# Patent

## Title
Packaging substrates for integrated circuits and soldering methods

## Abstract

A packaging substrate (310) includes a semiconductor interposer (120) and at least one other intermediate substrate (110), e.g. a BT substrate. The semiconductor interposer has first contact pads (136C) attachable to dies (124) above the interposer, and second contact pads (340) attachable to circuitry below the interposer. Through vias (330) are made in the semiconductor substrate (140) of the interposer (120). Conductive paths going through the through vias connect the first contact pads (136C) to the second contact pads (340). The dies (124) are attached to the interposer after the attachment of the interposer to the BT substrate. In sequential soldering operations, the solder hierarchy is maintained by dissolving some material (e.g. copper) in the solder during soldering to raise the solder's melting temperature. For example, all of the solders may initially have the same melting temperature, but each solder's melting temperature is increased during soldering to prevent the solder from melting in the subsequent soldering operations.

## Background
BACKGROUND OF THE INVENTION
The present invention relates to packaging of integrated circuits and to soldering methods.
Integrated circuit dies (“chips”) can be attached to a lead frame and then packaged in a ceramic or plastic carrier. The leads of the lead frame can then be soldered to a printed circuit board (PCB). Alternatively, the chip can be soldered directly to the PCB (“flip chip” packaging). The flip chip packaging reduces the package size and shortens the electrical connections between the die and the PCB, but the flip chip packaging is vulnerable to solder failures caused by thermal expansion and contraction. The solder failures are due to the differences in the coefficient of thermal expansion (CTE) between the die and the PCB.
The CTE mismatch has been addressed by providing an intermediate substrate between the die and the PCB, with an intermediate CTE. For example, in a ball grid array (BGA) package, the die is flip-chip attached to the intermediate substrate (“BGA substrate”), and the BGA substrate is soldered to the PCB. The BGA substrate provides interconnect lines between the die and the PCB. A silicon die may have a CTE of about 2.7 ppm/° C. (parts per million per degree Centigrade); a PCB made of FR4 can have a CTE of about 20 ppm/° C.; a BGA substrate made from BT (bis-maleimide triazine) has a CTE of about 16 ppm/° C., and a BGA substrate made from ceramic has a CTE of about 9 ppm/° C.
In addition to reducing the thermal stresses, the intermediate substrate may allow a smaller die size by allowing the die to have smaller contact pads with a reduced pitch. The minimum size and pitch of the die's contact pads is limited by the size and pitch of the contact pads on the substrate to which the die is attached. For example, if the die is flip-chip bonded to a BT substrate, the size and pitch of the die's contact pads can be smaller than if the die is attached to an FR4 substrate (PCB).
The intermediate substrate may also reduce the PCB area taken by the die because the intermediate substrate may redistribute the die's contact pads. The position of the die's contact pads is restricted by the die's circuitry. The BGA substrate's contact pads that are bonded to the PCB are not restricted by the die's circuitry. For example, the die may have contact pads only on the periphery, but the BGA substrate's contact pads attached to the PCB may be evenly distributed over the BGA area.
Further, if multiple dies are mounted on a single intermediate substrate, the dies can be interconnected by interconnects in the intermediate substrate without using the PCB routing resources. This leads not only to saving the PCB area but also to shorter interconnections between the dies and hence to a better electrical performance (higher speed and lower power consumption, inductance and capacitance).
FIG. 1 illustrates another package with two intermediate substrates 110, 120 between dies (ICs) 124 and PCB 130. Intermediate substrate 110 is a BT substrate, soldered to the underlying PCB 130 with solder balls 134. Intermediate substrate 120 is a silicon interposer attached to the top surface of BT substrate 110 by an adhesive (not shown). Silicon interposer 120 includes metal layers 136 formed over silicon substrate 140 and separated by dielectric layers 144. Dies 124 are attached to interposer 120 with their contact pads facing up. The dies' contact pads are wire bonded to contact pads 136C.1 provided by metal layers 136. The wire bonding is done with bond wires 150. Contact pads 136C.2 on top of the interposer are wire bonded to contact pads 360 on top of BT substrate 110 using bond wires 160. Interconnect lines made from layers 136 connect the contact pads 136C.1 to the contact pads 136C.2.
Metal layers 136 provide interconnects between the dies 124. The interconnects can be manufactured on silicon interposer 120 with a higher density and higher electrical performance than on BT substrate 110. There is no CTE mismatch between silicon substrate 120 and silicon dies 124.
For commercial reasons, a manufacturer may sell packaging substrates consisting substantially of a silicon interposer 120 and a BT substrate 110 (FIG. 2). Then the buyers of the packaging substrates attach the dies 124 and the PCBs 130 to the packaging substrates.
Alternative packaging substrates and packaging techniques are desirable.
Soldering: When multiple soldering operations are performed to form different solder joints, each subsequent soldering operation should not destroy the solder joints formed in the previous operations. This can be achieved, by a solder hierarchy, i.e. a hierarchy of the solder melting temperatures. Each subsequent soldering operation is performed with a solder having a lower melting temperature then the solders used in the previous operations, so the solders used in the previous operations do not melt. It is desirable to develop techniques that relax the solder hierarchy requirements.
SUMMARY
This section summarizes some features of the invention. Other features are described in the subsequent sections. The invention is defined by the appended claims which are incorporated into this section by reference.
In some embodiments of the present invention, a packaging substrate is provided which, like the packaging substrate of FIG. 2, includes a silicon interposer and a BT substrate. However, the silicon interposer has contact pads both on the top and the bottom, and has through-silicon vias made in the silicon substrate of the interposer. Conductive paths going through the through-silicon vias connect the contact pads on the top of the interposer to the contact pads on the bottom.
Silicon interposers with through-silicon vias have been described in U.S. Pat. No. 6,322,903, incorporated herein by reference, but not in a packaging substrate having two or more intermediate substrates as in some embodiments of the present invention. The packaging substrates according to some embodiments of the present invention provide a manufacturing challenge if the silicon interposer is thin. Thin interposers are desirable because to reduce the package size and improve the electrical characteristics (by shortening the conductive paths through the interposer). Also, in some embodiments, it is easier to manufacture the through-silicon vias if the interposer is thin. However, thin interposers are fragile, can be warped, and their heat dissipation capabilities are poor, so the interposer handling is complicated. In U.S. Pat. No. 6,322,903, at least in some embodiments, the interposer is thinned only after attachment to a die. However, in a packaging substrate, the interposer may have to be thinned to its final thickness before the die attachment. In some embodiments, the interposer is thinned before attachment to the BT substrate. The semiconductor substrate of the interposer can be quite thin, e.g. 100 μm or thinner. The semiconductor substrate and the interposer may have substantially planar top and bottom surfaces, as opposed to interposers with cavities large enough to contain a die, with the cavities' sidewalls being thicker than the rest of the interposer to increase the interposer's mechanical strength (see U.S. patent application Ser. No. 09/952,263 filed Sep. 13, 2001 by Halahan et al., incorporated herein by reference). The term “substantially planar” indicates that any non-planarity of the semiconductor substrate or the interposer is so minor as to have no significant effect on the mechanical strength of the structure.
Some aspects of the present invention relate to a manufacturing process, and to a BT substrate, that simplifies the handling of thin silicon interposers.
Soldering: In some embodiments of the present invention, maintaining the solder hierarchy is simplified through changing the solder melting temperature during soldering. It is well known that a solder melting temperature may increase if a soldered surface contains copper because the copper may dissolve in the solder during the soldering operation to raise the solder melting temperature. In some embodiments, this property is used to obtain a proper solder hierarchy. For example, in some embodiments, all of the sequential soldering operations use the same starting solder material. In each soldering operation, the solder's melting temperature increases, so the solder will not melt in the subsequent soldering operations. The manufacturing process is simplified because it eliminates the need to obtain different solder types with different initial melting temperatures.
In other embodiments, the solder for a current soldering operation may initially have even a lower melting temperature than the solders used in the subsequent operations, but the solder melting temperature is increased in the current soldering operation to prevent the solder from melting during the subsequent operations.
The invention is not limited to the embodiments discussed in this section. The invention is not limited to thin interposers, and further is applicable to non-silicon semiconductor interposers attached to non-BT intermediate substrates. Materials other than copper may be used to increase the solder melting temperature. Other features and advantages of the invention are described below. The invention is defined by the appended claims.



BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1 and 2 show vertical cross sections of integrated circuit packaging structures according to prior art.
FIGS. 3–13 show vertical cross sections of integrated circuit packaging structures according to some embodiments of the present invention.
FIG. 14 is a flowchart of an integrated circuit packaging process according to one embodiment of the present invention.
FIG. 15 shows a vertical cross section of an integrated circuit packaging structure according to one embodiment of the present invention.



DESCRIPTION OF SOME EMBODIMENTS
The embodiments described in this section illustrate but do not limit the invention. The invention is not limited to particular materials, process steps, or dimensions. The invention is defined by the appended claims.
FIG. 3 illustrates an integrated circuit packaging substrate 310 having two intermediate integrated circuit packaging substrates 110, 120. Substrate 120 is a silicon interposer attached to BT substrate 110. Dies 124 and PCB 130 will be attached later.
Silicon interposer 120 includes metal layers 136 formed over silicon substrate 140. Substrate 140 has substantially planar top and bottom surfaces, and is quite thin. In some embodiments, the planarity of substrate 140 is suitable for fine geometry photolithography (finer than possible with BT and FR4 substrates). The thickness of substrate 140 can be 100 μm or less (50 μm to 35 μm thickness values believed to be achievable, and smaller values may be possible). Layers 136 provide interconnect lines and may also provide power and ground planes, resistors, inductors, capacitor plates for decoupling capacitors and other capacitor types, and possibly other elements, known or to be invented. Layers 136 can be separated from each other, and from the substrate, by dielectric layers 144. Layers 136 contact each other and the silicon substrate through openings in the dielectric layers. Layers 136 can also be formed directly on the silicon substrate if desired. Layers 136 provide contact pads 136C at the top surface of the interposer. The contact pads are available for flip-chip attachment to dies 124.
Silicon substrate 140 includes metalized through-silicon vias 330 that pass between the top and bottom surfaces of substrate 140. Conductive paths are provided from contact pads 136C at the top of the interposer to contact pads 340 at the bottom of the interposer through the vias 330. Contact pads 340 are attached to contact pads 350 at the top surface of BT substrate 110.
Interconnects (not shown) in BT substrate 110 connect the contact pads 350 to contact pads 360 at the bottom surface of substrate 110. Solder balls 134 are formed on pads 360 by conventional techniques for attachment to PCB 130.
The size and spacing (pitch) of contact pads 136C on interposer 120 matches the size and the pitch of the contact pads on dies 124. If dies 124 are silicon integrated circuits, their CTE matches the CTE of the interposer, so the pitch of contact pads 136C can be small because the low thermal stresses at the interface between the dies and the interposer make it unnecessary to use large solder balls 370. The contact pads 340 on the bottom of the interposer match the top contact pads 350 of BT substrate 110. For some fabrication technologies, the minimum dimensions are as shown in the following table. The dimensions can typically be reduced if more expensive technologies are used.














