# Patent

## Title
Electrode material, fuel cell including the same, and method of manufacturing the same

## Abstract

A novel electrode that can be used at high temperature in air, a fuel cell using the material, and a method of manufacture of the same are provided. The electrode material containing a component expressed by La1-sAsNi1-x-y-zCuxFeyBzO3-δ (wherein, A and B are at least one element independently selected from the group consisting of alkaline earth metals, transition metals excluding Fe, Ni and Cu, and rare earths excluding La, and x>0, y>0, x+y+z<1, 0≦s≦0.05, and 0≦z≦0.05) exhibits relatively high conductivity at high temperature, and has the advantage of combination with other materials in relation to coefficient of thermal expansion.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims priority under 35 U.S.C. §119 to Japanese Patent Applications No. 2010-70793 filed on Mar. 25, 2010, No. 2011-12852 filed on Jan. 25, 2011, No. 2011-50537 Mar. 8, 2011, and No. 2011-50538 Mar. 8, 2011. The entire disclosure of Japanese Patent Applications No. 2010-70793 filed on Mar. 25, 2010, No. 2011-12852 filed on Jan. 25, 2011, No. 2011-50537 Mar. 8, 2011, and No. 2011-50538 Mar. 8, 2011 are hereby incorporated herein by reference.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The technical field relates to an electrode material, a fuel cell including the same, and a method of manufacturing the same.
2. Description of the Related Art
A solid oxide fuel cell (SOFC) includes a plurality of cells having an anode, an electrolyte layer, a cathode, and a current collecting layer. In an SOFC, the cell is laminated through a separator and an interconnector. The current collecting layer is provided to reduce electrical resistance at a connection between the cathode and the separator, or with the interconnector.
An SOFC as described in Japanese Patent Application Laid-Open No. 2009-277411 includes a connecting layer arranged between the cathode and the separator. In Japanese Patent Application Laid-Open No. 2009-277411, the material used in the connecting layer includes a Pt paste or a conductive metal oxide powder. In Japanese Patent Application Laid-Open No. 2009-277411, the conductive metal oxide powder includes LaNi1-xFexO3, La1-xSrxCoO3, and the like.
In Japanese Patent No. 3414657, the cathode material includes LaNi1-xFexO3.
SUMMARY OF THE INVENTION
Pt has a high cost, and is unsuitable as a material for general purpose articles.
When La1-xSrxCoO3 is used as the material for the current collecting layer, the coefficient of thermal expansion (heat expansion ratio) of the current collecting layer material is 18-20 ppm/K, and is extremely large in comparison to the coefficient of thermal expansion of the cathode of 12.5 ppm/K when for example La1-ySryCo1-zFezO3 is the material used in the cathode. A large mismatch of coefficient of thermal expansion between the cathode material and the current collecting layer material causes cracking in the current collecting layer or delamination between the cathode and the current collecting layer.
Although the coefficient of thermal expansion of LaNi1-xFexO3 is of the order of 13.4-9.8 ppm/K, the conductivity in air at 600-1000° C. has a low value of not more than 700 S/cm. Consequently, there is a need for a new electrode material that can be used at high temperature in air.
Therefore, the object of the present invention is to provide a material or the like that exhibits improvement both in respect of coefficient of thermal expansion and conductivity for use as a material in an electrode of a fuel cell, or the like.
An electrode material according to a first aspect of the present invention has a composition expressed as La1-sAsNi1-x-y-zCuxFeyBzO3-δ. Wherein, A and B are at least one element independently selected from the group consisting of alkaline earth metals, transition metals excluding Fe, Ni and Cu, and rare earths excluding La. x, y, z and s meet x>0, y>0, x+y+z<1, 0≦s≦0.05, and 0≦z≦0.05.
This electrode material may be manufactured by a method including the step of firing a material that includes La, Ni, Cu and Fe and that has a molar ratio of La, Ni, Cu and Fe of La:Ni:Cu:Fe=1:(1−x−y):x:y (wherein 0<x, 0<y, x+y<1) at not more than 1200° C., and preferably at not more than 1200° C. in O2.



BRIEF DESCRIPTION OF DRAWINGS
Referring now to the attached drawings, which form a part of this original disclosure:
FIG. 1 is a cross sectional view of an example of a fuel cell.
FIG. 2 is an XRD pattern of a test obtained in Working Example E1.
FIG. 3 is a composition diagram of Working Examples E1-E23 and Comparative Examples A1-A6. In the figure, the coefficient of thermal expansion of the test material and the conductivity at 750° C. are both shown in each example.
FIG. 4 is a composition diagram of Working Examples F1-F23 and Comparative Examples D1-D7. In the figure, the coefficient of thermal expansion of the test material and the conductivity at 750° C. are both shown in each example.



