p. 1 
81Yt ENVIRONMENTAL LABORATORY 

Chain-of-Custody 

Project : GLPIO.Ol-01-39 

Shipping Address: 

3M Environmental Laboratory 

3M Center, Bldg 260-5N-17 

St. Paul, MN 55144 

Phone: (651) 733-9873 

All. Phone: (651) 736-6559 

Fax: (651) 733-4687 

Requester: Hohenstein, Gary Allan (MAPLEWOI Completion Date: 

Department: 530711 Project Lead: Cliff Jacoby 

Project Number: 0022674449 Phone Number: 651-733-2533 

Date Created: 11/27/2012 Email Address: cbjacoby2@mmm.com 

Project Description: Former Sludge Incorporation Area (FSIA) GW 

Sampling- Q4 2012 

Comments: 

3MSamnleNumber Sample Descrintion Date/Time Samoled Matrix Comment 

GLP10-01-01-39-001 DAL-GW-13012-0- 0, (I 3p 11 3D Ild ~~i W 

GI.PIO-01-01-39-002 DAL-GW-130R-DB- t o o rJ. b W 

GLPIO.Ol-01-39-003 DAL-GW-130S-0- ,2 3D ~ ( v 

GLPI0-01-01-39-004 DAL-GW-130S-DB- i 1 a ~ 1 ( I 

GLPIO-01-01-39-005 DAL-GW-130S-FMS- ja( D u lo~ 

GLPI0-01-01-39-006 DAL-GW-130L-0- ( ;D ~ D lid 0Z Iq/ 

GLP10-01-01-39-007 DAL-GW-130L-DB- v D 0 ~,O I 

GLPIO-Ol-01-39-008 DAL-GW-131R-0- 19 6 ,;, 1 ;2 OK 16 &15 ', 

GLPIO-01-O1-39-009 DAL-GW-131R-D!3- A 65 IAg ~ O OSLK I 

GLPIO-01-01-39-010 DAL-GW-131S-0- I )OL' a,0 

GLPIO-01-01-39-011 DAL-GW-131S-DB- I a la 04 ~a0 ~ 

, 

V'/ 

GI-P10-07-01-39-012 DAL-GW-131S-FMS- a t

?~ W 

G010-01-01-39-013 DAL-GW-131L-0- O f~ O 

GLPIO-01-01-39-014 DAL-GW-131L-DB- w loo J~ P, yJ ' 

Sample Condition Upon Receipt Acceptable 

Temperature: a.,- Deg C ~ Received on Ice 

Collected by (print): 

Reli7~, hlied by: Date ate

// 

11 items accounted for 

El Other: 

Time Shipped Vin Date Time 

ia o~ 9A 2-2 

I 

Collector's signature : 

Received b . 

1) 1 

Page I of 5 
30 ENVIRONMENTAL LABORATORY 

Chain-of-Custody 

Shipping Address: 

3M Environmental Laboratory 

3M Center, Bldg 260-5N-17 

St. Paul, MN 55144 

Phone: (651) 733-9873 

Alt. Phone: (651) 736-6559 

Project: GLP10-01-01-39 (cont.) Fax: (651) 733-4687 

Requester: Hohenstein, Gary Allan (MAPLEWO( Completion Date: 

Department: 530711 Project Lead: Cliff Jacoby 

Project Number: 0022674449 Phone Number. 651-733-2533 

Date Created: 11/27/2012 Email Address: cbjacoby2@mmm.com 

Project Description: Former Sludge Incorporation Area (FSIA) GW 

Sampling-Q4 2012 

3M Sample Number Sample Description Date/Time Sampled Matrix Comment 

GLPIO-01-01-39-O1s DAL-GW-133R-0- ~'~ +~ BS ' Q~~a 

GLPIO-01-01-39-016 DAL" GW" 133R-DB- DS ~~~~ ~ yv/ 

GLP10.01"01 " 39-O17 DAL-GWa33S-o- 6 ' p 

GLP10-01-01-39-018 DAL-GW-133S-DB- ~ ~ 3" 

GLP10-01-01-39-019 DAL-GW-133L-0- a $4~y 

GLP10-o1-01-39-020 DALGW-133L-DB- ( 3D 

GLP10-01-01-39-021 DALGW-134R-0- I 0 OS ld 

GLP10-Ol-Ol-39-022 DALGW-134R-DB- ~ S U ~. ~tytl W 

GLP10-01-0]-39-023 DAL-OW-134S-0- 05, 

GLPIO.Ol-01-39-024 DAL-GW-134S-DB- I 0 

GLPIO-O]-01-39-025 DAILGW-134L"0- a 9p.? ~ 

GLPIO-OI-Ol-39-026 DAL-GW-134L"DB" ~ y 0 

GLI'10-01-01-39-027 DAL-GW-135R-0- r' 

GI,PIO-01-01-39-028 DAL-GW-135R-1)B- l a o< )A//)g 10 VJ 

GLPIO-01-01-39-029 DAL-GW-135S-0- a 03 /s- ) / 

GLP10-01-01-39-030 DAL-Gbv-1355-Dls- ~ ~~ d / OS l (7~I VJ 

GLPIO-01-O1-39-031 DAL-GW-135L0- jd, OS 1 ' I ~a 

Sample Condition Upon Receipt XAcceptable XAll items accounted for 

Temperature: .- gr Deg C D Received on lee 0 Other: 

Collected by (print): &L ~ML Collector's signature: 

Relin e by: Date Time Shipped Via Received by : v -Date Time 

) a~ ~ ~+ / i 1_Ii ~j, 

Page 2 of 5 
3M ENVIRONMENTAL LABORATORY 

Chain-of-Custody 

Shipping Address: 

3M Environmental Laboratory 

3M Center, Bldg 260-5N-17 

St . Paul, MN 55144 

Phone: (651) 733-9873 

Alt. Phone: (651) 736-6559 

Project: CLP10-o1-01-39 (cont.) Fax: (651) 733-4687 

Requester: Hohenstein, Gary Allan (MAPLEWO( Completion Date: 

Department: 530711 Project Lead: Cliff Jacoby 

Project Number: 0022674449 Phone Number. 651-733-2533 

Date Created: 11/27/2012 Email Address: cbjacoby2@mmm.com 

Project Description: Former Sludge Incorporation Area (FSIA) GW 

Sampling- Q4 2012 

3M Sample Number Sample Descrintion Date/Time Sample Matrix Common 

GLPIO-0I-01-39-032 DAL-GW-135L-DB- a 0~ )a o 

GLPIO-01-O1-39-033 DAL-GW-136R-0- _ ) 

GLP1O-01-O1-39-034 DAL-OW-136R-1)[3- ~ 

g 

GLPID-OI-Ol-39-035 DAL-OW-136S-0- a y 

GLP10-01-01-39-036 DAL-GW-136S-DB- a 3a a ( D 

GLP1O-01-01-39-037 DAL-GW-136S-FMS- 3a i'a 11 ~, Z 

GLP10-01-O1-39-038 DAL-GW-I36L-0- O a 3~ ys/' 

GLP10-01-01-39-039 DAL-GW-136L-DB- ., M;- 3q 6tJ 

GLPIO-01-01-39-040 DAL-GW-137R-0- 04 

GLPIO.OI-Ol-39-041 DAL-OW-13711-13BGLPIO.Ol-01-39-042 DAL-GW-137S-0- ~a 11 India v; Vf 

GLPIO-Ol-01-39-043 DAL-GW-137S-DB- 1 A105 11a, 15 f{n! 

GLP10-O1-01-39-044 DAL-GW-137S-FMS- YOU Os'' 

6d/0 

I5 )nf 

GLPIO.Ol-01-39-045 DAL-OW-137L-0- a 

-~_ OS' Ir3. V' 

GLPIO.Ol-01-39-04G DAI:GW-137L-Dl3- os o5 D 1,~ 

GLPIO-01-O1-39-047 DAL-GW'-138R-0- 

GLPID-01-01-39-048 DAL-GW-138R-D13- 4 5n.,t0W -0Ml I 

Sample Condition Upon Receipt 

7

.. Acceptable XAll items accounted for 

Temperature : r~-' Deg C ~0 Received on Ice El Other: 

Collected by(prinQ : AA;Ls ~yha-~ Collector's signature; 

Relinqgipllgd by: Date Time Shipped Via Received by" Date Time 

aw ell E ~ 1 

Page 3 of 5 
311111 ENVIRONMENTAL LABORATORY 

Chain-of-Custody 

Shipping Address: 

3M Environmental Laboratory 

3M Center, Bldg 260-5N-17 

St . Paul, MN 55144 

Phone: (651) 733-9873 

Alt. Phone: (651) 736-6559 

Project: GLP10-O1-01-39 (cont.) Fax: (651) 733-4687 

Requester: Holtenstein, Gary Allan (MAPLEWOI Completion Date : 

Department: 530711 Project Lead: Cliff Jacoby 

Project Number: 0022674449 Phone Number. 651-733-2533 

Date Created : 11/27/2012 Email Address : cbjacoby2@mmm.com 

Project Description: Former Sludge Incorporation Area (FSIA) GW 

Sampling- Q4 2012 

3A7 Snmnle Number Sample Descrintfon Date/Time Snmnled Matrix Comment 

GLPIO-01-01-39-049 DAL-CW-138S-0- 1a a 0 jaO.SI1a DgIO W 

G] .PIO-01-01-39-t150 DAL-GW-I38S-Dtd- ) I ~ os la Oc/ la 

GLPIO-01-01-39-051 DAL-GW-138L-0- a 65 ja - 10900 

GLPIO-OI-Ol-39-052 DAI. GW-138L-DId- ~ O.~ r ~a bS Id, I bA W 

GLP10-01-DI-39-053 DAL:GW-CW26C-0- OS 12, lf~t, ~O a{ l// 

GLPIO-01-01-39-054 llAL-GW-CW26C-DB- a OS 1~. gL) yJ 

GLPIO-01-0]-39-055 DAL-GW-CW26L-0- (a a aSIt~Ib~ VU 

01-13I0-01-01-39-056 DAI.GW-CW261 .-D13- ( Id ~Oi ISSa 

E 

~^-) 

GLPIO-01-01-39-057 DAL-GW-140R-0- 

E E J III Il I 

GLPIG-01-01-39-058 DAL-GW-140R-DB- p 11 (A (( 0 I 

Gl.l'10-O1-01-39-059 DAL-GW-14111-0- ( 30 d A IL(S ~ 

I 

I 

GLPIO-01-01-39-060 DA),-GW-141R-D8- 13, if 36 I 30 J,Ie.js ~ / 

GLP10-01-01-39-061 DAL-GW-141R-FMS- '~ D s ,)_ N~J W 

GLPIO-01-01-39-062 DAL-GW-142R-0- IA 11 O ( 0 695- I 

GI .PIO-ol-01-39-063 DAL-GW-142R-Dt3- ja ~( 0 O h, jOg W 

GLPI0-01-01-39-064 DAI: GW-143R-0- AZ. c. - 1~ I- _ 

GLPIO-01-G1-39-065 DAL-OW-14312-D13- 

_ 

~4~ et - p 

Simple Condition Upon Receipt L~ Acceptable ~All items accounted for 

Temperature : ~~ ocg C /~ Received on lee El Other: 

Collected by (print) : 

&& ~M- 

~-S Collector's signature : 

b 

Rclinqui he by: Date Time Shipped Via Received by: Date Time 

- 

9 / 4 

` a iaa> FPd vAL' 12 / /~z //3a 

Page 4 of 5 
I 3M ENVIRONMENTAL LABORATORY 

', Chain-of-Custody 

Shipping Address: 

