# Patent

## Title
Power and regasification system for LNG

## Abstract

The present invention provides a power and regasification system based on liquefied natural gas (LNG), comprising a vaporizer by which liquid motive fluid is vaporized, said liquid motive fluid being LNG or a motive fluid liquefied by means of LNG; a turbine for expanding the vaporized motive fluid and producing power; heat exchanger means to which expanded motive fluid vapor is supplied, said heat exchanger means also being supplied with LNG for receiving heat from said expanded fluid vapor, whereby the temperature of the LNG increases as it flows through the heat exchanger means; a conduit through which said motive fluid is supplied from at least the outlet of said heat exchanger to the inlet of said; and a line for transmitting regasified LNG.

## Background
FIELD
The present invention relates to the field of power generation. More particularly, the invention relates to a system which both utilizes liquefied natural gas for power generation and re-gasifies the liquefied natural gas.
BACKGROUND
In some regions of the world, the transportation of natural gas through pipelines is uneconomic. The natural gas is therefore cooled to a temperature below its boiling point, e.g. −160° C., until becoming liquid and the liquefied natural gas (LNG) is subsequently stored in tanks. Since the volume of natural gas is considerably less in liquid phase than in gaseous phase, the LNG can be conveniently and economically transported by ship to a destination port.
In the vicinity of the destination port, the LNG is transported to a regasification terminal, whereat it is reheated by heat exchange with sea water or with the exhaust gas of gas turbines and converted into gas. Each regasification terminal is usually connected with a distribution network of pipelines so that the regasified natural gas may be transmitted to an end user. While a regasification terminal is efficient in terms of the ability to vaporize the LNG so that it may be transmitted to end users, there is a need for an efficient method for harnessing the cold potential of the LNG as a cold sink for a condenser to generate power.
Use of Rankine cycles for power generation from evaporating LNG are considered in “Design of Rankine Cycles for power generation from evaporating LNG”, Maertens, J., International Journal of Refrigeration, 1986, Vol. 9, May. In addition, further power cycles using LNG/LPG (liquefied petroleum gas) are considered in U.S. Pat. No. 6,367,258. Another power cycle utilizing LNG is considered in U.S. Pat. No. 6,336,316. More power cycles using LNG are described in “Energy recovery on LNG import terminals ERoS RT project” by Snecma Moteurs, made available at the Gastech 2005, The 21st International Conference & Exhibition for the LNG, LPG and Natural Gas Industries, —14/17 Mar., 2005 Bilbao, Spain.
On the other hand, a power cycle including a combined cycle power plant and an organic Rankine cycle power plant using the condenser of the steam turbine as its heat source is disclosed in U.S. Pat. No. 5,687,570, the disclosure of which is hereby included by reference.
It is an object of the present invention to provide an LNG-based power and regasification system, which utilizes the low temperature of the LNG as a cold sink for the condenser of the power system in order to generate electricity or produce power for direct use.
Other objects and advantages of the invention will become apparent as the description proceeds.
SUMMARY
The present invention provides a power and regasification system based on liquefied natural gas (LNG), comprising a vaporizer by which liquid motive fluid is vaporized, said liquid motive fluid being LNG or a motive fluid liquefied by means of LNG; a turbine for expanding the vaporized motive fluid and producing power; heat exchanger means to which expanded motive fluid vapor is supplied, said heat exchanger means also being supplied with LNG for receiving heat from said expanded fluid vapor, whereby the temperature of the LNG increases as it flows through the heat exchanger means; a conduit through which said motive fluid is supplied from at least the outlet of said heat exchanger to the inlet of said vaporizer; and a line for transmitting regasified LNG.
Power is generated due to the large temperature differential between cold LNG, e.g. approximately −160° C., and the heat source of the vaporizer. The heat source of the vaporizer may be sea water at a temperature ranging between approximately 5° C. to 20° C. or heat such as an exhaust gas discharged from a gas turbine or low pressure steam exiting a condensing steam turbine.
The system further comprises a pump for delivering liquid motive fluid to the vaporizer.
The system may further comprise a compressor for compressing regasified LNG and transmitting said compressed regasified LNG along a pipeline to end users. The compressor may be coupled to the turbine. The regasified LNG may also be transmitted via the line to storage.
In one embodiment of the invention, the power system is a closed Rankine cycle power system such that the conduit further extends from the outlet of the heat exchanger means to the inlet of the vaporizer and the heat exchanger means is a condenser by which the LNG condenses the motive fluid exhausted from the turbine to a temperature ranging from approximately −90° C. to −120° C. The motive fluid is advantageously organic fluid such as ethane, ethene or methane or equivalents, or a mixture of propane and ethane or equivalents. The temperature of the LNG heated by the turbine exhaust is advantageously further increased by means of a heater. In an example of such an embodiment, the present invention provides a closed organic Rankine cycle power and regasification system for liquefied natural gas (LNG), comprising:

    
    
        a) a vaporizer in which liquid motive fluid is vaporized, said liquid motive fluid being a motive fluid liquefied by the LNG;
        b) a turbine for expanding the vaporized motive fluid;
        c) a condenser to which expanded motive fluid vapor is supplied, said condenser also being supplied with LNG for receiving heat from said expanded fluid vapor wherein said LNG condenses said expanded motive fluid exiting the turbine and whereby the temperature of the LNG increases as it flows through the condenser;
        d) a condenser/heater for condensing vapors extracted from an intermediate stage of said turbine and heating motive fluid condensate supplied to said condenser/heater from said condenser;
        e) a conduit through which said motive fluid is supplied from at from the outlet of the condenser to the inlet of the vaporizer; and
        f) a line for transmitting regasified LNG.
    
