EMISSIONS TEST REPORT 

BIG BEND STATION 

FACILITY ID NUMBER: 0570039 

EMISSION UNIT ID NO: -004 

PARTICULATE MATTER, AMMONIA SLIP,SULFUR DIOXIDE, 

NITROGEN OXIDE, AND 

VISIBLE EMISSIONS EVALUATION 

May 21, 2009 

Prepared For: 

Tampa Electric Company 

Big Bend Station 

P.O. Box 111 

Tampa, Florida 33601-0111 

Prepared By: 

Tampa Electric Company 

Environmental, Health & Safety 

Air Services Group 

Air Services Group 

5010 Causeway Boulevard 

Tampa, Florida 33619- 6130 
REPORT CERTIFICATION 

 The sampling and subsequent data entry/reduction detailed in this report 

was conducted at my direction, and I hereby certify that this test report is 

authentic and accurate to the best of my knowledge. 

Signature:__________________________ 

Scott E. Given 

Environmental Technician 

Test Team Lead 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the test performance, associated quality assurance 

activities, the resultant calculations, and the contents of this report, and certify 

that all project quality objectives have been met. This report is approved for 

submittal. 

Signature:__________________________ 

Raymond A. McDarby, Jr. 

Senior Environmental Technician 

Quality Assurance/Quality Control Specialist 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the testing details and results submitted in this report, 

and hereby certify that this test report is authentic and accurate to the best of 

my knowledge. 

Signature:__________________________ 

David A. Smith, QSTI 

Coordinator – Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 
TABLE OF CONTENTS

SECTION PAGE

1.0 INTRODUCTION 1 

2.0 DISCUSSION OF RESULTS / EXECUTIVE SUMMARY 2 

3.0 SOURCE DESCRIPTION / TEST PROCEDURES 4 

4.0 TEST RESULTS 

 PARTICULATE MATTER TEST SUMMARY 7 

 AMMONIA SLIP TEST SUMMARY 8 

 SULFUR DIOXIDE AND NITROGEN OXIDES DATA SUMMARY 9 

 VISIBLE EMISSIONS DATA FROM OPACITY MONITOR 10 

 HEAT INPUT CALCULATIONS 11 

5.0 FIGURES 

PARTICULATE SAMPLING TRAVERSE POINTS 13 

APPENDICES

A PARTICULATE MATTER TEST DATA 

A-1 RUN CALCULATIONS 

A-2 LABORATORY ANALYTICAL DATA 

A-3 CALIBRATION DATA 

A-4 FIELD DATA SHEETS 

A-5 CHAIN OF CUSTODY 

B AMMONIA SLIP TEST DATA 

B-1 RUN DATA 

 B-2 RAW DATA 

 B-3 METHOD MAP 

 B-4 SUMMARIZED QA DATA 

 B-5 LEAK RATE DATA 

 B-6 ETHYLENE CTS DATA 

 B-7 SPIKE DATA 

 B-8 SNR TEST DATA 

 B-9 ANNUAL CELL PATH CHECK DATA 

 B-10 CYLINDER GAS CERTIFICATES OF ANALYSIS 

C CONTINUOUS EMISSIONS MONITORING DATA 

D OPERATIONS DATA 
E FUEL INFORMATION 

E-1 BUNKERING INFORMATION 

E-2 FUEL ANALYSIS 

F TEST PARTICIPANTS 
1

1.0 INTRODUCTION

On May 21, 2009, Tampa Electric Company’s Environmental, Health, & Safety, 

Air Services Group, performed particulate matter (PM) and ammonia slip tests at 

the Big Bend Station (Facility ID No.: 0570039), Boiler No. 4, (E.U. ID No.: -004). 

Particulate Matter (PM) testing was conducted according to procedures 

stipulated by the Florida Department of Environmental Protection (FDEP) for 

fossil fuel steam generators, and requirements in Title V Permit # 0570039-028-

AV, Compliance determination procedures and methods, §B.26 through §B.30. 

Ammonia Slip testing was conducted in accordance with FDEP Air Construction 

(AC) Permit 0570039-020-AC (as modified in permit 0570039-026-AC), 

COMPLIANCE DETERMINATION, §A.19. 
2

2.0 DISCUSSION OF RESULTS

Executive Summary 

Tampa Electric Company 

Big Bend Station 

Dry-Bottom Tangentially Fired Utility Boiler 

Emission Unit ID -004 

Coal/Petroleum Coke/Polk Residual 

Compliance Parameter Test Result FDEP Permit Limit 

May 21, 2009

Particulate, lb/mmBtu 0.01 0.01 

Particulate, lbs/hr 31.5 43.3 

Ammonia, ppmv 1 10 

SO2, lb/mmBtu 0.30 0.821

SO2, lbs/hr 1251 35511

NOX, lb/mmBtu 0.09 0.102

NOX, lbs/hr 372 4332,5

VE, % opacity 5 203

Heat Input, mmBtu/hr 4240 43304

Unit Load (% of permit) 98% 90 – 100% 

1

 Based on a 30-day rolling average. 

2

 Based on a heat input weighted 30-day rolling average. 

3

 6-minute average. 

4 Permitting Note: The heat input has been placed in the permit to identify the capacity of the 

unit for purposes of confirming that emissions testing is conducted within the 90 – 100% of the 

unit’s rated capacity (or to limit future operation to 110% of the test load), to establish 

appropriate emission limits and to aid in determining future rule applicability. 

5 This limit is based on a heat input of 4330 mmBtu/hr. 

The average particulate matter emissions were derived by performing three, 2-

hour United States Environmental Protection Agency (USEPA) reference method 

5B test runs. The average emission rates were calculated as 0.01 lb/mmBtu, 

and 31.5 lbs/hr. The FDEP Title V permitted emission rates are 0.01 lb/mmBtu 

and 43.3 lbs/hr (§ B.5.i (a) & (b)). 

The average ammonia slip concentration was derived from three 1-hour USEPA 

reference method 320 test runs. The average concentration was calculated as 1 

ppmv. The FDEP AC permitted concentration is 10 ppmv (§ A.17.). 
3

During the particulate matter test the Sulfur Dioxide (SO2) emission rates were 

determined to be 0.30 lb/mmBtu and 1251 lbs/hr. The FDEP Title V permitted 

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling 

average (§ B.7 (a) & (b)). 

During the particulate matter test the nitrogen dioxide (NO2) emission rates (as 

total oxides) were determined to be 0.09 lb/mmBtu and 372 lbs/hr. The FDEP 

AC permitted emission rate is 0.10 lb/mmBtu and 433 lbs/hr, based on a 30-day 

rolling average (§A.16). 

Visible emissions were determined to be 5%, maximum 6-minute average, during 

a one-hour test conducted under soot blowing conditions. The FDEP Title V 

permitted emission rate is 20 percent opacity (6-minute average) except for one 

6-minute period per hour of not more than 27 (twenty-seven) percent (§B.6). 

During the particulate matter test performed on May 21, 2009 Boiler No. 4 was 

operated at an average heat input rate of 4240 mmBtu/hr and an average load of 

442 megawatts. The average quantity of fuel burned was 193.7 tons per hour. 
4

3.0 SOURCE DESCRIPTION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM 

coordinates East 361.9 North 3075.0. Boiler No. 4 source sampling location 

consists of a circular stack 28.83 feet in diameter with four sample ports located 

90 degrees apart on the stack circumference. Upstream and downstream gas 

flow disturbances were determined to be 8.51 and 2.99 stack diameters from the 

test ports, respectively. Using these criteria, a total of 24 sampling points were 

chosen for particulate sampling for each stack, as stipulated in the U.S. EPA 

Method 1 test procedure. A diagram of the stack sampling location is included in 

Figure 1 along with other pertinent information on the test site. 

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash 

emissions, a selective catalytic reduction (SCR) system for control of nitrogen 

oxides emissions, an ammonia injection system to control sulfur trioxide 

formation, and a flue gas desulfurization (FGD) system for control of sulfur 

dioxide emissions. 

On May 21, 2009, the boiler was fired with a solid fuel matrix comprised of 85% 

coal and 15% petroleum coke. 

Particulate sampling was performed according to USEPA Method 5-B 

"Determination of Nonsulfuric Acid Particulate Matter from Stationary Sources". 

Particulate matter was collected on a high purity, glass micro fiber filter 

measuring 8.26 cm in diameter. 

Ammonia slip testing was performed using USEPA Method 320 “Measurement of 

Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform 

Infrared (FTIR) Spectroscopy”. Spectra and test performance was reviewed by 

RJK Consulting for appropriateness, completeness, and quality control. 
5

Sulfur Dioxide and Nitrogen Oxide data was supplied by the installed Continuous 

Emissions Monitoring systems (CEMs), Data Acquisition and Handling System 

(DAHS) as one minute averages for the duration of the particulate matter test. 

Visible emissions compliance was assessed using the installed Continuous 

Opacity Monitor (COM) as recorded by the DAHS as one minute averages during 

the soot blowing portion of the particulate matter test. 
6

4.0 TEST RESULTS
BIG BEND STATION

PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2* Run 3 Test Summary

Vm(std), scf 71.982 68.059 69.512 69.851

Bws, ratio 0.156 0.161 0.159 0.159

O2, % volume 5555.0

Md, lb/lb - mole 30.44 30.44 30.44 30.44

Ms, lb/lb - mole 28.49 28.44 28.46 28.46

Qs, acf/min 2.14E+06 2.04E+06 2.08E+06 2.09E+06

Qs(std), dscf/min 1.60E+06 1.51E+06 1.55E+06 1.55E+06

I, % 100.6 100.7 100.6 100.6

C, lbs/dscf 7.18E-07 6.04E-07 4.12E-07 5.78E-07

Er, lb/mmBtu 0.01 0.01 0.01 0.01

Em, lbs/hr 39.1 32.9 22.5 31.5

Emission rate (Er), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O2))

Mass emissions (Em), lbs/hr, calculated as: Er, lb/mmBtu x Heat Input

*

Run 2 was a soot blowing run

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

May 21, 2009

7
BIG BEND STATION

AMMONIA SLIP TEST DATA

Calculated Data

Run NH3 Water SF6 Cell Temp Pressure

Number Start Stop ppmvw % ppm °C ATM

1 10:59 11:59 0.796 15.56 -0.02 150 0.9560

2 13:03 14:04 0.739 16.31 -0.02 150 0.9623

3 14:06 15:07 0.623 15.95 -0.02 150 0.9610

Average:

NH3

1

, ppmvw is corrected for FTIR bias factor from annual QA/QC checks.

This value is: 1.0602

ppmvw

0.84

0.78

0.66

1

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

May 21, 2009

NH3

1

FTIR Recorded Data

Run Time

40 CFR 63 Reference Method 320

Summarized Data

8
BIG BEND STATION

SULFUR DIOXIDE and NITROGEN OXIDES DATA

Outlet SO2 Data

Average SO2 Concentration, ppmvw: 107.9

Average CO2 Concentration, % volume wet: 10.93

Calculated SO2 Emission Rate, lb/mmBtu: 0.30

Calculated SO2 Emission Rate, lbs/hr: 1251

Unit #4 NOx Data

Average NOx concentration, ppmvw: 49.69

Average CO2 Concentration, % volume wet: 12.18

Calculated NOx Emission Rate, lb/mmBtu: 0.09

Calculated NOx Emission Rate, lbs/hr: 372

SO2 Emission Rate, lb(s)/mmBtu is calculated as:

SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw)

NOx Emission Rate, lb/mmBtu is calculated as:

NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw)

Emission Rates in lbs/hr are calculated as:

Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr

Average Concentration values were taken from 8:00 to 15:43 EST.

Heat Input Calculated for this test was 4240 mmBtu/hr

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

May 21, 2009

9
BIG BEND STATION

VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY4 Record# DATE TIME OPACITY4

1 05/21/2009 10:54 3.64 31 05/21/2009 11:24 3.76

2 05/21/2009 10:55 4.19 32 05/21/2009 11:25 3.58

3 05/21/2009 10:56 4.14 33 05/21/2009 11:26 3.47

4 05/21/2009 10:57 4.46 34 05/21/2009 11:27 3.17

5 05/21/2009 10:58 4.21 35 05/21/2009 11:28 3.20

6 05/21/2009 10:59 4.70 36 05/21/2009 11:29 3.44

7 05/21/2009 11:00 5.67 37 05/21/2009 11:30 3.29

8 05/21/2009 11:01 4.70 38 05/21/2009 11:31 3.54

9 05/21/2009 11:02 4.03 39 05/21/2009 11:32 3.67

10 05/21/2009 11:03 4.07 40 05/21/2009 11:33 3.97

11 05/21/2009 11:04 4.12 41 05/21/2009 11:34 3.83

12 05/21/2009 11:05 5.54 42 05/21/2009 11:35 3.98

13 05/21/2009 11:06 6.35 43 05/21/2009 11:36 4.04

14 05/21/2009 11:07 5.35 44 05/21/2009 11:37 3.78

15 05/21/2009 11:08 4.10 45 05/21/2009 11:38 3.79

16 05/21/2009 11:09 4.07 46 05/21/2009 11:39 3.85

17 05/21/2009 11:10 3.90 47 05/21/2009 11:40 3.98

18 05/21/2009 11:11 4.04 48 05/21/2009 11:41 3.93

19 05/21/2009 11:12 3.78 49 05/21/2009 11:42 3.70

20 05/21/2009 11:13 4.31 50 05/21/2009 11:43 3.51

21 05/21/2009 11:14 4.45 51 05/21/2009 11:44 3.75

22 05/21/2009 11:15 4.09 52 05/21/2009 11:45 3.73

23 05/21/2009 11:16 4.07 53 05/21/2009 11:46 3.52

24 05/21/2009 11:17 4.00 54 05/21/2009 11:47 3.20

25 05/21/2009 11:18 3.56 55 05/21/2009 11:48 3.61

26 05/21/2009 11:19 3.77 56 05/21/2009 11:49 3.57

27 05/21/2009 11:20 3.84 57 05/21/2009 11:50 3.71

28 05/21/2009 11:21 3.68 58 05/21/2009 11:51 3.46

29 05/21/2009 11:22 3.94 59 05/21/2009 11:52 3.75

30 05/21/2009 11:23 4.37 60 05/21/2009 11:53 3.54

Test Average: 3.974 %

Minimum One Minute Average: 3.170 %

Maximum One Minute Average: 6.350 %

Maximum Six Minute Average: 4.922 %

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

SOOTBLOWING CONDITIONS

10
BIG BEND STATION

HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (April): 9602 KMBtu/MWh

9.6020E+06 mmBtu/MWh

Testing Start Time: 8:00

Testing End Time: 15:43

Total Test Time: 7.72 hours

Average Unit Load, MWe: 442 MW

Heat Input, mmBtu/h = mmBtu/MWh x MW: 4240 mmBtu/hr

Laboratory Sample ID: AB01114

Btu as received: 10946 Btu/lb

Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 193.7 Tons/hour

Unit #4

Test Time Information

Calculated Heat Input

Fuel Consumption Calculation

DRY-BOTTOM TANGENTIALLY FIRED BOILER

May 21, 2009

11
12

5.0 FIGURES
13

FIGURE 1

EXHAUST STACK 

239 FT

BIG BEND GENERATING STATION 

PARTICULATE TRAVERSE POINTS 

71 FT

SAMPLING 

PLATFORM 

ESP OUTLET

UPPER

 

LOWER

ESP OUTLET

499 FT

260 FT

189 FT

N

A

B C 

D 

PORT LOCATION PLAN 

REVISED 12-30-

BOILER NO. 4 TEST LOCATION 

STACK DIAMETERS DOWNSTREAM 

FROM DISTURBANCE = 3.0 

STACK DIAMETERS UPSTREAM 

FROM DISTURBANCE = 10.0 

STACK DIAMETERR = 24.0 FT. ID. 

