REPORT OF PARTICULATE SO2 AND

FLUORIDE EMISSIONS TESTS

FOR BORAL BRICKS NO. 1 BRICK

KILN Macon, Mississippi April 22, 1999

Boral Bricks Route 4, Box 2 Macon, Mississippi

39341 contact: Burt Sasser ph: 800/748-8888 Boral Bricks P.O. Box 1178 Columbus, Georgia

31902 contact: David Johnson ph: 334/480-2487

Performed By: Environmental Monitoring

Laboratories Ridgeland, Mississippi •601/856-3092

3•Emission Factor Development
Emission Factor Develop for Stack Testing at Boral Bricks. Macon. MS Plant on Aoril 22. 1999 by Environmental

Monitoring

Laboratories,

Ridgeland MS
Schedule: 1.67 cars/hr 3,168 brick/car Brick Weight:

3.49 Ib/fired brick (40 cars/day schedule at time of stack testing) (verified by quality control reports) 1.67 ea•

3,168 l)r-,isk.

3.49 hr

ton 200011•

Emission Factor Develonment: filterable PM

Average Emission Rate (Ib PM hr) Kiln Throughput

(ton hr)
1.51 Ib

1• I• 9.23 ton filterable PM

0.16 Ib/ton
Emission Factor Summary_:
Pollutant

Avg. Emission Rate Avg. Emission Factor PM 1.51 Ib/hr SO 6.93 Ib/hr

• Total Fluorides

3.57 Ib/hr

HF emissions can be conservatively

assumed to equal between 90 and 95% of the Total Fluorides emissions.

Page 1ENVIRONMENTAL MONITORING LABORATORIES,
P.O. Box 655 D 624 Ridgewood Road phone: 601/856-3092 Ridgeland, Mississippi

39158 ./bx 601/853-2151

June 3, 1999 Subject: Boral Bricks.

Macon, Mississippi

On April 22, 1999, Environmental

Monitoring

Laboratories

performed

air emissions

testing for Boral Bricks in Macon,

Mississippi.

Testing

was performed

to determine

emissions

of particulate matter, sulfur dioxide

and total fluoride

(as HF) from the No. 1 Brick Kiln at the request of Boral Bricks.
Test results: Particulate

Emissions SO2 Emissions Fluoride

Emissions #/hr. grains/dscf

#/hr.

ppm

#/hr.

ppm 1.51 0.014

6.93

57

3.57

99
Mr. David Johnson

of Boral Bricks coordinated

the testing project.

Brad McKnight

of Environmental-lVIonitoring Laboratories

was responsible

for sample collection.

Danny Russell of Environmental

Monitoring

Laboratories

was responsible

for particulate

analysis

and for report preparation.

Fluoride

samples

were shipped

to Oxford Laboratories

in Wilmington, North Carolina

for analysis.

Otherwise,

sample custody

was limited to Mr. McKnight

and Mr. Russell. Following is a report of the test.REPORT OF PARTICULATE,

SO2 AND FLUORIDE

EMISSIONS

TESTS BORAL BRICKS

NO. 1 BRICK KILN MACON, MISSISSIPPI APRIL 22, 1999

CONTENTS 1.0 TEST RESULTS page 1 2.0 SOURCE

DESCRIPTION 2 3.0 TEST PROCEDURES 2 4.0 DATA REDUCTION 3 5.0 NOMENCLATURE 6 6.0 CALIBRATION 7 7.0 APPENDICES: 8 A. Field and Laboratory

Data B. Calibrations C. Fluoride Analysis Report (Oxford)

REPORT CERTIFICATION

I certify that I have examined

the information

submitted

herein, and based upon inquires of those responsible

for obtaining

the data or upon my direct acquisition

of data, I believe the submitted information

is true, accurate and complete.

Daniel G. Russell1.0 Test Results:

The following

table is a technical

summary

of the measured

flow parameters and test results for particulate,

SO2, and fluoride

emissions

testing done on April 22, 1999 for Boral Brick's No. 1 Brick Kiln in Macon, Mississippi.

Run No Time Start Time End PARTICULATE

EMISSIONS PARTICULATE EMISSIONS SO2 EMISSIONS SO2 EMISSIONS F1 EMISSIONS F1 EMISSIONS VOLUMETRIC

FLOWRATE VOLUMETRIC FLOWRATE VELOCITY STACK TEMPERATURE MOISTURE SAMPLE RATE #/hrgr/dscf #/hrppm#/hrppm

ft./sec.

% isokinetic

1 4/22/99 1009 11091.42 0.013 8.8671.93.93 107.4 22070 12370 40.63988.3

2

3 4/22/99 4/22/99 1119 1228 1120 1329 1.68 0.016 6.80 55.83.5798.5 21892 12226 40.34048.0 1.42 0.014 5.12 42.53.2189.9 21860 12079 40.24088.5100

AVG.