DETAILED DESCRIPTION OF THE INVENTION
1. Electrode Material
An electrode material according to the present invention has a composition expressed as La1-sAsNi1-x-y-zCuxFeyBzO3-δ. Wherein, A and B are at least one element independently selected from the group consisting of alkaline earth metals, transition metals excluding Fe, Ni and Cu, and rare earths excluding La. x, y, z and s meet x>0, y>0, x+y+z<1, 0≦s≦0.05, and 0≦z≦0.05.
An example of an alkaline earth metal is Ca and Sr, or the like. An example of a transition metal is Sc, Ti, Cr, Mn, Co, Y, Zr, or the like. An example of a rare earth is Ce, Pr, Gd, or the like.
Element A may be at least one element selected from the group consisting of alkaline earth metals and rare earths excluding La. Element B may be at least one element selected from transition metals excluding Fe, Ni and Cu.
This material realizes both high conductivity and low coefficient of thermal expansion. More specifically, when fired in O2, the conductivity of the material at 750° C. may, be 800 S/cm or more, 850 S/cm or more, or 880 S/cm or more. Furthermore, the coefficient of thermal expansion of the material fired in O2 may be not more than 14.0 ppm/K, or not more than 13.5 ppm/K. Furthermore, when fired in air, the conductivity of the material may be at least 800 S/cm at 750° C., at least 850 S/cm, or may be at least 880 S/cm.
Furthermore, the coefficient of thermal expansion of the material when fired in air is preferably not more than 14.5 ppm/K.
In order to realize these conductivity and coefficient of thermal expansion values, a range for the value of x may be x≧0.05, or x≦0.5, or 0.05≦x≦0.5, or 0.1≦x≦0.5. In addition, a range for the value of y may be y≧0.03, or y≦0.3, or 0.03≦y≦0.3, or 0.03≦y≦0.2. A range of δ≦0.4 is preferred, a range of δ≧0.0 is more preferred, and 0.0≦δ≦0.4 still more preferred.
Higher conductivity is obtained when x≧0.05, and a still higher conductivity is obtained when x≦0.5.
The coefficient of thermal expansion is suppressed to a low value when y≧0.03. High conductivity is obtained when y≦0.3.
Still higher conductivity is obtained when δ≦0.4. Although a superior result is obtained even when δ<0.0, since costs are incurred due to the requirement to increase the partial pressure of oxygen during preparation, the range δ≧0.0 is further preferred.
At least one of s>0 or z>0 may be satisfied, or at least one of s≧0.005 and z≧0.005 may be satisfied, or at least one of s≧0.01 and z≧0.01 may be satisfied.
When s=0, and z=0, La1-sAsNi1-x-y-zCuxFeyBzO3-δ in the above formula becomes LaNi1-x-yCuxFeyO3-δ.
Since both high conductivity and low coefficient of thermal expansion are obtained, this material is suitably used as a material in a fuel cell, and in particular, is suitable for use as an electrode material of a fuel cell. As used herein, an “electrode” includes not only a cathode or an anode, but is a concept that also includes a current collecting layer.
The electrode material does not include a high-cost material such as Pt or the like as a required component, and therefore can be used as a low-cost electrode material.
The crystal phase of this material preferably contains a perovskite phase, and more preferably a perovskite single phase. In this manner, higher conductivity is realized.
Normally, all Ni in LaNiO3 are trivalent. However, a portion of the Ni may be bivalent. The heterogeneous phase that originates from the bivalent Ni is expressed as general formula Lan+1NinO3n+1 (wherein, n is 1, 2, or 3). For example when n=3, the heterogeneous phase is expressed as La4Ni3O10, and includes four La3+, two Ni3+ and one Ni2+. High conductivity is obtained when a heterogeneous phase is not present in the electrode material or when the corresponding abundance ratio of heterogeneous phase in the electrode material is low. XRD (X-ray diffraction) pattern of the heterogeneous phase exhibits a peak at 31.2°-32.3°. Therefore, no peak at this position, or a small peak is preferred in order to express high conductivity.
Since x>0 and y>0, LaNiO3 in the electrode material is simultaneously substituted with Cu and Fe. Since this simultaneous substitution achieves both high conductivity and low coefficient of thermal expansion, the addition of elements such as the elements A or B, or the like is allowed. Furthermore, additional control of the conductivity and the coefficient of thermal expansion is enabled by the added amount of the elements. When this electrode material is applied to the electrode of a fuel cell, the bonding properties of the electrode material/fuel cell material interface are improved by a configuration in which the elements contained in the layer that make contact with a layer of the electrode material are contained in the layer of the electrode material.
The electrode material may include element A and/or B as a compound other than La1-sAsNi1-x-y-xCuxFeyBzO3-δ. The proportion of A, B, La, Ni, Cu and Fe in the electrode material may be La: A:Ni:Cu:Fe:B=1−s:s:1−x−y−z:x:y:z. Furthermore, at least one of s≧0.005 and z≧0.005 may be satisfied, or at least one of s≧0.01 and z≧0.01 may be satisfied.
The electrode material containing La1-sAsNi1-x-y-zCuxFeyBzO3-δ is suitably configured as an electrode material for a fuel cell, and in particular is suitable as a material for a current collecting layer. Since this electrode material has high conductivity, when applied in a current collecting layer, electrical resistance can be reduced in the connection between a cathode and a separator or an interconnector. Furthermore since the mismatch of the coefficient of thermal expansion between the cathode and the current collecting layer is suppressed to a small value, cracking or delamination is suppressed between the cathode and the current collecting layer.
When applied to a cathode, La1-sAsNi1-x-y-zCuxFeyBzO3-δ may be used as a single material, or a composite material with a rare-earth doped ceria such as Ce0.9Gd0.1O2 (GDC) may be used. A rare-earth doped ceria is a solid electrolyte material, is known to exhibit low reactivity with perovskite oxides, and does not form a high-resistance compound even when subjected to high temperature such as during firing. When LaNi1-x-yCuxFeyO3-δ is mixed with a rare-earth doped ceria that does not have very high coefficient of thermal expansion such as 12 ppm/K, further reduction of the coefficient of thermal expansion of the mixture layer is enabled depending on the mixing ratio. Since a rare-earth doped ceria and a solid electrolyte exhibit superior interfacial adhesion, adhesion with a solid electrolyte can also be improved by forming a mixture layer, and thereby an improvement can be expected in the effect of preventing delamination resulting from a heat cycle.
2. Fuel Cell
The material in section [1.] above is used as an electrode material. A fuel cell will be described below that uses this material as a current collecting layer.
The fuel cell according to the present embodiment is includes a fuel cell 1 as shown in FIG. 1 (hereinafter simply referred to as “cell”), and an interconnector (not shown). A plurality of cells 1 are stacked, and the interconnectors are arranged between the cells 1. The cells 1 are electrically connected by the interconnector.
The cells 1 are ceramic thin plates having a thickness of a level of 0.5-5 mm. As illustrated in FIG. 1, the fuel cell 1 according to the present embodiment includes an anode 11, an electrolyte layer (solid electrolyte layer) 12, a cathode 13, and a current collecting layer 14.
The material of the anode 11 includes, for example, NiO—YSZ. More specifically, the thickness of the anode 11 is substantially 0.5-5 mm. The anode 11 contains NiO and is imparted with conductivity by a reduction treatment.
