**Iron and Steel Data Supporting the 2013 A nnual Review Report** 

**Data Compiled: November 2013 - March 2014**

**Tab Name**

Sum ma ry

Rankings

Top DMR Pollutants

Top Pollutant Data

Iron and Steel - IN0000205 Iron and Steel - IN0000281 Iron and Steel - W V0003336

Iron and Steel - AL0070068 Iron and Steel - PA0004472 - Cyanide Iron and Steel - PA0004472 - TRC Iron and Steel - W V0004499**Iron and Steel Data Supporting the 2013 A nnual Review Report**  **Data Compiled: November 2013 - March 2014**
**Tab Description** 2013 Final Rankings for the DMR and TRI databases. Also shows what percent DMR and TRI make up for the category being reviewed. Top pollutants in the 2011 DMR Database for the Iron and Steel Category . Includes facility count, pounds, and TW PE for each pollutant. Highlights the pollutants that were reviewed as part of the 2013 Annual Review. Also includes corrections to the top pollutant data after the 2013 Annual Review was completed. Top facilities for each top pollutant in the 2011 DMR Database for the Iron and Steel Category reviewed as part of the 2013 Annual Review. Includes facility pounds and TW PE. Also includes corrections to the top facility data after the 2013 Annual Review was com pleted. Facility-specific data and notes on Arcelormittal Indiana Harbor LLC in East Chicago, IL. Includes data corrections from the 2013 Annual Review. Facility-specific data and notes on USS Gary W orks in Gary , IN. Facility-specific data and notes on W eirton Steel Corporation in W eirton, W V. Facility-specific data and notes on Nucor Steel Decatur in Trinity , AL. Includes data corrections from the 2013 Annual Review. Facility-specific data and notes on cyanide discharges from USS- Clairton Plant in Clairton, PA. Facility-specific data and notes on total residual chlorine discharges from USS- Clairton Plant in Clairton, PA. Facility-specific data and notes on Mountain State Carbon Follansbee Plant in Follansbee, W V.**2013 - Final Combined Rankings Excluding Categories Recently Reviewed**

**2/7/2014 Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool**  Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**PSC Point Source Category**  **Total Count of**  **Facilities Direct** 

**Only Indirect** 

**Only** 414 Organic chemicals, plastics and sy nthetic fibers 631 194 380 430 Pulp, paper and paperboard 221 145 63 419 Petroleum refining 267 192 52 501 Drinking W ater Treatment 2 0 0 440 Ore mining and dressing 33 29 3 420 Iron and steel manufacturing 222 118 50 418 Fertilizer m anufacturing 41 32 4 415 Inorganic chemicals manufacturing 153 56 71 421 Nonferrous metals manufacturing 119 52 49 455 Pesticide chemicals 56 30 24 409 Sugar processing 14 12 2 433 Metal Finishing 1785 263 1256 451 Concentrated Aquatic Animal Production 0 0 0 434 Coal m ining 17 17 0 432 Meat and Poultry Products 156 82 61 429 Timber products processing 102 67 21 435 Oil & Gas Extraction 0 0 0 463 Plastics molding and forming 114 24 71 503 Miscellaneous Foods and Beverages 131 19 109 445 Landfills 1 1 0 417 Soap and detergent manufacturing 70 4 62 424 Ferroalloy

manufacturing 5 5 0 436 Mineral Mining and Processing 83 49 32 458 Carbon black manufacturing 4 4 0 464 Metal m olding and casting (foundries) 199 89 72 410 Textile mills 44 4 33 471 Nonferrous metals forming and metal powders 119 28 56 428 Rubber Manufacturing 157 26 85 438 Metal Products and Machinery 74 18 45 422 Phosphate manufacturing 10 9 1 406 Grain mills 23 7 10 457 Explosives manufacturing 9 5 2 469 Electrical and electronic components 70 5 62 437 Centralized W aste Treatment 2 1 1 460 Hospital 0 0 0 468 Copper forming 109 24 41 467 Alum inum forming 114 18 60 439 Pharmaceutical manufacturing 84 9 71 411 Cement manufacturing 53 43 8

407 Canned and preserved fruits and vegetables processing 26 8 18 405 Dairy

products processing 291 36 247 413 Electroplating 306 15 264 466 Porcelain Enameling 4 0 3 444 Wa ste combustors 2 1 0 **TRI Facility Counts**508 Printing & Publishing 57 2 54

425 Leather tanning and finishing 13 1 11 426 Glass manufacturing 53 9 35 442 Transportation Equipment Cleaning 1 1 0 443 Paving and roofing materials (tars and asphalt) 29 16 6 461 Battery

manufacturing 54 3 35 507 Independent and Stand Alone Labs 1 0 1 408 Canned and preserved seafood processing 6 6 0 427 Asbestos manufacturing 0 0 0 454 Gum and wood chemicals manufacturing 10 8 1 465 Coil coating 37 1 36 446 Paint formulating 53 10 41 505 Food Service Establishments 0 0 0 506 Industrial Laundries 0 0 0 502 Tobacco Products 17 1 15 447 Ink formulating 10 1 9 509 Photo Processing 0 0 0 459 Photographic 0 0 0**Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool** Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

**Both Direct and**  **Indirect TRI LBY**  **TRI TWPE Total**  **Count of Facilities**  **Ma**

**jors Minors**  **DMR LBY DMR TWPE**  57 25991167.15 147675.2182 470 189 281 2738253625 1540387.114 13 17750608.67 651376.5506 234 194 40 2239681616 1034369.59 23 23589915.03 680608.0883 479 96 383 516230325.2 751580.6938 2 12810 1643 1335 20 1315 4216219611 1384298.003 1 1826546.128 1229923.39 93 53 40 698538772.3 109758.1093 54 33509051.72 82937.27287 146 83 63 1279823916 1170699.952 5 4377973.034 6667.914961 39 19 20 122486680.9 599100.4356 26 8732577.95 326863.4381 217 70 147 1532389542 142060.7974 18 4669549.932 42948.34437 57 28 29 157405728.4 382840.4371 2 2115074.33 373899.7328 33 20 13 29998642.94 19317.89791 0 487306.72 429.8574031 26 19 7 65490570.71 373178.6753 266 4300840.877 51738.65198 626 86 540 216670888.6 264963.1311 0 0 0 266 20 246 105515454.3 291885.136 0 292406.0871 563.9618167 218 13 205 8405721295 188756.1494 13 51722815.47 39117.80918 158 34 124 464043654 119028.2383 14 39325.3567 32332.84936 139 4 135 1136810374 98629.5955 0 0 0 150 14 136 5024628205 106089.5093 19 2926175.403 69161.81513 78 5 73 724327795.5 26693.83158 3 3983961.506 4901.790156 119 7 112 4247927288 57364.7284 0 19942.9 42850.60386 234 5 229 81481172.75 19311.53355 4 94322.31682 2368.142999 18 3 15 2781234.308 47123.66268 0 135757.55 8990.980096 13 2 11 13220221.92 27260.26418 2 2103016.382 2946.423878 992 27 965 3093991064 31156.47101 0 559.579 27865.49368 2 0 2 4375209.577 0.2009075 38 212440.0484 9671.857609 53 8 45 27454867.86 16283.18749 7 592379.4161 1074.029372 67 31 36 33130533.05 22342.79249 35 1340579.676 17883.4982 34 11 23 6011501.362 3438.610671 46 962717.5478 10197.31036 77 15 62 19197556.73 7322.237141 11 316649.16 7951.962317 491 76 415 230974159.8 7672.994297 0 18457.5674 193.4171027 12 8 4 23096767.64 13597.30481 6 2851270.356 10517.45364 34 7 27 55857054.6 2808.320562 2 18485.4034 17.39397107 11 4 7 104873877.7 11829.26076 3 2889479.15 3575.853324 12 5 7 80960904.97 8179.21937 0 265785.1 2353.763007 19 9 10 211936878.3 7864.421151 0 0 0 155 2 153 16801424.87 9419.724086 44 41872.93951 6178.329298 28 8 20 4005009.424 2613.052703 36 175623.3605 1303.472471 27 9 18 4106427.55 6962.480421 4 1046704.288 2347.025621 58 20 38 37208518.52 4519.197551 2 1148.100086 651.7279191 323 6 317 99524423.29 5964.807959

0 5894286.82 4420.079944 51 7 44 856519832.8 1063.841802 8 4992508.337 3766.50093 54 3 51 36114818.66 593.1695576 27 1105818.527 4097.304214 0 0 0 0 0 1 300.216 27.83928 3 0 3 579081.6817 2733.890934 1 45.5586 88.22424233 9 5 4 484441.2705 2652.262618 **DMR Facility Counts**1 19936 388 12 2 10 1397612.326 1891.085596

1 218884.82 1898.084539 3 1 2 52662.71522 8.195757828 9 40981.34463 246.0956356 43 1 42 10436822.26 1555.930967 0 11.7 0.012987 49 1 48 20451295.3 1697.742516 7 136.35443 1062.519238 48 3 45 11673576.8 581.4361552 16 16899.04192 869.8050999 2 0 2 10969.23373 298.0498167 0 1.482 4.46838 33 5 28 69404043.95 756.2223126 0 99330 74.1664 53 8 45 68783703.06 686.4242635 0 0 0 2 0 2 7018812.068 517.9002151 1 2733.19054 33.58020866 12 3 9 3863729.745 360.0025889 0 19825.1946 74.98402799 5 1 4 24097.81521 249.914905 2 70441.63756 86.45111028 8 0 8 50775.60004 3.051504149 0 0 0 87 0 87 10346303.53 45.63688716 0 0 0 5 0 5 380387.7176 12.62378436 1 88022.7562 12.5288154 1 0 1 5.17447E-07 0 0 1304.0257 3.612719447 3 0 3 26080.35784 2.222387256 0 0 0 1 0 1 21973.57197 0.06279474 0 0 0 1 0 1 21973.57197 0.06279474

