# Patent

## Title
Method of fabricating semiconductor substrate and method of fabricating light emitting device

## Abstract

The present invention provides a method of fabricating a semiconductor substrate and a method of fabricating a light emitting device. The method includes forming a first semiconductor layer on a substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, and separating the substrate from the second semiconductor layer by etching at least a second portion of the first semiconductor layer using a chemical solution.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation of U.S. patent application Ser. No. 13/137,124, filed on Jul. 21, 2011, which is a continuation of U.S. patent application Ser. No. 12/805,958, filed on Aug. 26, 2010, and now issued as U.S. Pat. No. 8,026,119, and claims priority from and the benefit of Korean Patent Application No. 10-2009-0079429, filed on Aug. 26, 2009, Korean Patent Application No. 10-2009-0079431, filed on Aug. 26, 2009, Korean Patent Application No. 10-2009-0079434, filed on Aug. 26, 2009, and Korean Patent Application No. 10-2009-0079436, filed on Aug. 26, 2009, which are hereby incorporated by reference for all purposes as if fully set forth herein.


BACKGROUND
1. Field
The present invention relates to a method of fabricating a semiconductor substrate and a method of fabricating a light emitting device. More particularly, the present invention relates to a method of fabricating a semiconductor substrate and a method of fabricating a light emitting device based on separating a growth substrate.
2. Discussion of the Background
Light emitting diodes (LEDs) that have a gallium nitride (GaN) based semiconductor may be used for various applications, such as traffic signals, backlights in liquid crystal panels, and the like. It is known that luminous efficiency of an LED is influenced by the dislocation density of crystals and crystal defects. GaN-based semiconductor crystals may be grown on a heterogeneous substrate, such as sapphire or the like. However, lattice mismatch or a difference of thermal expansion coefficients may occur between a GaN layer and a substrate, which may result in a high dislocation density or an increase in defects.
The GaN-based semiconductor crystals may be grown on a homogeneous substrate, such as a GaN substrate and the like. However, it may be difficult to form a GaN melt and to fabricate a GaN substrate due to a high dissociation rate of nitrogen in GaN, and the like. A GaN bulk crystal grown for a GaN substrate may be separated by mechanical grinding or laser ablation. However, it may be difficult to produce a GaN substrate of a practical size using these methods. Particularly, the laser ablation method may require a considerable amount of time to perform, which may increase the cost of a GaN substrate.
GaN crystal growth is shown and described in “Polycrystalline GaN for light emitter and field electron emitter applications,” by S. Hasegawa, S. Nishida, T. Yamashita, H. Asahi, (Thin Solid Films 487 (2005), pp 260-267) (hereinafter, “Hasegawa, et al.”), which is hereby incorporated by reference in its entirety for all purposes as if fully set forth herein. In Hasegawa, et al., GaN crystals are grown on quartz substrates, high-melting-point metal substrates of Tungsten (W), Molybdenum (Mo), Tantalum (Ta) and Niobium (Nb), and Silicon (Si) substrates using plasma assisted molecular beam epitaxy, respectively.
Since it may be difficult and costly to fabricate the GaN substrate, semiconductor devices such as LEDs or laser diodes are generally manufactured by growing a GaN layer on a heterogeneous substrate such as sapphire and the like. However, as mentioned above, the high dislocation density or the increase in defect density may degrade the luminous efficiency of the LED. In addition, the sapphire substrate has a lower thermal conductivity than the GaN substrate, and may cause deterioration in heat dissipation properties of a device. Thus, use of a sapphire substrate for LEDs or laser diodes may limit operational lifespan thereof.
To solve such problems of the sapphire substrate, a laser lift-off process has been developed in which a secondary substrate is attached to a GaN layer after the GaN layer is grown on a heterogeneous substrate as a growth substrate. The secondary substrate in turn is locally decomposed from an interface between the sapphire substrate and the GaN layer by an excimer laser to remove the sapphire substrate. This process is used to fabricate a vertical-type light emitting device suitable for large size LEDs (i.e., a power chip) and the like.
As described above, however, separation of the growth substrate using the laser may require an extended processing time, thereby causing an increase in manufacturing costs of the light emitting device. Further, since it may be necessary to increase transmittance of the sapphire substrate to laser beams in order to radiate a laser beam through the sapphire substrate, it may be necessary to polish an exposed surface of the sapphire substrate, which may decrease a thickness of the sapphire substrate.
SUMMARY OF THE INVENTION
The present invention provides a method of fabricating a semiconductor substrate and a method of fabricating a light emitting device.
The present invention also provides a method of fabricating a flat and easily separable GaN substrate on a heterogeneous substrate at low cost.
The present invention also provides a light emitting device fabricated using the GaN substrate which may have improved performance or long operational lifespan.
Additional features of the invention will be set forth in the description which follows, and in part will be apparent from the description, or may be learned by practice of the invention.
The present invention discloses a method of fabricating a semiconductor substrate, the method including forming a first semiconductor layer on a substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, and separating the first substrate from the second semiconductor layer by etching at least a second portion of the first semiconductor layer using a chemical solution.
The present invention also discloses a method of fabricating a light emitting device, the method including forming a first semiconductor layer on a first substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, forming a first compound semiconductor layer on the second semiconductor layer, forming an active layer on the first compound semiconductor layer, forming a second compound semiconductor layer on the active layer, attaching a second substrate to the second compound semiconductor layer, and separating the first substrate from the second semiconductor layer by etching at least a second portion of the first semiconductor layer using a chemical solution.
The present invention also discloses a method of fabricating a semiconductor substrate, the method including forming a first semiconductor layer on a substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, and growing the void in the first semiconductor layer by heating the substrate after forming the second semiconductor layer.
The present invention also discloses a method of fabricating a light emitting device, the method including forming a first semiconductor layer on a first substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, forming a first compound semiconductor layer on the second semiconductor layer, forming an active layer on the first compound semiconductor layer, forming a second compound semiconductor layer on the active layer, attaching a second substrate to the second compound semiconductor layer, and growing the void in the first semiconductor layer by heating the first substrate after attaching the second substrate.
The present invention also discloses a method of fabricating a semiconductor substrate, the method including forming a first semiconductor layer on a substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, and evaporating reaction by-products of the metallic material layer and nitrogen to remove the reaction by-products formed during formation of the void.
The present invention also discloses a method of fabricating a light emitting device, the method including forming a first semiconductor layer on a substrate, forming a metallic material layer on the first semiconductor layer, forming a second semiconductor layer on the first semiconductor layer and the metallic material layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer, forming a first compound semiconductor layer on the second semiconductor layer, forming an active layer on the first compound semiconductor layer, forming a second compound semiconductor layer on the active layer, and evaporating reaction by-products of the metallic material layer and nitrogen to remove the reaction by-products during formation of the void.
The present invention also discloses a method of fabricating a light emitting device, the method including forming, in a first chamber, a second semiconductor layer on a substrate including a first semiconductor layer and a metallic material layer on the first semiconductor layer, wherein a void is formed in a first portion of the first semiconductor layer under the metallic material layer during formation of the second semiconductor layer; transferring the substrate having the second semiconductor layer from the first chamber to a second chamber; and forming, in the second chamber, a compound semiconductor layer on the second semiconductor layer.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.



