# EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -004

PARTICULATE MATTER, AMMONI A SLIP,SULFUR DIOXIDE, NITROGEN OXIDE, AND VISIBLE EMISSIONS EVALUATION May 21, 2009

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Air Services Group

Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Scott E. Given Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith, QSTI Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1

2.0 DISCUSSION OF RESULTS / EXECUTIVE SUMMARY 2

3.0 SOURCE DESCRIPTION / TEST PROCEDURES 4

4.0 TEST RESULTS

PARTICULATE MATTER TEST SUMMARY 7

AMMONIA SLIP TEST SUMMARY 8

SULFUR DIOXIDE AND NITROGEN OXIDES DATA SUMMARY 9

VISIBLE EMISSIONS DATA FR OM OPACITY MONITOR 10

HEAT INPUT CALCULATIONS 11

5.0 FIGURES

PARTICULATE SAMPLING TRAVERSE POINTS 13

APPENDICES A PARTICULATE MATTER TEST DATA A-1 RUN CALCULATIONS A-2 LABORATORY ANALYTICAL DATA A-3 CALIBRATION DATA A-4 FIELD DATA SHEETS A-5 CHAIN OF CUSTODY

B AMMONIA SLIP TEST DATA B-1 RUN DATA B-2 RAW DATA B-3 METHOD MAP B-4 SUMMARIZED QA DATA B-5 LEAK RATE DATA B-6 ETHYLENE CTS DATA B-7 SPIKE DATA B-8 SNR TEST DATA B-9 ANNUAL CELL PATH CHECK DATA B-10 CYLINDER GAS CERTIFICATES OF ANALYSIS

C CONTINUOUS EMISSION S MONITORING DATA

D OPERATIONS DATA

### E FUEL INFORMATION E-1 BUNKERING INFORMATION E-2 FUEL ANALYSIS

F TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On May 21, 2009, Tampa Electric Company ’s Environmental, Health, & Safety, Air Services Group, performed particulate matter (PM) and ammonia slip tests at the Big Bend Station (Facilit y ID No.: 0570039), Boiler No. 4, (E.U. ID No.: -004). Particulate Matter (PM) testing was conducted according to procedures stipulated by the Florida Department of Environmental Protection (FDEP) for fossil fuel steam generator s, and requirements in Title V Permit # 0570039-028-
AV, Compliance determination procedures and methods , §B.26 through §B.30. Ammonia Slip testing was conducted in accordance with FDEP Air Construction (AC) Permit 0570039-020-AC (as modified in permit 0570039-026-AC),

COMPLIANCE DETERMINATION , §A.19.

### 2 

## 2.0 DISCUSSION OF RESULTS Executive Summary Tampa Electric Company Big Bend Station Dry-Bottom Tangentially Fired Utility Boiler Emission Unit ID -004

Coal/Petroleum Coke/Polk Residual Compliance Parameter Test Result FDEP Permit Limit May 21, 2009 Particulate, lb/mmBtu 0.01 0.01 Particulate, lbs/hr 31.5 43.3 Ammonia, ppmv 1 10 SO 2 

### , lb/mmBtu 0.30 0.82 1 

### SO 2 

### , lbs/hr 1251 3551 1 

### NO X 

### , lb/mmBtu 0.09 0.10 2


### NO X 

### , lbs/hr 372 433 2,5 

### VE, % opacity 5 20 3 

### Heat Input, mmBtu/hr 4240 4330 4 

### Unit Load (% of permit) 98% 90 – 100%

1 Based on a 30-day rolling average.
2 Based on a heat input weighted 30-day rolling average.
3 6-minute average.
4 Permitting Note: The heat input has been placed in the permit to identify the capacity of the unit for purposes of confirming that emissions testing is conducted within the 90 – 100% of the unit’s rated capacity (or to limit future operat ion to 110% of the test load), to establish appropriate emission limits and to aid in determining future rule applicability.
5 This limit is based on a heat input of 4330 mmBtu/hr.


### The average particulate matter emissions were derived by performing three, 2-

hour United States Envir onmental Protection Agency (USEPA) reference method 5B test runs. The average emission rates were calculated as 0.01 lb/mmBtu, and 31.5 lbs/hr. The FDEP Title V permitt ed emission rates are 0.01 lb/mmBtu and 43.3 lbs/hr (§ B.5.i (a) & (b)).

The average ammonia slip concentration was derived from three 1-hour USEPA

reference method 320 test runs. The av erage concentration was calculated as 1 ppmv. The FDEP AC permitted concentration is 10 ppmv (§ A.17.).

### 3 

### During the particulate matter test the Sulfur Dioxide (SO 2 

### ) emission rates were

determined to be 0.30 lb/mmBtu and 1251 lb s/hr. The FDEP Title V permitted

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling average (§ B.7 (a) & (b)).

During the particulate matter test the nitrogen dioxide (NO 2 

### ) emission rates (as total oxides) were determined to be 0. 09 lb/mmBtu and 372 lbs/hr. The FDEP AC permitted emission rate is 0.10 lb /mmBtu and 433 lbs/hr, based on a 30-day rolling average (§A.16).

Visible emissions were determined to be 5%, maximum 6-minute average, during

a one-hour test conducted under soot bl owing conditions. The FDEP Title V permitted emission rate is 20 percent opac ity (6-minute average) except for one 6-minute period per hour of not more than 27 (twenty-seven) percent (§B.6).

During the particulate matter test per formed on May 21, 2009 Boiler No. 4 was operated at an average heat input rate of 4240 mmBtu/hr and an average load of 442 megawatts. The average quantity of fuel burned was 193.7 tons per hour.

### 4 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM

coordinates East 361.9 Nort h 3075.0. Boiler No. 4 source sampling location
consists of a circular sta ck 28.83 feet in diam eter with four sample ports located 90 degrees apart on the stack circumference. Upstream and downstream gas
flow disturbances were determined to be 8.51 and 2.99 stack di ameters from the test ports, respectively. Using these cr iteria, a total of 24 sampling points were chosen for particulate sampling for each stack, as stipulat ed in the U.S. EPA Method 1 test procedure. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash emissions, a selective catalytic reducti on (SCR) system for control of nitrogen oxides emissions, an ammonia injection system to control sulfur trioxide formation, and a flue gas desulfurization (FGD) system for control of sulfur

dioxide emissions.

On May 21, 2009, the boiler was fired with a solid fuel matrix comprised of 85% coal and 15% petroleum coke.

Particulate sampling was perform ed according to USEPA Method 5-B

"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".

Particulate matter was collected on a hi gh purity, glass micro fiber filter measuring 8.26 cm in diameter.

Ammonia slip testing was performed using USEPA Method 320 “Measurement of Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy”. Spec tra and test performance was reviewed by RJK Consulting for appropriateness, completeness, and quality control.

### 5 

### Sulfur Dioxide and Nitrogen Ox ide data was supplied by the installed Continuous Emissions Monitoring systems (CEMs), Data Acquisition and Handling System (DAHS) as one minute averages for the duration of the particulate matter test.

Visible emissions compliance was asse ssed using the installed Continuous Opacity Monitor (COM) as recorded by the DAHS as one minute averages during the soot blowing portion of the particulate matter test.

### 6 

## 4.0 TEST RESULTS

## BIG BEND STATIO N PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2 * 

### Run 3 T est Summar y V m(std) 

### , scf 71.982 68.059 69.512 69.851

B ws 

### , ratio 0.156 0.161 0.159 0.159

O 2 

### , % volume 5555

. 0

M

d 

### , lb/lb - mole 30.44 30.44 30.44 30.44

M

s 

### , lb/lb - mole 28.49 28.44 28.46 28.46

Q s 

### , acf/min 2.14E+06 2.04E+06 2.08E+06 2.09E+06

Q s(std) 

### , dscf/min 1.60E+06 1.51E+06 1.55E+06 1.55E+06

I, % 100.6 100.7 100.6 100.6

C, lbs/dscf 7.18E-07 6.04E-07 4.12E-07 5.78E-07

E r 

### , lb/mmBtu 0.01 0.01 0.01 0.01

E m 

### , lbs/hr 39.1 32.9 22.5 31.5

Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 )) Mass emissions (E m ), lbs/hr, calculated as: E r , lb/mmBtu x Heat Input

* Run 2 was a soot blowing run 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILER May 21, 2009

7

## BIG BEND STATIO N AMMONIA SLIP TEST DAT A

Calculated Data
Run NH 3 

### Water SF 6 

### Cell Temp Pressure Number Start Stop ppmvw % ppm °C ATM 1 10:59 11:59 0.796 15.56 -0.02 150 0.9560 2 13:03 14:04 0.739 16.31 -0.02 150 0.9623 3 14:06 15:07 0.623 15.95 -0.02 150 0.9610 Average: NH 3 1 

### , ppmvw is corrected for FTIR bias factor from annual QA/QC checks.
This value is: 1.0602 ppmvw 0.84 0.78 0.66

1 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R May 21, 2009

NH 3 1



### FTIR Recorded Data
Run Time 

### 40 CFR 63 Reference Method 320 Summarized Data

8

## BIG BEND STATIO N SULFUR DIOXIDE and NITROGEN OXIDES DAT A

Outlet SO 2 

### Data Average SO 2 

### Concentration, ppmvw: 107.9 Average CO 2 

### Concentration, % volume wet: 10.93
Calculated SO 2 

### Emission Rate, lb/mmBtu: 0.30
Calculated SO 2 

### Emission Rate, lbs/hr: 1251



### Unit #4 NO x 

### Data Average NO x 

### concentration, ppmvw: 49.69 Average CO 2 

### Concentration, % volume wet: 12.18
Calculated NO x 

### Emission Rate, lb/mmBtu: 0.09
Calculated NO x 

### Emission Rate, lbs/hr: 372

SO2 Emission Rate, lb(s)/mmBtu is calculated as: SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw) NOx Emission Rate, lb/mmBtu is calculated as: NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw) Emission Rates in lbs/hr are calculated as: Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr Average Concentration values were taken from 8:00 to 15:43 EST. Heat Input Calculated for this test was 4240 mmBtu/hr 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILER May 21, 2009

9

## BIG BEND STATIO N V ISIBLE EMISSIONS DATA FROM OPACITY MONITO R

Record# DATE TIME OPACITY4 Record# DATE TIME OPACITY4 1 05/21/2009 10:54 3.64 31 05/21/2009 11:24 3.76 2 05/21/2009 10:55 4.19 32 05/21/2009 11:25 3.58 3 05/21/2009 10:56 4.14 33 05/21/2009 11:26 3.47 4 05/21/2009 10:57 4.46 34 05/21/2009 11:27 3.17 5 05/21/2009 10:58 4.21 35 05/21/2009 11:28 3.20 6 05/21/2009 10:59 4.70 36 05/21/2009 11:29 3.44 7 05/21/2009 11:00 5.67 37 05/21/2009 11:30 3.29 8 05/21/2009 11:01 4.70 38 05/21/2009 11:31 3.54 9 05/21/2009 11:02 4.03 39 05/21/2009 11:32 3.67 10 05/21/2009 11:03 4.07 40 05/21/2009 11:33 3.97 11 05/21/2009 11:04 4.12 41 05/21/2009 11:34 3.83 12 05/21/2009 11:05 5.54 42 05/21/2009 11:35 3.98 13 05/21/2009 11:06 6.35 43 05/21/2009 11:36 4.04 14 05/21/2009 11:07 5.35 44 05/21/2009 11:37 3.78 15 05/21/2009 11:08 4.10 45 05/21/2009 11:38 3.79 16 05/21/2009 11:09 4.07 46 05/21/2009 11:39 3.85 17 05/21/2009 11:10 3.90 47 05/21/2009 11:40 3.98 18 05/21/2009 11:11 4.04 48 05/21/2009 11:41 3.93 19 05/21/2009 11:12 3.78 49 05/21/2009 11:42 3.70 20 05/21/2009 11:13 4.31 50 05/21/2009 11:43 3.51 21 05/21/2009 11:14 4.45 51 05/21/2009 11:44 3.75 22 05/21/2009 11:15 4.09 52 05/21/2009 11:45 3.73 23 05/21/2009 11:16 4.07 53 05/21/2009 11:46 3.52 24 05/21/2009 11:17 4.00 54 05/21/2009 11:47 3.20 25 05/21/2009 11:18 3.56 55 05/21/2009 11:48 3.61 26 05/21/2009 11:19 3.77 56 05/21/2009 11:49 3.57 27 05/21/2009 11:20 3.84 57 05/21/2009 11:50 3.71 28 05/21/2009 11:21 3.68 58 05/21/2009 11:51 3.46 29 05/21/2009 11:22 3.94 59 05/21/2009 11:52 3.75 30 05/21/2009 11:23 4.37 60 05/21/2009 11:53 3.54

Test Avera g e: 3.974 % Minimum One Minute Avera g e: 3.170 % Maximum One Minute Avera g e: 6.350 %

Maximum Six Minute Avera g e: 4.922 % 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R SOOTBLOWING CONDITIONS

10

## BIG BEND STATIO N HEAT INPUT CALCULATION S

Gross Heat Rate, Previous Month ( A p ril ) : 9602 KMBtu/MWh 9.6020E+06 mmBtu/MWh

Testing Start Time: 8:00

Testing End Time: 15:43

T otal Test Time: 7.72 hours

Average Unit Load, MWe: 442 MW Heat Input, mmBtu/h = mmB tu/MWh x MW: 4240 mmBtu/hr

Laboratory Sample ID: AB01114 Btu as received: 10946 

### Btu/lb T ons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 193.7 T ons/hour 

### Unit #4

Test Time Information

Calculated Heat Input

Fuel Consumptio n Calculation DRY-BOTTOM TANGENTIALLY FIRED BOILE R May 21, 2009

11

### 12 

## 5.0 FIGURES

### 13 FIGURE 1 EXHAUST STACK 239 FT BIG BEND GENERATING STATION

PARTICULATE TRAVERSE POINTS

71 FT

SAMPLING PLATFORM

ESP OUTLET UPPER

LOWER
ESP OUTLET 499 FT

260 FT

189 FT 

# N A

B C D

PORT LOCATION PLAN

REVISED 12-30- BOILER NO. 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 10.0

STACK DIAMETERR = 24.0 FT. ID. STACK AREA = 452.389 SQ FT.