3918883.447 8932381.498**Total LBY Total TWPE**  **% of Total TWPE**  **Combined %**

**of Total TWPE**  **TRI % of Total**  **DMR % of**

**Total** 2,764,244,793 1,688,062 0.13 0.13 9% 91% 2,257,432,225 1,685,746 0.13 0.26 39% 61% 539,820,240 1,432,189 0.11 0.37 48% 52% 4,216,232,421 1,385,941 0.11 0.48 0.1% 99.9% 700,365,318 1,339,681 0.10 0.59 92% 8% 1,313,332,968 1,253,637 0.10 0.68 7% 93% 126,864,654 605,768 0.05 0.73 1% 99% 1,541,122,119 468,924 0.04 0.77 70% 30% 162,075,278 425,789 0.03 0.80 10% 90% 32,113,717 393,218 0.03 0.83 95% 5% 65,977,877 373,609 0.03 0.86 0% 100% 220,971,729 316,702 0.02 0.88 16% 84% 105,515,454 291,885 0.02 0.91 0% 100% 8,406,013,701 189,320 0.01 0.92 0% 100% 515,766,469 158,146 0.01 0.93 25% 75% 1,136,849,700 130,962 0.01 0.94 25% 75% 5,024,628,205 106,090 0.01 0.95 0% 100% 727,253,971 95,856 0.01 0.96 72% 28% 4,251,911,250 62,267 0.00 0.97 8% 92% 81,501,116 62,162 0.00 0.97 69% 31% 2,875,557 49,492 0.00 0.97 5% 95% 13,355,979 36,251 0.00 0.98 25% 75% 3,096,094,081 34,103 0.00 0.98 9% 91% 4,375,769 27,866 0.00 0.98 100% 0% 27,667,308 25,955 0.00 0.98 37% 63% 33,722,912 23,417 0.00 0.99 5% 95% 7,352,081 21,322 0.00 0.99 84% 16% 20,160,274 17,520 0.00 0.99 58% 42% 231,290,809 15,625 0.00 0.99 51% 49% 23,115,225 13,791 0.00 0.99 1% 99% 58,708,325 13,326 0.00 0.99 79% 21% 104,892,363 11,847 0.00 0.99 0% 100% 83,850,384 11,755 0.00 0.99 30% 70% 212,202,663 10,218 0.00 0.99 23% 77% 16,801,425 9,420 0.00 1.00 0% 100% 4,046,882 8,791 0.00 1.00 70% 30% 4,282,051 8,266 0.00 1.00 16% 84% 38,255,223 6,866 0.00 1.00 34% 66% 99,525,571 6,617 0.00 1.00 10% 90%
862,414,120 5,484 0.00 1.00 81% 19% 41,107,327 4,360 0.00 1.00 86% 14% 1,105,819 4,097 0.00 1.00 100% 0% 579,382 2,762 0.00 1.00 1% 99% 484,487 2,740 0.00 1.00 3% 97%1,417,548 2,280 0.00 1.00 17% 83% 271,548 1,906 0.00 1.00 100% 0% 10,477,804 1,802 0.00 1.00 14% 86% 20,451,307 1,698 0.00 1.00 0% 100% 11,673,713 1,644 0.00 1.00 65% 35% 27,868 1,168 0.00 1.00 74% 26% 69,404,045 760.7 0.00 1.00 1% 99% 68,883,033 760.6 0.00 1.00 10% 90% 7,018,812 518 0.00 1.00 0% 100% 3,866,463 394 0.00 1.00 9% 91% 43,923 325 0.00 1.00 23% 77% 121,217 90 0.00 1.00 97% 3% 10,346,304 46 0.00 1.00 0% 100% 380,388 13 0.00 1.00 0% 100% 88,023 13 0.00 1.00 100% 0% 27,384 6 0.00 1.00 62% 38% 21,974 0 0.00 1.00 0% 100% 21,974 0 0.00 1.00 0% 100%

12,851,265**Revised Top Pollutants in Iron and Steel (Part 420) from DMR2011**

1/28/2014 Republic Conduit submitted changes to their chromium, hexavalent discharges after the static DMR 2011 database was pulled. Therefore, the rankings were updated with this change.

Pollutants Reviewed as part of the 2013 ARR

**PSC Code PSC Description**  **Fac Count**  **Pollutant** 420 Iron and steel manufacturing 17 Fluoride 420 Iron and steel manufacturing 18 Alum inum 420 Iron and steel manufacturing 29 Cyanide 420 Iron and steel manufacturing 29 Total Residual Chlorine 420 Iron and steel manufacturing 4 Silver 420 Iron and steel manufacturing 68 Lead 420 Iron and steel manufacturing 32 Chromium 420 Iron and steel manufacturing 99 Zinc 420 Iron and steel manufacturing 5 Benzo[a]py rene 420 Iron and steel manufacturing 2 Benz[a]anthracene 420 Iron and steel manufacturing 48 Copper 420 Iron and steel manufacturing 50 Iron 420 Iron and steel manufacturing 11 Selenium 420 Iron and steel manufacturing 10 Chromium, Hexavalent 420 Iron and steel manufacturing 13 Manganese 420 Iron and steel manufacturing 10 Cadmium 420 Iron and steel manufacturing 48 Am mo nia as N 420 Iron and steel manufacturing 26 Mercury 420 Iron and steel manufacturing 3 Magnesium 420 Iron and steel manufacturing 6 Arsenic 420 Iron and steel manufacturing 2 Benzo(b)fluoranthene 420 Iron and steel manufacturing 13 Chloride 420 Iron and steel manufacturing 2 Indeno[1,2,3-cd]py rene 420 Iron and steel manufacturing 1 Chromium, Trivalent 420 Iron and steel manufacturing 11 Sulfate 420 Iron and steel manufacturing 5 Nitrogen, nitrate dissolved 420 Iron and steel manufacturing 3 Nitrite nitrogen, dissolved (as N) 420 Iron and steel manufacturing 2 Benzo[k]fluoranthene 420 Iron and steel manufacturing 2 Chrysene 420 Iron and steel manufacturing 28 Nickel 420 Iron and steel manufacturing 2 Boron 420 Iron and steel manufacturing 2 Dibenz[a,h]anthracene 420 Iron and steel manufacturing 3 Di(2-ethylhexyl) phthalate 420 Iron and steel manufacturing 2 Phenol 420 Iron and steel manufacturing 1 Fluoranthene 420 Iron and steel manufacturing 3 Moly bdenum 420 Iron and steel manufacturing 5 Am mo nia as NH3 420 Iron and steel manufacturing 1 Sodium 420 Iron and steel manufacturing 6 Benzene 420 Iron and steel manufacturing 2 Barium 420 Iron and steel manufacturing 1 Anthracene 420 Iron and steel manufacturing 2 Phenanthrene 420 Iron and steel manufacturing 1 Py rene 420 Iron and steel manufacturing 2 Fluorene 420 Iron and steel manufacturing 1 Carbon tetrachloride 420 Iron and steel manufacturing 1 Chlorodibromomethane420 Iron and steel manufacturing 4 Naphthalene

420 Iron and steel manufacturing 2 Tetrachloroethy lene 420 Iron and steel manufacturing 4 Antim ony 420 Iron and steel manufacturing 1 Acenaphthylene 420 Iron and steel manufacturing 1 Acenaphthene 420 Iron and steel manufacturing 1 Strontium 420 Iron and steel manufacturing 1 Trichloroethy lene 420 Iron and steel manufacturing 1 Chloroform 420 Iron and steel manufacturing 1 Vanadium 420 Iron and steel manufacturing 1 Xylene 420 Iron and steel manufacturing 1 1,1,1-Trichloroethane 420 Iron and steel manufacturing 1 BerylliumRepublic Conduit submitted changes to their chromium, hexavalent discharges after the static DMR 2011 database was pulled. Therefore, the rankings were updated with this change.

**TWPE % of Total** 

**TWPE Pollutant TWPE**  47,788.13 19% 34,229 37513.45 15% 18,423 34131.827 14% 34,132 28,595.93 12% 28,596 Corrected DMR TW PE: 15851.954 6% 15,852 12599.777 5% 12290.729 5% 163,881.30 8,472.90 3% 8329.3545 3% 6885.3016 3% 6688.7733 3% 4,855.33 2% 4635.4215 2% 2975 1% 2,106.59 1% 1888.5872 1% 1706.0822 1% 1628.4627 1% 1448.9363 1% 1166.2624 0% 649.68862 0% 643.14909 0% 572.48421 0% 510.91109 0% 413.51136 0% 410.73748 0% 278.26225 0% 269.04393 0% 256.73798 0% 243.0116 0% 111.02558 0% 109.82318 0% 77.70121 0% 56.954036 0% 31.864444 0% 28.009384 0% 14.012539 0% 14.010086 0% 7.239893 0% 3.300746 0% 3.1271753 0% 2.5450456 0% 2.0785034 0% 0.8047359 0% 0.6489783 0% 0.3980766 0% **Corrected Category DMR TWPE** 213,622 **Corrected Top 5 Pollutant TWPE**

131,232 **Corrected Data after 2013 A nnual Review was** 

**Completed**0.3220258 0%

0.2433926 0% 0.1452544 0% 0.1296625 0% 0.0925042 0% 0.0345892 0% 0.0271849 0% 0.017409 0% 0.0166684 0% 0.0107855 0% 0.0074761 0% 0.0032625 0% 246,270.94**JRK QC**

32,785.13 23.58% 73.05% 8,891 18.51%

16.84% Corrected DMR TW PE: 14.11% 202,645.94 7.82% 6.22% 6.07% 4.18% 4.11% 3.40% 3.30%**420 - Iron and Steel - Pollutant Data**

