# Patent

## Title
Particles for malodor reduction

## Abstract

A composition including a plurality of particles, wherein the particles include: about 30% to about 95% by weight of a carrier; about 0.1% to about 30% by weight of a perfume; and about 0.00025% to about 30% by weight of a malodor agent; wherein the malodor agent comprises one or more malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and wherein each of the particles has a mass between about 0.1 mg to about 5 g.

## Background
FIELD OF THE INVENTION
Particles including malodor reduction compositions and methods of using such particles for managing malodor in laundry articles.
BACKGROUND OF THE INVENTION
Laundry articles having significant malodors is a problem that continues to face consumers.
People enjoy wearing garments that smell fresh and clean. Maintaining a full wardrobe that is populated with a sufficient number of garments that are fresh and clean can be a burden on many people because they are too busy to regularly spend their time taking care of their laundry and do not wish to pay for a service that will take care of their laundry. Further, many people have garments that comprise fabrics or appurtenances that may not be durable enough to withstand multiple wearing, washing, and drying cycles without a the appearance or function of the garment being degraded.
To compensate for these problems, many people wear garments multiple times before they launder the garment. In many circumstances, wearing a garment multiple times between washings or dry cleaning is fine. A shirt, pants, or skirt may be worn multiple times between washings if the garment has not picked up any visible stains, the person has not perspired appreciably, the person has not been in an environment having odiferous air such as a smoky environment, restaurant selling strong smelling foods, or the person has not contacted strongly smelling objects such as a pet. However, the typical experience for most people is that they do perspire, are in environments where strong odors are present, or come into contact with smelly pets and the like. So even if a person avoids acquiring a stain or smudge on their garment during wear, it is probable that the garment has picked up some odors during wear.
Sometimes laundered garments are stored in a closet for weeks or months prior to being worn. By the time the garment is worn, the scent of the garment acquired during laundering has worn off. Depending on the environment in which the garment is stored, the garment may have a neutral or no odor or may have a musty, moldy, stale malodor. The malodors associated with long term storage of garments can negatively impact the experience of the person, and those around her, who chooses to wear a garment that has been stored for an appreciable period of time.
A similar situation arises when a person wants to continue to wear an article of clothing that has been worn earlier in the day. For example, after getting off work, a person may want to go out with friends to a restaurant, pub, or movie. After wearing the clothing during the work day, the clothing may have a neutral or non-noticeable odor, or even worse may have an unattractive odor that was acquired during the course of the day. The neutral or even negative malodor can have a negative impact on the psyche of the wearer and form a negative impression upon the people around the wearer of such a garment.
Similar problems can be associated with storing laundry articles that have been worn. With wear, clothing can become sweaty and smelly. Prior to laundering, the soiled laundry article might be stored in a gym bag, trunk of the car, laundry hamper, or pile of clothing. Over time, the level of malodor can increase to a degree such that it becomes repulsive for the consumer and those around her. Further, the malodor may be experienced by the consumer when she handles the soiled laundry prior to washing.
Common malodors and sources thereof can include amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C2-C12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew). The typical technical approach for managing malodors is to apply a malodor reduction ingredient or to mask the malodor with perfume. Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed laundry article that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is constraining.
With these limitations in mind, there is a continuing unaddressed need for technologies for managing malodors in laundered and soiled laundry articles.
SUMMARY OF THE INVENTION
A composition comprising a plurality of particles, wherein said particles comprise: about 30% to about 95% by weight of a carrier; about 0.1% to about 30% by weight of a perfume; and about 0.00025% to about 30% by weight of a malodor agent; wherein said malodor agent comprises from about 1 to about 30 malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and wherein each of said particles has a mass between about 0.1 mg to about 5 g.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a particle.
FIG. 2 is a package containing particles.
FIG. 3 is a package containing particles.



DETAILED DESCRIPTION OF THE INVENTION
As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein, the term “perfume” does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value “MORV” that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.
As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.
Malodor Reduction Materials
A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical identifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3and there for Tables 4, 5and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.










Codes















A = Vapor Pressure > 0.1 torr


B = Vapor Pressure is between 0.01 torr and 0.1 torr


C = logP < 3


D = logP > 3


E = Probability of Ingredient Color Instability = 0%


F = Probability of Ingredient Color Instability < 71%


G = Odor Detection Threshold less than p.ol = 8


H = Odor Detection Threshold greater than p.ol = 8


I = Melamine formaldehyde PMC Headspace Response Ratio greater than


or equal to 10


J = Melamine formaldehyde PMC leakage less than or equal to 5%


K = Log of liquid dish neat product liquid-air partition coefficient greater


than or equal to −7


L = Log of liquid dish neat product liquid-air partition coefficient greater


than or equal to −5
















TABLE 1







List of materials with at least one MORV from 1 to 5










Num-

CAS
Comment


ber
Material Name
Number
Code













1
2-ethylhexyl (Z)-3-(4-
5466-77-3
DEFHJ



methoxyphenyl)acrylate


2
2,4-dimethyl-2-(5,5,8,8-tetramethyl-
131812-67-4
DFHJ



5,6,7,8-tetrahydronaphthalen-2-yl)-



1,3-dioxolane


3
1,1-dimethoxynon-2-yne
13257-44-8
ACEFHJK


4
para-Cymen-8-ol
1197-01-9
BCGIJK


7
3-methoxy-7,7-dimethyl-10-
216970-21-7
BDEFHJK



methylenebicyclo[4.3.1]decane


9
Methoxycyclododecane
2986-54-1
DEFHJK


10
1,1-dimethoxycyclododecane
950-33-4
DEFHJK


11
(Z)-tridec-2-enenitrile
22629-49-8
DEFHJK


13
Oxybenzone
131-57-7
DEFGJ


14
Oxyoctaline formate
65405-72-3
DFHJK


16
4-methyl-1-oxaspiro[5.5]undecan-4-
57094-40-3
CFGIJK



ol


17
7-methyl-2H-benzo[b][1,4]dioxepin-
28940-11-6
CGIK



3(4H)-one


18
1,8-dioxacycloheptadecan-9-one
1725-01-5
DGJ


21
4-(tert-pentyl)cyclohexan-1-one
16587-71-6
ADFGIJKL


22
o-Phenyl anisol
86-26-0
DEFHJK


23
3a,5,6,7,8,8b-hexahydro-
823178-41-2
DEFHJK



2,2,6,6,7,8,8-heptamethyl-4H-



indeno(4,5-d)-1,3-dioxole


25
7-isopropyl-8,8-dimethyl-6,10-
62406-73-9
BDEFHIJK



dioxaspiro[4.5]decane


28
Octyl 2-furoate
39251-88-2
DEFHJK


29
Octyl acetate
112-14-1
BDEFHJKL


30
octanal propylene glycol acetal
74094-61-4
BDEFHJKL


31
Octanal
124-13-0
ACHIKL


32
Octanal dimethyl acetal
10022-28-3
ACEFGJKL


33
Myrcene
123-35-3
ADEFGIKL


34
Myrcenol
543-39-5
BCEFGIJK


35
Myrcenyl acetate
1118-39-4
ADEFGJK


36
Myristaldehyde
124-25-4
DFHJK


37
Myristicine
607-91-0
CGJK


38
Myristyl nitrile
629-63-0
DEFHJK


39
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-
103614-86-4
DEFHIJK



octahydronaphthalen-1-ol


42
Ocimenol
5986-38-9
BCHIJK


43
Ocimenol
28977-58-4
BCHIJK


47
Nopyl acetate
128-51-8
DEFHJK


48
Nootkatone
4674-50-4
DHJK


49
Nonyl alcohol
143-08-8
BDEFGIJKL


50
Nonaldehyde
124-19-6
ADHIKL


52
12-methyl-14-tetradec-9-enolide
223104-61-8
DFHJK


57
N-ethyl-p-menthane-3-carboxamide
39711-79-0
DEFGIJK


61
1-(3-methylbenzofuran-2-yl)ethan-1-
23911-56-0
CEFHIK



one


62
2-methoxynaphthalene
93-04-9
BDEFHK


63
Nerolidol
7212-44-4
DEFHJK


64
Nerol
106-25-2
BCHIK


65
1-ethyl-3-
31996-78-8
ACEFHIJKL



methoxytricyclo[2.2.1.02,6]heptane


67
Methyl (E)-non-2-enoate
111-79-5
ADEFHJKL


68
10-isopropyl-2,7-dimethyl-1-
89079-92-5
BDEFHIJK



oxaspiro[4.5]deca-3,6-diene


69
2-(2-(4-methylcyclohex-3-en-1-
95962-14-4
DHJK



yl)propyl)cyclopentan-1-one


70
Myrtenal
564-94-3
ACFHIJKL


71
(E)-4-(2,2,3,6-
54992-90-4
BDEFHIJK



tetramethylcyclohexyl)but-3-en-2-



one


74
Myraldyl acetate
53889-39-7
DHJK


75
Musk tibetine
145-39-1
DHIJ


76
1,7-dioxacycloheptadecan-8-one
3391-83-1
DGJ


77
Musk ketone
81-14-1
DHJ


78
Musk ambrette
83-66-9
DHIJ


79
3-methylcyclopentadecan-1-one
541-91-3
DEFHJK


80
(E)-3-methylcyclopentadec-4-en-1-
82356-51-2
DHJK



one


82
3-methyl-4-phenylbutan-2-ol
56836-93-2
BCEFHIK


83
1-(4-isopropylcyclohexyl)ethan-1-ol
63767-86-2
BDEFHIJK


85
Milk Lactone
72881-27-7
DEFHJK


91
Methyl octine carbonate
111-80-8
BDEFHKL


92
Methyl octyl acetaldehyde
19009-56-4
ADFHJKL


93
6,6-dimethoxy-2,5,5-trimethylhex-2-
67674-46-8
ACHIJKL



ene


98
Methyl phenylethyl carbinol
2344-70-9
BCEFHIK


100
Methyl stearate
112-61-8
DEFHJ


101
Methyl nonyl acetaldehyde dimethyl
68141-17-3
BDEFHJK



acetal


102
Methyl nonyl ketone
112-12-9
BDFHJKL


103
Methyl nonyl acetaldehyde
110-41-8
BDFHJK


104
Methyl myristate
124-10-7
DEFHJK


105
Methyl linoleate
112-63-0
DEFHJ


106
Methyl lavender ketone
67633-95-8
CFHJK


108
Methyl isoeugenol
93-16-3
ACEFHK


109
Methyl hexadecanoate
112-39-0
DEFHJK


110
Methyl eugenol
93-15-2
ACEFHK


112
Methyl epijasmonate
1211-29-6
CHJK


113
Methyl dihydrojasmonate
24851-98-7
DFHJK


114
Methyl diphenyl ether
3586-14-9
DEFHJK


117
Methyl cinnamate
103-26-4
BCEFHK


119
Methyl chavicol
140-67-0
ADEFHK


120
Methyl beta-naphthyl ketone
93-08-3
CEFHK


122
Methyl 2-octynoate
111-12-6
ACEFHKL


123
Methyl alpha-cyclogeranate
28043-10-9
ACHIJKL


126
Methoxycitronellal
3613-30-7
ACFGIJK


128
Menthone 1,2-glycerol ketal
67785-70-0
CEFHJ



(racemic)


