# Patent

## Title
Tool with tool body and protective layer system

## Abstract

There is proposed a tool with a tool body and a wear resistant layer system, which layer system comprises at least one layer of MeX. Me comprises titanium and aluminum and X is nitrogen or carbon. The tool has a tool body of high speed steel (HSS) or of cemented carbide, but it is not a solid carbide end mill and not a solid carbide ball nose mill. In the MeX layer the quotient QI as defined by the ratio of the diffraction intensity I(200) to I(111) assigned respectively to the (200) and (111) plains in the X ray diffraction of the material using θ-2θ method is selected to be ≧1. Further, the I(200) is at least twenty times larger than the intensity average noise value, both measured with a well-defined equipment and setting thereof.

## Background
This application is a continuation of application Ser. No. 09/537,292, filed Mar. 29, 2000 which is a division of Ser. No. 08/928,652 filed on Sep. 12, 1997 now U.S. Pat. No. 6,071,560.


BACKGROUND AND SUMMARY OF THE INVENTION
The description incorporates U.S. Pat. No. 5,709,784 by reference herein. This application is related to U.S. Pat. No. 6,071,560 issued Jun. 6, 2000 and U.S. Pat. No. 6,274,249 issued Aug. 14, 2001.
The present invention is directed on a tool with a tool body and a wear resistant layer system, wherein the layer system comprises at least one layer of MeX, wherein

    
    
        Me comprises titanium and aluminum,
        X is at least one of nitrogen and of carbon.
    
    


DEFINITION


    
    
        The term QI is defined as the ratio of the diffraction intensities I(200) to I(111), assigned respectively to the (200) and (111) plains in the X ray diffraction of a material using the θ-2θ method. Thus, there is valid QI=I(200)/I(111). The intensity values were measured with the following equipment and with the following settings:
    
    















Siemens Diffractometer D500



















Power:
Operating voltage: 30 kV




Operating current: 25 mA



Aperture Diaphragms:
Diaphragm position I: 1°




Diaphragm position II: 0.1°



Detector Diaphragm:
Soller slit



Time constant:
4 s



2θ angular speed:
0.05°/min



Radiation:
Cu-Kα(0.15406 nm)










When we refer to “measured according to MS” we refer to this equipment and to these settings. Thereby, all quantitative results for QI and I throughout this application have been measured by MS.

    
    
        We understand by “tool body” the uncoated tool.
        We understand under “hard material” a material with which tools which are mechanically and thermally highly loaded in operation are coated for wear resistance. Preferred examples of such materials are referred to below as MeX materials.
    
    


It is well-known in the tool-protecting art to provide wear resistant layer systems which comprise at least one layer of a hard material, as defined by MeX.
The present invention has the object of significantly improving the lifetime of such tools. This is resolved by selecting for said at least one layer a QI value, for which there is valid

QI≧1

and wherein the tool body is made of high speed steel (HSS) or of cemented carbide, whereby said tool is not a solid carbide end mill or a solid carbide ball nose mill. Further, the value of I(200) is higher by a factor of at least 20 than the intensity noise average level as measured according to MS.

