# Patent

## Title
Semiconductor device and method for manufacturing the same

## Abstract

In the transistor including an oxide semiconductor film, which includes a film for capturing hydrogen from the oxide semiconductor film (a hydrogen capture film) and a film for diffusing hydrogen (a hydrogen permeable film), hydrogen is transferred from the oxide semiconductor film to the hydrogen capture film through the hydrogen permeable film by heat treatment. Specifically, a base film or a protective film of the transistor including an oxide semiconductor film has a stacked-layer structure of the hydrogen capture film and the hydrogen permeable film. At this time, the hydrogen permeable film is formed on a side which is in contact with the oxide semiconductor film. After that, hydrogen released from the oxide semiconductor film is transferred to the hydrogen capture film through the hydrogen permeable film by the heat treatment.

## Background
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device which is provided with a circuit including a semiconductor element such as a transistor. For example, the present invention relates to a power device which is mounted on a power supply circuit, a semiconductor integrated circuit including a memory, a thyristor, a converter, an image sensor, or the like, an electro-optical device typified by a liquid crystal display device, a light-emitting display device including a light-emitting element, and the like; and an electronic device on which any of the above circuit and devices are mounted as a component.
In this specification, a semiconductor device generally refers to a device which can function by utilizing semiconductor characteristics; an electro-optical device, a light-emitting display device, a semiconductor circuit, and an electronic device are all included in the category of the semiconductor device.
2. Description of the Related Art
Many transistors formed over a glass substrate or the like are manufactured using amorphous silicon, polycrystalline silicon, or the like, as typically seen in liquid crystal display devices. Although transistors formed using amorphous silicon have low field-effect mobility, they can be formed over a larger glass substrate. On the other hand, although transistors formed using polycrystalline silicon have high field-effect mobility, they are not suitable for being formed over a larger glass substrate.
Other than a transistor formed using silicon, in recent years, a technique in which a transistor is formed using an oxide semiconductor and applied to an electronic device or an optical device has attracted attention. For example, a technique of forming a transistor by using zinc oxide or In—Ga—Zn—O-based oxide as an oxide semiconductor, and of using the transistor for a switching element of a pixel of a display device and the like is disclosed in Patent Document 1 and Patent Document 2.
In an oxide semiconductor, part of hydrogen serves as a donor to release electrons as carriers. When the carrier concentration in the oxide semiconductor becomes high, a channel is formed in a transistor without voltage application to a gate. That is, the threshold voltage of the transistor shifts to the negative direction. It is difficult to remove hydrogen in the oxide semiconductor completely; therefore, it is also difficult to control the threshold voltage.
In Patent Document 3, it is disclosed that when hydrogen is added in an oxide semiconductor film, electrical conductivity of the oxide semiconductor is increased by approximately four to five orders of magnitude. In addition, it is disclosed that hydrogen is diffused into the oxide semiconductor film from an insulating film which is in contact with the oxide semiconductor film.
REFERENCE
[Patent Document 1] Japanese Published Patent Application No. 2007-123861
[Patent Document 2] Japanese Published Patent Application No. 2007-096055
[Patent Document 3] Japanese Published Patent Application No. 2008-141119
SUMMARY OF THE INVENTION
An object of one embodiment of the present invention is to manufacture a highly reliable semiconductor device by giving stable electric characteristics to a transistor including an oxide semiconductor film.
A technical idea of one embodiment of the present invention is as follows: in a transistor including an oxide semiconductor film, which includes a film for capturing or absorbing hydrogen from the oxide semiconductor film (a hydrogen capture film or a hydrogen absorption film) and a film for diffusing hydrogen (a hydrogen permeable film), hydrogen is transferred from the oxide semiconductor film to the hydrogen capture film through the hydrogen permeable film by heat treatment.
Specifically, a base film or a protective film of the transistor including an oxide semiconductor film has a stacked-layer structure of the hydrogen capture film and the hydrogen permeable film. At this time, the hydrogen permeable film is formed on a side which is in contact with the oxide semiconductor film. After that, hydrogen released from the oxide semiconductor film is transferred to the hydrogen capture film through the hydrogen permeable film by the heat treatment.
Note that the hydrogen concentration in the vicinity of the interface of the oxide semiconductor film can be reduced by providing the hydrogen permeable film between the oxide semiconductor film and the hydrogen capture film.
A highly reliable semiconductor device can be manufactured by giving stable electric characteristics to a transistor including an oxide semiconductor film.



BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1A to 1C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 2A to 2C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 3A to 3C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 4A to 4C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 5A to 5C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 6A to 6C are a top view and cross-sectional views illustrating an example of a semiconductor device according to one embodiment of the present invention.
FIGS. 7A to 7D are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 1A to 1C.
FIGS. 8A to 8D are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 2A to 2C.
FIGS. 9A to 9D are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 3A to 3C.
FIGS. 10A to 10D are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 4A to 4C.
FIGS. 11A to 11C are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 5A to 5C.
FIGS. 12A to 12D are cross-sectional views illustrating an example of a method for manufacturing a semiconductor device corresponding to the semiconductor device in FIGS. 6A to 6C.
FIG. 13 is a circuit diagram illustrating an example of a liquid crystal display device according to one embodiment of the present invention.
FIG. 14A is a circuit diagram illustrating an example of a semiconductor memory device according to one embodiment of the present invention, and FIG. 14B is a graph showing electric characteristics thereof.
FIG. 15A is a circuit diagram illustrating an example of a semiconductor memory device according to one embodiment of the present invention, and FIG. 15B is a graph showing electric characteristics thereof.
FIG. 16A is a block diagram illustrating a specific example of a CPU according to one embodiment of the present invention, and FIGS. 16B and 16C are circuit diagrams each illustrating a part of the CPU.
FIGS. 17A to 17C are perspective views illustrating examples of electronic devices each equipped with a semiconductor device according to one embodiment of the present invention.
FIGS. 18A and 18B are graphs showing the concentration distribution of hydrogen and nitrogen in the depth direction measured with SIMS.



DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below in detail with reference to the accompanying drawings. However, the present invention is not limited to the description below, and it is easily understood by those skilled in the art that modes and details disclosed herein can be modified in various ways without departing from the spirit and the scope of the present invention. Therefore, the present invention is not construed as being limited to description of the embodiments below. In describing structures of the present invention with reference to the drawings, the same reference numerals are used in common for the same portions in different drawings. Note that the same hatch pattern is applied to similar parts, and the similar parts are not especially denoted by reference numerals in some cases.
Before the present invention is described, terms used in this specification will be briefly explained. First, when one of a source and a drain of a transistor is called a drain, the other is called a source in this specification. That is, they are not distinguished depending on the potential level. Therefore, a portion called a source in this specification can be alternatively referred to as a drain.
Note that voltage refers to a potential difference between a predetermined potential and a reference potential (e.g., a ground potential) in many cases. Note that voltage can also be referred to as potential.
Further, even when the expression “to be connected” is used in this specification, there is a case in which no physical connection is made in an actual circuit and a wiring is just extended.
Note that the ordinal numbers such as “first” and “second” in this specification are used for convenience and do not denote the order of steps or the stacking order of layers. In addition, the ordinal numbers in this specification do not denote particular names which specify the present invention.
Embodiment 1
In this embodiment, an example of a transistor of one embodiment of the present invention will be described with reference to FIGS. 1A to 1C.
FIG. 1A is a top view of the transistor. A cross section along the dashed-dotted line A-B in FIG. 1A and a cross section along the dashed-dotted line C-D in FIG. 1A correspond to a cross section A-B in FIG. 1B and a cross section C-D in FIG. 1C, respectively.
Here, the cross section A-B in FIG. 1B will be described in detail.
The transistor includes a substrate 100, a base film 102 which is over the substrate 100 and includes a first base film 102a and a second base film 102b over the first film 102a, an oxide semiconductor film 106 over the base film 102, a pair of electrodes 116 which is over the oxide semiconductor film 106 and is partly in contact with the oxide semiconductor film 106, a gate insulating film 112 over the oxide semiconductor film 106 and the pair of electrodes 116, and a gate electrode 104 overlapping with the oxide semiconductor film 106 with the gate insulating film 112 provided therebetween.
Here, a hydrogen capture film is used for the first base film 102a, and a hydrogen permeable film is used for the second base film 102b. Note that the hydrogen concentration in the vicinity of the interface of the oxide semiconductor film can be reduced by providing the hydrogen permeable film between the oxide semiconductor film and the hydrogen capture film.
The first base film 102a can be formed using an oxynitride film containing indium nitride (or indium). Specifically, a compound material containing in addition to at least indium nitride, at least one or more kinds of indium oxide, gallium oxide, zinc oxide, tin oxide, aluminum oxide, tungsten oxide, molybdenum oxide, titanium oxide, tantalum oxide, and silicon oxide can be used. Note that an oxynitride refers to a compound in which nitrogen is substituted for part of oxygen included in an oxide.
For example, the nitrogen concentration in the first base film 102a can be higher than or equal to 0.01 atomic % and lower than 7 atomic %. An oxynitride film containing indium nitride whose nitrogen concentration is greater than or equal to 0.01 atomic % and less than 7 atomic % has a high insulating property. Alternatively, the nitrogen concentration in the first base film 102a can be higher than or equal to 7 atomic and lower than or equal to 20 atomic %. An oxynitride film containing indium nitride whose nitrogen concentration is greater than or equal to 7 atomic % and less than or equal to 20 atomic % in some cases has a high conductivity when bonding to hydrogen. At this time, leakage of electric charges from the pair of electrodes 116 through the first base film 102a can be prevented owing to the second base film 102b having a high insulating property. Note that the nitrogen concentration in the first base film 102a can be quantified by X-ray photoelectron spectroscopy (XPS) analysis.
Part of hydrogen contained in the oxynitride film containing indium nitride releases electrons serving as carriers. Since an electron has a negative charge, an electric field is generated in a manner similar to the case where a negative bias is applied from a back gate electrode, so that the threshold voltage of the transistor is shifted to the positive direction. In the transistor including the oxide semiconductor film, parts of oxygen vacancies and part of hydrogen in the oxide semiconductor film release electrons serving as carriers, whereby the threshold voltage of the transistor tends to shift to the negative direction. Therefore, in some cases, it is preferable to shift the threshold voltage of the transistor to the positive direction by the negative charges of the oxynitride film containing indium nitride. Note that the amount of negative charges can be adjusted by controlling the hydrogen concentration in the first base film 102a. The hydrogen concentration in the first base film 102a can be adjusted by the nitrogen concentration in the first base film 102a. 
The hydrogen concentration in the first base film 102a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that the hydrogen concentration in the first base film 102a can be quantified by secondary ion mass spectrometry (SIMS).
As the second base film 102b, an oxide film having a high insulating property is used. For example, a silicon oxide film or a silicon oxynitride film can be used. Note that the thickness of the second base film 102b is greater than or equal to 0.5 nm and less than or equal to 15 nm, preferably greater than or equal to 2 nm and less than or equal to 5 nm. It is possible to diffuse hydrogen at a lower temperature when the thickness of the second base film 102b is smaller. The second base film 102b may be a film from which oxygen is released by heat treatment.
Here, silicon oxynitride refers to a substance that contains more oxygen than nitrogen and, silicon oxynitride preferably contains oxygen, nitrogen, silicon, and hydrogen at concentrations ranging from greater than or equal to 50 atomic % and less than or equal to 70 atomic %, greater than or equal to 0.5 atomic % and less than or equal to 15 atomic %, greater than or equal to 25 atomic % and less than or equal to 35 atomic %, and greater than or equal to 0 atomic % and less than or equal to 10 atomic %, respectively. Note that the above ranges are ranges for cases where measurement is performed using Rutherford backscattering spectrometry (RBS) and hydrogen forward scattering spectrometry (HFS). In addition, the total of the percentages of the constituent elements does not exceed 100 atomic %.
The hydrogen concentration in the oxide semiconductor film 106 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the oxide semiconductor film 106 can be quantified by SIMS.
Here, alkali metals are not elements which compose an oxide semiconductor, and therefore, are impurities. In addition, alkaline earth metals are also impurities in the case where the alkaline earth metals do not compose oxide semiconductor. Alkali metals, in particular, Na diffuses in an insulating film which is in contact with the oxide semiconductor film and Na becomes Na+. In addition, in the oxide semiconductor film, Na cuts or enters a bond between a metal and oxygen which are included in the oxide semiconductor. As a result, for example, deterioration of electric characteristics of the transistor such as a normally-on state of the transistor due to shift of a threshold voltage to the negative direction or a reduction in field-effect mobility occurs; in addition, variation in electric characteristics of the transistor is also caused. Such deterioration of electric characteristics of the transistor and variation in electric characteristics of the transistor due to the impurity remarkably appear when the hydrogen concentration in the oxide semiconductor film is sufficiently low. Therefore, when the hydrogen concentration in the oxide semiconductor film is less than or equal to 1×1018 cm−3 or less than or equal to 1×1017 cm−3, the impurity concentration is preferably reduced. Specifically, the measurement value of Na concentration is preferably less than or equal to 5×10−16 cm−3, more preferably less than or equal to 1×1016 cm−3, still more preferably less than or equal to 1×1015 cm−3. In addition, the measurement value of lithium (Li) concentration is preferably less than or equal to 5×1015/cm−3, more preferably less than or equal to 1×1015/cm−3. In addition, the measurement value of potassium (K) concentration is preferably less than or equal to 5×1015/cm−3, more preferably less than or equal to 1×1015/cm−3.
The off-state current of the transistor including the oxide semiconductor film 106 described above can be significantly reduced. For example, the off-state current of the transistor where the channel length is 3 μm and the channel width is 1 μm is less than or equal to 1×10−18 A, less than or equal to 1×10−21 A, or less than or equal to 1×1024 A.
For the oxide semiconductor film 106, for example, a material including two or more kinds of elements selected from In, Ga, Zn, and Sn can be used.
The oxide semiconductor film 106 is formed using a material whose band gap is greater than or equal to 2.5 eV, preferably greater than or equal to 3.0 eV in order to reduce the off-state current of the transistor.
As a material used for the oxide semiconductor film 106, any of the following can be used, for example: an In—Sn—Ga—Zn—O-based material; an In—Ga—Zn—O-based material, an In—Sn—Zn—O-based material, an In—Al—Zn—O-based material, a Sn—Ga—Zn—O-based material, an Al—Ga—Zn—O-based material, or a Sn—Al—Zn—O-based material; an In—Zn—O-based material, a Sn—Zn—O-based material, an Al—Zn—O-based material, a Zn—Mg—O-based material, a Sn—Mg—O-based material, an In—Mg—O-based material, or an In—Ga—O-based material; an In—O-based material, a Sn—O-based material, or a Zn—O-based material; and the like. Here, for example, an In—Ga—Zn—O-based material means an oxide containing indium (In), gallium (Ga), and zinc (Zn), and there is no particular limitation on the composition ratio. Further, the In—Ga—Zn—O-based material may contain an element other than In, Ga, and Zn. In this case, the amount of oxygen in the oxide semiconductor film 106 is preferably in excess of that in the stoichiometric composition ratio. When the amount of oxygen is in excess of the stoichiometric composition ratio, generation of carriers which result from oxygen vacancies in the oxide semiconductor film 106 can be suppressed.
Note that in the case where an In—Zn—O-based material is used for the oxide semiconductor film 106 as an example, the atomic ratio thereof is set so that In/Zn is greater than or equal to 0.5 and less than or equal to 50, preferably greater than or equal to 1 and less than or equal to 20, more preferably greater than or equal to 1.5 and less than or equal to 15. When the atomic ratio of Zn is in the above range, the field-effect mobility of the transistor can be improved. Here, when the atomic ratio of the compound is In:Zn:O=X:Y:Z, the relation of Z>1.5X+Y is preferably satisfied.
Alternatively, a material represented by a chemical formula, InMo3(ZnO)m (m>0) may be used for the oxide semiconductor film 106. Here, M represents one or more metal elements selected from Ga, Al, Mn, and Co. For example, M may be Ga, Ga and Al, Ga and Mn, Ga and Co, or the like.
It is preferable that the oxide semiconductor film 106 be formed using a material including a metal element which is the same as the metal element included in the first base film 102a. This is because in the case where a sputtering method is employed, the films can be deposited separately in accordance with deposition gases with the use of the same target and the material cost and the apparatus cost can be reduced. For example, in the case where an In—Ga—Zn—O film is used as the oxide semiconductor film 106, an In—Ga—Zn—O—N film can be used as the first base film 102a. 
The oxide semiconductor film 106 is in a single crystal state, a polycrystalline (also referred to as polycrystal) state, an amorphous state, or the like.
The oxide semiconductor film 106 is preferably a c-axis aligned crystalline oxide semiconductor (CAAC-OS) film.
The CAAC-OS film is not completely single crystal nor completely amorphous. The CAAC-OS film is an oxide semiconductor film with a crystal-amorphous mixed phase structure where crystal parts and amorphous parts are included in an amorphous phase. Note that in most cases, the crystal part fits inside a cube whose one side is less than 100 nm. From an observation image obtained with a transmission electron microscope (TEM), a boundary between an amorphous part and a crystal part in the CAAC-OS film is not clear. Further, with the TEM, a grain boundary in the CAAC-OS film is not found. Thus, in the CAAC-OS film, a reduction in electron mobility, due to the grain boundary, is suppressed.
In each of the crystal parts included in the CAAC-OS film, a c-axis is aligned in a direction parallel to a normal vector of a surface where the CAAC-OS film is formed or a normal vector of a surface of the CAAC-OS film, triangular or hexagonal atomic arrangement which is seen from the direction perpendicular to the a-b plane is formed, and metal atoms are arranged in a layered manner or metal atoms and oxygen atoms are arranged in a layered manner when seen from the direction perpendicular to the c-axis. Note that, among crystal parts, the directions of the a-axis and the b-axis of one crystal part may be different from those of another crystal part. In this specification, a simple term “perpendicular” includes a range from 85° to 95°. In addition, a simple term “parallel” includes a range from −5° to 5°.
In the CAAC-OS film, distribution of crystal parts is not necessarily uniform. For example, in the formation process of the CAAC-OS film, in the case where crystal growth occurs from a surface side of the oxide semiconductor film, the proportion of crystal parts in the vicinity of the surface of the oxide semiconductor film is higher than that in the vicinity of the surface where the oxide semiconductor film is formed in some cases. Further, when an impurity is added to the CAAC-OS film, the crystal part in a region to which the impurity is added becomes amorphous in some cases.
Since the c-axes of the crystal parts included in the CAAC-OS film are aligned in the direction parallel to a normal vector of a surface where the CAAC-OS film is formed or a normal vector of a surface of the CAAC-OS film, the directions of the c-axes may be different from each other depending on the shape of the CAAC-OS film (the cross-sectional shape of the surface where the CAAC-OS film is formed or the cross-sectional shape of the surface of the CAAC-OS film). Note that when the CAAC-OS film is formed, the direction of c-axis of the crystal part is the direction parallel to a normal vector of the surface where the CAAC-OS film is formed or a normal vector of the surface of the CAAC-OS film. The crystal part is formed by film formation or by performing treatment for crystallization such as heat treatment after film formation.
With use of the CAAC-OS film in a transistor, change in electric characteristics of the transistor due to irradiation with visible light or ultraviolet light can be reduced. Thus, the transistor has high reliability.
The gate insulating film 112 can be formed to have a single-layer structure or a stacked-layer structure using one or more of silicon oxide, silicon oxynitride, silicon nitride oxide, silicon nitride, aluminum oxide, zirconium oxide, yttrium oxide, hafnium oxide, and the like by, for example, a plasma-enhanced CVD method, a sputtering method, an ALD method, or the like. A film from which oxygen is released by heat treatment is preferably used for the gate insulating film 112. With the use of such a film from which oxygen is released by heat treatment, oxygen vacancies generated in the oxide semiconductor film 106 can be repaired and deterioration in electric characteristics of the transistor can be suppressed.
Here, silicon nitride oxide refers to a substance that contains more nitrogen than oxygen and, silicon nitride oxide preferably contains oxygen, nitrogen, silicon, and hydrogen at concentrations ranging from higher than or equal to 5 atomic % and lower than or equal to 30 atomic %, higher than or equal to 20 atomic % and lower than or equal to 55 atomic %, higher than or equal to 25 atomic % and lower than or equal to 35 atomic %, and higher than or equal to 10 atomic % and lower than or equal to 25 atomic %, respectively. Note that the above ranges are ranges for cases where measurement is performed using RBS and HFS. In addition, the total of the percentages of the constituent elements does not exceed 100 atomic %.
To release oxygen by heat treatment means that the released amount of oxygen which is converted into oxygen atoms is greater than or equal to 1.0×1018 cm−3 or greater than or equal to 1.0×1020 cm−3 in thermal desorption spectroscopy (TDS) analysis.
Here, a method in which the amount of released oxygen is measured using TDS analysis will be described below.
The amount of released gas in TDS analysis is proportional to the integral value of ion intensity. Therefore, the amount of released gas can be calculated from the ratio between the integral value of measured ion intensity and the reference value of a standard sample. The reference value of a standard sample refers to, in a sample containing an atom at a predetermined density, the ratio of the density of the atom to the integral value of ion intensity corresponding to the atom.
For example, the amount of the released oxygen molecules (NO2) from an insulating film can be found according to Equation 1 with the TDS analysis results of a silicon wafer containing hydrogen at a predetermined density, which is the standard sample, and the TDS analysis results of the insulating film. Here, all gases having a mass number (or mass-to-charge ratio) of 32 which are obtained by the TDS analysis are assumed to originate from an oxygen molecule. CH3OH, which is given as a gas having a mass number of 32, is not taken into consideration on the assumption that it is unlikely to be present. Further, an oxygen molecule including an oxygen atom having a mass number of 17 or 18 which is an isotope of an oxygen atom is not taken into consideration either because the proportion of such a molecule in the natural world is minimal.

