## Attachment 2: Technical Support Document for Related Permit Action

The technical support document for Air Emission Permit No. 03700011

- 012 can also be found online: http://www.pca.state.mn.us/index.php/view

- document.html?gid=22570

.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 1 of 33 

## TECHNICAL SUPPORT DOCUMENT

For

AIR EMISSION PERMIT NO. 03700011

‐ 012

This technical support document (TSD) is intended for all parties interested in the permit and to meet

the requirements that have been set forth by the federal and state regulations (40 CFR § 70.7(a)(5) and

Minn. R. 7007.0850, subp. 1). The purpose of this document is to provide the legal and factual
justification for each applicable requirement or policy decision considered in the determination to issue

the permit.

1. General Information

1.1 Applicant and Stationary Source Location:

Table 1. Applicant and Source Address

Applicant/Address Stationary Source/Address

(SIC Code: 2911)

Flint Hills Resources Pine Bend, LLC

PO Box 64596

St. Paul, MN 55164

‐ 0596 (Operator)

4111 East 37th St. North

Wichita, KS 67220 (Owner) Flint Hills Resources Pine Bend Refinery

13775 Clark Road

Rosemount, Dakota County, Minnesota 55068

Contact: Greg Myers 651

‐ 480

‐ 2712 (CHP) Mark Manninen 651

‐ 480

‐ 2685 (Tier 3 Clean Fuel)



## 1.2 Facility Description

Flint Hills Resources Pine Bend, LLC (FHR) owns and operates the Pine Bend Refinery (“refinery” or “facility”) in the city of Rosemount, Dakota County, Minnesota. The refinery primarily processes heavy,

sour crude oil from Western Canada, although it may also process oil from other parts of the world.
Pipelines currently deliver all of the crude oil to the refinery, where FHR processes it to produce a wide

variety of products. These products include gasoline, diesel fuel, heating oil, jet fuel, petroleum coke,
asphalt and elemental sulfur. FHR distributes these products to customers in Minnesota and the
surrounding Upper Midwest states via pipelines, trucks, barges and railcars.

1.3 Description of the Activities Allowed by this Permit Action

This permit action is a major amendment to an existing major source. It is composed of two unrelated

permit actions. The first project is for the construction of a natural gas based combined heat and power cogeneration facility, generating up to a net 49.9 megawatts (MW) of electricity to reduce electrical
purchases from the grid and up to 290,000 lb/hr steam production, depending on operating
configuration, to improve the efficiency of steam production at FHR.

The second project involves investments proposed by FHR to meet the Environmental Protection
Agency’s Tier 3 gasoline sulfur standard which becomes effective in 2017. The Tier 3 program will set

new vehicle emissions standards and lower the sulfur content of gasoline. To accomplish this, FHR plans

to increase the extent of hydrotreating in the 33 (EU084

‐ 085) and 38 (EU102

‐ 104) Unit gas

‐ oil
hydrotreaters (GOHTs) to remove sulfur from intermediate fuel products. No physical changes are required at the GOHTs to accommodate the additional hydrotreating. However, additional sulfur

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 2 of 33 

## removal via hydrotreating increases the removal of nitrogen, both of which tax existing sulfur

‐ management units, including amine systems, sour water system, and sulfur

‐ recovery plant which

support desulfurization.

FHR proposes installing a process unit (EU361) to convert gas containing sulfur and nitrogen into a salable, non

‐ hazardous, aqueous liquid fertilizer, ammonium thiosulfate (ATS). FHR also proposes to use

a more efficient amine solution in the existing amine treatment units. FHR also plans a sour

‐ water

skimmers and tanks improvements project to reduce potential process safety risks. This will improve

FHR’s skimming and storage systems for sour water. This project will be funded separately and
completed independent of the ATS process unit or other project

‐ related work.

This permit action also incorporates reopenings for EU102, EU103 and SV066. There are also two

corrections with respect to permit action ‐ 010 regarding a 40 CFR pt. 60, subp. Ja NO X 

## limit on EU352
(23H3) and monitoring of pressure drop for EU336 (Coke Drum System E & F).

1.4 Facility Emissions:

Table 2. Title I Emissions Summary for Combined Heat and Power Project

Pollutant Emissions

Increase from

the

Modification
(tpy) Limited

Emissions

Increase from

the

Modification
(tpy) Source

‐ wide

Contemporaneous

Increases and

Decreases *
(tpy) Net

Emissions

Increase

(tpy) NSR/112(g)

Significant

Thresholds

for Major

Sources

(tpy) NSR/ 112(g)

Review
Required?
(Yes/No)

PM 16.8 16.8 NA 16.8 25 No

PM 10 

## 16.8 16.8 NA 16.8 15 Yes

PM 2.5 

## 16.8 16.8 NA 16.8 10 Yes

NO

x 

## 187.7 27.7 NA 27.7 40 No

SO 2 

## 4.1 4.1 NA 4.1 40 No

CO 267.9 66.9 NA 66.9 100 No

Ozone (VOC) 57.1 28.0 NA 28.0 40 No

Lead 1.4E

‐ 03 1.4E

‐ 03 NA 1.4E

‐ 03 0.6 No

CO 2 

## e** 345,263 345,263 NA 345,263 75,000 Yes

SAM*** 4.7 4.7 NA 4.7 7 No

Hexane (I) and

total (T) HAPs 5.2(I)/6.8(T) 5.2(I)/6.8(T) NA 5.2(I)/6.8(T) 10/25 No



## *Other emission changes during the contemporaneous period as defined by 40 CFR § 52.21, 40 CFR

§ 52.24 or 40 CFR pt. 51.

**Carbon dioxide equivalents as defined in Minn. R. 7007.0100.

*** Sulfuric acid mist

Table 3. Title I Emissions Summary for Tier 3 Clean Fuels Project

Pollutant Emissions

Increase from

the

Modification
(tpy) Limited

Emissions

Increase from

the

Modification
(tpy) Source

‐ wide

Contemporaneous

Increases and

Decreases *
(tpy) Net Emissions

Increase

(tpy) NSR/112(g)

Significant

Thresholds

for Major

Sources

(tpy) NSR/ 112(g)

Review
Required? (Yes/No)

PM 30.7 11.7 NA 11.7 25 No

PM 10 

## 27.3 9.6 NA 9.6 15 No

PM 2.5 

## 9.0 8.4 NA 8.4 10 No

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 3 of 33 Pollutant Emissions

Increase from

the

Modification
(tpy) Limited

Emissions

Increase from

the

Modification
(tpy) Source

‐ wide

Contemporaneous

Increases and

Decreases *
(tpy) Net Emissions

Increase

(tpy) NSR/112(g)

Significant

Thresholds

for Major

Sources

(tpy) NSR/ 112(g)

Review
Required?
(Yes/No)

NO

x 

## 33.5 33.5 NA 33.5 40 No

SO 2 

## 36.4 36.4 NA 36.4 40 No

CO 18.4 18.4 NA 18.4 100 No

Ozone (VOC) 35.5 35.5 NA 35.5 40 No

Lead 9.4E

‐ 05 9.4E

‐ 05 NA 9.4E

‐ 05 0.6 No

CO 2 

## e** 39,164 39,164 NA 39,164 75,000 No

SAM*** 0.1 0.1 NA 0.1 7 No

H 2 

## S 3.8 3.8 NA 3.8 10 No

TRS 4.1 4.1 NA 4.1 10 No

RSC 7.9 7.9 NA 7.9 10 No

Carbon

Disulfide (I) and

total (T) HAPs 2.1(I)/2.8(T) 2.1(I)/2.8(T) NA 2.1(I)/2.8(T) 10/25 No



## *Other emission changes during the contemporaneous period as defined by 40 CFR § 52.21, 40 CFR

§ 52.24 or 40 CFR pt. 51.

**Carbon dioxide equivalents as defined in Minn. R. 7007.0100.

*** Sulfuric acid mist

H 2 

## S = Hydrogen Sulfide, TRS = Total Reduced Sulfur, RSC = Reduced Sulfur Compounds

Table 4. Total Facility Potential to Emit Summary

PM

tpy PM 10


## tpy PM 2.5


## tpy SO 2


## tpy NO

x 

## tpy CO

tpy CO 2 

## e

Tpy VOC

tpy All

HAPs

tpy

Total Facility Limited

Potential Emissions

Pre

‐ Mod 1032.7 641.1 627.6 3770 3952.6 2391.0 7,837,536 2610.5 855

CHP (Change in PTE) 16.8 16.8 16.8 4.1 27.7 66.9 345,263 28.0 6.8

Tier 3 (Change in PTE) 11.7 2 

## 9.6 2 

## 8.4 2 

## 36.4 33.5 18.4 39,164 35.5 2.8

Total Facility Limited

Potential Emissions

Post

‐ Mod 1061.2 667.5 652.8 3770 1 

## 4013.8 2476.3 8,221,963 2674 864.6

1: Facility

‐ wide 3770 tpy SO 2 

### limit will remain in the permit

2: Includes 7.23 tpy PM, 1.45 tpy PM 10 

### and 0.35 tpy PM 2.5 

### assigned to new haul road traffic, an insignificant activity (IA060)



## Table 5. Facility Classification

Classification Major Synthetic Minor/Area Minor/Area

PSD X

Part 70 Permit Program X

Part 63 NESHAP X



## 2. Regulatory and/or Statutory Basis

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 4 of 33 

## New Source Review

The facility is an existing major source under New Source Review regulations. No changes to the facility’s

major source status are authorized by this permit.

The combined heat and power (CHP) project is subject to PSD/NSR for criteria pollutants PM 10 

## and PM 2.5 

## and for CO 2 

## e. FHR has proposed Best Available Control Technology (BACT) limits for PM 10 

## , PM 2.5 

## and

CO 2 

## e at GP135 for the gas turbine (EU359) and duct burners (EU360) at the cogeneration plant.

For discussion of Endangered Species, and National Historic Preservation Acts, and the PSD Additional

Impacts Analysis, see Additional Air Quality Regulatory Applicability Documentation below.

Part 70 Permit Program

The facility is a major source under the Part 70 permit program. This permit action does not change this

status.

New Source Performance Standards (NSPS)

40 CFR pt. 60, subp. KKKK: NSPS for Stationary Combustion Turbines

40 CFR pt. 60, subp. Ja: NSPS for Petroleum Refineries for which Construction, Reconstruction, or

Modification Commenced After May 14, 2007

40 CFR pt. 60, subp. Kb: NSPS for Volatile Organic Liquid Storage Vessels (Including Petroleum Liquid

Storage Vessels) for which Construction, Reconstruction, or Modification Commenced After July 23,

1984

40 CFR pt. 60, subp. GGGa: NSPS for Equipment Leaks of VOC in Petroleum Refineries for which

Construction, Reconstruction, or Modification Commenced After November 7, 2006

40 CFR pt. 60, subp. QQQ: NSPS for VOC Emissions from Petroleum Refinery Wastewater Systems

National Emission Standards for Hazardous Air Pollutants (NESHAP)

40 CFR pt. 63, subp. CC: NESHAP from Petroleum Refineries

40 CFR pt. 63, subp. YYYY: NESHAP for Stationary Combustion Turbines

Compliance Assurance Monitoring (CAM)

CAM applies to the CHP modification allowed in this permit amendment, since the unit is an other
pollutant specific emission unit (PSEU) for CO and NO X


## . Because the controlled PTE for CO and NO X 

## is

below 100 tpy the Permittee is not required to submit the monitoring plan required under 40 CFR § 64.4

until their next application for permit renewal because the unit is not a large PSEU.

Environmental Review & Air Emissions Risk Analysis (AERA)

The CHP project is subject to a mandatory EAW for construction of an electric power generating plant

and associated facilities designed for or capable of operating at a capacity of 25 to 50 MW. The project

also triggers a mandatory EAW under Minn. R. 4410.4300, subp. 15(B) for construction of a stationary

source that generates a combined 100,000 tons or more per year of greenhouse gas emissions.

The Tier 3 Clean Fuels project is subject to a mandatory EAW under Minn. R. 4410.4300, subp. 10 for

construction of a facility on a single site designed for or capable of storing 1 million gallons or more of

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 5 of 33 

## hazardous materials. The storage capacity of the proposed sour water tanks will be greater than 1

million gallons.

Minnesota State Rules

Portions of the facility are subject to the following Minnesota Standards of Performance:

 Minn. R. 7011.1435 Incorporation of New Source Performance Standard by Reference

 Minn. R. 7011.1520 Incorporation of New Source Performance Standard by Reference

 Minn. R. 7011.7280 Petroleum Refineries

 Minn. R. 7011.8120 Stationary Combustion Turbines

Table 6. Regulatory Overview of Units Affected by the Modification/Permit Amendment

Subject

Item* Applicable Regulations Rationale

GP008

GP019

GP042

GP046 Various groups subject to 40

CFR pt. 60, subp. Kb

requirements TK586, TK587 and TK588 being added as associated items to these

groups.

GP067

GP069

GP076

GP082

GP087

GP090

GP091

GP093

GP095

GP096

GP099

GP100

GP101

GP102

GP114

GP125 Various groups subject to 40

CFR pt. 60, subp. QQQ, 40 CFR

pt. 61, subp. FF and Leak

Detection And Repair FS140 being added as an associated item to these groups.

GP054 Minn. R. 7011.1405 EU167 added to GP054. This is an existing affected facility at a petroleum refinery.

GP132 40 CFR Section 52.21(j) BACT;

Minn. R. 7007.3000 FS139 added to GP132 as equipment in natural gas service to comply

with LDAR requirements of GPs 087, 090, 091, 093, 101 and 114

GP135 40 CFR Section 52.21(j) BACT;

Minn. R. 7007.3000

40 CFR pt. 60, subp. KKKK

40 CFR pt. 63, subp. YYYY BACT Limits on PM 10 

## , PM 2.5 

## and CO 2 

## e.

NSPS for Stationary Combustion Turbines: Construction after Feb. 18,

2005, maximum heat input greater than 10 mmBtu/hr. Limits on NO X 

## and SO 2


## . NESHAP for Stationary Combustion Turbines: Stationary combustion

turbine is located at a major HAP source.

GP136 40 CFR Section 52.21 and

Minn. R. 7007.3000 Limits to avoid a major modification under 40 CFR Section 52.21.

SV042

SV093

SV094 40 CFR pt. 60, subp. Ja Applicability of 40 CFR pt. 60, subp. J will expire after startup of

EU361 at which time requirements of 40 CFR pt. 60, subp. Ja become

effective.

SV066 Minn. R. 7017.2025 Setting a new heat input limit for SV066.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 6 of 33 Subject

Item* Applicable Regulations Rationale

EU102

EU103 Minn. R. 7017.2025 Setting new heat input limits for both EU102 and EU103 and a new

maximum O 2 

## concentration operating limit for EU103.

EU213 Minn. R. 7017.2025 Setting new heat input limit for EU213.

EU352 40 CFR pt. 60, subp. Ja Correction to PER010. EU352 requires induced rather than forced

draft and is subject to a lower NO X 

## limit.

EU361 SIP for SO 2 

## NAAQS, 40 CFR pts.

50 and 52, subp. Y, MN SIP

40 CFR pt. 60, subp. Ja

Minn. R. 7011.0715 SO 2 

## limits to 1

‐ , 3

‐ and 24

‐ hr and 12

‐ month rolling averages.

NSPS for Petroleum Refineries for which Construction,

Reconstruction or Modification Commenced after May 14, 2007

Post

‐ 1969 Industrial Process Equipment Rule



## *Location of the requirement in the permit (e.g., EU, SV, GP, etc.).

The language 'This is a state

‐ only requirement and is not enforceable by the U.S. Environmental

Protection Agency (EPA) Administrator and citizens under the Clean Air Act' refers to permit

requirements that are established only under state law and are not established under or required by the

federal Clean Air Act. The language is to clarify the distinction between permit conditions that are required by federal law and those that are required only under state law. State law

‐ only

requirements are not enforceable by the EPA or by citizens under the federal Clean Air Act, but are fully

enforceable by the MPCA and citizens under provisions of state law.

3. Technical Information

Major PSD Amendment for Combined Heat and Power Cogeneration Facility (DQ 4744)

The combined heat and power (CHP) cogeneration facility will generate electricity and steam to be
provided exclusively to the refinery to reduce electricity purchases from the grid and improve steam production efficiency at FHR. The efficiency benefits from CHP and distributed generation result in a

reduction of refinery operating costs and air emissions compared to electricity purchased from the grid.

Cogeneration of electricity and steam is more efficient than producing both separately, and on

‐ site
electricity generation prevents losses related to transmission and distribution.

This permit action authorizes the construction of a combined

‐ cycle natural gas facility consisting of a

General Electric LM6000 PF combustion turbine (EU359), a heat recovery steam generator (HRSG) with

duct burners (EU360), a steam turbine and an air

‐ cooled condenser. The total generating capacity will be

49.9 megawatts (MW) net and up to 290,000 pounds per hour (lb/hr) of 250 pounds per square inch
(psi) steam (depending on operating scenario).

The project does not involve the modification of any existing emission units; therefore, the emissions

increase analysis for Prevention of Significant Deterioration (PSD) applicability includes only new

emission units constructed with this project.

CHP Facility Description

The facility will include a General Electric LM6000 PF aeroderivative combustion turbine (EU359) rated

at 49.9 MW net located on property owned by FHR; HRSG with duct burners (EU360) and exhaust stack
(SV189); steam

‐ turbine generator set with extraction point for steam supply to the refinery; air

‐ cooled

condenser for heat rejection; switchyard; piping (including equipment in natural gas service (FS139) with

the potential for fugitive emissions of natural gas); and auxiliary equipment and buildings normally
provided for plants of this type (e.g., auxiliary transformers, water treatment equipment and operations

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 7 of 33 

## and maintenance building). The CHP facility will provide all net power and steam it generates to the
refinery for its sole consumption.

The HRSG will produce steam at 900 psig and 750 o 

## F. Depending on power and steam demands and

limits, the steam will either be regulated at 250 psig and exported to the refinery or directed to a steam

turbine capable of converting its energy to up to 12 MW of electricity. Steam export will be transported

to the refinery via a new steam/condensate pipe supported aboveground on sleeper supports.

The combustion turbine (EU359) will be fueled by natural gas supplied by the Northern Natural Gas

interstate pipeline system to a delivery point at the refinery. Piping will carry the gas from the delivery

point to the CHP cogeneration facility. EU359 will be equipped with low

‐ NO X 

## burners. No exhaust bypass

stack will be used making the turbine incapable of running independently from the steam heat recovery

system. The HRSG will have natural gas

‐ fired duct burners (EU360) for supplementary heat input and

contain an oxidation catalyst (CE078) for reducing CO and VOC emissions, as well as an aqueous

ammonia based selective catalytic reduction (SCR) system (CE079) for reducing NO X


## . Aqueous ammonia
(19%) for the SCR system will be delivered to the CHP cogeneration site and stored in a tank. Forwarding

pumps will transfer the aqueous ammonia from the storage tank to the ammonia vaporization skid near

the HRSG. The aqueous ammonia will then be vaporized by electric heaters or flue gas and injected into

the ammonia grid upstream of the SCR catalyst. Use of clean fuels (i.e., natural gas) and good

combustion practices will serve as the basis for BACT limitations for PM 10 

## and PM 2.5



## . These techniques
along with energy efficiency measures will provide the basis for the CO 2 

## e BACT limit. The cogeneration
plant will be located south of the existing refinery process area, but still within the FHR facility boundary.

The steam export pipeline will run north from the cogeneration facility to connect with the existing
refinery pipe rack. This project will not have emergency or auxiliary engines because it is not designed to

start up after a power outage without a feed from the transmission grid (i.e., “black start” capability).

Construction is anticipated to begin in mid

‐ 2015. FHR anticipates an in

‐ service date as early as fourth

quarter 2016.

The current base design case for power distribution routes power from the CHP generators to load

centers in the refinery and does not enter the transmission system (i.e., grid). FHR is exploring

alternative pathways to move the power from the CHP into the refinery, including the potential use of

the transmission system supplying the refinery. The present analysis is based solely on the base design

case and not the alternative connection options under consideration. If the design changes to one of the

alternatives, the applicability of any additional rules (i.e., Acid Rain Program, 40 CFR pt. 60, subp. TTTT,

Cross State Air Pollution Rule/Clean Air Interstate Rule (CSAPR/CAIR)) will be addressed with a future

permit amendment and the project schedule could change as a result. CAIR is currently stayed in

Minnesota.

Review of Non

‐ Modified Units Potentially Affected by CHP Project

The CHP cogeneration facility will have no impact on the capacity, utilization or output of the refinery

process units. The refinery is capable of meeting its electric demands from the grid and its process

steam demand from gas

‐ fired boilers and other process steam generators and would retain that
capability regardless of whether the CHP cogeneration facility were constructed. There will be no

modifications to the refinery steam system within the refinery battery limits. The refining process equipment and emission units are not affected units.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 8 of 33 

## Steam will be extracted from the HRSG and/or steam turbine and exported to the refinery as dictated by

process steam requirements. This represents a more efficient and economical source of steam than the

existing boilers and is expected to reduce fuel usage in those boilers. The boilers are not affected units.

Air cooled condensers will be used to meet heat rejection requirements. No heat rejection or emission

increase will result in the existing cooling towers as a result of this project. Approximately 5 gallons per

minute of blowdown from the CHP facility’s steam system will be evaporated in the cooling towers. The

blowdown is expected to have a total dissolved solids (TDS) concentration of 130 milligrams per liter (mg/L). The cooling towers currently operate with a TDS concentration of 1000 to 3000 mg/L. The

recirculation rate will not be affected by this project. The blowdown discharge would be dilutive in

concentration and not increase the water flow rate of the cooling towers. The project does not have the
potential to increase drift emissions and the cooling towers are not affected units.

The CHP facility will not be connected to the refinery flare system or result in changes to the frequency

of refinery turnaround events that could cause flaring. The flare system is not an affected unit.

The CHP facility is not expected to increase load at the wastewater treatment plant so emissions at the

closed

‐ vent system thermal oxidizer shouldn’t increase. During normal operations, wastewater discharge from the project will be sent to the cooling tower basin(s). A backup system will exist to truck

blowdown water to the wastewater treatment plant if the blowdown is not accepted by the cooling

towers. Since blowdown does not contain hydrocarbons or sulfur compounds that would off

‐ gas to the

collection system for destruction in the thermal oxidizer, the wastewater treatment plant equipment is

not an affected unit(s).

PSD Regulatory Applicability Analysis

Because the CHP cogeneration facility contains only new emission units, the actual

‐ to

‐ potential test specified in 40 CFR Section 52.21(a)(2)(iv)( d ) will be used:

“Actual

‐ to

‐ potential test for projects that only involve construction of a new emission unit(s). A
significant emissions increase of a regulated NSR pollutant is projected to occur if the sum of the
difference between the potential to emit (as defined in paragraph (b)(4) of this section) from

each new emissions unit following completion of the project and the baseline actual emissions
(as defined in paragraph (b)(48)(iii) of this section) of these units before the project equals or

exceeds the significant amount for that pollutant (as defined in paragraph (b)(23) of this
section.)”

The terms “new emission unit”, “potential to emit” and “baseline actual emissions” have specific

meanings ascribed by the applicable rules. A “new emission unit” includes any part of a stationary

source that will emit a regulated NSR pollutant and be newly constructed. The “baseline actual

emissions” for a new emission unit is zero prior to initial operation. Potential to emit (PTE) is defined as:

“...[t]he maximum capacity of a stationary source to emit a pollutant under its physical and
operational design. Any physical or operational limitation on the capacity of the source to emit a pollutant, including air pollution control equipment and restrictions on hours of operation or on

the type or amount of material combusted, stored, or processed, shall be treated as part of its
design if the limitation or the effect it would have on emissions is federally enforceable.”

The PTE for an emission unit yet to be constructed is calculated as the product of its hourly maximum
throughput or heat input capacity and an uncontrolled emission factor taken from AP

‐ 42, a

manufacturer’s performance guarantee, existing regulatory standards or other information sources.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 9 of 33 

## Enforceable emission limitations on the capacity of the source to emit a pollutant (e.g., air pollution

control equipment, restrictions on hours of operation) may be taken to reduce the unit’s PTE.

New Combustion Turbine (EU359)

The LM6000 PF combustion turbine (EU359) will be fired exclusively with pipeline natural gas. It will be
equipped with low

‐ NO X 

## technology and SCR (CE079) to maintain low NO X 

## emissions, and a catalytic

oxidizer (CE078) to control CO and VOC emissions. The PTE for PM 10 

## and PM 2.5 

## are based on proposed

PM 10 

## and PM 2.5 

## BACT limits derived from a statistical analysis of available performance test results for

other LM6000 PF installations as discussed in more detail in the attached BACT analysis. The PTE

calculations for NO X 

## , CO and VOC are based on performance guarantees and estimates from the

manufacturer and design basis specifications provided to the SCR and catalyst vendor(s) as applicable.

Calculations for other PSD pollutants are based on emission factors for natural gas combustion from AP

‐
42 chapter 1.4.

PTE of combustion turbines varies greatly based on ambient conditions. They are highest during cold

ambient temperatures due to colder air being denser allowing for higher mass flow and fuel input rates

in the turbine. PTE calculations are based on an ambient temperature of
‐ 16 o 

## F, corresponding to the

turbine’s 435 mmBtu/hr rated capacity based on a higher heating value (HHV) basis.

For most pollutants the maximum emission rates occur at 100 percent load. However, CO and NO X 

## emissions are greatest when the turbine is starting up or shutting down. CO and NO X 

## startup emissions

are calculated using startup emission curves provided by the manufacturer. Annual PSD PTE calculations

account for 48 hours of startup and shutdown operation based on 12 startups and shutdowns per year,

each with an average duration of four hours. This is a conservative assumption as FHR expects to

operate the CHP facility continuously with one or two startups and shutdowns per year.

EU359 is subject to BACT for PM 10 

## , PM 2.5 

## and CO 2 

## e emissions as described in the BACT analysis. FHR will

take synthetic minor limits for CO and NO X 

## to avoid a major modification under 40 CFR Section 52.21. CO

and NO X 

## emissions will be monitored by the use of continuous emissions monitoring systems (CEMS)
(MR202, MR203).

New Duct Burners (EU360)

The duct burners (EU360) will be fired exclusively with pipeline natural gas. The PTE for PM 10 

## and PM 2.5



## are based on the same proposed PM 10 

## and PM 2.5 

## BACT limits for EU359 above. EU360 will use low

‐ NO X 

## burners and NO X 

## , CO and VOC emissions will be controlled by the same SCR (CE079) and catalytic

oxidizer (CE078) as EU359. PTE for these pollutants is based on design basis specifications provided to

the SCR and catalyst vendor(s) as applicable. Calculations for other PSD pollutants are based on emission

factors for natural gas combustion from AP

‐ 42. The rated heat input capacity of EU360 is 239 mmBtu/hr

on a HHV basis.

The duct burners (EU360) will operate only when the combustion turbine (EU359) is at or near full load,

at which time the HRSG will already be heated. The startup and shutdown of the duct burners will not

result in higher emissions. The maximum emission rates occur when the duct burners are operating at

100 percent load. The duct burners are subject to BACT for PM 10 

## , PM 2.5 

## and CO 2 

## e as described in the

BACT analysis.

New Equipment in Natural Gas Service at the CHP Facility (FS139)

This project involves the installation of certain equipment in natural gas service (FS139). FHR estimates

the number of valves and flanges associated with this project based on similar combined

‐ cycle designs,

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 10 of 33 

## adding a 33 percent safety factor to the estimate to take into account potential differences in the site
specific design. FHR estimates the CHP facility will have 100 valves in natural gas service and three
flanges per valve.

FHR’s Title V permit establishes that refinery equipment in VOC service is subject to enhanced LDAR

requirements. LDAR requirements include a lower definition of a “leaking” component threshold

concentration and installation of components with low

‐ leak and/or leakless technologies in certain
applications. FHR proposes to extend the application of the enhanced LDAR requirements to FS139 for

purposes of monitoring GHG emissions at the CHP facility. FS139 will be added to the existing BACT limit

at GP132. For purposes of estimating GHG PTE for the new components and in consideration of the

enhanced LDAR requirements, the following assumptions were made (Equations from RTI International.

“Emission Estimation Protocol for Petroleum Refineries.” May 2011):

 96% of valves and connections (flanges) are assumed to be emitting 100 ppm methane; the

remaining 4% are assumed to be emitting 10,000 ppm methane

 Valve equation: tpy = 2.29 E

‐ 06 x (# of components) x (2.2 lb/kg) x 4.38 x (emission conc.) 0.746



##  Flange equation: tpy = 4.61 E

‐ 06 x (# of components) x (2.2 lb/kg) x 4.38 x (emission conc.) 0.703



## The PTE from new components using these equations overestimates emissions because most

components are expected to perform well below the estimated leak rates.

PSD Reasonable Possibility Recordkeeping Requirements

Federal PSD rules at 40 CFR Section 52.21(r)(6) define when a Permittee is required to conduct
recordkeeping and reporting when using the actual

‐ to

‐ projected

‐ actual emissions increase calculation
methodology for modified or affected units. Since the CHP facility consists only of new units, the actual

‐

to

‐ projected

‐ actual emissions methodology was not used and reasonable possibility recordkeeping

requirements do not apply.

Additional Air Quality Regulatory Applicability Documentation

Minnesota Rule Chapter 4410 ‐ Environmental Review

Though not an air quality program, Minnesota’s Environmental Review process at Chapter 4410 contains
mandatory Environmental Assessment Worksheet (EAW) and Environmental Impact Statement (EIS)

categories that are germane to the proposed projects. A proposed project that meets a mandatory EAW

or EIS category must complete the respective environmental assessment/impact analysis for review and
approval by a responsible governmental unit (RGU). Two mandatory EAW categories were examined

concerning electric generating facilities and air pollution generation.

EAW Trigger for Electric Generating Facilities

The following mandatory EAW trigger is described at Minn. R. 4410.4300, subp. 3:

“Subp. 3 Electric generating facilities. For construction of an electric power generation plant and

associated facilities designed for or capable of operating at a capacity of between 25 megawatts

and 50 megawatts, the EQB shall be the RGU. For electric power generating plants and

associated facilities designed for and capable of operating at a capacity of 50 megawatts or

more, environmental review shall be conducted according to parts 7849.1000 to 7849.2100 and

7850.1000 to 7850.5600.”

The proposed CHP facility is designed for and capable of operating at a net generating capacity of 49.9

MW. Thus, pursuant to Minn. R. 4410.4300, subp. 3, the CHP facility triggers a mandatory EAW.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 11 of 33 

## EAW Trigger for Air Pollution Generation Increase

The following mandatory EAW trigger is described at Minn. R. 4410.4300, subp. 15:

“Subp. 15 Air pollution. Items A and B designate the RGU for the type of project listed.

A. For construction of a stationary source facility that generates 250 tons or more per year or modification of a stationary source facility that increases generation by 250 tons or more per

year of any single air pollutant, other than those air pollutants described in item B, after

installation of air pollution control equipment, the PCA shall be the RGU.

B. For construction of a stationary source facility that generates a combined 100,000 tons or

more per year or modification of a stationary source facility that increases generation by a

combined 100,000 tons or more per year of greenhouse gas emissions, after installation of air
pollution control equipment, expressed as carbon dioxide equivalents, the PCA shall be the RGU.

For purposes of this subpart, “greenhouse gases” include carbon dioxide, methane, nitrous oxide,
hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride, and their combined

carbon dioxide equivalents shall be computed by multiplying the mass amount of emissions for

each of the six greenhouse gases in the pollutant GHGs by the gas’s associated global warming
potential published in Table A

‐ 1 to subpart A of Code of Federal Regulations, title 40, part 98,

Global Warming Potentials, as amended, and summing the resultant value for each.”

For determining air emissions generation increase under this category, the MPCA clarified that the

calculation method is to follow the methods for a state air permit or modification in Minn. R. 7007.1200,
subp. 3 for non

‐ Title I modifications as described below:

“The state permit calculation method compares the potential to emit (PTE) before and after a proposed change. The comparison can be thought of as looking at snapshots in time of the

emissions before and after a proposed project.

For permits, this calculation method compares hourly emission rates. For EAWs, however, the

trigger is in tons per year. Therefore, you would follow the steps described by Minn. R.

7007.1200, subps. 3.A, 3.B, and 3.C to obtain a comparison of the potential emissions before and
after the proposed project. After you find the change in the potential hourly emission rates, you

would then make a tons

‐ per

‐ year calculation considering emission control equipment, emission

decreases, or long term potential limits as appropriate. For example, if your facility has or is

proposing an annual cap on emissions, this limit would be taken into account when deciding if

there is an emissions increase.”

The emissions increase due to this project is calculated as the sum of the PTE of the new units:

 New combustion turbine (EU359)

 New duct burners (EU360)

 New natural gas equipment at the CHP facility (FS139)

Table 7. Change in Air Pollution Generation for EAW Applicability (tpy)

Emission Unit MPCA ID NO X 

### SO 2 

### CO PM PM 10 

### PM 2.5 

### VOC CO 2 

### e

New Combustion Turbine EU 359 15.7 2.7 37.9 10.8 10.8 10.8 17.7 222,682

New Duct Burners EU 360 12.0 1.5 29.0 6.0 6.0 6.0 10.3 122,541

New Equipment in Natural Gas Service

at CHP Facility FS 139 ‐‐  ‐‐ ‐‐  ‐‐  ‐‐  ‐‐  ‐‐ 40

Net Air Pollution Generation (tpy) 27.7 4.1 66.9 16.8 16.8 16.8 16.8 345,263

Mandatory EAW Trigger (tpy) 250 250 250 250 250 250 250 100,000

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 12 of 33 Is Net Air Pollution Generation > EAW Trigger? No No No No No No No Yes



## Therefore, the project triggers a mandatory EAW by exceeding the applicability threshold for CO 2 

## e

emissions.

Administrative SIP Order for SO 2 

## Emissions

FHR is one of 27 sources in Minnesota that has a site

‐ specific Administrative State Implementation Plan
(SIP) Order to achieve and maintain NAAQS. FHR’s SIP Order was originally adopted on April 2, 1991, for

the SO 2 

## NAAQS that were in effect at that time. The order was most recently amended on May 15, 2013
[78 F.R. 28501].

Part III of the current Order, titled “Changes Not Requiring a Modification of this Order”, describes new

and modified SO 2 

## emission units that may operate without a modification to the Order. Subpart A of this

Part, below, is relevant to the CHP facility:

“A. The Company may install and operate any new sulfur dioxide process or control equipment

with a maximum potential sulfur dioxide emissions rate that does not exceed 2.28 pounds per hour, except as expressly allowed elsewhere in this part (Part III.)”

The combustion turbine (EU359) and duct burners (EU360) will be restricted to firing only pipeline

natural gas as defined at 40 CFR Section 72.2, which results in an SO 2 

## PTE of 0.94 lb/hr, which is below

the 2.28 lb/hr threshold. Therefore, a modification to the Order is not required for the CHP facility

project pursuant to Part III, Subpart A, of the Order.

Subpart D, below, is also potentially relevant to the CHP facility:

“D. The Company may install and operate new structures, or modify and operate existing

structures if the new or modified structures do not increase the effective structural dimensions

assumed in the modeling presented in Exhibit 1.”

The CHP facility is sufficiently far from the existing refinery SO 2 

## sources included in the SIP modeling and

of a sufficiently low height that it is not expected to affect downwash from sources included in the SO 2 

## modeling analysis. Therefore, a modification to the Order is not required for the CHP facility project

pursuant to Part III, Subpart D, of the Order.

40 CFR pt. 60: New Source Performance Standards

Subpart KKKK applies to stationary combustion turbines that commence construction, modification or

reconstruction after February 18, 2005, and have a maximum heat input at peak load equal to or greater

than 10 mmBtu/hr based on HHV of the fuel. Since the heat input of the combustion turbine (EU359) is

greater than 10 mmBtu/hr, 40 CFR pt. 60, subp. KKKK is applicable. Also, as specified at 40 CFR Section
60.4305(a), 40 CFR pt. 60, subp. KKKK applies to the associated HRSG and duct burners (EU360).

40 CFR pt. 60, subp. KKKK establishes standards for NO X 

## and SO 2 

## and for NO X 

## , separate standards apply

for EU359 and EU360. The NO X 

## emission standards may be met on either a concentration or output

basis. For SO 2 

## the emission standard may be met on either an output or fuel content basis.

On September 20, 2013 EPA proposed a rule to establish NSPS for GHG emissions from power plants

under either a newly created 40 CFR pt. 60, subp. TTTT or existing subp. KKKK. The relevant proposed

standard is 1100 lb CO 2 

## /MWh, with a potential range of 1000 to 1200 lb CO 2 

## /MWh in the final rule. FHR

is proposing a BACT limit at the low end of this range of 1000 lb CO 2 

## /MWh. According to applicability

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 13 of 33 

## criteria currently proposed by EPA, the CHP facility would not be subject to this NSPS; however the CO 2 

## e

BACT emission limit is consistent with the standard being considered by EPA.

40 CFR pt. 63: National Emissions Standards for Hazardous Air Pollutants

The proposed CHP facility will use only air cooled condensers as discussed above. Open water is not
recirculated, thus 40 CFR pt. 63, subp. Q does not apply. The refinery is an existing source under 40 CFR

pt. 63, subp. CC. Unless the entire refinery undergoes reconstruction or a new process unit has HAPs PTE

greater than 10 tpy single or 25 tpy total HAPs, new source standards are not triggered. The CHP facility

does not trigger reconstruction and does not include a new process unit, therefore new source

standards under subp. CC do not apply.

40 CFR pt. 63, subp. YYYY establishes emission and operating limitations for HAPs from stationary

combustion turbines at major HAP sources. As established at 40 CFR Section 63.6095(d), EPA has stayed

all requirements other than the initial notification requirement for gas fired subcategories under subp.

YYYY. Since EU359 is a lean premix gas fired stationary combustion turbine and is not capable of firing

fuel oil, compliance with the other requirements of 40 CFR pt. 63, subp. YYYY are not required. FHR need
only comply with the initial notification requirements of 40 CFR pt. 63, subp. YYYY.

40 CFR pt. 64: Compliance Assurance Monitoring

The combustion turbine (EU359) and duct burners (EU360) are subject to emission limits or standards

and include new control devices. The emissions from both units were combined for purposes of

comparing them to CAM applicability. Pre control PTE is above 100 tpy for NO X 

## and CO and post control

PTE is below 100 tpy. Thus, the CHP facility project emission units qualify as other PSEU for NO X 

## and CO

in accordance with 40 CFR Section 64.5(b). Currently, no CAM plan is required until the next Title V

permit renewal application. The CHP facility will use NO X 

## and CO CEMS to meet the requirements of 40

CFR Section 64.3(d)(1).

40 CFR pt. 72: Acid Rain Program

Cogeneration facilities that supply less than one

‐ third its potential electrical output capacity to a utility

power distribution system for sale are not affected units and not subject to the requirements of the Acid

Rain Program. The Combined Heat and Power Cogeneration project will not sell any electricity using a utility power distribution system and thus, through 40 CFR Section 72.6(b)(4)(ii), it is not subject to the

Acid Rain Program.

Best Available Control Technology (BACT) Analysis

As part of the CHP Permit application, FHR included a BACT analysis for PM 10 

## , PM 2.5 

## and GHG. The

emissions increases for these pollutants were above the significant emission rate (SER) for these
pollutants. FHR followed the top

‐ down approach for BACT which includes the steps shown below.

1. Identify All Available Control Technologies;

2. Eliminate Technically Infeasible Options;

3. Rank Remaining Control Technologies by Control Effectiveness;

4. Evaluate Most Effective Control Technologies and Document Result; and

5. Select Best Available Control Technology (BACT)

For the PM 10 

## and PM 2.5 

## BACT analysis, FHR consulted the following sources: EPA’s RACT/BACT/LAER

Clearinghouse (RBLC), EPA’s Clean Air Technology Center (CATC) website, South Coast Air Quality

Management District’s BACT Guidelines including LAER/BACT determinations for both major and non

‐

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 14 of 33 

## major polluting facilities, Bay Area Air Quality Management District’s BACT Guidelines specifically PM 10 

## BACT determinations for combined

‐ cycle gas turbines > 40 MW, and other EPA and state air quality

permits.

For the GHG BACT analysis, FHR followed EPA’s guidance document “PSD and Title V Permitting

Guidance for Greenhouse Gases” (EPA

‐ 457/B

‐ 11

‐ 001, March 2011). FHR also consulted the following

additional sources: EPA’s Clean Air Act Advisory Committee (CAAAC) website, U.S. Department of Energy (DOE)/ National Energy Technology Laboratory (NETL) websites, EPA’s RACT/BACT/LAER Clearinghouse
(RBLC), EPA’s proposed Standards of Performance for Greenhouse Gas Emissions from New Stationary

Sources: Electric Utility Generating Units, EPA white paper from October 2010 titled, “Available and

Emerging Technologies for Reducing Greenhouse Gas Emission from Industrial, Commercial, and

Institutional Boilers”, Massachusetts Institute of Technology’s website for carbon capture and storage technologies, and other EPA and state air quality permits.

PM 10 

## /PM 2.5 

## BACT for Combustion Turbine and Duct Burners

FHR selected good combustion practices and natural gas fuel use meeting the definition of pipeline

natural gas at 40 CFR Section 72.2 as BACT for the combustion turbine (EU359) and duct burners
(EU360). Good combustion practices involve proper design of the combustors and burners, maintenance

in accordance with good engineering practices and filtration of the inlet air. This is consistent with

previous BACT determinations for PM 10 

## and PM 2.5 

## at similar sources and also consistent with the Bay

Area Air Quality Management District’s BACT guidelines for combined

‐ cycle power plants.

The turbine manufacturer expects to guarantee a total PM emission rate of 4.0 lb/hr, including filterable

and condensable fractions. Table 3.1

‐ 2a of AP

‐ 42 lists a total PM emission factor for natural gas turbines

of 0.0066 lb/mmBtu. Performance test data (see Attachment 2) shows that a GE LM6000 turbine can

achieve PM 10 

## and PM 2.5 

## emission rates lower than 0.0066 lb/mmBtu. FHR reviewed 42 performance test

results for LM6000 PM 10 

## and PM 2.5 

## emissions, performed a statistical analysis and added three standard

deviations to the mean to arrive at a proposed BACT limit of 0.0057 lb/mmBtu. Using the heat input

capacities of the turbine (435 mmBtu) and duct burners (239 mmBtu), FHR calculated a lb/hr limit for

PM 10 

## and PM 2.5 

## of 3.8 lb/hr.

Add

‐ on control including baghouses, electrostatic precipitators or wet scrubbers can provide particulate

control for solid and liquid fuel combustion applications for filterable PM but are not technically feasible

for natural gas combustion emissions. These add

‐ on controls achieve post control PM limits from 0.0020

to 0.0050 gr/dscf based on limits in the RBLC database. The proposed PM 10 

## and PM 2.5 

## BACT limits of

0.0057 lb/mmBtu translate close to 0.0020 gr/dscf without the use of add

‐ on controls. Thus the
proposed BACT limit is similar or nearly equivalent to the most stringent BACT limits for add

‐ on control

from the RBLC. In addition, the particulate emissions from natural gas combustion are primarily
expected to be condensable PM and unable to be controlled by a baghouse, ESP or other add

‐ on

control. For these reasons add

‐ on controls for particulate are not technically feasible for the combustion

turbine and duct burners.

GHG BACT for Combustion Turbine and Duct Burners

FHR selected use of natural gas and implementation of technically feasible design and operational

energy efficiency measures as BACT. Carbon Capture and Sequestration (CCS) is not a currently available

or technically feasible control technology for GHG from the proposed combustion turbine and duct

burners, but it was carried through the 5

‐ step process on a voluntary basis. FHR estimated the capital

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 15 of 33 

## investment to install CCS control technology at $387.8 million. This is more than the cost of the project

itself (~$125

‐ $150 million) showing that CCS as a control option for BACT is economically infeasible.

FHR proposes a BACT limit of 1000 lb CO 2 

## e/MWh gross output. EPA has proposed a New Source

Performance Standard of 1100 lb/MWh gross output based on a 12

‐ month rolling average for turbines

with heat input between 250 and 850 mmBtu/hr. The design heat input of the turbine proposed at FHR

falls within this range. EPA also requested comments on setting the standard between 1000 and 1200 lb

CO 2 

## e/MWh. Accordingly, the proposed BACT limit is lower than the NSPS proposed by EPA and at the

low end of the range being considered by EPA.

GHG BACT for Natural Gas Equipment Leaks

Various new components (e.g. valves, pumps and/or flanges) in natural gas service will be installed with

the CHP cogeneration facility. These equipment will be represented as FS139. FHR proposes to adhere to

its enhanced leak detection and repair (LDAR) standards under groups 087, 090, 091, 093, 101 and 114

as BACT. FS139 will be added as an associated item to GP132 which references the LDAR groups above

as compliance methods with the proposed BACT. FHR will operate in compliance with the combined

LDAR program provisions in the permit which reflect the requirements of the Consent Decree and meet

the requirements of 40 CFR pt. 60, subp. GGGa.

PSD Additional Impacts Analysis

In accordance with 40 CFR Section 52.21(o), FHR prepared an additional impacts analysis examining the
potential for impairment to visibility, soils and vegetation that may occur as a result of the project and

any general commercial, residential, industrial and other growth associated with the project. This
analysis concluded that there will be no appreciable commercial, residential, industrial or other growth

due to the project, and hence, no impact to air quality in the area. Further, it was concluded that air

emissions from the project will not adversely affect ambient air quality, soils and vegetation, or visibility.

Endangered Species Act

The Endangered Species Act (ESA) submittal to EPA Region V was forwarded to U.S. Fish and Wildlife

Service (Service) on May 13, 2014. The Service responded that no records indicate any listed species

within the three kilometer action area for the proposed project. However, the Mississippi River is within

the action area and Higgins eye ( Lampsilis higginsii ) and sheepnose ( Plethobasus cyphyus ) may be

present in the river within reasonable distance downstream of the action area. Because of this, FHR and

USEPA considered the possibility that some pollutants could be deposited in the Mississippi River and
transported downstream to where Higgins eye and sheepnose may be present, but results from

calculated ecological screening quotients indicated no adverse effects to ecological receptors. The

Service concurred that the proposed permit may affect, but will not likely adversely affect Higgins eye or sheepnose downstream of the action area in a letter dated August 7, 2014 (see Attachment 5).

National Historic Preservation Act

The National Historic Preservation Act (NHPA) submittal to EPA Region V was forwarded to the State

Historic Preservation Office (SHPO) on April 17, 2014, with EPA’s recommendation that the proposed

CHP project will have no adverse effect on any listed or eligible historic properties. SHPO agreed with

EPA’s recommendation in a letter dated May 7, 2014 (see Attachment 6).