    


In another embodiment of the invention, the power system is an open cycle power system, the motive fluid is LNG, and the heat exchanger means is a heater for re-gasifying the LNG exhausted from the turbine.
The heat source of the heater may be sea water at a temperature ranging between approximately 5° C. to 20° C. or waste heat such as an exhaust gas discharged from a gas turbine.



BRIEF DESCRIPTION OF THE DRAWINGS
Embodiments of the present invention are described by way of example with reference to the accompanying drawings wherein:
FIG. 1 is a schematic arrangement of a closed cycle power system in accordance with one embodiment of the invention;
FIG. 2 is a temperature-entropy diagram of the closed cycle power system of FIG. 1;
FIG. 3 is a schematic arrangement of an open cycle power system in accordance with another embodiment of the invention;
FIG. 4 is a temperature-entropy diagram of the open cycle power system of FIG. 3.
FIG. 5 is a schematic arrangement of a closed cycle power system in accordance with a further embodiment of the invention;
FIG. 6 is a temperature-entropy diagram of the closed cycle power system of FIG. 5;
FIG. 7 is a schematic arrangement of a two pressure level closed cycle power system in accordance with a further embodiment of the invention;
FIG. 7A is a schematic arrangement of an alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B′ is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B′′ is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B′′′ is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B′′′′ is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7B′′′′′ is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7C is a schematic arrangement of further alternative versions of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7D is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7E is a schematic arrangement of a further alternative version of the two pressure level closed cycle power system in accordance with the embodiment of the invention shown in FIG. 7;
FIG. 7F is a schematic arrangement of a further embodiment of a two pressure level open cycle power system in accordance with the present invention;
FIG. 7G is a schematic arrangement of a further alternative version of the two pressure level open cycle power system in accordance with the embodiment of the invention shown in FIG. 7F;
FIG. 7H is a schematic arrangement of a further alternative version of the two pressure level open cycle power system in accordance with the embodiment of the invention shown in FIG. 7F;
FIG. 7I is a schematic arrangement of a further alternative version of the two pressure level open cycle power system in accordance with the embodiment of the invention shown in FIG. 7F;
FIG. 7J is a schematic arrangement of a further alternative version of the two pressure level open cycle power system in accordance with the embodiment of the invention shown in FIG. 7F;
FIG. 7K is a schematic arrangement of a further alternative version of the two pressure level open cycle power system in accordance with the embodiment of the invention shown in FIG. 7F;
FIG. 7L is a schematic arrangement of further embodiments of an open cycle power system in accordance with the present invention;
FIG. 7M is a schematic arrangement of a further embodiment of the present invention including an closed cycle power plant and an open cycle power plant;
FIG. 8 is a schematic arrangement of a closed cycle power system in accordance with a further embodiment of the invention; and
FIG. 9 is a schematic arrangement of a closed cycle power system in accordance with a still further embodiment of the invention.



