PJGUBE +ll ....... WASTE MANAGEMENT DECJSION 

· . .J 

'· .. . . 

.. · ' ·) 

WliP·20 

VES 004401 
- ··~= ... ·-·· DIIC:JilOI' 

1. e-eept.c ... l!!i11ty lp( 

o..ld• U.t. 

........ .....,_.at F-ui'J 

u. D!siei• ta Dttr Ann!nl 101: •e,;s tot !1ft• 

• f.s ,...,... !wr!:\ 

·iool-

(J:) C!!tt!!tJas ""m 

Cl) !llM ... ljltph 1'" ttt"tl= 

•• IM1z:&Jel Inn' ,, .... ..,.... 

•. , !trd' '" !mlr:t!e ... 

... (pd.Jat) 

.) 

. ... .. l 

· • • _,. a.od...S• ------

.u.ctt. .. Dllt..-f ------

-·--------------

•uta 

_,.._ ca~efiN"J' Cad.• ------- -------

.... 

.... 

- .. 

VES 004402 
~.-.. . · ·.· 

. ·) 

INCOMING WAS'm SBIPIIENT PJlOCZDURES 

In a:uad&Dce with 264.18(<) IDIJ/ar 36 ID. Mm. Code '12Ul8(c), .:b +tpment cl 'IO'a8te, upco 

arrinJ at the facility, will be iupeeted ao cleflned b<reiD before the iniUatlan oi tm1J 1\Jrtber acdvily. Tbi8 

.., ...... two ~ !!rat, It COlllpllreS the actual ~ ldesll.ity wil.h that detenaiDod ill lbe prc6le ~ 

and that lilled 00 the - manifest. rr the - coolorms to the apec:ttd d...,.;pt;ool a.od propertiee .. 

clet.eriDIMd durilllthe prollle review, tbeD the ilo!ormatloo oblabd clurinc pmllinJ can ,.._ably be u.d 

.. lbe baoia for mft!'M8inr the - which a:rma at the facility. Socoadb". it proridee a O«DDd level of 

- that the coolemp!a1ed - IDIIll8gemeu1 tec:hnique <an be utilized. Other CWM pe.--mel (or a 

CWM1ppl<lYed iabontory) <an pc-ovicle the ~ OIJA/or BupplosbeDtal ~ ~ priar to or 

....,..... rib thearrinJ ol' tbe load. WMie thip• to thatbaff armed u the Cac:llity are ....Wclered to be 

in the receiving proceoa unlll such time that Facility Maoapmeot makee a 6nal dec:iolco repn!ing ~ 

~ at IUC!I time lbe -11ft c:oosideJed .....-pted. 

If the waste does not coof0111l to the especiC!d deocriptiooa ODd properties • determined cluriDi the 

profile rniew (ja !OWICI to beiiODCOil!orminc), tbeo the iDl<>rmatioll oblaiaed Uliacthe Vaivtot""7 ~ad 

tm1 &iftilemeolel Aoaq8es perl"ormed, will be utilised to DD~~ge the waste. 

All waote obipmenll which are subject to the Land Dilpooal RoottriciiL>os oi 40 CFR Part 268 ad 11...-e 

been 1natec1, nemptod, variaDced, or - the WGfll'iole tr •••+4 otaodard ar prohjbjtlon wllbout 

~-muet be IICCOIIlll"'ll by a Conn &om the s.eeter or~ ~ that the t.reated, e:rempte<\ 

or ....n.m.ed ...8.te-the WOjliiatoo ......._.,. ~ Jlr"b'"b!tion, ar 'fWiellce (.,..that the 1111111 'od 

- ~ - lbe l:e&lmeotllabdanl or pt •4411'""1) eod i.nctudes erJif a~ a.oaJ;ytlcal data or 

rot.,......... to 8Udl dUa or doouo>eol.alaoo (ID aceordanee wilb 40 CFR 268). FIJnhenoan, 61 ...-wbieh are 

to the laod ~ restrictlooo aod require lfte!moul muot be by a fonn &oailbe 

iP-ntor (01' •treat«) that (1) DOtlllootl tbat the ........ cm'I&IN probibitecl" eoDIItitueola; (2) kleotif!eo the 

app...,..ate" s-trneat lllaDdwdo •• • led wil.h the - iel; and (a) iacludel1111,1...,p;ceb!e ~ dPa 

or 4m to ruth cWa (lD .....,....,. with 40 c:FB 2118), See SecdoD 4.U for a diocu8oloo ...,.,.....the 

inCOft!llllkm Bod~ to be~ by the~-

WAP·21 llEVlSION 11 

~ 

VES 004403 
• ~! 

'-"'• - obipmeat l<leu!l' u ... bepll vpoD lll'rinl ol lhe - at lhe fadllt7. 'lba 

in'V"'ion, 

~ 

18111pliac ead IIDIIO'oia o{ the jn"""'"" - will be pedormed in ~ rib the 

doocribod in Seetiaol2.0 aDd 8.0. 

lo the ...... o{ c:ootainer ablpmenta not CO¥el-ed in the e=eptloao, .-h c:oot.eiDe\o in the ablpmoDi will 

111m! ita c:ooteota vtsue11y lnlpeeled b)' ~ a IWI depth -uc.l ~ to YUil";y that the coatePta ore 

similar prior to C<llllj'08ilinl, Tb~ iet:Oifiollecbnicion wiJi """'pbylicalllale f.w eedl clnun OCI the recemoc 

documeDia c.ee ~5o 1, Ph,r8ic8l ~ WCIIUbeet), wbidl the lob will eompue to the prolllecl plvsical 

dtwctiptioiu ol the - J.ocoming - will bate ka fW1 depth ~rticill sample ......u.r inapected Cor C<>lor 

·aDd pbMe (liquid. oalld, MIIIHotid), Druml oi Jllt<bpclebemicolo 1rill be ~ opeced aDd illlf 1 c•od to 

,.,.;rylhatlbe clnun il packed .. idenlified in Sectico 5.1.1. 

Upcc ~. 10 pe=t o{ the <OCIIaioen frcllll eedl - p'Oiile wit.blD a 8bipmeot, ~ be 

J'ftlldoml,y aeleded 8lld Mmpled, auwcluc to Sectico 2.0.. lo tho eftiDt that a lliDIIe drum ol a apecllio .-

pra!le lo J-ilod, that dNIII will be -npled A mnlrragp o{ 1M eaatainerbecl ihlpmeot •mp!oe ~ the 

--prdile m-:y be ''"di..,.;ted prior to 8D8Iyole, porided the iodivldual88lllpla""' elmilllr ID ~ 

~ appearaoce. ... ... 

For WMie (ecoi>ei'l arer 80 drums, liD e• !if w! siop dr.-p"8b ~will be tabQ u _.rt 'C, 

·the me.. ··c .o..t;,a Tbe sra~> llllljlle will be lalioclto _. ,......., ... JDal>dWc1 ~ Tblo pw~o wm . ' 

Whore....,bfiwrl,.,.tobeJ'8DIIoml1aeJoetedi'OfoamP'nioriutljwtiao(lo hollugpodt;ac..t.._...,, 

· drum ; ,......, •• 01), the c:oota!nen to be en1uo1ec1 will be eeleded 1lliDc a i'8Ddom llUIIIber tahle. cr a .-lam 

DUIDbetr eeoentor oa a penooal """'~""« or p.,.. •"'" ~- Drum i!llillhen wiD be ·s '""Ito the ~ . drums in a ~l'l!IDI upcc ~prior to 011\l&l. D tit •"DJ"ini 'lbe ....,.,_ tDiiDben wiiJ be 8""*8teci 

to - t•h wbir:b .. • •-wiD be ~at tb1l time. 

Qed a! « ..... will~ E j'OOiled only wilh umplee film the-Jll'i&t wliich..., o{ timilllr 

eokr -~ lo eclcJ!tioo, ~~-&om the-~ abibR ~-ioplvobl""" ...... ~ 

lhellindetc.7~izidtlioee-be•eeoMc!,!See~tbenBa• . 'i;, t ' •aw!llle .. rbi · 

to wllleli dlnlmt!-~ .d.-•· ~ ~ be D..'de ~ tb,.'.,•ite!tw 'floual 

iD!IfoectlaD. 

S.mpioe tram~.- ""ipmmt• w11 be oubjod.ed to Mendatory ~ (~ -=tioo S.O). 

All audl ....... Will be relltloed'f'llr. period Nlfl*'ld to~ the-f'llr iDeiDentiDo. 

'nle reeu1t1 oi ihe v1au11 to.pectiDoa ead v .. c~at<>ry ~ will be • • +ted oo lite -

..,.,.;pt ~do • -~ (WBAD), tn*al !on:a attad>td • Fl£ure 6-l. Tblo Corm io ...ed to,., •t the 

pn>~~~e em.181ioo date. lhe reea11a oilhe Mendmory Ana~;yeM c- 8ectldli U), aD.i lite determluadao ol · 

ccar..........-......,,_ <- Seetioll5.2l. 

.· 

IIEVIBION 11 

11/2919( 

VES 004404 
. -. 

:) 

'!be fOilowiDe ~ wblcll are cle6ned in Soc:tion 4.1.4, will DOt be •mp!ecl upon airM1 bat, at 

a mjnjmum, will be ~ to a vioua1 inlpoctlon as clo<!crlbed below. on.- llllltcl'iolla ere DOt ~ 

beca1we they exhibit C8IIIIUII "" Dppractlcal sampllnc and IIDIIlytiall comp!iratiom .wl beca..a """ded 

ehemical and pbylical dote bu pnMousiJ been oblalned: 

l) Pacbce<1 cbrmicola ODd clobria (-Sectloo 4-U Cor deo<ript.lon). Thio inopectlon procedure 

will apply to u.- drums which &nl oek!d.ed ror verificatioo or the drum in't'elll.or7 abeda 

(DIS). During the w:rillcatloo, theae drumo will be ldeoti6ed 811 coo(crming. nor......,..,. wiDjc 

and pcoce He, or DOD-C<III[arminr and diacrepeDt. '!be deliniticmo end '~ will be 

aa fo.llon: 

CooCormjng Pmw A c1rum that - guidelines ODd an material ;, idenlillood and 

, wueepow!a .nth DIS. Contormiag drums will be P" t<l. 

PI (II! hie nn,m,. A drum that ia DOl eoofarmlnr but suffident information ia 89'li1able 

to detetmlDe U ~. Tbe follow!nr are enmp!M 1/1 pi QC ble dnJml: 

1. Mlaoin( DIS but DIS ......aab1e in oOJIP"OY8l package; 

2. 

3. . 

4. 

5. 

e. 

7: 

. 8. 

9. 

Malerill ideoti6ed OD DIS but not ..-m In the clrvm; 

BrokeD bct{Je(a) rill lecihle leboloW; 

. &.>bsl boltle(o) and loW(I) 4Mb Ojed, but .... •oriolld ... HI!ob!e with Joslc-1 

<lec!uctica and DIS reoiew; 

Extra coota1nen or illtulified JDaleriol; 

Eztra ld..,tjf!eble ODd ~ moter!al; 

Bxn~ , •• cotPPEandjob•lJ'P'ioo (~ marbro,aheorbom 

...... cardboer<l); 

Material on DIS~ but q PM !eo are iDwtiectb ldeoWied; 

NCIIHIOIJiaiDeri *' CADCI but jdentjf\eb!e &am DIS; 

. Wbut •al.• • t,J?'O'oiw a.ld>DIB. 

. PPo'""' ce.ab""'l!' . drumB will be aa:epted lllid pc · o II. The ~ ior J*br ol P'P'"'' '-abNiee . 

10. 

drums will be no>tiliod of the ~ww.;. . . eel with the pc He drl-. Tbe 

genontor or piiClulr will alao be DOtilied that the ....timood ~ ol pr ble materia1a . 

·. ~ o:ont~ wiD DOt be tolenl.od 8Dd will ;.. ln. tbe --- ol deteiiid 

·_...,.,Up to andlndnd!nebennlog tbe ~ fnm aendble~­

to TWI r..r treetm.,. 

Bl!MSlON 11 

IJ,'29,1U 

' 

.. 

. .. 

VES 004405 
. : 

i. .a . ... ) .. ' 

2) 

IMgepcglL Pnvrur A ~ when insuftiDent iDformatioD ill tmlilable to &e« wiDe 

~ cllbe drum or lbe drum CDOiains • ._.,.,..~ maun.J. 'lbe followiQe are 

eamples cl diocae!*Dt drums: 

L ODe or more brokeD bottleo wbere lbe oontenta """""' be dolamioed; 

2.. Unidout11iable material; 

3. Mlsoioe label aDd COD'•'ner does not match llll,7llli:ni oo lbe DIS; 

4. U~e mauriel in drum; 

5. DIS not &"fllilable. 

Tbe porticm of lbe drum wbicb is diocrcpeDt will be rejeded. All DOD direct cbu&e drums 

will be impoct.e<1 during pc • 1 in lbe SpeciaiV l'!c I 11 Bnllcti"' 

!'.mpy _ .......... deiiDed at 85 lAC '72L107(b). Tbeee- will be 'Oioually ~ 

upoo receipt. In odctitlon to dilrereoces In plvaical appeeraoce, tbeeil wu1ea will be . ' 

detamiDed to be ll<lOCOII!onnlng ~ lbey eooteiD meterial in ~ greater 1181 3,-. 

cllbe total~ otlbe contaioer or more tban one lnob of ..;due r-m.·oolbe boUom 

oC lbe OOidaiDor or wben \he ~ coolabor (onil 1• t) 11M &ee llquida lD 'mare ~ lbe 

above quantities. 

3) ~ eDd other~ procllact.o ~ lD -·-queoll.tles ill their 

.,....... uu•• 1 "0<1 P"" top,. TW1 will ~ llld vilualb" loopeot 5,.. ol'lbe iao• • q outer 

''"'"'" ottboooe materiali to ovl(r !bat \he ablpaoeot ooot.m. __. w prhl"' 

C •l":iaa pioclucta Or rMm!taJo TWJ will opeD 6'J' but oot ._ diM. ODe of lbe lDo I Jg 

_...._of eacb iDvninr prolile to,_, tllllt lbe met11 iBI ie u dorribod oolbe WPS. 

6) Aeroool CIID8 mol Letture BotUes: n-o- will»~ imported upoo pr• 1 c 

.. Into bumable ~ 

6) Coalrollecl•d'"'• "'.do&ed ill lll UAC Sedioo.802. Tbeie ~ otmalerialt will oot 

I» ..-eel or •mp!oit b.1 TW1 c1i1e to the ~ il<n•ullis U... material8. TWI wll 

requn ., laoeolol) "&om lbe prJrer cllbeee lbllleriotla ee "l"" 11!*1. iD tbe 

.. ~ . 

·.oo•ined in 8etdcll ~ n,. maleriall"" .-..~ b7 a~.[ ••' 11 or . . . 

~.,....,._;.or-.. or reclenl.ee_eac7· · 

1) P~ lnfedloU.Medic:al WUie (P1)lW) ee deliDed b7 IBPA 

8) w- wblob ore ~ .. c'lleNe lhroucb ... irwpectina proCea w-lD arigiDal - . . . P"" • IIIP•oe will be oubjec:t to 5 .. io!peCtloa u per ~LL4 aboft. Weetee wblch """DOt in 

.....,.. P""k•oe wil be IUI!!oct to 100'*< "¥ilouel inoprtkm EnmpJes cilbeae tn- ot 

- ere, ~ cal.bode ray lubet, a"Uibed &lou, pipin& lllten IIDCI filter cartridp., 

wlrecr tubiQg. peper"producta, ~metal sbeet!Dg ODd pan.. UJ*wi•eampnr-4"0Dd 

. devil& Tbia liit II DOt -tto be ell iol:bm, omd 111aJ t.. 1• W wi&b loe8l IBPA 

appro98l. 

RBYIBlON U 

~ 

· . 

VES 004406 
9) Priar 1ce«:t Apprunl: M.olerWo wbich do oat Call lato oae <I tbo olher noimptloa 

= ciieo, but pnMilt illlp"..:ti<M •"!P"n' or..,..,.,. mmpljtatlope u .. <llhla e:ae '' t1uu 

will be .,..m.ed .., a pn>lile opecific bella, with iDit.ial .-lew ~ the IEPA field oftlce 

(CAIDorille). PrGllle .opprova1 w!1l be IIUbject to iEPA·DLPC Permit 8eetioD ~ (e.& 

IU) llfllli'O'IIl. 

AAe.. a - bae been• ec:ehtd ~the r.:ii&J, iDipe<:tecl. Mmpltd, ~--.,..eel Ill~ with 

SectiaDa 5.1. 2.0. aDd 3.0, Fdty y_, N!N wil N¥itw the pdlle iDC.......U..., the Uandat017 ~ 

8Dd tbe IIIIIDlf• to cltWnaiDe wbetber the moteriol ,..,;.o;d .....cor- with tbo poollle illl~- the 

1118Di(oat, aDd wbetbtr it CIUl be ~ _,pt Ill tbo lio:llity. '!be ~ flvlrt!cm• Ill the ~ ..... 

Cellon: . . 

hdlity ~ w!1l relY em oae or man of the CoiJowiDc """'* <I iol'onalltiGil to ... ~~· -•· ,. • 

lhe idoadty tithe jntqpq mat rW tcptber with 111q olher ,_.... Dia I' "' 

. . . . 

0 

0 

V'.....tiDopectioD <ltbo _. ...... -

&unpl!rc 

0 .lltallta <I~~ 

0 Appupiootet...d~B· I kSioi>N .......... "-'Cea116 ...... ,.~ 

o W..&e v..;r,. 

'!be fL1Cw 'L ... L eda-tbo ilboote-,.;o be ClllllfiUed with iDrormiuioo tUea a-the 

!clklwlalr-•• !':pod duriJDc J"4llal c- 8octiaD 4.1): 

o wa... Pre& 8beeL 

0 .... r4W{J ,..,b __ 

o Art~ w'JMILM tk a',...., ...,..., ~ tbo II"' -· .i.:b .a a ~ nW IWe&y DMa 

............ - · ... ,,.tc.. 

Spedllc·crllorill'tcr"-. ·· . ~ ......... ..,tlleWJW) (Jipre 1'1). CcaatW..;..willlie . . . 

"""--' ... b WJlAD. Ddea ' 'L I fl Q W witb.llipldlle pM ' ...... be deta • lf"l M 

d ibeoilllAn ·w~n.. 

Fa:ility Va • 

w:J1ieo4 iDlor!llllllaD or reNia <I tbo Mppcl•lory ~do oat amfllna or ~~~e: ''mt wilh.,.... 

flofoo , ... a.., it a-lo ~ Bf d hd 1D Appoadi& WAP-D or ialu :! r' tc1 1o 

IDI,.....,. _....., bued ... eden*ifto fac:ta -,1 P.• ..->. 

WAJ':21i 

VES 004407 
') 

Tbe Fadlity MM..,.ent must clauil7 the ..,.. aa beiQg in DOD-CCDC..-il it il ·jfjra~ 

clilferent !rom the infonlllliion shown in the profile pepenoorlt or oo the IIIIIDifest, or di8"en in quantily &om 

that iudicaled oo the manifest, iD ~ with 40 CFR 264.7~ atJ4/or 35 JD. Adm. Code 72U 72. 