0.014 6.9356.73.5798.6

40.4

102 106 100 1.512.0 SOURCE

DESCRIPTION: Source description

here is limited to a description

of the stacks and sampling

site. Boral Bricks may be consulted

for detailed

descriptions

of the process and of operating

conditions

during the test The No. 1..Brick Kiln exhausts

to the atmosphere

by way of a 40.75 inch diameter

vertical stack extending

through

the roof of the building

housing

the kiln. Two sample ports at 90 °
are provided

at a location

37.5 inches below the stack exit and 114 inches above the point where the fan duct enters the stack.
3.0 TEST PROCEDURES: Test procedures

used are those described

in the Code of Federal Regulations,

Title 40, Part 60, Appendix

A.. Specifically,

Method

1 was used to determine the number

of sample points and Methods

5, 6 and 26A were used to measure velocity, moisture,

and particulate,

SO2 and fluoride

emissions.

The Method

6 option of using the particulate

sample train for SO2 determination

was used. Sample duration

was 60 minutes for each of triplicate

samples. Filters were recovered

by rinsing the front half of the filter holder into the probe wash and securing the filters in glass petri dishes. Part of the sample filter normally

adheres to the filter gasket, and some of the adhering

material

is recovered

into the probe wash. Therefore

some of the filter weight is attributed

to the probe wash weight.

Filters were heated in an oven for 2 hours at 105 C, desiccated

at least 24 hours and weighed

to constant

weight.

Probe wash samples•in acetone were e•zaporated_to

dryness•ver

low heat in tared_beakers,

desiccated

format least 24 hours and weighed

to constant

weight.

Weighings

were made at 6 hour or greater intervals (samples

stored in desiccator).

Final weights were considered

valid and were recorded if there was no more than 0.5 milligrams

difference

from the previous

weighing. The back half samples

in 3% hydrogen

peroxide

distilled

water were recovered

and an aliquot removed for sulfur dioxide analysis.

Following

gravimetric

analysis

for particulate,

the filter and probe wash residue was added to the impinger

catch. Those samples

were shipped

Oxford Laboratories for analysis

by IC-HPLC

as described

in Method

13.4.0 DATA

REDUCTION4 Boral Bricks No.1 Brick Kiln PM/F1 Emissions

Test April 22, 1999 Collected Test Data: RUN

RUN 2 RUN 3 Date 4/22/99

4/22/99

4/22/99 Time start 1009

1119

1228 Time end 1109

1120

1329 1. As

sq ft 9.0570

9.0570

9.0570 2. Dn

in. 0.336

0.336

0.336 3. Cp

dimensionless 0.84

0.84

0.84 4. Theta

minutes 60.00

60.00

60.00 s. y

dimensionless 1.01

1.01

1.01 6. Pbar

in. Hg
z pg

in. H20 8. Vm

cf (dry gas) 9. sqr(AP),avg

in.H20^.5 0.5501 lo. AH

in. H20 2.8308

2.5125

2.4625 11. ts

degrees F 397.71

404.21

408.29 12. tm

degrees F 77.17

79.71

82.83 18. Vlc

ml 103

92

98 14. CO2

percent 2.50

2.50

2.50 15. 02

percent 18.00

18.00

18.00 is CO 0.00

0.00 percent 17. M,PM

milligrams 18. M,F

milligrams 29.74

29.74

29.74 -0.22 -0.22

-0.22 53.577 50.491

50.337 0.5590 0.5528

0.00 46.1 51.8

44.1 128.00 110.00

99.50

403.40

SO2 Sample

Weight

Determination Coll•ata

Vsoln ml 500

500

500 'Va ml 10

10

10 Calculation RUN NO. 2

3 M,SO2 N(Vt-Vtb)(Vsoln/Va)(32.03 mg/meq)

288.27

209.80

158.55 RUN N0. 2 Vt-Vtb ml 18

13.1

9.9 N meq./ml 0.0100

0.0100

0.0100Boral Bricks No. 1 Brick Kiln PM/F1 Emissions

Test April 22, 1999 Calculations:

RUN

RUN 2 RUN 3 AVG.

•. Pm

in.Hg

(DH/13.6)+Pbar 29.9481

29.9247

29.9211 z Ps

in. Hg

(Pg/13.6)+Pbar 29.7238

29.7238

29.7238 3. An

sq ft

((Oral24)^2)(3.1416 6.16E-04

6.16E-04

6.16E-04 4. Vmstd

dscf

Vm Y(Pm/Pstd)(Tstd/Tm) 53.239

49.897

49.453

50.863 s. Vwstd

scf

(.04707cf/ml)(Vlc) 4.848

4.330

4.613 6. Bws

dimensionlessVwstd/(Vwstd+Vmstd) 0.0835

0.0799

0.0853

0.0829 z Md

mol.wt, dry basis .44 co2+.32 O2+.28(CO+N2) 29.12

29.12

29.12 s. Ms

mol.wt, wet basis Md(1-Bws)+l

8 Bws

28.19

28.23

28.17 9. Vs

ft/sec Kp Cp (sqrDP)sqr(Ts/(Ps

Ms))

40.61

40.29

40.23

40.37 lo. Q

cfm

Vs As(60 sec/min)

22070

21892

21860

21940 •' Qstw

scfm

Q(Ps/Pstd)(Tstd/Ts) 13497

13287

13206

13330 •2. Qstd

dscfm

Qstw(1-Bws) 12370

12226

12079

12225
• I

percent [(100 Ts)(.002669

Vlc+(Vm Pm/Tm)]/(60

theta Vs Ps An)

