# Patent

## Title
Metal halide lamp

## Abstract

Metal halide lamps have a discharge vessel operable at a high coldest spot temperature. The discharge vessel encloses a discharge space comprising an ionizable gas filling and, in addition to Hg, also an alkali iodide of Na of Li or a combination of both. According to the invention, the filling also comprises TbI3 or GdI3 or a combination thereof.

## Background
This is a divisional of application Ser. No. 09/732,191, filed Dec. 7, 2000 now U.S. Pat. No. 6,597,116.


The invention relates to a metal halide lamp comprising a discharge vessel having a ceramic wall, which discharge vessel encloses a discharge space comprising an ionizable filling which, in addition to Hg, comprises an alkali iodide of Na or Li or a combination thereof.
A lamp of the type described in the opening paragraph is known from WO 99/28946-A1. The known lamp combines a high specific luminous flux with fairly good color properties (for example, a value of the general color-rendering index Ra≧60 and a color temperature Tc in the range of 3000 K and 6000 K).
In this lamp, use is made of the recognition that a good color rendition is possible when Na halide is used as a filling constituent of a lamp and when there is a strong broadening and reversal of the Na emission in the Na-D lines during lamp operation. This requires a high temperature of, for example 1170 K (900° C.) of the coldest spot Tkp in the discharge vessel. When the Na-D lines are reversed and broadened, they take the form of an emission band in the spectrum, with two maxima at a mutual distance Δλ.
The requirement for a high value of Tkp has the result that the discharge vessel is relatively small, which leads to a high temperature of the wall of the discharge vessel in the practical lamp. The required high temperature excludes the use of quartz or quartz glass for the wall of the discharge vessel and necessitates the use of ceramic material for the wall of this vessel.
In this description and the claims, a ceramic material wall is understood to mean both a wall of metal oxide such as, for example, sapphire or densely sintered polycrystalline Al2O3, and metal nitride, for example AlN.
The light emitted by the lamp has a color point with co-ordinates (x, y) which deviates from that of a blackbody. The mathematical collection of color points of blackbodies is referred to as the blackbody line (BBL). An application of the known lamp as a light source with a Tc above 4700 K has the drawback that the color point of the lamp with co-ordinates x, y is more than 0.05 scale division above the BBL. Consequently, the known lamp is less suitable for use as, for example, a studio lamp.
It is an object of the invention to realize a lamp of the type described in the opening paragraph, in which the drawback described is eliminated.
According to the invention, a lamp of the type described in the opening paragraph is therefore characterized in that the filling of the discharge vessel also comprises TbI3 or GdI3 or a combination thereof.
A lamp according to the invention has the advantage that a value of the color temperature Tc above 4700 K, preferably above 5000 K can be realized and that a general color-rendering index Ra of at least 85 can be realized, while the lamp has a color point which is less than 0.02 above the BBL. The filling preferably comprises TbI3 in a molar ratio of at least 5% and at most 45%. This contributes to a satisfactory stability of the color properties of the lamp during its lifetime. A similar advantage can be realized if the filling comprises GdI3 in a molar ratio of at least 5% and at most 45%.
In a further embodiment, the filling comprises Nal and TlI. A lamp can then be obtained which emits light at a color temperature Tc of between 5500 K and 7600 K and a general color-rendering index Ra of between 85 and 96, with a relatively long lifetime and a relatively small decline of the luminous flux during the lifetime.
In a further embodiment of the lamp according to the invention, the filling comprises CeI3 and TbI3. A lamp can then be realized with a color temperature Tc of between 4700 K and 7500 K and a relatively large luminous flux. To this end, the filling of the lamp preferably comprises NaI, CeI3, ErI3 and TbI3. When the filling comprises TbI3 in a molar ratio of at least 8% and at most 16%, this will contribute to the stability of the color temperature Tc of the lamp during its lifetime. This also generally leads to a smaller shift of the color point of the lamp.
In a further variant, the filling of the lamp comprises LiI, CeI3 and TbI3, which results in a satisfactory stability of the color properties of the lamp in the case of different lamp positions.
The lamp according to the invention appears to be very suitable for use as a light source for, inter alia, video recordings for which a color temperature of more 4700 K, preferably above 5000 K is desired.
These and other aspects of the invention are apparent from and will be elucidated with reference to the embodiments described hereinafter.



