# Patent

## Title
Complementary metal oxide semiconductor image sensor and method for fabricating the same

## Abstract

A complementary metal oxide semiconductor (CMOS) device and a method for fabricating the same are provided. The CMOS image sensor includes: a first conductive type substrate including a trench; a channel stop layer formed by using a first conductive type epitaxial layer over an inner surface of the trench; a device isolation layer formed on the channel stop layer to fill the trench; a second conductive type photodiode formed in a portion of the substrate in one side of the channel stop layer; and a transfer gate structure formed on the substrate adjacent to the photodiode to transfer photo-electrons generated from the photodiode.

## Background
FIELD OF THE INVENTION
The present invention relates to an image sensor; and more particularly, to a complementary metal oxide semiconductor (CMOS) image sensor and a method for fabricating the same.
DESCRIPTION OF RELATED ARTS
Complementary metal oxide semiconductor (CMOS) devices have been widely used in mobile phones, cameras for personal computers and electronic appliances. The CMOS image sensors provide a simple operation method compared to charge coupled devices (CCD) which have been conventionally used as image sensors. Signal processing circuits can be integrated in one chip through using the CMOS image sensors. Thus, it is possible to embody a system on chip, thereby obtaining minimization of a module.
Furthermore, the CMOS image sensors have a lot of advantages including reducing production costs since the CMOS image sensors can use a set-up technology with compatibility.
FIG. 1 is a cross-sectional view illustrating a portion of a unit pixel of a conventional CMOS image sensor.
As shown in FIG. 1, a device isolation layer 12 is locally formed in a lower structure formed by stacking a highly doped P++-type substrate 10 and a lowly doped P−-type epitaxial layer (not shown). Hereinafter, the lower structure is referred as a semiconductor structure. A gate pattern 18 including a stack structure of a gate insulation layer 14 and a gate conductive layer 16 on the semiconductor structure, and a plurality of spacers 19 on both sidewalls of the gate pattern 18 form a transfer gate structure 20.
Also, a plurality of highly doped P+-type impurity regions 24 and 25, each serving a role as a P0-type impurity and as a channel stop layer respectively, and a lowly doped N−-type photodiode 21 are formed in a portion of the semiconductor structure aligned with one side of the transfer gate structure 20 through an ion-implantation process and a heat diffusion process. A highly doped N+-type floating diffusion region 22 is formed in a portion of the semiconductor structure aligned with the other side of the transfer gate structure 20.
At this time, the device isolation layer 12 serves a role in preventing an electron movement between neighboring pixels, i.e., a crosstalk event. Recently, to surely prevent the crosstalk event, a trench is formed deeply. However, if the trench is formed with a depth of several micrometers, it is possible to prevent electrons generated from a deep portion of the semiconductor structure from moving to the neighboring pixels; however, there may be a limitation that sidewalls of the trench deeply formed (hereinafter, referred to as a deep trench) cannot be all doped. Accordingly, a depletion layer of the photodiode 21 expands to the sidewalls of the deep trench and thus, a dark current may increase.
SUMMARY OF THE INVENTION
It is, therefore, an object of the present invention to a complementary metal oxide semiconductor (CMOS) image sensor capable of preventing a crosstalk event and a flow of dark current and a method for fabricating the same.
In accordance with one aspect of the present invention, there is provided a complementary metal oxide semiconductor (CMOS) image sensor, including: a first conductive type substrate including a trench; a channel stop layer formed by using a first conductive type epitaxial layer over an inner surface of the trench; a device isolation layer formed on the channel stop layer to fill the trench; a second conductive type photodiode formed in a portion of the substrate in one side of the channel stop layer; and a transfer gate structure formed on the substrate adjacent to the photodiode to transfer photo-electrons generated from the photodiode.
In accordance with another aspect of the present invention, there is provided a CMOS image sensor, including: a first conductive type substrate including a trench; a channel stop layer formed by using a first conductive type epitaxial layer to fill the trench; a second conductive type photodiode formed in a portion of the substrate in one side of the channel stop layer; and a transfer gate structure formed on the substrate adjacent to the photodiode to transfer photo-electrons generated from the photodiode.
In accordance with further aspect of the present invention, there is provided a method for fabricating a CMOS image sensor, including: preparing a first conductive type substrate including a trench; forming a first conductive type channel stop layer over an inner surface of the trench by performing an epitaxy process; forming a device isolation layer on the channel stop layer to fill the trench; forming a gate pattern for a transfer gate structure on the substrate in one side of the channel stop layer; forming spacers on sidewalls of the gate pattern; and forming a second conductive type photodiode in a portion of the substrate between the trench and the gate pattern by performing an ion-implantation process.
In accordance with still further aspect of the present invention, there is provided a method for fabricating a CMOS image sensor, including: preparing a first conductive type substrate including a trench; forming a first conductive type channel stop layer to fill the trench by performing an epitaxy process; forming a gate pattern for a transfer gate structure on the substrate in one side of the channel stop layer; forming spacers on sidewalls of the gate pattern; and forming a second conductive type photodiode in a portion of the substrate between the trench and the gate pattern by performing an ion-implantation process.