According to the present invention it has been recognised that the QI values as specified lead to an astonishingly high improvement of wear resistance, and thus of lifetime of a tool, if such a tool is of the kind as specified.
Up to now, application of a wear resistant layer systems of MeX hard material was done irrespective of interaction between tool body material and the mechanical and thermal load the tool is subjected to in operation. The present invention thus resides on the fact that it has been recognised that an astonishing improvement of wear resistance is realised when selectively combining the specified QI value with the specified kind of tools, thereby realising a value of I(200) higher by a factor of at least 20 than the average noise intensity level, both measured with MS.
With respect to inventively coating cemented carbide tool bodies, it has further been recognised that a significant improvement in lifetime is reached if such cemented carbide tools are inserts, drills or gear cutting tools, as e.g. hobs or shaper cutters, whereby the improvement is especially pronounced for such inserts or drills.
The inventively reached improvement is even increased if QI is selected to be at least 2, and an even further improvement is realised by selecting QI to be at least 5. The largest improvements are reached if QI is at least 10. It must be stated that QI may increase towards infinite, if the layer material is realised with a unique crystal orientation according to a diffraction intensity I(200) at a vanishing diffraction intensity I(111). Therefore, there is not set any upper limit for QI which is only set by practicability.
As is known to the skilled artisan, there exists a correlation between hardness of a layer and stress therein. The higher the stress, the higher the hardness.
Nevertheless, with rising stress, the adhesion to the tool body tends to diminish. For the tool according to the present invention, a high adhesion is rather more important than the highest possible hardness. Therefore, the stress in the MeX layer is advantageously selected rather at the lower end of the stress range given below.
These considerations limit in practice the QI value exploitable.
In a preferred embodiment of the inventive tool, the MeX material of the tool is titanium aluminum nitride, titanium aluminum carbonitride or titanium aluminum boron nitride, whereby the two materials first mentioned are today preferred over titanium aluminum boron nitride.
In a further form of realisation of the inventive tool, Me of the layer material MeX may additionally comprise at least one of the elements boron, zirconium, hafnium, yttrium, silicon, tungsten, chromium, whereby, out of this group, it is preferred to use yttrium and/or silicon and/or boron. Such additional element to titanium and aluminum is introduced in the layer material, preferably with a content i, for which there is valid

0.05 at. %≦i≦60 at. %,

taken Me as 100 at %.

A still further improvement in all different embodiments of the at least one MeX layer is reached by introducing an additional layer of titanium nitride between the MeX layer and the tool body with a thickness d, for which there is valid

0.05 μm≦d≦5 μm.

In view of the general object of the present invention, which is to propose the inventive tool to be manufacturable at lowest possible costs and thus most economically, there is further proposed that the tool has only one MeX material layer and the additional layer which is deposited between the MeX layer and the tool body.
Further, the stress σ in the MeX is preferably selected to be

    
    
        1 GPa≦σ≦4 GPa, thereby most preferably within the range

1.5 GPa≦σ≦2.5 GPa.

    
    


The content x of titanium in the Me component of the MeX layer is preferably selected to be

    
    
        70 at %≦x≦40 at %, thereby in a further preferred embodiment within the range

65 at %≦x≦55 at %.

    
    


On the other hand, the content y of aluminum in the Me component of the MeX material is preferably selected to be

    
    
        30 at %≦y≦60 at %, in a further preferred embodiment even to be

35 at %≦y≦45 at %.

    
    


In a still further preferred embodiment, both these ranges, i.e. with respect to titanium and with respect to aluminum are fulfilled.
The deposition, especially of the MeX layer, may be done by any known vacuum deposition technique, especially by a reactive PVD coating technique, as e.g. reactive cathodic arc evaporation or reactive sputtering. By appropriately controlling the process parameters, which influence the growth of the coating, the inventively exploited QI range is realised.
To achieve excellent and reproducible adhesion of the layers to the tool body a plasma etching technology was used, as a preparatory step, based on an Argon plasma as described in Appendix A, which document is integrated to this description by reference, with respect to such etching and subsequent coating. This document accords with the U.S. application Ser. No. 08/710,095 of the same inventor (two inventors!) and applicant as the present application.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a diagram showing the relationship between nitrogen partial pressure and bias voltage of the tool body as applied for reactive cathodic arc eruption in accordance with the present invention;
FIG. 2 is a diagram showing the relationship between typical intensity and diffraction angle <θ where the titanium aluminum nitride layer is deposited in the QI≧1 region;
FIG. 3 is a diagram similar to FIG. 2 but with the layer deposited on a QI≦1 region; and
FIG. 4 is a diagram similar to FIGS. 2 and 3 for the working point P1 in FIG. 1.