From DMR Database: TSD 02 - Facility Discharges query
Facilities Reviewed as part of the 2013 ARR

**Fluoride Discharges PSC**  **Code NPDES ID**  **FA CILITY_NA** **ME** 420 PA0094510 USS MON VALLEY W ORKS - EDGAR T HOMSON PLANT 420 IN0000205 ARCELORMITTAL INDIANA HARBOR LLC 420 IN0000281 USS GARY W ORKS 420 WV 0003336 WE IRTON STEEL CORPORATION 420 IL0000329 US STEEL GRANITE CITY W ORKS 420 IN0000175 ARCELORMITTAL BURNS HARBOR LLC 420 OH0009997 AK STEEL CORP 420 WV 0004499 MOUNTAIN STATE CARBON FOLLANSBEE PLANT 420 OH0006912 REPUBLIC STEEL CANTON FACILITY 420 IN0054682 NUCOR STEEL 420 OH0129003 UNITED STATES STEEL CORP 420 PA0006327 ALLEGHENY LUDLUM BAGDAD 420 PA0003239 PENN STATE SPECIAL METALS LLC 420 PA0011568 ARCELORMITTAL PLATE LLC COATESVILLE FACILITY 420 IN0045284 ALLEGHENY LUDLUM CORP 420 OH0000957 ARCELORMITTAL CLEVELAND INC 420 CT0003701 ALLEGHENY LUDLUM STEEL STRIP PLANT

**Al uminum**  **PSC Code**  **NPDES ID FA** **CILITY_NA ME**  420 AL0070068 NUCOR STEEL DECATUR LLC 420 KY0002712 IPSCO TUBULARS (KENTUCKY) INC 420 PA0013820 ALLEGHENY LUDLUM LLC 420 WV 0003336 WE IRTON STEEL CORPORATION 420 WV 0004499 MOUNTAIN STATE CARBON FOLLANSBEE PLANT 420 AL0003646 USS FAIRFIELD W ORKS 420 TX0087599 DELTA TUBULAR PROCESSING 420 PA0000868 JMC STEEL GROUP W HEATLAND TUBE DIV COUNCIL 420 AL0054941 NUCOR STEEL TUSCALOOSA INC 420 PA0006327 ALLEGHENY LUDLUM BAGDAD 420 AL0065773 USS FAIRFIELD W ORKS 420 PA0013463 US STEEL FAIRLESS HILLS W ORKS 420 AL0003735 NUCOR STEEL BIRMINGHAM INC 420 WV 0004502 WH EELING-NISSHIN 420 CT0003701 ALLEGHENY LUDLUM STEEL STRIP PLANT 420 TX0007706 JSW STEEL USA PIPE COATING DIVISION 420 CT0026794 NUCOR STEEL CONNECTICUT, INC. 420 WV 0023281 MOUNTAIN STATE CARBON FOLLANSBEE PLANT

**Cyanide PSC**  **Code NPDES ID**  **FA CILITY_NA** **ME** 420 PA0004472 USS - CLAIRTON PLANT420 WV 0004499 MOUNTAIN STATE CARBON FOLLANSBEE PLANT

420 WV 0003336 WE IRTON STEEL CORPORATION 420 IN0000175 ARCELORMITTAL BURNS HARBOR LLC 420 PA0002437 SHENANGO INC 420 OH0011274 ARCELORMITTAL W ARREN INC 420 AL0003247 SLOSS INDUSTRIES CORPORATION COKE PLANT 420 AL0003417 ABC COKE 420 IN0000094 HARSCO METALS ECR 420 CO0000621 EVRAZ ROCKY MOUNTAIN STEEL

420 MI0043524 FORD MOTOR CO ROUGE POW ER & UTILITIES OPERATIONS 420 IN0000205 ARCELORMITTAL INDIANA HARBOR LLC 420 KY0000558 AK STEEL ASHLAND W ORKS - COKE PLANT 420 IL0000329 US STEEL GRANITE CITY W ORKS 420 IN0000281 USS GARY W ORKS 420 MD0001201 RG STEEL SPARROW S POINT LLC 420 KY0000485 AK STEEL ASHLAND W ORKS - COKE PLANT 420 OH0009997 AK STEEL CORP 420 OH0000957 ARCELORMITTAL CLEVELAND INC 420 MI0026786 UNITED STATE STEEL-GREAT LAKES 420 CA0005002 USS-POSCO INDUSTRIES 420 OH0011363 THOMAS STEEL STRIP CORP 420 AL0001767 EMPIRE COKE COMPANY 420 AL0003646 USS FAIRFIELD W ORKS 420 AR0036552 BEKAERT CORP 420 KY0092118 PRECOAT METALS

**Total Residual Chlorine PSC**  **Code NPDES ID**  **FA CILITY_NA** **ME**

420 PA0094510 USS MON VALLEY W ORKS - EDGAR T HOMSON PLANT 420 PA0004472 USS - CLAIRTON PLANT 420 WV 0003336 WE IRTON STEEL CORPORATION 420 MD0001201 RG STEEL SPARROW S POINT LLC

420 TX0000027 US STEEL TUBULAR PRODUCTS INC TEXAS OPERATIONS DIV 420 PA0002437 SHENANGO INC 420 PA0005754 ALLEGHENY TECHNOLOGIES MIDLAND PLANT 420 NY0269310 ARCELORMITTAL TECUMSEH REDEVELOPMENT 420 KY0000485 AK STEEL ASHLAND W ORKS - COKE PLANT 420 OH0000957 ARCELORMITTAL CLEVELAND INC 420 OH0006912 REPUBLIC STEEL CANTON FACILITY 420 NY0001368 ARCELORMITTAL LACKAW ANNA LLC 420 IL0000612 ALTON STEEL INC 420 PA0013463 US STEEL FAIRLESS HILLS W ORKS 420 PA0006335 IPSCO KOPPEL TUBULARS CORP

420 OH0011371 WH EELING-PITTSBURGH STEEL CORP YORKVILLE PLANT 420 WV 0004499 MOUNTAIN STATE CARBON FOLLANSBEE PLANT 420 SC0047392 NUCOR STEEL CORPORATION 420 KY0098221 GALLATIN STEEL CO 420 IN0000337 AMERICAN IRON OXIDE CO PORTAGE 420 NE0111287 NUCOR STEEL NEBRASKA420 WV 0004502 WH EELING-NISSHIN

420 KY0000558 AK STEEL ASHLAND W ORKS - COKE PLANT 420 CT0026794 NUCOR STEEL CONNECTICUT, INC. 420 PA0003239 PENN STATE SPECIAL METALS LLC 420 AR0049166 IPSCO TUBULARS INC 420 IN0000094 HARSCO METALS ECR 420 AL0054941 NUCOR STEEL TUSCALOOSA INC 420 IL0076627 ATLAS TUBE INC**CITY State**  **Ma jor/Mi** 
**nor Group** 

**Code Group Desc**  **LBY TWPE**  BRADDOCK PA M F Fluoride 697715.2222 20931.46 EAST CHICAGO IN M F Fluoride 500103.0842 15003.09 GARY IN M F Fluoride 339402.9 10182.09 WE IRTON WV M F Fluoride 331192.6356 9935.779 GRANITE CITY IL M F Fluoride 162786 4883.58 BURNS HARBOR IN M F Fluoride 84725.13776 2541.754 MIDDLETOW N OH M F Fluoride 74869.83714 2246.095 FOLLANSBEE WV M F Fluoride 53178.99056 1595.37 CANTON OH M F Fluoride 23033.61795 691.0085 CRAW FORDSVILLE IN N F Fluoride 9202.104278 276.0631 LORAIN OH M F Fluoride 8055.439622 241.6632 LEECHBURG PA M F Fluoride 1721.763493 51.6529 KOPPEL PA M F Fluoride 1631.353757 48.94061 COATESVILLE PA M F Fluoride 1500.513522 45.01541 NEW CASTLE IN M F Fluoride 266.4 7.992 CLEVELAND OH M F Fluoride 198.5134613 5.955404 WA LLINGFORD CT M F Fluoride 124.8144993 3.744435

2289708.328 68691

**CITY State**  **Ma jor/Mi** 
**nor Group** 

**Code Group Desc**  **LBY TWPE**  TRINITY AL M AL Alum inum 477029.2098 28621.75 WI LDER KY N AL Alum inum 42781.92881 2566.916 BRACKENRIDGE PA M AL Alum inum 37427.17826 2245.631 WE IRTON WV M AL Alum inum 35393.44815 2123.607 FOLLANSBEE WV M AL Alum inum 14300.7219 858.0433 FAIRFIELD AL M AL Alum inum 8430.962464 505.8577 HOUSTON TX N AL Alum inum 3204.335337 192.2601 WH EATLAND PA M AL Alum inum 1993.94 119.6364 TUSCALOOSA AL N AL Alum inum 1520.632543 91.23795 LEECHBURG PA M AL Alum inum 814.3263407 48.85958 FAIRFIELD AL N AL Alum inum 782.7209069 46.96325 FAIRLESS HILLS PA M AL Alum inum 670.206379 40.21238 BIRMINGHAM AL N AL Alum inum 442.0768871 26.52461 FOLLANSBEE WV M AL Alum inum 209.8376931 12.59026 WA LLINGFORD CT M AL Alum inum 158.172461 9.490348 BAYTOW N TX M AL Alum inum 43.74829485 2.624898 WA LLINGFORD CT N AL Alum inum 13.98497656 0.839099 FOLLANSBEE WV N AL Alum inum 6.73466072 0.40408 37513.449 9529679

**CITY State**  **Ma jor/Mi** 
**nor Group** 

**Code Group Desc**  **LBY TWPE**  CLAIRTON PA M CN Cyanide 12141.283 13476.82FOLLANSBEE WV M CN Cyanide 6340.469209 7037.921

