# Patent

## Title
Composition for noxious organisms-controlling agent and method for using the same

## Abstract

The present invention relates to a composition for noxious organisms-controlling agent having a synergistic effect and a method for using said composition, which comprises, as active ingredients thereof, one or more compounds selected from the phthalamide derivatives represented by general formula (I) being useful as an insecticide or acaricide and one or more compounds selected from the compounds having insecticidal, acaricidal or nematocidal activity:




wherein R1, R2 and R3 may be the same or different and each represent hydrogen atom, C3-C6 cycloalkyl, -A1-Qp, etc., each of X and Y may be the same or different and represents hydrogen atom, halogen atom, etc., n is an integer of 1 to 4, m is an integer of 1 to 5, and each of Z1 and Z2 represents O or S.

## Background
This is a continuation application of U.S. application Ser. No. 10/475,030 filed Oct. 16, 2003, which is now U.S. Pat. No. 7,361,653.


TECHNICAL FIELD
The present invention relates to a composition for noxious organisms-controlling agent having a synergistic effect and a method for using said composition, which comprises a phthalamide derivative represented by general formula (I) being useful as an insecticide or acaricide and one or more compounds selected from the compounds having insecticidal, acaricidal or nematocidal activity.
BACKGROUND ART
The phthalamide derivatives of the present invention represented by general formula (I) are known compounds disclosed in JP-A-11-240857 and JP-A-2001-131141, wherein it is mentioned that these compounds have an insecticidal or acaricidal activity.
On the other hand, the compounds having insecticidal, acaricidal or nematocidal activity, as the second active ingredient of the present invention, are known compounds as disclosed in The Pesticide Manual Eleventh Edition 1997, etc.
DISCLOSURE OF THE INVENTION
There exist many noxious organisms which are difficult or impossible to control by the use of a single member selected from the phthalamide derivatives represented by the general formula (I) of the present invention and the insecticidal, acaricidal or nematocidal compounds. Accordingly, it is expected that discovery of the means and method for the effective control of such noxious organisms will lead to a more effective production of crop plants.
With the aim of solving the problem mentioned above, the present inventors have conducted extensive studies. As a result, it has been found that a plurality of noxious organisms can be controlled effectively by the combined use of one or more compounds selected from the phthalamide derivatives represented by the general formula (I) and one or more compounds selected from the insecticidal, acaricidal or nematocidal compounds. The present invention has been accomplished on the basis of this finding.
The present invention relates to a composition for noxious organisms-controlling agent comprising, as active ingredients thereof, one or more compounds selected from the phthalamide derivatives represented by the general formula (I):




wherein R1, R2 and R3, which may be the same or different, each represent a hydrogen atom, a C3-C6 cycloalkyl group, a halo C3-C6 cycloalkyl group or -A1-Qp (in this formula, A1 represents a C1-C8 alkylene group, a C3-C6 alkenylene group or a C3-C6 alkynylene group; Q represents a hydrogen atom; a halogen atom; a cyano group; a nitro group; a halo C1-C6 alkyl group; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkoxycarbonyl group; a di C1-C6 alkoxyphosphoryl group in which the alkoxy groups may be the same or different; a di C1-C6 alkoxythiophosphoryl group in which the alkoxy groups may be the same or different; a diphenylphosphino group; a diphenylphosphono group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group means a pyridyl group, a pyridine-N-oxide group, a pyrimidinyl group, a furyl group, a tetrahydrofuryl group, a thienyl group, a tetrahydrothienyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an oxazolyl group, an isoxazolyl group, an oxadiazolyl group, a thiazolyl group, an isothiazolyl group, a thiadiazolyl group, an imidazolyl group, a triazolyl group or a pyrazolyl group); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or —Z3—R4 (in this formula, Z3 represents —O—, —S—, —SO—, —SO2— or —N(R5)— (in this formula, R5 represents a hydrogen atom; a C1-C6 alkylcarbonyl group; a halo C1-C6 alkylcarbonyl group; a C1-C6 alkoxycarbonyl group; a phenylcarbonyl group; a substituted phenylcarbonyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a phenyl C1-C4 alkoxycarbonyl group; or a substituted phenyl C1-C4 alkoxycarbonyl group having, on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group), and R4 represents a hydrogen atom; a C1-C6 alkyl group; a halo C1-C6 alkyl group; a C3-C6 alkenyl group; a halo C3-C6 alkenyl group; a C3-C6 alkynyl group; a halo C3-C6 alkynyl group; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkylcarbonyl group; a halo C1-C6 alkylcarbonyl group; a C1-C6 alkoxycarbonyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a phenyl C1-C4 alkyl group; a substituted phenyl C1-C4 alkyl group having, on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); or a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group); and p represents an integer of 1-4); and R1 and R2 may be taken conjointly to form a 4- to 7-membered ring which may be interrupted by one to three, the same or different hetero atoms selected from oxygen atom, sulfur atom and nitrogen atom;

X may be the same or different and represents a hydrogen atom; a halogen atom; a cyano group; a nitro group; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A2-R6 (in this formula, A2 represents —O—, —S—, —SO—, —SO2—, —C(═O)—, —C(═NOR7)— (in this formula, R7 represents a hydrogen atom, a C1-C6 alkyl group, a halo C1-C6 alkyl group, a C3-C6 alkenyl group, a halo C3-C6 alkenyl group, a C3-C6 alkynyl group, a cyclo C3-C6 alkyl group, a phenyl C1-C4 alkyl group or a substituted phenyl C1-C4 alkyl group having, on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group), a C1-C6 alkylene group, a halo C1-C6 alkylene group, a C2-C6 alkenylene group, a halo C2-C6 alkenylene group, a C2-C6 alkynylene group or a halo C3-C6 alkynylene group, and
(1) in a case where A2 represents —O—, —S—, —SO— or —SO2—, R6 represents a halo C3-C6 cycloalkyl group; a halo C3-C6 cycloalkenyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A3-R8 (in this formula, A3 represents a C1-C6 alkylene group, a halo C1-C6 alkylene group, a C3-C6 alkenylene group, a halo C3-C6 alkenylene group, a C3-C6 alkynylene group or a halo C3-C6 alkynylene group, and R3 represents a hydrogen atom; a halogen atom; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkoxycarbonyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A4-R9 (in this formula, A4 represents —O—, —S—, —SO—, —SO2— or —C(═O), and R9 represents a C1-C6 alkyl group; a halo C1-C6 alkyl group; a C3-C6 alkenyl group; a halo C3-C6 alkenyl group; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); or a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group)),

(2) in a case where A2 represents —C(═O)— or —C(═NOR7)— (in this formula, R7 is as defined above), R6 represents a C1-C6 alkyl group; a halo C1-C6 alkyl group; a C2-C6 alkenyl group; a halo C2-C6 alkenyl group; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkoxy group; a C1-C6 alkylthio group; a mono C1-C6 alkylamino group; a di C1-C6 alkylamino group in which the alkyl groups may be the same or different; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a phenylamino group; a substituted phenylamino group having, on the ring thereof, at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); or a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group, and

(3) in a case where A2 represents a C1-C6 alkylene group, a halo C1-C6 alkylene group, a C2-C6 alkenylene group, a halo C2-C6 alkenylene group, a C2-C6 alkynylene group or a halo C3-C6 alkynylene group, R6 represents a hydrogen atom; a halogen atom; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkoxycarbonyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A5-R10 (in this formula, A5 represents —O—, —S—, —SO— or —SO2—, and R10 represents a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A6-R11 (in this formula, A6 represents a C1-C6 alkylene group; a halo C1-C6 alkylene group; a C2-C6 alkenylene group; a halo C2-C6 alkenylene group; a C2-C6 alkynylene group; or a halo C3-C6 alkynylene group; and R11 represents a hydrogen atom; a halogen atom; a C3-C6 cycloalkyl group; a halo C3-C6 cycloalkyl group; a C1-C6 alkoxy group; a halo C1-C6 alkoxy group; a C1-C6 alkylthio group; a halo C1-C6 alkylthio group; a C1-C6 alkylsulfinyl group; a halo C1-C6 alkylsulfinyl group; a C1-C6 alkylsulfonyl group; a halo C1-C6 alkylsulfonyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a phenoxy group; a substituted phenoxy group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a phenylthio group; a substituted phenylthio group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above; or a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group))), and

n represents an integer of 1-4;
and X may be taken conjointly together with an adjacent carbon atom on the phenyl ring to form a condensed ring (the term condensed ring means naphthalene, tetrahydronaphthalene, indene, indane, quinoline, quinazoline, chromane, isochromane, indole, indoline, benzodioxane, benzodioxole, benzofuran, dihydrobenzofuran, benzothiophene, dihydrobenzothiophene, benzoxazole, benzothiazole, benzimidazole or indazole), and said condensed ring may have at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group, halo C1-C6 alkylsulfonyl group, phenyl group, substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group, heterocyclic group (the term heterocyclic group is as defined above) and substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; and
Y may be the same or different and represents a hydrogen atom; a halogen atom; a cyano group; a nitro group; a halo C3-C6 cycloalkyl group; a phenyl group; a substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; a heterocyclic group (the term heterocyclic group is as defined above); a substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; or -A2-R6 (in this formula, A2 and R6 are as defined above); and m represents an integer of 1-5; and
Y may be taken conjointly together with an adjacent carbon atom on the phenyl ring to form a condensed ring (the term condensed ring is as defined above), and said condensed ring may have at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group, halo C1-C6 alkylsulfonyl group, phenyl group, substituted phenyl group having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group, heterocyclic group (the term heterocyclic group is as defined above) and substituted heterocyclic group (the term heterocyclic group is as defined above) having at least one, the same or different substituents selected from the group consisting of halogen atom, C1-C6 alkyl group, halo C1-C6 alkyl group, C1-C6 alkoxy group, halo C1-C6 alkoxy group, C1-C6 alkylthio group, halo C1-C6 alkylthio group, C1-C6 alkylsulfinyl group, halo C1-C6 alkylsulfinyl group, C1-C6 alkylsulfonyl group and halo C1-C6 alkylsulfonyl group; and
Z1 and Z2 represent an oxygen atom or a sulfur atom; and
one or more compounds selected from compounds having an insecticidal, acaricidal or nematocidal activity;
and to a method for using said composition.
The noxious organisms-controlling agent of the present invention exhibits a marked effect even when dosage thereof is so low that any of the ingredients constituting said agent can exhibit no effect at such a low dosage if used singly, and exhibits a marked controlling effect against noxious organisms and agent-resistant noxious organisms which cannot be controlled with any of the single ingredients.
MODE FOR PRACTICE OF THE INVENTION
In the definition of general formula (I) representing the phthalamide derivative of this invention, the term “halogen atom” means chlorine atom, bromine atom, iodine atom or fluorine atom; “C1-C6 alkyl” means a straight or branched chain alkyl group having 1-6 carbon atoms such as methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl, t-butyl, n-pentyl, n-hexyl and the like; “halo C1-C6 alkyl” means a straight or branched chain alkyl group having 1-6 carbon atoms which is substituted with at least one, the same or different halogen atoms; “C1-C8 alkylene” means a straight or branched chain alkylene group having 1-8 carbon atoms such as methylene, ethylene, propylene, trimethylene, dimethylmethylene, tetramethylene, isobutylene, dimethylethylene, octamethylene and the like;
As the “4- to 7-membered ring which may be interrupted by 1 to 3, the same or different hetero atoms selected from oxygen atom, sulfur atom and nitrogen atom” formed through a mutual combination of R1 and R2, for example, azetidine ring, pyrrolidine ring, pyrroline ring, piperidine ring, imidazolidine ring, imidazoline ring, oxazolidine ring, thiazolidine ring, isoxazolidine ring, isothiazolidine ring, tetrahydropyridine ring, piperazine ring, morpholine ring, thiomorpholine ring, dioxazine ring, dithiazine ring and the like can be referred to.
In some cases, the phthalamide derivative of the present invention represented by general formula (I) may have an asymmetric carbon atom or an asymmetric center in the structural formula thereof, and may have two or more optical isomers. The present invention involves all such optical isomers and mixtures consisting of the optical isomers at arbitrary ratios. In some cases, the present invention involves salts, hydrates and the like of these compounds.
The phthalamide derivatives represented by general formula (I) can be obtained by using the compounds and production processes disclosed in JP-A-11-240857 and JP-A-2001-131141.
Among the compounds represented by general formula (I), preferable are those in which R1 represents a hydrogen atom, R2 represents a C1-C6 alkyl group, a C1-C6 alkylthio C1-C6 alkyl group, a C1-C6 alkylsulfinyl C1-C6 alkyl group or a C1-C6 alkylsulfonyl C1-C6 alkyl group, R3 represents a hydrogen atom, X represents a halogen atom, n represents 1, Z1 and Z2 represent an oxygen atom, Y which may be the same or different represents a halogen atom, a C1-C6 alkyl group, a halo C1-C6 alkyl group or a halo C1-C6 alkoxy group, and m represents 2 or 3. Among these compounds, particularly preferable are the following compounds: N2-(1,1-dimethyl-2-methylthioethyl)-3-iodo-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}-phthalamide, N2-(1,1-dimethyl-2-methylsulfonylethyl)-3-iodo-N′-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-phenyl}phthalamide and N2-(1,1-dimethyl-2-methylsulfinylethyl)-3-iodo-N′-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-phenyl}phthalamide.
In Table 1, typical compounds of the present invention are listed. This invention, however, is by no means limited by these compounds. As examples of such compounds, the compounds disclosed in JP-A-11-240857 and JP-A-2001-131141 can be referred to.
General Formula (I)








TABLE 1








(I)








 



















Property


No
R1
R2
R3
Xn
Ym
mp ° C.
