STACK AREA = 452.389 SQ FT. 

PORT LENGTH’S = 17 IN. 

TRAVERSE

 POINT 

 1 

 2 

 3 

 4 

 5 

 6 

 % OF 

STACK DIAMETER 

 IN. FROM 

STACK WALL

 2.1% 

 6.7% 

11.8%

17.7%

25.0%

35.6%

 6.05 IN. 

 19.30 IN. 

 33.98 IN. 

 50.98 IN. 

 72.00 IN. 

102.53 IN. 
APPENDIX A 

PARTICULATE MATTER TEST DATA 
A-1 

RUN CALCULATIONS 
Air Services Group

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Stack-Boiler #4

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 1

Date:

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.211 inches

Barometric Pressure, Pb: 29.68 "Hg Nozzle Area, An: 0.000243 ft2

Stack Pressure, Ps: 29.61 "Hg Average Orifice Meter, ΔH: 1.303 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 73.073 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 81.4 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 129.0 o

F

5.0 % O2 Average √Δp: 0.911 "H2O

0.0 % CO Condensate Volume, Vlc: 283.0 ml

81.0 % N2 Meter Box Y: 1.015 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Heat Input: 4240 mmBtu/hr

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.341 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 71.982 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.156 %

FDA = 1.0 - Bws 0.844 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.49 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 54.65 ft/second

Qs = vs x As x 60 2.141E+06 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1.603E+06 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.6 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.02345 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.005 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.004 grains/acf

C = cs / 7000 7.182E-07 lbs/dscf

ER = C x Fd x (20.9 /(20.9 - %O2) 0.009 lbs/mmBtu

EM = ER, lbs/mmBtu x Heat Input, mmBtu/hr 39.1 lbs/hr

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

May 21, 2009
Environmental, Health, & Safety

Air Services Group

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Stack-Boiler #4

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded, Sootblowing

Run Number: 2 - S

Date:

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.211 inches

Barometric Pressure, Pb: 29.69 "Hg Nozzle Area, An: 0.000243 ft2

Stack Pressure, Ps: 29.62 "Hg Average Orifice Meter, ΔH: 1.181 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 69.380 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 83.7 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 130.3 o

F

5.0 % O2 Average √Δp: 0.865 "H2O

0.0 % CO Condensate Volume, Vlc: 277.3 ml

81.0 % N2 Meter Box Y: 1.015 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Heat Input: 4240 mmBtu/hr

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.072 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 68.059 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.161 %

FDA = 1.0 - Bws 0.839 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.44 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 52.02 ft/second

Qs = vs x As x 60 2.038E+06 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1.514E+06 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.7 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01865 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.004 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 6.041E-07 lbs/dscf

ER = C x Fd x (20.9 /(20.9 - %O2) 0.008 lbs/mmBtu

EM = ER, lbs/mmBtu x Heat Input, mmBtu/hr 32.9 lbs/hr

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

May 21, 2009
Environmental, Health, & Safety

Air Services Group

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Stack-Boiler #4

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 3

Date:

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.211 inches

Barometric Pressure, Pb: 29.70 "Hg Nozzle Area, An: 0.000243 ft2

Stack Pressure, Ps: 29.63 "Hg Average Orifice Meter, ΔH: 1.233 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 70.991 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 85.0 o

F

Gas Analysis: 14.0 % CO2 Average Stack Temp., Ts: 130.0 o

F

5.0 % O2 Average √Δp: 0.882 "H2O

0.0 % CO Condensate Volume, Vlc: 278.4 ml

81.0 % N2 Meter Box Y: 1.015 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Heat Input: 4240 mmBtu/hr

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.124 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 69.512 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.159 %

FDA = 1.0 - Bws 0.841 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.44 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.46 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 53.00 ft/second

Qs = vs x As x 60 2.076E+06 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1.548E+06 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.6 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01300 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.0029 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.0022 grains/acf

C = cs / 7000 4.123E-07 lbs/dscf

ER = C x Fd x (20.9 /(20.9 - %O2) 0.005 lbs/mmBtu

EM = ER, lbs/mmBtu x Heat Input, mmBtu/hr 22.5 lbs/hr

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

May 21, 2009
A-2 

LABORATORY ANALYTICAL DATA 
Customer AIR SERVICES Plant BIG BEND Unit 4

Method 5-B Stack Test Completion Date 05/21/2009Analyst SS Sample Number

ACETONE BEAKER 1st weighing Date 05/28/2009 Time 15:30 % RH 38.0%

2nd weighing Date 05/29/2009 Time 9:00 % RH 38.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

***Blank*** Run 1 Run 2 S Run 3

Acetone Container ID AIR G5 AIR G2 AIR G1 AIR G6

Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 Enter Container ID Enter Container ID Enter Conta

1st Gross Wt., grams 99.7000 99.4917 95.1299 99.4383

2nd Gross Wt., grams 99.7000 99.4918 95.1296 99.4382 

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 99.70000 99.49175 95.12975 99.43825 Enter Gross Wts. Enter Gross Wts. Enter Gros

Tare Wt., grams 99.70035 99.47520 95.11590 99.42855 

Acetone Blank Wt., mg -0.35 -0.35 -0.35 -0.35

Acetone Particulate Wt., mg 16.90 14.20 10.05

Acetone Residue, mg/g -0.0022

Acetone Blank Criteria

 FILTER 1st weighing Date 05/27/2009 Time 15:30 % RH 39.0%

 2nd weighing Date 05/28/2009 Time 9:45 % RH 38.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

Filter/Thimble ID 203179 203176 203177 203178 

1st Gross Wt., grams 0.2479 0.2513 0.2524 0.2507

2nd Gross Wt., grams 0.2479 0.2512 0.2525 0.2507 

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 0.24790 0.25125 0.25245 0.25070 Enter Gross Wts. Enter Gross Wts. Enter Gros

Tare Wt., grams 0.24740 0.24470 0.24800 0.24775 

Filter Particulate Wt., mg 6.55 4.45 2.95

Difference, milligrams 0.5

Total Sample Particulate Wt., mg 23.45 18.65 13.00

OK to subtract acetone blank

Start Here
A-3 

CALIBRATION DATA 
Environmental, Health, & Safety

Air Services Group

SUMMARY OF EQUIPMENT CALIBRATIONS

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 08)

INITIAL 03/19/2009 USEPA RM 5 1.010

POST TEST 05/27/2009 (ORIFICE) 1.015

NOZZLE (SN75)

INITIAL 04/27/2009 CALIPER 0.211

POST TEST 05/22/2009 MEASUREMENTS 0.210

PYROMETER (PY 20) 03/19/2009 ASTM THERMOMETER + 2o

 F

PITOT TUBE (PT 12) 04/28/2009 USEPA RM 2 Cp = 0.84

BAROMETER (BR 07) 04/21/2009 NWS COMPARISON + 0.01" Hg
Environmental Services

Air Services Group

Blue Team

Manufacturer: APEX Calibration Date:

Model Number: 522 Barometric Pressure: 30.11 "Hg

Instrument Code Number: ^MB08 Theoretical Critical Vacuum: 14.20 "Hg

LabWorks Sample Number: Calibrated By:

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

0.69 15 223.300 229.981 6.681 72 72 72 72

1.20 15 229.981 238.881 8.900 72 72 73 73

1.95 15 238.881 250.358 11.477 73 73 74 74

3.60 15 250.358 266.082 15.724 74 74 77 77

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

48 0.3452 22.0 72 72 72.0

55 0.4596 20.5 72 72 72.0

63 0.5923 19.0 72 72 72.0

73 0.8106 16.5 72 72 72.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.681 6.760 6.770 1.012 0.001 1.909 0.058

8.903 9.000 9.014 1.011 0.000 1.871 0.021

11.481 11.598 11.617 1.010 0.000 1.827 -0.023

15.733 15.873 15.898 1.009 -0.002 1.794 -0.056

Averages: 1.010 1.850

Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

20-Mar-09

Critical Orifice Readings

Ambient Temperatures

CALCULATED DATA

Critical Orifice

The Critical Orifice Coefficient, K', should be in English units.

IMPORTANT

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

03/19/2009

SEG

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

Quarterly Calibration
Environmental Services

Air Services Group

Manufacturer: APEX Calibration Date:

Model Number: 522 Barometric Pressure: 31.3 "Hg

Instrument Code Number: MB08 Theoretical Critical Vacuum: 14.76 "Hg

LabWorks Sample Number: Calibrated By:

Associated Test: Team: RED

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

1.2 10 945.400 951.370 5.970 69 69 69 69

1.2 10 951.370 957.355 5.985 69 69 69 69

1.2 10 957.355 963.335 5.980 69 69 69 69

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

55 0.4596 21.5 70 70 70.0

55 0.4596 21.5 70 70 70.0

55 0.4596 21.5 70 70 70.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.249 6.249 5.998 1.000 0.001 1.805 0.000

6.264 6.249 5.998 0.997 -0.001 1.805 0.000

6.259 6.249 5.998 0.998 0.000 1.805 0.000

Averages: 0.999 1.805

Prior Y: 1.015

% Difference:(+/-5%) 1.61% PASS

BB#4-(05-21-09)

IMPORTANT

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.

Ambient Temperatures

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

Critical Orifice Readings

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

RJN

05/27/2009

POST - TEST CALIBRATION CHECK

CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice
Environmental Services

Air Services Group

Shared Resource

Calibration Date: Responsible Party:

Nozzle Maximum Average

I.D. D1 D2 D3 Difference, " Dn, inches

^SN01 0.292 0.293 0.293 0.001 0.115

^SN04 0.323 0.324 0.321 0.003 0.127

^SN05 0.382 0.383 0.380 0.003 0.150

^SN06 0.499 0.501 0.501 0.002 0.197

^SN10 0.755 0.753 0.754 0.002 0.297

^SN12 0.985 0.986 0.988 0.003 0.388

^SN15 0.415 0.415 0.417 0.002 0.164

^SN16 0.505 0.505 0.507 0.002 0.199

^SN19 0.712 0.712 0.714 0.002 0.281

^SN22 0.937 0.938 0.937 0.001 0.369

^SN30 0.795 0.795 0.796 0.001 0.313

^SN36 0.474 0.476 0.474 0.002 0.187

^SN37 0.525 0.523 0.525 0.002 0.206

^SN38 0.637 0.635 0.638 0.003 0.251

^SN46 0.482 0.482 0.484 0.002 0.190

^SN47 0.514 0.515 0.515 0.001 0.203

^SN48 0.638 0.638 0.640 0.002 0.251

^SN50 0.793 0.790 0.792 0.003 0.312

^SN58 0.613 0.614 0.613 0.001 0.241

^SN68 0.624 0.625 0.625 0.001 0.246

^SN69 0.949 0.949 0.947 0.002 0.373

^SN70 1.564 1.564 1.564 0.000 0.616

^SN71 1.563 1.563 1.563 0.000 0.615

^SN72 0.958 0.958 0.960 0.002 0.377

^SN73 1.283 1.282 1.283 0.001 0.505

^SN74 1.229 1.229 1.230 0.001 0.484

^SN75 0.536 0.536 0.536 0.000 0.211

^SN76 0.632 0.632 0.632 0.000 0.249

^SN77 0.691 0.691 0.691 0.000 0.272

Nozzle Diameter, Dn (cm)

QUARTERLY NOZZLE CALIBRATIONS

STEEL NOZZLE SET

04/27/2009 RJN
Environmental Services

Air Services Group

Shared Resource

Calibration Date:

Calibration Personnel:

Test Designation:

Maximum Average

D1 D2 D3 Difference, " Dn, inches

0.210 0.210 0.211 0.001 0.210

Data Notations: 

Maximum Difference must be < 0.004".

Quarterly (pre-test) value for nozzle ID SN75 was 0.211

Difference (Pre-test/Post-test) is: 0.001 PASS

POST TEST NOZZLE CALIBRATION 

Nozzle

Identifier

Nozzle Diameter, Dn (in)

05/22/2009

SEG

BB #4-(05/21/09

SN75
Air Services Group

Shared

Pyrometer Under Test

Pyrometer Number: ^PY20

Labworks Sample #

Calibration Date: 03/19/2009

Calibrator Information

Calibrator Type/Manufacturer: Hart Scientific

Calibrator Serial Number: AOA024

Date of Last Calibration: 04/29/2009

Calibration Personnel (Typed and Signature):

Calibration Data

Calibration Reference Pyrometer

Point Temperature Indication Difference

1 400 398 2

2 212 213 -1

3 32 32 0

Reference temperatures must encompass the expected range of measurement. These three points

should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit.

Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration

Point Difference

1 Pass

2 Pass

3 Pass

Reviewer:

Pyrometer Calibration

0

SEG

20-Mar-09
Pitot Tube ID #

Calibration Date Operating Quarter/Year: 2/2009

Openings Damaged? ___ Y ___N Repaired? ____Y ___ N ___ N/A

Labworks #:

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0 degrees Dt 0.48 < Dt > 0.95 cm

α 2 0 degrees α < 10 degrees

β 1 0 degrees

β 2 0 degrees

β1 < 5 degrees (alongside top impact openings)

Gamma, Theta, Α, Ζ, and W Determinationsβ2 < 5 degrees (alongside bottom impact openings)

ψ 0 degrees Ζ < 0.32 cm (Αsinψ)

Α 2.32 cm W < 0.08 cm (Asinο)

Ζ 0.000 cm Α distance between tips

ο angle of plane on side of pitots

ο 0 degrees ψ angle between tips

W 0.000 cm

Comments:

Calibrated by:

PITOT TUBE CALIBRATION

DATA SHEET

PT12

04/28/2009 Shared Resource

0

Pass

Pass

Pass (α1 measured across top impact openings)

Pass (α2 measured across bottom impact openings)

Pass

Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, 

Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement

details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems:

Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

REMOVABLE

RJN
Environmental Services

Air Services Group

Blue Team

Instrument Number:

Calibration Date:

Calibration Personnel:

Difference

Time "Hg

9:00 -0.01

10:30 -0.01

11:30 0.01

Average Difference: -0.00333

Note: Barometric readings must agree within ± 0.1 "Hg.

Current Reference is National Weather Service, TIA.

Comments (Note any adjustments):

BAROMETER CALIBRATION

^BR07

04/21/2009

SEG

Barometer Reading Reference Reading

Inches Mercury Inches Mercury

30 30.01

30 30.01

30.03 30.02

Current Conditions at Tampa International Airport
A-4 

FIELD DATA SHEETS 



A-5 

CHAIN OF CUSTODY 

APPENDIX B 

AMMONIA SLIP TEST DATA 
B-1 

RUN DATA 



 B-2 

RAW DATA 







 B-3 

METHOD MAP 
EPA METHOD 320 - METHOD MAP 

OVERALL CONC UNCERTAINTIES OCU 

OCUcomp is the maximum of RSAcomp times OFUcomp or MAUcomp 

OFUcomp is the maximum of FRUcomp, FCUcomp, FAUcomp, and FMUcomp 

RSAcomp is the typical concentration observed in data set [Appendix I] 

MAUcomp is calculated using Appendix D information 

RMS is the root mean square noise level of the system [Appendix C]or noise levels 

observed in the specific analytical regions used [Appendix G] 

DLcomp, Aucomp, and AAIcomp are described in Appendix B 

FUcomp, FLcomp, are the upper and lower wavenumber limits of the analysis region 

used in a method. 

FRUcomp is calculated using Appendix E and is based on the comparison of two CTS 

data sets. 

SRMScomp is the average of the RMS value observed for each subtracted pair of CTS 

spectra 

BAVcomp is the average of the calculated areas for each added pair of CTS spectra 

FFUcts and FFLcts are the upper and lower limits of the CTS analysis region used 

FCUcomp is determined by using Appendix F procedures if reference spectra are 

produced or are from an unknown source. 

If reference spectra are obtained from a documented source and the error in values can be 

provided by the supplier then that value can be 

used to define the component FCU value. 

For Hitran calculated spectra the FCU is minimal and should set at 0.05 [0.5%] 

If a set of references are used in the method and there is uncertainity in concentration of 

any spectrum in the set then Appendix F procedures should be applied 

FAUcomp is determined using Appendix H procedures 

Part of the procedure is used to determine cell pathlength. A better procedure involving 

ASTM-D6348 and using a freon gas can be 

substituted for cell path confirmation. 

Two added sets of CTS spectra are required with a minimum of 3 spectra per set made at 

the CTS ref pressure. 

These sets are used to compare CTS band area absorbance [ average or integrated] 

Use the average of the results for each spectra used in these caluculations for final FAU 

FMUcomp is determined using Appendix I procedures 
These calculations require actual sample spectra. The number is not specified so a 

minimum of three are suggested. 

These spectra may or may not have the component[s] of interest present. 

RSAcomp is the reported concentration of the component in the spectrum being used. 

AAI is the area of the comp absorbance at the concentration determined by AUcomp and 

DLcomp. 

RMSScomp is RMS evaluation of the spectrum resulting from subtraction of all 

compounds and interferents present in an analysis region 

Note: Above guidance assumes only one analysis region is used for concentration 

determination of a component. 

 If more than one region is used the results of all calulations must be the weighted 

average of all regions 

 The weighting factor is determined by the size of each region in wavenumbers. 

Note2: If analysis software includes region window selection ability to editted out large 

interfereant peaks and [or] 

 dynamic reference selection then CLS results using an assembled method will 

often be better than methd 320 calculations reported. 
 B-4 

SUMMARIZED QA DATA 
Environmental Services

Air Services Group

FTIR LAB REPORT

Location: Big Bend

Unit: 4

Test Date: 05/21/2009

Peak Analysis:

ACLF: 15798.2575 PASSED

FWHH: 0.4856 PASSED

Single Beam: 0.97 PASSED

Ethylene CTS Spectra:

Low Range Pre-Test: 20.8898276 PASSED 20.96 0.4192

Low Range Post-Test: 20.886514 PASSED 21.3792 20.5408

0.0033136 Difference

SNR Test(3 Run Mean)

920-975 cm-1 987-1087 cm-1 2900-3000 cm-1

RMS Noise: 0.068498 0.073051 0.122081

MAU: 0.297484 0.31725 0.530183

SNR: 1466 1370 820

Cylinder Bottles:

NH3 Cylinder S/N:NH3 Cylinder S/N: EA-0004542 N2 Cylinder S/N: CC-125621

Expiration Date: 28-Jan-10 Expiration Date: 20-Mar-12

Bottle Pressure: 1900/1400 Bottle Pressure: 1800/1400

CTS Cylinder S/N:CTS Cylinder S/N: 4020902 Freon Cylinder S/N: N/A

Expiration Date: 28-Jan-12 Expiration Date: N/A

Bottle Pressure: 1400/300 Bottle Pressure: N/A

Temperatures:

Umbilical #1(10 Foot): 300 PASSED

Probe: 300 PASSED

FTIR Leak Check:

Vac.

Initial 0.120

Maximum 0.122

Leakage 0.002

% Leak 2.003

* Must be < 4%

Barometric Pressure 29.68

System Pressure 0.9553

Spike Response Time Up/Down 45
 B-5 

LEAK RATE DATA 
Leak Rates

Spectrum Date Time CO2high WaterH Temp (C) Pressure (Atm)

LEAK RATE_000001.LAB 05/21/2009 47:20.3 -0.02093 3.677043 150 0.119562

LEAK RATE_000002.LAB 05/21/2009 47:29.7 -0.02167 3.781037 150 0.120012

LEAK RATE_000003.LAB 05/21/2009 47:39.0 -0.0178 3.904974 150 0.119958

LEAK RATE_000004.LAB 05/21/2009 47:48.4 -0.01725 3.855458 150 0.120012

LEAK RATE_000005.LAB 05/21/2009 47:57.8 -0.01622 3.959517 150 0.120279

LEAK RATE_000006.LAB 05/21/2009 48:07.2 -0.01247 4.198507 150 0.120529

LEAK RATE_000007.LAB 05/21/2009 48:16.6 -0.01965 4.145409 150 0.120851

LEAK RATE_000008.LAB 05/21/2009 48:26.0 -0.0176 4.231237 150 0.120694

LEAK RATE_000009.LAB 05/21/2009 48:35.4 -0.01257 4.334605 150 0.12104

LEAK RATE_000010.LAB 05/21/2009 48:44.9 -0.01256 4.341918 150 0.121172

LEAK RATE_000011.LAB 05/21/2009 48:54.2 -0.00689 4.456692 150 0.121386

LEAK RATE_000012.LAB 05/21/2009 49:03.6 -0.013 4.187246 150 0.121578

LEAK RATE_000013.LAB 05/21/2009 49:13.1 -0.01645 4.559827 150 0.121586

LEAK RATE_000014.LAB 05/21/2009 49:22.4 -0.0058 4.426224 150 0.121739

LEAK RATE_000015.LAB 05/21/2009 49:31.8 -0.01877 4.361546 150 0.121957

Page 1 of 1
 B-6 

ETHYLENE CTS DATA 
Ethylene CTS standard Results - Tampa Electric MKS FTIR System 

#

Lower Region Upper Region 

Date Dif.-nominal 949.43 pk Dif.-nominal 2988.4 pk Standard Conc. 900-1000cm-1 reg 2800-3050cm-1 reg 

[cm-1] [cm-1] PPM reported conc. PPM reported conc. PPM

Example 0.024 8:24:00 5.03 4.41843 3.854914 

20

LOW RANGEPre-TestSpectrum Date Time C2H4 Temp (C) Pressure (Atm)PRECHECK_000007 05/21/2009 8:34:54 21.055968 150 0.964972

PRECHECK_000008 05/21/2009 8:35:50 20.833107 150 0.964264PRECHECK_000009 05/21/2009 8:36:46 20.825958 150 0.96427PRECHECK_000010 05/21/2009 8:37:43 20.823475 150 0.962623PRECHECK_000011 05/21/2009 8:38:39 20.91063 150 0.963794Post-TestSpectrum Date Time C2H4 Temp (C) Pressure (Atm)CTS_000409.LAB 05/21/2009 16:01:27 20.791885 150 0.971425CTS_000410.LAB 05/21/2009 16:02:23 20.827944 150 0.998068CTS_000411.LAB 05/21/2009 16:03:20 20.844568 150 1.004292CTS_000412.LAB 05/21/2009 16:04:16 20.970343 150 1.026814CTS_000413.LAB 05/21/2009 16:05:12 20.99783 150 1.077998
 B-7 

SPIKE DATA 
COMPOUND SPIKING INFORMATION SHEET: BB#4 Compliance

All conc. in PPM All Flow in LIT/MinSpike Label Spike Gas Spike Gas Total Flow Spike Gas Spike Gas SF56 Gas Exptd SF6 Expt Sample Trv Cell Flush Wait min prior Native s

In Conc. Flow Rate Rate FR % of Tot Flow Conc. In Conc. Sample Conc. Time to Cell [min] Time [min] / after spike dilution c

Preliminary 50.1 1 11 9.090909091 5.664237755 2.99 0.249616 1.2828 0.40909091 1.86108 0.9090Mid Spike 50.1 1 11 9.090909091 5.350227089 2.99 0.252144 1.2828 0.40909091 1.86108 0.9090Final 50.1 1 11 9.090909091 5.293497864 2.99 0.252302 1.2828 0.40909091 1.86108 0.9090Note:Tank Certified Concentrations : 50.1 2.99Sample lines are assumed as 3/8 OD [ 9/32" ID]Calibration lines are assumed as 1/4 OD [ 3/32" ID]Cell volume is assumed as 1.5 litersPreliminary NativeNH3 1.11SF6 -0.02First RunNH3 0.80SF6 -0.02Second RunNH3 0.74SF6 -0.02Third RunNH3 0.62SF6 -0.02
Native

Spectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000001.LAB 05/21/2009 9:56:51 9.571389 15.37527 -0.022572 1.110467 150 0.958112RAW_000002.LAB 05/21/2009 9:57:47 9.650423 15.579446 -0.02016 1.099675 150 0.957737RAW_000003.LAB 05/21/2009 9:58:44 9.664538 15.498573 -0.023199 1.184036 150 0.957231RAW_000004.LAB 05/21/2009 9:59:40 9.525 15.270251 -0.01899 1.100407 150 0.959022RAW_000005.LAB 05/21/2009 10:00:36 9.547134 15.460906 -0.02153 1.096363 150 0.957458RAW_000006.LAB 05/21/2009 10:01:33 9.548934 15.621311 -0.021382 1.149348 150 0.957844RAW_000007.LAB 05/21/2009 10:02:29 9.455227 15.470348 -0.023698 1.114115 150 0.958647RAW_000008.LAB 05/21/2009 10:03:26 9.478468 15.403819 -0.023724 1.07004 150 0.958236RAW_000009.LAB 05/21/2009 10:04:22 9.544648 15.643941 -0.024079 1.091974 150 0.958272RAW_000010.LAB 05/21/2009 10:05:18 9.460892 15.631537 -0.02269 1.080498 150 0.959569Preliminary SpikeSpectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000011.LAB 05/21/2009 10:06:15 8.414733 14.218709 0.216614 0.766196 150 0.961527RAW_000012.LAB 05/21/2009 10:07:11 8.317543 13.923193 0.251455 1.632104 150 0.961134RAW_000013.LAB 05/21/2009 10:08:08 8.332355 14.064097 0.247891 2.237182 150 0.959284RAW_000014.LAB 05/21/2009 10:09:04 8.353111 13.872268 0.249611 2.611062 150 0.960671RAW_000015.LAB 05/21/2009 10:10:00 8.342266 13.772104 0.251257 2.967268 150 0.96048RAW_000016.LAB 05/21/2009 10:10:57 8.343999 13.930647 0.249264 3.172666 150 0.960605RAW_000017.LAB 05/21/2009 10:11:53 8.344879 13.985506 0.248277 3.343473 150 0.960837RAW_000018.LAB 05/21/2009 10:12:50 8.327165 13.816005 0.250494 3.510818 150 0.959462RAW_000019.LAB 05/21/2009 10:13:46 8.295203 13.874017 0.249005 3.62704 150 0.959052RAW_000020.LAB 05/21/2009 10:14:42 8.256015 13.990845 0.247073 3.686025 150 0.959545RAW_000021.LAB 05/21/2009 10:15:39 8.284556 13.898525 0.248444 3.807125 150 0.959736RAW_000022.LAB 05/21/2009 10:16:35 8.273056 13.787793 0.246917 3.861018 150 0.960402RAW_000023.LAB 05/21/2009 10:17:32 8.275966 13.964545 0.247412 3.915745 150 0.959152RAW_000024.LAB 05/21/2009 10:18:28 8.27115 14.014067 0.247418 3.987342 150 0.958385RAW_000025.LAB 05/21/2009 10:19:24 8.33917 13.820909 0.246521 4.07038 150 0.959379RAW_000026.LAB 05/21/2009 10:20:21 8.320519 13.833763 0.24763 4.169982 150 0.959551RAW_000027.LAB 05/21/2009 10:21:17 8.422175 13.991079 0.246746 4.193979 150 0.959647RAW_000028.LAB 05/21/2009 10:22:14 8.33611 13.866765 0.248091 4.239352 150 0.959837RAW_000029.LAB 05/21/2009 10:23:10 8.346263 13.726868 0.248022 4.255335 150 0.96139RAW_000030.LAB 05/21/2009 10:24:06 8.337697 13.927172 0.245212 4.304216 150 0.959046RAW_000031.LAB 05/21/2009 10:25:03 8.332434 13.999169 0.246834 4.335892 150 0.958528RAW_000032.LAB 05/21/2009 10:25:59 8.271807 13.81152 0.247593 4.371319 150 0.959111RAW_000033.LAB 05/21/2009 10:26:55 8.291526 13.837884 0.248992 4.441643 150 0.959486RAW_000034.LAB 05/21/2009 10:27:52 8.221155 13.99145 0.250286 4.465228 150 0.959688RAW_000035.LAB 05/21/2009 10:28:48 8.202179 13.949442 0.247868 4.47871 150 0.960533RAW_000036.LAB 05/21/2009 10:29:45 8.254481 13.769145 0.249587 4.551546 150 0.960069RAW_000037.LAB 05/21/2009 10:30:41 8.315633 13.828757 0.245283 4.484059 150 0.95955RAW_000038.LAB 05/21/2009 10:31:37 8.282946 13.958423 0.246597 4.459526 150 0.960146RAW_000039.LAB 05/21/2009 10:32:34 8.338794 13.970686 0.242073 4.48283 150 0.957439RAW_000040.LAB 05/21/2009 10:33:30 8.361159 14.02122 0.242994 4.492259 150 0.956332RAW_000041.LAB 05/21/2009 10:34:27 8.312418 14.018682 0.243577 4.45385 150 0.957445RAW_000042.LAB 05/21/2009 10:35:23 8.36093 14.02636 0.240693 4.4571 150 0.956529