130
Octahydro-1H-4,7-methanoindene-1-
30772-79-3
BCFHIJKL



carbaldehyde


134
3-(3-(tert-butyl)phenyl)-2-
62518-65-4
BDHJK



methylpropanal


135
(E)-4-(4,8-dimethylnona-3,7-dien-1-
38462-23-6
DEFHJK



yl)pyridine


137
(E)-trideca-3,12-dienenitrile
134769-33-8
DEFHJK


140
2,2-dimethyl-3-(m-tolyl)propan-1-ol
103694-68-4
CEFHIJK


141
2,4-dimethyl-4,4a,5,9b-
27606-09-3
CEFHJK



tetrahydroindeno[1,2-d][1,3]dioxine


142
Maceal
67845-30-1
BDFHJK


143
4-(4-hydroxy-4-
31906-04-4
CHJ



methylpentyl)cyclohex-3-ene-1-



carbaldehyde


145
1-Limonene
5989-54-8
ADEFGIJKL


146
(Z)-3-hexen-1-yl-2-cyclopenten-1-
53253-09-1
BDHK



one


148
Linalyl octanoate
10024-64-3
DEFHJ


149
Linalyl isobutyrate
78-35-3
BDHJK


152
Linalyl benzoate
126-64-7
DFHJ


153
Linalyl anthranilate
7149-26-0
DFHJ


155
Linalool oxide (furanoid)
60047-17-8
BCHIJK


156
linalool oxide
1365-19-1
CGIJK


158
(2Z,6E)-3,7-dimethylnona-2,6-
61792-11-8
BDEFHJK



dienenitrile


159
3-(4-methylcyclohex-3-en-1-
6784-13-0
ACFHIJK



yl)butanal


161
(2,5-dimethyl-1,3-dihydroinden-2-
285977-85-7
CEFHJK



yl)methanol


162
3-(4-(tert-butyl)phenyl)-2-
80-54-6
BDHJK



methylpropanal


167
(E)-1-(1-methoxypropoxy)hex-3-ene
97358-54-8
ACEFGJKL


168
Leaf acetal
88683-94-7
ACEFGJKL


170
1-Carveol
2102-58-1
BCHIJK


174
Lauryl alcohol
112-53-8
DEFGJK


175
Lauryl acetate
112-66-3
DEFHJK


176
Lauric acid
143-07-7
DEFHJ


177
Lactojasmone
7011-83-8
BDEFHIJKL


178
Lauraldehyde
112-54-9
BDFHJK


179
3,6-dimethylhexahydrobenzofuran-
92015-65-1
BCEFHIJKL



2(3H)-one


182
4-(1-ethoxyvinyl)-3,3,5,5-
36306-87-3
BDFHIJK



tetramethylcyclohexan-1-one


183
Khusimol
16223-63-5
CEFHJK


184
5-(sec-butyl)-2-(2,4-
117933-89-8
DEFHJ



dimethylcyclohex-3-en-1-yl)-5-



methyl-1,3-dioxane


185
(1-methyl-2-((1,2,2-
198404-98-7
DEFHJK



trimethylbicyclo[3.1.0]hexan-3-



yl)methyl)cyclopropyl)methanol


186
2-propylheptanenitrile
208041-98-9
ADEFHIJKL


187
(E)-6-(pent-3-en-1-yl)tetrahydro-2H-
32764-98-0
BCFHIKL



pyran-2-one


189
2-hexylcyclopentan-1-one
13074-65-2
BDFHJKL


190
2-methyl-4-phenyl-1,3-dioxolane
33941-99-0
BCEFGIK


192
2,6,9,10-tetramethyl-1-
71078-31-4
BDEFHIJK



oxaspiro(4.5)deca-3,6-diene


193
Isopulegol
89-79-2
BCEFHIJKL


195
Isopropyl palmitate
142-91-6
DEFHJ


196
Isopropyl myristate
110-27-0
DEFHJK


197
Isopropyl dodecanoate
10233-13-3
DEFHJK


199
Isopimpinellin
482-27-9
CFGJ


206
Iso3-methylcyclopentadecan-1-one
3100-36-5
DEFGJK


208
Isomenthone
491-07-6
ADEFGIJKL


209
Isojasmone
95-41-0
BDFHJKL


210
Isomenthone
36977-92-1
ADEFGIJKL


211
Isohexenyl cyclohexenyl
37677-14-8
DFHJK



carboxaldehyde


212
Isoeugenyl benzyl ether
120-11-6
DFHJ


215
1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2
DHJK



1,2,3,4,5,6,7,8-octahydronaphthalen-



2-yl)ethan-1-one


218
Isocyclocitral
1335-66-6
ACFHIJKL


221
Isobutyl quinoline
65442-31-1
DEFHJK


227
Isobornylcyclohexanol
68877-29-2
DEFHJK


228
Isobornyl propionate
2756-56-1
BDEFHIJK


229
Isobornyl isobutyrate
85586-67-0
BDEFHIJK


230
Isobornyl cyclohexanol
66072-32-0
DEFHJK


231
Isobornyl acetate
125-12-2
ADEFHIJKL


233
Isobergamate
68683-20-5
DEFHJK


234
Isoamyl undecylenate
12262-03-2
DEFHJK


238
Isoamyl laurate
6309-51-9
DEFHJK


242
Isoambrettolide
28645-51-4
DGJ


243
Irisnitrile
29127-83-1
ADEFHKL


244
Indolene
68527-79-7
DEFHJ


246
Indol/Hydroxycitronellal Schiff base
67801-36-9
DEFHJ


247
4,4a,5,9b-tetrahydroindeno[1,2-
18096-62-3
BCEFGJK



d][1,3]dioxine


249
Hydroxy-citronellol
107-74-4
CEFGIJK


252
2-cyclododecylpropan-1-ol
118562-73-5
DEFHJK


253
Hydrocitronitrile
54089-83-7
CEFHJK


254
Hydrocinnamyl alcohol
122-97-4
BCEFHIK


256
Hydratropaldehyde dimethyl acetal
90-87-9
ACEFHJK


259
5-ethyl-4-hydroxy-2-methylfuran-
27538-09-6
CFGIK



3(2H)-one


260
2,3-dihydro-3,3-dimethyl-1H-indene-
173445-44-8
DHJK



5-propanal


261
3-(3,3-dimethyl-2,3-dihydro-1H-
173445-65-3
DHJK



inden-5-yl)propanal


263
Hexyl octanoate
1117-55-1
DEFHJK


267
Hexyl hexanoate
6378-65-0
DEFHJKL


269
Hexyl cinnamic aldehyde
101-86-0
DHJ


271
Hexyl benzoate
6789-88-4
DEFHJK


274
Hexenyl tiglate
84060-80-0
BDEFHJK


276
(E)-3,7-dimethylocta-2,6-dien-1-yl
3681-73-0
DEFHJ



palmitate


277
Hexadecanolide
109-29-5
DEFGJK


278
2-butyl-4,4,6-trimethyl-1,3-dioxane
54546-26-8
ADEFHIJKL


280
Ethyl (1R,2R,3R,4R)-3-
116126-82-0
BDEFHIJK



isopropylbicyclo[2.2.1]hept-5-ene-2-



carboxylate


281
3a,4,5,6,7,7a-hexahydro-1H-4,7-
5413-60-5
CEFGJK



methanoinden-6-yl acetate


285
2-(1-(3,3-
141773-73-1
DEFHJ



dimethylcyclohexyl)ethoxy)-2-



methylpropyl propionate


286
Heliotropine diethyl acetal
40527-42-2
CEFGJ


288
Helional
1205-17-0
CHJK


289
(E)-oxacyclohexadec-13-en-2-one
111879-80-2
DGJK


290
Gyrane
24237-00-1
ADEFHIJKL


292
Guaiol
489-86-1
DEFHJK


293
1-(2,6,6-trimethylcyclohex-2-en-1-
68611-23-4
DHJK



yl)pentan-3-one


294
Ethyl 2-ethyl-6,6-dimethylcyclohex-
57934-97-1
BDEFHIJK



2-ene-1-carboxylate


295
Germacrene B
15423-57-1
DEFHJK


296
Germacrene D
23986-74-5
DEFHJK


300
Geranyl phenylacetate
102-22-7
DFHJ


301
Geranyl phenyl acetate
71648-43-6
DFHJ


303
Geranyl linalool
1113-21-9
DFHJ


307
Geranyl cyclopentanone
68133-79-9
DHJK


316
gamma-Undecalactone (racemic)
104-67-6
DEFHJKL


317
gamma-Terpinyl acetate
10235-63-9
BDHJK


318
gamma-Terpineol
586-81-2
BCGIJK


321
gamma-Nonalactone
104-61-0
BCEFHIKL


322
gamma-Muurolene
30021-74-0
DEFHJKL


323
gamma-(E)-6-(pent-3-en-1-
63095-33-0
BCEFHKL



yl)tetrahydro-2H-pyran-2-one


324
gamma-Ionone
79-76-5
BDEFHIJK


325
gamma-Himachalene
53111-25-4
BDEFHJKL


328
gamma-Gurjunene
22567-17-5
DEFHJKL


329
gamma-Eudesmol
1209-71-8
DFHJK


330
gamma-Dodecalactone
2305-05-7
DEFHJK


331
gamma-Damascone
35087-49-1
BDEFHIJK


332
gamma-Decalactone
706-14-9
BDEFHIJKL


333
gamma-Cadinene
39029-41-9
DEFHJKL


334
1-(3,3-dimethylcyclohexyl)pent-4-
56973-87-6
BDEFHJK



en-1-one


335
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-
1222-05-5
DEFHJK



hexahydrocyclopenta[g]isochromene


336
Furfuryl octanoate
39252-03-4
DEFHJK


338
Furfuryl hexanoate
39252-02-3
CEFHJK


339
Furfuryl heptanoate
39481-28-2
CEFHJK


342
2-methyldecanenitrile
69300-15-8
BDEFHJKL


343
8,8-dimethyl-3a,4,5,6,7,7a-
76842-49-4
DEFHJK



hexahydro-1H-4,7-methanoinden-6-



yl propionate


344
Ethyl (3aR,4S,7R,7aR)-octahydro-
80657-64-3
DEFHIJK



3aH-4,7-methanoindene-3a-



carboxylate


347
Diethyl cyclohexane-1,4-
72903-27-6
CEFHJK



dicarboxylate


349
(6-isopropyl-9-methyl-1,4-
63187-91-7
CEFHJ



dioxaspiro[4.5]decan-2-yl)methanol


350
2-isobutyl-4-methyltetrahydro-2H-
63500-71-0
BCEFHIJK



pyran-4-ol


352
Undec-10-enenitrile
53179-04-7
BDEFHJK


353
(Z)-6-ethylideneoctahydro-2H-5,8-
69486-14-2
CEFGJK



methanochromen-2-one


356
3-(2-ethylphenyl)-2,2-
67634-15-5
BDHJK



dimethylpropanal


358
(E)-4,8-dimethyldeca-4,9-dienal
71077-31-1
BDFHJK


359
(E)-4-((3aR,4R,7R,7aR)-
501929-47-1
DEFHJK



1,3a,4,6,7,7a-hexahydro-5H-4,7-



methanoinden-5-ylidene)-3-



methylbutan-2-ol


360
8,8-dimethyl-3a,4,5,6,7,7a-
171102-41-3
DEFHJK



hexahydro-1H-4,7-methanoinden-6-



yl acetate


361
3-(4-ethylphenyl)-2,2-
134123-93-6
DEFHJK



dimethylpropanenitrile


362
2-heptylcyclopentan-1-one
137-03-1
DFHJKL


363
1-ethoxyethoxy Cyclododecane
389083-83-4
DEFHJK


364
3-cyclohexene-1-carboxylic acid,
815580-59-7
ACHIJKL



2,6,6-trimethyl-, methyl ester


368
Farnesyl acetate
29548-30-9
DEFHJK


369
Farnesol
4602-84-0
DEFHJK


370
Oxacyclohexadecan-2-one
106-02-5
DEFGJK


371
1-cyclopentadec-4-en-1-one
14595-54-1
DEFGJK


372
1-cyclopentadec-4-en-1-one
35720-57-1
DEFGJK


373
2-methoxy-4-(4-
128489-04-3
CGJ



methylenetetrahydro-2H-pyran-2-



yl)phenol


374
Eugenyl acetate
93-28-7
CFHJK


375
Eugenol
97-53-0
CHIK


377
Ethylmethylphenylglycidate
77-83-8
CFHJK


378
Ethylene brassylate
105-95-3
DFGJ


381
Ethyl undecylenate
692-86-4
DEFHJK


385
Ethyl palmitate
628-97-7
DEFHJ


386
Ethyl nonanoate
123-29-5
BDEFHJKL


388
Ethyl myristate
124-06-1
DEFHJK


390
Ethyl linalool
10339-55-6
BCEFHJK


391
Ethyl laurate
106-33-2
DEFHJK


394
Ethyl hexyl ketone
925-78-0
ADFHIKL


397
Ethyl decanoate
110-38-3
BDEFHJK


398
Ethyl gamma-Safranate
35044-57-6
ADHIJK


407
Ethyl 3-phenylglycidate
121-39-1
CGJK


413
6-ethyl-2,10,10-trimethyl-1-
79893-63-3
BDEFHIJK



oxaspiro[4.5]deca-3,6-diene


414
Elemol
639-99-6
DEFHJK


415
(2-(1-ethoxyethoxy)ethyl)benzene
2556-10-7
BCEFHJK


416
(E)-3-methyl-5-(2,2,3-
67801-20-1
DHJK



trimethylcyclopent-3-en-1-yl)pent-4-



en-2-ol


417
d-xylose
58-86-6
CGIJ


418
(E)-4-((3aS,7aS)-octahydro-5H-4,7-
30168-23-1
DFHJK



methanoinden-5-ylidene)butanal


421
Dodecanal dimethyl acetal
14620-52-1
DEFHJK


424
d-Limonene
5989-27-5
ADEFGIJKL


425
Dipropylene Glycol
25265-71-8
CEFGIK


426
Dispirone
83863-64-3
BDEFHJK


428
Diphenyloxide
101-84-8
BDEFHK


429
Diphenylmethane
101-81-5
DEFGK


432
Dimethyl benzyl carbinyl butyrate
10094-34-5
DEFHJK


436
2,6-dimethyloct-7-en-4-one
1879-00-1
ADEFHIJKL


441
Octahydro-1H-4,7-methanoinden-5-
64001-15-6
DEFHJKL



yl acetate


444
Dihydrocarveol acetate
20777-49-5
BDEFHIJK


445
Dihydrocarveol
619-01-2
BCEFHIJKL


449
Dihydro Linalool
18479-51-1
BCEFGIJKL


450
Dihydro Isojasmonate
37172-53-5
DHJK


453
Dibutyl sulfide
544-40-1
ADEFHIKL


457
Dibenzyl
103-29-7
DEFGJK


459
delta-Undecalactone
710-04-3
DEFHJKL


461
delta-Elemene
20307-84-0
BDEFHJK


462
delta-Guaiene
3691-11-0
DEFHJKL


463
delta-Dodecalactone
713-95-1
DEFHJK


464
delta-Decalactone
705-86-2
BDEFHIJKL


465
delta-Cadinene
483-76-1
DEFHJKL


466
delta-damascone
57378-68-4
ADHIJK


467
delta-Amorphene
189165-79-5
DEFHJKL


468
delta-3-Carene
13466-78-9
ADEFGIJKL


470
Decylenic alcohol
13019-22-2
BDEFHJK


471
Decyl propionate
5454-19-3
DEFHJK


473
Decanal diethyl acetal
34764-02-8
DEFHJK


474
Decahydro-beta-naphthol
825-51-4
BCEFGIK


475
1-cyclohexylethyl (E)-but-2-enoate
68039-69-0
BDFHJK


478
3-(4-isopropylphenyl)-2-
103-95-7
BDFHJK



methylpropanal


479
Cyclotetradecane
295-17-0
DEFGJKL


480
Cyclopentadecanone
502-72-7
DEFGJK


482
Cyclohexyl salicylate
25485-88-5
DFGJ


484
3a,4,5,6,7,7a-hexahydro-1H-4,7-
113889-23-9
DEFHJK



methanoinden-6-yl butyrate


485
Cyclic ethylene dodecanedioate
54982-83-1
DFGJ


486
8,8-dimethyl-1,2,3,4,5,6,7,8-
68991-97-9
DHJK



octahydronaphthalene-2-



carbaldehyde


487
3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2
DEFHJK



methanoinden-5-yl isobutyrate


488
Curzerene
17910-09-7
DHJK


491
Cumic alcohol
536-60-7
CHIJK


493
Coumarone
1646-26-0
BCEFHIK


497
2-(3-phenylpropyl)pyridine
2110-18-1
CEFHJK


498
Dodecanenitrile
2437-25-4
DEFHJK


501
(E)-cycloheptadec-9-en-1-one
542-46-1
DEFGJ


502
Citryl acetate
6819-19-8
DFHJK


503
Citrus Propanol
15760-18-6
CEFHIJK


505
Citronitrile
93893-89-1
CEFHJK


519
Citral propylene glycol acetal
10444-50-5
CEFHJK


520
Citral dimethyl acetal
7549-37-3
BCEFHJK


521
Citral diethyl acetal
7492-66-2
BDEFHJK


524
cis-Ocimene
3338-55-4
ADGIKL


527
cis-Limonene oxide
13837-75-7
ADEFGIJKL


529
Cis-iso-ambrettolide
36508-31-3
DGJ


530
cis-6-nonenol
35854-86-5
BCEFHIKL


531
cis-carveol
1197-06-4
BCHIJK


532
cis-4-Decen-1-al
21662-09-9
ADHKL


534
cis-3-hexenyl-cis-3-hexenoate
61444-38-0
BDEFHJK


537
cis-3-Hexenyl salicylate
65405-77-8
DEFGJ


541
Cis-3-hexenyl Benzoate
25152-85-6
DEFHJK


544
cis-3-Hexenyl 2-methylbutyrate
53398-85-9
ADEFHJKL


546
cis-3, cis-6-nonadienol
53046-97-2
ACEFHK


548
Cinnamyl propionate
103-56-0
DEFHJK


550
Cinnamyl isobutyrate
103-59-3
DEFHJK


551
Cinnamyl formate
104-65-4
BCEFHK


552
Cinnamyl cinnamate
122-69-0
DHJ


553
Cinnamyl acetate
103-54-8
BCEFHK


555
Cinnamic alcohol
104-54-1
BCEFHIK


558
Cetyl alcohol
36653-82-4
DEFHJ


559
(E)-1-(2,6,6-trimethylcyclohex-2-en-
79-78-7
DHJK



1-yl)hepta-1,6-dien-3-one


560
2-methyl-4-(2,6,6-trimethylcyclohex-
65405-84-7
DFHJK



1-en-1-yl)butanal


561
(3aR,5aR,9aR,9bR)-3a,6,6,9a-
3738-00-9
DEFHJK



tetramethyldodecahydronaphtho[2,1-



b]furan


562
1,6-dioxacycloheptadecan-7-one
6707-60-4
DGJ


563
1-(6-(tert-butyl)-1,1-dimethyl-2,3-
13171-00-1
DEFHJK



dihydro-1H-inden-4-yl)ethan-1-one


565
Cedryl methyl ether
19870-74-7
ADEFHJK


566
Cedryl formate
39900-38-4
BDEFHJK


567
Cedryl acetate
77-54-3
DEFHJK


568
(4Z,8Z)-1,5,9-trimethyl-13-
71735-79-0
DFHJK



oxabicyclo[10.1.0]trideca-4,8-diene


569
Cedrol
77-53-2
DEFHJK


570
5-methyl-1-(2,2,3-
139539-66-5
DEFHJK



trimethylcyclopent-3-en-1-yl)-6-



oxabicyclo[3.2.1]octane


571
5-methyl-1-(2,2,3-
426218-78-2
DFHJ



trimethylcyclopent-3-en-1-yl)-6-



oxabicyclo[3.2.1]octane


572
1,1,2,3,3-pentamethyl-1,2,3,5,6,7-
33704-61-9
BDEFHIJK



hexahydro-4H-inden-4-one


573
Caryophyllene alcohol acetate
32214-91-8
DEFHJK


574
Caryolan-1-ol
472-97-9
DEFHJK


577
Carvyl acetate
97-42-7
BDHIJK


578
Caprylnitrile
124-12-9
ACEFGIKL


580
Caprylic alcohol
111-87-5
ACEFGIKL


581
Caprylic acid
124-07-2
BCEFHIK


582
Capric acid
334-48-5
DEFHJK


584
Capraldehyde
112-31-2
ADHKL


586
3-(4-methoxyphenyl)-2-
5462-06-6
BCHJK



methylpropanal


587
Camphorquinone
10373-78-1
ACEFGIJK


589
Camphene
79-92-5
ADEFGIJKL


591
Ethyl 2-methyl-4-oxo-6-
59151-19-8
DHJ



pentylcyclohex-2-ene-1-carboxylate


592
Butylated hydroxytoluene
128-37-0
DEFGIJK


594
Butyl stearate
123-95-5
DEFHJ


595
Butyl butyryl lactate
7492-70-8
CEFGJK


599
Butyl 10-undecenoate
109-42-2
DEFHJK


600
2-methyl-4-(2,2,3-
72089-08-8
DEFHJK



trimethylcyclopent-3-en-1-yl)butan-



1-ol


601
3-(4-(tert-butyl)phenyl)propanal
18127-01-0
BDHJK


603
Bornyl isobutyrate
24717-86-0
BDEFHIJK


604
Bornyl acetate
76-49-3
ADEFHIJKL


606
2-ethoxy-2,6,6-trimethyl-9-
68845-00-1
BDEFHJK



methylenebicyclo[3.3.1]nonane


607
(ethoxymethoxy)cyclododecane
58567-11-6
DEFHJK


608
Bisabolene
495-62-5
DEFHJK


609
Bigarade oxide
72429-08-4
ADEFHJKL


610
beta-Vetivone
18444-79-6
DHJK


611
beta-Terpinyl acetate
10198-23-9
BDHJK


612
beta-Terpineol
138-87-4
BCGIJK


613
beta-Sinensal
60066-88-8
DHJK


614
beta-Sesquiphellandrene
20307-83-9
DEFHJK


615
beta-Selinene
17066-67-0
BDEFGJK


616
beta-Santalol
77-42-9
DEFHJK


618
beta-Pinene
127-91-3
ADEFGIJKL


620
beta-Naphthyl ethyl ether
93-18-5
BDEFHJK


621
beta-Patchoulline
514-51-2
BDEFGJKL


624
beta-Himachalene Oxide
57819-73-5
BDFHJK


625
beta-Himachalene
1461-03-6
DEFHJKL


626
beta-Guaiene
88-84-6
DEFHJKL


627
(2,2-dimethoxyethyl)benzene
101-48-4
DHJK


628
beta-Farnesene
18794-84-8
DEFHJK


631
beta-Copaene
18252-44-3
BDEFHJKL


632
beta-Cedrene
546-28-1
BDEFGJKL


633
beta-Caryophyllene
87-44-5
DEFHJKL


635
beta-Bisabolol
15352-77-9
DFHJK


636
Beta ionone epoxide
23267-57-4
BDEFHIJK


638
Bergaptene
484-20-8
CGJ


639
Benzyl-tert-butanol
103-05-9
CEFGJK


644
Benzyl laurate
140-25-0
DEFHJ


649
Benzyl dimethyl carbinol
100-86-7
BCEFGIK


650
Benzyl cinnamate
103-41-3
DHJ


653
Benzyl benzoate
120-51-4
DHJ


655
Benzophenone
119-61-9
DEFHK


658
7-isopentyl-2H-
362467-67-2
DHJ



benzo[b][1,4]dioxepin-3(4H)-one


659
2′-isopropyl-1,7,7-
188199-50-0
DEFHJK



trimethylspiro[bicyclo[2.2.1]heptane-



2,4′-[1,3]dioxane]


660
4-(4-methylpent-3-en-1-yl)cyclohex-
21690-43-7
DEFHJK



3-ene-1-carbonitrile


661
Aurantiol
89-43-0
DEFHJ


663
Anisyl phenylacetate
102-17-0
DFHJ


668
Methyl (E)-octa-4,7-dienoate
189440-77-5
ACEFHKL


671
Amyl Cinnamate
3487-99-8
DEFHJK


673
(3aR,5aS,9aS,9bR)-3a,6,6,9a-
6790-58-5
DEFHJK



tetramethyldodecahydronaphtho[2,1-



b]furan


674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a-
211299-54-6
DEFHJK



hexamethyloctahydro-4H-4a,9-



methanoazuleno[5,6-d][1,3]dioxole


675
2,5,5-trimethyl-1,2,3,4,5,6,7,8-
71832-76-3
DEFHJK



octahydronaphthalen-2-ol


676
2,5,5-trimethyl-1,2,3,4,5,6,7,8-
41199-19-3
DEFHJK



octahydronaphthalen-2-ol


677
1-((2-(tert-
139504-68-0
DEFHJK



butyl)cyclohexyl)oxy)butan-2-ol


678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-
57345-19-4
DEFHJ



tetramethyldodecahydro-5H-3,5a-



epoxynaphtho[2,1-c]oxepine


679
2,2,6,6,7,8,8-heptamethyldecahydro-
476332-65-7
ADEFHJK



2H-indeno[4,5-b]furan


680
2,2,6,6,7,8,8-heptamethyldecahydro-
647828-16-8
ADEFHJK



2H-indeno[4,5-b]furan


681
Amber acetate
37172-02-4
BDEFHJK


682
Alpinofix ®
811436-82-5
DEFHJ


683
alpha-Thujone
546-80-5
ADEFGIJKL


684
alpha-Vetivone
15764-04-2
DHJK


686
alpha-Terpinyl propionate
80-27-3
BDEFHJK


691
alpha-Sinensal
17909-77-2
DHJK


692
alpha-Selinene
473-13-2
BDEFHJK


693
alpha-Santalene
512-61-8
ADEFHJKL


694
alpha-Santalol
115-71-9
DEFHJK


696
alpha-Patchoulene
560-32-7
ADEFHJKL


697
alpha-neobutenone
56973-85-4
BDHJK


698
alpha-Muurolene
10208-80-7
DEFHJKL


700
alpha-methyl ionone
127-42-4
BDHJK


702
alpha-Limonene
138-86-3
ADEFGIJKL


704
alpha-Irone
79-69-6
BDHJK


706
alpha-Humulene
6753-98-6
DEFHJK


707
alpha-Himachalene
186538-22-7
BDEFHJK


708
alpha-Gurjunene
489-40-7
BDEFHJKL


709
alpha-Guaiene
3691-12-1
DEFHJKL


710
alpha-Farnesene
502-61-4
DEFHJK


711
alpha-Fenchene
471-84-1
ADEFGIJKL


712
alpha-Eudesmol
473-16-5
DEFHJK


713
alpha-Curcumene
4176-17-4
DEFHJK


714
alpha-Cubebene
17699-14-8
ADEFHJKL


715
alpha-Cedrene epoxide
13567-39-0
ADEFHJK


716
alpha-Cadinol
481-34-5
DEFHJK


717
alpha-Cadinene
24406-05-1
DEFHJKL


718
alpha-Bisabolol
515-69-5
DFHJK


719
alpha-bisabolene
17627-44-0
DEFHJK


720
alpha-Bergamotene
17699-05-7
BDEFHJKL


721
alpha-Amylcinnamyl alcohol
101-85-9
DEFHJ


722
alpha-Amylcinnamyl acetate
7493-78-9
DEFHJ


723
alpha-Amylcinnamaldehyde diethyl
60763-41-9
DEFHJ



acetal


724
alpha-Amylcinnamaldehyde
122-40-7
DHJK


725
alpha-Amorphene
23515-88-0
DEFHJKL


726
alpha-Agarofuran
5956-12-7
BDEFHJK


727
1-methyl-4-(4-methyl-3-penten-1-
52475-86-2
DFHJK



yl)-3-Cyclohexene-1-carboxaldehyde


730
1-Phenyl-2-pentanol
705-73-7
CEFHK


731
1-Phenyl-3-methyl-3-pentanol
10415-87-9
CEFHJK


733
2,3,4-trimethoxy-benzaldehyde
2103-57-3
BCGI


735
2,4,5-trimethoxy-benzaldehyde
4460-86-0
BCG


736
2,4,6-trimethoxybenzaldehyde
830-79-5
BCGI


738
2,4-Nonadienal
6750-03-4
ACHKL


741
2,6,10-Trimethylundecanal
105-88-4
BDFGJK


742
alpha,4-Dimethyl benzenepropanal
41496-43-9
ACHJK


746
Allyl cyclohexyl propionate
2705-87-5
BDEFHJK


748
Allyl amyl glycolate
67634-00-8
BCEFGJK


750
Allo-aromadendrene
25246-27-9
BDEFHJKL


752
Aldehyde C-11
143-14-6
ADHJK


754
Methyl (E)-2-(((3,5-
94022-83-0
DEFHJ



dimethylcyclohex-3-en-1-



yl)methylene)amino)benzoate


757
2,6,10-trimethylundec-9-enal
141-13-9
BDFHJK


758
Acetoxymethyl-isolongifolene
59056-62-1
BDEFHJK



(isomers)