Major Amendment for Tier 3 Clean Fuels Projects (DQ 4761)

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 16 of 33 

## The ammonium thiosulfate (ATS) process unit project consists of three primary components: (1)

construction of a new ATS process unit (EU361) (2) switching the amine solution to improve H 2 

## S capture efficiency and (3) installation of replacement sour water skimmers and tanks.

New ATS Process Unit (EU361)

The planned configuration to produce ATS is a unique two

‐ stage process that manufactures aqueous

ATS solution containing approximately 40% water and 60% ammonium thiosulfate salt. In the first stage,

a sour water steam stripping process will be installed that separates ammonia (NH 3 

## ) and hydrogen

sulfide (H 2 

## S) from sour water streams that are generated by refinery process units used to produce low

sulfur gasoline. There are two steps in the sour water stripping process. The first involves the separation

of NH 3 

## and H 2 

## S and the second involves the reaction/recombination of NH 3 

## and H 2 

## S to form ATS.

In the second stage of ATS production, EU361 will use a multistage absorption process to convert NH 3 

## and H 2 

## S from the new sour water stripper to produce the final ATS product. A burner in the EU361

combustion chamber and any unconverted SO 2 

## and NH 3 

## from the reactor will be the main source of air

emissions from the process. The natural gas fired burner only operates during start

‐ up (expected to last

less than 8 hours per event), and converts H 2 

## S to SO 2 

## during normal operations. Over 99.9% of SO 2 

## generated from H 2 

## S oxidation will be recovered and used in the reaction to produce ATS solution.

While the nitrogen from the NH 3 

## feed stream is converted to fertilizer in the ATS process, the oxidation

process will generate some NO X 

## and other products of combustion. Due to potential formation of salts

and sulfuric acid mist, the final absorption column will be equipped with a demister filter system controlling particulate and acid mist emissions generated by the process. The design will also include a

heat recovery boiler downstream of the oxidation chamber generating refinery process steam. Because

of this along with energy efficiency built into the project through a change in amine chemistry (discussed
below), no other increase in steam production or boiler utilization is required. With the exception of
fugitive equipment, no additional emission units are included as part of the sour water stripping process. Design will include good engineering practices to reduce emissions during unplanned malfunctions of

EU361, including a diversion line upstream of EU361 so that the stripper off gases can be processed in

the existing sulfur recovery units (SRUs).

Two existing 117,000 gallon tanks will be used as day tank storage for ATS product, qualifying as insignificant activities under Minn. R. 7007.1300, subp. 3.I. Additionally, new ATS product storage tanks

will be constructed on the property at the southeast corner of the intersection of Highways 52 and 55.

The current estimate of tankage needs, excluding the day tank storage noted above, is two new tanks
(with a design capacity of approximately 2.8 million gallons each) in addition to using two existing tanks

at that location (with a design capacity of approximately 1 million gallons each) to store the ATS solution
produced at EU361. An alternative design is also under consideration which would not utilize the

existing tanks; instead, the proposed two new tanks would be enlarged to contain the entire required
design capacity of approximately 4 million gallons each. Since ATS is neither a VOC nor HAP there are no

emissions or applicable air quality regulations associated with transfer, storage or loadout of the ATS
product.

ATS liquid has a low National Fire Protection Association (NFPA) rating for fire hazard and reactivity in

comparison to other nitrogen based agricultural fertilizers. FHR’s ATS solution is expected to have

similar properties and NFPA ratings. ATS helps increase agricultural yields by satisfying crops’ need for

both nitrogen and sulfur. ATS supplies crops with sulfur which improves yields and quality by improving

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 17 of 33 

## soil structure, increasing water infiltration, aiding the breakdown of previous crop residues and
enhancing nitrogen use by the plant.

Amine Efficiency Project

FHR operates a number of amine units that use amine solution to capture and transfer H 2 

## S from the gas

oil hydrotreaters and other process units, which reduces sulfur in refinery fuel gas and other process

streams.

In gas oil hydrotreating, hydrogen gas is consumed by reaction with sulfur in the gas oil to produce H 2 

## S

and other impurities. The recovered gas is sent to an amine contactor where the amine solution is used

to remove H 2 

## S and other impurities before it is compressed and returned to the hydrotreaters. The H 2 

## S

rich amine solution is then stripped by steam in the amine regeneration units recovering H 2 

## S for

processing in the existing SRUs and the new EU361. Although the H 2 

## S is removed, virtually no amine is

lost in the refinery units or the amine regenerator while it circulates through the system. The
regenerated amine is recirculated back to the refinery contactors to bring additional H 2 

## S to the amine

unit on a continuous basis.

FHR plans to switch the amine solution in the amine units from monoethanolamine (MEA) to diglycolamine (DGA), which is intended to improve the efficiency and level of removal of sulfur

containing substances from process streams. DGA has been shown to be more effective in recovering

H 2 

## S and other reduced sulfur compounds with lower steam input needed. Thus, additional sulfur will be

removed from fuels and refinery intermediates in a more efficient manner.

Sour Water Skimmers and Tanks Improvements Project

FHR generates process water containing H 2 

## S, NH 3 

## and VOC, referred to as “sour water” by the fuel

desulfurization process. FHR utilizes skimmers to separate oil from the sour water and dedicated storage

tanks to store and manage inventories of sour water. Skimmed sour water is transferred to the sour

water strippers where the H 2 

## S, NH 3 

## and other impurities are removed from the sour water prior to reuse

of the water.

The sour water project involves replacing the existing sour water skimmers and storage tanks. Both will

be sized larger than the existing units to improve retention time and separation. This equipment is
planned to be installed away from the center of the existing process units, applying industry best

practices to minimize process safety risk. The three storage tanks (TKs 586

‐ 588) will have external
floating roofs and a layer of sponge oil (diesel fuel or similar) to control air emissions. If the ATS project

is approved and constructed, one of the sour water skimmers and one sour water storage tank will be

used primarily for process feed to EU361, but would be built regardless of the installation of EU361.

Additional Air Quality Regulatory Applicability Documentation

EAW Trigger for Storage Facilities

The following mandatory EAW trigger is described at Minn. R. 4410.4300, subp. 10:

“Subp. 10. Storage facilities. Items A to C designate the RGU for the type of project listed:

A. For construction of a facility designed for or capable of storing more than 7,500 tons of coal or

with an annual throughput of more than 125,000 tons of coal; or the expansion of an existing
facility by these respective amounts, the PCA shall be the RGU.

B. For construction of a facility on a single site designed for or capable of storing 1,000,000
gallons or more of hazardous materials, the PCA shall be the RGU.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 18 of 33 

## C. For construction of a facility designed for or capable of storing on a single site 100,000 gallons

or more of liquefied natural gas, synthetic gas, or anhydrous ammonia, the PCA shall be the

RGU.”

The Sour Water Skimmers and Tanks Improvements Project includes construction of a storage facility
designed for or capable of storing more than 1 million gallons of sour water. Sour water is considered a

hazardous material because it has the potential to contain low levels of chemicals that are hazardous air
pollutants (benzene and H 2 

## S) and hazardous materials as classified by the Dept. of Transportation. Also,

the ATS Process Unit Project includes construction of a storage facility designed for or capable of storing

more than 1 million gallons of ATS, although ATS is not considered a hazardous material and would not
trigger EAW requirements. An EAW was not triggered as a result of the emissions increases associated

with this project. The emissions generation increases due to these projects are calculated as the sum of

the PTE of the new and existing units:

 New ATS process unit (EU361)

 New sour water tanks (TK586, TK587, TK588)

 New equipment in VOC, GHG and H 2 

## S service (FS140, including new equipment at FS052, FS095,
FS117)

 New haul road truck traffic (IA060)

 Existing SRUs 26 (EU045, EU047) and 45 Units (EU111, EU112, EU113, EU114) for PM emissions

Affected non

‐ modified units emissions are not included in this list because the PTE will not change as a

result of the Tier 3 Clean Fuels Project.

Table 8. Change in Air Pollution Generation for EAW Applicability (tpy)

Emission Unit MPCA ID NO X 

### SO 2 

### CO PM PM 10 

### PM 2.5 

### VOC CO 2 

### e

ATS Process Unit EU 361 33.53 19.71 7.60 2.11 5.89 5.89 1.97 32,994

Sour Water Tanks TK 586

‐ 588 ‐‐  ‐‐  ‐‐  ‐‐  ‐‐  ‐‐ 28.00 ‐‐

New Equipment at ATS Process Unit FS 140 ‐‐  ‐‐ ‐‐  ‐‐  ‐‐  ‐‐ 0.82 23

New Equipment at FS 052 FS 052 ‐‐  ‐‐  ‐‐  ‐‐  ‐‐  ‐‐ 1.12 28

New Equipment at FS 095 FS 095 ‐‐  ‐‐  ‐‐  ‐‐  ‐‐  ‐‐ 1.12 28

New Equipment at FS 117 FS 117 ‐‐  ‐‐  ‐‐  ‐‐  ‐‐  ‐‐ 1.92 48

26 Unit Sulfur Recovery Unit EU 045

EU 047 ‐‐  ‐‐  ‐‐ 0.60 0.60 0.60 ‐‐  ‐‐

45 Unit Sulfur Recovery Unit EU 111

‐ 114 ‐‐  ‐‐  ‐‐ 0.60 0.60 0.60 ‐‐  ‐‐

New Haul Road Truck Traffic IA 060 ‐‐  ‐‐  ‐‐ 7.23 1.45 0.35 ‐‐  ‐‐

Net Air Pollution Generation (tpy) 33.53 19.71 7.60 10.53 8.53 7.44 34.96 33,121

Mandatory EAW Trigger (tpy) 250 250 250 250 250 250 250 100,000

Is Net Air Pollution Generation > EAW Trigger? No No No No No No No No



## Administrative SIP Order for SO 2 

## Emissions

Part III of the current Order, titled “Changes Not Requiring a Modification of this Order”, describes new

and modified SO 2 

## emission units that may operate without a modification to the Order. Subpart A of this

Part, below, is relevant to the Tier 3 Clean Fuels Projects permit:

“A. The Company may install and operate any new sulfur dioxide process or control equipment

with a maximum potential sulfur dioxide emissions rate that does not exceed 2.28 pounds per hour, except as expressly allowed elsewhere in this part (Part III.)

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 19 of 33 

## The Company may modify and operate any existing sulfur dioxide process or control equipment

to increase the sulfur dioxide emission rate up to 2.28 lb/hr over the modeled emission rate for

that source in Exhibit 1.”

Exhibit 1 referenced in Part III Subpart A includes a list of each of the SO 2 

## modeled emission units by

individual stack. The proposed stack for the ATS process unit (SV190) has a potential emissions rate that

exceeds 2.28 lb/hr SO 2



## . A modification to the Order is required for this project pursuant to Part III,
Subpart A, of the Order.

Fuel Gas Sulfur Content CMS and SO 2 

## CEMS Monitoring

As part of the SO 2 

## SIP modification being processed concurrently with this permit action, hydrogen

sulfide (H 2 

## S) monitoring requirements that are an artifact of historic permitting are being removed from

the SO 2 

## maintenance SIP. H 2 

## S monitoring continues to be required in the Title V permit for compliance

demonstration under 40 CFR pt. 60, subps. J and Ja. FHR has implemented a more robust monitoring

strategy (a combination of refinery fuel gas reduced sulfur CEMS and heater stack SO 2 

## CEMS) for the

purpose of quantifying SO 2 

## emissions from fuel gas fired sources. This monitoring approach accounts for

additional sulfur compounds beyond H 2 

## S; historically H 2 

## S was solely used to calculate SO 2 

## emissions for

the SO 2 

## maintenance SIP. This monitoring improvement was proposed and approved with permit action

‐ 008 in 2011 and SIP Amendment 8 in 2010.

Similar to the previously approved monitoring for the 41 Unit mix drum, FHR incorporated into its Title V

permit (but not the SIP) the option to use fuel gas total sulfur CEMS for the 45 Unit mix drum as an

alternative to the existing heater stack SO 2 

## monitoring. The 2013 permit amendment sought this option

to ensure the precision of the monitoring strategy as the refinery implements a fuel gas sulfur reduction

project in 2015. The refinery will continue to use the existing stack SO 2 

## CEMS for SIP compliance until

the SIP with this monitoring alternative is approved.

Hydrocarbon Flare System

FHR proposes to update the existing flare language in the SO 2 

## maintenance SIP to include more

restrictive language that is consistent with FHR’s actual operation and management of the hydrocarbon

flare systems. The proposed language confirms that the flares are intended to be used during unplanned

and infrequent events (i.e., malfunctions), and that gases resulting from refinery operations, including

gases from scheduled startups and shutdowns of refinery process units, are not flared except during
unplanned and infrequent events.

Adding SO 2 

## SIP Limits to Title V Permit

Sulfur dioxide SIP limits that are not already in the Flint Hills Title V permit will be added in this permit

action. The SO 2 

## SIP limits are in tabular form in Appendix C of the permit and will be added to Table A of

the permit. Those limits added in this permit action are shown in Table 9 below:

Table 9. Sulfur Dioxide (SO 2 

## ) State Implementation Plan (SIP) Limits Added to Permit

Location * 1

‐ hr Rate (lb/hr) 3

‐ hr Rate (lb/hr) 24

‐ hr Rate (lb/hr) Annual Rate
(tpy)

EU228 ‐‐  ‐‐ 182.6

‐‐
SV066 6.8 6.8 6.8 16.0

EU026 7.3 ‐‐ ‐‐ ‐‐
EU016 6.3 6.3 6.3 15.0

EU084 13.4 ‐‐ ‐‐ ‐‐

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 20 of 33 EU019 10.0 10.0 10.0 23.7

EU005 6.8 ‐‐ ‐‐ ‐‐
SV082 6.9 6.9 6.9 24.3

EU085 9.9 9.9 9.9 34.8

EU006 2.4 2.4 2.4 5.7

EU028 5.6 ‐‐ ‐‐ ‐‐
EU030 5.6 ‐‐ ‐‐ ‐‐ EU241/EU240 14.1 14.1 14.1 49.4

EU034 12.7 ‐‐ ‐‐ ‐‐
EU054 1.0 1.0 1.0 2.3

EU055 66.4 ‐‐ 66.4

‐‐
EU057 0.4 0.4 0.4 1.0

EU061 1.3 1.3 1.3 3.0
EU077/EU076 0.4 0.4 0.4 0.9

SV083 30.1 30.1 30.1 105.6

EU102 2.9 2.9 2.9 10.3

EU103 2.9 2.9 2.9 10.3

EU104 4.8 4.8 4.8 16.8

EU040 19.5 19.5 19.5 68.4

EU041 17.5 17.5 17.5 61.4

EU324 12.6 12.6 12.6 44.1

EU035 9.4 9.4 9.4 13.4

EU052 61.7 61.7 61.7 216.3

EU050 6.5 6.5 6.5 22.7

EU051 7.3 7.3 7.3 25.7

EU056 3.0 3.0 3.0 7.1

EU058 2.9 2.9 2.9 6.8

EU059 1.6 1.6 1.6 3.9

EU060 2.1 2.1 2.1 5.0

EU053 2.6 2.6 2.6 9.2

EU204 14.3 14.3 14.3 50.0

EU213 36.6 36.6 36.6 128.4

EU212 16.5 16.5 16.5 39.0

EU313 9.9 9.9 9.9 23.5

EU296 69.4 69.4 69.4 243.3

SV165 17.0 17.0 17.0 59.5

EU126 5.1 5.1 5.1 12.0

SV094 1.6 1.6 1.6 4.5

EU131 (GP011) 0.002 0.002 0.002 0.009

EU129 (GP011) 0.004 0.004 0.004 0.02

EU312 (GP011) 0.016 0.016 0.016 0.07

EU007, EU024,

EU036, EU042,

EU100, EU128,

EU130, EU132,

EU198, EU199
(GP011) 0.008 0.008 0.008 0.04

EU282 50.7 ‐‐ ‐‐ ‐‐
EU127 0.008 0.008 0.008 0.04

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 21 of 33 EU032 8.0 8.0 8.0 1.73

EU033 8.0 8.0 8.0 1.73
EU037/EU038 20.2 20.2 20.2 4.36

*: The order in which equipment is listed in Appendix C



## Other Title V Permit Changes

The bypass stack requirement under “Other Requirements” for SV042 (decommissioned) was removed

from the permit. The SO 2 

## SIP citation at MR069 was updated to match other SIP condition citations
throughout the permit. Requirements for the Merox Incinerator (EU245) and Boiler No. 10 (EU337) were

removed. Fuel gas that was previously combusted at EU245 was rerouted to EU055 and EU245 was subsequently shut down and taken out of commission. EU337 was initially included in modeling and

given permit requirements but was never constructed at the facility. The two monitors MR071 (EMRC

Temperature Thermocouple for 34H

‐ 3) and MR147 (34H3 Flow Meter for Exhaust Gases) on EU245 were

also removed. CM056 was removed and MR103 was incorrectly associated with this continuous

monitoring system. The Merox Incinerator, Boiler No. 10 and Wood River engine were removed from

the permit. The 45H6 stack (SV094, EU111, EU113, EU260), 23H3 (EU352), 25H2 (EU353), CHP unit
(EU359, EU360) and ATS Process Unit (EU361) will be added to the table of SO 2 

## modeling parameters (permit Appendix C). EU062, EU109, CE013, SV021, SV078 and SV180 were all removed and

disassociated with all equipment.

With the removal of EU245, the off gas was rerouted to EU055 (see detailed discussion in PER008 TSD).

As a result of this, CM055 is renamed ‘31H2: 66.4 lbs SO2/hr (3

‐ hr avg) EU 055’ (formerly ‘Merox Off Gas

Inc.: 230 lbs SO2/hr (3

‐ hr ave.) EU 245’). Also, MR144 is a monitor for 94H3 and was incorrectly

associated with CM055. MR144 will be disassociated with CM055.

All SIP for SO 2 

## requirements will have their citation changed to: “Title I Condition: 40 CFR Section 50.4,

SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y”

40 CFR pt. 60 New Source Performance Standards

40 CFR pt. 60, subp. Ja

The ATS process unit (EU361) will recover ATS from H 2 

## S and SO 2 

## from a source of sour gas produced at

the refinery. 40 CFR pt. 60, subp. Ja does not define whether sulfur refers to elemental sulfur or compounds which contain sulfur. EPA noted considering non

‐ Claus sulfur recovery unit technologies in

the preamble to the proposed rulemaking for NSPS subp. Ja. They also provided clarification that sulfur

refers to compounds containing sulfur in the Summary of Public Comments and Responses from 2008.

Given this information, EU361 meets the definition of a Sulfur Recovery Plant (SRP) because it is a

process unit that recovers sulfur (as ATS) from a source of sour gas produced at the refinery.

Under 40 CFR Section 60.101a, a sulfur recovery plant means all process units which recover sulfur from

H 2 

## S and/or SO 2 

## from a common source of sour gas produced at a petroleum refinery. Since the ATS

process will share the same source of clean acid gas with the existing SRUs as a source of H 2 

## S, the
proposed ATS process unit will be considered part of the same SRP as the existing SRUs.

The existing SRUs are not currently subject to NSPS subp. Ja. The term “modification” is defined at 40

CFR Section 60.14(a). NSPS subp. Ja regulates SO 2 

## emissions at an SRP. The maximum hourly SO 2 

## emission rate is not expected to change from installation of EU361. However, the maximum hourly SO 2 

## emission rate from the entire SRP (including EU361) will increase because of the addition of EU361 to

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 22 of 33 

## the SRP. Thus, the SRP as a whole will undergo a modification and be subject to NSPS subp. Ja following

the ATS Process Unit Project.

The emissions limit will be applicable to the entire SRP (existing SRUs and EU361) and the associated

emission points. NSPS subp. Ja has multiple emissions limits for an SRP depending on capacity and

whether the system includes oxygen enrichment. The SRP capacity is greater than 20 long tons per day
(LTD) and the #4 and #5 SRU process trains have the capability to use oxygen enrichment. The SRP will

thus be subject to the SO 2 

## limit (E LS 

## ) dependent upon the level of oxygen enrichment used according to
Equation 1 from NSPS subp. Ja, corrected to zero percent oxygen at the exhaust and based on a 12

‐ hour
rolling average:

E LS 

## (ppmv at 0% O 2 

## ) = ‐ 0.038 x (%O 2 

## ) 2 

## + 11.53 x %O 2 

## + 25.6 40 CFR Section 60.102a(f)(1)(iii)

The emissions limit calculated for systems not using oxygen enrichment (operating at 20.9% O 2 

## ) using

the equation above equals 250 ppmv. Emissions will be monitored using CEMS for SO 2 

## (MR211) and O 2 

## (MR212) as required by 40 CFR Section 60.106a(a)(1).

Each SRU at the refinery is subject to the emissions limit of 250 ppmv at 0% O 2 

## under 40 CFR pt. 63,
subp. UUU. Thus, the default O 2 

## content of 20.9% will be used at all times for purposes of compliance

demonstration. Root cause and corrective action analyses are required each time there are SO 2 

## emissions in excess of 500 lbs during any 24

‐ hour period. Corrective action analyses requirements are

described in 40 CFR Section 60.103a. The initial performance test for the SRP will be required after

startup of EU361. This test will include the existing SRU stacks and the new SV190 assigned to EU361.

40 CFR pt. 60, subp. Kb

The new sour water tanks (TKs 586

‐ 588) will have a storage capacity greater than 15,000 cubic meters

and maximum true vapor pressure of 34.5 kilopascal (kPa). Thus, these storage tanks will be subject to

40 CFR pt. 60, subp. Kb. FHR will comply with 40 CFR pt. 60, subp. Kb by installing external floating roofs

on each new sour water tank. A closed vent system and control device is not required because the true

vapor pressure is less than 76.6 kPa. Storage of ATS is not regulated under 40 CFR pt. 60, subp. Kb

because ATS is not considered a volatile organic liquid.

40 CFR pt. 60, subp. GGGa

All refinery process units are already subject to 40 CFR pt. 60, subp. GGGa. FHR accepted subp. GGGa
applicability with air emission permit no. 03700011

‐ 005 issued August 19, 2008. The new VOC

equipment installed with the Tier 3 Clean Fuels Projects permit will also be subject to subp. GGGa.

40 CFR pt. 60, subp. QQQ

At the site of EU361, all existing individual drain systems are currently subject to 40 CFR pt. 60, subp.

QQQ. All new drains and junction boxes will be subject to 40 CFR pt. 60, subp. QQQ. FHR will comply

with the requirements for all individual drain systems affected by the projects and the aggregate facility

associated with the site of EU361.

Reopenings (DQ# 4404, 4405, 4800, 4812, 4813, 4818, 4854, 4855, 4947)

DQ# 4404: A reopening of EU104 (38H

‐ 2) to set a heat input limit to less than or equal to 56.0
mmBtu/hr. This limit was already in the permit.

DQ# 4405: A reopening of EU085 (33H

‐ 32) to set a heat input limit to less than or equal to 107.8
mmBtu/hr. This limit was already in the permit.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 23 of 33 

## DQ# 4800: A reopening of EU102 (38H

‐ 1A) and EU103 (38H

‐ 1B) will update the heat input limits to less

than or equal to 30.7 mmBtu/hr and 28.9 mmBtu/hr, respectively. The maximum oxygen concentration

operating limit for EU103 is also being updated to less than or equal to 4.90%. These updates are based

on results of a performance test conducted April 9

‐ 10, 2014.

DQ# 4812 and 4854: A reopening of EU056 (31H

‐ 4) will update the heat input limit to less than or equal

to 43.1 mmBtu/hr based on results of a performance test conducted February 5, 2014. Test frequency is

every 36 months from February 5, 2014.

DQ# 4813 and 4855: A reopening of EU035 (23H

‐ 2) will update the heat input limit to less than or equal

to 108.4 mmBtu/hr based on results of a performance test conducted November 21, 2013. Test
frequency is every 60 months from November 21, 2013.

DQ# 4818: A reopening of EU005 (11H

‐ 1) will set the performance test frequency at 60 months from the

date of the test. The next performance test will be due on or before June 27, 2018.

DQ# 4947: A reopening of SV066 (32H

‐ 5/6/7) will update the heat input limit to less than or equal to

117.6 mmBtu/hr. This update is based on results of a performance test conducted June 10, 2014. The

testing schedule will revert back to the original due date of March 3 with the next test due on or before

March 3, 2017.

There is one additional change for EU213 (27H501) that did not include a DQ number. This change will
update the heat input limit to less than or equal to 449.5 mmBtu/hr. This update is based on the results

of a PM 10 

## performance test conducted on January 17, 2012. The previous limit was based on a VOC data

submittal engineering test conducted on November 2, 2006; however, data submittal engineering tests

are not required to maintain compliance with heat input limits set by Minn. R. 7017.2025 per Minn. R.

7017.2001.

Expired SO 2 

## SIP Limits

New limits for SO 2 

## SIP became effective upon EPA’s approval of Amendment 9 to FHR’s SIP [78 FR
28501]. The expired limits were removed from the permit at EU005, EU026, EU028 and EU030 and the

trigger language for the effective limits was removed.

Removing Items from Removed GP043

GP043 was removed during permit action 009 but still had listed associated items within the group.

There were no conditions in GP043 so there was no reference to the group in Table A of the permit.

However, the facility description had the listed associated items and the group shown as removed. This

permit action removed the associated items in the facility description from GP043.

Additional Changes to Title V Permit

Requirements to submit and comply with a Fugitive Emissions Control Plan for the haul roads at the ATS

Storage Terminal location have been added to the total facility level of the permit in lieu of modeling the
paved roads, which is consistent with the MPCA’s paved road guidance. Submittal of the plan is due 60
days after permit issuance and the plan will become effective upon startup of the ATS Storage Terminal.

Requirements of GP012 (Portable Diesel Engines) were moved to the total facility level in the permit and

contain the label “(Portable Diesel Engines)”. These engines were not represented by EU numbers and

their PTE which was located at GP012 in the facility description will be temporarily relocated to EU362
(Portable Diesel Engines) until a permanent location can be decided after Tempo replaces Delta.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 24 of 33 

## GP005, GP129 and GP130 were PTE placeholder groups for VOC fugitive emissions, GHG tank emissions

and GHG fugitive emissions, respectively. These emissions will be temporarily relocated to FS141 and

TK589 before a permanent fix placing the individual FS and TK PTE in the facility description during a

future permit action. Each placeholder group will be removed.

The Storage Tank Recordkeeping requirement at the total facility level has been removed. Tank group requirements are being consolidated with this permit action. The following changes are being made:

associated tanks and requirements of GP038 are moving to GP039; associated tanks and requirements

of GP008 are moving to GP019; associated tanks and requirements of GP025 are moving to GP034; and,

associated tanks and requirements of GP027 are moving to GP026. GPs 008, 025, 027 and 038 are being

removed and references to these groups at GP010 are being removed and replaced with the GP

reference of the GP that their requirements are being moved to as listed above. Minor updates have

been made to reference tank vapor pressure applicability consistent with 40 CFR pt. 60, subp. Kb at GPs

019, 026, 034 and 039.

During Title V reissuance (permit action ‐ 009) MR033 and MR165 were identified as identical equipment

in the permit. MR165 was removed and MR033 was kept. Permit requirements for MR033 are being

added in this permit action. MR033 is an O 2 

## monitor on the 25H3 stack (SV038) and allows the measured

SO 2 

## concentration to be adjusted to an O 2 

## % free basis. In the facility description, GP116 is being added

as an associated item to MR033.

The quarterly reporting requirement for portable diesel engines at the FC level is being revised to state

that reports are due 30 days after the end of each calendar quarter. The same revision is being made to

the Relative Accuracy Test Audit (RATA) Results Summary requirement for SV094. This summary is due

30 days after the end of each calendar quarter following a CEMS RATA. Excess Emissions/Downtime

Reports (EERs) reports for EU040, GP009 and GP011 are being revised to be due 30 days after each

quarter following an EER.

Typographical corrections are being made to the NO X 

## and CO performance test requirements for EU053.

The associated stack with EU053 is SV047. The performance test requirements mistakenly associate

SV046 with EU053.

Prior to 2005, FHR maintained an O 2 

## CEMS used to correlate NO X 

## and CO emissions via periodic
performance testing. On April 27, 2005 FHR certified a NO X 

## and CO CEMS and removed the correlation.

FHR has since removed the performance testing requirements from the permit and in this permit action

will remove the two monitoring requirements for NO X 

## and CO at EU041.

Table 8 to 40 CFR pt. 63, subp. ZZZZ details the applicable general provisions that diesel engines must compile. Table 8 states the general provisions of 40 CFR Section 63.6(e) do not apply, thus maintaining a Startup, Shutdown, Malfunction Plan (SSMP) document does not apply. The requirements to record,

maintain and update an SSMP will be removed from EU312 and GP127.

Corrections from Permit No. 03700011

‐ 010

During the initial design for EU352 (23H3) FHR expected that forced draft and induced draft would be
required for SCR control. Accordingly, the current permit reflects NO X 

## limits from NSPS subp. Ja for a

forced draft heater. In engineering work done since the time PER010 was issued, FHR determined that

EU352 only requires an induced draft fan and does not need a forced draft fan. Thus, EU352 will have a

natural draft design and be subject to lower NO X 

## limits from 40 CFR pt. 60, subp. Ja.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 25 of 33 

## FHR is also proposing clarification to monitoring and recordkeeping requirements for EU336 (Coke Drum

System E and F). There is currently a safety interlock system using three pressure monitors instead of

one monitor. These monitors record the pressure of the system to determine when it is safe to open the

coke drum. When two of the pressure monitors measure less than the target pressure value, the coke

drum can be opened to the atmosphere. FHR proposed to clarify the specific monitoring used to

determine compliance with the 2.0 psig 365

‐ day rolling average and 5.0 psig per event operational

limitation and more clearly document when it is allowed to vent the coke drum to the atmosphere.

3.1 Emissions Increase Analysis

Attachment 2 to this TSD contains the Title I net emissions increase calculations for these projects.

The Combined Heat and Power Project involves only new emission units, so the calculation method used

to evaluate emissions increases for this project is the Actual

‐ to

‐ Potential method. Emissions calculations

for the turbine (EU359) and duct burners (EU360) are described as follows. PTE for PM, PM 10 

## and PM 2.5



## are all based on proposed BACT limits on PM 10 

## and PM 2.5 

## derived from a statistical analysis of available
performance test results for other LM6000 PF turbine installations. PTE calculations for NO X 

## , CO and

VOC are based on performance guarantees and estimates from the turbine manufacturer and design

basis specifications provided to the SCR and catalyst vendor(s) as applicable. Calculations for other
pollutants are based on emission factors for natural gas combustion from AP

‐ 42 Chapter 1.4.

The Tier 3 Clean Fuels Project involves both new and existing emission units, therefore FHR utilized the
hybrid test for calculating emissions increases as specified in 40 CFR Section 52.21(a)(2)(iv)( f

). The

Actual

‐ to

‐ Potential method of calculating PTE was used for new units where the increase in emissions
equals the potential to emit minus the baseline where for new units, the baseline is equal to zero prior

to construction and operation. For existing units the Actual

‐ to

‐ Projected

‐ Actual method was used to

calculate the emissions increases. This emission calculation method was used for the 26 Unit Sulfur

Recovery Unit (EU045, EU047) and the 45 Unit Sulfur Recovery Unit (EU111

‐ EU114). Project related
potential increase in utilization for non

‐ modified units is another calculation method that was used for

existing equipment experiencing an increase in emissions as a result of the projects. This method was

used for calculating the potential emissions increase attributable to the projects from the sulfur
degassing system (GP115), Cooling Towers no. 5 (EU271) and no. 7 (EU354) and haul road truck traffic
(IA060, in permit appendix B).

Federal PSD rules at 40 CFR Section 52.21(r)(6) define when a Permittee is required to conduct
recordkeeping and reporting when using the actual

‐ to

‐ projected

‐ actual emissions increase calculation
methodology for modified or affected units. For the Tier 3 Clean Fuels project, recordkeeping will be
required for the emission sources noted above that used actual

‐ to

‐ projected

‐ actual method to calculate

emission increases for SO 2 

## , PM 10 

## , PM 2.5 

## and RSC, since the project emissions increase is greater than 50%

of the PSD significant emission rate for each of these pollutants. The reasonable possibility
recordkeeping will become effective upon startup of the ATS process.

3.2 Dispersion Modeling

Flint Hills triggered mandatory EAWs for both the Combined Heat and Power (CHP) and Tier 3 Clean

Fuels projects. EAW requires potential air impacts and cumulative potential air impacts (EAW questions

16 and 19) to be addressed as part of the assessment. Existing unpaved roads will be paved prior to
operation of the ATS storage and loadout facility. The Permittee will prepare and submit a fugitive dust

management plan within 60 days of permit 03700011

‐ 012 issuance for the haul road truck traffic to

reduce potential fugitive dust and meet the MPCA’s paved road dust policy.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 26 of 33 

## The results in Table 10 reflect EAW SIL modeling results of the combined impact from both the

Combined Heat and Power and Tier 3 Clean Fuels projects. The table does not include H 2 

## S since there is

no H 2 

## S SIL currently in the MPCA rules; however an H 2 

## S SIL analysis was completed for the combined

projects assuming 3% of the MAAQS for the SIL. The calculated H 2 

## S half

‐ hour SIL is 2.1 ug/m 3 

## and the

combined project modeled results were 20.8 ug/m 3 

## or 99% of the calculated SIL.

Table 10. SIL

‐ Only Modeling Results for CHP/Tier 3 EAW

Pollutant Avg. Period SIL (ug/m 3 

## ) Total Modeled Conc. (ug/m 3 

## ) Percent of Standard (%)

NO 2 

## 1

‐ hr 7.52 6.43 85.5%

Annual 1 0.18 18%

SO 2 

## 1

‐ hr 7.83 4.63 59.1%

3

‐ hr 25 4.22 16.9%

24

‐ hr 5 1.24 24.8%

Annual 1 0.12 12%

PM 10 

## 24

‐ hr 5 0.54 10.8%

Annual 1 0.07 7.0%

PM 2.5 

## 24

‐ hr 1.2 0.44 36.7%

Annual 0.3 0.07 23.3%

CO 1

‐ hr 2000 6.97 0.35%

8

‐ hr 500 4.33 0.87%

The CHP project triggered PSD/NSR and so Flint Hills conducted PSD modeling for PM 10 

## and PM 2.5



## . FHR

utilized a Significant Impact Level (SIL) screening approach to demonstrate that the project will not

cause or contribute to a NAAQS exceedance. In addition, the project used an increment screening

method developed by MPCA to screen out of full increment analysis. Both the SIL and increment
approach are consistent with EPA’s latest Guidance for PM 2.5 

## Modeling (May, 2014). EPA reviewed and
approved the increment screening approach for this project. The CHP project did not increase paved

road emissions so the project

‐ only SIL modeling did not include existing paved road sources. The results

of the modeling for PSD SIL analysis for the CHP project are shown below in Table 11.

Table 11. SIL

‐ Only Modeling Results for CHP PSD

Pollutant Avg. Period SIL (ug/m 3 

## ) Total Modeled Conc. (ug/m 3 

## ) Percent of Standard (%)

PM 10 

## 24

‐ hr 5 0.54 10.8%

Annual 1 0.04 4.0%

PM 2.5 

## 24

‐ hr 1.2 0.38 31.7%

Annual 0.3 0.04 13.3%

The Tier 3 Clean Fuels project triggered an amendment to the Permittee’s SO 2 

## SIP. Site

‐ wide SO 2 

## modeling was conducted against 3 ‐ and 24

‐ hr and annual NAAQS covered by the maintenance SIP and a

SIL analysis was conducted for the more recently promulgated 1

‐ hr NAAQS. Currently, the existing SO 2 

## SIP does not cover, nor require a demonstration for the new 1

‐ hr standard. Nevertheless, FHR
performed a 1

‐ hr SIL analysis for the Tier 3 Clean Fuels project to demonstrate the work authorized by

the proposed modification of FHR’s SIP administrative order will not cause concerns relating to the new

standard. Existing FHR/MPCA monitors show that the emissions from the current facility operations

result in actual ambient concentrations of SO 2 

## well below the new 1

‐ hr SO 2 

## NAAQS. The modeling results

for SO 2 

## against the NAAQS and 1

‐ hr SIL analysis are shown below in Table 12.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 27 of 33 

## Table 12. 3

‐ hr, 24

‐ hr, Annual NAAQS/1

‐ hr SIL Modeling Results for Tier 3 SO 2 

## SIP

Pollutant Avg. Period NAAQS/SIL
(ug/m 3 

## ) Total Modeled Conc. (ug/m 3 

## )
(NAAQS includes background

& nearby sources) Percent of SIL/Standard

(%)

SO 2 

## 1

‐ hr 7.83 (SIL) 4.63 59.1%

3

‐ hr 1300 (N) 539 41.5%

24

‐ hr 365 (N) 177 48.5%

Annual 80 (N) 22 27.5%

3.3 Monitoring

In accordance with the Clean Air Act, it is the responsibility of the owner or operator of a facility to have

sufficient knowledge of the facility to certify that the facility is in compliance with all applicable

requirements.

In evaluating the monitoring included in the permit, the MPCA considered the following:

 the likelihood of the facility violating the applicable requirements;

 whether add

‐ on controls are necessary to meet the emission limits;

 the variability of emissions over time;

 the type of monitoring, process, maintenance, or control equipment data already available for

the emission unit;

 the technical and economic feasibility of possible periodic monitoring methods; and

 the kind of monitoring found on similar units elsewhere.

The table below summarizes the monitoring requirements associated with this amendment.

Table 13. Monitoring

Subject

Item* Requirement (rule basis) Monitoring Discussion

GP132 New fugitive equipment
(FS139) in NG service
(BACT limit; 40 CFR § 52.21

& Minn. R. 7007.3000) See listed LDAR GPs

referenced in GP132 Compliance demonstration requirements are

contained in LDAR groups 087, 090, 091, 093, 101

and 114. FS139 is being added to this existing

group.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 28 of 33 Subject

Item* Requirement (rule basis) Monitoring Discussion

GP135 PM 10 

## /PM 2.5 

## : < 0.0057 lb/

mmBtu heat input using 3

‐ hr avg

PM 10 

## /PM 2.5 

## : < 3.8 lb/hr

using 3

‐ hr avg

CO 2 

## e: < 1000 lb/MWh

using 12

‐ mo rolling avg

Fuel use: pipeline natural

gas only
(BACT limit; 40 CFR § 52.21

& Minn. R. 7007.3000)

NO X 

## : < 27.7 tpy using 365
day rolling sum

CO: < 66.9 tpy using 365
day rolling sum

VOC: < 28.0 tpy using 365
day rolling sum (Title I Condition: to avoid

major modification under

40 CFR § 52.21 & Minn. R.
7007.3000)

NO X 

## : < 25 ppm at 15% O 2 

## >

75% load & > 0 o 

## F (EU359)

NO X 

## : < 96 ppm at 15% O 2 

## <

75% load & < 0 o 

## F (EU359)

SO 2 

## : < 110 ng/J heat input
(40 CFR pt. 60, subp. KKKK)

PM: < 0.1 lb/mmBtu using

3

‐ hr rolling avg

SO 2 

## : < 1.75 lb/mmBtu

using 3

‐ hr rolling avg Opacity: < 20% with

exceptions
(Minn. R. 7011.1410) PM 10 

## /PM 2.5 

## : Initial
performance test

180 days after

startup

CO 2 

## e: Monitor fuel

flow rate and fuel

gas analysis

NO X 

## /CO: Monitor

NO X, 

## CO, O 2 

## , & Stack

Flow CEM to continuously

measure NO X 

## & CO

emissions, also FHR

will calculate and

record 365 day
rolling sum of

emissions

VOC: Initial
performance test

180 days after

startup. Compliance

with CO limit using

CO CEM

demonstrates
compliance with

VOC limit

Fuel: operate CMS

to record fuel flow

rate

PM/SO 2 

## /Opacity:

Compliance via fuel

restriction Initial performance testing 180 days after startup

for PM 10 

## & PM 2.5 

## BACT limits. CO 2 

## e BACT limits shall

use methods in 40 CFR pt. 98, subp. C including fuel

use, and gas analysis monitoring.

NO X 

## , CO, O 2 

## , & Stack Flow CEMS will be used to comply with NO X 

## & CO limits along with
recordkeeping. Initial performance test for VOC and
compliance with CO limit via CO CEM demonstrates
compliance with VOC limit. Test frequency plans to

be submitted following the performance test.

FHR will calibrate, operate, maintain a CMS to

record fuel flow to EU359 and EU360.

Monitoring of NO X 

## & SO 2 

## limits from NSPS subp.

KKKK are included in the standard.

Compliance with PM, SO 2 

## and Opacity limits from

Minn. R. 7011.1410 is shown by complying with the

fuel restriction; therefore no additional monitoring

will be required.

GP136 VOC: < 28.0 tpy using 12

‐ month rolling sum (Title I Condition: to avoid

major modification under

40 CFR § 52.21 & Minn. R.
7007.3000) Recordkeeping:
Monthly records of

VOC emissions VOC limit applies to the sum of emissions from all

TKs in GP136. Limit based on 12 month rolling sum,

thus daily recordkeeping is not required.

SV042

SV093

SV094 SO 2 

## : < 250 ppmv (dry, 0%

excess air) using 12

‐ hr
rolling avg (40 CFR pt. 60, subp. Ja) Performance testing

180 days after initial

startup of EU361 for

initial compliance

with limits Limit from 40 CFR pt. 60, subp. J expires and limit

from subp. Ja becomes effective after startup of

EU361. Limit from 40 CFR pt. 60, subp. J is also cited

from 40 CFR pt. 63, subp. UUU and this citation will

remain after the NSPS subp. J applicability expires.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 29 of 33 Subject

Item* Requirement (rule basis) Monitoring Discussion

SV066 Heat Input: < 117.6
mmBtu/hr using 8

‐ hr block

avg (Minn. R. 7017.2025) Performance test at

36 months New limit based on performance test results.

EU005 SO 2 

## : < 6.8 lb/hr using 3

‐ hr

and 24

‐ hr rolling avgs.

SO 2 

## : < 16.0 tpy using 12

‐

mo rolling avg (Title I Condition: SIP for

SO 2 

## NAAQS) SO 2 

## emissions

calculations and
recordkeeping Limits became effective upon EPA approval of

Amendment 9 to FHR’s SO 2 

## SIP.

EU026 SO 2 

## : < 7.3 lb/hr using 3

‐ hr

and 24

‐ hr rolling avgs.

SO 2 

## : < 17.3 tpy using 12

‐

mo rolling avg (Title I Condition: SIP for

SO 2 

## NAAQS) SO 2 

## emissions

calculations and
recordkeeping Limits became effective upon EPA approval of

Amendment 9 to FHR’s SO 2 

## SIP.

EU028 SO 2 

## : < 5.6 lb/hr using 3

‐ hr

and 24

‐ hr rolling avgs.

SO 2 

## : < 13.2 tpy using 12

‐

mo rolling avg (Title I Condition: SIP for

SO 2 

## NAAQS) SO 2 

## emissions

calculations and
recordkeeping Limits became effective upon EPA approval of

Amendment 9 to FHR’s SO 2 

## SIP.

EU030 SO 2 

## : < 5.6 lb/hr using 3

‐ hr

and 24

‐ hr rolling avgs.

SO 2 

## : < 13.2 tpy using 12

‐

mo rolling avg (Title I Condition: SIP for

SO 2 

## NAAQS) SO 2 

## emissions

calculations and
recordkeeping Limits became effective upon EPA approval of

Amendment 9 to FHR’s SO 2 

## SIP.

EU035 Heat Input: < 108.4 mmBtu /hr using 8

‐ hr block avg (Minn. R. 7017.2025) Performance test at

60 months New limit based on performance test results. Test
frequency based on result less than 60% of limit.

EU056 Heat Input: < 43.1 mmBtu/

hr using 8

‐ hr block avg (Minn. R. 7017.2025) Performance test at

36 months New limit based on performance test results. Test
frequency based on result 60

‐ 90% of limit.

EU102 Heat Input: < 30.7 mmBtu/

hr using 8

‐ hr block avg (Minn. R. 7017.2025) Performance test at

36 months New limit based on performance test results. Test
frequency based on result 60

‐ 90% of limit.

EU103 Heat Input: < 28.9 mmBtu/

hr using 8

‐ hr block avg (Minn. R. 7017.2025) Performance test at

36 months New limit based on performance test results. Test
frequency based on result 60

‐ 90% of limit.

EU213 Heat Input: < 449.5
mmBtu/hr using 8

‐ hr block

avg (Minn. R. 7017.2025) Performance test at

60 months Heat duty limit based on PM10 test 1/17/12. The

previous limit of 436.6 mmBtu/hr was from a test solely to establish a VOC emission factor on 11/2/06. The permit performance test is for PM10.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 30 of 33 Subject

Item* Requirement (rule basis) Monitoring Discussion

EU352 NO X 

## : < 40 ppm on 30 day
rolling avg, or

NO X 

## : < 0.040 lb/mmBtu on

30 day rolling avg (HHV)
(40 CFR pt. 60, subp. Ja) Monitoring from

NSPS subp. Ja for

concentration of

H 2 

## S, NO X 

## and stack

temperature. Heater has induced rather than forced draft.

Induced draft meets the definition of natural draft

process heaters under NSPS subp. Ja, thus EU352
(23H3) is subject to more stringent NO X 

## limits.

EU361 SO 2 

## : < 5.0 lb/hr using 1

‐ hr

avg

SO 2 

## : < 5.0 lb/hr using 3

‐ hr
rolling avg

SO 2 

## : < 5.0 lb/hr using 24

‐ hr
rolling avg

SO 2 

## : < 5.0 lb/hr using 12

‐

mo rolling avg (Title I Condition: SIP for

SO 2 

## NAAQS, 40 CFR pts. 50

& 52)

Opacity: < 20%
(Minn. R. 7011.0715) CEMS to monitor

SO 2 

## in lb/hr records

of SO 2 

## emissions Monitoring based on the Minnesota Performance

Standard for Control Equipment is adequate to have

a reasonable assurance of compliance.



## *Location of the requirement in the permit (e.g., EU, SV, GP, etc.).

3.4 Insignificant Activities

Flint Hills Resources Pine Bend Refinery has several operations which are classified as insignificant

activities under the MPCA’s permitting rules. These are listed in Appendix B to the permit. The following
insignificant activities are included in this modification. Only equipment used for hydraulic or hydrostatic

testing and cleaning operations will be added to Appendix B of the permit. The remaining insignificant

activities listed below are already represented in Appendix B.

The permit is required to include periodic monitoring for all emissions units, including insignificant

activities, per EPA guidance. The insignificant activities at this Facility are only subject to general
applicable requirements. Using the criteria outlined earlier in this TSD, the following table documents

the justification why no additional periodic monitoring is necessary for the insignificant activities

affected by this modification.

Table 14. Insignificant Activities

Insignificant Activity General Applicable

Emission limit Discussion

Emissions from a laboratory,

as defined in Minn. R.

