novel 

compounds of the invention in large scale. This novel method can also be used in large scale to 

obtain single enantiomers of omeprazole in neutral form.” ‘504 patent, col. 2, lines 11-15. It 

appears that the process is claimed in AstraZeneca’s U.S. Patent 5,693,818, which issued from 

the ‘504 patent’s parent application 256,174. Clearly, in a general sense, the enantiomers of 

omeprazole in non-salt or neutral form are not part of the invention of the ‘504 patent, because 

they were admittedly known in the prior art. The ‘504 patent additionally states that “The 

separation of the enantiomers of omeprazole in analytical scale is described in e.g. J. 

Chromatography, 532, 305-19 (1990), and in a preparative scale in DE 4035455.” ‘504 patent, 

col. 1, lines 27-29. Thus, Example 12 is not related to the subject matter of claims 1, 6 and 7 of 

the ‘504 patent, which are directed to salts. 

35. Here, nothing in the specification of the ‘504 patent declares or signifies to a person 

of ordinary skill in the art that any salt compound must have a minimum of 94% e.e. In fact, 

that value is merely the reported result for one example – an example of a free base, non-salt 

compound not related to the subject matter of claims 1, 6 and 7 of the ‘504 patent. A person of 

ordinary skill in 1995 would have understood that nothing in Example 12 lays down a ground 

rule that all salt compounds in the patent have a minimum of 94% e.e. 

36. In sum, the compound in claims 1, 6 and 7 is simply a salt of (-)-omeprazole, and 

claim 2 signifies a higher level of optical purity – essentially free of the (+)-enantiomer, based 

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16 

on the express definition at 3:31-36. The only term defined as having a specific, numeric lower 

limit is “very high optical purity,” which is not claimed in the ‘504 patent. 

37. The ‘504 patent’s prosecution history provides further support for Hanmi’s optical 

purity constructions. As discussed above, the ‘512 application as filed contained 34 claims. All 

of the relevant original claims called for “optically pure” enantiomers, and none recited a 

specific numerical lower limit of optical purity. Original claim 1 is again shown below: 

1. An optically pure enantiomeric compound comprising a Na+

, Mg2+, 

Li+

, K+, Ca2+ or N+(R)4 salt of (+)-5-methoxy-2[[(4-methoxy-3,5-dimethyl-2-

pyridinyl)methyl]sulfinyl]-1H-benzimidazole or (-)-5-methoxy-2[[(4-methoxy3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-1H-benzimidazole, wherein R is an 

alkyl with 1-4 carbon atoms. 

‘512 application at p. 26. 

38. Following the August 12, 1996 rejection of claims, AstraZeneca responded February 

12, 1997 by cancelling all then-pending claims (1-34) and adding new claims 35-44 (now issued 

as claims 1-10 of the ‘504 patent), as I discussed above. In the new claim set, the independent 

claims (corresponding to patent claims 1, 6 and 7) were broader than any original claim to the 

enantiomers in that they did not characterize the compounds as “optically pure.” The term 

“optically pure” only appeared in dependent claim 36, which became claim 2 of the ‘504 patent. 

Thus, while “optically pure” in claim 2 should be construed in accordance with the patent’s 

express definition at col. 3, lines 31-36, by dropping that term from the original independent 

claims, AstraZeneca signaled to a skilled artisan that claims other than claim 2 encompass some 

measure of optical impurity. Nothing in the remainder of the prosecution history supports 

AstraZeneca’s position that claims 1, 6 and 7 are limited to 94% e.e. and that claim 2 should be 

limited to 98% e.e. 

“optically pure” – ‘504 patent claim 2 

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17 

39. Claim 2 of the ‘504 patent recites an “optically pure” alkaline salt. I am informed 

that Hanmi submits that this term should be construed as follows: 

“essentially free of (+)-omeprazole alkaline salt, i.e., the single enantiomer”. 

I agree with this proposed construction, because the express definition of “optically pure” in the 

‘504 patent’s specification at col. 3, lines 31-36, should control for the reasons set forth above. 

The key aspect of the definition is “essentially free of,” but without a numerical component. 

“(-)-enantiomer of 5-methoxy-2[[(4-methoxy-3,5-dimethyl-2-

pyridinyl)methyl]sulfinyl]-1H-benzimidazole” – ‘192 patent 

40. Each of independent claims 1, 2 and 12 of the ‘192 patent expressly recites “the (-)-

enantiomer of 5-methoxy-2[[(4-methoxy-3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-1Hbenzimidazole.” I am informed that Hanmi submits that this term should be construed the same 

as in the ‘504 patent as: 

“(-)-omeprazole” or the “(-)-enantiomer of omeprazole.” 

I agree that a person of ordinary skill in the art would not include a numerical optical purity 

limitation of 98% e.e., for the following reasons. 

41. In AZ v. DRL, the Court noted that in the context of the parent ‘504 patent, a person 

of ordinary skill in the art would know that “[t]he ‘(-)’ denotes that the compound has some 

level of optical purity,” citing certain cases. Pages *18-19. Again, the Court’s recognition of 

the well known ‘(-)’ symbol in the compound’s name, as denoting one of the enantiomers as 

opposed to the racemate or the other enantiomer, is consistent with Hanmi’s proposed 

construction – “(-)-omeprazole or the (-)-enantiomer of omeprazole.” 

42. The Court construed the phrase “consisting essentially of the (-)-enantiomer of 5-

methoxy-2[[(4-methoxy-3,5-dimethyl-2-pyridinyl)methyl]sulfinyl]-1H-benzimidazole” of 

the’192 patent independent claims 1, 2 and 12 as “a (-)-enantiomer that is essentially free of its 

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18 

(+) contaminant, which means at least 98% e.e.,” basically agreeing with AstraZeneca’s 

position (pages *29-31, quotation at *31). I respectfully disagree with this construction. 

43. The ‘192 patent specification first discusses the term “(-)-enantiomer of 

[omeprazole]” at col. 1, lines 17-20, and goes on to define the term “single enantiomer” of (-)-

omeprazole as “substantially free from its (+) enantiomeric contaminant.” Col. 1, lines 21-23. 

The claims of the ‘192 patent do not recite the term “single enantiomer.” Nonetheless, I would 

have no problem if the Court equates the terms and adds “substantially free from its (+) 

enantiomeric contaminant” to Hanmi’s proposed construction. In my view, however, the ‘192 

claims would not be understood by a person of ordinary skill in the art to include the 98% e.e. 

limitation in the ‘192 claims, which I am informed AstraZeneca presses here without regard to 

the phrase “substantially free from its (+) enantiomeric contaminant” appearing at col. 1, lines 

21-23. 

44. From my perspective, one of ordinary skill in the art would find that no basis exists 

for AstraZeneca’s position that the claims should be limited to any specific lower limit of 

optical purity. The ‘192 patent’s specification only states that the expression “single enantiomer 

refers to the fact that the (-)-enantiomer is substantially free from its (+) enantiomeric 

contaminant.” See ‘192 patent at col. 1, lines 16-23. Even if the Court equates the claimed “(-)-

enantiomer” with the unclaimed term “single enantiomer” and construes the independent claims 

as “substantially free of”, there should be no inclusion of 98% e.e. as the floor in independent 

claims 1, 2 and 12. 

45. First, there is no mention or discussion anywhere in the ‘192 patent’s specification as 

printed of 98% e.e., or any other numerical lower limit. 

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19 

46. Second, as I noted above under the “salt” discussion, the ‘192 patent’s underlying 

application (Appl’n. No. 833,962) referenced the parent ‘512 application. As before, I have 

been asked to assume the full parent application’s disclosure was incorporated into the ‘192 

patent. On that assumption, the ‘192 independent claims still should not be limited to 98% e.e. 

It is significant that while all of the original claims of the parent ‘512 application claim no more 

than six particular salts of (-)-omeprazole, the ‘192 patent discloses and claims use of the free 

base or neutral form of (-)-omeprazole, or a pharmaceutically acceptable salt thereof. ‘192 

patent at col. 1, lines 16-22 and independent claims 1, 2 and 12. If the ‘192 claims are limited 

to 98% e.e., they would exclude the free base (-)-enantiomer reported in Example 12 of the ‘504 

patent / ‘512 application, which states that the compound was obtained at 94% e.e. (‘504 patent, 

col. 10, line 48 to col. 11, line 3) – the only Example of making the free base (-)-enantiomer by 

the allegedly “novel process” that is reported. 

47. Moreover, the Court in the prior AZ v. DRL claim construction opinion agreed with 

AstraZeneca’s arguments that the phrase “consisting essentially of the (-)-enantiomer of (-)-

omeprazole” in the independent claims of the ‘192 patent should be construed consistently with 

the term “optically pure” in claim 2 of the ‘504 patent. Pages *28-30. I cannot take issue with 

that approach, given the ‘504 patent’s definition of “optically pure” as “essentially free of the 

(+)-enantiomer” (col. 3, lines 31-36) vs. the ‘192 patent -- if the term “(-)-enantiomer” (as 

opposed to “single enantiomer”) is found to be defined as “substantially free from its (+)-

enantiomeric contaminant” (col. 1, lines 16-23). Regardless, I have pointed out in detail above 

that limiting “optically pure” in claim 2 of the ‘504 patent to 98% e.e. is at odds with the 

express definition of “optically pure” not requiring a numerical limit, the presence of nonlimiting “Examples,” and AstraZeneca’s actions in prosecution where it cancelled the initial 

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claims requiring "optically pure" compounds and replaced them with optically impure claims 

except for claim 2. For the same reasons, to the extent the '504 patent and its prosecution 

history are relevant, independent claims 1, 2 and 12 of the '192 patent should not be limited to 

98% e.e. minimum because the basis of that finding was the '504 disclosure. 

48. From my review, nothing in the prosecution history of the' 192 patent requires a 

98% e.e. limitation in the independent claims. 

I declare under penalty of perjury that the foregoing is true and correct. 

Dated: November 3, 2011 h~.~~ 

Jerry L. Atwood, Ph.D. 

20 

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EXHIBIT A

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CURRICULUM VITAE 

Jerry L. Atwood 

Personal 

 Date of Birth: July 27, 1942 

 Place of Birth: Springfield, Missouri 

Education

 B.S., Southwest Missouri State, Chemistry and Mathematics, 1964 

 Ph.D., University of Illinois, 1968

Professional Experience

 Assistant Professor, University of Alabama, 1968-1972 

 Associate Professor, University of Alabama, 1972-1978 

 Professor, University of Alabama, 1978-1987 

 Visiting Professor, Imperial College, 1977 

 Visiting Professor, University of Sussex, 1985 

 University Research Professor, University of Alabama, 1987 - 1994 

 Professor and Chairman, University of Missouri-Columbia, 1994- 

 Curators' Professor, University of Missouri-Columbia, 1999-

Professional Activities 

Co-Editor-in-Chief, New Journal of Chemistry (2005-) 

 Editor, Journal of Supramolecular Chemistry (2000-2004) 

 Editor, Supramolecular Chemistry (1992-2000) 

 Associate Editor, Chemical Communications (1996-2006) 

 Consulting Editor, Journal of Chemical Crystallography (1999-) 

 Editor, Journal of Chemical Crystallography (1985-1998) 

 Regional Editor, Journal of Coordination Chemistry, A & B (1985-1993) 

 Editor, Journal of Inclusion Phenomena (1983-1991) 

 Editorial Advisory Board, Crystal Growth & Design (2000-) 

 International Advisory Editorial Board, New Journal of Chemistry (2003-) 

 Editorial Board, Supramolecular Chemistry (2000-) 

 Editorial Board, Journal of Coordination Chemistry (1993-) 

 Editorial Board, Journal of Organometallic Chemistry (1986-2000) 

 Editorial Board, Crystal Engineering (1998-) 

 Co-Editor, Inclusion Compounds (five volumes) 

 Co-Editor, Comprehensive Supramolecular Chemistry (ten volumes) 

 Co-Editor, Encyclopedia of Supramolecular Chemistry (two volumes) 

 Member, American Chemical Society 

 Member, American Institute of Chemical Engineers 

 Member, Royal Society of Chemistry 

 Member, American Crystallographic Association 

 Institute of Scientific Information, Highly Cited Researchers, isihighlycited.com 

Publications Summary

 Publications in Refereed Journals 672 

 Patents 13 

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Honors and Awards: 

1986 Burnum Award for Teaching and Research, U of Alabama 

1987 University Research Professor, U of Alabama 

1989 von Humboldt Senior Scientist Award, Germany 

1992 Japanese Society for the Promotion of Science Award 

1996 Outstanding Alumni Award, SMSU 

1999 Curators' Professor, University of Missouri (MU) 

2000 President's Award for Research and Creative Activity, MU 

2000 Izatt-Christensen International Macrocyclic Chemistry Award 

2000 Polish Academy of Science, Elected Foreign Member 

2002 Alumni-Faculty Award, MU 

2005 Royal Society of Chemistry, Elected Fellow 

2005 Honorary Medal of the Institute of Physical Chemistry, 

 Polish Academy of Sciences 

2005 Midwest Chemist Award, American Chemical Society 

2010 Distinguished Faculty Alumni Award, MU 

PUBLICATIONS 

Jerry L. Atwood 

 1. J. L. Atwood and G. D. Stucky, "The Crystal and Molecular Stucture of 

[Al(CH3)3]2.C4H8O2," J. Amer. Chem. Soc., 89, 5362 (1967). 

 2. J. L. Atwood and G. D. Stucky, "Dative Nitrogen-to-Metal p-bonding in 

Bis(dimethylamino)beryllium," Chem. Comm., 1169 (1967). 

 3. J. L. Atwood and G. D. Stucky, "Mg[Al(OCH3)2(CH3)2]2.C4H8O2 A Novel 

Coordination Compound of a Metal Alkoxide and a Donor Molecule," J. 

Organometal. Chem., 13, 53 (1968). 

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 4. J. L. Atwood and G. D. Stucky, "The Stereochemistry of Polynuclear Compounds of 

the Main Group Elements. VII. The Structure of 

Octamethyldialuminummonomagnesium," J. Amer. Chem. Soc., 91, 2538 (1969). 

 5. J. L. Atwood and G. D. Stucky, "The Stereochemistry of Polynuclear Compounds of 

the Main Group Elements. XI. The Structure of Bis(dimethylamino)beryllium and Its 

Reaction with Trimethylaluminum," J. Amer. Chem. Soc., 91, 4426 (1969). 

 6. J. L. Atwood and G. D. Stucky, "The Stereochemistry of Polynuclear Compounds of 

the Main Group Elements. XII. The Synthesis and Structure of the 

Ethyleniminodimethylaluminum Trimer," J. Amer. Chem. Soc., 92, 285 (1970). 

 7. J. L. Atwood, P. A. Milton, and S. K. Seale, "Thermal Decomposition of Anionic 

Organoaluminum Thiocyanates," J. Organometal. Chem., 28, C29 (1971). 

 8. C. D. Whitt and J. L. Atwood, "The Structure of Dimethylbis(quinuclidine)- 

beryllium," J. Organometal. Chem., 32, 17 (1971). 

 9. C. D. Whitt, L. M. Parker, and J. L. Atwood, "The Crystal Structure of 

Trimethyl(quinuclidine)aluminum," J. Organometal. Chem., 32, 291 (1971). 

10. P. G. Laubereau, L. Ganguly, J. H. Burns, B. M. Benjamin, J. Selbin, and 

 J. L. Atwood, "Triindenylthoriumchloride and Triindenyluraniumchloride," Inorg. 

Chem., 10, 2274 (1971). 

11. J. L. Atwood and P. A. Milton, "Thermolysis of Tetramethylammonium 

Iodotrimethylaluminate," J. Organometal. Chem., 36, C1 (1972). 

12. K. D. Smith and J. L. Atwood, "The Nature of the Scandium-Carbon Bond. The 

Crystal and Molecular Structure of [(C5H5)2ScCl]2," J. C. S. Chem. Comm., 593 

(1972). 

13. J. L. Atwood and W. R. Newberry, III, "Solid State Structure and Solution Behavior 

of Compounds of the Type M[Al2(CH3)6X]," J. Organometal. Chem., 42, C77 

(1972). 

14. R. A. Abramovitch, G. Grins, R. B. Rogers, J. L. Atwood, M. D. Williams, and S. 

Crider, "A Novel b-Alkylation of Pyridine and Quinoline 1-Oxides," J. Org. Chem., 

37, 3383 (1972). 

15. M. L. Simms, J. L. Atwood, and D. A. Zatko, "The Crystal Structure of 

Ethylenebis(biguanide)silver(III) Perchlorate," J. C. S. Chem. Comm., 46 (1973). 

16. J. L. Atwood and R. E. Cannon, "The Synthesis and Structure of Potassium 

Cyanotrimethylaluminate," J. Organometal. Chem., 47, 321 (1973). 

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17. J. L. Atwood and K. D. Smith, "The Nature of the Scandium-Carbon Bond. II. The 

Crystal and Molecular Structure of Tricyclopentadienylscandium," J. Amer. Chem. 

Soc., 95, 1488 (1973). 

18. J. L. Atwood, J. H. Burns, and P. G. Laubereau, "The Crystal Structure of 

Triindenylsamarium," J. Amer. Chem. Soc., 95, 1830 (1973). 

19. J. L. Atwood, S. K. Seale, and D. H. Roberts, "Thermal Decomposition of Anionic 

Organoaluminum Compounds. III. The Preparation and Structure of the Neutral 

Addition Complex of Acetonitrile and Trimethylaluminum," J. Organometal. Chem., 

51, 105 (1973). 

20. J. L. Atwood, M. L. Simms, and D. A. Zatko, "Bis(2,2'-bipyridine)silver(II) Nitrate 

Monohydrate, Ag(N2C10H8)2.(NO3)2.H2O," Cryst. Struct. Comm., 2, 279 (1973). 

21. J. L. Atwood and P. A. Milton, "The Crystal Structure of Iododimethyl- 

(trimethylamine)aluminum," J. Organometal. Chem., 52, 275 (1973). 

22. J. L. Atwood and D. C. Hrncir, "Thermal Decomposition of Anionic 

Organoaluminum Compounds. IV. The Formation of Alkali Metal 

Tetramethylaluminates and the Crystal Structure of Rb[Al(CH3)4]," J. 

Organometal. Chem., 61, 43 (1973). 

23. J. L. Atwood, B. L. Bailey, B. L. Kindberg, and W. J. Cook, "Ferrocenylalanes. The 

Preparation and Properties of (C5H5)Fe[p-C5H4Al2(CH3)4Cl]," Aust. J. Chem., 26, 

2297 (1973). 

24. J. L. Atwood, C. F. Hains, M. Tsutsui, and A. E. Gebala, "X-ray Crystallographic 

Characterization of the Uranium-Carbon Sigma bond in Tricyclopentadienylphenylethynyluranium (IV)," J. C. S. Chem. Comm., 452 (1973). 

25. J. L. Atwood and K. D. Smith, "Crystal Structure of Di-m-chloro-bis[di-h-cyclopentadienylscandium(III)] Dimer," J. C. S. Dalton Trans., 2487 (1973). 

26. M. Tsutsui, N. Ely, A. E. Gebala, and J. L. Atwood, "Sigma-Bonded Organometallic 

Derivatives of the Lanthanides and Actinides," Ann. N. Y. Acad. Sci., 239, 160 

(1973). 

27. S. K. Seale and J. L. Atwood, "Cationic Influence in Anionic Organoaluminum 

Chemistry Synthesis and Structure of Dimethylthallium Isothiocyanatotrimethylaluminate," J. Organometal. Chem., 64, 57 (1974). 

28. J. L. Atwood and W. R. Newberry, III, "The Interaction of Aromatic Hydrocarbons 

with Organometallic Compounds of the Main Group Elements III. The Crystal 

Structure of K[Al2(CH3)6F].C6H6," J. Organometal. Chem., 66, 15 (1974). 

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29. J. L. Atwood and W. R. Newberry, III, "The Interaction of Aromatic Hydrocarbons 

with Organometallic Compounds of the Main Group Elements. II. Solution 

Behavior and Crystal Structure of K[Al2(CH3)6N3]," J. Organometal. Chem., 65,

145 (1974). 

30. J. L. Atwood and K. D. Smith, "Synthesis and Structure of Bis(indenyl)magnesium," 

J. Amer. Chem. Soc., 96, 994 (1974). 

31. J. L. Atwood and K. D. Smith, "Crystal and Molecular Structure of Trichlorotris- 

(tetrahydrofuran)scandium(III)," J. C. S. Dalton Trans., 921 (1974). 

32. S. K. Seale and J. L. Atwood, "Thermal Decomposition of Anionic Organoaluminum 

Compounds. V. The Preparation and Crystal Structure of the 

(Isopropylidenamino)dimethylaluminum Dimer," J. Organometal. Chem., 73, 27 

(1974). 

33. J. L. Atwood, M. D. Williams, R. H. Garner, and E. J. Cone, "The Crystal and 

Molecular Structure of 4-Bromo-2,3-carbomethoxyl-2-cyclohepten-1-one," Acta 

Cryst., B30, 2066 (1974). 

34. J. L. Atwood, D. C. Hrncir, C. Wong, and W. W. Paudler, "The Structure of a 

Hydrazino-Bridged[12]Annulene. A 12 p-monocyclic Antiaromatic Compound," J. 

Amer. Chem. Soc., 96, 6132 (1974). 

35. J. L. Atwood, D. K. Krass, and W. W. Paudler, "1,2,4-Triazines XIII: The Bond 

Lengths and Bond Angles of a 1,2,4-Triazine," J. Heterocyclic Chem., 11, 743 

(1974). 

36. J. L. Atwood, D. C. Hrncir, and W. R. Newberry, III, "Potassium Methyltrichloroaluminate, K[CH3AlCl3]," Cryst. Struct. Comm., 3, 615 (1974). 

37. J. L. Atwood and W. A. Sheppard, "The Crystal and Molecular Structure of 4,5-

Dicyano-1-imidazolyl(phenyl)bromonium Ylide, C11H5N4Br," Acta Cryst., B31, 

2638 (1975). 

38. J. L. Atwood, W. E. Hunter, D. C. Hrncir, E. Samuel, H. Alt, and M. D. Rausch, 

"Molecular Structures of the Bis(h5-indenyl)dimethyl-Derivatives of Titanium, 

Zirconium, and Hafnium," Inorg. Chem., 14, 1757 (1975). 

39. J. L. Atwood and W. R. Newberry, III, "The Crystal Structure of Cesium 

Azidotrimethylaluminate," J. Organometal. Chem., 87, 1 (1975). 

40. J. L. Atwood, W. E. Hunter, C. Wong, and W. W. Paudler, "The X-ray 

Crystallographically Determined Confirmation of [2.2](2,5)Furano(2,5)- 

pyridinophane," J. Heterocyclic Chem., 12, 433 (1975). 

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41. J. L. Atwood, K. E. Stone, H. G. Alt, D. C. Hrncir, and M. D. Rausch, "Crystal and 

Molecular Structure of Titanocene Dicarbonyl, (h5-C5H5)2Ti(CO)2," J. 

Organometal. Chem., 95, C4 (1975). 

42. J. R. Chang, G. L. McPherson, and J. L. Atwood, "The Electron Paramagnetic 

Resonance Spectra of V(II) and Ni(II) Doped into Crystals of CsCdCl3," Inorg. 

Chem., 14, 3079 (1975). 

43. R. A. Abramovitch, J. L. Atwood, M. L. Good, and B. A. Lampert, "Crystal 

Structure and Mössbauer Spectrum of [2]-Ferrocenophanethiazine 1,1-Dioxide," 

Inorg. Chem., 14, 3085 (1975). 

44. D. H. Miles, U. Kokpol, J. L. Atwood, K. E. Stone, T. A. Bryson, and C. Wilson, 

"Structure of Sarracenin. An Unusual Diacteal Monoterpene from the Insectivorous 

Plant Sarrcenia Flava," J. Amer. Chem. Soc., 98 1569 (1976). 

45. J. L. Atwood, W. E. Hunter, H. Alt, and M. D. Rausch, "The Molecular Structure of 

1,1-Bis(h5-cyclopentadienyl)2,3,4,5-tetraphenyltitanole and its Hafnium Analogue," 

J. Amer. Chem. Soc., 98, 2454 (1976). 

46. J. L. Atwood, M. Tsutsui, N. Ely, and A. E. Gebala, "The Crystal and Molecular 

Structure of Tricyclopentadienylethynyluranium(IV)," J. Coord. Chem., 5, 209 

(1976). 

47. I. Bernal, J. L. Atwood, F. Calderazzo, and D. Vitali, "Structural Studies on 

Organodisulfides as Ligands. I. The Crystal and Molecular Structure of 

[Re2Br2(CO)6S2(C6H5)2], a Compound Containing Both Disulfide and Bromide 

Bridges and Capable of Reversible Coordination of an Intact Disulfide Ligand," 

Gazz. Chim. Italiana, 106, 971 (1976). 

48. J. L. Atwood and S. K. Seale, "The Interaction of Aromatic Hydrocarbons with 

Organometallic Compounds of the Main Group Elements IV. The Preparation and 

Structure of the Novel Selenide K[CH3Se{Al(CH3)3}3].2C6H6," J. Organometal. 

Chem., 114, 107 (1976). 

49. J. Holton, M. F. Lappert, D. G. H. Ballard, R. Pearce, J. L. Atwood, and W. E. 

Hunter, "Dimeric-Dimethyl Lanthanide Complexes, a New Class of ElectronDeficient Compounds, and the Crystal and Molecular Structure of [(h5-

C5H5)2YbCH3]2," J. C. S. Chem. Comm., 480 (1976). 

50. J. Holton, M. F. Lappert, G. R. Schollary, D. G. H. Ballard, R. Pearce, J. L. Atwood, 

and W. E. Hunter, "m-Dialkyl Inner Transition Metal (III) Tetra-alkyl-aluminates. 

The Crystal and Molecular Structure of [(h5-C5H5)2M(CH3)2Al(CH3)2] (M = Y or 

Yb)," J. C. S. Chem. Comm., 425 (1976). 

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51. K. D. Smith and J. L. Atwood, "Diindenylmagnesium," Inorg. Syn., 16, 137 (1976). 

52. J. L. Atwood and J. D. Atwood, "Liquid Clathrates," Advan. Chem. Ser., 150, 112 

(1976). 

53. R. A. Abramovitch, I. Shinkai, B. W. Cue, F. A. Ragan, and J. L. Atwood, "A New 

Ring Transformation of 3-Halo-2-azido-pyridine 1-Oxides. A Novel Synthesis of 

1,2-Oxazin-6-ones," J. Heterocycl. Chem., 13, 415 (1976). 

54. M. M. Goodman, J. L. Atwood, R. T. Carlin, W. E. Hunter, and W. W. Paudler, 

"Tetrazolo[1.5-b]-1,2,4-Triazines: Syntheses and Structure Determination," J. Org. 

Chem., 41, 2860 (1976). 

55. J. L. Atwood, J. K. Newell, W. E. Hunter, I. Bernal, F. Calderazzo, I. P. Mavani, and 

D. Vitali, "Synthesis, Crystal and Molecular Structure of m-Dibromo-mtetraphenyldiphosphinebis(tricarbonylrhenium(I)), a Molecule Containing a New 

Type of Tetraphenyldiphosphane Bridge," J. C. S. Chem. Comm., 441 (1976). 

56. R. L. Mahaffey, J. L. Atwood, M. B. Humphrey, and W. W. Paudler, "N-(pBromphenyl)[2.2](2,5)pyrrolophane: Synthesis and Self-Condensation," J. Org. 

Chem., 41, 2963 (1976). 

57. J. L. Atwood and A. L. Shoemaker, "Synthesis and Crystal Structure of the Novel 

Ferrocenylalane [(h5-C5H5)Fe(h5-C5H3)Al2Me3Cl]2," J. C. S. Chem. Comm., 536 

(1976). 

58. J. L. Atwood, W. E. Hunter, B. A. Lampert, and R. H. Garner, "The Crystal and 

Molecular Structure of 1-Hydroxy-2,3-dicarbomethoxy-1,3-cycloheptadiene," J. 

Cryst. Mol. Struct., 6, 291 (1976). 