3M Environmental Laboratory 

3M Center, Bldg 260-5N-17 

St. Paul, MN 55144 

i Phone: (651) 733-9873 

I Alt. Phone: (651) 736-6559 

Project: GLP10-O1-01-39 (cont.) i Fax: (651) 733-4687 

Requester: Hohenstein, Gary Allen (M IiPLEWOt Completion Date : 

Department: 530711 j Project Lead: Cliff Jacoby 

Project Number: 0022674449 I Phone Number: 651-733-2533 

Date Created: 11/27/2012 'i Email Address: cbjacoby2lJa mmm.com 

Project Description: Former Sludge Incorporation Area (FSIA) GW 

Sampling - Q4 2012 I 

3MSample Number SamnleDescriotion Date/TimeSample d Matrix Comment 

GLPIO-01-01-39-066 DAL-GW-143R-FMS- 0 9- 

GLPIO-01-01-39-067 

DAL-OW-145R-O1- 

~ a (p, Q ]p~ D 1 ra fla ~ ` ' 

GLPIO-01-01-39-068 DAL-OW-145R-D9- a ,Z, 

~ ot h). A 16 a 

GLPIO-Oi-01-39-069 DAL-GW-145R-FMS- ( a ta d ~ I~ Ov 

GLPIO-01-01-39-070 DAL-GW- -R]3- /01 

GLP10-01-01-39-071 DAL-GW- (y5g-RDGLPIO-01-01-39-072 DAL-GW-TRIP01I-0- 

GLPIO-01 "01-39"073 DAL-GW-TRIP01~, LSGLP10-01-01-39-074 DAL-OW-TRIPOI1 i MSGLP10-01-01-39-075 DAL-GW-TRIP01~'-HSSample Condition Upon Receipt )51, Acceptable ,L4All items accounted for 

Temperature : 07 Deg C '/El 

I 

Received on lee / El Other: 

i 

Collected by (print): Collector's signature: 

Rel~inqujahe by: Date I Time Shipped Via Received by: Date Time 

raOI I JaOJ F / 

i 

Page 5 of 5 
p.8 : 

p. 10 

10 

Standard ID # 

1 

12008-22 

Component Standard Corrected Final Concentration 

Description ID# Conc. or 

Purity 

Expiration 

Date 

Weight or 

Volume Balance 10 

Weight 

(P51M L) 

FFISA qv&&P~&L. LO-111Z L&I-LoML 10 .0 

?FPeA LiEi9o-reok t4li-))13 5H-5~41- 1010 

PFHAA jW411 - I I I jqsj)P :YjW , q 11 -7)13 S6.'& M L 10 .0 

I PRAPA I'loo Ll - I I 1 10 .0 

'PENA o-occ?-11H Z4,3E0 Li / 1-71)3 5-7.,5 ot ib-0 

PFPA I 7-C, C) C?- I 1 -3 '56~0!>'ML Ll /1 -7 11'3 H9 .501, ID .0 

KUnA I'i00q-I(tP 140vot',%L 14 /1? 11 .3 W,E5V L 10 .0 

I. ?FDD A ~2-00q-fkl q qzc~$L-. 1411-7113 5D.-B M L ID-0 

P f: T~- A I scoq - I (S 4090fhWILI q /1-711e> jo J .-I A L 

PF,3,s I zot>q -//q lukx PkL q 11 -7 1 1'~, -p,-L~A I- I D I C) 

L- PrH I2-D&q-1zC . 5s5yer-& 91-2511 6,9.0 p L 0 . 1) 

F 135A ~ZC017-17-1 Hl3GP*,,L 4)'-7'13 jpO~JpjAL 10,0 

V- 0 1,13 A 1-2r~oq - 17- 2- 5t~50 P%~L q I I --I I I S Hicl .SWL 1 0 . 0 - 

-f-PFoA 41-2-ZIIB I rnL - 9.5-9 

-r-i>rok TCrtj-otq2-ZP, 54k,51rnf- L417-7-113 I V11 L- - CF~OASd CI .SIR 

-i - PFOA LIWLIG' im L. - C.F`~CR5,3 9.5 Ig 0 

T-PFI)A tC4z12-VD7Z-7-2&' ~50y,.q1tYll- i4)2-Ljj3 (yn I- - 

Cr,0-qs8 9-45s 

T -PrVA C, p. 1 -4 . co, C,02, 1-31 U 5 0 V, 5 1 rn L Lj 17,,LJ13 IML~ 9 9 

bf - P P70 Jyql- -2 -1 

tv-Ff-~DS 

V 

regl2-vou- 2bL, rWy(k,1ML q/2,7~1 11~3 I wj- CF-0-92-1 q - -4-7 

br-Pr-L)S 

J~_ODU,_410 

50"Jj)) qJ-2-Z113 JVAI_ cf ~OJ21 9-1-7 

-2 ar'o-OZ-1 9. 1-? 

br- P"s ol:-Om~ 60t451miL lvv)L CF=C,.qzl 19,2-1 

r.01" , 

ons 

C 0 Imb, 11 e CIZC& lc~ t al el 

fi Y, a I a nc, - CJ6 0720 71 

Final Vol ume 

1 

2E5mL Approximate 

Concentration of the mix 

G-N301 Uil OVIS YVe re CAAl' C%i ef~,na\ ccric, C56 112- 

ExpirationDate: 5175113 -- Ncj~e 

Expiration Date : 12 f2 LoI I 3 

Storage Location : A°i7 0 Pipette IDs: a -1 

Prepared By: Cle 

MULTbCOMPONENT PREPARATION LOG 

Book No. 12008 

Page No. 22 

Description: I Ad !~ FC MI x Solvent: ~] P C I-I 

DatePrepared : lw22f S'> 3MTrace #: 7N12-02(n'-1-y/4 

Reviewed by : 

Signature, Date 
SINGLE COMPONENT PREPARATION LOG 

Date : ... / d^ / -?- /a Book No. 12009 

Analyst: K, C 

Description: - Pr f;A S+tyLk 

Stock Number. 1C 

Weight or Volume 

Used: _ ©, f © q,-9 cN 

Concentration or 

Purity: 

Corrected Weight: 

°I`7. ~~v 

10 /.r) C~ 

Final Volume: a5 m L 

Page No. 109 

ipette 

ID(s): 9/'7 

Other Correction 

Factors: 10-9 9-~ 

Solvent end TN-A A "e""h 1 4Y ~,'C 

Number -('/IZ^D31a S/4/ 

Final Concentration: L1 

Storage Location : . . . /'y =) 7V Expiration Date : '-/-1-7- /3 

Reviewedby: -rp/~IVl ~11KQ~ 10I 

Sign~au're, Dale 
SINGLE COMPONENT PREPARATION LOG 

Date : Book No. 12009 

C Page No. 110 

Analyst: )C~ q~ 

Description: I~Y' PC r! 6 61 

Stock Number. CKO -7-001 

Weight orVot'Ismde O' f I AA G Balen 

~D(s) ' 1 -7 

Concentration or (~ ~--~ o~

~ 

Other Correction ©, p, q /_ 

Purity : 1 hD ! Factors : t IIrJ

Corrected Weight : -1 Q Number. I Z,'0 7u 1`0~ 3~N 

Final Volume: O( ~5 In L Final Concentration: L4 5 

Storage Location : /-1J 70 Expiration Date: /-/" n- 13 

Solvent and TN-A 

Reviewed by: .0b. Signature, " ` t - ~ Date 
SINGLE COMPONENT PREPARATION LOG 

Date:- 10 " /-7'4 ._ 

Book No. 72009 

Analyst: 

Description: Plt_ N-,c A JTVel 

Stock Number.-TG I'~ - l0 ~.,.7 

Weight or Volume 

Used: , ~ 1 "I 

Concentration or 

Purlty: Cl $ .aa 

ipette 

ID(s): 

Page No. 111 

q0 , 

Other Correction 

Factors : , '

+1 Solvent and 

~ . ~ ~ cl J 

TNA A ' ~6" 4' ' °

Corrected Weight : q Number : -C/V ( Z-O3I A 30 y 

Final Volume: a_5__,,-t L 

Storage Location : A57o 

Final Concentration: 

I:xpiration Date : 1-/-)-7-/3 

Reviewed by : `4 U e& 1~I Tll ~Z. 

Signaturo, Date 
Date: /0 

Analyst: JL J F 

SINGLE COMPONENT PREPARATION LOG 

Description: 

- 

PY' /~Jt7 S'/TVGIt 

Stock Number. C/!." oC100 

Weight or Volume 

Used: 01 11505 

Concentration or 

Purity: 9,3 .()20 

Corrected Weight 00 1 ' o( ll 

Final Volume. VtJm L 

Book No. 12009 

Page No. 113 

.pette 

ID(s}: _C~ 

Other Conec6'on Q G ..,, 

Factors: 0 ! i ~~ 

Solvent and TN -A a'd''" n ;~r'e 

4911'). 

Final Concentration:- - ~ L/ 1/90 

Number: !Z- 3A{ 

l 

Storage Location : /? ~ ~ QExpiration Date : yJ 

Reviewed by: 14 Al VI V 1 YLLI 1 01~'Jt) ) O2 

s~inaure~T- Date 
SINGLE COMPONENT PREPARATION LOG 

Date : / V ^ t' -~" /o~ 

Analyst TE 

Description: PFAII^t S')'(7L 1( 

Stock Number. . . _ TG f5, 11 4030 

Weight or Volume 

Used : 0. 109.15,, 

Book No. 12009 

Page No. 114 

ipette 

ID(s): ~ 

Concentration or 

Purity : 99. &a `o Other Correction o, ~y' 

Factors: ©. ~1 i b 

Solvent andTN-A ~~'~' " 

Corrected Weight : O. 10 269 ~ Number. 119) i, 

Final Volume : a5 ML Final Concentration: y350 

Storage Location : /°`! 5 lO Expiration Date: 

`~" 1'~^ 1 ~ 

Reviewed by: '~(/l1~ V1rV-/ to ~ 

it ' 

Signature, Date 
SINGLE COMPONENT PREPARATION LOG 

Date : 

Analyst: 

/0-»- /a 

h .t FDescription: 0Y' L.JI'7 -f1yGl 

Stock Number. I G R-d3rlJ 

Book No. 12009 

Page No. 115 

WeightorVolume .~7 Balance ipette 

Used: 0 " ~ ~~n( G ID(s): ~ 

Concentration or n '-7 I L1 G) Other Correction 

Purity: 

Corrected Weight: l./ , 1 C9 6,55 

a n - / 

Number : TIlJ17 ^ 03l 0`2 3 ~J 

Final Volume: a : ~ M '-~ Final Concentration: 5a5r~ M L 

Storage Location: /"I S ~ 0 Expiration Date : `7- )~^ j 3 

Factors : © . 1 

Solvent d TN A r ce~n Im ItsReviewed by: YLpA`V1 V\`", ,O1^' I 

Slgnatll , Dale 
SINGLE COMPONENT PREPARATION LOG 

Date: / (/ - ) / - /a Book No. 12009 

Analyst: ~ 

Description: /" f uyt /-7 ,,J49('~ 

Stock NumberTC I'\ l I "U` 03 I 

Weight or Volume © 

Used: 

Page No. 116 

Pipette 

ID(s): ~ 

Concentration or Q/~ C( O~

(~ 

Other Correction 

Purity : . _ / f(J . tJ / Factors : 0,99~ 

Corrected Weight: ©,© ~~ g ~ ~ 

Solvent and 

A 1V! G- 3 );R ~ 34) 

Final Volume: 

Storage Location : 

a5mL 

A 5-7O 

Final Concentration: 

Expiration Date: 

yo©o 

I/ -j 

Reviewed by : _ 4 M 4 6/1-~ 1O V

9aD' 

r

. 