0.242421333 4.4677363

Results-Recovery 97.12% 78.88%
Mid Spike

Spectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000131.LAB 05/21/2009 12:00:38 9.414345 15.690762 -0.01851 0.64598 150 0.962592RAW_000132.LAB 05/21/2009 12:01:35 8.323884 14.604865 0.215248 0.310473 150 0.964633RAW_000133.LAB 05/21/2009 12:02:31 8.293777 14.09477 0.260682 0.354719 150 0.963794RAW_000134.LAB 05/21/2009 12:03:28 8.327495 14.238074 0.257961 0.722653 150 0.963758RAW_000135.LAB 05/21/2009 12:04:24 8.288538 14.353838 0.260877 1.123555 150 0.962734RAW_000136.LAB 05/21/2009 12:05:21 8.317845 14.154359 0.258554 1.49666 150 0.963752RAW_000137.LAB 05/21/2009 12:06:17 8.306508 14.195277 0.259934 1.9116 150 0.962675RAW_000138.LAB 05/21/2009 12:07:14 8.226913 14.338928 0.260884 2.22242 150 0.963865RAW_000139.LAB 05/21/2009 12:08:10 8.287744 14.295667 0.257433 2.497309 150 0.962985RAW_000140.LAB 05/21/2009 12:09:06 8.296001 14.115497 0.25784 2.746342 150 0.96229RAW_000141.LAB 05/21/2009 12:10:03 8.331204 14.254138 0.260512 3.029011 150 0.963421RAW_000142.LAB 05/21/2009 12:10:59 8.263595 14.312464 0.260522 3.205731 150 0.963709RAW_000143.LAB 05/21/2009 12:11:56 8.266532 14.156622 0.258512 3.35172 150 0.963621RAW_000144.LAB 05/21/2009 12:12:52 8.251986 14.098066 0.262475 3.496376 150 0.962717RAW_000145.LAB 05/21/2009 12:13:48 8.25275 14.29827 0.258408 3.694846 150 0.962938RAW_000146.LAB 05/21/2009 12:14:45 8.229365 14.304665 0.255118 3.743775 150 0.962812RAW_000147.LAB 05/21/2009 12:15:41 8.182514 14.128282 0.259316 3.86432 150 0.963276RAW_000148.LAB 05/21/2009 12:16:38 8.213764 14.24658 0.259417 3.962146 150 0.962771RAW_000149.LAB 05/21/2009 12:17:34 8.298604 14.406182 0.260196 4.024177 150 0.962794RAW_000150.LAB 05/21/2009 12:18:30 8.258108 14.267814 0.258031 4.001077 150 0.962943RAW_000151.LAB 05/21/2009 12:19:27 8.23058 14.162892 0.259268 4.040577 150 0.963788RAW_000152.LAB 05/21/2009 12:20:23 8.290249 14.386847 0.25776 4.132456 150 0.963049RAW_000153.LAB 05/21/2009 12:21:20 8.349968 14.384175 0.258154 4.176603 150 0.963128RAW_000154.LAB 05/21/2009 12:22:16 8.324376 14.167949 0.259615 4.157514 150 0.963604RAW_000155.LAB 05/21/2009 12:23:13 8.334044 14.265654 0.257933 4.220736 150 0.962759RAW_000156.LAB 05/21/2009 12:24:09 8.313623 14.431666 0.258229 4.243697 150 0.96255RAW_000157.LAB 05/21/2009 12:25:06 8.209853 14.274137 0.256305 4.295358 150 0.963055RAW_000158.LAB 05/21/2009 12:26:02 8.299555 14.156803 0.259463 4.25045 150 0.963949RAW_000159.LAB 05/21/2009 12:26:58 8.334809 14.37405 0.258718 4.3592 150 0.962132RAW_000160.LAB 05/21/2009 12:27:55 8.320801 14.35539 0.255405 4.331233 150 0.963151RAW_000161.LAB 05/21/2009 12:28:51 8.204269 14.10346 0.256178 4.352884 150 0.963508RAW_000162.LAB 05/21/2009 12:29:47 8.271558 14.196736 0.258894 4.426425 150 0.964205

0.256825667 4.3701807

Results-Recovery 101.86% 81.68%
Final Spike

Spectrum Date Time CO2high WaterH SF6 NH3low Temp (C) Pressure (Atm)RAW_000331.LAB 05/21/2009 15:08:44 9.087673 15.545847 0.034169 0.471141 150 0.961021RAW_000332.LAB 05/21/2009 15:09:41 8.316373 14.549508 0.262444 0.215333 150 0.960443RAW_000333.LAB 05/21/2009 15:10:38 8.269835 14.40519 0.263146 0.197649 150 0.959926RAW_000334.LAB 05/21/2009 15:11:34 8.289158 14.201839 0.263255 0.380378 150 0.961569RAW_000335.LAB 05/21/2009 15:12:30 8.257661 14.33254 0.261583 0.639869 150 0.959879RAW_000336.LAB 05/21/2009 15:13:27 8.292715 14.378548 0.261123 0.946546 150 0.960531RAW_000337.LAB 05/21/2009 15:14:23 8.185153 14.171334 0.260161 1.247186 150 0.961081RAW_000338.LAB 05/21/2009 15:15:20 8.149281 14.154103 0.262098 1.422308 150 0.96017RAW_000339.LAB 05/21/2009 15:16:16 8.178864 14.308905 0.258384 1.643827 150 0.960414RAW_000340.LAB 05/21/2009 15:17:13 8.228129 14.25363 0.261585 1.790565 150 0.961188RAW_000341.LAB 05/21/2009 15:18:09 8.218201 14.110685 0.260807 1.950675 150 0.96045RAW_000342.LAB 05/21/2009 15:19:05 8.22594 14.238516 0.261057 2.184233 150 0.960379RAW_000343.LAB 05/21/2009 15:20:02 8.217563 14.302813 0.260497 2.352208 150 0.959503RAW_000344.LAB 05/21/2009 15:20:58 8.308079 14.196646 0.257706 2.533771 150 0.959551RAW_000345.LAB 05/21/2009 15:21:55 8.267305 14.161286 0.258724 2.719881 150 0.959534RAW_000346.LAB 05/21/2009 15:22:51 8.218225 14.302692 0.259348 2.959884 150 0.959438RAW_000347.LAB 05/21/2009 15:23:48 8.29031 14.264668 0.25928 3.151886 150 0.959968RAW_000348.LAB 05/21/2009 15:24:44 8.299126 14.082866 0.259543 3.355879 150 0.959333RAW_000349.LAB 05/21/2009 15:25:41 8.251649 14.144494 0.258471 3.487445 150 0.960075RAW_000350.LAB 05/21/2009 15:26:37 8.344042 14.264525 0.256943 3.687453 150 0.959718RAW_000351.LAB 05/21/2009 15:27:33 8.25653 14.11426 0.259 3.766756 150 0.959908RAW_000352.LAB 05/21/2009 15:28:30 8.241554 14.080467 0.262228 3.849185 150 0.959647RAW_000353.LAB 05/21/2009 15:29:26 8.255683 14.259041 0.255654 3.927996 150 0.95973RAW_000354.LAB 05/21/2009 15:30:23 8.227933 14.255063 0.257031 3.971992 150 0.958641RAW_000355.LAB 05/21/2009 15:31:19 8.325161 14.067875 0.255471 4.008022 150 0.960099RAW_000356.LAB 05/21/2009 15:32:16 8.270023 14.147918 0.257133 4.104521 150 0.959941RAW_000357.LAB 05/21/2009 15:33:12 8.312762 14.286307 0.254015 4.185822 150 0.960379RAW_000358.LAB 05/21/2009 15:34:09 8.262644 14.165361 0.258552 4.192727 150 0.960581RAW_000359.LAB 05/21/2009 15:35:05 8.285486 14.073093 0.260446 4.289372 150 0.962396RAW_000360.LAB 05/21/2009 15:36:01 8.227065 14.24756 0.258451 4.329121 150 0.961533RAW_000361.LAB 05/21/2009 15:36:58 8.278161 14.22448 0.259775 4.382397 150 0.961302RAW_000362.LAB 05/21/2009 15:37:54 8.255054 14.0475 0.263432 4.431328 150 0.96142RAW_000363.LAB 05/21/2009 15:38:51 8.305893 14.093783 0.260695 4.502025 150 0.961592RAW_000364.LAB 05/21/2009 15:39:47 8.252356 14.220447 0.25836 4.512483 150 0.96136RAW_000365.LAB 05/21/2009 15:40:44 8.264661 14.058598 0.258085 4.467692 150 0.960251RAW_000366.LAB 05/21/2009 15:41:40 8.367954 13.993873 0.259192 4.502998 150 0.960593RAW_000367.LAB 05/21/2009 15:42:36 8.366025 14.164224 0.25988 4.55746 150 0.960087RAW_000368.LAB 05/21/2009 15:43:33 8.317135 14.176866 0.256888 4.51077 150 0.959914

0.258653333 4.5237427

Results-Recovery 102.52% 85.46%
 B-8 

SNR TEST DATA 
SNR-Test

SNR Report, 05/21/2009, 8:02 AM

Number of Scans = 60

Resolution = .5 cm-1 Single Sided

Pass 1

Range = 920-975 cm-1, RMS Noise=0.062624% (0.271955 mAU), SNR=1597

Range = 987-1087 cm-1, RMS Noise=0.072422% (0.314509 mAU), SNR=1381

Range = 2900-3000 cm-1, RMS Noise=0.116985% (0.507984 mAU), SNR=855

Pass 2

Range = 920-975 cm-1, RMS Noise=0.069386% (0.301382 mAU), SNR=1441

Range = 987-1087 cm-1, RMS Noise=0.071497% (0.310504 mAU), SNR=1399

Range = 2900-3000 cm-1, RMS Noise=0.125246% (0.543974 mAU), SNR=798

Pass 3

Range = 920-975 cm-1, RMS Noise=0.073482% (0.319116 mAU), SNR=1361

Range = 987-1087 cm-1, RMS Noise=0.075235% (0.326739 mAU), SNR=1329

Range = 2900-3000 cm-1, RMS Noise=0.124013% (0.538590 mAU), SNR=806

Mean Results

Range = 920-975 cm-1, RMS Noise=0.068498% (0.297484 mAU), SNR=1466

Range = 987-1087 cm-1, RMS Noise=0.073051% (0.317250 mAU), SNR=1370

Range = 2900-3000 cm-1, RMS Noise=0.122081% (0.530183 mAU), SNR=820

RMS Noise Mau SNR

920-975 cm-1 0.068498 0.297484 1466

987-1087 cm-1 0.073051 0.31725 1370

2900-3000 cm-1 0.122081 0.530183 820

Page 1 of 1
 B-9 

ANNUAL CELL PATH CHECK DATA 
PathLength Verification Spread Sheet TAMPA ELECTRIC

Stack FTIR System

test gas information reference information calculated path length

date F116 conc F116 press F116 temp. pk area F116 conc F116 pressF116 temp pk area [meters] e

PPM mm deg C 1080-1160 PPM-M mm deg C 1080-1160 

test 35 680 150 5.9 206.9 761 185 7.09 5.084645 

05/09/2007 35 781.28 149.7 6.557 206.9 761 185 7.09 4.914824 01/06/2009 34.8 791.1 149.5 6.353 206.9 761 185 7.09 4.727596 

adj PL-1/6/2009 34.8 791.1 149.5 6.353 206.9 761 185 7.09 4.727596 4.82 meters is the next logical pathlength lower than the std 5.11 meters. Based on the next highest path length seen in MKS spectra of 5.4 meter. [ dif of 0.29met
B-10 

CYLINDER GAS CERTIFICATES OF ANALYSIS 



APPENDIX C 

CONTINUOUS EMISSIONS MONITORING DATA 
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 8:00 53.9 12.32 77.2 11

