# Patent

## Title
UV filter combinations comprising benzylidene malonates

## Abstract

Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone;(b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.

## Background
The present invention relates to the use of specific UV filter combinations comprising benzylidene malonates for cosmetic preparations.
It is well known that ultraviolet radiation (light) is harmful to human skin. Depending on the wavelength UV radiation causes different types of skin damage. UV-B radiation (about 290 to about 320 nm) is responsible for sunburn and can cause skin cancer. UV-A radiation (about 320 to about 400 nm) while producing tanning of the skin, contributes also to sunburn and the induction of skin cancers. Moreover, the harmful effects of the UV-B radiation may be aggravated by UV-A radiation.
Therefore, an effective sunscreen formulation preferably comprises both at least one UV-A and UV-B filter and a broad band UV filter covering the full range from about 290 nm to about 40 nm to prevent the human skin from the damage of sunlight.
Besides their screening power on solar radiation UV filters must also have good resistance to water and perspiration and also satisfactory photostability.
Unfortunately, many effective organic UV filters have a poor oil-solubility at a certain concentration and tend to crystallization. As a consequence the UV protection efficacy is significantly decreased.
It is known that there are lipophilic UV filters like Butyl Methoxydibenzoylmethane (sold under the tradename “Parsol 1789” by DSM) which have the particularity and also the disadvantage of being solid at ambient temperature. As a result, their use in sunscreen cosmetic compositions implies certain constraints in terms of their formulation and their use, in particular the selection of specific suitable cosmetic solvents that afford a proper solubility of these UV filters. Thus, a UV filter should show high solubility in common cosmetic oils or should be a good solvent for other UV filters that show poor oil solubility.
Moreover the oil soluble UV filters should be included in cosmetic sun care products without any impact on the sensorial characteristic of the emulsion. For that reason the optimal distribution of the UV absorber within the hydro-lipid film left on the skin after spreading should be guaranteed.
It is therefore an object of the present invention to find UV absorber formulations which have improved properties regarding the UV absorber.
Surprisingly it has been found that specific monomeric benzylidene malonates have very good properties as cosmetic UV-B absorbers.
Therefore, the present invention relates to the use of a UV filter combination, comprising

    (a) a first UV filter selected from benzylidene malonates of formula






wherein

    
    
        R1 methyl; ethyl; propyl; or n-butyl;
        if R1 is methyl, then
        R is tert. butyl;
    
    






    
    
         a radical of formula
    
    






    
    
         or a or a radical of formula
    
    






    
    
         wherein
        R2 and R3, independently from each other are hydrogen; or methyl;
        R4 is methyl; ethyl; or n-propyl;
        R5 and R6 independently from each other are hydrogen; or C1-C3alkyl;
        if R1 is ethyl; propyl; or n-butyl, then
        R is isopropyl; and
    
    
    (b) a second UV filter selected from
    
        (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
        (b2) Butyl Methoxydibenzoylmethane;
        (b3) Diethylhexyl Butamido Triazone;
        (b4) Ethylhexyl Triazone;
        (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate;
        (b6) Ethylhexyl Methoxycinnamate;
        (b7) Ethylhexyl Salicylate;
        (b8) Homosalate;
        (b9) Octocrylene;
        (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
        (b11) Phenylbenzimidazole Sulfonic Acid;
        (b12) Titanium Dioxide;
        (b13) micronized Tris-Biphenyl Triazine; and
        (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone;
        (b15) benzoic acid,4,4′-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]-propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; BBDAPT); CAS Regno. 207562-42-3 corresponding to the formula
    
    






wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b15); for the protection of human and animal hair and skin against UV radiation.

Prefereably, in formula (1)
R is a radical of formula




and

R1 is methyl.
Most preferred are compounds of formula (1), wherein in formula (1a) at least one of R2 or R3 is methyl.
Most preferred are also compounds of formula (1), wherein in formula (1a) R2 and R3 are methyl.
Preferred are also compounds, wherein

    
    
        R1 is ethyl; propyl; or n-butyl; and
        R is isopropyl.
    
    




Examples of compounds of formula (1) are listed in the Table 1 below:







TABLE 1







Examples of monomeric benzylidene malonates 


according to the present invention








 










R1
R












MBM-01
methyl






 


MBM-02
methyl






 


MBM-03
methyl






 


MBM-04
methyl






 


MBM-05
methyl






 


MBM-06
methyl






 


MBM-07
methyl






 


MBM-08
methyl






 


MBM-09
methyl






 


MBM-10
ethyl






 


MBM-11
propyl






 


MBM-12
n-butyl






 


MBM-13
methyl













Preferably the present UV filter combination comprises two of components (b1)-(b15).
Preferably the UV filter combinations comprise

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; and
    (c) a third UV-filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; and
    (c) a third UV-filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; and
    (c) a third UV-filter (b2) Butyl Methoxydibenzoylmethane.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b4) Ethylhexyl Triazone and/or (b15) benzoic acid,4,4′-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; and
    (c) a third UV-filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol or (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; and
    (c) a third UV-filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol or (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane.


Preferred are also UV filter combinations comprising three of components (b1)-(b15).
Preferred are UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
    (c) a third UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b4) Ethylhexyl Triazone.


Preferred are UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
    (c) a third UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
    (c) a third UV filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b4) Ethylhexyl Triazone.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
    (c) a third UV filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane.


Preferred are also UV filter combination comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate;
    (c) a third UV filter (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b4) Ethylhexyl Triazone.


Preferred are also UV filter combination comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate;
    (c) a third UV filter (b2) Butyl Methoxydibenzoylmethane; and
    (d) a fourth UV filter (b4) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane.


Preferred are also UV filter combinations comprising four or more than four of components (b1)-(b14).
Preferred are UV filter combination comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
    (c) a third filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenyl or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane;
    (d) a fourth filter (b4) Ethylhexyl Triazone; and
    (e) further filters (b7) Ethylhexyl Salicylate and/or (b13) micronized Tris-Biphenyl Triazine and/or (b9) Octocrylene and/or (b3) Diethylhexyl Butamido Triazone and/or (b11) Phenylbenzimidazole Sulfonic Acid and/or (b12) Titanium Dioxide and/or (b8) Homosalate and/or micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone and/or (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane;

and

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
    (c) a third filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenyl or (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane;
    (d) a fourth filter (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; and
    (e) further filters (b7) Ethylhexyl Salicylate and/or (b13) micronized Tris-Biphenyl Triazine and/or (b9) Octocrylene and/or (b3) Diethylhexyl Butamido Triazone and/or (b11) Phenylbenzimidazole Sulfonic Acid and/or (b12) Titanium Dioxide and/or (b8%) Homosalate and/or micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone.


Preferred are also UV filter combinations comprising

    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1;
    (b) a second UV filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
    (c) a third filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane;
    (d) a fourth filter (b4) Ethylhexyl Triazone and/or (b15) benzoic acid,4,4′-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; and
    (e) further filters (b7) Ethylhexyl Salicylate and/or (b13) micronized Tris-Biphenyl Triazine and/or (b9) Octocrylene and/or (b3) Diethylhexyl Butamido Triazone and/or (b11) Phenyl-benzimidazole Sulfonic Acid and/or (b12) Titanium Dioxide and/or (b8) Homosalate and/or micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone, and
    (a) a first UV filter selected from a benzylidene malonate of formula (1) as defined in claim 1,
    (b) a second UV filter (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
    (c) a third filter (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate or (b2) Butyl Methoxydibenzoylmethane;
    (d) a fourth filter (b15) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; and
    (e) further filters (b7) Ethylhexyl Salicylate and/or (b13) micronized Tris-Biphenyl Triazine and/or (b9) Octocrylene and/or (b3) Diethylhexyl Butamido Triazone and/or (b11) Phenylbenzimidazole Sulfonic Acid and/or (b12) Titanium Dioxide and/or (b8) Homosalate and/or micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone and/or BEMT (Tinosorb S, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) encapsulated in a polymer matrix, as described in IP.com Journal (2009), 9(1B), 17 (Tinosorb S aqua, BASF)


In Table 2 the preferred UV filter combinations according to the present invention are summarized:







TABLE 2







preferred UV filter combinations according to the present invention










UV filter




Compo-
UV filter



nent (a)
Component (b1)-(b15)