Signature, Date 
Date: /0-/-7-1 rS 

Analyst: ,IL J F - 

SINGLE COMPONENT PREPARATION LOG 

Description: T' r' a6> F'i S~J( 

Stock Number: 

Weight or Volume 2~, Balance, ipette 

Used: ©~ « ~7 1 ~ ID(s): 

Concentratlon or Other Correctioq 

Purity: I ! r / I 0/10 Factors: 

Book No. 12009 

Page No. 117 

9J `7 

©"-. .1_._l-q]_ 

67 , 

~^ Solvent and TN-A~ ' w"~n r 

Corrected Weight: ~ of rx~ A Number. -TfV I'd - U3~~ 3~`'I 

Final Volume : ol J w1 L Final Concentration: ~ ( o( V /, 

Storage Location : A S-7o Expiration Date: '7 " ~~" ) 3 

Reviewed by: /11Il~ Vl /-eJ 1 ~ ) /u 1f 2 

Signature, Date 
Date : 

Analyst: 

10- 1-7- IQ 

KS FSINGLE COMPONENT PREPARATION LOG 

Description: P FT~ A It 

Stock Number: ' l 0 co . 1 

Weight or Volume / 

Used: ~ ~ 0 tp ID(s): 

pate 

Book No. 12009 

Page No. 118 

Concentration or (~ 1 ^y Other Correction qU~/ 

Purity: ~ 1 r i Factors: ©. 1 I p 

Corrected Weight : tJ Id p~ 

Solvent and 

`

~

r'/l~ 1 ~~ ~U31 

Final Volume : Final Concentration: !"~f/650 ,(,q /t,-t L 

Storage Location: /-15 -70 Expiration Date: //-1-7-13 

Reviewed by : L4 u ` F'UJ 10 1 iv 11 1, Signature, Date 
SINGLE COMPONENT PREPARATION LOG 

Date: j V - ) -7 ^ /9, 

Analyst: Ka FDescriptlon: PF6S 54-eJ< 

Stock Number. T c- R ` r d I 

Book No. 12009 

Page No. 119 

Weight or Volume ~r . 'O ~ J©~ 'BalahcelPi 

Used : 1 7 D(s) 9 11 

Concentration or 

Purity: I(p . / /D 

Corrected Weight © V a g 010:5 

Final Volume : 

Other Correction © ~ C/ fr 

Factors: 

Solvent andTN-A /`Tw' "'h,"' 1e 

Number: TjV ~A -^ l73 I'a N'-/ 

Final Concentration : 

3SGO .L(4 l Wl 1^ 

Storage Location : YJ 5-70 Expiration Date : '7' /-7- 

Reviewed by: C D lt l vt V1 W4 t~ l %o I 

SignaYure, oate 
Date: 

Analyst: 

i©- 1-7- ia. 

1(J iSINGLE COMPONENT PREPARATION LOG 

Description: L-PF95 540~, l< 

Stock Number: T~ ~ I a - d ~ ~ ~ 

Book No. 12009 

Page No. 120 

Weight or Volume © 

/0,3S ~ alance/ pette '^-~ 

Used: ID(s): 

Concentration or ~,(~ ~] ~'7 Other Correction 

Purity : _ / 1 -p /0 Factors: ~" 1 -1 tlJ 

Corrected Weight: ©,09~a~ ~ 

SolventaNumber

: I/U~ot"r03~p~ 3~/ 

Final Volume: aSmZ Final Concentration: /iV/ L 

Storage Location: A 670 Expiration Date : '~) ` ! 5 

~ VQIL,e ce.l c,l -,-leX ctsryj~- TOO pf~'~'y ~,Cao~r~~ -l~ 60 P. 

® nC 

Reviewed by" 1"L \I~ u.", I0,g

Signeture, Date 
SINGLE COMPONENT PREPARATION LOG 

Date : 

Analyst: 

I(~ ~ '7~! 

ILJ E 

Description: F8SA ._5Gk 

Book No. 12009 

Page No. 121 

Stock Number. -T('9 -L141 

Weight or Volume ,, 

Used: ~ 

ConcentraUon or 

Purity: C1 -1 .S /O 

Corrected Weight: O 

Final Volume: 05 to, L 

Storage Location : 

Other Correction 

Factors: v" 1 I / 

Solvent and TN-A f'y a'6AJ"Ie 

Number: TN1Z"D3to'L 34) 

Final Concentration: 

Expiration Date: 

~~13d~~L 

Reviewed by: 'K A U W`-t;.6 W~611-2 

Signature, ate 
SINGLE COMPONENT PREPARATION LOG 

Date: /©"l-7^t9 Book No. 12009 

Analyst -93. F - 

Description: 5-izO( 

StockNumber.-_.I GK-v2 Uv 

Weight or Volume © . ' 

Used: 

ipette 

ID(s) : 

Concentration or qC[ 2, Other Correction 

Purity : ' I O, ~ w Factors: 

Page No. 122 

D.g9(~ 

~r 2 Solvent andTN-A A~'"rt'~t" 

Corrected Weight : ©, 1o( IU--~ A Number. TIl7)7-^03l ~ SJ~~/ 

Final Volume : oC:J M L' Final Concentration: 

Storage Location : A5-70 Expiration Date : 

5o50 14 Jm L 

Reviewed by: ~'~ I,~ ~ `01301/2 

Sign-at re. 

I~.~

° ate 
AnalyticalInstrument Data 

and 

Data Reduction Calculations 
p. 25 

MULTI-COMPONENT PREPARATION LOG 

Book No. 12008 

Page No. 34 

Description: ~L /' I I~ Solvent: AIIIl AL~ 

Date Prepared : 11 I b I i~J 3M Tra~ #e -_ti r T / 1 7 

Prepared By: Expiration Date : . ~ ti ~ 1 ?~ 

Storage Location : I P9-0\ _- Pipette IDs: a +-,gai AtL 

'Expiration Date: 31251 1?) - 

Standard ID # 12008-34 

Component Standard Corrected Final Concentration 

Description ID # Cone. or 

Purity 

Expiration 

Date 

Weight or 

Volume Balance ID 

Weight 

~'~6 >a - R

i~~+uh 

12oo°I-Iq~ ~21Uh9Imt . 5~e113 ),m L `- - JT' o5 , 

pFO~- s'qm° 

1 d-v r(/t" 

~Zoaq-lqa ~low9~n~ 5~b~i~, 3.7-m L - - 5o o 

~98 

lAh 1200q-120 ~AImL 31261 13 ~J .ZmC ~ - 

~ i 1/ A Jb1JM-101 UAIm L `l ~~~~~ 3.1 r;i L - 50 3 

r-r Z 

\ 

Final Volume r 

2;~1ML 

~ 

Approximate 

Concentration of the mix 

I 

Reviewed by: 

Signature, Date 
Date: ~ ~ IZ Book No. 72009 

Page No. 202 

Analyst, -~ 

Description: 

SINGLE COMPONENT PREPARATION LOG 

Fc, 14~it1 ~1r11~r~ 

Stock Number: IT 0 0(b- 2z"1 

Weight or Volume ~7 Irn L Balance 

Used: 

Concentration or ~ O Other Correction 

Purity: 'J V ;Gl .q' I ,n G Factors: 

211241~2 

Solvent and TN-A 

Corrected Weight -~ Number. /A ! I I I!?-- Wa ke- TN I 2 

Final Volume : Final Concentration : 

Storage Location : Vj le-0 , Expiration Date : ;! 2 

Reviewed by; 
Date: 

Analyst: 

1l ~ 12 

SINGLE COMPONENT PREPARATION LOG 

Description : Y1lo1k SiOt(l'Ik AlxYIC/t'-' 

Stock Number: ~ w",~ ~ b 42 ~ ~ 

1 I I 

Weight or Volume . I 

Used: (J 

Concentration or 

Purity: 

Corrected Weight: 

9l0 ~q w 

Book No. 12009 

Page No. 195 

O .lu~~oil 

Final Volume: 1~ PYI ~- 

StorageLocation: A9 I v 

Other Correction q69 

Factors: a 

Solvent and TN-A 

Number. 

Final Concentration : ~21U~9fmL. 

Expiration Date : 5 I tP 20 I b 

Reviewed 
Date : 

Analyst: 

SINGLE COMPONENT PREPARATION LOG 

K ~ti 

Description: ~ ~ 61- FC AI 1( 

Stock Number. I -)- ( )ni, - :2.-? 

Book No. 120D9 

Page No. 133 

Weight orVolume n ,f m ~ 0614j".(~ 

Used : / a 

Concentration or Other Correction 

Purity: afkl I/YI L Factors: 

Corrected Weight : 

Final Volume: 7 6 vi L 

Storage Location : 

Solvent and TN-A 

Number: PC1J 'TN12'(1/h12.'314 

Final Concentration : ~ ~ . a ,1,-- (t"I C 

Expiration Date: 

Reviewed by: ft1f IA~p.AahChBW 1023"-2-

signature, Date 
SINGLE COMPONENT PREPARATION LOG 

Date: ---) ~) I 2M I 1'L. Book No. 12009 

Page No. 134 

Analyst : - ~_ _ 

Descriptlon: (5 . I ,(i. . q I M L en M I q 

Stock Number I ~, 0 0 Ll - W7j 

1 

vveigm or veiume ,! F3alance/P~ 

Used: Z . 6 r~ L I~ls): 10 11 

Concentration or 

L 

Other Correction 

Pudty: 1 D,U 9 )m Factors: 

Corrected Weight : 

Final Volume: 25 YVI L 

Solvent and TN-A 

Number. AC-1J - TN t2-0312-3I4 

Final Concentration :-0 -~-,ot q I Vdi L 

Storage Location : A6' Expira6onDate: A .2~; I20 1 " / 

Reviewed by: l,,Gll .tGdl"t'/JLg&1A1J %0123117-

signature, Date 
p. 30 

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p. 31 

-Buster : J2930203 Batch Name : 

Froject:\\usfile01\B2\Projects\Lab_InstrumentDala\Buster\BuslerData\FYojects\GLPIO-01-01-39Batch :b121221a Tab:Sample SetISET1 AcqMethod :PFOAonly 750uLflow . 