1
CH3
H
H
3-NO2
2-CH3-5-Cl
169-171


2
C2H5
H
H
3-Cl
2-CH3-4-OCHF2
179-180


3
C2H5
H
H
3-NO2
2-CH3-5-Cl
175-177


4
n-C3H7
H
H
3-NO2
2-CH3-4-OCHF2
184-186


5
i-C3H7
H
H
3-Cl
4-C4H9-n
169-171


6
i-C3H7
H
H
3-Cl
4-C4H9-t
224-226


7
i-C3H7
H
H
3-Cl
4-CF(CF3)2
198-200


8
i-C3H7
H
H
3-Cl
4-CF2CF2CF3
203-204


9
i-C3H7
H
H
3-Cl
4-(CF2)3CF3
176-178


10
i-C3H7
H
H
3-Cl
4-OCF2CHFOC3F7-n
169-171


11
i-C3H7
H
H
6-Cl
4-SCH3
193-195


12
i-C3H7
H
H
3-Cl
4-SO2CH3
208-210


13
i-C3H7
H
H
3-Cl
4-SCHF2
220-222


14
i-C3H7
H
H
3-Cl
4-SCF2CHF2
198-200


15
i-C3H7
H
H
3-Cl
4-SO2CF2CHF2
227-230


16
i-C3H7
H
H
3-Cl
4-COCH3
217-219


17
i-C3H7
H
H
3-Cl
4-Ph
215-217


18
i-C3H7
H
H
3-Cl
2-CH3-4-OCH3
191-192


19
i-C3H7
H
H
3-Cl
2-CH3-4-CF2CF3
199-200


20
i-C3H7
H
H
3-Cl
2-CH3-4-OCF3
199-201


21
i-C3H7
H
H
3,6-Cl2
2-CH3-4-OCHF2
221-222


22
i-C3H7
H
H
3-Br
4-OCF3
208-210


23
i-C3H7
H
H
3-Br
2-CH3-4-CF2CF3
201-202


24
i-C3H7
H
H
3-Br
2-CH3-4-CF(CF3)2
222-224


25
i-C3H7
H
H
3-Br
2-CH3-4-SCH3
215-217


26
i-C3H7
H
H
3-Br
2-CH3-4-(3-CF3-PhO)
156-158


27
i-C3H7
H
H
3-Br
2-CH3-4-(5-CF3-2-Pyi-O)
182-184


28
i-C3H7
H
H
3-Br
-3-OCH2O-4-
195-198


29
i-C3H7
H
H
6-Br
2-CH3-4-OCF2CHFCF3
212-213


30
i-C3H7
H
H
6-Br
2-CH3-4-OCF2CHClF
211-213


31
i-C3H7
H
H
6-Br
2-CH3-4-OCF2CHF2
214-215


32
i-C3H7
H
H
5,6-Br2
2-CH3-4-OCHF2
208-210


33
i-C3H7
H
H
3-I
4-CF2CF2CF3
217-219


34
i-C3H7
H
H
3-I
4-CF(CF3)2
209-211


35
i-C3H7
H
H
3-I
4-SCH2CHF2
195-197


36
i-C3H7
H
H
3-I
4-SCHF2
204-206


37
i-C3H7
H
H
3-I
4-S(CF2)3CF3
185-187


38
i-C3H7
H
H
3-I
2-CH3-4-Cl
215-217


39
i-C3H7
H
H
3-I
2-Cl-4-CF3
170-171


40
i-C3H7
H
H
3-I
2-CH3-4-CF3
202-203


41
i-C3H7
H
H
3-I
2-CH3-4-CF2CF3
195-196


42
i-C3H7
H
H
3-I
2-CH3-4-CF2CF2CF3
193-195


43
i-C3H7
H
H
3-I
2-CH3-4-CF(CF3)2
211-213


44
i-C3H7
H
H
3-I
2-CH3-4-OCF3
214-216


45
i-C3H7
H
H
3-I
2-CH3-4-OCHF2
207-209


46
i-C3H7
H
H
3-I
2-CH3-4-OCH2CF2CHF2
229-231


47
i-C3H7
H
H
3-I
2-CH3-4-OCF2CHFCF3
213-214


48
i-C3H7
H
H
3-I
2-Cl-4-OCF3
173-175


49
i-C3H7
H
H
6-I
4-SCF(CF3)2
216-218


50
i-C3H7
H
H
6-I
2-Cl-4-CF3
195-196


51
i-C3H7
H
H
6-I
2-CH3-4-CF(CF3)2
237-239


52
i-C3H7
H
H
6-I
2-Cl-4-CF2CF2CF3
199-200


53
i-C3H7
H
H
3-F
2-CH3-4-CF(CF3)2
241-243


54
i-C3H7
H
H
3-F
2-CH3-4-OCF3
183-184


55
i-C3H7
H
H
3-NO2
3-F
228-230


56
i-C3H7
H
H
3-NO2
2-CH3-4-OCHF2
186-188


57
n-C4H9
H
H
3-NO2
2-CH3-5-Cl
172-174


58
s-C4H9
H
H
6-Cl
2-CH3-4-OCHF2
213-215


59
t-C4H9
H
H
3-NO2
2-CH3-4-OCHF2
172-173


60
c-C3H5
H
H
3-Cl
2-CH3-4-OCHF2
156-158


61
c-C4H7
H
H
3-NO2
2-CH3-5-Cl
206-208


62
c-C5H9
H
H
3-NO2
2-CH3-5-Cl
200-202


63
c-C6H11
H
H
3-NO2
2-CH3-5-Cl
225-227


64
CH2C3H5-c
H
H
3-NO2
2-CH3-5-F
190-192


65
CH2CH2Cl
H
H
3-NO2
2-CH3-5-F
179-181


66
CH2CH═CH2
H
H
3-NO2
2-CH3-4-OCHF2
194-195


67
CH2C≡CH
H
H
3-NO2
2-CH3-4-OCHF2
190-191


68
i-C3H7
H
H
3-Cl
4-CH═CBr2
209.8-214.8


69
i-C3H7
H
H
6-Cl
4-CH═CCl2
199.7


70
i-C3H7
H
H
3-I
4-CH═C(Cl)CF3
196.6


71
i-C3H7
H
H
6-I
4-CH═C(Cl)CF3
203.3


72
t-C4H9
H
H
3-I
2-CH3-4-CF2CF3
205-207


73
t-C4H9
H
H
6-I
2-CH3-4-CF2CF3
216-217


74
n-C4H9
H
H
6-I
2-CH3-4-CF2CF3
181.8-187.7


75
n-C5H11
H
H
6-I
2-CH3-4-CF2CF3
168.7-171.3


76
i-C3H7
H
H
6-CH3
2-CH3-4-CF2CF3
177-179


77
CH2CH2OC2H5
H
H
3-I
2-CH3-4-CF2CF3
146.5-150.3


78
CH2CH2OC2H5
H
H
6-I
2-CH3-4-CF2CF3
157.3-160.4


79
c-C5H9
H
H
6-I
2-CH3-4-CF2CF3
205.2


80
c-C6H11
H
H
6-I
2-CH3-4-CF2CF3
239.0-244.4


81
i-C3H7
H
H
3-I
4-SCF3
226-227


82
i-C3H7
H
H
3-NO2
4-SOCF3
202-205


83
i-C3H7
H
H
3-Cl
4-SOCF3
242-244


84
i-C4H9
H
H
3-I
2-CH3-4-CF2CF3
200.4-206.8


85
s-C4H9
H
H
6-I
2-CH3-4-CF2CF3
216.1-218.0


86
CH(C2H5)—CH2OCH3
H
H
3-I
2-CH3-4-CF2CF3
177


88
CH(C2H5)—CH2OCH3
H
H
6-I
2-CH3-4-CF2CF3
198.3-201.0


89
CH2CF3
H
H
6-I
2-CH3-4-CF2CF3
184.7-202.5


90
i-C3H7
H
H
3-I
3-N═C(CF2CF3)O-4
214-216


91
t-C4H9
H
H
3-I
3-N═C(CF2CF3)O-4
253-254


92
i-C3H7
H
H
3-Cl
2-F-4-OCF3
126-128


93
i-C3H7
H
H
3-I
2-F-4-OCF3
220-222


94
i-C3H7
H
H
3-I
2-C2H5-4-OCF3
241-243


95
t-C4H9
H
H
3-I
2-C2H5-4-OCF3
224-225


96
i-C3H7
H
H
3-Cl-4-F
2-CH3-4-OCF3
184-186


97
i-C3H7
H
H
3-Cl-4-F
2-CH3-4-CF(CF3)2
200-201


98
i-C3H7
H
H
5-I
2-CH3-4-OCF2CHF2
203-204


99
i-C3H7
H
H
4-I
2-CH3-4-CF(CF3)2
215-216


100
i-C3H7
H
H
3-I
2-CH3-4-C≡C—C4H9-t
205


101
i-C3H7
H
H
3-Cl
2-CH3-4-CN
230


102
i-C3H7
H
H
3-I
2-F-4-C2F5
190


103
i-C3H7
H
H
3-I
2-Cl-4-C2F5
200


104
i-C3H7
H
H
3-I
2-CF3-4-C2F5
255


105
i-C3H7
H
H
3-I
2-OCH3-4-C2F5
152


106
2-TetFur
H
H
3-Cl
2-CH3-4-C2F5
153


107
2-TetFur
H
H
6-Cl
2-CH3-4-C2F5
130


108
CH2-4-Pyi
H
H
3-Cl
2-CH3-4-C2F5
 88


109
CH2-4-Pyi
H
H
6-Cl
2-CH3-4-C2F5
Paste


110
i-C3H7
H
H
3-I
2-C2F5-4-C2F5
245


111
i-C3H7
H
H
H
4-O-(2-Pym)
246


112
C(CH3)2CH2CH3
H
H
3-I
2-CH3-4-C2F5
193


113
C(CH3)2CH2CH3
H
H
3-I
2-CH3-4-OCF3
180


114
C(CH3)2CH2CH3
H
H
3-I
2-CH3-4-OCHF2
176-177


115
i-C3H7
H
H
3-I
2-Cl-4-OCF2O-5
226


116
i-C3H7
H
H
3-I
2-Cl-3-OCF2CF2O-4
219


117
C(CH3)2CH2Cl
H
H
3-I
2-CH3-4-C2F5
168-169


118
i-C3H7
H
H
3-I
4-(2-CH3-4-Thz)
217


119
i-C3H7
H
H
3-I
4-(2-CH3-4-Oxa)
212


120
i-C3H7
H
H
3-I
4-(2-i-C3H7-4-Thz)
199


121
CH(CH3)-2-Pyi
H
H
3-I
2-CH3-4-OCF3
158-161


122
N(Ph)COCF3
H
H
3-I
2-CH3-4-C2F5
239-241


123
CH(CH3)2Fur
H
H
3-I
2-CH3-4-C3F7-i
191


124
CH(CH3)-2-Thi
H
H
3-I
2-CH3-4-C3F7-i
159


125
i-C3H7
H
H
3-CF3SO
2-CH3-4-C3F7-i
211-213


126
t-C4H9
H
H
3-I
2-N═C(CF3)O-3
120


127
i-C3H7
H
H
3-I
2-CH3-4-C(CH3)═NOCH3
218


128
t-C4H9
H
H
6-CF3S
2-CH3-4-C3F7-i
245-247


129
C(CH3)2CH2SCH3
H
H
3-I
2-CH3-4-C3F7-i
205-206


130
C(CH3)2CH2SO2CH3
H
H
3-I
2-CH3-4-C3F7-i
90-95


131
C(CH3)2CH2SOCH3
H
H
3-I
2-CH3-4-C3F7-i
88-90


132
CH(CH3)CH2SCH3
H
H
3-I
2-CH3-4-C3F7-i
197-199


133
CH(CH3)CH2SO2CH3
H
H
3-I
2-CH3-4-C3F7-i
 82


134
CH(CH3)CH2SOCH3
H
H
3-I
2-CH3-4-C3F7-i
134


135
C(CH3)2CH2SCH3
H
H
3-I
2-Cl-4-OCF3
166


136
C(CH3)2CH2SO2CH3
H
H
3-I
2-Cl-4-OCF3
141


137
C(CH3)2CH2SO2CH3
H
H
3-Br
2-Cl-4-OCF3
133


138
C(CH3)2CH2SC2H5
H
H
3-I
2-CH3-4-C2F5
188-189


139
C(CH3)2CH2SO2C2H5
H
H
3-I
2-CH3-4-C2F5
120-122


140
C(CH3)2CH2SOC2H5
H
H
3-I
2-CH3-4-C2F5
125-126


141
C(CH3)2CH2SCH3
H
H
3-Cl
2-CH3-4-C3F7-i
199-200


142
CH(CH3)CH2SCH3
H
H
3-I
2-Cl-4-C3F7-i
190









In Table 1, “Ph” means a phenyl group, “c” means an alicyclic hydrocarbon group, “Pyi” means a pyridyl group, “Pym” means a pyrimidinyl group, “Fur” means a furyl group, “TetFur” means a tetrahydrofuryl group, “Thi” means a thienyl group, “Thz” means a thiazolyl group, and “Oxa” means an oxazolyl group.
As the compounds having an insecticidal, acaricidal or nematocidal activity, which the composition for noxious organisms-controlling agent of the present invention comprises, insecticidal compounds such as chloronicotinyl compounds, carbamate compounds, pyrethroid compounds, macrolide compounds, phosphorus compounds and the like can be referred to. Examples thereof include the following compounds indicated by their general names, however, the present invention is by no means limited by these compounds:
acetamiprid, pymetrozine, fenitrothion, acephate, carbaryl, methomyl, cartap, cyhalothrin, ethofenprox, teflubenzuron, flufenoxuron, tebufenozide, fenpyroximate, pyridaben, imidacloprid, buprofezin, BPMC (fenobucarb), malathion, methidathion, fenthion, diazinon, oxydeprofos, vamidothion, ethiophencarb, pirimicarb, permethrin, cypermethrin, bifenthrin, halfenprox, silafluofen, nitenpyram, chlorfluazuron, methoxyfenozide, tebufenpyrad, pyrimidifen, dicofol, propargite, hexythiazox, clofentezine, spinosad, milbemectin, BT (bacillus thuringiensis), indoxacarb, chlorfenapyr, fipronil, etoxazole, acequinocyl, pirimiphos-methyl, acrinathrin, quinomethionate, chlorpyrifos, avermectin, emamectin-benzoate, fenbutatin oxide, terbufos, ethoprophos, cadusafos, fenamiphos, fensulfothion, DSP, dichlofenthion, fosthiazate, oxamyl, isamidofos, fosthietan, isazofos, thionazin, benfuracarb, spirodiclofen, ethiofencarb, azinphos-methyl, disulfoton, methiocarb, oxydemeton-methyl, parathion, cyfluthrin, beta-cyfluthrin, tebupyrimfos, spiromesifen, endosulfan, amitraz, tralomethrin, acetoprole, ethiprole and the like.
Further, it is also possible to use the compounds mentioned above in combination with insecticides, acaricides and nematocides having the following general names or chemical names, or those disclosed in the following Patent Kokai gazettes, etc.:
ethion, trichlorfon (DEP), metamidophos, dichlorvos (DDVP), mevinphos, monocrotophos, dimethoate, formothion, mecarbam, thiometon, disulfoton, naled (BRP), methylparathion, cyanophos, diamodafos, albendazole, oxibendazole, fenbendazole, oxfendazole, propaphos, sulprofos, prothiofos, profenofos, isophenphos, temephos, phenthoate, dimethylvinphos, chlorfenvinphos, tetrachlorvinphos, phoxim, isoxathion, pyraclofos, chlorpyrifos-methyl, pyridafenthion, phosalone, phosmet, dioxabenzofos, quinalphos, pyrethrins, allethrin, prallethrin, resmethrin, permethrin, tefluthrin, fenpropathrin, alpha-cypermethrin, lambda-cyhalothrin, deltamethrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, cycloprothrin, thiodicarb, aldicarb, alanycarb, metolcarb, xylylcarb, propoxur, fenoxycarb, fenothiocarb, bifenazate, carbofuran, carbosulfan, furathiocarb, diafenthiuron, diflubenzuron, hexaflumuron, novaluron, lufenuron, chlorfluazuron, cyhexatin, Oleic acid sodium salt, Potassium oleate, methoprene, hydroprene, binapacryl, amitraz, chlorobenzilate, brompropylate, tetradifon, bensultap, benzoximate, chromafenozide, endosulfan, diofenolan, tolfenpyrad, triazamate, nicotine-sulfate, thiacloprid, thiamethoxam, clothianidin, dinotefuran (MT I-446), fluazinam, pyriproxyfen, hydramethylnon, cyromazine, TPIC (tripropylisocyanurate), thiocyclam, fenazaquin, polynactins, azadirachtin, rotenone, Hydroxy propyl starch, mesulfenfos, phosphocarb, isoamidofos, aldoxycarb, metam-sodium, morantel tartrate, dazomet, levamisol, trichlamide, pyridalyl, 2-[2-(4-cyanophenyl)-1-(3-trifluoromethylphenyl)-ethylidene]-N-(4-trifluoromethoxyphenyl)hydrazine carboxamide and its E isomer, its Z isomer, and mixtures of E and Z isomers at arbitrary mixing ratios, and the substituted aminoquinazolinone (thion) derivatives or salts thereof disclosed in JP-A-8-325239 and Japanese Patent Application 2000-334700, etc.
When the phthalamide derivative specified by the present invention is combined with the second active ingredient of the present invention, namely one or more compounds selected from the compounds having an insecticidal, acaricidal or nematocidal activity and the composition thus obtained is used as a composition for noxious organisms-controlling agent, the amount of the active ingredient compounds in 100 parts by weight of the composition may be appropriately selected from a range of 0.1-50 parts by weight and preferably 1-20 parts by weight. In the active ingredient compounds, the ratio between the specified phthalamide and the one or more compounds selected from the compounds having an insecticidal, acaricidal or nematocidal activity may be appropriately selected from a range of 0.05-2,000 parts by weight and preferably 10-100 parts by weight of the one or more compounds having an insecticidal, acaricidal or nematocidal activity, per one part by weight of the specified phthalamide derivative.
