# Patent

## Title
Spacer formation with straight sidewall

## Abstract

Disclosed herein is a semiconductor device comprising a first dielectric disposed over a channel region of a transistor formed in a substrate and a gate disposed over the first dielectric. The semiconductor device further includes a second dielectric disposed vertically, substantially perpendicular to the substrate, at an edge of the gate, and a spacer disposed proximate to the second dielectric. The spacer includes a cross-section with a perimeter that includes a top curved portion and a vertical portion substantially perpendicular to the substrate. The perimeter further includes a discontinuity at an interface of the top curved portion with the vertical portion. Further, disclosed herein are methods associated with the fabrication of the aforementioned semiconductor device.

## Background
BACKGROUND OF THE INVENTION
1. Technical Field
The present disclosure relates to the fabrication of spacers. More specifically, the present disclosure relates to fabricating spacers having vertical sidewalls and to improving spacer shape and spacer width.
2. Related Art
In integrated circuit fabrication technology, a spacer is a structural feature commonly formed proximate to a sidewall of a topographical feature. One function of the spacer may be to improve the electrical performance of a device comprising the topographical feature. Another function of the spacer is to act as a mask during fabrication.
For example, in modern complementary metal oxide semiconductor (CMOS) processes, oxide or nitride spacers may be formed at the sidewalls of a polycrystalline silicon (poly-Si) transistor gate in order to electrically isolate the gate from the transistor's source and drain terminals. Similarly, in modern bipolar junction transistor (BJT) technologies, in which the BJTs have self-aligned emitters, oxide spacers may be formed at an edge of a self-aligned emitter in order to isolate the emitter from the base electrode.
Further, spacers are used as ion implantation hard masks for achieving double-diffused structures in lightly doped drain/source metal oxide field-effect transistors (LDD-MOSFETs). Spacers may also be used as hard masks for transferring patterns in an underlying layer or substrate. In the latter application, the use of spacers enhances a conventional lithography process by allowing double the expected number of features to be transferred to the underlying layer or substrate in one exposure step. Furthermore, in self-aligned silicide layer formation, spacers may be used to prevent shorting the gate and source/drain terminals during the salicide process.
A spacer may also serve as an active terminal of a device. For example, in split-gate transistors, which are used in embedded charge trapping memory devices, a poly-Si spacer may be used to form one of the two gates of a split-gate transistor memory cell. The poly-Si spacer gate is typically metallized and serves as a select gate for the memory cell.
There are several parameters to consider when fabricating spacers, especially when they are to be used in the applications mentioned above. Etch rate, etch chemistry, material deposition thickness, among other parameters, may all affect the spacers' shape and width. Offsets in width or irregular sidewall profiles result from non-ideal fabrication conditions, which directly affect overall device performance.
For example, a split-gate transistor may have an undesired drive strength or selection threshold if there is an offset in the selection gate spacer's nominal width. Furthermore, a tapered or curved spacer sidewall profile may result in shorting the gate and drain terminals during a salicide process. Also, in applications where spacers are used for pattern transfer, incorrect feature sizes and incorrect pitch values may result from offsets in nominal spacer width and from tapered or curved spacer sidewall profiles.
BRIEF SUMMARY OF THF INVENTION
Disclosed herein are structure and method embodiments comprising spacers having highly vertical sidewalk and spacers which can be fabricated with improved process control.
One embodiment is directed to a semiconductor device comprising a first dielectric disposed over a channel region of a transistor formed in a substrate and a gate disposed over the first dielectric. The semiconductor device further includes a second dielectric disposed vertically, substantially perpendicular to the substrate, at an edge of the gate, and a spacer disposed proximate to the second dielectric. The spacer includes a cross-section with a perimeter that includes a top curved portion and a vertical portion substantially perpendicular to the substrate. The perimeter further includes a discontinuity at an interface of the top curved portion with the vertical portion.
Another embodiment is directed to a method of fabricating a semiconductor device. The method comprises disposing a gate structure on a substrate. The gate structure comprises a transistor gate, a first dielectric disposed beneath the transistor gate, and a second dielectric at least on sidewalls of the gate and over the gate. The method further comprises disposing a first layer of material over the second dielectric, disposing a second layer of material over the first layer of material, etching the second layer of material such that portions of the second layer of material remain on sidewalls of the first layer of material, and etching the first layer of material with an etchant having substantially higher selectivity to the first layer of material than to the second layer of material.
Yet another embodiment is directed to a method of fabricating a semiconductor device, comprising disposing a first dielectric on a substrate, disposing a first gate layer over the first dielectric, etching the first gate layer to form a first transistor gate, and etching the first dielectric such that a portion of the first dielectric remains beneath the first transistor gate. The method further includes disposing a second dielectric over the first transistor gate and over the substrate, disposing a second gate layer over the second dielectric, and disposing a thin layer of material over the second gate layer, the thin layer of material substantially thinner than the second gate layer. Furthermore, the method comprises etching the thin layer to leave of the thin layer on sidewalls of the second gate layer and forming, by etching through the second gate layer, a second transistor gate comprising a sidewall having a cross-section that includes a vertical portion substantially perpendicular to the substrate and a top curved portion.
Further features and advantages of the invention, as well as the structure and operation of various embodiments of the invention, are described in detail below with reference to the accompanying drawings. It is noted that the invention is not limited to the specific embodiments described herein. Such embodiments are presented herein for illustrative purposes only. Additional embodiments will be apparent to persons skilled in the relevant art(s) based on the teachings contained herein.