~ ~ <riteria 11M used to arrive at thio c!orition n.e, are: 

0 

0 

For built-.., ..natioaa greatA!r thaD ~in volume or, 

For bMcb - (e.r., druml, bop, ele.), AllY variaiJoo in pieee count (Le., tbe 

nwnl>es: ot pleoeto lilled on the manifest or drum ilm!ntoty cb!o - "'Il""' with 

the IIWIIber of p1..;,. rec:eioe<l) or, 

o Il iolpect.loo or~ of AllY- c1etetmi1Ms oi& .,., ... , dill'.._ eDit 

bet......, the !lll1lical pi'OpOI1ieo of the - ad the deea ipti<w OD the prc6le 

tmd/or shippinr paperwork. s;p;r ........ dill'.._... are: 

1) Variatioao &om ccof<>nll!lllCe erileria as deoaibed in AppoDdiz WAP·D or; 

2) ~.-.lUI "!bicb are mutullll7 e.:Juej,. hued OD ICieotific facta aAd 

principloe from the waste cleecription oo the maoii'OIIt or prool!le ~ 

5.2.4 An Eyall!a!.!op of Wbeth!!r W..S" Found to !je jp >!m.mqfmp'M' CI!Q be A&; ....... 

'l!j!l be l!eleetsd 

Ilthe inf~ tdlocted in (1) !IDd ~ """"' jM!reteo tW """ or more ot the mcc.,»ngevab•tjoo <riteria io lli(poili •ool.lydllf.......t llom the ll*lireot or pro6le Wormetlon, Fadllty ~must 

undatake to IOCI:O\ID1 fw the appare~~t oboened diii......,.,.. 'lblo .,.,...&a will ·IDdude ooe or mont ol the 

follow!n&: 

0 ll!Mew of •mpliog metboda to -111 ~ ••q>lb>g; 

0 Supp!m>enta! ~ .. !lj>OOClilied in Sectioa 3.8; 

0 ~ 8ft!uatloG ri the - · poofile ..m·;. . .. ~ ... cJjoco....._ with the 

. gooert!&arI! intor-'ba r" ·e4 cbi.c thio ....,pitlm ...., reeoa.. the· dllctepme1 , the ·neolut:ioG iL tht 

cliiJoepomi;y Will be docupwpt ciR ihe WBAn lllooig with the reoulla ill the Incoming wUie ..,.qiie. .: 

I!~in!pci.nlng-.-.aluatio.ocriterlaCIIIIDOt bereooiYed, the-..m boi •• ..; ed 

DllD'<lOIIII'OI'JI>ixc ad the reou1t11 clocumeD&ed on the WRAD aloag with the reou11a ot the •• ic -

&ll!llytea.. 

w-fOIIDd to be in IMH!Gilf'""""""" will either be rejected w ~pro&led for J)C*iblo ~ 

bJ the lilcility cleepile the ......... 

w-tW ..... reJec:ted <luriag •mloeding 111111 be placed ""'* ... the trudt for tranoportelloD. as 

!· ) ••....-1 with the ...,..u.:r. w-u.t - "!Jacte<l an. the lnal8parter '-depertecl the facDit7 -WI 

WAP-26 

VES 004408 
!.• 

"] 

in a~ area bolclillc 01117 """'P*Oie. materiala, baled CIG the MaDdalory ADalyees ieaJ11a. A record.; kept 

oC the loatlioo oC 1111 druml OIHita a1 .. tin>eL 

Al~. TWl mar re-ealua1e the-to dillermlDe wlletber the-materialaa Gpped 

·(Le. !,..,;.cent rib WPS rmd/at: mamr..t dac.) CIID be handled a1 the Fac:ilny. It the r.cwty c1etermi1o1M tba1 

the - can be IIIIUlllpCI c<lCIIIisteni rib permit rtqa&emeots, the lblpmeot will be """""'ied Tbe prollle 

information w111 be ameoded prior to '"""""""' or lbe DO:U abipmes>t. w-to be ,...proliled w111 be .,q..,t 

to the pro6le proce88 requiremeota ... aet forth in Seotioo 4.0 • 

.If the r&-eV111uatioa proeedule indicates !.bat tbe - ClOD be IOOCepled aod the geoerator ........, 

a l"f:flaed WBBt.e ~t decisloo will be pr_.,c~ by Fadllly Mm•e '""'• if lbe metbod or DIOIIJIII'IIIII 

tbqet. 

It a~ eminot be '""""ed within 16 • oC ""ipnm• rec:e!pt, the IBPA wtl be IIOdlled, in 

writinc. or the dilcn!peDcy and or attemp.. to l'fl<Xll>l:ile iL w- will be n¥cted row the fcillowinr """""'"' 

0 

0 

0 

0 

0 

. , 

Fadllly ~ Cor 11111 .._ determinml tW it CIODDOt _,.. the -rW in 

Mmpliaooe withal~ permjt ~ 8Dd llaodudl or~ ODd ..cety. 

A 111811!Ceot cliaorepanl::r (or llOII"COilfOi-) CIIIIDCt be ,.....,ed to the 

aeoentor'e and TWl's satloCactloo 1llliDr the pcu4taeo oulliDed above. 

Tbe ~'e/t.n\oopcrter'l popes ....... il DOt iD ..... aDd the pi I I If caDII<It 

be coiTec:led upon llft'iotal. 

Stonge opooce in ...,te!ner atonge areoa at: In oo«w balk lqo!ld atonge IIDb le DOt 

uailoble to provide ...,•ptloa of incompatible "W'm'IIIL 

A liquid - 1a DOt compatible (piS" the Liquid w- CompeHNiily Tootl wilh -

lllreel!y In atonce and no """' gatiw. or otber " ; w •t motbod le ~ · 

Rejecl.cl- will be pickecklp by the aenftator at: by ~ ~ lr..,.. 1..- to be relolrDed to 

lhe 8'lll'"ftlor'• r.dlity ... tnmoported to an altemata huardous - tu,;, tent, ot<n;e. at: diopoeol r.cillt)'. 

WAP-27 BBVIBION 11 

9fJ9J94 

·. 

,. 

VES 004409 
.... .. , ' • 1 

. .. ." 

FIGUBEIH 

PRY81CAL DE8CIUP'l10N WOBBflfiEKl 

AND 

WA81'B KBCED"l' ANALYSIS I)()CUMENT . 

. ·. w~ 28 

.. · 

. 

. ' 

t 

' ( -i •• 

'· 

VES 004410 
M'M EBIND. 

--

l'iiOCESI CCIII: ( , __ ..._"P'J_ 

( )WIFfii-UCUNI I 

( --&lkMCILY 

( , ........ -. ........ -

( ) DIOUI -·--..III!CUIIED 

~Dar!NMOQAA: ---

Reiii.TS: ~-- FAll;.,_·--

-YIICAI.CI • c:.J1111-'I:I: - --------------

MlfU - B JIOII~~N::··=II~I~t-~;,~C~C>~CM~i~ii~IB~Ifl~wt~: :::::::::::::::~lllll~ifl:~=== .-E&iWClMIOc HBITI: ---------:--------------

-.....--_. -· ' .. .....,.......... .... ___ --.~--- _.... .... ____ .. .._. 0... ________ ,.., ....... ......._ 

~-

VES 004411 
' ,; ·' J - " 

PHYSICAL DESCR:X:P'T:X:ON WOR:KSHEET 

DRUM I 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

ll 

12 

13 

14 

15 

16 

" 

17 

18 

19 

20 

21 

22 

IDI'III , __ 

PIOriLI '--

SIZE COLOR/OESCRIPriOH 

' . . 

nm __ _ 

1 or aJrJAIJDS __ 

tFULL tSOL tLIQ 

.. 

" 

• \ 

. " 

• 

VES 004412 
:--· 8 .. 0 PROCESS OPJ!:RA110NS PllOCEDORES 

) . 

Each IXICI'Iei:Dent ol a waate within the r.cility, durinc which arrr eboalp in i1a ~ IDIIJ 

oceur, meba it aullject to addit.ionel inapecUon. umplincand analyses to determine "''Jl""lFlaF ~and 

~ ol the waate.. Many of the aoalysea needed Car the tft&tmalt, 1ton1ge, and dioposal f\wcllOIIIi are 

perlormed durizlg iocom!ne waste shipment ideDt.ffication. These are not ~ uole8s it is known or 

bellevecl that the wute dlaracteristlcs bave cllanpl during ~ 

Ezlstlog and anUoipated opetalions •t the focili~. for which current and pedodjc oampling and 

analyses is importaut, 

~ 

indode the following: 

Doc:antiDi 

Incinenldon 

The ~ procedure& for eocl> ol these are described separately below. 

8.1 Stonge 

Before au.y - are placed into a storage unit, Facility Management will-the compoollbility 

of the - with the ~ unit mat.eriala ol eonatrudioo and with W1IStes ~ stored therein. 

6.Ll W.pe in Ccmtaine[s 

Ccotainerlud .....tes ue stored with mpec:t to lgnitlbift\y, reactmt.y and """P'*'uftl.y. 

CompaUI>ility sball be.cletennined .,...,....;,! with DOTHM·181 guldellnea aa 8\lmlllllrbod m the "Scggep'ion 

Table b iJa.ardoua Materials" listed ill 49 CFR 177.MS (.see Apperulix WAP.O). Baood on the initial DOT 

l>aJerd dooo delermineliou and .,..qaio ollhe waMe, the drummed waste will be aeerepted wdizic to 

eompa~. ,_ D>lllerials will be oepueted from inercnpatible maU!rlala by &tOrap in oogrepted • 

within the drum storap OO!!ctinp Tblo is oecomjillabed by the data from the WPS, Manclatoey ~ and 

~AnalYse& requetted by the Padity Manogtmvm\. Compat>1lility. iqreption will not~ to · ' 

· material ...tUcb luive been •epacbafid, ~ or aolidilled at TWI. • • + l • • • • •• • . \ 

. To fllrtber veri(Y that._... ate beloc 'properlY ·c:atA!goriied. 'l'Wl Wilt Institute a P!cl8a.., of· 

· ·Omtamerisod Stonge Compet.ibility ~ ~ will be · 1 soeci ~ perfonn!ng a liquid: Willllte' 

· oompatlhility oil the waate>eeeivod forcon+•iller t;~Qoage oooulline<lin Appelldix WAP·A. '!'be t.eotin& 

will not apply to soi.on qti!IDiity patbaed cbemirels or other material .-npted under ._U and 5.1.1- In the 

. nmt that a compalib!My is performed ... -' lab which ..... "''*''eel .. lneompatlble per Dql', the 

· COIIlpatlllility teet will toke PJecedeoee """' the DOT ............ ~ 

8.1.2 Wtste jn Thnp 

Liquid Wllltel deli'med in balk Ccrm (e.g., taDk !nJI:b, railr<>ed taDk con), or pouiiPod from clruma, 

are ~ placed in bulk t;IQoage taDb prior to inciDeratioo. Prior to tnnsrerrlog ""1 Waste into a '*""""' 

WAP·211 

•· 

VES 004413 
•.• t.aDir, lbe Ml!!p••iJ:·''itJcllbe -wi*h tbe ID8&eriaJ ~ill !be iaaltmd lbe iaak...amallcl ~ 

will be determiDod 11J a liquid - """P""l·;ft7 - (M AI'P"W'iz WAP-A:J. lA ec!c!jtlm laalt W1ll 

rompeliN!fty wiD be •-odd 11J porformiac a liquid.- • pe+ibi*y-aa lbe liquid wule n>ceioed fcJr 

bulk -.p with a~ OOiiipClliit.t cllbe laDb wilbilllbe -'•" I 1J11em to wbidl tbe DeW- will 

be added. 

6.1.8 Jbd!s 8e'i" Stonft 

Bulk oaicla will be w" I'd ao fallon for nnlnadi"' into the bullr. liOIIdo pile 

1} ~ .......... which paaooot lbe p6iDt. miAII" - can be ~ into the lllolnllle pil& 

2) The BTU ODd cbloriDe CDIII&ellta uood orill be either: (II) Tbe hill- 'IBbae cllbe 

CUI"1U1 pit or tbe Qwnlnc DIIIUirial, or (b} Tbe -~ W wil be •mp!ed after 

lllildog aDd lbe oample will be oaalJud for BTU md dlloriDe, 

u o-tttlq 

In tbe<le<enq ~liquid-are dr.can!ed rraatdnm. cral.bor ..,....,....._...,.,.... 

bulk ...... tmil&. Tbe "i'P'k"""" Manc!atory ADaiJoiea will be ptil\1iaoad ... Wllllealo be .. . ' 

. Prlorto........,t!nJ,aLiquidWI!IIeCc.,'l' llljlii)Teetllldopec:ille_.,._ .... ......,. •. ~soc! 

II8II1JIIe will be perf..--.1 lo..,..,... tW - to be balbd t.csootJ- ue piLe A.,.._ a '&fta4 

, . :) .......... io A ........... p<Ji>o."tioDM.t 0 i C qh cltbe jnte 1 '"--liqaidt. 

·: )' ·-

u 

lil 

~ 

the h ·: non .--lquld, ~ md IOiid-ue dotott..,...IIJ bicb ~ 

thermal owic!etlnn Tbe realllbll - indude ........,.... .-t11.t ... lt:I'IIIIIJeclto resDO'N sa """ . putletllteo, mf otba 1¥ • •• 1 • •-(I.a., 1111!, .. aDd~ llwlp, oorubller IOidl (bee bc8e clult) . . . ' 

. that Me 1\utber I I II. 

'l'bebttl 4 ,, , . r;;,·,..-~; b lh··-.bediYideclilliotwo4 $ ;-=b 

willl • opec;& . . . ~ 

a Pitb · f I wCII.IbllnatWibe- a.DJ.riliiD.~...,peniil&a ' ' 2' 1 

I '••llllli ....... liall timiDt cllbe s--opaliliao:wl.,...olnlioto; . . 

o TI 9 w!B i'ei!.i!t•"""coallrm~b , '"'*..Stlllitbe t rt 5 'iceGf 

!bot ...,._ .m... are mch t.bU It tao;~ be - to the .;...c *P ~ 1 1 .., .....,..., or 

1\zrtMr a·• ••M) -.- apoo permit ar ~ , . 4• . 1 5, &c. CD1Ite 

tz•• · Mnat ot lllld ~ ..-ncted ~ wtl be ~sad ...r- mmh-iect. • oeeded. · 

ajpoii>R lbe appapioe.e w· =-~or 14 I 3 .,. • 1v1t a ., w or ...... -

off lite fw st.onp, further b•• ..... rJDt.flar L4 1 will ~aft ..,.o;zjate r-•i" tj n 

1'orma 011-.duJce wi*h .c) CPil .... 21111), 

.. : 

WAP·80 

VES 004414 
. ) ... 

6.3.1 Ptt-tne•meJtt Ana!y!ee 

AD .....te. red to the indoerator are blended to meet permit .....traiD1a aod to maintain ote.!7 lt8te 

(normal) cperaiXm of the iDciDentor. Liquid - is ~ in bulk laDb prior to inciDeralica. J>ro. 

tnatmenl ~ (6.8.1 numbers Hl) are optiooaJ Car liquid waate in taob wllicb will IJIIdarao furlber 

blmclins prior to incinentloo. Priclc to iDc:ineralioo, a sample i.s drawn mm the bllllt to be fed aod ~ed 

for lhe foilowixlr ~ 

1. Heat Ya!ut - Heet 'Niue io III<80III'ed to c:ootrol U.. feed ratea of - fed into the 

incilloraton. 'lbe ...amum beat Yllloe wbicb can be buraed per bDw ia "''blished ill the 

opel&liDQ permit. 

2. Aah Ccl!!le!Jt - Aah conle!Jt is ~ to control per<:eot. aoh of wiate fed the 

~ cbem*- bumen of the izlciDeraton. Tbe ma..m...m aoh C<JilkDt forfed into tbe aecoodoay cbamM is "*b!jebrd in u.,; ...... tillc permk. Wbere the permit 

baa - eatablbbed a limit, lhio ~ will DOt be perlbrmed. t 

3. Total Qllorine Qmtmt - CbloriDe coole!Jt is -.red to c:oo!rol the percea1 ~ iD 

- fed into the illoioeraton. 'lbe mezimnm dlb iDe CXJDtesrt far waate led into -the 

~ is etllabllobed in tbe opaaliue permit. 

4 . fhp1pt Qm!m' lo ~ aod.118ed in~ with c:blorliM 8Dd bromiDe~ to 

delenaiDe the haloaen eon-in-feedo to the ......Mory t "w -"""*-of 

the illdDenton. Tbe mnfmum balopn eootalt far-fed iDto theM du) dwn'* 

5. Bl • .,Qmt ..... ia-...claad118ediD~wllbdllorb>eaad~~.., 

cfet I .. tbe IJoioeeD -"'-feed& to the ...........,. ...._._ -"""*-of 

·the illdDeraton. Tbe _.......,~"""*"~~~c ........... fed IDto ~(II> ...., .... t ... 

. pHII!nt!l!i' 1Md to~ the~ cltaali; tan. -r:rioll tif~aad poorid& 

"* a -•at cteu rar.JII'OPer hie rM !I 

7. Bprslfir Gmjtx - 'l'bio iDM D.tiuu lo 1l8ed to _.. lhd d.. apedllc ......,uy oC bulk or 

~ c:ompooite liquid is -. u-the cJeaien lpedfic lf8Yit1 fc!r the otorace taob <o.r. -

U). 

'lbe permit cpenlinawluee......, meNt""ed tbnJush a trial bum. The penail operalinc........, me,y 

be d>Mpcl lilt is domaootnted tbnJush a trial burn that the """'permit~ .iow tbe iDdnontor to 

operale will*l the penlllt = · ii1ait 8Dd a& a~ lt8te (IIOlmel) opa~ 

WAP-31 I!BVJSlON U 

9{29/94 

VES 004415 
:;"-"'· Tbe 1'acili9 vi. 8 ..,. 'will rme..lbe bleod"""""""' to......, permit""""""""' aod.to _,... 

_ .... . ")· · . . , 

.. ·. 

that lbe bleDd willllloor ICeM\r etate c--o operation or· the iDciDeralor. Tbe blood will be .....-e-1 . . wheoenr ..-ry to - oil permit opecihtim• Tbie le accomplillbed through taak-to-lllllk ~ wllh 

additiooal W118te8. A Uqul<l W- C<wnpotibil!ty Teot will be perfOI'IIICd prior to all taak•to-tanlt ttauol'en. of 

Hquid -e. This new blend io !ben ~ fer lbe blood polr'lmeten. wblcb are uoed to determiDo optimum 

bleod ebanocteristlcs as mentioned iD tbe Jft'riaul pncnpb. 

Containeri<od - ia aeqlleiiOod fer iocioenlt!ca tbJoouch careful iodezios ol CODialoer teed. Tbe 

parameter•,.. 7 far oeleelioo otpoper feed MqUODOe ar-Value, Cblorioe eo-> are evaluated'-<~ 

on tbe Malldatory ADoiJoeo. Fcrlbe - riall jdrntif!od iD Seetioa 6.U. \be """""' ol tbe above paaaeten 

are cateaoriJed bued OD ~ eod • .... I i W """''''"jm idormatloD obtaloed pel' 8ec:lioo U eod 5.L 

CootaJner feed eequmcee reflect 1D onpz.g enheetion of cpentiDs e:peri.eoce. 

6.3.2 'l'mtment H+'l!e Enlua!ioa 

Poet-tzoea-"""""""'ODd~ will C0116rm....,.,.,..,.. _.,..,, aod that 1be c:baraderilllal 

ollbe pro<e~~~ ellluent uewch that it .... be - to lbe Dl!li otap (clio<:buae, dilpooalcr 1\aiber treo-ot) 

bued oo permit or pro<eee eo-.inl&. lo ~with~ CI'R 288.?(b), reoiduM (or...-...) ..-.Jllor 

ftoom OIHite tn-i- ollaod diopooaJ roetricted ~ ~ ~ tt>d/cr evaluated, u oeecled, ...,.._:u,.. 

apptoprl•lla ..... ,_... lll.oDdanl (e.g., Cwotitueut Coooeotration io W..., Extno<t (CCWE) "f8!uee) or 

pdUb!tiaa Tbe iadoentloD proeell reeulta io tbe.&O t1jm oltbe f .... lie i ' I - ub, .. aod 8l:l'llllber 

.,.temlollda. Each reooidlle bel beOD ~~to deO-elop. , .. .. ~ thai, ia ......!stet)t 

aod iDdependerrt ot lbe original- fer iA:ioer *" w-... trw-~ - oiJ'-oite 

r .... furtber --will be .... ,q>MJie<l tiy \be llp!II'CIIIriot ,..·e ... 1 or~ forma. · 

locizleniar ub aod alas ~ io the rolar1 kim ODd ""' oerubl>or ICIIido ~ lo . . · i• !- !' •• uoita numben 2, 3 ar 4 ani •mpled, lllllb'Ad aod ~ oo a......- bMio (See ~ 

WAP·B, 8eclloo 2..2.1) in """""""" . wilh -tYtia11 p~ ""''*ed . to ..,.q.e . ...,._ tbe ~ 

tnat • Uodard or Jll""'ltAtion (See Appendix WAP-B): 

Iodoent« ... fi-nlecl·k> ~ lb .. l.lleuth. ,· ll'!l'iciD.;;.. ~ eilhor - l""'d. ttt\ll....t aod 

~ .... ~~criazetz led ..;d ~en; eele.t. · · · 

Tbe Fadlir;y ~ -d ievfew the aDeO.ticol ..... aod ~D>ioe tbe ill "'i!L"' ol the 

troeet •l'fllidue. It !be~ .-.~Umeet 'tbe ... op-..tresh••• ~ ce:,.. CCWE ...... >.Ibe . bMI w • reo~c~ue il !ben lpplOY8Il for o!ripnwrt Bilch •' ·, lflll ill ;,.,...,P.Oniec! wllb ·the folowbic . . . doc, a M .. ef t• 

Laud ])jape-' a-ictkm Treet!!Wit Certfl!cetlm; 

Aoa\lltice!Beport or re!-to 8IIOb ~data. 

WAP-82 

., 

VES 004416 
:•': 

' r''. ) 

. . . 

.. 

