# Patent

## Title
Fire ant killer (F.A.K.)/ insecticide

## Abstract

A fire ant killer chemical composition (the “FAK Composition”) for effective killing of fire ants where the FAK Composition utilizes a minimal amount of active ingredients thereby significantly reducing safety concerns with respect to the use of said active ingredients, the FAK composition having a dish detergent composition and an insecticide composition.

## Background
CROSS REFERENCE
The present non-provisional patent application is a continuation-in-part of U.S. patent application Ser. No. 12/471,373 filed May, 23, 2009, which claims benefit to provisional patent application Ser. No. 61/055,639, the disclosures of which are incorporated in its entirety herein by reference.


BACKGROUND OF THE INVENTION
FAK is a chemical composition created for the eradication of fire ants and their mound. FAK destroys on contact as opposed to the granular mixes which require time to activate. FAK is an environmentally friendly insecticide that can be used in multiple scenarios ranging from spot spraying the mounds in any location around a home or business to spraying inside the home or business. When properly prepared, FAK kills the first few fire ants and saturates deep into the colony or mound to kill the eggs and queen in minutes and is immediately safe for activities involving pets or children.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows an MSDS sheet for one possible insecticide composition: Spectracide's Triazicide Insect Killer Once and Done! Concentrate.
FIGS. 2a to 2e shows the Material Safety Data Sheets (MSDS) for one possible dish detergent composition: Ultra Dawn Apple Blossom Dishwashing liquid.



DESCRIPTION OF PREFERRED EMBODIMENTS
The present invention features a composition (the “FAK Composition”) for killing fire ants. In some embodiments, the FAK Composition comprises an insecticide composition and a dish detergent composition. In some embodiments, the FAK Composition is a liquid composition.
In some embodiments, the insecticide contained within the insecticide composition comprises a pyrethroid insecticide, the active agent for the insecticide composition. Two brand names for products available in the public market that can be used as insecticide compositions for the present invention and which are products that contain a pyrethroid are Spectracide's “Triazicide”, and “Hot Shot”. Both products are manufactured by Spectrum Group, a division of United industries Corporation and can be purchased online or at a variety of retails stores such as Loews, Home Depot, or Wal-Mart. Spectracide's “Triazicide Insect Killer Once & Done Concentrate” (“Once and Done”), for example, a possible insecticide composition, is manufactured by Spectrum Group and Spectrum Group is located at P.O. Box 142642, St. Louis, Mo. 63114-0642. Once and Done has a product number of HG-95829 and a formula code of 21-1065.
Spectracide's Triazicide and Hot Shot products contain a pyrethroid insecticide where the concentration of the pyrethroid ranges from 0.002% to 0.08%, depending on the given specific product type. For example, as reflected in FIG. 1, the Triazicide product, Once and Done contains a pyrethroid, Gamma-Cyhalothrin at 0.08%.
The dish detergent composition can comprise a dish detergent available on the open market such as dish detergents by Dawn, Joy, Palmolive and Equate dish detergents. It is believed that the active agent in the dish detergent composition is a chlorinated phenol microbial agent. For example, Dawn Apple Blossom Dishwashing Liquid/Antibacterial Hand Soap, a possible dish detergent composition for the present invention, can be obtained via Dawn's parent company, The Procter & Gamble Company, located at 5299 Spring Grove Avenue in Cincinnati, Ohio, 45217-1087. Dawn's Apple Blossom Dishwashing liquid contains a chlorinated phenol microbial agent, triclosan, at 0.01% (See FIG. 2).
In some embodiments, the dish detergent composition comprises less than 0.1% of a chlorinated phenol microbial agent. One example of a chlorinated phenol microbial agent is triclosan (IUPAC name is 5-chloro-2-(2,4-dichlorophenoxy)phenol)), and is found in soaps and detergent at about 0.001-1.00%. Triclosan is also found in deodorants, toothpastes, shaving creams, mouth washes, and cleaning supplies and is infused in an increasing number of consumer products, such as kitchen utensils, toys, bedding, socks, and trash bags. Triclosan has been shown to be effective in reducing and controlling bacterial contamination on the hands and on treated products. More recently, showering or bathing with 2% triclosan has become a recommended regimen for the decolonization of patients whose skin is carrying methicillin resistant Staphylococcus aureus (MRSA) following the successful control of MRSA outbreaks in several clinical settings. Triclosan is regulated by the U.S. Food and Drug Administration, the Environmental Protection Agency, and the European Union. Detergent products known to have triclosan include Dawn, Joy, Palmolive and Equate dish detergents.
Table 1 shows the ingredients for a variety of publicly available dish detergent products which can comprise the dish detergent composition for the present invention.