Sample 

Sample Name Sample ID Vial Position Data File Inj .Volume (pl) Comments 

t 

b121221a001 Solvent Blank 91 b121221a 10.000 Mill QWater TN12-0421 

b121221a002 Solvent Blank 91 b121221a 10.000 Mill QWater TN12-0421 

3 b121221003 Solvent Blank 91 b121221a 10.000 Mill 0 Water TM 2-0421 

4 b121221404 12011-30-8 8 b121221a 10.000 1 .0 ng/ml-FC std in Mlli Q Water 

5 b121221005 12011-30-8 8 b121221a 10.000 1 .0 ng/mL FC std in Milli Q Water 

6 b121221a006 12011 " 30-8 8 b121221a 10.000 1 .0 ng/mL FCstd In Mill Q Water 

7 b121221007 12011-30-8 8 b121221a 10 .000 1 .0 ng/mL FCstd in Ivilli Q Water 

8 b121221a008 Solvent Blank 91 b121221 a 10.000 Mill Q Water TN12-0421 

9 b121221a009 Solvent Blank 92 b121221a 10 .000 Mill Q Water TN72-0421 

10 b121221a010 12011 "30-1 1 b121221a 10 .000 0.025 ng/mL FCstd in Mlli Q Water 

11 b121221a011 12011-30-2 2 b121221a 10 .000 0.03 ng/M- PC std in Mill Q Water \ 

12 6121221a012 12011-30-3 3 b121221a 10 .000 0.04 ng/rr1 PC std in Mill Q Water 

i 13 b121221a013 12011-30-4 4 b121221a 10 .000 0.05 ng/mL PC std in Mill Q Water f 

14 b121221a014 12011-30-5 5 b121221a 10 .000 0.1 ng/mL FCstd in Mlh Q Water 

15 b121221a015 12011-30-6 6 b121221a 10 .000 0.25 ng/mL PC std in Milt Q Water 

16 . b121221a016 12011 "30-7 7 b121221a 10 .000 0.5 ng/mL FCstd in N1111 0 Water 

17 b121221a017 12011-30-8 8 b121221a 10 .000 1 .0 ng/mL FCstd in Mill Q Water 

18 b121221018 12011-30-9 9 b121221a 10 .000 2 .5 ng/mL FC std in Mlli Q Water 

19 b121221a019 12011-30-10 10 b121221a 10 .000 5.0 ng/mL FCstd In Mill Q Water 

20 b121221020 12011-30-11 11 b121221a 10 .000 10 ng/mL FC std in Mill Q Water r 

21 ' 6121221a021 12011-30-12 12 b121221a 10 .000 25 ng/rnL FC std in Mill Q Water ', 

22 , b121221a022 12011-30-13 13 b121221a 10 .000 50 ng/n-L PC std in Mill 0 Water 

23 b121221a023 12011-30-14 14 b121221a 10 .000 75 ng/rrL FC std in Mill Q Water 

24 b121221aO24 12011-30-15 16 b1212211a 10 .000 100 ng/n'L FC std in Mill Q Water 

25 b121221025 Solvent Blank 92 bl 21221 a 1 10 .000 Mill Q Water TM 2-0421 

26 b121221aO26 Solvent Blank 92 b121221a 0. ater - 

R 

27 b121221aO27 Solvent Blank 93 b121221a 10 .000 Mill Q Water TN1 2-0421 

1 

a 8 

b121221028 

0 

1 

Solvent Blank 93 b121221a a r 

1 

1, 

9 

b 

1 

2 22 02 LCS-121220-1 16 b121221a 10 .000 0.5ppb LCS 

b 

1 

1 

1121221030 LCS-121220-2 17 b121221a 10.000 0.5ppb LCS 

31 b121221a031 LCS-121220-3 18 b121221a 10.000 0.5ppb LCS 

32 b121221a032 LCS-121220-4 19 b121221a 10.000 5ppb LCS 

33 b121221a033 LCS-121220-5 20 6121221a 10.000 5ppb LCS 

34 b121221a034 LCS-121220-6 21 b121221a 10.000 5ppb LCS 

35 - b121221a035 LCS-121220-7 22 b121221a 10.000 30ppb LCS 

36 , b121221a036 LCS-121220-8 23 b121221a 10.000 30ppb LCS 

37 b121221a037 LCS-121220-9 24 b121221a 10.000 30ppb LCS 

38 b121221a038 Solvent Blank 93 b121221a 10.000 Mill Q Water TN12-0421 

39 ~ b121221a039 Solvent Blank 94 b121221a 10.000 Mill! Q Water TM 2-0421 

40 b121221040 12011-30-9 9 b121221a 10.000 2.Sng/mLFCstdinMill Qwater 

41 b121221a041 Solvent Blank 94 b121221a 10.000 Mill Q Water TM 2-0421 

42 1>121221042 GLP10-01-01-39" 070 25 b121221a 10.000 DAL-GW-131S-RB43 1>121221043 GLP10-01-01-39" 071 26 b121221a 10.000 DAL-GW-145R-RB44 b121221a044 GLP10-01-01-39-072 27 6121221a 10.000 DAL-GW-TPoP01 "0- 

45 b121221a045 GLP10-01-01-39-073 28 b121221a 10.000 DAL-GW-TPoF01-LS48 b121221a046 GLP10-01-01-39-074 29 b121221a 10.000 DAL-GW-TFUF01-MS47 b121221a047 GLPIO-01-01-39-075 30 6121221a 10.000 DAL-GW-TRIF01-HS " 

48 b121221048 GLP10-09-01-39-001 31 b121221a 10.000 DAL-GW-130R-0- 

49 b121221a049 GLP10-01-01-39-002 32 b121221a 10.000 DAL-GW-130R-DB50 b121221a050 Solvent Blank 94 b121221a 10.000 Mill Q Water TM 2-0421 

51 b121221a051 12011-30-8 8 b121221a 10.000 1 .Ong/mLFCsldinMill Qwater 

52 b121221a052 Solvent Blank 95 b121221a 10.000 Mill Q Water TN12-0421 

53 b121221a053 GLP10-01-01-39-003 33 b121221a 10.000 DAL-GW-130S-0- 

54 b121221a054 GLP10-01-01-39-004 34 b121221a 10.000 DAL-GW-130S-DB55 b121221a055 GLP10-01-01-39-005 35 b121221a 10.000 DAL-GW-130S-FMS56 b121221056 GLP10-01-01-39-006 36 1>121221a 10.000 DAL-GW-130L-0- 

b121221a057 GLP10-01 " 01-39-007 37 b121221a 10.000 DAL-GW-130L-DBb121221a058 GLPIO-01-01-39-008 38 b121221a 10.000 DAL-GW-131R-0- 

b121221a059 GLP10-01-01-39-009 39 )121221a 10.000 DAL-GW-131R-D6- .- ._ 

80 1>121221a060 GLP10-01-01-39-010 40 b121221a 1 0.000 DAL-GW-1318-0- 

Data printed by CJG Page 1 of 3 

Printing Time : 12 :49 :59 PM 

Printing Date : Friday, December 21, 2012 
p. 32 

-Buster : J2930203 Batch Name : 

Project: \\usfile0l\82\Projects\Lab InstrumentData\Buster\BusterData\Frojects\GLPIG-01-01-398atch :bi21221a Tab:Sanple SeI :SET1 AcqMethod :PFOAonly 750uLflow 

Sample 

Sample Name Sample ID VIaIPositlon DataFile Inj .Volume (pl) Comments 

61 b121221a061 GLPIO-01-01-39-011 41 b121 221a 10 .000 DA L-GW-131S-DB62 b121221a062 GLP10-01-01-39-012 42 b121221a 10 .000 DAL-GW-131S-FMS- . 

63 b121221a063 Solvent Blank 95 b121221a 10 .000 k411i Q Water TN12-0421 

64 b121221a064 12011-30-10 10 b121221a 10 .000 5 .0 ng/mL FCstd in Iv511i Q Water 

65 b121221a065 Solvent Blank 96 b121221a 10 .000 AkIliQWater TN12-0421 

66 b121221a066 GLPIO-01-01-39-013 43 6121221a 10 .000 IML-GW-131L-0- 

67' b121221a067 GLP10-01-01-39-014 44 1:121221a 10 .000 DAL-GW-131L-DB68 b121221a068 GLP10-01-01-39-015 45 b121221a 10.000 DAL-GW-133R 0- 

69 b121221a069 GLP10-01-01-39-016 46 b121221a 10 .000 DAL-GW-133R DB70 b121221a070 GLP10-01-01-39-017 47 b121221a 10 .000 DAL-GW-133S-0- 

71 b1212218071 GLPIO-01-01-39-018 48 b121221a 10 .000 DAL-GW-133S-DB72 b121221a072 GLP10-01-01-39-019 49 b121221a 10 .000 DAL-GW-133L-0- 

73 b121221a073 GLP10-01-01-39-020 50 b121221a 10 .000 DAL-GW-133L-mB74 b121221074 GLP10-01-01-39-021 51 b121221a 10 .000 DAL-GW-134R-0- 

75 b121221a075 GLP10-01-01-39-022 52 b121221a 10 .000 DAL-GW-13412DB76 b121221a076 Solvent Blank 96 b121221a 10 .000 kklli Q Water TN1 2.0421 

77 b121221a077 12011-30-9 9 b121221a 10 .000 2 .5 ng/mL FCstd in IvSlli Q Water 

78 b121221a078 Solvent Blank 97 b121221a 10 .000 MiIIiQWater TN12-0421 

79, b121221a079 GLP10-01-01-39-023 53 b121221a 10 .000 DAL-GW-134S-0- 

80 b121221a080 GLPIO-01-01-39-024 54 6121221a 10 .000 DAL-GW-134S-DB81 b121221a081 GLPIO-01-01-39-025 55 b121221a 10 .000 DAL-GW-134L-0- 

82 b121221a082 GLP10-01-01-39-026 56 b121221a 10.000 DAL-GW-134L-DB83 b121221a083 GLP10-01-01-39-027 57 b121221a 10.000 DAL-GW-135R-0- 

84 b121221a084 GLP10-01-01-39-028 58 b121221a 10.000 DAL-GW-135R-DB85 b121221a085 GLPIO-01-01-39- 29 59 b121221a 10.000 DAL-GW-135S-0- 

86 b121221a086 GLP10-01-01-39-030 60 b121221a 10.000 DAL-GW-135S-DB87 b121221a087 GLP10-01-01-39-031 61 b121221a 10.000 DAL-GW-135L-0- 

88 b121221a088 GLP10-01-01-39-032 62 b121221a 10.000 DAL-GW-135L-DB- _ 

89 b121221a089 Solvent Blank 97 b121221a 10.000 Mill Q Water TN12-0421 . 

90 b121221a090 12011-30-9 9 b121221a 10 .000 2.5ng/rH-FCstdinMIliQWater 

91 b121221a091 Solvent Blank 98 b121221a 10 .000 Iv511i Q Water TN12-0421 

92 b121221a092 GLP10-01-01-39-035 63 b121221a 10 .000 DAL-GW-136S-0- 

93 b121221a093 GLP10-01-01-39-036 64 6121221a 10 .000 DAL-GW-136S-DB94 b121221a094 GLP10-01-01-39-037 65 b121221a 10 .000 DAL-GW-136S-FMS95 b121221a095 GLPIO-01-01-39-038 66 b121221a 10 .000 DAL-GW-136L-0- 

96 b121221a096 GLP10-01-01-39-039 67 b121221a 10 .000 DAL-GW-136L-DB97 b121221a097 GLP10-01-01-39-042 68 b121221a 10 .000 DAL-GW-137S-0- 

98 b121221a098 GLP10-01-01-39-043 69 b121221a 10 .000 DAL-GW-137S-DB99 b121221a099 GLP10-01-01-39-044 70 b121221a 10 .000 DAL-GW-137S-FMS100 b121221a100 GLP10-01-01-39-045 71 b121221a 10 .000 DAL-GW-137L-0- 

101 b121221a101 GLP10-01-01-39-046 72 b121221a 10 .000 DAL-GW-137L-DB102 b121221a102 Solvent Blank 98 b121221a 10.000 MiIliQWater TN12-0421 

103 b121221 a103 12011-30-10 10 b121221a 10 .000 5 .0 ng/mL FC std in Iv511i Q Water 

104 b121221a104 Solvent Blank 99 b121221a 10.000 MiIliQWater TN12-0421 

105 b121221a105 GLP10-01-01-39-049 73 b121221a 10.000 DAL-GW-138S-0- 

106 b121221a106 GLP10-01-01-39-050 74 b121221a 10.000 DAL-GW-138S-DB- ' 

107 b121221a107 GLP10-01-01-39-051 75 b121221a 10.000 DAL-GW-138L-0- 

108 b121221a108 GLP10-01-01-39-052 76 b121221a 10.000 DAL-GW-138L-DB- . 

