# Patent

## Title
Absorbent article with blood slipping agent

## Abstract

The present invention addresses the problem of providing an absorbent article that is provided with a liquid-permeable layer, said liquid-permeable layer having convex portions that are hollow inside, has an improved ability to transfer menstrual blood from the liquid-permeable layer to an absorbent body and can reduce the amount of the menstrual blood remaining in the liquid-permeable layer (in particular, the internal cavities in the convex portions). To solve this problem, provided is a sanitary napkin provided with a liquid-permeable top sheet, a liquid-impermeable back sheet and an absorbent body that is interposed between the top sheet and the back sheet, wherein convex portions, said convex portions being hollow inside and formed in an excretion orifice contact region of the top sheet, are coated with a blood lubricity-imparting agent that has a kinetic viscosity of 0.01-80 mm2/s at 40° C., a water retention rate of 0.01-4.0 mass % and a weight-average molecular weight of less than 1,000.

## Background
RELATED APPLICATIONS
The present application is a National Phase of International Application Number PCT/JP2013/073024 filed Aug. 28, 2013 and claims priority to Japanese Application Number 2012-218895 filed Sep. 28, 2012.
TECHNICAL FIELD
The present invention relates to an absorbent article.
BACKGROUND ART
As top sheets for absorbent articles there are known top sheets having concavoconvexities formed therein by gear stretching (PTLs 1 and 2).
The top sheets described in PTLs 1 and 2 each have a first layer provided on the skin contact side and a second layer provided on the non-skin contact side, the first layer having internally hollow projections bulging out on the skin contact side, and being partially bonded with the second layer at the sections other than the projections.
CITATION LIST
Patent Literature
PTL 1 Japanese Unexamined Patent Publication No. 2004-174234
PTL 2 Japanese Unexamined Patent Publication No. 2009-160035
SUMMARY OF INVENTION
Technical Problem
However, since the top sheets described in PTLs 1 and 2 have hollow interiors for the projections, the liquid permeability can be potentially reduced. In particular, highly viscous menstrual blood tends to reside in the interior spaces of the projections.
It is therefore an object of the invention to provide an absorbent article comprising a liquid-permeable layer having projections with hollow interiors, the absorbent article having improved migration of menstrual blood from the liquid-permeable layer to the absorbent body, and allowing reduced residue of menstrual blood in the liquid-permeable layer (especially in the interior spaces of the projections).
Solution to Problem
In order to solve the problems described above, the invention provides an absorbent article comprising a liquid-permeable layer with a skin contact surface, a liquid-impermeable layer with a non-skin-contacting surface, and an absorbent body situated between the liquid-permeable layer and the liquid-impermeable layer, the liquid-permeable layer having a first layer formed on the skin contact surface side and a second layer formed on the non-skin contact surface side, wherein the first layer has a projection with a hollow interior bulging out on the skin contact surface side, which are formed at least in the excretory opening contact region on the skin contact surface side and is partially bonded with the second layer at the sections other than the projection, and at least the projection of the excretory opening contact region is coated with a blood slipping agent having a 40° C. kinematic viscosity of 0.01 to 80 mm2/s, a water holding percentage of 0.01 to 4.0 mass % and a weight-average molecular weight of less than 1,000.
Advantageous Effects of Invention
According to the invention there is provided an absorbent article comprising a liquid-permeable layer having a projection with a hollow interior, the absorbent article having improved migration of menstrual blood from the liquid-permeable layer to the absorbent body, and allowing the residue of menstrual blood in the liquid-permeable layer (especially in the interior space of the projection) to be reduced.



BRIEF DESCRIPTION OF DRAWING
FIG. 1 is a partial cutaway plan view of a sanitary napkin according to one embodiment of the absorbent article of the invention.
FIG. 2 is a cross-sectional view of FIG. 1 along line A-A.
FIG. 3 is a partial perspective view of the top sheet of the sanitary napkin shown in FIG. 1.
FIG. 4 is a diagram illustrating the production steps for the top sheet shown in FIG. 3.
FIG. 5 is a pair of partial expanded views of the outer peripheral surface of a gear stretching roll (tooth/groove arrangement pattern) used for production of the top sheet shown in FIG. 3.
FIG. 6 is a partial magnified cross-sectional view of the meshed state of tooths/grooves of a gear stretching roll used for production of a top sheet.
FIG. 7 is a diagram illustrating the production steps for the sanitary napkin shown in FIG. 1.
FIG. 8 is an electron micrograph of the skin contact surface of a top sheet in a sanitary napkin wherein the top sheet comprises tri-C2L oil fatty acid glycerides.
FIG. 9 is a pair of photomicrographs of menstrual blood containing and not containing a blood slipping agent.
FIG. 10 is a diagram illustrating a method of measuring surface tension.



DESCRIPTION OF EMBODIMENTS
The absorbent article of the invention will now be described.
The absorbent article according to aspect 1 is an absorbent article comprising a liquid-permeable layer with a skin contact surface, a liquid-impermeable layer with a non-skin-contacting surface, and an absorbent body situated between the liquid-permeable layer and the liquid-impermeable layer, the liquid-permeable layer having a first layer formed on the skin contact surface and a second layer formed on the non-skin contact surface side, wherein the first layer has a projection with a hollow interior bulging out on the skin contact surface side, which are formed at least in the excretory opening contact region on the skin contact surface side, and is partially bonded with the second layer at the sections other than the projection, and at least the projection of the excretory opening contact region is coated with a blood slipping agent having a 40° C. kinematic viscosity of 0.01 to 80 mm2/s, a water holding percentage of 0.01 to 4.0 mass % and a weight-average molecular weight of less than 1,000.
In the absorbent article of aspect 1, menstrual blood excreted by the wearer and reaching the excretory opening contact region slips down together with the blood slipping agent present in the projection, and migrates through the liquid-permeable layer into the absorbent body. The absorbent article of aspect 1 therefore has improved migration of menstrual blood from the liquid-permeable layer to the absorbent body, and reduced residue of menstrual blood in the liquid-permeable layer (especially the interior spaces of the projections). This prevents the skin contact surface of the liquid-permeable layer from having a sticky feel, and maintains a smooth feel. This function and effect of the blood slipping agent is exhibited regardless of changes in menstrual blood discharge during menstruation (that is, whether the amount of discharged menstrual blood is large or small).
In a preferred aspect (aspect 2) of the absorbent article according to aspect 1, the fiber density is essentially the same in the top section and side section of the projection. When the projections are to be formed by ordinary gear stretching, the gear-stretched sections become the side sections of the projections, and therefore the fiber density tends to be lower at the side sections of the projections than at the top sections of the projections. Since liquid readily migrates from sections of low fiber density to sections of high fiber density, a lower fiber density at the side sections of the projections than at the top sections of the projections inhibits migration of liquid. In contrast, an absorbent article according to aspect 2 has essentially the same fiber density at the top sections and the side sections of the projections, and therefore migration of liquid is not inhibited.
In a preferred aspect (aspect 3) of the absorbent article according to aspect 1 or 2, the basis weight is essentially the same in the top section and side section of the projection. When the projections are to be formed by ordinary gear stretching, the gear-stretched sections become the side sections of the projections, and therefore the basis weight tends to be lower at the side sections of the projections than at the top sections of the projections. If the basis weight is lower at the side sections of the projections than at the top sections of the projections, the projections will have high collapsability. In contrast, an absorbent article according to aspect 3 has essentially the same basis weight at the top sections and the side sections of the projections, and therefore the projections are resistant to collapse.
In a preferred aspect (aspect 4) of the absorbent article according to any of aspects 1 to 3, the IOB of the blood slipping agent is 0.00 to 0.60.
In a preferred aspect (aspect 5) of the absorbent article according to any one of aspects 1 to 4, the blood slipping agent is selected from the group consisting of the following items (i)-(iii), and any combination thereof:
(i) a hydrocarbon;
(ii) a compound having (ii-1) a hydrocarbon moiety, and (ii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii) a compound having (iii-1) a hydrocarbon moiety, (iii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen of the hydrocarbon moiety;
with the proviso that when 2 or more oxy groups are inserted in the compound of (ii) or (iii), the oxy groups are not adjacent.
In a preferred aspect (aspect 6) of the absorbent article of any of aspects 1 to 5, the blood slipping agent is selected from the group consisting of the following items (i′)-(iii′), and any combination thereof:
(i′) a hydrocarbon;
(ii′) a compound having (ii′-1) a hydrocarbon moiety, and (ii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—) ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii′) a compound having (iii′-1) a hydrocarbon moiety, (iii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii′-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen on the hydrocarbon moiety;
with the proviso that when 2 or more same or different bonds are inserted in the compound of (ii′) or (iii′), the bonds are not adjacent.
In a preferred aspect (aspect 7) of the absorbent article according to any of aspects 1 to 6, the blood slipping agent is selected from the group consisting of the following items (A)-(F), and any combination thereof:
(A) an ester of (A1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety, and (A2) a compound having a chain hydrocarbon moiety and 1 carboxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(B) an ether of (B1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety and (B2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(C) an ester of (C1) a carboxylic acid, hydroxy acid, alkoxy acid or oxoacid comprising a chain hydrocarbon moiety and 2-4 carboxyl groups substituting hydrogens on the chain hydrocarbon moiety and (C2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(D) a compound having a chain hydrocarbon moiety and one bond selected from the group consisting of an ether bond (—O—), carbonyl bond (—CO—), ester bond (—COO—) and carbonate bond (—OCOO—) inserted between a C—C single bond of the chain hydrocarbon moiety;
(E) a polyoxy C3-C6 alkylene glycol, or alkyl ester or alkyl ether thereof; and
(F) a chain hydrocarbon.
In a preferred aspect (aspect 8) of the absorbent article according to any of aspects 1 to 7, the blood slipping agent is selected from the group consisting of (a1) an ester of a chain hydrocarbon tetraol and at least one fatty acid, (a2) an ester of a chain hydrocarbon triol and at least one fatty acid, (a3) an ester of a chain hydrocarbon diol and at least one fatty acid, (b1) an ether of a chain hydrocarbon tetraol and at least one aliphatic monohydric alcohol, (b2) an ether of a chain hydrocarbon triol and at least one aliphatic monohydric alcohol, (b3) an ether of a chain hydrocarbon diol and at least one aliphatic monohydric alcohol, (c1) an ester of a chain hydrocarbon tetracarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 4 carboxyl groups, and at least one aliphatic monohydric alcohol, (c2) an ester of a chain hydrocarbon tricarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 3 carboxyl groups, and at least one aliphatic monohydric alcohol, (c3) an ester of a chain hydrocarbon dicarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 2 carboxyl groups, and at least one aliphatic monohydric alcohol, (d1) an ether of an aliphatic monohydric alcohol and an aliphatic monohydric alcohol, (d2) a dialkyl ketone, (d3) an ester of a fatty acid and an aliphatic monohydric alcohol, (d4) a dialkyl carbonate, (e1) a polyoxy C3-C6 alkylene glycol, (e2) an ester of a polyoxy C3-C6 alkylene glycol and at least one fatty acid, (e3) an ether of a polyoxy C3-C6 alkylene glycol and at least one aliphatic monohydric alcohol, and (f1) a chain alkane, and any combination thereof.
In a preferred aspect (aspect 9) of the absorbent article of any of aspects 1 to 8, the blood slipping agent has a vapor pressure of 0.00 to 0.01 Pa at 1 atmosphere, 40° C.
There are no particular restrictions on the type and usage of the absorbent article of the invention. For example, absorbent articles include sanitary products and sanitary articles, such as sanitary napkins and panty liners, which may be for humans or animals other than humans, such as pets. The liquid to be absorbed by the absorbent article is not particularly restricted, but will mainly be liquid excreta, such as menstrual blood.
Embodiments of the absorbent article of the invention will now be described, using a sanitary napkin as an example, with reference to the accompanying drawings.
As shown in FIG. 1 and FIG. 2, the sanitary napkin 1 according to one embodiment of the absorbent article of the invention comprises a liquid-permeable top sheet 2, a liquid-impermeable back sheet 3, and an absorbent body 4 formed between the top sheet 2 and the back sheet 3.
In FIG. 1, the X-axial direction is the widthwise direction of the sanitary napkin 1, the Y-axial direction is the lengthwise direction of the sanitary napkin 1, and the direction of the plane extending in the X-axial and Y-axial directions corresponds to the planar direction of the sanitary napkin 1. The same applies to the other drawings as well.
The sanitary napkin 1 is worn to absorb liquid excreta, such as menstrual blood. It is worn in such a manner that the top sheet 2 is on the skin side of the wearer, and the back sheet 3 is located on the side of the clothing (underwear) of the wearer. Liquid excreta, such as menstrual blood permeates the top sheet 2 and reaches the absorbent body 4, and is absorbed and retained in the absorbent body 4. Leakage of liquid excreta that has been absorbed and retained in the absorbent body 4 is prevented by the back sheet 3.
As shown in FIG. 1, the top sheet 2 and back sheet 3 have their edges bonded together in the lengthwise direction by seal sections 11a, 11b, forming the body section 6, while having their edges bonded together in the widthwise direction by seal sections 12a, 12b, forming essentially rectangular wing sections 7a, 7b that extend out in the widthwise direction from the body section 6.
The shape of the body section 6 can be appropriately adjusted in a range suited to the body of the wearer and to underwear, examples of shapes for the body section 6 including essentially rectangular, essentially elliptical and essentially gourd-like shapes. The dimensions in the lengthwise direction of the body section 6 will usually be 100 to 500 mm and preferably 150 to 350 mm, while the dimensions in the widthwise direction of the body section 6 will usually be 30 to 200 mm and preferably 40 to 180 mm.
The bonding method for the seal sections 11a, 11b, 12a, 12b may be embossing, ultrasonic waves or a hot-melt adhesive. In order to increase the bonding strength, two or more different bonding methods may be combined (for example, bonding with a hot-melt adhesive followed by embossing).
As an example of embossing, the top sheet 2 and back sheet 3 may be passed together between a patterned embossing roll, with patterned projections, and a flat roll, for embossing (a method known as round sealing). By heating the embossing roll and/or flat roll by this method, each sheet is softened so that the seal sections become more distinct. Examples of emboss patterns include lattice-like patterns, zigzag patterns and wavy patterns.
Examples of hot-melt adhesives include pressure-sensitive adhesives and heat-sensitive adhesives composed mainly of rubber-based compounds, such as styrene-ethylene-butadiene-styrene (SEES), styrene-butadiene-styrene (SBS) or styrene-isoprene-styrene (SIS), or composed mainly of olefin-based compounds, such as linear low-density polyethylene; and water-sensitive adhesives comprising water-soluble polymers (such as polyvinyl alcohol, carboxylmethyl cellulose and gelatin) or water-swelling polymers (such as polyvinyl acetate and sodium polyacrylate). Examples of adhesive coating methods include spiral coating application, coater application, curtain coater application and summit-gun coating.
As shown in FIG. 2, pressure-sensitive adhesive sections 13a, 13b are provided on the clothing side of the back sheet 3 forming the wing sections 7a, 7b, and a pressure-sensitive adhesive section 13c is provided on the clothing side of the back sheet 3 forming the body section 6. The pressure-sensitive adhesive section 13c is attached to the crotch section of underwear, while the wing sections 7a, 7b are folded toward the outer wall of the underwear and the pressure-sensitive adhesive sections 13a, 13b are attached to the crotch section of the underwear, thereby stably anchoring the sanitary napkin 1 to the underwear.
Examples of pressure-sensitive adhesives to be used in the pressure-sensitive adhesive sections 13a, 13b, 13c include styrene-based polymers, such as styrene-ethylene-butylene-styrene block copolymer, styrene-butylene polymer, styrene-butylene-styrene block copolymer and styrene-isobutylene-styrene copolymer; tackifiers, such as C5 petroleum resins, C9 petroleum resins, dicyclopentadiene-based petroleum resins, rosin-based petroleum resins, polyterpene resins and terpenephenol resins; monomer plasticizers, such as tricresyl phosphate, dibutyl phthalate and dioctyl phthalate; and polymer plasticizers, such as vinyl polymer and polyester.
The top sheet 2 is a sheet that allows permeation of liquid excreta, such as menstrual blood, an example thereof being a liquid-permeable layer. As shown in FIG. 2 and FIG. 3, a plurality of projections 8 and recesses 9 are formed on the skin contact surface of the top sheet 2 (the top side in FIG. 2). In FIG. 2, the interior spaces of the projections 8 are omitted, but in actuality the interiors of the projections 8 are hollow, as shown in FIG. 3.
For this embodiment, projections 8 are formed over essentially the entire absorbent body placement region that includes the excretory opening contact region 20 on the skin contact surface of the top sheet 2, it being sufficient for the projections 8 to be formed in at least the excretory opening contact region 20 on the skin contact surface of the top sheet 2. The absorbent body placement region is the region in which the absorbent body 4 overlaps the top sheet 2 when the absorbent body 4 has been projected onto the top sheet 2.
The excretory opening contact region 20 is the region in which the excretory opening of the wearer (for example, the labia minora, labia majora, etc.) contact when the sanitary napkin 1 is worn. The excretory opening contact region 20 is the region delineated by the dotted line in FIG. 1, and it is set at essentially the center of the absorbent body placement region. The location and area of the excretory opening contact region 20 may be adjusted as appropriate. The excretory opening contact region 20 may be set to be essentially the same region as the region that actually contacts with the excretory opening, or it may be set as a larger region, but from the viewpoint of preventing leakage of liquid excreta, such as menstrual blood to the exterior, it is preferably set as a region larger than the region that actually contacts with the excretory opening. The length of the excretory opening contact region 20 will usually be 50 to 200 mm and is preferably 70 to 150 mm, and the width will usually be 10 to 80 mm and is preferably 20 to 50 mm.
For this embodiment, the excretory opening contact region 20 is set as a virtual region, but it may instead be set as a visually recognizable region. Visual recognition may be produced, for example, by coloration of the excretory opening contact region 20, or by formation of recesses in a continuous or intermittent fashion along the periphery of the excretory opening contact region 20 (for example, recesses formed by heat embossing treatment).
While not shown here, essentially the entire excretory opening contact region 20 is coated with a blood slipping agent having a 40° C. kinematic viscosity of 0.01 to 80 mm2/s, a water holding percentage of 0.01 to 4.0 mass % and a weight-average molecular weight of less than 1,000. The details regarding the blood slipping agent will be described in a different section.
For this embodiment, essentially the entire excretory opening contact region 20 is coated with the blood slipping agent, but it is sufficient to coat the blood slipping agent on at least the projections 8 of the excretory opening contact region 20. So long as the blood slipping agent is coated on at least the projections 8 of the excretory opening contact region 20, it may also be coated on sections other than the projections 8 of the excretory opening contact region 20 (for example, the recesses 9), or it may be coated in regions other than the excretory opening contact region 20 on the skin contact surface (for example, the regions surrounding the excretory opening contact region 20). For example, the blood slipping agent may be coated essentially over the entire skin contact surface or essentially over the entire absorbent body placement region.
If the blood slipping agent is coated on at least the projections 8 of the excretory opening contact region 20, the following function and effect will be exhibited. When menstrual blood excreted by the wearer reaches the excretory opening contact region 20, it slips together with the blood slipping agent present in the projections 8 down into the recesses 9, and migrates through the top sheet 2 into the absorbent body 4. Therefore, the sanitary napkin 1 has improved migration of menstrual blood from the top sheet 2 to the absorbent body 4, and can reduce residue of menstrual blood in the top sheet 2 (especially in the interior spaces of the projections 8). This prevents the skin contact surface of the top sheet 2 from having a sticky feel, and maintains a smooth feel. This function and effect of the blood slipping agent is exhibited regardless of changes in menstrual blood discharge during menstruation (that is, whether the amount of discharged menstrual blood is large or small).
Since this embodiment has projections 8 and recesses 9 in the excretory opening contact region 20 such that the excretory opening contact region 20 has an irregular structure, the function and effect of the blood slipping agent is effectively exhibited. The function and effect of the blood slipping agent can be reinforced by coating the blood slipping agent on the recesses 9 in addition to the projections 8.
Incidentally, since the blood slipping agent functions as a lubricating agent to reduce friction between fibers, it can improve the flexibility of the top sheet 2 as a whole.
The sanitary napkin 1 does not require components, such as emollients and immobilizing agents, unlike in known absorbent articles containing skin care compositions, lotion compositions and the like, and the blood slipping agent alone may be applied to the top sheet 2.
The basis weight of the blood slipping agent may usually be about 1 to 30 g/m2, preferably about 2 to 20 g/m2 and even more preferably about 3 to 10 g/m2. If the basis weight of the blood slipping agent is lower than about 1 g/m2, menstrual blood will tend to remain in the top sheet 2, while if the basis weight of the blood slipping agent is greater than about 30 g/m2, there will tend to be an increase in the sticky feel during wear.
The basis weight of the blood slipping agent can be measured in the following manner, for example.
(1) The region of the top sheet that is to be measured is cut out using a sharp blade, such as a cutter replacement blade, while minimizing any alteration in thickness, to obtain a sample.
(2) The area of the sample: SA (m2) and the mass: SM0 (g) are measured.
(3) The sample is stirred for at least 3 minutes in a solvent that can dissolve the blood slipping agent, such as ethanol or acetone, to dissolve the blood slipping agent in the solvent.
(4) The sample is filtered on mass-measured filter paper, and the sample is thoroughly rinsed with the solvent on the filter paper. The sample on the filter paper is dried in an oven at 60° C.
(5) The masses of the filter paper and sample are measured, and the mass of the filter paper is subtracted to calculate the dry sample mass: SM1 (g).
(6) The basis weight BBS (g/m2) of the blood slipping agent is calculated by the following formula.

