# Patent

## Title
P-N junction for use as an RF mixer from GHZ to THZ frequencies

## Abstract

This disclosure describes a semiconductor device that can be used as a mixer at RF frequencies extending from a few tens of GHz into the THz frequency range. The device is composed of narrow bandgap semiconductors grown by solid source molecular beam epitaxy. The device can comprise a GaSb substrate, a AlSb layer on the GaSb substrate, a In0.69Al0.31As0.41Sb0.59 layer, on the AlSb layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping, a In0.27Ga0.73Sb layer on the In0.69Al0.31As0.41 Sb0.59 layer, wherein the In0.27Ga0.73Sb layer is Be doped, wherein the first section of the In0.69Al0.31As0.41Sb0.59 layer has is Te doped, wherein the second section of the In0.69Al0.31As0.41Sb0.59 layer has a grade in Te concentration, and wherein the third section of the In0.69Al0.31As0.41Sb0.59 layer is Te doped.

## Background
This application claims the benefit of U.S. Provisional Patent Application No. 61/129,188 filed on Jun. 10, 2008, the entirety of which is herein incorporated by reference.


This disclosure describes a semiconductor device that can be used as a mixer at RF frequencies extending from a few tens of GHz into the THz frequency range.
The device is composed of narrow bandgap semiconductors grown by solid source molecular beam epitaxy. The narrow bandgaps allows the p-n heterojunction to operate as a mixer with considerably lower local oscillator (LO) power than required by currently available high frequency mixers.
Mixers are used in a large variety of communication and radar systems over a very wide range of frequencies. The narrow bandgap semiconductors used in this p-n heterojunction exhibit very high electron mobilities and very low contact resistances. It is these properties that enable the mixer to operate at THz frequencies.
Currently, there is a great interest in developing electronic devices that work in the THz frequency range for use in cameras for recording images, and in spectroscopic systems for the detection of chemical and biological agents, and a mixer is a critical component in these applications.
Existing semiconductor mixers require a local oscillator signal source to operate, and in some cases a combination of a DC bias and a local oscillator source are used. DC bias sources are not desirable as they introduce noise into the system. In many implementations, using a DC bias will complicate the circuitry as additional wires must be used to connect it to a mixer. The DC interconnect problem becomes particularly difficult in focal plane imaging arrays containing thousands of pixels, as a DC connection is needed for each pixel. At operating frequencies above about 100 GHz, currently available detectors require several milliwatts of local oscillator power. This is a significant problem as small high-power local oscillator sources at these frequencies are not readily available. The lack of readily-integrable sources is an impediment in the development of portable hand-held or space-based systems where weight is a major concern.
This disclosure describes the employment of narrow bandgap semiconductors in the production of the p-n mixer diode, allowing the diode to change its state from a low conductance to high conductance at a very low forward voltage. As a result, the mixer will operate with a low-power local oscillator source, and without a DC bias.
Another aspect is that the use of these semiconductors will introduce smaller parasitic resistances and reactances than what might be obtainable from conventional semiconductors, and thus will function at higher operating frequencies than currently available mixers.
The use of molecular beam epitaxial deposition techniques allows the growth of thin semiconductor layers that result in the short transit times needed for high-speed operation, and is compatible with standard lithographic fabrication processes.
Mixers use the nonlinear current-voltage (I-V) characteristic of a semiconductor diode to frequency-convert an RF signal. As a result of the nonlinear behavior of the diode the signal of interest at frequency ωS is multiplied with the local oscillator signal at frequency ωLO to produce output signals at all the sum and difference frequencies. These intermediate frequencies, ωIF, are easily filtered and amplified for further processing. The most interesting frequencies for applications where ωS is in the THz frequency range are often ωIF=nωLO±ωS where n is an integer. This is particularly true when there are no small light-weight local oscillator sources with adequate power output.
A DC bias voltage may be used to operate at the most desirable part of the diode's I-V characteristic in order to use a low-power local oscillator, but that is often not useful solution. A DC source adds unwanted electronic noise, and there can be problems with filtering and the wire layouts needed to apply the DC bias. These difficulties are multiplied many times when the mixer is to be used in an imaging application where local oscillator power is needed for each of the pixels in an array that may contain several thousand pixels.



