# Patent

## Title
Organic electroluminescent materials and devices

## Abstract

A compound comprising a first ligand LA having a Formula selected from:




is disclosed. In the Formulas rings B and C are 5-membered or 6-membered aromatic or heteroaromatic ring; Z1, Z2, X1, X2, X3, X4, X5, and X6 are each C or N, but X1, X2, X3, or X4 is C when it forms a direct bond to Z2; Y is selected from CRR′, NR′, O, S, and Se; R, R′, RA, RB, RC, and RD are each selected from a variety of substituents; the ligand LA is coordinated to a metal M by the dashed lines, and optionally to other ligands. Organic light emitting devices and consumer products containing the compounds are also disclosed.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 62/560,902, filed Sep. 20, 2017, the entire contents of which are incorporated herein by reference.


FIELD
The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.
BACKGROUND
Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)3, which has the following structure:




In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.
As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
As used herein, “solution processable” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
SUMMARY
According to an aspect of the present disclosure, a compound comprising a first ligand LA having the Formula selected from the group consisting of




is provided. In Formulae IA, IB, and IC:

    
    
        ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
        RA, RB, RC, and RD each independently represent mono to the maximum possible number of substituents, or no substituent;
        Z1 and Z2 are each independently selected from the group consisting of C and N;
        X1, X2, X3, X4, X5, and X6 are each independently selected from the group consisting of C and N;
        X1, X2, X3, or X4 is C when it forms a direct bond to Z2;
        Y is selected from the group consisting of CRR′, NR′, O, S, and Se;
        R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
        any two substituents are optionally joined or fused into a ring;
        the ligand LA is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;

wherein M does not form a direct bond to X1 in Formula IB;

wherein M does not form a direct bond to X4 in Formula IC;

        the metal M can be coordinated to other ligands; and
        the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.
    
    


In some embodiments, an organic light emitting device (OLED) is described. The OLED can include an anode; a cathode; and an organic layer, disposed between the anode and the cathode, where the organic layer includes a compound comprising a first ligand LA of Formula IA, Formula IB, or Formula IC, as described herein.
A consumer product comprising the OLED is also disclosed.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows an organic light emitting device.
FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.



DETAILED DESCRIPTION
Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.
More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.
The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.
Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.
Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.
The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
The terms “halo,” “halogen,” and “halide” are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.
The term “acyl” refers to a substituted carbonyl radical (C(O)—Rs).
The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R or —C(O)—O—Rs) radical.
The term “ether” refers to an —ORs radical.
The terms “sulfanyl” or “thio-ether” are used interchangeably and refer to a —SRs radical.
The term “sulfinyl” refers to a —S(O)—Rs radical.
The term “sulfonyl” refers to a —SO2—Rs radical.
The term “phosphino” refers to a —P(Rs)3 radical, wherein each Rs can be same or different.
The term “silyl” refers to a —Si(Rs)3 radical, wherein each Rs can be same or different.
In each of the above, Rs can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred Rs is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
The term “alkyl” refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group is optionally substituted.
The term “cycloalkyl” refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group is optionally substituted.
The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N. Additionally, the heteroalkyl or heterocycloalkyl group is optionally substituted.
The term “alkenyl” refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain. Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term “heteroalkenyl” as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group is optionally substituted.
The term “alkynyl” refers to and includes both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group is optionally substituted.
The terms “aralkyl” or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group is optionally substituted.
The term “heterocyclic group” refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
The term “aryl” refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group is optionally substituted.
The term “heteroaryl” refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group is optionally substituted.
Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinations thereof.
In yet other instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
The term “substituted” refers to a substituent other than H that is bonded to the relevant position, e.g., a carbon. For example, where R1 represents mono-substituted, then one R1 must be other than H. Similarly, where R1 represents di-substituted, then two of R1 must be other than H. Similarly, where R1 is unsubstituted, R1 is hydrogen for all available positions. The maximum number of substitutions possible in a structure (for example, a particular ring or fused ring system) will depend on the number of atoms with available valencies.
As used herein, “combinations thereof” indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective fragment can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
As used herein, “deuterium” refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
According to an aspect of the present disclosure, a compound comprising a first ligand LA having the Formula selected from the group consisting of




is provided. In Formulae IA, IB, and IC:

    
    
        ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
        RA, RB, RC, and RD each independently represent mono to the maximum possible number of substituents, or no substituent;
        Z1 and Z2 are each independently selected from the group consisting of C and N;
        X1, X2, X3, X4, X5, and X6 are each independently selected from the group consisting of C and N;
        X1, X2, X3, or X4 is C when it forms a direct bond to Z2;
        Y is selected from the group consisting of CRR′, NR′, O, S, and Se;
        R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
        any two substituents are optionally joined or fused into a ring;
        the ligand LA is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;

wherein M does not form a direct bond to X1 in Formula IB;

wherein M does not form a direct bond to X4 in Formula IC;

        the metal M can be coordinated to other ligands; and
        the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.
    
    


In some embodiments, ring B can be a ring system comprising two fused rings, such as naphthalene, benzimidazole, etc. In such instances, the maximum substitutions for RB could be hexa- or penta-substitutions, respectively.
In some embodiments, metal M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Pd, Au, and Cu. In some embodiments, metal M is Ir or Pt.
In some embodiments, R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
In some embodiments, the compound is homoleptic. In some embodiments, the compound is heteroleptic.
In some embodiments, Y is O.
In some embodiments, X1 through X6 are each independently C. In some embodiments, X1 through X4 are each independently CR.
In some embodiments, ring C is a fused benzene ring.
In some embodiments, ring B is selected from the group consisting of pyridine, pyrimidine, pyrazine, pyridazine, benzene imidazole, pyrazole, triazole, pyrrole, oxazole, thiazole, and imidazole derived carbene. In some embodiments, ring A is benzene and ring B is pyridine with Z1 as N. In some embodiments, ring A is pyridine with N coordinated to metal, and ring B is benzene.
In some embodiments, the first ligand LA is selected from the group consisting of:


























































































































































and aza variants thereof; and

    
    
        wherein Ra is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
    
    


In some embodiments, the first ligand LA is selected from the group consisting of LA1 through LA4780, wherein LA1 through LA240 have a structure of Formula II:




wherein R1, R2, X, and Y are defined as:


















Ligand
R1
R2
X
Y









LA1
H
H
C
S



LA2
RB1
H
C
S



LA3
RB3
H
C
S



LA4
RB4
H
C
S



LA5
RB7
H
C
S



LA6
RB10
H
C
S



LA7
RA3
H
C
S



LA8
RA34
H
C
S



LA9
H
H
C
O



LA10
RB1
H
C
O



LA11
RB3
H
C
O



LA12
RB4
H
C
O



LA13
RB7
H
C
O



LA14
RB10
H
C
O



LA15
RA3
H
C
O



LA16
RA34
H
C
O



LA17
H
H
C
NCH3



LA18
RB1
H
C
NCH3



LA19
RB3
H
C
NCH3



LA20
RB4
H
C
NCH3



LA21
RB7
H
C
NCH3



LA22
RB10
H
C
NCH3



LA23
RA3
H
C
NCH3



LA24
RA34
H
C
NCH3



LA25
H
H
C
C(CH3)2



LA26
RB1
H
C
C(CH3)2



LA27
RB3
H
C
C(CH3)2



LA28
RB4
H
C
C(CH3)2



LA29
RB7
H
C
C(CH3)2



LA30
RB10
H
C
C(CH3)2



LA31
RA3
H
C
C(CH3)2



LA32
RA34
H
C
C(CH3)2



LA33
H
H
C
Si(CH3)2



LA34
RB1
H
C
Si(CH3)2



LA35
RB3
H
C
Si(CH3)2



LA36
RB4
H
C
Si(CH3)2



LA37
RB7
H
C
Si(CH3)2



LA38
RB10
H
C
Si(CH3)2



LA39
RA3
H
C
Si(CH3)2



LA40
RA34
H
C
Si(CH3)2



LA41
H
RB1
C
S



LA42
RB1
RB1
C
S



LA43
RB3
RB1
C
S



LA44
RB4
RB1
C
S



LA45
RB7
RB1
C
S



LA46
RB10
RB1
C
S



LA47
RA3
RB1
C
S



LA48
RA34
RB1
C
S



LA49
H
RB1
C
O



LA50
RB1
RB1
C
O



LA51
RB3
RB1
C
O



LA52
RB4
RB1
C
O



LA53
RB7
RB1
C
O



LA54
RB10
RB1
C
O



LA55
RA3
RB1
C
O



LA56
RA34
RB1
C
O



LA57
H
RB1
C
NCH3



LA58
RB1
RB1
C
NCH3



LA59
RB3
RB1
C
NCH3



LA60
RB4
RB1
C
NCH3



LA61
RB7
RB1
C
NCH3



LA62
RB10
RB1
C
NCH3



LA63
RA3
RB1
C
NCH3



LA64
RA34
RB1
C
NCH3



LA65
H
RB1
C
C(CH3)2



LA66
RB1
RB1
C
C(CH3)2



LA67
RB3
RB1
C
C(CH3)2



LA68
RB4
RB1
C
C(CH3)2



LA69
RB7
RB1
C
C(CH3)2



LA70
RB10
RB1
C
C(CH3)2



LA71
RA3
RB1
C
C(CH3)2



LA72
RA34
RB1
C
C(CH3)2



LA73
H
RB1
C
Si(CH3)2



LA74
RB1
RB1
C
Si(CH3)2



LA75
RB3
RB1
C
Si(CH3)2



LA76
RB4
RB1
C
Si(CH3)2



LA77
RB7
RB1
C
Si(CH3)2



LA78
RB10
RB1
C
Si(CH3)2



LA79
RA3
RB1
C
Si(CH3)2



LA80
RA34
RB1
C
Si(CH3)2



LA81
H
RB2
C
S



LA82
RB1
RB2
C
S



LA83
RB3
RB2
C
S



LA84
RB4
RB2
C
S



LA85
RB7
RB2
C
S



LA86
RB10
RB2
C
S



LA87
RA3
RB2
C
S



LA88
RA34
RB2
C
S



LA89
H
RB2
C
O



LA90
RB1
RB2
C
O



LA91
RB3
RB2
C
O



LA92
RB4
RB2
C
O



LA93
RB7
RB2
C
O



LA94
RB10
RB2
C
O



LA95
RA3
RB2
C
O



LA96
RA34
RB2
C
O



LA97
H
RB2
C
NCH3



LA98
RB1
RB2
C
NCH3



LA99
RB3
RB2
C
NCH3



LA100
RB4
RB2
C
NCH3



LA101
RB7
RB2
C
NCH3



LA102
RB10
RB2
C
NCH3



LA103
RA3
RB2
C
NCH3



LA104
RA34
RB2
C
NCH3



LA105
H
RB2
C
C(CH3)2



LA106
RB1
RB2
C
C(CH3)2



LA107
RB3
RB2
C
C(CH3)2



LA108
RB4
RB2
C
C(CH3)2



LA109
RB7
RB2
C
C(CH3)2



LA110
RB10
RB2
C
C(CH3)2



LA111
RA3
RB2
C
C(CH3)2



LA112
RA34
RB2
C
C(CH3)2



LA113
H
RB2
C
Si(CH3)2



LA114
RB1
RB2
C
Si(CH3)2



LA115
RB3
RB2
C
Si(CH3)2



LA116
RB4
RB2
C
Si(CH3)2



LA117
RB7
RB2
C
Si(CH3)2



LA118
RB10
RB2
C
Si(CH3)2



LA119
RA3
RB2
C
Si(CH3)2



LA120
RA34
RB2
C
Si(CH3)2



LA121
H
H
N
S



LA122
RB1
H
N
S



LA123
RB3
H
N
S



LA124
RB4
H
N
S



LA125
RB7
H
N
S



LA126
RB10
H
N
S



LA127
RA3
H
N
S



LA128
RA34
H
N
S



LA129
H
H
N
O



LA130
RB1
H
N
O



LA131
RB3
H
N
O



LA132
RB4
H
N
O



LA133
RB7
H
N
O



LA134
RB10
H
N
O



LA135
RA3
H
N
O



LA136
RA34
H
N
O



LA137
H
H
N
NCH3



LA138
RB1
H
N
NCH3



LA139
RB3
H
N
NCH3



LA140
RB4
H
N
NCH3



LA141
RB7
H
N
NCH3



LA142
RB10
H
N
NCH3



LA143
RA3
H
N
NCH3



LA144
RA34
H
N
NCH3



LA145
H
H
N
C(CH3)2



LA146
RB1
H
N
C(CH3)2



LA147
RB3
H
N
C(CH3)2



LA148
RB4
H
N
C(CH3)2



LA149
RB7
H
N
C(CH3)2



LA150
RB10
H
N
C(CH3)2



LA151
RA3
H
N
C(CH3)2



LA152
RA34
H
N
C(CH3)2



LA153
H
H
N
Si(CH3)2



LA154
RB1
H
N
Si(CH3)2



LA155
RB3
H
N
Si(CH3)2



LA156
RB4
H
N
Si(CH3)2



LA157
RB7
H
N
Si(CH3)2



LA158
RB10
H
N
Si(CH3)2



LA159
RA3
H
N
Si(CH3)2



LA160
RA34
H
N
Si(CH3)2



LA161
H
RB1
N
S



LA162
RB1
RB1
N
S



LA163
RB3
RB1
N
S



LA164
RB4
RB1
N
S



LA165
RB7
RB1
N
S



LA166
RB10
RB1
N
S



LA167
RA3
RB1
N
S



LA168
RA34
RB1
N
S



LA169
H
RB1
N
O



LA170
RB1
RB1
N
O



LA171
RB3
RB1
N
O



LA172
RB4
RB1
N
O



LA173
RB7
RB1
N
O



LA174
RB10
RB1
N
O



LA175
RA3
RB1
N
O



LA176
RA34
RB1
N
O



LA177
H
RB1
N
NCH3



LA178
RB1
RB1
N
NCH3



LA179
RB3
RB1
N
NCH3



LA180
RB4
RB1
N
NCH3



LA181
RB7
RB1
N
NCH3



LA182
RB10
RB1
N
NCH3



LA183
RA3
RB1
N
NCH3



LA184
RA34
RB1
N
NCH3



LA185
H
RB1
N
C(CH3)2



LA186
RB1
RB1
N
C(CH3)2



LA187
RB3
RB1
N
C(CH3)2



LA188
RB4
RB1
N
C(CH3)2



LA189
RB7
RB1
N
C(CH3)2



LA190
RB10
RB1
N
C(CH3)2



LA191
RA3
RB1
N
C(CH3)2



LA192
RA34
RB1
N
C(CH3)2



LA193
H
RB1
N
Si(CH3)2



LA194
RB1
RB1
N
Si(CH3)2



LA195
RB3
RB1
N
Si(CH3)2



LA196
RB4
RB1
N
Si(CH3)2



LA197
RB7
RB1
N
Si(CH3)2



LA198
RB10
RB1
N
Si(CH3)2



LA199
RA3
RB1
N
Si(CH3)2



LA200
RA34
RB1
N
Si(CH3)2



LA201
H
RB2
N
S



LA202
RB1
RB2
N
S



LA203
RB3
RB2
N
S



LA204
RB4
RB2
N
S



LA205
RB7
RB2
N
S



LA206
RB10
RB2
N
S



LA207
RA3
RB2
N
S



LA208
RA34
RB2
N
S



LA209
H
RB2
N
O



LA210
RB1
RB2
N
O



LA211
RB3
RB2
N
O



LA212
RB4
RB2
N
O



LA213
RB7
RB2
N
O



LA214
RB10
RB2
N
O



LA215
RA3
RB2
N
O



LA216
RA34
RB2
N
O



LA217
H
RB2
N
NCH3



LA218
RB1
RB2
N
NCH3



LA219
RB3
RB2
N
NCH3



LA220
RB4
RB2
N
NCH3



LA221
RB7
RB2
N
NCH3



LA222
RB10
RB2
N
NCH3



LA223
RA3
RB2
N
NCH3



LA224
RA34
RB2
N
NCH3



LA225
H
RB2
N
C(CH3)2



LA226
RB1
RB2
N
C(CH3)2



LA227
RB3
RB2
N
C(CH3)2



LA228
RB4
RB2
N
C(CH3)2



LA229
RB7
RB2
N
C(CH3)2



LA230
RB10
RB2
N
C(CH3)2



LA231
RA3
RB2
N
C(CH3)2



LA232
RA34
RB2
N
C(CH3)2



LA233
H
RB2
N
Si(CH3)2



LA234
RB1
RB2
N
Si(CH3)2



LA235
RB3
RB2
N
Si(CH3)2



LA236
RB4
RB2
N
Si(CH3)2



LA237
RB7
RB2
N
Si(CH3)2



LA238
RB10
RB2
N
Si(CH3)2



LA239
RA3
RB2
N
Si(CH3)2



LA240
RA34
RB2
N
Si(CH3)2










wherein LA241 through LA360 have a structure of Formula III:





wherein R2, R3 and Y are defined as provided below:

















Ligand
R2
R3
Y









LA241
H
H
S



LA242
H
RB1
S



LA243
H
RB2
S



LA244
H
RB3
S



LA245
H
RB4
S



LA246
H
RB5
S



LA247
H
RA34
S



LA248
H
RA52
S



LA249
H
H
O



LA250
H
RB1
O



LA251
H
RB2
O



LA252
H
RB3
O



LA253
H
RB4
O



LA254
H
RB5
O



LA255
H
RA34
O



LA256
H
RA52
O



LA257
H
H
NCH3



LA258
H
RB1
NCH3



LA259
H
RB2
NCH3



LA260
H
RB3
NCH3



LA261
H
RB4
NCH3



LA262
H
RB5
NCH3



LA263
H
RA34
NCH3



LA264
H
RA52
NCH3



LA265
H
H
C(CH3)2



LA266
H
RB1
C(CH3)2



LA267
H
RB2
C(CH3)2



LA268
H
RB3
C(CH3)2



LA269
H
RB4
C(CH3)2



LA270
H
RB5
C(CH3)2



LA271
H
RA34
C(CH3)2



LA272
H
RA52
C(CH3)2



LA273
H
H
Si(CH3)2



LA274
H
RB1
Si(CH3)2



LA275
H
RB2
Si(CH3)2



LA276
H
RB3
Si(CH3)2



LA277
H
RB4
Si(CH3)2



LA278
H
RB5
Si(CH3)2



LA279
H
RA34
Si(CH3)2



LA280
H
RA52
Si(CH3)2



LA281
RB1
H
S



LA282
RB1
RB1
S



LA283
RB1
RB2
S



LA284
RB1
RB3
S



LA285
RB1
RB4
S



LA286
RB1
RB5
S



LA287
RB1
RA34
S



LA288
RB1
RA52
S



LA289
RB1
H
O



LA290
RB1
RB1
O



LA291
RB1
RB2
O



LA292
RB1
RB3
O



LA293
RB1
RB4
O



LA294
RB1
RB5
O



LA295
RB1
RA34
O



LA296
RB1
RA52
O



LA297
RB1
H
NCH3



LA298
RB1
RB1
NCH3



LA299
RB1
RB2
NCH3



LA300
RB1
RB3
NCH3



LA301
RB1
RB4
NCH3



LA302
RB1
RB5
NCH3



LA303
RB1
RA34
NCH3



LA304
RB1
RA52
NCH3



LA305
RB1
H
C(CH3)2



LA306
RB1
RB1
C(CH3)2



LA307
RB1
RB2
C(CH3)2



LA308
RB1
RB3
C(CH3)2



LA309
RB1
RB4
C(CH3)2



LA310
RB1
RB5
C(CH3)2



LA311
RB1
RA34
C(CH3)2



LA312
RB1
RA52
C(CH3)2



LA313
RB1
H
Si(CH3)2



LA314
RB1
RB1
Si(CH3)2



LA315
RB1
RB2
Si(CH3)2



LA316
RB1
RB3
Si(CH3)2



LA317
RB1
RB4
Si(CH3)2



LA318
RB1
RB5
Si(CH3)2



LA319
RB1
RA34
Si(CH3)2



LA320
RB1
RA52
Si(CH3)2



LA321
RB2
H
S



LA322
RB2
RB1
S



LA323
RB2
RB2
S



LA324
RB2
RB3
S



LA325
RB2
RB4
S



LA326
RB2
RB5
S



LA327
RB2
RA34
S



LA328
RB2
RA52
S



LA329
RB2
H
O



LA330
RB2
RB1
O



LA331
RB2
RB2
O



LA332
RB2
RB3
O



LA333
RB2
RB4
O



LA334
RB2
RB5
O



LA335
RB2
RA34
O



LA336
RB2
RA52
O



LA337
RB2
H
NCH3



LA338
RB2
RB1
NCH3



LA339
RB2
RB2
NCH3



LA340
RB2
RB3
NCH3



LA341
RB2
RB4
NCH3



LA342
RB2
RB5
NCH3



LA343
RB2
RA34
NCH3



LA344
RB2
RA52
NCH3



LA345
RB2
H
C(CH3)2



LA346
RB2
RB1
C(CH3)2



LA347
RB2
RB2
C(CH3)2



LA348
RB2
RB3
C(CH3)2



LA349
RB2
RB4
C(CH3)2



LA350
RB2
RB5
C(CH3)2



LA351
RB2
RA34
C(CH3)2



LA352
RB2
RA52
C(CH3)2



LA353
RB2
H
Si(CH3)2



LA354
RB2
RB1
Si(CH3)2



LA355
RB2
RB2
Si(CH3)2



LA356
RB2
RB3
Si(CH3)2



LA357
RB2
RB4
Si(CH3)2



LA358
RB2
RB5
Si(CH3)2



LA359
RB2
RA34
Si(CH3)2



LA360
RB2
RA52
Si(CH3)2










wherein LA361 through LA456 have a structure of Formula IV,





wherein R2, R4, Y, and X are defined as provided below:


















Ligand
R2
R4
Y
Z









LA361
H
H
S
S



LA362
H
RB1
S
S



LA363
H
RB3
S
S



LA364
H
RB4
S
S



LA365
H
RB7
S
S



LA366
H
RB10
S
S



LA367
H
RA3
S
S



LA368
H
RA34
S
S



LA369
H
H
S
O



LA370
H
RB1
S
O



LA371
H
RB3
S
O



LA372
H
RB4
S
O



LA373
H
RB7
S
O



LA374
H
RB10
S
O



LA375
H
RA3
S
O



LA376
H
RA34
S
O



LA377
H
H
S
NCH3



LA378
H
RB1
S
NCH3



LA379
H
RB3
S
NCH3



LA380
H
RB4
S
NCH3



LA381
H
RB7
S
NCH3



LA382
H
RB10
S
NCH3



LA383
H
RA3
S
NCH3



LA384
H
RA34
S
NCH3



LA385
H
H
O
S



LA386
H
RB1
O
S



LA387
H
RB3
O
S



LA388
H
RB4
O
S



LA389
H
RB7
O
S



LA390
H
RB10
O
S



LA391
H
RA3
O
S



LA392
H
RA34
O
S



LA393
H
H
O
O



LA394
H
RB1
O
O



LA395
H
RB3
O
O



LA396
H
RB4
O
O



LA397
H
RB7
O
O



LA398
H
RB10
O
O



LA399
H
RA3
O
O



LA400
H
RA34
O
O



LA401
H
H
O
NCH3



LA402
H
RB1
O
NCH3



LA403
H
RB3
O
NCH3



LA404
H
RB4
O
NCH3



LA405
H
RB7
O
NCH3



LA406
H
RB10
O
NCH3



LA407
H
RA3
O
NCH3



LA408
H
RA34
O
NCH3



LA409
RB1
H
S
S



LA410
RB1
RB1
S
S



LA411
RB1
RB3
S
S



LA412
RB1
RB4
S
S



LA413
RB1
RB7
S
S



LA414
RB1
RB10
S
S



LA415
RB1
RA3
S
S



LA416
RB1
RA34
S
S



LA417
RB1
H
S
O



LA418
RB1
RB1
S
O



LA419
RB1
RB3
S
O



LA420
RB1
RB4
S
O



LA421
RB1
RB7
S
O



LA422
RB1
RB10
S
O



LA423
RB1
RA3
S
O



LA424
RB1
RA34
S
O



LA425
RB1
H
S
NCH3



LA426
RB1
RB1
S
NCH3



LA427
RB1
RB3
S
NCH3



LA428
RB1
RB4
S
NCH3



LA429
RB1
RB7
S
NCH3



LA430
RB1
RB10
S
NCH3



LA431
RB1
RA3
S
NCH3



LA432
RB1
RA34
S
NCH3



LA433
RB1
H
O
S



LA434
RB1
RB1
O
S



LA435
RB1
RB3
O
S



LA436
RB1
RB4
O
S



LA437
RB1
RB7
O
S



LA438
RB1
RB10
O
S



LA439
RB1
RA3
O
S



LA440
RB1
RA34
O
S



LA441
RB1
H
O
O



LA442
RB1
RB1
O
O



LA443
RB1
RB3
O
O



LA444
RB1
RB4
O
O



LA445
RB1
RB7
O
O



LA446
RB1
RB10
O
O



LA447
RB1
RA3
O
O



LA448
RB1
RA34
O
O



LA449
RB1
H
O
NCH3



LA450
RB1
RB1
O
NCH3



LA451
RB1
RB3
O
NCH3



LA452
RB1
RB4
O
NCH3



LA453
RB1
RB7
O
NCH3



LA454
RB1
RB10
O
NCH3



LA455
RB1
RA3
O
NCH3



LA456
RB1
RA34
O
NCH3










wherein LA457 through LA696 have a structure of Formula V:





wherein R1, R2, X, and Y are defined as provided below:


















Ligand 
R1
R2
X
Y









LA457
H
H
C
S



LA458
RB1
H
C
S



LA459
RB3
H
C
S



LA460
RB4
H
C
S



LA461
RB7
H
C
S



LA462
RB10
H
C
S



LA463
RA3
H
C
S



LA464
RA34
H
C
S



LA465
H
H
C
O



LA466
RB1
H
C
O



LA467
RB3
H
C
O



LA468
RB4
H
C
O



LA469
RB7
H
C
O



LA470
RB10
H
C
O



LA471
RA3
H
C
O



LA472
RA34
H
C
O



LA473
H
H
C
NCH3



LA474
RB1
H
C
NCH3



LA475
RB3
H
C
NCH3



LA476
RB4
H
C
NCH3



LA477
RB7
H
C
NCH3



LA478
RB10
H
C
NCH3



LA479
RA3
H
C
NCH3



LA480
RA34
H
C
NCH3



LA481
H
H
C
C(CH3)2



LA482
RB1
H
C
C(CH3)2



LA483
RB3
H
C
C(CH3)2



LA484
RB4
H
C
C(CH3)2



LA485
RB7
H
C
C(CH3)2



LA486
RB10
H
C
C(CH3)2



LA487
RA3
H
C
C(CH3)2



LA488
RA34
H
C
C(CH3)2



LA489
H
H
C
Si(CH3)2



LA490
RB1
H
C
Si(CH3)2



LA491
RB3
H
C
Si(CH3)2



LA492
RB4
H
C
Si(CH3)2



LA493
RB7
H
C
Si(CH3)2



LA494
RB10
H
C
Si(CH3)2



LA495
RA3
H
C
Si(CH3)2



LA496
RA34
H
C
Si(CH3)2



LA497
H
RB1
C
S



LA498
RB1
RB1
C
S



LA499
RB3
RB1
C
S



LA500
RB4
RB1
C
S



LA501
RB7
RB1
C
S



LA502
RB10
RB1
C
S



LA503
RA3
RB1
C
S



LA504
RA34
RB1
C
S



LA505
H
RB1
C
O



LA506
RB1
RB1
C
O



LA507
RB3
RB1
C
O



LA508
RB4
RB1
C
O



LA509
RB7
RB1
C
O



LA510
RB10
RB1
C
O



LA511
RA3
RB1
C
O



LA512
RA34
RB1
C
O



LA513
H
RB1
C
NCH3



LA514
RB1
RB1
C
NCH3



LA515
RB3
RB1
C
NCH3



LA516
RB4
RB1
C
NCH3



LA517
RB7
RB1
C
NCH3



LA518
RB10
RB1
C
NCH3



LA519
RA3
RB1
C
NCH3



LA520
RA34
RB1
C
NCH3



LA521
H
RB1
C
C(CH3)2



LA522
RB1
RB1
C
C(CH3)2



LA523
RB3
RB1
C
C(CH3)2



LA524
RB4
RB1
C
C(CH3)2



LA525
RB7
RB1
C
C(CH3)2



LA526
RB10
RB1
C
C(CH3)2



LA527
RA3
RB1
C
C(CH3)2



LA528
RA34
RB1
C
C(CH3)2



LA529
H
RB1
C
Si(CH3)2



LA530
RB1
RB1
C
Si(CH3)2



LA531
RB3
RB1
C
Si(CH3)2



LA532
RB4
RB1
C
Si(CH3)2



LA533
RB7
RB1
C
Si(CH3)2



LA534
RB10
RB1
C
Si(CH3)2



LA535
RA3
RB1
C
Si(CH3)2



LA536
RA34
RB1
C
Si(CH3)2



LA537
H
RB2
C
S



LA538
RB1
RB2
C
S



LA539
RB3
RB2
C
S



LA540
RB4
RB2
C
S



LA541
RB7
RB2
C
S



LA542
RB10
RB2
C
S



LA543
RA3
RB2
C
S



LA544
RA34
RB2
C
S



LA545
H
RB2
C
O



LA546
RB1
RB2
C
O



LA547
RB3
RB2
C
O



LA548
RB4
RB2
C
O



LA549
RB7
RB2
C
O



LA550
RB10
RB2
C
O



LA551
RA3
RB2
C
O



LA552
RA34
RB2
C
O



LA553
H
RB2
C
NCH3



LA554
RB1
RB2
C
NCH3



LA555
RB3
RB2
C
NCH3



LA556
RB4
RB2
C
NCH3



LA557
RB7
RB2
C
NCH3



LA558
RB10
RB2
C
NCH3



LA559
RA3
RB2
C
NCH3



LA560
RA34
RB2
C
NCH3



LA561
H
RB2
C
C(CH3)2



LA562
RB1
RB2
C
C(CH3)2



LA563
RB3
RB2
C
C(CH3)2



LA564
RB4
RB2
C
C(CH3)2



LA565
RB7
RB2
C
C(CH3)2



LA566
RB10
RB2
C
C(CH3)2



LA567
RA3
RB2
C
C(CH3)2



LA568
RA34
RB2
C
C(CH3)2



LA569
H
RB2
C
Si(CH3)2



LA570
RB1
RB2
C
Si(CH3)2



LA571
RB3
RB2
C
Si(CH3)2



LA572
RB4
RB2
C
Si(CH3)2



LA573
RB7
RB2
C
Si(CH3)2



LA574
RB10
RB2
C
Si(CH3)2



LA575
RA3
RB2
C
Si(CH3)2



LA576
RA34
RB2
C
Si(CH3)2



LA577
H
H
N
S



LA578
RB1
H
N
S



LA579
RB3
H
N
S



LA580
RB4
H
N
S



LA581
RB7
H
N
S



LA582
RB10
H
N
S



LA583
RA3
H
N
S



LA584
RA34
H
N
S



LA585
H
H
N
O



LA586
RB1
H
N
O



LA587
RB3
H
N
O



LA588
RB4
H
N
O



LA589
RB7
H
N
O



LA590
RB10
H
N
O



LA591
RA3
H
N
O



LA592
RA34
H
N
O



LA593
H
H
N
NCH3



LA594
RB1
H
N
NCH3



LA595
RB3
H
N
NCH3



LA596
RB4
H
N
NCH3



LA597
RB7
H
N
NCH3



LA598
RB10
H
N
NCH3



LA599
RA3
H
N
NCH3



LA600
RA34
H
N
NCH3



LA601
H
H
N
C(CH3)2



LA602
RB1
H
N
C(CH3)2



LA603
RB3
H
N
C(CH3)2



LA604
RB4
H
N
C(CH3)2



LA605
RB7
H
N
C(CH3)2



LA606
RB10
H
N
C(CH3)2



LA607
RA3
H
N
C(CH3)2



LA608
RA34
H
N
C(CH3)2



LA609
H
H
N
Si(CH3)2



LA610
RB1
H
N
Si(CH3)2



LA611
RB3
H
N
Si(CH3)2



LA612
RB4
H
N
Si(CH3)2



LA613
RB7
H
N
Si(CH3)2



LA614
RB10
H
N
Si(CH3)2



LA615
RA3
H
N
Si(CH3)2



LA616
RA34
H
N
Si(CH3)2



LA617
H
RB1
N
S



LA618
RB1
RB1
N
S



LA619
RB3
RB1
N
S



LA620
RB4
RB1
N
S



LA621
RB7
RB1
N
S



LA622
RB10
RB1
N
S



LA623
RA3
RB1
N
S



LA624
RA34
RB1
N
S



LA625
H
RB1
N
O



LA626
RB1
RB1
N
O



LA627
RB3
RB1
N
O



LA628
RB4
RB1
N
O



LA629
RB7
RB1
N
O



LA630
RB10
RB1
N
O



LA631
RA3
RB1
N
O



LA632
RA34
RB1
N
O



LA633
H
RB1
N
NCH3



LA634
RB1
RB1
N
NCH3



LA635
RB3
RB1
N
NCH3



LA636
RB4
RB1
N
NCH3



LA637
RB7
RB1
N
NCH3



LA638
RB10
RB1
N
NCH3



LA639
RA3
RB1
N
NCH3



LA640
RA34
RB1
N
NCH3



LA641
H
RB1
N
C(CH3)2



LA642
RB1
RB1
N
C(CH3)2



LA643
RB3
RB1
N
C(CH3)2



LA644
RB4
RB1
N
C(CH3)2



LA645
RB7
RB1
N
C(CH3)2



LA646
RB10
RB1
N
C(CH3)2



LA647
RA3
RB1
N
C(CH3)2



LA648
RA34
RB1
N
C(CH3)2



LA649
H
RB1
N
Si(CH3)2



LA650
RB1
RB1
N
Si(CH3)2



LA651
RB3
RB1
N
Si(CH3)2



LA652
RB4
RB1
N
Si(CH3)2



LA653
RB7
RB1
N
Si(CH3)2



LA654
RB10
RB1
N
Si(CH3)2



LA655
RA3
RB1
N
Si(CH3)2



LA656
RA34
RB1
N
Si(CH3)2



LA657
H
RB2
N
S



LA658
RB1
RB2
N
S



LA659
RB3
RB2
N
S



LA660
RB4
RB2
N
S



LA661
RB7
RB2
N
S



LA662
RB10
RB2
N
S



LA663
RA3
RB2
N
S



LA664
RA34
RB2
N
S



LA665
H
RB2
N
O



LA666
RB1
RB2
N
O



LA667
RB3
RB2
N
O



LA668
RB4
RB2
N
O



LA669
RB7
RB2
N
O



LA670
RB10
RB2
N
O



LA671
RA3
RB2
N
O



LA672
RA34
RB2
N
O



LA673
H
RB2
N
NCH3



LA674
RB1
RB2
N
NCH3



LA675
RB3
RB2
N
NCH3



LA676
RB4
RB2
N
NCH3



LA677
RB7
RB2
N
NCH3



LA678
RB10
RB2
N
NCH3



LA679
RA3
RB2
N
NCH3



LA680
RA34
RB2
N
NCH3



LA681
H
RB2
N
C(CH3)2



LA682
RB1
RB2
N
C(CH3)2



LA683
RB3
RB2
N
C(CH3)2



LA684
RB4
RB2
N
C(CH3)2



LA685
RB7
RB2
N
C(CH3)2



LA686
RB10
RB2
N
C(CH3)2



LA687
RA3
RB2
N
C(CH3)2



LA688
RA34
RB2
N
C(CH3)2



LA689
H
RB2
N
Si(CH3)2



LA690
RB1
RB2
N
Si(CH3)2



LA691
RB3
RB2
N
Si(CH3)2



LA692
RB4
RB2
N
Si(CH3)2



LA693
RB7
RB2
N
Si(CH3)2



LA694
RB10
RB2
N
Si(CH3)2



LA695
RA3
RB2
N
Si(CH3)2



LA696
RA34
RB2
N
Si(CH3)2










wherein LA697 through LA816 have a structure of Formula VI:





wherein R2, R3, and Y are defined as provided below:


















Ligand
R2
R3
Y
Ligand
R1
R2
R14







LA697
H
H
S
LA757
RB1
RB4
NCH3


LA698
H
RB1
S
LA758
RB1
RB5
NCH3


LA699
H
RB2
S
LA759
RB1
RA34
NCH3


LA700
H
RB3
S
LA760
RB1
RA52
NCH3


LA701
H
RB4
S
LA761
RB1
H
C(CH3)2


LA702
H
RB5
S
LA762
RB1
RB1
C(CH3)2


LA703
H
RA34
S
LA763
RB1
RB2
C(CH3)2


LA704
H
RA52
S
LA764
RB1
RB3
C(CH3)2


LA705
H
H
O
LA765
RB1
RB4
C(CH3)2


LA706
H
RB1
O
LA766
RB1
RB5
C(CH3)2


LA707
H
RB2
O
LA767
RB1
RA34
C(CH3)2


LA708
H
RB3
O
LA768
RB1
RA52
C(CH3)2


LA709
H
RB4
O
LA769
RB1
H
Si(CH3)2


LA710
H
RB5
O
LA770
RB1
RB1
Si(CH3)2


LA711
H
RA34
O
LA771
RB1
RB2
Si(CH3)2


LA712
H
RA52
O
LA772
RB1
RB3
Si(CH3)2


LA713
H
H
NCH3
LA773
RB1
RB4
Si(CH3)2


LA714
H
RB1
NCH3
LA774
RB1
RB5
Si(CH3)2


LA715
H
RB2
NCH3
LA775
RB1
RA34
Si(CH3)2


LA716
H
RB3
NCH3
LA776
RB1
RA52
Si(CH3)2


LA717
H
RB4
NCH3
LA777
RB2
H
S


LA718
H
RB5
NCH3
LA778
RB2
RB1
S


LA719
H
RA34
NCH3
LA779
RB2
RB2
S


LA720
H
RA52
NCH3
LA780
RB2
RB3
S


LA721
H
H
C(CH3)2
LA781
RB2
RB4
S


LA722
H
RB1
C(CH3)2
LA782
RB2
RB5
S


LA723
H
RB2
C(CH3)2
LA783
RB2
RA34
S


LA724
H
RB3
C(CH3)2
LA784
RB2
RA52
S


LA725
H
RB4
C(CH3)2
LA785
RB2
H
O


LA726
H
RB5
C(CH3)2
LA786
RB2
RB1
O


LA727
H
RA34
C(CH3)2
LA787
RB2
RB2
O


LA728
H
RA52
C(CH3)2
LA788
RB2
RB3
O


LA729
H
H
Si(CH3)2
LA789
RB2
RB4
O


LA730
H
RB1
Si(CH3)2
LA790
RB2
RB5
O


LA731
H
RB2
Si(CH3)2
LA791
RB2
RA34
O


LA732
H
RB3
Si(CH3)2
LA792
RB2
RA52
O


LA733
H
RB4
Si(CH3)2
LA793
RB2
H
NCH3


LA734
H
RB5
Si(CH3)2
LA794
RB2
RB1
NCH3


LA735
H
RA34
Si(CH3)2
LA795
RB2
RB2
NCH3


LA736
H
RA52
Si(CH3)2
LA796
RB2
RB3
NCH3


LA737
RB1
H
S
LA797
RB2
RB4
NCH3


LA738
RB1
RB1
S
LA798
RB2
RB5
NCH3


LA739
RB1
RB2
S
LA799
RB2
RA34
NCH3


LA740
RB1
RB3
S
LA800
RB2
RA52
NCH3


LA741
RB1
RB4
S
LA801
RB2
H
C(CH3)2


LA742
RB1
RB5
S
LA802
RB2
RB1
C(CH3)2


LA743
RB1
RA34
S
LA803
RB2
RB2
C(CH3)2


LA744
RB1
RA52
S
LA804
RB2
RB3
C(CH3)2


LA745
RB1
H
O
LA805
RB2
RB4
C(CH3)2


LA746
RB1
RB1
O
LA806
RB2
RB5
C(CH3)2


LA747
RB1
RB2
O
LA807
RB2
RA34
C(CH3)2


LA748
RB1
RB3
O
LA808
RB2
RA52
C(CH3)2


LA749
RB1
RB4
O
LA809
RB2
H
Si(CH3)2


LA750
RB1
RB5
O
LA810
RB2
RB1
Si(CH3)2


LA751
RB1
RA34
O
LA811
RB2
RB2
Si(CH3)2


LA752
RB1
RA52
O
LA812
RB2
RB3
Si(CH3)2


LA753
RB1
H
NCH3
LA813
RB2
RB4
Si(CH3)2


LA754
RB1
RB1
NCH3
LA814
RB2
RB5
Si(CH3)2


LA755
RB1
RB2
NCH3
LA815
RB2
RA34
Si(CH3)2


LA756
RB1
RB3
NCH3
LA816
RB2
RA52
Si(CH3)2









wherein LA817 through LA912 have a structure of Formula VII:





wherein R2, R4, and Y are defined as provided below:


















Ligand
R2
R4
Y
Z









LA817
H
H
S
S



LA818
H
RB1
S
S



LA819
H
RB3
S
S



LA820
H
RB4
S
S



LA821
H
RB7
S
S



LA822
H
RB10
S
S



LA823
H
RA3
S
S



LA824
H
RA34
S
S



LA825
H
H
S
O



LA826
H
RB1
S
O



LA827
H
RB3
S
O



LA828
H
RB4
S
O



LA829
H
RB7
S
O



LA830
H
RB10
S
O



LA831
H
RA3
S
O



LA832
H
RA34
S
O



LA833
H
H
S
NCH3



LA834
H
RB1
S
NCH3



LA835
H
RB3
S
NCH3



LA836
H
RB4
S
NCH3



LA837
H
RB7
S
NCH3



LA838
H
RB10
S
NCH3



LA839
H
RA3
S
NCH3



LA840
H
RA34
S
NCH3



LA841
H
H
O
S



LA842
H
RB1
O
S



LA843
H
RB3
O
S



LA844
H
RB4
O
S



LA845
H
RB7
O
S



LA846
H
RB10
O
S



LA847
H
RA3
O
S



LA848
H
RA34
O
S



LA849
H
H
O
O



LA850
H
RB1
O
O



LA851
H
RB3
O
O



LA852
H
RB4
O
O



LA853
H
RB7
O
O



LA854
H
RB10
O
O



LA855
H
RA3
O
O



LA856
H
RA34
O
O



LA857
H
H
O
NCH3



LA858
H
RB1
O
NCH3



LA859
H
RB3
O
NCH3



LA860
H
RB4
O
NCH3



LA861
H
RB7
O
NCH3



LA862
H
RB10
O
NCH3



LA863
H
RA3
O
NCH3



LA864
H
RA34
O
NCH3



LA865
RB1
H
S
S



LA866
RB1
RB1
S
S



LA867
RB1
RB3
S
S



LA868
RB1
RB4
S
S



LA869
RB1
RB7
S
S



LA870
RB1
RB10
S
S



LA871
RB1
RA3
S
S



LA872
RB1
RA34
S
S



LA873
RB1
H
S
O



LA874
RB1
RB1
S
O



LA875
RB1
RB3
S
O



LA876
RB1
RB4
S
O



LA877
RB1
RB7
S
O



LA878
RB1
RB10
S
O



LA879
RB1
RA3
S
O



LA880
RB1
RA34
S
O



LA881
RB1
H
S
NCH3



LA882
RB1
RB1
S
NCH3



LA883
RB1
RB3
S
NCH3



LA884
RB1
RB4
S
NCH3



LA885
RB1
RB7
S
NCH3



LA886
RB1
RB10
S
NCH3



LA887
RB1
RA3
S
NCH3



LA888
RB1
RA34
S
NCH3



LA889
RB1
H
O
S



LA890
RB1
RB1
O
S



LA891
RB1
RB3
O
S



LA892
RB1
RB4
O
S



LA893
RB1
RB7
O
S



LA894
RB1
RB10
O
S



LA895
RB1
RA3
O
S



LA896
RB1
RA34
O
S



LA897
RB1
H
O
O



LA898
RB1
RB1
O
O



LA899
RB1
RB3
O
O



LA900
RB1
RB4
O
O



LA901
RB1
RB7
O
O



LA902
RB1
RB10
O
O



LA903
RB1
RA3
O
O



LA904
RB1
RA34
O
O



LA905
RB1
H
O
NCH3



LA906
RB1
RB1
O
NCH3



LA907
RB1
RB3
O
NCH3



LA908
RB1
RB4
O
NCH3



LA909
RB1
RB7
O
NCH3



LA910
RB1
RB10
O
NCH3



LA911
RB1
RA3
O
NCH3



LA912
RB1
RA34
O
NCH3










wherein LA913 through LA1152 have a structure of Formula VIII:





wherein R1, R2, Y, and X are defined as provided below:


















Ligand
R1
R2
X
Y









LA913
H
H
C
S



LA914
RB1
H
C
S



LA915
RB3
H
C
S



LA916
RB4
H
C
S



LA917
RB7
H
C
S



LA918
RB10
H
C
S



LA919
RA3
H
C
S



LA920
RA34
H
C
S



LA921
H
H
C
O



LA922
RB1
H
C
O



LA923
RB3
H
C
O



LA924
RB4
H
C
O



LA925
RB7
H
C
O



LA926
RB10
H
C
O



LA927
RA3
H
C
O



LA928
RA34
H
C
O



LA929
H
H
C
NCH3



LA930
RB1
H
C
NCH3



LA931
RB3
H
C
NCH3



LA932
RB4
H
C
NCH3



LA933
RB7
H
C
NCH3



LA934
RB10
H
C
NCH3



LA935
RA3
H
C
NCH3



LA936
RA34
H
C
NCH3



LA937
H
H
C
C(CH3)2



LA938
RB1
H
C
C(CH3)2



LA939
RB3
H
C
C(CH3)2



LA940
RB4
H
C
C(CH3)2



LA941
RB7
H
C
C(CH3)2



LA942
RB10
H
C
C(CH3)2



LA943
RA3
H
C
C(CH3)2



LA944
RA34
H
C
C(CH3)2



LA945
H
H
C
Si(CH3)2



LA946
RB1
H
C
Si(CH3)2



LA947
RB3
H
C
Si(CH3)2



LA948
RB4
H
C
Si(CH3)2



LA949
RB7
H
C
Si(CH3)2



LA950
RB10
H
C
Si(CH3)2



LA951
RA3
H
C
Si(CH3)2



LA952
RA34
H
C
Si(CH3)2



LA953
H
RB1
C
S



LA954
RB1
RB1
C
S



LA955
RB3
RB1
C
S



LA956
RB4
RB1
C
S



LA957
RB7
RB1
C
S



LA958
RB10
RB1
C
S



LA959
RA3
RB1
C
S



LA960
RA34
RB1
C
S



LA961
H
RB1
C
O



LA962
RB1
RB1
C
O



LA963
RB3
RB1
C
O



LA964
RB4
RB1
C
O



LA965
RB7
RB1
C
O



LA966
RB10
RB1
C
O



LA967
RA3
RB1
C
O



LA968
RA34
RB1
C
O



LA969
H
RB1
C
NCH3



LA970
RB1
RB1
C
NCH3



LA971
RB3
RB1
C
NCH3



LA972
RB4
RB1
C
NCH3



LA973
RB7
RB1
C
NCH3



LA974
RB10
RB1
C
NCH3



LA975
RA3
RB1
C
NCH3



LA976
RA34
RB1
C
NCH3



LA977
H
RB1
C
C(CH3)2



LA978
RB1
RB1
C
C(CH3)2



LA979
RB3
RB1
C
C(CH3)2



LA980
RB4
RB1
C
C(CH3)2



LA981
RB7
RB1
C
C(CH3)2



LA982
RB10
RB1
C
C(CH3)2



LA983
RA3
RB1
C
C(CH3)2



LA984
RA34
RB1
C
C(CH3)2



LA985
H
RB1
C
Si(CH3)2



LA986
RB1
RB1
C
Si(CH3)2



LA987
RB3
RB1
C
Si(CH3)2



LA988
RB4
RB1
C
Si(CH3)2



LA989
RB7
RB1
C
Si(CH3)2



LA990
RB10
RB1
C
Si(CH3)2



LA991
RA3
RB1
C
Si(CH3)2



LA992
RA34
RB1
C
Si(CH3)2



LA993
H
RB2
C
S



LA994
RB1
RB2
C
S



LA995
RB3
RB2
C
S



LA996
RB4
RB2
C
S



LA997
RB7
RB2
C
S



LA998
RB10
RB2
C
S



LA999
RA3
RB2
C
S



LA1000
RA34
RB2
C
S



LA100l
H
RB2
C
O



LA1002
RB1
RB2
C
O



LA1003
RB3
RB2
C
O



LA1004
RB4
RB2
C
O



LA1005
RB7
RB2
C
O



LA1006
RB10
RB2
C
O



LA1007
RA3
RB2
C
O



LA1008
RA34
RB2
C
O



LA1009
H
RB2
C
NCH3



LA1010
RB1
RB2
C
NCH3



LA1011
RB3
RB2
C
NCH3



LA1012
RB4
RB2
C
NCH3



LA1013
RB7
RB2
C
NCH3



LA1014
RB10
RB2
C
NCH3



LA1015
RA3
RB2
C
NCH3



LA1016
RA34
RB2
C
NCH3



LA1017
H
RB2
C
C(CH3)2



LA1018
RB1
RB2
C
C(CH3)2



LA1019
RB3
RB2
C
C(CH3)2



LA1020
RB4
RB2
C
C(CH3)2



LA1021
RB7
RB2
C
C(CH3)2



LA1022
RB10
RB2
C
C(CH3)2



LA1023
RA3
RB2
C
C(CH3)2



LA1024
RA34
RB2
C
C(CH3)2



LA1025
H
RB2
C
Si(CH3)2



LA1026
RB1
RB2
C
Si(CH3)2



LA1027
RB3
RB2
C
Si(CH3)2



LA1028
RB4
RB2
C
Si(CH3)2



LA1029
RB7
RB2
C
Si(CH3)2



LA1030
RB10
RB2
C
Si(CH3)2



LA1031
RA3
RB2
C
Si(CH3)2



LA1032
RA34
RB2
C
Si(CH3)2



LA1033
H
H
N
S



LA1034
RB1
H
N
S



LA1035
RB3
H
N
S



LA1036
RB4
H
N
S



LA1037
RB7
H
N
S



LA1038
RB10
H
N
S



LA1039
RA3
H
N
S



LA1040
RA34
H
N
S



LA1041
H
H
N
O



LA1042
RB1
H
N
O



LA1043
RB3
H
N
O



LA1044
RB4
H
N
O



LA1045
RB7
H
N
O



LA1046
RB10
H
N
O



LA1047
RA3
H
N
O



LA1048
RA34
H
N
O



LA1049
H
H
N
NCH3



LA1050
RB1
H
N
NCH3



LA1051
RB3
H
N
NCH3



LA1052
RB4
H
N
NCH3



LA1053
RB7
H
N
NCH3



LA1054
RB10
H
N
NCH3



LA1055
RA3
H
N
NCH3



LA1056
RA34
H
N
NCH3



LA1057
H
H
N
C(CH3)2



LA1058
RB1
H
N
C(CH3)2



LA1059
RB3
H
N
C(CH3)2



LA1060
RB4
H
N
C(CH3)2



LA1061
RB7
H
N
C(CH3)2



LA1062
RB10
H
N
C(CH3)2



LA1063
RA3
H
N
C(CH3)2



LA1064
RA34
H
N
C(CH3)2



LA1065
H
H
N
Si(CH3)2



LA1066
RB1
H
N
Si(CH3)2



LA1067
RB3
H
N
Si(CH3)2



LA1068
RB4
H
N
Si(CH3)2



LA1069
RB7
H
N
Si(CH3)2



LA1070
RB10
H
N
Si(CH3)2



LA1071
RA3
H
N
Si(CH3)2



LA1072
RA34
H
N
Si(CH3)2



LA1073
H
RB1
N
S



LA1074
RB1
RB1
N
S



LA1075
RB3
RB1
N
S



LA1076
RB4
RB1
N
S



LA1077
RB7
RB1
N
S



LA1078
RB10
RB1
N
S



LA1079
RA3
RB1
N
S



LA1080
RA34
RB1
N
S



LA1081
H
RB1
N
O



LA1082
RB1
RB1
N
O



LA1083
RB3
RB1
N
O



LA1084
RB4
RB1
N
O



LA1085
RB7
RB1
N
O



LA1086
RB10
RB1
N
O



LA1087
RA3
RB1
N
O



LA1088
RA34
RB1
N
O



LA1089
H
RB1
N
NCH3



LA1090
RB1
RB1
N
NCH3



LA1091
RB3
RB1
N
NCH3



LA1092
RB4
RB1
N
NCH3



LA1093
RB7
RB1
N
NCH3



LA1094
RB10
RB1
N
NCH3



LA1095
RA3
RB1
N
NCH3



LA1096
RA34
RB1
N
NCH3



LA1097
H
RB1
N
C(CH3)2



LA1098
RB1
RB1
N
C(CH3)2



LA1099
RB3
RB1
N
C(CH3)2



LA1100
RB4
RB1
N
C(CH3)2



LA1101
RB7
RB1
N
C(CH3)2



LA1102
RB10
RB1
N
C(CH3)2



LA1103
RA3
RB1
N
C(CH3)2



LA1104
RA34
RB1
N
C(CH3)2



LA1105
H
RB1
N
Si(CH3)2



LA1106
RB1
RB1
N
Si(CH3)2



LA1107
RB3
RB1
N
Si(CH3)2



LA1108
RB4
RB1
N
Si(CH3)2



LA1109
RB7
RB1
N
Si(CH3)2



LA1110
RB10
RB1
N
Si(CH3)2



LA1111
RA3
RB1
N
Si(CH3)2



LA1112
RA34
RB1
N
Si(CH3)2



LA1113
H
RB2
N
S



LA1114
RB1
RB2
N
S



LA1115
RB3
RB2
N
S



LA1116
RB4
RB2
N
S



LA1117
RB7
RB2
N
S



LA1118
RB10
RB2
N
S



LA1119
RA3
RB2
N
S



LA1120
RA34
RB2
N
S



LA1121
H
RB2
N
O



LA1122
RB1
RB2
N
O



LA1123
RB3
RB2
N
O



LA1124
RB4
RB2
N
O



LA1125
RB7
RB2
N
O



LA1126
RB10
RB2
N
O



LA1127
RA3
RB2
N
O



LA1128
RA34
RB2
N
O



LA1129
H
RB2
N
NCH3



LA1130
RB1
RB2
N
NCH3



LA1131
RB3
RB2
N
NCH3



LA1132
RB4
RB2
N
NCH3



LA1133
RB7
RB2
N
NCH3



LA1134
RB10
RB2
N
NCH3



LA1135
RA3
RB2
N
NCH3



LA1136
RA34
RB2
N
NCH3



LA1137
H
RB2
N
C(CH3)2



LA1138
RB1
RB2
N
C(CH3)2



LA1139
RB3
RB2
N
C(CH3)2



LA1140
RB4
RB2
N
C(CH3)2



LA1141
RB7
RB2
N
C(CH3)2



LA1142
RB10
RB2
N
C(CH3)2



LA1143
RA3
RB2
N
C(CH3)2



LA1144
RA34
RB2
N
C(CH3)2



LA1145
H
RB2
N
Si(CH3)2



LA1146
RB1
RB2
N
Si(CH3)2



LA1147
RB3
RB2
N
Si(CH3)2



LA1148
RB4
RB2
N
Si(CH3)2



LA1149
RB7
RB2
N
Si(CH3)2



LA1150
RB10
RB2
N
Si(CH3)2



LA1151
RA3
RB2
N
Si(CH3)2



LA1152
RA34
RB2
N
Si(CH3)2










wherein LA1153 through LA1272 have a structure of Formula IX:





wherein R2, R3, and Y are defined as provided below:


















Ligand
R2
R3
Y
Ligand
R1
R2
R14







LA1153
H
H
S
LA1213
RB1
RB4
NCH3


LA1154
H
RB1
S
LA1214
RB1
RB5
NCH3


LA1155
H
RB2
S
LA1215
RB1
RA34
NCH3


LA1156
H
RB3
S
LA1216
RB1
RA52
NCH3


LA1157
H
RB4
S
LA1217
RB1
H
C(CH3)2


LA1158
H
RB5
S
LA1218
RB1
RB1
C(CH3)2


LA1159
H
RA34
S
LA1219
RB1
RB2
C(CH3)2


LA1160
H
RA52
S
LA1220
RB1
RB3
C(CH3)2


LA1161
H
H
O
LA1221
RB1
RB4
C(CH3)2


LA1162
H
RB1
O
LA1222
RB1
RB5
C(CH3)2


LA1163
H
RB2
O
LA1223
RB1
RA34
C(CH3)2


LA1164
H
RB3
O
LA1224
RB1
RA52
C(CH3)2


LA1165
H
RB4
O
LA1225
RB1
H
Si(CH3)2


LA1166
H
RB5
O
LA1226
RB1
RB1
Si(CH3)2


LA1167
H
RA34
O
LA1227
RB1
RB2
Si(CH3)2


LA1168
H
RA52
O
LA1228
RB1
RB3
Si(CH3)2


LA1169
H
H
NCH3
LA1229
RB1
RB4
Si(CH3)2


LA1170
H
RB1
NCH3
LA1230
RB1
RB5
Si(CH3)2


LA1171
H
RB2
NCH3
LA1231
RB1
RA34
Si(CH3)2


LA1172
H
RB3
NCH3
LA1232
RB1
RA52
Si(CH3)2


LA1173
H
RB4
NCH3
LA1233
RB2
H
S


LA1174
H
RB5
NCH3
LA1234
RB2
RB1
S


LA1175
H
RA34
NCH3
LA1235
RB2
RB2
S


LA1176
H
RA52
NCH3
LA1236
RB2
RB3
S


LA1177
H
H
C(CH3)2
LA1237
RB2
RB4
S


LA1178
H
RB1
C(CH3)2
LA1238
RB2
RB5
S


LA1179
H
RB2
C(CH3)2
LA1239
RB2
RA34
S


LA1180
H
RB3
C(CH3)2
LA1240
RB2
RA52
S


LA1181
H
RB4
C(CH3)2
LA1241
RB2
H
O


LA1182
H
RB5
C(CH3)2
LA1242
RB2
RB1
O


LA1183
H
RA34
C(CH3)2
LA1243
RB2
RB2
O


LA1184
H
RA52
C(CH3)2
LA1244
RB2
RB3
O


LA1185
H
H
Si(CH3)2
LA1245
RB2
RB4
O


LA1186
H
RB1
Si(CH3)2
LA1246
RB2
RB5
O


LA1187
H
RB2
Si(CH3)2
LA1247
RB2
RA34
O


LA1188
H
RB3
Si(CH3)2
LA1248
RB2
RA52
O


LA1189
H
RB4
Si(CH3)2
LA1249
RB2
H
NCH3


LA1190
H
RB5
Si(CH3)2
LA1250
RB2
RB1
NCH3


LA1191
H
RA34
Si(CH3)2
LA1251
RB2
RB2
NCH3


LA1192
H
RA52
Si(CH3)2
LA1252
RB2
RB3
NCH3


LA1193
RB1
H
S
LA1253
RB2
RB4
NCH3


LA1194
RB1
RB1
S
LA1254
RB2
RB5
NCH3


LA1195
RB1
RB2
S
LA1255
RB2
RA34
NCH3


LA1196
RB1
RB3
S
LA1256
RB2
RA52
NCH3


LA1197
RB1
RB4
S
LA1257
RB2
H
C(CH3)2


LA1198
RB1
RB5
S
LA1258
RB2
RB1
C(CH3)2


LA1199
RB1
RA34
S
LA1259
RB2
RB2
C(CH3)2


LA1200
RB1
RA52
S
LA1260
RB2
RB3
C(CH3)2


LA1201
RB1
H
O
LA1261
RB2
RB4
C(CH3)2


LA1202
RB1
RB1
O
LA1262
RB2
RB5
C(CH3)2


LA1203
RB1
RB2
O
LA1263
RB2
RA34
C(CH3)2


LA1204
RB1
RB3
O
LA1264
RB2
RA52
C(CH3)2


LA1205
RB1
RB4
O
LA1265
RB2
H
Si(CH3)2


LA1206
RB1
RB5
O
LA1266
RB2
RB1
Si(CH3)2


LA1207
RB1
RA34
O
LA1267
RB2
RB2
Si(CH3)2


LA1208
RB1
RA52
O
LA1268
RB2
RB3
Si(CH3)2


LA1209
RB1
H
NCH3
LA1269
RB2
RB4
Si(CH3)2


LA1210
RB1
RB1
NCH3
LA1270
RB2
RB5
Si(CH3)2


LA1211
RB1
RB2
NCH3
LA1271
RB2
RA34
Si(CH3)2


LA1212
RB1
RB3
NCH3
LA1272
RB2
RA52
Si(CH3)2









wherein LA1273 through LA1368 have a structure of Formula X:





wherein R2, R4, Y, and Z are defined as provided below:


















Ligand
R2
R4
Y
Z









LA1273
H
H
S
S



LA1274
H
RB1
S
S



LA1275
H
RB3
S
S



LA1276
H
RB4
S
S



LA1277
H
RB7
S
S



LA1278
H
RB10
S
S



LA1279
H
RA3
S
S



LA1280
H
RA34
S
S



LA1281
H
H
S
O



LA1282
H
RB1
S
O



LA1283
H
RB3
S
O



LA1284
H
RB4
S
O



LA1285
H
RB7
S
O



LA1286
H
RB10
S
O



LA1287
H
RA3
S
O



LA1288
H
RA34
S
O



LA1289
H
H
S
NCH3



LA1290
H
RB1
S
NCH3



LA1291
H
RB3
S
NCH3



LA1292
H
RB4
S
NCH3



LA1293
H
RB7
S
NCH3



LA1294
H
RB10
S
NCH3



LA1295
H
RA3
S
NCH3



LA1296
H
RA34
S
NCH3



LA1297
H
H
O
S



LA1298
H
RB1
O
S



LA1299
H
RB3
O
S



LA1300
H
RB4
O
S



LA1301
H
RB7
O
S



LA1302
H
RB10
O
S



LA1303
H
RA3
O
S



LA1304
H
RA34
O
S



LA1305
H
H
O
O



LA1306
H
RB1
O
O



LA1307
H
RB3
O
O



LA1308
H
RB4
O
O



LA1309
H
RB7
O
O



LA1310
H
RB10
O
O



LA1311
H
RA3
O
O



LA1312
H
RA34
O
O



LA1313
H
H
O
NCH3



LA1314
H
RB1
O
NCH3



LA1315
H
RB3
O
NCH3



LA1316
H
RB4
O
NCH3



LA1317
H
RB7
O
NCH3



LA1318
H
RB10
O
NCH3



LA1319
H
RA3
O
NCH3



LA1320
H
RA34
O
NCH3



LA1321
RB1
H
S
S



LA1322
RB1
RB1
S
S



LA1323
RB1
RB3
S
S



LA1324
RB1
RB4
S
S



LA1325
RB1
RB7
S
S



LA1326
RB1
RB10
S
S



LA1327
RB1
RA3
S
S



LA1328
RB1
RA34
S
S



LA1329
RB1
H
S
O



LA1330
RB1
RB1
S
O



LA1331
RB1
RB3
S
O



LA1332
RB1
RB4
S
O



LA1333
RB1
RB7
S
O



LA1334
RB1
RB10
S
O



LA1335
RB1
RA3
S
O



LA1336
RB1
RA34
S
O



LA1337
RB1
H
S
NCH3



LA1338
RB1
RB1
S
NCH3



LA1339
RB1
RB3
S
NCH3



LA1340
RB1
RB4
S
NCH3



LA1341
RB1
RB7
S
NCH3



LA1342
RB1
RB10
S
NCH3



LA1343
RB1
RA3
S
NCH3



LA1344
RB1
RA34
S
NCH3



LA1345
RB1
H
O
S



LA1346
RB1
RB1
O
S



LA1347
RB1
RB3
O
S



LA1348
RB1
RB4
O
S



LA1349
RB1
RB7
O
S



LA1350
RB1
RB10
O
S



LA1351
RB1
RA3
O
S



LA1352
RB1
RA34
O
S



LA1353
RB1
H
O
O



LA1354
RB1
RB1
O
O



LA1355
RB1
RB3
O
O



LA1356
RB1
RB4
O
O



LA1357
RB1
RB7
O
O



LA1358
RB1
RB10
O
O



LA1359
RB1
RA3
O
O



LA1360
RB1
RA34
O
O



LA1361
RB1
H
O
NCH3



LA1362
RB1
RB1
O
NCH3



LA1363
RB1
RB3
O
NCH3



LA1364
RB1
RB4
O
NCH3



LA1365
RB1
RB7
O
NCH3



LA1366
RB1
RB10
O
NCH3



LA1367
RB1
RA3
O
NCH3



LA1368
RB1
RA34
O
NCH3










wherein LA1369 through LA1608 have a structure of Formula XI:





wherein R1, R2, X, and Y are defined as provided below:


