BBS (g/m2)=[SM0 (g)−SM1 (g)]/SA (m2)

In order to minimize error, multiple samples are taken from multiple absorbent articles, without the total area of the sample exceeding 100 cm2, conducting several repeated measurements and taking the average value.
The blood slipping agent is preferably coated without obstructing the voids between the fibers of the top sheet 2. For example, the blood slipping agent may be adhering as droplets or particulates on the surfaces of the fibers of the top sheet 2, or covering the surfaces of the fibers.
The blood slipping agent is preferably coated so that the surface area is increased. This will increase the contact area between the blood slipping agent and the menstrual blood and facilitate slipping of the blood slipping agent together with the menstrual blood. When the blood slipping agent is present as droplets or particulates, the particle diameters can be reduced to increase the surface area.
Examples of methods for coating the blood slipping agent include methods that employ coating applicators (for example, non-contact coaters, such as spiral coaters, curtain coaters, spray coaters and dip coaters, and contact coaters). Non-contact coaters are preferred coating applicators. This will allow the droplet or particulate blood slipping agent to evenly disperse over the entirety, while reducing damage to the top sheet 2.
The blood slipping agent may, if desired, be applied as a coating solution containing a volatile solvent, such as an alcohol-based solvent, ester-based solvent or aromatic solvent. If the coating solution includes a volatile solvent, the viscosity of the coating solution containing the blood slipping agent will be lowered, thereby allowing the application steps to be simplified, facilitating application and making heating during application unnecessary.
The blood slipping agent may be coated directly, if it is a liquid at room temperature, or it may be heated to lower the viscosity, and when it is a solid at room temperature, it may be heated to liquefaction and coated with a control seam HMA (Hot Melt Adhesive) gun. By increasing the air pressure of the control seam HMA gun, it is possible to coat the blood slipping agent as fine particulates. The coating amount of the blood slipping agent can be adjusted, for example, by adjusting the discharged amount from a control seam HMA gun.
The blood slipping agent may be coated during production of the top sheet 2, or it may be coated in the manufacturing line for the sanitary napkin 1. From the viewpoint of minimizing equipment investment, the blood slipping agent is preferably coated in the manufacturing line for the sanitary napkin 1, and in order to prevent shedding of the blood slipping agent which may contaminate the line, the blood slipping agent or its composition is preferably coated during a step downstream from the manufacturing line, and specifically, immediately before encapsulation of the product in an individual package.
As shown in FIG. 3, the top sheet 2 has a first layer 21 provided on the skin contact surface side, and a second layer 22 provided on the non-skin contact surface side.
One side of the first layer 21 (the top side in FIG. 3) is the skin contact surface of the sanitary napkin 1. As shown in FIG. 3, a second layer 22 is layered on the non-skin contact surface side of the first layer 21, so that the top sheet 2 has a two-layer structure. The top sheet 2 may also have one or more third layers in addition to the first layer 21 and the second layer 22. So long as the second layer 22 is provided on the non-skin contact surface side of the first layer 21, there are no particular restrictions on the location where the third layer is provided. For example, one or more third layers may be provided between the first layer 21 and the second layer 22. Alternatively, one or more third layers may be provided on the side of the second layer 22 opposite the first layer 21 side.
The first layer 21 has concavoconvexities formed by gear stretching as described below, and as shown in FIG. 3, it has a plurality of projections 8 and recesses 9. As shown in FIG. 3, the projections 8 bulge out toward the skin contact surface side, and have hollow interiors. With this embodiment, the shapes of the projections 8 are flat rectangular solids or truncated square pyramids with rectangular bottoms and overall rounded edge lines, but the shapes of the projections 8 may be appropriately varied within a range such that the interiors are hollow. Examples for the shapes of the projections 8 include pyramidal shapes (for example, triangular pyramids and square pyramids) with rounded tops, and cones or arches with rounded tops. As shown in FIG. 3, the projections 8 and recesses 9 are alternately disposed in the X direction and Y direction, with the recesses 9 located between the adjacent projections 8 in the rows in the X direction and Y direction (that is, four recesses 9 surrounding one projection 8). As shown in FIG. 3, the projections 8 are disposed each shifted at half-pitch in every two adjacent rows, and therefore when the top sheet 2 is viewed flat, the arrangement pattern of the projections 8 is a zigzag grid-like pattern. In FIG. 3, the Y direction corresponds to the machine direction (MD direction) and the X direction corresponds to the direction perpendicular to the MD direction (CD direction) during the process of producing the top sheet 2.
The heights of the projections 8 are usually 0.1 to 10 mm and preferably 0.5 to 2.5 mm, the widths (X direction) are usually 0.1 to 20 mm and preferably 2 to 10 mm, the lengths (Y direction) are usually 0.1 to 20 mm and preferably 2 to 10 mm, and the spacings between the projections 8 (widths or lengths of the recesses 9) are usually 0.2 to 20 mm and preferably 1 to 10 mm.
Examples for the first layer 21 and second layer 22 include nonwoven fabrics, synthetic resin films with liquid permeation holes formed therein, and laminates of synthetic resin films and nonwoven fabric laminates, with nonwoven fabrics being preferred. Examples of nonwoven fabrics include air-through nonwoven fabrics, heat-bonded nonwoven fabrics, spunbond nonwoven fabrics, meltblown nonwoven fabric, spunlace nonwoven fabrics and needle punching nonwoven fabrics. Examples of fibers used to form nonwoven fabrics include natural fibers (wool, cotton and the like), regenerated fibers (rayon, acetate and the like), inorganic fibers (glass fibers, carbon fibers and the like), synthetic resin fibers (polyolefins, such as polyethylene, polypropylene, polybutylene, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic acid copolymer, and ionomer resins; polyesters, such as polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate and polylactic acid, and polyamides, such as nylon). The form of the fibers composing the nonwoven fabric may be, for example, composite fibers, such as core/sheath fibers, side-by-side fibers and sea/island fibers, hollow type fibers; irregularly shaped fibers, such as flat fibers, Y-shaped fibers or C-shaped fibers; solid crimped fibers, such as latent crimped or developed crimped fibers, or split fibers that have been split by a physical load, such as a water stream, heat, embossing or the like. The size of the fibers composing the nonwoven fabric is preferably 1 to 20 dtex and more preferably 1.5 to 4 dtex.
When the first layer 21 is a nonwoven fabric, the breaking elongation percentage is preferably 50% or greater in a prescribed direction. This will allow uniform shaping of the concavoconvexities. The breaking elongation percentage is the elongation percentage at the point where the nonwoven fabric breaks under extension in a specific direction, and it is calculated by (L2−L1)/L1, where L1 is the original length of the nonwoven fabric in the relaxed state and L2 is the length when extended.
When the first layer 21 is a nonwoven fabric, it preferably contains elastic fibers from the viewpoint of flexibility and stretchability. Examples of nonwoven fabrics containing elastic fibers include stretchable nonwoven fabrics having a non-elastic layer composed of essentially non-elastic fibers on at least one side of an elastic layer containing elastic fibers, with both layers bonded by heat fusion while maintaining the form of the constituent fibers of the elastic layer (stretchable composite nonwoven fabrics), and stretchable nonwoven fabrics having a plurality of elastic filaments running in one direction without crossing each other, and bonded in an extendable nonwoven fabric across their full lengths in an essentially non-extended state. Various stretchable nonwoven fabrics are known and may be selected for use as appropriate (for example, known stretchable fabrics as described in Japanese Unexamined Patent Publication No. 2008-179128, Japanese Unexamined Patent Publication No. 2007-22066, Japanese Unexamined Patent Publication No. 2007-22066 and Japanese Patent No. 3054930).
Examples of elastic fiber materials include thermoplastic elastomers, such as styrene-based elastomers, polyolefin-based elastomers, polyester-based elastomers and polyurethane-based elastomers, and examples of nonelastic fiber materials include polyethylene (PE), polypropylene (PP), polyester (PET or PBT), polyamide and the like.
There are no particular restrictions on the basis weight of the first layer 21 and second layer 22, but the basis weight of the first layer 21 is usually 10 to 100 g/m2 and preferably 10 to 30 g/m2, and the basis weight of the second layer 22 is usually 5 to 50 g/m2 and preferably 10 to 30 g/m2. The overall basis weight of the top sheet 2 including the first layer 21 and the second layer 22 is usually 15 to 150 g/m2 and preferably 20 to 60 g/m2.
In the projections 8 of the first layer 21, preferably the fiber density and basis weight of the top sections and side sections are essentially equal. That is, preferably the fiber density and basis weight is essential constant across all of the projections 8. When the heights are to be formed by ordinary gear stretching, the gear-stretched sections become the side sections of the projections, and therefore the fiber density and basis weight tend to be lower at the side sections of the projections than at the top sections of the projections. Since liquid readily migrates from low sections to high sections of fiber density, a lower fiber density at the side sections of the projections than at the top sections of the projections inhibits migration of liquid. Also, if the basis weight is lower at the side sections of the projections than at the top sections of the projections, the projections will have high collapsability. In contrast, if the fiber density at the top sections and side sections of the projections 8 is essentially the same, migration of liquid is not inhibited and the projections are resistant to collapse. The side sections of the projections 8 include sections present in the MD direction (Y direction) and the CD direction (X direction). When the fiber density and basis weight of the top sections and side sections is essentially the same, any part of the side sections will have essentially the same fiber density and basis weight.
Since liquid tends to migrate from sections of low fiber density to sections of high fiber density, the presence and extent of the fiber density gradient in the projections 8 can be evaluated by dropping a colored liquid (for example, a pigment-containing liquid) onto the projections 8 and determining the change in color density after dropping. Specifically, the dark-colored sections can be evaluated as sections with high liquid migration, i.e. with relatively high fiber density, while the light-colored sections can be evaluated as sections with low liquid migration, i.e. with relatively low fiber density.
The basis weight of the projections 8 can be measured in the following manner.
(1) A mark is created in the region to be measured and the area: SAα (m2) is measured. In order to minimize error, marking is made so that the total area of the sample exceeds 5 cm2.
(2) The marked area is cut with a sharp blade, for example a cutter replacement blade, and the total mass measured as TM (g).
(3) The basis weight BS, (g/m2) of the area to be measured is determined by the following formula:

BSα (g/m2)=TM (g)/SAα (m2).