Similar reference numerals and symbols refer to similar components.
DETAILED DESCRIPTION
The present invention is a power and regasification system based on liquid natural gas (LNG). While transported LNG, e.g. mostly methane, is vaporized in the prior art at a regasification terminal by being passed through a heat exchanger, wherein sea water or another heat source e.g. the exhaust of a gas turbine heats the LNG above its boiling point, an efficient method for utilizing the cold LNG to produce power is needed. By employing the power system of the present invention, the cold temperature potential of the LNG serves as a cold sink of a power cycle. Electricity or power is generated due to the large temperature differential between the cold LNG and the heat source, e.g. sea water.
FIGS. 1 and 2 illustrate one embodiment of the invention, wherein cold LNG serves as the cold sink medium in the condenser of a closed Rankine cycle power plant. FIG. 1 is a schematic arrangement of the power system and FIG. 2 is a temperature-entropy diagram of the closed cycle.
The power system of a closed Rankine cycle is generally designated as numeral 10. Organic fluid such as ethane, ethene or methane or an equivalent, is used advantageously as the motive fluid for power system 10 and circulates through conduits 8. Pump 15 delivers liquid organic fluid at state A, the temperature of which ranges from about −80° C. to −120° C., to vaporizer 20 at state B. Sea water in line 18 at an average temperature of approximately 5-20° C. introduced to vaporizer 20 serves to transfer heat to the motive fluid passing therethrough (i.e. from state B to state C). The temperature of the motive fluid consequently rises above its boiling point to a temperature of approximately −10 to 0° C., and the vaporized motive fluid produced is supplied to turbine 25. The sea water discharged from vaporizer 20 via line 19 is returned to the ocean. As the vaporized motive fluid is expanded in turbine 25 (i.e. from state C to state D), power or advantageously electricity is produced by generator 28 operated to turbine 25. Advantageously, turbine 25 rotates at about 1500 RPM or 1800 RPM. LNG in line 32 at an average temperature of approximately −160° C. introduced to condenser 30 (i.e. at state E) serves to condense the motive fluid exiting turbine 25 (i.e. from state D to state A) corresponding to a liquid phase, so that pump 15 delivers the liquid motive fluid to vaporizer 20. Since the LNG lowers the temperature of the motive fluid to a considerably low temperature of about −80° C. to −120° C., the recoverable energy available by expanding the vaporized motive fluid in turbine 25 is relatively high.
The temperature of LNG in line 32 (i.e. at state F) increases after heat is transferred thereto within condenser 30 by the expanded motive fluid exiting turbine 25, and is further increased by sea water, which is passed through heater 36 via line 37. Sea water discharged from heater 36 via line 38 is returned to the ocean. The temperature of the sea water introduced into heater 35 is usually sufficient to re-gasify the LNG, which may held in storage vessel 42 or, alternatively, be compressed and delivered by compressor 45 through line 43 to a pipeline for distribution of vaporized LNG to end users. Compressor 45 for re-gasifying the natural gas prior to transmission may be driven by the power generated by turbine 25 or, advantageously driven by electricity produced by electric generator 25.
When sea water is not available or not used or not suitable for use, heat such as that contained in the exhaust gas of a gas turbine may be used to transfer heat to the motive fluid in vaporizer 20 or to the natural gas directly or via a secondary heat transfer fluid (in heater 36).
FIGS. 3 and 4 illustrate another embodiment of the invention, wherein LNG is the motive fluid of an open cycle power plant. FIG. 3 is a schematic arrangement of the power system and FIG. 4 is a temperature-entropy diagram of the open cycle.
The power system of an open turbine-based cycle is generally designated as numeral 50. LNG 72, e.g. transported by ship to a selected destination, is the motive fluid for power system 50 and circulates through conduits 48. Pump 55 delivers cold LNG at state G, the temperature of which is approximately −160° C., to vaporizer 60 at state H. Sea water at an average temperature of approximately 5-20° C. introduced via line 18 to vaporizer 60 serves to transfer heat to the LNG passing therethrough from state H to state I. The temperature of the LNG consequently rises above its boiling point to a temperature of approximately −10 to 0° C., and the vaporized LNG produced is supplied to turbine 65. The sea water is discharged via line 19 from vaporizer 60 is returned to the ocean. As the vaporized LNG is expanded in turbine 65 from state I to state J, power or advantageously electricity is produced by generator 68 coupled to turbine 65. Advantageously, turbine 65 rotates at 1500 RPM or 1800 RPM. Since the LNG at state G has a considerably low temperature of −160° C. and is subsequently pressurized by pump 55 from state G to state H so that high pressure vapor is produced in vaporizer 60, the energy in the vaporized LNG is relatively high and is utilized via expansion in turbine 65.
The temperature of LNG vapor at state J, after expansion within turbine 65, is increased by transferring heat thereto from sea water, which is supplied to, via line 76, and passes through heater 75. The sea water discharged from heater 75 via line 77 and returned to the ocean. The temperature of sea water introduced to heater 75 is sufficient to heat the LNG vapor, which may held in storage 82 or, alternatively, be compressed and delivered by compressor 85 through line 83 to a pipeline for distribution of vaporized LNG to end users. Compressor 80 which compresses the natural gas prior to transmission may be driven by the power generated by turbine 65 or, advantageously, driven by electricity produced by electric generator 68. Alternatively, the pressure of the vaporized natural gas discharged from turbine 65 may be sufficiently high so that the natural gas which is heated in heater 75 can be transmitted through a pipeline without need of a compressor.
When sea water is not available or not used, heat such as heat contained in the exhaust gas of a gas turbine may be used to transfer heat to the natural gas in vaporizer 60 or in heater 75 or via a secondary heat transfer fluid.
