### TS-H201PP Attachment 6 Page 1 of 4

#:- 

### CBI 

# Material Safety Data Sheet

Issued Dec-2-2011

Revised

Printed Dec-2-2011 1. Product/Company identification
1.1. Identification of the substance or preparation

Trade name (CBI) Purpose R&D use only Common name Fluoroalkyl acrylate copolymer emulsion. Major application Water and oil repellent agent for Textile.

1.2. Company/undertaking identification

Manufacturer (CBI)

Supplier in US (CBI)

1.3. Emergency telephone Company (CBI)



### 2. Hazards identification
Emergency Overview

Non-flammable material.



### 3. Composition/information on ingredients

name CAS Number Mass% 

### (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI) (CBI)

4. First-aid measures

Inhalation If inhaled, remove to fresh ai r. If not breathin g, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before

reuse. Eye Contact In case of contact, immedi ately flush eyes with plenty of water for at least 15 minutes. Call a physician. Ingestion Rinse mouth. Get medical attention.



### 5. Fire-fighting measures

General Information Non-flammable.

Flash Point: None.

Flammable Limits: LEL: no data UEL: no data

Hazardous decomposition produc ts including carbon dioxide, carbon monoxide, hydrogen fluori de, toxic gases or particles may be formed during combustion. These products may cause severe eye, nose, throat, and lung irritation or toxic effects Extinguishing Media Water, Powder, alcohol- resistant foam, water in large amounts,

carbon dioxide. Fire-fighting Instructions Wear self-contained breathing apparatus (SCBA) and full protective gear. Use water spray to cool fire exposed containers.TS-H201PP CONFIDENTIAL Attachment 6 Page 2 of 4



### 6. Accidental release measures
General Information Use proper personal prot ective equipment as indicated in Section

8.

Spills/Leaks Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer.



### 7. Handling and storage Handling Wear suitable protective clothing (see section 8)

Use in well ventilated areas. Make emergency shower and eyes wash available in the work

area. As there is a possibility for inhaling poisonous decomposition gas from smoking a cigarette to wh ich compound may be adhered, “no smoking” practice should be maintained in a work place and after handling materials, wash face and hands thoroughly.

Storage Store in a cool, dry area at –5 deg C to 40 deg C. Keep away from direct heat or sunlight. Keep containers tightly closed when not in use.



### 8. Exposure controls/personal protection
Engineering Controls: Use only with adequate ventilation. Vent heated extruder or dryer fumes outside work area.

Do not aerosolize in non-controlled environment. In spray applications, use airless type and exhaust ducts, drip pans, or other design features to minimize worker exposure to mists and overspray.

Personal Protective Equipment Eyes Wear safety glasse s with side shields. Hand Wear appropriate protective gloves to prevent exposure. Skin and body Wear protecti ve clothing and boots to minimize contact with skin. Respirators Use a NIOSH or European St andard EN 149 approved respirator when necessary. If thermal decomposition occurs, mask for acidic gases must be used to av oid inhalation of the product.

Exposure Limits HF TLV(as F): 3ppm; (ceiling values)(ACGIH 1999) MAK: 3ppm; 2.5mg/m3, BA T 7mg/g creatinine (1999) MAK as STEL: 6ppm, 5mg/m3 (1999) COF2 TLV: 2ppm; 5.4mg/m3 (as TWA); 5ppm, 13mg/m3(as STEL) (ACGIH 1997) PFIB TLV: 0.01ppm; 0.082mg/m3 (ceiling values)(ACGIH 1993-1994)



### 9. Physical and chemical properties
Physical State (CBI)

Color (CBI)

Odor (CBI) pH (CBI) Boiling point (CBI) Freezing point (CBI) Vapor pressure (CBI) Vapor density (CBI) Specific gravity (CBI) Solubility in water (CBI)TS-H201PP CONFIDENTIAL Attachment 6 Page 3 of 4 Flash point None Auto-ignition Temp. No data Explosion limits No data



### 10. Stability and reactivity
Chemical Stability Normally stable. Conditions to Avoid Exposure to op en flame or higher temperatures . Incompatibility None reasonably foreseeable

Materials to avoid None reasonably foreseeable. Polymerization Polymerization will not occur. Decomposition Carbon monoxide, ca rbon dioxide, HF, COF2, PFIB.



### 11. Toxicological information

This material No data

Data of individual components: (CBI) No data (CBI) LD 50 >2000mg/kg(OECD TG401)(rat) NOEL=200mg/kg/day(rat) Ames test Negative Chromosomal aberrations Negative Toxicity to Reproduction(rat) NOEL Parental=1000mg/kg/day NOEL F1 offspring=1000mg/kg/day



### 12. Ecological information
Ecotoxicological Information

No data are available.

Chemical Fate Information

No data are available.



### 13. Disposal considerations
Dispose of in compliance with local government regulations. Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HF. Dispose of waste product in a sanitary landfill. Product may be recycled.



### 14. Transport information

Hazard Class None

UN Number None

DOT Classifica tion None



### 15. Regulatory information
TSCA:Not Registered.

NFPA Ratings: Health: Not determine Flammability Not determine Reactivity Not determine



### 16. Other information

The data in this Material Safety Data Sheet relate s only to the specific material designated herein

and does not relate to use in combination wi th any other material or in any process.
NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY,TS-H201PP CONFIDENTIAL Attachment 6 Page 4 of 4
OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIE D, IS MADE CONCERNI NG THE INFORMATION

PROVIDED HEREIN.