The first layer 21 is partially bonded to the second layer 22 at the sections other than the projections 8 (at the recesses 9 in the case of this embodiment). The recesses 9 of the first layer 21 may be fully bonded to the second layer 22, or they may be partially bonded to the second layer 22.
The manner of bonding for this mode is heat fusion by heat embossing treatment, whereby embossed sections are formed that bond the recesses 9 of the first layer 21 with the second layer 22. In other words, the recesses 9 of the first layer 21 are bonded with the second layer 22 by embossed sections. Examples of modes of bonding other than heat fusion by heat embossing treatment include bonding by ultrasonic embossing and adhesives.
From the viewpoint of improving heat sealability by heat embossing treatment, the first layer 21 and/or second layer 22 preferably contain heat-sealable fibers. Examples of heat-sealable fibers include heat-sealable fibers composed of thermoplastic resins, such as polyolefins, polyesters and polyamides. Examples of polyolefins include straight-chain low-density polyethylene (LLDPE), low-density polyethylene (LDPE), medium-density polyethylene (MDPE), high-density polyethylene (HDPE), polypropylene, polybutylene, and copolymers composed mainly of the foregoing (for example, ethylene-vinyl acetate copolymer (EVA), ethylene-ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA) or an ethylene-propylene random copolymer (EP)). Polyethylene, and especially HDPE, is preferred from the viewpoint of thermal processing properties since it has a relatively low softening point of around 100° C., and also has low rigidity and a pliable feel. Examples of polyesters include polyesters of straight-chain or branched polyhydroxyalkane acids up to C20, such as polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), polylactic acid and polyglycolic acid, copolymers composed mainly thereof, and copolymerized polyesters composed mainly of alkylene terephthalates copolymerized with a small amount of another component. PET is preferred from the viewpoint of its elastic repulsion which allows formation of fibers and nonwoven fabrics with high cushioning properties, as well as from an economical viewpoint, since it can be commercially obtained at low cost. Examples of polyamides include 6-nylon and 6,6-nylon. The heat-sealable fibers may be composed of a single type of thermoplastic resin, or they may be composite fibers comprising two or more thermoplastic resins (for example, core-sheath composite fibers or side-by-side composite fibers). Heat-sealable fibers may be short staple fibers or long filaments. The thicknesses of the heat-sealable fibers may be adjusted to 1-7 dtex, for example.
A plurality of open holes may also be provided in the top sheet 2. This will increase the liquid permeability and reduce leakage and mustiness. The open holes can be formed by perforating the top sheet 2, for example. The diameters of the open holes can be adjusted to 0.2 to 10 mm, for example. When a plurality of open holes are formed, the spacing between the open holes may be adjusted to 0.5 to 20 mm, for example.
The top sheet 2 may also be subjected to hydrophilicizing treatment. Hydrophilicizing treatment may be, for example, coating of the surface of the top sheet 2 with a hydrophilic agent, or addition of a hydrophilic agent to the constituent components of the first layer 21 and/or second layer 22, corona treatment, plasma treatment, or the like. When the top sheet 2 is subjected to hydrophilicizing treatment, lipophilic regions created by the blood slipping agent and hydrophilic regions created by the hydrophilic agent become sparsely dispersed in the top sheet 2, so that menstrual blood will tend to slip from the projections 8 of the top sheet 2 and migrate into the absorbent body.
The back sheet 3 is a sheet that prevents permeation of liquid excreta, such as menstrual blood, an example thereof being a liquid-impermeable layer. The back sheet 3 can prevent leakage of absorbed liquid excreta into the absorbent body 4. One side of the back sheet is the non-skin-contacting surface (the side with which the clothing (underwear) of the wearer contacts). The back sheet 3 is preferably moisture-permeable in addition to being liquid-impermeable, in order to reduce mustiness during wear.
Examples for the back sheet 3 include waterproof treated nonwoven fabrics, films of synthetic resins (such as polyethylene, polypropylene and polyethylene terephthalate), composite sheets comprising nonwoven fabrics and synthetic resin films (such as composite films having an air permeable synthetic resin film bonded to a spunbond or spunlace nonwoven fabric), and SMS nonwoven fabrics comprising a highly water-resistant meltblown nonwoven fabric sandwiched between high-strength spunbond nonwoven fabrics.
The absorbent body 4 contains an absorbent material that absorbs liquid excreta, such as menstrual blood. The absorbent material contained in the absorbent body 4 is not particularly restricted so long as it can absorb and hold liquid excreta, such as menstrual blood. The absorbent material may be, for example, water-absorbent fibers or a high-water-absorbing material (for example, a high-water-absorbent resin or high-water-absorbent fibers). The absorbent body 4 may also contain additives, such as antioxidants, light stabilizers, ultraviolet absorbers, neutralizers, nucleating agents, epoxy stabilizers, lubricants, antimicrobial agents, flame retardants, antistatic agents, pigments or plasticizers, as necessary.
Examples of water-absorbent fibers include wood pulp obtained using a conifer or broadleaf tree material as the starting material (for example, mechanical pulp, such as groundwood pulp, refiner ground pulp, thermomechanical pulp and chemithermomechanical pulp; chemical pulp, such as Kraft pulp, sulfide pulp and alkaline pulp; and semichemical pulp); mercerized pulp or crosslinked pulp obtained by chemical treatment of wood pulp; nonwood pulp, such as bagasse, kenaf, bamboo, hemp and cotton (for example, cotton linter); regenerated cellulose, such as rayon and fibril rayon; and semi-synthetic celluloses, such as acetates and triacetates, among which ground pulp is preferred from the viewpoint of low cost and easy shaping.
Examples of high-water-absorbing materials include starch-based, cellulose-based and synthetic polymer high-water-absorbing materials. Examples of starch-based or cellulose-based high-water-absorbing materials include starch-acrylic acid (acrylate) graft copolymer, saponified starch-acrylonitrile copolymer and crosslinked sodium carboxymethyl cellulose, and examples of synthetic polymer-based high-water-absorbing materials include polyacrylic acid salt-based, polysulfonic acid salt-based, maleic anhydride salt-based, polyacrylamide-based, polyvinyl alcohol-based, polyethylene oxide-based, polyaspartic acid salt-based, polyglutamic acid salt-based, polyalginic acid salt-based, starch-based and cellulose-based high water-absorbent resins (Superabsorbent Polymers: SAP), among which polyacrylic acid salt-based (especially sodium polyacrylate-based) high water-absorbent resins are preferred. Examples of high-water-absorbing material forms include particulate, filamentous and scaly forms, and in the case of particulates, the particle size is preferably 50 to 1000 and more preferably 100 to 600 μm.
When the absorbent body 4 contains a high-water-absorbing material (for example, a high-water-absorbing resin or high water-absorbent fibers), the content of the high-water-absorbing material will usually be 5 to 80 mass %, preferably 10 to 60 mass % and more preferably 20 to 40 mass % of the absorbent body 4.
The absorbent body 4 may also contain silver, copper, zinc, silica, active carbon, aluminosilicate compounds, zeolite, or the like. These can impart functions, such as deodorant, antibacterial or heat-absorbing effects to the absorbent body.
The thickness and basis weight of the absorbent body 4 can be appropriately adjusted according to the properties desired for the sanitary napkin 1 (for example, absorption property, strength and lightweight property). The thickness of the absorbent body 4 will usually be 0.1 to 15 mm, preferably 1 to 10 mm and more preferably 2 to 5 mm, and the basis weight will usually be 20 to 1000 g/m2, preferably 50 to 800 g/m2 and more preferably 100 to 500 g/m2. The thickness and basis weight of the absorbent body 4 may be constant across the entire absorbent body 4, or it may partially differ.
The absorbent body 4 may have a core containing an absorbent material, and a core wrap covering the core. The core wrap is not particularly restricted so long as it has liquid permeability and absorbent body retentivity. Examples for the core wrap include nonwoven fabrics, woven fabrics, liquid permeation hole-formed synthetic resin films and meshed net-like sheets, among which tissues formed by a wet method using ground pulp as the main material are preferred from the viewpoint of low cost.
In addition to the top sheet 2, the sanitary napkin 1 may be provided with a second sheet positioned between the top sheet 2 and the absorbent body 4, as a liquid-permeable layer. In this case, a blood slipping agent may be coated onto the second sheet.
The second sheet is not particularly restricted so long as it allows passage of liquid excreta, such as menstrual blood, and the second sheet thickness, basis weight, density and other properties may be appropriately adjusted within ranges that allow passage of liquid excreta, such as menstrual blood.
Examples for the second sheet include nonwoven fabrics, woven fabrics, liquid permeation hole-formed synthetic resin films and meshed net-like sheets. Examples of nonwoven fabrics include air-through nonwoven fabrics, spunbond nonwoven fabrics, point bond nonwoven fabrics, spunlace nonwoven fabrics, needle punching nonwoven fabrics, meltblown nonwoven fabrics, and their combinations (such as SMS), and examples of fibers to compose the nonwoven fabrics include natural fibers (wool, cotton and the like), regenerated fibers (rayon, acetate and the like), inorganic fibers (glass fiber, carbon fibers and the like), synthetic resin fibers (polyolefins, such as polyethylene, polypropylene, polybutylene, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-acrylic acid copolymer and ionomer resins; polyesters, such as polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate and polylactic acid; and polyamides, such as nylon). The nonwoven fabric may be combined with composite fibers, such as core/sheath fibers, side-by-side fibers and sea/island fibers, hollow type fibers; irregularly shaped fibers, such as flat fibers, Y-shaped fibers or C-shaped fibers; solid crimped fibers, such as latent crimped or developed crimped fibers, or split fibers that have been split by a physical load, such as a water stream, heat, embossing or the like.
An embodiment of a method for producing an absorbent article of the invention will now be described with reference to the accompanying drawings, using a method for producing a sanitary napkin 1 as an example.
The production method according to this embodiment comprises a step of forming an absorbent body 4 (step 1), a step of layering a top sheet 2 on the absorbent body 4 (step 2), a step of forming compressed grooves in the layered body (step 3), a step of layering a back sheet 3 (step 4), a step of cutting out a sanitary napkin 1 (step 5) and a step of coating the sanitary napkin 1 with a blood slipping agent (step 6), and the production apparatus 200 shown in FIG. 7 is used.
[Step 1]
Recesses 224 are formed at a prescribed pitch in the circumferential direction on the peripheral surface of a suction drum 220 rotating in the machine direction MD, as a molding form in which the absorbent body material 222 is to be packed. When the suction drum 220 is rotated and the recesses 224 approach the material feeder 221, the suction section 226 acts on the recesses 224 and the absorbent body material 222 supplied from the material feeder 221 is vacuum suctioned into the recesses 224. The material feeder 221 is formed to cover the suction drum 220, and the material feeder 221 supplies the absorbent body material 222 into the recesses 224 by air transport, forming an absorbent body 4 in the recesses 224. The absorbent body 4 formed in the recesses 224 is transferred onto a carrier sheet 210 advancing in the machine direction MD.
[Step 2]
The top sheet 2 is layered on the absorbent body 4, forming a layered body 262. A method for producing the top sheet 2 will be described below.
Next, compressed grooves are formed if necessary in the layered body 262. Compressed grooves are formed using an embossing apparatus 230. The embossing apparatus 230 has an upper roll 231 provided with projections (not shown) on the outer peripheral surface, and a lower roll 232 having a smooth outer peripheral surface. The projections of the upper roll 231 are formed to correspond to the shapes and arrangement pattern of the compressed grooves. When the layered body 262 passes between the upper roll 231 and lower roll 232 of the embossing apparatus 230, the layered body 262 becomes compressed in the thickness direction, and compressed grooves are formed in the layered body 262. The compressed grooves are formed on the top sheet 2 around the excretory opening contact region 20 or in the surrounding region of the excretory opening contact region 20. Formation of compressed grooves integrate the top sheet 2 with the absorbent body 4. When the step of forming the compressed grooves with the embossing apparatus 230 is unnecessary, it may be omitted.
[Step 3]
The back sheet 3 supplied from the back sheet roll 240 is layered on the surface of the lower side of the layered body 234 (the side opposite the top sheet) via an adhesive layer, to form a continuous section 244 of the sanitary napkin. When the step of forming compressed grooves with an embossing apparatus 230 is omitted, the layered body 234 and the layered body 262 are identical.
[Step 4]
A cutter 250 is used to cut the continuous section 244 of the sanitary napkin, thereby cutting out a sanitary napkin.
[Step 5]
A blood slipping agent 261 is coated onto the top sheet 2 of the sanitary napkin using spray 260, thereby forming a blood slipping agent layer on the surface of the top sheet 2. The blood slipping agent layer is formed in at least the excretory opening contact region 20 on the skin contact surface of the top sheet 2.
For this embodiment, the blood slipping agent was coated after cutting out the sanitary napkin, but it may instead be coated at any stage before cutting, or it may be coated during the production steps for the top sheet. In order to prevent dripping down of the blood slipping agent that has been coated during production, the blood slipping agent is preferably coated at a downstream stage of the production process, such as immediately before packaging of the sanitary napkin.
The method for producing the sanitary napkin 1 may comprise, in addition to steps 1 to 5, also a step of forming seal sections 7a, 7b, 8a, 8b and a step of forming pressure-sensitive adhesive sections 9a, 9b, 9c. 
<Method for Producing Top Sheet>
An embodiment of a method for producing a top sheet 2 will now be described with reference to the accompanying drawings.
The gear stretcher 100 shown in FIG. 4 was used for the method of this embodiment.
As shown in FIG. 4, the gear stretcher 100 comprises a pair of gear stretching rolls 120, 130. The rotating shafts of the gear stretching rolls 120, 130 are provided perpendicular to the machine direction MD, and by transferring driving force from a drive unit (not shown) to either rotating shaft, the gear stretching rolls 120, 130 rotate in an meshed manner.
As shown in FIGS. 4 to 6, a plurality of teeth 121 are provided on the outer peripheral surface of the gear stretching roll 120. As shown in FIG. 5(a), the teeth 121 are provided in a zigzag grid-like manner at fixed spacings, and the sections where the teeth 121 are not provided constitute grooves 122. As shown in FIG. 5(a), the teeth 121 and grooves 122 are disposed in alternating rows in the MD direction, and the grooves 122 are located between adjacent teeth 121 in each row.
As shown in FIGS. 4 to 6, a plurality of teeth 131 are provided on the outer peripheral surface of the gear stretching roll 130. As shown in FIG. 5(b), the teeth 131 are provided in a zigzag grid-like manner at fixed spacings, and the sections where the teeth 131 are not provided constitute grooves 132. As shown in FIG. 5(b), the teeth 131 and grooves 132 are disposed in alternating rows in the MD direction, and the grooves 132 are located between adjacent teeth 131 in each row.
As shown in FIG. 6, the tooth/grooves of the gear stretching rolls 120, 130 engage with each other when the gear teeth 121 of the gear stretching roll 120 enter into the grooves 132 of the gear stretching roll 130 while the gear teeth 131 of the gear stretching roll 130 enter into the grooves 122 of the gear stretching roll 120.
The pitch P of the teeth 121, 131 of the gear stretching rolls 120, 130 (the distance between the center lines) is preferably 0.2 to 40 mm and more preferably 3 to 15 mm. The heights H of the teeth 121, 131 are preferably 0.1 to 10 mm and more preferably 0.5 to 2.5 mm. The teeth 121, 131 have trapezoidal shapes that narrow from the bottom sections toward the tip sections, the widths W1 of the bottom sections of the teeth 121, 131 being preferably 0.2 to 20 mm and more preferably 1 to 5 mm, and the widths W2 of the tip sections of the teeth being preferably 0.01 to 5 mm and more preferably 0.5 to 2.5 mm. The widths of the gear teeth 121, 131 (CD direction) determine the widths of the projections 8 and recesses 9 (X direction), while the lengths of the gear teeth 121, 131 (MD direction) determine the lengths of the projections 8 and recesses 9 (Y direction).
The corners of the tip sections of the teeth of the gear stretching rolls 120, 130 are preferably chamfered. The value of the width W2 is the value before chamfering.
The spacing between the teeth 121, 131 when the teeth/grooves of the gear stretching rolls 120, 130 are meshed is preferably 0.05 to 5 mm and more preferably 0.1 to 2.5 mm. The mesh depth D of the teeth 121, 131 of the gear stretching rolls 120, 130 is preferably 0.1 to 5 mm and more preferably 0.5 to 3 mm. The mesh depth D of the teeth is the length of the overlapping sections of the teeth 121, 131, when the meshed sections of the teeth/grooves of the gear stretching rolls 120, 130 are viewed flat from the rotating shaft direction of the gear stretching rolls 120, 130 (CD direction).
As shown in FIG. 5(a), suction holes 1220 are formed in the grooves 122 of the gear stretching roll 120. The suction holes 1220 are connected to a suction apparatus, such as a vacuum pump (not shown), and the first layer 21 is bonded to the peripheral surface of the gear stretching roll 120, and is transported while maintaining formation of concavoconvexities.
As shown in FIG. 4, the first layer 21 has concavoconvexities formed by passage through the meshed sections of the teeth/grooves of the gear stretching rolls 120, 130. The sections where protrusions are formed by the teeth 121 of the gear stretching roll 120 correspond to the recesses 9 of the first layer 21, and the sections where protrusions are formed by the teeth 131 of the gear stretching roll 130 correspond to the projections 8 of the first layer 21.
As shown in FIG. 4, the first layer 21 in which concavoconvexities have been formed is firmly held against the peripheral surface of the gear stretching roll 120 by suction force through the suction holes 1220, while being layered with the separately reeled out second layer 22, and being pressed between the gear stretching roll 120 and an anvil roll 140. The anvil roll 140 is a flat roll without concavoconvexities on the outer peripheral surface. The anvil roll 140 is heated to a prescribed temperature, and during passage between the gear stretching roll 120 and the anvil roll 140, the sections where protrusions have been formed by the teeth 121 of the gear stretching roll 120 (that is, the recesses 9 of the first layer 21) become bonded with the second layer 22 by heat fusion, thereby forming embossed sections where the recesses 9 of the first layer 21 are bonded with the second layer 22. In this manner there is formed a top sheet 2 having a second layer 22, and a first layer 21 that has projections 8 with hollow interiors bulging toward the skin contact surface side and partially bonded with the second layer 22 at the sections other than the projections 8 (the recesses 9 for this embodiment). Instead of bonding by heat fusion, the layers may be bonded with an adhesive or by ultrasonic bonding.
In embossing treatment conducted with the gear stretching roll 120 and anvil roll 140, the heating temperature is usually 50° C. to 180° C. and preferably 70° C. to 160° C., the pressure is usually 10 to 3000 N/mm and preferably 50 to 500 N/mm, and the treatment time is usually 0.0001 to 10 seconds and preferably 0.005 to 2 seconds.
As shown in FIG. 4, a wind-out roll 110 and a pair of first driving rolls 151, 152 are provided upstream from the gear stretching rolls 120, 130. The wind-out roll 110 winds out the first layer 21 from a supply roll (sheet roll) for the first layer 21 before formation of concavoconvexities, and supplies it to the pair of first driving rolls 151, 152. The first driving rolls 151, 152 supply the first layer 21 to gear stretching rolls 120, 130. In the transport pathway from the first driving rolls 151, 152 to the gear stretching rolls 120, 130 there are provided a tension detector (not shown), and a controller (not shown) that controls the peripheral speed V1 of the first driving rolls 151, 152 based on the degree of detected tension at the tension detector. The controller relatively adjusts the peripheral speeds V1 of the first driving rolls 151, 152 with respect to the peripheral speeds V2 of the gear stretching rolls 120, 130, based on the detection output from the tension detector. This causes the tension of the first layer 21 supplied to the gear stretching rolls 120, 130 to be adjusted to the desired tension. When the tension detected at the tension detector is greater than the desired tension, the controller increases the peripheral speeds V1 of the first driving rolls 151, 152 to be greater than the peripheral speeds V2 of the gear stretching rolls 120, 130, lowering the tension of the first layer 21 supplied to the gear stretching rolls 120, 130. On the other hand, when the tension detected at the tension detector is less than the desired tension, the controller decreases the peripheral speeds V1 of the first driving rolls 151, 152 to be less than the peripheral speeds V2 of the gear stretching rolls 120, 130, increasing the tension of the first layer 21 supplied to the gear stretching rolls 120, 130. The peripheral speeds V1 of the first driving rolls 151, 152 are adjusted relative to the wind-out speed of the wind-out roll 110 to allow the desired tension to be applied to the first layer 21. The relatively adjusted peripheral speeds V1 of the first driving rolls 151, 152 and peripheral speeds V2 of the gear stretching rolls 120, 130 are the speeds of the roll surfaces.
As shown in FIG. 4, a pair of second driving rolls 153, 154 are provided downstream from the gear stretching rolls 120, 130. The second driving rolls 153, 154 pull the top sheet 2 out from the gear stretching rolls 120, 130 and transport it to the subsequent step (see FIG. 7). In the transport pathway from the gear stretching rolls 120, 130 to the second driving rolls 153, 154 there are provided a tension detector (not shown), and a controller (not shown) that controls the peripheral speed V3 of the second driving rolls 153, 154 based on the degree of detected tension at the tension detector. The controller relatively adjusts the peripheral speeds V3 of the second driving rolls 153, 154 with respect to the peripheral speeds V2 of the gear stretching rolls 120, 130, based on the detection output from the tension detector. This allows the tension of the top sheet 2 drawn out from the gear stretching rolls 120, 130 to be adjusted to the desired tension. When the tension detected at the tension detector is greater than the desired tension, the controller reduces the peripheral speeds V3 of the second driving rolls 153, 154 to be greater than the peripheral speeds V2 of the gear stretching rolls 120, 130, lowering the tension of the top sheet 2 drawn out from the gear stretching rolls 120, 130. On the other hand, when the tension detected at the tension detector is less than the desired tension, the controller increases the peripheral speeds V3 of the second driving rolls 153, 154 to be greater than the peripheral speeds V2 of the gear stretching rolls 120, 130, increasing the tension of the top sheet 2 drawn out from the gear stretching rolls 120, 130. The relatively adjusted peripheral speeds V2 of the gear stretching rolls 120, 130 and peripheral speeds V3 of the second driving rolls 153, 154 are the speeds of the roll surfaces.
When the projections 8 are to be formed by ordinary gear stretching, the sections stretched by engagement of the teeth/grooves of the gear stretching rolls 120, 130 become the side sections of the projections 8, and therefore the fiber density and basis weight tend to be lower at the side sections of the projections 8 than at the top sections of the projections 8. Since liquid readily migrates from low sections to high sections of fiber density, a lower fiber density at the side sections of the projections 8 than at the top sections of the projections 8 inhibits migration of liquid. Also, if the basis weight is lower at the side sections of the projections 8 than at the top sections of the projections 8, the projections 8 will have high collapsability. Thus, the basis weights of the top sections and side sections of the projections 8 are preferred to be essentially equal. For this embodiment, the basis weights of the top sections and side sections of the projections 8 are rendered essentially equal by adjustment of the peripheral speeds V1 of the first driving rolls 151, 152. Specifically, when the first layer 21 is supplied to the rotating pair of gear stretching rolls 120, 130 by the pair of first driving rolls 151, 152, and the first layer 21 is stretched by the meshed sections of the teeth/grooves of the gear stretching rolls 120, 130, the peripheral speeds V1 of the first driving rolls 151, 152 are increased to be greater than the peripheral speeds V2 of the gear stretching rolls 120, 130, in order to prevent reduction in the basis weight and fiber density of the stretched sections (i.e. the side sections of the projections 8). This allows the first layer 21 to be overfed with respect to the gear stretching rolls 120, 130, to prevent reduction in the basis weight and fiber density at the stretched sections (i.e. the sections corresponding to the side sections of the projections 8). As a result, the basis weight and fiber density at the top sections and side sections of the projections 8 are rendered essentially equal. The peripheral speeds V1 of the first driving rolls 151, 152 are preferably 1 to 1.6 times and more preferably 1.1 to 1.4 times the peripheral speeds V2 of the gear stretching rolls 120, 130. Such adjustment of the peripheral speeds V1 of the first driving rolls 151, 152 is described in detail in Japanese Unexamined Patent Publication No. 2011-80172, for example.
From the viewpoint of drawing out the top sheet 2 from between the pair of gear stretching rolls 120, 130 while applying tension to the top sheet 2, the ratio of the peripheral speeds V2 of the gear stretching rolls 120, 130 with respect to the peripheral speeds V3 of the second driving rolls 153, 154 [(V2/V3)×100] is preferably 10% to 90%, more preferably 30% to 70% and even more preferably 30% to 50%. Also, the peripheral speeds V3 of the second driving rolls 153, 154 are preferably set to speeds that are higher than the peripheral speeds V1 of the first driving rolls 151, 152 (V3>V1). The ratio of the peripheral speeds V1 of the first driving rolls 151, 152 with respect to the peripheral speeds V3 of the second driving rolls 153, 154 [(V1/V3)×100] is preferably 30% to 80% and more preferably 40% to 60%.
For the top sheet 2, the first layer 21 may have tunnel sections running through the interior spaces of the projections 8. The tunnel sections have interior spaces connecting the interior spaces of the projections 8. The details regarding formation of the concavoconvexities of the first layer 21 are described in Japanese Unexamined Patent Publication No. 2009-160035, for example.
<Blood Slipping Agent>
The blood slipping agent has a kinematic viscosity of about 0.01 to about 80 mm2/s at 40° C., a water holding percentage of about 0.05 to about 4.0 mass %, and a weight-average molecular weight of less than about 1,000.
The 40° C. kinematic viscosity of the blood slipping agent may be appropriately adjusted in the range of about 0 to about 80 mm2/s, but it is preferably about 1 to about 70 mm2/s, more preferably about 3 to about 60 mm2/s, even more preferably about 5 to about 50 mm2/s and yet more preferably about 7 to about 45 mm2/s. As used herein, the “40° C. kinematic viscosity” may be referred to simply as “kinematic viscosity”.
The kinematic viscosity tends to be higher with a) a larger molecular weight of the blood slipping agent, b) a higher percentage of polar groups, such as carbonyl bonds (—CO—), ether bonds (—O—), carboxyl groups (—COOH) and hydroxyl groups (−OH), and c) a larger IOB.
In order to have a kinematic viscosity of about 0 to about 80 mm2/s at 40° C., the melting point of the blood slipping agent is preferably no higher than 45° C. This is because the kinematic viscosity will tend to be higher if the blood slipping agent contains crystals at 40° C.
The significance of the kinematic viscosity of the blood slipping agent will be explained below, but a kinematic viscosity exceeding about 80 mm2/s will tend to result in high viscosity of the blood slipping agent, such that it will not as easily slip down from the projections to the recesses together with menstrual blood that has reached the skin contact surface of the top sheet, and subsequently migrate into the absorbent body.
The kinematic viscosity can be measured according to JIS K 2283:2000, “5. Kinematic Viscosity Test Method”, using a Cannon-Fenske reverse-flow viscometer, at a testing temperature of 40° C.
The water holding percentage of the blood slipping agent may be appropriately adjusted in the range of about 0.01 to about 4.0 mass %, but it is preferably about 0.02 to about 3.5 mass %, more preferably about 0.03 to about 3.0 mass %, even more preferably about 0.04 to about 2.5 mass % and yet more preferably about 0.05 to about 2.0 mass %.
As used herein, “water holding percentage” means the percentage (weight) of water that can be held by a substance, and it may be measured in the following manner.
(1) A 20 mL test tube, a rubber stopper, the substance to be measured and deionized water are allowed to stand for a day and a night in a thermostatic chamber at 40° C.
(2) Into the test tube in the thermostatic chamber there are charged 5.0 g of the substance to be measured and 5.0 g of deionized water.
(3) The mouth of the test tube is closed with the rubber stopper in the thermostatic chamber, and the test tube is rotated once and allowed to stand for 5 minutes.
(4) A 3.0 g portion of the layer of the substance to be measured (usually the upper layer) is sampled into a glass dish with a diameter of 90 mm and a mass of W0 (g), in the thermostatic chamber.
(5) The dish is heated at 105° C. for 3 hours in an oven to evaporate off the moisture, and the mass W1 (g) of each dish is measured.
(6) The water holding percentage is calculated by the following formula.