BRIEF DESCRIPTION OF THE DRAWINGS
Embodiments of the invention will now be described, by way of example only, with reference to the accompanying schematic drawings in which corresponding reference symbols indicate corresponding parts. Further, the accompanying drawings, which are incorporated herein and form part of the specification, illustrate embodiments of the present invention, and, together with the description, further serve to explain the principles of the invention and to enable a person skilled in the relevant art(s) to make and use the invention.
FIG. 1 is a cross-sectional view of a split-gate transistor comprising a spacer having a curved sidewall.
FIGS. 2A-2E illustrate various cross-sectional views of split-gate transistors during an example fabrication process.
FIG. 3 shows a split-gate transistor, according to an example embodiment.
FIGS. 4A-4D illustrate various cross-sectional views of split-gate transistors during fabrication, according to an example embodiment.



The features and advantages of embodiments of the present invention will become more apparent from the detailed description set forth below when taken in conjunction with the drawings. In the drawings, like reference numbers generally indicate identical or similar elements, unless otherwise mentioned. Additionally, generally, the left-most digit(s) of a reference number identifies the drawing in which the reference number first appears.
DETAILED DESCRIPTION OF THE INVENTION
This specification discloses one or more embodiments that incorporate features of this invention. The disclosed embodiment(s) merely exemplify the present invention. The scope of the present invention is not limited to the disclosed embodiment(s).
The embodiment(s) described, and references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” etc., indicate that the embodiment(s) described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is understood that it is within the knowledge of one skilled in the art to effect such feature, structure, or characteristic in connection with other embodiments whether or not expressly described.
Before describing the various embodiments in detail, further explanation shall be given regarding certain terms that are used throughout the descriptions.
The terms “etch” or “etching” or “etch-back process” are used herein to generally describe a fabrication process of patterning a material such that at least a portion of the material remains after etching is completed. It shall be construed that etching a semiconductor material, for example, involves the steps of patterning a mask layer disposed over the semiconductor material (e.g., a photoresist layer or a hard mask), subsequently removing areas of the semiconductor material that are no longer protected by the mask layer, and optionally removing remaining portions of the mask layer. It shall also be construed that such removing step is conducted using an “etchant” and that such an etchant has a “selectivity” that is higher to the semiconductor material than to the mask layer. Further, it shall be understood that etching may be used in general terms without a mask layer, yet still yielding removed parts and remaining parts of the etched material.
The term “selectivity” between two materials is described herein as the ratio between the etch rates of the two materials under the same etching conditions. For example, an etchant with a selectivity of 3:1 to the semiconductor over the mask layer means that the etchant removes the semiconductor material at a rate three times faster than that at which it removes the mask layer.
The term “substrate” is used herein to generally describe a material onto which subsequent material layers are added. In this disclosure, the substrate itself may be patterned and materials added on top of it may also be patterned or remain without patterning. Furthermore, although throughout the following descriptions, the substrate is most commonly thought to be silicon, the substrate may also be any of a wide variety of materials, including commonly used semiconductor materials.
Further, it shall be understood that devices fabricated in and/or on the substrate may be in several regions of the substrate and furthermore that these regions may not be mutually exclusive. That is, in some embodiments, portions of one or more regions may overlap.
Further, the terms “deposit” or “dispose” are used herein to describe the act of applying a layer of material to the substrate or to layers already applied to the substrate, whether these layers are patterned or not. Further, it shall be understood that the deposited layer of material is conformal, unless otherwise mentioned. The term “conformal” is used herein to describe a film that at least partially covers one or more sidewalls of features patterned on a substrate.