763
Acetate C9
143-13-5
BDEFHJKL


764
Acetarolle ®
744266-61-3
DFHJK


766
Acetaldehyde phenylethyl propyl
7493-57-4
CEFHJK



acetal


767
Acetaldehyde dipropyl acetal
105-82-8
ACEFGIKL


768
Acetaldehyde benzyl 2-methoxyethyl
7492-39-9
BCEFHJK



acetal


769
(Z)-2-(4-methylbenzylidene)heptanal
84697-09-6
DHJ


770
9-decenal
39770-05-3
ADHKL


771
8-Hexadecenolide
123-69-3
DGJ


772
7-Methoxycoumarin
531-59-9
CHK


774
7-epi-alpha-Selinene
123123-37-5
BDEFHJK


775
7-eip-alpha-Eudesmol
123123-38-6
DEFHJK


776
7-Acetyl-1,1,3,4,4,6-
1506-02-1
DEFHJ



hexamethyltetralin


778
6-Isopropylquinoline
135-79-5
CEFHJK


781
6,6-dimethyl-2-norpinene-2-
33885-51-7
BCFHJK



propionaldehyde


782
6,10,14-trimethyl-2-Pentadecanone
502-69-2
DEFHJK


786
5-Isopropenyl-2-methyl-2-
13679-86-2
ACGIJKL



vinyltetrahydrofuran


788
5-Cyclohexadecenone
37609-25-9
DEFGJK


791
4-Terpinenol
562-74-3
BCHIJK


792
4-Pentenophenone
3240-29-7
BCEFHIK


800
4-Carvomenthenol
28219-82-1
BCHIJK


802
4,5,6,7-Tetrahydro-3,6-
494-90-6
BCEFHIJKL



dimethylbenzofuran


803
4-(p-Methoxyphenyl)-2-butanone
104-20-1
BCEFHJK


804
3-Thujopsanone
25966-79-4
BDEFHJK


805
3-Propylidenephthalide
17369-59-4
CEFHK


806
3-Nonylacrolein
20407-84-5
BDFHJK


807
3-Methyl-5-phenyl-1-pentanal
55066-49-4
BDFHJK


814
3-Hexenyl isovalerate
10032-11-8
ADEFHJKL


821
3,6-Dimethyl-3-octanyl acetate
60763-42-0
ADEFHIJKL


824
3,4,5-trimethoxybenzaldehyde
86-81-7
BCGIK


826
3-(p-
7775-00-0
BDFHJK



Isopropylphenyl)propionaldehyde


827
2-Undecenenitrile
22629-48-7
BDEFHJK


828
2-Undecenal
2463-77-6
ADHJK


829
2-trans-6-trans-Nonadienal
17587-33-6
ACHKL


831
2-Phenylethyl butyrate
103-52-6
DEFHJK


833
2-Phenyl-3-(2-furyl)prop-2-enal
57568-60-2
CHJ


834
2-Phenoxyethanol
122-99-6
BCEFGIK


837
2-Nonen-1-al
2463-53-8
ADHKL


839
2-Nonanol
628-99-9
BDEFGIKL


840
2-Nonanone
821-55-6
ADFHIKL


849
2-Isobutyl quinoline
93-19-6
CEFHJK


850
2-Hexylidene cyclopentanone
17373-89-6
DFHJKL


852
2-Heptyl tetrahydrofuran
2435-16-7
BDEFHJKL


856
2-Decenal
3913-71-1
ADHKL


864
2,6-Nonadienal
26370-28-5
ACHKL


865
2,6-Nonadien-1-ol
7786-44-9
ACEFHK


866
2,6-dimethyl-octanal
7779-07-9
ADFGIJKL


868
1-Decanol
112-30-1
BDEFGJK


869
1-Hepten-1-ol, 1-acetate
35468-97-4
ACEFHKL


870
10-Undecen-1-ol
112-43-6
DEFHJK


871
10-Undecenal
112-45-8
ADHJK


872
10-epi-gamma-Eudesmol
15051-81-7
DFHJK


873
1,8-Thiocineol
68391-28-6
ADEFHIJKL


876
1,3,5-undecatriene
16356-11-9
ADEFHJKL


877
1,2-Dihydrolinalool
2270-57-7
BCEFGIJKL


878
1,3,3-trimethyl-2-norbornanyl
13851-11-1
ADEFHIJKL



acetate


879
1,1,2,3,3-Pentamethylindan
1203-17-4
ADHIJKL


881
(Z)-6,10-dimethylundeca-5,9-dien-2-
3239-37-0
DEFHJK



yl acetate


884
(Z)-3-Dodecenal
68141-15-1
BCFHJK


885
(S)-gamma-Undecalactone
74568-05-1
DEFHJKL


886
(R)-gamma-Undecalactone
74568-06-2
DEFHJKL


890
(E)-6,10-dimethylundeca-5,9-dien-2-
3239-35-8
DEFHJK



yl acetat


892
(2Z)-3-methyl-5-phenyl-2-
53243-59-7
DEFHJK



Pentenenitrile


893
(2S,5S,6S)-2,6,10,10-tetramethyl-1-
65620-50-0
DFHIJK



oxaspiro[4_5]decan-6-ol


894
(2E)-3-methyl-5-phenyl-2-
53243-60-0
CEFHJK



pentenenitrile


897
(+)-Dihydrocarveol
22567-21-1
BCEFHIJKL


905
Menthone
89-80-5
ADEFGIJKL


908
(R,E)-2-methyl-4-(2,2,3-
185068-69-3
CHJK



trimethylcyclopent-3-en-1-yl)but-2-



en-1-ol


912
2-(8-isopropyl-6-
68901-32-6
DEFHJK



methylbicyclo[2.2.2]oct-5-en-2-yl)-



1,3-dioxolane


913
gamma-methyl ionone
7388-22-9
BDHIJK


914
3-(3-isopropylphenyl)butanal
125109-85-5
BDHJK


916
3-(1-ethoxyethoxy)-3,7-
40910-49-4
BDEFHJK



dimethylocta-1,6-diene


919
3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3
CEFHJK



methanoinden-6-yl propionate


920
Bulnesol
22451-73-6
DEFHJK


922
Benzyl phenylacetate
102-16-9
DHJ


923
Benzoin
119-53-9
CEFHJ


924
(E)-1,2,4-trimethoxy-5-(prop-1-en-1-
2883-98-9
BCFGJK



yl)benzene


925
alpha,alpha,6,6-tetramethyl
33885-52-8
BDFHJK



bicyclo[3.1.1]hept-2-ene-propanal


926
7-epi-sesquithujene
159407-35-9
DEFHJKL


927
5-Acetyl-1,1,2,3,3,6-
15323-35-0
DEFHJK



hexamethylindan


928
3-Methylphenethyl alcohol
1875-89-4
BCEFHIK


929
3,6-Nonadien-1-ol
76649-25-7
ACEFHK


930
2-Tridecenal
7774-82-5
BDFHJK


933
Patchouli alcohol
5986-55-0
DEFHIJK


937
p-Cresyl isobutyrate
103-93-5
BDHJK


939
p-Cresyl n-hexanoate
68141-11-7
DEFHJK


941
5-hexyl-4-methyldihydrofuran-
67663-01-8
BDEFHIJKL



2(3H)-one


942
Ethyl (2Z,4E)-deca-2,4-dienoate
3025-30-7
BDEFHJK


943
Pelargene
68039-40-7
DEFHJK


945
2-cyclohexylidene-2-
10461-98-0
DFHJK



phenylacetonitrile


946
Perillaldehyde
2111-75-3
ACHIJK


947
Perillyl acetate
15111-96-3
DFHJK


948
Perillyl alcohol
536-59-4
CHIJK


950
(2-isopropoxyethyl)benzene
68039-47-4
ACEFHJKL


951
Ethyl (2Z,4E)-deca-2,4-dienoate
313973-37-4
BDEFHJK


953
(2-(cyclohexyloxy)ethyl)benzene
80858-47-5
DEFHJK


954
Phenethyl 2-methylbutyrate
24817-51-4
DEFHJK


955
Phenethyl alcohol
60-12-8
BCEFGIK


959
Phenethyl phenylacetate
102-20-5
DHJ


962
Phenoxanol
55066-48-3
DEFHJK


965
Phenyl benzoate
93-99-2
DFHJK


967
Phenyl ethyl benzoate
94-47-3
DHJ


969
Phenylacetaldehyde ethyleneglycol
101-49-5
BCEFGIK



acetal


973
2-(6,6-dimethylbicyclo[3.1.1]hept-2-
30897-75-7
ACFHIJKL



en-2-yl)acetaldehyde


974
Pinocarveol
5947-36-4
BCEFGIJKL


976
Piperonyl acetone
55418-52-5
CEFGJ


978
3a,4,5,6,7,7a-hexahydro-1H-4,7-
68039-44-1
DEFHJK



methanoinden-6-yl pivalate


980
(4aR,8aS)-7-methyloctahydro-1,4-
41724-19-0
CEFGJKL



methanonaphthalen-6(2H)-one


982
p-Menth-3-en-1-ol
586-82-3
BCGIJK


985
(E)-3,3-dimethyl-5-(2,2,3-
107898-54-4
DHJK



trimethylcyclopent-3-en-1-yl)pent-4-



en-2-ol


988
1-methyl-4-(4-methylpent-3-en-1-
52474-60-9
DFHJK



yl)cyclohex-3-ene-1-carbaldehyde


993
Propylene glycol
57-55-6
ACEFGIKL


998
p-Tolyl phenylacetate
101-94-0
DFHJ


1000
Ethyl 2,4,7-decatrienoate
78417-28-4
BDEFHJK


1003
2-benzyl-4,4,6-trimethyl-1,3-dioxane
67633-94-7
DEFHJK


1006
2,4-dimethyl-4-
82461-14-1
BDEFHJK



phenyltetrahydrofuran


1007
(2R,4a′R,8a′R)-3,7′-dimethyl-
41816-03-9
DEFHJK



3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-



spiro[oxirane-2,2′-



[1,4]methanonaphthalene]


1008
(Z)-6-ethylideneoctahydro-2H-5,8-
93939-86-7
BCEFHJKL



methanochromene


1009
2-((S)-1-((S)-3,3-
236391-76-7
DFHJ



dimethylcyclohexyl)ethoxy)-2-



oxoethyl propionate


1010
Methyl 2,2-dimethyl-6-
81752-87-6
ADHIJKL



methylenecyclohexane-1-carboxylate


1012
2-methyl-5-phenylpentan-1-ol
25634-93-9
DEFHJK


1016
4-methyl-2-phenyl-3,6-dihydro-2H-
60335-71-9
BCEFGJK



pyran


1020
Sabinol
471-16-9
BCEFHIJKL


1021
Safrole
94-59-7
BCEFHK


1022
2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0
DHIJK



8-en-1-one


1023
3-methyl-5-(2,2,3-
65113-99-7
DEFHJK



trimethylcyclopent-3-en-1-yl)pentan-



2-ol


1024
(Z)-2-ethyl-4-(2,2,3-
28219-61-6
DEFHJK



trimethylcyclopent-3-en-1-yl)but-2-



en-1-ol


1025
(E)-2-methyl-4-(2,2,3-
28219-60-5
CHJK



trimethylcyclopent-3-en-1-yl)but-2-



en-1-ol


1026
5-methoxyoctahydro-1H-4,7-
86803-90-9
CHJK



methanoindene-2-carbaldehyde


1027
5-methoxyoctahydro-1H-4,7-
193425-86-4
CHJK



methanoindene-2-carbaldehyde


1028
Sclareol
515-03-7
DEFHJ


1029
Sclareol oxide
5153-92-4
DEFHJK


1031
Selina-3,7(11)-diene
6813-21-4
DEFHJKL


1032
2-(1-(3,3-
477218-42-1
DEFHJ



dimethylcyclohexyl)ethoxy)-2-



methylpropyl



cyclopropanecarboxylate


1033
3-(4-isobutylphenyl)-2-
6658-48-6
DHJK



methylpropanal


1035
Spathulenol
6750-60-3
DEFHJK


1036
Spirambrene
533925-08-5
BCEFHJK


1037
Spirodecane
6413-26-9
BCEFGIJKL


1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-
224031-70-3
DGJK



1-one


1042
2-(4-methylthiazol-5-yl)ethan-1-ol
137-00-8
CGIKL


1043
2-(heptan-3-yl)-1,3-dioxolane
4359-47-1
ACEFHIJKL


1045
(Z)-dodec-4-enal
21944-98-9
BDFHJK


1046
tau-Cadinol
5937-11-1
DEFHJK


1047
tau-Muurolol
19912-62-0
DEFHJK


1053
Tetrahydrojasmone
13074-63-0
BDFHIJKL


1057
2,6,10,10-tetramethyl-1-
36431-72-8
BDFHIJKL



oxaspiro[4.5]dec-6-ene


1059
Thiomenthone
38462-22-5
BDEFHIJKL


1060
Thujopsene
470-40-6
BDEFGJKL


1062
Thymol methyl ether
1076-56-8
ADHIJKL


1063
1-(2,2,6-trimethylcyclohexyl)hexan-
70788-30-6
DEFHJK



3-ol


1064
trans,trans-2,4-Nonadienal
5910-87-2
ACHKL


1065
trans,trans-Farnesol
106-28-5
DEFHJK


1066
trans-2,cis-6-Nonadienal
557-48-2
ACHKL


1067
trans-2-Decenal
3913-81-3
ADHKL


1070
trans-2-Nonen-1-al
18829-56-6
ADHKL


1072
trans-3,cis-6-nonadienol
56805-23-3
ACEFHK


1073
trans-4-Decen-1-al
65405-70-1
ADHKL


1075
trans-ambrettolide
51155-12-5
DGJ


1077
trans-beta-ocimene
13877-91-3
ADGIKL


1078
trans-beta-Ocimene
3779-61-1
ADGIKL


1082
trans-Geraniol
106-24-1
BCHIK


1083
trans-Hedione
2570-03-8
DFHJK


1085
7-(1,1-Dimethylethyl)-2H-1,5-
195251-91-3
CEFHJ



benzodioxepin-3(4H)-one


1089
Tricyclone
68433-81-8
DEFHJK


1090
Tridecyl alcohol
112-70-9
DEFGJK


1091
Triethyl citrate
77-93-0
CEFGJ


1093
Methyl 2-((1-hydroxy-3-
144761-91-1
DFHJ



phenylbutyl)amino)benzoate


1095
1-((2E,5Z,9Z)-2,6,10-
28371-99-5
DHJK



trimethylcyclododeca-2,5,9-trien-1-



yl)ethan-1-one


1097
Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0
BDEFHJK



2h-indeno(4,5-b)furan


1099
13-methyl oxacyclopentadec-10-en-
365411-50-3
DEFHJK



2-one


1102
Undecanal
112-44-7
BDHJK


1104
(E)-4-methyldec-3-en-5-ol
81782-77-6
BDEFHIJK


1105
Valencene
4630-07-3
BDEFHJK


1107
Valerianol
20489-45-6
DEFHJK


1111
Vanillin isobutyrate
20665-85-4
CHJ


1113
Vaniwhite ®
5533-03-9
CGIK


1116
(Z)-2-methyl-4-(2,6,6-
68555-62-4
BDFHJK



trimethylcyclohex-2-en-1-yl)but-2-



enal


1117
Methyl 2,4-dihydroxy-3,6-
4707-47-5
CGIJ



dimethylbenzoate


1120
1-methoxy-3a,4,5,6,7,7a-hexahydro-
27135-90-6
ACEFHJKL



1H-4,7-methanoindene


1121
Methyl (Z)-2-((3-(4-(tert-
91-51-0
DFHJ



butyl)phenyl)-2-



methylpropylidene)amino)benzoate


1125
(Z)-hex-3-en-1-yl isobutyrate
41519-23-7
ADEFHJKL


1126
Vertacetal
5182-36-5
BCFHJK


1129
1-((3R,3aR,7R,8aS)-3,6,8,8-
32388-55-9
DHJK



tetramethyl-2,3,4,7,8,8a-hexahydro-



1H-3a,7-methanoazulen-5-yl)ethan-



1-one


1131
Methyl (Z)-2-(((2,4-
68738-99-8
DEFHJ



dimethylcyclohex-3-en-1-



yl)methylene)amino)benzoate


1135
Vetiverol
89-88-3
CEFHIJK


1136
Vetivert Acetate
117-98-6
DEFHJK


1137
Decahydro-3H-spiro[furan-2,5′-
68480-11-5
DEFGJKL



[4,7]methanoindene]


1138
(2Z,6E)-nona-2,6-dienenitrile
67019-89-0
ACEFHKL


1139
(Z)-cyclooct-4-en-1-yl methyl
87731-18-8
BCHJKL



carbonate


1140
(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-
552-02-3
DEFHJK



tetramethyldecahydro-1H-



cyclopropa[e]azulen-4-ol


1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8-
127459-79-4
DHJ



tetrahydronaphthalene-2-carbonitrile


1143
(1S,2S,3S,5R)-2,6,6-
133636-82-5
DEFHJK



trimethylspiro[bicyclo[3.1.1]heptane-



3,1′-cyclohexan]-2′-en-4′-one


1144
1′,1′,5′,5′-tetramethylhexahydro-
154171-76-3
DEFHJK



2′H,5′H-spiro[[1,3]dioxolane-2,8′-



[2,4a]methanonaphthalene]


1145
1′,1′,5′,5′-tetramethylhexahydro-
154171-77-4
DEFHJK



2′H,5′H-spiro[[1,3]dioxolane-2,8′-



[2,4a]methanonaphthalene] K


1146
4-(4-hydroxy-3-
122-48-5
CEFGJ



methoxyphenyl)butan-2-one


1147
(1R,8aR)-4-isopropyl-1,6-dimethyl-
41929-05-9
DEFHJKL



1,2,3,7,8,8a-hexahydronaphthalene


1148
4,5-epoxy-4,11,11-trimethyl-8-
1139-30-6
DEFHJK



methylenebicyclo(7.2.0)undecane


1149
1,3,4,6,7,8alpha-hexahydro-1,1,5,5-
23787-90-8
DEFHIJK



tetramethyl-2H-2,4alpha-



methanophtalen-8(5H)-one
















TABLE 2







List of materials with at least one MORV greater than 5 to 10










Num-

CAS
Comment


ber
Material Name
Number
Code













2
2,4-dimethyl-2-(5,5,8,8-tetramethyl-
131812-67-4
DFHJ



5,6,7,8-tetrahydronaphthalen-2-yl)-



1,3-dioxolane


23
3a,5,6,7,8,8b-hexahydro-
823178-41-2
DEFHJK



2,2,6,6,7,8,8-heptamethyl-4H-



indeno(4,5-d)-1,3-dioxole


141
2,4-dimethyl-4,4a,5,9b-
27606-09-3
CEFHJK



tetrahydroindeno[1,2-d][1,3]dioxine


185
(1-methyl-2-((1,2,2-
198404-98-7
DEFHJK



trimethylbicyclo[3.1.0]hexan-3-



yl)methyl)cyclopropyl)methanol


227
Isobornylcyclohexanol
68877-29-2
DEFHJK


230
Isobornyl cyclohexanol
66072-32-0
DEFHJK


246
Indol/Hydroxycitronellal Schiff base
67801-36-9
DEFHJ


248
Hydroxymethyl isolongifolene
59056-64-3
DEFHJK


343
8,8-dimethyl-3a,4,5,6,7,7a-
76842-49-4
DEFHJK



hexahydro-1H-4,7-methanoinden-6-



yl propionate


359
(E)-4-((3aR,4R,7R,7aR)-
501929-47-1
DEFHJK



1,3a,4,6,7,7a-hexahydro-5H-4,7-



methanoinden-5-ylidene)-3-



methylbutan-2-ol


565
Cedryl methyl ether
19870-74-7
BDEFHJK


631
beta-Copaene
18252-44-3
BDEFHJKL


659
2′-isopropyl-1,7,7-
869292-93-3
BDEFHJK



trimethylspiro[bicyclo[2.2.1]heptane-



2,4′-[1,3]dioxane]


674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a-
211299-54-6
DEFHJK



hexamethyloctahydro-4H-4a,9-



methanoazuleno[5,6-d][1,3]dioxole


678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-
57345-19-4
DEFHJ



tetramethyldodecahydro-5H-3,5a-



epoxynaphtho[2,1-c]oxepine


679
2,2,6,6,7,8,8-heptamethyldecahydro-
476332-65-7
DEFHJK



2H-indeno[4,5-b]furan


715
alpha-Cedrene epoxide
13567-39-0
BDEFHJK


758
Acetoxymethyl-isolongifolene
59056-62-1
DEFHJK



(isomers)


