# Patent

## Title
Cleaning composition for the food and beverage industry

## Abstract

An aqueous cleaning composition and methods for use in the agricultural, food and beverage industry which comprises at least 3% of hydrogen peroxide and a plurality of non-ionic surfactants, wherein said cleaning composition is substantially free of any alkalinity source.

## Background
TECHNICAL FIELD
This disclosure is directed to a cleaning composition for use in the agricultural, food and beverage industry. It is especially useful in agricultural based industries such as the wine industry and other such industries which utilize large vessels that need cleaning on a continuous basis in view of the accumulation of mineral deposits and organic complexes, proteins, starches, soils and associated stains.
The disclosure further is directed to a method of cleaning vessels used in the agricultural, food and beverage industries which comprises diluting with water an aqueous composition which comprises at least 3% of hydrogen peroxide and a plurality of non-ionic surfactants, wherein said cleaning composition is substantially free of any alkalinity source and applying said diluted composition to said vessel in an amount necessary to clean said vessel of mineral deposits and/or organic complexes, proteins, starches, soils and associated stains, wherein said diluted composition comprises less than about 10% of said aqueous composition.
BACKGROUND
Agriculturally based industries including the food and beverage industry use equipment that must be cleaned frequently. Soils left behind from the production process generally consist of mineral deposits, organic complexes, proteins, starches, soils and associated stains. These soils and stains are generally cleaned with a highly alkaline cleaner composed of an alkalinity source, such as sodium hydroxide, potassium hydroxide, or sodium metasilicate, detergents, wetting agents, and possibly sodium hypochlorite. These alkaline cleaners are generally not effective at cleaning mineral deposits. Acidic cleaners are used to remove such mineral deposits and are generally composed of a blend of phosphoric acid and nitric acid, along with surfactants and detergents. These acidic cleaners are not very effective at cleaning organic complexes, proteins, starches, soils and associated stains. Thus, neither acidic nor alkaline cleaners are capable of effectively cleaning vessels which contain organic complexes, proteins, starches, soils and associated stains, as well as, mineral deposits.
Furthermore, such alkaline cleaners result in cation buildup which often results in harm to the environment such as osmotic pressure driving water out of root systems, leaf burning, plant stress, reduced water infiltration leading to increased runoff and erosion and reduced hydraulic conductivity. Thus, water management becomes difficult and expensive. Remediation is costly and continuous. In the end excess cation content can negatively affect the taste, yield and quality of a crop. This is especially damaging to industries, such as wineries, where such a result will be devastating to the business.
Thus, a cleaning composition that is effective at removing organic complexes, proteins, starches, soils and associated stains, as well as, mineral deposits is greatly needed in the agricultural, food and beverage industry.
SUMMARY
Accordingly, present application relates to an aqueous cleaning composition for use in the food and beverage industry which comprises at least 3% of hydrogen peroxide and a plurality of non-ionic surfactants, wherein said cleaning composition is substantially free of any alkalinity source. Preferably, the composition is also substantially free of any phosphonate source as well. In another aspect, an organic acid is added to the composition.
Another embodiment provides for an aqueous cleaning composition for use in the food and beverage industry which comprises from 3-6% hydrogen peroxide, 1-10%, propoxylated and ethoxylated C8-C10 linear alcohols, 1-10% propoxylated and ethoxylated C6-C10 linear alcohols, 5-20% organic acid, rinse aids and defoamers and at least 50% water wherein said composition is substantially free of any alkalinity source and is substantially free of any phosphonate source wherein is said composition is capable of cleaning soils consisting of mineral deposits, organic complexes, proteins and starches.
The present application further relates to the use of such compositions to clean vessels used in the agricultural, food and beverage industries. Accordingly, such compositions are used in methods for cleaning vessels used in such industries by applying said compositions to said vessel by spraying, foaming and immersion.