Minimum
Solder ball
Solder ball


Contacts
pitch
diameter
height




















Contact pads 136C
125
μm
60 μm (solder balls
50
μm





370 on IC 124)


Contact pads 340,
254
μm


350


Contact pads 360
1.27
mm
0.5 mm (solder
0.4
mm





balls 134)









To facilitate the interposer handling, the metal contact pads 340 are formed to protrude out of vias 330. The protruding contact pads 340 are inserted into cavities in BT substrate 110, as explained in more detail below. The invention is not limited to the protruding contact pads or the cavities however.
Silicon interposer 120 can be manufactured using conventional techniques. See e.g. the aforementioned U.S. Pat. No. 6,322,903. Other techniques are described in U.S. patent application Ser. No. 10/410,929 filed on Apr. 9, 2003 by P. Halahan et al., entitled “Electroplating and electroless plating of conductive materials into openings, and structures obtained thereby”, incorporated herein by reference. Still other techniques can possible be used, whether known or to be invented. An exemplary manufacturing process is as follows. Vias 330 (FIG. 4) are etched in the top surface of silicon substrate 140 (e.g. monocrystalline silicon) by DRIE (deep reactive ion etching) to an exemplary depth Hv=150 μm. (The dimensions, etching processes, and other particulars are exemplary and not limiting.) The via diameter Dv is 251 μm to 100 μm. The via diameter DV is one of the parameters defining the diameter of contact pads 340 (FIG. 3), and DV is chosen large enough to provide the necessary mechanical strength for the protruding contact pads. Exemplary dimensions below will be given for Dv=65 μm. Silicon dioxide layer 410 is thermally grown on the wafer to a thickness of about 1 μm. A larger thickness can also be used to reduce the capacitance between substrate 140 and the metal features that will be fabricated in vias 330. Barrier layer 420 of titanium-tungsten (TiW) is sputtered on oxide 410 to a thickness of 0.2 μm. A seed copper (Cu) layer 430.1 is sputtered on the wafer to a thickness sufficient to ensure a continuous copper coverage in the via. Thicknesses of 0.5 μm to 21 μm are believed to be adequate, depending on the sputter technology. A dry photoresist film 440 is deposited on the wafer and patterned to expose the vias 330.
Optionally, gold (Au) layer 444 and nickel (Ni) layer 448 are electroplated, in that order, to an exemplary thickness of 0.2 μm and 1.0 μm respectively.
Copper 430.2 is electroplated on nickel 448 to fill the vias 330 and possibly protrude out of the vias. In the electroplating of layers 444, 448, 430.2, the cathode terminal (not shown) of the power source is placed at the periphery of wafer 140 in physical contact with seed layer 430.1.
Optionally, nickel (Ni) layer 450 is electroplated on the top surface of copper layer 430.2 to an exemplary thickness of 0.5 μm.
Resist 440 is removed (FIG. 5). A wet copper etch removes the exposed portions of seed copper 430.1, with nickel 450 acting as a mask. Nickel 450 protects copper 430.2 in vias 330. Copper 430.2, 430.1 can be etched laterally during the wet etch, but the lateral etch does not remove the copper over the vias 330 because the copper extends laterally beyond the via edges. In those embodiments in which the nickel 450 is omitted, the copper etch may reduced the thickness of copper 430.2, but this is acceptable if the copper protrusions above the vias are sufficiently thick. In either case, it is desirable for the top surface of copper 430.2 to be at or above the top surface of oxide 410 after the copper etch.
Then a CMP step (chemical mechanical polishing) is performed to remove copper 430.2, nickel 448, gold 444, and TiW 420 off the top surface of substrate 140 (FIG. 6). The CMP stops on oxide 410. The structure has a planar top surface.
In an alternative embodiment, the wet etch of copper 430.1 is omitted, and copper 430.1 is removed by the CMP step. The separate wet etch of copper 430.1 may be desirable however because it may shorten the more expensive CMP step, thus reducing the total manufacturing cost.
Oxide 410 can be patterned if desired. Metal layers 136 (FIG. 7) and dielectric layers 144 are deposited on the interposer wafer and patterned to provide interconnects and, possibly, other elements as described above. In some embodiments, metal 136 is copper and dielectric 144 is polyimide, but other materials can also be used. Some or all of dielectric layers 144 can be silicon dioxide, photosensitive benzocyclobutene (BCB), polybenzoxazole (PBO), or other materials. For a capacitor, a high dielectric constant material (such as Ta2O5) can be used. Aluminum, conductive polysilicon, and other materials can be used as layers 136. Solder wettable materials (e.g. Ni or Au) can be plated on contact pads 136C if desired.
Then the interposer wafer is thinned from the bottom to expose the gold 444. See FIG. 8. The exposed metal provides the contact pads 340 (FIG. 3) that will be soldered to BT substrate 110. The wafer thinning can be performed with any of the techniques described in the aforementioned U.S. Pat. No. 6,322,903 and U.S. patent application Ser. No. 10/410,929. See also U.S. Pat. No. 6,498,381 issued on Dec. 24, 2002 to Halahan et al. and incorporated herein by reference. In one embodiment, the wafer thinning includes a CF4 plasma etch at atmospheric pressure. The plasma etch exposes the oxide 410 and then etches the silicon 140, oxide 410 and TiW 420 selectively to copper 430.1. (Copper 430.1 is etched later as explained below.) The plasma etch etches silicon 140 faster than oxide 410, so the oxide protrudes out of the silicon on the bottom surface of the wafer after the etch. In one embodiment, the final thickness “Tsif” (marked in FIG. 8) of silicon substrate 140 is 100 μm, and it can be smaller (e.g. 35 μm). Oxide 410 and TiW 420 form 5 μm protrusions around the copper 430.1 below the silicon surface.
