Final Test Report for Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility Based on information and belief formed after reasonable inquiry,

I certify that the statements and information

in this test report are true, accurate, and complete. Permitted Facility Representative Name: Title: Company: Sign Date: Connie O'Neal EHS Administrator Florim USA Monday, June 20, 2011
Date 6/20/2011

I have reviewed
all testing details and results
in this test report and hereby certify that the test report
is authentic and accurate. Name: Title: Company: Sign Date: Troy Burrows Corporate Quality Manager Entec Services, Inc. 6/20/2011 Page

1 of 39

### Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility Facility Information: !Florim USA 1 300 International Blvd.



# _ ==:]

I 6/20/2011 

### Testing Company: En
t ec Services, Inc

. 1 3 0 Monroe Dr

. ! clarksville



### -- 

# J

I Pelham

JI AL
IJ 35124



# I Con Pho Fax Em tact: ne: Connie O'Neal 931-553-7510

Contact:

II- J _ s _ u _ tt _ on ___________



# ---11 Phone:

2 05-358-101



# i Fax:

1 205-358-1036



# I ail: cjames@florimusa

. com

Email: 

## sutton@entecservices.com



# J - lndustry/SCC/NAIS



## f._ __ ___

__, AFS#:

FRS#: Air Permit Number: Permitted Source 10/Name: 1 562538

llr- F - lo - n - . m - U - SA - , I - n - c. ---

-

- Permitted Maximum Process Rate: Max. Normal Operation Process Rate: Target Process Test Rate 

# L

I SCC

I Description

l 30500812

J 

### Indu stria

l Processes -Mineral Products

- Ceramic Clay/Tile Manufacture

- Glazing and firing kiln**
(u se sees 3-05-008-45

& 

### -50
) The following state and federal regulations that apply to the proposed testing: Description

of the source (including control equipment). Please see the attachments
for source or process flow diagram: Spray Dryer No.2- SACMI Model ATM052, Control Equipment- Venturi Wet Scrubber Vertical Dryer No.

1 - EVA Model 984, no control device Glaze Line (GL-1)- Control Equipment -Eurofilter Dust Collector Glaze Line (GL- 3, 4, 5)- Control Equipment- Venturi Wet Scrubber Roller Kiln No. 1 - SACMI Model JMS223, Control Equipment- Eurofilter Dry Sorbent Injection Baghouse Sampling Location Information: Round D uct Rect.Duct 

### Equiv.
Di s t a n ce
- from Distance

fr om Num
b er of **Min Trave~:s**  

### L oc a tio n Diaru. Le n g t b JW idth Di am

u ps t te am dl st.

d o wnst

r eam
d is t. 

### Traverse
Po r ts

P o in t s 

### Glaze Line

j 

### 35.5

0

0

()


### 384

168

2

24 (GL- 3, 4, 5) Glaze Line 41.5

0



### 0

0
240

114

2

20 (GL -1)

-

-

-



### - 

### Roller Kiln 43.25

0

0

0

86

. 5

216

2

24 No.1 May Spray Dryer

44

0

0

0

84

110

2

24 No.2 Vertical Dryer

19

0

0

0

39 

# -f=J

,o,

2

24 No.

I



### - 

### Roller Kiln #I 

### 43.25

0



### 0

0 86.5

2

24 October ------- --

-



### - --- 

### Monday, June 20, 2011

Page

2 of 39Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Test Parameter Information: Target

Test Num.ber
of Tesl:Ruo SampJe Location Parameter Method TestRWis Duratio11 Polnt3 CQmtnents - Glaze Line Selenium
Method 29

3 240

0 (GL-
3, 4, 5) Glaze Line Arsenic
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Antimony
Method 29

3 240

0 (GL- 3, 4, 5 ) Glaze Line Beryllium
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Cadmium
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Chromium
Method 29

3 240

0 (GL- 3, 4, 5)

- - Glaze Line Cobalt
Method 29

3 240

0 (GL-

3 , 4, 5) Glaze Line Lead
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Manganese
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Nickel
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Mercury
Method 29

3 240

0 (GL- 3, 4, 5) Glaze Line Filterable Particulate Method

5

3 240

0 (GL- 3, 4, 5)

- Glaze Line !Nickel
Method 29

3 240

0 (GL

- 1) Glaze Line Mercury
Method 29

3 240

0 (GL -1) Glaze Line Lead
Method 29

3 240

0 (GL -1)

-

- Glaze Line Chromium
Method 29

3 240

0 (GL -1) Glaze Line Manganes

e Method 29

3 240

0 (GL -1)

-

-

I Glaze Line Cobalt
Method 29

3 240

0 ( GL -1) **~**

--- Glaze Line Cadmium
Method 29

3 240

0 (GL-1) Gla z e Line Arsenic
Method 29

3 240

0 (GL -1) Glaze Line Antimony
Method 29

3 240

0 (GL -1)

- Glaze Line Beryllium
Method 29

3 240

0 (GL -1)

- Gla z e Line Selenium
Method 29

3 240

0 ( G L-1

)

1- Glaze Line Filterable

P a rticul

a te Method

5

3 240

0 ( GL -1)

-- - - - -'--
----
1- -- Roller Kiln
#
l 2,3,7,8-TCDD
Method
23

3 240

0 October

I Roller Kiln #I

1 ,2,3, 7 ,8-PeCDD Method
23

3 240
1
0 October

-- --
--

-

-

-- Monday, June 20, 2011

Page

3 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacilityRollerKiln#I1,2,3,4,7,8-HxCDDOctoberRollerKiln#I1,2,3,6,7,8-HxCDDOctoberRollerKiln#11,2,3,7,8,9-HxCDDOctoberRollerKiln#11,2,3,4,6,7,8-HpCDDOctoberRollerKiln#1OCDDOctoberRollerKiln#I2,3,7,8-TCDFOctoberRollerKiln#11,2,3,7,8-PeCDFOctoberRollerKiln#12,3,4,7,8-PeCDFOctoberRollerKiln#1I,2,3,4,7,8-HxCDFOctoberRollerKiln#I1,2,3,6,7,8-HxCDFOctoberRollerKiln#12,3,4,6,7,8-HxCDFOctoberRollerKiln#I1,2,3,7,8,9-HxCDFOctoberRollerKiln#I1,2,3,4,6,7,8-HpCDFOctoberRollerKiln#11,2,3,4,7,8,9-HpCDFOctoberRollerKiln#1OCDFOctoberRollerKiln#1TotalDioxinsOctoberRollerKiln#1frotalFuransOctoberRollerKiln2,3,7,8-TCDDNo.1MayRollerKilnI,2,3,7,8-PeCDDNo.1MayRollerKilnNo.IMayRollerKilnNo.1MayRollerKilnNo.IMayRollerKilnNo.1MayRollerKilnNo.1MayRollerKilnNo.IMayRollerKilnNo.IMayRollerKiln1,2,3,4,7,8-HxCDD1,2,3,6,7,8-HxCDD1,2,3,7,8,9-HxCDD1,2,3,4,6,7,8-HpCDDOCDD2,3,7,8-TCDF1,2,3,7,8-PeCDF2,3,4,7,8-PeCDFNo.lMayRollerKilnNo.IMayt------I,2,3,4,7,8-HxCDFMonday,June20,20116/20/2011Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400Method2332400--1---+-------Method2332400Method2332400Method23L-+--2-4_0_-+__o___,___Method23--32400-Page4of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011RollerKiln1,2,3,6,7,8-HxCDFMethod2332400No.1MayRollerKiln2,3,4,6,7,8-HxCDFMethod2332400No.1MayRollerKiln1,2,3,7,8,9-HxCDFMethod23I32400No.1MayIl--RollerKiln1,2,3,4,6,7,8-HpCDFMethod2332400No.1May--RollerKiln1,2,3,4,7,8,9-HpCDFMethod2332400No.1MayRollerKilnOCDFMethod2332400No.1May--RollerKilnTotalDioxinsMethod2332400No.1MayRollerKilnTotalFuransMethod2332400No.1MayRollerKilnNickelMethod293240I0No.1MayRollerKilnMercuryMethod2932400No.1MayRollerKilnAntimonyMethod2932400No.1MayRollerKilnArsenicMethod2932400No.1May-RollerKilnBerylliumMethod2932400No.IMay--RollerKilnCadmiumMethod2932400No.1MayRollerKilnChromiumMethod2932400No.1MayRollerKilnCobaltMethod2932400No.1MayRollerKilnManganeseMethod2932400No.1MayRollerKilnSeleniumMethod2932400No.1May-RollerKilnLeadMethod 2932400No.1MayRollerKilnFilterableParticulateMethod532400No.IMaySprayDryer2,3,7,8-TCDDMethod2332400No.2SprayDryer1,2,3,7,8-PeCDDMethod2332400No.2--- -SprayD1yer1,2,3,4,7,8-HxCDDMethod2332400No.2SprayDryer1,2,3,6,7,8-HxCDDMethod2332400No.2SprayD1yer1,2,3,7,8,9-HxCDDMethod2332400No.21---SprayD1yer1,2,3,4,6,7,8-HpCDDMethod2332400No.2·-SprayD1yerOCDDMethod2332400No.2SprayD1yer2,3,7,8-TCDFMethod2332400No.21---'--------Monday,June20,2011Page5of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011SprayDryer1,2,3,7,8-PeCDFMethod2332400No.2SprayDryer2,3,4,7,8-PeCDFMethod23f----32400No.2SprayDryer1,2,3,4,7,8-HxCDFMethod2332400No.2>----SprayDryer1,2,3,6,7,8-HxCDFMethod2332400No.2-SprayDryer2,3,4,6,7,8-HxCDFMethod2332400No.2SprayDryer1,2,3,7,8,9-HxCDFMethod2332400No.2-SprayDryer1,2,3,4,6,7,8-HpCDFMethod2332400No.2SprayDryer1,2,3,4,7,8,9-HpCDFMethod2332400jNo.2SprayDryerOCDFMethod2332400No.2--SprayDryerTotalDioxinsMethod2332400No.2SprayDtyerTotalFuransMethod2332400No.2VerticalDryer2,3,7,8-TCDDMethod2332400No.1VerticalDryer1,2,3,7,8-PeCDDMethod2332400No.1VerticalDryer1,2,3,4,7,8-HxCDDMethod2332400No.1VerticalDryer1,2,3,6,7,8-HxCDDMethod2332400No.1VerticalDryer1,2,3,7,8,9-HxCDDMethod2332400No.1VerticalDryer1,2,3,4,6,7,8-HpCDDMethod2332400No.1VerticalDtyerOCDDMethod2332400No.1VerticalDryer2,3,7,8-TCDFMethod2332400No.IVerticalDryer1,2,3,7,8-PeCDFMethod23I32400No.1VerticalDryer2,3,4,7,8-PeCDFMethod2332400No.1VetiicalDryer1,2,3,4,7,8-HxCDFMethod2332400No.l-VerticalDryer1,2,3,6,7,8-HxCDFMethod2332400No.1--VetiicalDryer2,3,4,6,7,8-HxCDFMethod2332400No.lVerticalDryerI,2,3,7,8,9-HxCDFMethod2332400No.IVerticalDtyerl,2,3,4,6,7,8-HpCDFMethod2332400No.IVerticalDryer1,2,3,4,7,8,9-HpCDFMethod2332400No.1-VetiicalDtyerOCDFMethod2332400No.1l---------------Monday,June20,2011Page6of39Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Vertical Dryer Total Dioxins Method
23

3 240

0 No.1 r--

. 1 V ertlca Dryer Total Furans Method
23

3 240

0 No.1 The following describes any modifications and/or deviations

to the applicable test methods.

