# Patent

## Title
Method of copper/copper surface bonding using a conducting polymer for application in IC chip bonding

## Abstract

A semiconductor chip having an exposed metal terminating pad thereover, and a separate substrate having a corresponding exposed metal bump thereover are provided. A conducting polymer plug is formed over the exposed metal terminating pad. A conforming interface layer is formed over the conducting polymer plug. The conducting polymer plug of the semiconductor chip is aligned with the corresponding metal bump. The conforming interface layer over the conducting polymer plug is mated with the corresponding metal bump. The conforming interface layer is thermally decomposed, adhering and permanently attaching the conducting polymer plug with the corresponding metal bump. Methods of forming and patterning a nickel carbonyl layer are also disclosed.

## Background
This is a division of patent application Ser. No. 10/076,244, filing date Feb. 13, 2002 now U.S. Pat. No. 6,821,888, A Method Of Copper/Copper Surface Bonding Using A Conducting Polymer For Application In IC Chip Bonding, which is a Continuation-In-Part of patent application Ser. No. 09/612,576, filing date Jul. 7, 2000, A Method Of Copper/Copper Surface Bonding Using A Conducting Polymer For Application In IC Chip Bonding, now abandoned, assigned to the same assignee as the present invention, which are herein incorporated by reference in their entirety.


FIELD OF THE INVENTION
The present invention relates generally to the packaging of semiconductor devices, and more specifically to copper interconnect processes between chips and substrates in packaging processes.
BACKGROUND OF THE INVENTION
Recent integration of copper interconnect processes into IC (integrated circuit) manufacturing requires copper terminating chips to be bonded directly on the copper metal pad and circuit boards. The present invention allows the use of conducting polymers to bond copper terminating chips directly on copper substrate or printed circuit boards.
U.S. Pat. No. 5,923,955 to Wong describes a process for creating a flip-chip bonded combination for a first and second integrated circuits using a Ni/Cu/TiN structure.
U.S. Pat. No. 5,891,756 to Erickson describes a method for forming a solder bump pad, and specifically to converting a wire bond pad of a surface-mount IC device to a flip-chip solder bump pad such that the IC device can be flip-chip mounted to a substrate. The method uses a Ni layer over the pad.
U.S. Pat. No. 5,795,818 to Marrs describes a method of forming an interconnection between bonding pads on an integrated circuit chip and corresponding bonding contacts on a substrate. The method uses coined ball bond bumps.
U.S. Pat. No. 5,904,859 to Degani describes a method for applying under bump metallization (UBM) for solder bump interconnections on interconnection substrates. The UBM comprises a Cu, Cu/Cr, Cr multilayer structure.
U.S. Pat. No. 5,767,009 to Yoshida et al. describes a method of reducing cross talk noise between stacked semiconductor chips by the use of a chip on chip mounting structure.
U.S. Pat. No. 5,804,876 to Lake et al. describes a low contact resistance electrical bonding interconnect having a metal bond pad portion and conductive epoxy portion.
SUMMARY OF THE INVENTION
Accordingly, it is an object of the present invention is to provide a method of bonding a chip to a substrate without the need for a bump metal, wetting agents, and barrier materials.
Another object of the present invention is to provide a method of bonding a chip to a substrate avoiding the use of environmentally unfriendly solder and solder material.
An additional object of the present invention is to provide a method of bonding a chip to a substrate in smaller micron scale metal pitch sizes.
Other objects will appear hereinafter.
It has now been discovered that the above and other objects of the present invention may be accomplished in the following manner. Specifically, a semiconductor chip having an exposed metal terminating pad thereover, and a separate substrate having a corresponding exposed metal bump thereover are provided. A conducting polymer plug is formed over the exposed metal terminating pad. A conforming interface layer is formed over the conducting polymer plug. The conducting polymer plug of the semiconductor chip is aligned with the corresponding metal bump. The conforming interface layer over the conducting polymer plug is mated with the corresponding metal bump. The conforming interface layer is thermally decomposed, adhering and permanently attaching the conducting polymer plug of the semiconductor chip with the corresponding metal bump of the separate substrate. Methods of forming and patterning a nickel carbonyl layer are also disclosed.



BRIEF DESCRIPTION OF THE DRAWINGS
The features and advantages of the present invention will be more clearly understood from the following description taken in conjunction with the accompanying drawings in which like reference numerals designate similar or corresponding elements, regions and portions and in which:
FIGS. 1 to 6 schematically illustrate in cross-sectional representation a preferred embodiment of the present invention.



DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
Unless otherwise specified, all structures, layers, etc. may be formed or accomplished by conventional methods known in the prior art.
Accordingly, as shown in FIG. 1, semiconductor structure 200 includes an overlying final metal layer 212 connected to, for example, metal line 214 through metal via 216. Metal terminating pad 218 overlies final metal layer 212 at a predetermined position within first passivation layer 220.
Semiconductor structure 200 is understood to possibly include a semiconductor wafer or substrate, active and passive devices formed within the wafer, conductive layers and dielectric layers (e.g., inter-poly oxide (IPO), intermetal dielectric (IMD), etc.) formed over the wafer surface. The term “semiconductor structure 200” is meant to include a semiconductor chip.
Final metal layer 212 and metal terminating pad 218 are preferably comprised of copper as will be used for illustrative purposes hereafter.
Additional metal vias 216, metal lines 214, metal terminating pads 218, etc., may be formed within and over semiconductor structure 200 although for purposes of illustration, only single such structures are shown in FIG. 11. For purposes of simplicity, metal via 216, metal line 214, and final metal layer 212 are not explicitly illustrated in the following FIGS. 2–6.
Final passivation layer 222 is formed over first passivation layer 220 and copper terminating pad 218 to a thickness of from about 1000 to 10,000 Å, and more preferably from about 2000 to 5000 Å.
Opening 224 is formed within second passivation layer 222 exposing copper terminating pad 218.
As shown in FIG. 2, planarized conducting polymer plug 250 is formed within opening 224 by flowing or using a spin-on-technique on copper surfaces such a bonding pads 218 or copper tracks on printed circuit boards. Planarized conducting polymer plug 250 is preferably from about 1000 to 10,000 Å thick, and more preferably from about 3000 to 6000 Å thick.
Conducting polymer plug 250 includes, but is not restricted to doped polyacetylene, poly (para-phenylene vinylene) (PPV), or polyaniline manufactured by DuPont, Ciba Geigy, and Sieman's and others.
Conducting polymer plug 250 is used to achieve an effective copper/copper surface bonding in copper terminating IC chip pads 218. The conducting polymer has good conductive properties, is highly doped to degeneracy (see below), has good adhesive properties and very useful thermal insulation properties.
The main characteristics of the conducting polymer forming conducting polymer plug 250 is the presence of the so-called conjugated chain where the chemical bonding between the atoms in the mainly carbon “backbone” of the polymer chain alternates between single and double bonds.
There are two types of bonds namely the omega-bond and the phi-bond. Electrons in the former (omega-bond) are strongly localized and form strong bonds, in contrast to the later (phi-bond) in which the electrons form weak bonds and are not localized.
The electrons in phi-bonds can be thought of a cloud that extends along the entire length of the conjugated chain in which electrons are free to move in a similar fashion to conducting electrons in a metal. The conducting polymer is heavily doped to achieve a conduction which is comparable to a degenerate semiconductor and is sufficient enough not to perturb the device performance.
As shown in FIG. 3, interface layer 260 is formed over second passivation layer 222 and conducting polymer plug 250. Interface layer 260 is preferably comprised of nickel carbonyl (Ni(CO)4) as will be used for illustrative purposes hereafter. The material for interface layer is selected to be subject to thermal decomposition be chemical combustible.
Ni(CO)4 has a freezing point of −19° C., between −19° C. and 40° C. nickel carbonyl exists as a liquid and, at temperatures above 40° C., the following reaction takes place:

Ni(CO)4→Ni+4CO

Below 40° C., the reverse reaction takes place:

