# Patent

## Title
MRAM cells including coupled free ferromagnetic layers for stabilization

## Abstract

A free ferromagnetic data storage layer of an MRAM cell is coupled to a free ferromagnetic stabilization layer, which stabilization layer is directly electrically coupled to a contact electrode, on one side, and is separated from the free ferromagnetic data storage layer, on an opposite side, by a spacer layer. The spacer layer provides for the coupling between the two free layers, which coupling is one of: a ferromagnetic coupling and an antiferromagnetic coupling.

## Background
BACKGROUND
Magnetoresistive random access memory (MRAM) typically employs an array of magnetic storage elements, or cells, which are each located at, or near, an intersection, or crossing, of a corresponding word line with a corresponding bit line. Those skilled in the art know that spin transfer can be used as an alternative to, or in addition to, an external magnetic field in programming current perpendicular to plane (CPP) configurations MRAM cells, which may be either of the magnetic tunnel junction (MTJ) type or of the spin valve (SV) type. When a spin-polarized write current passes through a data storage layer of the cell, which is a free ferromagnetic layer, a portion of the spin angular momentum of the electrons incident on the data storage layer is transferred to the data storage layer. A spin transfer effect, that is caused by conduction electrons traveling from a pinned ferromagnetic layer of the cell to the data storage layer, switches the magnetization orientation of the data storage layer from a direction that is opposite to that of the magnetization orientation of the pinned layer, to a direction that coincides with that of the magnetization orientation of the pinned layer, for example, to program, or write, a logical “0” to the cell; and, a spin transfer effect that is caused by conduction electrons traveling in the opposite direction, switches the magnetization orientation of the data storage layer back to the direction that is opposite to that of the magnetization orientation of the pinned layer, for example, to write a logical “1” to the cell.
In some MRAM arrays, data storage layers may be susceptible to an inadvertent switching, for example, caused by thermally induced lattice vibration. This thermal instability of the storage layers may be due to a reduction in the size and/or magnetization thereof. Furthermore, a significant amount of Joule heating may be generated by a write current, and those cells, which are adjacent to one being written, particularly in ultra high density MRAM arrays, may be inadvertently switched due to the heating. Thus, there is a need for MRAM cell configurations that provide for enhanced thermal stability.
BRIEF SUMMARY
A first free ferromagnetic layer of an MRAM cell, which functions for data storage, is separated, on one side, by a first spacer layer, from a pinned ferromagnetic layer, and is separated, on an opposite side, by a second spacer layer, from a second free ferromagnetic layer, which is directly electrically coupled to a contact electrode, and which acts to stabilize the cell, via coupling across the second spacer layer. The coupling is one of a ferromagnetic coupling and an antiferromagnetic coupling, and has a strength that is greater than a coercivity of the second free ferromagnetic layer. When a writing current is applied to the cell, a magnetization orientation of the first free ferromagnetic layer is reversed by a spin transfer effect of the current, and, then, a magnetization orientation of the second free ferromagnetic layer is reversed, via the coupling between the first and second free layers, to stabilize the new magnetization orientation of the data storage layer, just programmed by the writing current. The second spacer layer may include one or more sub-layers and may further provide for spin depolarization.



BRIEF DESCRIPTION OF THE DRAWINGS
The following drawings are illustrative of particular embodiments of the disclosure and therefore do not limit the scope. The drawings are not to scale (unless so stated) and are intended for use in conjunction with the explanations in the following detailed description. Embodiments of the disclosure will hereinafter be described in conjunction with the appended drawings, wherein like numerals denote like elements.
FIG. 1 is a schematic showing a basic configuration of an MRAM cell, according to some embodiments.
FIGS. 2A-C are schematics showing a sequence of events associated with the application of a write current to the cell of FIG. 1.
FIGS. 3A-C are schematics showing various configurations of an MRAM cell, according to alternate embodiments.