05/21/2009 8:01 54.3 12.29 81.2 11.06

05/21/2009 8:02 53.1 12.28 90.6 11.01

05/21/2009 8:03 51.3 12.31 95.5 11.04

05/21/2009 8:04 51 12.38 106.7 11.07

05/21/2009 8:05 51.3 12.36 108.2 11.07

05/21/2009 8:06 49.9 12.37 113.3 11.16

05/21/2009 8:07 48.3 12.43 117.4 11.04

05/21/2009 8:08 48.4 12.4 120.9 10.96

05/21/2009 8:09 49.6 12.27 109.6 11

05/21/2009 8:10 49.1 12.26 91.4 11.02

05/21/2009 8:11 49.5 12.27 82.2 11

05/21/2009 8:12 50 12.26 80.5 10.98

05/21/2009 8:13 51.3 12.33 84.6 11.04

05/21/2009 8:14 50.6 12.3 94.7 11.05

05/21/2009 8:15 49.6 12.37 97.4 11.08

05/21/2009 8:16 49.2 12.39 102.2 11.22

05/21/2009 8:17 47.8 12.46 108.6 11.15

05/21/2009 8:18 47.1 12.48 113.7 11.13

05/21/2009 8:19 47.6 12.43 119.1 11.1

05/21/2009 8:20 46.9 12.42 131.6 11.07

05/21/2009 8:21 46.9 12.46 132.2 11

05/21/2009 8:22 48.8 12.34 104.4 11.05

05/21/2009 8:23 48.4 12.33 89 11.02

05/21/2009 8:24 49.7 12.34 94.1 11.04

05/21/2009 8:25 49.1 12.3 98.2 11.05

05/21/2009 8:26 51.2 12.33 95 11.06

05/21/2009 8:27 52 12.35 103.4 11.09

05/21/2009 8:28 52.2 12.34 111.5 11.09

05/21/2009 8:29 51.8 12.39 111.5 11.1

05/21/2009 8:30 52.2 12.39 113.6 11.08

05/21/2009 8:31 51.1 12.39 124.1 11.05

05/21/2009 8:32 50.7 12.36 138.9 11.03

05/21/2009 8:33 50.2 12.35 140.7 11.06

05/21/2009 8:34 49.6 12.4 115.4 11.13

05/21/2009 8:35 49.1 12.43 91 11.02

05/21/2009 8:36 50.2 12.39 86.2 11.06

05/21/2009 8:37 50.8 12.32 93.1 10.99

05/21/2009 8:38 50.9 12.28 99.3 11.01

05/21/2009 8:39 51.4 12.29 111.4 11.04

05/21/2009 8:40 51.2 12.33 121.7 11.05

05/21/2009 8:41 51.5 12.36 130.3 11.06

05/21/2009 8:42 51.3 12.35 136.3 11.02

Page 1 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 8:43 50.9 12.32 134.3 11.03

05/21/2009 8:44 51.7 12.35 124.2 11.02

05/21/2009 8:45 51 12.35 98.1 11.06

05/21/2009 8:46 49.7 12.36 84.3 11.01

05/21/2009 8:47 48.9 12.33 75.9 11.11

05/21/2009 8:48 48.9 12.32 82 11.03

05/21/2009 8:49 49.5 12.31 85.3 11.03

05/21/2009 8:50 48.9 12.31 94 10.98

05/21/2009 8:51 48.8 12.32 114.7 10.95

05/21/2009 8:52 49.9 12.28 128 10.99

05/21/2009 8:53 51 12.31 136.1 10.97

05/21/2009 8:54 51.8 12.27 144.6 10.97

05/21/2009 8:55 51.6 12.29 137.6 10.97

05/21/2009 8:56 51.8 12.3 128.3 11.1

05/21/2009 8:57 50.3 12.33 98.6 11.12

05/21/2009 8:58 49.5 12.39 88.4 11.12

05/21/2009 8:59 48.8 12.43 95.8 11.13

05/21/2009 9:00 49.2 12.43 102.7 11.07

05/21/2009 9:01 49.5 12.4 108.5 11

05/21/2009 9:02 49.8 12.37 116.6 11.02

05/21/2009 9:03 49.7 12.26 126.2 11.01

05/21/2009 9:04 49.6 12.3 133.1 11.02

05/21/2009 9:05 50 12.3 148.2 10.97

05/21/2009 9:06 51.6 12.27 149 11

05/21/2009 9:07 51.6 12.27 140.5 11.03

05/21/2009 9:08 52.3 12.29 113.9 11

05/21/2009 9:09 52.6 12.31 90.6 11.12

05/21/2009 9:10 51.8 12.35 91 11.05

05/21/2009 9:11 52.6 12.34 103.1 11.03

05/21/2009 9:12 52.3 12.3 103.1 11.05

05/21/2009 9:13 52 12.32 111.7 11.02

05/21/2009 9:14 52 12.3 121.2 10.93

05/21/2009 9:15 51.9 12.25 126.5 10.96

05/21/2009 9:16 51.5 12.27 147.5 10.93

05/21/2009 9:17 51.3 12.24 143.3 10.94

05/21/2009 9:18 52.3 12.24 133.7 10.94

05/21/2009 9:19 52.6 12.25 119.4 11.04

05/21/2009 9:20 50.5 12.32 109.3 11.07

05/21/2009 9:21 49.1 12.38 86.2 11.13

05/21/2009 9:22 49.3 12.4 89.1 11.1

05/21/2009 9:23 48.9 12.39 97.9 11.08

05/21/2009 9:24 48.3 12.38 101.6 11.05

05/21/2009 9:25 48.1 12.38 93.9 11.03

Page 2 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 9:26 48.3 12.32 94.7 11.07

05/21/2009 9:27 47.9 12.34 107.8 10.95

05/21/2009 9:28 48.9 12.32 105.1 10.92

05/21/2009 9:29 49.2 12.21 95.2 11

05/21/2009 9:30 48.3 12.26 104.2 11.07

05/21/2009 9:31 49.2 12.35 117.4 11.05

05/21/2009 9:32 49.6 12.36 118.7 11.06

05/21/2009 9:33 50 12.36 125.9 11.05

05/21/2009 9:34 49.8 12.38 122.8 11.02

05/21/2009 9:35 49.7 12.35 103.1 11.04

05/21/2009 9:36 49.6 12.41 97.1 11.03

05/21/2009 9:37 49.9 12.36 109.4 11.02

05/21/2009 9:38 49.8 12.34 105.5 10.98

05/21/2009 9:39 49.1 12.34 99.5 11.04

05/21/2009 9:40 48.8 12.32 98.4 11

05/21/2009 9:41 49.4 12.35 104.2 11.06

05/21/2009 9:42 49.1 12.36 106.4 11.04

05/21/2009 9:43 49.5 12.44 109.7 10.98

05/21/2009 9:44 49.6 12.37 110.4 11.05

05/21/2009 9:45 50.1 12.39 119.5 10.99

05/21/2009 9:46 50.5 12.33 132.7 10.96

05/21/2009 9:47 49.7 12.35 136.7 10.98

05/21/2009 9:48 50.5 12.32 127.2 10.92

05/21/2009 9:49 50.3 12.28 103.3 11.03

05/21/2009 9:50 50.4 12.31 88.4 10.98

05/21/2009 9:51 51.2 12.32 89.3 11.05

05/21/2009 9:52 50.7 12.33 93.1 11.07

05/21/2009 9:53 50.2 12.42 99.5 11.06

05/21/2009 9:54 49.6 12.45 101.9 11

05/21/2009 9:55 50.8 12.39 102.8 10.99

05/21/2009 9:56 51.1 12.33 110.2 10.99

05/21/2009 9:57 51.5 12.31 121.5 10.94

05/21/2009 9:58 51.9 12.33 134.6 10.98

05/21/2009 9:59 52.3 12.38 140 10.99

05/21/2009 10:00 52.3 12.31 125.2 11.03

05/21/2009 10:01 50.9 12.36 97.6 11.03

05/21/2009 10:02 26.4 10.7 28.5 4.35

05/21/2009 10:03 6.8 2.94 28.9 1.54

05/21/2009 10:04 0.5 0.47 92 9.33

05/21/2009 10:05 0.6 0.09 100.6 11.07

05/21/2009 10:06 0.6 0.07 106.1 11.02

05/21/2009 10:07 13.7 0.29 110.4 11.04

05/21/2009 10:08 53.2 7.75 121.4 11

Page 3 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 10:09 52.9 12.33 129.1 11.01

05/21/2009 10:10 52.9 12.56 134.5 10.99

05/21/2009 10:11 52 12.45 121.3 11.01

05/21/2009 10:12 51.1 12.4 116.9 11.1

05/21/2009 10:13 50.3 12.4 99 11.13

05/21/2009 10:14 49 12.43 83.1 11.13

05/21/2009 10:15 48.2 12.41 87.6 11.08

05/21/2009 10:16 47.3 12.38 101.9 11.08

05/21/2009 10:17 46.3 12.38 104.7 11.05

05/21/2009 10:18 46.8 12.39 106.8 11.02

05/21/2009 10:19 47.2 12.34 112 11.08

05/21/2009 10:20 46.7 12.38 114 10.97

05/21/2009 10:21 48 12.35 116.6 11

05/21/2009 10:22 48.5 12.29 120.9 11.02

05/21/2009 10:23 47.8 12.32 129 11.02

05/21/2009 10:24 48.7 12.37 119.1 11.03

05/21/2009 10:25 49.1 12.36 101.3 11.02

05/21/2009 10:26 51.1 12.34 100.7 10.95

05/21/2009 10:27 51.3 12.28 102.1 10.94

05/21/2009 10:28 51.2 12.3 89.7 11.05

05/21/2009 10:29 52.2 12.34 78.7 11.01

05/21/2009 10:30 51.8 12.26 90.5 11.02

05/21/2009 10:31 50.6 12.29 94.6 11.02

05/21/2009 10:32 49.5 12.33 94 10.97

05/21/2009 10:33 50.2 12.27 105.5 11.05

05/21/2009 10:34 49.4 12.29 119.7 11.08

05/21/2009 10:35 48.9 12.35 122.9 11.05

05/21/2009 10:36 47.8 12.39 123.1 11.07

05/21/2009 10:37 47.5 12.38 110.2 10.98

05/21/2009 10:38 48.2 12.33 107.1 10.98

05/21/2009 10:39 48.9 12.29 112.6 10.96

05/21/2009 10:40 49.2 12.29 123.4 10.97

05/21/2009 10:41 49.7 12.31 120 10.99

05/21/2009 10:42 49.8 12.3 101.9 10.96

05/21/2009 10:43 50.5 12.26 90 10.98

05/21/2009 10:44 50 12.26 96.9 11.04

05/21/2009 10:45 48.4 12.38 105.3 11.05

05/21/2009 10:46 49.5 12.41 114.9 11.07

05/21/2009 10:47 49.7 12.38 123.3 11.04

05/21/2009 10:48 49.3 12.42 127.3 11.01

05/21/2009 10:49 49.4 12.37 119 11.04

05/21/2009 10:50 49 12.39 120.3 11.04

05/21/2009 10:51 48.6 12.39 116.5 11.03

Page 4 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 10:52 49.4 12.36 120.5 10.99

05/21/2009 10:53 48.7 12.39 121.1 10.97

05/21/2009 10:54 50 12.36 124.4 10.98

05/21/2009 10:55 51 12.33 121.8 10.91

05/21/2009 10:56 53 12.26 116.5 10.95

05/21/2009 10:57 53.6 12.24 106.2 10.95

05/21/2009 10:58 53.6 12.32 105 10.95

05/21/2009 10:59 53 12.27 104.6 11

05/21/2009 11:00 51.3 12.34 95.4 10.95

05/21/2009 11:01 51.3 12.32 101.7 10.98

05/21/2009 11:02 51.4 12.31 109.3 11.05

05/21/2009 11:03 50.9 12.32 109.7 11.02

05/21/2009 11:04 49.7 12.29 112 10.97

05/21/2009 11:05 49 12.28 117.4 11

05/21/2009 11:06 48.2 12.32 121.3 10.96

05/21/2009 11:07 48.9 12.26 127 10.92

05/21/2009 11:08 48.7 12.23 136.4 10.97

05/21/2009 11:09 47.5 12.29 145.2 10.98

05/21/2009 11:10 47.1 12.31 134.3 10.95

05/21/2009 11:11 48 12.38 118.8 11.02

05/21/2009 11:12 48.5 12.33 103 11.01

05/21/2009 11:13 49.6 12.36 99.9 10.98

05/21/2009 11:14 50.8 12.27 92.9 10.97

05/21/2009 11:15 50.5 12.25 96.2 10.91

05/21/2009 11:16 51.7 12.22 107.2 10.97

05/21/2009 11:17 51.1 12.21 107 10.91

05/21/2009 11:18 50.8 12.27 107 10.93

05/21/2009 11:19 49.8 12.26 124.2 10.98

05/21/2009 11:20 48.9 12.3 132.5 11.03

05/21/2009 11:21 48.4 12.34 131.7 11

05/21/2009 11:22 48.4 12.38 131.6 11.02

05/21/2009 11:23 48 12.38 135.7 11

05/21/2009 11:24 48.5 12.38 120 10.94

05/21/2009 11:25 50.2 12.3 113.7 10.94

05/21/2009 11:26 49 12.28 95.8 11.05

05/21/2009 11:27 48.7 12.35 84.8 11.07

05/21/2009 11:28 48.3 12.36 85.3 11.05

05/21/2009 11:29 48.8 12.34 98.6 11.04

05/21/2009 11:30 49.3 12.31 99.6 11.02

05/21/2009 11:31 50.2 12.37 98.8 11.03

05/21/2009 11:32 51.4 12.36 99.5 10.96

05/21/2009 11:33 51.7 12.31 115 10.94

05/21/2009 11:34 53 12.33 130.6 10.85

Page 5 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 11:35 54.8 12.2 135.8 10.86