PORT LENGTH’S = 17 IN. TRAVERSE POINT

1

2

3

4

5

6 % OF STACK DIAMETER IN. FROM STACK WALL

2.1%

6.7%

11.8%

17.7%

25.0%

35.6% 6.05 IN.

19.30 IN.

33.98 IN.

50.98 IN.

72.00 IN.

102.53 IN.

# APPENDIX A

PARTICULATE MATTER TEST DATA

# A-1

RUN CALCULATIONS

### Air Services Group

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Stack-Boiler #4
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 1
Date:

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.211 inches Barometric Pressure, P b : 29.68 "Hg Nozzle Area, A n : 0.000243 ft 2
Stack Pressure, P s : 29.61 "Hg Average Orifice Meter, Δ H: 1.303 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 73.073 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 81.4 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 129.0 o F
5.0 % O 2 Average √ Δ p: 0.911 "H 2 O 0.0 % CO Condensate Volume, V l c : 283.0 ml 81.0 % N 2 Meter Box Y: 1.015 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu Heat Input: 4240 mmBtu/hr
Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.341 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 71.982 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.156 %
FDA = 1.0 - B ws 0.844 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.49 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 54.65 ft/second Q s = v s x A s x 60 2.141E+06 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1.603E+06 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.6 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.02345 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m ( std ) 0.005 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.004 grains/acf C = c s / 7000 7.182E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.009 lbs/mmBtu
E M = E R , lbs/mmBtu x Heat Input, mmBtu/hr 39.1 lbs/hr 

### 40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

May 21, 2009

### Environmental, Health, & Safety Air Services Group

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Stack-Boiler #4
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded, Sootblowing
Run Number: 2 - S
Date:

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.211 inches Barometric Pressure, P b : 29.69 "Hg Nozzle Area, A n : 0.000243 ft 2
Stack Pressure, P s : 29.62 "Hg Average Orifice Meter, Δ H: 1.181 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 69.380 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 83.7 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 130.3 o F
5.0 % O 2 Average √ Δ p: 0.865 "H 2 O 0.0 % CO Condensate Volume, V l c : 277.3 ml 81.0 % N 2 Meter Box Y: 1.015 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu Heat Input: 4240 mmBtu/hr
Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.072 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 68.059 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.161 %
FDA = 1.0 - B ws 0.839 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.44 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 52.02 ft/second Q s = v s x A s x 60 2.038E+06 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1.514E+06 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.7 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01865 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m ( std ) 0.004 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.003 grains/acf C = c s / 7000 6.041E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.008 lbs/mmBtu
E M = E R , lbs/mmBtu x Heat Input, mmBtu/hr 32.9 lbs/hr 

### 40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

May 21, 2009

### Environmental, Health, & Safety Air Services Group

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Stack-Boiler #4
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 3
Date:

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.211 inches Barometric Pressure, P b : 29.70 "Hg Nozzle Area, A n : 0.000243 ft 2
Stack Pressure, P s : 29.63 "Hg Average Orifice Meter, Δ H: 1.233 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 70.991 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 85.0 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 130.0 o F
5.0 % O 2 Average √ Δ p: 0.882 "H 2 O 0.0 % CO Condensate Volume, V l c : 278.4 ml 81.0 % N 2 Meter Box Y: 1.015 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu Heat Input: 4240 mmBtu/hr
Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.124 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 69.512 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.159 %
FDA = 1.0 - B ws 0.841 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.44 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.46 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 53.00 ft/second Q s = v s x A s x 60 2.076E+06 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1.548E+06 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.6 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01300 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m ( std ) 0.0029 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0022 grains/acf C = c s / 7000 4.123E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.005 lbs/mmBtu
E M = E R , lbs/mmBtu x Heat Input, mmBtu/hr 22.5 lbs/hr 

### 40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

May 21, 2009

# A-2

LABORATORY ANALYTICAL DATACustomer AIR SERVICES Plant BIG BEND Unit4Method 5-B Stack Test Completion Date05/21/2009Analyst SSSample NumberACETONE BEAKER1st weighing Date 05/28/2009 Time 15:30 % RH 38.0%2nd weighing Date 05/29/2009 Time 9:00 % RH 38.0%3rd weighing Date Time % RH4th weighing Date Time % RH***Blank***Run 1 Run 2 S Run 3Acetone Container IDAIR G5 AIR G2 AIR G1 AIR G6Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 Enter Container ID Enter Container ID Enter Container ID1st Gross Wt., grams 99.7000 99.4917 95.1299 99.43832nd Gross Wt., grams 99.7000 99.4918 95.1296 99.43823rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams 99.70000 99.49175 95.12975 99.43825 Enter Gross Wts. Enter Gross Wts. Enter Gross Wts.Tare Wt., grams 99.70035 99.47520 95.11590 99.42855Acetone Blank Wt.,mg-0.35 -0.35 -0.35 -0.35Acetone Particulate Wt.,mg16.90 14.20 10.05Acetone Residue, mg/g-0.0022Acetone Blank CriteriaFILTER1st weighingDate 05/27/2009 Time 15:30 % RH 39.0%2nd weighing Date 05/28/2009 Time 9:45 % RH 38.0%3rd weighing Date Time % RH4th weighing Date Time % RHFilter/Thimble ID 203179 203176 203177 2031781st Gross Wt., grams 0.2479 0.2513 0.2524 0.25072nd Gross Wt., grams 0.2479 0.2512 0.2525 0.25073rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams 0.24790 0.25125 0.25245 0.25070 Enter Gross Wts. Enter Gross Wts. Enter Gross Wts.Tare Wt., grams 0.24740 0.24470 0.24800 0.24775Filter Particulate Wt.,mg6.55 4.45 2.95Difference, milligrams0.5Total Sample Particulate Wt.,mg23.45 18.65 13.00OK to subtract acetone blankStart Here

# A-3

CALIBRATION DATA

## Environmental, Health, & Safet y Air Services Group

SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 08) INITIA L 03/19/2009 USEPA RM 5 1.010 POST TEST 05/27/2009 (ORIFICE) 1.015

NOZZLE (SN75) INITIA L 04/27/2009 CALIPER 0.211 POST TEST 05/22/2009 MEASUREMENTS 0.210

PYROMETER (PY 20) 03/19/2009 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 12) 04/28/2009 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 04/21/2009 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Blue Team Manufacturer: APEX Calibration Date: Model Number: 522 Barometric Pressure: 30.11 "Hg Instrument Code Number: ^MB08 Theoretical Critical Vacuum: 14.20 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.69 15 223.300 229.981 6.681 72 72 72 72 1.20 15 229.981 238.881 8.900 72 72 73 73 1.95 15 238.881 250.358 11.477 73 73 74 74 3.60 15 250.358 266.082 15.724 74 74 77 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3452 22.0 72 72 72.0 55 0.4596 20.5 72 72 72.0 63 0.5923 19.0 72 72 72.0 73 0.8106 16.5 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.681 6.760 6.770 1.012 0.001 1.909 0.058 8.903 9.000 9.014 1.011 0.000 1.871 0.021 11.481 11.598 11.617 1.010 0.000 1.827 -0.023 15.733 15.873 15.898 1.009 -0.002 1.794 -0.056 Averages: 1.010 1.850

Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 20-Mar-09 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 03/19/2009

SEG

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

### Environmental Services Air Services Group

Manufacturer: APEX Calibration Date: Model Number: 522 Barometric Pressure: 31.3 "Hg Instrument Code Number: MB08 Theoretical Critical Vacuum: 14.76 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.2 10 945.400 951.370 5.970 69 69 69 69 1.2 10 951.370 957.355 5.985 69 69 69 69 1.2 10 957.355 963.335 5.980 69 69 69 69

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4596 21.5 70 70 70.0 55 0.4596 21.5 70 70 70.0 55 0.4596 21.5 70 70 70.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC
Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.249 6.249 5.998 1.000 0.001 1.805 0.000 6.264 6.249 5.998 0.997 -0.001 1.805 0.000 6.259 6.249 5.998 0.998 0.000 1.805 0.000 Averages: 0.999 1.805 Prior Y: 1.015 % Difference:(+/-5%) 1.61% PASS BB#4-(05-21-09)
IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

RJN 05/27/2009 

### POST - TEST CALIBRATION CHECK

CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Service s A ir Services Grou p

Shared Resource

Calibration Date: Responsible Party:

Nozzle Maximum 

### Average

I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.292 0.293 0.293 0.001 0.115 ^SN04 0.323 0.324 0.321 0.003 0.127 ^SN05 0.382 0.383 0.380 0.003 0.150 ^SN06 0.499 0.501 0.501 0.002 0.197 ^SN10 0.755 0.753 0.754 0.002 0.297 ^SN12 0.985 0.986 0.988 0.003 0.388 ^SN15 0.415 0.415 0.417 0.002 0.164 ^SN16 0.505 0.505 0.507 0.002 0.199 ^SN19 0.712 0.712 0.714 0.002 0.281 ^SN22 0.937 0.938 0.937 0.001 0.369 ^SN30 0.795 0.795 0.796 0.001 0.313 ^SN36 0.474 0.476 0.474 0.002 0.187 ^SN37 0.525 0.523 0.525 0.002 0.206 ^SN38 0.637 0.635 0.638 0.003 0.251 ^SN46 0.482 0.482 0.484 0.002 0.190 ^SN47 0.514 0.515 0.515 0.001 0.203 ^SN48 0.638 0.638 0.640 0.002 0.251 ^SN50 0.793 0.790 0.792 0.003 0.312 ^SN58 0.613 0.614 0.613 0.001 0.241 ^SN68 0.624 0.625 0.625 0.001 0.246 ^SN69 0.949 0.949 0.947 0.002 0.373 ^SN70 1.564 1.564 1.564 0.000 0.616 ^SN71 1.563 1.563 1.563 0.000 0.615 ^SN72 0.958 0.958 0.960 0.002 0.377 ^SN73 1.283 1.282 1.283 0.001 0.505 ^SN74 1.229 1.229 1.230 0.001 0.484 ^SN75 0.536 0.536 0.536 0.000 0.211 ^SN76 0.632 0.632 0.632 0.000 0.249 ^SN77 0.691 0.691 0.691 0.000 0.272 

### Nozzle Diameter, D n 

### (cm) QUARTERLY NOZZLE CALIBRATIONS

STEEL NOZZLE SET

04/27/2009 RJN

### Environmental Service s A ir Services Grou p

Shared Resource Calibration Date: Calibration Personnel: Test Designation:

Maximum 

### Average
D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

0.210 0.210 0.211 0.001 0.210

Data Notations: Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN75 was 0.211

Difference (Pre-test/Post-test) is: 0.001 PASS POST TEST NOZZLE CALIBRATION

Nozzle
Identifier Nozzle Diameter, D n 

### (in) 05/22/2009 SEG BB #4-(05/21/09



### SN75

### Air Services Group

Shared Pyrometer Under Test Pyrometer Number: ^PY20 Labworks Sample # Calibration Date: 03/19/2009

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: AOA024 Date of Last Calibration: 04/29/2009 Calibration Personnel (Typed and Signature):

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 398 2 2 

### 212 213 -1 3 

### 32 32 0

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### Pyrometer Calibration

0

SEG



### 20-Mar-09

### Pitot Tube ID # Calibration Date Operating Quarter/Year: 2/2009 Openings Damaged? ___ Y

_ _

_ N Repaired?

_ __ _ Y ___ N ___ N/A

Labworks #:

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0 degrees Dt 0.48 < Dt > 0.95 cm

α 2 0 degrees α < 10 degrees β 1 0 degrees β 2 0 degrees β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α

, Ζ

, and W Determination s β 2 < 5 degrees (alongside bottom impact openings)

ψ 0 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.32 cm W < 0.08 cm (Asin ο )

Ζ 0.000 cm Α distance between tips

ο angle of plane on side of pitots

ο 0 degrees ψ angle between tips
W 0.000 cm



### Comments:

Calibrated by: PITOT TUBE CALIBRATION DATA SHEET

PT12

04/28/2009 

### Shared Resource

0

Pass
Pass
Pass ( α 1 measured across top impact openings) 

### Pass ( α 2 measured across bottom impact openings)



### Pass

Pass

NOTES All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.



### REMOVABLE

RJN

### Environmental Services Air Services Group

Blue Team Instrument Number: Calibration Date: Calibration Personnel:

Difference T ime "H g 9:00 -0.01 10:30 -0.01 11:30 0.01

Avera g e Difference: -0.00333

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA.

Comments (Note any ad j ustments): BAROMETER CALIBRATION

^BR07 04/21/2009 SEG

Barometer Readin g Reference Readin g Inches Mercury Inches Mercury 30 30.01 30 30.01 30.03 30.02

Current Conditions at Tampa International Airport

# A-4

FIELD DATA SHEETS

# A-5

CHAIN OF CUSTODY

# APPENDIX B

AMMONIA SLIP TEST DATA

# B-1

RUN DATA

# B-2

RAW DATA

# B-3

METHOD MAP

### EPA METHOD 320 - METHOD MAP

OVERALL CONC UNCERTAINTIES OCU

OCUcomp is the maximum of RSAc omp times OFUcomp or MAUcomp OFUcomp is the maximum of FRUcomp, FCUcomp, FAUcomp, and FMUcomp RSAcomp is the typical concentratio n observed in data set [Appendix I]

MAUcomp is calculated using Appendix D information

RMS is the root mean square noise level of the system [Appendix C]or noise levels observed in the specific analyt ical regions used [Appendix G] DLcomp, Aucomp, and AAIcomp ar e described in Appendix B FUcomp, FLcomp, are the upper and lower wa venumber limits of the analysis region used in a method.