DETAILED DESCRIPTION
An aqueous cleaning composition for use in the food and beverage industry will be described herein. The composition is defined by certain ingredients in the amounts specified. Accordingly, an aqueous cleaning composition for use in the food and beverage industry comprises at least 3% by weight of hydrogen peroxide and a plurality of non-ionic surfactants, wherein said cleaning composition is substantially free of any alkalinity source. Preferably, the composition is also substantially free of any phosphonate source as well.
Further, the use of such compositions to clean vessels used in the agricultural, food and beverage industries. Accordingly, such compositions are used in methods for cleaning vessels used in such industries by applying said compositions to said vessel by spraying, foaming and immersion. One such method provides for a method of cleaning vessels used in the agricultural, food and beverage industries which comprises diluting with water an aqueous composition which comprises at least 3% of hydrogen peroxide and a plurality of non-ionic surfactants, wherein said cleaning composition is substantially free of any alkalinity source and applying said diluted composition to said vessel in an amount necessary to clean said vessel of mineral deposits and/or contain organic complexes, proteins, starches, soils and associated stains, wherein said diluted composition comprises less than about 10% of said aqueous composition.
One aspect is that the composition is substantially free of any alkalinity source and in another aspect it is substantially free of any phosphonate source. Thus, the composition is substantially free of any alkali in one embodiment and substantially free of any alkali and phosphonate in another embodiment. The term “substantially free” as used herein means that the composition is free from any amount of alkali and/or phosphonate which would prove harmful to the environment by, for example, increasing osmotic pressure driving water out of root systems, leaf burning, plant stress, reduced water infiltration leading to increased runoff and erosion and reduced hydraulic conductivity. The compositions are substantially free by utilizing ingredients that do not contain alkali and/or phosphonate. A composition would be considered to be “substantially free” of alkali and/or phosphonate sources if any such composition contained alkali and/or phosphonate resulting from unknown sources that were not intentionally added to the composition and in an amount that did no harm to the environment as described above.
The expression of quantity in terms of percent means the percentage by weight, relative to the weight of the total composition.
The term “about” when used to modify a numeric quantity of an ingredient in the compositions of the invention or employed in the methods of the invention refers to a minor variation in the numerical quantity that can occur through inadvertent error, differences in source or purity and the like.
A key ingredient in the cleaning composition is hydrogen peroxide. Hydrogen peroxide can be a very active material. As such, hydrogen peroxide can be added as such or it can be added in the form of a stabilized composition. Examples of stabilized hydrogen peroxides include Peroxy Blend (Akzo Nobel), Peroxy Base 2 (Burlington Chemical Co.), or Peroxy Green 2 (Hubbard Hall). If a stabilized blend of hydrogen peroxide is used, the amount of hydrogen peroxide in the cleaning composition should total at least 3 percent of said cleaning composition even though the amount of stabilized blend may be more. For example if a stabilized blend contains 31% hydrogen peroxide, the amount of the stabilized blend should be at least about 10 percent of the cleaning composition so that said cleaning composition contains at least 3 percent hydrogen peroxide.
As noted above, the disclosed compositions require the use of a plurality of non-ionic surfactants. Preferred non-ionic surfactants include alkoxylated alcohols, such as propoxylated and ethoxylated C8-C10 linear alcohols and propoxylated and ethoxylated C6-C10 linear alcohols. Other non-ionic surfactants that can be used are interdispersed ethoxylated-propoxylated alcohols, block ethoxylated-propoxylated alcohols, ethoxylated phenol, propoxylated alkyl phenols, alkyl polyglycoside, alkyl secondary alcohol ethoxylate, amine oxides and combinations thereof including Tomadol 23, 25, 45, 91 series, Nonidet SF-3 and SF-5, Plurafac B-25-2, Plurafac LF-7000, Pluronic N-3.
In one embodiment, an organic acid is added to the composition. Many organic acids can be used including citric acid, lactic acid, malic acid, gluconic acid, acetic acid, phosphoric acid, oxalic acid, sulfamic acid and substituted and non-substituted and combinations thereof An especially useful acid is acetic acid and substituted acetic acid, such as hydroxyl acetic acid.
To aid in cleaning, other adjuvants such as rinse aids and defoamers can be added. Such rinse aids and defoamers include block copolymers of propylene oxide and ethylene oxide, silicone emulsions, modified silicones, and polysiloxane including T-DET EPO series, Pluronic L, P, and R series, Dee Fo PI series, Foam BanMS series, and Silicone AF-8805, 8810, 8820, and 8830.
The above described embodiments will be further appreciated in light of the following examples which are provided as being illustrative of the invention and not to limit its scope.
EXAMPLE 1