Ligand
R1
R2
X
Y









LA1369
H
H
C
S



LA1370
RB1
H
C
S



LA1371
RB3
H
C
S



LA1372
RB4
H
C
S



LA1373
RB7
H
C
S



LA1374
RB10
H
C
S



LA1375
RA3
H
C
S



LA1376
RA34
H
C
S



LA1377
H
H
C
O



LA1378
RB1
H
C
O



LA1379
RB3
H
C
O



LA1380
RB4
H
C
O



LA1381
RB7
H
C
O



LA1382
RB10
H
C
O



LA1383
RA3
H
C
O



LA1384
RA34
H
C
O



LA1385
H
H
C
NCH3



LA1386
RB1
H
C
NCH3



LA1387
RB3
H
C
NCH3



LA1388
RB4
H
C
NCH3



LA1389
RB7
H
C
NCH3



LA1390
RB10
H
C
NCH3



LA1391
RA3
H
C
NCH3



LA1392
RA34
H
C
NCH3



LA1393
H
H
C
C(CH3)2



LA1394
RB1
H
C
C(CH3)2



LA1395
RB3
H
C
C(CH3)2



LA1396
RB4
H
C
C(CH3)2



LA1397
RB7
H
C
C(CH3)2



LA1398
RB10
H
C
C(CH3)2



LA1399
RA3
H
C
C(CH3)2



LA1400
RA34
H
C
C(CH3)2



LA1401
H
H
C
Si(CH3)2



LA1402
RB1
H
C
Si(CH3)2



LA1403
RB3
H
C
Si(CH3)2



LA1404
RB4
H
C
Si(CH3)2



LA1405
RB7
H
C
Si(CH3)2



LA1406
RB10
H
C
Si(CH3)2



LA1407
RA3
H
C
Si(CH3)2



LA1408
RA34
H
C
Si(CH3)2



LA1409
H
RB1
C
S



LA1410
RB1
RB1
C
S



LA1411
RB3
RB1
C
S



LA1412
RB4
RB1
C
S



LA1413
RB7
RB1
C
S



LA1414
RB10
RB1
C
S



LA1415
RA3
RB1
C
S



LA1416
RA34
RB1
C
S



LA1417
H
RB1
C
O



LA1418
RB1
RB1
C
O



LA1419
RB3
RB1
C
O



LA1420
RB4
RB1
C
O



LA1421
RB7
RB1
C
O



LA1422
RB10
RB1
C
O



LA1423
RA3
RB1
C
O



LA1424
RA34
RB1
C
O



LA1425
H
RB1
C
NCH3



LA1426
RB1
RB1
C
NCH3



LA1427
RB3
RB1
C
NCH3



LA1428
RB4
RB1
C
NCH3



LA1429
RB7
RB1
C
NCH3



LA1430
RB10
RB1
C
NCH3



LA1431
RA3
RB1
C
NCH3



LA1432
RA34
RB1
C
NCH3



LA1433
H
RB1
C
C(CH3)2



LA1434
RB1
RB1
C
C(CH3)2



LA1435
RB3
RB1
C
C(CH3)2



LA1436
RB4
RB1
C
C(CH3)2



LA1437
RB7
RB1
C
C(CH3)2



LA1438
RB10
RB1
C
C(CH3)2



LA1439
RA3
RB1
C
C(CH3)2



LA1440
RA34
RB1
C
C(CH3)2



LA1441
H
RB1
C
Si(CH3)2



LA1442
RB1
RB1
C
Si(CH3)2



LA1443
RB3
RB1
C
Si(CH3)2



LA1444
RB4
RB1
C
Si(CH3)2



LA1445
RB7
RB1
C
Si(CH3)2



LA1446
RB10
RB1
C
Si(CH3)2



LA1447
RA3
RB1
C
Si(CH3)2



LA1448
RA34
RB1
C
Si(CH3)2



LA1449
H
RB2
C
S



LA1450
RB1
RB2
C
S



LA1451
RB3
RB2
C
S



LA1452
RB4
RB2
C
S



LA1453
RB7
RB2
C
S



LA1454
RB10
RB2
C
S



LA1455
RA3
RB2
C
S



LA1456
RA34
RB2
C
S



LA1457
H
RB2
C
O



LA1458
RB1
RB2
C
O



LA1459
RB3
RB2
C
O



LA1460
RB4
RB2
C
O



LA1461
RB7
RB2
C
O



LA1462
RB10
RB2
C
O



LA1463
RA3
RB2
C
O



LA1464
RA34
RB2
C
O



LA1465
H
RB2
C
NCH3



LA1466
RB1
RB2
C
NCH3



LA1467
RB3
RB2
C
NCH3



LA1468
RB4
RB2
C
NCH3



LA1469
RB7
RB2
C
NCH3



LA1470
RB10
RB2
C
NCH3



LA1471
RA3
RB2
C
NCH3



LA1472
RA34
RB2
C
NCH3



LA1473
H
RB2
C
C(CH3)2



LA1474
RB1
RB2
C
C(CH3)2



LA1475
RB3
RB2
C
C(CH3)2



LA1476
RB4
RB2
C
C(CH3)2



LA1477
RB7
RB2
C
C(CH3)2



LA1478
RB10
RB2
C
C(CH3)2



LA1479
RA3
RB2
C
C(CH3)2



LA1480
RA34
RB2
C
C(CH3)2



LA1481
H
RB2
C
Si(CH3)2



LA1482
RB1
RB2
C
Si(CH3)2



LA1483
RB3
RB2
C
Si(CH3)2



LA1484
RB4
RB2
C
Si(CH3)2



LA1485
RB7
RB2
C
Si(CH3)2



LA1486
RB10
RB2
C
Si(CH3)2



LA1487
RA3
RB2
C
Si(CH3)2



LA1488
RA34
RB2
C
Si(CH3)2



LA1489
H
H
N
S



LA1490
RB1
H
N
S



LA1491
RB3
H
N
S



LA1492
RB4
H
N
S



LA1493
RB7
H
N
S



LA1494
RB10
H
N
S



LA1495
RA3
H
N
S



LA1496
RA34
H
N
S



LA1497
H
H
N
O



LA1498
RB1
H
N
O



LA1499
RB3
H
N
O



LA1500
RB4
H
N
O



LA1501
RB7
H
N
O



LA1502
RB10
H
N
O



LA1503
RA3
H
N
O



LA1504
RA34
H
N
O



LA1505
H
H
N
NCH3



LA1506
RB1
H
N
NCH3



LA1507
RB3
H
N
NCH3



LA1508
RB4
H
N
NCH3



LA1509
RB7
H
N
NCH3



LA1510
RB10
H
N
NCH3



LA1511
RA3
H
N
NCH3



LA1512
RA34
H
N
NCH3



LA1513
H
H
N
C(CH3)2



LA1514
RB1
H
N
C(CH3)2



LA1515
RB3
H
N
C(CH3)2



LA1516
RB4
H
N
C(CH3)2



LA1517
RB7
H
N
C(CH3)2



LA1518
RB10
H
N
C(CH3)2



LA1519
RA3
H
N
C(CH3)2



LA1520
RA34
H
N
C(CH3)2



LA1521
H
H
N
Si(CH3)2



LA1522
RB1
H
N
Si(CH3)2



LA1523
RB3
H
N
Si(CH3)2



LA1524
RB4
H
N
Si(CH3)2



LA1525
RB7
H
N
Si(CH3)2



LA1526
RB10
H
N
Si(CH3)2



LA1527
RA3
H
N
Si(CH3)2



LA1528
RA34
H
N
Si(CH3)2



LA1529
H
RB1
N
S



LA1530
RB1
RB1
N
S



LA1531
RB3
RB1
N
S



LA1532
RB4
RB1
N
S



LA1533
RB7
RB1
N
S



LA1534
RB10
RB1
N
S



LA1535
RA3
RB1
N
S



LA1536
RA34
RB1
N
S



LA1537
H
RB1
N
O



LA1538
RB1
RB1
N
O



LA1539
RB3
RB1
N
O



LA1540
RB4
RB1
N
O



LA1541
RB7
RB1
N
O



LA1542
RB10
RB1
N
O



LA1543
RA3
RB1
N
O



LA1544
RA34
RB1
N
O



LA1545
H
RB1
N
NCH3



LA1546
RB1
RB1
N
NCH3



LA1547
RB3
RB1
N
NCH3



LA1548
RB4
RB1
N
NCH3



LA1549
RB7
RB1
N
NCH3



LA1550
RB10
RB1
N
NCH3



LA1551
RA3
RB1
N
NCH3



LA1552
RA34
RB1
N
NCH3



LA1553
H
RB1
N
C(CH3)2



LA1554
RB1
RB1
N
C(CH3)2



LA1555
RB3
RB1
N
C(CH3)2



LA1556
RB4
RB1
N
C(CH3)2



LA1557
RB7
RB1
N
C(CH3)2



LA1558
RB10
RB1
N
C(CH3)2



LA1559
RA3
RB1
N
C(CH3)2



LA1560
RA34
RB1
N
C(CH3)2



LA1561
H
RB1
N
Si(CH3)2



LA1562
RB1
RB1
N
Si(CH3)2



LA1563
RB3
RB1
N
Si(CH3)2



LA1564
RB4
RB1
N
Si(CH3)2



LA1565
RB7
RB1
N
Si(CH3)2



LA1566
RB10
RB1
N
Si(CH3)2



LA1567
RA3
RB1
N
Si(CH3)2



LA1568
RA34
RB1
N
Si(CH3)2



LA1569
H
RB2
N
S



LA1570
RB1
RB2
N
S



LA1571
RB3
RB2
N
S



LA1572
RB4
RB2
N
S



LA1573
RB7
RB2
N
S



LA1574
RB10
RB2
N
S



LA1575
RA3
RB2
N
S



LA1576
RA34
RB2
N
S



LA1577
H
RB2
N
O



LA1578
RB1
RB2
N
O



LA1579
RB3
RB2
N
O



LA1580
RB4
RB2
N
O



LA1581
RB7
RB2
N
O



LA1582
RB10
RB2
N
O



LA1583
RA3
RB2
N
O



LA1584
RA34
RB2
N
O



LA1585
H
RB2
N
NCH3



LA1586
RB1
RB2
N
NCH3



LA1587
RB3
RB2
N
NCH3



LA1588
RB4
RB2
N
NCH3



LA1589
RB7
RB2
N
NCH3



LA1590
RB10
RB2
N
NCH3



LA1591
RA3
RB2
N
NCH3



LA1592
RA34
RB2
N
NCH3



LA1593
H
RB2
N
C(CH3)2



LA1594
RB1
RB2
N
C(CH3)2



LA1595
RB3
RB2
N
C(CH3)2



LA1596
RB4
RB2
N
C(CH3)2



LA1597
RB7
RB2
N
C(CH3)2



LA1598
RB10
RB2
N
C(CH3)2



LA1599
RA3
RB2
N
C(CH3)2



LA1600
RA34
RB2
N
C(CH3)2



LA1601
H
RB2
N
Si(CH3)2



LA1602
RB1
RB2
N
Si(CH3)2



LA1603
RB3
RB2
N
Si(CH3)2



LA1604
RB4
RB2
N
Si(CH3)2



LA1605
RB7
RB2
N
Si(CH3)2



LA1606
RB10
RB2
N
Si(CH3)2



LA1607
RA3
RB2
N
Si(CH3)2



LA1608
RA34
RB2
N
Si(CH3)2










wherein LA1609 through LA1728 have a structure of Formula XII:





wherein R2, R3, and Y are defined as provided below:

















Ligand
R2
R3
Y









LA1609
H
H
S



LA1610
H
RB1
S



LA1611
H
RB2
S



LA1612
H
RB3
S



LA1613
H
RB4
S



LA1614
H
RB5
S



LA1615
H
RA34
S



LA1616
H
RA52
S



LA1617
H
H
O



LA1618
H
RB1
O



LA1619
H
RB2
O



LA1620
H
RB3
O



LA1621
H
RB4
O



LA1622
H
RB5
O



LA1623
H
RA34
O



LA1624
H
RA52
O



LA1625
H
H
NCH3



LA1626
H
RB1
NCH3



LA1627
H
RB2
NCH3



LA1628
H
RB3
NCH3



LA1629
H
RB4
NCH3



LA1630
H
RB5
NCH3



LA1631
H
RA34
NCH3



LA1632
H
RA52
NCH3



LA1633
H
H
C(CH3)2



LA1634
H
RB1
C(CH3)2



LA1635
H
RB2
C(CH3)2



LA1636
H
RB3
C(CH3)2



LA1637
H
RB4
C(CH3)2



LA1638
H
RB5
C(CH3)2



LA1639
H
RA34
C(CH3)2



LA1640
H
RA52
C(CH3)2



LA1641
H
H
Si(CH3)2



LA1642
H
RB1
Si(CH3)2



LA1643
H
RB2
Si(CH3)2



LA1644
H
RB3
Si(CH3)2



LA1645
H
RB4
Si(CH3)2



LA1646
H
RB5
Si(CH3)2



LA1647
H
RA34
Si(CH3)2



LA1648
H
RA52
Si(CH3)2



LA1649
RB1
H
S



LA1650
RB1
RB1
S



LA1651
RB1
RB2
S



LA1652
RB1
RB3
S



LA1653
RB1
RB4
S



LA1654
RB1
RB5
S



LA1655
RB1
RA34
S



LA1656
RB1
RA52
S



LA1657
RB1
H
O



LA1658
RB1
RB1
O



LA1659
RB1
RB2
O



LA1660
RB1
RB3
O



LA1661
RB1
RB4
O



LA1662
RB1
RB5
O



LA1663
RB1
RA34
O



LA1664
RB1
RA52
O



LA1665
RB1
H
NCH3



LA1666
RB1
RB1
NCH3



LA1667
RB1
RB2
NCH3



LA1668
RB1
RB3
NCH3



LA1669
RB1
RB4
NCH3



LA1670
RB1
RB5
NCH3



LA1671
RB1
RA34
NCH3



LA1672
RB1
RA52
NCH3



LA1673
RB1
H
C(CH3)2



LA1674
RB1
RB1
C(CH3)2



LA1675
RB1
RB2
C(CH3)2



LA1676
RB1
RB3
C(CH3)2



LA1677
RB1
RB4
C(CH3)2



LA1678
RB1
RB5
C(CH3)2



LA1679
RB1
RA34
C(CH3)2



LA1680
RB1
RA52
C(CH3)2



LA1681
RB1
H
Si(CH3)2



LA1682
RB1
RB1
Si(CH3)2



LA1683
RB1
RB2
Si(CH3)2



LA1684
RB1
RB3
Si(CH3)2



LA1685
RB1
RB4
Si(CH3)2



LA1686
RB1
RB5
Si(CH3)2



LA1687
RB1
RA34
Si(CH3)2



LA1688
RB1
RA52
Si(CH3)2



LA1689
RB2
H
S



LA1690
RB2
RB1
S



LA1691
RB2
RB2
S



LA1692
RB2
RB3
S



LA1693
RB2
RB4
S



LA1694
RB2
RB5
S



LA1695
RB2
RA34
S



LA1696
RB2
RA52
S



LA1697
RB2
H
O



LA1698
RB2
RB1
O



LA1699
RB2
RB2
O



LA1700
RB2
RB3
O



LA1701
RB2
RB4
O



LA1702
RB2
RB5
O



LA1703
RB2
RA34
O



LA1704
RB2
RA52
O



LA1705
RB2
H
NCH3



LA1706
RB2
RB1
NCH3



LA1707
RB2
RB2
NCH3



LA1708
RB2
RB3
NCH3



LA1709
RB2
RB4
NCH3



LA1710
RB2
RB5
NCH3



LA1711
RB2
RA34
NCH3



LA1712
RB2
RA52
NCH3



LA1713
RB2
H
C(CH3)2



LA1714
RB2
RB1
C(CH3)2



LA1715
RB2
RB2
C(CH3)2



LA1716
RB2
RB3
C(CH3)2



LA1717
RB2
RB4
C(CH3)2



LA1718
RB2
RB5
C(CH3)2



LA1719
RB2
RA34
C(CH3)2



LA1720
RB2
RA52
C(CH3)2



LA1721
RB2
H
Si(CH3)2



LA1722
RB2
RB1
Si(CH3)2



LA1723
RB2
RB2
Si(CH3)2



LA1724
RB2
RB3
Si(CH3)2



LA1725
RB2
RB4
Si(CH3)2



LA1726
RB2
RB5
Si(CH3)2



LA1727
RB2
RA34
Si(CH3)2



LA1728
RB2
RA52
Si(CH3)2










wherein LA1729 through LA1824 have a structure of Formula XIII:





wherein R2, R4, Y, and Z are defined as provided below:


















Ligand
R2
R4
Y
Z









LA1729
H
H
S
S



LA1730
H
RB1
S
S



LA1731
H
RB3
S
S



LA1732
H
RB4
S
S



LA1733
H
RB7
S
S



LA1734
H
RB10
S
S



LA1735
H
RA3
S
S



LA1736
H
RA34
S
S



LA1737
H
H
S
O



LA1738
H
RB1
S
O



LA1739
H
RB3
S
O



LA1740
H
RB4
S
O



LA1741
H
RB7
S
O



LA1742
H
RB10
S
O



LA1743
H
RA3
S
O



LA1744
H
RA34
S
O



LA1745
H
H
S
NCH3



LA1746
H
RB1
S
NCH3



LA1747
H
RB3
S
NCH3



LA1748
H
RB4
S
NCH3



LA1749
H
RB7
S
NCH3



LA1750
H
RB10
S
NCH3



LA1751
H
RA3
S
NCH3



LA1752
H
RA34
S
NCH3



LA1753
H
H
O
S



LA1754
H
RB1
O
S



LA1755
H
RB3
O
S



LA1756
H
RB4
O
S



LA1757
H
RB7
O
S



LA1758
H
RB10
O
S



LA1759
H
RA3
O
S



LA1760
H
RA34
O
S



LA1761
H
H
O
O



LA1762
H
RB1
O
O



LA1763
H
RB3
O
O



LA1764
H
RB4
O
O



LA1765
H
RB7
O
O



LA1766
H
RB10
O
O



LA1767
H
RA3
O
O



LA1768
H
RA34
O
O



LA1769
H
H
O
NCH3



LA1770
H
RB1
O
NCH3



LA1771
H
RB3
O
NCH3



LA1772
H
RB4
O
NCH3



LA1773
H
RB7
O
NCH3



LA1774
H
RB10
O
NCH3



LA1775
H
RA3
O
NCH3



LA1776
H
RA34
O
NCH3



LA1777
RB1
H
S
S



LA1778
RB1
RB1
S
S



LA1779
RB1
RB3
S
S



LA1780
RB1
RB4
S
S



LA1781
RB1
RB7
S
S



LA1782
RB1
RB10
S
S



LA1783
RB1
RA3
S
S



LA1784
RB1
RA34
S
S



LA1785
RB1
H
S
O



LA1786
RB1
RB1
S
O



LA1787
RB1
RB3
S
O



LA1788
RB1
RB4
S
O



LA1789
RB1
RB7
S
O



LA1790
RB1
RB10
S
O



LA1791
RB1
RA3
S
O



LA1792
RB1
RA34
S
O



LA1793
RB1
H
S
NCH3



LA1794
RB1
RB1
S
NCH3



LA1795
RB1
RB3
S
NCH3



LA1796
RB1
RB4
S
NCH3



LA1797
RB1
RB7
S
NCH3



LA1798
RB1
RB10
S
NCH3



LA1799
RB1
RA3
S
NCH3



LA1800
RB1
RA34
S
NCH3



LA1801
RB1
H
O
S



LA1802
RB1
RB1
O
S



LA1803
RB1
RB3
O
S



LA1804
RB1
RB4
O
S



LA1805
RB1
RB7
O
S



LA1806
RB1
RB10
O
S



LA1807
RB1
RA3
O
S



LA1808
RB1
RA34
O
S



LA1809
RB1
H
O
O



LA1810
RB1
RB1
O
O



LA1811
RB1
RB3
O
O



LA1812
RB1
RB4
O
O



LA1813
RB1
RB7
O
O



LA1814
RB1
RB10
O
O



LA1815
RB1
RA3
O
O



LA1816
RB1
RA34
O
O



LA1817
RB1
H
O
NCH3



LA1818
RB1
RB1
O
NCH3



LA1819
RB1
RB3
O
NCH3



LA1820
RB1
RB4
O
NCH3



LA1821
RB1
RB7
O
NCH3



LA1822
RB1
RB10
O
NCH3



LA1823
RB1
RA3
O
NCH3



LA1824
RB1
RA34
O
NCH3










wherein LA1825 through LA2064 have a structure of Formula XIV:





wherein R1, R5, X, and Y are defined as provided below:


















Ligand
R1
R5
X
Y









LA1825
H
H
C
S



LA1826
RB1
H
C
S



LA1827
RB3
H
C
S



LA1828
RB4
H
C
S



LA1829
RB7
H
C
S



LA1830
RB10
H
C
S



LA1831
RA3
H
C
S



LA1832
RA34
H
C
S



LA1833
H
H
C
O



LA1834
RB1
H
C
O



LA1835
RB3
H
C
O



LA1836
RB4
H
C
O



LA1837
RB7
H
C
O



LA1838
RB10
H
C
O



LA1839
RA3
H
C
O



LA1840
RA34
H
C
O



LA1841
H
H
C
NCH3



LA1842
RB1
H
C
NCH3



LA1843
RB3
H
C
NCH3



LA1844
RB4
H
C
NCH3



LA1845
RB7
H
C
NCH3



LA1846
RB10
H
C
NCH3



LA1847
RA3
H
C
NCH3



LA1848
RA34
H
C
NCH3



LA1849
H
H
C
C(CH3)2



LA1850
RB1
H
C
C(CH3)2



LA1851
RB3
H
C
C(CH3)2



LA1852
RB4
H
C
C(CH3)2



LA1853
RB7
H
C
C(CH3)2



LA1854
RB10
H
C
C(CH3)2



LA1855
RA3
H
C
C(CH3)2



LA1856
RA34
H
C
C(CH3)2



LA1857
H
H
C
Si(CH3)2



LA1858
RB1
H
C
Si(CH3)2



LA1859
RB3
H
C
Si(CH3)2



LA1860
RB4
H
C
Si(CH3)2



LA1861
RB7
H
C
Si(CH3)2



LA1862
RB10
H
C
Si(CH3)2



LA1863
RA3
H
C
Si(CH3)2



LA1864
RA34
H
C
Si(CH3)2



LA1865
H
RB1
C
S



LA1866
RB1
RB1
C
S



LA1867
RB3
RB1
C
S



LA1868
RB4
RB1
C
S



LA1869
RB7
RB1
C
S



LA1870
RB10
RB1
C
S



LA1871
RA3
RB1
C
S



LA1872
RA34
RB1
C
S



LA1873
H
RB1
C
O



LA1874
RB1
RB1
C
O



LA1875
RB3
RB1
C
O



LA1876
RB4
RB1
C
O



LA1877
RB7
RB1
C
O



LA1878
RB10
RB1
C
O



LA1879
RA3
RB1
C
O



LA1880
RA34
RB1
C
O



LA1881
H
RB1
C
NCH3



LA1882
RB1
RB1
C
NCH3



LA1883
RB3
RB1
C
NCH3



LA1884
RB4
RB1
C
NCH3



LA1885
RB7
RB1
C
NCH3



LA1886
RB10
RB1
C
NCH3



LA1887
RA3
RB1
C
NCH3



LA1888
RA34
RB1
C
NCH3



LA1889
H
RB1
C
C(CH3)2



LA1890
RB1
RB1
C
C(CH3)2



LA1891
RB3
RB1
C
C(CH3)2



LA1892
RB4
RB1
C
C(CH3)2



LA1893
RB7
RB1
C
C(CH3)2



LA1894
RB10
RB1
C
C(CH3)2



LA1895
RA3
RB1
C
C(CH3)2



LA1896
RA34
RB1
C
C(CH3)2



LA1897
H
RB1
C
Si(CH3)2



LA1898
RB1
RB1
C
Si(CH3)2



LA1899
RB3
RB1
C
Si(CH3)2



LA1900
RB4
RB1
C
Si(CH3)2



LA1901
RB7
RB1
C
Si(CH3)2



LA1902
RB10
RB1
C
Si(CH3)2



LA1903
RA3
RB1
C
Si(CH3)2



LA1904
RA34
RB1
C
Si(CH3)2



LA1905
H
RB6
C
S



LA1906
RB1
RB6
C
S



LA1907
RB3
RB6
C
S



LA1908
RB4
RB6
C
S



LA1909
RB7
RB6
C
S



LA1910
RB10
RB6
C
S



LA1911
RA3
RB6
C
S



LA1912
RA34
RB6
C
S



LA1913
H
RB6
C
O



LA1914
RB1
RB6
C
O



LA1915
RB3
RB6
C
O



LA1916
RB4
RB6
C
O



LA1917
RB7
RB6
C
O



LA1918
RB10
RB6
C
O



LA1919
RA3
RB6
C
O



LA1920
RA34
RB6
C
O



LA1921
H
RB6
C
NCH3



LA1922
RB1
RB6
C
NCH3



LA1923
RB3
RB6
C
NCH3



LA1924
RB4
RB6
C
NCH3



LA1925
RB7
RB6
C
NCH3



LA1926
RB10
RB6
C
NCH3



LA1927
RA3
RB6
C
NCH3



LA1928
RA34
RB6
C
NCH3



LA1929
H
RB6
C
C(CH3)2



LA1930
RB1
RB6
C
C(CH3)2



LA1931
RB3
RB6
C
C(CH3)2



LA1932
RB4
RB6
C
C(CH3)2



LA1933
RB7
RB6
C
C(CH3)2



LA1934
RB10
RB6
C
C(CH3)2



LA1935
RA3
RB6
C
C(CH3)2



LA1936
RA34
RB6
C
C(CH3)2



LA1937
H
RB6
C
Si(CH3)2



LA1938
RB1
RB6
C
Si(CH3)2



LA1939
RB3
RB6
C
Si(CH3)2



LA1940
RB4
RB6
C
Si(CH3)2



LA1941
RB7
RB6
C
Si(CH3)2



LA1942
RB10
RB6
C
Si(CH3)2



LA1943
RA3
RB6
C
Si(CH3)2



LA1944
RA34
RB6
C
Si(CH3)2



LA1945
H
H
N
S



LA1946
RB1
H
N
S



LA1947
RB3
H
N
S



LA1948
RB4
H
N
S



LA1949
RB7
H
N
S



LA1950
RB10
H
N
S



LA1951
RA3
H
N
S



LA1952
RA34
H
N
S



LA1953
H
H
N
O



LA1954
RB1
H
N
O



LA1955
RB3
H
N
O



LA1956
RB4
H
N
O



LA1957
RB7
H
N
O



LA1958
RB10
H
N
O



LA1959
RA3
H
N
O



LA1960
RA34
H
N
O



LA1961
H
H
N
NCH3



LA1962
RB1
H
N
NCH3



LA1963
RB3
H
N
NCH3



LA1964
RB4
H
N
NCH3



LA1965
RB7
H
N
NCH3



LA1966
RB10
H
N
NCH3



LA1967
RA3
H
N
NCH3



LA1968
RA34
H
N
NCH3



LA1969
H
H
N
C(CH3)2



LA1970
RB1
H
N
C(CH3)2



LA1971
RB3
H
N
C(CH3)2



LA1972
RB4
H
N
C(CH3)2



LA1973
RB7
H
N
C(CH3)2



LA1974
RB10
H
N
C(CH3)2



LA1975
RA3
H
N
C(CH3)2



LA1976
RA34
H
N
C(CH3)2



LA1977
H
H
N
Si(CH3)2



LA1978
RB1
H
N
Si(CH3)2



LA1979
RB3
H
N
Si(CH3)2



LA1980
RB4
H
N
Si(CH3)2



LA1981
RB7
H
N
Si(CH3)2



LA1982
RB10
H
N
Si(CH3)2



LA1983
RA3
H
N
Si(CH3)2



LA1984
RA34
H
N
Si(CH3)2



LA1985
H
RB1
N
S



LA1986
RB1
RB1
N
S



LA1987
RB3
RB1
N
S



LA1988
RB4
RB1
N
S



LA1989
RB7
RB1
N
S



LA1990
RB10
RB1
N
S



LA1991
RA3
RB1
N
S



LA1992
RA34
RB1
N
S



LA1993
H
RB1
N
O



LA1994
RB1
RB1
N
O



LA1995
RB3
RB1
N
O



LA1996
RB4
RB1
N
O



LA1997
RB7
RB1
N
O



LA1998
RB10
RB1
N
O



LA1999
RA3
RB1
N
O



LA2000
RA34
RB1
N
O



LA2001
H
RB1
N
NCH3



LA2002
RB1
RB1
N
NCH3



LA2003
RB3
RB1
N
NCH3



LA2004
RB4
RB1
N
NCH3



LA2005
RB7
RB1
N
NCH3



LA2006
RB10
RB1
N
NCH3



LA2007
RA3
RB1
N
NCH3



LA2008
RA34
RB1
N
NCH3



LA2009
H
RB1
N
C(CH3)2



LA2010
RB1
RB1
N
C(CH3)2



LA2011
RB3
RB1
N
C(CH3)2



LA2012
RB4
RB1
N
C(CH3)2



LA2013
RB7
RB1
N
C(CH3)2



LA2014
RB10
RB1
N
C(CH3)2



LA2015
RA3
RB1
N
C(CH3)2



LA2016
RA34
RB1
N
C(CH3)2



LA2017
H
RB1
N
Si(CH3)2



LA2018
RB1
RB1
N
Si(CH3)2



LA2019
RB3
RB1
N
Si(CH3)2



LA2020
RB4
RB1
N
Si(CH3)2



LA2021
RB7
RB1
N
Si(CH3)2



LA2022
RB10
RB1
N
Si(CH3)2



LA2023
RA3
RB1
N
Si(CH3)2



LA2024
RA34
RB1
N
Si(CH3)2



LA2025
H
RB6
N
S



LA2026
RB1
RB6
N
S



LA2027
RB3
RB6
N
S



LA2028
RB4
RB6
N
S



LA2029
RB7
RB6
N
S



LA2030
RB10
RB6
N
S



LA2031
RA3
RB6
N
S



LA2032
RA34
RB6
N
S



LA2033
H
RB6
N
O



LA2034
RB1
RB6
N
O



LA2035
RB3
RB6
N
O



LA2036
RB4
RB6
N
O



LA2037
RB7
RB6
N
O



LA2038
RB10
RB6
N
O



LA2039
RA3
RB6
N
O



LA2040
RA34
RB6
N
O



LA2041
H
RB6
N
NCH3



LA2042
RB1
RB6
N
NCH3



LA2043
RB3
RB6
N
NCH3



LA2044
RB4
RB6
N
NCH3



LA2045
RB7
RB6
N
NCH3



LA2046
RB10
RB6
N
NCH3



LA2047
RA3
RB6
N
NCH3



LA2048
RA34
RB6
N
NCH3



LA2049
H
RB6
N
C(CH3)2



LA2050
RB1
RB6
N
C(CH3)2



LA2051
RB3
RB6
N
C(CH3)2



LA2052
RB4
RB6
N
C(CH3)2



LA2053
RB7
RB6
N
C(CH3)2



LA2054
RB10
RB6
N
C(CH3)2



LA2055
RA3
RB6
N
C(CH3)2



LA2056
RA34
RB6
N
C(CH3)2



LA2057
H
RB6
N
Si(CH3)2



LA2058
RB1
RB6
N
Si(CH3)2



LA2059
RB3
RB6
N
Si(CH3)2



LA2060
RB4
RB6
N
Si(CH3)2



LA2061
RB7
RB6
N
Si(CH3)2



LA2062
RB10
RB6
N
Si(CH3)2



LA2063
RA3
RB6
N
Si(CH3)2



LA2064
RA34
RB6
N
Si(CH3)2










wherein LA2065 through LA2184 have a structure of Formula XV:





wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
R14







LA2065
H
H
S
LA2125
RB1
RB4
NCH3


LA2066
H
RB1
S
LA2126
RB1
RB5
NCH3


LA2067
H
RB2
S
LA2127
RB1
RA34
NCH3


LA2068
H
RB3
S
LA2128
RB1
RA52
NCH3


LA2069
H
RB4
S
LA2129
RB1
H
C(CH3)2


LA2070
H
RB5
S
LA2130
RB1
RB1
C(CH3)2


LA2071
H
RA34
S
LA2131
RB1
RB2
C(CH3)2


LA2072
H
RA52
S
LA2132
RB1
RB3
C(CH3)2


LA2073
H
H
O
LA2133
RB1
RB4
C(CH3)2


LA2074
H
RB1
O
LA2134
RB1
RB5
C(CH3)2


LA2075
H
RB2
O
LA2135
RB1
RA34
C(CH3)2


LA2076
H
RB3
O
LA2136
RB1
RA52
C(CH3)2


LA2077
H
RB4
O
LA2137
RB1
H
Si(CH3)2


LA2078
H
RB5
O
LA2138
RB1
RB1
Si(CH3)2


LA2079
H
RA34
O
LA2139
RB1
RB2
Si(CH3)2


LA2080
H
RA52
O
LA2140
RB1
RB3
Si(CH3)2


LA2081
H
H
NCH3
LA2141
RB1
RB4
Si(CH3)2


LA2082
H
RB1
NCH3
LA2142
RB1
RB5
Si(CH3)2


LA2083
H
RB2
NCH3
LA2143
RB1
RA34
Si(CH3)2


LA2084
H
RB3
NCH3
LA2144
RB1
RA52
Si(CH3)2


LA2085
H
RB4
NCH3
LA2145
RB6
H
S


LA2086
H
RB5
NCH3
LA2146
RB6
RB1
S


LA2087
H
RA34
NCH3
LA2147
RB6
RB2
S


LA2088
H
RA52
NCH3
LA2148
RB6
RB3
S


LA2089
H
H
C(CH3)2
LA2149
RB6
RB4
S


LA2090
H
RB1
C(CH3)2
LA2150
RB6
RB5
S


LA2091
H
RB2
C(CH3)2
LA2151
RB6
RA34
S


LA2092
H
RB3
C(CH3)2
LA2152
RB6
RA52
S


LA2093
H
RB4
C(CH3)2
LA2153
RB6
H
O


LA2094
H
RB5
C(CH3)2
LA2154
RB6
RB1
O


LA2095
H
RA34
C(CH3)2
LA2155
RB6
RB2
O


LA2096
H
RA52
C(CH3)2
LA2156
RB6
RB3
O


LA2097
H
H
Si(CH3)2
LA2157
RB6
RB4
O


LA2098
H
RB1
Si(CH3)2
LA2158
RB6
RB5
O


LA2099
H
RB2
Si(CH3)2
LA2159
RB6
RA34
O


LA2100
H
RB3
Si(CH3)2
LA2160
RB6
RA52
O


LA2101
H
RB4
Si(CH3)2
LA2161
RB6
H
NCH3


LA2102
H
RB5
Si(CH3)2
LA2162
RB6
RB1
NCH3


LA2103
H
RA34
Si(CH3)2
LA2163
RB6
RB2
NCH3


LA2104
H
RA52
Si(CH3)2
LA2164
RB6
RB3
NCH3


LA2105
RB1
H
S
LA2165
RB6
RB4
NCH3


LA2106
RB1
RB1
S
LA2166
RB6
RB5
NCH3


LA2107
RB1
RB2
S
LA2167
RB6
RA34
NCH3


LA2108
RB1
RB3
S
LA2168
RB6
RA52
NCH3


LA2109
RB1
RB4
S
LA2169
RB6
H
C(CH3)2


LA2110
RB1
RB5
S
LA2170
RB6
RB1
C(CH3)2


LA2111
RB1
RA34
S
LA2171
RB6
RB2
C(CH3)2


LA2112
RB1
RA52
S
LA2172
RB6
RB3
C(CH3)2


LA2113
RB1
H
O
LA2173
RB6
RB4
C(CH3)2


LA2114
RB1
RB1
O
LA2174
RB6
RB5
C(CH3)2


LA2115
RB1
RB2
O
LA2175
RB6
RA34
C(CH3)2


LA2116
RB1
RB3
O
LA2176
RB6
RA52
C(CH3)2


LA2117
RB1
RB4
O
LA2177
RB6
H
Si(CH3)2


LA2118
RB1
RB5
O
LA2178
RB6
RB1
Si(CH3)2


LA2119
RB1
RA34
O
LA2179
RB6
RB2
Si(CH3)2


LA2120
RB1
RA52
O
LA2180
RB6
RB3
Si(CH3)2


LA2121
RB1
H
NCH3
LA2181
RB6
RB4
Si(CH3)2


LA2122
RB1
RB1
NCH3
LA2182
RB6
RB5
Si(CH3)2


LA2123
RB1
RB2
NCH3
LA2183
RB6
RA34
Si(CH3)2


LA2124
RB1
RB3
NCH3
LA2184
RB6
RA52
Si(CH3)2









wherein LA2185 through LA2280 have a structure of Formula XVI:





wherein R4, R5, Y, and Z are defined as provided below:


















Ligand
R5
R4
Y
Z









LA2185
H
H
S
S



LA2186
H
RB1
S
S



LA2187
H
RB3
S
S



LA2188
H
RB4
S
S



LA2189
H
RB7
S
S



LA2190
H
RB10
S
S



LA2191
H
RA3
S
S



LA2192
H
RA34
S
S



LA2193
H
H
S
O



LA2194
H
RB1
S
O



LA2195
H
RB3
S
O



LA2196
H
RB4
S
O



LA2197
H
RB7
S
O



LA2198
H
RB10
S
O



LA2199
H
RA3
S
O



LA2200
H
RA34
S
O



LA2201
H
H
S
NCH3



LA2202
H
RB1
S
NCH3



LA2203
H
RB3
S
NCH3



LA2204
H
RB4
S
NCH3



LA2205
H
RB7
S
NCH3



LA2206
H
RB10
S
NCH3



LA2207
H
RA3
S
NCH3



LA2208
H
RA34
S
NCH3



LA2209
H
H
O
S



LA2210
H
RB1
O
S



LA2211
H
RB3
O
S



LA2212
H
RB4
O
S



LA2213
H
RB7
O
S



LA2214
H
RB10
O
S



LA2215
H
RA3
O
S



LA2216
H
RA34
O
S



LA2217
H
H
O
O



LA2218
H
RB1
O
O



LA2219
H
RB3
O
O



LA2220
H
RB4
O
O



LA2221
H
RB7
O
O



LA2222
H
RB10
O
O



LA2223
H
RA3
O
O



LA2224
H
RA34
O
O



LA2225
H
H
O
NCH3



LA2226
H
RB1
O
NCH3



LA2227
H
RB3
O
NCH3



LA2228
H
RB4
O
NCH3



LA2229
H
RB7
O
NCH3



LA2230
H
RB10
O
NCH3



LA2231
H
RA3
O
NCH3



LA2232
H
RA34
O
NCH3



LA2233
RB6
H
S
S



LA2234
RB6
RB1
S
S



LA2235
RB6
RB3
S
S



LA2236
RB6
RB4
S
S



LA2237
RB6
RB7
S
S



LA2238
RB6
RB10
S
S



LA2239
RB6
RA3
S
S



LA2240
RB6
RA34
S
S



LA2241
RB6
H
S
O



LA2242
RB6
RB1
S
O



LA2243
RB6
RB3
S
O



LA2244
RB6
RB4
S
O



LA2245
RB6
RB7
S
O



LA2246
RB6
RB10
S
O



LA2247
RB6
RA3
S
O



LA2248
RB6
RA34
S
O



LA2249
RB6
H
S
NCH3



LA2250
RB6
RB1
S
NCH3



LA2251
RB6
RB3
S
NCH3



LA2252
RB6
RB4
S
NCH3



LA2253
RB6
RB7
S
NCH3



LA2254
RB6
RB10
S
NCH3



LA2255
RB6
RA3
S
NCH3



LA2256
RB6
RA34
S
NCH3



LA2257
RB6
H
O
S



LA2258
RB6
RB1
O
S



LA2259
RB6
RB3
O
S



LA2260
RB6
RB4
O
S



LA2261
RB6
RB7
O
S



LA2262
RB6
RB10
O
S



LA2263
RB6
RA3
O
S



LA2264
RB6
RA34
O
S



LA2265
RB6
H
O
O



LA2266
RB6
RB1
O
O



LA2267
RB6
RB3
O
O



LA2268
RB6
RB4
O
O



LA2269
RB6
RB7
O
O



LA2270
RB6
RB10
O
O



LA2271
RB6
RA3
O
O



LA2272
RB6
RA34
O
O



LA2273
RB6
H
O
NCH3



LA2274
RB6
RB1
O
NCH3



LA2275
RB6
RB3
O
NCH3



LA2276
RB6
RB4
O
NCH3



LA2277
RB6
RB7
O
NCH3



LA2278
RB6
RB10
O
NCH3



LA2279
RB6
RA3
O
NCH3



LA2280
RB6
RA34
O
NCH3










wherein LA2281 through LA2520 have a structure of Formula XVII:





wherein R1, R5, X, and Y are defined as provided below:


















Ligand
R1
R5
X
Y









LA2281
H
H
C
S



LA2282
RB1
H
C
S



LA2283
RB3
H
C
S



LA2284
RB4
H
C
S



LA2285
RB7
H
C
S



LA2286
RB10
H
C
S



LA2287
RA3
H
C
S



LA2288
RA34
H
C
S



LA2289
H
H
C
O



LA2290
RB1
H
C
O



LA2291
RB3
H
C
O



LA2292
RB4
H
C
O



LA2293
RB7
H
C
O



LA2294
RB10
H
C
O



LA2295
RA3
H
C
O



LA2296
RA34
H
C
O



LA2297
H
H
C
NCH3



LA2298
RB1
H
C
NCH3



LA2299
RB3
H
C
NCH3



LA2300
RB4
H
C
NCH3



LA2301
RB7
H
C
NCH3



LA2302
RB10
H
C
NCH3



LA2303
RA3
H
C
NCH3



LA2304
RA34
H
C
NCH3



LA2305
H
H
C
C(CH3)2



LA2306
RB1
H
C
C(CH3)2



LA2307
RB3
H
C
C(CH3)2



LA2308
RB4
H
C
C(CH3)2



LA2309
RB7
H
C
C(CH3)2



LA2310
RB10
H
C
C(CH3)2



LA2311
RA3
H
C
C(CH3)2



LA2312
RA34
H
C
C(CH3)2



LA2313
H
H
C
Si(CH3)2



LA2314
RB1
H
C
Si(CH3)2



LA2315
RB3
H
C
Si(CH3)2



LA2316
RB4
H
C
Si(CH3)2



LA2317
RB7
H
C
Si(CH3)2



LA2318
RB10
H
C
Si(CH3)2



LA2319
RA3
H
C
Si(CH3)2



LA2320
RA34
H
C
Si(CH3)2



LA2321
H
RB1
C
S



LA2322
RB1
RB1
C
S



LA2323
RB3
RB1
C
S



LA2324
RB4
RB1
C
S



LA2325
RB7
RB1
C
S



LA2326
RB10
RB1
C
S



LA2327
RA3
RB1
C
S



LA2328
RA34
RB1
C
S



LA2329
H
RB1
C
O



LA2330
RB1
RB1
C
O



LA2331
RB3
RB1
C
O



LA2332
RB4
RB1
C
O



LA2333
RB7
RB1
C
O



LA2334
RB10
RB1
C
O



LA2335
RA3
RB1
C
O



LA2336
RA34
RB1
C
O



LA2337
H
RB1
C
NCH3



LA2338
RB1
RB1
C
NCH3



LA2339
RB3
RB1
C
NCH3



LA2340
RB4
RB1
C
NCH3



LA2341
RB7
RB1
C
NCH3



LA2342
RB10
RB1
C
NCH3



LA2343
RA3
RB1
C
NCH3



LA2344
RA34
RB1
C
NCH3



LA2345
H
RB1
C
C(CH3)2



LA2346
RB1
RB1
C
C(CH3)2



LA2347
RB3
RB1
C
C(CH3)2



LA2348
RB4
RB1
C
C(CH3)2



LA2349
RB7
RB1
C
C(CH3)2



LA2350
RB10
RB1
C
C(CH3)2



LA2351
RA3
RB1
C
C(CH3)2



LA2352
RA34
RB1
C
C(CH3)2



LA2353
H
RB1
C
Si(CH3)2



LA2354
RB1
RB1
C
Si(CH3)2



LA2355
RB3
RB1
C
Si(CH3)2



LA2356
RB4
RB1
C
Si(CH3)2



LA2357
RB7
RB1
C
Si(CH3)2



LA2358
RB10
RB1
C
Si(CH3)2



LA2359
RA3
RB1
C
Si(CH3)2



LA2360
RA34
RB1
C
Si(CH3)2



LA2361
H
RB6
C
S



LA2362
RB1
RB6
C
S



LA2363
RB3
RB6
C
S



LA2364
RB4
RB6
C
S



LA2365
RB7
RB6
C
S



LA2366
RB10
RB6
C
S



LA2367
RA3
RB6
C
S



LA2368
RA34
RB6
C
S



LA2369
H
RB6
C
O



LA2370
RB1
RB6
C
O



LA2371
RB3
RB6
C
O



LA2372
RB4
RB6
C
O



LA2373
RB7
RB6
C
O



LA2374
RB10
RB6
C
O



LA2375
RA3
RB6
C
O



LA2376
RA34
RB6
C
O



LA2377
H
RB6
C
NCH3



LA2378
RB1
RB6
C
NCH3



LA2379
RB3
RB6
C
NCH3



LA2380
RB4
RB6
C
NCH3



LA2381
RB7
RB6
C
NCH3



LA2382
RB10
RB6
C
NCH3



LA2383
RA3
RB6
C
NCH3



LA2384
RA34
RB6
C
NCH3



LA2385
H
RB6
C
C(CH3)2



LA2386
RB1
RB6
C
C(CH3)2



LA2387
RB3
RB6
C
C(CH3)2



LA2388
RB4
RB6
C
C(CH3)2



LA2389
RB7
RB6
C
C(CH3)2



LA2390
RB10
RB6
C
C(CH3)2



LA2391
RA3
RB6
C
C(CH3)2



LA2392
RA34
RB6
C
C(CH3)2



LA2393
H
RB6
C
Si(CH3)2



LA2394
RB1
RB6
C
Si(CH3)2



LA2395
RB3
RB6
C
Si(CH3)2



LA2396
RB4
RB6
C
Si(CH3)2



LA2397
RB7
RB6
C
Si(CH3)2



LA2398
RB10
RB6
C
Si(CH3)2



LA2399
RA3
RB6
C
Si(CH3)2



LA2400
RA34
RB6
C
Si(CH3)2



LA2401
H
H
N
S



LA2402
RB1
H
N
S



LA2403
RB3
H
N
S



LA2404
RB4
H
N
S



LA2405
RB7
H
N
S



LA2406
RB10
H
N
S



LA2407
RA3
H
N
S



LA2408
RA34
H
N
S



LA2409
H
H
N
O



LA2410
RB1
H
N
O



LA2411
RB3
H
N
O



LA2412
RB4
H
N
O



LA2413
RB7
H
N
O



LA2414
RB10
H
N
O



LA2415
RA3
H
N
O



LA2416
RA34
H
N
O



LA2417
H
H
N
NCH3



LA2418
RB1
H
N
NCH3



LA2419
RB3
H
N
NCH3



LA2420
RB4
H
N
NCH3



LA2421
RB7
H
N
NCH3



LA2422
RB10
H
N
NCH3



LA2423
RA3
H
N
NCH3



LA2424
RA34
H
N
NCH3



LA2425
H
H
N
C(CH3)2



LA2426
RB1
H
N
C(CH3)2



LA2427
RB3
H
N
C(CH3)2



LA2428
RB4
H
N
C(CH3)2



LA2429
RB7
H
N
C(CH3)2



LA2430
RB10
H
N
C(CH3)2



LA2431
RA3
H
N
C(CH3)2



LA2432
RA34
H
N
C(CH3)2



LA2433
H
H
N
Si(CH3)2



LA2434
RB1
H
N
Si(CH3)2



LA2435
RB3
H
N
Si(CH3)2



LA2436
RB4
H
N
Si(CH3)2



LA2437
RB7
H
N
Si(CH3)2



LA2438
RB10
H
N
Si(CH3)2



LA2439
RA3
H
N
Si(CH3)2



LA2440
RA34
H
N
Si(CH3)2



LA2441
H
RB1
N
S



LA2442
RB1
RB1
N
S



LA2443
RB3
RB1
N
S



LA2444
RB4
RB1
N
S



LA2445
RB7
RB1
N
S



LA2446
RB10
RB1
N
S



LA2447
RA3
RB1
N
S



LA2448
RA34
RB1
N
S



LA2449
H
RB1
N
O



LA2450
RB1
RB1
N
O



LA2451
RB3
RB1
N
O



LA2452
RB4
RB1
N
O



LA2453
RB7
RB1
N
O



LA2454
RB10
RB1
N
O



LA2455
RA3
RB1
N
O



LA2456
RA34
RB1
N
O



LA2457
H
RB1
N
NCH3



LA2458
RB1
RB1
N
NCH3



LA2459
RB3
RB1
N
NCH3



LA2460
RB4
RB1
N
NCH3



LA2461
RB7
RB1
N
NCH3



LA2462
RB10
RB1
N
NCH3



LA2463
RA3
RB1
N
NCH3



LA2464
RA34
RB1
N
NCH3



LA2465
H
RB1
N
C(CH3)2



LA2466
RB1
RB1
N
C(CH3)2



LA2467
RB3
RB1
N
C(CH3)2



LA2468
RB4
RB1
N
C(CH3)2



LA2469
RB7
RB1
N
C(CH3)2



LA2470
RB10
RB1
N
C(CH3)2



LA2471
RA3
RB1
N
C(CH3)2



LA2472
RA34
RB1
N
C(CH3)2



LA2473
H
RB1
N
Si(CH3)2



LA2474
RB1
RB1
N
Si(CH3)2



LA2475
RB3
RB1
N
Si(CH3)2



LA2476
RB4
RB1
N
Si(CH3)2



LA2477
RB7
RB1
N
Si(CH3)2



LA2478
RB10
RB1
N
Si(CH3)2



LA2479
RA3
RB1
N
Si(CH3)2



LA2480
RA34
RB1
N
Si(CH3)2



LA2481
H
RB6
N
S



LA2482
RB1
RB6
N
S



LA2483
RB3
RB6
N
S



LA2484
RB4
RB6
N
S



LA2485
RB7
RB6
N
S



LA2486
RB10
RB6
N
S



LA2487
RA3
RB6
N
S



LA2488
RA34
RB6
N
S



LA2489
H
RB6
N
O



LA2490
RB1
RB6
N
O



LA2491
RB3
RB6
N
O



LA2492
RB4
RB6
N
O



LA2493
RB7
RB6
N
O



LA2494
RB10
RB6
N
O



LA2495
RA3
RB6
N
O



LA2496
RA34
RB6
N
O



LA2497
H
RB6
N
NCH3



LA2498
RB1
RB6
N
NCH3



LA2499
RB3
RB6
N
NCH3



LA2500
RB4
RB6
N
NCH3



LA2501
RB7
RB6
N
NCH3



LA2502
RB10
RB6
N
NCH3



LA2503
RA3
RB6
N
NCH3



LA2504
RA34
RB6
N
NCH3



LA2505
H
RB6
N
C(CH3)2



LA2506
RB1
RB6
N
C(CH3)2



LA2507
RB3
RB6
N
C(CH3)2



LA2508
RB4
RB6
N
C(CH3)2



LA2509
RB7
RB6
N
C(CH3)2



LA2510
RB10
RB6
N
C(CH3)2



LA2511
RA3
RB6
N
C(CH3)2



LA2512
RA34
RB6
N
C(CH3)2



LA2513
H
RB6
N
Si(CH3)2



LA2514
RB1
RB6
N
Si(CH3)2



LA2515
RB3
RB6
N
Si(CH3)2



LA2516
RB4
RB6
N
Si(CH3)2



LA2517
RB7
RB6
N
Si(CH3)2



LA2518
RB10
RB6
N
Si(CH3)2



LA2519
RA3
RB6
N
Si(CH3)2



LA2520
RA34
RB6
N
Si(CH3)2










wherein LA2521 through LA2640 have a structure of Formula XVIII:





wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA2521
H
H
S
LA2581
RB1
RB4
NCH3


LA2522
H
RB1
S
LA2582
RB1
RB5
NCH3


LA2523
H
RB2
S
LA2583
RB1
RA34
NCH3


LA2524
H
RB3
S
LA2584
RB1
RA52
NCH3


LA2525
H
RB4
S
LA2585
RB1
H
C(CH3)2


LA2526
H
RB5
S
LA2586
RB1
RB1
C(CH3)2


LA2527
H
RA34
S
LA2587
RB1
RB2
C(CH3)2


LA2528
H
RA52
S
LA2588
RB1
RB3
C(CH3)2


LA2529
H
H
O
LA2589
RB1
RB4
C(CH3)2


LA2530
H
RB1
O
LA2590
RB1
RB5
C(CH3)2


LA2531
H
RB2
O
LA2591
RB1
RA34
C(CH3)2


LA2532
H
RB3
O
LA2592
RB1
RA52
C(CH3)2


LA2533
H
RB4
O
LA2593
RB1
H
Si(CH3)2


LA2534
H
RB5
O
LA2594
RB1
RB1
Si(CH3)2


LA2535
H
RA34
O
LA2595
RB1
RB2
Si(CH3)2


LA2536
H
RA52
O
LA2596
RB1
RB3
Si(CH3)2


LA2537
H
H
NCH3
LA2597
RB1
RB4
Si(CH3)2


LA2538
H
RB1
NCH3
LA2598
RB1
RB5
Si(CH3)2


LA2539
H
RB2
NCH3
LA2599
RB1
RA34
Si(CH3)2


LA2540
H
RB3
NCH3
LA2600
RB1
RA52
Si(CH3)2


LA2541
H
RB4
NCH3
LA2601
RB6
H
S


LA2542
H
RB5
NCH3
LA2602
RB6
RB1
S


LA2543
H
RA34
NCH3
LA2603
RB6
RB2
S


LA2544
H
RA52
NCH3
LA2604
RB6
RB3
S


LA2545
H
H
C(CH3)2
LA2605
RB6
RB4
S


LA2546
H
RB1
C(CH3)2
LA2606
RB6
RB5
S


LA2547
H
RB2
C(CH3)2
LA2607
RB6
RA34
S


LA2548
H
RB3
C(CH3)2
LA2608
RB6
RA52
S


LA2549
H
RB4
C(CH3)2
LA2609
RB6
H
O


LA2550
H
RB5
C(CH3)2
LA2610
RB6
RB1
O


LA2551
H
RA34
C(CH3)2
LA2611
RB6
RB2
O


LA2552
H
RA52
C(CH3)2
LA2612
RB6
RB3
O


LA2553
H
H
Si(CH3)2
LA2613
RB6
RB4
O


LA2554
H
RB1
Si(CH3)2
LA2614
RB6
RB5
O


LA2555
H
RB2
Si(CH3)2
LA2615
RB6
RA34
O


LA2556
H
RB3
Si(CH3)2
LA2616
RB6
RA52
O


LA2557
H
RB4
Si(CH3)2
LA2617
RB6
H
NCH3


LA2558
H
RB5
Si(CH3)2
LA2618
RB6
RB1
NCH3


LA2559
H
RA34
Si(CH3)2
LA2619
RB6
RB2
NCH3


LA2560
H
RA52
Si(CH3)2
LA2620
RB6
RB3
NCH3


LA2561
RB1
H
S
LA2621
RB6
RB4
NCH3


LA2562
RB1
RB1
S
LA2622
RB6
RB5
NCH3


LA2563
RB1
RB2
S
LA2623
RB6
RA34
NCH3


LA2564
RB1
RB3
S
LA2624
RB6
RA52
NCH3


LA2565
RB1
RB4
S
LA2625
RB6
H
C(CH3)2


LA2566
RB1
RB5
S
LA2626
RB6
RB1
C(CH3)2


LA2567
RB1
RA34
S
LA2627
RB6
RB2
C(CH3)2


LA2568
RB1
RA52
S
LA2628
RB6
RB3
C(CH3)2


LA2569
RB1
H
O
LA2629
RB6
RB4
C(CH3)2


LA2570
RB1
RB1
O
LA2630
RB6
RB5
C(CH3)2


LA2571
RB1
RB2
O
LA2631
RB6
RA34
C(CH3)2


LA2572
RB1
RB3
O
LA2632
RB6
RA52
C(CH3)2


LA2573
RB1
RB4
O
LA2633
RB6
H
Si(CH3)2


LA2574
RB1
RB5
O
LA2634
RB6
RB1
Si(CH3)2


LA2575
RB1
RA34
O
LA2635
RB6
RB2
Si(CH3)2


LA2576
RB1
RA52
O
LA2636
RB6
RB3
Si(CH3)2


LA2577
RB1
H
NCH3
LA2637
RB6
RB4
Si(CH3)2


LA2578
RB1
RB1
NCH3
LA2638
RB6
RB5
Si(CH3)2


LA2579
RB1
RB2
NCH3
LA2639
RB6
RA34
Si(CH3)2


LA2580
RB1
RB3
NCH3
LA2640
RB6
RA52
Si(CH3)2









wherein LA2641 through LA2736 have a structure of Formula XIX:





wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA2641
H
H
S
S
LA2689
RB6
H
S
S


LA2642
H
RB1
S
S
LA2690
RB6
RB1
S
S


LA2643
H
RB3
S
S
LA2691
RB6
RB3
S
S


LA2644
H
RB4
S
S
LA2692
RB6
RB4
S
S


LA2645
H
RB7
S
S
LA2693
RB6
RB7
S
S


LA2646
H
RB10
S
S
LA2694
RB6
RB10
S
S


LA2647
H
RA3
S
S
LA2695
RB6
RA3
S
S


LA2648
H
RA34
S
S
LA2696
RB6
RA34
S
S


LA2649
H
H
S
O
LA2697
RB6
H
S
O


LA2650
H
RB1
S
O
LA2698
RB6
RB1
S
O


LA2651
H
RB3
S
O
LA2699
RB6
RB3
S
O


LA2652
H
RB4
S
O
LA2700
RB6
RB4
S
O


LA2653
H
RB7
S
O
LA2701
RB6
RB7
S
O


LA2654
H
RB10
S
O
LA2702
RB6
RB10
S
O


LA2655
H
RA3
S
O
LA2703
RB6
RA3
S
O


LA2656
H
RA34
S
O
LA2704
RB6
RA34
S
O


LA2657
H
H
S
NCH3
LA2705
RB6
H
S
NCH3


LA2658
H
RB1
S
NCH3
LA2706
RB6
RB1
S
NCH3


LA2659
H
RB3
S
NCH3
LA2707
RB6
RB3
S
NCH3


LA2660
H
RB4
S
NCH3
LA2708
RB6
RB4
S
NCH3


LA2661
H
RB7
S
NCH3
LA2709
RB6
RB7
S
NCH3


LA2662
H
RB10
S
NCH3
LA2710
RB6
RB10
S
NCH3


LA2663
H
RA3
S
NCH3
LA2711
RB6
RA3
S
NCH3


LA2664
H
RA34
S
NCH3
LA2712
RB6
RA34
S
NCH3


LA2665
H
H
O
S
LA2713
RB6
H
O
S


LA2666
H
RB1
O
S
LA2714
RB6
RB1
O
S


LA2667
H
RB3
O
S
LA2715
RB6
RB3
O
S


LA2668
H
RB4
O
S
LA2716
RB6
RB4
O
S


LA2669
H
RB7
O
S
LA2717
RB6
RB7
O
S


LA2670
H
RB10
O
S
LA2718
RB6
RB10
O
S


LA2671
H
RA3
O
S
LA2719
RB6
RA3
O
S


LA2672
H
RA34
O
S
LA2720
RB6
RA34
O
S


LA2673
H
H
O
O
LA2721
RB6
H
O
O


LA2674
H
RB1
O
O
LA2722
RB6
RB1
O
O


LA2675
H
RB3
O
O
LA2723
RB6
RB3
O
O


LA2676
H
RB4
O
O
LA2724
RB6
RB4
O
O


LA2677
H
RB7
O
O
LA2725
RB6
RB7
O
O


LA2678
H
RB10
O
O
LA2726
RB6
RB10
O
O


LA2679
H
RA3
O
O
LA2727
RB6
RA3
O
O


LA2680
H
RA34
O
O
LA2728
RB6
RA34
O
O


LA2681
H
H
O
NCH3
LA2729
RB6
H
O
NCH3


LA2682
H
RB1
O
NCH3
LA2730
RB6
RB1
O
NCH3


LA2683
H
RB3
O
NCH3
LA2731
RB6
RB3
O
NCH3


LA2684
H
RB4
O
NCH3
LA2732
RB6
RB4
O
NCH3


LA2685
H
RB7
O
NCH3
LA2733
RB6
RB7
O
NCH3


LA2686
H
RB10
O
NCH3
LA2734
RB6
RB10
O
NCH3


LA2687
H
RA3
O
NCH3
LA2735
RB6
RA3
O
NCH3


LA2688
H
RA34
O
NCH3
LA2736
RB6
RA34
O
NCH3









wherein LA2737 through LA2976 have a structure of Formula XX:





wherein R1, R5, Y, and X are defined as provided below:




