1028
Sclareol
515-03-7
DEFHJ


1097
Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0
DEFHJK



2h-indeno(4,5-b)furan
















TABLE 3







List of materials with at least one MORV from 0.5 to less than 1










Number
Material Name
CAS Number
Comment Code













12
1-ethoxy-4-(tert-
181258-89-9
ADEFHJK



pentyl)cyclohexane


19
(3Z)-1-(2-buten-1-yloxy)-3-
888744-18-1
ADEFHJKL



hexene


20
4-(2-methoxypropan-2-yl)-1-
14576-08-0
ADHIJKL



methylcyclohex-1-ene


24
O-Methyl linalool
60763-44-2
ADHIJKL


26
o-Methoxycinnamaldehyde
1504-74-1
ACHK


27
Octanal, 3,7-dimethyl-
25795-46-4
ADGIJKL


53
3,3-Dimethyl-5(2,2,3-
329925-33-9
CEFHJ



Trimethyl-3-Cyclopenten-



1yl)-4-Penten-2-ol


54
n-Hexyl salicylate
6259-76-3
DEFHJ


55
n-Hexyl 2-butenoate
19089-92-0
ADEFHJKL


59
Neryl Formate
2142-94-1
BCEFHJK


72
Methyl-beta-ionone
127-43-5
DHJK


73
Myroxide
28977-57-3
ADGIJKL


81
(E)-3,7-dimethylocta-4,6-
18479-54-4
BCEFGIJK



dien-3-ol


84
(Z)-hex-3-en-1-yl
188570-78-7
BCEFHIKL



cyclopropanecarboxylate


96
Methyl phenyl carbinyl
120-45-6
BCHJK



propionate


97
Methyl phenylacetate
101-41-7
ACEFHIKL


107
2-methyl-6-
91069-37-3
BCEFGIKL



oxaspiro[4.5]decan-7-one


111
Methyl geraniate
2349-14-6
BCHJKL


115
2-ethoxy-4-
5595-79-9
CFGK



(methoxymethyl)phenol


116
Methyl
40203-73-4
ACEFHIKL



cyclopentylideneacetate


125
Methoxymelonal
62439-41-2
ACGIJK


133
((1s,4s)-4-
13828-37-0
BDEFHIJK



isopropylcyclohexyl)methanol


147
Linalyl propionate
144-39-8
BDFHJK


150
Linalyl formate
115-99-1
ACFHJK


151
Linalyl butyrate
78-36-4
BDEFHJK


154
Linalyl acetate
115-95-7
BDHJK


157
Linalool
78-70-6
BCEFGIJK


163
(Z)-hex-3-en-1-yl methyl
67633-96-9
ACEFGKL



carbonate


166
Lepidine
491-35-0
BCEFHIKL


169
L-Carvone
6485-40-1
ACGIJKL


181
Khusinil
75490-39-0
DHJK


191
Isoraldeine
1335-46-2
BDHIJK


194
Isopropylvinylcarbinol
4798-45-2
ACGIKL


198
Isopropyl 2-methylbutyrate
66576-71-4
ACEFGIJKL


201
Isopentyrate
80118-06-5
ADEFGIJKL


204
Isononyl acetate
40379-24-6
BDEFHJKL


205
Isononanol
27458-94-2
BDEFGIKL


213
Isoeugenyl acetate
93-29-8
CFHJK


214
Isoeugenol
97-54-1
CEFHIK


232
Isoborneol
124-76-5
ACEFHIJKL


237
Isoamyl octanoate
2035-99-6
DEFHJK


239
Isoamyl isobutyrate
2050-01-3
ACEFGIJKL


255
Hydrocinnamic acid
501-52-0
CEFHIK


258
Hydratopic alcohol
1123-85-9
BCEFHIK


264
Hexyl propanoate
2445-76-3
ADEFHIKL


270
Hexyl butyrate
2639-63-6
BDEFHJKL


273
Hexyl 2-methylbutanoate
10032-15-2
BDEFHJKL


275
Hexyl 2-furoate
39251-86-0
DEFHJK


282
Heptyl alcohol
111-70-6
ACEFGIKL


283
Heptyl acetate
112-06-1
ADEFHKL


284
Heptaldehyde
111-71-7
ACHIKL


287
Heliotropin
120-57-0
BCGIK


302
Geranyl nitrile
5146-66-7
BCEFHKL


306
Geranyl formate
105-86-2
BCEFHJK


308
Geranyl caprylate
51532-26-4
DEFHJ


310
Geranyl benzoate
94-48-4
DFHJ


312
Geranial
141-27-5
ACHIKL


314
N,2-dimethyl-N-
84434-18-4
BCEFHJK



phenylbutanamide


319
gamma-Terpinene
99-85-4
ADEFGIJKL


346
2-(sec-butyl)cyclohexan-1-
14765-30-1
ADFHIKL



one


354
3-(2-ethylphenyl)-2,2-
67634-14-4
BDHJK



dimethylpropanal


355
2-(tert-butyl)cyclohexyl ethyl
67801-64-3
BDFHJK



carbonate


365
2-(tert-butyl)cyclohexyl ethyl
81925-81-7
ACFHIKL



carbonate


366
Fenchyl alcohol
1632-73-1
ACGIJKL


376
Eucalyptol
470-82-6
ADEFGIJKL


379
Ethyl vanillin acetate
72207-94-4
CHJ


387
Ethyl octanoate
106-32-1
BDEFHJKL


400
Ethyl cinnamate
103-36-6
BCEFHK


412
Ethyl 2-
2511-00-4
BDFHIJKL



(cyclohexyl)propionate


419
d-p-8(9)-Menthen-2-one
5524-05-0
ACGIJKL


420
4-methyl-2-phenyltetrahydro-
94201-73-7
BDEFHJK



2H-pyran


437
Dihydromyrcenol
18479-58-8
ADEFGIJK


438
Dihydrojasmone
1128-08-1
BCFHIJKL


439
Dihydroisophorone
873-94-9
ACEFGIJKL


440
Dihydroeugenol
2785-87-7
CEFHIJK


442
Dihydrocoumarin
119-84-6
BCGIKL


443
Dihydrocarvone
7764-50-3
ACGIJKL


447
Dihydro-alpha-terpinyl
80-25-1
BDEFHIJKL



acetate


448
Dihydro-alpha-ionone
31499-72-6
BDHIJK


454
Dibenzyl ether
103-50-4
DEFHJK


455
Dibutyl o-phthalate
84-74-2
DEFHJ


469
2-pentylcyclopentan-1-one
4819-67-4
BDFHIKL


472
Decyl anthranilate
18189-07-6
DEFHJ


477
Methyl (1s,4s)-1,4-
23059-38-3
ADEFHIJKL



dimethylcyclohexane-1-



carboxylate


481
Cyclohexylethyl acetate
21722-83-8
BDEFHJKL


492
Creosol
93-51-6
BCHIK


495
Cosmene
460-01-5
ADEFGIKL


496
4-cyclohexyl-2-methylbutan-
83926-73-2
BDEFGIJK



2-ol


504
2-benzyl-2-methylbut-3-
97384-48-0
BDHJK



enenitrile


509
Citronellyl nitrile
51566-62-2
BCEFGIKL


510
Citronellyl phenylacetate
139-70-8
DFHJ


512
Citronellyl formate
105-85-1
BCEFGJKL


515
Citronellyl benzoate
10482-77-6
DFHJ


517
Citronellol
106-22-9
BCHIJKL


518
Citronellal
106-23-0
ACHIJKL


522
Citral
5392-40-5
ACHIKL


525
cis-Pinane
6876-13-7
ADEFGIJKL


526
(Z)-3-methyl-2-(pent-2-en-1-
488-10-8
BCHIJKL



yl)cyclopent-2-en-1-one


528
cis-iso-Eugenol
5912-86-7
CEFHIK


535
cis-3-Hexenyl valerate
35852-46-1
BDEFHJKL


536
cis-3-Hexenyl tiglate
67883-79-8
BDEFHJK


538
cis-3-Hexenyl propionate
33467-74-2
ACEFHIKL


540
cis-3-Hexenyl butyrate
16491-36-4
ADEFHJKL


542
cis-3-Hexen-1-ol
928-96-1
ACEFHIKL


547
cis-2-Hexenol
928-94-9
ACEFHIKL


549
Cinnamyl nitrile
4360-47-8
ACEFGIK


554
Cinnamic aldehyde
104-55-2
ACHIK


556
Cinnamyl nitrile
1885-38-7
ACEFGIK


557
Chloroxylenol
88-04-0
BCHIJK


575
Carvacrol
499-75-2
DHIJK


576
Carvone
99-49-0
ACGIJKL


579
Carbitol
111-90-0
BCEFGIK


583
Caproyl alcohol
111-27-3
ACEFGIKL


585
2-(2,2,3-trimethylcyclopent-3-
15373-31-6
ACGIJKL



en-1-yl)acetonitrile


588
Camphor
76-22-2
ACEFGIJKL


602
(E)-2-methyl-4-(2,6,6-
3155-71-3
DHJK



trimethylcyclohex-1-en-1-



yl)but-2-enal


605
Borneol
507-70-0
ACEFHIJKL


617
beta-Pinene epoxide
6931-54-0
ACEFGIJKL


619
beta-Phellandrene
555-10-2
ADEFGIJKL


640
Benzylacetone
2550-26-7
ACEFGIK


641
Benzyl salicylate
118-58-1
DFGJ


645
Benzyl isovalerate
103-38-8
BDEFHJK


647
Benzyl isobutyrate
103-28-6
BCHJK


651
Benzyl butyrate
103-37-7
BCEFHJK


652
Benzyl alcohol
100-51-6
ACEFGIKL


662
1-(3,3-
25225-08-5
ADEFHIJKL



dimethylcyclohexyl)ethyl



formate


664
Anisyl acetate
104-21-2
BCEFGK


665
Anisyl formate
122-91-8
BCEFGK


667
Anethole
104-46-1
ACEFHK


672
Amyl benzoate
2049-96-9
DEFHJK


687
alpha-Terpinyl acetate
80-26-2
BDHJK


699
alpha-methyl-
10528-67-3
BDEFHIK



cyclohexanepropanol


701
alpha-methyl cinnamaldehyde
101-39-3
ACHIK


703
alpha-Isomethylionone
127-51-5
BDHIJK


740
2,5-Dimethyl-4-methoxy-
4077-47-8
ACEFGIJKL



3(2H)-furanone


743
Allyl phenoxyacetate
7493-74-5
BCGK


744
Allyl Phenethyl ether
14289-65-7
ACEFHK


745
Allyl heptanoate
142-19-8
ADEFHJKL


755
N-ethyl-N-(m-
179911-08-1
CEFHJK



tolyl)propionamide


760
3-hydroxybutan-2-one
513-86-0
ACEFGIKL


761
Acetoanisole
100-06-1
BCEFHIK


777
6-Methylquinoline
91-62-3
BCEFHIKL


779
6,8-Diethyl-2-nonanol
70214-77-6
BDEFGIJKL


784
5-Methyl-3-heptanone
541-85-5
ACFGIKL


789
4-Vinylphenol
2628-17-3
BCHIK


796
4-hydroxy-3-methoxy-
458-36-6
CH



cinnamaldehyde


797
4-Ethylguaiacol
2785-89-9
CEFHIK


799
4-Damascol
4927-36-0
BDFHJK


808
3-methyl-4-phenylpyrazole
13788-84-6
CEFHK


810
3-Methyl-1,2-
765-70-8
ACEFGIKL



cyclopentanedione


811
3-Methoxy-5-methylphenol
3209-13-0
BCHIK


812
3-Methoxy-3-Methyl Butanol
56539-66-3
ACGIKL


817
3-Hexenol
544-12-7
ACEFHIKL


819
3,7-dimethyl-2-methylene-6-
22418-66-2
ADFHIJK



octenal


820
3,7-dimethyl-1-octanol
106-21-8
BDEFGIJKL


832
2-Phenylethyl acetate
103-45-7
BCEFHK


835
2-Phenethyl propionate
122-70-3
BCEFHJK


836
2-Pentylcyclopentan-1-ol
84560-00-9
DEFHIKL


838
2-nonanone propylene glycol
165191-91-3
BDEFHJK



acetal


845
2-Methoxy-3-(1-
24168-70-5
BCEFGIK



methylpropyl)pyrazine


846
2-isopropyl-N,2,3-
51115-67-4
ACEFGIJK



trimethylbutyramide


847
2-Isopropyl-5-methyl-2-
35158-25-9
ADFGIJKL



hexenal


848
2-Isopropyl-4-methylthiazole
15679-13-7
ACHIJKL


851
2-Hexen-1-ol
2305-21-7
ACEFHIKL


858
2-Butoxyethanol
111-76-2
ACEFGIKL


875
1,4-Cineole
470-67-7
ADGIJKL


880
1-(2,6,6-Trimethyl-2-
43052-87-5
BDHIJK



cyclohexen-1-yl)-2-buten-1-



one


882
(Z)-3-hepten-1-yl acetate
1576-78-9
ACEFHKL


883
(S)—(1R,5R)-4,6,6-
1196-01-6
ACEFGIJKL



trimethylbicyclo[3.1.1]hept-3-



en-2-one


888
(R)-(−)-Linalool
126-91-0
BCEFGIJK


889
(l)-Citronellal
5949-05-3
ACHIJKL


891
(d)-Citronellal
2385-77-5
ACHIJKL


899
(+)-Citronellol
1117-61-9
BCHIJKL


900
(−)-Citronellol
7540-51-4
BCHIJKL


901
(+)-alpha-Pinene
7785-70-8
ADEFGIJKL


902
(+)-Carvone
2244-16-8
ACGIJKL


903
(−)-alpha-Pinene
7785-26-4
ADEFGIJKL


904
Methyl 2-methylbutyrate
868-57-5
ACEFGIKL


909
Hexyl tiglate
16930-96-4
BDEFHJKL


918
Allyl 2-
68901-15-5
CHJK



(cyclohexyloxy)acetate


921
1,5-
75147-23-8
CFHIJK



dimethylbicyclo[3.2.1]octan-



8-one oxime


931
alpha-acetoxystyrene
2206-94-2
ACEFHIK


940
p-Cymene
99-87-6
ADGIJKL


956
Phenethyl formate
104-62-1
ACEFHK


958
Phenethyl isobutyrate
103-48-0
DHJK


960
Phenethyl tiglate
55719-85-2
DHJK


971
Phenylethyl methacrylate
3683-12-3
DHJK


977
p-
4395-92-0
BDFHK



Isopropylphenylacetaldehyde


981
1,2-dimethyl-3-(prop-1-en-2-
72402-00-7
BCEFGIJKL



yl)cyclopentan-1-ol


983
p-Methoxyphenylacetone
122-84-9
BCEFHK


986
(2Z,5Z)-5,6,7-trimethylocta-
358331-95-0
ADHIJKL



2,5-dien-4-one


987
p-Propyl anisole
104-45-0
ADEFHKL


994
p-t-butyl phenyl acetaldehyde
109347-45-7
BDHJK


995
p-tert-Amyl cyclohexanol
5349-51-9
BDEFHIJK


1001
Racemic alpha-Pinene
80-56-8
ADEFGIJKL


1002
4-(4-hydroxyphenyl)butan-2-
5471-51-2
CEFGIK



one


1004
Rhodinol
141-25-3
BCHIJKL


1005
Ethyl (2,3,6-
93981-50-1
BDEFHJKL



trimethylcyclohexyl)carbonate


1011
1-(3,3-
25225-10-9
ADHIJKL



dimethylcyclohexyl)ethyl



acetate


1017
S)-(+)-Linalool
126-90-9
BCEFGIJK


1018
Sabinene
3387-41-5
ADEFGIJKL


1019
Sabinene hydrate
546-79-2
ADEFGIJKL


1030
Propyl (S)-2-(tert-
319002-92-1
BDEFHJK



pentyloxy)propanoate


1039
Spirolide
699-61-6
BCGIKL


1040
(Z)-5-methylheptan-3-one
22457-23-4
BCEFGIJKL



oxime


1041
1-phenylethyl acetate
93-92-5
ACEFHIK


1051
Tetrahydrogeranial
5988-91-0
ADGIJKL


1052
Tetrahydroionol
4361-23-3
BDEFHIJK


1054
Tetrahydrolinalool
78-69-3
BDEFGIJKL


1055
Tetrahydrolinalyl acetate
20780-48-7
ADEFHJKL


1058
Ethyl (1R,6S)-2,2,6-
22471-55-2
ADEFHIJKL



trimethylcyclohexane-1-



carboxylate


1061
Thymol
89-83-8
BDHIJK


1069
trans-2-Hexenol
928-95-0
ACEFHIKL


1071
trans-2-tert-
5448-22-6
ACGIJKL



Butylcyclohexanol


1074
trans-alpha-Damascone
24720-09-0
BDHIJK


1076
trans-Anethole
4180-23-8
ACEFHK


1079
trans-Cinnamic acid
140-10-3
CEFHK


1081
trans-Dihydrocarvone
5948-04-9
ACGIJKL


1084
trans-Isoeugenol
5932-68-3
CEFHIK


1088
Trichloromethyl phenyl
90-17-5
BDEFGJ



carbinyl acetate


1098
2-mercapto-2-methylpentan-
258823-39-1
ACEFHIJKL



1-ol


1110
Vanillin acetate
881-68-5
CH


1112
Vanitrope
94-86-0
CEFHK


1115
2,2,5-trimethyl-5-
65443-14-3
BDFGIJKL



pentylcyclopentan-1-one


1118
Veratraldehyde
120-14-9
BCGIK


1119
(1R,5R)-4,6,6-
18309-32-5
ACEFGIJKL



trimethylbicyclo[3.1.1]hept-3-



en-2-one


1122
Verdol
13491-79-7
ACGIJKL


1127
4-(tert-butyl)cyclohexyl
10411-92-4
BDEFHJK



acetate


1128
4-(tert-butyl)cyclohexyl
32210-23-4
BDEFHJK



acetate


1133
Vethymine
7193-87-5
CEFGK


1134
4-methyl-4-phenylpentan-2-yl
68083-58-9
BDFHJK



acetate


1141
(Z)-1-((2-
292605-05-1
ADEFHKL



methylallyl)oxy)hex-3-ene
















TABLE 4







List of malodor reduction materials with ALL MORVs from 1 to 5












CAS
Comment


Number
Material Name
Number
Code













7
3-methoxy-7,7-dimethyl-10-
216970-21-7
BDEFHJK



methylenebicyclo[4.3.1]decane


14
Oxyoctaline formate
65405-72-3
DFHJK


39
2,2,6,8-tetramethyl-
103614-86-4
DEFHIJK



1,2,3,4,4a,5,8,8a-octahydro-



naphthalen-1-ol


48
Nootkatone
4674-50-4
DHJK


183
Khusimol
16223-63-5
CEFHJK


199
Isopimpinellin
482-27-9
CFGJ


206
Iso3-methylcyclopentadecan-1-one
3100-36-5
DEFGJK


212
Isoeugenyl benzyl ether
120-11-6
DFHJ


215
1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2
DHJK



1,2,3,4,5,6,7,8-octahydro-



naphthalen-2-yl)ethan-1-one


229
Isobornyl isobutyrate
85586-67-0
BDEFHIJK


260
2,3-dihydro-3,3-dimethyl-1H-
173445-44-8
DHJK



indene-5-propanal


261
3-(3,3-dimethyl-2,3-dihydro-1H-
173445-65-3
DHJK



inden-5-yl)propanal


281
3a,4,5,6,7,7a-hexahydro-1H-4,7-
5413-60-5
CEFGJK



methanoinden-6-yl acetate


329
gamma-Eudesmol
1209-71-8
DFHJK


335
4,6,6,7,8,8-hexamethyl-
1222-05-5
DEFHJK



1,3,4,6,7,8-hexahydro-



cyclopenta[g]isochromene


353
(Z)-6-ethylideneoctahydro-2H-5,8-
69486-14-2
CEFGJK



methanochromen-2-one


360
8,8-dimethyl-3a,4,5,6,7,7a-
171102-41-3
DEFHJK



hexahydro-1H-4,7-methanoinden-



6-yl acetate


441
Octahydro-1H-4,7-methanoinden-
64001-15-6
DEFHJKL



5-yl acetate


484
3a,4,5,6,7,7a-hexahydro-1H-4,7-
113889-23-9
DEFHJK



methanoinden-6-yl butyrate


487
3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2
DEFHJK



methanoinden-5-yl isobutyrate


488
Curzerene
17910-09-7
DHJK


501
(E)-cycloheptadec-9-en-1-one
542-46-1
DEFGJ


566
Cedryl formate
39900-38-4
BDEFHJK


567
Cedryl acetate
77-54-3
DEFHJK


569
Cedrol
77-53-2
DEFHJK


570
5-methyl-1-(2,2,3-
139539-66-5
DEFHJK



trimethylcyclopent-3-en-1-yl)-6-



oxabicyclo[3.2.1]octane


573
Caryophyllene alcohol acetate
32214-91-8
DEFHJK


574
Caryolan-1-ol
472-97-9
DEFHJK


603
Bornyl isobutyrate
24717-86-0
BDEFHIJK


616
beta-Santalol
77-42-9
DEFHJK


621
beta-Patchoulline
514-51-2
BDEFGJKL


624
beta-Himachalene Oxide
57819-73-5
BDFHJK


627
(2,2-dimethoxyethyl)benzene
101-48-4
DHJK


632
beta-Cedrene
546-28-1
BDEFGJKL


663
Anisyl phenylacetate
102-17-0
DFHJ


680
2,2,6,6,7,8,8-heptamethyldeca-
647828-16-8
ADEFHJK



hydro-2H-indeno[4,5-b]furan


684
alpha-Vetivone
15764-04-2
DHJK


694
alpha-Santalol
115-71-9
DEFHJK


696
alpha-Patchoulene
560-32-7
ADEFHJKL


708
alpha-Gurjunene
489-40-7
BDEFHJKL


712
alpha-Eudesmol
473-16-5
DEFHJK


714
alpha-Cubebene
17699-14-8
ADEFHJKL


726
alpha-Agarofuran
5956-12-7
BDEFHJK


750
Allo-aromadendrene
25246-27-9
BDEFHJKL


764
Acetarolle
744266-61-3
DFHJK


775
7-eip-alpha-Eudesmol
123123-38-6
DEFHJK


776
7-Acetyl-1,1,3,4,4,6-
1506-02-1
DEFHJ



hexamethyltetralin


788
5-Cyclohexadecenone
37609-25-9
DEFGJK


804
3-Thujopsanone
25966-79-4
BDEFHJK


872
10-epi-gamma-Eudesmol
15051-81-7
DFHJK


919
3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3
CEFHJK



methanoinden-6-yl propionate


927
5-Acetyl-1,1,2,3,3,6-
15323-35-0
DEFHJK



hexamethylindan


933
Patchouli alcohol
5986-55-0
DEFHIJK


978
3a,4,5,6,7,7a-hexahydro-1H-4,7-
68039-44-1
DEFHJK



methanoinden-6-yl pivalate


1007
(2R,4a′R,8a′R)-3,7′-dimethyl-
41816-03-9
DEFHJK



3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-



spiro[oxirane-2,2′-



[1,4]methanonaphthalene]


1022
2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0
DHIJK



8-en-1-one


1024
(Z)-2-ethyl-4-(2,2,3-
28219-61-6
DEFHJK



trimethylcyclopent-3-en-1-yl)but-2-



en-1-ol


1027
5-methoxyoctahydro-1H-4,7-
193425-86-4
CHJK



methanoindene-2-carbaldehyde


1029
Sclareol oxide
5153-92-4
DEFHJK


1035
Spathulenol
6750-60-3
DEFHJK


1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-
224031-70-3
DGJK



en-1-one


1060
Thujopsene
470-40-6
BDEFGJKL


1089
Tricyclone
68433-81-8
DEFHJK


1107
Valerianol
20489-45-6
DEFHJK


1129
1-((3R,3aR,7R,8aS)-
32388-55-9
DHJK



3,6,8,8-tetramethyl-2,3,4,7,8,8a-



hexahydro-1H-3a,7-



methanoazulen-5-yl)ethan-1-one


1131
Methyl (Z)-2-(((2,4-
68738-99-8
DEFHJ



dimethylcyclohex-3-en-1-



yl)methylene)amino)benzoate


1136
Vetivert Acetate
117-98-6
DEFHJK


1137
Decahydro-3H-spiro[furan-2,5′-
68480-11-5
DEFGJKL



[4,7]methanoindene]


1140
(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-
552-02-3
DEFHJK



tetramethyldecahydro-1H-



cyclopropa[e]azulen-4-ol


1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8-
127459-79-4
DHJ



tetrahydronaphthalene-2-



carbonitrile


1143
(1S,2S,3S,5R)-2,6,6-
133636-82-5
DEFHJK



trimethylspiro[bicyclo[3.1.1]-



heptane-



3,1′-cyclohexan]-2′-en-4′-one


1144
1′,1′,5′,5′-tetramethylhexahydro-
154171-76-3
DEFHJK



2′H,5′H-spiro[[1,3]dioxolane-2,8′-



[2,4a]methanonaphthalene]


1145
1′,1′,5′,5′-tetramethylhexahydro-
154171-77-4
DEFHJK



2′H,5′H-spiro[[1,3]dioxolane-2,8′-



[2,4a]methanonaphthalene] K


1148
4,5-epoxy-4,11,11-trimethyl-8-
1139-30-6
DEFHJK



methylenebicyclo(7.2.0)undecane


1149
1,3,4,6,7,8alpha-hexahydro-
23787-90-8
DEFHIJK



1,1,5,5-tetramethyl-2H-2,4alpha-



methanophtalen-8(5H)-one
















TABLE 5







List of malodor reduction materials with ALL MORVs greater than 5 to 10










Number
Material Name
CAS Number
Comment Code





248
Hydroxymethyl
59056-64-3
BDEFHJK



isolongifolene
















TABLE 6







List of malodor reduction materials with ALL


MORVs from 0.5 to less than 1










Number
Material Name
CAS Number
Comment Code





472
Decyl anthranilate
18189-07-6
DEFHJ


526
(Z)-3-methyl-2-(pent-
488-10-8
BCHIJKL



2-en-1-yl)cyclopent-



2-en-1-one









The materials in Tables 1-6 can be supplied by one or more of the following:

    Firmenich Inc. of Plainsboro N.J. USA; International Flavor and Fragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA; Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad, Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.
    Actual MORV values for each material listed in Tables 1-6 above are as follows:

















MORV value
MORV
MORV
MORV


Material
for
Value for
Value for
value for


No.
Equation a.)
Equation b.)
Equation c.)
Equation d.)



















