## p. 1

## 81Yt ENVIRONMENTAL LABORATORY Chain-of-Custody Project : GLPIO

.Ol-01-39 Shipping Address: 3M Environmental Laboratory 3M Center, Bldg 260-5N-17 St. Paul, MN 55144 Phone: (651) 733-9873 All . Phone: (651) 736-6559 Fax : (651) 733-4687 Requester: Hohenstein, Gary Allan (MAPLEWOI Completion Date : Department: 530711 Project Lead: CliffJacoby Project Number: 0022674449 Phone Number: 651-733-2533 Date Created: 11/27/2012 Email Address: cbjacoby2@mmm .com Project Description: Former Sludge Incorporation Area (FSIA) GW Sampling- Q4 2012 Comments:

3MSamnleNumber Sample Descrintion Date/Time Samoled Matrix Comment GLP10-01-01-39-001 DAL-GW-13012-0- 0, (I 3p 11 3D Ild ~~i W GI .PIO-01-01-39-002 DAL-GW-130R-DB- t o 

## o rJ. b W GLPIO .Ol-01-39-003 DAL-GW-130S-0- ,2 3D ~ ( v GLPI0-01-01-39-004 DAL-GW-130S-DB- i 1 a ~ 1 ( I GLPIO-01-01-39-005 DAL-GW-130S-FMS- ja( D u lo~ GLPI0-01-01-39-006 DAL-GW-130L-0- ( ;D ~ D

# l i

# d 0Z Iq/ 

## GLP10-01-01-39-007 DAL-GW-130L-DB- v D 0 ~,O I GLPIO-Ol-01-39-008 DAL-GW-131R-0- 196, ;, 1 ;2 OK 16&15 ', GLPIO-01-O1-39-009 DAL-GW-131R-D!3- A 65 ~ IAg O OSLK I GLPIO-01-01-39-010 DAL-GW-131S-0- I )OL' a,0 GLPIO-01-01-39-011 DAL-GW-131S-DB- I a la 04 ~a0 ~

, 

# V'/ GI-P10-07-01-39-012 DAL-GW-131S-FMS- a t ?~ W G010-01-01-39-013 DAL-GW-131L-0- O f~ O GLPIO-01-01-39-014 DAL-GW-131L-DB- w looJ~ P, yJ ' Sample Condition Upon Receipt Acceptable Temperature: a .,- Deg C ~ Received on Ice 

## Collected by (print): ate

hlied by: Date Reli7~, // 

## 11 items accounted for El Other :

Time Shipped Vin Date Time 

# ia o~ 9A 2-2 

# I Collector's signature: Received b . 1) 1



## Page I of5

## 30 ENVIRONMENTAL LABORATORY Chain-of-Custody Shipping Address: 3M Environmental Laboratory 3M Center, Bldg 260-5N-17 St. Paul, MN 55144 Phone: (651) 733-9873 Alt. Phone: (651) 736-6559 Project : GLP10-01-01-39 (cont .) Fax : (651) 733-4687 Requester: Hohenstein, Gary Allan (MAPLEWO( Completion Date: Department: 530711 Project Lead: CliffJacoby Project Number: 0022674449 Phone Number. 651-733-2533 Date Created: 11/27/2012 Email Address : cbjacoby2@mmm

.com Project Description: Former Sludge Incorporation Area (FSIA) GW Sampling-Q42012 3M Sample Number Sample Description Date/Time Sampled Matrix Comment GLPIO-01-01-39-O1s DAL-GW-133R-0- ~'~ +~ BS ' Q~~a GLPIO-01-01-39-016 DAL" GW " 133R-DB- DS ~~~~ ~ yv/ GLP10 .01 "01 " 39-O17 DAL-GWa33S-o- 6 ' p
~ 

## GLP10-01-01-39-018 DAL-GW-133S-DB- ~ 3" GLP10-01-01-39-019 DAL-GW-133L-0- a $4~y GLP10-o1- 01-39-020 DALGW-133L-DB- ( 3D GLP10-01-01-39-021 DALGW-134R-0- I 0 OS ld GLP10-Ol-Ol-39-022 DALGW-134R-DB- ~ S U ~. ~tytl W 

## GLP10-01-0]-39-023 DAL-OW-134S-0- 05, GLPIO .Ol-01-39-024 DAL-GW-134S-DB- I 0 GLPIO-O]-01-39-025 DAILGW-134L"0- a 9p.? ~ GLPIO-OI-Ol-39-026 DAL-GW-134L" DB" ~ y 0 r' GLI'10-01-01-39-027 DAL-GW-135R-0- GI,PIO-01-01-39-028 DAL-GW-135R-1)B- l

# a o

# < )

# A//)g10 

# VJ GLPIO-01-01-39-029 DAL-GW-135S-0- a 03/s- ) / 

## GLP10-01-01-39-030 DAL-Gbv-1355-Dls- ~ ~~ d / OS l (7~I VJ GLPIO-01-O1-39-031 DAL-GW-135L0- jd, OS 1 ' I ~a Sample Condition Upon Receipt XAcceptable XAll items accounted for Temperature: .-gr Deg C D Received on lee 0 Other: Collected by (print) : &L ~ML Collector's signature: 

## Relin e by: Date Time Shipped Via Received by: v -Date Time



# )a~ ~ ~+ / i 

# 1_Ii~j,

Page 2 of 5

## 3MENVIRONMENTAL LABORATORY Chain-of-Custody Shipping Address: 3MEnvironmental Laboratory 3MCenter, Bldg 260-5N-17 St . Paul, MN 55144 Phone: (651) 733-9873 Alt. Phone: (651) 736-6559 Project : CLP10-o1-01-39 (cont.) Fax : (651) 733-4687 Requester: Hohenstein, Gary Allan (MAPLEWO( Completion Date : Department: 530711 Project Lead: CliffJacoby Project Number : 0022674449 Phone Number. 651-733-2533 Date Created: 11/27/2012 Email Address: cbjacoby2@mmm .com Project Description: Former Sludge Incorporation Area (FSIA) GW Sampling- Q4 2012 3M Sample Number Sample Descrintion Date/Time Sample Matrix Common 

## GLPIO-0I-01-39-032 DAL-GW-135L-DB- a 0~ )a o GLPIO-01-O1-39-033 DAL-GW-136R-0-
_ ) GLP1O-01-O1-39-034 DAL-OW-136R-1)[3- ~ g GLPID-OI-Ol-39-035 DAL-OW-136S-0- a y GLP10-01-01-39-036 DAL-GW-136S-DB- a 3a a ( D 

## GLP1O-01-01-39-037 DAL-GW-136S-FMS- 3a i'a 11 ~, Z GLP10-01-O1-39-038 DAL-GW-I36L-0- O a 3~ ys/' GLP10-01-01-39-039 DAL-GW-136L-DB- ., M ;- 3q 6tJ GLPIO-01-01-39-040 DAL-GW-137R-0- 

# 04 GLPIO .OI-Ol-39-041 DAL-OW-13711-13BGLPIO .Ol-01-39-042 DAL-GW-137S-0- ~a 11 India v; Vf GLPIO-Ol-01-39-043 DAL-GW-137S-DB- 1 A 1 0511a, 15 f{n! GLP10-O1-01-39-044 DAL-GW-137S-FMS- YO UOs'' 6d/0 I5 )nf GLPIO .Ol-01-39-045 DAL-OW-137L-0- a -~_ OS' Ir3 . V' 

## GLPIO .Ol-01-39-04G DAI :GW-137L-Dl3- os o5 D 1,~ GLPIO-01-O1-39-047 DAL-GW'-138R-0- GLPID-01-01-39-048 DAL-GW-1 38 R-D13- 45n.,t0W-0Ml I Sample Condition Upon Receipt 7 .. Acceptable XAll items accounted for Temperature: r~-' Deg C ~0 Received on Ice El Other : Collected by(prinQ

: AA;Ls ~yha-~ Collector's signature; Relinqgipllgd by: Date Time Shipped Via Received by" Date Time



# aw ellE ~ 1

Page 3 of 5

## 311111 ENVIRONMENTAL LABORATORY Chain-of-Custody Shipping Address: 3MEnvironmental Laboratory 3MCenter, Bldg 260-5N-17 St . Paul, MN 55144 Phone: (651) 733-9873 Alt. Phone: (651) 736-6559 Project : GLP10-O1-01-39 (cont.) Fax: (651) 733-4687 Requester: Holtenstein, Gary Allan (MAPLEWOI Completion Date: Department: 530711 Project Lead: CliffJacoby Project Number: 0022674449 Phone Number. 651-733-2533 

## Date Created: 11/27/2012 Email Address: cbjacoby2@mmm .com Project Description: Former Sludge Incorporation Area(FSIA) GW Sampling- Q4 2012 3A7 Snmnle Number Sample Descrintfon Date/Time Snmnled Matrix Comment GLPIO-01-01-39-049 DAL-CW-138S-0- 1a a 0 jaO .SI1a DgIO W G] .PIO-01-01-39-t150 DAL-GW-I38S-Dtd- ) I ~ os l a Oc/ la GLPIO-01-01-39-051 DAL-GW-138L-0- a 65 ja - 109 00 GLPIO-OI-Ol-39-052 DAI .GW-138L-DId- ~ O .~ r 

### ~a bS Id, I bA W GLP10-01-DI-39-053 DAL :GW-CW26C-0- OS

12, l f~t, ~O a{ l// GLPIO-01-01-39-054 llAL-GW-CW26C-DB- a OS 1~. gL) yJ GLPIO-01-0]-39-055 DAL-GW-CW26L-0- (a a 