The plasma etch forms copper oxide (not shown) on the exposed portions of copper 430.1. The copper oxide and the copper 430.1 are etched by a wet etch to expose gold 444. The gold provides a solderable oxide-free surface. Nickel 448 will prevent copper diffusion from layer 430.2 into the solder. The copper diffusion may be undesirable because it increases the solder melting temperature. In other embodiments, the copper diffusion is desirable to achieve a certain solder hierarchy (the hierarchy of the melting temperatures of different solders) as explained below. In such embodiments, the etch of copper 430.1 can be omitted.
As stated above, gold 444 can be omitted. The etch of copper 430.1 will then expose nickel 448.
In some embodiments, the copper 430.1 is not etched away. The copper oxide (not shown) on copper 430.1 can be removed by a wet etch. The copper oxide can also be removed by a solder flux during soldering of the interposer wafer to BT substrate 110 (the soldering operation is described below). Layers 444, 448 can be omitted.
Metal contact pads 340 are metal protrusions formed by the metal layers 430.2, 448, 444, 430.1, 420 below the bottom surface of silicon 140. In some embodiments, the height Hd of metal contact pads 340 is 50 μm.
A dielectric layer (not shown) can optionally be formed on the bottom surface of the interposer to cover the silicon 140 but not the metal contact pads 340. The dielectric can be formed without photolithography. See the aforementioned U.S. Pat. Nos. 6,322,903 and 6,498,381 and U.S. patent application Ser. No. 10/410,929.
The interposer wafer can be diced if desired. The dicing can be performed at the same time as the interposer wafer thinning if vias were formed along the dicing lines (scribe lines) simultaneously with vias 330 at the stage of FIG. 4. See U.S. Pat. No. 6,498,074 issued Dec. 24, 2002 to Siniaguine et al., entitled “THINNING AND DICING OF SEMICONDUCTOR WAFERS . . . ”, incorporated herein by reference.
In some embodiments, the interposer wafer is not diced. ICs 124 will be attached to the wafer.
In some embodiments, metal 430.2 does not fill the through-silicon vias. Metal 430.2 is a thin film deposited over the via sidewalls, and it can be part of a layer 136. See the aforementioned U.S. Pat. No. 6,498,381. Also, in some embodiments the contact pads 340 do not protrude out of the bottom surface of the interposer.
Interposer 120 (diced or undiced) can be attached to a conventional BT substrate 110 with solder, conductive epoxy, anisotropic adhesive, thermocompression, or possibly by other techniques, known or to be invented. In some embodiments, however, specially processed BT substrates are used to minimize the interposer handling. The interposer handling should preferably be minimized if the interposer is thin. The interposer's silicon substrate 140 can be 100 μm or thinner, the interposer can be fragile, and its heat dissipation capability can be low. Also, the interposer can be warped. Further, some conventional soldering techniques, e.g. the techniques that involve electroplating of solder and under-ball metallurgy layers on contact pads 340, may require photolithography on the bottom surface of the interposer. The use of photolithography is undesirable because of possible wafer damage and mask misalignment. The use of a conventional BT substrate can also be difficult due to a possibly non-uniform height of protruding contact pads 340. Those contact pads 340 that have a smaller height may be unable to reach the BT substrate contact pads 350 (FIG. 3). Therefore, a specially processed BT substrate 110 is used in some embodiments, as shown in FIGS. 9 and 10.
BT substrate 110 of FIGS. 9 and 10 is formed from one or more BT layers laminated in a conventional manner. Three layers 110.1, 110.2, 110.3 are shown, but any number of layers can be present. Thin film metal layers 910 (e.g. copper) are formed on BT layers 110.i(i=1, 2, 3) and on the bottom side of layer 110.1 in a conventional manner to provide signal routing paths and ground and power planes. Layers 910 are interconnected through vias in the BT layers 110.i(i.e. 110.1, 110.2, 110.3) using known techniques to provide conductive paths between contact pads 350 and contact pads 360. The bottom metal layer 910 provides contact pads 360 (FIG. 3) at the bottom surface of BT substrate 110.
The difference between the BT substrate 110 of FIG. 9 and a conventional BT substrate is that the top contact pads 350, and the top metal layer 910, are formed below the top BT layer 110.3. In FIG. 9, the top contact pads 350 and the top metal 910 are formed on BT layer 110.2. Layer 110.3 has vias 920 exposing the contact pads 350. Vias 920 form cavities in the top surface of BT substrate 110. Silicon interposer contact pads 340 will be inserted into these cavities to form a reliable mechanical and electrical contact.
In one embodiment, each cavity 920 has a diameter Dcav=150 μm to accommodate a 50 μm to 60 μm diameter Dc of the contact pads 340. Dc can be calculated starting with the diameter Dv (FIG. 4) of via 330, by subtracting double the thickness of the layers 410, 420, 430.1, 444, 448. The depth Hcav of each cavity 920 (about equal to the thickness of layer 110.3) is 50 μm for a 50 μm height Hd of contact pads 340 (Hcav is measured to the top surface of contact pads 350).
Cavities 920 are filled with solder paste 930. In one embodiment, the solder paste is deposited to cover the BT substrate, and then is wiped off by a squeegee blade to force the solder into cavities 920 and remove it from the top surface of BT layer 110.3.