1
0.548223914
0.876283261
1.22018588
−0.41901144


2
1.520311929
3.493450446
2.70657265
5.11342862


3
2.267801995
−0.81712657
0.43218875
1.595983683


4
−0.591063369
−0.48283571
0.16199804
1.210497701


7
1.437444636
2.131822996
3.81633465
1.318339345


9
2.151445882
−0.46189495
0.56090469
1.206360803


10
2.5733592
−0.58780849
1.39751471
1.258361951


11
3.052627325
1.008519135
−0.30475953
0.076323462


12
0.683776599
−0.01157903
0.82853231
0.326169402


13
1.549643217
1.809183231
0.70864531
2.22799611


14
2.82111224
2.339505033
1.240818
2.502429355


16
−0.31551128
−0.06816599
−0.04371934
2.76742389


17
−1.334904153
−0.5773313
1.75644798
1.898455724


18
−1.34154226
−2.63596666
0.06885109
1.001431671


19
0.15532384
0.09866097
0.64214585
−0.33330779


20
0.640261783
0.693213268
0.54637273
−0.97556029


21
0.936895364
−0.01521118
1.1697513
−0.63510809


22
1.158981042
1.115900089
−0.25859776
1.318200884


23
3.702361074
1.399942641
5.23954766
7.089933671


24
0.773874141
0.146848137
−1.05705847
−0.36193173


25
−1.016103969
−1.18967936
0.78064625
2.944710012


25
−1.016103969
−1.18967936
0.78064625
2.944710012


26
0.615085491
−0.00096877
−0.35697252
−0.18121401


27
0.70261974
−0.22197386
0.19710806
−2.37196477


28
1.366472597
−0.42546942
−0.59394241
−0.01417395


29
1.096043453
−1.02972898
−1.42167356
−0.63817943


30
1.143415203
−0.85945441
−0.41416913
2.499807942


31
1.138642907
−0.19595476
−0.54547769
−0.98828898


32
1.914414495
−0.64487788
0.63212987
1.166699371


33
0.314847366
1.848003955
−1.3905032
−0.62848261


34
−0.113542761
0.981530917
0.32824239
1.126524277


35
0.472382903
1.494882467
−0.07201236
−0.64589543


36
3.158513795
1.084094934
−0.00328981
−0.17786385


37
−1.055631982
2.240172964
0.92596118
2.105391988


38
3.158513795
0.592820874
−0.49326241
0.212867212


39
1.083800659
2.069727985
2.48170879
3.205630609


42
−0.103134861
0.267726008
−0.65350189
1.125952363


43
0.323961628
1.469295081
−0.52991193
0.797908251


47
1.703678841
1.348737095
2.00634162
−0.16505407


48
2.370955056
2.783472865
2.68240273
1.221864405


49
1.670680003
−0.41866107
−0.9173849
1.181929544


50
1.670680003
0.076369374
−0.49915943
−0.85392575


52
0.464485039
0.057512869
1.31230219
−0.11170276


53
0.626671823
−0.46954947
−0.33383736
0.277079201


54
0.666149043
0.009549925
−0.36226343
0.197224432


55
0.723473579
−1.50916383
−0.3848989
−0.71458778


57
0.381273227
1.192994109
1.65593321
−1.65739236


59
0.561360663
−0.17793966
−1.63250554
−0.7564969


61
0.146473611
−0.01535544
−0.16339658
1.738656146


62
1.20162032
−0.3576095
−0.10695443
1.322155191


63
1.084291915
2.258720158
−1.01245416
1.688283974


64
0.744770665
0.155243763
−1.8029919
1.023503542


65
0.972835178
2.797151284
1.53453579
0.857051645


67
2.069410561
0.021831924
0.37855159
−0.67235457


68
0.527636614
0.590831983
1.02843762
2.208655795


69
2.133965691
2.088998449
2.05751412
−0.9433713


70
0.327378959
0.996844599
1.23648533
−1.25138371


71
1.40093669
0.778222691
0.70401172
−0.24075444


72
0.617697349
−0.29503359
0.52404847
0.816184656


73
0.617792473
0.888976061
−0.45289639
0.615659244


74
1.437359024
1.548292147
0.10314807
−0.48982286


75
−1.970885622
3.398008325
4.08025266
−0.89948156


76
−1.32746934
−2.65365233
0.10272816
1.001614125


77
−2.541686116
3.295534192
3.75284227
0.404837808


78
−2.110794
2.109874746
3.13350902
−0.3880285


79
1.641162056
−0.28533994
1.53676145
0.652696023


80
1.594400214
0.283682865
2.23140233
1.111682021


81
0.176566806
−2.0786518
−2.13986952
0.981126964


82
0.980373758
−0.28813159
0.19404501
1.252564677


83
0.941833098
0.317310013
1.17606727
0.72992237


84
0.774237336
−0.27140727
0.72461427
−1.56415746


85
2.092976965
0.810644229
0.82999192
−0.62861806


91
2.061595915
−0.79930338
−0.18285395
−0.66898499


92
2.068748434
−0.24299896
0.07214682
−1.11758276


93
−0.08984279
−1.06025959
−0.05068694
1.560050105


96
0.927758203
−0.44129515
0.89190422
0.744284978


97
0.658667572
−0.68771072
0.46051026
−0.53120883


98
0.853222693
−0.2037738
−0.21414441
1.119784962


100
1.654535066
0.995056228
2.35139085
0.543654824


101
2.173663649
−0.11491477
1.48285148
1.698527571


102
2.066679492
−0.16785146
−0.84780149
0.12159477


103
2.335152618
−0.02866585
0.16993375
−0.98254522


104
2.760588276
0.459513599
1.35310241
0.000336976


105
1.654535066
3.654489674
3.13033965
0.544225478


106
1.750588169
−0.55853348
0.50257773
1.630011313


107
0.896789863
0.73615897
0.53011623
−0.54697747


108
0.532375207
0.826537134
1.21040312
0.690230716


109
2.407655187
0.742651426
1.80322099
0.271832856


110
0.54830833
2.916795026
1.40126098
0.690230716


111
0.939597126
−0.3750368
−1.23479972
−0.89366351


112
1.398518854
1.265740274
4.19618377
−0.12762692


113
1.415726941
0.086297006
3.43559555
−0.12964168


115
−1.557729423
−0.44113526
0.86330536
0.590708892


116
0.193562268
−1.58091165
0.83247813
−0.70978039


117
1.353510875
−0.59062398
−0.31776345
−0.3050158


119
0.830052725
2.28725579
0.38409695
0.219336109


120
1.261997955
−0.22622961
−1.04772194
2.028504137


122
1.505653628
−1.14748206
−0.19760084
−0.81373045


123
−0.658721962
−0.21299878
1.01439841
−0.76731016


125
0.749676998
−1.0761601
0.99563924
−1.15409002


126
0.931054384
−0.35067079
1.06050832
−1.62171794


128
−1.344832644
−0.09451199
1.19145467
1.621274257


130
1.153249538
1.605070708
2.38047907
−0.93842293


133
0.840066046
0.2323025
0.19054023
−0.26588341


134
0.522267541
0.824106618
1.83479545
0.364403434


135
2.142817887
2.142411243
−0.93830995
0.696522652


137
3.052627325
3.606270166
0.50445208
0.076323462


140
−0.153437637
0.246303216
0.76565758
1.800968868


141
2.067620311
1.424830396
2.33536931
7.644025075


142
0.98353103
1.950251373
2.50851828
−0.24499521


143
1.736969725
0.991537809
2.5691601
1.227191656


145
−0.211768579
1.46336231
−0.93580247
−1.48749449


146
1.912710035
0.926306508
1.81253333
0.494121361


147
0.675736703
0.99202385
−0.66034472
−0.66302669


148
0.757176542
1.83006252
0.16210659
0.243674851


149
0.438772371
1.091438092
−0.1560319
−0.61711642


150
0.84399938
0.675302022
−1.69771411
−0.73841711


151
0.633570539
0.988413715
−0.54991825
−0.43550324


152
0.911582356
1.974700218
−0.92267786
0.628660087


153
0.319053885
2.531735341
−0.39139184
0.734629224


154
0.714814512
0.690769753
−2.06588692
−0.73356628


155
−0.161798388
0.032135767
−0.13802086
1.734928461


156
−0.571799976
−1.32834264
−1.65346017
1.856689553


157
0.131224024
0.21510779
−1.70996346
0.964902175


158
1.201616145
−0.21158932
−0.8501176
−0.33330779


159
0.811289908
1.606645397
0.25352447
−1.83775117


159
0.811289908
1.606645397
0.25352447
−1.83775117


161
0.475184006
1.99305646
1.90910177
3.288337059


162
0.833030517
0.487189028
1.76798642
0.104378164


163
0.58993703
−0.46431772
0.74883588
−0.81090824


166
−0.121286831
−0.84664528
−0.32625341
0.778055656


167
0.846400186
−0.25922232
0.69248774
1.183696217


168
−0.310930833
−0.81048493
0.08527131
1.61831109


169
−0.2346025
0.890438419
−0.13206526
−0.83961838


170
−0.169223695
1.172917966
−0.11306441
0.099121666


174
2.863652137
0.236674094
−0.69038707
1.610215283


175
1.789769228
−0.31740428
−0.89529921
−0.09686469


176
2.625947334
0.083548191
0.30634559
−0.35925728


177
1.674319352
−0.22179044
0.42093738
−0.23683577


178
2.863652137
0.727069168
−0.26724686
−0.44888613


179
0.070511885
0.365852864
1.35327505
−0.03748038


181
0.976254543
0.691638796
0.51371978
−0.02503945


182
−1.842503751
−0.12688474
2.56277877
0.111744488


183
3.195758563
3.886545621
4.29482769
3.829845293


184
0.333889534
−0.67236766
2.21605977
4.254612125


185
5.61162203
1.40458529
2.86231343
1.035135749


186
1.068190511
−0.65969343
−0.63104765
−1.36962992


187
1.396358739
0.249705611
0.81449499
−0.15353102


189
1.544466636
−0.33742685
0.8096674
−0.44483677


190
−0.210918777
−1.04086063
0.02614862
3.362615492


191
0.715897301
0.666316436
−0.41719538
0.400723176


192
0.65612864
1.231196814
0.75462061
1.514581532


193
−0.394884432
1.129269425
−0.3157071
−0.61478944


194
−2.111794245
−0.71010521
0.53077207
0.59302222


195
1.18880856
0.704463775
1.99312777
1.419709023


196
1.885714606
0.436434665
1.44657532
1.145809063


197
2.174580668
0.133070149
0.99814905
0.871658496


198
−0.533922573
−2.16213117
0.5812107
−0.92280453


199
1.493919434
1.45125612
1.95141371
4.403441058


201
−0.005520296
−0.83362523
0.65480762
−0.38894276


204
0.732981164
−0.97494758
−0.91192246
−1.00034323


205
0.991838899
−0.60053505
−0.49983634
0.674468753


206
2.147983695
1.291351958
1.64553247
1.626455601


208
−0.386224123
−0.24799559
1.19406353
−1.61243489


209
1.447075297
0.122626462
1.08021156
0.473154634


210
−0.386224123
−0.24799559
1.19406353
−1.61243489


211
2.186118467
1.873949371
0.64852028
−0.59205851


212
1.367811201
1.689658923
1.8017376
2.525531645


213
0.925016223
0.875610609
0.31462609
0.847028648


214
−0.239873321
1.808823425
−0.36105512
−0.07650286


215
2.264275088
1.360001278
3.25759951
2.147928282


218
−0.509585598
−0.93428643
1.63030386
−0.79436377


221
1.876297063
0.026873469
0.45442758
1.538486988


227
5.317676982
2.824566654
1.73360625
3.103310061


228
3.323728685
1.554268023
1.8883835
0.957527434


229
3.218950175
1.464118271
2.47512497
1.214429025


230
5.242356467
3.482206715
3.50441556
1.614847073


230
5.242356467
3.482206715
3.50441556
1.614847073


231
2.710087358
1.517756148
0.35088855
0.603171932


231
2.710087358
1.517756148
0.35088855
0.603171932


232
0.703604481
0.42129186
0.39567696
0.41729786


233
1.312921486
0.816597603
2.17066283
0.472801294


234
0.874145958
0.741410502
1.71105733
−0.47289415


237
0.778921491
−1.02119303
0.4612164
−0.8881184


238
0.681403734
−0.342052
1.27750286
−0.3383341


239
−0.870637933
−2.58292907
0.79173772
−1.27888846


242
0.910211214
0.374558101
1.01712685
1.001043471


243
1.670680003
0.104780951
−0.6545574
−0.46985154


244
1.140332181
0.116513028
1.61110902
3.713305291


246
−0.634992987
0.548746912
4.62542427
7.660969857


247
−1.739729444
−0.91508372
1.18693162
3.108631198


248
5.81821686
6.320330665
6.14379552
5.214046447


249
0.348188924
−0.95333461
−0.08432225
1.866717393


252
2.456287983
−0.02516176
0.76814124
1.756087132


253
1.76915226
0.226389981
−0.18115009
−0.62385199


254
0.658956861
−0.39322197
−0.67153044
1.416053304


255
0.892122738
−0.46985097
0.42813903
−0.46752753


256
0.625043963
−0.65111806
1.4319541
2.110656697


258
−0.187789327
−0.85870492
−0.21766971
0.931521178


259
−1.261365139
−2.33099427
1.33595129
0.43644676


260
2.4020693
2.669351733
2.36395771
1.910609499


261
1.978618006
2.732613301
2.19594212
1.683156477


263
1.350274014
−0.59210334
0.14780643
−0.13113746


264
0.526085484
−1.54983116
−0.17497208
−0.8204696


267
1.175997006
−1.03507906
−0.11004734
−0.50564806


269
2.367197222
0.457286256
0.02211231
0.497925297


270
0.711734628
−1.45058685
−0.17018094
−0.71795736


271
1.073564668
−0.47951936
−0.80269361
0.136837431


273
0.663835001
−1.5674675
0.28509522
−1.12959038


274
1.628173498
−0.58892922
−0.3892777
−0.66728139


275
0.935336765
−0.9522644
−0.87000279
−0.29365972


276
−5.989155804
1.722071272
3.31094703
1.273171428


277
0.904631703
−1.02628534
0.49274649
1.000655271


278
0.293923493
−0.82335619
0.13147975
2.730914048


280
−0.284822555
0.322094188
3.2184015
0.383213731


281
2.201373139
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904
−1.320466583
−2.49763118
0.9787365
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905
−0.386224123
−0.24799559
1.19406353
−1.61243489


908
1.878331515
1.287303121
0.11530502
1.132065786


909
0.614968453
−1.61827184
−0.80789799
−0.66927285


912
0.530707518
0.774109528
3.0396125
4.394775258


913
0.337020095
1.531840025
0.10544973
0.347450471


914
0.774589061
1.224705331
1.87994281
−0.11684579


916
−0.363201351
0.35600238
−1.20673542
2.056973054


918
0.153047955
0.702054562
0.76757802
0.096096862


919
2.891894151
2.295157633
3.54101626
1.984030826


920
1.292959895
0.808281618
2.92956952
2.204248324


921
−0.465333775
0.862817284
0.1439546
0.64701735


922
1.54265003
0.291977233
0.79089158
0.801314068


923
1.340862559
0.503169303
0.53213093
3.164832031


924
0.158497146
1.507280765
2.25315926
1.173977914


925
1.23162703
1.671882685
3.1838372
−0.22917041


926
2.608734063
3.080604939
−0.69726361
−0.36219702


927
1.879182741
3.409153142
2.48473663
3.409954437


928
−0.093106169
0.019939108
0.15932154
1.229749745


929
1.670680003
1.94609957
0.19633838
1.14825764


930
3.052627325
0.956834107
−0.29721209
−0.31007607


931
0.367631287
0.501274945
−1.31074554
−0.39331005


933
3.702965303
3.03402795
4.33630831
4.238503729


937
0.570011387
0.097928934
1.03350455
−0.13392581


939
1.801474588
0.770314085
0.70188154
0.22333959


940
−0.412950838
−0.1781887
0.50649275
−0.57215449


941
1.691004766
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0.66279648
0.0318465