# aSIt~Ib~ VU 01-13I0-01-01-39-056 DAI .GW-CW261 .-D13- ( Id ~Oi ISSa E ~^-) GLPIO-01-01-39-057 DAL-GW-140R-0- E J Il III E I GLPIG-01-01-39-058 DAL-GW-140R-DB- p 11 (A (( 0 I 

## Gl .l'10-O1-01-39-059 DAL-GW-14111-0- ( 30 d AIL(S ~ I I GLPIO-01-01-39-060 

## DA),-GW-141R-D8- 13, if 36 I 30 J,Ie.js ~ / GLP10-01-01-39-061 DAL-GW-141R-FMS- '~ D s ,)_ N~J W GLPIO-01-01-39-062 DAL-GW-142R-0- IA 11 O ( 0 695- I 

## GI .PIO-ol-01-39-063 DAL-GW-142R-Dt3- ja ~( 0 O h, jOg W GLPI0-01-01-39-064 DAI :GW-143R-0- AZ. - 1~ I- _ c . GLPIO-01-G1-39-065 DAL-OW-14312-D13- _ ~4~ et - p Simple Condition Upon Receipt L~ Acceptable ~All items accounted for Temperature: ~~ ocg C /~ Received on lee El Other : Collected by (print) : && ~M- ~-S Collector's signature: 

## b

Rclinqui he by: Date Time Shipped Via Received by: Date Time 

# - 9 / 

# 4 

# ` a iaa> FPd vAL' 12/ /~z //3a

Page 4 of 5

## I 3MENVIRONMENTAL LABORATORY ', Chain-of-Custody Shipping Address: 3MEnvironmental Laboratory 3MCenter, Bldg 260-5N-17 St. Paul, MN 55144 i Phone: (651) 733-9873 I Alt. Phone: (651) 736-6559 Project : GLP10-O1-01-39 (cont.) i Fax: (651) 733-4687 Requester: Hohenstein, Gary Allen (M IiPLEWOt Completion Date: 

## Department : 530711 j Project Lead: CliffJacoby Project Number : 0022674449 I Phone Number: 651-733-2533 'i EmailAddress: cbjacoby2lJa mmm .com Date Created: 11/27/2012 

## Project Description: Former Sludge Incorporation Area (FSIA) GW Sampling - Q4 2012 I 3MSample Number SamnleDescriotion Date/TimeSampled Matrix Comment GLPIO-01-01-39-066 DAL-GW-143R-FMS- 

# 0 9- GLPIO-01-01-39-067 DAL-OW-145R-O1- ~ a (p, Q ]p~ D 1 ra fla ~ ` ' GLPIO-01-01-39-068 DAL-OW-145R-D9- a ,Z, ~ ot h). A 16a GLPIO-Oi-01-39-069 DAL-GW-145R-FMS- ( a ta d ~ I~ Ov 

## GLPIO-01-01-39-070 DAL-GW- -R]3- / 

# 01 GLP10-01-01-39-071 DAL-GW- (y5g-RDGLPIO-01-01-39-072 DAL-GW-TRIP01I-0- GLPIO-01 "01-39

"073 DAL-GW-TRIP01~,LS

## GLP10-01-01-39-074 DAL-OW-TRIPOI1iMSGLP10-01-01-39-075 DAL-GW-TRIP01~'-HSSample Condition Upon Receipt )51, Acceptable ,L4All items accounted for Temperature: 07 Deg C '/ElI Received on lee / El Other : 

## i Collected by (print) : Collector's signature: Rel~inqujahe by: Date I Time Shipped Via Received by: Date Time



# raOII JaOJ F /

i 

## Page 5 of5

## p.8:

## p. 10



# 10 Standard ID# 1 12008-22 Component Standard Corrected Final Concentration Description ID# Conc. or Purity Expiration

Date Weight or

Volume Balance 10 Weight (P51M L) 

# FFISA qv&&P~&L. LO-111Z L&I-LoML 10 .0 

# ?FPeA LiEi9o-reok t4li-))13 5H-5~41- 1010 

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# PFPA I7-C,C) C?- I1 -3 '56~0!>'ML Ll /1 -7 11'3 H9 .501, ID .0 

# KUnA I'i00q-I(tP 140vot',%L 14 /1? 11 .3 W,E5V L 10 .0 I.?FDD A ~2-00q-fkl q qzc~$L- . 1411-7113 5D .-BM L ID-0 Pf: T~- A I scoq - I (S 4090fhWILIq /1-711e> jo J .-I A L 

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# L- PrH I2-D&q-1zC. 5s5yer-& 91-2511 6,9 .0 p L 0. 1) 

# F 135A ~ZC017-17-1 Hl3GP*,,L 4)'-7'13 jpO~JpjAL 10,0 V-

# 01,13A 1-2r~oq- 17- 2- 5t~50P%~L q I I --I I I S Hicl .SWL 1 0. 0 - -f-PFoA 41-2-ZIIB I rnL - 9 .5-9 

# -r-i>rok TCrtj-otq2-ZP, 54k,51rnf- L417-7-113 I V11 L- - CF~OASd CI .SIR -i - PFOA LIWLIG' im L. - C

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r .01" , ons C0Imb, 11 e CIZC&lc~t alel fi Y, a I anc, - CJ6 072071 Final Volume 1

# 2E5mL

Approximate Concentration ofthe mix G-N301 Uil OVIS YVe re CAAl'C%i ef~,na\ ccric, C56 112- 

# ExpirationDate: 5175113 -- Ncj~e Expiration Date: 12 f2 LoI I 3 a -1 Storage Location: A°i7 0 Pipette IDs: Prepared By: Cle MULTbCOMPONENT PREPARATION LOG Book No. 12008 Page No. 22 Description: I Ad !~ FC MI x Solvent: ~] PCI-I DatePrepared: lw22f S'> 3MTrace# : 7N12-02(n'-1-y/ 4

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## SINGLE COMPONENT PREPARATION LOG

Date: ... / d^ / -?- /a Book No . 12009 Analyst: K, C Description: - Pr f;A S+tyLk

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## SINGLE COMPONENT PREPARATION LOG Date: Book No . 12009 C Page No. 110 Analyst: )C~ q~ Description: I~Y' PCr! 

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## SINGLE COMPONENT PREPARATION LOG

Date: / (/ - ) / - /a Book No. 12009 

## Analyst: ~ Description: /" f uyt /-7 ,,J49('~

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# I'\ lI "U` 03 I
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Signature, Date

## Date:

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# 10- 1-7- IQ

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Description: 

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# 11 1,

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Weight or Volume ~r . 'O ~ J©~ 'BalahcelPi

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# 1e Number : TjV~A-^ l73 I'a N' -/

Final Concentration: 3SGO .L(4 lWl 1^


## Storage Location: YJ 5 - 70 Expiration Date: '7' /-7-

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SignaYure, oate

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Description

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Weight or Volume © /0



# , 3

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# F8SA ._5Gk Book No. 12009 Page No. 121

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# - T(' 9 -L141 Weight or Volume ,,

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Final Concentration: Expiration Date: 

# ~~13d~

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Reviewed by: 'K A U W`-t;.6 W~611-2

Signature, ate

## SINGLE COMPONENT PREPARATION LOG

Date: /©"l-7^t9 Book No . 12009 

## Analyst 

# -9

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Reviewed by: ~'~ I,~ ~ `01301/2

Sign-at re. I~.~ ° ate

# AnalyticalInstrument Data



# and Data Reduction Calculations

## p. 25 MULTI-COMPONENT PREPARATION LOG Book No. 12008 Page No . 34 

## Description: ~L /' I I~ Solvent : AIIIl AL~ Date Prepared: 11 I b I i~J 3M Tra~ #e r -_ti T/ 1 7 Prepared By: Expiration Date: . ~ ti~ 1 ?~ Storage Location: IP9-0\ _- Pipette IDs: a +-,gai AtL 'Expiration Date: 31251 1?) -



## Standard ID# 12008-34 ComponentStandard Corrected Final Concentration Description ID# Cone. or Purity Expiration

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Reviewed by: Signature, Date

## Date: ~ ~ IZ Book No . 72009 Page No . 202 Analyst, -~ Description: 

## SINGLE COMPONENT PREPARATION LOG



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Final Volume: Final Concentration: Storage Location: Vj le-0 , Expiration Date: ;! 2

Reviewed by;

## Date:

Analyst: 

# 1l ~ 12 SINGLE COMPONENT PREPARATION LOG
Description: Y1lo1k SiOt(l'Ik AlxYIC/t'-'

Stock Number: ~

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# ~21U~9fmL . Expiration Date: 5 I tP 20I b

Reviewed

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## SINGLE COMPONENT PREPARATION LOG

K~ti Description: ~ ~ 

# 61- FC AI 1(

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## Final Volume: 7 6 vi L
Storage Location: Solvent and TN-A 

# Number: PC1J 'TN12'(1/h12.'314

Final Concentration: ~ ~ .a ,1,-- (t"I C
Expiration Date:



## Reviewed by: ft1fIA~p.AahChBW 1023"-2-

signature, Date

## SINGLE COMPONENT PREPARATION LOG Date: ---) ~) I 2M

I 1'L. Book No . 12009 Page No. 134 Analyst : - ~ __ 

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# Number. AC-1J - TNt2-0312-3I4

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Storage Location: A6' Expira6onDate: A .2~ ; I20 1 " /

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## p. 31

-Buster : J2930203 Batch Name : 

### Froject:\\usfile01\B2\Projects\Lab_InstrumentDala\Buster\BuslerData\FYojects\GLPIO-01-01-39Batch :b121221a Tab:Sample SetISET1 AcqMethod :PFOAonly 750uLflow. Sample Sample Name Sample ID Vial Position Data File Inj .Volume (pl) Comments 