The solder is chosen to have a high melting temperature to provide a desired solder hierarchy for subsequent solder attachment of dies 124 and PCB 130. In some embodiments, the solder paste is a no-clean type NC253 available from AIM of Montreal, Canada. This paste incorporates solder flux but there is no need to clean the flux after the solder reflow.
No-flow underfill 940 (dielectric) is dispensed on BT substrate 110 at the future site of interposer 120. In some embodiments, the underfill is type STAYCHIPTM 2078E available from Cookson Electronics, a company having an office in Georgia, the United States of America. This underfill performs both the underfill function and the solder flux function. The underfill can be dispensed with a dispensing system of type CAMELOT/SPEEDLINE 1818 available from Cookson Electronics.
Interposer wafer 120 is placed on BT substrate 110 (FIG. 10). Protruding contact pads 340 enter the cavities 920 and contact the solder 930 but do not necessarily reach the metal 910 of contact pads 350. A uniform height of contact pads 340 is not required for a good electrical contact.
Underfill 940 spreads out under the interposer. In the embodiment shown, the bottom surface of silicon 140 does not reach the BT substrate. Underfill 940 helps insulate the silicon from solder 930. Therefore, it is unnecessary to form a dielectric layer on the bottom silicon surface.
The interposer placement can be performed with a placement tool of type SIPLACE F4 available from Siemens corporation of Germany. The placement tool picks up the interposer from the top by a vacuum holder 1010 schematically shown in FIG. 10. The vacuum pick-up flattens the interposer if the interposer is warped. Dielectric 144 protects the interposer from being damaged by the holder. Other placement tools, with vacuum and non-vacuum holders, known or to be invented, can also possibly be used.
The structure is heated to reflow the solder paste 930 and cure the underfill 940. The solder wets the bottom and side surfaces of copper contact pads 340. In one embodiment, the final value of the gap G1 between the silicon 140 and the BT substrate 110 is 25 μm. The gap values of 5 to 10 μm and larger are believed to be appropriate to provide sufficient electrical insulation if no dielectric is formed on the bottom surface of silicon 140. The contact 340 portion inside the vias 920 is 25 μm high (C1=25 μm in FIG. 10). The value C1 is in the range from 10 μm to 45 μm in some embodiments.
Then vacuum holder 1010 releases the interposer.
In some embodiments, the vacuum holder releases the interposer before the solder reflow. The interposer stays in place due to a surface tension between silicon 140 and the underfill 940. Multiple interposers can be placed on BT substrate 110, and the solder reflow and underfill curing can be performed in a single heating step for all the interposers. A similar technique has previously been applied for flip-chip mounting of dies on a BT substrate, as described in M. Painaik and J. Hurtley, “Process Recommendations for Assembly of Flip Chips using No-flow Underfill”, Technical Bulletin, Cookson Semiconductor.
FIG. 11 illustrates another embodiment. The BT substrate 110 is similar to the BT substrate of FIGS. 9 and 10, but a metal layer 1110 is formed on the bottom and sidewalls of each cavity 920. Metal 1110 is believed to improve the strength and the electrical conductivity of the solder bond between contact pads 340 and contact pads 350. Metal layer 1110 can be copper deposited on the BT substrate and patterned by lift-off or some other process. In FIG. 11, metal 1110 extends out of cavities 920 to the top surface of the BT layer 110.3 but does not provide any interconnects or other elements on the top surface of layer 110.3. Metal 1110 is present only in the immediate vicinity of each cavity 920. Each contact 350 includes the portions of metal layers 910, 1110 on the bottom and sidewalls of the corresponding cavity 920. In other embodiments, metal 1110 provides an additional level of interconnects and/or a power or ground plane on layer 110.3.
In the BT embodiment described above, the BT layers 110.1, 110.2, 110.3 are laminated on top of each other. Each layer 110.1, 110.2 is a solid sheet placed laminated on the structure in a solid form. In some embodiments, the top layer 110.3 is made from a material different from the material of layers 110.1, 110.2. For example, solder dam materials can be used, such as photoimageable polyimide, Dupont VACREL 8100, Dupont Flexible PhotoImageable Coverlay (PIC) 1000 & 2000, Shipley (Dynachem) DynaMASK 5000, Shipley ConforMASK 2500, and possibly others. Some of the solder dam materials (e.g. polyimide) can be deposited in a liquid (possibly viscous) form and then cured.
FIG. 12 is similar to FIG. 11, but solder balls 1210 have been attached to contact pads 136C. Solder balls 1210 eliminate the need for solder balls 370 (FIG. 3) on dies 124. The packaging substrate manufacturer can provide solder balls 1210 to simplify the die 124 attachment for the substrate buyers. Solder 1210 can be attached to the interposer at any fabrication stage. In one embodiment, solder 1210 is attached to pads 136C before the interposer wafer is thinned, i.e. before the stage of FIG. 8. The interposer wafer is mechanically stronger at this stage and its heat dissipating capability is higher, so the interposer handling is easier.
Metal 1110 may be omitted (as in FIG. 10).
In some embodiments, solder 1210 has a lower melting temperature than solder 930. Therefore, solder 930 is not melted during the attachment of dies 124.