942
1.451782586
−0.565439
−0.32447381
−0.43378383


943
1.188491672
0.120632811
0.20106994
3.078484746


945
1.214814941
0.806987609
0.47605587
1.372949466


946
0.561732094
1.21448402
0.35542793
−1.03704442


947
0.956565856
1.505997176
0.88115653
−0.60583691


948
0.592575441
1.383482681
0.93567635
1.058669028


950
0.343657562
−0.85471906
−0.21125904
1.184648122


951
1.236659334
3.828926809
1.57729777
−0.31942874


953
1.836389049
0.755753735
−0.36014522
1.262853393


953
1.836389049
0.755753735
−0.36014522
1.262853393


954
1.001653875
−0.85635082
0.89224781
−0.39245818


955
−0.122918652
−0.846489
−0.63367729
1.182912962


956
0.589766639
−0.9783487
−0.67638264
−0.38772225


958
0.715082397
−0.90020686
0.86817768
0.030652004


959
1.609198886
0.500797943
0.795571
0.908389449


960
0.952787327
−0.90555475
−0.17381408
0.06786323


962
1.836429446
0.208275147
−0.14300625
1.067462181


965
1.9158432
0.35211823
−1.02174589
0.625657932


967
1.383869627
0.274520494
−0.11659267
0.840327437


969
−0.445579934
−1.68867059
−0.5241276
2.233793943


971
0.736419048
0.409875189
−0.63140848
0.034514594


973
1.073465817
2.18418874
2.01361447
−0.93754437


974
0.130904221
1.882440008
1.85101055
0.112524893


976
−0.236681385
−0.09745533
0.1779313
2.08923366


977
0.904402612
0.936956925
0.87731788
0.102346515


978
2.201759817
2.123549573
3.7881607
2.358768953


980
1.784266982
1.845281076
3.42873622
−0.31098233


981
−0.225023329
0.087962898
−0.29053012
0.514272787


982
−0.231175318
−0.0159671
1.27391892
1.090487158


983
0.889215441
0.24321159
0.06877629
0.816247177


985
1.864634345
0.133647536
1.29803755
1.951226654


986
0.511450274
−2.33512445
−0.56246315
−0.42184152


987
0.847260813
0.368638185
0.4114346
0.219336109


988
1.596170102
1.592158381
0.30052357
0.283467897


993
−3.549941097
−2.6847861
−0.17502622
1.41034664


994
0.445802042
0.899738574
0.61059602
0.323194673


995
0.949498724
0.357111159
0.28371155
−0.14156488


998
2.197271885
1.578871826
0.90563334
1.056619658


998
2.197271885
1.578871826
0.90563334
1.056619658


1000
1.456120673
0.626173572
0.07683183
−0.43324035


1001
−0.440378333
0.918089245
0.03050609
−1.62235977


1002
0.819929066
0.459101825
−0.09227583
0.324342063


1003
1.64412453
−0.09343399
0.70197344
3.710273595


1004
0.796928207
0.459954079
−0.88538616
0.152000937


1005
0.044923203
−0.19994963
0.60082875
0.258347835


1006
−0.320452673
−0.33232662
−0.52315783
1.406273663


1007
4.040291133
3.474551355
3.57146797
3.565985043


1008
0.764519082
0.917635102
2.88258762
2.319622474


1009
−0.071112206
0.539362906
2.98048732
0.580423329


1010
−0.689737481
0.547928768
1.98805626
−0.76653376


1011
0.343668917
0.931501008
−0.05483722
0.395369857


1012
1.926713131
0.124849138
−0.09654906
1.126499382


1016
0.124247716
0.193102712
0.39003599
1.737670628


1017
0.131224136
0.21510779
−1.70996346
0.964902175


1018
0.499624069
0.962843507
0.77617619
−1.15296947


1019
0.813491983
0.322635656
0.02800396
0.599500927


1020
0.715468114
1.015469049
1.45994989
0.352548581


1021
−1.176339404
1.539767848
−0.14427147
1.389902738


1022
1.364966718
1.690570939
2.05914194
2.364375484


1023
2.154641091
0.800066339
0.85365652
0.965810338


1024
2.302280068
1.252164308
1.73414439
1.549538352


1025
1.878331515
1.287303121
0.11530502
1.132065786


1026
2.97722987
2.096441965
3.87172868
0.550274831


1027
2.474381478
1.950326182
3.81861867
1.366897355


1028
1.778414353
3.114931059
4.47690731
6.054314034


1029
3.672910795
2.760483725
3.26915034
3.042677588


1030
−0.604959715
−2.13584086
0.8687855
0.024144016


1031
2.012732245
2.293857161
0.54405555
1.261882121


1032
−1.086688867
0.953083194
2.92177054
0.876865185


1033
1.617520676
1.008017006
2.21183536
−0.1288484


1035
2.506372295
3.419954592
4.58206882
4.134341651


1036
−0.675805062
−0.15357004
0.94597719
3.966016669


1037
−0.275092569
−0.67687665
−0.52763797
1.489972106


1038
2.753559643
3.81185814
2.71344734
2.243351472


1039
0.65087433
0.026885305
−0.0153558
0.011870127


1040
0.141526548
−1.65455278
0.50170705
−1.90794


1041
0.458680435
−0.69730218
−0.48806249
0.586073092


1042
−0.513264812
−0.22001961
0.36339519
1.03208599


1043
−1.497887014
−1.76116109
−0.76634926
1.137002742


1045
2.863652137
1.96790869
0.43661485
−0.44756897


1046
0.981194248
1.73892162
2.21166953
2.738129365


1047
0.981194248
1.73892162
2.21166953
2.738129365


1051
0.70261974
−0.22197386
0.19710806
−2.37196477


1052
0.662126832
0.741436531
0.61672724
0.289359903


1053
0.87463644
−0.19717783
1.2664131
−0.4187507


1054
0.284558077
−1.46754925
−0.03124571
0.587227244


1055
0.885837831
−0.91907796
−0.45817355
−1.1936897


1057
0.790964847
1.387925398
−0.18370692
1.302393792


1058
−1.052897931
−0.85226912
0.90324527
−1.09684959


1059
−0.871565421
−0.17856476
1.51267137
−1.52734367


1060
3.311161199
3.074783921
2.10199297
1.822541682


1061
−0.655128061
0.497032417
0.92381279
−0.56348341


1062
−0.443129049
0.96200606
1.51641349
−0.22974864


1063
1.385675542
0.738759296
1.1677069
0.501211562


1064
1.670680003
−0.20756775
−0.73755051
−0.84924056


1065
1.43532227
1.656262941
−1.09448841
1.674272267


1066
1.670680003
1.284791101
0.14864516
−0.84985664


1067
2.237616041
0.345329863
−0.60597063
−0.71581056


1069
−0.24632881
−0.23975349
−0.01449288
0.574861147


1070
1.670680003
0.070165381
−0.64700996
−0.85055617


1071
−1.02687397
−0.36244273
0.13010074
0.535909448


1072
1.670680003
1.94609957
0.19633838
1.14825764


1073
2.237616041
1.438074134
0.31117554
−0.71786492


1074
−0.192632911
0.142411101
0.79310676
0.125548041


1075
0.909356011
0.368597887
1.03689838
1.001198751


1076
0.812238101
0.195908668
0.21564664
0.219336109


1077
0.325255266
1.131242708
−2.79377204
−0.62848261


1078
0.325255266
1.131242708
−2.79377204
−0.62848261


1079
0.85330799
−0.6855194
−0.90046979
−0.46415796


1081
−0.131519393
0.731836014
0.81604919
−1.29993979


1082
0.744770665
0.155243763
−1.8029919
1.023503542


1083
1.415726941
0.086297223
3.43559555
−0.12964168


1084
0.161304111
0.66712144
0.58401752
0.373809692


1085
−0.72863532
−0.2873027
2.21251376
3.003873022


1088
−1.1773616
−0.23258175
0.40529195
0.994988969


1089
2.769817302
1.661618789
3.97585272
1.059236597


1090
3.052627325
0.420821685
−0.57080756
1.751222205


1091
−3.379896722
−3.71174986
2.53586709
0.644702886


1093
0.72304265
1.667011476
2.53982093
2.7903213


1095
0.744219765
1.372184572
0.15852396
1.126053442


1097
4.407270402
2.670641491
5.02636153
5.361271976


1098
−1.85804837
−2.59071226
−0.46522239
0.655734646


1099
0.745797788
−0.20547378
4.27836342
4.646390386


1102
2.068748434
−0.24299896
0.07214682
−1.11758276


1104
1.018876287
0.025163067
−0.1106021
0.838914654


1105
2.387326861
3.865456674
2.2251199
0.728667998


1107
2.352582059
2.595496601
3.20492728
2.844590737


1110
0.302703712
0.599942142
−0.25637571
−0.03195517


1111
0.750930333
0.656784751
1.68326413
0.329846578


1112
−0.205527848
0.287622624
−0.00340777
0.59203719


1115
0.999825037
0.662221152
0.43571192
0.342558518


1116
0.873381263
1.544324176
0.13703728
−0.38172701


1117
−0.682983903
1.798204302
2.42110319
−0.39173951


1118
0.069769623
0.496895599
0.67857133
−0.14954441


1119
−0.671908804
−0.65984824
0.5238174
−0.85314111


1120
0.953790113
1.106552668
3.00006904
1.585038764


1121
−1.184630973
2.476138312
4.80971952
2.450646806


1122
−1.02687397
−0.36244273
0.13010074
0.535909448


1125
0.387315524
−0.36101406
1.14153708
−0.75303953


1126
1.021783831
−0.0070257
−0.14327539
3.954381426


1127
0.990592079
0.305612583
0.14155512
−0.29526854


1128
0.990592079
0.305612583
0.14155512
−0.29526854


1129
3.18966648
3.284362987
4.49398568
3.950809104


1131
1.650621055
1.545704806
2.37535081
1.259373143


1133
−1.519747805
−0.60804324
0.02746106
0.590708892


1134
0.815942067
−0.16126019
−0.54117238
0.613093526


1135
0.626973385
1.998305877
2.61706075
1.570404253


1136
2.812199484
1.353198146
2.05618426
1.869204406


1137
2.208307057
1.387136198
3.21521374
2.069795393


1138
1.670680003
1.316442078
0.14822999
−0.46985154


1139
1.408517438
0.890457374
1.24524408
0.685687797


1140
2.765860952
2.525539595
4.12464228
3.833744077


1141
−0.484394663
0.677713073
−0.22783646
−0.37267608


1142
2.54335679
4.298105601
3.36234238
2.684404542


1143
4.204367611
3.062126931
3.4234313
2.072899554


1144
2.479165229
3.226545885
4.65897152
4.952127235


1145
2.479158921
3.226545885
4.65897152
4.952127235


1146
0.774334025
1.075800774
1.06893156
1.011113116


1147
0.844648531
1.21935371
2.59138595
0.805938034


1148
2.906236436
1.550674121
3.56959167
2.832126896


1149
2.837627443
3.707154326
4.53384262
2.625871865









Particles

The malodor reduction materials can be practical for inclusion in particles. The particles can comprise about 30% to about 95% by weight of a carrier. The particles can comprise about 0.1% to about 30% by weight of a perfume. The particles can comprise about 0.00025% to about 30% by weight of a malodor agent. The particles can comprise about 0.001% to about 30% by weight of a malodor agent. The malodor agent can comprise one or more reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001. The particles can have a mass between about 0.1 mg to about 5 g.
The malodor reduction materials can have a Fragrance Fidelity Index of from about Fragrance Fidelity Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1and most preferably 0 or a Fragrance Fidelity Index average of 3 to about 0.001.
The particles can comprise a weight ratio of parts of malodor agent to perfume of from about 1:20,000 to about 3000:1, optionally from about 1:10,000 to about 1,000:1, optionally 5,000:1 to about 500:1, optionally from about 1:15 to about 1:1.
The particles can comprise one or more malodor reduction materials having a log P greater than 3, preferably greater than 3 but less than 8, preferably said one or more malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147;1148, 1149, and mixtures thereof; optionally the malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097and mixtures thereof; optionally the malodor reduction materials are selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148, 1149 Table 5 material 248 and mixtures thereof, optionally the malodor reduction materials are selected from the group consisting of Table 4 materials 261; 680; 788;1129, 1148, 1149 and mixtures thereof. All of the aforementioned odor reduction materials have a log P that is equal to or greater than 3, thus they deposit through the wash especially well. The more selective lists of malodor materials above can be practical for counteracting all of the key malodors.
In one aspect of said product, said malodor reduction materials are not selected from the group consisting of Table 1-3 malodor reduction materials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 or mixtures thereof.
The malodor reduction materials can be unencapsulated. The malodor reduction materials can be encapsulated. The malodor agent can comprise one or more encapsulated malodor reduction materials and one or more unencapsulated malodor reduction materials. One or more of the malodor reduction materials can be provided in a delivery system. The delivery system can include a delivery system selected from the group consisting of polymer-assisted delivery, molecular assisted deliver, cyclodextrin deliver, starch encapsulated delivery, zeolite delivery, inorganic delivery, and combinations thereof.
The carrier can be or comprise a material selected from the group consisting of water soluble inorganic alkali metal salt, water-soluble alkaline earth metal salt, water-soluble organic alkali metal salt, water-soluble organic alkaline earth metal salt, water soluble carbohydrate, water-soluble silicate, water soluble urea, and any combination thereof. Alkali metal salts can be, for example, selected from the group consisting of salts of lithium, salts of sodium, and salts of potassium, and any combination thereof. Useful alkali metal salts can be, for example, selected from the group consisting of alkali metal fluorides, alkali metal chlorides, alkali metal bromides, alkali metal iodides, alkali metal sulfates, alkali metal bisulfates, alkali metal phosphates, alkali metal monohydrogen phosphates, alkali metal dihydrogen phosphates, alkali metal carbonates, alkali metal monohydrogen carbonates, alkali metal acetates, alkali metal citrates, alkali metal lactates, alkali metal pyruvates, alkali metal silicates, alkali metal ascorbates, and combinations thereof.
Alkali metal salts can be selected from the group consisting of, sodium fluoride, sodium chloride, sodium bromide, sodium iodide, sodium sulfate, sodium bisulfate, sodium phosphate, sodium monohydrogen phosphate, sodium dihydrogen phosphate, sodium carbonate, sodium hydrogen carbonate, sodium acetate, sodium citrate, sodium lactate, sodium tartrate, sodium silicate, sodium ascorbate, potassium fluoride, potassium chloride, potassium bromide, potassium iodide, potassium sulfate, potassium bisulfate, potassium phosphate, potassium monohydrogen phosphate, potassium dihydrogen phosphate, potassium carbonate, potassium monohydrogen carbonate, potassium acetate, potassium citrate, potassium lactate, potassium tartrate, potassium silicate, potassium, ascorbate, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of salts of magnesium, salts of calcium, and the like, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of alkaline metal fluorides, alkaline metal chlorides, alkaline metal bromides, alkaline metal iodides, alkaline metal sulfates, alkaline metal bisulfates, alkaline metal phosphates, alkaline metal monohydrogen phosphates, alkaline metal dihydrogen phosphates, alkaline metal carbonates, alkaline metal monohydrogen carbonates, alkaline metal acetates, alkaline metal citrates, alkaline metal lactates, alkaline metal pyruvates, alkaline metal silicates, alkaline metal ascorbates, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of magnesium fluoride, magnesium chloride, magnesium bromide, magnesium iodide, magnesium sulfate, magnesium phosphate, magnesium monohydrogen phosphate, magnesium dihydrogen phosphate, magnesium carbonate, magnesium monohydrogen carbonate, magnesium acetate, magnesium citrate, magnesium lactate, magnesium tartrate, magnesium silicate, magnesium ascorbate, calcium fluoride, calcium chloride, calcium bromide, calcium iodide, calcium sulfate, calcium phosphate, calcium monohydrogen phosphate, calcium dihydrogen phosphate, calcium carbonate, calcium monohydrogen carbonate, calcium acetate, calcium citrate, calcium lactate, calcium tartrate, calcium silicate, calcium ascorbate, and combinations thereof. Inorganic salts, such as inorganic alkali metal salts and inorganic alkaline earth metal salts, do not contain carbon. Organic salts, such as organic alkali metal salts and organic alkaline earth metal salts, contain carbon. The organic salt can be an alkali metal salt or an alkaline earth metal salt of sorbic acid (i.e., asorbate). Sorbates can be selected from the group consisting of sodium sorbate, potassium sorbate, magnesium sorbate, calcium sorbate, and combinations thereof.
The carrier can be or comprise a material selected from the group consisting of a water-soluble inorganic alkali metal salt, a water-soluble organic alkali metal salt, a water-soluble inorganic alkaline earth metal salt, a water-soluble organic alkaline earth metal salt, a water-soluble carbohydrate, a water-soluble silicate, a water-soluble urea, and combinations thereof.
The carrier or water soluble-soluble carrier can be selected from the group consisting of sodium chloride, potassium chloride, calcium chloride, magnesium chloride, sodium sulfate, potassium sulfate, magnesium sulfate, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, sodium acetate, potassium acetate, sodium citrate, potassium citrate, sodium tartrate, potassium tartrate, potassium sodium tartrate, calcium lactate, water glass, sodium silicate, potassium silicate, dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose, isomalt, xylitol, candy sugar, coarse sugar, and combinations thereof. In one embodiment, the carrier or water-soluble carrier can be sodium chloride. In one embodiment, the carrier or water-soluble carrier can be table salt.
The carrier can be or comprise a material selected from the group consisting of sodium bicarbonate, sodium sulfate, sodium carbonate, sodium formate, calcium formate, sodium chloride, sucrose, maltodextrin, corn syrup solids, corn starch, wheat starch, rice starch, potato starch, tapioca starch, clay, silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, and combinations thereof.
The carrier can be selected from the group consisting of water soluble organic alkali metal salt, water soluble inorganic alkaline earth metal salt, water soluble organic alkaline earth metal salt, water soluble carbohydrate, water soluble silicate, water soluble urea, starch, clay, water insoluble silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, polyethylene glycol, and combinations thereof.
The carrier can be selected from the group consisting of polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl amine, partially hydrolyzed polyvinyl acetate, polyalkylene oxide, polyethylene glycol, acrylamide, acrylic acid, cellulose, alkyl cellulosics, methyl cellulose, ethyl cellulose, propyl cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides, starch, modified starch, gelatin, alginates, xyloglucans, hemicellulosic polysaccharides, xylan, glucuronoxylan, arabinoxylan, mannan, glucomannan, galactoglucomannan, natural gums, pectin, xanthan, carrageenan, locus bean, arabic, tragacanth, polyacrylates, sulfonated polyacrylates, water-soluble acrylate copolymers, alkylhydroxy cellulosics, methylcellulose, carboxymethylcellulose sodium, modified carboxy-methylcellulose, dextrin, ethylcellulose, propylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol copolymers, hydroxypropyl methyl cellulose, and mixtures thereof. A water soluble carrier can be practical.
The particles can comprise from about 40% by weight to about 99% by weight of the particles of the carrier. The carrier can be polyethylene glycol.
The precursor material can comprise more than about 40% by weight polyethylene glycol having a weight average molecular weight from about 2000 to about 13000. Polyethylene glycol (PEG) has a relatively low cost, may be formed into many different shapes and sizes, minimizes unencapsulated perfume diffusion, and dissolves well in water. PEG comes in various weight average molecular weights. A suitable weight average molecular weight range of PEG includes from about 2,000 to about 13,000, from about 4,000 to about 12,000, alternatively from about 5,000 to about 11,000, alternatively from about 6,000 to about 10,000, alternatively from about 7,000 to about 9,000, alternatively combinations thereof. PEG is available from BASF, for example PLURIOL E 8000.
The particles can comprise more than about 40% by weight of the particles of PEG. The particles can comprise more than about 50% by weight of the particles of PEG. The particles can comprise more than about 60% by weight of the particles of PEG. The particles may comprise from about 65% to about 99% by weight of the composition of PEG. The particles may comprise from about 40% to about 99% by weight of the composition of PEG.
Alternatively, the particles can comprise from about 40% to less than about 90%, alternatively from about 45% to about 75%, alternatively from about 50% to about 70%, alternatively combinations thereof and any whole percentages or ranges of whole percentages within any of the aforementioned ranges, of PEG by weight of the particles.
Depending on the application, the particles can comprise from about 0.5% to about 5% by weight of the particles of a balancing agent selected from the group consisting of glycerin, polypropylene glycol, isopropyl myristate, dipropylene glycol, 1,2-propanediol, and PEG having a weight average molecular weight less than 2,000, and mixtures thereof.
The particles can comprise an antioxidant. The antioxidant can help to promote stability of the color and or odor of the particles over time between production and use. The particles can comprise between about 0.01% to about 1% by weight antioxidant. The particles can comprise between about 0.001% to about 2% by weight antioxidant. The particles can comprise between about 0.01% to about 0.1% by weight antioxidant. The antioxidant can be butylated hydroxytoluene.
In addition to the PEG in the particles, the particles can comprise perfume. The perfume can be unencapsulated perfume, encapsulated perfume, or a combination of encapsulated perfume and unencapsulated perfume.
The particles can comprise 0.1% to about 30% by weight perfume, or optionally 0.1% to about 20% by weight perfume. The perfume can be unencapsulated perfume, encapsulated perfume, perfume provided by a perfume delivery technology, or a perfume provided in some other manner Perfumes are generally described in U.S. Pat. No. 7,186,680 at column 10, line 56, to column 25, line 22. The particles can comprise unencapsulated perfume and are essentially free of perfume carriers, such as perfume microcapsules. The particles can comprise perfume carrier materials (and perfume contained therein). Examples of perfume carrier materials are described in U.S. Pat. No. 7,186,680, column 25, line 23, to column 31, line 7. Specific examples of perfume carrier materials may include cyclodextrin and zeolites.
The particles can comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of perfume by weight of the particles. The particles can comprise from about 0.1% by weight to about 6% by weight of the particles of perfume. The perfume can be unencapsulated perfume and or encapsulated perfume.
The perfume can comprise a perfume raw material having a saturation vapor pressure greater than about 0.01 torr. Such a vapor pressure can be practical for having the perfume be sufficiently volatile to reach the consumers nose when the particles are in use. The composition can comprise a perfume raw material having a logP greater than about 3. Such a logP for the perfume can be practical for having acceptable deposition onto a laundry article, article of clothing. The perfume can comprise a perfume raw material having a saturation vapor pressure greater than about 0.01 torr and a logP greater than about 3. Such a perfume can be practical for providing sufficient volatility for the perfume to reach the consumers nose and sufficient deposition on to a laundry article, article of clothing, textile, or the like.
The particles can be free or substantially free of a perfume carrier. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of unencapsulated perfume by weight of the particles.
The particles can comprise unencapsulated perfume and perfume microcapsules. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively from about 2% to about 10%, alternatively combinations thereof and any whole percentages or ranges of whole percentages within any of the aforementioned ranges, of the unencapsulated perfume by weight of the particles. Such levels of unencapsulated perfume can be appropriate for any of the particles disclosed herein that have unencapsulated perfume.
The particles can comprise unencapsulated perfume and a perfume microcapsule but be free or essentially free of other perfume carriers. The particles can comprise unencapsulated perfume and perfume microcapsules and be free of other perfume carriers.
The particles can comprise encapsulated perfume. Encapsulated perfume can be provided as a plurality of perfume microcapsules. A perfume microcapsule is perfume oil enclosed within a shell. The shell can have an average shell thickness less than the maximum dimension of the perfume core. The perfume microcapsules can be friable perfume microcapsules. The perfume microcapsules can be moisture activated perfume microcapsules.
The perfume microcapsules can comprise a melamine/formaldehyde shell. Perfume microcapsules may be obtained from Appleton, Quest International, or International Flavor & Fragrances, or other suitable source. The perfume microcapsule shell can be coated with polymer to enhance the ability of the perfume microcapsule to adhere to fabric. This can be desirable if the particles are designed to be a fabric treatment composition. The perfume microcapsules can be those described in U.S. Patent Pub. 2008/0305982.
The particles can comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of encapsulated perfume by weight of the particles.
The particles can comprise perfume microcapsules but be free of or essentially free of unencapsulated perfume. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively about 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of encapsulated perfume by weight of the particles.
The particles may comprise dye. The particles may comprise less than about 0.1%, alternatively about 0.001% to about 0.1%, alternatively about 0.01% to about 0.02%, alternatively combinations thereof and any hundredths of percent or ranges of hundredths of percent within any of the aforementioned ranges, of dye by weight of the particles. Examples of suitable dyes include, but are not limited to, LIQUITINT PINK AM, AQUA AS CYAN 15, and VIOLET FL, available from Milliken Chemical.
The particles may have a variety of shapes. The particles may be formed into different shapes include tablets, pills, spheres, and the like. A particle can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong. Lentil shaped refers to the shape of a lentil bean. Compressed hemispherical refers to a shape corresponding to a hemisphere that is at least partially flattened such that the curvature of the curved surface is less, on average, than the curvature of a hemisphere having the same radius. A compressed hemispherical particle 10 can have a ratio of height (H) to maximum base dimension B of from about 0.01 to about 0.45, as shown in FIG. 1, alternatively from about 0.1 to about 0.45, alternatively from about 0.1 to about 0.4, alternatively from about 0.2 to about 0.3, the base being the substantially flat surface of the compressed hemispherical particle. Oblong shaped refers to a shape having a maximum dimension and a maximum secondary dimension orthogonal to the maximum dimension, wherein the ratio of maximum dimension to the maximum secondary dimension is greater than about 1.2. An oblong shape can have a ratio of maximum base dimension to maximum minor base dimension greater than about 1.5. An oblong shape can have a ratio of maximum base dimension to maximum minor base dimension greater than about 2. Oblong shaped particles 10 can have a maximum base dimension from about 2 mm to about 6 mm, a maximum minor base dimension of from about 2 mm to about 6 mm
Individual particles 10 can have a mass from about 0.1 mg to about 5 g, alternatively from about 10 mg to about 1 g, alternatively from about 10 mg to about 500 mg, alternatively from about 10 mg to about 250 mg, alternatively from about 0.95 mg to about 125 mg, alternatively combinations thereof and any whole numbers or ranges of whole numbers of mg within any of the aforementioned ranges. In a plurality of particles 10, individual particles 10 can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong.
An individual particle may have a volume from about 0.003 cm3 to about 0.15 cm3. A number of particles 10 may collectively comprise a dose for dosing to a laundry washing machine or laundry wash basin. A single dose of the particles 10 may comprise from about 1 g to about 27 g. A single dose of the particles 10 may comprise from about 5 g to about 27 g, alternatively from about 13 g to about 27 g, alternatively from about 14 g to about 20 g, alternatively from about 15 g to about 19 g, alternatively from about 18 g to about 19 g, alternatively combinations thereof and any whole numbers of grams or ranges of whole numbers of grams within any of the aforementioned ranges. The individual particles 10 forming the dose of particles 10 that can make up the dose can have a mass from about 0.95 mg to about 2 g. The plurality of particles 10 can be made up of particles 10 having different size, shape, and/or mass. The particles 10 in a dose can have a maximum dimension less than about 1 centimeter.
Particles 10 that have occlusions of gas can be practical for possibly multiple reasons. Such particles 10 can float in a liquid. Particles 10 that have gas entrained therein are comprised of gas inclusions and solid and or liquid materials. Since the particles 10 have gas entrained therein, the particles 10 have a density that is less than the density of the constitutive solid and or liquid materials forming the particle. For instance if the particle is formed of a constitutive material having a density of 1 g/cm3, and the particle is 10% by volume air, the density of the particle is 0.90 g/cm3.
For particles 10 that are used as a laundry scent additive, it can be practical that the particles 10 float in the wash solution of a laundry washing machine. Providing particles 10 that float in a the wash solution of a washing machine can provide the benefit of enhanced perfume bloom during the washing cycle as compared to particles 10 that sink and remain submerged during the washing cycle. As the particles 10 dissolve in the wash, encapsulated perfume and or unencapsulated perfume can be released from the particles 10. Perfume bloom during the washing cycle can be important to the consumer in that it can promote a more pleasant experience to the person doing the laundry and can provide a pleasant scent in the portion of the household in which laundering is conducted.
Further, providing particles 10 that float and comprise malodor reduction materials can help release the malodor reduction materials. The malodor reduction materials can reduce the perceived malodor existing in the laundry room from soiled laundry articles that may have been positioned in the laundry room for a long period of time and have developed malodors.
The particles 10 can be packaged together as a packaged composition comprising a plurality of particles 10. The particles 10 can comprise a carrier, perfume, malodor agent, and occlusions of gas. Without being bound by theory, occlusions of gas are thought to provide for improved strength of the particles 10 as compared to particles 10 having occlusions of gas having other shapes. Spherical occlusions of gas might provide for improved strength over non-spherical occlusions of gas.
Each of the particles 10 can have a density less than 1 g/cm3. Each of the particles 10 can have a density less than about 0.95 g/cm3. Since the density of a typical washing solution is about 1 g/cm3, it can be desirable to provide particles 10 that have a density less than 1 g/cm3 or even less than about 0.95 g/cm3. By having the density less than 1 g/cm3 or even less than about 0.95 g/cm3, it is thought that with the typical manufacturing variability for particle making processes, that nearly all of the particles 10 produced will have a density less than about 1 g/cm3. Having nearly all of the particles 10 have a density less than about 1 g/cm3 can be desirable for providing for particles 10 that float in a wash liquor. The perfume bloom and release of malodor reduction materials that can occur from a wash liquor may be greater for particles 10 that float as compared to particles 10 that sink.
Each of the particles 10 can have a mass between about 0.1 mg to about 5 g. The particles 10 can have a maximum dimension of less than about 20 mm The particles 10 can have a maximum dimension of less than about 10 mm The particles 10 having such a mass and maximum dimension are thought to be readily dissolvable in solutions such a wash solutions used in laundering clothing.
Each of the particles 10 can have a volume and the occlusions of gas within the particles 10 can comprise between about 0.5% to about 50% by volume of the particle, or even between about 1% to about 20% by volume of the particle, or even between about 2% to about 15% by volume of the particle, or event between about 4% to about 12% by volume of the particle. Without being bound by theory, it is thought that if the volume of the occlusions of gas is too great, the particles 10 may not be sufficiently strong to be packaged, shipped, stored, and used without breaking apart in an undesirable manner.
The occlusions of gas can have an effective diameter between about 1 micron to about 2000 microns, or even between about 5 microns to about 1000 microns, or even between about 5 microns to about 200 microns, or even between about 25 to about 50 microns. In general, it is thought that smaller occlusions of gas are more desirable than larger occlusions of gas. If the effective diameter of the occlusions of gas are too large, it is thought that the particles 10 might not be sufficiently strong to be to be packaged, shipped, stored, and used without breaking apart in an undesirable manner. The effective diameter is diameter of a sphere having the same volume as the occlusion of gas. The occlusions of gas can be spherical occlusions of gas.
The particles 10 can be formed into water soluble particles 10 that carry the perfume and the malodor reduction materials. The particles 10 can be formed by a rotoforming process. The particles 10 can be formed on a SANDVIK ROTOFORM 3000 having a 750 mm wide 10 m long belt. The rotoforming cylinder can have 2 mm diameter apertures set at 10 mm pitch in the cross machine direction and 9.35 mm pitch in the machine direction. The rotoforming cylinder be set at about 3 mm above the belt. The belt speed and rotational speed of the rotoforming cylinder can be set at 10 m/min A melt of the precursor material for the particles 10 can be pumped to the rotoforming cylinder at a rate of about 3.1 kg/min from a mixer. A plate and frame heat exchanger can be set to control the temperature to be about 50 degrees Celsius. Upstream of the stator of the rotoformer, a gas feed line and mill can be provided to provide for particles 10 having occlusions of gas if desired. The mill can be a rotor-stator type mill. The mill can be a Quadro Z1 in-line mixer with a single stage of medium rotor stators, operated at about 400 RPM. The mill and gas feed line can be combined in a single unit. An Oakes Foamer (E. T. Oakes Corporation, 686 Old Willets Path, Hauppauge, N.Y. 11788) 2MT1A continuous foamer) can be used to provide the gas feed line, flow regulator, and mill in a single unit.
A precursor material comprising the composition of the particles 10 can be prepared by providing molten carrier into a mixer, which can optionally be a batch mixer. The mixer can be heated so as to help prepare the precursor material at the desired temperature. Perfume can added to the molten carrier, optionally in the mixer. Dye, if present, can be added to the mixer. Other adjunct materials can be added to the precursor material if desired. The precursor material can optionally be prepared by in-line mixing or other known approaches for mixing materials.
Method of Use
Any of the particles 10 disclosed herein may be used in any conventional manner. For example, the particles 10 can be used to treat a laundry article. For instance, about 1 g to about 100 g of the particles 10 can be provided in a washing machine or laundry wash basin. The laundry article can be washed in a wash liquor into which the particles 10 are dissolved. The perfume and or malodor reduction materials can form part of the wash liquor. For instance all or a portion of the perfume or perfumes and or malodor reduction material or materials can be dispersed within the wash liquor, dissolved in the wash liquor, exist as a separate phase, or otherwise exist in or be part of the wash liquor. During the wash cycle, all or a portion of the perfume or perfumes and or malodor reduction material or materials can be deposited on the laundry article being washed. All or a portion of the perfume or perfumes and or malodor reduction material may be transported from the wash liquor into the head space above the wash liquor and can be further dispersed into the surroundings of the washing machine or wash basin. The bloom of the malodor reduction materials can help to reduce the impact of malodor present in the room in which the laundry article is washed. The particles 10 can be provided in a fluid pervious package 20, as shown in FIG. 2. The particles 10 can be provided in a water soluble package. The water soluble package 20 can comprise a water soluble film 30, as shown in FIG. 3. The water soluble film can be a polyvinyl alcohol film. The fluid pervious package 20 or water soluble package 20 can contain from about 1 mg to about 100 g of the particles 10.
The laundry article can be treated with a quantity of particles 10 that deliver at least 0.001 mg of malodor agent/kg of laundry article, preferably from about 0.001 mg of malodor agent/kg of laundry article to about 30 mg of malodor agent/kg of laundry article, more preferably from about 0.1 mg of malodor agent/kg of laundry article to about 20 mg of malodor agent/kg of laundry article, most preferably from about 0.2 of malodor agent/kg of laundry article to about 10 mg of malodor agent/kg of laundry article.
The particles 10 can also be used to reduce malodor from a laundry article by providing about 1 g to about 100 g of any of the particles 10 disclosed herein in a fluid pervious package. The fluid pervious package can be a pouch, as shown in FIG. 2. The package can be placed proximal to the laundry article or the package can be contacted with the laundry article. By placing the package proximal to the laundry article or contacting the laundry article with the package one or more of the perfume and the malodor agent can be transferred from the particles 10, through the package, and to the laundry article or the air-space around the laundry article. The mass transfer can occur via diffusion, dispersion, transport of portions of the particles 10 through the package to the laundry article by contact.
Perfumes
The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone, delta-damascone, beta-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies
The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies canalso be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 A1.
In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of: perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:
In one aspect, said perfume delivery technology may comprise perfume microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 33-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone, delta-damascone, beta-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl] cyclopentan-2-one, 2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA, International Flavors & Fragrances Corp. of South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.
In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use “reactive” polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of polymeric amines include polymers based on polyalkylimines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2-aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1and USP 6,413,920 B1.
Test Methods
Malodor reduction materials may be separated from mixtures and indentified by analytical methods that include GC-MS and/or NMR.
Test Method for Determining Saturation Vapor Pressure (VP)
The saturation Vapor Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at 25° C. expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.
Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (logP)
The value of the log of the Octanol/Water Partition Coefficient (logP) is computed for each PRM in the perfume mixture being tested. The logP of an individual PRM is calculated using the Consensus logP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless logP value. The ACD/Labs' Consensus logP Computational Model is part of the ACD/Labs model suite.
Test Method for the Generation of Molecular Descriptors
In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.
For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service (“CAS”), a division of the American Chemical Society, Columbus, Ohio, U.S.A. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.
A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), is used to duplicate the 2-dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.
For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a “.smi” or “.txt” file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: C1=CC═CC═C1 benzene.
The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapor Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water Partition Coefficient (logP); Odor Detection Threshold (ODT); Malodor Reduction Value (MORV); and/or Universal Malodor Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.