Water holding percentage (mass %)=100×[W0 (g)−W1 (g)]/3.0 (g)

The measurement is conducted three times, and the average value is recorded.
The significance of the water holding percentage of the blood slipping agent will be explained below, but a low water holding percentage will tend to lower the affinity between the blood slipping agent and menstrual blood, thus impeding its migration into the absorbent body together with menstrual blood that has reached the skin contact surface of the top sheet. If the water holding percentage is high, on the other hand, the affinity between menstrual blood and the blood modifying agent will become very high, similar to a surfactant, and absorbed menstrual blood will tend to remain on the skin contact surface of the top sheet, resulting in more red coloration of the skin contact surface of the top sheet.
The water holding percentage tends to be a larger value with a) a smaller molecular weight of the blood slipping agent, and b) a higher percentage of polar groups, such as carbonyl bonds (—CO—), ether bonds (—O—), carboxyl groups (—COOH) and hydroxyl groups (−OH). This is because the blood slipping agent has greater hydrophilicity. The water holding percentage will tend to have a larger value with a greater IOB, i.e with a higher inorganic value or with a lower organic value. This is also because the blood slipping agent has greater hydrophilicity.
The significance of the kinematic viscosity and water holding percentage of the blood slipping agent will now be explained.
Menstrual blood excreted by the wearer and reaching the excretory opening contact region contacts the blood slipping agent in the projections and slips down together with it into the recesses, passing through the top sheet and migrating into the absorbent body.
More specifically, since the blood slipping agent with a kinematic viscosity of about 0.01 to about 80 mm2/s at 40° C. has very low viscosity near the body temperature of the wearer and has a constant affinity with the menstrual blood, it slips down from the projections to the recesses together with the menstrual blood, and utilizing the energy during sliding, the menstrual blood is able to pass through the recesses of the top sheet to rapidly migrate into the absorbent body. Also, since the blood slipping agent present in the projections has a water holding percentage of about 0.01 to about 4.0 mass %, presumably it has no affinity with the hydrophilic component (blood plasma, etc.) in the menstrual blood, and therefore the menstrual blood does not easily remain on the top sheet.
When the menstrual blood discharged by the wearer is a large amount of menstrual blood, the menstrual blood easily migrates into the absorbent body, even when the kinetic energy of the menstrual blood itself is high and the kinematic viscosity of the blood slipping agent is relatively high so that it does not easily slip down together with the menstrual blood, or when the water holding percentage value is relatively high so that affinity with the hydrophilic components of the menstrual blood is high, or when the weight-average molecular weight value is relatively high so that it does not easily slip down together with the menstrual blood, or when the skin contact surface of the top sheet does not have an irregular structure.
When the menstrual blood discharge by the wearer is a small amount of menstrual blood, on the other hand, the kinetic energy of the menstrual blood is low, and menstrual blood that has reached the skin contact surface of the top sheet tends to easily pool in such cases. Consequently, the blood slipping agent slides down from the projections into the recesses together with the menstrual blood, and the menstrual blood is drawn into the top sheet and then drawn into the absorbent body, so that the menstrual blood can rapidly migrate into the absorbent body.
The blood slipping agent has a weight-average molecular weight of less than about 1,000, and preferably a weight-average molecular weight of less than about 900. This is because if the weight-average molecular weight is about 1,000 or higher, tack may be produced in the blood slipping agent itself, tending to create a feeling of discomfort for the wearer. If the weight-average molecular weight increases, the viscosity of the blood slipping agent will tend to increase, and it will therefore be difficult to lower the viscosity of the blood slipping agent by heating to a viscosity suitable for coating, and as a result, the blood slipping agent may need to be diluted with a solvent.
The blood slipping agent preferably has a weight-average molecular weight of about 100 or greater, and more preferably it has a weight-average molecular weight of about 200 or greater. This is because if the weight-average molecular weight is low, the vapor pressure of the blood slipping agent may be increased, gasification may occur during storage and the amount may be reduced, often leading to problems, such as odor during wear.
As used herein, “weight-average molecular weight” includes the concept of a polydisperse compound (for example, a compound produced by stepwise polymerization, an ester formed from a plurality of fatty acids and a plurality of aliphatic monohydric alcohols), and a simple compound (for example, an ester formed from one fatty acid and one aliphatic monohydric alcohol), and in a system comprising Ni molecules with molecular weight Mi (i=1, or i=1, 2 . . . ), it refers to Mw determined by the following formula.

Mw=ΣNiMi2/ΣNiMi 

The weight-average molecular weights used throughout the present specification are the values measured by gel permeation chromatography (GPC), based on polystyrene.
The GPC measuring conditions may be the following, for example.
Device: Lachrom Elite high-speed liquid chromatogram by Hitachi High-Technologies Corp.
Columns: SHODEX KF-801, KF-803 and KF-804, by Showa Denko K.K.
Eluent: THF
Flow rate: 1.0 mL/min
Driving volume: 100 μL
Detection: RI (differential refractometer)
The weight-average molecular weights listed in the examples of the present specification were measured under the conditions described below.
The blood slipping agent may have an IOB of about 0.00 to about 0.60.
The IOB (Inorganic Organic Balance) is an indicator of the hydrophilic-lipophilic balance, and as used herein, it is the value calculated by the following formula by Oda et al.:

IOB=Inorganic value/organic value.

The inorganic value and the organic value are based on the organic paradigm described in “Organic compound predictions and organic paradigms” by Fujita A., Kagaku no Ryoiki (Journal of Japanese Chemistry), Vol. 11, No. 10 (1957) p. 719-725.
The organic values and inorganic values of major groups, according to Fujita, are summarized in Table 1 below.











TABLE 1








Inorganic
Organic



Group
value
value




















—COOH
150
0



—OH
100
0



—O—CO—O—
80
0



—CO—
65
0



—COOR
60
0



—O—
20
0



Triple bond
3
0



Double bond
2
0



CH2
0
20



iso branching
0
−10



tert branching
0
−20



Light metal (salt)
≧500
0










For example, in the case of an ester of tetradecanoic acid which has 14 carbon atoms and dodecyl alcohol which has 12 carbon atoms, the organic value is 520 (CH2, 20×26) and the inorganic value is 60 (—COOR, 60×1), and therefore IOB=0.12.
The IOB of the blood slipping agent is preferably between about 0.00 and 0.60, more preferably between about 0.00 and 0.50, even more preferably between about 0.00 and 0.40 and most preferably between about 0.00 and 0.30. If the IOB is within this range, it will be easier to meet the aforementioned conditions for the water-holding capacity and kinematic viscosity.
The blood slipping agent preferably has a melting point of no higher than 45° C., and more preferably it has a melting point of no higher than 40° C. If the blood slipping agent has a melting point of no higher than 45° C., the blood slipping agent will more easily exhibit a kinematic viscosity in the aforementioned range.
As used herein, the term “melting point” refers to the peak top temperature for the endothermic peak during conversion from solid to liquid, upon measurement with a differential scanning calorimetry analyzer at a temperature-elevating rate of 10° C./min. The melting point may be measured using a Model DSC-60 DSC measuring apparatus by Shimadzu Corp., for example.
If the blood slipping agent has a melting point of no higher than about 45° C., it may be either liquid or solid at room temperature (about 25° C.), or in other words, the melting point may be either about 25° C. or higher or below about 25° C., and for example, it may have a melting point of about −5° C. or about −20° C.
The blood slipping agent does not have a lower limit for its melting point, but its vapor pressure is preferably low. The vapor pressure of the blood slipping agent is preferably between about 0 and about 200 Pa, more preferably between about 0 and about 100 Pa, more preferably between about 0 and about 10 Pa, even more preferably between about 0 and about 1 Pa and yet more preferably between about 0.0 and about 0.1 Pa, at 25° C. (1 atmosphere).
Considering that the absorbent article of the present disclosure is to be used in contact with the human body, the vapor pressure is preferably between about 0 and about 700 Pa, more preferably between about 0 and about 100 Pa, more preferably between about 0 and about 10 Pa, even more preferably between about 0 and about 1 Pa and yet more preferably between about 0.0 and about 0.1 Pa, at 40° C. (1 atmosphere). If the vapor pressure of the blood slipping agent is high, gasification may occur during storage and the amount may be reduced, often creating problems, such as odor during wear.
The melting point of the blood slipping agent may be selected depending on the weather or duration of wear. For example, in regions with a mean atmospheric temperature of no higher than about 10° C., using a blood slipping agent with a melting point of no higher than about 10° C. may help the blood slipping agent function after excretion of menstrual blood, even if it has been cooled by the ambient temperature.
Also, when the absorbent article is to be used for a prolonged period of time, the melting point of the blood slipping agent is preferably at the high end of the range of no higher than about 45° C. This is so that the blood slipping agent will not be easily affected by sweat or friction during wearing, and will not easily become biased even during prolonged wearing.
In the technical field, the skin contact surfaces of top sheets are coated with surfactants in order to alter the surface tension of menstrual blood and promote rapid absorption of menstrual blood. However, the top sheet coated with the surfactant has very high affinity for the hydrophilic components (blood plasma, etc.) in menstrual blood, and acts to attract them, tending to cause menstrual blood instead to remain on the top sheet. The blood slipping agent, unlike conventionally known surfactants, has low affinity with menstrual blood and therefore does not cause residue of menstrual blood on the top sheet and allows rapid migration into the absorbent body.
The blood slipping agent is preferably selected from the group consisting of the following items (i)-(iii), and any combination thereof:
(i) a hydrocarbon;
(ii) a compound having (ii-1) a hydrocarbon moiety, and (ii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii) a compound having (iii-1) a hydrocarbon moiety, (iii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen of the hydrocarbon moiety.
As used herein, “hydrocarbon” refers to a compound composed of carbon and hydrogen, and it may be a chain hydrocarbon, such as a paraffinic hydrocarbon (containing no double bond or triple bond, also referred to as “alkane”), an olefin-based hydrocarbon (containing one double bond, also referred to as “alkene”), an acetylene-based hydrocarbon (containing one triple bond, also referred to as “alkyne”), or a hydrocarbon or cyclic hydrocarbon comprising two or more bonds selected from the group consisting of double bonds or triple bonds, such as aromatic hydrocarbons and alicyclic hydrocarbons.
Preferred as such hydrocarbons are chain hydrocarbons and alicyclic hydrocarbons, with chain hydrocarbons being more preferred, paraffinic hydrocarbons, olefin-based hydrocarbons and hydrocarbons with two or more double bonds (containing no triple bond) being more preferred, and paraffinic hydrocarbons being even more preferred.
Chain hydrocarbons include straight-chain hydrocarbons and branched-chain hydrocarbons.
When two or more oxy groups (—O—) are inserted in the compounds of (ii) and (iii) above, the oxy groups (—O—) are not adjacent. Thus, compounds (ii) and (iii) do not include compounds with continuous oxy groups (i.e. peroxides).
In the compounds of (iii), compounds in which at least one hydrogen on the hydrocarbon moiety is substituted with a hydroxyl group (—OH) are preferred over compounds in which at least one hydrogen on the hydrocarbon moiety is substituted with a carboxyl group (—COOH). This is because the carboxyl groups bond with metals and the like in menstrual blood, increasing the water holding percentage of the blood slipping agent, which may sometimes exceed the prescribed range. The same is true from the viewpoint of the IOB as well. As shown in Table 1, the carboxyl groups bond with metals and the like in menstrual blood, drastically increasing the inorganic value from 150 to 400 or greater, and therefore a blood slipping agent with carboxyl groups can increase the IOB value to more than about 0.60 during use.
The blood slipping agent is more preferably selected from the group consisting of the following items (i′)-(iii′), and any combination thereof:
(i′) a hydrocarbon;
(ii′) a compound having (ii′-1) a hydrocarbon moiety, and (ii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii′) a compound having (iii′-1) a hydrocarbon moiety, (iii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii′-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen on the hydrocarbon moiety.
When 2 or more identical or different bonds are inserted in a compound of (ii′) or (iii′), that is, when 2 or more identical or different bonds selected from among carbonyl bonds (—CO—), ester bonds (—COO—), carbonate bonds (—OCOO—) and ether bonds (—O—) are inserted, the bonds are not adjacent to each other, and at least one carbon atom lies between each of the bonds.
The blood slipping agent more preferably has no more than about 1.8 carbonyl bonds (—CO—), no more than two ester bonds (—COO—), no more than about 1.5 carbonate bonds (—OCOO—), no more than about 6 ether bonds (—O—), no more than about 0.8 carboxyl groups (—COOH) and/or no more than about 1.2 hydroxyl groups (—OH), per 10 carbon atoms in the hydrocarbon moiety.
The blood slipping agent is even more preferably selected from the group consisting of the following items (A)-(F), and any combination thereof:
(A) an ester of (A1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety, and (A2) a compound having a chain hydrocarbon moiety and 1 carboxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(B) an ether of (B1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety and (B2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(C) an ester of (C1) a carboxylic acid, hydroxy acid, alkoxy acid or oxoacid comprising a chain hydrocarbon moiety and 2-4 carboxyl groups substituting hydrogens on the chain hydrocarbon moiety and (C2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(D) a compound having a chain hydrocarbon moiety and one bond selected from the group consisting of an ether bond (—O—), carbonyl bond (—CO—), ester bond (—COO—) and carbonate bond (—OCOO—) inserted between a C—C single bond of the chain hydrocarbon moiety;
(E) a polyoxy C3-C6 alkylene glycol, or alkyl ester or alkyl ether thereof; and
(F) a chain hydrocarbon.
The blood slipping agent according to (A) to (F) will now be explained in detail.
[(A) Ester of (A1) a Compound Having a Chain Hydrocarbon Moiety and 2-4 Hydroxyl Groups Substituting Hydrogens on the Chain Hydrocarbon Moiety, and (A2) a Compound Having a Chain Hydrocarbon Moiety and 1 Carboxyl Group Substituting a Hydrogen on the Chain Hydrocarbon Moiety]
The (A) ester of (A1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety, and (A2) a compound having a chain hydrocarbon moiety and 1 carboxyl group substituting a hydrogen on the chain hydrocarbon moiety (hereunder also referred to as “compound (A)”) does not need to have all of the hydroxyl groups esterified, so long as it has the aforementioned kinematic viscosity, water holding percentage and weight-average molecular weight.
Examples for the (A1) compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting at hydrogens of the chain hydrocarbon moiety (hereunder also referred to as “compound (A1)”) include chain hydrocarbon tetraols, such as alkanetetraols including pentaerythritol, chain hydrocarbon triols, such as alkanetriols including glycerin, and chain hydrocarbon diols, such as alkanediols including glycols.
Compounds for the (A2) compound having a chain hydrocarbon moiety and one carboxyl group substituting at a hydrogen of the chain hydrocarbon moiety include compounds in which one hydrogen on the hydrocarbon is substituted with one carboxyl group (—COOH), such as fatty acids.
Examples for compound (A) include (a1) an ester of a chain hydrocarbon tetraol and at least one fatty acid, (a2) an ester of a chain hydrocarbon triol and at least one fatty acid, and (a3) an ester of a chain hydrocarbon diol and at least one fatty acids.
[(a1) Ester of a Chain Hydrocarbon Tetraol and at Least One Fatty Acid]
Examples of esters of a chain hydrocarbon tetraol and at least one fatty acid include tetraesters of pentaerythritols and fatty acids, represented by the following formula (1):




triesters of pentaerythritol and fatty acids, represented by the following formula (2):





diesters of pentaerythritol and fatty acids, represented by the following formula (3):





and monoesters of pentaerythritol and fatty acids, represented by the following formula (4).