BRIEF DESCRIPTION OF THE DRAWINGS
The above and other objects and features of the present invention will become better understood with respect to the following description of the preferred embodiments given in conjunction with the accompanying drawings, in which:
FIG. 1 is a cross-sectional view illustrating a portion of a unit pixel of a conventional complementary metal oxide semiconductor (CMOS) image sensor;
FIG. 2 is a cross-sectional view illustrating a portion of a unit pixel of a CMOS image sensor in accordance with a first embodiment of the present invention;
FIGS. 3A to 3C are cross-sectional views illustrating a method for fabricating the CMOS image sensor shown in FIG. 2;
FIG. 4 is a cross-sectional view illustrating a portion of a unit pixel of a CMOS image sensor in accordance with a second embodiment of the present invention; and
FIGS. 5A to 5B are cross-sectional views illustrating a method for fabricating the CMOS image sensor shown in FIG. 4.



DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, detailed descriptions on preferred embodiments of the present invention will be provided with reference to the accompanying drawings.
Also, it should be noted that thicknesses of layers and regions are overstated to clearly define the layers and the regions in the specification. If it is written that a layer is formed on another layer or a substrate, the layer can be formed on said another layer or the substrate directly, or a third layer can be interposed between layers. Furthermore, the same reference numerals indicate the same constitution elements throughout the specification.
FIG. 2 is a cross-sectional view illustrating a portion of a unit pixel of a CMOS image sensor in accordance with a first embodiment of the present invention.
Referring to FIG. 2, the unit pixel of the CMOS image sensor in accordance with the first embodiment of the present invention includes: a highly doped P++-type substrate 110 provided with a deep trench (not shown); a channel stop layer 115 formed by using a highly doped P+-type epitaxial layer over an inner surface of the deep trench; a device isolation layer 130 formed on the channel stop layer 115 to fill the deep trench; a lowly doped N−-type photodiode 124 formed in a portion of the substrate 110 in one side of the channel stop layer 115; and a transfer gate structure 123 formed on the substrate 110 closed to the photodiode 124 to transfer photo-electrons generated from the photodiode 124. Furthermore, the unit pixel of the CMOS image sensor further includes a floating diffusion region 126 formed in a portion of the substrate 110 adjacent to the transfer gate structure 123 and opposite to the photodiode 124.
At this time, the transfer gate structure 123 includes a gate pattern 120 formed by using a gate insulation layer 117 and a gate conductive layer 119, and a plurality of spacers 122 formed on both sidewalls of the gate pattern 120. Particularly, the gate conductive layer 119 is formed by using one selected from the group consisting of polysilicon, tungsten silicide and a stack layer thereof. The plurality of spacers 122 are formed by using a nitride layer, an oxide layer or an oxynitride layer.
Although not shown, a highly doped P+-type epitaxial layer is stacked on the highly concentrated P+-type substrate 110. At this time, the substrate 110 is a single crystal silicon layer.
That is, in accordance with the first embodiment of the present invention, the epitaxial grown channel stop layer 115 is formed by being doped in a conductive type which is opposite to that of the photodiode 124 over the inner surface of the deep trench. Thus, it is possible to form the uniform channel stop layer 115 although a line width of the trench is narrow and a depth of the trench is deep. Accordingly, it is possible to prevent not only a crosstalk event of the CMOS image sensor from being generated but also dark current from flowing.
FIGS. 3A to 3C are cross-sectional views illustrating a method for fabricating the CMOS image sensor in accordance with the first embodiment of the present invention shown in FIG. 2.
First, as shown in FIG. 3A, a pad oxide layer 111 and a pad nitride layer 112 are deposited on a highly doped P++-type substrate 110. At this time, a lowly doped P−-type epitaxial layer (not shown) is formed on an upper portion of the substrate 110.