Turning to FIG. 5, a further embodiment designated 10A of a closed cycle power system (similar to the embodiment described with reference to FIG. 1) is shown, wherein LNG pump 40A is used to pressurize the LNG prior to supplying it to condenser 30A to a pressure, e.g. about 80 bar, for producing a pressure for the re-gasified LNG suitable for supply via line 43A to a pipeline for distribution of vaporized LNG to end users. Pump 40A is used rather than compressor in the embodiment shown in FIG. 1. Basically, the operation of the present embodiment is similar to the operation of the embodiment of the present invention described with reference to FIGS. 1 and 2. Consequently, this embodiment is more efficient. Advantageously, turbine 25A included in this embodiment, advantageously rotates at 1500 RPM or 1800 RPM. Furthermore, a mixture of propane and ethane or equivalents is an advantageous motive fluid for closed organic Rankine power system in this embodiment. However, ethane, ethene or other suitable organic motive fluids can also be used in this embodiment. This is because the cooling curve of the propane/ethane mixture organic motive fluid in the condenser 30A is more suited to the heating curve of LNG at such high pressures enabling the LNG cooling source to be used more effectively (see FIG. 6). However, advantageously, a dual pressure organic Rankine cycle using a single organic motive fluid e.g. advantageously ethane, ethene or an equivalent, can be used here wherein two different expansion levels and also two condensers can be used (see e.g. FIG. 7). As can be seen, expanded organic vapors are extracted from turbine 25B in an intermediate stage via line 26B and supplied to condenser 31B wherein organic motive fluid condensate is produced. In addition, further expanded organic vapors exit turbine 25B via line 27B and are supplied to further condenser 30B wherein further organic motive fluid condensate is produced. Advantageously, turbine 25B rotates at 1500 RPM or 1800 RPM. Condensate produced in condensers 30B and 31B is supplied to vaporizer 20B using cycle pump II, 16B and cycle pump I, 15B, respectively where sea water (or other equivalent heating) is supplied thereto via line 18B for providing heat to the liquid motive fluid present in vaporizer 20B and producing vaporized motive fluid. Condensers 30B and 31B are also supplied with LNG using pump 40B so that the LNG is pressurized to a relatively high pressure e.g. about 80 bars. As can be seen from FIG. 7, the LNG is supplied first of all to condenser 30B for condensing the relatively low pressure organic motive fluid vapor exiting turbine 25B and thereafter, the heated LNG exiting condenser 30B is supplied to condenser 31B for condensing the relatively higher pressure organic motive fluid vapor extracted from turbine 25B. Thus, in accordance with this embodiment of the present invention, the supply rate or mass flow of the motive fluid in the bleed cycle, i.e. line 26B, condenser 31B and cycle pump I, 15B, can be increased so that additional power can be produced. Thereafter, the further heated LNG exiting condenser 31B is advantageously supplied to heater 36B for producing LNG vapor which may be held in storage 42B or, alternatively, be delivered by through line 43B to a pipeline for distribution of vaporized LNG to end users. While only one turbine is shown in FIG. 7, advantageously, two separate turbine modules, i.e. a high pressure turbine module and a low pressure turbine module, can be used.
In an alternative version (see FIG. 7A) of the last mentioned embodiment, direct-contact condenser/heater 32B′ can be used together with condensers 30B′ and 31B′. By using direct-contact condenser/heater 32B′, it is ensured that the motive fluid supplied to vaporizer 20B′ will not be cold and thus there will be little danger of freezing sea water or heating medium in the vaporizer. In addition, the mass flow of the motive fluid in the power cycle can be further increased thereby permitting an increase in the power produced. Furthermore, thereby, the dimensions of the turbine at e.g. its first stage can be improved, e.g. permit the use of blades having a larger size. Consequently, the turbine efficiency is increased. In this alternative version, production of the motive fluid, e.g. ethane, ethane-propane mixture, can be conveniently carried out by distilling the LNG into its various components or fractionates using e.g. distillation column 46B′. Ethane, comprising one such fractionate, produced in such a manner can be supplied to vaporizer 20B′ through line 47B′ to provide the motive fluid for operating the power cycle of organic turbine 25B′. Furthermore, the ethane produced can be used for make-up fluid for compensating for loss of motive fluid in the power system. Thus, an integrated motive fluid supply for the closed cycle organic Rankine cycle power plant is provided.
In a still further alternative version (see FIG. 7B) of the embodiment described with reference to FIG. 7, reheater 22B′′ is included and used in conjunction with direct-contact condenser/heater 32B′′ and condensers 30B′′ and 31B′′. By including the reheater the wetness of the vapors exiting high-pressure turbine module 24B′′ will be substantially reduced or eliminated thus ensuring that the vapors supplied to low-pressure turbine module 25B are substantially dry so that effective expansion and power production can be achieved. Advantageously, one heat source can be used for providing heat for the vaporizer while another heat source can be provided for supplying for the reheater.
In an alternative arrangement (see FIG. 7B′) of the embodiment described with reference to FIG. 7 which is similar to the version described with reference to FIG. 7B, rather than having both high-pressure turbine module 24B′′ and low-pressure turbine module 25B′′ connected to a electric generator to produce electric power, high-pressure turbine module 24B′′ is connected to an electric generator while low-pressure turbine module 25B′′ is connected to pump 40′B′′ for pumping LNG from its supply to low pressure condenser 30B′′, thereafter to intermediate pressure condenser 31B′′ and then to heater 36B′′ and line 43B′′. For start-up purposes a prime mover, e.g. a diesel engine or small gas turbine can be provided on e.g. the other side of the LNG pump 40′B′′. By using low-pressure turbine module 25B′′ to run LNG pump 40′B′′ directly, no external electrical power is required to operate the pump, providing a more efficient system. Moreover, advantageously, e.g. if varying LNG supply rates are needed, the low-pressure turbine module control can be used such that LNG pump 40′B′′ can be a variable speed pump. Furthermore, advantageously, electricity produced by generator 28′B′′ can be used to drive other auxiliaries so that together with the mechanical energy used to drive LNG pump 40′B′′ the regasification system 10′B′′ can be made substantially independent from external electricity supply.