(In the formulas, R1 to R4 each represent a chain hydrocarbon.)

The fatty acids composing the esters of pentaerythritol and fatty acids (R1COOH, R2COOH, R3COOH, and R4COOH) are not particularly restricted so long as the pentaerythritol and fatty acid esters satisfy the conditions for the kinematic viscosity, water holding percentage and weight-average molecular weight, and for example, there may be mentioned saturated fatty acids, such as a C2-C30 saturated fatty acids, including acetic acid (C2) (C2 representing the number of carbons, corresponding to the number of carbons of R1C, R2C, R3C or R4C, same hereunder), propanoic acid (C3), butanoic acid (C4) and its isomers, such as 2-methylpropanoic acid (C4), pentanoic acid (C5) and its isomers, such as 2-methylbutanoic acid (C5) and 2,2-dimethylpropanoic acid (C5), hexanoic acid (C6), heptanoic acid (C7), octanoic acid (C8) and its isomers, such as 2-ethylhexanoic acid (C8), nonanoic acid (C9), decanoic acid (C10), dodecanoic acid (C12), tetradecanoic acid (C14), hexadecanoic acid (C16), heptadecanoic acid (C17), octadecanoic acid (Cn), eicosanoic acid (C20), docosanoic acid (C22), tetracosanoic acid (C24), hexacosanoic acid (C26), octacosanoic acid (C28) and triacontanoic acid (C30), as well as isomers of the foregoing that have not been mentioned.
The fatty acid may also be an unsaturated fatty acid. Examples of unsaturated fatty acids include C3-C20 unsaturated fatty acids, such as monounsaturated fatty acids including crotonic acid (C4), myristoleic acid (C14), palmitoleic acid (C16), oleic acid (C18), elaidic acid (C18), vaccenic acid (C18), gadoleic acid (C20) and eicosenoic acid (C20), di-unsaturated fatty acids including linolic acid (C18) and eicosadienoic acid (C20), tri-unsaturated fatty acids including linolenic acids, such as α-linolenic acid (C18) and γ-linolenic acid (C18), pinolenic acid (C18), eleostearic acids, such as α-eleostearic acid (C18) and β-eleostearic acid (C18), Mead acid (C20), dihomo-γ-linolenic acid (C20) and eicosatrienoic acid (C20), tetra-unsaturated fatty acids including stearidonic acid (C20), arachidonic acid (C20) and eicosatetraenoic acid (C20), penta-unsaturated fatty acids including bosseopentaenoic acid (C18) and eicosapentaenoic acid (C20), and partial hydrogen adducts of the foregoing.
Considering the potential for degradation by oxidation and the like, the ester of pentaerythritol and a fatty acid is preferably an ester of pentaerythritol and a fatty acid derived from a saturated fatty acid, or in other words, an ester of pentaerythritol and a saturated fatty acid.
Also, in order to lower the water holding percentage value, the ester of pentaerythritol and a fatty acid is preferably a diester, triester or tetraester, more preferably a triester or tetraester, and most preferably a tetraester.
From the viewpoint of the IOB being from about 0.00 to about 0.60, for a tetraester of pentaerythritol and a fatty acid, the total number of carbons of the fatty acid composing the tetraester of the pentaerythritol and fatty acid, i.e. the total number of carbons of the R1C, R2C, R3C and R4C portions in formula (1), is preferably about 15 (the IOB is 0.60 when the total number of carbon atoms is 15).
Examples of tetraesters of pentaerythritol and fatty acids include tetraesters of pentaerythritol with hexanoic acid (C6), heptanoic acid (C7), octanoic acid (C8), such as 2-ethylhexanoic acid (C8), nonanoic acid (C9), decanoic acid (C10 and/or dodecanoic acid (C12).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a triester of pentaerythritol and a fatty acid, the total number of carbons of the fatty acid composing the triester of the pentaerythritol and fatty acid, i.e. the total number of carbons of the R1C, R2C and R3C portions in formula (2), is preferably about 19 or greater (the IOB is 0.58 when the number of carbon atoms is 19).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a diester of pentaerythritol and a fatty acid, the total number of carbons of the fatty acid composing the diester of the pentaerythritol and fatty acid, i.e. the total number of carbons of the R1C and R2C portion in formula (3), is preferably about 22 or greater (the IOB is 0.59 when the number of carbon atoms is 22).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a monoester of pentaerythritol and a fatty acid, the total number of carbons of the fatty acid composing the monoester of the pentaerythritol and fatty acid, i.e. the number of carbons of the R1C portion in formula (4), is preferably about 25 or greater (the IOB is 0.60 when the number of carbon atoms is 25).
The effects of double bonds, triple bonds, iso-branches and tert-branches are not considered in this calculation of the IOB (same hereunder).
Commercial products which are esters of pentaerythritol and fatty acids include UNISTAR H-408BRS and H-2408BRS-22 (mixed product) (both products of NOF Corp.).
[(a2) Ester of a Chain Hydrocarbon Triol and at Least One Fatty Acid]
Examples of esters of a chain hydrocarbon triol and at least one fatty acid include triesters of glycerin and fatty acids, represented by formula (5):




diesters of glycerin and fatty acids, represented by the following formula (6):





and monoesters of glycerin and fatty acids, represented by the following formula (7):





(wherein R5-R7 each represent a chain hydrocarbon).

The fatty acid composing the ester of glycerin and a fatty acid (R5COOH, R6COOH and R7COOH) is not particularly restricted so long as the ester of glycerin and a fatty acid satisfies the conditions for the kinematic viscosity, water holding percentage and weight-average molecular weight, and for example, there may be mentioned the fatty acids mentioned for the “(a1) Ester of chain hydrocarbon tetraol and at least one fatty acid”, namely saturated fatty acids and unsaturated fatty acids, and in consideration of the potential for degradation by oxidation and the like, the ester is preferably a glycerin and fatty acid ester derived from a saturated fatty acid, or in other words, an ester of glycerin and a saturated fatty acid.
Also, from the viewpoint of lowering the water holding percentage value, the ester of glycerin and a fatty acid is preferably a diester or triester, and more preferably a triester.
A triester of glycerin and a fatty acid is also known as a triglyceride, and examples include triesters of glycerin and octanoic acid (C8), triesters of glycerin and decanoic acid (C10), triesters of glycerin and dodecanoic acid (C12), triesters of glycerin and 2 or more different fatty acids, and mixtures of the foregoing.
Examples of triesters of glycerin and 2 or more fatty acids include triesters of glycerin with octanoic acid (C8) and decanoic acid (C10), triesters of glycerin with octanoic acid (C8), decanoic acid (C10) and dodecanoic acid (C12), and triesters of glycerin with octanoic acid (C8), decanoic acid (C10), dodecanoic acid (C12), tetradecanoic acid (C14), hexadecanoic acid (C16) and octadecanoic acid (C18).
Considered from the viewpoint of obtaining a melting point of no higher than about 45° C., the triester of glycerin and a fatty acid preferably has a total number of carbon atoms in the fatty acid composing the triester of glycerin and a fatty acid, i.e. a total number of carbons in the R5C, R6C and R7C portions in formula (5), of about 40 or less.
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a triester of glycerin and a fatty acid, the total number of carbons of the fatty acid composing the triester of the glycerin and fatty acid, i.e. the total number of carbons of the R5C, R6C and R7C portions in formula (5), is preferably about 12 or greater (the IOB is 0.60 when the total number of carbon atoms is 12).
Triesters of glycerin and fatty acids, being aliphatic and therefore potential constituent components of the human body, are preferred from the viewpoint of safety.
Commercial products of triesters of glycerin and fatty acids include tri-coconut fatty acid glycerides, NA36, PANACET 800, PANACET 800B and PANACET 810S, and tri-C2L oil fatty acid glycerides and tri-CL oil fatty acid glycerides (all products of NOF Corp.).
A diester of glycerin and a fatty acid is also known as a diglyceride, and examples include diesters of glycerin and decanoic acid (C10), diesters of glycerin and dodecanoic acid (C12), diesters of glycerin and hexadecanoic acid (C16), diesters of glycerin and 2 or more different fatty acids, and mixtures of the foregoing.
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a diester of glycerin and a fatty acid, the total number of carbons of the fatty acid composing the diester of the glycerin and fatty acid, i.e. the total number of carbons of the R5C and R6C portions in formula (6), is preferably about 16 or greater (the IOB is 0.58 when the total number of carbon atoms is 16).
Monoesters of glycerin and fatty acids are also known as monoglycerides, and examples include glycerin and octadecanoic acid (C18) monoester, and glycerin and docosanoic acid (C22) monoester.
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a monoester of glycerin and a fatty acid, the total number of carbons of the fatty acid composing the monoester of the glycerin and fatty acid, i.e. the number of carbons of the R5C portion in formula (7), is preferably about 19 or greater (the IOB is 0.59 when the number of carbon atoms is 19).
[(a3) Ester of a Chain Hydrocarbon Diol and at Least One Fatty Acid]
Examples of esters of a chain hydrocarbon diol and at least one fatty acid include monoesters and diesters of fatty acids with C2-C8 chain hydrocarbon diols, such as C2-C6 glycols, including ethylene glycol, propylene glycol, butylene glycol, pentylene glycol and hexylene glycol.
Specifically, examples of esters of a chain hydrocarbon diol and at least one fatty acid include diesters of C2-C6 glycols and fatty acids, represented by the following formula (8):

R8COOCkH2kOCOR9  (8)

(wherein k represents an integer of 2 to 6, and R8 and R9 each represent a chain hydrocarbon), and monoesters of C2-C6 glycols and fatty acids, represented by the following formula (9):

R8COOCkH2kOH  (9)

(wherein k represents an integer of 2 to 6, and R8 is a chain hydrocarbon).

The fatty acid to be esterified in an ester of a C2-C6 glycol and a fatty acid (corresponding to R8COOH and R9COOH in formula (8) and formula (9)) is not particularly restricted so long as the ester of the C2-C6 glycol and fatty acid satisfies the conditions for the kinematic viscosity, water, holding percentage and weight-average molecular weight, and for example, there may be mentioned the fatty acids mentioned above for the “(a1) Ester of chain hydrocarbon tetraol and at least one fatty acid”, namely saturated fatty acids and unsaturated fatty acids, and in consideration of the potential for degradation by oxidation and the like, it is preferably a saturated fatty acid.
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a diester of butylene glycol represented by formula (8) (k=4) and a fatty acid, the total number of carbons of the R8C and R9C portions is preferably about 6 or greater (the IOB is 0.60 when the total number of carbon atoms is 6).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a monoester of ethylene glycol represented by formula (9) (k=2) and a fatty acid, the number of carbons of the R8C portion is preferably about 12 or greater (the IOB is 0.57 when the number of carbon atoms is 12).
Considering the potential for degradation by oxidation and the like, the ester of the C2-C6 glycol and fatty acid is preferably a C2-C6 glycol and fatty acid ester derived from a saturated fatty acid, or in other words, an ester of a C2-C6 glycol and a saturated fatty acid.
Also, from the viewpoint of lowering the water holding percentage value, the ester of the C2-C6 glycol and fatty acid is preferably a glycol and fatty acid ester derived from a glycol with a greater number of carbons, such as an ester of a glycol and a fatty acid derived from butylene glycol, pentylene glycol or hexylene glycol.
Also, from the viewpoint of lowering the water holding percentage value, the ester of a C2-C6 glycol and fatty acid is preferably a diester.
Examples of commercial products of esters of C2-C6 glycols and fatty acids include COMPOL BL and COMPOL BS (both products of NOF Corp.).
[(B) Ether of (B1) a Compound Having a Chain Hydrocarbon Moiety and 2-4 Hydroxyl Groups Substituting Hydrogens on the Chain Hydrocarbon Moiety and (B2) a Compound Having a Chain Hydrocarbon Moiety and 1 Hydroxyl Group Substituting a Hydrogen on the Chain Hydrocarbon Moiety]
The (B) ether of (B1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety and (B2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety (hereunder also referred to as “compound (B)”) does not need to have all of the hydroxyl groups etherified, so long as it has the aforementioned kinematic viscosity, water holding percentage and weight-average molecular weight.
The (B1) compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting at hydrogens of the chain hydrocarbon moiety (hereunder also referred to as “compound (B1)”), may be pentaerythritol, glycerin or glycol, for example, mentioned as compound (A1) for “compound (A)”.
The (B2) compound having a chain hydrocarbon moiety and one hydroxyl group substituting at a hydrogen of the chain hydrocarbon moiety (hereunder also referred to as “compound (B2)”) may be, for example, a compound in which one hydrogen of the hydrocarbon is substituted with one hydroxyl group (—OH), such as an aliphatic monohydric alcohol, which may be a saturated aliphatic monohydric alcohol or an unsaturated aliphatic monohydric alcohol.
Examples of saturated aliphatic monohydric alcohols include C1-C20 saturated aliphatic monohydric alcohols, such as methyl alcohol (C1) (C1 representing the number of carbon atoms, same hereunder), ethyl alcohol (C2), propyl alcohol (C3) and its isomers, including isopropyl alcohol (C3), butyl alcohol (C4) and its isomers, including sec-butyl alcohol (C4) and tert-butyl alcohol (C4), pentyl alcohol (C5), hexyl alcohol (C6), heptyl alcohol (C7), octyl alcohol (C8) and its isomers, including 2-ethylhexyl alcohol (C8), nonyl alcohol (C9), decyl alcohol (C10), dodecyl alcohol (C12), tetradecyl alcohol (C14), hexadecyl alcohol (C16), heptadecyl alcohol (C17), octadecyl alcohol (C18) and eicosyl alcohol (C20), as well as their isomers other than those mentioned.
Unsaturated aliphatic monohydric alcohols include those wherein one C—C single bond of a saturated aliphatic monohydric alcohol mentioned above is replaced with a C═C double bond, such as oleyl alcohol, and for example, such alcohols are commercially available by New Japan Chemical Co., Ltd. as the RIKACOL Series and UNJECOL Series.
Examples for compound (B) include (b1) ethers of a chain hydrocarbon tetraol and at least one aliphatic monohydric alcohol, such as monoethers, diethers, triethers and tetraethers, preferably diethers, triethers and tetraethers, more preferably triethers and tetraethers and even more preferably tetraethers, (b2) ethers of a chain hydrocarbon triol and at least one aliphatic monohydric alcohol, such as monoethers, diethers and triethers, preferably diethers and triethers and more preferably triethers, and (b3) ethers of a chain hydrocarbon diol and at least one aliphatic monohydric alcohol, such as monoethers and diethers, and preferably diethers.
Examples of ethers of a chain hydrocarbon tetraol and at least one aliphatic monohydric alcohol include tetraethers, triethers, diethers and monoethers of pentaerythritol and aliphatic monohydric alcohols, represented by the following formulas (10) to (13):




(wherein R10-R13 each represent a chain hydrocarbon).

Examples of ethers of a chain hydrocarbon triol and at least one aliphatic monohydric alcohol include triethers, diethers and monoethers of glycerin and aliphatic monohydric alcohols, represented by the following formulas (14) to (16):




(wherein R14-R16 each represent a chain hydrocarbon).

Ethers of a chain hydrocarbon diol and at least one aliphatic monohydric alcohol include diethers of C2-C6 glycols and aliphatic monohydric alcohols, represented by the following formula (17):

R17OCnH2nOR18  (17)

(wherein n is an integer of 2 to 6, and R17 and Rn are each a chain hydrocarbon),

and monoethers of C2-C6 glycols and aliphatic monohydric alcohols, represented by the following formula (18):

R17OCnH2nOH  (18)

(wherein n is an integer of 2 to 6, and R17 is a chain hydrocarbon).