BRIEF DESCRIPTION OF THE DRAWINGS
The patent or application file contains at least one drawing executed in color. Copies of this patent or patent application publication with color drawings will be provided by the Office upon request and payment of the necessary fee.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention, and together with the description serve to explain the principles of the invention.
FIG. 1 is a flow diagram of a method of fabricating a semiconductor substrate in accordance with a first exemplary embodiment of the present invention, in which (A) is a sectional view of a process of forming a first GaN layer, (B) is a sectional view of a process of forming a Ta layer, (C) is a sectional view of a process of forming a second GaN layer and a void, (D) is a sectional view of the semiconductor substrate after forming the second GaN layer, (E) is a sectional view of the semiconductor substrate from which a sapphire substrate is separated, and (F) is a sectional view of a finished GaN substrate.
FIG. 2 is a scanning electron microscope (SEM) cross-section of a semiconductor substrate according to a first example of the first exemplary embodiment.
FIG. 3 is an energy dispersive x-ray spectrometer (EDX) spectrum diagram of the semiconductor substrate according to the first example of the first exemplary embodiment.
FIG. 4(A) is a SEM cross-section of an enlarged area shown in FIG. 2 according to the first example of the first exemplary embodiment, FIG. 4(B), FIG. 4(C) and FIG. 4(D) are a Ga EDX diagram, an Al EDX diagram, and an O EDX diagram of the semiconductor substrate according to the first example of the first exemplary embodiment, respectively.
FIG. 5 is SEM micrographs of the semiconductor substrate according to the first example of the first exemplary embodiment, in which (A) is a SEM micrograph of a cross-section of the semiconductor substrate and (B) is a SEM micrograph of a surface of the semiconductor substrate.
FIG. 6 is EDX diagrams of the semiconductor substrate according to the first example of the first exemplary embodiment, in which (A) is an EDX diagram of Ga and (B) is an EDX diagram of Ta.
FIG. 7 is SEM micrographs of a semiconductor substrate according to a first comparative example, in which (A) is a SEM perspective view of the semiconductor substrate and (B) is a SEM surface of the semiconductor substrate.
FIG. 8 is an EDX spectrum and EDX diagrams of the semiconductor substrate according to the first comparative example, in which (A) is an EDX spectrum of the semiconductor substrate of FIG. 7(B), (B) is an EDX diagram of Ga of FIG. 7(B), and (C) is an EDX diagram of N of FIG. 7(B).
FIG. 9 is a SEM micrograph and an EDX spectrum of the semiconductor substrate according to the first comparative example, in which (A) is a SEM micrograph of a side section of a void and (B) is an EDX spectrum of the void of FIG. 9(A).
FIG. 10 is EDX diagrams of the semiconductor substrate according to the first comparative example, in which (A) is an EDX diagram of Ga of FIG. 9(A), (B) is an EDX diagram of N of FIG. 9(A), and (C) is an EDX diagram of Ta of FIG. 9(A).
FIG. 11 is a sectional view of an LED array according to a second exemplary embodiment of the present invention.
FIG. 12 is a SEM micrograph of a side section of a semiconductor substrate according to a second example of the first exemplary embodiment.
FIG. 13 is a SEM micrograph of a side section of a semiconductor substrate of according to a third example of the first exemplary embodiment.
FIG. 14 is a SEM micrograph of a side section of a semiconductor substrate of according to a fourth example of the first exemplary embodiment.
FIG. 15(A) is a diagram showing an exemplary embodiment of a Ta2O5 film converted from a 5 nm thick Ta layer, and FIG. 15(B) is a diagram showing an exemplary embodiment of a Ta2O5 film formed on a surface of a 100 nm thick Ta layer.
FIG. 16(A) is a SEM micrograph of a surface of a substrate having a 5 nm thick Ta mask, and FIG. 16(B) is a SEM micrograph of a surface of a substrate having a 10 nm thick Ta2O5 mask.
FIG. 17 is a flow diagram of a method of fabricating a light emitting device according to a third exemplary embodiment of the present invention.
FIG. 18 is a flow diagram of a method of fabricating a light emitting device according to a fourth exemplary embodiment of the present invention, in which (A) is a sectional view of a process of forming a first GaN layer and a Ta layer, (B) is a sectional view of a process of forming a second GaN layer and a void, and (C) is a sectional view of a process of forming compound semiconductor layers on the second GaN layer.
FIG. 19 is a schematic view of an apparatus used for forming a second GaN layer and compound semiconductor layers.



DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS
The invention is described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the exemplary embodiments set forth herein. Rather, these exemplary embodiments are provided so that this disclosure is thorough, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the size and relative sizes of layers and regions may be exaggerated for clarity. Like reference numerals in the drawings denote like elements.
It will be understood that when an element such as a layer, film, region or substrate is referred to as being “on” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
FIG. 1 is a flow diagram of a method of manufacturing a semiconductor substrate 100 in accordance with a first exemplary embodiment of the present invention. In FIG. 1, (A) is a sectional view of a process of forming a first GaN layer, (B) is a sectional view of a process of forming a Ta layer, (C) is a sectional view of a process of forming a second GaN layer and a void, (D) is a sectional view of the semiconductor substrate after forming the second GaN layer, (E) is a sectional view of the semiconductor substrate from which a sapphire substrate is separated, and (F) is a sectional view of a finished GaN substrate.
Referring to FIG. 1(A), reference numeral 101 indicates a sapphire (Al2O3) substrate. First, a first GaN layer 102 having a thickness of about 2 μm is formed on the sapphire substrate 101. This thickness of the first GaN layer 102 is provided as an example.
Next, referring to FIG. 1(B), a Ta layer (metallic material layer) 103 having a thickness of about 50 nm is formed in a shape of stripes, which have a width of 5 μm and are separated a distance of 5 μm from each other, on the first GaN layer 102 by electron beam (EB) deposition and lift-off. The shape, thickness, width, and separation distance of the Ta layer 103 are provided as an example.
Referring to FIG. 1(C), a second GaN layer 104 is formed on the first GaN layer 102 and the Ta layer 103 by metal organic chemical vapor deposition (MOCVD). The first GaN layer 102 and the second GaN layer 104 may each include different semiconductor material such as AlGaN, InGaN, or AlInGaN. FIG. 1(C) shows the second GaN layer 104 during formation thereof. In this embodiment, N in the first GaN layer 102 combines with Ta to form TaN, which is changed into a different substance and rises into a vapor phase region in which the concentration of N is relatively high. The TaN becomes unstable at 900° C. or more and is evaporated at 1000° C. or more. As the TaN is evaporated, a hole 103a is deepened to form a void 102a. Here, although N in the first GaN layer 102 becomes TaN, Ga remains in the first GaN layer 102. Since this Ga remaining in the first GaN layer 102 is the same as Ga deposited during the vapor deposition, it is used as the raw material. However, GaN may also be grown on a Ta film. As disclosed in Hasegawa, et al., there is a possibility that the surface of the Ta layer 103 becomes not only Ta, but also Ta2O5 in a reaction with air, as described below.
On the other hand, the thickness of the second GaN layer 104 may be greater than or equal to one half the thickness of the Ta layer 103. In addition, the second GaN layer 104 may have a thickness less than 1000 μm for use as a substrate.
As will be described below in more detail, Ta and N may react with each other to produce reaction by-products in the form of TaxNy during growth of the second GaN layer 104. Such by-products may deteriorate semiconductor substrate quality. Thus, it may be necessary to remove the reaction by-products by adjusting growth conditions. The reaction by-products may be removed by adjusting the growth conditions of the second GaN layer 104, for example, growth temperature, growth pressure, growth speed, flux of TMGa as a Ga source, and the like. Alternatively, the reaction by-products may be removed by evaporation by maintaining the substrate 101 at a temperature at which the reaction by-products are evaporated or by lowering a pressure around the substrate 101, after stopping the growth of the second GaN layer 104. Alternatively, the reaction by-products may be removed by maintaining the substrate 101 at a temperature at which the reaction by-products are evaporated or by lowering a pressure around the substrate 101, after completing the growth of the second GaN layer 104.
Next, referring to FIG. 1(D), once the formation of the second GaN layer 104 is completed, the semiconductor substrate 100 is formed. While the second GaN layer 104 is formed by MOCVD, a portion of the first GaN layer 102 under the Ta layer 103 is removed by etching and a formation region of the void 102a is extended substantially to the sapphire substrate 101, as shown in FIG. 1(D). Further, the surface of the substrate is flattened to progress the growth of the first GaN layer 102 along with the growth of the second GaN layer 104, as shown in FIG. 1. Consequently, it is possible to omit a process of flattening the surface of the substrate during formation of the semiconductor substrate 100 according to the first exemplary embodiment.
Next, referring to FIG. 1(E), the sapphire substrate 101 is separated from the first GaN layer 102. Then, referring to FIG. 1(F), a GaN substrate 100 may be obtained by polishing the first GaN layer 102, from which the sapphire substrate 101 is removed. The GaN substrate 100 may be used as a semiconductor substrate for manufacturing a device by attaching a silicon-based substrate such as Si or SiC to an upper side of the GaN substrate 100 and flattening a lower surface thereof.
Furthermore, although separation of the sapphire substrate 101 may be performed by a conventional laser lift-off or polishing process, the void 102a formed in the first GaN layer 102 may also be used to separate the sapphire substrate 101.
For example, the sapphire substrate 101 may be separated from the second GaN layer 104 by etching at least a portion of the first GaN layer 102 using a chemical solution. If the void 102a is not formed, it may be difficult for the chemical solution to infiltrate into an interface between the sapphire substrate 101 and the first GaN layer 102, making it difficult to separate the sapphire substrate 101 using the chemical solution. However, if the void 102a is formed in the first GaN layer 102, the chemical solution may infiltrate into the interface between the sapphire substrate 101 and the first GaN layer 102 through the void 102a, so that the sapphire substrate 101 can be more easily separated using the chemical solution.
Examples of the chemical solution may include KOH, NaOH, H2PO4, HCL, and H2SO4. The sapphire substrate 101 is separated from the second GaN layer 104 by etching the first GaN layer 102, which has the void 102a formed therein, using such a chemical etchant.
In addition to the chemical solution, light may be used to activate the chemical solution. That is, etching the first GaN layer 102 with the chemical solution may be conventional wet-type etching, photo-enhanced chemical etching or photo electrochemical etching.
Alternatively, separation of the sapphire substrate 101 may be achieved by twisting the sapphire substrate 101. Furthermore, separation of the sapphire substrate 101 may be achieved by heating the substrate 101 to grow the void 102a after completing the formation of the second GaN layer 104. As the void 102a gradually grows, a coupling force between the second GaN layer 104 and the sapphire substrate 101 is gradually weakened. As a result, the sapphire substrate 101 may be naturally separated from the second GaN layer 104. The sapphire substrate 101 may also be separated by applying force to the sapphire substrate 101 after the growth of the void 102.
The sapphire substrate 101 may be heated to 300° C. or more. For example, the sapphire substrate 101 may be heated in the range of 900 ̃1100° C. Heating the sapphire substrate 101 may be performed while attaching a silicon-based substrate such as Si or SiC to the surface of the GaN substrate 100.
As such, when the semiconductor substrate 100 including the GaN layer is formed by MOCVD, the first GaN layer 102 can be easily separated from the sapphire substrate 101 using the void 102a, so that the separated GaN layer can be used as the GaN substrate. Accordingly, the GaN substrate may be manufactured at lower cost than the conventional GaN substrate.
Detailed examples of the manufacturing method of the semiconductor substrate 100 will be described hereinafter. In a first example of the first exemplary embodiment, the process of forming the second GaN layer 104 using an MOCVD apparatus will be described. In this example, crystal growth was performed at a heating temperature of 1045° C. for 5 hours while supplying tri-methyl gallium (TMGa) as a raw gas at a flux of 20 μmol/min. Further, in the first example, a Ta layer 103 having a thickness of 50 nm was formed in a shape of stripes on the first GaN layer 102.
In FIG. 2, the semiconductor substrate 100 with the second GaN layer 104 formed thereon under these conditions is shown. FIG. 2 is a SEM micrograph of a side section of a portion of the semiconductor substrate 100. As shown in FIG. 2, the void 102a is formed in a portion of the first GaN layer 102 under the Ta layer 103. An enlarged region including the void 102a in FIG. 2 was analyzed using an energy dispersion x-ray spectrometer (EDX), and the analysis result is shown in FIG. 3.
In the EDX spectrum of FIG. 3, GaN of the first GaN layer 102, and Al and O of the sapphire substrate 101 are observed, but Ta is substantially not observed. Further, in EDX diagrams of FIG. 4(B), FIG. 4(C), and FIG. 4(D), Ga of the first GaN layer 102, and Al and O of the sapphire substrate 101 are observed, but Ta is not substantially observed.