7007.1300, subp. 3(G) PM, variable depending

on airflow

Opacity ≤ 20%
(Minn. R. 7011.0710/0715) These are very small, intermittent, bench

‐ top
operations that typically do not even have any

emissions. It is highly unlikely that they could

violate the applicable requirement.

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 31 of 33 Insignificant Activity General Applicable

Emission limit Discussion

Equipment used for
hydraulic or hydrostatic

testing PM, variable depending

on airflow

Opacity ≤ 20%
(Minn. R. 7011.0710/0715) While no known emissions estimation method

exists for these units, based on general knowledge

of how they operate, it is highly unlikely that they

could generate particulate matter. In addition,

these units would be operated and vented directly

into a building, so testing is not feasible.

Brazing, soldering or welding

equipment PM, variable depending

on airflow

Opacity < 20%
(Minn. R. 7011.0710/0715) For these units, based on EPA published emissions
factors, it is highly unlikely that they could violate

the applicable requirement. In addition, these units

are typically operated and vented inside a building,

so testing for PM or opacity is not feasible.

Cleaning operations: alkaline/phosphate cleaners

and associated cleaners and

associated burners PM, variable depending

on airflow

Opacity ≤ 20%
(Minn. R. 7011.0610 &

Minn. R. 7011.0710/0715) For these units, there are some factors available for

the burners, but very little information regarding

the cleaning operation itself. However, based on general knowledge of how they operate, it is highly
unlikely that they could violate the applicable

requirement or that testing would be feasible.

Infrequent use of spray paint equipment for routine
housekeeping or plant
upkeep activities not

associated with primary
production processes at the

stationary source PM, variable depending

on airflow or process weight rate
Opacity ≤ 20%
(Minn. R. 7011.0715) While spray equipment will have the potential to

emit particulate matter, these particular activities

are those not associated with production, so they

would be infrequent and usually occur outdoors.

Testing or monitoring is not feasible.



## 3.5 Permit Organization

In general, the permit meets the MPCA Delta Guidance for ordering and grouping of requirements. One

area where this permit deviates slightly from Delta guidance is in the use of appendices. While
appendices are fully enforceable parts of the permit, in general, any requirement that the MPCA thinks

should be electronically tracked (e.g., limits, submittals, etc.), should be in Table A or B of the permit.

The main reason is that the appendices are word processing sections and are not part of the electronic
tracking system. Violation of the appendices can be enforced, but the computer system will not automatically generate the necessary enforcement notices or documents. Staff must generate these.

Another area that deviates from the guidance is in the use of groups where the requirements in the

group apply to the members of the group individually. This was done in order to shorten the permit and

where no testing or tracking specific to a unit is in the permit (thereby reducing the likelihood that there

where will be further unit

‐ specific requirements later). This is the case for the requirements at GP 135
(Combustion Turbine and Duct Burners) and GP 136 (ATS Sour Water Tanks).

3.6 Comments Received

Public Notice Period: December 23, 2014 ‐ January 21, 2015

EPA 45

‐ day Review Period: December 23, 2014 ‐ February 5, 2015

Comments were not received from the public during the public notice period. Comments were not

received from EPA during their review period. There was a phone call from EPA on 1/15/15 asking why

## Technical Support Document, Permit Action Number: 03700011 ‐ 012

Page 32 of 33 

## the emissions increases were not added together for purposes of applying PSD and BACT. Both
applications were for separate unrelated projects so the emissions increases were assessed separately.

Both projects however, were processed together in one permit action. This situation is also explained in

the TSD for permit no. 03700011

‐ 010 for why that permit did not go through a BACT analysis for VOC

emissions.

4. Permit Fee Assessment

Attachment 7 to this TSD contains the MPCA’s assessment of Application and Additional Points used to

determine the permit application fee for this permit action as required by Minn. R. 7002.0019. The

permit action includes two permit applications, both received after the effective date of the rule (July 1,
2009). The action includes modeling review for both projects (30 pts.), BACT review for PM 10 

## , PM 2.5 

## and

GHG (45 pts.), NSPS review of subps. Ja and KKKK (20 pts.), NESHAP review of subp. YYYY (10 pts.), limits

to avoid a major modification under PSD for both projects (20 pts.) and environmental review triggering
subparts 10 for greater than 1 million gallons storage (35 pts.) and 15B for GHG emissions increase

greater than 100,000 tpy (70 pts.).

5. Conclusion

Based on the information provided by Flint Hills Resources Pine Bend Refinery, the MPCA has

reasonable assurance that the proposed operation of the emission facility, as described in the Air

Emission Permit No. 03700011

‐ 012 and this TSD, will not cause or contribute to a violation of applicable

federal regulations and Minnesota Rules.

Staff Members on Permit Team: Tarik Hanafy (permit engineer)

Brent Rohne (enforcement)

Curtis Stock (compliance)

Steve Irwin (modeling)

Jim Sullivan (modeling)

Kim Grosenheider (environmental review)

Amanda Smith (State Implementation Plan)

Amrill Okonkwo (peer reviewer)

Beckie Olson (permit writing assistant)

Sandy Simbeck (administrative support)

AQ File No. 106A; DQ#s 4744, 4761, reopenings DQ#s 4404, 4405, 4800, 4812, 4813, 4818, 4854, 4855,