Next, a deep trench isolation (DTI) etching process is performed, thereby deeply forming a trench, i.e., a deep trench, in the substrate 110. For instance, a mask process and an etching process are employed and then, a predetermined mask pattern (not shown) is formed on the pad nitride layer 112. Afterwards, an etching process is performed by using the mask pattern, thereby etching predetermined portions of the pad nitride layer 112, the pad oxide layer 111 and the substrate 110. Hence, the aforementioned deep trench 113 is formed in a portion of the substrate 110. Afterwards, the mask pattern is removed through a strip process.
At this time, a device isolation is performed through a typical shallow trench isolation (STI) process in remaining portions except the unit pixel.
Next, as shown in FIG. 3B, an epitaxy process is performed by using an in-situ method, thereby growing the highly doped P+-type channel stop layer 115 over an inner surface of the deep trench 113. At this time, a first conductive type impurity diffusion region can be formed on the substrate in which the photodiode is formed (hereinafter, referred to as a photodiode region). For instance, the pad nitride layer 112 and the pad oxide layer 111 exiting on the photodiode region are etched and afterwards, the epitaxy process is performed, thereby forming the channel stop layer 115 on the substrate 110 of the photodiode region.
Next, as shown in FIG. 3C, the pad nitride layer 112 and the pad oxide layer 111 are removed through a wet etching process.
Next, a high density plasma (HDP) oxide layer is deposited on the channel oxide layer 115 to fill the deep trench. Afterwards, the deposited HDP oxide layer is planarized and thus, a device isolation layer 130 is formed. At this time, the device isolation layer 130 is formed in a predetermined height from a lower portion of the deep trench 113 to prevent a gate conductive layer 119 which will be deposited through a substrate process from remaining inside the trench 113.
Next, a gate insulation layer 117 is formed on an entire layer including the device isolation layer 130 and afterwards, the aforementioned gate conductive layer 119 is formed on the gate insulation layer 117. In more detail, a gate oxide layer is formed through an oxidation process and afterwards, a conductive material such as polysilicon is deposited through a chemical vapor deposition (CVD) method.
Next, predetermined portions of the gate conductive layer 119 and the gate insulation layer 117 are etched, thereby forming a gate pattern 120 for a transfer gate structure 123 on the substrate 110. Afterwards, a plurality of spacers 122 formed by using an insulation layer are formed on both sidewalls of the gate pattern 120.
Next, an ion-implantation process is employed by using a predetermined mask pattern, thereby forming a photodiode 124 in a portion of the substrate 110 between the channel stop layer 115 and the gate pattern 120. For instance, the lowly doped N−-type photodiode 124 is formed by implanting an N-type impurity such as phosphorous (P) or arsenic (As).
Next, a floating diffusion region 126 is formed in a portion of the substrate 110 adjacent to the gate pattern 120 and opposite to the photodiode 124 by performing an ion-implantation process.
FIG. 4 is a cross-sectional view illustrating a portion of a unit pixel of a CMOS image sensor in accordance with a second embodiment of the present invention.
Referring to FIG. 4, the unit pixel of the CMOS image sensor in accordance with the second embodiment of the present invention includes: a highly doped P++-type substrate 210 provided with a trench (not shown); a channel stop layer 215 formed by using a highly doped P+-type epitaxial layer to fill the trench; a lowly doped N−-type photodiode 224 formed in a portion of the substrate 210 in one side of the channel stop layer 215; and a transfer gate structure 223 formed on the substrate 210 closed to the photodiode 224 to transfer photo-electrons generated from the photodiode 224. Furthermore, the unit pixel of the CMOS image sensor further includes a floating diffusion region 226 formed in a portion of the substrate 210 adjacent to the transfer gate structure 223 and opposite to the photodiode 224.