DETAILED DESCRIPTION OF THE INVENTION
EXAMPLES 1
An arc ion plating apparatus using magnetically controlled arc sources as described in Appendix A was used operated as shown in table 1 to deposit the MeX layer as also stated in table 1 on cemented carbide inserts. The thickness of the MeX layer deposited was always 5 μm. Thereby, in the samples Nr. 1 to 7, the inventively stated QI values where realised, whereas, for comparison, in the samples number 8 to 12 this condition was not fulfilled. The I(200) value was always significantly larger than 20 times the noise average value, measured according to MS. The coated inserts were used for milling under the following conditions to find the milling distance attainable up to delamination. The resulting milling distance according to the lifetime of such tools is also shown in table 1.
Test Cutting Conditions
















Material being cut:
SKD 61 (HRC45)



Cutting speed:
100 m/min



Feed speed:
0.1 m/edge



Depth of cut:
2 mm










The shape of the inserts coated and tested was in accordance with SEE 42 TN (G9).
It is clearly recognisable from table 1 that the inserts, coated according to the present invention, are significantly more protected against delamination than the inserts coated according to the comparison conditions.
Further, the result of sample 7 clearly shows that here the stress and thus hardness of the layer was reduced, leading to lower cutting distance than would be expected for a high QI of 22.5, still fulfilling the stress-requirements as defined above.












TABLE 1











Attainable






Cutting Dis-



Coating Conditions

tance (m)


















Bias

Arc



QI =

(distance




Voltage
N2 pressure
Current



I(200)/
Residual
till delami-


Sample No.
(−V)
(mbar)
(A)
Layer
x
y
I(111)
Stress GPa
nation)
Remarks




















Present












Invention


1
60
2.0 × 10−2
150
(TixAly)N
0.5
0.5
1.5
5.2
2.2 m (2.1 m)


2
60
8.0 × 10−2
150
(TixAly)N
0.5
0.5
6.7
4.8
2.8 m (2.5 m)


3
40
2.0 × 10−2
150
(TixAly)N
0.5
0.5
8.1
4.2
8.8 m (8.5 m)
face












lapping


4
40
3.0 × 10−2
150
(TixAly)N
0.4
0.6
10.2
3.9
3.9 m (3.5 m)


5
40
0.5 × 10−2
150
(TixAly)N
0.5
0.5
6.0
5.8
2.0 m (1.7 m)


6
30
2.0 × 10−2
150
(TixAly)N
0.5
0.5
15.4
2.5
4.2 m (4.0 m)


7
20
2.0 × 10−2
150
(TixAly)N
0.5
0.5
22.5
1.2
3.3 m (3.3 m)


Comparison


8
60
0.5 × 10−2
150
(TixAly)N
0.5
0.5
0.8
6.1
1.0 m (0.8 m)


9
100
2.0 × 10−2
150
(TixAly)N
0.5
0.5
0.7
5.5
0.9 m (0.9 m)


10
100
3.0 × 10−2
150
(TixAly)N
0.5
0.5
0.9
4.8
0.8 m (0.7 m)


11
150
2.0 × 10−2
150
(TixAly)N
0.5
0.5
0.2
7.2
0.1 m (0.1 m)


12
100
0.5 × 10−2
150
(TixAly)N
0.4
0.6
0.1
6.8
0.2 m (0.1 m)









EXAMPLES 2
The apparatus as used for coating according to Example 1 was also used for coating the samples Nr. 13 to 22 of table 2. The thickness of the overall coating was again 5 μm. It may be seen that in addition to the coating according to Example 1 there was applied an interlayer of titanium nitride between the MeX layer and the tool body and an outermost layer of the respective material as stated in table 2. The condition with respect to I(200) and average noise level, measured according to MS was largely fulfilled.
It may be noted that provision of the interlayer between the MeX layer and the tool body already resulted in a further improvement. An additional improvement was realised by providing an outermost layer of one of the materials titanium carbonitride, titanium aluminum oxinitride and especially with an outermost layer of aluminum oxide. Again, it may be seen that by realising the inventively stated QI values with respect to the comparison samples number 19 to 22, a significant improvement is realised.
The outermost layer of aluminum oxide of 0.5 μm thickness, was formed by plasma CVD.
The coated inserts of cemented carbide were tested under the same cutting conditions as those of Example 1, QI was measured according to MS.














