# Charles Busch

Enclosed are the results of analyses for samples received by the laboratory on02/08/13 11:30
.If you have any questions concerning this report, please feel free to contact me at 1-800-858-5227. Oily Waste Analysis RE: Oily Waste Analysis Ankeny, IA 50021 825 SW Irvinedale Drive John Deere Des Moines Works 05 March 2013

ANALYTICAL REPORT FOR SAMPLES Client Sample ID Laboratory IDMatrix Date Sampled Date Received 

## FC Composite 2 1B30478-01 Sludge 12/06/12 14:30 02/08/13 11:30 THF Extract 1B30478-02 Other 12/06/12 14:30 02/08/13 11:30 Toluene Extract 1B30478-03 Other 12/06/12 14:30 02/08/13 11:30 TCLP Extract 1B30478-04 Water 12/06/12 14:30 02/08/13 11:30

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 1 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23



# COC Goes Here

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 2 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Analyte Limit Batch Reporting PreparedAnalyzedMethodNotes Dilution Units 

## FC Composite 2 1B30478-01 (Sludge) Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton TCLP Extraction EPA 1311 

### 7.6 1WB073502/27/1302/27/13 

### pH 1 

### TCLP pH, Final 

### 0.1

" 

### 5.0 " " " 

### " " 

### TCLP pH, Initial 

### 0.1 

### EPOW Extraction EPA 1330A 

### 302 1WC006402/22/1302/22/13 

### ml 1 

### THF Extract Final Volume 

### 1.0

" 

### 404 " " " 

### " " 

### Toluene Extract Final Volume 

### 1.0

" 

### 936 " " " 

### " " 

### Acetate Buffer Final Volume 

### 1.0

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 3 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Analyte Limit Batch Reporting PreparedAnalyzedMethodNotes Dilution Units 

## THF Extract 1B30478-02 (Other) Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton Determination of Total Metals ND EPA 6010B 02/28/1302/28/13 

### mg/L 1WB0732

4 

### Barium, total 0.040 R-01

" 

### 0.164 " " " 

### " " 

### Chromium, total 

### 0.040

" 

### 1.91 " " " 

### " " 

### Copper, total 

### 0.040

" 

### 0.110 " " " 

### " " 

### Lead, total 

### 0.040 ND EPA 7471A 03/01/1303/01/13 

### " 1WC0011

1 

### Mercury, total 0.0005 EPA 6010B 

### 0.486 1WB073202/28/1302/28/13 

### " 4 

### Nickel, total 

### 0.040 ND " " " 

### " "

" 

### Vanadium, total 0.200 R-01 

### ND " " " 

### " "

" 

### Zinc, total 0.040 R-01

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 4 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Analyte Limit Batch Reporting PreparedAnalyzedMethodNotes Dilution Units 

## Toluene Extract 1B30478-03 (Other) Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton Determination of Total Metals ND EPA 6010B 02/28/1302/28/13 

### mg/L 1WB0732

1 

### Barium, total 0.010

" 

### 0.013 " " " 

### " " 

### Chromium, total 

### 0.010

" 

### 0.068 " " " 

### " " 

### Copper, total 

### 0.010 ND " " " 

### " "

" 

### Lead, total 0.010 EPA 7471A 

### 0.0005 1WC001103/01/1303/01/13 

### " " 

### Mercury, total 

### 0.0005 EPA 6010B 

### 0.042 1WB073202/28/1302/28/13 

### " " 

### Nickel, total 

### 0.010 ND " " " 

### " "

" 

### Vanadium, total 0.050

" 

### 0.015 " " " 

### " " 

### Zinc, total 

### 0.010

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 5 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Analyte Limit Batch Reporting PreparedAnalyzedMethodNotes Dilution Units 

## TCLP Extract 1B30478-04 (Water) Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton Determination of Total Metals EPA 6010B 

### 0.048 1WB073202/28/1302/28/13 

### mg/L 1 

### Barium, total 

### 0.010 ND " " " 

### " "

" 

### Chromium, total 0.010

" 

### 0.097 " " " 

### " " 

### Copper, total 

### 0.010 ND " " " 

### " "

" 

### Lead, total 0.010 ND EPA 7471A 03/01/1303/01/13 

### " 1WC0011

" 

### Mercury, total 0.0005 EPA 6010B 

### 0.244 1WB073202/28/1302/28/13 

### " " 

### Nickel, total 

### 0.010 ND " " " 

### " "

" 

### Vanadium, total 0.050

" 

### 0.026 " " " 

### " " 

### Zinc, total 

### 0.010

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 6 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Limit

ReportingUnits Level SpikeResult

Source%REC%REC LimitsRPD RPD Limit Notes Analyte 

## Determination of Total Metals - Quality Control 

# Keystone Laboratories, Inc. - Newton

Batch 1WB0732 - EPA 3010A Digestion (Water) Blank (1WB0732-BLK1) 

### Prepared & Analyzed: 02/28/13 Barium, total mg/L ND 0.010 Chromium, total " ND 0.010 Copper, total " ND 0.010 Lead, total " ND 0.010 Nickel, total " ND 0.010 Vanadium, total " ND 0.050 Zinc, total " ND 0.010 