1
2
3
4
≧5

















Combi-
1
MBM
MBBT
BEMT




nation



DHHB


of 3 UV



BMBM


filters
2
MBM
BEMT
DHHB






BMBM



3
MBM
DHHB
BMBM



4
MBM
EHT
MBBT





BBDAPT
BEMT






DHHB






BMBM


Combi-
5
MBM
MBBT
BEMT
EHT


nation



DHHB
BBDAPT


of 4 UV



BMBM


filters
6
MBM
BEMT
DHHB
EHT






BMBM
BBDAPT



7
MBM
DHHB
BMBM
EHT







BBDAPT


Combi-
8
MBM
BEMT
MBBT
EHT
EHS


nation



DHHB

TBT


of ≧5 UV



BMBM

OCR


filters





DBT








PBSA








TiO2








HMS








DHHM








BBDAPT



9
MBM
MBBT
DHHB
EHT
EHS






BMBM
BBDAPT
TBT








OCR








DBT








PBSA








TiO2








HMS








DHHM



10
MBM
MBBT
DHHB
BBDAPT
EHS






BMBM

TBT








OCR








DBT








PBSA








TiO2








HMS








DHHM








BEMT*





MBM MONOMERIC Benzylidene Malonate


BEMT Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine


BMBM Butyl Methoxydibenzoylmethane


DBT Diethylhexyl Butamido Triazone


EHT Ethylhexyl Triazone


BBDAPT Bis(butylbenzoate) diaminotriazine aminopropylsiloxane


DHHB Diethylamino Hydroxy Benzoyl Hexyl Benzoate


EHS Ethylhexyl Salicylate


HMS Homosalate


OCR Octocrylene


MBBT Micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol


PBSA Phenylbenzimidazole Sulfonic Acid


TiO2 Titanium Dioxide


TBT Micronized Tris-Biphenyl Triazine


DHHM Micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone


BEMT* Tinosorb S, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) encapsulated in a polymer matrix, as described in IP.com Journal (2009), 9(1B), 17 (Tinosorb S aqua, BASF)






The present invention also refers to novel monomeric benzylidene compounds. These compounds correspond to formula




wherein

    R′1 methyl; ethyl; propyl; or n-butyl;
    if R′1 is methyl, then
    R′ is tert. butyl; or a radical of formula






or a radical of formula





wherein

    R′2 and R′3, independently from each other are hydrogen; or methyl;
    R′4 is methyl; ethyl; or n-propyl;
    if R′1 is ethyl; or propyl; then
    R′ is isopropyl.


Preferred are benzylidene malonates according of formula (1′), wherein R′1 is methyl.
Most preferred are benzylidene malonates according of formula (1′), wherein R′2 and R′3 are methyl.
Even more preferred are benzylidene malonates according of formula (1′), wherein R′ is a radical of formula




and

    R′1 is methyl.


Preferred are also benzylidene malonates of formula (1′), wherein

    R′1 is ethyl, ethyl; propyl; or n-butyl; and
    R′ is isopropyl.


The benzylidene malonates according to the present invention are prepared in a manner known per se according to the following reaction scheme:




The Knoevenagel condensation under conditions (a) is carried out under azeotropic removal of water in the presence of a catalyst (literature: Jones, Gurnos. Knoevenagel condensation. Organic Reactions (New York) 15, 204-599 (1967).
Solvents used in this step are for example benzene, toluene, o-xylene, m-xylene, p-xylene, chloroform, dichloromethane, ethanol, methanol, tetrahydrofurane, acetonitrile, ethyl acetate, CCl4, cyclohexane, n-hexane, n-pentane, or ionic liquids as for example 1-methyl-3-butyl imidazolium bromide. Mixtures of solvents can also be used.
The reaction temperature is preferably between 0° C. and the reflux temperature of the solvent mixture, preferably between 0° C. and 180° C., and more preferably between 20° and 150° C. The reaction time is preferably from 5 min to 72 h, and more preferably from 1 to 10 h.
The catalysts used in this reaction step are preferably primary, secondary or tertiary amines like piperidine, n-hexylamine, pyridine or triethylamine. The basic amines can be used as such or in combination with an acidic compound like acetic acid, benzoic acid or HCl. Suitable catalysts are any catalysts which are normally used in Knoevenagel reactions. Preferably are used catalysts such as a salt of an organic base with an organic acid, such as piperidinium acetate.
The Knoevenagel condensation under conditions (b) is carried out in the presence of a tetraalkyl orthotitanate Ti(OR′) (0.5 req. to 5 eq. with respect to the aldehyde) as described for example in K. Yamashita et al., Tetrahedron 2005, 61, 7981-7985. Solvents used in this step are alcohols R′OH, for example ethanol, methanol, isopropanol, n-propanol, n-butanol, 2-methyl-1-butanol, isobutanol, 2-butanol, 2-pentanol. Other suitable solvents are benzene, toluene, o-xylene, m-xylene, p-xylene, chloroform, dichloromethane, tetrahydrofurane, acetonitrile, ethyl acetate, CCl4, cyclohexane, n-hexane, n-pentane, or ionic liquids as for example 1-methyl-3-butyl imidazolium bromide. Mixtures of solvents can also be used. The reaction temperature is preferably between −10° C. and the reflux temperature of the solvent mixture, preferably between 0° C. and 180° C., and more preferably between 20° and 150° C.
The Knoevenagel condensation under conditions (c) is carried out in the presence of a titanium tetrachloride TiCl4 (0.5 req. to 5 eq. with respect to the aldehyde) as described for example in W. Lehnert, Tetrahedron Letters 1970, 54, 4723-4724 or in H. Chen et al., Eur. J. Org. Chem. 2006, 2329-2335. Solvents used in this step are ethers like tetrahydrofurane, dioxane, tert-butyl-methylether, diethyl ether, or alcohols R′OH, for example ethanol, methanol, isopropanol, n-propanol, n-butanol, 2-methyl-1-butanol, isobutanol, 2-butanol, 2-pentanol. Other suitable solvents are benzene, toluene, o-xylene, m-xylene, p-xylene, chloroform, dichloromethane, tetrahydrofurane, acetonitrile, ethyl acetate, CCl4, cyclohexane, n-hexane, n-pentane, or ionic liquids as for example 1-methyl-3-butyl imidazolium bromide. Mixtures of solvents can also be used.
The reaction temperature is preferably between −10° C. and the reflux temperature of the solvent mixture, preferably between 0° C. and 180° C., and more preferably between 20° and 150° C.
The UV filter combination according to the present invention is especially useful for the protection of organic materials that are sensitive to ultraviolet light, especially human and animal skin and hair, against the action of UV radiation. Such UV filter combinations are accordingly suitable as light-protective agents in cosmetic, pharmaceutical and veterinary medicine preparations. Such compounds are preferably used in the dissolved state.
The invention accordingly relates also to a cosmetic preparation comprising the UV filter combination according to the present invention and cosmetically tolerable carriers or adjuvants.
The cosmetic preparation may also comprise, in addition to the UV absorber combination according to the invention, one or more further UV protective agents of the following substance classes:

    p-aminobenzoic acid derivatives, benzophenone derivatives, 3-imidazol-4-yl acrylic acid and esters; benzofuran derivatives, polymeric UV absorbers, cinnamic acid derivatives, camphor derivatives, menthyl o-aminobenzoate; merocyanine derivatives; or encapsulated UV absorbers.


The UV absorbers described in “Sunscreens”, Eds. N.J. Lowe, N. A. Shaath, Marcel Dekker, Inc., New York and Basle or in Cosmetics & Toiletries (107), 50ff (1992) also can be used as additional UV protective substances.
Special preference is given to the light-protective agents indicated in the following Table 2:







TABLE 3







Suitable UV filter substances and adjuvants which can be additionally used with


the UV absorbers of formula MBM-01-MBM-12 according to the present invention









No.
Chemical Name
CAS No.












1
(+/−)-1,7,7-trimethyl-3-[(4-methylphenyl)methylene]bicyclo-
36861-47-9



[2.2.1]heptan-2-one; p-methyl benzylidene camphor


2
1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one;
15087-24-8



benzylidene camphor


3
(2-Hydroxy-4-methoxyphenyl)(4-methylphenyl)methanone
1641-17-4


4
2,4-dihydroxybenzophenone
131-56-6


5
2,2′,4,4′-tetrahydroxybenzophenone
131-55-5


6
2-Hydroxy-4-methoxy benzophenone;
131-57-7


7
2-Hydroxy-4-methoxy benzophenone-5-sulfonic acid
4065-45-6


8
2,2′-dihydroxy-4,4′-dimethoxybenzophenone
131-54-4


9
2,2′-Dihydroxy-4-methoxybenzophenone
131-53-3


10
Alpha-(2-oxoborn-3-ylidene)toluene-4-sulphonic acid and its salts
56039-58-8



(Mexoryl SL)


12
Methyl N,N,N-trimethyl-4-[(4,7,7-trimethyl-3-oxobicyclo[2,2,1]hept-2-
52793-97-2



ylidene)methyl]anilinium sulphate (Mexoryl SO)


13
Isopentyl p-methoxycinnamate; isoamyl methoxy cinnamate
71617-10-2


14
2-ethylhexyl 4-(dimethylamino)benzoate
21245-02-3


15
2-ethylhexyl 4-methoxycinnamate; Octyl Methoxy Cinnamate
5466-77-3


16
4-aminobenzoic acid
150-13-0


17
Benzoic acid, 4-amino-, ethyl ester, polymer with oxirane
113010-52-9


18
2-Propenamide, N-[[4-[(4,7,7-trimethyl-3-oxobicyclo[2.2.1]hept-2-
147897-12-9



ylidene)methyl]phenyl]methyl]-, homopolymer


19
Triethanolamine salicylate
2174-16-5


20
3,3′-(1,4-phenylenedimethylene)bis[7,7-dimethyl-2-oxo-
90457-82-2



bicyclo[2.2.1]heptane-1 methanesulfonic acid] (Cibafast H)