The electrolyte layer 12 is provided between the cathode 13 and the anode 11. A ceria-based material which consists of ceria and a rare-earth may be used as the material for the electrolyte layer 12. The ceria-based material includes for example GDC (gadolinium doped ceria), SDC (samarium doped ceria), and the like. The concentration of the rare earth in the ceria-based material is preferably 5-20 mol %. Rare earth stabilized zirconium may also be used.
The thickness of the current collecting layer 12 is for example 20 μm or less.
The material used as the cathode for example includes LSCF (lanthanum strontium cobalt ferrite). The thickness of the cathode 13 is approximately 5-50 μm.
The current collecting layer 14 includes the electrode material as described above. The thickness of the current collecting layer 14 is approximately 5-200 μm. The current collecting layer 14 for example is prepared by firing a green body which consists of the cathode 13 and the green tape of the electrode material attached to the cathode 13.
The cell 1 may include a component such as another layer, and may vary features such as the shape, material or dimension of various components.
3. Method of Manufacturing Electrode Material
(1) First Manufacturing Method
The method of manufacture for an electrode material in [1.] above may include the step of firing a material that includes La, Ni, Cu and Fe, and has a molar ratio of La, Ni, Cu and Fe of La:Ni:Cu:Fe=1:(1−x−y):x:y at not more than 1200° C. (firing step). The manufacturing method includes preparation of a starting material that includes La, Ni, Cu, and Fe in these proportions.
The starting materials used in the firing step may be obtained by mixing a metal oxide powder and/or a hydroxide powder as described above, or may be obtained by a liquid phase synthesis method or a co-precipitation method in which the starting material is a metal alkoxide or a metal nitrate.
The preferred range for x, y, and δ has been described above. In other words, the starting material preferably is prepared so that the molar ratio of La, Ni, Cu and Fe is La:Ni:Cu:Fe=1:0.2-0.92:0.05-0.5:0.03-0.03. Reduction of Ni and Cu tends to occur under high temperature in air. As a result, the firing step in the manufacturing of this material is preferably conducted at not more than 1200° C. to prepare δ in a suitable range. The firing step is preferably performed at not more than 1200° C. in O2.
The firing step may be considered as a single step, or may include two or more thermal treatments having different temperature conditions. At least one treatment of these treatments may execute thermal treatment of the starting material above to a temperature of at least 1100° C. The firing step may include a thermal treatment set to having a temperature condition set to less than 1100° C. The temperature condition in any of the thermal treatments may be set to a temperature condition of not more than 1200° C. Although Fe has relatively low reactivity, production of single-phase perovskite structures is facilitated by thermal treatment of the starting materials to at least 1100° C.
Before the firing step, a calcination process may be executed to calcine the starting material at a temperature of at least 1100° C. When executing the calcination process, the temperature during the firing step may be less than 1100° C. Furthermore, the calcination process may be performed at not more than 1200° C.
However, the firing temperature conditions, and the time and the like required for firing may be varied in response to the starting material particle diameter and other conditions.
(2) Second Manufacturing Method
The firing step of a method of manufacturing the electrode material including the element A and/or the element B may include a step of placing a green body being a mixture containing La, Ni, Cu and Fe in the above proportions adjacent to a layer containing the element A and/or the element B, and firing. In this manner, the element A and/or the element B diffuse in the fired body, and thereby obtains La1-sAsNi1-x-y-zCuxFeyBzO3-δ.
The layer that contains the element A and/or the element B includes a SOFC solid electrolyte, a cathode, or an interconnector, or the like. In particular, the alkaline earth metal may be contained in a cathode material such as La1-xSrxCoO3 or La1-xSrxCo1-yFeyO3, or the like, or an interconnector material such as La1-xCaxCrO, or the like. A rare earth may be contained in the electrolyte material such as GDC (gadolinium doped ceria), a cathode material, an interconnector material, or the like. The transition metal element may be contained in the electrolyte material such as YSZ (yttria stabilized zirconia), a cathode material, an interconnector material, or the like.
Other conditions may include applying the same conditions as the first manufacturing method in (1) above.
(3) Third Manufacturing Method
The firing step in a method of manufacture for an electrode material containing the element A and/or the element B may include the step of firing a starting material that includes La, Ni, Cu, Fe, the element A and the element B at a molar ratio of La:Ni:Cu:Fe:A:B=(1−s):(1−x−y−s):x:y:s:z at not more than 1200° C.
The starting material may be prepared so that the molar ratio of La, Ni, Cu and Fe is La:Ni:Cu:Fe=(0.95-1):(0.15-0.92):(0.05-0.5):(0.03-0.3). Furthermore, the range for s and z may be as described above.
Other conditions may include applying the same conditions as the first manufacturing method in (1) above or the second manufacturing method in (2) above.
EXAMPLES
Preparation of Test Sample and Measurement of Characteristics
i. Working Examples E1-E23
Firing in O2 
Simultaneous substitution using Fe and Cu was executed in LaNiO3-δ. The characteristics of the resulting test sample were examined by changing the proportions of the Cu element and the Fe element.
(i-1) Preparation of Test Sample
After drying powders of lanthanum hydroxide, nickel oxide, copper oxide, and iron oxide for 12 hours at 110° C., weighing is performed at the predetermined molar ratios shown in Table 1.
These weighed powders are mixed with water, and then dried. Thereafter, a mixed powder is prepared by passing through a sieve.
Then, placing the mixed powder in an aluminum crucible provided with a lid, a solid state reaction is performed by thermal treatment for 12 hours at a predetermined calcination temperature shown in the Table 1 in O2 to thereby obtain respective perovskite phase calcined powders. FIG. 2 illustrates XRD pattern of the calcined powder in Working Example 1.
The calcined powder is pulverized, and pressed uniaxially to thereby obtain a green body using a cold isostatic press (CIP).
After placing the green body in an aluminum crucible with a lid, a fired body is obtained by a thermal treatment at a predetermined firing temperature for 12 hours as shown in Table 1 in O2 (Working Example E1-E23).
(i-2) Measurement of Characteristics
(Density)
The density of the fired body is calculated from the dimensions and the weight, and the results are shown in Table 1.
(Conductivity)
A test piece of 3×4×40 mm is cut from the fired body, and the conductivity of the fired body is measured at 600° C.-900° C. in air using a DC four-terminal method. Since the conductivity is also dependent on the density in addition to the composition ratio of the sintered body, the portion depending on the density of the measurement value is corrected using Equation (1) below derived with reference to Etsuro YAMADA (author) “Shigen to Sozai” vol. 119, No. 1, pages 1-8 published in 2003 based on the equation of Meredith et al.