The term “substantially perpendicular,” in reference to a topographical feature's sidewall, is used herein to generally describe a sidewall disposed at an angle ranging between about 85 degrees and 90 degrees with respect to the substrate. The term “substantially shorter,” in reference to the length of a first feature relative to that of a second feature, is used herein to generally imply that the length of the first feature is at most one half the length of the second feature. Lastly, the term “substantially longer” is used herein, in reference to the length of a first feature relative to that of a second feature, to generally imply that the length of the first feature is a least twice the length of the second feature.
Turning now to the drawings, FIG. 1 illustrates an example of a non-volatile memory cell 100 having a split-gate transistor architecture. Memory cell 100 is formed on substrate 102. For ease of description, substrate 102 is assumed to be silicon. Other substrate materials may be used. Further, substrate 102 may be p-type silicon or a p-type well formed in an n-type silicon substrate or well. Memory cell 100 includes a first n-type doped region 104 and a second n-type doped region 106. The first doped region 104 may be used as a source/drain region, and similarly, the second doped region 106 may also be used as a source/drain region. While regions 104 and 106 are n-type in this example, they may also be p-type regions when substrate 102 is n-type silicon or an n-type well formed in a p-type silicon substrate. Further, regions 104 and 106 may be formed, for example, using ion implantation. For convenience, region 104 is referred herein as the drain of memory cell 100, and region 106 is referred to as a the source of memory cell 100, irrespective of biases applied thereto. The terms drain and source are used by convention, not as limitations.
Memory cell 100 includes two gates, a select gate 114 and a memory gate 110. Each gate may be a poly-Si layer. As shall be described below, select gate 114 is a spacer. Select gate 114 is disposed over dielectric layer 112, whereas memory gate 110 is disposed over a charge-trapping dielectric 108. The charge-trapping dielectric 108 may include, for example, a charge-trapping silicon nitride layer sandwiched between two silicon dioxide layers; this three-layer arrangement is referred to as an “oxide, nitride, oxide (ONO) stack,” or simply as “ONO layers.” Alternatively, charge-trapping dielectric 108 may include a silicon-rich nitride film, or any film that includes, but is not limited to, silicon, oxygen, and nitrogen, in various stoichiometries.
Dielectric 112 electrically isolates select gate 114 from memory gate 110. Dielectric 112 comprises a first portion that is disposed vertically, i.e., substantially perpendicular to substrate 102, and a second portion disposed horizontally beneath select gate 114. The first portion and the second portion are connected to one another, e.g., dielectric 112 may be deposited in a single step to form its horizontal and vertical portions. In some examples, dielectric 112 and charge trapping dielectric 108 may have the same architecture, e.g., they may both be ONO stacks, while in other examples they may be physically distinguishable. For example, dielectric 112 is assumed to be a single-layer silicon dioxide film whereas dielectric 108 is an ONO stack.
To better understand how offsets in select gate 114 affect performance of memory cell 100, example write, erase, and read operations, as they relate to memory cell 100, shall now be described. In order to “write” a digital bit in memory cell 100, a positive voltage on the order of 5 volts, for example, is applied to region 106 while region 104 and substrate 102 are grounded. A low positive voltage on the order of 1.5 volts, for example, is applied to select gate 114 while a higher positive voltage on the order of 8 volts, for example, is applied to memory gate 110. As electrons are accelerated within a channel region between source and drain, some acquire sufficient energy to transport upwards and become trapped within charge-trapping dielectric 108. This phenomenon is known as hot electron injection, and it is an example mechanism for storing charge within charge-trapping dielectric 108. As such, charges trapped within charge-trapping dielectric 108 correspond to the “high” bit state of memory cell 100. The trapped charge is retained even after the various voltage supplies are removed, hence the term “non-volatile” attributed to memory cell 100 in the preceding paragraphs.