NO2=NH2/SH2×SO2=α  (Equation 1)

NH2 is the value obtained by conversion of the amount of hydrogen molecules desorbed from the standard sample into densities. SH2 is the integral value of ion intensity when the standard sample is subjected to TDS analysis. Here, the reference value of the standard sample is set to NH2/SH2. SO2 is the integral value of ion intensity when the insulating film is subjected to TDS analysis. α is a coefficient affecting the ion intensity in the TDS analysis. Japanese Published Patent Application No. H6-275697 is to be referred to for details of Equation 1. Note that the amount of released oxygen from the above insulating film is measured with a thermal desorption spectroscopy apparatus produced by ESCO Ltd., EMD-WA1000S/W using a silicon wafer containing a hydrogen atom at 1×1016 cm−3 as the standard sample.
Further, in the TDS analysis, oxygen is partly detected as an oxygen atom. The ratio between oxygen molecules and oxygen atoms can be calculated from the ionization rate of the oxygen molecules. Note that since the above a includes the ionization rate of the oxygen molecules, the amount of the released oxygen atoms can be estimated through the evaluation of the amount of the released oxygen molecules.
Note that NO2 is the number of the released oxygen molecules. The amount of released oxygen when converted into oxygen atoms is twice the number of the released oxygen molecules.
In the above structure, the film from which oxygen is released by heat treatment may be oxygen-excess silicon oxide (SiOX (X>2)). In the oxygen-excess silicon oxide (SiOX (X>2)), the number of oxygen atoms per unit volume is more than twice the number of silicon atoms per unit volume. The number of silicon atoms and the number of oxygen atoms per unit volume are measured by RBS.
By supplying (or transferring) oxygen from the gate insulating film 112 to the oxide semiconductor film 106, the interface state density at the interface between the oxide semiconductor film 106 and the gate insulating film 112 can be decreased. As a result, carrier trapping due to an operation of the transistor or the like at the interface between the oxide semiconductor film 106 and the gate insulating film 112 can be suppressed; thus, a transistor with less deterioration in electric characteristics can be obtained.
Further, in some cases, electric charges are generated owing to oxygen vacancies in the oxide semiconductor film 106. In general, parts of oxygen vacancies in an oxide semiconductor film serve as a donor to release electrons as carriers. As a result, the threshold voltage of a transistor shifts to the negative direction. When oxygen is sufficiently supplied (or diffused) from the gate insulating film 112 to the oxide semiconductor film 106, oxygen vacancies in the oxide semiconductor film 106 which cause the shift of the threshold voltage to the negative direction can be reduced.
In other words, when the film from which oxygen is released by heat treatment is provided as the gate insulating film 112, the interface state density at the interface between the oxide semiconductor film 106 and the gate insulating film 112 and the oxygen vacancies in the oxide semiconductor film 106 can be reduced. Thus, the influence of carrier trapping at the interface between the oxide semiconductor film 106 and the gate insulating film 112 can be reduced.
It is preferable to reduce the hydrogen concentration in the oxide semiconductor film 106 with the oxygen vacancies, which cause the shift of the threshold voltage of the transistor to the negative direction, removed in such a manner as much as possible.
There is no particular limitation on the substrate 100 as long as it has heat resistance enough to withstand at least heat treatment performed later. For example, a glass substrate, a ceramic substrate, a quartz substrate, a sapphire substrate, or the like may be used as the substrate 100. Alternatively, a single crystal semiconductor substrate or a polycrystalline semiconductor substrate made of silicon, silicon carbide, or the like; a compound semiconductor substrate made of silicon germanium or the like; a silicon-on-insulator (SOI) substrate; or the like can be used as the substrate 100. Still alternatively, any of these substrates further provided with a semiconductor element may be used as the substrate 100.
Further alternatively, a flexible substrate may be used as the substrate 100. In that case, a transistor can be formed directly on the flexible substrate. Note that as a method for forming a transistor over a flexible substrate, there is also a method in which, after a transistor is formed over a non-flexible substrate, the transistor is separated and transferred to the substrate 100 which is a flexible substrate. In that case, a separation layer is preferably provided between the non-flexible substrate and the transistor.
The gate electrode 104 can be formed to have a single-layer structure or a stacked-layer structure using one or more of the following materials: Al, Ti, Cr, Co, Ni, Cu, Y, Zr, Mo, Ag, Ta, and W, a nitride of any of these elements, an oxide of any of these elements, and an alloy of any of these elements.
Although, in FIGS. 1A to 1C, the gate electrode 104 does not completely cover the oxide semiconductor film 106, the oxide semiconductor film 106 may be completely covered with the gate electrode 104 in order to prevent light from causing degradation of the oxide semiconductor film 106 and generation of an electric charge in the oxide semiconductor film 106.
The pair of electrodes 116 can be formed with a single-layer structure or a stacked-layer structure using a metal film, a metal nitride film, a metal oxide film, an alloy film, or the like given for the gate electrode 104.
When a film including Cu is used for the pair of electrodes 116, the wiring resistance can be reduced, and wiring delay or the like can be prevented even in a large-sized display device or the like. In the case where Cu is used for the pair of electrodes 116, the adhesion depends on the material of the substrate 100; in such a case, it is preferable to employ a stacked-layer structure using a film having favorable adhesion property to the substrate 100. As the film having favorable adhesion property to the substrate 100, a film including Ti, Mo, Mn, Cu, or Al can be used. For example, a Cu—Mn—Al alloy may be used.
Next, a method for manufacturing the transistor illustrated in FIGS. 1A to 1C will be described with reference to FIGS. 7A to 7D.
First, the base film 102 is formed by depositing a stack of the first base film 102a and the second base film 102b in this order over the substrate 100. Next, an oxide semiconductor film 136 is deposited by a sputtering method or the like (see FIG. 7A).
The first base film 102a can be deposited by a plasma-enhanced CVD method, a sputtering method, a pulsed laser deposition (PLD) method, an atomic layer deposition (ALD) method, or the like. For example, in the case where a sputtering method is employed, a target including at least indium oxide is used. As the target, in addition to indium oxide, a material including at least one of gallium oxide, zinc oxide, tin oxide, aluminum oxide, tungsten oxide, molybdenum oxide, titanium oxide, tantalum oxide, and silicon oxide may be used. Note that at least nitrogen may be contained in the deposition gas. As the deposition gas, at least one of a rare gas (such as helium, neon, argon, krypton, or xenon) and oxygen may be used. By depositing the first base film 102a in such a manner, the nitrogen concentration in the first base film 102a including at least indium nitride is greater than or equal to 0.01 atomic % and less than 7 atomic % or greater than or equal to 7 atomic % and less than or equal to 20 atomic %.
As the second base film 102b, a silicon oxide film or a silicon oxynitride film can be deposited by a plasma-enhanced CVD method, a sputtering method, a PLD method, an ALD method, or the like.
Next, the oxide semiconductor film 136 is processed to form the oxide semiconductor film 106 (see FIG. 7B). After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 106 to the first base film 102a through the second base film 102b. The transferred hydrogen is captured by the first base film 102a. At this time, the hydrogen concentration in the oxide semiconductor film 106 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first base film 102a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second base film 102b, oxygen can be transferred from the second base film 102b to the oxide semiconductor film 106 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 106 and the second base film 102b and the oxygen vacancies in the oxide semiconductor film 106 can be reduced.
Next, a conductive film is deposited over the oxide semiconductor film 106 and is processed to form the pair of electrodes 116 which is in contact with at least part of the oxide semiconductor film 106. Then, the gate insulating film 112 is deposited over the oxide semiconductor film 106 and the pair of electrodes 116 (see FIG. 7C). The conductive film to be the pair of electrodes 116 can be deposited using the above material by a sputtering method, a plasma-enhanced CVD method, a PLD method, an ALD method, an evaporation method, a printing method, or the like.
Next, a conductive film is deposited over the gate insulating film 112 and is processed to form the gate electrode 104 overlapping with the oxide semiconductor film 106 (see FIG. 7D). The conductive film to be the gate electrode 104 can be deposited using the above material by a sputtering method, a plasma-enhanced CVD method, a PLD method, an ALD method, an evaporation method, a printing method, or the like.
Note that heat treatment similar to the heat treatment performed after the formation of the oxide semiconductor film 106 may be performed after the formation of the gate insulating film 112 or the gate electrode 104 instead.
As described above, hydrogen is transferred from the oxide semiconductor film 106 to the first base film 102a through the second base film 102b and the transferred hydrogen is captured by the first base film 102a, whereby the highly purified oxide semiconductor film 106 can be formed. Therefore, a highly reliable semiconductor device in which the off-state current of the transistor is significantly small and the electric characteristics are stable can be manufactured.
The threshold voltage of the transistor can be shifted to the positive direction by the operation of negative charges which are generated due to part of the hydrogen captured by the first base film 102a. 
Through the process described above, the transistor illustrated in FIGS. 1A to 1C can be formed.
Next, a transistor having a structure different from that of the transistor illustrated in FIGS. 1A to 1C will be described with reference to FIGS. 2A to 2C.
FIGS. 2A to 2C are a top view and cross-sectional views of a transistor. A cross section along the dashed-dotted line A-B in FIG. 2A and a cross section along the dashed-dotted line C-D in FIG. 2A correspond to a cross section A-B in FIG. 2B and a cross section C-D in FIG. 2C, respectively.
The cross section A-B in FIG. 2B will be described below in detail.