## t b121221a001 Solvent Blank 91 b121221a 10 .000 Mill QWater TN12-0421 b121221a002 Solvent Blank 91 b121221a 10 .000 Mill QWater TN12-0421 3 b121221003 Solvent Blank 91 b121221a 10 .000 Mill 0Water TM 2-0421 4 b121221404 12011-30-8 8 b121221a 10 .000 1 .0 ng/ml-FCstd in Mlli QWater 5 b121221005 12011-30-8 8 b121221a 10 .000 1 .0 ng/mL FCstd in Milli QWater 6 b121221a006 12011 " 30-8 8 b121221a 10 .000 1 .0 ng/mL FCstd In Mill QWater 7 b121221007 12011-30-8 8 b121221a 10.000 1 .0 ng/mL FCstd in Ivilli QWater 8 b121221a008 Solvent Blank 91 b121221 a 10 .000 Mill QWater TN12-0421 9 b121221a009 Solvent Blank 92 b121221a 10.000 Mill QWater TN72-0421 10 b121221a010 12011 "30-1 1 b121221a 10.000 0 .025 ng/mL FCstd in Mlli QWater 11 b121221a011 12011-30-2 2 b121221a 10.000 0 .03 ng/M- PCstd in Mill QWater \ 12 6121221a012 12011-30-3 3 b121221a 10.000 0 .04 ng/rr1 PCstd in Mill Q Water i 13 b121221a013 12011-30-4 4 b121221a 10.000 0 .05 ng/mL PCstd in Mill Q Water f 14 b121221a014 12011-30-5 5 b121221a 10.000 0 .1 ng/mL FCstd in Mlh Q

Water 15 b121221a015 12011-30-6 6 b121221a 10.000 0 .25 ng/mL PCstd in Milt Q Water 16 . b121221a016 12011 "30-7 7 b121221a 10.000 0 .5 ng/mL FCstd in N1111 0Water 17 b121221a017 12011-30-8 8 b121221a 10.000 1 .0 ng/mL FCstd in Mill Q Water 18 b121221018 12011-30-9 9 b121221a 10.000 2.5 ng/mL FCstd in Mlli QWater 19 b121221a019 12011-30-10 10 b121221a 10.000 5 .0 ng/mL FCstd In Mill QWater 20 b121221020 12011-30-11 11 b121221a 10.000 10ng/mL FCstd in Mill QWater r 21 ' 6121221a021 12011-30-12 12 b121221a 10.000 25 ng/rnL FCstd in Mill QWater ', 22 , b121221a022 12011-30-13 13 b121221a 10.000 50 ng/n-L PCstd in Mill 0Water 23 b121221a023 12011-30-14 14 b121221a 10.000 75 ng/rrL FCstd in Mill QWater 

## 24 b121221aO24 12011-30-15 16 b1212211a 10.000 100 ng/n'L FCstd in Mill Q Water 25 b121221025 Solvent Blank 92 bl 21221a 1 10.000 Mill Q Water TM 2-0421 26 b121221aO26 Solvent Blank 92 b121221a 0 . ater - R 27 b121221aO27 Solvent Blank 93 b121221a 10.000 Mill Q Water TN1 2-0421 1 a 8 b121221028 0 1 Solvent Blank 93 b121221a a r 1 1, 9 b1 2 22 02 LCS-121220-1 16 b121221a 10.000 0 .5ppb LCS b 1 1
1121221030 LCS-121220-2 17 b121221a 10.000 0.5ppb LCS 31 b121221a031 LCS-121220-3 18 b121221a 10.000 0.5ppb LCS 32 b121221a032 LCS-121220-4 19 b121221a 10.000 5ppb LCS 33 b121221a033 LCS-121220-5 20 6121221a 10 .000 5ppb LCS 34 b121221a034 LCS-121220-6 21 b121221a 10 .000 5ppb LCS 35 - b121221a035 LCS-121220-7 22 b121221a 10 .000 30ppb LCS 36 , b121221a036 LCS-121220-8 23 b121221a 10 .000 30ppb LCS 37 b121221a037 LCS-121220-9 24 b121221a 10 .000 30ppb LCS 38 b121221a038 Solvent Blank 93 b121221a 10 .000 Mill QWater TN12-0421 39~ b121221a039 Solvent Blank 94 b121221a 10 .000 Mill! QWater TM 2-0421 40 b121221040 12011-30-9 9 b121221a 10 .000 2.Sng/mLFCstdinMill Qwater 41 b121221a041 Solvent Blank 94 b121221a 10 .000 Mill QWater TM 2-0421 42 1>121221042 GLP10-01-01-39 " 070 25 b121221a 10 .000 DAL-GW-131S-RB43 1>121221043 GLP10-01-01-39 " 071 26 b121221a 10 .000 DAL-GW-145R-RB44 b121221a044 GLP10-01-01-39-072 27 6121221a 10 .000 DAL-GW-TPoP01 "0- 45 b121221a045 GLP10-01-01-39-073 28 b121221a 10 .000 DAL-GW-TPoF01-LS48 b121221a046 GLP10-01-01-39-074 29 b121221a 10 .000 DAL-GW-TFUF01-MS47 b121221a047 GLPIO-01-01-39-075 30 6121221a 10 .000 DAL-GW-TRIF01-HS" 48 b121221048 GLP10-09-01-39-001 31 b121221a 10 .000 DAL-GW-130R-0- 49 b121221a049 GLP10-01-01-39-002 32 b121221a 10 .000 DAL-GW-130R-DB50 b121221a050 Solvent Blank 94 b121221a 10 .000 Mill QWater TM 2-0421 51 b121221a051 12011-30-8 8 b121221a 10 .000 1 .Ong/mLFCsldinMill Qwater 52 b121221a052 Solvent Blank 95 b121221a 10 .000 Mill QWater TN12-0421 53 b121221a053 GLP10-01-01-39-003 33 b121221a 10 .000 DAL-GW-130S-0- 54 b121221a054 GLP10-01-01-39-004 34 b121221a 10 .000 DAL-GW-130S-DB55 b121221a055 GLP10-01-01-39-005 35 b121221a 10 .000 DAL-GW-130S-FMS56 b121221056 GLP10-01-01-39-006 36 1>121221a 10 .000 DAL-GW-130L-0- b121221a057 GLP10-01 " 01-39-007 37 b121221a 10 .000 DAL-GW-130L-DBb121221a058 GLPIO-01-01-39-008 38 b121221a 10 .000 DAL-GW-131R-0- b121221a059 GLP10-01-01-39-009 39 )121221a 10 .000 DAL-GW-131R-D6- .- ._ 80 1>121221a060 GLP10-01-01-39-010 40 b121221a 1 0 .000 DAL-GW-1318-0- Data printed by CJG Page 1 of 3 Printing Time : 12 :49 :59 PM Printing Date : Friday, December 21, 2012