FRUcomp is calculated using Appendix E a nd is based on the comparison of two CTS data sets.

SRMScomp is the average of the RMS value ob served for each subtracted pair of CTS spectra BAVcomp is the average of the calculated areas for each added pair of CTS spectra FFUcts and FFLcts are the upper and lower li mits of the CTS analysis region used

FCUcomp is determined by using Appendix F procedures if reference spectra are produced or are from an unknown source. If reference spectra are obtained from a docum ented source and the error in values can be provided by the supplier then that value can be used to define the component FCU value. For Hitran calculated spectra the FCU is minimal and should set at 0.05 [0.5%] If a set of references are us ed in the method and there is unc ertainity in concentration of any spectrum in the set then Appendi x F procedures should be applied

FAUcomp is determined using Appendix H procedures

Part of the procedure is used to determine cell pathlength. A bette r procedure involving ASTM-D6348 and using a freon gas can be substituted for cell path confirmation. Two added sets of CTS spectra are required wi th a minimum of 3 spectra per set made at the CTS ref pressure. These sets are used to compare CTS ba nd area absorbance [ average or integrated] Use the average of the results for each spectra used in these caluculations for final FAU

FMUcomp is determined using Appendix I procedures

### These calculations require actual sample spec tra. The number is not specified so a minimum of three are suggested. These spectra may or may not have the co mponent[s] of interest present. RSAcomp is the reported concentration of the component in the spectrum being used. AAI is the area of the comp absorbance at the concentration determined by AUcomp and DLcomp. RMSScomp is RMS evaluation of the spectru m resulting from subtraction of all compounds and interferents pres ent in an analysis region

Note: Above guidance assumes only one anal ysis region is used for concentration determination of a component. If more than one region is used the results of all calulati ons must be the weighted average of all regions The weighting factor is dete rmined by the size of each region in wavenumbers.

Note2: If analysis software includes region window selectio n ability to editted out large interfereant peaks and [or] dynamic reference selection then CLS results using an assembled method will often be better than methd 320 calculations reported.

# B-4

SUMMARIZED QA DATAEnvironmental Services Air Services Group FTIR LAB REPORT

Location: Big Bend Unit: 4 Test Date: 05/21/2009

Peak Analysis: ACLF: 15798.2575 PASSED
FWHH: 0.4856 PASSED Single Beam: 0.97 PASSED Ethylene CTS Spectra: Low Range Pre-Test: 20.8898276 PASSED 20.96 0.4192 Low Range Post-Test: 20.886514 PASSED 21.3792 20.5408
0.0033136 Difference

SNR Test(3 Run Mean)

920-975 cm-1 987-1087 cm-1 2900-3000 cm-1 RMS Noise: 0.068498 0.073051 0.122081 MAU: 0.297484 0.31725 0.530183 SNR: 1466 1370 820

Cylinder Bottles: NH3 Cylinder S/N:NH3 Cylinder S/N: EA-0004542 N2 Cylinder S/N: CC-125621 Expiration Date: 28-Jan-10 Expiration Date: 20-Mar-12 Bottle Pressure: 1900/1400 Bottle Pressure: 1800/1400

CTS Cylinder S/N:CTS Cylinder S/N: 4020902 Freon Cylinder S/N: N/A Expiration Date: 28-Jan-12 Expiration Date: N/A Bottle Pressure: 1400/300 Bottle Pressure: N/A

Temperatures: Umbilical #1(10 Foot): 300 PASSED Probe: 300 PASSED

FTIR Leak Check: Vac. Initial 0.120 Maximum 0.122 Leakage 0.002 % Leak 2.003 * Must be < 4%

Barometric Pressure 29.68 System Pressure 0.9553 Spike Response Time Up/Down 45

# B-5

LEAK RATE DATALeak Rates

Spectrum Date Time CO2high WaterH Temp (C) Pressure (Atm) LEAK RATE_000001.LAB 05/21/2009 47:20.3 -0.02093 3.677043 150 0.119562 LEAK RATE_000002.LAB 05/21/2009 47:29.7 -0.02167 3.781037 150 0.120012 LEAK RATE_000003.LAB 05/21/2009 47:39.0 -0.0178 3.904974 150 0.119958 LEAK RATE_000004.LAB 05/21/2009 47:48.4 -0.01725 3.855458 150 0.120012 LEAK RATE_000005.LAB 05/21/2009 47:57.8 -0.01622 3.959517 150 0.120279 LEAK RATE_000006.LAB 05/21/2009 48:07.2 -0.01247 4.198507 150 0.120529 LEAK RATE_000007.LAB 05/21/2009 48:16.6 -0.01965 4.145409 150 0.120851 LEAK RATE_000008.LAB 05/21/2009 48:26.0 -0.0176 4.231237 150 0.120694 LEAK RATE_000009.LAB 05/21/2009 48:35.4 -0.01257 4.334605 150 0.12104 LEAK RATE_000010.LAB 05/21/2009 48:44.9 -0.01256 4.341918 150 0.121172 LEAK RATE_000011.LAB 05/21/2009 48:54.2 -0.00689 4.456692 150 0.121386 LEAK RATE_000012.LAB 05/21/2009 49:03.6 -0.013 4.187246 150 0.121578 LEAK RATE_000013.LAB 05/21/2009 49:13.1 -0.01645 4.559827 150 0.121586 LEAK RATE_000014.LAB 05/21/2009 49:22.4 -0.0058 4.426224 150 0.121739 LEAK RATE_000015.LAB 05/21/2009 49:31.8 -0.01877 4.361546 150 0.121957

Page 1 of 1

# B-6

ETHYLENE CTS DATAEthylene CTS standard Results - Tampa Electric MKS FTIR System#Lower Region Upper Region Lower UpperDate Dif.-nominal 949.43 pk Dif.-nominal 2988.4 pk Standard Conc. 900-1000cm-1 reg 2800-3050cm-1 reg Region % dif. Region %dif.[cm-1] [cm-1] PPM reported conc. PPM reported conc. PPMExample 0.024 8:24:00 5.03 4.41843 3.854914 12.1584493 23.361550720LOW RANGEPre-TestSpectrum Date Time C2H4 Temp (C) Pressure (Atm)PRECHECK_00000705/21/2009 8:34:54 21.055968 150 0.964972PRECHECK_00000805/21/2009 8:35:50 20.833107 150 0.964264PRECHECK_00000905/21/2009 8:36:46 20.825958 150 0.96427PRECHECK_00001005/21/2009 8:37:43 20.823475 150 0.962623PRECHECK_000011 05/21/2009 8:38:39 20.91063 150 0.963794Post-TestSpectrum Date Time C2H4 Temp (C) Pressure (Atm)CTS_000409.LAB 05/21/2009 16:01:27 20.791885 150 0.971425CTS_000410.LAB 05/21/2009 16:02:23 20.827944 150 0.998068CTS_000411.LAB 05/21/2009 16:03:20 20.844568 150 1.004292CTS_000412.LAB 05/21/2009 16:04:16 20.970343 150 1.026814CTS_000413.LAB 05/21/2009 16:05:12 20.99783 150 1.077998