The transistor illustrated in FIGS. 2A to 2C includes the substrate 100, the base film 102 which is over the substrate 100 and includes the first base film 102a and the second base film 102b over the first base film 102a, a pair of electrodes 216 over the base film 102, an oxide semiconductor film 206 which is over the pair of electrodes 216 and is in contact with at least part of the pair of electrodes 216, a gate insulating film 212 over the oxide semiconductor film 206 and the pair of electrodes 216, and a gate electrode 204 overlapping with the oxide semiconductor film 206 with the gate insulating film 212 provided therebetween. Here, the pair of electrodes 216, the oxide semiconductor film 206, the gate insulating film 212, and the gate electrode 204 are formed using methods and materials similar to those of the pair of electrodes 116, the oxide semiconductor film 106, the gate insulating film 112, and the gate electrode 104, respectively.
Although, in FIGS. 2A to 2C, the gate electrode 204 does not completely cover the oxide semiconductor film 206, the oxide semiconductor film 206 may be completely covered with the gate electrode 204 in order to prevent light from causing degradation of the oxide semiconductor film 206 and generation of an electric charge in the oxide semiconductor film 206.
Next, a method for manufacturing the transistor illustrated in FIGS. 2A to 2C will be described with reference to FIGS. 8A to 8D.
First, the base film 102 which includes the first base film 102a and the second base film 102b over the first base film 102a is formed over the substrate 100. Then, the pair of electrodes 216 is formed over the base film 102 (see FIG. 8A).
Next, the oxide semiconductor film 206 which is over the pair of electrodes 216 and is in contact with at least part of the pair of electrodes 216 is formed (see FIG. 8B). After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 206 to the first base film 102a through the second base film 102b. The transferred hydrogen is captured by the first base film 102a. At this time, the hydrogen concentration in the oxide semiconductor film 206 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first base film 102a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second base film 102b, oxygen can be transferred from the second base film 102b to the oxide semiconductor film 206 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 206 and the second base film 102b and the oxygen vacancies in the oxide semiconductor film 206 can be reduced.
Next, the gate insulating film 212 is deposited over the oxide semiconductor film 206 and the pair of electrodes 216 (see FIG. 8C).
Next, the gate electrode 204 overlapping with the oxide semiconductor film 206 with the gate insulating film 212 provided therebetween is formed (see FIG. 8D).
Note that heat treatment similar to the heat treatment performed after the formation of the oxide semiconductor film 206 may be performed after the formation of the gate insulating film 212 or the gate electrode 204 instead.
As described above, hydrogen is transferred from the oxide semiconductor film 206 to the first base film 102a through the second base film 102b and the transferred hydrogen is captured by the first base film 102a, whereby the highly purified oxide semiconductor film 206 can be formed. Therefore, a highly reliable semiconductor device in which the off-state current of the transistor is significantly small and the electric characteristics are stable can be manufactured.
The threshold voltage of the transistor can be shifted to the positive direction by the operation of negative charges which are generated due to part of the hydrogen captured by the first base film 102a. 
Through the process described above, the transistor illustrated in FIGS. 2A to 2C can be formed.
Next, a transistor having a structure different from that of the transistor illustrated in FIGS. 1A to 1C and FIGS. 2A to 2C will be described with reference to FIGS. 3A to 3C.
FIGS. 3A to 3C are a top view and cross-sectional views of a transistor. A cross section along the dashed-dotted line A-B in FIG. 3A and a cross section along the dashed-dotted line C-D in FIG. 3A correspond to a cross section A-B in FIG. 3B and a cross section C-D in FIG. 3C, respectively.
The cross section A-B in FIG. 3B will be described below in detail.
The transistor illustrated in FIGS. 3A to 3C includes the substrate 100, the base film 102 which is over the substrate 100 and includes the first base film 102a and the second base film 102b over the first base film 102a, an oxide semiconductor film 306 which is over the base film 102 and includes a channel region 305, a source region 307a, and a drain region 307b, a gate insulating film 312 over the oxide semiconductor film 306 and the base film 102, a gate electrode 304 overlapping with the oxide semiconductor film 306 with the gate insulating film 312 provided therebetween, a protective film 318 over the gate electrode 304 and the gate insulating film 312, and a pair of electrodes 316 which is over the protective film 318 and is in contact with the source region 307a and the drain region 307b through openings provided in the gate insulating film 312 and the protective film 318. Here, the pair of electrodes 316, the oxide semiconductor film 306, the gate electrode 304, and the gate insulating film 312 are formed using methods and materials similar to those of the pair of electrodes 116, the oxide semiconductor film 106, the gate electrode 104, and the gate insulating film 112, respectively.
Although, in FIGS. 3A to 3C, the shape of the openings provided in the gate insulating film 312 and the protective film 318 is a circle when seen from the top surface, the present invention is not limited to this shape. There is no particular limitation on the shape of the openings as long as the source region 307a and the drain region 307b are exposed through the respective openings.
The channel region 305 and the gate electrode 304 may have substantially the same shape when seen from the top surface. Note that the source region 307a and the drain region 307b include nitrogen, phosphorus, hydrogen, a rare gas, or the like.
Note that the channel region 305 is a high-resistance region, and the source region 307a and the drain region 307b are low-resistance regions.
Next, a method for manufacturing the transistor illustrated in FIGS. 3A to 3C will be described with reference to FIGS. 9A to 9D.
First, the base film 102 which includes the first base film 102a and the second base film 102b over the first base film 102a is formed over the substrate 100. Then, the oxide semiconductor film 306 is formed over the base film 102. After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 306 to the first base film 102a through the second base film 102b. The transferred hydrogen is captured by the first base film 102a. At this time, the hydrogen concentration in the oxide semiconductor film 306 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first base film 102a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second base film 102b, oxygen can be transferred from the second base film 102b to the oxide semiconductor film 306 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 306 and the second base film 102b and the oxygen vacancies in the oxide semiconductor film 306 can be reduced. Then, the gate insulating film 312 is formed over the oxide semiconductor film 306 and the base film 102 (see FIG. 9A).
Next, the gate electrode 304 overlapping with the oxide semiconductor film 306 with the gate insulating film 312 provided therebetween is formed. Then, with the use of the gate electrode 304 as a mask, nitrogen, phosphorus, hydrogen, or a rare gas is added to a part of the oxide semiconductor film 306. The addition or heat treatment in addition to the addition is performed, thereby by reducing the resistance of a region of the oxide semiconductor film 306, which does not overlap with the gate electrode 304. Accordingly, the channel region 305, the source region 307a, and the drain region 307b are formed (see FIG. 9B). Note that the heat treatment performed here can be performed after the formation of the oxide semiconductor film 306 instead.
Next, the protective film 318 is formed over the gate insulating film 312 and the gate electrode 304, and the respective openings through which each of the source region 307a and the drain region 307b are exposed are formed in the gate insulating film 312 and the protective film 318. Then, the pair of electrodes 316 which is in contact with the oxide semiconductor film 306 is formed (see FIG. 9D). Note that heat treatment similar to the heat treatment performed after the formation of the oxide semiconductor film 306 and the heat treatment performed to form the source region 307a and the drain region 307b may be performed after the formation of the protective film 318 or the pair of electrodes 316 instead.
As described above, hydrogen is transferred from the oxide semiconductor film 306 to the first base film 102a through the second base film 102b and the transferred hydrogen is captured by the first base film 102a, whereby the highly purified oxide semiconductor film 306 can be formed. Therefore, a highly reliable semiconductor device in which the off-state current of the transistor is significantly small and the electric characteristics are stable can be manufactured.
The threshold voltage of the transistor can be shifted to the positive direction by the operation of negative charges which are generated due to part of the hydrogen captured by the first base film 102a. 
Through the process described above, the transistor illustrated in FIGS. 3A to 3C can be formed.
Next, a transistor having a structure different from that of the transistor illustrated in FIGS. 1A to 1C, FIGS. 2A to 2C, and FIGS. 3A to 3C will be described with reference to FIGS. 4A to 4C.
FIGS. 4A to 4C are a top view and cross-sectional views of a transistor. A cross section along the dashed-dotted line A-B in FIG. 4A and a cross section along the dashed-dotted line C-D in FIG. 4A correspond to a cross section A-B in FIG. 4B and a cross section C-D in FIG. 4C, respectively.
The cross section A-B in FIG. 4B will be described below in detail.
The transistor illustrated in FIGS. 4A to 4C includes the substrate 100, a gate electrode 404 over the substrate 100, a gate insulating film 412 covering the gate electrode 404, an oxide semiconductor film 406 overlapping with the gate electrode 404 with the gate insulating film 412 provided therebetween, a pair of electrodes 416 which is over the oxide semiconductor film 406 and is in contact with at least part of the oxide semiconductor film 406, and a protective film 418 which is over the oxide semiconductor film 406 and the pair of electrodes 416 and includes a second protective film 418b and a first protective film 418a over the second protective film 418b. Here, the gate electrode 404, the gate insulating film 412, the oxide semiconductor film 406, and the pair of electrodes 416 are formed using methods and materials similar to those of the gate electrode 104, the gate insulating film 112, the oxide semiconductor film 106, and the pair of electrodes 116, respectively.
Note that the first protective film 418a and the second protective film 418b are formed using methods and materials similar to those of the first base film 102a and the second base film 102b, respectively.
Although, in FIGS. 4A to 4C, the gate electrode 404 does not completely cover the oxide semiconductor film 406, the oxide semiconductor film 406 may be completely covered with the gate electrode 404 in order to prevent light from causing degradation of the oxide semiconductor film 406 and generation of an electric charge in the oxide semiconductor film 406.