TABLE 2






Inter-




QI =
Attainable Cutting



layer



Outermost
I(200)/
Distance (m) (distance


Sample No.
(μm)
TiAl Layer
x
y
Layer
I(111)
till delamination)






















Present









Invention


13
TiN
(TixAly)N
0.5
0.5
—
1.5
4.5 m (4.2)



(0.4 μm)
(4.6 μm)


14
TiN
(TixAly)N
0.5
0.5
TiCN
7.2
7.8 (7.6 m)



(0.4 μm)
(4.1 μm)


(0.5 μm)


15
TiN
(TixAly)N
0.5
0.5
TiCN
6.8
6.2 m (5.5 m)



(0.4 μm)
(4.4 μm)


(0.5 μm)


16
TiCN
(TixAly)N
0.5
0.5
(TiAl)NO
5.2
6.2 m (6.0 m)



(0.4 μm)
(4.1 μm)


(0.5 μm)


17
TiN
(TixAly)N
0.5
0.5
Al2O3
12.5
10.1 m (9.8 m)



(0.4 μm)
(4.1 μm)


(0.5 μm)


18
TiN
(TixAly)N
0.5
0.5
Al2O3
7.0
9.8 m (9.5 m)



(0.4 μm)
(4.1 μm)


(0.5 μm)


Comparison


19
TiN
(TixAly)N
0.5
0.5
—
0.8
1.5 m (1.2 m)


20
TiN
(TixAly)N
0.5
0.5
TiCN
0.8
1.9 m (1.5 m)


21
TiN
(TixAly)N
0.5
0.5
TiCN
0.7
1.8 m (1.5 m)


22
TiN
(TixAly)N
0.5
0.5
(TiAl)NO
0.1
0.6 m (0.4 m)









EXAMPLE 3
Again, cemented carbide inserts were coated with the apparatus of Example 1 with the MeX layer as stated in table 3, still fulfilling the QI conditions as inventively stated and, by far, the condition of I(200) with respect to average noise level, measured according to MS. Thereby, there was introduced one of zirconium, hafnium, yttrium, silicon and chromium, with the amount as stated above, into Me.
The coated inserts were kept in an air oven at 750° C. for 30 min. for oxidation. Thereafter, the resulting thickness of the oxide layer was measured. These results are also shown in table 3. For comparison, inserts coated inventively with different Me compounds of the MeX material were equally tested. It becomes evident that by adding any of the elements according to samples 23 to 32 to Me, the thickness of the resulting oxide film is significantly reduced. With respect to oxidation the best results were realised by adding silicon or yttrium.
It must be pointed out, that it is known to the skilled artisan, that for the MeX material wear resistant layers there is valid: The better the oxidation resistance and thus the thinner the resulting oxide film, the better the cutting performance.













TABLE 3











Thick-








ness of








Oxide








Film


Sample No.
Layer Composition
w
x
y
z
(μm)





















Present








Invention


23
(TixAlyYz)N

0.48
0.5
0.02
0.7


24
(TixAlyCrz)N

0.48
0.5
0.02
0.9


25
(TixAlyZrz)N

0.48
0.5
0.02
0.7


26
(TixAlyYz)N

0.25
0.5
0.25
0.1


27
(TixAlyZrz)N

0.25
0.5
0.25
0.5


28
(TixAlyWz)N

0.4
0.5
0.1
0.8


29
(TixAlySiz)N

0.4
0.5
0.1
0.1


30
(TixAlySiz)N

0.48
0.5
0.02
0.2


31
(TixAlyHfz)N

0.4
0.5
0.1
0.9


32
(TixAlyYzSiw)N
0.1
0.3
0.5
0.1
0.05


Comparison


33
(TixAly)N

0.4
0.6

1.8


34
(TixAlyNbz)N

0.4
0.5
0.1
2.5


35
(TixAlyTaz)N

0.4
0.5
0.1
3.3









EXAMPLE 4
An apparatus and a coating method as used for the samples of Example 1 was again used.
HSS drills with a diameter of 6 mm were coated with a 4.5 μm MeX and a TiN interlayer was provided between the MeX layer and the tool body, with a thickness of 0.1 μm. The test condition were:
















Tool:
HSS twist drill, dia. 6 mm



Material:
DIN 1.2080 (AISI D3)



Cutting parameters:
vc = 35 m/min




f = 0.12 mm/rev.




15 mm deep blind holes with coolant.





