105.51

100.05

100.37

101.98 Particulate Emissions 1. E,PM

pounds/hr(M,PM/Vmstd)(Qstd)(60)/(453590) 1.42

1.68

1.42

1.51
z C,PM

grains/dscf(M,PM/Vmstd)(.Ot54 grainslrng)

0.O13•

•.0•60

•137

0_0144• S02 Emissions

•- E,SO2

pounds/hr(M,S

O2/Vmstd)(Qstd)(60)/(453590) 8.86

6.80

5.12

6.93
z C,SO

ppm

(M,S O2/Vms td)(13.27)

71.9

55.8

42.5

56.7 Fluoride Emissions 1. E,F

pounds/hr(M,Fl/Vmstd)(Qstd)(60)/(453590) 3.93

3.57

3.21

3.57
z C,F

ppm

(M,Fl/Vmstd)(44.68) 107.4

98.5

89.9

98.65 5.0 NOMENCLATURE
SYMBOL

UNITS

As t2 Bws dimensionless CO•COCpC,X percent percent dimensionless
as labeled

Nozzle cross sectional area Stack cross sectional area Wet gas fraction Carbon dioxide content by volume Carbon monoxide content by volume Pitot correction factor Concentration of pollutant X DGF dimensionless

Dry gas fraction Dn inches

Nozzle diameter All in. I-IzO

Pressure drop across meter orifice AP in. FIfO

Stack gas velocity pressure E,X #/hr E'X #/MM Btu F dscfpercent consistent milligrams #/#mole M,X Md

Emission rate of pollutant X Emission rate of pollutant X Volume of flue gas per MM Btu Nozzle velocity/stack

gas velocity

DESCRIPTION

Pitot tube constant Sample weight of pollutant X Dry molecular weight of stack gas Ms #/# mole

Wet molecular weight of stack gas N2 9ercent

Nitrogen content by volume, dry basis O percent

Oxygen content by volume, dry basis in. Hg Pg in. Hg Pm in, Hg Ps in. Hg

Barometric pressure Stack static pressure Total pressure at meter (Pbar+(DH/13.6) PstdQQstclQstdw Total stack pressure (Pbar+(Pg/13.6)) in. Hg

Standard barometric pressure 29.92 acfm Volumetric flow rate at stack conditions d•cfrn Volumetric flow rate at standard condi•ons•dry

basis scfm minutes Volumetric flow rate at standard conditions, wet basis Sample duration tan °F

Meter temperature (Txn denotes "R) ts °F

Stack temperature (Ts denotes "R) Tstd °R

Standard temperature

528°R Vlc ml

volume of water collected Vm ft

Volume of dry gas sampled through meter Vmstd dscf Vwstd scf Y dimensionless

Sample volume at standard conditions Sample volume of water vapor Meter coefficient Excess air Xsair percent6.0 CALIBRATIONS: Measurement devices used by Environmental

Monitoring

Laboratories

and subject to changes in measurement precision are initially calibrated

prior to use. Those instruments

for which calibration

factors are subject to change or for which calibration

checks are required, are calibrated

following

each field use or as otherwise

directed and noted. Calibration procedures

for specific equipment

are as follows. Dry Gas Meter: Dry gas meters are periodically

removed from the sampling consoles and cleaned and repaired (new gaskets etc. as required). Following

the overhaul of a meter, the measuring

precision is checked by the Bell Prover Method and adjusted when necessary

to read to within 2% of 100% accuracy.

This service is provided by Big Three Meter Company in Jackson, Mississippi.

Overhaul

service or any six month period is followed by a five point calibration described in APTD-0576

using either a wet test meter or calibrated

dry gas meter (used exclusively

for calibrations)

as a standard reference.

Following

field use, a gas meter calibration

is checked in one of two ways. [1] Three calibration checks at intermediate

orifice settings are performed

or [2] orifice meter coefficients

are used. If a meter coefficient

obtained from pre-test and post-test checks differs by more than 5%, the coefficient

(Y) giving the lower sample volume is used in the calculations. Orifice: The orifice coefficient

is initially determined

and is rechecked

following

a major gas meter repair and calibration. Nozzles: Nozzles are checked before each field use with a precision (.001 in.) dial caliper. Three measurements

on different axes are made; an average of those three readings is used in calculations.

If the tolerance among measurements

exceeds 0.004 inches (highest to lowest reading) the nozzle is repaired and recalibrated

or discarded. Pitot Tubes: Pitot tubes meeting EPA geometry

standards are assigned a coefficient

of 0.84. Pitot tubes are visually inspected for damage before, during and after use. Those pitot tubes not meeting the geometry

standards are assigned a coefficient from the manufacturer's

calibration

which it retains unless damaged.

All pitot tubes used by Environmental

Monitoring Laboratories are manufactured

by NuTech, Inc. Temperature Measuring

Instruments: All temperature

measurements

are made with type K thermocouples

and digital thermocouple

thermometers,

which have an initial calibration

traceable to NBS. Thermocouples

are checked during a test series against an ASTM mercury in glass thermometer

at ambient temperature.