To “erase” memory cell 100 (i.e., in order to remove charges trapped in charge-trapping dielectric 108 due to hot electron injection) a positive voltage on the order of 5 volts, for example, is applied to region 106 while region 104 is held at a fixed bias or simply left floating, and select gate 108 and substrate 102 are grounded. A high-magnitude negative voltage, −8 volts for example, is applied to memory gate 110. Under these bias conditions, channel holes gain sufficient kinetic energy to overcome the oxide barrier and are injected into the charge-trapping layer. This added positive charge compensates the trapped negative charged electrons, thereby effectively erasing memory cell 100 to put it in the “low” bit state.
To “read” the state of memory cell 100, a low voltage applied is to memory gate 110 and to select gate 114. The low voltage is chosen so that it lies substantially equidistant between the threshold voltage necessary to tarn on the split-gate transistor when storing a “high” bit and the threshold voltage necessary to turn on the split-gate transistor when storing a “low” bit. As such, if the application of the low voltage during the “read” operation caused substantial current flow between regions 104 and 106, then the memory cell holds a “low” bit. Conversely, if the application of the low voltage during the “read” operation caused no current follow between regions 104 and 106, then the memory cell holds a “high” bit.
Since the current during the “read” operation is directly proportional to the width of the memory gate 110 and to the width 116 of select gate 114, the width of each gate is a critical dimension. In other words, the width of memory gate 110 and the width of select gate 114 must be fabricated within tight process tolerances in order to yield a gate width substantially equal to a nominal width set forth during the design of memory cell 100. Otherwise, if the gate widths are either too short or too long as compared to the nominal width, incorrect operation of memory cell 100 will occur. Further, in an array comprising a plurality of memory cells such as memory cell 100, each cell would have different characteristics due to mismatches in select gate length. This mismatch leads to poor memory array performance. As shall be seen below, while it may be possible to accurately control the width of memory gate 110 during fabrication, controlling the width 116 of select gate 114 is more complicated.
FIGS. 2A-2E illustrate cross-sectional views of an example fabrication process for the memory cell 100 shown FIG. 1. It is to be understood that this description is meant to provide a general overview of the major steps involved in fabricating a split-gate transistor and that, in actual practice, many more features and/or fabrication steps may be provided to form memory cell 100.
FIG. 2A shows a semiconductor substrate 202 (for example silicon) having disposed thereon a dielectric 208 and a transistor gate layer 210. Substrate 202 may be p-type or n-type silicon as described previously. Further, substrate 202 may be a specific region of a larger semiconductor substrate (not shown). Dielectric 208 may comprise a stack of multiple dielectrics such as an ONO stack. Transistor gate layer 210 may be a poly-Si film, a metal alloy, or any other material that may serve as a transistor gate. For ease of description, it is assumed that dielectric 208 and transistor gate layer 210 are an ONO stack and a polycrystalline film, respectively.
Dielectric 208 and transistor gate layer 210 may be deposited on substrate 202 by conventional deposition methods. For example, the nitride layer of the ONO stack comprised in dielectric 208 may be deposited using low pressure chemical vapor deposition (LPCVD), whereas the oxide layer disposed under the nitride film of the ONO stack may be grown directly from substrate 202 using thermal oxidation; further, the oxide layer disposed over the silicon nitride film in the ONO stack may also be deposited using plasma-enhanced chemical vapor deposition (PECVD). Similarly, transistor gate layer 210 may be deposited via PECVD or any other methods typically used to deposit polycrystalline silicon. It shall be understood that different deposition (or growth) methods may impart varying electrical characteristic to memory cell 100 due to varying film qualities.