Ligand
R1
R5
X
Y
Ligand
R1
R5
X
Y







LA2737
H
H
C
S
LA2857
H
H
N
S


LA2738
RB1
H
C
S
LA2858
RB1
H
N
S


LA2739
RB3
H
C
S
LA2859
RB3
H
N
S


LA2740
RB4
H
C
S
LA2860
RB4
H
N
S


LA2741
RB7
H
C
S
LA2861
RB7
H
N
S


LA2742
RB10
H
C
S
LA2862
RB10
H
N
S


LA2743
RA3
H
C
S
LA2863
RA3
H
N
S


LA2744
RA34
H
C
S
LA2864
RA34
H
N
S


LA2745
H
H
C
O
LA2865
H
H
N
O


LA2746
RB1
H
C
O
LA2866
RB1
H
N
O


LA2747
RB3
H
C
O
LA2867
RB3
H
N
O


LA2748
RB4
H
C
O
LA2868
RB4
H
N
O


LA2749
RB7
H
C
O
LA2869
RB7
H
N
O


LA2750
RB10
H
C
O
LA2870
RB10
H
N
O


LA2751
RA3
H
C
O
LA2871
RA3
H
N
O


LA2752
RA34
H
C
O
LA2872
RA34
H
N
O


LA2753
H
H
C
NCH3
LA2873
H
H
N
NCH3


LA2754
RB1
H
C
NCH3
LA2874
RB1
H
N
NCH3


LA2755
RB3
H
C
NCH3
LA2875
RB3
H
N
NCH3


LA2756
RB4
H
C
NCH3
LA2876
RB4
H
N
NCH3


LA2757
RB7
H
C
NCH3
LA2877
RB7
H
N
NCH3


LA2758
RB10
H
C
NCH3
LA2878
RB10
H
N
NCH3


LA2759
RA3
H
C
NCH3
LA2879
RA3
H
N
NCH3


LA2760
RA34
H
C
NCH3
LA2880
RA34
H
N
NCH3


LA2761
H
H
C
C(CH3)2
LA2881
H
H
N
C(CH3)2


LA2762
RB1
H
C
C(CH3)2
LA2882
RB1
H
N
C(CH3)2


LA2763
RB3
H
C
C(CH3)2
LA2883
RB3
H
N
C(CH3)2


LA2764
RB4
H
C
C(CH3)2
LA2884
RB4
H
N
C(CH3)2


LA2765
RB7
H
C
C(CH3)2
LA2885
RB7
H
N
C(CH3)2


LA2766
RB10
H
C
C(CH3)2
LA2886
RB10
H
N
C(CH3)2


LA2767
RA3
H
C
C(CH3)2
LA2887
RA3
H
N
C(CH3)2


LA2768
RA34
H
C
C(CH3)2
LA2888
RA34
H
N
C(CH3)2


LA2769
H
H
C
Si(CH3)2 
LA2889
H
H
N
Si(CH3)2


LA2770
RB1
H
C
Si(CH3)2 
LA2890
RB1
H
N
Si(CH3)2


LA2771
RB3
H
C
Si(CH3)2 
LA2891
RB3
H
N
Si(CH3)2


LA2772
RB4
H
C
Si(CH3)2
LA2892
RB4
H
N
Si(CH3)2


LA2773
RB7
H
C
Si(CH3)2 
LA2893
RB7
H
N
Si(CH3)2


LA2774
RB10
H
C
Si(CH3)2 
LA2894
RB10
H
N
Si(CH3)2


LA2775
RA3
H
C
Si(CH3)2 
LA2895
RA3
H
N
Si(CH3)2


LA2776
RA34
H
C
Si(CH3)2 
LA2896
RA34
H
N
Si(CH3)2


LA2777
H
RB1
C
S
LA2897
H
RB1
N
S


LA2778
RB1
RB1
C
S
LA2898
RB1
RB1
N
S


LA2779
RB3
RB1
C
S
LA2899
RB3
RB1
N
S


LA2780
RB4
RB1
C
S
LA2900
RB4
RB1
N
S


LA2781
RB7
RB1
C
S
LA2901
RB7
RB1
N
S


LA2782
RB10
RB1
C
S
LA2902
RB10
RB1
N
S


LA2783
RA3
RB1
C
S
LA2903
RA3
RB1
N
S


LA2784
RA34
RB1
C
S
LA2904
RA34
RB1
N
S


LA2785
H
RB1
C
O
LA2905
H
RB1
N
O


LA2786
RB1
RB1
C
O
LA2906
RB1
RB1
N
O


LA2787
RB3
RB1
C
O
LA2907
RB3
RB1
N
O


LA2788
RB4
RB1
C
O
LA2908
RB4
RB1
N
O


LA2789
RB7
RB1
C
O
LA2909
RB7
RB1
N
O


LA2790
RB10
RB1
C
O
LA2910
RB10
RB1
N
O


LA2791
RA3
RB1
C
O
LA2911
RA3
RB1
N
O


LA2792
RA34
RB1
C
O
LA2912
RA34
RB1
N
O


LA2793
H
RB1
C
NCH3
LA2913
H
RB1
N
NCH3


LA2794
RB1
RB1
C
NCH3
LA2914
RB1
RB1
N
NCH3


LA2795
RB3
RB1
C
NCH3
LA2915
RB3
RB1
N
NCH3


LA2796
RB4
RB1
C
NCH3
LA2916
RB4
RB1
N
NCH3


LA2797
RB7
RB1
C
NCH3
LA2917
RB7
RB1
N
NCH3


LA2798
RB10
RB1
C
NCH3
LA2918
RB10
RB1
N
NCH3


LA2799
RA3
RB1
C
NCH3
LA2919
RA3
RB1
N
NCH3


LA2800
RA34
RB1
C
NCH3
LA2920
RA34
RB1
N
NCH3


LA2801
H
RB1
C
C(CH3)2
LA2921
H
RB1
N
C(CH3)2


LA2802
RB1
RB1
C
C(CH3)2
LA2922
RB1
RB1
N
C(CH3)2


LA2803
RB3
RB1
C
C(CH3)2
LA2923
RB3
RB1
N
C(CH3)2


LA2804
RB4
RB1
C
C(CH3)2
LA2924
RB4
RB1
N
C(CH3)2


LA2805
RB7
RB1
C
C(CH3)2
LA2925
RB7
RB1
N
C(CH3)2


LA2806
RB10
RB1
C
C(CH3)2
LA2926
RB10
RB1
N
C(CH3)2


LA2807
RA3
RB1
C
C(CH3)2
LA2927
RA3
RB1
N
C(CH3)2


LA2808
RA34
RB1
C
C(CH3)2
LA2928
RA34
RB1
N
C(CH3)2


LA2809
H
RB1
C
Si(CH3)2
LA2929
H
RB1
N
Si(CH3)2


LA2810
RB1
RB1
C
Si(CH3)2 
LA2930
RB1
RB1
N
Si(CH3)2


LA2811
RB3
RB1
C
Si(CH3)2
LA2931
RB3
RB1
N
Si(CH3)2


LA2812
RB4
RB1
C
Si(CH3)2 
LA2932
RB4
RB1
N
Si(CH3)2


LA2813
RB7
RB1
C
Si(CH3)2 
LA2933
RB7
RB1
N
Si(CH3)2


LA2814
RB10
RB1
C
Si(CH3)2
LA2934
RB10
RB1
N
Si(CH3)2


LA2815
RA3
RB1
C
Si(CH3)2 
LA2935
RA3
RB1
N
Si(CH3)2


LA2816
RA34
RB1
C
Si(CH3)2
LA2936
RA34
RB1
N
Si(CH3)2


LA2817
H
RB6
C
S
LA2937
H
RB6
N
S


LA2818
RB1
RB6
C
S
LA2938
RB1
RB6
N
S


LA2819
RB3
RB6
C
S
LA2939
RB3
RB6
N
S


LA2820
RB4
RB6
C
S
LA2940
RB4
RB6
N
S


LA2821
RB7
RB6
C
S
LA2941
RB7
RB6
N
S


LA2822
RB10
RB6
C
S
LA2942
RB10
RB6
N
S


LA2823
RA3
RB6
C
S
LA2943
RA3
RB6
N
S


LA2824
RA34
RB6
C
S
LA2944
RA34
RB6
N
S


LA2825
H
RB6
C
O
LA2945
H
RB6
N
O


LA2826
RB1
RB6
C
O
LA2946
RB1
RB6
N
O


LA2827
RB3
RB6
C
O
LA2947
RB3
RB6
N
O


LA2828
RB4
RB6
C
O
LA2948
RB4
RB6
N
O


LA2829
RB7
RB6
C
O
LA2949
RB7
RB6
N
O


LA2830
RB10
RB6
C
O
LA2950
RB10
RB6
N
O


LA2831
RA3
RB6
C
O
LA2951
RA3
RB6
N
O


LA2832
RA34
RB6
C
O
LA2952
RA34
RB6
N
O


LA2833
H
RB6
C
NCH3
LA2953
H
RB6
N
NCH3


LA2834
RB1
RB6
C
NCH3
LA2954
RB1
RB6
N
NCH3


LA2835
RB3
RB6
C
NCH3
LA2955
RB3
RB6
N
NCH3


LA2836
RB4
RB6
C
NCH3
LA2956
RB4
RB6
N
NCH3


LA2837
RB7
RB6
C
NCH3
LA2957
RB7
RB6
N
NCH3


LA2838
RB10
RB6
C
NCH3
LA2958
RB10
RB6
N
NCH3


LA2839
RA3
RB6
C
NCH3
LA2959
RA3
RB6
N
NCH3


LA2840
RA34
RB6
C
NCH3
LA2960
RA34
RB6
N
NCH3


LA2841
H
RB6
C
C(CH3)2
LA2961
H
RB6
N
C(CH3)2


LA2842
RB1
RB6
C
C(CH3)2
LA2962
RB1
RB6
N
C(CH3)2


LA2843
RB3
RB6
C
C(CH3)2
LA2963
RB3
RB6
N
C(CH3)2


LA2844
RB4
RB6
C
C(CH3)2
LA2964
RB4
RB6
N
C(CH3)2


LA2845
RB7
RB6
C
C(CH3)2
LA2965
RB7
RB6
N
C(CH3)2


LA2846
RB10
RB6
C
C(CH3)2
LA2966
RB10
RB6
N
C(CH3)2


LA2847
RA3
RB6
C
C(CH3)2
LA2967
RA3
RB6
N
C(CH3)2


LA2848
RA34
RB6
C
C(CH3)2
LA2968
RA34
RB6
N
C(CH3)2


LA2849
H
RB6
C
Si(CH3)2
LA2969
H
RB6
N
Si(CH3)2


LA2850
RB1
RB6
C
Si(CH3)2
LA2970
RB1
RB6
N
Si(CH3)2


LA2851
RB3
RB6
C
Si(CH3)2
LA2971
RB3
RB6
N
Si(CH3)2


LA2852
RB4
RB6
C
Si(CH3)2
LA2972
RB4
RB6
N
Si(CH3)2


LA2853
RB7
RB6
C
Si(CH3)2
LA2973
RB7
RB6
N
Si(CH3)2


LA2854
RB10
RB6
C
Si(CH3)2
LA2974
RB10
RB6
N
Si(CH3)2


LA2855
RA3
RB6
C
Si(CH3)2
LA2975
RA3
RB6
N
Si(CH3)2


LA2856
RA34
RB6
C
Si(CH3)2
LA2976
RA34
RB6
N
Si(CH3)2









wherein LA2977 through LA3096 have a structure of Formula XXI:





wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA2977
H
H
S
LA3037
RB1
RB4
NCH3


LA2978
H
RB1
S
LA3038
RB1
RB5
NCH3


LA2979
H
RB2
S
LA3039
RB1
RA34
NCH3


LA2980
H
RB3
S
LA3040
RB1
RA52
NCH3


LA2981
H
RB4
S
LA3041
RB1
H
C(CH3)2


LA2982
H
RB5
S
LA3042
RB1
RB1
C(CH3)2


LA2983
H
RA34
S
LA3043
RB1
RB2
C(CH3)2


LA2984
H
RA52
S
LA3044
RB1
RB3
C(CH3)2


LA2985
H
H
O
LA3045
RB1
RB4
C(CH3)2


LA2986
H
RB1
O
LA3046
RB1
RB5
C(CH3)2


LA2987
H
RB2
O
LA3047
RB1
RA34
C(CH3)2


LA2988
H
RB3
O
LA3048
RB1
RA52
C(CH3)2


LA2989
H
RB4
O
LA3049
RB1
H
Si(CH3)2


LA2990
H
RB5
O
LA3050
RB1
RB1
Si(CH3)2


LA2991
H
RA34
O
LA3051
RB1
RB2
Si(CH3)2


LA2992
H
RA52
O
LA3052
RB1
RB3
Si(CH3)2


LA2993
H
H
NCH3
LA3053
RB1
RB4
Si(CH3)2


LA2994
H
RB1
NCH3
LA3054
RB1
RB5
Si(CH3)2


LA2995
H
RB2
NCH3
LA3055
RB1
RA34
Si(CH3)2


LA2996
H
RB3
NCH3
LA3056
RB1
RA52
Si(CH3)2


LA2997
H
RB4
NCH3
LA3057
RB6
H
S


LA2998
H
RB5
NCH3
LA3058
RB6
RB1
S


LA2999
H
RA34
NCH3
LA3059
RB6
RB2
S


LA3000
H
RA52
NCH3
LA3060
RB6
RB3
S


LA3001
H
H
C(CH3)2
LA3061
RB6
RB4
S


LA3002
H
RB1
C(CH3)2
LA3062
RB6
RB5
S


LA3003
H
RB2
C(CH3)2
LA3063
RB6
RA34
S


LA3004
H
RB3
C(CH3)2
LA3064
RB6
RA52
S


LA3005
H
RB4
C(CH3)2
LA3065
RB6
H
O


LA3006
H
RB5
C(CH3)2
LA3066
RB6
RB1
O


LA3007
H
RA34
C(CH3)2
LA3067
RB6
RB2
O


LA3008
H
RA52
C(CH3)2
LA3068
RB6
RB3
O


LA3009
H
H
Si(CH3)2
LA3069
RB6
RB4
O


LA3010
H
RB1
Si(CH3)2
LA3070
RB6
RB5
O


LA3011
H
RB2
Si(CH3)2
LA3071
RB6
RA34
O


LA3012
H
RB3
Si(CH3)2
LA3072
RB6
RA52
O


LA3013
H
RB4
Si(CH3)2
LA3073
RB6
H
NCH3


LA3014
H
RB5
Si(CH3)2
LA3074
RB6
RB1
NCH3


LA3015
H
RA34
Si(CH3)2
LA3075
RB6
RB2
NCH3


LA3016
H
RA52
Si(CH3)2
LA3076
RB6
RB3
NCH3


LA3017
RB1
H
S
LA3077
RB6
RB4
NCH3


LA3018
RB1
RB1
S
LA3078
RB6
RB5
NCH3


LA3019
RB1
RB2
S
LA3079
RB6
RA34
NCH3


LA3020
RB1
RB3
S
LA3080
RB6
RA52
NCH3


LA3021
RB1
RB4
S
LA3081
RB6
H
C(CH3)2


LA3022
RB1
RB5
S
LA3082
RB6
RB1
C(CH3)2


LA3023
RB1
RA34
S
LA3083
RB6
RB2
C(CH3)2


LA3024
RB1
RA52
S
LA3084
RB6
RB3
C(CH3)2


LA3025
RB1
H
O
LA3085
RB6
RB4
C(CH3)2


LA3026
RB1
RB1
O
LA3086
RB6
RB5
C(CH3)2


LA3027
RB1
RB2
O
LA3087
RB6
RA34
C(CH3)2


LA3028
RB1
RB3
O
LA3088
RB6
RA52
C(CH3)2


LA3029
RB1
RB4
O
LA3089
RB6
H
Si(CH3)2


LA3030
RB1
RB5
O
LA3090
RB6
RB1
Si(CH3)2


LA3031
RB1
RA34
O
LA3091
RB6
RB2
Si(CH3)2


LA3032
RB1
RA52
O
LA3092
RB6
RB3
Si(CH3)2


LA3033
RB1
H
NCH3
LA3093
RB6
RB4
Si(CH3)2


LA3034
RB1
RB1
NCH3
LA3094
RB6
RB5
Si(CH3)2


LA3035
RB1
RB2
NCH3
LA3095
RB6
RA34
Si(CH3)2


LA3036
RB1
RB3
NCH3
LA3096
RB6
RA52
Si(CH3)2









wherein LA3097 through LA3192 have a structure of Formula XXII:





wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA3097
H
H
S
S
LA3145
RB6
H
S
S


LA3098
H
RB1
S
S
LA3146
RB6
RB1
S
S


LA3099
H
RB3
S
S
LA3147
RB6
RB3
S
S


LA3100
H
RB4
S
S
LA3148
RB6
RB4
S
S


LA3101
H
RB7
S
S
LA3149
RB6
RB7
S
S


LA3102
H
RB10
S
S
LA3150
RB6
RB10
S
S


LA3103
H
RA3
S
S
LA3151
RB6
RA3
S
S


LA3104
H
RA34
S
S
LA3152
RB6
RA34
S
S


LA3105
H
H
S
O
LA3153
RB6
H
S
O


LA3106
H
RB1
S
O
LA3154
RB6
RB1
S
O


LA3107
H
RB3
S
O
LA3155
RB6
RB3
S
O


LA3108
H
RB4
S
O
LA3156
RB6
RB4
S
O


LA3109
H
RB7
S
O
LA3157
RB6
RB7
S
O


LA3110
H
RB10
S
O
LA3158
RB6
RB10
S
O


LA3111
H
RA3
S
O
LA3159
RB6
RA3
S
O


LA3112
H
RA34
S
O
LA3160
RB6
RA34
S
O


LA3113
H
H
S
NCH3
LA3161
RB6
H
S
NCH3


LA3114
H
RB1
S
NCH3
LA3162
RB6
RB1
S
NCH3


LA3115
H
RB3
S
NCH3
LA3163
RB6
RB3
S
NCH3


LA3116
H
RB4
S
NCH3
LA3164
RB6
RB4
S
NCH3


LA3117
H
RB7
S
NCH3
LA3165
RB6
RB7
S
NCH3


LA3118
H
RB10
S
NCH3
LA3166
RB6
RB10
S
NCH3


LA3119
H
RA3
S
NCH3
LA3167
RB6
RA3
S
NCH3


LA3120
H
RA34
S
NCH3
LA3168
RB6
RA34
S
NCH3


LA3121
H
H
O
S
LA3169
RB6
H
O
S


LA3122
H
RB1
O
S
LA3170
RB6
RB1
O
S


LA3123
H
RB3
O
S
LA3171
RB6
RB3
O
S


LA3124
H
RB4
O
S
LA3172
RB6
RB4
O
S


LA3125
H
RB7
O
S
LA3173
RB6
RB7
O
S


LA3126
H
RB10
O
S
LA3174
RB6
RB10
O
S


LA3127
H
RA3
O
S
LA3175
RB6
RA3
O
S


LA3128
H
RA34
O
S
LA3176
RB6
RA34
O
S


LA3129
H
H
O
O
LA3177
RB6
H
O
O


LA3130
H
RB1
O
O
LA3178
RB6
RB1
O
O


LA3131
H
RB3
O
O
LA3179
RB6
RB3
O
O


LA3132
H
RB4
O
O
LA3180
RB6
RB4
O
O


LA3133
H
RB7
O
O
LA3181
RB6
RB7
O
O


LA3134
H
RB10
O
O
LA3182
RB6
RB10
O
O


LA3135
H
RA3
O
O
LA3183
RB6
RA3
O
O


LA3136
H
RA34
O
O
LA3184
RB6
RA34
O
O


LA3137
H
H
O
NCH3
LA3185
RB6
H
O
NCH3


LA3138
H
RB1
O
NCH3
LA3186
RB6
RB1
O
NCH3


LA3139
H
RB3
O
NCH3
LA3187
RB6
RB3
O
NCH3


LA3140
H
RB4
O
NCH3
LA3188
RB6
RB4
O
NCH3


LA3141
H
RB7
O
NCH3
LA3189
RB6
RB7
O
NCH3


LA3142
H
RB10
O
NCH3
LA3190
RB6
RB10
O
NCH3


LA3143
H
RA3
O
NCH3
LA3191
RB6
RA3
O
NCH3


LA3144
H
RA34
O
NCH3
LA3192
RB6
RA34
O
NCH3









wherein LA3193 through LA3432 have a structure of Formula XXIII:





wherein R1, R5, X, and Y are defined as provided below:




















Ligand 
R1
R5
X
Y
Ligand
R1
R5
X
Y







LA3193
H
H
C
S
LA3313
H
H
N
S


LA3194
RB1
H
C
S
LA3314
RB1
H
N
S


LA3195
RB3
H
C
S
LA3315
RB3
H
N
S


LA3196
RB4
H
C
S
LA3316
RB4
H
N
S


LA3197 
RB7
H
C
S
LA3317
RB7
H
N
S


LA3198 
RB10
H
C
S
LA3318
RB10
H
N
S


LA3199 
RA3
H
C
S
LA3319
RA3
H
N
S


LA3200
RA34
H
C
S
LA3320
RA34
H
N
S


LA3201
H
H
C
O
LA3321
H
H
N
O


LA3202
RB1
H
C
O
LA3322
RB1
H
N
O


LA3203
RB3
H
C
O
LA3323
RB3
H
N
O


LA3204
RB4
H
C
O
LA3324
RB4
H
N
O


LA3205
RB7
H
C
O
LA3325
RB7
H
N
O


LA3206
RB10
H
C
O
LA3326
RB10
H
N
O


LA3207
RA3
H
C
O
LA3327
RA3
H
N
O


LA3208
RA34
H
C
O
LA3328
RA34
H
N
O


LA3209
H
H
C
NCH3
LA3329
H
H
N
NCH3


LA3210
RB1
H
C
NCH3
LA3330
RB1
H
N
NCH3


LA3211
RB3
H
C
NCH3
LA3331
RB3
H
N
NCH3


LA3212
RB4
H
C
NCH3
LA3332
RB4
H
N
NCH3


LA3213
RB7
H
C
NCH3
LA3333
RB7
H
N
NCH3


LA3214
RB10
H
C
NCH3
LA3334
RB10
H
N
NCH3


LA3215
RA3
H
C
NCH3
LA3335
RA3
H
N
NCH3


LA3216
RA34
H
C
NCH3
LA3336
RA34
H
N
NCH3


LA3217
H
H
C
C(CH3)2
LA3337
H
H
N
C(CH3)2


LA3218
RB1
H
C
C(CH3)2
LA3338
RB1
H
N
C(CH3)2


LA3219
RB3
H
C
C(CH3)2
LA3339
RB3
H
N
C(CH3)2


LA3220
RB4
H
C
C(CH3)2
LA3340
RB4
H
N
C(CH3)2


LA3221
RB7
H
C
C(CH3)2
LA3341
RB7
H
N
C(CH3)2


LA3222
RB10
H
C
C(CH3)2
LA3342
RB10
H
N
C(CH3)2


LA3223
RA3
H
C
C(CH3)2
LA3343
RA3
H
N
C(CH3)2


LA3224
RA34
H
C
C(CH3)2
LA3344
RA34
H
N
C(CH3)2


LA3225
H
H
C
Si(CH3)2
LA3345
H
H
N
Si(CH3)2


LA3226
RB1
H
C
Si(CH3)2
LA3346
RB1
H
N
Si(CH3)2


LA3227
RB3
H
C
Si(CH3)2
LA3347
RB3
H
N
Si(CH3)2


LA3228
RB4
H
C
Si(CH3)2
LA3348
RB4
H
N
Si(CH3)2


LA3229
RB7
H
C
Si(CH3)2
LA3349
RB7
H
N
Si(CH3)2


LA3230
RB10
H
C
Si(CH3)2
LA3350
RB10
H
N
Si(CH3)2


LA3231
RA3
H
C
Si(CH3)2
LA3351
RA3
H
N
Si(CH3)2


LA3232
RA34
H
C
Si(CH3)2
LA3352
RA34
H
N
Si(CH3)2


LA3233
H
RB1
C
S
LA3353
H
RB1
N
S


LA3234
RB1
RB1
C
S
LA3354
RB1
RB1
N
S


LA3235
RB3
RB1
C
S
LA3355
RB3
RB1
N
S


LA3236
RB4
RB1
C
S
LA3356
RB4
RB1
N
S


LA3237
RB7
RB1
C
S
LA3357
RB7
RB1
N
S


LA3238
RB10
RB1
C
S
LA3358
RB10
RB1
N
S


LA3239
RA3
RB1
C
S
LA3359
RA3
RB1
N
S


LA3240
RA34
RB1
C
S
LA3360
RA34
RB1
N
S


LA3241
H
RB1
C
O
LA3361
H
RB1
N
O


LA3242
RB1
RB1
C
O
LA3362
RB1
RB1
N
O


LA3243
RB3
RB1
C
O
LA3363
RB3
RB1
N
O


LA3244
RB4
RB1
C
O
LA3364
RB4
RB1
N
O


LA3245
RB7
RB1
C
O
LA3365
RB7
RB1
N
O


LA3246
RB10
RB1
C
O
LA3366
RB10
RB1
N
O


LA3247
RA3
RB1
C
O
LA3367
RA3
RB1
N
O


LA3248
RA34
RB1
C
O
LA3368
RA34
RB1
N
O


LA3249
H
RB1
C
NCH3
LA3369
H
RB1
N
NCH3


LA3250
RB1
RB1
C
NCH3
LA3370
RB1
RB1
N
NCH3


LA3251
RB3
RB1
C
NCH3
LA3371
RB3
RB1
N
NCH3


LA3252
RB4
RB1
C
NCH3
LA3372
RB4
RB1
N
NCH3


LA3253
RB7
RB1
C
NCH3
LA3373
RB7
RB1
N
NCH3


LA3254
RB10
RB1
C
NCH3
LA3374
RB10
RB1
N
NCH3


LA3255
RA3
RB1
C
NCH3
LA3375
RA3
RB1
N
NCH3


LA3256
RA34
RB1
C
NCH3
LA3376
RA34
RB1
N
NCH3


LA3257
H
RB1
C
C(CH3)2
LA3377
H
RB1
N
C(CH3)2


LA3258
RB1
RB1
C
C(CH3)2
LA3378
RB1
RB1
N
C(CH3)2


LA3259
RB3
RB1
C
C(CH3)2
LA3379
RB3
RB1
N
C(CH3)2


LA3260
RB4
RB1
C
C(CH3)2
LA3380
RB4
RB1
N
C(CH3)2


LA3261
RB7
RB1
C
C(CH3)2
LA3381
RB7
RB1
N
C(CH3)2


LA3262
RB10
RB1
C
C(CH3)2
LA3382
RB10
RB1
N
C(CH3)2


LA3263
RA3
RB1
C
C(CH3)2
LA3383
RA3
RB1
N
C(CH3)2


LA3264
RA34
RB1
C
C(CH3)2
LA3384
RA34
RB1
N
C(CH3)2


LA3265
H
RB1
C
Si(CH3)2
LA3385
H
RB1
N
Si(CH3)2


LA3266
RB1
RB1
C
Si(CH3)2
LA3386
RB1
RB1
N
Si(CH3)2


LA3267
RB3
RB1
C
Si(CH3)2
LA3387
RB3
RB1
N
Si(CH3)2


LA3268
RB4
RB1
C
Si(CH3)2
LA3388
RB4
RB1
N
Si(CH3)2


LA3269
RB7
RB1
C
Si(CH3)2
LA3389
RB7
RB1
N
Si(CH3)2


LA3270
RB10
RB1
C
Si(CH3)2
LA3390
RB10
RB1
N
Si(CH3)2


LA3271
RA3
RB1
C
Si(CH3)2
LA3391
RA3
RB1
N
Si(CH3)2


LA3272
RA34
RB1
C
Si(CH3)2
LA3392
RA34
RB1
N
Si(CH3)2


LA3273
H
RB6
C
S
LA3393
H
RB6
N
S


LA3274
RB1
RB6
C
S
LA3394
RB1
RB6
N
S


LA3275
RB3
RB6
C
S
LA3395
RB3
RB6
N
S


LA3276
RB4
RB6
C
S
LA3396
RB4
RB6
N
S


LA3277
RB7
RB6
C
S
LA3397
RB7
RB6
N
S


LA3278
RB10
RB6
C
S
LA3398
RB10
RB6
N
S


LA3279
RA3
RB6
C
S
LA3399
RA3
RB6
N
S


LA3280
RA34
RB6
C
S
LA3400
RA34
RB6
N
S


LA3281
H
RB6
C
O
LA3401
H
RB6
N
O


LA3282
RB1
RB6
C
O
LA3402
RB1
RB6
N
O


LA3283
RB3
RB6
C
O
LA3403
RB3
RB6
N
O


LA3284
RB4
RB6
C
O
LA3404
RB4
RB6
N
O


LA3285
RB7
RB6
C
O
LA3405
RB7
RB6
N
O


LA3286
RB10
RB6
C
O
LA3406
RB10
RB6
N
O


LA3287
RA3
RB6
C
O
LA3407
RA3
RB6
N
O


LA3288
RA34
RB6
C
O
LA3408
RA34
RB6
N
O


LA3289
H
RB6
C
NCH3
LA3409
H
RB6
N
NCH3


LA3290
RB1
RB6
C
NCH3
LA3410
RB1
RB6
N
NCH3


LA3291
RB3
RB6
C
NCH3
LA3411
RB3
RB6
N
NCH3


LA3292
RB4
RB6
C
NCH3
LA3412
RB4
RB6
N
NCH3


LA3293
RB7
RB6
C
NCH3
LA3413
RB7
RB6
N
NCH3


LA3294
RB10
RB6
C
NCH3
LA3414
RB10
RB6
N
NCH3


LA3295
RA3
RB6
C
NCH3
LA3415
RA3
RB6
N
NCH3


LA3296
RA34
RB6
C
NCH3
LA3416
RA34
RB6
N
NCH3


LA3297
H
RB6
C
C(CH3)2
LA3417
H
RB6
N
C(CH3)2


LA3298
RB1
RB6
C
C(CH3)2
LA3418
RB1
RB6
N
C(CH3)2


LA3299
RB3
RB6
C
C(CH3)2
LA3419
RB3
RB6
N
C(CH3)2


LA3300
RB4
RB6
C
C(CH3)2
LA3420
RB4
RB6
N
C(CH3)2


LA3301
RB7
RB6
C
C(CH3)2
LA3421
RB7
RB6
N
C(CH3)2


LA3302
RB10
RB6
C
C(CH3)2
LA3422
RB10
RB6
N
C(CH3)2


LA3303
RA3
RB6
C
C(CH3)2
LA3423
RA3
RB6
N
C(CH3)2


LA3304
RA34
RB6
C
C(CH3)2
LA3424
RA34
RB6
N
C(CH3)2


LA3305
H
RB6
C
Si(CH3)2 
LA3425
H
RB6
N
Si(CH3)2


LA3306
RB1
RB6
C
Si(CH3)2 
LA3426
RB1
RB6
N
Si(CH3)2


LA3307
RB3
RB6
C
Si(CH3)2 
LA3427
RB3
RB6
N
Si(CH3)2


LA3308
RB4
RB6
C
Si(CH3)2 
LA3428
RB4
RB6
N
Si(CH3)2


LA3309
RB7
RB6
C
Si(CH3)2 
LA3429
RB7
RB6
N
Si(CH3)2


LA3310
RB10
RB6
C
Si(CH3)2 
LA3430
RB10
RB6
N
Si(CH3)2


LA3311
RA3
RB6
C
Si(CH3)2 
LA3431
RA3
RB6
N
Si(CH3)2


LA3312
RA34
RB6
C
Si(CH3)2 
LA3432
RA34
RB6
N









wherein LA3433 through LA3552 have a structure of Formula XXIV:





wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA3433
H
H
S
LA3493
RB1
RB4
NCH3


LA3434
H
RB1
S
LA3494
RB1
RB5
NCH3


LA3435
H
RB2
S
LA3495
RB1
RA34
NCH3


LA3436
H
RB3
S
LA3496
RB1
RA52
NCH3


LA3437
H
RB4
S
LA3497
RB1
H
C(CH3)2


LA3438
H
RB5
S
LA3498
RB1
RB1
C(CH3)2


LA3439
H
RA34
S
LA3499
RB1
RB2
C(CH3)2


LA3440
H
RA52
S
LA3500
RB1
RB3
C(CH3)2


LA3441
H
H
O
LA3501
RB1
RB4
C(CH3)2


LA3442
H
RB1
O
LA3502
RB1
RB5
C(CH3)2


LA3443
H
RB2
O
LA3503
RB1
RA34
C(CH3)2


LA3444
H
RB3
O
LA3504
RB1
RA52
C(CH3)2


LA3445
H
RB4
O
LA3505
RB1
H
Si(CH3)2


LA3446
H
RB5
O
LA3506
RB1
RB1
Si(CH3)2


LA3447
H
RA34
O
LA3507
RB1
RB2
Si(CH3)2


LA3448
H
RA52
O
LA3508
RB1
RB3
Si(CH3)2


LA3449
H
H
NCH3
LA3509
RB1
RB4
Si(CH3)2


LA3450
H
RB1
NCH3
LA3510
RB1
RB5
Si(CH3)2


LA3451
H
RB2
NCH3
LA3511
RB1
RA34
Si(CH3)2


LA3452
H
RB3
NCH3
LA3512
RB1
RA52
Si(CH3)2


LA3453
H
RB4
NCH3
LA3513
RB6
H
S


LA3454
H
RB5
NCH3
LA3514
RB6
RB1
S


LA3455
H
RA34
NCH3
LA3515
RB6
RB2
S


LA3456
H
RA52
NCH3
LA3516
RB6
RB3
S


LA3457
H
H
C(CH3)2
LA3517
RB6
RB4
S


LA3458
H
RB1
C(CH3)2
LA3518
RB6
RB5
S


LA3459
H
RB2
C(CH3)2
LA3519
RB6
RA34
S


LA3460
H
RB3
C(CH3)2
LA3520
RB6
RA52
S


LA3461
H
RB4
C(CH3)2
LA3521
RB6
H
O


LA3462
H
RB5
C(CH3)2
LA3522
RB6
RB1
O


LA3463
H
RA34
C(CH3)2
LA3523
RB6
RB2
O


LA3464
H
RA52
C(CH3)2
LA3524
RB6
RB3
O


LA3465
H
H
Si(CH3)2
LA3525
RB6
RB4
O


LA3466
H
RB1
Si(CH3)2
LA3526
RB6
RB5
O


LA3467
H
RB2
Si(CH3)2
LA3527
RB6
RA34
O


LA3468
H
RB3
Si(CH3)2
LA3528
RB6
RA52
O


LA3469
H
RB4
Si(CH3)2
LA3529
RB6
H
NCH3


LA3470
H
RB5
Si(CH3)2
LA3530
RB6
RB1
NCH3


LA3471
H
RA34
Si(CH3)2
LA3531
RB6
RB2
NCH3


LA3472
H
RA52
Si(CH3)2
LA3532
RB6
RB3
NCH3


LA3473
RB1
H
S
LA3533
RB6
RB4
NCH3


LA3474
RB1
RB1
S
LA3534
RB6
RB5
NCH3


LA3475
RB1
RB2
S
LA3535
RB6
RA34
NCH3


LA3476
RB1
RB3
S
LA3536
RB6
RA52
NCH3


LA3477
RB1
RB4
S
LA3537
RB6
H
C(CH3)2


LA3478
RB1
RB5
S
LA3538
RB6
RB1
C(CH3)2


LA3479
RB1
RA34
S
LA3539
RB6
RB2
C(CH3)2


LA3480
RB1
RA52
S
LA3540
RB6
RB3
C(CH3)2


LA3481
RB1
H
O
LA3541
RB6
RB4
C(CH3)2


LA3482
RB1
RB1
O
LA3542
RB6
RB5
C(CH3)2


LA3483
RB1
RB2
O
LA3543
RB6
RA34
C(CH3)2


LA3484
RB1
RB3
O
LA3544
RB6
RA52
C(CH3)2


LA3485
RB1
RB4
O
LA3545
RB6
H
Si(CH3)2


LA3486
RB1
RB5
O
LA3546
RB6
RB1
Si(CH3)2


LA3487
RB1
RA34
O
LA3547
RB6
RB2
Si(CH3)2


LA3488
RB1
RA52
O
LA3548
RB6
RB3
Si(CH3)2


LA3489
RB1
H
NCH3
LA3549
RB6
RB4
Si(CH3)2


LA3490
RB1
RB1
NCH3
LA3550
RB6
RB5
Si(CH3)2


LA3491
RB1
RB2
NCH3
LA3551
RB6
RA34
Si(CH3)2


LA3492
RB1
RB3
NCH3
LA3552
RB6
RA52
Si(CH3)2









wherein LA3553 through LA3648 have a structure of Formula XXV:





wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA3553
H
H
S
S
LA3601
RB6
H
S
S


LA3554
H
RB1
S
S
LA3602
RB6
RB1
S
S


LA3555
H
RB3
S
S
LA3603
RB6
RB3
S
S


LA3556
H
RB4
S
S
LA3604
RB6
RB4
S
S


LA3557
H
RB7
S
S
LA3605
RB6
RB7
S
S


LA3558
H
RB10
S
S
LA3606
RB6
RB10
S
S


LA3559
H
RA3
S
S
LA3607
RB6
RA3
S
S


LA3560
H
RA34
S
S
LA3608
RB6
RA34
S
S


LA3561
H
H
S
O
LA3609
RB6
H
S
O


LA3562
H
RB1
S
O
LA3610
RB6
RB1
S
O


LA3563
H
RB3
S
O
LA3611
RB6
RB3
S
O


LA3564
H
RB4
S
O
LA3612
RB6
RB4
S
O


LA3565
H
RB7
S
O
LA3613
RB6
RB7
S
O


LA3566
H
RB10
S
O
LA3614
RB6
RB10
S
O


LA3567
H
RA3
S
O
LA3615
RB6
RA3
S
O


LA3568
H
RA34
S
O
LA3616
RB6
RA34
S
O


LA3569
H
H
S
NCH3
LA3617
RB6
H
S
NCH3


LA3570
H
RB1
S
NCH3
LA3618
RB6
RB1
S
NCH3


LA3571
H
RB3
S
NCH3
LA3619
RB6
RB3
S
NCH3


LA3572
H
RB4
S
NCH3
LA3620
RB6
RB4
S
NCH3


LA3573
H
RB7
S
NCH3
LA3621
RB6
RB7
S
NCH3


LA3574
H
RB10
S
NCH3
LA3622
RB6
RB10
S
NCH3


LA3575
H
RA3
S
NCH3
LA3623
RB6
RA3
S
NCH3


LA3576
H
RA34
S
NCH3
LA3624
RB6
RA34
S
NCH3


LA3577
H
H
O
S
LA3625
RB6
H
O
S


LA3578
H
RB1
O
S
LA3626
RB6
RB1
O
S


LA3579
H
RB3
O
S
LA3627
RB6
RB3
O
S


LA3580
H
RB4
O
S
LA3628
RB6
RB4
O
S


LA3581
H
RB7
O
S
LA3629
RB6
RB7
O
S


LA3582
H
RB10
O
S
LA3630
RB6
RB10
O
S


LA3583
H
RA3
O
S
LA3631
RB6
RA3
O
S


LA3584
H
RA34
O
S
LA3632
RB6
RA34
O
S


LA3585
H
H
O
O
LA3633
RB6
H
O
O


LA3586
H
RB1
O
O
LA3634
RB6
RB1
O
O


LA3587
H
RB3
O
O
LA3635
RB6
RB3
O
O


LA3588
H
RB4
O
O
LA3636
RB6
RB4
O
O


LA3589
H
RB7
O
O
LA3637
RB6
RB7
O
O


LA3590
H
RB10
O
O
LA3638
RB6
RB10
O
O


LA3591
H
RA3
O
O
LA3639
RB6
RA3
O
O


LA3592
H
RA34
O
O
LA3640
RB6
RA34
O
O


LA3593
H
H
O
NCH3
LA3641
RB6
H
O
NCH3


LA3594
H
RB1
O
NCH3
LA3642
RB6
RB1
O
NCH3


LA3595
H
RB3
O
NCH3
LA3643
RB6
RB3
O
NCH3


LA3596
H
RB4
O
NCH3
LA3644
RB6
RB4
O
NCH3


LA3597
H
RB7
O
NCH3
LA3645
RB6
RB7
O
NCH3


LA3598
H
RB10
O
NCH3
LA3646
RB6
RB10
O
NCH3


LA3599
H
RA3
O
NCH3
LA3647
RB6
RA3
O
NCH3


LA3600
H
RA34
O
NCH3
LA3648
RB6
RA34
O
NCH3









wherein LA3649 through LA3888 have a structure of Formula XXVI:





wherein R1, R5, X, and Y are defined as provided below:




















Ligand
R1
R5
X
Y
Ligand
R1
R5
X
Y







LA3649
H
H
C
S
LA3769
H
H
N
S


LA3650
RB1
H
C
S
LA3770
RB1
H
N
S


LA3651
RB3
H
C
S
LA3771
RB3
H
N
S


LA3652
RB4
H
C
S
LA3772
RB4
H
N
S


LA3653
RB7
H
C
S
LA3773
RB7
H
N
S


LA3654
RB10
H
C
S
LA3774
RB10
H
N
S


LA3655
RA3
H
C
S
LA3775
RA3
H
N
S


LA3656
RA34
H
C
S
LA3776
RA34
H
N
S


LA3657
H
H
C
O
LA3777
H
H
N
O


LA3658
RB1
H
C
O
LA3778
RB1
H
N
O


LA3659
RB3
H
C
O
LA3779
RB3
H
N
O


LA3660
RB4
H
C
O
LA3780
RB4
H
N
O


LA3661
RB7
H
C
O
LA3781
RB7
H
N
O


LA3662
RB10
H
C
O
LA3782
RB10
H
N
O


LA3663
RA3
H
C
O
LA3783
RA3
H
N
O


LA3664
RA34
H
C
O
LA3784
RA34
H
N
O


LA3665
H
H
C
NCH3
LA3785
H
H
N
NCH3


LA3666
RB1
H
C
NCH3
LA3786
RB1
H
N
NCH3


LA3667
RB3
H
C
NCH3
LA3787
RB3
H
N
NCH3


LA3668
RB4
H
C
NCH3
LA3788
RB4
H
N
NCH3


LA3669
RB7
H
C
NCH3
LA3789
RB7
H
N
NCH3


LA3670
RB10
H
C
NCH3
LA3790
RB10
H
N
NCH3


LA3671
RA3
H
C
NCH3
LA3791
RA3
H
N
NCH3


LA3672
RA34
H
C
NCH3
LA3792
RA34
H
N
NCH3


LA3673
H
H
C
C(CH3)2
LA3793
H
H
N
C(CH3)2


LA3674
RB1
H
C
C(CH3)2
LA3794
RB1
H
N
C(CH3)2


LA3675
RB3
H
C
C(CH3)2
LA3795
RB3
H
N
C(CH3)2


LA3676
RB4
H
C
C(CH3)2
LA3796
RB4
H
N
C(CH3)2


LA3677
RB7
H
C
C(CH3)2
LA3797
RB7
H
N
C(CH3)2


LA3678
RB10
H
C
C(CH3)2
LA3798
RB10
H
N
C(CH3)2


LA3679
RA3
H
C
C(CH3)2
LA3799
RA3
H
N
C(CH3)2


LA3680
RA34
H
C
C(CH3)2
LA3800
RA34
H
N
C(CH3)2


LA3681
H
H
C
Si(CH3)2 
LA3801
H
H
N
Si(CH3)2


LA3682
RB1
H
C
Si(CH3)2 
LA3802
RB1
H
N
Si(CH3)2


LA3683
RB3
H
C
Si(CH3)2 
LA3803
RB3
H
N
Si(CH3)2


LA3684
RB4
H
C
Si(CH3)2 
LA3804
RB4
H
N
Si(CH3)2


LA3685
RB7
H
C
Si(CH3)2 
LA3805
RB7
H
N
Si(CH3)2


LA3686
RB10
H
C
Si(CH3)2
LA3806
RB10
H
N
Si(CH3)2


LA3687
RA3
H
C
Si(CH3)2
LA3807
RA3
H
N
Si(CH3)2


LA3688
RA34
H
C
Si(CH3)2 
LA3808
RA34
H
N
Si(CH3)2


LA3689
H
RB1
C
S
LA3809
H
RB1
N
S


LA3690
RB1
RB1
C
S
LA3810
RB1
RB1
N
S


LA3691
RB3
RB1
C
S
LA3811
RB3
RB1
N
S


LA3692
RB4
RB1
C
S
LA3812
RB4
RB1
N
S


LA3693
RB7
RB1
C
S
LA3813
RB7
RB1
N
S


LA3694
RB10
RB1
C
S
LA3814
RB10
RB1
N
S


LA3695
RA3
RB1
C
S
LA3815
RA3
RB1
N
S


LA3696
RA34
RB1
C
S
LA3816
RA34
RB1
N
S


LA3697
H
RB1
C
O
LA3817
H
RB1
N
O


LA3698
RB1
RB1
C
O
LA3818
RB1
RB1
N
O


LA3699
RB3
RB1
C
O
LA3819
RB3
RB1
N
O


LA3700
RB4
RB1
C
O
LA3820
RB4
RB1
N
O


LA3701
RB7
RB1
C
O
LA3821
RB7
RB1
N
O


LA3702
RB10
RB1
C
O
LA3822
RB10
RB1
N
O


LA3703
RA3
RB1
C
O
LA3823
RA3
RB1
N
O


LA3704
RA34
RB1
C
O
LA3824
RA34
RB1
N
O


LA3705
H
RB1
C
NCH3
LA3825
H
RB1
N
NCH3


LA3706
RB1
RB1
C
NCH3
LA3826
RB1
RB1
N
NCH3


LA3707
RB3
RB1
C
NCH3
LA3827
RB3
RB1
N
NCH3


LA3708
RB4
RB1
C
NCH3
LA3828
RB4
RB1
N
NCH3


LA3709
RB7
RB1
C
NCH3
LA3829
RB7
RB1
N
NCH3


LA3710
RB10
RB1
C
NCH3
LA3830
RB10
RB1
N
NCH3


LA3711
RA3
RB1
C
NCH3
LA3831
RA3
RB1
N
NCH3


LA3712
RA34
RB1
C
NCH3
LA3832
RA34
RB1
N
NCH3


LA3713
H
RB1
C
C(CH3)2
LA3833
H
RB1
N
C(CH3)2


LA3714
RB1
RB1
C
C(CH3)2
LA3834
RB1
RB1
N
C(CH3)2


LA3715
RB3
RB1
C
C(CH3)2
LA3835
RB3
RB1
N
C(CH3)2


LA3716
RB4
RB1
C
C(CH3)2
LA3836
RB4
RB1
N
C(CH3)2


LA3717
RB7
RB1
C
C(CH3)2
LA3837
RB7
RB1
N
C(CH3)2


LA3718
RB10
RB1
C
C(CH3)2
LA3838
RB10
RB1
N
C(CH3)2


LA3719
RA3
RB1
C
C(CH3)2
LA3839
RA3
RB1
N
C(CH3)2


LA3720
RA34
RB1
C
C(CH3)2
LA3840
RA34
RB1
N
C(CH3)2


LA3721
H
RB1
C
Si(CH3)2 
LA3841
H
RB1
N
Si(CH3)2


LA3722
RB1
RB1
C
Si(CH3)2 
LA3842
RB1
RB1
N
Si(CH3)2


LA3723
RB3
RB1
C
Si(CH3)2 
LA3843
RB3
RB1
N
Si(CH3)2


LA3724
RB4
RB1
C
Si(CH3)2 
LA3844
RB4
RB1
N
Si(CH3)2


LA3725
RB7
RB1
C
Si(CH3)2
LA3845
RB7
RB1
N
Si(CH3)2


LA3726
RB10
RB1
C
Si(CH3)2 
LA3846
RB10
RB1
N
Si(CH3)2


LA3727
RA3
RB1
C
Si(CH3)2 
LA3847
RA3
RB1
N
Si(CH3)2


LA3728
RA34
RB1
C
Si(CH3)2 
LA3848
RA34
RB1
N
Si(CH3)2


LA3729
H
RB6
C
S
LA3849
H
RB6
N
S


LA3730
RB1
RB6
C
S
LA3850
RB1
RB6
N
S


LA3731
RB3
RB6
C
S
LA3851
RB3
RB6
N
S


LA3732
RB4
RB6
C
S
LA3852
RB4
RB6
N
S


LA3733
RB7
RB6
C
S
LA3853
RB7
RB6
N
S


LA3734
RB10
RB6
C
S
LA3854
RB10
RB6
N
S


LA3735
RA3
RB6
C
S
LA3855
RA3
RB6
N
S


LA3736
RA34
RB6
C
S
LA3856
RA34
RB6
N
S


LA3737
H
RB6
C
O
LA3857
H
RB6
N
O


LA3738
RB1
RB6
C
O
LA3858
RB1
RB6
N
O


LA3739
RB3
RB6
C
O
LA3859
RB3
RB6
N
O


LA3740
RB4
RB6
C
O
LA3860
RB4
RB6
N
O


LA3741
RB7
RB6
C
O
LA3861
RB7
RB6
N
O


LA3742
RB10
RB6
C
O
LA3862
RB10
RB6
N
O


LA3743
RA3
RB6
C
O
LA3863
RA3
RB6
N
O


LA3744
RA34
RB6
C
O
LA3864
RA34
RB6
N
O


LA3745
H
RB6
C
NCH3
LA3865
H
RB6
N
NCH3


LA3746
RB1
RB6
C
NCH3
LA3866
RB1
RB6
N
NCH3


LA3747
RB3
RB6
C
NCH3
LA3867
RB3
RB6
N
NCH3


LA3748
RB4
RB6
C
NCH3
LA3868
RB4
RB6
N
NCH3


LA3749
RB7
RB6
C
NCH3
LA3869
RB7
RB6
N
NCH3


LA3750
RB10
RB6
C
NCH3
LA3870
RB10
RB6
N
NCH3


LA3751
RA3
RB6
C
NCH3
LA3871
RA3
RB6
N
NCH3


LA3752
RA34
RB6
C
NCH3
LA3872
RA34
RB6
N
NCH3


LA3753
H
RB6
C
C(CH3)2
LA3873
H
RB6
N
C(CH3)2


LA3754
RB1
RB6
C
C(CH3)2
LA3874
RB1
RB6
N
C(CH3)2


LA3755
RB3
RB6
C
C(CH3)2
LA3875
RB3
RB6
N
C(CH3)2


LA3756
RB4
RB6
C
C(CH3)2
LA3876
RB4
RB6
N
C(CH3)2


LA3757
RB7
RB6
C
C(CH3)2
LA3877
RB7
RB6
N
C(CH3)2


LA3758
RB10
RB6
C
C(CH3)2
LA3878
RB10
RB6
N
C(CH3)2


LA3759
RA3
RB6
C
C(CH3)2
LA3879
RA3
RB6
N
C(CH3)2


LA3760
RA34
RB6
C
C(CH3)2
LA3880
RA34
RB6
N
C(CH3)2


LA3761
H
RB6
C
Si(CH3)2
LA3881
H
RB6
N
Si(CH3)2


LA3762
RB1
RB6
C
Si(CH3)2
LA3882
RB1
RB6
N
Si(CH3)2


LA3763
RB3
RB6
C
Si(CH3)2
LA3883
RB3
RB6
N
Si(CH3)2


LA3764
RB4
RB6
C
Si(CH3)2
LA3884
RB4
RB6
N
Si(CH3)2


LA3765
RB7
RB6
C
Si(CH3)2
LA3885
RB7
RB6
N
Si(CH3)2


LA3766
RB10
RB6
C
Si(CH3)2
LA3886
RB10
RB6
N
Si(CH3)2


LA3767
RA3
RB6
C
Si(CH3)2
LA3887
RA3
RB6
N
Si(CH3)2


LA3768
RA34
RB6
C
Si(CH3)2
LA3888
RA34
RB6
N
Si(CH3)2









wherein LA3889 through LA4008 have a structure of Formula XXVII:





wherein R3, R5, and Y are defined as provided below:

















Ligand
R5
R3
Y









LA3889
H
H
S



LA3890
H
RB1
S



LA3891
H
RB2
S



LA3892
H
RB3
S



LA3893
H
RB4
S



LA3894
H
RB5
S



LA3895
H
RA34
S



LA3896
H
RA52
S



LA3897
H
H
O



LA3898
H
RB1
O



LA3899
H
RB2
O



LA3900
H
RB3
O



LA3901
H
RB4
O



LA3902
H
RB5
O



LA3903
H
RA34
O



LA3904
H
RA52
O



LA3905
H
H
NCH3



LA3906
H
RB1
NCH3



LA3907
H
RB2
NCH3



LA3908
H
RB3
NCH3



LA3909
H
RB4
NCH3



LA3910
H
RB5
NCH3



LA3911
H
RA34
NCH3



LA3912
H
RA52
NCH3



LA3913
H
H
C(CH3)2



LA3914
H
RB1
C(CH3)2



LA3915
H
RB2
C(CH3)2



LA3916
H
RB3
C(CH3)2



LA3917
H
RB4
C(CH3)2



LA3918
H
RB5
C(CH3)2



LA3919
H
RA34
C(CH3)2



LA3920
H
RA52
C(CH3)2



LA3921
H
H
Si(CH3)2



LA3922
H
RB1
Si(CH3)2



LA3923
H
RB2
Si(CH3)2



LA3924
H
RB3
Si(CH3)2



LA3925
H
RB4
Si(CH3)2



LA3926
H
RB5
Si(CH3)2



LA3927
H
RA34
Si(CH3)2



LA3928
H
RA52
Si(CH3)2



LA3929
RB1
H
S



LA3930
RB1
RB1
S



LA3931
RB1
RB2
S



LA3932
RB1
RB3
S



LA3933
RB1
RB4
S



LA3934
RB1
RB5
S



LA3935
RB1
RA34
S



LA3936
RB1
RA52
S



LA3937
RB1
H
O



LA3938
RB1
RB1
O



LA3939
RB1
RB2
O



LA3940
RB1
RB3
O



LA3941
RB1
RB4
O



LA3942
RB1
RB5
O



LA3943
RB1
RA34
O



LA3944
RB1
RA52
O



LA3945
RB1
H
NCH3



LA3946
RB1
RB1
NCH3



LA3947
RB1
RB2
NCH3



LA3948
RB1
RB3
NCH3



LA3949
RB1
RB4
NCH3



LA3950
RB1
RB5
NCH3



LA3951
RB1
RA34
NCH3



LA3952
RB1
RA52
NCH3



LA3953
RB1
H
C(CH3)2



LA3954
RB1
RB1
C(CH3)2



LA3955
RB1
RB2
C(CH3)2



LA3956
RB1
RB3
C(CH3)2



LA3957
RB1
RB4
C(CH3)2



LA3958
RB1
RB5
C(CH3)2



LA3959
RB1
RA34
C(CH3)2



LA3960
RB1
RA52
C(CH3)2



LA3961
RB1
H
Si(CH3)2



LA3962
RB1
RB1
Si(CH3)2



LA3963
RB1
RB2
Si(CH3)2



LA3964
RB1
RB3
Si(CH3)2



LA3965
RB1
RB4
Si(CH3)2



LA3966
RB1
RB5
Si(CH3)2



LA3967
RB1
RA34
Si(CH3)2



LA3968
RB1
RA52
Si(CH3)2



LA3969
RB6
H
S



LA3970
RB6
RB1
S



LA3971
RB6
RB2
S



LA3972
RB6
RB3
S



LA3973
RB6
RB4
S



LA3974
RB6
RB5
S



LA3975
RB6
RA34
S



LA3976
RB6
RA52
S



LA3977
RB6
H
O



LA3978
RB6
RB1
O



LA3979
RB6
RB2
O



LA3980
RB6
RB3
O



LA3981
RB6
RB4
O



LA3982
RB6
RB5
O



LA3983
RB6
RA34
O



LA3984
RB6
RA52
O



LA3985
RB6
H
NCH3



LA3986
RB6
RB1
NCH3



LA3987
RB6
RB2
NCH3



LA3988
RB6
RB3
NCH3



LA3989
RB6
RB4
NCH3



LA3990
RB6
RB5
NCH3



LA3991
RB6
RA34
NCH3



LA3992
RB6
RA52
NCH3



LA3993
RB6
H
C(CH3)2



LA3994
RB6
RB1
C(CH3)2



LA3995
RB6
RB2
C(CH3)2



LA3996
RB6
RB3
C(CH3)2



LA3997
RB6
RB4
C(CH3)2



LA3998
RB6
RB5
C(CH3)2



LA3999
RB6
RA34
C(CH3)2



LA4000
RB6
RA52
C(CH3)2



LA4001
RB6
H
Si(CH3)2



LA4002
RB6
RB1
Si(CH3)2



LA4003
RB6
RB2
Si(CH3)2



LA4004
RB6
RB3
Si(CH3)2



LA4005
RB6
RB4
Si(CH3)2



LA4006
RB6
RB5
Si(CH3)2



LA4007
RB6
RA34
Si(CH3)2



LA4008
RB6
RA52
Si(CH3)2










wherein LA4009 through LA4104 have a structure of Formula XXVIII:





wherein R4, R5, Y, and Z are defined as provided below:


















Ligand
R5
R4
Y
Z









LA4009
H
H
S
S



LA4010
H
RB1
S
S



LA4011
H
RB3
S
S



LA4012
H
RB4
S
S



LA4013
H
RB7
S
S



LA4014
H
RB10
S
S



LA4015
H
RA3
S
S



LA4016
H
RA34
S
S



LA4017
H
H
S
O



LA4018
H
RB1
S
O



LA4019
H
RB3
S
O



LA4020
H
RB4
S
O



LA4021
H
RB7
S
O



LA4022
H
RB10
S
O



LA4023
H
RA3
S
O



LA4024
H
RA34
S
O



LA4025
H
H
S
NCH3



LA4026
H
RB1
S
NCH3



LA4027
H
RB3
S
NCH3



LA4028
H
RB4
S
NCH3



LA4029
H
RB7
S
NCH3



LA4030
H
RB10
S
NCH3



LA4031
H
RA3
S
NCH3



LA4032
H
RA34
S
NCH3



LA4033
H
H
O
S



LA4034
H
RB1
O
S



LA4035
H
RB3
O
S



LA4036
H
RB4
O
S



LA4037
H
RB7
O
S



LA4038
H
RB10
O
S



LA4039
H
RA3
O
S



LA4040
H
RA34
O
S



LA4041
H
H
O
O



LA4042
H
RB1
O
O



LA4043
H
RB3
O
O



LA4044
H
RB4
O
O



LA4045
H
RB7
O
O



LA4046
H
RB10
O
O



LA4047
H
RA3
O
O



LA4048
H
RA34
O
O



LA4049
H
H
O
NCH3



LA4050
H
RB1
O
NCH3



LA4051
H
RB3
O
NCH3



LA4052
H
RB4
O
NCH3



LA4053
H
RB7
O
NCH3



LA4054
H
RB10
O
NCH3



LA4055
H
RA3
O
NCH3



LA4056
H
RA34
O
NCH3



LA4057
RB6
H
S
S



LA4058
RB6
RB1
S
S



LA4059
RB6
RB3
S
S



LA4060
RB6
RB4
S
S



LA4061
RB6
RB7
S
S



LA4062
RB6
RB10
S
S



LA4063
RB6
RA3
S
S



LA4064
RB6
RA34
S
S



LA4065
RB6
H
S
O



LA4066
RB6
RB1
S
O



LA4067
RB6
RB3
S
O



LA4068
RB6
RB4
S
O



LA4069
RB6
RB7
S
O



LA4070
RB6
RB10
S
O



LA4071
RB6
RA3
S
O



LA4072
RB6
RA34
S
O



LA4073
RB6
H
S
NCH3



LA4074
RB6
RB1
S
NCH3



LA4075
RB6
RB3
S
NCH3



LA4076
RB6
RB4
S
NCH3



LA4077
RB6
RB7
S
NCH3



LA4078
RB6
RB10
S
NCH3



LA4079
RB6
RA3
S
NCH3



LA4080
RB6
RA34
S
NCH3



LA4081
RB6
H
O
S



LA4082
RB6
RB1
O
S



LA4083
RB6
RB3
O
S



LA4084
RB6
RB4
O
S



LA4085
RB6
RB7
O
S



LA4086
RB6
RB10
O
S



LA4087
RB6
RA3
O
S



LA4088
RB6
RA34
O
S



LA4089
RB6
H
O
O



LA4090
RB6
RB1
O
O



LA4091
RB6
RB3
O
O



LA4092
RB6
RB4
O
O



LA4093
RB6
RB7
O
O



LA4094
RB6
RB10
O
O



LA4095
RB6
RA3
O
O



LA4096
RB6
RA34
O
O



LA4097
RB6
H
O
NCH3



LA4098
RB6
RB1
O
NCH3



LA4099
RB6
RB3
O
NCH3



LA4100
RB6
RB4
O
NCH3



LA4101
RB6
RB7
O
NCH3



LA4102
RB6
RB10
O
NCH3



LA4103
RB6
RA3
O
NCH3



LA4104
RB6
RA34
O
NCH3










wherein LA4105 through LA4344 have a structure of Formula XXIX:





wherein R1, R5, X, and Y are defined as provided below:


















Ligand
R1
R5
X
Y









LA4105
H
H
C
S



LA4106
RB1
H
C
S



LA4107
RB3
H
C
S



LA4108
RB4
H
C
S



LA4109
RB7
H
C
S



LA4110
RB10
H
C
S



LA4111
RA3
H
C
S



LA4112
RA34
H
C
S



LA4113
H
H
C
O



LA4114
RB1
H
C
O



LA4115
RB3
H
C
O



LA4116
RB4
H
C
O



LA4117
RB7
H
C
O



LA4118
RB10
H
C
O



LA4119
RA3
H
C
O



LA4120
RA34
H
C
O



LA4121
H
H
C
NCH3



LA4122
RB1
H
C
NCH3



LA4123
RB3
H
C
NCH3



LA4124
RB4
H
C
NCH3



LA4125
RB7
H
C
NCH3



LA4126
RB10
H
C
NCH3



LA4127
RA3
H
C
NCH3



LA4128
RA34
H
C
NCH3



LA4129
H
H
C
C(CH3)2



LA4130
RB1
H
C
C(CH3)2



LA4131
RB3
H
C
C(CH3)2



LA4132
RB4
H
C
C(CH3)2



LA4133
RB7
H
C
C(CH3)2



LA4134
RB10
H
C
C(CH3)2



LA4135
RA3
H
C
C(CH3)2



LA4136
RA34
H
C
C(CH3)2



LA4137
H
H
C
Si(CH3)2



LA4138
RB1
H
C
Si(CH3)2



LA4139
RB3
H
C
Si(CH3)2



LA4140
RB4
H
C
Si(CH3)2



LA4141
RB7
H
C
Si(CH3)2



LA4142
RB10
H
C
Si(CH3)2



LA4143
RA3
H
C
Si(CH3)2



LA4144
RA34
H
C
Si(CH3)2



LA4145
H
RB1
C
S



LA4146
RB1
RB1
C
S



LA4147
RB3
RB1
C
S



LA4148
RB4
RB1
C
S



LA4149
RB7
RB1
C
S



LA4150
RB10
RB1
C
S



LA4151
RA3
RB1
C
S



LA4152
RA34
RB1
C
S



LA4153
H
RB1
C
O



LA4154
RB1
RB1
C
O



LA4155
RB3
RB1
C
O



LA4156
RB4
RB1
C
O



LA4157
RB7
RB1
C
O



LA4158
RB10
RB1
C
O



LA4159
RA3
RB1
C
O



LA4160
RA34
RB1
C
O



LA4161
H
RB1
C
NCH3



LA4162
RB1
RB1
C
NCH3



LA4163
RB3
RB1
C
NCH3



LA4164
RB4
RB1
C
NCH3



LA4165
RB7
RB1
C
NCH3



LA4166
RB10
RB1
C
NCH3



LA4167
RA3
RB1
C
NCH3



LA4168
RA34
RB1
C
NCH3



LA4169
H
RB1
C
C(CH3)2



LA4170
RB1
RB1
C
C(CH3)2



LA4171
RB3
RB1
C
C(CH3)2



LA4172
RB4
RB1
C
C(CH3)2



LA4173
RB7
RB1
C
C(CH3)2



LA4174
RB10
RB1
C
C(CH3)2



LA4175
RA3
RB1
C
C(CH3)2



LA4176
RA34
RB1
C
C(CH3)2



LA4177
H
RB1
C
Si(CH3)2



LA4178
RB1
RB1
C
Si(CH3)2



LA4179
RB3
RB1
C
Si(CH3)2



LA4180
RB4
RB1
C
Si(CH3)2



LA4181
RB7
RB1
C
Si(CH3)2



LA4182
RB10
RB1
C
Si(CH3)2



LA4183
RA3
RB1
C
Si(CH3)2



LA4184
RA34
RB1
C
Si(CH3)2



LA4185
H
RB6
C
S



LA4186
RB1
RB6
C
S



LA4187
RB3
RB6
C
S



LA4188
RB4
RB6
C
S



LA4189
RB7
RB6
C
S



LA4190
RB10
RB6
C
S



LA4191
RA3
RB6
C
S



LA4192
RA34
RB6
C
S



LA4193
H
RB6
C
O



LA4194
RB1
RB6
C
O



LA4195
RB3
RB6
C
O



LA4196
RB4
RB6
C
O



LA4197
RB7
RB6
C
O



LA4198
RB10
RB6
C
O



LA4199
RA3
RB6
C
O



LA4200
RA34
RB6
C
O



LA4201
H
RB6
C
NCH3



LA4202
RB1
RB6
C
NCH3



LA4203
RB3
RB6
C
NCH3



LA4204
RB4
RB6
C
NCH3



LA4205
RB7
RB6
C
NCH3



LA4206
RB10
RB6
C
NCH3



LA4207
RA3
RB6
C
NCH3



LA4208
RA34
RB6
C
NCH3



LA4209
H
RB6
C
C(CH3)2



LA4210
RB1
RB6
C
C(CH3)2



LA4211
RB3
RB6
C
C(CH3)2



LA4212
RB4
RB6
C
C(CH3)2



LA4213
RB7
RB6
C
C(CH3)2



LA4214
RB10
RB6
C
C(CH3)2



LA4215
RA3
RB6
C
C(CH3)2



LA4216
RA34
RB6
C
C(CH3)2



LA4217
H
RB6
C
Si(CH3)2



LA4218
RB1
RB6
C
Si(CH3)2



LA4219
RB3
RB6
C
Si(CH3)2



LA4220
RB4
RB6
C
Si(CH3)2



LA4221
RB7
RB6
C
Si(CH3)2



LA4222
RB10
RB6
C
Si(CH3)2



LA4223
RA3
RB6
C
Si(CH3)2



LA4224
RA34
RB6
C
Si(CH3)2



LA4225
H
H
N
S



LA4226
RB1
H
N
S



LA4227
RB3
H
N
S



LA4228
RB4
H
N
S



LA4229
RB7
H
N
S



LA4230
RB10
H
N
S



LA4231
RA3
H
N
S



LA4232
RA34
H
N
S



LA4233
H
H
N
O



LA4234
RB1
H
N
O



LA4235
RB3
H
N
O



LA4236
RB4
H
N
O



LA4237
RB7
H
N
O



LA4238
RB10
H
N
O



LA4239
RA3
H
N
O



LA4240
RA34
H
N
O



LA4241
H
H
N
NCH3



LA4242
RB1
H
N
NCH3



LA4243
RB3
H
N
NCH3



LA4244
RB4
H
N
NCH3



LA4245
RB7
H
N
NCH3



LA4246
RB10
H
N
NCH3



LA4247
RA3
H
N
NCH3



LA4248
RA34
H
N
NCH3



LA4249
H
H
N
C(CH3)2



LA4250
RB1
H
N
C(CH3)2



LA4251
RB3
H
N
C(CH3)2



LA4252
RB4
H
N
C(CH3)2



LA4253
RB7
H
N
C(CH3)2



LA4254
RB10
H
N
C(CH3)2



LA4255
RA3
H
N
C(CH3)2



LA4256
RA34
H
N
C(CH3)2



LA4257
H
H
N
Si(CH3)2



LA4258
RB1
H
N
Si(CH3)2



LA4259
RB3
H
N
Si(CH3)2



LA4260
RB4
H
N
Si(CH3)2



LA4261
RB7
H
N
Si(CH3)2



LA4262
RB10
H
N
Si(CH3)2



LA4263
RA3
H
N
Si(CH3)2



LA4264
RA34
H
N
Si(CH3)2



LA4265
H
RB1
N
S



LA4266
RB1
RB1
N
S



LA4267
RB3
RB1
N
S



LA4268
RB4
RB1
N
S



LA4269
RB7
RB1
N
S



LA4270
RB10
RB1
N
S



LA4271
RA3
RB1
N
S



LA4272
RA34
RB1
N
S



LA4273
H
RB1
N
O



LA4274
RB1
RB1
N
O



LA4275
RB3
RB1
N
O



LA4276
RB4
RB1
N
O



LA4277
RB7
RB1
N
O



LA4278
RB10
RB1
N
O



LA4279
RA3
RB1
N
O



LA4280
RA34
RB1
N
O



LA4281
H
RB1
N
NCH3



LA4282
RB1
RB1
N
NCH3



LA4283
RB3
RB1
N
NCH3



LA4284
RB4
RB1
N
NCH3



LA4285
RB7
RB1
N
NCH3



LA4286
RB10
RB1
N
NCH3



LA4287
RA3
RB1
N
NCH3



LA4288
RA34
RB1
N
NCH3



LA4289
H
RB1
N
C(CH3)2



LA4290
RB1
RB1
N
C(CH3)2



LA4291
RB3
RB1
N
C(CH3)2



LA4292
RB4
RB1
N
C(CH3)2



LA4293
RB7
RB1
N
C(CH3)2



LA4294
RB10
RB1
N
C(CH3)2



LA4295
RA3
RB1
N
C(CH3)2



LA4296
RA34
RB1
N
C(CH3)2



LA4297
H
RB1
N
Si(CH3)2



LA4298
RB1
RB1
N
Si(CH3)2



LA4299
RB3
RB1
N
Si(CH3)2



LA4300
RB4
RB1
N
Si(CH3)2



LA4301
RB7
RB1
N
Si(CH3)2



LA4302
RB10
RB1
N
Si(CH3)2



LA4303
RA3
RB1
N
Si(CH3)2



LA4304
RA34
RB1
N
Si(CH3)2



LA4305
H
RB6
N
S



LA4306
RB1
RB6
N
S



LA4307
RB3
RB6
N
S



LA4308
RB4
RB6
N
S



LA4309
RB7
RB6
N
S



LA4310
RB10
RB6
N
S



LA4311
RA3
RB6
N
S



LA4312
RA34
RB6
N
S



LA4313
H
RB6
N
O



LA4314
RB1
RB6
N
O



LA4315
RB3
RB6
N
O



LA4316
RB4
RB6
N
O



LA4317
RB7
RB6
N
O



LA4318
RB10
RB6
N
O



LA4319
RA3
RB6
N
O



LA4320
RA34
RB6
N
O



LA4321
H
RB6
N
NCH3



LA4322
RB1
RB6
N
NCH3



LA4323
RB3
RB6
N
NCH3



LA4324
RB4
RB6
N
NCH3



LA4325
RB7
RB6
N
NCH3



LA4326
RB10
RB6
N
NCH3



LA4327
RA3
RB6
N
NCH3



LA4328
RA34
RB6
N
NCH3



LA4329
H
RB6
N
C(CH3)2



LA4330
RB1
RB6
N
C(CH3)2



LA4331
RB3
RB6
N
C(CH3)2



LA4332
RB4
RB6
N
C(CH3)2



LA4333
RB7
RB6
N
C(CH3)2



LA4334
RB10
RB6
N
C(CH3)2



LA4335
RA3
RB6
N
C(CH3)2



LA4336
RA34
RB6
N
C(CH3)2



LA4337
H
RB6
N
Si(CH3)2



LA4338
RB1
RB6
N
Si(CH3)2



LA4339
RB3
RB6
N
Si(CH3)2



LA4340
RB4
RB6
N
Si(CH3)2



LA4341
RB7
RB6
N
Si(CH3)2



LA4342
RB10
RB6
N
Si(CH3)2



LA4343
RA3
RB6
N
Si(CH3)2



LA4344
RA34
RB6
N
Si(CH3)2










wherein LA4345 through LA4464 have a structure of Formula XXX:





wherein R3, R5, and Y are defined as provided below:

