05/21/2009 11:36 53.8 12.22 126.6 10.93

05/21/2009 11:37 53.4 12.23 112.6 10.91

05/21/2009 11:38 53 12.16 106.7 10.96

05/21/2009 11:39 51.7 12.23 114.6 11.02

05/21/2009 11:40 50.1 12.3 116.7 11.02

05/21/2009 11:41 50 12.29 115.8 10.97

05/21/2009 11:42 48.9 12.31 115.8 10.99

05/21/2009 11:43 48.1 12.31 134.7 10.85

05/21/2009 11:44 48.1 12.3 142.5 10.86

05/21/2009 11:45 48.2 12.28 118.1 10.91

05/21/2009 11:46 48.5 12.27 104.8 10.96

05/21/2009 11:47 48.5 12.3 101 10.9

05/21/2009 11:48 49.9 12.25 94.3 10.94

05/21/2009 11:49 49.5 12.24 95 10.96

05/21/2009 11:50 48.4 12.27 97.6 11.01

05/21/2009 11:51 47.5 12.33 100.9 11

05/21/2009 11:52 48.1 12.34 107.9 11.01

05/21/2009 11:53 49.4 12.32 108.9 10.95

05/21/2009 11:54 49.6 12.26 112 10.89

05/21/2009 11:55 50.5 12.21 122.5 10.87

05/21/2009 11:56 50.6 12.21 129.6 10.86

05/21/2009 11:57 50.4 12.2 137.2 10.86

05/21/2009 11:58 50.8 12.21 141.9 10.93

05/21/2009 11:59 51.2 12.24 136.2 10.94

05/21/2009 12:00 50.9 12.31 126.4 10.98

05/21/2009 12:01 50.3 12.35 104.9 10.97

05/21/2009 12:02 50.8 12.31 90.7 10.93

05/21/2009 12:03 49.6 12.25 86.3 10.96

05/21/2009 12:04 48.4 12.28 88.9 10.89

05/21/2009 12:05 48.5 12.26 92.6 10.9

05/21/2009 12:06 49.4 12.22 103 10.97

05/21/2009 12:07 48.7 12.29 109.5 10.91

05/21/2009 12:08 49.2 12.33 120.6 10.92

05/21/2009 12:09 48.2 12.27 129.5 10.91

05/21/2009 12:10 48 12.27 138.1 10.85

05/21/2009 12:11 49.1 12.26 132.4 10.91

05/21/2009 12:12 49.4 12.26 122.4 10.9

05/21/2009 12:13 49.4 12.28 104.4 10.95

05/21/2009 12:14 50.8 12.32 87.1 10.95

05/21/2009 12:15 50.1 12.33 89.5 10.91

05/21/2009 12:16 52.3 12.26 88.3 10.9

05/21/2009 12:17 52.6 12.18 92.9 10.82

Page 6 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 12:18 53 12.15 99.8 10.82

05/21/2009 12:19 53 12.18 112.2 10.85

05/21/2009 12:20 52.8 12.2 118.5 10.9

05/21/2009 12:21 52.5 12.26 123.8 10.92

05/21/2009 12:22 52.7 12.3 130.4 10.87

05/21/2009 12:23 52.8 12.26 130.4 10.89

05/21/2009 12:24 51.5 12.27 125.2 10.94

05/21/2009 12:25 50.8 12.27 103.5 11.01

05/21/2009 12:26 49.7 12.32 86.6 11

05/21/2009 12:27 48.3 12.32 83 10.92

05/21/2009 12:28 48.5 12.3 92.1 10.86

05/21/2009 12:29 49 12.3 100.1 10.84

05/21/2009 12:30 50.2 12.26 106.2 10.8

05/21/2009 12:31 51.3 12.2 109.6 10.85

05/21/2009 12:32 52.3 12.19 117.4 10.88

05/21/2009 12:33 52.4 12.18 124.6 10.94

05/21/2009 12:34 51.5 12.29 120.2 10.94

05/21/2009 12:35 52.1 12.31 110.5 10.95

05/21/2009 12:36 52.1 12.33 112.9 11.01

05/21/2009 12:37 50.7 12.33 114.6 10.95

05/21/2009 12:38 49.9 12.33 111.6 10.94

05/21/2009 12:39 49.8 12.33 99.7 10.97

05/21/2009 12:40 49.1 12.31 89 10.97

05/21/2009 12:41 49 12.3 94 10.84

05/21/2009 12:42 50.7 12.25 103.9 10.84

05/21/2009 12:43 51.2 12.21 114.3 10.87

05/21/2009 12:44 50.5 12.22 125.6 10.93

05/21/2009 12:45 50.8 12.29 132.4 10.93

05/21/2009 12:46 51.9 12.32 114.2 10.96

05/21/2009 12:47 51.6 12.31 107.6 10.95

05/21/2009 12:48 52.2 12.35 104.2 10.95

05/21/2009 12:49 52.2 12.33 97.7 10.83

05/21/2009 12:50 53 12.27 106.9 10.85

05/21/2009 12:51 52.8 12.2 116.3 10.88

05/21/2009 12:52 51.7 12.28 127.5 10.8

05/21/2009 12:53 52.8 12.27 134.3 10.77

05/21/2009 12:54 53 12.21 122.4 10.88

05/21/2009 12:55 50.9 12.26 106.2 11.02

05/21/2009 12:56 50 12.35 92.8 10.95

05/21/2009 12:57 50 12.32 86.9 10.91

05/21/2009 12:58 49.8 12.32 87.4 10.87

05/21/2009 12:59 49.6 12.31 90.3 10.97

05/21/2009 13:00 48.4 12.38 104 10.99

Page 7 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 13:01 48.9 12.36 110.4 10.85

05/21/2009 13:02 49.7 12.3 114.2 10.86

05/21/2009 13:03 49.3 12.23 115.5 10.89

05/21/2009 13:04 49.7 12.27 123.2 10.88

05/21/2009 13:05 50.7 12.27 128.4 10.87

05/21/2009 13:06 52.3 12.21 118 10.9

05/21/2009 13:07 51.6 12.26 95.2 10.99

05/21/2009 13:08 51.1 12.35 86.1 10.94

05/21/2009 13:09 50.4 12.4 86 10.9

05/21/2009 13:10 50.3 12.34 95.7 10.89

05/21/2009 13:11 50.6 12.31 105.6 10.82

05/21/2009 13:12 51 12.25 109.8 10.88

05/21/2009 13:13 51 12.22 108.1 10.79

05/21/2009 13:14 51 12.27 115.4 10.86

05/21/2009 13:15 50.8 12.24 125.6 10.82

05/21/2009 13:16 51.5 12.24 129.5 10.85

05/21/2009 13:17 51.1 12.25 135.5 10.91

05/21/2009 13:18 50 12.29 110.9 10.91

05/21/2009 13:19 49.5 12.32 88.6 10.91

05/21/2009 13:20 49.9 12.27 82.9 10.91

05/21/2009 13:21 49.9 12.3 82.6 10.91

05/21/2009 13:22 49.4 12.29 83.8 10.94

05/21/2009 13:23 49 12.33 90.6 10.93

05/21/2009 13:24 48.9 12.33 98.7 10.96

05/21/2009 13:25 47.5 12.35 110.2 10.95

05/21/2009 13:26 47.1 12.39 119.9 10.93

05/21/2009 13:27 47 12.37 125.8 10.95

05/21/2009 13:28 46.8 12.35 131.3 11.01

05/21/2009 13:29 46.6 12.4 126 11.03

05/21/2009 13:30 47.4 12.42 94.4 10.96

05/21/2009 13:31 48.8 12.35 78 10.92

05/21/2009 13:32 49.3 12.25 80.7 10.87

05/21/2009 13:33 49 12.2 81.2 10.88

05/21/2009 13:34 49 12.21 78.2 10.81

05/21/2009 13:35 49.7 12.2 89.9 10.85

05/21/2009 13:36 50.1 12.25 102.2 10.89

05/21/2009 13:37 50.4 12.29 97.9 10.87

05/21/2009 13:38 50.5 12.3 97.3 10.87

05/21/2009 13:39 50 12.31 102.4 10.95

05/21/2009 13:40 49.2 12.32 111.3 10.84

05/21/2009 13:41 49.5 12.3 132.6 10.9

05/21/2009 13:42 49.8 12.28 130.9 10.87

05/21/2009 13:43 51 12.31 99.9 10.9

Page 8 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 13:44 50.8 12.3 83.9 10.96

05/21/2009 13:45 49.8 12.34 85.5 11.01

05/21/2009 13:46 49.7 12.35 89.8 10.9

05/21/2009 13:47 48.9 12.36 103.6 10.94

05/21/2009 13:48 48.6 12.35 111.1 10.92

05/21/2009 13:49 47.8 12.36 114.9 10.93

05/21/2009 13:50 48.9 12.39 115 11.01

05/21/2009 13:51 49.7 12.39 112.2 10.86

05/21/2009 13:52 50.1 12.37 112.7 10.82

05/21/2009 13:53 51.2 12.25 119.1 10.82

05/21/2009 13:54 51.4 12.23 127 10.79

05/21/2009 13:55 52.1 12.23 136.1 10.82

05/21/2009 13:56 53.5 12.27 137.9 10.81

05/21/2009 13:57 53.8 12.29 117.1 10.88

05/21/2009 13:58 53.5 12.32 88.9 10.95

05/21/2009 13:59 53.2 12.38 88.4 10.91

05/21/2009 14:00 52.5 12.37 95.7 10.94

05/21/2009 14:01 50.9 12.35 99.3 10.96

05/21/2009 14:02 50.9 12.35 97.8 10.88

05/21/2009 14:03 51.2 12.29 96.9 10.86

05/21/2009 14:04 50.6 12.25 102.2 10.88

05/21/2009 14:05 50.5 12.28 109.9 10.85

05/21/2009 14:06 49.9 12.28 116.3 10.86

05/21/2009 14:07 50.4 12.23 123.8 10.85

05/21/2009 14:08 51.5 12.23 144.7 10.85

05/21/2009 14:09 50.9 12.27 122.5 10.96

05/21/2009 14:10 50.3 12.38 90.7 10.89

05/21/2009 14:11 50.6 12.31 81.4 10.92

05/21/2009 14:12 50.7 12.29 84.6 10.96

05/21/2009 14:13 49.6 12.3 84.2 10.82

05/21/2009 14:14 50 12.3 82.5 10.83

05/21/2009 14:15 51.8 12.22 92.5 10.74

05/21/2009 14:16 52.7 12.12 101.6 10.83

05/21/2009 14:17 51.6 12.17 112.4 10.85

05/21/2009 14:18 52.1 12.24 116.2 10.82

05/21/2009 14:19 53 12.24 128.4 10.85

05/21/2009 14:20 51.2 12.26 133.3 10.94

05/21/2009 14:21 49.8 12.37 137.5 10.98

05/21/2009 14:22 49.1 12.39 116.6 10.89

05/21/2009 14:23 48.6 12.36 95.4 10.95

05/21/2009 14:24 48.2 12.37 86.8 10.96

05/21/2009 14:25 47.8 12.35 84.8 10.93

05/21/2009 14:26 47.5 12.3 85.1 10.94

Page 9 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 14:27 46.7 12.32 91.2 10.9