In the omoat thet tbe ca171ia doel DOt meet the "''JJI''Olriellnw._,t staDdlad (Le., CCWE ..,._), 

tbe FociiV ~ will ionr'lpk the illlllllpliDc procedure aDd the ~ pruc:eduro to ........ DO 

cootaminetion Two et!d!tjmelllalplool will be ••tmi«e-1 for anal1* ol the panmotere wldch • W 

lftelmos# lllalldarcls iD the firot I'OUIId of ...,.q.;.. rt the ~ aoaq- plll8, the re8due wil be ""'*Oted 

for &po.l fllhe..,..... of the """"minetlo:~C '*"be ciMenDioed, it will be clocui:Deuted. H-, if the 

.--s ~ c!oee not meet the 8JIP"'P'iate lnw•ment IIW!dard (~e., CCWB nluee), TWI will-the 

reelduee in order to meet the appoprlote -•ment l&aDdud (l.o., OCWE ~. ~. TWI -

r~ adclltiona1 IIID!pliaa and ...,.... I!Dd chooooo to rell'ellt the raidue wblch did - iDiliall;r - the 

- lltandiJrd. 

. •' 

.-

: 

· . REVIBlONU 

912111114 

VES 004417 
) 

'7.0 QUAU'JT cONmoL POLICY 

TWI 11M dee akped a prO!Jim <L quelky CDIItr<ll pndi:ei....S ~ to OIIOUI'e that prec:Mdon 

....Srma) ...,_. liiiODedthr<JucbauiaDaCilalabor8iorieL ABiite)obonltorieureK;Uktd to l*'' ·: •e 

In !bit ~ Coou.:t labcniGrieo .......,eel by 1M '"""'*" .,.. aubject to ioopectiOD ODd audit while 

pa!Drlllillc .....,... Cor CWM. A review aC 1M coalnll:t loboralory Ia coaduu:ted to eaoure tbet 1M quality 

ecotral aC CWM data ia 11•1111 1 +i 

Tbe quality CUIIlnll jAO!Jim Ia buecJ Oil "ffepclbook for ADaiJtice) Quality Control io w~ ODd 

w~ Lahontorieol' EPA, lUrch 19'79. Good lobcntooy ,.. r .. whicb '"" _,.po 

hii!IC!tin& bcuoekeepillc IID<I oofety - maintolne<l Ill aD laborat.orlee. Tbe followillc praot.lteo - be 

in~Jolonw"od a& .. lite loborotcrioc 

All iDotnlmealaliol - be ~ tbroagb 1M - a("" ~ c:beck lll8lldud. 

Dhag • • froaucceplallle """""nwlt criteria nqu;r. couection. Tbe ..__ ~ 

ataudood resalle- ...... deoi Tbe .-d mit, ... CODtliD =hwtion ... • .... 

beodwnert criterio aDd rneim ......... reeords. ' 

a...,.m bUb are tn*:aDJpepatd with M<h blldl aC...,... aDd -'>'sed to -... 

- oample coolemlne'ioo bao""' OCCUiftd. Ilblmlt IIIIAI,y.- do 110t ran wtlhiD acceptable laiito, 

A...,.. 1o -o-s ;., +'f 5 , ~;r: · .,_ ~« M<h t-.r wi>plrio boiac ~ ror • 

puticq1or permet«. A bliDd ""P""e'a BDple will be ......... td to 1M i1bon14rJ lXI a 

IDC.'IQtbb't.lis. ltelllll&a~tbeee "ali ••-.lJ-ewilbetavicwut.&:r · t )· 

A qudl:y conuu oolution ar oompJe ..-terial will be ~ a& leMt .,.,.,. ror M<h doy or 

.-11 Web i\IQ to ... tbet eeljj I' aDd -- 5 • • I a( ill ' .... __ ..., B ftbiD 

ao:ceplabie limlla. ,. prOcedure ..,.,._ 1M laboretoi:J' !hat preocrihed pro I i= ODd 

... .., n boiar nwiD•einowi a-.t~o aCtbeee a:wob-.... . epcww ror review. 

Few•• •L " are ~ to .-mr neue ia md M t • exbcticu. rDJ/r~ 

I illlw tee!1u4ipw at ............. lewela. 'lbit ~ potitle& ilaC« lh 1 aluout 

ilie e&ct ot tli....p~e ~ .. lbe ~ill q I' T;i. ., ... nlllci of ~ 

ruu·s •• It« eid. ~.,.ilea~ wil be wiintalaed u.U.U:,,Ihe _ _... 

....r ... tbe .......... ...,.. wil be forti6ocl. 

. W.AP-34 &BVJlliOH u 

9.121119' 

,. ' 

VES 004418 
. .' ') 

' 

WbeD 8'l8ilohle, ~ maiA!rWo &om the Nadobal lmlitm or ~ aDd 

Tedmnkv, or re.r-ll>llllerlall &om~ other recosolsed -, will be obtained aDd 

~ ..... dine to DOI'DI8! W>ara~ary metboclolagy to IDdi<ale eceunq or the methods. 

n- maleriolo will be iaal;yud ot --. quarler!y il' the Jl"l''IIDeler baa been perfi>amed 

duriar that quarter. Reference ma1eria1o are not required Cor acretitlog metboda. 

AD CWM laboratoriea partlclpate in 'rcuwl robin' sample ~ 'n-. oamplea will be 

IIUbmittecl by the QAIQC Group and will be for the anel}llia or1101111a1 perameten. s-.!ta ~ 

muot be reported to the group. Dfei uklol fnmlthe norms -bhbed by the Ulljar~ or 

labonl.ories particlpeliog will be inftlllpled aDd ~ 

At ~ cme llllllple per month Is eeo.t to a CWM d ·an '"" labonl<lry or a .............. ODd 

appl'O'Yed C0111l11cllaborat.ory rer porallel-"-' Tbeee op11t oamplee or a J'8PCrl or bolll 

reouJ&o ..., eeo.t to t.be Quality CooQoJ. Unit wileD. an OUUide loboralllry io ewplojed. 

Samplelaent to the ~ lohoratory wil be J.aaled in ODd analyzed without~· 

knowleclp or lite lab Naill& 

- Tbe fllcilily nporUo the followlnc iDI'armatiaD ... •IIIOOIIIb-be* 

0 

0 

0 

0 

0 

Nlllllber or """''>'e8 ~eel 

Numhor aDd reoW1a oC d•q.Y. "" 

Nlllllber aDd,...... cl fart!flcellgns 

Illlb ...a.t ..eel 

~or OCX:WniiCe for qualt:y CCIIIIlol dledl: ........ wit.biD ecceptllble 

Jimila 

o M ... aDd lllaDcWd deolatiaD or en.oJ;Jte in quetitioo. 

n.e· lilclll*>' allo reporta iDtra-.lab """ I'OIIIId robin reoulla .. lbo7 - ead ,..,_ 

---anel}llia ot Jeut quarter\y. 

A written ""PY 'cl q third puty ccintow:t IUJontory'o ~ ecatrc1 p......tateo Is •"'"'ftted to 

CWM '*"'to lpP,IOIIl. . A qu.ik, -w-IDopeo:liou .. oqgdoded to ..... tll!o* prilpor.ftoOC>Idi ead 

· @ ++ i are...;..~ DllliD......t All~ ..... ~ to 1w> t liouaD<I-* of~ pi'OCOCJaree 

while 'UIIdor contno:L to CWM. A reriew of tbe - labcwai<Wj Is .....;....eel to _, t.bot the q.iality 

OO!Iitl'ol II beiDa miint..;.,..s, 

WAP-86 

: 

VES 004419 
. . 

) 

.. . ... . . . . . 

. . •':'\ 

"' / 

APPENDIX WAP-A 

. .. . 

. ·,' 

. ' 

.-

• . 

. -

.· . . . 

VES 004420 
.-:, . : . } 

'n>efollowiog..qtblpr~ are deelped to iclenti(y oroereen -· '1'blo' an:-.-! b7C'Nli, 

baed ~ ita opentiQg expe leoce, aa rllpid but elroc:tive a>....,. for estaNi•hing kfl7 decioico per-. 

perllnes>.t to proper--rite me•• Tbe _.,_ cleecribecl iD tbe eec:t1ao1 below ore t.oec1 oa ASTil md 

'SI.alldard lletbocll' ~ b7 EPA or are hued cc procodureo aod ~ CormuJa&ed by CWll aod a>eet 

CWM perf""""""" -...m.. Aoaqtbl procedunls DOt lisliocl below 1111\Y be added .. neo r ry with prior 

IEP A appnwaL 

It IObould be noted tbet tbe inrormatioo .,.-..1 Ill th!e appendix II pocric in ebenlo:ter. TllenCore, 

oertaiD-a>ethoda are clillo.-d wblcb llllll7 pertain to tz ' em or dilpoea1 pre c - tbat ere eoa:luded I':JIIP 

lbe cadllty for wbicb !.be fo~ WBIIIe ~ plm il )>reooDted. 

J. UNIQUE ANALYnCAL PROCEDUR&'J 

DOt lmlilol>le' fioom "SSaDccord · in 8ecticm n wblcb ro~owo. m ot~>w-. u... - are ••lwtihtted 

for 'Staiodtact .w.tbod8" where they prvoide .,,&..... equMioDt infonDIIUoa. 

Bmsb sc;r-TJ=••••11!rh ... km · &anp&-olWM'teaarectBDbinedwit& JMnplee olotber ..-.err a 4• 

at ~ ratic:& hrthi::r t.estlng iDay be requirecl in cWder to CODllnD tbat tbe cleeirect ..-... -

ocewrect. 

Qb,,,, 'Mr vlkrh+ '" bfiPetrPglbc•'*'••LimMQ:rte•• 1 '"*' lBPLCl ·Tbiamethod(CWK&?8) 

lll'ortbe.....q.uoC2,~aclcl t2,4-D),2,4,6-tricbloi ipl .. • )acAtii:ldd CZ,4,6-T), ..t2,4,6-

. •. . trichlot .,.. ..... , .. ~ llelct (l!iha:) ill ~-eolilll ....... BPLC/tJV. Tbe eblr:lropbeDollli<kle SDcl 

........ ~ to~••li•• Mila b.r heatillcdllirr!DJibe~'rilt...- olkali. 'l'lle ... . . -

) 

IIJ'e u-.o....n..a ~ 1oepee\tte ..-b.r the eddi!ion oCHCL. 'ibe "qqleO'JI ri'*ime oilbefiee"..a 

are thea ~ uob!r HPLC Wlin« ullrimolet clotedlao. 

Ill ...... &!~Met . An llllquot oClfBBie is a>idcl with cli8llllecl -ter. 'l'lle ~ ;S fllt.arecllhrouJb 

IIIIer """"'aod tbe ,.....,..ent flltl8!e il then anai.Y-1 r ... sul6cl& 8omnoled .. • · ~pot • rm - 11114 

1:1 hjdroeblaric'ldd are added 11114 the eiJior Proctuoec! is olsuallj COIIIp&led with ataDdM elL 

WAP-A·l JIBVJSION U . 9129194 

VES 004421 
. ) 

Heel l1eh1t br XsiDO:wed &At• !NlRl Sr 2 1 - Bat m ........m.;, io defemlnod b.r xluftued il*b.-.pj ill a dillllle Nftertarre mode bJ pAoeillc a paoperb' miud....,.. ill, a c1i1fua ~ 

cell. 'lbe ..,...._ podweo NIB .mo. ....... tpeetnc whi<h- c:oonet.od to a._ m ................. 

wiDe a preoloolly deflaed aolibultiw -. Tbe motbocl lint ..,_ far ampleo to estreot qn•litatift 

apeet>.....pe f-&em the NIB op«tno and then j»>OIoces quantit8ti'fe dot& Car._ m mmt.notjre....., 

multivariate talibratioDL 

Mota!f!!qeep btX·Bay1'lyon "' IXJ!F)- W•uapleo mqbe p ; al,il'= -,. l>JeriD<Iolctoa_ 

"'""'iDed mnhllise. 'lbe p...,ed .......-ill placed illaemple bolder and poeitloaecl far .-line-~ 

oatp.lt irfentj6ee tbl p M f Clf lt'fWIIl ~!or Li ~ C pGJ I I Semi-p• f& r ~ I ) Hted .IDitiall 

ill then pooolble .-a... to Dl:riz -"bed lluldudo. 

""'"""..,,.....,.., ......... ,.r.., -Aportiwoflllmjlleia ,..·; •IDtomwqaiatewiuowwdi& ,. ... ._... 

die ted uolag a mizlwe of aitric Uld ~ od<loL 'lbe .-1• baited ill a wiaow&N - ..... 

IJCOJII +4 llepo to ft"linkniae the 1 ee:Ji'ly of--., A.tt. ~ the - dilaAd to~ 

~ filtered aDd -'1>ed bJ the appooptW.. ~ 

<BW.ete 4010) bJ ..., wu;aiate oepn~~ao pcoc:edxa• < .. ,., ema:tiaa, flllz r , ~ tbia ~ovw 

~). Tbeestreotiothenllliadalld~illalltep wiw......-illlideodi>od;r< 2adtuba 

'lbe • •• 0 • of milia& ~ Uld _,..,taboo about 80 ,.,_ 8lld ,_..ill a CGior cbulp ill 

~tube. 'lbe eolar 4eu l'f w 2 io iuuuwly popcatiwal to the _,.,..,.,. ... -til . .,of the enti' t.J • o r 

~)of""-,e.g.,baul:lkldw,J 2 ,. opbeool(PCI?,pw2•~~ et!eb,)ch-booaCPABII), 

... tolal petl .._ JoG-t - ('l'P&j. 

PCB s.re.. bd I - 4 partiaa oCthe ~.....pe io PEl ,al,... 101 . i .. 

(CWM9HllllillJN·«01>Jr.s1, -> rm- '8 ,~,· }Ill cdbJ .. :1 'lbe-.-Cm.s . . . . .., . .is theia llhi:led IPi!d i ' I 2 ft:J ill air., ,... pr-ooei. iDIIde tie. Metlboc~i m'ed tuba 'lbe·- Nmlu of~ ... 

a-b&dar Uld , . .. li!l tabo !ibau'* 80 miDulee Mid ,._.. iD a eolar .... 1D ~ tube. -D.· C111cr • 

derelopmeotileiDta~pcopcalicuoltothe •,. • :1 ofPCBuadiodefectedl>Ja~o • 0 • 

fmnt Aci4jty - a-.. are 'EjiOtlul a JIOI"'IIl ol OoOO, ...,Do hot or the JW :1 *' opeci6e opeciea if · 

......... 

; 

' 

VES 004422 
~ Qn!clr 'ri !S•IIP:tioo Pn!cec!ur! • Adeoignated- c.--.mp~e io llliDcl wllh tbe lf'l*qwiate eatrodJoo 

J]Qjd aDd fl!rred rcw ad ·petecl time period. Afterl!ltndloo, tbe pH udl.ar-.. CXIIIteDt ... det JmiDed 

llling lbe appropriate !lppi'O'IIld me!hod:i. 

.. .··) . . 

Wnec<jy!ty 5cmn ·A llllmpie oCwaote -erial io ~by a~ CIIIUDter or 8U1'W17 mew. ~ty 

Ieveii aboft ~ ... DOled, •-dod ad iaftetip'ed 

'1'lpk lB!Il <;qppetjhi'ily • A.•-I!Odd by per!ormiQc a Liquid Wute Compatibility Teot oo tbe liquid -

- will be added. CantaiDment area muter eompooke wiD be made up OD<e per week. 

matm.l will be cbe<kecl ......,., tbio- eompooite.. 

Tbe ill ic .. ' 

\l!emo!tt • Tbo ~ of the mat.erial 1a vWually ....._ted mint~- .. a..,_ rcw 1ow ~· 

• " 

r.mtejp=jze4 S!mn fgmte!j!!!jty. wm be --"'by perf...,.. a liquid w-CmvpotiWI!y Tea"" 

fhe waate a Gifelted tor amtafner ..... M CoDon; 

a. 'lbe teot PI OJ"- llfJPiieo 01:117 to - ;.! tW &llo tbe p&illt lllle U:& 

b. A muter ..,....,.. for each ol tbe DOT buad cltue cetepieo will be me!ntajnec! d tbe llil:e. 

c. Tbo IJIMier o JjiOiite will be made up~ by acidiz>c 100 miL of each ......m.r in the co' &"J 

to 1111 ......... , tab' lioad --. •

. d . W'- tbe ..i.ect rcw " , oa.ffity Wlli&elloo hao been~ a eompMibDIIJ ~ w11 b;e 

· pel'cwuioe4 :..U, tbe .............. DOT~ oW COIUgdry. 

e. 'l'be : t '' ·.,. - Will be pe:formeclao ftlllon: · 

· · ·L · . lA ilrcier:tA>~IIiutlle JIIilltecaqullu,:P olu.~ ...... ldolu JlD 

.· ,) .·,; 

. =etc ,. the --.er «•tp -.Will be maiDtalaed m .a w ·+i , i;,liied ••· e . 

. 2. A,:llJO lllil eomple ..,.the ir•n,lng ~ will be .tbeokeol ~ a 100 lllil -.pie ol the 

iljiP.qwia&e DOT baiard clue maoter eompc>lite ...... U..liqu6d • ••tiJjty.teK. 

8. If tbe ...,.._ pa-. the OOIJJil'lliblli teot, tbe eDtire liOO lllilllll:dure II edde4 to the 

. ........ eompool.te. Tbo ......,._ ia UleD apptO+Ed to be IIGred widliD ~ oltbe aioelue 

~ """''inin& ~ oe tbolt DOT ~oa.on~c:~ooe.,. a , . 

If tbe .-..... raila the competiiJillly teet, the ..... will IJ<It be adlleol to tbe -

COIJIIlOI& 

;. 

VES 004423 
8. U'the..........., il DOt~,.,. wKII eay eziotiar DOT ha.d doio- he, the 

clr=- will I» ...., 1 'ad ID olof:lrCe UDtllllll:b time tbat they com I» moved cllreclq to a 

~-tar 11-..t. 

'!'be teotinc '*""'-wil not IJIPlJ to -a qou>tity ~ t!.emlrolo, materiallhelbM been re!*b&ed 

ar ooljc!ified, ar other materiol " "'"P""' UlldeJ: UA la16.ll. In the_,. 11:.-a e , .. a ~ il pa f'oi awd 

011 ma&erieis wbioh- in<lialled .. ..._polible I* oor bual'cl clua, the """'P"tJM!Iy- will take 

'* ....... u.e oor ~ .-.,._, 

PAB..UIBTER 

Sample Wed Up Techlliqueo: 

Irmz · 

Acid 

~ 

dia< .,,_~for flome lllomk: 

aboarpllan opa:ti....., 

Add ......... jii'<U<Iln tar a.rAdd~~~;""" Add 4 .... olcilt, .,_ortH.oludoa ,....,..u. tar .....,_ 

Acid di8 ... ...... 

-

c( ........ 

Alb6De di8 ,, (tar eolldt). 

Orgimie 

~ 

Teclullquee 

bmelliquid-llqald -aDa 

Omt,imra · • 1 'k • . Af:id..bue dea-1ip. ... • .. 

.Badllet -idila 

.MBTBOD BEPBKBHCB 

8-8«17; 1-8020 

&91~ ·-!1128; &-BalltiD .746 

l.aoaG 

1:3040 

8-M-08; 1-liOiiO 

1:3080 

&r+ ·~··~ . .. !tje.jM CGiillm o 'Aiit..i ss,.~-·t~~· .. otP••etalnlli "ioaaw .... llarooitC Y . a ' ,. 

IHU-22; 14510 

1-3620 

1:3580 

1...0 

l-86GO 

•t-liSU 

. Bib Gel ao-..p . SulbO wp 

L>ao ...... ~ W..bocllo: 

~Coupled 1"'--AIAlmic .. !!mi ..._, .. 

BJa t » ,., UCPJ 

A••' J 

Ala:Dio abicapdau, clirec:t I I " " metbod 

A1Allllic abicaptioa, furmce .-hod .ArMDic 

Ala:Dio abicapdau, rur..ce -*bod . 

A1Allllic abearptiarl, ........ tvdride IDOitbod 

WAP-A-4 

8:114-22;-1-ae:IO . 1:S830 

IHW-22:1~ 

1-«110 

1-7040; .. 20U 

1-'!0U;~ 

IHU-10; 1-'1080; .. 2CU. 

1-'1081; .. 306.8 

RBVIBlONU 

9121119' 

,. 

VES 004424 
.. 

. ")' 

·-

PA!WIB'lD 

BoaizD . 

Alomie abootptiw, direc:t ..,.Uotiou -u.od 

AIGmie abootptiuu, 1\unaoe -u.od 

Beryllium 

. Alomie abootptiuu, dlreet .......... -u.od 

Alamie abuptiw. Nrnac:e -u.od 

Cadmjen 

. A*omic.abearptioll, dir«t .... otiou method 

Atomic abootptiw. fia'naa! -u.od 

caJeium 

A-* abo ptiw. dlreet upiratico -*bod 

Al=lo abouo ptloo, runwe -u...d 

Cbraaoium 

Aloalit abootptiw. clir<ct ............ method 

Atomic abouoptloo, rum.:.~ 

He:aataluat ~ C&pc fg ··.me 

Besa"fllilllt c:lllomham: Cc.looi&Mril! 

eow- BeoamiJeat c:m-lum:..,.... ~ . 

Iroo. 