When the composition for noxious organisms-controlling agent of the present invention is put to use, the composition is used in an appropriate solid, liquid or powdery form prepared according to the conventional method in the pesticide making. According to the need, adjuvants and the like are added to the composition at an appropriate ratio. The mixture is subjected to melting, suspending, mixing, impregnation, adsorption or adhesion, and then formed into an appropriate preparation form such as emulsion, powder, granule, wettable powder, flowable composition, etc. according to the purpose, and put to use.
The composition for noxious organisms-controlling agent of the present invention is suitable for controlling various agricultural, forestry and horticultural pests making harm to paddyfield rice plants, vegetables, fruit plants, flowers and ornamental plants and the like; pests making injury on stored grain; sanitary insect pests; nematodes, etc. As examples of the pests, the following can be referred to:
pests belonging to HETEROPTERA of HEMIPTERA such as plataspid bug (Megacopta punctatissimum), whitespotted larger spined bug (Eysarcoris lewisi), whitespotted bug (Eysarcoris parvus), southern green stink bug (Nezara viridula), brownwinged green bug (Plautia stali), narrow squash bug (Cletus puctiger), rice bug (Leptocorisa chinensis), bean bug (Riptortus clavatus), rice leaf bug (Togo hemipterus), pear lace bug (Stephanitis nashi), azelea lace bug (Stephanitis pyrioides), pale green plant bug (Apolygus spinolai), sorghum plant bug (Stenotus rubrovittalus), rice leaf bug (Trigonotylus coelestialium), etc.;
pests belonging to HOMOPTERA such as grape leafhopper (Arboridia apicalis), tea green leafhopper (Empoasca onukii), green rice leafhopper (Nephotettix cincticeps), green rice leafhopper (Nephotettix virescens), small brown planthopper (Laodelphax striatellus), brown rice planthopper (Nilaparvata lugens), whitebacked rice planthopper (Sogatella furcifera), citrus psylla (Diaphorina citri), citrus spiny whitefly (Aleurocanthus spiniferus), silver leaf whitefly (Bemisia argentifolli), sweetpotato whitefly (Bemisia tabaci), citrus whitefly (Dialeurodes citri), greenhouse whitefly (Trialeurodes vaporariorum), grapeleaf louse (Viteus vitifolli), woolly apple aphid (Eriosoma lanigerum), spiraea aphid (Aphis citricola), cowpea aphid (Aphis craccivora), cotton aphid (Aphis gossipii), greenhouse-potato aphid (Aulacorthum solani), cabbage aphid (Brevicoryne brassicae), potato aphid (Macrosiphum euphorbiae), green-peach aphid (Myzus persicae), oat bird-cherry aphid (Rhopalosiphum padi), japanese grain aphid (Sitobion akebiae), comstock mealybug (Pseudococcus comstocki), Indian wax scale (Ceroplastes ceriferus), red scale (Aonidiella aurantii), San Jose scale (Comstockaphis perniciosa), mulberry scale (Pseudaulacapsis pentagoa), arrowedhead scale (Unaspis yanonensis), etc.;
pests belonging to LEOPIDOPTERA such as summer fruit fortrix (Adoxophyes orana fasciata), smaller tea tortrix (Adoxophyes honmai), apple tortrix (Archips fuscocupreanus), peach fruit moth (Carposina niponensis), oriental fruit moth (Grapholita molesta), oriental tea tortrix (Homona magnanima), tea leafroller (Caloptilia theivora), mugwort looper (Ascotis selenaria), grape berry moth (Endopiza viteana), codling moth (Laspeyresia pomonella), apple leafminer (Phyllonorycter ringoniella), apple leaf miner (Lyonetia prunifoliella malinella), citrus leafminer (Phyllocnistis citrella), diamondback moth (Plutella xylostella), pink bollworm (Pectinophora gossypiella), peach fruit moth (Carposina niponensis), rice stem borer (Chilo supperssalis), yellow rice borer (Scirpophaga incertulas), rice leafroller (Cnaphalocrosis medinalis), cabbage webworm (Hellulla undalis), Chinese yellow swallowtail (Papilio xuthus), common white (Pieris rapae crucivora), tent catapillar (Malacosoma neustria testacea), fall webworm (Hyphantria cunea), bluegrass webworm (Parapediasia tererrella), corn earworm (Helicoverpa armigera), Heliothis (Heliothis spp.), cutworm (Agrotis segetum), beet semi-looper (Autographa nigrisigna), cabbage armyworm (Mamestra brassicae), beat armyworm (Spodoptera exigua), common cutworm (Spodoptera litura), etc.;
pests belonging to COLEOPTERA such as cupreous chafer (Anomala cuprea), Japanese beetle (Popillia japonica), powderpost beetle (Lyctus brunneus), confused flour beetle (Tribolium confusum), twenty-eight-spotted ladybird (Epilachna vigintioctopunctata), whitespotted longicorn beetle (Anoplophora malasiaca), Japanese pine sawyer (Monochamus alteratus), azuki bean weevil (Callosobruchus chinensis), cucurbit leaf beetle (Aulacophora femoralis), rootworm (Diabrotica spp.), boll weevil (Anthonomus grandis grandis), Mexican beetle (Epilachna varivestis), Colorado leaf beetle (Leptinotarsa decemlineata), rice water weevil (Lissorhoptrus oryzophylus), rice leaf beetle (Oulema oryzae), hunting billbug (Sphenophrus venatus vestitus), etc.;
pests belonging to HYMENOPTERA such as cabbage sawfly (Athalia rosae ruficornis), rose argid sawfly (Arge pagana), Formica japonica, etc.;
pests belonging to DIPTERA such as rice leafminer (Agromyza oryzae), rice leafminer (Hydrellia griseola), legume leafminer (Liriomyza trifolii), onion maggot (Delia antiqua), house fly (Musca domestica), Culex pipiens molestus, house mosquito (Culex pipiens pallens), etc.;
pests belonging to THYSANOPTERA such as yellow tea thrips (Scirtothrips dorsalis), southern yellow thrips (Thrips palmi), onion thrips (Thrips tabaci), cirtus yellow thrips (Frankliniella occidentalis), etc.;
pests belonging to ISOPTERA such as Formosan subterranean termites (Coptotermes formosanus), japanese subterranean termite (Reticulitermes speratus), booklice (Psocoptera), Liposcelis bostrychophilus, etc.; 
pests belonging to ORTHOPTERA such as rice grasshopper (Oxya yezoensis), mole crichet (Gryllotalpa sp.), American cockroach (Periplaneta americana), German cockroach (Blattella germanica), etc.;
pests belonging to ACARINA such as citrus red mite (Panonychus citri), fruit tree red spider mite (Panonychus ulmi), two-spotted spider mite (Tetranychus urticae), Kanzawa spider mite (Tetranychus kanzawai), southern false spider mite (Brevipalpus phoenicis), clover mite (Bryobia praetiosa), pink citrus rust mite (Aculops pelekassi), japanese pear rust mite (Eriophyes chibaensis), broad mite (Polyphagotarsonemus latus), bulb mite (Rhizoglyphus robini), mold mite (Tyrophagus putrescentiae), etc.;
pests belonging to TYLENCHIDA such as coffee root-lesion nematode (Pratylenchus coffeae), Cobb root-lesion nematode (Pratylenchus penetrans), potato cyst nematode (Globodera rostochiensis), southern root-knot nematode (Meloidogyne incognita), etc.;
pests belonging to DOLYLAMIDA such as needle nematode (Longidorus sp.), etc.; and
pests belonging to GASTRPODA such as slug (Incilaria bilineata), etc.
The useful plants to which the composition for noxious organisms-controlling agent of the present invention can be applied are not particularly limited, and the following plants can be referred to as examples thereof:
cereals such as rice, barley, wheat, rye, oat, corn, etc.; beans and peas such as soybean, red bean, broad bean, pea, kidney-bean, peanut, etc.; fruit trees such as apple, citrus trees and fruits, pear, grape, peach, plum, cherry, walnut, chestnut, almond, banana, strawberry, etc.; leafy and fruit vegetables such as cabbage, tomato, spinach, broccoli, lettuce, onion, stone-leek, Spanish paprika, egg-plant, pepper, etc.; root crops such as carrot, potato, sweet potato, taro, radish, lotus rhizome, turnip, burdock, garlic, etc.; processing crops such as cotton, flax, beet, hop, sugar can, sugar beet, olive, gum, coffee, tobacco, tea, etc.; cucurbitaceous plants such as pumpkin, cucumber, musk melon, water melon, melon, etc.; pasture plants such as orchard grass, sorghum, timothy, clover, alfalfa, etc.; lawn grasses such as mascarenegrass, bent grass, etc.; perfumery crops such as lavender, rosemary, thyme, parsley, pepper, ginger, etc.; flowers and ornamental plants such as chrysanthemum, rose, carnation, orchid, etc.; garden-trees such as ginkgo tree, cherry tree, gold-leaf plant, etc.; and timber woods such as white fir, silver fir, pine, hatchet-leaved arbor-vitae, Japan cedar, Japanese eypress, etc.
In order to control various disease pests, the composition for noxious organisms-controlling agent of the present invention is applied to the plants on which appearance of the noxious organisms is expected, either as it is or in the form of a dilution or suspension in a proper quantity of water or the like at a dosage effective for the control of the noxious organisms. For instance, with the aim of controlling the appearance of noxious organisms on fruit trees, cereals and vegetables, the composition may be directly used for foliage treatment, or the composition may also be used for seed treatments such as immersion of seeds in the agent solution, seed coating, calper treatment or the like, or absorption from the root by soil treatment or the like, such as incorporation into total soil layer, row treatment, soil incorporation, cell seedling treatment, prickling-in-hole treatment, plant foot treatment, top dressing, nursery box application of rice, submerged application, etc. In addition, application of the composition to the nutrient solution in the water culture, the use by fumigation, and the injection into tree stalks, etc. are also usable.
Further, apart from the spraying treatment on stored grain pests, house pests, sanitary insect pests and forest pests, application to construction material of house, fumigation, bait, etc. are also adoptable.
As the method of treating seeds, a method of dipping seeds in a diluted or undiluted liquid preparation of the liquid or solid composition and thereby making the agent permeate into the seeds; a method of mixing a solid or liquid preparation with seeds for the sake of powder coating and thereby making the agent adhere to the seed surface; a method of mixing the preparation with an adhesive carrier such as resin, polymer or the like and coating seeds with such an adhesive mixture; a method of spraying the preparation to the neighborhood of seeds simultaneously with planting, etc. can be referred to.
The term “seed” to be treated with the composition of the present invention means a plant body of the initial stage of cultivation used for reproduction of plants, and involves not only the seeds but also plant bodies for nutrient reproduction such as bulb, tuber, seed tuber, aerial tuber, scaly bulb, stalks for cuttage, and the like.