If alternative methods were requested, see the attachments
for documentation of request AND approval, including dates. =-

-- -- ----

- ----- ___ _j Monday, June 20, 2011

Page

7 of 39

# Tile MACT ICR Request

- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 

# Sampling



# I Stack Data Results Summary Location 

# Glaze Line (GL-
3, 4, 5)- Method
29 Run Number Test Date Run Start Time Run Finish Time Net Run Time, minutes Dry Gas MeterVo1ume Sampled, dscf Moisture Content
of Stack Gas, % Moisture Saturation

at Stack Gas Temperature,

% Carbon Dioxide,

% Oxygen,% Average Stack Gas Temperature,



# op Dry Volumetric Flow Rate, dry scfrn Actual Wet Volumetric Flue Gas Flow Rate, acfrn Percent Isokinetic
of Sampling Rate, % F-Factor, dscfrn/MMBtu@ %02 Fw Fe 

# Monday, June 20, 2011 6/20/2011 M29-1 5/24/2010 11:35:00 

# AM 3:40:00 PM 240 160.202 2.99 5.22 0 20.8 93.33 12,736.3 13,631.1 101.6 0 0 0



# Avera

e M29-2 M29-3 5/25/2010 5/25/2010 8:26:00 1:49:00PM 

# AM 12:36:00 5:55:00 PM PM 240
240 163.773 160.427 161.467 2.71 2.99 2.897 4.31 4.97 4.833 0

0 0.000 20.8
20.8 20.800 87.04 91.63 90.667 12,953.9 12,793.7 12,827.967 13,726.0 13,709.5 13,688.867 102.1 101.3 101.667 0

0 0.000 0

0 0.000 0

0 0.000 

# Page

8 of 39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Location Glaze Line (GL -1)- Method 29



# Avera

e Run Number

M29-l M29-2 M29-3 Test Date

5/26/2010 5/26/2010 5/27/2010 Run Start Time

9:22:00 AM 2:18:00 7:55:00AM PM Run Finish Time

1:33:00 PM 6:28:00 12:15:00 PM PM Net Run Time, minutes

240
240
240 Dry Gas Meter Volume Sampled, dscf

147

. 329 153.752 157.914 152.998 Moisture Content of Stack Gas, %

2.56 2.29
2.22 2.357 Moisture Saturation

at Stack Gas Temperature,

%

6.58 6.39
5.97 6.313 Carbon Dioxide,

%

0

0

0

0

. 000 Oxygen,%

20.8 20.8
20.8 20.800 Average Stack Gas Temperature,

°F

100.75 99.80 97.55 99.367 Dry Volumetric Flow Rate, dry scfin
10,147.6 10,599.9 10,865.2 10,537

. 567 Actual Wet Volumetric Flue Gas Flow Rate, acfin 11,012.4 11,451.9 11,683.0 11,382.433 Percent Isokinetic
of Sampling Rate, %

103.7
103

. 6 103.8
103

. 700 F-Factor, dscfm/MMBtu@ %02

0

0

0 0.000 Fw

0

0

0 0.000 Fe

0

0

0 0.000 

# Monday, June 20, 2011

Page

9 of 39Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 Location Roller Kiln #1 October- Method
23

Avera

e Run Number

M23-1 M23-2 M23-3 Test Date

10/1112010 10/1112010 10/12/2010 Run Start Time
8:08:00AM 12:23:00 7:47:00AM PM Run Finish Time

12:11:00 PM 5:25:00 11:49:00 PM
AM Net Run Time, minutes

240
240
240 Dry Gas Meter Volume Sampled, dscf
196.040 198.180 200.079 198.100 Moisture Content of Stack Gas, %

6.47 6.09 6.56 6.373 Moisture Saturation

at Stack Gas Temperature,

% 100.00 100.00 100.00 100.000 Carbon Dioxide,

%

3

3

3 3.000 Oxygen,%

18.3 18.4
18.2 18.300 Average Stack Gas Temperature,

°F

279.50 281.42 281.88 280.933 Dry Volumetric Flow Rate, dry scfin
15,556.9 15,818.0 15,974.2 15,783.033 Actual Wet Volumetric Flue Gas Flow Rate, acfin 23,603.3 23,964.5 24,337.9 23,968.567 Percent Isokinetic
of Sampling Rate, %

100.9 100.3 100.3 100.500 F-Factor, dscfin/MMBtu@ %02

0

0

0 0.000 Fw

0

0

0 0.000 Fe

0

0

0 0.000 ------- Monday, June 20, 2011

Page 10 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011---LocationRollerKilnNo.1May-Method23Avera'eRunNumberM23-lM23-2 M23-3TestDate5/25/20105/25/20105/26/2010RunStartTime8:10:00AM4:25:007:57:00AMPMRunFinishTime12:14:00PM8:31:0012:08:00PMPMNetRunTime,minutes240240240DryGasMeterVolumeSampled,dscf202.228198.290205.746202.088MoistureContentofStackGas,%6.146.737.426.763Moisture SaturationatStackGasTemperature,%100.00100.00100.00100.000CarbonDioxide,%2.52.52.52.500Oxygen,%19.119.319.319.233AverageStackGasTemperature,°F265.00267.67265.92266.197DryVolumetricFlowRate,dryscfin16,185.716,241.516,668.316,365.167ActualWetVolumetricFlueGasFlowRate,acfin23,560.523,878.824,637.824,025.700PercentIsokineticofSamplingRate,%100.097.798.898.833F-Factor,dscfin/MMBtu@%020000.000Fw0000.000Fe0000.000Monday,June20,2011Page11of39

### Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Location 

### Roller Kiln No.
1 

### May- Method 29

Avera

e Run Number

M29-l M29-2 M29-3 Test Date

5/25/2010 5/25/2010 5/26/2010 Run Start Time

10

: 18:00 4:29:00 7:58:00AM 

### AM
PM Run Finish Time

2

: 25

: 00 PM 8:31

: 00 12

: 08:00 PM PM Net Run Time, minutes

240
240
240 Dry Gas Meter Volume Sampled, dscf
124.257 122.389 127.604 124.750 Moisture Content of Stack Gas, %

6.13 6.98 7.56 6.890 Moisture Saturation

at Stack Gas Temperature,

% 100.00 100.00 100.00 100.000 Carbon Dioxide,

%

2.5

2.5

2.5 2.500 Oxygen,%

19.1

19

. 3

19

. 3 19.233 Average Stack Gas Temperature,

oF

265.38 266.42
269

. 17 266.990 Dry Volumetric Flow Rate, dry scfrn

15,657

. 8 15,473.0 15,972.1 15,700

. 967 Actual Wet Volumetric Flue Gas Flow Rate, acfrn 22,801.5 22,770

. 9
23

, 750.3 23,107.567 Percent Isokinetic
of Sampling Rate, %

99.0

98

. 6 99.6 99.067 F-Factor, dscfrniMMBtu@ %02

0

0

0 0.000 Fw

0

0

0 0.000 Fe

0

0

0 0.000 

### Monday, June 20, 2011

Page 12 of 39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Location 

# Spray Dryer No.
2 -Method
23

Ave.-a

e Run Number

M23-l M23-2 M23-3 Test Date

10/12/2010 10/12/2010 10/13/2010 Run Start Time
8:07:00AM

I :16:00 8:16:00 AM PM Run Finish Time
12:11:00PM 5:43:00 12:18:00 PM PM Net Run Time, minutes

240
240
240 Dry Gas Meter Volume Sampled, dscf
152.146 130.996 131.978 138.373 Moisture Content of Stack Gas, %

23.11 22.98 21.47 22.520 Moisture Saturation

at Stack Gas Temperature,

%
22.41 21.30 21.02 21.577 Carbon Dioxide,

%

3

3

2.5 2.833 Oxygen,%

18.3 18.5
18.3 18.367 Average Stack Gas Temperature,

oF

144.71 142.71 142.33 143.250 Dry Volumetric Flow Rate, dry scfm
15,580.5 16,370.0 16,381.3 16,110.600 Actual Wet Volumetric Flue Gas Flow Rate, acfm 23,301.6 24,049.2 23,884.5 23,745.100 Percent Isokinetic
of Sampling Rate, %

104.2 103.3 104.0 103.833 F-Factor, dscfm!MMBtu@ %02

0

0

0 0.000 Fw

0

0

0 0.000 Fe

0

0

0 0.000 

# l

_j Monday, June 20, 2011

Page 13 of 39

### Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 

## ----- Location Vertical Dryer No. 1 - Method
23

A vera

e Run Number

M23-l M23-2 M23-3 Test Date

10/13/2010 10/14/2010 10/14/2010 Run Start Time

2:58:00 PM 9:40:00

2

: 56

: 00 PM 

### AM Run Finish Time

7

: 08

: 00 PM

1 : 52

: 00

7

: 04

: 00 PM PM Net Run Time

, minutes

240
240
240 Dry Gas Meter Volume Sampled, dscf
172.081 178.973

175

. 714 175.589 Moisture Content of Stack Gas, %

9.26 4.60 6.87 6.910 Moisture Saturation

at Stack Gas Temperature,

% 100.00 100.00 100.00 100.000 Carbon Dioxide,

%

2

2

2 2.000 Oxygen,%

19

19

19 19.000 Average Stack Gas T e mperature,

° F

237.71 239.58 238.04 238.443 Dry Volumetric Flow Rate

, dry scfin
4,127.5 4,433.7 4,277.8 4,279

. 667 Actual Wet Volumetric Flue Gas Flow Rate, actin 6,059.4 6,151.5 6,066.5 6,092.467 Percent Isokinetic
of Sampling Rate, %