    
    
        Computing Molecular Structure Descriptors using winMolconn:
        1) Assemble the molecular structure for one or more perfume ingredients in the form of a MACCS Structure-Data File, also called an SDF file, or as a SMILES file.
        2) Using version 1.0.1.3 of the winMolconn program, running on an appropriate computer, compute the full complement of molecular descriptors that are available from the program, using the SDF or SMILES file described above as input.
        
            a. The output of winMolconn is in the form of an ASCII text file, typically space delimited, containing the structure identifiers in the first column and respective molecular descriptors in the remaining columns for each structure in the input file.
        
        
        3) Parse the text file into columns using a spreadsheet software program or some other appropriate technique. The molecular descriptor labels are found on the first row of the resulting table.
        4) Find and extract the descriptor columns, identified by the molecular descriptor label, corresponding to the inputs required for each model.
        
            a. Note that the winMolconn molecular descriptor labels are case-sensitive.

MORV and Universal MORV calculation

        
        
    
    
    1.) Input Molecular Descriptor values as determined via the method above into the following four equations:

MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)  a)

MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2C2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)  b)

MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).  c)

MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)  d)

    Equation a) relates a material's effectiveness in reducing the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)
    Equation b) relates a material's effectiveness in reducing the malodor trimethylamine (amine based malodors)
    Equation c) relates a material's effectiveness in reducing the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)
    Equation d) relates a material's effectiveness in reducing the malodor skatole (indole based malodors)
    2.) For purpose of the present application, a material's MORV is the highest MORV value from equations 1.)a) through 1.)d).
    3.) If all MORVvalues from equations 1.)a) through 1.)d) above are greater than 0.5, the subject material has a Universal MORV.

Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker Index (BI) for a Malodor Reduction Material



Blocker materials suitable for use in particles 10 of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.
Method for Assigning the FFI to Test Samples
The first step in the method for assigning an FFI to the test samples on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.
Making the FFI Reference Swatches
Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μL of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FFI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.
At least four perfumers/expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert panel is asked to rank order swatches according to a scale between 0 and 3. The panel must demonstrate statistical differences between the swatches as seen in Table 7.







TABLE 7







Results FFI of reference swatches


from six perfumers/expert graders.











Expert Grader

Std
















FFI
Swatch
1
2
3
4
5
6
Ave
Dev.



















0
Control: stripped
0
0
0.5
0
0
0
0.08
0.2



swatch NIL ethyl











vanillin










1
Stripped swatch with
0.5
0.5
0.5
1.5
0.5
1.0
0.75
0.4



13 μL 25 ppm ethyl











vanillin










2
Stripped swatch with
2.0
1.5
1.5
2.0
2.0
2.0
1.8
0.2



13 μL 120 ppm ethyl











vanillin










3
Stripped swatch with
3.0
2.0
3.0
3.0
3.0
3.0
2.8
0.4



13 μL 1000 ppm ethyl











vanillin









The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.







TABLE 8







This table demonstrates acceptable expert graders


with an acceptable range and the panel meets the


requirement for discriminating statistics.











Expert Grader

Std















FFI
Swatch
1
3
4
5
6
Ave
Dev.


















0
Control: stripped swatch
0
0.5
0
0
0
0.08
0.2



NIL ethyl vanillin









1
Stripped swatch with 13 μL
0.5
0.5
1.5
0.5
1.0
0.80
0.4



25 ppm ethyl vanillin









2
Stripped swatch with 13 μL
2.0
1.5
2.0
2.0
2.0
1.9
0.2



120 ppm ethyl vanillin









3
Stripped swatch with 13 μL
3.0
3.0
3.0
3.0
3.0
3.0
0.0



1000 ppm ethyl vanillin









The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch.







TABLE 9







Swatch treatments comprising the Fragrance


Fidelity Index (FFI) reference scale









Swatch treatment
Conc. of ethyl vanillin
FFI





Clean fabric swatch w/ 13 μL
1000 ppm ethyl vanillin
3


ethyl vanillin


Clean fabric swatch w/ 13 μL
 120 ppm ethyl vanillin
2


ethyl vanillin


Clean fabric swatch w/ 13 μL
 25 ppm ethyl vanillin
1


ethyl vanillin


Clean fabric swatch NIL ethyl vanillin
NIL ethyl vanillin
0









Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μLt of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hours of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.
Assigning the FFI to the test material
At least two perfumers/expert graders are used to assign an FFI grade to a test sample. The perfumer/expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FFI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.
Method for Assigning the BI to Test Sample
The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.
Making the BI Reference Swatches
Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acid solution to one clean swatch, 5 μL of the 0.08% isovaleric acid solution to the next swatch and 20 μL of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.
At least four perfumers/expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10.







TABLE 10







Results from six perfumers/expert graders to create the BI scale.











Expert Grader

Std















BI
Swatch
1
2
3
4
5
Ave
Dev.


















0
Control: stripped swatch NIL
0
0
0
0
0
0
0



isovaleric acid









1
Stripped swatch with 2 μL
0.5
2.0
1.0
1.0
0.5
1.0
0.5



0.08% isovaleric acid









2
Stripped swatch with 5 μL
2.0
2.5
2.0
2.0
2.0
2.1
0.2



0.08% isovaleric acid









3
Stripped swatch with 20 μL
3.0
3.0
3.0
3.0
2.5
2.8
0.2



0.08% isovaleric acid









The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.







TABLE 11







This table demonstrates acceptable expert graders


with an acceptable range and the panel meets the


requirement for discriminating statistics.











Expert Grader

Std














BI
Swatch
1
3
4
5
Ave
Dev.

















0
Control: stripped swatch
0
0
0
0
0
0



NIL isovaleric acid








1
Stripped swatch with 2 μL
0.5
1.0
1.0
0.5
0.8
0.3



0.08% isovaleric acid








2
Stripped swatch with 5 μL
2.0
2.0
2.0
2.0
2.0
0



0.08% isovaleric acid








3
Stripped swatch with 20 μL
3.0
3.0
3.0
2.5
2.9
0.2



0.08% isovaleric acid









The reference swatches represent the 0, 1, 2, and 3 BIs on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.







TABLE 12







Swatch treatments comprising the Blocker Index (BI) reference scale.









Swatch/treatment
Wt of isovaleric acid
BI





Clean fabric swatch w/ 20 μL 0.08%
 16 mg isovaleric acid
3


isovaleric acid


Clean fabric swatch w/ 5 μL 0.08%
  4 mg isovaleric acid
2


isovaleric acid


Clean fabric swatch w/ 2 μL 0.08%
1.6 mg isovaleric acid
1


isovaleric acid


Clean fabric swatch NIL isovaleric acid
NIL isovaleric acid
0









Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid +test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid +test material swatches and the BI reference swatches should be made within 2 hrs of each other. The isovaleric acid+test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1and about 100 ppm to determine the BI.
Assigning the BI to the Test Material
At least two perfumers/expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid +test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the isovaleric acid +test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid+test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.
Malodor Reduction Materials with FFI and BI Grades Based on the Aforementioned
















Table








Ref #
CAS#
log P
Name
Conc
FFI
BI





















281
54830-99-8
3.11
3a,4,5,6,7,7a-hexahydro-4,7-
10 ppm
0
2.0





methano-1H-indenyl acetate
50 ppm
0.5
2.0


677
139504-68-0
3.75
1-((2-(tert-
10 ppm
0
2.3





butyl)cyclohexyl)oxy)butan-2-ol
50 ppm
1.8
2.0


962
55066-48-3
3.17
3-methyl-5-phenylpentan-1-ol
10 ppm
0
2.3






50 ppm
0.5
1.7


261
173445-65-3
3.29
3-(3,3-dimethyl-2,3-dihydro-1H-
10 ppm
0
1.8





inden-5-yl)propanal
50 ppm
1.3
1.3


1139
87731-18-8
2.11
(Z)-cyclooct-4-en-1-yl methyl
10 ppm
0
2.0





carbonate
50 ppm
1.0
2.7



4430-31-3
1.43
3,4,4a,5,6,7,8,8a-octahydrochromen-
10 ppm
0
2.0





2-one
50 ppm
0
2.0


204
40379-24-6
3.89
7-methyloctyl acetate
10 ppm
0
2.0






50 ppm
0
2.7


1005
93981-50-1
5.59
ethyl (2,3,6-trimethylcyclohexyl)
50 ppm
0.5
2.6





carbonate





391
106-33-2
5.73
Ethyl laurate
50 ppm
0.3
2.2


1148
1139-30-6
4.06
Caryophyllene Oxide
50 ppm
0.5
2.3


524
13877-91-3
4.31
3,7-Dimethyl-1,3,6-Octatriene(cis-β
50 ppm
0
2.8



3338-55-4

ocimene 70%)





1149
23787-90-8
4
1,3,4,6,7,8alpha-hexahydro-
10 ppm
0
1.5





1,1,5,5-tetramethyl-2H-2,4alpha-
50 ppm
0.8
2.3





methanophtalen-8(5H)-one






112-42-5
4.62
Undecanol
50 ppm
0.8
2.3


174
112-53-8
5.17
1-dodecanol
50 ppm
0.5
2.3



98-52-2
2.78
4-tert-butyl cyclohexane
10 ppm
0
2.0






50 ppm
0.3
2.0


109
112-39-0
6.41
Methyl palmitate
10 ppm

2.0









Malodor Control Materials with Improved Performance at Lower Levels.

Below are some non-limiting examples of preferred behavior by which the malodor control material gives improved malodor control at lower concentration. These nonlimiting data provide additional compelling data that malodor is being blocked, not masked.















Table







Ref #
CAS#
Name
Conc
FFI
BI




















N/A
68912-13-0
8,8-dimethyl-3a,4,5,6,7,7a-
10 ppm
0
1.5




hexahydro-1H-4,7-
50 ppm
0
2.2




methanoinden-6-yl propionate


N/A
TBD
4,8-dimethyl-1-(methylethyl)-
10 ppm

2.0




7-oxybiciclo[4.3.0]nonane
50 ppm
0.3
2.2









Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor reduction material could fail to demonstrate odor blocking (BI>2.5) at a higher concentration it should be retested at a lower concentration to determine if it passes.















Table







Ref #
CAS #
Name
Conc
FFI
BI




















N/A
173445-65-3
1H-Indene-5-propanal, 2,3-
10 ppm
0
1.5




dihydro-3,3-dimethyl-
50 ppm
0.5
2.7









EXAMPLE 1
Compositions Comprising Malodor Reduction Materials
In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction agents.












% wt Active













Component
CAS#
A
B
C
D
E





2,2,8,8-tetramethyl-octahydro-1H-
29461-14-1
35-45
15-25
 5-20
10-30
15-25


2,4a-methanonapthalene-10-one








1H-Indene-ar-propanal,2,3-
300371-33-9
10-20
 1-30
NIL
 5-10
1-5


dihydro-1,1-dimethyl-








Hexadecanoic acid, (2E)-3,7-
3681-73-0
35-45
10-25
NIL
30-40
35-50


dimethyl-2,6-octadien-1-yl ester








1-Pentanol-3-methyl-5-phenyl
55066-48-3
10-20
10-25
 2-10
 5-17
10


4,7-Methano-1H-inden-5-ol,
171102-41-3
0-5
10-25
NIL
1-6
1-5


3a,4,5,6,7,7a-hexahydro-, 5-acetate








4,8-dimethyl-1-(methylethyl)-7-
N/A
0-5
NIL
NIL
NIL
1-5


oxybiciclo [4.3.0]nonane








(3Z)-3,7-dimethylocta-1,3,6-triene
3338-55-4
NIL
NIL
10-20
2-5
NIL


1H-Indene-5-propanal, 2,3-
173445-65-3
NIL
NIL
NIL
7.5-16 
 1-15


dihydro-3,3-dimethyl-








3,4,4a,5,6,7,8,8a-
4430-31-3
NIL
NIL
NIL
3-7
 1-15


octahydrochromen-2-one








1-(2-tert-
139504-68-0
NIL
NIL
NIL
0.25-1.5 
NIL


butylcyclohexyl)oxybutan-2-ol








ethyl (2,3,6-trimethylcyclohexyl)
93981-50-1
NIL
NIL
15-30
NIL
2


carbonate








benzyl 2-hydroxypropanoate
2051-96-9
NIL
NIL
2-5
NIL
NIL


(3,5-dimethylcyclohex-3-en-1-
67634-16-6
NIL
NIL
 5-30
NIL
NIL


yl)methanol








2-Dodecanol
10203-28-8
NIL
0.25-1  
NIL
0.5-3 
NIL









EXAMPLE 2
Compositions Comprising Malodor Reduction Agents












% wt Active














Ingredient
CAS #
A
B
C
B
D
E

















(E)-1-(2,6,6-trimethyl-1-
127-42-4
 4
8
2
8
 3
 2


cyclohex-2-enyl)pent-1-en-3-









one









ethyl dodecanoate
106-33-2
NIL
1
NIL
3
NIL
NIL


3a,4,5,6,7,7a-hexahydro-1H-
68912-13-0
 8
30
1
4
 1
  3.5


4,7-methanoinden-1-yl









propanoate









[1R-(1R*,4R*,6R*,10S*)]-
1139-30-6
NIL
0.3
2
0.5
NIL
  0.5


4,12,12-trimethyl-9-









methylene-5-









oxatricyclo[8.2.0.04,6]dodecane









(8E)-cyclohexadec-8-en-1-one
3100-36-5
NIL
5
NIL
7
NIL
NIL


3,5,5-trimethylhexyl acetate
58430-94-7
25
15
50 
35
60
56


ethyl (2,3,6-
93981-50-1
NIL
1
NIL
5
NIL
NIL


trimethylcyclohexyl)









carbonate









2,4-dimethyl-4,4a,5,9b-
27606-09-3
25
10
15 
15
16
15


tetrahydroindeno[1,2-









d][1,3]dioxine









2,2,7,7-
23787-90-8
 8
9
5
7
 5
 5


tetramethyltricyclo[6.2.1.01,6]