In the drawing:
FIG. 1 shows a lamp according to the invention,
FIG. 2 is a cross-section of a discharge vessel of the lamp shown in FIG. 1.



FIG. 1 shows a metal halide lamp comprising a discharge vessel 3, which is not drawn to scale in a cross-section in FIG. 2, which discharge vessel has a ceramic wall enclosing a discharge space 11 comprising an ionizable filling which, in addition to Hg comprises an alkali iodide of Na or Li or a combination thereof. The filling of the discharge vessel also comprises TbI3 or GdI3 or a combination of both.
The discharge space accommodates two electrodes 4, 5, each of W in the drawing, with electrode bars 4a, 5a and with an electrode tip 4b, 5b spaced apart at a distance EA. The discharge vessel has a cylindrical part with an internal diameter ID, extending between end faces 33a, 33b and at least through the distance EA. The discharge space enclosed by the discharge vessel is sealed at the area of the end faces 33a, 33b. 
The discharge vessel is sealed on one side by a ceramic extended plug 34, 35 which extends as far as the end face 33a, 33b and tightly encloses, with some interspace, a current feedthrough conductor 40, 41 and 50, 51, respectively to the electrodes 4, 5 arranged in the discharge vessel and is connected thereto in a gastight manner near one end remote from the discharge space by means of a melt-ceramic compound 10. The discharge vessel is enclosed by an outer envelope 1 which has a lamp base 2 at one end. In the operating condition of the lamp, a discharge extends between the electrodes 4 and 5. Electrode 4 is connected via a current conductor 8 to a first electric contact which forms part of the lamp base 2. Electrode 5 is connected via a current conductor 9 to a second electric contact which forms part of the lamp base 2.
A large number of practical realizations with mutually different filling constituents and different power were made of the lamp described above. In a first series, the filling of the discharge vessel comprised NaI, TlI and TbI3. In a first variant, the iodide salts of the filling had a molar ratio of 49:13:38 and the total salt quantity was 7.1 mg. Such a lamp with a nominal power of 35 W had a specific light output of 59 lm/W corresponding to a wall load of 45 W/cm2. The lamp emitted light at a color temperature Tc of 7035 K and had a general color-rendering index Ra of 92. The co-ordinates (x; y) of the color point were (0.306:0.315), a fraction below the BBL. After a lifetime of 1000 hours, the decline of the specific luminous flux was 8 lm/W. The color point which remained below the BBL moved towards the co-ordinates (0.320; 0.324) which corresponds to a Tc of 6280 K. A similar lamp had a nominal power of 50 W, a wall load of 61 W/cm2 and a specific luminous flux of 73 lm/W. The values for Tc and Ra were 5500 K and 95, respectively, and the color point co-ordinates were (0.332; 0.349), being 0.01 scale division above the BBL.
In the case of a lamp with a nominal power of 70 W and 150 W, the iodide salt filling had a molar ratio of 57:4:39. In the case of the lamp of 70 W, the salt filling had a mass of 6 mg and the values for Tc and Ra were 7511 K and 88, respectively, and its color point co-ordinates were (0.298; 0.318). The lamp had a specific luminous flux of 78 lm/W, showing a decline of about 20% after a lifetime of 2000 hours. In the lamp of 150 W, with a salt filling of 8.5 mg, the values for Tc and Ra were 6600 K and 96, respectively, and its color point co-ordinates were (0.310; 0.333). In this case, the value for the wall load was 59 W/cm2. The lamp had a specific luminous flux of 74 lm/W. For both lamps, the color point was located about 0.01 scale division above the BBL. The lamp of 150 W reached a lifetime of more than 4000 hours. At 2000 hours, the specific luminous flux was 86% of the original value and 80% at 4000 hours. The color temperature Tc had remained substantially constant after 2000 hours.
For the purpose of comparison, two lamps were made with an iodide salt filling of NaI, TlI and GdI3 in a molar ratio of 72:4:24. For the lamp of 35 W, the salt filling had a mass of 5.95 mg and the values for Tc and Ra were 7380 K and 85, respectively, and the color point co-ordinates were (0.298; 0.326). The lamp had a specific luminous flux of 66.5 lm/W. For the lamp of 50 W, the wall load was 42 W/cm2, and the values for Tc and Ra were 5880 K and 90, respectively, with color point co-ordinates (0.323; 0.351). The lamp had a specific luminous flux of 68 lm/W. The color point in both lamps was located less than 0.02 scale division above the BBL.
A second series of practical realizations of the lamp described was provided with a discharge vessel having an ionizable filling comprising, in addition to Hg, also NaI, CeI3, ErI3 and TbI3. The Table below states some data of these lamps.