Continuity

and proper thermocouple

contact location are checked by challenging the thermocouple

with a temperature

change. (EMTIC GD-028

June 21, 1994) Barometer: Aneroid field barometers

are checked against and adjusted to readings from a mercury barometer

or readings obtained from local weather authorities. Differential Pressure Gauges: Velocity head (delta P) and orifice pressure differential

(delta H) measurements

are made using water manometers

of the appropriate

range unless otherwise

noted in the test data. Manometers

do not require calibration.REPORT OF PARTICULATE SO2 AND

FLUORIDE EMISSIONS TESTS

FOR BORAL BRICKS NO. 1 BRICK

KILN Macon, Mississippi April 22, 1999

Boral Bricks Route 4, Box 2 Macon, Mississippi

39341 contact: Burt Sasser ph: 800/748-8888 Boral Bricks P.O. Box 1178 Columbus, Georgia

31902 contact: David Johnson ph: 334/480-2487

Pe.rformed By: Environmental Monitoring

Laboratories Ridgeland, Mississippi •'601/856-3092

)aEmission Factor Development Emission Factor Oeveloo for Sfa•-k Testino_ at Boral Bricks. Macon. MS P;a•t on ADHI 22. by Environmental

Monitoring

Laboratories,

Ridge•and MS Schedule: 1.67 carslhr 3,168 brick/car Brick Weight:

3.49 Ib/fired brick (40 cars/day schedule at time of stack testing) (verified by quality control reports) 1.67 saFhr

3,168 brisk

3.49 tb 9.23 ton/hr ton 2000tb

Emission Factor Develooment; filterable PM

Average Emission Rate (Ib PM / hr) Kiln Throughput

(ton / hr) 1.51 Ib k• k• 9.23 ton filterable PM

0.16 Ib/ton Emission Factor Summary, Pollutant

Avg. Emission R•e

IAvg. Em!_=_,=!on Factor PM 1.51 Ib/hr

0.16 Ib/ton !SO2 6.93 Ib/hr

0.75 Ib/ton Total Fluorides

3.57 Ib/hr

0;39 Ib/ton HF emissions

can be conservatively

assumed to equal between 90 and 95% of the Total Fluorides emissions.

Page IENVIRONMENTAL MONITORING P.O. Box655 D 624 Ridgewood Road Ridgeland, Mississippi

39158 LABORATORIES,phone: 601/856-3092 fax 601/853-2151

June 3, 1999 Subject: Boral Bricks.

Macon, Mississippi

On April 22, 1999, Environmental

Monitoring

Laboratories

performed

air emissions

testing for Boral Bricks in Macon,

Mississippi.

Testing

was performed

to determine

emissions

of particulate matter, sulfur dioxide

and total fluoride

(as HF) from the No. 1 Brick Kiln at the request of Boral Bricks.
Test results: Particulate

Emissions

1.51 grains/dscf 0.014 S02 Emissionsppm 6.93

57
Mr. David Johnson

of Boral Bricks coordinated

the testing project.Fluoride

Emissionsppm 3.57 99 Brad McKnight

of Environmental Monitoring

Laboratories

was responsible

for sample collection.

Danny Russell of Environmental

Monitoring

Laboratories

was responsible

for particulate

analysis

and for report preparation.

Fluoride

samples

were shipped

to Oxford Laboratories

in Wilmington, Norffi Carolina

for analysis.

Otherwise,

sample custody

was limited to Mr. McKnight

and Mr. Russell. Following is a report of the test.REPORT OF PARTICULATE,

SO2 AND FLUORIDE

EMISSIONS

TESTS MACON, MISSISSIPPI APRIL 22, 1999

CONTENTS 1.0 TEST RESULTS 2.0 SOURCE

DESCRIPTION 3.0 TEST PROCEDURES 4.0 DATA REDUCTION 5.0 NOMENCLATURE 6.0 CALIBRATION 7.0 APPENDICES: A. Field and Laboratory

Data B. Calibrations C. Fluoride Analysis Report (Oxford) page 1223678

REPORT CERTIFICATION
I certify that I have examined

the information

submitted

herein, data or upon my direct acquisition

of data, I believe the submitted information

true, accurate and complete. is Signed Daniel O. Russell1.0 Test Results:

The following

table is a technical

.summary

of the measured

flow parameters and test results for particulate,

SO2, and fluoride

emissions

testing done on April 22, 1999 for Boral Brick's No. 1 Brick Kiln in Macon, Mississippi.

Run No 1

2

3

AVG. Date 4/22/99

4/22/99

4/22/99 Time Start 1009

1119

1228 Time End 1109

1120

1329 PARTICULATE EMIS S IONS PARTICULATE EMISSIONS SO2 EMISSIONS SO2 EMISSIONS F1 EMISSIONS F1 EMISSIONS :VOLUMETRIC

FLOWRATE VOLUMETRIC FLOWRATE VELOCITY STACK TEMPERATURE MOISTURE SAMPLE RATE #/hrgr/dscf #/hrppm#/hrppmacfm dscfm ft./sec. F%% isokinetic