DETAILED DESCRIPTION
The following detailed description is exemplary in nature and is not intended to limit the scope, applicability, or configuration in any way. Rather, the following description provides practical illustrations for implementing exemplary embodiments.
FIG. 1 is a schematic showing a basic configuration of an MRAM cell 100, according to some embodiments. FIG. 1 illustrates cell 100 including a pinned layer 112, a free ferromagnetic data storage layer 111, a first spacer layer 121, which extends between data storage layer 111 and pinned layer 112, a free ferromagnetic stabilization layer 113, which is directly electrically coupled to a first electrode contact layer 101, and a second spacer layer 131, which extends alongside stabilization layer 113, opposite first electrode contact layer 101, and between stabilization layer 113 and data storage layer 111. First spacer layer 121 is nonmagnetic and may be either conductive, for example, formed from metallic materials, such as Au, Ag, and Cu, or insulative, for example, formed from oxide and semiconductor barriers, such as AlO, TiO and MgO. FIG. 1 further illustrates pinned layer 112 of cell 100, which may either be a single layer or a synthetic antiferromagnetic coupled structure (SAF), being pinned by an adjacent antiferromagnetic pinning layer 110, which is directly electrically coupled to a second electrode contact layer 103. Those skilled in the art will appreciate that, although not shown, cell 100 is electrically coupled, via electrode contacts 101 and 103, to an intersection of a corresponding word line and bit line of an MRAM array, which may include on the order of 1,000, or more, intersecting word and bit lines and corresponding MRAM cells.
According to embodiments of the present disclosure, second spacer layer 131 is conductive and provides either ferromagnetic coupling or antiferromagnetic coupling between data storage layer 111 and stabilization layer 113, wherein a strength of the coupling is greater than a coercivity of the stabilization layer 113; when a magnetization orientation of data storage layer 111 is switched, or re-programmed, the magnetization orientation of stabilization layer 113 will follow, as will be further described in conjunction with FIG. 2C. The coupling between free layers 111, 113, whether ferromagnetic or antiferromagnetic, stabilizes cell 100 against, for example, inadvertent heat-induced switching. Free layers 111, 113 may be formed from transition metals, such as Ni, Co and Fe, alloys thereof, for example, NiFe and CoFe, or ternary alloys, such as CoFeB. According to an exemplary embodiment, stabilization layer 113 has a coercivity in a range from approximately 50 Oe to approximately 200 Oe, and is approximately 4 nm thick, and data storage layer 111 is approximately 3 nm thick. A thickness of second spacer layer 131 may be between approximately 2 nm and approximately 20 nm, and second spacer layer 131 may further provide for spin depolarization. Second spacer layer 131 may be formed from a conductive and antiferromagnetic material, such as FeMn, RhMn, FeRhMn, IrMn, PtMn, PdMn, PtPdMn, NiMn, CrMn or CrPtMn, or from a conductive and paramagnetic material, for example, formed by doping nonmagnetic metals, or alloys, such as Al, Cu, Ag and Pt, with magnetic atoms of, for example, Fe, Co, Ni, Cr or Mn. According to yet further embodiments, second spacer layer 131 is formed from a conductive and non-magnetic material, such as Al, Cu, Pt, Ag or Ru.
FIGS. 2A-C are schematics showing a sequence of events associated with the application of a write current to cell 100. FIG. 2A illustrates cell 100 in which data storage layer 111 has been programmed such that the magnetization orientation thereof is aligned with that of pinned layer 112. FIG. 2A further illustrates second spacer layer 131 providing for antiferromagnetic coupling between stabilization layer 113 and data storage layer 111, in order to stabilize the magnetization orientation of layer 111, until a write current is applied to cell 100 in order to re-program cell 100. FIG. 2B schematically illustrates the applied write current with an arrow W. As previously described, cell 100, is electrically coupled, via contacts 101 and 103, between a word line and bit line of an MRAM array such that a voltage potential, between the lines, drives write current W. FIG. 2B further illustrates, data storage layer 111 having been switched, or reprogrammed, to an opposite magnetization orientation, via a spin transfer effect of write current W. Once the magnetization orientation of layer 111 has been reversed, antiferromagnetic coupling between layer 111 and stabilization layer 113, will cause the magnetization orientation of layer 113 to reverse, as illustrated in FIG. 2C. In FIG. 2C, cell 100 is re-programmed and stabilized by the antiferromagnetic coupling between free layers 111 and 113.