λe={(2+0.5φv)×(2−0.54φv)}/{(2−φv)×(2−2φv)}×λc  (1)

Wherein:

    
    
        measurement value=λc,
        conductivity after correction=λe
        (1−density)=φv
    
    


The conductivity after correction is shown in Table 1.
(Coefficient of Thermal Expansion)
A test piece of 3×4×20 mm was cut from the sintered body, and the coefficient of thermal expansion of the fired body was measured at 40-1000° C. in air using a dilatometer. The results are shown in Table 1.
(Oxygen Nonstoichiometry)
In some of the Working Examples, chemical analysis was performed by pulverizing a portion of the sintered body in a mortar. The molar ratio and the oxygen nonstoichiometry δ of the element is calculated from the resulting weight ratio of the elements. The results are shown in Table 7.
ii. Comparative Examples A1-A6
Substitution using Fe and Cu was executed with respect to LaNiO3-δ, and firing was performed in O2. In other words, the ratio of the Cu element and the Fe element is different from the Working Examples, and the setting is adapted so that x or y takes a value of 0 (zero).
More specifically, in addition to the starting material ratio and other conditions as shown in Table 2, a test sample was prepared using the same operation as section i. above (firing in O2), and the characteristics are measured. The results are shown in Table 2.
iii. Comparative Examples B1-B3
In the following comparative examples, simultaneous substitution was executed using Co (cobalt) and Fe to obtain a sintered body. In the comparative examples, the composition of the test sample is expressed as LaNi1-a-bFeaCobO3-δ.
More specifically, in addition to the starting material ratio and other conditions as shown in Table 3, a test sample was prepared using the same operation as section i. above (firing in O2) using starting materials including powders of lanthanum hydroxide, nickel oxide, cobalt oxide, and iron oxide, and the characteristics are measured. The results are shown in Table 3.
iv. Comparative Examples C1-C4
In the following comparative examples, a sintered body was formed in simultaneous substitution using Fe and Sr (strontium) that is an alkaline earth metal. The composition of the test sample is expressed as La1-cSrcNi1-a-bFeaCobO3-δ.
More specifically, in addition to the starting material ratio and other conditions as shown in Table 4, a test sample was prepared using the same operation as section i. above (firing in O2) using starting materials including powders of lanthanum hydroxide, strontium carbonate, nickel oxide, cobalt oxide, and iron oxide, and the characteristics are measured. The results are shown in Table 4.
v. Working Examples F1-F23
Firing in Air
A test sample was prepared with reference to the starting material ratio and other conditions as shown in Table 5 using lanthanum hydroxide, nickel oxide, copper oxide and iron oxide, and the characteristics are measured. In particular, in the Working Examples, firing is executed by thermal treatment for one hour at a predetermined firing temperature shown in Table 5 in air. In addition to the conditions shown in Table 5, the same treatment as section i. above (firing in O2) was executed. The results are shown in Table 5.
vi. Comparative Examples D1-D7
In the same manner as Working Examples F1-F23, simultaneous substitution using Fe and Cu was performed with respect to LaNiO3-δ, and then firing is executed in air. The ratio of the Cu element and the Fe element is different from the Working Examples, and a setting is adapted so that x or y takes a value of 0 (zero). More specifically, apart from the starting material ratio and other conditions as shown in Table 6, the same treatment as section i. above (firing in O2) was executed to thereby obtain a test sample, and the characteristics thereof are measured. The results are shown in Table 6.
vii. Working Examples G1-G3
Working Example G1
Calcined powder is obtained by the operation of Working Example E1. After pulverizing the calcined powder, a green body was obtained by uniaxial pressing at 200 kgf/cm2. A fired body is obtained by placing the green body in an aluminum crucible with a lid and thermal treatment for 12 hours at 1000° C. in air.
Working Examples G2 and G3
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, and cobalt oxide that are used in the ratios as illustrated in Table 8, in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a fired body. The characteristics of the resulting fired body are measured by the same operations as those described in i. above. The results are shown in Table 8.
viii. Working Examples H1-H5
Working Example H1
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, and zirconium oxide are used in the ratios as illustrated in Table 9 in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a calcined powder. After the calcined powder is pulverized, mixing is performed by addition of a solvent such as terpineol, and a binder such as ethylcellulose to obtain a paste. This paste is used to form a layer by screen-printing onto a YSZ fired body that is one type of SOFC electrolyte material. The resulting laminated body is dried, and a laminated fired body is obtained by thermal treatment at 1000° C. in air for one hour.
The characteristics of the resulting laminated fired body are measured using the same operations as those described in i. above, and the results are shown in Table 9.
Working Example H2
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, and manganese oxide are used in the ratios as illustrated in Table 9 in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a calcined powder. A paste was obtained from the calcined powder by the same manner as Working Example H1. This paste is used to form a layer by screen-printing onto a LaSrMnO3 fired body that is one type of SOFC cathode material. The resulting laminated body is dried and thermally treated in the same manner as Working Example H1 to obtain a laminated fired body.
The characteristics of the resulting laminated fired body are measured using the same operations as those described in i. above, and the results are shown in Table 9.
However, conductivity is configured as follows. The LaSrMnO3 fired body acting as a substrate and the layer formed by screen-printing (hereinafter termed the “LaNiCuFeO3 layer”) both exhibit conductivity. Therefore, firstly the conductivity of the whole laminated fired body is obtained in the same manner as i. above. When the conductivity is assumed to be conductivity resulting from the parallel resistance of LaSrMnO3 substrate with the LaNiCuFeO3 layer formed by screen-printing, the conductivity of the LaNiCuFeO3 layer may be calculated from the conductivity of the overall laminated fired body and the conductivity of LaSrMnO3 substrate that is separately measured.
Working Example H3
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, and gadolinium oxide are used in the ratios as illustrated in Table 9 in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a calcined powder. A paste was obtained from the calcined powder by the same manner as Working Example H1. This paste is used to form a layer by screen-printing onto a GDC fired body that is one type of SOFC electrolyte material. The resulting laminated body is dried and thermally treated in the same manner as Working Example H1 to obtain a laminated fired body.
The characteristics of the resulting laminated fired body are measured using the same operations as those described in i. above, and the results are shown in Table 9.
Working Example H4
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, and calcium carbonate are used in the ratios as illustrated in Table 9 in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a calcined powder. After pulverization of the calcined powder, a paste was obtained from the calcined powder by the same manner as Working Example H1. This paste is used to form a layer by screen-printing onto a LaCaCrO3 fired body that is one type of SOFC interconnector material. The resulting laminated body is dried and thermally treated in the same manner as Working Example H1 to obtain a laminated fired body.
The characteristics of the resulting laminated fired body are measured using the same operations as those described in i. above, and the results are shown in Table 9. However since the LaCaCrO3 fired body that acts as a substrate also exhibits conductivity, the measurement of the conductivity is performed in the same manner as Working Example H2.
Working Example H5