BRIEF DESCRIPTION OF THE FIGURES
FIG. 1 is a graph illustrating voltage dependence calculated for an ideal diode with the saturation density of the new In0.27Ga0.73Sb diode and a GaAs diode.
FIG. 2 is a graph illustrating the energy band structure for a p-type InzGa1-zSb/InxAl1-xAsySb1-y diode. z=0.27, x=0.69, y=0.41 for the diode in FIG. 4.
FIG. 3 illustrates a diode layer structure.
FIG. 4 illustrates a diode mesa schematic.
FIG. 5 illustrates current-voltage characteristics of the p-n junction.
FIG. 6 illustrates an improved diode layer structure with SI—InP substrate.
FIG. 7 illustrates an improved diode layer structure with SI—GaAs substrate.
FIG. 8 illustrates an improved diode layer structure with SI—InP substrate.
FIG. 9 illustrates an improved diode layer structure with SI—GaAs substrate.
FIG. 10 illustrates an antiparallel diode pair.



This disclosure addresses the local oscillator power deficiency problem by using a new narrow-bandgap heterojunction diode that requires less local oscillator power than required by currently available mixer diodes.
GaAs Schottky barrier diodes currently represent the state-of-the-art in commercially available mixer diodes. The current-voltage characteristic of a diode may be calculated using J=JS(eqV/ηKT−1) where J is the current density (amperes per diode area), V is the applied bias (volts), q the electronic charge (coulombs), η the ideality factor, usually  ̃1, K the Boltzmann factor (joules/Kelvin) T the temperature (Kelvin), and JS the saturation current density. The saturation current densities reported in the literature for GaAs diodes are in the range of 1×10−6 A/cm2 or less, which is 4 orders of magnitude smaller than the 1×10−2 A/cm2 typical saturation current density measured for the In0.27Ga0.73Sb/In0.69Al0.31As0.41Sbl0.59 heterojunction diode in this application.
The difference between these diodes is illustrated in FIG. 1 where the bias dependence of the current density using this model is plotted for the two diodes. An aspect to note is that the In0.27Ga0.73Sb diode reaches a given forward bias current at a much lower bias than a GaAs diode. A figure of merit is the bias where the current density is 1 μA/μm2 or 102 A/cm2 which is 0.23 V for the In0.27Ga0.73Sb and 0.47 V, or twice as much, for the GaAs Schottky diode. This translates into the In0.27Ga0.73Sb diode operating at lower local oscillator power than a GaAs diode.
While the diode illustrated here uses a pair of semiconductors with the In0.27Ga0.73Sb/In0.69Al0.31As0.41Sbl0.59 composition with a lattice constant of 6.2 Å many other compositions are possible. The bandgap of the InzGa1-zSb alloy decreases as the indium fraction increases from z=0.27, and these even narrower bandgap diodes would require even lower local oscillator power levels
The bandgap for the InzGa1-zSb heterojunction diode is illustrated in FIG. 2. It is composed of a very thin p-type InzGa1-zSb layer and a thicker n-type InxAl1-xAsySb1-y layer.
A large saturation current density is required to have a mixer that will operate with a low power-local oscillator source. The saturation current density for this heterojunction is largely set by the bandgap of the InzGa1-zSb layer. The structure reported here has z=0.27 and a bandgap of 0.5 eV.
Larger saturation current densities can be obtained by using a larger In concentration in the p layer to obtain a smaller bandgap. It may be necessary to have the same lattice constant in both the n and p layers of the heterostructure. This can be accomplished by adjusting the composition of the InxAl1-xAsySb1-y n layer to have the same lattice constant as the InzGa1-zSb being used.
For a given lattice constant, the bandgap of the InxAl1-xAsySb1-y layer may be adjusted by varying both the In/Al and As/Sb concentrations. This is useful in adjusting the conduction band offset between the InzGa1-zSb layer and the InxAl1-xAsySb1-y layer. The conduction band offset between the InzGa1-zSb and InxAl1-xAsySb1-y is a parameter that may be adjusted to obtain optimum performance.
EXAMPLE
A version of the diode with the energy band structure shown in FIG. 2, has been grown and tested and the complete layer structure is shown in FIG. 3. The AlSb layer has a lattice constant of 6.1355 Å and helps to accommodate the lattice mismatch between the GaSb substrate with a 6.0954 Å lattice constant and the p-n layers with a 6.2 Å lattice constant.