The term “soil” or “cultivation carrier” for plants in the practice of the using method of the present invention means a support for use in culture of a plant and especially a support in which roots are to be grown. They are not limited in material quality, but any material may be used so far as a plant can be grown therein. For instance, so-called various soils, nursery mat, water and the like can be used. Specific examples of the material constituting the soil or cultivation carrier include sand, pumice, vermiculite, diatomaceous earth, agar, gelatinous materials, polymeric materials, rock wool, glass wool, wood chips, bark and the like.
As method for spraying the composition to foliage part of crops or stored grain pest, sanitary insect pest, forest pest, etc., a method of diluting a liquid preparation such as emulsifiable concentrate, flowable agent and the like or a solid preparation such as wettable preparation, granular wettable preparation and the like with water properly and spraying the dilution, a method of spraying a powdery composition, a method of fumigation, etc. can be referred to.
As method for applying the composition to the soil, a method of applying a liquid preparation either diluted or undiluted with water to the plant foot, nursery bed for raising seedlings or the like, a method of spraying a granular agent to the plant foot or nursery bed, a method of spraying a dust, a wettable powder, a wettable granule or a granular agent to the soil and mixing it with the whole soil either before seeding or before transplantation, a method of spraying a dust, a wettable powder, a wettable granule, a granular agent or the like to planting holes, planting rows, etc. can be referred to.
As method for applying the composition to a nursery box of paddyfield rice, a method of applying the composition in the form of dust, granular wettable powder, granule, etc. can be referred to, though the preparation form may vary depending on the time of application, namely whether the application is carried out in sowing period, greening period or transplanting period. It is also possible to apply the composition in the form of a mixture with soil, as in the form of mixture of soil and a dust, a granular wettable powder or a granule, according to a method of mixing into bed soil, covering soil, or the whole soil. It is also possible to apply the composition by merely making the soil and various preparations into layers.
For applying the composition of the present invention to a paddy field, a solid preparation such as jumbo-pack, granule, wettable granule, and the like or a liquid preparation such as flowable, emulsifiable concentrate and the like is scattered to a paddy field usually in a submerged state. Otherwise, it is also possible to scatter or inject an appropriate agent as it is or in the form of a mixture with fertilizers into soil at the time of transplantation. It is further possible to apply an emulsifiable concentrate to the water inlet or water flow source of irrigating system, by which the composition can be applied together with water supplied to the paddy field in a labor-saving manner.
In case of upland field crops, the composition of the present invention may be applied to the cultivation carrier surrounding the seeds or plant bodies in the period from the seeding to the seedling raising. In cases where plant seeds are directly sown to the field, the composition may directly be applied to seeds to make a seed coating, or may also be applied to the base of hills in the course of cultivation to achieve a successful result. It is also possible to scatter a granular preparation or to apply a liquid preparation after dilution with water or without dilution. Another preferable treatment is to mix a granular preparation with a cultivation carrier before seeding and to sow seeds thereafter.
In cases where cultured plants to be transplanted are treated at the seeding time or in the seedling raising period, it is preferable to treat the seeds directly, or to carry out an irrigating treatment of a seedling raising bed with a liquefied agent, or to carry out a powdering treatment thereof with a granular agent. Further, it is also preferable to apply a granular agent to the planting holes at the time of set-planting or to mix the agent into the cultivation carrier in the neighborhood of the sites of transplantation.
The composition for noxious organisms-controlling agent of the present invention may be put to use after forming it into a usual preparation form, such as emulsifiable concentrate, wettable powder, granular wettable powder, flowable preparation, solution, granule, dust, fumigant and the like. Although the dosage thereof varies depending on the content of active ingredient in the composition, climate conditions, preparation form, method of application, place of application, objective noxious organism to be controlled, objective crop plant, etc. The dosage may be appropriately selected from a range of 0.1 gram to 1,000 grams and preferably 1 gram to 500 grams in terms of weight of active ingredient, per are of the field. In the case of seed treatment, it is possible to use the composition in an amount of 0.01-50% and preferably in an amount of 0.1-10% in terms of weight of active ingredient, based on the weight of seed. In cases where an emulsifiable concentrate or a wettable powder is diluted with water and then put to use, the concentration at the time of application is 0.00001-0.1%. In the cases of a granular preparation, a dust, and a liquid composition to be applied to seeds, the composition is directly applied without dilution, usually.
For the purpose of controlling the diseases and/or the weeds which appear simultaneously with the time of the application of the composition for noxious organisms-controlling agent of the present invention, the second active ingredient of the present invention, namely the compound having an insecticidal, acaricidal or nematocidal activity, may be replaced with a compound having a fungicidal or herbicidal activity. By taking such a measure, the span of objective disease and pests to be controlled can be expanded and the dosage can be reduced, and the herbicidal effect can be increased synergistically. The same effect as above can be expected also by adding a compound having a fungicidal or herbicidal activity to the composition for noxious organisms-controlling agent of the present invention and putting the mixture thus obtained to use.
As said compound having a fungicidal or herbicidal activity, the following can be referred to.
Thus, examples of the compound having a fungicidal activity include azoxystrobin, diclocymet, pyroquilon, kasugamycin, IBP (iprobenfos), hymexazol, mepronil, tricyclazole, edifenphos, isoprothiolane, blasticidin, flutolanil, diclomezine, pencycuron, carbendazim, dodine, propamocarb, pyrimethanil, fluquinconazole, fosetyl-AL, bromoconazole, triticonazole, flumetover, fenamidone, tolylfluanid, dichlofluanid, trifloxystrobin, triadimenol, spiroxamine, fenhexamid, iprovalicarb, fthalide, iprodione, thiophanate, benomyl, triflumizole, fluazinam, zineb, captan, manzeb, fenarimol, calcium polysulfide, triadimefon, vinclozolin-, dithianon, bitertanol, polycarbamate, iminoctadine-DBS, pebulate, polyoxin-B, propineb, chinomethionat, dichlofluanid, chlorothalonil, difenoconazole, fluoroimide, triforine, oxadixyl, streptomycin, mancozeb, oxolinic acid, mepronil, metalaxyl, propiconazole, hexaconazole, sulfur, pyrifenox, basic copper sulfate, pyrimethanil, iprobenfos, tolclofos-methyl, maneb, thiophanate-methyl, thifluzamide, furametpyr, flusulfamide, kresoxim-methyl, carpropamid, hydroxyisoxazole, echlomezole, procymidone, vinclozolin, ipconazole, furconazole, myclobutanil, tetraconazole, tebuconazole, imibenconazole, prochloraz, pefurazoate, cyproconazole, mepanipyrim, thiadiazin, probenazole, acibenzolar-S-methyl, validamycin(-A), fenoxanil, N-(3-chloro-4-methylphenyl)-4-methyl-1,2,3-thiadiazole-5-carboxamide, etc.
Examples of the compound having a herbicidal activity include bensulfuron-methyl, azimsulfuron, cinosulfuron, cyclosulfamuron, pyrazosulfuron-ethyl, imazosulfuron, indanofan, cyhalofop-butyl, thenylchlor, esprocarb, etobenzanid, cafenstrole, clomeprop, dimethametryn, daimuron, bifenox, pyributicarb, pyriminobac-methyl, pretilachlor, bromobutide, benzofenap, benthiocarb, bentoxazone, benfuresate, mefenacet, fenoxaprop-P-ethyl, phenmedipham, diclofop-methyl, desmedipham, ethofumesate, isoproturon, amidosulfuron, anilofos, ethoxysulfuron, iodosulfuron, isoxadifen, foramsulfuron, pyraclonil-, mesosulfuron, diuron, neburon, dinoterb, carbetamide, bromoxynil, oxadiazon, dimefuron, diflufenican, aclonifen, benzofenap, oxaziclomefone, isoxaflutole, oxadiargyl, flurtamone, metribuzin, methabenzthiazuron, tribufos, metamitron, ethiozin, flufenacet, sulcotrion, fentrazamide, propoxycarbazone, flucarbazone, metosulam, amicarbazone, etc.
Further, it is also possible to mix the herbicides expressed by the following general names into the composition of this invention:
glyphosate-isopropyl amine, glyphosate-trimesium, glufosinate-ammonium, bialaphos, butamifos, prosulfocarb, asulam, linuron, calcium peroxide, alachlor, pendimethalin, acifluofen-sodium, lactofen, ioxynil-octanoate, alloxydim, sethoxydim, napropamide, pyrazolate, pyraflufen-ethyl, imazapyr, sulfentrazone, oxadiazon, paraquat, diquat, simazine, atrazine, fluthiacet-methyl, quizalofop-ethyl, bentazone (BAS-3510-H), triaziflam, etc.
Further, the composition of the present invention can be used in the form of a mixture with the following compounds having a plant growth regulating activity:
thidiazuron, mefenpyr, ethephon, cyclanilide, etc.
The composition of this invention can be used as a mixture with the following biotic pesticides to exhibit a similar effect:
viral preparations such as Nuclear polyhedrosis virus (NPV), Granulosis virus (GV), Cytoplastic polyhedrosis virus (CPV), Entomopox virus (EPV), etc.:
microbial pesticides used as insecticide or nematocide such as Monacrosporium phymatophagum, Steinernema caprocapsae, Steinernema kushidai, Pasteuria penetrans, etc.;
microbial pesticides used as fungicide such as Trichoderma lignorum, Agrobacterium radiobactor, Erwinia carotovora, Bacillus subtilis, monacrosporium.phamatophagum etc.; and
microial pesticides used as herbicide such as Xanthomonas capestris, etc.
Further, it is also possible to use the composition of the present invention in combination with the following biotic pesticides:
natural enemy organisms such as Parasitic wasp (Encarsia formosa), Parasitic wasp (Aphidius colemani), Gall-mildge (Aphidoletes aphidimyza), Parasitic wasp (Diglyphus isaea), Parasitic mite (Dacnusa sibirica), Predatory mite (Phytoseiulus persimilis), Predatory-mite (Amblyseius cucumeris), Predatory bug (Orius sauteri), etc.;
microbial pesticides such as Beauveria brongniartii), etc.; and
pheromones such as (Z)-10-tetradecenyl=acetate, (E,Z)-4,10-tetradecadienyl=acetate, (Z)-8-dodecenyl=acetate, (Z)-11-tetradecenyl=acetate, (Z)-13-icosen-10-one, (Z)-8-dodecenyl=acetate, (Z)-11-tetradecenyl=acetate, (Z)-13-icosen-10-one, 14-methyl-1-octadecene, etc.