21
Benzoic acid, 4,4′-[[6-[[4-[[(1,1-dimethylethyl)amino]carbonyl]-
154702-15-5



phenyl]amino]1,3,5-triazine-2,4-diyl]diimino]bis-, bis(2-ethylhexyl)-



ester; diethylhexyl butamido triazone (Uvasorb HEB)


22
Phenol, 2-(2H-benzotriazol-2-yl)-4-methyl-6-[2-methyl-3-[1,3,3,3-
155633-54-8



tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propyl]-; drometrizole



trisiloxane (Mexoryl XL)


23
Dimethicodiethylbenzalmalonate; Polysilicone 15 (Parsol SLX)
207574-74-1


24
Benzenesulfonic acid, 3-(2H-benzotriazol-2-yl)-4-hydroxy-5-(1-
92484-48-5



methylpropyl)-, monosodium salt (Tinogard HS)


25
1-Dodecanaminium, N-[3-[[4-(dimethylamino)benzoyl]amino]propyl]-
156679-41-3



N,N-dimethyl-, salt with 4-methylbenzenesulfonic acid (1:1) (Escalol



HP610)


26
1-Propanaminium, N,N,N-trimethyl-3-[(1-oxo-3-phenyl-2-propenyl)-
177190-98-6



amino]-, chloride


27
1H-Benzimidazole-4,6-disulfonic acid, 2,2′-(1,4-phenylene)bis-
170864-82-1


28
1-Propanaminium, 3-[[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethyl-
340964-15-0



ethyl)-4-hydroxyphenyl]-1-oxopropyl]amino]-N,N-diethyl-N-methyl-,



methyl sulfate (salt)


29
2-Propenoic acid, 3-(1H-imidazol-4-yl)-
104-98-3


30
Benzoic acid, 2-hydroxy-, [4-(1-methylethyl)phenyl]methyl ester
94134-93-7


31
1,2,3-Propanetriol, 1-(4-aminobenzoate) (Glyceryl PABA)
136-44-7


32
Benzeneacetic acid, 3,4-dimethoxy-a-oxo-
4732-70-1


33
2-Propenoic acid, 2-cyano-3,3-diphenyl-, ethyl ester
5232-99-5


34
Anthralinic acid, p-menth-3-yl ester
134-09-8


35
sterols (cholesterol, lanosterol, phytosterols), as described in



WO0341675


36
mycosporines and/or mycosporine-like amino acids as described in



WO2002039974, e.g. Helioguard 365 from Milbelle AG, isolated



mycosporine like amino acids from the red alga porphyra umbilicalis



(INCI: Porphyra Umbilicalis) that are encapsulated into liposomes)


37
alpha-lipoic-acid as described in DE 10229995


38
synthetic organic polymers as described in EP 1 371 358,



[0033]-[0041]


39
phyllosilicates as described in EP 1371357 [0034]-[0037]


40
silica compounds as described in EP1371356, [0033]-[0041]


41
inorganic particles as described in DE10138496 [0043]-[0055]


42
latex particles as described in DE10138496 [0027]-[0040]


43
1H-Benzimidazole-4,6-disulfonic acid, 2,2′-(1,4-phenylene)bis-,
180898-37-7



disodium salt; Bisimidazylate (Neo Heliopan APC)


44
Di-2-ethylhexyl-3,5-dimethoxy-4-hydroxy-benzalmalonate (Oxynex



ST, EMD Chemicals, as described in US 20040247536)


45
T-LiteTM MAX: Titanium Dioxide (and) Dimethoxydiphenylsilane



(and) Triethoxycaprylylsilane Crosspolymer (and) Hydrated Silica



(and) Aluminum Hydroxyde


46
T-Lite SF: Titanium Dioxide (and) Aluminum Hydroxide (and)



Dimethicone/Methicone Copolymer


47
T-Lite SF-S: Titanium Dioxide (and) Hydrated Silica (and)



Dimethicone/Methicone Copolymer (and) Aluminum Hydroxide


48
Z-COTE ® MAX: Zinc Oxide (and) Diphenyl Capryl Methicone


49
Z-COTE HP1: Zinc Oxide (and) Triethoxycaprylylsilane


50
1,1-[(2,2′-Dimethylpropoxy)carbonyl]-4,4-diphenyl-1,3-butadiene
363602-15-7


51
UV filter capsules containing an organic sunscreen as described in



DE102007035567 or WO 2009012871









In addition, BEMT (Tinosorb S, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) encapsulated in a polymer matrix, for example in PMMA, as described in IP.com Journal (2009), 9(1B), 17, can also be used as additional UV protective substance.
The following compounds can also be used as additional UV protective substances:
Merocyanine derivatives as described in WO 2004/006878:




(A) and (B) can be either in E- or Z-configuration.
Each of the above-mentioned light-protective agents, especially the light-protective agents in the above Tables indicated as being preferred, can be used in admixture with the UV absorber combination according to the invention. It will be understood in that connection that, in addition to the UV absorber combination according to the invention, it is also possible for more than one of the additional light-protective agents to be used, for example, two, three, four, five or six further light-protective agents. Preference is given to the use of mixing ratios of UV absorbers according to the invention/further light-protective agents of from 1:99 to 99:1, especially from 1:95 to 95:1 and preferably from 10:90 to 90:10, based on weight. Of special interest are mixing ratios of from 20:80 to 80:20, especially from 40:60 to 60:40 and preferably of approximately 50:50. Such mixtures can be used, inter alia, to improve solubility or to increase UV absorption.
Appropriate mixtures can be used especially advantageously in a cosmetic composition according to the invention.
The cosmetic compositions contain, for example, from 0.1 to 30% by weight, preferably from 0.1 to 15% by weight and especially from 0.5 to 10% by weight, based on the total weight of the composition, of the UV absorber composition according to the present invention and at least one cosmetically tolerable adjuvant.
The cosmetic compositions can be prepared by physically mixing the UV absorbers with the adjuvant using customary methods, for example by simply stirring together the individual components, especially by making use of the dissolution properties of already known cosmetic UV absorbers, for example OMC, salicylic acid isooctyl ester, inter alia. The UV absorber can be used, for example, without further treatment.
The cosmetic compositions may be, for example, creams, gels, lotions, alcoholic and aqueous/alcoholic solutions, emulsions, wax/fat compositions, stick preparations, powders or ointments.
The compositions according to the invention, for example creams, gels, lotions, alcoholic and aqueous/alcoholic solutions, emulsions, wax/fat compositions, stick preparations, powders or ointments, may in addition contain, as further adjuvants and additives, mild surfactants, super-fatting agents, pearlescent waxes, consistency regulators, thickeners, polymers, silicone compounds, fats, waxes, stabilisers, biogenic active ingredients, deodorising active ingredients, anti-dandruff agents, film formers, swelling agents, further UV light-protective factors, antioxidants, hydrotropic agents, preservatives, insect repellents, self-tanning agents, solubilisers, perfume oils, colourants, bacteria-inhibiting agents and the like.
Cosmetic formulations according to the invention are contained in a wide variety of cosmetic preparations. There come into consideration, for example, especially the following preparations: skin-care preparations, bath preparations, skin-care preparations, cosmetic personal care preparations, foot-care preparations, light-protective preparations, skin-tanning preparations, depigmenting preparations, insect-repellents, deodorants, antiperspirants, preparations for cleansing and caring for blemished skin, hair-removal preparations in chemical form (depilation), shaving preparations, fragrance preparations, cosmetic hair-treatment preparations.
The final formulations listed may exist in a wide variety of presentation forms, for example:

    
    
        in the form of liquid preparations as a W/O, O/W, O/W/O, W/O/W or PIT emulsion and all kinds of microemulsions,
        in the form of a gel,
        in the form of an oil, a cream, milk or lotion,
        in the form of a powder, a lacquer, a tablet or make-up,
        in the form of a stick,
        in the form of a spray (spray with propellent gas or pump-action spray) or an aerosol,
        in the form of a foam, or
        in the form of a paste.
    