TABLE 4







Bias
N2-
Arc







Number of



Voltage
Pressure
current
inter-





Residual
drilled



(−V)
(mbar)
(A)
layer
layer
x
y
z
QI
Stress (GPa)
holes



























Present













Invention


36
40
3.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4

5.4
2.1
210






0.1 μm


37
40
3.0 × 10−2
200
TiN
(TixAlyBz)N
0.58
0.4
0.02
3.8
2.3
190






0.1 μm


Comparison


38
150
1.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4

0.03
4.5
30






0.1 μm


39
150
1.0 × 10−2
200
TiN
(TixAlyBz)N
0.58
0.4
0.02
0.1
4.8
38






0.1 μm









The lifetime of the tool was determined by the number of holes which could be drilled before failure of the drill.
The results of the inventively coated drills are shown as samples No. 36 and 37 in Table 4, the samples No. 38 and 39 again show comparison samples. Again, I(200) exceeded 20 times intensity average noise level by far, for samples 36, 37, as measured by MS.
EXAMPLE 5
Again, the apparatus and method as mentioned for Example 1 was used for coating HSS roughing mills with a diameter of 12 mm with a 4.5 μm MeX layer. There was provided a titanium nitride interlayer with a thickness of 0.1 μm between the MeX layer and the tool body. The test conditions were:
















Tool:
HSS roughing mill, dia. 12 mm




z = 4



Material:
AISI H13 (DIN 1.2344)




640 N/mm2



Cutting parameters:
vc = 47.8 m/min




ft = 0.07 mm




ap = 18 mm




ae = 6 mm




climb milling, dry.










The HSS rouging mill was used until an average width of flank wear of 0.2 mm was obtained.
Sample No. 40 in Table No. 5 shows the results of the inventively coated tool, sample 41 is again for comparison. Again, I(200) of sample Nr. 40 fulfilled the condition with respect to noise, as measured by MS.


















TABLE 5







Bias
N2-
Arc






Cutting



Voltage
Pressure
current
inter-




Residual
distance



(−V)
(mbar)
(A)
layer
layer
x
y
QI
Stress (GPa)
(m)


























Present
40
3.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
5.4
2.1
35 m


invention



0.1 μm


40


Comparison
150
1.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
0.03
4.5
11 m


41



0.1 μm





(chipping












and peel-












ing off)









EXAMPLE 6
Again, the apparatus and coating method according to Example 1 was used. Solid carbide end mills with a diameter of 10 mm with 6 teeth were coated with a 3.0 μm MeX layer. There was provided a titanium nitride interlayer with a thickness of 0.08 μm between the MeX and the tool body. Test conditions for the end mills were:
















Tool:
Solid carbide end mill, dia. 10 mm




z = 6



Material:
AISI D2 (DIN 1.2379)




60 HRC



Cutting parameters:
vc = 20 m/min




ft = 0.031 mm




ap = 15 mm




ae = 1 mm




Climb milling, dry










The solid carbide end mills were used until an average width of flank wear of 0.20 mm was obtained. It is to be noted that solid carbide end mills do not belong to that group of tool which is inventively coated with a hard material layer having QI≧1. From the result in Table 6 it may clearly be seen that for this kind of tools QI>1 does not lead to an improvement. Again, the I(200) to noise condition, measured with MS, was fulfilled for sample No. 42, for sample No. 43 the I(111) to noise condition was fulfilled.


















TABLE 6







Bias
N2-
Arc






Cutting



Voltage
Pressure
current
inter-




Residual
distance



(−V)
(mbar)
(A)
layer
layer
x
y
QI
Stress (GPa)
(m)


























Present
40
3.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
5.0
2.2
17 m


Invention



0.08 μm


42


Comparison
150
1.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
0.05
4.7
32 m


43



0.08 μm









EXAMPLE 7
Again, an apparatus and method as used for the samples of Example 1 were used.
Solid carbide drills with a diameter of 11.8 mm were coated with a 4.5 μm MeX layer. There was provided a TiN interlayer between the MeX layer and the tool body.













Test conditions:



















Tool:
Solid carbide drill, diam. 11.8 mm



Workpiece:
Cast iron GG25



Machining conditions:
vc = 110 m/min




f = 0.4 mm/rev.




Blind hole 3 × diam.