59. B. Kalyanaraman, J. L. Atwood, and L. D. Kispert, "The Crystal Structure of aChloroacetic Acid," J. C. S. Chem. Comm., 715 (1976). 

60. B. Kalyanaraman, J. L. Atwood, and L. D. Kispert, "The Crystal Structure of 

Chlorodifluroacetamide," J. Cryst. Mol. Struct., 6, 311 (1976). 

61. I. Bernal, J. L. Atwood, F. Calderazzo, and D. Vitali, "Structural Studies on 

Organodisulfides as Metal Ligands. II. The Crystal and Molecular Structure of 

[Re2Br2(CO)6]S2(CH3)2, a Compound Containing an Intact Dimethyldisulfide 

Bridge Across the Two Metals," Israel J. Chem., 15, 153 (1976/77). 

62. J. L. Atwood, "Liquid Clathrates," Rec. Adv. Separation Sci., 3, 195 (1977). 

63. J. L. Atwood, W. E. Hunter, and K. D. Crissinger, "The Synthesis and Crystal 

Structure of Tetramethylammonium Acetatotrimethylaluminate," J. Organometal. 

Chem., 127, 403 (1977). 

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64. D. H. Miles, J. Bhattacharyya, N. Mody, J. L. Atwood, S. Black, and P. A. Hedin, 

"The Structure of Juncusol. Novel Cytotoxic Dihydrophenanthrene from the 

Estuarine Marsh Plant Juncus Roemerianus," J. Amer. Chem. Soc., 99, 200 (1977). 

65. J. L. Atwood, K. E. Stone, H. G. Alt, D. C. Hrncir, and M. D. Rausch, The Crystal 

Structure of Dicarbonyldicyclopentadienyltitanium(II), (h5-C5H5)2Ti(CO)2," J. 

Organometal. Chem., 132, 367 (1977). 

66. J. L. Atwood, G. K. Barker, J. Holton, W. E. Hunter, and M. F. Lappert, 

"Silylmethyl and Related Complexes. V. Metallocene Bis(trimethylsilyl)- methyls 

and Benzhydryls of Early Transition Metals [M(h5-C5H5)2R] (M = Ti or V) and 

[M(h5-C5H5)2X(R)] (M = Zr or Hf) and the Crystal and Molecular Structures of 

[M(h5-C5H5)2(CHPh2)2] (M = Zr or Hf)," J. Amer. Chem. Soc., 99, 6645 (1977). 

67. J. L. Atwood and D. J. Darensbourg, "Intramolecular Hydrogen Bonding 

Implications of the Lability of the Molybdenum-Piperidine Bond. The Molecular 

Structure of cis-Mo(CO)4[P(OCH3)3]NHC5H10," Inorg. Chem., 16, 2314 (1977). 

68. R. Gruning and J. L. Atwood, "The Crystal Structure of N-sodiohexamethyldisilazane, Na[N{Si(CH3)3}2]," J. Organometal. Chem., 137, 101 (1977). 

69. J. L. Atwood, R. D. Rogers, C. Kutal, and P. Grutsch, "X-ray Crystallographic 

Characterization of the Single Hydrogen Bridge Attachment of the Tetrahydroborate 

Group in [(MePh2P)3CuBH4]," J. C. S. Chem. Comm., 593 (1977). 

70. J. L. Atwood and J. M. Cummings, "The Crystal Structure of Rubidium 

Azidotrimethylaluminate," J. Cryst. Mol. Struct., 7, 257 (1977). 

71. B. Kalyanaraman, L. D. Kispert, and J. L. Atwood, "The Disordered Crystal 

Structure of Bromodifluoroacetamide and Trifluoroacetamide," Acta Crystallogr., 

B34, 1131 (1978). 

72. J. L. Atwood, J. K. Newell, W. E. Hunter, I. Bernal, F. Calderazzo, I. P. Mavani, and 

D. Vitali, "The Crystal and Molecular Structure of m-Dibromo-m-tetraphenyldiphosaphanebis[tricarbonylrhenium(I)]," J. C. S. Dalton Trans., 1189 (1978). 

73. J. L. Atwood, R. D. Rogers, W. E. Hunter, J. Holton, R. Pearce, and M. F. Lappert, 

"Neutral and Anionic Silylmethyl Complexes of the Group 3a and Lanthanoid 

Metals; the Crystal and Molecular Structure of [Li(thf)][Yb{CH(SiMe3)2}3Cl] 

(thf = Tetrahydrofuran)," J. C. S. Chem. Comm., 140 (1978). 

74. E. Carmona-Guzman, G. Wilkinson, J. L. Atwood, W. E. Hunter, and R. D. Rogers, 

"Interaction for Bis(trimethylsilylmethyl)magnesium and Molybdenumtetrachloridebis(tetrahydrofuran). The Crystal Structure of Chlorotris(trimethylsilylmethyl)(trimethylphosphine)molybdenum(IV)," J. C. S. Chem. Comm., 

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465 (1978). 

75. R. D. Rogers, J. L. Atwood, and R. Gruning, "The Crystal Structure of NLithiohexamethyldisilazane," J. Organometal. Chem., 157, 229 (1978). 

76. J. L. Atwood, R. D. Rogers, W. E. Hunter, I. Bernal, R. Lukas, and H. Brunner, "Xray Structure of (C15H15)W(CO)2: A Compound Containing Three Unusually 

Bonded Five-Membered Rings," J. C. S. Chem. Comm., 451 (1978). 

77. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "The Crystal and Molecular 

Structures of Tetra(cyclopentadienyl)zirconium," J. Amer. Chem. Soc., 100, 5238 

(1978). 

78. R. J. Radel, J. L. Atwood, and W. W. Paudler, "Brominations of some 1,2,4-Triazine 

2-Oxides," J. Org. Chem., 43, 2514 (1978). 

79. K. D. Crissinger, R. D. Rogers, and J. L. Atwood, "The Synthesis of 

M[Al2(CH3)6NO3] (M = K+, Rb+, Cs+, NR4+) and the Crystal Structures of 

K[Al2(CH3)6NO3] and K[Al(CH3)3NO3].C6H6," J. Organometal. Chem., 155, 1 

(1978). 

80. J. L. Atwood, L. G. Canada, A. N. K. Lau, A. G. Ludwick, and L. M. Ludwick, 

"Crystal Structure of exo-6-Chloromercury-7-dihydro-exo-7-methoxyaldrin 

(1,2,3,4,10,10-Hexachloro-exo-6-chloromercurio-1,4,4a,5,6,7,8,8a-octahydro-endo, 

exo-1, 4:5, 8-dimethano-exo-7-ethoxynaphthalenel)," J. C. S. Dalton Trans., 1573 

(1978). 

81. J. Mattia, M. B. Humphrey, J. L. Atwood, and M. D. Rausch, "The Syntheses and 

Molecular Structures of Two Metalloindene Complexes: 1,1-Bis(h5-cyclopentadienyl)-

2,3,-bis-(pentafluorophenyl)benzotitanole and 1,1-Bis(h5-cyclopentadienyl)-2-

trimethylsilyl-3-phenylbenzotitanole," Inorg. Chem., 17, 3257 (1978). 

82. C. Kutal, P. Grutsch, J. L. Atwood, and R. D. Rogers, "Structural Characterization of the 

Single Hydrogen Bridge Attachment of the Tetrahydroborate Group in Tris-

(methyldiphenylphosphine)tetrahydroborate-copper," Inorg. Chem., 17, 3558 (1978). 

83. F. Calderazzo, I. P. Mavani, D. Vitali, I. Bernal, J. K. Korp, and J. L. Atwood, "Studies 

on Organometallic Compounds with Hetero Multiple Bridges. V. Crystal and Molecular 

Structure of the Parent Rhenium Complex Re2Br2(CO)6(thf)2 and Products of the 

Tricarbonylrhenium(I) Derived from It," J. Organometal. Chem., 160, 207 (1978). 

84. J. L. Atwood, H. T. Mayfield, and W. A. Sheppard, "4,5-Dicayno-2- 

imidazolyl(diethyl)sulfonium Ylide, (CN)2C3N2S(C2H5)2," Cryst. Struct. Comm., 

7, 739 (1978). 

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85. J. Jeffery, M. F. Lappert, N. T. Luong-Thi, J. L. Atwood, and W. E. Hunter, "Bulky 

Alkyls and Hydridoalkyls of Zirconium(IV): Influence of Steric Constraints Upon 

(i) Conformation and the Zr-C Rotational Barrier, and (ii) the Zr-C Bond Length. Xray Crystal and Molecular Structure of [Zr(h-C5H5)2{CH(SiMe3)2}Ph]," J. C. S. 

Chem. Comm., 1081 (1978). 

86. B. Kalyanaraman, L. D. Kispert, and J. L. Atwood, "Crystal Structure of 2-

Chloroacetamide (a Form): A Reinvestigation," J. Cryst. Mol. Struct., 8, 175 (1978). 

87. G. R. Newkome, V. Majestic, F. Fronczek, and J. L. Atwood, "Synthesis and X-ray 

Structure of N[(CH2)2O(2,6-C6H3N)O2-(CH2)2]3N: A D3 Macrobicyclic Ligand 

Capped by Two sp Nitrogen Atoms," J. Amer. Chem. Soc., 101, 1047 (1979). 

88. J. Holton, M. F. Lappert, D. G. H. Ballard, R. Pearce, J. L. Atwood, and W. E. 

Hunter, "Alkyl-bridged Complexes of the d- and f-block Elements. Part 1. Di-mcyclopentadienylmetal (III) Tetra-alkylaluminates [M(h-C5H5)2R2AlR2] (M = Sc, 

Y, or Ho, with R = Et), and the Crystal and Molecular Structure of [Yb(hC5H5)2Me2AlMe2]," J. C. S. Dalton Trans., 45, (1979). 

89. J. Holton, M. F. Lappert, D. G. H. Ballard, R. Pearce, J. L. Atwood, and W. E. 

Hunter, "Alkyl-bridged Complexes of the d- and f-block elements. Part 2. Di-mcyclopentadienylmetal (III) Methyls [{M(hC5H5)2Me}2] (M = Y, Dy, Ho, Er, Tm, 

or Yb) and the Crystal and Molecular Structures of [{M(h-C5H5)2Me}2] (M = Yb)," 

J. C. S. Dalton Trans., 54. (1979). 

90. J. Korp, I. Bernal, J. L. Atwood, F. Calderazzo, and D. Vitali, "Synthesis, Properties, 

and Crystal and Molecular Structure of [Re2Br2(CO)6(Se2Ph2)], a Binuclear 

Rhenium(I) Complex Containing a Diphenyl Diselenide Bridge," J. C. S. Dalton 

Trans., 1492 (1979). 

91. J. D. Korp, I. Bernal, J. L. Atwood, W. E. Hunter, F. Calderazzo, and D. Vitali, 

"Studies on Organometallic Compounds with Hetero Multiple Bridges. X-ray 

Crystal and Molecular Structure of Mn2Br2(CO)6P2Ph4, the Product Resulting from 

Co-ordinative Addition of P2Ph4 to Manganese (I)," J. C. S. Chem. Comm., 576 

(1979). 

92. J. Holton, M. F. Lappert, D. G. H. Ballard, R. Pearce, J. L. Atwood, and W. E. 

Hunter, "Kinetically-Stable Lanthanide Metal Alkyls and Bridging Methyls," in 

"Organometallics of the f-Elements," edited by T. J. Marks and R. D. Fischer, D. 

Reidel, Boston, 1979, pp. 179-220. 

93. J. L. Atwood, R. Shakir, J. T. Malito, M. Herberhold, W. Kremnitz, W. P. E. 

Bernhagen, and H. G. Alt, "The Preparation and Crystal Structures of 

Dicarbonylcyclopentadienylnitrosylchromium and Dicarbonylfluoroenylnitrosylchromium," J. Organometal. Chem., 165, 65 (1979). 

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94. R. Shakir, M. J. Zaworotko, and J. L. Atwood, "The Crystal and Molecular Structure 

of K[Al2(CH3)6SCN], a Compound which Contains an S,N-Bridging Thiocyanate 

Ligand," J. Organometal. Chem., 171, 9 (1979). 

95. M. Y. Darensbourg, J. L. Atwood, R. R. Burch, W. E. Hunter, and N. Walker, 

"Structural and Chemical Characterization of a Phosphine Bound M-H-M Bridged 

Carbonylate: [NEt4][(m-H)Mo2(Co)9PPh3]," J. Amer. Chem. Soc., 101, 2631 

(1979). 

96. R. D. Rogers, W. J. Cook, and J. L. Atwood, "Ferrocenylalanes 3. The Synthesis and 

Crystal Structure of (h5-C5H5)Fe[h5-C5H4Al2(CH3)4Cl]," Inorg. Chem., 18, 279 

(1979). 

97. W. W. Paudler, R. L. Mahaffey, and J. L. Atwood, "Novel Rearrangement of a 

[2.2](2,5)Pyrrolophane," J. Org. Chem., 44, 2498 (1979). 

98. D. J. Sikora, M. D. Rausch, R. D. Rogers, and J. L. Atwood, "The Structure and 

Reactivity of the First Hafnium Carbonyl, (h5-C5H5)2Hf(CO)2," J. Amer. Chem. 

Soc., 101, 5079 (1979). 

99. J. L. Atwood, W. E. Hunter, R. D. Rogers, E. Carmona-Guzman, and G. Wilkinson, 

"The Crystal Structures of (h-C6H6)MoMe2(PPhMe2)2 and (hC6H5Me)MoMe2(PPhMe2)2," J. C. S. Dalton Trans., 1519 (1979). 

100. M. B. Honan, J. L. Atwood, I. Bernal, and W. Herrmann, "The Crystal and 

Molecular Structure of 1-Bromobenzocymantrene, (h5-C9H6Br)Mn(CO)3. J. 

Organometal. Chem., 179, 403 (1979). 

101. R. D. Rogers and J. L. Atwood, "The Interaction of Aromatic Hydrocarbons with 

Organometallic Compounds of the Main Group Elements. VI. The Synthesis and 

Crystal Structure of Cesium Diiododimethylaluminate p-Xylene Solvate," J. Cryst. 

Mol. Struct., 9, 45 (1979). 

102. R. Shakir, M. J. Zaworotko, and J. L. Atwood, "The Crystal and Molecular 

Structure of Cesium Isothiocyanotrimethylaluminate, Cs[Al(CH3)3NCS]," J. Cryst. 

Mol. Struct., 9, 135 (1979). 

103. M. J. Zaworotko, J. L. Atwood, and L. Floch, "The Crystal and Molecular Structure 

of 5-Amino-1,2,3,4-thiatriazole," J. Cryst. Mol. Struct., 9, 173 (1979). 

104. M. J. Zaworotko and J. L. Atwood, "Crystal and Molecular Structure of 

Cl2AlN(C2H2)C2H4N(CH3)2, a Neutral, Chelated Four-Coordinate Aluminum 

Compound, which Contains Two Types of Al-N Bond," Inorg. Chem., 19, 268 

(1980). 

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105. P. H. Daniels, J. L. Wong, J. L. Atwood, L. G. Canada, and R. D. Rogers, 

"Unreactive 1-Azadiene and Reactive 2-Azadiene in Diels-Alder Reaction of 

Pentachloroazacyclopentadienes," J. Org. Chem., 45, 435 (1980). 

106. E. Carmona-Guzman, G. Wilkinson, R. D. Rogers, W. E. Hunter, M. J. Zaworotko, 

and J. L. Atwood, "Synthesis and Crystal Structures of 

Chloro(trimethylphosphine)tris(trimethylsilylmethyl)molybdenum(IV) and Di-mchloro-bis[bis(carbonyl)trimethylphosphine (1-2-h-trimethylsilylmethylcarbonyl)molybdenum(II)]," J. C. S. Dalton Trans., 229 (1980). 

107. J. L. Atwood, W. E. Hunter, E. Carmona-Guzman, and G. Wilkinson, "The 

Synthesis and Crystal Structure of Hydrido(tetrahydroborato)tetrakis(trimethylphosphine)molybdenum(II)," J. C. S. Dalton Trans., 467 (1980). 

108. B. Cetinkaya, I. Gumrukcu, M. F. Lappert, J. L. Atwood, and R. Shakir, "Lithium 

and Sodium 2,6-Di-t-butylphenoxides and the Crystal and Molecular Structure of 

[Li(OC6H2CH3)-4-But-2,6(OEt2)]2," J. Amer. Chem. Soc., 102, 2086 (1980). 

109. B. Cetinkaya, I. Gumrukcu, M. F. Lappert, J. L. Atwood, R. D. Rogers, and M. J. 

Zaworotko, "Bivalent Germanium, Tin, and Lead 2,6-Di-t-butylphenoxides and the 

Crystal and Molecular Structures of M(OC6H2Me-4-But-2,6)2 (M = Ge or Sn)," J. 

Amer. Chem. Soc., 102, 2088 (1980). 

110. B. Cetinkaya, P. B. Hitchcock, M. F. Lappert, C. Torroni, J. L. Atwood, W. E. 

Hunter, and M. J. Zaworotko, "Transition-metal Complexes of Two Tautomers of a 

Bulky Phenoxide, 2,6-But

2-4-MeC6H2O(ArO); Preparation and the Crystal and 

Molecular Structure of a Phenoxytitanium(III) and a Cyclohexadienoneylrhodium(I) Complex, [Ti(C5H5-h)2OAr] and [Rh(ArO-h)2OAr] and [Rh(ArOh5)(PPh3)2]," J. Organometal. Chem., 188, C31 (1980). 

111. R. Shakir, J. L. Atwood, T. S. Janik, and J. D. Atwood, "Synthesis and Crystal 

Structure of the Novel Hexanuclear Manganese Complex 

[Mn6(CO)9{OP(OEt)2}9]," J. Organometal. Chem., 190, C14 (1980). 

112. J. T. Malito, R. Shakir, and J. L. Atwood, "Synthesis and Structural Studies of 

Chromium, Molybdenum and Tungsten Compounds containing Cyclopentadienyllike Ligands. 3. Dicarbonylnitrosyl(h5-pentamethylcyclo- pentadienyl) 

Complexes," J. C. S. Dalton Trans., 1253 (1980). 

113. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "Synthesis and Structure of (h5-

C5H5)3Gd.OC4H8," J. Organometal. Chem., 192, 65 (1980). 

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114. D. F. Foust, M. D. Rausch, W. E. Hunter, J. L. Atwood, and E. Samuel, "The 

Formation and Molecular Structure of Bis (h5-cyclopentadienyl)bis(pentafluorophenyl)vinylene-vanadium: An Acetylene derivative of Vanadocene," J. 

Organometal. Chem., 197, 217 (1980). 

115. M. D. Rausch, W. P. Hart, J. L. Atwood, and M. J. Zaworotko, "The Formation and 

Molecular Structure of (h5-Nitrocyclopentadienyl)dicarbonylrhodium," J. 

Organometal. Chem., 197, 225 (1980). 

116. M. Y. Darensbourg, R. R. Burch, J. L. Atwood, and W. E. Hunter, "The mH[Mo(CO)4(PMePh2)]2 Anion: An Example of Phosphine Enhancement of MetalMetal Interaction," J. Amer. Chem. Soc., 102, 3290 (1980). 

117. R. V. Bynum, W. E. Hunter, R. D. Rogers, and J. L. Atwood, "Pyrrolyl Complexes 

of the Early Transition Metals. 1. Synthesis and Crystal Structure of (h5-

C5H5)2Zr(h1-NC4H4)2, (h5-C5H5)2Zr(h1-NC4H4)2, and [Na(THF)6]2[Zr- (h1-

NC4H4)6]," Inorg. Chem., 19, 2368 (1980). 

118. R. D. Rogers, W. E. Hunter, and J. L. Atwood, "The Nature of the Novel (C15H15) 

Ligand in [W(CO)2(h5-C5H5)(h3-C15H15)]," J. C. S. Dalton Trans., 1032 (1980). 

119. G. L. McPherson, A. M. McPherson, and J. L. Atwood, "Structures of CsMgBr3, 

CsCdBr3, CsCdBr3, and CsMgI3-Diamagnetic Linear Chain Lattices, J. Phys. 

Chem. Solids, 41, 495 (1980). 

120. J. A. Paulson, D. A. Krost, G. L. McPherson, R. D. Rogers, and J. L. Atwood, 

"Structural, Spectroscopic and Theoretical Studies of an Exchange Coupled 

Manganese(II)-Copper(II) Dimer," Inorg. Chem., 19, 2519 (1980). 

121. R. D. Rogers, L. B. Stone, and J. L. Atwood, "Tetramethylammonium Iodotrimethylaluminate," Cryst. Struct. Comm., 9, 143 (1980). 

122. J. D. Atwood, T. S. Janik, J. L. Atwood, and R. D. Rogers, "Synthesis of 

Bis(benzene)tetracarbonyldivanadium, (C6H6)2V2(CO)4," Syn. Reac. Inorg. Met. 

Org. Chem., 10, 397 (1980). 

123. M. F. Lappert, T. R. Martin, J. L. Atwood, and W. E. Hunter, "Metal Complexes 

Derived from the o-Xylidene Ligand, o-C6H4(CH2}2, and the Crystal and 

Molecular Structure of the Metallocycle [Zr(h-C5H5)2{(CH2)2C6H4-o}]," J. C. S. 

Chem. Comm., 476 (1980). 

124. M. F. Lappert, T. R. Martin, C. R. C. Milne, J. L. Atwood, W. E. Hunter, and R. E. 

Penttila, "Synthesis and Structure of the NbIV Metallocycle [M- (hC5H4SiMe3)2{CH2C6H4CH2-o}] (M = Nb, R = Me3Si) and Reductive Cleavage 

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of d Analogues (M = Ti, Zr, or Hf; R = H or Me3Si) by Na[C10H8]," J. 

Organometal. Chem., 192, C35 (1980). 

125. S. R. Stobart, K. R. Dixon, D. T. Eadie, J. L. Atwood, and M. J. Zaworotko, 

"Transition-Metal Complexes with Pyrazolyl Bridging Ligands Between Very 

Different Metal Centers," Angew. Chem. Int. Ed. Engl., 19, 931 (1980). 

126. M. F. Lappert, M. J. Slade, J. L. Atwood, and M. J. Zaworotko, "Monomeric, 

Coloured Germanium(II) and Tin(II) Di-t-Butylamides, and the Crystal and 

Molecular Structure of Ge[NCMe2(CH2)3CMe2]2," J. C. S. Chem. Comm., 621 

(1980). 

127. M. D. Rausch, D. J. Sikora, D. C. Hrncir, W. E. Hunter, and J. L. Atwood, 

"Formation and Molecular Structure of a Novel Organometallic Titanoxane Derived 

from the Reaction of Dicarbonyltitanocene and Hexafluorobut-2-yne," Inorg. 

Chem., 19, 3817 (1980). 

128. J. L. Atwood, R. D. Rogers, W. E. Hunter, C. Floriani, G. Fachinetti, and A. ChiesiVilla, "The Crystal and Molecular Structure of Two Early Transition Metal 

Dicarbonyldicyclopentadienyl Complexes: (h5-C5H5)2Zr(CO)2 and [(h5-

C5H5)2V(CO)2][B(C6H5)4]," Inorg. Chem., 19, 3812 (1980). 

129. M. F. Lappert, P. I. W. Yarrow, J. L. Atwood, R. Shakir, and J. Holton, 

"Preparation and Properties of Some Bis(cyclopentadienyl)ytterbium(II) Complexes 

and the X-ray Crystal and Molecular Structure of [Yb- (h-C5H4SiMe3)2(thf)2]," J. 

C. S. Chem. Comm., 987 (1980). 

130. D. Pace, W. E. Hunter, R. Shakir, L. D. Kispert, and J. L. Atwood, "Crystal and 

Molecular Structure of Dichlorofluoroacetamide," J. Cryst. Mol. Struct., 10, 115 

(1980). 

131. E. Carmona, F. Gonzalez, M. L. Poveda, J. L. Atwood, and R. D. Rogers, "Alkyl 

and Acyl Derivatives of Nickel(II) Containing Tertiary Phosphine Ligands," J. 

C. S. Dalton Trans., 2108 (1980). 

132. D. J. Sikora, M. D. Rausch, R. D. Rogers, and J. L. Atwood, "New Syntheses and 

Molecular Structures of the Decamethylmetallocene Dicarbonyls, (h5-

C5H5)2M(CO)2 (M = Ti, Zr, Hf)," J. Amer. Chem. Soc., 103, 1265 (1981). 

133. K. O. Devaney, M. R. Freedman, G. L. McPherson, and J. L. Atwood, "Electron 

Paramagnetic Resonance Studies of Manganese (II) and Nickel (II) in Three 

Structural Phases of Rubidium Magnesium Chloride and the Crystal Structure of aRubidium Magnesium Chloride," Inorg. Chem., 20, 140 (1981). 

134. M. F. Lappert, P. I. Riley, P. I. W. Yarrow, J. L. Atwood, W. E. Hunter, and M. J. 

Zaworotko, "Metallocene Derivatives of Early Transition Elements. Part 3. 

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Synthesis, Characterization, Conformation, and Rotational Barriers, Zr-Csp3 of the 

Zirconium (IV) Chlorides [Zr (h-C5H4R)2{CH(SiMe3)2}Cl] and the Crystal and 

Molecular Structures of the t-Butyl and Trimethylsilyl Complexes (R = Me3C of 

Me3Si)," J. C. S. Dalton Trans., 814 (1981). 

135. S. Randle, D. H. Miles, R. Shakir, and J. L. Atwood, "The Structure of Juncunone: 

A Biogenetically Intriguing Molecule from the Marsh Plant Juncus roemerianus," 

J. Org. Chem., 46, 2813 (1981). 

136. D. J. Sikora, M. D. Rausch, R. D. Rogers, and J. L. Atwood, "The Formation and 

Molecular Structure of Bis(h5-cyclopentadienyl)bis(trifluorophosphine)- titanium," 

J. Amer. Chem. Soc., 103, 982 (1981). 

137. W. E. Hunter, J. L. Atwood, G. Fachinetti, and C. Floriani, "The Crystal Structure 

of 1,1-Bis(h5-cyclopentadienyl)2,3,4,5-tetraphenylzirconole," 

J. Organometal. Chem., 204, 67 (1981). 

138. R. Shakir and J. L. Atwood, "The Crystal and Molecular Structure of 

Dicarbonylindenylnitrosylchromium, (h5-C9H7)Cr(CO)2(NO)," Acta Crystallogr., 

B37, 1656 (1981). 

139. J. L. Atwood, R. D. Rogers, J. M. Cummings, I. Bernal, F. Calderazzo, and D. 

Vitali, "Studies on Organometallic Compounds with Hetero Multiple Bridges. VI. 

Synthesis and Crystal and Molecular Structure of a Diphenylditelluride-Bridged 

Complex, a Member of a Family of Rhenium(I) Compounds Containing 

Chalcogens as Donor Atoms," J. C. S. Dalton Trans., 1004 (1981). 

140. R. D. Rogers, B. Kalyanaraman, M. S. Dalton, W. Smith, L. D. Kispert, and J. L. 

Atwood, "Crystal Structure of Bromofluoroacetic Acid: A Chiral Molecule," J. 

Cryst. Mol. Struct., 11, 105 (1981). 

141. F. R. Fronczek, V. K. Majestic, G. R. Newkome, W. E. Hunter, and J. L. Atwood, 

"The Crystal Structures of a Macrocycle Containing 2,6-Pyridino and Piperazino 

Subunits, and of the Tetrachlorocobalt(III)ate Salt of its Diprotoned Cation," J. 

C. S. Perkin II, 331 (1981). 

142. R. D. Rogers, J. L. Atwood, D. Foust, and M. D. Rausch, "The Crystal Structure of 

Vanadocene, (h5-C5H5)2V," J. Cryst. Mol. Struct., 11, 183 (1981). 

143. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "The First Authentic Example of a 

Difference in the Structural Organometallic Chemistry of Zirconium and Hafnium: 

The Crystal and Molecular Structure of (h5-C5H5)2Hf (h1-C5H5)2," J. Amer. 

Chem. Soc., 103, 692 (1981). 