Alomie ~ clir<ct ..... otiou -'lwei 

Alcmlc lot t*• ' filn>oce -w 

AtCIIDio lobeotpduu, clinct MJ*IIdun .-bod 

AScall: abootpduta, &-. -w . . PbalaolhrcliDo melhocl (f--.) 

I.-I 

Al<mic abouoptiw, dite:t ......... -*bod 

At.amle abearpdaa, furriaDt Jadhod 

Mp wo 

Mea 

Atcalic el+ I ,; "• direct I ' . . ' met.hiocl . . Alomie IIIMwptiLcl, filn>oce -w 

Y ; f....a tHo 4"* t. 1 +r-l 

IA.Jcrdrlwae --·IA:..JIIlw r n.....,. 

N"dool .~ ... 

ASclllic:~jijiw, cllnct ""''irirdun -*bod 

Alcmlc • ; . • ' """'-aoi$bod sse~o·-.· 

Atomic alaaptiw, funloo:e ~ 

"*--o el j ' h \ ......... ~ melhocl 

saAtomic abuptiw, direct ............ metbod 

Alomie a.lwpiou, Nri.ce IMihocl 

1-7080; 4-liOB.l 

1-'ro81; 4-208.2 

1-70110; 4-110.1 

1-7081; 4-llo..t ' 

1-'1'130; 4-21!.1 

1·7181; 4-213.2 

1-71«1; 4-m.l 

+21.6.2 

1-7190; 4-118.1 

l-71111; +11&.2 

l-'7UIIi 

1·1196;~D 

1-'1187; +~ 

. 1-7210;4-~ 

HID.2 

1·'1380; +21111.1 

+2:1U 

:.i..s&OOFeD 

1-'TCO; +2311.1 

1-7W;._.DI.i 

1-'7460; .. :H2-1 

1.17~ .-MS.l 

+-J4U 

. ~12; 1·7470 

&34-05; ~12; 1•'7471 

. 1-7630; .. 249.1 . 1"7611; + 248.2 

. "'"18; 1-7740; oH7D.2 

' 1.17741; +270..8 

1-7780; .. 272.1 

1-'1'181; +272.2 

VES 004425 
.. ~ ...... p~· 

. · .. ·,?\ .. . !I 

Gu Qli I "' , .... )&thoda 

B•' 

N~ 

; ....., Volatile OrpDicl 

Volalile OrpDico 

Aromatic Vclali)e Orplliol 

A<rUeln. 

PbeDOia 

~ ... ~ 

~Eaten ()rpDOCh1orioe Peotkideo aDd pCIIo 

NitroaJ'OdiSiict aDd Cyclic Kei<IOM 

p~~~ 

Cb)orill&ted 

()rpnOPh ....... 

~ 

Peeljdc!M CbJoriDatedHer,. r• 

ocs-. 

GM ~ Bpt<b 'P11(ethoclo 

GCIMS )(dbal fOI' DiolcliD 

GCIMS )(etba<t!or VoiU!Ie OrpDicl 

GCIMS Yatbad fOI' s.m>-VoiU!Ie ()rpDica 

Infrsred Speeb"""""' )lelllodl 

9a ' 4 c lo{elbodo: 

WAP·A-8 

1·7840; '-2711.1 

1-784.1; .. 2711.2 

1·'19150: .. 2811.1 

• 2811.2 

1-801B 

Hl015 

1-8020 

1-80110 

1-8040 

1-8080 

8-84-22;1~ 1..., 

1~00 

1-6i21r 

1-8Wl 

1-8150 

H&O'J; a.B21!0 

1-8280. 8280 1~7~ 

1~ 8S'IO; .,. 

a.D'J621, l)tOiS; 6-

BBVISION 11 

9129/94 

:' · . 

VES 004426 
.:-:• p}.RAYE'l'ER 

~~Methods: 

; '"""' .J 

........ ·.::) . 

Acidity 

AlkalinitY 

AmmoDia 

AnioDB by Ion ~pby 

Aab CoatAA' 

Bromidee 

Cblorideo 

Ext;ractioo 

~~ 

J>rccedure 

Flalb point Penaky·MarteoS cJoeed-cup method 

Selailosh clooed-cup m.elbod 

ClevelaDd opeD'CUP 

l'luoride 

Pr8e c,ao;dee 

HaJoceD CcoleDt 

Heat Value 

Oil aDd Grease ()Diedon-)ledul:tloo (Jiedos) Po\ellllll (OBP) 

Pel;relkum HJdrocUbolla, Total Recoverable p~ . 

pH:M..-ent 

Pbooi>"""" 

~Screen 

8otidl 

METHOD REFERENCE 

8-9H8; 2·2310 

2·2320 

4-850-3 

s.sNo: a-D482'1; ..aoo.o 8-91~ S.D482. DS174 

2-4600Br'; 4-SOO.O. S20.1 

2-41i00Cl'": 4-900-0. 826.3 

S.D1125; 4-1.20.1 

HSI,O 

&8H9; 1-1010; &-D9S 

t-1020;3-~ 

s-D92 

2...000F"; 4-SOO.O, 340.2, 340.8 

2-4600CN1U 

&-))808, D2861. D4S27 

&87-37• S.D240. D2016 2-6520; 4-413.1, 4ia.2 

&-DU98 

2-652QF; 4-418.1 

2-6630, 8420; 4-420.1 

1-\lOA 9041., eoci;; ~; 8-E'IO; 4-160.1 2~F: ..aoo.o, S61U"' 

8-87-38 

· 2-2540B; Heo.3 

2·2Ml!C; 4-160.1 

2-aMoD;4-160.2 

2-2640E. 2540G; HeM 

ll-2710F; 3-D71l..D8111. "Dl2l'l, Dlol29 

240080.'·: 4-300.0. s'IU 8-87~ s-D129. DS17'1, D4827 

1.0010A; WSOOCN'"C,G; +3S6.l. 

&-l).608.~ · 

U$10; s-D26'19 . . 

1-9030;~

HSU 

8-86-815: &-D88, D446, Dll98S . &-1)96, DSl'IS, B208 

VES 004427 
..... ~ 

·,·') 

--· 

. ' 

·· ) 

'!be~~ are cleiecllbed In the folowioi puN• .. ._ 'lbe lint dicit fll lbe 

ree .......... IIUIDI>en above ore~ to the numbed..._, below: 

1- "''eot Mel.bodo l'ar EYaluatincSolid Waste, P~ Methodio', SW-846, Tbird Ectitlca, 1986 

u IIDODded 11.1 UpdaU I Co1ub' 1992), 0.8. Butb *'"'"' Prot...uan ~. Oftiee fll &61 Woet.e 

(N'l'IS, 68 Pert Ro,al s-1, Springfield, VA 22161) or - .-nt edita or revilioo (GPO, Supt. 

fll IloeumeDU, Wl!llblngton, DC 20402). 

·. 

'Stadord Methodt f« Ilia 'Enm!n•!lm <I Water and Wulewoter', l8lh ~ AmerlceD Puhllc ~ 

H!!flllh ....... t!an (1015 FifteeDt.h Street, NW, Weal>inctoa. DC 200()6), Amerioan Waler Worb 

7-

~klo, Watet En•il->t Fodonltica, 1992, cw more recent odiUoo cw upclale. 

"AI!Dual Book fll ASTM Standotda', Amerioan Society for Te8tlnJ ODd Ma• e zWa (1916 Rltce Street, 

Pbiladelpbia, PA 19013-118'1), 1992,..,-recent edltico 01' re"rillon. 

"Metbodt r ... Cbemleal A:oaiJiia ., w- and WIIJfW, BPA-«X!/4-'19-020, u.s. Bawb I noeuta! :, 

Prol«tioa Joaerx:1, ~ Mr.aitcrinc ODd Support l.olbarai<:1r7 (Cinrirmati, OH 46288), .. 

reorioed .Man:h 1963, ... mare recent .........., or f«<miMI ediUcn. .. , 

Inbond ~ Melboclln IEJU,B'I'P Prooedurell Yam.~: Levell En>io--'IMDtal ). -

(2D4 Bdl!lm), EPA~-7&-201, Oct4ber, 1978, « II!OI'e receot edltioD. 

"hid Digeotioa Bombe-", Bulletin 47.S, Parr~ C'hnP"V (Moline, n. 61266), or mare .....,;.m 

buldln. 

"Met.hoda r ... Orpme C))emicel ~ fllllunit:IFel IIIII lDdwolrial Wlllllewaler', Appmdk A fll 

'1\lle 40 Code ol Fedora! BecuJaticmo Part 186, ti. S. 'Butihll .., Prolectiocl l!emq, 

~MoaltoriJJclllll8uppart~Mpme r!edJimta1980 ... marencellll 

l'1l'liol<m. 

'CWM ~ Metboclo Mauuar, Q.rmjre! w..te ~ Ine.. Anal,ytbl J>roeramo, 

September 1992-

. at-lani-~Jtb~ .. oeedweelioled ben wiueh ...,l'l!'tiMcleon be lmplemen~ upo11 the etrectlft elate fll 

t.he 1et' . o, wilb Mlll!ce"ah.to t.he IEPA-DLPC Permit 8eetloi>. 

·. 

WAP-A-8 BBVJSION U 

9129/94. 

VES 004428 
,' ... , 

APPENDIX WAP·B 

ASH AND DRY SCRUBBER SOLIDS 

.. 

. I. ' •I. • - .. • 

... 

' ··.: . 

VES004429 
'·"':'·"• 

. :' 

1.0 PURPOSE 

APPENDIX WAP-B 

ASH AND DRY SCRUBB~ SOLIDS 

SAMPLING PROTOCOL 

The TWI lnc:llloftll.cl destto)' huardoaa waatea in bigb temper~~ture tberma1 cuidation J>i" Tblo 

procedure proricleo --..ce lbat a repr....,tat!ve 181:Dple oC ash or dry ~~:n~bber ooiida (DSS) io colleded for 

~ 

2.0 SAMPLING 

2.1 Sample ldeDtlfleatlon 

2.1.1 Each sample '"""alner ia labeled with date, time oC cla,y, tompltr, and con••i-jdentjfbtjm JIWIIber. 

Tbe IUiJpleoare Joaed into lbo laboratory Produetion ~ lc¢ook upon c1e11wrJ to lhe 

laboral<>ry. 

u Sample Collection 

2.2.1 Aolt aod DSS IIIUIIpleo are ccllected, aaoolyud aocl ewluoled on a quuteo1y t.oio to oaaure lbe 

; 

2..2..2 &mp!ee are collected aa outlined in Section 2.2.1 oC tbe W AP. An ...,... ia ~ uaeci to obUin 

a~ aample oC lbo ash or DSS. Each oemple jlr-be filled 'lrilh IOih or DSS. ~ 

2...2.8 . Trained opentiooa ~ .,.;n ccllect tbo lllllpie ud ~ ....,., .. ~ec~p c:ustocl,y by 

oowpJeem, lippllcahle eediooa oCibo _lohoNI<>ry Pmll....... 0 . 'n~-<:uolody qbooiL Sample 

preperation ud ~ wil be por!ormed •...., .. p '!rwNe Colowiog wbidllbo l!eJ ..,.,., oC 

the lllh .(Sectian 4.0) will be dete7minod. 

2.3 Sam~1 PC5RWbiid 

2.S.l I\ io the ~ oCPedlil7 v..,..,..... to 1111118J> CllllJ qullifled pei.....el to perform lbo Mh 

or D68 IRII2pllne p....,...,a tbet haft ~ lnliiiW in the irnple"*Diation of lhio proceclure are 

COIIIidt!Jed to be quolillod. 

3.0 SAMPLE ANALYSJ8 

8.1' 'Each ..... wil j)o leDI to a CWK or CWK iifiPIOIEd lab tor ... oC IJlB ccw"'>_.,; b,r tbt . 

"''P'vl*iiie ~ . 

3.2 Tbe triddua at-codoa tbiousii tbtt lockaeralir:ID .,.._..to the incineratar reaiduala wil be .._ . . . . .in ~ wilh TWI St.Dderd Dl-risloc Practice 161SL 

WAP-B-1 .RE.VISION U .. W29/94 

'· ' 

VES 004430 
.··U 4.0 

u 

4.2 

u 

u 

··· ') 

.. 

. . 

. • 

-· J. 

DJSP08l'J'ION OF A8R AND DRY SCJWBBER SOUD8 (1)88) 

ADr ..,....,, of Mh ... DS8 Lbat wu IOJilpled for tetotiDtr In........,.. to the app~opla&oe lt'""•ment 

standard or probibitloo, will be mained by lbe facility until nUia ere 8\01Iillollle for -··m 

Tile aoaq.ia .-.Ita are ='reel ap!Dot the LDR ll"h"""''lltaDcluda for lbe cocleo in the ooat•'""•· 

The ..,.,t.Ome, ia ~if' al t-ee'nep! llmdordo ue met. 

Tbe ~ .-.11. .,. ~ .,..mot lbe LDR -tii&Ddatda for all cocleo IIC<epted by 

TWt Meetiltc the - st.oodarda Ia de.maDsltaled lhrwgb the procea 

When eompliMce with the LDR lltaDdards bill been demoostrated, the 11111terio1 will be etabilill"' aud 

ouboequ<miJ.yclisp-" oial CWJollqlproved '-nloua-~t f =·;,., Tbe DIIIDir..t aud 

I.encl ~ ReaVictioo Tratmeol Cettj;f\eetieoo will be 1 1-ted prior to .t.ipnen• 

WAP·B-2 

/ 

( 

VES 004431 
APPENDIX WAP.C 

WABTE ACCEPTABIL1'l'Y CB1'l'BBlA 

.. . 

,• 

··. . \ 

·:·.· .· . 

.. . 

... 

VES 004432 
.. . : . 

. ' 

:·.·:) ......... 

WASTE ACCBP1'ABlLI'IY ClU'IBJliA 

Tbe rollowlog Nettietiuw apply to the acx:epC&oce vi-exbibi*ine certain properties or apecillc -

u T.WL Prior to eccepU~nce c- Seaion 6.2>. the Mandet017 ADa~yMo ODd the w- Prollle 8beet ..m be 

e'f8luo&ed opiDot tbio appeudiL Alq reotrictiaos ldmt!l!ed will be doou11....,ted Oil the - ..,..,..._.t 

deci... Tbe !itt viitem8 under eech vilheoe h ........ io--to be e:xhauortift. Tbe pUIJiLc ~ 

will iacble a re.lew vi the MBDSa a a -.cb vi the other blbliosnPhle --<- Appendix WAP·P> 

fllr o,wouw, product- common -.. The ll&lure ol tbe .-tri<Uona are aa ro~~owc 

Bf.JICT .. 7hete Met-,.... may J10t be proc 

Thorium C«DpooJOda 

u..-um Compoonde 

d at the t•@ty. 

Reclnec!m materWa aa dellued by the TWI Part B RCBA Permil, ar .,-er U.. jU millinda J* bour 

(per 8ecticn S.U) 

.Perjzjt !:!spits! Wi ! 

WAP.(}l 'REVIBION 11 

MMN 

VES 004433 
..... 

D008 NlCd J!atteriee 

D008 Leed acid BaUeriee 

K069 Non-Calcium Sulfate 

Pboopboi<><IO 

Metial }Vdllcla 

.iJIIooe6.i-roomateo . 

i.) · . .-· WAP-0-2 BEVJSIONU 

9/29194 

VES 004434 
... , ... 

. '·') . '· .: 

Wti/IU wlDeh eahibila es>e!J"tlc d>anlcteriatlca (e.g., poc>pe!lmta, exploaiv-. ~ Omruneble llquida, 

elc.) will either be ~ per \he Smell Quootity Cbemicalgolidelirww or will be ..,.pte<! per tbt UowJuc 

proc:ed\ft. 

When \he -.olume o/a-lltl'OIIIIl or c:lwla'ee ill illcinerator per!cnDIIIlCO indbteelhoi a ...... chwge me 

io ...-...Jtecl, TWI will follow the following proceclqn: 

l) Tbe material will be reviewed U1inJ re!....,_IDCormatlou, MSDSt whee 

available, geaerator di"''tO'IrGo or pnvioua -ieu::e. :a-d Oil thio 

review, TWI will determlne it a ...... eharte me ia ~ 

2) When It baa been deletwille<llhoi alllrger charp m io ~. 

TWI will ei1.ber. 

-> ~ ifthio type o/materiol 11M been~ pro d at TWlill larger dllqe "!-

aDd lhonbJ ••bljob a ebargoe lile; or 

b) c-hri a- barn o/the -*'ial to~ wW dlolrp .U. would IMi -.pteble. 'l'llia 

teot barn willslarhrilh !tie qtlADtll;r tlpOCi6ed in \he BQCG'o of the ""'"'rile"'' 4 t~~•eot aDd 

be inn ' by co more Ibm doubla the preoloue c:barJo ftoGm lbia "atMt!nc pciDt '-"4 em lha 

iocineo"*"'" ope.atlmd.. Tbe iM- Mor operatlooa ~ whioh will be enlao&ed to 

det«miDo if dlolrp .. ""' be inn ! ! d will be .. . 

r..uo-

> Y8CUl;!Dl cleCI t Ill \he prlmaq or """ oodo•1 dw,.,;,.. 

> Temperature lila'' ••• ill the primary tbaber ol > lOO'T 

> . V".....t IDenupdon of the l'riD*7IIMM 

> N-otea.V o1a1A1 pia flow. 

NOI'B: 'l'llia teet pmocol OliV be utilbed to • Hfeh re'fiood <Drp.., fw .U ~ preoioiJob' llmlleci 

in \he SQCG;a. Teet barn ,....,,_!Migj. wil be potided to lbe IEPA-DLPC priar to hnrw• •••.r ........ <Drge .... 

WAP.C.S BEVISIONll 

~ 

., 

VES 004435 
· · . DIOXIN lf.i llNG • lrute.,.tdcll Clllltaln ~than Mlsotu.-Coa.citoe..ta requlredlmdn 

~ IIi a 1 ppm tau.bDid before 80C8ptaDce. 

Erbcn (2-<2.4~>-et11112,2odichloropropanale)) 

R~ ~Jene.bio (8,4,&-tric:hJOI'OI'bes>ol}) 

2,4,11-t.riehlorophenc 

2,4,6-~ 

2,4,5-T c;•.~-& adell 

2,~TP (2·(2,~) propaooic: acid. Silvex) 

2,3,4,6-tetnd1lcropbmol 

Pentecl>L• opbeuolll'CP) 

BOJ>Del (0,0-dimelll;yl Q- ~~) 

Debria er..n fire imol•iuc PCBo ~ the rompnnnd!o lilted above 

Some Clltheoe- (lliMm. 2,4,6-T, ond PCP) are doteeted by the~-wbicb will be~ 

OD diozin IIUip<!Ct --per the TWl Diasio Suapeet Wute PollcJ. Additb>al - Ji8ted .-..if 

jnc!lreted "'the ~ Oil the pro6lit iDI'OI"ID81ioQ. wiD be terted...., pa ~ph It> I .,_. 

. The !<lAowi:ue are bnmd name JlO'OCiuolll wbicb iDclude the """'J>'U>ldalialed abaft (1!111 lilt It DO& i · WI tAl 

:' -:) be all illclllme): 

.. .,., '~ . J • .... 1> 

AWCHBM 

AMINE 2,4,5-T 

AQUA· VEX 

BRUSR·BHAP 

BRUSH.TOX 

DACINB 

:·DED-WBBD 

DOUBLE 8'l'B.ENGTB 

.DOWCIDBS 

.DOWCIDB8 

D6WCIDB'28 

DOWCIDE BC-7 

. DOWCIDE G-8'1' 

ENVE!n'DT 

ENVI!lln'T 

EMUI.8AMINE BK 

F..STBBONB 

FAIWCO FENCE RIDER 

FENOPROP 

FOBRON 

FRUITONET 

INVERTON 24!> 

. KUBON 

KUROSAL 

LlNBRIDD 

PZNCBI.OR 

PENTACON 

.PENWAll 

PRILTOX 

REDDON 

SANTOBRITB 

SANTOPBBN 

SILVl·RAP 

SINlTUHO 

SPONTOX 

SUPER D WEEDONB 

T·NOX 

TORMANA 

TaAN!wo:NB 

TlUBt1l'ON 

TBINOXOL 

U48 

VEON~ 

VE!lTONzr 

VlSXO BRAP LOW 

VOLA'ltLE E8l'.l!3 

WEEDAil 

WEJm.&GONB 

WEEDBBADS 

WEEDONB 

. . . 

BEVISlON 11 

wwc 

VES 004436 
.. ;: .. 

APPENDIX WAP-D 

DE'I'BBMlNATION OP INCOMING WASTE 

CONJ'OJtMANCEINONCONFOftMANCB 

: 

,. 

. .. 

. .. ''.) 