# B-7

SPIKE DATACOMPOUND SPIKING INFORMATION SHEET: BB#4 ComplianceAll conc. in PPM All Flow in LIT/MinSpike Label Spike Gas Spike Gas Total Flow Spike Gas Spike Gas SF56 Gas Exptd SF6 Expt Sample Trv Cell Flush Wait min prior Native sample cal line lengthIn Conc. Flow Rate Rate FR % of Tot Flow Conc. In Conc. Sample Conc. Time to Cell [min] Time [min] / after spike dilution correction [meters]Preliminary 50.1 1 11 9.090909091 5.664237755 2.99 0.249616 1.2828 0.40909091 1.86108 0.909091 33Mid Spike 50.1 1 11 9.090909091 5.350227089 2.99 0.252144 1.2828 0.40909091 1.86108 0.909091 33Final 50.1 1 11 9.090909091 5.293497864 2.99 0.252302 1.2828 0.40909091 1.86108 0.909091 33Note:Tank Certified Concentrations : 50.1 2.99Sample lines are assumed as 3/8 OD [ 9/32" ID]Calibration lines are assumed as 1/4 OD [ 3/32" ID]Cell volume is assumed as 1.5 litersPreliminary NativeNH3 1.11SF6 -0.02First RunNH3 0.80SF6 -0.02Second RunNH3 0.74SF6 -0.02Third RunNH3 0.62SF6 -0.02NativeSpectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000001.LAB 05/21/2009 9:56:51 9.571389 15.37527 -0.022572 1.110467 150 0.958112RAW_000002.LAB 05/21/2009 9:57:47 9.650423 15.579446 -0.02016 1.099675 150 0.957737RAW_000003.LAB 05/21/2009 9:58:44 9.664538 15.498573 -0.023199 1.184036 150 0.957231RAW_000004.LAB 05/21/2009 9:59:40 9.525 15.270251 -0.01899 1.100407 150 0.959022RAW_000005.LAB 05/21/2009 10:00:36 9.547134 15.460906 -0.02153 1.096363 150 0.957458RAW_000006.LAB 05/21/2009 10:01:33 9.548934 15.621311 -0.021382 1.149348 150 0.957844RAW_000007.LAB 05/21/2009 10:02:29 9.455227 15.470348 -0.023698 1.114115 150 0.958647RAW_000008.LAB 05/21/2009 10:03:26 9.478468 15.403819 -0.023724 1.07004 150 0.958236RAW_000009.LAB 05/21/2009 10:04:22 9.544648 15.643941 -0.024079 1.091974 150 0.958272RAW_000010.LAB 05/21/2009 10:05:18 9.460892 15.631537 -0.02269 1.080498 150 0.959569Preliminary SpikeSpectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000011.LAB 05/21/2009 10:06:15 8.414733 14.218709 0.216614 0.766196 150 0.961527RAW_000012.LAB 05/21/2009 10:07:11 8.317543 13.923193 0.251455 1.632104 150 0.961134RAW_000013.LAB 05/21/2009 10:08:08 8.332355 14.064097 0.247891 2.237182 150 0.959284RAW_000014.LAB 05/21/2009 10:09:04 8.353111 13.872268 0.249611 2.611062 150 0.960671RAW_000015.LAB 05/21/2009 10:10:00 8.342266 13.772104 0.251257 2.967268 150 0.96048RAW_000016.LAB 05/21/2009 10:10:57 8.343999 13.930647 0.249264 3.172666 150 0.960605RAW_000017.LAB 05/21/2009 10:11:53 8.344879 13.985506 0.248277 3.343473 150 0.960837RAW_000018.LAB 05/21/2009 10:12:50 8.327165 13.816005 0.250494 3.510818 150 0.959462RAW_000019.LAB 05/21/2009 10:13:46 8.295203 13.874017 0.249005 3.62704 150 0.959052RAW_000020.LAB 05/21/2009 10:14:42 8.256015 13.990845 0.247073 3.686025 150 0.959545RAW_000021.LAB 05/21/2009 10:15:39 8.284556 13.898525 0.248444 3.807125 150 0.959736RAW_000022.LAB 05/21/2009 10:16:35 8.273056 13.787793 0.246917 3.861018 150 0.960402RAW_000023.LAB 05/21/2009 10:17:32 8.275966 13.964545 0.247412 3.915745 150 0.959152RAW_000024.LAB 05/21/2009 10:18:28 8.27115 14.014067 0.247418 3.987342 150 0.958385RAW_000025.LAB 05/21/2009 10:19:24 8.33917 13.820909 0.246521 4.07038 150 0.959379RAW_000026.LAB 05/21/2009 10:20:21 8.320519 13.833763 0.24763 4.169982 150 0.959551RAW_000027.LAB 05/21/2009 10:21:17 8.422175 13.991079 0.246746 4.193979 150 0.959647RAW_000028.LAB 05/21/2009 10:22:14 8.33611 13.866765 0.248091 4.239352 150 0.959837RAW_000029.LAB 05/21/2009 10:23:10 8.346263 13.726868 0.248022 4.255335 150 0.96139RAW_000030.LAB 05/21/2009 10:24:06 8.337697 13.927172 0.245212 4.304216 150 0.959046RAW_000031.LAB 05/21/2009 10:25:03 8.332434 13.999169 0.246834 4.335892 150 0.958528RAW_000032.LAB 05/21/2009 10:25:59 8.271807 13.81152 0.247593 4.371319 150 0.959111RAW_000033.LAB 05/21/2009 10:26:55 8.291526 13.837884 0.248992 4.441643 150 0.959486RAW_000034.LAB 05/21/2009 10:27:52 8.221155 13.99145 0.250286 4.465228 150 0.959688RAW_000035.LAB 05/21/2009 10:28:48 8.202179 13.949442 0.247868 4.47871 150 0.960533RAW_000036.LAB 05/21/2009 10:29:45 8.254481 13.769145 0.249587 4.551546 150 0.960069RAW_000037.LAB 05/21/2009 10:30:41 8.315633 13.828757 0.245283 4.484059 150 0.95955RAW_000038.LAB 05/21/2009 10:31:37 8.282946 13.958423 0.246597 4.459526 150 0.960146RAW_000039.LAB 05/21/2009 10:32:34 8.338794 13.970686 0.242073 4.48283 150 0.957439RAW_000040.LAB 05/21/2009 10:33:30 8.361159 14.02122 0.242994 4.492259 150 0.956332RAW_000041.LAB 05/21/2009 10:34:27 8.312418 14.018682 0.243577 4.45385 150 0.957445RAW_000042.LAB 05/21/2009 10:35:23 8.36093 14.02636 0.240693 4.4571 150 0.9565290.242421333 4.4677363Results-Recovery97.12% 78.88%Mid SpikeSpectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000131.LAB 05/21/2009 12:00:38 9.414345 15.690762 -0.01851 0.64598 150 0.962592RAW_000132.LAB 05/21/2009 12:01:35 8.323884 14.604865 0.215248 0.310473 150 0.964633RAW_000133.LAB 05/21/2009 12:02:31 8.293777 14.09477 0.260682 0.354719 150 0.963794RAW_000134.LAB 05/21/2009 12:03:28 8.327495 14.238074 0.257961 0.722653 150 0.963758RAW_000135.LAB 05/21/2009 12:04:24 8.288538 14.353838 0.260877 1.123555 150 0.962734RAW_000136.LAB 05/21/2009 12:05:21 8.317845 14.154359 0.258554 1.49666 150 0.963752RAW_000137.LAB 05/21/2009 12:06:17 8.306508 14.195277 0.259934 1.9116 150 0.962675RAW_000138.LAB 05/21/2009 12:07:14 8.226913 14.338928 0.260884 2.22242 150 0.963865RAW_000139.LAB 05/21/2009 12:08:10 8.287744 14.295667 0.257433 2.497309 150 0.962985RAW_000140.LAB 05/21/2009 12:09:06 8.296001 14.115497 0.25784 2.746342 150 0.96229RAW_000141.LAB 05/21/2009 12:10:03 8.331204 14.254138 0.260512 3.029011 150 0.963421RAW_000142.LAB 05/21/2009 12:10:59 8.263595 14.312464 0.260522 3.205731 150 0.963709RAW_000143.LAB 05/21/2009 12:11:56 8.266532 14.156622 0.258512 3.35172 150 0.963621RAW_000144.LAB 05/21/2009 12:12:52 8.251986 14.098066 0.262475 3.496376 150 0.962717RAW_000145.LAB 05/21/2009 12:13:48 8.25275 14.29827 0.258408 3.694846 150 0.962938RAW_000146.LAB 05/21/2009 12:14:45 8.229365 14.304665 0.255118 3.743775 150 0.962812RAW_000147.LAB 05/21/2009 12:15:41 8.182514 14.128282 0.259316 3.86432 150 0.963276RAW_000148.LAB 05/21/2009 12:16:38 8.213764 14.24658 0.259417 3.962146 150 0.962771RAW_000149.LAB 05/21/2009 12:17:34 8.298604 14.406182 0.260196 4.024177 150 0.962794RAW_000150.LAB 05/21/2009 12:18:30 8.258108 14.267814 0.258031 4.001077 150 0.962943RAW_000151.LAB 05/21/2009 12:19:27 8.23058 14.162892 0.259268 4.040577 150 0.963788RAW_000152.LAB 05/21/2009 12:20:23 8.290249 14.386847 0.25776 4.132456 150 0.963049RAW_000153.LAB 05/21/2009 12:21:20 8.349968 14.384175 0.258154 4.176603 150 0.963128RAW_000154.LAB 05/21/2009 12:22:16 8.324376 14.167949 0.259615 4.157514 150 0.963604RAW_000155.LAB 05/21/2009 12:23:13 8.334044 14.265654 0.257933 4.220736 150 0.962759RAW_000156.LAB 05/21/2009 12:24:09 8.313623 14.431666 0.258229 4.243697 150 0.96255RAW_000157.LAB 05/21/2009 12:25:06 8.209853 14.274137 0.256305 4.295358 150 0.963055RAW_000158.LAB 05/21/2009 12:26:02 8.299555 14.156803 0.259463 4.25045 150 0.963949RAW_000159.LAB 05/21/2009 12:26:58 8.334809 14.37405 0.258718 4.3592 150 0.962132RAW_000160.LAB 05/21/2009 12:27:55 8.320801 14.35539 0.255405 4.331233 150 0.963151RAW_000161.LAB 05/21/2009 12:28:51 8.204269 14.10346 0.256178 4.352884 150 0.963508RAW_000162.LAB 05/21/2009 12:29:47 8.271558 14.196736 0.258894 4.426425 150 0.9642050.256825667 4.3701807Results-Recovery101.86% 81.68%Final SpikeSpectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000331.LAB 05/21/2009 15:08:44 9.087673 15.545847 0.034169 0.471141 150 0.961021RAW_000332.LAB 05/21/2009 15:09:41 8.316373 14.549508 0.262444 0.215333 150 0.960443RAW_000333.LAB 05/21/2009 15:10:38 8.269835 14.40519 0.263146 0.197649 150 0.959926RAW_000334.LAB 05/21/2009 15:11:34 8.289158 14.201839 0.263255 0.380378 150 0.961569RAW_000335.LAB 05/21/2009 15:12:30 8.257661 14.33254 0.261583 0.639869 150 0.959879RAW_000336.LAB 05/21/2009 15:13:27 8.292715 14.378548 0.261123 0.946546 150 0.960531RAW_000337.LAB 05/21/2009 15:14:23 8.185153 14.171334 0.260161 1.247186 150 0.961081RAW_000338.LAB 05/21/2009 15:15:20 8.149281 14.154103 0.262098 1.422308 150 0.96017RAW_000339.LAB 05/21/2009 15:16:16 8.178864 14.308905 0.258384 1.643827 150 0.960414RAW_000340.LAB 05/21/2009 15:17:13 8.228129 14.25363 0.261585 1.790565 150 0.961188RAW_000341.LAB 05/21/2009 15:18:09 8.218201 14.110685 0.260807 1.950675 150 0.96045RAW_000342.LAB 05/21/2009 15:19:05 8.22594 14.238516 0.261057 2.184233 150 0.960379RAW_000343.LAB 05/21/2009 15:20:02 8.217563 14.302813 0.260497 2.352208 150 0.959503RAW_000344.LAB 05/21/2009 15:20:58 8.308079 14.196646 0.257706 2.533771 150 0.959551RAW_000345.LAB 05/21/2009 15:21:55 8.267305 14.161286 0.258724 2.719881 150 0.959534RAW_000346.LAB 05/21/2009 15:22:51 8.218225 14.302692 0.259348 2.959884 150 0.959438RAW_000347.LAB 05/21/2009 15:23:48 8.29031 14.264668 0.25928 3.151886 150 0.959968RAW_000348.LAB 05/21/2009 15:24:44 8.299126 14.082866 0.259543 3.355879 150 0.959333RAW_000349.LAB 05/21/2009 15:25:41 8.251649 14.144494 0.258471 3.487445 150 0.960075RAW_000350.LAB 05/21/2009 15:26:37 8.344042 14.264525 0.256943 3.687453 150 0.959718RAW_000351.LAB 05/21/2009 15:27:33 8.25653 14.11426 0.259 3.766756 150 0.959908RAW_000352.LAB 05/21/2009 15:28:30 8.241554 14.080467 0.262228 3.849185 150 0.959647RAW_000353.LAB 05/21/2009 15:29:26 8.255683 14.259041 0.255654 3.927996 150 0.95973RAW_000354.LAB 05/21/2009 15:30:23 8.227933 14.255063 0.257031 3.971992 150 0.958641RAW_000355.LAB 05/21/2009 15:31:19 8.325161 14.067875 0.255471 4.008022 150 0.960099RAW_000356.LAB 05/21/2009 15:32:16 8.270023 14.147918 0.257133 4.104521 150 0.959941RAW_000357.LAB 05/21/2009 15:33:12 8.312762 14.286307 0.254015 4.185822 150 0.960379RAW_000358.LAB 05/21/2009 15:34:09 8.262644 14.165361 0.258552 4.192727 150 0.960581RAW_000359.LAB 05/21/2009 15:35:05 8.285486 14.073093 0.260446 4.289372 150 0.962396RAW_000360.LAB 05/21/2009 15:36:01 8.227065 14.24756 0.258451 4.329121 150 0.961533RAW_000361.LAB 05/21/2009 15:36:58 8.278161 14.22448 0.259775 4.382397 150 0.961302RAW_000362.LAB 05/21/2009 15:37:54 8.255054 14.0475 0.263432 4.431328 150 0.96142RAW_000363.LAB 05/21/2009 15:38:51 8.305893 14.093783 0.260695 4.502025 150 0.961592RAW_000364.LAB 05/21/2009 15:39:47 8.252356 14.220447 0.25836 4.512483 150 0.96136RAW_000365.LAB 05/21/2009 15:40:44 8.264661 14.058598 0.258085 4.467692 150 0.960251RAW_000366.LAB 05/21/2009 15:41:40 8.367954 13.993873 0.259192 4.502998 150 0.960593RAW_000367.LAB 05/21/2009 15:42:36 8.366025 14.164224 0.25988 4.55746 150 0.960087RAW_000368.LAB 05/21/2009 15:43:33 8.317135 14.176866 0.256888 4.51077 150 0.9599140.258653333 4.5237427Results-Recovery102.52% 85.46%

# B-8

SNR TEST DATASNR-Test

SNR Report, 05/21/2009, 8:02 AM Number of Scans = 60 Resolution = .5 cm-1 Single Sided

Pass 1 Range = 920-975 cm-1, RMS Noise=0.062624% (0.271955 mAU), SNR=1597 Range = 987-1087 cm-1, RMS Noise=0.072422% (0.314509 mAU), SNR=1381 Range = 2900-3000 cm-1, RMS Noise=0.116985% (0.507984 mAU), SNR=855

Pass 2 Range = 920-975 cm-1, RMS Noise=0.069386% (0.301382 mAU), SNR=1441 Range = 987-1087 cm-1, RMS Noise=0.071497% (0.310504 mAU), SNR=1399 Range = 2900-3000 cm-1, RMS Noise=0.125246% (0.543974 mAU), SNR=798

Pass 3 Range = 920-975 cm-1, RMS Noise=0.073482% (0.319116 mAU), SNR=1361 Range = 987-1087 cm-1, RMS Noise=0.075235% (0.326739 mAU), SNR=1329 Range = 2900-3000 cm-1, RMS Noise=0.124013% (0.538590 mAU), SNR=806

Mean Results Range = 920-975 cm-1, RMS Noise=0.068498% (0.297484 mAU), SNR=1466 Range = 987-1087 cm-1, RMS Noise=0.073051% (0.317250 mAU), SNR=1370 Range = 2900-3000 cm-1, RMS Noise=0.122081% (0.530183 mAU), SNR=820

RMS Noise Mau SNR 920-975 cm-1 0.068498 0.297484 1466 987-1087 cm-1 0.073051 0.31725 1370 2900-3000 cm-1 0.122081 0.530183 820

Page 1 of 1

# B-9

ANNUAL CELL PATH CHECK DATAPathLength Verification Spread SheetTAMPA ELECTRICStack FTIR Systemtest gas information reference information calculated path lengthdate F116 conc F116 press F116 temp. pk area F116 conc F116 pressF116 temp pk area [meters] expected % dif AcceptablePPM mm deg C 1080-1160 PPM-M mm deg C 1080-1160 [<+/-5%]test 35 680 150 5.9 206.9 761 185 7.09 5.084645 5.11 -0.49866205/09/2007 35 781.28 149.7 6.557 206.9 761 185 7.09 4.914824 5.11 -3.971165 YES01/06/2009 34.8 791.1 149.5 6.353 206.9 761 185 7.09 4.727596 5.11 -8.088771 NOadj PL-1/6/2009 34.8 791.1 149.5 6.353 206.9 761 185 7.09 4.727596 4.82 -1.954575 YES4.82 meters is the next logical pathlength lower than the std 5.11 meters. Based on the next highest path length seen in MKS spectra of 5.4 meter. [ dif of 0.29meters]

# B-10

CYLINDER GAS CERTIFICATES OF ANALYSIS

# APPENDIX C

CONTINUOUS EMISSIONS MONITORING DATANOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 8:00 53.9 12.32 77.2 11 05/21/2009 8:01 54.3 12.29 81.2 11.06 05/21/2009 8:02 53.1 12.28 90.6 11.01 05/21/2009 8:03 51.3 12.31 95.5 11.04 05/21/2009 8:04 51 12.38 106.7 11.07 05/21/2009 8:05 51.3 12.36 108.2 11.07 05/21/2009 8:06 49.9 12.37 113.3 11.16 05/21/2009 8:07 48.3 12.43 117.4 11.04 05/21/2009 8:08 48.4 12.4 120.9 10.96 05/21/2009 8:09 49.6 12.27 109.6 11 05/21/2009 8:10 49.1 12.26 91.4 11.02 05/21/2009 8:11 49.5 12.27 82.2 11 05/21/2009 8:12 50 12.26 80.5 10.98 05/21/2009 8:13 51.3 12.33 84.6 11.04 05/21/2009 8:14 50.6 12.3 94.7 11.05 05/21/2009 8:15 49.6 12.37 97.4 11.08 05/21/2009 8:16 49.2 12.39 102.2 11.22 05/21/2009 8:17 47.8 12.46 108.6 11.15 05/21/2009 8:18 47.1 12.48 113.7 11.13 05/21/2009 8:19 47.6 12.43 119.1 11.1 05/21/2009 8:20 46.9 12.42 131.6 11.07 05/21/2009 8:21 46.9 12.46 132.2 11 05/21/2009 8:22 48.8 12.34 104.4 11.05 05/21/2009 8:23 48.4 12.33 89 11.02 05/21/2009 8:24 49.7 12.34 94.1 11.04 05/21/2009 8:25 49.1 12.3 98.2 11.05 05/21/2009 8:26 51.2 12.33 95 11.06 05/21/2009 8:27 52 12.35 103.4 11.09 05/21/2009 8:28 52.2 12.34 111.5 11.09 05/21/2009 8:29 51.8 12.39 111.5 11.1 05/21/2009 8:30 52.2 12.39 113.6 11.08 05/21/2009 8:31 51.1 12.39 124.1 11.05 05/21/2009 8:32 50.7 12.36 138.9 11.03 05/21/2009 8:33 50.2 12.35 140.7 11.06 05/21/2009 8:34 49.6 12.4 115.4 11.13 05/21/2009 8:35 49.1 12.43 91 11.02 05/21/2009 8:36 50.2 12.39 86.2 11.06 05/21/2009 8:37 50.8 12.32 93.1 10.99 05/21/2009 8:38 50.9 12.28 99.3 11.01 05/21/2009 8:39 51.4 12.29 111.4 11.04 05/21/2009 8:40 51.2 12.33 121.7 11.05 05/21/2009 8:41 51.5 12.36 130.3 11.06 05/21/2009 8:42 51.3 12.35 136.3 11.02