No coolant










The solid carbide drills were used until a maximum width of flank wear of 0.8 mm was obtained. The I(200) to noise condition was again fulfilled, measured with MS.


















TABLE 7







Bias
N2-
Arc






Drilling



Voltage
Pressure
current
inter-




Residual
distance



(−V)
(mbar)
(A)
layer
layer
x
y
QI
Stress (GPa)
(m)


























Present
40
3.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
5.4
2.1
  95 m


Invention



0.1 μm


44


Comparison
150
1.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
0.03
4.5
48.5 m


45



0.1 μm









EXAMPLE 8
Again, the apparatus and method as stated in Example 1 were used.
Cemented carbide inserts for turning with a shape in accordance with CNGP432 were coated with a 4.8 μm MeX layer. There was provided a TiN interlayer with a thickness of 0.12 μm between the MeX layer and the tool body. The test conditions were:
















Tool:
Carbide insert (CNGP432)



Material:
DIN 1.4306(X2CrNi 1911)



Cutting parameters:
vc = 244 m/min




f = 0.22 mm/rev.




ap = 1.5 mm




with emulsion










The tool life was evaluated in minutes. The indicated value is an average of three measurements. Again, I(200)/noise condition, measured with MS, was fulfilled.


















TABLE 8







Bias
N2-
Arc






Tool



Voltage
Pressure
current
inter-




Residual
life



(−V)
(mbar)
(A)
layer
layer
x
y
QI
Stress (GPa)
(min)


























Present
40
3.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
5.8
1.9
18.1 min


Invention



0.12 μm


46


Comparison
150
1.0 × 10−2
200
TiN
(TixAly)N
0.6
0.4
0.04
4.9
 5.5 min


47



0.12 μm









In FIG. 1 there is shown, with linear scaling a diagram of nitrogen partial pressure versus bias voltage of the tool body as applied for reactive cathodic arc evaporation as the reactive PVD deposition method used to realise the Examples which were discussed above.
All the process parameters of the cathodic arc evaporation process, namely

    
    
        arc current;
        process temperature;
        deposition rate;
        evaporated material;
        strength and configuration of magnetic field adjacent the arc source;
        geometry and dimensions of the process chamber and of the workpiece tool to be treated

were kept constant. The remaining process parameters, namely partial pressure of the reactive gas—or total pressure—and bias voltage of the tool body to be coated as a workpiece and with respect to a predetermined electrical reference potential, as to the ground potential of the chamber wall, were varied.

    
    


Thereby, titanium aluminum nitride was deposited. With respect to reactive gas partial pressure and bias voltage of the tool body, different working points were established and the resulting QI values at the deposited hard material layers were measured according to MS.
It turned out that there exists in the diagram according to FIG. 1 an area P, which extends in a first approximation linearly from at least adjacent the origin of the diagram coordinates, wherein the resulting layer leads to very low XRD intensity values of I(200) and I(111). It is clear that for exactly determining the limits of P, a high number of measurements will have to be done. Therein, none of the I(200) and I(111) intensity values is as large as 20 times the average noise level, measured according to MS.
On one side of this area P and as shown in FIG. 1 QI is larger than 1, in the other area with respect to P, QI is lower than 1. In both these areas at least one of the values I(200), I(111) is larger than 20 times the average noise level, measured according to MS.
As shown with the arrows in FIG. 1, diminishing of the partial pressure of the reactive gas—or of the total pressure if it is practically equal to the said partial pressure—and/or increasing of the bias voltage of the tool body being coated, leads to reduction of QI. Thus, the inventive method for producing a tool which comprises a tool body and a wear resistant layer system, which latter comprises at least one hard material layer, comprises the steps of reactive PVD depositing the at least one hard material layer in a vacuum chamber, thereby preselecting process parameter values for the PVD deposition process step beside of either or both of the two process parameters, namely of partial pressure of the reactive gas and of bias voltage of the tool body. It is one of these two parameters or both which are then adjusted for realising the desired QI values, thus, and according to the present invention, bias voltage is reduced and/or partial reactive gas pressure is increased to get QI values, which are, as explained above, at least larger than 1, preferably at least larger than 2 or even 5 and even better of 10. Beside the inventively exploited QI value, in this “left hand” area, with respect to P, I(200) is larger, mostly much larger than 20 times the average noise level of intensity, measured according to MS.
In FIG. 2 a typical intensity versus angle 2θ diagram is shown for the titanium aluminum nitride hard material layer deposited in the QI≧1 region according to the present invention of FIG. 1, resulting in a QI value of 5.4. The average noise level N* is much less than I(200)/20. Measurement is done according to MS.
In FIG. 3 a diagram in analogy of that in FIG. 2 is shown, but the titanium aluminum nitride deposition being controlled by bias voltage and nitrogen partial pressure to result in a QI≦1. The resulting QI value is 0.03. Here the I(111) value is larger than the average noise level of intensity, measured according to MS.
Please note that in FIG. 1 the respective QI values in the respective regions are noted at each working point measured (according to MS).
In FIG. 4 a diagram in analogy to that of the FIGS. 2 and 3 is shown for working point P1 of FIG. 1. It may be seen that the intensities I(200) and I(111) are significantly reduced compared with those in the area outside P. None of the values I(200) and I(111) reaches the value of 20 times the noise average level N*.
Thus, by simply adjusting at least one of the two QI-controlling reactive PVD process parameters, namely of reactive gas partial pressure and of workpiece bias voltage, the inventively exploited QI value is controlled.
In FIG. 1 there is generically shown with ∂QI<0 the adjusting direction for lowering QI, and it is obvious that in opposite direction of adjusting the two controlling process parameters, and increase of QI is reached.