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144. R. D. Rogers, J. L. Atwood, A. Emad, D. J. Sikora, and M. D. Rausch, "The 

Formation and Molecular Structures of (h5-C5H5)3Y.OC4H8 and (h5-

C5H5)3La.OC4H8," J. Organometal. Chem., 216, 383 (1981). 

145. E. Carmona, F. Gonzales, M. L. Poveda, J. L. Atwood, and R. D. Rogers, 

"Synthesis and Properties of Dialkyl Complexes of Nickel(II). The Crystal 

Structure of Bis(trimethylsilylmethyl)bis(pyridine)nickel(II)," J. C. S. Dalton 

Trans., 777 (1981). 

146. D. C. Hrncir, R. D. Rogers, and J. L. Atwood, "New Bonding Mode for a Bridging 

Dioxygen Ligand: The Crystal and Molecular Structure of [K.dibenzo-18-crown6][Al2Me6O2].2C6H6," J. Amer. Chem. Soc., 103, 4277 (1981). 

147. J. L. Atwood, W. E. Hunter, A. H. Cowley, R. A. Jones, and C. A. Stewart, "The 

Solid State Structures of Bis(cyclopentadienyl)tin, Bis(cyclopentadienyl)lead, and 

Bis(pentamethylcyclopentadienyl)lead," J. C. S. Chem. Comm., 925 (1981). 

148. W. J. Evans, A. L. Wayda, W. E. Hunter, and J. L. Atwood, "Heteroleptic tert-Butyl 

Lanthanide Complexes: Synthesis and Structure of Monomeric 

Bis(cyclopentadienyl)(tert-butyl)lutetium Tetrahydrofuranate," J. C. S. Chem. 

Comm., 292 (1981). 

149. F. Calderazzo, D. Vitali, I. P. Mavani, F. Marchetti, I. Bernal, J. D. Korp, J. L. 

Atwood, R. D. Rogers, and M. S. Dalton, "Preparation and Properties and Crystal 

and Molecular Structure of Bis(Sec-Amine) Complexes of Rhenium(I)," J. C. S. 

Dalton Trans., 2523 (1981). 

150. M. F. Lappert, S. J. Miles, J. L. Atwood, M. J. Zaworotko, and A. J. Carty, 

"Oxidative Addition of an Alcohol to the Ge(II) Alkyl Ge[CH(SiMe3)2]2; 

Molecular Structure of Ge[CH(SiMe3)2]2(H)OEt," J. Organometal. Chem., 212, 

C4 (1981). 

151. J. L. Atwood, D. C. Hrncir, R. D. Rogers, and J. A. K. Howard, "Novel Linear AlH-Al Electron-Deficient Bond in Na[(CH3)3Al-H-Al(CH3)3]," J. Amer. Chem. 

Soc., 103, 6787 (1981). 

152. W. J. Evans, A. L. Wayda, W. E. Hunter, and J. L. Atwood, "Organolanthanoid 

Activation of Carbon Monoxide: Single and Multiple Insertion of CO into t-Butyl 

Lanthanoid Bonds; X-ray Crystallographic Identification of a New Bonding Mode 

for a Bridging Enedione Diolate Ligand Formed By Formal Coupling of Four CO 

Molecules," J. C. S. Chem. Comm., 706 (1981). 

153. W. J. Evans, I. Bloom, W. E. Hunter, and J. L. Atwood, "Synthesis and X-ray 

Crystal Structure of a Soluble Divalent Organosamarium Complex," J. Amer. 

Chem. Soc., 103, 6507 (1981). 

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154. J. Jeffrey, M. F. Lappert, N. T. Luong-Thi, M. Webb, J. L. Atwood, and W. E. 

Hunter, "Metallocene Derivatives of Early Transition Metals. Part 4. Chemistry of 

the Complexes [M(h-C5H5)2RR'][M = Ti, Zr, or Hf; R = CH3M'Me3 (M' = C, Si, 

Ge or Sn) or CH(SiMe3)2; R' = Cl or alkyl] and the X-ray Structures of [Zr(hC5H5)2(CH2M'Me3)2] (M' = C or Si)," J. C. S. Dalton Trans., 1593 (1981). 

155. J. L. Atwood, W. E. Hunter, A. L. Wayda, and W. J. Evans, "Synthesis and 

Crystallographic Characterization of a Dimeric Alkynide Bridged 

Organolanthanide: [(C5H5)2ErC∫CC(CH3)3]2," Inorg. Chem., 20, 4115 (1981). 

156. M. F. Lappert, A. Singh, J. L. Atwood, and W. E. Hunter, "Organometallic 

Complexes of the Group 3A and Lanthanoid Metals Containing MCl2Li Bridging 

Units; the X-ray Structure of [Nd(h-Cp")2(m-Cl)2Li(thf)2][Cp" = C5H3(SiMe3)2; 

thf = tetrahydrofuran]," J. C. S. Chem. Comm., 1191 (1981). 

157. M. F. Lappert, A. Singh, J. L. Atwood, and W. E. Hunter, "The Use of the 

Bis(trimethylsilyl)cyclopentadienyl Ligand for Stabilizing Early (f0-f3) 

Lanthanocene Chlorides; X-ray Structure of [(Pr(h-Cp")2Cl)2] [Cp" = 

C5H3(SiMe3)2] and of Isoleptic Scandium and Ytterbium Complexes," J. C. S. 

Chem. Comm., 1190 (1981). 

158. W. Liese, K. Dehnicke, R. D. Rogers, R. Shakir, and J. L. Atwood, "A 

Spectroscopic and Crystallographic Study of the [ReNCl4]- Ion," J. C. S. Dalton 

Trans., 1061 (1981). 

159. J. L. Atwood, D. C. Hrncir, R. Shakir, M. S. Dalton, R. D. Priester, and R. D. 

Rogers, "Reaction of Trimethylaluminum with Crown Ethers. The Synthesis and 

Structure of (Dibenzo-18-crown-6)bis(trimethylaluminum) and of (15-crown5)tetrakis(trimethylaluminum)," Organometallics, 1, 1021 (1982). 

160. M. D. Rausch, D. W. Macomber, W. P. Hart, J. L. Atwood, and R. D. Rogers, "The 

Formation and Molecular Structure of Acetylcyclopentadienylsodium.tetrahydrofuranate," J. Organometal. Chem., 238, 79 (1982). 

161. J. L. Atwood, M. B. Honan, and R. D. Rogers, "Crystal and Molecular Structure of 

(h5-C5H5)Ta (h5-C2H4)Cl2(PMe2Ph)2, a Crowded Molecule which Exhibits a 

Distorted h5-Coordination Mode of the Cyclopentadienyl Ligand," J. Cryst. Spec. 

Res, 12, 205 (1982). 

162. M. J. Zaworotko, R. D. Rogers, and J. L. Atwood, "Interaction of 

Trimethylaluminum and Trimethylgallium with the Acetate Ion. Synthesis and 

Crystal Structures of [N(CH3)4][Al2(CH3)6CH3COO] and 

Rb[Ga2(CH3)6CH3COO]," Organometallics, 1, 1179 (1982). 

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163. M. J. Zaworotko, R. Shakir, J. L. Atwood, V. Sriyunyongwat, S. D. Reynolds, and 

T. A. Albright, "Synthesis and Structure of Dicarbonyl(h5-methylcyclopentadienyl)triphenylphosphinemanganese(I)," Acta Crystallogr., B38, 1572 

(1982). 

164. J. L. Atwood, A. H. Cowley, W. E. Hunter, and S. K. Mehrotra, "The Crystal and 

Molecular Structure of Sulfamide (t-BuNH)2SO2," Inorg. Chem., 21, 435 (1982). 

165. K. A. Beveridge, G. W. Bushnell, K. R. Dixon, D. T. Eadie, S. R. Stobart, M. J. 

Zaworotko, and J. L. Atwood, "Pyrazolyl-bridged Iridium Dimers. 1. 

Accommodation of Both Weak and Strong Metal-Metal Interactions by a Bridging 

Pyrazolyl Framework in Dissymetric Dimeric Structures," J. Amer. Chem. Soc., 

104, 920 (1982). 

166. A. W. Coleman, D. T. Eadie, S. R. Stobart, M. J. Zaworotko, and J. L. Atwood, 

"Pyrazolyl-bridged Iridium Dimers. 2. Contrasting Modes of Two-Center 

Oxidative Addition to a Bimetallic System and Reductive Access to the Starting 

Complex: Three Key Di-iridium Structures Representing Short Non-bonding and 

Long and Short Bonding Metal-Metal Interactions," J. Amer. Chem. Soc., 104, 922 

(1982). 

167. W. J. Evans, J. H. Meadows, A. L. Wayda, W. E. Hunter, and J. L. Atwood, 

"Organolanthanide Hydride Chemistry. 1. Synthesis and X-ray Crystallographic 

Characterization of Dimeric Organolanthanide and Organoyttrium Hydride 

Complexes," J. Amer. Chem. Soc., 104, 2008 (1982). 

168. W. J. Evans, J. H. Meadows, A. L. Wayda, W. E. Hunter, and J. L. Atwood, 

"Organolanthanide Hydride Chemistry. 2. Synthesis and X-ray Crystallographic 

Characterization of Trimetallic Organolanthanide Polyhydride Complex," J. 

Amer. Chem. Soc., 104, 2015 (1982). 

169. D. F. Foust, R. D. Rogers, M. D. Rausch, and J. L. Atwood, "Photo-induced 

Reactions of (h5-C5H5)2MH3, (h5-C5H5)2M(CO)H (M = Nb, Ta), and the 

Molecular Structure of (h5-C5H5)2Ta(CO)H," J. Amer. Chem. Soc., 104, 5646 

(1982). 

170. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "Synthesis and Crystal Structure of 

[(h5-C5H5)2HfO]3.C6H5Me," J. Cryst. Spec. Res., 12, 239 (1982). 

171. E. Carmona, J. M. Marin, M. L. Poveda, J. L. Atwood, R. D. Rogers, and G. 

Wilkinson, "Bis-dinitrogen and Diethylene Complexes of Molybdenum(0)," Angew. 

Chem., 21, 441 (1982). 

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172. J. L. Atwood, A. H. Cowley, W. E. Hunter, and S. K. Mehrotra, "Pyrrolyl 

Compounds of Main-Group Elements. 1. Synthesis of (h1-C4H4N)3As and Crystal 

and Molecular Structures of (h1-C4H4N)3As," Inorg. Chem., 21, 1354 (1982). 

173. M. D. Rausch, B. H. Edwards, J. L. Atwood, and R. D. Rogers, "Formation and 

Molecular Structure of (h4-Tetraphenylcyclobutadiene)dicarbonylnitrosylmanganese)," Organometallics, 1, 1567 (1982). 

174. R. A. Jones, A. L. Stuart, J. L. Atwood, W. E. Hunter, and R. D. Rogers, "Steric 

Effects of Phosphido Ligands. Synthesis and Crystal Structure of Di-tertbutylphosphido-Bridged Dinuclear Metal-Metal Bonded Complexes of Fe(II), 

Co(I,II), and Ni(I)," Organometallics, 1, 1721 (1982). 

175. R. D. Holmes-Smith, S. R. Stobart, J. L. Atwood, and W. E. Hunter, "Transitionmetal Silacyclohexyl Derivatives. Crystal and Molecular Structure of Carbonyl(hcyclopentadienyl)(1-phenyl-1-silacyclohex-1-yl)(triphenylphosphine)iron(II)," 

J. C. S. Dalton Trans., 2461 (1982). 

176. G. Erker, K. Engel, U. Dorf, J. L. Atwood, and W. E. Hunter, "The Reaction of 

(Butadiene)zirconocene and -hafnocene with Ethylene," Agnew. Chem. Int. Ed. 

Engl., 21, 914 (1982). 

177. E. Carmona, J. M. Marin, M. L. Poveda, R. D. Rogers, and J. L. Atwood, 

"Preparation and Properties of Dinitrogen Complexes of Molybdenum and 

Tungsten with Trimethylphosphine as Coligand. III. Synthesis and Properties of 

cis-[W(N2)2(PMe3)4], trans-[W(C2H4)2(PMe3)4] and [M(N2)(PMe3)5](M = Mo, 

W). The Crystal and Molecular Structure of [Mo(N2)(PMe3)5]," J. Organometal. 

Chem., 238, C63 (1982). 

178. W. E. Hunter, D. C. Hrncir, R. V. Bynum, R. A. Penttila, and J. L. Atwood, "The 

Search for Dimethylzirconocene: Crystal Structures of Dimethylzirconocene, 

Dimethylhafnocene, Chloromethylzirconocene, and m-Oxobis(methylzirconocene)," Organometallics, 2, 750 (1983). 

179. J. L. Atwood, D. C. Hrncir, R. D. Priester, and R. D. Rogers, "Decomposition of 

High-Oxygen Content Organoaluminum Compounds. The Formation and Structure 

of the [Al7O6Me16]- Anion," Organometallics, 2, 985 (1983). 

180. G. Erker, K. Kropp, J. L. Atwood, and W. E. Hunter, "Reactions of 

Vinylzirconocene Complexes with a Zirconiumhydride-the Unexpected Formation 

of m-(b-h1:a-b-h2-Styryl)-m-chlorobisbis-Zirconocene Complex,"

Organometallics, 2, 1555 (1983). 

181. J. L. Atwood, W. E. Hunter, R. A. Jones, and T. C. Wright, "Reversible Metalmetal Bond Cleavage Accompanied by a Geometrical Isomerism. Synthesis and 

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Crystal Structures of Isomers of [Rh(m-tBu2P)(CO)2]2. Catalysis of Alkene 

Hydroformylation," Organometallics, 2, 470 (1983). 

182. R. A. Jones, A. L. Stuart, J. L. Atwood, and W. E. Hunter, "Structure of 

Chlorotristrimethylphosphinecobalt(I), C9H27ClCoP3," J. Cryst. Spec. Res., 13, 

273 (1983). 

183. J. L. Atwood, W. E. Hunter, H.-M. Zhang, M. F. Lappert, and A. Singh, "Synthesis 

and Characterization of Stable Anionic Structure of [AsPh4][Nd{hC5H3(SiMe3)2}2Cl2]." J. C. S. Chem. Comm., 69 (1983). 

184. W. J. Evans, I. Bloom, W. E. Hunter, and J. L. Atwood, "Organolanthanide Hydride 

Chemistry. 3. Reactivity of Low Valent Samarium with Unsaturated 

Hydrocarbons Leading to a Structurally Characterized Samarium Hydride 

Complex," J. Amer. Chem. Soc., 105, 1401 (1983). 

185. W. J. Evans, I. Bloom, W. E. Hunter, and J. L. Atwood "Synthesis of 

Organosamarium Complexes Containing Sm-C and Sm-P Bonds. Crystallographic 

Characterization of [(CH3C5H4)2SmC∫CC(CH3)3]2," Organometallics, 2, 709 

(1983). 

186. J. L. Atwood, K. R. Dixon, D. T. Eadie, S. R. Stobart, and M. J. Zaworotko, 

"Crystal and Molecular Structures of Tetrafluoroborate Salts of the cisChlorobis(triethylphosphine)(3-trifluoromethyl,5-methylpyrazole)platinum (II) and 

cis-Chlorobis(triethylphosphine)(indazole)platinum(II) Cations," Inorg. Chem., 22, 

774 (1983). 

187. M. D. Rausch, B. H. Edwards, R. D. Rogers, and J. L. Atwood, "The Formation of 

Diphenylphosphinocyclopentadienylthallium, and Its Utility in the Synthesis of 

Heterobimetallic Ti-Mn Complexes: The Molecular Structure of (h5-

cyclopentdienyl)(h5-cyclopentadienyl)(h5-diphenylphosphincyclopentadienyl) 

dichlorotitanium-[P]manganese," J. Amer. Chem. Soc., 105, 3882 (1983). 

188. J. L. Atwood, R. D. Priester, R. D. Rogers, and L. G. Canada, "Reaction of 

Trimethylaluminum with Crown Ethers. II. The Synthesis and Structure of 

(Dibenzo-18-crown-6)tris(trimethylaluminum) and of (18-crown-6)tetrakis- 

(trimethylaluminum)," J. Incl. Phenomena, 1, 61 (1983). 

189. E. Carmona, J. M. Marin, M. L. Poveda, J. L. Atwood, and R. D. Rogers, 

"Preparation and Properties of Dinitrogen Trimethylphosphine Complexes of 

Molybdenum and Tungsten. 4. Synthesis, Chemical Properties and X-ray Structure 

of cis-[Mo(N2)2(PMe3)4]. The Crystal and Molecular Structures of trans-

[Mo(C2H4)2(PMe3)4] and trans, mer-[Mo(C2H4)2(CO)(PMe3)3]," J. Amer. 

Chem. Soc., 105, 3014 (1983). 

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190. E. Carmona, L. Sanchez, M. L. Poveda, J. M. Marin, J. L. Atwood, and R. D. 

Rogers, "b-C-H Interaction versus Dihaptoacyl Coordination in a Molybdenum 

Acetyl Complex. X-ray Crystal Structure of [Mo(COCH3)(S2CNMe2)- 

(CO)(PMe3)2]," J. C. S. Chem. Comm., 161 (1983). 

191. R. B. Hallock, O. T Beachley, Jr., W. E. Hunter, and J L. Atwood, "A Reexamination of the Product from the Ga(CH2SiMe3)3 - KH Reaction: 

KGa(CH2SiMe3)3H," Inorg. Chem., 22, 3683 (1983). 

192. B. H. Edwards, R. D. Rogers, D. J. Sikora, J. L. Atwood, and M. D. Rausch, 

"Formation, Reactivities, and Molecular Structure of Phosphine Derivatives of 

Titanocene. Isolation and Characterization of a Titanium Monoolefin p Complex," 

J. Amer. Chem. Soc., 105, 416 (1983). 

193. M. F. Lappert, M. J. Slade, A. Singh, J. L. Atwood, R. D. Rogers, and R. Shakir, 

"Structure and Reactivity of Sterically Hindered Lithium Amides and Their Diethyl 

Etherates; Crystal and Molecular Structures of [LiN(SiMe3)2(OEt2)]2 and 

[Li(NCMe2CH2CH2CH2CMe2)]4," J. Amer. Chem. Soc., 105, 302 (1983). 

194. W. J. Evans, J. H. Meadows, W. E. Hunter, and J. L. Atwood, "Organolanthanide 

and Organoyttrium Hydride Chemistry. 4. Reaction of Isocyanides with 

[(C5H4R)2Yb(THF)]2 to Form a Structurally Characterized N-Alkyl Forminidoyl 

Complex," Organometallics, 2, 1252 (1983). 

195. J. L. Atwood and M. J. Zaworotko, "The Formation and Structure of the Novel 

Aluminoxane Anion [Me2AlO.AlMe3]2," J. C. S. Chem. Comm., 302 (1983). 

196. M. F. Lappert, A. Singh, J. L. Atwood, and W. E. Hunter, "Metallocene(III) 

Tetrahydroborates of the Group 3a Elements and the X-ray Structure of 

[Sc(C5H3(SiMe3)2)2(H2)BH2]," J. C. S. Chem. Comm., 206 (1983). 

197. R. A. Jones, A. L. Stuart, J. L. Atwood, and W. E. Hunter, "Substitution Reactions 

of Bis-tertbutylphosphido Complexes of Nickel(I). Crystal Structures of 

Ni2(tBu2P)2(CO)2(PMe3), (Ni-Ni) and Ni2(tBu2P)2(CO)3, (Ni-Ni)," 

Organometallics, 2, 874 (1983). 

198. J. L. Atwood, I. Bernal, F. Calderazzo, L. G. Canada, R. Poli, R. D. Rogers, C. A. 

Veracini, and D. Vitali, "Studies on Organometallic Hetero-Multiple-Bridged 

Molecules. 8. Preparation and Crystal and Molecular Structures of Diphenyl 

Dichalcogenide Complexes of Manganese (I). Kinetic, Spectroscopic and 

Equilibrium Data: A Quantitative Assessment of the Solid-State and Solution 

Properties Within Members of Homogeneous Families of Chalcogenide LowValent Metal Complexes," Inorg. Chem., 22, 1797 (1983). 

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199. E. Carmona, J. M. Marin, M. L. Poveda, J. L. Atwood, and R. D. Rogers, 

"Preparation and Properties of Dinitrogentrimethylphosphine Complexes of 

Molybdenum and Tungsten. II. Synthesis and Crystal Structures of 

[MCl(N2)(PMe3)4] (M = Mo, W) and trans-[MoCl2(PMe3)4], Polyhedron, 2, 185 

(1983). 

200. A. H. Cowley, J. E. Kilduff, N. C. Norman, M. Pakulski, J. L. Atwood, and W. E. 

Hunter, "Electrophilic Additions to Diphosphenes (RP=PR)," J. Amer. Chem. Soc., 

105, 4845 (1983). 

201. D. L. Reger, K. A. Belmore, J. L. Atwood, and W. E. Hunter, "Cis Addition of 

Hydride to h5-Ring. Crystal and Molecular Structure of (h5-C5H5)FeCO(PPh3)(EC(CO2Et)=C(H)Me)." J. Amer. Chem. Soc., 105, 5743 (1983). 

202. A. H. Cowley, R. A. Jones, C. A. Stewart, A. L. Stuart, J. L. Atwood, W. E. Hunter, 

and H.-M. Zhang, "Synthesis and Structure of an h5-Phosphaalkene Nickel 

Complex," J. Amer. Chem. Soc., 105, 3737 (1983). 

203. E. Carmona, F. Gonzalez, M. L. Poveda, J. M. Marin, J. L. Atwood, and R. D. 

Rogers, "Reaction of cis-[Mo(N2)2(PMe3)4] with CO2. Synthesis and 

Characterization of Products of Disproportionation and the X-ray Structure of a 

Tetrametallic Mixed-Valence MoII-MoV Carbonate with a Novel Mode of 

Carbonate Binding," J. Amer. Chem. Soc., 105, 3365 (1983). 

204. R. A. Jones, M. H. Seeberger, J. L. Atwood, and W. E. Hunter, 

"Diazasilametallacycles: Crystal and Molecular Structure of 

Ti(NBuSiMe2NBu)Cl2," J. Organometal. Chem., 247, 1 (1983). 

205. E. Carmona, J. M. Marin, M. L. Poveda, L. Sanchez, R. D. Rogers, and J. L. 

Atwood, "Synthesis of Chloro(trimethylphosphine)tris(trimethylsilylmethyl)- 

tungsten(IV); Synthesis and Molecular Structure of Di-m-chloro-bis[dicarbonyl- 

(trimethylphosphine)(1-2-h-trimethylsilylmethyl-carbonyl)tungsten(II)]," J. Chem. 

Soc. Dalton Trans., 1003 (1983). 

206. R. D. Rogers and J. L. Atwood, "The Crystal and Molecular Structure of 

SnBr[N(SiMe3)2]3," J. Cryst. Spec. Res., 13, 1 (1983). 

207. R. A. Jones, N. C. Norman, M. H. Seeberger, J. L. Atwood, and W. E. Hunter, 

"Synthesis and X-ray Crystal Structures of [M(m-(tBu)(H)P)(PMe3)2]2, M = Rh, 

Ni, Containing Rh=Rh Double and Ni-Ni Single Bonds, Organometallics, 2, 1629 

(1983). 

208. W. A. Herrmann, J. Plank, J. L. Hubbard, G. W. Kriechbaum, W. Kalcher, B. 

Koumbouris, G. Ihl, A. Schafer, M. L. Ziegler, H. Pfisterer, C. Pahl, J. L. Atwood, 

and R. D. Rogers, "Transition Metal Methylene Complexes. LI. Carbocyclic 

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Carbenes, Carbene Bridges, Small Hydrocarbon Ligands, and Metallacycles: 

Examples of a General Synthetic Concept," Z. Naturforsch., 38b, 1392 (1983). 

209. J. L. Atwood, D. C. Hrncir, and R. D. Rogers, "The Use of Crown Ethers to Access 

New M[Al2R6X] Species. Synthesis and Crystal Structure of [K.dibenzo-18-

crown-6][Al2Me6Cl].2C6H6," J. Incl. Phenom., 1, 199 (1983). 

210. R. A. Jones, A. L. Stuart, J. L. Atwood, and W. E. Hunter, "Synthesis of Di-tertbutylphosphido-Bridged Dimers of Cobalt (I) Containing Cobalt-Cobalt Double 

Bonds. Crystal Structures of [Co(m-t-Bu2P)(CO)2]2 and [Co(m-tBu2P)(PMe3)L]2 (L = CO or N2)," Organometallics, 2, 1437 (1983). 

211. K. A. Beveridge, G. W. Bushnell, S. R. Stobart, J. L. Atwood, and W. E. Hunter, 

"Pyrazolyl-Bridged Iridium Dimers. 4. Crystal and Molecular Structures of 

Bis(cycloocta-1,5-diene)bis(m-pyrazolyl)diiridium(I), Its Dirhodium(I) Isomorph, 

and Two Bis(cycloocta-1,5-diene)diiridium(I) Analogues Incorporating 3.5-

Disubstituted m-Pyrazolyl Ligands," Organometallics, 2, 1447 (1983). 

212. J. L. Atwood, D. E. Berry, S. R. Stobart, and M. J. Zaworotko, "Aspects of 

Organocadmium Chemistry. Part 3. Cyclometallated Alkyls and Aryls of Zn, Cd, 

and Hg and the Crystal and Molecular Structure of Bis[(o-N,Ndimethylaminomethyl)phenyl]mercury(II)," Inorg. Chem., 22, 3480 (1983). 

213. J. L. Atwood, W. E. Hunter, R. A. Jones, and T. C. Wright, "Synthesis and X-ray 

Crystal Structure of Tris(bis-tertbutylphosphido)tricarbonyltrirhodium(I)," Inorg. 

Chem., 22, 993 (1983). 

214. F. Calderazzo, R. Poli, D. Vitali, J. D. Korp, I. Bernal, G. Pelizzi, J. L. Atwood, and 

W. E. Hunter, "Studies on Organometallic Hetero-Multiple-Bridged (HMB) 

Molecules. IX. Synthesis and Crystal and Molecular Structure of 

Mn2X2(CO)6P2Ph4 (X = Br, I) and Mn2Br2(CO)6As2Ph4, the Products Arising 

from Co-ordinative Addition of P2Ph4 and As2Ph4 to Manganese(I)." Gazz. Chim. 

Ital., 113, 761 (1983). 

215. G. Erker, K. Engel, J. L. Atwood, and W. E. Hunter, "The Zirconocene-Induced 

Coupling of Butadiene with Carbonyl Compounds," Angew. Chem. Int. Ed. Engl., 

22, 494 (1983). 

216. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "The Crystal Structure of 

LiBr.(CH3OCH2CH2OCH3)2," J. Cryst. Spec. Res., 14, 29 (1984). 

217. R. D. Rogers and J. L. Atwood, "Reaction of K2SO4 with AlMe3 and the Crystal 

Structures of K2[Al4Me12SO4] with K2[Al4Me12SO4].0.5p-Xylene," 

Organometallics, 3, 271 (1984). 

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218. G. S. Bristow, M. F. Lappert, T. R. Martin, J. L. Atwood, and W. E. Hunter, 

"Metallocyclopentenes. Part 2. The Preparation of o-Xylidene Derivatives of Ti, 

Zr, Hf, or Nb; the Crystal and Molecular Structures of [M(h-C5H4R)2(p-

(CH2)2C6H4)] (R = H, M = Ti, Zr or Hf; R = SiMe3, M = Nb)," J. C. S. Dalton 

Trams., 399 (1984). 

219. R. D. Rogers, R. V. Bynum, and J. L. Atwood, "Synthesis and Crystal Structure of 

(h5-C5H5)2Hf(h1-NC4H4)2," J. Cryst. Spec. Res., 14, 21 (1984). 

220. R. D. Rogers and J. L. Atwood, "The Crystal and Molecular Structure of [K.DB-18-

C-6][AlMe3NO3].3C6H6," J. Cryst. Spec. Res., 14, 1 (1984). 

221. R. A. Jones, B. R. Whittlesey, J. L. Atwood, and W. E. Hunter, "Synthesis and Xray Crystal Structure of OsBr2(CNtBu)4.2CH2Cl2," Polyhedron, 3, 385 (1984). 