## p. 32 -Buster : J2930203 Batch Name : 

### Project: \\usfile0l\82\Projects\Lab InstrumentData\Buster\BusterData\Frojects\GLPIG-01-01-398atch :bi21221a Tab:Sanple SeI :SET1 AcqMethod :PFOAonly 750uLflow Sample Sample Name Sample ID VIaIPositlon DataFile Inj .Volume (pl) Comments 61 b121221a061 GLPIO-01-01-39-011 41 b121 221a 10.000 DAL-GW-131S-DB62 b121221a062 GLP10-01-01-39-012 42 b121221a 10.000 DAL-GW-131S-FMS- . 63 b121221a063 Solvent Blank 95 b121221a 10.000 k411i QWater TN12-0421 64 b121221a064 12011-30-10 10 b121221a 10.000 5.0 ng/mL FCstd in Iv511i QWater 65 b121221a065 Solvent Blank 96 b121221a 10.000 AkIliQWater TN12-0421 66 b121221a066 GLPIO-01-01-39-013 43 6121221a 10.000 IML-GW-131L-0- 67' b121221a067 GLP10-01-01-39-014 44 1:121221a 10.000 DAL-GW-131L-DB68 b121221a068 GLP10-01-01-39-015 45 b121221a 10.000 DAL-GW-133R 0- 69 b121221a069 GLP10-01-01-39-016 46 b121221a 10.000 DAL-GW-133RDB70 b121221a070 GLP10-01-01-39-017 47 b121221a 10.000 DAL-GW-133S-0- 71 b1212218071 GLPIO-01-01-39-018 48 b121221a 10.000 DAL-GW-133S-DB72 b121221a072 GLP10-01-01-39-019 49 b121221a 10.000 DAL-GW-133L-0- 73 b121221a073 GLP10-01-01-39-020 50 b121221a 10.000 DAL-GW-133L-mB74 b121221074 GLP10-01-01-39-021 51 b121221a 10.000 DAL-GW-134R-0- 75 b121221a075 GLP10-01-01-39-022 52 b121221a 10.000 DAL-GW-13412DB76 b121221a076 Solvent Blank 96 b121221a 10.000 kklli QWater TN12 .0421 77 b121221a077 12011-30-9 9 b121221a 10.000 2.5 ng/mL FCstd in IvSlli QWater 78 b121221a078 Solvent Blank 97 b121221a 10.000 MiIIiQWater TN12-0421 79, b121221a079 GLP10-01-01-39-023 53 b121221a 10.000 DAL-GW-134S-0- 80 b121221a080 GLPIO-01-01-39-024 54 6121221a 10.000 DAL-GW-134S-DB81 b121221a081 GLPIO-01-01-39-025 55 b121221a 10.000 DAL-GW-134L-0- 82 b121221a082 GLP10-01-01-39-026 56 b121221a 10 .000 DAL-GW-134L-DB83 b121221a083 GLP10-01-01-39-027 57 b121221a 10 .000 DAL-GW-135R-0- 84 b121221a084 GLP10-01-01-39-028 58 b121221a 10 .000 DAL-GW-135R-DB85 b121221a085 GLPIO-01-01-39- 29 59 b121221a 10 .000 DAL-GW-135S-0- 86 b121221a086 GLP10-01-01-39-030 60 b121221a 10 .000 DAL-GW-135S-DB87 b121221a087 GLP10-01-01-39-031 61 b121221a 10 .000 DAL-GW-135L-0- 88 b121221a088 GLP10-01-01-39-032 62 b121221a 10 .000 DAL-GW-135L-DB- _ 89 b121221a089 Solvent Blank 97 b121221a 10 .000 Mill QWater TN12-0421 . 90 b121221a090 12011-30-9 9 b121221a 10.000 2 .5ng/rH-FCstdinMIliQWater 91 b121221a091 Solvent Blank 98 b121221a 10.000 Iv511i QWater TN12-0421 92 b121221a092 GLP10-01-01-39-035 63 b121221a 10.000 DAL-GW-136S-0- 93 b121221a093 GLP10-01-01-39-036 64 6121221a 10.000 DAL-GW-136S-DB94 b121221a094 GLP10-01-01-39-037 65 b121221a 10.000 DAL-GW-136S-FMS95 b121221a095 GLPIO-01-01-39-038 66 b121221a 10.000 DAL-GW-136L-0- 96 b121221a096 GLP10-01-01-39-039 67 b121221a 10.000 DAL-GW-136L-DB97 b121221a097 GLP10-01-01-39-042 68 b121221a 10.000 DAL-GW-137S-0- 98 b121221a098 GLP10-01-01-39-043 69 b121221a 10.000 DAL-GW-137S-DB99 b121221a099 GLP10-01-01-39-044 70 b121221a 10.000 DAL-GW-137S-FMS100 b121221a100 GLP10-01-01-39-045 71 b121221a 10.000 DAL-GW-137L-0- 101 b121221a101 GLP10-01-01-39-046 72 b121221a 10.000 DAL-GW-137L-DB102 b121221a102 Solvent Blank 98 b121221a 10.000 MiIliQWater TN12-0421 103 b121221 a103 12011-30-10 10 b121221a 10.000 5.0 ng/mL FCstd in Iv511i QWater 104 b121221a104 Solvent Blank 99 b121221a 10.000 MiIliQWater TN12-0421 105 b121221a105 GLP10-01-01-39-049 73 b121221a 10.000 DAL-GW-138S-0- 106 b121221a106 GLP10-01-01-39-050 74 b121221a 10.000 DAL-GW-138S-DB- ' 107 b121221a107 GLP10-01-01-39-051 75 b121221a 10.000 DAL-GW-138L-0- 108 b121221a108 GLP10-01-01-39-052 76 b121221a 10.000 DAL-GW-138L-DB- . 109 b121221a109 GLPIO-01-01-39-053 77 b121221a 10.000 DAL-GW-CW26G0- 110 b121221a110 GLPIO-01-01-39-054 78 b121221a 10.000 DAL-GW-CW26C-DB111 b121221a111 GLPIO-01-01-39-055 79 b121221a 10 .000 Q4L-GW-CW26L-0- '112 6121221a112 GLP10-01-01-39-056 80 b121221a 10 .000 DAL-GW-CW26L-D& 113 b121221a113 GLPIO-01-0139-057 81 b121221a 10 .000 DAL-GW-140R-0- j114 b121221a114 GLP10-01-01-39-058 82 b121221a 10 .000 DAL-GW-140R-DB- .115 b121221a115 Solvent Blank 99 b121221a 10 .000 Mill QWater TN12-0421 716 b121221a116 12011-30-8 8 b121221a 10 .000 1 .0 ng/rnL FCstd in Iv511i QWater 117 b121221a117 Solvent Blank 100 b121221a 10 .000 NLIIiQWaterTN12-0421 - 118 b121221a118 GLP10-01-01-39-059 83 b121221a 10.000 DAL-GW-141R-0- 119 b121221a119 GLP10-01-01-39-060 84 b121221a 10 .000 DAL-GW-141R-DB120 I b121221a 12

0 I GLP I0-01-01-39-061 85 b121221a 10.000 DAL-GW-141R-FMS- )ata printed by CJG Page 2 of 3 ?rinting Time : 12 :44 :59 PM ?rinting Date; Friday, December 21, 2012

## p. 33

-Buster : J2930203 Batch Name : 

### Roject: \\usfile0l\82\Ftojects\Lab_Instrument Data\Buster\Buster Data\Projects\GLP10-01-01-39 Batch:b121221a Tab:Savple SetSET1 AcqMethod :PFOA only 75OuLflow . Sarnple 

## Sample Name Sample ID Vial Position Data File Inj .Volume (pl) Comments ly21221aI21 GLP10-01-01-39-062 86 IA211221a 10.000 DAL-GW-142R-0- b121221a122 GLPIO-01-01-39-063 87 b121221a 10.000 DAL-GW-142R-DB1233 y121221laI23 GLPIO-01-01-39-067 88 b121221a 10.000 DAL-GW-145POE 124 b121221a124 GLPIO-01-01-39-068 89 y121221a 10.000 DAL-GW-14SR-DB125 b121221a125 GLP10-01-01-39-069 90 b121221a 10.000 DAL-GW-145R-FlvS126 b1211221a126 Solvent Blank 100 b121221a 10.000 M11i Q WaterTN12-0421 127 b1211221a127 12011-30-11 11 b121221a 10.000 10ng/niL FCstd in Milli 0Water 128 P2122U128 Polvent Blank 91 b12122 1a 10

.000 NTlli 0 Water TN12-0421

Data printed by CJG Page 3 of 3 Printing Time : 12 :4a :59 PM Printing Date : Friday, December 21, 2012-BUster : J2930203 Batch Name : N/A



### Acqasition Infovnetion: isitimMethod: pF(1A only 7500L f1cw .dem ted: FYidsy DECEVbec 21 2012 10 : 51 : 00 PM hkrlified: Friday IY . .ce:b3 21 2012 12 : 42: 53 1M wument : peox only 6ynrlumizetion Mode: lc sync Auto-Ei7silibmtirn : Off Acquisition Duration: l9min0sec N,rt= of Scars: 3619 HSS(rle In File: 1 Acquisition Nmdile: Acquisition hktknd Software versiam Analyst 1 .6 .1 Pgilent LC Pwp Method arpert ies 

## Pump tnxel : Agilent 1100 LC Bunry Rnp Minimum Freesuae (Fei) : 0.0 hsrzimn: Pxessme (pei) : 5801 .0 Dead Volume (wl) : 40.0 Ywdmm FlowRanp (ml/mixY) : 100.0 h9ximm P~ Ramp (psi/ss) : 290.0 vex FlowRamp Up (ml/min') : 100.0 hEx Flow

Barcp Ih (ml/min') : 100.0 Step Table: Star Total 7Lm(min) Flow ,Rate (Wl/min) A (&) B ($) C 0.00 750 90.0 10.0 1 0.50 750 90.0 10.0 2 4.00 750 70.0 30.0 3 6.00 750 70.0 30.0 4 11 .00 750 20.0 80.0 13.00 750 20.0 80.0 6 13.50 750 10.0 90.0 7 16.00 750 10.0 90.0 8 16.50 750 90.0 10.0 9 19.00 750 90.0 10.0 Left CarpttPssibility: 50 .0 Right Qaipxeeslbility: 115.0 Left Dead Volume (MI) : 40.0 Dead Volume (p1)

: 40.0 t Stroke Volume ()al) : -1 0 ~ Stroke Volume (N1) : -1 .0 

### i t Solvent : A1 Right Sol~vent : Bl " Fgilent Autcsaupler PaOPEWties Autassnpler Ncrlel : Agitent 1100 viemoAuto-canpler Syringe Size (al .) : 100 mjecticn Volume ((tl) : 10.00 DrawSpeed (yl/min) : 200.0 aject speed (Al/min) : 200.0 Needle level On) : 0 .00 1H :pevadue amtrol Not used Wash is rot uSed Use custom Inject= pt0 .7tart Pb Agilent Column Oven Properties Left 7Hr[r-taturze (°C) : 30 .00 Right 'la~pe .attrze (°C) : 30.00 1tr:pPlatlrte Tolerance +/- (00: 1 .00 Start AcaluisitimTolerance +/- (*C) : 0.50 TimTable (Used) Om1um switching Valve Installed DEN Position for first sample in the batch; Right Use same, position for all ssrtples in the batch Total Tim

(min) Valve Position 0.0C Left 5.OC Right Period I ; -------------- Scans in period; 3619 Relative Start Tim ; 0.00 rreec i ts in Fexiod: 1

Data printed by CJG Page 1 of 2 Printing Time : 12 :43 :58 PM Printing Date : Friday, December 21, 2012-Buster : J2930203 Sdhedu1ed Mdwt : NJ Fblarity: Nagative Stan [+a3e: N/A IM Sasce: Tunoo Spray Resolution Ql : unit Resolution Q3: Unit Intensity 7hres. : 0.00 cps Sett,ling Tim