In the embodiment of FIG. 12, solder 1210 has the same or higher melting temperature than solder 930, but the melting temperature of solder 930 is increased during the attachment of interposer 120 to BT substrate 110. The melting temperature of solder 930 becomes higher than the melting temperature of solder 1210. The melting temperature of solder 930 is increased because the copper from layer 1110 and/or layer 350 dissolves in solder 930. In the embodiment of FIG. 12, copper 430.1 was not etched away as in FIG. 8, so copper 430.1 can also dissolve in the solder. In some embodiments, solders 1210, 930 are initially the same solder (i.e. the same material), which simplifies the wafer fabrication. For example, a eutectic solder Sn/Ag3.0/Cu0.5 (known as type LF128 from AIM) can be used.
Metal contact pads 136C can be formed from a material other than copper. In some embodiments, interconnects 136 are made of copper, but contact pads 136C are plated with a layer 1220 of nickel or gold. Layer 1220 does not dissolve in solder 1210 and provides a barrier for the copper diffusion from interconnects 136, so the melting temperature of solder 1210 does not change. In other embodiments, the melting temperature of solder 1210 changes during the attachment of the interposer to substrate 110, but the melting temperature of solder 1210 remains below the melting temperature of solder 930.
FIGS. 13–14 illustrate a possible manufacturing sequence with multiple die levels 124.1, 124.2, 124.3 attached to the packaging substrate. The packaging substrate is manufactured as in FIG. 12. The interposer vias are marked 330.0 (instead of 330 as in FIG. 12), the contact pads at the bottom of the interposer are marked 340.0, and the solder at the top is marked 1210.0.
Each die 124.1 has one or more metalized through vias 330.1 formed in the die's semiconductor substrate 140.1 (e.g. monocrystalline silicon). Each via 330.1 passes between the top and bottom surfaces of substrate 140.1. Conductive paths are provided from contact pads at the top of the die 124.1 to contact pads 340.1 at the bottom of the die through the vias 330.1. Contact pads 340.1 protrude out of the respective vias 330.1. The dies 124.1 can be manufactured using the same techniques as described above for interposer 120 (involving the wafer thinning to expose the contact pads 340.1). Each die may have the same general structure as interposer 120 in FIG. 12. Of course, the circuitry in dies 124.1 does not have to be identical to the interposer circuitry, and different dies 124.1 may differ from each other. Also, contact pads 340.1 may have smaller dimensions, and may be placed closer to each other, as they do not have to meet the BT substrate dimension requirements. Pads 340.1 can be copper/nickel/gold structures as in FIG. 12, or they can be made from other materials. The metal in vias 330.1 is insulated from substrate 140.1 by a dielectric 410 (FIG. 12).
In some embodiments, dies 124.1 have devices (e.g. transistors, diodes, and others) manufactured at the top surface (active surface). Solder balls 1210.1 are attached to the contact pads on top of the dies, possibly before the wafer thinning operation exposing the contact pads 340.1, as in FIG. 12.
Dies 124.2 may be similar to dies 124.1, but there is no solder on dies 124.2. Dies 124.2 include metalized vias 330.2 in semiconductor substrates 140.2, and contact pads 340.2 protruding out of the vias. The active surface of dies 124.2 is the top surface in some embodiments.
The third level dies 124.3 are like dies 124 in FIG. 3. Their active surface is the bottom surface. Solder 370 is attached to the bottom contact pads.
The manufacturing sequence is shown in FIG. 14. Solder 1210.0 is attached to interposer 120, possibly before the interposer thinning (step 1410). Then the interposer is attached to BT substrate 110 as described above (step 1420). During this step, the melting temperature of solder 930 (FIG. 12) increases and becomes higher than the melting temperature of solder 1210.0. Solder 1210.0 may or may not be melted during this step. The melting of solder 1210.0 does not present a problem because the dies 124.1 have not yet been attached to the interposer.
In some embodiments, all of solders 120.0, 120.1, 930, 370 are initially the same material. In an illustrative example, the solders are eutectic type LF128 described above, with the initial melting temperature of 218° C. The melting temperature of solder 930 increases to about 230° C. in step 1420.
At step 1430, dies 124.1 are soldered to interposer 120 with solder 1210.0, at a temperature of about 218° C. or higher, but below 230° C. not to melt the solder 930. The copper from contact pads 340.1 dissolves in solder 1210.0 and increases its melting temperature to about 230° C. Solder 1210.1 may melt, but its melting temperature does not increase because the solder 1210.1 is not in contact with copper or other material that could increase the solder melting temperature (the top surface portions of the top contact pads of die 124.1 are made of suitable materials to ensure that the solder melting temperature does not increase).
At step 1440, dies 124.2 are attached to dies 124.1 with solder 1210.1. Solders 1210.0 and 930 do not melt. The melting temperature of solder 1210.1 is increased to about 230° C. due to the diffusion of copper from contact pads 340.2.
At step 1450, dies 124.3 are flip-chip attached to dies 124.2 with solder 370. Solders 930, 1210.0, 1210.2 do not melt. If desired, the top contact pads on dies 124.2 may have copper to increase the melting temperature of solder 370. The higher melting temperature may be desirable to prevent the solder melting during the attachment of BT substrate 110 to PCB 130 (FIG. 3). For example, the solder 134 used for the PCB attachment may be the same material (LF128) as used for the previous steps.