Page 1 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 8:43 50.9 12.32 134.3 11.03 05/21/2009 8:44 51.7 12.35 124.2 11.02 05/21/2009 8:45 51 12.35 98.1 11.06 05/21/2009 8:46 49.7 12.36 84.3 11.01 05/21/2009 8:47 48.9 12.33 75.9 11.11 05/21/2009 8:48 48.9 12.32 82 11.03 05/21/2009 8:49 49.5 12.31 85.3 11.03 05/21/2009 8:50 48.9 12.31 94 10.98 05/21/2009 8:51 48.8 12.32 114.7 10.95 05/21/2009 8:52 49.9 12.28 128 10.99 05/21/2009 8:53 51 12.31 136.1 10.97 05/21/2009 8:54 51.8 12.27 144.6 10.97 05/21/2009 8:55 51.6 12.29 137.6 10.97 05/21/2009 8:56 51.8 12.3 128.3 11.1 05/21/2009 8:57 50.3 12.33 98.6 11.12 05/21/2009 8:58 49.5 12.39 88.4 11.12 05/21/2009 8:59 48.8 12.43 95.8 11.13 05/21/2009 9:00 49.2 12.43 102.7 11.07 05/21/2009 9:01 49.5 12.4 108.5 11 05/21/2009 9:02 49.8 12.37 116.6 11.02 05/21/2009 9:03 49.7 12.26 126.2 11.01 05/21/2009 9:04 49.6 12.3 133.1 11.02 05/21/2009 9:05 50 12.3 148.2 10.97 05/21/2009 9:06 51.6 12.27 149 11 05/21/2009 9:07 51.6 12.27 140.5 11.03 05/21/2009 9:08 52.3 12.29 113.9 11 05/21/2009 9:09 52.6 12.31 90.6 11.12 05/21/2009 9:10 51.8 12.35 91 11.05 05/21/2009 9:11 52.6 12.34 103.1 11.03 05/21/2009 9:12 52.3 12.3 103.1 11.05 05/21/2009 9:13 52 12.32 111.7 11.02 05/21/2009 9:14 52 12.3 121.2 10.93 05/21/2009 9:15 51.9 12.25 126.5 10.96 05/21/2009 9:16 51.5 12.27 147.5 10.93 05/21/2009 9:17 51.3 12.24 143.3 10.94 05/21/2009 9:18 52.3 12.24 133.7 10.94 05/21/2009 9:19 52.6 12.25 119.4 11.04 05/21/2009 9:20 50.5 12.32 109.3 11.07 05/21/2009 9:21 49.1 12.38 86.2 11.13 05/21/2009 9:22 49.3 12.4 89.1 11.1 05/21/2009 9:23 48.9 12.39 97.9 11.08 05/21/2009 9:24 48.3 12.38 101.6 11.05 05/21/2009 9:25 48.1 12.38 93.9 11.03

Page 2 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 9:26 48.3 12.32 94.7 11.07 05/21/2009 9:27 47.9 12.34 107.8 10.95 05/21/2009 9:28 48.9 12.32 105.1 10.92 05/21/2009 9:29 49.2 12.21 95.2 11 05/21/2009 9:30 48.3 12.26 104.2 11.07 05/21/2009 9:31 49.2 12.35 117.4 11.05 05/21/2009 9:32 49.6 12.36 118.7 11.06 05/21/2009 9:33 50 12.36 125.9 11.05 05/21/2009 9:34 49.8 12.38 122.8 11.02 05/21/2009 9:35 49.7 12.35 103.1 11.04 05/21/2009 9:36 49.6 12.41 97.1 11.03 05/21/2009 9:37 49.9 12.36 109.4 11.02 05/21/2009 9:38 49.8 12.34 105.5 10.98 05/21/2009 9:39 49.1 12.34 99.5 11.04 05/21/2009 9:40 48.8 12.32 98.4 11 05/21/2009 9:41 49.4 12.35 104.2 11.06 05/21/2009 9:42 49.1 12.36 106.4 11.04 05/21/2009 9:43 49.5 12.44 109.7 10.98 05/21/2009 9:44 49.6 12.37 110.4 11.05 05/21/2009 9:45 50.1 12.39 119.5 10.99 05/21/2009 9:46 50.5 12.33 132.7 10.96 05/21/2009 9:47 49.7 12.35 136.7 10.98 05/21/2009 9:48 50.5 12.32 127.2 10.92 05/21/2009 9:49 50.3 12.28 103.3 11.03 05/21/2009 9:50 50.4 12.31 88.4 10.98 05/21/2009 9:51 51.2 12.32 89.3 11.05 05/21/2009 9:52 50.7 12.33 93.1 11.07 05/21/2009 9:53 50.2 12.42 99.5 11.06 05/21/2009 9:54 49.6 12.45 101.9 11 05/21/2009 9:55 50.8 12.39 102.8 10.99 05/21/2009 9:56 51.1 12.33 110.2 10.99 05/21/2009 9:57 51.5 12.31 121.5 10.94 05/21/2009 9:58 51.9 12.33 134.6 10.98 05/21/2009 9:59 52.3 12.38 140 10.99 05/21/2009 10:00 52.3 12.31 125.2 11.03 05/21/2009 10:01 50.9 12.36 97.6 11.03 05/21/2009 10:02 26.4 10.7 28.5 4.35 05/21/2009 10:03 6.8 2.94 28.9 1.54 05/21/2009 10:04 0.5 0.47 92 9.33 05/21/2009 10:05 0.6 0.09 100.6 11.07 05/21/2009 10:06 0.6 0.07 106.1 11.02 05/21/2009 10:07 13.7 0.29 110.4 11.04 05/21/2009 10:08 53.2 7.75 121.4 11

Page 3 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 10:09 52.9 12.33 129.1 11.01 05/21/2009 10:10 52.9 12.56 134.5 10.99 05/21/2009 10:11 52 12.45 121.3 11.01 05/21/2009 10:12 51.1 12.4 116.9 11.1 05/21/2009 10:13 50.3 12.4 99 11.13 05/21/2009 10:14 49 12.43 83.1 11.13 05/21/2009 10:15 48.2 12.41 87.6 11.08 05/21/2009 10:16 47.3 12.38 101.9 11.08 05/21/2009 10:17 46.3 12.38 104.7 11.05 05/21/2009 10:18 46.8 12.39 106.8 11.02 05/21/2009 10:19 47.2 12.34 112 11.08 05/21/2009 10:20 46.7 12.38 114 10.97 05/21/2009 10:21 48 12.35 116.6 11 05/21/2009 10:22 48.5 12.29 120.9 11.02 05/21/2009 10:23 47.8 12.32 129 11.02 05/21/2009 10:24 48.7 12.37 119.1 11.03 05/21/2009 10:25 49.1 12.36 101.3 11.02 05/21/2009 10:26 51.1 12.34 100.7 10.95 05/21/2009 10:27 51.3 12.28 102.1 10.94 05/21/2009 10:28 51.2 12.3 89.7 11.05 05/21/2009 10:29 52.2 12.34 78.7 11.01 05/21/2009 10:30 51.8 12.26 90.5 11.02 05/21/2009 10:31 50.6 12.29 94.6 11.02 05/21/2009 10:32 49.5 12.33 94 10.97 05/21/2009 10:33 50.2 12.27 105.5 11.05 05/21/2009 10:34 49.4 12.29 119.7 11.08 05/21/2009 10:35 48.9 12.35 122.9 11.05 05/21/2009 10:36 47.8 12.39 123.1 11.07 05/21/2009 10:37 47.5 12.38 110.2 10.98 05/21/2009 10:38 48.2 12.33 107.1 10.98 05/21/2009 10:39 48.9 12.29 112.6 10.96 05/21/2009 10:40 49.2 12.29 123.4 10.97 05/21/2009 10:41 49.7 12.31 120 10.99 05/21/2009 10:42 49.8 12.3 101.9 10.96 05/21/2009 10:43 50.5 12.26 90 10.98 05/21/2009 10:44 50 12.26 96.9 11.04 05/21/2009 10:45 48.4 12.38 105.3 11.05 05/21/2009 10:46 49.5 12.41 114.9 11.07 05/21/2009 10:47 49.7 12.38 123.3 11.04 05/21/2009 10:48 49.3 12.42 127.3 11.01 05/21/2009 10:49 49.4 12.37 119 11.04 05/21/2009 10:50 49 12.39 120.3 11.04 05/21/2009 10:51 48.6 12.39 116.5 11.03

Page 4 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 10:52 49.4 12.36 120.5 10.99 05/21/2009 10:53 48.7 12.39 121.1 10.97 05/21/2009 10:54 50 12.36 124.4 10.98 05/21/2009 10:55 51 12.33 121.8 10.91 05/21/2009 10:56 53 12.26 116.5 10.95 05/21/2009 10:57 53.6 12.24 106.2 10.95 05/21/2009 10:58 53.6 12.32 105 10.95 05/21/2009 10:59 53 12.27 104.6 11 05/21/2009 11:00 51.3 12.34 95.4 10.95 05/21/2009 11:01 51.3 12.32 101.7 10.98 05/21/2009 11:02 51.4 12.31 109.3 11.05 05/21/2009 11:03 50.9 12.32 109.7 11.02 05/21/2009 11:04 49.7 12.29 112 10.97 05/21/2009 11:05 49 12.28 117.4 11 05/21/2009 11:06 48.2 12.32 121.3 10.96 05/21/2009 11:07 48.9 12.26 127 10.92 05/21/2009 11:08 48.7 12.23 136.4 10.97 05/21/2009 11:09 47.5 12.29 145.2 10.98 05/21/2009 11:10 47.1 12.31 134.3 10.95 05/21/2009 11:11 48 12.38 118.8 11.02 05/21/2009 11:12 48.5 12.33 103 11.01 05/21/2009 11:13 49.6 12.36 99.9 10.98 05/21/2009 11:14 50.8 12.27 92.9 10.97 05/21/2009 11:15 50.5 12.25 96.2 10.91 05/21/2009 11:16 51.7 12.22 107.2 10.97 05/21/2009 11:17 51.1 12.21 107 10.91 05/21/2009 11:18 50.8 12.27 107 10.93 05/21/2009 11:19 49.8 12.26 124.2 10.98 05/21/2009 11:20 48.9 12.3 132.5 11.03 05/21/2009 11:21 48.4 12.34 131.7 11 05/21/2009 11:22 48.4 12.38 131.6 11.02 05/21/2009 11:23 48 12.38 135.7 11 05/21/2009 11:24 48.5 12.38 120 10.94 05/21/2009 11:25 50.2 12.3 113.7 10.94 05/21/2009 11:26 49 12.28 95.8 11.05 05/21/2009 11:27 48.7 12.35 84.8 11.07 05/21/2009 11:28 48.3 12.36 85.3 11.05 05/21/2009 11:29 48.8 12.34 98.6 11.04 05/21/2009 11:30 49.3 12.31 99.6 11.02 05/21/2009 11:31 50.2 12.37 98.8 11.03 05/21/2009 11:32 51.4 12.36 99.5 10.96 05/21/2009 11:33 51.7 12.31 115 10.94 05/21/2009 11:34 53 12.33 130.6 10.85

Page 5 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 11:35 54.8 12.2 135.8 10.86 05/21/2009 11:36 53.8 12.22 126.6 10.93 05/21/2009 11:37 53.4 12.23 112.6 10.91 05/21/2009 11:38 53 12.16 106.7 10.96 05/21/2009 11:39 51.7 12.23 114.6 11.02 05/21/2009 11:40 50.1 12.3 116.7 11.02 05/21/2009 11:41 50 12.29 115.8 10.97 05/21/2009 11:42 48.9 12.31 115.8 10.99 05/21/2009 11:43 48.1 12.31 134.7 10.85 05/21/2009 11:44 48.1 12.3 142.5 10.86 05/21/2009 11:45 48.2 12.28 118.1 10.91 05/21/2009 11:46 48.5 12.27 104.8 10.96 05/21/2009 11:47 48.5 12.3 101 10.9 05/21/2009 11:48 49.9 12.25 94.3 10.94 05/21/2009 11:49 49.5 12.24 95 10.96 05/21/2009 11:50 48.4 12.27 97.6 11.01 05/21/2009 11:51 47.5 12.33 100.9 11 05/21/2009 11:52 48.1 12.34 107.9 11.01 05/21/2009 11:53 49.4 12.32 108.9 10.95 05/21/2009 11:54 49.6 12.26 112 10.89 05/21/2009 11:55 50.5 12.21 122.5 10.87 05/21/2009 11:56 50.6 12.21 129.6 10.86 05/21/2009 11:57 50.4 12.2 137.2 10.86 05/21/2009 11:58 50.8 12.21 141.9 10.93 05/21/2009 11:59 51.2 12.24 136.2 10.94 05/21/2009 12:00 50.9 12.31 126.4 10.98 05/21/2009 12:01 50.3 12.35 104.9 10.97 05/21/2009 12:02 50.8 12.31 90.7 10.93 05/21/2009 12:03 49.6 12.25 86.3 10.96 05/21/2009 12:04 48.4 12.28 88.9 10.89 05/21/2009 12:05 48.5 12.26 92.6 10.9 05/21/2009 12:06 49.4 12.22 103 10.97 05/21/2009 12:07 48.7 12.29 109.5 10.91 05/21/2009 12:08 49.2 12.33 120.6 10.92 05/21/2009 12:09 48.2 12.27 129.5 10.91 05/21/2009 12:10 48 12.27 138.1 10.85 05/21/2009 12:11 49.1 12.26 132.4 10.91 05/21/2009 12:12 49.4 12.26 122.4 10.9 05/21/2009 12:13 49.4 12.28 104.4 10.95 05/21/2009 12:14 50.8 12.32 87.1 10.95 05/21/2009 12:15 50.1 12.33 89.5 10.91 05/21/2009 12:16 52.3 12.26 88.3 10.9 05/21/2009 12:17 52.6 12.18 92.9 10.82