100.3

97

. 2 98.9 98.800 F-Factor, dscfin/MMBtu@ %02

0

0

0 0.000 Fw

0

0

0 0.000 Fe

0

0

0 0.000 

### Monday, June 20, 2011

Page 14 of 39

### Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Emissions Summary 

### Location: Glaze Line (GL

- 3, 4, 5)
- Method
29



# l Compound: Antimony



### Averal!e RunNumber

M29-3
M29-l M29-2 Mass_mg
0.000757

0

. 00145 0.00608

0.003 Eglhr

3

. 62E

- 03

6
. 92E-03

2

. 89E-02

0

. 013 mg/dscm
1.67E-04

3

. 20E-04 1.31E-03

0.001 mg/dscm@7%02

2

. 32E-02 4.45E-02 1.82E-OI

0

. 083 

### Compound: Arsenic



### Averal!e Run Number

M29-2 M29-3
M29-1 Mass_mg

0.0012 0.0012

0

. 00187
0.001 Eg/hr
5.69E-03

5

. 74E-03 8.92E-03

0

. 007 mg/dscm
2.59E-04

2

. 64E-04

4

. 12E-04

0

. 000 mg/dscm@7%02

3

. 60E-02

3

. 67E-02

5

. 73E-02
0.043 

### Compound: Beryllium



### Averal!e RunNumber

M29-2 M29-3
M29-1 Mass_mg

0.0003 0.0003 0.0003
0.000 Eg/hr
1.42E-03 1.44E-03 1.43E-03

0.001 mg/dscm
6.47E-05

6

. 60E-05

6

. 61E-05
0.000 mg/dscm@7%02
8.99E-03 9.17E-03

9

. 19E-03

0

. 009 

### Compound: Cadmium



### Averal!e RunNumber

M29-2
M29-3
M29-1 Mass_mg

0

. 00015

0

. 00015

0

. 000298
0.000 Eglhr

7

. 12E-04 7.18E-04 1.42E-03

0

. 001 mg/ d scm 3.23E-05 3.30E-05

6

. 57E-05
0.000 m g/ d sc m @ 7%02

4.4 9E

- 03 4.59E-03 9.13E-03

0.006 

### Compound: Chromium



### Averal!e Run Number

M29

- 2 M29-3
M29-l Mass_mg

0.345

0.15
0.154
0.216 Eg/hr
1.64E+OO 7.18E-0

1 7.35E-OI

1.031 mg/dscm
7.44E-02 3.30E-02 3.40E-02

0.047 mg/ d scm@7%02

1. 03E+OI 4.59E+OO 4.73E+OO

6

. 540 

### Compound: Cobalt



### Ave ra !!e Run Number

M29-2

M29

- 3 M29-1 Mass_mg

0.0147

0

. 0147 0.0175
0.016 Eg/h

r 6.98E-02 7.03E-02

8

. 35E-02

O.D75 mg/d

s cm 3.17E-03

3

. 24E-03

3

. 86E-03

0

. 003 **dscm 02**  4.41E-Ol 4.50E-Ol

5

. 37E-01
0.476 

### Compo

u nd

: Lead



### Avera!!e ---- --- 

### Monday, June 20

, 2011

Page 15 of 39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 RunNumber

M29-2 M29-3
M29-1 Mass_mg

0.00513 0.00362 0.0172
0.009 Eg/hr
2.43E-02 1.73E-02 8.20E-02

0.041 mg/dscm
l.llE-03 7.97E-04 3.79E-03

0.002 **m~dscm@7%02**


# 1.54E-01 1.11E-01 5.27E-01

0.264 

# Compound: Manganese

Avera!!e RunNumber

M29-2 M29-3
M29-1 Mass_mg

0.528
0.223

1.294
0.682 Eg/hr

2

. 51E+OO 1.07E+OO 6.17E+OO

3.250 mg/dscm
1.14E-01 4.91E-02 2.85E-01

0.149 mg/dscm @7%02 1.58E+01 6.82E+OO 3.96E+01
20.740 

# Compound: Mercury

Avera!!e RunNumber

M29-3
M29-1 M29-2 Mass_mg
0.000706

0

. 000329 0.000375

0.000 Eg/hr
3.38E-03 1.57E-03 1.78E-03

0.002 mg/dscm
1.55E-04

7

. 25E-05 8.09E-05

0

. 000 **m~dscm @7%02**  

# 2.15E-02 l.OlE-02 1.12E-02

0.014 

# Compound: Nickel

Avera!!e RunNumber

M29-3
M29-1 M29-2 Mass_mg

0.00817 0.00629 0.0109

0

. 008 Eg/hr
3.91E-02

3

. 00E-02 5.17E-02

0

. 040 mg/dscm
1.80E-03 1.39E-03 2.35E-03

0.002 mg/dscm @7% 02 2.50E-01 1.93E-01 3.27E-Ol

0.257 

# Compound: Selenium

Avera!!e RunNumber

M29-3
M29-1 M29-2 Mass_mg

0.00311 0.00385 0.00302

0.003 Eg/hr
1.49E-02 1.84E-02 1.43E-02

0.016 mg/dscm
6.85E-04 8.49E-04 6.51E-04

0.001 mg/dscm@7%02

9

. 52E-02 1.18E-01

9 .0 5E-02

0.101 

# Location: Glaze Line (GL -1)- 

# Method 29 Compound: Antimony

Avera!!e RunNumber

M29-1 M29-2 M29-3 Mass_mg

0.0003
0.0003 0.0003
0.000 Eg/hr
1.24E-03 1.24E-03 1.24E-03

0.001 mg/dscm
7.19E-05 6.89E-05 6.71E-05

0.000 mg/dscm@7%02
9.99E-03 9.58E-03 9.33E-03

0.010 

# Compound: Arsenic

Avera!!e 

# l Run Number

M29-1 M29-2 M29-3 Mass_mg

0.0012 0.0012 0.0012

0.001 Eg/hr
4.96E-03 4.96E-03 4.95E-03

0.005 mg/dscm
2.88E-04 2.76E-04 2.68E-04

0.000

J 

# Monday, June 20,2011

Page 16 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011mg/dscm@7%024.00E-023.84E-023.73E-020.039Compmmd:BerylliumAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.00030.00030.00030.000Eg!hr1.24E-031.24E-031.24E-030.001mg/dscm7.19E-056.89E-056.71E-050.000mg/dscm@7%029.99E-039.58E-039.33E-030.010Compound:CadmiumAveral!eRunNumberM29-lM29-2M29-3Mass_mg0.000150.000150.0001930.000Eg!hr6.20E-046.20E-047.97E-040.001mg/dscm3.60E-053.45E-054.32E-050.0005.00E-034.80E-036.00E-030.005Compound:ChromiumAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.002810.002780.001910.003Eglhr1.16E-021.15E-027.89E-030.010mg/dscm6.74E-046.39E-044.27E-040.001mg/dscm@7%029.37E-028.88E-025.94E-020.081Compound:CobaltAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.00030.00030.001020.001Eglhr1.24E-031.24E-034.21E-030.002mg/dscm7.19E-056.89E-052.28E-040.000mg/dscm@7%029.99E-039.58E-033.17E-020.017Compound:LeadAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.001470.0009860.0006740.001Eglhr6.07E-034.08E-032.78E-030.004mg/dscm3.52E-042.27E-041.51E-040.000mg/dscm@7%024.89E-023.16E-022.10E-020.034Compound:ManganeseAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.004190.02040.00540.010Eg/hr1.73E-028.44E-022.23E-020.041mg/dscml.OOE-034.69E-031.21E-030.002mg/dscm@7%021.39E-Ol6.52E-011.68E-Ol0.320Compound:MercuryAveral!eRunNumberM29-JM29-2M29-3Mass_mg0.0006310.0006810.0005260.001Monday,June20,2011Page17of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011------Eglhr2.61E-032.82E-032.17E-030.003mg/dscm1.51E-041.56E-041.18E-040.000mg/dscm@7%022.10E-022.17E-021.64E-020.020Compound:NickelAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.001440.00170.005940.003Eglhr5.95E-037.03E-032.45E-020.012mg/dscm3.45E-043.91E-041.33E-030.001mg/dscm@7%024.80E-025.43E-021.85E-010.096Compound:SeleniumAveral!eRunNumberM29-1M29-2M29-3Mass_mg0.0030.003060.0030.003Eglhr1.24E-021.27E-021.24E-020.013mg/dscm7.19E-047.03E-046.71E-040.001mg/dscm@7%029.99E-029.77E-029.33E-020.097Location:RollerKiln#1October-Method23Compound:1,2,3,4,6,7,8-HpCDDAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.000005780.000005930.00001010.000Eglhr2.75E-052.84E-054.84E-050.000ng/dscm1.04E+OO1.06E+OO1.78E+OO1.293ng/dscm@7%025.56E+OO5.89E+OO9.16E+OO6.870Compound:1,2,3,4,6,7,8-HpCDFAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.000000008120.000000006310.0000000080.000Eglhr3.87E-083.02E-083.83E-080.000ng/dscm1.46E-031.12E-031.41E-030.001ng/dscm@7%027.81E-036.23E-037.26E-030.007Compound:1,2,3,4,7,8,9-HpCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000004440.000000004990.000000007360.000Eg/hr2.11E-082.39E-083.53E-080.000ng/dscm8.00E-048.89E-041.30E-030.001ng/dscm@7%024.28E-034.94E-036.69E-030.005Compound:1,2,3,4,7,8-HxCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.0000005550.0000006160.000000780.000Eg/hr2.64E-062.95E-063.74E-060.000ng/dscml.OOE-011.1OE-011.38E-010.116ng/dscm@7%025.35E-016.l2E-017.10E-010.619Monday,June20,2011Page18of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011Compound:1,2,3,4,7,8-HxCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000005320.000000004840.000000008620.000Eg/hr2.53E-082.32E-084.13E-080.000ng/dscm9.58E-048.63E-041.52E-030.001ng/dscm@7%025.12E-034.80E-037.83E-030.006Compound:1,2,3,6,7,8-HxCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.0000008050.0000008390.000001140.000Eg/hr3.83E-064.02E-065.46E-060.000ng/dscm1.45E-011.50E-012.01E-OI0.165ng/dscm@7%027.75E-018.34E-011.03E+OO0.880Compound:1,2,3,6,7,8-HxCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000004960.000000005280