Many variations are possible. For example, any number of dies can be used at each level. Also, one or more dies 124.2 can be attached directly to interposer 120, i.e. there may be three levels of dies over one interposer area but only two levels of dies over another interposer area. Any number of die levels can be present in different interposer areas.
Other solder types and melting temperatures can be used, and materials other than copper can be used to increase the melting temperatures. Different materials and contact pad structures can be used in different dies. The semiconductor substrates can be different semiconductor materials.
Varying the solder melting temperature to achieve a desired solder hierarchy is not limited to the interposer structures, but may be used in other semiconductor packages, known or to be invented, with or without interposers.
In some embodiments, interposer 120 and/or dies 124.1 are provided with deep cavities 920 at the top surface to increase the mechanical strength of the solder attachment and provide a reliable electrical contact. See FIG. 15. The attachment of dies 124.1 to interposer 120 is performed by the same techniques as the attachment of the interposer to BT substrate 110. The attachment of dies 124.2 to dies 124.1 can also be performed in this way.
As shown in FIG. 15, the top dielectric layer 144 in interposer 120 is a thick layer, e.g. 50 μm thick. This can be a photoimageable material such as described above for BT layer 110.3. Openings in top layer 144 expose contact pads 136C. Contact pads 340.1 on die 124.1 protrude by some distance, e.g. 50 μm, below the bottom surface of silicon substrate 140.1 of die 124.1. The contact pads are inserted into the cavities in the top surface of the interposer. These cavities are the openings in top layer 144 that expose the contact pads 136C.
Metal layer 1110 (e.g. gold or nickel) can be deposited on the sidewalls and bottom of the vias in top layer 144 to improve the electrical connection and provide a barrier against copper 136 diffusion into solder 1210.0. Alternatively, metal 1110 can be plated only on the bottom of the openings to provide a copper diffusion barrier.
In some embodiments, the same dimensions are obtained as for the attachment between the BT substrate and the interposer, i.e. the final value of the gap between the silicon 140.1 and interposer 120 is 25 μm (gap values of 5 to 10 μm and larger are believed to be appropriate to provide sufficient electrical insulation if no dielectric is formed on the bottom surface of silicon 140.1); the contact 340.1 portion inside the cavities in top layer 144 is 25 μm high (note dimension C1 in FIG. 10). This value is in the range from 10 μm to 45 μm in some embodiments. Other dimensions can also be used.
Underfill (not shown) can be injected between the interposer and the dies 124.1 using known techniques.
In some embodiments, dies 124.1 are attached to interposer 120 before the interposer is thinned. See the aforementioned U.S. Pat. No. 6,322,903. The attachment process can be the same as the process of attaching the interposer to BT substrate 110. For example, in some embodiments, before the interposer is thinned, solder paste 1210.0 is placed into the cavities on top of the interposer, then a no-fill underfill is dispensed and a die or dies 124.1 placed on the interposer, then a heating step is performed. A copper diffusion barrier can be omitted. Copper 1110 and/or 136 on top of the interposer and copper 430.1 from dies 124.1 dissolves in solder 1210.0 to increase the solder melting temperature. Then interposer 120 is thinned and attached to BT substrate 110. Solder 1210.0 will not melt during the attachment of interposer 120 to BT substrate 110.
The invention is not limited to the embodiments described above. For example, non-eutectic solders can be used. The “melting temperature” is any temperature as high or higher than the solidus and but not higher than the liquidus. As is known, the solidus is the highest temperature at which 100% of solder is solid, i.e. the solder is just beginning to melt. The liquidus is the lowest temperature at which 100% of the solder is liquid. For a eutectic solder, the solidus and the liquidus are the same.
Also, in some embodiments, the cavities 920 (FIG. 9) extend through two or more BT layers, for example, through layers 110.3 and 110.2. Contact pads 350 can thus be formed from the metal layer 910 located between the BT layers 110.1, 110.2. The layer 910 on BT layer 110.2 can be used for interconnects, power or ground planes, or other elements as discussed above. The invention is not limited to particular materials, dimensions and processes. For example, anisotropic adhesive, conductive epoxy, and/or thermocompression can be used instead of solder. The invention is applicable to non-silicon semiconductor interposers.
The interposer may include capacitors having a capacitance of 5.0 pF or higher. For example, capacitance values of 10 pF, 100 pF, or higher have been used on circuit boards to decouple the power lines from the ground lines or for other purposes, and such capacitors can be manufactured in the interposer. Resistors having resistance values of 10 Ω and higher (e.g. 50 Ω, 100 Ω, or 150 Ω) are used on circuit boards for line termination and other purposes, and they can be manufactured in the interposer. Inductors having inductance values of 100 nH or higher are commonly used on circuit boards and can be manufactured in the interposer. The invention is not limited to particular capacitance, resistance or inductance values. Other embodiments and variations are within the scope of the invention, as defined by the appended claims.