WE IRTON WV M CN Cyanide 2447.2947 2716.497 BURNS HARBOR IN M CN Cyanide 1817.22 2017.114 PITTSBURGH PA M CN Cyanide 1663.41659 1846.392 WA RREN OH M CN Cyanide 1012.580611 1123.964 BIRMINGHAM AL M CN Cyanide 966.2461287 1072.533 TARRANT AL M CN Cyanide 793.09 880.3299 EAST CHICAGO IN M CN Cyanide 670.2908389 744.0228 PUEBLO CO M CN Cyanide 593.5566221 658.8479

DEARBORN MI M CN Cyanide 411.33 456.5763 EAST CHICAGO IN M CN Cyanide 389.0230909 431.8156 ASHLAND KY M CN Cyanide 376.9 418.359 GRANITE CITY IL M CN Cyanide 334.5 371.295 GARY IN M CN Cyanide 236.540165 262.5596 SPARROW S POINT MD M CN Cyanide 159.88 177.4668 ASHLAND KY M CN Cyanide 157.63 174.9693 MIDDLETOW N OH M CN Cyanide 104.958 116.5034 CLEVELAND OH M CN Cyanide 65.418381 72.6144 RIVER ROUGE MI M CN Cyanide 47.98145455 53.25941 PITTSBURG CA M CN Cyanide 9.769405968 10.84404 WA RREN OH M CN Cyanide 6.139534507 6.814883 TUSCALOOSA AL N CN Cyanide 1.480400177 1.643244 FAIRFIELD AL M CN Cyanide 0.9465 1.050615 VAN BUREN AR M CN Cyanide 0.9135 1.013985 HAW ESVILLE KY M CN Cyanide 0.536 0.59496 34131.827 4852755

**CITY State**  **Ma jor/Mi** 
**nor Group** 

**Code Group Desc**  **LBY TWPE** 

BRADDOCK PA M CHLOR Total Residual Chlorine 95051.82938 47525.91 CLAIRTON PA M CHLOR Total Residual Chlorine 28013.7424 14006.87 WE IRTON WV M CHLOR Total Residual Chlorine 10972.91061 5486.455 SPARROW S POINT MD M CHLOR Total Residual Chlorine 5584.37526 2792.188

LONE STAR TX M CHLOR Total Residual Chlorine 3475.660466 1737.83 PITTSBURGH PA M CHLOR Total Residual Chlorine 2076.870917 1038.435 MIDLAND PA M CHLOR Total Residual Chlorine 2067.494271 1033.747 LACKAW ANNA NY N CHLOR Total Residual Chlorine 1526.830217 763.4151 ASHLAND KY M CHLOR Total Residual Chlorine 1490.920883 745.4604 CLEVELAND OH M CHLOR Total Residual Chlorine 556.4996023 278.2498 CANTON OH M CHLOR Total Residual Chlorine 231.8497965 115.9249 BLASDELL NY M CHLOR Total Residual Chlorine 188.7647933 94.3824 ALTON IL M CHLOR Total Residual Chlorine 150.1398691 75.06993 FAIRLESS HILLS PA M CHLOR Total Residual Chlorine 131.1836695 65.59183 AMBRIDGE PA M CHLOR Total Residual Chlorine 85.88699612 42.9435

YORKVILLE OH M CHLOR Total Residual Chlorine 78.00394068 39.00197 FOLLANSBEE WV M CHLOR Total Residual Chlorine 65.64253927 32.82127 HUGER SC M CHLOR Total Residual Chlorine 59.54199889 29.771 WA RSAW KY N CHLOR Total Residual Chlorine 40.17743469 20.08872 PORTAGE IN M CHLOR Total Residual Chlorine 37.57031546 18.78516 NORFOLK NE M CHLOR Total Residual Chlorine 30.17741443 15.08871FOLLANSBEE WV M CHLOR Total Residual Chlorine 26.50728208 13.25364

ASHLAND KY M CHLOR Total Residual Chlorine 13.61053462 6.805267 WA LLINGFORD CT N CHLOR Total Residual Chlorine 6.711699515 3.35585 KOPPEL PA M CHLOR Total Residual Chlorine 3.005352418 1.502676 BLYTHEVILLE AR N CHLOR Total Residual Chlorine 0.851619856 0.42581 EAST CHICAGO IN M CHLOR Total Residual Chlorine 0.213288459 0.106644 TUSCALOOSA AL N CHLOR Total Residual Chlorine 0.053053376 0.026527 CHICAGO IL N CHLOR Total Residual Chlorine 0.010632708 0.005316 75983.518 1177375**% of Total TWPE TWPE**  **% LBS**  **Corrected Facility TWPE**  30.47% 28.34 0.06% 944.67 21.84% 31.39% 1443.92 14.82% 21.31% 14.46% 20.79% 7.11% 10.22% 3.70% 5.32% 3.27% 4.70% 2.32% 3.34% 1.01% 1.45% 0.40% 0.58% 0.35% 0.51% 0.08% 0.11% 0.07% 0.10% 0.07% 0.09% 0.01% 0.02% 0.01% 0.01% 0.01% 0.01% Revised Pollutant TW PE: 47789 Revised Pollutant Total Pounds: 1591993.106

**% of Total TWPE TWPE**  **% LBS**  **Corrected Facility TWPE**  76.30% NA NA NA 9,531.50 6.84% 5.99% 5.66% 2.29% 1.35% 0.51% 0.32% 0.24% 0.13% 0.13% 0.11% 0.07% 0.03% 0.03% 0.01% 0.00% 0.00%

**% of Total TWPE TWPE**  **% LBS** 

39.48% NA NA NA **Corrected Data after 2013 A nnual Review**  **was Completed Corrected Data for USS Mon Valley** 

**Corrected Data for USS Mon Valley**

**Corrected Data for USS Mon Valley**20.62% 7.96% 5.91% 5.41% 3.29% 3.14% 2.58% 2.18% 1.93%

1.34% 1.27% 1.23% 1.09% 0.77% 0.52% 0.51% 0.34% 0.21% 0.16% 0.03% 0.02% 0.00% 0.00% 0.00% 0.00%

**% of Total TWPE TWPE**  **% LBS** 

62.55% 138.33 0.48% 276.66 18.43% 48.98% 7.22% 19.19% 3.67% 9.76%

2.29% 6.08% 1.37% 3.63% 1.36% 3.62% 1.00% 2.67% 0.98% 2.61% 0.37% 0.97% 0.15% 0.41% 0.12% 0.33% 0.10% 0.26% 0.09% 0.23% 0.06% 0.15%

0.05% 0.14% 0.04% 0.11% 0.04% 0.10% 0.03% 0.07% 0.02% 0.07% 0.02% 0.05%

**Corrected Data for USS Mon Valley**0.02% 0.05% 0.01% 0.02% 0.00% 0.01% 0.00% 0.01% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% Revised Pollutant TW PE: 28595.93 Revised Pollutant Total Pounds: 57191.87**New Pollutant TWPE**
34,229

0.00% 12638.83 421294.5

**New Pollutant TWPE**

18,423 **Corrected Data after 2013 A nnual Review** 

**was Completed 420 - Iron and Steel** 

**Ar celormittal Indiana Harbor LLC**  **East Chicago, IN** IN0000205 (TRI ID: 46312LTVST3001D)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** Divide 5/31/11 concentration from Outfall 010 by 100. Corrected fluoride TW PE = 1,444. Corrected facility TW PE = 5,350
**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.

**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable**  **Load (lbs/yr) Total TWPE** 

**(lbs-eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)**
Fluoride 500,103 15,003 Lead 1,321 3,713 2,959 8,317 Cyanide 389 432 Zinc 8,017 9,000 321 360 Chloride 3,514,284 85.5 Iron 9,043 50.6 Sulfate 6,424,311 35.9 Am mo nia as N 20,304 219,000 22.5 243 Cadmium 0 740 Total Residual Chlorine 0 8,948 Solids, total suspended 1,755,677 1,143,950 Total phenols 13.2 7,665 18,910

**Date Outfall**  **Fluoride Concentration**  **(mg/L) Wastewater** 

**Flow(MGD) Corrected Load** 

**(lb/period)** 5/31/2011 10 0.36 44.9 4182.01

Issues at Outfall 010
Fluoride, Outfall 009

Occurred? No Reported? Yes Estim ated? No Occurred? No Reported? Yes Estim ated? No Occurred? Yes 3/31/2011 No Concentration (mg/L) 0.4 2/28/2011 No Concentration (mg/L) 1/31/2011 No Concentration (mg/L) **Corrected Data**

**Fluoride: View Details**

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 009 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No

Fluoride, Outfall 010

Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes 6/30/2011 No Concentration (mg/L) 5/31/2011 No Concentration (mg/L) 36 4/30/2011 No Concentration (mg/L) 3/31/2011 No Concentration (mg/L) 0.46 2/28/2011 No Concentration (mg/L) 1/31/2011 No Concentration (mg/L) Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 010 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  Annual Load from Monitoring Data (lb/yr)
Number of Months Requiring Estimation

11/30/2011 No Concentration (mg/L) 10/31/2011 No Concentration (mg/L) 9/30/2011 No Concentration (mg/L) 0.28 8/31/2011 No Concentration (mg/L) 7/31/2011 No Concentration (mg/L) 6/30/2011 No Concentration (mg/L) 5/31/2011 No Concentration (mg/L) 0.36 4/30/2011 No Concentration (mg/L) (mg/L)Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No

Fluoride, Outfall 011

Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes 10/31/2011 No Concentration (mg/L) 9/30/2011 No Concentration (mg/L) 0.84 8/31/2011 No Concentration (mg/L) 7/31/2011 No Concentration (mg/L) 6/30/2011 No Concentration (mg/L) 5/31/2011 No Concentration (mg/L) 0.82 4/30/2011 No Concentration (mg/L) 3/31/2011 No Concentration (mg/L) 1.6 2/28/2011 No Concentration (mg/L) 1/31/2011 No Concentration (mg/L) Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 011 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