Ni+4 CO→Ni(CO)4

Two methods may be used to form Ni(CO)4 interface layer 260. In the first method, nickel is first deposited (through sputtering or electroplating) over second passivation layer 222 and conducting polymer plug 250. Then, carbon monoxide (CO) is introduced into the reaction chamber and reacts with the deposited nickel layer to form Ni(CO)4 interface layer 260. The CO may be pressurized as necessary. The temperature of the chamber and/or the temperature of the wafer must be less than 40° C. to form the Ni(CO)4 and then keep below −19° C. to maintain the Ni(CO)4 interface layer 260 as a solid.
In the second method, liquid Ni(CO)4 (at a temperature between −19° C. and 40° C.) is flowed over second passivation layer 222 and conducting polymer plug 250 and then the temperature of the chamber and/or the temperature of the wafer is lowered to less than −19° C. so as to convert the liquid Ni(CO)4 into solid Ni(CO)4 interface layer 260.
Regardless of which method is used, the temperature of the chamber and/or the temperature of the wafer must be less than −19° C. to maintain the Ni(CO)4 interface layer 260 as a solid.
As shown in FIG. 4, the excess of Ni(CO)4 interface layer 260 not over conducting polymer plug 250 is removed to form conforming Ni(CO)4 interface layer 260′ over conducting polymer plug 250. To remove the excess of Ni(CO)4 interface layer 260 not over conducting polymer plug 250, a partial chrome photomask (not shown) is formed over the wafer with the chrome portion of the photomask overlying that portion of the Ni(CO)4 interface layer 260 overlying the conducting polymer plug 250. The partial chrome photomask is then subjected to a radiation source such that radiation penetrates the photomask to the Ni(CO)4 interface layer 260 not over conducting polymer plug 250 and raising the temperature of that portion of the Ni(CO)4 interface layer 260 above 40° C. so that the reaction

Ni(CO)4→Ni+4CO

takes place, removing the Ni(CO)4 interface layer 260 not over conducting polymer plug 250. No radiation may penetrate the chrome portion of the photomask overlying the Ni(CO)4 interface layer 260 over conducting polymer plug 250 so that portion of the Ni(CO)4 interface layer 260 remains as Ni(CO)4.

Final passivation layer 222 is also then removed, exposing conducting polymer plug 250 with overlying conforming Ni(CO)4 interface layer 260′. As shown in FIG. 5, pre-formed metal bump 300 (connected to metal track 310 within substrate 320) is aligned, mechanically pressed, and mated with, conducting polymer plug 250 with overlying conforming Ni(CO)4 interface layer 260′. Substrate 320 may be a bond pad or a printed circuit board, for example.
Metal bump 300 and metal track 310 are preferably comprised of copper as will be used for illustrative purposes hereafter. Cu metal bump 300 is formed by electroless plating, at about 200° C.
As shown in FIG. 6, conforming Ni(CO)4 interface layer 260′ thermally decomposes allowing copper bump 300 to adhere directly with conducting polymer plug 250 at temperature above about 40° C.:

Ni(CO)4→Ni+4CO

With slight application of pressure, the thermal decomposition of Ni(CO)4 interface layer 260′ facilitates Ni bonding of copper bump 300 to conducting poly plug 250.

The present invention may find wide application in flip-chip, chip-on-board, and micron metal bonding and provides for micron scale bonding.
Thus, the present invention permits semiconductor chips with copper interconnect termination to be directly bonded by a flip-chip, chip-on-board, and micron metal bonding processes onto a copper substrate or printed circuit board, eliminating the need for a bump metal, wetting agent metals and barrier materials with the attendant costly process steps and materials involved. It further avoids the use of environmentally unfriendly solder and solder materials, and allows for use in smaller micron scale metal pitch sizes unlike most of the current bonding techniques.
While particular embodiments of the present invention have been illustrated and described, it is not intended to limit the invention, except as defined by the following claims.

## Claims

1. A method of patterning a solid Ni(CO)4 layer, comprising the steps of:
providing a substrate having a solid Ni(CO)4 layer formed thereover; forming a partial chrome photoresist layer over the solid Ni(CO)4 layer; the partial chrome photoresist layer having a chrome portion and a non-chrome portion; and
exposing the partial chrome photoresist layer with radiation that penetrates only the non-chrome portion of the photoresist layer to the underlying solid Ni(CO)4 layer whereby the temperature of the radiation exposed portion of the solid Ni(CO)4 layer is increased to above 40° C. so that the radiation exposed portion of the solid Ni(CO)4 layer decomposes so that the solid Ni(CO)4 layer is patterned.

2. The method of claim 1, whereby the solid Ni(CO)4 layer decomposes according to the reaction:


Ni(CO)4→Ni+4CO.

3. The method of claim 1, whereby the solid Ni(CO)4 layer has a temperature of less than −19°C.

4. The method of claim 1, whereby the solid Ni(CO)4 layer has a temperature of less than −19°C.; and the solid Ni(CO)4 layer decomposes above 40° C. according to the reaction:


Ni(CO)4→Ni+4CO.