: 0.0000 Irsec hR Pause: 5.0070 rteec M7 : : NO Step sin: 0.00 lti Q1 Ness (19) Q3 M75 .5 (I8 .) Dsell(rreec) F9rart Start Stcg IL 433.000 369.000 100.00 a -14.00 -14.00 PbTY-1 CKP -9.00 -9 .00 Ql Mass (7s) 43 hbs.s (W) Dwell (rtezC) FBYNr Start StoF IL 413 .000 219.000 100.00 CE -24.00 -24.00 PFIIA-2 CXf -15.00 -15.00 Ql mass (Da) Q3 Mass (L9) Di .e11(nGec) Ruav Start Stg I 417 .000 169.000 100.00 CE -28.00 -28.00 PFQ'r3 (92= -9.00 -9 .00 Parameter Table(L72io3 I Experiment 1) CAD: 6 .00 QIIi : 35.00 G91 : 45.00 GM : 60.00 IS : -4500 .00 'hM : 450.00 ihe: ¢1

-40.00 eF -10.00 IQ1 10.00

Data printed by CJG Batch Name : N/A

Page 2 of 2 Printing Time : 12 :43 :58 PM Printing Date : Friday, December 21, 2012

## p. 36

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## p. 42 

# Printing Date and Time: 4/29/2013; 1 :01 PM 

# Regressions Peak Name: PFOA No Internal Standard Q1/Q3 Masses: 413.00/369.00, 413.00/219 .00, 413.00/169.00 Da Fit Quadratic Weighting 1 / x Iterate No a0 1 .78E+04 a1 7.88E+05 a2 -4.38E+03 Correlation coefficient 0.9993 Use Area
Curvefit criteria r> 0.994987437

b121221a.xls Regressions Page 4 of 13

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## p. 45 Printing Date and Time; 4/29/2013 ; 1 :01 PM Method Blanks PFOA Sem eName Sem elD Sam p le Comment Am Counts b121221a001 Solvent Blank MIIIIQWater TN12-0421 - 342969 6121221a002 Solvent Blank MIIIIQWater TN12-0421 131558 6121221a003 Solvent Blank MIIIIQWater TN12-0421 48937 6121221a008 SoNentBlank MIIIIQWater TN12-0421 4960 b121221a009 Solvent Blank MIIIIQWater TN12-0421 5965 b121221a025 Solvent Blank MIIIIQWater TN12-0421 4642 b121221a028 Solvent Blank MIIIIQWater TN12-0421 1575 b121221a027 Solvent Blank MIIIIQWaterTN12-0421 5162 b121221a028 Solvent Blank MIIIIQWaterTN12-0421 3846 b121221a038 Solvent Blank MIIIIQWaterTN12-0421 2702 b121221a039 Solvent Blank MIIIIQWaterTN12-0421 4201 b121221e041 Solvent Blank Milli Q WaterTN12-0421 3939 b121221a050 Solvent Blank Milli Q WaterTN12-0421 2911 b121221a052 Solvent Blank Milli Q WaterTN12-0421 3724 b121221a063 Solvent Blank Milli Q WaterTN12-0421 1499 6121221e065 Solvent Blank Milli Q WaterTN12-0421 3168 6121221a076 Solvent Blank MIIIIQWaterTN12-0421 4288 b121221a078 Solvent Blank MIIIIQWaterTN12-0421 3722 b121221a089 Solvent Blank MIIIIQWaterTN12-0421 4562 b121221a091 Solvent Blank MIIIIQWaterTN12-0421 6002 6121221a102 Solvent Blank MIIIIQWaterTN12-0421 3289 b121221a104 Solvent Blank MIIIIQWaterTN12-0421 3524 b121221a115 Solvent Blank MIIIIQWaterTN12-0421 5041 b121221a117 Solvent Blank MIIIIQWaterTN12-0421 5403 b121221a126 Solvent Blank MIIIIQWaterTN12-0421 3103 b121221a128 Solvent Blank MIIIIQWaterTN12-0421 5133 Average Area Counts of Method Blanks I 4015 I %RSD 30 Average Area Counts of Method Blanks Multiplied by TM 8030 _ LOO Standard area counts 39845 LOQ standard conc., ngfmL 0 .0240 vlann up blank- not usedfor LOQ detenninatian vann up blank- not usedfor LOO determination warmup blank- not usedfor LOQ determination

b121221a.xls Method Blanks Page 7 of 13

## p. 46 Printing Date and Time 4/29/2013; 1 :01 PM 

# LCS Recoveries Spiked Sample Conc . Calc. Conc. Name Sample ID Sample Comment (ng/mL) (ng/mL) %Rec . Set average RSD 612~29 LCS-121220-1 0.5ppb LCS b121221a030 LCS-121220-2 0.5ppb LCS b121221a031 LCS-121220-3 0.5 b LCS b121221a032 LCS-121220-4 5ppb LCS b121221a033 LCS-121220-5 5ppb LCS b121221a034 LCS-121220-6 5 b LCS b121221a035 LCS-121220-7 30ppb LCS b121221a036 LCS-121220-8 30ppb LCS b121221a037 LCS-121220-9 30ppb LCS 0.477 0.459 96.1 0.477 0.448 93.9 0.477 0.462 96.9 4.77 4

.84 102 4.77 4

.90 103 4.77 4

.89 103 28.7 I 26.3 1 91 .6 28.7 24.7 86.1 28.7 25.2 87.9 Overall Average 95 .8 %RSD I 6 .6 PFOA

95.6 1 .6 103 0

.56 88.5 3.2

b121221a.xls LCS Page 8 of 13

## p. 47 Pdntlng Date and Time 4/29/2013; 1 :01 PM 

### Sample Result with QC NCv Not Calculated

; Endogenous samplegreaterthan 2xspike level

Dataflle b121221a042 6121221a043 Dilution

1 1 

## GLP10-01-01-39 Rlnseate Blanks PFOA Conc. FMS 3MOMS ID Sample Des,In (ng/mL) %Recovery GLP10-O1-01-39-070 DAL-GW-131S-R6- <0 .0240 NA GLP10-Ot-01-39-071 DAL-GW-145R "RB- ~0 .0240 _ NA
Datafile b121221a048 b121221a049 Average 770 %RPD 4.9
Dilution 6121221a053 10 b121221a054 10 b121221a055 10 Avemge 148 Field Mafdx Spike 101 %RPD 1 .4
Datafile Dilution b121221a056 10 b121221a057 10

Dilution 

## 100 100 DAL GW

130R PFOA
__ - ~ Conc. FMS 3MOMSID Sam p le Descri p

tion n /mL %Recove _ GLP10-01-01-39-001 DAL-GW " 130R-0- I 

### _ _ 751 I 

## NA GLP10-01-01-39-002 _ DAL-GW-130R-DB " 789 NA


### DAL GW

130S PFOA Conc. FMS 3MOMS ID Sam p le Descri ption 

### (11 9 1,01L) YeRecove GLP70-Ot-01-39-003 DAL-GW-130S-0- 147 _ NA GLP10-Ot-01-39-004 DAL-GW-130S-D& 149 NA GLP70-Oi-01-39-005 DAL " GW-130S-FMS- 221 72 .3



### DAL GW

13oL PFOA - _ Cona FMS 3MOMS ID Sam p le Descri ption n /mL %Recove GLP10-01-01-39-006 DAL-OW-130L"00 . I 

## 47.1 I NA GLP10-01-Oi-39-007 DAL-GW-130L-DB- .4 52 NA Average 49 .8 %RPD 11

b121221a058 Dilution

100 

### DAL GW

131R PFOA Conc, FMS 3M UMSID Sam ple Descri ption n mL %Recov GLP10-01-01-39-008 DAL-GW-131R-0- 1590 I NA GLP10-01-01-39-009 DAL-GW-131R-DB- 1870 NA b121221a059 100 Average 1630 %RPD 4.9
Dilution b121221a060 1 b121221a061 1 b121221a062 10 

### DAL OW 131S PFOA Conc . FMS 3M LIMS ID Sam ple Descri ption n mL %Recove GLP10-01-01-39-010 DAL-OW-131S-0- 24 .1 NA GLP70-01-Oi "39-011 DAL-GW-131S-D& 24 .1 NA GLP10-01-01-39-012 DAL-GW-131S-FMS- 40 .7 82

.2 Avenge 24 .1 Field Mablx Spike 20 .2 %RPD 0 .0
Dilution 1,121221a066 10 1,121221a067 10 

### DAL GW 131L PFOA Conc . _FMS 3MOMS ID Sam ple Descri ption n mL %Recove GLPi0-01-01-39-013 DAL-GW-131L-0- I 

### 78 .6 I 

## NA GLP10 .01-01-39-014 DAL-GW-131L-DB- 76 .0 NA Average 77.3 %RPD 3.4
Dilution b121221a068 10 b121221a069 10 

### DAL GW 133R PFOA Conc. - FMS 3M LIMS ID Sam ple Descri ption n /mL %Recov GLP70-01-01-39-015 j DAL-GW-133R-G- _ 69 .6 NA GLP10-01-01-39-016 DAL " GW-133R-DB- 65 NA Average 67.4 %RPD 6.5

b121221a.zls Sample Data WCC Page 9of 13

## p. 48 Pdn9ng Dale and Time 4/29/2013;1 :01 PM 

### Sample Result with OC NC =Not Calculated; Endagenoussample greater than 2x spike level

Dilution b121221a070 10 b121221a071 10 

### DAL GW 133S PFOA - Cona FMS 3M UMSID Sam p le Descri ption n ml %Recove _ GLP70-01-01-39-017 DAL-GW-133S-0- 309 NA GLP10-01-01-39-018 DAL-GW-133S-DB- 318 NA Average 314 %RPD 2.9
Dilution b121221a072 10 b121221a073 10 

### DAL GW 133L PFOA Cono . FMS 3M UMSID Sam ple Descri p

tion n m %Recove_ (31-P10-01-011-39-1319 JUAL-UW-133L-U- 380 NA Average 380 Y .RPD 0 .0
Dilution b121221a074 100 b121221a075 100 