109 b121221a109 GLPIO-01-01-39-053 77 b121221a 10.000 DAL-GW-CW26G0- 

110 b121221a110 GLPIO-01-01-39-054 78 b121221a 10.000 DAL-GW-CW26C-DB111 b121221a111 GLPIO-01-01-39-055 79 b121221a 10.000 Q4L-GW-CW26L-0- 

'112 6121221a112 GLP10-01-01-39-056 80 b121221a 10.000 DAL-GW-CW26L-D& 

113 b121221a113 GLPIO-01-0139-057 81 b121221a 10.000 DAL-GW-140R-0- 

j114 b121221a114 GLP10-01-01-39-058 82 b121221a 10.000 DAL-GW-140R-DB- 

.115 b121221a115 Solvent Blank 99 b121221a 10.000 Mill QWater TN12-0421 

716 b121221a116 12011-30-8 8 b121221a 10.000 1 .0 ng/rnL FCstd in Iv511i Q Water 

117 b121221a117 Solvent Blank 100 b121221a 10.000 NLIIiQWaterTN12-0421 - 

118 b121221a118 GLP10-01-01-39-059 83 b121221a 10 .000 DAL-GW-141R-0- 

119 b121221a119 GLP10-01-01-39-060 84 b121221a 10.000 DAL-GW-141R-DB12 0 I b12 122 1a 120 I GLPI0-01-01-39-061 85 b121221a 10 .000 DAL-GW-141R-FMS- 

)ata printed by CJG Page 2 of 3 

?rinting Time : 12 :44 :59 PM 

?rinting Date ; Friday, December 21, 2012 
p. 33 

-Buster : J2930203 Batch Name : 

Roject: \\usfile0l\82\Ftojects\Lab_Instrument Data\Buster\Buster Data\Projects\GLP10-01-01-39 Batch:b121221a Tab:Savple SetSET1 AcqMethod :PFOA only 75OuLflow . 

Sarnple 

Sample Name Sample ID Vial Position Data File Inj .Volume (pl) Comments 

ly21221aI21 GLP10-01-01-39-062 86 IA211221a 10 .000 DAL-GW-142R-0- 

b121221a122 GLPIO-01-01-39-063 87 b121221a 10 .000 DAL-GW-142R-DBE 1233 y121221laI23 GLPIO-01-01-39-067 88 b121221a 10 .000 DAL-GW-145PO124 b121221a124 GLPIO-01-01-39-068 89 y121221a 10 .000 DAL-GW-14SR-DB125 b121221a125 GLP10-01-01-39-069 90 b121221a 10 .000 DAL-GW-145R-FlvS126 b1211221a126 Solvent Blank 100 b121221a 10 .000 M11i Q Water TN1 2-0421 

127 b1211221a127 12011-30-11 11 b121221a 10 .000 1 0 ng/niL FC std in Milli 0 Water 

128 P2122U128 Polvent Blank 91 b121221a 10.000 NTlli 0 Water TN12-0421 

Data printed by CJG Page 3 of 3 

Printing Time : 12 :4a :59 PM 

Printing Date : Friday, December 21, 2012 
-BUster : J2930203 Batch Name : N/A 

Acqasition Infovnetion : 

isitim Method : pF(1A only 7500L f1cw .dem 

ted : FYidsy DECEVbec 21 2012 10 : 51 : 00 PM 

hkrlified : Friday IY. .ce:b3 21 2012 12 : 42 : 53 1M 

wument : peox only 

6ynrlumizetion Mode : lc sync 

Auto-Ei7silibmtirn : Off 

Acquisition Duration : l9min0sec 

N,rt= of Scars: 3619 

HSS(rle In File : 1 

Acquisition Nmdile : Acquisition hktknd 

Software versiam Analyst 1 .6 .1 

Pgilent LC Pwp Method arpert ies 

Pump tnxel: Agilent 1100 LC Bunry Rnp 

Minimum Freesuae (Fei) : 0 .0 

hsrzimn : Pxessme (pei) : 5801 .0 

Dead Volume (wl) : 40 .0 

Ywdmm Flow Ranp (ml/mixY) : 100 .0 

h9ximm P~ Ramp (psi/ss) : 290.0 

vex Flow Ramp Up (ml/min') : 100.0 

hEx Flow Barcp Ih (ml/min') : 100.0 

Step Table: 

Star Total 7Lm(min) Flow ,Rate (Wl/min) A (&) B ($) 

C 0 .00 750 90 .0 10 .0 

1 0 .50 750 90 .0 10 .0 

2 4 .00 750 70 .0 30 .0 

3 6 .00 750 70 .0 30 .0 

4 11 .00 750 20 .0 80 .0 

13 .00 750 20 .0 80 .0 

6 13 .50 750 10 .0 90 .0 

7 16 .00 750 10 .0 90 .0 

8 16 .50 750 90 .0 10 .0 

9 19 .00 750 90 .0 10 .0 

Left CarpttPssibility : 50 .0 

Right Qaipxeeslbility : 115 .0 

Left Dead Volume (MI) : 40 .0 

Dead Volume (p1) : 40 .0 

t Stroke Volume ()al) : -1 0 

~ Stroke Volume (N1) : -1 .0 

i 

t Solvent : A1 

Right Sol~vent : Bl " 

Fgilent Autcsaupler PaOPEWties 

Autassnpler Ncrlel : Agitent 1100 viemo Auto-canpler 

Syringe Size (al.) : 100 

mjecticn Volume ((tl) : 10 .00 

Draw Speed (yl/min) : 200 .0 

aject speed (Al/min) : 200 .0 

Needle level On) : 0.00 

1H:pevadue amtrol Not used 

Wash is rot uSed 

Use custom Inject= pt0.7tart Pb 

Agilent Column Oven Properties 

Left 7Hr[r-taturze (°C) : 30 .00 

Right 'la~pe .attrze (°C) : 30 .00 

1tr:pPlatlrte Tolerance +/- (00 : 1 .00 

Start Acaluisitim Tolerance +/- (*C) : 0 .50 

Tim Table (Used) 

Om1um switching Valve Installed DEN 

Position for first sample in the batch ; Right 

Use same, position for all ssrtples in the batch 

Total Tim (min) Valve Position 

0 .0C Left 

5 .OC Right 

Period I; 

-------------- 

Scans in period ; 3619 

Relative Start Tim; 0 .00 rreec 

its in Fexiod: 1 

Data printed by CJG Page 1 of 2 

Printing Time : 12 :43 :58 PM 

Printing Date : Friday, December 21, 2012 
-Buster : J2930203 

Sdhedu1ed Mdwt : NJ 

Fblarity : Nagative 

Stan [+a3e : N/A 

IM Sasce: Tunoo Spray 

Resolution Ql : unit 

Resolution Q3 : Unit 

Intensity 7hres . : 0 .00 cps 

Sett,ling Tim: 0 .0000 Irsec 

hR Pause : 5 .0070 rteec 

M7: : NO 

Step sin: 0 .00 lti 

Q1 Ness (19) Q3 M75.5 (I8.) Dsell(rreec) F9rart Start Stcg IL 

433 .000 369 .000 100 .00 a -14 .00 -14 .00 PbTY-1 

CKP -9 .00 -9 .00 

Ql Mass (7s) 43 hbs.s (W) Dwell (rtezC) FBYNr Start StoF IL 

413 .000 219 .000 100 .00 CE -24 .00 -24 .00 PFIIA-2 

CXf -15 .00 -15 .00 

Ql mass (Da) Q3 Mass (L9) Di.e11(nGec) Ruav Start Stg I 

417 .000 169 .000 100 .00 CE -28 .00 -28 .00 PFQ'r3 

(92= -9 .00 -9 .00 

Parameter Table(L72io3 I Experiment 1) 

CAD : 6 .00 

QIIi : 35 .00 

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p. 42 

Printing Date and Time: 

4/29/2013; 1 :01 PM 

Regressions 

Peak Name: PFOA 

No Internal Standard 

Q1/Q3 Masses: 413.00/369 .00, 413.00/219.00, 413.00/169 .00 Da 

Fit Quadratic Weighting 1 / x Iterate No 

a0 1 .78E+04 

a1 7.88E+05 

a2 -4.38E+03 

Correlation coefficient 0.9993 

Use Area 

Curve fit criteria r> 0.994987437 

b121221a.xls Regressions Page 4 of 13 
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p. 45 

Printing Date and Time; 

4/29/2013; 1 :01 PM 

Method Blanks 

PFOA 

Sem eName Sem elD Sample Comment Am Counts 

b121221a001 Solvent Blank MIIIIQWater TN12-0421 - 342969 

6121221a002 Solvent Blank MIIIIQWater TN12-0421 131558 

6121221a003 Solvent Blank MIIIIQWater TN12-0421 48937 

6121221a008 SoNentBlank MIIIIQWater TN12-0421 4960 

b121221a009 Solvent Blank MIIIIQWater TN12-0421 5965 

b121221a025 Solvent Blank MIIIIQWater TN12-0421 4642 

b121221a028 Solvent Blank MIIIIQWater TN12-0421 1575 

b121221a027 Solvent Blank MIIIIQWater TN12-0421 5162 

b121221a028 Solvent Blank MIIIIQWater TN12-0421 3846 

b121221a038 Solvent Blank MIIIIQWater TN12-0421 2702 

b121221a039 Solvent Blank MIIIIQWater TN12-0421 4201 

b121221e041 Solvent Blank Milli Q Water TN12-0421 3939 

b121221a050 Solvent Blank Milli Q Water TN12-0421 2911 

b121221a052 Solvent Blank Milli Q Water TN12-0421 3724 

b121221a063 Solvent Blank Milli Q Water TN12-0421 1499 

6121221e065 Solvent Blank Milli Q Water TN12-0421 3168 

6121221a076 Solvent Blank MIIIIQWater TN12-0421 4288 

b121221a078 Solvent Blank MIIIIQWater TN12-0421 3722 

b121221a089 Solvent Blank MIIIIQWater TN12-0421 4562 

b121221a091 Solvent Blank MIIIIQWater TN12-0421 6002 

6121221a102 Solvent Blank MIIIIQWater TN12-0421 3289 

b121221a104 Solvent Blank MIIIIQWater TN12-0421 3524 

b121221a115 Solvent Blank MIIIIQWater TN12-0421 5041 

b121221a117 Solvent Blank MIIIIQWater TN12-0421 5403 

b121221a126 Solvent Blank MIIIIQWater TN12-0421 3103 

b121221a128 Solvent Blank MIIIIQWater TN12-0421 5133 

Average Area Counts of Method Blanks I 4015 I 

%RSD 30 

Average Area Counts of Method Blanks Multiplied by TM 8030 _ 

LOO Standard area counts 39845 

LOQ standard conc., ngfmL 0.0240 

vlann up blank- not used for LOQ detenninatian 

vann up blank- not used for LOO determination 

warm up blank- not used for LOQ determination 

b121221a.xls Method Blanks Page 7 of 13 
p. 46 

Printing Date and Time 

4/29/2013; 1 :01 PM 

LCS Recoveries 

Spiked 

Sample Conc. Calc. Conc. 