Next, a method for manufacturing the transistor illustrated in FIGS. 4A to 4C will be described with reference to FIGS. 10A to 10D.
First, the gate electrode 404 is formed over the substrate 100. Next, the gate insulating film 412 is deposited so as to cover the gate electrode 404 (see FIG. 10A).
Next, the oxide semiconductor film 406 overlapping with the gate electrode 404 with the gate insulating film 412 provided therebetween is formed (see FIG. 10B).
Next, the pair of electrodes 416 which is over the oxide semiconductor film 406 and is in contact with at least part of the oxide semiconductor film 406 is formed (see FIG. 10C).
Next, the protective film 418 including the second protective film 418b and the first protective film 418a over the second protective film 418b is formed over the oxide semiconductor film 406 and the pair of electrodes 416 (see FIG. 10D). After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 406 to the first protective film 418a through the second protective film 418b. The transferred hydrogen is captured by the first protective film 418a. At this time, the hydrogen concentration in the oxide semiconductor film 406 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first protective film 418a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second protective film 418b, oxygen can be transferred from the second protective film 418b to the oxide semiconductor film 406 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 406 and the second protective film 418b and the oxygen vacancies in the oxide semiconductor film 406 can be reduced.
As described above, hydrogen is transferred from the oxide semiconductor film 406 to the first protective film 418a through the second protective film 418b and the transferred hydrogen is captured by the first protective film 418a, whereby the highly purified oxide semiconductor film 406 can be formed. Therefore, a highly reliable semiconductor device in which the off-state current of the transistor is significantly small and the electric characteristics are stable can be manufactured.
The threshold voltage of the transistor can be shifted to the positive direction by the operation of negative charges which are generated due to part of the hydrogen captured by the first protective film 418a. 
Through the process described above, the transistor illustrated in FIGS. 4A to 4C can be formed.
Next, a transistor having a structure different from that of the transistor illustrated in FIGS. 1A to 1C, FIGS. 2A to 2C, FIGS. 3A to 3C, and FIGS. 4A to 4C will be described with reference to FIGS. 5A to 5C.
FIGS. 5A to 5C are a top view and cross-sectional views of a transistor. A cross section along the dashed-dotted line A-B in FIG. 5A and a cross section along the dashed-dotted line C-D in FIG. 5A correspond to a cross section A-B in FIG. 5B and a cross section C-D in FIG. 5C, respectively.
The cross section A-B in FIG. 5B will be described below in detail.
The transistor illustrated in FIGS. 5A to 5C includes the substrate 100, the gate electrode 404 over the substrate 100, the gate insulating film 412 covering the gate electrode 404, a pair of electrodes 516 over the gate insulating film 412, an oxide semiconductor film 506 which is in contact with at least part of the pair of electrodes 516 and overlaps with the gate electrode 404 with the gate insulating film 412 provided therebetween, and a protective film 518 which is over the oxide semiconductor film 506 and the pair of electrodes 516 and includes a second protective film 518b and a first protective film 518a over the second protective film 518b. Here, the oxide semiconductor film 506, the pair of electrodes 516, and the protective film 518 are formed using methods and materials similar to those of the oxide semiconductor film 106, the pair of electrodes 116, and the protective film 418, respectively.
Although, in FIGS. 5A to 5C, the gate electrode 404 does not completely cover the oxide semiconductor film 506, the oxide semiconductor film 506 may be completely covered with the gate electrode 404 in order to prevent light from causing degradation of the oxide semiconductor film 506 and generation of an electric charge in the oxide semiconductor film 506.
Next, a method for manufacturing the transistor illustrated in FIGS. 5A to 5C will be described with reference to FIGS. 11A to 11C.
First, the gate electrode 404 is formed over the substrate 100. Next, the gate insulating film 412 is deposited so as to cover the gate electrode 404. Then, the pair of electrodes 516 is formed over the gate insulating film 412 (see FIG. 11A).
Next, the oxide semiconductor film 506 which overlaps with the gate electrode 404 with the gate insulating film 412 provided therebetween and is in contact with at least part of the pair of electrodes 516 is formed (see FIG. 11B).
Next, the protective film 518 including the second protective film 518b and the first protective film 518a over the second protective film 518b is formed over the oxide semiconductor film 506 and the pair of electrodes 516 (see FIG. 11C). After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 506 to the first protective film 518a through the second protective film 518b. The transferred hydrogen is captured by the first protective film 518a. At this time, the hydrogen concentration in the oxide semiconductor film 506 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first protective film 518a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second protective film 518b, oxygen can be transferred from the second protective film 518b to the oxide semiconductor film 506 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 506 and the second protective film 518b and the oxygen vacancies in the oxide semiconductor film 506 can be reduced.
As described above, hydrogen is transferred from the oxide semiconductor film 506 to the first protective film 518a through the second protective film 518b and the transferred hydrogen is captured by the first protective film 518a, whereby the highly purified oxide semiconductor film 506 can be formed. Therefore, a highly reliable semiconductor device in which the off-state current of the transistor is significantly small and the electric characteristics are stable can be manufactured.
The threshold voltage of the transistor can be shifted to the positive direction by the operation of negative charges which are generated due to part of the hydrogen captured by the first protective film 518a. 
Through the process described above, the transistor illustrated in FIGS. 5A to 5C can be formed.
Next, a transistor having a structure different from that of the transistor illustrated in FIGS. 1A to 1C, FIGS. 2A to 2C, FIGS. 3A to 3C, FIGS. 4A to 4C, and FIGS. 5A to 5C will be described with reference to FIGS. 6A to 6C.
FIGS. 6A to 6C are a top view and cross-sectional views of a transistor. A cross section along the dashed-dotted line A-B in FIG. 6A and a cross section along the dashed-dotted line C-D in FIG. 6A correspond to a cross section A-B in FIG. 6B and a cross section C-D in FIG. 6C, respectively.
The cross section A-B in FIG. 6B will be described below in detail.
The transistor illustrated in FIGS. 6A to 6C includes the substrate 100, the gate electrode 404 over the substrate 100, the gate insulating film 412 covering the gate electrode 404, an oxide semiconductor film 606 which is over the gate electrode 404 with the gate insulating film 412 provided therebetween and includes a channel region 605, a source region 607a, and a drain region 607b, a protective film 618 which is over the gate insulating film 412 and the oxide semiconductor film 606 and includes a second protective film 618b and a first protective film 618a over the second protective film 618b, and a pair of electrodes 616 which is over the protective film 618 and is in contact with the source region 607a and the drain region 607b each through an opening provided in the protective film 618. Here, the pair of electrodes 616, the oxide semiconductor film 606, and the protective film 618 are formed using methods and materials similar to those of the pair of electrodes 116, the oxide semiconductor film 106, and the protective film 418, respectively.
Although, in FIGS. 6A to 6C, there seems to be a region where the first protective film 618a is not formed over the second protective film 618b, the present invention is not limited to this structure. For example, the first protective film 618a may be formed over the entire surface of the second protective film 618b. 
Although, in FIGS. 6A to 6C, the gate electrode 404 and the channel region 605 have substantially the same shape seen from the top surface, the present invention is not limited to this shape. The gate electrode 404 and the channel region 605 may have different shapes from each other.
Note that the source region 607a and the drain region 607b include nitrogen, phosphorus, hydrogen, a rare gas, or the like.
Note that the channel region 605 is a high-resistance region, and the source region 607a and the drain region 607b are low-resistance regions.
Next, a method for manufacturing the transistor illustrated in FIGS. 6A to 6C will be described with reference to FIGS. 12A to 12D.
First, the gate electrode 404 is formed over the substrate 100. Next, the gate insulating film 412 is deposited so as to cover the gate electrode 404. Then, the oxide semiconductor film 606 overlapping with the gate electrode 404 with the gate insulating film 412 provided therebetween is formed (see FIG. 12A).
Next, with the use of a resist mask or the like as a mask, nitrogen, phosphorus, hydrogen, or a rare gas is added to a part of the oxide semiconductor film 606. The addition or heat treatment in addition to the addition is performed, thereby reducing the resistance of a region of the oxide semiconductor film 606, which does not overlap with the gate electrode 404. Accordingly, the channel region 605, the source region 607a, and the drain region 607b are formed (see FIG. 12B). Note that the resist mask or the like may be formed by a back exposure technique with the use of the gate electrode 404 as a mask. In that case, an area where the source region 607a overlaps with the gate electrode 404 and an area where the drain region 607b overlaps with the gate electrode 404 can be reduced; thus, the parasitic capacitance is reduced. Accordingly, the operation speed of the transistor can be increased. In addition, the number of photomasks used for forming the resist mask can be reduced, whereby the manufacturing cost for the transistor can be reduced, which is preferable.
Next, a protective film 638 is formed by depositing a stack of a second protective film 638b and a first protective film 638a in this order over the oxide semiconductor film 606 and the gate insulating film 412 (see FIG. 12C). After that, heat treatment is performed at a temperature higher than 450° C. and lower than the strain point of the substrate 100, preferably higher than or equal to 500° C. and lower than or equal to 650° C. to transfer hydrogen released from the oxide semiconductor film 606 to the first protective film 638a through the second protective film 638b. The transferred hydrogen is captured by the first protective film 638a. At this time, the hydrogen concentration in the oxide semiconductor film 606 is less than 1×1019 cm−3, preferably less than or equal to 5×1018 cm−3. The hydrogen concentration in the first protective film 638a is greater than or equal to 1×1019 cm−3 and less than or equal to 5×1020 cm−3, preferably greater than or equal to 1×1020 cm−3 and less than or equal to 3×1020 cm−3. Note that in the case where a film from which oxygen is released by heat treatment is provided as the second protective film 638b, oxygen can be transferred from the second protective film 638b to the oxide semiconductor film 606 by the heat treatment. Thus, the interface state density at the interface between the oxide semiconductor film 606 and the second protective film 638b and the oxygen vacancies in the oxide semiconductor film 606 can be reduced.