1.42 0.013 8.8671.93.93 107.4 22070 12370 40.63988.3106

1.68 0.016 6.80 55.83.5798.5 21892 12226 40.34048.0100

1.42 0.014 5.12 42.53.2189.9 21860 12079 40.24088.5100

1.51 0.014 6.9356.73.5798.6 21940 12225 40.44038.31022.0 SOURCE

DESCRIPTION: Source description

here is limited to a description

of the stacks and sampling

site. Boral Bricks may be consulted

for detailed

descriptions

of the process and of operating

conditions

during the test The No. 1 Brick Kiln exhausts

to the atmosphere

by way of a 40.75 inch diameter

vertical stack extending

through

the roof of the building

housing

the kiln. Two sample ports at 90 ° are provided

at a location

37.5 inches below the stack exit and 114 inches above the point where the fan duct enters the stack. 3.0 TEST

PROCEDURES: Test procedures

used are those described

in the Code of Federal Regulations,

Title 40, Part 60, Appendix

A.. Specifically,

Method

1 was used to determine the number

of sample points and Methods

5, 6 and 26A were used to measure velocity, moisture,

and particulate,

SO2 and fluoride

emissions.

The Method

6 option of using the particulate

sample train for SO2 determination

was used. Sample duration

was 60 minutes for each of triplicate

samples. Filters were recovered

by rinsing the front half of the filter holder into the probe wash and securing the filters in glass petri dishes. Part of the sample filter normally

adheres

to the filter gasket, and some of the adhering

material

is recovered

into the probe wash. Therefore

some of the filter weight is attributed

to the probe wash weight.

Filters were heated in an oven for 2 hours at 105" C, desiccated

at least 24 hours and weighed

to constant

weight.

Probe wash samples in acetone were evaporated

to dryness

over low heat in tared beakers,

desiccated

for at le•o•t 24-hours•and•veighed to co•ast•s•t

weight.

Weighings

were made at 6 hour or greater intervals (samples

stored in desiccator).

Final weights

were considered

valid and were recorded if there was no more than 0.5 milligrams

difference

from the previous

weighing. The back half samples

in 3% hydrogen

peroxide

distilled

water were recovered

and an aliquot removed for sulfur dioxide

analysis.

Following

gravimetric

analysis

for particulate,

the filter and probe wash residue was added to the impinger

catch. Those samples

were shipped

Oxford Laboratories for analysis

by IC-HPLC

as described

in Method

13.Boral

Bricks No. 1 Brick Kiln PM/F1 Emissions

Test April 22, 1999 Collected Test Data: Date Time start Time end As sq ft Dn in. Cp dimensionless 4. Theta

minutes 5. y

dimensionless n" Pbar

in. Hg z pg

in. H20 s. Vm

cf (dry gas) sqr(•P),avg in.H20^.5 •o. AH

in. H20 tl. ts

degrees F 12. tm

degrees F •3. Vlc

ml 14. CO2

percent is. 02

percent 16. CO

percent lz M,PM

milligrams is. M,F

milligrams SO2 Sample

Weight

Determination Collected data RUN NO. Vt-Vtb ml RUN1 4/22/99 1009 1109 9.0570 0.336 0.84 60.00 1.01 29.74 -0.22 53.577 0.5590 2.8308 397.71 77.17 1032.50 18.00 0.00 46.1 128.00

RUN2 4/22/99 1119 1120 9.0570 0.336 0.84 60.00 1.01 29.74 -0.22

RUN 3 4/22/99 1228 1329 9.0570 0.336 0.84 60.00 1.01

50.491 0.5528 0.5501 2.5125 404.21 79.71922.50 18.00 0.0051.8 110.00 29.74 -0.22 50.337 2.4625 408.29 82.83982.50 18.00 0.00 44.1 99.50

118 213.1

39.9
10 N meq./ml 0.0100.

0.0100

0.0100 Vsoln ml 500

500

500 Va ml Calculation RUN NO. 1

2

3 M,SO2 10

10 N(Vt-Vtb)(Vsoln/Va)(32.03 mg/meq)

288.27

209.80

158.55

403.40Boral

Bricks No. 1 Brick Kiln PM/F1 Emissions

Test April 22, 1999 Calculations:

•- Pm

in.Hg
2. Ps

in. Hg

3. An

sq ft

(DH/13.6)+Pbar (Pg/13.6)+Pbar ((Dn/24)^2)(3.1416) 4. Vmstd

dscf

Vm Y(Pm/Pstd)(Tstd/Tm) s. Vwstd

scf

(.04707cffml)(Vlc) a Bws

dimensionlessVwstd/(Vwstd+Vmstd) RUN 1 RUN 2 RUN 3 AVG.

z Md

mol.wt, dry basis .44 co2+.32 O2+.28(CO+N2) s.' Ms

mol.wt, wet basis Md(l-Bws)+18

Bws 9. Vs

ft/sec Kp Cp (sqrDP)sqr(Ts/(Ps

Ms)) ,o. Q

cfm

n. Qstw

scfm

Vs As(60 see/rain) Q(Ps/Pstd)(Tstd/Ts) •z Qstd

dscfm

Qstw(1-Bws) z3. I

percent [(100 Ts)(.002669

Vle+(Vm Pro/Tin)I/(60

theta Vs Ps An) Particulate Emissions 1. E,PM

pounds/hr(M,PM/Vmstd)(Qstd)(60)/(453590)
z C,PM

grains/dscf(M,PM/Vmstd)(.0154 grains/mg)