A 1.2 μm thick In0.69Al0.31As0.41Sb0.59 layer is used to allow the strain due to growing it on an AlSb layer to relax before forming the p-n junction.
The bottom 0.1 μm of the In0.69Al0.31As0.41Sb0.59 layer is more heavily doped to provide a low resistance path between the p-n region and the bottom ohmic contact metallization illustrated by the mesa schematic shown in FIG. 4.
The Te concentration is graded through a 0.1 μm In0.69Al0.31As0.41Sb0.59 to the concentration desired for the n layer part of the junction. The In0.69Al0.31As0.41Sb0.59 layer is designed to have a bandgap of about 0.8 eV with a valence band offset near 350 meV according to work by Glisson and et al and Vurgaftman et al. According to the same work, the 0.2 μm In0.27Ga0.73Sb p-type layer has a bandgap near 0.5 eV.
The p layer has been placed on top of the n layer in this structure as this is expected to result in a better definition of the doping profile with little intermixing.
The I-V data for a square mesa diode 55 μm on and edge is shown in FIG. 5. The forward current reaches a current density of one μA/μm2 at 0.25 V, which is low compared to GaAs diodes as illustrated in FIG. 1.
The diode has an ideality factor. η, near one indicating that high quality semiconductor material was used to form the p-n junction.
The low currents found at several volts reverse bias are another indication that the diode is made of good quality semiconductor material.
Similar diodes with the improved layer structure illustrated in FIG. 6 and using advanced lithography to obtain 5 μm diameter diodes also have the high saturation current density illustrated here and η ̃1. A series resistance, Rs, of four ohms and a zero bias capacitance of C0=23 Ff have been measured for these small diodes. These results are used to calculate a cutoff frequency of 1⁄2πRsC0=1.7 THz for these diodes. This is close to the cutoff frequencies found for GaAs mixer diodes, and is expected to increase with improvements in device design and material quality.
This improved diode structure uses an InP substrate that is semi-insulating unlike the GaSb substrate in FIG. 3. Using a semi-insulating substrate allows the development of complex circuits needing electrically isolated devices on a single substrate.
The InP substrate has a lattice constant of 5.869 Å that requires a more complex buffer layer structure composed of In0.52Al0.48As that is lattice matched to InP. This layer is used to smooth the starting InP surface and to transition from a phosphorus based semiconductor to an arsenic based one. The Al0.65Ga0.35Sb layer has a 6.122 Å lattice constant and is used to grade toward the 6.2 Å lattice constant of the p-n junction. The In0.19Ga0.19Al0.62Sb layer has a 6.2 Å lattice constant and is used to complete the transition from the InP substrate lattice constant to the 6.2 Å lattice constant of junction layers.
The Al0.65Ga0.35Sb and In0.19Ga0.19Al0.62Sb layers have high resistivities that will allow device isolation in complex circuits.
In addition, the 0.65 or lower Al fraction was chosen to minimize oxidation problems that would occur with AlSb.
The heavily n-type doped In0.27Ga0.73Sb is used as a contact layer to connect the bottom of the p-n mesa to the bottom ohmic contact metallization pad. In FIG. 4 the bottom ohmic contact pad is on the In0.69Al0.31As0.41Sb0.59 layer to the right of the mesa. In0.27Ga0.73Sb is used as the contact layer in FIG. 6 to minimize the parasitic resistance of this layer. This comes about as it has a mobility of 4500 cm2/Vs compared to about 2500 cm2/Vs for the In0.69Al0.31As0.41Sb0.59 used in FIG. 3. In addition, it is much easier to grow In0.27Ga0.73Sb than In0.69Al0.31As0.41Sb0.59. The SI—InP was used as it is frequently used in modern semiconductor electronics and to demonstrate that the p-n heterojunction could be made on it.
Example
Another embodiment includes a device with a substrate wherein the substrate is GaAs or InP, wherein the substrate is undoped, a GaAs layer on the substrate, wherein the GaAs layer is undoped, an Al0.65Ga0.35Sb layer on the GaAs layer, wherein the Al0.65Ga0.35Sb layer is undoped, an In0.19Ga0.19 Al0.62Sb layer on the Al0.65Ga0.35Sb, wherein the In0.19Ga0.19 Al0.62Sb layer is undoped, an InAs0.66Sb0.34 layer on the In0.19Ga0.19 Al0.62Sb, wherein the InAs0.66Sb0.34 layer is Te doped, an In0.69Al0.31As0.41Sb0.59 layer with a top side and a bottom side, wherein the bottom side is on the InAs0.66Sb0.34 layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping, and a InzGa1-zSb layer on the In0.69Al0.31As0.41Sb0.59 layer, wherein the InzGa1-zSb layer is doped with Be.