.000000005780.000Eg/hr2.36E-082.53E-082.77E-080.000ng/dscm8.94E-049.41E-041.02E-030.0014.78E-035.23E-035.25E-030.005Compound:1,2,3,7,8,9-HxCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000001680.000001870.000002530.000Eg/hr8.00E-068.96E-061.21E-050.000ng/dscm3.03E-013.33E-014.47E-010.361ng/dscm@7%021.62E+OO1.85E+OO2.30E+OO1.923Compound:1,2,3,7,8,9-HxCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000001480.000000001310.000000003270.000Eg/hr7.05E-096.27E-091.57E-080.000ng/dscm2.67E-042.33E-045.77E-040.0001.43E-031.30E-032.97E-030.002Compound:1,2,3,7,8-PeCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000001630.000001730.000002110.000Eg/hr7.76E-068.28E-061.01E-050.000ng/dscm2.94E-013.08E-OI3.72E-010.325ng/dscm@7%021.57E+OO1.71E+OO1.92E+OO1.733Compound:1,2,3,7,8-PeCDFAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.000000006390.000000006430.000000006920.000Eg/hr3.04E-083.08E-083.31E-080.000Monday,June20,2011Page19of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011ng/dscm1.15E-031.15E-031.22E-030.001ng/dscm@7%026.15E-036.39E-036.28E-030.006Compound:2,3,4,6,7,8-HxCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000004160.000000004360.000000005940.000Eg!hr1.98E-082.09E-082.85E-080.000ng/dscm7.49E-047.77E-041.05E-030.001ng/dscm@7%024.00E-034.32E-035.41E-030.005Compound:2,3,4,7,8-PeCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000008010.000000007050.000000002770.000Eg!hr3.81E-083.38E-081.33E-080.000ng/dscm1.44E-031.26E-034.89E-040.001ng/dscm@7%027.70E-037.01E-032.52E-030.006Compound:2,3,7,8-TCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000001160.000001220.000001340.000Eg!hr5.52E-065.84E-066.42E-060.000ng/dscm2.09E-012.17E-012.37E-010.221ng/dscm@7%021.12E+OO1.21E+OO1.22E+OO1.183Compound:2,3,7,8-TCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.00000001390.00000001340.00000001350.000Eg!hr6.62E-086.42E-086.47E-080.000ng/dscm2.50E-032.39E-032.38E-030.002ng/dscm@7%021.34E-021.33E-021.23E-020.013Compound:OCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.00004320.00004180.00009030.000Eg!hr2.06E-042.00E-044.33E-040.000ng/dscm7.78E+OO7.45E+OO1.59E+Ol10.377ng/dscm@7%024.16E+Ol4.14E+Ol8.19E+Ol54.967Compound:OCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.00000001470.00000001270.00000002260.000Eg!hr7.00E-086.08E-081.08E-070.000ng/dscm2.65E-032.26E-033.99E-030.003ng/dscm@7%021.42E-021.26E-022.05E-020.016Compound:TotalDioxinsAvern•e•RunNumberM23-1M23-2M23-3---------Monday,June20,2011Page20of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011Mass_mg0.000054810.0000540050.00010830.000Eglhr2.61E-042.59E-045.19E-040.000ng/dscm9.87E+OO9.62E+OO1.91E+OI12.8635.28E+OI5.35E+019.83E+0168.200Compound:TotalFuransAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.00000007150.00000006670.00000008480.000Eglhr3.40E-073.19E-074.06E-070.000ng/dscm1.29E-021.19E-02l.SOE-020.013ng/dscm@7%026.90E-026.62E-027.72E-020.071Location:RollerKilnNo.1May-Method23Compound:1,2,3,4,6,7,8-HpCDDAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.000007910.000006730.000006680.000Eglhr3.80E-053.31E-053.25E-050.000ng/dscm1.38E+OO1.20E+OOl.l5E+OO1.243ng/dscm@7%021.07E+011.04E+019.99E+OO10.363Compound:1,2,3,4,6,7,8-HpCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000009650.0000000190.00000000890.000Eglhr4.63E-089.34E-084.33E-080.000ng/dscm1.69E-033.38E-03l.53E-030.002ng/dscm@7%021.31E-022.94E-02l.33E-020.019Compound:1,2,3,4,7,8,9-HpCDFAvera!!eRunNumberM23-lM23-2M23-3Mass_mg0.00000000360.00000000440.00000000680.000Eg/hr1.73E-082.16E-083.31E-080.000ng/dscm6.29E-047.84E-041.17E-030.001ng/dscm@7%024.86E-036.81E-031.02E-020.007Compound:1,2,3,4,7,8-HxCDDAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.0000004010.0000005070.0000004480.000Eglhr1.93E-062.49E-062.18E-060.000ng/dscm7.00E-029.03E-027.69E-020.079ng/dscm@7%025.41E-017.84E-016.68E-Ol0.664Compound:1,2,3,4,7,8-HxCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000003920.00000000480.000000004950.000Eglhr1.88E-082.36E-082.41E-080.000ng/dscm6.85E-048.55E-048.50E-040.001ng/dscm@7%025.29E-037.43E-037.38E-030.007Monday,June20,2011Page21of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011Compound:1,2,3,6,7,8-FixC:l)l)AverageRunNumberM23-1M23-2M23-3Mass_mg0.0000009350.000001010.0000008850.000Eg/hr4.49E-064.96E-064.30E-060.000ng/dscm1.63E-01l.80E-011.52E-Ol0.1651.26E+OO1.56E+OO1.32E+OO1.380Compound:1,2,3,6,7,8-FixC:l)FAverageRunNumberM23-1M23-2M23-3Mass_mg0.00000000630.000000007170.000000006540.000Eg/hr3.03E-083.52E-083.18E-080.000ng/dscm1.10E-031.28E-031.12E-030.001ng/dscm@7%028.49E-031.11E-029.73E-030.010Compound:1,2,3,7,8,9-FixC:l)l)AverageRunNumberM23-1M23-2M23-3Mass_mg0.000001640.000001780.000001610.000Eg/hr7.88E-068.75E-067.83E-060.000ng/dscm2.86E-013.17E-012.76E-010.293ng/dscm@7%022.21E+OO2.75E+OO2.40E+OO2.453Compound:1,2,3,7,8,9-HxC:l)FAverageRunNumberM23-1M23-2M23-3Mass_mg0.00000000330.0000000050.000000004870.000Eg/hr1.58E-082.46E-082.37E-080.000ng/dscm5.76E-048.91E-048.36E-040.001ng/dscm@7%024.45E-037.74E-037.26E-030.006Compound:1,2,3,7,8-PeC:l)l)AverageRunNumberM23-1M23-2M23-3Mass_mg0.000001440.00000150.000001410.000Eg/hr6.92E-067.37E-066.85E-060.000ng/dscm2.52E-012.67E-Ol2.42E-010.254ng/dscm@7%021.95E+OO2.32E+OO2.10E+OO2.123Compound:1,2,3,7,8-PeC:l)FAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000007710.00000000580.00000000720.000Eg/hr3.70E-082.85E-083.50E-080.000ng/dscm1.35E-031.03E-031.24E-030.001ng/dscm@7%021.04E-028.95E-03l.08E-020.010Compound:2,3,4,6,7,8-HxC:l)FAverageRunNumberM23-1M23-2M23-3Mass_mg0.00000000420.00000000460.000000004530.000Eg/hr2.02E-082.26E-082.20E-080.000---------Monday,June20,2011Page22of39

# Tile MACT ICR Request· Site Specific Test Plan Florim USA

· Clarksville, Tennessee Facility 6/20/2011 ng/dscm
7.34E-04 8.19E-04 7.78E-04



# 0. 001 

# 1 ng/dscm@7%02

5

. 67E-03 7.12E-03

6

. 76E-03
0.007 

# Compound: 2,3,4,

7 ,8-PeCDF

Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.0000000069 0.00000000934 0.0000000092

0.000 Eg/hr
3.31E-08 4.59E-08 4.47E-08

0.000 ng/dscm
1.21E-03 1.66E-03 1.58E-03

0.001 ng/dscm@7%02
9.34E-03 1.44E-02 1.37E-02

0.012 

# Compound: 2,3,7,8-TCDD

Averal!e RunNumber

M23-l M23-2 M23-3 Mass_mg 0.00000106 0.00000125 0.00000124

0.000 Eglhr
5.09E-06 6.14E-06 6.03E-06

0.000 ng/dscm
1.85E-Ol 2.23E-01 2.13E-Ol

0.207 ng/dscm@7%02
1.43E+OO 1.94E+OO 1.85E+OO

1.740 

# Compound: 2,3,7,8-TCDF

Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.00000000848 0.00000000834

0

. 00000000965

0.000 Eg/hr
4.07E-08 4.10E-08 4.69E-08

0.000 ng/dscm
1.48E-03 1.49E-03 1.66E-03

0.002 ng/dscm@7%02
1.14E-02

1 . 29E-02 1.44E-02

0.013 

# Compound: OCDD

Averal!e RunNumber

M23-l M23-2 M23-3 Mass_mg 0.0000684 0.0000712 0.0000635

0.000 Eg/hr
3.28E-04 3.50E-04 3.09E-04

0.000 ng/dscm
1.19E+Ol

1 .2 7E+Ol 1.09E+Ol
11.833 ng / d sc m @7%02 9.19E+Ol 1.10E+02 9.47E+Ol
98.867 

# Compound: OCDF

Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.000000011 0.000000048 0.0000000207

0.000 Eg/hr
5.28E-08 2.36E-07 l.OIE-07

0

. 000 ng/dscm
1.92E-03 8.55E-03 3.55E-03

0.005 ng/dscm@7%02
1.48E-02 7.43E-02 3.08E-02

0.040 

# Compound: Total Dioxins

Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.000081786 0.000083977 0.000075773