## Claims

1. A tool with a tool body and a wear resistant layer system, said layer system comprising at least one layer of MeX, wherein
Me comprises titanium and aluminum; 
X is at least one of nitrogen and of carbon 
and wherein said layer has a QI value 


QI≧5 


and said tool body is of one of the materials 
high speed steel (HSS); 
cemented carbide, 
and wherein said tool is not a solid carbide end mill and not a solid carbide ball nose mill 
whereby the value of I (200) is at least 20 times the intensity average noise value, both measured according to MS.

2. The tool of claim 1, wherein the tool is selected from a group consisting of a cemented carbide insert, a cemented carbide drill and a cemented carbide gear cutting tool.

3. The tool of claim 1, wherein said MeX material is selected from the group consisting of titanium aluminum nitride, titanium aluminum carbonitride, and titanium aluminum boron nitride.

4. The tool of claim 1, wherein Me comprises at least one further element selected from the group consisting of born, zirconium, hafnium, yttrium, silicon, tungsten, and chromium.

5. The tool of claim 4, wherein said further element is contained in Me with a content i


0.05 at. %≦i≦60 at. %, 


taken Me as 100 at. %.

6. The tool of claim 1, further comprising a further layer of titanium nitride between said at least one layer and said tool body and wherein said further layer has a thickness d, for which there is valid


0.05 μm≦d≦5.0 μm.

7. The tool of claim 6, wherein said layer system is formed by said at least one layer and said further layer.

8. The tool of claim 1, wherein the stress within said at least one layer, σ, is
 1 GPa≦σ≦6 GPa.

9. The tool of claim 1, wherein the content x of titanium in said Me is:


70 at. %≧x≧40 at. %.

10. The tool of claim 1, wherein the content y of aluminum in said Me is:


30 at. %≦y≦60 at. %.

11. The tool of claim 9, wherein the content y of aluminum in said Me is:


30 at. %≦y≦60 at. %.

12. The tool of claim 1, wherein Q1≧10.

13. The tool of claim 1, wherein 1 GPa≦σ≦4 GPa.

14. The tool of claim 1, wherein 1.5 GPa≦σ≦2.5 GPa.

15. The tool of claim 1, wherein the content of x of titanium in said Me is


65 at. %≧x≧55 at. %.

16. The tool of claim 1, wherein the content of aluminum in said Me is


35 at. %≦y≦45 at. %.

17. The tool of claim 9, wherein the content y of aluminum in said Me is


35 at. %≦y≦45 at. %.

18. The tool of claim 17, wherein the content of x of titanium in said Me is


65 at. %≧x≧55 at. %.