Starting materials include powders of lanthanum hydroxide, nickel oxide, copper oxide, iron oxide, strontium carbonate, zirconium oxide are used in the ratios as illustrated in Table 9 in conjunction with operations that are the same as those described in Working Example G1 to thereby obtain a calcined powder. A paste was obtained from the calcined powder by the same manner as Working Example H1. This paste is used to form a layer by screen-printing onto a LaSrCoFeO3 fired body that is an SOFC cathode material. The resulting laminated body is dried and thermally treated in the same manner as Working Example H1 to obtain a laminated fired body.
The characteristics of the resulting laminated fired body are measured using the same operations as those described in i. above, and the results are shown in Table 9. However since the LaSrCoFeO3 fired body that acts as a substrate also exhibits conductivity, the measurement of the conductivity is performed in the same manner as Working Example H2.
[Results]
As shown in FIG. 2, the crystal phase of the sintered body in Working Example E1 is a perovskite single phase. Although this is not shown, the crystal phase of any of Working Example E1-E23, F1-F23, G1-G3 and H1-H5, and Comparative Examples A1-A6, B1-B3, C1-C4, and D1-D7 is also a perovskite single phase.
In the Working Examples E1-E23 that are fired in O2 as shown in Table 1, relatively high conductivity of at least 680 S/cm is obtained at not more than 900° C., and in particular, conductivity of at least 800 S/cm is obtained at temperature of 750° C. Furthermore in Working Examples E1-E23, coefficient of thermal expansion not more than 14.0 ppm/K is obtained.
Next, reference is made to the results in Comparative Examples A1-A6, B1-B3, and C1-C4 (Table 2 to Table 4). These comparative examples are fired in O2 in the same manner as Working Examples E1-E23. However, in contrast to Working Examples E1-E23, Comparative Examples A1-A6 is subjected to single substitution using Cu or Fe, and simultaneous substitution with Cu and Fe is not executed.
As shown in Table 2, LaNiO3-δ that does not include Cu and Fe has low conductivity and high coefficient of thermal expansion (Comparative Example A1).
When executing single substitution using Cu (Comparative Examples A4-A6, FIG. 3), as shown in Table 2, although relatively high conductivity is exhibited in 0.05≦x≦0.2, the coefficient of thermal expansion is high. When x=0.5, the conductivity is conspicuously small and the coefficient of thermal expansion is even higher. The reason for the reduction in conductivity is thought to be due to the fact that mobility of the carrier is reduced by removal of oxygen from the test sample and due to a reduction in the carrier concentration as a result of conversion of a large amount of Cu to a divalent by the removal of oxygen from the test material. The increase in the coefficient of thermal expansion is considered to be due to the increase in the lattice volume due to removal of oxygen under high temperature.
When executing simple substitution using Fe (Comparative Examples A2-A3, FIG. 3), as shown in Table 2, the coefficient of thermal expansion is suppressed to a low value when 0.3≦x≦0.5. However, conductivity is reduced as the degree of substitution is increased. The reduction in the conductivity is considered to result from a reduction in the carrier concentration due to an absence of Cu when only Fe substitution is executed, or a reduction in the mobility of the carrier, or both.
As shown in Table 3, almost no improvement in conductivity was exhibited by simultaneous substitution of Fe and Co (Comparative Examples B1-B3). Furthermore, in these comparative examples, the coefficient of thermal expansion is large, and preferred characteristics as an electrode material are not observed.
As shown in Table 4, conductivity is extremely low, and the coefficient of thermal expansion is large due to simultaneous substitution of Sr, Fe and Co (Comparative Examples C1-C4).
As described above, Working Examples E1-E23 that are fired in O2 obtain a substance that is adapted for use as an electrode material in relation to both conductivity and coefficient of thermal expansion, in comparison to single substitution with Fe or Cu (Comparative Examples A1-A6), or simultaneous substitution with Fe and Co (Comparative Examples B1-B3), or with Fe, Co and Sr (Comparative Examples C1-C4).
Next, a test sample that is fired in air was examined.
As shown in Table 5, in Working Examples F1-F23 which are fired in air, a relatively large conductivity of at least 680 S/cm was obtained at 900° C., and in particular, conductivity of at least 800 S/cm is obtained at 750° C. Furthermore in Working Examples F1-F23, coefficient of thermal expansion not more than 14.5 ppm/K, and in particular not more than 14.4 ppm/K is obtained.
In contrast, as shown in Table 6, LaNiO3-δ that does not include Cu and Fe exhibits reduced conductivity when fired in air (Comparative Example D1).
When executing single substitution using Cu (Comparative Examples D4-D7, FIG. 4), as shown in Table 6, conductivity is conspicuously reduced. The reason for the reduction in conductivity is considered to be the fact that mobility of the carrier and the concentration of carrier are reduced as a result of removal of oxygen from the test sample during firing since Fe is absent.
As described above, Working Examples F1-F23 that are fired in air obtain superior characteristics as an electrode material in relation to conductivity or coefficient of thermal expansion, or in relation to both conductivity and coefficient of thermal expansion, in comparison to simultaneous substitution with Fe and Co (Comparative Examples B1-B3), or with Fe, Co and Sr (Comparative Examples C1-C4).
As clearly demonstrated by the above description, a material having the composition of La1-sAsNi1-x-y-zCuxFeyBzO3-δ. (Working Examples E1-E23, F1-F23, G1-G3, H1-H5) obtains superior characteristics as an electrode material used in a fuel cell. In other words, preferred characteristics as an electrode material for a fuel cell are obtained both in respect of conductivity and coefficient of thermal expansion by simultaneous substitution of Cu and Fe.
The reason for such superior characteristics will be examined below.
It is likely that the carrier concentration is increased in La1-sAsNi1-x-y-zCuxFeyBzO3-δ as a result of substitution of Ni by trivalent Cu which includes a higher number of electrons, and consequently the conductivity is improved.
Generally, it is considered to be difficult to achieve a sufficient increase in a carrier concentration with substitution only with Cu since oxygen in the test sample is removed under high temperature in air, and therefore forms bivalent Cu. However, the Gibbs energy of Fe which substituted at the same time is lower than the Gibbs energy of Ni or Cu, and therefore simultaneous substitution with Fe is thought to suppress removal of oxygen from the test sample. Consequently, Ni in LaNi1-x-yCuxFeyO3-δ can be substituted to a large degree by trivalent Cu.
Generally, electrons migrate via oxygen in an electrode material having a perovskite structure, and therefore when there is a deficiency due to removal of oxygen, there is a risk that the mobility of the carrier will be reduced. In the material system of the working examples, since the mobility of the carrier is maintained by suppressing removal of oxygen by simultaneous substitution of Fe, a reduction in conductivity under a condition of high temperature in air, and in particular under a conditions of removal of oxygen can be suppressed.
When there is a deficiency in oxygen, a material that has a perovskite structure is expected to undergo an expansion in lattice volume as a result of an increase in the distance between the atoms that constitute the material. In the material system according to the working examples, it is considered to be likely that the coefficient of thermal expansion is reduced as a result of the reduction in the exchange of oxygen by Fe between the atmosphere and the test sample, and more particularly as a result of suppressing removal of oxygen under conditions of an air and high temperature that facilitate oxygen removal.
It is thought that the conductivity is increased by increasing the concentration of the carrier by producing trivalent Cu as the value for δ that expresses the oxygen nonstoichiometry becomes smaller. Furthermore, it is considered that the conductivity is increased, and the mobility of the carrier is increased in the test sample as complete crystallization in which there is no deficiency in the atoms constituting the perovskite is approached.
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Table 8
Table 9

