From the viewpoint of the IOB being between about 0.00 and about 0.60, in a tetraether of pentaerythritol and an aliphatic monohydric alcohol, the total number of carbon atoms of the aliphatic monohydric alcohol composing the tetraether of pentaerythritol and the aliphatic monohydric alcohol, i.e. the total number of carbon atoms of the R10, R11, R12 and R13 portions in formula (10), is preferably about 4 or greater (the IOB is 0.44 when the total number of carbon atoms is 4).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a triether of pentaerythritol and an aliphatic monohydric alcohol, the total number of carbon atoms of the aliphatic monohydric alcohol composing the triether of pentaerythritol and the aliphatic monohydric alcohol, i.e. the total number of carbon atoms of the R10, R11 and R12 portions in formula (11), is preferably about 9 or greater (the IOB is 0.57 when the total number of carbon atoms is 9).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a diether of pentaerythritol and an aliphatic monohydric alcohol, the total number of carbon atoms of the aliphatic monohydric alcohol composing the diether of pentaerythritol and the aliphatic monohydric alcohol, i.e. the total number of carbon atoms of the R10 and R11 portions in formula (12), is preferably about 15 or greater (the IOB is 0.60 when the total number of carbon atoms is 15).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a monoether of pentaerythritol and an aliphatic monohydric alcohol, the number of carbon atoms of the aliphatic monohydric alcohol composing the monoether of pentaerythritol and the aliphatic monohydric alcohol, i.e. the number of carbon atoms of the R10 portion in formula (13), is preferably about 22 or greater (the IOB is 0.59 when the number of carbon atoms is 22).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a triether of glycerin and an aliphatic monohydric alcohol, the total number of carbon atoms of the aliphatic monohydric alcohol composing the triether of glycerin and the aliphatic monohydric alcohol, i.e. the total number of carbon atoms of the R14, R15 and R16 portions in formula (14), is preferably about 3 or greater (the IOB is 0.50 when the total number of carbon atoms is 3).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a diether of glycerin and an aliphatic monohydric alcohol, the total number of carbon atoms of the aliphatic monohydric alcohol composing the diether of glycerin and the aliphatic monohydric alcohol, i.e. the total number of carbon atoms of the R14 and R′5 portions in formula (15), is preferably about 9 or greater (the IOB is 0.58 when the total number of carbon atoms is 9).
From the viewpoint of the IOB being between about 0.00 and about 0.60, in a monoether of glycerin and an aliphatic monohydric alcohol, the number of carbon atoms of the aliphatic monohydric alcohol composing the monoether of glycerin and the aliphatic monohydric alcohol, i.e. the number of carbon atoms of the R14 portion in formula (16), is preferably 16 or greater (the IOB is 0.58 when the number of carbon atoms is 16).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a diether of butylene glycol represented by formula (17) (n=4) and an aliphatic monohydric alcohol, the total number of carbon atoms of the R17 and R18 portions is preferably about 2 or greater (the IOB is 0.33 when the total number of carbon atoms is 2).
From the viewpoint of the IOB being from about 0.00 to about 0.60, in a monoether of ethylene glycol represented by formula (18) (n=2) and an aliphatic monohydric alcohol, the number of carbon atoms of the R17 portion is preferably about 8 or greater (the IOB is 0.60 when the number of carbon atoms is 8).
Compound (B) can be produced by dehydrating condensation of compound (B1) and compound (B2) in the presence of an acid catalyst.
[(C) Ester of (C1) a Carboxylic Acid, Hydroxy Acid, Alkoxy Acid or Oxoacid Comprising a Chain Hydrocarbon Moiety and 2-4 Carboxyl Groups Substituting Hydrogens on the Chain Hydrocarbon Moiety and (C2) a Compound Having a Chain Hydrocarbon Moiety and 1 Hydroxyl Group Substituting a Hydrogen on the Chain Hydrocarbon Moiety]
The (C) ester of (C1) a carboxylic acid, hydroxy acid, alkoxy acid or oxoacid comprising a chain hydrocarbon moiety and 2-4 carboxyl groups substituting hydrogens on the chain hydrocarbon moiety and (C2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety (hereunder also referred to as “compound (C)”) does not need to have all of the carboxyl groups esterified so long as it has the aforementioned kinematic viscosity, water holding percentage and weight-average molecular weight.
Examples for the (C1) carboxylic acid, hydroxy acid, alkoxy acid or oxoacid including a chain hydrocarbon moiety and 2-4 carboxyl groups substituting hydrogens of the chain hydrocarbon moiety (hereunder also referred to as “compound (C1)”) include chain hydrocarbon carboxylic acids with 2-4 carboxyl groups, for example, chain hydrocarbon dicarboxylic acids, which include alkanedicarboxylic acids, such as ethanedioic acid, propanedioic acid, butanedioic acid, pentanedioic acid, hexanedioic acid, heptanedioic acid, octanedioic acid, nonanedioic acid and decanedioic acid, chain hydrocarbon tricarboxylic acids, which include alkanetricarboxylic acids, such as propanetrioic acid, butanetrioic acid, pentanetrioic acid, hexanetrioic acid, heptanetrioic acid, octanetrioic acid, nonanetrioic acid and decanetrioic acid, and chain hydrocarbon tetracarboxylic acids, which include alkanetetracarboxylic acids, such as butanetetraoic acid, pentanetetraoic acid, hexanetetraoic acid, heptanetetraoic acid, octanetetraoic acid, nonanetetraoic acid and decanetetraoic acid.
Also, compound (C1) includes chain hydrocarbon hydroxy acids with 2-4 carboxyl groups, for example, chain hydrocarbon alkoxy acids with 2-4 carboxyl groups, such as malic acid, tartaric acid, citric acid and isocitric acid, and O-acetylcitric acid or chain hydrocarbon oxoacids with 2-4 carboxyl groups.
The (C2) compound with a chain hydrocarbon moiety and one hydroxyl group substituting at a hydrogen of the chain hydrocarbon moiety may be any of those mentioned for “compound (B)”, such as an aliphatic monohydric alcohol.
Compound (C) may be (c1) an ester, for example a monoester, diester, triester or tetraester, preferably a diester, triester or tetraester, more preferably a triester or tetraester and even more preferably a tetraester, of a chain hydrocarbon tetracarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 4 carboxyl groups, and at least one aliphatic monohydric alcohol, (c2) an ester, for example, a monoester, diester or triester, preferably a diester or triester and more preferably a triester, of a chain hydrocarbon tricarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 3 carboxyl groups, and at least one aliphatic monohydric alcohol, or (c3) an ester, for example, a monoester or diester, and preferably a diester, of a chain hydrocarbon dicarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 2 carboxyl groups, and at least one aliphatic monohydric alcohol.
Examples for compound (C) include dioctyl adipate and tributyl O-acetylcitrate, of which commercially available products exist.
[(D) Compound Having a Chain Hydrocarbon Moiety and One Bond Selected from the Group Consisting of an Ether Bond (—O—), Carbonyl Bond (—CO—), Ester Bond (—COO—) and Carbonate Bond (—OCOO—) Inserted Between a C—C Single Bond of the Chain Hydrocarbon Moiety]
The (D) compound having a chain hydrocarbon moiety and one bond selected from the group consisting of an ether bond (—O—), carbonyl bond (—CO—), ester bond (—COO—) and carbonate bond (—OCOO—) inserted between a C—C single bond of the chain hydrocarbon moiety (hereunder also referred to as “compound (D)”) may be (d1) an ether of an aliphatic monohydric alcohol and an aliphatic monohydric alcohol, (d2) a dialkyl ketone, (d3) an ester of a fatty acid and an aliphatic monohydric alcohol, or (d4) a dialkyl carbonate.
[(d1) Ether of an Aliphatic Monohydric Alcohol and an Aliphatic Monohydric Alcohol]
Ethers of aliphatic monohydric alcohols and aliphatic monohydric alcohols include compounds having the following formula (19):

R19OR20  (19)

(wherein R19 and R20 each represent a chain hydrocarbon).

The aliphatic monohydric alcohol composing the ether (corresponding to R19OH and R20 OH in formula (19)) is not particularly restricted so long as the ether satisfies the conditions for the kinematic viscosity, water holding percentage and weight-average molecular weight, and for example, it may be one of the aliphatic monohydric alcohols mentioned for “compound (B)”.
[(d2) Dialkyl Ketone]
The dialkyl ketone may be a compound of the following formula (20):

R21COR22  (20)

(wherein R21 and R22 are each an alkyl group).

The dialkyl ketone may be a commercially available product, or it may be obtained by a known method, such as by oxidation of a secondary alcohol with chromic acid or the like.
[(d3) Ester of a Fatty Acid and an Aliphatic Monohydric Alcohol]
Examples of esters of fatty acids and aliphatic monohydric alcohols include compounds having the following formula (21):

R23COOR24  (21)

(wherein R23 and R24 each represent a chain hydrocarbon).

Examples of fatty acids composing esters (corresponding to R23COOH in formula (21)) include the fatty acids mentioned for the “(a1) esters of chain hydrocarbon tetraols and fatty acids”, and specifically these include saturated fatty acids and unsaturated fatty acids, with saturated fatty acids being preferred in consideration of the potential for degradation by oxidation and the like. The aliphatic monohydric alcohol composing the ester (corresponding to R24OH in formula (21)) may be one of the aliphatic monohydric alcohols mentioned for “compound (B)”.
Examples of esters of such fatty acids and aliphatic monohydric alcohols include esters of dodecanoic acid (C12) and dodecyl alcohol (C12) and esters of tetradecanoic acid (C14) and dodecyl alcohol (C12), and examples of commercial products of esters of such fatty acids and aliphatic monohydric alcohols include ELECTOL WE20 and ELECTOL WE40 (both products of NOF Corp.).
[(d4) Dialkyl Carbonate]
The dialkyl carbonate may be a compound of the following formula (22):

R25OC(═O)OR26  (22)

(wherein R25 and R26 are each an alkyl group).

The dialkyl carbonate may be a commercially available product, or it may be synthesized by reaction between phosgene and an alcohol, reaction between formate chloride ester and an alcohol or alcoholate, or reaction between silver carbonate and an alkyl iodide.
From the viewpoint of the water holding percentage and vapor pressure, the weight-average molecular weight is preferably about 100 or greater and more preferably about 200 or greater, for (d1) an ether of an aliphatic monohydric alcohol and an aliphatic monohydric alcohol, (d2) a dialkyl ketone, (d3) an ester of a fatty acid and an aliphatic monohydric alcohol, and (d4) a dialkyl carbonate.
If the total number of carbon atoms is about 8 in a (d2) dialkyl ketone, the melting point will be approximately −50° C. and the vapor pressure will be about 230 Pa at 20° C., in the case of 5-nonanone, for example.
[(E) Polyoxy C3-C6 Alkylene Glycol, or Alkyl Ester or Alkyl Ether Thereof]
The (E) polyoxy C3-C6 alkylene glycol, or its alkyl ester or alkyl ether (hereunder also referred to as “compound (E)”) may be (e1) a polyoxy C3-C6 alkylene glycol, (e2) an ester of a polyoxy C3-C6 alkylene glycol and at least one fatty acid, or (e3) an ether of a polyoxy C3-C6 alkylene glycol and at least one aliphatic monohydric alcohol. These will now be explained.
[(e1) Polyoxy C3-C6 Alkylene Glycol]
The polyoxy C3-C6 alkylene glycol is i) a homopolymer having one backbone selected from the group consisting of oxy C3-C6 alkylene backbones, i.e. oxyethylene backbone, oxypropylene backbone, oxybutylene backbone, oxypentylene backbone and oxyhexylene backbone, and having hydroxy groups at both ends, ii) a block copolymer having a backbone of two or more selected from among the aforementioned group and having hydroxy groups at both ends, or iii) a random copolymer having a backbone of two or more selected from among the aforementioned group and having hydroxy groups at both ends.
A polyoxy C3-C6 alkylene glycol is represented by the following formula (23):

HO—(CmH2mO)n—H  (23)

(wherein m is an integer of 3-6).