TABLE 1





Detergent
Ingredients







Ultra Dawn
Water, sodium lauryl sulfate, sodium laureth sulfate, alkyl


Anti-Bacterial
dimethyl amine oxide, SD alcohol, sodium chloride, PPG-



26, PEI-14 PEG-10/PPG-7 copolymer,



cyclohexanediamine, magnesium chloride,



phenoxyethanol, triclosan, methylisothiazolinone,



fragrance, D & C Red 33, FD & C Yellow 5


Joy Anti-
Water, sodium lauryl sulfate, sodium laureth sulfate, alkyl


Bacterial
dimethyl amine oxide, sodium chloride, PPG-26, PEI-14



PEG-10/PPG-7 copolymer, cyclohexanediamine,



phenoxyethanol, triclosan, methylisothiazolinone,



fragrance, D & C Red 33, FD & C Yellow 5


Palmolive
Water, sodium laureth sulfate, lauramidopropyl betaine,


Ultra
sodium dodecylbenzene sulfonate, SD 3A alcohol, lactic


Antibacterial
Acid, sodium xylene sulfonate, fragrance, tetrasodium



EDTA, dyes









In some embodiments, the dish detergent composition further comprises one or more of the following ingredients: sodium lauryl sulfate, sodium laureth sulfate, C12-14-16 dimethyl amine oxide, SD alcohol, sodium chloride, PPG-26, PEI-14 PEG-10/PPG-7 copolymer, cyclohexanediamine, phenoxyethanol, magnesium chloride, methylisothlazolinone, fragrance, D &C Red 33, FD&C Yellow 5.
In some embodiments, the dish detergent composition comprises one or more of the following ingredients: sodium lauryl sulfate, sodium laureth sulfate, C12-14.16 dimethyl amine oxide, SD alcohol, sodium chloride, PPG-26, PEI-14 PEG-10/PPG-7 copolymer, cyclohexanediamine, phenoxyethanol, magnesium chloride, methylisothlazolinone, fragrance, D &C Red 33, FD&C Yellow 5.
It is believe that the present invention is not anticipated or obvious in light of prior art and that the present invention is extremely advantageous because it uses only a fraction of the insecticides and antimicrobial agents active in the insecticide compositions and dish detergent compositions, respectively. As such, the present invention is much safer for use and is much different from the prior art because of the extremely low levels of active ingredients present in the FAK Composition. The FAK Composition comprises the dish detergent composition comprising a chlorinated phenol; and the insecticide composition comprising a pyrethroid. In the FAK Composition the percentage of the dish detergent composition ranges from 0.0001% to 5% of the FAK Composition and the percentage of the insecticide composition ranges from 0.0001% to 5% of the FAK Composition and wherein the chlorinated phenol is present in an amount ranging from 1.0×10−10% to 0.01% in the FAK Composition and wherein the percentage of the pyrethroid is present in an amount ranging from 1.0×10−20% to 0.08% in the FAK Composition.
Furthermore, for use, the FAK Composition above may be diluted. For example, the FAK Composition may be diluted at about 1-3 ounces, e.g., 2 ounces, to about 0.75 to 1.25, e.g., about 1 gallon or 128 fl ounces, of a solution (meaning that the percentage of the combination of the dish detergent composition and the insecticide compositions, the active ingredients of the FAK Composition, can be reduced to just 0.015 of the overall diluted FAK Composition. In some embodiments, the solution comprises water. In some embodiments, the FAK Composition is diluted with water at a ratio of 2 ounces of FAK Composition to 1 gallon of water.
The following protocols are non-limiting examples for preparation and use of the FAK Composition.
EXAMPLES
Using a 2:1 Mixture of Dish Detergent Composition to Insecticide Composition
INITIAL MIXTURE (Concentrated form): In some embodiments, a FAK composition can be formulated as follows. First combine two gallons (256 fl. ounces) of dish detergent composition with one gallon (128 fl. ounces) of insecticide composition to form an initial mixture.
Next, isolate 2 fluid ounces of the initial mixture.
DILUTION: Dilute the 2 fluid ounces of the Initial Mixture by combining the 2 fluid ounces of the initial mixture with 128 fl. ounces of an inactive solution to arrive at the final FAK Composition. This example final FAK Composition results in a composition wherein the active ingredients, the Insecticide composition and the dish detergent composition, make up just 1.5% of the final FAK composition.
This example embodiment results in a FAK Composition comprising approximately 1.0% of a dish detergent composition and approximately 0.5% of an insecticide composition.
It is important to illustrate that both the formation of the initial mixture and the dilution steps significantly reduce the concentration of the active agents contained within the FAK Composition. These changes can be displayed mathematically as follows, where it is assumed that no chemical reactions affect said changes and where it is assumed merely for example purposes that the initial concentrations of the active agents in both the insecticide composition and the dish detergent composition, prior to combination of the initial mixture and dilution, are 0.01%.
Percentage Change in Active Agents after Initial Mixture (Concentrated)
→ Determine new percentages of Agents