Ligand
R5
R3
Y









LA4345
H
H
S



LA4346
H
RB1
S



LA4347
H
RB2
S



LA4348
H
RB3
S



LA4349
H
RB4
S



LA4350
H
RB5
S



LA4351
H
RA34
S



LA4352
H
RA52
S



LA4353
H
H
O



LA4354
H
RB1
O



LA4355
H
RB2
O



LA4356
H
RB3
O



LA4357
H
RB4
O



LA4358
H
RB5
O



LA4359
H
RA34
O



LA4360
H
RA52
O



LA4361
H
H
NCH3



LA4362
H
RB1
NCH3



LA4363
H
RB2
NCH3



LA4364
H
RB3
NCH3



LA4365
H
RB4
NCH3



LA4366
H
RB5
NCH3



LA4367
H
RA34
NCH3



LA4368
H
RA52
NCH3



LA4369
H
H
C(CH3)2



LA4370
H
RB1
C(CH3)2



LA4371
H
RB2
C(CH3)2



LA4372
H
RB3
C(CH3)2



LA4373
H
RB4
C(CH3)2



LA4374
H
RB5
C(CH3)2



LA4375
H
RA34
C(CH3)2



LA4376
H
RA52
C(CH3)2



LA4377
H
H
Si(CH3)2



LA4378
H
RB1
Si(CH3)2



LA4379
H
RB2
Si(CH3)2



LA4380
H
RB3
Si(CH3)2



LA4381
H
RB4
Si(CH3)2



LA4382
H
RB5
Si(CH3)2



LA4383
H
RA34
Si(CH3)2



LA4384
H
RA52
Si(CH3)2



LA4385
RB1
H
S



LA4386
RB1
RB1
S



LA4387
RB1
RB2
S



LA4388
RB1
RB3
S



LA4389
RB1
RB4
S



LA4390
RB1
RB5
S



LA4391
RB1
RA34
S



LA4392
RB1
RA52
S



LA4393
RB1
H
O



LA4394
RB1
RB1
O



LA4395
RB1
RB2
O



LA4396
RB1
RB3
O



LA4397
RB1
RB4
O



LA4398
RB1
RB5
O



LA4399
RB1
RA34
O



LA4400
RB1
RA52
O



LA4401
RB1
H
NCH3



LA4402
RB1
RB1
NCH3



LA4403
RB1
RB2
NCH3



LA4404
RB1
RB3
NCH3



LA4405
RB1
RB4
NCH3



LA4406
RB1
RB5
NCH3



LA4407
RB1
RA34
NCH3



LA4408
RB1
RA52
NCH3



LA4409
RB1
H
C(CH3)2



LA4410
RB1
RB1
C(CH3)2



LA4411
RB1
RB2
C(CH3)2



LA4412
RB1
RB3
C(CH3)2



LA4413
RB1
RB4
C(CH3)2



LA4414
RB1
RB5
C(CH3)2



LA4415
RB1
RA34
C(CH3)2



LA4416
RB1
RA52
C(CH3)2



LA4417
RB1
H
Si(CH3)2



LA4418
RB1
RB1
Si(CH3)2



LA4419
RB1
RB2
Si(CH3)2



LA4420
RB1
RB3
Si(CH3)2



LA4421
RB1
RB4
Si(CH3)2



LA4422
RB1
RB5
Si(CH3)2



LA4423
RB1
RA34
Si(CH3)2



LA4424
RB1
RA52
Si(CH3)2



LA4425
RB6
H
S



LA4426
RB6
RB1
S



LA4427
RB6
RB2
S



LA4428
RB6
RB3
S



LA4429
RB6
RB4
S



LA4430
RB6
RB5
S



LA4431
RB6
RA34
S



LA4432
RB6
RA52
S



LA4433
RB6
H
O



LA4434
RB6
RB1
O



LA4435
RB6
RB2
O



LA4436
RB6
RB3
O



LA4437
RB6
RB4
O



LA4438
RB6
RB5
O



LA4439
RB6
RA34
O



LA4440
RB6
RA52
O



LA4441
RB6
H
NCH3



LA4442
RB6
RB1
NCH3



LA4443
RB6
RB2
NCH3



LA4444
RB6
RB3
NCH3



LA4445
RB6
RB4
NCH3



LA4446
RB6
RB5
NCH3



LA4447
RB6
RA34
NCH3



LA4448
RB6
RA52
NCH3



LA4449
RB6
H
C(CH3)2



LA4450
RB6
RB1
C(CH3)2



LA4451
RB6
RB2
C(CH3)2



LA4452
RB6
RB3
C(CH3)2



LA4453
RB6
RB4
C(CH3)2



LA4454
RB6
RB5
C(CH3)2



LA4455
RB6
RA34
C(CH3)2



LA4456
RB6
RA52
C(CH3)2



LA4457
RB6
H
Si(CH3)2



LA4458
RB6
RB1
Si(CH3)2



LA4459
RB6
RB2
Si(CH3)2



LA4460
RB6
RB3
Si(CH3)2



LA4461
RB6
RB4
Si(CH3)2



LA4462
RB6
RB5
Si(CH3)2



LA4463
RB6
RA34
Si(CH3)2



LA4464
RB6
RA52
Si(CH3)2










wherein LA4465 through LA4560 have a structure of Formula XXXI:





wherein R4, R5, Y, and Z are defined as provided below:


















Ligand
R5
R4
Y
Z









LA4465
H
H
S
S



LA4466
H
RB1
S
S



LA4467
H
RB3
S
S



LA4468
H
RB4
S
S



LA4469
H
RB7
S
S



LA4470
H
RB10
S
S



LA4471
H
RA3
S
S



LA4472
H
RA34
S
S



LA4473
H
H
S
O



LA4474
H
RB1
S
O



LA4475
H
RB3
S
O



LA4476
H
RB4
S
O



LA4477
H
RB7
S
O



LA4478
H
RB10
S
O



LA4479
H
RA3
S
O



LA4480
H
RA34
S
O



LA4481
H
H
S
NCH3



LA4482
H
RB1
S
NCH3



LA4483
H
RB3
S
NCH3



LA4484
H
RB4
S
NCH3



LA4485
H
RB7
S
NCH3



LA4486
H
RB10
S
NCH3



LA4487
H
RA3
S
NCH3



LA4488
H
RA34
S
NCH3



LA4489
H
H
O
S



LA4490
H
RB1
O
S



LA4491
H
RB3
O
S



LA4492
H
RB4
O
S



LA4493
H
RB7
O
S



LA4494
H
RB10
O
S



LA4495
H
RA3
O
S



LA4496
H
RA34
O
S



LA4497
H
H
O
O



LA4498
H
RB1
O
O



LA4499
H
RB3
O
O



LA4500
H
RB4
O
O



LA4501
H
RB7
O
O



LA4502
H
RB10
O
O



LA4503
H
RA3
O
O



LA4504
H
RA34
O
O



LA4505
H
H
O
NCH3



LA4506
H
RB1
O
NCH3



LA4507
H
RB3
O
NCH3



LA4508
H
RB4
O
NCH3



LA4509
H
RB7
O
NCH3



LA4510
H
RB10
O
NCH3



LA4511
H
RA3
O
NCH3



LA4512
H
RA34
O
NCH3



LA4513
RB6
H
S
S



LA4514
RB6
RB1
S
S



LA4515
RB6
RB3
S
S



LA4516
RB6
RB4
S
S



LA4517
RB6
RB7
S
S



LA4518
RB6
RB10
S
S



LA4519
RB6
RA3
S
S



LA4520
RB6
RA34
S
S



LA4521
RB6
H
S
O



LA4522
RB6
RB1
S
O



LA4523
RB6
RB3
S
O



LA4524
RB6
RB4
S
O



LA4525
RB6
RB7
S
O



LA4526
RB6
RB10
S
O



LA4527
RB6
RA3
S
O



LA4528
RB6
RA34
S
O



LA4529
RB6
H
S
NCH3



LA4530
RB6
RB1
S
NCH3



LA4531
RB6
RB3
S
NCH3



LA4532
RB6
RB4
S
NCH3



LA4533
RB6
RB7
S
NCH3



LA4534
RB6
RB10
S
NCH3



LA4535
RB6
RA3
S
NCH3



LA4536
RB6
RA34
S
NCH3



LA4537
RB6
H
O
S



LA4538
RB6
RB1
O
S



LA4539
RB6
RB3
O
S



LA4540
RB6
RB4
O
S



LA4541
RB6
RB7
O
S



LA4542
RB6
RB10
O
S



LA4543
RB6
RA3
O
S



LA4544
RB6
RA34
O
S



LA4545
RB6
H
O
O



LA4546
RB6
RB1
O
O



LA4547
RB6
RB3
O
O



LA4548
RB6
RB4
O
O



LA4549
RB6
RB7
O
O



LA4550
RB6
RB10
O
O



LA4551
RB6
RA3
O
O



LA4552
RB6
RA34
O
O



LA4553
RB6
H
O
NCH3



LA4554
RB6
RB1
O
NCH3



LA4555
RB6
RB3
O
NCH3



LA4556
RB6
RB4
O
NCH3



LA4557
RB6
RB7
O
NCH3



LA4558
RB6
RB10
O
NCH3



LA4559
RB6
RA3
O
NCH3



LA4560
RB6
RA34
O
NCH3










wherein LA4561 through LA4780 have a structure of Formula XXXII:





wherein R1, R2, R3, and Y are defined as provided below:


















Ligand
R1
R3
R2
Y









LA4561
H
H
H
O



LA4562
RB1
RB1
H
O



LA4563
RB3
RB3
H
O



LA4564
RB4
RB4
H
O



LA4565
RB7
RB7
H
O



LA4566
RB10
RB10
H
O



LA4567
RA3
RA3
H
O



LA4568
RA34
RA34
H
O



LA4569
RB1
H
H
O



LA4570
RB3
H
H
O



LA4571
RB4
H
H
O



LA4572
RB7
H
H
O



LA4573
RB10
H
H
O



LA4574
RA3
H
H
O



LA4575
RA34
H
H
O



LA4576
H
RB1
H
O



LA4577
H
RB3
H
O



LA4578
H
RB4
H
O



LA4579
H
RB7
H
O



LA4580
H
RB10
H
O



LA4581
H
RA3
H
O



LA4582
H
RA34
H
O



LA4583
H
H
H
S



LA4584
RB1
RB1
H
S



LA4585
RB3
RB3
H
S



LA4586
RB4
RB4
H
S



LA4587
RB7
RB7
H
S



LA4588
RB10
RB10
H
S



LA4589
RA3
RA3
H
S



LA4590
RA34
RA34
H
S



LA4591
RB1
H
H
S



LA4592
RB3
H
H
S



LA4593
RB4
H
H
S



LA4594
RB7
H
H
S



LA4595
RB10
H
H
S



LA4596
RA3
H
H
S



LA4597
RA34
H
H
S



LA4598
H
RB1
H
S



LA4599
H
RB3
H
S



LA4600
H
RB4
H
S



LA4601
H
RB7
H
S



LA4602
H
RB10
H
S



LA4603
H
RA3
H
S



LA4604
H
RA34
H
S



LA4605
H
H
H
NCH3



LA4606
RB1
RB1
H
NCH3



LA4607
RB3
RB3
H
NCH3



LA4608
RB4
RB4
H
NCH3



LA4609
RB7
RB7
H
NCH3



LA4610
RB10
RB10
H
NCH3



LA4611
RA3
RA3
H
NCH3



LA4612
RA34
RA34
H
NCH3



LA4613
RB1
H
H
NCH3



LA4614
RB3
H
H
NCH3



LA4615
RB4
H
H
NCH3



LA4616
RB7
H
H
NCH3



LA4617
RB10
H
H
NCH3



LA4618
RA3
H
H
NCH3



LA4619
RA34
H
H
NCH3



LA4620
H
RB1
H
NCH3



LA4621
H
RB3
H
NCH3



LA4622
H
RB4
H
NCH3



LA4623
H
RB7
H
NCH3



LA4624
H
RB10
H
NCH3



LA4625
H
RA3
H
NCH3



LA4626
H
RA34
H
NCH3



LA4627
H
H
H
C(CH3)2



LA4628
RB1
RB1
H
C(CH3)2



LA4629
RB3
RB3
H
C(CH3)2



LA4630
RB4
RB4
H
C(CH3)2



LA4631
RB7
RB7
H
C(CH3)2



LA4632
RB10
RB10
H
C(CH3)2



LA4633
RA3
RA3
H
C(CH3)2



LA4634
RA34
RA34
H
C(CH3)2



LA4635
RB1
H
H
C(CH3)2



LA4636
RB3
H
H
C(CH3)2



LA4637
RB4
H
H
C(CH3)2



LA4638
RB7
H
H
C(CH3)2



LA4639
RB10
H
H
C(CH3)2



LA4640
RA3
H
H
C(CH3)2



LA4641
RA34
H
H
C(CH3)2



LA4642
H
RB1
H
C(CH3)2



LA4643
H
RB3
H
C(CH3)2



LA4644
H
RB4
H
C(CH3)2



LA4645
H
RB7
H
C(CH3)2



LA4646
H
RB10
H
C(CH3)2



LA4647
H
RA3
H
C(CH3)2



LA4648
H
RA34
H
C(CH3)2



LA4649
H
H
H
Si(CH3)2



LA4650
RB1
RB1
H
Si(CH3)2



LA4651
RB3
RB3
H
Si(CH3)2



LA4652
RB4
RB4
H
Si(CH3)2



LA4653
RB7
RB7
H
Si(CH3)2



LA4654
RB10
RB10
H
Si(CH3)2



LA4655
RA3
RA3
H
Si(CH3)2



LA4656
RA34
RA34
H
Si(CH3)2



LA4657
RB1
H
H
Si(CH3)2



LA4658
RB3
H
H
Si(CH3)2



LA4659
RB4
H
H
Si(CH3)2



LA4660
RB7
H
H
Si(CH3)2



LA4661
RB10
H
H
Si(CH3)2



LA4662
RA3
H
H
Si(CH3)2



LA4663
RA34
H
H
Si(CH3)2



LA4664
H
RB1
H
Si(CH3)2



LA4665
H
RB3
H
Si(CH3)2



LA4666
H
RB4
H
Si(CH3)2



LA4667
H
RB7
H
Si(CH3)2



LA4668
H
RB10
H
Si(CH3)2



LA4669
H
RA3
H
Si(CH3)2



LA4670
H
RA34
H
Si(CH3)2



LA4671
H
H
RB1
O



LA4672
RB1
RB1
RB1
O



LA4673
RB3
RB3
RB1
O



LA4674
RB4
RB4
RB1
O



LA4675
RB7
RB7
RB1
O



LA4676
RB10
RB10
RB1
O



LA4677
RA3
RA3
RB1
O



LA4678
RA34
RA34
RB1
O



LA4679
RB1
H
RB1
O



LA4680
RB3
H
RB1
O



LA4681
RB4
H
RB1
O



LA4682
RB7
H
RB1
O



LA4683
RB10
H
RB1
O



LA4684
RA3
H
RB1
O



LA4685
RA34
H
RB1
O



LA4686
H
RB1
RB1
O



LA4687
H
RB3
RB1
O



LA4688
H
RB4
RB1
O



LA4689
H
RB7
RB1
O



LA4690
H
RB10
RB1
O



LA4691
H
RA3
RB1
O



LA4692
H
RA34
RB1
O



LA4693
H
H
RB1
S



LA4694
RB1
RB1
RB1
S



LA4695
RB3
RB3
RB1
S



LA4696
RB4
RB4
RB1
S



LA4697
RB7
RB7
RB1
S



LA4698
RB10
RB10
RB1
S



LA4699
RA3
RA3
RB1
S



LA4700
RA34
RA34
RB1
S



LA4701
RB1
H
RB1
S



LA4702
RB3
H
RB1
S



LA4703
RB4
H
RB1
S



LA4704
RB7
H
RB1
S



LA4705
RB10
H
RB1
S



LA4706
RA3
H
RB1
S



LA4707
RA34
H
RB1
S



LA4708
H
RB1
RB1
S



LA4709
H
RB3
RB1
S



LA4710
H
RB4
RB1
S



LA4711
H
RB7
RB1
S



LA4712
H
RB10
RB1
S



LA4713
H
RA3
RB1
S



LA4714
H
RA34
RB1
S



LA4715
H
H
RB1
NCH3



LA4716
RB1
RB1
RB1
NCH3



LA4717
RB3
RB3
RB1
NCH3



LA4718
RB4
RB4
RB1
NCH3



LA4719
RB7
RB7
RB1
NCH3



LA4720
RB10
RB10
RB1
NCH3



LA4721
RA3
RA3
RB1
NCH3



LA4722
RA34
RA34
RB1
NCH3



LA4723
RB1
H
RB1
NCH3



LA4724
RB3
H
RB1
NCH3



LA4725
RB4
H
RB1
NCH3



LA4726
RB7
H
RB1
NCH3



LA4727
RB10
H
RB1
NCH3



LA4728
RA3
H
RB1
NCH3



LA4729
RA34
H
RB1
NCH3



LA4730
H
RB1
RB1
NCH3



LA4731
H
RB3
RB1
NCH3



LA4732
H
RB4
RB1
NCH3



LA4733
H
RB7
RB1
NCH3



LA4734
H
RB10
RB1
NCH3



LA4735
H
RA3
RB1
NCH3



LA4736
H
RA34
RB1
NCH3



LA4737
H
H
RB1
C(CH3)2



LA4738
RB1
RB1
RB1
C(CH3)2



LA4739
RB3
RB3
RB1
C(CH3)2



LA4740
RB4
RB4
RB1
C(CH3)2



LA4741
RB7
RB7
RB1
C(CH3)2



LA4742
RB10
RB10
RB1
C(CH3)2



LA4743
RA3
RA3
RB1
C(CH3)2



LA4744
RA34
RA34
RB1
C(CH3)2



LA4745
RB1
H
RB1
C(CH3)2



LA4746
RB3
H
RB1
C(CH3)2



LA4747
RB4
H
RB1
C(CH3)2



LA4748
RB7
H
RB1
C(CH3)2



LA4749
RB10
H
RB1
C(CH3)2



LA4750
RA3
H
RB1
C(CH3)2



LA4751
RA34
H
RB1
C(CH3)2



LA4752
H
RB1
RB1
C(CH3)2



LA4753
H
RB3
RB1
C(CH3)2



LA4754
H
RB4
RB1
C(CH3)2



LA4755
H
RB7
RB1
C(CH3)2



LA4756
H
RB10
RB1
C(CH3)2



LA4757
H
RA3
RB1
C(CH3)2



LA4758
H
RA34
RB1
C(CH3)2



LA4759
H
H
RB1
Si(CH3)2



LA4760
RB1
RB1
RB1
Si(CH3)2



LA4761
RB3
RB3
RB1
Si(CH3)2



LA4762
RB4
RB4
RB1
Si(CH3)2



LA4763
RB7
RB7
RB1
Si(CH3)2



LA4764
RB10
RB10
RB1
Si(CH3)2



LA4765
RA3
RA3
RB1
Si(CH3)2



LA4766
RA34
RA34
RB1
Si(CH3)2



LA4767
RB1
H
RB1
Si(CH3)2



LA4768
RB3
H
RB1
Si(CH3)2



LA4769
RB4
H
RB1
Si(CH3)2



LA4770
RB7
H
RB1
Si(CH3)2



LA4771
RB10
H
RB1
Si(CH3)2



LA4772
RA3
H
RB1
Si(CH3)2



LA4773
RA34
H
RB1
Si(CH3)2



LA4774
H
RB1
RB1
Si(CH3)2



LA4775
H
RB3
RB1
Si(CH3)2



LA4776
H
RB4
RB1
Si(CH3)2



LA4777
H
RB7
RB1
Si(CH3)2



LA4778
H
RB10
RB1
Si(CH3)2



LA4779
H
RA3
RB1
Si(CH3)2



LA4780
H
RA34
RB1
Si(CH3)2,










wherein RB1 to RB23 have the following structures:








and

wherein RA1 to RA52 have the following structures:




















In some embodiments, the compound has a formula of M(LA)x(LB)y(LC)z where LB and LC are each a bidentate ligand; x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M.
In some embodiments, the compound has a formula selected from the group consisting of Ir(LA)3, Ir(LA)(LB)2, Ir(LA)2(LB), Ir(LA)2(LC), and Ir(LA)(LB)(LC); and ligands LA, LB, and LC are different from each other.
In some embodiments, the compound has a formula of Pt(LA)(LB), where LA and LB can be the same or different. In some such embodiments, LA and LB are connected to form a tetradentate ligand. In some such embodiments, LA and LB are connected at two places to form a macrocyclic tetradentate ligand.
In some embodiments where the compound has the formula M(LA)x(LB)y(LC)z, ligands LB and LC are each independently selected from the group consisting of










where:

    
    
        each Y1 to Y13 is independently selected from the group consisting of carbon and nitrogen;
        X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO2, CR1R2, SiR1R2, and GeR1R2;
        R1 and R2 are optionally fused or joined to form a ring;
        each Ra, Rb, Rc, and Rd may represent from mono substitution to the possible maximum number of substitution, or no substitution;
        R1, R2, Ra, Rb, Rc, and Rd are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
        any two adjacent substituents of Ra, Rb, Rc, and Rd are optionally fused or joined to form a ring or form a multidentate ligand.
    
    


In some such embodiments where the compound has the formula M(LA)x(LB)y(LC)z, ligands LB and LC are each independently selected from the group consisting of













In some embodiments, the compound is Compound Ax having the formula Ir(LAi)3; where x=i; i is an integer from 1 to 4780, and LA1 to LA4780 are defined as set forth above.
In some embodiments, the compound is Compound By having the formula Ir(LA1)(LBk)2; where y=468i+k−468; i is an integer from 1 to 4780, and k is an integer from 1 to 468; and ligand LBk has the following structures








































































































































































































































































































In some embodiments, the compound is the Compound Cz having the formula Ir(LAi)2(LCj); where z=1260i+j−1260; i is an integer from 1 to 4780; j is an integer from 1 to 1260; and ligand LCi is selected from the group consisting of the following structures:
LC1 through LC1260 are based on a structure of Formula X,




in which R1, R2, and R3 are defined as:

















Ligand
R1
R2
R3









LC1
RD1
RD1
H



LC2
RD2
RD2
H



LC3
RD3
RD3
H



LC4
RD4
RD4
H



LC5
RD5
RD5
H



LC6
RD6
RD6
H



LC7
RD7
RD7
H



LC8
RD8
RD8
H



LC9
RD9
RD9
H



LC10
RD10
RD10
H



LC11
RD11
RD11
H



LC12
RD12
RD12
H



LC13
RD13
RD13
H



LC14
RD14
RD14
H



LC15
RD15
RD15
H



LC16
RD16
RD16
H



LC17
RD17
RD17
H



LC18
RD18
RD18
H



LC19
RD19
RD19
H



LC20
RD20
RD20
H



LC21
RD21
RD21
H



LC22
RD22
RD22
H



LC23
RD23
RD23
H



LC24
RD24
RD24
H



LC25
RD25
RD25
H



LC26
RD26
RD26
H



LC27
RD27
RD27
H



LC28
RD28
RD28
H



LC29
RD29
RD29
H



LC30
RD30
RD30
H



LC31
RD31
RD31
H



LC32
RD32
RD32
H



LC33
RD33
RD33
H



LC34
RD34
RD34
H



LC35
RD35
RD35
H



LC36
RD40
RD40
H



LC37
RD41
RD41
H



LC38
RD42
RD42
H



LC39
RD64
RD64
H



LC40
RD66
RD66
H



LC41
RD68
RD68
H



LC42
RD76
RD76
H



LC43
RD1
RD2
H



LC44
RD1
RD3
H



LC45
RD1
RD4
H



LC46
RD1
RD5
H



LC47
RD1
RD6
H



LC48
RD1
RD7
H



LC49
RD1
RD8
H



LC50
RD1
RD9
H



LC51
RD1
RD10
H



LC52
RD1
RD11
H



LC53
RD1
RD12
H



LC54
RD1
RD13
H



LC55
RD1
RD14
H



LC56
RD1
RD15
H



LC57
RD1
RD16
H



LC58
RD1
RD17
H



LC59
RD1
RD18
H



LC60
RD1
RD19
H



LC61
RD1
RD20
H



LC62
RD1
RD21
H



LC63
RD1
RD22
H



LC64
RD1
RD23
H



LC65
RD1
RD24
H



LC66
RD1
RD25
H



LC67
RD1
RD26
H



LC68
RD1
RD27
H



LC69
RD1
RD28
H



LC70
RD1
RD29
H



LC71
RD1
RD30
H



LC72
RD1
RD31
H



LC73
RD1
RD32
H



LC74
RD1
RD33
H



LC75
RD1
RD34
H



LC76
RD1
RD35
H



LC77
RD1
RD40
H



LC78
RD1
RD41
H



LC79
RD1
RD42
H



LC80
RD1
RD64
H



LC81
RD1
RD66
H



LC82
RD1
RD68
H



LC83
RD1
RD76
H



LC84
RD2
RD1
H



LC85
RD2
RD3
H



LC86
RD2
RD4
H



LC87
RD2
RD5
H



LC88
RD2
RD6
H



LC89
RD2
RD7
H



LC90
RD2
RD8
H



LC91
RD2
RD9
H



LC92
RD2
RD10
H



LC93
RD2
RD11
H



LC94
RD2
RD12
H



LC95
RD2
RD13
H



LC96
RD2
RD14
H



LC97
RD2
RD15
H



LC98
RD2
RD16
H



LC99
RD2
RD17
H



LC100
RD2
RD18
H



LC101
RD2
RD19
H



LC102
RD2
RD20
H



LC103
RD2
RD21
H



LC104
RD2
RD22
H



LC105
RD2
RD23
H



LC106
RD2
RD24
H



LC107
RD2
RD25
H



LC108
RD2
RD26
H



LC109
RD2
RD27
H



LC110
RD2
RD28
H



LC111
RD2
RD29
H



LC112
RD2
RD30
H



LC113
RD2
RD31
H



LC114
RD2
RD32
H



LC115
RD2
RD33
H



LC116
RD2
RD34
H



LC117
RD2
RD35
H



LC118
RD2
RD40
H



LC119
RD2
RD41
H



LC120
RD2
RD42
H



LC121
RD2
RD64
H



LC122
RD2
RD66
H



LC123
RD2
RD68
H



LC124
RD2
RD76
H



LC125
RD3
RD4
H



LC126
RD3
RD5
H



LC127
RD3
RD6
H



LC128
RD3
RD7
H



LC129
RD3
RD8
H



LC130
RD3
RD9
H



LC131
RD3
RD10
H



LC132
RD3
RD11
H



LC133
RD3
RD12
H



LC134
RD3
RD13
H



LC135
RD3
RD14
H



LC136
RD3
RD15
H



LC137
RD3
RD16
H



LC138
RD3
RD17
H



LC139
RD3
RD18
H



LC140
RD3
RD19
H



LC141
RD3
RD20
H



LC142
RD3
RD21
H



LC143
RD3
RD22
H



LC144
RD3
RD23
H



LC145
RD3
RD24
H



LC146
RD3
RD25
H



LC147
RD3
RD26
H



LC148
RD3
RD27
H



LC149
RD3
RD28
H



LC150
RD3
RD29
H



LC151
RD3
RD30
H



LC152
RD3
RD31
H



LC153
RD3
RD32
H



LC154
RD3
RD33
H



LC155
RD3
RD34
H



LC156
RD3
RD35
H



LC157
RD3
RD40
H



LC158
RD3
RD41
H



LC159
RD3
RD42
H



LC160
RD3
RD64
H



LC161
RD3
RD66
H



LC162
RD3
RD68
H



LC163
RD3
RD76
H



LC164
RD4
RD5
H



LC165
RD4
RD6
H



LC166
RD4
RD7
H



LC167
RD4
RD8
H



LC168
RD4
RD9
H



LC169
RD4
RD10
H



LC170
RD4
RD11
H



LC171
RD4
RD12
H



LC172
RD4
RD13
H



LC173
RD4
RD14
H



LC174
RD4
RD15
H



LC175
RD4
RD16
H



LD176
RD4
RD17
H



LC177
RD4
RD18
H



LC178
RD4
RD19
H



LC179
RD4
RD20
H



LC180
RD4
RD21
H



LC181
RD4
RD22
H



LC182
RD4
RD23
H



LC183
RD4
RD24
H



LC184
RD4
RD25
H



LC185
RD4
RD26
H



LC186
RD4
RD27
H



LC187
RD4
RD28
H



LC188
RD4
RD29
H



LC189
RD4
RD30
H



LC190
RD4
RD31
H



LC191
RD4
RD32
H



LC192
RD4
RD33
H



LC193
RD4
RD34
H



LC194
RD4
RD35
H



LC195
RD4
RD40
H



LC196
RD4
RD41
H



LC197
RD4
RD42
H



LC198
RD4
RD64
H



LC199
RD4
RD66
H



LC200
RD4
RD68
H



LC201
RD4
RD76
H



LC202
RD4
RD1
H



LC203
RD7
RD5
H



LC204
RD7
RD6
H



LC205
RD7
RD8
H



LC206
RD7
RD9
H



LC207
RD7
RD10
H



LC208
RD7
RD11
H



LC209
RD7
RD12
H



LC210
RD7
RD13
H



LC211
RD7
RD14
H



LC212
RD7
RD15
H



LC213
RD7
RD16
H



LC214
RD7
RD17
H



LC215
RD7
RD18
H



LC216
RD7
RD19
H



LC217
RD7
RD20
H



LC218
RD7
RD21
H



LC219
RD7
RD22
H



LC220
RD7
RD23
H



LC221
RD7
RD24
H



LC222
RD7
RD25
H



LC223
RD7
RD26
H



LC224
RD7
RD27
H



LC225
RD7
RD28
H



LC226
RD7
RD29
H



LC227
RD7
RD30
H



LC228
RD7
RD31
H



LC229
RD7
RD32
H



LC230
RD7
RD33
H



LC231
RD7
RD34
H



LC232
RD7
RD35
H



LC233
RD7
RD40
H



LC234
RD7
RD41
H



LC235
RD7
RD42
H



LC236
RD7
RD64
H



LC237
RD7
RD66
H



LC238
RD7
RD68
H



LC239
RD7
RD76
H



LC240
RD8
RD5
H



LC241
RD8
RD6
H



LC242
RD8
RD9
H



LC243
RD8
RD10
H



LC244
RD8
RD11
H



LC245
RD8
RD12
H



LC246
RD8
RD13
H



LC247
RD8
RD14
H



LC248
RD8
RD15
H



LC249
RD8
RD16
H



LC250
RD8
RD17
H



LC251
RD8
RD18
H



LC252
RD8
RD19
H



LC253
RD8
RD20
H



LC254
RD8
RD21
H



LC255
RD8
RD22
H



LC256
RD8
RD23
H



LC257
RD8
RD24
H



LC258
RD8
RD25
H



LC259
RD8
RD26
H



LC260
RD8
RD27
H



LC261
RD8
RD28
H



LC262
RD8
RD29
H



LC263
RD8
RD30
H



LC264
RD8
RD31
H



LC265
RD8
RD32
H



LC266
RD8
RD33
H



LC267
RD8
RD34
H



LC268
RD8
RD35
H



LC269
RD8
RD40
H



LC270
RD8
RD41
H



LC271
RD8
RD42
H



LC272
RD8
RD64
H



LC273
RD8
RD66
H



LC274
RD8
RD68
H



LC275
RD8
RD76
H



LC276
RD11
RD5
H



LC277
RD11
RD6
H



LC278
RD11
RD9
H



LC279
RD11
RD10
H



LC280
RD11
RD12
H



LC281
RD11
RD13
H



LC282
RD11
RD14
H



LC283
RD11
RD15
H



LC284
RD11
RD16
H



LC285
RD11
RD17
H



LC286
RD11
RD18
H



LC287
RD11
RD19
H



LC288
RD11
RD20
H



LC289
RD11
RD21
H



LC290
RD11
RD22
H



LC291
RD11
RD23
H



LC292
RD11
RD24
H



LC293
RD11
RD25
H



LC294
RD11
RD26
H



LC295
RD11
RD27
H



LC296
RD11
RD28
H



LC297
RD11
RD29
H



LC298
RD11
RD30
H



LC299
RD11
RD31
H



LC300
RD11
RD32
H



LC301
RD11
RD33
H



LC302
RD11
RD34
H



LC303
RD11
RD35
H



LC304
RD11
RD40
H



LC305
RD11
RD41
H



LC306
RD11
RD42
H



LC307
RD11
RD64
H



LC308
RD11
RD66
H



LC309
RD11
RD68
H



LC310
RD11
RD76
H



LC311
RD13
RD5
H



LC312
RD13
RD6
H



LC313
RD13
RD9
H



LC314
RD13
RD10
H



LC315
RD13
RD12
H



LC316
RD13
RD14
H



LC317
RD13
RD15
H



LC318
RD13
RD16
H



LC319
RD13
RD17
H



LC320
RD13
RD18
H



LC321
RD13
RD19
H



LC322
RD13
RD20
H



LC323
RD13
RD21
H



LC324
RD13
RD22
H



LC325
RD13
RD23
H



LC326
RD13
RD24
H



LC327
RD13
RD25
H



LC328
RD13
RD26
H



LC329
RD13
RD27
H



LC330
RD13
RD28
H



LC331
RD13
RD29
H



LC332
RD13
RD30
H



LC333
RD13
RD31
H



LC334
RD13
RD32
H



LC335
RD13
RD33
H



LC336
RD13
RD34
H



LC337
RD13
RD35
H



LC338
RD13
RD40
H



LC339
RD13
RD41
H



LC340
RD13
RD42
H



LC341
RD13
RD64
H



LC342
RD13
RD66
H



LC343
RD13
RD68
H



LC344
RD13
RD76
H



LC345
RD14
RD5
H



LC346
RD14
RD6
H



LC347
RD14
RD9
H



LC348
RD14
RD10
H



LC349
RD14
RD12
H



LC350
RD14
RD15
H



LC351
RD14
RD16
H



LC352
RD14
RD17
H



LC353
RD14
RD18
H



LC354
RD14
RD19
H



LC355
RD14
RD20
H



LC356
RD14
RD21
H



LC357
RD14
RD22
H



LC358
RD14
RD23
H



LC359
RD14
RD24
H



LC360
RD14
RD25
H



LC361
RD14
RD26
H



LC362
RD14
RD27
H



LC363
RD14
RD28
H



LC364
RD14
RD29
H



LC365
RD14
RD30
H



LC366
RD14
RD31
H



LC367
RD14
RD32
H



LC368
RD14
RD33
H



LC369
RD14
RD34
H



LC370
RD14
RD35
H



LC371
RD14
RD40
H



LC372
RD14
RD41
H



LC373
RD14
RD42
H



LC374
RD14
RD64
H



LC375
RD14
RD66
H



LC376
RD14
RD68
H



LC377
RD14
RD76
H



LC378
RD22
RD5
H



LC379
RD22
RD6
H



LC380
RD22
RD9
H



LC381
RD22
RD10
H



LC382
RD22
RD12
H



LC383
RD22
RD15
H



LC384
RD22
RD16
H



LC385
RD22
RD17
H



LC386
RD22
RD18
H



LC387
RD22
RD19
H



LC388
RD22
RD20
H



LC389
RD22
RD21
H



LC390
RD22
RD23
H



LC391
RD22
RD24
H



LC392
RD22
RD25
H



LC393
RD22
RD26
H



LC394
RD22
RD27
H



LC395
RD22
RD28
H



LC396
RD22
RD29
H



LC397
RD22
RD30
H



LC398
RD22
RD31
H



LC399
RD22
RD32
H



LC400
RD22
RD33
H



LC401
RD22
RD34
H



LC402
RD22
RD35
H



LC403
RD22
RD40
H



LC404
RD22
RD41
H



LC405
RD22
RD42
H



LC406
RD22
RD64
H



LC407
RD22
RD66
H



LC408
RD22
RD68
H



LC409
RD22
RD76
H



LC410
RD26
RD5
H



LC411
RD26
RD6
H



LC412
RD26
RD9
H



LC413
RD26
RD10
H



LC414
RD26
RD12
H



LC415
RD26
RD15
H



LC416
RD26
RD16
H



LC417
RD26
RD17
H



LC418
RD26
RD18
H



LC419
RD26
RD19
H



LC420
RD26
RD20
H



LC421
RD26
RD21
H



LC422
RD26
RD23
H



LC423
RD26
RD24
H



LC424
RD26
RD25
H



LC425
RD26
RD27
H



LC426
RD26
RD28
H



LC427
RD26
RD29
H



LC428
RD26
RD30
H



LC429
RD26
RD31
H



LC430
RD26
RD32
H



LC431
RD26
RD33
H



LC432
RD26
RD34
H



LC433
RD26
RD35
H



LC434
RD26
RD40
H



LC435
RD26
RD41
H



LC436
RD26
RD42
H



LC437
RD26
RD64
H



LC438
RD26
RD66
H



LC439
RD26
RD68
H



LC440
RD26
RD76
H



LC441
RD35
RD5
H



LC442
RD35
RD6
H



LC443
RD35
RD9
H



LC444
RD35
RD10
H



LC445
RD35
RD12
H



LC446
RD35
RD15
H



LC447
RD35
RD16
H



LC448
RD35
RD17
H



LC449
RD35
RD18
H



LC450
RD35
RD19
H



LC451
RD35
RD20
H



LC452
RD35
RD21
H



LC453
RD35
RD23
H



LC454
RD35
RD24
H



LC455
RD35
RD25
H



LC456
RD35
RD27
H



LC457
RD35
RD28
H



LC458
RD35
RD29
H



LC459
RD35
RD30
H



LC460
RD35
RD31
H



LC461
RD35
RD32
H



LC462
RD35
RD33
H



LC463
RD35
RD34
H



LC464
RD35
RD40
H



LC465
RD35
RD41
H



LC466
RD35
RD42
H



LC467
RD35
RD64
H



LC468
RD35
RD66
H



LC469
RD35
RD68
H



LC470
RD35
RD76
H



LC471
RD40
RD5
H



LC472
RD40
RD6
H



LC473
RD40
RD9
H



LC474
RD40
RD10
H



LC475
RD40
RD12
H



LC476
RD40
RD15
H



LC477
RD40
RD16
H



LC478
RD40
RD17
H



LC479
RD40
RD18
H



LC480
RD40
RD19
H



LC481
RD40
RD20
H



LC482
RD40
RD21
H



LC483
RD40
RD23
H



LC484
RD40
RD24
H



LC485
RD40
RD25
H



LC486
RD40
RD27
H



LC487
RD40
RD28
H



LC488
RD40
RD29
H



LC489
RD40
RD30
H



LC490
RD40
RD31
H



LC491
RD40
RD32
H



LC492
RD40
RD33
H



LC493
RD40
RD34
H



LC494
RD40
RD41
H



LC495
RD40
RD42
H



LC496
RD40
RD64
H



LC497
RD40
RD66
H



LC498
RD40
RD68
H



LC499
RD40
RD76
H



LC500
RD41
RD5
H



LC501
RD41
RD6
H



LC502
RD41
RD9
H



LC503
RD41
RD10
H



LC504
RD41
RD12
H



LC505
RD41
RD15
H



LC506
RD41
RD16
H



LC507
RD41
RD17
H



LC508
RD41
RD18
H



LC509
RD41
RD19
H



LC510
RD41
RD20
H



LC511
RD41
RD21
H



LC512
RD41
RD23
H



LC513
RD41
RD24
H



LC514
RD41
RD25
H



LC515
RD41
RD27
H



LC516
RD41
RD28
H



LC517
RD41
RD29
H



LC518
RD41
RD30
H



LC519
RD41
RD31
H



LC520
RD41
RD32
H



LC521
RD41
RD33
H



LC522
RD41
RD34
H



LC523
RD41
RD42
H



LC524
RD41
RD64
H



LC525
RD41
RD66
H



LC526
RD41
RD68
H



LC527
RD41
RD76
H



LC528
RD64
RD5
H



LC529
RD64
RD6
H



LC530
RD64
RD9
H



LC531
RD64
RD10
H



LC532
RD64
RD12
H



LC533
RD64
RD15
H



LC534
RD64
RD16
H



LC535
RD64
RD17
H



LC536
RD64
RD18
H



LC537
RD64
RD19
H



LC538
RD64
RD20
H



LC539
RD64
RD21
H



LC540
RD64
RD23
H



LC541
RD64
RD24
H



LC542
RD64
RD25
H



LC543
RD64
RD27
H



LC544
RD64
RD28
H



LC545
RD64
RD29
H



LC546
RD64
RD30
H



LC547
RD64
RD31
H



LC548
RD64
RD32
H



LC549
RD64
RD33
H



LC550
RD54
RD34
H



LC551
RD64
RD42
H



LC552
RD64
RD64
H



LC553
RD64
RD66
H



LC554
RD64
RD68
H



LC555
RD64
RD76
H



LC556
RD66
RD5
H



LC557
RD66
RD6
H



LC558
RD66
RD9
H



LC559
RD66
RD10
H



LC560
RD66
RD12
H



LC561
RD66
RD15
H



LC562
RD66
RD16
H



LC563
RD66
RD17
H



LC564
RD66
RD18
H



LC565
RD66
RD19
H



LC566
RD66
RD20
H



LC567
RD66
RD21
H



LC568
RD66
RD23
H



LC569
RD66
RD24
H



LC570
RD66
RD25
H



LC571
RD66
RD27
H



LC572
RD66
RD28
H



LC573
RD66
RD29
H



LC574
RD66
RD30
H



LC575
RD66
RD31
H



LC576
RD66
RD32
H



LC577
RD66
RD33
H



LC578
RD66
RD34
H



LC579
RD66
RD42
H



LC580
RD66
RD68
H



LC581
RD66
RD76
H



LC582
RD68
RD5
H



LC583
RD68
RD6
H



LC584
RD68
RD9
H



LC585
RD68
RD10
H



LC586
RD68
RD12
H



LC587
RD68
RD15
H



LC588
RD68
RD16
H



LC589
RD68
RD17
H



LC590
RD68
RD18
H



LC591
RD68
RD19
H



LC592
RD68
RD20
H



LC593
RD68
RD21
H



LC594
RD68
RD23
H



LC595
RD68
RD24
H



LC596
RD68
RD25
H



LC597
RD68
RD27
H



LC598
RD68
RD28
H



LC599
RD68
RD29
H



LC600
RD68
RD30
H



LC601
RD68
RD31
H



LC602
RD68
RD32
H



LC603
RD68
RD33
H



LC604
RD68
RD34
H



LC605
RD68
RD42
H



LC606
RD68
RD76
H



LC607
RD76
RD5
H



LC608
RD76
RD6
H



LC609
RD76
RD9
H



LC610
RD76
RD10
H



LC611
RD76
RD12
H



LC612
RD76
RD15
H



LC613
RD76
RD16
H



LC614
RD76
RD17
H



LC615
RD76
RD18
H



LC616
RD76
RD19
H



LC617
RD76
RD20
H



LC618
RD76
RD21
H



LC619
RD76
RD23
H



LC620
RD76
RD24
H



LC621
RD76
RD25
H



LC622
RD76
RD27
H



LC623
RD76
RD28
H



LC624
RD76
RD29
H



LC625
RD76
RD30
H



LC626
RD76
RD31
H



LC627
RD76
RD32
H



LC628
RD76
RD33
H



LC629
RD76
RD34
H



LC630
RD76
RD42
H



LC631
RD1
RD1
RD1



LC632
RD2
RD2
RD1



LC633
RD3
RD3
RD1



LC634
RD4
RD4
RD1



LC635
RD5
RD5
RD1



LC636
RD6
RD6
RD1



LC637
RD7
RD7
RD1



LC638
RD8
RD8
RD1



LC639
RD9
RD9
RD1



LC640
RD10
RD10
RD1



LC641
RD11
RD11
RD1



LC642
RD12
RD12
RD1



LC643
RD13
RD13
RD1



LC644
RD14
RD14
RD1



LC645
RD15
RD15
RD1



LC646
RD16
RD16
RD1



LC647
RD17
RD17
RD1



LC648
RD18
RD18
RD1



LC649
RD19
RD19
RD1



LC650
RD20
RD20
RD1



LC651
RD21
RD21
RD1



LC652
RD22
RD22
RD1



LC653
RD23
RD23
RD1



LC654
RD24
RD24
RD1



LC655
RD25
RD25
RD1



LC656
RD26
RD26
RD1



LC657
RD27
RD27
RD1



LC658
RD28
RD28
RD1



LC659
RD29
RD29
RD1



LC660
RD30
RD30
RD1



LC661
RD31
RD31
RD1



LC662
RD32
RD32
RD1



LC663
RD33
RD33
RD1



LC664
RD34
RD34
RD1



LC665
RD35
RD35
RD1



LC666
RD40
RD40
RD1



LC667
RD41
RD41
RD1



LC668
RD42
RD42
RD1



LC669
RD64
RD64
RD1



LC670
RD66
RD66
RD1



LC671
RD68
RD68
RD1



LC672
RD76
RD76
RD1



LC673
RD1
RD2
RD1



LC674
RD1
RD3
RD1



LC675
RD1
RD4
RD1



LC676
RD1
RD5
RD1



LC677
RD1
RD6
RD1



LC678
RD1
RD7
RD1



LC679
RD1
RD8
RD1



LC680
RD1
RD9
RD1



LC681
RD1
RD10
RD1



LC682
RD1
RD11
RD1



LC683
RD1
RD12
RD1



LC684
RD1
RD13
RD1



LC685
RD1
RD14
RD1



LC686
RD1
RD15
RD1



LC687
RD1
RD16
RD1



LC688
RD1
RD17
RD1



LC689
RD1
RD18
RD1



LC690
RD1
RD19
RD1



LC691
RD1
RD20
RD1



LC692
RD1
RD21
RD1



LC693
RD1
RD22
RD1



LC694
RD1
RD23
RD1



LC695
RD1
RD24
RD1



LC696
RD1
RD25
RD1



LC697
RD1
RD26
RD1



LC698
RD1
RD27
RD1



LC699
RD1
RD28
RD1



L1700
RD1
RD29
RD1



LC701
RD1
RD30
RD1



LC702
RD1
RD31
RD1



LC703
RD1
RD32
RD1



LC704
RD1
RD33
RD1



LC705
RD1
RD34
RD1



LC706
RD1
RD35
RD1



LC707
RD1
RD40
RD1



LC708
RD1
RD41
RD1



LC709
RD1
RD42
RD1



LC710
RD1
RD64
RD1



LC711
RD1
RD66
RD1



LC712
RD1
RD68
RD1



LC713
RD1
RD76
RD1



LC714
RD2
RD1
RD1



LC715
RD2
RD3
RD1



LC716
RD2
RD4
RD1



LC717
RD2
RD5
RD1



LC718
RD2
RD6
RD1



LC719
RD2
RD7
RD1



LC720
RD2
RD8
RD1



LC721
RD2
RD9
RD1



LC722
RD2
RD10
RD1



LC723
RD2
RD11
RD1



LC724
RD2
RD12
RD1



LC725
RD2
RD13
RD1



LC726
RD2
RD14
RD1



LC727
RD2
RD15
RD1



LC728
RD2
RD16
RD1



LC729
RD2
RD17
RD1



LC730
RD2
RD18
RD1



LC731
RD2
RD19
RD1



LC732
RD2
RD20
RD1



LC733
RD2
RD21
RD1



LC734
RD2
RD22
RD1



LC735
RD2
RD23
RD1



LC736
RD2
RD24
RD1



LC737
RD2
RD25
RD1



LC738
RD2
RD26
RD1



LC739
RD2
RD27
RD1



LC740
RD2
RD28
RD1



LC741
RD2
RD29
RD1



LC742
RD2
RD30
RD1



LC743
RD2
RD31
RD1



LC744
RD2
RD32
RD1



LC745
RD2
RD33
RD1



LC746
RD2
RD34
RD1



LC747
RD2
RD35
RD1



LC748
RD2
RD40
RD1



LC749
RD2
RD41
RD1



LC750
RD2
RD42
RD1



LC751
RD2
RD64
RD1



LC752
RD2
RD66
RD1



LC753
RD2
RD68
RD1



LC754
RD2
RD76
RD1



LC755
RD3
RD4
RD1



LC756
RD3
RD5
RD1



LC757
RD3
RD6
RD1



LC758
RD3
RD7
RD1



LC759
RD3
RD8
RD1



LC760
RD3
RD9
RD1



LC761
RD3
RD10
RD1



LC762
RD3
RD11
RD1



LC763
RD3
RD12
RD1



LC764
RD3
RD13
RD1



LC765
RD3
RD14
RD1



LC766
RD3
RD15
RD1



LC767
RD3
RD16
RD1



LC768
RD3
RD17
RD1



LC769
RD3
RD18
RD1



LC770
RD3
RD19
RD1



LC771
RD3
RD20
RD1



LC772
RD3
RD21
RD1



LC773
RD3
RD22
RD1



LC774
RD3
RD23
RD1



LC775
RD3
RD24
RD1



LC776
RD3
RD25
RD1



LC777
RD3
RD26
RD1



LC778
RD3
RD27
RD1



LC779
RD3
RD28
RD1



LC780
RD3
RD29
RD1



LC781
RD3
RD30
RD1



LC782
RD3
RD31
RD1



LC783
RD3
RD32
RD1



LC784
RD3
RD33
RD1



LC785
RD3
RD34
RD1



LC786
RD3
RD35
RD1



LC787
RD3
RD40
RD1



LC788
RD3
RD41
RD1



LC789
RD3
RD42
RD1



LC790
RD3
RD64
RD1



LC791
RD3
RD66
RD1



LC792
RD3
RD68
RD1



LC793
RD3
RD76
RD1



LC794
RD4
RD5
RD1



LC795
RD4
RD6
RD1



LC796
RD4
RD7
RD1



LC797
RD4
RD8
RD1



LC798
RD4
RD9
RD1



LC799
RD4
RD10
RD1



LC800
RD4
RD11
RD1



LC801
RD4
RD12
RD1



LC802
RD4
RD13
RD1



LC803
RD4
RD14
RD1



LC804
RD4
RD15
RD1



LC805
RD4
RD16
RD1



LC806
RD4
RD17
RD1



LC807
RD4
RD18
RD1



LC808
RD4
RD19
RD1



LC809
RD4
RD20
RD1



LC810
RD4
RD21
RD1



LC811
RD4
RD22
RD1



LC812
RD4
RD23
RD1



LC813
RD4
RD24
RD1



LC814
RD4
RD25
RD1



LC815
RD4
RD26
RD1



LC816
RD4
RD27
RD1



LC817
RD4
RD28
RD1



LC818
RD4
RD29
RD1



LC819
RD4
RD30
RD1



LC820
RD4
RD31
RD1



LC821
RD4
RD32
RD1



LC822
RD4
RD33
RD1



LC823
RD4
RD34
RD1



LC824
RD4
RD35
RD1



LC825
RD4
RD40
RD1



LC826
RD4
RD41
RD1



LC827
RD4
RD42
RD1



LC828
RD4
RD64
RD1



LC829
RD4
RD66
RD1



LC830
RD4
RD68
RD1



LC831
RD4
RD76
RD1



LC832
RD4
RD1
RD1



LC833
RD7
RD5
RD1



LC834
RD7
RD6
RD1



LC835
RD7
RD8
RD1



LC836
RD7
RD9
RD1



LC837
RD7
RD10
RD1



LC838
RD7
RD11
RD1



LC839
RD7
RD12
RD1



LC840
RD7
RD13
RD1



LC841
RD7
RD14
RD1



LC842
RD7
RD15
RD1



LC843
RD7
RD16
RD1



LC844
RD7
RD17
RD1



LC845
RD7
RD18
RD1



LC846
RD7
RD19
RD1



LC847
RD7
RD20
RD1



LC848
RD7
RD21
RD1



LC849
RD7
RD22
RD1



LC850
RD7
RD23
RD1



LC851
RD7
RD24
RD1



LC852
RD7
RD25
RD1



LC853
RD7
RD26
RD1



LC854
RD7
RD27
RD1



LC855
RD7
RD28
RD1



LC856
RD7
RD29
RD1



LC857
RD7
RD30
RD1



LC858
RD7
RD31
RD1



LC859
RD7
RD32
RD1



LC860
RD7
RD33
RD1



LC861
RD7
RD34
RD1



LC862
RD7
RD35
RD1



LC863
RD7
RD40
RD1



LC864
RD7
RD41
RD1



LC865
RD7
RD42
RD1



LC866
RD7
RD64
RD1



LC867
RD7
RD66
RD1



LC868
RD7
RD68
RD1



LC869
RD7
RD76
RD1



LC870
RD8
RD5
RD1



LC871
RD8
RD6
RD1



LC872
RD8
RD9
RD1



LC873
RD8
RD10
RD1



LC874
RD8
RD11
RD1



LC875
RD8
RD12
RD1



LC876
RD8
RD13
RD1



LC877
RD8
RD14
RD1



LC878
RD8
RD15
RD1



LC879
RD8
RD16
RD1



LC880
RD8
RD17
RD1



LC881
RD8
RD18
RD1



LC882
RD8
RD19
RD1



LC883
RD8
RD20
RD1



LC884
RD8
RD21
RD1



LC885
RD8
RD22
RD1



LC886
RD8
RD23
RD1



LC887
RD8
RD24
RD1



LC888
RD8
RD25
RD1



LC889
RD8
RD26
RD1



LC890
RD8
RD27
RD1



LC891
RD8
RD28
RD1



LC892
RD8
RD29
RD1



LC893
RD8
RD30
RD1



LC894
RD8
RD31
RD1



LC895
RD8
RD32
RD1



LC896
RD8
RD33
RD1



LC897
RD8
RD34
RD1



LC898
RD8
RD35
RD1



LC899
RD8
RD40
RD1



LC900
RD8
RD41
RD1



LC901
RD8
RD42
RD1



LC902
RD8
RD64
RD1



LC903
RD8
RD66
RD1



LC904
RD8
RD68
RD1



LC905
RD8
RD76
RD1



LC906
RD11
RD5
RD1



LC907
RD11
RD6
RD1



LC908
RD11
RD9
RD1



LC909
RD11
RD10
RD1



LC910
RD11
RD12
RD1



LC911
RD11
RD13
RD1



LC912
RD11
RD14
RD1



LC913
RD11
RD15
RD1



LC914
RD11
RD16
RD1



LC915
RD11
RD17
RD1



LC916
RD11
RD18
RD1



LC917
RD11
RD19
RD1



LC918
RD11
RD20
RD1



LC919
RD11
RD21
RD1



LC920
RD11
RD22
RD1



LC921
RD11
RD23
RD1



LC922
RD11
RD24
RD1



LC923
RD11
RD25
RD1



LC924
RD11
RD26
RD1



LC925
RD11
RD27
RD1



LC926
RD11
RD28
RD1



LC927
RD11
RD29
RD1



LC928
RD11
RD30
RD1



LC929
RD11
RD31
RD1



LC930
RD11
RD32
RD1



LC931
RD11
RD33
RD1



LC932
RD11
RD34
RD1



LC933
RD11
RD35
RD1



LC934
RD11
RD40
RD1



LC935
RD11
RD41
RD1



LC936
RD11
RD42
RD1



LC937
RD11
RD64
RD1



LC938
RD11
RD66
RD1



LC939
RD11
RD68
RD1



LC940
RD11
RD76
RD1



LC941
RD13
RD5
RD1



LC942
RD13
RD6
RD1



LC943
RD13
RD9
RD1



LC944
RD13
RD10
RD1



LC945
RD13
RD12
RD1



LC946
RD13
RD14
RD1



LC947
RD13
RD15
RD1



LC948
RD13
RD16
RD1



LC949
RD13
RD17
RD1



LC950
RD13
RD18
RD1



LC951
RD13
RD19
RD1



LC952
RD13
RD20
RD1



LC953
RD13
RD21
RD1



LC954
RD13
RD22
RD1



LC955
RD13
RD23
RD1



LC956
RD13
RD24
RD1



LC957
RD13
RD25
RD1



LC958
RD13
RD26
RD1



LC959
RD13
RD27
RD1



LC960
RD13
RD28
RD1



LC961
RD13
RD29
RD1



LC962
RD13
RD30
RD1



LC963
RD13
RD31
RD1



LC964
RD13
RD32
RD1



LC965
RD13
RD33
RD1



LC966
RD13
RD34
RD1



LC967
RD13
RD35
RD1



LC968
RD13
RD40
RD1



LC969
RD13
RD41
RD1



LC970
RD13
RD42
RD1



LC971
RD13
RD64
RD1



LC972
RD13
RD66
RD1



LC973
RD13
RD68
RD1



LC974
RD13
RD76
RD1



LC975
RD14
RD5
RD1



LC976
RD14
RD6
RD1



LC977
RD14
RD9
RD1



LC978
RD14
RD10
RD1



LC979
RD14
RD12
RD1



LC980
RD14
RD15
RD1



LC981
RD14
RD11
RD1



LC982
RD14
RD17
RD1



LC983
RD14
RD18
RD1



LC984
RD14
RD19
RD1



LC985
RD14
RD20
RD1



LC986
RD14
RD21
RD1



LC987
RD14
RD22
RD1



LC988
RD14
RD23
RD1



LC989
RD14
RD24
RD1



LC990
RD14
RD25
RD1



LC991
RD14
RD26
RD1



LC992
RD14
RD27
RD1



LC993
RD14
RD28
RD1



LC994
RD14
RD29
RD1



LC995
RD14
RD30
RD1



LC996
RD14
RD31
RD1



LC997
RD14
RD32
RD1



LC998
RD14
RD33
RD1



LC999
RD14
RD34
RD1



LC1000
RD14
RD35
RD1



LC1001
RD14
RD40
RD1



LC1002
RD14
RD41
RD1



LC1003
RD14
RD42
RD1



LC1004
RD14
RD64
RD1



LC1005
RD14
RD66
RD1



LC1006
RD14
RD68
RD1



LC1007
RD14
RD76
RD1



LC1008
RD22
RD5
RD1



LC1009
RD22
RD6
RD1



LC1010
RD22
RD9
RD1



LC1011
RD22
RD10
RD1



LC1012
RD22
RD12
RD1



LC1013
RD22
RD15
RD1



LC1014
RD22
RD16
RD1



LC1015
RD22
RD17
RD1



LC1016
RD22
RD18
RD1



LC1017
RD22
RD19
RD1



LC1018
RD22
RD20
RD1



LC1019
RD22
RD21
RD1



LC1020
RD22
RD23
RD1



LC1021
RD22
RD24
RD1



LC1022
RD22
RD25
RD1



LC1023
RD22
RD26
RD1



LC1024
RD22
RD27
RD1



LC1025
RD22
RD28
RD1



LC1026
RD22
RD29
RD1



LC1027
RD22
RD30
RD1



LC1028
RD22
RD31
RD1



LC1029
RD22
RD32
RD1



LC1030
RD22
RD33
RD1



LC1031
RD22
RD34
RD1



LC1032
RD22
RD35
RD1



LC1033
RD22
RD40
RD1



LC1034
RD22
RD41
RD1



LC1035
RD22
RD42
RD1



LC1036
RD22
RD64
RD1



LC1037
RD22
RD66
RD1



LC1038
RD22
RD68
RD1



LC1039
RD22
RD76
RD1



LC1040
RD26
RD5
RD1



LC1041
RD26
RD6
RD1



LC1042
RD26
RD9
RD1



LC1043
RD26
RD10
RD1



LC1044
RD26
RD12
RD1



LC1045
RD26
RD15
RD1



LC1046
RD26
RD16
RD1



LC1047
RD26
RD17
RD1



LC1048
RD26
RD18
RD1



LC1049
RD26
RD19
RD1



LC1050
RD26
RD20
RD1



LC1051
RD26
RD21
RD1



LC1052
RD26
RD23
RD1



LC1053
RD26
RD24
RD1



LC1054
RD26
RD25
RD1



LC1055
RD26
RD27
RD1



LC1056
RD26
RD28
RD1



LC1057
RD26
RD29
RD1



LC1058
RD26
RD30
RD1



LC1059
RD26
RD31
RD1



LC1060
RD26
RD32
RD1



LC1061
RD26
RD33
RD1



LC1062
RD26
RD34
RD1



LC1063
RD26
RD35
RD1



LC1064
RD26
RD40
RD1



LC1065
RD26
RD41
RD1



LC1066
RD26
RD42
RD1



LC1067
RD26
RD64
RD1



LC1068
RD26
RD66
RD1



LC1069
RD26
RD68
RD1



LC1070
RD26
RD76
RD1



LC1071
RD35
RD5
RD1



LC1072
RD35
RD6
RD1



LC1073
RD35
RD9
RD1



LC1074
RD35
RD10
RD1



LC1075
RD35
RD12
RD1



LC1076
RD35
RD15
RD1



LC1077
RD35
RD16
RD1



LC1078
RD35
RD17
RD1



LC1079
RD35
RD18
RD1



LC1080
RD35
RD19
RD1



LC1081
RD35
RD20
RD1



LC1082
RD35
RD21
RD1



LC1083
RD35
RD23
RD1



LC1084
RD35
RD24
RD1



LC1085
RD35
RD25
RD1



LC1086
RD35
RD27
RD1



LC1087
RD35
RD28
RD1



LC1088
RD35
RD29
RD1



LC1089
RD35
RD30
RD1



LC1090
RD35
RD31
RD1



LC1091
RD35
RD32
RD1



LC1092
RD35
RD33
RD1



LC1093
RD35
RD34
RD1



LC1094
RD35
RD40
RD1



LC1095
RD35
RD41
RD1



LC1096
RD35
RD42
RD1



LC1097
RD35
RD64
RD1



LC1098
RD35
RD66
RD1



LC1099
RD35
RD68
RD1



LC1100
RD35
RD76
RD1



LC1101
RD40
RD5
RD1



LC1102
RD40
RD6
RD1



LC1103
RD40
RD9
RD1



LC1104
RD40
RD10
RD1



LC1105
RD40
RD12
RD1



LC1106
RD40
RD15
RD1



LC1107
RD40
RD16
RD1



LC1108
RD40
RD17
RD1



LC1109
RD40
RD18
RD1



LC1110
RD40
RD19
RD1



LC1111
RD40
RD20
RD1



LC1112
RD40
RD21
RD1



LC1113
RD40
RD23
RD1



LC1114
RD40
RD24
RD1



LC1115
RD40
RD25
RD1



LC1116
RD40
RD27
RD1



LC1117
RD40
RD28
RD1



LC1118
RD40
RD29
RD1



LC1119
RD40
RD30
RD1



LC1120
RD40
RD31
RD1



LC1121
RD40
RD32
RD1



LC1122
RD40
RD33
RD1



LC1123
RD40
RD34
RD1



LC1124
RD40
RD41
RD1



LC1125
RD40
RD42
RD1



LC1126
RD40
RD64
RD1



LC1127
RD40
RD66
RD1



LC1128
RD40
RD68
RD1



LC1129
RD40
RD76
RD1



LC1130
RD41
RD5
RD1



LC1131
RD41
RD6
RD1



LC1132
RD41
RD9
RD1



LC1133
RD41
RD10
RD1



LC1134
RD41
RD12
RD1



LC1135
RD41
RD15
RD1



LC1136
RD41
RD16
RD1



LC1137
RD41
RD17
RD1



LC1138
RD41
RD18
RD1



LC1139
RD41
RD19
RD1



LC1140
RD41
RD20
RD1



LC1141
RD41
RD21
RD1



LC1142
RD41
RD23
RD1



LC1143
RD41
RD24
RD1



LC1144
RD41
RD25
RD1



LC1145
RD41
RD27
RD1



LC1146
RD41
RD28
RD1



LC1147
RD41
RD29
RD1



LC1148
RD41
RD30
RD1



LC1149
RD41
RD31
RD1



LC1150
RD41
RD32
RD1



LC1151
RD41
RD33
RD1



LC1152
RD41
RD34
RD1



LC153
RD41
RD42
RD1



LC1154
RD41
RD64
RD1



LC1155
RD41
RD66
RD1



LC1156
RD41
RD68
RD1



LC1157
RD41
RD76
RD1



LC1158
RD64
RD5
RD1



LC1159
RD64
RD6
RD1



LC1160
RD64
RD9
RD1



LC1161
RD64
RD10
RD1



LC1162
RD64
RD12
RD1



LC1163
RD64
RD15
RD1



LC1164
RD64
RD16
RD1



LC1165
RD64
RD17
RD1



LC1166
RD64
RD18
RD1



LC1167
RD64
RD19
RD1



LC1168
RD64
RD20
RD1



LC1169
RD64
RD21
RD1



LC1170
RD64
RD23
RD1



LC1171
RD64
RD24
RD1



LC1172
RD64
RD25
RD1



LC1173
RD64
RD27
RD1



LC1174
RD64
RD28
RD1



LC1175
RD64
RD29
RD1



LC1176
RD64
RD30
RD1



LC1177
RD64
RD31
RD1



LC1178
RD64
RD32
RD1



LC1179
RD64
RD33
RD1



LC1180
RD64
RD34
RD1



LC1181
RD64
RD42
RD1



LC1182
RD64
RD64
RD1



LC1183
RD64
RD66
RD1



LC1184
RD64
RD68
RD1



LC1185
RD64
RD76
RD1



LC1186
RD66
RD5
RD1



LC1187
RD66
RD6
RD1



LC1188
RD66
RD9
RD1



LC1189
RD66
RD10
RD1



LC1190
RD66
RD12
RD1



LC1191
RD66
RD15
RD1



LC1192
RD66
RD16
RD1



LC1193
RD66
RD17
RD1



LC1194
RD66
RD18
RD1



LC1195
RD66
RD19
RD1



LC1196
RD66
RD20
RD1



LC1197
RD66
RD21
RD1



LC1198
RD66
RD23
RD1



LC1199
RD66
RD24
RD1



LC1200
RD66
RD25
RD1



LC1201
RD66
RD27
RD1



LC1202
RD66
RD28
RD1



LC1203
RD66
RD29
RD1



LC1204
RD66
RD30
RD1



LC1205
RD66
RD31
RD1



LC1206
RD66
RD32
RD1



LC1207
RD66
RD33
RD1



LC1208
RD66
RD34
RD1



LC1209
RD66
RD42
RD1



LC1210
RD66
RD68
RD1



LC1211
RD66
RD76
RD1



LC1212
RD68
RD5
RD1



LC1213
RD68
RD6
RD1



LC1214
RD68
RD9
RD1



LC1215
RD68
RD10
RD1



LC1216
RD68
RD12
RD1



LC1217
RD68
RD15
RD1



LC1218
RD68
RD16
RD1



LC1219
RD68
RD17
RD1



LC1220
RD68
RD18
RD1



LC1221
RD68
RD19
RD1



LC1222
RD68
RD20
RD1



LC1223
RD68
RD21
RD1



LC1224
RD68
RD23
RD1



LC1225
RD68
RD24
RD1



LC1226
RD68
RD25
RD1



LC1227
RD68
RD27
RD1



LC1228
RD68
RD28
RD1



LC1229
RD68
RD29
RD1



LC1230
RD68
RD30
RD1



LC1231
RD68
RD31
RD1



LC1232
RD68
RD32
RD1



LC1233
RD68
RD33
RD1



LC1234
RD68
RD34
RD1



LC1235
RD68
RD42
RD1



LC1236
RD68
RD76
RD1



LC1237
RD76
RD5
RD1



LC1238
RD76
RD6
RD1



LC1239
RD76
RD9
RD1



LC1240
RD76
RD10
RD1



LC1241
RD76
RD12
RD1



LC1242
RD76
RD15
RD1



LC1243
RD76
RD16
RD1



LC1244
RD76
RD17
RD1



LC1245
RD76
RD18
RD1



LC1246
RD76
RD19
RD1



LC1247
RD76
RD20
RD1



LC1248
RD76
RD21
RD1



LC1249
RD76
RD23
RD1



LC1250
RD76
RD24
RD1



LC1251
RD76
RD25
RD1



LC1252
RD76
RD27
RD1



LC1253
RD76
RD28
RD1



LC1254
RD76
RD29
RD1



LC1255
RD76
RD30
RD1



LC1256
RD76
RD31
RD1



LC1257
RD76
RD32
RD1



LC1258
RD76
RD33
RD1



LC1259
RD76
RD34
RD1



LC1260
RD76
RD42
RD1










and

wherein RD1 to RD81 has the following structures:


























In some embodiments, an organic light emitting device (OLED) is described. The OLED can include an anode; a cathode; and an organic layer, disposed between the anode and the cathode, where the organic layer includes a compound comprising a first ligand LA of Formula IA, Formula IB, or Formula IC, as described herein.
In some embodiments, a consumer product comprising an OLED as described herein is described.
In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.
According to another aspect, an emissive region in an OLED (e.g., the organic layer described herein) is disclosed. The emissive region comprises a compound comprising a first ligand LA of Formula IA, Formula IB, or Formula IC, as described herein.
In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes.
According to another aspect, a formulation comprising the compound described herein is also disclosed.
The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used may be a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of CnH2n+1, OCnH2n+1, OAr1, N(CnH2n+1)2, N(Ar1)(Ar2), CH═CH—CnH2n+1, C≡C—CnH2n+1, Ar1, Ar1—Ar2, and CnH2n—Ar1, or the host has no substitutions. In the preceding substituents n can range from 1 to 10; and Ar1 and Ar2 can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.
The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:
















and combinations thereof.

Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
Combination with Other Materials
The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
Conductivity Dopants:
A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.










HIL/HTL:

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoOx; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:




Each of Ar1 to Ar9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In one aspect, Ar1 to Ar9 is independently selected from the group consisting of:




wherein k is an integer from 1 to 20; X101 to X108 is C (including CH) or N; Z101 is NAr1, O, or S; Ar1 has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:




wherein Met is a metal, which can have an atomic weight greater than 40; (Y101-Y102) is a bidentate ligand, Y101 and Y102 are independently selected from C, N, O, P, and S; L101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k′′ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y101-Y102) is a 2-phenylpyridine derivative. In another aspect, (Y101-Y102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc+/Fc couple less than about 0.6 V.
Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.























































EBL:

An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
Host:
The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
Examples of metal complexes used as host are preferred to have the following general formula:




wherein Met is a metal; (Y103-Y104) is a bidentate ligand, Y103 and Y104 are independently selected from C, N, O, P, and S; L101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k′′ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:




wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y103-Y104) is a carbene ligand.
Examples of other organic compounds used as host are selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
In one aspect, the host compound contains at least one of the following groups in the molecule:







wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X101 to X108 are independently selected from C (including CH) or N. Z101 and Z102 are independently selected from NR101, O, or S.

Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,








































Additional Emitters:

One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.









































































HBL:

A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
In another aspect, compound used in HBL contains at least one of the following groups in the molecule:




wherein k is an integer from 1 to 20; L101 is an another ligand, k′ is an integer from 1 to 3.

ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
In one aspect, compound used in ETL contains at least one of the following groups in the molecule:




wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar1 to Ar3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X101 to X108 is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:




wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,




























Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
EXPERIMENTAL
Dopant Synthesis




Compound 10, the ligand used to synthesize Dopant A, was prepared in seven steps according to Scheme I.




Step 1: Synthesis of 6-bromo-1-methoxynaphthalene (2)
6-Bromonaphthalen-1-ol (compound 1, 10 g, 44.8 mmol) was dissolved in dry acetone (180 mL) under a room temperature ( ̃22° C.) atmosphere in a 500 mL, 3-necked round bottomed flask topped with a reflux condenser. Then, potassium carbonate (12.39 g, 90 mmol) and methyl iodide (5.61 ml, 90 mmol) were added and the reaction mixture was stirred at 65° C. for 18 hours. The reaction was cooled to room temperature ( ̃22° C.), causing a white solid to precipitate from the reaction mixture. The precipitate was then was filtered off and the filtrate was concentrated under vacuum. The reaction mixture was partitioned between EtOAc and brine (200 mL) and the organics were separated and washed with brine (2×50 mL), dried over MgSO4, and the solvents removed to afford an orange oil. Recrystallization from iso-hexane afforded compound 2 of Scheme I as a white solid (8.0 g, 33.7 mmol, 75% yield).
Step 2: Synthesis of 2-(5-methoxynaphthalen-2-yl)phenol (4)
Potassium carbonate (9.97 g, 72.1 mmol), 6-bromo-1-methoxynaphthalene (5.7 g, 24.04 mmol) and (2-hydroxyphenyl)boronic acid (compound 3, 4.97 g, 36.1 mmol) were dissolved in a 4.5:1 mixture of dioxane:water (300 mL) in a 500 mL three-necked round bottomed flask topped with a reflux condenser. The mixture was sparged with N2 for 15 min, and then tetrakis(triphenylphosphine)palladium(0) (1.389 g, 1.202 mmol) was added, and the mixture was sparged with N2 for additional 5 min. The reaction was stirred for 18 h at 80° C. The reaction mixture was taken to pH 7 using HCl 2N and partitioned between EtOAc and brine. The organics were separated and washed with brine (2×200 mL), dried over MgSO4, and the solvents removed. The crude was purified by flash chromatography using mixtures of iso-hexane/dichloromethane to afford compound 4 of Scheme I as a yellow solid (5.50 g, 21.75 mmol, 90% yield).
Step 3: Synthesis of 7-methoxynaphtho[2,3-b]benzofuran (5)
Palladium(II) acetate (0.484 g, 2.157 mmol) and 3-nitropyridine (0.268 g, 2.157 mmol) were placed in a 500 mL high-pressure ACE brand reaction vessel topped with a rubber septum and evacuated/backfilled with N2 three times. Then 2-(5-methoxynaphthalen-2-yl)phenol (5.40 g, 21.57 mmol) dissolved in dry 1,2-dimethoxyethane (150.0 ml) was added under N2 via cannula followed by tert-butyl peroxybenzoate (8.14 ml, 43.1 mmol). The ACE reaction vessel was sealed and the reaction mixture stirred at 120° C. for 40 min. The reaction mixture was allowed to cool to room temperature ( ̃22° C.), then filtered through a plug of Celite® (diatomaceous earth) eluting with dichloromethane. Solvents were removed in vacuo to afford a brown solid. The crude was purified by flash chromatography using mixtures of iso-hexane/acetone to afford compound 5 of Scheme I as a white solid (1.8 g, 7.25 mmol, 33% yield).
Step 4: Synthesis of naphtho[2,3-b]benzofuran-7-ol (6)
7-methoxynaphtho[2,3-b]benzofuran (16.0 g, 64.4 mmol) was dissolved in dry dichloromethane (120.0 ml) under N2 in a 250 mL three-necked round bottomed flask fitted with an addition funnel. The mixture was cooled down to −78° C. before tribromoborane (1M in dichloromethane, 97 ml, 97 mmol) was added dropwise. The reaction mixture was allowed to warm to room temperature ( ̃22° C.) and stirred for two hours. The reaction mixture was then poured into water-ice and extracted with dichloromethane (3×100 mL), with 10 mL of acetone to facilitate solubility, dried over MgSO4, and the solvents removed. A red solid was obtained which was further triturated with iso-hexane to afford compound 6 of Scheme I as an off-white solid (14.42 g, 60.9 mmol, 95% yield).
Step 5: Synthesis of naphtho[2,3-b]benzofuran-7-yl trifluoromethanesulfonate (7)
Naphtho[2,3-b]benzofuran-7-ol (14.4 g, 61.5 mmol) and pyridine (7.46 ml, 92 mmol) were dissolved in dry dichloromethane (300 mL) under N2 in a 3-necked round bottomed flask fitted with an addition funnel. The mixture was cooled down to 0° C. and trifluoromethanesulfonic anhydride (12.46 ml, 73.8 mmol) was added dropwise. The reaction mixture was slowly allowed to warm to room temperature ( ̃22° C.) and stirred for an additional 16 h. The reaction mixture was partitioned between dichlormethane (100 mL) and saturated aqueous NaHCO3 (200 mL), the organics were then separated, dried over MgSO4 and the solvents removed to afford a brown solid that further triturated with iso-hexane to afford compound 7 of Scheme I as an off-white solid (18.63 g, 50.3 mmol, 82% yield).
Step 6: Synthesis of 4,4,5,5-tetramethyl-2-(naphtho[2,3-b]benzofuran-7-yl)-1,3,2-dioxaborolane (8)
Bis(pinacolato)diboron (15.34 g, 60.4 mmol), naphtho[2,3-b]benzofuran-7-yl trifluoromethanesulfonate (18.44 g, 50.3 mmol), potassium acetate (9.88 g, 101 mmol) and 1,1′-bis(diphenylphosphino)ferrocenepalladium(II)dichloride dichloromethane complex (1.23 g, 1.51 mmol) were dissolved in dry dioxane (200 mL) in a 3-necked round bottomed flask fitted with a reflux condenser. The mixture was sparged with nitrogen for 15 min then the reaction was stirred for 18 h at 100° C. The reaction mixture was partitioned between ethyl acetate (EtOAc) (200 mL) and brine (200 mL), the organics were separated, washed with brine (2×200 mL), dried over MgSO4 and the solvents removed. The crude was purified by flash chromatography using mixtures of iso-hexane/dichloromethane to afford compound 8 of Scheme I as a yellow solid (12.0 g, 34.7 mmol, 68.9%).
Step 7: Synthesis of 5-methyl-2-(naphtho[2,3-b]benzofuran-7-yl)pyrimidine (10)
A mixture of 4,4,5,5-tetramethyl-2-(naphtho[2,3-b]benzofuran-7-yl)-1,3,2-dioxaborolane (2.02 g, 5.9 mmol), 5-methyl-2-chloropyrimidine (compound 9, 0.93 g, 7.2 mmol), 2 M aq. potassium carbonate (6 mL, 12 mmol) and ethanol (30 mL) were sparged with nitrogen for 10 min. Silicate DPP-Pd silica-based catalyst (0.404 g, 0.12 mmol) was added and the reaction mixture heated at 76° C. for 18 h. The solvent was removed under reduced pressure. The residue was dry-loaded onto silica gel and purified on an Interchim automated system (80 g column) eluting with 0-30% ethyl acetate in heptanes. The product containing fractions were concentrated under reduced pressure and the solid dried in a vacuum oven for 4 hours to afford compound 10 of Scheme I (5-methyl-2-(naphtho[2,3-b]benzofuran-7-yl)-pyrimidine) (1.33 g, 99.3% UPLC purity) as an off-white solid.
Synthesis of Dopant A
Dopant A was synthesized according to the reaction below.




Synthesis of bis[(6-methyl-2-phenylpyridin-2-yl)]-5-methyl-2-(naphtho[2,3-b]benzofuran-7-yl)pyrimidin-2-yl]iridium(III) (Dopant A)
A solution of 5-methyl-2-(naphtho[2,3-b]benzofuran-7-yl)pyrimidine (1.48 g, 4.75 mmol, 1.76 equiv) in ethanol (75 mL) was sparged with nitrogen for 10 min. [Ir(2-phenyl-6-methyl-pyridin-2-yl(−1H))2-(MeOH)2](trifluororethanesulfonate) (2.0 g, 2.7 mmol, 1.0 equiv) was added and the reaction mixture was heated 78° C. for 36 h. The mixture was cooled to room temperature ( ̃22° C.), filtered, the solids washed with methanol (2×25 mL), and air dried. The crude material was chromatographed on silica gel (135 g) layered with basic alumina (43 g), eluting with 20% hexanes in dichloromethane. Product containing fractions were concentrated under reduced pressure and the solid dried in a vacuum oven for 9 h to afford Dopant A (1.8 g, 82% yield 99.3% HPLC purity) as an orange solid.
The ligand used to synthesize Dopant B, 5-methyl-2-(naphthalen-1-yl)pyrimidine, was prepared according to the synthesis scheme below.




Synthesis of 5-Methyl-2-(naphthalen-1-yl)pyrimidine
A mixture of naphthalen-1-ylboronic acid (15 g, 96 mmol), 2-chloro-5-methylpyrimidine (9 g, 70 mmol), 2 M aq. potassium carbonate (58 mL, 116 mmol) and ethanol (300 mL) was sparged with nitrogen for 15 min. Silicate DPP-Pd silica-based catalyst (3.87 g, 1.16 mmol, 0.17 equiv) was added and the reaction mixture heated at 78° C. for 48 h. The reaction mixture was cooled to room temperature ( ̃22° C.) filtered and the filtrate was concentrated under reduced pressure. The residue was diluted with ethyl acetate and washed with saturated brine. The organic layer was dried over sodium sulfate, filtered and concentrated under reduced pressure. The residue was purified by chromatography on silica gel, eluting with 0-20% ethyl acetate in heptanes to afford 5-methyl-2-(naphthalen-1-yl)pyrimidine (12.65 g, 82% yield, 99.8% UPLC purity) as a white solid.
Dopant B was synthesized according to the equation below.




Synthesis of bis[((2-phenyl-2′-yl)-6-methylpyridin)-1-yl]-((5-methyl-2-(naphthalen-1-yl)-2-′yl)pyrimidin-1-yl)iridium(III) (Dopant B)
A solution of 5-methyl-2-(naphthalen-1-yl)pyrimidine (1.19 g, 5.39 mmol) in ethanol (75 mL) was sparged with nitrogen for 15 minutes, then Ir(2-phenyl-6-methylpyridin-2-yl(-1H))2-(MeOH)2](trifluoromethanesulfonate) (1.0 g, 2.7 mmol) was added and the reaction mixture heated at 78° C. for 30 h. The mixture was cooled to room temperature ( ̃22° C.), filtered and the solids dissolved in a minimum amount of dichloromethane (traces of insoluble material remained). The crude material was chromatographed on silica gel (100 g) layered with basic alumina (30 g), eluting with 20% hexanes in dichloromethane. Product containing fractions were concentrated under reduced pressure and the solid dried in a vacuum oven for 14 h to afford bis[((2-phenyl-2′-yl)-6-methylpyridin)-1-yl]-((5-methyl-2-(naphthalen-1-yl)-2-′yl)pyrimidin-1-yl) iridium(II) (1.52 g, 75% yield, 99.2% HPLC purity) as an orange solid.
Device Examples







All example devices were fabricated by high vacuum (<10−7 Torr) thermal evaporation. The anode electrode was 1150 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium) followed by 1,000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H2O and O2) immediately after fabrication, and a moisture getter was incorporated inside the package. The organic stack of the device examples consisted of sequentially, from the ITO surface, 100 Å of HATCN as the hole injection layer (HIL); 450 Å of HTL-1 as the hole transporting layer (HTL); 400 Å of an emissive layer (EML) comprising Host-1 as a host, SD-1 as a stability dopant (18%), and Dopant A or Dopant B as the emitter (3%); 350 Å of Liq doped with 35% of ETM-1 as the ETL; and 10 Å of Liq as the electron injection layer (EIL). The stability dopant was added to the electron-transporting host to help transport positive charge in the emissive layer.
Upon fabrication, the electroluminescence (EL) and current density-voltage-luminance (JVL) performance of the devices was measured. The device lifetimes were evaluated at a current density of 80 mA/cm2. The results are summarized in Table I and compare the performance of Dopant A in Example 1 vs. Dopant B in Comparative Example 2. Both dopants afford devices with identical voltages and external quantum efficiencies. However, Dopant A provides narrower line width (full width at half maximum, FWHM) and significantly longer device lifetime than Dopant B. The emission wavelength of Dopant A is also red-shifted versus Dopant B, which is desirable for application of the dopants of the present invention as red emissive materials in OLED devices.













TABLE 1












At 
At 







10 mA/cm2
80 mA/














Device 


λ

Vol-

cm2


Exam-

1931 CIE
max 
FWHM 
tage 
EQE 
LT95%















ple
Emitter
x
y
[nm]
[au]
[au]
[au]
[au]





Inven-
Dopant
0.550
0.448
580
0.91
1.00
1.00
1.62


tive
A









Exam-










ple 1










Compar-
Dopant
0.518
0.479
567
1.00
1.00
1.00
1.00


ative
B









Exam-










ple 2





au = normalized units






It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.

## Claims

1. A compound comprising a first ligand LA having the Formula selected from the group consisting of:



wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein RA, RB, RC, and RD each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z1 and Z2 are each independently selected from the group consisting of C and N;
wherein X1, X2, X3, X4, X5, and X6 are each C;
wherein when the first ligand LA has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand LA is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X1 in Formula IB;
wherein M does not form a direct bond to X4 in Formula IC;
wherein the metal M can be coordinated to other ligands; and
wherein the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.

2. The compound of claim 1, wherein M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Pd, Au, and Cu.

3. The compound of claim 1, wherein M is Ir or Pt.

4. The compound of claim 1, wherein R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.

5. The compound of claim 1, wherein Y is O.

6. The compound of claim 1, wherein ring C is a fused benzene ring.

7. The compound of claim 1, wherein when the first ligand LA has the Formula of Formula IA, ring B is selected from the group consisting of pyrimidine, pyrazine, pyridazine, imidazole, pyrazole, triazole, pyrrole, oxazole, thiazole, and imidazole derived carbene; and
when the first ligand LA has the Formula of Formula IB or IC, ring B is selected from the group consisting of pyridine, pyrimidine, pyrazine, pyridazine, benzene, imidazole, pyrazole, triazole, pyrrole, oxazole, thiazole, and imidazole derived carbene.

8. The compound of claim 1, wherein the first ligand LA is selected from the group consisting of:













































































































and aza variants thereof; and
wherein Ra is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

9. The compound of claim 1, wherein the first ligand LA is selected from the group consisting of LA121 through LA456, LA577 through LA2736, LA2857 through LA4104, and LA4225 through LA4780, wherein LA121 through LA240 have a structure of Formula II:



wherein R1, R2, X, and Y are defined as:


















Ligand
R1
R2
X
Y









LA121
H
H
N
S



LA122
RB1
H
N
S



LA123
RB3
H
N
S



LA124
RB4
H
N
S



LA125
RB7
H
N
S



LA126
RB10
H
N
S



LA127
RA3
H
N
S



LA128
RA34
H
N
S



LA129
H
H
N
O



LA130
RB1
H
N
O



LA131
RB3
H
N
O



LA132
RB4
H
N
O



LA133
RB7
H
N
O



LA134
RB10
H
N
O



LA135
RA3
H
N
O



LA136
RA34
H
N
O



LA137
H
H
N
NCH3



LA138
RB1
H
N
NCH3



LA139
RB3
H
N
NCH3



LA140
RB4
H
N
NCH3



LA141
RB7
H
N
NCH3



LA142
RB10
H
N
NCH3



LA143
RA3
H
N
NCH3



LA144
RA34
H
N
NCH3



LA145
H
H
N
C(CH3)2



LA146
RB1
H
N
C(CH3)2



LA147
RB3
H
N
C(CH3)2



LA148
RB4
H
N
C(CH3)2



LA149
RB7
H
N
C(CH3)2



LA150
RB10
H
N
C(CH3)2



LA151
RA3
H
N
C(CH3)2



LA152
RA34
H
N
C(CH3)2



LA153
H
H
N
Si(CH3)2



LA154
RB1
H
N
Si(CH3)2



LA155
RB3
H
N
Si(CH3)2



LA156
RB4
H
N
Si(CH3)2



LA157
RB7
H
N
Si(CH3)2



LA158
RB10
H
N
Si(CH3)2



LA159
RA3
H
N
Si(CH3)2



LA160
RA34
H
N
Si(CH3)2



LA161
H
RB1
N
S



LA162
RB1
RB1
N
S



LA163
RB3
RB1
N
S



LA164
RB4
RB1
N
S



LA165
RB7
RB1
N
S



LA166
RB10
RB1
N
S



LA167
RA3
RB1
N
S



LA168
RA34
RB1
N
S



LA169
H
RB1
N
O



LA170
RB1
RB1
N
O



LA171
RB3
RB1
N
O



LA172
RB4
RB1
N
O



LA173
RB7
RB1
N
O



LA174
RB10
RB1
N
O



LA175
RA3
RB1
N
O



LA176
RA34
RB1
N
O



LA177
H
RB1
N
NCH3



LA178
RB1
RB1
N
NCH3



LA179
RB3
RB1
N
NCH3



LA180
RB4
RB1
N
NCH3



LA181
RB7
RB1
N
NCH3



LA182
RB10
RB1
N
NCH3



LA183
RA3
RB1
N
NCH3



LA184
RA34
RB1
N
NCH3



LA185
H
RB1
N
C(CH3)2



LA186
RB1
RB1
N
C(CH3)2



LA187
RB3
RB1
N
C(CH3)2



LA188
RB4
RB1
N
C(CH3)2



LA189
RB7
RB1
N
C(CH3)2



LA190
RB10
RB1
N
C(CH3)2



LA191
RA3
RB1
N
C(CH3)2



LA192
RA34
RB1
N
C(CH3)2



LA193
H
RB1
N
Si(CH3)2



LA194
RB1
RB1
N
Si(CH3)2



LA195
RB3
RB1
N
Si(CH3)2



LA196
RB4
RB1
N
Si(CH3)2



LA197
RB7
RB1
N
Si(CH3)2



LA198
RB10
RB1
N
Si(CH3)2



LA199
RA3
RB1
N
Si(CH3)2



LA200
RA34
RB1
N
Si(CH3)2



LA201
H
RB2
N
S



LA202
RB1
RB2
N
S



LA203
RB3
RB2
N
S



LA204
RB4
RB2
N
S



LA205
RB7
RB2
N
S



LA206
RB10
RB2
N
S



LA207
RA3
RB2
N
S



LA208
RA34
RB2
N
S



LA209
H
RB2
N
O



LA210
RB1
RB2
N
O



LA211
RB3
RB2
N
O



LA212
RB4
RB2
N
O



LA213
RB7
RB2
N
O



LA214
RB10
RB2
N
O



LA215
RA3
RB2
N
O



LA216
RA34
RB2
N
O



LA217
H
RB2
N
NCH3



LA218
RB1
RB2
N
NCH3



LA219
RB3
RB2
N
NCH3



LA220
RB4
RB2
N
NCH3



LA221
RB7
RB2
N
NCH3



LA222
RB10
RB2
N
NCH3



LA223
RA3
RB2
N
NCH3



LA224
RA34
RB2
N
NCH3



LA225
H
RB2
N
C(CH3)2



LA226
RB1
RB2
N
C(CH3)2



LA227
RB3
RB2
N
C(CH3)2



LA228
RB4
RB2
N
C(CH3)2



LA229
RB7
RB2
N
C(CH3)2



LA230
RB10
RB2
N
C(CH3)2



LA231
RA3
RB2
N
C(CH3)2



LA232
RA34
RB2
N
C(CH3)2



LA233
H
RB2
N
Si(CH3)2



LA234
RB1
RB2
N
Si(CH3)2



LA235
RB3
RB2
N
Si(CH3)2



LA236
RB4
RB2
N
Si(CH3)2



LA237
RB7
RB2
N
Si(CH3)2



LA238
RB10
RB2
N
Si(CH3)2



LA239
RA3
RB2
N
Si(CH3)2



LA240
RA34
RB2
N
Si(CH3)2









wherein LA241 through LA360 have a structure of Formula III:




wherein R2, R3 and Y are defined as provided below:

















Ligand
R2
R3
Y









LA241
H
H
S



LA242
H
RB1
S



LA243
H
RB2
S



LA244
H
RB3
S



LA245
H
RB4
S



LA246
H
RB5
S



LA247
H
RA34
S



LA248
H
RA52
S



LA249
H
H
O



LA250
H
RB1
O



LA251
H
RB2
O



LA252
H
RB3
O



LA253
H
RB4
O



LA254
H
RB5
O



LA255
H
RA34
O



LA256
H
RA52
O



LA257
H
H
NCH3



LA258
H
RB1
NCH3



LA259
H
RB2
NCH3



LA260
H
RB3
NCH3



LA261
H
RB4
NCH3



LA262
H
RB5
NCH3



LA263
H
RA34
NCH3



LA264
H
RA52
NCH3



LA265
H
H
C(CH3)2



LA266
H
RB1
C(CH3)2



LA267
H
RB2
C(CH3)2



LA268
H
RB3
C(CH3)2



LA269
H
RB4
C(CH3)2



LA270
H
RB5
C(CH3)2



LA271
H
RA34
C(CH3)2



LA272
H
RA52
C(CH3)2



LA273
H
H
Si(CH3)2



LA274
H
RB1
Si(CH3)2



LA275
H
RB2
Si(CH3)2



LA276
H
RB3
Si(CH3)2



LA277
H
RB4
Si(CH3)2



LA278
H
RB5
Si(CH3)2



LA279
H
RA34
Si(CH3)2



LA280
H
RA52
Si(CH3)2



LA281
RB1
H
S



LA282
RB1
RB1
S



LA283
RB1
RB2
S



LA284
RB1
RB3
S



LA285
RB1
RB4
S



LA286
RB1
RB5
S



LA287
RB1
RA34
S



LA288
RB1
RA52
S



LA289
RB1
H
O



LA290
RB1
RB1
O



LA291
RB1
RB2
O



LA292
RB1
RB3
O



LA293
RB1
RB4
O



LA294
RB1
RB5
O



LA295
RB1
RA34
O



LA296
RB1
RA52
O



LA297
RB1
H
NCH3



LA298
RB1
RB1
NCH3



LA299
RB1
RB2
NCH3



LA300
RB1
RB3
NCH3



LA301
RB1
RB4
NCH3



LA302
RB1
RB5
NCH3



LA303
RB1
RA34
NCH3



LA304
RB1
RA52
NCH3



LA305
RB1
H
C(CH3)2



LA306
RB1
RB1
C(CH3)2



LA307
RB1
RB2
C(CH3)2



LA308
RB1
RB3
C(CH3)2



LA309
RB1
RB4
C(CH3)2



LA310
RB1
RB5
C(CH3)2



LA311
RB1
RA34
C(CH3)2



LA312
RB1
RA52
C(CH3)2



LA313
RB1
H
Si(CH3)2



LA314
RB1
RB1
Si(CH3)2



LA315
RB1
RB2
Si(CH3)2



LA316
RB1
RB3
Si(CH3)2



LA317
RB1
RB4
Si(CH3)2



LA318
RB1
RB5
Si(CH3)2



LA319
RB1
RA34
Si(CH3)2



LA320
RB1
RA52
Si(CH3)2



LA321
RB2
H
S



LA322
RB2
RB1
S



LA323
RB2
RB2
S



LA324
RB2
RB3
S



LA325
RB2
RB4
S



LA326
RB2
RB5
S



LA327
RB2
RA34
S



LA328
RB2
RA52
S



LA329
RB2
H
O



LA330
RB2
RB1
O



LA331
RB2
RB2
O



LA332
RB2
RB3
O



LA333
RB2
RB4
O



LA334
RB2
RB5
O



LA335
RB2
RA34
O



LA336
RB2
RA52
O



LA337
RB2
H
NCH3



LA338
RB2
RB1
NCH3



LA339
RB2
RB2
NCH3



LA340
RB2
RB3
NCH3



LA341
RB2
RB4
NCH3



LA342
RB2
RB5
NCH3



LA343
RB2
RA34
NCH3



LA344
RB2
RA52
NCH3



LA345
RB2
H
C(CH3)2



LA346
RB2
RB1
C(CH3)2



LA347
RB2
RB2
C(CH3)2



LA348
RB2
RB3
C(CH3)2



LA349
RB2
RB4
C(CH3)2



LA350
RB2
RB5
C(CH3)2



LA351
RB2
RA34
C(CH3)2



LA352
RB2
RA52
C(CH3)2



LA353
RB2
H
Si(CH3)2



LA354
RB2
RB1
Si(CH3)2



LA355
RB2
RB2
Si(CH3)2



LA356
RB2
RB3
Si(CH3)2



LA357
RB2
RB4
Si(CH3)2



LA358
RB2
RB5
Si(CH3)2



LA359
RB2
RA34
Si(CH3)2



LA360
RB2
RA52
Si(CH3)2









wherein LA361 through LA456 have a structure of Formula IV,





wherein R2, R4, Y, and X are defined as provided below:

















Ligand
R2
R4
Y
Z









LA361
H
H
S
S



LA362
H
RB1
S
S



LA363
H
RB3
S
S



LA364
H
RB4
S
S



LA365
H
RB7
S
S



LA366
H
RB10
S
S



LA367
H
RA3
S
S



LA368
H
RA34
S
S



LA369
H
H
S
O



LA370
H
RB1
S
O



LA371
H
RB3
S
O



LA372
H
RB4
S
O



LA373
H
RB7
S
O



LA374
H
RB10
S
O



LA375
H
RA3
S
O



LA376
H
RA34
S
O



LA377
H
H
S
NCH3



LA378
H
RB1
S
NCH3



LA379
H
RB3
S
NCH3



LA380
H
RB4
S
NCH3



LA381
H
RB7
S
NCH3



LA382
H
RB10
S
NCH3



LA383
H
RA3
S
NCH3



LA384
H
RA34
S
NCH3



LA385
H
H
O
S



LA386
H
RB1
O
S



LA387
H
RB3
O
S



LA388
H
RB4
O
S



LA389
H
RB7
O
S



LA390
H
RB10
O
S



LA391
H
RA3
O
S



LA392
H
RA34
O
S



LA393
H
H
O
O



LA394
H
RB1
O
O



LA395
H
RB3
O
O



LA396
H
RB4
O
O



LA397
H
RB7
O
O



LA398
H
RB10
O
O



LA399
H
RA3
O
O



LA400
H
RA34
O
O



LA401
H
H
O
NCH3



LA402
H
RB1
O
NCH3



LA403
H
RB3
O
NCH3



LA404
H
RB4
O
NCH3



LA405
H
RB7
O
NCH3



LA406
H
RB10
O
NCH3



LA407
H
RA3
O
NCH3



LA408
H
RA34
O
NCH3



LA409
RB1
H
S
S



LA410
RB1
RB1
S
S



LA411
RB1
RB3
S
S



LA412
RB1
RB4
S
S



LA413
RB1
RB7
S
S



LA414
RB1
RB10
S
S



LA415
RB1
RA3
S
S



LA416
RB1
RA34
S
S



LA417
RB1
H
S
O



LA418
RB1
RB1
S
O



LA419
RB1
RB3
S
O



LA420
RB1
RB4
S
O



LA421
RB1
RB7
S
O



LA422
RB1
RB10
S
O



LA423
RB1
RA3
S
O



LA424
RB1
RA34
S
O



LA425
RB1
H
S
NCH3



LA426
RB1
RB1
S
NCH3



LA427
RB1
RB3
S
NCH3



LA428
RB1
RB4
S
NCH3



LA429
RB1
RB7
S
NCH3



LA430
RB1
RB10
S
NCH3



LA431
RB1
RA3
S
NCH3



LA432
RB1
RA34
S
NCH3



LA433
RB1
H
O
S



LA434
RB1
RB1
O
S



LA435
RB1
RB3
O
S



LA436
RB1
RB4
O
S



LA437
RB1
RB7
O
S



LA438
RB1
RB10
O
S



LA439
RB1
RA3
O
S



LA440
RB1
RA34
O
S



LA441
RB1
H
O
O



LA442
RB1
RB1
O
O



LA443
RB1
RB3
O
O



LA444
RB1
RB4
O
O



LA445
RB1
RB7
O
O



LA446
RB1
RB10
O
O



LA447
RB1
RA3
O
O



LA448
RB1
RA34
O
O



LA449
RB1
H
O
NCH3



LA450
RB1
RB1
O
NCH3



LA451
RB1
RB3
O
NCH3



LA452
RB1
RB4
O
NCH3



LA453
RB1
RB7
O
NCH3



LA454
RB1
RB10
O
NCH3



LA455
RB1
RA3
O
NCH3



LA456
RB1
RA34
O
NCH3









wherein LA577 through LA696 have a structure of Formula V:




wherein R1, R2, X, and Y are defined as provided below:


















Ligand 
R1
R2
X
Y









LA577
H
H
N
S



LA578
RB1
H
N
S



LA579
RB3
H
N
S



LA580
RB4
H
N
S



LA581
RB7
H
N
S



LA582
RB10
H
N
S



LA583
RA3
H
N
S



LA584
RA34
H
N
S



LA585
H
H
N
O



LA586
RB1
H
N
O



LA587
RB3
H
N
O



LA588
RB4
H
N
O



LA589
RB7
H
N
O



LA590
RB10
H
N
O



LA591
RA3
H
N
O



LA592
RA34
H
N
O



LA593
H
H
N
NCH3



LA594
RB1
H
N
NCH3



LA595
RB3
H
N
NCH3



LA596
RB4
H
N
NCH3



LA597
RB7
H
N
NCH3



LA598
RB10
H
N
NCH3



LA599
RA3
H
N
NCH3



LA600
RA34
H
N
NCH3



LA601
H
H
N
C(CH3)2



LA602
RB1
H
N
C(CH3)2



LA603
RB3
H
N
C(CH3)2



LA604
RB4
H
N
C(CH3)2



LA605
RB7
H
N
C(CH3)2



LA606
RB10
H
N
C(CH3)2



LA607
RA3
H
N
C(CH3)2



LA608
RA34
H
N
C(CH3)2



LA609
H
H
N
Si(CH3)2



LA610
RB1
H
N
Si(CH3)2



LA611
RB3
H
N
Si(CH3)2



LA612
RB4
H
N
Si(CH3)2



LA613
RB7
H
N
Si(CH3)2



LA614
RB10
H
N
Si(CH3)2



LA615
RA3
H
N
Si(CH3)2



LA616
RA34
H
N
Si(CH3)2



LA617
H
RB1
N
S



LA618
RB1
RB1
N
S



LA619
RB3
RB1
N
S



LA620
RB4
RB1
N
S



LA621
RB7
RB1
N
S



LA622
RB10
RB1
N
S



LA623
RA3
RB1
N
S



LA624
RA34
RB1
N
S



LA625
H
RB1
N
O



LA626
RB1
RB1
N
O



LA627
RB3
RB1
N
O



LA628
RB4
RB1
N
O



LA629
RB7
RB1
N
O



LA630
RB10
RB1
N
O



LA631
RA3
RB1
N
O



LA632
RA34
RB1
N
O



LA633
H
RB1
N
NCH3



LA634
RB1
RB1
N
NCH3



LA635
RB3
RB1
N
NCH3



LA636
RB4
RB1
N
NCH3



LA637
RB7
RB1
N
NCH3



LA638
RB10
RB1
N
NCH3



LA639
RA3
RB1
N
NCH3



LA640
RA34
RB1
N
NCH3



LA641
H
RB1
N
C(CH3)2



LA642
RB1
RB1
N
C(CH3)2



LA643
RB3
RB1
N
C(CH3)2



LA644
RB4
RB1
N
C(CH3)2



LA645
RB7
RB1
N
C(CH3)2



LA646
RB10
RB1
N
C(CH3)2



LA647
RA3
RB1
N
C(CH3)2



LA648
RA34
RB1
N
C(CH3)2



LA649
H
RB1
N
Si(CH3)2



LA650
RB1
RB1
N
Si(CH3)2



LA651
RB3
RB1
N
Si(CH3)2



LA652
RB4
RB1
N
Si(CH3)2



LA653
RB7
RB1
N
Si(CH3)2



LA654
RB10
RB1
N
Si(CH3)2



LA655
RA3
RB1
N
Si(CH3)2



LA656
RA34
RB1
N
Si(CH3)2



LA657
H
RB2
N
S



LA658
RB1
RB2
N
S



LA659
RB3
RB2
N
S



LA660
RB4
RB2
N
S



LA661
RB7
RB2
N
S



LA662
RB10
RB2
N
S



LA663
RA3
RB2
N
S



LA664
RA34
RB2
N
S



LA665
H
RB2
N
O



LA666
RB1
RB2
N
O



LA667
RB3
RB2
N
O



LA668
RB4
RB2
N
O



LA669
RB7
RB2
N
O



LA670
RB10
RB2
N
O



LA671
RA3
RB2
N
O



LA672
RA34
RB2
N
O



LA673
H
RB2
N
NCH3



LA674
RB1
RB2
N
NCH3



LA675
RB3
RB2
N
NCH3



LA676
RB4
RB2
N
NCH3



LA677
RB7
RB2
N
NCH3



LA678
RB10
RB2
N
NCH3



LA679
RA3
RB2
N
NCH3



LA680
RA34
RB2
N
NCH3



LA681
H
RB2
N
C(CH3)2



LA682
RB1
RB2
N
C(CH3)2



LA683
RB3
RB2
N
C(CH3)2



LA684
RB4
RB2
N
C(CH3)2



LA685
RB7
RB2
N
C(CH3)2



LA686
RB10
RB2
N
C(CH3)2



LA687
RA3
RB2
N
C(CH3)2



LA688
RA34
RB2
N
C(CH3)2



LA689
H
RB2
N
Si(CH3)2



LA690
RB1
RB2
N
Si(CH3)2



LA691
RB3
RB2
N
Si(CH3)2



LA692
RB4
RB2
N
Si(CH3)2



LA693
RB7
RB2
N
Si(CH3)2



LA694
RB10
RB2
N
Si(CH3)2



LA695
RA3
RB2
N
Si(CH3)2



LA696
RA34
RB2
N
Si(CH3)2









wherein LA697 through LA816 have a structure of Formula VI:




wherein R2, R3, and Y are defined as provided below:


















Ligand
R2
R3
Y
Ligand
R1
R2
R14







LA697
H
H
S
LA757
RB1
RB4
NCH3


LA698
H
RB1
S
LA758
RB1
RB5
NCH3


LA699
H
RB2
S
LA759
RB1
RA34
NCH3


LA700
H
RB3
S
LA760
RB1
RA52
NCH3


LA701
H
RB4
S
LA761
RB1
H
C(CH3)2


LA702
H
RB5
S
LA762
RB1
RB1
C(CH3)2


LA703
H
RA34
S
LA763
RB1
RB2
C(CH3)2


LA704
H
RA52
S
LA764
RB1
RB3
C(CH3)2


LA705
H
H
O
LA765
RB1
RB4
C(CH3)2


LA706
H
RB1
O
LA766
RB1
RB5
C(CH3)2


LA707
H
RB2
O
LA767
RB1
RA34
C(CH3)2


LA708
H
RB3
O
LA768
RB1
RA52
C(CH3)2


LA709
H
RB4
O
LA769
RB1
H
Si(CH3)2


LA710
H
RB5
O
LA770
RB1
RB1
Si(CH3)2


LA711
H
RA34
O
LA771
RB1
RB2
Si(CH3)2


LA712
H
RA52
O
LA772
RB1
RB3
Si(CH3)2


LA713
H
H
NCH3
LA773
RB1
RB4
Si(CH3)2


LA714
H
RB1
NCH3
LA774
RB1
RB5
Si(CH3)2


LA715
H
RB2
NCH3
LA775
RB1
RA34
Si(CH3)2


LA716
H
RB3
NCH3
LA776
RB1
RA52
Si(CH3)2


LA717
H
RB4
NCH3
LA777
RB2
H
S


LA718
H
RB5
NCH3
LA778
RB2
RB1
S


LA719
H
RA34
NCH3
LA779
RB2
RB2
S


LA720
H
RA52
NCH3
LA780
RB2
RB3
S


LA721
H
H
C(CH3)2
LA781
RB2
RB4
S


LA722
H
RB1
C(CH3)2
LA782
RB2
RB5
S


LA723
H
RB2
C(CH3)2
LA783
RB2
RA34
S


LA724
H
RB3
C(CH3)2
LA784
RB2
RA52
S


LA725
H
RB4
C(CH3)2
LA785
RB2
H
O


LA726
H
RB5
C(CH3)2
LA786
RB2
RB1
O


LA727
H
RA34
C(CH3)2
LA787
RB2
RB2
O


LA728
H
RA52
C(CH3)2
LA788
RB2
RB3
O


LA729
H
H
Si(CH3)2
LA789
RB2
RB4
O


LA730
H
RB1
Si(CH3)2
LA790
RB2
RB5
O


LA731
H
RB2
Si(CH3)2
LA791
RB2
RA34
O


LA732
H
RB3
Si(CH3)2
LA792
RB2
RA52
O


LA733
H
RB4
Si(CH3)2
LA793
RB2
H
NCH3


LA734
H
RB5
Si(CH3)2
LA794
RB2
RB1
NCH3


LA735
H
RA34
Si(CH3)2
LA795
RB2
RB2
NCH3


LA736
H
RA52
Si(CH3)2
LA796
RB2
RB3
NCH3


LA737
RB1
H
S
LA797
RB2
RB4
NCH3


LA738
RB1
RB1
S
LA798
RB2
RB5
NCH3


LA739
RB1
RB2
S
LA799
RB2
RA34
NCH3


LA740
RB1
RB3
S
LA800
RB2
RA52
NCH3


LA741
RB1
RB4
S
LA801
RB2
H
C(CH3)2


LA742
RB1
RB5
S
LA802
RB2
RB1
C(CH3)2


LA743
RB1
RA34
S
LA803
RB2
RB2
C(CH3)2


LA744
RB1
RA52
S
LA804
RB2
RB3
C(CH3)2


LA745
RB1
H
O
LA805
RB2
RB4
C(CH3)2


LA746
RB1
RB1
O
LA806
RB2
RB5
C(CH3)2


LA747
RB1
RB2
O
LA807
RB2
RA34
C(CH3)2


LA748
RB1
RB3
O
LA808
RB2
RA52
C(CH3)2


LA749
RB1
RB4
O
LA809
RB2
H
Si(CH3)2


LA750
RB1
RB5
O
LA810
RB2
RB1
Si(CH3)2


LA751
RB1
RA34
O
LA811
RB2
RB2
Si(CH3)2


LA752
RB1
RA52
O
LA812
RB2
RB3
Si(CH3)2


LA753
RB1
H
NCH3
LA813
RB2
RB4
Si(CH3)2


LA754
RB1
RB1
NCH3
LA814
RB2
RB5
Si(CH3)2


LA755
RB1
RB2
NCH3
LA815
RB2
RA34
Si(CH3)2


LA756
RB1
RB3
NCH3
LA816
RB2
RA52
Si(CH3)2








wherein LA817 through LA912 have a structure of Formula VII:




wherein R2, R4, and Y are defined as provided below:


















Ligand
R2
R4
Y
Z









LA817
H
H
S
S



LA818
H
RB1
S
S



LA819
H
RB3
S
S



LA820
H
RB4
S
S



LA821
H
RB7
S
S



LA822
H
RB10
S
S



LA823
H
RA3
S
S



LA824
H
RA34
S
S



LA825
H
H
S
O



LA826
H
RB1
S
O



LA827
H
RB3
S
O



LA828
H
RB4
S
O



LA829
H
RB7
S
O



LA830
H
RB10
S
O



LA831
H
RA3
S
O



LA832
H
RA34
S
O



LA833
H
H
S
NCH3



LA834
H
RB1
S
NCH3



LA835
H
RB3
S
NCH3



LA836
H
RB4
S
NCH3



LA837
H
RB7
S
NCH3



LA838
H
RB10
S
NCH3



LA839
H
RA3
S
NCH3



LA840
H
RA34
S
NCH3



LA841
H
H
O
S



LA842
H
RB1
O
S



LA843
H
RB3
O
S



LA844
H
RB4
O
S



LA845
H
RB7
O
S



LA846
H
RB10
O
S



LA847
H
RA3
O
S



LA848
H
RA34
O
S



LA849
H
H
O
O



LA850
H
RB1
O
O



LA851
H
RB3
O
O



LA852
H
RB4
O
O



LA853
H
RB7
O
O



LA854
H
RB10
O
O



LA855
H
RA3
O
O



LA856
H
RA34
O
O



LA857
H
H
O
NCH3



LA858
H
RB1
O
NCH3



LA859
H
RB3
O
NCH3



LA860
H
RB4
O
NCH3



LA861
H
RB7
O
NCH3



LA862
H
RB10
O
NCH3



LA863
H
RA3
O
NCH3



LA864
H
RA34
O
NCH3



LA865
RB1
H
S
S



LA866
RB1
RB1
S
S



LA867
RB1
RB3
S
S



LA868
RB1
RB4
S
S



LA869
RB1
RB7
S
S



LA870
RB1
RB10
S
S



LA871
RB1
RA3
S
S



LA872
RB1
RA34
S
S



LA873
RB1
H
S
O



LA874
RB1
RB1
S
O



LA875
RB1
RB3
S
O



LA876
RB1
RB4
S
O



LA877
RB1
RB7
S
O



LA878
RB1
RB10
S
O



LA879
RB1
RA3
S
O



LA880
RB1
RA34
S
O



LA881
RB1
H
S
NCH3



LA882
RB1
RB1
S
NCH3



LA883
RB1
RB3
S
NCH3



LA884
RB1
RB4
S
NCH3



LA885
RB1
RB7
S
NCH3



LA886
RB1
RB10
S
NCH3



LA887
RB1
RA3
S
NCH3



LA888
RB1
RA34
S
NCH3



LA889
RB1
H
O
S



LA890
RB1
RB1
O
S



LA891
RB1
RB3
O
S



LA892
RB1
RB4
O
S



LA893
RB1
RB7
O
S



LA894
RB1
RB10
O
S



LA895
RB1
RA3
O
S



LA896
RB1
RA34
O
S



LA897
RB1
H
O
O



LA898
RB1
RB1
O
O



LA899
RB1
RB3
O
O



LA900
RB1
RB4
O
O



LA901
RB1
RB7
O
O



LA902
RB1
RB10
O
O



LA903
RB1
RA3
O
O



LA904
RB1
RA34
O
O



LA905
RB1
H
O
NCH3



LA906
RB1
RB1
O
NCH3



LA907
RB1
RB3
O
NCH3



LA908
RB1
RB4
O
NCH3



LA909
RB1
RB7
O
NCH3



LA910
RB1
RB10
O
NCH3



LA911
RB1
RA3
O
NCH3



LA912
RB1
RA34
O
NCH3









wherein LA913 through LA1152 have a structure of Formula VIII:




wherein R1, R2, Y, and X are defined as provided below:


















Ligand 
R1
R2
X
Y









LA913
H
H
C
S



LA914
RB1
H
C
S



LA915
RB3
H
C
S



LA916
RB4
H
C
S



LA917
RB7
H
C
S



LA918
RB10
H
C
S



LA919
RA3
H
C
S



LA920
RA34
H
C
S



LA921
H
H
C
O



LA922
RB1
H
C
O



LA923
RB3
H
C
O



LA924
RB4
H
C
O



LA925
RB7
H
C
O



LA926
RB10
H
C
O



LA927
RA3
H
C
O



LA928
RA34
H
C
O



LA929
H
H
C
NCH3



LA930
RB1
H
C
NCH3



LA931
RB3
H
C
NCH3



LA932
RB4
H
C
NCH3



LA933
RB7
H
C
NCH3



LA934
RB10
H
C
NCH3



LA935
RA3
H
C
NCH3



LA936
RA34
H
C
NCH3



LA937
H
H
C
C(CH3)2 



LA938
RB1
H
C
C(CH3)2



LA939
RB3
H
C
C(CH3)2



LA940
RB4
H
C
C(CH3)2



LA941
RB7
H
C
C(CH3)2



LA942
RB10
H
C
C(CH3)2



LA943
RA3
H
C
C(CH3)2



LA944
RA34
H
C
C(CH3)2



LA945
H
H
C
Si(CH3)2 



LA946
RB1
H
C
Si(CH3)2 



LA947
RB3
H
C
Si(CH3)2 



LA948
RB4
H
C
Si(CH3)2 



LA949
RB7
H
C
Si(CH3)2 



LA950
RB10
H
C
Si(CH3)2 



LA951
RA3
H
C
Si(CH3)2 



LA952
RA34
H
C
Si(CH3)2 



LA953
H
RB1
C
S



LA954
RB1
RB1
C
S



LA955
RB3
RB1
C
S



LA956
RB4
RB1
C
S



LA957
RB7
RB1
C
S



LA958
RB10
RB1
C
S



LA959
RA3
RB1
C
S



LA960
RA34
RB1
C
S



LA961
H
RB1
C
O



LA962
RB1
RB1
C
O



LA963
RB3
RB1
C
O



LA964
RB4
RB1
C
O



LA965
RB7
RB1
C
O



LA966
RB10
RB1
C
O



LA967
RA3
RB1
C
O



LA968
RA34
RB1
C
O



LA969
H
RB1
C
NCH3



LA970
RB1
RB1
C
NCH3



LA971
RB3
RB1
C
NCH3



LA972
RB4
RB1
C
NCH3



LA973
RB7
RB1
C
NCH3



LA974
RB10
RB1
C
NCH3



LA975
RA3
RB1
C
NCH3



LA976
RA34
RB1
C
NCH3



LA977
H
RB1
C
C(CH3)2



LA978
RB1
RB1
C
C(CH3)2



LA979
RB3
RB1
C
C(CH3)2



LA980
RB4
RB1
C
C(CH3)2



LA981
RB7
RB1
C
C(CH3)2



LA982
RB10
RB1
C
C(CH3)2



LA983
RA3
RB1
C
C(CH3)2



LA984
RA34
RB1
C
C(CH3)2



LA985
H
RB1
C
Si(CH3)2 



LA986
RB1
RB1
C
Si(CH3)2 



LA987
RB3
RB1
C
Si(CH3)2 



LA988
RB4
RB1
C
Si(CH3)2 



LA989
RB7
RB1
C
Si(CH3)2 



LA990
RB10
RB1
C
Si(CH3)2 



LA991
RA3
RB1
C
Si(CH3)2 



LA992
RA34
RB1
C
Si(CH3)2 



LA993
H
RB2
C
S



LA994
RB1
RB2
C
S



LA995
RB3
RB2
C
S



LA996
RB4
RB2
C
S



LA997
RB7
RB2
C
S



LA998
RB10
RB2
C
S



LA999
RA3
RB2
C
S



LA1000
RA34
RB2
C
S



LA1001
H
RB2
C
O



LA1002
RB1
RB2
C
O



LA1003
RB3
RB2
C
O



LA1004
RB4
RB2
C
O



LA1005
RB7
RB2
C
O



LA1006
RB10
RB2
C
O



LA1007
RA3
RB2
C
O



LA1008
RA34
RB2
C
O



LA1009
H
RB2
C
NCH3



LA1010
RB1
RB2
C
NCH3



LA1011
RB3
RB2
C
NCH3



LA1012
RB4
RB2
C
NCH3



LA1013
RB7
RB2
C
NCH3



LA1014
RB10
RB2
C
NCH3



LA1015
RA3
RB2
C
NCH3



LA1016
RA34
RB2
C
NCH3



LA1017
H
RB2
C
C(CH3)2



LA1018
RB1
RB2
C
C(CH3)2



LA1019
RB3
RB2
C
C(CH3)2



LA1020
RB4
RB2
C
C(CH3)2



LA1021
RB7
RB2
C
C(CH3)2



LA1022
RB10
RB2
C
C(CH3)2



LA1023
RA3
RB2
C
C(CH3)2



LA1024
RA34
RB2
C
C(CH3)2



LA1025
H
RB2
C
Si(CH3)2 



LA1026
RB1
RB2
C
Si(CH3)2 



LA1027
RB3
RB2
C
Si(CH3)2 



LA1028
RB4
RB2
C
Si(CH3)2 



LA1029
RB7
RB2
C
Si(CH3)2 



LA1030
RB10
RB2
C
Si(CH3)2 



LA1031
RA3
RB2
C
Si(CH3)2 



LA1032
RA34
RB2
C
Si(CH3)2 



LA1033
H
H
N
S



LA1034 
RB1
H
N
S



LA1035
RB3
H
N
S



LA1036 
RB4
H
N
S



LA1037
RB7
H
N
S



LA1038
RB10
H
N
S



LA1039 
RA3
H
N
S



LA1040
RA34
H
N
S



LA1041
H
H
N
O



LA1042 
RB1
H
N
O



LA1043 
RB3
H
N
O



LA1044
RB4
H
N
O



LA1045 
RB7
H
N
O



LA1046 
RB10
H
N
O



LA1047 
RA3
H
N
O



LA1048
RA34
H
N
O



LA1049 
H
H
N
NCH3



LA1050
RB1
H
N
NCH3



LA1051
RB3
H
N
NCH3



LA1052
RB4
H
N
NCH3



LA1053
RB7
H
N
NCH3



LA1054 
RB10
H
N
NCH3



LA1055
RA3
H
N
NCH3



LA1056 
RA34
H
N
NCH3



LA1057
H
H
N
C(CH3)2



LA1058
RB1
H
N
C(CH3)2



LA1059
RB3
H
N
C(CH3)2



LA1060
RB4
H
N
C(CH3)2



LA1061
RB7
H
N
C(CH3)2



LA1062
RB10
H
N
C(CH3)2



LA1063
RA3
H
N
C(CH3)2



LA1064
RA34
H
N
C(CH3)2



LA1065
H
H
N
Si(CH3)2



LA1066
RB1
H
N
Si(CH3)2



LA1067
RB3
H
N
Si(CH3)2



LA1068
RB4
H
N
Si(CH3)2



LA1069
RB7
H
N
Si(CH3)2



LA1070
RB10
H
N
Si(CH3)2



LA1071
RA3
H
N
Si(CH3)2



LA1072
RA34
H
N
Si(CH3)2



LA1073
H
RB1
N
S



LA1074
RB1
RB1
N
S



LA1075
RB3
RB1
N
S



LA1076
RB4
RB1
N
S



LA1077
RB7
RB1
N
S



LA1078
RB10
RB1
N
S



LA1079
RA3
RB1
N
S



LA1080
RA34
RB1
N
S



LA1081
H
RB1
N
O



LA1082
RB1
RB1
N
O



LA1083
RB3
RB1
N
O



LA1084
RB4
RB1
N
O



LA1085
RB7
RB1
N
O



LA1086
RB10
RB1
N
O



LA1087
RA3
RB1
N
O



LA1088
RA34
RB1
N
O



LA1089
H
RB1
N
NCH3



LA1090
RB1
RB1
N
NCH3



LA1091
RB3
RB1
N
NCH3



LA1092
RB4
RB1
N
NCH3



LA1093
RB7
RB1
N
NCH3



LA1094
RB10
RB1
N
NCH3



LA1095
RA3
RB1
N
NCH3



LA1096
RA34
RB1
N
NCH3



LA1097
H
RB1
N
C(CH3)2



LA1098
RB1
RB1
N
C(CH3)2



LA1099
RB3
RB1
N
C(CH3)2



LA1100
RB4
RB1
N
C(CH3)2



LA1101
RB7
RB1
N
C(CH3)2



LA1102
RB10
RB1
N
C(CH3)2



LA1103
RA3
RB1
N
C(CH3)2



LA1104
RA34
RB1
N
C(CH3)2



LA1105
H
RB1
N
Si(CH3)2



LA1106
RB1
RB1
N
Si(CH3)2



LA1107
RB3
RB1
N
Si(CH3)2



LA1108
RB4
RB1
N
Si(CH3)2



LA1109
RB7
RB1
N
Si(CH3)2



LA1110
RB10
RB1
N
Si(CH3)2



LA1111
RA3
RB1
N
Si(CH3)2



LA1112
RA34
RB1
N
Si(CH3)2



LA1113
H
RB2
N
S



LA1114
RB1
RB2
N
S



LA1115
RB3
RB2
N
S



LA1116
RB4
RB2
N
S



LA1117
RB7
RB2
N
S



LA1118
RB10
RB2
N
S



LA1119
RA3
RB2
N
S



LA1120
RA34
RB2
N
S



LA1121
H
RB2
N
O



LA1122
RB1
RB2
N
O



LA1123
RB3
RB2
N
O



LA1124
RB4
RB2
N
O



LA1125
RB7
RB2
N
O



LA1126
RB10
RB2
N
O



LA1127
RA3
RB2
N
O



LA1128
RA34
RB2
N
O



LA1129
H
RB2
N
NCH3



LA1130
RB1
RB2
N
NCH3



LA1131
RB3
RB2
N
NCH3



LA1132
RB4
RB2
N
NCH3



LA1133
RB7
RB2
N
NCH3



LA1134
RB10
RB2
N
NCH3



LA1135
RA3
RB2
N
NCH3



LA1136
RA34
RB2
N
NCH3



LA1137
H
RB2
N
C(CH3)2



LA1138
RB1
RB2
N
C(CH3)2



LA1139
RB3
RB2
N
C(CH3)2



LA1140
RB4
RB2
N
C(CH3)2



LA1141
RB7
RB2
N
C(CH3)2



LA1142
RB10
RB2
N
C(CH3)2



LA1143
RA3
RB2
N
C(CH3)2



LA1144
RA34
RB2
N
C(CH3)2



LA1145
H
RB2
N
Si(CH3)2



LA1146
RB1
RB2
N
Si(CH3)2



LA1147
RB3
RB2
N
Si(CH3)2



LA1148
RB4
RB2
N
Si(CH3)2



LA1149
RB7
RB2
N
Si(CH3)2



LA1150
RB10
RB2
N
Si(CH3)2



LA1151
RA3
RB2
N
Si(CH3)2



LA1152
RA34
RB2
N
Si(CH3)2









wherein LA1153 through LA1272 have a structure of Formula IX:




wherein R2, R3, and Y are defined as provided below:


















Ligand
R2
R3
Y
Ligand
R1
R2
R14







LA1153
H
H
S
LA1213
RB1
RB4
NCH3


LA1154
H
RB1
S
LA1214
RB1
RB5
NCH3


LA1155
H
RB2
S
LA1215
RB1
RA34
NCH3


LA1156
H
RB3
S
LA1216
RB1
RA52
NCH3


LA1157
H
RB4
S
LA1217
RB1
H
C(CH3)2


LA1158
H
RB5
S
LA1218
RB1
RB1
C(CH3)2


LA1159
H
RA34
S
LA1219
RB1
RB2
C(CH3)2


LA1160
H
RA52
S
LA1220
RB1
RB3
C(CH3)2


LA1161
H
H
O
LA1221
RB1
RB4
C(CH3)2


LA1162
H
RB1
O
LA1222
RB1
RB5
C(CH3)2


LA1163
H
RB2
O
LA1223
RB1
RA34
C(CH3)2


LA1164
H
RB3
O
LA1224
RB1
RA52
C(CH3)2


LA1165
H
RB4
O
LA1225
RB1
H
Si(CH3)2


LA1166
H
RB5
O
LA1226
RB1
RB1
Si(CH3)2


LA1167
H
RA34
O
LA1227
RB1
RB2
Si(CH3)2


LA1168
H
RA52
O
LA1228
RB1
RB3
Si(CH3)2


LA1169
H
H
NCH3
LA1229
RB1
RB4
Si(CH3)2


LA1170
H
RB1
NCH3
LA1230
RB1
RB5
Si(CH3)2


LA1171
H
RB2
NCH3
LA1231
RB1
RA34
Si(CH3)2


LA1172
H
RB3
NCH3
LA1232
RB1
RA52
Si(CH3)2


LA1173
H
RB4
NCH3
LA1233
RB2
H
S


LA1174
H
RB5
NCH3
LA1234
RB2
RB1
S


LA1175
H
RA34
NCH3
LA1235
RB2
RB2
S


LA1176
H
RA52
NCH3
LA1236
RB2
RB3
S


LA1177
H
H
C(CH3)2
LA1237
RB2
RB4
S


LA1178
H
RB1
C(CH3)2
LA1238
RB2
RB5
S


LA1179
H
RB2
C(CH3)2
LA1239
RB2
RA34
S


LA1180
H
RB3
C(CH3)2
LA1240
RB2
RA52
S


LA1181
H
RB4
C(CH3)2
LA1241
RB2
H
O


LA1182
H
RB5
C(CH3)2
LA1242
RB2
RB1
O


LA1183
H
RA34
C(CH3)2
LA1243
RB2
RB2
O


LA1184
H
RA52
C(CH3)2
LA1244
RB2
RB3
O


LA1185
H
H
Si(CH3)2
LA1245
RB2
RB4
O


LA1186
H
RB1
Si(CH3)2
LA1246
RB2
RB5
O


LA1187
H
RB2
Si(CH3)2
LA1247
RB2
RA34
O


LA1188
H
RB3
Si(CH3)2
LA1248
RB2
RA52
O


LA1189
H
RB4
Si(CH3)2
LA1249
RB2
H
NCH3


LA1190
H
RB5
Si(CH3)2
LA1250
RB2
RB1
NCH3


LA1191
H
RA34
Si(CH3)2
LA1251
RB2
RB2
NCH3


LA1192
H
RA52
Si(CH3)2
LA1252
RB2
RB3
NCH3


LA1193
RB1
H
S
LA1253
RB2
RB4
NCH3


LA1194
RB1
RB1
S
LA1254
RB2
RB5
NCH3


LA1195
RB1
RB2
S
LA1255
RB2
RA34
NCH3


LA1196
RB1
RB3
S
LA1256
RB2
RA52
NCH3


LA1197
RB1
RB4
S
LA1257
RB2
H
C(CH3)2


LA1198
RB1
RB5
S
LA1258
RB2
RB1
C(CH3)2


LA1199
RB1
RA34
S
LA1259
RB2
RB2
C(CH3)2


LA1200
RB1
RA52
S
LA1260
RB2
RB3
C(CH3)2


LA1201
RB1
H
O
LA1261
RB2
RB4
C(CH3)2


LA1202
RB1
RB1
O
LA1262
RB2
RB5
C(CH3)2


LA1203
RB1
RB2
O
LA1263
RB2
RA34
C(CH3)2


LA1204
RB1
RB3
O
LA1264
RB2
RA52
C(CH3)2


LA1205
RB1
RB4
O
LA1265
RB2
H
Si(CH3)2


LA1206
RB1
RB5
O
LA1266
RB2
RB1
Si(CH3)2


LA1207
RB1
RA34
O
LA1267
RB2
RB2
Si(CH3)2


LA1208
RB1
RA52
O
LA1268
RB2
RB3
Si(CH3)2


LA1209
RB1
H
NCH3
LA1269
RB2
RB4
Si(CH3)2


LA1210
RB1
RB1
NCH3
LA1270
RB2
RB5
Si(CH3)2


LA1211
RB1
RB2
NCH3
LA1271
RB2
RA34
Si(CH3)2


LA1212
RB1
RB3
NCH3
LA1272
RB2
RA52
Si(CH3)2








wherein LA1273 through LA1368 have a structure of Formula X:




wherein R2, R4, Y, and Z are defined as provided below:


