0.000 Eglhr
3.93E-04 4.13E-04 3.68E-04

0.000 ng/dscm
1.43E+01 1.50E+01 1.30E+Ol
14.100 ng/dscm@7%02

1 . 10E+02 1.30E+02 1.13E+02 117.667 

# Compound: Total Furans

Averal!e RunNumber

M23-l
M23-2 M23-3 

# -----
---- ---- -- 

# Monday, June 20, 2011

Page 23 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011Mass_mg0.00000006510.00000011650.00000008330.000Eg!hr3.13E-075.73E-074.05E-070.000ng/dscml.l4E-022.08E-021.43E-020.016ng/dscm@7%028.80E-021.81E-011.24E-010.131Location:RollerKilnNo.1May-Method29Compound:AntimonyAvera!!:eRunNumberM29-1M29-2M29-3Mass_mg0.001520.001310.001430.001Eg!hrl.l5E-029.94E-031.07E-020.011mg/dscm4.32E-043.78E-043.96E-040.000mg/dscm@7%023.34E-033.28E-033.44E-030.003Compound:ArsenicAvera!!:eRunNumberM29-1M29-2M29-3Mass_mg0.007930.01790.014110.013Eg!hr6.00E-021.36E-011.06E-010.101mg/dscm2.25E-035.17E-033.91E-030.004mg/dscm@7%021.74E-024.49E-023.40E-020.032Compound:BerylliumAvera!!:eRunNumberM29-1M29-2M29-3Mass_mg0.00030.00030.00030.000Eg!hr2.27E-032.28E-032.25E-030.002mg/dscm8.53E-058.66E-058.30E-050.000mg/dscm@7%026.59E-047.52E-047.21E-040.001Compound:CadmiumAvera!!:eRunNumberM29-1M29-2M29-3Mass_mg0.001550.00060.00090.001Eg!hr1.17E-024.55E-036.76E-030.008mg/dscm4.41E-041.73E-042.49E-040.000mg/dscm@7%023.41E-031.50E-032.16E-030.002Compound:ChromiumAvera!!eRunNumberM29-1M29-2M29-3Mass_mg0.022490.019040.03810.027Eg/hr1.70E-011.44E-012.86E-010.200mg/dscm6.39E-035.49E-031.05E-020.007mg/dscm@7%024.93E-024.77E-029.12E-020.063Compound:CobaltAvera!!eRunNumberM29-1M29-2M29-3Mass_mg0.000510.000980.000850.001Eg/hr3.86E-037.43E-036.38E-030.006mg/dscm1.45E-042.83E-042.35E-040.000mg/dscm@7%021.12E-032.46E-032.04E-030.002Monday,June20,2011Page24of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacilityCompound:LeadRunNumberM29-1Mass_mg0.00767Eg!hr5.80E-02mg/dscm2.18E-03mg/dscm@7%021.68E-02Compound:ManganeseRunNumberM29-1Mass_mg0.01105Eg!hr8.35E-02mg/dscm3.14E-03mg/dscm@7%022.42E-02Compound:MercuryRunNumberM29-1Mass_mg0.08986Eg!hr6.79E-01mg/dscm2.55E-02mg/dscm@7%021.97E-01Compound:NickelRunNumberM29-1Mass_mg0.00531Eg/hr4.01E-02mg/dscm1.51E-03mg/dscm@7%021.17E-02Compound:SeleniumRunNumberM29-1Mass_mg0.04062Eglhr3.07E-01mg/dscml.l5E-02mg/dscm@7%028.88E-02Location:SprayDryerNo.2-Method23Compound:1,2,3,4,6,7,8-HpCDDRunNumberM23-lMass_mg0.0000148Eglhr9.09E-05ng/dscm3.44E+OOng/dscm@7%021.84E+01Compound:1,2,3,4,6,7,8-HpCDFRunNumberMass_mgMonday,June20,2011M23-10.000000003626/20/2011M29-20.006885.22E-021.99E-031.73E-02M29-20.03542.69E-011.02E-028.86E-02M29-20.126689.61E-013.66E-023.18E-01M29-20.002762.09E-027.97E-046.92E-03M29-20.059634.52E-011.72E-021.49E-01M23-20.00001098.17E-052.94E+OO1.70E+01M23-20.00000000355M29-30.015091.13E-014.18E-033.63E-02M29-30.032572.45E-019.02E-037.84E-02M29-30.146411.10E+OO4.05E-023.52E-01M29-30.007425.57E-022.05E-031.78E-02M29-30.078635.91E-012.18E-021.89E-01M23-30.00001239.\6E-053.29E+OO1.76E+01M23-30.00000000396lAverage0.0100.0740.0030.023Average0.0260.1990.0070.064Average0.1210.9130.0340.289Average0.0050.0390.0010.012Average0.0600.4500.0170.142Average0.0000.0003.22317.667Avera!!e0.000Page25of39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility Eglhr

2

. 22E-08 ng/dscm
8.40E-04 ng/dscm@7%02
4.49E-03 

# Compound:

1 

# ,2,3,4,

7 ,8,9-HpCDF RunNumber

M23-l Mass_mg

0. 00000000367 Eglhr
2.25E-08 ng/dscm
8.52E-04 ng / dscm @ 7%02 4.55E-03 

# Compound: 

# 1,2,3,4,7,8-HxCDD RunNumber

M23-l Mass_mg 0.000000605 Eglhr
3.72E-06 ng/dscm
1.40E-01 ng/dscm@7%02
7.48E-Ol 

# Compound: 

# 1,2,3,4,7,8-HxCDF RunNumber

M23-l Mass_mg

0. 00000000141 Eglhr
8.66E-09 ng/dscm
3.27E-04 ngldscm

@ 7%02 1.75E-03 

# Compound: 

# 1,2,3,6,7,8-HxCDD RunNumber

M23-1 Mass_mg

0

. 000000981 Eg/hr
6.03E-06 ng/dscm
2.28E-01 ng/dscm

@ 7%02 1.22E+OO 

# Compound:

1 

# ,2,3,6,7,8-HxCDF RunNumber

M23-l Mass_mg

0. 00000000139 Eglhr
8.54E-09 ng/dscm
3.23E-04 n g/ dscm @ 7%02 1.73E-03 

# Compound:



# 1 ,2,3,7,8,9-HxCDD Run Number

M23-l Mass_mg 0.0000024 Eglhr
1.47E-05 ng/dscm
5.57E-01 ng/dscm@7%02
2.98E+OO 

# Compound:

1 

# ,2,3,7 ,8,9-HxCDF 

# Monday, June 20, 2011 6/20/2011

2

. 66E-08 9.57E-04 5.54E-03 M23-2 0.00000000577

4

. 33E-08 1 . 56E-03 9

. 04E-03 M23-2 0.000000461 3.46E-06 1.24E-01 7.18E-01 M23-2 0.00000000259 1.94E-08 6

. 98E-04 4.04E-03 M23-2 0

. 000000719 5

. 39E-06 1.94E-01 1.12E+OO M23-2 0.00000000241 1.81 E-08 6

. 50E-04 3.76E-03 M23-2 0.00000179 1.34E-05 4.83E-OI 2

. 80E+OO 2.95E-08 1.06E-03 5.67E-03 M23-3 0.00000000285 2.12E-08 7.63E-04 4.08E-03 M23-3 0

. 000000387 2.88E-06 1.04E-01 5.56E-Ol M23-3 0.00000000473 3.52E-08 1.27E-03 6

. 79E-03 M23-3 0.000000628 4.68E-06 1.68E-01 8.98E-01 M23-3 0. 00000000

11 7 8.71E-09 3.13E-04 1.67E-03 M23-3 0.00000165 1.23E-05 4.42E-01 2.36E+OO

0

. 000 0.001 0.005 

# Averal!e 0.000 0.000 0.001 0

. 006 

# Averal!e 0.000 0.000 0.123 0.674 

# Averal!e 0.000 0

. 000 0.001 0

. 004 

# Avera!!e 0.000 0.000 0.197 1.079 

# Avera!!e 0.000 0.000 0.000 0.002 0.000 0.000 0.494 2

. 713 

# Averal!e 

# Page 26 of 39

# Tile MACT ICR Request

- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 RunNumber

M23-1 M23-2 M23-3 Mass_mg

0. 00000000197 0.00000000348

0

. 00000000175

0.000 Eg/hr

1.21 E-08 2.61E-08 l.30E-08

0.000 ng/dscm
4.57E-04

9

. 38E-04 4.68E-04

0.001 ng/dscm@7%02
2.44E-03 5.43E-03 2.50E-03

0.003 

# Compound:

1 ,2,3,
7 ,8-PeCDD



# Averal!e RunNumber

M23-l M23-2 M23-3 Mass_mg 0.00000152 0.00000116 0.000000793

0

. 000 Eg/hr
9.34E-06

8

. 70E-06 5.91E-06

0.000 ng/dscm
3.53E-01 3.13E-01

2

. 12E-01

0

. 293 **n~dscm@7%02**


# 1.89E+OO l.81E+OO l.l3E+OO

1.610 

# Compound: 1,2,3,7,8-PeCDF



# Avera!!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.00000000143 0.0000000021 0.0000000013

0.000 Eg/hr
8.79E-09 1.57E-08 9.68E-09

0.000 ng/dscm
3.32E-04 5.66E-04 3.48E-04

0.000 ng/dscm@7%02
1.77E-03 3.28E-03 l.86E-03

0.002 

# Compound: 2,3,4,6,

7 ,8-HxCDF



# Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.00000000138 0.00000000259 0.00000000127