4947

Attachments: 1. Facility Description and CD

‐ 01 Forms

2. Calculation Spreadsheets

3. BACT Analysis for PM 10 

## , PM 2.5 

## and GHG

4. ESA Consult Letter

5. NHPA Consult Letter

6. Points Calculator

# Attachment 1:
Facility Description and CD

‐ 01 FormsMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus1GP 001PER 009RemovedRemoved2GP 002PER 010Cooling Towers (#1, #3, #4, #5, #6 and #7) and associated Heat ExchangeSystemsEU 268, EU 269, EU 270, EU 271, EU 272, EU 354Active3GP 003PER 001ULSD Project CO EmissionsEU 294, EU 295, EU 296, SV 167, SV 168Active4GP 004PER 001ULSD Project VOC EmissionsEU 294, EU 295, EU 296, FS 133, FS 134, TK 522, TK 523Active5GP 005PER 001Process Fugitive Emissions from the Total FacilityActive6GP 005PER 012Process Fugitive Emissions from the Total FacilityRemoved7GP 007PER 001Tanks subject to NSPS UU (each tank)TK 019, TK 029, TK 037, TK 039, TK 411, TK 412, TK 414, TK 415, TK 416, TK417, TK 418, TK 423, TK 424Active8GP 008PER 007External FloatingTanks NSPS Kb > 39,890 gallonsTK 001, TK 002, TK 003, TK 004, TK 005, TK 006, TK 007, TK 061, TK 062, TK063, TK 064, TK 066, TK 068, TK 080, TK 083, TK 087, TK 088, TK 150, TK151, TK 152, TK 160Active9GP 008PER 012External FloatingTanks NSPS Kb > 39,890 gallonsRemoved10GP 009PER 001Tanks subject to VOC Limit (CFP)TK 001, TK 002, TK 003, TK 004, TK 005, TK 006, TK 007, TK 010, TK 011, TK012, TK 013, TK 014, TK 015, TK 016, TK 017, TK 018, TK 019, TK 021, TK022, TK 023, TK 024, TK 025, TK 026, TK 027, TK 028, TK 029, TK 030, TK031, TK 033, TK 034, TK 035, TK 037, TK 038, TK 039, TK 046, TK 047, TK048, TK 049, TK 061, TK 062, TK 063, TK 064, TK 065, TK 066, TK 067, TK068, TK 080, TK 081, TK 082, TK 083, TK 084, TK 085, TK 086, TK 087, TK088, TK 130, TK 131, TK 132, TK 133, TK 134, TK 150, TK 151, TK 152, TK153, TK 154, TK 160, TK 161, TK 200, TK 201, TK 205, TK 206, TK 334, TK336, TK 411, TK 412, TK 414, TK 415, TK 416, TK 417, TK 418, TK 423, TK424Active11GP 010PER 009Tanks/Basins subject to NESHAP FF w/vapor recovery & control deviceEU 178, EU 182, EU 183, EU 184, EU 185, EU 186, EU 187, EU 188, EU 189,EU 190, EU 191, EU 218, EU 222, EU 223, EU 278, EU 280, EU 281, EU 289,EU 290, EU 291, EU 292, EU 293, EU 314, EU 327, EU 345, EU 346, TK 336,TK 524, TK 525Active12GP 011PER 009Diesel Engines with SIP Conditions and <83.3 hr/monEU 007, EU 024, EU 036, EU 042, EU 100, EU 128, EU 129, EU 130, EU 131,EU 132, EU 198, EU 199, EU 312Active13GP 012PER 00900PB027Portable Diesel EnginesActive14GP 012PER 01200PB027Portable Diesel EnginesRemoved15GP 014PER 00900PB025RemovedRemoved16GP 015PER 009FCC Catalyst TransfersEU 230, EU 231, EU 232Active17GP 017PER 001Loading Rack Activities in CFP group limitEU 004, EU 205, EU 207, EU 208, EU 209, EU 216Active18GP 019PER 007External Floating Tanks NSPS Kb > 39,890 (0.75-11.1 psi)Active19GP 019PER 012External Floating Tanks NSPS Kb > 39,890 galsTK 001, TK 002, TK 003, TK 004, TK 005, TK 006, TK 007, TK 061, TK 062, TK063, TK 064, TK 066, TK 068, TK 080, TK 083, TK 087, TK 088, TK 150, TK151, TK 152, TK 160, TK 586, TK 587, TK 588Active20GP 023PER 007NSPS K Tanks w/ fixed roof > 40,000 gals without CVS/CDTK 500ActivePage 1 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus21GP 024PER 001NSPS Ka Tanks w/fixed roof > 40,000 galsTK 502, TK 505Active22GP 025PER 009NSPS Kb Tanks w/fixed roof > 39,890 galsTK 019, TK 021, TK 022, TK 029, TK 030, TK 031, TK 033, TK 034, TK 035, TK037, TK 038, TK 039, TK 046, TK 047, TK 081, TK 130, TK 131, TK 132, TK133, TK 134, TK 153, TK 154, TK 336, TK 411, TK 412, TK 414, TK 415, TK416, TK 417, TK 418, TK 423, TK 424, TK 513, TK 515, TK 516, TK 526, TK528, TK 573, TK 574Active23GP 025PER 012NSPS Kb Tanks w/fixed roof > 39,890 galsRemoved24GP 026PER 009NSPS Kb Tanks w/fixed roof & CVS/CD 19,813-39,890 gals (vp>4.0 psi)Active25GP 026PER 012NSPS Kb Tanks w/fixed roof & CVS/CD 19,813-39,890 galsTK 200, TK 201, TK 303, TK 373, TK 514Active26GP 027PER 009NSPS Kb Tanks w/fixed roof between 19,813 and 39,890 galsTK 200, TK 201, TK 303, TK 373, TK 514Active27GP 027PER 012NSPS Kb Tanks w/fixed roof between 19,813 and 39,890 galsRemoved28GP 032PER 009NSPS K Tanks w/fixed roof & CVS/CD & > 40,000 galsTK 367, TK 368Active29GP 033PER 009RemovedRemoved30GP 034PER 009NSPS Kb Tanks w/fixed roof & CVS/CD > 39,890 and tvp>0.75Active31GP 034PER 012NSPS Kb Tanks w/fixed roof & CVS/CD > 39,890 galsTK 019, TK 021, TK 022, TK 029, TK 030, TK 031, TK 033, TK 035, TK 037, TK038, TK 039, TK 046, TK 047, TK 081, TK 130, TK 131, TK 132, TK 133, TK134, TK 153, TK 154, TK 336, TK 411, TK 412, TK 414, TK 415, TK 416, TK417, TK 418, TK 423, TK 424, TK 515, TK 516, TK 526, TK 528, TK 573, TK574Active32GP 035PER 009RemovedRemoved33GP 037PER 001IFR tank/basin subject to NESHAPs FF following the requirements of KbTK 205, TK 206Active34GP 038PER 004NSPS Kb Tanks w/internal floating roof > 39,890 gallonsTK 010, TK 011, TK 012, TK 013, TK 014, TK 015, TK 016, TK 017, TK 018, TK023, TK 024, TK 025, TK 026, TK 027, TK 028, TK 048, TK 049, TK 065, TK067, TK 082, TK 084, TK 085, TK 086, TK 161, TK 205, TK 206, TK 522, TK523Active35GP 038PER 012NSPS Kb Tanks w/internal floating roof > 39,890 gallonsRemoved36GP 039PER 009NSPS Kb Tanks w/internal floating> 39,890 gals & tvp (0.75-11.1 psi)Active37GP 039PER 012NSPS Kb Tanks w/internal floating roof > 39,890 galsTK 010, TK 011, TK 012, TK 013, TK 014, TK 015, TK 016, TK 017, TK 018, TK023, TK 024, TK 025, TK 026, TK 027, TK 028, TK 048, TK 049, TK 065, TK067, TK 082, TK 084, TK 085, TK 086, TK 161, TK 205, TK 206, TK 522, TK523Active38GP 042PER 009MACT CC Group 1 Tank Requirements, satisfied by NSPS KbTK 001, TK 002, TK 003, TK 004, TK 005, TK 006, TK 007, TK 010, TK 011, TK012, TK 013, TK 014, TK 015, TK 016, TK 017, TK 018, TK 024, TK 025, TK026, TK 027, TK 028, TK 061, TK 062, TK 063, TK 064, TK 065, TK 066, TK067, TK 080, TK 082, TK 083, TK 084, TK 085, TK 086, TK 087, TK 088, TK150, TK 151, TK 152, TK 160, TK 161, TK 205, TK 206, TK 367, TK 368, TK513, TK 515, TK 522, TK 523ActivePage 2 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus39GP 042PER 012MACT CC Group 1 Tank Requirements, satisfied by NSPS KbTK 001, TK 002, TK 003, TK 004, TK 005, TK 006, TK 007, TK 010, TK 011, TK012, TK 013, TK 014, TK 015, TK 016, TK 017, TK 018, TK 024, TK 025, TK026, TK 027, TK 028, TK 061, TK 062, TK 063, TK 064, TK 065, TK 066, TK067, TK 080, TK 082, TK 083, TK 084, TK 085, TK 086, TK 087, TK 088, TK150, TK 151, TK 152, TK 160, TK 161, TK 205, TK 206, TK 367, TK 368, TK513, TK 515, TK 522, TK 523, TK 586, TK 587, TK 588Active40GP 043PER 009RemovedTK 303, TK 312, TK 330, TK 331, TK 366, TK 373, TK 411, TK 412, TK 414, TK415, TK 416, TK 417, TK 418, TK 500, TK 501, TK 502, TK 504, TK 527Removed41GP 043PER 012RemovedRemoved42GP 044PER 009Tanks MN R 1969-73 and > 65,000 galsTK 039, TK 085, TK 086, TK 411, TK 412, TK 414Active43GP 045PER 009Tanks MN R 1969-73 and > 2,000-65,000 galsTK 201, TK 366Active44GP 046PER 009Tanks MN R post 1973 and > 40,000 galsTK 006, TK 007, TK 049, TK 066, TK 067, TK 068, TK 087, TK 088, TK 130, TK131, TK 132, TK 133, TK 134, TK 150, TK 151, TK 152, TK 153, TK 154, TK160, TK 161, TK 205, TK 206, TK 300, TK 367, TK 368, TK 415, TK 416, TK417, TK 418, TK 423, TK 424, TK 500, TK 502, TK 505, TK 513, TK 515, TK516, TK 517, TK 522, TK 523, TK 526, TK 574Active45GP 046PER 012Tanks MN R post 1973 and > 40,000 galsTK 006, TK 007, TK 049, TK 066, TK 067, TK 068, TK 087, TK 088, TK 130, TK131, TK 132, TK 133, TK 134, TK 150, TK 151, TK 152, TK 153, TK 154, TK160, TK 161, TK 205, TK 206, TK 300, TK 367, TK 368, TK 415, TK 416, TK417, TK 418, TK 423, TK 424, TK 500, TK 502, TK 505, TK 513, TK 515, TK516, TK 517, TK 522, TK 523, TK 526, TK 574, TK 586, TK 587, TK 588Active46GP 047PER 009Tanks MN R post 1973 and >2,000 - 40,000 galsTK 373, TK 501, TK 514Active47GP 052PER 001Tanks NSPS QQQTK 063, TK 064, TK 205, TK 206Active48GP 053PER 009EFR tank/basin subject to NESHAPs FF following the requirements of KbEU 200, EU 201, EU 347, TK 063, TK 064Active49GP 054PER 009Storage Tank Heaters built before June 11, 1973EU 144, EU 145, EU 146, EU 157, EU 158, EU 159, EU 160, EU 163, EU 164,EU 165, EU 166Active50GP 054PER 012Storage Tank Heaters built before June 11, 1973EU 144, EU 145, EU 146, EU 157, EU 158, EU 159, EU 160, EU 163, EU 164,EU 165, EU 166, EU 167Active51GP 055PER 008Emission Units subject to Minn. R. built before June 11, 1973EU 054, EU 056, EU 057, EU 058, EU 059, EU 060, EU 061, EU 076, EU 240,EU 241Active52GP 056PER 001Storage Tank Heaters built after June 11, 1973EU 149, EU 168, EU 169, EU 170, EU 171, EU 172, EU 173, EU 274, EU 275Active53GP 057PER 009Emission Units subject to Minn. R. built after June 11, 1973EU 055, EU 093, EU 094, EU 095, EU 096, EU 097, EU 098, EU 099, EU 102,EU 103, EU 104, EU 209Active54GP 058PER 009Equipment subject to both NESH FF controls and NSPS QQQEU 178, EU 278, EU 279, EU 283, EU 284, EU 315, TK 063, TK 064, TK 205,TK 206Active55GP 059PER 009Containers subject to NESH FF; w/vac trucks to haul NESH FF wasteEU 284, EU 315, EU 345, EU 346Active56GP 060PER 009Oil/water separators w/floating roof subject to NSPS QQQ and NESHAP FFEU 279Active57GP 061PER 009RemovedRemoved58GP 062PER 009Oil/water separatorsw/fixed roof subject to NSPS QQQ and NESH FF w/CVS &control deviceEU 177, EU 178, EU 278, EU 283, EU 290, EU 291, EU 292, EU 345, EU 346ActivePage 3 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus59GP 062PER 012Oil/water separators w/fixed roof subject to NSPS QQQ and NESH FF w/CVS &control deviceEU 177, EU 178, EU 278, EU 283, EU 290, EU 291, EU 292, EU 345, EU 346Active60GP 063PER 009RemovedRemoved61GP 065PER 009Treatment Processes to meet destruction req. NESH FFEU 182, EU 183, EU 184, EU 185, EU 186, EU 187, EU 188, EU 189, EU 190,EU 191, EU 200, EU 201, EU 280, EU 281, EU 289, EU 293, EU 327, EU 347Active62GP 066PER 009RemovedRemoved63GP 067PER 009All equipment included in individual drain system subject to NSPS QQQ orNESHAPs FFEU 316, EU 317, FS 001, FS 002, FS 006, FS 018, FS 019, FS 022, FS 024, FS027, FS 029, FS 031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS045, FS 048, FS 054, FS 060, FS 062, FS 063, FS 064, FS 069, FS 070, FS075, FS 077, FS 083, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS096, FS 099, FS 104, FS 109, FS 110, FS 112, FS 119, FS 130, FS 132, FS133, FS 134Active64GP 067PER 012All equipment included in individual drain system subject to NSPS QQQ orNESHAPs FFEU 316, EU 317, FS 001, FS 002, FS 006, FS 018, FS 019, FS 022, FS 024, FS027, FS 029, FS 031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS045, FS 048, FS 054, FS 060, FS 062, FS 063, FS 064, FS 069, FS 070, FS075, FS 077, FS 083, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS096, FS 099, FS 104, FS 109, FS 110, FS 112, FS 119, FS 130, FS 132, FS133, FS 134, FS 140Active65GP 068PER 009Drains subject to NESH FF equipped with plugsEU 316, FS 006, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 048, FS 060, FS 062, FS063, FS 064, FS 069, FS 070, FS 075, FS 077, FS 085, FS 087, FS 088, FS091, FS 093, FS 095, FS 096, FS 099, FS 104, FS 109, FS 110, FS 112, FS119Active66GP 069PER 009Drains subject to NESH FF and also subject to NSPS QQQ (water seal; lube oil orequivalent)FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 042, FS 060, FS 062, FS 063, FS 064, FS 069, FS070, FS 075, FS 077, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS096, FS 099, FS 104, FS 119Active67GP 069PER 012Drains subject to NESH FF and also subject to NSPS QQQ (water seal; lube oil orequivalent)FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 042, FS 060, FS 062, FS 063, FS 064, FS 069, FS070, FS 075, FS 077, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS096, FS 099, FS 104, FS 119, FS 140Active68GP 071PER 009Drains subject to NSPS QQQ (sealed w/plug)FS 006, FS 052, FS 054, FS 055, FS 058, FS 083, FS 085, FS 102, FS 106, FS109, FS 112, FS 133, FS 134Active69GP 072PER 009Drains subject to NSPS QQQ active (water seal, lube oil or equivalent)FS 006, FS 052, FS 054, FS 055, FS 058, FS 083, FS 085, FS 102, FS 106, FS109, FS 112, FS 133, FS 134Active70GP 075PER 009Drains subject to NSPS QQQ inactive (equipped with plugs water seal orequivalent)FS 006, FS 052, FS 054, FS 055, FS 058, FS 083, FS 085, FS 102, FS 106, FS109, FS 112, FS 133, FS 134Active71GP 076PER 009Junction Boxes subject to NESH FF when equipped with carbon canistersEU 317, FS 018, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 045, FS 060, FS 062, FS 063, FS 064, FS 070, FS075, FS 077, FS 085, FS 095, FS 104, FS 109, FS 112, FS 119, FS 133Active72GP 076PER 012Junction Boxes subject to NESH FF when equipped with carbon canistersEU 317, FS 018, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 045, FS 060, FS 062, FS 063, FS 064, FS 070, FS075, FS 077, FS 085, FS 095, FS 104, FS 109, FS 112, FS 119, FS 133, FS140ActivePage 4 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus73GP 077PER 004Junction Boxes receiving Wastewater from NSPS QQQ Units not subject toNESHAPs FFFS 045, FS 048, FS 052, FS 054, FS 058, FS 102, FS 106, FS 109, FS 134Active74GP 079PER 009Non-contact Cooling Water SystemsEU 319Active75GP 080PER 001Stormwater SewersEU 320Active76GP 081PER 009Fugitive Compressors Exempt from LDAR RequirementsFS 054, FS 055, FS 058, FS 060, FS 062, FS 064, FS 070, FS 079, FS 080, FS083, FS 102, FS 133Active77GP 082PER 009Fugitive Compressors LDAR RequirementsFS 006, FS 024, FS 027, FS 035, FS 045, FS 069, FS 075, FS 088, FS 102, FS109, FS 128Active78GP 082PER 012Fugitive Compressors LDAR RequirementsFS 006, FS 024, FS 027, FS 035, FS 045, FS 069, FS 075, FS 088, FS 102, FS109, FS 128, FS 140Active79GP 087PER 010Fugitive LDAR All Equipment in VOC or HAP ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138Active80GP 087PER 012Fugitive LDAR All Equipment in VOC or HAP ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140Active81GP 088PER 009Fugitive LDAR in Vacuum ServiceFS 006, FS 022, FS 024, FS 029, FS 031, FS 032, FS 039, FS 048Active82GP 089PER 001Fugitive LDAR Emission Sources not in VOC or HAP ServiceActive83GP 090PER 010Fugitive LDAR Equipment Designated Non-detectable emissions (NDE)FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138Active84GP 090PER 012Fugitive LDAR Equipment Designated Non-detectable emissions (NDE)FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140ActivePage 5 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus85GP 091PER 010Fugitive LDAR Open-ended LinesFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138Active86GP 091PER 012Fugitive LDAR Open-ended LinesFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140Active87GP 092PER 009RemovedRemoved88GP 093PER 010Fugitive LDAR PSV to Atmosphere in Gas/Vapor ServiceFS 002, FS 006, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS 052, FS054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS 069, FS070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 088, FS 091, FS093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS 109, FS 110, FS112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS 138Active89GP 093PER 012Fugitive LDAR PSV to Atmosphere in Gas/Vapor ServiceFS 002, FS 006, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS 052, FS054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS 069, FS070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 088, FS 091, FS093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS 109, FS 110, FS112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS 138, FS 140Active90GP 094PER 009Fugitive LDAR PSV with Upstream Rupture DisksFS 018, FS 019, FS 041, FS 042, FS 045, FS 070, FS 077, FS 117Active91GP 095PER 009Fugitive LDAR Pumps In Heavy Liquid ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134Active92GP 095PER 012Fugitive LDAR Pumps In Heavy Liquid ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 140ActivePage 6 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus93GP 096PER 010Fugitive LDAR Light Liquid PumpsFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138Active94GP 096PER 012Fugitive LDAR Light Liquid PumpsFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140Active95GP 099PER 010Fugitive LDAR Sample StationsFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138Active96GP 099PER 012Fugitive LDAR Sample StationsFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140Active97GP 100PER 009Fugitive LDAR Heavy Liquid Valves and PSVs (in LL/HL Service)FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134Active98GP 100PER 012Fugitive LDAR Heavy Liquid Valves and PSVs (in LL/HL Service)FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 140Active99GP 101PER 010Fugitive LDAR Valves in Light Liquid ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138ActivePage 7 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus100GP 101PER 012Fugitive LDAR Valves in Light Liquid ServiceFS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS 048, FS052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS 064, FS069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS 087, FS088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS 106, FS109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 133, FS 134, FS 137, FS138, FS 140Active101GP 102PER 009Units where carbon canisters may be used to meet NESHAP FF RequirementsFS 001, FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS029, FS 031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS048, FS 052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS064, FS 069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS087, FS 088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS106, FS 109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 130, FS 132, FS133, FS 134Active102GP 102PER 012Units where carbon canisters may be used to meet NESHAP FF RequirementsFS 001, FS 002, FS 006, FS 008, FS 018, FS 019, FS 022, FS 024, FS 027, FS029, FS 031, FS 032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 045, FS048, FS 052, FS 054, FS 055, FS 056, FS 058, FS 060, FS 062, FS 063, FS064, FS 069, FS 070, FS 075, FS 077, FS 079, FS 080, FS 083, FS 085, FS087, FS 088, FS 091, FS 093, FS 095, FS 096, FS 099, FS 102, FS 104, FS106, FS 109, FS 110, FS 112, FS 117, FS 119, FS 128, FS 130, FS 132, FS133, FS 134, FS 140Active103GP 104PER 009Refinery Emergency Flares and Flare System (for Consent Decree Flare Policy)CE 022, CE 023, CE 024, CE 025, EU 301, EU 302, EU 303, EU 304Active104GP 106PER 009Control Equipment Used to Meet Requirements of MACT CCCE 002, CE 003, CE 013, CE 048, CE 050, EU 055, MR 189Active105GP 106PER 012Control Equipment Used to Meet Requirements of MACT CCCE 002, CE 003, CE 048, CE 050, EU 055, MR 189Active106GP 108PER 009RemovedRemoved107GP 109PER 009RemovedRemoved108GP 111PER 009Fuel Gas Supply SystemsEU 256, EU 263, MR 075, MR 076, MR 080, MR 088Active109GP 112PER 009Sulfur Recovery UnitsEU 045, EU 111, EU 112, MR 036, MR 037, MR 082, MR 084, MR 114, MR139, SV 042, SV 093, SV 094Active110GP 113PER 009RemovedRemoved111GP 114PER 001Fugitive LDAR Connectors, Misc. All FS numbers are included in this group.Active112GP 115PER 001Sulfur Degassing SystemEU 217, TK 505, TK 526Active113GP 116PER 010Refinery Fuel Gas SO2 EmissionsMR 033, MR 156, MR 161, MR 162, MR 166, MR 196Active114GP 117PER 007Limit that Applies to Gas Oil HDS Heaters (EU084 and EU085)EU 084, EU 085Active115GP 118PER 009Temporary Portable Coke CrushersEU 325, EU 326Active116GP 122PER 009Liquid Butane Storage FacilityCE 026, CE 069, TK 517Active117GP 123PER 009Equipment subject to NSPS NNNEU 328, EU 329, EU 330ActivePage 8 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show:Action:AQD Facility ID:Facility Name:Active and Pending RecordsPER 01203700011Flint Hills Resources Pine Bend RefineryFACILITY DESCRIPTION: GROUPS (GP)11 December, 2014 16:06ID No.AddedBy(Action)RetiredBy(Action)Includein EIOperatorIDfor ItemGroup DescriptionGroup ItemsGroupStatus118GP 124PER 009Drains subject to NESH FF only and equipped w/water seal or equivalentEU 316, FS 006, FS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS032, FS 035, FS 036, FS 039, FS 041, FS 042, FS 060, FS 062, FS 063, FS064, FS 069, FS 070, FS 075, FS 077, FS 085, FS 087, FS 088, FS 091, FS093, FS 095, FS 096, FS 099, FS 104, FS 109, FS 110, FS 112, FS 119Active119GP 125PER 009Drains subject to NESH FF and NSPS QQQ sealed with plugsFS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 042, FS 060, FS 062, FS 064, FS 069, FS 070, FS075, FS 077, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS 096, FS099, FS 104, FS 119Active120GP 125PER 012Drains subject to NESH FF and NSPS QQQ sealed with plugsFS 018, FS 019, FS 022, FS 024, FS 027, FS 029, FS 031, FS 032, FS 035, FS036, FS 039, FS 041, FS 042, FS 060, FS 062, FS 064, FS 069, FS 070, FS075, FS 077, FS 085, FS 087, FS 088, FS 091, FS 093, FS 095, FS 096, FS099, FS 104, FS 119, FS 140Active121GP 126PER 009Affected Sources at the refinery under MACT GGGGGCE 028, CE 029, CE 056, CE 057, CE 070, EU 292, EU 331, EU 332, EU 333,SV 177, SV 178, SV 179Active122GP 127PER 009Stationary Diesels (Compression Ignition) Subject to MACT ZZZZEU 007, EU 024, EU 036, EU 042, EU 100, EU 127, EU 128, EU 129, EU 130,EU 132, EU 198, EU 199Active123GP 128PER 009Stationary Diesels (Spark Igniton 4SRB) Subject to MACT ZZZZEU 338, EU 339, EU 340, EU 341, EU 342, EU 343, EU 344Active124GP 128PER 012Stationary Diesels (Spark Ignition 4SRB) Subject to MACT ZZZZEU 338, EU 339, EU 340, EU 341, EU 342, EU 343, EU 344Active125GP 129PER 009Refinery-wide Greenhouse Gas Emissions for TanksActive126GP 129PER 012Refinery-wide Greenhouse Gas Emissions for TanksRemoved127GP 130PER 009Refinery-wide Greenhouse Gas Emissions for Fugitive SourcesActive128GP 130PER 012Refinery-wide Greenhouse Gas Emissions for Fugitive SourcesRemoved129GP 131PER 010RGP Vapor Combustion UnitCE 071, EU 350, EU 351, SV 182Active130GP 132PER 010Fugitive Equipment in Natural Gas (non-VOC) ServiceFS 045, FS 048Active131GP 132PER 012Fugitive Equipment in Natural Gas (non-VOC) ServiceFS 045, FS 048, FS 139Active132GP 133PER 011Emergency Propane GeneratorsCE 075, EU 355, EU 356, EU 357, SV 185, SV 186, SV 187Active133GP 134PER 011Temporary TK002 Thermal OxidizersCE 076, CE 077, EU 358, MR 201, SV 188Active134GP 135PER 012Combustion Turbine and Duct BurnersCE 078, CE 079, EU 359, EU 360, FS 139, MR 202, MR 203, MR 204, MR 205,MR 206, MR 207, MR 208, MR 209, MR 210, MR 216, SV 189Active135GP 136PER 012Sour Water TanksTK 586, TK 587, TK 588ActivePage 9 of 9MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus1SV 001Up, No CapNot Provided8835PER 001101H1RR Load to StackActive2SV 002PER 009RemovedRemoved3SV 003Up, With CapEstimate70267000.62535PER 001102UNIT3BT Load VRU StackActive4SV 004Up, No CapEstimate500366354.58131PER 00111H111H1 StackActive5SV 005Up, No CapEstimate539279026.13115PER 00111H211H2 StackActive6SV 006Up, With CapEstimate65014020.6713.5PER 009EE 1852EE1852 Diesel StackActive7SV 007PER 009RemovedRemoved8SV 008PER 009RemovedRemoved9SV 009PER 009RemovedRemoved10SV 010PER 009RemovedRemoved11SV 011PER 009RemovedRemoved12SV 012PER 009RemovedRemoved13SV 013PER 009RemovedRemoved14SV 014PER 009RemovedRemoved15SV 015Up, No CapEstimate350437126.79198.5PER 00112H412H4 StackActive16SV 016PER 009RemovedRemoved17SV 017Up, No CapEstimate5056873110.96193PER 00116H116H1 StackActive18SV 018PER 009RemovedRemoved19SV 019Up, No CapContinuous Monitor4504260249.64263PER 00117UNIT1FCC Main StackActive20SV 020PER 009RemovedRemoved21SV 021Up, No CapEstimate1300500005.51150.03PER 00117UNIT1FCC Bypass StackActive22SV 021Up, No CapEstimate1300500005.51150.03PER 01217UNIT1FCC Bypass StackRemoved23SV 022PER 001DELETERemoved24SV 023Up, With CapEstimate65014020.6715PER 001EE1718EE1718 Diesel StackActive25SV 024PER 009RemovedRemoved26SV 025Up, No CapEstimate324554757192PER 00119H119H1 StackActive27SV 026PER 009RemovedRemovedPage 1 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus28SV 027Up, No CapEstimate500134664.63127PER 00121H1_221H1S StackActive29SV 028Up, No CapEstimate500134664.63127PER 00121H1_121H1N StackActive30SV 029Up, No CapEstimate500134664.63131PER 00121H2_221H2S StackActive31SV 030Up, No CapEstimate500134664.63131PER 00121H2_121H2N StackActive32SV 031Up, With CapEstimate12011203.193.2PER 00121ME9021H1 Decoke Pit StackActive33SV 032Up, No CapEstimate350362125.35190PER 00123H123H1 StackActive34SV 033Up, No CapEstimate415341084.38190PER 00123H223H2 StackActive35SV 034Up, With CapEstimate65015880.523PER 00123ME2623ME26 Diesel StackActive36SV 035Up, No CapEstimate1208720PER 00123ME29AP20 Decoke Pit StackActive37SV 036Up, No CapEstimate2270.550PER 00125V5325V53 Deaerator Vent StackActive38SV 037Up, No CapEstimate325538717.46253.5PER 00125H125H1 StackActive39SV 038Up, No CapEstimate325436228241.83PER 00125H325H3 StackActive40SV 039Up, With CapEstimate65013960.6720PER 001EE1657EE1657 Diesel StackActive41SV 040PER 009RemovedRemoved42SV 041PER 009RemovedRemoved43SV 042Up, No CapEstimate350672586.9213.25PER 00726H21&41#5 SRU 26 Unit StackActive44SV 043PER 009RemovedRemoved45SV 044Up, No CapEstimate300188013.65150PER 00127H10127H101 StackActive46SV 045Up, No CapEstimate300188013.65150PER 00127H10227H102 StackActive47SV 046Up, No CapEstimate28014887910.28150PER 00127H127H1 StackActive48SV 047Up, No CapEstimate60094002.58150PER 00128H128H1 StackActive49SV 048Up, No CapEstimate49189763.6567PER 00131H131H1 StackActive50SV 049Up, No CapEstimate60064083.1361PER 00131H231H2 StackActive51SV 050Up, No CapEstimate398154904.42106.5PER 00131H431H4 StackActive52SV 051Up, No CapEstimate25025992.6359PER 00131H531H5 StackActive53SV 052Up, No CapEstimate750196473.594PER 00131H731H7 StackActive54SV 053Up, No CapEstimate460218473.4494.5PER 00131H831H8 StackActivePage 2 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus55SV 054Up, No CapEstimate514120902.9781.5PER 00131H931H9 StackActive56SV 055Up, No CapEstimate440201114.5100PER 00131H1031H10 StackActive57SV 056PER 009RemovedRemoved58SV 057PER 009RemovedRemoved59SV 058PER 009RemovedRemoved60SV 059PER 009RemovedRemoved61SV 060PER 009RemovedRemoved62SV 061PER 009RemovedRemoved63SV 062PER 009RemovedRemoved64SV 063PER 009RemovedRemoved65SV 064PER 009RemovedRemoved66SV 065PER 009RemovedRemoved67SV 066Up, No CapEstimate325538688.96205PER 00132H532H5 6 7 StackActive68SV 067Up, With CapEstimate5756020371PER 00132H9_132H9 StackActive69SV 068Up, With CapEstimate4507330.2527.5PER 00132H9_2Powerform Cat Reg StackActive70SV 069PER 009RemovedRemoved71SV 070PER 009RemovedRemoved72SV 071PER 009RemovedRemoved73SV 072PER 009RemovedRemoved74SV 073Up, No CapEstimate469498256100PER 00133H433H1 2 Stack (33H4)Active75SV 074Up, No CapEstimate445390986.46183PER 00133H3133H31 StackActive76SV 075Up, No CapEstimate539338714.71184.13PER 00133H3233H32 StackActive77SV 076PER 009RemovedRemoved78SV 077PER 009RemovedRemoved79SV 078Up, No CapContinuous Monitor550285785.17176.25PER 00134H334H2 Stack (34H3 is stack)Active80SV 078Up, No CapContinuous Monitor550285785.17176.25PER 01234H334H2 Stack (34H3 is stack)Removed81SV 079PER 009RemovedRemovedPage 3 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus82SV 080PER 009RemovedRemoved83SV 081PER 009RemovedRemoved84SV 082Up, No CapEstimate309234823.31200PER 00137H137H1 2 6 StackActive85SV 083Up, No CapEstimate3508724311.21269PER 00137H337H3 4 5 StackActive86SV 084DownEstimate90010110.5142PER 00137H4Plat Cat Reg StackActive87SV 085Up, No CapEstimate65015880.526PER 001EE1309EE1309 Diesel StackActive88SV 086PER 001DELETERemoved89SV 087Up, No CapEstimate55093082.42150PER 00138H1A38H1A StackActive90SV 088Up, No CapEstimate55093082.42150PER 00138H1B38H1B StackActive91SV 089Up, No CapEstimate309183132.75200PER 00138H238H2 StackActive92SV 090PER 001DELETERemoved93SV 091PER 009RemovedRemoved94SV 092PER 009RemovedRemoved95SV 093Up, No CapContinuous Monitor525536424.75200PER 00145H6145H61 StackActive96SV 094Up, No CapEstimate60048793.33176.1PER 00145H645H6 StackActive97SV 095PER 007REMOVEDRemoved98SV 096Up, With CapEstimate65016430.8320PER 00971C11_1RemovedRemoved99SV 097Up, With CapEstimate65016430.8320PER 00971C11_271C11 Diesel StackActive100SV 098HorizontalEstimate65014680.3315PER 00181P44481P444 Diesel StackActive101SV 099Up, No CapEstimate6505870.3315PER 00181P8981P89 Diesel StackActive102SV 100Up, With CapEstimate65012690.6718PER 00181P15981P159 Diesel StackActive103SV 101Up, No CapEstimate6504110.3314PER 00993P160RemovedRemoved104SV 102HorizontalEstimate65011620.6720PER 00181P35781P357 Diesel StackActive105SV 103HorizontalEstimate65014680.8320PER 00981P450RemovedRemoved106SV 104Up, No Cap3.5232PER 00184ME3North Flare StackActive107SV 105Up, No Cap3250PER 00184ME23East Flare StackActive108SV 106Up, No Cap3250PER 00184ME24West Flare StackActivePage 4 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus109SV 107Up, No Cap4.5395PER 00984ME27Utility Flare StackActive110SV 108Up, With CapEstimate3505220.8353PER 00186H2786H27 StackActive111SV 109Up, With CapEstimate35010440.6761PER 00186H1586H15A B StackActive112SV 110PER 00186H186H1 StackActive113SV 111PER 009RemovedRemoved114SV 112PER 009RemovedRemoved115SV 113Up, With CapEstimate3503130.6745PER 00186H586H5 StackActive116SV 114Up, With CapEstimate35010460.8353PER 00186H1886H18A B StackActive117SV 115Up, With CapEstimate35010460.8353PER 00186H1986H19A B StackActive118SV 116Up, With CapEstimate35010460.8345PER 00186H3286H32 33 StackActive119SV 117Up, With CapEstimate3505220.8361PER 00186H2286H22 StackActive120SV 118Up, With CapEstimate35010460.8361PER 00186H2486H24A B StackActive121SV 119Up, With CapEstimate3505220.8353PER 00186H2586H25 StackActive122SV 120Up, With CapEstimate3505220.8353PER 00186H2686H26 & 86H38 StackActive123SV 121Up, With CapEstimate35010460.8361PER 00186H3486H34 35 StackActive124SV 122Up, With CapEstimate35010460.8361PER 00186H3686H36 37 StackActive125SV 123Up, No CapNot Provided8835PER 00188H1Butane Oxidizer (88H1) StackActive126SV 124PER 009RemovedRemoved127SV 125Up, No CapEstimate1300560005.6371.7PER 00194H194H1 StackActive128SV 126HorizontalEstimate6506370.515PER 00193P40093P400 Diesel StackActive129SV 127HorizontalEstimate86616190.520PER 00193P57093P570 Diesel StackActive130SV 128Up, With CapEstimate3503130.6745PER 00186H686H6 StackActive131SV 129Up, With CapEstimate3505340.6715PER 00186H886H8 StackActive132SV 130Up, With CapEstimate35010440.6753PER 00186H1686H16A B StackActive133SV 1313008.67180PER 00811H611H6 StackActive134SV 132Estimate32039740549.5PER 00171B871B8 StackActive135SV 133Up, With CapEstimate12011201.8310.5PER 00121ME11921H-2 Decoke Pit StackActivePage 5 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus136SV 134Up, No CapEstimate2270.550PER 00125V5225V52 Deaerator Vent StackActive137SV 135Up, No Cap0.6750PER 00126ME138SRU 5 Sulfur Pit Vent StackActive138SV 136Up, No CapEstimate28014887910.28150PER 00127H50127H501 StackActive139SV 137Estimate2270.3325PER 00127V50927V509 Deaerator Vent StackActive140SV 138Up, No CapEstimate2280.1750PER 00133V4133V41 Deaerator Vent StackActive141SV 139Up, With CapEstimate35010460.8353PER 00186H1786H17A B StackActive142SV 140PER 009RemovedRemoved143SV 141PER 009RemovedRemoved144SV 142Continuous Monitor140025000740PER 00188H288H2 StackActive145SV 143Continuous Monitor1400500000840PER 00186H4186H41 StackActive146SV 144Up, With CapEstimate13015000.6758PER 001TK423TK423 Demister StackActive147SV 145Up, With CapEstimate13015000.6768PER 001TK424TK424 Demister StackActive148SV 146Up, No CapEstimate1300817009.1350PER 00194H394H3 StackActive149SV 147Up, With CapEstimate35010440.8372PER 00186H286H2 StackActive150SV 148Up, With CapEstimate1306000.550PER 00186ME254BTK019 Demister StackActive151SV 149Up, With CapEstimate1306000.550PER 00186ME252BTK029 Demister StackActive152SV 150Up, With CapEstimate13015000.6750PER 00186ME256BTK037 Demister StackActive153SV 151Up, With CapEstimate13015000.6758PER 00186ME255BTK039 Demister StackActive154SV 152Up, With CapEstimate13015000.6750PER 00186ME257BTK411 Demister StackActive155SV 153Up, With CapEstimate13015000.6750PER 00186ME258BTK412 Demister StackActive156SV 154Up, With CapEstimate13015000.6742PER 00186ME253BTK414 Demister StackActive157SV 155Up, With CapEstimate13015000.6758PER 00186ME251BTK415 Demister StackActive158SV 156Up, With CapEstimate13015000.6758PER 00186ME247BTK416 Demister StackActive159SV 157Up, With CapEstimate13015000.6750PER 00186ME249BTK417 Demister StackActive160SV 158Up, With CapEstimate13015000.6750PER 00186ME250BTK418 Demister StackActive161SV 159PER 001102H1Stack Vent at the Enclosed Flare at Bottom LoadingActive162SV 160Up, No CapEstimate170.3380PER 00117V1FCC Fresh Cat Hopper StackActivePage 6 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus163SV 161Up, No CapEstimate2003960.580PER 00117V2_2FCC Spent Cat Hopper StackActive164SV 162HorizontalEstimate10000.6710PER 00117V2_1FCC Spent Cat Baghouse StackActive165SV 163Up, No CapEstimate3505340.6715PER 00186H786H7 StackActive166SV 164Up, No CapEstimate4211222644.570PER 00971B671B6 StackActive167SV 165Up, No CapEstimate65061,6908.63133.86PER 00929H1_2Hydrocracker Feed Heater and ReboilerActive168SV 166Up, No CapEstimate311127,0129.5115PER 00930H401New Hydrogen Plant Reformer FurnaceActive169SV 167Up, With CapManufacturer957881.25110.5PER 00930UNIT_1Hydrogen Plant PSA Feed BypassActive170SV 168Up, With CapManufacturer9028171.25110.5PER 00930UNIT_2Hydrogen Plant PSA Purge BypassActive171SV 169Up, With CapManufacturer10050671.25110.5PER 00930UNIT_3Hydrogen Plant H2 Product BypassActive172SV 170PER 009EGEN401DecommissionedRemoved173SV 171Up, With CapManufacturer97365010.8529.5PER 00981P598No. 6 Cooling Tower Diesel PumpActive174SV 172Up, No CapManufacturer2129850.12530PER 00917V1817V18 Deaerator Stack VentActive175SV 173Up, No CapEstimate48752736550PER 00971B9Boiler No. 9 StackActive176SV 174Estimate21214600.3451.5PER 00937V6737V67 Deaerator Stack VentActive177SV 175PER 00971V1RemovedRemoved178SV 176Up, No CapEstimate325421516.33200PER 00225H425H4 StackActive179SV 177PER 009Process Vents Associated with Spring Lake Remediation SystemActive180SV 178PER 009Process Vents Associated with Soil Extraction Units 86H41 &88H2Active181SV 179PER 009Process Vents Associated with Misc. Remediation SystemsActive182SV 1803256.040PER 009Boiler B-10( Not Approved for Construction)Active183SV 1803256.040PER 012Boiler B-10( Not Approved for Construction)Removed184SV 181PER 009Desalter Brine StackActive185SV 182Up, No CapEstimate100030000840PER 010RGP Vapor Combustion StackActive186SV 183Up, No CapManufacturer2505433013.3190PER 01023H323H3 #3 Coker Heater StackActive187SV 184Up, No CapManufacturer2507573015.7170PER 01025H225H2 #3 Crude Heater StackActive188SV 185Up, With CapManufacturer11003570.243.9PER 011S3Sump 3 Emergency Generator Exhaust StackActive189SV 186Up, With CapManufacturer11003570.243.9PER 011S7Sump 7 Emergency Generator Exhaust StackActivePage 7 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION: STACK/VENTS (SV)ID No.Discharge DirectionFlow Rate/TemperatureInformation SourceExit GasTemperatureat Top(oF)DesignFlow Rateat Top(ACFM)Width(feet)Diameteror Length(feet)Inside DimensionsHeight ofOpeningFromGround(feet)AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemOperators DescriptionStack/VentStatus190SV 187Up, With CapManufacturer155015070.327.0PER 011LSLS Emergency Generator Exhaust StackActive191SV 188Up, No CapManufacturer1400315PER 011Temporary Portable TO StackActive192SV 189Up, No CapEstimate20019314012170PER 012CHPHRSG StackActive193SV 190Up, No CapManufacturer220103242.75195PER 012ATSATS Process UnitActivePage 8 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION:CONTROL EQUIPMENT (CE)ID No.AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemControlEquip.TypeControl Equipment DescriptionModelControlEquip.StatusManufacturerPollutantsControlledAfterburnerCombustionParametersCaptureEfficiency(%)Destruction/CollectionEfficiency(%)1CE 001PER 00100PB022048Activated Carbon AdsorptionNAActiveHAPvolVOC10010098982CE 002PER 011101H1023FlaringZCT-2-8-35-2-3/6ActiveJohn ZinkHAPvolVOC10010097.297.23CE 003PER 007102CVS001048Activated Carbon AdsorptionHAT-2500-825ActiveJohn ZinkHAPsHAPvolVOC100100100098.298.24CE 004PER 00717H2022Direct Flame Afterburner w/Heat ExchangerNAActiveAlcorn Combustion CoCOHAPsHAPvolVOCMinTemp:1650F100100100100999999995CE 005PER 00717H4022Direct Flame Afterburner w/Heat ExchangerNAActiveAlcorn Combustion CoCOHAPsHAPvolVOCMin. Temp:1650F;Res. Time:1.8 sec100100100100999999996CE 006PER 00717ME202011Electrostatic Precipitator - Medium EfficiencyN/AActiveEnvironmentalElements CorpArsenic CpBeryl CpdsChromiumMerc CpdsManganeseNickel CpLeadPMAntimonySelenium100100100100100100100100100100707070707070707070707CE 007PER 00121ME90013Gas Scrubber (General, Not Classified)NAActiveFlint Hills ResourcesSO2100508CE 008PER 001Deleted099OtherRemovedDeleted9CE 009PER 00726H21021Direct Flame AfterburnerNAActiveJohn ZinkCarbon disCarbonyl STRSMin Temp:600F; Res.Time: 1 sec10010010099999910CE 010PER 00726H41022Direct Flame Afterburner w/Heat ExchangerNAActiveJohn ZinkCarbon disCarbonyl STRSRes. Time:1.13 min10010010099999911CE 011PER 001023FlaringDELETERemovedDELETE12CE 012PER 00926V86099Other,#5 SRU Degas CVSNARemovedFlint Hills ResourcesCarbonyl STRS1001000013CE 013PER 01134H3021Direct Flame AfterburnerNAActiveCoen (burners)Carbon disCarbonyl SHAPvolTRSVOCMin. Temp:set by stacktest1001001001001009999999999Page 1 of 5MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION:CONTROL EQUIPMENT (CE)ID No.AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemControlEquip.TypeControl Equipment DescriptionModelControlEquip.StatusManufacturerPollutantsControlledAfterburnerCombustionParametersCaptureEfficiency(%)Destruction/CollectionEfficiency(%)14CE 013PER 01234H3021Direct Flame AfterburnerNARemovedCoen (burners)Carbon disCarbonyl SHAPvolTRSVOCMin. Temp:set by stacktest100100100100100999999999915CE 014PER 00134CVS001099OtherNAActiveFlint Hills ResourcesCarbon disCarbonyl STRS10010010000016CE 015PER 00786ME194015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.517CE 016PER 001Deleted099OtherNARemovedDesign by Ford Bacon& Davis18CE 017PER 00745H61021Direct Flame AfterburnerJob 110029ActiveMcGillCarbon disCarbonyl STRSMin Temp:Hot Standy;Res. Time:12.3 sec10010010099999919CE 018PER 00745H6021Direct Flame AfterburnerNAActiveContinentalCarbon disCarbonyl STRSMin Temp:1000 F;Res. Time:1.4 sec10010010099999920CE 019PER 009Removed099Other, #3 & #4 SRU Degas CVSNARemovedFlint Hills ResourcesCarbonyl STRS1001000021CE 020PER 009Removed099DeletedRemovedN/ACarbon dis0022CE 021PER 001099OtherDELETERemovedDELETECarbonyl S0023CE 022PER 00784ME3023FlaringNAActiveJohn ZinkTRSVOC100100999924CE 023PER 00784ME23023FlaringNAActiveJohn ZinkHAPsHAPvolTRSVOC1001001001009999999925CE 024PER 00784ME24023FlaringNAActiveJohn ZinkHAPsHAPvolTRSVOC1001001001009999999926CE 025PER 00784ME25023FlaringNAActiveJohn ZinkHAPsTRSVOC10010010099999927CE 026PER 00188H1021Direct Flame AfterburnerNAActiveKaldairHAPvolVOC100100989828CE 027PER 009Removed047Vapor Recovery System-Condensers, Hoods, & OtherEnclosuresNARemovedFlint Hills ResourcesVOC1000Page 2 of 5MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION:CONTROL EQUIPMENT (CE)ID No.AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemControlEquip.TypeControl Equipment DescriptionModelControlEquip.StatusManufacturerPollutantsControlledAfterburnerCombustionParametersCaptureEfficiency(%)Destruction/CollectionEfficiency(%)29CE 028PER 01194H1022Direct Flame Afterburner w/Heat ExchangerCF-4ActiveMaxon CombustfumeHAPsHAPvolVOC1001001009898.098.030CE 029PER 01194H3021Direct Flame AfterburnerNAActiveJohn ZinkHAPvolVOCMin Temp:Se by StackTest10010098.098.031CE 030PER 00123H1013Gas Scrubber (General, Not Classified)NAActiveFlint Hills ResourcesSO21005032CE 031PER 00121ME119013Gas Scrubber (General, Not Classified)NAActiveFlint Hills ResourcesSO21005033CE 033PER 00988CVS002099Other (88H2)NAActiveHAPvolVOC1001000034CE 034PER 00986CVS001099Other (86H41)NAActiveVOC100035CE 035PER 00786ME254B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.536CE 036PER 00786ME250B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.537CE 037PER 00786ME249B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.538CE 038PER 00786ME247B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.539CE 039PER 00786ME251B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.540CE 040PER 00786ME258B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.541CE 041PER 00786ME257B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.542CE 042PER 00786ME255B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.543CE 043PER 00786ME252B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.544CE 044PER 00786ME256B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.545CE 045PER 00786ME253B015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinFlexifiber Type BDActiveEntex FabricationsOpacity10099.546CE 046PER 00100PB009099OtherNAActiveFlint Hills ResourcesHAPvolVOC1001000047CE 047PER 00745H8022Direct Flame Afterburner w/Heat ExchangerPVYD-24ActiveJohn ZinkCarbon disCarbonyl STRS10010010099999948CE 048PER 00984CVS001099Other (Flare Gas Recovery Sys)NAActiveFlint Hills ResourcesHAPvolVOC1001000049CE 049PER 00100PB010099OtherNAActiveFlint Hills ResourcesHAPvolVOC1001000050CE 050PER 011102H1023FlaringZTOFActiveJohn ZinkHAPsVOC10010098.098.051CE 051PER 00194CVS015099OtherNAActiveCVSHAPvolVOC10010000Page 3 of 5MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION:CONTROL EQUIPMENT (CE)ID No.AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemControlEquip.TypeControl Equipment DescriptionModelControlEquip.StatusManufacturerPollutantsControlledAfterburnerCombustionParametersCaptureEfficiency(%)Destruction/CollectionEfficiency(%)52CE 052PER 007099OtherDELETERemovedDELETE53CE 053PER 00184UNIT2047Vapor Recovery System-Condensers, Hoods, & OtherEnclosuresNAActiveJohn ZinkHAPvolTRSVOC10010010000054CE 054PER 00194CVS013099OtherNAActiveNAHAPvolVOC1001000055CE 055PER 00786ME88015Mist Eliminator - Low Velocity, i.e., V<250 Ft/MinNAActiveNAOpacity10099.556CE 056PER 01188H2021Direct Flame AfterburnerCustomActiveJohn ZinkHAPvolVOCMi. Temp:Set byStack Test100100959557CE 057PER 01186H41021Direct Flame AfterburnerCustomActiveJohn ZinkHAPvolVOCMin. Temp:Set byStack Test10010099.9599.9558CE 058PER 009102CVS005099Other (CVS)NAActiveNAHAPvolVOC1001000059CE 059PER 00711CVS001099Other(CVS Flare from 11V45)ActiveHAPvolVOC1001000060CE 060PER 00714CVS001099Other(CVS Flare from 14V22)ActiveHAPvolVOC1001000061CE 061PER 011CT1; EU268014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinTU-12ActiveMarleyPM10PM0.001%Drift Rate0.0010.00162CE 062PER 011CT3; EU269014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinTU-12ActiveMarleyPM10PM0.001%Drift Rate0.0010.00163CE 063PER 011CT4; EU270014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinTU-12ActiveMarleyPM0.001%Drift Rate0.00164CE 064PER 011CT5; EU27014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinTU-12ActiveMarleyPM10PM0.001%Drift Rate0.0010.00165CE 065PER 011CT6; EU272014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinTU-12ActiveMarleyPM10PM0.001%Drift Rate0.0010.00166CE 066PER 001SV068050Packed-Gas Adsorption ColumnJohnson MattheyActiveFHRHyd. AcidPollutantsControlledare theChlorides1009967CE 067PER 001SV 084050Packed-Gas Adsorption ColumnJohnson MattheyActiveFHRHyd. AcidPollutantsControlledare theChlorides1009968CE 068PER 009SV 019107Selective Noncatalytic Reduction for NOXSV1500AAActiveEly EnergyNOx1009769CE 069PER 01188ME38A/B073Refrigerated CondenserActiveHAPvolVOC10010000Page 4 of 5MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:07FACILITY DESCRIPTION:CONTROL EQUIPMENT (CE)ID No.AddedBy(Action)RetiredBy(Action)OperatorIDfor ItemControlEquip.TypeControl Equipment DescriptionModelControlEquip.StatusManufacturerPollutantsControlledAfterburnerCombustionParametersCaptureEfficiency(%)Destruction/CollectionEfficiency(%)70CE 070PER 011048Activated Carbon AdsorptionActiveHAPvolVOC100100989571CE 071PER 011023FlaringKEP-100ActiveJohn ZinkVOC1009872CE 072PER 01023H3139SCR (Selective Catalytic Reduction)TBDActiveTBDNOx1007573CE 073PER 01025H2139SCR (Selective Catalytic Reduction)TBDActiveTBDNOx1008074CE 074PER 01011H6139SCR (Selective Catalytic Reduction)TBDActiveTBDNOx1007875CE 075PER 011LS203Catalytic ConverterG150LGActiveOlympianCOVOC100100989676CE 076PER 011131Thermal OxidizerTBDActiveTBDVOC> 1400F,>0.5sresidencetime1009877CE 077PER 011013Gas Scrubber (General, Not Classified)TBDActiveTBDSO21009578CE 078PER 012109Catalytic OxidizerTBDActiveTBDAcroleinBenzeneCOFormaldehyVOC100100100100100437276495179CE 079PER 012139SCR (Selective Catalytic Reduction)TBDActiveTBDNOx1008680CE 080PER 012014Mist Eliminator - High Velocity, i.e., V>250 Ft/MinCustomActiveHaldor-TopsoePM2.5PM10PM100100100107590Page 5 of 5ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d1Truck Bottom Loading (gas,distillate) including the trucksEU 004ActivePER 009CE 003CE 050CE 058SV 003 (M)SV 159 (B)102UNIT32911NANA2Truck Bottom Loading (gas,distillate) including the trucks -Loading-Unloading EquipmentEU 004ActivePER 012CE 003CE 050CE 058SV 003 (M)SV 159 (B)102UNIT32911NANA119.93#1 Crude Heater atmosphericdistillationEU 005ActivePER 009SV 004 (M)11H12911StricklandNA119.94#1 Crude Heater atmosphericdistillation - DistillationEquipmentEU 005ActivePER 012SV 004 (M)11H12911StricklandNA575#1 Crude Heater crudepreflashEU 006ActivePER 001SV 005 (M)11H22911PetrochemNA576#1 Crude Heater crudepreflash - Process HeaterEU 006ActivePER 012SV 005 (M)11H22911PetrochemNA7Emergency generator @ #1,2crude unitsEU 007ActivePER 009SV 006 (M)EE1852Energy2911CaterpillarNA603Hp8Emergency generator @ #1,2crude units - Reciprocating ICEngineEU 007ActivePER 012SV 006 (M)EE1852Energy2911CaterpillarNA603Hp9DELETEEU 008 RemovedPER 001291110DELETEEU 009 RemovedPER 001291111DELETEEU 010 RemovedPER 001291112DELETEEU 011 RemovedPER 001291113DELETEEU 012 RemovedPER 001291114DELETEEU 013 RemovedPER 001291115DELETEEU 014 RemovedPER 001291116DELETEEU 015 RemovedPER 0012911138.217Vacuum Pre-Strip HeaterEU 016ActivePER 001SV 015 (M)12H42911PetrochemNA138.218Vacuum Pre-Strip Heater -Process HeaterEU 016ActivePER 012SV 015 (M)12H42911PetrochemNA19DELETEEU 017 RemovedPER 0012911236.920#2 Vac HeaterEU 019ActivePER 001SV 017 (M)16H12911NANAPage 1 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus1EU 004PER 00901/01/1999Active2EU 