## Claims

1. A method for manufacturing a packaging substrate, the method comprising:
(1) obtaining an interposer comprising:
a semiconductor substrate having one or more through vias therein passing between a top surface of the semiconductor substrate and a bottom surface of the semiconductor substrate, the semiconductor substrate having a substantially planar bottom surface;
a conductor in each of the through vias, each conductor providing a conductive path through the corresponding through via;
wherein the interposer comprises one or more first conductive contact pads attachable to circuitry above the interposer but not attached to any circuitry, one or more second conductive contact pads attachable to circuitry below the interposer, and one or more conductive paths each of which comprises at least one of the conductors and connects at least one of the first contact pads to at least one of the second contact pads;
(2) obtaining an intermediate substrate having a top surface facing the interposer and having a bottom surface attachable to a printed circuit board, the intermediate substrate comprising:
a dielectric substrate or a plurality of dielectric substrates attached to each other;
one or more first conductive contact pads attachable to circuitry above the intermediate substrate;
one or more second conductive contact pads attachable to a printed circuit board below the intermediate substrate;
one or more conductive paths each of which connects at least one first contact pad of the intermediate substrate to at least one second contact pad of the intermediate substrate;
(3) attaching at least one first contact pad of the intermediate substrate to at least one second contact pad of the interposer while the top surface of the interposer is not attached to any circuitry.

2. The method of claim 1 wherein the one or more second contacts of the intermediate substrate are attachable to a printed circuit board but none of the one or more contacts at the bottom surface of the intermediate substrate are attached to any circuitry during the operation (3).

3. The method of claim 1 wherein the intermediate substrate comprises said plurality of the dielectric substrates.

4. The method of claim 1 wherein the dielectric substrate or substrates are made of an organic material.

5. The method of claim 1 wherein the dielectric substrate or substrates are made of bis-maleimide triazine (BT).

6. The method of claim 1 wherein the semiconductor substrate has substantially planar top and bottom surfaces.

7. The method of claim 6 wherein the semiconductor substrate is at most 100 μm thick.

8. The method of claim 1 wherein the interposer has substantially planar top and bottom surfaces.

9. The method of claim 1 wherein the interposer further comprises solder attached to one or more of the first contact pads.

10. The method of claim 9 wherein obtaining the interposer comprises forming vias in the top surface of the semiconductor substrate, forming said conductor in each of the vias, and thinning the semiconductor substrate from the bottom surface to turn the vias into the through vias;
wherein the one or more solder balls are attached to the first contact pads before the vias become the through vias.

11. The method of claim 9 wherein the solder balls are attached to the first contact pads before the operation (3).

12. The method of claim 1 wherein the interposer is one of a plurality of interposers attached to the intermediate substrate in the attaching operation, and the attaching operation comprises:
(i) placing non-flow underfill on the intermediate substrate;
(ii) placing each interposer in sequence, one after another, on the intermediate substrate, the placing operation comprising, for each interposer:
picking up the interposer by a placement device;
placing the interposer on the underfill on the intermediate substrate; and
releasing the interposer with the placement device;
(iii) after all of the interposers have been placed, curing the underfill, but not curing the underfill until all of the interposers have been placed.

13. The method of claim 1 wherein each conductor is a metal conductor.

14. The method of claim 1 wherein the interposer comprises a capacitor having a capacitance of at least 5.0 pF, and/or a resistor having a resistance of at least 10 Ω, and/or an inductor having an inductance of at least 100 nH.

15. A manufacturing method comprising:
placing a first solder on a first structure;
soldering the first structure to a second structure with a second solder whose melting temperature is initially not higher than a melting temperature of the first solder, wherein in the soldering operation a material from at least one of the first and second structures dissolves in the second solder to raise the second solder's melting temperature and make it higher than the first solder's melting temperature;
wherein at least one of the first and second structures comprises an integrated circuit and/or an intermediate integrated circuit packaging substrate.

16. The method of claim 15 wherein the material dissolved in the second solder is from a soldered surface of the second structure.

17. The method of claim 15 wherein the first and second solders are initially identical materials.

18. The method of claim 15 further comprising, after the soldering operation, soldering the first structure to a third structure with the first solder.

19. The method of claim 18 further comprising, before the soldering to the third structure, placing a third solder on the third structure, wherein prior to the soldering of the first structure to the third structure, the first solder's melting temperature is not higher than the third solder's melting temperature, but during the soldering of the first structure to the third structure a material from at least one of the first and third structures dissolves in the first solder to raise the first solder's melting temperature and make it higher than the third solder's melting temperature.

20. The method of claim 19 wherein the first, second and third solders are initially identical materials.

21. The method of claim 15 wherein the first and second solders are eutectic.

22. The method of claim 15 wherein the second solder's melting temperature after the soldering operation is the second solder's liquidus temperature.

23. The method of claim 15 wherein each of said melting temperatures of a solder is a temperature in the range between a solidus and a liquidus of the solder.