FIG. 2B shows semiconductor device 200 having two transistor gates, and a gate dielectric disposed thereunder. While only two transistor gates are shown in FIG. 2B, it shall be understood that more than two gates may be formed. The two transistor gates are formed by patterning transistor gate layer 210. The patterning of transistor gate layer 210 may be achieved by defining an etch mask (not shown) using photolithography and subsequently etching exposed regions of transistor gate layer 210 with an etchant that has higher selectivity to transistor gate layer 210 than to the etch mask. While this patterning step is defined in general terms, one of skill in the art would readily understand that transistor gate layer 210 may be patterned with more advanced lithography techniques, such as for example a double patterning step. Following the pattering of transistor gate layer 210, exposed regions of dielectric 208 are removed. Transistor gate layer 210 thereby serves as a hard mask for the removal of the exposed regions of dielectric 208.
FIG. 2C shows the formation of a conformal dielectric 212 layer on and around both gates. Dielectric 212 may be deposited utilizing a deposition process which enables step coverage. Such deposition processes may be, for example, PECVD. While dielectric 212 may be any of a wide variety of commonly used dielectrics, it is assumed, for ease of description, to be silicon dioxide. Dielectric 212 may be of equal thickness or thicker than dielectric 208. Dielectric 212 further extends over the region between the formed transistor gates.
FIG. 2D shows the disposition of a spacer layer 214 on the semiconductor device 200 of FIG. 2C. Spacer layer 214 is disposed on dielectric 212 utilizing a conformal deposition process. Again, PECVD may be used to deposit spacer layer 214. For ease of description, spacer layer 214 may be for example a poly-Si film. The deposited thickness of spacer layer 214 may be, for example, less than the thickness of transistor gate layer 210.
Following the deposition of spacer layer 214, an etch mask is disposed on spacer layer 214 and patterned (step not shown). The pattern defined in the etch mask are for forming two spacers on either side of each gate. As shown in FIG. 2E, following the etch-back process, spacers 214a and 214b are formed on either side of transistor gate layer 210a and 210b. As shown in FIG. 2E, the formed spacers 214a and 214b have a cross-sectional view that comprises a perimeter having a curved portion. In some instances, the spacer's sidewall may be sloped.
This sidewall shape results from increased corner erosion during the etch-back process and from the anisotropy of the dry etchants typically used to conduct poly-Si etching (e.g., reactive ion etching (RIE) in chloro-fluorine plasmas). Specifically, since spacer layer 214 has a step due to the elevation of transistor gate layer 210, spacer layer 214 must be over-etched in order to completely remove the portion of spacer layer 214 located directly on top of the gate. Further, since the region of spacer layer 214 that is on the sidewall of transistor gate layer 210 is conformal, the spacer resulting from the etch-back process has an outward curved sidewall since the etchant is anisotropic.
In addition to a curved sidewall profile, the aforementioned process conditions introduce offsets in the final width of spacer 214. For example, variation in the duration of the etch-back process is directly related to how much corner erosion occurs. As such, spacer 214 may have a width 216 that is shorter than the targeted nominal width.
FIG. 3 illustrates an example non-volatile memory cell 300, according to an embodiment of the present invention. Memory cell 300 is formed on substrate 302. Substrate 302 is silicon and may be a p-type silicon bulk or a p-type region in an n-type bulk or well. Memory cell 300 includes a first n-type region 304 and a second n-type region 306. The first doped region 304 may be used as a source/drain region, and similarly the second doped region 306 may be used as a source/drain region. While region 304 and region 306 are n-type in this example embodiment, they may also be p-type regions in another embodiment, when substrate 302 is an n-type bulk or an n-type well.
Memory cell 300 further includes two gates, a select gate 314, which is a spacer, and a memory gate 310. Gate 310 may be a poly-Si layer disposed and patterned using conventional techniques. However, select gate 314 is a spacer formed according to an example fabrication process, according to an embodiment of the present invention described below with reference to FIGS. 4A-4D.