EXAMPLES
Next, typical examples and test examples of the present invention are mentioned below. This invention is by no means limited by these examples. In the examples, the terms “part” and “parts” are both by weight.
Example 1
















Compound of Table 1
 5 parts



Fenpyroximate
10 parts



Silicic acid hydrate
30 parts



Hitenol N-08 (manufactured by
 5 parts



Daiichi Kogyo Seiyaku)



Calcium ligninsulfonate
 3 parts



Wettable clay
47 parts










After impregnating silicic acid hydrate with the active ingredient compounds, the silicic acid hydrate is uniformly blended with other ingredients to form a wettable powder composition.
Example 2
















Compound of Table 1
10 parts



Tebufenpyrad
10 parts



Sorpol 3105 (manufactured by
 5 parts



Toho Yakuhin Kogyo)



Propylene glycol
 5 parts



Rhodopol (manufactured by Rohne
 2 parts



Poulenc Inc.)



Water
68 parts










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Example 3
















Compound of Table 1
10 parts



Isoprothiolane
20 parts



SP-3005X (manufactured by Toho
15 parts



Kagaku)



Xylene
35 parts



N-Methylpyrrolidone
20 parts










The above-mentioned ingredients are uniformly mixed and melted to form an emulsifiable concentrate.
Example 4

















Compound of Table 1
10
parts



Tebufenozide
20
parts



Sorpol 3105
5
parts



Propylene glycol
2
parts



Rhodopol 23
1
part



Water
62
parts










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Example 5
















Compound of Table 1
10 parts



Buprofezin
 5 parts



Silicic acid hydrate
34 parts



Hitenol N-08
 3 parts



Demol T
 2 parts



Calcium carbonate powder
46 parts










After impregnating silicic acid hydrate with the active ingredient compounds, the silicic acid hydrate is uniformly blended with other ingredients to form a wettable powder composition.
Example 6
















Compound of Table 1
10 parts



Pyridaben
15 parts



SP-3005X
15 parts



Xylene
40 parts



N-Methylpyrrolidone
20 parts










The above-mentioned ingredients are uniformly mixed together and melted to form an emulsifiable concentrate.
Example 7

















Compound of Table 1
10
parts



Pyraflufen-ethyl
20
parts



Sorpol 3105
5
parts



Propylene glycol
2
parts



Rhodopol 23
0.5
part



Water
62.5
parts










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Example 8
















Compound of Table 1
10 parts 



Acetamiprid
5 parts



Sorpol 3105
5 parts



Propylene glycol
3 parts



Rhodopol
2 parts



Water
75 parts 










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Example 9
















Compound of Table 1
10 parts



Imidacloprid
10 parts



SP-3005X
15 parts



Xylene
45 parts



N-Methylpyrrolidone
20 parts










The above-mentioned ingredients are uniformly mixed together and melted to form an emulsifiable concentrate.
Example 10
















Compound of Table 1
5 parts



Chlorfenapyr
10 parts 



Sorpol 3105
5 parts



Propylene glycol
3 parts



Rhodopol 23
2 parts



Water
75 parts 










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Example 11
















Compound of Table 1
5 parts



Pymetrozine
10 parts 



Sorpol 3105
5 parts



Propylene glycol
3 parts



Rhodopol 23
2 parts



Water
75 parts 










The above-mentioned ingredients are uniformly mixed together and dispersed in water to form a flowable preparation.
Test Example 1
Insecticidal Test on Smaller Tea Tortrix (Adoxophyes orana fosciota)
Tea leaves were dipped in a solution of a chemical diluted to a prescribed concentration for 30 seconds. After air-dryness, the leaves were transferred to a plastic dish having a diameter of 9 cm, inoculated with ten 4th instar larvae of smaller tea tortrix, and left to stand in a thermostatted chamber at 25° C. Four days and seven days after the treatment, the number of alive insects were counted, from which percentage of death was calculated. The test was carried out with two replications of 10 insects. The results are shown in Table 2.









TABLE 2









Death rate



(%)












After
After



Concentration
4
7


Test agent
(ppm)
days
days














Compound
+ chlorpyriphos
0.3 + 1
35
75


19
+ chlorfluazuron
0.3 + 1
35
95



+ chlorfenapyr
0.3 + 1
30
75



+ emamectin-benzoate
  0.3 + 0.1
25
85



+ methoxyfenozide
  0.3 + 0.1
75
95



+ indoxacarb
0.3 + 1
55
95



+ fenpyroximate
 0.3 + 50
30
85


Compound
+ chlorpyriphos
0.3 + 1
20
45


20
+ chlorfluazuron
0.3 + 1
25
85



+ chlorfenapyr
0.3 + 1
20
75



+ emamectin-benzoate
  0.3 + 0.1
25
75



+ methoxyfenozide
  0.3 + 0.1
45
85



+ indoxacarb
0.3 + 1
45
75



+ fenpyroximate
 0.3 + 50
30
80


Compound
+ chlorpyriphos
0.3 + 1
15
45


39
+ chlorfluazuron
0.3 + 1
20
75



+ chlorfenapyr
0.3 + 1
15
70



+ emamectin-benzoate
  0.3 + 0.1
20
70



+ methoxyfenozide
  0.3 + 0.1
40
80



+ indoxacarb
0.3 + 1
40
70



+ fenpyroximate
 0.3 + 50
25
75


Compound
+ chlorpyriphos
0.3 + 1
20
45


40
+ chlorfluazuron
0.3 + 1
25
80



+ chlorfenapyr
0.3 + 1
15
70



+ emamectin-benzoate
  0.3 + 0.1
20
70



+ methoxyfenozide
  0.3 + 0.1
35
85



+ indoxacarb
0.3 + 1
35
75



+ fenpyroximate
 0.3 + 50
20
70


Compound
+ chlorpyriphos
0.3 + 1
40
80


41
+ chlorfluazuron
0.3 + 1
35
95



+ chlorfenapyr
0.3 + 1
30
75



+ emamectin-benzoate
  0.3 + 0.1
30
100



+ methoxyfenozide
  0.3 + 0.1
75
95



+ indoxacarb
0.3 + 1
55
95



+ fenpyroximate
 0.3 + 50
35
90


Compound
+ chlorpyriphos
0.3 + 1
45
85


42
+ chlorfluazuron
0.3 + 1
35
100



+ chlorfenapyr
0.3 + 1
30
85



+ emamectin-benzoate
  0.3 + 0.1
30
100



+ methoxyfenozide
  0.3 + 0.1
75
95



+ indoxacarb
0.3 + 1
55
95



+ fenpyroximate
 0.3 + 50
30
85


Compound
+ chlorpyriphos
0.3 + 1
45
85


43
+ chlorfluazuron
0.3 + 1
35
95



+ chlorfenapyr
0.3 + 1
30
85



+ emamectin-benzoate
  0.3 + 0.1
30
100



+ methoxyfenozide
  0.3 + 0.1
75
95



+ indoxacarb
0.3 + 1
50
95



+ fenpyroximate
 0.3 + 50
35
90


Compound
+ chlorpyriphos
0.3 + 1
25
65


44
+ chlorfluazuron
0.3 + 1
30
85



+ chlorfenapyr
0.3 + 1
25
80



+ emamectin-benzoate
  0.3 + 0.1
25
75



+ methoxyfenozide
  0.3 + 0.1
45
90



+ indoxacarb
0.3 + 1
45
80


Compound
+ chlorpyriphos
0.3 + 1
30
75


45
+ chlorfluazuron
0.3 + 1
25
90



+ chlorfenapyr
0.3 + 1
20
75



+ emamectin-benzoate
  0.3 + 0.1
30
80



+ methoxyfenozide
  0.3 + 0.1
35
85



+ indoxacarb
0.3 + 1
35
75


Compound
+ chlorpyriphos
0.3 + 1
20
65


46
+ chlorfluazuron
0.3 + 1
35
80



+ chlorfenapyr
0.3 + 1
20
75



+ emamectin-benzoate
  0.3 + 0.1
25
85



+ methoxyfenozide
  0.3 + 0.1
35
85



+ indoxacarb
0.3 + 1
40
75


Compound
+ chlorpyriphos
0.3 + 1
40
80


47
+ chlorfluazuron
0.3 + 1
40
95



+ chlorfenapyr
0.3 + 1
35
95



+ emamectin-benzoate
  0.3 + 0.1
40
95



+ methoxyfenozide
  0.3 + 0.1
75
100



+ indoxacarb
0.3 + 1
45
90



+ fenpyroximate
 0.3 + 50
35
95


Compound
+ chlorpyriphos
0.3 + 1
25
75


48
+ chlorfluazuron
0.3 + 1
35
85



+ chlorfenapyr
0.3 + 1
35
80



+ emamectin-benzoate
  0.3 + 0.1
30
90



+ methoxyfenozide
  0.3 + 0.1
40
75



+ indoxacarb
0.3 + 1
35
80


Compound
+ chlorpyriphos
0.3 + 1
30
80


54
+ chlorfluazuron
0.3 + 1
25
85



+ chlorfenapyr
0.3 + 1
30
85



+ emamectin-benzoate
  0.3 + 0.1
30
95



+ methoxyfenozide
  0.3 + 0.1
35
80



+ indoxacarb
0.3 + 1
30
85


Compound
+ chlorpyriphos
0.1 + 1
35
75


129
+ chlorfluazuron
0.1 + 1
35
95



+ chlorfenapyr
0.1 + 1
30
75



+ emamectin-benzoate
  0.1 + 0.1
25
85



+ methoxyfenozide
  0.1 + 0.1
75
95



+ indoxacarb
0.1 + 1
55
95



+ fenpyroximate
 0.1 + 50
30
85


Compound
+ chlorpyriphos
0.1 + 1
35
75


130
+ chlorfluazuron
0.1 + 1
35
95



+ chlorfenapyr
0.1 + 1
30
75



+ emamectin-benzoate
  0.1 + 0.1
25
85



+ methoxyfenozide
  0.1 + 0.1
75
95



+ indoxacarb
0.1 + 1
55
95



+ fenpyroximate
 0.1 + 50
30
85


Compound
+ chlorpyriphos
0.1 + 1
35
75


131
+ chlorfluazuron
0.1 + 1
35
95



+ chlorfenapyr
0.1 + 1
30
75



+ emamectin-benzoate
  0.1 + 0.1
25
85



+ methoxyfenozide
  0.1 + 0.1
75
95



+ indoxacarb
0.1 + 1
55
95



+ fenpyroximate
 0.1 + 50
30
85


Compound 19

0.3
0
30


Compound 20

0.3
0
25


Compound 39

0.3
0
20


Compound 40

0.3
0
25


Compound 41

0.3
0
30


Compound 42

0.3
0
30


Compound 43

0.3
0
35


Compound 44

0.3
0
20


Compound 45

0.3
0
25


Compound 46

0.3
0
15


Compound 47

0.3
0
30


Compound 48

0.3
0
25


Compound 54

0.3
0
25


Compound 129

0.1
10
30


Compound 130

0.1
10
25


Compound 131

0.1
5
20


chlorpyriphos

1
10
10


chlorfluazuron

1
10
30


chlorfenapyr

1
0
0


emamectin-

0.1
10
45


benzoate


methoxyfenozide

0.1
0
50


indoxacarb

1
10
40


fenpyroximate

50
0
0


Untreated plot

—
0
0









Test Example 2
Insecticidal Test on Green Peach Aphid (Myzus persicae)
Chinese cabbage plants (variety: Aichi) were planted in plastic pots having a diameter of 8 cm and a height of 8 cm, on which green peach aphids were inoculated. Then, a solution of an agent which had been diluted to a predetermined concentration was thoroughly sprayed to the leaves and stalks. After air-dryness, the pots were left to stand in a green house. Six days after the spraying treatment, the number of the insects parasitic on each Chinese cabbage plant was counted, from which the control value was calculated according to the following equation. The test was carried out with two replications on one pot per one plot.