In both alternatives described with reference to FIG. 7A or 7B, the position of direct contact condenser/heaters 32B′ and 32B′′ can be changed such that the inlet of direct contact condenser/heaters 32B′ can receive motive fluid condensate exiting intermediate pressure condenser 31B′ (see FIG. 7A) while direct contact condenser/heaters 32B′′ can receive pressurized motive fluid condensate exiting cycle pump 16B′′ (see FIG. 7B).
In further alternatives (see FIG. 7B′′ and FIG. 7B′′′) of the embodiment described with reference to FIG. 7 which are similar to the versions described with reference to FIG. 7B and FIG. 7B′ respectively, advantageously, the output of intermediate pressure condenser 31B′′ can be supplied to the inlet of pump 15B′′. Also here, advantageously, the output of condenser/heater 32B′′ can supplied to vaporizer 20B′′ without the use of pump 15B′′ so that, in such an option, only the output of intermediate pressure condenser 31B′′ is supplied to the inlet of pump 15B′′. If an indirect condenser/heater 32′′ is to be used to an advantage (see FIG. 7B′′′′) the motive fluid advantageously flows is as shown in FIG. 7B′′′′.
In a further embodiment described with reference to FIG. 7B′′′′′, direct-contact vapor-liquid heater 21B′′ is used to heat the motive fluid condensate with vapor from vaporizer 20B′′ prior to supplying the motive fluid condensate to the vaporizer. By using direct-contact vapor-liquid heater 21B′′, the liquid motive fluid condensate is heated before it is supplied to vaporizer 20B′′ and very reliable operation of the apparatus is achieved. This embodiment can be used in conjunction with any of the embodiments described herein. Note that with reference to the embodiment described with reference to FIG. 7B′′′′, when a direct-contact heater/condenser is used rather than indirect condenser/heater 32B′′, it is advantageous that motive fluid condensate is supplied to vaporizer 20B′′ or to the direct-contact vapor liquid heater only from intermediate pressure condenser 31B′′.
In an additional alternative version (see FIG. 7C) of the embodiment described with reference to FIG. 7, condensate produced in low pressure condenser 30B′′′ (or low pressure condenser 30B′′′′) can also be supplied to intermediate pressure condenser 31B′′′ (intermediate pressure condenser 31B′′′′) to produce condensate from intermediate pressure vapor extracted from an intermediate stage of the turbine by indirect or direct contact respectively.
FIG. 7D shows a still further alternative version of the embodiment described with reference to FIG. 7 wherein rather than using a direct contact condenser/heater, an indirect condenser/heater is used. In this alternative, only one cycle pump can be used wherein suitable valves can be used in the intermediate pressure condensate lines.
In an alternative shown in FIG. 7E, only one indirect condenser using LNG is used while a direct contact condenser/heater is also used.
In an additional embodiment of the present invention (see FIG. 7F), numeral 50A designates an open cycle power plant wherein portion of the LNG is drawn off the main line of the LNG and cycled through a turbine for producing power. In this embodiment, two direct contact condenser/heaters are used for condensing vapor extracted and exiting the turbine respectively using pressurized LNG pressurized by pump 55A prior to supply to the direct contact condenser/heaters.
In an alternative version, designated 50B in FIG. 7G, of the embodiment described with reference to FIG. 7F using an open cycle power plant, reheater 72B is included and used in conjunction with direct-contact condenser/heaters 31B and 33B. By including the reheater, the wetness of the vapors exiting high-pressure turbine module 64B will be substantially reduced or eliminated thus ensuring that the vapors supplied to low-pressure turbine module 65B are substantially dry so that effective expansion and power production can be achieved. Advantageously, one heat source can be used for providing heat for the vaporizer while another heat source can be provided for supplying for the reheater.
In a still further alternative option of the embodiment described with reference to FIG. 7F wherein an open cycle power plant is used, two indirect contact condensers can be used rather than the direct contact condensers used in the embodiment described with reference to FIG. 7F. Two different configurations for the two indirect contact condensers can be used (see FIGS. 7H and 7I).
In an additional alternative option of the embodiment described with reference to FIG. 7F wherein an open cycle power plant is used, an additional direct contact condenser/heater can be used in addition to the two indirect contact condensers (see FIG. 7J).
Furthermore, advantageously, in a further alternative option, see FIG. 7K, of the embodiment described with reference to FIG. 7F wherein an open cycle power plant is used, one direct contact condenser and one indirect contact condenser can be used.
Moreover, in a further embodiment, advantageously, in an open cycle power plant, one direct contact condenser or one indirect contact condenser can be used (see FIG. 7L).
In addition, in a further embodiment, advantageously, an open cycle power plant and closed cycle power plant can be combined (see FIG. 7M). In this embodiment, any of the described alternatives can be used as part of the open cycle power plant portion and/or closed cycle power plant portion.
Furthermore, it should be pointed out that, advantageously, the components of the various alternatives can be combined. Furthermore, also advantageously, certain components can be omitted from the alternatives. Additionally, an alternative used in a closed cycle power plant can be used in an open cycle power plant. E.g. the alternative described with reference to FIG. 7C (closed cycle power plant) can be used in an open cycle power plant (e.g. condensers 30B′′′ and 31B′′′ can be used in stead of condensers 33B′ and 34B′ shown in FIG. 7H, condensers 30B′′′′ and 31B′′′′′′ can be used in stead of condensers 33B′ and 34B′ shown in FIG. 7H).