undecan-5-one









(3,5-dimethylcyclohex-3-en-
67634-16-6
NIL
0.7
NIL
0.5
NIL
NIL


1-yl)methanol









3-(7,7-dimethyl-4-
33885-52-8
30
20
25 
15
15
18


bicyclo[3.1.1]hept-3-enyl)-









2,2-dimethylpropanal









Total

100 
100
100 
100
100 
100 









EXAMPLE 3
Malodor Reduction Agent













% wt Active











Ingredient
CAS #
A
B
C














5-Cyclohexadecen-1-One
37609-25-9
15.0
2.00
2.00


decahydro-2,2,7,7,8,9,9-
476332-65-7
0.005
0.01
0.01


heptamethylindeno(4,3a-b)furan


2,3-Dihydro-5,6-dimethoxy-2-(4-
33704-61-9
0.3
0.5
0.5


piperidinylmethylene)-1H-inden-1-one


Cedryl Methyl Ether
19870-74-7
6.0
10.0
4.0


Trans-4-Decenal
65405-70-1
0.005
0.002
0.002


Decyl Aldehyde
112-31-2
3.74
2.0
2.0


3-methyl cyclopentadecenone
63314-79-4
0.4
1.0
1.0


Diphenyl Oxide
101-84-8
0.5
1.0
1.0


3a,4,5,6,7,7a-hexahydro-4,7-methano-
54830-99-8
5.0
8.0
8.0


1H-indenyl acetate


3a,4,5,6,7,7a-hexahydro-1H-4,7-
68912-13-0
6.0
8.0
8.0


methanoinden-1-yl propanoate


2-(5-methyl-2-propan-2-yl-8-
68901-32-6
10.0
15.0
15.0


bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane


(E)-3,7-dimethyl-2,6-
3681-73-0
10.0
10.0
16.0


octadienylhexadecanoate


Iso Nonyl Acetate
58430-94-7
6.65
8.0
3.0


2,2,7,7-
23787-90-8
10.0
8.0
8.0


tetramethyltricyclo[6.2.1.01,6]undecan-5-


one


(1-Methyl-2-(1,2,2-
198404-98-7
0.1
0.3
0.3


trimethylbicyclo[3.1.0]-hex-3-


ylmethyl)cyclopropyl)methanol


Lauric Aldehyde
112-54-9
0.625
1.0
0.7


Methyl Iso Eugenol
93-16-3
18.000
10.0
13.0


Methyl hexadecanoate
112-39-0
3.000
10.0
12.0


2,3-dihydro-1,1-1H-dimethyl-indene-ar-
300371-33-9
0.400
0.0
0.3


propanal


4-tert-butylcyclohexanol
98-52-2
0.400
0.1
0.1


2-isobutyl-4-hydroxy-4-
63500-71-0
1.600
2.0
2.0


methyltetrahydropyran


Undecyl Aldehyde
112-44-7
1.725
2.888
1.888


Undecylenic Aldehyde
112-45-8
0.550
0.2
1.2


Total

100
100.0
100.0









EXAMPLE 4
Malodor Reducing Agent














% wt


Ingredients
CAS#
Active

















5-Cyclohexadecen-1-One
37609-25-9
2.6


2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-
647828-16-8
0.005


b]furan


1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-
33704-61-9
0.3


4H-inden-4-one


(3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-
19870-74-7
6


tetramethyloctahydro-1H-3a,7-methanoazulene


dodecanenitrile
2437-25-4
0.06


Trans 4-Decenal
65405-70-1
0.001


decanal
112-31-2
3


(E)-3-methylcyclopentadec-4-en-1-one
82356-51-2
0.4


oxydibenzene
101-84-8
0.5


Dipropylene Glycol
25265-71-8
0.054


3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-
54830-99-8
4


inden-(5 and 6)-yl acetate


3-(2-ethylphenyl)-2,2-dimethylpropanal
67634-15-5
3


3-(3-isopropylphenyl)butanal
125109-85-5
0.6


8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-
68912-13-0
6


methanoinden-6-yl propionate


2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-
68901-32-6
10


en-2-yl)-1,3-dioxolane


d E)-3,7-dimethylocta-2,6-dien-1-yl palmitate
3681-73-0
10


7-methyloctyl acetate
40379-24-6
3


2,2,7,7-tetramethyltricyclo(6.2.1.0(1,6))-
23787-90-8
10


undecan-5-one


(1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-
198404-98-7
0.1


3-yl)methyl)cyclopropyl)methanol


dodecanal
112-54-9
0.6


Linalyl Benzoate
126-64-7
1.74


4-(tert-butyl)cyclohexyl acetate
32210-23-4
4


octahydro-1H-4,7-methanoindene-1-carbaldehyde
30772-79-3
0.26


methyl 2-(3-oxo-2-pentylcyclopentyl)acetate
24851-98-7
4.15


(Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene
93-16-3
18.23


Methyl Palmitate
112-39-0
3


3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-
300371-33-9
0.4


yl)propanal


4-tert-butyl cyclohexanol
98-52-2
0.05


3-methyl-5-phenylpentan-1-ol
55066-48-3
3.5


2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol
63500-71-0
1.6


(E)-4-methyldec-3-en-5-ol
81782-77-6
0.8


undecanal
112-44-7
1.7


undec-10-enal
112-45-8
0.35









EXAMPLE 5
Particles Comprising a Malodor Agent
Examples of Particles 10 that Comprise a Malodor Reduction Agent


















Blue
Purple
Green





Formula
Formula
Formula


Component
Function
GCAS/CAS
Wt %
Wt %
Wt %







PEG 8000
Carrier
95229421
 80.79%
 80.85%
 80.89%


1-((2-(tert-
Malodor
139504-68-0
 9.60%
 9.60%
 9.60%


butyl)cyclohexyl)oxy)butan-
reduction


2-ol


Malodor reduction
Malodor

 2.40%
 2.40%
 2.40%


agent of Example 5
reduction


Blue AH
Dye
95559345
0.0021%


Liquitint Violet FL
Dye
92038834

 0.015%


Liquitint Green 101
Dye
10053851


0.0011%


Water
Carrier

0.2079%
0.1350%
0.1089%


Unencapsulated
Perfume

 7.00%
 7.00%
 7.00%


Perfume









The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm ”
Every document cited herein, including any cross referenced or related patent or application is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

## Claims

1. A composition comprising a plurality of particles, wherein said particles comprise:
about 30% to about 95% by weight of a carrier;
about 0.1% to about 30% by weight of a perfume; and
about 0.00025% to about 30% by weight of a malodor agent;
wherein said malodor agent comprises one or more malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and
wherein each of said particles has a mass between about 0.1 mg to about 5 g.

2. The composition according to claim 1, wherein said carrier is selected from the group consisting of water soluble organic alkali metal salt, water soluble inorganic alkaline earth metal salt, water soluble organic alkaline earth metal salt, water soluble carbohydrate, water soluble silicate, water soluble urea, starch, clay, water insoluble silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, polyethylene glycol, and combinations thereof.

3. The composition according to claim 1, wherein said carrier is selected from the group consisting of polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl amine, partially hydrolyzed polyvinyl acetate, polyalkylene oxide, polyethylene glycol, acrylamide, acrylic acid, cellulose, alkyl cellulosics, methyl cellulose, ethyl cellulose, propyl cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides, starch, modified starch, gelatin, alginates, xyloglucans, hemicellulosic polysaccharides, xylan, glucuronoxylan, arabinoxylan, mannan, glucomannan, galactoglucomannan, natural gums, pectin, xanthan, carrageenan, locus bean, arabic, tragacanth, polyacrylates, sulfonated polyacrylates, water-soluble acrylate copolymers, alkylhydroxy cellulosics, methylcellulose, carboxymethylcellulose sodium, modified carboxy-methylcellulose, dextrin, ethylcellulose, propylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol copolymers, hydroxypropyl methyl cellulose, and mixtures thereof.

4. The composition according claim 1, wherein said carrier is water soluble.

5. The composition according to claim 1, wherein said perfume comprises encapsulated perfume.

6. The composition according to claim 5, wherein said carrier is polyethylene glycol having a weight average molecular weight from about 2000 to about 13000.

7. The composition according to claim 1, wherein at least a portion of said malodor agent is unencapsulated.

8. The composition according to claim 1, wherein at least a portion of said malodor agent is encapsulated.

9. The composition according to claim 1, wherein said particles comprise occlusions of gas.

10. The composition according to claim 9, wherein said perfume comprises unencapsulated perfume.

11. The composition according to claim 10, wherein each of said particles has a volume and said occlusions of gas within said particles comprise between about 0.5% to about 50% by volume of said particles.

12. The composition according to claim 11, wherein said occlusions of gas have an effective diameter between about 1 micron to about 2000 microns.

13. The composition according to claim 12, wherein said occlusions of gas are spherical occlusions of gas.

14. The composition according to claim 1, wherein said malodor reduction materials have a Fragrance Fidelity Index of from about 3 to about 0.001.

15. The composition according to claim 1, wherein said malodor agent comprises one or more malodor reduction materials having a log P greater than 3 and said one or more malodor reduction materials are selected from the group consisting of 2-ethylhexyl (Z)-3-4-methoxyphenyl)acrylate; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 1,1-dimethoxynon-2-yne; 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; methoxycyclododecane; 1,1-dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate; 1,8-dioxacycloheptadec an-9-one; 4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl furan-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene; 2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal; tetradecanenitrile; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol; 2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide; N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide; 2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol; (Z)-3,7-dimethylocta-2,6-dien-1-ol; methyl (E)-non-2-enoate; 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one; (4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate; 2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite; 1,7-dioxacycloheptadecan-8-one; 1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one; 1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene; 3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one; 1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methyl non-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene; methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; methyl tetradecanoate; methyl (9Z,12Z)-octadeca-9,12-dienoate; methyl palmitate; 1-methyl-2-phenoxybenzene; 1-allyl-4-methoxybenzene; 1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate; 7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol; 3-(3-(tert-butyl)phenyl) -2-methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; (S)-1-methyl-4-(prop-1-en-2-yl)cyecyclohex-1-ene; 3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-yl isobutyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile; 3-(4-methylcyclohex-3-en-1-yl)butanal; (2,5-dimethyl-1,3-dihydroinden-2-yl)methanol; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; dodecan-1-ol; dodecyl acetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one; dodecanal; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol; 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyllmethanol; 2-propylheptanenitrile; 2-hexylcyclopentan-1-one; 2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; isopropyl palmitate; isopropyl tetradecanoate; isopropyl dodecanoate; (E)-cyclohexadec-8-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 2-hexylcyclopent-2-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; (Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; 6-(sec-butyl)quinoline; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; (1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 4-(( 2 R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; (1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl (E)-undec-6-enoate; isopentyl dodecanoate; (E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile; (E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol; 8,8-di(1H-indol -1-yl)-2,6-dimethyloctan-2-ol; 2-cyclododecylpropan-1-ol; 3-methyl-5-phenylpentanenitrile; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate; (Z)-hex-1-en-1-yl (Z)-2-methylbut-2-enoate; (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one; ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; (E)-oxacyclohexadec-13-en-2-one; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate; (1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene; (1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol; (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one; 5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; (1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; (Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene; (1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one; (1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1-(3,3-dimethylcyclohexyl)pent-4-en-1-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; ethyl (3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; (6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol; undec-10-enenitrile; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one; 1-cyclopentadec-4-en-1-one; 1,4-dioxacycloheptadecane-5,17-dione; ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate; 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-9(1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; 7,9-Dimethylspirol[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-1-phenylpropan-2-yl butyrate; octahydro-1H-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate; 3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane; 6-hexyltetrahydro-2H-pyran-2-one; (3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; (1S,8aR)-4,7-dimethyl-1-(prop an-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene; (Z)-1((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one; (1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene; 3,7,7-trimethylbicyclol[4.1.0]hept-3-ene; dec-9-en-1-ol; decyl propionate; 1,1-diethoxydecane; 1-cyclohexylethyl (E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate; 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-1-one; 3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate; 3-(4-methylcyclohex-3-en-1-yl)butan-1-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane; (E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene; (E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-1,3,6-triene; (E)-oxacycloheptadec-11-en-2-one; (Z)-dec-4-enal; (E)-hex-3-en-1-yl (E)-hex-3-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl 2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl cinnamate; hexadecan-1-ol; (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 1,6-dioxacycloheptadecan-7-one; 1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-yl formate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl acetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclol[3.2.1]octane; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one; (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (1S,2S,5R,8S)-4,4,8-trimethyltricyclol[6.3.1.02,5]dodecan-1-ol; 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile; decanoic acid; decanal; 2,2-dimethyl-3-methylenebicyclol[2.2.1]heptane; ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol; 3-(4-(tert-butyl)phenyl)propanal; (1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane; (ethoxymethoxy)cyclododecane; (E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene; 3,3,6,7-tetramethyloctahydro-2H-chromene; (5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spirol[4.5]dec-6-en-8-one; 1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate; (2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal; (R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene; (4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene; (Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene; (1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene; (1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2]-b oxirene; (R)-3 5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene; (1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene; (E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene; (1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; benzyl dodecanoate; benzyl cinnamate; benzyl benzoate; 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl (E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl 2-phenylacetate; pentyl (Z)-3-phenylacrylate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol; 2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol; (3S,5aR,7aS,11aS,11bR)-3,8,8,1 1a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; 2-(sec-butyl)-1-vinylcyclohexyl acetate; (4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane; (E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol; (1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one; (1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R,Z)-1(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one; 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one; (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene; (4aR,8S,9aS)-3,5,5,8tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene; (1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene; 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene; (3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan -2-ol; (R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5 6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol; (Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene; 2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate; (Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene; (E)-2-benzylideneheptanal; (1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; 3-methyl-1-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl 3-cyclohexylpropanoate; (1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; (E)-undec-9-enal; methyl (E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 2,6,10-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)-oxacycloheptadec-8-en-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one; 6-isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal; 6,10,14-trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; (1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one; (Z)-dodec-2-enal; (E)-hex-3-en-1-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3-(4-isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline; (E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-yl acetate; undec-10-en-1-ol; undec-10-enal; 2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal; (S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol; (2E)-3-methyl-5-phenyl-2-pentenenitrile; (2S,5R)-2-isopropyl-5-methylcyclohexan-1-one; (R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane; (E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one; 3-(3-isopropylphenyl)butanal; 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; 2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol; benzyl 2-phenylacetate; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal; 2-methyl-5-(6-methylhept-5-en-2 -yl)bicyclo[3.1.0]hex-2-ene; 1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one; (E)-tridec-2-enal; (1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl (2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; 2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl 2-phenylacetate; phenyl benzoate; phenethyl benzoate; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate; (E)-3 3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-1,3-dioxane; 2,4-dimethyl-4-phenyltetrahydrofuran; (2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; 2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; 2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; (E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal; (1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; (Z)-dodec-4-enal; (1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; 3-methyl-2-pentylcyclopentan-1-one; 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene; (1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7, 8-octahydrocyclopropa[d]naphthalene; 1-isopropyl-2-methoxy-4-methylbenzene; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (Z)-dec-2-enal; (E)-non-2-enal; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one; (Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene; (E)-3,7-dimethylocta-2,6-dien-1-ol; (1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; methyl 2-((1-hydroxy-3-phenylbutyl)amino)benzoate; 1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyl octahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal; 1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 2,4,6-trimethyl-4-phenyl-1,3-dioxane; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol; 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one; 1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol; 1-ethoxy-4-(tert-pentyl)cyclohexane; (3Z)-1-(2-buten-1-yloxy)-3-hexene; 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene; 3-methoxy-3,7-dimethylocta-1,6-diene; 3,7-dimethyloctanal; hexyl 2-hydroxybenzoate; hexyl (Z)-but-2-enoate; (Z)-3,7-dimethylocta-2,6-dien-1-yl formate; (Z)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-en-3-one; (E)-3,7-dimethylocta-4,6-dien-3-ol; methyl (Z)-3,7-dimethylocta-2,6-dienoate; ((1s,4s)-4-isopropylcyclohexyl)methanol; 3,7-dimethylocta-1,6-dien-3-yl propionate; 3,7-dimethylocta-1,6-dien-3-yl formate; 3,7-dimethylocta-1,6-dien-3-yl butyrate; 3,7-dimethylocta-1,6-dien-3-yl acetate; 3,7-dimethylocta-1,6-dien-3-ol; 2,2-dimethyl-5-phenylhexanenitrile; (Z)-4-(6,6-dimethylcyclohex-2-en-1-yl)-3-methylbut-3-en-2-one; 7-methyloctyl acetate; isopentyl octanoate; hexyl propionate; hexyl butyrate; hexyl 2-methylbutanoate; hexyl furan-2-carboxylate; heptyl acetate; (Z)-3,7-dimethylocta-2,6-dienenitrile; (E)-3,7-dimethylocta-2,6-dien-1-yl formate; (E)-3,7-dimethylocta-2,6-dien-1-yl octanoate; (E)-3,7-dimethylocta-2,6-dien-1-yl benzoate; (E)-3,7-dimethylocta-2,6-dienal; 1-isopropyl-4-methylcyclohexa-1,4-diene; 2-(sec-butyl)cyclohexan-1-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; 2-(tert-butyl)cyclohexyl ethyl carbonate; ethyl octanoate; ethyl 2-cyclohexylpropanoate; 4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol; 3-methyl-2-pentylcyclopent-2-en-1-one; 2-(4-methylcyclohexyl)propan-2-yl acetate; 4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one; (oxybis(methylene))dibenzene; dibutyl phthalate; decyl 2-aminobenzoate; methyl (1s,4s)-1,4-dimethylcyclohexane-1-carboxylate; 2-cyclohexylethyl acetate; (3Z,5Z)-2,6-dimethylocta-1,3,5,7-tetraene; 4-cyclohexyl-2-methylbutan-2-ol; 2-benzyl-2-methylbut-3-enenitrile; 3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-1-yl 2-phenylacetate; 3,7-dimethyloct-6-en-1-yl formate; 3,7-dimethyloct-6-en-1-yl benzoate; 3,7-dimethyloct-6-en-1-ol;3,7-dimethyloct-6-enal; (E)-3,7-dimethylocta-2,6-dienal; (1R,2S,5R)-2,6,6-trimethylbicyclol[3.1.1]heptane; (Z)-hex-3-en-1-yl pentanoate; (E)-hex-3-en-1-yl (E)-2-methylbut-2-enoate; (Z)-hex-3-en-1-yl butyrate; 4-chloro-3,5-dimethylphenol; 5-isopropyl-2-methylphenol; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; 3-isopropyl-6-methylenecyclohex-1-ene; benzyl 2-hydroxybenzoate; benzyl 3-methylbutanoate; 1-(3,3-dimethylcyclohexyl)ethyl formate; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; pentyl benzoate; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate; (Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one; (2-(allyloxy)ethyl)benzene; allyl heptanoate; 6,8-dimethylnonan-2-ol; -methyl-5-phenylhexan-3-one; 3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-1-ol; 2-pentylcyclopentan-1-ol; (2S,4S)-2-heptyl-2,4-dimethyl-1,3-dioxolane; (E)-2-isopropyl-5-methylhex-2-enal; 1-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (R)-3,7-dimethylocta-1,6-dien-3-ol;3 7-dimethyloct-6-enal; (R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-1-ol; 3,7-dimethyloct-6-en-1-ol; (1R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; hexyl (Z)-2-methylbut-2-enoate; p-cymene; phenethyl isobutyrate; phenethyl (Z)-2-methylbut-2-enoate; phenethyl methacrylate; (2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one; 1-methoxy-4-propylbenzene; 2-(4-(tert-butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan-1-ol; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; ethyl (2,3,6-trimethylcyclohexyl) carbonate; 1-(3,3-dimethylcyclohexyl)ethyl acetate; (S)-3,7-dimethylocta-1,6-dien-3-ol; 1-isopropyl-4-methylenebicyclo[3.1.0]hexane; 3,7-dimethyloctanal; 4-(2,2,6-trimethylcyclohexyl)butan-2-ol; 3,7-dimethyloctan-3-ol; 3,7-dimethyloctan-3-yl acetate; ethyl (1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate; 2-isopropyl-5-methylphenol; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; 2,2,2-trichloro-1-phenylethyl acetate; 2,2,5-trimethyl-5-pentylcyclopentan-1-one; (4-tert-butylcyclohexyl) acetate; 4-(tert-butyl)cyclohexyl acetate; 4-methyl-4-phenylpentan-2-yl acetate; (Z)-1-((2-methylallyl)oxy)hex-3-ene; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one, and mixtures thereof.

16. The composition according to claim 1, wherein said malodor reduction materials are not selected from the group consisting of geranyl nitrile; helional; nonanal; linalool; (S)-(+)-linalool; (R)-(−)-linalool; nerol; tetrahydrolinalool; 2-phenylethyl acetate; eugenol; ethyl linalool; allyl heptoate; agrumen nitrile; citronitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2-methyl-5-phenylpentan-1-ol; dodecanenitrile; 2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (R,E)-2-methyl-4-(2,2,3 -trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl (E)-but-2-enoate; allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinyl acetate; gamma terpinyl acetate; methyl dodecyl ether; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; cinnamyl isobutyrate; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gamma methyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl 2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal; Dimethoxycyclododecane; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; oxacyclohexadecan-2-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentalglisochromene; Ethylene brassylate; Methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidenelamino)benzoate; 4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedryl methyl ether; vetivert acetate; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; Benzophenone; Farnesol; trans,trans-farnesol; 3-(3-isopropylphenyl)butanal; 2,6,10-trimethylundec-9-enal; 3-(4-(tert-butyl)phenyl)propanal; 3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1); Citronellal (d); (E)-4,8-dimethyldeca-4,9-dienal; Pino Acetaldehyde; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral; Geranial; MethoxyMelonal; o-methoxycinnamaldehyde; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; Methyl Octyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral; Octanal; 2-Undecenal; 10-Undecenal; Trans -trans-2,6-Nonadienal; Trans-2, cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde; p-methyl-alpha-pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde; 3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methyl palmitate; Methyl iso eugenol; and mixtures thereof.

17. The composition according to claim 1, wherein said composition comprises from about 0.005% to about 10% of said malodor agent, wherein said malodor agent comprises from about 1 to about 30 malodor reduction materials having a Blocker Index of 3 to about 0.001, wherein at least a portion of said malodor reduction materials are encapsulated.

18. A process for treating a laundry article using the composition according to claim 1 comprising the steps of:
providing about 1 mg to about 100 g of said particles in a washing machine or laundry wash basin; and
washing said laundry article in a wash liquor in said washing machine or laundry wash basin into which said particles are dissolved.

19. A process for reducing malodor from a laundry article using the composition according to claim 1 comprising the steps of:
providing about 1 mg to about 100 g of said particles in a fluid pervious package; and placing said package proximal to said laundry article or contacting said laundry article with said fluid pervious package.