004PER 01201/01/1999Active3EU 005PER 00901/01/1955Active4EU 005PER 01201/01/1955Active5EU 006PER 00101/01/1955Active6EU 006PER 01201/01/1955Active7EU 007PER 00907/31/198507/01/1985Active8EU 007PER 01207/31/198507/01/1985Active9EU 008PER 001Removed10EU 009PER 001Removed11EU 010PER 001Removed12EU 011PER 001Removed13EU 012PER 001Removed14EU 013PER 001Removed15EU 014PER 001Removed16EU 015PER 001Removed17EU 016PER 00101/01/1977Active18EU 016PER 01201/01/1977Active19EU 017PER 001Removed20EU 019PER 00101/01/1973ActivePage 1 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d236.921#2 Vac Heater - ProcessHeaterEU 019ActivePER 012SV 017 (M)16H12911NANA22DELETEEU 020 RemovedPER 001291123DELETEEU 021 RemovedPER 001291124DELETEEU 023 RemovedPER 001291125Emergency Generator @ FCCEU 024ActivePER 001SV 023 (M)EE1718Energy2911CaterpillarNA603Hp26Emergency Generator @ FCC- Reciprocating IC EngineEU 024ActivePER 012SV 023 (M)EE1718Energy2911CaterpillarNA603Hp27DELETEEU 025 RemovedPER 0012911145.628#1 Vac HeaterEU 026ActivePER 001SV 025 (M)19H12911BornNA145.629#1 Vac Heater - ProcessHeaterEU 026ActivePER 012SV 025 (M)19H12911BornNA30DELETEEU 027 RemovedPER 002291113231#1 Coker HeaterEU 028ActivePER 001SV 027 (P)SV 028 (P)21H1-12911AlcornNA13232#1 Coker Heater - ProcessHeaterEU 028ActivePER 012SV 027 (P)SV 028 (P)21H1-12911AlcornNA33DELETEEU 029 RemovedPER 001291113234#2 Coker HeaterEU 030ActivePER 001SV 029 (P)SV 030 (P)21H2-12911EconothermNA13235#2 Coker Heater - ProcessHeaterEU 030ActivePER 012SV 029 (P)SV 030 (P)21H2-12911EconothermNA36DELETEEU 031 RemovedPER 001291113237Steam/Air Heater Decoking -21H-1EU 032ActivePER 001CE 007SV 031 (M)21H1-22911NANA13238Steam/Air Heater Decoking -21H-1 - Process HeaterEU 032ActivePER 012CE 007SV 031 (M)21H1-22911NANA13239Steam/Air Heater Decoking -21H-2EU 033ActivePER 001CE 007SV 031 (M)21H2-22911NANA13240Steam/Air Heater Decoking -21H-2 - Process HeaterEU 033ActivePER 012CE 007SV 031 (M)21H2-22911NANA16541#3 Coker HeaterEU 034ActivePER 001SV 032 (M)23H1-12911Pullman KelloggNA16542#3 Coker Heater - ProcessHeaterEU 034ActivePER 012SV 032 (M)23H1-12911Pullman KelloggNAPage 2 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus21EU 019PER 01201/01/1973Active22EU 020PER 001Removed23EU 021PER 001Removed24EU 023PER 001Removed25EU 024PER 00106/30/198705/01/1987Active26EU 024PER 01206/30/198705/01/1987Active27EU 025PER 001Removed28EU 026PER 00101/01/1955Active29EU 026PER 01201/01/1955Active30EU 027PER 002Removed31EU 028PER 00101/01/1955Active32EU 028PER 01201/01/1955Active33EU 029PER 001Removed34EU 030PER 00101/01/1963Active35EU 030PER 01201/01/1963Active36EU 031PER 001Removed37EU 032PER 00101/01/1955Active38EU 032PER 01201/01/1955Active39EU 033PER 00101/01/1963Active40EU 033PER 01201/01/1963Active41EU 034PER 00101/01/1983Active42EU 034PER 01201/01/1983ActivePage 2 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d12243#3 Coker HeaterEU 035ActivePER 001SV 033 (M)23H2-12911EconothermNA12244#3 Coker Heater - ProcessHeaterEU 035ActivePER 012SV 033 (M)23H2-12911EconothermNA45Emergency Generator @ #3CokerEU 036ActivePER 001SV 034 (M)23ME26Energy2911CumminsNA685Hp46Emergency Generator @ #3Coker - Reciprocating ICEngineEU 036ActivePER 012SV 034 (M)23ME26Energy2911CumminsNA685Hp16547Steam/Air Heater Decoking23H-1EU 037ActivePER 007CE 030SV 035 (M)23H1-22911NANA16548Steam/Air Heater Decoking23H-1 - Process HeaterEU 037ActivePER 012CE 030SV 035 (M)23H1-22911NANA12249Steam/Air Heater Decoking23H-2EU 038ActivePER 007CE 030SV 036 (M)23H2-22911NANA12250Steam/Air Heater Decoking23H-2 - Process HeaterEU 038ActivePER 012CE 030SV 036 (M)23H2-22911NANA25351#3 Crude Unit Charge HeaterEU 040ActivePER 002SV 037 (M)25H12911PetrochemNA25352#3 Crude Unit Charge Heater -Process HeaterEU 040ActivePER 012SV 037 (M)25H12911PetrochemNA20653#3 Crude Unit VacPre-Fractionator HeaterEU 041ActivePER 002SV 038 (M)25H32911PetrochemNA20654#3 Crude Unit VacPre-Fractionator Heater -Process HeaterEU 041ActivePER 012SV 038 (M)25H32911PetrochemNA55Emergency Generator @ #3Crude UnitEU 042ActivePER 009SV 039 (M)EE1657Energy2911CumminsNA600Hp56Emergency Generator @ #3Crude Unit - Reciprocating ICEngineEU 042ActivePER 012SV 039 (M)EE1657Energy2911CumminsNA600Hp57DELETEEU 043 RemovedPER 001291158DELETEEU 044 RemovedPER 001291159#5 Sulfur Recovery Unit (SRU)EU 045ActivePER 009CE 008CE 009SV 042 (M)26UNIT-1Sulfur2911NANA525Tonne60#5 Sulfur Recovery Unit (SRU)- Sulfur Recovery UnitEU 045ActivePER 012CE 008CE 009SV 042 (M)26UNIT-1Sulfur2911NANA525Tonne61DELETEEU 046 RemovedPER 0012911Page 3 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus43EU 035PER 00103/31/1986Active44EU 035PER 01203/31/1986Active45EU 036PER 00106/30/198201/01/1982Active46EU 036PER 01206/30/198201/01/1982Active47EU 037PER 00701/01/1983Active48EU 037PER 01201/01/1983Active49EU 038PER 00703/31/1986Active50EU 038PER 01203/31/1986Active51EU 040PER 00206/30/198801/01/1988Active52EU 040PER 01206/30/198801/01/1988Active53EU 041PER 00206/30/198801/01/1988Active54EU 041PER 01206/30/198801/01/1988Active55EU 042PER 00906/30/198801/01/1988Active56EU 042PER 01206/30/198801/01/1988Active57EU 043PER 001Removed58EU 044PER 001Removed59EU 045PER 00906/14/199301/01/1993Active60EU 045PER 01206/14/199301/01/1993Active61EU 046PER 001RemovedPage 3 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d62SRU 5 Sulfur PitEU 047ActivePER 009CE 009CE 012SV 042 (M)26ME22Sulfur2911NANA525Tonne63SRU 5 Sulfur Pit - SulfurRecovery UnitEU 047ActivePER 012CE 009CE 012SV 042 (M)26ME22Sulfur2911NANA525Tonne64DELETEEU 048 RemovedPER 00129118465Distillate HDS RecycleHydrogen Charge HeaterEU 050ActivePER 001SV 044 (M)27H1012911Tulsa HeatersNA8466Distillate HDS RecycleHydrogen Charge Heater -Process HeaterEU 050ActivePER 012SV 044 (M)27H1012911Tulsa HeatersNA8467Distillate Hydrotreater FractntrHtrEU 051ActivePER 001SV 045 (M)27H1022911Tulsa HeatersNA8468Distillate Hydrotreater FractntrHtr - Distillation EquipmentEU 051ActivePER 012SV 045 (M)27H1022911Tulsa HeatersNA80069#2 H2 Plant Reformer HeaterEU 052ActivePER 001SV 046 (M)27H12911Multiple ManufacturersNA80070#2 H2 Plant Reformer Heater -Process HeaterEU 052ActivePER 012SV 046 (M)27H12911Multiple ManufacturersNA3471Naphtha Hydrotreater ReactorChg HtrEU 053ActivePER 001SV 047 (M)28H12911Optimized Process FurNA3472Naphtha Hydrotreater ReactorChg Htr - ReactorEU 053ActivePER 012SV 047 (M)28H12911Optimized Process FurNA2373#6 HDS Reactor ChargeHeaterEU 054ActivePER 001SV 048 (M)31H12911PetrochemNA2374#6 HDS Reactor ChargeHeater - Process HeaterEU 054ActivePER 012SV 048 (M)31H12911PetrochemNA2375#2 HDS Fractionation Heater(31H2)EU 055ActivePER 009SV 049 (M)31H22911Multiple ManufacturersNA2376#2 HDS Fractionation Heater(31H2) - FractionationEquipmentEU 055ActivePER 012SV 049 (M)31H22911Multiple ManufacturersNA7177HDS Heater (hot oil system)EU 056ActivePER 001SV 050 (M)31H42911Babcock & WilcoxNA7178HDS Heater (hot oil system) -Process HeaterEU 056ActivePER 012SV 050 (M)31H42911Babcock & WilcoxNA1079Unisar Reactor Charge HeaterEU 057ActivePER 001SV 051 (M)31H52911PetrochemNA1080Unisar Reactor Charge Heater- Process HeaterEU 057ActivePER 012SV 051 (M)31H52911PetrochemNAPage 4 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus62EU 047PER 00911/22/199301/01/1993Active63EU 047PER 01211/22/199301/01/1993Active64EU 048PER 001Removed65EU 050PER 00108/14/199301/01/1993Active66EU 050PER 01208/14/199301/01/1993Active67EU 051PER 00108/14/199301/01/1993Active68EU 051PER 01208/14/199301/01/1993Active69EU 052PER 00104/23/199301/01/1993Active70EU 052PER 01204/23/199301/01/1993Active71EU 053PER 00106/29/199301/01/1993Active72EU 053PER 01206/29/199301/01/1993Active73EU 054PER 00112/31/195501/01/1955Active74EU 054PER 01212/31/195501/01/1955Active75EU 055PER 00912/31/195501/01/1955Active76EU 055PER 01212/31/195501/01/1955Active77EU 056PER 00112/31/195501/01/1955Active78EU 056PER 01212/31/195501/01/1955Active79EU 057PER 00112/31/195501/01/1955Active80EU 057PER 01212/31/195501/01/1955ActivePage 4 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d68.481#5 HDS Charge Heater(naphtha)EU 058ActivePER 006SV 052 (M)31H72911NANA68.482#5 HDS Charge Heater(naphtha) - Process HeaterEU 058ActivePER 012SV 052 (M)31H72911NANA38.683#1 HDS Reactor ChargeHeaterEU 059ActivePER 001SV 053 (M)31H82911NANA38.684#1 HDS Reactor ChargeHeater - Process HeaterEU 059ActivePER 012SV 053 (M)31H82911NANA5085#1 HDS Fractionation HeaterEU 060ActivePER 001SV 054 (M)31H92911PetrochemNA5086#1 HDS Fractionation Heater -Fractionation EquipmentEU 060ActivePER 012SV 054 (M)31H92911PetrochemNA29.887#2 HDS Reactor ChargeHeaterEU 061ActivePER 001SV 055 (M)31H102911EconothermNA29.888#2 HDS Reactor ChargeHeater - Process HeaterEU 061ActivePER 012SV 055 (M)31H102911EconothermNA89Sour Water Collection VesselOff GasEU 062ActivePER 001CE 013SV 078 (M)31V772911NANA90Sour Water Collection VesselOff GasEU 062 RemovedPER 01231V772911NANA91Fuel Gas Supply System (47unit) BACKUP: MonitoringPoint for FG H2SEU 063 RemovedPER 00947UNIT-42911NANA92DELETEEU 064 RemovedPER 001291193DELETEEU 065 RemovedPER 001291194DELETEEU 066 RemovedPER 001291195DELETEEU 067 RemovedPER 001291196DELETEEU 068 RemovedPER 001291197DELETEEU 069 RemovedPER 001291198DELETEEU 070 RemovedPER 001291199DELETEEU 071 RemovedPER 0012911100DELETEEU 072 RemovedPER 0012911135101Powerformer Reactor ChargeHeater (Grouped with EU073/074/075)EU 073ActivePER 001SV 066 (M)32H52911PowerformerNAPage 5 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus81EU 058PER 00612/31/195501/01/1955Active82EU 058PER 01212/31/195501/01/1955Active83EU 059PER 00112/31/195501/01/1955Active84EU 059PER 01212/31/195501/01/1955Active85EU 060PER 00112/31/195501/01/1955Active86EU 060PER 01212/31/195501/01/1955Active87EU 061PER 00112/31/195501/01/1955Active88EU 061PER 01212/31/195501/01/1955Active89EU 062PER 00112/31/195501/01/1955Active90EU 062PER 01212/31/195501/01/1955Removed91EU 063PER 00912/31/1955Removed92EU 064PER 00112/31/1955Removed93EU 065PER 00112/31/1955Removed94EU 066PER 001Removed95EU 067PER 001Removed96EU 068PER 001Removed97EU 069PER 001Removed98EU 070PER 001Removed99EU 071PER 001Removed100EU 072PER 001Removed101EU 073PER 00101/01/1980ActivePage 5 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d135102Powerformer Reactor ChargeHeater (Grouped with EU073/074/075) - Process HeaterEU 073ActivePER 012SV 066 (M)32H52911PowerformerNA135103Powerformer Reactor #1Reheat Heater(Grouped withEU 073/074/075)EU 074ActivePER 001SV 066 (M)32H62911PowerformerNA135104Powerformer Reactor #1Reheat Heater(Grouped withEU 073/074/075) - ProcessHeaterEU 074ActivePER 012SV 066 (M)32H62911PowerformerNA135105Powerformer Reactor #2Reheat Heater( (Grouped withEU 073/074/075)EU 075ActivePER 001SV 066 (M)32H72911PowerformerNA135106Powerformer Reactor #2Reheat Heater( (Grouped withEU 073/074/075) - ProcessHeaterEU 075ActivePER 012SV 066 (M)32H72911PowerformerNA9107Powerformer Regenerator GasHeaterEU 076ActivePER 001SV 067 (M)32H9-12911PowerformerNA9108Powerformer Regenerator GasHeater - Process HeaterEU 076ActivePER 012SV 067 (M)32H9-12911PowerformerNA109Powerformer CatalystRegenerationEU 077ActivePER 009CE 022CE 023CE 024CE 025CE 066SV 068 (M)32H9-22911NANA110Powerformer CatalystRegeneration - RefiningEquipmentEU 077ActivePER 012CE 022CE 023CE 024CE 025CE 066SV 068 (M)32H9-22911NANA111DELETEEU 083 RemovedPER 0012911115.7112Gas Oil HDS Charge HeaterEU 084ActivePER 001SV 074 (M)33H312911PetrochemNA115.7113Gas Oil HDS Charge Heater -Process HeaterEU 084ActivePER 012SV 074 (M)33H312911PetrochemNA128.8114Gas Oil HDS FractionationCharge HeaterEU 085ActivePER 001SV 075 (M)33H322911PetrochemNA128.8115Gas Oil HDS FractionationCharge Heater - ProcessHeaterEU 085ActivePER 012SV 075 (M)33H322911PetrochemNAPage 6 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus102EU 073PER 01201/01/1980Active103EU 074PER 00101/01/1980Active104EU 074PER 01201/01/1980Active105EU 075PER 00101/01/1980Active106EU 075PER 01201/01/1980Active107EU 076PER 00101/01/1955Active108EU 076PER 01201/01/1955Active109EU 077PER 00901/01/1955Active110EU 077PER 01201/01/1955Active111EU 083PER 001Removed112EU 084PER 00101/01/1973Active113EU 084PER 01201/01/1973Active114EU 085PER 00101/01/1973Active115EU 085PER 01201/01/1973ActivePage 6 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d116DELETEEU 086 RemovedPER 0012911117DELETEEU 087 RemovedPER 0012911118DELETEEU 088 RemovedPER 0012911119DELETEEU 091 RemovedPER 001291124120Naphtha Hydrotreater ChargeHeaterEU 093ActivePER 001SV 082 (M)37H12911THINA24121Naphtha Hydrotreater ChargeHeater - Process HeaterEU 093ActivePER 012SV 082 (M)37H12911THINA33122Naphtha Hydotreater StripperReboilerEU 094ActivePER 001SV 082 (M)37H22911EconothermNA33123Naphtha Hydotreater StripperReboiler - BoilerEU 094ActivePER 012SV 082 (M)37H22911EconothermNA391.0124Platformer Charge Heater(Grouped with EU095/096/097)EU 095ActivePER 001SV 083 (M)37H32911PetrochemNA391.0125Platformer Charge Heater(Grouped with EU095/096/097) - Process HeaterEU 095ActivePER 012SV 083 (M)37H32911PetrochemNA391.0126Platformer #1Interheater(Grouped with EU095/096/097)EU 096ActivePER 001SV 083 (M)37H4-12911PetrochemNA391.0127Platformer #1Interheater(Grouped with EU095/096/097) - Process HeaterEU 096ActivePER 012SV 083 (M)37H4-12911PetrochemNA391.0128Platformer #2Interheater(Grouped with EU095/096/097)EU 097ActivePER 001SV 083 (M)37H52911PetrochemNA391.0129Platformer #2Interheater(Grouped with EU095/096/097) - Process HeaterEU 097ActivePER 012SV 083 (M)37H52911PetrochemNA33130Platformer Stabilizer ReboilerHeaterEU 098ActivePER 001SV 082 (M)37H62911EconothermNA33131Platformer Stabilizer ReboilerHeater - Process HeaterEU 098ActivePER 012SV 082 (M)37H62911EconothermNA132Platformer CatalystRegeneration VentEU 099ActivePER 009CE 022CE 023CE 024CE 025CE 067SV 084 (M)37H4-22911NANAPage 7 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus116EU 086PER 001Removed117EU 087PER 001Removed118EU 088PER 001Removed119EU 091PER 00112/31/1994Removed120EU 093PER 00101/01/1981Active121EU 093PER 01201/01/1981Active122EU 094PER 00101/01/1981Active123EU 094PER 01201/01/1981Active124EU 095PER 00101/01/1981Active125EU 095PER 01201/01/1981Active126EU 096PER 00101/01/1981Active127EU 096PER 01201/01/1981Active128EU 097PER 00101/01/1981Active129EU 097PER 01201/01/1981Active130EU 098PER 00101/01/1981Active131EU 098PER 01201/01/1981Active132EU 099PER 00901/01/1981ActivePage 7 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d133Platformer CatalystRegeneration Vent -RegeneratorEU 099ActivePER 012CE 022CE 023CE 024CE 025CE 067SV 084 (M)37H4-22911NANA134Emergency Generator atPlatformerEU 100ActivePER 001SV 085 (M)EE1309Energy2911CumminsNA685Hp135Emergency Generator atPlatformer - Reciprocating ICEngineEU 100ActivePER 012SV 085 (M)EE1309Energy2911CumminsNA685Hp136DELETEEU 101 RemovedPER 001291129137Unit 38 Gasoil HDS A-TrainHeaterEU 102ActivePER 001SV 087 (M)38H1A2911PetrochemNA29138Unit 38 Gasoil HDS A-TrainHeater - Process HeaterEU 102ActivePER 012SV 087 (M)38H1A2911PetrochemNA29139Unit 38 Gasoil HDS B-TrainHeaterEU 103ActivePER 001SV 088 (M)38H1B2911PetrochemNA29140Unit 38 Gasoil HDS B-TrainHeater - Process HeaterEU 103ActivePER 012SV 088 (M)38H1B2911PetrochemNA56141Unit 38 Gasoil HDSFractionation Charge HeaterEU 104ActivePER 001SV 089 (M)38H22911OPFNA56142Unit 38 Gasoil HDSFractionation Charge Heater -Process HeaterEU 104ActivePER 012SV 089 (M)38H22911OPFNA143DELETEEU 106 RemovedPER 0012911144DELETEEU 107 RemovedPER 0012911145DELETEEU 108 RemovedPER 0012911146Caustic Settler Off GasEU 109ActivePER 001SV 078 (M)42V162911NANA147Caustic Settler Off GasEU 109 RemovedPER 01242V162911NANA148#3 Sulfur Recovery Unit (SRU)EU 111ActivePER 001CE 016CE 018SV 093 (M)SV 094 (B)45UNIT2-1Sulfur2911NANA190Tonne149#3 Sulfur Recovery Unit (SRU)- Sulfur Recovery UnitEU 111ActivePER 012CE 016CE 018SV 093 (M)SV 094 (B)45UNIT2-1Sulfur2911NANA190Tonne150#4 Sulfur Recovery Unit (SRU)EU 112ActivePER 001CE 016CE 017SV 093 (M)45UNIT3-1Sulfur2911NANA350Tonne151#4 Sulfur Recovery Unit (SRU)- Sulfur Recovery UnitEU 112ActivePER 012CE 016CE 017SV 093 (M)45UNIT3-1Sulfur2911NANA350TonnePage 8 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus133EU 099PER 01201/01/1981Active134EU 100PER 00101/01/1982Active135EU 100PER 01201/01/1982Active136EU 101PER 001Removed137EU 102PER 00112/31/198501/01/1985Active138EU 102PER 01212/31/198501/01/1985Active139EU 103PER 00112/31/198501/01/1985Active140EU 103PER 01212/31/198501/01/1985Active141EU 104PER 00112/31/198501/01/1985Active142EU 104PER 01212/31/198501/01/1985Active143EU 106PER 001Removed144EU 107PER 001Removed145EU 108PER 001Removed146EU 109PER 00112/31/1955Active147EU 109PER 01212/31/1955Removed148EU 111PER 00112/31/197301/01/1973Active149EU 111PER 01212/31/197301/01/1973Active150EU 112PER 00112/31/197301/01/1973Active151EU 112PER 01212/31/197301/01/1973ActivePage 8 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d152SRU 3 Sulfur PitEU 113ActivePER 009CE 017CE 019SV 093 (M)SV 094 (B)TK369Sulfur2911NANA193Tonne153SRU 3 Sulfur Pit - SulfurRecovery UnitEU 113ActivePER 012CE 017CE 019SV 093 (M)SV 094 (B)TK369Sulfur2911NANA193Tonne154SRU 4 Sulfur PitEU 114ActivePER 001CE 017SV 093 (M)TK370Sulfur2911NANA350Tonne155SRU 4 Sulfur Pit - SulfurRecovery UnitEU 114ActivePER 012CE 017SV 093 (M)TK370Sulfur2911NANA350Tonne156DELETEEU 115 RemovedPER 0012911157DELETEEU 116 RemovedPER 0012911158RETIREDEU 121 RetiredPER 0072911159RETIREDEU 122 RetiredPER 0072911160RETIREDEU 123 RetiredPER 0072911161RETIREDEU 124 RetiredPER 0072911162DELETEEU 125 RemovedPER 0012911120163Steam Boiler No. 6 atBoilerhouseEU 126ActivePER 007SV 164 (M)71B62911VogtNA120164Steam Boiler No. 6 atBoilerhouse - BoilerEU 126ActivePER 012SV 164 (M)71B62911VogtNA165Plant Air Compressor DieselEngineEU 127ActivePER 001SV 096 (P)SV 097 (P)71C11Energy2911Detroit DieselNA705Hp166Plant Air Compressor DieselEngine - Reciprocating ICEngineEU 127ActivePER 012SV 096 (P)SV 097 (P)71C11Energy2911Detroit DieselNA705Hp167Diesel for Standby Circ Pumpat #3 Cooling Tower (S end)EU 128ActivePER 001SV 098 (M)81P444Energy2911CaterpillarNA630Hp168Diesel for Standby Circ Pumpat #3 Cooling Tower (S end) -Reciprocating IC EngineEU 128ActivePER 012SV 098 (M)81P444Energy2911CaterpillarNA630Hp169Diesel for Standby Circ Pumpat #3 Cooling Tower (N end)EU 129ActivePER 001SV 099 (M)81P89Energy2911CaterpillarNA325Hp170Diesel for Standby Circ Pumpat #3 Cooling Tower (N end) -Reciprocating IC EngineEU 129ActivePER 012SV 099 (M)81P89Energy2911CaterpillarNA325Hp171Diesel for Standby Circ Pumpat #4 Cooling TowerEU 130ActivePER 001SV 100 (M)81P159Energy2911CaterpillarNA546HpPage 9 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus152EU 113PER 00912/31/197301/01/1973Active153EU 113PER 01212/31/197301/01/1973Active154EU 114PER 00112/31/197301/01/1973Active155EU 114PER 01212/31/197301/01/1973Active156EU 115PER 001Removed157EU 116PER 001Removed158EU 121PER 00706/29/200601/01/1966Retired159EU 122PER 00706/29/200601/01/1966Retired160EU 123PER 00706/29/200601/01/1966Retired161EU 124PER 00706/29/200601/01/1966Retired162EU 125PER 00112/31/1999Removed163EU 126PER 00701/01/1966Active164EU 126PER 01201/01/1966Active165EU 127PER 00104/19/199301/01/1993Active166EU 127PER 01204/19/199301/01/1993Active167EU 128PER 00108/31/197601/01/1976Active168EU 128PER 01208/31/197601/01/1976Active169EU 129PER 00101/31/196201/01/1962Active170EU 129PER 01201/31/196201/01/1962Active171EU 130PER 00101/31/196701/01/1967ActivePage 9 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d172Diesel for Standby Circ Pumpat #4 Cooling Tower -Reciprocating IC EngineEU 130ActivePER 012SV 100 (M)81P159Energy2911CaterpillarNA546Hp173Diesel for Fire Water Pump at#4 Cooling TowerEU 131ActivePER 009SV 101 (M)93P160Energy2911175Hp174Diesel for Fire Water Pump at#4 Cooling Tower -Reciprocating IC EngineEU 131ActivePER 012SV 101 (M)93P160Energy2911175Hp175Diesel for Standby Circ Pumpat #5 Cooling TowerEU 132ActivePER 001SV 102 (M)81P357Energy2911CaterpillarNA500Hp176Diesel for Standby Circ Pumpat #5 Cooling Tower -Reciprocating IC EngineEU 132ActivePER 012SV 102 (M)81P357Energy2911CaterpillarNA500Hp177Diesel for Standby Circ Pumpat #6 Cooling TowerEU 133 RemovedPER 00981P450Energy2911CaterpillarNA630Hp178DELETEEU 140 RemovedPER 0012911179DELETEEU 141 RemovedPER 0012911180DELETEEU 142 RemovedPER 0012911181DELETEEU 143 RemovedPER 00129111.56182Tank 19 HeaterEU 144ActivePER 001SV 108 (M)86H272911BastexNA1.56183Tank 19 Heater - ProcessHeaterEU 144ActivePER 012SV 108 (M)86H272911BastexNA1.56184Tank 39 HeaterEU 145ActivePER 001SV 109 (M)86H15-12911NANA1.56185Tank 39 Heater - ProcessHeaterEU 145ActivePER 012SV 109 (M)86H15-12911NANA1.56186Tank 39 HeaterEU 146ActivePER 001SV 109 (M)86H15-22911NANA1.56187Tank 39 Heater - ProcessHeaterEU 146ActivePER 012SV 109 (M)86H15-22911NANA1.56188Tank 400 HeaterEU 147 RemovedPER 00986H12911Brow FintubeNA1.56189Tank 400 HeaterEU 148 RemovedPER 009SV 147 (M)86H22911Brow FintubeNA1.6190Asphalt Line HeaterEU 149ActivePER 001SV 16386H72911NANA1.6191Asphalt Line Heater - ProcessHeaterEU 149ActivePER 012SV 16386H72911NANA192DELETEEU 150 RemovedPER 0012911Page 10 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus172EU 130PER 01201/31/196701/01/1967Active173EU 131PER 00910/31/1966Active174EU 131PER 01210/31/1966Active175EU 132PER 00108/31/197901/01/1979Active176EU 132PER 01208/31/197901/01/1979Active177EU 133PER 00906/30/198801/01/1988Removed178EU 140PER 001Removed179EU 141PER 001Removed180EU 142PER 001Removed181EU 143PER 001Removed182EU 144PER 00112/31/196201/01/1962Active183EU 144PER 01212/31/196201/01/1962Active184EU 145PER 00112/31/197001/01/1970Active185EU 145PER 01212/31/197001/01/1970Active186EU 146PER 00112/31/197001/01/1970Active187EU 146PER 01212/31/197001/01/1970Active188EU 147PER 00912/31/196901/01/1969Removed189EU 148PER 00912/31/196901/01/1969Removed190EU 149PER 00112/31/1969Active191EU 149PER 01212/31/1969Active192EU 150PER 001RemovedPage 10 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d193DELETEEU 151 RemovedPER 00129110.93194Tank 402 HeaterEU 152 RemovedPER 00986H52911Brow FintubeNA0.93195Tank 403 HeaterEU 153 RemovedPER 00986H62911Brow FintubeNA1.56196Tank 410 Line HeaterEU 154 RemovedPER 00986H82911NANA1.56197Tank 410 HeaterEU 155 RemovedPER 00986H16-12911NANA1.56198Tank 410 HeaterEU 156 RemovedPER 00986H16-22911NANA1.56199Tank 411 HeaterEU 157ActivePER 001SV 13986H17-12911BastexNA1.56200Tank 411 Heater - ProcessHeaterEU 157ActivePER 01286H17-12911BastexNA1.56201Tank 411 HeaterEU 158ActivePER 001SV 13986H17-22911BastexNA1.56202Tank 411 Heater - ProcessHeaterEU 158ActivePER 012SV 13986H17-22911BastexNA1.56203Tank 412 HeaterEU 159ActivePER 001SV 114 (M)86H18-12911BastexNA1.56204Tank 412 Heater - ProcessHeaterEU 159ActivePER 012SV 114 (M)86H18-12911BastexNA1.56205Tank 412 HeaterEU 160ActivePER 001SV 114 (M)86H18-22911BastexNA1.56206Tank 412 Heater - ProcessHeaterEU 160ActivePER 012SV 114 (M)86H18-22911BastexNA1.56207Tank 413 HeaterEU 161 RemovedPER 00986H19-12911BastexNA1.56208Tank 413 HeaterEU 162 RemovedPER 00986H19-22911BastexNA1.56209Tank 414 HeaterEU 163ActivePER 001SV 116 (M)86H322911BastexNA1.56210Tank 414 Heater - ProcessHeaterEU 163ActivePER 01286H322911BastexNA1.56211Tank 414 HeaterEU 164ActivePER 001SV 116 (M)86H332911BastexNA1.56212Tank 414 Heater - ProcessHeaterEU 164ActivePER 012SV 116 (M)86H332911BastexNA1.56213Tank 415 HeaterEU 165ActivePER 001SV 117 (M)86H222911BastexNA1.56214Tank 415 Heater - ProcessHeaterEU 165ActivePER 012SV 117 (M)86H222911BastexNA1.56215Tank 416 HeaterEU 166ActivePER 001SV 118 (M)86H242911NANAPage 11 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus193EU 151PER 001Removed194EU 152PER 00912/31/196901/01/1969Removed195EU 153PER 00912/31/196901/01/1969Removed196EU 154PER 00912/31/197001/01/1970Removed197EU 155PER 00912/31/197001/01/1970Removed198EU 156PER 00912/31/197001/01/1970Removed199EU 157PER 00112/31/197001/01/1970Active200EU 157PER 01212/31/197001/01/1970Active201EU 158PER 00112/31/197001/01/1970Active202EU 158PER 01212/31/197001/01/1970Active203EU 159PER 00112/31/197001/01/1970Active204EU 159PER 01212/31/197001/01/1970Active205EU 160PER 00112/31/197001/01/1970Active206EU 160PER 01212/31/197001/01/1970Active207EU 161PER 00912/31/197001/01/1970Removed208EU 162PER 00912/31/197001/01/1970Removed209EU 163PER 00112/31/197101/01/1971Active210EU 163PER 01212/31/197101/01/1971Active211EU 164PER 00112/31/197101/01/1971Active212EU 164PER 01212/31/197101/01/1971Active213EU 165PER 00112/31/197401/01/1974Active214EU 165PER 01212/31/197401/01/1974Active215EU 166PER 00112/31/197601/01/1976ActivePage 11 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d1.56216Tank 416 Heater - ProcessHeaterEU 166ActivePER 012SV 118 (M)86H242911NANA1.56217Tank 416 HeaterEU 167ActivePER 001SV 118 (M)86H24B2911NANA1.56218Tank 416 Heater - ProcessHeaterEU 167ActivePER 012SV 118 (M)86H24B2911NANA1.56219Tank 417 HeaterEU 168ActivePER 001SV 119 (M)86H252911NANA1.56220Tank 417 Heater - ProcessHeaterEU 168ActivePER 012SV 119 (M)86H252911NANA1.56221Tank 418 HeaterEU 169ActivePER 001SV 120 (M)86H262911NANA1.56222Tank 418 Heater - ProcessHeaterEU 169ActivePER 012SV 120 (M)86H262911NANA1.56223Tank 423 HeaterEU 170ActivePER 001SV 121 (M)86H342911Thermal FintubeNA1.56224Tank 423 Heater - ProcessHeaterEU 170ActivePER 012SV 121 (M)86H342911Thermal FintubeNA1.56225Tank 423 HeaterEU 171ActivePER 001SV 121 (M)86H352911Thermal FintubeNA1.56226Tank 423 Heater - ProcessHeaterEU 171ActivePER 012SV 121 (M)86H352911Thermal FintubeNA1.56227Tank 424 HeaterEU 172ActivePER 001SV 122 (M)86H362911Thermal FintubeNA1.56228Tank 424 Heater - ProcessHeaterEU 172ActivePER 012SV 122 (M)86H362911Thermal FintubeNA1.56229Tank 424 HeaterEU 173ActivePER 009SV 122 (M)86H372911Thermal FintubeNA1.56230Tank 424 Heater - ProcessHeaterEU 173ActivePER 012SV 122 (M)86H372911Thermal FintubeNA231DELETEEU 175 RemovedPER 0012911232OSWTP - Trash Rack &Diversion Box (94ME16A)EU 177ActivePER 009SV 125 (M)94ME16A2911NANA233OSWTP - Trash Rack &Diversion Box (94ME16A) -Refining EquipmentEU 177ActivePER 012SV 125 (M)94ME16A2911NANA234OSWTP - API Oil/WaterSeparator Fore Bay (94B1A &94B1B)EU 178ActivePER 009CE 028SV 125 (M)94B1A-22911NANA235OSWTP - API Oil/WaterSeparator Fore Bay (94B1A &94B1B) - SeparationEquipmentEU 178ActivePER 012CE 028SV 125 (M)94B1A-22911NANAPage 12 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus216EU 166PER 01212/31/197601/01/1976Active217EU 167PER 00112/31/197601/01/1976Active218EU 167PER 01212/31/197601/01/1976Active219EU 168PER 00112/31/197701/01/1977Active220EU 168PER 01212/31/197701/01/1977Active221EU 169PER 00112/31/197701/01/1977Active222EU 169PER 01212/31/197701/01/1977Active223EU 170PER 00112/31/198901/01/1989Active224EU 170PER 01212/31/198901/01/1989Active225EU 171PER 00112/31/198901/01/1989Active226EU 171PER 01212/31/198901/01/1989Active227EU 172PER 00112/31/198901/01/1989Active228EU 172PER 01212/31/198901/01/1989Active229EU 173PER 00912/31/198901/01/1989Active230EU 173PER 01212/31/198901/01/1989Active231EU 175PER 00107/31/1990Removed232EU 177PER 00901/31/197701/01/1977Active233EU 177PER 01201/31/197701/01/1977Active234EU 178PER 00901/31/197701/01/1977Active235EU 178PER 01201/31/197701/01/1977ActivePage 12 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d236OSWTP - Sludge Basin 2AEU 182ActivePER 001CE 028SV 125 (M)94B2A2911NANA237OSWTP - Sludge Basin 2A -Refining EquipmentEU 182ActivePER 012CE 028SV 125 (M)94B2A2911NANA238OSWTP - Equalization Basin2BEU 183ActivePER 001CE 028SV 125 (M)94B2B2911NANA239OSWTP - Equalization Basin2B - Refining EquipmentEU 183ActivePER 012CE 028SV 125 (M)94B2B2911NANA240OSWTP - Equalization Basin2CEU 184ActivePER 001CE 028SV 125 (M)94B2C2911NANA241OSWTP - Equalization Basin2C - Refining EquipmentEU 184ActivePER 012CE 028SV 125 (M)94B2C2911NANA242OSWTP-Enhanced BiologicalTreatment Basin 94B3CEU 185ActivePER 001CE 028SV 125 (M)SV 146 (O)94B3C2911NANA243OSWTP-Enhanced BiologicalTreatment Basin 94B3C -Refining EquipmentEU 185ActivePER 012CE 028SV 125 (M)SV 146 (O)94B3C2911NANA244OSWTP - DAF Tank (old)EU 186ActivePER 001CE 028SV 125 (M)94V42911NANA245OSWTP - DAF Tank (old) -Refining EquipmentEU 186ActivePER 012CE 028SV 125 (M)94V42911NANA246OSWTP - DAF Tank (new)EU 187ActivePER 001CE 028SV 125 (M)94V212911NANA247OSWTP - DAF Tank (new) -Refining EquipmentEU 187ActivePER 012CE 028SV 125 (M)94V212911NANA248OSWTP - DAF Rapid Mix Tank(old)EU 188ActivePER 001CE 028SV 125 (M)94V22911NANA249OSWTP - DAF Rapid Mix Tank(old) - Mixing EquipmentEU 188ActivePER 012CE 028SV 125 (M)94V22911NANA250OSWTP - DAF Rapid Mix Tank(new)EU 189ActivePER 001CE 028SV 125 (M)94V192911NANA251OSWTP - DAF Rapid Mix Tank(new) - Mixing EquipmentEU 189ActivePER 012CE 028SV 125 (M)94V192911NANA252OSWTP - DAF Floc Tank (old)EU 190ActivePER 001CE 028SV 125 (M)94V32911NANA253OSWTP - DAF Floc Tank (old)- Refining EquipmentEU 190ActivePER 012CE 028SV 125 (M)94V32911NANA254OSWTP - DAF Floc Tank(new)EU 191ActivePER 001CE 028SV 125 (M)94V202911NANA255OSWTP - DAF Floc Tank(new) - Refining EquipmentEU 191ActivePER 012CE 028SV 125 (M)94V202911NANAPage 13 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus236EU 182PER 00101/31/197701/01/1977Active237EU 182PER 01201/31/197701/01/1977Active238EU 183PER 00101/31/197701/01/1977Active239EU 183PER 01201/31/197701/01/1977Active240EU 184PER 00101/31/197701/01/1977Active241EU 184PER 01201/31/197701/01/1977Active242EU 185PER 00101/01/1990Active243EU 185PER 01201/01/1990Active244EU 186PER 00101/31/197701/01/1977Active245EU 186PER 01201/31/197701/01/1977Active246EU 187PER 00112/31/198901/01/1989Active247EU 187PER 01212/31/198901/01/1989Active248EU 188PER 00101/31/197701/01/1977Active249EU 188PER 01201/31/197701/01/1977Active250EU 189PER 00112/31/198901/01/1989Active251EU 189PER 01212/31/198901/01/1989Active252EU 190PER 00101/31/197701/01/1977Active253EU 190PER 01201/31/197701/01/1977Active254EU 191PER 00112/31/198901/01/1989Active255EU 191PER 01212/31/198901/01/1989ActivePage 13 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d256OSWTP - Aerobic DigesterEU 192ActivePER 001CE 028SV 125 (M)94V142911NANA257OSWTP - Aerobic Digester -DigesterEU 192ActivePER 012CE 028SV 125 (M)94V142911NANA258DELETEEU 195 RemovedPER 0012911259OSWTP - Oily SludgeDewatering (Centrifuge)EU 197ActivePER 001CE 028SV 125 (M)SV 14694ME582911NANA260OSWTP - Oily SludgeDewatering (Centrifuge) -Refining EquipmentEU 197ActivePER 012CE 028SV 125 (M)SV 14694ME582911NANA261Diesel for Fire Water Pump atLagoonEU 198ActivePER 001SV 126 (M)93P400Energy2911CaterpillarNA650Hp262Diesel for Fire Water Pump atLagoon - Reciprocating ICEngineEU 198ActivePER 012SV 126 (M)93P400Energy2911CaterpillarNA650Hp263Diesel for Fire Water Pump atStorm/Water BasinEU 199ActivePER 001SV 127 (M)93P570Energy2911CaterpillarNA650Hp264Diesel for Fire Water Pump atStorm/Water Basin -Reciprocating IC EngineEU 199ActivePER 012SV 127 (M)93P570Energy2911CaterpillarNA650Hp265OSWTP-Equalization Basin 7AEU 200ActivePER 00194B7A2911NANA266OSWTP-Equalization Basin 7A- Refining EquipmentEU 200ActivePER 01294B7A2911NA267OSWTP-Equalization Basin 7BEU 201ActivePER 00194B7B2911NANA268OSWTP-Equalization Basin 7B- Refining EquipmentEU 201ActivePER 01294B7B2911NANA185269Steam Boiler #8EU 204ActivePER 001SV 13271B8HrSteam2911NebraskaNA150000Lb185270Steam Boiler #8 - BoilerEU 204ActivePER 012SV 13271B8HrSteam2911NebraskaNA150000Lb271Asphalt & Heavy Fuel OilTruck LoadingEU 205ActivePER 001102ME72911NANA272Asphalt & Heavy Fuel OilTruck Loading -Loading-Unloading EquipmentEU 205ActivePER 012102ME72911NANA273DELETEEU 206 RemovedPER 0012911274Barge Loading/UnloadingHeavy Product (N side)EU 207ActivePER 001SV 003103UNIT-22911NANAPage 14 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus256EU 192PER 00101/31/197701/01/1977Active257EU 192PER 01201/31/197701/01/1977Active258EU 195PER 001Removed259EU 197PER 00112/31/199001/01/1990Active260EU 197PER 01212/31/199001/01/1990Active261EU 198PER 00104/30/1983Active262EU 198PER 01204/30/1983Active263EU 199PER 00105/31/1993Active264EU 199PER 01205/31/1993Active265EU 200PER 001Active266EU 200PER 012Active267EU 201PER 001Active268EU 201PER 012Active269EU 204PER 00104/19/199301/01/1996Active270EU 204PER 01204/19/199301/01/1996Active271EU 205PER 001Active272EU 205PER 012Active273EU 206PER 00112/31/1999Removed274EU 207PER 00101/01/1972ActivePage 14 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d275Barge Loading/UnloadingHeavy Product (N side) -Barge Loading EquipmentEU 207ActivePER 012SV 003103UNIT-22911NANA276Barge Loading/UnloadingHeavy Product (S side)EU 208ActivePER 001SV 003103UNIT-32911NANA277Barge Loading/UnloadingHeavy Product (S side) -Barge Loading EquipmentEU 208ActivePER 012SV 003103UNIT-32911NANA278Track 8 Rail LoadingEU 209ActivePER 001CE 002SV 001101UNIT-12911NANA279Track 8 Rail Loading -Loading-Unloading EquipmentEU 209ActivePER 012CE 002SV 001101UNIT-12911NANA280DELETEEU 210 RemovedPER 0012911281DELETEEU 211 RemovedPER 001291141028211H-6EU 212ActivePER 010CE 074SV 13111H6HrFuel2911NANA375.2Mcf41028311H-6 - Refining EquipmentEU 212ActivePER 012CE 074SV 13111H6HrFuel2911NANA375.2Mcf475284#3 H2 HeaterEU 213ActivePER 001SV 13627H5012911TechnipNA475285#3 H2 Heater - Process HeaterEU 213ActivePER 012SV 13627H5012911TechnipNA286Equipment RequiringPerformance TestEU 214ActivePER 00100PB0032911NANA287Equipment RequiringPerformance Test - OtherEmission UnitEU 214ActivePER 01200PB0032911NANA288MACT Equipment RequiringPerformance TestEU 215ActivePER 00100PB0042911NANA289MACT Equipment RequiringPerformance Test - RefiningEquipmentEU 215ActivePER 01200PB0042911NANA290Tracks 1-7 Rail LoadingExcluding Sulfur, spent acidloadingEU 216ActivePER 001101UNIT-22911NANA291Tracks 1-7 Rail LoadingExcluding Sulfur, spent acidloading - Loading-UnloadingEquipmentEU 216ActivePER 012101UNIT-22911NANA292Sulfur LoadingEU 217ActivePER 001102UNIT-42911NANAPage 15 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus275EU 207PER 01201/01/1972Active276EU 208PER 00101/01/1972Active277EU 208PER 01201/01/1972Active278EU 209PER 00101/01/1993Active279EU 209PER 01201/01/1993Active280EU 210PER 001Removed281EU 211PER 001Removed282EU 212PER 01001/01/1999Active283EU 212PER 01201/01/1999Active284EU 213PER 00101/01/2000Active285EU 213PER 01201/01/2000Active286EU 214PER 001Active287EU 214PER 012Active288EU 215PER 001Active289EU 215PER 012Active290EU 216PER 00101/01/1993Active291EU 216PER 01201/01/1993Active292EU 217PER 001ActivePage 15 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d293Sulfur Loading -Loading-Unloading EquipmentEU 217ActivePER 012102UNIT-42911NANA294Old Oil/Water Separator at OldBottom Loading RackEU 218ActivePER 001102UNIT-52911NANA295Old Oil/Water Separator at OldBottom Loading Rack -Loading-Unloading EquipmentEU 218ActivePER 012102UNIT-52911NANA296Coke Pile Fugitive EmissionsEU 219ActivePER 001104UNIT2911297Coke Pile Fugitive Emissions -Coke Handling EquipmentEU 219ActivePER 012104UNIT2911298Pet Coke - Coke Load/PileFugitive - RailEU 220ActivePER 001104UNIT-12911299Pet Coke - Coke Load/PileFugitive - Rail - Coke HandlingEquipmentEU 220ActivePER 012104UNIT-12911300EU- Coke Load/Pile fugitive -RailEU 221ActivePER 001104UNIT-22911301EU- Coke Load/Pile fugitive -Rail - Coke HandlingEquipmentEU 221ActivePER 012104UNIT-2291130211V-45 Sludge Recycle TanksEU 222ActivePER 00111V452911NANA30311V-45 Sludge Recycle Tanks- Refining EquipmentEU 222ActivePER 01211V452911NANA30414V-22 Slop DrumEU 223ActivePER 00114V222911NANA30514V-22 Slop Drum - RefiningEquipmentEU 223ActivePER 01214V222911NANA30617A1119 VentEU 224ActivePER 00117A11192911NANA30717A1119 Vent - RefiningEquipmentEU 224ActivePER 01217A11192911NANA30817A1120 VentEU 225ActivePER 00117A11202911NANA30917A1120 Vent - RefiningEquipmentEU 225ActivePER 01217A11202911NANA31017A1132 VentEU 226ActivePER 00117A11322911NANA31117A1132 Vent - RefiningEquipmentEU 226ActivePER 01217A11322911NANA312Startup Airline PreheaterEU 227ActivePER 00117H12911NANAPage 16 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus293EU 217PER 012Active294EU 218PER 001Active295EU 218PER 012Active296EU 219PER 001Active297EU 219PER 012Active298EU 220PER 001Active299EU 220PER 012Active300EU 221PER 001Active301EU 221PER 012Active302EU 222PER 001Active303EU 222PER 012Active304EU 223PER 001Active305EU 223PER 012Active306EU 224PER 001Active307EU 224PER 012Active308EU 225PER 001Active309EU 225PER 012Active310EU 226PER 001Active311EU 226PER 012Active312EU 227PER 001ActivePage 16 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d313Startup Airline Preheater -Process HeaterEU 227ActivePER 01217H12911NANA314FCCUEU 228ActivePER 009CE 004CE 005CE 006CE 068SV 019 (M)SV 021 (B)17UNIT1Day2911Multiple ManufacturersNA90000Bbl315FCCU - Refining EquipmentEU 228ActivePER 012CE 004CE 005CE 006CE 068SV 019 (M)17UNIT1Day2911Multiple ManufacturersNA90000Bbl316RemovedEU 229 RemovedPER 0092911317FCC Fresh Catalyst Transferto HopperEU 230ActivePER 001SV 16017V1-1Hr2911NANA12.5Ton318FCC Fresh Catalyst Transferto Hopper - Material HandlingEquipmentEU 230ActivePER 012SV 16017V1-1Hr2911NANA12.5Ton319FCC Spent Catalyst Transferto HopperEU 231ActivePER 001SV 16217V2-1Hr2911NANA80Ton320FCC Spent Catalyst Transferto Hopper - Material HandlingEquipmentEU 231ActivePER 012SV 16217V2-1Hr2911NANA80Ton321FCC Spent Catalyst Transferto HopperEU 232ActivePER 001SV 16117V2-2Hr2911NANA12.5Ton322FCC Spent Catalyst Transferto Hopper - Material HandlingEquipmentEU 232ActivePER 012SV 16117V2-2Hr2911NANA12.5Ton32325V52 Deaerator VentEU 233ActivePER 001SV 13425V522911NANA32425V52 Deaerator Vent -Refining EquipmentEU 233ActivePER 012SV 13425V522911NANA32525V53 Deaerator VentEU 234ActivePER 001SV 03625V532911NANA32625V53 Deaerator Vent -Refining EquipmentEU 234ActivePER 012SV 03625V532911NANA2032726H21 Standby Incinerator forTGTU #2 Bypasses & SRU5Sulfur DegassingEU 235ActivePER 007CE 009SV 04226H212911NANA2032826H21 Standby Incinerator forTGTU #2 Bypasses & SRU5Sulfur Degassing - IncineratorEU 235ActivePER 012CE 009SV 04226H212911NANA32926H40 TGTU #2EU 236ActivePER 007SV 04226H402911NANAPage 17 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus313EU 227PER 012Active314EU 228PER 00901/01/1968Active315EU 228PER 01201/01/1968Active316EU 229PER 009Removed317EU 230PER 001Active318EU 230PER 012Active319EU 231PER 001Active320EU 231PER 012Active321EU 232PER 001Active322EU 232PER 012Active323EU 233PER 001Active324EU 233PER 012Active325EU 234PER 001Active326EU 234PER 012Active327EU 235PER 00701/01/1992Active328EU 235PER 01201/01/1992Active329EU 236PER 00701/01/1992ActivePage 17 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d33026H40 TGTU #2 - RefiningEquipmentEU 236ActivePER 012SV 04226H402911NANA36.833126H41 TGTU #2 IncineratorEU 237ActivePER 007CE 010SV 04226H412911NANA36.833226H41 TGTU #2 Incinerator -IncineratorEU 237ActivePER 012CE 010SV 04226H412911NANA33327V509 Deaerator VentEU 238ActivePER 001SV 13727V5092911NANA33427V509 Deaerator Vent -Refining EquipmentEU 238ActivePER 012SV 13727V5092911NANA335ReservedEU 239 RemovedPER 00929119336H2 Plant Vaporizer HeaterEU 240ActivePER 001SV 07333H12911SelasNA9337H2 Plant Vaporizer Heater -Process HeaterEU 240ActivePER 012SV 07333H12911SelasNA174338#1 H2 Plant Reformer/HeaterEU 241ActivePER 001SV 07333H22911SelasNA174339#1 H2 Plant Reformer/Heater -Process HeaterEU 241ActivePER 012SV 07333H22911SelasNA340Benfield OH AccumulatorEU 242ActivePER 00133V112911NANA341Benfield OH Accumulator -Refining EquipmentEU 242ActivePER 01233V112911NANA34233V41 Deaerator VentEU 243ActivePER 001SV 13833V412911NANA34333V41 Deaerator Vent -Refining EquipmentEU 243ActivePER 012SV 13833V412911NANA344Condensate StripperEU 244ActivePER 00133V672911NANA345Condensate Stripper -Stripping EquipmentEU 244ActivePER 01233V672911NANA346Merox Off Gas Incinerator (oldSRU 1/2 incinerator)EU 245ActivePER 001CE 013SV 07834H32911NANA347Merox Off Gas Incinerator (oldSRU 1/2 incinerator)EU 245 RemovedPER 01234H32911NANA34835A0001 VentEU 246ActivePER 00135A00012911NANA34935A0001 Vent - RefiningEquipmentEU 246ActivePER 01235A00012911NANA35035A0307 VentEU 247ActivePER 00135A03072911NANA35135A0307 Vent - RefiningEquipmentEU 247ActivePER 01235A03072911NANAPage 18 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus330EU 236PER 01201/01/1992Active331EU 237PER 00701/01/1992Active332EU 237PER 01201/01/1992Active333EU 238PER 001Active334EU 238PER 012Active335EU 239PER 009Removed336EU 240PER 00101/01/1973Active337EU 240PER 01201/01/1973Active338EU 241PER 00101/01/1973Active339EU 241PER 01201/01/1973Active340EU 242PER 001Active341EU 242PER 012Active342EU 243PER 001Active343EU 243PER 012Active344EU 244PER 001Active345EU 244PER 012Active346EU 245PER 00101/01/1955Active347EU 245PER 01201/01/1955Removed348EU 246PER 001Active349EU 246PER 012Active350EU 247PER 001Active351EU 247PER 012ActivePage 18 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d35235A0384/385 VentEU 248ActivePER 00135A03842911NANA35335A0384/385 Vent - RefiningEquipmentEU 248ActivePER 01235A03842911NANA35437A0461 VentEU 249ActivePER 00137A04612911NANA35537A0461 Vent - RefiningEquipmentEU 249ActivePER 01237A04612911NANA35637A0810 VentEU 250ActivePER 00137A08102911NANA35737A0810 Vent - RefiningEquipmentEU 250ActivePER 01237A08102911NANA35837A0863 VentEU 251ActivePER 00137A08632911NANA35937A0863 Vent - RefiningEquipmentEU 251ActivePER 01237A08632911NANA360Platformer Catalyst HopperVent to 37H-4EU 252ActivePER 00137H4-32911NANA361Platformer Catalyst HopperVent to 37H-4 - HopperEU 252ActivePER 01237H4-32911NANA36239A0101/102 VentEU 253ActivePER 00139A01012911NANA36339A0101/102 Vent - RefiningEquipmentEU 253ActivePER 01239A01012911NANA364Unit 94H3-Thermal OxidizerBack-upEU 254ActivePER 001CE 029CE 051SV 14694H32911365Unit 94H3-Thermal OxidizerBack-up - Other CombustionEU 254ActivePER 012CE 029CE 051SV 14694H3291136617V18 DeaeratorEU 255ActivePER 001SV 17217V18291136717V18 Deaerator - RefiningEquipmentEU 255ActivePER 012SV 17217V182911368Fuel Gas Supply System (41unit) Monitoring Point for FGH2SEU 256ActivePER 00141V332911NANA369Fuel Gas Supply System (41unit) Monitoring Point for FGH2S and sulfur - RefiningEquipmentEU 256ActivePER 01241V332911NANA37042A0456/457 VentEU 257ActivePER 00142A04562911NANA37142A0456/457 Vent - RefiningEquipmentEU 257ActivePER 01242A04562911NANAPage 19 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus352EU 248PER 001Active353EU 248PER 012Active354EU 249PER 001Active355EU 249PER 012Active356EU 250PER 001Active357EU 250PER 012Active358EU 251PER 001Active359EU 251PER 012Active360EU 252PER 001Active361EU 252PER 012Active362EU 253PER 001Active363EU 253PER 012Active364EU 254PER 001Active365EU 254PER 012Active366EU 255PER 001Active367EU 255PER 012Active368EU 256PER 001Active369EU 256PER 012Active370EU 257PER 001Active371EU 257PER 012ActivePage 19 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d37245A0453 VentEU 258ActivePER 00145A04532911NANA37345A0453 Vent - RefiningEquipmentEU 258ActivePER 01245A04532911NANA37445V-19/22 Caustic NeutralizerOff GasEU 259ActivePER 00145F02412911NANA37545V-19/22 Caustic NeutralizerOff Gas - NeutralizerEU 259ActivePER 01245F02412911NANA376Incinerator for SRU4 Bypassesof TGTU1 SRU3/4 SulfurDegassing SW TK PurgeGassingEU 260ActivePER 009CE 017SV 093SV 09445H612911NANA377Incinerator for SRU4 Bypassesof TGTU1 SRU3/4 SulfurDegassing SW TK PurgeGassing - IncineratorEU 260ActivePER 012CE 017SV 093SV 09445H612911NANA378Tail Gas Treating Unit #1(SCOT)EU 261ActivePER 001CE 01645H72911NANA379Tail Gas Treating Unit #1(SCOT) - Sulfur Recovery UnitEU 261ActivePER 012CE 01645H72911NANA380Tail Gas Treating Unit #1(SCOT) IncineratorEU 262ActivePER 001CE 04745H82911NANA381Tail Gas Treating Unit #1(SCOT) Incinerator -IncineratorEU 262ActivePER 012CE 04745H82911NANA382Fuel Gas Supply System (45unit) Monitoring Point for FGH2SEU 263ActivePER 00145V382911NANA383Fuel Gas Supply System (45unit) Monitoring Point for FGH2S and sulfur - RefiningEquipmentEU 263ActivePER 01245V382911NANA38447A0065 VentEU 264ActivePER 00147A00652911NANA38547A0065 Vent - RefiningEquipmentEU 264ActivePER 01247A00652911NANA38637V67 DeaeratorEU 265ActivePER 00137V67291138737V67 Deaerator - RefiningEquipmentEU 265ActivePER 01237V67291138871V1 DeaeratorEU 266ActivePER 00171V12911Page 20 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus372EU 258PER 001Active373EU 258PER 012Active374EU 259PER 001Active375EU 259PER 012Active376EU 260PER 00901/01/1983Active377EU 260PER 01201/01/1983Active378EU 261PER 00101/01/1981Active379EU 261PER 01201/01/1981Active380EU 262PER 00101/01/1981Active381EU 262PER 01201/01/1981Active382EU 263PER 001Active383EU 263PER 012Active384EU 264PER 001Active385EU 264PER 012Active386EU 265PER 001Active387EU 265PER 012Active388EU 266PER 001ActivePage 20 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d38971V1 Deaerator - RefiningEquipmentEU 266ActivePER 01271V1291139071ME34 Alky Driers MoistureAnalyzer VentEU 267ActivePER 00171ME342911NANA39171ME34 Alky Driers MoistureAnalyzer Vent - RefiningEquipmentEU 267ActivePER 01271ME342911NANA392No 1 Cooling TowerEU 268ActivePER 009CE 06181CT1291140,300Gal393No 1 Cooling Tower - zFugitiveEU 268ActivePER 012CE 06181CT1291140,300Gal394No 3 Cooling TowerEU 269ActivePER 009CE 06281CT3291147,800Gal395No 3 Cooling Tower - zFugitiveEU 269ActivePER 012CE 06281CT3291147,800Gal396No 4 Cooling TowerEU 270ActivePER 009CE 06381CT4291137,200Gal397No 4 Cooling Tower - zFugitiveEU 270ActivePER 012CE 06381CT4291137,200Gal398No 5 Cooling TowerEU 271ActivePER 009CE 06481CT5291137,200Gal399No 5 Cooling Tower - zFugitiveEU 271ActivePER 012CE 06481CT5291137,200Gal400No 6 Cooling TowerEU 272ActivePER 010CE 06581CT6291165,000Gal401No 6 Cooling Tower - zFugitiveEU 272ActivePER 012CE 06581CT6291165,000Gal402RemovedEU 273 RemovedPER 0092911NANA6.8403Asphalt tk Heater for tk 415EU 274ActivePER 00186H232911NANA6.8404Asphalt tk Heater for tk 415 -Process HeaterEU 274ActivePER 01286H232911NANA1.6405Asphalt tk Heater for tk 418EU 275ActivePER 00186H382911NANA1.6406Asphalt tk Heater for tk 418 -Process HeaterEU 275ActivePER 01286H382911NANA7.2407Central Buffer Zone Offgas(86H41)EU 276ActivePER 009CE 057SV 14386H41Min2911NANA1800Ft3(s)7.2408Central Buffer Zone Offgas(86H41) - Refining EquipmentEU 276ActivePER 012CE 057SV 14386H41Min2911NANA1800Ft3(s)7.2409West Buffer Zone Offgas(88H2)EU 277ActivePER 009CE 033CE 056SV 14288H2Min2911NANA1200Ft3(s)7.2410West Buffer Zone Offgas(88H2) - Refining EquipmentEU 277ActivePER 012CE 033CE 056SV 14288H2Min2911NANA1200Ft3(s)Page 21 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus389EU 266PER 012Active390EU 267PER 001Active391EU 267PER 012Active392EU 268PER 009Active393EU 268PER 012Active394EU 269PER 009Active395EU 269PER 012Active396EU 270PER 009Active397EU 270PER 012Active398EU 271PER 009Active399EU 271PER 012Active400EU 272PER 010Active401EU 272PER 012Active402EU 273PER 009Removed403EU 274PER 001Active404EU 274PER 012Active405EU 275PER 001Active406EU 275PER 012Active407EU 276PER 00901/01/1998Active408EU 276PER 01201/01/1998Active409EU 277PER 00901/01/1998Active410EU 277PER 01201/01/1998ActivePage 21 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d411OSWTP-API Oil/WaterSeparator Exit Bay (94B1A &94B1B)EU 278ActivePER 00994B1A-32911NANA412OSWTP-API Oil/WaterSeparator Exit Bay (94B1A &94B1B) - SeparationEquipmentEU 278ActivePER 01294B1A-32911NANA413OSWTP-API Oil/WaterSeparator Mid Bay 94B1A &94B1BEU 279ActivePER 00994B1B2911NANA414OSWTP-API Oil/WaterSeparator Mid Bay 94B1A &94B1B - SeparationEquipmentEU 279ActivePER 01294B1B2911NANA415OSWTP-Enhanced BiologicalTreatment Basin 94B3AEU 280ActivePER 00194B3A2911NANA416OSWTP-Enhanced BiologicalTreatment Basin 94B3A -Refining EquipmentEU 280ActivePER 01294B3A2911NANA417OSWTP-Enhanced BiologicalTreatment Basin 94B3BEU 281ActivePER 00194B3B2911NANA418OSWTP-Enhanced BiologicalTreatment Basin 94B3B -Refining EquipmentEU 281ActivePER 01294B3B2911NANA99.96419OSWTP - Thermal OxidizerEU 282ActivePER 009CE 028CE 029CE 051SV 125SV 14694H12911NANA99.96420OSWTP - Thermal Oxidizer -Other CombustionEU 282ActivePER 012CE 028CE 029CE 051SV 125SV 14694H12911NANA42194S-2A/D Slop Oil Sump atAPI Oil/Water SeparatorEU 283ActivePER 00194LT02072911NANA42294S-2A/D Slop Oil Sump atAPI Oil/Water Separator -Separation EquipmentEU 283ActivePER 01294LT02072911NANA423Phase Separator at Alt WasteHandling SiteEU 284ActivePER 00194ME1142911NANA424Phase Separator at Alt WasteHandling Site - SeparationEquipmentEU 284ActivePER 01294ME1142911NANA425Centrate SumpEU 285ActivePER 00194ME1612911NANAPage 22 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus411EU 278PER 00901/01/1977Active412EU 278PER 01201/01/1977Active413EU 279PER 00901/01/1977Active414EU 279PER 01201/01/1977Active415EU 280PER 00101/01/1977Active416EU 280PER 01201/01/1977Active417EU 281PER 00101/01/1977Active418EU 281PER 01201/01/1977Active419EU 282PER 00901/01/1990Active420EU 282PER 01201/01/1990Active421EU 283PER 00101/01/1977Active422EU 283PER 01201/01/1977Active423EU 284PER 001Active424EU 284PER 012Active425EU 285PER 00101/01/1990ActivePage 22 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d426Centrate Sump - PumpEU 285ActivePER 01294ME1612911NANA427Spring Lake: Lift StationEU 286ActivePER 00194ME872911NANA428Spring Lake: Lift Station -Loading-Unloading EquipmentEU 286ActivePER 01294ME872911NANA429Land Treatment FacilityEU 287ActivePER 00194UNIT-12911430Land Treatment Facility -Refining EquipmentEU 287ActivePER 01294UNIT-12911431Spring Lake Loading Arm forRemoval of RecoveredProductEU 288ActivePER 00194UNIT-72911NANA432Spring Lake Loading Arm forRemoval of RecoveredProduct - Loading-UnloadingEquipmentEU 288ActivePER 01294UNIT-72911NANA433Air Saturation Drum 94V22EU 289ActivePER 00194V222911NANA434Air Saturation Drum 94V22 -Separation EquipmentEU 289ActivePER 01294V222911NANA43594V-25D Wemco D CellEU 290ActivePER 00994V25D2911WemcoNA43694V-25D Wemco D Cell -Refining EquipmentEU 290ActivePER 01294V25D2911WemcoNA43794V-25E Wemco E CellEU 291ActivePER 00994V25E2911WemcoNA43894V-25E Wemco E Cell -Refining EquipmentEU 291ActivePER 01294V25E2911WemcoNA43994V-25F Wemco F CellEU 292ActivePER 00994V25F2911WemcoNA44094V-25F Wemco F Cell -Refining EquipmentEU 292ActivePER 01294V25F2911WemcoNA441Air Saturation Drum 94V5EU 293ActivePER 00194V52911NANA442Air Saturation Drum 94V5 -Separation EquipmentEU 293ActivePER 01294V52911NANA141443Hydrocracker Feed HeaterEU 294ActivePER 001SV 165 (M)29H-12911141444Hydrocracker Feed Heater -Process HeaterEU 294ActivePER 012SV 165 (M)29H-12911100445Hydrocracker ReboilerEU 295ActivePER 001SV 165 (M)29H-22911100446Hydrocracker Reboiler - BoilerEU 295ActivePER 012SV 165 (M)29H-22911Page 23 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus426EU 285PER 01201/01/1990Active427EU 286PER 00101/01/1998Active428EU 286PER 01201/01/1998Active429EU 287PER 001Active430EU 287PER 012Active431EU 288PER 001Active432EU 288PER 012Active433EU 289PER 00101/01/1990Active434EU 289PER 01201/01/1990Active435EU 290PER 00901/01/1990Active436EU 290PER 01201/01/1990Active437EU 291PER 00901/01/1990Active438EU 291PER 01201/01/1990Active439EU 292PER 00901/01/1990Active440EU 292PER 01201/01/1990Active441EU 293PER 00101/01/1977Active442EU 293PER 01201/01/1977Active443EU 294PER 001Active444EU 294PER 012Active445EU 295PER 001Active446EU 295PER 012ActivePage 23 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d900447No. 4 Hydrogen PlantReformerEU 296ActivePER 001SV 166 (M)30H-4012911900448No. 4 Hydrogen PlantReformer - RefiningEquipmentEU 296ActivePER 012SV 166 (M)30H-4012911449Hydrogen Plant PSA FeedEU 297ActivePER 001SV 167 (B)30UNIT_12911450Hydrogen Plant PSA Feed -Other Emission UnitEU 297ActivePER 012SV 167 (B)30UNIT_12911451Hydrogen Plant PSA PurgeEU 298ActivePER 001SV 168 (B)30UNIT_22911452Hydrogen Plant PSA Purge -Other Emission UnitEU 298ActivePER 012SV 168 (B)30UNIT_22911453Hydrogen Plant H2 ProductEU 299ActivePER 001SV 169 (B)30UNIT_32911454Hydrogen Plant H2 Product -Other Emission UnitEU 299ActivePER 012SV 169 (B)30UNIT_329112.545584ME23 E. 