Page 6 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 12:18 53 12.15 99.8 10.82 05/21/2009 12:19 53 12.18 112.2 10.85 05/21/2009 12:20 52.8 12.2 118.5 10.9 05/21/2009 12:21 52.5 12.26 123.8 10.92 05/21/2009 12:22 52.7 12.3 130.4 10.87 05/21/2009 12:23 52.8 12.26 130.4 10.89 05/21/2009 12:24 51.5 12.27 125.2 10.94 05/21/2009 12:25 50.8 12.27 103.5 11.01 05/21/2009 12:26 49.7 12.32 86.6 11 05/21/2009 12:27 48.3 12.32 83 10.92 05/21/2009 12:28 48.5 12.3 92.1 10.86 05/21/2009 12:29 49 12.3 100.1 10.84 05/21/2009 12:30 50.2 12.26 106.2 10.8 05/21/2009 12:31 51.3 12.2 109.6 10.85 05/21/2009 12:32 52.3 12.19 117.4 10.88 05/21/2009 12:33 52.4 12.18 124.6 10.94 05/21/2009 12:34 51.5 12.29 120.2 10.94 05/21/2009 12:35 52.1 12.31 110.5 10.95 05/21/2009 12:36 52.1 12.33 112.9 11.01 05/21/2009 12:37 50.7 12.33 114.6 10.95 05/21/2009 12:38 49.9 12.33 111.6 10.94 05/21/2009 12:39 49.8 12.33 99.7 10.97 05/21/2009 12:40 49.1 12.31 89 10.97 05/21/2009 12:41 49 12.3 94 10.84 05/21/2009 12:42 50.7 12.25 103.9 10.84 05/21/2009 12:43 51.2 12.21 114.3 10.87 05/21/2009 12:44 50.5 12.22 125.6 10.93 05/21/2009 12:45 50.8 12.29 132.4 10.93 05/21/2009 12:46 51.9 12.32 114.2 10.96 05/21/2009 12:47 51.6 12.31 107.6 10.95 05/21/2009 12:48 52.2 12.35 104.2 10.95 05/21/2009 12:49 52.2 12.33 97.7 10.83 05/21/2009 12:50 53 12.27 106.9 10.85 05/21/2009 12:51 52.8 12.2 116.3 10.88 05/21/2009 12:52 51.7 12.28 127.5 10.8 05/21/2009 12:53 52.8 12.27 134.3 10.77 05/21/2009 12:54 53 12.21 122.4 10.88 05/21/2009 12:55 50.9 12.26 106.2 11.02 05/21/2009 12:56 50 12.35 92.8 10.95 05/21/2009 12:57 50 12.32 86.9 10.91 05/21/2009 12:58 49.8 12.32 87.4 10.87 05/21/2009 12:59 49.6 12.31 90.3 10.97 05/21/2009 13:00 48.4 12.38 104 10.99

Page 7 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 13:01 48.9 12.36 110.4 10.85 05/21/2009 13:02 49.7 12.3 114.2 10.86 05/21/2009 13:03 49.3 12.23 115.5 10.89 05/21/2009 13:04 49.7 12.27 123.2 10.88 05/21/2009 13:05 50.7 12.27 128.4 10.87 05/21/2009 13:06 52.3 12.21 118 10.9 05/21/2009 13:07 51.6 12.26 95.2 10.99 05/21/2009 13:08 51.1 12.35 86.1 10.94 05/21/2009 13:09 50.4 12.4 86 10.9 05/21/2009 13:10 50.3 12.34 95.7 10.89 05/21/2009 13:11 50.6 12.31 105.6 10.82 05/21/2009 13:12 51 12.25 109.8 10.88 05/21/2009 13:13 51 12.22 108.1 10.79 05/21/2009 13:14 51 12.27 115.4 10.86 05/21/2009 13:15 50.8 12.24 125.6 10.82 05/21/2009 13:16 51.5 12.24 129.5 10.85 05/21/2009 13:17 51.1 12.25 135.5 10.91 05/21/2009 13:18 50 12.29 110.9 10.91 05/21/2009 13:19 49.5 12.32 88.6 10.91 05/21/2009 13:20 49.9 12.27 82.9 10.91 05/21/2009 13:21 49.9 12.3 82.6 10.91 05/21/2009 13:22 49.4 12.29 83.8 10.94 05/21/2009 13:23 49 12.33 90.6 10.93 05/21/2009 13:24 48.9 12.33 98.7 10.96 05/21/2009 13:25 47.5 12.35 110.2 10.95 05/21/2009 13:26 47.1 12.39 119.9 10.93 05/21/2009 13:27 47 12.37 125.8 10.95 05/21/2009 13:28 46.8 12.35 131.3 11.01 05/21/2009 13:29 46.6 12.4 126 11.03 05/21/2009 13:30 47.4 12.42 94.4 10.96 05/21/2009 13:31 48.8 12.35 78 10.92 05/21/2009 13:32 49.3 12.25 80.7 10.87 05/21/2009 13:33 49 12.2 81.2 10.88 05/21/2009 13:34 49 12.21 78.2 10.81 05/21/2009 13:35 49.7 12.2 89.9 10.85 05/21/2009 13:36 50.1 12.25 102.2 10.89 05/21/2009 13:37 50.4 12.29 97.9 10.87 05/21/2009 13:38 50.5 12.3 97.3 10.87 05/21/2009 13:39 50 12.31 102.4 10.95 05/21/2009 13:40 49.2 12.32 111.3 10.84 05/21/2009 13:41 49.5 12.3 132.6 10.9 05/21/2009 13:42 49.8 12.28 130.9 10.87 05/21/2009 13:43 51 12.31 99.9 10.9

Page 8 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 13:44 50.8 12.3 83.9 10.96 05/21/2009 13:45 49.8 12.34 85.5 11.01 05/21/2009 13:46 49.7 12.35 89.8 10.9 05/21/2009 13:47 48.9 12.36 103.6 10.94 05/21/2009 13:48 48.6 12.35 111.1 10.92 05/21/2009 13:49 47.8 12.36 114.9 10.93 05/21/2009 13:50 48.9 12.39 115 11.01 05/21/2009 13:51 49.7 12.39 112.2 10.86 05/21/2009 13:52 50.1 12.37 112.7 10.82 05/21/2009 13:53 51.2 12.25 119.1 10.82 05/21/2009 13:54 51.4 12.23 127 10.79 05/21/2009 13:55 52.1 12.23 136.1 10.82 05/21/2009 13:56 53.5 12.27 137.9 10.81 05/21/2009 13:57 53.8 12.29 117.1 10.88 05/21/2009 13:58 53.5 12.32 88.9 10.95 05/21/2009 13:59 53.2 12.38 88.4 10.91 05/21/2009 14:00 52.5 12.37 95.7 10.94 05/21/2009 14:01 50.9 12.35 99.3 10.96 05/21/2009 14:02 50.9 12.35 97.8 10.88 05/21/2009 14:03 51.2 12.29 96.9 10.86 05/21/2009 14:04 50.6 12.25 102.2 10.88 05/21/2009 14:05 50.5 12.28 109.9 10.85 05/21/2009 14:06 49.9 12.28 116.3 10.86 05/21/2009 14:07 50.4 12.23 123.8 10.85 05/21/2009 14:08 51.5 12.23 144.7 10.85 05/21/2009 14:09 50.9 12.27 122.5 10.96 05/21/2009 14:10 50.3 12.38 90.7 10.89 05/21/2009 14:11 50.6 12.31 81.4 10.92 05/21/2009 14:12 50.7 12.29 84.6 10.96 05/21/2009 14:13 49.6 12.3 84.2 10.82 05/21/2009 14:14 50 12.3 82.5 10.83 05/21/2009 14:15 51.8 12.22 92.5 10.74 05/21/2009 14:16 52.7 12.12 101.6 10.83 05/21/2009 14:17 51.6 12.17 112.4 10.85 05/21/2009 14:18 52.1 12.24 116.2 10.82 05/21/2009 14:19 53 12.24 128.4 10.85 05/21/2009 14:20 51.2 12.26 133.3 10.94 05/21/2009 14:21 49.8 12.37 137.5 10.98 05/21/2009 14:22 49.1 12.39 116.6 10.89 05/21/2009 14:23 48.6 12.36 95.4 10.95 05/21/2009 14:24 48.2 12.37 86.8 10.96 05/21/2009 14:25 47.8 12.35 84.8 10.93 05/21/2009 14:26 47.5 12.3 85.1 10.94

Page 9 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 14:27 46.7 12.32 91.2 10.9 05/21/2009 14:28 47.4 12.32 96.3 10.92 05/21/2009 14:29 47 12.3 104.7 10.89 05/21/2009 14:30 47.2 12.32 107.1 10.88 05/21/2009 14:31 47.7 12.28 110.9 10.95 05/21/2009 14:32 48.1 12.3 117.6 11.02 05/21/2009 14:33 47.9 12.36 119.6 10.93 05/21/2009 14:34 49.8 12.33 122.6 10.9 05/21/2009 14:35 49.6 12.34 123 10.85 05/21/2009 14:36 50 12.3 119.7 10.9 05/21/2009 14:37 50.6 12.3 110.6 10.95 05/21/2009 14:38 51 12.35 103.4 10.99 05/21/2009 14:39 50.7 12.37 103.7 10.87 05/21/2009 14:40 52.7 12.35 106.1 10.93 05/21/2009 14:41 51.3 12.31 108.3 10.98 05/21/2009 14:42 51.3 12.39 98.9 11 05/21/2009 14:43 51.5 12.4 80.8 10.95 05/21/2009 14:44 53 12.33 80.9 10.92 05/21/2009 14:45 53.1 12.28 85 10.96 05/21/2009 14:46 53 12.34 90 10.91 05/21/2009 14:47 52.7 12.3 96.2 10.94 05/21/2009 14:48 52.6 12.31 102.7 10.84 05/21/2009 14:49 52.9 12.27 109.3 10.86 05/21/2009 14:50 51.6 12.27 119.9 10.9 05/21/2009 14:51 50.9 12.31 129.9 10.98 05/21/2009 14:52 50.2 12.33 132.9 11.02 05/21/2009 14:53 49.8 12.42 115.6 11.01 05/21/2009 14:54 49.2 12.43 104.5 11.05 05/21/2009 14:55 49 12.43 106 11.03 05/21/2009 14:56 47.7 12.45 109.6 11.09 05/21/2009 14:57 47.4 12.48 111.7 10.95 05/21/2009 14:58 47.7 12.43 117 10.87 05/21/2009 14:59 49.9 12.3 122.3 10.8 05/21/2009 15:00 50.4 12.19 132.1 10.85 05/21/2009 15:01 51.7 12.2 126.4 10.83 05/21/2009 15:02 54 12.22 105.3 10.93 05/21/2009 15:03 54.2 12.26 89.7 10.94 05/21/2009 15:04 54.2 12.25 85.4 10.95 05/21/2009 15:05 53.4 12.31 76.3 10.97 05/21/2009 15:06 52.7 12.3 75.3 10.97 05/21/2009 15:07 51.3 12.38 76.5 10.95 05/21/2009 15:08 51.4 12.37 80.8 10.93 05/21/2009 15:09 50.2 12.33 84.9 10.94

Page 10 of 11NOx and SO2 DAHS Raw Data



### Date Time NOXL4 CO24 SO2_S3 CO2_S3 05/21/2009 15:10 48.8 12.4 92.8 10.94 05/21/2009 15:11 48.9 12.38 108.4 10.97 05/21/2009 15:12 47.7 12.35 115.2 11.11 05/21/2009 15:13 45.9 12.44 107.9 11.12 05/21/2009 15:14 44.8 12.49 107.2 11.07 05/21/2009 15:15 44.8 12.46 120.9 11.01 05/21/2009 15:17 46.1 12.37 88.7 10.93 05/21/2009 15:18 48.2 12.29 88.9 10.91 05/21/2009 15:19 49.8 12.25 91.3 10.97 05/21/2009 15:20 51.4 12.28 83.4 10.95 05/21/2009 15:21 52.6 12.3 89.4 10.94 05/21/2009 15:22 52.8 12.3 94.9 10.95 05/21/2009 15:23 52.8 12.31 97.5 10.98 05/21/2009 15:24 52.2 12.33 91.9 10.99 05/21/2009 15:25 52.8 12.31 102.6 10.92 05/21/2009 15:26 53.6 12.27 105.7 10.87 05/21/2009 15:27 53.9 12.22 109.3 10.88 05/21/2009 15:28 53.5 12.23 111.7 10.9 05/21/2009 15:29 53.4 12.21 123.2 10.86 05/21/2009 15:30 52.5 12.23 119.8 10.87 05/21/2009 15:31 51 12.29 117.6 10.94 05/21/2009 15:32 51.4 12.3 110.9 10.93 05/21/2009 15:33 51.2 12.27 81.2 10.94 05/21/2009 15:34 50.8 12.28 62.5 10.95 05/21/2009 15:35 51.1 12.26 69.5 10.91 05/21/2009 15:36 52.2 12.22 74.8 10.94 05/21/2009 15:37 51.9 12.22 80.4 10.94 05/21/2009 15:38 50.8 12.25 92.2 10.94 05/21/2009 15:39 50.9 12.29 103 10.96 05/21/2009 15:40 50.2 12.32 109.5 10.96 05/21/2009 15:41 49.4 12.37 114.4 10.97 05/21/2009 15:42 49.4 12.36 117.3 10.98 05/21/2009 15:43 48.9 12.35 111.2 10.98