Name Sample ID Sample Comment (ng/mL) (ng/mL) %Rec. Set average RSD 

612~29 LCS-121220-1 0.5ppb LCS 

b121221a030 LCS-121220-2 0.5ppb LCS 

b121221a031 LCS-121220-3 0.5 b LCS 

b121221a032 LCS-121220-4 5ppb LCS 

b121221a033 LCS-121220-5 5ppb LCS 

b121221a034 LCS-121220-6 5 b LCS 

b121221a035 LCS-121220-7 30ppb LCS 

b121221a036 LCS-121220-8 30ppb LCS 

b121221a037 LCS-121220-9 30ppb LCS 

0.477 0.459 96.1 

0.477 0.448 93.9 

0.477 0.462 96.9 

4.77 4.84 102 

4.77 4.90 103 

4.77 4.89 103 

28.7 I 26.3 1 91 .6 

28.7 24.7 86.1 

28.7 25.2 87.9 

Overall Average 95.8 

%RSD I 6.6 

PFOA 

95.6 1 .6 

103 0.56 

88.5 3.2 

b121221a.xls LCS Page 8 of 13 
p. 47 

Pdntlng Date and Time 

4/29/2013; 1 :01 PM 

Sample Result with QC 

NC v Not Calculated; Endogenous sample greater than 2x spike level 

Dataflle 

b121221a042 

6121221a043 

Dilution 

1 

1 

GLP10-01-01-39 Rlnseate Blanks PFOA 

Conc. FMS 

3MOMS ID Sample Des,In (ng/mL) %Recovery 

GLP10-O1-01-39-070 DAL-GW-131S-R6- <0.0240 NA 

GLP10-Ot-01-39-071 DAL-GW-145R"RB- ~0.0240 _ NA 

Datafile 

b121221a048 

b121221a049 

Average 770 

%RPD 4.9 

Dilution 

6121221a053 10 

b121221a054 10 

b121221a055 10 

Avemge 148 

Field Mafdx Spike 101 

%RPD 1 .4 

Datafile Dilution 

b121221a056 10 

b121221a057 10 

Dilution 100 

100 

DAL GW 130R __ PFOA 

- ~ Conc. FMS 

3MOMSID Sample Description _ n /mL %Recove 

GLP10-01-01-39-001 DAL-GW" 130R-0- 

I 

_ _ 

751 

I 

NA 

GLP10-01-01-39-002 _ DAL-GW-130R-DB" 789 NA 

DAL G W 130S PFOA 

Conc. FMS 

3MOMS ID Sample Description (11 91,01L) YeRecove 

GLP70-Ot-01-39-003 DAL-GW-130S-0- 147 

_ 

NA 

GLP10-Ot-01-39-004 DAL-GW-130S-D& 149 NA 

GLP70-Oi-01-39-005 DAL" GW-130S-FMS- 221 72.3 

DAL GW 13oL _ PFOA - 

Cona FMS 

3MOMS ID Sample Description n /mL %Recove 

GLP10-01-01-39-006 DAL-OW-130L"00. 

I 

47.1 

I 

NA 

GLP10-01-Oi-39-007 DAL-GW-130L-DB- 52 .4 NA 

Average 49.8 

%RPD 11 

b121221a058 

Dilution 

100 

DAL GW 131R PFOA 

Conc, FMS 

3M UMS ID Sample Description n mL %Recov 

GLP10-01-01-39-008 DAL-GW-131R-0- 1590 I NA 

b121221a059 100 GLP10-01-01-39-009 DAL-GW-131R-DB- 1870 NA 

Average 1630 

%RPD 4.9 

Dilution 

b121221a060 1 

b121221a061 1 

b121221a062 10 

DAL OW 131S PFOA 

Conc. FMS 

3M LIMS ID Sample Description n mL %Recove 

GLP10-01-01-39-010 DAL-OW-131S-0- 24.1 NA 

GLP70-01-Oi"39-011 DAL-GW-131S-D& 24.1 NA 

GLP10-01-01-39-012 DAL-GW-131S-FMS- 40.7 82.2 

Avenge 24.1 

Field Mablx Spike 20.2 

%RPD 0.0 

Dilution 

1,121221a066 10 

1,121221a067 10 

DAL GW 131L PFOA 

Conc. 

_ 

FMS 

3MOMS ID Sample Description n mL %Recove 

GLPi0-01-01-39-013 DAL-GW-131L-0- 

I 

78.6 

I 

NA 

GL P10.01-01-39-014 DAL-GW-131L-DB- 76.0 NA 

Average 77.3 

%RPD 3.4 

Dilution 

b121221a068 10 

b121221a069 10 

DAL GW 133R PFOA 

Conc. - FMS 

3M LIMS ID Sample Description n /mL %Recov 

GLP70-01-01-39-015 j DAL-GW-133R-G- 

_ 

69.6 NA 

GLP10-01-01-39-016 DAL" GW-133R-DB- 65 NA 

Average 67.4 

%RPD 6.5 

b121221a.zls Sample Data WCC Page 9 of 13 
p. 48 

Pdn9ng Dale and Time 

4/29/2013;1 :01 PM 

Sample Result with OC 

NC =Not Calculated; Endagenous sample greater than 2x spike level 

Dilution 

b121221a070 10 

b121221a071 10 

DAL GW 133S PFOA - 

Cona FMS 

3M UMS ID Sample Description n ml %Recove _ 

GLP70-01-01-39-017 DAL-GW-133S-0- 309 NA 

GLP10-01-01-39-018 DAL-GW-133S-DB- 318 NA 

Average 314 

%RPD 2.9 

Dilution 

b121221a072 10 

b121221a073 10 

DAL GW 133L PFOA 

Cono. FMS 

3M UMS ID Sample Description n m %Recove _ 

(31-P10-01-011-39-1319 JUAL-UW-133L-U- 380 NA 

Average 380 

Y.RPD 0.0 

Dilution 

b121221a074 100 

b121221a075 100 

DAL GW 134R _PFOA 

Conc. FM 

3MLIMS ID Sample Description n mL °/.R ve 

GLP70-01-01-39-021 DAL-GW-134R-0- 1380 NA 

GLP10-01-01-39-022 DAL-GW-134R-DB- 1380 NA 

Avenge 1380 

%RPD 0 .0 

Dilution 

b121221a079 1 

b121221a080 1 

DAL GW 134S PF_OA 

Cona FMS 

3M UMS ID Sample Description n mL Y.R_ecove 

GLP10-01-01-39-023 DAL-GW-134S-0- 14.8 NA 

GLP10-01-01-39-024 DAL-GW-134S-DB- 13.9 NA 

Average 14 .4 

%RPD 6.3 

Dilution 

1,121221a081 100 

b121221a082 100 

DAL GW 134L PFOA 

Conc. FMS 

3MLIMS ID Sample Description n mL _ %Recove 

GLP10-01-01-39-025 DAL-GW-134L-0- 441 

I 

NA 

GLP10-01-01-39-026 DAL-GW-134L-DB- 433 NA I 

Average 437 

%RPD 1 .8 

Dilution 

b121221083 100 

b121221a084 100 

DAL GW 135R PFOA _ 

Conc. FMS 

3M LIMS ID sample Description n /mL_ %Recove 

GLP10-01-01-39-027 DAL-GW-135R-0- 3080 I NA 

GLP10-01-01-39-028 DAL-GW-135R-DB- 3100 NA 

Average 3080 

%RPD 1 .3 

Dilution 

b121221a085 10 

b121221a086 10 

DAL GW 135S PFOA 

Cone. - FMS 

3M UMS ID sample Description n mL _%R_ecove 

GLP70-01-01-39-029 DAL-GW-135S-0- 24.7 - 

1 

NA 

GLP10-01-01-39-030 DAL-GW-135S-DB- 23.8 NA 

Avemge 24.3 

%RPD 3.7 

Dilution 

b121221a087 10 

b121221a088 10 

DAL GW 135L PF_OA_ 

Co nc FM S 

3M UMS ID Sample Description n m %R o ve 

GLP10-01-01-39-031 DAL-GW-135L-0- 191 

I 

NA 

GLP10-01-01-39-032 DAL-GW-135L-DB- 186 NA 

Average 189 

%RPD 2.7 

b121221a .xls Sample Data wQC Page 10 of 13 
p. 49 

Printing Date and Time 

4129/2013;1 :01 PM 

Sample Result with OC 

NC - Not Calculated; Endogenous sample greater than 2x spike level 

Dilution 

b121221a092 10 

b1212218093 10 

b121221s094 10 

DAL GW 136S PFOA 

Conc. FMS 

3M UMS ID Sample Description _n mL %Recove 

GLP10-01 "01-39-035 DAL-GW-136S-0- 95 .4 NA 

GLP10-01-01-39-036 DAL-GW-136S-DB- 83 .7 NA 

GLP10-01-01-39-037 DAL-GW-138S-FMS- 188 100 

Average 94 .6 

FIeldMauIxSplke 101 

%RPD 1 .8 

Dilution 

b121221a095 10 

b121221a096 10 

DAL GW 136L PF_OA - 

Conc. FMS 

3M LIMS ID sample Description n mL %Recove 

GLP10-01-01-39-038 DAL-GW-136L-0- 

136L 82.7 NA 

Average 81 .8 

MAD 2.3 

Dilution 

b121221a097 1 

b121221a098 1 

b121221a098 1 

DAL GW 137S PFOA 

Conc. FMS 

IM LIMSID Sample Descri ption n mL_ %Recove 

GLP10-01-01-39-042 DAL-GW-137S-0- 0.819 NA 

GLP10-01-01-39-043 DAL-GW-137S-DBI 

0.584 NA 

GLP10-01-01-39-044 DAL-GW-137S-FMS" 2.02 74.0 

Average 0.602 

Field Mahix Spike 1 .92 

%RPD 5.8 

Dilution 

b121221a100 1 

6121221a101 1 

DAL GW 137L PFOA 

Conc. FMS 

3M LIMS ID Sample Descrl flon n mL %Recove _ 

GLP10-01-01-39-045 DAL-GW-137L-0- 0.349 NA 

GLP10-01-01-39-046 DAL-GW-137L-DB- 0.329 NA 

Average 0.339 

%RPD 5.9 

DIlu9on 

b121221a105 10 

b121221a108 10 

DAL G W 138S PF_OA_ 

Cono. FMS 

3M LIMS ID Sample Description n lmL %.Recove 

GLP10-Oi-01-39-049 DAL-GW-138S-0- 154 NA - 

GLP10-Oi-01-39-050 DAL-GW-138S-DB- 156 NA 

Average 155 

%RPD 1 .3 

b121221a107 

6121221a108 

Dilution 

DAL GW 138L P_FOA 

Conc. FMS 

3M LIMS ID Sample Description n mL %Recove _ 

GLP10-01-01-39-051 DAL-GW-138L-0- 0.428 NA 

GLP10-01-01-39-052 DAL-GW-138L-DB- 0.465 NA 

Averege 0.447 

Y.RPD 8.3 ' 