Next, the protective film 618 including the second protective film 618b and the first protective film 618a over the second protective film 618b and the pair of electrodes 616 which is in contact with the oxide semiconductor film 606 are formed in a manner such that the respective openings through which each of the source region 607a and the drain region 607b are exposed are formed in the protective film 638, a conductive film is deposited, and then the conductive film and the first protective film 638a are processed (see FIG. 12D). Although the first protective film 638a is processed at the same time as formation of the pair of electrodes 616 by processing the conductive film, without limitation to this structure, the first protective film 638a is not necessarily processed.
Through the process described above, the transistor illustrated in FIGS. 6A to 6C can be formed.
This embodiment can be implemented in appropriate combination with the other embodiments.
Embodiment 2
In this embodiment, a liquid crystal display device manufactured using the transistor described in Embodiment 1 will be described. Note that although an example in which one embodiment of the present invention is applied to the liquid crystal display device is described in this embodiment, the present invention is not limited to this embodiment. For example, application of one embodiment of the present invention to an electroluminescence (EL) display device which is one of light-emitting devices is readily conceived by those skilled in the art.
FIG. 13 is a circuit diagram of an active matrix liquid crystal display device. The liquid crystal display device includes source lines SL_1 to SL_a, gate lines GL_1 to GL_b, and a plurality of pixels 2200. Each pixel 2200 includes a transistor 2230, a capacitor 2220, and a liquid crystal element 2210. The plurality of pixels 2200 with such a configuration forms a pixel portion of the liquid crystal display device. In the case where the source line or the gate line is simply mentioned, it is denoted as the source line SL or the gate line GL in some cases.
The transistor described in Embodiment 1, which is one embodiment of the present invention, is used as the transistor 2230. Since the transistor described in Embodiment 1 is a transistor including an oxide semiconductor having favorable electric characteristics, a liquid crystal display device with high display quality and low power consumption can be obtained.
The gate line GL is connected to a gate of the transistor 2230, the source line SL is connected to a source of the transistor 2230, and a drain of the transistor 2230 is connected to one of capacitor electrodes of the capacitor 2220 and one of pixel electrodes of the liquid crystal element 2210. The other of the capacitor electrodes of the capacitor 2220 and the other of the pixel electrodes of the liquid crystal element 2210 are each connected to a common electrode. Note that the common electrode may be formed using the same material in the same layer as the gate line GL.
Further, the gate line GL is connected to a gate driver circuit. The gate driver circuit may include the transistor described in Embodiment 1.
The source line SL is connected to a source driver circuit. The source driver circuit may include the transistor described in Embodiment 1.
One of or both of the gate driver circuit and the source driver circuit may be formed over a separately prepared substrate and connected by a connection method such as a chip on glass (COG) method, a wire bonding method, or a tape automated bonding (TAB) method.
Since a transistor is easily broken by static electricity or the like, a protection circuit is preferably provided. The protection circuit is preferably formed using a nonlinear element.
When a voltage that is higher than or equal to the threshold voltage of the transistor 2230 is applied to the gate line GL, an electric charge supplied from the source line SL flows as a drain current of the transistor 2230 and is accumulated in the capacitor 2220. After charging for one row, the transistors 2230 in the row are turned off and voltage application from the source line SL stops; however, a voltage which is needed can be kept by the electric charges accumulated in the capacitors 2220. Then, charging of the capacitors 2220 in the next row starts. In this manner, charging for the first row to the b-th row is carried out. A drain current is a current that flows from a source to a drain through a channel in a transistor. The drain current flows when a gate voltage is higher than the threshold voltage.
In the case where a transistor having a small off-state current is used as the transistor 2230, the period for which the voltage is kept can be lengthened. By this effect, the display rewriting frequency can be reduced in the case where an image with little motion (including a still image) is displayed; accordingly, further reduction in power consumption is possible. Further, the capacitance of the capacitor 2220 can be further reduced; accordingly, power consumed for charging can be reduced.
As described above, according to one embodiment of the present invention, a liquid crystal display device with high display quality and low power consumption can be provided.
This embodiment can be implemented in appropriate combination with the other embodiments.
Embodiment 3
In this embodiment, an example of manufacturing a semiconductor memory device using the transistor described in Embodiment 1 will be described.
Typical examples of a volatile semiconductor memory device include a dynamic random access memory (DRAM) which stores data by selecting a transistor included in a memory element and accumulating electric charges in a capacitor and a static random access memory (SRAM) which holds stored data using a circuit such as a flip-flop.
Typical examples of a nonvolatile semiconductor memory device include a flash memory which has a node between a gate electrode and a channel region of a transistor and stores data by holding an electric charge in the node.
The transistor described in Embodiment 1 can be applied to some of transistors included in the above-described semiconductor memory device.
First, a memory cell included in a semiconductor memory device to which the transistor described in Embodiment 1 is applied will be described with reference to FIGS. 14A and 14B.
A memory cell includes a bit line BL, a word line WL, a sense amplifier SAmp, a transistor Tr, and a capacitor C (see FIG. 14A).
Note that it is known that the voltage held in the capacitor C is gradually decreased with time as shown in FIG. 14B owing to the off-state current of the transistor Tr. A voltage originally charged from V0 to V1 is decreased with time to VA that is a limit for reading out data 1. This period is called a holding period T_1. In the case of a two-level memory cell, refresh operation needs to be performed within the holding period T_1.
Here, when the transistor described in Embodiment 1 is used as the transistor Tr, the holding period T_1 can be increased because off-state current is small. That is, frequency of the refresh operation can be reduced; thus, power consumption can be reduced. For example, in the case where a memory cell is formed using a transistor including an oxide semiconductor film in which an off-state current is less than or equal to 1×10−21 A, preferably less than or equal to 1×10−24 A, data can be held for several days to several tens of years without supply of electric power.
As described above, according to one embodiment of the present invention, a semiconductor memory device with high reliability and low power consumption can be provided.
Next, an example of a memory cell included in a semiconductor memory device to which the transistor described in Embodiment 1 is applied, which is different from the memory cell in FIGS. 14A and 14B, will be described with reference to FIGS. 15A and 15B.
FIG. 15A is a circuit diagram of a memory cell. The memory cell includes a transistor Tr_1, a gate line GL_1 connected to a gate of the transistor Tr_1, a source line SL_1 connected to a source of the transistor Tr_1, a transistor Tr_2, a source line SL_2 connected to a source of the transistor Tr_2, a drain line DL_2 connected to a drain of the transistor Tr_2, a capacitor C, a capacitor line CL connected to one terminal of the capacitor C, and a node N connected to the other terminal of the capacitor C, a drain of the transistor Tr_1, and a gate of the transistor Tr_2.
The memory cell illustrated in FIG. 15A utilizes variation in the threshold voltage of the transistor Tr_2, which depends on the potential of the node N. For example, FIG. 15B shows a relation between a voltage VCL of the capacitor line CL and a drain current Ids_2 flowing through the transistor Tr_2.
Here, the voltage of the node N can be adjusted through the transistor Tr_1. For example, the potential of the source line SL_1 is set to VDD. In this case, when the potential of the gate line GL_1 is set to be higher than or equal to a potential obtained by adding VDD to the threshold voltage Vth of the transistor Tr_1, the potential of the node N can be HIGH. Further, when the potential of the gate line GL_1 is set to be lower than or equal to the threshold voltage Vth of the transistor Tr_1, the potential of the node N can be LOW.
Thus, either a VCL-Ids_2 curve (N=LOW) or a VCL-Ids_2 curve (N=HIGH) can be obtained. That is, when N=LOW, Ids_2 is small at a VCL of 0V; accordingly, data 0 is stored. Further, when N=HIGH, Ids_2 is large at a VCL of 0V; accordingly, data 1 is stored. In such a manner, data can be stored.
Here, when the transistor described in Embodiment 1 is used as the transistor Tr_1, the off-state current of the transistor can be significantly reduced; therefore, unintentional leakage of an electric charge accumulated in the node N by flowing between the source and the drain of the transistor Tr_1 can be suppressed. As a result, data can be held for a long time. Further, since the threshold voltage of the transistor Tr_1 according to one embodiment of the present invention is adjusted, a voltage needed for writing can be reduced; thus, power consumption can be made small compared to a flash memory or the like.
Note that the transistor described in Embodiment 1 may be used as the transistor Tr_2.
As described above, according to one embodiment of the present invention, a semiconductor memory device with high reliability for a long time and low power consumption can be obtained.
This embodiment can be implemented in appropriate combination with the other embodiments.
Embodiment 4
A central processing unit (CPU) can be formed by using the transistor described in Embodiment 1 for at least a part of the CPU.