The antiferromagnetic coupling between layers 111 and 113, which is illustrated by FIGS. 2A-C, may be achieved by magnetostatic coupling. Magnetostatic coupling, that has a significant coupling strength, can exist across second spacer layer 131, which has a thickness of over approximately 20 nm, and may be independent of a material that forms spacer layer 131. Alternately, ferromagnetic coupling may be achieved by Neel coupling (a.k.a. orange-peel coupling), which arises from interface roughness, or via RKKY interaction. RKKY coupling is oscillatory and can be either ferromagnetic or antiferromagnetic, depending upon a thickness of second spacer layer 131. The oscillation period is typically about 0.5 nm and also depends upon the materials from which spacer layer 131, and free layers 111, 113 are formed. By carefully choosing the spacer thickness and material, and by engineering the interface roughness to cancel out the magnetostatic coupling, a net ferromagnetic coupling can be achieved. A thickness of second spacer layer 131 that provides for ferromagnetic coupling may be less than approximately 10 nm.
FIGS. 3A-C are schematics showing various configurations of an MRAM cell 300A, 300B and 300C, respectively, according to alternate embodiments. Each of cells 300A-C is similar to cell 100 in that each includes electrode contact layers 101, 103, pinned layer 112, which is pinned by layer 110, first spacer layer 121, which separates pinned layer 112 from free ferromagnetic data storage layer 111, and free ferromagnetic stabilization layer 113. In contrast to cell 100, each of cells 300A-C includes a multi-layer conductive spacer layer 231A, 231B and 231C, respectively.
FIG. 3A illustrates conductive spacer layer 231A of cell 300A including a first sub-layer 21 and a second sub-layer 31, wherein second sub-layer 31 is directly adjacent data storage layer 111 and has a thickness that is less than that of first sub-layer 21. FIG. 3B illustrates conductive spacer layer 231B of cell 300B also including first and second sub-layers 21, 31, except that the arrangement thereof is reversed from that for cell 300A. According to some embodiments, first sub-layer 21 is non-magnetic and may have a thickness of approximately 4 nm, and second sub-layer 31 may either be antiferromagnetic or paramagnetic, and may have a thickness of approximately 2 nm. According to those embodiments in which second sub-layer 31 is paramagnetic, second sub-layer 31 may be formed by doping first sub-layer 21 with a magnetic material. FIG. 3C illustrates conductive spacer layer 231C of cell 300C including a first sub-layer 41, a second sub-layer 42 and a third sub-layer 43; first sub-layer 41 is directly adjacent data storage layer 111, second sub-layer 42 extends between first and third sub-layers 41, 43, and third sub-layer 43 is directly adjacent stabilization layer 113. FIG. 3C further illustrates first and third sub-layers 41, 43 having a thickness that is less than that of second sub-layer 42. According to some embodiments, second sub-layer 42 is non-magnetic and may have a thickness of approximately 4 nm, and first and third sub-layers 41, 43 are each either antiferromagnetic or paramagnetic and may each have a thickness of approximately 2 nm. According to some additional embodiments, first and third sub-layers 41, 43 are each non-magnetic and second sub-layer may be either antiferromagnetic or paramagnetic. Multi-layer conductive spacer layers 231A, 231B, 231C may be particularly suited to depolarize conduction electron spin orientation in order to prevent spin transfer in free ferromagnetic stabilization layer 113. It should be noted that material matching at the interfaces of the sub-layers for these multi-layer spacer layer embodiments is important to prevent interlayer mixing of atoms, due to thermal diffusion. Furthermore, the thicknesses of the sub-layers should be adjusted to achieve the desired magnetic coupling strength, spin-depolarization efficiency and diffusion-blocking ability. Examples of some suitable antiferromagnetic materials, which may be incorporated by multi-layer conductive spacer layers 231A, 231B, 231C, include, without limitation, FeMn, RhMn, FeRhMn, IrMn, PtMn, PdMn, NiMn, CrMn and CrPtMn. Examples of some suitable conductive non-magnetic materials for spacer layers 231A, 231B, 231C include, without limitation, Al, Cu, Pt, Ag, Au, Ru and alloys thereof; and these non-magnetic materials may be doped with magnetic atoms such as Fe, Co, Ni, Cr or Mn, to form suitable paramagnetic materials for layers 231A, 231B, 231C.
In the foregoing detailed description, embodiments of the disclosure have been described. These implementations, as well as others, are within the scope of the appended claims.