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Flare - zControlEU 304ActivePER 012SV 104 (M)84ME32911463Light Plant #1EU 305ActivePER 001Diesel0012911464Light Plant #1 - RefiningEquipmentEU 305ActivePER 012Diesel0012911465Light Plant #2EU 306ActivePER 001Diesel0022911466Light Plant #2 - RefiningEquipmentEU 306ActivePER 012Diesel0022911467Light Plant #3EU 307ActivePER 001Diesel0032911468Light Plant #3 - RefiningEquipmentEU 307ActivePER 012Diesel0032911469Compressor #1EU 308ActivePER 001Diesel0042911Page 24 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus447EU 296PER 001Active448EU 296PER 012Active449EU 297PER 001Active450EU 297PER 012Active451EU 298PER 001Active452EU 298PER 012Active453EU 299PER 001Active454EU 299PER 012Active455EU 301PER 009Active456EU 301PER 012Active457EU 302PER 009Active458EU 302PER 012Active459EU 303PER 009Active460EU 303PER 012Active461EU 304PER 009Active462EU 304PER 012Active463EU 305PER 001Active464EU 305PER 012Active465EU 306PER 001Active466EU 306PER 012Active467EU 307PER 001Active468EU 307PER 012Active469EU 308PER 001ActivePage 24 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d470Compressor #1 - CompressorEU 308ActivePER 012Diesel0042911471FW Pump #1EU 309ActivePER 001Diesel0052911472FW Pump #1 - PumpEU 309ActivePER 012Diesel0052911473FW Pump #2EU 310ActivePER 001Diesel0062911474FW Pump #2 - PumpEU 310ActivePER 012Diesel0062911475Main Control PilotsEU 311ActivePER 00141FE00072911476Main Control Pilots - OtherEmission UnitEU 311ActivePER 01241FE00072911477No. 6 Cooling Tower DieselPumpEU 312ActivePER 009SV 17181P598Energy29111155Hp478No. 6 Cooling Tower DieselPump - Reciprocating ICEngineEU 312ActivePER 012SV 17181P598Energy29111155Hp479Steam Boiler No. 9EU 313ActivePER 009SV 17371B92911480Steam Boiler No. 9 - BoilerEU 313ActivePER 012SV 17371B92911481Oily Sludge Storage VesselEU 314ActivePER 00194V262911482Oily Sludge Storage Vessel -Material Handling EquipmentEU 314ActivePER 01294V262911483Vac Trucks at FHREU 315ActivePER 00100PB0952911484Vac Trucks at FHR - OtherEmission UnitEU 315ActivePER 01200PB0952911485FHR Lab InsideEU 316ActivePER 001113Unit_12911486FHR Lab Inside - OtherEmission UnitEU 316ActivePER 012113Unit_12911487FHR Lab OutdoorsEU 317ActivePER 001113Unit_22911488FHR Lab Outdoors - OtherEmission UnitEU 317ActivePER 012113Unit_22911489Unit 26 CO2EU 318ActivePER 00146 Unit_12911490Unit 26 CO2 - RefiningEquipmentEU 318ActivePER 01246 Unit_12911491Non Contact Cooling WaterSystemsEU 319ActivePER 00900PB0962911Page 25 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus470EU 308PER 012Active471EU 309PER 001Active472EU 309PER 012Active473EU 310PER 001Active474EU 310PER 012Active475EU 311PER 001Active476EU 311PER 012Active477EU 312PER 009Active478EU 312PER 012Active479EU 313PER 00901/05/2006Active480EU 313PER 01201/05/2006Active481EU 314PER 001Active482EU 314PER 012Active483EU 315PER 001Active484EU 315PER 012Active485EU 316PER 001Active486EU 316PER 012Active487EU 317PER 001Active488EU 317PER 012Active489EU 318PER 001Active490EU 318PER 012Active491EU 319PER 009ActivePage 25 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d492Non Contact Cooling WaterSystems - CoolerEU 319ActivePER 01200PB0962911493Storm SewersEU 320ActivePER 00100SWS2911494Storm Sewers - OtherEmission UnitEU 320ActivePER 01200SWS2911495Natural Gas PoolEU 321ActivePER 00100PB0482911496Natural Gas Pool - OtherEmission UnitEU 321ActivePER 01200PB0482911497Fuel Gas PoolEU 322ActivePER 00100PB0492911498Fuel Gas Pool - MaterialHandling EquipmentEU 322ActivePER 01200PB0492911499API SeparatorEU 323ActivePER 00194B1A_12911500API Separator - SeparationEquipmentEU 323ActivePER 01294B1A_12911163501#3 Crude Unit Vacuum HeaterEU 324ActivePER 002SV 17625H-42911163502#3 Crude Unit Vacuum Heater- Process HeaterEU 324ActivePER 012SV 17625H-42911503Temporary Coke Crusher #1EU 325ActivePER 008HrCoke2911Pioneer4250150Ton504Temporary Coke Crusher #1 -CrusherEU 325ActivePER 012HrCoke2911Pioneer4250150Ton505Temporary Coke Crusher #2EU 326ActivePER 008HrCoke2911Pioneer4233100Ton506Temporary Coke Crusher #2 -CrusherEU 326ActivePER 012HrCoke2911Pioneer4233100Ton507OSWTP- Dissolved NitrogenFloatation UnitEU 327ActivePER 00994ME3242911508OSWTP- Dissolved NitrogenFloatation Unit - DissolverEU 327ActivePER 01294ME32429111955509Poly Unit De-PropanizerEU 328ActivePER 00943V-52911The Fluor CorporationL1955510Poly Unit De-Propanizer -Other Emission UnitEU 328ActivePER 01243V-52911The Fluor CorporationL511Sat Gas De-PropanizerEU 329ActivePER 00943V-192911Sauder Custom Fab512Sat Gas De-Propanizer - OtherEmission UnitEU 329ActivePER 01243V-192911Sauder Custom Fab1960513Alky Unit De-PropanizerEU 330ActivePER 00935V-22911Flint Steel CorpPage 26 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus492EU 319PER 012Active493EU 320PER 001Active494EU 320PER 012Active495EU 321PER 001Active496EU 321PER 012Active497EU 322PER 001Active498EU 322PER 012Active499EU 323PER 001Active500EU 323PER 012Active501EU 324PER 002Active502EU 324PER 012Active503EU 325PER 008Active504EU 325PER 012Active505EU 326PER 008Active506EU 326PER 012Active507EU 327PER 009Active508EU 327PER 012Active509EU 328PER 009Active510EU 328PER 012Active511EU 329PER 009Active512EU 329PER 012Active513EU 330PER 009ActivePage 26 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d1960514Alky Unit De-Propanizer -Separation EquipmentEU 330ActivePER 01235V-22911Flint Steel Corp515Containers/Vac Trucks/FracTanks used for managingremediation wastesEU 331ActivePER 0092911516Containers/Vac Trucks/FracTanks used for managingremediation wastes - MaterialHandling EquipmentEU 331ActivePER 0122911517Transfer Systems Associatedwith Remediation SystemsEU 332ActivePER 0092911518Transfer Systems Associatedwith Remediation Systems -Material Handling EquipmentEU 332ActivePER 01229115191st & A GroundwaterRemediation Knockout Pot86V22EU 333ActivePER 00986V2229115201st & A GroundwaterRemediation Knockout Pot86V22 - Refining EquipmentEU 333ActivePER 01286V222911521Coke Drum System A and BEU 334ActivePER 00921Unit_12911522Coke Drum System A and B -Coke Handling EquipmentEU 334ActivePER 01221Unit_12911523Coke Drum System C and DEU 335ActivePER 00921Unit_22911524Coke Drum System C and D -Coke Handling EquipmentEU 335ActivePER 01221Unit_22911525Coke Drum System E and FEU 336ActivePER 00923Unit2911526Coke Drum System E and F -Coke Handling EquipmentEU 336ActivePER 01223Unit2911527Boiler B-10 (Not Approved forConstruction)EU 337ActivePER 009SV 1802911528Boiler B-10 (Not Approved forConstruction)EU 337 RemovedPER 0122911529Octane Comparator at KnockEngine Building (52ME2BEU 338ActivePER 00952Unit2911530Octane Comparator at KnockEngine Building (52ME2B) -Refining EquipmentEU 338ActivePER 01252Unit2911Page 27 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus514EU 330PER 012Active515EU 331PER 009Active516EU 331PER 012Active517EU 332PER 009Active518EU 332PER 012Active519EU 333PER 009Active520EU 333PER 012Active521EU 334PER 009Active522EU 334PER 012Active523EU 335PER 009Active524EU 335PER 012Active525EU 336PER 009Active526EU 336PER 012Active527EU 337PER 009Active528EU 337PER 012Removed529EU 338PER 009Active530EU 338PER 012ActivePage 27 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d531Octane Comparator at KnockEngine Building (52ME91EU 339ActivePER 00952Unit2911532Octane Comparator at KnockEngine Building (52ME91) -Refining EquipmentEU 339ActivePER 01252Unit2911533Octane Comparator at KnockEngine Building (52ME92EU 340ActivePER 00952Unit2911534Octane Comparator at KnockEngine Building (52ME92) -Refining EquipmentEU 340ActivePER 01252Unit2911535Octane Comparator at KnockEngine Building (52ME2AEU 341ActivePER 00952Unit2911536Octane Comparator at KnockEngine Building (52ME2A) -Refining EquipmentEU 341ActivePER 01252Unit2911537Octane Comparator at KnockEngine Building (52ME65BEU 342ActivePER 00952Unit2911538Octane Comparator at KnockEngine Building (52ME65B) -Refining EquipmentEU 342ActivePER 01252Unit2911539Octane Comparator at KnockEngine Building (52ME93EU 343ActivePER 00952Unit2911540Octane Comparator at KnockEngine Building (52ME93) -Refining EquipmentEU 343ActivePER 01252Unit2911541Octane Comparator at KnockEngine Building (52ME65AEU 344ActivePER 00952Unit2911542Octane Comparator at KnockEngine Building (52ME65A) -Refining EquipmentEU 344ActivePER 01252Unit2911543Desalter Brine API 94ME259AEU 345ActivePER 009SV 18194ME259AWastewater2911SiemensCustom544Desalter Brine API 94ME259A- Refining EquipmentEU 345ActivePER 012SV 18194ME259AWastewater2911SiemensCustom545Desalter Brine API 94ME259BEU 346ActivePER 009SV 18194ME259BWastewater2911SiemensCustom546Desalter Brine API 94ME259B- Refining EquipmentEU 346ActivePER 012SV 18194ME259BWastewater2911SiemensCustom547Equalization Basin 94V49EU 347ActivePER 00994V49Wastewater2911CB&ICustom1.5Page 28 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus531EU 339PER 009Active532EU 339PER 012Active533EU 340PER 009Active534EU 340PER 012Active535EU 341PER 009Active536EU 341PER 012Active537EU 342PER 009Active538EU 342PER 012Active539EU 343PER 009Active540EU 343PER 012Active541EU 344PER 009Active542EU 344PER 012Active543EU 345PER 00901/01/201101/01/2007Active544EU 345PER 01201/01/201101/01/2007Active545EU 346PER 00901/01/201101/01/2007Active546EU 346PER 01201/01/201101/01/2007Active547EU 347PER 00901/01/201201/01/2011ActivePage 28 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d548Equalization Basin 94V49 -Above Ground Storage TankEU 347ActivePER 01294V49Wastewater2911CB&ICustom1.5549CE-45H6:SRU#3 BypassIncineratorEU 348ActivePER 0092911550CE-45H6:SRU#3 BypassIncinerator - IncineratorEU 348ActivePER 0122911551CE-88H1:Butane StorageTankEU 349ActivePER 0092911552CE-88H1:Butane StorageTank - Above Ground StorageTankEU 349ActivePER 0122911553RGP Railcar Loading RackEU 350ActivePER 010CE 071SV 182 (M)HrProduct29111125Bbl554RGP Railcar Loading Rack -Loading-Unloading EquipmentEU 350ActivePER 012CE 071SV 182 (M)HrProduct29111125Bbl555RGP Vapor Combustion UnitEU 351ActivePER 010CE 071SV 182 (M)HrProduct2911John ZinkKEP-10055Mmbtu556RGP Vapor Combustion Unit -Other CombustionEU 351ActivePER 012CE 071SV 182 (M)HrProduct2911John ZinkKEP-10055Mmbtu26455723H3 HeaterEU 352ActivePER 010CE 072SV 183 (M)23H3HrFuel2911TBDTBD241.6Mcf26455823H3 Heater - Process HeaterEU 352ActivePER 012CE 072SV 183 (M)23H3HrFuel2911TBDTBD241.6Mcf32655925H2 HeaterEU 353ActivePER 010CE 073SV 184 (M)25H2HrFuel2911TBDTBD319.6Mcf32656025H2 Heater - Process HeaterEU 353ActivePER 012CE 073SV 184 (M)25H2HrFuel2911TBDTBD319.6Mcf561No 7 Cooling TowerEU 354ActivePER 010#7CTMinWater2911TBDTBD40000Gal562No 7 Cooling Tower - zFugitiveEU 354ActivePER 012#7CTMinWater2911TBDTBD40000Gal0.75563Sump 3 Emergency GeneratorEU 355ActivePER 011SV 185 (M)S3Elect Energy2911OlympianG50LG50Kw0.75564Sump 3 Emergency Generator- Reciprocating IC EngineEU 355ActivePER 012SV 185 (M)S3Elect Energy2911OlympianG50LG50Kw0.75565Sump 7 Emergency GeneratorEU 356ActivePER 011SV 186 (M)S7Elect Energy2911OlympianG50LG50Kw0.75566Sump 7 Emergency Generator- Reciprocating IC EngineEU 356ActivePER 012SV 186 (M)S7Elect Energy2911OlympianG50LG50Kw1.94567Lift Station EmergencyGeneratorEU 357ActivePER 011CE 075SV 187 (M)LSElect Energy2911OlympianG150LG150Kw1.94568Lift Station EmergencyGenerator - Reciprocating ICEngineEU 357ActivePER 012CE 075SV 187 (M)LSElect Energy2911OlympianG150LG150KwPage 29 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus548EU 347PER 01201/01/201201/01/2011Active549EU 348PER 009Active550EU 348PER 012Active551EU 349PER 009Active552EU 349PER 012Active553EU 350PER 01006/01/201402/01/2013Active554EU 350PER 01206/01/201402/01/2013Active555EU 351PER 01006/01/201402/01/2013Active556EU 351PER 01206/01/201402/01/2013Active557EU 352PER 010Active558EU 352PER 012Active559EU 353PER 010Active560EU 353PER 012Active561EU 354PER 010Active562EU 354PER 012Active563EU 355PER 011Active564EU 355PER 012Active565EU 356PER 011Active566EU 356PER 012Active567EU 357PER 011Active568EU 357PER 012ActivePage 29 of 30 (b)ST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name:MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROAD11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)MaxFuelInput(mil Btu)Flint Hills Resources Pine Bend RefineryRetiredBy(Action)Operator DescriptionID No.EmissionUnitStatusAddedBy(Action)ControlEquip.ID No(s).Stack/VentID No(s).OperatorIDfor ItemInsignificantActivitySICManufacturerModelNumberMax.DesignCapacityMaximumDesignCapacityMaterials Units nUnits d569Temporary Portable ThermalOxidizer(s)EU 358ActivePER 011CE 076CE 077SV 188 (M)Hr2911TBDTBD40Mmbtu570Temporary Portable ThermalOxidizer(s) - OtherCombustionEU 358ActivePER 012CE 076CE 077SV 188 (M)Hr2911TBDTBD40Mmbtu434.5571Combustion Turbine - TurbineEU 359ActivePER 012CE 078CE 079SV 189 (M)CTGHrElect Energy2911GELM-6000PF434500Mmbtu239.1572Duct Burners - Duct BurnerEU 360ActivePER 012CE 078CE 079SV 189 (M)HrEnergy2911TBDTBD239100Mmbtu43.8573ATS Process Unit - RefiningEquipmentEU 361ActivePER 012CE 080SV 190 (M)ATSDay2911Haldor-TopsoeCustom400Ton574Portable Diesel Engines -Reciprocating IC EngineEU 362ActivePER 0122911variousvariousPage 30 of 30 (a)11 December, 2014 16:07FACILITY DESCRIPTION: EMISSION UNIT (EU)ID No.ElevatorTypeBottleneckPct.Fuel/SpaceHeatFiring MethodAddedBy(Action)RemovalDateInitialStartupDateCommenceConst.DateEmissionUnitStatus569EU 358PER 011Active570EU 358PER 012Active571EU 359PER 01210/01/201603/01/2015Active572EU 360PER 01210/01/201603/01/2015Active573EU 361PER 01209/01/201604/01/2015Active574EU 362PER 012ActivePage 30 of 30 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK11TK 001630048 150 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK22TK 002630048 150 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK33TK 003630048 150 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK44TK 004630048 150 Exterior Floating Roof W/Welded TankSActivePER 009Organic LiquidTK55TK 0051127748 200 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK66TK 0062209248 280 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK77TK 0072212848 280 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK108TK 010504048 134 Internal Floating RoofActivePER 001Organic LiquidTK119TK 011504048 134 Internal Floating RoofActivePER 001Organic LiquidTK1210TK 012504048 134 Internal Floating RoofActivePER 001Organic LiquidTK1311TK 013504048 134 Internal Floating RoofActivePER 001Organic LiquidTK1412TK 014178548 80 Internal Floating RoofActivePER 001Organic LiquidTK1513TK 015178548 80 Internal Floating RoofActivePER 001Organic LiquidTK1614TK 016178548 80 Internal Floating RoofActivePER 001Organic LiquidTK1715TK 017178548 80 Internal Floating RoofActivePER 001Organic LiquidTK1816TK 018504048 134 Internal Floating RoofActivePER 001Organic LiquidTK1917TK 019142848 60 Fixed RoofActivePER 009AsphaltTK2118TK 021178548 80 Fixed RoofActivePER 001Organic LiquidTK2219TK 022178548 80 Fixed RoofActivePER 001Organic LiquidTK2320TK 023178548 80 Internal Floating RoofActivePER 004Organic LiquidTK2421TK 024126048 67 Internal Floating RoofActivePER 001Organic LiquidTK2522TK 025126048 67 Internal Floating RoofActivePER 001Organic LiquidTK2623TK 026126648 67 Internal Floating RoofActivePER 001Organic LiquidTK2724TK 027126048 67 Internal Floating RoofActivePER 001Organic LiquidTK2825TK 028281448 100 Internal Floating RoofActivePER 001Organic LiquidTK2926TK 029178548 80CE 043Fixed RoofActivePER 007AsphaltTK3027TK 03084040 60 Fixed RoofActivePER 001Organic LiquidPage 1 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus1TK 0011955Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive2TK 0021955Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive3TK 0031955Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive4TK 0041955Mechanical (metallic shoe seal), with shoe moPER 009WeldedActive5TK 0051961Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive6TK 0061979Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive7TK 0071979Mechanical (metallic shoe seal), with shoe moPER 00101WeldedActive8TK 0101954Mechanical (metallic shoe seal), primary onlyPER 00181WeldedActive9TK 0111955Mechanical (metallic shoe seal), with shoe moPER 00181WeldedActive10TK 0121954Mechanical (metallic shoe seal), with shoe moPER 00181WeldedActive11TK 0131955Mechanical (metallic shoe seal), with shoe moPER 001 Column Supported Roof, Construction TypeN81WeldedActive12TK 0141955Mechanical (metallic shoe seal), primary onlyPER 00111WeldedActive13TK 0151955Mechanical (metallic shoe seal), with shoe moPER 00111WeldedActive14TK 0161955Mechanical (metallic shoe seal), with shoe moPER 00111WeldedActive15TK 0171955Mechanical (metallic shoe seal), with shoe moPER 00111WeldedActive16TK 0181960Mechanical (metallic shoe seal), primary onlyPER 00181WeldedActive17TK 0191962PER 009Active18TK 0211955PER 001Active19TK 0221955PER 001Active20TK 0231955PER 004Active21TK 0241955Mechanical (metallic shoe seal), primary onlyPER 00111WeldedActive22TK 0251955Mechanical (metallic shoe seal), primary onlyPER 00111WeldedActive23TK 0261954Mechanical (metallic shoe seal), with shoe moPER 00111WeldedActive24TK 0271954Mechanical (metallic shoe seal), with shoe moPER 00111WeldedActive25TK 0281958Mechanical (metallic shoe seal), primary onlyPER 00161WeldedActive26TK 0291962PER 007Active27TK 0301954PER 001ActivePage 1 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK3128TK 03184040 60 Fixed RoofActivePER 001Organic LiquidTK3329TK 033260448 100 Fixed RoofActivePER 001Organic LiquidTK3430TK 03412624 30 Fixed RoofRetiredPER 009Organic LiquidTK3531TK 03542036 45 Fixed RoofActivePER 001Organic LiquidTK3632TK 03642036 45 Fixed RoofRemovedPER 009SludgeTK3733TK 037504048 134CE 044Fixed RoofActivePER 007AsphaltTK3834TK 03847544 42 Fixed RoofActivePER 001Organic LiquidTK3935TK 039294056 95CE 042Fixed RoofActivePER 007AsphaltTK4636TK 046126048 70 Fixed RoofActivePER 001Organic LiquidTK4737TK 047226848 90 Fixed RoofActivePER 009Organic LiquidTK4838TK 048420048 125 Internal Floating RoofActivePER 001Organic LiquidTK4939TK 049420048 125 Internal Floating RoofActivePER 001Organic LiquidTK5040TK 05031534 40 Fixed RoofRemovedPER 009NaphthaTK5141TK 05131534 40 Fixed RoofRemovedPER 009NaphthaTK5242TK 05242040 43 Fixed RoofRetiredPER 009Organic Liquid Strorage TankTK5343TK 05321030 35 Fixed RoofRemovedPER 009Regular Stock ReformateTK5444TK 05421020 35 Fixed RoofRemovedPER 009Regular Stock NaphthaTK5545TK 05542040 43 Internal Floating RoofRemovedPER 009NaphthaTK5646TK 05612624 30 Internal Floating RoofRemovedPER 009GasolineTK5747TK 05712624 30 Fixed RoofRemovedPER 009GasolineTK5948TK 05912624 30 Fixed RoofRemovedPER 009Naphtha for AsphaltTK6049TK 06012624 30 Fixed RoofRemovedPER 009Naphtha for AsphaltTK6150TK 061117656 60 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK6251TK 062117656 60 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK6352TK 063136548 70 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK6453TK 064136548 70 Exterior Floating Roof W/Welded TankSActivePER 009Organic Liquid @ 94 UnitTK6554TK 065100848 60 Internal Floating RoofActivePER 009EthanolPage 2 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus28TK 0311955PER 001Active29TK 0331955PER 001Active30TK 0341955PER 009Retired31TK 0351955PER 001Active32TK 0361996PER 00901Removed33TK 0371960PER 007Active34TK 0381966PER 001Active35TK 0391970PER 007Active36TK 0461963PER 001Active37TK 0471962PER 009Active38TK 0481967Mechanical (metallic shoe seal), primary onlyPER 00181WeldedActive39TK 0491974Mechanical (metallic shoe seal), primary onlyPER 00181WeldedActive40TK 0501996PER 00901Removed41TK 0511996PER 00901Removed42TK 052PER 00901Retired43TK 0531996PER 00901Removed44TK 0541996PER 00901Removed45TK 0552004Resilient seal (nonmetallic), liquid mounted,pPER 009 Column Supported Roof, Construction TypeN11WeldedRemoved46TK 0561996Resilient seal (nonmetallic), liquid mounted,pPER 009 Column Supported Roof, Construction TypeN11WeldedRemoved47TK 0571996PER 00901Removed48TK 0591996PER 00901Removed49TK 0601996PER 00901Removed50TK 0611962Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive51TK 0621963Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive52TK 0631962Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive53TK 0641962Mechanical (metallic shoe seal), with shoe moPER 009WeldedActive54TK 0651962Mechanical (metallic shoe seal), primary onlyPER 009WeldedActivePage 2 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK6655TK 066630048 150 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK6756TK 067630048 150 Internal Floating RoofActivePER 009Organic LiquidTK6857TK 068630048 150 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK8058TK 080178548 80 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK8159TK 081178548 80 Fixed RoofActivePER 001Organic LiquidTK8260TK 082420048 125 Internal Floating RoofActivePER 009Organic LiquidTK8361TK 08384048 55 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK8462TK 084180648 80 Internal Floating RoofActivePER 009Organic LiquidTK8563TK 085226848 90 Internal Floating RoofActivePER 009Organic LiquidTK8664TK 086226850 90 Internal Floating RoofActivePER 001Organic LiquidTK8765TK 0871050048 200 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK8866TK 0881050048 200 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK9267TK 09231544 44 Pressure TankRemovedPER 009PentaneTK9568TK 095643.6155 55 Pressure TankRemovedPER 009ButaneTK9669TK 096105065 65 Pressure TankRemovedPER 009ButaneTK9770TK 097642.655 55 Pressure TankRemovedPER 009ButaneTK9871TK 098642.655 55 Pressure TankRemovedPER 009ButaneTK9972TK 099642.655 55 Pressure TankRemovedPER 009ButaneTK10073TK 10070.52109 11 Pressure TankRemovedPER 009PropaneTK10174TK 10170.52109 11 Pressure TankRemovedPER 009PropaneTK10275TK 10270.52109 11 Pressure TankRemovedPER 009PropaneTK10376TK 10370.52109 11 Pressure TankRemovedPER 009PropaneTK10477TK 10470.52109 11 Pressure TankRemovedPER 009PropaneTK10578TK 10570.52109 11 Pressure TankRemovedPER 009PropaneTK10679TK 10670.52109 11 Pressure TankRemovedPER 009PropaneTK10780TK 10770.52109 11 Pressure TankRemovedPER 009PropaneTK10881TK 10870.52109 11 Pressure TankRemovedPER 009PropanePage 3 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus55TK 0661980Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive56TK 0671980Mechanical (metallic shoe seal), with shoe moPER 009WeldedActive57TK 0681982Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive58TK 0801955Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive59TK 0811955PER 001Active60TK 0821964Mechanical (metallic shoe seal), primary onlyPER 009WeldedActive61TK 0831967Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive62TK 0841967Mechanical (metallic shoe seal), primary onlyPER 009WeldedActive63TK 0851970Mechanical (metallic shoe seal), primary onlyPER 00961WeldedActive64TK 0861971Mechanical (metallic shoe seal), primary onlyPER 00161WeldedActive65TK 0871977Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive66TK 0881977Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive67TK 0921960PER 00901Removed68TK 0951963PER 00901Removed69TK 0961968PER 00901Removed70TK 0971988PER 00901Removed71TK 0981988PER 00901Removed72TK 0991988PER 00901Removed73TK 1001954PER 00901Removed74TK 1011954PER 00901Removed75TK 1021954PER 00901Removed76TK 1031954PER 00901Removed77TK 1041954PER 00901Removed78TK 1051954PER 00901Removed79TK 1061954PER 00901Removed80TK 1071954PER 00901Removed81TK 1081954PER 00901RemovedPage 3 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK10982TK 10970.52109 11 Pressure TankRemovedPER 009PropaneTK11083TK 11070.52109 11 Pressure TankRemovedPER 009PropaneTK11184TK 11170.52109 11 Pressure TankRemovedPER 009PropaneTK11285TK 11270.52109 11 Pressure TankRemovedPER 009PropaneTK11386TK 11370.52109 11 Pressure TankRemovedPER 009PropaneTK11487TK 11470.52109 11 Pressure TankRemovedPER 009PropaneTK11588TK 11570.52109 11 Pressure TankActivePER 009PropaneTK11689TK 11670.52109 11 Pressure TankRemovedPER 009PropaneTK11790TK 11770.52109 11 Pressure TankActivePER 009PropaneTK11891TK 11870.52109 11 Pressure TankRemovedPER 009PropaneTK11992TK 11970.52109 Pressure TankRemovedPER 009PropaneTK13093TK 130441048 125 Fixed RoofActivePER 001Organic LiquidTK13194TK 131441048 125 Fixed RoofActivePER 001Organic LiquidTK13295TK 132840048 175 Fixed RoofActivePER 001Organic LiquidTK13396TK 133840048 175 Fixed RoofActivePER 001Organic LiquidTK13497TK 134735048 162 Fixed RoofActivePER 001Organic LiquidTK14098TK 140117119 12.5 Pressure TankRemovedPER 009Liquid CO2TK14199TK 141117119 12.5 Pressure TankRemovedPER 009Liquid CO2TK150100TK 150420048 125 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK151101TK 151420048 125 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK152102TK 152210048 90 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK153103TK 153420048 125 Fixed RoofActivePER 001Organic LiquidTK154104TK 154126048 70 Fixed RoofActivePER 001Organic LiquidTK160105TK 160420048 125 Exterior Floating Roof W/Welded TankSActivePER 001Organic LiquidTK161106TK 161420048 125 Internal Floating RoofActivePER 009Organic LiquidTK200107TK 2003036 12 Fixed RoofActivePER 009Organic Liquid@ 103 UnitTK201108TK 2013036 12 Fixed RoofActivePER 009Organic Liquid @ 103 UnitPage 4 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus82TK 1091954PER 00901Removed83TK 1101954PER 00901Removed84TK 1111954PER 00901Removed85TK 1121954PER 00901Removed86TK 1131954PER 00901Removed87TK 1141954PER 00901Removed88TK 1151954PER 00901Active89TK 1161954PER 00901Removed90TK 1171954PER 00901Active91TK 1181954PER 00901Removed92TK 119PER 00901Removed93TK 1301983PER 001Active94TK 1311983PER 001Active95TK 1321984PER 001Active96TK 1331985PER 001Active97TK 1341988PER 001Active98TK 140PER 00901Removed99TK 141PER 00901Removed100TK 1501988Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive101TK 1511988Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive102TK 1521988Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive103TK 1531988PER 001Active104TK 1541988PER 001Active105TK 1601988Mechanical (metallic shoe seal), with shoe moPER 001WeldedActive106TK 1611988Mechanical (metallic shoe seal), with shoe moPER 009WeldedActive107TK 2001958PER 009Active108TK 2011972PER 009ActivePage 4 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK202109TK 202610 10 Fixed RoofRetiredPER 009Organic LiquidTK205110TK 20539148 38 Internal Floating RoofActivePER 009Organic Liquid @ 94 UnitTK206111TK 20639148 30 Internal Floating RoofActivePER 009Organic Liquid @ 94 UnitTK208112TK 2082020 13 Fixed RoofRemovedPER 009Chemical/Additive Storage Vessel @ 36 UnitTK209113TK 209914 10 Fixed RoofRemovedPER 009Chemical/Additive @ 35 UnitTK300114TK 3008436 20 Fixed RoofActivePER 009Water/Process Mixture Storage Tank @ 21 UnitTK303115TK 3032418 15CE 014Fixed RoofActivePER 009Chemical/Additive Storage TankTK304116TK 3041412 15 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank @ 42 UnitTK305117TK 305412 8 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank @ 42 UnitTK307118TK 30711Fixed RoofRemovedPER 009Chemical/Additive Storage TankTK312119TK 3123226 15CE 014Fixed RoofRemovedPER 009Chemical/Additive Storage TankTK318120TK 31821032 34 Fixed RoofActivePER 001Demin WaterTK319121TK 31921032 34 Fixed RoofActivePER 001Demin WaterTK320122TK 32021030 35 Fixed RoofRetiredPER 009Clarified Oil Storage TankTK325123TK 3252125 12 Fixed RoofRetiredPER 009Water/Process Mixture Storage TankTK327124TK 327616 8 Fixed RoofRemovedPER 009Asphalt Additive @ 102 UnitTK328125TK 3285320 21 Fixed RoofActivePER 001Fresh Sul Acid @ 35 UnitTK329126TK 3295320 21 Fixed RoofActivePER 001Fresh Sul Acid @ 35 UnitTK330127TK 3305320 21 Fixed RoofActivePER 001Spent Sul Acid @ 35 UnitTK331128TK 3315320 21 Fixed RoofActivePER 001Spent Sul Acid @ 35 UnitTK334129TK 33431.536 12 Fixed RoofRetiredPER 009Wet SlopTK335130TK 33531.536 12 Fixed RoofRetiredPER 009Wet SlopTK336131TK 33611832 25CE 028Fixed RoofActivePER 001Organic Liquid Storage TankTK365132TK 36516340 50 Fixed RoofRetiredPER 009SulfurTK366133TK 3662618 16 Fixed RoofRemovedPER 009Amine @ 45 UnitTK367134TK 36725236 35 Fixed RoofActivePER 009Non-Phen Water @ 45 UnitTK368135TK 36827036 35 Fixed RoofActivePER 009Non-Phen Water @ 45 UnitPage 5 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus109TK 2021972PER 009Retired110TK 2051978Mechanical (metallic shoe seal), primary onlyPER 00911WeldedActive111TK 2061978Mechanical (metallic shoe seal), primary onlyPER 00911WeldedActive112TK 208PER 009Removed113TK 20920061972PER 009Removed114TK 300PER 00901Active115TK 303PER 00901Active116TK 304PER 00901Removed117TK 305PER 00901Removed118TK 307PER 00901Removed119TK 3122007PER 00901Removed120TK 318PER 00101Active121TK 319PER 00101Active122TK 320PER 00901Retired123TK 325PER 00901Retired124TK 327PER 00901Removed125TK 328PER 00101Active126TK 329PER 00101Active127TK 330PER 00101Active128TK 331PER 00101Active129TK 334PER 00901Retired130TK 335PER 00901Retired131TK 336PER 00101Active132TK 365PER 00901Retired133TK 366PER 00901Removed134TK 367PER 00901Active135TK 368PER 00901ActivePage 5 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK371136TK 3713131 13 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank @ 33 UnitTK373137TK 3733416 19 Fixed RoofActivePER 009Chemical/Additive Storage Tank @ 45 UnitTK374138TK 3743434 13 Fixed RoofRemovedPER 009Chemical/Additive Storage TankTK400139TK 400126048 70 Fixed RoofRemovedPER 009AsphaltTK401140TK 401126048 70 Fixed RoofRemovedPER 009AsphaltTK402141TK 40225240 35 Fixed RoofRemovedPER 009AsphaltTK403142TK 40325240 35 Fixed RoofRemovedPER 009AsphaltTK410143TK 410126048 70 Fixed RoofRemovedPER 009AsphaltTK411144TK 411504048 134CE 041Fixed RoofActivePER 007AsphaltTK412145TK 412504048 134CE 040Fixed RoofActivePER 007AsphaltTK413146TK 413126048 70 Fixed RoofRemovedPER 009AsphaltTK414147TK 4141260040 232CE 045Fixed RoofActivePER 007AsphaltTK415148TK 4151260056 196CE 039Fixed RoofActivePER 007AsphaltTK416149TK 416504056 125CE 038Fixed RoofActivePER 007AsphaltTK417150TK 4171470048 229CE 037Fixed RoofActivePER 007AsphaltTK418151TK 4181470048 229CE 036Fixed RoofActivePER 007AsphaltTK420152TK 42012640 25 Internal Floating RoofRemovedPER 009Organic LiquidTK421153TK 42112640 25 Fixed RoofRemovedPER 009Organic LiquidTK422154TK 4228432 21 Fixed RoofRemovedPER 009AsphaltTK423155TK 423399056 110CE 055Fixed RoofActivePER 007AsphaltTK424156TK 424399056 110CE 015Fixed RoofActivePER 007AsphaltTK500157TK 50020140 30 Fixed RoofActivePER 001Cooling Water @ 21 UnitTK501158TK 5011012 12 Fixed RoofActivePER 001Water/Process Mixture Storage TankTK502159TK 50220030 35 Fixed RoofActivePER 001Jet Water @ 23 UnitTK504160TK 5041518 12 Fixed RoofRemovedPER 009Chemical/Additive Storage TankTK505161TK 505105048 64 Fixed RoofActivePER 001SulfurTK507162TK 5074UndergroundRemovedPER 009Organic Liquid Storage TankPage 6 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus136TK 371PER 00901Removed137TK 373PER 00901Active138TK 3741999PER 00901Removed139TK 40020041969PER 009Removed140TK 4011996PER 00901Removed141TK 40220041969PER 009Removed142TK 40320041969PER 009Removed143TK 41020041970PER 009Removed144TK 4111970PER 007Active145TK 4121970PER 007Active146TK 41320041970PER 009Removed147TK 4141971PER 007Active148TK 4151974PER 007Active149TK 4161976PER 007Active150TK 4171977PER 007Active151TK 4181977PER 007Active152TK 42020041969Mechanical (metallic shoe seal), primary onlyPER 00911WeldedRemoved153TK 4211969PER 009Removed154TK 42220041969PER 009Removed155TK 4231989PER 007Active156TK 4241989PER 007Active157TK 500PER 00101Active158TK 501PER 00101Active159TK 502PER 00101Active160TK 504PER 00901Removed161TK 505PER 001 Self-Supporting Fixed Roof With No InternalS01Active162TK 507PER 00901RemovedPage 6 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)TK508163TK 5082UndergroundRemovedPER 009Organic Liquid Storage TankTK511164TK 511612 10 Fixed RoofRemovedPER 009Hydrogen Peroxide @ OSWTP26TK513165TK 51311332 24 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank @ 26 Unit26TK514166TK 5142924 14 Fixed RoofActivePER 009Chemical/Additive Storage Tank @ 26 Unit26TK515167TK 51565048 48 Fixed RoofActivePER 009Sour Water Tank @ 26 Unit26TK516168TK 51624140 32 Fixed RoofActivePER 009Stripped Sour Water @ 26 UnitTK517169TK 5172100094 196CE 026CE 069OtherActivePER 009Organic Liquid Storage TankTK521170TK 521ActivePER 009Never InstalledTK522171TK 522806464 155 Internal Floating RoofActivePER 001Heavy NaphthaTK523172TK 5232188264 255 Internal Floating RoofActivePER 001Heavy Naphtha102 TK12173TK 5242034 10 UndergroundActivePER 009Wastewater Storage Tank 102TK1252TK1174TK 525RemovedPER 009Organic Liquid Storage Tank 52TK1TK526175TK 526ActivePER 001Sulfur Storage Tank86TK316176TK 527RemovedPER 009Chemical/Additive Storage Tank35TK4177TK 528ActivePER 001Chemical/Additive Storage Tank 35TK471TK3178TK 529RemovedPER 009Chemical/Additive Storage Tank 71TK386TK166179TK 530RemovedPER 009Chemical/Additive Storage Tank86TK527180TK 531RemovedPER 009Chemical/Additive Storage Tank102TK1181TK 532RemovedPER 009Chemical/Additive Storage Tank 102TK1102TK10182TK 533RemovedPER 009Chemical/Additive Storage Tank 102TK10102TK11183TK 534RemovedPER 009Chemical/Additive Storage Tank 102TK11102TK14184TK 535RemovedPER 009Chemical/Additive Storage Tank 102TK14102TK2185TK 536RemovedPER 009Chemical/Additive Storage Tank 102TK2102TK3186TK 537RemovedPER 009Chemical/Additive Storage Tank 102TK3102TK4187TK 538RemovedPER 009Chemical/Additive Storage Tank 102TK4102TK5188TK 539RemovedPER 009Chemical/Additive Storage Tank 102TK5102TK6189TK 540RemovedPER 009Chemical/Additive Storage Tank 102TK6Page 7 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus163TK 508PER 00901Removed164TK 511PER 00901Removed165TK 513PER 00901Removed166TK 514PER 00901Active167TK 515PER 009 Self-Supporting Fixed Roof With No InternalS01Active168TK 516PER 00901Active169TK 517PER 00901Active170TK 521PER 009Active171TK 522Mechanical (metallic shoe seal), with shoe moPER 001 Column Supported Roof, Construction TypeNWeldedActive172TK 523Mechanical (metallic shoe seal), with shoe moPER 001 Column Supported Roof, Construction TypeNWeldedActive173TK 524PER 009Active174TK 525PER 009Removed175TK 526PER 001Active176TK 527PER 009Removed177TK 528PER 001Active178TK 529PER 009Removed179TK 530PER 009Removed180TK 531PER 009Removed181TK 532PER 009Removed182TK 533PER 009Removed183TK 534PER 009Removed184TK 535PER 009Removed185TK 536PER 009Removed186TK 537PER 009Removed187TK 538PER 009Removed188TK 539PER 009Removed189TK 540PER 009RemovedPage 7 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)102TK7190TK 541RemovedPER 009Chemical/Additive Storage Tank 102TK7102TK8191TK 542RemovedPER 009Chemical/Additive Storage Tank 102TK8102TK9192TK 543RemovedPER 009Chemical/Additive Storage Tank 102TK9104TK4193TK 544RemovedPER 009Chemical/Additive Storage Tank 104TK4105V3194TK 545RemovedPER 009Chemical/Additive Storage Tank 105V311TK5195TK 546RemovedPER 009Chemical/Additive Storage Tank 11TK511TK6196TK 547RemovedPER 009Chemical/Additive Storage Tank 11TK611TK7197TK 548RemovedPER 009Chemical/Additive Storage Tank 11TK711TK8198TK 549RemovedPER 009Chemical/Additive Storage Tank 11TK818TK1199TK 550RemovedPER 009Chemical/Additive Storage Tank 18TK121V32200TK 551RemovedPER 009Chemical/Additive Storage Tank 21V3225TK5201TK 552RemovedPER 009Chemical/Additive Storage Tank 25TK525V35202TK 553RemovedPER 009Chemical/Additive Storage Tank 25V3525V39203TK 554RemovedPER 009Chemical/Additive Storage Tank 25V3925V40204TK 555RemovedPER 009Chemical/Additive Storage Tank 25V4025V41205TK 556RemovedPER 009Chemical/Additive Storage Tank 25V4126ME3206TK 557RemovedPER 009Chemical/Additive Storage Tank 26ME326V81207TK 558RemovedPER 009Chemical/Additive Storage Tank 26V8138TK1208TK 559RemovedPER 009Chemical/Additive Storage Tank 38TK138TK2209TK 560RemovedPER 009Chemical/Additive Storage Tank 38TK245TK2210TK 561RemovedPER 009Chemical/Additive Storage Tank 45TK252TK2211TK 562RemovedPER 009Chemical/Additive Storage Tank 52TK252V1212TK 563ActivePER 001Chemical/Additive Storage Tank 52V171V43213TK 564RemovedPER 009Chemical/Additive Storage Tank 71V4381V38214TK 565RemovedPER 009Chemical/Additive Storage Tank 81V3886TK425215TK 566RemovedPER 009Chemical/Additive Storage Tank 86TK42594V10216TK 567RemovedPER 009Chemical/Additive Storage Tank 94V10Page 8 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus190TK 541PER 009Removed191TK 542PER 009Removed192TK 543PER 009Removed193TK 544PER 009Removed194TK 545PER 009Removed195TK 546PER 009Removed196TK 547PER 009Removed197TK 548PER 009Removed198TK 549PER 009Removed199TK 550PER 009Removed200TK 551PER 009Removed201TK 552PER 009Removed202TK 553PER 009Removed203TK 554PER 009Removed204TK 555PER 009Removed205TK 556PER 009Removed206TK 557PER 009Removed207TK 558PER 009Removed208TK 559PER 009Removed209TK 560PER 009Removed210TK 561PER 009Removed211TK 562PER 009Removed212TK 563PER 001Active213TK 564PER 009Removed214TK 565PER 009Removed215TK 566PER 009Removed216TK 567PER 009RemovedPage 8 of 9 (b)InsignificantActivityOperatorIDfor ItemMINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: STORAGE TANKS (TK)ID No.Capacity(1000 gal)InteriorHeight(ft.)InteriorDiameter(ft.)AddedBy(Action)Construction TypeTankStatusProduct StoredControlEquip.ID No(s).RetiredBy(Action)94V11217TK 568RemovedPER 009Chemical/Additive Storage Tank 94V1194V12218TK 569RemovedPER 009Chemical/Additive Storage Tank 94V1294V24219TK 570RemovedPER 009Chemical/Additive Storage Tank 94V2494V27220TK 571RemovedPER 009Chemical/Additive Storage Tank 94V27TK512221TK 572RemovedPER 009Chemical/Additive Storage Tank 71TK512102TK15222TK 57330242 35 Fixed RoofActivePER 004Chemical/Additive Storage Tank 102TK1535TK5223TK 57415930 30 Fixed RoofActivePER 004Spent Sulfuric Acid Storage Tank 35TK594TK16224TK 575311 7 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 94TK1694TK17225TK 576311 7 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 94TK17104TK9226TK 5773.812 7.5 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 104TK925TK7227TK 5786.320 8 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 25TK733TK1228TK 5796.320 8 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 33TK135TK6229TK 580712 10 Fixed RoofRemovedPER 009Chemical/Additive Storage Tank 35TK611V31230TK 5811.7Fixed RoofActivePER 009Chemical/Additive Storage Tank 11V3131V8231TK 5822Fixed RoofActivePER 009Chemical/Additive Storage Tank 31V816TK1232TK 5836.420 8 Fixed RoofActivePER 009Chemical/Additive Stroage Tank 16TK1RGP1233TK 584168076 Pressure TankActivePER 010Propylene 70% Propane 30%RGP2234TK 585168076 Pressure TankActivePER 010Propylene 70% Propane 30%235TK 586290044 100 Exterior Floating Roof W/Welded TankSActivePER 012Sour Water236TK 587290044 100 Exterior Floating Roof W/Welded TankSActivePER 012Sour Water237TK 588290044 100 Exterior Floating Roof W/Welded TankSActivePER 012Sour Water238TK 589ActivePER 012GHG for all TKsPage 9 of 9 (a)ID No.FACILITY DESCRIPTION: STORAGE TANKS (TK)11 December, 2014 16:08YearRemovedYearInstalledSeal Type(floating roof only)AddedBy(Action)Support Type(floating roof only)ColumnCountColumnDiameter(ft.)Deck Type(floating roof only)TankStatus217TK 568PER 009Removed218TK 569PER 009Removed219TK 570PER 009Removed220TK 571PER 009Removed221TK 572PER 009Removed222TK 5732005PER 004Active223TK 5742006PER 004Active224TK 5752006PER 009Removed225TK 5762006PER 009Removed226TK 5772006PER 009Removed227TK 5782006PER 009Removed228TK 5792006PER 009Removed229TK 5802006PER 009Removed230TK 5811991PER 009Active231TK 5821954PER 009Active232TK 583PER 009Active233TK 5842013PER 010Active234TK 5852013PER 010Active235TK 586Mechanical (metallic shoe seal), with shoe moPER 0120WeldedActive236TK 587Mechanical (metallic shoe seal), with shoe moPER 0120WeldedActive237TK 588Mechanical (metallic shoe seal), with shoe moPER 0120WeldedActive238TK 589PER 012ActivePage 9 of 9 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus1FS 001PER 00900PB046Unburied Sewer Lines subject to NESHAP FF or NSPS QQQActive2FS 001PER 01200PB046Unburied Sewer Lines subject to NESHAP FF or NSPS QQQ - MaterialHandling/Transfer/StorageActive3FS 0021993PER 001101UNITCE 002Track 8 Load and Uncontrolled RailActive4FS 0021993PER 012101UNITCE 002Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/StorageActive5FS 003PER 009RemovedRemoved6FS 004PER 009RemovedRemoved7FS 005PER 009RemovedRemoved8FS 0061999PER 001102UNIT3VOC CE 003CE 040Bottom LoadingActive9FS 0061999PER 012102UNIT3VOC CE 003CE 040Bottom Loading - Material Handling/Transfer/StorageActive10FS 0071999PER 009RemovedRemoved11FS 0081955PER 001102UNITVOCTop Loading and UC Top LoadingActive12FS 0081955PER 012102UNITVOCTop Loading and UC Top Loading - Material Handling/Transfer/StorageActive13FS 009PER 001104UNITPMCoke PileActive14FS 009PER 012104UNITPMCoke Pile - PilesActive15FS 010PER 009RemovedRemoved16FS 011PER 009RemovedRemoved17FS 0161972PER 001103UNITVOCUC BargeActive18FS 0161972PER 012103UNITVOCUC Barge - Open Air SourceActive19FS 017PER 009RemovedRemoved20FS 0181955PER 00111UNIT1VOC11-1 Crude UnitActive21FS 0181955PER 01211UNIT1VOC11-1 