Controlling value=100−{(Ta×Cb)/(Tb×Ca)}×100

    
    
        Ta: Number of parasitic insects after spraying in the treated plot
        Tb: Number of parasitic insects before spraying in the treated plot
        Ca: Number of parasitic insects after spraying in the untreated plot
        Cb: Number of parasitic insects before spraying in the untreated plot
    
    


The results are shown in Table 3.












TABLE 3










Control





Concentration
degree



Test agent

(ppm)
(%)





















Compound 19
+ Acephate
100 + 10
81




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
43




+ pyridaben
100 + 10
92




+ milbemectin
100 + 1
100



Compound 20
+ Acephate
100 + 10
81




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
52




+ pyridaben
100 + 10
92




+ milbemectin
100 + 1
94



Compound 39
+ Acephate
100 + 10
83




+ imidacloprid
100 + 0.1
97




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
48




+ pyridaben
100 + 10
92




+ milbemectin
100 + 1
94



Compound 40
+ Acephate
100 + 10
86




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
48




+ pyridaben
100 + 10
92




+ milbemectin
100 + 1
100



Compound 41
+ Acephate
100 + 10
95




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
60




+ pyridaben
100 + 10
88




+ milbemectin
100 + 1
98



Compound 42
+ Acephate
100 + 0
95




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
55




+ pyridaben
100 + 10
90




+ milbemectin
100 + 1
100



Compound 43
+ Acephate
100 + 10
90




+ imidacloprid
100 + 0.1
95




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
60




+ pyridaben
100 + 10
85




+ milbemectin
100 + 1
100



Compound 44
+ Acephate
100 + 10
75




+ imidacloprid
100 + 0.1
80




+ bifenthrin
100 + 0.1
95




+ flufenoxuron
100 + 50
55




+ pyridaben
100 + 10
73




+ milbemectin
100 + 1
93



Compound 45
+ Acephate
100 + 10
70




+ imidacloprid
100 + 0.1
78




+ bifenthrin
100 + 0.1
93




+ flufenoxuron
100 + 50
61




+ pyridaben
100 + 10
78




+ milbemectin
100 + 1
98



Compound 46
+ Acephate
100 + 10
65




+ imidacloprid
100 + 0.1
75




+ bifenthrin
100 + 0.1
94




+ flufenoxuron
100 + 50
55




+ pyridaben
100 + 10
68




+ milbemectin
100 + 1
95



Compound 47
+ Acephate
100 + 10
78




+ imidacloprid
100 + 0.1
88




+ bifenthrin
100 + 0.1
94




+ flufenoxuron
100 + 50
58




+ pyridaben
100 + 10
75




+ milbemectin
100 + 1
94



Compound 48
+ Acephate
100 + 10
66




+ imidacloprid
100 + 0.1
93




+ bifenthrin
100 + 0.1
96




+ flufenoxuron
100 + 50
48




+ pyridaben
100 + 10
75




+ milbemectin
100 + 1
90



Compound 54
+ Acephate
100 + 10
65




+ imidacloprid
100 + 0.1
92




+ bifenthrin
100 + 0.1
89




+ flufenoxuron
100 + 50
55




+ pyridaben
100 + 10
73




+ milbemectin
100 + 1
95



Compound 129
+ Acephate
100 + 10
85




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
45




+ pyridaben
100 + 10
90




+ milbemectin
100 + 1
100



Compound 130
+ Acephate
100 + 10
87




+ imidacloprid
100 + 0.1
100




+ bifenthrin
100 + 0.1
100




+ flufenoxuron
100 + 50
54




+ pyridaben
100 + 10
96




+ milbemectin
100 + 1
95



Compound 131
+ Acephate
100 + 10
81




+ imidacloprid
100 + 0.1
99




+ bifenthrin
100 + 0.1
97



Compound 19

100
0



Compound 20

100
0



Compound 39

100
0



Compound 40

100
0



Compound 41

100
0



Compound 42

100
0



Compound 43

100
0



Compound 44

100
0



Compound 45

100
0



Compound 46

100
0



Compound 47

100
0



Compound 48

100
0



Compound 54

100
0



Compound 129

100
5



Compound 130

100
10



Compound 131

100
0



acephate

 10
48



imidacloprid

 0.1
69



bifenthrin

 0.1
80



flufenoxuron

 50
11



pyridaben

 10
43



milbemectin

 1
82










Test Example 3
Insecticidal Test on Brown Rice Planthopper (Nilaparvata lugens)
Rice seedlings (variety: Nihombare) were dipped in a solution of an agent diluted to a predetermined concentration for 30 seconds. After air-dryness, each seedling was introduced into a glass-made test tube having a diameter of 1.8 cm and a height of 20 cm, and inoculated with ten 3rd inster nimphs of brown rice planthopper. Then, the test tube was stoppered with cotton. One day after and four days after the treatment, the number of alive insects was counted, based on which the insect death rate was calculated. The test was carried out with two replications of 10 heads.
The results are shown in Table 4.









TABLE 4









Death rate



(%)











Concentration
After
After


Test agent
(ppm)
1 days
5 days














Compound 19
+ buprofezin
100 + 0.3
15
75



+ pymetrozin
100 + 100
20
85



+ silafluofen
100 + 1
95
100



+ imidacloprid
100 + 0.1
85
100


Compound 20
+ buprofezin
100 + 0.3
10
80



+ pymetrozin
100 + 100
25
90



+ silafluofen
100 + 1
85
90



+ imidacloprid
100 + 0.1
65
95


Compound 39
+ buprofezin
100 + 0.3
15
70



+ pymetrozin
100 + 100
30
85



+ silafluofen
100 + 1
85
85



+ imidacloprid
100 + 0.1
65
95


Compound 40
+ buprofezin
100 + 0.3
20
75



+ pymetrozin
100 + 100
25
90



+ silafluofen
100 + 1
90
95



+ imidacloprid
100 + 0.1
75
95


Compound 41
+ buprofezin
100 + 0.3
15
100



+ pymetrozin
100 + 100
30
90



+ silafluofen
100 + 1
85
95



+ imidacloprid
100 + 0.1
85
100


Compound 42
+ buprofezin
100 + 0.3
25
100



+ pymetrozin
100 + 100
35
95



+ silafluofen
100 + 1
85
95



+ imidacloprid
100 + 0.1
90
100


Compound 43
+ buprofezin
100 + 0.3
30
100



+ pymetrozin
100 + 100
40
95



+ silafluofen
100 + 1
90
100



+ imidacloprid
100 + 0.1
90
100


Compound 44
+ buprofezin
100 + 0.3
15
95



+ pymetrozin
100 + 100
25
95



+ silafluofen
100 + 1
75
80



+ imidacloprid
100 + 0.1
80
95


Compound 45
+ buprofezin
100 + 0.3
20
95



+ pymetrozin
100 + 100
30
100



+ silafluofen
100 + 1
80
80



+ imidacloprid
100 + 0.1
85
90


Compound 46
+ buprofezin
100 + 0.3
15
80



+ pymetrozin
100 + 100
25
90



+ silafluofen
100 + 1
75
75



+ imidacloprid
100 + 0.1
70
75


Compound 47
+ buprofezin
100 + 0.3
20
75



+ pymetrozin
100 + 100
30
85



+ silafluofen
100 + 1
65
70



+ imidacloprid
100 + 0.1
70
85


Compound 48
+ buprofezin
100 + 0.3
25
85



+ pymetrozin
100 + 100
35
90



+ silafluofen
100 + 1
70
75



+ imidacloprid
100 + 0.1
75
80


Compound 54
+ buprofezin
100 + 0.3
15
75



+ pymetrozin
100 + 100
30
75



+ silafluofen
100 + 1
65
65



+ imidacloprid
100 + 0.1
80
88


Compound 129
+ buprofezin
100 + 0.3
15
80



+ pymetrozin
100 + 100
15
90



+ silafluofen
100 + 1
90
100



+ imidacloprid
100 + 0.1
85
100


Compound 130
+ buprofezin
100 + 0.3
20
85



+ pymetrozin
100 + 100
25
90



+ silafluofen
100 + 1
90
95



+ imidacloprid
100 + 0.1
90
95


Compound 131
+ buprofezin
100 + 0.3
25
85



+ pymetrozin
100 + 100
20
85



+ silafluofen
100 + 1
95
100



+ imidacloprid
100 + 0.1
85
100


Compound 19

100
0
0


Compound 20

100
0
0


Compound 39

100
0
0


Compound 40

100
0
0


Compound 41

100
0
0


Compound 42

100
0
0


Compound 43

100
0
0


Compound 44

100
0
0


Compound 45

100
0
0


Compound 46

100
0
0


Compound 47

100
0
0


Compound 48

100
0
0


Compound 54

100
0
0


Compound 129

100
0
0


Compound 130

100
0
0


Compound 131

100
0
0


buprofezin

 0.3
0
45


pymetrozin

100
10
40


silafluofen

 1
30
30


imidacloprid

 0.1
35
35


Untreated plot

—
0
5









Test Example 4
Insecticidal Test on Resistant Strain of Two-Spotted Spider Mite
A plastic-made cup having a diameter of 8 cm was filled with water and covered with a lid having a hole having a diameter of 1 cm. A notched filter paper was placed over the lid, and a part of the filter paper was hung down from the lid into the water to maintain the filter paper always in a wet state by the capillary phenomenon.
A leaf disk prepared from the first leaves of kidney bean (variety: Topcrop) was placed on the filter paper, and inoculated with 10 female adults of resistant strain of two-spotted spider mite. On a turn table, 50 ml of an agent solution diluted to a predetermined concentration was uniformly sprayed. After the spraying treatment, the whole was left to stand in a thermostatted chamber at 25° C.
Two days after the spraying treatment, the number of alive spider mites were counted, based on which the spider mites death rate were calculated. The test was carried out with two replications of 10 adults. The results are shown in Table 5.









TABLE 5







Death



Concentration
rate


Test agent
(ppm)
(%)


















Compound 19
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
90



+ halfenprox
100 + 100
85


Compound 20
+ tebufenpyrad
100 + 100
90



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
90


Compound 39
+ tebufenpyrad
100 + 100
85



+ fenbutatin oxide
100 + 100
75



+ halfenprox
100 + 100
90


Compound 40
+ tebufenpyrad
100 + 100
85



+ fenbutatin oxide
100 + 100
90



+ halfenprox
100 + 100
95


Compound 41
+ tebufenpyrad
100 + 100
90



+ fenbutatin oxide
100 + 100
95



+ halfenprox
100 + 100
85


Compound 42
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
90



+ halfenprox
100 + 100
90


Compound 43
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
90



+ halfenprox
100 + 100
95


Compound 44
+ tebufenpyrad
100 + 100
85



+ fenbutatin oxide
100 + 100
95



+ halfenprox
100 + 100
90


Compound 45
+ tebufenpyrad
100 + 100
75



+ fenbutatin oxide
100 + 100
80



+ halfenprox
100 + 100
75


Compound 46
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
90



+ halfenprox
100 + 100
80


Compound 47
+ tebufenpyrad
100 + 100
85



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
75


Compound 48
+ tebufenpyrad
100 + 100
90



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
95


Compound 54
+ tebufenpyrad
100 + 100
80



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
90


Compound 129
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
85



+ spirodiclofen
100 + 10 
90


Compound 130
+ tebufenpyrad
100 + 100
90



+ fenbutatin oxide
100 + 100
95



+ halfenprox
100 + 100
80



+ spirodiclofen
100 + 10 
75


Compound 131
+ tebufenpyrad
100 + 100
95



+ fenbutatin oxide
100 + 100
85



+ halfenprox
100 + 100
90



+ spirodiclofen
100 + 10 
85


Compound 19

100
0


Compound 20

100
0


Compound 39

100
0


Compound 40

100
0


Compound 41

100
0


Compound 42

100
0


Compound 43

100
0


Compound 44

100
0


Compound 45

100
0


Compound 46

100
0


Compound 47

100
0


Compound 48

100
0


Compound 54

100
0


Compound 129

100
5


Compound 130

100
10


Compound 131

100
5


tebufenpyrad

100
60


fenbutatin oxide

100
50


halfenprox

100
35


Untreated plot

—
0









Test Example 5
Test for the Effect on Southern Root-Knot Nematode (Meloidogyne incognita)
Two kilograms of a soil polluted with southern root-knot nematode was blended with a predetermined dose of a granular preparation. The mixture was filled into a 1/5,000 are Wagner pot. After sowing melon seeds and carrying out the treatment of the present invention, the pot was left to stand in a greenhouse. Sixty days after the treatment, 25 g of the soil was sampled out, the nematode was separated therefrom according to the method of Berman, and the numbers of nematodes were counted after 48 hours. The test was carried out with two replications, on one pot/group.
The results are shown in Table 6. In the tables, “ai” means active ingredient.