### DAL GW 134R _PFOA Conc. FM 3MLIMS ID Sam p le Descri p

tion n mL ve °/ .R GLP70-01-01-39-021 DAL-GW-134R-0- 1380 NA GLP10-01-01-39-022 DAL-GW-134R-DB- 1380 NA Avenge 1380 %RPD 0.0
Dilution b121221a079 1 b121221a080 1 

### DAL GW 134S PF_OA Cona FMS 3M UMSID Sam p le Descri p

tion n mL Y .R_ecove GLP10-01-01-39-023 DAL-GW-134S-0- 14 .8 NA GLP10-01-01-39-024 DAL-GW-134S-DB- 13 .9 NA Average 14.4 %RPD 6.3
Dilution 1,121221a081 100 b121221a082 100 

### DAL GW 134L PFOA Conc. FMS 3MLIMS ID Sam p le Descri ption n mL _ %Recove GLP10-01-01-39-025 DAL-GW-134L-0- 441 I NA I GLP10-01-01-39-026 DAL-GW-134L-DB- 433 NA Average 437 %RPD 1 .8
Dilution b121221083 100 b121221a084 100 

### DAL GW 135R PFOA _ Conc. FMS 3M LIMS ID sam p le Descri ption n /mL_ %Recove GLP10-01-01-39-027 DAL-GW-135R-0- 3080 I NA GLP10-01-01-39-028 DAL-GW-135R-DB- 3100 NA Average 3080 %RPD 1 .3
Dilution b121221a085 10 b121221a086 10 

### DAL GW 135S PFOA - Cone. FMS 3M UMSID sam p le Descri p

tion n mL _%R_ecove - GLP70-01-01-39-029 DAL-GW-135S-0- 24 .7 1 NA GLP10-01-01-39-030 DAL-GW-135S-DB- 23 .8 NA Avemge 24 .3 %RPD 3 .7
Dilution b121221a087 10 b121221a088 10 

### DAL GW 135L PF_OA_ Conc FM

S 3M UMSID Sam p le Descri p

tion n m %R o ve GLP10-01-01-39-031 DAL-GW-135L-0- 191 I NA GLP10-01-01-39-032 DAL-GW-135L-DB- 186 NA Average 189 %RPD 2.7

b121221a.xls Sample Data wQC Page 10of 13

## p. 49 Printing Date and Time 4129/2013;1 :01 PM 

### Sample Result with OC NC - Not Calculated

; Endogenous sample greaterthan 2xspike level
Dilution b121221a092 10 b1212218093 10 b121221s094 10 

### DAL GW 136S PFOA Conc. FMS 3M UMSID Sam ple Descri ption _n mL %Recove GLP10-01 "01-39-035 DAL-GW-136S-0- 95.4 NA GLP10-01-01-39-036 DAL-GW-136S-DB- 83.7 NA GLP10-01-01-39-037 DAL-GW-138S-FMS- 188 100 Average 94.6 FIeldMauIxSplke 101 %RPD 1 .8
Dilution b121221a095 10 b121221a096 10 

### DAL GW 136L PF_OA - Conc. FMS 3M LIMS ID sam p le Descri p

tion n mL %Recove GLP10-01-01-39-038 DAL-GW-136L-0- 136L 82 .7 NA Average 81 .8 MAD 2.3
Dilution b121221a097 1 b121221a098 1 b121221a098 1 

### DAL GW 137S PFOA Conc. FMS IM LIMSID Sam p le Descri p

tion n mL_ %Recove GLP10-01-01-39-042 DAL-GW-137S-0- 0 .819 NA GLP10-01-01-39-043 DAL-GW-137S-DBI 0 .584 NA GLP10-01-01-39-044 DAL-GW-137S-FMS" 2.02 74 .0 Average 0 .602 Field MahixSpike 1 .92 %RPD 5.8
Dilution b121221a100 1 6121221a101 1 

### DAL GW 137L PFOA Conc. FMS 3M LIMS ID Sam ple Descrl flon n mL %Recove _ GLP10-01-01-39-045 DAL-GW-137L-0- 0 .349 NA GLP10-01-01-39-046 DAL-GW-137L-DB- 0 .329 NA Average 0 .339 %RPD 5 .9
DIlu9on b121221a105 10 b121221a108 10 

### DAL GW 138S PF_OA_ Cono . FMS 3M LIMS ID Sam p le Descri ption n lmL % .Recove- GLP10-Oi-01-39-049 DAL-GW-138S-0- 154 NA GLP10-Oi-01-39-050 DAL-GW-138S-DB- 156 NA Average 155 %RPD 1 .3

b121221a107 6121221a108 Dilution 

### DAL GW 138L P_FOA Conc. FMS 3M LIMS ID Sam p le Descri p

tion n mL %Recove _ GLP10-01-01-39-051 DAL-GW-138L-0- 0.428 NA GLP10-01-01-39-052 DAL-GW-138L-DB- 0.465 NA Averege 0.447 Y .RPD 8.3 '
Dilution b121221009 100 6121221a110 100 

### DAL G W C W26C PFOA Concs FMS 3M UMSID Sam p le DescrI 6on n mL %Rernv GLP10-01-01-39-053 DAL-GW-CW26P0- 353 NA GLP10-01-01-39-054 DAL-GW-CW26GD8- 348 NA Average 351 %RPD 1 .4
Dilution b121221011 100 b121221a112 100 

### DAL GW C W26L PFOA _ Conc. FMS 3M LIMS ID Sam ple Descri p

tion n /mL %Recove GLP10-01-01-39-055 DAL-GW-CW26L-0- 828 I NA GLP10-01-01-39-f156 DAL-GW-CW28L-DB- 620_ NA Average 624 °/aRPD 1 .3

b121221a.xls Sample Data wQC Page 11 of 13

## p. 50 Printing DateandIme 4129/2013

; 1 :01 PM 

### Sample Result with QC NC =NotCalculated; Endogenous sample greaterthan 2x spike level

DIIuBOn b121221a113 10 b121221a114 10 

### DAL GW 140R PF_OA Cono . FMS 3M LIMSID Samto Descrl tlon n mL %Recov_e GLP10-01-01-39-057 DAL-GW-140R-0- 121 NA GLP10-01-01-39-058 not -GW-i40R-DB- 118 NA Average 120 %RPD 2 .5
Dilution b121221a118 1 1,121221 119 - 1 b121221a120 1 

### DAL GW 141R PFOA Conc. FMS 3M LIMS ID Semle Descri p tion n mL %Recove GLP10-01-01-39-059 DAL-GW-141R-0- 1 .88 NA GLP10-01-01-39-060 DAL-GW-141R-DB- 1 .85 1 NA GLP10-01-01-39-081 DAL-GW-141R-FMS- 3.27 73.3 Average 1 .87 Field MatrixSpike 1 .92 %RPD 1 .6
DlluBon b121221a121 10 b121221a122 10 

### DAL GW 142R PFO_A_ Conc. FMS 3M LIMS ID So-P ie Descri ption n mL %Recove GLP10-01-01-39-062 DAL-GW-142R-0- 48.8 I NA GLP10A1-01-39-063 DAL-GW-142R-DI3- 45.5 NA Average, 46.1 °/ .RPD 2.4
Dilution b121221a123 10 1,121221a124 10 b121221a125 10 

### DAL GW 145R PFOA Cons. FMS 3MLIMSID Sam p le Descri ption n ml _5/ . _Wove GLP10-01-01-39-067 DAL-GW-145R-0- 55.8 NA GLP10-01-01-39-068 DAL-GW-145R-DB- 56.3 NA GLP10-01-0139-G89 DAL-GW-145R-FMS- 143 88 .2 Avenge 56.0 FIeldMaulxSplke 101 "/ .RPD 1 .3
Datafile Dilution 6121221a044 1 6121221a045 1 1,121221a046 1 b121221a047 10 

### Tri o Blank PFOA Canc. FMS 3M LIMS ID Sam p le Descri p

tion n mL _%Recove GLP10-01-01-39-072 DAL-GW-TRIP01-0- <0.0240 NA GLP70-01-01-39-073 DAL-GW-TRIP01-LS- 

### ~ 1 .67 87.2 GLP70-01-01-39-074 DAL-GW-TRIP01-MS- 17.1 84.7 GLP10-01-Ot-39-075 DAL-GW-TRIP01-HS- 89 .8 88.9 LowField Matrix Spike 1 .92 MidFieldMatdx Spike 20 .2 High FieldMatrixSpike 101 LOQ 0 .0240 LOQ'10 0.240 LOO-100 2.40

b121221a .bs Sample Data wQC Page 12 of 13

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# A copy ofthe Chain of

Custody can befound in LABWARE LIMS A copy ofthe GPOand/or Protocol can befound in the Lotus Notes GPODatabase 

# Communications Misc -- Note to File

# 3M ENVIRONMENTAL LABORATORY Project or Study Number:

___._ ....... ._._._..__..__w

.._...____..... LIMS Number:-

_ ....-. ..___._.__~--- .___-__

Affected Data: 

# Note to File GLPI0-01-O1-39

_

... .__ ... .._ .._ ...- GLPI 0-01-01-39 

# None All logbook pages for the individual stock standards and mixes used for the calibration curves and LCS used for the analysis of GLP10-01-01-39 were printed to pdf (exact copies of originals) 

# and included in a folder labeled 'Logbook pages for GLP10-01-01-39' located in the projectfolder located at: P:\Projects\Lab_ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

# PFOA\GLP10-01-01-39 FSIA Q4 The chromatograms for results file b121221a were printed to pdf and saved in the project folder 

# located at : P:\Projects\Lab_ESA Analyticai\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 PFOA\GLP10-01-01-39 FSIA Q4 A pdf copy of the signed protocol amendment GLP10-01-01 Amendment 39 is located in the project folder located at P:\Projects\Lab ESA Analytical\Lab Requests 2012 - stw\GLP10-01-01 Decatur Phase 3 

# PFOA\GLP10-01-01-39 FSIA Q4 ~Once the data

package has been reviewedby QA and thereport signed, the

pdfwill be moved to the shared drive (\\usfile01\b2\Projects\Lab Shared\Archive Requests\Electronic Reports) and a reference to the location of the pdf will be added to the archived request formunder Elec Media Path.