Crude Unit - Process EmissionsActive22FS 0191962PER 00111UNIT2VOC11-2 Crude UnitActive23FS 0191962PER 01211UNIT2VOC11-2 Crude Unit - Process EmissionsActive24FS 020PER 009RemovedRemoved25FS 021PER 009RemovedRemoved26FS 0221977PER 00112UNITVOC12 Vacuum DistillationActivePage 1 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus27FS 0221977PER 01212UNITVOC12 Vacuum Distillation - Process EmissionsActive28FS 023PER 009RemovedRemoved29FS 0241988PER 00114UNITVOC14-Saturate PlantActive30FS 0241988PER 01214UNITVOC14-Saturate Plant - Process EmissionsActive31FS 025PER 009RemovedRemoved32FS 026PER 009RemovedRemoved33FS 0271962PER 00115UNITVOC15-Coker GasolineActive34FS 0271962PER 01215UNITVOC15-Coker Gasoline - Process EmissionsActive35FS 028PER 009RemovedRemoved36FS 0291962PER 00116UNITVOC16 Vacuum DistillationActive37FS 0291962PER 01216UNITVOC16 Vacuum Distillation - Process EmissionsActive38FS 030PER 009RemovedRemoved39FS 0311968PER 00117UNIT1VOC17-Fluid Catalytic Cracking (FCC) UnitActive40FS 0311968PER 01217UNIT1VOC17-Fluid Catalytic Cracking (FCC) Unit - Process EmissionsActive41FS 0321993PER 00117UNIT2VOC17-Clarified Oil Vacuum FracActive42FS 0321993PER 01217UNIT2VOC17-Clarified Oil Vacuum Frac - Process EmissionsActive43FS 033PER 009RemovedRemoved44FS 034PER 009RemovedRemoved45FS 0351968PER 00118UNIT1VOC18-1 FCC Gasoline PlantActive46FS 0351968PER 01218UNIT1VOC18-1 FCC Gasoline Plant - Process EmissionsActive47FS 0361988PER 00118UNIT2VOC18-2 FCC Gasoline PlantActive48FS 0361988PER 01218UNIT2VOC18-2 FCC Gasoline Plant - Process EmissionsActive49FS 037PER 009RemovedRemoved50FS 038PER 009RemovedRemoved51FS 0391973PER 00119UNITVOC19 Vacuum DistillationActive52FS 0391973PER 01219UNITVOC19 Vacuum Distillation - Process EmissionsActive53FS 040PER 009RemovedRemovedPage 2 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus54FS 0411955PER 00121UNIT1VOC21-1Delayed CokerActive55FS 0411955PER 01221UNIT1VOC21-1Delayed Coker - Process EmissionsActive56FS 0421963PER 00121UNIT2VOC21-2 Delayed CokerActive57FS 0421963PER 01221UNIT2VOC21-2 Delayed Coker - Process EmissionsActive58FS 043PER 009RemovedRemoved59FS 044PER 009RemovedRemoved60FS 0451983PER 00123UNITVOC23- Delayed Coker & Gasoline PlantActive61FS 0451983PER 01223UNITVOC23- Delayed Coker & Gasoline Plant - Process EmissionsActive62FS 046PER 009RemovedRemoved63FS 0471999PER 009RemovedRemoved64FS 0481988PER 00125UNITVOC25-Crude UnitActive65FS 0481988PER 01225UNITVOC25-Crude Unit - Process EmissionsActive66FS 049PER 009RemovedRemoved67FS 050PER 009RemovedRemoved68FS 051PER 009RemovedRemoved69FS 0521993PER 00126UNITVOC26-Sulfur Recovery Unit SRU 5, TGTU 2Active70FS 0521993PER 01226UNITVOC26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process EmissionsActive71FS 053PER 009RemovedRemoved72FS 0541993PER 00127UNIT2VOC27-Distillate HydrotreaterActive73FS 0541993PER 01227UNIT2VOC27-Distillate Hydrotreater - Process EmissionsActive74FS 0551993PER 00127UNIT1VOC27- Hydrogen Plant No. 2Active75FS 0551993PER 01227UNIT1VOC27- Hydrogen Plant No. 2 - Process EmissionsActive76FS 0562002PER 00127Unit5VOC27-5 Hydrogen Plant No. 3Active77FS 0562002PER 01227Unit5VOC27-5 Hydrogen Plant No. 3 - Process EmissionsActive78FS 057EIS 001VOC#2 Hydrogen Plant Drain SystemActive79FS 057PER 012VOC#2 Hydrogen Plant Drain System - Process EmissionsActive80FS 0581993PER 00128UNITVOC28-Naphtha HydrotreaterActivePage 3 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus81FS 0581993PER 01228UNITVOC28-Naphtha Hydrotreater - Process EmissionsActive82FS 059PER 009RemovedRemoved83FS 0601955PER 00131UNITVOC31 Product DesulfurizationActive84FS 0601955PER 01231UNITVOC31 Product Desulfurization - Process EmissionsActive85FS 061PER 009RemovedRemoved86FS 0621980PER 00132UNIT1VOC32 PowerformerActive87FS 0621980PER 01232UNIT1VOC32 Powerformer - Process EmissionsActive88FS 0631985PER 00132UNIT3VOC32 PenexActive89FS 0631985PER 01232UNIT3VOC32 Penex - Process EmissionsActive90FS 0641984PER 00132UNIT2VOC32 Aviation Gasoline 0Active91FS 0641984PER 01232UNIT2VOC32 Aviation Gasoline 0 - Process EmissionsActive92FS 065PER 009RemovedRemoved93FS 066PER 009RemovedRemoved94FS 067PER 009RemovedRemoved95FS 0691973PER 00133UNIT2VOC33-Hydrogen Plant No. 1Active96FS 0691973PER 01233UNIT2VOC33-Hydrogen Plant No. 1 - Process EmissionsActive97FS 0701973PER 00933UNIT1VOC33 Low Pressure GOHTActive98FS 0701973PER 01233UNIT1VOC33 Low Pressure GOHT - Process EmissionsActive99FS 071PER 009RemovedRemoved100FS 072PER 009RemovedRemoved101FS 0731999PER 009RemovedRemoved102FS 0751960PER 00135UNITVOC35 AlkylationActive103FS 0751960PER 01235UNITVOC35 Alkylation - Process EmissionsActive104FS 076PER 009RemovedRemoved105FS 0771978PER 00136UNITVOC36 DimersolActive106FS 0771978PER 01236UNITVOC36 Dimersol - Process EmissionsActive107FS 078PER 009RemovedRemovedPage 4 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus108FS 0791981PER 00137UNIT2VOC37 Naptha Hydro-DesulfurizerActive109FS 0791981PER 01237UNIT2VOC37 Naptha Hydro-Desulfurizer - Process EmissionsActive110FS 0801981PER 00137UNIT1VOC37 PlatformerActive111FS 0801981PER 01237UNIT1VOC37 Platformer - Process EmissionsActive112FS 081PER 009RemovedRemoved113FS 082PER 009ReservedRemoved114FS 0831985PER 00138UNITVOC38 High Pressure Gas/Oil HydrotreaterActive115FS 0831985PER 01238UNITVOC38 High Pressure Gas/Oil Hydrotreater - Process EmissionsActive116FS 084PER 009ReservedRemoved117FS 0851993PER 00139UNITVOC39 Oxy FuelActive118FS 0851993PER 01239UNITVOC39 Oxy Fuel - Process EmissionsActive119FS 086PER 009ReservedRemoved120FS 0871983PER 00141UNIT2VOC41 Amine SystemActive121FS 0871983PER 01241UNIT2VOC41 Amine System - Process EmissionsActive122FS 0881984PER 00141UNIT1VOC41 Fuel Gas Liquid RecoveryActive123FS 0881984PER 01241UNIT1VOC41 Fuel Gas Liquid Recovery - Process EmissionsActive124FS 089PER 009ReservedRemoved125FS 090PER 009ReservedRemoved126FS 0911955PER 00142UNITVOC42 Caustic Treating (C3,C4)Active127FS 0911955PER 01242UNITVOC42 Caustic Treating (C3,C4) - Process EmissionsActive128FS 092PER 009RemovedRemoved129FS 0931963PER 00143UNITVOC43 PolymerizationActive130FS 0931963PER 01243UNITVOC43 Polymerization - Process EmissionsActive131FS 094PER 009RemovedRemoved132FS 0951973PER 00145UNIT3&4VOC CE 01945 Sulfur Recovery Unit 3 & 4Active133FS 0951973PER 01245UNIT3&4VOC CE 01945 Sulfur Recovery Unit 3 & 4 - Process EmissionsActive134FS 0961973PER 00145UNIT2VOC45 Fuel Gas TreatingActivePage 5 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus135FS 0961973PER 01245UNIT2VOC45 Fuel Gas Treating - Process EmissionsActive136FS 097EIS 001VOC45 Sulfur Recovery Unit 3 & 4 Drain SystemActive137FS 097PER 012VOC45 Sulfur Recovery Unit 3 & 4 Drain System - Process EmissionsActive138FS 098EIS 001VOC45 Fuel Gas Treating Drain SystemActive139FS 098PER 012VOC45 Fuel Gas Treating Drain System - Process EmissionsActive140FS 0991974PER 00945UNIT1SWS/Non-Phenolic/PhenolicActive141FS 0991974PER 01245UNIT1SWS/Non-Phenolic/Phenolic - Process EmissionsActive142FS 100PER 009RemovedRemoved143FS 101PER 009RemovedRemoved144FS 1021993PER 00147UNIT47 H2 Recovery GasActive145FS 1021993PER 01247UNIT47 H2 Recovery Gas - Process EmissionsActive146FS 103PER 009RemovedRemoved147FS 1041989PER 00152UNIT1VOCGas and Distillate BlendingActive148FS 1041989PER 01252UNIT1VOCGas and Distillate Blending - Process EmissionsActive149FS 105PER 009RemovedRemoved150FS 1061955PER 00171UNITVOC71 Process Steam BoilersActive151FS 1061955PER 01271UNITVOC71 Process Steam Boilers - Process EmissionsActive152FS 107PER 009RemovedRemoved153FS 1091992PER 00184UNIT3VOC CE 03184 Flare Gas RecoveryActive154FS 1091992PER 01284UNIT3VOC CE 03184 Flare Gas Recovery - Process EmissionsActive155FS 1101992PER 00184UNIT2VOCNorth FlareActive156FS 1101992PER 01284UNIT2VOCNorth Flare - Process EmissionsActive157FS 111PER 009RemovedRemoved158FS 1121992PER 00184UNIT1VOCNew Flare System and 84-Flare (84Unit1 and 84Unit_1)Active159FS 1121992PER 01284UNIT1VOCNew Flare System and 84-Flare (84Unit1 and 84Unit_1) - Process EmissionsActive160FS 113PER 009RemovedRemoved161FS 114PER 009RemovedRemovedPage 6 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus162FS 115PER 009RemovedRemoved163FS 116PER 009RemovedRemoved164FS 117PER 001102UNIT2VOCAll Tankage (including line pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2Active165FS 117PER 012102UNIT2VOCAll Tankage (including line pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process EquipmentActive166FS 118PER 009RemovedRemoved167FS 1191976PER 00194UNITVOC CE 028CE 043OSWTP Fugitive Emissions Includes Non-vented EquipmentActive168FS 1191976PER 01294UNITVOC CE 028CE 043OSWTP Fugitive Emissions Includes Non-vented Equipment - Process EmissionsActive169FS 120PER 009RemovedRemoved170FS 123PER 00100UNIT1VOCHeavy Liquid Tanks(00Unit_1, HLTanksC and HLTanksV)Active171FS 123PER 01200UNIT1VOCHeavy Liquid Tanks(00Unit_1, HLTanksC and HLTanksV) - Process EmissionsActive172FS 124PER 009RemovedRemoved173FS 125PER 009RemovedRemoved174FS 126PER 009RemovedRemoved175FS 127PER 009RemovedRemoved176FS 1281994PER 00188UNITVOC CE 02688-ButaneActive177FS 1281994PER 01288UNITVOC CE 02688-Butane - Process EmissionsActive178FS 129PER 009RemovedRemoved179FS 130PER 00100UNIT UJCarbon Canisters & Associated PipingActive180FS 130PER 01200UNIT UJCarbon Canisters & Associated Piping - Process EmissionsActive181FS 131PER 009RemovedRemoved182FS 1321998PER 00186UNIT3VOC CE 036CE 037SVE Thermal Oxidizer(86 UNIT3 and 88 UNIT2)Active183FS 1321998PER 01286UNIT3VOC CE 036CE 037SVE Thermal Oxidizer(86 UNIT3 and 88 UNIT2) - Process EmissionsActive184FS 1332002PER 00129UNITVOCHydrocracker Feed EquipmentActive185FS 1332002PER 01229UNITVOCHydrocracker Feed Equipment - Process EmissionsActive186FS 134PER 00130UNITVOCNo. 4 Hydrogen Plant Fugitive EquipmentActivePage 7 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:08FACILITY DESCRIPTION: FUGITIVE SOURCES (FS)ID No.Fugitive Source DescriptionYearInstalledYearRemovedAddedBy(Action)RetiredBy(Action)InsignificantActivityOperatorIDfor ItemPollutant(s)EmittedControlEquip.ID No(s).FugitiveSourceStatus187FS 134PER 01230UNITVOCNo. 4 Hydrogen Plant Fugitive Equipment - Process EmissionsActive188FS 1352010PER 00944UNIT44 PenexRemoved189FS 136PER 00925UNITVOC25 Unit Drains Requiring Emission ControlsActive190FS 136PER 01225UNITVOC25 Unit Drains Requiring Emission Controls - Process EmissionsActive191FS 137PER 010VOCRGP TransferActive192FS 137PER 012VOCRGP Transfer - Process EmissionsActive193FS 138PER 010VOCRGP Loading RackActive194FS 138PER 012VOCRGP Loading Rack - Process EmissionsActive195FS 139PER 012VOCCHP Equipment in Natural Gas Service - Process EmissionsActive196FS 140PER 01248UNITCO2H2SVOC48 ATS Process Unit - Process EmissionsActive197FS 141PER 012Emissions for all FS unitsActivePage 8 of 8MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus1Flamepres267656MR 0013144D1K5B4Rosemount101TT0350EU 209SV 001PER 009Pilot indicator for ZTOF at rail loadingActive2Fuel UseNAMR 002NANA86F0747EU 276SV 143PER 001Natural Gas Flow to 86H41Active3TempNAMR 003NANA88TK517CE 026PER 001Pilot Thermocouple for Butane StorageTank 086TKActive4VOC12887011MR 004Advance Plus/Optichrom FIDSiemens102AO502CE 003CE 058EU 004SV 003PER 001VOC Monitor at Bottom Loading UnitActive5CO3.244108.1MR 005Advance Optima/URAS 14ABB11A1300EU 212SV 131PER 00111H-6 CO MonitorActive6NOx3.244135.1MR 006Advance Optima/Limas 11ABB11A2300EU 212SV 131PER 00111H6 NOx MonitorActive7O23.244127.1MR 007Advance Optima/Magnos 16ABB11A2301EU 212SV 131PER 001O2 Monitor for 11H6Active8Fuel Use6562MR 0083095MA34A0011AA00NBBSRosemount11FT2000EU 212SV 131PER 00111H6 Fuel Gas FlowmeterActive9Fuel Use318015MR 0093051CD2A02A1AH2E5Rosemount11FT0002CEU 005SV 004PER 00111H1 Fuel Gas FlowmeterActive10O2CO15745-211-1-07-4MR 010WDG111Ametek12A0100EU 016SV 015PER 00112H4 Firebox O2Active11Fuel Use441766MR 0113051CD3A02A1AH2B3K5Rosemount12FT0801EU 016SV 015PER 00112H4 Fuel Gas FlowmeterActive12MR 012PER 001DELETEActive13O23.243379.1MR 013Advance Optima/Magnos 16ABB16A1201EU 019SV 017PER 00116H1 O2 MonitorActive14CO3.2443399.1MR 014Advance Optima/URAS 14AAB16A1300EU 019SV 017PER 00116H1 CO MonitorActive15NOx3.2143400.1MR 015Advance Optima/Limas 11AAB16A1200EU 019SV 017PER 00116H1 NOx MonitorActive16Fuel Use62478MR 0163095MA34A0013AA00NBBSRosemount16FT0062EU 019SV 017PER 00116H1 Fuel Gas FlowmeterActive17Opacity5601950MR 017LightHawk 560Teledyne Monitor Labs17A3000CE 004CE 005CE 006EU 228SV 019PER 00717ME-187 FCC Common Stack OpacityAnalyzerActivePage 1 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus1MR 001 PER 009Active2MR 002 PER 001NoActive3MR 003 PER 001NoActive4MR 004 PER 0015000 7500No09/25/2001Active5MR 005 PER 001500 750No02/25/2002Active6MR 006 PER 00150 75No02/25/2002Active7MR 007 PER 00125 37.5No02/25/2002Active8MR 008 PER 001Active9MR 009 PER 001Active10MR 010 PER 001NoActive11MR 011 PER 001Active12MR 012 PER 001Active13MR 013 PER 00125 37.512/07/2001Active14MR 014 PER 001500 75012/07/2001Active15MR 015 PER 00150 75No12/07/2001Active16MR 016 PER 001Active17MR 017 PER 00760 9005/01/20091ActivePage 1 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus18NOx3.234168.3MR 018Advance Optima/Limas 11AAB17A3001-ACE 004CE 005CE 006EU 228SV 019PER 001FCC Common Stack NOx AnalyzerActive19SO22230MR 0192500 TRServomex17A3002CE 004CE 005CE 006EU 228SV 019PER 001FCC Common Stack SO2 AnalyzerActive20MR 020PER 001RemovedActive21CO0595-2377MR 0212500Servomex17A3670CE 004CE 005CE 006EU 228SV 019PER 001FCC CO(%) in Flue Gas MonitorActive22Fuel Use114559MR 0223051CD2Rosemount17FT0199CE 004CE 005CE 006EU 228SV 019SV 021PER 00117H-2 Fuel Gas Flow MeterActive23Fuel Use114559MR 0223051CD2Rosemount17FT0199CE 004CE 005CE 006EU 228SV 019PER 01217H-2 Fuel Gas Flow MeterActive24Fuel Use510513MR 0233051CD3A02A1AH2B3D3K5Rosemount17FT0538CE 004CE 005CE 006EU 228SV 019SV 021PER 00117H-4 Fuel Gas Flow MeterActive25Fuel Use510513MR 0233051CD3A02A1AH2B3D3K5Rosemount17FT0538CE 004CE 005CE 006EU 228SV 019PER 01217H-4 Fuel Gas Flow MeterActive26Air FlowNAMR 024NANA17FT3006CE 004CE 005CE 006EU 228SV 019PER 001EMRC Flow for 17ME-187ActivePage 2 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus18MR 018 PER 0011000 150003/24/1993Active19MR 019 PER 001100 15003/24/1993Active20MR 020 PER 001Active21MR 021 PER 001Active22MR 022 PER 001Active23MR 022 PER 012Active24MR 023 PER 001Active25MR 023 PER 012Active26MR 024 PER 00103/24/1993ActivePage 2 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus27TempNAMR 025NANA17TT3005CE 004CE 005CE 006EU 228SV 019PER 001EMRC Temperature Thermocouple for17ME-187Active28Fuel Use1188358MR 0263051CD3A02A1AH2B3K5Rosemount19FT0401EU 026SV 025PER 00119H1 Fuel Gas MeterActive29O2CO96558-1MR 027Thermox WDG-IVAmetek23A2028EU 035SV 033PER 00123H-2 O2 AnalyzerActive30Fuel Use9630001MR 0281151DP4E12Rosemount23FT1128EU 035SV 033PER 00123H-2 Fuel Gas Flow Meter pass 1Active31Fuel UseIllegibleMR 0291151DP4E12Rosemount23FT1129EU 035SV 033PER 00123H-2 Fuel Gas Flow Meter pass 2Active32Fuel Use9630006MR 0301151DP4E12Rosemount23FT1228EU 035SV 033PER 00123H-2 Fuel Gas Flow Meter pass 3Active33Fuel Use9630000MR 0313051CD3A02A1AH2B3K5D3Rosemount23FT1229EU 035SV 033PER 00123H-2 Fuel Gas Flow Meter pass 4Active34O23.250856.4MR 032Magnos 106ABB25A1272CE 073EU 040EU 353SV 037SV 184PER 01025H-1 or 25H-2 O2 AnalyzerActive35O2C096558-3MR 033Thermox WDG-IVAmetek25A1267EU 041SV 038PER 00945 Drum Fuel GAs Combustion O2Monitor at 25H3Active36O2C096558-3MR 033Thermox WDG-IVAmetek25A1267EU 041GP 116SV 038PER 01245 Drum Fuel Gas Combustion O2Monitor at 25H3Active37Fuel Use74973MR 0343095MARosemount25FT0414EU 040SV 037PER 00125H-1 Fuel Gas Flow MeterActive38Fuel Use109185MR 0353051S1CD3A2F12A2AB3K5Rosemount25FT2414EU 041SV 038PER 00125H-3 Fuel Gas Flow MeterActive39SO23.242533.1MR 036Advance Optima/URAS 14ABB26A0691EU 235SV 042PER 001TGTU2 SO2 Analyzer - 26H21Active40O2C9-355MR 037Oxymat 5FSiemens26A0692EU 235SV 042PER 001TGTU2 O2 Analyzer - 26H21Active41Fuel Use84310MR 0383051CD2A02A1AH2E5B1Rosemount26FT0463AEU 236PER 00126H-40 Natural Gas Flow MeterActive42Fuel Use82790MR 0393051S1CD3A2F12A1AB3K5MRosemount26FT0668EU 237PER 00126H-41 Fuel Gas Flow MeterActivePage 3 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus27MR 025 PER 00103/24/1993Active28MR 026 PER 001Active29MR 027 PER 00125 37.5No12/21/1992Active30MR 028 PER 001Active31MR 029 PER 001Active32MR 030 PER 001Active33MR 031 PER 001Active34MR 032 PER 01022 25No12/12/1992Active35MR 033 PER 00925 37.5No12/09/1992Active36MR 033 PER 01225 37.5No12/09/1992Active37MR 034 PER 001Active38MR 035 PER 001Active39MR 036 PER 001500 75011/02/2001Active40MR 037 PER 00125 37.5No11/11/1993Active41MR 038 PER 001Active42MR 039 PER 001ActivePage 3 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus43Air FlowNAMR 040NANA26FT0690EU 235SV 042PER 009Flow for Meter TGTU2 - 26H21Active44Fuel Use121257MR 0413051CD3A02A1AH2B3E5Rosemount26FT1258EU 235SV 042PER 00126H-21 Fuel Gas FlowActive45TempNAMR 042NANA26TT0693SV 042PER 009EMRC Temperature Thermocouple forTGTU2Active46NOx3.241918.1MR 043Advance Optima/Limas 11ABB27A7003EU 213SV 136PER 00127H-501 NOx AnalyzerActive47CO3.241903.1MR 044Advance Optima/URAS 14ABB27A7616EU 213SV 136PER 00127H-501 CO AnalyzerActive48O2C-103296B-1MR 045Thermox WDG-IVAmetek27A0464EU 052SV 046PER 00127H-1 O2 AnalyzerActive49C-103296B-3MR 046Thermox WDG-IVAmetek27A2068SV 044PER 00427H-101 O2 AnalyzerRemoved50O2C-103296B-4MR 047Thermox WDG-IVAmetek/Thermox27A2722EU 051SV 045PER 00127H-102 O2 AnalyzerActive51O210203538MR 048Thermox WDG-IVAmetek27A7002EU 213SV 136PER 00127H501 Firebox O2 AnalyzerActive52Fuel Use75934MR 0493051CD3A02A1AH2B3E5Rosemount27FT0317AEU 052SV 046PER 00127H-1 Fuel Gas Supply Flow MeterActive53Fuel Use5165775MR 0503095MVRosemount27FT7153EU 213SV 136PER 00127H-501 Natural Gas Supply Flow MeterActive54Fuel Use96881MR 0513051CD2A02A1AH2B3E5Rosemount27FT2072EU 050SV 044PER 00127H-101 Natural Gas Supply Flow MeterActive55Fuel Use96882MR 0523051CD2AO2A1AB3E5H2Rosemount27FT2080EU 050SV 044PER 00127H-101 Fuel Gas Supply Flow Meter 2Active56Fuel Use97107MR 0533051CD2A02A1AH2B3E5Rosemount27FT2709EU 051SV 045PER 00127H-102 Fuel Gas Supply Flow MeterActive57Fuel Use910630MR 0543051CD3A02A1AH2B3E5Rosemount27FT0275EU 052SV 046PER 00127H-1 PSA Gas Supply Flow MeterActive58Fuel UseNAMR 055NANA27FT0338EU 052SV 046PER 00127H-1 Natural Gas Supply Flow MeterActive59Fuel Use97106MR 0563051CD2AO2A1AH2B3E5Rosemount27FT2702EU 051SV 045PER 00127H-102 Natural Gas Supply Flow MeterActive60Fuel Use84481MR 0573051S1GD3A2F12A2AB3K5Rosemount27FT4741EU 050SV 044PER 00127H-101 Fuel Gas Supply Flow Meter 1Active61Fuel Use1007302MR 0583051CD1A02A1AC1B3K5H2Rosemount27FT7133EU 213SV 136PER 00127H501 PSA Purge Gas FlowActivePage 4 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus43MR 040 PER 009Active44MR 041 PER 001Active45MR 042 PER 009NoActive46MR 043 PER 00150 75No12/14/2001Active47MR 044 PER 001500 750No12/14/2001Active48MR 045 PER 00125 37.5No08/17/1994Active49MR 046 PER 004No08/17/1994Removed50MR 047 PER 00125 37.5No08/17/1994Active51MR 048 PER 001Active52MR 049 PER 001Active53MR 050 PER 001Active54MR 051 PER 001NoActive55MR 052 PER 001Active56MR 053 PER 001NoActive57MR 054 PER 001NoActive58MR 055 PER 001NoActive59MR 056 PER 001NoActive60MR 057 PER 001Active61MR 058 PER 001ActivePage 4 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus62MR 059PER 009DELETERemoved63MR 060PER 009DELETERemoved64O2C103296B-2MR 061Thermox WDG-IVAmetek28A0114EU 053SV 047PER 00128H-1 O2 AnalyzerActive65Fuel Use69243MR 0623051CD2A02A1AH2B3E5Rosemount28FT0117EU 053SV 047PER 00128H-1 Fuel Gas Supply Flow MeterActive66103128MR 0633051CD1A02A1AH2B3K5Rosemount28FT0157EU 053SV 047PER 00128H-1 Natural Gas Supply Flow MeterActive67O210204870BMR 064Thermox WDG-IVAmetek32A3000EU 073EU 074EU 075SV 066PER 00132H5,6,7 O2 Analyzer for NOxActive68O210204870AMR 065Thermos II WDG-IVAmetek33A0926EU 085SV 075PER 00133H32 Firebox O2Active69O22-5991-39-2-07MR 066Thermox IIThermox33A0951EU 084SV 074PER 00133H31 Firebox O2Active70Fuel Use94530MR 0673095MA2CAJA10AA000BBDRosemount33FT0965EU 085SV 075PER 00133H32 Fuel Gas FlowActive71Fuel Use192152MR 0683051CD2A02A1AH2B3E5Rosemount33FT1123EU 084SV 074PER 00133H31 Fuel Gas FlowActive72SO23.244692.3MR 069Optima URAS-14AAB34A0612EU 055SV 049PER 00831H2 SO2 AnalyzerActive73MR 070PER 001Being RemovedActive74Temp413111MR 0713144PD1A2E5B4Rosemount34TT0603CE 013EU 245SV 078PER 001EMRC Temperature Thermocouple for34H-3Active75Temp413111MR 0713144PD1A2E5B4Rosemount34TT0603PER 012EMRC Temperature Thermocouple for34H-3Removed76Fuel Use638986MR 0723051CG3A02A1AH2B3D3K5Rosemount38FT0215EU 103SV 088PER 00138H1B Fuel Gas FlowActive77Fuel Use150159MR 0733051CD3020A1AH2B3K5Rosemount38FT0623EU 104SV 089PER 00138H2 Fuel Gas FlowActive78Fuel Use109632MR 0743051CD3A03A1AH2B3E5Rosemount38FT0115EU 102SV 087PER 00138H1A Fuel Gas FlowActive79H2S7288MR 075466/4000Ametek41A1050EU 256GP 111PER 00141V33 Fuel Gas Mix Drum H2SActivePage 5 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus62MR 059 PER 009Removed63MR 060 PER 009Removed64MR 061 PER 00125 37.5No12/14/2001Active65MR 062 PER 001Active66MR 063 PER 001No09/28/1993Active67MR 064 PER 001Active68MR 065 PER 001NoActive69MR 066 PER 001Active70MR 067 PER 001Active71MR 068 PER 001Active72MR 069 PER 008500 750Active73MR 070 PER 001Active74MR 071 PER 001No06/23/1994Active75MR 071 PER 012No06/23/1994Removed76MR 072 PER 001No06/23/1994Active77MR 073 PER 001No06/23/1994Active78MR 074 PER 001Active79MR 075 PER 001300 450ActivePage 5 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus80Fuel Use1354016MR 0763095MA33A002AA001BBN50Rosemount41FT1052EU 256GP 111PER 00141V-33 Fuel Gas Mix Drum Refinery FlowMeterActive81Fuel Use341802MR 0773051CD3Rosemount41FT0007EU 311PER 001Natural Gas Flow to Pilots of Heaters inMain Control AreaActive82TempNAMR 078NAEMRC45T4657SV 093PER 009EMRC Temperature Thermocouple forTGTU1Active83TempNAMR 079NAEMRC45T4653CE 018EU 111SV 094PER 00145H6 Stack TempActive84H2S5003430001MR 080Advance Optima/Advance PluSiemens45A0505EU 263GP 111PER 00245V-39 Fuel Gas Mix Drum H2SActive85O2N1-M1-0136MR 081Oxymat 6FSiemens45A4650CE 018EU 111SV 094PER 00145H-6 O2Active86SO22500-2168MR 0822500 A2-GENServomex45A4651CE 018EU 111SV 094PER 00145H-6 SO2Active87O2N1-M1-0137MR 083Oxymat 6FSiemens45A4654EU 260SV 093PER 001TGTU1 O2 Analyzer - 45H61Active88SO22550-1449MR 0842500 A2-GENServomex45A4655EU 260SV 093PER 001TGTU1 SO2 Analyzer - 45H61Active89Fuel UseNAMR 0851151DPRosemount45FT0266EU 261PER 00145H-7 Natural Gas Flow MeterActive90Fuel Use392455MR 0861151DP5E12B1Rosemount45FT0359EU 262PER 00145H-8 Fuel Gas Flow MeterActive91Fuel Use765064MR 0873051CD3A02A1AH2B3K5D3Rosemount45FT0723EU 260SV 093PER 00145H61 Fuel Gas FlowActive92Fuel Use19319MR 0883095MA33A0012AA001BBN5Rosemount45FT0962EU 263GP 111PER 00245V-39 Fuel Gas Mix Drum Flow MeterActive93Air FlowNAMR 089NAEMRC45F4652CE 018EU 111SV 094PER 00145H6 Stack FlowActive94Air FlowNAMR 090NAEMRC45F4656EU 260SV 093PER 009Flow Meter for TGTU1Active9512643811MR 091Optichrom AdvanceApplied Automation47A0065GP 111PER 009Fuel Gas H2S Concentration (BACKUP)Removed96122013MR 0923051CD2A02A1AH2B3M5E5Rosemount47FT0066GP 111PER 009Fuel Gas Mix Drum Flow MeterRemoved97O2C151413MR 093Thermox WDG-IV Series 200Ametek71A2934EU 204SV 132PER 00171B8 O2 Analyzer to Monitor NOxEmissionsActivePage 6 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus80MR 076 PER 001Active81MR 077 PER 001No06/12/2001Active82MR 078 PER 009Active83MR 079 PER 001Active84MR 080 PER 002300 450No10/05/1989Active85MR 081 PER 00125 37.5Active86MR 082 PER 001500 750No12/13/2001Active87MR 083 PER 00125 37.5NoActive88MR 084 PER 001500 750NoActive89MR 085 PER 001No10/05/1989Active90MR 086 PER 001No10/05/1989Active91MR 087 PER 001Active92MR 088 PER 002Active93MR 089 PER 001Active94MR 090 PER 009Active95MR 091 PER 009Removed96MR 092 PER 009Removed97MR 093 PER 00125 37.5NoActivePage 6 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus98Fuel Use414434MR 0943051CD2A02A1AH2B3K5Rosemount71FT2911EU 204SV 132PER 00171B8 Natural Gas Supply Flow MeterActive99Temp31222MR 0953044CA1B4M5Rosemount84TT0541EU 304SV 104PER 001North Flare Pilot ThermocoupleActive100TempNAMR 096NANA84T0759EU 303SV 107PER 001Utility Flare Pilot ThermocoupleActive101TempNAMR 097NANA84T0792EU 301SV 105PER 001East Flare Pilot ThermocoupleActive102TempNAMR 098NANA84T0829EU 302SV 106PER 001West Flare Pilot ThermocoupleActive103TempVC914219MR 099ZCT3840428XXJohn Zink86H41EU 276SV 143PER 009SVE System: Temperature Monitor forCentral Buffer at 86H41Active104TempVC914206MR 100ZCT274031828XXJohn Zink88H2CE 033CE 056EU 277SV 142PER 009SVE System: Temperature Monitor forWest Buffer (88H2)Active105Fuel Use777333MR 1013051CD3A02A1AH2B3K5D3Rosemount94FT0670CE 028CE 029CE 051EU 282SV 125PER 00194H1 & 94H3 Natural Gas FlowActive106TempNAMR 102444TK2U1A215Rosemount94TT0525CE 028CE 051EU 282SV 125PER 00194H-1 Thermocouple for Fire BoxTemperatureActive107TempNAMR 1033244MV1K5B4M5Rosemount94TIT3217CE 029CE 051EU 282SV 146PER 001Temperature Monitor (Stack) for 94H-3Thermal OxidizerActive108SO2NAMR 104NAABB94A1002CE 028CE 051EU 282SV 125PER 00194H1 SO2 AnalyzerActive109Fuel Use116457MR 105LT81AAIBF3B2B2CAFCI11FT0804EU 006SV 005PER 00111H2 Fuel Gas FlowmeterActive110O2NAMR 1061101/1131Servomex17A3003CE 004CE 005CE 006EU 228SV 019PER 001FCC O2 Dry PercentActivePage 7 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus98MR 094 PER 001Active99MR 095 PER 001No06/11/2001Active100MR 096 PER 001Active101MR 097 PER 001NoActive102MR 098 PER 001NoActive103MR 099 PER 009NoActive104MR 100 PER 009NoActive105MR 101 PER 001NoActive106MR 102 PER 001NoActive107MR 103 PER 001NoActive108MR 104 PER 001200 300NoActive109MR 105 PER 001Active110MR 106 PER 00125 37.5YesActivePage 7 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus111CO0490001-3783MR 1074900Servomex17A3010CE 004CE 005CE 006EU 228SV 019PER 001FCC CO LowActive112Fuel Use62050MR 1083095MA23AJA10AA000BBRosemount21FT0040EU 028SV 027SV 028PER 00121H-1 West Fuel Gas FlowmeterActive113Fuel Use72553MR 1093095MA23AJA10AA000BBRosemount21FT0041EU 028SV 027SV 028PER 00121H-1 East Fuel Gas FlowmeterActive114Fuel Use88094MR 1103095MA2CAJA10AA000BBDRosemount21FT0240EU 030SV 029SV 030PER 00121H-2 West Fuel Gas FlowmeterActive115Fuel Use88093MR 1113095MA2CAJA10AA000BBDRosemount21FT0241EU 030SV 029SV 030PER 00121H-2 East Fuel Gas FlowmeterActive116Fuel Use257385MR 1123051CD3A02A1AH2B3E5Rosemount23FT0128EU 034SV 032PER 00123H-1 South Fuel Gas FlowmeterActive117Fuel Use360533MR 1133051CD3A02A1AH2B3E5Rosemount23FT0129EU 034SV 032PER 00123H-1 North Fuel Gas FlowmeterActive118CO3.244036.3MR 114Advance Optima/URAS 14AAB26A4142EU 235SV 042PER 001TGTU2 CO AnalyzerActive119Fuel Use976785MR 1153051CD3A02A1AC1B3K5H2Rosemount27FT7422EU 213SV 136PER 001Natural Gas Flowmeter to PilotsActive120Fuel Use317968MR 1163051CD3A02A1AH2E5Rosemount31FT0001AEU 054SV 048PER 00131H1 Fuel Gas FlowmeterActive121Fuel Use317969MR 1173051CD3A02A1AH2E5Rosemount31FT0001BEU 055SV 049PER 00131H2 Fuel Gas FlowmeterActive122Fuel Use318012MR 1183051CD2A02A1AH2E5Rosemount31FT0064EU 058SV 052PER 00131H7 Fuel Gas FlowmeterActive123Fuel UseNAMR 1193095MVRosemount31FT0086EU 059SV 053PER 00131H8 Fuel Gas FlowmeterActive124Fuel Use317976MR 1203051CD3A02A1AH2E5Rosemount31FT0087EU 060SV 054PER 00131H9 Fuel Gas FlowmeterActive125Fuel Use74974MR 1213095MA23AJA10AA000BBRosemount31FT0542EU 061SV 055PER 00131H10 Fuel Gas FlowmeterActive126Fuel Use44979MR 1223095MA23AJA10AA001BBRosemount31FT0585EU 057SV 051PER 00131H-5 Fuel Gas FlowmeterActivePage 8 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus111MR 107 PER 001100 150YesActive112MR 108 PER 001Active113MR 109 PER 001Active114MR 110 PER 001Active115MR 111 PER 001Active116MR 112 PER 001Active117MR 113 PER 001Active118MR 114 PER 001100 150NoActive119MR 115 PER 001Active120MR 116 PER 001Active121MR 117 PER 001Active122MR 118 PER 001Active123MR 119 PER 001Active124MR 120 PER 001Active125MR 121 PER 001Active126MR 122 PER 001ActivePage 8 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus127Fuel UseNAMR 1233051CD2A02A1AH2E5BRosemount31FT0718EU 056SV 050PER 00131H4 Fuel Gas FlowmeterActive128Fuel UseNAMR 1243051CD3A02A1AH2E5Rosemount32FT0054EU 076SV 067PER 00132H-9 Fuel Gas FlowmeterActive129Fuel Use45412MR 1253095MA25AJA10AA001BBRosemount32FT0059EU 073SV 066PER 00132H-5 Fuel Gas FlowmeterActive130Fuel Use48504MR 1263095MA25JA10AA001BBRosemount32FT0060EU 074SV 066PER 00132H-6 Fuel Gas FlowmeterActive131Fuel Use92256MR 1273095MA23AJA10AA001BBRosemount32FT0063EU 075SV 066PER 00132H-7 Fuel Gas FlowmeterActive132Fuel Use69262MR 1283051CD3A020A1AH2B3K5Rosemount33FT0210EU 240SV 073PER 00133H1 Fuel Gas FlowmeterActive133Fuel Use1316887MR 1293051CD3A02A1AH2B3K5Rosemount33FT0028EU 241SV 073PER 00133H2 Fuel Gas FlowmeterActive134NOx3.245997.3MR 130Advance Optima/LIMAS 11AAB37A0941EU 095EU 096EU 097SV 083PER 00137H-3/4/5 NOx AnalyzerActive135CO3.246005.3MR 131Advance Optima/URAS 14AAB37A0942EU 095EU 096EU 097SV 083PER 00137H-3/4/5 CO AnalyzerActive136O23.246001.3MR 132Optima Magnos 106ABB37A0943EU 095EU 096EU 097SV 083PER 00137 O2 PercentActive137Fuel Use577330MR 1333051CD3A02A1AH2B3K5D3Rosemount37FT0059EU 093SV 082PER 00137H-1 Fuel Gas FlowmeterActive138Fuel Use296368MR 1341151DP4E12M2B1Rosemount37FT0192EU 094SV 082PER 00137H-2 Fuel Gas FlowmeterActive139Fuel Use296373MR 1351151DP4E12M2B1Rosemount37FT0325EU 096SV 083PER 00137H4 Fuel Gas FlowmeterActive140Fuel Use106625MR 1363095MA3CAJA10AA000BBRosemount37FT0358EU 097SV 083PER 00137H5 Fuel Gas FlowmeterActive141Fuel Use84541MR 1373095MA2CAJA10AA000BBRosemount37FT0379EU 095SV 083PER 00137H3 Fuel Gas FlowmeterActive142Fuel UseNAMR 1383051Rosemount37FT0600EU 098SV 082PER 00137H6 Fuel Gas FlowmeterActivePage 9 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus127MR 123 PER 001Active128MR 124 PER 001Active129MR 125 PER 001Active130MR 126 PER 001Active131MR 127 PER 001Active132MR 128 PER 001Active133MR 129 PER 001Active134MR 130 PER 001500 75NoActive135MR 131 PER 001200 300NoActive136MR 132 PER 00125 37.5NoActive137MR 133 PER 001Active138MR 134 PER 001Active139MR 135 PER 001Active140MR 136 PER 001Active141MR 137 PER 001Active142MR 138 PER 001ActivePage 9 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus143CO2510-2202MR 1392510 A2-GENServomex45A5505EU 260SV 093PER 00145 CO ppmActive144Fuel Use625225MR 1403051CD2A02A1AH2B3K5Rosemount88FT2379CE 033CE 056EU 277SV 142PER 001Natural Gas 88H-2 SVE OxidizerActive145Fuel Use97088MR 1413051CD2A02A1AH2B3E35Rosemount84FT0741EU 301SV 105PER 001East Flare Natural Gas FlowmeterActive146Fuel Use78847MR 1423051CD2AO2A1AH2BE5M5Rosemount84FT0841EU 302SV 106PER 001West Flare Natural Gas FlowmeterActive147Fuel Use1603826MR 1431151DP4522B3M3Rosemount84FT1141EU 304SV 104PER 001North Flare Natural Gas FlowmeterActive148SO2N/AMR 144N/AAAB94A1006CE 029CE 051EU 254EU 282SV 146PER 00194H3 SO2 AnalyzerActive149Air FlowNAMR 145OFS-2000Optical Scientific94FT1001CE 028CE 051EU 282SV 125PER 009Flow Meter for 94H1 Exhaust GasesActive150Air FlowNAMR 146OFS-2000Optical Scientific94FT1005CE 029CE 051EU 282SV 146PER 009Flow Meter for 94H3 Exhaust GasesActive151Air Flow03060115EMR 147OFS-2000Optical Scientific34FT0610CE 013EU 245SV 078PER 00134H3 Flow Meter for Exhaust GasesActive152Air Flow03060115EMR 147OFS-2000Optical Scientific34FT0610PER 01234H3 Flow Meter for Exhaust GasesRemoved153NOxMR 148ThermoxAmetek25A1265EU 041PER 001NOx Monitor at 25H3Active154COMR 149ThermoxAmetek25A1266EU 041PER 001CO Monitor at 25H3Active155NOx3.250862.4MR 150Limas 11ABB25A1270CE 073EU 040EU 353SV 184PER 010NOx Monitor at 25H1 or 25H2Active156CO3.25844.4MR 151Uras 14ABB25A1271CE 073EU 040EU 353SV 184PER 010CO Monitor at 25H1 or 25H2ActivePage 10 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus143MR 139 PER 0011000 1500YesActive144MR 140 PER 001Active145MR 141 PER 001Active146MR 142 PER 001Active147MR 143 PER 001Active148MR 144 PER 001200 300NoActive149MR 145 PER 009NoActive150MR 146 PER 009NoActive151MR 147 PER 001NoActive152MR 147 PER 012NoRemoved153MR 148 PER 001500 750Active154MR 149 PER 001200 300Active155MR 150 PER 01044 50Active156MR 151 PER 010445 500ActivePage 10 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus157NOxMR 152EU 324SV 176PER 002NOx Monitor at 25H4Active158COMR 153EU 324SV 176PER 002CO Monitor at 25H4Active159O2MR 154EU 324SV 176PER 002O2 Monitor at 25H4Active160Fuel UseMR 155EU 324SV 176PER 002Fuel Gas Flow Meter at 25H4Active161%SULMR 156GP 116PER 00941 Unit Fuel Gas Mix Drum Total SulfurActive162MR 157PER 00445 Unit Fuel Gas Mix Drum Total SulfurRemoved163MR 158PER 009Unit Fuel Gas Mix Drum Total SulfurRemoved164MR 159PER 00441 Mix Drum Fuel Gas Combustion SO2Monitor at ____Removed165MR 160PER 00441 Mix Drum Fuel Gas Combustion SO2Monitor at ____Removed166SO2MR 161EU 041GP 116PER 00945 Mix Drum Fuel Gas Combustion SO2Monitor at 25H3Active167SO2MR 162GP 116PER 00945 SO2 Monitor at 29H1/2Active168MR 163PER 00441 Mix Drum Fuel Gas Combustion O2Monitor at ____Removed169MR 164PER 00441 Mix Drum Fuel Gas Combustion O2Monitor at ____Removed170MR 165GP 116SV 038PER 00945 Mix Drum Fuel Gas Combustion O2Monitor at 25H3Removed171O2MR 166EU 294EU 295GP 116SV 165PER 00945 Mix Drum Fuel Gas Combustion O2Monitor at 29H1/2Active172COMR 167EU 050PER 00227H-101 CO MonitorActive173NOxMR 168EU 050PER 00227H-101 NOx MonitorActive174MR 169SV 082PER 00237H1 2 6 O2 Analyzer for NOxActive175NOxMR 170EU 126PER 00371B6 NOx MonitorActive176COMR 171EU 126PER 00371B6 CO MonitorActivePage 11 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus157MR 152 PER 002Active158MR 153 PER 002Active159MR 154 PER 002Active160MR 155 PER 002Active161MR 156 PER 009Active162MR 157 PER 004Removed163MR 158 PER 009Removed164MR 159 PER 004Removed165MR 160 PER 004Removed166MR 161 PER 009Active167MR 162 PER 009Active168MR 163 PER 004Removed169MR 164 PER 004Removed170MR 165 PER 009Removed171MR 166 PER 009Active172MR 167 PER 002Active173MR 168 PER 002Active174MR 169 PER 002Active175MR 170 PER 003Active176MR 171 PER 003ActivePage 11 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus177O2MR 172EU 126PER 00371B6 O2 MonitorActive178MR 173SV 032PER 00623H-1 NOx MonitorRemoved179MR 174SV 032PER 00623H-1 CO MonitorRemoved180MR 175SV 032PER 00623H-1 O2 MonitorRemoved181MR 176SV 033PER 00623H-2 NOx MonitorRemoved182MR 177SV 033PER 00623H-2 CO MonitorRemoved183MR 178SV 033PER 00623H-2 O2 MonitorRemoved184NOxMR 179EU 294EU 295SV 165PER 00929H-1/2 NOx MonitorActive185COMR 180EU 294EU 295SV 165PER 00929H-1/2 CO MonitorActive186O2MR 181EU 294EU 295SV 165PER 00429H-1/2 O2 MonitorActive187O2MR 182EU 050SV 044PER 00427H-101 O2 MonitorActive188NOx3.343.090.6MR 183Limas 11ABBEU 228SV 019PER 009NH3 Slip CMSActive189Air FlowMR 184EU 055SV 049PER 00831H2 Flow Meter for Exhaust GasesActive190TempMR 185CE 066EU 077SV 068PER 009HCL adsorber inlet temperature indicator(32TI01110)Active191TempMR 186CE 067EU 099GP 057SV 084PER 009HCL adsorber inlet temperature indicator(37TC1150A)Active192TempMR 187EU 312SV 171PER 009Catalyst Inlet temperature for #6 CTDiesel Pump (81TI8210)Active193TempMR 188EU 312SV 171PER 009Catalyst Bed Differential Pressure for #6CT Diesel Pump (81PDT8211)ActivePage 12 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus177MR 172 PER 003Active178MR 173 PER 006Removed179MR 174 PER 006Removed180MR 175 PER 006Removed181MR 176 PER 006Removed182MR 177 PER 006Removed183MR 178 PER 006Removed184MR 179 PER 009Active185MR 180 PER 009Active186MR 181 PER 004Active187MR 182 PER 004Active188MR 183 PER 009100 10008/09/2006Active189MR 184 PER 008Active190MR 185 PER 009Active191MR 186 PER 009Active192MR 187 PER 009Active193MR 188 PER 009ActivePage 12 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus194TempMR 189CE 002EU 209FS 002GP 106PER 009Temperature Indicator for 101H1Active195TempMR 190John ZinkEU 351PER 010RGP VCU Thermocouple for FlamePresenceActive196O2TBDMR 191Magnos 206ABBCE 072EU 352SV 183PER 01023H-3 O2 MonitorActive197NOxTBDMR 192Limas 11ABBCE 072EU 352SV 183PER 01023H-3 NOx MonitorActive198COTBDMR 193Uras 26ABBCE 072EU 352SV 183PER 01023H-3 CO MonitorActive199Fuel UseTBDMR 194TBDTBDCE 072EU 352SV 183PER 01023H-3 Fuel FlowmeterActive200Fuel UseTBDMR 195TBDTBDCE 073EU 353SV 184PER 01025H-2 Fuel FlowmeterActive201%SULMR 196MR45TSGP 116PER 01045 Unit Fuel Gas Mix Drum Total SulfurActive202MR 197EU 351PER 010Propylene VCU FlowActive203TempMR 198EU 212SV 131PER 01011H6 Stack TemperatureActive204TempMR 199EU 352SV 183PER 01023H3 Stack TemperatureActive205TempMR 200EU 353SV 184PER 01025H2 Stack TemperatureActive206SO2MR 201CE 077EU 358SV 188PER 011Temporary TK2 SO2 CEMActive207NOxTBDMR 202Limas 11ABBGP 135PER 01275 Unit NOxActive208COTBDMR 203Uras 26ABBGP 135PER 01275 Unit COActive209O2TBDMR 204Magnos 206ABBGP 135PER 01275 Unit O2Active210Air FlowTBDMR 205DP-50EMRCGP 135PER 01275 Unit Stack FlowActivePage 13 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus194MR 189 PER 009Active195MR 190 PER 010NoActive196MR 191 PER 01022 25Active197MR 192 PER 01044 50Active198MR 193 PER 010445 500Active199MR 194 PER 010Active200MR 195 PER 010Active201MR 196 PER 010Active202MR 197 PER 010Active203MR 198 PER 010Active204MR 199 PER 010Active205MR 200 PER 010Active206MR 201 PER 011Active207MR 202 PER 0123.75 5NoActive208MR 203 PER 01215 20NoActive209MR 204 PER 01222 25NoActive210MR 205 PER 012NoActivePage 13 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ParametersMonitoredSerial NumberID No.Model NumberManufacturerOperatorIDfor ItemMonitoredItem(ID No(s).)RetiredBy(Action)AddedBy(Action)Monitor DescriptionMonitorStatus211Fuel UseMR 206EU 359PER 012Combustion Turbine Fuel Flow MeterActive212Fuel UseMR 207EU 360PER 012Duct Burners Fuel Flow MeterActive213MR 208GP 135PER 012CHP Facility Electricity Generation 1Active214MR 209GP 135PER 012CHP Facility Electricity Generation 2Active215MR 210GP 135PER 012CHP Facility Steam DeliveryActive216SO2MR 211EU 361PER 012ATS SO2 AnalyzerActive217O2MR 212EU 361PER 012ATS O2 AnalyzerActive218Air FlowMR 213EU 361PER 012ATS Air Flow MonitorActive219NOxMR 214EU 361PER 012ATS NOx AnalyzerActive220COMR 215EU 361PER 012ATS CO AnalyzerActive221TempMR 216GP 135PER 012Ambient Air MonitorActivePage 14 of 14 (a)11 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORS (MR)ID No.AddedBy(Action)SpanValueSystemFullScaleValueBypassCapability?RemovalDateInstallationDateOpticalPathLengthRatioMonitorStatus211MR 206 PER 012NoActive212MR 207 PER 012NoActive213MR 208 PER 012NoActive214MR 209 PER 012NoActive215MR 210 PER 012NoActive216MR 211 PER 012500NoActive217MR 212 PER 012Active218MR 213 PER 012Active219MR 214 PER 012Active220MR 215 PER 012Active221MR 216 PER 012ActivePage 14 of 14 (b)MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY11 December, 2014 16:09520 LAFAYETTE ROADST. PAUL, MN 55155-4194FACILITY DESCRIPTION: DATAACQUISITION SYSTEMS (DA)Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend RefineryID No.RemovalDateInstallationDateData StorageMediumSerial NumberManufacturerModel NumberDASStatusOperatorIDfor ItemData Acquisition System DescriptionRetiredBy(Action)AddedBy(Action)1DA 004ElectronicOSIActivePI Historian - for ATSPER 0122DA 001ElectronicActiveVCU Temperature Data Acquisition SystemPER 0103DA 002ElectronicOSIActivePI Historian - for 23H3PER 0104DA 003ElectronicOSIActivePI Historian - for 25H2PER 010Page 1 of 1MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:0911 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORING SYSTEMS (CM)ID No.AddedBy(Action)RetiredBy(Action)MonitorID No(s).DASID No(s).OperatorIDfor ItemCMS DescriptionParameterMonth/YearInstalledMonth/YearRemovedCert.DateCert.BasisCMSStatus1CM 001PER 001MR 004 New Truck Bottom Loading: 10 milligrams/liter of total organiccompounds gasoline loaded, EU 004Volatile Organic CompoundsOtherActive2CM 002PER 001MR 009 #1 Crude Heater Distillation: 12.8 lbs SO2 (1-hr & 3-hr ave., fuel flow),EU 005Fuel UsageOtherActive3CM 003PER 001MR 105 #1 Crude Heater Preflash: EU 006Fuel UsageOtherActive4CM 004PER 001MR 011 Vacuum Pre-Strip Heater: EU 016Fuel UsageOtherActive5CM 005PER 001MR 010 Vacuum Pre-Strip Heater: 0.045 lbs NOx/mmBtu, (3-hr ave.), EU 016Carbon MonoxideOtherActive6CM 006PER 001MR 016 #2 Vac Heater: 15.3 tons SO2/yr (365-day ave.), EU 019Fuel UsageOtherActive7CM 007PER 001MR 013MR 014#2 Vac Heater: EU 019Carbon MonoxideOtherActive8CM 008PER 001MR 013MR 015#2 Vac Heater:0.045 lbs NOx/mmBtu, (3-hr ave.) EU 019Nitrogen OxidesOtherActive9CM 009PER 001MR 026 # 1 Vac Heater: 6.5 lbs SO2/hr (3-hr & 24-hr ave., fuel flow), EU 026Fuel UsageOtherActive10CM 010PER 001MR 108MR 109# 1Coker Heater: 5.5 lbs SO2/hr (3-hr & 24-hr ave., fuel flow), EU028Fuel UsageOtherActive11CM 011PER 001MR 110MR 111#2 Coker Heater: 5.5 lbs SO2/hr (3-hr & 24-hr ave. fuel flow), EU 030Fuel UsageOtherActive12CM 012PER 001MR 112MR 113#3 Coker Heater: 9.7 lbs SO2/hr (3-hr & 24-hr ave., fuel flow), EU034Fuel UsageOtherActive13CM 013PER 001MR 027 #3 Coker Heater: 0.12 lbs NOx/mmBtu (365-day ave.) EU 035Nitrogen OxidesOtherActive14CM 014PER 001MR 027 #3 Coker Heater: 0.10 lbs CO/mmBtu (1-hr ave.) EU 035Carbon MonoxideOtherActive15CM 015PER 001MR 028MR 029MR 030MR 031#3 Coker Heater: EU 035Fuel UsageOtherActive16CM 016PER 001MR 032MR 034#3 Crude Unit Atm Distillate Heater: 0.12 lbs NOx/mmBtu (365-dayave.); 0.10 lbs CO/mmBtu (1-hr ave.); EU 040OxygenOtherActive17CM 017PER 001MR 033MR 035#3 Crude Unit Vac Distillate Heater: 0.12 lbs NOx/mmBtu (365-dayave.); 0.10 lbs CO/mmBtu (1-hr ave.); EU 041OxygenOtherActive18CM 018PER 001MR 037 #5 Sulfur Recovery Unit: 250 ppm (12-hr ave. ), EU 045; SV 042Oxygen40CFR60Active19CM 019PER 001MR 036 # 5 Sulfur Recovery Unit: 170.8 lbs SO2/hr (1-hr & 3-hr), SV 042Sulfur DioxideOtherActive20CM 020PER 001MR 114 # 5 Sulfur Recovery Unit: 121.0 tons CO/yr (365-day ave.), SV 045Carbon MonoxideOtherActive21CM 021PER 007MR 183 # 5 Sulfur Recovery Unit: 50 ppmvd NOx (24-hr roll. avg.; 9.7 lb/hr365-day roll. avg), SV 042Nitrogen OxidesOtherActivePage 1 of 3MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:0911 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORING SYSTEMS (CM)ID No.AddedBy(Action)RetiredBy(Action)MonitorID No(s).DASID No(s).OperatorIDfor ItemCMS DescriptionParameterMonth/YearInstalledMonth/YearRemovedCert.DateCert.BasisCMSStatus22CM 022PER 001MR 046MR 052MR 057Distillate HDS Recycle H2 Charge Heater: 0.08 lbs NOx/mmBtu(24-hr ave.) EU 050OxygenOtherActive23CM 023PER 001MR 047MR 053MR 056Distillate Hydrotreater Frac. Heater: 0.08 lbs NOx/mmBtu (24-hr ave.)EU 051OxygenOtherActive24CM 024PER 001MR 045 #2 H2 Plant Reformer Heater: 0.10 lbs NOx/ mmBtu (24-hr ave), EU052OxygenOtherActive25CM 025PER 001MR 049MR 054MR 055#2 H2 Plant Reformer Heater: EU 052, Fuel FlowFuel UsageOtherActive26CM 026PER 001MR 061 Naptha Hydrotreater Heater: 0.14 lbs NOx/mmBtu (24-hr aver < 90%);0.10 lbs NOx/mmBtu (24-hr ave. > 90%), EU 053OxygenOtherActive27CM 027PER 001MR 062MR 063Naptha Hydrotreater Heater: EU 053, fuel FlowFuel UsageOtherActive28CM 028PER 001MR 064 Powerformer Reactor Heaters: 0.045 lbs NOx/mmBtu (3-hr ave.); SV066OxygenOtherActive29CM 029PER 001MR 125MR 126MR 127Powerformer Reactor Heaters:SV 066, fuel flowFuel UsageOtherActive30CM 030PER 001MR 066 Gas Oil HDS Charge Heater: 0.045 lbs NOx/mmBtu (3-hr ave. ), EU084OxygenOtherActive31CM 031PER 001MR 068 Gas Oil HDA Charge Heater: 37.6 lbs SO2/hr (3-hr & 24-hr ave.), EU084, Fuel FlowFuel UsageOtherActive32CM 032PER 001MR 065 Gas Oil HDS Fract. Charge Heater: 0.045 lbs NOx/mmBtu (3-hr), EU085OxygenOtherActive33CM 033PER 001MR 067 Gas Oil HDS Fract. Charge Heater: 167.6 tons SO2/yr (365-day ave.)EU 084 and EU 085Fuel UsageOtherActive34CM 034PER 001MR 132 Platformer Heater/Interheaters: EU 095/EU 096/EU 097, SV 083, FuelFlowOxygenOtherActive35CM 035PER 001MR 130 Platformer Heater/Interheaters: SV 083Nitrogen OxidesOtherActive36CM 036PER 001MR 131 Platformer Heater/Interheaters: 0.040 lbs CO/mmBtu (3-hr ave.), SV083Carbon MonoxideOtherActive37CM 037PER 001MR 083 SRU #3 & #4: 200 ppm SO2 (12-hr ave.), SV 093OxygenOtherActive38CM 038PER 001MR 083 SRU #3 & #4: 250 ppm SO2 (12-hr ave.), SV 093Oxygen40CFR60Active39CM 039PER 001MR 084 SRU #3 & #4: 149.0 lbs SO2/hr (1-hr & 3-hr), SV 093Sulfur DioxideOtherActive40CM 040PER 001MR 087MR 089SRU #3 & #4: SV 093, Fuel Flow.Fuel UsageOtherActivePage 2 of 3MINNESOTA POLLUTION CONTROL AGENCYAIR QUALITY520 LAFAYETTE ROADST. PAUL, MN 55155-4194Show: Active and Pending RecordsAction: PER 012AQD Facility ID: 03700011Facility Name: Flint Hills Resources Pine Bend Refinery11 December, 2014 16:0911 December, 2014 16:09FACILITY DESCRIPTION: CONTINUOUS MONITORING SYSTEMS (CM)ID No.AddedBy(Action)RetiredBy(Action)MonitorID No(s).DASID No(s).OperatorIDfor ItemCMS DescriptionParameterMonth/YearInstalledMonth/YearRemovedCert.DateCert.BasisCMSStatus41CM 041PER 001MR 093 Steam Boiler No. 8: 0.20 lbs NOx/mmBtu (30-day ave. ), EU 204Oxygen40CFR60Active42CM 042PER 001MR 092MR 094Steam Boiler No. 8: EU 204, fuel flowFuel UsageOtherActive43CM 043PER 001MR 005 11H6 Heater: CO, EU 212Carbon MonoxideOtherActive44CM 044PER 001MR 006MR 00711H6 Heater: 0.045 lbs NOx/mmBtu (3-hr ave. ), EU 212Nitrogen OxidesOtherActive45CM 045PER 001MR 008 11H6 Heater: EU 212, fuel flowFuel UsageOtherActive46CM 046PER 001MR 043MR 048#3 H2 Heater: 0.042 lbs NOx/mmBtu (24-hr ave.), EU 213Nitrogen OxidesOtherActive47CM 047PER 001MR 044 #3 H2 Heater: CO, EU 213Carbon MonoxideOtherActive48CM 048PER 001MR 050MR 058MR 115#3 H2 Heater: EU 213, fuel flowFuel UsageOtherActive49CM 049PER 001MR 017 FCCU: 30% opacity (1-hr ave.), EU 228Opacity40CFR60Active50CM 050PER 001MR 018MR 106FCCU: 450 ppm NOx (24-hr ave.), EU 228Nitrogen OxidesOtherActive51CM 051PER 001MR 019 FCCU: 25 ppm SO2 (365-day ave.), EU 228Sulfur DioxideOtherActive52CM 052PER 001MR 019 FCCU: 50 ppm SO2 (7-day ave.), EU 228Sulfur Dioxide40CFR60Active53CM 053PER 001MR 021MR 107FCCU: 500 ppm CO (1-hr ave. ), EU 228Carbon Monoxide40CFR60Active54CM 054PER 001MR 022MR 023FCCU: EU 228, fuel flowFuel UsageOtherActive55CM 055PER 001MR 069MR 144Merox Off Gas Inc.: 230 lbs SO2/hr (3-hr ave.) EU 245Sulfur DioxideOtherActive56CM 055PER 012MR 069 31H2: 66.4 lbs SO2/hr (3-hr avg) EU 055Sulfur DioxideOtherActive57CM 056PER 001MR 071MR 103Merox Off Gas Incinerator/Back up: EU 254, TempActive58CM 056PER 012Merox Off Gas Incinerator/Back up: EU 254, TempRemoved59CM 057PER 010MR 190 DA 001 VCU ThermocoupleTemperature 02/2013ActivePage 3 of 3MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 004