05/21/2009 14:28 47.4 12.32 96.3 10.92

05/21/2009 14:29 47 12.3 104.7 10.89

05/21/2009 14:30 47.2 12.32 107.1 10.88

05/21/2009 14:31 47.7 12.28 110.9 10.95

05/21/2009 14:32 48.1 12.3 117.6 11.02

05/21/2009 14:33 47.9 12.36 119.6 10.93

05/21/2009 14:34 49.8 12.33 122.6 10.9

05/21/2009 14:35 49.6 12.34 123 10.85

05/21/2009 14:36 50 12.3 119.7 10.9

05/21/2009 14:37 50.6 12.3 110.6 10.95

05/21/2009 14:38 51 12.35 103.4 10.99

05/21/2009 14:39 50.7 12.37 103.7 10.87

05/21/2009 14:40 52.7 12.35 106.1 10.93

05/21/2009 14:41 51.3 12.31 108.3 10.98

05/21/2009 14:42 51.3 12.39 98.9 11

05/21/2009 14:43 51.5 12.4 80.8 10.95

05/21/2009 14:44 53 12.33 80.9 10.92

05/21/2009 14:45 53.1 12.28 85 10.96

05/21/2009 14:46 53 12.34 90 10.91

05/21/2009 14:47 52.7 12.3 96.2 10.94

05/21/2009 14:48 52.6 12.31 102.7 10.84

05/21/2009 14:49 52.9 12.27 109.3 10.86

05/21/2009 14:50 51.6 12.27 119.9 10.9

05/21/2009 14:51 50.9 12.31 129.9 10.98

05/21/2009 14:52 50.2 12.33 132.9 11.02

05/21/2009 14:53 49.8 12.42 115.6 11.01

05/21/2009 14:54 49.2 12.43 104.5 11.05

05/21/2009 14:55 49 12.43 106 11.03

05/21/2009 14:56 47.7 12.45 109.6 11.09

05/21/2009 14:57 47.4 12.48 111.7 10.95

05/21/2009 14:58 47.7 12.43 117 10.87

05/21/2009 14:59 49.9 12.3 122.3 10.8

05/21/2009 15:00 50.4 12.19 132.1 10.85

05/21/2009 15:01 51.7 12.2 126.4 10.83

05/21/2009 15:02 54 12.22 105.3 10.93

05/21/2009 15:03 54.2 12.26 89.7 10.94

05/21/2009 15:04 54.2 12.25 85.4 10.95

05/21/2009 15:05 53.4 12.31 76.3 10.97

05/21/2009 15:06 52.7 12.3 75.3 10.97

05/21/2009 15:07 51.3 12.38 76.5 10.95

05/21/2009 15:08 51.4 12.37 80.8 10.93

05/21/2009 15:09 50.2 12.33 84.9 10.94

Page 10 of 11
NOx and SO2 DAHS Raw Data

Date Time NOXL4 CO24 SO2_S3 CO2_S3

05/21/2009 15:10 48.8 12.4 92.8 10.94

05/21/2009 15:11 48.9 12.38 108.4 10.97

05/21/2009 15:12 47.7 12.35 115.2 11.11

05/21/2009 15:13 45.9 12.44 107.9 11.12

05/21/2009 15:14 44.8 12.49 107.2 11.07

05/21/2009 15:15 44.8 12.46 120.9 11.01

05/21/2009 15:17 46.1 12.37 88.7 10.93

05/21/2009 15:18 48.2 12.29 88.9 10.91

05/21/2009 15:19 49.8 12.25 91.3 10.97

05/21/2009 15:20 51.4 12.28 83.4 10.95

05/21/2009 15:21 52.6 12.3 89.4 10.94

05/21/2009 15:22 52.8 12.3 94.9 10.95

05/21/2009 15:23 52.8 12.31 97.5 10.98

05/21/2009 15:24 52.2 12.33 91.9 10.99

05/21/2009 15:25 52.8 12.31 102.6 10.92

05/21/2009 15:26 53.6 12.27 105.7 10.87

05/21/2009 15:27 53.9 12.22 109.3 10.88

05/21/2009 15:28 53.5 12.23 111.7 10.9

05/21/2009 15:29 53.4 12.21 123.2 10.86

05/21/2009 15:30 52.5 12.23 119.8 10.87

05/21/2009 15:31 51 12.29 117.6 10.94

05/21/2009 15:32 51.4 12.3 110.9 10.93

05/21/2009 15:33 51.2 12.27 81.2 10.94

05/21/2009 15:34 50.8 12.28 62.5 10.95

05/21/2009 15:35 51.1 12.26 69.5 10.91

05/21/2009 15:36 52.2 12.22 74.8 10.94

05/21/2009 15:37 51.9 12.22 80.4 10.94

05/21/2009 15:38 50.8 12.25 92.2 10.94

05/21/2009 15:39 50.9 12.29 103 10.96

05/21/2009 15:40 50.2 12.32 109.5 10.96

05/21/2009 15:41 49.4 12.37 114.4 10.97

05/21/2009 15:42 49.4 12.36 117.3 10.98

05/21/2009 15:43 48.9 12.35 111.2 10.98

Page 11 of 11
APPENDIX D 

OPERATIONS DATA 
PI Load Data

Plant Information Source: bbnd-1pisrv

Start Time: 05/21/2009 8:00

End Time: 05/21/2009 15:43

Time Interval: 1m

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

Run Average: 441.6058077

21-May-09 08:00:00 441.3484497

21-May-09 08:01:00 442.1470337

21-May-09 08:02:00 442.2201538

21-May-09 08:03:00 442.6086731

21-May-09 08:04:00 443.5735474

21-May-09 08:05:00 443.316925

21-May-09 08:06:00 442.0003357

21-May-09 08:07:00 441.2180786

21-May-09 08:08:00 439.7739868

21-May-09 08:09:00 440.8313293

21-May-09 08:10:00 441.8311462

21-May-09 08:11:00 442.6912842

21-May-09 08:12:00 443.7612305

21-May-09 08:13:00 443.683136

21-May-09 08:14:00 443.9883118

21-May-09 08:15:00 442.9405212

21-May-09 08:16:00 442.3270569

21-May-09 08:17:00 441.2596436

21-May-09 08:18:00 441.0534363

21-May-09 08:19:00 442.0534363

21-May-09 08:20:00 442.8302917

21-May-09 08:21:00 441.8825378

21-May-09 08:22:00 441.0657043

21-May-09 08:23:00 439.5478821

21-May-09 08:24:00 439.4868164

21-May-09 08:25:00 440.0005493

21-May-09 08:26:00 441.8337097

21-May-09 08:27:00 442.4703674

21-May-09 08:28:00 442.6210632

21-May-09 08:29:00 442.8276062

21-May-09 08:30:00 442.3089905

21-May-09 08:31:00 442.5509033

21-May-09 08:32:00 441.7009583

21-May-09 08:33:00 441.4145813

21-May-09 08:34:00 441.6594238

21-May-09 08:35:00 443.0140686

Page 1 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 08:36:00 444.4216919

21-May-09 08:37:00 444.1888428

21-May-09 08:38:00 444.9801636

21-May-09 08:39:00 443.4008179

21-May-09 08:40:00 442.3776245

21-May-09 08:41:00 442.0639954

21-May-09 08:42:00 442.6013184

21-May-09 08:43:00 442.7523193

21-May-09 08:44:00 442.7675781

21-May-09 08:45:00 443.7899475

21-May-09 08:46:00 442.882019

21-May-09 08:47:00 442.95578

21-May-09 08:48:00 442.3097839

21-May-09 08:49:00 440.6479187

21-May-09 08:50:00 440.4558105

21-May-09 08:51:00 441.3942261

21-May-09 08:52:00 440.5916748

21-May-09 08:53:00 440.8940735

21-May-09 08:54:00 441.7871704

21-May-09 08:55:00 441.9177246

21-May-09 08:56:00 442.7553711

21-May-09 08:57:00 443.4120483

21-May-09 08:58:00 443.6861877

21-May-09 08:59:00 443.5646667

21-May-09 09:00:00 442.0809021

21-May-09 09:01:00 439.8606873

21-May-09 09:02:00 439.54245

21-May-09 09:03:00 439.6355896

21-May-09 09:04:00 440.1604309

21-May-09 09:05:00 441.737915

21-May-09 09:06:00 442.4550781

21-May-09 09:07:00 444.1456604

21-May-09 09:08:00 445.4481201

21-May-09 09:09:00 445.5050659

21-May-09 09:10:00 444.8925476

21-May-09 09:11:00 443.5678406

21-May-09 09:12:00 442.6455078

21-May-09 09:13:00 442.055481

21-May-09 09:14:00 442.1560059

21-May-09 09:15:00 440.2982788

21-May-09 09:16:00 441.3341675

21-May-09 09:17:00 442.6631165

21-May-09 09:18:00 441.9446106

21-May-09 09:19:00 442.0198669

21-May-09 09:20:00 443.6613159

Page 2 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 09:21:00 443.7605896

21-May-09 09:22:00 443.0891113

21-May-09 09:23:00 442.6401978

21-May-09 09:24:00 442.8692932

21-May-09 09:25:00 443.5458069

21-May-09 09:26:00 443.0218811

21-May-09 09:27:00 443.2827759

21-May-09 09:28:00 441.3904114

21-May-09 09:29:00 441.0585327

21-May-09 09:30:00 441.72995

21-May-09 09:31:00 442.1555786

21-May-09 09:32:00 442.4585571

21-May-09 09:33:00 441.9461975

21-May-09 09:34:00 441.8492432

21-May-09 09:35:00 441.743103

21-May-09 09:36:00 442.4894409

21-May-09 09:37:00 443.2001953

21-May-09 09:38:00 442.0503845

21-May-09 09:39:00 442.4883118

21-May-09 09:40:00 442.7108154

21-May-09 09:41:00 442.6940918

21-May-09 09:42:00 442.7326965

21-May-09 09:43:00 441.3128357

21-May-09 09:44:00 440.8492737

21-May-09 09:45:00 440.5092163

21-May-09 09:46:00 440.8470764

21-May-09 09:47:00 441.8596497

21-May-09 09:48:00 443.6419373

21-May-09 09:49:00 443.3471375

21-May-09 09:50:00 444.3762207

21-May-09 09:51:00 443.8509521

21-May-09 09:52:00 443.554718

21-May-09 09:53:00 443.0422363

21-May-09 09:54:00 441.4807129

21-May-09 09:55:00 441.2987671

21-May-09 09:56:00 441.440033

21-May-09 09:57:00 442.0067749

21-May-09 09:58:00 442.5539551

21-May-09 09:59:00 442.1159973

21-May-09 10:00:00 441.8138428

21-May-09 10:01:00 442.8445129

21-May-09 10:02:00 442.9263916

21-May-09 10:03:00 442.9659424

21-May-09 10:04:00 442.7772827

21-May-09 10:05:00 442.3642883

Page 3 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 10:06:00 440.8868713

21-May-09 10:07:00 440.0628662

21-May-09 10:08:00 440.4731445

21-May-09 10:09:00 440.8102112

21-May-09 10:10:00 442.1495667

21-May-09 10:11:00 442.3555603

21-May-09 10:12:00 442.8424072

21-May-09 10:13:00 443.4101563

21-May-09 10:14:00 442.9845886

21-May-09 10:15:00 442.9186401

21-May-09 10:16:00 443.5179749

21-May-09 10:17:00 441.6231384

21-May-09 10:18:00 440.8895264

21-May-09 10:19:00 440.890686

21-May-09 10:20:00 440.9755554

21-May-09 10:21:00 441.6052246

21-May-09 10:22:00 441.644928

21-May-09 10:23:00 442.2487488

21-May-09 10:24:00 442.6262207

21-May-09 10:25:00 443.5635986

21-May-09 10:26:00 443.7840881

21-May-09 10:27:00 443.6678772

21-May-09 10:28:00 442.6725159

21-May-09 10:29:00 441.4628906

21-May-09 10:30:00 441.5689392

21-May-09 10:31:00 441.4485779

21-May-09 10:32:00 442.2986755

21-May-09 10:33:00 442.0184021

21-May-09 10:34:00 442.920166

21-May-09 10:35:00 443.0847778

21-May-09 10:36:00 443.8547974

21-May-09 10:37:00 442.23349

21-May-09 10:38:00 441.3763733

21-May-09 10:39:00 441.2053833

21-May-09 10:40:00 440.3790283

21-May-09 10:41:00 441.491333

21-May-09 10:42:00 442.8070679

21-May-09 10:43:00 443.7145081

21-May-09 10:44:00 443.8128052

21-May-09 10:45:00 443.9549561

21-May-09 10:46:00 442.0995483

21-May-09 10:47:00 441.0323792

21-May-09 10:48:00 441.4909058

21-May-09 10:49:00 441.6219788

21-May-09 10:50:00 441.8672791

Page 4 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 10:51:00 441.541748

21-May-09 10:52:00 442.0046082

21-May-09 10:53:00 443.3245239

21-May-09 10:54:00 442.8285828

21-May-09 10:55:00 442.848938

21-May-09 10:56:00 443.6434631

21-May-09 10:57:00 443.5458069

21-May-09 10:58:00 441.2781372

21-May-09 10:59:00 441.4552917

21-May-09 11:00:00 440.3585205

21-May-09 11:01:00 440.3786621

21-May-09 11:02:00 440.6682129

21-May-09 11:03:00 440.2955627

21-May-09 11:04:00 442.0007935

21-May-09 11:05:00 444.0406189

21-May-09 11:06:00 444.1815796

21-May-09 11:07:00 443.3703003

21-May-09 11:08:00 441.9579468

21-May-09 11:09:00 441.4848938

21-May-09 11:10:00 442.4943848

21-May-09 11:11:00 442.4558411

21-May-09 11:12:00 442.7557373

21-May-09 11:13:00 442.4866333

21-May-09 11:14:00 441.6841736

21-May-09 11:15:00 442.3566589

21-May-09 11:16:00 442.5960388

21-May-09 11:17:00 442.8388672

21-May-09 11:18:00 442.1419373

21-May-09 11:19:00 441.6187134

21-May-09 11:20:00 441.383728

21-May-09 11:21:00 441.7659912

21-May-09 11:22:00 441.0127563

21-May-09 11:23:00 441.9824829

21-May-09 11:24:00 441.9256897

21-May-09 11:25:00 443.1329041

21-May-09 11:26:00 444.1804504

21-May-09 11:27:00 444.0575562

21-May-09 11:28:00 442.920166

21-May-09 11:29:00 441.4247437

21-May-09 11:30:00 440.5825806

21-May-09 11:31:00 440.5834351

21-May-09 11:32:00 441.1500854

21-May-09 11:33:00 441.8723755

21-May-09 11:34:00 442.0452881

21-May-09 11:35:00 441.3244934

Page 5 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 11:36:00 441.8672791

21-May-09 11:37:00 442.8096313

21-May-09 11:38:00 443.1795654

21-May-09 11:39:00 444.1307068

21-May-09 11:40:00 442.5162354

21-May-09 11:41:00 442.348877

21-May-09 11:42:00 443.8052063

21-May-09 11:43:00 442.5430908

21-May-09 11:44:00 441.6412659

21-May-09 11:45:00 441.8452454

21-May-09 11:46:00 440.1964111

21-May-09 11:47:00 439.8051147

21-May-09 11:48:00 439.8500061

21-May-09 11:49:00 439.9970093

21-May-09 11:50:00 440.6792297

21-May-09 11:51:00 441.8014832

21-May-09 11:52:00 441.0737915

21-May-09 11:53:00 441.4661865

21-May-09 11:54:00 441.8053589

21-May-09 11:55:00 442.6577148

21-May-09 11:56:00 442.9546204

21-May-09 11:57:00 442.6874695

21-May-09 11:58:00 442.8312988

21-May-09 11:59:00 443.0574951

21-May-09 12:00:00 442.4776611

21-May-09 12:01:00 442.1560364

21-May-09 12:02:00 441.4425049

21-May-09 12:03:00 441.2436829

21-May-09 12:04:00 441.6459961

21-May-09 12:05:00 440.5532837

21-May-09 12:06:00 440.1013184

21-May-09 12:07:00 441.6261902

21-May-09 12:08:00 441.3230286

21-May-09 12:09:00 441.6622009

21-May-09 12:10:00 442.5943298

21-May-09 12:11:00 443.493927

21-May-09 12:12:00 441.4094849

21-May-09 12:13:00 442.9037476

21-May-09 12:14:00 442.5661621

21-May-09 12:15:00 442.2029724

21-May-09 12:16:00 441.5203552

21-May-09 12:17:00 442.0046082

21-May-09 12:18:00 443.3397827

21-May-09 12:19:00 444.6444702

21-May-09 12:20:00 443.7110901

Page 6 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 12:21:00 442.8743896

21-May-09 12:22:00 443.5714722

21-May-09 12:23:00 442.5059814

21-May-09 12:24:00 441.1152039

21-May-09 12:25:00 439.4868164

21-May-09 12:26:00 438.4007568

21-May-09 12:27:00 439.4552917

21-May-09 12:28:00 439.801178

21-May-09 12:29:00 439.5455017

21-May-09 12:30:00 440.0337524

21-May-09 12:31:00 442.2090149

21-May-09 12:32:00 442.7675781

21-May-09 12:33:00 442.4559326

21-May-09 12:34:00 441.1299744

21-May-09 12:35:00 439.6394348

21-May-09 12:36:00 438.5906067

21-May-09 12:37:00 439.3756104

21-May-09 12:38:00 439.6484985

21-May-09 12:39:00 440.3366699

21-May-09 12:40:00 441.8418579

21-May-09 12:41:00 441.8379822

21-May-09 12:42:00 441.9417725

21-May-09 12:43:00 441.665863

21-May-09 12:44:00 442.6363525

21-May-09 12:45:00 442.8591309

21-May-09 12:46:00 440.8296509

21-May-09 12:47:00 440.2816772

21-May-09 12:48:00 440.6835327

21-May-09 12:49:00 441.1233826

21-May-09 12:50:00 442.0503845

21-May-09 12:51:00 441.8596191

21-May-09 12:52:00 441.8123474

21-May-09 12:53:00 441.9958801

21-May-09 12:54:00 441.4842529

21-May-09 12:55:00 441.3331909

21-May-09 12:56:00 440.1953735

21-May-09 12:57:00 439.0104675

21-May-09 12:58:00 437.956543

21-May-09 12:59:00 439.1551208

21-May-09 13:00:00 441.0758667

21-May-09 13:01:00 440.5865173

21-May-09 13:02:00 440.6141357

21-May-09 13:03:00 440.0558167

21-May-09 13:04:00 440.4786682

21-May-09 13:05:00 440.788208

Page 7 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 13:06:00 439.4455566