In addition, while two pressure levels are described herein, advantageously, several or a number of pressure levels can be used and, advantageously, an equivalent number of condensers can be used to provide effective use of the pressurized LNG as a cold sink or source for the power cycles.
In FIG. 8, a further embodiment of the present invention is shown wherein a closed organic Rankine cycle power system is fused. Numeral 10C designates a power plant system including steam turbine system 100 as well closed is used as well as organic Rankine cycle power system 35C. Also here LNG pump 40C is advantageously used for pressurizing the LNG prior to supplying it to condenser 30C to a pressure, e.g. about 80 bar, for producing a pressure for the re-gasified LNG suitable for supply via line 43C to a pipeline for distribution of vaporized LNG to end users. In this embodiment, ethane or equivalent is advantageously used as the organic motive fluid. Advantageously in this embodiment, power plant system 10C includes, in addition, gas turbine unit 125 the exhaust gas of which provide the heat source for steam turbine system 100. In such a case, as can be seen from FIG. 8, the exhaust gas of gas turbine 124 is supplied to vaporizer 120 for producing steam from water contained therein. The steam produced is supplied to steam turbine 105 where it expands and produces power and advantageously drives electric generator 110 generating electricity. The expanded steam is supplied to steam condenser/vaporizer 120C where steam condensate is produced and cycle pump 115 supplies the steam condensate to vaporizer 120 thus completing the steam turbine cycle. Condenser/vaporizer 120C also acts as a vaporizer and vaporizes liquid organic motive fluid present therein. The organic motive fluid vapor produced is supplied to organic vapor turbine 25C and expands therein and produces power and advantageously drives electric generator 28C that generates electricity. Advantageously, turbine 25C rotates at 1500 RPM or 1800 RPM. Expanded organic motive fluid vapor exiting organic vapor turbine is supplied to condenser 30C where organic motive fluid condensate is produced by pressurized LNG supplied thereto by LNG pump 40C. Cycle pump 15C supplies the organic motive fluid condensate from condenser 30C to condenser/vaporizer 120C. Pressurized LNG is heated in condenser 30C and advantageously heater 36C further the pressurized LNG so that re-gasified LNG is produced for storage or supply via a pipeline for distribution of vaporized LNG to end users. Due to pressurizing of the LNG prior to supplied the LNG to the condenser, it can be advantageous to use a propane/ethane mixture as the organic motive fluid of the organic Rankine cycle power system rather than ethane mentioned above. On the other hand, advantageously, ethane, ethene or equivalent can be used as the motive fluid while two condensers or other configurations mentioned above can be used in the organic Rankine cycle power system.
Turning to FIG. 9, a further embodiment of the present invention is shown wherein a closed organic Rankine cycle power system is used. Numeral 10D designates a power plant system including intermediate power cycle system 100D as well as closed organic Rankine cycle power system 35D. Also here LNG pump 40D is advantageously used for pressurizing the LNG prior to supplying it to condenser 30D to a pressure, e.g. about 80 bar, for producing a pressure for the re-gasified LNG suitable for supply via line 43D to a pipeline for distribution of vaporized LNG to end users. In this embodiment, ethane, ethene or equivalent are advantageously used as the organic motive fluid. Advantageously, in this embodiment, power plant system 10D includes gas turbine unit 125D the exhaust gas of which provide the heat source for intermediate heat transfer cycle system 100D. In such a case, as can be seen from FIG. 9, the exhaust gas of gas turbine 124D is supplied to an intermediate cycle 100D for transferring heat from the exhaust gas to the vaporizer 120D for producing intermediate fluid vapor from intermediate fluid liquid contained therein. The vapor produced is supplied to intermediate vapor turbine 105D where it expands and produces power and advantageously drives electric generator 110D generating electricity. Advantageously, turbine 25D rotates at 1500 RPM or 1800 RPM. The expanded vapor is supplied to vapor condenser/vaporizer 120D where intermediate fluid condensate is produced and cycle pump 115D supplies the intermediate fluid condensate to vaporizer 120 thus completing the intermediate fluid turbine cycle. Several motive fluids are suitable for use in the intermediate cycle. An example of such a motive fluid is pentane, i.e. n-pentane or iso-pentane. Condenser/vaporizer 120D also acts as a vaporizer and vaporizes liquid organic motive fluid present therein. The organic motive fluid vapor produced is supplied to organic vapor turbine 25D and expands therein and produces power and advantageously drives electric generator 28D that generates electricity. Expanded organic motive fluid vapor exiting organic vapor turbine is supplied to condenser 30D where organic motive fluid condensate is produced by pressurized LNG supplied thereto by LNG pump 40D. Cycle pump 15D supplies the organic motive fluid condensate from condenser 30D to condenser/vaporizer 120D. Pressurized LNG is heated in condenser 30D and advantageously heater 36D further the pressurized LNG so that re-gasified LNG is produced for storage or supply via a pipeline for distribution of vaporized LNG to end users. Due to pressurizing of the LNG prior to supplied the LNG to the condenser, it can be advantageous to use a propane/ethane mixture as the organic motive fluid of the organic Rankine cycle power system rather than ethane mentioned above. On the other hand, advantageously ethane, ethene or equivalent can be used as the motive fluid while two condensers or other configurations mentioned above can be used in the organic Rankine cycle power system. Furthermore, a heat transfer fluid such as thermal oil or other suitable heat transfer fluid can be used for transferring heat from the hot gas to the intermediate fluid and, advantageously, a heat transfer fluid such as an