    


Of special importance as cosmetic compositions for the skin are light-protective preparations, such as sun milks, lotions, creams, oils, sunblocks or tropicals, pretanning preparations or after-sun preparations, also skin-tanning preparations, for example self-tanning creams. Of particular interest are sun protection creams, sun protection lotions, sun protection oils, sun protection milk and sun protection preparations in the form of a spray.
Of special importance as cosmetic compositions for the hair are the above-mentioned preparations for hair treatment, especially hair-washing preparations in the form of shampoos, hair conditioners, hair-care preparations, e.g. pretreatment preparations, hair tonics, styling creams, styling gels, pomades, hair rinses, treatment packs, intensive hair treatments, hair-straightening preparations, liquid hair-setting preparations, hair foams and hairsprays. Of special interest are hair-washing preparations in the form of shampoos.
The cosmetic preparation according to the invention contains from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, based on the total weight of the composition, of a UV absorber of formula (1) or of a mixture of UV absorbers and a cosmetically tolerable adjuvant.
The cosmetic preparation can be prepared by physically mixing the UV absorber or UV absorbers with the adjuvant using conventional methods, for example by simply stirring the individual components together.
The cosmetic preparation according to the invention can be formulated as a water-in-oil or oil-in-water emulsion, as an oil-in-alcohol lotion, as a vesicular dispersion of an ionic or non-ionic amphiphilic lipid, as a gel, solid stick or as an aerosol formulation.
As a water-in-oil or oil-in-water emulsion, the cosmetically tolerable adjuvant preferably contains from 5 to 50% of an oil phase, from 5 to 20% of an emulsifier and from 30 to 90% water. The oil phase can comprise any oil suitable for cosmetic formulations, for example one or more hydrocarbon oils, a wax, a natural oil, a silicone oil, a fatty acid ester or a fatty alcohol. Preferred mono- or poly-ols are ethanol, isopropanol, propylene glycol, hexylene glycol, glycerol and sorbitol.
For the cosmetic preparation according to the invention it is possible to use any conventionally usable emulsifier, for example one or more ethoxylated esters of natural derivatives, for example polyethoxylated esters of hydrogenated castor oil, or a silicone oil emulsifier, for example silicone polyol; an unethoxylated or ethoxylated fatty acid soap; an ethoxylated fatty alcohol; an unethoxylated or ethoxylated sorbitan ester; an ethoxylated fatty acid; or an ethoxylated glyceride.
The cosmetic preparation according to the invention is distinguished by excellent protection of human skin against the damaging effect of sunlight.
In the following Examples percentages relate to weight. The amounts of the benzylidene malonates compounds used relate to the pure substance.
Method for SPF Measurement
Method to Assess In Vitro Sun Protection Factor Measurement (SPF)


    End-product application rate 1.4 mg/cm2 on PMMA plates (Helioplates®)
    UV Transmittance analysis with Labsphere UV-1000S Transmittance Analyser






  
    S
    ⁢
    
      
    
    ⁢
    P
    ⁢
    
      
    
    ⁢
    F
  
  =
  
    
      
        ∫
        
          290
          ⁢
          
            
          
          ⁢
          nm
        
        
          400
          ⁢
          
            
          
          ⁢
          nm
        
      
      ⁢
      
        
          
            E
            λ
          
          ·
          
            S
            λ
          
          ·
          d
        
        ⁢
        
          
        
        ⁢
        λ
      
    
    
      
        ∫
        
          290
          ⁢
          
            
          
          ⁢
          nm
        
        
          400
          ⁢
          
            
          
          ⁢
          nm
        
      
      ⁢
      
        
          
            E
            λ
          
          ·
          
            S
            λ
          
          ·
          
            T
            λ
          
          ·
          d
        
        ⁢
        
          
        
        ⁢
        λ
      
    
  




wherein Eλ=erythema action spectrum; Sλ=solar spectral irradiance and Tλ=spectral transmittance of the sample.

Method to Assess In Vitro UVA Protection Factor (UVA PF)

    End-product application rate 1.2 mg/cm2 on PMMA plates (Helioplates®)
    UV Transmittance analysis with Labsphere UV-1000S Transmittance Analyser
    Pre-irradiation step (to take the sun care product photostability into account) via a solar simulator such as Atlas Suntest CPS+






  PFUVA
  =
  
    
      
        
          ∑
          320
          400
        
        ⁢
        Δλ
      
      
        
          ∑
          320
          400
        
        ⁢
        
          
            T
            λ
          
          ·
          Δλ
        
      
    
    =
    
      1
      
        T
        m
      
    
  




Wherein Tλ, =sunscreen product transmittance at wave length λ and Tm=mean arithmetical value of Transmittance data in the UVA range.

    
    
        particulate organic filter 50-200 nm, aqueous dispersion, active ingredient
        particulate organic filter 50-200 nm, encapsulated active ingredient
        particulate inorganic filter 10-200 nm, active ingredient
    
    












Example 1: O/W FORMULATION—Anionic System emulsifier
















Emulsion high Protection
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Cyclomethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Ethylhexyl Palmitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Glyceryl Stearate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Potassium Cetyl Phosphate
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80



VP/Eicosene Copolymer
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Acrylates/Palmeth-25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



Acrylate Copolymer



Glycerin
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00



Disodium EDTA
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20


Part C
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben



Tocopheryl Acetate
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according
25.5
20.3
16.3
23.5
19.2
33
28.6
22.2
31.6



the method described



UVA PF measured according
10.7
10.6
6
15.3
8.8
10.8
10.6
6
15.6



the method described



















Example 2: Sun Milk



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
C12-15 Alkyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Isohexadecane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Cyclopentasiloxane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Stearic Acid
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



PEG-100 Stearate (and)
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Glyceryl Stearate



Potassium Cetyl Phosphate
1.30
1.30
1.30
1.30
1.30
1.30
1.30
1.30
1.30



PVP/Eicosene Copolymer
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Propylene Glycol
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Xanthan Gum
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Acrylates/C10-30 Alkyl
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Acrylate Crosspolymer



Disodium EDTA
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15


Part C
Triethanolamine
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs



Dimethicone
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40



Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben



Tocopheryl Acetate
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 3: Every Day Lotion



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Stearyl Phosphate
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Triisodecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Tricontanyl PVP
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Ethoxydiglycol Oleate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Squalane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



C12-15 Alkyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Glyceryl Stearate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Cetyl Alcohol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Steareth-10 Allyl
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Ether/Acrylates Copolymer



Glycerin
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Diazolidinyl Urea (and)
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Iodopropynyl



Butylcarbamate



Sodium Lauroyl Glutamate
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70


Part C
Cyclopentasiloxane (and)
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Dimethiconol



Triethanolamine
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85



Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate



Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Ethylhexyl
7.00







5.00



Methoxycinnamate



Bis-Ethylhexyloxyphenol

2.00





2.00



Methoxyphenyl Triazine **



Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described



UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 4: Every Day Lotion—Nonionic System emulsifier—O/W FORMULATION
















Sun Cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Tribehenin PEG-20 esters
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dibutyl adipate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



PPG-2 Myristyl Ether
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Propionate


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



PVP/dimethylconylacrylate/
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



polycarbamyl/polyglycol ester



Disodium EDTA
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Sclerotium Gum
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ammonium Acryldimethyltaurate/
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Beneth-25 Methacrylate



Crosspolymer.


Part C
Cyclopentasiloxane (and)
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



cyclohexasiloxane



Phenoxyethanol (and)
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben



Sodium Hydroxide (and) Aqua
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy Benzoyl

4.00

4.00

4.00
4.00

4.00



Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00



Methanone, 1,1′-(1,4-piperazine-







2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Zinc Oxide
4.00



Isoamyl p-Methoxycinnamate

3.00



Polysilicone-15


5.00



Disodium Phenyl



2.00



Dibenzylmidazole Tetrasulfonate



Benzophenone-3




3.00



Terephthalylidene Dicamphor





1.00
1.00
1.00
1.00



Sulfonic Acid



Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described



UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 5: Every Day Lotion—Nonionic System emulsifier—O/W FORMULATION
















UV-A/UV-B Daily Care UV Protection Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Oleth-3 Phosphate
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Steareth-21
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Steareth-2
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cetyl Alcohol
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Stearyl Alcohol
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Tribehenin
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Isohexadecane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Glycerin
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Disodium EDTA
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part C
Aqua
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00



Diazolidinyl Urea (and)
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



iodopropynyl Butyl-



carbamate



Propylene Glycol
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00


Part D
Sodium Acrylates Co-
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



polymer (and)



Paraffinium Liquidum (and)



PPG-1 Trideceth-6



Cyclopentasiloxane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



PEG-12 Dimethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tocopheryl Acetate
0.45
0.45
0.45
0.45
0.45
0.45
0.45
0.45
0.45



Water (and) Citric Acid
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs



Fragrance
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylpheno *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according
25.5
20.3
16.3
23.5
19.2
33
28.6
22.2
31.6



the method described



UVA PF measured according
10.7
10.6
6
15.3
8.8
10.8
10.6
6
15.6



the method described



















Example 6: Daily Care Lotion



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Polyglyceryl Methyl
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Glucose Distearate



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cetearyl Alcohol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Octyl Stearate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Caprylic/Capric
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Triglyceride



Isohexadecane
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00


Part B
Aqua
64.80
64.80
64.80
64.80
64.80
64.80
64.80
64.80
64.80



Glycerin
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00


Part C
Phenoxyethanol (and)
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Methylparaben (and)



Butylparaben (and)



Ethylparaben (and)



Propylparaben



Cyclomethicone (and)
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethicone



Steareth-10 Allyl
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Ether/Acrylates



Copolymer


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 7: O/W FORMULATION—Sunscreen Gel



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Alcohol Denatured
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Hydroxypropyl Cellulose
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Acrylates/Octylacrylamide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Copolymer



C12-15 Alkyl Benzoate
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



Cyclotetrasiloxane (and)
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Cyclopentasiloxane



PEG/PPG-4/12
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Ethylhexyl
7.00







5.00



Methoxycinnamate



Bis-Ethylhexyloxyphenol

2.00





2.00



Methoxyphenyl Triazine **



Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described



UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 8: Gel Cream
















Gel Cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Acrylate/C10-30 Alkyl-
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40



acrylate Crosspolymer



Polyacrylic Acid
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Xanthan Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Cetearyl alcohol
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



C12-15 Alkylbenzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Caprylic/Capric
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Triglyceride



Dimethicone
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Dimethiconol
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Sodium Hydroxyde
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Preservative
.q.s. 
.q.s. 
.q.s. 
.q.s. 
.q.s. 
.q.s. 
.q.s. 
.q.s. 
.q.s. 