Component
% By Weight
Type of Component

















Deionized Water
77.4
Water


31% Peroxy Blend
10
Stabilized Hydrogen




Peroxide


T DET LF 416
2.5
Alkoxylated Alcohol


Plurafac S405LF
2.5
Alkoxylated Linear Alcohol


T DET EPO 62LF
7.5
Polyalkylene Defoamer


FOAM BAN MS-455-3A
0.1
Siloxane Defoamer









EXAMPLE 2












Component
% By Weight
Type of Component

















Deionized Water
56.35
Water


31% Peroxy Blend
20
Stabilized Hydrogen




Peroxide


T DET LF 416
2.5
Alkoxylated Alcohol


Plurafac S405LF
2.5
Alkoxylated Linear Alcohol


T DET EPO 62LF
7.5
Polyalkylene Defoamer


FOAM BAN MS-455-3A
0.1
Siloxane Defoamer


Hydroxy Acetic Acid 70%
10
Organic Acid









T DET LF Series and Plurafac SLF Series are propoxylated or ethoxylated C8-C10 linear alcohols made by T DET by Harcros Organics of Kansas City, Mo. and Plurafac BASF.
Plurafac 5400 Series are propoxylated or ethoxylated C6-C10 linear alcohols made by BASF.
T DET EPO Series are polyethylene-polypropylene glycols made by Harcros Organics of Kansas City, Mo.
Testing was done in field trials using 1-2% solution, applied by spray for 30 minutes, with photographs of the surfaces before and after cleaning, comparing visual appearance. The tests illustrated that the compositions of Examples 1 and 2 were highly effective in cleaning mineral deposits as well as organic complexes.
As shown and described herein, the disclosed embodiments are highly effective in cleaning and removing organic complexes, proteins, starches, soils and associated stains, as well as, mineral deposits from vessels used in the agricultural, food and beverage industries.
This disclosure is intended to explain how to fashion and use various embodiments in accordance with the invention rather than to limit the true, intended, and fair scope and spirit thereof The foregoing description is not intended to be exhaustive or to limit the invention to the precise form disclosed. Modifications or variations are possible in light of the above teachings. The embodiment(s) was chosen and described to provide the best illustration of the principles of the invention and its practical application, and to enable one of ordinary skill in the art to utilize the invention in various embodiments and with various modifications as are suited to the particular use contemplated. All such modifications and variations are within the scope of the invention as determined by the appended claims, as may be amended during the pendency of this application for patent, and all equivalents thereof, when interpreted in accordance with the breadth to which they are fairly, legally, and equitably entitled.

## Claims

1. A method of cleaning vessels used in the agricultural, food and beverage industry consisting of:
diluting with water an aqueous composition consisting of about 3-6% hydrogen peroxide, a plurality of non-ionic surfactants are alkoxylated alcohols selected from the group consisting of about 1-10%, propoxylated and ethoxylated C8-C10 linear alcohols, and about 1-10% propoxylated and ethoxylated C6-C10 linear alcohols and combinations thereof, about 5-20% organic acid, rinse aids and defoamers and at least about 50% water wherein said composition is substantially free of any alkalinity source and is substantially free of any phosphonate source; and
applying the cleaning composition to a vessel in an amount necessary to clean the vessel of mineral deposits and/or organic complexes, proteins, starches, soils and associated stains.

2. A method of cleaning vessels used in the agricultural, food and beverage industry consisting of:
diluting with water an aqueous composition consists of about 20% hydrogen peroxide, a plurality of non-ionic surfactants consisting of alkoxylated alcohols selected from the group consisting of about 2.5% propoxylated and ethoxylated C8-C10 linear alcohols, and about 2.5% propoxylated and ethoxylated C6-C10 linear alcohols and combinations thereof, about 10% organic acid, about 7.5% defoamer, about 0.1% siloxane and an amount of deionized water so that the aqueous composition totals 100%; and
applying the cleaning composition to a vessel in an amount necessary to clean the vessel of mineral deposits and/or organic complexes, proteins, starches, soils and associated stains.

3. A method of cleaning vessels consisting of:
diluting with water a cleaning composition consisting of 10% hydrogen peroxide, 2.5% alkoxylated alcohol, 2.5% alkoxylated linear alcohol, 7.5% polyalkylene defoamer; 0.1% siloxane defoamer, and 77.4% deionized water; and
applying the cleaning composition to a vessel in an amount necessary to clean said vessel of mineral deposits and/or organic complexes, proteins, starches, soils and associated stains.

4. A method of cleaning vessels consisting of:
diluting with water a cleaning composition consisting of 20% hydrogen peroxide, 2.5% alkoxylated alcohol, 2.5% alkoxylated linear alcohol, 7.5% polyalkylene defoamer, 0.1% siloxane defoamer, 10% organic acid, and an amount of deionized water so that the cleaning composition totals 100%; and
applying the cleaning composition to a vessel in an amount necessary to clean said vessel of mineral deposits and/or organic complexes, proteins, starches, soils and associated stains.

5. The method of claim 1, wherein said aqueous composition is applied by spraying, immersion or foaming.