organic, alkylated heat transfer fluid e.g. a synthetic alkylated aromatic heat transfer fluid. Examples can be an alkyl substituted aromatic fluid, Therminol LT, of the Solutia company having a center in Belgium or a mixture of isomers of an alkylated aromatic fluid, Dowtherm J, of the Dow Chemical Company. Also other fluids such as hydrocarbons having the formula CnH2n+2 wherein n is between 8 and 20 can also be used for this purpose. Thus, iso-dodecane or 2,2,4,6,6-pentamethylheptane, iso-eicosane or 2,2,4,4,6,6,8,10,10-nonamethylundecane, iso-hexadecane or 2,2,4,4,6,8,8-heptamethylnonane, iso-octane or 2,2,4 trimethylpentane, iso-nonane or 2,2,4,4 tetramethylpentane and a mixture of two or more of said compounds can be used for such a purpose, in accordance with U.S. patent application Ser. No. 11/067,710, the disclosure of which is hereby incorporated by reference. When an organic, alkylated heat transfer fluid or other hydrocarbon having the formula CnH2n+2 wherein n is between 8 and 20 is used as the heat transfer fluid, it can be used to also produce power or electricity by e.g. having vapors produced by heat in the hot gas expand in a turbine, with the expanded vapors exiting the turbine being condensed in a condenser which is cooled by intermediate fluid such that intermediate fluid vapor is produced which is supplied to the intermediate vapor turbine. In addition, advantageously, a suitable heat transfer fluid such as thermal oil or brine or other suitable heat transfer fluid can be used for transferring heat from the hot gas to the motive fluid, e.g. propane/ethane mixture, ethane, ethene or equivalent used in bottoming organic fluid cycle 35D.
Furthermore, any of the alternatives described herein can be used in the embodiments described with reference to FIG. 8 or FIG. 9.
While in the embodiments and alternatives described above it is stated that the rotational speed of the turbine is advantageously 1500 or 1800 RPM, advantageously, in accordance with the present invention, other speeds can also be used, e.g. 3000 or 3600 RPM.
It should be pointed out that while in several embodiments a condenser/heater is described and shown, e.g. those described with reference to FIGS. 7A (component 32B), 7B (component 32B′′), 7B′ (component 32B′′), 7D, 7E (component 32B′′′′′′), 7F (components 33A and 34A), 7G (components 33B and 34B), 7J, 7K (components 33B′′′′ and 34B′′′′), 7M, as a direct condenser/heater, an indirect condenser/heater can also be used in those embodiments.
In addition, advantageously, motive fluid supplied to the vaporizer in the various embodiments can additionally be heated by motive fluid vapor supplied from the vaporizer in order to pre-heat the motive fluid prior to entering the vaporizer.
Additionally, advantageously, reheater 22B′′ shown and described with reference to FIGS. 7B and 7B′′ and reheater 72 shown and described with reference to FIG. 7G need not be included.
Furthermore, while in the embodiment described with reference to FIG. 7A an integrated motive fluid supply is described, such an integrated motive fluid supply can be used in all embodiments in which a closed cycle organic Rankine cycle power plant is included. It such be pointed out that, advantageously, propane, being also a fractionate of LNG, can also be distilled out from the LNG in the integrated motive fluid supply so that it can be used together with ethane also so produced, advantageously, to prepare an ethane-propane mixture for use in the closed cycle organic Rankine cycle power plant as its motive fluid.
Moreover, advantageously, rather than using an electric generator in the various embodiments, the turbine or turbines can be used to run a compressor or pump of the LNG and/or natural gas.
Advantageously, the methods of the present invention can also be used to cool the inlet air of a gas turbine and/or to carry out intercooling in an intermediate stage or stages of the compressor of a gas turbine. Furthermore, advantageously, the methods of the present invention can be used such that LNG after cooling and condensing the motive fluid can be used to cool the inlet air of a gas turbine and/or used to carry out intercooling in an intermediate stage or stages of the compressor of a gas turbine.
It should be pointed out that, advantageously, steam turbine system 100, described with reference to Fig. can be a condensing steam turbine system.
Additionally, while it is mentioned above that the heat source for the vaporizer can sea water at a temperature ranging between approximately 5° C. to 20° C. or heat such as an exhaust gas discharged from a gas turbine or low pressure steam exiting a condensing steam turbine other heat sources may be used. Non limiting examples of such heat sources include hot gases from a process, ambient air, exhaust water from a combined cycle steam turbine, hot water from a water heater, etc.
While methane, ethane, ethene or equivalents are mentioned above as advantageous motive fluids for the organic Rankine cycle power plants they are to be taken as non-limiting examples of the advantageous motive fluids. Thus, other saturated or unsaturated aliphatic hydrocarbons e.g. propane, propene, etc. can also be used as the motive fluid for the organic Rankine cycle power plants. In addition, cyclopropane can also be used as the motive fluid for the organic Rankine cycle power plants. Furthermore, substituted saturated or unsaturated hydrocarbons can also be used as the motive fluids for the organic Rankine cycle power plants. Trifluromethane (CHF3), fluromethane (CH3F), tetrafluroethane (C2F4) and hexafluroethane (C2F6) are also worthwhile motive fluids for the organic Rankine cycle power plants described herein. Furthermore, such Chlorine (Cl) substituted saturated or unsaturated hydrocarbons can also be used as the motive fluids for the organic Rankine cycle power plants but would not be used due to their negative environmental impact.
Auxiliary equipment (e.g. values, controls, etc.) are not shown in the figures for sake of simplicity.
While some embodiments of the invention have been described by way of illustration, it will be apparent that the invention can be carried into practice with many modifications, variations and adaptations, and with the use of numerous equivalents or alternative solutions that are within the scope of persons skilled in the art, without departing from the spirit of the invention or exceeding the scope of the claims.

