Charles Busch

Enclosed are the results of analyses for samples received by the laboratory on 02/08/13 11:30. If you have any 

questions concerning this report, please feel free to contact me at 1-800-858-5227.

 Oily Waste Analysis

RE: Oily Waste Analysis

Ankeny, IA 50021

825 SW Irvinedale Drive

John Deere Des Moines Works

05 March 2013

ANALYTICAL REPORT FOR SAMPLES

Client Sample ID Laboratory ID Matrix Date Sampled Date Received

FC Composite 2 1B30478-01 Sludge 12/06/12 14:30 02/08/13 11:30

THF Extract 1B30478-02 Other 12/06/12 14:30 02/08/13 11:30

Toluene Extract 1B30478-03 Other 12/06/12 14:30 02/08/13 11:30

TCLP Extract 1B30478-04 Water 12/06/12 14:30 02/08/13 11:30

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 1 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

COC Goes Here

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 2 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Analyte Result Limit Batch

Reporting

Units Dilution Prepared Analyzed Method Notes 

FC Composite 2

1B30478-01 (Sludge)

Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton

TCLP Extraction

TCLP pH, Final 7.6 0.1 pH 1 1WB0735 02/27/13 02/27/13 EPA 1311

TCLP pH, Initial 5.0 0.1 " " " " " "

EPOW Extraction

THF Extract Final Volume 302 1.0 ml 1 1WC0064 02/22/13 02/22/13 EPA 1330A

Toluene Extract Final Volume 404 1.0 " " " " " "

Acetate Buffer Final Volume 936 1.0 " " " " " "

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 3 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Analyte Result Limit Batch

Reporting

Units Dilution Prepared Analyzed Method Notes 

THF Extract

1B30478-02 (Other)

Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton

Determination of Total Metals

Barium, total ND 0.040 mg/L 4 1WB0732 02/28/13 02/28/13 EPA 6010B R-01

Chromium, total 0.164 0.040 " " " " " "

Copper, total 1.91 0.040 " " " " " "

Lead, total 0.110 0.040 " " " " " "

Mercury, total ND 0.0005 " 1 1WC0011 03/01/13 03/01/13 EPA 7471A

Nickel, total 0.486 0.040 " 4 1WB0732 02/28/13 02/28/13 EPA 6010B

Vanadium, total ND 0.200 " " " " " " R-01

Zinc, total ND 0.040 " " " " " " R-01

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 4 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Analyte Result Limit Batch

Reporting

Units Dilution Prepared Analyzed Method Notes 

Toluene Extract

1B30478-03 (Other)

Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton

Determination of Total Metals

Barium, total ND 0.010 mg/L 1 1WB0732 02/28/13 02/28/13 EPA 6010B

Chromium, total 0.013 0.010 " " " " " "

Copper, total 0.068 0.010 " " " " " "

Lead, total ND 0.010 " " " " " "

Mercury, total 0.0005 0.0005 " " 1WC0011 03/01/13 03/01/13 EPA 7471A

Nickel, total 0.042 0.010 " " 1WB0732 02/28/13 02/28/13 EPA 6010B

Vanadium, total ND 0.050 " " " " " "

Zinc, total 0.015 0.010 " " " " " "

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 5 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Analyte Result Limit Batch

Reporting

Units Dilution Prepared Analyzed Method Notes 

TCLP Extract

1B30478-04 (Water)

Date Sampled:12/6/2012 2:30:00PM

Keystone Laboratories, Inc. - Newton

Determination of Total Metals

Barium, total 0.048 0.010 mg/L 1 1WB0732 02/28/13 02/28/13 EPA 6010B

Chromium, total ND 0.010 " " " " " "

Copper, total 0.097 0.010 " " " " " "

Lead, total ND 0.010 " " " " " "

Mercury, total ND 0.0005 " " 1WC0011 03/01/13 03/01/13 EPA 7471A

Nickel, total 0.244 0.010 " " 1WB0732 02/28/13 02/28/13 EPA 6010B

Vanadium, total ND 0.050 " " " " " "

Zinc, total 0.026 0.010 " " " " " "

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 6 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

Determination of Total Metals - Quality Control

Keystone Laboratories, Inc. - Newton

Batch 1WB0732 - EPA 3010A Digestion (Water)

Blank (1WB0732-BLK1) Prepared & Analyzed: 02/28/13 

Barium, total ND 0.010 mg/L

Chromium, total ND 0.010 "

Copper, total ND 0.010 "

Lead, total ND 0.010 "

Nickel, total ND 0.010 "

Vanadium, total ND 0.050 "

Zinc, total ND 0.010 "

Blank (1WB0732-BLK2) Prepared & Analyzed: 02/28/13 

Barium, total ND 0.010 mg/L

Chromium, total ND 0.010 "

Copper, total ND 0.010 "

Lead, total ND 0.010 "