29.9481 29.7238 6.16E-04 53.239 4.848 0.0835 29.12 28.19 40.61 22070 13497 12370 105.5I

1.42

29.9247

29.9211 29.7238 29.7238 6.16E-04 49.897 4.330 O.O799 29.12 28.23 40.29 21892 13287 12226 6.16E-04 49.453 4.613 0.0853 29.12 28.17 40.23 21860 13206 12079 100.37

50.863

0.0829

40.37 21940 13330 12225 101.98 100.05

1.68 1.42

1.51 0.0133 0.0160

0.0137

0.0144 S02 Emissions
•- E,SO2

poundshtr0Vl,SO2/Vmstd)(Qstd)(60)/(453590) C,SO ppm

(M,SO2/Vmstd)(13.27) Fluoride Emissions 1. E,F

pounds/hr(M,Fl/Vmstd)(Qstd)(60)/(453590) 2. C,F

ppm 8,8671.9

6.80

5.12 55.8 42.5

6.9356.7

3.93 3.57

3.21

3.57 (M,Ft/Vmstd)(44.68) 107.4

98.5

89.9

98.66.0

CALIBRATIONS: Measurement devices used by Environmental

Monitoring

Laboratories

and subject to changes in measurement precision are initially calibrated

prior to use. Those instruments

for which calibration

factors are subject to change or for which calibration

checks are required,

are calibrated

following

each field use or as otherwise

directed and noted. Calibration procedures

for specific equipment

are as follows. Dry Gas Meter: Dry gas meters are periodically

removed from the sampling consoles and cleaned and repaired (new gaskets etc. as required). Following

the overhaul of a meter, the measuring

precision

is checked by the Bell Prover Method and adjusted when necessary

to read to within 2% of 100% accuracy.

This service is provided

by Big Three Meter Company in Jackson, Mississippi.

Overhaul

service or any six month period is followed by a five point calibration described in APTD-0576

using either a wet test meter or calibrated

dry gas meter (used exclusively

for calibrations)

as a standard reference.

Following

field use, a gas meter calibration

is checked in one of two ways. [1] Three calibration checks at intermediate

orifice settings are performed

or [2] orifice meter coefficients

are used. If a meter coefficient

obtained from pre-test and post-test checks differs by more than 5%, the coefficient

(Y) giving the lower sample volume is used in the calculations. Orifice: The orifice coefficient

is initially determined

and is rechecked

following

a major gas meter repair and calibration. Nozzles: Nozzles are checked before each field use with a precision

(.001 in.) dial caliper. Three measurements

on different axes are made; an average of those three readings is used in calculations.

If the tolerance

among measurements

exceeds 0.004 inches (highest to lowest reading) the nozzle is repaired and recalibrated

or discarded. Pitot Tubes: Pitot tubes meeting EPA geometry

standards

are assigned a coefficient

of 0.84. Pitot tubes are visually inspected

for damage before, during and after use. Those pitot tubes not meeting the geometry

standards

are assigned a coefficient from the manufacturer's

calibration

which it retains unless damaged.

All pitot tubes used by Environmental

Monitoring Laboratories are manufactured

by NuTech, Inc. Temperature Measuring

Instruments: All temperature

measurements

are made with type K thermocouples

and digital thermocouple

thermometers,

which have an-it•at-catibrafxmtraceabtea•o-NBS. Thermocouples

are checked during a test series against an A•'I'M mercury in glass thermometer

at ambient temperature.

Continuity

and proper thermocouple

contact location are checked by challenging the thermocouple

with a temperature

change. (EMTIC GD-028

June 21, 1994) Barometer: Aneroid field barometers

are checked against and adjusted to readings from a mercury barometer

or readings obtained from local weather authorities. Differential Pressure Gauges: Velocity head (delta P) and orifice pressure differential

(delta H) measurements

are made using water manometers

of the appropriate

range unless otherwise

noted in the test data. Manometers

do not require calibration.7.0 APPENDICES
Field

and. •yfical

Daa B. Calibrations C. Huoride

•ysis

Report

(Oxford)SOURCE: TEST

FOR: ORS" Date:

SKETCH,OF STACK

STACK DIAMETER: Distance from ports to disturbance: A, to upstream

disturbance B, to downstream

disturbance Upstream diameters: Downstream diameters: Minimum No. sample points required: No. sample points selected: Port Length:

"•',•" Port, Type: Port Access:MINIMUM

NO. OF POINTS ON A DIAMETER downstream diometers 0.5 1.0

1.5

2.0 _v_ejocit• l 20 .• 16_.L 12'' 2 .0

4 .0

6 .0

8 .0 upstream diameters PERCENT

OF DIAMETER poinls on a diameter

. 2 4 6 8 10 12 14 16 No. 14.6 6.7 4.4 3,2 2,6 2,1 1.8 1.6 2 85.4 25.0 14.6 10.5 8,2 6.7 5.7 4,9 3 75.0 29.6 19,4 14.6 11.8 9.9 8.5 4 93.3 70.4 32.3 22.6 17.7 14.6 12,5 5 85.4 67,7 34,2 25.0 20.1 16.9 6 95,6 80,6 65,8 35.6 26,9 22,0 7 89.5 77.4 64.4 36,6 28.3 8 96.8 85.4 75,0 63.4 37.5 9 91.8 82.3 73.1 62.5 10 97.4 88.2 79.9 71.7 93,3 85,4 78.0 •2 97.9 90.1 83.1 13 94,3 87.5 M 98,2 91,5 15 95.1 16 98.4 ink:h:es velocity

head-Source: "rest

For: /Test Operators: •eter •o× mple Box Probe/Pitot Pitot Cp Nozzle Dia. Filter No. Arab. Temp OF Bar. Press. "Hg Static Press. "Hg

....--. •.'• Port lJ'Elapsed lJ

DGM Point II Time tl Reading tl M,o/soo II

Ft."