222. R. D. Rogers, J. L. Atwood, T. A. Albright, W. A. Lee, and M. D. Rausch, "The 

Structure of Biphenylene- and Triphenylene-Cr(CO)3. An Analysis of the Bonding 

of Cr(CO)3 to Bicyclic Polyenes," Organometallics, 3, 263 (1984). 

223. R. D. Rogers, J. C. Baker, and J. L. Atwood, "The Crystal Structure of 

[NBu4][AlI4]," J. Cryst. Spec. Res., 14, 334 (1984). 

224. J. L. Atwood, A. D. McMaster, R. D. Rogers, and S. R. Stobart, "Stereochemically 

Non-rigid Silanes, Germanes, and Stannanes. 12. Crystal and Molecular Structures 

Tetra(h1-indenyl) Derivatives of Germanium and Tin: meso Diastereoisomers with 

S4 Symmetry," Organometallics, 3, 1500 (1984). 

225. G. Erker, W. Fromberg, J. L. Atwood, and W. E. Hunter, "Hydrozirconation of 

Nitriles: Proof of a Linear Heteroallene Structure in (Benzylideneamido)- 

zirconocene Chloride," Angew. Chem. Int. Ed. Engl., 23, 68 (1984). 

226. J. L. Atwood, T. Fjeldberg, M. F. Lappert, N. T. Luong-Thi, R. Shakir, and A. J. 

Thorne, "Molecular Structures of Bis(trimethylsilylmethyl)lithium (LiR)n, R = 

[CH(SiMe3)2] in the Vapour (Gas-phase Electron Diffraction: a Monomer, n = 1) 

and the Crystal (X-ray: a Polymer, n = •)," J. Chem. Soc. Chem. Commun., 1163 

(1984). 

227. A. H. Cowley, R. A. Jones, J. G. Lasch, N. C. Norman, C. A. Stuart, J. L. Atwood, 

W. E. Hunter, and H.-M. Zhang, "Synthesis and Structures of Free and Coordinated 

Phosphaalkenes," J. Amer. Chem. Soc., 106, 7015 (1984). 

228. A. L. Wayda, J. L. Atwood, and W. E. Hunter, "Homoleptic Organolathanoid 

Hydrocarbyls. The Synthesis and X-ray Crystal Structure of Tris(ortho-N,Ndimethylaminomethylphenyl)lutetium," Organometallics, 3, 939 (1984). 

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229. E. Carmona, M. Paneque, M. L. Poveda, R. D. Rogers, and J. L. Atwood, "Further 

Studies on Organonickel Compounds: the Synthesis of some New Alkyl-, Acyland Cyclopentadienyl-Derivatives and the Crystal Structure of trans-

[Ni(CH2SiMe3)2(PMe3)2]," Polyhedron, 3, 317 (1984). 

230. C. M. Means, N. C. Means, S. G. Bott, and J. L. Atwood, "How Short is a Bond of 

Order Zero? A Close Cs...Cs Contact in the [Cs2(18-crown-6)]2+ Cation," J. Am. 

Chem. Soc., 106, 7627 (1984). 

231. J. L. Atwood, R. D. Rogers, and R. V. Bynum, "Tris(1,2-dimethoxyethane)lithium 

 m-Chloro-m-oxo-bis[chloro(pentamethylcyclopentadienyl)(1-pyrrolyl)zirconate(IV)] Dimethoxyethane solvate, [Li(C4H10O2)3][Zr2Cl3O(C4H4N)2-

(C10H15)2].C4H10O2," Acta Crystallogr. C40, 1812 (1984). 

232. J. L. Atwood, K. A. Beveridge, G. W. Bushnell, K. R. Dixon, D. T. Eadie, S. R. 

Stobart, and M. J. Zaworotko, "Pyrazolyl-Bridged Iridium Dimers. 4. Two 

Fragment, Two Center Oxidative Addition of Halogens and Methyl Halides to 

trans-Bis(triphenylphosphine)dicarbonyldi(m-pyrazolato)diiridium(I)." Inorg. 

Chem., 23, 4050 (1984). 

233. E. Samuel, R. D. Rogers, and J. L. Atwood, "Synthesis and Crystal Structure of 

[(h5-C9H11)TiCl(m-O)]4," J. Cryst. Spec. Res., 14, 573, (1984). 

234. W. J. Evans, J. H. Meadows, W. E. Hunter, and J. L. Atwood, "Organolanthanide 

and Organoyttrium Hydride Chemistry. 5. Improved Synthesis of 

[C5H4R)2YH(THF)]2 Complexes and Their Reactivity With Alkenes, Alkynes, 

1,2-Propadiene, Nitriles, and Pyridine, Including Structural Characterization of an 

Alkylideneamido Product," J. Amer. Chem. Soc., 106, 1291 (1984). 

235. A. H. Cowley, J. E. Kilduff, J. G. Lasch, S. K. Mehrotra, N. C. Norman, M. 

Pakulski, B. R. Whittlesey, J. L. Atwood, and W. E. Hunter, "Synthesis and 

Structures of Compounds Containing Double Bonds Between the Heavier Group 

VA Elements: Diphosphenes, Diarsenes, Phosphaarsenes, and Phosphastibenes," 

Inorg. Chem., 23, 2582 (1984). 

236. W. A. Herrmann, J. Plank, G. W. Kriechbaum, M. L. Ziegler, H. Pfisterer, J. L. 

Atwood, and R. D. Rogers, "Komplexchemie reaktiver organischer Verbindungen. 

XLVII. Synthese, Strukturchemie und Druckcarbonylierung von MetallcarbenKomplexen," J. Organometal. Chem., 264, 327 (1984). 

237. M. D. Rausch, D. F. Foust, R. D. Rogers, and J. L. Atwood, "The Formation and 

Molecular Structure of Bis(h5-cyclopentadienyl)(2-[(dimethylamino)methyl]- 

phenyl-C,N)yttrium." J. Organometal. Chem., 265, 241 (1984). 

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238. R. D. Rogers, E. Carmona, A. Galindo, J. L. Atwood, and L. G. Canada, 

"Trimethylphosphine Complexes of Molybdenum and Tungsten. The Synthesis and 

Chemical Properties of MoCl4(PMe3)3 and MoO(acac)2PMe3." J. Organometal. 

Chem., 277, 403 (1984). 

239. E. Carmona, L. Sanchez, J. M. Marin, M. L. Poveda, J. L. Atwood, R. D. Priester, 

and R. D. Rogers, "h2-Acyl Coordination and b-C-H Interaction in Acyl Complexes 

of Molybdenum. Crystal and Molecular Structures of Mo(h2-

COCH2SiMe3)Cl(CO)(PMe3)3 and Mo(COCH3)(S2CNMe2)(CO)(PMe3)2," J. 

Amer. Chem. Soc., 106, 3214 (1984). 

240. J. L. Atwood, "Liquid Clathrates," in "Inclusion Compounds," Vol. 1, Eds., J. L. 

Atwood, J. E. D. Davies, and D. D. MacNicol, Academic Press, London, 1984, pp. 

375-405. 

241. J. L. Atwood, "New Inclusion Methods for Separations Problems," Sep. Sci. Tech., 

19, 751 (1984). 

242. J. L. Atwood, H. Elgamal, G. H. Robinson, S. G. Bott, J. A. Weeks, and W. E. 

Hunter, "From Crown Ethers to Zeolites: Reaction of EtAlCl2 with Crown Ethers," 

J. Incl. Phenom., 2, 367 (1984). 

243. J. L. Atwood, "The Interaction of Alkali Metal Cations with Aromatic Molecules in 

Complexes of the Type M[AlMe3X].aromatic, M[Al2Me6X].aromatic, and 

Related," J. Incl. Phenom., 3, 13 (1985). 

244. W. J. Evans, I. Bloom, W. E. Hunter, and J. L. Atwood, "Metal Vapor Synthesis of 

(C5Me5)2Sm(THF)2 and (C5Me4Et)2Sm(THF)2 and Their Reactivity with 

Organomercurial Reagents. Synthesis and X-ray Structural Analysis of 

(C5Me5)2Sm(C6H5)(THF)," Organometallics, 4, 112 (1985). 

245. H. Zhang, C. M. Means, N. C. Means, and J. L. Atwood, "Reaction of 

Trimethylaluminum with Crown Ethers. IV. Crystal Structure of (18-Crown6)Tetrakis(trimethylaluminum).p-xylene Solvate," J. Cryst. Spec. Res., 15, 445 

(1985). 

246. W. J. Evans, J. W. Grate, I. Bloom, W. E. Hunter, and J. L. Atwood, "Reactivity of 

(C5Me5)2Sm(THF)2 with Oxygen Containing Substrates: Synthesis and X-ray 

Crystallographic Characterization of an Oxo-bridged Bimetallic Organosamarium 

Complex, [(C5Me5)2Sm]2(m-O)," J. Am. Chem. Soc., 107, 405 (1985). 

247. H. D. H. Showalter, E. M. Berman, J. L. Johnson, J. L. Atwood and W. E. Hunter, 

"A Facile Synthesis of Functionalized 9,10-Anthracenediones via Tosylate and 

Triflate Phenolic Activation," Tetrahedron Letters, 26, 157 (1985). 

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248. G. H. Robinson, S. G. Bott, H. Elgamal, W. E. Hunter, and J. L. Atwood, "Reaction 

of Trimethylaluminum with Crown Ethers. III. The Synthesis and Crystal 

Structure of (12-crown-4)-bis(trimethylaluminum)," J. Incl. Phenom., 3, 65 (1985). 

249. W. J. Evans, T. T. Peterson, M. D. Rausch, W. E. Hunter, and J. L. Atwood, 

"Synthesis and X-ray Crystallographic Characterization of an Asymmetric 

Organoyttrium Hallide Dimer: (C5Me5)2Y[(m-Cl)YCl(C5Me5)2]," 

Organometallics, 4, 554 (1985). 

250. R. B. Hallock, W. E. Hunter, J. L. Atwood, and O. T. Beachley, "Synthesis and 

Structural Study of Ga(CH2SiMe3)3. Me2NC2H4NMe2.Ga(CH2SiMe3)3," 

Organometallics, 4, 547 (1985). 

251. M. J. Zaworotko, C. R. Kerr, and J. L. Atwood, "Reaction of the Phenoxide Ion 

with Trimethylaluminum. Isolation and Crystal Structure of [K.dibenzo-18-crown6][Al2Me6OPh] and K[AlMe3(OPh)2]," Organometallics, 4, 238 (1985). 

252. W. J. Evans, J. W. Grate, H. W. Choi, I. Bloom, W. E. Hunter, and J. L. Atwood, 

"Solution Synthesis and Crystallographic Characterization of the Divalent 

Organosamarium Complexes [(C5Me5)SmI(THF)2]2," J. Amer. Chem. Soc., 107, 

941 (1985). 

253. J. H. Medley, F. R. Fronczek, N. Ahmad, M. C. Day, R. D. Rogers, C. R. Kerr, and 

J. L. Atwood, "The Crystal Structures of NaAlR4, R = Methyl, Ethyl, and nPropyl," J. Cryst. Spec. Res., 15, 99 (1985). 

254 O. T. Beachley, T. D. Getman, R. U. Kirss, R. B. Hallock, W. E. Hunter, and J. L. 

Atwood, "Preparation and Properties of Cyclopentadienylgallium(III) Compounds," 

Organometallics, 4, 751 (1985). 

255. A. H. Cowley, S. K. Mehrotra, W. E. Hunter, and J. L. Atwood, "Synthesis and 

Crystal Structure of the Bis(cyclopentadienyl)gallium Ethoxide Dimer," 

Organometallics, 4, 1115 (1985). 

256. J. L. Atwood, W. E. Hunter, R. D. Rogers, and J. A. Weeks, "Behavior of 

M[Al2Me6N3](M = K, Rb, Cs) with Aromatic Solvents and the Crystal Structures 

Two Related Complexes," J. Incl. Phenom., 3, 113 (1985). 

257. W. J. Evans, J. W. Grate, L. A. Hughes, H. Zhang, and J. L. Atwood, "Reductive 

Homologation of CO to a Ketenecarboxylate by a Low Valent Organolanthanide 

Complex: Synthesis and X-ray Crystal Structure of 

[(C5Me5)4Sm2(OCCCO2)(THF)]2," J. Amer. Chem. Soc., 107, 3728 (1985). 

258. M. J. Zaworotko, R. J. Stamps, M. T. Ledet, H. Zhang, and J. L. Atwood, 

"Heterocyclophane Complexes of Transition Metals. 1. Synthesis and Crystal 

Structure of Both the h5- and the h6-[2.2](2,5)PyrroloparacyclophanetriCase 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 48 of 90 PageID: 4311
carbonylchromium," Organometallics, 4, 1697 (1985). 

259. S. G. Bott, H. Elgamal, and J. L. Atwood, "Seven-Coordinate Aluminum in 

[AlCl2.benzo-15-crown-5][AlCl3Et]," J. Amer. Chem. Soc., 107, 1796 (1985). 

260. J. L. Atwood, S. G. Bott, C. Eaborn, M. N. El-Kheli, and J. D. Smith, "The Crystal 

and Molecular Structure of Fluoro(hydroxy){tris(dimethylphenylsilyl)- 

methyl}borane," J. Organometal. Chem., 294, 23 (1985). 

261. O. T. Beachley, Jr., R. B. Hallock, H. Zhang, and J. L. Atwood, "Synthesis, 

Characterizations and Crystal and Molecular Structures of 

Pentamethylcyclopentadienyl Gallium Chloride Compounds, Ga(C5Me5)2Cl and 

Ga(C5Me5)Cl2," Organometallics, 4, 1675 (1985). 

262. S. P. McManus, J. A. Knight, E. J. Meehan, R. A. Abramovitch, M. N. Offor, J. L. 

Atwood, and W. E. Hunter, "Ferrocenesulfonyl Azide: Structure and Kinetics of 

Solution Thermolysis," J. Org. Chem., 50, 2742 (1985). 

263. M. J. Wovkulich, J. L. Atwood, L. Canada, and J. D. Atwood, "A Crystallographic 

Determination of the Influence of the Trans Ligand on the Bonding of 

Triphenylphosphine. Crystal and Molecular Structures of Cr(CO)4(PPh3)L (L = 

PBu3, P(OMe)3, and P(OPh)3)," Organometallics, 4, 867 (1985). 

264. W. J. Evans, I. Bloom, J. W. Grate, L. A. Hughes, W. E. Hunter, and J. L. Atwood, 

"Synthesis and Characterization of the Samarium-Cobalt Complexes 

(C5Me5)2(THF)SmCo(CO)4 and [SmI2(THF)5][Co(CO)4]: X-ray Crystal 

Structure of a Seven-Coordinate Samarium(III) Cation Complex," Inorg. Chem., 24, 

4620 (1985). 

265. D. R. Corbin, J. L. Atwood, and G. D. Stucky, "Hydrogenation of Unsaturated 

Dicarboxylic Acids by Dicarbonylbis(h5-cyclopentadienyl)titanium(II) and the 

Molecular Structure of m-Acetylenedicarboxylatobis[bis(h5-methylcyclopentadienyl)titanium(III)]," Inorg. Chem., 25, 98 (1986). 

266. R. V. Bynum, H.-M. Zhang, W. E. Hunter, and J. L. Atwood, "Pyrrolyl Complexes 

of the Early Transition Metals. 3. Preparation and Crystal Structure of (h5-

C5H5)2Zr-(h1-NC4H2Me2)2 and Zr(h1-NC4H2Me2)4," Can. J. Chem., 64, 1304 

(1986). 

267. G. Erker, U. Dorf, J. L. Atwood, and W. E. Hunter, "The Metallaoxirane Type 

Structure of Cp2ZrCl(CPh2OCH3) and the Question of Modeling the Chemistry of 

Alkylidene Units on a Metal Oxide Surface," J. Amer. Chem. Soc., 108, 2251 

(1986). 

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268. S. G. Bott, A. W. Coleman, and J. L. Atwood, "Preparation and Structure of the 

First Complex of an Early Transition Metal and a Calixarene, 

Calix[6]arene[TiCl2(m-O)TiCl3]2," J. Chem. Soc., Chem. Commun., 610 (1986). 

269. S. G. Bott, A. W. Coleman, and J. L. Atwood, "Inclusion of both Cation and 

Neutral Molecule by a Calixarene. Structure of the [p-tertButylmethoxycalix[4]arene.Na.toluene]+ Cation," J. Amer. Chem. Soc., 108, 1709 

(1986). 

270. W. J. Evans, L. A. Hughes, D. K. Drummond, H. Zhang, and J. L. Atwood, "Facile 

Stereospecific Synthesis of a Dihydroxyindenoindene Unit from an Alkyne and CO 

Via Samarium-mediated CO and CH Activation," J. Amer. Chem. Soc., 108, 1722 

(1986). 

271. M. D. Rausch, K. J. Moriarty, J. L. Atwood, J. A. Weeks, W. E. Hunter, and H. G. 

Brittian, "Synthetic, X-ray Structural and Luminescence Studies on 

Pentamethylcyclopentadienyl Derivatives of Lanthanum, Cerium and 

Praseodymium," Organometallics, 5, 1281 (1986). 

272. R. A. Jones, T. C. Wright, J. L. Atwood, and W. E. Hunter, "Structure of Bis(m-ditert-butylphosphido)-bis(dicarbonylrhodium)(Rh-Rh) in P1," Acta Crystallogr., 

C42, 294 (1986). 

273. H. Prinz, S. G. Bott, and J. L. Atwood, "Decyclization of Crown Ethers. Ringopening Reaction of 18-Crown-6 with ZrCl4," J. Am. Chem. Soc., 108, 2113 

(1986). 

274. W. J. Evans, J. W. Grate, K. R. Levan, I. Bloom, T. T. Peterson, R. J. Doedens, H. 

Zhang, and J. L. Atwood, "Synthesis and X-ray Crystal Structure of 

Bis(pentamethylcyclopentadienyl) Lanthanide and Yttrium Halide Complexes," 

Inorg. Chem., 25, 3614 (1986). 

275. E. Samuel, J. L. Atwood, and W. E. Hunter, "Cyclization of Phenylpropiolic Acid 

on Titanocene. Synthesis and Molecular Structure of Bis(h5-cyclopentadienyl)(cynamylato-C3,0)-titanium Phenylpropiolic Acid (1/1), a Novel 

Titanacycle. Synthesis of Bis(cyclopentadienyl)bis(phenylpropiolato)- titanium," J. 

Organometal. Chem., 311, 325 (1986). 

276. J. L. Atwood, "Applications of Inclusion in Separation Science," in "Chemical 

Separations," Ed. J. Navratil and C. J. King, Litarvan, Golden, CO, 1986. 

277. S. G. Bott, U. Kynast, and J. L. Atwood, "Reaction of Early Transition Metal 

Complexes with Macrocycles. II. Synthesis and Structure of TiCl3(H2O).18-

crown-6, a Compound with a Unique Bidentate Bonding Mode for the 18-crown-6 

Molecule," J. Incl. Phenom., 4, 241 (1986). 

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278. J. Z. Cayias, E. A. Babaian, D. C. Hrncir, S. G. Bott, and J. L. Atwood, "Crystal 

Structure of [Zr(dmpe)(CH2SiMe3)4] (dmpe = PMe2CH2CH2PMe2). Evidence in 

Support of the Postulation for the Presence of an Agostic Hydrogen," J. Chem. Soc., 

Dalton Trans., 2743 (1986). 

279. Y. P. Singh, P. Rupani, A. Singh, A. K. Rai, R. C. Mehrotra, R. D. Rogers, and J. L. 

Atwood, "Synthesis and IR, UV, NMR (1H and 11B) and Mass Spectral Studies of 

Some New b-ketonamine Complexes of Boron: Crystal and Molecular Structure of 

OC6H4OBOC(R)CHC(R')NR" (R = p-ClC6H4, R' = C6H5, R" = CH3)," Inorg. 

Chem., 25, 3076 (1986). 

280. P. C. Blake, M. F. Lappert, R. G. Taylor, J. L. Atwood, W. E. Hunter, and H. 

Zhang, "A Complete Series of U(III) Halides, [(UCp"2X)n] (X = F, Cl, Br or I; Cp" 

= h-C5H3(SiMe3)2); Single-crystal X-ray Structure Determinations of the Chloride 

and Bromide (n = 2 for X = m-Cl- or m-Br-)," J. Chem. Soc., Chem. Commun., 

1394 (1986). 

281. A. W. Coleman, S. G. Bott, and J. L. Atwood, "Preparation and Structure of 

(Calix[8]arene Methyl Ether).2 CDCl3," J. Incl. Phenom., 4, 247 (1986). 

282. P. C. Blake, M. F. Lappert, J. L. Atwood, and H. Zhang, "The Synthesis and 

Characterisation, Including X-ray Diffraction Study, of [Th{h-C5H3(SiMe3)2}3]; 

the First Thorium(III) Crystal Structure," J. Chem. Soc., Chem. Commun., 1148 

(1986). 

283. W. J. Evans, D. K. Drummond, S. G. Bott, and J. L. Atwood, "Reductive Distortion 

of Azobenzene by an Organosamarium(II) Reagent to Form 

[(C5Me5)2Sm]2(C6H5)2N2: An X-ray Crystallographic Snapshot of an Agostic 

Hydrogen Complex on an Ortho Metalation Reaction Coordinate," 

Organometallics, 5, 2389 (1986). 

284. J. W. Chambers, A. J. Baskar, S. G. Bott, J. L. Atwood, and M. D. Rausch, 

"Formation and Molecular Structures of (h5-Pentabenzylcyclopentadienyl)- and 

(h5-Pentaphenylcyclopentadienyl)dicarbonyl Derivatives of Cobalt and Rhodium," 

Organometallics, 5, 1635 (1986). 

285. E. A. Babaian, D. C. Hrncir, S. G. Bott, and J. L. Atwood, "Siloxy-Zirconium 

Chemistry. I. Reaction of Zr-C s-Bonds with R3SiOH and the Crystal Structure of 

(1,2-dimethoxyethane)-bis(triphenylsiloxy)dichlorozirconium(IV), (DME) 

ZrCl2(OSiPh3)2," Inorg. Chem., 25, 4818 (1986). 

286. D. A. Atwood, S. G. Bott, and J. L. Atwood, "Preparation and Structure of the 

[YbCl2

.15-crown-5]+ Cation, a New Synthetic Intermediate for Organolanthanide 

Chemistry," J. Coord. Chem., 16, 93 (1987). 

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287. W. J. Evans, T. P. Hanusa, J. H. Meadows, W. E. Hunter, and J. L. Atwood, 

"Synthesis and X-ray Crystal Structure of m, n2-N-Alkylformimidoyl Complexes of 

Erbium and Yttrium: A Structural Comparison," Organometallics, 6, 295 (1987). 

288. D. H. Miles, A. A. de la Cruz, A. M. Ly, D. -S. Lho, E. Gomez, J. A. Weeks, and 

J. L. Atwood, "Toxicants from Mangrove Plants IV: Ichthyotoxins from the 

Philippine Plant Heritiera Littoralis," ACS Symposium Series, 330, 491 (1987). 

289. A. W. Coleman, H. Zhang, S. G. Bott, J. L. Atwood, and P. H. Dixneuf, "Reactivity 

of the Diphosphine Ph2PCH2PPh2 with [(h6-p-CH3C6H4Pri)RuCl2]2. Crystal 

Structures of Ruthenium Complexes Containing Monodentate and Singly-Bridging 

Diphosphine Ligands," J. Coord. Chem., 16, 9 (1987). 

290. O. T. Beachley, Jr., J. P. Kopasz, H. Zhang, W. E. Hunter, and J. L. Atwood, 

"Synthesis and Characterization of Amphoteric Ligands Including the Crystal and 

Molecular Structure of [(Me3SiCH2)2InPPh2]2," J. Organometal. Chem., 325, 69 

(1987). 

291. A. W. Coleman, S. G. Bott, and J. L. Atwood, "Reaction of Trimethylaluminum 

with Calixarenes. I. Synthesis and Structure of [Calix[8]arene Methyl 

Ether][AlMe3]6.2 Toluene and of [p-tert-Butylcalix[8]arene Methyl 

Ether][AlMe3]6.4 Benzene," J. Incl. Phenom., 5, 581 (1987). 

292. S. G. Bott, M. Clark, J. S. Thrasher, and J. L. Atwood, "Crystal and Molecular 

Structure of S-Methyl(pentafluorosulfanyl)thiocarbamate," J. Cryst. Spec. Res., 17, 

187 (1987). 

293. G. H. Robinson, W. E. Hunter, S. G. Bott, and J. L. Atwood, "The Interation of 

Group III Metal Alkyls with Crown Ethers. The Synthesis and Structure of 

[Ga(CH3)3]2[Dibenzo-18-crown-6] and [Al(CH3)3]2[Dicyclohexano-18-crown6]," J. Organomet. Chem., 326, 9 (1987). 

294. E. A. Babaian, L. M. Barden, D. C. Hrncir, W. E. Hunter, and J. L. Atwood, 

"Indium-Based Liquid Clathrates. I. The Preparation of the First Indium Liquid 

Inclusion Compound and Crystal Structure of its Parent Complex, [K.18-Crown6]2-[In2I3Cl2(CH3)3]," J. Incl. Phenom., 5, 605 (1987). 

295. M. D. Rausch, K. J. Moriarty, J. L. Atwood, W. E. Hunter, and E. Samuel, "The 

Formation, Crystal and Molecular Structures of Bis(h5-indenyl)dicarbonylzirconium," J. Organomet. Chem., 327, 39 (1987). 

296. N. C. Means, C. M. Means, S. G. Bott, and J. L. Atwood, "Interaction of AlCl3

with Tetrahydrofuran. Formation and Crystal Structure of [AlCl2(THF)4][AlCl4]," 

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Inorg. Chem., 26, 1466 (1987). 

297. E. Hey, M. F. Lappert, J. L. Atwood, and S. G. Bott, 

"Bis(trimethylsilyl)phosphinodithioformates, the P-Analogues of Dithiocarbamates; 

X-ray Structures of [ZrCp2(Cl)(h2-S2CPR2)](1a) and [(ZrCp2(m-S))2], a 

Thermolysis Product of (1a) (Cp = h-C5H5, R = SiMe3)," J. Chem. Soc., 

Chem. Commun., 421 (1987). 

298. E. Hey, M. F. Lappert, J. L. Atwood, and S. G. Bott, "A Hexaphosphorus Chain as 

Part of a Dimeric P,P'-containing Ligand; 1,3-Phosphozirconation of White 

Phosphorus; X-ray Structure of [Zr(h-C5H5)2(O(PR2)PP(PR2)P)] (R = SiMe3)," 

J. Chem. Soc., Chem. Commun., 597 (1987). 

299. W. J. Evans, D. K. Drummond, J. W. Grate, H. Zhang, and J. L. Atwood, 

"Structural Diversity in Bis(pentamethylcyclopentadienyl) Lanthanide Halide 

Complexes: X-ray Crystal Structures of [(C5Me5)2SmCl]3 and 

(C5Me5)10Sm5Cl5[Me(OCH2CH2)4OMe]," J. Amer. Chem. Soc., 109, 3928 

(1987). 

300. G. H. Robinson, H. Zhang, and J. L. Atwood, "Reaction of Trimethylaluminum 

with a Macrocyclic Tetradentate Tertiary Amine. Synthesis and Molecular 

Structure of [Al(CH3)3]4[N-tetramethylcyclam]," J. Organometal. Chem., 331, 153 

(1987). 

301. J. L. Atwood, "Inclusion (Clathrate) Compounds," Encyclopedia of Physical 

Science and Technology, Vol. 6, 583-594 (1987). 

302. A. W. Coleman, A. J. Baskar, S. G. Bott, and J. L. Atwood, "Synthesis and Crystal 

Structure of a Novel Mixed Valence Iron Compound, [(h5-cyclopentadienyl)(h6-

tetralin)Fe(II)]3[Fe(III)(NCS)6]," J. Coord. Chem., 17, 339 (1988). 

303. S. G. Bott, A. Alvanipour, S. D. Morley, D. A. Atwood, C. M. Means, A. W. 

Coleman, and J. L. Atwood, "Stabilization of the AlMe2+ Cation by Crown 

Ethers," Angew. Chem. Int. Engl. Ed., 26, 485 (1987). 