The present inventors have found that with polypropylene glycol (corresponding to a homopolymer of formula (23) where m=3), the condition for the water holding percentage is not satisfied when the weight-average molecular weight is less than about 1,000. Therefore, polypropylene glycol homopolymer is not included in the scope of the blood slipping agent described above, and propylene glycol should be included in the (e1) polyoxy C3-C6 alkylene glycol only as a copolymer or random polymer with another glycol.
Incidentally, investigation by the present inventors suggests that with polyethylene glycol (corresponding to a homopolymer of formula (23) where m=2), the condition for the kinematic viscosity and water holding percentage cannot be satisfied when the weight-average molecular weight is less than about 1,000.
From the viewpoint of the IOB being about 0.00 to about 0.60, when formula (23) is polybutylene glycol (a homopolymer where m=4), for example, preferably n about 7 (when n 7, the IOB is 0.57).
Examples of commercial products of poly C3-C6 alkylene glycols include UNIOLTM PB-500 and PB-700 (all products of NOF Corp.).
[(e2) Ester of a Polyoxy C3-C6 Alkylene Glycol and at Least One Fatty Acid]
The ester of a polyoxy C3-C6 alkylene glycol and at least one fatty acid may be one wherein one or both of the OH ends of a polyoxy C3-C6 alkylene glycol mentioned above under “(e1) Polyoxy C3-C6 alkylene glycol” are esterified by a fatty acid, i.e. a monoester or a diester.
Examples of fatty acids to be esterified in the ester of a polyoxy C3-C6 alkylene glycol and at least one fatty acid include the fatty acids mentioned above under “(a1) Ester of chain hydrocarbon tetraol and at least one fatty acid”, and specifically these include saturated fatty acids and unsaturated fatty acids, with saturated fatty acids being preferred in consideration of the potential for degradation by oxidation and the like.
[(e3) Ether of a Polyoxy C3-C6 Alkylene Glycol and at Least One Aliphatic Monohydric Alcohol]
The ether of a polyoxy C3-C6 alkylene glycol and at least one aliphatic monohydric alcohol may be one wherein one or both of the OH ends of a polyoxy C3-C6 alkylene glycol mentioned above under “(e1) Polyoxy C3-C6 alkylene glycol” are etherified by an aliphatic monohydric alcohol, i.e. a monoether or diether.
In an ether of a polyoxy C3-C6 alkylene glycol and at least one aliphatic monohydric alcohol, the aliphatic monohydric alcohol to be etherified may be an aliphatic monohydric alcohol among those mentioned for “compound (B)”.
[(F) Chain Hydrocarbon]
Examples of chain hydrocarbons include (f1) chain alkanes, such as straight-chain alkanes and branched chain alkanes. Straight-chain alkanes with melting points of no higher than about 45° C. have up to about 22 carbon atoms, and at a vapor pressure of 1 atmosphere and about 0.01 Pa or less at 25° C., the number of carbon atoms is 13 or greater. Branched chain alkanes tend to have lower melting points than straight-chain alkanes, given the same number of carbon atoms. Branched chain alkanes may therefore include those with 22 and more carbon atoms, even with melting points of below about 45° C.
Examples of commercially available hydrocarbon products include PARLEAM 6 (NOF Corp.).
At least the projections 8 of the excretory opening contact region 20 may be coated with the blood slipping agent alone, or with a blood slipping agent-containing composition comprising the blood slipping agent and at least one other component.
Such a blood slipping agent-containing composition will now be described. Coating of the blood slipping agent-containing composition is the same as coating of the blood slipping agent, and explanation thereof will therefore be omitted.
[Blood Slipping Agent-Containing Composition]
The blood slipping agent-containing composition contains the aforementioned blood slipping agent and at least one other component. The other component is not particularly restricted so long as it does not inhibit the function and effect of the blood slipping agent, and it may be any one commonly employed in absorbent articles of the art, and especially top sheets.
Examples for the other component(s) include silicone oils, silicones, silicone-based resins and the like.
Examples for the other component(s) also include antioxidants, such as BHT (2,6-di-t-butyl-p-cresol), BHA (butylated hydroxyanisole) and propyl gallate.
Further examples for the other component(s) include vitamins, such as natural vitamins and synthetic vitamins. Examples of vitamins include water-soluble vitamins, such as group B vitamins, including B1, vitamin B2, vitamin B3, vitamin B5, vitamin B6, vitamin B7, vitamin B9 and vitamin B12, and vitamin C.
Other examples of vitamins include fat-soluble vitamins, such as group A vitamins, group D vitamins, group E vitamins and group K vitamins. The derivatives of these vitamins are also included.
Examples for the other component(s) include amino acids, such as alanine, arginine, lysine, histidine, proline and hydroxyproline, and peptides.
Other examples for the other component(s) include zeolite, such as natural zeolite, examples of which include analcite, chabazite, heulandite, natrolite, stilbite and thomosonite, and synthetic zeolite.
Still other examples for the other component(s) include cholesterol, hyaluronic acid, lecithin and ceramide.
Yet other examples for the other component(s) include drugs, such as skin astringents, anti-pimple medications, anti-wrinkle agents, anti-cellulite agents, skin whiteners, antimicrobial agents and antifungal agents.
Examples of skin astringents include zinc oxide, aluminum sulfate, tannic acid and the like, and oil-soluble skin astringents, such as fat-soluble polyphenols. Fat-soluble polyphenols include natural fat-soluble polyphenols, such as barley extract, otogiriso extract, white deadnettle extract, chamomilla extract, burdock extract, salvia extract, linden extract, common lime extract, white birch extract, common horsetail extract, sage extract, salvia extract, walnut (J. regia L. var. orientalis) extract, hibiscus extract, loquat leaf extract, Miquel's linden extract, hop extract, common horse-chestnut extract and coix seed extract.
Examples of anti-pimple medications include salicylic acid, benzoyl peroxide, resorcinol, sulfur, erythromycin and zinc.
Examples of anti-wrinkle agents include lactic acid, salicylic acid, salicylic acid derivatives, glycolic acid, phytic acid, lipoic acid and lysophosphatidic acid.
Examples of anti-cellulite agents include xanthine compounds, such as aminophylline, caffeine, theophylline and theobromine.
Examples of skin whiteners include niacinamide, kojic acid, arbutin, glucosamine and its derivatives, phytosterol derivatives, and ascorbic acid and its derivatives, as well as mulberry extract and placenta extract.
Examples for the other component(s) also include anti-inflammatory components, pH regulators, antimicrobial agents, humectants, aromatics, pigments, dyes, pigments and plant extracts.
Examples of anti-inflammatory components include naturally-derived anti-inflammatory drugs, such as peony, golden grass, otogiriso, chamomile, licorice, peach leaf, Japanese mugwort and perilla extract, and synthetic anti-inflammatory drugs, such as allantoin and dipotassium glycyrrhizinate.
Examples of pH regulators include those that keep the skin weakly acidic, such as malic acid, succinic acid, citric acid, tartaric acid and lactic acid.
Titanium oxide is an example of a pigment.
The blood slipping agent-containing composition contains the blood slipping agent and the one or more other components at preferably about 50 to about 99 mass % and about 1 to about 50 mass %, respectively, more preferably about 60 to about 99 mass % and about 1 to about 40 mass %, respectively, even more preferably about 70 to about 99 mass % and about 1 to about 30 mass %, respectively, yet more preferably about 80 to about 99 mass % and about 1 to about 20 mass %, respectively, even yet more preferably about 90 to 99 mass % and about 1 to about 10 mass %, respectively, and even yet more preferably about 95 to 99 mass % and about 1 to about 5 mass %, respectively. This is from the viewpoint of the functions and effects of the blood slipping agent and the other components.
The blood slipping agent-containing composition preferably contains a surfactant in not greater than the amount from hydrophilicizing treatment of the top sheet or second sheet. More specifically, the blood slipping agent-containing composition contains a surfactant in a basis weight range of preferably about 0.0 to about 1.0 g/m2, more preferably about 0.0 to about 0.8 g/m2, even more preferably about 0.1 to about 0.5 g/m2, and yet more preferably about 0.1 to about 0.3 g/m2.
This is because when the amount of surfactant is increased, menstrual blood will tend to be retained in the top sheet. The surfactant, incidentally, has no water holding percentage. This is because there is no layer of the substance to be measured due to its mixture with water.
The blood slipping agent-containing composition contains water in a basis weight range of preferably about 0.0 to about 1.0 g/m2, more preferably about 0.0 to about 0.8 g/m2, even more preferably about 0.1 to about 0.5 g/m2, and yet more preferably about 0.1 to about 0.3 g/m2. Since water lowers the absorption performance of the absorbent article, the amount is preferably low.
Similar to the blood slipping agent, the blood slipping agent-containing composition, as a composition, has at 40° C., a kinematic viscosity of preferably about 0 to about 80 mm2/s, more preferably a kinematic viscosity of about 1 to about 70 mm2/s, even more preferably a kinematic viscosity of about 3 to about 60 mm2/s, yet more preferably a kinematic viscosity of about 5 to about 50 mm2/s, and even yet more preferably a kinematic viscosity of about 7 to about 45 mm2/s.
If the kinematic viscosity of the blood slipping agent-containing composition exceeds 80 mm2/s, the viscosity will increase and the blood slipping agent composition may not slide down into the interior of the absorbent article as easily with menstrual blood that has reached the skin contact surface of the top sheet.
When the blood slipping agent-containing composition contains a component that is miscible with the blood slipping agent, as at least one other component, the other component preferably has a weight-average molecular weight of less than about 1,000, and more preferably a weight-average molecular weight of less than about 900. This is because, if the weight-average molecular weight is about 1,000 or higher, tack may result in the blood slipping agent-containing composition itself, tending to create a feeling of discomfort for the wearer. If the weight-average molecular weight increases, the viscosity of the blood slipping agent-containing composition will tend to increase, and it will therefore be difficult to lower the viscosity of the blood slipping agent composition by heating to a viscosity suitable for coating, and as a result, the blood slipping agent may need to be diluted with a solvent.
The blood slipping agent-containing composition, as a composition, has a water holding percentage of about 0.01 to about 4.0 mass %, preferably it has a water holding percentage of about 0.02 to about 3.5 mass %, more preferably it has a water holding percentage of about 0.03 to about 3.0 mass %, even more preferably it has a water holding percentage of about 0.04 to about 2.5 mass %, and yet more preferably it has a water holding percentage of about 0.05 to about 2.0 mass %.
A low water holding percentage value will tend to lower the affinity between the blood slipping agent composition and menstrual blood, thus inhibiting it from sliding down into the interior of the absorbent article with menstrual blood that has reached the skin contact surface of the top sheet.
When the blood slipping agent-containing composition contains solid matter, it is preferably removed by filtration for measurement of the kinematic viscosity and water holding percentage.
EXAMPLES
Test Example 1
The blood slipping agents used for the test examples are listed below.
[(a1) Ester of a Chain Hydrocarbon Tetraol and at Least One Fatty Acid]
UNISTAR H-408BRS, product of NOF Corp.
Pentaerythritol tetra(2-ethylhexanoate), weight-average molecular weight: approximately 640
UNISTAR H-2408BRS-22, product of NOF Corp.
Mixture of pentaerythritol tetra(2-ethylhexanoate) and neopentylglycol di(2-ethylhexanoate) (58:42 as weight ratio), weight-average molecular weight: approximately 520
[(a2) Ester of a Chain Hydrocarbon Triol and at Least One Fatty Acid]
Cetiol SB45DEO, Cognis Japan
Glycerin and fatty acid triester, with oleic acid or stearylic acid as the fatty acid.
SOY42, product of NOF Corp.
Glycerin and fatty acid triester with C14 fatty acid:C16 fatty acid:C18 fatty acid:C20 fatty acid (including both saturated fatty acids and unsaturated fatty acids) at a mass ratio of about 0.2:11:88:0.8, weight-average molecular weight: 880
Tri-C2L oil fatty acid glyceride, product of NOF Corp.
Glycerin and fatty acid triester with C8 fatty acid:C10 fatty acid:C12 fatty acid at a weight ratio of about 37:7:56, weight-average molecular weight: approximately 570
Tri-CL oil fatty acid glyceride, product of NOF Corp.
Glycerin and fatty acid triester with C8 fatty acid:C12 fatty acid at a weight ratio of about 44:56, weight-average molecular weight: approximately 570
PANACET 810s, product of NOF Corp.
Glycerin and fatty acid triester with C8 fatty acid:C10 fatty acid at a weight ratio of about 85:15, weight-average molecular weight: approximately 480
PANACET 800, product of NOF Corp.
Glycerin and fatty acid triester with octanoic acid (C8) as the entire fatty acid portion, weight-average molecular weight: approximately 470
PANACET 800B, product of NOF Corp.
Glycerin and fatty acid triester with 2-ethylhexanoic acid (C8) as the entire fatty acid portion, weight-average molecular weight: approximately 470
NA36, product of NOF Corp.
Glycerin and fatty acid triester with C16 fatty acid:C18 fatty acid:C20 fatty acid (including both saturated fatty acids and unsaturated fatty acids) at a weight ratio of about 5:92:3, weight-average molecular weight: approximately 880
Tri-coconut fatty acid glyceride, product of NOF Corp.
Glycerin and fatty acid triester with C8 fatty acid:C10 fatty acid: C12 fatty acid:C14 fatty acid:C16 fatty acid (including both saturated fatty acids and unsaturated fatty acids) at a weight ratio of about 4:8:60:25:3, weight-average molecular weight: 670
Caprylic acid diglyceride, product of NOF Corp.
Glycerin and fatty acid diester with octanoic acid as the fatty acid, weight-average molecular weight: approximately 340
[(a3) Ester of a Chain Hydrocarbon Diol and at Least One Fatty Acid]
UNISTAR H-208BRS, product of NOF Corp.
Neopentyl glycol di(2-ethylhexanoate), weight-average molecular weight: approximately 360
COMPOL BL, product of NOF Corp.
Dodecanoic acid (C12) monoester of butylene glycol, weight-average molecular weight: approximately 270
COMPOL BS, product of NOF Corp.
Octadecanoic acid (C18) monoester of butylene glycol, weight-average molecular weight: approximately 350
[(c2) Ester of a Chain Hydrocarbon Tricarboxylic Acid, Hydroxy Acid, Alkoxy Acid or Oxoacid with 3 Carboxyl Groups, and at Least One Aliphatic Monohydric Alcohol]
Tributyl 0-acetylcitrate, product of Tokyo Kasei Kogyo Co., Ltd.
Weight-average molecular weight: approximately 400
Tributyl citrate, product of Tokyo Kasei Kogyo Co., Ltd.
Weight-average molecular weight: approximately 360
[(c3) Ester of a Chain Hydrocarbon Dicarboxylic Acid, Hydroxy Acid, Alkoxy Acid or Oxoacid with 2 Carboxyl Groups, and at Least One Aliphatic Monohydric Alcohol]
Dioctyl adipate, product of Wako Pure Chemical Industries, Ltd.
Weight-average molecular weight: approximately 380
[(d3) Esters of a Fatty Acid and Aliphatic Monohydric Alcohol]
ELECTOL WE20, product of NOF Corp.
Ester of dodecanoic acid (C12) and dodecyl alcohol (C12), weight-average molecular weight: approximately 360
ELECTOL WE40, product of NOF Corp.
Ester of tetradecanoic acid (C14) and dodecyl alcohol (C12), weight-average molecular weight: approximately 390
[(e1) Polyoxy C3-C6 Alkylene Glycol]
UNIOL PB500, product of NOF Corp.
Polybutylene glycol, weight-average molecular weight: approximately 500
UNIOL PB700, product of NOF Corp.
Polyoxybutylene polyoxypropylene glycol, weight-average molecular weight: approximately 700
[(f1) Chain Alkane]
PARLEAM 6, product of NOF Corp.
Branched chain hydrocarbon, produced by copolymerization of liquid isoparaffin, isobutene and n-butene followed by hydrogen addition, polymerization degree: approximately 5-10, weight-average molecular weight: approximately 330
[Other Materials]
NA50, product of NOF Corp.
Glycerin and fatty acid triester obtained by addition of hydrogen to NA36 for reduced proportion of double bonds from unsaturated fatty acid starting material, weight-average molecular weight: approximately 880
(Caprylic acid/capric acid) monoglyceride, product of NOF Corp.
Glycerin and fatty acid monoester, with octanoic acid (C8) and decanoic acid (C10) at a weight ratio of about 85:15, weight-average molecular weight: approximately 220
Monomuls 90-L2 lauric acid monoglyceride, product of Cognis Japan
Isopropyl citrate, product of Tokyo Kasei Kogyo Co., Ltd.
Weight-average molecular weight: approximately 230
Diisostearyl malate
Weight-average molecular weight: approximately 640
UNIOL PB1000R, product of NOF Corp.
Polybutylene glycol, weight-average molecular weight: approximately 1,000
UNIOL D-250, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 250
UNIOL D-400, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 400
UNIOL D-700, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 700
UNIOL D-1000, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 1,000
UNIOL D-1200, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 1,160
UNIOL D-2000, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 2,030
UNIOL D-3000, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 3,000
UNIOL D-4000, product of NOF Corp.
Polypropylene glycol, weight-average molecular weight: approximately 4,000
PEG1500, product of NOF Corp.
Polyethylene glycol, weight-average molecular weight: approximately 1,500-1,600
WILBRITE cp9, product of NOF Corp.
Polybutylene glycol compound with OH groups at both ends esterified by hexadecanoic acid (C16), weight-average molecular weight: approximately 1,150
UNILUBE MS-70K, product of NOF Corp.
Stearyl ether of polypropylene glycol, approximately 15 repeating units, weight-average molecular weight: approximately 1,140
NONION S-6, product of NOF Corp.
Polyoxyethylene monostearate, approximately 7 repeating units, weight-average molecular weight: approximately 880
UNILUBE 5TP-300 KB
Polyoxyethylene polyoxypropylene pentaerythritol ether, produced by addition of 5 mol of ethylene oxide and 65 mol of propylene oxide to 1 mol of pentaerythritol, weight-average molecular weight: 4,130
WILBRITE s753, product of NOF Corp.
Polyoxyethylene polyoxypropylene polyoxybutylene glycerin, weight-average molecular weight: approximately 960
UNIOL TG-330, product of NOF Corp.
Glyceryl ether of polypropylene glycol, approximately 6 repeating units, weight-average molecular weight: approximately 330
UNIOL TG-1000, product of NOF Corp.
Glyceryl ether of polypropylene glycol, approximately 16 repeating units, weight-average molecular weight: approximately 1,000
UNIOL TG-3000, product of NOF Corp.
Glyceryl ether of polypropylene glycol, approximately 16 repeating units, weight-average molecular weight: approximately 3,000
UNIOL TG-4000, product of NOF Corp.
Glyceryl ether of polypropylene glycol, approximately 16 repeating units, weight-average molecular weight: approximately 4,000
UNILUBE DGP-700, product of NOF Corp.
Diglyceryl ether of polypropylene glycol, approximately 9 repeating units, weight-average molecular weight: approximately 700
UNTOX HC60, product of NOF Corp.
Polyoxyethylene hydrogenated castor oil, weight-average molecular weight: approximately 3,570
Vaseline, product of Cognis Japan
Petroleum-derived hydrocarbon, semi-solid
Test Example 2
[Menstrual Blood Surface Residue Rate A, with Absorption of Large Amount of Blood]
A test was conducted to evaluate the absorption property of a sanitary napkin after one-time absorption of a large amount of blood.
There were prepared a top sheet, formed of a hydrophilic agent-treated air-through nonwoven fabric (composite fiber composed of polyester and polyethylene terephthalate, basis weight: 35 g/m2), a second sheet, formed of an air-through nonwoven fabric (composite fiber composed of polyester and polyethylene terephthalate, basis weight: 30 g/m2), an absorbent body comprising pulp (basis weight: 150 to 450 g/m2, increased at the center section), an acrylic super-absorbent polymer (basis weight: 15 g/m2) and tissue as a core wrap, a water-repellent agent-treated side sheet, and a back sheet composed of a polyethylene film.
The top sheet was a top sheet produced by the method described in Japanese Unexamined Patent Publication No. 2008-2034, having a ridge-furrow structure, with a ridge thickness of approximately 1.5 mm and a furrow thickness of approximately 0.4 mm, and the pitch of the ridge-furrow structure (ridge width+furrow width) was approximately 4 mm and open holes were formed in the furrows at an open area of approximately 15%.
UNISTAR H-408BRS (product of NOF Corp., tetraester of pentaerythritol and fatty acid) was selected as the blood slipping agent, and it was coated onto the skin contact surface (ridge-furrow side) of the top sheet from a control seam HMA gun at room temperature, to a basis weight of 5.0 g/m2. With an electron microscope it was confirmed that the H-408BRS was adhering onto the fiber surfaces as fine particulates.
A back sheet, an absorbent body, a second sheet, and a top sheet with the ridge-furrow side facing upward, were stacked in that order to form sanitary napkin No. 1-1.
Sanitary napkins No. 1-2 to No. 1-49 were produced, changing the blood slipping agent from UNISTAR H-408BRS to the ones listed in Table 2. Each blood slipping agent was used directly, when it was liquid at room temperature, or when the blood slipping agent was solid at room temperature it was heated to its melting point of +20° C., and then a control seam HMA gun was used for atomization of the blood slipping agent and coating onto the skin contact surface of the top sheet to a basis weight of about 5 g/m2.
The blood slipping agent was coated onto essentially the entire skin contact surface of the top sheet, and on both the ridges and furrows.
[Test Methods]
After measuring the weight W2 (g) of the top sheet (the weight of the top sheet before the test), an acrylic board with an opened hole (200 mm×100 mm, 125 g, with a 40 mm×10 mm hole opened at the center) was placed on the top sheet, at the center section in the lengthwise direction and widthwise direction of the absorbent article, and 4.0 g of horse EDTA blood at 37±1° C. (obtained by adding ethylenediaminetetraacetic acid (hereunder, “EDTA”) to horse blood to prevent coagulation) was dropped through the hole using a pipette.
After dropping the horse EDTA blood, the acrylic board was immediately removed, the top sheet was taken off, the weight W3 (g) (weight of the top sheet after the test) was measured and the “surface residue rate A (mass %)” was calculated by the following formula.

Surface residue rate A (mass %)=100×[W3 (g)−W2 (g)]/4.0 (g)

The tack on the skin contact surface of the top sheet was measured at 35° C., and evaluated on the following scale.
G: No tack
F: Slight tack
P: Tack
The surface residue rate A and tack of each absorbent article, and the properties of each blood slipping agent, are shown below in Table 2. FIG. 8 is an electron micrograph of the skin contact surface of a top sheet in a sanitary napkin wherein the top sheet comprises tri-C2L oil fatty acid glycerides.















TABLE 2








Water
Weight-


Surface





Kinematic
holding
average

Melting
residue




viscosity
percentage
molecular

point
rate A


No.
Blood slipping agent
(mm2/s, 40° C.)
(mass %)
weight
IOB
(° C.)
(mass %)
Tack























1-1
H-408 BRS
45
0.7
640
0.13
<−5
0.8
G


1-2
H-2408 BRS-22
22
0.8
520
0.18
<−5
0.8
G


1-3
Tri-C2L oil fatty acid glyceride
20
<1.0
570
0.27
37

G


1-4
Tri-CL oil fatty acid glyceride
15
<1.0
570
0.28
38

G


1-5
PANACET810s
 9
0.3
480
0.32
−5
0.8
G


1-6
PANACET800
15
0.5
470
0.33
−5
1.8
G


1-7
PANACET800B
20
<1.0
470
0.33
−5

G


1-8
NA36
40
<1.0
880
0.16
37

G


1-9
Tri-coconut oil fatty acid glyceride
25
<1.0
670
0.28
30

G


1-10
Caprylic acid diglyceride
25
2.7
340
0.58
<45
1.0
G


1-11
UNISTAR H-208BRS
 8
0.7
360
0.24
<−5
0.5
G


1-12
COMPOL BL
10
1.6
270
0.50
2
1.3
G


1-13
COMPOL BS
35
0.3
350
0.36
37
2.5
G


1-14
Tributyl O-acetylcitrate
15
0.9
400
0.60
<45
0.5
G


1-15
Tributyl citrate
12
0.6
360
0.78
<45
1.8
G


1-16
Dioctyl adipate
 7
0.4
380
0.27
<45
1.5
G


1-17
ELECTOL WE20
10
0.3
360
0.13
29
0.5
G


1-18
ELECTOL WE40
15
0.5
390
0.12
37
2.3
G


1-19
UNIOL PB500
40
3.6
500
0.44
<45
2.5
G


1-20
UNIOL PB700
50
2.3
700
0.49
−5
1.3
G


1-21
PARLEAM 6
 5
0.06
330
0.00
−5
2.0
G


1-22
NA50
  80<<
—*
880
0.18
52
4.3
G


1-23
(Caprylic acid/capric acid) monoglyceride
70
4.0<<
220
1.15
<45
5.0
G


1-24
90-L2 lauric acid monoglyceride
  80<<
4.0<<
<1,000
0.87
58
5.0
G


1-25
Isopropyl citrate
120 
4.0<<
230
1.56
<45
4.8
F


1-26
Diisostearyl malate
450 
4.0<<
640
0.28
<45
3.3
F


1-27
UNIOL PB1000R
70
5.5
1000
0.40
<45
2.5
F


1-28
UNIOL D-250
20
4.0<<
250

<45
3.8
G


1-29
UNIOL D-400
30
4.0<<
400
0.76
<45
4.8
G


1-30
UNIOL D-700
50
34.6
700
0.58
<45
4.8
G


1-31
UNIOL D-1000
70
26.7
1,000
0.51
<45
3.8
F


1-32
UNIOL D-1200
90
16.2
1,160
0.48
<45
3.0
F


1-33
UNIOL D-2000
160 

2,030

<45

P


1-34
UNIOL D-3000

0.6
3,000
0.39
<45
3.0
P


1-35
UNIOL D-4000
450 
0.5
4,000
0.38
<45
2.5
P


1-36
PEG 1500
120 
4.0<<
1,500-1,600
0.78
40
5.5
P


1-37
WILBRITE CP9
120 
0.6
1,150
0.21
35
6.8
P


1-38
UNILUBE MS-70K
50
2.8
1,140
0.30
<−10
1.5
F


1-39
NONION S-6
65
4.0<<
880
0.44
37

G


1-40
UNILUBE 5TP-300KB
310 
3.9
4,130
0.39
<45
2.0
P


1-41
WILBRITE s753
120 
27.3
960
0.67
−5
3.5
F


1-42
UNIOL TG-330
30

330
1.27
<45

G


1-43
UNIOL TG-1000
100 
21.2
1,000
0.61
<45
3.5
G


1-44
UNIOL TG-3000
230 
4.3
3,000
0.42
<45
1.0
P


1-45
UNIOL TG-4000
300 
2.4
4,000
0.40
<45
2.0
P


1-46
UNILUBE DGP-700
200 
4.0<<
700
0.91
<0
3.5
F


1-47
UNIOX HC60
1150 

3,570
0.46
33

P


1-48
Vaseline
  80<<
0.0
<1,000
0.00
55
4.0
P


1-49
None
—
—
—
—
—
7.5
G





*High viscosity, unmeasurable.