FIG. 16A is a block diagram illustrating a specific configuration of a CPU. The CPU illustrated in FIG. 16A includes an arithmetic logic unit (ALU) 1191, an ALU controller 1192, an instruction decoder 1193, an interrupt controller 1194, a timing controller 1195, a register 1196, a register controller 1197, a bus interface (Bus I/F) 1198, a rewritable ROM 1199, and an ROM interface (ROM I/F) 1189 over a substrate 1190. A semiconductor substrate, an SOI substrate, a glass substrate, or the like is used as the substrate 1190. The ROM 1199 and the ROM interface 1189 may each be provided over a separate chip. Obviously, the CPU illustrated in FIG. 16A is just an example in which the configuration has been simplified, and an actual CPU may have various configurations depending on the application.
An instruction that is input to the CPU through the bus interface 1198 is input to the instruction decoder 1193 and decoded therein, and then, input to the ALU controller 1192, the interrupt controller 1194, the register controller 1197, and the timing controller 1195.
The ALU controller 1192, the interrupt controller 1194, the register controller 1197, and the timing controller 1195 conduct various controls in accordance with the decoded instruction. Specifically, the ALU controller 1192 generates signals for controlling the operation of the ALU 1191. While the CPU is executing a program, the interrupt controller 1194 judges an interrupt request from an external input/output device or a peripheral circuit on the basis of its priority or a mask state, and processes the request. The register controller 1197 generates an address of the register 1196, and reads/writes data from/into the register 1196 in accordance with the state of the CPU.
The timing controller 1195 generates signals for controlling operation timings of the ALU 1191, the ALU controller 1192, the instruction decoder 1193, the interrupt controller 1194, and the register controller 1197. For example, the timing controller 1195 includes an internal clock generation portion for generating an internal clock signal CLK2 based on a reference clock signal CLK1, and supplies the clock signal CLK2 to the above circuits.
In the CPU illustrated in FIG. 16A, a memory element is provided in the register 1196. The memory element described in Embodiment 3 can be used as the memory element provided in the register 1196.
In the CPU illustrated in FIG. 16A, the register controller 1197 selects operation of holding data in the register 1196 in accordance with an instruction from the ALU 1191. That is, the register controller 1197 selects whether data is held by a phase-inversion element or a capacitor in the memory element included in the register 1196. When data holding by the phase-inversion element is selected, power supply voltage is supplied to the memory element in the register 1196. When data holding by the capacitor is selected, the data is rewritten in the capacitor, and supply of power supply voltage to the memory element in the register 1196 can be stopped.
The supply of the power supply voltage can be stopped by providing a switching element between a memory element group and a node to which a power supply potential VDD or a power supply potential VSS is supplied, as illustrated in FIG. 16B or 16C. Circuits illustrated in FIGS. 16B and 16C will be described below.
In each of FIGS. 16B and 16C, as a switching element for controlling supply of a power supply potential to a memory element, an example of a configuration of a memory circuit including the transistor described in Embodiment 1 is illustrated.
The memory device illustrated in FIG. 16B includes a switching element 1141 and a memory element group 1143 including a plurality of memory elements 1142. Specifically, as each of the memory elements 1142, the memory element described in Embodiment 3 can be used. Each of the memory elements 1142 included in the memory element group 1143 is supplied with the high-level power supply potential VDD via the switching element 1141. Further, each of the memory elements 1142 included in the memory element group 1143 is supplied with a potential of a signal IN and a potential of the low-level power supply potential VSS.
In FIG. 16B, the transistor having a significantly small off-state current described in Embodiment 1 is used as the switching element 1141, and the switching of the transistor is controlled by a signal SigA supplied to a gate thereof.
Note that FIG. 16B illustrates the structure in which the switching element 1141 includes only one transistor; however, without limitation to this structure, the switching element 1141 may include a plurality of transistors. In the case where the switching element 1141 includes a plurality of transistors which serve as switching elements, the plurality of transistors may be connected to each other in parallel, in series, or in combination of parallel connection and series connection.
In FIG. 16C, an example of a memory device in which each of the memory elements 1142 included in the memory element group 1143 is supplied with the low-level power supply potential VSS via the switching element 1141 is illustrated. The supply of the low-level power supply potential VSS to each of the memory elements 1142 included in the memory element group 1143 can be controlled by the switching element 1141.
Data can be held even in the case where a switching element is provided between a memory element group and a node to which the power supply potential VDD or the power supply potential VSS is supplied, an operation of a CPU is temporarily stopped, and the supply of the power supply voltage is stopped; accordingly, power consumption can be reduced. For example, while a user of a personal computer does not stop inputting information to an input device such as a keyboard, the operation of the CPU can be stopped, so that the power consumption can be reduced.
Although the CPU is given as an example, the transistor can also be applied to an LSI such as a digital signal processor (DSP), a custom LSI, or a field programmable gate array (FPGA).
This embodiment can be implemented in appropriate combination with the other embodiments.
Embodiment 5
In this embodiment, examples of an electronic device to which any of Embodiments 1 to 4 is applied will be described.
FIG. 17A illustrates a portable information terminal. The portable information terminal illustrated in FIG. 17A includes a housing 9300, a button 9301, a microphone 9302, a display portion 9303, a speaker 9304, and a camera 9305, and has a function as a mobile phone. One embodiment of the present invention can be applied to the display portion 9303 and the camera 9305. Although not illustrated, one embodiment of the present invention can also be applied to an arithmetic unit, a wireless circuit, or a memory circuit in a main body.
FIG. 17B illustrates a display, which includes a housing 9310 and a display portion 9311. One embodiment of the present invention can be applied to the display portion 9311. By application of one embodiment of the present invention, a display with high display quality and low power consumption can be provided even when the size of the display portion 9311 is increased.
FIG. 17C illustrates a digital still camera. The digital still camera illustrated in FIG. 17C includes a housing 9320, a button 9321, a microphone 9322, and a display portion 9323. One embodiment of the present invention can be applied to the display portion 9323. Although not illustrated, one embodiment of the present invention can also be applied to a memory circuit or an image sensor.
By application of one embodiment of the present invention, power consumption of an electronic device can be reduced and the reliability of the electronic device can be improved.
This embodiment can be implemented in appropriate combination with the other embodiments.
Example 1
In this example, a specific example in which hydrogen released from an oxide semiconductor film is transferred to a hydrogen capture film through a hydrogen permeable film will be described using SIMS results of a sample subjected to heat treatment and a sample not subjected to heat treatment.
Samples in each of which a 300 nm thick oxide semiconductor film (In—Ga—Zn—O film) was deposited over a quartz substrate, a 5 nm thick silicon oxide film was deposited over the oxide semiconductor film, and a 300 nm thick oxynitride film (In—Ga—Zn—O—N film) was deposited over the silicon oxide film were prepared.
The oxide semiconductor film was deposited by a sputtering method under the following conditions: an In—Ga—Zn—O target (In2O3:ZnO:Ga2O3=1:1:2 [molar ratio]) was used, the electric power applied between the target and the substrate was set to 500 W (DC), the deposition pressure was set to 0.4 Pa, the deposition gas was argon at the flow rate of 30 sccm and oxygen at the flow rate of 15 sccm, and the temperature of the substrate surface during heat treatment was set to 200° C.
The silicon oxide film was deposited by a sputtering method under the following conditions: a synthesized quartz target was used, the deposition electric power was set to 1 kW, the deposition pressure was set to 0.4 Pa, the deposition gas was argon at the flow rate of 25 sccm and oxygen at the flow rate of 25 sccm, and the temperature of the substrate surface during heat treatment was set to 100° C.
The oxynitride film was deposited by a sputtering method under the following conditions: a In—Ga—Zn—O target (In2O3:ZnO:Ga2O3=1:1:2 [molar ratio]) was used, the deposition electric power was set to 500 W, the deposition pressure was set to 0.4 Pa, the deposition gas was argon at the flow rate of 40 sccm, and the temperature of the substrate surface during heat treatment was set to 200° C.
FIG. 18A shows the concentration distribution of hydrogen in the depth direction measured with SIMS, and FIG. 18B shows the concentration distribution of nitrogen in the depth direction measured with SIMS. Here, a range 6001 shows the oxynitride film, a range 6002 shows the silicon oxide film, a range 6003 shows the oxide semiconductor film, and a range 6004 shows the quartz substrate. Note that the range 6002 is not quantified. In addition, an accurate quantitative value in a region in the vicinity of each layer is not obtained due to a matrix effect. Note that the SIMS analysis was performed using IMS 7fR manufactured by CAMECA Societe par Actions Simplifiée (SAS).
In FIG. 18A, a thin line 6010 indicates the concentration distribution of hydrogen of the sample in a state immediately after the deposition and a thick line 6020 indicates the concentration distribution of hydrogen of the sample subjected to heat treatment at 550° C. in a nitrogen atmosphere for an hour after the deposition. Such concentration distribution reveals that the hydrogen concentration in the oxide semiconductor film is reduced and the hydrogen concentration in the oxynitride film is increased by performing the heat treatment, i.e., that hydrogen is transferred from the oxide semiconductor film to the oxynitride film through the silicon oxide film by the heat treatment.
In FIG. 18B, a thin line 6030 indicates the concentration distribution of nitrogen of the sample in a state immediately after deposition and a thick line 6040 indicates the concentration distribution of nitrogen of the sample subjected to heat treatment at 550° C. in a nitrogen atmosphere for an hour after the deposition. Such concentration distribution reveals that the concentration distribution of nitrogen in the samples before and after the heat treatment hardly varies.
This application is based on Japanese Patent Application Serial No. 2011-067195 filed with Japan Patent Office on Mar. 25, 2011, the entire contents of which are hereby incorporated by reference.