In the first example, it was observed that holes 103a were formed in the Ta layer 103 during the formation of the second GaN layer 104. Analysis results of the holes 103a formed in the Ta layer 103 are shown in FIG. 5 and FIG. 6, and will be described in detail hereinafter. Here, the analysis results shown in FIG. 5 and FIG. 6 were obtained using the EDX by stopping the process of forming the second GaN layer 104 using the MOCVD apparatus.
FIG. 5 shows SEM micrographs of the semiconductor substrate of the first example, in which (A) is a SEM micrograph of a side section of the semiconductor substrate 100 and (B) is a SEM micrograph of a surface of the semiconductor substrate 100. FIG. 6 shows EDX diagrams of the surface of the semiconductor substrate 100 of FIG. 5(B), in which (A) is an EDX diagram of Ga and (B) is an EDX diagram of Ta.
In the SEM micrograph of the semiconductor substrate 100 of FIG. 5(A), it is observed that a portion of the first GaN layer 102 under the Ta layer 103 is etched and the void 102a is formed therein. In the SEM micrograph of the semiconductor substrate 100 of FIG. 5(B), it is observed that holes 103a were formed on a surface of the Ta layer 103. EDX analysis results for Ga and Ta on the surface of the Ta layer 103 including the holes 103a are shown in FIG. 6(A) and FIG. 6(B). As shown in the EDX diagrams, the Ta layer 103 remains, and Ga and GaN are thinly grown on the remaining Ta layer 103.
As such, for the semiconductor substrate 100 of the first example, the conditions for forming the second GaN layer 104 using the MOCVD apparatus were adjusted to permit the void 102a to be formed in the first GaN layer 102 using the Ta layer by etching. Thus, when the second GaN layer 104 was formed as illustrated in the first exemplary embodiment, it was possible to form the void 102a in the first GaN layer 102 by etching during growth of the first GaN layer 102. That is, when a metallic material layer was partially formed on the first GaN layer 102, it was possible to form the void 102a in the first GaN layer 102.
In addition, the MOCVD conditions for the first example are provided as an example, and thus, may be set to allow the growth of the first GaN layer and the formation of the void 102a to be simultaneously progressed. Here, since the growth rate of the first GaN layer 102 was slower than that of the second GaN layer 104, the MOCVD conditions were adjusted in consideration of the growth rate of the first GaN layer 102 in the first example.
Further, in the first example, the holes 103a were formed in the Ta layer 103 during the process of growing the second GaN layer 104, but, for example, the Ta layer 103 may be formed using a mask which is previously formed with holes. Further, the shape of the Ta layer 103 is not limited to the aforementioned stripe shape, and may be changed depending on a device structure to be formed on the semiconductor substrate 100. An example of a device formed using the semiconductor substrate 100 will be described below.
Further, the semiconductor substrate 100 of the first exemplary embodiment may be reused as a substrate 101 forming a GaN layer having the aforementioned void by separating the GaN substrate and then a surface of the sapphire substrate 101 on which a new GaN substrate is formed may be flattened by reactive ion etching (RIE) or the like. Hence, manufacturing costs of the GaN substrate can be further reduced.
Further, although the sapphire substrate is used as a growth substrate in the first exemplary embodiment, any suitable substrate, for example, a silicon-based substrate, may be used so long as it allows growth of the GaN layer thereon.
In a second example of the first exemplary embodiment, the process of forming the second GaN layer 104 using an MOCVD apparatus will be described. In this example, crystal growth was performed at a heating temperature of 1045° C. for 5 hours while supplying TMGa as a raw gas at a flux of 20 μmol/min. Further, in the second example, a Ta layer 103 having a thickness of 30 nm was formed in a shape of stripes on the first GaN layer 102.
In FIG. 12, the semiconductor substrate 100 with the second GaN layer 104 formed thereon under these conditions is shown. FIG. 12 is a SEM micrograph of a cross-section of a portion of the semiconductor substrate 100. As shown in FIG. 12, a void 102a is formed in a portion of the first GaN layer 102 under the Ta layer 103. Further, in the second example, it was observed that holes 103a were formed in the Ta layer 103 during the formation of the second GaN layer 104.
For the semiconductor substrate 100 of the second example, the conditions for forming the second GaN layer 104 using the MOCVD apparatus were adjusted to permit the void 102a to be formed in the first GaN layer 102 using the Ta layer 103 by etching. Thus, when the second GaN layer 104 is formed as illustrated in the second example, it is possible to form the void 102a in the first GaN layer 102 by etching during growth of the first GaN layer 102. In other words, when a metallic material layer was partially formed on the first GaN layer 102, it was possible to form the void 102a in the first GaN layer 102. The metallic material layer may be used for etching the first GaN layer 102 as discussed above in relation to the first exemplary embodiment.
In the sectional view of FIG. 12, the voids 102a caused by etching are not formed in the first GaN layer 102 under the overall lower surface of each of the Ta layers 103, but under opposite ends of each of the Ta layers 103. FIG. 12 shows that etching is performed in the first GaN layer 102 from the opposite ends of each of the Ta layers 103.
Further, the MOCVD conditions for the second example are provided as an example, and thus, may be set to allow the growth of the first GaN layer and the formation of the void 102a to be simultaneously progressed. Here, since the growth rate of the first GaN layer 102 is slower than that of the second GaN layer 104, the MOCVD conditions were adjusted in consideration of the growth rate of the first GaN layer 102 in the second example.
Further, in the second example, the holes 103a were formed in the Ta layer 103 during the process of growing the second GaN layer 104, but, for example, the Ta layer 103 may be formed using a mask which is previously formed with holes. Further, the shape of the Ta layer 103 is not limited to the aforementioned stripe shape, and may be changed depending on a device structure to be formed on the semiconductor substrate 100. An example of a device formed using the semiconductor substrate 100 will be described below.
Further, the semiconductor substrate 100 of the second example may be reused as a substrate 101 for forming a GaN layer having the aforementioned void. The GaN substrate may be separated and then a surface of the sapphire substrate 101 on which a new GaN substrate is formed may be flattened by RIE or the like. Hence, manufacturing costs of the GaN substrate can be further reduced.
In a third example of the first exemplary embodiment, the process of forming the second GaN layer 104 using an MOCVD apparatus will be described. In this example, crystal growth was performed at a heating temperature of 1045° C. for 5 hours while supplying TMGa as a raw gas at a flux of 20 μmol/min. Further, in the third example, a Ta layer 103 having a thickness of 50 nm was formed in a shape of stripes on the first GaN layer 102.
In FIG. 13, the semiconductor substrate 100 with the second GaN layer 104 formed thereon under these conditions is shown. FIG. 13 is an SEM micrograph of a side section of a portion of the semiconductor substrate 100. As shown in this Fig., a void 102a is formed in a portion of the first GaN layer 102 under the Ta layer 103. Further, in the third example, it was observed that holes 103a were formed in the Ta layer 103 during the formation of the second GaN layer 104.
For the semiconductor substrate 100 of the third example, the conditions for forming the second GaN layer 104 using the MOCVD apparatus were adjusted to permit the void 102a to be formed in the first GaN layer 102 under the Ta layer 103 by etching. Thus, when the second GaN layer 104 was formed as illustrated in the first exemplary embodiment, it was possible to form the void 102a in the first GaN layer 102 by etching during growth of the first GaN layer 102. In other words, when a metallic material layer was partially formed on the first GaN layer 102, it was possible to form the void 102a in the first GaN layer 102. The metallic material layer may be used for etching the first GaN layer 102 as discussed above in relation to the first exemplary embodiment.
In addition, the MOCVD conditions for the third example are provided as an example, and thus, may be set to allow the growth of the first GaN layer 102 and the formation of the void 102a to be simultaneously progressed. Here, since the growth rate of the first GaN layer 102 is slower than that of the second GaN layer 104, the MOCVD conditions were adjusted in consideration of the growth rate of the first GaN layer 102 in the third example.
Further, in the third example, the holes 103a were formed in the Ta layer 103 during the process of growing the second GaN layer 104, but the Ta layer 103 may be formed using a mask which is previously formed with holes. Further, the shape of the Ta layer 103 is not limited to the aforementioned stripe shape, and may be changed depending on a device structure to be formed on the semiconductor substrate 100. An example of a device formed using the semiconductor substrate 100 will be described below.
In a fourth example of the first exemplary embodiment, the process of forming the second GaN layer 104 using an MOCVD apparatus will be described. In this example, crystal growth was performed at a heating temperature of 1045° C. for 5 hours while supplying TMGa as a raw gas at a flux of 20 μmol/min. Further, in the fourth example, a Ta layer 103 having a thickness of 100 nm was formed in a shape of stripes on the first GaN layer 102.