Dilution 

b121221009 100 

6121221a110 100 

DAL G W C W26C PFOA 

Concs FMS 

3M UMS ID Sample DescrI 6on n mL %Rernv 

GLP10-01-01-39-053 DAL-GW-CW26P0- 353 NA 

GLP10-01-01-39-054 DAL-GW-CW26GD8- 348 NA 

Average 351 

%RPD 1.4 

Dilution 

b121221011 100 

b121221a112 100 

DAL GW C W26L PFOA _ 

Conc. FMS 

3M LIMS ID Sample Description n /mL %Recove 

GLP10-01-01-39-055 DAL-GW-CW26L-0- 828 I NA 

GLP10-01-01-39-f156 DAL-GW-CW28L-DB- 620_ NA 

Average 624 

°/aRPD 1.3 

b121221a .xls Sample Data wQC Page 11 of 13 
p. 50 

Printing Date andIme 

4129/2013; 1 :01 PM 

Sample Result with QC 

NC =Not Calculated; Endogenous sample greater than 2x spike level 

DIIuBOn 

b121221a113 10 

b121221a114 10 

DAL GW 140R PF_OA 

Cono. FMS 

3M LIMS ID Sam to Descrl tlon n mL %Recov_e 

GLP10-01-01-39-057 DAL-GW-140R-0- 121 NA 

GLP10-01-01-39-058 not -GW-i40R-DB- 118 NA 

Average 120 

%RPD 2.5 

Dilution 

b121221a118 1 

1,121221 119 - 1 

b121221a120 1 

DAL GW 141R PFOA 

Conc. FMS 

3M LIMS ID Sem le Description n mL %Recove 

GLP10-01-01-39-059 DAL-GW-141R-0- 1 .88 NA 

GLP10-01-01-39-060 DAL-GW-141R-DB- 1 .85 

1 

NA 

GLP10-01-01-39-081 DAL-GW-141R-FMS- 3.27 73 .3 

Average 1 .87 

Field Matrix Spike 1 .92 

%RPD 1 .6 

DlluBon 

b121221a121 10 

b121221a122 10 

DAL GW 142R PFO_A_ 

Conc. FMS 

3M LIMS ID So- Pie Description n mL %Recove 

GLP10-01-01-39-062 DAL-GW-142R-0- 48 .8 I NA 

GLP10A1-01-39-063 DAL-GW-142R-DI3- 45 .5 NA 

Average, 46 .1 

°/.RPD 2.4 

Dilution 

b121221a123 10 

1,121221a124 10 

b121221a125 10 

DAL GW 145R PFOA 

Cons. FMS 

3MLIMSID Sample Description n ml 

_5/ ._Wove 

GLP10-01-01-39-067 DAL-GW-145R-0- 55 .8 NA 

GLP10-01-01-39-068 DAL-GW-145R-DB- 56 .3 NA 

GLP10-01-0139-G89 DAL-GW-145R-FMS- 143 88.2 

Avenge 56 .0 

FIeldMaulxSplke 101 

"/.RPD 1 .3 

Datafile Dilution 

6121221a044 1 

6121221a045 1 

1,121221a046 1 

b121221a047 10 

Trio Blank PFOA 

Canc. FMS 

3M LIMS ID Sample Description n mL _%Recove 

GLP10-01-01-39-072 DAL-GW-TRIP01-0- <0 .0240 NA 

GLP70-01-01-39-073 DAL-GW-TRIP01-LS- 

~ 

1 .67 87 .2 

GLP70-01-01-39-074 DAL-GW-TRIP01-MS- 17.1 84 .7 

GLP10-01-Ot-39-075 DAL-GW-TRIP01-HS- 89.8 88 .9 

LowField Matrix Spike 1 .92 

Mid Field Matdx Spike 20.2 

High Field Matrix Spike 101 

LOQ 0.0240 

LOQ'10 0.240 

LOO-100 2.40 

b121221a .bs Sample Data wQC Page 12 of 13 
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$ 
A copy of the Chain of 

Custody can be found in 

LAB WARE LIMS 

A copy of the GPO and/or 

Protocol can be found in the 

Lotus Notes GPO Database 

Communications 

Misc -- Note to File 
3M ENVIRONMENTAL LABORATORY 

Project or Study Number: 

___ ._.... . . . ._._ ._..__..__w.._ . . .____. .. .. 

LIMS Number:-

_. .. .-. ..___ ._.__~---.___-__ 

Affected Data: 

Note to File 

GLP I 0-01-O1-39 

_... .__... .._.._...-

GLPI 0-01-01-39 

None 

All logbook pages for the individual stock standards and mixes used for the calibration curves 

and LCS used for the analysis of GLP 10-01-01-39 were printed to pdf (exact copies of originals) 

and included in a folder labeled 'Logbook pages for GLP10-01-01-39' located in the project folder 

located at : 

P:\Projects\Lab_ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

PFOA\GLP10-01-01-39 FSIA Q4 

The chromatograms for results file b121221a were printed to pdf and saved in the project folder 

located at : 

P:\Projects\Lab_ESA Analyticai\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

PFOA\GLP10-01-01-39 FSIA Q4 

A pdf copy of the signed protocol amendment GLP10-01-01 Amendment 39 is located in the 

project folder located at 

P:\Projects\Lab ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

PFOA\GLP10-01-01-39 FSIA Q4 

~Once the data package has been reviewed by QA and the report signed, the pdf will be moved to 

the shared drive (\\usfile01\b2\Projects\Lab Shared\Archive Requests\Electronic Reports) and a 

reference to the location of the pdf will be added to the archived request form under Elec Media 

Path. 

Recorded By: Date: 

12 ~ 2ln ~ 12 
Collection Bottle Prep 

Sample Prep 

Standard Prep 

(pdf in project folder) 
Note To File 

Project or Study I Decatur Phase 3-FSIA groundwater 

Descri tion: i 

_ ._.-__

. .~. .. .._-_....--- 

LIMS Nutnbcr: f GLP10-01-O1-39 ._..____._.__....._. ...__. . ._-_._ .__. . . . _- .. .-_~.- .___. .. ... 

Affected Data: ~ None _ 

On November 29, 2012, seventy-five 250 mL Nalgene bottles were marked with a 200 mL level line and 

labeled . The trip blank and trip blank spikes were filled with Milli Q water (TN12-0400) and sealed after they 

were spiked. 

The field matrix spike bottles for select sampling locations were spiked with the following: 

Field Matrix Spikes 

Well No. 

Spiking 

Solution 

Approx. 

Value 

(pglmL) 

Spike 

Amount 

(pL) 

Spike 

Cono. 

tngimL) 

137S 12 008-22 10.0 40 2.0 

141 R 12008-22 10 .0 40 2.0 

131S 12009-202 100 40 20 

143R 12009-202 100 40 20 

130S 12009-202 100 200 100 

138S 12009-202 100 200 100 

145R 12009-202 100 200 100 

12008-22 10.0 40 2.0 

Trip Blank Set 12009-202 100 40 20 

12009-202 100 200 100 

A 1-L container of Milli Q Water (TN12-0400) will be provided to be used for the collection of equipment rinseate 

blanks. - 

Used Eppendorf Research pipette 3402277 to add spiking solution to samples. 

Recorded By: Date: 

I1I2q 112 
Printing 122012012; 2:32 PM 

GLPiD" 0101-39SamPlePrc,yWO=kShoelyETS-8 

da :721TOh2 "-Fal St'CJO 

"Oai.1. ..~ . . 

t8 Y 

Bam  " ,p Io1D -~ Sa m le DascrIpUOn 

LCS "121220-7 0.5uPbLCS ~^ 

LCS4t72202,--, D.S ;pbLCS 

LC-'127220.3 0. bIS - 

LC6127220A 5 b LCS 

Dilution I 

NA 

NA 

NAJ 

NA 

Sam_Ple>liquu-t L), ( 

I NA 

NA ' +- 

NA 

NA 

~ikin Bid 10 

12009-?,30,_ 

12W9" 134 

12W9-13A 

Sylka Am(JUL) 

_, +0 

.50 

 --50 _ 

Rea 8anl WatarImL/ 

10 .0 

10 .0 

10 .0 

100 

Final Vol /mLL 

,- 70.05 

70.06 

_ 10.0a 

70.05 

_ -_,

. . ..-.,- 

LCS " 1212205 5 LCS 

LCS_12t2208_ " -SPPbLCS 

LOS-12,12Y0 ~7 (~ 30pObLCS 

NA 

NA 

' NA 

_ 6NNA~_ - 

NA- _~~ 

72008" 133 

1200&133 

12008-22 

50--,  

50 

30 - 

,_ __ 10.0 

 ,- 100 

10 .0 

1005 I 

7005 1 

70,03 

~ - LCS-12i2 9LNPb LC NA A 1 

'_ 

12008-22 _30 10.0 70, _ 

lCS~121220"9 30pot, LCS NA NA 12008- 2 

_ 

30 10.0 10.03 1 

Gf p70-01-0t-39{101 DAL"GW-130R-0- 10D 0 .700 

_ . . . . 

NA 

__ 

NA 9,9 10,0 

. 

OLP10A1At"39-002 DAL-GW-130RAB" 100 - 0700 NA __ Nq - .--- 9.9 

_ 

10.0- 

GL70-OtAi" 38-003 DAL"GW" 130S-0- 

J~ 

10 100 - 

NA NA 

-~ 

.. .. 

9.0 iDA 

GLP10 Oi-0'1-39^ 04 DAL"GW" 73UTS'-~- i0 100 NA NA, 9.0 10 .0 - " .~ 

__ 

..-_. .._ 

GLP70 "OtAi-39-0OS DAL-GW-139S"PMSG

,.._, .. . _ 

LP10-0 7 "Oi " 39-0OB DAL"GW"130L-0 " 

10 

10 

7,00 

1 .00 

~ 

NA } 

-,--, NA 

. -.,. . .-._ 

NA 

_ NA 

- 

9.0 

90_-_-_ 

10 .0 

_ 70 .0 

GLP10AtA i-39 "0D7 _ DAL-GW"130L-DBGLP70-01 "Dt-39-008 DAL"GW-137R-0- 

AL-GW" 131R-OB " UPfO" 01 "01 " 39 I 

10 

100 

100 

7,W 

O10( 

, NA 

NA 1 

- NA 

NA _ 

NA , 

9.0 

9.9 

9.9 

10,0 

1D,0 

10 .0 ~ 

- --~~--~^- _ 

6LP10-Oi "07-9-010DA4GW"131S-0" NA 

,,_a 

_" NA 

,_ ," , 

NA NA _ .`! __ NA NA I _ 

.-

._-_ GLP70-01-01_38-071 DAL-GW-1313" OB- NA NA NA _. NA I .." NA NA I 

GLPfO .O7-0133-D72 DALGW-1315-FM - i0" 100 NA N 9 .0 10.0 _ _ 

GLP10-0t-01-39"D73 DA4GW-731L-0" 10 100 NA NA 9 .0 70.0 

GLP70 " 07A1~ 9 "p14 ALGW-79YL-OB " 10 100 NA,-, 

,-_- 

NA _ 9 .0 10.0 

GLP10 O7-01-39"D75 I D GW" "733R" 0 10 700 NA NA 9 .0 10.0 - A L ;" ,, 

GLP10 " Ot~ A7-08-0 i6 ~~DAIrGW-133R-OB- 70 

_,_ -, 

1 00 NA 

_ 

_ NA_ _ . . 

~ ~~ ~~ 

_ 

9 .0 

, 

10.0 

GLP70-01-07-39-0~~DAL-GW"7335-0- 10 100 _ ._,_,._ . 

NA NA 9 .0 10.0 _ 

GLP70-O7-0 7-3-07A DAL"GW"133S-UA" 70 100 NA 

- ~~ 

9,0 - 10,0 I _ 

GLPt0-O7-01-3S~Ji8 DAL-GVV"733L" 0" 70 _ - 1A0 NA NA 9,0 

-- 

700 _, 

GLP70-01-01 .39 "020 DAf--GW-733L DB- t0 7_00 NA 

-,_--

. ._.._ 

NA 9D 70,0 1 _- 

3LP10 " OtA1-39A21 DAL-GW"73AR-0- -."~_ 100 OAOD NA _ 

-, 

" "" 

NA iD.O I 

-_ 

GLP10-07-01-39-02Y DAL"GW"134R"DB- 100 0.1110 W , 

_ .. . . .

7- 

NA 9,9 

_

. 

___

_ 

--* ~ 

_. .

-,___

. .__--- 

OLP70-111-0 1-99-029 DAL"GW"7JAS-0- NA NA NA - NA NA 77 = 

OLP10-OtAi-39A24 OAL-GW"1345-UBGLP7Q-Ol-0'I_39415 DAL-GW"134L-0- _ 

GP70-0t "07- 39-028 DAL-GW"134L-D8 

NA 

100 

100 

NA 

0.100 

~~ 0700 

NA 

NA ., 

NA 

NA, 

NA .,_ ., ., . .. . __ 

_ NA 

- 

NA 

99 

89 1 

NA ; 

-, 700 1 

10.0 --- , 

GLP10A7 01-79-0V IDAL-GW"135R " 0" 100 0,700 NA NA 99 ! 100 , , " 

GLP10 " Ot "01 " 391128 DAL-GW"135R-0BGLP70 " 07-01-992 -~2 OAL"GW"7955-0 " 

700 

10 

0700" --~_

.- 

1,00 

NA 

NA - 

. ... 