11/30/2011 No Concentration (mg/L) 10/31/2011 No Concentration (mg/L) 9/30/2011 No Concentration (mg/L) 0.29 8/31/2011 No Concentration (mg/L) 7/31/2011 No Concentration (mg/L)Estimated? No Occurred? No Reported? Yes Estimated? No

FLUORIDE 78,590 NA 57,316 NA Annual Load (lb/yr)

**Chemical Group 2007 DMR (lbs/yr)**  **2007 TRI (lbs/yr) 2008 DMR**  **(lbs/yr) 2008 TRI (lbs/yr)**  Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

11/30/2011 No Concentration (mg/L)Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

**Corrected Facility TWPE**  Corrected Load TW F

5,350 44,121 0.03

**Corrected Total Load for**  **Outfall 010 Outfall 010** 

**Load with Months**  **Estimated Corrected Total** 

**Fluoride Load for all Outfalls**  **Fluoride TWF Total Corrected Fluoride**  **TWPE** 12,811 13,976 48,131 0.03 1,444

**Monitoring Period Load (lb/period)** 

31 3,531 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × 34.1 33.95 28 No Load Calculated 34.2 31 No Load Calculated **Corrected Data**

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**9,098

9,925

**Monitoring Period Load**  **(lb/period)**

44.4 30 No Load Calculated 44.9 31 418,490 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 5,362 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 44.9 30 45.05

No Load Calculated 44.65 28 No Load Calculated 44.8 31 No Load Calculated Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation** 30 No Load Calculated

Sum of Monitoring Period Loads

1 34.2 34.29 31 No Load Calculated 34.1 30 2,396 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 No Load Calculated

34.02 31 33.8

No Load Calculated 33.9 30 No Load Calculated 34.05 31 3,172 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 (MGD) × 3.785 (L/gal) × Number of Days × 2.205 34.1 30 No Load Calculated427,119
465,948

**Monitoring Period**

**Load (lb/period)** 

36.3 31 No Load Calculated 35.7 30 7,517 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 No Load Calculated

34.7 31 33.4

No Load Calculated 31.9 30 No Load Calculated 32.84 31 6,967 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 7,727 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 18.9 30 18.6

No Load Calculated 13.7 28 No Load Calculated 13.41 31 No Load Calculated Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation** 30 No Load Calculated

Sum of Monitoring Period Loads 1 45.2 45.3 31 No Load Calculated 44.9 30 3,267 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 No Load Calculated

43.2 31 44.3

No Load Calculated22,211
24,230

72,635 NA 49,863 NA 500,103

**2009 TRI (lbs/yr)**  **2010 TRI (lbs/yr)** Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**2009 DMR (lbs/yr)**  **2010 DMR (lbs/yr)**  **2011 DMR (lbs/yr)**

30 No Load Calculated

Sum of Monitoring Period Loads 1 37.3Total TW PE

1323.63

5230.13

72.34%

Total TW PE 0

100.00%KB QC

0.36 4182.00948 0.36 4182.009 **Corrected Concentration**  **(mg/L) Corrected** 

**Load (lb/period)** 12,811

13976NA

**2011 TRI (lbs/yr)** **420 - Iron and Steel**

**USS Gary Works Gary, IN**  IN0000281 (TRI ID: 46402SSGRYONENO)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** Back-calculated the concentration from the mass data.

**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.
**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable** 

**Load (lbs/yr) Total TWPE (lbs** 

**eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)** Fluoride 339,403 10,182 Copper 1,479 1,387 932 874 Lead 727 12,035 Cyanide 263 1,334 Selenium 262 858 Zinc 4,784 191 Chloride 5,419,516 132 Benzo[a]pyrene 124 14,776 Mercury 113 Am mo nia as N 82,812 91.9 Sulfate 5,739,316 Solids, total suspended 1,003,339 1,487,740
BOD, carbonaceous, 05 day , 20C 559,914 1,361,329
Oil and grease 549,085 1,451,970 Total phenols 3,142 9,490

No obvious issues.
Fluoride, Outfall 005

**Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Limit** Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes 4/30/2011 No Quantity (kg/day) 100 3/31/2011 No Quantity (kg/day) 82.5 Compare fluoride discharges to treatable levels.

**Fluoride: View Details**

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 005

2/28/2011 No Quantity (kg/day) 113 1/31/2011 No Quantity (kg/day) 82.08Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

Fluoride, Outfall 028

Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes 4/30/2011 No Quantity (kg/day) 79.8 3/31/2011 No Quantity (kg/day) 84.3 2/28/2011 No Quantity (kg/day) 74.009 1/31/2011 No Quantity (kg/day) 79.3 Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 028

**Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Limit** Annual Load from Monitoring Data (lb/yr)
Number of Months Requiring Estimation

12/31/2011 No Quantity (kg/day) 90.7 11/30/2011 No Quantity (kg/day) 83.4 10/31/2011 No Quantity (kg/day) 82.9 9/30/2011 No Quantity (kg/day) 78.4 8/31/2011 No Quantity (kg/day) 85.7 7/31/2011 No Quantity (kg/day) 94.3 6/30/2011 No Quantity (kg/day) 92.9 5/31/2011 No Quantity (kg/day) 82.5Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No

Fluoride, Outfall 030

Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes 3/31/2011 No Quantity (kg/day) 240 2/28/2011 No Quantity (kg/day) 268 1/31/2011 No Quantity (kg/day) 210 Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 030

**Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Limit** Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

12/31/2011 No Quantity (kg/day) 126 11/30/2011 No Quantity (kg/day) 73.9 10/31/2011 No Quantity (kg/day) 97.5 9/30/2011 No Quantity (kg/day) 69.8 8/31/2011 No Quantity (kg/day) 74.8 7/31/2011 No Quantity (kg/day) 77.09 6/30/2011 No Quantity (kg/day) 72.6 5/31/2011 No Quantity (kg/day) 80.2Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No Occurred? Yes
Reported? Yes Estimated? No

FLUORIDE 78,467 NA 92,425 NA 68,285 Annual Load (lb/yr)

**Chemical Group 2007 DMR**  **(lbs/yr) 2007 TRI (lbs/yr)**  **2008 DMR (lbs/yr)**  **2008 TRI (lbs/yr) 2009 DMR**  **(lbs/yr)** Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

12/31/2011 No Quantity (kg/day) 279 11/30/2011 No Quantity (kg/day) 254 10/31/2011 No Quantity (kg/day) 285 9/30/2011 No Quantity (kg/day) 266 8/31/2011 No Quantity (kg/day) 253 7/31/2011 No Quantity (kg/day) 244 6/30/2011 No Quantity (kg/day) 228 5/31/2011 No Quantity (kg/day) 240 4/30/2011 No Quantity (kg/day) 237Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

**Wastewater Flow (MGD)**  **Number**

**of Days Monitoring Period** 

**Load (lb/period) Equation**  **Back-Calculated Concentration (mg/L)** 

0.424

0.601

0.465

0.512 30 6,630 Daily Load (kg/day) × Number 51.6 46.9 31 5,642 Daily Load (kg/day) × Number of Days × 2.205 5,611 Daily

Load (kg/day) × Number of Days × 2.205 49.7 28 7,000 51.1 31

Daily Load (kg/day) × Number of Days × 2.2050.501

0.531 0.53

0.516 0.52

0.417 0.42

0.434 0.43

0.477 0.48

0.523 0.52

0.518 0.52
71,565

71,565

**Monitoring Period**

**Load (lb/period)** 

2.91 2.91

2.92 2.92

2.93 2.93

3.01 3.01 **Back-Calculated Concentration (mg/L)** 

31 5,766 Daily Load (kg/day) × Number of Days × 2.205

7 30 7.6

5,280 Daily Load (kg/day) × Number of Days × 2.205 6.7 28 4,569 Daily Load (kg/day) × Number of Days × 2.205 7.2 31 5,425 Daily Load (kg/day) × Number of Days × 2.205 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Wastewater Flow (MGD)**  **Number**

**of Days Equation**  31 6,200 Daily Load (kg/day) × Number of Days × 2.205 Sum of Monitoring Period Loads

0 46.3 42.1 30 5,520 Daily Load (kg/day) × Number of Days × 2.205 45.9 31 5,673 Daily Load (kg/day) × Number of Days × 2.205 31 5,859 Daily Load (kg/day) × Number of Days × 2.205 47.7 30 54.3

5,190 Daily Load (kg/day) × Number of Days × 2.205 48.3 31 6,448 Daily Load (kg/day) × Number of Days × 2.205 46.26 30 6,150 Daily Load (kg/day) × Number of Days × 2.205 (kg/day) × Number of Days × 2.205 43.5 31 5,642 Daily Load (kg/day) × Number of Days × 2.2053.16 3.17

2.96 2.96

3.77 3.77

3.41 3.41

3.29 3.30

3.43 3.43

2.91 2.91

3.50 3.49
66,482
66,482

**Monitoring Period**

**Load (lb/period)** 

2.86 2.85

3.32 3.32

2.79 2.79 **Back-Calculated Concentration (mg/L)** 

31 16,430 Daily Load (kg/day) × Number of Days × 2.205 22.76 21.31 28 16,550 Daily Load (kg/day) × Number of Days × 2.205 19.43 31 14,322 Daily Load (kg/day) × Number of Days × 2.205 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Wastewater Flow (MGD)**  **Number**

**of Days Equation**  8,587 Daily

Load (kg/day) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 30 4,890 Daily Load (kg/day) × Number of Days × 2.205