Page 11 of 11

# APPENDIX D

OPERATIONS DATAPI Load Data

Plant Information Source: bbnd-1pisr v Start Time: 05/21/2009 8:00

End Time: 05/21/2009 15:43 T ime Interval: 1m

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe Run Avera g e: 441.6058077 21-May-09 08:00:00 441.3484497 21-May-09 08:01:00 442.1470337 21-May-09 08:02:00 442.2201538 21-May-09 08:03:00 442.6086731 21-May-09 08:04:00 443.5735474 21-May-09 08:05:00 443.316925 21-May-09 08:06:00 442.0003357 21-May-09 08:07:00 441.2180786 21-May-09 08:08:00 439.7739868 21-May-09 08:09:00 440.8313293 21-May-09 08:10:00 441.8311462 21-May-09 08:11:00 442.6912842 21-May-09 08:12:00 443.7612305 21-May-09 08:13:00 443.683136 21-May-09 08:14:00 443.9883118 21-May-09 08:15:00 442.9405212 21-May-09 08:16:00 442.3270569 21-May-09 08:17:00 441.2596436 21-May-09 08:18:00 441.0534363 21-May-09 08:19:00 442.0534363 21-May-09 08:20:00 442.8302917 21-May-09 08:21:00 441.8825378 21-May-09 08:22:00 441.0657043 21-May-09 08:23:00 439.5478821 21-May-09 08:24:00 439.4868164 21-May-09 08:25:00 440.0005493 21-May-09 08:26:00 441.8337097 21-May-09 08:27:00 442.4703674 21-May-09 08:28:00 442.6210632 21-May-09 08:29:00 442.8276062 21-May-09 08:30:00 442.3089905 21-May-09 08:31:00 442.5509033 21-May-09 08:32:00 441.7009583 21-May-09 08:33:00 441.4145813 21-May-09 08:34:00 441.6594238 21-May-09 08:35:00 443.0140686

Page 1 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 08:36:00 444.4216919 21-May-09 08:37:00 444.1888428 21-May-09 08:38:00 444.9801636 21-May-09 08:39:00 443.4008179 21-May-09 08:40:00 442.3776245 21-May-09 08:41:00 442.0639954 21-May-09 08:42:00 442.6013184 21-May-09 08:43:00 442.7523193 21-May-09 08:44:00 442.7675781 21-May-09 08:45:00 443.7899475 21-May-09 08:46:00 442.882019 21-May-09 08:47:00 442.95578 21-May-09 08:48:00 442.3097839 21-May-09 08:49:00 440.6479187 21-May-09 08:50:00 440.4558105 21-May-09 08:51:00 441.3942261 21-May-09 08:52:00 440.5916748 21-May-09 08:53:00 440.8940735 21-May-09 08:54:00 441.7871704 21-May-09 08:55:00 441.9177246 21-May-09 08:56:00 442.7553711 21-May-09 08:57:00 443.4120483 21-May-09 08:58:00 443.6861877 21-May-09 08:59:00 443.5646667 21-May-09 09:00:00 442.0809021 21-May-09 09:01:00 439.8606873 21-May-09 09:02:00 439.54245 21-May-09 09:03:00 439.6355896 21-May-09 09:04:00 440.1604309 21-May-09 09:05:00 441.737915 21-May-09 09:06:00 442.4550781 21-May-09 09:07:00 444.1456604 21-May-09 09:08:00 445.4481201 21-May-09 09:09:00 445.5050659 21-May-09 09:10:00 444.8925476 21-May-09 09:11:00 443.5678406 21-May-09 09:12:00 442.6455078 21-May-09 09:13:00 442.055481 21-May-09 09:14:00 442.1560059 21-May-09 09:15:00 440.2982788 21-May-09 09:16:00 441.3341675 21-May-09 09:17:00 442.6631165 21-May-09 09:18:00 441.9446106 21-May-09 09:19:00 442.0198669 21-May-09 09:20:00 443.6613159

Page 2 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 09:21:00 443.7605896 21-May-09 09:22:00 443.0891113 21-May-09 09:23:00 442.6401978 21-May-09 09:24:00 442.8692932 21-May-09 09:25:00 443.5458069 21-May-09 09:26:00 443.0218811 21-May-09 09:27:00 443.2827759 21-May-09 09:28:00 441.3904114 21-May-09 09:29:00 441.0585327 21-May-09 09:30:00 441.72995 21-May-09 09:31:00 442.1555786 21-May-09 09:32:00 442.4585571 21-May-09 09:33:00 441.9461975 21-May-09 09:34:00 441.8492432 21-May-09 09:35:00 441.743103 21-May-09 09:36:00 442.4894409 21-May-09 09:37:00 443.2001953 21-May-09 09:38:00 442.0503845 21-May-09 09:39:00 442.4883118 21-May-09 09:40:00 442.7108154 21-May-09 09:41:00 442.6940918 21-May-09 09:42:00 442.7326965 21-May-09 09:43:00 441.3128357 21-May-09 09:44:00 440.8492737 21-May-09 09:45:00 440.5092163 21-May-09 09:46:00 440.8470764 21-May-09 09:47:00 441.8596497 21-May-09 09:48:00 443.6419373 21-May-09 09:49:00 443.3471375 21-May-09 09:50:00 444.3762207 21-May-09 09:51:00 443.8509521 21-May-09 09:52:00 443.554718 21-May-09 09:53:00 443.0422363 21-May-09 09:54:00 441.4807129 21-May-09 09:55:00 441.2987671 21-May-09 09:56:00 441.440033 21-May-09 09:57:00 442.0067749 21-May-09 09:58:00 442.5539551 21-May-09 09:59:00 442.1159973 21-May-09 10:00:00 441.8138428 21-May-09 10:01:00 442.8445129 21-May-09 10:02:00 442.9263916 21-May-09 10:03:00 442.9659424 21-May-09 10:04:00 442.7772827 21-May-09 10:05:00 442.3642883

Page 3 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 10:06:00 440.8868713 21-May-09 10:07:00 440.0628662 21-May-09 10:08:00 440.4731445 21-May-09 10:09:00 440.8102112 21-May-09 10:10:00 442.1495667 21-May-09 10:11:00 442.3555603 21-May-09 10:12:00 442.8424072 21-May-09 10:13:00 443.4101563 21-May-09 10:14:00 442.9845886 21-May-09 10:15:00 442.9186401 21-May-09 10:16:00 443.5179749 21-May-09 10:17:00 441.6231384 21-May-09 10:18:00 440.8895264 21-May-09 10:19:00 440.890686 21-May-09 10:20:00 440.9755554 21-May-09 10:21:00 441.6052246 21-May-09 10:22:00 441.644928 21-May-09 10:23:00 442.2487488 21-May-09 10:24:00 442.6262207 21-May-09 10:25:00 443.5635986 21-May-09 10:26:00 443.7840881 21-May-09 10:27:00 443.6678772 21-May-09 10:28:00 442.6725159 21-May-09 10:29:00 441.4628906 21-May-09 10:30:00 441.5689392 21-May-09 10:31:00 441.4485779 21-May-09 10:32:00 442.2986755 21-May-09 10:33:00 442.0184021 21-May-09 10:34:00 442.920166 21-May-09 10:35:00 443.0847778 21-May-09 10:36:00 443.8547974 21-May-09 10:37:00 442.23349 21-May-09 10:38:00 441.3763733 21-May-09 10:39:00 441.2053833 21-May-09 10:40:00 440.3790283 21-May-09 10:41:00 441.491333 21-May-09 10:42:00 442.8070679 21-May-09 10:43:00 443.7145081 21-May-09 10:44:00 443.8128052 21-May-09 10:45:00 443.9549561 21-May-09 10:46:00 442.0995483 21-May-09 10:47:00 441.0323792 21-May-09 10:48:00 441.4909058 21-May-09 10:49:00 441.6219788 21-May-09 10:50:00 441.8672791

Page 4 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 10:51:00 441.541748 21-May-09 10:52:00 442.0046082 21-May-09 10:53:00 443.3245239 21-May-09 10:54:00 442.8285828 21-May-09 10:55:00 442.848938 21-May-09 10:56:00 443.6434631 21-May-09 10:57:00 443.5458069 21-May-09 10:58:00 441.2781372 21-May-09 10:59:00 441.4552917 21-May-09 11:00:00 440.3585205 21-May-09 11:01:00 440.3786621 21-May-09 11:02:00 440.6682129 21-May-09 11:03:00 440.2955627 21-May-09 11:04:00 442.0007935 21-May-09 11:05:00 444.0406189 21-May-09 11:06:00 444.1815796 21-May-09 11:07:00 443.3703003 21-May-09 11:08:00 441.9579468 21-May-09 11:09:00 441.4848938 21-May-09 11:10:00 442.4943848 21-May-09 11:11:00 442.4558411 21-May-09 11:12:00 442.7557373 21-May-09 11:13:00 442.4866333 21-May-09 11:14:00 441.6841736 21-May-09 11:15:00 442.3566589 21-May-09 11:16:00 442.5960388 21-May-09 11:17:00 442.8388672 21-May-09 11:18:00 442.1419373 21-May-09 11:19:00 441.6187134 21-May-09 11:20:00 441.383728 21-May-09 11:21:00 441.7659912 21-May-09 11:22:00 441.0127563 21-May-09 11:23:00 441.9824829 21-May-09 11:24:00 441.9256897 21-May-09 11:25:00 443.1329041 21-May-09 11:26:00 444.1804504 21-May-09 11:27:00 444.0575562 21-May-09 11:28:00 442.920166 21-May-09 11:29:00 441.4247437 21-May-09 11:30:00 440.5825806 21-May-09 11:31:00 440.5834351 21-May-09 11:32:00 441.1500854 21-May-09 11:33:00 441.8723755 21-May-09 11:34:00 442.0452881 21-May-09 11:35:00 441.3244934

Page 5 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 11:36:00 441.8672791 21-May-09 11:37:00 442.8096313 21-May-09 11:38:00 443.1795654 21-May-09 11:39:00 444.1307068 21-May-09 11:40:00 442.5162354 21-May-09 11:41:00 442.348877 21-May-09 11:42:00 443.8052063 21-May-09 11:43:00 442.5430908 21-May-09 11:44:00 441.6412659 21-May-09 11:45:00 441.8452454 21-May-09 11:46:00 440.1964111 21-May-09 11:47:00 439.8051147 21-May-09 11:48:00 439.8500061 21-May-09 11:49:00 439.9970093 21-May-09 11:50:00 440.6792297 21-May-09 11:51:00 441.8014832 21-May-09 11:52:00 441.0737915 21-May-09 11:53:00 441.4661865 21-May-09 11:54:00 441.8053589 21-May-09 11:55:00 442.6577148 21-May-09 11:56:00 442.9546204 21-May-09 11:57:00 442.6874695 21-May-09 11:58:00 442.8312988 21-May-09 11:59:00 443.0574951 21-May-09 12:00:00 442.4776611 21-May-09 12:01:00 442.1560364 21-May-09 12:02:00 441.4425049 21-May-09 12:03:00 441.2436829 21-May-09 12:04:00 441.6459961 21-May-09 12:05:00 440.5532837 21-May-09 12:06:00 440.1013184 21-May-09 12:07:00 441.6261902 21-May-09 12:08:00 441.3230286 21-May-09 12:09:00 441.6622009 21-May-09 12:10:00 442.5943298 21-May-09 12:11:00 443.493927 21-May-09 12:12:00 441.4094849 21-May-09 12:13:00 442.9037476 21-May-09 12:14:00 442.5661621 21-May-09 12:15:00 442.2029724 21-May-09 12:16:00 441.5203552 21-May-09 12:17:00 442.0046082 21-May-09 12:18:00 443.3397827 21-May-09 12:19:00 444.6444702 21-May-09 12:20:00 443.7110901

Page 6 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 12:21:00 442.8743896 21-May-09 12:22:00 443.5714722 21-May-09 12:23:00 442.5059814 21-May-09 12:24:00 441.1152039 21-May-09 12:25:00 439.4868164 21-May-09 12:26:00 438.4007568 21-May-09 12:27:00 439.4552917 21-May-09 12:28:00 439.801178 21-May-09 12:29:00 439.5455017 21-May-09 12:30:00 440.0337524 21-May-09 12:31:00 442.2090149 21-May-09 12:32:00 442.7675781 21-May-09 12:33:00 442.4559326 21-May-09 12:34:00 441.1299744 21-May-09 12:35:00 439.6394348 21-May-09 12:36:00 438.5906067 21-May-09 12:37:00 439.3756104 21-May-09 12:38:00 439.6484985 21-May-09 12:39:00 440.3366699 21-May-09 12:40:00 441.8418579 21-May-09 12:41:00 441.8379822 21-May-09 12:42:00 441.9417725 21-May-09 12:43:00 441.665863 21-May-09 12:44:00 442.6363525 21-May-09 12:45:00 442.8591309 21-May-09 12:46:00 440.8296509 21-May-09 12:47:00 440.2816772 21-May-09 12:48:00 440.6835327 21-May-09 12:49:00 441.1233826 21-May-09 12:50:00 442.0503845 21-May-09 12:51:00 441.8596191 21-May-09 12:52:00 441.8123474 21-May-09 12:53:00 441.9958801 21-May-09 12:54:00 441.4842529 21-May-09 12:55:00 441.3331909 21-May-09 12:56:00 440.1953735 21-May-09 12:57:00 439.0104675 21-May-09 12:58:00 437.956543 21-May-09 12:59:00 439.1551208 21-May-09 13:00:00 441.0758667 21-May-09 13:01:00 440.5865173 21-May-09 13:02:00 440.6141357 21-May-09 13:03:00 440.0558167 21-May-09 13:04:00 440.4786682 21-May-09 13:05:00 440.788208