In FIG. 14, the semiconductor substrate 100 with the second GaN layer 104 formed thereon under these conditions is shown. FIG. 14 is a SEM micrograph of a side section of a portion of the semiconductor substrate 100. As shown in FIG. 14, a void 102a is formed in a portion of the first GaN layer 102 under the Ta layer 103. Further, in the fourth example, it was observed that holes 103a were formed in the Ta layer 103 during the formation of the second GaN layer 104.
For the semiconductor substrate 100 of the fourth example, the conditions for forming the second GaN layer 104 using the MOCVD apparatus were adjusted to permit the void 102a to be formed in the first GaN layer 102 using the Ta layer 103 by etching. Thus, when the second GaN layer 104 was formed as illustrated in the first exemplary embodiment, it was possible to form the void 10a in the first GaN layer 102 by etching during growth of the first GaN layer 102. In other words, when a metallic material layer was partially formed on the first GaN layer 102, it was possible to form the void 102a in the first GaN layer 102. The metallic material layer may be used for etching the first GaN layer 102 as discussed above in relation to the first exemplary embodiment.
In addition, the MOCVD conditions for the fourth example are provided as an example, and thus, may be set to allow the growth of the first GaN layer and the formation of the void 102a to be simultaneously progressed. Here, since the growth rate of the first GaN layer 102 is slower than that of the second GaN layer 104, the MOCVD conditions were adjusted in consideration of the growth rate of the first GaN layer 102 in the fourth example.
Further, in the fourth example, the holes 103a were formed in the Ta layer 103 during the process of growing the second GaN layer 104, but, for example, the Ta layer 103 may be formed using a mask which is previously formed with holes. Further, the shape of the Ta layer 103 is not limited to the aforementioned stripe shape, and may be changed depending on a device structure to be formed on the semiconductor substrate 100. An example of a device formed using the semiconductor substrate 100 will be described below.
A first comparative example will be described hereinafter. In the first comparative example, the process of forming the second GaN layer 104 of the semiconductor substrate 100 under different conditions of the MOCVD apparatus will be described.
In the first comparative example, crystal growth was performed at a heating temperature of 1045° C. for 5 hours while supplying TMGa as a raw gas at a flux of 87 μmol/min.
In FIG. 7, the semiconductor substrate 100 with the second GaN layer 104 formed thereon under these conditions is shown. In FIG. 7, (A) is a SEM micrograph of a side section of a portion of the semiconductor substrate 100 and (B) is a SEM micrograph of a surface of the semiconductor substrate shown in (A). As clearly shown in these micrographs, granular materials are precipitated on the surface of the second GaN layer 104 and a void 102a is formed in a portion of the first GaN layer 102 under the Ta layer 103. The following EDX analysis shows that the granular materials are Ga granules, N granules, and Ta granules.
FIG. 8 shows results of EDX analysis on the surface of the granular materials. In FIG. 8, (A) is an EDX spectrum of the granular materials shown in FIG. 7(B), (B) is an EDX diagram of Ga obtained by EDX analysis of the granular materials of FIG. 7(B), and (C) is an EDX diagram of N obtained by EDX analysis of the granular materials of FIG. 7(B). In the EDX spectrum of FIG. 8(A), Ga, N and a trace of Ta are observed, so that Ga and N are observed as shown in the EDX diagrams of FIG. 8(B) and FIG. 8(C).
Results of EDX analysis on cross sections of the granular materials are shown in FIGS. 9 and 10. In FIG. 9, (A) is a SEM micrograph of a side section of a void formed as a granular material shown in FIG. 7(B) and (B) is an EDX spectrum of the void shown in (A). In FIG. 10, (A) is an EDX diagram of Ga obtained by EDX analysis on the side section of the void of FIG. 9(A), (B) is an EDX diagram of N obtained by EDX analysis on the side section of the void of FIG. 9(A), and (C) is an EDX diagram of Ta obtained by EDX analysis on the side section of the void of FIG. 9(A).
In the spectrum of FIG. 9(B), Ga and N of the second GaN layer 104 and the granular materials, Ta of the Ta layer 103, and Al and O of the sapphire substrate 101 are observed. Further, as shown in (A) to (C) of FIG. 10, Ga, N and Ta are observed at the void.
From these results, it is ascertained that the granular materials precipitated on the surface of the second GaN layer 104 are Ga granules, N granules, and Ta granules. Namely, in the first comparative example, it is believed that a bond between Ga and N at an etched portion of the first GaN layer 103 is broken, a reaction of GaO is caused, and gasification of Ga and N is blocked, thereby causing precipitation of the Ga granules, N granules and Ta granules on the surface of the second GaN layer.
As such, in the conditions of the MOCVD apparatus for the first comparative example, the flux of TMGa was set to 87 μmol/min, which is higher than that of the first example, thereby causing the precipitation of such granular materials on the substrate. Thus, a desired flux X of the TMGa not causing precipitation of the granular materials on the substrate is less than 87 μmol/min.
The granular materials of the first comparative example contain Ta and N, which can be removed by evaporation when the substrate 101 is maintained at a relatively high temperature or when a pressure around the substrate 101 is lowered. Further, the granular materials may be evaporated during growth of the second GaN layer by maintaining the substrate 101 at a temperature at which Ta and N of the granular materials are evaporated, or by maintaining the substrate 101 at a pressure at which these granular materials are evaporated, after stopping the growth of the second GaN layer.
In the second, third, and fourth examples of the first exemplary embodiment, the thickness of the Ta layer 103 was changed to 30 nm, 50 nm, and 100 nm, respectively. The void 102a was formed in the first GaN layer 104 by etching even when the thickness of the Ta layer 103 was changed in this manner.
FIG. 15 diagrammatically shows that a Ta2O5 region formed in the Ta layer 103 varies depending on the thickness of the Ta layer 103. FIG. 15(A) is a diagram showing a Ta2O5 film converted from a 5 nm thick Ta layer 103 and FIG. 15(B) is a diagram showing a Ta2O5 film converted from a surface of a 100 nm thick Ta layer. After depositing the Ta layer 103 on the surface of the first GaN layer 102 using an electron beam (EB) deposition apparatus, the Ta layer 103 was transferred to an MOCVD apparatus while being exposed to air. During the transfer of the Ta layer 103, the Ta layer 103 was converted into Ta2O5 by reaction with oxygen. As a result, when the Ta layer 103 was deposited to a thickness of 5 nm as shown in FIG. 15(A), the overall Ta layer 103 was converted into Ta2O5, and when the 100 nm thick Ta layer 103 was deposited as shown in FIG. 15(B), the surface of the Ta layer 103 was converted into Ta2O5. In other words, when Ta contacts air at room temperature, Ta2O5 is formed. FIG. 15(A) diagrammatically shows an example of lateral growth of a 5 nm thick Ta layer on a GaN layer. Further, FIG. 16 shows an example of lateral growth of a 10 nm thick Ta2O5 film on a substrate. In both examples, the growth was progressed without etching of the GaN layer under the Ta layer. In other words, when a substrate having a 5 nm thick Ta layer thereon was transferred to the MOCVD apparatus while being exposed to air, a 5 nm thick Ta2O5 film was formed on the substrate in FIG. 15(A). The Ta2O5 film was a very good mask which was laterally grown. On the other hand, when the 100 nm thick Ta layer was deposited as shown in FIG. 15(B), the result was different. When the Ta layer is deposited by EB deposition, a raw material of Ta is positioned in air and a thin oxide layer is thus formed on the Ta layer. As Ta is further deposited, it is converted initially into Ta2O5, but conversion into Ta2O5 gradually slows to allow deposition of Ta. The Ta2O5 film has a thickness of 5 nm or less on the GaN layer and contains a portion composed of Ta. An upper layer of the Ta2O5 film is composed of Ta. Further, as the substrate having the Ta layer thereon is transferred to the MOCVD apparatus while being exposed to air, a thin Ta2O5 film is formed on the Ta layer. As a result, the surface of the Ta layer is enveloped in the thin Ta2O5 film. In this Ta layer, the Ta2O5 film on the GaN layer is partially mixed with Ta. This result is diagrammatically shown in FIG. 15(B). Although N of the GaN layer and Ta of the Ta layer are coupled to form TaN, Ga is still used as the raw material, since Ga is the same as Ga deposited during vapor deposition.
In the first, second, third, and fourth examples, a Ta2O5 region formed by oxidation of the Ta layer 103 was laterally grown with respect to the first GaN layer 102 and serves as an etching mask. As a result, in the second example, as shown in FIG. 12, it was ascertained that the Ta2O5 region was not formed at the opposite ends of the 30 nm thick Ta layer 103, and the formation of the void 102a was progressed from portions of the first GaN layer 102 under the opposite ends of the Ta layer 103. In both the third and fourth examples, in which the Ta layers 103 were formed to a thickness of 50 nm and a thickness of 100 nm, respectively, the formation of the void 102a was progressed as in the second example, since the Ta2O5 region was formed on the surface of the Ta layer to act as the etching mask with respect to the first GaN layer 102.