No. Sample Pts.

[•Kq.- Minutes/Pt. •,•'•
K FACTOR SETUP Meter Temp

•O•" % H20

/• Stack Temp.

q•O ( .q£:• •: Factor

f.• q.o•

GAS ANALYSIS: o2 I g COTime CONDENSATE: init. •) final SILICA GEL: init. 3•- final 737

Notes: "'0 .•a,"

Head AP in. H20

Orifice AH in. H•O

LJA Sample Train: •ak Checks: JJpit°t Tubes:

High ENVIRONMENTAL MONITORING

LABORATORIES,

INC. RIDGELAND, MISSISSIPPI

601/856-3•g)2

Stack Temp o F Oven Temp. o F

.00• cfm @•"Hg

Pretest:

Sample Train Pitot Tubesbource:

__._•. Test For: pitt Test Operators:

-,, *•.ter Box .mple Box

•i•1•.•. Probe/Pitot Pitot Cp Nozzle Dia. Filter No. !Amb. Temp.°F Bar. Press. "Hg

] ¢ Static Press. "Hg

I. • RUN NO. ____• Date ,••

K FACTOR SETUP N°tes:

AH@ Meter Temp % H20 Stack Temp. K Factor le CONDENSATE: init. • SILICA GEL: init. •)

• (7i; •se•

DGM rne Reading Cse• Ft.3

Velocity

tl Orifice Head Ap

AH in. H•O

in. H•O

• "It ic i :i1 2-!'i•0 '1"1

Sample Train:

•0/-->

•,/•7 • Checks: Pitot Tubes:

High

@ • H20

Low

S tack Temp o F

in

it Meter Temp

il Oven OFi[ out

Pretest: Sample Train Pitot Tubes ENVIRONMENTAL MONITORING

LABORATORIES,

INC. RIDGELAND, MISSISSIPPI

6a11/856-31•)2Source: Test

For:. Test Operators: ,mple Box Probe/Pitot No. Sample Pts.

• Minutes/Pt. Q,. •- K FACTOR SETUP AH@ GAS ANALYSIS: CO•COTime Nozzle Dia. Filter No. Amb, Temp. OF"

• • Bar, Press. "Hg

_¢ q.7q Static Press. "Hg

,--.'q,,,-•.- CONDENSATE: init. •0 final SILICA GEL: init. •3"• final Port Tim Point linlm

DGM

Velocity

Orifice Reading Head AP

AH Ft, in. H20

in. H•O

Leak Checks:

Sample Train: Pitot Tubes: Stack Te•np o F

Meter Temp o F in out

ENVIRONMENTAL MONITORING

LABORATORIES,

INC, RIDGELAND, MISSISSIPPI

6III/•56-3|•)2 RUN NO. Date

•

Notes:

Imp. Temp. Telnp OF

Sample Train Pitot TubesSAMPLES: DATE

TAKEN: DELIVERED BY: ANALYZED BY:

7._ ---• • DATE ANALYZED: /# RECEIVED

BY:

FILTERS: (Attach chain of custody if additional exchanges occur) [, RUN

NO. 'FILTER NO. FILTER TARE, gins. ]FINAL WEIGHT,

gms. NET GAIN, gms. I,.C3o•

o2f7

5-'7o• II

PROBE WASH: RUN NO. CONTAINER I.D. VOLUME INTACT? VOLUME, ml
TARE WEIGHT,

gms.

FINAL WEIGHT,

gms NET GAIN, gins. LESS BLANK,

gms.

(//)
/or.deo

¢
PARTICULATE SAMPLE

WEIGHT:SAMPLES: DATE

TAKEN: DELIVERED BY: ANALYZED BY: DATE ANALYZED:

t• RECEIVED BY:

/"•,
(Attach chain of custody if additional exchanges occur) Standardize BaC12 titration

H2SO4 H2SO 4 normality Volume,

ml

BaC12 Volume, ml

BaCI2 normality *

*N BaCl, ((ml H2SO4)(N H2SO4))/(ml

BaClx) B aCI2 Normality

= 9 • O '• i•ll•J•lll•F, tf•'•Iit•t•'•l•!•l•ll•l•g•/•.•l.•/il•:[|• •"•J•'•

";l• "•",'

•" Sample Ti•ations: Sample ID

Sample Aliquot Volume, ml

Volume,

ml

BaC12 Volume, ml I• .o /_?.••.!

RemarksDRY GAS METER

CALIBRATION

Meter ID Calibration Method Calibration Meter ID Date NuTech (2298915) DGM/DGM 651729 4/26/99

By WBM Pbar 29.50

Va•.