304. W. J. Evans, R. A. Keyer, H. Zhang, and J. L. Atwood, "Synthesis and X-ray 

Crystal Structure of [(C5Me5)2Sm]2C4(C6H5)2, a Complex Containing h2-Alkyne 

Coordination to Samarium," J. Chem. Soc., Chem. Commun., 837 (1987). 

305. D. Caine, C. J. McCloskey, J. L. Atwood, S. G. Bott, H. Zhang, and D. 

VanDerveer, "The Synthesis and Base-Induced Methylation Reactions of Cis-7aHydroxy-3a-phenylsulfenyl-3z,4,5,6,7,7a-hexahydro-4-indano ne," J. Org. Chem., 

52, 1280 (1987). 

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306. J. L. Atwood, S. G. Bott, P. B. Hitchcock, C. Eaborn, R. S. Shariffudin, J. D. Smith, 

and A. C. Sullivan, "The Chemistry of Trichloro(tris(trimethylsilyl)methyl) and 

Trichloro(tris(dimethylphenyl)silyl) methyl gallates, -indates and -thallates. Crystal 

and Molecular Structures of [Li(thf)2(μ-Cl)2Ga(Cl)C(SiMe2Ph)3]thf, [Li(thf)3-(μCl)InCl2C(SiMe3)3] and [(SiMe3)3CIn(μ-Cl)(μ-Fe(CO)4InC(SiMe3)3] (thf = 

tetrahydrofuran)," J. Chem. Soc., Dalton Trans., 747 (1987). 

307. G. H. Robinson, H. Zhang, and J. L. Atwood, "Reaction of Trimethylaluminum 

with Thiacrown Ethers. Crystal and Molecular Structure of [AlMe3]4[14]anesS4," 

Organometallics, 6, 887 (1987). 

308. M. V. Lakshmikantham, M. S. Raasch, M. P. Cava, S. G. Bott, and J. L. Atwood,

"Thioquinones. A Reinvestigation of Perkin and Green's Diaminodithio- quinone,"

J. Org. Chem., 52, 1875 (1987). 

309. J. A. Ewen, L. Haspeslagh, J. L. Atwood, and H. Zhang, "Synthesis, Crystal 

Structure, and Isospecific Propylene Polymerizations with Ethylenebis(4,5,6,7- 

tetrahydro-1-indenyl)hafnium(IV) Dichloride," J. Amer. Chem. Soc., 109, 6544 

(1987). 

310. G. H. Robinson, S. G. Bott, and J. L. Atwood, "Triethylaluminum-based 

Ferrocenylalanes. Synthesis and Crystal Structure of [(h-C5H5)Fe (hC5H4)Al(C2H5)4Cl]," J. Coord. Chem., 16, 219 (1987). 

311. S. G. Bott, A. W. Coleman, and J. L. Atwood, "The Synthesis and Molecular 

Structure of t-Butylcalix[4]arene Methyl Ether complexed with Aluminum Alkyl 

Species," J. Incl. Phenom., 6, 747 (1987). 

312. S. G. Bott, H. Prinz, A. Alvanipour, and J. L. Atwood, "Reaction of Early 

Transition Metals with Macrocycles. III. Synthesis and Structure of 18-Crown6.MCl4 

 (M=Ti, Sn)," J. Coord. Chem., 16, 303 (1987). 

313. M. A. Edelman, M. F. Lappert, J. L. Atwood, and H. Zhang, "The Synthesis and Xray Structure of a Novel Monocyclopentadienyluranium(IV) Chloride 

[UCp'''Cl2(THF)(m-Cl)2Li(THF)2][Cp'''=h-C5H2(SiMe3)3-1,2,4]," Inorg. Chim. 

Acta, 139, 185 (1987). 

314. P. C. Blake, M. F. Lappert, R. G. Taylor, J. L. Atwood, and H. Zhang, "Some 

Aspects of the Coordination and Organometallic Chemistry of Thorium and 

Uranium (MIII, MIV, UV) in +3 and +4 Oxidation States," Inorg. Chim. Acta., 139, 

13 (1987). 

315. P. C. Stark, M. Huff, E. A. Babaian, L. M. Barden, D. C. Hrncir, S. G. Bott, and J. 

L. Atwood, "Indium-based Liquid Clathrates. II. Inclusion Compounds Derived 

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from Salts of the Tetrachloroindate Anion, InCl4- and the Crystal Structure of [Li15-Crown-5][In(CH3)3Cl]," J. Incl. Phenom., 6, 683 (1987). 

316. J. L. Atwood, S. G. Bott, A. W. Coleman, K. D. Robinson, S. B. Whetstone, and C. 

M. Means, "The H3O+ Cation in Aromatic Solvents. Synthesis, Structure and 

Behavior of [H3O.18-Crown-6][Cl-H-Cl]," J. Am. Chem. Soc., 109, 8100 (1987). 

317. A. M. Arif, D. E. Heaton, R. A. Jones, K. B. Kidd, T. C. Wright, B. R. Whittlesey, 

J. L. Atwood, W. E. Hunter, and H. Zhang, "Synthesis and Structures of Di- and 

Tri-nuclear Di-tert-butylphosphido and Di-tert-butylarsenido Complexes of Iridium. 

X-ray Crystal Structures of [Ir(m-t-Bu2E)(CO)2]2 (E=P, As), 

[Ir(tOBu2PH)(CO)]2(m-H)(m-t-Bu2P), [Ir(t-Bu2PH)(CO)(m-H)]2(H)(m-t-Bu2P) 

and Ir3(m-t-Bu2P)3(CO)5," Inorg. Chem., 26, 4065 (1987). 

318. U. Kynast, S. G. Bott, and J. L. Atwood, "Reaction of Early Transition Metal 

Complexes with Macrocycles. IV. Synthesis and Structure of [PPh4]2[18-Crown6.(VCl4)2] and 18-Crown-6.VCl3.H2O," J. Coord. Chem., 17, 53 (1988). 

319. A. W. Coleman, S. G. Bott, S. D. Morley, C. M. Means, K. D. Robinson, H. 

Zhang, and J. L. Atwood, "Novel Layer Structure of Sodium Calix[4]arene 

Sulphonate Complexes - a Class of Organic Clays?" Angew. Chem. Int. Ed. Engl., 

27, 1361 (1988). 

320. W. J. Evans, J. M. Olofson, H. Zhang, and J. L. Atwood, "Synthesis and X-ray 

Crystal Structure of an Unusual Oligomeric Bis(pentamethylcyclopentadienyl) 

Halide Complex of Cerium: [(C5Me5)2CeCl2K(THF)]n," Organometallics, 7, 629 

(1988). 

321. W. J. Evans, M. A. Hozbar, S. G. Bott, G. H. Robinson, and J. L. Atwood, "Utility 

of Cyclodichlorophosphazane as a NaC5H5 Scavenging Reagent: Synthesis of an 

Organoyttrium Hydroxide Complex and the X-ray Crystal Structure of the Layered 

Compound [(C5H5)2Y(μ-OH)2]C6H5C C6H5," Inorg. Chem., 27, 1990 (1988). 

322. S. G. Bott, A. W. Coleman, and J. L. Atwood, "Intercalation of Cationic, Anionic 

and Molecular Species by Organic Hosts. Preparation and Crystal Structure of 

[NH4]6[calix[4]arenesulphonate][MeOSO3].(H2O)2," J. Amer. Chem. Soc., 110, 

610 (1988). 

323. W. J. Evans, D. K. Drummond, H. Zhang, and J. L. Atwood, "Synthesis and X-ray 

Crystal Structure of the Divalent [Bis-(trimethylsilyl)amido]samarium Complexes 

[(Me3Si)2N]2Sm(THF)2 and ([(Me3Si)2N]Sm(m-I)(DME)(THF))2," Inorg. 

Chem., 27, 575 (1988). 

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324. E. Hey, S. G. Bott, and J. L. Atwood, "Synthesis of Bis(h-cyclopentadienyl)- 

(1,2,3-triphosphanto-P,P)zirconium(IV) and hafnium(IV), [(h-C5H5)M- (PPh-PPhPPh)] (M=Zr, Hf) and Structure of the Hafnocene Derivative," Chem. Ber., 121, 

561 (1988). 

325. J. S. Thrasher, J. B. Nielsen, S. G. Bott, D. J. McClure, S. A. Morris, and J. L. 

Atwood,"Bis[pentafluorosulfanyl(trifluoromethyl)amino]mercury, Hg[N(CF3)- 

SF5]2, and Bis[pentafluorotellurium(trifluoromethyl)amino]mercury, 

Hg[N(CF3)TeF5]2," Inorg. Chem., 27, 570 (1988). 

326. P. J. Cragg, S. G. Bott, and J. L. Atwood, "Lanthanide and Actinide Complexes of 

Monoaza-15-Crown-5. Syntheses and Crystal Structure of [La(monoaza-15- 

Crown-5)(NO3)3] and [UO2(NO3)2]2(μ-H2O)(monoaza-15-crown-5)," J. Lanth. 

Act. Res. 2, 265 (1988). 

327. G. H. Robinson, E. S. Appel, S. A. Sangokoyo, H. Zhang, and J. L. Atwood, 

"Synthesis and Molecular Structure of [Al(CH3)]2[15] and N4[Al(CH3)3]2: An 

Aluminum-Nitrogen Macrocyclic Cage," J. Coord. Chem., 17, 373 (1988). 

328. W. J. Evans, D. K. Drummond, L. R. Chamberlain, R. J. Doedens, S. G. Bott, H. 

Zhang, and J. L. Atwood, "Synthetic, Structural and Reactivity Studies of the 

Reduction and CO Derivatization of Azobenzene Mediated by Divalent Lanthanide 

Complexes," J. Amer. Chem. Soc., 110, 4983 (1988). 

329. W. J. Evans, D. K. Drummond, L. A. Hughes, R. J. Doedens, H. Zhang, and J. L. 

Atwood, "Variable Coordination Numbers in Crystalline 

Bis(pentamethylcyclopentadienyl) Samarium Oxide, Iodide, and Alkoxide 

Complexes," Polyhedron, 7, 1693 (1988). 

330. R. Shakir, R. D. Rogers, J. L. Atwood, D. W. Macomber, Y.-P. Wang, and M. D. 

Rausch, "The Formation and Molecular Structures of Formyl-, Cyano-, and 

Aminocyclopentadienyldicarbonylnitrosylchromium," J. Cryst. Spec. Res., 18, 767 

(1988). 

331. A. Alvanipour, H. Zhang, and J. L. Atwood, "Synthesis, Structure, and Solution 

Behavior of [Na.15-Crown-5][Mn(CO)5]," J. Organomet. Chem., 358, 295 (1988). 

332. P. C. Blake, E. Hey, M. F. Lappert, J. L. Atwood, and H. Zhang, 

"Bis(trimethylsilyl)phosphido complexes. II. Bis(trimethylsilyl)phosphidobis- 

(tetrahydrofuran)lithium as a reducing agent; X-ray structure of [UCp"2(mCl)2Li(THF)2][Cp"=h-C5H3(SiMe3)2-1,3; THF=OC4H8]," J. Organomet. Chem., 

353, 307 (1988). 

333. J. L. Atwood, M. F. Lappert, R. G. Smith, and H. Zhang, "Four-co-ordinate 

Lanthanide Metal(III) Chloro(alkyls)s: Synthesis and X-ray Structure of [LaR3(mCase 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 56 of 90 PageID: 4319
Cl)Li(pmdeta)] [R=CH(SiMe3)2, pmdeta = N,N,N',N",N"-pentamethyldiethylenetriamine]," J. Chem. Soc., Chem. Commun., 1308 (1988). 

334. E. Hey, M. F. Lappert, J. L. Atwood, and S. G. Bott, "Insertion of Diphenyldiazomethane into [ZrCp2(Cl)PR2] (Cp = h-C5H5, R = SiMe3), X-Ray Structures 

of [ZrCp2(PR2)X] (X = Cl or Me) and [ZrCp2(Cl){N(CPh2)NPR2}]," Polyhedron, 

7, 2083 (1988). 

335. J. L. Atwood, "Inclusion Compounds in Separation Science: An Overview," in 

Separation Technology, Eds., N. N. Li and H. Strathmann, Engineering Foundation, 

New York, 1988, pp. 46-56. 

336. J. A. Ewen, L. Haspeslagh, M. J. Elder, J. L. Atwood, H. Zhang, and H. N. Cheng, 

"Catalysts for Propylene Polymerization," Transition Metals and Organometallics 

as Catalysts for Olefin Polymerization, W. Kaminsky and H. Sinn, Eds., SpringerVerlag, Berlin, 1988, p. 281. 

337. P. C. Blake, M. F. Lappert, J. L. Atwood, and H. Zhang, "A Series of Bis(hcyclopentadienyl)uranium(III) Dichloro-bridged-alkali-metal and Dihalogenobis(hcyclopentadienyl)uranate(III) Complexes," J. C. S. Chem. Comm., 1436 (1988). 

338. A. Antinolo, G. S. Bristow, G. K. Campbell, A. W. Duff, P. B. Hitchcock, R. A. 

Kamarudin, M. F. Lappert, R. J. Norton, N. Sarjudeen, D. J. W. Winterborn, J. L. 

Atwood, W. E. Hunter, and H. Zhang, "Synthetic and Structural Studies on Some 

Organic Compounds of Zirconium," Polyhedron, 8, 1601 (1989). 

339. J. L. Atwood, A. W. Coleman, H. Zhang, and S. G. Bott, "Organic Clays. 

Synthesis and Structure of Na5[calix[4]arene sulfonate]·12 H2O, K5[calix[4]arene 

sulfonate]·8 H2O, Rb5[calix[4]arene sulfonate]·5 H2O, and Cs5[calix[4]arene 

sulfonate]·4 H2O," J. Incl. Phenom., 7, 203 (1989). 

340. H. Yoo, H. Zhang, J. L. Atwood, and G. W. Gokel, "A Lariat Ether that Forms a 

Pseudo-sandwich Complex," Tetrahderon Lett., 30, 2489 (1989). 

341. M. D. Rausch, W. C. Spink, J. L. Atwood, A. J. Baskar, and S. G. Bott "Dimethyland Diphenylphosphino-cyclopentadienyl Derivatives of Cobalt, Rhodium and 

Iridium: The Crystal and Molecular Structure of Dicarbonyl-{π-[h5-Cyclopentadienyl)dimethylphosphine-P]}Dirhodium," Organometallics, 8, 2627 (1989). 

342. E. Hey, S. B. Wild, S. G. Bott, and J. L. Atwood, "The Synthesis and Crystal 

Structure of (R*,R*)-(±)-[(h5-C5H5){1,2-C6H4(PMePh)2}Fe(PCl3)Cl.2 MeCN," 

Z. Naturforsch., 44b, 615 (1989). 

343. A. Nakano, Y. Li, P. Geoffroy, M. Kim, J. L. Atwood, S. G. Bott, L. Echegoyen, 

and G. W. Gokel, "Cistulynes: Proton NMR and Single Crystal X-ray Evidence 

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for Structure and Cation Encapsulation in a Rigid Molecular Channel Model 

System," Tetrahedron Lett., 5099 (1989). 

344. J. L. Atwood, "Inclusion Compounds," in Ullman's Encyclopedia of Industrial 

Chemistry, Vol. A14, 119 (1989). 

345. J. L. Atwood, S. G. Bott, C. M. Means, A. W. Coleman, H. Zhang, and M. T. May, 

"Synthesis of Salts of the Hydrogen Dichloride Anion in Aromatic Solvents. II. 

The Synthesis and Crystal Structure of [K·18-crown-6]- [Cl-H-Cl], [Mg·18-crown6][Cl-H-Cl]2, [H3O+·18-crown-6][Cl-H-Cl], and the Related [H3O+·18-crown6][Br-H-Br]," Inorg. Chem., 29, 467 (1990). 

346. F. Hamada, S. G. Bott, G. W. Orr, A. W. Coleman, H. Zhang, and J. L. Atwood, 

"Thiocalix[4]arenes, I. Synthesis and Structure of Ethylthiocalix[4]arene Methyl 

Ether and the Related Structure of Bromocalix[4]arene Methyl Ether," J. Incl. 

Phenom., 9, 195 (1990). 

347. G. M. Gray, N. Takada, M. Jan, H. Zhang, and J. L. Atwood, "Synthesis and 

Characterization of a Series of trans-[(CO)5MPh2PX(CH2)3M=CHC6H4-o-O]2M' 

(M = Mo; X = NH or M = Cr, W; X = CH2; M' = Ni, Cu, Zn) Complexes and the 

X-ray Crystal Structure of trans-[(CH)5MoP(OCH2CMe2CH2O)NH(CH2)2N= 

CHC6H4-o-O)]2Cu," J. Organometal. Chem., 381, 53 (1990). 

348. H. Zhang and J. L. Atwood, "Crystal and Molecular Structure of 

Cyclotriveratrylene," J. Cryst. Spec. Res., 20, 465 (1990). 

349. M. B. Power, A. R. Barron, J. L. Atwood, and S. G. Bott, "π-Face Selectivity of 

Coordinated Ketones to Nucleophilic Additions: The Importance of AluminumOxygen π-Bonding," J. Am. Chem. Soc., 112, 3446 (1990). 

350. T. Lu, H. K. Yoo, H. Zhang, S. G. Bott, J. L. Atwood, L. Echegoyen, and G. W. 

Gokel, "Podand-Catalyzed Nucleophilic Aromatic Substitutions of Anthraquinones: A Novel Synthetic Approach and a Mechanistic Suggestion from Solid 

State Data," J. Org. Chem., 55, 2269 (1990). 

351. M. B. Power, A. W. Applett, S. G. Bott, J. L. Atwood, and A. R. Barron, "Aldol 

Condensation of Ketones Promoted by Sterically Crowded Aryloxide Compounds 

of Aluminum," Organometallics, 9, 2529 (1990). 

352. J. L. Atwood, S. G. Bott, R. A. Jones, and S. U. Koschmieder, "Synthesis and 

Structure of Cp*BePBut

2: The First Diorganophosphide Derivative of Beryllium," 

J. Chem. Soc., Chem. Commun., 692 (1990). 

353. R. D. Rogers, J. L. Atwood, M. D. Rausch, and D. W. Macomber, "Crystal 

Stuctures of (h5-C5H4COMe)M(CO)3Me (M = Mo, W)," J. Cryst. Mol. Struct., 20, 

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555 (1990). 

354. M. J. Zaworotko, J. L. Atwood, and R. D. Priester, "Structure, Conformation and 

Reactivity of Organotransition Metal p-Complexes. Part 2. X-Ray 

Crystallographic Characterization of Two Neutral Half-Sandwich Cr(CO)3

Complexes," J. Coord. Chem., 22, 209 (1990). 

355. A. W. Coleman, C. M. Means, S. G. Bott, and J. L. Atwood, "Air-Stable Liquid 

Clathrates, I. Crystal Structure of [NBu4][Br3] and Reactivity of the 

 [NBu4][Br3].7 C6H6 Liquid Clathrate," J. Cryst. Spec. Res., 20, 199, (1990). 

356. D. A. Atwood, R. A. Jones, A. H. Cowley, J. L. Atwood, and S. G. Bott, "X-ray 

Crystal Structure of the Dimethylgallium Azide Polymer and Its Use as a Gallium 

Nitride Precursor," J. Organomet. Chem., 394, C6 (1990). 

357. J. L. Atwood, "Cation Complexation by Calixarenes," in Cation Binding by 

Macrocycles, Eds., G. W. Gokel and Y. Inoue, Dekker, New York, 1990, pp. 581-

597. 

358. S. G. Bott, A. Alvanipour, and J. L. Atwood, "Stabilization of H2O.BF3 by 

Hydrogen-Bonding to 18-Crown-6," J. Incl. Phenom. 10, 153 (1990). 

359. M. D. Rausch, W. C. Spink, B. G. Conway, R. D. Rogers, J. L. Atwood, and L. G. 

Canada, "Synthetic and Structural Studies on (h5: h5-Fulvalene)bimetallic 

Compounds Derived from (h5: h5-Fulvalene)dithallium" J. Organomet. Chem., 

383, 227 (1990). 

360. J. L. Atwood and S. G. Bott "Water Soluble Calixarene Salts. A Class of 

Compounds with Solid-State Structures Resembling those of Clays", in 

Calixarenes, Eds., J. Vicens and V. Böhmer, Kluwer, 1990, pp. 209-221. 

361. C. M. Means, S. G. Bott, and J. L. Atwood, "Reduction of Sugars with Aluminum 

Alkyls. Preparation and Structure of [AlCl2(NC5H5)(OEt2)]2(m-O)- (mAlCl.2NC5H5)," Polyhedron, 9, 309, (1990). 

362. M. B. Power, S. G. Bott, D. L. Clark, J. L. Atwood, and A. R. Barron, "The 

Interaction of Organic Carbonyls with Sterically Crowded Aryloxide Compounds 

of Aluminum," Organometallics, 9, 3086 (1990). 

363. A. H. Cowley, R. A. Jones, M. A. Mardones, J. Ruiz, J. L. Atwood, and S. G. Bott, 

"Synthesis and Structure of a Diphosphagalletane: A Novel Base-Stabilized Ga2P2

Ring System," Angew. Chem. Int. Ed. Engl., 29, 1150 (1990). 

364. A. H. Cowley, R. A. Jones, M. A. Mardones, J. Ruiz, J. L. Atwood, and S. G. Bott, 

"Cleavage of a Phosphorus-Carbon Double Bond and Formation of a Linear 

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Terminal Phosphinidene Complex," J. Amer. Chem. Soc., 112, 6734 (1990). 

365. J. L. Atwood, S. G. Bott, and R. L. Vincent, "Crystal Structure of Dinitrato -

tris(pyridine)nickel (II), Ni(NC5H5)3(NO3)2," J. Cryst. Spec. Res., 20, 631 (1990). 

366. D. H. Miles, J. M. R. del Medeiros, V. Chittawond, C. Swithenbank, Z. Lidert, J. A. 

Weeks, J. L. Atwood, and P. A. Hedin, "3'-Formyl-2',4',6'-Trihydroxy-5'- 

methyldihydrochalcone, A Prospective New Agrochemical from Psidium 

acutangulum," J. Nat. Products, 53, 1548 (1990). 

367. A. H. Cowley, R. A. Jones, M. Mardones, S. G. Bott and J. L. Atwood, "An 

Aluminum - Phosphorus Cubane, a New Aluminum Phosphide Precursor," Angew. 

Chem. Int. Ed. Engl., 29, 1409 (1990). 

368. F. Hamada, T. Fukugaki, K. Murai, G. W. Orr, and J. L. Atwood, "Liquid-Liquid 

Extraction of Transition and Alkali Metal Cations by a New Calixarene: Diphenyl 

Phosphino Calix[4]arene Methyl Ether," J. Incl. Phenom., 10, 57 (1991). 

369. J. L. Atwood, S. G. Bott, K. D. Robinson, E. J. Bishop, and M. T. May, 

"Preparation and X-ray Structure of [H3O+.18-Crown-6][H5O2+](Cl-)2, a 

Compound Containing both H3O+ and H5O2+ Crystallized from Aromatic 

Solution," J. Cryst. Spec. Res., 21, 458 (1991). 

370. E. Hey-Hawkins, M. F. Lappert, J. L. Atwood, and S. G. Bott, 

"Bis(trimethylsilyl)phosphido Complexes. Part 3. Synthesis Structures and 

Reactions of [Bis(trimethylsilyl)phosphido]zirconocene(IV) and the X-ray 

Structure of {AlMe2μ-P(SiMe3)2}2." J. Chem. Soc., Dalton Trans., 939 (1991). 

371. M. B. Power, S. G. Bott, E. J. Bishop, K. D. Tierce, J. L. Atwood, and A. R. 

Barron, "Acylation and Esterification of the Aryloxide Ligand in AlMe(BHT)2" J. 

Chem. Soc., Dalton Trans., 241 (1991). 

372. C. J. Harlan, T. C. Wright, J. L. Atwood, and S. G. Bott, "Hydrazinophosphine 

Complexes of Iron: Metallocycle Formation via Attack on Coordinated Carbon 

Monoxide," Inorg. Chem., 30, 1955 (1991). 

373. J. C. Medina, T. T. Goodnow, S. Bott, J. L. Atwood, A. E. Kaifer, and G. W. Gokel, 

Ferrocenyldimethyl-[2.2]-Cryptand: Solid State Structure of the External Hydrate 

and Alkali and Alkaline-earth-dependent Electrochemical Behaviour," J. Chem. 

Soc., Chem. Commun., 290 (1991). 

374. R. Alvarez, J. L. Atwood, E. Carmona, P. J. Perez, M. L. Poveda, and R. D. Rogers, 

"Formation of Carbonyl-Carbonate Complexes of Molybdenum by Reductive 

Disproportionation of Carbon Dioxide. X-Ray Structure of Mo4(μ4-

CO3)(CO)2(O)2(μ2-OH)4 (PMe3)6," Inorg. Chem., 30, 1493 (1991). 

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375. J. C. Medina, C. Li, S. G. Bott, J. L. Atwood, and G. W. Gokel, "A Molecular 

Receptor Based on the Ferrocene System: Selective Complexation Using Atomic 

Ball-bearings," J. Am. Chem. Soc., 113, 366 (1991). 

376. J. L. Atwood, G. W. Orr, F. Hamada, R. L. Vincent, S. G. Bott, and K. D. 

Robinson,"Second Sphere Coordination of a Transition Metal Complex by a 

Calix[4]arene," J. Am. Chem. Soc., 113, 2760 (1991). 

377. J. L. Atwood, F. Hamada, K. D. Robinson, G. W. Orr, and R. L. Vincent, "X-Ray 

diffraction evidence for aromatic π hydrogen bonding to H2O," Nature, 349, 683 

(1991). 

378. D. H. Miles, V. Chittawong, D.-S. Lho, A. M. Payne, A. A. de la Cruz, E. D. 

Gomez, J. A. Weeks, and J. L. Atwood, "Toxicants from Mangrove Plants, VII. 

Vallapin and Vallapianin, Novel Sesquiterpene Lactones from the Mangrove Plant 

Heritiera littoralis," J. Natural Prod., 54, 286 (1991). 

379. N. S. Kishore, T. Lu, L. J. Knoll, A. Katoh, D. A. Rudnick, P. P. Mehta, B. 

Devadas, M. Huhn, J. L. Atwood, S. P. Adams, G. W. Gokel, and J. I. Gordon, "The 

Substrate Specificity of Saccharomyces cerevisiae Myristoyl-CoA:Protein NMyristoyltransferase," J. Biol. Chem., 266, 8835 (1991). 

380. J. L. Atwood, S. G. Bott, F. M. Elms, C. Jones, and C. L. Raston, "Tertiary Amine 

Adducts of Gallane," Inorg. Chem., 30, 3792 (1991). 

381. J. A. Ewen, M. J. Elder, R. L. Jones, L. Haspeslagh, J. L. Atwood, S. G. Bott, and 

K. Robinson, "Metallocene/Polypropylene Structural Relationships: Implications 

on Polymerization and Stereochemical Control Mechanisms" Makromol. Chem.,

Macromol Symp., 48/49, 253 (1991). 

382. E. Carmona, L. Contreras, M. L. Poveda, L. J. Sanchez, J. L. Atwood, and R. D. 

Rogers," h2-Acyl and Methyl complexes of Tungsten. Crystal and Molecular 

Structures of W(h2-COCH2SiMe3)Cl(CO)(PMe3)3 and W(CH3)(S2CNMe2)- 

(CO)2(PMe3)2," Organometallics, 10, 61 (1991). 

383. L. M. Clarkson, W. Clegg, D. C. R. Hockless, N. C. Norman, L. J. Farrugia, S. G. 

Bott, and J. L. Atwood, "Synthetic and Structural Studies on Group 13 Complexes 

Containing the M(CO)3(h-C5H5) Fragment (M = Cr, Mo); Part 2," J. Chem. Soc., 

Dalton Trans., 2241 (1991). 