Page 7 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 13:06:00 439.4455566 21-May-09 13:07:00 437.8917847 21-May-09 13:08:00 436.1297913 21-May-09 13:09:00 434.9243164 21-May-09 13:10:00 437.1882935 21-May-09 13:11:00 437.6499939 21-May-09 13:12:00 437.9573059 21-May-09 13:13:00 438.2874451 21-May-09 13:14:00 439.5478821 21-May-09 13:15:00 440.0276794 21-May-09 13:16:00 439.8750916 21-May-09 13:17:00 440.9974976 21-May-09 13:18:00 440.9822388 21-May-09 13:19:00 439.735199 21-May-09 13:20:00 438.7879333 21-May-09 13:21:00 438.6255798 21-May-09 13:22:00 438.9146118 21-May-09 13:23:00 438.2221069 21-May-09 13:24:00 439.18927 21-May-09 13:25:00 439.4776611 21-May-09 13:26:00 441.397644 21-May-09 13:27:00 441.7968445 21-May-09 13:28:00 441.9995117 21-May-09 13:29:00 441.7561035 21-May-09 13:30:00 440.7304688 21-May-09 13:31:00 441.1439819 21-May-09 13:32:00 440.5804138 21-May-09 13:33:00 438.3932495 21-May-09 13:34:00 437.7540588 21-May-09 13:35:00 440.0309143 21-May-09 13:36:00 441.5580444 21-May-09 13:37:00 442.4465942 21-May-09 13:38:00 442.5539246 21-May-09 13:39:00 441.5867615 21-May-09 13:40:00 441.0236511 21-May-09 13:41:00 439.9319458 21-May-09 13:42:00 438.9527588 21-May-09 13:43:00 439.3460999 21-May-09 13:44:00 439.4372559 21-May-09 13:45:00 440.9110413 21-May-09 13:46:00 440.5397339 21-May-09 13:47:00 440.7075806 21-May-09 13:48:00 441.2967224 21-May-09 13:49:00 441.3026733 21-May-09 13:50:00 441.6853943

Page 8 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 13:51:00 441.75354 21-May-09 13:52:00 441.855835 21-May-09 13:53:00 441.7658386 21-May-09 13:54:00 440.3951416 21-May-09 13:55:00 440.5236511 21-May-09 13:56:00 440.8847351 21-May-09 13:57:00 441.0137634 21-May-09 13:58:00 441.7095947 21-May-09 13:59:00 443.4618835 21-May-09 14:00:00 443.3204346 21-May-09 14:01:00 442.2060242 21-May-09 14:02:00 440.5168152 21-May-09 14:03:00 439.2833557 21-May-09 14:04:00 439.4427795 21-May-09 14:05:00 440.1124573 21-May-09 14:06:00 439.5733032 21-May-09 14:07:00 439.904541 21-May-09 14:08:00 441.7146912 21-May-09 14:09:00 441.6994324 21-May-09 14:10:00 441.3918152 21-May-09 14:11:00 439.7102966 21-May-09 14:12:00 440.1904907 21-May-09 14:13:00 440.2093811 21-May-09 14:14:00 440.4176636 21-May-09 14:15:00 441.2111206 21-May-09 14:16:00 442.0836792 21-May-09 14:17:00 441.5401306 21-May-09 14:18:00 441.5647888 21-May-09 14:19:00 441.5987244 21-May-09 14:20:00 442.0773926 21-May-09 14:21:00 441.0266418 21-May-09 14:22:00 440.1086426 21-May-09 14:23:00 439.9801941 21-May-09 14:24:00 437.9107971 21-May-09 14:25:00 438.8789063 21-May-09 14:26:00 439.4508972 21-May-09 14:27:00 440.104126 21-May-09 14:28:00 440.9269409 21-May-09 14:29:00 441.2168579 21-May-09 14:30:00 440.3464355 21-May-09 14:31:00 439.517334 21-May-09 14:32:00 438.4072266 21-May-09 14:33:00 439.2175293 21-May-09 14:34:00 439.2503052 21-May-09 14:35:00 439.5393677 21-May-09 14:36:00 441.2111206 21-May-09 14:37:00 441.734314 21-May-09 14:38:00 441.8936462

Page 9 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 14:39:00 441.6917725 21-May-09 14:40:00 441.6646729 21-May-09 14:41:00 441.0608826 21-May-09 14:42:00 441.6078491 21-May-09 14:43:00 440.9090881 21-May-09 14:44:00 440.7413025 21-May-09 14:45:00 438.9947205 21-May-09 14:46:00 439.5106506 21-May-09 14:47:00 439.1594238 21-May-09 14:48:00 439.980835 21-May-09 14:49:00 441.0196838 21-May-09 14:50:00 443.1276855 21-May-09 14:51:00 441.8062439 21-May-09 14:52:00 442.2168274 21-May-09 14:53:00 441.7029419 21-May-09 14:54:00 440.8946533 21-May-09 14:55:00 440.4786682 21-May-09 14:56:00 440.5282593 21-May-09 14:57:00 440.2399902 21-May-09 14:58:00 440.2026367 21-May-09 14:59:00 440.4407959 21-May-09 15:00:00 441.0343018 21-May-09 15:01:00 441.9232178 21-May-09 15:02:00 441.8492432 21-May-09 15:03:00 441.8999634 21-May-09 15:04:00 441.085907 21-May-09 15:05:00 440.4695129 21-May-09 15:06:00 441.0432739 21-May-09 15:07:00 438.8917236 21-May-09 15:08:00 439.7462463 21-May-09 15:09:00 439.602356 21-May-09 15:10:00 440.4176331 21-May-09 15:11:00 441.4858093 21-May-09 15:12:00 442.8896484 21-May-09 15:13:00 443.3733521 21-May-09 15:14:00 442.609436 21-May-09 15:15:00 441.4766235 21-May-09 15:16:00 441.20401 21-May-09 15:17:00 440.7838745 21-May-09 15:18:00 440.8082886 21-May-09 15:19:00 440.8230591 21-May-09 15:20:00 440.2965698 21-May-09 15:21:00 440.6465454 21-May-09 15:22:00 442.0402222 21-May-09 15:23:00 443.5471191 21-May-09 15:24:00 444.196228 21-May-09 15:25:00 442.7691956 21-May-09 15:26:00 441.4781494

Page 10 of 11PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 21-May-09 15:27:00 440.4164734 21-May-09 15:28:00 441.0222778 21-May-09 15:29:00 440.9517212 21-May-09 15:30:00 441.7923584 21-May-09 15:31:00 441.0432739 21-May-09 15:32:00 441.5010376 21-May-09 15:33:00 442.2655334 21-May-09 15:34:00 442.3968201 21-May-09 15:35:00 441.5315552 21-May-09 15:36:00 440.5397034 21-May-09 15:37:00 439.9064636 21-May-09 15:38:00 440.0209045 21-May-09 15:39:00 440.1382751 21-May-09 15:40:00 439.7333984 21-May-09 15:41:00 440.1399231 21-May-09 15:42:00 440.7398071 21-May-09 15:43:00 441.0982056

Page 11 of 11

# APPENDIX E

FUEL INFORMATION

# E-1

BUNKERING INFORMATIONTime Fuel Tons Blended Percent Blended (%) Total Fuel Bunkered (tons)

05/20/2009 11:40 Petcoke 233.7 15.85
05/20/2009 11:40 Standard 371.3 25.19
05/20/2009 11:40 Standard L 869.0 58.96

05/20/2009 17:02 Petcoke 148.1 15.19
05/20/2009 17:02 Standard 279.1 28.62
05/20/2009 17:02 Standard L 547.9 56.19

05/20/2009 21:15 Petcoke 132.5 15.21
05/20/2009 21:15 Standard 255.8 29.37
05/20/2009 21:15 Standard L 482.8 55.42

05/21/2009 1:01 Petcoke 114.5 15.09
05/21/2009 1:01 Standard 213.9 28.18
05/21/2009 1:01 Standard L 430.6 56.73

05/21/2009 4:53 Petcoke 85.9 15.34
05/21/2009 4:53 Standard 156.2 27.89
05/21/2009 4:53 Standard L 318.0 56.78

05/21/2009 11:35 Petcoke 217.7 15.51
05/21/2009 11:35 Standard 385.5 27.46
05/21/2009 11:35 Standard L 800.8 57.04

05/21/2009 17:24 Petcoke 153.8 14.83
05/21/2009 17:24 Standard 313.1 30.19
05/21/2009 17:24 Standard L 570.1 54.98

05/21/2009 21:16 Petcoke 84.8 15.11
05/21/2009 21:16 Standard 167.0 29.76
05/21/2009 21:16 Standard L 309.3 55.12

1171.0 Total Petcoke 456.3 2141.9 Total Standard 865.6 4328.5 Total Standard L 1680.2 7641.4 Total Fuel 3002.1

15.3 Total % Petcoke Blended 15.2 28.0 Total % Standard Blended 28.8 56.6 Total % Standard L Blended 56.0 Total % Standard L Blended 

### BB4 PM Stack Test Bunkered Fuels 5/21/09

1474.0

975.1

871.1

759.0

560.1

Total % Standard Blended Total Petcoke Total Standard

Total Fuel

Total % Petcoke Blended Total Standard L Total Bunkered Before Test and During Test Total Bunkered During Test 1404.0

1037.0

561.1

# E-2

FUEL ANALYSIS

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For: 

## Laboratory ID: AB01114

Date and Time Collected: Sampled By: 

### Sample Information

F.WADE Description: 

### Location Code: 06/29/09 Report Date:

Big Bend 4 Compliance 

### TE_BB_4_COMP_COAL

Project Account Code: 06/01/09 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 05/21/09 3:00:00 PM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 5.84 06/10/09 9:36:00 AM

Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 9.55 06/10/09 9:36:00 AM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 8.64 06/10/09 2:17:00 PM

Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 10.14 06/10/09 2:14:00 PM

BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 12096 06/04/09 9:11:00 AM

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 10946 06/10/09 2:17:00 PM
BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 12846 06/10/09 2:10:00 PM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14296 06/10/09 2:14:00 PM

Carbon, as Received % ASTM D-5373 PENDING

Carbon, Dry Basis % ASTM D-5373 PENDING

Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.09 06/18/09 2:57:00 PM
Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.1 06/18/09 2:57:00 PM

HHV (BTU/Lb) Calculated (Mason) BTU/Lb Mason Calc. PENDING

Hydrogen, as Received % ASTM D-5373 PENDING

Hydrogen, Dry Basis % ASTM D-5373 PENDING

Nitrogen, as Received % ASTM D-5373 PENDING

Nitrogen, Dry Basis % ASTM D-5373 PENDING

NOx emission rate, lb/mmB tu lb/mmBtu EPA RM-7E KAMCR 0.09 06/23/09 12:56:00 PM

NOx emission rate, lbs/hr lbs/hr EPA RM-7E KAMCR 372 06/23/09 12:56:00 PM

Oxygen, as Received % ASTM D-5373 PENDING

Oxygen, Dry Basis % Calculated PENDING

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 E PA Method 5B/1 7 KAMCR 16.9 06/23/09 12:56:00 PM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 E PA Method 5B/1 7 KAMCR 14.2 06/23/09 12:56:00 PM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 E PA Method 5B/1 7 KAMCR 10.05 06/23/09 12:56:00 PM
Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 E PA Method 5B/1 7 KAMCR 6.55 06/23/09 12:56:00 PM
Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 E PA Method 5B/1 7 KAMCR 4.45 06/23/09 12:56:00 PM
Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 E PA Method 5B/1 7 KAMCR 2.95 06/23/09 12:56:00 PM

Particulate Wt., Total Sample, Run 1 mg 0.0001 E PA Method 5B/1 7 KAMCR 23.45 06/23/09 12:56:00 PM

Report Number: Page 1 of 2 "General Report" AB01114-062909-10

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit Particulate Wt., Total Sample, Run 2 mg 0.0001 E PA Method 5B/1 7 KAMCR 18.65 06/23/09 12:56:00 PM

Particulate Wt., Total Sample, Run 3 mg 0.0001 E PA Method 5B/1 7 KAMCR 13.00 06/23/09 12:56:00 PM

PM, lb/mmBtu lb/mmBtu EPA RM-5/17 KAMCR 0.01 06/23/09 12:56:00 PM

Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated KAPXJ 4.67 06/10/09 12:11:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KAMCR 1251 06/23/09 12:56:00 PM

SO2 emission rate, lbs/mmBtu lbs/mmBtu EPA - RM6C KAMCR 0.30 06/23/09 12:56:00 PM

Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 2.97 06/09/09 3:14:00 PM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 2.68 06/10/09 2:17:00 PM

Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.15 06/10/09 2:10:00 PM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 14.79 06/10/09 2:16:00 PM


### Comments

Designee for Peggy Penner, Manager, Laboratory Services All results calculated on a wet to we t basis, unless otherwise indicated.
Should there be any questions regarding this report, please contact:

(813) 630-7490 Ellen Demers,

Report Number: Page 2 of 2 "General Report" AB01114-062909-10

# APPENDIX F

TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL, HEALTH, & SAFETY AIR SERVICES GROUP – TEST TEAM Scott Given Environmental Technician – Test Team Lead Ryan Newell Environmental Technician

RM-320 FTIR Gary Barber Environmental Technician

PROCESS DATA Adam Ballans Associate En gineer – Big Bend Station R.A. McDarby Senior Environmental Technician

FUEL ANALYSIS Patrice Jackson Envi ronmental Technician Ellen Demers Environmental Technician

PARTICULATE LABORATORY Sam Soth Environmental Technician

SUPPORTING DATA COLLECTION AND ANALYSIS R.A. McDarby Senior Environmental Technician

PROJECT QUALITY OBJECTIVES & REPORTING R.A. McDarby Senior Environmental Technician Robert J. Kricks, Ph.D. Principal – RJK Consulting (Spectra & Method)

TEST COORDINATION Adam Ballans Associate En gineer – Big Bend Station David A. Smith Coordinator – Air Services Group