Ligand
R2
R4
Y
Z









LA1273
H
H
S
S



LA1274
H
RB1
S
S



LA1275
H
RB3
S
S



LA1276
H
RB4
S
S



LA1277
H
RB7
S
S



LA1278
H
RB10
S
S



LA1279
H
RA3
S
S



LA1280
H
RA34
S
S



LA1281
H
H
S
O



LA1282
H
RB1
S
O



LA1283
H
RB3
S
O



LA1284
H
RB4
S
O



LA1285
H
RB7
S
O



LA1286
H
RB10
S
O



LA1287
H
RA3
S
O



LA1288
H
RA34
S
O



LA1289
H
H
S
NCH3



LA1290
H
RB1
S
NCH3



LA1291
H
RB3
S
NCH3



LA1292
H
RB4
S
NCH3



LA1293
H
RB7
S
NCH3



LA1294
H
RB10
S
NCH3



LA1295
H
RA3
S
NCH3



LA1296
H
RA34
S
NCH3



LA1297
H
H
O
S



LA1298
H
RB1
O
S



LA1299
H
RB3
O
S



LA1300
H
RB4
O
S



LA1301
H
RB7
O
S



LA1302
H
RB10
O
S



LA1303
H
RA3
O
S



LA1304
H
RA34
O
S



LA1305
H
H
O
O



LA1306
H
RB1
O
O



LA1307
H
RB3
O
O



LA1308
H
RB4
O
O



LA1309
H
RB7
O
O



LA1310
H
RB10
O
O



LA1311
H
RA3
O
O



LA1312
H
RA34
O
O



LA1313
H
H
O
NCH3



LA1314
H
RB1
O
NCH3



LA1315
H
RB3
O
NCH3



LA1316
H
RB4
O
NCH3



LA1317
H
RB7
O
NCH3



LA1318
H
RB10
O
NCH3



LA1319
H
RA3
O
NCH3



LA1320
H
RA34
O
NCH3



LA1321
RB1
H
S
S



LA1322
RB1
RB1
S
S



LA1323
RB1
RB3
S
S



LA1324
RB1
RB4
S
S



LA1325
RB1
RB7
S
S



LA1326
RB1
RB10
S
S



LA1327
RB1
RA3
S
S



LA1328
RB1
RA34
S
S



LA1329
RB1
H
S
O



LA1330
RB1
RB1
S
O



LA1331
RB1
RB3
S
O



LA1332
RB1
RB4
S
O



LA1333
RB1
RB7
S
O



LA1334
RB1
RB10
S
O



LA1335
RB1
RA3
S
O



LA1336
RB1
RA34
S
O



LA1337
RB1
H
S
NCH3



LA1338
RB1
RB1
S
NCH3



LA1339
RB1
RB3
S
NCH3



LA1340
RB1
RB4
S
NCH3



LA1341
RB1
RB7
S
NCH3



LA1342
RB1
RB10
S
NCH3



LA1343
RB1
RA3
S
NCH3



LA1344
RB1
RA34
S
NCH3



LA1345
RB1
H
O
S



LA1346
RB1
RB1
O
S



LA1347
RB1
RB3
O
S



LA1348
RB1
RB4
O
S



LA1349
RB1
RB7
O
S



LA1350
RB1
RB10
O
S



LA1351
RB1
RA3
O
S



LA1352
RB1
RA34
O
S



LA1353
RB1
H
O
O



LA1354
RB1
RB1
O
O



LA1355
RB1
RB3
O
O



LA1356
RB1
RB4
O
O



LA1357
RB1
RB7
O
O



LA1358
RB1
RB10
O
O



LA1359
RB1
RA3
O
O



LA1360
RB1
RA34
O
O



LA1361
RB1
H
O
NCH3



LA1362
RB1
RB1
O
NCH3



LA1363
RB1
RB3
O
NCH3



LA1364
RB1
RB4
O
NCH3



LA1365
RB1
RB7
O
NCH3



LA1366
RB1
RB10
O
NCH3



LA1367
RB1
RA3
O
NCH3



LA1368
RB1
RA34
O
NCH3









wherein LA1369 through LA1608 have a structure of Formula XI:




wherein R1, R2, X, and Y are defined as provided below:


















Ligand
R1
R2
X
Y









LA1369
H
H
C
S



LA1370
RB1
H
C
S



LA1371
RB3
H
C
S



LA1372
RB4
H
C
S



LA1373
RB7
H
C
S



LA1374
RB10
H
C
S



LA1375
RA3
H
C
S



LA1376
RA34
H
C
S



LA1377
H
H
C
O



LA1378
RB1
H
C
O



LA1379
RB3
H
C
O



LA1380
RB4
H
C
O



LA1381
RB7
H
C
O



LA1382
RB10
H
C
O



LA1383
RA3
H
C
O



LA1384
RA34
H
C
O



LA1385
H
H
C
NCH3



LA1386
RB1
H
C
NCH3



LA1387
RB3
H
C
NCH3



LA1388
RB4
H
C
NCH3



LA1389
RB7
H
C
NCH3



LA1390
RB10
H
C
NCH3



LA1391
RA3
H
C
NCH3



LA1392
RA34
H
C
NCH3



LA1393
H
H
C
C(CH3)2



LA1394
RB1
H
C
C(CH3)2



LA1395
RB3
H
C
C(CH3)2



LA1396
RB4
H
C
C(CH3)2



LA1397
RB7
H
C
C(CH3)2



LA1398
RB10
H
C
C(CH3)2



LA1399
RA3
H
C
C(CH3)2



LA1400
RA34
H
C
C(CH3)2



LA1401
H
H
C
Si(CH3)2



LA1402
RB1
H
C
Si(CH3)2



LA1403
RB3
H
C
Si(CH3)2



LA1404
RB4
H
C
Si(CH3)2



LA1405
RB7
H
C
Si(CH3)2



LA1406
RB10
H
C
Si(CH3)2



LA1407
RA3
H
C
Si(CH3)2



LA1408
RA34
H
C
Si(CH3)2



LA1409
H
RB1
C
S



LA1410
RB1
RB1
C
S



LA1411
RB3
RB1
C
S



LA1412
RB4
RB1
C
S



LA1413
RB7
RB1
C
S



LA1414
RB10
RB1
C
S



LA1415
RA3
RB1
C
S



LA1416
RA34
RB1
C
S



LA1417
H
RB1
C
O



LA1418
RB1
RB1
C
O



LA1419
RB3
RB1
C
O



LA1420
RB4
RB1
C
O



LA1421
RB7
RB1
C
O



LA1422
RB10
RB1
C
O



LA1423
RA3
RB1
C
O



LA1424
RA34
RB1
C
O



LA1425
H
RB1
C
NCH3



LA1426
RB1
RB1
C
NCH3



LA1427
RB3
RB1
C
NCH3



LA1428
RB4
RB1
C
NCH3



LA1429
RB7
RB1
C
NCH3



LA1430
RB10
RB1
C
NCH3



LA1431
RA3
RB1
C
NCH3



LA1432
RA34
RB1
C
NCH3



LA1433
H
RB1
C
C(CH3)2



LA1434
RB1
RB1
C
C(CH3)2



LA1435
RB3
RB1
C
C(CH3)2



LA1436
RB4
RB1
C
C(CH3)2



LA1437
RB7
RB1
C
C(CH3)2



LA1438
RB10
RB1
C
C(CH3)2



LA1439
RA3
RB1
C
C(CH3)2



LA1440
RA34
RB1
C
C(CH3)2



LA1441
H
RB1
C
Si(CH3)2



LA1442
RB1
RB1
C
Si(CH3)2



LA1443
RB3
RB1
C
Si(CH3)2



LA1444
RB4
RB1
C
Si(CH3)2



LA1445
RB7
RB1
C
Si(CH3)2



LA1446
RB10
RB1
C
Si(CH3)2



LA1447
RA3
RB1
C
Si(CH3)2



LA1448
RA34
RB1
C
Si(CH3)2



LA1449
H
RB2
C
S



LA1450
RB1
RB2
C
S



LA1451
RB3
RB2
C
S



LA1452
RB4
RB2
C
S



LA1453
RB7
RB2
C
S



LA1454
RB10
RB2
C
S



LA1455
RA3
RB2
C
S



LA1456
RA34
RB2
C
S



LA1457
H
RB2
C
O



LA1458
RB1
RB2
C
O



LA1459
RB3
RB2
C
O



LA1460
RB4
RB2
C
O



LA1461
RB7
RB2
C
O



LA1462
RB10
RB2
C
O



LA1463
RA3
RB2
C
O



LA1464
RA34
RB2
C
O



LA1465
H
RB2
C
NCH3



LA1466
RB1
RB2
C
NCH3



LA1467
RB3
RB2
C
NCH3



LA1468
RB4
RB2
C
NCH3



LA1469
RB7
RB2
C
NCH3



LA1470
RB10
RB2
C
NCH3



LA1471
RA3
RB2
C
NCH3



LA1472
RA34
RB2
C
NCH3



LA1473
H
RB2
C
C(CH3)2



LA1474
RB1
RB2
C
C(CH3)2



LA1475
RB3
RB2
C
C(CH3)2



LA1476
RB4
RB2
C
C(CH3)2



LA1477
RB7
RB2
C
C(CH3)2



LA1478
RB10
RB2
C
C(CH3)2



LA1479
RA3
RB2
C
C(CH3)2



LA1480
RA34
RB2
C
C(CH3)2



LA1481
H
RB2
C
Si(CH3)2



LA1482
RB1
RB2
C
Si(CH3)2



LA1483
RB3
RB2
C
Si(CH3)2



LA1484
RB4
RB2
C
Si(CH3)2



LA1485
RB7
RB2
C
Si(CH3)2



LA1486
RB10
RB2
C
Si(CH3)2



LA1487
RA3
RB2
C
Si(CH3)2



LA1488
RA34
RB2
C
Si(CH3)2



LA1489
H
H
N
S



LA1490
RB1
H
N
S



LA1491
RB3
H
N
S



LA1492
RB4
H
N
S



LA1493
RB7
H
N
S



LA1494
RB10
H
N
S



LA1495
RA3
H
N
S



LA1496
RA34
H
N
S



LA1497
H
H
N
O



LA1498
RB1
H
N
O



LA1499
RB3
H
N
O



LA1500
RB4
H
N
O



LA1501
RB7
H
N
O



LA1502
RB10
H
N
O



LA1503
RA3
H
N
O



LA1504
RA34
H
N
O



LA1505
H
H
N
NCH3



LA1506
RB1
H
N
NCH3



LA1507
RB3
H
N
NCH3



LA1508
RB4
H
N
NCH3



LA1509
RB7
H
N
NCH3



LA1510
RB10
H
N
NCH3



LA1511
RA3
H
N
NCH3



LA1512
RA34
H
N
NCH3



LA1513
H
H
N
C(CH3)2



LA1514
RB1
H
N
C(CH3)2



LA1515
RB3
H
N
C(CH3)2



LA1516
RB4
H
N
C(CH3)2



LA1517
RB7
H
N
C(CH3)2



LA1518
RB10
H
N
C(CH3)2



LA1519
RA3
H
N
C(CH3)2



LA1520
RA34
H
N
C(CH3)2



LA1521
H
H
N
Si(CH3)2



LA1522
RB1
H
N
Si(CH3)2



LA1523
RB3
H
N
Si(CH3)2



LA1524
RB4
H
N
Si(CH3)2



LA1525
RB7
H
N
Si(CH3)2



LA1526
RB10
H
N
Si(CH3)2



LA1527
RA3
H
N
Si(CH3)2



LA1528
RA34
H
N
Si(CH3)2



LA1529
H
RB1
N
S



LA1530
RB1
RB1
N
S



LA1531
RB3
RB1
N
S



LA1532
RB4
RB1
N
S



LA1533
RB7
RB1
N
S



LA1534
RB10
RB1
N
S



LA1535
RA3
RB1
N
S



LA1536
RA34
RB1
N
S



LA1537
H
RB1
N
O



LA1538
RB1
RB1
N
O



LA1539
RB3
RB1
N
O



LA1540
RB4
RB1
N
O



LA1541
RB7
RB1
N
O



LA1542
RB10
RB1
N
O



LA1543
RA3
RB1
N
O



LA1544
RA34
RB1
N
O



LA1545
H
RB1
N
NCH3



LA1546
RB1
RB1
N
NCH3



LA1547
RB3
RB1
N
NCH3



LA1548
RB4
RB1
N
NCH3



LA1549
RB7
RB1
N
NCH3



LA1550
RB10
RB1
N
NCH3



LA1551
RA3
RB1
N
NCH3



LA1552
RA34
RB1
N
NCH3



LA1553
H
RB1
N
C(CH3)2



LA1554
RB1
RB1
N
C(CH3)2



LA1555
RB3
RB1
N
C(CH3)2



LA1556
RB4
RB1
N
C(CH3)2



LA1557
RB7
RB1
N
C(CH3)2



LA1558
RB10
RB1
N
C(CH3)2



LA1559
RA3
RB1
N
C(CH3)2



LA1560
RA34
RB1
N
C(CH3)2



LA1561
H
RB1
N
Si(CH3)2



LA1562
RB1
RB1
N
Si(CH3)2



LA1563
RB3
RB1
N
Si(CH3)2



LA1564
RB4
RB1
N
Si(CH3)2



LA1565
RB7
RB1
N
Si(CH3)2



LA1566
RB10
RB1
N
Si(CH3)2



LA1567
RA3
RB1
N
Si(CH3)2



LA1568
RA34
RB1
N
Si(CH3)2



LA1569
H
RB2
N
S



LA1570
RB1
RB2
N
S



LA1571
RB3
RB2
N
S



LA1572
RB4
RB2
N
S



LA1573
RB7
RB2
N
S



LA1574
RB10
RB2
N
S



LA1575
RA3
RB2
N
S



LA1576
RA34
RB2
N
S



LA1577
H
RB2
N
O



LA1578
RB1
RB2
N
O



LA1579
RB3
RB2
N
O



LA1580
RB4
RB2
N
O



LA1581
RB7
RB2
N
O



LA1582
RB10
RB2
N
O



LA1583
RA3
RB2
N
O



LA1584
RA34
RB2
N
O



LA1585
H
RB2
N
NCH3



LA1586
RB1
RB2
N
NCH3



LA1587
RB3
RB2
N
NCH3



LA1588
RB4
RB2
N
NCH3



LA1589
RB7
RB2
N
NCH3



LA1590
RB10
RB2
N
NCH3



LA1591
RA3
RB2
N
NCH3



LA1592
RA34
RB2
N
NCH3



LA1593
H
RB2
N
C(CH3)2



LA1594
RB1
RB2
N
C(CH3)2



LA1595
RB3
RB2
N
C(CH3)2



LA1596
RB4
RB2
N
C(CH3)2



LA1597
RB7
RB2
N
C(CH3)2



LA1598
RB10
RB2
N
C(CH3)2



LA1599
RA3
RB2
N
C(CH3)2



LA1600
RA34
RB2
N
C(CH3)2



LA1601
H
RB2
N
Si(CH3)2



LA1602
RB1
RB2
N
Si(CH3)2



LA1603
RB3
RB2
N
Si(CH3)2



LA1604
RB4
RB2
N
Si(CH3)2



LA1605
RB7
RB2
N
Si(CH3)2



LA1606
RB10
RB2
N
Si(CH3)2



LA1607
RA3
RB2
N
Si(CH3)2



LA1608
RA34
RB2
N
Si(CH3)2









wherein LA1609 through LA1728 have a structure of Formula XII:




wherein R2, R3, and Y are defined as provided below:

















Ligand
R2
R3
Y









LA1609
H
H
S



LA1610
H
RB1
S



LA1611
H
RB2
S



LA1612
H
RB3
S



LA1613
H
RB4
S



LA1614
H
RB5
S



LA1615
H
RA34
S



LA1616
H
RA52
S



LA1617
H
H
O



LA1618
H
RB1
O



LA1619
H
RB2
O



LA1620
H
RB3
O



LA1621
H
RB4
O



LA1622
H
RB5
O



LA1623
H
RA34
O



LA1624
H
RA52
O



LA1625
H
H
NCH3



LA1626
H
RB1
NCH3



LA1627
H
RB2
NCH3



LA1628
H
RB3
NCH3



LA1629
H
RB4
NCH3



LA1630
H
RB5
NCH3



LA1631
H
RA34
NCH3



LA1632
H
RA52
NCH3



LA1633
H
H
C(CH3)2



LA1634
H
RB1
C(CH3)2



LA1635
H
RB2
C(CH3)2



LA1636
H
RB3
C(CH3)2



LA1637
H
RB4
C(CH3)2



LA1638
H
RB5
C(CH3)2



LA1639
H
RA34
C(CH3)2



LA1640
H
RA52
C(CH3)2



LA1641
H
H
Si(CH3)2



LA1642
H
RB1
Si(CH3)2



LA1643
H
RB2
Si(CH3)2



LA1644
H
RB3
Si(CH3)2



LA1645
H
RB4
Si(CH3)2



LA1646
H
RB5
Si(CH3)2



LA1647
H
RA34
Si(CH3)2



LA1648
H
RA52
Si(CH3)2



LA1649
RB1
H
S



LA1650
RB1
RB1
S



LA1651
RB1
RB2
S



LA1652
RB1
RB3
S



LA1653
RB1
RB4
S



LA1654
RB1
RB5
S



LA1655
RB1
RA34
S



LA1656
RB1
RA52
S



LA1657
RB1
H
O



LA1658
RB1
RB1
O



LA1659
RB1
RB2
O



LA1660
RB1
RB3
O



LA1661
RB1
RB4
O



LA1662
RB1
RB5
O



LA1663
RB1
RA34
O



LA1664
RB1
RA52
O



LA1665
RB1
H
NCH3



LA1666
RB1
RB1
NCH3



LA1667
RB1
RB2
NCH3



LA1668
RB1
RB3
NCH3



LA1669
RB1
RB4
NCH3



LA1670
RB1
RB5
NCH3



LA1671
RB1
RA34
NCH3



LA1672
RB1
RA52
NCH3



LA1673
RB1
H
C(CH3)2



LA1674
RB1
RB1
C(CH3)2



LA1675
RB1
RB2
C(CH3)2



LA1676
RB1
RB3
C(CH3)2



LA1677
RB1
RB4
C(CH3)2



LA1678
RB1
RB5
C(CH3)2



LA1679
RB1
RA34
C(CH3)2



LA1680
RB1
RA52
C(CH3)2



LA1681
RB1
H
Si(CH3)2



LA1682
RB1
RB1
Si(CH3)2



LA1683
RB1
RB2
Si(CH3)2



LA1684
RB1
RB3
Si(CH3)2



LA1685
RB1
RB4
Si(CH3)2



LA1686
RB1
RB5
Si(CH3)2



LA1687
RB1
RA34
Si(CH3)2



LA1688
RB1
RA52
Si(CH3)2



LA1689
RB2
H
S



LA1690
RB2
RB1
S



LA1691
RB2
RB2
S



LA1692
RB2
RB3
S



LA1693
RB2
RB4
S



LA1694
RB2
RB5
S



LA1695
RB2
RA34
S



LA1696
RB2
RA52
S



LA1697
RB2
H
O



LA1698
RB2
RB1
O



LA1699
RB2
RB2
O



LA1700
RB2
RB3
O



LA1701
RB2
RB4
O



LA1702
RB2
RB5
O



LA1703
RB2
RA34
O



LA1704
RB2
RA52
O



LA1705
RB2
H
NCH3



LA1706
RB2
RB1
NCH3



LA1707
RB2
RB2
NCH3



LA1708
RB2
RB3
NCH3



LA1709
RB2
RB4
NCH3



LA1710
RB2
RB5
NCH3



LA1711
RB2
RA34
NCH3



LA1712
RB2
RA52
NCH3



LA1713
RB2
H
C(CH3)2



LA1714
RB2
RB1
C(CH3)2



LA1715
RB2
RB2
C(CH3)2



LA1716
RB2
RB3
C(CH3)2



LA1717
RB2
RB4
C(CH3)2



LA1718
RB2
RB5
C(CH3)2



LA1719
RB2
RA34
C(CH3)2



LA1720
RB2
RA52
C(CH3)2



LA1721
RB2
H
Si(CH3)2



LA1722
RB2
RB1
Si(CH3)2



LA1723
RB2
RB2
Si(CH3)2



LA1724
RB2
RB3
Si(CH3)2



LA1725
RB2
RB4
Si(CH3)2



LA1726
RB2
RB5
Si(CH3)2



LA1727
RB2
RA34
Si(CH3)2



LA1728
RB2
RA52
Si(CH3)2









wherein LA1729 through LA1824 have a structure of Formula XIII:




wherein R2, R4, Y, and Z are defined as provided below:


















Ligand
R2
R4
Y
Z









LA1729
H
H
S
S



LA1730
H
RB1
S
S



LA1731
H
RB3
S
S



LA1732
H
RB4
S
S



LA1733
H
RB7
S
S



LA1734
H
RB10
S
S



LA1735
H
RA3
S
S



LA1736
H
RA34
S
S



LA1737
H
H
S
O



LA1738
H
RB1
S
O



LA1739
H
RB3
S
O



LA1740
H
RB4
S
O



LA1741
H
RB7
S
O



LA1742
H
RB10
S
O



LA1743
H
RA3
S
O



LA1744
H
RA34
S
O



LA1745
H
H
S
NCH3



LA1746
H
RB1
S
NCH3



LA1747
H
RB3
S
NCH3



LA1748
H
RB4
S
NCH3



LA1749
H
RB7
S
NCH3



LA1750
H
RB10
S
NCH3



LA1751
H
RA3
S
NCH3



LA1752
H
RA34
S
NCH3



LA1753
H
H
O
S



LA1754
H
RB1
O
S



LA1755
H
RB3
O
S



LA1756
H
RB4
O
S



LA1757
H
RB7
O
S



LA1758
H
RB10
O
S



LA1759
H
RA3
O
S



LA1760
H
RA34
O
S



LA1761
H
H
O
O



LA1762
H
RB1
O
O



LA1763
H
RB3
O
O



LA1764
H
RB4
O
O



LA1765
H
RB7
O
O



LA1766
H
RB10
O
O



LA1767
H
RA3
O
O



LA1768
H
RA34
O
O



LA1769
H
H
O
NCH3



LA1770
H
RB1
O
NCH3



LA1771
H
RB3
O
NCH3



LA1772
H
RB4
O
NCH3



LA1773
H
RB7
O
NCH3



LA1774
H
RB10
O
NCH3



LA1775
H
RA3
O
NCH3



LA1776
H
RA34
O
NCH3



LA1777
RB1
H
S
S



LA1778
RB1
RB1
S
S



LA1779
RB1
RB3
S
S



LA1780
RB1
RB4
S
S



LA1781
RB1
RB7
S
S



LA1782
RB1
RB10
S
S



LA1783
RB1
RA3
S
S



LA1784
RB1
RA34
S
S



LA1785
RB1
H
S
O



LA1786
RB1
RB1
S
O



LA1787
RB1
RB3
S
O



LA1788
RB1
RB4
S
O



LA1789
RB1
RB7
S
O



LA1790
RB1
RB10
S
O



LA1791
RB1
RA3
S
O



LA1792
RB1
RA34
S
O



LA1793
RB1
H
S
NCH3



LA1794
RB1
RB1
S
NCH3



LA1795
RB1
RB3
S
NCH3



LA1796
RB1
RB4
S
NCH3



LA1797
RB1
RB7
S
NCH3



LA1798
RB1
RB10
S
NCH3



LA1799
RB1
RA3
S
NCH3



LA1800
RB1
RA34
S
NCH3



LA1801
RB1
H
O
S



LA1802
RB1
RB1
O
S



LA1803
RB1
RB3
O
S



LA1804
RB1
RB4
O
S



LA1805
RB1
RB7
O
S



LA1806
RB1
RB10
O
S



LA1807
RB1
RA3
O
S



LA1808
RB1
RA34
O
S



LA1809
RB1
H
O
O



LA1810
RB1
RB1
O
O



LA1811
RB1
RB3
O
O



LA1812
RB1
RB4
O
O



LA1813
RB1
RB7
O
O



LA1814
RB1
RB10
O
O



LA1815
RB1
RA3
O
O



LA1816
RB1
RA34
O
O



LA1817
RB1
H
O
NCH3



LA1818
RB1
RB1
O
NCH3



LA1819
RB1
RB3
O
NCH3



LA1820
RB1
RB4
O
NCH3



LA1821
RB1
RB7
O
NCH3



LA1822
RB1
RB10
O
NCH3



LA1823
RB1
RA3
O
NCH3



LA1824
RB1
RA34
O
NCH3









wherein LA1825 through LA2064 have a structure of Formula XIV:




wherein R1, R5, X, and Y are defined as provided below:


















Ligand
R1
R5
X
Y









LA1825
H
H
C
S



LA1826
RB1
H
C
S



LA1827
RB3
H
C
S



LA1828
RB4
H
C
S



LA1829
RB7
H
C
S



LA1830
RB10
H
C
S



LA1831
RA3
H
C
S



LA1832
RA34
H
C
S



LA1833
H
H
C
O



LA1834
RB1
H
C
O



LA1835
RB3
H
C
O



LA1836
RB4
H
C
O



LA1837
RB7
H
C
O



LA1838
RB10
H
C
O



LA1839
RA3
H
C
O



LA1840
RA34
H
C
O



LA1841
H
H
C
NCH3



LA1842
RB1
H
C
NCH3



LA1843
RB3
H
C
NCH3



LA1844
RB4
H
C
NCH3



LA1845
RB7
H
C
NCH3



LA1846
RB10
H
C
NCH3



LA1847
RA3
H
C
NCH3



LA1848
RA34
H
C
NCH3



LA1849
H
H
C
C(CH3)2



LA1850
RB1
H
C
C(CH3)2



LA1851
RB3
H
C
C(CH3)2



LA1852
RB4
H
C
C(CH3)2



LA1853
RB7
H
C
C(CH3)2



LA1854
RB10
H
C
C(CH3)2



LA1855
RA3
H
C
C(CH3)2



LA1856
RA34
H
C
C(CH3)2



LA1857
H
H
C
Si(CH3)2



LA1858
RB1
H
C
Si(CH3)2



LA1859
RB3
H
C
Si(CH3)2



LA1860
RB4
H
C
Si(CH3)2



LA1861
RB7
H
C
Si(CH3)2



LA1862
RB10
H
C
Si(CH3)2



LA1863
RA3
H
C
Si(CH3)2



LA1864
RA34
H
C
Si(CH3)2



LA1865
H
RB1
C
S



LA1866
RB1
RB1
C
S



LA1867
RB3
RB1
C
S



LA1868
RB4
RB1
C
S



LA1869
RB7
RB1
C
S



LA1870
RB10
RB1
C
S



LA1871
RA3
RB1
C
S



LA1872
RA34
RB1
C
S



LA1873
H
RB1
C
O



LA1874
RB1
RB1
C
O



LA1875
RB3
RB1
C
O



LA1876
RB4
RB1
C
O



LA1877
RB7
RB1
C
O



LA1878
RB10
RB1
C
O



LA1879
RA3
RB1
C
O



LA1880
RA34
RB1
C
O



LA1881
H
RB1
C
NCH3



LA1882
RB1
RB1
C
NCH3



LA1883
RB3
RB1
C
NCH3



LA1884
RB4
RB1
C
NCH3



LA1885
RB7
RB1
C
NCH3



LA1886
RB10
RB1
C
NCH3



LA1887
RA3
RB1
C
NCH3



LA1888
RA34
RB1
C
NCH3



LA1889
H
RB1
C
C(CH3)2



LA1890
RB1
RB1
C
C(CH3)2



LA1891
RB3
RB1
C
C(CH3)2



LA1892
RB4
RB1
C
C(CH3)2



LA1893
RB7
RB1
C
C(CH3)2



LA1894
RB10
RB1
C
C(CH3)2



LA1895
RA3
RB1
C
C(CH3)2



LA1896
RA34
RB1
C
C(CH3)2



LA1897
H
RB1
C
Si(CH3)2



LA1898
RB1
RB1
C
Si(CH3)2



LA1899
RB3
RB1
C
Si(CH3)2



LA1900
RB4
RB1
C
Si(CH3)2



LA1901
RB7
RB1
C
Si(CH3)2



LA1902
RB10
RB1
C
Si(CH3)2



LA1903
RA3
RB1
C
Si(CH3)2



LA1904
RA34
RB1
C
Si(CH3)2



LA1905
H
RB6
C
S



LA1906
RB1
RB6
C
S



LA1907
RB3
RB6
C
S



LA1908
RB4
RB6
C
S



LA1909
RB7
RB6
C
S



LA1910
RB10
RB6
C
S



LA1911
RA3
RB6
C
S



LA1912
RA34
RB6
C
S



LA1913
H
RB6
C
O



LA1914
RB1
RB6
C
O



LA1915
RB3
RB6
C
O



LA1916
RB4
RB6
C
O



LA1917
RB7
RB6
C
O



LA1918
RB10
RB6
C
O



LA1919
RA3
RB6
C
O



LA1920
RA34
RB6
C
O



LA1921
H
RB6
C
NCH3



LA1922
RB1
RB6
C
NCH3



LA1923
RB3
RB6
C
NCH3



LA1924
RB4
RB6
C
NCH3



LA1925
RB7
RB6
C
NCH3



LA1926
RB10
RB6
C
NCH3



LA1927
RA3
RB6
C
NCH3



LA1928
RA34
RB6
C
NCH3



LA1929
H
RB6
C
C(CH3)2



LA1930
RB1
RB6
C
C(CH3)2



LA1931
RB3
RB6
C
C(CH3)2



LA1932
RB4
RB6
C
C(CH3)2



LA1933
RB7
RB6
C
C(CH3)2



LA1934
RB10
RB6
C
C(CH3)2



LA1935
RA3
RB6
C
C(CH3)2



LA1936
RA34
RB6
C
C(CH3)2



LA1937
H
RB6
C
Si(CH3)2



LA1938
RB1
RB6
C
Si(CH3)2



LA1939
RB3
RB6
C
Si(CH3)2



LA1940
RB4
RB6
C
Si(CH3)2



LA1941
RB7
RB6
C
Si(CH3)2



LA1942
RB10
RB6
C
Si(CH3)2



LA1943
RA3
RB6
C
Si(CH3)2



LA1944
RA34
RB6
C
Si(CH3)2



LA1945
H
H
N
S



LA1946
RB1
H
N
S



LA1947
RB3
H
N
S



LA1948
RB4
H
N
S



LA1949
RB7
H
N
S



LA1950
RB10
H
N
S



LA1951
RA3
H
N
S



LA1952
RA34
H
N
S



LA1953
H
H
N
O



LA1954
RB1
H
N
O



LA1955
RB3
H
N
O



LA1956
RB4
H
N
O



LA1957
RB7
H
N
O



LA1958
RB10
H
N
O



LA1959
RA3
H
N
O



LA1960
RA34
H
N
O



LA1961
H
H
N
NCH3



LA1962
RB1
H
N
NCH3



LA1963
RB3
H
N
NCH3



LA1964
RB4
H
N
NCH3



LA1965
RB7
H
N
NCH3



LA1966
RB10
H
N
NCH3



LA1967
RA3
H
N
NCH3



LA1968
RA34
H
N
NCH3



LA1969
H
H
N
C(CH3)2



LA1970
RB1
H
N
C(CH3)2



LA1971
RB3
H
N
C(CH3)2



LA1972
RB4
H
N
C(CH3)2



LA1973
RB7
H
N
C(CH3)2



LA1974
RB10
H
N
C(CH3)2



LA1975
RA3
H
N
C(CH3)2



LA1976
RA34
H
N
C(CH3)2



LA1977
H
H
N
Si(CH3)2



LA1978
RB1
H
N
Si(CH3)2



LA1979
RB3
H
N
Si(CH3)2



LA1980
RB4
H
N
Si(CH3)2



LA1981
RB7
H
N
Si(CH3)2



LA1982
RB10
H
N
Si(CH3)2



LA1983
RA3
H
N
Si(CH3)2



LA1984
RA34
H
N
Si(CH3)2



LA1985
H
RB1
N
S



LA1986
RB1
RB1
N
S



LA1987
RB3
RB1
N
S



LA1988
RB4
RB1
N
S



LA1989
RB7
RB1
N
S



LA1990
RB10
RB1
N
S



LA1991
RA3
RB1
N
S



LA1992
RA34
RB1
N
S



LA1993
H
RB1
N
O



LA1994
RB1
RB1
N
O



LA1995
RB3
RB1
N
O



LA1996
RB4
RB1
N
O



LA1997
RB7
RB1
N
O



LA1998
RB10
RB1
N
O



LA1999
RA3
RB1
N
O



LA2000
RA34
RB1
N
O



LA2001
H
RB1
N
NCH3



LA2002
RB1
RB1
N
NCH3



LA2003
RB3
RB1
N
NCH3



LA2004
RB4
RB1
N
NCH3



LA2005
RB7
RB1
N
NCH3



LA2006
RB10
RB1
N
NCH3



LA2007
RA3
RB1
N
NCH3



LA2008
RA34
RB1
N
NCH3



LA2009
H
RB1
N
C(CH3)2



LA2010
RB1
RB1
N
C(CH3)2



LA2011
RB3
RB1
N
C(CH3)2



LA2012
RB4
RB1
N
C(CH3)2



LA2013
RB7
RB1
N
C(CH3)2



LA2014
RB10
RB1
N
C(CH3)2



LA2015
RA3
RB1
N
C(CH3)2



LA2016
RA34
RB1
N
C(CH3)2



LA2017
H
RB1
N
Si(CH3)2



LA2018
RB1
RB1
N
Si(CH3)2



LA2019
RB3
RB1
N
Si(CH3)2



LA2020
RB4
RB1
N
Si(CH3)2



LA2021
RB7
RB1
N
Si(CH3)2



LA2022
RB10
RB1
N
Si(CH3)2



LA2023
RA3
RB1
N
Si(CH3)2



LA2024
RA34
RB1
N
Si(CH3)2



LA2025
H
RB6
N
S



LA2026
RB1
RB6
N
S



LA2027
RB3
RB6
N
S



LA2028
RB4
RB6
N
S



LA2029
RB7
RB6
N
S



LA2030
RB10
RB6
N
S



LA2031
RA3
RB6
N
S



LA2032
RA34
RB6
N
S



LA2033
H
RB6
N
O



LA2034
RB1
RB6
N
O



LA2035
RB3
RB6
N
O



LA2036
RB4
RB6
N
O



LA2037
RB7
RB6
N
O



LA2038
RB10
RB6
N
O



LA2039
RA3
RB6
N
O



LA2040
RA34
RB6
N
O



LA2041
H
RB6
N
NCH3



LA2042
RB1
RB6
N
NCH3



LA2043
RB3
RB6
N
NCH3



LA2044
RB4
RB6
N
NCH3



LA2045
RB7
RB6
N
NCH3



LA2046
RB10
RB6
N
NCH3



LA2047
RA3
RB6
N
NCH3



LA2048
RA34
RB6
N
NCH3



LA2049
H
RB6
N
C(CH3)2



LA2050
RB1
RB6
N
C(CH3)2



LA2051
RB3
RB6
N
C(CH3)2



LA2052
RB4
RB6
N
C(CH3)2



LA2053
RB7
RB6
N
C(CH3)2



LA2054
RB10
RB6
N
C(CH3)2



LA2055
RA3
RB6
N
C(CH3)2



LA2056
RA34
RB6
N
C(CH3)2



LA2057
H
RB6
N
Si(CH3)2



LA2058
RB1
RB6
N
Si(CH3)2



LA2059
RB3
RB6
N
Si(CH3)2



LA2060
RB4
RB6
N
Si(CH3)2



LA2061
RB7
RB6
N
Si(CH3)2



LA2062
RB10
RB6
N
Si(CH3)2



LA2063
RA3
RB6
N
Si(CH3)2



LA2064
RA34
RB6
N
Si(CH3)2









wherein LA2065 through LA2184 have a structure of Formula XV:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
R14







LA2065
H
H
S
LA2125
RB1
RB4
NCH3


LA2066
H
RB1
S
LA2126
RB1
RB5
NCH3


LA2067
H
RB2
S
LA2127
RB1
RA34
NCH3


LA2068
H
RB3
S
LA2128
RB1
RA52
NCH3


LA2069
H
RB4
S
LA2129
RB1
H
C(CH3)2


LA2070
H
RB5
S
LA2130
RB1
RB1
C(CH3)2


LA2071
H
RA34
S
LA2131
RB1
RB2
C(CH3)2


LA2072
H
RA52
S
LA2132
RB1
RB3
C(CH3)2


LA2073
H
H
O
LA2133
RB1
RB4
C(CH3)2


LA2074
H
RB1
O
LA2134
RB1
RB5
C(CH3)2


LA2075
H
RB2
O
LA2135
RB1
RA34
C(CH3)2


LA2076
H
RB3
O
LA2136
RB1
RA52
C(CH3)2


LA2077
H
RB4
O
LA2137
RB1
H
Si(CH3)2


LA2078
H
RB5
O
LA2138
RB1
RB1
Si(CH3)2


LA2079
H
RA34
O
LA2139
RB1
RB2
Si(CH3)2


LA2080
H
RA52
O
LA2140
RB1
RB3
Si(CH3)2


LA2081
H
H
NCH3
LA2141
RB1
RB4
Si(CH3)2


LA2082
H
RB1
NCH3
LA2142
RB1
RB5
Si(CH3)2


LA2083
H
RB2
NCH3
LA2143
RB1
RA34
Si(CH3)2


LA2084
H
RB3
NCH3
LA2144
RB1
RA52
Si(CH3)2


LA2085
H
RB4
NCH3
LA2145
RB6
H
S


LA2086
H
RB5
NCH3
LA2146
RB6
RB1
S


LA2087
H
RA34
NCH3
LA2147
RB6
RB2
S


LA2088
H
RA52
NCH3
LA2148
RB6
RB3
S


LA2089
H
H
C(CH3)2
LA2149
RB6
RB4
S


LA2090
H
RB1
C(CH3)2
LA2150
RB6
RB5
S


LA2091
H
RB2
C(CH3)2
LA2151
RB6
RA34
S


LA2092
H
RB3
C(CH3)2
LA2152
RB6
RA52
S


LA2093
H
RB4
C(CH3)2
LA2153
RB6
H
O


LA2094
H
RB5
C(CH3)2
LA2154
RB6
RB1
O


LA2095
H
RA34
C(CH3)2
LA2155
RB6
RB2
O


LA2096
H
RA52
C(CH3)2
LA2156
RB6
RB3
O


LA2097
H
H
Si(CH3)2
LA2157
RB6
RB4
O


LA2098
H
RB1
Si(CH3)2
LA2158
RB6
RB5
O


LA2099
H
RB2
Si(CH3)2
LA2159
RB6
RA34
O


LA2100
H
RB3
Si(CH3)2
LA2160
RB6
RA52
O


LA2101
H
RB4
Si(CH3)2
LA2161
RB6
H
NCH3


LA2102
H
RB5
Si(CH3)2
LA2162
RB6
RB1
NCH3


LA2103
H
RA34
Si(CH3)2
LA2163
RB6
RB2
NCH3


LA2104
H
RA52
Si(CH3)2
LA2164
RB6
RB3
NCH3


LA2105
RB1
H
S
LA2165
RB6
RB4
NCH3


LA2106
RB1
RB1
S
LA2166
RB6
RB5
NCH3


LA2107
RB1
RB2
S
LA2167
RB6
RA34
NCH3


LA2108
RB1
RB3
S
LA2168
RB6
RA52
NCH3


LA2109
RB1
RB4
S
LA2169
RB6
H
C(CH3)2


LA2110
RB1
RB5
S
LA2170
RB6
RB1
C(CH3)2


LA2111
RB1
RA34
S
LA2171
RB6
RB2
C(CH3)2


LA2112
RB1
RA52
S
LA2172
RB6
RB3
C(CH3)2


LA2113
RB1
H
O
LA2173
RB6
RB4
C(CH3)2


LA2114
RB1
RB1
O
LA2174
RB6
RB5
C(CH3)2


LA2115
RB1
RB2
O
LA2175
RB6
RA34
C(CH3)2


LA2116
RB1
RB3
O
LA2176
RB6
RA52
C(CH3)2


LA2117
RB1
RB4
O
LA2177
RB6
H
Si(CH3)2


LA2118
RB1
RB5
O
LA2178
RB6
RB1
Si(CH3)2


LA2119
RB1
RA34
O
LA2179
RB6
RB2
Si(CH3)2


LA2120
RB1
RA52
O
LA2180
RB6
RB3
Si(CH3)2


LA2121
RB1
H
NCH3
LA2181
RB6
RB4
Si(CH3)2


LA2122
RB1
RB1
NCH3
LA2182
RB6
RB5
Si(CH3)2


LA2123
RB1
RB2
NCH3
LA2183
RB6
RA34
Si(CH3)2


LA2124
RB1
RB3
NCH3
LA2184
RB6
RA52
Si(CH3)2








wherein LA2185 through LA2280 have a structure of Formula XVI:




wherein R4, R5, Y, and Z are defined as provided below:


















Ligand
R5
R4
Y
Z









LA2185
H
H
S
S



LA2186
H
RB1
S
S



LA2187
H
RB3
S
S



LA2188
H
RB4
S
S



LA2189
H
RB7
S
S



LA2190
H
RB10
S
S



LA2191
H
RA3
S
S



LA2192
H
RA34
S
S



LA2193
H
H
S
O



LA2194
H
RB1
S
O



LA2195
H
RB3
S
O



LA2196
H
RB4
S
O



LA2197
H
RB7
S
O



LA2198
H
RB10
S
O



LA2199
H
RA3
S
O



LA2200
H
RA34
5
O



LA2201
H
H
S
NCH3



LA2202
H
RB1
S
NCH3



LA2203
H
RB3
S
NCH3



LA2204
H
RB4
S
NCH3



LA2205
H
RB7
S
NCH3



LA2206
H
RB10
S
NCH3



LA2207
H
RA3
S
NCH3



LA2208
H
RA34
S
NCH3



LA2209
H
H
O
S



LA2210
H
RB1
O
S



LA2211
H
RB3
O
S



LA2212
H
RB4
O
S



LA2213
H
RB7
O
S



LA2214
H
RB10
O
S



LA2215
H
RA3
O
S



LA2216
H
RA34
O
S



LA2217
H
H
O
O



LA2218
H
RB1
O
O



LA2219
H
RB3
O
O



LA2220
H
RB4
O
O



LA2221
H
RB7
O
O



LA2222
H
RB10
O
O



LA2223
H
RA3
O
O



LA2224
H
RA34
O
O



LA2225
H
H
O
NCH3



LA2226
H
RB1
O
NCH3



LA2227
H
RB3
O
NCH3



LA2228
H
RB4
O
NCH3



LA2229
H
RB7
O
NCH3



LA2230
H
RB10
O
NCH3



LA2231
H
RA3
O
NCH3



LA2232
H
RA34
O
NCH3



LA2233
RB6
H
S
S



LA2234
RB6
RB1
S
S



LA2235
RB6
RB3
S
S



LA2236
RB6
RB4
S
S



LA2237
RB6
RB7
S
S



LA2238
RB6
RB10
S
S



LA2239
RB6
RA3
S
S



LA2240
RB6
RA34
S
S



LA2241
RB6
H
S
O



LA2242
RB6
RB1
S
O



LA2243
RB6
RB3
S
O



LA2244
RB6
RB4
S
O



LA2245
RB6
RB7
S
O



LA2246
RB6
RB10
S
O



LA2247
RB6
RA3
S
O



LA2248
RB6
RA34
5
O



LA2249
RB6
H
S
NCH3



LA2250
RB6
RB1
S
NCH3



LA2251
RB6
RB3
S
NCH3



LA2252
RB6
RB4
S
NCH3



LA2253
RB6
RB7
S
NCH3



LA2254
RB6
RB10
S
NCH3



LA2255
RB6
RA3
S
NCH3



LA2256
RB6
RA34
S
NCH3



LA2257
RB6
H
O
S



LA2258
RB6
RB1
O
S



LA2259
RB6
RB3
O
S



LA2260
RB6
RB4
O
S



LA2261
RB6
RB7
O
S



LA2262
RB6
RB10
O
S



LA2263
RB6
RA3
O
S



LA2264
RB6
RA34
O
S



LA2265
RB6
H
O
O



LA2266
RB6
RB1
O
O



LA2267
RB6
RB3
O
O



LA2268
RB6
RB4
O
O



LA2269
RB6
RB7
O
O



LA2270
RB6
RB10
O
O



LA2271
RB6
RA3
O
O



LA2272
RB6
RA34
O
O



LA2273
RB6
H
O
NCH3



LA2274
RB6
RB1
O
NCH3



LA2275
RB6
RB3
O
NCH3



LA2276
RB6
RB4
O
NCH3



LA2277
RB6
RB7
O
NCH3



LA2278
RB6
RB10
O
NCH3



LA2279
RB6
RA3
O
NCH3



LA2280
RB6
RA34
O
NCH3









wherein LA2281 through LA2520 have a structure of Formula XVII:




wherein R1, R5, X, and Y are defined as provided below:


















Ligand 
R1
R5
X
Y









LA2281
H
H
C
S



LA2282
RB1
H
C
S



LA2283
RB3
H
C
S



LA2284
RB4
H
C
S



LA2285
RB7
H
C
S



LA2286
RB10
H
C
S



LA2287
RA3
H
C
S



LA2288
RA34
H
C
S



LA2289
H
H
C
O



LA2290
RB1
H
C
O



LA2291
RB3
H
C
O



LA2292
RB4
H
C
O



LA2293
RB7
H
C
O



LA2294
RB10
H
C
O



LA2295
RA3
H
C
O



LA2296
RA34
H
C
O



LA2297
H
H
C
NCH3



LA2298
RB1
H
C
NCH3



LA2299
RB3
H
C
NCH3



LA2300
RB4
H
C
NCH3



LA2301
RB7
H
C
NCH3



LA2302
RB10
H
C
NCH3



LA2303
RA3
H
C
NCH3



LA2304
RA34
H
C
NCH3



LA2305
H
H
C
C(CH3)2



LA2306
RB1
H
C
C(CH3)2



LA2307
RB3
H
C
C(CH3)2



LA2308
RB4
H
C
C(CH3)2



LA2309
RB7
H
C
C(CH3)2



LA2310
RB10
H
C
C(CH3)2



LA2311
RA3
H
C
C(CH3)2



LA2312
RA34
H
C
C(CH3)2



LA2313
H
H
C
Si(CH3)2



LA2314
RB1
H
C
Si(CH3)2



LA2315
RB3
H
C
Si(CH3)2



LA2316
RB4
H
C
Si(CH3)2



LA2317
RB7
H
C
Si(CH3)2



LA2318
RB10
H
C
Si(CH3)2



LA2319
RA3
H
C
Si(CH3)2



LA2320
RA34
H
C
Si(CH3)2



LA2321
H
RB1
C
S



LA2322
RB1
RB1
C
S



LA2323
RB3
RB1
C
S



LA2324
RB4
RB1
C
S



LA2325
RB7
RB1
C
S



LA2326
RB10
RB1
C
S



LA2327
RA3
RB1
C
S



LA2328
RA34
RB1
C
S



LA2329
H
RB1
C
O



LA2330
RB1
RB1
C
O



LA2331
RB3
RB1
C
O



LA2332
RB4
RB1
C
O



LA2333
RB7
RB1
C
O



LA2334
RB10
RB1
C
O



LA2335
RA3
RB1
C
O



LA2336
RA34
RB1
C
O



LA2337
H
RB1
C
NCH3



LA2338
RB1
RB1
C
NCH3



LA2339
RB3
RB1
C
NCH3



LA2340
RB4
RB1
C
NCH3



LA2341
RB7
RB1
C
NCH3



LA2342
RB10
RB1
C
NCH3



LA2343
RA3
RB1
C
NCH3



LA2344
RA34
RB1
C
NCH3



LA2345
H
RB1
C
C(CH3)2



LA2346
RB1
RB1
C
C(CH3)2



LA2347
RB3
RB1
C
C(CH3)2



LA2348
RB4
RB1
C
C(CH3)2



LA2349
RB7
RB1
C
C(CH3)2



LA2350
RB10
RB1
C
C(CH3)2



LA2351
RA3
RB1
C
C(CH3)2



LA2352
RA34
RB1
C
C(CH3)2



LA2353
H
RB1
C
Si(CH3)2



LA2354
RB1
RB1
C
Si(CH3)2



LA2355
RB3
RB1
C
Si(CH3)2



LA2356
RB4
RB1
C
Si(CH3)2



LA2357
RB7
RB1
C
Si(CH3)2



LA2358
RB10
RB1
C
Si(CH3)2



LA2359
RA3
RB1
C
Si(CH3)2



LA2360
RA34
RB1
C
Si(CH3)2



LA2361
H
RB6
C
S



LA2362
RB1
RB6
C
S



LA2363
RB3
RB6
C
S



LA2364
RB4
RB6
C
S



LA2365
RB7
RB6
C
S



LA2366
RB10
RB6
C
S



LA2367
RA3
RB6
C
S



LA2368
RA34
RB6
C
S



LA2369
H
RB6
C
O



LA2370
RB1
RB6
C
O



LA2371
RB3
RB6
C
O



LA2372
RB4
RB6
C
O



LA2373
RB7
RB6
C
O



LA2374
RB10
RB6
C
O



LA2375
RA3
RB6
C
O



LA2376
RA34
RB6
C
O



LA2377
H
RB6
C
NCH3



LA2378
RB1
RB6
C
NCH3



LA2379
RB3
RB6
C
NCH3



LA2380
RB4
RB6
C
NCH3



LA2381
RB7
RB6
C
NCH3



LA2382
RB10
RB6
C
NCH3



LA2383
RA3
RB6
C
NCH3



LA2384
RA34
RB6
C
NCH3



LA2385
H
RB6
C
C(CH3)2



LA2386
RB1
RB6
C
C(CH3)2



LA2387
RB3
RB6
C
C(CH3)2



LA2388
RB4
RB6
C
C(CH3)2



LA2389
RB7
RB6
C
C(CH3)2



LA2390
RB10
RB6
C
C(CH3)2



LA2391
RA3
RB6
C
C(CH3)2



LA2392
RA34
RB6
C
C(CH3)2



LA2393
H
RB6
C
Si(CH3)2



LA2394
RB1
RB6
C
Si(CH3)2



LA2395
RB3
RB6
C
Si(CH3)2



LA2396
RB4
RB6
C
Si(CH3)2



LA2397
RB7
RB6
C
Si(CH3)2



LA2398
RB10
RB6
C
Si(CH3)2



LA2399
RA3
RB6
C
Si(CH3)2



LA2400
RA34
RB6
C
Si(CH3)2



LA2401
H
H
N
S



LA2402
RB1
H
N
S



LA2403
RB3
H
N
S



LA2404
RB4
H
N
S



LA2405
RB7
H
N
S



LA2406
RB10
H
N
S



LA2407
RA3
H
N
S



LA2408
RA34
H
N
S



LA2409
H
H
N
O



LA2410
RB1
H
N
O



LA2411
RB3
H
N
O



LA2412
RB4
H
N
O



LA2413
RB7
H
N
O



LA2414
RB10
H
N
O



LA2415
RA3
H
N
O



LA2416
RA34
H
N
O



LA2417
H
H
N
NCH3



LA2418
RB1
H
N
NCH3



LA2419
RB3
H
N
NCH3



LA2420
RB4
H
N
NCH3



LA2421
RB7
H
N
NCH3



LA2422
RB10
H
N
NCH3



LA2423
RA3
H
N
NCH3



LA2424
RA34
H
N
NCH3



LA2425
H
H
N
C(CH3)2



LA2426
RB1
H
N
C(CH3)2



LA2427
RB3
H
N
C(CH3)2



LA2428
RB4
H
N
C(CH3)2



LA2429
RB7
H
N
C(CH3)2



LA2430
RB10
H
N
C(CH3)2



LA2431
RA3
H
N
C(CH3)2



LA2432
RA34
H
N
C(CH3)2



LA2433
H
H
N
Si(CH3)2



LA2434
RB1
H
N
Si(CH3)2



LA2435
RB3
H
N
Si(CH3)2



LA2436
RB4
H
N
Si(CH3)2



LA2437
RB7
H
N
Si(CH3)2



LA2438
RB10
H
N
Si(CH3)2



LA2439
RA3
H
N
Si(CH3)2



LA2440
RA34
H
N
Si(CH3)2



LA2441
H
RB1
N
S



LA2442
RB1
RB1
N
S



LA2443
RB3
RB1
N
S



LA2444
RB4
RB1
N
S



LA2445
RB7
RB1
N
S



LA2446
RB10
RB1
N
S



LA2447
RA3
RB1
N
S



LA2448
RA34
RB1
N
S



LA2449
H
RB1
N
O



LA2450
RB1
RB1
N
O



LA2451
RB3
RB1
N
O



LA2452
RB4
RB1
N
O



LA2453
RB7
RB1
N
O



LA2454
RB10
RB1
N
O



LA2455
RA3
RB1
N
O



LA2456
RA34
RB1
N
O



LA2457
H
RB1
N
NCH3



LA2458
RB1
RB1
N
NCH3



LA2459
RB3
RB1
N
NCH3



LA2460
RB4
RB1
N
NCH3



LA2461
RB7
RB1
N
NCH3



LA2462
RB10
RB1
N
NCH3



LA2463
RA3
RB1
N
NCH3



LA2464
RA34
RB1
N
NCH3



LA2465
H
RB1
N
C(CH3)2



LA2466
RB1
RB1
N
C(CH3)2



LA2467
RB3
RB1
N
C(CH3)2



LA2468
RB4
RB1
N
C(CH3)2



LA2469
RB7
RB1
N
C(CH3)2



LA2470
RB10
RB1
N
C(CH3)2



LA2471
RA3
RB1
N
C(CH3)2



LA2472
RA34
RB1
N
C(CH3)2



LA2473
H
RB1
N
Si(CH3)2



LA2474
RB1
RB1
N
Si(CH3)2



LA2475
RB3
RB1
N
Si(CH3)2



LA2476
RB4
RB1
N
Si(CH3)2



LA2477
RB7
RB1
N
Si(CH3)2



LA2478
RB10
RB1
N
Si(CH3)2



LA2479
RA3
RB1
N
Si(CH3)2



LA2480
RA34
RB1
N
Si(CH3)2



LA2481
H
RB6
N
S



LA2482
RB1
RB6
N
S



LA2483
RB3
RB6
N
S



LA2484
RB4
RB6
N
S



LA2485
RB7
RB6
N
S



LA2486
RB10
RB6
N
S



LA2487
RA3
RB6
N
S



LA2488
RA34
RB6
N
S



LA2489
H
RB6
N
O



LA2490
RB1
RB6
N
O



LA2491
RB3
RB6
N
O



LA2492
RB4
RB6
N
O



LA2493
RB7
RB6
N
O



LA2494
RB10
RB6
N
O



LA2495
RA3
RB6
N
O



LA2496
RA34
RB6
N
O



LA2497
H
RB6
N
NCH3



LA2498
RB1
RB6
N
NCH3



LA2499
RB3
RB6
N
NCH3



LA2500
RB4
RB6
N
NCH3



LA2501
RB7
RB6
N
NCH3



LA2502
RB10
RB6
N
NCH3



LA2503
RA3
RB6
N
NCH3



LA2504
RA34
RB6
N
NCH3



LA2505
H
RB6
N
C(CH3)2



LA2506
RB1
RB6
N
C(CH3)2



LA2507
RB3
RB6
N
C(CH3)2



LA2508
RB4
RB6
N
C(CH3)2



LA2509
RB7
RB6
N
C(CH3)2



LA2510
RB10
RB6
N
C(CH3)2



LA2511
RA3
RB6
N
C(CH3)2



LA2512
RA34
RB6
N
C(CH3)2



LA2513
H
RB6
N
Si(CH3)2



LA2514
RB1
RB6
N
Si(CH3)2



LA2515
RB3
RB6
N
Si(CH3)2



LA2516
RB4
RB6
N
Si(CH3)2



LA2517
RB7
RB6
N
Si(CH3)2



LA2518
RB10
RB6
N
Si(CH3)2



LA2519
RA3
RB6
N
Si(CH3)2



LA2520
RA34
RB6
N
Si(CH3)2









wherein LA2521 through LA2640 have a structure of Formula XVIII:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA2521
H
H
S
LA2581
RB1
RB4
NCH3


LA2522
H
RB1
S
LA2582
RB1
RB5
NCH3


LA2523
H
RB2
S
LA2583
RB1
RA34
NCH3


LA2524
H
RB3
S
LA2584
RB1
RA52
NCH3


LA2525
H
RB4
S
LA2585
RB1
H
C(CH3)2


LA2526
H
RB5
S
LA2586
RB1
RB1
C(CH3)2


LA2527
H
RA34
S
LA2587
RB1
RB2
C(CH3)2


LA2528
H
RA52
S
LA2588
RB1
RB3
C(CH3)2


LA2529
H
H
O
LA2589
RB1
RB4
C(CH3)2


LA2530
H
RB1
O
LA2590
RB1
RB5
C(CH3)2


LA2531
H
RB2
O
LA2591
RB1
RA34
C(CH3)2


LA2532
H
RB3
O
LA2592
RB1
RA52
C(CH3)2


LA2533
H
RB4
O
LA2593
RB1
H
Si(CH3)2


LA2534
H
RB5
O
LA2594
RB1
RB1
Si(CH3)2


LA2535
H
RA34
O
LA2595
RB1
RB2
Si(CH3)2


LA2536
H
RA52
O
LA2596
RB1
RB3
Si(CH3)2


LA2537
H
H
NCH3
LA2597
RB1
RB4
Si(CH3)2


LA2538
H
RB1
NCH3
LA2598
RB1
RB5
Si(CH3)2


LA2539
H
RB2
NCH3
LA2599
RB1
RA34
Si(CH3)2


LA2540
H
RB3
NCH3
LA2600
RB1
RA52
Si(CH3)2


LA2541
H
RB4
NCH3
LA2601
RB6
H
S


LA2542
H
RB5
NCH3
LA2602
RB6
RB1
S


LA2543
H
RA34
NCH3
LA2603
RB6
RB2
S


LA2544
H
RA52
NCH3
LA2604
RB6
RB3
S


LA2545
H
H
C(CH3)2
LA2605
RB6
RB4
S


LA2546
H
RB1
C(CH3)2
LA2606
RB6
RB5
S


LA2547
H
RB2
C(CH3)2
LA2607
RB6
RA34
S


LA2548
H
RB3
C(CH3)2
LA2608
RB6
RA52
S


LA2549
H
RB4
C(CH3)2
LA2609
RB6
H
O


LA2550
H
RB5
C(CH3)2
LA2610
RB6
RB1
O


LA2551
H
RA34
C(CH3)2
LA2611
RB6
RB2
O


LA2552
H
RA52
C(CH3)2
LA2612
RB6
RB3
O


LA2553
H
H
Si(CH3)2 
LA2613
RB6
RB4
O


LA2554
H
RB1
Si(CH3)2
LA2614
RB6
RB5
O


LA2555
H
RB2
Si(CH3)2
LA2615
RB6
RA34
O


LA2556
H
RB3
Si(CH3)2
LA2616
RB6
RA52
O


LA2557
H
RB4
Si(CH3)2
LA2617
RB6
H
NCH3


LA2558
H
RB5
Si(CH3)2
LA2618
RB6
RB1
NCH3


LA2559
H
RA34
Si(CH3)2
LA2619
RB6
RB2
NCH3


LA2560
H
RA52
Si(CH3)2
LA2620
RB6
RB3
NCH3


LA2561
RB1
H
S
LA2621
RB6
RB4
NCH3


LA2562
RB1
RB1
S
LA2622
RB6
RB5
NCH3


LA2563
RB1
RB2
S
LA2623
RB6
RA34
NCH3


LA2564
RB1
RB3
S
LA2624
RB6
RA52
NCH3


LA2565
RB1
RB4
S
LA2625
RB6
H
C(CH3)2


LA2566
RB1
RB5
S
LA2626
RB6
RB1
C(CH3)2


LA2567
RB1
RA34
S
LA2627
RB6
RB2
C(CH3)2


LA2568
RB1
RA52
S
LA2628
RB6
RB3
C(CH3)2


LA2569
RB1
H
O
LA2629
RB6
RB4
C(CH3)2


LA2570
RB1
RB1
O
LA2630
RB6
RB5
C(CH3)2


LA2571
RB1
RB2
O
LA2631
RB6
RA34
C(CH3)2


LA2572
RB1
RB3
O
LA2632
RB6
RA52
C(CH3)2


LA2573
RB1
RB4
O
LA2633
RB6
H
Si(CH3)


LA2574
RB1
RB5
O
LA2634
RB6
RB1
Si(CH3)


LA2575
RB1
RA34
O
LA2635
RB6
RB2
Si(CH3)


LA2576
RB1
RA52
O
LA2636
RB6
RB3
Si(CH3)


LA2577
RB1
H
NCH3
LA2637
RB6
RB4
Si(CH3)


LA2578
RB1
RB1
NCH3
LA2638
RB6
RB5
Si(CH3)


LA2579
RB1
RB2
NCH3
LA2639
RB6
RA34
Si(CH3)


LA2580
RB1
RB3
NCH3
LA2640
RB6
RA52
Si(CH3)








wherein LA2641 through LA2736 have a structure of Formula XIX:




wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA2641
H
H
S
S
LA2689
RB6
H
S
S


LA2642
H
RB1
S
S
LA2690
RB6
RB1
S
S


LA2643
H
RB3
S
S
LA2691
RB6
RB3
S
S


LA2644
H
RB4
S
S
LA2692
RB6
RB4
S
S


LA2645
H
RB7
S
S
LA2693
RB6
RB7
S
S


LA2646
H
RB10
S
S
LA2694
RB6
RB10
S
S


LA2647
H
RA3
S
S
LA2695
RB6
RA3
S
S


LA2648
H
RA34
S
S
LA2696
RB6
RA34
S
S


LA2649
H
H
S
O
LA2697
RB6
H
S
O


LA2650
H
RB1
S
O
LA2698
RB6
RB1
S
O


LA2651
H
RB3
S
O
LA2699
RB6
RB3
S
O


LA2652
H
RB4
S
O
LA2700
RB6
RB4
S
O


LA2653
H
RB7
S
O
LA2701
RB6
RB7
S
O


LA2654
H
RB10
S
O
LA2702
RB6
RB10
S
O


LA2655
H
RA3
S
O
LA2703
RB6
RA3
S
O


LA2656
H
RA34
S
O
LA2704
RB6
RA34
S
O


LA2657
H
H
S
NCH3
LA2705
RB6
H
S
NCH3


LA2658
H
RB1
S
NCH3
LA2706
RB6
RB1
S
NCH3


LA2659
H
RB3
S
NCH3
LA2707
RB6
RB3
S
NCH3


LA2660
H
RB4
S
NCH3
LA2708
RB6
RB4
S
NCH3


LA2661
H
RB7
S
NCH3
LA2709
RB6
RB7
S
NCH3


LA2662
H
RB10
S
NCH3
LA2710
RB6
RB10
S
NCH3


LA2663
H
RA3
S
NCH3
LA2711
RB6
RA3
S
NCH3


LA2664
H
RA34
S
NCH3
LA2712
RB6
RA34
S
NCH3


LA2665
H
H
O
S
LA2713
RB6
H
O
S


LA2666
H
RB1
O
S
LA2714
RB6
RB1
O
S


LA2667
H
RB3
O
S
LA2715
RB6
RB3
O
S


LA2668
H
RB4
O
S
LA2716
RB6
RB4
O
S


LA2669
H
RB7
O
S
LA2717
RB6
RB7
O
S


LA2670
H
RB10
O
S
LA2718
RB6
RB10
O
S


LA2671
H
RA3
O
S
LA2719
RB6
RA3
O
S


LA2672
H
RA34
O
S
LA2720
RB6
RA34
O
S


LA2673
H
H
O
O
LA2721
RB6
H
O
O


LA2674
H
RB1
O
O
LA2722
RB6
RB1
O
O


LA2675
H
RB3
O
O
LA2723
RB6
RB3
O
O


LA2676
H
RB4
O
O
LA2724
RB6
RB4
O
O


LA2677
H
RB7
O
O
LA2725
RB6
RB7
O
O


LA2678
H
RB10
O
O
LA2726
RB6
RB10
O
O


LA2679
H
RA3
O
O
LA2727
RB6
RA3
O
O


LA2680
H
RA34
O
O
LA2728
RB6
RA34
O
O


LA2681
H
H
O
NCH3
LA2729
RB6
H
O
NCH3


LA2682
H
RB1
O
NCH3
LA2730
RB6
RB1
O
NCH3


LA2683
H
RB3
O
NCH3
LA2731
RB6
RB3
O
NCH3


LA2684
H
RB4
O
NCH3
LA2732
RB6
RB4
O
NCH3


LA2685
H
RB7
O
NCH3
LA2733
RB6
RB7
O
NCH3


LA2686
H
RB10
O
NCH3
LA2734
RB6
RB10
O
NCH3


LA2687
H
RA3
O
NCH3
LA2735
RB6
RA3
O
NCH3


LA2688
H
RA34
O
NCH3
LA2736
RB6
RA34
O
NCH3








wherein LA2857 through LA2976 have a structure of Formula XX:




wherein R1, R5, Y, and X are defined as provided below:


