TABLE 1














CALCINATION
FIRING




WORKING






TEMPERATURE
TEMPERATURE
FIRING TIME
FIRING


EXAMPLE
Cu x
Fe y
La(OH)3
NiO
CuO
Fe2O3
[° C.]
[° C.]
[hour]
ATMOSPHERE





E1
0.20
0.05
1.000
0.750
0.200
0.025
1100
1100
12
OXYGEN


E2
0.05
0.05
1.000
0.900
0.050
0.025
1200
1200
12
OXYGEN


E3
0.20
0.30
1.000
0.500
0.200
0.150
1100
1100
12
OXYGEN


E4
0.25
0.05
1.000
0.700
0.250
0.025
1100
1100
12
OXYGEN


E5
0.30
0.03
1.000
0.670
0.300
0.015
1100
1100
12
OXYGEN


E6
0.15
0.10
1.000
0.750
0.150
0.050
1100
1100
12
OXYGEN


E7
0.20
0.10
1.000
0.700
0.200
0.050
1100
1100
12
OXYGEN


E8
0.25
0.10
1.000
0.650
0.250
0.050
1100
1100
12
OXYGEN


E9
0.15
0.15
1.000
0.700
0.150
0.075
1100
1100
12
OXYGEN


E10
0.15
0.05
1.000
0.800
0.150
0.025
1100
1000
12
OXYGEN


E11
0.20
0.03
1.000
0.770
0.200
0.015
1100
1000
12
OXYGEN


E12
0.35
0.05
1.000
0.600
0.350
0.025
1100
1100
12
OXYGEN


E13
0.10
0.05
1.000
0.850
0.100
0.025
1100
1100
12
OXYGEN


E14
0.30
0.05
1.000
0.650
0.300
0.025
1100
1100
12
OXYGEN


E15
0.40
0.05
1.000
0.550
0.400
0.025
1100
1100
12
OXYGEN


E16
0.45
0.05
1.000
0.500
0.450
0.025
1100
1100
12
OXYGEN


E17
0.20
0.15
1.000
0.650
0.200
0.075
1100
1100
12
OXYGEN


E18
0.10
0.20
1.000
0.700
0.100
0.100
1100
1100
12
OXYGEN


E19
0.20
0.20
1.000
0.600
0.200
0.100
1100
1100
12
OXYGEN


E20
0.30
0.20
1.000
0.500
0.300
0.100
1100
1100
12
OXYGEN


E21
0.05
0.25
1.000
0.700
0.050
0.125
1100
1100
12
OXYGEN


E22
0.20
0.25
1.000
0.550
0.200
0.125
1100
1100
12
OXYGEN


E23
0.10
0.30
1.000
0.600
0.100
0.150
1100
1100
12
OXYGEN












COEFFICIENT OF












WORKING
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







E1
92.5
1585.9
1450.7
1376.0
1290.6
1176.9
13.2



E2
68.0
963.2
870.6
823.6
773.1
682.2
13.3



E3
79.5
1035.4
943.2
899.5
835.0
728.0
13.0



E4
79.3
1841.0
1612.5
1498.8
1391.7
1186.8
13.3



E5
80.8
1806.7
1570.0
1459.3
1347.0
1132.6
13.3



E6
75.2
1355.0
1211.7
1145.6
1077.1
916.5
13.2



E7
79.9
1606.4
1419.1
1329.4
1243.6
1066.0
13.1



E8
84.5
1629.7
1423.3
1334.3
1241.2
1051.7
13.1



E9
80.9
1611.7
1456.7
1385.7
1291.2
1136.2
13.2



E10
58.9
1194.6
1074.4
1015.5
957.6
837.0
13.4



E11
61.2
1090.2
967.3
909.5
851.7
730.8
13.4



E12
97.8
1533.4
1409.3
1341.9
1270.8
1117.8
13.4



E13
74.2
1089.0
978.4
923.8
869.2
762.3
13.4



E14
96.5
1744.7
1541.7
1444.7
1346.8
1151.9
13.4



E15
95.0
1353.4
1243.9
1184.4
1121.7
986.6
13.6



E16
97.0
1262.4
1131.1
1068.3
997.9
863.6
14.0



E17
80.4
1455.8
1290.7
1215.6
1133.6
976.5
13.1



E18
77.3
1427.8
1290.6
1227.6
1143.9
1006.6
13.1



E19
81.6
1390.4
1232.8
1161.0
1082.6
932.7
13.2



E20
91.8
1325.7
1202.9
1140.7
1072.9
936.2
13.4



E21
71.4
1145.1
1056.8
1014.0
965.9
884.1
13.1



E22
80.3
1211.9
1089.0
1032.0
960.2
832.2
13.0



E23
75.5
1090.3
1000.0
956.8
900.4
806.1
13.1



























TABLE 2














CALCINATION
FIRING
FIRING



COMPARATIVE






TEMPERATURE
TEMPERATURE
TIME
FIRING


EXAMPLE
Cu x
Fe y
La(OH)3
NiO
CuO
Fe2O3
[° C.]
[° C.]
[hour]
ATMOSPHERE





A1
—
—
1
1
—
—
900
900
12
OXYGEN


A2
—
0.3
1
0.7
—
0.15
1200
1200
12
OXYGEN


A3
—
0.5
1
0.5
—
0.25
1200
1200
12
OXYGEN


A4
0.05
—
1
0.95
0.05
—
900
900
12
OXYGEN


A5
0.2
—
1
0.8
0.2
—
900
900
12
OXYGEN


A6
0.5
—
1
0.5
0.5
—
900
900
12
OXYGEN












COEFFICIENT OF












COMPARATIVE
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







A1
55
867.5
792.7
755.5
721.6
647.7
13.8



A2
66.8
746.5
704
681.4
663.2
629.5
13



A3
62.8
261.5
260.7
259.2
257.5
253.7
12.7



A4
63.8
1275.6
1076
1023.8
976.4
881.2
14.1



A5
71.9
1208.9
1064.9
997.6
928.6
789.3
13.8



A6
69.7
406.7
355.6
333.2
306.9
261.1
15.7



























TABLE 3














CALCINATION
FIRING
FIRING



COMPARATIVE






TEMPERATURE
TEMPERATURE
TIME
FIRING


EXAMPLE
Fe a
Co b
La(OH)3
NiO
Fe2O3
Co3O4
[° C.]
[° C.]
[TIME]
ATMOSPHERE





B1
0.10
0.40
1.000
0.500
0.050
0.133
900
1200
12
OXYGEN


B2
0.25
0.25
1.000
0.500
0.125
0.083
900
1200
12
OXYGEN


B3
0.40
0.10
1.000
0.500
0.200
0.033
900
1200
12
OXYGEN












COEFFICIENT OF












COMPARATIVE
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







B1
78.4
854.8
822.2
805.5
789.5
754.4
15.6



B2
76.6
569.8
559.4
553.1
545.7
533.8
14.8



B3
71.5
381.5
379.9