The device as outlined above can be such that the InAs0.66Sb0.34 layer is from about 0.1μ to about 1.0μ thick and in particular about 0.5μ thick and wherein the InAs0.66Sb0.34 layer has about 1.5×1018 Te cm−3 to about 3.0×1018 Te cm−3 and in particular about 2.5×1018 Te cm−3.
The device can be such that the In0.69Al0.31As0.41Sb0.59 layer is about 75 nm to about 300 nm thick and in particular about 140 nm thick and comprises a first section of about 3 nm to about 50 nm and in particular about 10 nm from the bottom side, a second section of about 10 nm to about 100 nm and in particular about 30 nm from the first section; and a third section of about 50 nm to about 200 nm and in particular about 100 nm from the second section, wherein the first section of about 3 nm to about 50 nm and in particular about 10 nm of the In0.69Al0.31As0.41Sb0.59 layer from the bottom side has Te doping and in particular about 6.4×1018 Te cm−3, wherein the second section of about 10 nm to about 100 nm and in particular about 30 nm of the In0.69Al0.31As0.41Sb0.59 layer from the first section has a grade in Te concentration, and wherein the third section of about 100 nm of the In0.69Al0.31As0.41Sb0.59 layer from the second section has about 2×1017 Te cm−3.
The device can be such that the InzGa1-zSb layer is about 20 nm to about 200 nm and particular about 50 nm thick.
The device can be such that the InzGa1-zSb layer has varying amounts of Be doping and in particular about 1×1019 Be cm−3.
The device can be such that the Al0.65Ga0.35Sb layer has a lattice constant of 6.12 Å and wherein the GaAs substrate has a lattice constant of 5.653 Å and wherein the, In0.19Ga0.19 Al0.62Sb, InAs0.66Sb0.34, In0.69Al0.31As0.41Sb0.59 and InzGa1-zSb layers have a lattice constant of 6.2 Å.
The device can be such that it can be used as a mixer at RF frequencies extending from about 20 GHz to about 2 THz frequency range.
The device can be such that the device can be used as a mixer at RF frequencies of about 2 THz.
The device can be such that the bandgap of the InzGa1-zSb alloy decreases as the indium fraction increases from z=0.27.
The device can further include a mesa ohmic contact on the In0.27Ga0.73Sb layer; and a bottom ohmic contact on the InAs0.66Sb0.34 layer.
A method of making a p-n junction for use as an RF mixer from GHz to THz frequencies by providing a GaAs substrate, wherein the GaAs substrate is undoped. growing by solid source molecular beam epitaxy a GaAs layer on the GaAs substrate, wherein the GaAs is undoped, growing by solid source molecular beam epitaxy a Al0.65Ga0.35Sb layer on the GaAs, wherein the Al0.65Ga0.35Sb layer is undoped, growing an by solid source molecular beam epitaxy In0.19Ga0.19 Al0.62Sb layer on the Al0.65Ga0.35Sb, wherein the In0.19Ga0.19 Al0.62Sb layer is undoped, growing by solid source molecular beam epitaxy an InAs0.66Sb0.34 layer, wherein the InAs0.66Sb0.34 layer is Te doped, growing by solid source molecular beam epitaxy a In0.69Al0.31As0.41Sb0.59 layer with a top side and a bottom side, wherein the bottom side is on the InAs0.66Sb0.34 layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping, growing a In0.27Ga0.73Sb layer on the In0.69Al0.31As0.41Sb0.59 layer, wherein the In0.27Ga0.73Sb layer is doped with Be.
Commercially available mixers are generally Schottky barriers on GaAs or Si. The Si devices operate at frequencies of 40 GHz or lower which is well below the frequency range of the application we are addressing. GaAs diodes do operate at frequencies in the THz but they require several mW of local oscillator power when a DC bias is not used.
The saturation current density of a diode is a measure of the LO power that will be required. Mixer diodes with a large saturation current density will need less LO power than a mixer with low saturation current density. The mixer diode here has a saturation density  ̃1×10−2 A/cm2 compared to <10−6 A/cm2 for GaAs Schottky mixer diodes in support of the claim to a lower LO power for the mixer reported here.