NA 

-^ -- NA 

99 I 

9,0 

" 

10.0 

10.0 

1 --"_ 

I _ 

GLP10-01 IDAL".- GW"1355-11E 70 1.00 NA I NA 90 10,0 

GLPfOAf "01 " 39-03 7 DAL-GW-135L0- 10 

- 

-,- ",-1 .00 J 

 -- - !~ 

,  NA . _ ._. 

~ 

90 70,0 

GLP70-O1 :01-09-032 DAL-GVd-735L-D8- 10 100 . . (!A I 

-_- . ._ 

NA _ 8U 

- 

__10.0 . ..._ . . . 

&P-10-R- 01 " 39-035 

DS-0- 

10 100 NA 

.----_

".-,_" NA 9,0 _.-.

.__ .- ._ _ 

70.6 ~ 

6LP10-01 "O7 " 79"030 DAL "OW"7305-DD- 10 i .00 

-'-._, 

NA NA 

_ -

.,., . ., .-- 

- 

9 .0 10.0 

GLP10 ;01 " 01 " 39-037 DAL-736S-FMS. 10 1 "00 . .. .. ._ ..~ 

--,_NA NA 9 .0 _.-...... _ 

70,0 

GLp104147 " 39A38 DAL"GW-7361.-0- W 7 .00 . 

NA NA 9,0 10.0 

GLP10 01-01 a 9 "0 9 IDAL-GW"138L -DB- 10 1,00 NA NA 90 10A i __ - 9 

GLP10 " 01-01 " 39"092 DAl-GW"137S-0- NA 

, 

NA 

__ 

_ _ NA _ 

""- 

_ 

MNA ___ NA_ NA I 

GLF10i11-01 " 39-043 bAL-GW"187S-D B-~ NA NA,_,__ N~ _NA____ _ NA NA 

~~ 

I 

GLP10-01-01J9-044 DAL"GW" 137S " FMS- NA NA NA NA _  , NA NA iGLP10-01A1 , 79 A45 DAL-GW"737LA" NA NA ( NA NA NA NA I _ 

GLP10-0t-01 " 39 "046 OAL-GW"137L"DB- NA __

NA 

_ 

NA 

_ 

--_-_ . 

NA ... . ._.- NA NA - . . 

GLP70-01-01 " 39-049 DAI-GW-0385A- 10 1 .00 --N . . .. ,. . . 

NA 9 .0 _ _ 10.0 ._.__ . 

I . . . - 

-_'__' __- GLP70-07-07-39-0SO DAL-GW-f389-0B" 10 1 .00 _ _-NA 

~ 

NA 9 "0 _ ..w,_... 70A 

GL 

.. . .

.-_-- P70-0t-01 " 39-051 DAL-GW"13BL-0" 

GLP70- t "0739 "0 0Al"GW-f3BL-DB" 

LPf0- 7-07 " 39-053 DAL-GW-0W26C-0" 

NA 

NA 

f00 

._

NA 

'___. . ._..,_ 

0 .100 

NA 

NA , ., 

NA 

NA _.._._._ . . .. ... . .. . 

NA . .. . . ......-_ . 

NA 

NA 

NA 

B.9 

NA 

NA 

0-0 

1 ~ _. . 

°-- 

--- 

_ G 

GlPt0

0 

" 01-07-39A54 DAL-GW-CW26G09- 

-"._ -".. 

QLPt0AtA 

..

1-39~055 DAL-GW-CW28L-0" 

GLP70-0Y-07-39A56 OAL-GW-CW26LDo .- 

100 

100 

100 

-  

0,100 

0 .100 

O.tOD 

, 

NA -.._.,__ .. . .

.- _ 

_,N 

NA 

_-, 

NA 

~ NA 

NA 

"- 

-- --_- - 

9 .9 - ~ 

9,9-F 

8.9 

~ 

,-, 

~ 10.0 

~ 10.0 

70,0 

-- _ 

.-, . .-". 

GLP70-07-01-39-05% UAL " W"140R-0- 10 

, 

~ 

1,00 NA NA 

- - _ - 

9,0 10.0 

GLP70 1 07-3f)458 OAL-GW-7e,OR-DB- 10 700 NA tJA 9.0 10.0 - -0 : 

GLP70-01-01-39"059 DAL-OW-741R"0" NA NA - -~ NA ' ~ NA ~ I NA 

GLP10-0t-01-39-0BO OAL-GW-041R"D8" NA Nq NA NA i NA NA 

GLP70-01-01-39-061 DAL-GW" t41R-FMS" NA NA 

~ 

u 

,-, _ 

NH 

_ 

~_NA NA 

~_ 

_ 

NA 

GLP7q-01-0139-062 DAL-GW-142R"4 10 7,00 

~ 

NA N A, _ I 9.0 I 10.0 

GLP70-01-0i-34063 DAL-GW" 14W R-UB " 10 1 .00 NA NA 8.0 10.0 

GLP7-01A1 "39~067 DAL-GW-146RA---- 10 

__ 

---~ _~1 .00 - - NA 

 _ 

_ NA 

- 

9.0 1 0.0 

_ 

GLP10-01-01-39 A068 DAL " GW" 145R"DB" 10 1 .00 NA IJA __ 

' 

_ _90 1 100 

GLP70-01-01-38-069 DAL-GW-145R"FMS- 1 10 100 NA NA _ 

_ 

_ __ 9.0 

" 

10.0 

GLP70-Ot-01-39-070 DAL-GW-131S-RO- NA NA NA NA NA NA ,_ 

GLP70"D1-07 "39-077 ~ D AL " GW-145R"RB NA NA NA NA _ 

- 

NA ~ -___, 

1 " 39A72 fDALGWTRCP01~0 " 

_ 

NA NA NA 

- 

NA 

,_, _ 

NA NA 

OLPID.01-01 -39-073 ,D " NA ~ NA 

__ _ - 

NA 

~- 

.__-_ .____ ._ . . 

NA 

_ 

NA NA _ . 

GLP70-07-07-39-D 749-D74 !DAL " GW-TRIP0I-MS- NA 

- 

I NA NA NA NA NA " , 

OL P10-O7-07-39-075 'DAL " GW"TRIP01 "H5- i0 J , ,00 ,_NA NA  _ ,90 700 _ _ 

72R0112 CJG' GLP70-Ot-01-39 sam !os diluted wA h Milli U WetartN72-0421 and v one. m xod__ , - 

72/20112 CJG; SWndard curve 12 01 1-30 oliauoted into 2"mL 91=5s aNOViaI. Ten eut 

l 

onela o! Mi1110 

I 

Walor TN122f wcro a- d ac s0lvenVmet hed blanks . 

i forsamaleatluot 7120I72CJ GLCSSPre pared Using MIII- 0Water TN12A42 

- " _~ 

,__ 

1217I1/19CJG Used 6 oonrlod iatta¢L13882Ban -~ 115B168 -r --~- -- ~ 

STS-8A441 samPla PreP 121220 AS 

L'-3G 12+2D/12 

Pago 7 or 1 
Analytical Case Narrative 

Data Reduction Calculations 

(excel spreadsheet in project 

folder) 

Control Chart -Analytical 

Uncertainty 

(excel spreadsheet in project 

folder) 
p. 97 

3M Confidential 3M Environmental Laboratory 

Project : GLP10-01-01-39 

Sequence b121221a 

3M Environmental Laboratory 

3M Technical Lead: Susan Wolf 

Building 260-5N-17 

651-733-9851 

Report Author. Chelsie Grochow 

Analytical Team: 

Chelsie Grochow 

Analytical Case Narrative for Method ETS-8-44.1 

Project GLP10-01-01-39 

Decatur FSIA GW- Q4 2092 Sampling 

Direct injection analysis of samples 

Sequence:b121221a 

Report Date: December 26, 2012 

Instrument run summary will be printed and included in the raw data package. 

Results table, calibration curves, and chromatograms will be printed to pdf. 

ETS 8-044 Analytical Summary Checklist Page 1 of 3 
p. 98 

3M Confidential 3M Environmental Laboratory 

Project: GLP10-01-01-39 

Sequence b121221a 

1 Project Scope and Data Quality Objective 

General Projed Outline available . ® yes © No If No, Please briefly describe 

project scope and DQO 

GLP 10 Yes No 

2 Sample Container Preparation 

Sample container preparation documented in a Note lo File included in the raw data package. 

3 Sample Analysis 

3 .1 System Suitability 

Initial System Suitability area counts with RSD 55% and retention time with ® Yes ~ No 

RSD 52% (ETS-8-44 section 13 .1) 

3.1 .1 System Suitability Deviations 

NA 

3.2 Instrument Calibration 

Curve type Quadratic, 11x 

>0.990 Lineadty criteria met (ETS-8-44 section 13.2) Yes No 

< :t 25% residuals, except LOQ of t30% (ETS-8-44 section 13 .2) Yes El No 

Mid-level calibration points disabled Yes I~ No 

The highest standard was disabled for PFOA to meet method criteria . 

3.3 Continuing Calibration Verification 

t25% Difference criteria met for periodic CCVs (ETS-8-44 section 13.2) ~i11 No I 

3.3.1 Continuing Calibration Verification Deviations 

NA 

3 .4 Method Blanks 

Method blanks uniquely identified in the run sequence. ® Yes LJ No 

Average area counts of target analytes In the method blank present at 2, '/ x ( 

the area counts of the L00 standard (ETS-8-44 Section 13.3) 

~ Yes [i No 

3.4.1 Method Blank Deviations 

NA. 

ETS 8-044 Analytical Summary Checklist Page 2 of 3 
P. 99 

3M Confidential 3M Environmental Laboratory 

Project: GLP10-01-01-39 

Sequence b121221a 

3.5 Lab Control Spikes 

t20°/a recovery criteria met (ETS 8-44 Section 13.4) ® Yes I] No 

<20% RSD precision (ETS 8-44 Section 13.4) Ix] Yes No 

3.5.1 Lab Control Spike Deviations 

NA. 

3.6 Sample Replicates 

------ RPD for field duplicates <20% (ETS-8-44 Section 13 .4) Yes f E] Na 

3.6.1 Sample Replicates Deviations 

NA. 

3.7 Field Matrix Spikes 

t30% recovery criteria met. (ETS 8-44 Section 13.4) ® Yes I [] No 

3.7.1 Field Matrix Spike Deviations 

NA. 

3.8 Limit of Quantitation (LOO) 

A8 LOQs equal the low-level calibration standard concentration 

with area counts at least twice that of the method blank(s) (ETS 8- E Yes i] No 

44 Section 13.2) 

3.9 Manual Integrations 

Manual integration reviewed by another analyst/team lead (ET -12-

010.0, section 9) : : Reviewed by: b~Yv~. Date:/2 ® Yes El No 

4 Additional analytical notes 

All data will be reported. 

5 Signatures 

,en~ 12.112 Lo 112- 

Analyst Date 

ETS 8-044 Analytical Summary Checklist Page 3 of 3 
Buster: AP14000: J2930203 page 1/1 

DATB 1 2 /21 / 12 

ANALYST;CJG 

STUDY NUMBER" GLPIO-O1-01-39 Matrix : water 

Sample Prep Date: 12/20/12 

Sample Aliquot Date: 2/1 20/12 

Mobile Pbase: (A) 2mM ammonium acetate (B) Methanol 

TN-A- or standard number (A) 12 015-50 (B) TN12-0342 3/4 

Guard (Pre-autosampler) column betasil Cl8 

Size: 4.6 mm X 100 mm Type: C18 Sphere size : 5 

Part number: 70105-104630 Lot number: 11919 Serial number 10021756 Started 7/25/12 

Analytical column betasil C18 

Size : 4.6 mm X 100 mm Type: C18 Sphere size: 5 

Part number: 7010$-104630 Lot number: 119 Serial number 10021762 Started 10/9/12 

Batch Name: b121221a 

Printed : Friday, December 21, 2012 12:48 PM