Accordingly, as in the first, second, third, and fourth examples, a thickness of the Ta layer 103 may be in the range of 20 ̃100 nm in order to permit formation of the Ta2O5 region, which acts as the etching mask. Further, in FIG. 16(A), which shows an example of a 5 nm thick Ta mask formed on the first GaN layer 102, the void 102a is not formed under the Ta mask. Further, in FIG. 16(B), which shows an example of forming only the Ta2O5 mask, it is ascertained that the Ta2O5 mask can be formed on the GaN layer and InGaAlN layer, for example. Thus, since the Ta2O5 mask is formed regardless of the thickness of the Ta layer 103, it is possible to progress the formation of the void 102a in the first GaN layer 102 under the Ta2O5 mask.
Next, in a second exemplary embodiment of the present invention, a light emitting diode (LED) array formed on the semiconductor substrate 100 of the first exemplary embodiment will be described with reference to FIG. 11.
FIG. 11 is a sectional view of an LED array according to the second exemplary embodiment.
Referring to FIG. 11, LEDs 200 are separated from each other on the semiconductor substrate 100. Each LED 200 includes a lower semiconductor layer 201 composed of a first compound semiconductor layer, an active layer 202, and an upper semiconductor layer 203 composed of a second compound semiconductor layer. The upper and lower semiconductor layers 203, 201 may comprise the same class as the first and second GaN layers 102, 104. The active layer 202 may have a single or multi-quantum well structure having a barrier layer, and may be formed of a material and composition selected depending on a desired light emitting frequency. For example, the active layer 202 may be formed of a gallium nitride-based compound semiconductor. The upper and lower semiconductor layers 201, 203 may be gallium nitride-based compound semiconductors having a greater band gap than that of the active layer 202.
In the present exemplary embodiment, the lower semiconductor layer 201 on the semiconductor substrate 100 is formed on the second GaN layer 104. Thus, it is possible to reduce manufacturing costs by manufacturing the LEDs 200 using the semiconductor substrate 100.
On the other hand, during formation of the second GaN layer 104, reaction by-products of Ta and N may be precipitated and in turn negatively influence crystal quality of the lower semiconductor layer 201, active layer 202 and upper semiconductor layer 203 formed thereon. Accordingly, it is desirable that the by-products be removed by evaporation during or after the formation of the second GaN layer 104, as described above in FIG. 1 and the first comparative example.
The reaction by-products may be removed by evaporation during formation of the lower semiconductor layer 201. For example, when the first compound semiconductor layer is grown by MOCVD, the reaction by-products may be removed by evaporation by adjusting a growth temperature, growth pressure, growth speed, and flux of a Ga source of the lower semiconductor layer 210, as in the case of removing the reaction by-products using growth of the second GaN layer 104. Particularly, the reaction by-products may be removed by evaporation by setting the flux of TMGa as the Ga source of the lower semiconductor layer 201 to less than 87 μmol/min.
The upper semiconductor layer 203 is located above a portion of the lower semiconductor layer 201, with the active layer 202 interposed between the upper semiconductor layer 203 and the lower semiconductor layer 201. Further, an upper electrode layer 204 may be formed on the upper semiconductor layer 203. The upper electrode layer 204 may be a transparent electrode layer formed of, for example, indium tin oxide (ITO), Ni/Au, and the like.
Further, an upper electrode pad 205 is formed on the upper electrode layer 204 and a lower electrode 207 is formed on an exposed region of the lower semiconductor layer 201.
After the LEDs 200 are formed on the single semiconductor substrate 100 in this manner, the LEDs 200 are divided into individual LEDs 200 by cutting a portion of the semiconductor substrate 100 between the LEDs 200. In each LED of this embodiment, the upper electrode pad 205 and the lower electrode pad 207 are laterally arranged, but the LED may be fabricated to have vertically arranged electrodes. In other words, a vertical type LED may be fabricated by separating the sapphire substrate 101 using the void 102a of the semiconductor substrate 100, flattening the separated surface of the first GaN layer 102 by RIE or the like, and forming an upper electrode pad 205 and a lower electrode pad 207.
As such, it is possible to reduce manufacturing costs of the LED array by manufacturing the LEDs 200 using the semiconductor substrate 100. Further, when forming the LEDs 200 on the second GaN layer 104, it is possible to construct an LED array with improved luminous efficiency and high brightness by forming the compound semiconductors such that the second GaN layer 104 and the lower semiconductor layer 201 have different indices of refraction from each other. Further, when a laser diode is formed using the semiconductor substrate 100, it is possible to achieve an improvement in heat dissipation properties together with long operational lifetime of the laser diode, since the laser diode is formed on the GaN layer, which exhibits better thermal conductivity than the sapphire substrate 101.
In the second exemplary embodiment, the LEDs 200 are formed on the second GaN layer of the semiconductor substrate 100. Alternatively, the LEDs 200 may be formed in the same manner using the GaN substrate, from which the sapphire substrate 101 is separated.
Therefore, the semiconductor substrate 100 is used to manufacture semiconductor devices such as LEDs or laser diodes, thereby facilitating fabrication of high performance semiconductor devices at low cost without using an expensive GaN substrate.
Next, a method of fabricating a light emitting device via separation of a growth substrate will be described with reference to FIG. 17.
FIG. 17 is a flow diagram of a method of fabricating a light emitting device according to a third exemplary embodiment.
Referring to FIG. 17(A), a first GaN layer 102 is grown on a sapphire substrate 101 as a first substrate, and a Ta layer 103 is formed in a shape of stripes on the first GaN layer 102, as described with reference to FIG. 1(A) to FIG. 1(D). Then, a second GaN layer 104 is formed on the first GaN layer 102 and the Ta layer 103. Here, voids 102a are formed in the first GaN layer 102. Further, during formation of the second GaN layer 104, holes 103a may be formed in the Ta layer 103. The holes 103a may be previously formed by patterning before the second GaN layer 104 is formed.
Referring to FIG. 17(B), a first conductive compound semiconductor layer 301, an active layer 302, and a second conductive compound semiconductor layer 303 are sequentially formed on the second GaN layer 104.
The first conductive compound semiconductor layer 301, active layer 302, and second conductive compound semiconductor layer 303 may be gallium nitride-based semiconductors and may be formed by MOCVD. The active layer 302 may have a single or multi-quantum well structure, and may be formed of a material and composition selected depending on a desired light emitting frequency. The first and second semiconductor layers 301 and 303 may be formed of a material having a greater band gap than that of the active layer 302.
Then, a second substrate 400 is attached to the second conductive compound semiconductor layer 303. The second substrate 400 may be a metal substrate having good thermal conductivity or a silicon-based substrate such as Si or SiC. The second substrate 400 may be attached to the second conductive compound semiconductor layer 303 in various ways, for example, via a bonding metal.
Referring to FIG. 17(C), the sapphire substrate 101 is separated from the second GaN layer 104. The sapphire substrate 101 may be separated from the second GaN layer 104 by etching the first GaN layer 102 using a chemical solution. Although the first GaN layer 102 is shown as being completely removed from an interface between the sapphire substrate 101 and the first GaN layer 102, the present invention is not limited to this configuration and only a portion of the first GaN layer may be removed therefrom. Since the chemical solution and the etching method are the same as those of the first exemplary embodiment illustrated in FIG. 1, a description thereof will be omitted herein.
Alternatively, the sapphire substrate 101 may be separated through growth of the voids 102a. Referring again to FIG. 17(C), the sapphire substrate 101 is heated to grow the voids 102a. Then, adjoining voids 102a meet each other so that the sapphire substrate 101 is separated from the second GaN layer 104. The sapphire substrate 101 may be heated to 300° C. or more, for example, in the range of 900 ̃1100° C.
Heating the sapphire substrate 101 may be performed while attaching the second substrate 400 to the second conductive compound semiconductor layer 303. As a result, the sapphire substrate 101 may be easily separated without using a different process for separating the sapphire substrate 101.
Further, although the adjoining voids 102a are illustrated as meeting each other to allow the sapphire substrate 101 to be separated from the second GaN layer 104, the adjoining voids 102a may not meet each other when the sapphire substrate 101 is heated. In this case, since the voids 102a have a sufficient size, the sapphire substrate 101 may be easily separated by applying force to the sapphire substrate. Here, it is desirable that the voids 102a be grown by heating the sapphire substrate 101 until a lower end of the voids 102a contacts the sapphire substrate 101.
Referring to FIG. 17(D), after the sapphire substrate 101 is separated from the second GaN layer, the separated surface is flattened by RIE or polishing. Here, the first conductive semiconductor layer 301 may be exposed by polishing the second GaN layer 104 to remove the second GaN layer 104. Alternatively, if the second GaN layer 104 is a first conductive semiconductor layer, the second GaN layer 104 may remain.