9.5 31 6.7 7.5 31 6,665 Daily Load (kg/day) × Number of Days × 2.205 5.6 30 4,620 Daily Load (kg/day) × Number of Days × 2.205 31 5,270 Daily Load (kg/day) × Number of Days × 2.205

5.8 31 5.4

5,115 Daily Load (kg/day) × Number of Days × 2.205 6.48 30 4,808 Daily Load (kg/day) × Number of Days × 2.205 6.7 31 5,487 Daily Load (kg/day) × Number of Days × 2.2052.83 2.83

3.01 3.01

3.09 3.09

3.69 3.69

3.41 3.41

3.70 3.70

3.50 3.50

3.13 3.12

3.57 3.56
201,356
201,356

NA 273,120 NA 339,403 NA

**2010 TRI (lbs/yr) 2011 DMR (lbs/yr)**  **2011 TRI (lbs/yr)** Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**2009 TRI (lbs/yr)**  **2010 DMR**

**(lbs/yr)** 19,040 Daily Load (kg/day) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 30 16,770 Daily Load (kg/day) × Number of Days × 2.205

20.65 31 21.44 21.5 31 19,468 Daily Load (kg/day) × Number of Days × 2.205 18.99 30 17,610 Daily Load (kg/day) × Number of Days × 2.205 31 16,709 Daily Load (kg/day) × Number of Days × 2.205

19.59 31 17.49

17,267 Daily Load (kg/day) × Number of Days × 2.205 19.48 30 15,070 Daily Load (kg/day) × Number of Days × 2.205 21.09 31 16,430 Daily Load (kg/day) × Number of Days × 2.205 22.15 30 15,690 Daily Load (kg/day) × Number of Days × 2.205**KB QC**

\ 0.424 Min Conc 0.417 Max Conc 3.77 0.601

0.4650.512

0.501

0.531

0.516

0.417

0.434

0.477

0.523

0.518

2.91

2.92

2.93

3.013.16

2.96

3.77

3.41

3.29

3.43

2.91

3.50

2.86

3.32

2.792.83

3.01

3.09

3.69

3.41

3.70

3.50

3.13

3.57**420 - Iron and Steel**

**Weirton Steel Corporation Weirton, WV**  WV0003336 (TRI ID: 26062W RTNS400TH)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** The facility

discharges cooling water, stormwater runoff, and process water from both outfalls. The facility’s permit calls for monitoring of fluoride discharges from outfall 003, but does not include fluoride limits . The fluoride permit limit for outfall 004 is 1.4 mg/L on an average monthly basis and 2.2 mg/L daily m aximum. Compare fluoride discharges to treatable levels.
**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.

**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable**  **Load (lbs/yr) Total TWPE (lbs** 

**eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)**
Chromium 165,495 33,080 11,585 2,316 Fluoride 331,193 8,271 9,936 248 Total Residual Chlorine 10,973 5,486
Cyanide 2,716 14,509 Alum inum 35,393 2,124 Manganese 12,153 851 Iron 122,337 685 2,427 Chromium, Hexavalent 565 2,645
Chromium, Trivalent 511 1,467 Sulfate 10,312,760 331 7,365 Solids, total suspended 796,255
Oil and grease 145,155 Nitrogen 98,352

Issues at Outfall 003
Fluoride, Outfall 003

Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes 6/30/2011 No Concentration (mg/L) 8.32 8 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Limit**

9/30/2011 No Concentration (mg/L) 22.04 **Fluoride: View Details**

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 003

3/31/2011 No Concentration (mg/L)Estimated? No Occurred? Yes Reported? Yes Estimated? No

Fluoride, Outfall 004

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

**Chemical Group 2007 DMR (lbs/yr)**  **2007 TRI (lbs/yr) 2008 DMR**  **(lbs/yr) 2008 TRI (lbs/yr)**  **2009 DMR (lbs/yr)**  Annual Load (lb/yr) Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

12/31/2011 No Concentration (mg/L) 0.37 1.4 11/30/2011 No Concentration (mg/L) 0.36 1.4 10/31/2011 No Concentration (mg/L) 0.53 1.4 9/30/2011 No Concentration (mg/L) 0.48 1.4 8/31/2011 No Concentration (mg/L) 0.43 1.4 7/31/2011 No Concentration (mg/L) 0.73 1.4 Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Fluoride (00951) for Outfall 004 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit?** 12/31/2011 No Concentration (mg/L) 5.82

**Me asurement**  **Ty pe**  **Av g Daily Value**  **Limit** Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

6/30/2011 No Concentration (mg/L) 0.507 1.4 5/31/2011 No Concentration (mg/L) 0.24 1.4 4/30/2011 No Concentration (mg/L) 0.32 1.4 3/31/2011 No Concentration (mg/L) 0.23 1.4 2/28/2011 No Concentration (mg/L) 0.26 1.4 1/31/2011 No Concentration (mg/L) 0.19 1.4FLUORIDE 20,280 NA 308,514 NA 297,091Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

The facility’s permit calls for monitoring of fluoride discharges from outfall 003, but does not include fluoride limits .

Min **Monitoring Period Load**  Max **(lb/period)**

92 10.99

183,444 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × 7.86 90 47,231 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 **Wastewater Flow (MGD)**  **Number of**

**Days**

91 69,444 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 10.84 **Equation**329,176
329,176

**Monitoring Period Load**  **(lb/period)**

2,016
2,016

**2009 TRI (lbs/yr)**  **2010 DMR**

**(lbs/yr) 2010 TRI (lbs/yr)**  **2011 DMR (lbs/yr) 2011 TRI**  **(lbs/yr)** Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

110 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Sum of Monitoring Period Loads 0 30 118 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 1.14 31 1.3 0.58 31 80.5 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.79 30 96.5 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 234 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 1.04 31 1.23

118 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - 6.5 92 29,057

**Wastewater Flow (MGD)**  **Number of**

**Days Equation**  Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Sum of Monitoring Period Loads Number of Days × 2.205

2.47 215 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 30 314 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 30 271 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 3.39 31 3.37 3.14 31 190 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 126 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 2.38 28 145 2.49 31

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205NA 222,552 NA 331,193 N0.19

22.04**420 - Iron and Steel**

**Nucor Steel Decatur LLC Trinity, A** **L** AL0070068 (TRI ID: 35603TRCST4301H)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:**

Correct 12/2011 concentration for outfall 011 based on data from facility contact, drops Al TW PE to 9,530. Corrected facility

TW PE = 10,716.
**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.

**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable** 

**Load (lbs/yr) Total TWPE** 

**(lbs-eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)**
Alum inum 28,622 Chromium 469 Copper 661 416 Zinc 231 Lead 29.7 66.5 Cadmium 1.703 Nickel 0.019 Total Residual Chlorine 0 2.35
Solids, total suspended 12,843,313
Solids, total dissolved 7,096,316
Chemical oxygen dem and (COD) 1,095,713
Oil and grease 15,592 610,255 1,184 1184.222 BOD, 5-day , 20 deg. C 5,472 29,806 7.570818182

**Date Outfall**  **Al uminum**  **Concentration (mg/L)**  **Wastewater**

**Flow(MGD) Corrected Load** 

**for 12/31/11 (lb/period)**  12/31/2011 11 0.463 0.53 188.42

Issues at Outfall 011

Alum inum , Outfall 002 The facility

contact confirmed the 2011 discharges and stated that the December 2011 aluminum concentration reading for outfall 011 of 775 mg/L was taken immediately following a m ajor precipitation event. Therefore, it did not represent typical daily discharges during the 92 day
mo nitoring period. The facility performed additional sampling on January 26, 2012, and provided EPA a revised value of 0.463 m g/L for aluminum at outfall 011.

**Al uminum: View Details** 

2011 Monitoring Period-Level Loads for Alum inum (01105) for Outfall 002 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Facility Provided Data - 1/31/14**Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 003

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 004

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

3/31/2011 No Concentration (mg/L) 1.59 **Information Limit?**  **Ty pe** 

6/30/2011 No Concentration (mg/L) 4.99

9/30/2011 No Concentration (mg/L) 5.65

12/31/2011 No Concentration (mg/L) 0.804

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 003 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

Concentration (mg/L) 0.22

12/31/2011 No Concentration (mg/L) 28.4 6/30/2011 No

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 004 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

3/31/2011 No Concentration (mg/L) 14.3

6/30/2011 No Concentration (mg/L) 24.3

9/30/2011 No Concentration (mg/L) 12.4

12/31/2011 No Concentration (mg/L) 21.5Estimated? No

Alum inum , Outfall 006

Occurred? Yes Reported? Yes Estimated? No Occurred? No Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 007

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 008 Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 006 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

6/30/2011 No Concentration (mg/L) 3/31/2011 No Concentration (mg/L) 23.1

9/30/2011 No Concentration (mg/L) 7.68

12/31/2011 No Concentration (mg/L) 10.4

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 007 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

3/31/2011 No Concentration (mg/L) 0.69

6/30/2011 No Concentration (mg/L) 1.49

9/30/2011 No Concentration (mg/L) 2.47

12/31/2011 No Concentration (mg/L) 0.81

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 008 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 010

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

Alum inum , Outfall 011

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes 3/31/2011 No Concentration (mg/L) 14.8

3/31/2011 No Concentration (mg/L) 1.33 **Information Limit?**  **Ty pe** 

3/31/2011 No Concentration (mg/L) 5.16

6/30/2011 No Concentration (mg/L) 3.68

9/30/2011 No Concentration (mg/L) 11.7

12/31/2011 No Concentration (mg/L) 9.78

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 010 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

12.2

9/30/2011 No Concentration (mg/L) 4.06 6/30/2011 No Concentration (mg/L)

12/31/2011 No Concentration (mg/L) 4.27

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 011 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

9/30/2011 No Concentration 3.14 6/30/2011 No Concentration (mg/L) 3.58Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

Alum inum , Outfall 012

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

Alum inum , Outfall 013

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes

Estimated? No

**Chemical Group 2007 DMR**  **(lbs/yr) 2007 TRI (lbs/yr)**  **2008 DMR (lbs/yr)**  **2008 TRI**

**(lbs/yr)** ALUMINUM

- - 102,489 NA Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

6/30/2011 No Concentration (mg/L) 1.28

12/31/2011 No Concentration (mg/L) 4.02 (mg/L)

12/31/2011 No Concentration (mg/L) 775

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 012 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

2011 Monitoring Period-Level Loads for Aluminum (01105) for Outfall 013 **Monitoring Period Discharge**  **Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** 

Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr)

12/31/2011 No Concentration (mg/L) 3.89 6/30/2011 No Concentration (mg/L) 5.69Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

Correct 12/2011 concentration for outfall 011 based on data from facility contact, drops Al TW PE to 9,530.