Ligand
R1
R5
X
Y









LA2857 
H
H
N
S



LA2858
RB1
H
N
S



LA2859
RB3
H
N
S



LA2860
RB4
H
N
S



LA2861
RB7
H
N
S



LA2862
RB10
H
N
S



LA2863
RA3
H
N
S



LA2864
RA34
H
N
S



LA2865
H
H
N
O



LA2866
RB1
H
N
O



LA2867
RB3
H
N
O



LA2868
RB4
H
N
O



LA2869
RB7
H
N
O



LA2870
RB10
H
N
O



LA2871
RA3
H
N
O



LA2872
RA34
H
N
O



LA2873
H
H
N
NCH3



LA2874
RB1
H
N
NCH3



LA2875
RB3
H
N
NCH3



LA2876
RB4
H
N
NCH3



LA2877
RB7
H
N
NCH3



LA2878
RB10
H
N
NCH3



LA2879
RA3
H
N
NCH3



LA2880
RA34
H
N
NCH3



LA2881
H
H
N
C(CH3)2



LA2882
RB1
H
N
C(CH3)2



LA2883
RB3
H
N
C(CH3)2



LA2884
RB4
H
N
C(CH3)2



LA2885
RB7
H
N
C(CH3)2



LA2886
RB10
H
N
C(CH3)2



LA2887
RA3
H
N
C(CH3)2



LA2888
RA34
H
N
C(CH3)2



LA2889
H
H
N
Si(CH3)2



LA2890
RB1
H
N
Si(CH3)2



LA2891
RB3
H
N
Si(CH3)2



LA2892
RB4
H
N
Si(CH3)2



LA2893
RB7
H
N
Si(CH3)2



LA2894
RB10
H
N
Si(CH3)2



LA2895
RA3
H
N
Si(CH3)2



LA2896
RA34
H
N
Si(CH3)2



LA2897
H
RB1
N
S



LA2898
RB1
RB1
N
S



LA2899
RB3
RB1
N
S



LA2900
RB4
RB1
N
S



LA2901
RB7
RB1
N
S



LA2902
RB10
RB1
N
S



LA2903
RA3
RB1
N
S



LA2904
RA34
RB1
N
S



LA2905
H
RB1
N
O



LA2906
RB1
RB1
N
O



LA2907
RB3
RB1
N
O



LA2908
RB4
RB1
N
O



LA2909
RB7
RB1
N
O



LA2910
RB10
RB1
N
O



LA2911
RA3
RB1
N
O



LA2912
RA34
RB1
N
O



LA2913
H
RB1
N
NCH3



LA2914
RB1
RB1
N
NCH3



LA2915
RB3
RB1
N
NCH3



LA2916
RB4
RB1
N
NCH3



LA2917
RB7
RB1
N
NCH3



LA2918
RB10
RB1
N
NCH3



LA2919
RA3
RB1
N
NCH3



LA2920
RA34
RB1
N
NCH3



LA2921
H
RB1
N
C(CH3)2



LA2922
RB1
RB1
N
C(CH3)2



LA2923
RB3
RB1
N
C(CH3)2



LA2924
RB4
RB1
N
C(CH3)2



LA2925
RB7
RB1
N
C(CH3)2



LA2926
RB10
RB1
N
C(CH3)2



LA2927
RA3
RB1
N
C(CH3)2



LA2928
RA34
RB1
N
C(CH3)2



LA2929
H
RB1
N
Si(CH3)2



LA2930
RB1
RB1
N
Si(CH3)2



LA2931
RB3
RB1
N
Si(CH3)2



LA2932
RB4
RB1
N
Si(CH3)2



LA2933
RB7
RB1
N
Si(CH3)2



LA2934
RB10
RB1
N
Si(CH3)2



LA2935
RA3
RB1
N
Si(CH3)2



LA2936
RA34
RB1
N
Si(CH3)2



LA2937
H
RB6
N
S



LA2938
RB1
RB6
N
S



LA2939
RB3
RB6
N
S



LA2940
RB4
RB6
N
S



LA2941
RB7
RB6
N
S



LA2942
RB10
RB6
N
S



LA2943
RA3
RB6
N
S



LA2944
RA34
RB6
N
S



LA2945
H
RB6
N
O



LA2946
RB1
RB6
N
O



LA2947
RB3
RB6
N
O



LA2948
RB4
RB6
N
O



LA2949
RB7
RB6
N
O



LA2950
RB10
RB6
N
O



LA2951
RA3
RB6
N
O



LA2952
RA34
RB6
N
O



LA2953
H
RB6
N
NCH3



LA2954
RB1
RB6
N
NCH3



LA2955
RB3
RB6
N
NCH3



LA2956
RB4
RB6
N
NCH3



LA2957
RB7
RB6
N
NCH3



LA2958
RB10
RB6
N
NCH3



LA2959
RA3
RB6
N
NCH3



LA2960
RA34
RB6
N
NCH3



LA2961
H
RB6
N
C(CH3)2



LA2962
RB1
RB6
N
C(CH3)2



LA2963
RB3
RB6
N
C(CH3)2



LA2964
RB4
RB6
N
C(CH3)2



LA2965
RB7
RB6
N
C(CH3)2



LA2966
RB10
RB6
N
C(CH3)2



LA2967
RA3
RB6
N
C(CH3)2



LA2968
RA34
RB6
N
C(CH3)2



LA2969
H
RB6
N
Si(CH3)2



LA2970
RB1
RB6
N
Si(CH3)2



LA2971
RB3
RB6
N
Si(CH3)2



LA2972
RB4
RB6
N
Si(CH3)2



LA2973
RB7
RB6
N
Si(CH3)2



LA2974
RB10
RB6
N
Si(CH3)2



LA2975
RA3
RB6
N
Si(CH3)2



LA2976
RA34
RB6
N
Si(CH3)2









wherein LA2977 through LA3096 have a structure of Formula XXI:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA2977
H
H
S
LA3037
RB1
RB4
NCH3


LA2978
H
RB1
S
LA3038
RB1
RB5
NCH3


LA2979
H
RB2
S
LA3039
RB1
RA34
NCH3


LA2980
H
RB3
S
LA3040
RB1
RA52
NCH3


LA2981
H
RB4
S
LA3041
RB1
H
C(CH3)2


LA2982
H
RB5
S
LA3042
RB1
RB1
C(CH3)2


LA2983
H
RA34
S
LA3043
RB1
RB2
C(CH3)2


LA2984
H
RA52
S
LA3044
RB1
RB3
C(CH3)2


LA2985
H
H
O
LA3045
RB1
RB4
C(CH3)2


LA2986
H
RB1
O
LA3046
RB1
RB5
C(CH3)2


LA2987
H
RB2
O
LA3047
RB1
RA34
C(CH3)2


LA2988
H
RB3
O
LA3048
RB1
RA52
C(CH3)2


LA2989
H
RB4
O
LA3049
RB1
H
Si(CH3)2


LA2990
H
RB5
O
LA3050
RB1
RB1
Si(CH3)2


LA2991
H
RA34
O
LA3051
RB1
RB2
Si(CH3)2


LA2992
H
RA52
O
LA3052
RB1
RB3
Si(CH3)2


LA2993
H
H
NCH3
LA3053
RB1
RB4
Si(CH3)2


LA2994
H
RB1
NCH3
LA3054
RB1
RB5
Si(CH3)2


LA2995
H
RB2
NCH3
LA3055
RB1
RA34
Si(CH3)2


LA2996
H
RB3
NCH3
LA3056
RB1
RA52
Si(CH3)2


LA2997
H
RB4
NCH3
LA3057
RB6
H
S


LA2998
H
RB5
NCH3
LA3058
RB6
RB1
S


LA2999
H
RA34
NCH3
LA3059
RB6
RB2
S


LA3000
H
RA52
NCH3
LA3060
RB6
RB3
S


LA3001
H
H
C(CH3)2
LA3061
RB6
RB4
S


LA3002
H
RB1
C(CH3)2
LA3062
RB6
RB5
S


LA3003
H
RB2
C(CH3)2
LA3063
RB6
RA34
S


LA3004
H
RB3
C(CH3)2
LA3064
RB6
RA52
S


LA3005
H
RB4
C(CH3)2
LA3065
RB6
H
O


LA3006
H
RB5
C(CH3)2
LA3066
RB6
RB1
O


LA3007
H
RA34
C(CH3)2
LA3067
RB6
RB2
O


LA3008
H
RA52
C(CH3)2
LA3068
RB6
RB3
O


LA3009
H
H
Si(CH3)2
LA3069
RB6
RB4
O


LA3010
H
RB1
Si(CH3)2
LA3070
RB6
RB5
O


LA3011
H
RB2
Si(CH3)2
LA3071
RB6
RA34
O


LA3012
H
RB3
Si(CH3)2
LA3072
RB6
RA52
O


LA3013
H
RB4
Si(CH3)2
LA3073
RB6
H
NCH3


LA3014
H
RB5
Si(CH3)2
LA3074
RB6
RB1
NCH3


LA3015
H
RA34
Si(CH3)2
LA3075
RB6
RB2
NCH3


LA3016
H
RA52
Si(CH3)2
LA3076
RB6
RB3
NCH3


LA3017
RB1
H
S
LA3077
RB6
RB4
NCH3


LA3018
RB1
RB1
S
LA3078
RB6
RB5
NCH3


LA3019
RB1
RB2
S
LA3079
RB6
RA34
NCH3


LA3020
RB1
RB3
S
LA3080
RB6
RA52
NCH3


LA3021
RB1
RB4
S
LA3081
RB6
H
C(CH3)2


LA3022
RB1
RB5
S
LA3082
RB6
RB1
C(CH3)2


LA3023
RB1
RA34
S
LA3083
RB6
RB2
C(CH3)2


LA3024
RB1
RA52
S
LA3084
RB6
RB3
C(CH3)2


LA3025
RB1
H
O
LA3085
RB6
RB4
C(CH3)2


LA3026
RB1
RB1
O
LA3086
RB6
RB5
C(CH3)2


LA3027
RB1
RB2
O
LA3087
RB6
RA34
C(CH3)2


LA3028
RB1
RB3
O
LA3088
RB6
RA52
C(CH3)2


LA3029
RB1
RB4
O
LA3089
RB6
H
Si(CH3)2


LA3030
RB1
RB5
O
LA3090
RB6
RB1
Si(CH3)2


LA3031
RB1
RA34
O
LA3091
RB6
RB2
Si(CH3)2


LA3032
RB1
RA52
O
LA3092
RB6
RB3
Si(CH3)2


LA3033
RB1
H
NCH3
LA3093
RB6
RB4
Si(CH3)2


LA3034
RB1
RB1
NCH3
LA3094
RB6
RB5
Si(CH3)2


LA3035
RB1
RB2
NCH3
LA3095
RB6
RA34
Si(CH3)2


LA3036
RB1
RB3
NCH3
LA3096
RB6
RA52
Si(CH3)2








wherein LA3097 through LA3192 have a structure of Formula XXII:




wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA3097
H
H
S
S
LA3145
RB6
H
S
S


LA3098
H
RB1
S
S
LA3146
RB6
RB1
S
S


LA3099
H
RB3
S
S
LA3147
RB6
RB3
S
S


LA3100
H
RB4
S
S
LA3148
RB6
RB4
S
S


LA3101
H
RB7
S
S
LA3149
RB6
RB7
S
S


LA3102
H
RB10
S
S
LA3150
RB6
RB10
S
S


LA3103
H
RA3
S
S
LA3151
RB6
RA3
S
S


LA3104
H
RA34
S
S
LA3152
RB6
RA34
S
S


LA3105
H
H
S
O
LA3153
RB6
H
S
O


LA3106
H
RB1
S
O
LA3154
RB6
RB1
S
O


LA3107
H
RB3
S
O
LA3155
RB6
RB3
S
O


LA3108
H
RB4
S
O
LA3156
RB6
RB4
S
O


LA3109
H
RB7
S
O
LA3157
RB6
RB7
S
O


LA3110
H
RB10
S
O
LA3158
RB6
RB10
S
O


LA3111
H
RA3
S
O
LA3159
RB6
RA3
S
O


LA3112
H
RA34
S
O
LA3160
RB6
RA34
S
O


LA3113
H
H
S
NCH3
LA3161
RB6
H
S
NCH3


LA3114
H
RB1
S
NCH3
LA3162
RB6
RB1
S
NCH3


LA3115
H
RB3
S
NCH3
LA3163
RB6
RB3
S
NCH3


LA3116
H
RB4
S
NCH3
LA3164
RB6
RB4
S
NCH3


LA3117
H
RB7
S
NCH3
LA3165
RB6
RB7
S
NCH3


LA3118
H
RB10
S
NCH3
LA3166
RB6
RB10
S
NCH3


LA3119
H
RA3
S
NCH3
LA3167
RB6
RA3
S
NCH3


LA3120
H
RA34
S
NCH3
LA3168
RB6
RA34
S
NCH3


LA3121
H
H
O
S
LA3169
RB6
H
O
S


LA3122
H
RB1
O
S
LA3170
RB6
RB1
O
S


LA3123
H
RB3
O
S
LA3171
RB6
RB3
O
S


LA3124
H
RB4
O
S
LA3172
RB6
RB4
O
S


LA3125
H
RB7
O
S
LA3173
RB6
RB7
O
S


LA3126
H
RB10
O
S
LA3174
RB6
RB10
O
S


LA3127
H
RA3
O
S
LA3175
RB6
RA3
O
S


LA3128
H
RA34
O
S
LA3176
RB6
RA34
O
S


LA3129
H
H
O
O
LA3177
RB6
H
O
O


LA3130
H
RB1
O
O
LA3178
RB6
RB1
O
O


LA3131
H
RB3
O
O
LA3179
RB6
RB3
O
O


LA3132
H
RB4
O
O
LA3180
RB6
RB4
O
O


LA3133
H
RB7
O
O
LA3181
RB6
RB7
O
O


LA3134
H
RB10
O
O
LA3182
RB6
RB10
O
O


LA3135
H
RA3
O
O
LA3183
RB6
RA3
O
O


LA3136
H
RA34
O
O
LA3184
RB6
RA34
O
O


LA3137
H
H
O
NCH3
LA3185
RB6
H
O
NCH3


LA3138
H
RB1
O
NCH3
LA3186
RB6
RB1
O
NCH3


LA3139
H
RB3
O
NCH3
LA3187
RB6
RB3
O
NCH3


LA3140
H
RB4
O
NCH3
LA3188
RB6
RB4
O
NCH3


LA3141
H
RB7
O
NCH3
LA3189
RB6
RB7
O
NCH3


LA3142
H
RB10
O
NCH3
LA3190
RB6
RB10
O
NCH3


LA3143
H
RA3
O
NCH3
LA3191
RB6
RA3
O
NCH3


LA3144
H
RA34
O
NCH3
LA3192
RB6
RA34
O
NCH3








wherein LA3193 through LA3432 have a structure of Formula XXIII:




wherein R1, R5, X, and Y are defined as provided below:




















Ligand
R1
R5
X
Y
Ligand
R1
R5
X
Y







LA3193
H
H
C
S
LA3313
H
H
N
S


LA3194
RB1
H
C
S
LA3314
RB1
H
N
S


LA3195
RB3
H
C
S
LA3315
RB3
H
N
S


LA3196
RB4
H
C
S
LA3316
RB4
H
N
S


LA3197
RB7
H
C
S
LA3317
RB7
H
N
S


LA3198
RB10
H
C
S
LA3318
RB10
H
N
S


LA3199
RA3
H
C
S
LA3319
RA3
H
N
S


LA3200
RA34
H
C
S
LA3320
RA34
H
N
S


LA3201
H
H
C
O
LA3321
H
H
N
O


LA3202
RB1
H
C
O
LA3322
RB1
H
N
O


LA3203
RB3
H
C
O
LA3323
RB3
H
N
O


LA3204
RB4
H
C
O
LA3324
RB4
H
N
O


LA3205
RB7
H
C
O
LA3325
RB7
H
N
O


LA3206
RB10
H
C
O
LA3326
RB10
H
N
O


LA3207
RA3
H
C
O
LA3327
RA3
H
N
O


LA3208
RA34
H
C
O
LA3328
RA34
H
N
O


LA3209
H
H
C
NCH3
LA3329
H
H
N
NCH3


LA3210
RB1
H
C
NCH3
LA3330
RB1
H
N
NCH3


LA3211
RB3
H
C
NCH3
LA3331
RB3
H
N
NCH3


LA3212
RB4
H
C
NCH3
LA3332
RB4
H
N
NCH3


LA3213
RB7
H
C
NCH3
LA3333
RB7
H
N
NCH3


LA3214
RB10
H
C
NCH3
LA3334
RB10
H
N
NCH3


LA3215
RA3
H
C
NCH3
LA3335
RA3
H
N
NCH3


LA3216
RA34
H
C
NCH3
LA3336
RA34
H
N
NCH3


LA3217
H
H
C
C(CH3)2 
LA3337
H
H
N
C(CH3)2


LA3218
RB1
H
C
C(CH3)2
LA3338
RB1
H
N
C(CH3)2


LA3219
RB3
H
C
C(CH3)2
LA3339
RB3
H
N
C(CH3)2


LA3220
RB4
H
C
C(CH3)2
LA3340
RB4
H
N
C(CH3)2


LA3221
RB7
H
C
C(CH3)2
LA3341
RB7
H
N
C(CH3)2


LA3222
RB10
H
C
C(CH3)2
LA3342
RB10
H
N
C(CH3)2


LA3223
RA3
H
C
C(CH3)2
LA3343
RA3
H
N
C(CH3)2


LA3224
RA34
H
C
C(CH3)2
LA3344
RA34
H
N
C(CH3)2


LA3225
H
H
C
Si(CH3)2
LA3345
H
H
N
Si(CH3)2


LA3226
RB1
H
C
Si(CH3)2
LA3346
RB1
H
N
Si(CH3)2


LA3227
RB3
H
C
Si(CH3)2
LA3347
RB3
H
N
Si(CH3)2


LA3228
RB4
H
C
Si(CH3)2
LA3348
RB4
H
N
Si(CH3)2


LA3229
RB7
H
C
Si(CH3)2
LA3349
RB7
H
N
Si(CH3)2


LA3230
RB10
H
C
Si(CH3)2
LA3350
RB10
H
N
Si(CH3)2


LA3231
RA3
H
C
Si(CH3)2
LA3351
RA3
H
N
Si(CH3)2


LA3232
RA34
H
C
Si(CH3)2
LA3352
RA34
H
N
Si(CH3)2


LA3233
H
RB1
C
S
LA3353
H
RB1
N
S


LA3234
RB1
RB1
C
S
LA3354
RB1
RB1
N
S


LA3235
RB3
RB1
C
S
LA3355
RB3
RB1
N
S


LA3236
RB4
RB1
C
S
LA3356
RB4
RB1
N
S


LA3237
RB7
RB1
C
S
LA3357
RB7
RB1
N
S


LA3238
RB10
RB1
C
S
LA3358
RB10
RB1
N
S


LA3239
RA3
RB1
C
S
LA3359
RA3
RB1
N
S


LA3240
RA34
RB1
C
S
LA3360
RA34
RB1
N
S


LA3241
H
RB1
C
O
LA3361
H
RB1
N
O


LA3242
RB1
RB1
C
O
LA3362
RB1
RB1
N
O


LA3243
RB3
RB1
C
O
LA3363
RB3
RB1
N
O


LA3244
RB4
RB1
C
O
LA3364
RB4
RB1
N
O


LA3245
RB7
RB1
C
O
LA3365
RB7
RB1
N
O


LA3246
RB10
RB1
C
O
LA3366
RB10
RB1
N
O


LA3247
RA3
RB1
C
O
LA3367
RA3
RB1
N
O


LA3248
RA34
RB1
C
O
LA3368
RA34
RB1
N
O


LA3249
H
RB1
C
NCH3
LA3369
H
RB1
N
NCH3


LA3250
RB1
RB1
C
NCH3
LA3370
RB1
RB1
N
NCH3


LA3251
RB3
RB1
C
NCH3
LA3371
RB3
RB1
N
NCH3


LA3252
RB4
RB1
C
NCH3
LA3372
RB4
RB1
N
NCH3


LA3253
RB7
RB1
C
NCH3
LA3373
RB7
RB1
N
NCH3


LA3254
RB10
RB1
C
NCH3
LA3374
RB10
RB1
N
NCH3


LA3255
RA3
RB1
C
NCH3
LA3375
RA3
RB1
N
NCH3


LA3256
RA34
RB1
C
NCH3
LA3376
RA34
RB1
N
NCH3


LA3257
H
RB1
C
C(CH3)2
LA3377
H
RB1
N
C(CH3)2


LA3258
RB1
RB1
C
C(CH3)2
LA3378
RB1
RB1
N
C(CH3)2


LA3259
RB3
RB1
C
C(CH3)2
LA3379
RB3
RB1
N
C(CH3)2


LA3260
RB4
RB1
C
C(CH3)2
LA3380
RB4
RB1
N
C(CH3)2


LA3261
RB7
RB1
C
C(CH3)2
LA3381
RB7
RB1
N
C(CH3)2


LA3262
RB10
RB1
C
C(CH3)2
LA3382
RB10
RB1
N
C(CH3)2


LA3263
RA3
RB1
C
C(CH3)2
LA3383
RA3
RB1
N
C(CH3)2


LA3264
RA34
RB1
C
C(CH3)2
LA3384
RA34
RB1
N
C(CH3)2


LA3265
H
RB1
C
Si(CH3)2
LA3385
H
RB1
N
Si(CH3)2


LA3266
RB1
RB1
C
Si(CH3)2
LA3386
RB1
RB1
N
Si(CH3)2


LA3267
RB3
RB1
C
Si(CH3)2
LA3387
RB3
RB1
N
Si(CH3)2


LA3268
RB4
RB1
C
Si(CH3)2
LA3388
RB4
RB1
N
Si(CH3)2


LA3269
RB7
RB1
C
Si(CH3)2
LA3389
RB7
RB1
N
Si(CH3)2


LA3270
RB10
RB1
C
Si(CH3)2
LA3390
RB10
RB1
N
Si(CH3)2


LA3271
RA3
RB1
C
Si(CH3)2
LA3391
RA3
RB1
N
Si(CH3)2


LA3272
RA34
RB1
C
Si(CH3)2
LA3392
RA34
RB1
N
Si(CH3)2


LA3273
H
RB6
C
S
LA3393
H
RB6
N
S


LA3274
RB1
RB6
C
S
LA3394
RB1
RB6
N
S


LA3275
RB3
RB6
C
S
LA3395
RB3
RB6
N
S


LA3276
RB4
RB6
C
S
LA3396
RB4
RB6
N
S


LA3277
RB7
RB6
C
S
LA3397
RB7
RB6
N
S


LA3278
RB10
RB6
C
S
LA3398
RB10
RB6
N
S


LA3279
RA3
RB6
C
S
LA3399
RA3
RB6
N
S


LA3280
RA34
RB6
C
S
LA3400
RA34
RB6
N
S


LA3281
H
RB6
C
O
LA3401
H
RB6
N
O


LA3282
RB1
RB6
C
O
LA3402
RB1
RB6
N
O


LA3283
RB3
RB6
C
O
LA3403
RB3
RB6
N
O


LA3284
RB4
RB6
C
O
LA3404
RB4
RB6
N
O


LA3285
RB7
RB6
C
O
LA3405
RB7
RB6
N
O


LA3286
RB10
RB6
C
O
LA3406
RB10
RB6
N
O


LA3287
RA3
RB6
C
O
LA3407
RA3
RB6
N
O


LA3288
RA34
RB6
C
O
LA3408
RA34
RB6
N
O


LA3289
H
RB6
C
NCH3
LA3409
H
RB6
N
NCH3


LA3290
RB1
RB6
C
NCH3
LA3410
RB1
RB6
N
NCH3


LA3291
RB3
RB6
C
NCH3
LA3411
RB3
RB6
N
NCH3


LA3292
RB4
RB6
C
NCH3
LA3412
RB4
RB6
N
NCH3


LA3293
RB7
RB6
C
NCH3
LA3413
RB7
RB6
N
NCH3


LA3294
RB10
RB6
C
NCH3
LA3414
RB10
RB6
N
NCH3


LA3295
RA3
RB6
C
NCH3
LA3415
RA3
RB6
N
NCH3


LA3296
RA34
RB6
C
NCH3
LA3416
RA34
RB6
N
NCH3


LA3297
H
RB6
C
C(CH3)2
LA3417
H
RB6
N
C(CH3)2


LA3298
RB1
RB6
C
C(CH3)2
LA3418
RB1
RB6
N
C(CH3)2


LA3299
RB3
RB6
C
C(CH3)2
LA3419
RB3
RB6
N
C(CH3)2


LA3300
RB4
RB6
C
C(CH3)2
LA3420
RB4
RB6
N
C(CH3)2


LA3301
RB7
RB6
C
C(CH3)2
LA3421
RB7
RB6
N
C(CH3)2


LA3302
RB10
RB6
C
C(CH3)2
LA3422
RB10
RB6
N
C(CH3)2


LA3303
RA3
RB6
C
C(CH3)2
LA3423
RA3
RB6
N
C(CH3)2


LA3304
RA34
RB6
C
C(CH3)2
LA3424
RA34
RB6
N
C(CH3)2


LA3305
H
RB6
C
Si(CH3)2
LA3425
H
RB6
N
Si(CH3)2


LA3306
RB1
RB6
C
Si(CH3)2
LA3426
RB1
RB6
N
Si(CH3)2


LA3307
RB3
RB6
C
Si(CH3)2
LA3427
RB3
RB6
N
Si(CH3)2


LA3308
RB4
RB6
C
Si(CH3)2
LA3428
RB4
RB6
N
Si(CH3)2


LA3309
RB7
RB6
C
Si(CH3)2
LA3429
RB7
RB6
N
Si(CH3)2


LA3310
RB10
RB6
C
Si(CH3)2
LA3430
RB10
RB6
N
Si(CH3)2


LA3311
RA3
RB6
C
Si(CH3)2
LA3431
RA3
RB6
N
Si(CH3)2


LA3312
RA34
RB6
C
Si(CH3)2
LA3432
RA34
RB6
N








wherein LA3433 through LA3552 have a structure of Formula XXIV:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA3433
H
H
S
LA3493
RB1
RB4
NCH3


LA3434
H
RB1
S
LA3494
RB1
RB5
NCH3


LA3435
H
RB2
S
LA3495
RB1
RA34
NCH3


LA3436
H
RB3
S
LA3496
RB1
RA52
NCH3


LA3437
H
RB4
S
LA3497
RB1
H
C(CH3)2


LA3438
H
RB5
S
LA3498
RB1
RB1
C(CH3)2


LA3439
H
RA34
S
LA3499
RB1
RB2
C(CH3)2


LA3440
H
RA52
S
LA3500
RB1
RB3
C(CH3)2


LA3441
H
H
O
LA3501
RB1
RB4
C(CH3)2


LA3442
H
RB1
O
LA3502
RB1
RB5
C(CH3)2


LA3443
H
RB2
O
LA3503
RB1
RA34
C(CH3)2


LA3444
H
RB3
O
LA3504
RB1
RA52
C(CH3)2


LA3445
H
RB4
O
LA3505
RB1
H
Si(CH3)2


LA3446
H
RB5
O
LA3506
RB1
RB1
Si(CH3)2


LA3447
H
RA34
O
LA3507
RB1
RB2
Si(CH3)2


LA3448
H
RA52
O
LA3508
RB1
RB3
Si(CH3)2


LA3449
H
H
NCH3
LA3509
RB1
RB4
Si(CH3)2


LA3450
H
RB1
NCH3
LA3510
RB1
RB5
Si(CH3)2


LA3451
H
RB2
NCH3
LA3511
RB1
RA34
Si(CH3)2


LA3452
H
RB3
NCH3
LA3512
RB1
RA52
Si(CH3)2


LA3453
H
RB4
NCH3
LA3513
RB6
H
S


LA3454
H
RB5
NCH3
LA3514
RB6
RB1
S


LA3455
H
RA34
NCH3
LA3515
RB6
RB2
S


LA3456
H
RA52
NCH3
LA3516
RB6
RB3
S


LA3457
H
H
C(CH3)2
LA3517
RB6
RB4
S


LA3458
H
RB1
C(CH3)2
LA3518
RB6
RB5
S


LA3459
H
RB2
C(CH3)2
LA3519
RB6
RA34
S


LA3460
H
RB3
C(CH3)2
LA3520
RB6
RA52
S


LA3461
H
RB4
C(CH3)2
LA3521
RB6
H
O


LA3462
H
RB5
C(CH3)2
LA3522
RB6
RB1
O


LA3463
H
RA34
C(CH3)2
LA3523
RB6
RB2
O


LA3464
H
RA52
C(CH3)2
LA3524
RB6
RB3
O


LA3465
H
H
Si(CH3)2
LA3525
RB6
RB4
O


LA3466
H
RB1
Si(CH3)2
LA3526
RB6
RB5
O


LA3467
H
RB2
Si(CH3)2
LA3527
RB6
RA34
O


LA3468
H
RB3
Si(CH3)2
LA3528
RB6
RA52
O


LA3469
H
RB4
Si(CH3)2
LA3529
RB6
H
NCH3


LA3470
H
RB5
Si(CH3)2
LA3530
RB6
RB1
NCH3


LA3471
H
RA34
Si(CH3)2
LA3531
RB6
RB2
NCH3


LA3472
H
RA52
Si(CH3)2
LA3532
RB6
RB3
NCH3


LA3473
RB1
H
S
LA3533
RB6
RB4
NCH3


LA3474
RB1
RB1
S
LA3534
RB6
RB5
NCH3


LA3475
RB1
RB2
S
LA3535
RB6
RA34
NCH3


LA3476
RB1
RB3
S
LA3536
RB6
RA52
NCH3


LA3477
RB1
RB4
S
LA3537
RB6
H
C(CH3)2


LA3478
RB1
RB5
S
LA3538
RB6
RB1
C(CH3)2


LA3479
RB1
RA34
S
LA3539
RB6
RB2
C(CH3)2


LA3480
RB1
RA52
S
LA3540
RB6
RB3
C(CH3)2


LA3481
RB1
H
O
LA3541
RB6
RB4
C(CH3)2


LA3482
RB1
RB1
O
LA3542
RB6
RB5
C(CH3)2


LA3483
RB1
RB2
O
LA3543
RB6
RA34
C(CH3)2


LA3484
RB1
RB3
O
LA3544
RB6
RA52
C(CH3)2


LA3485
RB1
RB4
O
LA3545
RB6
H
Si(CH3)2


LA3486
RB1
RB5
O
LA3546
RB6
RB1
Si(CH3)2


LA3487
RB1
RA34
O
LA3547
RB6
RB2
Si(CH3)2


LA3488
RB1
RA52
O
LA3548
RB6
RB3
Si(CH3)2


LA3489
RB1
H
NCH3
LA3549
RB6
RB4
Si(CH3)2


LA3490
RB1
RB1
NCH3
LA3550
RB6
RB5
Si(CH3)2


LA3491
RB1
RB2
NCH3
LA3551
RB6
RA34
Si(CH3)2


LA3492
RB1
RB3
NCH3
LA3552
RB6
RA52
Si(CH3)2








wherein LA3553 through LA3648 have a structure of Formula XXV:




wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA3553
H
H
S
S
LA3601
RB6
H
S
S


LA3554
H
RB1
S
S
LA3602
RB6
RB1
S
S


LA3555
H
RB3
S
S
LA3603
RB6
RB3
S
S


LA3556
H
RB4
S
S
LA3604
RB6
RB4
S
S


LA3557
H
RB7
S
S
LA3605
RB6
RB7
S
S


LA3558
H
RB10
S
S
LA3606
RB6
RB10
S
S


LA3559
H
RA3
S
S
LA3607
RB6
RA3
S
S


LA3560
H
RA34
S
S
LA3608
RB6
RA34
S
S


LA3561
H
H
S
O
LA3609
RB6
H
S
O


LA3562
H
RB1
S
O
LA3610
RB6
RB1
S
O


LA3563
H
RB3
S
O
LA3611
RB6
RB3
S
O


LA3564
H
RB4
S
O
LA3612
RB6
RB4
S
O


LA3565
H
RB7
S
O
LA3613
RB6
RB7
S
O


LA3566
H
RB10
S
O
LA3614
RB6
RB10
S
O


LA3567
H
RA3
S
O
LA3615
RB6
RA3
S
O


LA3568
H
RA34
S
O
LA3616
RB6
RA34
S
O


LA3569
H
H
S
NCH3
LA3617
RB6
H
S
NCH3


LA3570
H
RB1
S
NCH3
LA3618
RB6
RB1
S
NCH3


LA3571
H
RB3
S
NCH3
LA3619
RB6
RB3
S
NCH3


LA3572
H
RB4
S
NCH3
LA3620
RB6
RB4
S
NCH3


LA3573
H
RB7
S
NCH3
LA3621
RB6
RB7
S
NCH3


LA3574
H
RB10
S
NCH3
LA3622
RB6
RB10
S
NCH3


LA3575
H
RA3
S
NCH3
LA3623
RB6
RA3
S
NCH3


LA3576
H
RA34
S
NCH3
LA3624
RB6
RA34
S
NCH3


LA3577
H
H
O
S
LA3625
RB6
H
O
S


LA3578
H
RB1
O
S
LA3626
RB6
RB1
O
S


LA3579
H
RB3
O
S
LA3627
RB6
RB3
O
S


LA3580
H
RB4
O
S
LA3628
RB6
RB4
O
S


LA3581
H
RB7
O
S
LA3629
RB6
RB7
O
S


LA3582
H
RB10
O
S
LA3630
RB6
RB10
O
S


LA3583
H
RA3
O
S
LA3631
RB6
RA3
O
S


LA3584
H
RA34
O
S
LA3632
RB6
RA34
O
S


LA3585
H
H
O
O
LA3633
RB6
H
O
O


LA3586
H
RB1
O
O
LA3634
RB6
RB1
O
O


LA3587
H
RB3
O
O
LA3635
RB6
RB3
O
O


LA3588
H
RB4
O
O
LA3636
RB6
RB4
O
O


LA3589
H
RB7
O
O
LA3637
RB6
RB7
O
O


LA3590
H
RB10
O
O
LA3638
RB6
RB10
O
O


LA3591
H
RA3
O
O
LA3639
RB6
RA3
O
O


LA3592
H
RA34
O
O
LA3640
RB6
RA34
O
O


LA3593
H
H
O
NCH3
LA3641
RB6
H
O
NCH3


LA3594
H
RB1
O
NCH3
LA3642
RB6
RB1
O
NCH3


LA3595
H
RB3
O
NCH3
LA3643
RB6
RB3
O
NCH3


LA3596
H
RB4
O
NCH3
LA3644
RB6
RB4
O
NCH3


LA3597
H
RB7
O
NCH3
LA3645
RB6
RB7
O
NCH3


LA3598
H
RB10
O
NCH3
LA3646
RB6
RB10
O
NCH3


LA3599
H
RA3
O
NCH3
LA3647
RB6
RA3
O
NCH3


LA3600
H
RA34
O
NCH3
LA3648
RB6
RA34
O
NCH3








wherein LA3649 through LA3888 have a structure of Formula XXVI:




wherein R1, R5, X, and Y are defined as provided below:




















Ligand
R1
R5
X
Y
Ligand 
R1
R5
X
Y







LA3649
H
H
C
S
LA3769 
H
H
N
S


LA3650
RB1
H
C
S
LA3770
RB1
H
N
S


LA3651
RB3
H
C
S
LA3771
RB3
H
N
S


LA3652
RB4
H
C
S
LA3772
RB4
H
N
S


LA3653
RB7
H
C
S
LA3773
RB7
H
N
S


LA3654
RB10
H
C
S
LA3774
RB10
H
N
S


LA3655
RA3
H
C
S
LA3775 
RA3
H
N
S


LA3656
RA34
H
C
S
LA3776 
RA34
H
N
S


LA3657
H
H
C
O
LA3777 
H
H
N
O


LA3658
RB1
H
C
O
LA3778
RB1
H
N
O


LA3659
RB3
H
C
O
LA3779
RB3
H
N
O


LA3660
RB4
H
C
O
LA3780
RB4
H
N
O


LA3661
RB7
H
C
O
LA3781
RB7
H
N
O


LA3662
RB10
H
C
O
LA3782
RB10
H
N
O


LA3663
RA3
H
C
O
LA3783 
RA3
H
N
O


LA3664
RA34
H
C
O
LA3784
RA34
H
N
O


LA3665
H
H
C
NCH3
LA3785
H
H
N
NCH3


LA3666
RB1
H
C
NCH3
LA3786
RB1
H
N
NCH3


LA3667
RB3
H
C
NCH3
LA3787 
RB3
H
N
NCH3


LA3668
RB4
H
C
NCH3
LA3788 
RB4
H
N
NCH3


LA3669
RB7
H
C
NCH3
LA3789 
RB7
H
N
NCH3


LA3670
RB10
H
C
NCH3
LA3790
RB10
H
N
NCH3


LA3671
RA3
H
C
NCH3
LA3791 
RA3
H
N
NCH3


LA3672
RA34
H
C
NCH3
LA3792
RA34
H
N
NCH3


LA3673
H
H
C
C(CH3)2 
LA3793
H
H
N
C(CH3)2 


LA3674
RB1
H
C
C(CH3)2 
LA3794
RB1
H
N
C(CH3)2 


LA3675
RB3
H
C
C(CH3)2 
LA3795
RB3
H
N
C(CH3)2 


LA3676
RB4
H
C
C(CH3)2 
LA3796
RB4
H
N
C(CH3)2 


LA3677
RB7
H
C
C(CH3)2 
LA3797
RB7
H
N
C(CH3)2 


LA3678
RB10
H
C
C(CH3)2 
LA3798
RB10
H
N
C(CH3)2 


LA3679
RA3
H
C
C(CH3)2 
LA3799
RA3
H
N
C(CH3)2 


LA3680
RA34
H
C
C(CH3)2 
LA3800
RA34
H
N
C(CH3)2 


LA3681
H
H
C
Si(CH3)2
LA3801
H
H
N
Si(CH3)2


LA3682 
RB1
H
C
Si(CH3)2
LA3802
RB1
H
N
Si(CH3)2


LA3683 
RB3
H
C
Si(CH3)2
LA3803
RB3
H
N
Si(CH3)2


LA3684 
RB4
H
C
Si(CH3)2
LA3804
RB4
H
N
Si(CH3)2


LA3685 
RB7
H
C
Si(CH3)2
LA3805
RB7
H
N
Si(CH3)2


LA3686
RB10
H
C
Si(CH3)2
LA3806
RB10
H
N
Si(CH3)2


LA3687
RA3
H
C
Si(CH3)2
LA3807
RA3
H
N
Si(CH3)2


LA3688
RA34
H
C
Si(CH3)2
LA3808
RA34
H
N
Si(CH3)2


LA3689
H
RB1
C
S
LA3809
H
RB1
N
S


LA3690
RB1
RB1
C
S
LA3810
RB1
RB1
N
S


LA3691
RB3
RB1
C
S
LA3811
RB3
RB1
N
S


LA3692
RB4
RB1
C
S
LA3812
RB4
RB1
N
S


LA3693
RB7
RB1
C
S
LA3813
RB7
RB1
N
S


LA3694
RB10
RB1
C
S
LA3814
RB10
RB1
N
S


LA3695
RA3
RB1
C
S
LA3815
RA3
RB1
N
S


LA3696
RA34
RB1
C
S
LA3816
RA34
RB1
N
S


LA3697
H
RB1
C
O
LA3817
H
RB1
N
O


LA3698
RB1
RB1
C
O
LA3818
RB1
RB1
N
O


LA3699
RB3
RB1
C
O
LA3819
RB3
RB1
N
O


LA3700
RB4
RB1
C
O
LA3820
RB4
RB1
N
O


LA3701
RB7
RB1
C
O
LA3821
RB7
RB1
N
O


LA3702
RB10
RB1
C
O
LA3822
RB10
RB1
N
O


LA3703
RA3
RB1
C
O
LA3823
RA3
RB1
N
O


LA3704
RA34
RB1
C
O
LA3824
RA34
RB1
N
O


LA3705
H
RB1
C
NCH3
LA3825
H
RB1
N
NCH3


LA3706
RB1
RB1
C
NCH3
LA3826
RB1
RB1
N
NCH3


LA3707
RB3
RB1
C
NCH3
LA3827
RB3
RB1
N
NCH3


LA3708
RB4
RB1
C
NCH3
LA3828
RB4
RB1
N
NCH3


LA3709
RB7
RB1
C
NCH3
LA3829
RB7
RB1
N
NCH3


LA3710
RB10
RB1
C
NCH3
LA3830
RB10
RB1
N
NCH3


LA3711
RA3
RB1
C
NCH3
LA3831
RA3
RB1
N
NCH3


LA3712
RA34
RB1
C
NCH3
LA3832
RA34
RB1
N
NCH3


LA3713
H
RB1
C
C(CH3)2
LA3833
H
RB1
N
C(CH3)2


LA3714
RB1
RB1
C
C(CH3)2
LA3834
RB1
RB1
N
C(CH3)2


LA3715
RB3
RB1
C
C(CH3)2
LA3835
RB3
RB1
N
C(CH3)2


LA3716
RB4
RB1
C
C(CH3)2
LA3836
RB4
RB1
N
C(CH3)2


LA3717
RB7
RB1
C
C(CH3)2
LA3837
RB7
RB1
N
C(CH3)2


LA3718
RB10
RB1
C
C(CH3)2
LA3838
RB10
RB1
N
C(CH3)2


LA3719
RA3
RB1
C
C(CH3)2
LA3839
RA3
RB1
N
C(CH3)2


LA3720
RA34
RB1
C
C(CH3)2
LA3840
RA34
RB1
N
C(CH3)2


LA3721
H
RB1
C
Si(CH3)2
LA3841
H
RB1
N
Si(CH3)2


LA3722
RB1
RB1
C
Si(CH3)2
LA3842
RB1
RB1
N
Si(CH3)2


LA3723
RB3
RB1
C
Si(CH3)2
LA3843
RB3
RB1
N
Si(CH3)2


LA3724
RB4
RB1
C
Si(CH3)2
LA3844
RB4
RB1
N
Si(CH3)2


LA3725
RB7
RB1
C
Si(CH3)2
LA3845
RB7
RB1
N
Si(CH3)2


LA3726
RB10
RB1
C
Si(CH3)2
LA3846
RB10
RB1
N
Si(CH3)2


LA3727
RA3
RB1
C
Si(CH3)2
LA3847
RA3
RB1
N
Si(CH3)2


LA3728
RA34
RB1
C
Si(CH3)2
LA3848
RA34
RB1
N
Si(CH3)2


LA3729
H
RB6
C
S
LA3849
H
RB6
N
S


LA3730
RB1
RB6
C
S
LA3850
RB1
RB6
N
S


LA3731
RB3
RB6
C
S
LA3851
RB3
RB6
N
S


LA3732
RB4
RB6
C
S
LA3852
RB4
RB6
N
S


LA3733
RB7
RB6
C
S
LA3853
RB7
RB6
N
S


LA3734
RB10
RB6
C
S
LA3854
RB10
RB6
N
S


LA3735
RA3
RB6
C
S
LA3855
RA3
RB6
N
S


LA3736
RA34
RB6
C
S
LA3856
RA34
RB6
N
S


LA3737
H
RB6
C
O
LA3857
H
RB6
N
O


LA3738
RB1
RB6
C
O
LA3858
RB1
RB6
N
O


LA3739
RB3
RB6
C
O
LA3859
RB3
RB6
N
O


LA3740
RB4
RB6
C
O
LA3860
RB4
RB6
N
O


LA3741
RB7
RB6
C
O
LA3861
RB7
RB6
N
O


LA3742
RB10
RB6
C
O
LA3862
RB10
RB6
N
O


LA3743
RA3
RB6
C
O
LA3863
RA3
RB6
N
O


LA3744
RA34
RB6
C
O
LA3864
RA34
RB6
N
O


LA3745
H
RB6
C
NCH3
LA3865
H
RB6
N
NCH3


LA3746
RB1
RB6
C
NCH3
LA3866
RB1
RB6
N
NCH3


LA3747
RB3
RB6
C
NCH3
LA3867
RB3
RB6
N
NCH3


LA3748
RB4
RB6
C
NCH3
LA3868
RB4
RB6
N
NCH3


LA3749
RB7
RB6
C
NCH3
LA3869
RB7
RB6
N
NCH3


LA3750
RB10
RB6
C
NCH3
LA3870
RB10
RB6
N
NCH3


LA3751
RA3
RB6
C
NCH3
LA3871
RA3
RB6
N
NCH3


LA3752
RA34
RB6
C
NCH3
LA3872
RA34
RB6
N
NCH3


LA3753
H
RB6
C
C(CH3)2
LA3873
H
RB6
N
C(CH3)2


LA3754
RB1
RB6
C
C(CH3)2
LA3874
RB1
RB6
N
C(CH3)2


LA3755
RB3
RB6
C
C(CH3)2
LA3875
RB3
RB6
N
C(CH3)2


LA3756
RB4
RB6
C
C(CH3)2
LA3876
RB4
RB6
N
C(CH3)2


LA3757
RB7
RB6
C
C(CH3)2
LA3877
RB7
RB6
N
C(CH3)2


LA3758
RB10
RB6
C
C(CH3)2
LA3878
RB10
RB6
N
C(CH3)2


LA3759
RA3
RB6
C
C(CH3)2
LA3879
RA3
RB6
N
C(CH3)2


LA3760
RA34
RB6
C
C(CH3)2
LA3880
RA34
RB6
N
C(CH3)2


LA3761
H
RB6
C
Si(CH3)2
LA3881
H
RB6
N
Si(CH3)2


LA3762
RB1
RB6
C
Si(CH3)2
LA3882
RB1
RB6
N
Si(CH3)2


LA3763
RB3
RB6
C
Si(CH3)2
LA3883
RB3
RB6
N
Si(CH3)2


LA3764
RB4
RB6
C
Si(CH3)2
LA3884
RB4
RB6
N
Si(CH3)2


LA3765
RB7
RB6
C
Si(CH3)2
LA3885
RB7
RB6
N
Si(CH3)2


LA3766
RB10
RB6
C
Si(CH3)2
LA3886
RB10
RB6
N
Si(CH3)2


LA3767
RA3
RB6
C
Si(CH3)2
LA3887
RA3
RB6
N
Si(CH3)2


LA3768
RA34
RB6
C
Si(CH3)2
LA3888
RA34
RB6
N
Si(CH3)2








wherein LA3889 through LA4008 have a structure of Formula XXVII:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA3889
H
H
S
LA3949
RB1
RB4
NCH3


LA3890
H
RB1
S
LA3950
RB1
RB5
NCH3


LA3891
H
RB2
S
LA3951
RB1
RA34
NCH3


LA3892
H
RB3
S
LA3952
RB1
RA52
NCH3


LA3893
H
RB4
S
LA3953
RB1
H
C(CH3)2


LA3894
H
RB5
S
LA3954
RB1
RB1
C(CH3)2


LA3895
H
RA34
S
LA3955
RB1
RB2
C(CH3)2


LA3896
H
RA52
S
LA3956
RB1
RB3
C(CH3)2


LA3897
H
H
O
LA3957
RB1
RB4
C(CH3)2


LA3898
H
RB1
O
LA3958
RB1
RB5
C(CH3)2


LA3899
H
RB2
O
LA3959
RB1
RA34
C(CH3)2


LA3900
H
RB3
O
LA3960
RB1
RA52
C(CH3)2


LA3901
H
RB4
O
LA3961
RB1
H
Si(CH3)2


LA3902
H
RB5
O
LA3962
RB1
RB1
Si(CH3)2


LA3903
H
RA34
O
LA3963
RB1
RB2
Si(CH3)2


LA3904
H
RA52
O
LA3964
RB1
RB3
Si(CH3)2


LA3905
H
H
NCH3
LA3965
RB1
RB4
Si(CH3)2


LA3906
H
RB1
NCH3
LA3966
RB1
RB5
Si(CH3)2


LA3907
H
RB2
NCH3
LA3967
RB1
RA34
Si(CH3)2


LA3908
H
RB3
NCH3
LA3968
RB1
RA52
Si(CH3)2


LA3909
H
RB4
NCH3
LA3969
RB6
H
S


LA3910
H
RB5
NCH3
LA3970
RB6
RB1
S


LA3911
H
RA34
NCH3
LA3971
RB6
RB2
S


LA3912
H
RA52
NCH3
LA3972
RB6
RB3
S


LA3913
H
H
C(CH3)2
LA3973
RB6
RB4
S


LA3914
H
RB1
C(CH3)2
LA3974
RB6
RB5
S


LA3915
H
RB2
C(CH3)2
LA3975
RB6
RA34
S


LA3916
H
RB3
C(CH3)2
LA3976
RB6
RA52
S


LA3917
H
RB4
C(CH3)2
LA3977
RB6
H
O


LA3918
H
RB5
C(CH3)2
LA3978
RB6
RB1
O


LA3919
H
RA34
C(CH3)2
LA3979
RB6
RB2
O


LA3920
H
RA52
C(CH3)2
LA3980
RB6
RB3
O


LA3921
H
H
Si(CH3)2
LA3981
RB6
RB4
O


LA3922
H
RB1
Si(CH3)2
LA3982
RB6
RB5
O


LA3923
H
RB2
Si(CH3)2
LA3983
RB6
RA34
O


LA3924
H
RB3
Si(CH3)2
LA3984
RB6
RA52
O


LA3925
H
RB4
Si(CH3)2
LA3985
RB6
H
NCH3


LA3926
H
RB5
Si(CH3)2
LA3986
RB6
RB1
NCH3


LA3927
H
RA34
Si(CH3)2
LA3987
RB6
RB2
NCH3


LA3928
H
RA52
Si(CH3)2
LA3988
RB6
RB3
NCH3


LA3929
RB1
H
S
LA3989
RB6
RB4
NCH3


LA3930
RB1
RB1
S
LA3990
RB6
RB5
NCH3


LA3931
RB1
RB2
S
LA3991
RB6
RA34
NCH3


LA3932
RB1
RB3
S
LA3992
RB6
RA52
NCH3


LA3933
RB1
RB4
S
LA3993
RB6
H
C(CH3)2


LA3934
RB1
RB5
S
LA3994
RB6
RB1
C(CH3)2


LA3935
RB1
RA34
S
LA3995
RB6
RB2
C(CH3)2


LA3936
RB1
RA52
S
LA3996
RB6
RB3
C(CH3)2


LA3937
RB1
H
O
LA3997
RB6
RB4
C(CH3)2


LA3938
RB1
RB1
O
LA3998
RB6
RB5
C(CH3)2


LA3939
RB1
RB2
O
LA3999
RB6
RA34
C(CH3)2


LA3940
RB1
RB3
O
LA4000
RB6
RA52
C(CH3)2


LA3941
RB1
RB4
O
LA4001
RB6
H
Si(CH3)2


LA3942
RB1
RB5
O
LA4002
RB6
RB1
Si(CH3)2


LA3943
RB1
RA34
O
LA4003
RB6
RB2
Si(CH3)2


LA3944
RB1
RA52
O
LA4004
RB6
RB3
Si(CH3)2


LA3945
RB1
H
NCH3
LA4005
RB6
RB4
Si(CH3)2


LA3946
RB1
RB1
NCH3
LA4006
RB6
RB5
Si(CH3)2


LA3947
RB1
RB2
NCH3
LA4007
RB6
RA34
Si(CH3)2


LA3948
RB1
RB3
NCH3
LA4008
RB6
RA52
Si(CH3)2








wherein LA4009 through LA4104 have a structure of Formula XXVIII:




wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA4009
H
H
S
S
LA4057
RB6
H
S
S


LA4010
H
RB1
S
S
LA4058
RB6
RB1
S
S


LA4011
H
RB3
S
S
LA4059
RB6
RB3
S
S


LA4012
H
RB4
S
S
LA4060
RB6
RB4
S
S


LA4013
H
RB7
S
S
LA4061
RB6
RB7
S
S


LA4014
H
RB10
S
S
LA4062
RB6
RB10
S
S


LA4015
H
RA3
S
S
LA4063
RB6
RA3
S
S


LA4016
H
RA34
S
S
LA4064
RB6
RA34
S
S


LA4017
H
H
S
O
LA4065
RB6
H
S
O


LA4018
H
RB1
S
O
LA4066
RB6
RB1
S
O


LA4019
H
RB3
S
O
LA4067
RB6
RB3
S
O


LA4020
H
RB4
S
O
LA4068
RB6
RB4
S
O


LA4021
H
RB7
S
O
LA4069
RB6
RB7
S
O


LA4022
H
RB10
S
O
LA4070
RB6
RB10
S
O


LA4023
H
RA3
S
O
LA4071
RB6
RA3
S
O


LA4024
H
RA34
S
O
LA4072
RB6
RA34
S
O


LA4025
H
H
S
NCH3
LA4073
RB6
H
S
NCH3


LA4026
H
RB1
S
NCH3
LA4074
RB6
RB1
S
NCH3


LA4027 
H
RB3
S
NCH3
LA4075
RB6
RB3
S
NCH3


LA4028 
H
RB4
S
NCH3
LA4076
RB6
RB4
S
NCH3


LA4029 
H
RB7
S
NCH3
LA4077
RB6
RB7
S
NCH3


LA4030 
H
RB10
S
NCH3
LA4078
RB6
RB10
S
NCH3


LA4031 
H
RA3
S
NCH3
LA4079
RB6
RA3
S
NCH3


LA4032 
H
RA34
S
NCH3
LA4080
RB6
RA34
S
NCH3


LA4033 
H
H
O
S
LA4081
RB6
H
O
S


LA4034 
H
RB1
O
S
LA4082
RB6
RB1
O
S


LA4035 
H
RB3
O
S
LA4083
RB6
RB3
O
S


LA4036 
H
RB4
O
S
LA4084
RB6
RB4
O
S


LA4037 
H
RB7
O
S
LA4085
RB6
RB7
O
S


LA4038 
H
RB10
O
S
LA4086
RB6
RB10
O
S


LA4039 
H
RA3
O
S
LA4087
RB6
RA3
O
S


LA4040 
H
RA34
O
S
LA4088
RB6
RA34
O
S


LA4041 
H
H
O
O
LA4089
RB6
H
O
O


LA4042 
H
RB1
O
O
LA4090
RB6
RB1
O
O


LA4043 
H
RB3
O
O
LA4091
RB6
RB3
O
O


LA4044 
H
RB4
O
O
LA4092
RB6
RB4
O
O


LA4045 
H
RB7
O
O
LA4093
RB6
RB7
O
O


LA4046 
H
RB10
O
O
LA4094
RB6
RB10
O
O


LA4047 
H
RA3
O
O
LA4095
RB6
RA3
O
O


LA4048 
H
RA34
O
O
LA4096
RB6
RA34
O
O


LA4049 
H
H
O
NCH3
LA4097
RB6
H
O
NCH3


LA4050 
H
RB1
O
NCH3
LA4098
RB6
RB1
O
NCH3


LA4051 
H
RB3
O
NCH3
LA4099
RB6
RB3
O
NCH3


LA4052 
H
RB4
O
NCH3
LA4100
RB6
RB4
O
NCH3


LA4053 
H
RB7
O
NCH3
LA4101
RB6
RB7
O
NCH3


LA4054 
H
RB10
O
NCH3
LA4102
RB6
RB10
O
NCH3


LA4055 
H
RA3
O
NCH3
LA4103
RB6
RA3
O
NCH3


LA4056 
H
RA34
O
NCH3
LA4104
RB6
RA34
O
NCH3








wherein LA4225 through LA4344 have a structure of Formula XXIX:




wherein R1, R5, X, and Y are defined as provided below:


















Ligand
R1
R5
X
Y









LA4225 
H
H
N
S



LA4226 
RB1
H
N
S



LA4227 
RB3
H
N
S



LA4228 
RB4
H
N
S



LA4229 
RB7
H
N
S



LA4230
RB10
H
N
S



LA4231
RA3
H
N
S



LA4232
RA34
H
N
S



LA4233
H
H
N
O



LA4234
RB1
H
N
O



LA4235
RB3
H
N
O



LA4236
RB4
H
N
O



LA4237
RB7
H
N
O



LA4238
RB10
H
N
O



LA4239
RA3
H
N
O



LA4240
RA34
H
N
O



LA4241
H
H
N
NCH3



LA4242
RB1
H
N
NCH3



LA4243
RB3
H
N
NCH3



LA4244
RB4
H
N
NCH3



LA4245
RB7
H
N
NCH3



LA4246
RB10
H
N
NCH3



LA4247
RA3
H
N
NCH3



LA4248
RA34
H
N
NCH3



LA4249
H
H
N
C(CH3)2 



LA4250
RB1
H
N
C(CH3)2 



LA4251
RB3
H
N
C(CH3)2 



LA4252
RB4
H
N
C(CH3)2 



LA4253
RB7
H
N
C(CH3)2 



LA4254
RB10
H
N
C(CH3)2 



LA4255
RA3
H
N
C(CH3)2 



LA4256
RA34
H
N
C(CH3)2 



LA4257
H
H
N
Si(CH3)2



LA4258
RB1
H
N
Si(CH3)2



LA4259
RB3
H
N
Si(CH3)2



LA4260
RB4
H
N
Si(CH3)2



LA4261
RB7
H
N
Si(CH3)2



LA4262
RB10
H
N
Si(CH3)2



LA4263
RA3
H
N
Si(CH3)2



LA4264
RA34
H
N
Si(CH3)2



LA4265
H
RB1
N
S



LA4266
RB1
RB1
N
S



LA4267
RB3
RB1
N
S



LA4268
RB4
RB1
N
S



LA4269
RB7
RB1
N
S



LA4270
RB10
RB1
N
S



LA4271
RA3
RB1
N
S



LA4272
RA34
RB1
N
S



LA4273
H
RB1
N
O



LA4274
RB1
RB1
N
O



LA4275
RB3
RB1
N
O



LA4276
RB4
RB1
N
O



LA4277
RB7
RB1
N
O



LA4278
RB10
RB1
N
O



LA4279
RA3
RB1
N
O



LA4280
RA34
RB1
N
O



LA4281
H
RB1
N
NCH3



LA4282
RB1
RB1
N
NCH3



LA4283
RB3
RB1
N
NCH3



LA4284
RB4
RB1
N
NCH3



LA4285
RB7
RB1
N
NCH3



LA4286
RB10
RB1
N
NCH3



LA4287
RA3
RB1
N
NCH3



LA4288
RA34
RB1
N
NCH3



LA4289
H
RB1
N
C(CH3)2 



LA4290
RB1
RB1
N
C(CH3)2 



LA4291
RB3
RB1
N
C(CH3)2 



LA4292
RB4
RB1
N
C(CH3)2 



LA4293
RB7
RB1
N
C(CH3)2 



LA4294
RB10
RB1
N
C(CH3)2 



LA4295
RA3
RB1
N
C(CH3)2 



LA4296
RA34
RB1
N
C(CH3)2 



LA4297
H
RB1
N
Si(CH3)2



LA4298
RB1
RB1
N
Si(CH3)2



LA4299
RB3
RB1
N
Si(CH3)2



LA4300
RB4
RB1
N
Si(CH3)2



LA4301
RB7
RB1
N
Si(CH3)2



LA4302
RB10
RB1
N
Si(CH3)2



LA4303
RA3
RB1
N
Si(CH3)2



LA4304
RA34
RB1
N
Si(CH3)2



LA4305
H
RB6
N
S



LA4306
RB1
RB6
N
S



LA4307
RB3
RB6
N
S



LA4308
RB4
RB6
N
S



LA4309
RB7
RB6
N
S



LA4310
RB10
RB6
N
S



LA4311
RA3
RB6
N
S



LA4312
RA34
RB6
N
S



LA4313
H
RB6
N
O



LA4314
RB1
RB6
N
O



LA4315
RB3
RB6
N
O



LA4316
RB4
RB6
N
O



LA4317
RB7
RB6
N
O



LA4318
RB10
RB6
N
O



LA4319
RA3
RB6
N
O



LA4320
RA34
RB6
N
O



LA4321
H
RB6
N
NCH3



LA4322
RB1
RB6
N
NCH3



LA4323
RB3
RB6
N
NCH3



LA4324
RB4
RB6
N
NCH3



LA4325
RB7
RB6
N
NCH3



LA4326
RB10
RB6
N
NCH3



LA4327
RA3
RB6
N
NCH3



LA4328
RA34
RB6
N
NCH3



LA4329
H
RB6
N
C(CH3)2



LA4330
RB1
RB6
N
C(CH3)2



LA4331
RB3
RB6
N
C(CH3)2



LA4332
RB4
RB6
N
C(CH3)2



LA4333
RB7
RB6
N
C(CH3)2



LA4334
RB10
RB6
N
C(CH3)2



LA4335
RA3
RB6
N
C(CH3)2



LA4336
RA34
RB6
N
C(CH3)2



LA4337
H
RB6
N
Si(CH3)2



LA4338
RB1
RB6
N
Si(CH3)2



LA4339
RB3
RB6
N
Si(CH3)2



LA4340
RB4
RB6
N
Si(CH3)2



LA4341
RB7
RB6
N
Si(CH3)2



LA4342
RB10
RB6
N
Si(CH3)2



LA4343
RA3
RB6
N
Si(CH3)2



LA4344
RA34
RB6
N
Si(CH3)2









wherein LA4345 through LA4464 have a structure of Formula XXX:




wherein R3, R5, and Y are defined as provided below:


















Ligand
R5
R3
Y
Ligand
R5
R3
Y







LA4345
H
H
S
LA4405
RB1
RB4
NCH3


LA4346
H
RB1
S
LA4406
RB1
RB5
NCH3


LA4347
H
RB2
S
LA4407
RB1
RA34
NCH3


LA4348
H
RB3
S
LA4408
RB1
RA52
NCH3


LA4349
H
RB4
S
LA4409
RB1
H
C(CH3)2


LA4350
H
RB5
S
LA4410
RB1
RB1
C(CH3)2


LA4351
H
RA34
S
LA4411
RB1
RB2
C(CH3)2


LA4352
H
RA52
S
LA4412
RB1
RB3
C(CH3)2


LA4353
H
H
O
LA4413
RB1
RB4
C(CH3)2


LA4354
H
RB1
O
LA4414
RB1
RB5
C(CH3)2


LA4355
H
RB2
O
LA4415
RB1
RA34
C(CH3)2


LA4356
H
RB3
O
LA4416
RB1
RA52
C(CH3)2


LA4357
H
RB4
O
LA4417
RB1
H
Si(CH3)2


LA4358
H
RB5
O
LA4418
RB1
RB1
Si(CH3)2


LA4359
H
RA34
O
LA4419
RB1
RB2
Si(CH3)2


LA4360
H
RA52
O
LA4420
RB1
RB3
Si(CH3)2


LA4361
H
H
NCH3
LA4421
RB1
RB4
Si(CH3)2


LA4362
H
RB1
NCH3
LA4422
RB1
RB5
Si(CH3)2


LA4363
H
RB2
NCH3
LA4423
RB1
RA34
Si(CH3)2


LA4364
H
RB3
NCH3
LA4424
RB1
RA52
Si(CH3)2


LA4365
H
RB4
NCH3
LA4425
RB6
H
S


LA4366
H
RB5
NCH3
LA4426
RB6
RB1
S


LA4367
H
RA34
NCH3
LA4427
RB6
RB2
S


LA4368
H
RA52
NCH3
LA4428
RB6
RB3
S


LA4369
H
H
C(CH3)2
LA4429
RB6
RB4
S


LA4370
H
RB1
C(CH3)2
LA4430
RB6
RB5
S


LA4371
H
RB2
C(CH3)2
LA4431
RB6
RA34
S


LA4372
H
RB3
C(CH3)2
LA4432
RB6
RA52
S


LA4373
H
RB4
C(CH3)2
LA4433
RB6
H
O


LA4374
H
RB5
C(CH3)2
LA4434
RB6
RB1
O


LA4375
H
RA34
C(CH3)2
LA4435
RB6
RB2
O


LA4376
H
RA52
C(CH3)2
LA4436
RB6
RB3
O


LA4377
H
H
Si(CH3)2
LA4437
RB6
RB4
O


LA4378
H
RB1
Si(CH3)2
LA4438
RB6
RB5
O


LA4379
H
RB2
Si(CH3)2
LA4439
RB6
RA34
O


LA4380
H
RB3
Si(CH3)2
LA4440
RB6
RA52
O


LA4381
H
RB4
Si(CH3)2
LA4441
RB6
H
NCH3


LA4382
H
RB5
Si(CH3)2
LA4442
RB6
RB1
NCH3


LA4383
H
RA34
Si(CH3)2
LA4443
RB6
RB2
NCH3


LA4384
H
RA52
Si(CH3)2
LA4444
RB6
RB3
NCH3


LA4385
RB1
H
S
LA4445
RB6
RB4
NCH3


LA4386
RB1
RB1
S
LA4446
RB6
RB5
NCH3


LA4387
RB1
RB2
S
LA4447
RB6
RA34
NCH3


LA4388
RB1
RB3
S
LA4448
RB6
RA52
NCH3


LA4389
RB1
RB4
S
LA4449
RB6
H
C(CH3)2


LA4390
RB1
RB5
S
LA4450
RB6
RB1
C(CH3)2


LA4391
RB1
RA34
S
LA4451
RB6
RB2
C(CH3)2


LA4392
RB1
RA52
S
LA4452
RB6
RB3
C(CH3)2


LA4393
RB1
H
O
LA4453
RB6
RB4
C(CH3)2


LA4394
RB1
RB1
O
LA4454
RB6
RB5
C(CH3)2


LA4395
RB1
RB2
O
LA4455
RB6
RA34
C(CH3)2


LA4396
RB1
RB3
O
LA4456
RB6
RA52
C(CH3)2


LA4397
RB1
RB4
O
LA4457
RB6
H
Si(CH3)2


LA4398
RB1
RB5
O
LA4458
RB6
RB1
Si(CH3)2


LA4399
RB1
RA34
O
LA4459
RB6
RB2
Si(CH3)2


LA4400
RB1
RA52
O
LA4460
RB6
RB3
Si(CH3)2


LA4401
RB1
H
NCH3
LA4461
RB6
RB4
Si(CH3)2


LA4402
RB1
RB1
NCH3
LA4462
RB6
RB5
Si(CH3)2


LA4403
RB1
RB2
NCH3
LA4463
RB6
RA34
Si(CH3)2


LA4404
RB1
RB3
NCH3
LA4464
RB6
RA52
Si(CH3)2








wherein LA4465 through LA4560 have a structure of Formula XXXI:




wherein R4, R5, Y, and Z are defined as provided below:




