Parfum
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Aqua
ad 100.0
ad 100.0
ad 100.0
ad 100.0
ad 100.0
ad 100.0
ad 100.0
ad 100.0
ad 100.0



PH-value adjusted to 6.0


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00

4.00
4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00



Methanone, 1,1′-(1,4-piperazine-







2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Zinc Oxide
4.00



Isoamyl p-Methoxycinnamate

3.00



Polysilicone-15


5.00



Disodium Phenyl



2.00



Dibenzylmidazole



Tetrasulfonate



Benzophenone-3




3.00



Terephthalylidene Di-





1.00
1.00
1.00
1.00



camphor Sulfonic Acid



Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described



UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 9: O/W FORMULATION—Emulsifier free



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Acrylates/C10-30 Alkyl
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40



Acrylate Crosspolymer



Xanthan Gum
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Ethylhexyloxyglycerine
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Butylene Glycol
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



Glycinc Soja
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Tocopheryl Acetate
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



PETP
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Trisodium EDTA
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Ethanol
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50



Parfume
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Watersoluble Dyes
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02



Aqua
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according
25.5
20.3
16.3
23.5
19.2
33
28.6
22.2
31.6



the method described



UVA PF measured according
10.7
10.6
6
15.3
8.8
10.8
10.6
6
15.6



the method described



















Example 10: SPRAY FORMULATION—Classic
















Sprayable Sunscreen Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Potassium Cetyl
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Phosphate



Isohexadecane
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



VP/Eicosene Copolymer
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Di-C12-13 Alkyl Tartrate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



C12-15 Alkyl Benzoate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Sorbeth-30
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Sorbitan Stearate (and)
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Sucrose Cocoate



Aqua
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00


Part C
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben


Part D
Water (and) Citric Acid
qs
qs
qs
qs
qs
qs
qs
qs
qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 11: COLD PROCESS SPRAY
















COLD PROCESS SPRAY
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Sorbitan-30
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00


Part B
Isostearyl Alcohol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Sorbitan Oleate (and)
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Polyglycerol 3-Poly-



ricinoleate



Polysorbate-20
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00


Part C
DMDM Hydantoin
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Aqua
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100



Hydroxypropyl Starch
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Phosphate



Acrylates Copolymer
3.35
3.35
3.35
3.35
3.35
3.35
3.35
3.35
3.35



Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate



Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Ethylhexyl
7.00







5.00



Methoxycinnamate



Bis-Ethylhexyloxyphenol

2.00





2.00



Methoxyphenyl Triazine **



Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described



UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 12: SPRAY FORMULATION—Foaming
















Sun spray foaming
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Behenyl Alcohol (and)
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Glyceryl Stearate (and)



Glyceryl Stearate



Citrate (and) Disodium



Ethylene Di(Cocamide



PEG-15 Disulfate)



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Isotrideceth-12
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Ethylhexyl Salicylate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Hydrogenated Coco-
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



glycerides



C12-15 Alkyl Benzoate
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00


Part B
Aqua
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Glycerin
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Galactoarabinan
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25


Part C
Disodium Ethylene Di-
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



(Cocamide PEG-15 Di-



sulfate) (and) Sodium



Lauroyl Lactylate



Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100


Part D
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben



Tocopheryl Acetate
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00

4.00
4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00



Methanone, 1,1′-(1,4-piperazine-







2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Zinc Oxide
4.00



Isoamyl p-Methoxycinnamate

3.00



Polysilicone-15


5.00



Disodium Phenyl



2.00



Dibenzylmidazole



Tetrasulfonate



Benzophenone-3




3.00



Terephthalylidene Di-





1.00
1.00
1.00
1.00



camphor Sulfonic Acid



Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described



UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 13: SPRAY FORMULATION—Foaming
















Foameous O/W Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Stearic Acid
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Cetearyl Alcohol
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



PEG-30-Stearate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Aluminium Starch
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Octenylisuccinate



Talc
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Polyurethane
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Magnese silicate
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



PEG-180/Octoxynol-
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



40/TMMG Copolymer



Cyclomethicone
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Dimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenyl Trimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone/Vinyl
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone Crosspolymer



Cetyl Palmitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cera Microcristallina
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Hydrated Polyisobutene
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Citric Acid
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



glycerin
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Parfume, Preservatives
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Sodium Hydroxide
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Dyes etc.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Aqua
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100



pH-value adjusted to 6.0-7.5



Propellent
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according
25.5
20.3
16.3
23.5
19.2
33
28.6
22.2
31.6



the method described



UVA PF measured according
10.7
10.6
6
15.3
8.8
10.8
10.6
6
15.6



the method described



















Example 14: SPRAY FORMULATION—Continuous
















Continuous Spray sport sunscreen
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















SD-Alcohol 40
63.0
63.0
63.0
63.0
63.0
63.0
63.0
63.0
63.0



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Acrylates/Octylacryl-
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



amide Copolymer



Parfume
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Propellent
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 15: W/O FORMULATION
















EG-free sunscreen
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Hexyldecanol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Polyglyceryl-3 Methyl-
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40



glucose Distearate



Phenethyl Benzoate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Polyglyceryl-10 poly-
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40



hydroxy stearate



Cetyl Ethylhexanoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Isohexadecane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Phenoxyethanol (and)
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Methylparaben (and) Ethyl-



paraben (and) Butylparaben



(and) Propylparaben (and)



Isobutylparaben


Part B
Aqua
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00


Part C
Sodium Acrylates Co-
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



polymer (and) Mineral Oil



(and) PPG-1 Trideceth-6



Cyclopentasiloxane
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Ethylhexyl
7.00







5.00



Methoxycinnamate



Bis-Ethylhexyloxyphenol

2.00





2.00



Methoxyphenyl Triazine **



Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described



UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 16: Water resistant W/O emulsion



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Polyglyceryl-10 Penta-
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



stearate (and) Behenyl Alcohol



(and) Sodium Stearoyl



Lactylate



VP/Eicosene Copolymer
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Phenethyl Benzoate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tridecyl Trimellitate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Stearyl Alcohol
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Squalane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



C12-15 Alkyl Benzoate
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100


Part C
Glycerin
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80



Steareth-10 Allyl Ether/
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Acrylates Copolymer



Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate



Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part D
VP/Hexadecene Copolymer
2.70
2.70
2.70
2.70
2.70
2.70
2.70
2.70
2.70



Cyclomethicone
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50


PartE
Aqua (and) Tocopheryl
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50



Acetate (and) Caprylic/Capric



Triglyceride (and) Poly-



sorbate 80 (and) Lecithin



Fragrance
qs
qs
qs
qs
qs
qs
qs
qs
qs



Water (and) Sodium
qs
qs
qs
qs
qs
qs
qs
qs
qs



Hydroxide


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00

4.00
4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00



Methanone, 1,1′-(1,4-piperazine-







2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Zinc Oxide
4.00



Isoamyl p-Methoxycinnamate

3.00



Polysilicone-15


5.00



Disodium Phenyl



2.00



Dibenzylmidazole Tetrasulfonate



Benzophenone-3




3.00



Terephthalylidene





1.00
1.00
1.00
1.00



Dicamphor Sulfonic Acid



Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described



UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 17: Skin Protection Sunscreen W/O



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Glyceryl Oleate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



PEG-7 Hydrogenated
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Castor Oil



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Hydrogenated Castor Oil
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Microcrystalline Wax
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Beeswax
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



C12-15 Alkyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Isopropyl Isostearate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Mineral Oil
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Magnesium Sulfate
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50


Part C
Citric Acid
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05



Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate



Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according



the method described



UVA PF measured according



the method described



















Example 18: W/Si FORMULATION
















W/Si Sun Cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Bis-PEG/PPG-14/14
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethicone (and)



Cyclopentasiloxane



Phenethyl Benzoate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Cetyl PEG/PPG-10/1
1.70
1.70
1.70
1.70
1.70
1.70
1.70
1.70
1.70