_, 

VES 004437 
APJ'iENDU: WAP-D 

INCOMING WASTE OONPORMANCE/NON.CONPORMANCE 

Imwnine - Dll\1 _, from the iDCOI'IIIIItion determined durini the pro6JiDc pbue clue to the 'flll'W:Iility ID 

the ...-.o ~ the waste or ID eo!!.,.. ion of the wule DllllerW. lD CC'der to cletenDiDe wloelher a 

partloulat iDcoming woste stream ccofCrmll to the ia'ofiJe, the folll>winc oitaia wil be U8ed. AI other 

Mandatory IUid Supplemeotal ~ dala colloeted ..;a be .-1 to allow TWI to c1eUnDioe the t.e.t metbod 

for ...-;ng tho W8lte material. 

1. 

2. 

3. 

pB &neg: A ~ in the pH from the """" oped6ed in the profile docwDenta ms,y iodi<:aSe 

a eiJance ID the - ......,. Jt a pH variation ~ the ranc- opec:i6ecl on the tiquld pro6le 

sboel, the procedures outJiDed in Sectioo 5.2.4 will be IDitlatecl (e.g., a - which ;. td 1111111:1 

neutral ;. fOund to be corrooive). Material~ will be eva1uatec1 for oonrarmance oo toOowr. 

PrnCWnc t\nehrtim' RaWi Acceotable Brmm 

<2 <2 

2-12.5 2-12.6 

> 1.2.5 > 12.5 

W- prdlled aa pH 2 to pH 12.6 but ahiwed with an~ LDR filrm for IlOQ2 wli be 

CGDII<Jeled coofonning at pH <2 or pH > 12.6 i! oawortoc1 b)' the prc&cl + · e! caaotlh_., 

nMnmnbi!jb Poteptla! &mq; A variatiOil in the lbermaiiii:!Mty from the fndiretrn OJ*.;IIed ID 

the prollle ~will indleate a +a,.. in the -..,-. If the ....atian ...,_a change 

ID the buard .-. of the -, the poocedures outlined in Seclbl 5.2.4 will be IDitlatecl (e.g. a 

. mot ill wllitb did DOt ezbiiJil n """tty potertW ID the prallllo, pbMo doea ciur1D1 the 1,;.,..m,l 

l!bipDeDt . 

--rit ladlii.te .... ~the- oiHaa, will+ ....,lid llillwe.the .. oc:eoturo..oulbd 

'. ' 1D Sec:dooi U.f. Twi ;. Dot P!"'JJ''lted to accept PC8e > 110 ppm or TSCA deriYed PCB -. 

4. Bed! ·"viti 8cqea.; Tbe preaenoo of~malerialaMdelermloedi'JtheriOdio«tiwit)o­

(-Seedoa 8.1;~ wllllal&te the procedureo M aullined lza 8eclloo! 6.U, leedint to rej z :fiC n cltbe . 

--

WAJ>.l)·l RIM8lON 11 

~ 

... 

VES 004438 
.. •' 

' .. 

bnnmnt~ A oi«P'6 •rrl. -wion ill tbe appareul cis :oity 6:<D that optOIIed ill tbe profile 

docuii'Mt.a will iDdii::IHe a cUnp ill tbe wut.e -lhat wwld iDidate tbe ~ outlioecl ill 

SectioD &.U. 

BBVISION 11 

II/29/IK 

' I 

VES004439 
', : 

APPENDIX WAP·B 

..... .. . : . · .. 

VES 004440 
·-

··) 

APPENDIX WAP·E 

CONTAJNEIUZED WASTE: SPECIAL 8.UIPIJNG PROCEDUIUI:S 

1.0 PURPOBE 

This procedure providee --=e that rcpo eeectoU.c.......,. oCihe fallowiae ecmtaiDerilrllcare colle<:ted for Specifioo!lr, thMe are CODiai:oerised - oC delft aDd llU IDII&erilll, 

adhO&iveo and other bigbly elootie IIUbNDces, aDd ....ma 8lld other bard lllll&erial& ~ 

sampleo ..,.. eonee\ed by llliDe rou1tipoiat •"tiline 

2.0 DEPINlTIONS 

8.0 

2.1 Debria and like moteriaJ • inclo.W wood, briob. <.OQOI'et.e, ~ pioollc ebeoq 

2.2 Adbeoioea aod other hicbi.Y elut.ic tt>IOteriall· otlck;y, cJue-like, IUil>IIV', otretdlab6lt • iolll. 

2.8 Reoinl aDd other bard maleri8lo. piMtice aDd pla8tlo OOIDj)OIMDtl, epoDes IIDcl otiMr jll; . 111 

llmDar me1erlala that ba-fe hardened or eured t 

. 2.4 U.,JUpoiot...upie·Atample~oC.,,._ , .... .,.,u..tedtr-tbe......, ib.t 

INSPECl'ION 

Eech eonta!Mr ..nl be ....w.ted prlor to opeaiDg to detenDiDa it' a illl.ecri*7. Mter opening. tbe 

cooteiDer'o c:aatente wiD be viauolly ;. It r led lo c1etermiDe wbother-cr - it ....rormo with it.f 

proliled deou iptiuu. 

4.0 J'ERCENT 8AMPLBD 

See WNte ~ PIIID'Sedioo U. 

·. G.O 8AMPLI1fG • 

.Multip.mt_lllliliploe ce i apeo lh• -rir be cohtec!· tram coo~ eelee!ecl for i'"'c . 

. 8 •"'1"'nr-eirit *"* wiJ be aeleeted beeecl ce .-.Ita oC tbe inopecticn Rw11qM will be Ia CWM 

c:uolod7 &,. tBmple enl!ectjon UDiil t.raDoiCer oC cuetod,y lo tbe ~ flea· ..... . . . 

RBVISlONll 

9lllllr9' 

' 

VES 004441 
... :\ .. I ... · 

6.1 HIGHLY ELASTIC SUBSTAI'fCES 

Allbelliftl IDd odw biabl7 elaatlo ..... •• .. will be -mp!ed wilb • acoop at ~ -' 

ocioeon or l(qL The pr<x:edure ia to: 

6.1.1 dip tbe obovel at acoop inl<> the material I<> the cleptb of the blade and .-e; 

6.1.2 Ill\ tho acoop at ebovel with the oample aDd cut with the ......., or taop,_ • 

appropriate; 

6.1.:1 wind the boqiiJc partloD ol the S8IQple cato tbe acoop" ar......,. aDd lnllllfer the 

~ 1<> the -.pie....,..,;._ by.......,. tbe maWial &om the abarel or acoop into 

6.2 DEBIUB AND LIKB MATERIAL 

Delrio """·lite JDIIierials will be Mmplecl with ........ hammer, c:biloel aDd ~clap .. 

appoplase. The procedure io to: 

6.2.1 - hammer 81111 chioelt<> coiled IIIIDJ)Iea ol wood, lllicl< at otba-bard ma&md froc>mitbe . 

1<>p of the ......,mer IDd pl-. iD the lilmple cmtn- with 1a11p; 

6.2.2 - ........ 14 cut -DJ!Ie ofc,.ekead GdlerflMiib' cublble _ ....... (pw!dfnc rubber, 

piMIIe ... ·&.., ece.)-' plaee ill IISQille.. !ol rl with l<lap. 

6.3 RE81NS AND/OR OTHER HABD MATERW..S 

Reodos IIDd/or other bard material~ will be _..ped witb a a-, c:biloelllllllt.qp at acoop. 

Tbe procedure la to: 

u.t u ... ~ ..i4 cblid w redDce lllliterioi1W ibe t~t"i&:~. -or be piloi:ed iDa ' . . ~ •elMo 111111 plaee the~ iD the'""'' • • w1t1i )""P or oooap. 

· · 8.0 SAMPLiNG'PBBSONNBL · 

It io the '"I • Ulty of. Fedlity Mr J • I 1<> ...... aoly qualilled periOilll!!l 14 perflip" I • • jili C ofCGI!IIIIilwiJed-. P~ tbatblrfe beeD tniDedin the implementation 

of tblo JII'CIC8CliiN - ,.c edt<> be qualillecl. 

7.0 SAMPLE ANALYSIS 

Samples will be~ • rptcifled in Seetlom s.t, U. *>II S.S. &Ill! l'IJure 3-1 ot.the WAP. 

Ml*boal ~ wil be per{armid !It the nque1t of the~ Vmpnnl 

REVISION 11 

9/29194 

VES 004442 
.. ·-· 

' ' '>. . "I 

... : .·· :' .. '.•.}·· ·.• .. ....... ...... 

APPENDIX WAP·F \ 

·" 

VES 004443 
APPJ!INl)IX WAP·F 

BJBLI()GBAPBY OF 8'l'ANDARD CHDIICAL JtEFEJlENCE MAT"Rxa.LS 

2. ~Properties of :IJiduslriol Clw- • h, CurRDt Bdltim 1989, V111 N-d Relllbold. NY 

NY. 

5. 

WAP·F·l 

·. 

VES 004444 
, 

.· 

APPENDIX WAP-G 

BM-181 COMPA'n,BILlTY CLASSES 

'~~ 

.. ') 

. · .. • • > 

> ' I ' , • . . ' • '' . ' ' 'I . .. . . .... 

. :. \ . ,/ 

VES 004445 
: t'•• 

1.1 - 1.6 

:U-2-2 

8 

(.1 

.2 

•. s 

' J 5'.1 

6.2 

2.3 

.. 6.1 

8 

,. . ~ II 

..·:, 

.) 

:APPENDlX WAP - G 

ml-181 COMPA'l'IBILTIY CLASSES 

., .. . 

Jl\ali,mable 

~ 

Solids 

()ombustlblel 

J>aocerous When Wet 

P....,...... G8s z..,., A & B 

Couosives 

. · N.O.S. nebrll . . ·' 

Nl"'!Hazar'4louiollaleri81 . 

. . 

~ •••• ',' . -¥ ' :· ·.~:·~.: : :·: ;. ;~ 

;- ~. . : :~·~~. . .. 

BEVISION ·11 

lll'l9J9' 

VES 004446 
. ' 

... @ 

") 

) 

CHEMICAL WASTE MANAGEMENT 

PCB SCREENING POUCY 

.. . ' 

Revis1Qf11 

October 1991 

:; 

~ ~ .. ... · .. •:._. 

VES 004447 
, .) .. . . • 

... . ) .. . 

CWM PCB SCREENING POUCY 

L INTRODUCDOii 

-rhe Toxic Substances Control ~ (TSCA) is the prirniry SOUI'ce of federal 

regulations affecting the management of Polychlorinated Biphenyls (PCBs). Most 

of the provisions of the TSCA reg!Jialion$ specified In 40 CFR Part 761 apply to 

PCBs cx*'f if PCBs are present in concentrations above specified levels. The 40 

CFR Part 761 subpart 0 Storage and Disposal provisions apply generally to 

material at c:oncentratlons of 50 parts per mllion tppm) aile! above, However, no 

provision specifying a PCB concentration may ba avoided by _diluting PCB 

containing materials unless otherwise speclficaly provided . 

. . Furthermore. the Resource Conservation and Recovely Act (RCRA) is an 

' additlonal source of fedefat regulations affecting the management of. hazardous 

waste containing PCBs. The land disposal of liquid hazardous wastes c:ontanng 

PCBs at ccincentrations greater than or equal to !50 PPf:11 is prohibited i.ndec' the 

provisions of 40 CFR Part 268.32 (a)(2). The land cbPosal of liquid or nonliquid hazardous waste containing halOgenated aganJC ~ (Hoes) 

including PCBs (see 40 CFR Part 268 Appendix 111. for a listing of HOCs) at 

concentrations equal to or greater than 1 000 mgiL. or 1000 mglkg, respectively, 

is prohibited under the pr!Wislons of 40 CFR Part 268.32 (a)(3); (e)(1). and (e)(2) 

the "Callfcma Ust. • In addition, the management of liquid hazardous waste . . . . 

containing PCBs at coocenlralions of 50 ppm or above as wei. as liquid or nonlicjuid h;llardous wastes containing HOes lnC:IudihQ PcBs (see 40 CFR Part 268 . 

. Appendix Ill for 1st d HOCs) in ICtal c:oncentralions equal10 ar greater 1han 

1000 mg/l Or 1000 rng,1<g lor liquid or eoid, relpiG1Ivefy, n apecia,d under. !he. 

pr~ d -.o CFR Part ~42. · Flrialy; the land disposal d haiar.oous waSte 

c:ontan1g •PC8s IWld identified .by hi listed hazardous waSte cede fUilbeis 

·K065 IWld F009 (multi-Gouice leachate) Is regulated under Specific Land Disposal 

Restrictions (LDR) prcMslons under 40 cAA Part 268.43. These regWilion$ 

-require PCBs to b8 treated to the folowing levels (Table Q Prier tO land clspo!ial . 

2 

Re.vislon .1 

October 1991 

> 

t 

.-

VES004448 
....... 

' ) 

I •") .. 

I •• • 

PCB Screening Policy 

TABLE I 

Waste Water Non-Waste Water 

K085 & F039 mg/L ~ 

Aroclcf 1 016 0.013 0.92 

Aroclcf 1221 0.014 0.92 

Arodoc 1232 0.013 0.92 

Aroclcf 1242 0.017 0.92 

Arodoi 1248 0.013 0.92 

Arodor 1254 0.014 1.8 

ArOdcx 1260 0.014 1.8 

State and local agencies and permits may also regulate the management ol 

PCBs. Conllfiance with these regulations is recjuired wflerSYef IIley ~ more 

. stmgent than federal regulations (e.g., certain states req&n that 1he PCBs b8 

reported on a dry weight basis). 

Additionaly, TSCA adchisses PCBs, rlot Arcc:lora: . This irdldes Flti\ieillalty 

.produced PCBa ..:1 foreign prOduced matedall that inclJCfe Clophtu•. 

f'henodor•. Pyra.e.,..~ Kaiilctilor •. ainct fflllCior-. . . 

In cxder to assure that the appropriate praCtices are beiilg appied c:oniislently . . . 1hrougllotA_ChelniE:al Waste Management, Inc. (CWM) JIIQ8idi .g the management 

or wastes which. may potentia~~)' Contain PCBs, · It Is ~ tO der.ne pr~ to be 8fTlliOyed ihrougllQUt the G!Pi i~IY- lherifore, the tobwiug 

Policy and Procedures has been developed. 

.· Re\<iSion 1 

· Octo~1991 

: 

. . 

VES 004449 
i 

' 

... 

) 

PCB ScreeriRg Policy , . . 

D. POLICY. 

A. The trealmeri, swrage, and disposai of f1n1 TSCA regulated waste shaD 

OCCU' ort-t at a TSCA apprOYed treatment. storage, or c:isposal facilly. 

B. AJ PCB analy$8$ required as a result_of the appk:ation of !his policy.shal 

be performed by a CWM laboratory or a CWM apprCMid waste liboralory. 

C. ArTy waste !hat will be analyzed for PC8s r. acc:crdanc:e with thil policy . 

shal not be accepted for storage, treatment. or disposal IXIIi PCB 

analyses have been completed and evaJuatad. 

D. ArTy non-TSCA waste which meets the following criteria shal be treated as 

a PCB suspect waste uoti demonstrated otherwise, 1hrough cnemlqll 

analysis. 

II/. PCB SUSPECT WASTE~ · 

The following ~ have ~ deYeloped by Cheri lical Wast8 r.l'anagemeri.. nc. 

through its extensive opel atiiiQ experiences as wei aa thrOugh review of various 

&ources of literature for deli ling a WIISte as being PCB Suspect n-e aleria 

are intended to ~existing requirements which may have beeO Imposed 

through pennlt COIIdifloc IS, ~inlstraliYe orders, or CJiher ~ill Mh federal 

or state regUatory agencies. · 

krf wasta for which the genetator hits ~ed on th8 "Getierator'~ Waste .. 

Material Profile Sheet" -0! ~n~' octllf MJppOf1ilg doc:umlnralion'1hat Pees 

are J)fesent below regt.Aated levels. · 

Re~ision 1 

4 October1991 

: 

VES 004450 
........ ,· 

( ) 

( .;.) 

,> 

PCB Screening Policy 

B. Oi Bearilg Waste 

NOTE: • Oi bearing was1es are defined as any material (Tquid, sofld, 

organic, or aqueous) conlai!Wlg oa as descri)ed on the "Genetator:'s Waste 

Material Profile Sheer (other supporting documentation) OR any material 

which exhibits the visual presence of oil. The visual pre sa nee of ol may 

include, but is not limited to, an oil emulsion, oil film, oil phase, or water 

soluble oil. It is the responsibity of the laboratory Manager at each 

division to use sound judgment based on their analytical experience to 

make the final determination I a waste stream exhibits the visual presence 

of oi. 

C. . Municipal Waste Water Treatment Facility Sludge 

D. 

E. 

F. 

G. 

; 

Bulk Laboratory Wastes 

BaghoUse Dusts from Secondaly Smelters (e.g.! copper, aluminum) 

Afr.J Waste as Designated by ~ L.aboretory Manager 

All Wastes, liql ids or Solids, from the following: 

1. Electrical UtJiity Company 

2. Ncltural Gas Pipeb Transmission Company 

3. Solvent Recovery, ReuSe or Recycling Unit 

4: Oi Recovery, Reuse a R8eycling Unit 

5. Oi Maintenance CenJcn 

8. Pond Cloel.res [~ Pond SludgN n Dredgiugs) 

.7. . Remedial~ ~Sites · 

a RCRA Corrective Adion Prci;eete 

9. . . Trrtler/I..Lmber Treating Facility 

10. Hydraulic Equipment 

11. ENAAC Remedial Action PrOtects* 

• Unless demons1rated non-TSCA 

5 

Revision 1 

{)c;tobe( 1991 

.. 

\ 

VES 004451 
PCB Screening Policy 

12. Heat Transfer Units 

13. Metal Machiring (Cutting) Operations 

14. Pesticide/Herbicide Manufacturing 

15. Ink and Pigment Manufacturing 

16. Oil Based Paint Manufacturing 

17. Paper Recycling Operations 

18. Roofing Felt Manufacturing or Processing 

19. Auto FJull 

20. Non-WMI Waste Treaters 

21. Chlorobenzene Manufacturi1g 

IV. F'ROCEDURES 

A. Pre-Acceplance Samples 

Pre-acceptance samples are to be analyzed for PCBs by a laboraloly if 

· ') 1tle waste stream meets any of the criteria spec&ci in aectlori Dl aboVe: 

.. 

.. J 

B. Incoming Waste Shipment Samples 

The need to analyze incoming waste shipment samples for PCBs wil be 

.. estabished by the resu~~~ of the .sales sample Wlllyais and ·~ of 

the sales sample Waste Profile Sheet. i lfounatiOil against 1tiis policy. 

Table Rdescriberithe overaD requirements discussed below. 

· I( a waste ~ doel ncit meet 11f1J of the P.CB.auspect crit,rta; 1l)en 

there is no specific ~.tll'l'llri to Perform PCB'analysj!S on the:rnco.,)i,g . shiPmet 11s of this waste stream uliless spec:ilicaly required 1n:1tr a Waste . . . AnalYSis~ (WAP). . . . 

6 

f!evisior\ 1 

October 1991 

. ' 

VES 004452 
..... , 

.J 

PCB Screening Policy 

If a waste stream meets any of the PCB Suspect Crheria and the sales 

sample analysis indicates PCBs are less than 5 ppm' or the regulatOf)' limit 

(The EP.~ TSCA office has recently specified coricentrations of less than 

2 ppm PCBs in treatment residues for approval and refer to Table I for 

listed code specifications}, wtlichewf iS lowef, then the laboratoryJtec;hnical 

manager must specify on the Waste Management DecisiOn (WMO) whether 

PCB analyses on incorring waste shipments are required and, If so, the 

frequency of analyses. 

If a waste stream meets any 0! the PCB Suspect Critlfla and. tO. sales 

sample analysis indicates PCBs are above 5 ppm' or the regulatory imil, 

whichever is lower, then the laboratory~echnical manager must specify on 

the WMO lh!ll PCB analyses on incoming waste shipments are required 

and the frequency at which that analysis is to be performed. 

It the receipt matenal demonslrates a change in the waste from the preacceptance sample and It now~ the PCB suspect cr11eria, then PCB 

analysis must be performed before treab neut. atorage, or dispoUJ . 

. · 

·. 

• ·The specific c;rilerlon of 5 ppm is the ~ laboratory repol'ting · Umit for PCB 

analysis. II is a conServative approach to protecting the integrity of non-TSCA facilities . 

Revision 1 

7 . ·October 1991. 

\ 

VES 004453 
?CB screening PolicY 

. . ) -. 

TABLE II 

. 

WPS 

~ 1WMDI 

No ActiOn 

llequir•d 

Meets PCB Suspect 

Criteria 

*Sales Sample 

PCB Anults 

No 

Yes <.5 ppm 

.. 

Yes >5ppm 

. PCB Suspect 

• 

UI> D•• c_.,o....,..., 

.......-' 

>!i-PCI 

--

<IIIP"'tcl 

I Yos • No I I Yosl 

' ...,-

IWMDI IWMDIIIYII 

,,_....., Fr~Cl' 

ol TutinO of Tutlnll 

Receiving Procedures 

No specific actiOnS required. 

