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Bromoform																				Related Pages
Synonyms & Trade Names
			Methyl tribromide, Tribromomethane
CAS No.
			75-25-2
	RTECS No.
			PB5600000
	DOT ID & Guide
			2515 159

FormulaCHBr3
	Conversion
			1 ppm = 10.34 mg/m3
	IDLH
			850 ppmSee: 75252

Exposure Limits
			NIOSH RELTWA 0.5 ppm (5 mg/m3) [skin]
					OSHA PEL TWA 0.5 ppm (5 mg/m3) [skin]
	Measurement Methods
			**NIOSH** 1003;**OSHA** 7
					
					See: NMAM or OSHA Methods
										
Physical Description
			Colorless to yellow liquid with a chloroform-like odor.
					[Note: A solid below 47°F.]													
										
Molecular Weight252.8	
	Boiling Point301°F
	Freezing Point47°F
	Solubility0.1%
	Vapor Pressure5 mmHg
	Ionization Potential10.48 eV											
Specific Gravity2.89	
	Flash PointNA
	Upper Explosive LimitNA
	Lower Explosive LimitNA
Noncombustible Liquid
Incompatibilities & Reactivities
			Lithium, sodium, potassium, calcium, aluminum, zinc, magnesium, strong caustics, acetone
					[Note: Gradually decomposes, acquiring yellow color; air & light accelerate decomposition.]
Exposure Routes
			inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms
			irritation eyes, skin, respiratory system; central nervous system depression; liver, kidney damage
Target Organs
			Eyes, skin, respiratory system, central nervous system, liver, kidneys
										
Personal Protection/Sanitation
			(See protection codes) **Skin:**Prevent skin contact
							**Eyes:**Prevent eye contact
							**Wash skin:**When contaminated
							**Remove:**When wet or contaminated
							**Change:**No recommendation
	First Aid
			(See procedures)**Eye:**Irrigate immediately
							**Skin:**Soap wash promptly
							**Breathing:**Respiratory support
							**Swallow:**Medical attention immediately
Respirator Recommendations
			**NIOSH/OSHA****Up to 12.5 ppm**: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode£(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s)£**Up to 25 ppm**: (APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s)£(APF = 50) Any self-contained breathing apparatus with a full facepiece(APF = 50) Any supplied-air respirator with a full facepiece**Up to 850 ppm**: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode**Emergency or planned entry into unknown concentrations or IDLH conditions:** (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus**Escape:** (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canisterAny appropriate escape-type, self-contained breathing apparatus
				Important additional information about respirator selection
See also
			INTRODUCTION
					  ICSC CARD: 0108

			
							

			Page last reviewed:  October 30, 2019						Content
							source: 	National Institute for Occupational Safety and Health NIOSH Pocket Guide to Chemical Hazards
Introduction
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Appendices
A – NIOSH Potential Occupational Carcinogens
B – Thirteen OSHA-Regulated Carcinogens
C – Supplementary Exposure Limits
D – Substances with No Established RELs
E – OSHA Respirator Requirements for Selected Chemicals
F – Miscellaneous Notes
G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect
Type C & CE – Definitions for Type C and Type CE Respirators
Personal Protection and Sanitation Codes
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