Referring to FIG. 17(E), a lower electrode pad 401 is formed on the second substrate 400 and an upper electrode pad 402 is formed on the surface from which the sapphire substrate was separated. Then, the light emitting devices are divided into individual light emitting devices, thereby completing fabrication of vertical type light emitting devices as shown in FIG. 17(E).
Here, the first conductive semiconductor layer may be a GaN-based n-type compound semiconductor and the second conductive semiconductor layer may be a GaN-based p-type compound semiconductor. Thus, it is possible to form a rough surface on the separated surface, for example, on a surface of the first conductive semiconductor layer 301, by photo electrochemical etching or the like.
Although the method of fabricating a vertical type light emitting device is described in the third exemplary embodiment, a horizontal-type light emitting device may also be fabricated on the second substrate 400 after separation of the sapphire substrate 101, as described in the second exemplary embodiment.
As such, the method according to the present invention allows a growth substrate such as a sapphire substrate to be easily separated without using a laser beam after growing a GaN-based compound semiconductor layers on the sapphire substrate, thereby enabling a reduction in fabrication costs of LEDs. Further, the method according to the present invention does not require polishing of the sapphire substrate, which is performed for a laser lift-off process, so that the sapphire substrate may be used again.
Next, a method of fabricating a light emitting device using an apparatus including a plurality of chambers will be described with reference to FIGS. 18 and 19.
FIG. 18 is a flow diagram of a method of fabricating a light emitting device according to a fourth exemplary embodiment, and FIG. 19 is a schematic view of an apparatus for fabricating a light emitting device. In FIG. 18, (A) is a sectional view of a process of forming a first GaN layer and a metallic material layer, (B) is a sectional view of a process of forming a second GaN layer and a void, and (C) is a sectional view of a process of forming compound semiconductor layers.
Referring to FIG. 18(A), reference numeral 101 indicates a sapphire (Al2O3) substrate. First, a first GaN layer 102 having a thickness of about 2 μm is formed on the sapphire substrate 101. This thickness of the first GaN layer 102 is provided as an example.
Next, a Ta layer (metallic material layer) 103 having a thickness of about 50 nm is formed in a stripe shape, which have a width of 5 μm and are separated a distance of 5 μm from each other, on the first GaN layer 102 by EB deposition and lift-off. The shape, thickness, width, and separation distance of the Ta layer 103 are provided as an example.
Next, in FIG. 18(B), the substrate 101 having the first GaN layer 102 and Ta layer 103 is placed in a first chamber 10 (see FIG. 19), and a second GaN layer 104 is then formed on the first GaN layer 102 and the Ta layer 103 by MOCVD. FIG. 18(B) shows the second GaN layer 104 during formation thereof. In the present exemplary embodiment, N in the first GaN layer 102 combines with Ta to form TaN, which is changed into a different substance and rises towards a vapor phase region in which the concentration of N is relatively high. The TaN becomes unstable at 900° C. or more and is evaporated at 1000° C. or more. As the TaN is evaporated, a hole is deepened to form a void 102a. Here, although N in the first GaN layer 102 becomes TaN, Ga remains in the first GaN layer 102. Since this Ga remaining in the first GaN layer 102 is the same as Ga deposited during the vapor deposition, it is used as the raw material.
The thickness of the second GaN layer 104 may be greater than or equal to one half the thickness of the Ta layer 103. In addition, the second GaN layer 104 may have a thickness less than 1000 μm, but is not limited thereto.
While the second GaN layer 104 is formed by MOCVD, a portion of the first GaN layer 102 under the Ta layer 103 is removed by etching and a formation region of the void 102a is extended substantially to the sapphire substrate 101, as shown in the FIG. 18(B). Further, the surface of the substrate is flattened to progress the growth of the first GaN layer 102 along with the growth of the second GaN layer 104, as shown in FIG. 18.
As described above, while the second GaN layer 104 is grown, reaction by-products are produced by reaction between Ta and N. Such reaction by-products may contaminate a first chamber 10 and deteriorate crystal quality of compound semiconductors grown in the first chamber 10. Thus, growth of the compound semiconductors may be carried out in a second chamber 20 that is separated from the first chamber 10.
After the growth of the second GaN layer 104 is completed, the substrate 101 is transferred from the first chamber 10 to the second chamber 20 (see FIG. 19). The first chamber 10 is connected to the second chamber 20 via a communication path 30. A shutter 13 may be disposed between the first chamber 10 and the communication path 30 to prevent movement of contaminants from the first chamber 10 to the second chamber 20, and a shutter 23 may also be disposed between the second chamber 20 and the communication path 30 for the same purpose. Although the apparatus is shown as including the shutters 13, 23 between the respective chambers 10, 20 and the communication path 30, the apparatus may include a single shutter in the communication path 30.
Further, each of the chambers 10, 20 is provided with a pedestal 11 or 21 that supports the substrate 101 and includes a heater (not shown) for heating the substrate 101. Although not shown in FIG. 19, each of the chambers 10, 20 is connected to a source line for supplying a source gas and a carrier gas, and to a discharge line for vacuum discharge.
Since the first chamber 10 is connected to the second chamber 20 via the communication path 30, the substrate 101 may be transferred from the first chamber 10 to the second chamber 20 while remaining under vacuum.
Then, referring to FIG. 18(C), a first compound semiconductor layer 201, active layer 202 and second compound semiconductor layer 203 are formed on the second GaN layer 104 in the second chamber 20.
The compound semiconductor layers 201, 202 and 203 may be formed by MOCVD as in the second GaN layer 104 and may comprise GaN-based compound semiconductors.
Since the compound semiconductors are formed in the second chamber 20 separated from the first chamber 10, it is possible to prevent the crystal quality of the compound semiconductors from being degraded due to reaction by-products produced during formation of the void 102a. Furthermore, since the substrate 101 may be transferred from the first chamber 10 to the second chamber 20 while remaining under vacuum, it is possible to grow the second GaN layer 104 and the compound semiconductor layers 201, 202 and 203 by an in-situ process.
Further, in the fourth exemplary embodiment, since the void 102a is formed in the first GaN layer 102 on the substrate 101, separation of the substrate 101 may be easily achieved using the void 102a. 
The LED according to the second exemplary embodiment or the LED according to the third exemplary embodiment may be fabricated using the compound semiconductor layers of the fourth exemplary embodiment, and a detailed description thereof will be omitted herein to prevent repetition.
In the fourth exemplary embodiment, the first and second chambers 10, 20 are separated from each other, thereby preventing deterioration in crystal quality of the compound semiconductor layers by the reaction by-products produced during formation of the void 102a. 
In the first, second, third and fourth exemplary embodiments, the Ta layer is formed as the metallic material layer. However, the metallic material layer may be formed of Ta, P, Ni, Cr, any alloy thereof, or any alloy of metals and semiconductors. Further, any metallic material capable of being used for etching the first GaN layer may also be used. Thus, the metallic material may have a higher melting point than a heating temperature at which the second GaN layer 104 is formed.
As apparent from the above description, in the methods according to the exemplary embodiments, a void is formed in a semiconductor layer formed on a growth substrate so that the substrate can be easily removed from the semiconductor layer by etching the semiconductor layer with a chemical solution using the void or by growing the void. Accordingly, it is possible to remove the growth substrate such as a sapphire substrate in the absence of a laser beam, thereby enabling fabrication of semiconductor substrates, such as GaN substrates, or light emitting devices at low cost. Further, the void may be grown by heating the growth substrate in a process such as a process of bonding a second substrate, so that the growth substrate may be separated without an additional process for removing the growth substrate, thereby simplifying the process of fabricating a light emitting device.
In addition, according to the exemplary embodiments, the method enables fabrication of a flat and easily separable GaN substrate on a heterogeneous substrate at low cost while allowing effective removal of reaction by-products. Thus, it is possible to realize performance improvement and long operational lifespan of semiconductor devices, such as LEDs or laser diodes, which are manufactured using the GaN substrate.
Moreover, even in the case where a chamber is contaminated by reaction by-products during formation of the void, a compound semiconductor is grown in a different chamber separated from the chamber where the void is formed. Thus, it is possible to provide the compound semiconductor with good quality.
It will be apparent to those skilled in the art that various modifications and variation can be made in the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.