That is, compared with the first embodiment of the present invention which the channel stop layer 115 is formed over the inner surface of the trench, the channel stop layer 215 is formed by filling the entire trench in accordance with the second embodiment of the present invention. Accordingly, since an additional process for forming a device isolation layer is not necessary, it is possible to simplify a CMOS image sensor fabrication process.
FIGS. 5A and 5B are cross-sectional views illustrating a method for fabricating the CMOS image sensor in accordance with the second embodiment of the present invention shown in FIG. 4.
First, as shown in FIG. 5A, similar to the first embodiment of the present invention, a highly doped P+-type substrate 210 including a deep trench (not shown) is provided. For instance, predetermined portions of a pad oxide layer 211 and a pad nitride layer 212 formed on the substrate 210 are etched, thereby forming a deep trench in the substrate 210.
Next, as shown in FIG. 5B, an epitaxy process is performed by using an in-situ method and thus, a highly doped P+-type channel stop layer 215 is grown until the deep trench (not shown) is filled.
Next, a wet etching process is performed, thereby removing the pad nitride layer 212 and the pad oxide layer 211.
Next, a transfer gate structure 223 is formed through the method used in the first embodiment of the present invention. Afterwards, an ion-implantation process is employed, thereby forming a photodiode 224 in a portion of the substrate 210 between the transfer gate structure 223 and the channel stop layer 215. In more detail, a lowly doped N−-type ion is implanted and thus, the lowly doped N−-type photodiode 224 is formed. Herein, the transfer gate structure 223 includes a gate pattern 200 formed in a stack structure of a gate insulation layer 217 and a gate conductive layer 219, and a plurality of spacers 222 formed on both sidewalls of the gate pattern 220.
Next, an ion-implantation process is performed and then, a floating diffusion region 226 is formed in a portion of the substrate 210 adjacent to the transfer gate structure 223 an opposite to the photodiode 224. Preferably, a highly doped N+-type impurity is implanted, thereby forming the highly doped N+-type floating diffusion region 226.
On the basis of the present invention, a deep trench is formed in a substrate and then, an epitaxial grown channel stop layer is formed over an inner surface of the deep trench. Thus, it is possible to form the uniform channel stop layer on sidewalls of the deep trench. Accordingly, it is possible to prevent not only a crosstalk event but also a flow of dark current. Hence, efficiency of CMOS image sensors is greatly improved.
The present application contains subject matter related to the Korean patent application No. KR 2005-0085676, filed in the Korean Patent Office on Sep. 14, 2005, the entire contents of which being incorporated herein by reference.
While the present invention has been described with respect to certain preferred embodiments, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the following claims.

## Claims

1. A complementary metal oxide semiconductor (CMOS) image sensor, comprising:
a first conductive type substrate including a trench;
a channel stop layer formed by using a first conductive type epitaxial layer over an inner surface of the trench;
a device isolation layer formed on the channel stop layer to fill the trench;
a second conductive type photodiode formed in a portion of the substrate in one side of the channel stop layer;
a transfer gate structure formed on the substrate adjacent to the photodiode to transfer photo-electrons generated from the photodiode; and
a floating diffusion region formed in a portion of the substrate opposite to the photodiode and adjacent to the transfer gate structure to receive the photo-electrons from the transfer gate structure,
wherein bottom portions of the channel stop Layer are located in a deeper position from the surface of the first conductive type substrate than bottom portions of the second conductive type photodiode.

2. The CMOS image sensor of claim 1, further including a first conductive type impurity diffusion region on the substrate in which the photodiode is formed.

3. The CMOS image sensor of claim 2, wherein the device isolation layer is formed with a predetermined height from a lower portion of the trench to prevent a conductive material of the transfer gate structure from remaining inside the trench.