384. J. C. W. Chien, G. H. Llinas, M. D. Rausch, J. L. Atwood, and S. G. Bott, TwoState Propagation Mechanism for Propylene Polymerization Catalyzed by "rac[antiEthylidene(1-h5-tetramethylcyclopentadienyl)(1-h2-indenyl)dimethyl- titanium]," 

J. Am. Chem. Soc., 113, 8569 (1991). 

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385. J. L. Atwood, S. G. Bott, C. Jones, and C. L. Raston, "Oligomeric Gallium 

Amide/Hydride Complexes, [Ga2H2((NPriCH2)2)2] and [Ga3H5((NMeCH2)2)2], 

via Hydromethallation and Metalation," Inorg. Chem., 30, 4868 (1991). 

386. O. F. Schall, K. Robinson, J. L. Atwood, and G. W. Gokel, “Self-Assembling, 

Alkali-Metal-Complexing Nickel Salicylaldimine Complexes,” J. Am. Chem. Soc.,

113, 7434 (1991). 

387. J. L. Atwood, F. R. Bennett, F. M. Elms, C. Jones, C. L. Raston, and K. D. 

Robinson "Tertiary Amine Stabilized Dialane," J. Amer. Chem. Soc., 113, 8183 

(1991). 

388. J. L. Atwood, K. D. Robinson, C. Jones, and C. L. Raston "Cationic Aluminum 

Hydrides: [H2AlL]+[AlH4]-, L = N,N,N,',N",N"-Penta- methyldiethylene- triamine 

and N,N',N",N'''-Tetramethylcyclam," J. Chem. Soc., Chem. Commun., 1697 

(1991). 

389. D. A. Atwood, R. A. Jones, A. H. Cowley, S. G. Bott, and J. L. Atwood, "Primary 

Amido and Amine Adduct Complexes of Gallium: Synthesis and Structures of [tBu2Ga(m-NHPh)]2 and t-Bu3Ga.NH2Ph," Polyhedron, 10, 1897 (1991). 

390. A. H. Cowley, R. A. Jones, M. A. Mardones, J. L. Atwood, and S. G. Bott, “A 

Novel Gallium-Phosphorus Cage Compound,” Angew. Chem. Int. Ed. Engl., 30, 

1141 (1991). 

391. A. H. Cowley, R. A. Jones, M. A. Mardones, J. L. Atwood, and S. G. Bott, 

“Reaction of (t-BuGaCl2)2 with Ar’PHLi (Ar’ = 2,4,6-t-Bu3C6H2): Preparation of 

the Chloride-Bridged Dimer (t-BuGa(Cl)P(H)Ar’)2,” Heteroatom. Chem., 2, 

11(1991). 

392. S. G. Bott, A. Alvanipour, and J. L. Atwood, “Stabilization of Boron Trifluoride 

Monohydrate by Hydrogen Bonding to 18-Crown-6,” J. Incl. Phenom., 10, 153 

(1991). 

393. J. L. Atwood, S. G. Bott, and M. T. May, “Synthesis and Crystal Structure of 

[(ClAl(m-OH)2AlCl).18-crown-6][AlCl4]2.8/3 C6H5NO2, a Complex Featuring a 

Binuclear Aluminum-Containing Cation Threaded through 18-Crown-6,” J. Coord. 

Chem., 23, 313 (1991). 

394. J. A. Ewen, M. J. Elder, C. J. Harlan, R. L. Jones, J. L. Atwood, S. G. Bott, and K. 

Robinson, “p-Face Selectivity in Syndiospecific Propylene Polymerizations with 

Zirconium (IV) Monoalkyl Cations,” Polym. Prepr. (Am. Chem. Soc., Div. Polym. 

Chem.), 32, 469 (1991). 

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395. M. Tsesarskaja, T. P. Cleary, S. R. Miller, J. E. Trafton, S. Bott, J. L. Atwood, and 

G. W. Gokel, "Tribracchial Lariat Ethers: Syntheses, Binding, and Formation of an 

Intramolecular Macroring-sidearm Complex in the Absence of Any Cation," J. Incl. 

Phenom., 12, 187 (1992). 

396. R. K. Juneja, K. D. Robinson, G. W. Orr, R. H. Dubois, K. A. Belmore, and J. L. 

Atwood, "Inclusion of Multi-ring Compounds by p-tert-Butylcalix[5]arene," J. Incl. 

Phenom., 13, 93 (1992). 

397. J. L. Atwood, F. R. Bennett, C. Jones, G. A. Koutsantonis, C. L. Raston, and K. D. 

Robinson, “Polydentate Tertiary Amine Alane Adducts: Monomeric versus 

Polymeric Species,” J. Chem. Soc., Chem. Commun., 541 (1992). 

398. J. L. Atwood, D. L. Clark, R. K. Juneja, G. W. Orr, K. D. Robinson, and R. L. 

Vincent, "Double Partial Cone Conformation for Na8[calix[6]arene sulfonate].20.5 

H2O and Its Parent Acid," J. Am. Chem. Soc., 114, 7558 (1992). 

399. C. J. Harlan, T. C. Wright, S. G. Bott, and J. L. Atwood, "Synthesis and Structure of 

[CpFe(CO){(Ph2P)2NNMe2}][I]-CH2Cl2," J. Cryst. Spec. Res., 22, 91 (1992). 

400. C. J. Harlan, T. C. Wright, S. G. Bott, and J. L. Atwood, "Synthesis and X-ray 

Crystal Structure of a Five Coordinate d8 Complex: [Pt((Me2NN)(PMe2)- 

(PPh2))2Cl][Cl]," J. Cryst. Spec. Res., 22, 71 (1992). 

401. J. L. Atwood, G. W. Orr, N. C. Means, F. Hamada, H. Zhang, S. G. Bott, and K. D. 

Robinson, "Metal Ion Complexes of Water Soluble Calix[4]arenes," Inorg. Chem., 

31, 603 (1992). 

402. J. L. Atwood, G. W. Orr, F. Hamada, S. G. Bott, and K. D. Robinson, 

"Supramolecular Assemblies of Calix[4]arenes Organized by Weak Forces," 

Supramol. Chem., 1, 15 (1992). 

403. R. O. C. Hart, S. G. Bott, J. L. Atwood, and S. R. Cooper, “Higher Valent 

Manganese Chemistry. [Mn(biguanide)3]+, a Structurally Characterized MnIV

Complex with All-Nitrogen Coordination,” J. Chem. Soc., Chem. Commun., 894 

(1992). 

404. D. A. Atwood, R. A. Jones, A. H. Cowley, S. G. Bott, and J. L. Atwood, “Primary 

Amide and Amine Complexes of Gallium and Indium: X-ray Crystal Structures of 

[Me2Ga(m-NH(Bu))]2, Me3Ga.NH2(Bu) and Me3In.NH2(Bu),” J. Organomet. 

Chem., 434, 143 (1992). 

405. J. L. Atwood, A. Alvanipour, and H. Zhang, “Synthesis and Structure of 

((H2O).HBF4)2(18-crown-6),” J. Cryst. Spec. Res., 22, 349 (1992). 

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406. J. L. Atwood, F. R. Bennett, K. D. Robinson, F. M. Elms, G. A. Koutsantonis, C. L. 

Raston, and D. J. Young "Gallane/Phosphine Adducts: Air Stable 

[H3Ga{P(C6H11)3}] and Gallane Rich [(H3Ga)2{(PMe2CH2)2}]," Inorg. Chem., 

31, 2673 (1992). 

407. M. Clark, C. J. Kellen, K. D. Robinson, H. Zhang, Z.-Y. Yang, K. V. Madappat, J. 

W. Fuller, J. L. Atwood, and J. S. Thrasher "Naked SF5- Anion: The Crystal and 

Molecular Structure of [Cs+.(18-Crown-6)2][SF5-]," Eur. J. Solid State Inorg. 

Chem., 29, 809 (1992). 

408. R. H. Wallace, Y. S. Lu, J. C. Liu, and J. L. Atwood, "Synthesis of alpha-Pinene 

Derived C-2 Symmetrical, Optically-Active 1,2-Diols," Synlett, 992 (1992). 

409. H. Kim, O. F. Schall, J. Fang, J. E. Trafton, T. Lu, J. L. Atwood, and G. W. Gokel, 

“Direct Nucleophilic Aromatic Substitution Reactions in the Syntheses of 

Anthraquinone Derivatives: Chemistry and Binding of Podands, Crown Ethers, and 

a Cryptand,” J. Phys. Org. Chem., 5, 482 (1992). 

410. J. L. Atwood, S. G. Bott, C. Jones, and C. L. Raston, “Aluminum Fused Bis-p-tertButylcalix[4]arene: A Double Cone with Two p-Arene...H-Interactions for 

Included Methylene Chloride,” J. Chem. Soc., Chem. Commun., 1349 (1992). 

411. R. Chukwu, A. D. Hunter, B. D. Santarsiero, S. G. Bott, J. L. Atwood, and J. 

Chassalgnac, “Electrochemical, Spectroscopic, and Structural Studies of Mono- and 

Bimetallic Complexes of Iron,” Organometallics, 11, 589 (1992). 

412. D. A. Atwood, A. H. Cowley, R. A. Jones, M. A. Mardones, J. L. Atwood, and S. 

G. Bott, “Synthesis and Structures of Two Bulky Gallium Chlorides,” J. Coord. 

Chem., 25, 233 (1992). 

413. D. A. Atwood, R. A. Jones, A. H. Cowley, S. G. Bott, and J. L. Atwood, “Structural 

Characterization of a Dialkylgallium Cation: X-ray Crystal Structure of 

[Me2Ga(BuNH2)2]Br,” J. Organomet. Chem., 425, C1 (1992). 

414. R. A. Jones, S. U. Koschmieder, J. L. Atwood, and S. G. Bott, “Insertion of LiPEt2

into Poly(dimethylsiloxane) to Give [LiOSiMe2PEt2]6,” J. Chem. Soc., Chem. 

Commun., 726 (1992). 

415. J. L. Atwood, S. D. Christie, M. D. Clerk, D. A. Osmond, K. C. Sturge, and M. J. 

Zaworotko, "Interaction of Alkylaluminum Reagents with Organotransition Metal 

Arene Complexes: Net Addition of Alkide, Haloalkide and Dichloromethide to 

[(arene)2Fe]2+ Cations," Organometallics, 11, 337 (1992). 

416. J. L. Atwood, G. W. Orr, F. Hamada, R. L. Vincent, S. G. Bott, and K. D. 

Robinson, “Calixarenes as Second-Sphere Ligands for Transition Metal Ions,” J. 

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Incl. Phenom., 14, 37 (1992). 

417. D. A. Atwood, A. H. Cowley, R. A. Jones, M. A. Mardones, J. L. Atwood, and S. 

G. Bott, “Synthesis and Structures of [NMe2(m-NMe2)GaCl]2 and [TMP(mOEt)GaCl]2 (TMP = 2,6-tetramethylpipyridine),” J. Coord. Chem., 26, 285 (1992). 

418. C. Balagopalakrishna, M. V. Rajasekharan, S. Bott, J. L. Atwood, and B. L. 

Ramakrishna, "Synthesis, Crystal Structure, Magnetic Susceptibility, and Single 

Crystal EPR Studies of Bis(diazafluorenone)dichlorocopper(II): A Novel 

Cu(NN)2X2 System with an Unusual Distortion," Inorg. Chem., 31, 2843 (1992). 

419. D. A. Atwood, A. H. Cowley, R. A. Jones, J. L. Atwood, and S. G. Bott, “Synthesis 

and X-ray Structure of Me2InI(NH2(t-Bu)): The First Structurally Characterized 

Amine Adduct of a Dialkyl Indium Iodide,” J. Coord. Chem., 26, 293 (1992). 

420. D. A. Atwood, V. O. Atwood, A. H. Cowley, J. L. Atwood, and E. Roman, 

“Macrocyclic (C22H22 N4) Complexes of Ge(II), Sn(II), Ga(III), and In(III). Main 

Group Functionalities in an Unusual Environment,” Inorg. Chem., 31, 3871 (1992). 

421. J. Fang, R. Lu, H. Kim, I. Delgado, P. Geoffroy, J. L. Atwood, and G. W. Gokel, 

"Alkynes and Polyethylene Glycol Derivatives as Nucleophiles and Catalysts in 

Substitution Reactions of 1-Chloroanthraquinones," J. Org. Chem., 56, 7059 

(1992). 

422. J. C. W. Chien, G. H. Llinas, M. D. Rausch, Y.-G. Lin, H. H. Winter, J. L. Atwood, 

and S. G. Bott, “Metallocene Catalysts for Olefin Polymerizations. XXIV. 

Stereoblock Propylene Polymerization Catalyzed by rac-[anti-Ethylidene(1-h5-

Tetramethylcyclopentadienyl)(1-h5-Indenyl)dimethyltitanium]: A Two-State 

Propagation,” J. Poly. Sci. A. Poly. Chem., 30, 2601 (1992). 

423. J. C. Medina, T. T. Goodnow, M. T. Rojas, J. L. Atwood, B. C. Lynn, A. E. Kaifer, 

and G. W. Gokel, “Ferrocenyl Iron as a Donor Group for Complexed Silver in 

Ferrocenyldimethyl[2.2]cryptand: A Redox-Switched Receptor Effective in 

Water,” J. Am. Chem. Soc., 114, 10583 (1992). 

424. J. Li, A. D. Hunter, R. McDonald, B. D. Santarsiero, S. G. Bott, and J. L. Atwood, 

“p-Donor Interactions and the Origin of Arene Nonplanarity in Heterobimetallic 

(h6-arene)Cr(CO)3 Complexes Having s-Bonded Organometallic Substituents,” 

Organometallics, 11, 3050 (1992). 

425. J. L. Atwood, "Inclusion (Clathrate) Compounds," in Encyclopedia of Physical 

Science and Technology, Vol. 8, 25-36 (1992). 

426. F. Hamada, K. D. Robinson, G. W. Orr, and J. L. Atwood, "Alkali Metal Salts of 

Oxyanions of p-tert-Butylcalix[4]arene," Supramol. Chem., 2, 19 (1993). 

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427. G. Facey, R. H. Dubois, M. Zakrzewski, C. I. Ratcliffe, J. L. Atwood, and J. A. 

Ripmeester, “Phase Transition and Dynamic Structure of the Toluene Complex of tButylcalix[4]arene,” Supramol. Chem., 1, 199 (1993). 

428. D. A. Atwood, A. H. Cowley, P. R. Harris, R. A. Jones, J. L. Atwood, and S. G. 

Bott, “Cyclic Trimeric Hydroxy, Amido, Phosphido and Arsenido Derivatives of Al 

and Ga. X-ray Structures of [t-Bu2Ga(m-OH)]3 and [t-Bu2Ga(m-NH2)]3,” 

Organometallics, 12, 24 (1993). 

429. J. L. Atwood and G. W. Gokel, "Molecular Recognition," in McGraw-Hill 

Dictionary of Science, 244-247 (1993). 

430. R. M. Metzger, J. L. Atwood, W.-J. Lee, S. M. Rao, R. B. Lal, and B. H. Loo, 

"Structure of MAP:MNA, a New Nonlinear Optical Crystal," Acta Crystallogr., 

C49, 738 (1993). 

431. O. F. Schall, K. Robinson, J. L. Atwood, and G. W. Gokel, “Self-Assembling 

Nickel Clusters form Binding Sites for Alkali Metal Cations,” J. Am. Chem. Soc., 

115, 5962 (1993). 

432. D. Lorcy, K. D. Robinson, Y. Okuda, J. L. Atwood, and M. P. Cava, “Novel 

Electron Acceptors Derived from Isothianaphthlene,” J. Chem. Soc., Chem. 

Commun., 345 (1993). 

433. J. L. Atwood, G. W. Orr, S. G. Bott, and K. D. Robinson, “Supramolecular 

Complexes of Flexible, Extended Cavity Calix[4]arenes - Structural 

Characterization of a Molecular Venus’s Flytrap,” Angew. Chem. Int. Ed. Engl., 32, 

1093 (1993). 

434. J. L. Atwood, G. W. Orr, K. D. Robinson, and F. Hamada, “Calixarenes as Enzyme 

Models,” Supramol. Chem., 2, 309 (1993). 

435. F. M. Elms, M. G. Gardiner, G. A. Koutsantonis, C. L. Raston, J. L. Atwood, and 

K. D. Robinson, “Tertiary Phosphine Adducts of Alane and Gallane,” J. 

Organomet. Chem., 449, 45 (1993). 

436. F. Hamada, G. W. Orr, H. Zhang, and J. L. Atwood, "Crystal Structure of 

cyanocalix[4]arene methyl ether," J. Cryst. Spec. Res., 23, 681 (1993). 

437. M. V. Lakshmikantham, M. P. Cava, W. H. H. Gunther, P. N. Nugara, K. A. 

Belmore, J. L. Atwood, and P. Cragg, “Synthesis of 1,2-Ditellurolane Derivatives,”

J. Am. Chem. Soc., 115, 885 (1993). 

438. J. L. Atwood, G. W. Orr, R. K. Juneja, S. G. Bott, and F. Hamada, “Supramolecular 

Assemblies Based on Calixarenes,” Pure & Appl. Chem., 65, 1471 (1993). 

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439. R. K. Juneja, K. D. Robinson, C. P. Johnson, and J. L. Atwood, “Synthesis and 

Characterization of Rigid, Deep-Cavity Calix[4]arenes,” J. Am. Chem. Soc., 115, 

3818 (1993). 

440. J. L. Atwood, K. W. Butz, M. G. Gardiner, C. Jones, G. A. Koutsantonis, C. L. 

Raston, and K. D. Robinson, “Mixed-Donor and Monomeric N-Donor Adducts of 

Alane,” Inorg. Chem., 32, 3482 (1993). 

441. D. A. Atwood, A. H. Cowley, R. D. Hernandez, R. A. Jones, L. L. Rand, S. G. Bott, 

and J. L. Atwood, “Synthesis and Structural Characterization of a Homoleptic 

Bismuth Arenethiolate,” Inorg. Chem., 32, 2972 (1993). 

442. A. Razavi and J. L. Atwood, “Preparation and Crystal Structures of the 

Complexes(h5-C5H4CPh2-h5-C13H8)MCl2 (M = Zr, Hf) and the Catalytic 

Formation of High Molecular Weight High Tacticity Syndiotactic Polypropylene,”

J. Organomet. Chem., 459, 117 (1993). 

443. D. A. Atwood, V. O. Atwood, A. H. Cowley, H. R. Gobran, and J. L. Atwood, 

“Facile Transmetalation Reactions of Macrocyclic (C22H22N4) Complexes of 

Germanium(II), Tin(II), and Lead(II),” Inorg. Chem., 32, 4671 (1993). 

444. A. Razavi and J. L. Atwood, "Isospecific Propylene Polymerization with Unbridged 

Group 4 Metallocenes," J. Am. Chem. Soc., 115, 7529 (1993). 

445. R. D. Schluter, A. H. Cowley, D. A. Atwood, R. A. Jones, and J. L. Atwood, "An 

Alkyl-substituted indium(I) Tetramer," J. Coord. Chem., 30, 25 (1993). 

446. C. Scordilis-Kelley, K. D. Robinson, K. A. Belmore, J. L. Atwood, and R. T. 

Carlin, "Evidence for Hydrogen Bonds in 1,2-dimethyl-3-propylimidazolium 

Chloride and Its Chloroaluminate Molten Salts," J. Cryst. Spec. Res., 23, 601 

(1993). 

447. A. K. Singh, R. K. Juneja, J. L. Atwood, and R. J. Bridges, "Parasulfonatocalixarenes are Potent Blockers of Colonic Chloride Channels," Biophys. 

J., 64, A17 (1993). 

448. A. K. Singh, R. K. Juneja, R. Wang, J. L. Atwood, and R. J. Bridges, "TS-TMCalix[4]arene: A Subnanomolar Blocker of ORCC," Ped. Pulm., 9, 227 (1993). 

449. P. C. Junk and J. L. Atwood, “On the Crystal Structure of Hexathia-18-crown-6,” 

Supramol. Chem., 3, 241 (1994). 

450. A. Harton, M. K. Nagi, M. M. Glass, P. C. Junk, J. L. Atwood, and J. B. Vincent, 

“Synthesis and Characterization of Symmetric and Asymmetric Oxo-bridged 

Trinuclear Chromium Benzoate Complexes: Crystal and Molecular Structure of 

[Cr3O(O2CPh)6(py)3]ClO4,” Inorg. Chim. Acta, 217, 171 (1994). 

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451. J. L. Atwood, G. W. Orr, and K. D. Robinson, “First structural authentication of 

third-sphere coordination: [p-sulfonatocalix[4]arene]5- as a third-sphere ligand for 

Eu3+,” Supramol Chem., 3, 89 (1994). 

452. J. L. Atwood, S. M. Lawrence, and C. L. Raston, “N,N’-Di-tButylethylenediamine/ClnH3-nAlNMe3 Derivatives,”J. Chem. Soc., Chem. 

Commun., 73 (1994). 

453. J. L. Atwood, G. A. Koutsantonis, F.-C. Lee, and C. L. Raston, “A Thermally 

Stable Alane - Secondary Amine Adduct: [H3Al(2,2,6,6-Tetramethylpiperidine)],” 

J. Chem. Soc., Chem. Commun., 91 (1994). 

454. J. L. Atwood,. F.-C. Lee, C. L. Raston, and K. D. Robinson, “Bimetallic Aluminum 

and Gallium Derivatives of 1,1,1,5,5,5-Hexafluoropentane-2,4-dione via Selective 

Metallation/Hydrometallation,” J. Chem. Soc., Dalton Trans., 2019 (1994). 

455. J. L. Atwood, P. C. Junk, M. T. May, and K. D. Robinson, “Synthesis and X-ray 

Structure of [H3O+.18-crown-6][Br-Br-Br]; a Compound Containing both H3O+

and a Linear and Symmetrical Br3- Ion Crystallized from Aromatic Solution,” 

 J. Chem. Cryst., 24, 243 (1994). 

456. P. C. Junk and J. L. Atwood, “Synthesis and X-ray Structures of 

 [H3O+.18-crown-6]n[MCl4n-]; (M = Fe, n = 1; M = Co, n = 2); Compounds which 

Form Liquid Clathrates with Aromatic Solutions,” J. Chem. Cryst., 24, 247 (1994). 

457. J. L. Atwood, G. A. Koutsantonis, and C. L. Raston, “High Purity Fullerene-60 via 

Molecular Recognition,” Nature, 368, 229 (1994). 

458. J. W. Steed, P. C. Junk, J. L. Atwood, M. J. Barnes, C. L. Raston, and R. S. 

Burkhalter, “Ball and Socket Nano-Structures: New Supramolecular Chemistry 

Based on Cyclotriveratrylene,” J. Am. Chem. Soc., 116, 10346 (1994). 

459. J. W. Steed, R. K. Juneja, R. S. Burkhalter, and J. L. Atwood, “Synthesis of 

Cationic Organometallic Calixarene Hosts by Direct Metallation of the Outer 

Face,” J. Chem. Soc., Chem. Commun., 2205 (1994). 

460. J. L. Atwood, R. K. Juneja, P. C. Junk, and K. D. Robinson, “Structure of p-tertButylcalix[5]arene.Ethyl Acetate. A Polymeric Array of Neighbor-Included 

Calixarenes,” J. Chem. Cryst., 24, 573 (1994). 

461. Z. Hu, J. L. Atwood, and M. P. Cava, "A Simple Route to Sulfur Bridged 

Annulenes," J. Org. Chem., 59, 8071 (1994). 

462. J. L. Atwood, S. G. Bott, S. Harvey, and P. C. Junk, "Cationic, Neutral, and 

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Anionic Organoaluminum Species in [AlMe2.18-crown-6.AlMe2X][AlMeX3], (X 

= Cl, I)," Organometallics, 13, 4151 (1994). 

463. D. A. Atwood, V. O. Atwood, A. H. Cowley, R. A. Jones, J. L. Atwood, and S. G. 

Bott, "Synthesis and Structural Characterization of Homoleptic Gallium Amides," 

Inorg. Chem., 33, 3251 (1994). 

464. J. W. Steed, R. K. Juneja, and J. L. Atwood, "A Water-Soluble "Bear Trap" 

Exhibiting Strong Anion Complexation Properties," Angew. Chem. Int. Ed. Engl., 

33, 2456 (1994). 

465. J. L. Atwood, S. G. Bott, P. C. Junk, and M. T. May, “Liquid Clathrate Media 

Containing Transition Metal Halocarbonyl Anions,” J. Organomet. Chem., 487, 7 

(1995). 

466. H. Zhang, J. W. Steed, and J. L. Atwood, "Inclusion Chemistry of 

Cyclotetraveratrylene," Supramol. Chem., 4, 185 (1995). 

467. A. Razavi and J. L. Atwood, "Preparation and crystal structure of the complexes 

(h5-C5H3MeCMe2-h5-C13H8)MCl2 (M = Zr, Hf). Mechanistic aspects of 

catalytic formation of a syndio-iso-stereoblock type polypropylene," J. Organomet. 

Chem., 497, 105 (1995). 

468. P. C. Blake, M. F. Lappert, R. G. Taylor, J. L. Atwood, W. E. Hunter, and H. 

Zhang, "Synthesis, Spectroscopic Properties, and X-ray Structures of [MCp"2Cl2] 

[M = Th or U; Cp" = h-C5H3(SiMe3)2-1,3], [UCp"2X2] (X= Br, I or BH4," J. 

Chem. Soc., Dalton Trans., 3335 (1995). 

469. L. J. Barbour, J. W. Steed, and J. L. Atwood, "Inclusion Chemistry of 

Cyclotetracatechylene," J. Chem. Soc., Perkin Trans. 2 , 857 (1995). 

470. J. L. Atwood, L. J. Barbour, P. C. Junk, and G. W. Orr, "Structure of the Water 

Soluble p-Sulfonatocalix[4]arene which Acts as a Receptor for 

Tetramethylammonium Ions," Supramol. Chem., 5, 105 (1995). 

471. K. T. Holman, M. M. Halihan, J. W. Steed, S. S. Jurisson, and J. L. Atwood, 

"Hosting a Radioactive Guest: Binding of 99TcO4- by a Metallated 

Cyclotriveratrylene," J. Am. Chem. Soc., 117, 7848 (1995). 

472. J. L. Atwood and P. C. Junk, "Synthesis and X-ray Structure of 

 [H5O2+.21-Crown-7][WOCl5-]; a Complex in Which the 21-Crown-7 Molecule 

Adopts a Rigid, Bowlic Conformation," Chem. Comm., 1551 (1995). 

473. P. C. Junk, M. T. May, K. D. Robinson, L. MacGillivray, and J. L. Atwood, 

"Synthesis and X-ray Structure of [H3O+.18-crown-6][I7-]: A New Infinite SawCase 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 69 of 90 PageID: 4332
Horse Geometry for I7- Crystallized from a Liquid Clathrate Medium," Inorg. 

Chem., 34, 5395 (1995). 

474. L. R. MacGillivray and J. L. Atwood, "Proton Induced Chirality: Proton 

Complexation in the Chiral Cryptand [222-2H+] Dication Isolated from a Liquid 

Clathrate Medium," J. Org. Chem., 60, 4972 (1995). 

475. J. W. Steed, C. P. Johnson, C. L. Barnes, R. K. Juneja, J. L. Atwood, S. Reilly, R. 

L. Hollis, P. H. Smith, and D. L. Clark, "Supramolecular Chemistry of psulfonatocalix[5]arene: A Water Soluble, Bowl Shaped Host with a Large 

Molecular Cavity," J. Am. Chem. Soc., 117, 11426 (1995). 

476. A. Razavi, L. Peters, L. Nafpliotis, K. D. Daw, J. L. Atwood, and U. Thewald, "The 

Geometry of the Site and Its Relevance for Chain Migration and Stereospecificity," 

Macromol. Symp., 89, 345-67 (1995). 

477. A. Razavi, D. Vereecke, L. Petyers, K. D. Daw, L. Nafpliotis, and J. L. Atwood, 

"Manipulation of the Ligand Structure as an Effective and Versatile Tool for 

Modification of Active Site Properties in Homogeneous Ziegler-Natta Catalyst 

Systems," Ziegler Catal., 111-47 (1995). 

478. J. W. Steed, H. Zhang, and J. L. Atwood, “Inclusion Chemistry of 

Cyclotriveratrylene and Cyclotricatechylene,” Supramol. Chem., 7, 37 (1996). 