Memory cell 300 includes at least two dielectrics. The first dielectric 312 is a silicon dioxide layer. Dielectric 312 comprises a horizontal portion disposed beneath select gate 314 and a vertical portion sandwiched between memory gate 310 and select gate 314. While in this embodiment the horizontal portion and the vertical portion of dielectric 312 are assumed to be of the same material, in alternate embodiments, the two portions may be two distinct dielectric materials.
The second dielectric 308 is disposed directly beneath memory gate 310, and it is a charge trapping dielectric. Charge trapping dielectric 308 may include for example a silicon nitride layer sandwiched between two silicon dioxide layers, thus forming an ONO stack similar to the one previously described in memory cell 100. Alternatively, dielectric 308 may include a silicon-rich nitride film, or any film that includes, but is not limited to, silicon, oxygen, or nitrogen, in various stoichiometries.
Memory cell 300 has similar operation to memory cell 100. However, memory cell 300 differs structurally from memory cell 100 since in memory cell 300, select gate 314 includes cross-section having a perimeter comprising a vertical sidewall 320, substantially perpendicular to substrate 302, in the portion farthest away from the edge of memory gate 310. Moreover, spacer 314 includes a top curved portion 318 shorter in length than vertical sidewall 320 so as to provide a relatively flat surface (when compared with spacer 214) on top of spacer 314 for subsequent metallization steps. Furthermore, the top curved portion 318 and the vertical sidewall 320 are joined at a discontinuity 322. The discontinuity 322 is substantially shorter in length than both the top curved portion 318 and the vertical sidewall 320. The structural features of spacer 314 result from improved process control of critical dimension 316, which is the width of spacer 314, and from minimized corner erosion during fabrication, according to an embodiment of the present invention as shall be described below.
FIGS. 4A-4D illustrate various cross-sectional views of non-volatile memory cells 400, during their fabrication on substrate 402, according to an embodiment. Substrate 402 is silicon and may be p-type or n-type silicon. For example, substrate 402 may be a p-type bulk region of a silicon wafer or a p-well in an n-type region of the wafer. Similarly, substrate 402 may be an n-type bulk or an n-type well in a p-type bulk region. While the substrate is silicon in this example embodiment, alternative embodiments may use other semiconductor substrates commonly used in semiconductor technology. Further, while FIGS. 4A-4D depict only two memory cells 400, the many fabrication steps disclosed herein apply to the fabrication of more than two memory cells 400. Furthermore, while a plurality of steps are described, steps generally undertaken in the fabrication of semiconductor devices are omitted for the sake of conciseness.
FIG. 4A depicts two gate structures, each gate structure comprising a transistor gate 410, a charge trapping dielectric 408, and an additional dielectric 412 that is conformal to gate 410. The gate 410 is a poly-Si layer disposed and patterned with conventional deposition and patterning techniques, for example. While in this embodiment gate 410 is poly-Si, in alternative embodiments gate 410 may be made using other types of material that may serve as a transistor gate. Further, in this embodiment of the present invention, dielectric 408 may comprise a stack of multiple dielectrics such as an ONO stack, as previously described. Dielectric 412 may be silicon dioxide for example, and as in the case of dielectric 312, it comprises a horizontal portion and a vertical portion. The horizontal portion and the vertical portion of dielectric 412 are the same material in this embodiment. In alternate embodiments the horizontal portion and the vertical portion of dielectric 412 may be distinct materials or distinct material stacks.
There is disposed, conformal to the gate structures, a spacer layer 414. Spacer layer 414 is poly-Si, and it may be disposed using conventional poly-Si deposition techniques, such as the ones mentioned above. Further, there is disposed on spacer layer 414 a thin film dielectric 424. Thin film 424 is conformal to spacer layer 414. Further, thin film dielectric 424 is substantially thinner than spacer layer 414. Thin film 424 is used as a sacrificial layer. Specifically, as will become apparent below, thin film 424 is used to form sacrificial spacers on the sidewalls of spacer layer 414. In this example embodiment, thin film 424 is silicon nitride. However, thin film 424 may be any film that has etch chemistry that is substantially different than the etch chemistry of spacer layer 414. In other words, an etchant of thin film 424 must have very low selectivity to spacer layer 414. Conversely, an etchant of spacer layer 414 must have very low selectivity to thin film 424. In summary, spacer layer 414 and thin film 424 form a multi-stack structure wherein the materials in the structure are etched at much different etch rates when subjected to an etchant that has high selectivity to only one material within the structure.