### Blank (1WB0732-BLK2) 

### Prepared & Analyzed: 02/28/13 Barium, total mg/L ND 0.010 Chromium, total " ND 0.010 Copper, total " ND 0.010 Lead, total " ND 0.010 Nickel, total " ND 0.010 Vanadium, total " ND 0.050 Zinc, total " ND 0.010 

### LCS (1WB0732-BS1) 

### Prepared & Analyzed: 02/28/13 Barium, total mg/L 3.19 0.010 3.33333 80-120 95.6 Chromium, total " 3.27 0.010 3.33333 80-120 98.0 Copper, total " 3.38 0.010 3.33333 80-120 102 Lead, total " 3.11 0.010 3.33333 80-120 93.3 Nickel, total " 3.17 0.010 3.33333 80-120 95.0 Vanadium, total " 3.57 0.050 3.33333 80-120 107 Zinc, total " 3.22 0.010 3.33333 80-120 96.5 

### LCS Dup (1WB0732-BSD1) 

### Prepared & Analyzed: 02/28/13 Barium, total mg/L 3.26 0.010 3.33333 200 80-120 97.7 2.17 Chromium, total " 3.35 0.010 3.33333 200 80-120 101 2.64 Copper, total " 3.42 0.010 3.33333 200 80-120 103 1.16 Lead, total " 3.19 0.010 3.33333 200 80-120 95.8 2.66 Nickel, total " 3.25 0.010 3.33333 200 80-120 97.6 2.69 Vanadium, total " 3.62 0.050 3.33333 200 80-120 109 1.43 Zinc, total " 3.31 0.010 3.33333 200 80-120 99.4 2.90

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 7 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23

Result Limit

ReportingUnits Level SpikeResult

Source%REC%REC LimitsRPD RPD Limit Notes Analyte 

## Determination of Total Metals - Quality Control 

# Keystone Laboratories, Inc. - Newton

Batch 1WB0732 - EPA 3010A Digestion (Water) Duplicate (1WB0732-DUP1) 

### Prepared: 02/28/13 Analyzed: 03/01/13 Source: 1B30478-04 Barium, total mg/L 0.046 0.010 0.048 20 4.79 Chromium, total " 0.010 0.010 0.009 20 1.15 Copper, total " 0.0989 0.010 0.0967 20 2.33 Lead, total " ND 0.010 ND 20 Nickel, total " 0.238 0.010 0.244 20 2.68 Vanadium, total " 0.00439 0.050 0.00597 20 A-01 30.5 Zinc, total " 0.0289 0.010 0.0261 20 10.3 

### Batch 1WC0011 - EPA 7470A Hg Water Blank (1WC0011-BLK1) 

### Prepared & Analyzed: 03/01/13 Mercury, total mg/L ND 0.0005 

### LCS (1WC0011-BS1) 

### Prepared & Analyzed: 03/01/13 Mercury, total mg/L 0.002 0.0005 0.00250000 78-132 87.2 

### LCS Dup (1WC0011-BSD1) 

### Prepared & Analyzed: 03/01/13 Mercury, total mg/L 0.002 0.0005 0.00250000 20 QS-07 78-132 78.0 11.1 

### Certified Analyses Included in This Report Certifications Analyte Method/Matrix EPA 6010B in Water NELAC,SIA1X,KS-NT Barium, total NELAC,SIA1X,KS-NT Chromium, total NELAC,SIA1X,KS-NT Copper, total NELAC,SIA1X,KS-NT Lead, total NELAC,SIA1X,KS-NT Nickel, total NELAC,SIA1X,KS-NT Vanadium, total NELAC,SIA1X,KS-NT Zinc, total



### Certifying Authority Certificate Number Expires Code E-10110

Kansas Department of Health and Environment-KC 04/30/2013 KS-KC E-10287

Kansas Department of Health and Environment 10/30/2013 KS-NT 140

Missouri Department of Natural Resources 04/30/2013 MO-KC IA001

New Jersey Department of Environmental Protection 06/30/2013 NELAC 95

Iowa Department of Natural Resources 02/01/2014 SIA1X

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 8 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23


## Notes and Definitions R-01 The Reporting Limit for this analyte has been raised to account for matrix interference. QS-07The spike recovery for this QC sample was below established acceptance limits. A-01 RPD EXCEEDS ACCEPTANCE LIMITS; HOWEVER ANALYTE IS LESS THAN REPORTING LIMIT

Sample results reported on a dry weight basis Relative Percent Difference RPD dry Not Reported NR Analyte NOT DETECTED at or above the reporting limit ND Analyte DETECTED DET

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 9 of 10

### John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis Charles Busch Oily Waste Analysis Ankeny IA, 50021 Project: Project Number: Project Manager: Reported 03/05/13 11:23



### Jeffrey King, Ph.D. For Staci Arnold Project Manager I

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its entirety. 

## Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989 Newton, IA 50208 Page 10 of 10