TABLE





Lamp number
1
2
3
4
5
6





















Nominal wattage (W)
50
50
50
35
50
35


Molar salt comp.
74:6:6:14
69:8:8:15
73:6:5:16
73:5:6:16
74:6:5:15
74:7:4:15


Na:Ce:Er:Tb


Salt mass (mg)
8
2
6
5
6
6


Luminous flux (lm/W)
69
76
74
61
71
70


Color-rendering index
93
93
93
90
93
87


Ra


Color temperature Tc
5300
7070
5870
6620
4825
5190


(K)


Coordinates Color
.337:.341
.307:.307
.325:.333
.305:.290
.350:.351
.339:.327


point









All lamps had a wall load of less than 62 W/cm2. The specific luminous flux and the color temperature Tc of lamp nos. 1, 2 and 3 decreased during the first 500 hours of their lifetime; for the specific luminous flux, the decrease ranged between 16% and 27% and for the color temperature Tc between 700 K and 1200 K. However, for lamp 5, the specific luminous flux was still 80% of the original value and the color temperature Tc had changed by less than 115 K after 1000 hours. Lamp 6 showed the same phenomena. In contrast, the color temperature Tc of lamp 4 had decreased by more than 1200 K.
The influence of the operating position of the lamp on the color temperature Tc was also examined for lamps 3, 4, 5 and 6. For the lamps with 16 mol % of TbI3, the difference between the value of Tc in the horizontal operating position and an operating position at an angle of 45° to the horizontal was 1250 K. For the lamps 5 and 6, this difference was 300 K. The shift of the color point of these lamps was also determined. The color point of lamp 3 had the co-ordinates (0.353; 0.377) after 500 hours, which is a shift of 0.03 and 0.05 scale division. The shift was 0.039 and 0.056 scale division for lamp 4 after 1000 hours. The color points of lamps 5 and 6 after 1000 hours were (0.355; 0.344) and (0.341; 0.327), respectively. The largest shifts of measured color points of lamps 5 and 6 during a lifetime of 1000 hours were smaller than 0.023, both in the x direction and in the y direction.
In a further practical realization of the lamp according to the invention, the filling of the discharge vessel was formed by Hg, 3.3 mg of NaI+CeI3+ErI3+TbI3 in a molar ratio of 70:13:6:11, and 0.13 mg of HgI2. The lamp, which had a nominal power of 35 W, had a specific luminous flux of 64 lm/W with a value of the color temperature Tc and the color-rendering index Ra of 6080 K and 82, respectively. The co-ordinates of the color point were (0.322; 0.318). After 1000 hours, the color point had the co-ordinates (0.335; 0.342). In both cases, the color point was about 0.015 scale division below the BBL. Under the influence of a change of the operating position of the lamp, there was a change of the color temperature of maximally 700 K. Under otherwise equal circumstances a relative increase of the molar quantity of TbI3 led to a shift of the color point which was largely parallel to the BBL.
Finally, a lamp according to the invention was made in which, in addition to Hg, the ionizable filling of the discharge vessel comprised LiI, CeI3 and TbI3. The molar ratio of the iodide salts was 71:22:7 and the mass was 10 mg. The lamp had a nominal power of 70 W. The difference in value of the color temperature Tc under the influence of the operating position of the lamp was less than 300 K. The values for the specific luminous flux, color temperature Tc, color-rendering index Ra and color point co-ordinates in the horizontal and vertical operating positions were 72.3 lm/W, 5200 K, 84, (0.342; 0.383) and 73.5 lm/W, 5435 K, 83 and (0.335; 0.371), respectively.
Due to their color properties and relatively low power, the practical embodiments described have proved to be very suitable for use as light sources in SSTV (studio, stage, television), video and film recording conditions. Another great advantage is a lifetime of 1000 hours or more.
The protective scope of the invention is not limited to the embodiments described. The invention resides in each and every novel characteristic feature and each and every combination of characteristic features. Reference numerals in the claims do not limit their protective scope. The use of the verb “to comprise” and its conjugations does not exclude the presence of elements other than those stated in the claims. The use of the indefinite article “a” or “an” preceding an element does not exclude the presence of a plurality of such elements.