222 DH Time in. min H•O1.90 15.00 1.90 15.00 1.90 15.00 Callbratin•

Meter Vi Vf !Temp

Vi

Vf ft 3 ft 3 F ft 3 ft 3 234.770 246.036

66 468.888

480.126 246.036 257.125

72 480.126

491.120 257.125 268.058

74 491.120

501.945 FleidMeter Temp.

in Temp out init. final 74 76 74 75 76 78 75 76 78 79 76 77 Y

1.014 1.0121 1.012 Q

0.760.74 0.73 K
0.699 0.681 0.669 DH@
1.886 1.987 2.056

kvexages: 1.01

1.98

Y [Vcal)(Pbar)(Tdgm)]/[(Vagm)(Pm)(Tcal)] K Q(sqrt((Pm

Mm)/((Tm

out)(DH)) Q ((Vmi-Vmf)/min.)(TM,out/Tm,avg)(y) DH@ 0.921/K^2 Where: Y Meter correction factor, dimensionless Vcal= Volume of gas through calibrating meter, cubic feet Vdgm Volume of gas through field dry gas meter, cubic feet Pbar Barometric pressure, in. Hg Pm= Meter pressure, (Pbar DH/13.6) Tdgm Average dry gas meter temp, degrees R Tcal Temperature

of gas at calibrating meter, degrees RDRY GAS METER

CALIBRATION

Meter ID Calibration Method Calibration Meter ID Date NuTech (2298915) DGM/DGM 651729 12/30/98

By WBM Pbar 29.91

Vac. DH Tlmt Calibrating

Meter in. in. min Vi

Vf Temp

Vi

Vf Hg H,o

ft 3 ft 3 72 ft 3 ft 3 2 5.00 9.75 447.975

459.910

50 572.358

583.781 2 4.00 11.50: 459.910

473,002

52 583.781

596.452 2 3.00 15.50 473.002

487.651

50 596.452

610.790 2 2.00 19.00 487.651

502.164

48 610.790

625.074 2 1.00 19.75 502.164

513.060

52 625.074

635.830 Field Meter Temp. in iniL final 44 45 44 45 48 44 48 50 45 50 47 47 54 52 50Tem• out Y Q K / init. | final44 1.020 1.2 0.7051 1.851 45 1.010 l.ll 0.732 1.720 47 1.009 0.93 0•706 1.847 47 1.011 0.76 0.703 1.862 50 1,010 0.55 0.716 1.798 Averages: 1.01

1.82

¥ [Vcal)(Pbar)(Tdgm)]/[(Vdgm)(Pm)(Tcal)] K Q(sqrt((Pm

Mm)/((Tm

ou0(DH)) Q ((Vmi-Vmf)/min.)(TM,

out•m,avg)(Y) DH@ 0.921/K^2 Wherel Y Meter correction factor, dimensionless Veal Volume of gas through calibrating meter, cubic feet Vdgm Volume of gas through field dry gas meter, cubic feet Pbar Barometric pressure, in. Fig Pm Meter pressure, (Pbar DH/13.6) Tdgm Average dry gas meter temp, degrees R Tcal= Temperature

of gas at calibrating meter, degrees R( XFORDL•=nboratorles C. Analytical

and Consulting

Chemists DATE RECEIVED

05-07-99 1316 Sout• Fifth Street DATE REPORTED

05-24-99 Wilmington,

N.C. 28401 9 9w2 6 5 7 (910) 783-9793 Fax (9!0) 343-9688 PAGE t OF t ENVIRONMHNTAL MONITORING 242 INGLESIDE

DRIVE MADISON, MS 39110 ATTENTION: DANNY

RUSSELL P.O. # DGRS06

SAMPLE DESCRIPTION:

BORAL

BRICK

(3 F BY HPLC) I. BORAL

BRICK

R1 2. BORAL

BRICK

R2 3. BORAL

BRICK

R3 4. METHOD RESULTS Fluoride, as. F, Total

ug .uoride, as F, Total

ug 1

2

3

4 128000 109000

99500 128000 II0000

99200 NOTE: * SAMPLES

ANALYZED

BY .IC-HPLC.

R C. OXFORD•

CHEMISTPAGE_J___ OF __• ENVIRONMENTAL MONITORING

LAB ORATORIES POST OFFICE BOX 655 RIDGELAND, MISSISSIPPI

39158 PHONE: 601/856-3092 FAX: 601/853-2151

Attention:

Danny Russell Laboratory:Oxford

Laboratories,

Inc. 1316 South Fifth Street Willmington, NC 28401

910/763-9793 Please return copy of chain of custody with analytical report Attention: EML PO No. DGR506 Project: Boral Bricks (4-22-99) Rush

| Routine

• Fax Results :AN•YSES• -REQUES•I/ Fluoride by HPLC (Method 13)

Boral Brick R1 aqueou.s Boral Brick R2 aqueous Boral Brick R3 aqueous XXX Total gg Total gg Total gg

Relinquished by: (print name; initial) Dam/time

Received by: (print name; initial) Date/time Daniel G. Russell 5/6/99 Relinquished by: (print name; initial) Received by: (print name: initial) Date/time Relinquished by: (print name; initial) Date/time

Received by: (print name; initial) Date/time COURIER Fed-Ex

Date Shipped 5/6199 Date/time