479. L. J. Barbour, L. R. MacGillivray, and J. L. Atwood, "Crystal and Molecular 

Structure of [H3O.18-crown-6]2[ReCl6] Isolated from a Liquid Clathrate Medium," 

J. Chem. Cryst., 26, 59 (1996). 

480. J. W. Steed, C. P. Johnson, R. K. Juneja, and J. L. Atwood "Anion Inclusion Within 

the Cavity of p-Metalated p-tert-butylcalix[5]arene," Supramol. Chem., 6, 235 

(1996). 

481. J. L. Atwood, S. G. Bott, P. C. Junk, and M. T. May, "Anionic Coordination 

Complexes of Mo and W which Crystallize from Liquid Clathrate Media with 

Oxonium Ion-Crown Ether Cations," J. Coord. Chem., 37, 89 (1996). 

482. J. L. Atwood, "An Introduction to the Crystallography of Supramolecular 

Compounds," in Crystallography of Supramolecular Compounds, Eds: G. 

Tsoucaris, J. L. Atwood, and J. Lipkowski, Kluwer, Dordrecht, 1996, pp. 1-6. 

483. J. L. Atwood, "Structural Models of Biological Significance from Supramolecular 

Systems," in Crystallography of Supramolecular Compounds, Eds: G. Tsoucaris, J. 

L. Atwood, and J. Lipkowski, Kluwer, Dordrecht, 1996, pp. 355-365. 

484. L. J. Barbour, L. R. MacGillivray, and J. L. Atwood, "Structural Consequences of 

M-Cl...H-N Hydrogen Bonds in Substituted Pyridinium Salts of the 

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Cobalt(II)tetrachloride Anion Isolated from Liquid Clathrate Media," Supramol. 

Chem., 7, 167 (1996). 

485. L. R. MacGillivray and J. L. Atwood, "Insight into the Mechanism of the 

Protonation of Cryptand 222 within a Liquid Clathrate Medium: Synthesis and Xray Crystal Structure of [H3O][222-2H][(CoCl3)2(m-Cl)]," J. Chem. Soc., Chem. 

Commun., 735 (1996). 

486. C. P. Johnson, J. L. Atwood, J. W. Steed, C. B. Bauer, and R. D. Rogers, 

"Transition Metal Complexes of p-Sulfonatocalix[5]arene," Inorg. Chem., 35, 2602 

(1996). 

487. L. J. Barbour, A. Damon, G. W. Orr, and J. L. Atwood, "Inclusion of Protonated 

Organic Species by p-Sulfonatocalix[4]arene anions. Crystal and Molecular 

Structure of the Inclusion Compounds (Na)2[Cu(H2O)4(psulfonatocalix[4]arene)2][Cu(H2O)4(pyridine)2](pyridinium)2.10H2O and 

Na4(morpholinium)[p-sulfonatocalix[4]arene].8H2O," Supramol. Chem., 7, 209 

(1996). 

488. J. L. Atwood, "Diffraction Studies of Supramolecular Compounds," in Physical 

Supramolecular Chemistry, Eds.: L. Echegoyen and A. Kaifer, Kluwer, Dordrecht, 

1996, pp 261-272. 

489. J. L. Atwood, P. C. Junk, S. M. Lawrence, and C. L. Raston, "Zinc Dimerization of 

p-tert-butylcalix[4]arene," Supramol. Chem., 7, 15 (1996). 

490. J. L. Atwood, M. G. Gardiner, C. Jones, C. L. Raston, B. W. Skelton, and A. H. 

White, "Trimethylaluminum and -gallium Derivatives of Calix[4]arenes: Cone 

(Mono-metallic) or Doubly Flattened Partial Cone (Tetra-metallic) Conformations," 

J. Chem. Soc., Chem. Commun., 2487 (1996). 

491. J. L. Atwood, C. Jones, C. L. Raston, and K. D. Robinson, "The First Structural 

Characterization of a Five Coordinate Aluminum Trichloride - Bidentate Tertiary 

Amine Adduct, Trichloro(1,4-dimethylpiperazine)aluminum," Main Group Chem., 

1, 345 (1996). 

492. J. L. Atwood, L. J. Barbour, E. S. Dawson, P. C. Junk, and J. Kienzle, "X-ray 

Structure of the Water Soluble Adeninium p-Sulfonatocalix[4]arene which Displays 

Cationic and Anionic Bilayers," Supramol. Chem., 7, 271 (1996). 

493. J. L. Atwood, M. J. Barnes, M. G. Gardiner, and C. L. Raston, "Cyclotriveratrylene 

Polarisation Assisted Aggregation of C60," J. Chem. Soc., Chem. Commun., 1449 

(1996). 

494. C. L. Raston, J. L. Atwood, P. J. Nichols, and I. B. N. Sudria, "Supramolecular 

Encapsulation of Aggregates of C60," J. Chem. Soc., Chem. Commun., 2615 

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(1996). 

495. J. L. Atwood, K. T. Holman, and J. W. Steed, "Laying Traps for Elusive Prey: 

Recent Advances in the Non-Covalent Binding of Anions," J. Chem. Soc., Chem. 

Commun., 1401 (1996). 

496. L. R. MacGillivray and J. L. Atwood, "Structural Reorganization of the 

 [222-2H]2+ Dication Through Cation-p and Charge-Charge Interactions: Synthesis 

and Structure of Its [CoCl4].0.5 C6H5CH3 Salt," 

Angew. Chem. Int. Ed. Engl., 35, 1828 (1996). 

497. K. T. Holman, M. M. Halihan, S. S. Jurisson, J. L. Atwood, R. S. Burkhalter, A. R. 

Mitchell, and J. W. Steed, "Inclusion of Neutral and Anionic Guests within the 

Cavity of p-Metallated Cyclotriveratrylenes," J. Am. Chem. Soc., 118, 9567 (1996). 

498. A. D. Hunter, R. Chukwu, B. D. Santarsiero, S. G. Bott, and J. L. Atwood, 

"Synthesis and Characterization of Polyaromatic Azine Derivatives of (h5-

C5H5)Fe(CO)2 and (h5-C9H7)Fe(CO)2," J. Organomet. Chem., 526, 1 (1996). 

499. A. Razavi and J. L. Atwood, "Synthesis and Characterization of the Catalytic 

Isotactic-specific Metallocene [C4H9-C5H3-C(CH3)2-(C13H8)ZrCl2]. 

Mechanistic Aspects of the Formation of Isotactic Polypropylene, the 

Stereoregulative Effect of the Distal Substituent and the Relevance of C2

Symmetry, J. Organomet. Chem., 520, 115 (1996). 

500. J. L. Atwood, P. C. Junk, M. T. May, and K. D. Robinson, "New, Simple 

Coordination Compounds of Cr, Mo, and W from Liquid Clathrate Media," J. 

Coord. Chem., 40, 247 (1996). 

501. C. Li, J. C. Medina, E. Abel, J. L. Atwood, and G. W. Gokel, "Neutral Molecule 

Receptor Systems using Ferrocene's "Atomic Ball Bearing" Character as the 

Flexible Element," J. Am. Chem. Soc., 119, 1609 (1997). 

502. L. R. MacGillivray and J. L. Atwood, "Molecular Recognition of the Cyclic Water 

Trimer in the Solid State," J. Am. Chem. Soc., 119, 2592 (1997). 

503. L. R. MacGillivray and J. L. Atwood, "Ether Cleavage of [2.2.2]cryptand: 

Synthesis and X-ray Crystal Structure of [NH(CH2CH2I)3][I5]," J. Chem. Cryst., 

27, 209 (1997). 

504. K. T. Holman, J. W. Steed, and J. L. Atwood, "Intra-cavity Inclusion of 

[CpFeII(arene)]+ Guests by Cyclotriveratrylene," Angew. Chem. Int. Ed. Engl., 36, 

1736 (1997). 

505. L. R. MacGillivray and J. L. Atwood, "Structural Consequences of Competing 

Noncovalent Forces: the out-out Conformation of the Doubly Protonated 

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[2.2.2]cryptand," Chem. Commun., 477 (1997). 

506. L. J. Barbour, G. W. Orr, and J. L. Atwood, "Supramolecular Intercalation of C60

into a Calixarene Bilayer - a Well-Ordered Solid-State Structure Dominated by van 

der Waals Contacts," Chem. Commun., 1439 (1997). 

507. M. Staffilani, K. S. B. Hancock, J. W. Steed, K. T. Holman, J. L. Atwood, R. K. 

Juneja, and R. S. Burkhalter, "Anion Binding within the Cavity of p-Metalated 

Calixarenes," J. Am. Chem. Soc., 119, 6324 (1997). 

508. L. R. MacGillivray and J. L. Atwood, "Rational Design of Multi-Component 

Calix[4]arenes and Control of Their Alignment in the Solid State," J. Am. Chem. 

Soc., 119, 6931 (1997). 

509. K. T. Holman, J. L. Atwood, and J. W. Steed, "Supramolecular Anion Receptors," 

in Advances in Supramolecular Chemistry, Vol. 4, G. W. Gokel, Ed., JAI 

Publications, New York, 287 (1997). 

510. L. R. MacGillivray and J. L. Atwood, "A Chiral Spherical Molecular Assembly 

Held Together by 60 Hydrogen Bonds," Nature, 389, 469 (1997). 

C&EN, October 6, 1997, p. 12 

511. L. R. MacGillivray and J. L. Atwood, "Synthesis and Structure of (H2O)(12-crown4)Co(II)(Co(II)Cl3)(m-Cl) Isolated from a Liquid Clathrate Medium," J. Chem. 

Cryst., 27, 453 (1997). 

512. J. L. Atwood and J. W. Steed, "Structural and Topological Aspects of Anion 

Coordination," in Supramolecular Chemistry of Anions, A. Bianchi, K. BowmanJames, E. Garcia-Espana, Eds., Wiley-VCH, New York (1997). 

513. J. L. Atwood and P. C. Junk, "Synthesis and X-ray Structure of Oxonium Ion 

Complexes of 21-Crown-7 and Dibenzo-30-crown-10," J. Chem. Soc., Dalton 

Trans., 4393 (1997). 

514. J. L. Atwood and P. C. Junk, "Use of Metal Carbonyls in the Formation of H5O2+

in [H5O2+.15-Crown-5][MOCl4(H2O)-], (M=Mo, W), and a Second Sphere 

Coordination Complex in [mer-CrCl3(H2O)3.15-Crown-5]," 

J. Organomet. Chem., 565, 179 (1998). 

515. M. Staffilani, G. Bonvicini, J. W. Steed, K. T. Holman, J. L. Atwood, and M. R. J. 

Elsegood, "Bowl vs. Saddle Conformations in Cyclononatriene-based Anion 

Binding Hosts," Organometallics , 17, 1732 (1998). 

516. J. L. Atwood, L. J. Barbour, C. L. Raston, and I. B. N. Sudria, "Assemblies of C60

and C70 in the Molecular Pincer-Like Jaws of Calix[6]arene," Angew. Chem. Int. 

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Ed. Engl., 37, 981 (1998). 

517. P. C. Andrews, J. L. Atwood, L. J. Barbour, P. J. Nichols, and C. L. Raston, "Rigid 

Concave Surfaces: An Entry to Confinement of Globular Molecules, " Chem. Eur. 

J., 4, 1384 (1998). 

518. K. N. Rose, L. J. Barbour, G. W. Orr, and J. L. Atwood, "Self-Assembly of 

Carcerand-Like Dimers of Calix[4]resorcinarene Facilitated by Hydrogen Bonded 

Solvent Bridges," Chem. Commun., 407 (1998). 

519. L. J. Barbour, G. W. Orr, and J. L. Atwood, "Supramolecular Assembly of WellSeparated, Linear Columns of Closely Spaced C60 Molecules Facilitated by Dipole 

Induction," Chem. Commun., 1901 (1998). 

 C&EN, Science/Technology Concentrates, September 14, 1998, p. 28. 

520. A. Alvanipour, J. L. Atwood, S. G. Bott, P. C. Junk, U. H. Kynast, and H. Prinz, 

"Some Crown Ether Chemistry of Ti, Zr, and Hf Derived from Liquid Clathrate 

Media, " J. Chem. Soc., Dalton Trans., 1223 (1998). 

521. L. R. MacGillivray, K. T. Holman, and J. L. Atwood, "One-Dimensional Hydrogen 

Bonded Polymers Based on c-Methylcalix[4]resorcinarene and a Crystal 

Engineering Design Strategy," Cryst. Eng., 1, 87 (1998). 

522. P. C. Junk and J. L. Atwood, "Hydrogen-bonded Tetramethylethylenediammonium 

and Triphenylphosphonium 

 Complexes Derived from Liquid Clathrate Media," J. Coord. Chem., 46, 505 

 (1998). 

523. L. R. MacGillivray, R. H. Groeneman, and J. L. Atwood, "Design and SelfAssembly of Cavity-Containing Rectangular Grids," J. Am. Chem. Soc., 120, 2676 

(1998). 

524. E. Abel, R. Castro, I. M. McRobbie, L. Barbour, J. L. Atwood, A. E. Kaifer, and G. 

W. Gokel, "A Redox-Switchable Molecular Receptor Based on 

 Anthraquinone," Supramol. Chem., 9, 199 (1998). 

525. K. T. Holman, G. W. Orr, J. W. Steed, and J. L. Atwood, "Deep Cavity 

[CpFe(arene)]+

-Based Anion Hosts," Chem. Commun., 2109 (1998). 

526. P. C. Blake, M. A. Edelman, P. B. Hitchcock, J. Hu, M. F. Lappert, S. Tian, G. 

Muller, J. L. Atwood, and H. Zhang, "Organometallic Chemistry of the Actinides. 

Part 4. The Chemistry of Some Tris(cyclopentadienyl)actinide Complexes," 

J. Organometal. Chem., 551, 261 (1998). 

527. J. L. Atwood, L. R. MacGillivray, K. N. Rose, L. J. Barbour, K. T. Holman, and G. 

W. Orr, "Large Molecular Assemblies Held Together by Non-Covalent Bonds," in 

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Physical Methods of Characterization of Supramolecular Assemblies, Ed.: G. 

Tsoucaris, Dordrecht, 7 (1998). 

528. L. J. Barbour, G. W. Orr, and J. L. Atwood, "An Intermolecular (H2O)10 Cluster in 

a Solid-State Supramolecular Complex," Nature, 393, 671 (1998). 

529. R. H. Groeneman, L. R. MacGillivray, and J. L. Atwood, "Aromatic Inclusion 

within a Neutral Cavity-Containing Rectangular Grid," Chem. Commun., 2735 

(1998). 

530. L. J. Barbour and J. L. Atwood, "RES2INS: a Graphical Interface for the SHELX 

Program Suite," J. Appl. Cryst., 31, 963 (1998). 

531. L. R. MacGillivray, K. T. Holman, and J. L. Atwood, "Multi-Guest Inclusion within 

One-Dimensional Hydrogen Bonded Polymers Based on CMethylcalix[4]resorcinarene," Am. Cryst. Assoc. Trans., 33, 129 (1998). 

532. J. L. Atwood, L. J. Barbour, P. J. Nichols, C. L. Raston, and C. A. Sandoval, 

"Symmetry-Aligned Supramolecular Encapsulation of C60; [C60 > (L)2]. L = pBenzylcalix[5]arene or p-Benzylhexahomooxacalix[3]arene," Chem. Eur. J., 5, 990 

(1999). 

533. L. R. MacGillivray and J. L. Atwood, "Structural Classification and General 

Principles for the Design of Spherical Molecular Hosts," Angew. Chem., Int. Ed. 

Engl., 38, 1018 (1999). 

534. R. H. Groeneman, L. R. MacGillivray, and J. L. Atwood, "One-Dimensional 

Coordination Polymers Based upon Bridging Terephthalate Ions," Inorg. Chem., 

38, 208 (1999). 

535. P. C. Andrews, J. L. Atwood, L. J. Barbour, P. D. Croucher, P. J. Nichols, N. O. 

Smith, B. W. Skelton, A. H. White, and C. L. Raston, "Supramolecular 

Confinement of C60, S8, P4Se3, and Toluene by Metal(II) Macrocyclic 

Complexes," J. Chem. Soc., Dalton Trans., 2927 (1999). 

536. G. W. Orr, L. J. Barbour, and J. L. Atwood, "Controlling Molecular SelfOrganization: Formation of Nanometer-Scale Spheres and Tubules," 

Science, 285, 1049 (1999). 

 C&EN, News of the Week, August 16, 1999, p. 5. 

 

 Cover Illustration 

537. R. H. Groeneman and J. L. Atwood, "Terephthalate Bridged Coordination Polymers 

Based Upon Group Two Metals," Cryst. Eng., 2, 241 (1999). 

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538. L. R. MacGillivray and J. L. Atwood, "Unique Guest Inclusion within MultiComponent, Extended-Cavity Resorcin[4]arenes," Chem. Commun., 181 (1999). 

539. L. R. MacGillivray, J. L. Reid, J. L. Atwood, and J. A. Ripmeester, "Vinyl-Group 

Alignment Along the Upper Rim of a Multi-Component Resorcin[4]arene," Cryst. 

Eng., 2, 47 (1999). 

540. L. R. MacGillivray and J. L. Atwood, "Discrete and Infinite Host Frameworks 

Based upon Resorcin[4]arenes by Design," in Crystal Engineering: From 

Molecules and Crystals to Materials, Ed. A. G. Orpen and D. Braga, 407-419, 

Kluwer, The Netherlands, 1999. 

541. L. R. MacGillivray and J. L. Atwood, "Spherical Molecular Containers: From 

Discovery to Design," in Adv. Supramol. Chem., Vol. 6; Ed.: G. W. Gokel; JAI, 

157-183 (1999). 

542. J. L. Atwood, "Crystal Engineering Based on Diffraction Studies of Supramolecular 

Compounds," in Crystal Engineering, Ed. K. R. Seddon and M. Zaworotko, 371-

381, Kluwer, The Netherlands, 1999. 

543. J. L. Atwood, M. J. Hardie, C. L. Raston, and C. A. Sandoval, "Convergent 

Synthesis of p-Benzylcalix[7]arene: Condensation and UHIG of p-Benzylcalix[6 or 

8]arenes," Organic Lett., 1, 1523 (1999). 

544. J. L. Atwood and P. C. Junk, "Synthesis and X-ray Crystal Structures of Novel 

Oxonium Ion-12-Crown-4 Complexes Isolated from Liquid Clathrate Media," J. 

Coord. Chem., 51, 379 (2000). 

545. L. R. MacGillivray and J. L. Atwood, "Hydrogen Bonded Cavities Based upon 

Resorcin[4]arenes by Design," in Calixarenes for Separations; Ed.: G. L. Lumetta, 

R. D. Rogers, and A. S. Gopalan, ACS, 325-340, 2000. 

546. L. R. MacGillivray and J. L. Atwood, "Cavity-Containing Materials Based Upon 

Resorcin[4]arenes by Discovery and Design," J. Solid State Chem., 152, 199 

(2000). 

547. R. A. Groeneman and J. L. Atwood, "Self-Assembly of a Novel One-Dimensional 

Zig-Zag Coordination Polymer," Supramol. Chem., 11, 251 (2000). 

548. L. R. MacGillivray and J. L. Atwood, "The 'Boat' Conformation of a 

Resoprcin[4]arene Self-assembles as a 'T-Shaped' Building Block in the Solid State 

to Form a Linear 1D Hydrogen-Bonded Array," Supramol. Chem., 11, 293 (2000). 

549. L. R. Barbour, G. W. Orr, and J. L. Atwood, "Characterization of a Well Resolved 

Supramolecular Ice-Like (H2O)10 Cluster in the Solid State," Chem. Comm., 859 

(2000). 

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550. Z. Chen, J. Wang, V. S. Gopalaratnam, B. Orr, and J. L. Atwood, "Thermal 

Measurement Associated with Material Failure Using Thermochromic Coatings," 

Experimental Techniques, 24, 29 (2000). 

551. J. L. Atwood and P. C. Junk, "Formation and Crystal Structures of Novel Sevencoordinate 15-crown-5 Complexes of Manganese(II), Iron(II) and Cobalt(II) 

 Polyhedron, 19, 85 (2000). 

552. E. Elisabeth, L. J. Barbour, G. W. Orr, K. T. Holman, and J. L. Atwood, "Synthesis 

and Structure of a One Dimensional Coordination Polymer Based Upon 

Tetracyanocalix[4]arene in the Cone Conformation," Supramol. Chem., 12, 317 

(2000). 

553. M. S. Selvan, M. D. McKinley, R. H. Dubois, and J. L. Atwood, "Liquid-Liquid 

Equilibria for Toluene plus Heptane + 1-Ethyl-3-methylimidazolium Triiodide and 

Toluene plus Heptane + 1-Butyl-3-methylimidazolium Triiodide," J. Chem. Eng. 

Data, 45, 841 (2000). 

554. L. R. MacGillivray and J. L. Atwood, "Spherical Molecular Assemblies: A Class 

of Hosts for the Next Millennium," in Chemistry for the 21st Century.; Ed.: E. 

Keinan and I. Schechter, Wiley-VCH, 130-150, 2001. 

555. A. M. Bond, W. Miao, C. L. Raston, T. J. Ness, M. J. Barnes, and J. L. Atwood, 

"Electrochemical and Structural Studies on Microcrystals of the (C60)x(CTV) 

Inclusion Complexes (x = 1, 1.5; CTV = Cyclotriveratrylene)," J. Phys. Chem. B, 

105, 1687 (2001). 

556. R. H. Groeneman and J. L. Atwood, "Controlling Aromatic Inclusion within 

NonAqueous Copper Iodide Coordination Polymers," Supramol. Chem., 12, 353 

(2001). 

557. J. L. Atwood, L. J. Barbour, M. J. Hardie, C. L. Raston, M. N. Statton, and H. R. 

Webb, "Hetero-bimetallic Cage Molecules: Solvated Na2M2(psulfonatocalix[4]arene)2, M = Y, Eu," Cryst. Eng. Comm., 4, 1 (2001). 

558. J. L. Atwood, L. J. Barbour, M. J. Hardie, and C. L. Raston, "Metal 

Sulfonatocalixarene Complexes: Bi-layers, Capsules, Spheres, Tubular Arrays and 

Beyond," Coord. Chem. Rev., 222, 3 (2001). 

559. J. L. Atwood, L. J. Barbour, and A. Jerga, "Hydrogen-Bonded Molecular Capsules 

are Stable in Polar Media," Chem. Comm., 2376 (2001). 

560. J. L. Atwood, L. J. Barbour, M. J. Hardie, E. Lygris, C. L. Raston, and H. R. Webb, 

"Inclusion Complexes of 18-Crown-6 and (Na+.[2.2.2]cryptand) in [CMethylcalix[4]resorcinarene-Hn], n = 0, 1," Cryst. Eng. Comm., 10 (2001). 

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561. J. L. Atwood, L. J. Barbour, T. J. Ness, C. L. Raston, and P. L. Raston, "A Well 

Resolved Ice-Like (H2O)8 Cluster in an Organic Supramolecular Complex," J. Am. 

Chem. Soc., 123, 7192 (2001). 

562. K. N. Rose, M. J. Hardie, J. L. Atwood, and C. L. Raston, "Oxygen-center Laden 

C2h Symmetry Resorcin[4]arenes," J. Supramol. Chem., 1, 35 (2001). 

563. L. J. Barbour and J. L. Atwood, "Non-covalent Interactions Exert Extraordinary 

Influence Over Conformation and Properties of a Well-Known Supramolecular 

Building Block," Chem. Comm., 2020 (2001). 

564. J. L. Atwood, L. J. Barbour, and A. Jerga, "On the Synthesis and Structure of the 

Very Large Spherical Capsules Derived from Hexamers of Pyrogallol[4]arenes," 

J. Supramol. Chem., 1, 131 (2001). 

565. L. R. MacGillivray, K. T. Holman, and J. L. Atwood, "Hydrogen Bonds Assist the 

Organization of Up to 11 Guests within Self-Assembling Cavities of Nanometer 

Dimensions," J. Supramol. Chem., 1, 125 (2001). 

566. J. L. Atwood, T. Ness, P. J. Nichols, and C. L. Raston, "Confinement of Amino 

Acids in Tetra-p-sulfonated Calix[4]arene Bi-layers," Cryst. Growth & Design, 2, 

171 (2002). 

567. J. L. Atwood, L. J. Barbour, and C. L. Raston, "Supramolecular Organization of 

C60 into Linear Columns of Five-Fold, Z-Shaped Strands," Cryst. Growth & 

Design, 2, 3 (2002). 

568. J. L. Atwood, L. J. Barbour, and A. Jerga, "Organization of the Interior of 

Molecular Capsules by Hydrogen Bonding," Proc. Natl. Acad. Sci., 99, 4837 

(2002). 

569. J. L. Atwood, L. J. Barbour, and A. Jerga, "Supramolecular Stabilization of N2H7

+

," 

J. Am. Chem. Soc., 124, 2122 (2002). 

570. J. L. Atwood, L. J. Barbour, and A. Jerga, "Storage of Methane and Freon by 

Interstitial van der Waals Confinement," Science, 296, 2367 (2002). 

Science Express, May 9, 2002, www.sciencexpress.org 

C&EN, July 8, 2002, p. 27 

C&EN, Chemistry Highlights 2002, December 22, 2003, p. 47 

 Highlights, Angew. Chem. Int. Ed. Engl., 42, 1686 (2003) 

571. J. L. Atwood, L. J. Barbour, S. Dalgarno, C. L. Raston, and H. R. Webb, 

"Supramolecular Assemblies of p-Sulfonatocalix[4]arene with Aquated Trivalent 

Case 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 78 of 90 PageID: 4341
Lanthanide Ions," Dalton Trans., 4351 (2002). 

572. J. L. Atwood and A. Szumna, "Hydrogen Bonds Seal Single-Molecule Molecular 

Capsules," J. Am. Chem. Soc., 124, 10646 (2002). 

573. J. L. Atwood, L. J. Barbour, A. Jerga, and B. L. Schottel, "Guest Transport in a 

Non-Porous Organic Solid via Dynamic van der Waals Cooperativity," Science, 

298, 1000 (2002). 

Science Perspectives, J. W. Steed, 298, 976 (2002) 

C&EN, November 4, 2002, p. 8 

C&EN, Chemistry Highlights 2002, December 22, 2003, p. 47. 

574. J. L. Atwood, "Kagome Lattice: A Molecular Toolkit for Magnetism," Nature 

Materials, 1, 91 (2002). 

575. J. L. Atwood, L. J. Barbour, and A. Jerga, "Polymorphism of Pure p-tertButylcalix[4]arene: Conclusive Identification of the Phase Obtained by 

Desolvation," Chem. Comm., 2952 (2002). 

576. J. A. Gawenis, K. T. Holman, J. L. Atwood, and S. S. Jurisson, "Extraction of 

Pertechnetate and Perrhenate from Water with Deep-Cavity [CpFe(arene)]+-

Derivatized Cyclotriveratrylenes," Inorg. Chem., 41, 6028 (2002). 

577. J. L. Atwood, L. J. Barbour, M. W. Heaven, and C. L. Raston, "Synthesis of 2-

Imino-5-phenylimidazolidin-4-one and the Structure of Its Trifluoroacetate Salt," J. 

Chem. Cryst., 33, 175 (2003). 

578. J. L. Atwood and A. Szumna, "Cation-p Interactions in Neutral Resorcin[4]arenes," 

J. Supramol. Chem., 2, 421 (2003). 

579. J. L. Atwood and L. J. Barbour, "Molecular Graphics: From Science to Art," Cryst. 

Growth Des., 3, 3 (2003). 

 Cover Illustration (Cover design used for all 2003 issues.) 

580. Z. Chen, J. L. Atwood, and Y.-W. Mai, "Rate-Dependent Transition from Thermal 

Softening to Hardening in Elastomers," J. Applied Mechanics, 70, 611 (2003). 

581. J. L. Atwood and A. Szumna, "Anion-Sealed Single-Molecule Capsules," Chem. 

Comm., 940 (2003). 

C&EN, News of the Week, April 14, 2003, p. 11. 