# Recorded By: Date: 12~ 2ln ~ 12

# Collection Bottle Prep

Sample Prep 

# Standard Prep (pdfin projectfolder)

# Note To File

Project or Study I Decatur Phase 3-FSIA groundwater 

# Descri tion: i

_._.-__. .~... .._-_

....--- LIMS Nutnbcr : f GLP10-01-O1-39 ._ ..____ ._.__ ....._ ....__ .. ._-_ ._.__. . .. _-.. .-_~.- .___

...... Affected Data: ~ None _ On November 29, 2012, seventy-five 250 mL Nalgene bottles were marked with a 200mL level line and labeled. The trip blank and trip blank spikes werefilled with Milli Q water (TN12-0400) and sealed after they were spiked. Thefield matrix spike bottles for select sampling locations were spiked with the following: Field Matrix Spikes

Well No. Spiking Solution Approx.

Value (pglmL) Spike

Amount (pL) Spike

Cono . tngimL) 

## 137S 12 008-22 10.0 40 2.0 141 R 12008-22 10.0 40 2.0 131S 12009-202 100 40 20 

## 143R 12009-202 100 40 20 130S 12009-202 100 200 100 138S 12009-202 100 200 100 

## 145R 12009-202 100 200 100 12008-22 10.0 40 2.0 Trip Blank Set 12009-202 100 40 20 12009-202 100 200 100 

## A 1-L container of Milli Q Water (TN12-0400) will be provided to be used for the collection of equipment rinseate blanks. - 

# Used Eppendorf Research pipette 3402277to add spiking solution tosamples.



# Recorded By: Date: 

# I1I2q 112Printing 122012012 ; 2 :32 PM GLPiD " 0101-39SamPlePrc,yWO=kShoelyETS-8 St'CJO :721TOh2 "-Fal da "Oai .1. ..~. . t8 Y " ,p -~ le DascrIpUOn

Sa m BamIo1D LCS"121220-7 0 .5uPbLCS ~^ LCS4t72202,- -, D .S ;pbLCS LC-'127220

.3 0

. bIS - LC6127220A 5 b LCS Dilution I NA NA NAJ NA Sam_Ple>liquu-t L), ( I NA

NA '

+- NA NA ~ikin Bid 10

120 09-?,30,_ 12W9 " 134 12W9-13

A SylkaAm(JUL)
_, +0 .50 --50 _ Rea 8anlWatarImL/

10.0 10.0 10.0 100 FinalVol /mLL

,- 70 .05 70 .06

_ 10 .0a 70 .05

_ -_, . . . .-.,- LCS" 1212205 5 LCS LCS_" 12t2208_ -SP

PbLCS LOS-12,12Y0~7 30pObLCS (~ NA NA ' NA _ 6N

NA~_ - NA-_~~ 72008" 133

1200&133 12008-22 50--,

50 30 - ,_ __ 10

.0 ,- 100 10.0 1005 I

7005 1 70,03 ~

- LCS-12i2 9LNPb LC NA A 1 '_ 12008-22 _30 10 .0 70, _ lCS~121220

"9 30pot, LCS NA NA 12008-2 _ 30 10

.0 10

.03 1 p70-01-0t-39{101 DAL"GW-130R-0- Gf 10D 0.700 _ . . . . NA __ NA 9,9 10,0

. OLP10A1At " 39-002 DAL-GW-130RAB " 100 - 0700 NA __ Nq - .--- 9 .9 _ 10

.0- GL70-OtAi " 38-003 DAL" GW " 130S-0- J~ 10 100 - NA NA -~ .. .. 9 .0 iDA Oi-0'1-39^04 DAL" GW " 73UTS'-~- GLP10 i0 100 NA NA, 9 .0 10.0 - .~ "

__ ..-_ . .._ GLP70"OtAi-39-0OS DAL-GW-139S" PMSG . ._, . . . _ , LP10-07"Oi " 39-0OB DAL" GW " 130L-0" 10

10 7,00

1 .00 ~

NA } -,--, NA . -.,. . .-._

NA

_ NA - 9 .0 90_-_-_ 10.0

_ 70.0 GLP10AtAi-39"0D7 _ DAL-GW " 130L-DBGLP70-01 " Dt-39-008 DAL"GW-137R-0- AL-GW " 131R-OB" I UPfO " 01 "01 " 39 10 100 100 7,W

O10( , NA

NA 1 NA - N

A _ NA , 9

.0 9 .9 9 .9 10,0

1D,0 10.0 ~ ---~~--~^- _ 6LP10-Oi

"07-9-010DA4GW " 131S-0 " NA ,,_a

_ " N

A ,_ ," ,

NA NA

_.`!__ NA NA I _ .- ._-_ GLP70-01-01_38-071 DAL-GW-1313 " OB- NA NA NA

_ . NA I

. . " N A NA I GLPfO.O7-0133-D72 DALGW-1315-FM - i0 " 100 NA N 9.0 10 .0 _ _ GLP10-0t-01-3

9 " D73 DA4GW-731L-0 " 10 100 NA NA 9.0 70 .0 GLP70" 07A1~

9"p14 ALGW-79YL-OB" 10 100 NA, - , ,-_- NA _ 9.0 10 .0 GW " 733R " 0 O7-01-39 " D75 I D " GLP10 10 700 NA NA 9.0 10 .0 A L ;" ,, - GLP10" Ot~ A7-08-0i6 ~~DAIrGW-133R-OB- 70 _,_ -, 1 00 NA _

_ NA_ _ . . ~~ ~ ~~ _ 9.0 , 10

.0 GLP70-01-07- 39-0~~DAL-GW " 7335-0- 10 100

_ ._,_, ._ . NA NA 9.0 10 .0 _ GLP70-O7-07-3-07A DAL" GW " 133S-UA

" 70 10 0 NA ~~ - 9,0 - 10,0 I _ GLPt0-O7-01-3

S~Ji8 DAL-GVV

" 733L" 0 " 70 _ 1A0

- NA NA 9,0 -- 700 _, GLP70-01-01 .39"020 DAf--GW-733LDB- t0 7_00 NA -,_-- . ._

.._ NA 9D 70,0 1 _- 3LP10" OtA1-39A21 DAL-GW " 73AR-0-

- . " ~_ 100 OAOD _ NA -," "" NA iD .O I -_ GLP10-07-01-39-02Y DAL" GW " 134R " DB- 100 0 .1110 ,

W

. 7- .. . . _ NA 9,9

_ .

___ _

# -- * ~ _. .-,___. .__--- OLP70-111-01-99-029 D AL" GW " 7JAS-0- NA NA

# NA-

NA NA 

# 77 = OLP10-OtAi-39A24 OAL-GW " 1345-UBGLP7Q-Ol-0'I_39415 DAL-GW " 134L-0- _ GP70-0t "07- 39-028 DAL-GW " 134L-D8 NA

100 100 NA

0 .100 ~~ 0700 NA NA ., NA NA,

NA .,_., ., . . . . __
_ NA

- N A 99 89 1 NA ;

-, 700 1 --- 10 .0 , 01-7 9-0V IDAL-GW

" 135R" 0 " GLP10A7 100 0,700 NA NA 99 ! 100 , ,

" GLP10" Ot "01 " 391128 DAL-GW " 135R-0BGLP70" 07-01-992

-~2 OAL" GW

" 7955-0" 700

10 0700

" --~_.- 1,00 NA

NA - . .. .

NA -- NA -^ 99 I 9,0 " 10

.0 10 .0 1 --"_ I _ GLP10-01 IDAL" GW "1355-11E .- 70 1.00 NA I NA 90 10,0 GLPfOAf "01 " 39-037 DAL-GW-135L0- 10 - -, - ", -1 .00 J -- - !~ , NA

. _._ . ~ 90 70,0 GLP70-O1 :01-09-032 DAL-GVd-735L-D8- 10 100 (!A I
. .-_- . ._ NA _ 8U - __10 .0
. .. ._ . . . &P-10-R-01 " 39-035 DS-0- 10 100 NA .----_ ".-,_" NA 9,0

_ .-. .__.- ._ _ 70 .6 ~ 6LP10-01 "O7" 79

"030 DAL"OW

" 7305-DD- 10 i .00 -'-._, NA NA

_ - .,., . ., .-- - 9.0 10 .0 GLP10;01 " 01 " 39-037 DAL-736S-FMS . 10 1 "00

. .. .. ._. .~ --,_NA NA 9.0

_.- .. .. .. _ 70,0 GLp104147" 39A38 DAL"GW-7361 .-0- W 7 .00

. NA NA 9,0 10 .0 9 IDAL-GW

" 138L -DB- 01-01 9"0 GLP10 10 1,00 NA NA 90 10A i __

a 9 - GLP10" 01-01 " 39

"092 DAl-GW

" 137S-0- NA , NA __

_ _ NA _ ""- _ MNA
___ NA_ NA I GLF10i11-01 " 39-043 bAL-GW " 187S-D B-~ NA NA,_,__ N~ _NA____ _ NA NA~~I GLP10-01-01J9-044 DAL" GW " 137S" FMS- NA NA NA NA _ , NA NA i79A45 DAL-GW