Specify in Waste Managem8nt [)eclsion 

· ~ 

~ Whethtf PCB. · analyle& on wa5te. shlpineniS are required' 

and. if so, the frequency of ii\alyseS. 

WMD must specify that PCB ~ses 

are required on intX)mk'lg wasta~ ilnd must specifY the frequency of thO$& 

analyseS. . 

• or the regulatory limit. w~ is loWer . 

8 

Revision 1 

October 1991 

.. 

VES 004454 
·.· '\ 

... 

.. 

. ,: 

) 

•' ..... ' .. · . . , 

~· WU'I'Il :~•curaaa:~xOII 

D:IOX:I. SOSP&cr .. aLYSXS pOL:ICY 

. ... 

.· 

' ·: ... .. · .. 

.. '' 

' ·.· 

.. 

. ' ' . 

·e,..... .. ~ ... . . 

VES 004455 
,, 

\ 

'. 

' ) 

I . 

!WI DIOXJB AalLYSIS POLICY 

lJftJIOIICJC! lOll 

Trade Waste Incineration ia impl...atinv thia policr for the 

screening of waatea which mar contain dioa.ina. This. policr wil l i dentifr the trpea of waatea vbicb .u.t be analraed for 

dioaina or dioain. preouraora prior to a.,roval for acc eptance 

aa a vaate atre- at •nu . IIIPl-tatiOA of Wa policr wU 1 

P.roYide a -aaa of ensuring that potential.lr clioain 

contlllllinated vaatea are analJ&ed for dioun content aad suba~nt lr .anaged appropriatelJ a c:cordinv to applicable 

state and federal regulati ons. The final deciaiOD to -.nave 

a dioain bearing waate ~~~&at be ucla aocorclia.g to _ the 

conditions and restrictions of the goveruing facilitJ W~e 

AnalJaia Plan and. operati ng per.ita. 7, .. 

II. POLICY 

A. Waate atre- oontaplated for ..n.g-t a t TWi Ifill be 

aubj e cted to the Dioain suspect. Wute Criteria during the 

deciaion evaluation proceaa of the profiling procedure. 

B. lfailtu vbich are deterained to .. et the Dioliin Slulpeot 

Waate Criteria will r~re analraia tor dioain 

precur.ora prior to acceptance and -.nav-t tor 

treat.ent aa.d cliapoaal at the taoilitJ. . ~ . 

c . ·wutea vhioh.ara fou.nd to conta~ dloain precurao~a at or 

above tbe aita a~i- level for prec:uraora vill require 

clioain .a.alraia prior to a ccapt&Dce &Del -.nav-t for 

treaa..,,-8nd ·fia;oa&l at tlae· faaili~J · • . . · . . . 

D. Wutea vbich are found to contaia. cUoJ!ina at or ~ tli~ rite actiOD level will not be accepted for winav-t for 

treat.&Dt and. diapoaal at the facil!tr UDtil auoh ti .. that t~ea~t and cliapoaal .are allowed accorclint to the 

conclitiilna &Del rutdcticiu of the govemia.t facilitJ 

Waate AD&lJaia Plan and operating perait.a. 

; 

' 

VES 004456 
' ' .. 

. .. 

. . 

.. . . ·• 

.J 

·. 

The f oll owing criteria has been developed for defining a waste 

u dio.dn au.pect. Theae criteria ere inteaded to a uppl-ut 

niating requir-ta which •l' have been i~oaed through pe~t conditiona, adminiatrative orders, or other agre ... nta 

with f·eder al or state authorities. Waataa c-.idered under 

these criteria r~n .subject to all eaistin9 condiUoua 

i mposed bJ Chemical Waate -MaDav-t polioiu aDd 

anviroa.antal directives. 

A. 

••• 

OaDarator Defined Diozin Wast a. 

ADJ waate for which the 9BDerator baa indicated OD the "Generator's Waate Material Profile 8haat" or &DJ othat 

supportiD9 docn.entation that diOUDa Or diOJI!i!!la 

precuraora are prea-t· at &D7 level-. <r .. . 

. lfaataa PrOia the Pollowiuv: 

Thea• waataa ·will be couid!ared u suspect if theJ .. ,· have beaD subject to historical oonhaiDation frdiodna or dio:r.bi precursors, or if the waatea contain a 

known dio:r.in or dio:r.in preouraor aatarial . 

1. Ti mber/Lu.ber Traatin9 Paciliti ... 

~ P_.ticide/ Berbioide Nanufao~urinv rao~litiaa • 

3. HaDufaeturara _or Prooua.- u.-invt 

....... <:":'-. .. ·, ..... .. , ... · .. . ~ ··~ : . 

a ) · aciiao-, di-; tri-, or tetrachlorophenola , aDd · 

their chloro-pbno:r.y. dedvativa aoida, .. tara , · ~ :' ui4l otllft ·.S.lta. · · · · · · ' · · b) ..-ta hloropal ·. · · · · · · · ·· o), ··lllillo-. . di'"; trl-, ·tetra-, PBilta-, .or bauclal orobeluaD~ . . , .· . d)' ... ,· tdchloropheDo:r.nropionio acid . (ailve:r.) ·. . ... a) ''trtch.or0pb.eoaJaoeUo acid (2, ... ,5-T) 

f ) · ·lae:r.achl orophene · 

. •. c~ucia ·prodlac:ta fr- aoucaa ciu~aide of the 

Clfll/lllli 'l'aolmolovha faailJ of c :ct .. where •11ch 

cotlbutioa o_courr:ad 'lllldar acontt~lled conditiou 

and the for.atiOD of dioaina or: dioain related 

cOIIPOUDda ia auapeotlicl ·to Jaave· oonned (i . e . the: 

ootlbution of PVC, Cl'VC, 'etc.). · · 

·C. · Wutu ~dil9 u& baser~ nata nililben r032 , P039, · ltO.Ol, lt015. &011, .K030, ·JtOU, lt043, ltOI~, JtOt9 , UOS ,' . UU ,' ·ltUO , aDd ltl51 . 

.. 

' ~ :-:. I ' 

. . -. 

. .. , ,, •, 

VES 004457 
'·;. 

.~ \ 

. . ·. t 

lV. PROCalftU 

&. Precursor Analysis: 

'•, 

Dioxin precursor analysis -Y be conduc ted by llPt.C; CC or 

CC/ MB, or i-oassay scr- techDiquas followi ll9 

•pprove4 ID'A •thocls or CMK -difications of aueh 

•thocls. 

1 . Profile Approval . Samples: Profile approval s ... laa 

are to be analysed tor diodn precursors if the 

waste stre- -ts any of the eritar:ia apecified •:hl 

section Ill above. Wastes which are beipg 

nprofiled or raeertified dua to ohanvaa ill U... 

process gaaaratill9 the wasta, or u a raault ot 

generator iafo~Uon gathered duriag t!l. ajp- onfo~ce resolution duriJW 'iDcc.Uag aulyaia !iF• 

also subject to the cr:itada specified in saotJiGa 

2 . 

Ill. · '1 

Illoc.Uag Wuta 8biPMDt .... 1 .. : 

a) t'ba need to ualr•• 1Dcoii1D9 · vuta ahii-aat .... les for dioaill prac:Uraora will be .. tablial:aed by tl:aa r .. ul ta of tl:aa profile 

approval s ... l• &Dalyais aDd aa avalU.tiOD of 

tJ:aa. wuta profile abaat. illfo~UOD agdut · tl:aa criteria .. tabUabacl ill this poUcr·. 

.... 

_b ). If a vuta str.- cloaa· .11o.t .._.t ,_aar ot· the . ·.criteria .. tabUabacl- ia secUOD til ot .this 

policy, thaD tl:aera .1a llO jpaoitic raquit...at ~ pedom 4i!)alll. pHCII&fPr -1-raia Oil the 

--:'· ·-,f.Ac..Ua•· shi.,._t. s ... laa ·ot the tl~tla atr._,. :. ;::'J • ' ' I, • ••• • , ' ': • • ' '',· ''·. ' • ' ' • :: 

c). ·. i~ · tJ:aa ~ecetpt -ter.tiil _ci..,..trat'aa .:ctiallt•#-1-fr:~ . . iJi..tl:aa vuta fr• tM· profile approval .... le •. ~ 

d ) 

·u . a. intonation prodded .br t_ll8 eaaerator · .. ·:. 

during . the aOD-COilfOIWU.Clt r .. ohatioa pro~aaa) . allll .it aow ._ts tb criteria ·-..tablisha4. ill sactloa Ill of this policr, thaD -dioaill · precursor ealrs.ia aat be ·parfomad u ·part of the inc.tQg aulr•i•. 

Wastes vhi~ Mat the criteria eatablisiMcl ·iD 

lfaotiOil Ill of this poUor .aDd ti.hiC:rh a:ahibitad 

negative screen results. for dioain precuraora 

darbg profile . appr~val anahaia will not bil· ·. ·., acr.aaaed lQIOil .ncaipt. 

.. 

.. 

VES 004458 
... 

· ) 

e) Nut .. which ... t tbe cri'teda ••tabliahecl in 

••ctioD Ill of thia policJ and which eahibited 

positive screen results for dioaio precursors duriD9 profile approval analJ&ia will be 

screened upon receipt if the profile approval 

screen indicated dioaio precursors above the ~ 

precursor threahold value, and aubaequeot 

dioxin analJaia coofir:.ed dioaiu beloti the 

dioaiD thr .. hold value (or Dot present). The · inca.iD9 screen will be liai ted to onl J those 

preouraora which were detected duriov ' profile approval analJsia. · 

If the ioco.in9 acreeo indicat .. the pr .. ence 

of diodn precuracJra, incca1D9 . · diaat'D coafi~ticm aD&lJ&ia wi 11 be conducted if the 

level& of precursor& iD the iDca.iov soreaceed the leYels of preGUrsors in the profile approval analJsia with the toll~ 

guidelines: :·!· 

i) 

H) 

Profile ' approval precursor ac:r- na · posiu..,e. dioain confi~tiDD aD&hsh 

wu ~atiye, none dateoted. · -ad -

The 1Dcca1D9 scr- iDdicatu precursor levels vreater than a fao~or of 10 ti .. s 

above the profile approval result&. · 

.· . 

Prcifile approY&l pr-uraor sc·re• wu . I'Oaithe;' dioain' c:OilfiraatiOil analJaia · vu U,athe, ~t dioaili wu detec~ed 

below tueabol4 nlu. · · 

.. 

- u4- . 'fba·· iDCcainv aore-. ~cat .. . premsor 

·. J••~• ·. gJ:-,_ter '\~ . · p.tci~fi~ed . 1 ... . abOY!I tll.e: pz'Ofile mtoYal raault8. · fte· '::. '''.'.; .. . · 

p~orated .. leV.l ia ·deteraiawt u fallCiws: ·~· .J. '•. . . .• . . .. ~ 

(lm •. 1 or.il) x nt. · · · · .. .. . ·' f .. ·?. 

"wh;re: D'rL '"· di~aill': t~e~~ld. l~~~i DtJ) a 'dioah leve1 cleteet.d · · · (pr!lfU'e ap•ronl) 

PPL ::: profile qpro•al 

precursor level 

a. Dioain ,llla}Jaia:. 

Dioaill anal pia. will be perfol.ed, with the concurrence . of the g•erator of . the waste, · foUoviDv .. a cli.oaiD . . ' .;· .. :·,'li•~iftiii~.>;,!cireeD w.hi~ indicat .. ;::pr~aor· pre~\.--''t:,~•·· · or aboYe o .01_. 'br ve'iv\lt·; ' l)et'aetioa···u.m til ··foi' · cuoil.'i' ":~"'~; 

aD&lJsia will be aet at a ,l put per.ail\ioa hrubold~ 

VES 004459 
A. 

a. 

c. 

p , 

•• 

'•: .. .) 

Diplip: General · hailr u ... for ca.polllleb known •• 

polrchlorinatecl dibemo- p-diozilul (PCDOa). Specificallr, 

"dioxin" ia tJpicallJ u.ecl to refer to 2,3 ,7,1-

tetrachlorodiben•o-p-dioain, or 2,3,7,1-TCDD. · 

Diolip precunora: Cheaicab vbicb vho NDUhcturad 

have been ahowu to contain dioriu u a wute or bJ'-

product. Diozin precn&raon,. are of aiailar obeaical c~oaition to diorlu.s. aaae ea ... lea ~re 2',4,5• 

trichlorophenol, ailvea, and .haaacbloropboe. . 

UJ&: High Pn .. ure ·Liquid ChrOIUtographJ'... ' 

ualJ'aia teclllli'lue ia uecl in alii -thad lt2.•71, 

ADalJaia of Chloropheno&J' lerbiciclu uaiue BfLC• • 

'l'bia 

"~ 

.. 

.; ~ •• · OC· cciKS: Gaa Chr_.tographf, GC/Kua Spectro.copJ'. &nalraia inat~tati u uecl. for the · ~peciJ!ic 

identi.Ucatioll of J:i-roua oreanic CCIIIPOI&Dda. 'fJ'picaliJ', the -t)ocla tor .'l\l&lltUicaUoil !If apecUic dio&iua': or·. dio&in pUCI&riOl'!J. uae GC OK; GC/ .. te,olllli~ . . 

I"'Pol"" IC(IM: A 'lUiCk, a.ai•'l\l&lltitathe -thad of ide~:~tUtin9 the pruoce · of a apecifio o~cal .or 

ch.aical fUiilf, · ap.Oi•ficallr. •·146 lletbo<l , 4010 , . I'PR"oaaa.,. Tut for the Prea,oce of PeatachlotoPb*Do) : . 

..... 

. .· '• ·. '::: · ... :: .. ~·- ~::: .• :. :-· .. ~-~:- , . ~ .. "' . . ·.) ... • .. ~~-. ~ . ' .. .. -~ 

·' 

• ' 

•, ' . .• . ., . .'. 

•' 

. . "' . 

... .. 

'· 

.·. -·. ---. , ~: . 

• ., I 

. . , 

VES 004460 
~ .~. 

. . ) ·, <1. • .. . ...... 

POLl CY. REVIEW Of' PROf' I L~ CoNST i- tftli : ' ~ .. ~ :. ~ .. . . :."' .• . , ~ .. . . . .· Suap.Ct per poI icy : Not .. _, • .,~ per: ·pO'f'WY 

<--..a.,...:....- > . ·. . . ,.---""'-~~..., . ·~ ~ I . . . . ·. , . 

COnduct dioxin Proeeelt'w{tll ~bi ln· · precuraor 

analyaia 

proceaa, no pre• 

cur.or analyafa • .. J, • • ... . • 

Dioxin precuraora Precuraora not found 

found « >>----------. 

Doea generator want No No dloxi.n t .. ttne 

to have dioxin teat- int parforwed? » O~y 

dectaion 

No precuraor teatintJ 

on in-intJ waate 

V Yea 

Conduct dioxin 

analyeia ... :.. .. . 

I .-------,...;., . . · wu dioxin 

detected? 

Ye • Waa the dioxin Y.ea Deny deciaion «'': , 

-> level > 1 ppm? >>-reject ahfpaerit .t 

I VHo 

Approve dectaton, 

conduct· preeuraO.r analyata on inc-ine 

waate ahfpaMnta 

I 

Ia in-c-•ne w••.t• 

ahfPIMIIt .pr-.or 

la.vel > .Jo tt-• tM. . prof.fle . ..,a1yafa; pre-~ 1evelt!' .... 

. · ~Yea · 

Yea · • 

Conduct di.oxtn 

analysts 

..:.....: 

No 

APtH-ove dMfeton (or uc-..t 

wute ahf~), *~pre-· 

c:uraor t~t~ia1yitie on t-tne 

w .. t·e ahf.:...nta · 

'. 

... 

. . ttod1 ;y· chic ta tdft< 

,.,..._.;...._,__ ____ ...._..,v.a· · ~lyeia re•~t1U , 

. > fO#t ratto ·-of' lilr'f-·· :· 1.,..---r-----___. curaorw·. to cfJoxil'l'l, :· .if neca8earv .. . '• • . . . Accept the weat·e · aht.-.nt ·., 

L----------------~-J ------------~~..1 

..... ~ . · . 

. ·. 

VES 004461 
v 

VES 004462 
Prot11• . , 02fl07 

af;OC' r snACOS& 1Xiw:uiTY 0\LlD 

Oe.c:rlptioa : KIUD COUOSIVU/SOLVJ:Vn a.c.Jver I • UU10 ---- --

(\.Q "\ 

Dna I Iii• I Type o I r W.igbt COlor I o.adipdOJl ' P'ull \ loUd ' LtCI'J.!d 

8 55 C'P llJl'-rk bf'Wl .. ""~..rd r.s let;) 

2 

3 

• I re:os l ~, 5 

A~ ::Jl~f()o{l/,) 

' 

7 . I 

• 

10 

1l L_ 

u 

u 

~ .. ·.A I - u """' ... \1\- ~ 

-' !"iil 

~\ 

16 

.. "' ,~ 

17 g 

l8 

u 

20 

ffWSliL!-.::1&/uj..t ....,·,_ __ .... I- 3 /-Cli 

Loeatioa ----~-- ,_,.,,. ---------- - -------- ---

Wdght ------ -- .... •. 

i. 

VES 004463 
w 

VES 004464 
UNITED STATES ENVIRONMENTAl. PROTECTION AGENCY 

REGION5 

71 WEST JACKSON BOU\.EVAAD 

CHICAGO,l.ll0604-3590 

CERTJFIED MAlL 

IEIURN RECIIPI RWUISTED 

~glas Hurls, Oenml MaDa8cr 

VooliaES Tec}prirM Solutioos, LLC. 

7 Mobile Avenue 

Sauget, lll!nois 62201 

o-Mr.HeMs: 

l«lV212008 

A·ISJ 

As you know, on February 22, 2008, the U:S. Envirenmeatal Protection Agency issued 10 

Veolla ESt~ Solutions, L.L.C. (Veolia) a Cl![all Air Act Soction 114 Request for 

lofQrmalion. EP' A revised lbe n:qaest on June S, 2.008, and Sep4lmber 12, 2oo8. Pursu.oitt 10 

Item II c, the tostnport must ilJdude an e• empie of each calculalion pcrlormed. On October 14, 

2008, £PA received theteat report for Unit& 2, 3, aJ1(i 4. Appendix B of each r.epor1 is titled 

"Refm:nce Medlod Field Ollla ond Calcrulllioo&.• Weha¥e.localed the field data fur each lest 

ND tiDd the results ofENSR.'s calculations. However, ENSR failed to include an example of 

each calculation. Wo eitpected the test ):q)Olt to show each equadoo from the R'*"euce Mctho~ in 40 C.P.R. 60; AI'J'CD(IU A, that ENSR used. ln per!i<ular, we expccted.to iOe the 

oxamp!e calculaliOIIl for each of tho following peramciCr5 for one test nm for each incinerator; 

l!qUalioo Panmeter 

2-6 ll!olccular Weillbt of the Stack Gas 

2-7 Average Sblcl( o..-Vclocitv 

2-8 Avera'"" Stack Gu Drv Volumctrie Flow~ 

3·1 DrvMolccu1arWciaht 

4-1 Y!>lume ofWater Varxir ~ed • 

4-2 Volume ofWIIIer COllected in Silica Gel 

4-3 Sanole Gu Volume 

4-4 ~! tore Cooteat 

· 5-7 or S-8 bokinetic Variation from Raw Data or Intermediate Values 

29·1 In-Stack Olltectlon Limits 

29-2 An.alvtical Proc1ion I A. Front·fWf. McQis e Men:uni) 

29-3 Aoalvtical Fraction 2A. '&.c:.k-Half. Metals xca>t Men:urvl 

29-4 Total Train Metals (Exceof Memcr¥) 

29-S Analvtical Fnl<:tioo IS; Fro)li·HalfMel(:urY 

29-6 Amount ofMCR:IUY Collected in Sample FIIetioa 2 

: 

VES 004465 
l!!nualim> Parameter 

29-7 

Back-HalrMcrcuiY Values for AniMical Fractidils 3A. 3B .And 3C. 

29-8 

Total Am<fWlt of~ Collected in the Bid<-Fialf oflhe Sm~~>llnlt Ttain 

29-9 Total Train M~ Catch 

29-10 !JidMdual Mellll Conc:e~~tratlons in Sticlc Ou 

1'umant to Sectioo 114 oflhoClean Air Act, 42 U.S.C 'S 7414, wi1hin20 da)'l ofrecolpt 

of Ibis 1etter. V eolia must eitb<c ~ App«<dix B of each tCSI "'IJC)rt to includb lhese 

calculaliollS Ed to·make any noc:es$lf)' revisions to the em\ssi011 concentratioas ot submit a 

compact disc wilhd!e S!JCeadsbeet propm wcx\Sbeell tblt COIIl8in the ealculalionll. 

I!)'Oll have my questions reprding the letter_, pi- contact Cbar!CI!I Hall of .my staff a! 

(312) lSJ-.3443. 