0

. 000 Eg!hr
8.48E-09 l.94E-08 9.46E-09

0

. 000 ng/dscm
3.20E-04 6.98E-04 3.40E-04

0.000 **n~dscm@7%02**


# l.71E-03 4.04E-03 l.82E-03

0.003 

# Compound: 2,3,4,7,8-PeCDF



# Avera!!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.00000000138 0.00000000203 0.00000000126

0.000 Eg/hr
8.48E-09

1
. 52E-08 9.38E-09

0.000 ng/dscm
3.20E-04 5.47E-04 3.37E-04

0.000 n g/ d sc m @ 7%02 l.71E-03

3

. 17E-03 l.80E-03

0.002 

# Compound: 2,3,7,8-llCDD



# Averal!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.00000129 0.000000919 0.000000603

0

. 000 Eg/hr
7.93E-06 6.89E-06 4.49E-06

0.000 ng/dscm
2.99E-01 2.48E-Ol 1.61E-01

0.236 ng/dscm @7 %02 1.60E+OO 1.44E+OO

8.61 E-01

1.300 

# Compound:
2,3, 7 ,8-llCDF



# Averal!e RunNumber

M23-l M23-2 M23-3 Mass_mg 0.00000000159 0.00000000327 0.00000000432

0.000 Eg/hr
9.77E-09 2.45E-08 3.22E-08

0.000 ng/dscm
3.69E-04 8.82E-04 1.16E-03

0.001 ng/dscm@7%02
1.97E-03 5.llE-03 6.20E-03

0.004 

# ---- 

# Monday, June 20, 2011

Page 27 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011Compound:OCDDAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.0004670.0003010.000380.000Eg!hr2.87E-032.26E-032.83E-030.003ng/dscm1.08E+028.12E+011.02E+0297.067ng/dscm@7%025.77E+024.70E+025.45E+02530.667Compound:OCDFAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.00000006810.00000003680.00000005320.000Eg!hr4.18E-072.76E-073.96E-070.000ng/dscm1.58E-029.92E-031.42E-020.013ng/dscm@7%028.45E-025.75E-027.59E-020.073Compound:TotalDioxinsAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.0004885960.0003169490.0003963610.000Eg!hr3.00E-032.38E-032.95E-030.003ng/dscm1.13E+028.55E+011.06E+02101.500ng/dscm@7%026.04E+024.95E+025.67E+02555.333Compound:TotalFuransAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.00000008590.00000006460.00000007580.000Eg!hr5.28E-074.84E-075.65E-070.000ng/dscm1.99E-021.74E-022.03E-020.019ng/dscm@7%021.06E-011.01E-011.09E-010.105Location:VerticalDryerNo.1-Method23Compound:1,2,3,4,6,7,8-HpCDDAveral!eRunNumberM23-1M23-2M23-3Mass_mg0.000000710.0000002910.0000003590.000Eglhr1.02E-064.33E-075.24E-070.000ng/dscm1.46E-015.74E-027.22E-020.092ng/dscm@7%021.07E+OO4.20E-Ol5.28E-010.673Compound:1,2,3,4,6,7,8-HpCDFAvera!!eRunNumberM23-1M23-2M23-3Mass_mg0.000000002050.000000001820.000000001240.000Eg/hr2.95E-092.71E-091.81E-090.000ng/dscm4.21E-043.59E-042.49E-040.000ng/dscm@7%023.08E-032.63E-031.82E-030.003Compound:1,2,3,4,7,8,9-HpCDFAvera!!eRunNumberM23-lM23-2M23-3Mass_mg0.00000000430.000000002250.000000001760.000Monday,June20,2011Page28of39

# Tile MACT ICR Request

- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 Eg/hr
6.19E-09 3.34E-09 2.57E-09

0.000 ng/dscm

8

. 83E-04 4.44E-04 3.54E-04

0.001 ng/dscm@7%02
6.46E-03 3.25E-03 2.59E-03

0.004 

# Compound: 1,2,3,4,7,8-HxCDD

Avera!!e Run Number

M23-1
M23-2 M23-3 Mass_mg

0

. 0000000177 0.0000000085

8 0.0000000

I 05 0.000 Eg/hr
2.55E-08

1 .28 E-08 1.53E-08

0.000 ng/dscm
3.63E-03 1.69E-03 2.11E-03

0.002 ng/dscm@7%02
2.66E-02 1.24E-02 1.54E-02

O.D18 

# Compound:

1 ,2,3,4,7 ,8-HxCDF

Avera!!e Run Number

M23-1 M23-2 M23-3 Mass_mg 0.00000000356 0.00000000383 0.00000000191

0.000 Eg/hr
5.12E-09 5.69E-09 2.79E-09

0.000 ng/dscm
7.31E-04 7.56E-04 3.84E-04

0.001 ng/dscm@7%02
5.35E-03

5

. 53E-03 2.81E-03

0.005 

# Compound: 1,2,3,6,7,8-HxCDD

Avera!!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.0000000296 0.0000000138 0.0000000182

0.000 Eg/hr
4.26E-08 2.05E-08 2.66E-08

0.000 ng/dscm

6

. 08E-03 2.72E-03 3.66E-03

0

. 004 ng/dscm@7%02
4.45E-02 1.99E-02 2.68E-02

0.030 

# Compound: 1,2,3,6,7,8-HxCDF

Avera!!e RunNumber

M23-l M23-2 M23-3 Mass_mg 0.00000000116

0. 000000000779 0.000000000573

0.000 Eg/hr
1.67E-09 1.16E-09 8.37E-10

0

. 000 ng/dscm
2.38E-04 1.54E-04 1.15E-04

0.000 ng/dscm@7%02
1.74E-03 1.13E-03 8.41E-04

0.001 

# Compound: 1,2,3,7,8,9-HxCDD

Avera!!e RunNumber

M23-1 M23-2 M23-3 Mass_mg 0.0000000695 0.000000038 0.0000000489

0.000 Eg/hr
l.OOE-07 5.65E-08 7.14E-08

0.000 ng/dscm
1.43E-02 7.50E-03 9.83E-03

0.011 n g/dscm
@ 7%02 1.05E-Ol 5.49E-02 7.19E-02

0.077 

# Compound:

1 ,2,3, 7 ,8,9-HxCDF

Averal!e RunNumber

M23-l
M23-2 M23-3 Mass_mg

0. 00000000 182 0.00000000116 0.00000000082

0.000 Eg/hr
2.62E-09 1.72E-09 1.20E-09

0.000 ng/dscm
3.74E-04 2.29E-04

1 . 65E-04

0.000 ng / ds..:m @ ?%02 2.74E-03 1.68E-03 1.21E-03

0.002 

# Compound: 1,2,3,7,8-PeCDD



# A 

# vern•• 

# J ---- 

# Monday, June 20, 2011

Page 29 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011RunNumberM23-1M23-2M23-3Mass_mg0.00000002850.00000001350.00000001950.000Eg!hr4.10E-082.01E-082.85E-080.000ng/dscm5.85E-032.66E-033.92E-030.004ng/dscm@7%024.28E-021.95E-022.87E-020.030Compound:1,2,3,7,8-PeCDFAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.000000001920.000000001020.0000000008970.000Eg/hr2.76E-091.52E-091.31E-090.000ng/dscm3.94E-042.01E-041.80E-040.0002.88E-031.47E-031.32E-030.002Compound:2,3,4,6,7,8-HxCDFAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.000000001230.0000000008690.0000000006390.000Eg/hr1.77E-091.29E-099.33E-100.000ng/dscm2.52E-041.71E-041.28E-040.000ng/dscm@7%021.84E-031.25E-039.36E-040.001Compound:2,3,4,7,8-PeCDFAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.000000001920.000000001030.0000000008860.000Eg/hr2.76E-091.53E-091.29E-090.000ng/dscm3.94E-042.03E-041.78E-040.000ng/dscm@7%022.88E-031.49E-031.30E-030.002Compound:2,3,7,8-TCDDAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.00000003050.00000001270.00000002220.000Eg/hr4.39E-081.89E-083.24E-080.000ng/dscm6.26E-032.51E-034.46E-030.004ng/dscm@7%024.58E-021.84E-023.26E-020.032Compound:2,3,7,8-TCDFAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.000000002170.000000001070.000000001170.000Eg/hr3.12E-09\.59E-091.71E-090.000ng/dscm4.45E-042.11E-042.35E-040.000ng/dscm@7%023.26E-031.54E-031.72E-030.002Compound:OCDDAveraeeRunNumberM23-1M23-2M23-3Mass_mg0.00001320.000008050.00001170.000Eg/hr1.90E-051.20E-051.71E-050.000ng/dscm2.71E+OO1.59E+OO2.35E+OO2.217ng/dscm@7%021.98E+Ol1.16E+Ol1.72E+OI16.200Monday,June20,2011Page30of39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility Compound: OCDF RunNumb

e r Mass
_ mg E g/hr ng/dscm ng/dscm

@ 7%02 

# Compound: 

# Total Dioxins RunNumber Mass_mg Eg/hr ng/dscm ng/dscm@7%02 

# Compound: 

# Total Furans Run Number Mass_mg Eg/hr ng/dscm ng/dscm@7%02 

# Monday, June 20, 2011
M23-1 0.0000000349 5.02E-08 7.16E-03 5.24E-02 M23-1 0

. 000014086 2.03E-05 2.89E+OO 2

. 11E+01 M23-l 0.000000055 7.92E-08 1.13E-02 8.27E-02 

# 6/20/2011 M23-2 0.0000000313
4

. 65E-08 6

. 18E-03 4.52E-02 M23-2 0.000008428 1.25E-05 1.66E+OO 1.21 E+01 M23-2 0.0000000451 6.70E-08 8.90E-03 6.51E-02
M23-3 0.00000000491

7

. 17E-09 9.87E-04 7.22E-03 M23-3 0.000012178 l.78E-05 2.45E+OO 1.79E+01 M23-3 0.0000000148

2

. 16E-08 2.97E-03 2.17E-02 

# Averal!e 0.000 0

. 000 0.005 0.035 

# Averal!e 0.000 0.000 2.333 17

. 033 

# Averal!e 0.000 0.000 0

. 008 0.057 

# Page 31 of 39

### Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 

### Process Run Data Run
Name Tons per hour of tile made 

### APCD Run Data Run
Name BAGHOUSE Glaze Line (GL-1) VENTURI SCRUBBER Soray Dryer No.
2 VENTURI SCRUBBER Glaze Line (GL 3,4,5) BAGHOUSE Roller Kiln No.