PDDCF=V1(PDDC)/(V1+V2)

PICF=V2(PIC)/(V1+V2)

    
    
        Where PDDC=Starting Percentage of DDC active agent, PIC=Starting Percentage of IC active agent, V1=Volume of DDC, and V2=Volume of IC
        and
        PDDCF=New percentage of DDC active agent after combining with IC
        and
        PICF=New percentage of IC active agent after combining with DDC
        Solving for P1F and P2F using the preferred embodiment:

PDDCF=(256(0.01))/(256+128)=2.56/384

PDDCF=0.0066%

PICF=(128(0.01))/(256+128)=1.28/384

PICF=0.0033%

    
    


Thus, as the above calculations illustrate, the preferred embodiment results in an initial mixture where the concentration of the active agents in the insecticide composition and dish detergent composition is reduced proportionally corresponding to the ratio of dish detergent composition to insecticide composition combined in the Initial Mixture. The initial mixture is also referred to herein as the concentrate or concentrated form of a FAK Composition. In order to formulate the final FAK Composition, the FAK Composition concentrate can be diluted.
During Dilution, the concentration of the active agents is reduced further, as illustrated below.
Percentage Change in Active Agents (POST Dilution)
Dilution: Combine 2 fluid ounces of the above FAK initial mixture (concentrate) with 128 fl ounces of inactive ingredient solution such as water:

PDDDC=2(0.0066)/(2+128)=0.0132/130

PDDDC=1.015−4%

PDIC=2(0.0033)/(2+128)=0.0066/130

PDIC=5.07−5%

Where PDDDC=Percentage of DDC active agent in a diluted version of the above embodiment and PDIC=percentage of IC active agent in a diluted version of the above embodiment.

As the above calculations demonstrate, the final FAK Composition contains concentrations of active agents that are mere fractions of the initial concentrations found in the insecticide and dish detergent compositions.
The above example is not limiting of the present invention and one skilled in the art would recognize that the above possible embodiment is just one possible iteration for combining an insecticide composition and a dish detergent composition to formulate a FAK Composition. For example, the ratio of dish detergent composition to insecticide composition could be 3:1 or, as another example, the ratio of dish detergent composition to insecticide composition could be 1:2 resulting in a higher concentration of insecticide composition in the FAK composition. The following table illustrates such possible embodiments.









TABLE 2





Diluted FAK -
% of Insecticide
% of Dish Detergent


2 oz. concentrate FAK:
Composition in FAK
Composition in FAK


128 oz. water
Composition
Composition







Composition 1
.513%
1.03%


Composition 2 diluted
.384%
1.15%


Composition 3 diluted
.3%-.2%
1.2%-1.3%


Composition 4 diluted
.1%-05%
1.4%-1.45


Composition 5 diluted
.513-1.0%
1.03%-.05%


Composition 6 diluted
1.0%-1.4%
.05%-.01%









In addition, as recognized earlier, the concentrations of the active ingredients contained within insecticide compositions and dish detergent compositions may vary according to the product used for each composition. The following table illustrates the possible embodiments both for concentrated or pre-dilution FAK Compositions and FAK Compositions post dilution.