Dimethicone



Cyclopentasiloxane (and)
13.00
13.00
13.00
13.00
13.00
13.00
13.00
13.00
13.00



Cyclohexasiloxane



Ethylhexyl Palmitate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Cetyl Dimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Ethylhexyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



methoxycinnamate


Part B
Propylene Glycol
27.00
27.00
27.00
27.00
27.00
27.00
27.00
27.00
27.00



Magnesium Sulfate
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Heptahydrate



Glycerin
26.00
26.00
26.00
26.00
26.00
26.00
26.00
26.00
26.00



Alcohol Denatured
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 19: W/Si FORMULATION
















W/Si emulsion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Part A
Tetrabutoxypropyl
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90



Trisiloxane



Benzyl Laurate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tridecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Cetyl dimethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Polyglyceryl-4, isostearate,
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00



cetyl dimethicone copolyol



and hexyl laurate



polyglyceryl-3 dioleate
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Glyceryl tribehenate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



cyclomethicone
8.85
8.85
8.85
8.85
8.85
8.85
8.85
8.85
8.85


Part B
Aqua
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100



Xanthan gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Disodium EDTA
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Sodium chloride
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00


Part C
Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate



Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



panthenol
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Sodium ascorbyl
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



phosphate



tocopheryl acetate
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Phytantriol
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30



Fragrance/preservative
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Ethylhexyl
7.00







5.00



Methoxycinnamate



Bis-Ethylhexyloxyphenol

2.00





2.00



Methoxyphenyl Triazine **



Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described



UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 20: Lipstick FORMULATION
















Lipstick Composition
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Phenethyl Benzoate
4.00
3.00
2.00
1.00
4.00
4.00
4.00
3.00
5.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
0.50
1.00
2.00
0.50
0.50



Isoeicosane
8.00

13.00



Isododecane







15.00
15.00



polyisobutene
5.00

10.00



polybutene

15.00



Tridecyl Trimellitate
15.00
15.00
15.00



Diisostearate Dimerate







15.00
15.00



Octyl palmitate
15.00

12.00



Caprylic/Capric




16.00
20.00



Triglycerides



PEG-4 Diheptanoate
6.00



Polyglyceryl-3







3.00
3.00



Diisostearate



Castor (Ricinus communis)
10.00



oil (and) colorants



Castor (Ricinus communis)


4.00
60.00
22.00
35.00



oil



Trihydroxystearin

1.00



Ozokerite




4.50
1.50



Octyldodecanol (and)

12.00



Quaternium-18 Hectorite (and)



Propylene carbonate



Synthetic wax







9.40
9.40



Microcrystalline wax




2.00



Bees wax
12.00

7.00



25.00



Candellila wax
5.50

7.00
15.00
7.00
8.00



Carnauba wax
10.00

8.00
5.00
3.00
3.50



Cera Alba

5.00



Ceresine wax

5.00



5.00



Tribehenin

12.00



Octyldodecanol

12.00
10.00

17.00

55.00



polyethylene
1.50



Calcium Aluminum Boro-


1.00



silicate



Cetearyl Alcohol

10.00



Paraffin







7.60
7.60



Acetylated Lanolin Alcohol



5.00
5.00
10.00



Pigments/pearls







13.00
13.00



Colorants



12.00
13.00
13.00
9.50



Tocopherol Acetate

0.40
0.30




0.20
0.20



Preservative

0.10
0.30




0.10
0.10


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00

4.00
4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00



Methanone, 1,1′-(1,4-piperazine-







2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



Zinc Oxide
4.00



Isoamyl p-Methoxycinnamate

3.00



Polysilicone-15


5.00



Disodium Phenyl



2.00



Dibenzylmidazole Tetrasulfonate



Benzophenone-3




3.00



Terephthalylidene





1.00
1.00
1.00
1.00



Dicamphor Sulfonic Acid



Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described



UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 21: Oleogel FORMULATION
















SUNSCREEN Oleogel
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Mineral Oil
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Polyethylene
9.75
9.75
9.75
9.75
9.75
9.75
9.75
9.75
9.75



C12-15 Alkyl Benzoate
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



Isopropyl Palmitate
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00
9.00



Petrolatum
5.25
5.25
5.25
5.25
5.25
5.25
5.25
5.25
5.25



Aleurites Moluccana
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Seed Oil



Cetearyl Alcohol (and)
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Ceteareth-20



Macadamia Ternifolia
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Seed Oil



Arachis Hypogaea
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



(Peanut) Oil



Dimethicone
0.95
0.95
0.95
0.95
0.95
0.95
0.95
0.95
0.95



BHT
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05



Fragrance
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-


3.00

3.00


3.00



methane



Ethylhexyl Triazone





2.00
2.00
2.00
2.00



In vitro SPF measured according
25.5
20.3
16.3
23.5
19.2
33
28.6
22.2
31.6



the method described



UVA PF measured according
10.7
10.6
6
15.3
8.8
10.8
10.6
6
15.6



the method described



















Example 22: Make-up FORMULATION
















Foundations; O/W forms
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w






















Butylene Glycol
6.50
6.50
6.50
6.50
6.50
6.50
6.50
6.50
6.50



Magnesium Aluminum
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Silicate



Sodium Carboxymethyl-
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30



cellulose



Xanthan Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Triethanolamine
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Polysorbate 20
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



Sericite
7.00
7.00
7.00
7.00
7.00
7.00
7.00
7.00
7.00



Iron oxides
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10



Spherical Silica
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cetearyl octanoate
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



Stearic Acid
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Glyceryl stearate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tridecyl trimellilate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Aqua
qsp
qsp
qsp
qsp
qsp
qsp
qsp
qsp
qsp



Preservative
0.55
0.55
0.55
0.55
0.55
0.55
0.55
0.55
0.55


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM



6 or MBM 7 or MBM 8 or



MBM 9 or MBM 10 or MBM



11 or MBM 12 or MBM 13



Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine



Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00



Tetramethylbutylphenol *



Diethylamino Hydroxy


4.00

4.00


4.00



Benzoyl Hexyl Benzoate



Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane



Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ethylhexyl Salicylate

5.00



Tris-Biphenyl Triazine *


2.00



Octocrylene



8.00



Diethylhexyl Butamido




1.00



Triazone



Phenylbenzimidazole





2.00



Sulfonic Acid



Titanium Dioxide ***






2.00



Homosalate







10.00



Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-



2-hydroxybenzoyl]phenyl]-



CAS number (919803-06-8) *



In vitro SPF measured according
25.4
35.7
38.1
33.5
36.3
31.7
38.5
34.8
25



the method described



UVA PF measured according
8.9
10.8
14.6
7.8
15.6
8.9
11.6
10.7
7.6



the method described



















Example 23: Cationic FORMULATION
















Cationic O/W sun cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Distearyldimonium Chloride
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50
3.50



Glyceryl Stearate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Stearyl Alcohol
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenethyl Benzoate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



C12-15 Alkyl Benzoate
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Diethylhexyl Carbonate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Cetyl Ricinoleate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Triisostearin
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Trisodium EDTA
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20


Part C
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben












Tocopheryl Acetate
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-

3.00


3.00







methane












Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00





diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Ethylhexyl
7.00







5.00



Methoxycinnamate












Bis-Ethylhexyloxyphenol

2.00





2.00




Methoxyphenyl Triazine **












Merocyanine A or B


1.00





0.50



In vitro SPF measured according
39.6
32.9
36
39.8
36.4
50.7
42.3
49.2
59



the method described












UVA PF measured according
15.9
10.9
13.8
20.1
17.6
23.2
22
24.7
26.2



the method described



















Example 24: Cationic FORMULATION—Si/W FORMULATION
















Si/W sun cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Cyclopentasiloxane (and)
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00
8.00



Dimethicone/Vinyl












Dimethicone Crosspolymer












Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Dimethicone (and)
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00



Dimethicone/Vinyl












Dimethicone Crosspolymer












Cyclopentasiloxane
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00


Part B
Butylene Glycol
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Polyglyceryl-3 Disiloxane
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Dimethicone












Polyglyceryl-3 Polydimethyl-
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30



siloxyethyl Dimethicone












Acrylamide/Sodium
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Acryloyldimethyltaurate Co-












polymer (and) Isohexadecane












(and) Polysorbate 80












Ammonium Acryloyldimethyl-
0.65
0.65
0.65
0.65
0.65
0.65
0.65
0.65
0.65



taurate/VP Copolymer












Sodium Chloride
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00


3.00
3.00







Tetramethylbutylphenol *












Diethylamino Hydroxy

4.00

4.00

4.00
4.00

4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane












Ethylhexyl Triazone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tris-Biphenyl Triazine *