With sanitary napkin No. 1-49, which had no blood slipping agent, the surface residue rate A was 7.5 mass %, but with sanitary napkins No. 1-1 to No. 1-21 wherein the kinematic viscosity and water holding percentage were within the prescribed ranges, the surface residue rate A was 2.5 mass % or lower.
With sanitary napkins No. 1-1 to No. 1-21, it was observed that the horse EDTA blood that was dropped onto the ridges of the top sheet slid down from the ridges into the furrows, and was rapidly absorbed from the furrows into the absorbent body. However, with sanitary napkin No. 1-49 which had no blood slipping agent, the dropped horse EDTA blood did not slip down into the furrows but slowly dripped down into the furrows, most of it remaining on the ridges of the top sheet. Also, with the absorbent articles with high a water holding percentage, as with No. 1-30, for example, the horse EDTA blood that was dropped onto the ridges of the top sheet did not slip down into the furrows but slowly dripped while partially remaining on the top sheet, and a portion thereof remained on the ridges.
This suggests that sanitary napkins No. 1-1 to No. 1-21 allow rapid migration of menstrual blood from the top sheet into the absorbent body, when a large amount of menstrual blood has reached the top sheet at once.
Next, several volunteer subjects were asked to wear sanitary napkins Nos. 1-1 to 1-49, and most of the obtained responses indicated that with the sanitary napkins comprising blood slipping agents Nos. 1-1 to 1-21, the top sheets had no sticky feel and the top sheets were smooth, even after absorption of menstrual blood.
Test Example 3
[Menstrual Blood Surface Residue Rate B, with Absorption of Small Amount of Blood]
A test was conducted to evaluate the absorption property of a sanitary napkin after absorption of a small amount of blood.
There were prepared a top sheet, formed of a hydrophilic agent-treated air-through nonwoven fabric (composite fiber composed of polyester and polyethylene terephthalate, basis weight: 35 g/m2) (hereunder also referred to as “top sheet with ridge-furrows”), a second sheet formed of an air-through nonwoven fabric (composite fibers composed of polyester and polyethylene terephthalate, basis weight: 30 g/m2), an absorbent body comprising pulp (basis weight: 150 to 450 g/m2, increased at the center section), an acrylic super-absorbent polymer (basis weight: 15 g/m2) and tissue as a core wrap, a water-repellent agent-treated side sheet, and a back sheet composed of a polyethylene film.
The top sheet was a top sheet produced by the method described in Japanese Unexamined Patent Publication No. 2008-2034, having a ridge-furrow structure, with a ridge thickness of approximately 1.5 mm and a furrow thickness of approximately 0.4 mm, and the pitch of the ridge-furrow structure (ridge width+furrow width) was approximately 4 mm and open holes were formed in the furrows at an open area of approximately 15%.
UNISTAR H-408BRS (product of NOF Corp., tetraester of pentaerythritol and fatty acid) was selected as the blood slipping agent, and it was coated onto the skin contact surface (ridge-furrow side) of the top sheet from a control seam HMA gun at room temperature, to a basis weight of 5.0 g/m2. With an electron microscope it was confirmed that the H-408BRS was adhering onto the fiber surfaces as fine particulates.
A back sheet, an absorbent body, a second sheet, and a top sheet with the ridge-furrow side facing upward, were stacked in that order to form sanitary napkin No. 2-1(i).
A sanitary napkin No. 2-1(ii) was formed in the same manner as the sanitary napkin No. 2-1(i), except that the top sheet was changed to a top sheet formed of a flat hydrophilic agent-treated air-through nonwoven fabric (composite fiber composed of polyester and polyethylene terephthalate, basis weight: 35 g/m2), without a ridge-furrow structure (hereunder also referred to as “flat top sheet”).
Sanitary napkins No. 2-2(i) to No. 2-11(i) and No. 2-2(ii) to No. 2-11(ii) were produced, changing the blood slipping agent from UNISTAR H-408BRS to the ones listed in Table 3. Each blood slipping agent was used directly, when it was liquid at room temperature, or when the blood slipping agent was solid at room temperature it was heated to its melting point of +20° C., and then a control seam HMA gun was used for atomization of the blood slipping agent and coating onto the skin contact surface of the top sheet to a basis weight of about 5 g/m2.
The blood slipping agent was coated over essentially the entire skin contact surface of the top sheet, and on both the ridges and furrows of the top sheets with a ridge-furrow structure.
[Test Methods]
After measuring the weight W4 (g) of the top sheet (the weight of the top sheet before the test), approximately 0.25 g (2 drops) of horse EDTA blood at 37±1° C. was added dropwise through a pipette, on the top sheet at the center in the lengthwise direction and widthwise direction of the absorbent article. The horse EDTA blood was dropped onto the top parts of the ridges, in the top sheets with ridge-furrows.
At 30 seconds after dropping, the top sheet was taken off, the weight W5 (g) (weight of top sheet after the test) was measured and the “surface residue rate B (mass %)” was calculated by the following formula.

Surface residue rate B (mass %)=100×(W5 (g)−W4 (g))/W6 (g)

W6 (g) is the weight of the dropped horse EDTA blood, calculated from the weight of the pipette before and after dropping.
The results are shown in Table 3 below.










TABLE 3









Surface residue rate B




(mass %)














Top sheet with
Flat top



No.
Blood slipping agent
ridge-furrows
sheet







2-1
H-408 BRS
4%
32%



2-2
PANACET 810S
8%
40%



2-3
Capric acid diglyceride
8%
24%



2-4
COMPOL BL
4%
32%



2-5
Tributyl O-acetylcitrate
8%
44%



2-6
Dioctyl adipate
8%
32%



2-7
ELECTOL WE40
8%
24%



2-8
UNIOL PB500
4%
68%



2-9
PARLEAM 6
4%
100% 



2-10
UNIOL D-250
16% 
48%



2-11
None
28% 
28%










Table 3 shows that when the blood slipping agent was H-408BRS, PANACET 810S, capric acid diglyceride, COMPOL BL, tributyl O-acetylcitrate, dioctyl adipate, ELECTOL WE40, UNIOL PB500 or PARLEAM 6, the surface residue rate B of the top sheet with ridge-furrows was low. This suggests that blood slipping agents having the prescribed properties cause rapid migration of small amounts of blood from the ridges to the furrows and into the absorbent body.
Test Example 4
[Viscosity of Blood Containing Blood Slipping Agent]
The viscosity of the blood slipping agent-containing blood was measured using a Rheometric Expansion System ARES (Rheometric Scientific, Inc.). After adding 2 mass % of PANACET 810s to horse defibrinated blood, the mixture was gently agitated to form a sample, the sample was placed on a 50 mm-diameter parallel plate, with a gap of 100 μm, and the viscosity was measured at 37±0.5° C. The sample was not subjected to a uniform shear rate, due to the parallel plate, but the average shear rate indicated by the device was 10 s−1.
The viscosity of the horse defibrinated blood containing 2 mass % PANACET 810s was 5.9 mPa·s, while the viscosity of the horse defibrinated blood containing no blood slipping agent was 50.4 mPa·s. Thus, the horse defibrinated blood containing 2 mass % PANACET 810s clearly had an approximately 90% lower viscosity than the blood containing no blood slipping agent.
It is known that blood contains components, such as blood cells and has a thixotropic nature, and it is believed that the blood slipping agent of the present disclosure has an effect of lowering the viscosity of blood, such as menstrual blood in the low viscosity range. Lowering the blood viscosity presumably allows absorbed menstrual blood to more easily migrate rapidly from the top sheet to the absorbent body.
Test Example 5
[Photomicrograph of Blood Slipping Agent-Containing Blood]
Menstrual blood was sampled from healthy volunteers onto food storage wrap film, and PANACET 810s dispersed in a 10-fold mass of phosphate-buffered saline was added to a portion thereof to a PANACET 810s concentration of 1 mass %. The menstrual blood was dropped onto a slide glass, a cover glass was placed thereover, and the state of the erythrocytes was observed with an optical microscope. A photomicrograph of menstrual blood containing no blood slipping agent is shown in FIG. 9(a), and a photomicrograph of menstrual blood containing PANACET 810s is shown in FIG. 9(b).
As shown in FIG. 9, the erythrocytes formed aggregates, including a rouleaux structure, in the menstrual blood containing no blood slipping agent, while the erythrocytes were stably dispersed in the menstrual blood containing PANACET 810s. This suggests that the blood slipping agent has the function of stabilizing erythrocytes in blood.
Test Example 6
[Surface Tension of Blood Containing Blood Slipping Agent]
The surface tension of blood containing a blood slipping agent was measured by the pendant drop method, using a Drop Master500 contact angle meter by Kyowa Interface Science Co., Ltd. The surface tension was measured after adding a prescribed amount of blood slipping agent to sheep defibrinated blood, and thoroughly shaking.
The measurement was accomplished automatically with the apparatus, and the surface tension δ was determined by the following formula (see FIG. 10).

γ=g×ρ×(de)2×1/H 

g: Gravitational constant

1/H: Correction factor determined from ds/de

ρ: Density

de: Maximum diameter

ds: Diameter at location of increase by de from dropping edge

The density ρ was measured at the temperatures listed in Table 4, according to JIS K 2249-1995, “Density test methods and density/mass/volume conversion tables”, 5. Vibrating density test method.
The measurement was accomplished using a DA-505 by Kyoto Electronics Co., Ltd.
The results are shown in Table 4 below.












TABLE 4









Blood slipping agent

Measuring
Surface













Amount
temperature
tension


No.
Type
(mass %)
(° C.)
(mN/m)





1
—
—
35
62.1


2
PANACET
0.01
35
61.5


3
810s
0.05
35
58.2


4

0.10
35
51.2


5
ELECTOL
0.10
35
58.8



WE20


6
PARLEAM 6
0.10
35
57.5


7
—
—
50
56.3


8
WILBRITE
0.10
50
49.1



cp9









Based on Table 4 it is seen that the blood slipping agent has an effect of lowering the surface tension of blood.
Lowering the surface tension of blood presumably allows absorbed blood to rapidly migrate from the top sheet to the absorbent body, without being retained between the top sheet fibers.
Test Example 7
(1) Preparation of Absorbent Article Samples a (Example Product) and B (Comparative Example Product)
The gear stretcher 100 shown in FIG. 4 was used to produce a top sheet. The specific production method was as follows.
As the upper layer nonwoven fabric before formation of concavoconvexities there was used a blended laminate (basis weight: 18 g/m2) of PET/HDPE with a basis weight of 12 g/m2 (4.1 dtex thickness×51 mm length) and PET/HDPE with a basis weight of 6 g/m2 (2.2 dtex thickness×51 mm length).
The upper layer nonwoven fabric was stretched with the gear stretcher 100 shown in FIG. 4 to form concavoconvexities. The peripheral speeds V1 of the first driving rolls 151, 152 at this time were adjusted to be 1.2 times the peripheral speeds V2 of the gear stretching rolls 120, 130. This caused overfeeding of the upper layer nonwoven fabric with respect to the gear stretching rolls 120, 130, preventing reduction in the basis weight and fiber density of the stretched sections (i.e. the side sections of the projections) so that the basis weight and fiber density of the top sections and side sections of the projections were essential equal. The basis weight of the upper layer nonwoven fabric after formation of concavoconvexities was 22 g/m2, and the thickness (under 3 gf load) was 0.57 mm.
The upper layer nonwoven fabric after formation of concavoconvexities was bonded to a lower layer nonwoven fabric using the gear stretcher 100 shown in FIG. 4. The lower layer nonwoven fabric used was a nonwoven fabric composed of PET/HDPE (2.2 dtex thickness×51 mm length), with a basis weight of 18 g/m2 and a thickness (under 3 gf load) of 0.5 mm.
The basis weight of the top sheet as a whole was 40 g/m2, and the thickness (under 3 gf load) was 1.2 mm.
The top sheet was layered with an absorbent body to produce an absorbent article. The absorbent body used was ground pulp (basis weight: 250 g/m2) covered with a core wrap (tissue with basis weight of 14 g/m2). The interface between the top sheet and the absorbent body was spiral coated with a hot-melt adhesive (basis weight: 5 g/m2) to bond them together.
The skin contact surface of the absorbent article on which concavoconvexities had been formed was coated with a blood slipping agent (triglyceride), to prepare absorbent article sample A (example product). Separately, an absorbent article not coated with a blood slipping agent was prepared as absorbent article B (comparative example product). The coating basis weight of the blood slipping agent on absorbent article sample A was 5 g/m2.
(2) Measurement of Rewetting Amount, Penetration Time and Absorbent Body-Migration Time (Drain Time)
[Test Methods]
An acrylic board with an opened hole (200 mm×100 mm, 125 g, with a 40 mm×10 mm hole opened at the center) was placed on the skin contact surface of each sample, and 3 mL of horse EDTA blood at 37±1° C. (obtained by adding ethylenediaminetetraacetic acid (EDTA) to horse blood to prevent coagulation) was dropped through the hole using a pipette (once), and after 1 minute, 3 mL of horse EDTA blood at 37±1° C. was again added dropwise through the acrylic board hole with a pipette (twice). The dropping rate was 90 mL/min. The time from each dropping until the horse blood retained in the acrylic board hole disappeared, was recorded as the penetration time (sec), while the time until the horse blood disappeared from the surface and interior of the top sheet (the time until blood redness was no longer visible) was measured and recorded as the absorbent body migration rate (drain time) (sec).
After the second dropping of blood, the acrylic board was immediately removed and 10 sheets of filter paper (Qualitative filter paper No. 2, product of Advantech Toyo, Inc., 50 mm×35 mm) were placed on the location where the blood had been dropped, and then a weight was placed thereover to a pressure of 30 g/cm2. After 1 minute, the filter paper was removed and the rewetting rate was calculated by the following formula.

Rewetting rate (%)=100×(filter paper mass after test−initial filter paper mass)/6

[Results]

With sample A (example product), the liquid permeation rate (1st time) was 2 seconds, the liquid permeation rate (2nd time) was 5.28 seconds, the absorbent body migration rate (1st time) was 15.19 seconds, the absorbent body migration rate (2nd time) was 51.96 seconds, and the rewetting rate was 12.0%.
In contrast, with sample B (comparative example product), the liquid permeation rate (1st time) was 2.25 seconds, the liquid permeation rate (2nd time) was 4.41 seconds, the absorbent body migration rate (1st time) was longer than 60 seconds, the absorbent body migration rate (2nd time) was longer than 60 seconds, and the rewetting rate was 13.8%.
The absorbent body migration rate was significantly different between samples A and B. As shown by the absorbent body migration rate of sample B, menstrual blood tends to remain in the top sheet (especially the interior spaces of the projections) when the interiors of the projections of the top sheet are hollow. In contrast, as shown by the absorbent body migration rate of sample A, if a blood slipping agent is coated onto the projections it is possible for menstrual blood to rapidly migrate into the absorbent body from the top sheet even when the interiors of the projections of the top sheet are hollow, and this can lower residue of menstrual blood on the top sheet (especially in the interior spaces of the projections).
REFERENCE SIGNS LIST


    1 Sanitary napkin (absorbent article)
    2 Top sheet (liquid-permeable layer)
    3 Back sheet (liquid-impermeable layer)
    4 Absorbent body
    8 Projection
    9 Recess

## Claims

1. An absorbent article comprising a liquid-permeable layer with a skin contact surface, a liquid-impermeable layer with a non-skin-contacting surface, and an absorbent body situated between the liquid-permeable layer and the liquid-impermeable layer,
wherein the liquid-permeable layer has a first layer formed on the skin contact surface and a second layer formed on the non-skin contact surface side,
the first layer has a projection with a hollow interior bulging out on the skin contact surface side, which is formed at least in the excretory opening contact region on the skin contact surface side, and is partially bonded with the second layer at sections other than the projection, and
at least the projection of the excretory opening contact region is coated with a coating consisting essentially of a blood slipping agent having a 40° C. kinematic viscosity of 0.01 to 80 mm2/s, a water holding percentage of 0.01 to 4.0 mass % and a weight-average molecular weight greater than 0 and less than 1,000, wherein the coating is present at a basis weight ranging from about 1 g/m2 to about 30 g/m2, and the coating is configured to migrate from the skin contact surface through the liquid-permeable layer into the absorbent body with menstrual blood.

2. An absorbent article according to claim 1, wherein fiber density across all portions of the projection is essentially constant.

3. An absorbent article according to claim 1, wherein basis weight across all portions of the projection is essentially constant.

4. An absorbent article according to claim 1, wherein the Inorganic Organic Balance (JOB) of the blood slipping agent is 0.00 to 0.60.

5. An absorbent article according to claim 1, wherein the blood slipping agent is selected from the group consisting of the following items (i)-(iii), and any combination thereof:
(i) a hydrocarbon;
(ii) a compound having (ii-1) a hydrocarbon moiety, and (ii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii) a compound having (iii-1) a hydrocarbon moiety, (iii-2) one or more, same or different groups selected from the group consisting of carbonyl group (—CO—) and oxy group (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen of the hydrocarbon moiety;
with the proviso that when 2 or more oxy groups are inserted in the compound of (ii) or (iii), the oxy groups are not adjacent.

6. An absorbent article according to claim 1, wherein the blood slipping agent is selected from the group consisting of the following items (i′)-(iii′), and any combination thereof:
(i′) a hydrocarbon;
(ii′) a compound having (ii′-1) a hydrocarbon moiety, and (ii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety; and
(iii′) a compound having (iii′-1) a hydrocarbon moiety, (iii′-2) one or more, same or different bonds selected from the group consisting of carbonyl bond (—CO—), ester bond (—COO—), carbonate bond (—OCOO—), and ether bond (—O—) inserted between a C—C single bond of the hydrocarbon moiety, and (iii′-3) one or more, same or different groups selected from the group consisting of carboxyl group (—COOH) and hydroxyl group (—OH) substituting a hydrogen on the hydrocarbon moiety;
with the proviso that when 2 or more same or different bonds are inserted in the compound of (ii′) or (iii′), the bonds are not adjacent.

7. An absorbent article according to claim 1, wherein the blood slipping agent is selected from the group consisting of the following items (A)-(F), and any combination thereof:
(A) an ester of (A1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety, and (A2) a compound having a chain hydrocarbon moiety and 1 carboxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(B) an ether of (B1) a compound having a chain hydrocarbon moiety and 2-4 hydroxyl groups substituting hydrogens on the chain hydrocarbon moiety and (B2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(C) an ester of (C1) a carboxylic acid, hydroxy acid, alkoxy acid or oxoacid comprising a chain hydrocarbon moiety and 2-4 carboxyl groups substituting hydrogens on the chain hydrocarbon moiety and (C2) a compound having a chain hydrocarbon moiety and 1 hydroxyl group substituting a hydrogen on the chain hydrocarbon moiety;
(D) a compound having a chain hydrocarbon moiety and one bond selected from the group consisting of an ether bond (—O—), carbonyl bond (—CO—), ester bond (—COO—) and carbonate bond (—OCOO—) inserted between a C—C single bond of the chain hydrocarbon moiety;
(E) a polyoxy C3-C6 alkylene glycol, or alkyl ester or alkyl ether thereof; and
(F) a chain hydrocarbon.

8. An absorbent article according to claim 1, wherein the blood slipping agent is selected from the group consisting of (a1) an ester of a chain hydrocarbon tetraol and at least one fatty acid, (a2) an ester of a chain hydrocarbon triol and at least one fatty acid, (a3) an ester of a chain hydrocarbon diol and at least one fatty acid, (b1) an ether of a chain hydrocarbon tetraol and at least one aliphatic monohydric alcohol, (b2) an ether of a chain hydrocarbon triol and at least one aliphatic monohydric alcohol, (b3) an ether of a chain hydrocarbon diol and at least one aliphatic monohydric alcohol, (c1) an ester of a chain hydrocarbon tetracarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 4 carboxyl groups, and at least one aliphatic monohydric alcohol, (c2) an ester of a chain hydrocarbon tricarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 3 carboxyl groups, and at least one aliphatic monohydric alcohol, (c3) an ester of a chain hydrocarbon dicarboxylic acid, hydroxy acid, alkoxy acid or oxoacid with 2 carboxyl groups, and at least one aliphatic monohydric alcohol, (d1) an ether of an aliphatic monohydric alcohol and an aliphatic monohydric alcohol, (d2) a dialkyl ketone, (d3) an ester of a fatty acid and an aliphatic monohydric alcohol, (d4) a dialkyl carbonate, (e1) a polyoxy C3-C6 alkylene glycol, (e2) an ester of a polyoxy C3-C6 alkylene glycol and at least one fatty acid, (e3) an ether of a polyoxy C3-C6 alkylene glycol and at least one aliphatic monohydric alcohol, and (f1) a chain alkane, and any combination thereof.

9. The absorbent article according to claim 1, wherein the blood slipping agent has a vapor pressure of 0.00 to 0.01 Pa at 1 atmosphere, 40° C.