**Corrected Facility TWPE**  10,716

**Corrected Load for Outfall 11**  **Total**

**Corrected Al**  **uminum Load**  **Al uminum TWF**  **Total Corrected Al**  **uminum TWPE** 4319.42 158,858 0.06 9,532 1184.2

**Monitoring Period Load**  The facility

contact confirmed the 2011 discharges and stated that the December 2011 aluminum concentration reading for outfall 011 of 775 mg/L was taken immediately following a m ajor precipitation event. Therefore, it did not represent typical daily discharges during the 92 day
mo nitoring period. The facility performed additional sampling on January 26, 2012, and provided EPA a revised value of 0.463 mg/L for aluminum at outfall 011.

**Corrected Calculations**

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation (lb/period)** 

63,642
63,642

**Monitoring Period Load**  **(lb/period)**

34,680
34,680

**Monitoring Period Load**  **(lb/period)** Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - 1.33 90 1,593 **Flow (MGD)**
Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
6.605 91 25,032 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
8.35 92 36,233 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
1.27 92 784 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

0.81 181 270 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.78 184 34,410 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

0.057 90 612 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.12 91 2,288 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.15 92 1,495 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.06 92 990 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.2055,386
5,386

**Monitoring Period Load**  **(lb/period)**

3,431
3,431

**Monitoring Period Load**  **(lb/period)**

213

213

**Monitoring Period Load**  Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

90 1,301 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.18 91 No Load Calculated 0.075

0.23 92 1,403 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.091 92 727 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

0.026 90 13.5 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.052 91 58.8 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.066 92 125 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.025 92 15.5 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation (lb/period)** 

1,106
1,106

**Monitoring Period Load**  **(lb/period)**

615

615

**Monitoring Period Load**  **(lb/period)** 0.015 90 167 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

0.26 90 267 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 **Flow (MGD)**

0.028 90 109 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.056 91 157 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.071 92 638 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.027 92 203 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 -

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

0.03 91 278 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.039 92 122 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.015 92 49.1 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

91 1,822 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.84 92 2,042 Concentration (mg/L) × Flow 0.67322,490
322,490

**Monitoring Period Load**  **(lb/period)**

5,745
5,745

**Monitoring Period Load**  **(lb/period)**

39,721
39,721

**2009 DM R**  **(lbs/yr) 2009 TRI** 

**(lbs/yr) 2010 DM**  **R**

**(lbs/yr) 2010 TRI (lbs/yr)**  **2011 DM R (lbs/yr)** 
28,269 NA 90,846 NA 477,029 Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - 0.26 181 516 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.84 184 5,229 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 (MGD) × 3.785 (L/gal) × Number of Days × 2.205 0.53 92 318,359 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation)

**Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 **Limit Wastewater** 

**Flow (MGD) Number of Days**  **Equation**

Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - 4.57 184 27,318 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 1.44 181 12,403**AL Limit from 2008**  **Permit? Al**  **Limit from 2013 Permit?**  Report Only

- semi annual Report Only

- semi annual annual Report Only

- semi annual Report Only

- semi annual Not listed. Not listed. Report Only

- semi annual Report Only

- semi annual Report Only

- semi annual The facility

contact confirmed the 2011 discharges and stated that the December 2011 aluminum concentration reading for outfall 011 of 775 mg/L was taken immediately following a m ajor precipitation event. Therefore, it did not represent typical daily discharges during the 92 day

DMR Data from ADEM1.59 1.334

4.99 6.605

5.65 8.352

0.804 1.27

0.22 0.812

28.4 0.789

14.3 0.057

24.3 0.124

12.4 0.157

21.5 0.0623.1 0.075

0 0.188

7.68 0.238

10.4 0.091

0.692 0.026

1.49 0.052

2.47 0.066

0.812 0.0255.16 0.028

3.68 0.056

11.7 0.071

9.78 0.027

14.8 0.015

12.2 0.03

4.06 0.039

4.27 0.015

1.33 0.267

3.58 0.67

3.14 0.847775 0.535

1.28 0.267

4.02 0.847

5.69 1.443

3.89 4.573

**2011 TRI (lbs/yr)**  NA**Al ternate Sample provided by the facility**  0.463 0.463

4319.416601**Description changes from 2008- 2013 permit?**  None. None. None. None. None. Removed outfall. Removed outfall.

None.

None.

None.188.4166013 188.4166013
4,319**420 - Iron and Steel**

**USS - Clairton Plant Clairton, PA**  PA0004472 (TRI ID: none)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors.

Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** The cyanide perm it lim its for outfall 183 are 5.5 mg/L or 118 pounds per day (lbs/day) average monthly and 10 m g/L or 216 lbs/day daily m aximum. Back-calculated Concentration Values
**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.
**Pollutant Total Pounds** 

**(lbs/yr) Ma** **x A llowable** 

**Load (lbs/yr) Total TWPE (lbs**  **eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)** Total Residual Chlorine 28,014 82,216 14,007 41,108
Cyanide 12,141 43,070 13,477 47,808 Benzo[a]pyrene 23.3 445 2,349 44,833 Manganese 369 5,376 25.8 402 Iron 1,826 10,039 10.2 56.2 Am mo nia as N 3,764 198,195 4.17 22 Naphthalene 11.3 379 0.11 3.78 Benzene 0.026 10.8 Solids, total suspended 92,905 1,490,962
Oil and grease 18,421 116,581 Total phenols 105 391

No obvious issues.
Cyanide, Outfall 183

Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes 4/30/2011 No Quantity (kg/day) 13.6 53.5 3/31/2011 No Quantity (kg/day) 12.2 53.5 2/28/2011 No Quantity (kg/day) 11.08 53.5 1/31/2011 No Quantity (kg/day) 9.36 53.5 **Cyanide: View Details**

2011 Monitoring Period-Level Loads for Cy anide (00720) for Outfall 183
**Monitoring Period**  **Discharge**

**Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  **Limit**Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

**Chemical Group**  **2007 DMR**

**(lbs/yr) 2007 TRI** 

**(lbs/yr) 2008 DMR** 

**(lbs/yr) 2008 TRI** 

**(lbs/yr) 2009 DMR** 

**(lbs/yr)**

CYANIDE AND CYANIDE COMPOUNDS 8,335 13,215 9,101

Total Residual Chlorine 19,347 NA 8,435 NA 8,465 Annual Load (lb/yr) Annual Load from Monitoring Data (lb/yr)
Number of Months Requiring Estimation 12/31/2011 No Quantity (kg/day) 23.1 53.5 11/30/2011 No Quantity (kg/day) 24.1 53.5 10/31/2011 No Quantity (kg/day) 23.8 53.5 9/30/2011 No Quantity (kg/day) 8.94 53.5 8/31/2011 No Quantity (kg/day) 11.7 53.5 7/31/2011 No Quantity (kg/day) 12.3 53.5 6/30/2011 No Quantity (kg/day) 13.7 53.5 5/31/2011 No Quantity (kg/day) 16.3 53.5Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

The cyanide permit limits for outfall 183 are 5.5 mg/L or 118 pounds per day (lbs/day) average monthly and 10 mg/L or 216 lbs/day daily maximum.

**Monitoring**

**Period Load (lb/period)** 

1.12

1.19

1.30

1.38 **Back-Calculated Concentration**  **(mg/L)**

30 905 Daily

Load (kg/day) × Number of Days × 2.205 2.6 2.48 31 835 Daily Load (kg/day) × Number of Days × 2.205 2.47 28 684 Daily Load (kg/day) × Number of Days × 2.205 2.21 31 640 Daily Load (kg/day) × Number of Days × 2.205 **Wastewater Flow (MGD)**  **Number of**

**Days Equation** 1.75

1.57

1.34

1.30

1.05

2.72

2.58

2.37

12,141

12,141

**2009 TRI (lbs/yr)**  **2010 DMR**

**(lbs/yr) 2010 TRI** 

**(lbs/yr) 2011 DMR (lbs/yr)**  **2011 TRI (lbs/yr)** 

14,162 12,141

NA 15,441 NA 28,014 NA

Annual Load from Monitoring Data (lb/y r) × 12 / ( 12 - Number of Months Requiring Estimation) 31 1,585 Daily

Load (kg/day) × Number of Days × 2.205

Sum of Monitoring Period Loads

0 2.57 2.47 30 1,597 Daily Load (kg/day) × Number of Days × 2.205 2.31 31 1,629 Daily Load (kg/day) × Number of Days × 2.205 31 802 Daily

Load (kg/day) × Number of Days × 2.205

2.26 30 2.38

592 Daily Load (kg/day) × Number of Days × 2.205 2.43 31 846 Daily Load (kg/day) × Number of Days × 2.205 2.31 30 908 Daily Load (kg/day) × Number of Days × 2.205 2.46 31 1,118 Daily Load (kg/day) × Number of Days × 2.205**420 - Iron and Steel**