## Claims

1. A metal halide lanip comprising a discharge vessel having a wall consisting of a material excluding quartz, wherein the temperature of the coldest spot in said discharge vessel during normal operation of the lamp is 900° C., said discharge vessel enclosing a discharge space containing an ionizable filling comprising mercury, an alkali iodide, said alkali iodide being sodium iodide, lithium iodide or a combination of sodium iodide and lithium iodide, and a rare earth iodide, said rare earth iodide being terbium iodide or gadolinium iodide or a combination of terbium iodide and gadolinium iodide.

2. The lamp claimed in claim 1, the filling comprising gadolinium iodide in a molar ratio of at least 5% and at most 45%.

3. The lamp claimed in claim 1, the filling compring TlI and NaI.

4. A metal halide lamp comprising a discharge vessel having a ceramic wall, the discharge vessel enclosing a discharge space comprising an ionizable filling, said filling comprising, in addition to Hg, and iodide of Na or Li or a combination thereof, the filling of the discharge vessel further comprising TbI3 and TlI, wherein the molar ratio of said iodide of Na, TlI and TbI3 is 49:13:38 and having a nominal nower of 35 W.

5. A metal halide lamp comprising a discharge vessel having a wall consisting of a material excluding quartz, wherein the temperature of the coldest spot in said discharge vessel during normal operation of the lamp is 900° C., the wall at least partially enclosing a discharge space containing an ionizable filling comprising mercury, an alkali iodide, said alkali iodide being sodium iodide, lithium iodide or a combination of sodium iodide and lithium iodide, and a rare earth iodide, said rare earth iodide being terbium iodide or gadolinium iodide or a combination of terbium iodide and gadolinium iodide, the lamp power and filling constituents exhibiting a color temperature Tc greater than 4700° K and having color rendering index Ra of at least 85 and a color point less than 0.02 above the black body line.

6. A metal halide lamp comprising a discharge vessel having a ceramic wall, the discharge vessel enclosing a discharge space comprising an ionizable filling, said filling comprising, in addition to Hg, and iodide of Na or Li or a combination thereof, the filling of the discharge vessel further comprising LiI, CeI3 and TbI3 in a molar ratio of 71:22:7 and having a nominal power of 70 W.

7. A metal halide lamp comprising a discharge vessel having a ceramic wall, the discharge vessel enclosing a discharge space comprising an ionizable filling, said filling comprising, in addition to Hg, and iodide of Na or Li or a combination thereof, the filling of the discharge vessel further comprising TlI and GdI3, wherein said iodide of Na, TlI and GdI3 exist in a molar ratio of 71:4:24.