Reducing parasitic series resistances will lead to additional reductions in LO power, and to higher frequency operation. Alternatively, to attain the desired cutoff frequency the lower resistances will allow the use of devices with larger areas leading to higher capacitances. Using larger area devices means using simpler lithography techniques in the device fabrication.
The narrow bandgap materials used in this diode generally have higher mobilities than GaAs leading to smaller parasitic series resistances for a given geometry. Comparisons between GaAs Schottky diodes and the ones presented here is problematic because of the uncertainties in proprietary commercial device geometry, but comparisons can be estimated on the basis of Hall Effect data.
The n-type In0.27Ga0.73Sb used for the contact layer in FIG. 6 has a carrier concentration of 2.5×1018 cm−3 and mobility of 4.4×103 cm2/Volt-sec while GaAs with the same carrier concentration has a mobility of only 2×103 cm2/Volt-sec.3 The advanced structures in FIGS. 8 and 9 below use InAs0.64Sb0.36 for this layer and it has an even higher mobility of 5.5×103 cm2/Volt-sec.
For the diode geometry used here, the mesa resistance is not the dominant resistance, which limits the impact of the In0.69Al0.31As0.41Sb0.59 layer having a mobility near 2.5×103 cm2/Volt-sec that is lower than that for GaAs at the same carrier concentration.
A number of improvements can be made to the layer structure in FIG. 3. GaSb substrates are conducting and are not useable for circuit applications. Semi-insulating substrates are required for circuit applications where devices need to be electrically isolated.
Mixer diodes have been successfully grown by our group on both semi-insulating InP, illustrated in FIG. 6, and on SI GaAs as shown in FIG. 7. The thicknesses of the various layers can be optimized to reduce the parasitic series resistances in order to increase the cutoff frequency.
The thickness of the p-type In0.27Ga0.73Sb has been reduced to 50 nm and the doping increased to 1×1019 Be cm−3 to reduce the p layer resistance to one tenth that of the structure in FIG. 3.
The 1.2 μm thick In0.69Al0.31As0.41Sb0.59 layer has been replaced by a 140 nm In0.69Al0.31As0.41Sb0.59 layer doped at 2×1017 Te cm−3 near the junction.
The combined effect of these changes is a reduction of the resistance of the In0.69Al0.31As0.41Sb0.59 by a factor of forty.
The resistance between the bottom ohmic contact and the p-n layers has been reduced by about 60 by using a 0.5 μm In0.27Ga0.73Sb doped to have an electron concentration of 2.5×1018 cm−3. The improvements come from the higher doping and the higher mobility, 4400 cm2/Vs, for the In0.27Ga0.73Sb, compared to 2500 cm2/Vs for the In0.69Al0.31As0.41Sb0.59.
Additional improvements can be obtained by replacing the 0.5 μm n-type In0.27Ga0.73Sb with a 0.5 μm InAs0.66Sb0.34 2.5×1018 Te cm−3 layer. This can be done as shown in FIGS. 8 and 9 for both GaAs and InP substrates. InAs0.66Sb0.34 doped at this level has a mobility near 5500 cm2/Vs that is higher than that of In0.27Ga0.73Sb leading to a reduction in resistance.
The smaller bandgap of the InAs0.66Sb0.34. 0.15 eV compared to 0.5 eV for the In0.27Ga0.73Sb, will result in a smaller metal-semiconductor contact resistance which helps to reduce the parasitic series resistance and improve the frequency response.
The LO power required may be reduced by developing mixer diodes with a higher In fraction in the p-type InGaSb layer. These alloys will have a lattice constant larger than the 6.2 Å for the In0.27Ga0.73Sb alloy and may require replacing the In0.69Al0.31As0.41Sb0.59 layer and the InGaSb contact layer with new alloys with a higher In fraction. These alloys would have lower resistances than those used here resulting in an even higher cutoff frequency.
This new p-n mixer can be used in the antiparallel pair configuration illustrated in FIG. 9. This geometry is often used in subharmonic mixer applications.
The foregoing written specification is considered to be sufficient to enable one skilled in the art to practice the invention. The foregoing description details certain preferred embodiments and describes the best mode contemplated by the inventors. It will be appreciated, however, that no matter how detailed the foregoing may appear in text, the present embodiments may be practiced in many ways and should be construed in accordance with the appended claims and any equivalents thereof.