## Claims

1. A method of fabricating a light emitting device, the method comprising:
forming a plurality of compound semiconductor layers on a first substrate, the compound semiconductor layers comprising a first semiconductor layer;
disposing a second substrate on the compound semiconductor layers;
separating the first substrate from the compound semiconductor layers,
wherein forming the plurality of compound semiconductor layers comprises:
forming a plurality of voids in the first compound semiconductor layer; and
increasing a volume of the voids,
wherein separating the first substrate comprises:
etching a portion of the first semiconductor layer.

2. The method of claim 1, further comprising:
forming an additional layer on the first semiconductor layer.

3. The method of claim 2, wherein the voids are formed below the additional layer.

4. The method of claim 3, wherein the additional layer comprises a metallic material layer.

5. The method of claim 1, wherein the voids are extended to the first substrate before disposing the second substrate on the compound semiconductor layers.

6. The method of claim 5, wherein etching a portion of the first semiconductor layer comprises introducing a chemical solution to an interface between the first substrate and the first semiconductor layer via the voids.

7. The method of claim 1, wherein the first semiconductor layer comprises a GaN-based layer.

8. A method of fabricating a light emitting device, the method comprising:
forming a plurality of compound semiconductor layers on a first substrate, the compound semiconductor layers comprising a first semiconductor layer and a second semiconductor layer contacting the first semiconductor layer;
disposing a second substrate on the compound semiconductor layers;
separating the first substrate from the second semiconductor layer,
wherein forming the plurality of compound semiconductor layers comprises:
forming a plurality of voids in the first compound semiconductor layer; and
increasing a volume of the voids, and
wherein separating the first substrate from the second semiconductor layer comprises twisting the first substrate away from the first semiconductor layer.

9. A method of fabricating a light emitting device, the method comprising:
forming a plurality of compound semiconductor layers on a first substrate, the compound semiconductor layers comprising a first semiconductor layer and a second semiconductor layer contacting the first semiconductor layer;
disposing a second substrate on the compound semiconductor layers;
separating the first substrate from the second semiconductor layer,
wherein forming the plurality of compound semiconductor layers comprises:
forming a plurality of voids in the first compound semiconductor layer; and
increasing a volume of the voids, and
wherein separating the first substrate from the second semiconductor layer comprises heating the first substrate such that the voids weaken a coupling force between the first substrate and the first semiconductor layer.

10. The method of claim 1, wherein the second substrate is a silicon-based substrate, and the silicon-based substrate is disposed on the compound semiconductor layers before separating the first substrate from the compound semiconductor layers.

11. The method of claim 4, wherein the plurality of compound semiconductor layers further comprises a second semiconductor layer contacting the first semiconductor layer, the first semiconductor layer and the second semiconductor layer comprising GaN, and the metallic material layer comprises Ta.

12. The method of claim 11, wherein the metallic material layer is about 5-100 nm thick.