Nickel, total ND 0.010 "

Vanadium, total ND 0.050 "

Zinc, total ND 0.010 "

LCS (1WB0732-BS1) Prepared & Analyzed: 02/28/13 

Barium, total 3.19 0.010 mg/L 3.33333 95.6 80-120

Chromium, total 3.27 0.010 " 3.33333 98.0 80-120

Copper, total 3.38 0.010 " 3.33333 102 80-120

Lead, total 3.11 0.010 " 3.33333 93.3 80-120

Nickel, total 3.17 0.010 " 3.33333 95.0 80-120

Vanadium, total 3.57 0.050 " 3.33333 107 80-120

Zinc, total 3.22 0.010 " 3.33333 96.5 80-120

LCS Dup (1WB0732-BSD1) Prepared & Analyzed: 02/28/13 

Barium, total 3.26 0.010 mg/L 3.33333 97.7 80-120 2.17 200

Chromium, total 3.35 0.010 " 3.33333 101 80-120 2.64 200

Copper, total 3.42 0.010 " 3.33333 103 80-120 1.16 200

Lead, total 3.19 0.010 " 3.33333 95.8 80-120 2.66 200

Nickel, total 3.25 0.010 " 3.33333 97.6 80-120 2.69 200

Vanadium, total 3.62 0.050 " 3.33333 109 80-120 1.43 200

Zinc, total 3.31 0.010 " 3.33333 99.4 80-120 2.90 200

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 7 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

Determination of Total Metals - Quality Control

Keystone Laboratories, Inc. - Newton

Batch 1WB0732 - EPA 3010A Digestion (Water)

Duplicate (1WB0732-DUP1) Source: 1B30478-04 Prepared: 02/28/13 Analyzed: 03/01/13 

Barium, total 0.046 0.010 mg/L 0.048 4.79 20

Chromium, total 0.010 0.010 " 0.009 1.15 20

Copper, total 0.0989 0.010 " 0.0967 2.33 20

Lead, total ND 0.010 " ND 20

Nickel, total 0.238 0.010 " 0.244 2.68 20

Vanadium, total 0.00439 0.050 " 0.00597 30.5 20 A-01

Zinc, total 0.0289 0.010 " 0.0261 10.3 20

Batch 1WC0011 - EPA 7470A Hg Water

Blank (1WC0011-BLK1) Prepared & Analyzed: 03/01/13 

Mercury, total ND 0.0005 mg/L

LCS (1WC0011-BS1) Prepared & Analyzed: 03/01/13 

Mercury, total 0.002 0.0005 mg/L 0.00250000 87.2 78-132

LCS Dup (1WC0011-BSD1) Prepared & Analyzed: 03/01/13 

Mercury, total 0.002 0.0005 mg/L 0.00250000 78.0 78-132 11.1 20 QS-07

Certified Analyses Included in This Report

Method/Matrix Analyte Certifications

EPA 6010B in Water

Barium, total NELAC,SIA1X,KS-NT

Chromium, total NELAC,SIA1X,KS-NT

Copper, total NELAC,SIA1X,KS-NT

Lead, total NELAC,SIA1X,KS-NT

Nickel, total NELAC,SIA1X,KS-NT

Vanadium, total NELAC,SIA1X,KS-NT

Zinc, total NELAC,SIA1X,KS-NT

Code Certifying Authority Certificate Number Expires

KS-KC Kansas Department of Health and Environment-KC E-10110 04/30/2013

KS-NT Kansas Department of Health and Environment E-10287 10/30/2013

MO-KC Missouri Department of Natural Resources 140 04/30/2013

NELAC New Jersey Department of Environmental Protection IA001 06/30/2013

SIA1X Iowa Department of Natural Resources 95 02/01/2014

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 8 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Notes and Definitions 

R-01 The Reporting Limit for this analyte has been raised to account for matrix interference.

QS-07 The spike recovery for this QC sample was below established acceptance limits.

A-01 RPD EXCEEDS ACCEPTANCE LIMITS; HOWEVER ANALYTE IS LESS THAN REPORTING LIMIT

Sample results reported on a dry weight basis

RPD Relative Percent Difference

dry

NR Not Reported

ND Analyte NOT DETECTED at or above the reporting limit

DET Analyte DETECTED

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 9 of 10
John Deere Des Moines Works

825 SW Irvinedale Drive Oily Waste Analysis

Charles Busch

Oily Waste Analysis

Ankeny IA, 50021

Project:

Project Number:

Project Manager:

Reported

03/05/13 11:23

Jeffrey King, Ph.D. For Staci Arnold

Project Manager I

The results in this report apply to the samples analyzed in accordance with the Chain-of-Custody record. This analytical report must be reproduced in its 

entirety.

Phone 641-792-8451 600 East 17th Street South Fax 641-792-7989

Newton, IA 50208

Page 10 of 10