## Claims

1. A device comprising:
a GaSb substrate,
wherein the GaSb substrate is undoped;

a AlSb layer on the GaSb substrate,
wherein the AlSb layer is undoped;

a In0.69Al0.31As0.41Sb0.59 layer with a top side and a bottom side,
wherein the bottom side is on the AlSb layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping; and a In0.27Ga0.73Sb layer on the In0.69Al0.31As0.41Sb0.59 layer,
wherein the In0.27Ga0.73Sb layer is doped with Be;

wherein the In0.69Al0.31As0.41Sb0.59 layer is about 1.2 μm thick and consists of
a first section of about 0.1 μm from the bottom side;
a second section of about 0.1 μm from the first section; and
a third section of about 1 μm from the second section;
wherein the first section of about 0.1 μm of the In0.69Al0.31As0.41Sb0.59 layer from the bottom side has about 1.3×1017 Te cm−3;
wherein the second section of about 0.1 μm of the In0.69Al0.31As0.41Sb0.59 layer from the first section has a grade in Te concentration; and
wherein the third section of about 1 μm of the In0.69Al0.31As0.41Sb0.59 layer from the second section has about 4×1016 Te cm−3.

2. The device of claim 1 wherein the In0.27Ga0.73Sb layer is about 200 nm thick and
wherein the In0.27Ga0.73Sb layer has about 3×1018 Be cm−3.

3. The device of claim 2 wherein the ideality factor is near 1 and the saturation current density is about 2.5×10−2 Å/cm2.

4. The device of claim 3 wherein the AlSb layer has a lattice constant of 6.1355 Å and wherein the GaSb substrate has a lattice constant of 6.0954 Å.

5. The device of claim 4 wherein the In0.69Al0.31As0.41Sb0.59 and In0.27Ga0.73Sb layers have a lattice constant of 6.2 Å.

6. The device of claim 5 wherein the device can be used as a mixer at RF frequencies extending from a few tens of GHz into the THz frequency range.

7. The device of claim 6 wherein the device can be used as a mixer at RF frequencies of about 1 THz.

8. The device of claim 1 wherein the In0.27Ga0.73Sb layer has a bandgap of 0.5 eV.

9. The device of claim 1 wherein a larger saturation current density can be obtained by increasing the In concentration in the In0.69Al0.31As0.41Sb0.59 layer to obtain a smaller bandgap.

10. The device of claim 1 further including
a mesa ohmic contact on the In0.27Ga0.73Sb layer; and
a bottom ohmic contact on the In0.69Al0.31As0.41Sb0.59 layer.