Ligand
R5
R4
Y
Z
Ligand
R5
R4
Y
Z







LA4465
H
H
S
S
LA4513
RB6
H
S
S


LA4466
H
RB1
S
S
LA4514
RB6
RB1
S
S


LA4467
H
RB3
S
S
LA4515
RB6
RB3
S
S


LA4468
H
RB4
S
S
LA4516
RB6
RB4
S
S


LA4469
H
RB7
S
S
LA4517
RB6
RB7
S
S


LA4470
H
RB10
S
S
LA4518
RB6
RB10
S
S


LA4471
H
RA3
S
S
LA4519
RB6
RA3
S
S


LA4472
H
RA34
S
S
LA4520
RB6
RA34
S
S


LA4473
H
H
S
O
LA4521
RB6
H
S
O


LA4474
H
RB1
S
O
LA4522
RB6
RB1
S
O


LA4475
H
RB3
S
O
LA4523
RB6
RB3
S
O


LA4476
H
RB4
S
O
LA4524
RB6
RB4
S
O


LA4477
H
RB7
S
O
LA4525
RB6
RB7
S
O


LA4478
H
RB10
S
O
LA4526
RB6
RB10
S
O


LA4479
H
RA3
S
O
LA4527
RB6
RA3
S
O


LA4480
H
RA34
S
O
LA4528
RB6
RA34
S
O


LA4481
H
H
S
NCH3
LA4529
RB6
H
S
NCH3


LA4482
H
RB1
S
NCH3
LA4530
RB6
RB1
S
NCH3


LA4483
H
RB3
S
NCH3
LA4531
RB6
RB3
S
NCH3


LA4484
H
RB4
S
NCH3
LA4532
RB6
RB4
S
NCH3


LA4485
H
RB7
S
NCH3
LA4533
RB6
RB7
S
NCH3


LA4486
H
RB10
S
NCH3
LA4534
RB6
RB10
S
NCH3


LA4487
H
RA3
S
NCH3
LA4535
RB6
RA3
S
NCH3


LA4488
H
RA34
S
NCH3
LA4536
RB6
RA34
S
NCH3


LA4489
H
H
O
S
LA4537
RB6
H
O
S


LA4490
H
RB1
O
S
LA4538
RB6
RB1
O
S


LA4491
H
RB3
O
S
LA4539
RB6
RB3
O
S


LA4492
H
RB4
O
S
LA4540
RB6
RB4
O
S


LA4493
H
RB7
O
S
LA4541
RB6
RB7
O
S


LA4494
H
RB10
O
S
LA4542
RB6
RB10
O
S


LA4495
H
RA3
O
S
LA4543
RB6
RA3
O
S


LA4496
H
RA34
O
S
LA4544
RB6
RA34
O
S


LA4497
H
H
O
O
LA4545
RB6
H
O
O


LA4498
H
RB1
O
O
LA4546
RB6
RB1
O
O


LA4499
H
RB3
O
O
LA4547
RB6
RB3
O
O


LA4500
H
RB4
O
O
LA4548
RB6
RB4
O
O


LA4501
H
RB7
O
O
LA4549
RB6
RB7
O
O


LA4502
H
RB10
O
O
LA4550
RB6
RB10
O
O


LA4503
H
RA3
O
O
LA4551
RB6
RA3
O
O


LA4504
H
RA34
O
O
LA4552
RB6
RA34
O
O


LA4505
H
H
O
NCH3
LA4553
RB6
H
O
NCH3


LA4506
H
RB1
O
NCH3
LA4554
RB6
RB1
O
NCH3


LA4507
H
RB3
O
NCH3
LA4555
RB6
RB3
O
NCH3


LA4508
H
RB4
O
NCH3
LA4556
RB6
RB4
O
NCH3


LA4509
H
RB7
O
NCH3
LA4557
RB6
RB7
O
NCH3


LA4510
H
RB10
O
NCH3
LA4558
RB6
RB10
O
NCH3


LA4511
H
RA3
O
NCH3
LA4559
RB6
RA3
O
NCH3


LA4512
H
RA34
O
NCH3
LA4560
RB6
RA34
O
NCH3








wherein LA4561 through LA4780 have a structure of Formula XXXII:




wherein R1, R2, R3, and Y are defined as provided below:




















Ligand
R1
R3
R2
Y
Ligand
R1
R3
R2
Y







LA4561
H
H
H
O
LA4671
H
H
RB1
O


LA4562
RB1
RB1
H
O
LA4672
RB1
RB1
RB1
O


LA4563
RB3
RB3
H
O
LA4673
RB3
RB3
RB1
O


LA4564
RB4
RB4
H
O
LA4674
RB4
RB4
RB1
O


LA4565
RB7
RB7
H
O
LA4675
RB7
RB7
RB1
O


LA4566
RB10
RB10
H
O
LA4676 
RB10
RB10
RB1
O


LA4567
RA3
RA3
H
O
LA4677
RA3
RA3
RB1
O


LA4568
RA34
RA34
H
O
LA4678 
RA34
RA34
RB1
O


LA4569
RB1
H
H
O
LA4679
RB1
H
RB1
O


LA4570
RB3
H
H
O
LA4680
RB3
H
RB1
O


LA4571
RB4
H
H
O
LA4681
RB4
H
RB1
O


LA4572
RB7
H
H
O
LA4682
RB7
H
RB1
O


LA4573
RB10
H
H
O
LA4683 
RB10
H
RB1
O


LA4574
RA3
H
H
O
LA4684
RA3
H
RB1
O


LA4575
RA34
H
H
O
LA4685 
RA34
H
RB1
O


LA4576
H
RB1
H
O
LA4686
H
RB1
RB1
O


LA4577
H
RB3
H
O
LA4687
H
RB3
RB1
O


LA4578
H
RB4
H
O
LA4688
H
RB4
RB1
O


LA4579
H
RB7
H
O
LA4689
H
RB7
RB1
O


LA4580
H
RB10
H
O
LA4690
H
RB10
RB1
O


LA4581
H
RA3
H
O
LA4691
H
RA3
RB1
O


LA4582
H
RA34
H
O
LA4692
H
RA34
RB1
O


LA4583
H
H
H
S
LA4693
H
H
RB1
S


LA4584
RB1
RB1
H
S
LA4694
RB1
RB1
RB1
S


LA4585
RB3
RB3
H
S
LA4695
RB3
RB3
RB1
S


LA4586
RB4
RB4
H
S
LA4696
RB4
RB4
RB1
S


LA4587
RB7
RB7
H
S
LA4697
RB7
RB7
RB1
S


LA4588
RB10
RB10
H
S
LA4698
RB10
RB10
RB1
S


LA4589
RA3
RA3
H
S
LA4699
RA3
RA3
RB1
S


LA4590
RA34
RA34
H
S
LA4700
RA34
RA34
RB1
S


LA4591
RB1
H
H
S
LA4701
RB1
H
RB1
S


LA4592
RB3
H
H
S
LA4702
RB3
H
RB1
S


LA4593
RB4
H
H
S
LA4703
RB4
H
RB1
S


LA4594
RB7
H
H
S
LA4704
RB7
H
RB1
S


LA4595
RB10
H
H
S
LA4705
RB10
H
RB1
S


LA4596
RA3
H
H
S
LA4706
RA3
H
RB1
S


LA4597
RA34
H
H
S
LA4707
RA34
H
RB1
S


LA4598
H
RB1
H
S
LA4708
H
RB1
RB1
S


LA4599
H
RB3
H
S
LA4709
H
RB3
RB1
S


LA4600
H
RB4
H
S
LA4710
H
RB4
RB1
S


LA4601
H
RB7
H
S
LA4711
H
RB7
RB1
S


LA4602
H
RB10
H
S
LA4712
H
RB10
RB1
S


LA4603
H
RA3
H
S
LA4713
H
RA3
RB1
S


LA4604
H
RA34
H
S
LA4714
H
RA34
RB1
S


LA4605
H
H
H
NCH3
LA4715
H
H
RB1
NCH3


LA4606
RB1
RB1
H
NCH3
LA4716
RB1
RB1
RB1
NCH3


LA4607
RB3
RB3
H
NCH3
LA4717
RB3
RB3
RB1
NCH3


LA4608
RB4
RB4
H
NCH3
LA4718
RB4
RB4
RB1
NCH3


LA4609
RB7
RB7
H
NCH3
LA4719
RB7
RB7
RB1
NCH3


LA4610
RB10
RB10
H
NCH3
LA4720
RB10
RB10
RB1
NCH3


LA4611
RA3
RA3
H
NCH3
LA4721
RA3
RA3
RB1
NCH3


LA4612
RA34
RA34
H
NCH3
LA4722
RA34
RA34
RB1
NCH3


LA4613
RB1
H
H
NCH3
LA4723
RB1
H
RB1
NCH3


LA4614
RB3
H
H
NCH3
LA4724
RB3
H
RB1
NCH3


LA4615
RB4
H
H
NCH3
LA4725
RB4
H
RB1
NCH3


LA4616
RB7
H
H
NCH3
LA4726
RB7
H
RB1
NCH3


LA4617
RB10
H
H
NCH3
LA4727
RB10
H
RB1
NCH3


LA4618
RA3
H
H
NCH3
LA4728
RA3
H
RB1
NCH3


LA4619
RA34
H
H
NCH3
LA4729
RA34
H
RB1
NCH3


LA4620
H
RB1
H
NCH3
LA4730
H
RB1
RB1
NCH3


LA4621
H
RB3
H
NCH3
LA4731
H
RB3
RB1
NCH3


LA4622
H
RB4
H
NCH3
LA4732
H
RB4
RB1
NCH3


LA4623
H
RB7
H
NCH3
LA4733
H
RB7
RB1
NCH3


LA4624
H
RB10
H
NCH3
LA4734
H
RB10
RB1
NCH3


LA4625
H
RA3
H
NCH3
LA4735
H
RA3
RB1
NCH3


LA4626
H
RA34
H
NCH3
LA4736
H
RA34
RB1
NCH3


LA4627
H
H
H
C(CH3)2
LA4737
H
H
RB1
C(CH3)2


LA4628
RB1
RB1
H
C(CH3)2
LA4738
RB1
RB1
RB1
C(CH3)2


LA4629
RB3
RB3
H
C(CH3)2
LA4739
RB3
RB3
RB1
C(CH3)2


LA4630
RB4
RB4
H
C(CH3)2
LA4740
RB4
RB4
RB1
C(CH3)2


LA4631
RB7
RB7
H
C(CH3)2
LA4741
RB7
RB7
RB1
C(CH3)2


LA4632
RB10
RB10
H
C(CH3)2
LA4742
RB10
RB10
RB1
C(CH3)2


LA4633
RA3
RA3
H
C(CH3)2
LA4743
RA3
RA3
RB1
C(CH3)2


LA4634
RA34
RA34
H
C(CH3)2
LA4744
RA34
RA34
RB1
C(CH3)2


LA4635
RB1
H
H
C(CH3)2
LA4745
RB1
H
RB1
C(CH3)2


LA4636
RB3
H
H
C(CH3)2
LA4746
RB3
H
RB1
C(CH3)2


LA4637
RB4
H
H
C(CH3)2
LA4747
RB4
H
RB1
C(CH3)2


LA4638
RB7
H
H
C(CH3)2
LA4748
RB7
H
RB1
C(CH3)2


LA4639
RB10
H
H
C(CH3)2
LA4749
RB10
H
RB1
C(CH3)2


LA4640
RA3
H
H
C(CH3)2
LA4750
RA3
H
RB1
C(CH3)2


LA4641
RA34
H
H
C(CH3)2
LA4751
RA34
H
RB1
C(CH3)2


LA4642
H
RB1
H
C(CH3)2
LA4752
H
RB1
RB1
C(CH3)2


LA4643
H
RB3
H
C(CH3)2
LA4753
H
RB3
RB1
C(CH3)2


LA4644
H
RB4
H
C(CH3)2
LA4754
H
RB4
RB1
C(CH3)2


LA4645
H
RB7
H
C(CH3)2
LA4755
H
RB7
RB1
C(CH3)2


LA4646
H
RB10
H
C(CH3)2
LA4756
H
RB10
RB1
C(CH3)2


LA4647
H
RA3
H
C(CH3)2
LA4757
H
RA3
RB1
C(CH3)2


LA4648
H
RA34
H
C(CH3)2
LA4758
H
RA34
RB1
C(CH3)2


LA4649
H
H
H
Si(CH3)2
LA4759
H
H
RB1
Si(CH3)2


LA4650
RB1
RB1
H
Si(CH3)2
LA4760
RB1
RB1
RB1
Si(CH3)2


LA4651
RB3
RB3
H
Si(CH3)2
LA4761
RB3
RB3
RB1
Si(CH3)2


LA4652
RB4
RB4
H
Si(CH3)2
LA4762
RB4
RB4
RB1
Si(CH3)2


LA4653
RB7
RB7
H
Si(CH3)2
LA4763
RB7
RB7
RB1
Si(CH3)2


LA4654
RB10
RB10
H
Si(CH3)2
LA4764
RB10
RB10
RB1
Si(CH3)2


LA4655
RA3
RA3
H
Si(CH3)2
LA4765
RA3
RA3
RB1
Si(CH3)2


LA4656
RA34
RA34
H
Si(CH3)2
LA4766
RA34
RA34
RB1
Si(CH3)2


LA4657
RB1
H
H
Si(CH3)2
LA4767
RB1
H
RB1
Si(CH3)2


LA4658
RB3
H
H
Si(CH3)2
LA4768
RB3
H
RB1
Si(CH3)2


LA4659
RB4
H
H
Si(CH3)2
LA4769
RB4
H
RB1
Si(CH3)2


LA4660
RB7
H
H
Si(CH3)2
LA4770
RB7
H
RB1
Si(CH3)2


LA4661
RB10
H
H
Si(CH3)2
LA4771
RB10
H
RB1
Si(CH3)2


LA4662
RA3
H
H
Si(CH3)2
LA4772
RA3
H
RB1
Si(CH3)2


LA4663
RA34
H
H
Si(CH3)2
LA4773
RA34
H
RB1
Si(CH3)2


LA4664
H
RB1
H
Si(CH3)2
LA4774
H
RB1
RB1
Si(CH3)2


LA4665
H
RB3
H
Si(CH3)2
LA4775
H
RB3
RB1
Si(CH3)2


LA4666
H
RB4
H
Si(CH3)2
LA4776
H
RB4
RB1
Si(CH3)2


LA4667
H
RB7
H
Si(CH3)2
LA4777
H
RB7
RB1
Si(CH3)2


LA4668
H
RB10
H
Si(CH3)2
LA4778
H
RB10
RB1
Si(CH3)2


LA4669
H
RA3
H
Si(CH3)2
LA4779
H
RA3
RB1
Si(CH3)2


LA4670
H
RA34
H
Si(CH3)2
LA4780
H
RA34
RB1
Si(CH3)2








wherein RB1 to RB23 have the following structures:








and
wherein RA1 to RA51 have the following structures:

10. The compound of claim 9, wherein the compound has a formula of M(LA)x(LB)y(LC)z wherein LB and LC are each a bidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M.

11. The compound of claim 10, wherein the compound has a formula selected from the group consisting of Ir(LA)3, Ir(LA)(LB)2, Ir(LA)2(LB), Ir(LA)2(LC), and Ir(LA)(LB)(LC); and wherein LA, LB, and LC are different from each other.

12. The compound of claim 10, wherein LB and LC are each independently selected from the group consisting of:












wherein each Y1 to Y13 is independently selected from the group consisting of carbon and nitrogen;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO2, CR1R2, SiR1R2, and GeR1R2;
wherein R1 and R2 are optionally fused or joined to form a ring;
wherein each Ra, Rb, Rc, and Rd may represent from mono substitution to the possible maximum number of substitution, or no substitution;
wherein R′, R1, R2, Ra, Rb, Rc, and Rd are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein any two adjacent substituents of Ra, Rb, Rc, and Rd are optionally fused or joined to form a ring or form a multidentate ligand.

13. The compound of claim 11, wherein the compound is selected from the group consisting of Compound Ax having the formula Ir(LAi)3, Compound By having the formula Ir(LAi)(LBk)2; and Compound Cz having the formula Ir(LAi)2(LCj); wherein x=i, y=468i+k−468, and z=1260i+j−1260; wherein i is an integer from 121 to 456, 577 to 2736, 2857 to 4104, or 4225 to 4780; wherein k is an integer from 1 to 468; wherein j is an integer from 1 to 1260;
wherein LBk has the following structures:
































































































































































































































































































































and
wherein LCj is selected from the group consisting of the following structures:
LC1 through LC1260 are based on a structure of Formula X,





in which R1, R2, and R3 are defined as:





















Ligand
R1
R2
R3
Ligand
R1
R2
R3
Ligand
R1
R2
R3







LC1
RD1
RD1
H
LC421
RD26
RD21
H
LC841
RD7
RD14
RD1


LC2
RD2
RD2
H
LC422
RD26
RD23
H
LC842
RD7
RD15
RD1


LC3
RD3
RD3
H
LC423
RD26
RD24
H
LC843
RD7
RD16
RD1


LC4
RD4
RD4
H
LC424
RD26
RD25
H
LC844
RD7
RD17
RD1


LC5
RD5
RD5
H
LC425
RD26
RD27
H
LC845
RD7
RD18
RD1


LC6
RD6
RD6
H
LC426
RD26
RD28
H
LC846
RD7
RD19
RD1


LC7
RD7
RD7
H
LC427
RD26
RD29
H
LC847
RD7
RD20
RD1


LC8
RD8
RD8
H
LC428
RD26
RD30
H
LC848
RD7
RD21
RD1


LC9
RD9
RD9
H
LC429
RD26
RD31
H
LC849
RD7
RD22
RD1


LC10
RD10
RD10
H
LC430
RD26
RD32
H
LC850
RD7
RD23
RD1


LC11
RD11
RD11
H
LC431
RD26
RD33
H
LC851
RD7
RD24
RD1


LC12
RD12
RD12
H
LC432
RD26
RD34
H
LC852
RD7
RD25
RD1


LC13
RD13
RD13
H
LC433
RD26
RD35
H
LC853
RD7
RD26
RD1


LC14
RD14
RD14
H
LC434
RD26
RD40
H
LC854
RD7
RD27
RD1


LC15
RD15
RD15
H
LC435
RD26
RD41
H
LC855
RD7
RD28
RD1


LC16
RD16
RD16
H
LC436
RD26
RD42
H
LC856
RD7
RD29
RD1


LC17
RD17
RD17
H
LC437
RD26
RD64
H
LC857
RD7
RD30
RD1


LC18
RD18
RD18
H
LC438
RD26
RD66
H
LC858
RD7
RD31
RD1


LC19
RD19
RD19
H
LC439
RD26
RD68
H
LC859
RD7
RD32
RD1


LC20
RD20
RD20
H
LC440
RD26
RD76
H
LC860
RD7
RD33
RD1


LC21
RD21
RD21
H
LC441
RD35
RD5
H
LC861
RD7
RD34
RD1


LC22
RD22
RD22
H
LC442
RD35
RD6
H
LC862
RD7
RD35
RD1


LC23
RD23
RD23
H
LC443
RD35
RD9
H
LC863
RD7
RD40
RD1


LC24
RD24
RD24
H
LC444
RD35
RD10
H
LC864
RD7
RD41
RD1


LC25
RD25
RD25
H
LC445
RD35
RD12
H
LC865
RD7
RD42
RD1


LC26
RD26
RD26
H
LC446
RD35
RD15
H
LC866
RD7
RD64
RD1


LC27
RD27
RD27
H
LC447
RD35
RD16
H
LC867
RD7
RD66
RD1


LC28
RD28
RD28
H
LC448
RD35
RD17
H
LC868
RD7
RD68
RD1


LC29
RD29
RD29
H
LC449
RD35
RD18
H
LC869
RD7
RD76
RD1


LC30
RD30
RD30
H
LC450
RD35
RD19
H
LC870
RD8
RD5
RD1


LC31
RD31
RD31
H
LC451
RD35
RD20
H
LC871
RD8
RD6
RD1


LC32
RD32
RD32
H
LC452
RD35
RD21
H
LC872
RD8
RD9
RD1


LC33
RD33
RD33
H
LC453
RD35
RD23
H
LC873
RD8
RD10
RD1


LC34
RD34
RD34
H
LC454
RD35
RD24
H
LC874
RD8
RD11
RD1


LC35
RD35
RD35
H
LC455
RD35
RD25
H
LC875
RD8
RD12
RD1


LC36
RD40
RD40
H
LC456
RD35
RD27
H
LC876
RD8
RD13
RD1


LC37
RD41
RD41
H
LC457
RD35
RD28
H
LC877
RD8
RD14
RD1


LC38
RD42
RD42
H
LC458
RD35
RD29
H
LC878
RD8
RD15
RD1


LC39
RD64
RD64
H
LC459
RD35
RD30
H
LC879
RD8
RD16
RD1


LC40
RD66
RD66
H
LC460
RD35
RD31
H
LC880
RD8
RD17
RD1


LC41
RD68
RD68
H
LC461
RD35
RD32
H
LC881
RD8
RD18
RD1


LC42
RD76
RD76
H
LC462
RD35
RD33
H
LC882
RD8
RD19
RD1


LC43
RD1
RD2
H
LC463
RD35
RD34
H
LC883
RD8
RD20
RD1


LC44
RD1
RD3
H
LC464
RD35
RD40
H
LC884
RD8
RD21
RD1


LC45
RD1
RD4
H
LC465
RD35
RD41
H
LC885
RD8
RD22
RD1


LC46
RD1
RD5
H
LC466
RD35
RD42
H
LC886
RD8
RD23
RD1


LC47
RD1
RD6
H
LC467
RD35
RD64
H
LC887
RD8
RD24
RD1


LC48
RD1
RD7
H
LC468
RD35
RD66
H
LC888
RD8
RD25
RD1


LC49
RD1
RD8
H
LC469
RD35
RD68
H
LC889
RD8
RD26
RD1


LC50
RD1
RD9
H
LC470
RD35
RD76
H
LC890
RD8
RD27
RD1


LC51
RD1
RD10
H
LC471
RD40
RD5
H
LC891
RD8
RD28
RD1


LC52
RD1
RD11
H
LC472
RD40
RD6
H
LC892
RD8
RD29
RD1


LC53
RD1
RD12
H
LC473
RD40
RD9
H
LC893
RD8
RD30
RD1


LC54
RD1
RD13
H
LC474
RD40
RD10
H
LC894
RD8
RD31
RD1


LC55
RD1
RD14
H
LC475
RD40
RD12
H
LC895
RD8
RD32
RD1


LC56
RD1
RD15
H
LC476
RD40
RD15
H
LC896
RD8
RD33
RD1


LC57
RD1
RD16
H
LC477
RD40
RD16
H
LC897
RD8
RD34
RD1


LC58
RD1
RD17
H
LC478
RD40
RD17
H
LC898
RD8
RD35
RD1


LC59
RD1
RD18
H
LC479
RD40
RD18
H
LC899
RD8
RD40
RD1


LC60
RD1
RD19
H
LC480
RD40
RD19
H
LC900
RD8
RD41
RD1


LC61
RD1
RD20
H
LC481
RD40
RD20
H
LC901
RD8
RD42
RD1


LC62
RD1
RD21
H
LC482
RD40
RD21
H
LC902
RD8
RD64
RD1


LC63
RD1
RD22
H
LC483
RD40
RD23
H
LC903
RD8
RD66
RD1


LC64
RD1
RD23
H
LC484
RD40
RD24
H
LC904
RD8
RD68
RD1


LC65
RD1
RD24
H
LC485
RD40
RD25
H
LC905
RD8
RD76
RD1


LC66
RD1
RD25
H
LC486
RD40
RD27
H
LC906
RD11
RD5
RD1


LC67
RD1
RD26
H
LC487
RD40
RD28
H
LC907
RD11
RD6
RD1


LC68
RD1
RD27
H
LC488
RD40
RD29
H
LC908
RD11
RD9
RD1


LC69
RD1
RD28
H
LC489
RD40
RD30
H
LC909
RD11
RD10
RD1


LC70
RD1
RD29
H
LC490
RD40
RD31
H
LC910
RD11
RD12
RD1


LC71
RD1
RD30
H
LC491
RD40
RD32
H
LC911
RD11
RD13
RD1


LC72
RD1
RD31
H
LC492
RD40
RD33
H
LC912
RD11
RD14
RD1


LC73
RD1
RD32
H
LC493
RD40
RD34
H
LC913
RD11
RD15
RD1


LC74
RD1
RD33
H
LC494
RD40
RD41
H
LC914
RD11
RD16
RD1


LC75
RD1
RD34
H
LC495
RD40
RD42
H
LC915
RD11
RD17
RD1


LC76
RD1
RD35
H
LC496
RD40
RD64
H
LC916
RD11
RD18
RD1


LC77
RD1
RD40
H
LC497
RD40
RD66
H
LC917
RD11
RD19
RD1


LC78
RD1
RD41
H
LC498
RD40
RD68
H
LC918
RD11
RD20
RD1


LC79
RD1
RD42
H
LC499
RD40
RD76
H
LC919
RD11
RD21
RD1


LC80
RD1
RD64
H
LC500
RD41
RD5
H
LC920
RD11
RD22
RD1


LC81
RD1
RD66
H
LC501
RD41
RD6
H
LC921
RD11
RD23
RD1


LC82
RD1
RD68
H
LC502
RD41
RD9
H
LC922
RD11
RD24
RD1


LC83
RD1
RD76
H
LC503
RD41
RD10
H
LC923
RD11
RD25
RD1


LC84
RD2
RD1
H
LC504
RD41
RD12
H
LC924
RD11
RD26
RD1


LC85
RD2
RD3
H
LC505
RD41
RD15
H
LC925
RD11
RD27
RD1


LC86
RD2
RD4
H
LC506
RD41
RD16
H
LC926
RD11
RD28
RD1


LC87
RD2
RD5
H
LC507
RD41
RD17
H
LC927
RD11
RD29
RD1


LC88
RD2
RD6
H
LC508
RD41
RD18
H
LC928
RD11
RD30
RD1


LC89
RD2
RD7
H
LC509
RD41
RD19
H
LC929
RD11
RD31
RD1


LC90
RD2
RD8
H
LC510
RD41
RD20
H
LC930
RD11
RD32
RD1


LC91
RD2
RD9
H
LC511
RD41
RD21
H
LC931
RD11
RD33
RD1


LC92
RD2
RD10
H
LC512
RD41
RD23
H
LC932
RD11
RD34
RD1


LC93
RD2
RD11
H
LC513
RD41
RD24
H
LC933
RD11
RD35
RD1


LC94
RD2
RD12
H
LC514
RD41
RD25
H
LC934
RD11
RD40
RD1


LC95
RD2
RD13
H
LC515
RD41
RD27
H
LC935
RD11
RD41
RD1


LC96
RD2
RD14
H
LC516
RD41
RD28
H
LC936
RD11
RD42
RD1


LC97
RD2
RD15
H
LC517
RD41
RD29
H
LC937
RD11
RD64
RD1


LC98
RD2
RD16
H
LC518
RD41
RD30
H
LC938
RD11
RD66
RD1


LC99
RD2
RD17
H
LC519
RD41
RD31
H
LC939
RD11
RD68
RD1


LC100
RD2
RD18
H
LC520
RD41
RD32
H
LC940
RD11
RD76
RD1


LC101
RD2
RD19
H
LC521
RD41
RD33
H
LC941
RD13
RD5
RD1


LC102
RD2
RD20
H
LC522
RD41
RD34
H
LC942
RD13
RD6
RD1


LC103
RD2
RD21
H
LC523
RD41
RD42
H
LC943
RD13
RD9
RD1


LC104
RD2
RD22
H
LC524
RD41
RD64
H
LC944
RD13
RD10
RD1


LC105
RD2
RD23
H
LC525
RD41
RD66
H
LC945
RD13
RD12
RD1


LC106
RD2
RD24
H
LC526
RD41
RD68
H
LC946
RD13
RD14
RD1


LC107
RD2
RD25
H
LC527
RD41
RD76
H
LC947
RD13
RD15
RD1


LC108
RD2
RD26
H
LC528
RD64
RD5
H
LC948
RD13
RD16
RD1


LC109
RD2
RD27
H
LC529
RD64
RD6
H
LC949
RD13
RD17
RD1


LC110
RD2
RD28
H
LC530
RD64
RD9
H
LC950
RD13
RD18
RD1


LC111
RD2
RD29
H
LC531
RD64
RD10
H
LC951
RD13
RD19
RD1


LC112
RD2
RD30
H
LC532
RD64
RD12
H
LC952
RD13
RD20
RD1


LC113
RD2
RD31
H
LC533
RD64
RD15
H
LC953
RD13
RD21
RD1


LC114
RD2
RD32
H
LC534
RD64
RD16
H
LC954
RD13
RD22
RD1


LC115
RD2
RD33
H
LC535
RD64
RD17
H
LC955
RD13
RD23
RD1


LC116
RD2
RD34
H
LC536
RD64
RD18
H
LC956
RD13
RD24
RD1


LC117
RD2
RD35
H
LC537
RD64
RD19
H
LC957
RD13
RD25
RD1


LC118
RD2
RD40
H
LC538
RD64
RD20
H
LC958
RD13
RD26
RD1


LC119
RD2
RD41
H
LC539
RD64
RD21
H
LC959
RD13
RD27
RD1


LC120
RD2
RD42
H
LC540
RD64
RD23
H
LC960
RD13
RD28
RD1


LC121
RD2
RD64
H
LC541
RD64
RD24
H
LC961
RD13
RD29
RD1


LC122
RD2
RD66
H
LC542
RD64
RD25
H
LC962
RD13
RD30
RD1


LC123
RD2
RD68
H
LC543
RD64
RD27
H
LC963
RD13
RD31
RD1


LC124
RD2
RD76
H
LC544
RD64
RD28
H
LC964
RD13
RD32
RD1


LC125
RD3
RD4
H
LC545
RD64
RD29
H
LC965
RD13
RD33
RD1


LC126
RD3
RD5
H
LC546
RD64
RD30
H
LC966
RD13
RD34
RD1


LC127
RD3
RD6
H
LC547
RD64
RD31
H
LC967
RD13
RD35
RD1


LC128
RD3
RD7
H
LC548
RD64
RD32
H
LC968
RD13
RD40
RD1


LC129
RD3
RD8
H
LC549
RD64
RD33
H
LC969
RD13
RD41
RD1


LC130
RD3
RD9
H
LC550
RD64
RD34
H
LC970
RD13
RD42
RD1


LC131
RD3
RD10
H
LC551
RD64
RD42
H
LC971
RD13
RD64
RD1


LC132
RD3
RD11
H
LC552
RD64
RD64
H
LC972
RD13
RD66
RD1


LC133
RD3
RD12
H
LC553
RD64
RD66
H
LC973
RD13
RD68
RD1


LC134
RD3
RD13
H
LC554
RD64
RD68
H
LC974
RD13
RD76
RD1


LC135
RD3
RD14
H
LC555
RD64
RD76
H
LC975
RD14
RD5
RD1


LC136
RD3
RD15
H
LC556
RD66
RD5
H
LC976
RD14
RD6
RD1


LC137
RD3
RD16
H
LC557
RD66
RD6
H
LC977
RD14
RD9
RD1


LC138
RD3
RD17
H
LC558
RD66
RD9
H
LC978
RD14
RD10
RD1


LC139
RD3
RD18
H
LC559
RD66
RD10
H
LC979
RD14
RD12
RD1


LC140
RD3
RD19
H
LC560
RD66
RD12
H
LC980
RD14
RD15
RD1


LC141
RD3
RD20
H
LC561
RD66
RD15
H
LC981
RD14
RD16
RD1


LC142
RD3
RD21
H
LC562
RD66
RD16
H
LC982
RD14
RD17
RD1


LC143
RD3
RD22
H
LC563
RD66
RD17
H
LC983
RD14
RD18
RD1


LC144
RD3
RD23
H
LC564
RD66
RD18
H
LC984
RD14
RD19
RD1


LC145
RD3
RD24
H
LC565
RD66
RD19
H
LC985
RD14
RD20
RD1


LC146
RD3
RD25
H
LC566
RD66
RD20
H
LC986
RD14
RD21
RD1


LC147
RD3
RD26
H
LC567
RD66
RD21
H
LC987
RD14
RD22
RD1


LC148
RD3
RD27
H
LC568
RD66
RD23
H
LC988
RD14
RD23
RD1


LC149
RD3
RD28
H
LC569
RD66
RD24
H
LC989
RD14
RD24
RD1


LC150
RD3
RD29
H
LC570
RD66
RD25
H
LC990
RD14
RD25
RD1


LC151
RD3
RD30
H
LC571
RD66
RD27
H
LC991
RD14
RD26
RD1


LC152
RD3
RD31
H
LC572
RD66
RD28
H
LC992
RD14
RD27
RD1


LC153
RD3
RD32
H
LC573
RD66
RD29
H
LC993
RD14
RD28
RD1


LC154
RD3
RD33
H
LC574
RD66
RD30
H
LC994
RD14
RD29
RD1


LC155
RD3
RD34
H
LC575
RD66
RD31
H
LC995
RD14
RD30
RD1


LC156
RD3
RD35
H
LC576
RD66
RD32
H
LC996
RD14
RD31
RD1


LC157
RD3
RD40
H
LC577
RD66
RD33
H
LC997
RD14
RD32
RD1


LC158
RD3
RD41
H
LC578
RD66
RD34
H
LC998
RD14
RD33
RD1


LC159
RD3
RD42
H
LC579
RD66
RD42
H
LC999
RD14
RD34
RD1


LC160
RD3
RD64
H
LC580
RD66
RD64
H
LC1000
RD14
RD35
RD1


LC161
RD3
RD66
H
LC581
RD66
RD66
H
LC1001
RD14
RD40
RD1


LC162
RD3
RD68
H
LC582
RD68
RD5
H
LC1002
RD14
RD41
RD1


LC163
RD3
RD76
H
LC583
RD68
RD6
H
LC1003
RD14
RD42
RD1


LC164
RD4
RD5
H
LC584
RD68
RD9
H
LC1004
RD14
RD64
RD1


LC165
RD4
RD6
H
LC585
RD68
RD10
H
LC1005
RD14
RD66
RD1


LC166
RD4
RD7
H
LC586
RD68
RD12
H
LC1006
RD14
RD68
RD1


LC167
RD4
RD8
H
LC587
RD68
RD15
H
LC1007
RD14
RD76
RD1


LC168
RD4
RD9
H
LC588
RD68
RD16
H
LC1008
RD22
RD5
RD1


LC169
RD4
RD10
H
LC589
RD68
RD17
H
LC1009
RD22
RD6
RD1


LC170
RD4
RD11
H
LC590
RD68
RD18
H
LC1010
RD22
RD9
RD1


LC171
RD4
RD12
H
LC591
RD68
RD19
H
LC1011
RD22
RD10
RD1


LC172
RD4
RD13
H
LC592
RD68
RD20
H
LC1012
RD22
RD12
RD1


LC173
RD4
RD14
H
LC593
RD68
RD21
H
LC1013
RD22
RD15
RD1


LC174
RD4
RD15
H
LC594
RD68
RD23
H
LC1014
RD22
RD16
RD1


LC175
RD4
RD16
H
LC595
RD68
RD24
H
LC1015
RD22
RD17
RD1


LC176
RD4
RD17
H
LC596
RD68
RD25
H
LC1016
RD22
RD18
RD1


LC177
RD4
RD18
H
LC597
RD68
RD27
H
LC1017
RD22
RD19
RD1


LC178
RD4
RD19
H
LC598
RD68
RD28
H
LC1018
RD22
RD20
RD1


LC179
RD4
RD20
H
LC599
RD68
RD29
H
LC1019
RD22
RD21
RD1


LC180
RD4
RD21
H
LC600
RD68
RD30
H
LC1020
RD22
RD23
RD1


LC181
RD4
RD22
H
LC601
RD68
RD31
H
LC1021
RD22
RD24
RD1


LC182
RD4
RD23
H
LC602
RD68
RD32
H
LC1022
RD22
RD25
RD1


LC183
RD4
RD24
H
LC603
RD68
RD33
H
LC1023
RD22
RD26
RD1


LC184
RD4
RD25
H
LC604
RD68
RD34
H
LC1024
RD22
RD27
RD1


LC185
RD4
RD26
H
LC605
RD68
RD42
H
LC1025
RD22
RD28
RD1


LC186
RD4
RD27
H
LC606
RD68
RD76
H
LC1026
RD22
RD29
RD1


LC187
RD4
RD28
H
LC607
RD68
RD5
H
LC1027
RD22
RD30
RD1


LC188
RD4
RD29
H
LC608
RD76
RD6
H
LC1028
RD22
RD31
RD1


LC189
RD4
RD30
H
LC609
RD76
RD9
H
LC1029
RD22
RD32
RD1


LC190
RD4
RD31
H
LC610
RD76
RD10
H
LC1030
RD22
RD33
RD1


LC191
RD4
RD32
H
LC611
RD76
RD12
H
LC1031
RD22
RD34
RD1


LC192
RD4
RD33
H
LC612
RD76
RD15
H
LC1032
RD22
RD35
RD1


LC193
RD4
RD34
H
LC613
RD76
RD16
H
LC1033
RD22
RD40
RD1


LC194
RD4
RD35
H
LC614
RD76
RD17
H
LC1034
RD22
RD41
RD1


LC195
RD4
RD40
H
LC615
RD76
RD18
H
LC1035
RD22
RD42
RD1


LC196
RD4
RD41
H
LC616
RD76
RD19
H
LC1036
RD22
RD64
RD1


LC197
RD4
RD42
H
LC617
RD76
RD20
H
LC1037
RD22
RD66
RD1


LC198
RD4
RD64
H
LC618
RD76
RD21
H
LC1038
RD22
RD68
RD1


LC199
RD4
RD66
H
LC619
RD76
RD23
H
LC1039
RD22
RD76
RD1


LC200
RD4
RD68
H
LC620
RD76
RD24
H
LC1040
RD26
RD5
RD1


LC201
RD4
RD76
H
LC621
RD76
RD25
H
LC1041
RD26
RD6
RD1


LC202
RD4
RD1
H
LC622
RD76
RD27
H
LC1042
RD26
RD9
RD1


LC203
RD7
RD5
H
LC623
RD76
RD28
H
LC1043
RD26
RD10
RD1


LC204
RD7
RD6
H
LC624
RD76
RD29
H
LC1044
RD26
RD12
RD1


LC205
RD7
RD8
H
LC625
RD76
RD30
H
LC1045
RD26
RD15
RD1


LC206
RD7
RD9
H
LC626
RD76
RD31
H
LC1046
RD26
RD16
RD1


LC207
RD7
RD10
H
LC627
RD76
RD32
H
LC1047
RD26
RD17
RD1


LC208
RD7
RD11
H
LC628
RD76
RD33
H
LC1048
RD26
RD18
RD1


LC209
RD7
RD12
H
LC629
RD76
RD34
H
LC1049
RD26
RD19
RD1


LC210
RD7
RD13
H
LC630
RD76
RD42
H
LC1050
RD26
RD20
RD1


LC211
RD7
RD14
H
LC631
RD1
RD1
RD1
LC1051
RD26
RD21
RD1


LC212
RD7
RD15
H
LC632
RD2
RD2
RD1
LC1052
RD26
RD23
RD1


LC213
RD7
RD16
H
LC633
RD3
RD3
RD1
LC1053
RD26
RD24
RD1


LC214
RD7
RD17
H
LC634
RD4
RD4
RD1
LC1054
RD26
RD25
RD1


LC215
RD7
RD18
H
LC635
RD5
RD5
RD1
LC1055
RD26
RD27
RD1


LC216
RD7
RD19
H
LC636
RD6
RD6
RD1
LC1056
RD26
RD28
RD1


LC217
RD7
RD20
H
LC637
RD7
RD7
RD1
LC1057
RD26
RD29
RD1


LC218
RD7
RD21
H
LC638
RD8
RD8
RD1
LC1058
RD26
RD30
RD1


LC219
RD7
RD22
H
LC639
RD9
RD9
RD1
LC1059
RD26
RD31
RD1


LC220
RD7
RD23
H
LC640
RD10
RD10
RD1
LC1060
RD26
RD32
RD1


LC221
RD7
RD24
H
LC641
RD11
RD11
RD1
LC1061
RD26
RD33
RD1


LC222
RD7
RD25
H
LC642
RD12
RD12
RD1
LC1062
RD26
RD34
RD1


LC223
RD7
RD26
H
LC643
RD13
RD13
RD1
LC1063
RD26
RD35
RD1


LC224
RD7
RD27
H
LC644
RD14
RD14
RD1
LC1064
RD26
RD40
RD1


LC225
RD7
RD28
H
LC645
RD15
RD15
RD1
LC1065
RD26
RD41
RD1


LC226
RD7
RD29
H
LC646
RD16
RD16
RD1
LC1066
RD26
RD42
RD1


LC227
RD7
RD30
H
LC647
RD17
RD17
RD1
LC1067
RD26
RD64
RD1


LC228
RD7
RD31
H
LC648
RD18
RD18
RD1
LC1068
RD26
RD66
RD1


LC229
RD7
RD32
H
LC649
RD19
RD19
RD1
LC1069
RD26
RD68
RD1


LC230
RD7
RD33
H
LC650
RD20
RD20
RD1
LC1070
RD26
RD76
RD1


LC231
RD7
RD34
H
LC651
RD21
RD21
RD1
LC1071
RD35
RD5
RD1


LC232
RD7
RD35
H
LC652
RD22
RD22
RD1
LC1072
RD35
RD6
RD1


LC233
RD7
RD40
H
LC653
RD23
RD23
RD1
LC1073
RD35
RD9
RD1


LC234
RD7
RD41
H
LC654
RD24
RD24
RD1
LC1074
RD35
RD10
RD1


LC235
RD7
RD42
H
LC655
RD25
RD25
RD1
LC1075
RD35
RD12
RD1


LC236
RD7
RD64
H
LC656
RD26
RD26
RD1
LC1076
RD35
RD15
RD1


LC237
RD7
RD66
H
LC657
RD27
RD27
RD1
LC1077
RD35
RD16
RD1


LC238
RD7
RD68
H
LC658
RD28
RD28
RD1
LC1078
RD35
RD17
RD1


LC239
RD7
RD76
H
LC659
RD29
RD29
RD1
LC1079
RD35
RD18
RD1


LC240
RD8
RD5
H
LC660
RD30
RD30
RD1
LC1080
RD35
RD19
RD1


LC241
RD8
RD6
H
LC661
RD31
RD31
RD1
LC1081
RD35
RD20
RD1


LC242
RD8
RD9
H
LC662
RD32
RD32
RD1
LC1082
RD35
RD21
RD1


LC243
RD8
RD10
H
LC663
RD33
RD33
RD1
LC1083
RD35
RD23
RD1


LC244
RD8
RD11
H
LC664
RD34
RD34
RD1
LC1084
RD35
RD24
RD1


LC245
RD8
RD12
H
LC665
RD35
RD35
RD1
LC1085
RD35
RD25
RD1


LC246
RD8
RD13
H
LC666
RD40
RD40
RD1
LC1086
RD35
RD27
RD1


LC247
RD8
RD14
H
LC667
RD41
RD41
RD1
LC1087
RD35
RD28
RD1


LC248
RD8
RD15
H
LC668
RD42
RD42
RD1
LC1088
RD35
RD29
RD1


LC249
RD8
RD16
H
LC669
RD64
RD64
RD1
LC1089
RD35
RD30
RD1


LC250
RD8
RD17
H
LC670
RD66
RD66
RD1
LC1090
RD35
RD31
RD1


LC251
RD8
RD18
H
LC671
RD68
RD68
RD1
LC1091
RD35
RD32
RD1


LC252
RD8
RD19
H
LC672
RD76
RD76
RD1
LC1092
RD35
RD33
RD1


LC253
RD8
RD20
H
LC673
RD1
RD2
RD1
LC1093
RD35
RD34
RD1


LC254
RD8
RD21
H
LC674
RD1
RD3
RD1
LC1094
RD35
RD40
RD1


LC255
RD8
RD22
H
LC675
RD1
RD4
RD1
LC1095
RD35
RD41
RD1


LC256
RD8
RD23
H
LC676
RD1
RD5
RD1
LC1096
RD35
RD42
RD1


LC257
RD8
RD24
H
LC677
RD1
RD6
RD1
LC1097
RD35
RD64
RD1


LC258
RD8
RD25
H
LC678
RD1
RD7
RD1
LC1098
RD35
RD66
RD1


LC259
RD8
RD26
H
LC679
RD1
RD8
RD1
LC1099
RD35
RD68
RD1


LC260
RD8
RD27
H
LC680
RD1
RD9
RD1
LC1100
RD35
RD76
RD1


LC261
RD8
RD28
H
LC681
RD1
RD10
RD1
LC1101
RD40
RD5
RD1


LC262
RD8
RD29
H
LC682
RD1
RD11
RD1
LC1102
RD40
RD6
RD1


LC263
RD8
RD30
H
LC683
RD1
RD12
RD1
LC1103
RD40
RD9
RD1


LC264
RD8
RD31
H
LC684
RD1
RD13
RD1
LC1104
RD40
RD10
RD1


LC265
RD8
RD32
H
LC685
RD1
RD14
RD1
LC1105
RD40
RD12
RD1


LC266
RD8
RD33
H
LC686
RD1
RD15
RD1
LC1106
RD40
RD15
RD1


LC267
RD8
RD34
H
LC687
RD1
RD16
RD1
LC1107
RD40
RD16
RD1


LC268
RD8
RD35
H
LC688
RD1
RD17
RD1
LC1108
RD40
RD17
RD1


LC269
RD8
RD40
H
LC689
RD1
RD18
RD1
LC1109
RD40
RD18
RD1


LC270
RD8
RD41
H
LC690
RD1
RD19
RD1
LC1110
RD40
RD19
RD1


LC271
RD8
RD42
H
LC691
RD1
RD20
RD1
LC1111
RD40
RD20
RD1


LC272
RD8
RD64
H
LC692
RD1
RD21
RD1
LC1112
RD40
RD21
RD1


LC273
RD8
RD66
H
LC693
RD1
RD22
RD1
LC1113
RD40
RD23
RD1


LC274
RD8
RD68
H
LC694
RD1
RD23
RD1
LC1114
RD40
RD24
RD1


LC275
RD8
RD76
H
LC695
RD1
RD24
RD1
LC1115
RD40
RD25
RD1


LC276
RD11
RD5
H
LC696
RD1
RD25
RD1
LC1116
RD40
RD27
RD1


LC277
RD11
RD6
H
LC697
RD1
RD26
RD1
LC1117
RD40
RD28
RD1


LC278
RD11
RD9
H
LC698
RD1
RD27
RD1
LC1118
RD40
RD29
RD1


LC279
RD11
RD10
H
LC699
RD1
RD28
RD1
LC1119
RD40
RD30
RD1


LC280
RD11
RD12
H
LC700
RD1
RD29
RD1
LC1120
RD40
RD31
RD1


LC281
RD11
RD13
H
LC701
RD1
RD30
RD1
LC1121
RD40
RD32
RD1


LC282
RD11
RD14
H
LC702
RD1
RD31
RD1
LC1122
RD40
RD33
RD1


LC283
RD11
RD15
H
LC703
RD1
RD32
RD1
LC1123
RD40
RD34
RD1


LC284
RD11
RD16
H
LC704
RD1
RD33
RD1
LC1124
RD40
RD41
RD1


LC285
RD11
RD17
H
LC705
RD1
RD34
RD1
LC1125
RD40
RD42
RD1


LC286
RD11
RD18
H
LC706
RD1
RD35
RD1
LC1126
RD40
RD64
RD1


LC287
RD11
RD19
H
LC707
RD1
RD40
RD1
LC1127
RD40
RD66
RD1


LC288
RD11
RD20
H
LC708
RD1
RD41
RD1
LC1128
RD40
RD68
RD1


LC289
RD11
RD21
H
LC709
RD1
RD42
RD1
LC1129
RD40
RD76
RD1


LC290
RD11
RD22
H
LC710
RD1
RD64
RD1
LC1130
RD41
RD5
RD1


LC291
RD11
RD23
H
LC711
RD1
RD66
RD1
LC1131
RD41
RD6
RD1


LC292
RD11
RD24
H
LC712
RD1
RD68
RD1
LC1132
RD41
RD9
RD1


LC293
RD11
RD25
H
LC713
RD1
RD76
RD1
LC1133
RD41
RD10
RD1


LC294
RD11
RD26
H
LC714
RD2
RD1
RD1
LC1134
RD41
RD12
RD1


LC295
RD11
RD27
H
LC715
RD2
RD3
RD1
LC1135
RD41
RD15
RD1


LC296
RD11
RD28
H
LC716
RD2
RD4
RD1
LC1136
RD41
RD16
RD1


LC297
RD11
RD29
H
LC717
RD2
RD5
RD1
LC1137
RD41
RD17
RD1


LC298
RD11
RD30
H
LC718
RD2
RD6
RD1
LC1138
RD41
RD18
RD1


LC299
RD11
RD31
H
LC719
RD2
RD7
RD1
LC1139
RD41
RD19
RD1


LC300
RD11
RD32
H
LC720
RD2
RD8
RD1
LC1140
RD41
RD20
RD1


LC301
RD11
RD33
H
LC721
RD2
RD9
RD1
LC1141
RD41
RD21
RD1


LC302
RD11
RD34
H
LC722
RD2
RD10
RD1
LC1142
RD41
RD23
RD1


LC303
RD11
RD35
H
LC723
RD2
RD11
RD1
LC1143
RD41
RD24
RD1


LC304
RD11
RD40
H
LC724
RD2
RD12
RD1
LC1144
RD41
RD25
RD1


LC305
RD11
RD41
H
LC725
RD2
RD13
RD1
LC1145
RD41
RD27
RD1


LC306
RD11
RD42
H
LC726
RD2
RD14
RD1
LC1146
RD41
RD28
RD1


LC307
RD11
RD64
H
LC727
RD2
RD15
RD1
LC1147
RD41
RD29
RD1


LC308
RD11
RD66
H
LC728
RD2
RD16
RD1
LC1148
RD41
RD30
RD1


LC309
RD11
RD68
H
LC729
RD2
RD17
RD1
LC1149
RD41
RD31
RD1


LC310
RD11
RD76
H
LC730
RD2
RD18
RD1
LC1150
RD41
RD32
RD1


LC311
RD13
RD5
H
LC731
RD2
RD19
RD1
LC1151
RD41
RD33
RD1


LC312
RD13
RD6
H
LC732
RD2
RD20
RD1
LC1152
RD41
RD34
RD1


LC313
RD13
RD9
H
LC733
RD2
RD21
RD1
LC1153
RD41
RD42
RD1


LC314
RD13
RD10
H
LC734
RD2
RD22
RD1
LC1154
RD41
RD64
RD1


LC315
RD13
RD12
H
LC735
RD2
RD23
RD1
LC1155
RD41
RD66
RD1


LC316
RD13
RD14
H
LC736
RD2
RD24
RD1
LC1156
RD41
RD68
RD1


LC317
RD13
RD15
H
LC737
RD2
RD25
RD1
LC1157
RD41
RD76
RD1


LC318
RD13
RD16
H
LC738
RD2
RD26
RD1
LC1158
RD64
RD5
RD1


LC319
RD13
RD17
H
LC739
RD2
RD27
RD1
LC1159
RD64
RD6
RD1


LC320
RD13
RD18
H
LC740
RD2
RD28
RD1
LC1160
RD64
RD9
RD1


LC321
RD13
RD19
H
LC741
RD2
RD29
RD1
LC1161
RD64
RD10
RD1


LC322
RD13
RD20
H
LC742
RD2
RD30
RD1
LC1162
RD64
RD12
RD1


LC323
RD13
RD21
H
LC743
RD2
RD31
RD1
LC1163
RD64
RD15
RD1


LC324
RD13
RD22
H
LC744
RD2
RD32
RD1
LC1164
RD64
RD16
RD1


LC325
RD13
RD23
H
LC745
RD2
RD33
RD1
LC1165
RD64
RD17
RD1


LC326
RD13
RD24
H
LC746
RD2
RD34
RD1
LC1166
RD64
RD18
RD1


LC327
RD13
RD25
H
LC747
RD2
RD35
RD1
LC1167
RD64
RD19
RD1


LC328
RD13
RD26
H
LC748
RD2
RD40
RD1
LC1168
RD64
RD20
RD1


LC329
RD13
RD27
H
LC749
RD2
RD41
RD1
LC1169
RD64
RD21
RD1


LC330
RD13
RD28
H
LC750
RD2
RD42
RD1
LC1170
RD64
RD23
RD1


LC331
RD13
RD29
H
LC751
RD2
RD64
RD1
LC1171
RD64
RD24
RD1


LC332
RD13
RD30
H
LC752
RD2
RD66
RD1
LC1172
RD64
RD25
RD1


LC333
RD13
RD31
H
LC753
RD2
RD68
RD1
LC1173
RD64
RD27
RD1


LC334
RD13
RD32
H
LC754
RD2
RD76
RD1
LC1174
RD64
RD28
RD1


LC335
RD13
RD33
H
LC755
RD3
RD4
RD1
LC1175
RD64
RD29
RD1


LC336
RD13
RD34
H
LC756
RD3
RD5
RD1
LC1176
RD64
RD30
RD1


LC337
RD13
RD35
H
LC757
RD3
RD6
RD1
LC1177
RD64
RD31
RD1


LC338
RD13
RD40
H
LC758
RD3
RD7
RD1
LC1180
RD64
RD32
RD1


LC339
RD13
RD41
H
LC759
RD3
RD8
RD1
LC1179
RD64
RD33
RD1


LC340
RD13
RD42
H
LC760
RD3
RD9
RD1
LC1180
RD64
RD34
RD1


LC341
RD13
RD64
H
LC761
RD3
RD10
RD1
LC1181
RD64
RD42
RD1


LC342
RD13
RD66
H
LC762
RD3
RD11
RD1
LC1182
RD64
RD64
RD1


LC343
RD13
RD68
H
LC763
RD3
RD12
RD1
LC1183
RD64
RD66
RD1


LC344
RD13
RD76
H
LC764
RD3
RD13
RD1
LC1184
RD64
RD68
RD1


LC345
RD14
RD5
H
LC765
RD3
RD14
RD1
LC1185
RD64
RD76
RD1


LC346
RD14
RD6
H
LC766
RD3
RD15
RD1
LC1186
RD66
RD5
RD1


LC347
RD14
RD9
H
LC767
RD3
RD16
RD1
LC1187
RD66
RD6
RD1


LC348
RD14
RD10
H
LC768
RD3
RD17
RD1
LC1188
RD66
RD9
RD1


LC349
RD14
RD12
H
LC769
RD3
RD18
RD1
LC1189
RD66
RD10
RD1


LC350
RD14
RD15
H
LC770
RD3
RD19
RD1
LC1190
RD66
RD12
RD1


LC351
RD14
RD16
H
LC771
RD3
RD20
RD1
LC1191
RD66
RD15
RD1


LC352
RD14
RD17
H
LC772
RD3
RD21
RD1
LC1192
RD66
RD16
RD1


LC353
RD14
RD18
H
LC773
RD3
RD22
RD1
LC1193
RD66
RD17
RD1


LC354
RD14
RD19
H
LC774
RD3
RD23
RD1
LC1194
RD66
RD18
RD1


LC355
RD14
RD20
H
LC775
RD3
RD24
RD1
LC1195
RD66
RD19
RD1


LC356
RD14
RD21
H
LC776
RD3
RD25
RD1
LC1196
RD66
RD20
RD1


LC357
RD14
RD22
H
LC777
RD3
RD26
RD1
LC1197
RD66
RD21
RD1


LC358
RD14
RD23
H
LC778
RD3
RD27
RD1
LC1198
RD66
RD23
RD1


LC359
RD14
RD24
H
LC779
RD3
RD28
RD1
LC1199
RD66
RD24
RD1


LC360
RD14
RD25
H
LC780
RD3
RD29
RD1
LC1200
RD66
RD25
RD1


LC361
RD14
RD26
H
LC781
RD3
RD30
RD1
LC1201
RD66
RD27
RD1


LC362
RD14
RD27
H
LC782
RD3
RD31
RD1
LC1202
RD66
RD28
RD1


LC363
RD14
RD28
H
LC783
RD3
RD32
RD1
LC1203
RD66
RD29
RD1


LC364
RD14
RD29
H
LC784
RD3
RD33
RD1
LC1204
RD66
RD30
RD1


LC365
RD14
RD30
H
LC785
RD3
RD34
RD1
LC1205
RD66
RD31
RD1


LC366
RD14
RD31
H
LC786
RD3
RD35
RD1
LC1206
RD66
RD32
RD1


LC367
RD14
RD32
H
LC787
RD3
RD40
RD1
LC1207
RD66
RD33
RD1


LC368
RD14
RD33
H
LC788
RD3
RD41
RD1
LC1208
RD66
RD34
RD1


LC369
RD14
RD34
H
LC789
RD3
RD42
RD1
LC1209
RD66
RD42
RD1


LC370
RD14
RD35
H
LC790
RD3
RD64
RD1
LC1210
RD66
RD68
RD1


LC371
RD14
RD40
H
LC791
RD3
RD66
RD1
LC1211
RD66
RD76
RD1


LC372
RD14
RD41
H
LC792
RD3
RD68
RD1
LC1212
RD68
RD5
RD1


LC373
RD14
RD42
H
LC793
RD3
RD76
RD1
LC1213
RD68
RD6
RD1


LC374
RD14
RD64
H
LC794
RD4
RD5
RD1
LC1214
RD68
RD9
RD1


LC375
RD14
RD66
H
LC795
RD4
RD6
RD1
LC1215
RD68
RD10
RD1


LC376
RD14
RD68
H
LC796
RD4
RD7
RD1
LC1216
RD68
RD12
RD1


LC377
RD14
RD76
H
LC797
RD4
RD8
RD1
LC1217
RD68
RD15
RD1


LC378
RD22
RD5
H
LC798
RD4
RD9
RD1
LC1218
RD68
RD16
RD1


LC379
RD22
RD6
H
LC799
RD4
RD10
RD1
LC1219
RD68
RD17
RD1


LC380
RD22
RD9
H
LC800
RD4
RD11
RD1
LC1220
RD68
RD18
RD1


LC381
RD22
RD10
H
LC801
RD4
RD12
RD1
LC1221
RD68
RD19
RD1


LC382
RD22
RD12
H
LC802
RD4
RD13
RD1
LC1222
RD68
RD20
RD1


LC383
RD22
RD15
H
LC803
RD4
RD14
RD1
LC1223
RD68
RD21
RD1


LC384
RD22
RD16
H
LC804
RD4
RD15
RD1
LC1224
RD68
RD23
RD1


LC385
RD22
RD17
H
LC805
RD4
RD16
RD1
LC1225
RD68
RD24
RD1


LC386
RD22
RD18
H
LC806
RD4
RD17
RD1
LC1226
RD68
RD25
RD1


LC387
RD22
RD19
H
LC807
RD4
RD18
RD1
LC1227
RD68
RD27
RD1


LC388
RD22
RD20
H
LC808
RD4
RD19
RD1
LC1228
RD68
RD28
RD1


LC389
RD22
RD21
H
LC809
RD4
RD20
RD1
LC1229
RD68
RD29
RD1


LC390
RD22
RD23
H
LC810
RD4
RD21
RD1
LC1230
RD68
RD30
RD1


LC391
RD22
RD24
H
LC811
RD4
RD22
RD1
LC1231
RD68
RD31
RD1


LC392
RD22
RD25
H
LC812
RD4
RD23
RD1
LC1232
RD68
RD32
RD1


LC393
RD22
RD26
H
LC813
RD4
RD24
RD1
LC1233
RD68
RD33
RD1


LC394
RD22
RD27
H
LC814
RD4
RD25
RD1
LC1234
RD68
RD34
RD1


LC395
RD22
RD28
H
LC815
RD4
RD26
RD1
LC1235
RD68
RD42
RD1


LC396
RD22
RD29
H
LC816
RD4
RD27
RD1
LC1236
RD68
RD76
RD1


LC397
RD22
RD30
H
LC817
RD4
RD28
RD1
LC1237
RD76
RD5
RD1


LC398
RD22
RD31
H
LC818
RD4
RD29
RD1
LC1238
RD76
RD6
RD1


LC399
RD22
RD32
H
LC819
RD4
RD30
RD1
LC1239
RD76
RD9
RD1


LC400
RD22
RD33
H
LC820
RD4
RD31
RD1
LC1240
RD76
RD10
RD1


LC401
RD22
RD34
H
LC821
RD4
RD32
RD1
LC1241
RD76
RD12
RD1


LC402
RD22
RD35
H
LC822
RD4
RD33
RD1
LC1242
RD76
RD15
RD1


LC403
RD22
RD40
H
LC823
RD4
RD34
RD1
LC1243
RD76
RD16
RD1


LC404
RD22
RD41
H
LC824
RD4
RD35
RD1
LC1244
RD76
RD17
RD1


LC405
RD22
RD42
H
LC825
RD4
RD40
RD1
LC1245
RD76
RD18
RD1


LC406
RD22
RD64
H
LC826
RD4
RD41
RD1
LC1246
RD76
RD19
RD1


LC407
RD22
RD66
H
LC827
RD4
RD42
RD1
LC1247
RD76
RD20
RD1


LC408
RD22
RD68
H
LC828
RD4
RD64
RD1
LC1248
RD76
RD21
RD1


LC409
RD22
RD76
H
LC829
RD4
RD66
RD1
LC1249
RD76
RD23
RD1


LC410
RD26
RD5
H
LC830
RD4
RD68
RD1
LC1250
RD76
RD24
RD1


LC411
RD26
RD6
H
LC831
RD4
RD76
RD1
LC1251
RD76
RD25
RD1


LC412
RD26
RD9
H
LC832
RD4
RD1
RD1
LC1252
RD76
RD27
RD1


LC413
RD26
RD10
H
LC833
RD7
RD5
RD1
LC1253
RD76
RD28
RD1


LC414
RD26
RD12
H
LC834
RD7
RD6
RD1
LC1254
RD76
RD29
RD1


LC415
RD26
RD15
H
LC835
RD7
RD8
RD1
LC1255
RD76
RD30
RD1


LC416
RD26
RD16
H
LC836
RD7
RD9
RD1
LC1256
RD76
RD31
RD1


LC417
RD26
RD17
H
LC837
RD7
RD10
RD1
LC1257
RD76
RD32
RD1


LC418
RD26
RD18
H
LC838
RD7
RD11
RD1
LC1258
RD76
RD33
RD1


LC419
RD26
RD19
H
LC839
RD7
RD12
RD1
LC1259
RD76
RD34
RD1


LC420
RD26
RD20
H
LC840
RD7
RD13
RD1
LC1260
RD76
RD42
RD1









and wherein RD1 to RD81 has the following structures:

14. An organic light emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand LA having the Formula selected from the group consisting of:




wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein RA, RB, RC, and RD each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z1 and Z2 are each independently selected from the group consisting of C and N;
wherein X1, X2, X3, X4, X5, and X6 are each C;
wherein when the first ligand LA has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand LA is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X1 in Formula IB;
wherein M does not form a direct bond to X4 in Formula IC;
wherein the metal M can be coordinated to other ligands; and
wherein the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.

15. The OLED of claim 14, wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.

16. The OLED of claim 14, wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of a metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

17. The OLED of claim 16, wherein the host is selected from the group consisting of:
















and combinations thereof.

18. A consumer product comprising an organic light-emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand LA having the Formula selected from the group consisting of:




wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein RA, RB, RC, and RD each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z1 and Z2 are each independently selected from the group consisting of C and N;
wherein X1, X2, X3, X4, X5, and X6 are each C;
wherein when the first ligand LA has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, RA, RB, RC, and RD are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand LA is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X1 in Formula IB;
wherein M does not form a direct bond to X4 in Formula IC;
wherein the metal M can be coordinated to other ligands;
wherein the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand; and
wherein the consumer product is one of a flat panel display, a curved display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a rollable display, a foldable display, a stretchable display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, or a sign.

19. A formulation comprising the compound of claim 1.