SineeRly yours, . 

~~ 

ewton 

Acting DireClOr 

Air and Raclfalion Division 

VES 004466 
.. • 

! 

UMITED STATES £NVIRONMEN'tAL l'ROTE<;tiON A GENCY 

REGIONS 

n WEST JACKSON BOU!fVARD 

ClilCAGO, ll jl0604-3590 

·-

. CERTIFIED MAIL 

RETURN ~qrrr ~UESIED 

Douglas' Hams; Oco:cql Manager 

Veolia ES Technical Solulio.is, L.LC. 

7 Mobile Avenue · 

~auget, lllioois 62201; 

. . . Dear Mr. Hurls:. 

. . ·. 

A-181 

· · As you lcndw, on februaty22, 2008, the U,S. Environmental Protection Agency issued to 

VeoliaES Techn.icafSolutiom, L.LC. (Veolia) a Clean Air A\'lSection 114 Request for · 

lnfomif.tion. E? A revued the request on June s, 2008, and,SeptCmbq .J.2, 2008. Pursuant to 

Item lie; the teSt report must include an e:xample of eac;h calculation 'pcrfonned. On October 14, 

2008, EPA received the test r~ for Unit~ 2, 3, and 4.' Appeod,ix B of each rejxlrt is titled · 

"R:eference Method Field Data and Calculations." We have located the field data for each test 

nm and the resullll ofENSR's c8!c:uJatioos. Howevc:i-, ENSR failed to in<:Jvde an ~ple of · 

each calculation .. We Cl(j,ected the test repott to ·show each equation from the Reference 

Methods in 40 C.F ;R. 6o, Appendix A, that ENSR used. ·Jn particular, we expeCted to see the 

txlllllple calculatioi,)S.for each ofthe'followil).g parameters-for'one iest nm for e*:h incinerator:_ . .. _Eg\llltiOtl Parametet .. . .. 2-6 Molecular Wi:W>t of the Stack Gas 

2·7 Average Stacie Gas Velocity .. 

2-8 Aveilllte Stack.Gas Drv Volumetric Flow Rate 

3-1 Drv Molecular Weigbt . 

4-1 Vobune ofWntcc Vapor Condensed 

4-2 Volume of Water Collected in Silica Gel . 

4-3 . ~e Gas Volume 

4-4 · ·Moisture Content . 

5-7 or~ · !so kinetic V ariatiO.. from Raw Data or ln.tatmdiaie V aloes 

29-1 ln-Stacl: Detection Limits 

29-2 'cal Fraction lA, Front-Half. Metals (Except Mercury) · ... 29-3 . Analytical FJactioo 2A Ba~k-Hal! Metals (Except M 

29-4 Total Train, Metals (El!cept M 

29-S Anal}'!ical Fraction tB· Front-HalfMercur)t 

29..(; Am01mt ofMctCWY Collected in S8uwle Fraction 2 

VES 004467 
l&!uation PaJlllllete:r 

29-7 

Back-Half MercurY Values for Analvtical Ftactlons 3A 3B And 3C 

29-8 

Total Ainount of~ Collected in the Back-Half of the SamDlina Train 

29-9 Total Train Mefciiry Catch 

29-10 Individual Metal Concentrations in Stack Gas 

· Pursuant to Section 114 of the Clean Air Act, 42 U.S.C. § 7414, within20days of receipt 

of this Jetter, V eolia must either revise Appendix B of each test report to include ~ calculations and to make any necessarY revisions to the emission concen1n1tions or submit a 

compact disc with the spreadshecl prnSJMl worksheets that contain the calculations. 

1fynu have any questions re~ing the letter, please cnntact Charles Hall of my mtf at 

(312) 353-3443. 

Sincerely ymn, 

~l(br'f'(L. ewtori 

Acting Director 

Air ond Radiation Division 

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. USPS • Tracll &. CoDlinn 

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ILLiliOIS EPA' PUBLIC .IIEARIKG 

DIIIIFT CMPP and RCAA PEFMITS 

for 

ONYX ENVIRONMENtAL SERVICES, SAUGET 

T~N. July 22, 2oo3 

Cahoki• Village Ball 

C.-bOkia, IUinoi.s. 

SEARING OFFtctR: Charles tsatoesia.n 

COURT R£POR$R: Cynthia A. Kyers, CSR, OCR 

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CHARLES W.TOESI~ •. lllinoil EPA Hearing Officer . 

Ladi•• and Gentlemen, ~Y name is Charle3 

tor.atoeai&Jh I'a tb• hea:riog officer toniqbt. Th.1• 

bearin9 ia be.it\9 held by the Illinois sv-ironmental 

Protection l\9ency: This is the joint bearin.q of 

the eure.aus of ldr and Land- 1be purpose of the 

hear1nq is to receive comments and data &nd ans~or 

questions fr~ the public concGrnin; two dxafe 

pOtlnita. Ony)[ E.nvi~onst.entAl service-S, fortaally 

known as Trade Masts Incineration, haU requeated 

tvo petu'it5 from th& Illi~ois &nvironmenta.l 

Protection Aqency. The facil ity is located at 1 

~il• Avenue io Sauqe~, llinO s. fbe facility 

bAa .N.qVeated a Clean Air ~t Pet:Rit Pa:oqrUI 

Per:ait for its e.ir eaission.s and renewal of their 

Resource conoerv&tion and Recovery Act and 

Saxardous and Solid Waste Amen~ot ·Pepmit for the 

man39ement ot haz•rdous waste on bite. ~he 

facil ity eecepts, stores, and nei~atao 

h~za~doul waste. 

'this ht!a~inq is being held on the pz:oviaione 

o f 3S Illinois ~niS~rative Code Section 166 

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s~bpart A, and 35 Illinois Administrative code 

Section 105.182. 

tf you do not wish to speak at the h~rinq 

you ~Y au~it ritten nts, and in lndeed 

lenqtby c~nte o~ questions sboutd be subMitted 

and the lllinola EPA vill answer in vritinq. 

Written c0«11'18nts -.ast be postma-r-kect by aidniqb.t 

Au9uet 22, 2003- ~Y need not be notar11ed but 

ahou1d be 8ent to myself, Charles Katoesi an, 

that 1 S H-A-T-O·E-S-t-A-N, as in Nancy, tllinoia 

EPA Heating Ot'fic:or. at 1021 North Grand 11.ve.nuo 

east, v..o. Bo• 19276, Sprin9field, Illinois, 

62194-9216. Tni• infoooation is all avoilable in 

the notice that vas placed in the newspaper . . 

to addition, restr~ axe on either aide ot 

the rooa anc.t tbe.t'e • s a drinki.nq fouotaU ju.:st 

outside ot the closed doo~s, and also a aoda 

mac~ne. wo vill seart with some presentations by 

staff fr~ the Ill inoi$ EPA and United States &PA, 

then we will take written .-- or comments fr~ the 

pubU.c , and after people have Spok.en we wi ll tak.e 

general questions from the public. 

ln addition, I will note that there a£• 

II'JIUibe.tl !rocrt t.he CQII'IPa.nY involved who uy answer 

que.ations as vell. Please com up to the 

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utiotophono t here when you speak your COI'IIMnte and 

also plaase clearly state and spell your last name 

for the r ecord because the court reporter JWSt Qat 

e~erythin9 down on ~ne record for i t to be 

presetved. I' U start then with 1'ed oraqovieh 

f<oa the 11llnols BPA. 

1'80 OR.AGOVICH, Pea\it Unit t'.anaqer. 

(BY MR. OAAGOVICH) : Tbanl< you . Good 

cveninq, AIY name is Ted. Dragovich. I am t he 

manager of th@ Oieposal Alterna~ivos Unit for the 

Bureau of Land. Before we di scuss the specifics 

()f these pennJ.ta, I voulO. like ~ explain a little. 

bit about JtCAA, ""tu:RA• is an ac.ronp for the 

Resource Conservation and Reco11e.ry Act.. That wu 

a law vhich ~• ~ssed by Congress in 1916. Ita 

purpose ia to deal with hazardous waste iasuaa. 

R.CilA if!\POees requll"emen ts on people who IM-:'&90 

hazardous .waete f rom the time i t is qenerated 

through ita atora9o, eat~nt1 or piace~ont i n o 

lat>dflll. Facilities that manage haza~douo wasto 

must tir•t obt.o.in a permit, unle$S t hey wutt ozut 

o f the permit x~tiona in the regula tiona. 

Peoaits aro very specific abOu t what types. of 

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cti itiea a ro • l l owed at tho facil ity. Per~ite 

arc u.sually issued for t en year~ . Prior to 

expiration t he facility operator must submit & 

reneval application. It the appl atio~ is 

cocQlete, the facility s&y continue to operate 

after tl'ut petcit baS expired, unti~ the n:PA ..akea 

a final deei.sion on the application. 

Toni9h~ we a~e here ~o discuss • dzaft pe~lt 

tor tho rcnew&l of e pe~~ tor the Onyx 

incinerator . 

xn thiS casa the applicatiOn vas five volumM! 

of information. As we go through the application 

we ~ke 5Ut0 th~t their desiqn and operatin9 

procedures will ~et the federal RcRA regula tions 

as ve.ll a a any ~C~Cte scr inqest. state re9Ulatlona. 

1fe send a lilt of deficien-cies to the applicant 

'Who then 111\llt respond with a..dditioo.al 1nfoce.at1on. 

~fter wo go tbtouqh this p~ss a couple of 

ti~s, we have epou9h nfo~tion to kc a porait 

clecis1on. 

In t hl.a -partictJlar a~e, regulatory c:M.ngos .' 

wee• occurring at the same time ve were roviewinq 

t ho application. these changes were deSigned to 

coordlnat.e t he miss~on.s requireMfl~$ betti'Gin RC~ 

and ebe Clef.n Air: Act.. As a result • complian~ 

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schedule wa..a tncludod i n the draft permit to 

unsu~:o t hat applicant complied with new air 

eatssion atandarde as soon &s possible. The draft 

~t also includeS a schedule and procedure to 

restrict eaiatio;ll o f meuls before the f inal 

emiselone etandards a:re achieved- &ecause. o f tho 

ch&nqin9 r69Ulaeions .,nd the ceqvired coordination 

betvo~n the various Aqeneies and progr&ma involved 

with this faelity, it has been a lonq prooeJe; but 

we have developed a draft per.tt. 

It ie our obliqation as the lseuin9 Agency .to 

prapare a· d%aft pe~it and cal l a public hearing. 

That is why ve arc here toniqht; to g~t your 

~nta on the dc.a.ft petmlc:. We ·a:Ce requixed to 

issue a public notice of our draft decisi on and 

tbe t.i.M and loe.-tion of the b0arin9 at l.N&t 4 5 

dat• btlfor• the hearing is he.lcL A!t.er the 

he.acing the record is left open for thirty days t.O 

allo" all interea·t ed cit.iu~s .a.nd the ~-.ny t.0 

~nt on the draft pe~t. At that point ve 

Ul consolidate the col'llflents and address tben1. 

ov that may lead to chanqes to the d~Aft permit 

or the pcrtnit may stay tbe same . Our reaponao and 

final decieion will take at least thirty days to 

pcepa._ce, depe.nctin9 on ~ov extf!flSiv• the COCIIIMlDtS 

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are. 

At tbia timd 1 would like t o introduce ry. 

Riegle who wil l 91ve you s~ specific technical 

1nfo~tion on th• requirements in the propO,ed 

paudt. 

(HS. artGLI!I: Good eveninq, my rwoe is Ma%Y 

Rieqle. I all an enviro.nmental engineer with the 

ll).iuoia tnvirorunental Protection Aqency. 

On NOVQmber. 4# 1991, Onyx Envi roruaental 

Secvic.ae aubm,l.ttad a Pu t B r ene wal &pplieation to 

etore and incinerate waseea. Onyx is an exil~~ 

facUlty that has been opera ting since 1919. No 

e~iona or significant ch4P90S to the operation 

axe proposed. Tbe et._ppUcat.ion consiata of a Part 

A applicatt.o·n, a descri.ptioo of' the facility, and 

~3aie mana~~nt operations, a contingency or 

~r9ency re~ponse ~n, a training p1an for 

~loyees, a cloauro plan, a waste analyaia plan, 

and detailed process informati on .. 

the appli cation was reviewed by both the 

tedctr:al and state Environment.a.l Protec tion 

Aqenc1es to dete~ne whether the ~&nY ha~ 

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dMonstrate.d that it can h andle specific b.a_tardoua 

waat¢8 within t he strin9ent requixements of RCRA. 

Since ~be IEPA aod OSZPA found the opplication 

IM!et• tbe technical requixemants, the Aqeneies 

were t'ti<(Ui.ted to dealt or propose a peoait for the 

facility. 

on June 3, 2001, a draft perai.t va.a lseu.ed to 

onyx. Today, the Aqencies are going to the pul)llc: 

with ·thi• tentative decision and r aqucstioq inP,Ut 

on thO dr•ft permit. 

Onyx racieves h&zaroou' and non-hazardous 

wasteo for repackaginq, bUlking, and i ncineration . 

These wa•tes ~y either be solids, lL~ids, or 

sludCJ••. fh•Y ean be r e ceived i o t.a.nk truckS, 

ca1l carl, or conuiners. Wastos. ftOIIl bulk trUCks 

a.re puiDPOd into t.e.nks for storage or f~ directly 

to~ incinerator. 

All ~oadin9 and atorage 

ueas ~MJSt ~~-v• aecood~ry contai~t systeaa, 

consiating of lealcproof concrete structures 

desiqned to collect spills. ~e~e areaD will be 

inspected routinely tor spills or damage. The ' 

vo lutae or these cont.ainrwant systeM must be equal 

to tba largest t3nk in the area of 10 percent of 

th• total vol~ ot the containers stored in tbc 

a.re.a. 

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ThO Onyx facility has a ~otal of tbree 

operating nazatdou• ~aste incineration units. 

Uni.ta No. 2 and No •. 3 u :e f ixed baarth, duel 

cbaq')e.r type i ucinerators. Unit No. 4 i& a 

transport&ble rotary kiln. 

Thi:l pondt. would require we tac:i.li.ty to 

foUov apael.tlc procedUres in order to operete 

safely. These procedure& i nclude tbe waste 

analysts procedu.re. ehe employee training proqram, 

and ~rqency reDponse plan. The vast• analy•1• 

plan e.nour.es that onlY wastes which ca.n be 

properly handled ~re accepted at the faoil1ty. 

wa~to ~hich do not meet the acc~ptablG criteria 

aro refused. ·Once a waste haa been evaluated and 

de~ accepu.ble, it ~ be. transported f~ the 

9enc~atot to ~e facility. At th~ tac11lty, the 

"'a•t• il a9aio ana.lyt.ed to ensure that lt 1• the 

sA*! a .• tbe approftd. waste . tt~tos 111hicb do not 

~et the facility's acceptance crit•ria or conform 

to tho initial pre-•cceptanoe analysis, ~ust be 

rejected. 

The training plan and numerous safety syatema 

and deviseS at the facility ensure tbat tbe 

e~loyHI u• pro-perly t.raio.td fo.c their jobl and 

in .-erqency proce(!ureS, and that the b.a<U<Ia 

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asaoo1Atcd wi th b4ndli ng hazardous wastes aLe 

rniniJld 7.0d 0 

The facility ' • contingency plan is dotiqned to 

provide guidance tor a quick, efficient respon14 

in the event of a $pi ll, fire, or othar t ype of 

_,.rqency. The eont-inqency plan is p.covid.ed to 

1~ -rqoncy response lJ<(>Ut>S to provide local 

autbori~iel with the nfo~tio~ necessary to deal 

wi tb •n ~mergency ~hich may impact areas off-ait•· 

onyx hal provided a copy of tba contingency 

plan to t he local police ~ fire departwents, 

emorqency teaponae teams. and some araa hospite\5 . 

Onyx muat review the contingency plan wlth each 

·group annuallY 'to ensure that all peraonne l 

ln\folve-cl in an ~rq:ency s.itua tioo a_nt f-.ili&t: 

wi.tb the {a.cility, ctte types of wastes ba.l'ldl~ by 

t.be facility, and the eonti..ngeney p lan.. u · part. 

of tbe review of the facility's ~rgencY roapona• 

· p.rocedu.reo, 1:he "9e.ncy requi red the faci~ity to 

model an ~rt-a1te air re~ease so that lPC&l 

omerqancy response t~s can ev•luate the ~act 

·tbia typo of' sl~uation m2ty haW on the c;oaaunity. 

The coii!Pany JM.l.St p~perly .aintetn record# of 

· vaate t r ack11\9 doCU."'IIents tor u.nifeat.s}, .,ploy•• 

ua.ini.nq, inspecti on reeordsr · recoxd.s of opera.t1fl9 

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conditione, and any i ncidents.· and tbc ~intenAnce 

records of th& containment systemS and equipment. 

Ths company must ~lao pexform an tnvest19ati?n 

in~ all vaate manaqement activities, pa$t and 

present, to dcte ne if these activities have 

impacted the enviro~nt. (eitbe~ the land or 

groun4w.tterl . tbi.s i-S c&lled corrective action 

~nd addr•aaea the entire taci1ity, tneludin9 thOse 

ateas vbich are not covered through thi& 

pe~1t n9 action. 

ThO renewal permit contai nS & liance 

schedule. the purpose of the compli ance aehedulo 

is to btinq h~ facility in to compliance with ~~ 

n8w HAC1' au.ndards a.s soon as possible. Th• 

tiM:f .ta-8• have been Kep-c to a adni.&u:m con41de.rinCJ 

t.be a_aount atKl CQIIPlexi ty of liOrk. It will r:esult 

in tut!.n?' .nd eJtiss1.ons aonitorin9 to be 

ua.naterred tree the RCRA perllit ~ the Clean " i.r 

Act pat11lit.. l t wi ll Al.SO reSu.lt io new motal5 

i~ta and other constituents consistent with the 

Clean 7\it "ct Permit.· 

Ait oroissions are controlled through waste 

feed li mitations, e•issions .onito~inq, and oir 

po~luti n control equipment- Waate taed is 

liaite.d by bOth amount of waste fN peX hour and 

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concantration of cont~inants in tho waste . Ths 

c~t also cequ1tes· ~ waste teed cut·off ayatem 

~hich would atop • nY waste feed ineo the 

i ncinerator when certain opeiat inq condition& are 

not aet.. 

Onyx 18 ~:ec;ulred to sonitor ocu~ta_in ea1a11on 

U.its. 'l'he facility operates a d%y scrubber 

sys~. cadbon injection unl~. and 1~ tojectlon 

unit to oonerol •ir ~is ions . 

I n addition to Onr-'s own inspeetionl , the 

factlity will be nspect~d routinely by our 

in8poctoro to &naure the f4cility's ~Li~nce 

with all RCRA requira~ents . The lllin~ia &PA baa 

the authority to inspect the facility at any ti~ 

withOUt advance notice. 

~ purpose of t~ia public bearin9 ie to gather 

the public' • ~n s on tbe drAft poxelt. Aft.er 

tho bea.df\9, the record i s le.ft open for 30 days 

to allow all interested citize.ns, as well •• the 

c;:oanpany, to aubtait c()fi':IMinU on tl\e pe:D'11ta. 

1\fte.r the ~nt period ia cloao.d, thft 

Aqepcy will consolidate the comments ~nd addre ss 

each one. Changes. vi ll b6 eade to the ~aft 

pendt if t he J19etlcy receives COf'l'oentl vhicll 

identlfy technical l5sues that were oot adOqua~~Y 

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a.ddJ:O&GGd· If no technical issues are identified, 

no chal\9&8 to the Gta.f t pextnit vill be made. 'the 

reaponua eo e~nta ~ill probabl Y t•k• abOue 30 

days, depending on how extensive t he c~t• oto 

and hOW .uch work is involved for the cy. 

'tb&nk you. 

(BY MR. Jill BUJUG!Il: Gootl evening, "'Y n.,.. le 

JLin Blouqh, I ,.lift a pe:ooit W'riter i n tb~ Waste 

Maoage~ t Division of th~ United States 

&nv1ronment4l P'rot8ction Agency located ln 

Cbica ;o, IllinoiS, My purpose berc todaY ia to 

cUaCU.SS the. uSEf:A portion of the P.CAA peralt for 

the OOVX facility $.J\ S-.uqe t, llli.nOiS 

AS you have prevlou.a.ly been told, the ReM. Act 

of 1976 vas ~aoded i n 1984. rhe 1984 R&~o%doUS 

and Solid waste ~n&oents, known as BS'MA.. i.lftPOSed 

further r•quirecaent.a for the unaqQl\\f!.Q,t of 

hazardOu~ wa6te -

Tha State of tll.inois bas re.cei"ed 

aut ori~ation to ~inister several but not all 

HS•A proviaions. ~hose conditions for which the 

st•to has not. 't)ee!l yet autbo.ri z.ed ll\USt be issued 

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by the USEPA. At the preeene time tha State of 

Illinois ia not &ut~o ized for tne impl ement4t1on 

· of cequlations found in 40 CFR Part 264 Subpart 

CC. Onyx EnvlrCM'UI'Ontal services bave three 

r~ulated units tb<lt fall under Subpart cc. The 

unlts are contalnera, ~ants, and miscellaneous 

unitsThO fir1t set. of the federal cooditiona du.l. 

with eontainer storaqe which falls under what la 

known as x..vel 1 controls and requi re onpt. to JI.Ht 

t he a.ppU.ce.ble o.s. oepart~~ent of 1'ran sport,a tion 

rcqulattona. 

