### Instructions for filling Fuel Material Analysis Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Data for multiple boilers should be handled by using separate spreadsheets. Fields that are highlighted in yellow are required fields. Green highlighted cells should be filled using the drop

- down boxes, included. Gray fields are automatically filled from other fields.

Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

Please refer to the following steps when using these spreadsheets.

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the test date on the Boiler Information worksheet. 3. Please choose the type of fuel being sampled using the drop

- down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865

- 04". 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. 6. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected more. 7. Provide the results of the analyses for each constituent requested. Use the drop

- down boxes to fill in the units of

measure.

### Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being Fields that are highlighted in down boxes, included. Gray fields are

[FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet.

down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM

5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have

down boxes to fill in the units ofEIA

Facility Code Facility Name Boiler ID Test Date

2554 Dunkirk Steam Generating Station 4 4/19/2010Fuel Type 1 Fuel Type 2 Fuel Type 3

subbituminousOther Fuel DescriptionEIA

Facility Code Facility Name Boiler ID Basis An alyte

2554 Dunkirk Steam Generating Station 4 As Received Higher Heating Value 2554 Dunkirk Steam Generating Station 4 As Received % Moisture 2554 Dunkirk Steam Generating Station 4 As Received % Ash 2554 Dunkirk Steam Generating Station 4 As Received % Sulfur 2554 Dunkirk Steam Generating Station 4 Dry basis Higher Heating Value 2554 Dunkirk Steam Generating Station 4 Dry basis % Moisture 2554 Dunkirk Steam Generating Station 4 Dry basis % Ash 2554 Dunkirk Steam Generating Station 4 Dry basis % Sulfur 2554 Dunkirk Steam Generating Station 4 Dry basis Antim ony 2554 Dunkirk Steam Generating Station 4 Dry basis Arsenic 2554 Dunkirk Steam Generating Station 4 Dry basis Beryllium 2554 Dunkirk Steam Generating Station 4 Dry basis Cadmium 2554 Dunkirk Steam Generating Station 4 Dry basis Chlorine 2554 Dunkirk Steam Generating Station 4 Dry basis Chromium 2554 Dunkirk Steam Generating Station 4 Dry basis Cobalt 2554 Dunkirk Steam Generating Station 4 Dry basis Fluorine 2554 Dunkirk Steam Generating Station 4 Dry basis Lead 2554 Dunkirk Steam Generating Station 4 Dry basis Manganese 2554 Dunkirk Steam Generating Station 4 Dry basis Mercury 2554 Dunkirk Steam Generating Station 4 Dry basis Nickel 2554 Dunkirk Steam Generating Station 4 Dry basis SeleniumAn alysis M ethod for each Analyte

(example: ASTM D5865-04) D5865 D3302 D3174 D4239 D5865 D3302 D3174 D4239 SW 6010B SW 6010B SW 6010B SW 6010B

SW 6010B SW 6010B

SW 6010B SW 6010B D6722 SW 6010B SW 6010BEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6260B) 2554 Dunkirk Steam Generating Station 4 M30B, M29, OTM 27/28

Sample Number (minimum of 3 composite samples) Sample Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) 1 4/19/2010 8500.00 Btu/lb 27.8 2 4/19/2010 8470.00 Btu/lb 28.1 3 4/21/2010 8520.00 Btu/lb 27.7 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 4.75 0.21 11770 Btu/lb 0 6.58 0.29 4.75 0.21 11780 Btu/lb 0 6.61 0.29 4.96 0.2 11780 Btu/lb 0 6.86 0.28Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 0.185 mg/kg 2 mg /kg 1 mg /kg 1 0.056 mg/kg 2 mg /kg 1 mg /kg 1 0.073 mg/kg 2 mg /kg 1 mg /kg 1Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units mg /kg 4.82 mg/kg 2.77 mg /kg 9.29 mg /kg 2.59 mg /kg mg /kg 5.34 mg/kg 2.72 mg /kg 9.8 mg /kg 2.53 mg /kg mg /kg 3.99 mg/kg 3.88 mg /kg 9.04 mg /kg 2.34 mg /kgSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 2 mg /kg mg/kg 1.57 mg /kg 2 mg /kg mg/kg 1.46 mg /kg 2 mg /kg mg/kg 1.22 mg /kgEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6260B) 2554 Dunkirk Steam Generating Station 4 M26, CTM033, 6C, 7E

Sample Number (minimum of 3 composite samples) Sample Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) 1 4/22/2010 8530.00 Btu/lb 27.9 2 4/22/2010 8570.00 Btu/lb 27.4 3 4/22/2010 8520.00 Btu/lb 28.3 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 4.62 11830 Btu/lb 0 6.41 0.29 4.88 11800 Btu/lb 0 6.72 0.3 4.73 11880 Btu/lb 0 6.6 0.31Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis)Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel UnitsSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt UnitsEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6260B) 2554 Dunkirk Steam Generating Station 4 M6C, M10, M18, M0031 with SW -846, M0010, M0011, M25A

Sample Number (minimum of 3 composite samples) Sample Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) 1 4/22/2010 8530.00 Btu/lb 27.9 2 4/22/2010 8570.00 Btu/lb 27.4 3 4/22/2010 8520.00 Btu/lb 28.3 Fuel Testing ResultsM6C, M10, M18, M0031 with SW -846, M0010, M0011, M25A

% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 4.62 11830 Btu/lb 0 6.41 0.29 4.88 11800 Btu/lb 0 6.72 0.3 4.73 11880 Btu/lb 0 6.6 0.31Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis)Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel UnitsSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt UnitsEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6260B) 2554 Dunkirk Steam Generating Station 4

Sample Number (minimum of 3 composite samples) Sample Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis)Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis)Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel UnitsSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt UnitsUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the

Fuel Units of Measure - HHV anthracite Btu/lb bitum inous Btu/gallon subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) Units of Measure - Metals synfuel mg /g petroleum coke μg/g other mg /KgUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the orangehightlighted cell, if necessary

.

Units of Measure - Cl, Fl % ppm