379.4
376.3
368.7
13.5





























TABLE 4
















CALCINATION
FIRING
FIRING
FIRING


COMPARATIVE








TEMPERATURE
TEMPERATURE
TIME
ATMOS-


EXAMPLE
Sr c
Fe a
Co b
La(OH)3
SrCO3
NiO
Fe2O3
Co3O4
[° C.]
[° C.]
[hour]
PHERE





C1
0.10
0.40
0.10
0.900
0.100
0.500
0.200
0.033
900
900
12
OXYGEN


C2
0.20
0.40
0.10
0.900
0.200
0.500
0.200
0.033
900
900
12
OXYGEN


C3
0.10
0.25
0.25
0.900
0.100
0.500
0.125
0.083
900
900
12
OXYGEN


C4
0.10
0.10
0.40
0.900
0.100
0.500
0.050
0.133
900
900
12
OXYGEN












COEFFICIENT OF












COMPARATIVE
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







C1
62.1
251.3
241.1
235.0
229.3
213.3
13.7



C2
63.2
240.6
222.8
211.6
201.1
176.1
16.6



C3
61.5
351.4
335.0
325.3
315.3
289.4
16.1



C4
64.2
456.8
435.5
422.9
409.9
376.2
17.3



























TABLE 5














CALCINATION
FIRING
FIRING



WORKING






TEMPERATURE
TEMPERATURE
TIME
FIRING


EXAMPLE
Cu x
Fe y
La(OH)3
NiO
CuO
Fe2O3
[° C.]
[° C.]
[hour]
ATMOSPHERE





F1
0.15
0.05
1.000
0.800
0.150
0.025
1100
1000
1
AIR


F2
0.20
0.05
1.000
0.750
0.200
0.025
1100
1000
1
AIR


F3
0.25
0.05
1.000
0.700
0.250
0.025
1100
1000
1
AIR


F4
0.20
0.03
1.000
0.770
0.200
0.015
1100
1000
1
AIR


F5
0.30
0.03
1.000
0.670
0.300
0.015
1100
1000
1
AIR


F6
0.15
0.10
1.000
0.750
0.150
0.050
1100
1000
1
AIR


F7
0.20
0.10
1.000
0.700
0.200
0.050
1100
1000
1
AIR


F8
0.25
0.10
1.000
0.650
0.250
0.050
1100
1000
1
AIR


F9
0.15
0.15
1.000
0.700
0.150
0.075
1100
1000
1
AIR


F10
0.05
0.05
1.000
0.900
0.050
0.025
1100
1000
1
AIR


F11
0.35
0.05
1.000
0.600
0.350
0.025
1100
1000
1
AIR


F12
0.20
0.30
1.000
0.500
0.200
0.150
1100
1000
1
AIR


F13
0.10
0.05
1.000
0.850
0.100
0.025
1100
1000
1
AIR


F14
0.30
0.05
1.000
0.650
0.300
0.025
1100
1000
1
AIR


F15
0.40
0.05
1.000
0.550
0.400
0.025
1100
1000
1
AIR


F16
0.45
0.05
1.000
0.500
0.450
0.025
1100
1000
1
AIR


F17
0.20
0.15
1.000
0.650
0.200
0.075
1100
1000
1
AIR


F18
0.10
0.20
1.000
0.700
0.100
0.100
1100
1000
1
AIR


F19
0.20
0.20
1.000
0.600
0.200
0.100
1100
1000
1
AIR


F20
0.30
0.20
1.000
0.500
0.300
0.100
1100
1000
1
AIR


F21
0.05
0.25
1.000
0.700
0.050
0.125
1100
1000
1
AIR


F22
0.20
0.25
1.000
0.550
0.200
0.125
1100
1000
1
AIR


F23
0.10
0.30
1.000
0.600
0.100
0.150
1100
1000
1
AIR












COEFFICIENT OF












WORKING
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







F1
71.9
1151.8
1040.2
983.0
922.2
801.1
13.6



F2
79.0
1531.7
1401.1
1329.0
1246.5
1136.7
13.4



F3
83.6
1464.9
1338.3
1246.0
1159.4
985.5
14.1



F4
79.1
1405.1
1254.8
1173.2
1091.4
953.9
13.9



F5
85.4
1766.8
1545.9
1430.3
1322.3
1142.7
14.4



F6
73.3
1045.0
946.5
894.7
848.2
725.7
13.7



F7
77.4
1066.0
952.7
896.3
846.1
726.7
13.9



F8
82.0
1384.5
1218.0
1131.5
1076.8
895.2
14.2



F9
73.3
1256.0
1126.0
1066.3
1004.8
876.6
13.8



F10
69.4
961.7
844.3
803.0
764.7
687.8
13.5



F11
91.9
1298.2
1193.1
1140.6
1075.9
946.3
13.6



F12
77.9
968.4
882.2
845.5
781.0
680.9
12.5



F13
75.6
1058.7
945.9
896.1
847.2
749.5
13.6



F14
91.7
1522.1
1364.2
1275.7
1195.9
1023.9
13.6



F15
90.3
1145.8
1053.1
1006.7
949.6
835.3
13.8



F16
95.0
1132.8
1014.9
961.5
895.4
774.9
14.2



F17
84.4
1164.0
1035.9
972.5
920.0
785.8
13.3



F18
72.3
1156.8
1037.1
982.1
925.4
807.4
13.5



F19
77.5
1181.2
1051.2
986.9
933.6
797.4
13.4



F20
90.0
1122.9
1018.9
969.6
908.8
792.9
13.4



F21
66.4
914.5
843.2
811.2
779.4
715.9
12.9



F22
77.1
1087.8
979.2
928.8
868.3
749.2
13.2



F23
72.2
941.5
862.7
828.4
780.2
698.4
12.7



























TABLE 6














CALCINATION
FIRING
FIRING



COMPARATIVE






TEMPERATURE
TEMPERATURE
TIME
FIRING


EXAMPLE
Cu x
Fe y
La(OH)3
NiO
CuO
Fe2O3
[° C.]
[° C.]
[hour]
ATMOSPHERE





D1
—
—
1.000
1.000
—
—
900
1000
1
AIR


D2
—
0.30
1.000
0.700
—
0.150
1200
1000
1
AIR


D3
—
0.50
1.000
0.500
—
0.250
1200
1000
1
AIR


D4
0.05
—
1.000
0.950
0.050
—
900
1000
1
AIR


D5
0.10
—
1.000
0.900
0.100
—
900
1000
1
AIR


D6
0.20
—
1.000
0.800
0.200
—
900
1000
1
AIR


D7
0.50
0.000
1.000
0.500
0.500
0.000
900
1000
1
AIR












COEFFICIENT OF












COMPARATIVE
FIRED BODY
CONDUCTIVITY [S/cm]
LINEAR EXPANSION
















EXAMPLE
DENSITY [%]
600° C.
700° C.
750° C.
800° C.
900° C.
[ppm/K]