FIG. 4B illustrates memory cells 400 following an etch-back process for fabricating sacrificial spacers 424a and 424b on the sidewalls of spacer layer 414. A mask layer is disposed on thin film 424 (not shown) and patterned. Following the patterning of the mask layer, exposed regions of thin film 424 are etched, for example, in a CF4 or CH2F2 plasma etchant. These etchants have high selectivity to silicon nitride, e.g., they are highly selective to thin film 424. Also, these etchants have very low selectivity to spacer layer 414. Therefore, spacer layer 414 remains substantially unaltered even when it becomes in contact with the etchants.
FIG. 4C shows memory cells 400 following the sacrificial etch-back process that produced sacrificial spacers 424a and 424b. A subsequent etch-back process is conducted, but with an etchant having high selectivity to poly-Si, namely to the exposed regions of spacer layer 414. Such etchants may be for example, chlorine and/or fluorine based plasma etchants. These etchants have relatively low selectivity to sacrificial spacers 424a and 424b. Therefore, spacers 424a and 424b act as masks for the sidewalls of spacer layer 414 during the etch back process. Accordingly, there is virtually no corner erosion during the etch-back process for spacer layer 414, and the etch-back process yields a vertical sidewall profile. In addition, the etch-back process provides improved control over critical dimension 416 since spacer width 416 is insensitive to over-etching as a result of the sidewalls of spacer layer 414 being protected during the process.
FIG. 4D illustrates memory cells 400 following additional steps undertaken to remove exposed regions of dielectric 412 and to remove sacrificial spacers 424a and 424b. These procedures yield spacers 414a and 414b. Spacers 414a and 414b have a vertical sidewall 420, which is substantially perpendicular to substrate 402, and a top curved portion 418. The top curved portion 418 and the vertical sidewall 420 are joined by a discontinuity 422 that corresponds to the width of sacrificial spacers 424a and 424b. The width of discontinuity 422 is substantially shorter than the length of vertical sidewall 420 and substantially shorter than the length of the top curved portion 418. The width of discontinuity 422 may be minimized by keeping thin film 424 as thin as possible. Lastly, spacers 414b and the portion of dielectric 412 directly beneath them may be subsequently removed and source/drain regions may be implanted in order to yield the structure shown in the embodiment depicted in FIG. 3.
It is to be appreciated that the Detailed Description section, and not the Summary and Abstract sections (if any), is intended to be used to interpret the claims. The Summary and Abstract sections (if any) may set forth one or more but not all exemplary embodiments of the invention as contemplated by the inventor(s), and thus, are not intended to limit the invention or the appended claims in any way.
While the invention has been described herein with reference to exemplary embodiments for exemplary fields and applications, it should be understood that the invention is not limited thereto. Other embodiments and modifications thereto are possible, and are within the scope and spirit of the invention. For example, the methods disclosed herein may be used in applications where spacers are not limited to memory-cell fabrication. Such applications may include, for example, fabrication processes that use spacers as hard masks. Furthermore, the present invention is not limited multi-stack material comprising silicon nitride and poly-Si. Other multi-stack materials are contemplated and are within the scope of the present invention. For example, the multi-stack may be a silicon nitride/silicon dioxide stack, a silicon dioxide/poly-Si stack, and stacks of other materials typically used in semiconductor device fabrication.
The breadth and scope of the invention should not be limited by any of the above-described exemplary embodiments, but should be defined only in accordance with the following claims and their equivalents.