The second part of the perMit daals wltb Tanka 

Requ.ixtlfl6nts . orw:ter this condition· tbe tank• 

dASitp\ capacity of e.ach t ank eust be l.esa tban 

15 a3 and t he uxiftrU.m vapor pressure aust be less 

tbaa 16. 6kP4. '!'he ha.:.a.t:doUS waste in the: t.a.nk 

eball not be heAted to a eemperature that is 

qreater than the t emperature at which t be d&X~ 

va.por preoaure of 1 6.6kPa is determined. The 

ha~atdoua wante i,n the tank shall not be treated 

by any waBte stabilizatio·n process. 

The condition also has a los~ vent sto~ and 

control devise xequirements wh ich 11 controllad by 

the ca,_rbol\ N:tsorption Systea. The parait requires 

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that onyx cOP~ly with the Applicable waste testing 

and atoraqe caquireMents prior to all oft-slto 

ahiptM-nt of waste and prohib.ited troa h&vinq 

bypaes devla•• that could be used to dl~ert the 

qa,s oc vapor atc·e.U\ to the at;.ospbere t>cfoce 

e.nterin9 the contcol device. 'fbe fi.tLa.l sot of 

Fecteral condi~ion& •dd.ress t;be Kiscell.Aoe<>US Oni.t 

O.tu. ancl t.a.bP•cJc &oxes bquir~'t-S. t'he pe.rait 

requ.lres Onf" to: 

1. Maint..iP these areas at a. sl iqhtly neqa.ti ve 

pr~eauro un¢or both ventilation and inexting 

modO•• 

2. Hainte.in an oxyqen defic ient condition of 

leos than 5 percent oxyq~ Under the inertin9 mo~a 

ud: 

3. TlW b.n d.iscbaJ:q:e CllSt be incinerated in 

the peautted on-site !Jleioeratot (Onit No. 31 . 

At tl'lil t .iJie I would J..i.ke to introdUce Gary 

Vi.ct.orLne. 

G~Y VICTORINE, Incinerator Specialist 

(BY MR. 'IICTORINEI: c;ood evening. My """"' 

is Gary Victorine. I ~ an enginee~ with the 

USEP~ a.qion S up in CRicagO. Up at Re91oo 5 t 

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coordinate and ~r ck t hft RCRA perwitting of 

hazardOUS aate incine~a ors and othec devico& 

t hat born ha~ardous wa•te. 

I'd like to focus on several issues tb1a 

e<Veni.ng. First, .1 ' d l ike to provide a bit of 

biator:y on the requladons requc1i.n9 ha.zUdo\lS 

vasto incinecators. and al.so t ell you about bow 

those rul es are currently in transition. And 

second, I ' d like to taLk aboUt how risk asaesaecnt 

ha• been 9art of the requlatory picture , both in 

qcneral a"d in the specific case of t ho onyx 

facility. 

tbe Reaou_roe conservAtion and Recovery Act 

(RCAA) -requ.is:es the OSSPA to .develop national 

standatda Cor ~z~ dous waste combustion 

tacllitiea that are protective of hl.IIPAB bOalth and 

the en,iroNDOnt. In addition, S•ction 3005 (c) (3) 

of RCRA contains lanquager we c01¥00DlY ref« to as 

the • omnibus prov-isi on•, vbich qives tho OSEI?A and 

the authorized States tbe authO~iey to include 

addi.tional te.r.m.s and condi tions in oacb RCM 

facilitY permit. a$ necessary, to pz:oteet buma.n 

heolth and the erwiro_mMnt . 

In 1981 tbe USRPA is&ued ~ CQObuotion 

standards foe Lncinerators. Since that t~, 

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however , additionAl info~ti o h as beco~ 

available whicn euggested that those sta.oda.t"dl may 

not have fully addreeaed the potential riak ftom 

i ndirect expo.sures to emissions. Now incli.rect 

expoautu can occur as a result . of contact witb 

contarainat.ed eoil. plants, water, o%" food. 

sec•uso ot ou.r coaoern rega..rd.i-09 i.ndi«ct 

oxpOSU~ds, ebe US£PA strongly r•oomdended in ita 

1994 lla~ardOUS waste tU.nlr:U.zation and COIIIbUttlon 

stxateqy that site-specific risk aA&easaent• be 

cond~ctod tor. each combUstion f acility aeekin9 a 

RCI\l\ ?ormJ.t. 

Permittin9 a\\tborities could then ua~ th.o 

result• of thfi Site.-specitic Risk Asaessaent.s to 

deteaal.ne, on & case-by- <:.aS* basi&, wbethet the 

opcr&tion of the i.ftcinerator in accoxd&nee wi tt\ 

t.be atand..erds vould be protective of huaa.t\ bl.a.lth 

and t he e.l'lviro...-.nt. In tbe>Se casu wh.ere a RC:J\A 

peorlttl.ng •uworl.ty identified a pOtentiallY . 

siQnificant riek, it could invoka the ft~ibus 

aothor:it.y• and a'Uq:ment cbe RCAA pe.J:IIIit \lith 

additional conditions. 

In 1999 toe OSEPA re~ised ~d updated ito 

nation•l atandar<1S tor hazardOUS waste-bUrnin; 

i,ncinon.tor• and other devices. Tbe USEPA • 1 f i nal 

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standaXds yete p~~~l9ated on september 30~ 1999, 

1nc~eas1n9 control over e~iss ons of ha%atdous air 

pollutants at 172 inct.nerat.orsr ~~nt kilns, and 

l iqhtweight aggrega~e kilos operating in the · 

United States. 

Thea• !aci1ltles burn aboUt 80 per~t of the 

4 million tons of ha~ardou.s waste being ca.buated 

each year. 'the ,;.-aini.nq 15 to 20 percent of 

waste 1• butned in industrial boi lers and other 

types Of induetrlal furoac•s that wi l l be 

addresecd ln a future rulem&kin9· 

1he n~w •tanda.rd~ are based on the concept of 

~i~ chievable control ~ecbno~oqy (~A-c~, or 

"MAC'l'""), an •w~oac;h required by tlle eM. HA.CT 

"C"8f1ecu the m~&Xblua deqree ot hazardous air 

pollutlon ~eduction that can be achieved 

considerinq the a-qailabUit:y, eur-re..nt use, co•t.s, 

snd environmen~ ~cts of ar~ous eai~sionl 

contrOl technologies. The MAC!' still\daXd.e 11Jait 

ettlasione of dioxins and turan.s, mercury, t~ 

seml-volatile ·metals caa.i~ and lead; tho 

low-volatile metals, are~enic, berylli~, and 

ch:romiUJ:I; particulate ro.a.tter, hyd.rochlocic acid 

and chlorine, hydroca.d>On&, and cubon monoxide. 

'l'be nev rule wa.s unusual- under tbe joint. 

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authority of th~ Clean Ail' ACt and the h&O\ltce 

conserva tion and Recovery Act. The final role 

onsu~es that combustion facilities will b• able to 

~void t wo potentially different regul atory 

co=pliance sche~s by integratinq ~e mooitorinq , 

cQdPliance testing, ~0 record keepin9 

requi reDenee of the Clean Air Act and Resource 

conservation· and Recovery Act into oAe t~ 

the Titlo V Clea.n ~r .Act per:ade. t'be: nev lo'_,.C'f 

rule and the Title V pe~t il~ ~eplaee tho RCSA 

permit ae tho pr imarY regul atory tool r.e;~Ld ng 

ha~ardou~ v4stc incinerators. 

Ces:taiJ\ly, RCAA perad'ts will continue to be 

reqU~red, but once a facil~ty ~nstrates 

c,OIIIpll&nce witb the MAC'l' rule, it maY petition to 

ro..ove pendt conditiOnS f~ its RCi<A pedlit 

covorin9 the cQIIIbustor. Generally, the only 

exce.ption vou.ld be the s i tuation whe.re additional, 

aite-sp&c1tlc pe~it COnditions re9ardUlq ~a 

i~cinerator are needed to. protect hU11'AO health and 

· the Mvirorwent, in which case those c:oncU.t.iona 

would reMi n i1\ the RCAA peadt or coold bo added 

to the RCAA peroait. 

SiD~ ~~ MACT s~dards are technol~y b&eed 

inate&d of bei.DC] risk-based. the OSBPA parfomcd a 

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national or nationwi de risk asse ssment to 

dot~~ine whether ot not the standards also 

s atisfi ed the RCRA mandate to protect human he,lth 

and· the -enviro mM~nt. 'Tb.is national ris k 

eaaed on thi.S national. risk usess~nant, the 

osEPil coocludoed thae t he te<:hn<>lOCJY-b&sed HIICT 

standard.l Mt t.be protect:i'l/e ne ss requir-ement of 

RCRA· aecauee of tbis, the Agency conclude~ thbt 

i i oJr. tta:sesame.nta tJOul d, in 9eneral, no longer be 

needed foz: hazar;doul wil:st~ co~ustion fa_c;.il,ltics. 

Althougb comprehensive, tho national riek 

aasaaement did contain ~ev~al unoert•intlos &nd 

1Laitatloas, 3od as a result, the os&P~ could not 

protactLve o f hua&n he<b and . the . vir~nt in 

•ll cuea. Thu-a. i n some oases,. a siee-apec1fic' 

riak aae•aem.nt ~Y still be neoessaFY to confi~ 

whether operation of a particu lar baz&rdoUS w•ste 

combustor in accOrdance wi th the HACT standards 

w1ll be protective. 

In order to a..ssi.st the Illinol• £PA i.n 

evaluating whether or oot the new ~T standards 

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will bo cu.lly protective tor t h is par:ticuuu: 

.bcil.ity in this particular l oca tion, the USEPA 

conduce•d a acreen1n9 r i ak analysis. l n addition, 

beeitUSO onyx ~111 not have to coll'lPlY with the new 

MACT stand4rdl until June JO, 2004, thG scxeeoinq 

~atassaeot ~s alao used to develop oartain 

eal.s.slon restrictions vbich could be included in 

thtt RCAA permit in the short termwe rcfcz to this risk analysis as a screenin9 

f i rst, it focused only 

on thoao pollutants which t .he USEPio. believ es at 

this time to have a likelihood of excQeding 

aceeptGle levels for chronic toxicity or 

ine1'e.&aod cancor ci.sk. 

And second, it is a sc~eening ~ tho aonsa 

that several si.Jq>lifyi.nCJ a.sSU~~Ptiona haVe been 

m.CS. in tbe proce&s of condUccinq the uaeaaGent, 

ca.uoinC) lt. to en· on the side of' over--pxedict1"9 

ri.sk. 

A mo~ datal led eva~ a.ti on woul d generally be . 

expect'&d to result. i n l ower. pt:edi<::t~ ria\:. 

screen1n~ analyses are g:enerallY us~d as a first 

step 1n ~he 'risk eval uati on process and can be 

ueed to determine -whether ~ more 4etailed rlak 

analysis ia called for. 

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At thi:d time, .baaed on our experience with 

the ftndinqa of si•Uar risk assessments, uSBP~ 

Region 5 has cboaeri to focu_s specificallY on the 

potential health !.pacts of polychlorinated 

dfbenzodioxlna and polychlorinated dibeD~ofurana, 

~re coaDQnlY celled dioxins and turans, plua tb• 

specific co ic/c&LCin09enic aetals ~equla~ und•r 

tbe new USE'PA re.qulat.iODS. 

~he generel .oQal tor the r is k assas~nt 

·analyais ia contained in the OSEPA1S 1998 Draft 

ttutt\an Health Rislt Assessd nt Protocol for 

u.az3rdouS Wsste combostion F~cilities. ·wtuch ls 

a~a labl~ on our website. 

secauae the evaluation of multiplo chemic&ls, 

a ultipl.e exposuce pathv a.ys, and UNl tiplo fate anci 

tranlpo~t p~sses is a very. challenglng 

exes:ci••· • c:.ocmM:t'cial CC~~DPUtu softvAre px09't'61' 

vaa ~tilize4 to run the risk assessma.ot aQdel. 

Por t bia pxojeet, we us~ the softva...re ayst• 

c&lled Integr•ted Risk Assts~nt Protocol 

tot " 11Ul.e" ) ,' dQveioped by Lakos Environmental 

software of waterloo, Ontario. tRAP was expressly 

dosiqned ~o c1osely follow the e~ndationa, 

cbeaical-apeclfic parasaters, and fat• and 

tnllllport a1god.~ qi ven ill the US&PA' • 1998 

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combustion risk assoss~ent guidance· 

~ toE the findings o! the r isk serQ•nin9, 

fix&t with 't·•apect to cliox.in.s and )urane: 

osinq actual esd.ssiot\ data provi&!:d by the 

facllity, pre,LiJai.na.ry ca.lcul&tions predicted that. 

the potentiAl iocx-eased ti$k o.f cancer ftoa 

dioxina/furans would be - ell belov the Agency's 

typical action level of l evel ot l in 100f000. 

tba OSEPA is not at this t ime recoa.aendinq any 

f urther reductions in dioxins/furans emissions. 

With respect to t oxic/carcinQ9eDiO ~tala, 

the tta_z.otdous waste eow>ustion-MACT ~ule regulates 

emisaion concenttations of t.be metals arsenic, 

bct:yU Lull, chrOilium, lead, ca&niwn. a.nd Mtcury, 

beca.u.se of the Agency" s findings, as discussed ln 

the p..:eaable ot 1:bat rule, is tbese aet&la prcaent 

a qruter potenti.al threat than other• 9ene.ra.llY 

0111-lttod from a b.at.a,dou.s waste iocine.t•tor. 'the 

preamble futther oonelud&S that omissions ot tbe 

other eoxic and carcinogenic eeta~s ~11 be 

adequatel y ro#t~iceod via t~ now par~icut•e• 

e.iesion limit contAined in that rule. However, 

because tnc BWC~'t Rule sinqle:s out these aix 

oetala, we singled them out n tbi• ris~ 

sc«ent.nq. 

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SOJH of thet~e met.als have potential toxic 

effects, and others are considered to b4 

carcinogenic. For those that are toxic, the total 

caLculAted impacts of ~ m•tal were compared to a 

va.lue of 25 percen~ ot the e.u.a.rd I.o.ct.x • . . T'M.t 

is, only a llowing the incineration facility to 

subject a person to 25 percent or le3S of ·the. 

ma..d..um .xpoaure t hought to be s.Ue. tor those 

aetalo though t to cause ca.ncer, the result• vcre 

c:ompa_r.CS to • ru.xi.mwn increased uncer riak tarqet 

valuo oe 1 in 1,000,000. 

.t ' vo got. a little bit on l ead here but I 

won ' t qo into it in the interest of time- Lead 

needs to bo loo~od at a litUe bit differently. 

And aleo for metals, rather th&n st.o.~:tlng• 

vith caiuiona and tben ealculatinq ~to and 

r1aks, we condocteO the assessment in reve%ae . 

Region 5 star·ted with t.he iq>acts .and risk& 

considered. aceeptabl·e, and then worked tbe risk 

model backwards to detemine what eaissions would 

reSult in t hose qro~nd-level concentrations and 

i•pGcta. tn this way, the analysiG eventually 

resultad in a set of suqqasted A'l.eta.l& m1.sa1on 

li .. ito. 

Now, because actual aetals emissions. conin9 out 

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the ateck are difficult to measure on a routine 

basis, RCRA por•lto have generally, instead, 

i~po~ed ceatriotiona on tbe quantity of ~atala ted 

i nto the 1nciner•tor. The relationship between 

wb4t is fed into the incinerator and vh&t ia 

emitted out the stack is established vi& testing 

which seaaures both feed and ~ssions 

si.Utoneou!llY- In the case of the onyx facility, 

feed liaits vece 6eveloped based. on removal 

effici-.ncies demon-strated du_rinq previous stac.k. 

te3tinq for tho vari ous reguLated metals. 

Wben the Onyx facility complies witb t ho HACT 

rule, cU£rently scheduled fo~ June 30 of next 

year, the teod rates of these ~etalt will be 

pEecisely tr3ekad 'and averaged continuously by 

COIIIPUter. Until th•t. time , the P..CP.A pendt 

illpOSe& u.nual techniques ancl a.dlainistra.tl.vo 

cootrola to achieve the appxopriate teed Uait.e. 

Aft•r onyx begins cOifiPlying with the MACT 

standards an<l conducts it.s KACT QOq)liance t•at, 

and after it eUb=ita th6 result s of the compliance 

test, the regulations state that it can petition 

t.ho I llinois EPA to remove MOst of the incinerator 

condition• frora the RCAA permit. Tile Illinois EPA 

will •t t hat time evaluate the test ;eeults tO 

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determi ne if some conditions should remain in the 

RCRA permit . 

Thank you very mu~h tor coming out and 

participating in this ~ting tonight. 

ROBERT W. BERNOTEI T, CAAPP, Onit Manager 

Permi~ Section, Bureau of Air 

(.BY MR.. BE:R.NOTEIT}: Good evening, ·ladies a.nd 

qe.ntlomen, my name is Bob e.e.znoteit, an acting . 

Onit Manager in the Division of ~ir Poll ution 

Control Permit Section. I wi1l now give a brief 

auavaary of' the t ype of permit we ar4t here to 

provide information to you .on. We, Of course, 

. . are also here t o list en to youx concerns and to 

answer any questions that you may have. But 

tirst~ some background on the per.i t. 

The 1990 Clean Air Act ameoc::bents created a 

federal operating permit p r;ogram knoWn ~ation~ly 

as Title V. This. program, knovn in Illinois as 

the Clean Ai r Act Permit Program, (CAAPP}, focuses 

on the indu~trial so-ur ces ot air pollut i on of 

greatest .concern. Aga tn, CAAPP is an acronym for 

Clean Ai.r l\ct Pennit Program. CAAPP and Title V 

are synonymous teens and are interchanqeable in 

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IUinoi.D. 1:hat ie~ , we refer to tlle pen•ita: th:a.t 

result fro~ thia program as both Title v patmits 

and CMPP perlllita. 

The CA,P.PP r11quire.s tha t a si.t\918 petmit be 

issued to each offacted source tbat covers all 

emission unit• and ac~vities a t tbe souxeo. 

Detore a source could have a&nY as tOO penU.t• i,n 

sooe cas••. onyx. has bad as eany as 18 stat• 

s&pa.x:a.te &1r ope~atlnq pe~iti. 1!his often cauaoa 

confusion and pe~it conflicts. The sinqle, 

a~l-lncluaive pe~it stra~egy required by Title V 

oiq>ll.od the process down to a .single, enforceable 

docuMent. Thea• CAAPP per~ts ar e very detailed in 

scope and ran9e in size from 50 to 1,000 p49••· 

the typical ai:o ot an operat ing per~it before the 

CAAPP waa only l to 5 pages. onyx • s clr&f t peEeit 

i s 165 pac;as. 'the state opet.a ting permit• t:or 

onyx•s Unite 2 &nd 3 ~ere 5 pages eacb. 

The tEPA haa oomai ~d in writing to USEP~ to 

iaaue ita r~inio9 ~P permits by the end of 

th~O ye&r -- 2003. 

The i;asuonce of a t-~e V per~~oit trig9ers 

R~ny benefi~ that assist in tbe compliance aod 

Some of enforce~~ent of applicable require.enta. 

thel6 benctits· are: 

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~11 requirements ace consolidated in a single 

~mit; 

All oondit,ioos i n the peroit, with the 

exception of those to~ fees, are t edec&lly 

ento.cceable, et•t• enforceable, and enforceable by 

the publiCI 

Oft;en t~• .q~ .onitori..ncJ i .s requi.red, if 

not, the pc~lt at ~east provides a check that 

current monitoring is appropriate. 

Ths more repo~tinq r equired -- allovs a 

periodic eelf-eheck by t he $Ource of ~OPplianoe. 

Tho b19 4 r.eportinq requirements: 

1. Reportin9 of Devi&tions. 

2. Soai-Mnual Honitori ng Report; 

3 _ Annual Ca.pl.iance. certification, which ia 

ono of the aain tooLs for compli..ance and it only 

beCOMS required a .fter the 'title v pemit 1• 

1asued. Thi,s is one of. the primarY drawbacks of 

CAAPP permi&l not beinq issued as quickly as 

poniblt. 

4. Annual e.issions Report -- many may S4Y 

thla is ·already required, and i t is, but onco t he 

CAA.'PP permit l.s i .ssued there . becomes avaiLable t.o 

the tEPA o ainqle document to c tos a-cbeck with tho 

·Annual &aU-saions Report nUllllber s for coapUance. 

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