**USS - Clairton Plant Clairton, PA**  PA0004472 (TRI ID: none)

**RECOMMENDA**

**TION:** The chlorine permit limit for outfall 038 is 0.5 mg/L monthly average.

Total Residual Chlorine, Outfall 038

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No 11/30/2011 No Concentration (mg/L) 0.45 0.5 50.74 10/31/2011 No Concentration (mg/L) 0.04 0.5 61.05 9/30/2011 No Concentration (mg/L) 0.09 0.5 71.5 8/31/2011 No Concentration (mg/L) 0.12 0.5 66.22 5/31/2011 No Concentration (mg/L)

7/31/2011 No Concentration (mg/L) 0.47 0.5 63.15 6/30/2011 No Concentration (mg/L) 0.18 0.5 70.35 4/30/2011 No Concentration (mg/L) 0.08 0.5 41.7

0.05 0.5 61.98 3/31/2011 No Concentration (mg/L) 0.05 0.5 38.99 2/28/2011 No Concentration (mg/L) 0.11 0.5 41.83 1/31/2011 No Concentration (mg/L) 0.11 0.5 36.75 **Total Residual Chlorine: View Details**

2011 Monitoring Period-Level Loads for Total Residual Chlorine (50060) from Outfall 038
**Monitoring Period**  **Discharge**

**Information Below Detection** 

**Limit? Me**  **asurement**

**Ty pe**  **Av g** 

**Daily Value Limit**  **Wastewater Flow (MGD)** Occurred? Yes Reported? Yes Estimated? No Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation Annual Load (lb/yr) 12/31/2011 No Concentration (mg/L) 0.26 0.5 42.9**Monitoring Period Load**  **(lb/period)**

5,717 Concentration (mg/L) × Flow

(MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 632 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
30 30 1,611 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 2,056 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205

30 3,171 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
31 7,679 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 30 835

31 802 31 504 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 28 1,075 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 31 1,046 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205 **Number of Days**  **Equation**28,014

28,014 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Days × 2.205
Sum of Monitoring Period Loads 0 Annual Load from Monitoring Data (lb/yr) × 12 / ( 12 - Number of Months Requiring Estimation) 31 2,886**420 - Iron and Steel**

**Mountain State Carbon Follansbee Plant Follansbee, WV**  WV0004499 (TRI ID: 46312LTVST3001D)

**NOTES:** Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

**RECOMMENDA**

**TION:** The facility’s cyanide perm it lim its for outfall 005 are 0.0114 mg/L monthly average and 0.0284 m g/L daily m aximum. The facility’s cyanide perm it lim its for outfall 205 are 24.5 lb/day (11.1 kg/day) monthly

average and 34.9 lbs/day (15.8 kg/day) daily

m aximum. Calculated m ass for Outfall 005, back-calculated concentration for Outfall 205.
**DMR Loading Tool 2011 Total A** **nnual Loads** Pollutants Identified for Further Review Based on High TW PE.
**Pollutant Total Pounds**  **(lbs/yr) Ma** **x A llowable**  **Load (lbs/yr) Total TWPE** 

**(lbs-eq/yr) Ma** **x A llowable** 

**Load (lbs-eq/yr)** Cyanide 7,038 12,919 Benz[a]anthracene 6,885 2,092 Benzo[a]pyrene 5,106 19,448 Selenium 3,032 561 Fluoride 53,179 1,595 Alum inum 858 647 Arsenic 815 Benzo(b)fluoranthene 649 5,118 Indeno[1,2,3-cd]pyrene 572 5,118 Sulfate 6,170,906 487 1,100 Chloride 4,955,965 Am mo nia as N 438,779 991,339 Nitrogen 386,953 Solids, total suspended 385,938 2,508,885 Total Kjeldahl Nitrogen 326,913 Oil and grease 94,466 34,821
Nitrogen, nitrate dissolved 69,693
Nitrite nitrogen, dissolved (as N) 69,015

Red cells indicate violation of perm it.
Cyanide, Outfall 005

Occurred? Yes Reported? Yes Estim ated? No Occurred? Yes Reported? Yes 2/28/2011 No Concentration (mg/L) 0.012 1/31/2011 No Concentration (mg/L) 0.0089 **Cyanide: View Details**

2011 Monitoring Period-Level Loads for Cy anide (00720, 00718) for Outfall 005

**Monitoring Period Discharge**  **Information Below Detection**  **Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value** Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

Cyanide, Outfall 205

Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes 5/31/2011 No Quantity (kg/day) 7.88 4/30/2011 No Quantity (kg/day) 3.58 3/31/2011 No Quantity (kg/day) 10.4 2/28/2011 No Quantity (kg/day) 4.17 1/31/2011 No Quantity (kg/day) 12.2 Annual Load (lb/yr)

2011 Monitoring Period-Level Loads for Cyanide (00720, 00718) for Outfall 205

**Monitoring Period Discharge**  **Information Below Detection**  **Limit? Me**  **asurement**

**Ty pe**  **Av g Daily Value**  Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

12/31/2011 No Concentration (mg/L) 0.068 11/30/2011 No Concentration (mg/L) 0.0076 10/31/2011 No Concentration (mg/L) 0.0101 9/30/2011 No Concentration (mg/L) 0.0068 8/31/2011 No Concentration (mg/L) 0.0094 7/31/2011 No Concentration (mg/L) 0.0048 6/30/2011 No Concentration (mg/L) 0.016 5/31/2011 No Concentration (mg/L) 0.014 4/30/2011 No Concentration (mg/L) 0.012 3/31/2011 No Concentration (mg/L) 0.017Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No Occurred? Yes Reported? Yes Estimated? No

**Chemical Group 2007 DMR**  **(lbs/yr) 2007 TRI**  **(lbs/yr) 2008 DMR** 

**(lbs/yr) 2008 TRI (lbs/yr)** 

CYANIDE AND CYANIDE COMPOUNDS 16,566 14,152 Annual Load (lb/yr) Annual Load from Monitoring Data (lb/yr) Number of Months Requiring Estimation

12/31/2011 No Quantity (kg/day) 5.44 11/30/2011 No Quantity (kg/day) 12.2 10/31/2011 No Quantity (kg/day) 4.98 9/30/2011 No Quantity (kg/day) 6.25 8/31/2011 No Quantity (kg/day) 6.62 7/31/2011 No Quantity (kg/day) 9.0702 6/30/2011 No Quantity (kg/day) 3.401Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors. Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the y ear.

The facility’s cyanide perm it lim its for outfall 005 are 0.0114 mg/L monthly average and 0.0284 m g/L daily m aximum. The facility’s cyanide perm it lim its for outfall 205 are 24.5 lb/day (11.1 kg/day) monthly

average and 34.9 lbs/day (15.8 kg/day) daily

m aximum.

**Monitoring P eriod Load**  **(lb/period)**

0.0114 6.45 28 19.4 Concentration (mg/L) × Flow (MGD) × 3.785 0.0114 8.7 31 20.03 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s **Limit Wastewater** 

**Flow (MGD) Number of** 

**Days Equation** 520

520

**Monitoring P eriod Load**  **(lb/period)**

13.9 0.71 31 539 Daily Load (kg/day) × Number of Day

s × 2.205 31 716 Daily Load (kg/day) × Number of Day

s × 2.205

13.9 0.72 30 13.9 0.84

237 Daily Load (kg/day) × Number of Day

s × 2.205 13.9 0.87 28 258 Daily Load (kg/day) × Number of Day

s × 2.205 13.9 0.82 31 836 Daily Load (kg/day) × Number of Day

s × 2.205 Annual Load from Monitoring Data (lb/yr)

**Limit Wastewater** 

**Flow (MGD) Number of** 

**Days Equation**  31 185 Concentration (mg/L) ×

Flow (MGD) × 3.785 (L/gal) × Number of Day s Sum of Monitoring Period Loads 0 0.0114 10.5 0.0114 13.84 30 26.3 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 13.32 31 34.8 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 31 34.5 Concentration (mg/L) ×

Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 14.67 30 0.0114 14.19

24.9 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 14.08 31 17.4 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 13.7 30 56.2 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 30 26.4 Concentration (mg/L) ×

Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 12.2 31 0.0114 8.44

45.7 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s 0.0114 6.58 31 28.9 Concentration (mg/L) × Flow (MGD) × 3.785 (L/gal) × Number of Day s (L/gal) × Number of Day s5,821
5,821

**2009 DMR (lbs/yr)**  **2009 TRI**

**(lbs/yr) 2010 DMR** 

**(lbs/yr) 2010 TRI** 

**(lbs/yr) 2011 DMR (lbs/yr)**  **2011 TRI (lbs/yr)**  5,370 19,116 6,340 Annual Load from Monitoring Data (lb/yr)

372 Daily

Load (kg/day) × Number of Days × 2.205

Sum of Monitoring Period Loads 0 30 810 Daily Load (kg/day) × Number of Days × 2.205

13.9 0.69 31 13.9 0.73 13.9 0.69 31 341 Daily Load (kg/day) × Number of Days × 2.205 13.9 0.76 30 414 Daily Load (kg/day) × Number of Days × 2.205 31 620 Daily Load (kg/day) × Number of Days × 2.205

13.9 0.74 31 13.9 0.69

453 Daily Load (kg/day) × Number of Days × 2.205 13.9 0.71 30 225 Daily Load (kg/day) × Number of Days × 2.205KB QC

0.293 0.293

0.293 0.293 **Ma ss (kg/day)** 0.423 0.423

0.383 0.383

0.646 0.646

0.830 0.830

0.256 0.256

0.505 0.505

0.378 0.378

0.509 0.509

0.398 0.398

2.702 2.702

3.93 3.93

1.27 1.27

3.27 3.27

1.31 1.31

2.93 2.93 **Concentration (mg/L)** 1.27 1.27

3.47 3.47

2.36 2.36

2.17 2.17

1.91 1.91

4.42 4.42

2.08 2.08