2.00





Methanone, 1,1′-(1,4-piperazine-







2.00




diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Zinc Oxide
4.00











Isoamyl p-Methoxycinnamate

3.00










Polysilicone-15


5.00









Disodium Phenyl



2.00








Dibenzylmidazole












Tetrasulfonate












Benzophenone-3




3.00







Terephthalylidene





1.00
1.00
1.00
1.00



Dicamphor Sulfonic Acid












Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **












In vitro SPF measured according
37.6
33.3
24.2
25.2
29.7
32.5
42.4
28.8
37.3



the method described












UVA PF measured according
13.5
10.7
6.1
10.6
10
14.7
17.8
10.5
16.2



the method described



















Example 25: O/W FORMULATION—Anionic System emulsifier
















Emulsion high Protection
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Cyclomethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Ethylhexyl Palmitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Glyceryl Stearate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Potassium Cetyl Phosphate
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80
1.80



VP/Eicosene Copolymer
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Acrylates/Palmeth-25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



Acrylate Copolymer












Glycerin
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00



Disodium EDTA
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20


Part C
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben












Tocopheryl Acetate
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30


Part
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00


D
or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00




Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-


3.00

3.00


3.00




methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone





1.00
1.00



















Example 26: Sun Milk



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
C12-15 Alkyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Isohexadecane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Cyclopentasiloxane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Stearic Acid
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



PEG-100 Stearate (and)
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Glyceryl Stearate












Potassium Cetyl Phosphate
1.30
1.30
1.30
1.30
1.30
1.30
1.30
1.30
1.30



PVP/Eicosene Copolymer
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00


Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Propylene Glycol
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Xanthan Gum
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Acrylates/C10-30 Alkyl
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Acrylate Crosspolymer












Disodium EDTA
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15


Part C
Triethanolamine
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs



Dimethicone
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40
0.40



Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben












Tocopheryl Acetate
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00





Tetramethylbutylphenol *












Diethylamino Hydroxy


4.00

4.00


4.00




Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone



2.00
2.00



2.00



Ethylhexyl Salicylate

5.00










Tris-Biphenyl Triazine *


2.00









Octocrylene



8.00








Diethylhexyl Butamido




1.00







Triazone












Phenylbenzimidazole





2.00






Sulfonic Acid












Titanium Dioxide ***






2.00





Homosalate







10.00




Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *



















Example 27: Every Day Lotion



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Stearyl Phosphate
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Triisodecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Tricontanyl PVP
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Ethoxydiglycol Oleate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Squalane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



C12-15 Alkyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Glyceryl Stearate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Cetyl Alcohol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Steareth-10 Allyl
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Ether/Acrylates Copolymer












Glycerin
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Diazolidinyl Urea (and)
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Iodopropynyl












Butylcarbamate












Sodium Lauroyl Glutamate
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70


Part C
Cyclopentasiloxane (and)
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Dimethiconol












Triethanolamine
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85
1.85



Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate












Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-

3.00


3.00







methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone




2.00



2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00





diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Ethylhexyl
7.00







5.00



Methoxycinnamate












Bis-Ethylhexyloxyphenol

2.00





2.00




Methoxyphenyl Triazine **












Merocyanine A or B


1.00





0.50



















Example 28: Every Day Lotion—Nonionic System emulsifier—O/W FORMULATION
















Sun Cream
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Tribehenin PEG-20 esters
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dibutyl adipate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



PPG-2 Myristyl Ether
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Propionate











Part B
Aqua
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



PVP/dimethylconylacrylate/
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



polycarbamyl/polyglycol ester












Disodium EDTA
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Sclerotium Gum
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Ammonium Acryldimethyl-
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



taurate/Beneth-25 Methacrylate












Crosspolymer.











Part C
Cyclopentasiloxane (and)
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



cyclohexasiloxane












Phenoxyethanol (and)
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben












Sodium Hydroxide (and) Aqua
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp
Qsp


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00


3.00
3.00







Tetramethylbutylphenol *












Diethylamino Hydroxy Benzoyl

4.00

4.00

4.00
4.00

4.00



Hexyl Benzoate












Butyl Methoxydibenzoyl-


3.00

3.00


3.00
3.00



methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone

2.00





2.00
2.00



Tris-Biphenyl Triazine *






2.00





Methanone, 1,1′-(1,4-piperazine-







2.00




diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Zinc Oxide
4.00











Isoamyl p-Methoxycinnamate

3.00










Polysilicone-15


5.00









Disodium Phenyl



2.00








Dibenzylmidazole Tetrasulfonate












Benzophenone-3




3.00







Terephthalylidene Dicamphor





1.00
1.00
1.00
1.00



Sulfonic Acid












Drometrizole Trisiloxane





1.00
1.00
1.00
1.00



Bis-Ethylhexyloxyphenol








2.00



Methoxyphenyl Triazine **



















Example 29: Every Day Lotion—Nonionic System emulsifier—O/W FORMULATION
















UV-A/UV-B Daily Care UV Protection Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Oleth-3 Phosphate
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Steareth-21
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Steareth-2
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cetyl Alcohol
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Stearyl Alcohol
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Tribehenin
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80
0.80



Isohexadecane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Glycerin
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Disodium EDTA
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10


Part C
Aqua
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00



Diazolidinyl Urea (and)
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15
0.15



Iodopropynyl Butyl-












carbamate












Propylene Glycol
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00


Part D
Sodium Acrylates Co-
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



polymer (and)












Paraffinium Liquidum (and)












PPG-1 Trideceth-6












Cyclopentasiloxane
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



PEG-12 Dimethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tocopheryl Acetate
0.45
0.45
0.45
0.45
0.45
0.45
0.45
0.45
0.45



Water (and) Citric Acid
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs



Fragrance
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00




Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-


3.00

3.00


3.00




methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone





2.00
2.00
2.00
2.00



















Example 30: Daily Care Lotion



















A
B
C
D
E
F
G
H
I



INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Polyglyceryl Methyl
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



Glucose Distearate












Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Tridecyl Trimellitate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cetearyl Alcohol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Octyl Stearate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Caprylic/Capric
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Triglyceride












Isohexadecane
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00


Part B
Aqua
64.80
64.80
64.80
64.80
64.80
64.80
64.80
64.80
64.80



Glycerin
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00


Part C
Phenoxyethanol (and)
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Methylparaben (and)












Butylparaben (and)












Ethylparaben (and)












Propylparaben












Cyclomethicone (and)
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Dimethicone












Steareth-10 Allyl
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Ether/Acrylates












Copolymer











Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00





Tetramethylbutylphenol *












Diethylamino Hydroxy


4.00

4.00


4.00




Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone
2.00
2.00





0.50
2.00



Ethylhexyl Salicylate

5.00










Tris-Biphenyl Triazine *


2.00









Octocrylene



8.00








Diethylhexyl Butamido




1.00







Triazone












Phenylbenzimidazole





2.00






Sulfonic Acid












Titanium Dioxide ***






2.00





Homosalate







10.00




Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *



















Example 31: SPRAY FORMULATION—Classic
















Sprayable Sunscreen Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Potassium Cetyl
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



Phosphate












Isohexadecane
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Phenethyl Benzoate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Triisodecyl Trimellitate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Dimethyl Capramide
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



VP/Eicosene Copolymer
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



Di-C12-13 Alkyl Tartrate
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



C12-15 Alkyl Benzoate
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50


Part B
Aqua
qs
qs
qs
qs
qs
qs
qs
qs
qs




to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100
to 100



Sorbeth-30
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Sorbitan Stearate (and)
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00



Sucrose Cocoate












Aqua
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00


Part C
Phenoxyethanol (and)
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70
0.70



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben











Part D
Water (and) Citric Acid
qs
qs
qs
qs
qs
qs
qs
qs
qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol

2.00
2.00
2.00


2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00


3.00
3.00
3.00





Tetramethylbutylphenol *












Diethylamino Hydroxy


4.00

4.00


4.00




Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-
3.00


3.00

3.00


3.00



methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
6.0



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone



2.00
2.00
2.00
2.00
2.00




Ethylhexyl Salicylate

5.00










Tris-Biphenyl Triazine *


2.00









Octocrylene



8.00








Diethylhexyl Butamido




1.00







Triazone












Phenylbenzimidazole





2.00






Sulfonic Acid












Titanium Dioxide ***






2.00





Homosalate







10.00




Methanone, 1,1′-(1,4-piperazine-








2.00



diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *



















Example 32: SPRAY FORMULATION—Foaming
















Foameous O/W Lotion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w





















Stearic Acid
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Cetearyl Alcohol
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50
2.50



PEG-30-Stearate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Aluminium Starch
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Octenylisuccinate












Talc
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Polyurethane
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Magnese silicate
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



PEG-180/Octoxynol-
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25



40/TMMG Copolymer












Cyclomethicone
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Dimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Phenyl Trimethicone
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone/Vinyl
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethicone Crosspolymer












Cetyl Palmitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Cera Microcristallina
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Hydrated Polyisobutene
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Citric Acid
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



glycerin
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00



Parfume, Preservatives
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Sodium Hydroxide
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Dyes etc.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.