1 

### Process Lab Run Data Run

Name 11anualderermined 

### Monday, June 20, 2011 6/20/2011 Value 0 Value 0 0 0 0 Target **UOM. -=------'**  **'----~**

**mm ==**  

### tons/hr 1000 

# --- Target UOM Value Comments 0 0 0 0 Value UOM Comments 

### 0 :ons 

### JhJ 

### Page 32 of 39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 Sampling



# I Stack Data Results Detail 

# Location 

# Glaze Line (GL-
3, 4, 5) -Method
29

Avera

e Run Number

M29-1 M29-2 M29-3 Test Date

5/24/2010 5/25/2010 5/25/2010 Run Start Time

11:35:00 AM 8:26:00 AM 1:49:00 PM Run Finish Time

3:40:00 PM 12

: 36:00 PM 5:55:00 PM Net Traversing Points

24

24

24 Net Run Time, minutes

240
240
240 Nozzle Diameter, inches

0.255 0.255 0.255 0.255 Pi tot Tube Coefficient

0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor

0.982 0.982 0.982 0.982 Barometric Pressure, inches ofMercury

30.21 30.08 30.08 30.123 Average Orifice Meter Differential, inches H20

1.47
1.51
1.48 1.487 Dry Gas Meter Volume Sampled, cubic feet 173.205 172.675 174.985 173.622 Average Dry Gas Meter Temperature,

oF
108.04 91.63 110.63 103.433 Dry Gas Meter Volume Sampled, dscf
160.202 163.773 160.427 161.467 Total Moisture Liquid collected,

g

104.8 96.9 104.9 102.200 Volume of Water Vapor, standard cubic feet

4.93 4.56 4.94 4.810 Moisture Content of Stack Gas, %

2.99
2.71 2.99

2

. 897 Moisture Saturation

at Stack Gas Temperature,

%

5.22 4.31

4

. 97 4.833 Dry Mole Fraction

0.9701 0.9729 0.9701 0.971 Carbon Dioxide,

%

0

0

0 0.000 Oxygen,%

20.8 20.8
20.8 20.800 Carbon Monoxide

& 

# Nitrogen,

%

79.2 79.2 79.2 79.200 Fuel Factor Dry Molecular Weight, lb/lb-Mole

28.83 28.83

28

. 83
28

. 830 Wet Molecular weight, lb/lb-Mole

28.51 28.54 28.51 28.520 Flue Gas Static Pressure, inches of H20

-0.09 -0.08 -0.09 -0.087 Absolute Flue Gas Pressure, inches of Mercury

30.20 30.07 30.07

30

. 113 Average Stack Gas Temperature,

°F

93.33 87.04 91.63 90.667 Average Velocity Head, inches ofH20 0.3295082817 0.336884124 0.332992130
0.333 09215 762715 954034 Average Stack Gas Velocity, feet/second

33.05 33.28 33.24 33.190 Stack Cross-Sectional Area, square feet

6.874 6.874 6.874 6.874 Dry Volumetric Flow Rate, dry scfin
12,736.3 12,953.9 12,793.7 12,827.967 Actual Wet Volumetric Flue Gas Flow Rate, acfrn 13,631.1 13,726.0 13,709.5 13,688

. 867 Percent Isokinetic
of Sampling Rate, %

101.6 102.1 101.3 101.667 Percent Excess Air, %

19,!17.6 19,117.6 19,117.6 19,117

. 600 F-Factor, dscfrn/MMBtu

@ %02

0

0

0

0

. 000 Round Duct Diameter, inches

35.5

35

. 5 35.5 Rectangular Duct Width, inches

0

0

0 Rectangular Duct Length, inches

0

0

0 Fw

0

0

0

0

. 000 Fe

0

0

0 0.000 

# Monday, June 20, 2011

Page 33 of 39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 Location Glaze Line (GL 

# -1)- Method 29



# Avera **~** Run Number

M29-l M29-2 M29-3 Test Date

5/26/2010 5/26/2010 5/27/2010 Run Start Time

9:22:00 AM 2:18:00PM 7:55:00AM Run Finish Time

1:33:00 PM 6:28:00 PM 12:15:00PM Net Traversing Points

20

20

20 Net Run Time, minutes

240
240
240 Nozzle Diameter, inches

0.317 0.317 0.317 0.317 Pi tot Tube Coefficient

0.84 0.84
0.84 0.840 Dry Gas Meter Calibration Factor

0.982 0.982 0.982 0.982 Barometric Pressure, inches of Mercury

30.05 30.05 30.05 30.050 Average Orifice Meter Differential, inches H20

1.22
1.32
1.37 1.303 Dry Gas Meter Volume Sampled, cubic feet 158.230 163.440 166.680 162.783 Average Dry Gas Meter Temperature,

op


# 100.95 95.35 91.50 95.933 Dry Gas Meter Volume Sampled, dscf
147.329 153.752 157.914 152.998 Total Moisture Liquid collected,

g

82.3 76.8
76.1 78.400 Volume ofWater Vapor, standard cubic feet

3.87
3.61
3.58

3

. 687 Moisture Content of Stack Gas, %

2.56 2.29 2.22 2.357 Moisture Saturation

at Stack Gas Temperature,

%

6.58 6.39 5.97 6.313 Dry Mole Fraction

0.9744 0.9771 0.9778 0.976 Carbon Dioxide,

%

0

0

0 0.000 Oxygen,%

20.8 20.8
20.8 20.800 Carbon Monoxide

& 

# Nitrogen,

%

79.2 79.2 79.2 79.200 Fuel Factor Dry Molecular Weight, lb/lb-Mole

28.83 28.83 28.83 28.830 Wet Molecular weight, lb/lb-Mole

28.55 28.58 28.59 28.573 Flue Gas Static Pressure, inches ofH20

-0.04 -0.05 -0.04 -0.043 Absolute Flue Gas Pressure, inches ofMercury

30.05 30.05 30.05 30.050 Average Stack Gas Temperature,

°F

100.75 99.80 97.55 99.367 Average Velocity Head, inches ofH20 0.1133253953 0.122841059

0

. 128451490

0

. 122 9107 251302 488337 Average Stack Gas Velocity, feet/second

19.54 20.32 20.73 20.197 Stack Cross-Sectional Area, square feet

9

. 393 9.393 9.393 9.393 Dry Volumetric Flow Rate, d1y scfin
10,147.6 10,599.9 10,865.2 10,537

. 567 Actual Wet Volumetric Flue Gas Flow Rate, acfin 11,012.4 11,451.9 11,683.0 11,382.433 Percent

I so kinetic of Sampling Rate, %

103.7 103.6 103.8 103.700 Percent Excess Air, %

19,117.6 19,117.6 19,117.6 19,117.600 F-Factor, dscfin!MMBtu@ %02

0

0

0 0.000 Round Duct Diameter, inches

41.5 41.5
41.5 Rectangular Duct Width, inches

0

0

0 Rectangular Duct Length, inches

0

0

0 Fw

0

0

0 0.000 Fe

0

0

0 0.000 

# Monday, June 20, 2011

Page 34 of 39Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Location Roller Kiln
# 1 October

- Method
23

Avera

e Run Number

M23-1 M23-2 M23-3 Test Date

10/11/2010 10/11/2010

I 0/12/2010 Run Start Time

8:08:00 AM 12:23:00 PM 7:47:00 AM Run Finish Time

12:11:00 PM 5:25:00 PM 11:49:00 AM Net Traversing Points

24

24

24 Net Run Time, minutes

240
240
240 Nozzle Diameter, inches

0.312 0.312 0.312 0.312 Pitot Tube Coefficient

0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor

0.983 0.983 0.983 0.983 Barometric Pressure, inches of Mercury

29.55 29.55 29.55 29.550 Average Orifice Meter Differential, inches H20

2.67 2.76
2.83 2.753 Dry Gas Meter Volume Sampled, cubic feet 206.134 210.404 212.026 209.521 Average Dry Gas Meter Temperature,

oF

82.58 87.96 87.04 85.860 Dry Gas Meter Volume Sampled, dscf
196.040 198.180 200.079 198.100 Total Moisture Liquid collected,

g

288.4 273.3 298.2 286.633 Volume of Water Vapor, standard cubic feet

13

. 57 12.86

14

. 04 13.490 Moisture Content of Stack Gas, %

6.47 6.09 6.56 6.373 Moisture Saturation

at Stack Gas Temperature,

% 100.00 100.00 100.00 100.000 Dry Mole Fraction

0.9353 0.9391 0.9344 0.936 Carbon Dioxide,

%

3

3

3 3.000 Oxygen,%

18.3
18.4
18.2 18.300 Carbon Monoxide

& Nitrogen,

%

78.7 78.6
78.8 78.700 Fuel Factor

0.87 0.83 0.90 Dry Molecular Weight, lb/lb-Mole

29.21 29.22 29.21 29.213 Wet Molecular weight, lb/lb-Mole

28.48 28.54 28.47 28.497 Flue Gas Static Pressure, inches of H20

-0.22 -0.22 -0.22 -0.220 Absolute Flue Gas Pressure, inches of Mercury

29.53 29.53 29.53 29.530 Average Stack Gas Temperature,

oF

279.50 281.42 281.88 280.933 Average Velocity Head, inches of H20 0.3279458113 0.337879039 0.347362504
0.338 02214 64567 618031 Average Stack Gas Velocity, feet/second

38.56 39.15 39.76 39.157 Stack Cross-Sectional Area, square feet

10.202 10.202 10.202 10.202 Dry Volumetric Flow Rate, dry scfin
15,556.9 15,818.0 15,974.2 15,783.033 Actual Wet Volumetric Flue Gas Flow Rate, acfin 23,603.3 23,964