## Claims

1. An MRAM cell comprising:
a pinned layer having a predetermined magnetic orientation set by an adjacent antiferromagnetic pinning layer;
a spacer layer disposed between the pinned layer and a free ferromagnetic data storage layer; and
a multi-layered coupling layer disposed between the data storage layer and a free ferromagnetic stabilization layer, the coupling layer ferromagnetically coupling the data storage layer and stabilization layer in an anti-parallel magnetic relationship.

2. The MRAM cell of claim 1, further comprising a first electrode contact layer coupled to the stabilization layer and a second electrode contact layer coupled to the antiferromagnetic pinning layer.

3. The MRAM cell of claim 1, wherein the pinned layer comprises a synthetic antiferromagnetic coupled structure.

4. The MRAM cell of claim 1, wherein the coupling layer further provides for spin depolarization.

5. The MRAM cell of claim 1, wherein the coupling layer comprises an antiferromagnetic material.

6. The MRAM cell of claim 1, wherein the coupling layer comprises a paramagnetic material.

7. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer and a second paramagnetic sub-layer, the second sub-layer being directly adjacent the stabilization layer.

8. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer and a second paramagnetic sub-layer, the second sub-layer having a thickness that is less than that of the first sub-layer.

9. The MRAM cell of claim 8, wherein the second sub-layer is formed by doping a portion of the first sub-layer with a magnetic material.

10. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer and a second paramagnetic sub-layer, the second sub-layer being directly adjacent the data storage layer.

11. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer and a second paramagnetic sub-layer which achieves ferromagnetic coupling from interface roughness.

12. The MRAM cell of claim 11, wherein Neel coupling arises from the interface roughness.

13. The MRAM cell of claim 1, wherein:
the coupling layer includes a first paramagnetic sub-layer, a second non-magnetic sub-layer and a third paramagnetic sub-layer, the second sub-layer extending between the first and third sub-layers.

14. The MRAM cell of claim 1, wherein:
the coupling layer includes a first paramagnetic sub-layer, a second non-magnetic sub-layer and a third paramagnetic sub-layer,
the first and third sub-layers each have a thickness that is less than that of the second sub-layer.

15. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer, a second paramagnetic sub-layer and a third non-magnetic sub-layer, the second sub-layer extending between the first and third sub-layers.

16. The MRAM cell of claim 1, wherein:
the coupling layer includes a first non-magnetic sub-layer, a second paramagnetic sub-layer and a third non-magnetic sub-layer, the second layer having a thickness that is less than each of the first and third sub-layers.

17. An MRAM cell comprising:
a pinned layer;
an antiferromagnetic pinning layer, which pins the pinned layer;
a free ferromagnetic data storage layer;
a first spacer layer extending between the data storage layer and the pinned layer, the first spacer layer being nonmagnetic;
a free ferromagnetic stabilization layer;
a first electrode contact layer directly electrically coupled to the stabilization layer; and
a second spacer layer extending alongside the stabilization layer, opposite the first electrode contact layer and between the stabilization layer and the data storage layer, the second spacer layer including a first sub-layer and a second sub-layer, the second sub-layer having a thickness that is less than that of the first sub-layer; and
wherein the second spacer layer is conductive and provides for one of ferromagnetic coupling and antiferromagnetic coupling between the data storage layer and the stabilization layer;
the first sub-layer of the second spacer layer comprises a non-magnetic material;
the second sub-layer of the second spacer layer comprises a paramagnetic material and is formed by doping a portion of the first sub-layer with a magnetic material; and
a strength of the coupling between the data storage layer and the stabilization layer is greater than a coercivity of the stabilization layer.

18. The MRAM cell of claim 17, further comprising a second electrode contact layer directly coupled to the antiferromagnetic pinning layer.

19. A memory element comprising:
a pinned layer having a predetermined magnetic orientation set by an adjacent pinning layer;
a spacer layer disposed between the pinned layer and a free ferromagnetic data storage layer; and
a multi-layered coupling layer disposed between the data storage layer and a free ferromagnetic stabilization layer, the coupling layer comprising at least one non-magnetic layer and at least one magnetic layer.

20. The memory element of claim 19, wherein the non-magnetic layer has a greater thickness than the magnetic layer.