C&EN, Chemistry Highlights 2003, December 22, 2003, p. 47. 

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582. J. L. Atwood, L. J. Barbour, M. W. Heaven, and C. L. Raston, "Association and 

Orientation of C70 Complexation with Calix[5]arene," Chem. Comm., 2270 (2003). 

583. M. W. Heaven, L. J. Barbour, J. L. Atwood, and C. L. Raston, "Controlling the van 

der Waals Connectivity of Fullerene C60," Angew. Chem. Int. Ed. Engl., 42, 3254 

(2003). 

584. J. L. Atwood, L. J. Barbour, and A. Jerga, "A New Class of Material for the 

Recovery of Hydrogen from Gas Mixtures," Angew. Chem. Int. Ed. Engl., 43, 2948 

(2004). 

C&EN, News of the Week, May 31, 2004, p. 7. 

Science News, June 12, 2004, pp. 380-381. 

585. J. L. Atwood, S. J. Dalgarno, M. J. Hardie, and C. L. Raston, "Hydrogen-Bonded 

Arrays of a Ytterbium(III) p-sulfonatocalix[6]arene Complex," New J. Chem., 28, 

326 (2004). 

586. K. S. Chichak, S. J. Cantrill, A. R. Pease, S.-h. Chiiu, G. W. V. Cave, J. L. Atwood, 

and J. F. Stoddart, "Molecular Borromean Rings," Science, 304, 1308 (2004). 

C&EN, News of the Week, May 31, 2004, p. 5. 

C&EN, Chemistry Highlights 2004, December 20, 2004, p. 60-61. 

587. S. J. Dalgarno, M. J. Hardie, J. L. Atwood, and C. L. Raston, "Bilayers, Corrugated 

Bilayers, and Coordination Polymers of p-Sulfonatocalix[6]arene,"Inorg. Chem., 

43, 6351 (2004). 

588. J. L. Atwood, L. J. Barbour, S. J. Dalgarno, M. J. Hardie, C. L. Raston, and H. R. 

Webb, "Toward Mimicking Viral Geometry with Metal-Organic Systems," J. Am. 

Chem. Soc., 126, 13170 (2004). 

589. G. W. V. Cave, J. Antesberger, L. J. Barbour, R. M. McKinlay, and J. L. Atwood, 

"Inner Core Structure Responds to Communication between nanocapsule Walls," 

Angew. Chem. Int. Ed. Engl., 43, 5263 (2004). 

 Cover Illustration 

C&EN, Science & Technology, January 3, 2005, 30-32 

590. J. L. Atwood, L. J. Barbour, G. O. Lloyd, and P. K. Thallapally, "Polymorphism of 

Pure p-tert-Butylcalix[4]arene: Subtle Thermally-Induced Modifications," Chem. 

Comm., 922 (2004). 

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591. G. W. V. Cave, M. C. Ferrarelli, and J. L. Atwood, "A Supramolecular Approach to 

Deepening the Pyrogallol[4]arene Cavity: Nano-Cups," Chem. Comm., 2787 

(2005). 

592. J. L. Atwood, L. J. Barbour, P. K. Thallapally, and T. B. Wirsig, "A Crystalline 

Organic Substrate Absorbs Methane under STP Conditions," Chem. Comm., 51 

(2005). 

Materials Research Society Bulletin, 30, 2005, 154-155 

593. S. J. Dalgarno, M. J. Hardie, J. L. Atwood, J. E. Warren, and C. L. Raston, "A 

Complex 3-D 'wavy brick wall' Coordination Polymer Based on pSulfonatocalix[8]arene," New. J. Chem., 29, 649 (2005). 

594. J. Antesberger, G. W. V. Cave, M. C. Ferrarelli, M. W. Heaven, C. L. Raston, and 

J. L. Atwood, "Solvent-free, direct synthesis of supramolecular nano-capsules," 

Chem. Comm., 892 (2005). 

595. G. O. Lloyd, J. L. Atwood, and L. J. Barbour, "Water-assisted self-assembly of 

harmonic single and triple helices in a polymeric coordination complex," Chem. 

Comm., 1845 (2005). 

596. J. L. Atwood, S. J. Dalgarno, M. J. Hardie, and C. L. Raston, "Selective single 

crystal complexation of L- or D-leucine by p-sulfonatocalix[6]arene," Chem. 

Comm., 337 (2005). 

597. J. L. Atwood, G. W. V. Cave, and R. M. McKinlay, "A Supramolecular Blueprint 

Approach to Metal-Coordinated Capsules," PNAS, 102, 5944 (2005). 

598. P. K. Thallapally, G. O. Lloyd, T. B. Wirsig, M. W. Bredenkamp, J. L. Atwood, 

and L. J. Barbour, "Organic Crystals Absorb Hydrogen Gas under Mild 

Conditions,"Chem. Comm., 5272 (2005). 

599. P. K. Thallapally, G. O. Lloyd, J. L. Atwood, and L. J. Barbour, "Diffusion of 

Water in a Nonporous Hydrophobic Crystal," Angew. Chem. Int. Ed. Engl., 44, 

3848 (2005). 

 Editors' Choice, Science, 308, 1521 (2005). 

600. R. M. McKinlay, P. K. Thallapally, G. W. V. Cave, and J. L. Atwood, "Hydrogen 

Bonded Supramolecular Assemblies as Robust Templates in the Synthesis of Large 

Metal-Coordinated Capsules," Angew. Chem. Int. Ed. Engl., 44, 5733 (2005). 

601. P. K. Thallapally, T. B. Wirsig, L. J. Barbour, and J. L. Atwood, "Crystal 

Engineering of Non-porous Organic Solids for Methane Sorption," Chem. Comm., 

4420 (2005). 

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602. S. J. Dalgarno, D. B. Bassil, S. A. Tucker, and J. L. Atwood, "Fluorescent Probe 

Molecules Report Ordered Inner Phase of Nano-Capsules in Solution," Science, 

309, 2037 (2005). 

603. S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Host-Guest Complexes with pSulfonatocalix[4,5]arenes, Charged crown Ethers and Lanthanides: Factors 

Affecting Molecular Capsule Formation," Cryst. Growth Des., 6, 174 (2006). 

604. S. J. Dalgarno, G. W. V. Cave, and J. L. Atwood, "Toward the Isolation of 

Functional Organic Nano-tubes," Angew. Chem. Int. Ed. Engl., 45, 570 (2006). 

605. P. K. Thallapally, L. Dobrzanska, T. R. Gingrich, T. B. Wirsig, L. J. Barbour, and 

 J. L. Atwood, "Acetylene Absorption and Binding in a Nonporous Crystal Lattice," 

Angew. Chem. Int. Ed. Engl., 45, 6506 (2006). 

606. M. W. Heaven, G. W. V. Cave, R. M. McKinlay, J. Antesberger, S. J. Dalgarno, P. 

K. Thallapally, and J. L Atwood, "Hydrogen Bonded Hexamers Self-Assemble as 

Spherical and Tubular Superstructures on the Sub-Micron Scale," Angew. Chem. 

Int. Ed. Engl., 45, 6221 (2006). 

607. S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Sulfonatocalixarenes: Molecular 

Capsule and 'Russian Doll' Arrays to Structures Mimicking Viral Geometry," 

Chem. Comm., 4567 (2006). 

608. S. J. Dalgarno, N. P. Power, J. Antesberger, R. M. McKinlay, and J. L. Atwood, 

"Synthesis and Structural Characterisation of Lower Rim Halogenated 

Pyrogallol[4]arenes: Bi-layers and Hexameric Nano-capsules," Chem. Comm., 

3803 (2006). 

609. S. J. Dalgarno, D. B. Bassil, S. A. Tucker, and J. L. Atwood, "Cocrystallization and 

Encapsulation of a Fluorophore with Hexameric Pyrogallol[4]arene Nano-capsules: 

Structural and Fluorescence Studies," Angew. Chem. Int. Ed. Engl., 45, 7019 

(2006). 

610. P. K. Thallapally, S. J. Dalgarno, and J. L. Atwood, "Frustrated Organic Solids 

Display Unexpected Gas Sorption," J. Amer. Chem. Soc., 128, 15060 (2006). 

C&EN, News of the Week, November 13, 2006, 14 

611. R. M. McKinlay and J. L. Atwood, "Hexameric C-alkylpyrogallol[4]arene 

Molecular Capsules Sustained by Metal-ion Coordination and Hydrogen Bonds," 

Chem. Comm., 2956 (2006). 

612. P. K. Thallapally and J. L. Atwood, "Sorption of Nitrogen Oxides (NOx's) in a 

Nonporous Crystal Lattice," Chem. Comm., 1521 (2007). 

Chemistry World, Chemical Sciences, March 28, 2007 

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613. S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Synthesis and Structural 

Characterisation of Two Polynuclear Hafnium (IV) Complexes," Inorg. Chim. Acta, 

360, 1344 (2007). 

614. P. K. Thallapally, K. A. Kirby, and J. L. Atwood, "Comparison of Porous and 

Nonporous Materials for Gas Storage," New J. Chem., 31, 629 (2007). 

615. S. J. Dalgarno, P. K. Thallapally, L. J. Barbour, and J. L. Atwood, "Engineering 

Void Space in Organic van der Waals Crystals: Calixarenes Lead the Way", Chem. 

Soc. Rev., 36, 236 (2007). 

616. N. P. Power, S. J. Dalgarno, and J. L. Atwood, "Robust and Stable 

Pyrogallol[4]arene Molecular Capsules Facilitated via an Octanuclear Zinc 

Coordination Belt," New J. Chem., 31,17 (2007). 

 Cover Illustration 

617. S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Structural Versatility in 

Praseodymium Complexes of p-Sulfonatocalix[4]arene," Cryst. Growth Des., 7, 

1762 (2007). 

618. R. M. McKinlay and J. L. Atwood, "Hydrogen-Bonded Hexameric Nanotoroidal 

Assembly," Angew. Chem. Int. Ed. Engl., 46, 2394 (2007). 

619. R. M. McKinlay, S. J. Dalgarno, P. J. Nichols, S. Papadopoulos, 

 J. L. Atwood, and C. L. Raston, "Icosahedral Galloxane Clusters," Chem. Comm., 

2393 (2007). 

620. S. J. Dalgarno, N. P. Power, and J. L. Atwood, "Ionic Dimeric Pyrogallol[4]arene 

Capsules," Chem. Comm., 3447 (2007). 

621. P. K. Thallapally, B. P. McGrail, J. L. Atwood, C. Gaeta, C. Tedesco, and P. Neri, 

"Carbon Dioxide Capture in a Self-Assembled Organic Nanochannel," Chem. 

Mat.,19, 3355 (2007). 

 Cover Illustration 

622. S. J. Dalgarno, J. Antesberger, R. M. McKinlay, and J. L. Atwood, "Water as a 

Building Block in Solid-State Acetonitrile-Pyrogallol[4]arene Assemblies: 

Structural Investigations," Chem. Eur. J., 13, 8248 (2007). 

623. D. B. Bassil, S. J. Dalgarno, G. W. V. Cave, J. L. Atwood, and S. A. Tucker, 

"Spectroscopic Investigations of ADMA Encapsulated in Pyrogallol[4]arene 

Nanocapsules," J. Phys. Chem. B, 111, 9088 (2007). 

624. N. P. Power, S. J. Dalgarno, and J. L. Atwood, "Guest and Ligand Behavior in 

Case 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 83 of 90 PageID: 4346
Zinc-Seamed Pyrogallol[4]arene Molecular Capsules," Angew. Chem. Int. Ed. 

Engl., 46, 8601 (2007). 

 Inside Cover Illustration 

625. J. L. Daschbach, P. K. Thallapally, J. L. Atwood, B. P. McGrail, and L. X. Dang, 

"Free Energies of CO2/H2 Capture by p-tert-Butylcalix[4]arene: A Molecular 

Dynamics Study," J. Chem. Phys., 127, 104703-1-104703-4 (2007). 

626. J. L. Atwood, T. E. Clark, S. J. Dalgarno, M. Makha, C. L. Raston, J. Tian, and J. E. 

Warren, "Calix[5]arene: A Versatile Sublimate that Displays Gas Sorption 

Properties," Chem. Comm., 4848 (2007). 

 Cover illustration 

627. T. E. Clark, M. Makha, A. N. Sobolev, S. J. Dalgarno, J. L. Atwood, and C. L. 

Raston, "Structural Diversity of Methyl-Substituted Inclusion Complexes of 

Calix[5]arene," Cryst. Growth Des., 7, 2059 (2007). 

628. S. J. Dalgarno, J. E. Warren, J. Antesberger, T. E. Glass, and J. L. Atwood, "Large 

Diameter Non-covalent Nanotubes Based on the Self-assembly of paraCarboxylatocalix[4]arene," New J. Chem., 31, 1891 (2007). 

 Inside Cover Illustration 

629. S. J. Dalgarno, N. P. Power, J. E. Warren, and J. L. Atwood, "Rapid Formation of 

Metal-Organic Nano-Capsules Gives New Insight into the Self-Assembly Process," 

Chem. Comm., 1539 (2008). 

630. S. J. Dalgarno, N. P. Power, and J. L. Atwood, "Organic Nanocapsules," Organic 

Nanostructures, Ed. J. W. Steed and J. L. Atwood, Wiley, 317-346 (2008). 

631. P. K. Thallapally, B. P. McGrail, H. T. Schaef, S. J. Dalgarno, J. Tian, and J. L. 

Atwood, "Gas-Induced Transformation and Expansion of a Non-Porous Organic 

Solid," Nature Mat., 7, 146 (2008). 

632. S. J. Dalgarno, N. P. Power, and J. L. Atwood, "Metallo-Supramolecular Capsules," 

Coord. Chem. Rev., 252, 825 (2008). 

633. S. J. Dalgarno, K. M. C. Bosque, J. E. Warren, T. E. Glass, and J. L. Atwood, 

"Interpenetrated Nano-capsule Networks Based on the Alkali Metal Assisted 

Assembly of p-Carboxylatocalix[4]arene-O-methyl Ether," Chem. Comm., 1410 

(2008). 

634. T. E. Clark, M. Makha, A. N. Soblev, D. Su, H. Rohrs, M. L. Gross, J. L. Atwood, 

and C. L. Raston, "Self-organised nano-arrays of p-phosphonic acid functionalised 

higher order calixarenes," New J. Chem., 32, 1478 (2008). 

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635. S. J. Dalgarno, P. K. Thallapally, J. Tian, and J. L. Atwood, "Pseudo-polymorphism 

in the Toluene Solvate of p-tert-Butylcalix[5]arene: Structural and Gas Sorption 

Investigations," New J. Chem., 32, 2095 (2008). 

636. G. W. V. Cave, S. J. Dalgarno, J. Antesberger, M. C. Ferrarelli, R. M. McKinlay, 

and J. L. Atwood, "Investigations into Chain Length Control Over Solid-State 

Pyrogallol[4]arene Nanocapsule Packing," Supramol. Chem., 20, 157 (2008). 

637. T. E. Clark, M. Makha, A. N. Sobolev, H. Rohrs, J. L. Atwood, and C. L. Raston, 

"Engineering Nano-Rafts of Polyphosphonates," Chem. Eur. J., 3931 (2008). 

638. K. S. Iyer, M. Norret, S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Loading 

Molecular Hydrogen Cargo within Viruslike Nanocontainers," Angew. Chem. Int. 

Ed. Engl., 47, 6362 (2008). 

639. P. K, Thallapally, P. B. McGrail, S. J. Dalgarno, and J. L. Atwood, "Gas/SolventInduced Transformation and Expansion of a Nonporous Solid to 1:1 Host Guest 

Form," Cryst. Growth & Des., 8, 2090 (2008). 

640. S. J. Dalgarno, J. E. Warren, J. L. Atwood, and C. L. Raston, “Versatility of psulfonatocalix[5]arene in Building up Multicomponent Bilayers,” New J. Chem., 

32, 2100 (2008). 

641. P. K. Thallapally, J. Tian, M. R. Kishan, C. A. Fernandez, S. J. Dalgarno, P. B. 

McGrail, J. E. Warren, and J. L. Atwood, “A Flexible (Breathing) Interpenetrated 

Metal-Organic Frameworks for CO2 Separation Applications,” J. Am. Chem. Soc., 

130, 16842 (2008). 

642. P. Jin, S. J. Dalgarno, C. Barnes, S. J. Teat, and J. L. Atwood, "Ion Transport to the 

Interior of Metal-Organic Pyrogallol[4]arene Nano-Capsules," J. Am. Chem. Soc., 

130, 17262 (2008). 

643. P. Jin, S. J. Dalgarno, J. E. Warren, S. Teat, and J. L. Atwood, "Enhanced Control 

over Metal Composition in Mixed Ga/Zn and Ga/Cu Coordinated 

Pyrogallol[4]arene Nano-Capsules," Chem. Comm., 3348 (2009). 

644. J. Tian, P. K. Thallapally, S. J. Dalgarno, P. B. McGrail, and J. L. Atwood, 

“Amorphous Molecular Organic Solids for Gas Adsorption,” Angew. Chem. Int. Ed. 

Engl., 48, 5492 (2009). 

645. S. J. Dalgarno, T. Szabo, A. Siavosh-Haghighi, C. A. Deakyne, J. E. Adams, and J. 

L. Atwood, "Exploring the Limits of Encapsulation within Hexameric 

Pyrogallol[4]arene Nano-Capsules," Chem. Comm., 1339 (2009). 

646. J. Tian, S. J. Dalgarno, P. K. Thallapally, and J. L. Atwood, “Increased Control 

Over the Desolvation of p-tert-Butylcalix[5]arene,” Cryst. Eng. Comm., 11, 33 

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(2009). 

647. J. Tian, P. K. Thallapally, S. J. Dalgarno, and J. L. Atwood, “Free Transport of 

Water and CO2 in Nonporous Hydrophobic Clarithromycin Form II Crystals,” 

J. Am. Chem. Soc., 131, 13216 (2009). 

Chemical & Engineering News, News of the Week, September 7, 2009, p. 14. 

648. C. Tedesco, L. Erra, V. Cipolletti, C. Gaeta, P. Neri, M. Brunelli, A. N. Fitch, and 

 J. L. Atwood, “Methane Adsorption in a Supramolecular Organic Zeolite,” Chem. 

Eur. J., 16, 2371 (2010). 

649. A. K. Maerz, H. Thomas, N. P. Power, C. A. Deakyne, and J. L. Atwood, “Dimeric 

Nanocapsule Induces Conformational Change,” Chem. Comm., 1235 (2010). 

650. J. L. Atwood., E. K. Brechin, S. J. Dalgarno, R. Inglis, L. F. Jones, A. V. Mossine, 

M. J. Paterson, N. P. Power, S. J. Teat, “Magnetism in Metal-Organic Capsules,” 

Chem. Comm., 3484 (2010). 

651. M. R. Kishan, J. Tian, P. K. Thallapally, C. A. Fernandez, S. J. Dalgarno, J. E. 

Warren, B. P. McGrail, and J. L. Atwood, “Flexible Metal-Organic Supramolecular 

Isomers for Gas Separation,” Chem. Comm. 538 (2010). 

 Cover Illustration 

652. P. Jin, S. J. Dalgarno, and J. L. Atwood, “Mixed Metal-Organic Nanocapsules,” 

Coord. Chem. Rev., 254, 1760 (2010). 

653. J. L. Whetstine, K. K. Kline, D. A. Fowler, C. Barnes, J. L. Atwood, and S. A. 

Tucker, “Spectroscopic Investigations of Pyrene Butanol Encapsulated in Chexylpyrogallol[4]arene Nanocapsules,” New J. Chem., 34, 2587 (2010). 

654. K. T. Holman, S. D. Drake, J. W. Steed, G. W. Orr, and J. L. Atwood, “ArylExtended Cyclotriguaiacylenes and an Aryl Bridged Cryptophane that Provides 

Snapshots of a Molecular Gating Mechanism, Supramol. Chem., 22, 870 (2010). 

655. J. Tian, P. K. Thallapally, and J. L. Atwood, “Gas-Induced Solid State 

Transformation of an Organic Lattice: From Nonporous to Nanoporous,” Chem. 

Comm., 701 (2011). 

656. J. Tian, S. J. Dalgarno, and J. L. Atwood, “A New Strategy of Transforming 

Pharmaceutical Crystal Forms,” J. Am. Chem. Soc., 133, 1399 (2011). 

Chemical & Engineering News, News of the Week, January 17, 2011, p. 8. 

657. A. K. Maerz, D. A. Fowler, C. M. Beavers, S. J. Teat, S. J. Dalgarno, C. A. 

Deakyne, and J. L. Atwood, “Solid-State Investigation into Conformational Control 

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of Zinc(II) Dimeric Nanocapsules Using C-4-propoxyphenylpyrogallol[4}arenes,” 

Chem. Comm., submitted. 

658. A. V. Mossine, H. Kumari, D. A. Fowler, A. K. Maerz, S. R. Kline, C. L. Barnes, 

and J. L. Atwood, “Ferrocene as a Hydrophobic Temblating Agent with 

Pyrogallol[4]arenes,” Isr. J. Chem., 51, 840 (2011). 

659. P. Jin, S. J. Dalgarno, S. J. Teat, and J. L. Atwood, “Structural Alteration of the 

Metal-Organic Pyrogallol[4]arene Nano-Capsule Motif by Incorporation of Large 

Metal Centres,” Chem. Comm., submitted. 

660. D. A. Fowler, J. Tian, C. L. Barnes, S. J. Teat, and J. L. Atwood, “Cocrystallization 

of C-Butylpyrogallol[4]arene and C-Propan-3-olpyrogallol[4]arene with 

Gabapentin,” 

Cryst. Eng. Comm., 13, 1446 (2011). 

661. S. J. Dalgarno, J. L. Atwood, and C. L. Raston, "Structural Diversity in Lanthanide 

Diaza-Crown Ether Complexes of p-sulfonatocalix[4 or 5]arenes: 'Molecular 

Capsule' versus 'Alternative Bi-Layer' Arrays," Dalton Trans., submitted. 

662. S. J. Dalgarno, K. S. Iyer, J. L. Atwood, and C. L. Raston, “Hydrogen-Bonded 

Molecular Capsules,” Nanoscale, submitted. 

663. R. K. Motkuri, P. K. Thallapally, B. P. McGrail, and J. L. Atwood, “Role of 

Hydrocarbons on Pore Expansion and Contraction of a Flexible Metal-Organic 

Framework,” Chem. Comm., 7077 (2011). 

664. D. A. Fowler, A. V. Mossine, C. M. Beavers, S. J. Teat, S. J. Dalgarno, and J. L. 

Atwood, “Coordination Polymer Chains of Dimeric Pyrogallol[4]arene Capsules,” 

J. Am. Chem. Soc., 133, 11069 (2011). 

665. M. Lusi, J. L. Atwood, L. R. Macgillivray, and L. J. Barbour, “Isostructural 

Coordination Polymers: Epitaxis vs. Solid Solution,” Chem. Eng. Comm., 13, 4311 

(2011). 

666. K. Jucke, K. M. Anderson, M. H. Filby, J. A. K. Howard, J. W. Steed, M. Henry, 

M. J. Gutmann, J. Wright, S. A. Mason, L. J. Barbour, C. Oliver, A. W. Coleman, 

and J. L. Atwood, “The Structure of Water: Behaviour in p-Sulfonatocalix[4]arene, 

a Highly Hydrated Clay-Mimic,” Chem. Eu. J., accepted. 

667. A. K. Maerz, D. A. Fowler, A. V. Mossine, M. Mistry, H. Kumari, C. L. Banes, C. 

A. Deakyne, and J. L. Atwood, “Solvent Mediated Self-Assembly of Organic 

Nanostructures,” New J. Chem., 35, 784 (2011). 

668. L. Erra, C. Tedesco, V. Cipolletti, L. Annunziata, C. Gaeta, M. Brunelli, A. Fitch, 

C. Knofel, P. Llewellyn, J. L. Atwood, and P. Neri, “Acetylene and Argon 

Adsorption in a Supramolecular Organic Zeolite,” Chem. Mat., submitted. 

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669. K. K. Kline, D. A Fowler, S. A. Tucker, and J. L. Atwood, “Encapsulation of 

Acenaphthene within C-propan-3-ol-pyrogallol[4]arene Dimeric Nanocapsules,” 

Chem. Eu. J., in press. 

670. J. W. Steed, J. L. Atwood, and P. A Gale, “Definition and Emergence of 

Supramolecular Chemistry,” Supramolecular Chemistry: from Molecules to 

Nanomaterials, in press. 

671. J. Tian, S. Ma, C. Fernandez, P. K. Thallapally, D. A. Fowler, B. P. McGrail, and J. 

L. Atwood, “Cucurbit[7]uril: an Amorphous Molecular Material for Highly 

Selective Carbon Dioxide Uptake,” Chem. Comm., 7626 (2011). 

672. A. D. Martin, R. A. Boulos, K. S. Iyer, A. N. Sobolev, C. S. Bond, J. L. Atwood, S. 

J. Dalgarno, and C. L. Raston, “Solvent and Hydrogen Confinement in Molecular 

Capsules – Hirshfeld Surface and Molecular Smulation Analysis,” Chem. Comm., 

9882 (2011). 

673. H. Kumari, S. R. Kline, N. J. Schuster, C. L. Barnes, and J. L. Atwood, “Exploring 

the Ellipsoidal and Core-Shell Geometries of Copper-seamed Calkylpyrogallol[4]arene Nanocapsules in Solution,” J. Am. Chem. Soc., in press. 

674. H. Kumari, S. R. Kline, N. J. Schuster, and J. L. Atwood, “Investigation of Copperseamed C-alkylpyrogallol[4]arene Nanocapsules with Varying Chain Lengths in 

Solution,” Chem. Comm., in press. 

675. H. Kumari, S. R. Kline, R. L. Paul, A. V. Mossine, C. A. Deakyne, and J. L. 

Atwood, “Investigating Fluxional Behaviour of Gallium-containing Cbutylpyrogallol[4]arene Organic Nanocapsules,” Angew. Chem. Int. Ed., submitted. 

676. A. V. Mossine, P. Thavornyutikarn, and J. L. Atwood, “A Porous Network Solid 

Based on Tetracyanoresorcin[4]arene,” Cryst. Eng. Comm., submitted. 

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PATENTS 

1. "Liquid Clathrates" 

 U. S. Patent 4,024,170 (1977). 

2. "Coal Liquefaction Using Liquid Clathrates" 

 U. S. Patent 4,321,127 (1982). 

3. "Multidentate Macromolecular Complex Salt Clathrates" 

 U. S. Patent 4,496,744 (1985). 

4. "Calixarene Chloride-Channel Blockers" 

 with R. J. Bridges, R. K. Juneja, and A. K. Singh, 

 U. S. Patent 5,489,612 (1996). 

5. "Separation of Fullerenes by Complexation" 

 with C. L. Raston, U. S. Patent 5,711,927 (1998). 

6. "Substantially Spherical Molecular and Ionic Assemblies" 

 with L. R. MacGillivray, U. S. Patent 7,169,957 (2007). 

7. "Formation of Nanometer-Scale Structures" 

 with G. W. Orr and L. J. Barbour, U. S. Patent 6,495,669 (2002). 

8. "Hexameric Complexes and Their Preparation" 

 U. S. Patent 7,014,868 (2006). 

9. "Self-Assembled Calixarene Based Guest-Host Assemblies for Guest Storage by 

 van der Waals Confinement" 

 with L. J. Barbour and A. Jerga 

 U. S. Patent 7,132,571 (2006). 

10. "Calixarene-Based Guest-Host Assemblies for Guest Storage and Transfer," 

 with L. J. Barbour and A. Jerga 

 U. S. Patent 7,217,846 (2007). 

Case 3:11-cv-00760-JAP-TJB Document 132-2 Filed 11/07/11 Page 89 of 90 PageID: 4352
11. "Material for the Recovery of Hydrogen from Gas Mixtures" 

 with L. J. Barbour and A. Jerga 

 filed April 19, 2004. 

12. “Processes for the Preparation of Calixarene Derivatives” 

 with C. L. Raston 

 filed June 13, 2008. 

13. “New Strategy for Transforming Pharmaceutical Solids” 

 with J. Tian and S. J. Dalgarno 

 to be filed. 

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