11. A device comprising:
a substrate wherein the substrate is GaAs or InP,
wherein the substrate is undoped;

a GaAs layer on the substrate,
wherein the GaAs layer is undoped;

an Al0.65Ga0.35Sb layer on the GaAs layer,
wherein the Al0.65Ga0.35Sb layer is undoped;

an In0.19Ga0.19 Al0.62Sb layer on the Al0.65Ga0.35Sb,
wherein the In0.19Ga0.19Al0.62Sb layer is undoped;

an InAs0.66Sb0.34 layer on the In0.19Ga0.19Al0.62Sb,
wherein the InAs0.66Sb0.34 layer is Te doped;

an In0.69Al0.31As0.41Sb0.59 layer with a top side and a bottom side,
wherein the bottom side is on the InAs0.66Sb0.34 layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping; and

a InzGa1-zSb layer on the In0.69Al0.31As0.41Sb0.59 layer,
wherein the InzGa1-zSb layer is doped with Be and wherein z=0.27.

12. The device of claim 11 wherein the InAs0.66Sb0.34 layer is about 0.5μ thick.

13. The device of claim 11 wherein the InAs0.66Sb0.34 layer has about 2.5×1018 Te cm−3.

14. The device of claim 11 wherein the In0.69Al0.31As0.41Sb0.59 layer is about 140 nm thick and comprises
a first section of about 10 nm from the bottom side;
a second section of about 30 nm from the first section; and
a third section of about 100 nm from the second section;
wherein the first section of about 10 nm of the In0.69Al0.31As0.41Sb0.59 layer from the bottom side has about 6.4×1018 Te cm−3;
wherein the second section of about 30 nm of the In0.69Al0.31As0.41Sb0.59 layer from the first section has a grade in Te concentration; and
wherein the third section of about 100 nm of the In0.69Al0.31As0.41Sb0.59 layer from the second section has about 2×1017 Te cm−3.

15. The device of claim 11 wherein the InzGa1-zSb layer is about 50 nm thick.

16. The device of claim 11 wherein the InzGa1-zSb layer has about 1×1019 Be cm−3.

17. The device of claim 11 wherein the Al0.65Ga0.35Sb layer has a lattice constant of 6.12 Å and wherein the GaAs substrate has a lattice constant of 5.653 Å and wherein the, In0.19Ga0.19 Al0.62Sb, InAs0.66Sb0.34, In00.69Al0.31As0.41Sb0.59 and InzGa1-zSb layers have a lattice constant of 6.2 Å.

18. The device of claim 11 wherein the device can be used as a mixer at RF frequencies extending from about 20 GHz to about 2 THz frequency range.

19. The device of claim 11 wherein the device can be used as a mixer at RF frequencies of about 2 THz.

20. The device of claim 11 wherein the bandgap of the InzGa1-zSb alloy decreases as the indium fraction increases from z=0.27.

21. The device of claim 11 further including
a mesa ohmic contact on the In0.27Ga0.73Sb layer; and
a bottom ohmic contact on the InAs0.66Sb0.34 layer.

22. A method of making a p-n junction for use as an RF mixer from GHz to THz frequencies comprising:
providing a GaAs substrate,
wherein the GaAs substrate is undoped;

growing by solid source molecular beam epitaxy a GaAs layer on the GaAs substrate,
wherein the GaAs is undoped;

growing by solid source molecular beam epitaxy a Al0.65Ga0.35Sb layer on the GaAs, wherein the Al0.65Ga0.35Sb layer is undoped;
growing an by solid source molecular beam epitaxy In0.19Ga0.19Al0.62Sb layer on the Al0.65Ga0.35Sb
wherein the In0.19Ga0.19 Al0.62Sb layer is undoped;

growing by solid source molecular beam epitaxy an InAs0.66Sb0.34 layer,
wherein the InAs0.66Sb0.34 layer is Te doped;


growing by solid source molecular beam epitaxy a In0.69Al0.31As0.41Sb0.59 layer with a top side and a bottom side,
wherein the bottom side is on the InAs0.66Sb0.34 layer and wherein the In0.69Al0.31As0.41Sb0.59 comprises varying levels of Te doping;

growing a In0.27Ga0.73Sb layer on the In0.69Al0.31As0.41Sb0.59 layer,
wherein the In0.27Ga0.73Sb layer is doped with Be.