TABLE 6










Number of






nematodes





Dosage
per 25 g of



Test agent

(g ai/10a)
soil sample





















Compound 19
+ oxamyl
300 + 300
3




+ fosthiazate
300 + 300
1



Compound 20
+ oxamyl
300 + 300
4




+ fosthiazate
300 + 300
2



Compound 39
+ oxamyl
300 + 300
5




+ fosthiazate
300 + 300
1



Compound 40
+ oxamyl
300 + 300
4




+ fosthiazate
300 + 300
3



Compound 41
+ oxamyl
300 + 300
3




+ fosthiazate
300 + 300
2



Compound 42
+ oxamyl
300 + 300
7




+ fosthiazate
300 + 300
5



Compound 43
+ oxamyl
300 + 300
6




+ fosthiazate
300 + 300
2



Compound 44
+ oxamyl
300 + 300
5




+ fosthiazate
300 + 300
5



Compound 45
+ oxamyl
300 + 300
4




+ fosthiazate
300 + 300
2



Compound 46
+ oxamyl
300 + 300
1




+ fosthiazate
300 + 300
3



Compound 47
+ oxamyl
300 + 300
5




+ fosthiazate
300 + 300
3



Compound 48
+ oxamyl
300 + 300
4




+ fosthiazate
300 + 300
2



Compound 54
+ oxamyl
300 + 300
4




+ fosthiazate
300 + 300
2



Compound 129
+ oxamyl
300 + 300
8




+ fosthiazate
300 + 300
2



Compound 130
+ oxamyl
300 + 300
5




+ fosthiazate
300 + 300
1



Compound 131
+ oxamyl
300 + 300
6




+ fosthiazate
300 + 300
3



Compound 19

300
36



Compound 20

300
28



Compound 39

300
34



Compound 40

300
33



Compound 41

300
31



Compound 42

300
28



Compound 43

300
36



Compound 44

300
29



Compound 45

300
30



Compound 46

300
36



Compound 47

300
27



Compound 48

300
33



Compound 54

300
32



Compound 129

300
45



Compound 130

300
40



Compound 131

300
41



oxamyl

300
13



fosthiazate

300
7



Untreated group

—
33










Test Example 6
Test for the Control of Rice Water Weevil (Lissorhoptrus oryzophilus) and Rice Blast on Paddyfield Rice Plant by Nursery Box Application
Fifty grams of a granular preparation was applied to rice plant (variety: Koshihikari) cultured in a nursery box. On the same day as the day of treatment (in the middle ten days of May), the rice plant was transplanted to the main paddy field. The controlling effect against rice water weevil was evaluated by investigating the number of hills classified by the extent of injury, on 100 hills in each plot, 21 days after the transplantation, and calculating the overall extent of injury therefrom. The controlling effect against rice blast was evaluated by investigating the areal rate of disease spot 60 days after the transplantation.

Extent of injury={(4A+3B+2C+D)/(4×N)}×100

wherein

    
    
        A: percentage of injured leaves: 91% or higher
        B: percentage of injured leaves: 61-90%
        C: percentage of injured leaves: 31-60%
        D: percentage of injured leaves: 1-30%
        N: Number of hills investigated
    
    


The results are shown in Table 7.










TABLE 7







Extent
Areal




of
rate of disease



Dosage
injury
spot (%)



(g ai/
After
After


Test agent
Box)
21 days
60 days


















Compound 19 + imidacloprid +
0.5 + 1 + 2
3.5
0.4


carpropamid


Compound 20 + imidacloprid +
0.5 + 1 + 2
2.3
0.3


carpropamid


Compound 39 + imidacloprid +
0.5 + 1 + 2
1.5
0.1


carpropamid


Compound 40 + imidacloprid +
0.5 + 1 + 2
2.5
0.6


carpropamid


Compound 41 + imidacloprid +
0.5 + 1 + 2
1.3
0.2


carpropamid


Compound 42 + imidacloprid +
0.5 + 1 + 2
2.5
0.2


carpropamid


Compound 43 + imidacloprid +
0.5 + 1 + 2
1.3
0.1


carpropamid


Compound 44 + imidacloprid +
0.5 + 1 + 2
3.8
0.4


carpropamid


Compound 45 + imidacloprid +
0.5 + 1 + 2
2.2
0.3


carpropamid


Compound 46 + imidacloprid +
0.5 + 1 + 2
1.8
0.4


carpropamid


Compound 47 + imidacloprid +
0.5 + 1 + 2
2.8
0.2


carpropamid


Compound 48 + imidacloprid +
0.5 + 1 + 2
1.9
0.5


carpropamid


Compound 54 + imidacloprid +
0.5 + 1 + 2
1.3
0.6


carpropamid


Compound 129 + imidacloprid +
0.5 + 1 + 2
3.5
0.5


carpropamid


Compound 130 + imidacloprid +
0.5 + 1 + 2
2.9
0.4


carpropamid


Compound 131 + imidacloprid +
0.5 + 1 + 2
3.2
0.3


carpropamid


Compound 19
0.5
38.9
8.3


Compound 20
0.5
37.4
8.1


Compound 39
0.5
38.9
8.2


Compound 40
0.5
39.0
7.9


Compound 41
0.5
43.2
8.5


Compound 42
0.5
39.5
8.3


Compound 43
0.5
44.3
8.9


Compound 44
0.5
45.9
9.1


Compound 45
0.5
38.8
8.2


Compound 46
0.5
42.7
8.5


Compound 47
0.5
40.9
7.8


Compound 48
0.5
39.8
7.4


Compound 54
0.5
41.7
9.0


Compound 129
0.5
40.3
9.1


Compound 130
0.5
39.0
8.3


Compound 131
0.5
41.2
8.3


imidacloprid + carpropamid
1 + 2
5.8
1.2


Untreated plot
—
45.6
8.2









Test Example 7
Test for the Control of Small Brown Planthopper (Laodelphax striatellus) and Rice Leafroller (Cnaphalocrosis medinalis) on Paddyfield Rice Plant by Nursery Box Application
Fifty grams of a granular preparation was applied to rice plant (variety: Nihombare) cultured in a nursery box, after which the rice plant was transplanted to the main paddy field (in the middle of May). The controlling effect against small brown planthopper was evaluated by investigating the number of parasitic insects on 30 hills per each plot, 40 days and 60 days after the transplantation. The controlling effect against rice leafroller was evaluated by investigating the number of injured leaves on 100 hills per each plot, 50 days after the transplantation.
The results are shown in Table 8.










TABLE 8









Number of




parasitic



planthoppers per



30 hills
Percentage of












Dosage (g ai/
After
After
injured leaves (%)


Test agent
Box)
40 days
60 days
After 50 days















Compound 19
+ imidacloprid
0.5 + 1
0
4
0.03



+ benfuracarb
0.5 + 2.5
17
48
0.07


Compound 20
+ imidacloprid
0.5 + 1
0
7
0.05



+ benfuracarb
0.5 + 2.5
22
55
0.08


Compound 39
+ imidacloprid
0.5 + 1
0
9
0.04



+ benfuracarb
0.5 + 2.5
24
45
0.07


Compound 40
+ imidacloprid
0.5 + 1
0
10
0.02



+ benfuracarb
0.5 + 2.5
17
54
0.08


Compound 41
+ imidacloprid
0.5 + 1
0
6
0.04



+ benfuracarb
0.5 + 2.5
33
34
0.06


Compound 42
+ imidacloprid
0.5 + 1
0
7
0.03



+ benfuracarb
0.5 + 2.5
31
65
0.08


Compound 43
+ imidacloprid
0.5 + 1
0
9
0.02



+ benfuracarb
0.5 + 2.5
14
33
0.06


Compound 44
+ imidacloprid
0.5 + 1
0
3
0.03



+ benfuracarb
0.5 + 2.5
18
53
0.08


Compound 45
+ imidacloprid
0.5 + 1
0
4
0.02



+ benfuracarb
0.5 + 2.5
25
23
0.08


Compound 46
+ imidacloprid
0.5 + 1
0
7
0.05



+ benfuracarb
0.5 + 2.5
13
54
0.09


Compound 47
+ imidacloprid
0.5 + 1
0
7
0.04



+ benfuracarb
0.5 + 2.5
16
36
0.08


Compound 48
+ imidacloprid
0.5 + 1
0
6
0.03



+ benfuracarb
0.5 + 2.5
33
28
0.08


Compound 54
+ imidacloprid
0.5 + 1
0
9
0.02



+ benfuracarb
0.5 + 2.5
31
45
0.07


Compound 129
+ imidacloprid
0.5 + 1
0
7
0.04



+ benfuracarb
0.5 + 2.5
15
57
0.08


Compound 130
+ imidacloprid
0.5 + 1
0
6
0.06



+ benfuracarb
0.5 + 2.5
18
61
0.09


Compound 131
+ imidacloprid
0.5 + 1
0
8
0.05



+ benfuracarb
0.5 + 2.5
20
49
0.08


Compound 19

0.5
325
389
0.16


Compound 20

0.5
315
354
0.15


Compound 39

0.5
343
372
0.25


Compound 40

0.5
322
358
0.33


Compound 41

0.5
333
385
0.35


Compound 42

0.5
345
389
0.22


Compound 43

0.5
309
334
0.17


Compound 44

0.5
323
358
0.24


Compound 45

0.5
353
395
0.13


Compound 46

0.5
349
387
0.18


Compound 47

0.5
328
365
0.11


Compound 48

0.5
345
383
0.33


Compound 54

0.5
328
334
0.25


Compound 129

0.5
323
390
0.13


Compound 130

0.5
331
382
0.16


Compound 131

0.5
342
391
0.14


imidacloprid

1
0
29
1.63


benfuracarb

2.5
78
244
1.13


Untreated plot

—
355
388
1.54









Test Example 8
Test for the Control of Diamondback Moth (Plutella xyloxtella) and Aphid on Cabbage by Soil Treatment
A granular preparation was mixed into bed soil, and the mixture was filled into a cell seedling box and sown with seeds of cabbage (variety: YR Seitoku). Otherwise, cell seedling planted cabbage was treated with the granular agent either by a treatment in the foliage leaf extraction period, or by a pre-transplanting treatment, or by a pricking-in hole treatment, or by a plant foot treatment after the planting. Twenty one days after the transplanting (in the middle of June), the number of parasitic insects was counted on 30 hills in the case of diamondback moth and on 10 hills in the case of aphid.
The results are shown in Table 9.