" 737LA " GLP10-01A1 NA NA ( NA NA NA NA I _

, GLP10-0t-01 " 39"046 OAL-GW " 137L" DB- NA

__NA _ NA _

--_-_ . NA

. .. . ._.- NA NA - . . GLP70-01-01 " 39-049 DAI-GW-0385A- 10 1 .00

- - . . . . N ,. . . NA 9.0 _ _ 10 .0 ._.__. I -

. . . -_'__' __- GLP70-07-07-39-0SO DAL-GW-f389-0B " 10 1 .00

_ _-NA ~ NA 9" 0

_. .w,_

. . . 70A GL .. . . .-_-- P70-0t-01 " 39-051 DAL-GW " 13BL-0 " GLP70- t "0739"

0 0Al "GW-f3BL-DB " 7-07" 39-053 DAL-GW-0W26C-0 " LPf0- NA NA f00 ._ NA

'___ . . ._ ..,_ 0.100 NA

NA , ., NA NA

_ .._._ ._. . .. .. . . .. . NA

. .. . . .. .. ..-_. NA NA NA B .9 NA

NA 0 - 0 1 ~ _. . °--

_ --- G 0 GlPt0" 01-07-39A54 DAL-GW-CW26G09-

- " ._ -". . QLPt0AtA

. . 1-39~055 DAL-GW-CW28L-0 " GLP70-0 Y-07-39A56 OAL-GW-CW26LDo . - 100 100 100 -

0,100 0.100 O .tOD ,

NA

-. ._.,__.. . . .- _ _,N NA _-,

NA ~ NA NA

"- -

-- --_- 9.9 - ~

9,9-F 8 .9

~ ,-, ~ 10 .0 ~ 10 .0 70,0 _

-- .-, . .-". GLP70-07-01-39-05% UAL" W " 140R-0- 10

, 1,00

~ NA NA

_ - - - 9,0 10 .0 07-3f)458 OAL-GW-7e,OR-DB- GLP70 1 10 700 NA tJA 9.0 10 .0 - : -0 GLP70-01-01-39

"0 59 DAL-OW-741R

"0 " NA NA - -~ NA ' ~NA ~ I NA GLP10-0t-01-39-0BO OAL-GW-041R " D8 " NA Nq NA NA i NA NA DAL-GW " t41R-FMS" GLP70-01-01-39-061 NA NA ~u ,-, _ NH _ ~

_NA NA ~_ NA

_ GLP7q-01-0139-062 DAL-GW-142R " 4 10 7,00 ~ NA NA , _ I 9

.0 I 10

.0 GLP70-01-0i-34063 DAL-GW " 14W R-UB" 10 1 .00 NA NA 8 .0 10

.0 DAL-GW-146RA---- GLP7-01A

1 " 39~067 10 __
---~ _~ 1 .00 - - NA _

_ NA - 9 .0 1 0

.0

_ GLP10-01-01-39

A068 DAL" GW

" 145R " DB " 10 1 .00 NA IJA __ ' _ _90 1 100 GLP70-01-01-38-069 DAL-GW-145R " FMS- 1 10 100 NA NA _ _

_ __ 9

.0 " 10 .0 GLP70-Ot-01-39-070 DAL-GW-131S-RO- NA NA NA NA NA NA ,_ AL" GW-145R

" RB GLP70 " D1-07" 39-077 ~ D NA NA NA _ NA - NA ~ -___, 1 " 39A72

fDALGWTRCP01~0" _ NA NA NA - NA _ ,_, NA NA OLPID .01-01 -39-073 ,D " NA ~ NA __ _ - NA ~- .__-_ .____ ._ . .

NA _

NA NA

_. GLP70-07-07-39-D

749-D74 !DAL" GW-TRIP0I-MS- NA I NA - NA NA NA NA " , P10-O7-07-39-075 'DAL" GW "TRIP01 " H5- OL i0 J , ,00 ,_NA NA _ ,90 700

_ _ 72R0112 CJG' GLP70-Ot-01-39sam !os diluted wA h Milli U WetartN72-0421 and v one. m xod__ , - 72/20112 CJG

; SWndard curve 12 01 1-30 oliauoted into 2 " mL 91=5s aNOViaI . Ten eut l onela o! Mi1110 I Walor

TN122f wcroa- d ac s0lvenVmethed blanks . forsamaleatluot i 7120I72CJ GLCSSPre pared Using MIII- 0Water TN12A42 

# -"_~ ,__



# - r -~ --~- 1217I1/19CJG Used 6 oonrlod iatta¢L13882Ban 115B168 

# -- ~

STS-8A441 samPla PreP 121220AS 

# L'-3G 12+2D/12 Pago 7 or 1

# Analytical Case Narrative Data Reduction Calculations (excel spreadsheet in project

folder) 

# Control Chart -Analytical Uncertainty (excel spreadsheet in project

folder)

## p. 97 3M Confidential 3MEnvironmental Laboratory Project : GLP10-01-01-39 Sequence b121221a 

# 3M Environmental Laboratory 3M Technical Lead: Susan Wolf

Building 260-5N-17 651-733-9851 ReportAuthor

. Chelsie Grochow Analytical Team

: 

# Chelsie Grochow 

# Analytical Case Narrative for Method ETS-8-44.1

Project GLP10-01-01-39 Decatur FSIA GW- Q4 2092 Sampling

Direct injection analysis of samples Sequence:b121221a 

## Report Date: December 26, 2012
Instrument run summarywill be printed and included in the raw data package. Results table, calibration curves, andchromatograms will be printed to pdf.



# ETS 8-044Analytical Summary Checklist Page 1 of 3

## p. 98

3M Confidential 3M Environmental Laboratory Project: GLP10-01-01-39 Sequence b121221a 

# 1 Project Scope and Data Quality Objective General Projed Outline available. ® yes © No If No, Please briefly describe project scope and DQO GLP 10Yes No 

# 2 Sample Container Preparation Sample container preparation documented in a Note lo File included in the rawdata package. 3 Sample Analysis 

# 3.1 SystemSuitability Initial SystemSuitability area counts with RSD55% and retention time with ® Yes ~ No RSD52%(ETS-8-44 section 13.1) 

# 3 .1 .1 SystemSuitability Deviations NA 

# 3.2 Instrument Calibration Curve type Quadratic, 11x >0.990 Lineadty criteria met (ETS-8-44 section 13.2) Yes No < :t 25% residuals, except LOQof t30%(ETS-8-44 section 13.2) Yes El No Mi d-level calibration points disabled Yes I~ No 

# The highest standard was disabled for PFOA to meet method criteria. 3.3 Continuing Calibration Verification t25%Difference criteria metfor periodic CCVs (ETS-8-44 section 13.2) ~i11 No I 

# 3.3.1 Continuing Calibration Verification Deviations NA 

# 3.4 Method Blanks Method blanks uniquely identified in the run sequence. ® Yes LJ No Average area counts of target analytes In the method blank present at 2, '/ x ( the area counts of the L00standard (ETS-8-44 Section 13.3) ~Yes [i No 

# 3.4.1 Method Blank Deviations NA.



## ETS 8-044 Analytical Summary Checklist Page 2 of 3

## P. 99

3M Confidential 3M Environmental Laboratory Project: GLP10-01-01-39 Sequence b121221a 

# 3.5 Lab Control Spikes t20°/a recovery criteria met (ETS 8-44 Section 13.4) ® Yes I] No <20% RSDprecision (ETS 8-44 Section 13.4) Ix] Yes No 

# 3 .5 .1 Lab Control Spike Deviations NA . 

# 3.6 Sample Replicates

------ RPDfor f ield duplicates <20%(ETS-8-44 Section 13.4) Yes f E] Na 

# 3.6.1 Sample Replicates Deviations NA . 

# 3.7 Field Matrix Spikes t30%recovery criteria met. (ETS 8-44 Section 13.4) ® Yes I [] No 

# 3.7.1 Field Matrix Spike Deviations NA . 

# 3.8 Limit of Quantitation (LOO) A8 LOQs equal the low-level calibration standard concentration with area counts at least twice that of the method blank(s) (ETS 8- E Yes i] No 44 Section 13.2) 

# 3.9 Manual Integrations Manual integration reviewed by another analyst/teamlead (ET -12- 010 .0, section 9) : : Reviewed by: b~Yv~. Date :/2 ® Yes 

## El No 

# 4 Additional analytical notes All data will be reported. 

# 5 Signatures
,en~ 

# 12 .112 Lo112- Analyst Date

ETS 8-044 Analytical Summary Checklist Page 3 of 3

# Buster: AP14000: J2930203 page 1/1

DATB1 2/21 / 12 ANALYST;CJG STUDY NUMBER

" GLPIO-O1-01-39 Matrix: water Sample Prep Date: 12/20/12 Sample Aliquot Date: 2/1 20/12 Mobile Pbase: (A) 2mM ammoniumacetate (B) Methanol TN-A- or standard number (A) 12 015-50 (B) TN12-0342 3/4 Guard (Pre-autosampler) column betasil Cl8 Size: 4.6 mm

X100 mm Type: C18 Sphere size: 5 Part number : 70105-104630 Lot number: 11919 Serial number 10021756 Started 7/25/12 Analytical column betasil C18 Size: 4.6 mm

X 100 mm Type: C18 Sphere size: 5 Part number : 7010$-104630 Lot number : 119 Serial number 10021762 Started 10/9/12 Batch Name: b121221a 

## Printed: Friday, December 21, 2012 12:48 PM