D1
60.1
469.1
433.5
415.9
399.8
364.7
13.6



D2
59.8
389.4
369.9
361.6
354.1
341.0
11.5



D3
58.1
183.2
185.0
185.7
186.4
187.5
10.8



D4
62.1
683.9
586.1
560.5
537.2
490.6
13.9



D5
78.1
694.6
624.9
591.1
559.2
495.2
13.8



D6
82.5
625.1
555.3
522.7
489.2
421.6
13.9



D7
66.9
385.6
337.1
316.5
291.0
247.6
15.6





















TABLE 7









WORKING
MOLAR RATIO
















EXAMPLE
La
Ni
Cu
Fe
O
δ



















E1
1
0.75
0.20
0.05
3.0
0.0



E3
1
0.50
0.19
0.31
3.0
0.0



E4
1
0.70
0.25
0.05
2.9
0.1



E5
1
0.67
0.30
0.03
2.8
0.2



E9
1
0.68
0.16
0.16
2.8
0.2



E13
1
0.60
0.35
0.05
2.7
0.3



F2
1
0.76
0.19
0.05
2.8
0.2



F3
1
0.70
0.25
0.05
2.7
0.3



F5
1
0.68
0.29
0.03
2.6
0.4



F9
1
0.68
0.16
0.16
2.7
0.3























TABLE 8









A
M
CALCINATION
FIRING
FIRING
















WORKING


ATOMIC

ATOMIC

TEMPERATURE
TEMPERATURE
TIME


EXAMPLE
Cu X
Fe y
ELEMENT
s
ELEMENT
z
[° C.]
[° C.]
[hour]





G1
0.20
0.05
—
—
—
—
1100
1000
1


G2
0.20
0.05
—
—
Co
0.005
1100
1000
1


G3
0.20
0.05
—
—
Co
0.010
1100
1000
1




















COEFFICIENT







OF LINEAR



WORKING
FIRING
FIRED BODY
CONDUCTIVITY
EXPANSION



EXAMPLE
ATMOSPHERE
DENSITY [%]
at 750° C. [S/cm]
[ppm/K]







G1
AIR
61.0
1030.7
13.2



G2
AIR
65.0
1102.8
13.4



G3
AIR
67.0
1154.4
13.5























TABLE 9









A
M
CALCINATION
FIRING
FIRING
















WORKING


ATOMIC

ATOMIC

TEMPERATURE
TEMPERATURE
TIME


EXAMPLE
Cu X
Fe Y
ELEMENT
s
ELEMENT
z
[° C.]
[° C.]
[hour]





H1
0.20
0.05
—
—
Zr
0.010
1100
1000
1


H2
0.20
0.05
—
—
Mn
0.020
1100
1000
1


H3
0.20
0.05
Gd
0.005
—
—
1100
1000
1


H4
0.20
0.05
Ca
0.005
—
—
1100
1000
1


H5
0.20
0.05
Sr
0.005
Zr
0.010
1100
1000
1




















COEFFICIENT







OF LINEAR



WORKING
FIRING
FIRED BODY
CONDUCTIVITY
EXPANSION



EXAMPLE
ATMOSPHERE
DENSITY [%]
at 750° C. [S/cm]
[ppm/K]







H1
AIR
55.0
968.9
13.1



H2
AIR
65.0
1000.8
13.2



H3
AIR
59.0
994.6
13.2



H4
AIR
51.0
905.6
13.2



H5
AIR
57.0
974.0
13.2

## Claims

1. An electrode material containing a composition expressed by La1-sAsNi1-x-y-zCuxFeyBzO3-δ, wherein, A and B are at least one element independently selected from the group consisting of alkaline earth metals, transition metals excluding Fe, Ni and Cu, and rare earths excluding La, and x>0, y>0, x+y+z<1, 0≦s≦0.05, 0≦z≦0.05, and 0.0≦δ≦0.4.

2. The electrode material according to claim 1 comprising a perovskite phase.

3. The electrode material according to claim 1 wherein x≧0.05.

4. The electrode material according to claim 1 wherein x≦0.5.

5. The electrode material according to claim 1 wherein y≧0.03.

6. The electrode material according to claim 1 wherein y≦0.3.

7. The electrode material according to claim 1 having conductivity at 750° C. is 800 S/cm or more.

8. The electrode material according to claim 1 having coefficient of thermal expansion is 14.5 ppm/K or less.

9. The electrode material according to claim 1 wherein element A is at least one element selected from the group consisting of alkaline earth metals and rare earths excluding La, and element B is at least one element selected from transition metals excluding Fe, Ni and Cu.

10. A fuel cell comprising
an anode;
a cathode;
a solid electrolyte layer provided between the anode and the cathode; and
a current collecting layer including the electrode material according to claim 1, and provided on the cathode on the opposite side to the solid electrolyte.

11. A method of manufacturing an electrode material comprising the step of:
firing a starting material including La, Ni, Cu and Fe, and having a molar ratio of La, Ni, Cu and Fe such that La:Ni:Cu:Fe=1:(1−x−y):x:y (wherein 0<x, 0<y, x+y<1) at not more than 1200° C., to form a composition expressed by La1-sAsNi1-x-y-zCuxFeyBzO3-δ, wherein, A and B are at least one element independently selected from the group consisting of alkaline earth metals, transition metals excluding Fe, Ni and Cu, and rare earths excluding La, and x>0, y>0, x+y+z<1, 0≦s≦0.05, 0≦z≦0.05, and 0.0≦δ≦0.4.

12. The method of manufacturing according to claim 11 wherein the firing atmosphere in the firing step is an oxygen atmosphere.

13. The method of manufacturing according to claim 11 wherein the firing step includes thermal treatment of the starting material at 1100° C. or more.

14. The method of manufacturing according to claim 11 wherein before the firing step, a calcination processing step is included for thermal treatment of the starting material at 1100° C. or more.

15. The method of manufacturing according to claim 11 wherein before the firing step, a calcination processing step is included for thermal treatment of the starting material at 1100° C. or more, and the firing step is executed at less than 1100° C.