Aqua
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100
ad 100



pH-value adjusted to 6.0-7.5












Propellent
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs
Qs


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol
2.00
2.00
2.00


2.00
2.00
2.00




Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00


3.00
3.00
3.00


3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy

4.00

4.00


4.00

4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-


3.00

3.00


3.00




methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
8.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone





2.00
2.00
2.00



















Example 33: W/O FORMULATION
















EG-free sunscreen
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Hexyldecanol
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Polyglyceryl-3 Methyl-
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40



glucose Distearate












Phenethyl Benzoate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Triisodecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Polyglyceryl-10 poly-
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40
1.40



hydroxy stearate












Cetyl Ethylhexanoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Isohexadecane
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Phenoxyethanol (and)
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Methylparaben (and) Ethyl-












paraben (and) Butylparaben












(and) Propylparaben (and)












Isobutylparaben











Part B
Aqua
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100
Qs 100



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00


Part C
Sodium Acrylates Co-
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50



polymer (and) Mineral Oil












(and) PPG-1 Trideceth-6












Cyclopentasiloxane
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50
1.50


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-

3.00


3.00







methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone
2.00
2.00





2.00
2.00



Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00





diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Ethylhexyl
7.00







5.00



Methoxycinnamate












Bis-Ethylhexyloxyphenol

2.00





2.00




Methoxyphenyl Triazine **












Merocyanine A or B


1.00





0.50



















Example 34: W/Si FORMULATION
















W/Si emulsion
A
B
C
D
E
F
G
H
I


















INCI-Name
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w
% w/w




















Part A
Tetrabutoxypropyl
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90
0.90



Trisiloxane












Benzyl Laurate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Phenethyl Benzoate
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Tridecyl Trimellitate
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Dimethyl Capramide
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Cetyl dimethicone
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00



Polyglyceryl-4, isostearate,
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00
6.00



cetyl dimethicone copolyol












and hexyl laurate












polyglyceryl-3 dioleate
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60
0.60



Glyceryl tribehenate
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



cyclomethicone
8.85
8.85
8.85
8.85
8.85
8.85
8.85
8.85
8.85


Part B
Aqua
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100
Qsp 100



Xanthan gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Disodium EDTA
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Sodium chloride
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00



Glycerin
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00


Part C
Citric Acid (and) Silver
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Citrate












Sclerotium Gum
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



panthenol
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10



Sodium ascorbyl
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20
0.20



phosphate












tocopheryl acetate
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50



Phytantriol
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30
0.30



Bis-Ethylhexyloxyphenol
4.0

2.00


6.0


1.50



Methoxyphenyl Triazine)












encapsulated in a polymer












matrix, as described in












IP.com Journal (2009),












9(1B), 17 (Tinosorb S












aqua, BASF)












Fragrance/preservative
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.
q.s.


Part D
MBM 1 or MBM 2 or MBM 3
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00



or MBM 4 or MBM 5 or MBM












6 or MBM 7 or MBM 8 or












MBM 9 or MBM 10 or MBM












11 or MBM 12 or MBM 13












Bis-Ethylhexyloxyphenol


2.00
2.00
2.00
2.00
2.00
2.00
2.00



Methoxyphenyl Triazine












Methylene Bis-Benzotriazolyl
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00



Tetramethylbutylphenol *












Diethylamino Hydroxy
4.00


4.00
4.00
4.00
4.00
4.00
4.00



Benzoyl Hexyl Benzoate












Butyl Methoxydibenzoyl-

3.00


3.00







methane












Bis(butylbenzoate) diamino-
2.0
4.0
1.0
1.0
0.5
1.0
0.5
1.0
0.5



triazine aminopropyl-












siloxane (BBDAPT)












Ethylhexyl Triazone




2.00
2.00






Tris-Biphenyl Triazine *





2.00


2.00



Methanone, 1,1′-(1,4-piperazine-






2.00





diyl)bis[1-[2-[4-(diethylamino)-












2-hydroxybenzoyl]phenyl]-












CAS number (919803-06-8) *












Ethylhexyl
7.00







5.00



Methoxycinnamate












Bis-Ethylhexyloxyphenol

2.00





2.00




Methoxyphenyl Triazine **

## Claims

1. A method for protecting human and animal hair and skin against UV radiation by applying thereto a composition comprising:
(a) a first UV filter selected from benzylidene malonate of formula




 wherein
R1 is methyl;
R is





(b) at least two second UV filters selected from the group consisting of
(b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
(b3) Diethylhexyl Butamido Triazone;
(b4) Ethylhexyl Triazone;
(b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate;
(b6) Ethylhexyl Methoxycinnamate;
(b7) Ethylhexyl Salicylate;
(b8) Homosalate;
(b9) Octocrylene;
(b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
(b11) Phenylbenzimidazole Sulfonic Acid;
(b12) Titanium Dioxide;
(b13) micronized Tris-Biphenyl Triazine;
(b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; and
(b15) Benzoic acid,4,4′-[[3-[1,3,3,3-tetramethyl-1-trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester;
wherein at least one of the second UV filters is selected from component (b5) and component (b10);

(c) cosmetically tolerable carriers or adjuvants; and
(d) optionally one or more further UV agents selected from the group consisting of p-aminobenzoic acid derivatives, benzophenone derivatives, 3-imidazol-4-yl acrylic acid and esters; benzofuran derivatives, polymeric UV absorbers, cinnamic acid derivatives, camphor derivatives, menthyl o-aminobenzoate; and merocyanine derivatives,
wherein the first UV filter (a), the one or more second UV filters (b), and the one or more further UV agents (d), when present, are the only UV protective agents in the composition,
wherein the composition contains from 0.1 to 30% by weight of the UV filters (a) and (b) based on the total weight of the composition, and
wherein the composition contains from 0.1 to 15% by weight of UV filter (a) based on the total weight of the composition.

2. The method according to claim 1, wherein the composition comprises component (b1).

3. The method according to claim 2, wherein the composition comprises component (b5).

4. The method according to claim 2, wherein the composition comprises component (b10).

5. The method according to claim 1, wherein the composition comprises component (b4) and/or (b15).

6. The method according to claim 1, wherein the composition comprises at least three of the second UV filters selected from the group consisting of (b1) and (b3)-(b15).

7. The method according to claim 6, wherein the composition comprises components (b1), (b4), and (b10).

8. The method according to claim 6, wherein the composition comprises components (b1), (b4), and (b5).

9. The method according to claim 1, wherein the composition comprises at least four of the second UV filters selected from the group consisting of (b1) and (b3)-(b15).

10. The method according to claim 9, wherein the composition comprises component (b1), component (b4), at least one of component (b5) and (b10), and at least one of component (b3), (b7)-(b9), and (b11)-(b15).

11. The method according to claim 9, wherein the composition comprises component (b5), component (b10), at least one of component (b4) and (b15), and at least one of component (b3), (b7)-(b9), and (b11)-(b14).

12. The method according to claim 1,
wherein the composition contains from 0.5 to 10% by weight of the UV filters (a) and (b) based on the total weight of the composition.

13. A method for protecting human and animal hair and skin against UV radiation by applying thereto a composition consisting of:
(a) a first UV filter selected from benzylidene malonate of formula




 wherein
R1 is methyl;
R is





(b) at least two second UV filters selected from the group consisting of
(b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine;
(b3) Diethylhexyl Butamido Triazone;
(b4) Ethylhexyl Triazone;
(b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate;
(b6) Ethylhexyl Methoxycinnamate;
(b7) Ethylhexyl Salicylate;
(b8) Homosalate;
(b9) Octocrylene;
(b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol;
(b11) Phenylbenzimidazole Sulfonic Acid;
(b12) Titanium Dioxide;
(b13) micronized Tris-Biphenyl Triazine;
(b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; and
(b15) Benzoic acid,4,4′-[[3-[1,3,3,3-tetramethyl-1-trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester;
wherein at least one of the second UV filters is selected from component (b5) and component (b10);

(c) cosmetically tolerable carriers or adjuvants selected from the group consisting of creams, gels, lotions, alcoholic solutions, aqueous/alcoholic solutions, emulsions, wax/fat compositions, stick preparations, powders, ointments, mild surfactants, super-fatting agents, pearlescent waxes, consistency regulators, thickeners, polymers, silicone compounds, fats, waxes, stabilisers, biogenic active ingredients, deodorising active ingredients, anti-dandruff agents, film formers, swelling agents, antioxidants, hydrotropic agents, preservatives, insect repellents, self-tanning agents, solubilisers, perfume oils, colourants, bacteria-inhibiting agents, and combinations thereof; and
(d) optionally one or more further UV agents selected from the group consisting of p-aminobenzoic acid derivatives, benzophenone derivatives, 3-imidazol-4-yl acrylic acid and esters;

benzofuran derivatives, polymeric UV absorbers, cinnamic acid derivatives, camphor derivatives, menthyl o-aminobenzoate; and merocyanine derivatives,
wherein the composition contains from 0.1 to 30% by weight of the UV filters (a) and (b) based on the total weight of the composition, and
wherein the composition contains from 0.1 to 15% by weight of UV filter (a) based on the total weight of the composition.