. 5 24,337.9 23,968.567 Percent lsokinetic
of Sampling Rate,%

100.9
100

. 3 100.3 100.500 Percent Excess Air, %

738.9 782.8 699.1 740.267 F-Factor, dscfm!MMBtu@ %02

0

0

0 0.000 Round Duct Diameter, inches

43.25

43

. 25 43.25 Rectangular Duct Width, inches

0

0

0 Rectangular Duct Length, inches

0

0

0 Fw

0

0

0 0.000 Fe

0

0

0 0.000 Monday, June 20, 2011

Page 35 of 39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011LocationRollerKilnNo.1May-Method23lAveraeIRunNumberM23-1M23-2M23-3TestDate5/25/20105/25/20105/26/2010RunStartTime8:10:00AM4:25:00PM7:57:00AMRunFinish Time12:14:00PM8:31:00PM12:08:00PMNetTraversingPoints242424NetRunTime,minutes240240240NozzleDiameter,inches0.3120.3120.3120.312PitotTubeCoefficient0.840.840.840.840DryGasMeterCalibrationFactor1.0171.0081.0081.011BarometricPressure,inchesofMercury30.0830.0830.0730.077AverageOrificeMeterDifferential,inchesH202.312.372.522.400DryGasMeterVolumeSampled,cubicfeet204.222206.993209.547206.921AverageDryGasMeterTemperature,oF88.25101.7988.1392.723DryGasMeterVolumeSampled,dscf202.228198.290205.746202.088TotalMoistureLiquidcollected,g281.3303.7350.2311.733VolumeofWaterVapor,standardcubicfeet13.2414.3016.4814.673MoistureContentofStackGas,%6.14 6.737.426.763MoistureSaturationatStackGasTemperature,%100.00100.00100.00100.000DryMoleFraction0.93860.93270.92580.932CarbonDioxide,%2.52.52.52.500Oxygen,%19.119.319.319.233CarbonMonoxide&Nitrogen,%78.478.278.278.267FuelFactor0.720.640.64DryMolecularWeight,lb/lb-Mole29.1629.1729.1729.167WetMolecularweight,lb/lb-Mole28.4728.4228.3428.410FlueGasStaticPressure,inchesofH20-0.2-0.2-0.2-0.200AbsoluteFlueGasPressure,inchesofMercury30.0730.G730.0630.067AverageStackGasTemperature,oF265.00267.67265.92266.197AverageVelocityHead,inchesofH200.33924696060.3465411140.3686337620.35154402139673949002AverageStackGasVelocity,feet/second38.4939.0140.2539.250StackCross-SectionalArea,squarefeet10.20210.20210.20210.202DryVolumetricFlowRate,dryscfm16,185.716,241.516,668.316,365.167ActualWetVolumetlicFlueGasFlowRate,acfm23,560.523,878.824,637.824,025.700PercentIsokineticofSamplingRate,%100.097.798.898.833PercentExcessAir,%1,195.51,435.21,435.21,355.300F-Factor,dscfm/MMBtu@%020000.000RoundDuctDiameter,inches43.2543.2543.25RectangularDuctWidth,inches000RectangularDuctLength,inches000Fw0000.000Fe0000.000Monday,June20,2011Page36of39TileMACTICRRequest-SiteSpecificTestPlanFlorimUSA-Clarksville,TennesseeFacility6/20/2011LocationRollerKilnNo.IMay-Method29AveraeRunNumberM29-lM29-2M29-3TestDate5/25/20105/25/20105/26/2010RunStartTime10:18:00AM4:29:00PM7:58:00AMRunFinishTime2:25:00PM8:31:00PM12:08:00PMNetTraversingPoints242424NetRunTime,minutes240240240NozzleDiameter,inches0.250.250.250.250PitotTubeCoefficient0.840.840.840.840DryGasMeterCalibrationFactor0.9730.9730.9730.973BarometricPressure,inchesofMercury30.0830.0830.0730.077AverageOrificeMeterDifferential,inchesH201.061.051.131.080DryGasMeterVolumeSampled,cubicfeet131.837131.660134.240132.579AverageDryGasMeterTemperature,oF89.4297.0484.6790.377DryGasMeterVolumeSampled,dscf124.257122.389127.604124.750TotalMoistureLiquidcollected,g172.6195221.5196.367VolumeofWaterVapor,standardcubicfeet8.129.1810.439.243MoistureContentofStackGas,%6.13 6.987.566.890MoistureSaturationatStackGasTemperature,%100.00100.00100.00100.000DryMoleFraction0.93870.93020.92440.931CarbonDioxide,%2.52.52.52.500Oxygen,%19.119.319.319.233CarbonMonoxide&Nitrogen,%78.478.278.278.267FuelFactor0.720.640.64DryMolecularWeight,lb/lb-Mole29.1629.1729.1729.167WetMolecularweight,lbllb-Mole28.4828.3928.3328.400FlueGasStaticPressure,inchesofH20-0.2-0.2-0.2-0.200AbsoluteFlueGasPressure,inchesofMercury30.0730.0730.0630.067AverageStackGasTemperature,oF265.38266.42269.17266.990AverageVelocityHead,inchesofH200.31766189250.3153088370.3410190640.32590474261709065101AverageStackGasVelocity,feet/second37.2537.2038.8037.750StackCross-SectionalArea,squarefeet10.20210.20210.20210.202DryVolumetricFlowRate,dryscfm15,657.815,473.015,972.115,700.967ActualWetVolumetricFlueGasFlowRate,acfm22,801.522,770.923,750.323,107.567PercentIsokineticofSamplingRate,%99.098.699.699.067PercentExcessAir,%1,195.51,435.21,435.21,355.300F-Factor,dscfm/MMBtu@%020000.000RoundDuctDiameter,inches43.2543.2543.25RectangularDuctWidth,inches000RectangularDuctLength,inches000Fw0000.000Fe0000.000JMonday,June20,2011Page37of39

# Tile MACT ICR Request- Site Specific Test Plan Florim USA

- Clarksville, Tennessee Facility 6/20/2011 Location 

# Spray Dryer No.
2 -Method
23 

# Ave~ Run Number

M23-1 M23-2 M23-3 Test Date

10/12/2010 10/12/2010 10/13/2010 Run Start Time
8:07:00AM
1:16

: 00 PM 8:16:00AM Run Finish Time

12:11:00 PM 5:43:00 PM 12:18:00PM Net Traversing Points

24

24

24 Net Run Time, minutes

240
240
240 Nozzle Diameter, inches

0

. 275 0.25
0.25

0

. 258 Pi tot Tube Coefficient

0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor

1.002 1.002 1.002 1.002 BarometJ.ic Pressure, inches ofMercury

29

. 55 29.55 29.65

29

. 583 Average Olifice Meter Differential, inches H20

1.39
1.05
1.03 1.157 Dry Gas Meter Volume Sampled, cubic feet 157.639 135.610 134.125 142.458 Average Dry Gas Meter Temperature,

oF

83.25 82.33 74.17 79.917 Dry Gas Meter Volume Sampled, dscf
152.146 130.996 131.978 138.373 Total Moisture Liquid collected,

g

971.3 830.4 766.7 856.133 Volume of Water Vapor, standard cubic feet

45.72 39.09 36.09 40.300 Moisture Content of Stack Gas, %

23.11 22.98 21.47 22.520 Moisture Saturation

at Stack Gas Temperature,

%
22.41 21.30 21.02 21.577 Dry Mole Fraction

0

. 7759 0.787 0.7898

0

. 784 Carbon Dioxide,

%

3

3

2

. 5 2.833 Oxygen,%

18.3
18.5
18.3 18.367 Carbon Monoxide

& 

# Nitrogen,

%

78

. 7 78.5

79

. 2 78.800 Fuel Factor

0.87 0.80
1.04 Dry Molecular Weight, lb/lb-Mole

29.21 29.22 29.13

29

. 187 Wet Molecular weight, lb/lb-Mole

26.82 27.13

26

. 87
26

. 940 Flue Gas Static Pressure, inches of H20

-0

. 21 -0.2 -0.17

-0

. 193 Absolute Flue Gas Pressure, inches of Mercury

29.53 29.54 29.64 29.570 Average Stack Gas Temperature,

°F

144.71 142.71 142.33 143.250 Average Velocity Head, inches of H20

0

. 3436517380

0.3 71538226 0.364476093 0.360 20821 148949 807725 Average Stack Gas Velocity, feet/second

36.78 37.96 37.70 37.480 Stack Cross-Sectional Area, square feet

10.559 10.559 10.559 10.559 Dry Volumetric Flow Rate, dty scfin
15,580.5 16,370.0 16,381.3 16,110.600 Actual Wet Volumetric Flue Gas Flow Rate, acfm 23,301.6 24,049.2 23,884

. 5 23,745

. 100 Percent lsokinetic
of Sampling Rate, %

104

. 2 103.3 104.0 103

. 833 Percent Excess Air, %

738.9 831.8

701

. 5 757.400 F-Factor, dscfin!MMBtu@ %02

0

0

0

0

. 000 Round Duct Diameter, inches

44

44

44 Rectangular Duct Width, inches

0

0

0 Rectangular Duct Length, inches

0

0

0 Fw

0

0

0 0.000 Fe

0

0

0

0

. 000 

# Monday, June 20, 2011

Page 38 of 39Tile MACT ICR Request- Site Specific Test Plan Florim USA- Clarksville, Tennessee Facility 6/20/2011 Location Vertical Dryer No.

I -Method
23

Avera

e Run Number

M23-1 M23-2 M23-3 Test Date

10113/2010 10/1412010 10/14/2010 Run Start Time

2:58:00 PM 9:40:00AM 2:56:00 PM Run Finish Time

7:08:00 PM 1:52:00 PM

?

: 04:00PM Net Traversing Points

24

24

24 Net Run Time, minutes

240
240
240 Nozzle Diameter, inches

0

. 25 0.25
0.25

0

. 250 Pi tot Tube Coefficient

0.84

0

. 84

0

. 84 0.840 Dry Gas Meter Calibration Factor

1.002

1
. 002 1.002 1.002 Barometric Pressure, inches of Mercury 29.65 29.92

29.92 29.830 Average Orifice Meter Differential, inches H20

1.87
1.97
1.89 1.910 Dry Gas Meter Volume Sampled, cubic feet 178.532 181.671 179.938 180.047 Average Dry Gas Meter Temperature,

oF

86.46

79

. 63

84

. 29 83.460 Dry Gas Meter Volume Sampled

, dscf
172.081 178.973 175.714 175.589 Total Moisture Liquid collected,

g

373.3

183

. 2 275.5 277.333 Volume of Water Vapor, standard cubic feet

17

. 57

8

. 62

12

. 97

13

. 053 Moisture Content of Stack Gas, %

9

. 26 4.60 6.87 6.910 Moisture Saturation

at Stack Gas Temperature,

% 100.00 100.00 100.00 100.000 Dry Mole Fraction

0.9074

0

. 954 0.9313 0.931 Carbon Dioxide,

%

2

2

2 2.000 Oxygen,%

19

19

19 19.000 Carbon Monoxide

& Nitrogen,

% 79 79

79 79.000 Fuel Factor

0.95 0.95 0.95 Dry Molecular Weight, lb/lb-Mole

29

. 08 29.08 29.08 29.080 Wet Molecular weight

, lb/lb-Mole

28

. 05 28.57 28.32 28.313 Flue Gas Static Pressure, inches of H20

0.41 0.45
0.43 0.430 Absolute Flue Gas Pressure, inches of Mercury

29

. 68

29

. 95 29.95

29

. 860 Average Stack Gas Temperature,

oF

237.71 239.58 238.04 238.443 Average Velocity Head, inches ofH20 0.6087614826 0.643095892

0

. 621221607 0.624 24089 60242 252395 Average Stack Gas Velocity, feet/second

51.29 52.07 51.35 51.570 Stack Cross-Sectional
Are a, square feet

1.969 1.969 1.969 1.969 Dry Volumetric Flow Rate

, dry scfm
4,127.5 4,433

. 7 4,277.8 4,279.667 Actual Wet Volumetric Flue Gas Flow Rate, acfm 6,059.4 6,151.5

6
, 066.5 6,092.467 Percent Isokinetic
of Sampling Rate, %

100.3 97.2 98.9 98.800 Percent Excess Air, %

1,023

. 7 1,023.7 1,023

. 7 1,023

. 700 F-Factor

, dscfin!MMBtu

@ % 02

0

0

0 0.000 Round Duct Diameter

, inches

19

19

19 Rectangular Duct Width, inches

0

0

0 Rectangular Duct Length

, inches

0

0

0 Fw

0

0

0 0.000 Fe

0

0

0 0.000 Monday, June 20, 2011

Page 39 of 39