## Claims

1. A method of fabricating a semiconductor device, comprising:
disposing a gate structure on a substrate, the gate structure comprising:
a gate, a first dielectric disposed beneath the gate, and a second dielectric at least on sidewalls of the gate and over the gate;

disposing a first layer of material over the second dielectric;
disposing a second layer of material over the first layer of material;
etching the second layer of material such that portions of the second layer of material remain on sidewalls of the first layer of material;
etching the first layer of material with an etchant having substantially higher selectivity to the first layer of material than to the second layer of material; and
etching the portions of the second layer of material remaining on the sidewalls of the first layer of material.

2. The method of claim 1, wherein disposing the first layer of material comprises disposing polycrystalline silicon.

3. The method of claim 1, wherein disposing the second layer of material comprises disposing silicon nitride or silicon dioxide.

4. The method of claim 1, wherein disposing the second layer of material comprises disposing a film of the second layer of material that is substantially thinner than the first layer of material.

5. The method of claim 1, wherein disposing the second dielectric comprises disposing silicon nitride or silicon dioxide wherein the second dielectric comprises at least one type of dielectric material.

6. The method of claim 1, wherein disposing the gate structure, comprises disposing the first dielectric by sequentially depositing oxide, nitride, and oxide (ONO) layers.

7. A method of fabricating a semiconductor device, comprising:
forming a first dielectric layer on a substrate;
forming a first gate layer over the first dielectric layer;
patterning the first gate layer and the first dielectric layer to form a first gate stack;
forming a second dielectric layer over at least the first gate stack and the substrate;
forming a first layer of material over the second dielectric layer;
forming a second layer of material over the first layer of material;
removing a portion of the second layer of material wherein an unremoved portion of the second layer of material remains on sidewalls of the first layer of material;
etching the first layer of material with an etchant having substantially higher selectivity to the first layer of material than to the second layer of material;
etching the unremoved portion of the second layer of material remaining on the sidewalls of the first layer of material.

8. The method of claim 7, wherein the first layer of material includes polycrystalline silicon.

9. The method of claim 7, wherein the second layer of material includes silicon nitride or silicon dioxide.

10. The method of claim 7, wherein forming the second layer of material comprises disposing a film of the second layer of material that is substantially thinner than the first layer of material.

11. The method of claim 7, wherein the second dielectric layer includes silicon nitride or silicon dioxide, and wherein the second dielectric layer includes at least one type of dielectric material.

12. The method of claim 7, wherein forming the first dielectric layer comprises sequentially depositing oxide, nitride, and oxide (ONO) layers.

13. The method of claim 7, wherein forming the second dielectric layer, forming the first layer of material, and forming a second layer of material includes utilizing a conformal deposition process.

14. The method of 7, wherein etching the unremoved portion of the second layer of material causes the first layer of material to be a spacer of the semiconductor device, wherein the spacer includes a cross-section comprising a perimeter that includes a top curved portion and a vertical portion substantially perpendicular to the substrate, and the perimeter including a discontinuity at an interface of the top curved portion with the vertical portion.

15. A method of fabricating a semiconductor device, comprising:
disposing a gate structure on a substrate, the gate structure comprising:
a gate, a first dielectric disposed beneath the gate, and a second dielectric at least on sidewalls of the gate and over the gate;

disposing a first layer of material over the second dielectric, wherein the first layer of material includes polycrystalline silicon;
disposing a second layer of material over the first layer of material;
etching the second layer of material such that portions of the second layer of material remain on sidewalls of the first layer of material; and
etching the first layer of material with an etchant having substantially higher selectivity to the first layer of material than to the second layer of material.