## Claims

1. A method for manufacturing a semiconductor device comprising the steps of:
forming a gate electrode over a substrate;
forming a gate insulating film so as to cover the gate electrode;
forming an oxide semiconductor film over the gate insulating film;
forming a pair of electrodes over the oxide semiconductor film, the pair of electrodes being in contact with at least part of the oxide semiconductor film;
forming a protective film over the oxide semiconductor film and the pair of electrodes; and
performing heat treatment so as to release hydrogen from the oxide semiconductor film,
wherein the protective film comprises a hydrogen capture film and a hydrogen permeable film which are stacked in this order.

2. The method for manufacturing a semiconductor device according to claim 1,
wherein the hydrogen released from the oxide semiconductor film is transferred to the hydrogen capture film through the hydrogen permeable film by the heat treatment.

3. The method for manufacturing a semiconductor device according to claim 1,
wherein the hydrogen permeable film comprises an oxide film, and
wherein oxygen is transferred from the hydrogen permeable film to the oxide semiconductor film by performing the heat treatment.

4. The method for manufacturing a semiconductor device according to claim 1,
wherein the hydrogen capture film and the oxide semiconductor film comprise at least a metal element, and
wherein the hydrogen permeable film does not include the metal element.

5. The method for manufacturing a semiconductor device according to claim 1,
wherein the hydrogen capture film comprises an oxynitride film containing indium.

6. The method for manufacturing a semiconductor device according to claim 1,
wherein the hydrogen permeable film comprises a silicon oxide film or a silicon oxynitride film.

7. The method for manufacturing a semiconductor device according to claim 1,
wherein the oxide semiconductor film comprises an In—Ga—Zn—O based film, and
wherein the hydrogen capture film comprises an In—Ga—Zn—O—N based film.

8. The method for manufacturing a semiconductor device according to claim 1,
wherein a thickness of the hydrogen permeable film is less than or equal to 5 nm.

9. The method for manufacturing a semiconductor device according to claim 1,
wherein a temperature of the heat treatment is higher than 450° C. and lower than a strain point of the substrate.

10. A semiconductor device comprising:
a base film;
an oxide semiconductor film over the base film;
a gate insulating film over the oxide semiconductor film;
a gate electrode over the oxide semiconductor film with the gate insulating film provided therebetween; and
a pair of electrodes in contact with at least part of the oxide semiconductor film,
wherein the base film comprises a hydrogen capture film and a hydrogen permeable film which are stacked in this order.

11. The semiconductor device according to claim 10,
wherein the hydrogen capture film comprises an oxynitride film including indium, and
wherein the hydrogen permeable film comprises a silicon oxide film or a silicon oxynitride film.

12. The semiconductor device according to claim 10,
wherein the oxide semiconductor film comprises an In—Ga—Zn—O based film, and
wherein the hydrogen capture film comprises an In—Ga—Zn—O—N based film.

13. The semiconductor device according to claim 10,
wherein a thickness of the hydrogen permeable film is less than or equal to 5 nm.

14. The semiconductor device according to claim 10,
wherein the hydrogen permeable film is configured to transfer oxygen to the oxide semiconductor film by a heat treatment.

15. A semiconductor device comprising:
a gate electrode;
a gate insulating film covering the gate electrode;
an oxide semiconductor film over the gate electrode with the gate insulating film provided therebetween;
a pair of electrodes in contact with at least part of the oxide semiconductor film; and
a protective film over the oxide semiconductor film,
wherein the protective film comprises a hydrogen permeable film and a hydrogen capture film which are stacked in this order.

16. The semiconductor device according to claim 15,
wherein the hydrogen capture film comprises an oxynitride film including indium, and
wherein the hydrogen permeable film comprises a silicon oxide film or a silicon oxynitride film.

17. The semiconductor device according to claim 15,
wherein the oxide semiconductor film comprises an In—Ga—Zn—O based film, and
wherein the hydrogen capture film comprises an In—Ga—Zn—O—N based film.

18. The semiconductor device according to claim 15,
wherein a thickness of the hydrogen permeable film is less than or equal to 5 nm.

19. The semiconductor device according to claim 15,
wherein the hydrogen permeable film is configured to transfer oxygen to the oxide semiconductor film by a heat treatment.

20. A semiconductor device comprising:
a first insulating film;
an oxide semiconductor film over the first insulating layer;
a pair of electrodes over and in contact with at least part of the oxide semiconductor film; and
a second insulating film over the oxide semiconductor film and the pair of electrodes,
wherein one of the first insulating film and the second insulating film comprises a third insulating film and a fourth insulating film which are stacked, the third insulating film being adjacent to the oxide semiconductor film,
wherein the third insulating film and the fourth insulating film are configured to transfer hydrogen from the oxide semiconductor film to the fourth insulating film through the third insulating film by a heat treatment,
wherein the hydrogen is captured by the fourth insulating film.

21. The semiconductor device according to claim 20,
wherein the fourth insulating film comprises an oxynitride film including indium, and,
wherein the third insulating film comprises a silicon oxide film or a silicon oxynitride film.

22. The semiconductor device according to claim 20,
wherein the oxide semiconductor film comprises an In—Ga—Zn—O based film, and
wherein the fourth insulating film comprises an In—Ga—Zn—O—N based film.

23. The semiconductor device according to claim 20,
wherein a thickness of the third insulating film is less than or equal to 5 nm.

24. The semiconductor device according to claim 20,
wherein the third insulating film is configured to transfer oxygen to the oxide semiconductor film by a heat treatment.