TABLE 9









Number of



parasitic insects



per 30 hills












Dosage (mg

Diamond-




ai/
Method of
back


Test agent
hill)
treatment
moth
Aphid














Compound 19 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 20 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 39 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 40 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 41 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 42 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 43 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 44 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 45 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 46 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 47 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 48 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 54 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 129 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 130 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound 131 + imidacloprid
5 + 20
pre-
0
0




transplanting




treatment



5 + 20
pricking-in
0
0




hole treatment



5 + 20
plant foot
0
0




treatment


Compound
5
soil
1
445


19

incorporation



5
true leaf
2
457




extraction




season




treatment



5
pre-
1
399




transplanting




treatment



5
pricking-in
1
467




hole treatment



5
plant foot
2
489




treatment


Compound
5
soil
4
512


20

incorporation



5
true leaf
2
498




extraction




season




treatment



5
pre-
6
478




transplanting




treatment



5
pricking-in
3
499




hole treatment



5
plant foot
5
501




treatment


Compound
5
soil
3
513


39

incorporation



5
true leaf
2
487




extraction




season




treatment



5
pre-
4
457




transplanting




treatment



5
pricking-in
3
437




hole treatment



5
plant foot
2
456




treatment


Compound 40
5
soil
2
472




incorporation



5
true leaf
1
510




extraction




season




treatment



5
pre-
1
477




transplanting




treatment



5
pricking-in
1
486




hole treatment



5
plant foot
3
478




treatment


Compound 41
5
soil
3
457




incorporation



5
true leaf
2
495




extraction




season




treatment



5
pre-
1
458




transplanting




treatment



5
pricking-in
2
511




hole treatment



5
plant foot
2
456




treatment


Compound 42
5
soil
3
475




incorporation



5
true leaf
2
485




extraction




season




treatment



5
pre-
3
435




transplanting




treatment



5
pricking-in
1
473




hole treatment



5
plant foot
3
498




treatment


Compound 43
5
soil
2
501




incorporation



5
true leaf
2
448




extraction




season




treatment



5
pre-
3
482




transplanting




treatment



5
pricking-in
1
447




hole treatment



5
plant foot
2
467




treatment


Compound 44
5
soil
3
449




incorporation



5
true leaf
2
502




extraction




season




treatment



5
pre-
3
498




transplanting




treatment



5
pricking-in
3
478




hole treatment



5
plant foot
2
492




treatment


Compound 45
5
soil
2
472




incorporation



5
true leaf
2
463




extraction




season




treatment



5
pre-
1
472




transplanting




treatment



5
pricking-in
5
465




hole treatment



5
plant foot
4
489




treatment


Compound 46
5
soil
1
505




incorporation



5
true leaf
3
498




extraction




season




treatment



5
pre-
1
479




transplanting




treatment



5
pricking-in
3
447




hole treatment



5
plant foot
2
469




treatment


Compound 47
5
soil
3
438




incorporation



5
true leaf
2
499




extraction




season




treatment



5
pre-
4
452




transplanting




treatment



5
pricking-in
1
477




hole treatment



5
plant foot
2
511




treatment


Compound 48
5
soil
5
502




incorporation



5
true leaf
2
442




extraction




season




treatment



5
pre-
5
476




transplanting




treatment



5
pricking-in
1
492




hole treatment



5
plant foot
4
456




treatment


Compound 54
5
soil
1
478




incorporation



5
true leaf
3
459




extraction




season




treatment



5
pre-
1
487




transplanting




treatment



5
pricking-in
3
499




hole treatment



5
plant foot
2
463




treatment


Compound 129
5
soil
2
455




incorporation



5
true leaf
1
458




extraction




season




treatment



5
pre-
2
402




transplanting




treatment



5
pricking-in
3
397




hole treatment



5
plant foot
1
481




treatment


Compound 130
5
soil
1
453




incorporation



5
true leaf
1
399




extraction




season




treatment



5
pre-
1
421




transplanting




treatment



5
pricking-in
2
467




hole treatment



5
plant foot
1
498




treatment


Compound 131
5
soil
1
432




incorporation



5
true leaf
1
465




extraction




season




treatment



5
pre-
2
428




transplanting




treatment



5
pricking-in
2
391




hole treatment



5
plant foot
1
486




treatment


imidacloprid
20 
pre-
35
10




transplanting




treatment



20 
picking-in
40
16




hole treatment



20 
plant foot
38
13




treatment


Untreated plot
—

41
479





Note:


The effect in soil incorporation and true leaf extraction season treatment could not be evaluated due to phytotoxicity, in cases of a single use of imidacloprid and a mixed use of imidacloprid.






Test Example 9
Test for the Effect Against Cutworm on Beet
Beet seedlings (variety: Monoace S) planted in a paper pot was treated with 3 L/m2 of a solution of an agent diluted to a predetermined concentration, by the method of drench. Just after the drench, the plant was set. Predetermined days after the setting, the number of injured hills per 100 hills was counted. The test was carried out with two replications, 80 m2 per one plot.
The results are shown in Table 10.









TABLE 10









Number of injured



hills per 100 hills












Dosage
After 60
After 90
After 120


Test agent
(g ai/10a)
days
days
days














Compound 19 + acephate
15 + 50
0
3
11


Compound 20 + acephate
15 + 50
0
4
10


Compound 39 + acephate
15 + 50
0
2
8


Compound 40 + acephate
15 + 50
0
1
7


Compound 41 + acephate
15 + 50
0
5
9


Compound 42 + acephate
15 + 50
0
4
10


Compound 43 + acephate
15 + 50
0
2
6


Compound 44 + acephate
15 + 50
0
3
8


Compound 45 + acephate
15 + 50
0
1
5


Compound 46 + acephate
15 + 50
0
4
11


Compound 47 + acephate
15 + 50
0
5
12


Compound 48 + acephate
15 + 50
0
2
5


Compound 54 + acephate
15 + 50
0
2
6


Compound 129 + acephate
15 + 50
0
3
14


Compound 130 + acephate
15 + 50
0
2
9


Compound 131 + acephate
15 + 50
0
5
12


Compound 19
15
0
8
21


Compound 20
15
0
7
20


Compound 39
15
0
6
17


Compound 40
15
0
9
23


Compound 41
15
0
7
21


Compound 42
15
0
8
22


Compound 43
15
0
6
19


Compound 44
15
0
7
20


Compound 45
15
0
9
23


Compound 46
15
0
8
20


Compound 47
15
0
9
21


Compound 48
15
0
7
18


Compound 54
15
0
8
19


Compound 129
15
0
10
22


Compound 130
15
0
7
19


Compound 131
15
0
8
21


acephate
50
2
14
24


Untreated plot
—
6
26
30









Test Example 10
Test for the Control of Citrus Yellow Thrips (Frankliniella occidentalis) on Egg Plant by the Combined Use with Natural Enemy Pesticide
An agent solution diluted to a predetermined concentration was sprayed by means of a shouldered spraying machine to citrus yellow thrips (Frankliniella occidentalis) parasitic on egg-plant (variety: Senryo No. 2) in a vinyl house. After air-dryness, 100 heads per hill of Amblyseius cucumeris were let inoculate. Fourteen days, twenty one days and twenty eight days after the treatment, the numbers of citrus yellow thrips and Amblyseius cucumeris were counted on twenty leaves showing a most serious injury (the first ten days of June).
The results are shown in Table 11.










TABLE 11










Number of parasitic



Amount
insects per 20



applied
leaves












(ppm or


After



adults
After 14
After 21
28


Test agent
number)
days
days
days














Compound 19 + Amblyseius
100 ppm + 100
2
0
3


cucumeris
adults/hill


Compound 20 + Amblyseius
100 ppm + 100
3
0
2


cucumeris
adults/hill


Compound 39 + Amblyseius
100 ppm + 100
1
0
1


cucumeris
adults/hill


Compound 40 + Amblyseius
100 ppm + 100
4
0
4


cucumeris
adults/hill


Compound 41 + Amblyseius
100 ppm + 100
5
1
6


cucumeris
adults/hill


Compound 42 + Amblyseius
100 ppm + 100
3
0
4


cucumeris
adults/hill


Compound 43 + Amblyseius
100 ppm + 100
1
0
2


cucumeris
adults/hill


Compound 44 + Amblyseius
100 ppm + 100
1
0
1


cucumeris
adults/hill


Compound 45 + Amblyseius
100 ppm + 100
2
0
4


cucumeris
adults/hill


Compound 46 + Amblyseius
100 ppm + 100
4
1
6


cucumeris
adults/hill


Compound 47 + Amblyseius
100 ppm + 100
1
0
2


cucumeris
adults/hill


Compound 48 + Amblyseius
100 ppm + 100
3
1
5


cucumeris
adults/hill


Compound 54 + Amblyseius
100 ppm + 100
2
0
2


cucumeris
adults/hill


Compound 129 + Amblyseius
100 ppm + 100
2
0
3


cucumeris
adults/hill


Compound 130 + Amblyseius
100 ppm + 100
4
0
2


cucumeris
adults/hill


Compound 131 + Amblyseius
100 ppm + 100
3
0
4


cucumeris
adults/hill


Compound 19
100 ppm
20
27
55


Compound 20
100 ppm
21
28
49


Compound 39
100 ppm
19
32
58


Compound 40
100 ppm
22
31
52


Compound 41
100 ppm
18
29
59


Compound 42
100 ppm
19
25
50


Compound 43
100 ppm
23
31
57


Compound 44
100 ppm
25
33
53


Compound 45
100 ppm
18
29
59


Compound 46
100 ppm
20
34
57


Compound 47
100 ppm
21
27
52


Compound 48
100 ppm
19
31
59


Compound 54
100 ppm
18
25
61


Compound 129
100 ppm
19
29
51


Compound 130
100 ppm
21
28
50


Compound 131
100 ppm
23
30
54


Amblyseius cucumeris
100
8
5
15



adults/hill


Untreated plot
—
22
32
58









Test Example 11
Test for the Control of Rice Leafroller (Cnaphalocrocis medinalis), Rice Blast, Barnyard Grass (Echinochloa crus-galli) and Bulrush (Scirpus juncoides Roxb.) on Paddyfield Rice Plant by Submerged Application to Main Paddyfield
Ten days after the transplantation (in the middle ten days of May), a granular preparation was applied to water surface of main paddyfield. The controlling effect on rice leafroller was evaluated by counting the injured leaves on each plot (100 hills) 50 days after the transplantation, and calculating the percentage of injured leaves therefrom. The effect against rice blast was evaluated by measuring the areal rate of disease spot 60 days after the transplantation. The effects against barnyard grass and bulrush were evaluated by measuring the herbicidal effect by the naked eye four weeks after the treatment and expressing the result by numerically (0 means “no effect”, and 10 means “complete withering”). At the same time, the chemical injury on rice plant was also evaluated (0 means “no influence”).
The results are shown in Table 12.












TABLE 12









Percentage
Areal





of
rate
Herbicidal



injured
of disease
effect













leaves
spot
barn-




Test agent
(%)
(%)
yard
ful-
Phytotoxicity


Dosage (g ai/10a)
After 50 days
After 60 days
grass
rush
rice















Compound 129 + pyroquilon + bensulfron-methyl + indanofan
0.13
0.5
10
10
0


10.0 + 150.0 + 5.0 + 15.0


Compound 129 + fenoxanyl + bensulfron-methyl + indanofan
0.12
0.4
10
10
0


10.0 + 250.0 + 5.0 + 15.0


Compound 130 + pyroquilon + bensulfron-methyl + indanofan
0.11
0.3
10
10
0


10.0 + 150.0 + 5.0 + 15.0


Compound 130 + fenoxanyl + bensulfron-methyl + indanofan
0.15
0.5
10
10
0


10.0 + 250.0 + 5.0 + 15.0


Compound 131 + pyroquilon + bensulfron-methyl + indanofan
0.13
0.3
10
10
0


10.0 + 150.0 + 5.0 + 15.0


Compound 131 + fenoxanyl + bensulfron-methyl + indanofan
0.14
0.4
10
10
0


10.0 + 250.0 + 5.0 + 15.0


Compound 129 10.0
0.15
8.1
0
0
0


Compound 130 10.0
0.13
7.9
0
0
0


Compound 131 10.0
0.16
8.3
0
0
0


pyroquilon + bensulfron-methyl + indanofan
1.56
0.6
10
10
0


250.0 + 5.0 + 15.0


fenoxanyl + bensulfron-methyl + indanofan
1.63
0.8
10
10
0


250.0 + 5.0 + 15.0


Untreated plot —
1.66
8.2
0
0
0

## Claims

1. A composition for noxious organisms-controlling agent comprising, as active ingredients thereof, one or more compounds selected from phthalamide derivatives represented by formula (I):



wherein R1 represents a hydrogen atom, R2 represents a C1-C6 alkyl group, a C1-C6 alkylthio C1-C6 alkyl group, a C1-C6 alkylsulfinyl C1-C6 alkyl group or a C1-C6 alkylsulfonyl C1-C6 alkyl group, R3 represents a hydrogen atom, X represents a halogen atom, n represents 1, each of Z1 and Z2 represents an oxygen atom, Y may be the same or different and represents a halogen atom, a C1-C6 alkyl group, a halo C1-C6 alkyl group or a halo C1-C6 alkoxy group, and m represents 2 or 3 and
imidacloprid.

2. A composition for noxious organisms-controlling agent according to claim 1, wherein the phthalamide derivative represented by formula (I) is N2-(1,1-dimethyl-2-methylthioethyl)-3-iodo-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)-ethyl]phenyl}phthalamide, N2-(1,1-dimethyl-2-methylsulfonylethyl)-3-iodo-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-phenyl}-phthalamide or N2-(1,1-dimethyl-2-methylsulfinylethyl)-3-iodo-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}phthalamide.

3. A composition for noxious organisms-controlling agent according to claim 1, wherein the amount of said imidacloprid is 0.05 to 2,000 parts by weight per part by weight of the phthalamide derivative.

4. A method for using a composition for noxious organisms-controlling agent characterized by treating an objective noxious organism, an objective useful plant, a seed of an objective useful plant, soil or a cultivation carrier with an effective amount of the composition for noxious organisms-controlling agent according to claim 1 for the purpose of protecting an useful plant from a noxious organism.