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Title:   Author  item
                                            Murray, Rexitem
                                            Walter, Erinitem
                                            Doll, Kenneth

                                                         - *Ken*
  Submitted to: Meeting Abstract
                                    Publication Type: Abstract Only
                                    Publication Acceptance Date: 8/13/2014
                                    Publication  Date: 9/15/2014
                                    Citation: Murray, R.E., Walter, E.L., Doll, K.M. 2014. Bio-olefins from unsaturated fatty acids via tandem catalysis [abstract]. Asia-Pacific Resilience Innovation Summit and Expo, 9/15/14-9/17/14, Honolulu, HI. www.islandsconnect.com/program. Poster 108.Interpretive Summary:
                                Technical Abstract: A new catalytic route to bio-olefins from unsaturated fatty acids will be described. At the heart of the process, the catalyst apparently functions in a tandem mode by both dynamically isomerizing the positions of double bonds in an aliphatic chain and, subsequently, decarboxylating specific isomers with lower activation barriers. A mechanistic pathway with supporting evidence for this novel catalytic chemistry will be presented. The approach opens up new methodology for converting fatty acids, such as oleic acid, into useful industrial chemical intermediates.


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