## Claims

1. A closed organic Rankine cycle power plant and re-gasification system for liquefied natural gas (LNG), comprising:
a vaporizer receiving a liquid organic fluid liquefied by the LNG, wherein the vaporizer is connected to a source of seawater as a heat source, for vaporizing the liquid organic fluid as a motive fluid of the closed Rankine cycle power plant;
a turbine of said closed Rankine cycle power plant;
a first flow path connecting the vaporizer to the turbine, whereby the vaporized organic motive fluid from said vaporizer is supplied to the turbine through said first flow path and expanded in the turbine;
a condenser of said closed Rankine cycle power plant to which the expanded organic motive fluid vapor is supplied, said condenser also being supplied with LNG for receiving heat from said expanded organic motive fluid vapor, wherein said LNG condenses said expanded organic motive fluid and whereby a temperature of the LNG increases as it flows through the condenser;
a second flow path through which said organic motive fluid condensate is supplied from an outlet of the condenser to an inlet of the vaporizer;
a direct-contact heat exchanger in said second flow path for heating the organic motive fluid condensate supplied from the outlet of the condenser cooled by LNG, wherein the direct-contact heat exchanger is not in the first flow path connecting the vaporizer to the turbine;
a third flow path connected between a vapor section of said vaporizer and said direct-contact heat exchanger for supplying vaporized organic motive fluid from the vapor section of said vaporizer to said direct-contact heat exchanger, so that said vaporized organic motive fluid heats said organic motive fluid condensate supplied from the outlet of said condenser, and wherein a vapor exit of the vaporizer is present at said vapor section, and wherein said turbine is not in said third flow path; and
a line for transmitting re-gasified LNG.

2. The system according to claim 1, wherein the organic motive fluid comprises a motive fluid selected from the group consisting of propane, ethane and methane.

3. The system according to claim 1, wherein the organic motive fluid comprises a mixture of propane and ethane.

4. The system according to claim 1, further comprising a pump for pressurizing and delivering liquid organic motive fluid from the condenser to the vaporizer.

5. The system according to claim 1 further comprising a pump for increasing a pressure of said LNG supplied to said condenser prior to supplying it to the condenser at a pressure that is suitable for supplying the re-gasified LNG along a pipeline to end users.

6. The system according to claim 1 further comprising a further condenser for condensing expanded vapor extracted from said turbine, wherein said further condenser is cooled by heated LNG exiting said condenser.

7. The system according to claim 6, further comprising a condenser/heater for condensing vapors extracted from an intermediate stage of said turbine and heating motive fluid condensate supplied to said condenser/heater from said condenser.

8. The system according to claim 7 wherein said condenser/heater for condensing vapors extracted from an intermediate stage of said turbine and heating organic motive fluid condensate supplied to said condenser/heater comprises an indirect contact condenser/heater.

9. The system according to claim 7 wherein said condenser/heater for condensing vapors extracted from an intermediate stage of said turbine and heating organic motive fluid condensate supplied to said condenser/heater comprises a direct contact condenser/heater.

10. A closed organic Rankine cycle power plant and re-gasification system for liquefied natural gas (LNG), comprising:
a vaporizer receiving a liquid organic fluid liquefied by the LNG, wherein the vaporizer is connected to a source of seawater as a heat source for vaporizing the liquid organic fluid as a motive fluid of the closed Rankine cycle power plant;
a vapor turbine of said closed Rankine cycle power plant operated at high pressure;
a first flow path connecting the vaporizer to the vapor turbine, whereby the vaporized organic motive fluid from said vaporizer is supplied to the vapor turbine through said first flow path and expanded in the vapor turbine;
an electric generator for producing electric power operated by said vapor turbine operated at high pressure;
an intermediate pressure condenser of said closed Rankine cycle power plant to which the expanded organic motive fluid vapor is supplied from said vapor turbine operated at high pressure, said condenser also being supplied with LNG for receiving heat from said expanded organic motive fluid vapor, wherein said LNG condenses said expanded organic motive fluid exiting the vapor turbine operated at high pressure and whereby a temperature of the LNG increases as it flows through the condenser;
a further vapor turbine of said closed Rankine cycle power plant operated at low pressure for further expanding the expanded vapors exiting said vapor turbine operated at high pressure;
a low pressure condenser of said closed Rankine cycle power plant for condensing the expanded motive fluid vapor exiting said further vapor turbine operated at low pressure, said low pressure condenser also being supplied with LNG for receiving heat from said expanded motive fluid vapor exiting said further vapor turbine operated at low pressure and condensing said expanded motive fluid vapor exiting said further vapor turbine, whereby the temperature of the LNG increases as it flows through the low pressure condenser;
a LNG pump operated for increasing the pressure of said. LNG supplied to said low pressure condenser prior to supplying it to said low pressure condenser and thereafter to said intermediate pressure condenser at a pressure that is suitable for supplying a re-gasified LNG along a pipeline to end users;
a second flow path for supplying condensate exiting said intermediate pressure condenser to said vaporizer;
a direct-contact heat exchanger in said second flow path for heating the organic motive fluid condensate exiting said intermediate pressure condenser cooled by LNG, wherein the direct-contact heat exchanger is not in the first flow path connecting the vaporizer to the vapor turbine;
a third flow path connected between a vapor section of said vaporizer and said direct-contact heat exchanger for supplying vaporized organic motive fluid from the vapor section of said vaporizer to said direct-contact heat exchanger, so that said vaporized organic motive fluid heats said organic motive fluid condensate supplied from an outlet of said intermediate pressure condenser,
and wherein a vapor exit of the vaporizer is present at said vapor section, and wherein said vapor turbines are not in said third flow path; and
a line for transmitting re-gasified LNG.

11. The system according to claim 10, further comprising a condenser/heater for condensing vapors exiting said vapor turbine and heating motive fluid condensate supplied to said condenser/heater from said low pressure condenser.