TABLE 3





Concentrated FAK -




1 part insecticide: 2 part




dish detergent
Pyrethroid
Chlorinated Phenol







Composition 1
.026%
.0066%


Composition 2
.001%-.0.1%
.00001%-.01%


Composition 3
.0001%-1.0%
.000001%-.1%


Composition 4
.000001%-10%
.0000001%-1.0%


Composition 5
.0000001%-15%
.00000001%-10%


















TABLE 4





Diluted FAK -




2 oz. concentrate FAK:




128 oz. water
Pyrethroid
Chlorinated Phenol







Composition 1 diluted
.0004%
1.015−4%


Composition 2 diluted
.00001%-.001%
.00001%-.001%


Composition 3 diluted
.000001%-.01%
.000001%-.01%


Composition 4 diluted
.0000001%-.1%
.0000001%-.1%









Example for Preparing a Diluted FAK Composition and Suggested Use

Preparation of diluted FAK composition for use: Measure 2 ounces of FAK Composition concentrate per gallon of water. Pour FAK Composition into sprayer already with desired amount of water in sprayer. Agitate mound without spreading ants or dirt. Immediately spray the diluted FAK composition onto the agitated mound to totally saturate the mound and 1-2 feet area around the base of the mound.
The FAK composition may be used in the following ways:
(A) Perimeter spray as other insecticide is used to provide barrier protection and residue kill.
(B) Broadcast spray over large areas such as yards, animal pens, fields, gardens, and trees.
(C) Applied directly on pets as a spray or shampoo for fleas.
(D) Mixed with ornamental grass herbicides for dual application.
(E) FAK can also kill other ants, spiders, roaches, wasps, beetles and fleas. It has also been used to kill the spinning worms on pecan trees without harming other wildlife.
Non-Market Product FAK Composition Embodiment
In addition to the above embodiments, one skilled in the art would recognize that a FAK Composition could be developed by isolating only the specific active agents contained within the insecticide composition and the dish detergent composition and combining the same. As such, a FAK Composition could be developed by combining only an insecticide agent (pyrethroid), and an anti-microbial agent (chlorinated phenol), without including all of the additional ingredients contained within ordinary market products that happen to contain an insecticide agent or anti-microbial agent, such as Dawn for an anti-microbial agent, or Hot Shot for an insecticide agent.
In addition, it would be appreciate by one skilled in the art that a non-market product FAK Composition containing only the insecticide agent and the anti-microbial agent could further comprise additional ingredients to increase the efficacy of such a FAK Composition.
As used herein, the term “about” refers to plus or minus 10% of the referenced number.
The disclosures of the following U.S. Patents are incorporated in their entirety by reference herein: U.S. Pat. No. 20080070787, U.S. Pat. No. 20090208546.
Various modifications of the invention, in addition to those described herein, will be apparent to those skilled in the art from the foregoing description. Such modifications are also intended to fall within the scope of the appended claims. Each reference cited in the present application is incorporated herein by reference in its entirety.
Although there has been shown and described the above possible embodiment of the present invention, it will be readily apparent to those skilled in the art that modifications may be made thereto which do not exceed the scope of the appended claims. Therefore, the scope of the invention is only to be limited by the following claims.
The reference numbers recited in the below claims are solely for ease of examination of this patent application, and are exemplary, and are not intended in any way to limit the scope of the claims to the particular features having the corresponding reference numbers in the drawings.
In addition to ants, the present invention can effectively be applied to other insects such as Chiggers, White Grub, Japanese Beetle, Crickets, Fleas, Ticks (dog and deer), mites, Carpenter Ants, Red Ants, and Household Ants, cockroaches, palmetto bug, aphids (all-fruit/flowering), cutworms, caterpillar, June beetle, cutworm, stink bug, grasshopper, maggots, fly, fruit worm, wasp, hornets, yellow jackets, cicada, fruit tree borer, and all types of spiders. The present invention can be sprayed inside and outside of a house, building or structure.

## Claims

1. A fire ant killer chemical composition (the “FAK Composition”) effective in killing of fire ants where the FAK Composition utilizes a minimal amount of active ingredients thereby significantly reducing safety concerns with respect to the use of said active ingredients, the FAK composition comprising:
a) a dish detergent composition wherein the dish detergent composition comprises a chlorinated phenol; and
b) an insecticide composition wherein the insecticide composition comprises a pyrethroid
wherein the percentage in the dish detergent composition is present in an amount ranging from 0.0001% to 5% of the FAK Composition and wherein the percentage of the insecticide composition is present in an amount ranging from 0.0001% to 5% in the FAK Composition and wherein the chlorinated is present in an amount ranging from 1.0×10−10% to 0.01% in the FAK Composition and wherein the percentage of the pyrethroid is present in an amount ranging from 1.0×10−20% to 0.08% in the FAK Composition.

2. A method of killing fire ant eggs deposited or embedded within an ant hill, the method comprising spraying the composition of claim 1 into the fire ant hill or mound.