21-May-09 13:07:00 437.8917847

21-May-09 13:08:00 436.1297913

21-May-09 13:09:00 434.9243164

21-May-09 13:10:00 437.1882935

21-May-09 13:11:00 437.6499939

21-May-09 13:12:00 437.9573059

21-May-09 13:13:00 438.2874451

21-May-09 13:14:00 439.5478821

21-May-09 13:15:00 440.0276794

21-May-09 13:16:00 439.8750916

21-May-09 13:17:00 440.9974976

21-May-09 13:18:00 440.9822388

21-May-09 13:19:00 439.735199

21-May-09 13:20:00 438.7879333

21-May-09 13:21:00 438.6255798

21-May-09 13:22:00 438.9146118

21-May-09 13:23:00 438.2221069

21-May-09 13:24:00 439.18927

21-May-09 13:25:00 439.4776611

21-May-09 13:26:00 441.397644

21-May-09 13:27:00 441.7968445

21-May-09 13:28:00 441.9995117

21-May-09 13:29:00 441.7561035

21-May-09 13:30:00 440.7304688

21-May-09 13:31:00 441.1439819

21-May-09 13:32:00 440.5804138

21-May-09 13:33:00 438.3932495

21-May-09 13:34:00 437.7540588

21-May-09 13:35:00 440.0309143

21-May-09 13:36:00 441.5580444

21-May-09 13:37:00 442.4465942

21-May-09 13:38:00 442.5539246

21-May-09 13:39:00 441.5867615

21-May-09 13:40:00 441.0236511

21-May-09 13:41:00 439.9319458

21-May-09 13:42:00 438.9527588

21-May-09 13:43:00 439.3460999

21-May-09 13:44:00 439.4372559

21-May-09 13:45:00 440.9110413

21-May-09 13:46:00 440.5397339

21-May-09 13:47:00 440.7075806

21-May-09 13:48:00 441.2967224

21-May-09 13:49:00 441.3026733

21-May-09 13:50:00 441.6853943

Page 8 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 13:51:00 441.75354

21-May-09 13:52:00 441.855835

21-May-09 13:53:00 441.7658386

21-May-09 13:54:00 440.3951416

21-May-09 13:55:00 440.5236511

21-May-09 13:56:00 440.8847351

21-May-09 13:57:00 441.0137634

21-May-09 13:58:00 441.7095947

21-May-09 13:59:00 443.4618835

21-May-09 14:00:00 443.3204346

21-May-09 14:01:00 442.2060242

21-May-09 14:02:00 440.5168152

21-May-09 14:03:00 439.2833557

21-May-09 14:04:00 439.4427795

21-May-09 14:05:00 440.1124573

21-May-09 14:06:00 439.5733032

21-May-09 14:07:00 439.904541

21-May-09 14:08:00 441.7146912

21-May-09 14:09:00 441.6994324

21-May-09 14:10:00 441.3918152

21-May-09 14:11:00 439.7102966

21-May-09 14:12:00 440.1904907

21-May-09 14:13:00 440.2093811

21-May-09 14:14:00 440.4176636

21-May-09 14:15:00 441.2111206

21-May-09 14:16:00 442.0836792

21-May-09 14:17:00 441.5401306

21-May-09 14:18:00 441.5647888

21-May-09 14:19:00 441.5987244

21-May-09 14:20:00 442.0773926

21-May-09 14:21:00 441.0266418

21-May-09 14:22:00 440.1086426

21-May-09 14:23:00 439.9801941

21-May-09 14:24:00 437.9107971

21-May-09 14:25:00 438.8789063

21-May-09 14:26:00 439.4508972

21-May-09 14:27:00 440.104126

21-May-09 14:28:00 440.9269409

21-May-09 14:29:00 441.2168579

21-May-09 14:30:00 440.3464355

21-May-09 14:31:00 439.517334

21-May-09 14:32:00 438.4072266

21-May-09 14:33:00 439.2175293

21-May-09 14:34:00 439.2503052

21-May-09 14:35:00 439.5393677

21-May-09 14:36:00 441.2111206

21-May-09 14:37:00 441.734314

21-May-09 14:38:00 441.8936462

Page 9 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 14:39:00 441.6917725

21-May-09 14:40:00 441.6646729

21-May-09 14:41:00 441.0608826

21-May-09 14:42:00 441.6078491

21-May-09 14:43:00 440.9090881

21-May-09 14:44:00 440.7413025

21-May-09 14:45:00 438.9947205

21-May-09 14:46:00 439.5106506

21-May-09 14:47:00 439.1594238

21-May-09 14:48:00 439.980835

21-May-09 14:49:00 441.0196838

21-May-09 14:50:00 443.1276855

21-May-09 14:51:00 441.8062439

21-May-09 14:52:00 442.2168274

21-May-09 14:53:00 441.7029419

21-May-09 14:54:00 440.8946533

21-May-09 14:55:00 440.4786682

21-May-09 14:56:00 440.5282593

21-May-09 14:57:00 440.2399902

21-May-09 14:58:00 440.2026367

21-May-09 14:59:00 440.4407959

21-May-09 15:00:00 441.0343018

21-May-09 15:01:00 441.9232178

21-May-09 15:02:00 441.8492432

21-May-09 15:03:00 441.8999634

21-May-09 15:04:00 441.085907

21-May-09 15:05:00 440.4695129

21-May-09 15:06:00 441.0432739

21-May-09 15:07:00 438.8917236

21-May-09 15:08:00 439.7462463

21-May-09 15:09:00 439.602356

21-May-09 15:10:00 440.4176331

21-May-09 15:11:00 441.4858093

21-May-09 15:12:00 442.8896484

21-May-09 15:13:00 443.3733521

21-May-09 15:14:00 442.609436

21-May-09 15:15:00 441.4766235

21-May-09 15:16:00 441.20401

21-May-09 15:17:00 440.7838745

21-May-09 15:18:00 440.8082886

21-May-09 15:19:00 440.8230591

21-May-09 15:20:00 440.2965698

21-May-09 15:21:00 440.6465454

21-May-09 15:22:00 442.0402222

21-May-09 15:23:00 443.5471191

21-May-09 15:24:00 444.196228

21-May-09 15:25:00 442.7691956

21-May-09 15:26:00 441.4781494

Page 10 of 11
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

21-May-09 15:27:00 440.4164734

21-May-09 15:28:00 441.0222778

21-May-09 15:29:00 440.9517212

21-May-09 15:30:00 441.7923584

21-May-09 15:31:00 441.0432739

21-May-09 15:32:00 441.5010376

21-May-09 15:33:00 442.2655334

21-May-09 15:34:00 442.3968201

21-May-09 15:35:00 441.5315552

21-May-09 15:36:00 440.5397034

21-May-09 15:37:00 439.9064636

21-May-09 15:38:00 440.0209045

21-May-09 15:39:00 440.1382751

21-May-09 15:40:00 439.7333984

21-May-09 15:41:00 440.1399231

21-May-09 15:42:00 440.7398071

21-May-09 15:43:00 441.0982056

Page 11 of 11




APPENDIX E 

FUEL INFORMATION 
E-1 

BUNKERING INFORMATION 
Time Fuel Tons Blended Percent Blended (%) Total Fuel Bunkered (tons)

05/20/2009 11:40 Petcoke 233.7 15.85

05/20/2009 11:40 Standard 371.3 25.19

05/20/2009 11:40 Standard L 869.0 58.96

05/20/2009 17:02 Petcoke 148.1 15.19

05/20/2009 17:02 Standard 279.1 28.62

05/20/2009 17:02 Standard L 547.9 56.19

05/20/2009 21:15 Petcoke 132.5 15.21

05/20/2009 21:15 Standard 255.8 29.37

05/20/2009 21:15 Standard L 482.8 55.42

05/21/2009 1:01 Petcoke 114.5 15.09

05/21/2009 1:01 Standard 213.9 28.18

05/21/2009 1:01 Standard L 430.6 56.73

05/21/2009 4:53 Petcoke 85.9 15.34

05/21/2009 4:53 Standard 156.2 27.89

05/21/2009 4:53 Standard L 318.0 56.78

05/21/2009 11:35 Petcoke 217.7 15.51

05/21/2009 11:35 Standard 385.5 27.46

05/21/2009 11:35 Standard L 800.8 57.04

05/21/2009 17:24 Petcoke 153.8 14.83

05/21/2009 17:24 Standard 313.1 30.19

05/21/2009 17:24 Standard L 570.1 54.98

05/21/2009 21:16 Petcoke 84.8 15.11

05/21/2009 21:16 Standard 167.0 29.76

05/21/2009 21:16 Standard L 309.3 55.12

1171.0 Total Petcoke 456.3

2141.9 Total Standard 865.6

4328.5 Total Standard L 1680.2

7641.4 Total Fuel 3002.1

15.3 Total % Petcoke Blended 15.2

28.0 Total % Standard Blended 28.8

Total % Standard L Blended 56.6 Total % Standard L Blended 56.0

BB4 PM Stack Test Bunkered Fuels 5/21/09

1474.0

975.1

871.1

759.0

560.1

Total % Standard Blended

Total Petcoke

Total Standard

Total Fuel

Total % Petcoke Blended

Total Standard L

Total Bunkered Before Test and During Test Total Bunkered During Test

1404.0

1037.0

561.1
E-2 

FUEL ANALYSIS 
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Report For:

Laboratory ID: AB01114

Date and Time Collected:

Sampled By:

Sample Information

Description: F.WADE

Location Code:

Report Date: 06/29/09

Big Bend 4 Compliance

TE_BB_4_COMP_COAL

Project Account Code:

Sample Collection Method: Date of Sample Receipt: 06/01/09

Laboratory Results

05/21/09 3:00:00 PM

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 5.84 06/10/09 9:36:00 AM

Ash, as Determined % 0.01 ASTM D-5142 KAPXJ 9.55 06/10/09 9:36:00 AM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 8.64 06/10/09 2:17:00 PM

Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 10.14 06/10/09 2:14:00 PM

BTU in Coal, as Determined BTU/Lb. 1 ASTM D-5865 KAPXJ 12096 06/04/09 9:11:00 AM

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 10946 06/10/09 2:17:00 PM

BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 12846 06/10/09 2:10:00 PM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14296 06/10/09 2:14:00 PM

Carbon, as Received % ASTM D-5373 PENDING

Carbon, Dry Basis % ASTM D-5373 PENDING

Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.09 06/18/09 2:57:00 PM

Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.1 06/18/09 2:57:00 PM

HHV (BTU/Lb) Calculated (Mason) BTU/Lb Mason Calc. PENDING

Hydrogen, as Received % ASTM D-5373 PENDING

Hydrogen, Dry Basis % ASTM D-5373 PENDING

Nitrogen, as Received % ASTM D-5373 PENDING

Nitrogen, Dry Basis % ASTM D-5373 PENDING

NOx emission rate, lb/mmBtu lb/mmBtu EPA RM-7E KAMCR 0.09 06/23/09 12:56:00 PM

NOx emission rate, lbs/hr lbs/hr EPA RM-7E KAMCR 372 06/23/09 12:56:00 PM

Oxygen, as Received % ASTM D-5373 PENDING

Oxygen, Dry Basis % Calculated PENDING

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 16.9 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 14.2 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 10.05 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 6.55 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 4.45 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 2.95 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Total Sample, Run 1 mg 0.0001 23.45 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Report Number: Page 1 of 2 "General Report" AB01114-062909-10
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

Particulate Wt., Total Sample, Run 2 mg 0.0001 18.65 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

Particulate Wt., Total Sample, Run 3 mg 0.0001 13.00 06/23/09 12:56:00 PM EPA Method 5B/17 KAMCR

PM, lb/mmBtu lb/mmBtu EPA RM-5/17 KAMCR 0.01 06/23/09 12:56:00 PM

Pounds SO2 / Million BTU Lbs. 

SO2/MMBTU

4.67 06/10/09 12:11:00 PM Calculated KAPXJ

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KAMCR 1251 06/23/09 12:56:00 PM

SO2 emission rate, lbs/mmBtu lbs/mmBtu EPA - RM6C KAMCR 0.30 06/23/09 12:56:00 PM

Sulfur in Coal, as Determined % 0.01 ASTM D-4239 KAEMD 2.97 06/09/09 3:14:00 PM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 2.68 06/10/09 2:17:00 PM

Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.15 06/10/09 2:10:00 PM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 14.79 06/10/09 2:16:00 PM

Comments

Designee for Peggy Penner,

Manager, Laboratory Services

All results calculated on a wet to wet basis, unless otherwise indicated.

Should there be any questions regarding this report, please contact:

(813) 630-7490

Ellen Demers,

Report Number: Page 2 of 2 "General Report" AB01114-062909-10
APPENDIX F 

TEST PARTICIPANTS 
TEST PARTICIPANTS

ENVIRONMENTAL, HEALTH, & SAFETY 

AIR SERVICES GROUP – TEST TEAM

Scott Given Environmental Technician – Test Team Lead 

Ryan Newell Environmental Technician 

RM-320 FTIR

Gary Barber Environmental Technician 

PROCESS DATA

Adam Ballans Associate Engineer – Big Bend Station 

R.A. McDarby Senior Environmental Technician 

FUEL ANALYSIS

Patrice Jackson Environmental Technician 

Ellen Demers Environmental Technician 

PARTICULATE LABORATORY

Sam Soth Environmental Technician 

SUPPORTING DATA COLLECTION AND ANALYSIS

R.A. McDarby Senior Environmental Technician 

PROJECT QUALITY OBJECTIVES & REPORTING

R.A. McDarby Senior Environmental Technician 

Robert J. Kricks, Ph.D. Principal – RJK Consulting (Spectra & Method) 

TEST COORDINATION

Adam Ballans Associate Engineer – Big Bend Station 

David A. Smith Coordinator – Air Services Group