Carbon Dioxide Equivalent PER 009 1.08E+04 2.47E+03 1.08E+04

Methane PER 009 5.79E-01 1.32E-01 5.79E-01

Carbon Dioxide PER 009 1.08E+04 2.47E+03 1.08E+04

Hydrogen Sulfide PER 009 1.25E-01 2.84E-02 1.25E-01

Nitrous Oxide PER 009 2.04E-02 4.65E-03 2.04E-02

EU 005

Benzene PER 009 1.08E-03 2.47E-04 1.08E-03

A rsenic compounds PER 009 1.03E-04 2.35E-05 1.03E-04

Beryllium Compounds PER 009 6.18E-06 1.41E-06 6.18E-06

Carbon Dioxide Equivalent PER 010 7.12E+04 1.63E+04 7.12E+04

Cadmium compounds PER 009 5.66E-04 1.29E-04 5.66E-04

Methane PER 009 3.47E+00 7.93E-01 3.47E+00

Carbon Monoxide PER 001 2.10E+01 4.80E+00 2.10E+01

Carbon Dioxide PER 010 7.09E+04 1.62E+04 7.09E+04

Cobalt compounds PER 009 4.32E-05 9.87E-06 4.32E-05

Chromium compounds PER 009 7.21E-04 1.65E-04 7.21E-04

1,4-Dichlorobenzene PER 009 6.18E-04 1.41E-04 6.18E-04

Formaldehyde PER 009 3.86E-02 8.82E-03 3.86E-02

Hexane PER 009 9.27E-01 2.12E-01 9.27E-01

Naphthalene PER 009 3.14E-04 7.17E-05 3.14E-04

HAPs - Total PER 009 9.72E-01 2.22E-01 9.72E-01

Mercury Compounds PER 009 1.34E-04 3.06E-05 1.34E-04

Toluene PER 009 1.75E-03 4.00E-04 1.75E-03

Manganese compounds PER 009 1.96E-04 4.47E-05 1.96E-04

Nitrous Oxide PER 009 6.95E-01 1.59E-01 6.95E-01

Nickel compounds PER 009 1.08E-03 2.47E-04 1.08E-03

Nitrogen Oxides PER 001 2.36E+01 5.40E+00 2.36E+01

PM < 2.5 micron PER 009 3.91E+00 8.93E-01 3.91E+00

Lead PER 009 2.57E-04 5.88E-05 2.57E-04

PM < 10 micron PER 009 3.91E+00 8.93E-01 3.91E+00

Polycyclic organic matter PER 009 4.54E-05 1.04E-05 4.54E-05

Total Particulate Matter PER 009 3.91E+00 8.93E-01 3.91E+00

Selenium compounds PER 009 1.24E-05 2.82E-06 1.24E-05

Sulfur Dioxide PER 009 5.59E+01 5.07E+00 1.20E+01

Volatile Organic Compounds PER 009 2.83E+00 6.47E-01 2.83E+00

EU 006

Benzene PER 009 5.14E-04 1.17E-04 5.14E-04

A rsenic compounds PER 009 4.90E-05 1.12E-05 4.90E-05

Beryllium PER 009 2.94E-06 6.71E-07 2.94E-06

Carbon Dioxide Equivalent PER 010 3.38E+04 7.73E+03 3.38E+04

Cadmium compounds PER 009 2.69E-04 6.15E-05 2.69E-04

Methane PER 009 1.65E+00 3.77E-01 1.65E+00

Carbon Monoxide PER 001 2.06E+01 4.69E+00 2.06E+01

Carbon Dioxide PER 010 3.37E+04 7.70E+03 3.37E+04

Cobalt compounds PER 009 2.06E-05 4.69E-06 2.06E-05

Chromium compounds PER 009 3.43E-04 7.82E-05 3.43E-04

Page 1 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 006

1,4-Dichlorobenzene PER 009 2.94E-04 6.71E-05 2.94E-04

Formaldehyde PER 009 1.84E-02 4.19E-03 1.84E-02

Hexane PER 009 4.41E-01 1.01E-01 4.41E-01

Naphthalene PER 009 1.49E-04 3.41E-05 1.49E-04

HAPs - Total PER 009 4.62E-01 1.05E-01 4.62E-01

Mercury PER 009 6.36E-05 1.45E-05 6.36E-05

Toluene PER 009 8.32E-04 1.90E-04 8.32E-04

Manganese compounds PER 009 9.30E-05 2.12E-05 9.30E-05

Nitrous Oxide PER 009 3.30E-01 7.54E-02 3.30E-01

Nickel compounds PER 009 5.14E-04 1.17E-04 5.14E-04

Nitrogen Oxides PER 009 1.12E+01 2.57E+00 1.12E+01

PM < 2.5 micron PER 009 1.86E+00 4.25E-01 1.86E+00

Lead PER 009 1.22E-04 2.79E-05 1.22E-04

PM < 10 micron PER 009 1.86E+00 4.25E-01 1.86E+00

Polycyclic organic matter PER 009 2.16E-05 4.93E-06 2.16E-05

Total Particulate Matter PER 009 1.86E+00 4.25E-01 1.86E+00

Selenium compounds PER 009 5.87E-06 1.34E-06 5.87E-06

Sulfur Dioxide PER 001 5.70E+00 2.41E+00 5.70E+00

Volatile Organic Compounds PER 009 1.35E+00 3.07E-01 1.35E+00

EU 007

A cetaldehyde PER 001 4.99E-04 1.14E-04 4.99E-04

A crolein PER 001 1.56E-04 3.56E-05 1.56E-04

Benzene PER 001 1.54E-02 3.51E-03 1.54E-02

A rsenic compounds PER 001 8.32E-05 1.90E-05 8.32E-05

Beryllium Compounds PER 001 4.95E-05 1.13E-05 4.95E-05

Carbon Dioxide Equivalent PER 009 3.70E+02 7.40E+02 3.24E+03

Cadmium compounds PER 001 2.18E-04 4.97E-05 2.18E-04

Methane PER 009 1.50E-02 2.99E-02 1.31E-01

Carbon Monoxide PER 001 1.45E+01 3.32E+00 1.45E+01

Carbon Dioxide PER 009 3.69E+02 7.37E+02 3.23E+03

Chromium compounds PER 009 1.33E-03 3.03E-04 1.33E-03

Formaldehyde PER 001 1.56E-03 3.57E-04 1.56E-03

Naphthalene PER 001 2.58E-03 5.88E-04 2.58E-03

HAPs - Total PER 001 3.49E-02 7.98E-03 3.49E-02

Mercury Compounds PER 001 5.94E-05 1.36E-05 5.94E-05

Toluene PER 001 5.57E-03 1.27E-03 5.57E-03

Xylenes (mixed isomers) PER 009 3.82E-03 8.73E-04 3.82E-03

Manganese compounds PER 001 2.77E-04 6.33E-05 2.77E-04

Nitrous Oxide PER 009 2.99E-03 5.98E-03 2.62E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.37E-03 7.69E-04 3.37E-03

Nitrogen Oxides PER 001 6.34E+01 1.45E+01 6.34E+01

PM < 2.5 micron PER 009 1.85E+00 4.22E-01 1.85E+00

PM < 10 micron PER 009 1.85E+00 4.22E-01 1.85E+00

Total Particulate Matter PER 009 1.85E+00 4.22E-01 1.85E+00

Sulfur Dioxide PER 009 1.06E+00 2.41E-01 1.06E+00

Page 2 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 007

Volatile Organic Compounds PER 009 1.69E+00 3.86E-01 1.69E+00

EU 016

Benzene PER 009 1.25E-03 2.85E-04 1.25E-03

A rsenic compounds PER 009 1.19E-04 2.71E-05 1.19E-04

Beryllium Compounds PER 009 7.12E-06 1.63E-06 7.12E-06

Carbon Dioxide Equivalent PER 010 8.20E+04 1.87E+04 8.20E+04

Cadmium compounds PER 009 6.53E-04 1.49E-04 6.53E-04

Methane PER 009 4.00E+00 9.14E-01 4.00E+00

Carbon Monoxide PER 009 4.98E+01 1.14E+01 4.98E+01

Carbon Dioxide PER 010 8.17E+04 1.87E+04 8.17E+04

Cobalt compounds PER 009 4.98E-05 1.14E-05 4.98E-05

Chromium compounds PER 009 8.31E-04 1.90E-04 8.31E-04

1,4-Dichlorobenzene PER 009 7.12E-04 1.63E-04 7.12E-04

Formaldehyde PER 009 4.45E-02 1.02E-02 4.45E-02

Hexane PER 009 1.07E+00 2.44E-01 1.07E+00

Naphthalene PER 009 3.62E-04 8.26E-05 3.62E-04

HAPs - Total PER 009 1.12E+00 2.56E-01 1.12E+00

Mercury Compounds PER 009 1.54E-04 3.52E-05 1.54E-04

Toluene PER 009 2.02E-03 4.61E-04 2.02E-03

Manganese compounds PER 009 2.26E-04 5.15E-05 2.26E-04

Nitrous Oxide PER 009 8.01E-01 1.83E-01 8.01E-01

Nickel compounds PER 009 1.25E-03 2.85E-04 1.25E-03

Nitrogen Oxides PER 009 2.72E+01 6.22E+00 2.72E+01

PM < 2.5 micron PER 009 4.51E+00 1.03E+00 4.51E+00

Lead PER 009 2.97E-04 6.77E-05 2.97E-04

PM < 10 micron PER 009 4.51E+00 1.03E+00 4.51E+00

Polycyclic organic matter PER 009 5.23E-05 1.20E-05 5.23E-05

Total Particulate Matter PER 009 4.51E+00 1.03E+00 4.51E+00

Selenium compounds PER 009 1.42E-05 3.25E-06 1.42E-05

Sulfur Dioxide PER 009 1.38E+01 5.85E+00 1.38E+01

Volatile Organic Compounds PER 009 3.26E+00 7.45E-01 3.26E+00

EU 019

Benzene PER 009 2.14E-03 4.88E-04 2.14E-03

A rsenic compounds PER 009 2.04E-04 4.65E-05 2.04E-04

Beryllium Compounds PER 009 1.22E-05 2.79E-06 1.22E-05

Carbon Dioxide Equivalent PER 010 1.41E+05 3.21E+04 1.41E+05

Cadmium compounds PER 009 1.12E-03 2.56E-04 1.12E-03

Methane PER 009 6.87E+00 1.57E+00 6.87E+00

Carbon Monoxide PER 001 4.15E+01 9.48E+00 4.15E+01

Carbon Dioxide PER 010 1.40E+05 3.20E+04 1.40E+05

Cobalt compounds PER 009 8.55E-05 1.95E-05 8.55E-05

Chromium compounds PER 009 1.42E-03 3.25E-04 1.42E-03

1,4-Dichlorobenzene PER 009 1.22E-03 2.79E-04 1.22E-03

Formaldehyde PER 009 7.63E-02 1.74E-02 7.63E-02

Hexane PER 009 1.83E+00 4.18E-01 1.83E+00

Naphthalene PER 009 6.21E-04 1.42E-04 6.21E-04

Page 3 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 019

HAPs - Total PER 009 1.92E+00 4.39E-01 1.92E+00

Mercury Compounds PER 009 2.65E-04 6.04E-05 2.65E-04

Toluene PER 009 3.46E-03 7.90E-04 3.46E-03

Manganese compounds PER 009 3.87E-04 8.83E-05 3.87E-04

Nitrous Oxide PER 009 1.37E+00 3.13E-01 1.37E+00

Nickel compounds PER 009 2.14E-03 4.88E-04 2.14E-03

Nitrogen Oxides PER 009 4.67E+01 1.07E+01 4.67E+01

PM < 2.5 micron PER 009 7.73E+00 1.77E+00 7.73E+00

Lead PER 009 5.09E-04 1.16E-04 5.09E-04

PM < 10 micron PER 001 7.73E+00 1.77E+00 7.73E+00

Polycyclic organic matter PER 009 8.98E-05 2.05E-05 8.98E-05

Total Particulate Matter PER 001 7.73E+00 1.77E+00 7.73E+00

Selenium compounds PER 009 2.44E-05 5.58E-06 2.44E-05

Sulfur Dioxide PER 009 1.53E+01 1.00E+01 2.37E+01

Volatile Organic Compounds PER 001 5.60E+00 1.28E+00 5.60E+00

EU 024

A cetaldehyde PER 001 4.99E-04 1.14E-04 4.99E-04

A crolein PER 001 1.56E-04 3.56E-05 1.56E-04

Benzene PER 001 1.54E-02 3.51E-03 1.54E-02

A rsenic compounds PER 001 8.32E-05 1.90E-05 8.32E-05

Beryllium Compounds PER 001 4.95E-05 1.13E-05 4.95E-05

Carbon Dioxide Equivalent PER 009 3.70E+02 7.40E+02 3.24E+03

Cadmium compounds PER 001 2.18E-04 4.97E-05 2.18E-04

Methane PER 009 1.50E-02 2.99E-02 1.31E-01

Carbon Monoxide PER 001 1.45E+01 3.32E+00 1.45E+01

Carbon Dioxide PER 009 3.69E+02 7.37E+02 3.23E+03

Chromium compounds PER 001 1.33E-03 3.03E-04 1.33E-03

Formaldehyde PER 001 1.56E-03 3.57E-04 1.56E-03

Naphthalene PER 001 2.58E-03 5.88E-04 2.58E-03

HAPs - Total PER 001 3.49E-02 7.98E-03 3.49E-02

Mercury Compounds PER 001 5.94E-05 1.36E-05 5.94E-05

Toluene PER 001 5.57E-03 1.27E-03 5.57E-03

Xylenes (mixed isomers) PER 009 3.82E-03 8.73E-04 3.82E-03

Manganese compounds PER 001 2.77E-04 6.33E-05 2.77E-04

Nitrous Oxide PER 009 2.99E-03 5.98E-03 2.62E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.37E-03 7.69E-04 3.37E-03

Nitrogen Oxides PER 001 6.34E+01 1.45E+01 6.34E+01

PM < 2.5 micron PER 009 1.85E+00 4.22E-01 1.85E+00

PM < 10 micron PER 009 1.85E+00 4.22E-01 1.85E+00

Total Particulate Matter PER 009 1.85E+00 4.22E-01 1.85E+00

Sulfur Dioxide PER 009 1.06E+00 2.41E-01 1.06E+00

Volatile Organic Compounds PER 009 1.69E+00 3.86E-01 1.69E+00

EU 026

Benzene PER 009 1.32E-03 3.01E-04 1.32E-03

A rsenic compounds PER 009 1.25E-04 2.86E-05 1.25E-04

Page 4 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 026

Beryllium Compounds PER 009 7.52E-06 1.72E-06 7.52E-06

Carbon Dioxide Equivalent PER 010 8.67E+04 1.98E+04 8.67E+04

Cadmium compounds PER 009 6.90E-04 1.57E-04 6.90E-04

Methane PER 010 4.23E+00 9.66E-01 4.23E+00

Carbon Monoxide PER 009 5.27E+01 1.20E+01 5.27E+01

Carbon Dioxide PER 010 8.63E+04 1.97E+04 8.63E+04

Cobalt compounds PER 009 5.27E-05 1.20E-05 5.27E-05

Chromium compounds PER 009 8.78E-04 2.00E-04 8.78E-04

1,4-Dichlorobenzene PER 009 7.52E-04 1.72E-04 7.52E-04

Formaldehyde PER 009 4.70E-02 1.07E-02 4.70E-02

Hexane PER 009 1.13E+00 2.58E-01 1.13E+00

Naphthalene PER 009 3.82E-04 8.73E-05 3.82E-04

HAPs - Total PER 009 1.18E+00 2.70E-01 1.18E+00

Mercury Compounds PER 009 1.63E-04 3.72E-05 1.63E-04

Toluene PER 009 2.13E-03 4.87E-04 2.13E-03

Manganese compounds PER 009 2.38E-04 5.44E-05 2.38E-04

Nitrous Oxide PER 010 8.46E-01 1.93E-01 8.46E-01

Nickel compounds PER 009 1.32E-03 3.01E-04 1.32E-03

Nitrogen Oxides PER 009 2.87E+01 6.57E+00 2.88E+01

PM < 2.5 micron PER 009 4.76E+00 1.09E+00 4.76E+00

Lead PER 009 3.13E-04 7.16E-05 3.13E-04

PM < 10 micron PER 009 4.76E+00 1.09E+00 4.76E+00

Polycyclic organic matter PER 009 5.53E-05 1.26E-05 5.53E-05

Total Particulate Matter PER 009 4.76E+00 1.09E+00 4.76E+00

Selenium compounds PER 009 1.50E-05 3.44E-06 1.50E-05

Sulfur Dioxide PER 009 2.86E+01 6.18E+00 1.46E+01

Volatile Organic Compounds PER 009 3.45E+00 7.87E-01 3.45E+00

EU 028

Benzene PER 009 1.33E-03 3.04E+04 1.33E-03

A rsenic compounds PER 009 1.27E-04 2.89E-05 1.27E-04

Beryllium Compounds PER 009 7.61E-06 1.74E-06 7.61E-06

Carbon Dioxide Equivalent PER 010 8.76E+04 2.00E+04 8.76E+04

Cadmium compounds PER 009 6.97E-04 1.59E-04 6.97E-04

Methane PER 009 4.28E+00 9.76E-01 4.28E+00

Carbon Monoxide PER 009 5.32E+01 1.22E+01 5.32E+01

Carbon Dioxide PER 010 8.73E+04 1.99E+04 8.73E+04

Cobalt compounds PER 009 5.32E-05 1.22E-05 5.32E-05

Chromium compounds PER 009 8.87E-04 2.03E-04 8.87E-04

1,4-Dichlorobenzene PER 009 7.61E-04 1.74E-04 7.61E-04

Formaldehyde PER 009 4.75E-02 1.09E-02 4.75E-02

Hexane PER 009 1.14E+00 2.60E-01 1.14E+00

Naphthalene PER 009 3.87E-04 8.83E-05 3.87E-04

HAPs - Total PER 009 1.20E+00 2.73E-01 1.20E+00

Mercury Compounds PER 009 1.65E-04 3.76E-05 1.65E-04

Toluene PER 009 2.15E-03 4.92E-04 2.15E-03

Manganese compounds PER 009 2.41E-04 5.50E-05 2.41E-04

Page 5 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 028

Nitrous Oxide PER 009 8.55E-01 1.95E-01 8.55E-01

Nickel compounds PER 009 1.33E-03 3.04E-04 1.33E-03

Nitrogen Oxides PER 009 1.77E+02 4.05E+01 1.77E+02

PM < 2.5 micron PER 009 4.82E+00 1.10E+00 4.82E+00

Lead PER 009 3.17E-04 7.24E-05 3.17E-04

PM < 10 micron PER 009 4.82E+00 1.10E+00 4.82E+00

Polycyclic organic matter PER 009 5.59E-05 1.28E-05 5.59E-05

Total Particulate Matter PER 009 4.82E+00 1.10E+00 4.82E+00

Selenium compounds PER 009 1.52E-05 3.47E-06 1.52E-05

Sulfur Dioxide PER 009 2.39E+01 6.24E+00 1.48E+01

Volatile Organic Compounds PER 009 3.49E+00 7.96E-01 3.49E+00

EU 030

Benzene PER 009 1.33E-03 3.04E-04 1.33E-03

A rsenic compounds PER 009 1.27E-04 2.90E-05 1.27E-04

Beryllium Compounds PER 009 7.62E-06 1.74E-06 7.62E-06

Carbon Dioxide Equivalent PER 010 8.77E+04 2.00E+04 8.77E+04

Cadmium compounds PER 009 6.98E-04 1.59E-04 6.98E-04

Methane PER 009 4.88E+00 9.78E-01 4.28E+00

Carbon Monoxide PER 009 5.33E+01 1.22E+01 5.33E+01

Carbon Dioxide PER 010 8.74E+04 2.00E+04 8.74E+04

Cobalt compounds PER 009 5.33E-05 1.22E-05 5.33E-05

Chromium compounds PER 009 8.89E-04 2.03E-04 8.89E-04

1,4-Dichlorobenzene PER 009 7.62E-04 1.74E-04 7.62E-04

Formaldehyde PER 009 4.76E-02 1.09E-02 4.76E-02

Hexane PER 009 1.14E+00 2.61E-01 1.14E+00

Naphthalene PER 009 3.87E-04 8.84E-05 3.87E-04

HAPs - Total PER 009 1.20E+00 2.73E-04 1.20E+00

Mercury Compounds PER 009 1.65E-04 3.77E-05 1.65E-04

Toluene PER 009 2.16E-03 4.93E-04 2.16E-03

Manganese compounds PER 009 2.41E-04 5.51E-05 2.41E-04

Nitrous Oxide PER 009 8.56E-01 1.96E-01 8.56E-01

Nickel compounds PER 009 1.33E-03 3.04E-04 1.33E-03

Nitrogen Oxides PER 009 1.78E+02 4.06E+01 1.78E+02

PM < 2.5 micron PER 009 4.82E+00 1.10E+00 4.82E+00

Lead PER 009 3.17E-04 7.25E-05 3.17E-04

PM < 10 micron PER 009 4.82E+00 1.10E+00 4.82E+00

Polycyclic organic matter PER 009 5.60E-05 1.28E-05 5.60E-05

Total Particulate Matter PER 009 4.82E+00 1.10E+00 4.82E+00

Selenium compounds PER 009 1.52E-05 3.48E-06 1.52E-05

Sulfur Dioxide PER 009 1.48E+01 6.25E+00 1.48E+01

Volatile Organic Compounds PER 009 3.49E+00 7.97E-01 3.49E+00

EU 032

Carbon Dioxide Equivalent PER 010 3.58E+02 1.66E+03 7.27E+03

Methane PER 010 1.06E+00 4.91E+00 2.15E+01

Carbon Monoxide PER 009 2.31E+00 1.07E+01 2.31E+00

Carbon Dioxide PER 010 3.34E+02 1.55E+03 6.78E+03

Page 6 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 032

Hydrogen Sulfide PER 009 3.67E-01 1.50E+01 3.67E-01

Nitrous Oxide PER 010 5.22E-03 2.42E-02 1.06E-01

Nitrogen Oxides PER 009 4.97E-01 2.30E+00 4.97E-01

PM < 2.5 micron PER 009 2.61E-01 1.21E+00 2.61E-01

Lead PER 009 2.00E-03 9.28E-03 2.00E-03

PM < 10 micron PER 009 2.61E-01 1.21E+00 2.61E-01

Total Particulate Matter PER 009 5.01E-01 2.32E+00 5.01E-01

Sulfur Dioxide PER 009 1.73E+00 8.00E+00 1.73E+00

Volatile Organic Compounds PER 009 5.01E-01 2.32E+00 5.01E-01

EU 033

Carbon Dioxide Equivalent PER 010 3.58E+02 1.66E+03 7.27E+03

Methane PER 010 1.06E+00 4.91E+00 2.15E+01

Carbon Monoxide PER 009 2.31E+00 1.07E+01 2.31E+00

Carbon Dioxide PER 010 3.34E+02 1.55E+03 6.78E+03

Hydrogen Sulfide PER 009 3.67E-01 1.50E+01 3.67E-01

Nitrous Oxide PER 010 5.22E-03 2.42E-02 1.06E-01

Nitrogen Oxides PER 009 4.97E-01 2.30E+00 4.97E-01

PM < 2.5 micron PER 009 2.61E-01 1.21E+00 2.61E-01

Lead PER 009 2.00E-03 9.28E-03 2.00E-03

PM < 10 micron PER 009 2.61E-01 1.21E+00 2.61E-01

Total Particulate Matter PER 009 5.01E-01 2.32E+00 5.01E-01

Sulfur Dioxide PER 009 1.73E+00 8.00E+00 1.73E+00

Volatile Organic Compounds PER 009 5.01E-01 2.32E+00 5.01E-01

EU 034

Benzene PER 009 1.49E-03 3.40E-04 1.49E-03

A rsenic compounds PER 009 1.42E-04 3.24E-05 1.42E-04

Beryllium Compounds PER 009 8.50E-06 1.94E-06 8.50E-06

Carbon Dioxide Equivalent PER 010 8.93E+04 2.04E+04 8.93E+04

Cadmium compounds PER 009 7.79E-04 1.78E-04 7.79E-04

Methane PER 009 4.78E+00 1.09E+00 4.78E+00

Carbon Monoxide PER 001 5.95E+01 1.36E+01 5.95E+01

Carbon Dioxide PER 010 8.89E+04 2.03E+04 8.89E+04

Cobalt compounds PER 009 5.95E-05 1.36E-05 5.95E-05

Chromium compounds PER 009 9.92E-04 2.26E-04 9.92E-04

1,4-Dichlorobenzene PER 009 8.50E-04 1.94E-04 8.50E-04

Formaldehyde PER 009 5.31E-02 1.21E-02 5.31E-02

Hexane PER 009 1.28E+00 2.91E-01 1.28E+00

Naphthalene PER 009 4.32E-04 9.87E-05 4.32E-04

HAPs - Total PER 009 1.34E+00 3.05E-04 1.34E+00

Mercury Compounds PER 009 1.84E-04 4.21E-05 1.84E-04

Toluene PER 009 2.41E-03 5.50E-04 2.41E-03

Manganese compounds PER 009 2.69E-04 6.15E-05 2.69E-04

Nitrous Oxide PER 009 9.56E-01 2.18E-01 9.56E-01

Nickel compounds PER 009 1.49E-03 3.40E-04 1.49E-03

Nitrogen Oxides PER 009 1.98E+02 4.53E+01 1.98E+02

PM < 2.5 micron PER 009 5.38E+00 1.23E+00 5.38E+00

Page 7 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 034

Lead PER 009 3.54E-04 8.09E-05 3.54E-04

PM < 10 micron PER 001 5.38E+00 1.23E+00 5.38E+00

Polycyclic organic matter PER 009 6.25E-05 1.43E-05 6.25E-05

Total Particulate Matter PER 001 5.38E+00 1.23E+00 5.38E+00

Selenium compounds PER 009 1.70E-05 3.88E-06 1.70E-05

Sulfur Dioxide PER 009 4.25E+01 1.27E+01 5.58E+01

Volatile Organic Compounds PER 001 3.90E+00 8.90E-01 3.90E+00

EU 035

Benzene PER 009 1.10E-03 2.51E-04 1.10E-03

A rsenic compounds PER 009 1.05E-04 2.39E-05 1.05E-04

Beryllium Compounds PER 009 6.29E-06 1.44E-06 6.29E-06

Carbon Dioxide Equivalent PER 010 6.60E+04 1.51E+04 6.60E+04

Cadmium compounds PER 009 5.76E-04 1.32E-04 5.76E-04

Methane PER 009 3.34E+00 8.07E-01 3.53E+00

Carbon Monoxide PER 009 5.34E+01 1.22E+01 5.34E+01

Carbon Dioxide PER 010 6.57E+04 1.50E+04 6.57E+04

Cobalt compounds PER 009 4.40E-05 1.00E-05 4.40E-05

Chromium compounds PER 009 7.33E-04 1.67E-04 7.33E-04

1,4-Dichlorobenzene PER 009 6.29E-04 1.44E-04 6.29E-04

Formaldehyde PER 009 3.93E-02 8.97E-03 3.93E-02

Hexane PER 009 9.43E-01 2.15E-01 9.43E-01

Naphthalene PER 009 3.20E-04 7.30E-05 3.20E-04

HAPs - Total PER 009 9.89E-01 2.26E-01 9.89E-01

Mercury Compounds PER 009 1.36E-04 3.11E-05 1.36E-04

Toluene PER 009 1.78E-03 4.07E-04 1.78E-03

Manganese compounds PER 009 1.99E-04 4.55E-05 1.99E-04

Nitrous Oxide PER 009 6.68E-01 1.61E-01 7.07E-01

Nickel compounds PER 009 1.10E-03 2.51E-04 1.10E-03

Nitrogen Oxides PER 009 6.41E+01 1.46E+01 6.41E+01

PM < 2.5 micron PER 009 3.98E+00 9.09E-01 3.98E+00

Lead PER 009 2.62E-04 5.98E-05 2.62E-04

PM < 10 micron PER 009 3.98E+00 9.09E-01 3.98E+00

Polycyclic organic matter PER 009 4.62E-05 1.05E-05 4.62E-05

Total Particulate Matter PER 009 3.98E+00 9.09E-01 3.98E+00

Selenium compounds PER 009 1.26E-05 2.87E-06 1.26E-05

Sulfur Dioxide PER 009 4.13E+01 9.42E+00 4.13E+01

Volatile Organic Compounds PER 009 2.88E+00 6.58E-01 2.88E+00

EU 036

A cetaldehyde PER 001 5.67E-04 1.29E-04 5.67E-04

A crolein PER 001 1.77E-04 4.05E-05 1.77E-04

Benzene PER 001 1.75E-02 3.99E-03 1.75E-02

A rsenic compounds PER 001 9.45E-05 2.16E-05 9.45E-05

Beryllium Compounds PER 001 5.63E-05 1.28E-05 5.63E-05

Carbon Dioxide Equivalent PER 009 4.20E+02 8.40E+02 3.68E+03

Cadmium compounds PER 001 2.48E-04 5.65E-05 2.48E-04

Methane PER 009 1.70E-02 3.40E-02 1.49E-01

Page 8 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 036

Carbon Monoxide PER 001 1.65E+01 3.77E+00 1.65E+01

Carbon Dioxide PER 009 4.19E+02 8.38E+02 3.67E+03

Chromium compounds PER 001 1.51E-03 3.44E-04 1.51E-03

Formaldehyde PER 001 1.78E-03 4.05E-04 1.78E-03

Naphthalene PER 001 2.93E-03 6.68E-04 2.93E-03

HAPs - Total PER 001 3.97E-02 9.06E-03 3.97E-02

Mercury Compounds PER 001 6.75E-05 1.54E-05 6.75E-05

Toluene PER 001 6.32E-03 1.44E-03 6.32E-03

Xylenes (mixed isomers) PER 009 4.34E-03 9.92E-04 4.34E-03

Manganese compounds PER 001 3.15E-04 7.19E-05 3.15E-04

Nitrous Oxide PER 009 3.40E-03 6.80E-03 2.98E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.83E-03 8.73E-04 3.83E-03

Nitrogen Oxides PER 001 7.20E+01 1.64E+01 7.20E+01

PM < 2.5 micron PER 009 2.10E+00 4.80E-01 2.10E+00

PM < 10 micron PER 001 2.10E+00 4.80E-01 2.10E+00

Total Particulate Matter PER 001 2.10E+00 4.80E-01 2.10E+00

Sulfur Dioxide PER 009 1.20E+00 2.74E-01 1.20E+00

Volatile Organic Compounds PER 009 1.92E+00 4.38E-01 1.92E+00

EU 037

Carbon Dioxide Equivalent PER 010 1.43E+02 6.61E+02 2.90E+03

Methane PER 010 5.27E-01 2.44E+00 1.07E+01

Carbon Monoxide PER 009 4.63E+00 2.14E+01 4.63E+00

Carbon Dioxide PER 010 1.31E+02 6.07E+02 2.66E+03

Hydrogen Sulfide PER 009 3.33E-01 1.31E+01 3.33E-01

Nitrous Oxide PER 010 2.05E-03 9.49E-03 4.16E-02

Nitrogen Oxides PER 009 4.95E-01 2.29E+00 4.95E-01

PM < 2.5 micron PER 009 1.02E-01 4.73E-01 1.02E-01

Lead PER 009 7.86E-04 3.64E-03 7.86E-04

PM < 10 micron PER 009 1.02E-01 4.73E-01 1.02E-01

Total Particulate Matter PER 009 1.97E-01 9.10E-01 1.97E-01

Sulfur Dioxide PER 009 2.18E+00 1.01E+01 2.18E+00

Volatile Organic Compounds PER 009 1.97E-01 9.10E-01 1.97E-01

EU 038

Carbon Dioxide Equivalent PER 010 1.43E+02 6.61E+02 2.90E+03

Methane PER 010 5.27E-01 2.44E+00 1.07E+01

Carbon Monoxide PER 009 4.63E+00 2.14E+01 4.63E+00

Carbon Dioxide PER 010 1.31E+02 6.07E+02 2.66E+03

Hydrogen Sulfide PER 009 3.33E-01 1.31E+01 3.33E-01

Nitrous Oxide PER 010 2.05E-03 9.49E-03 4.16E-02

Nitrogen Oxides PER 009 4.95E-01 2.29E+00 4.95E-01

PM < 2.5 micron PER 009 1.02E-01 4.73E-01 1.02E-01

Lead PER 001 7.86E-04 3.64E-03 7.86E-04

PM < 10 micron PER 009 1.02E-01 4.73E-01 1.02E-01

Total Particulate Matter PER 009 1.97E-01 9.10E-01 1.97E-01

Sulfur Dioxide PER 009 2.18E+00 1.01E+01 2.18E+00

Page 9 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 038

Volatile Organic Compounds PER 009 1.97E-01 9.10E-01 1.97E-01

EU 040

Benzene PER 009 2.28E-03 5.21E-04 2.28E-03

A rsenic compounds PER 009 2.17E-04 4.96E-05 2.17E-04

Beryllium Compounds PER 009 1.30E-05 2.98E-06 1.30E-05

Carbon Dioxide Equivalent PER 010 1.37E+05 3.13E+04 1.37E+05

Cadmium compounds PER 009 1.20E-03 2.73E-04 1.20E-03

Methane PER 009 7.33E+00 1.67E+00 7.33E+00

Carbon Monoxide PER 009 1.11E+01 2.53E+01 1.11E+02

Carbon Dioxide PER 010 1.36E+05 3.11E+04 1.36E+05

Cobalt compounds PER 009 9.13E-05 2.08E-05 9.13E-05

Chromium compounds PER 009 1.52E-03 3.47E-04 1.52E-03

1,4-Dichlorobenzene PER 009 1.30E-03 2.98E-04 1.30E-03

Formaldehyde PER 009 8.15E-02 1.86E-02 8.15E-02

Hexane PER 009 1.96E+00 4.46E-01 1.96E+00

Naphthalene PER 009 6.63E-04 1.51E-04 6.63E-04

HAPs - Total PER 009 2.05E+00 4.68E-01 2.05E+00

Mercury Compounds PER 009 2.82E-04 6.45E-05 2.82E-04

Toluene PER 009 3.69E-03 8.43E-04 3.69E-03

Manganese compounds PER 009 4.13E-04 9.43E-05 4.13E-04

Nitrous Oxide PER 009 1.47E+00 3.35E-01 1.47E+00

Nickel compounds PER 009 2.28E-03 5.21E-04 2.28E-03

Nitrogen Oxides PER 009 4.99E+01 1.14E+01 4.99E+01

PM < 2.5 micron PER 009 8.26E+00 1.89E+00 8.26E+00

Lead PER 009 5.43E-04 1.24E-04 5.43E-04

PM < 10 micron PER 001 8.26E+00 1.89E+00 8.26E+00

Polycyclic organic matter PER 009 9.58E-05 2.19E-05 9.58E-05

Total Particulate Matter PER 001 8.26E+00 1.89E+00 8.26E+00

Selenium compounds PER 009 2.61E-05 5.95E-06 2.61E-05

Sulfur Dioxide PER 009 8.55E+01 1.95E+01 8.55E+01

Volatile Organic Compounds PER 001 5.98E+00 1.36E+00 5.98E+00

EU 041

Benzene PER 009 1.86E-03 4.24E-04 1.86E-03

A rsenic compounds PER 009 1.77E-04 4.04E-05 1.77E-04

Beryllium Compounds PER 009 1.06E-05 2.42E-06 1.06E-05

Carbon Dioxide Equivalent PER 010 1.11E+05 2.55E+04 1.11E+05

Cadmium compounds PER 009 9.73E-04 2.22E-04 9.73E-04

Methane PER 009 5.97E+00 1.36E+00 5.97E+00

Carbon Monoxide PER 009 9.90E+00 2.06E+01 9.02E+01

Carbon Dioxide PER 010 1.11E+05 2.53E+04 1.11E+05

Cobalt compounds PER 009 7.43E-05 1.70E-05 7.43E-05

Chromium compounds PER 009 1.24E-03 2.83E-04 1.24E-03

1,4-Dichlorobenzene PER 009 1.06E-03 2.42E-04 1.06E-03

Formaldehyde PER 009 6.63E-02 1.51E-02 6.63E-02

Hexane PER 009 1.59E+00 3.64E-01 1.59E+00

Naphthalene PER 009 5.40E-04 1.23E-04 5.40E-04

Page 10 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 041

HAPs - Total PER 009 1.67E+00 3.81E-01 1.67E+00

Mercury Compounds PER 009 2.30E-04 5.25E-05 2.30E-04

Toluene PER 009 3.01E-03 6.87E-04 3.01E-03

Manganese compounds PER 009 3.36E-04 7.67E-05 3.36E-04

Nitrous Oxide PER 009 1.19E+00 2.72E-01 1.19E+00

Nickel compounds PER 009 1.86E-03 4.24E-04 1.86E-03

Nitrogen Oxides PER 009 4.06E+01 9.27E+00 4.06E+01

PM < 2.5 micron PER 009 6.72E+00 1.53E+00 6.72E+00

Lead PER 009 4.42E-04 1.01E-04 4.42E-04

PM < 10 micron PER 009 6.72E+00 1.53E+00 6.72E+00

Polycyclic organic matter PER 009 7.80E-05 1.78E-05 7.80E-05

Total Particulate Matter PER 009 6.72E+00 1.53E+00 6.72E+00

Selenium compounds PER 009 2.12E-05 4.85E-06 2.12E-05

Sulfur Dioxide PER 009 6.97E+01 1.59E+01 6.97E+01

Volatile Organic Compounds PER 009 4.87E+00 1.11E+00 4.87E+00

EU 042

A cetaldehyde PER 009 4.97E-04 1.13E-04 4.97E-04

A crolein PER 001 1.55E-04 3.55E-05 1.55E-04

Benzene PER 001 1.53E-02 3.49E-03 1.53E-02

A rsenic compounds PER 001 8.28E-05 1.89E-05 8.28E-05

Beryllium Compounds PER 001 4.93E-05 1.13E-05 4.93E-05

Carbon Dioxide Equivalent PER 009 3.68E+02 7.36E+02 3.22E+03

Cadmium compounds PER 001 2.17E-04 4.95E-05 2.17E-04

Methane PER 009 1.49E-02 2.98E-02 1.30E-01

Carbon Monoxide PER 001 1.45E+01 3.30E+00 1.45E+01

Carbon Dioxide PER 009 3.67E+02 7.34E+02 3.21E+03

Chromium compounds PER 001 1.32E-03 3.02E-04 1.32E-03

Formaldehyde PER 001 1.56E-03 3.55E-04 1.56E-03

Naphthalene PER 001 2.56E-03 5.85E-04 2.56E-03

HAPs - Total PER 001 3.48E-02 7.94E-03 3.48E-02

Mercury Compounds PER 001 5.91E-05 1.35E-05 5.91E-05

Toluene PER 001 5.54E-03 1.26E-03 5.54E-03

Xylenes (mixed isomers) PER 009 3.80E-03 8.69E-04 3.80E-03

Manganese compounds PER 001 2.76E-04 6.30E-05 2.76E-04

Nitrous Oxide PER 009 2.98E-03 5.95E-03 2.61E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.35E-03 7.65E-04 3.35E-03

Nitrogen Oxides PER 001 6.31E+01 1.44E+01 6.31E+01

PM < 2.5 micron PER 009 1.84E+00 4.20E-01 1.84E+00

PM < 10 micron PER 001 1.84E+00 4.20E-01 1.84E+00

Total Particulate Matter PER 001 1.84E+00 4.20E-01 1.84E+00

Sulfur Dioxide PER 009 1.05E+00 2.40E-01 1.05E+00

Volatile Organic Compounds PER 009 1.68E+00 3.84E-01 1.68E+00

EU 045

A cetaldehyde PER 009

Carbon disulfide PER 009

Page 11 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 045

Carbonyl sulfide PER 009

Carbon Dioxide Equivalent PER 009 7.25E+04 1.65E+04 7.25E+04

Cyanide compounds PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009 7.25E+04 1.65E+04 7.25E+04

Formaldehyde PER 009

HAPs - Total PER 007

Nitrogen Oxides PER 009

PM < 2.5 micron PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 050

Benzene PER 009 7.57E-04 1.73E-04 7.57E-04

A rsenic compounds PER 009 7.21E-05 1.65E-05 7.21E-05

Beryllium Compounds PER 009 4.33E-06 9.88E-07 4.33E-06

Carbon Dioxide Equivalent PER 010 4.55E+04 1.04E+04 4.55E+04

Cadmium compounds PER 009 3.97E-04 9.06E-05 3.97E-04

Methane PER 009 2.43E+00 5.56E-01 2.43E+00

Carbon Monoxide PER 009 3.70E+00 6.92E+00 3.03E+01

Carbon Dioxide PER 010 4.53E+04 1.03E+04 4.53E+04

Cobalt compounds PER 009 3.03E-05 6.92E-06 3.03E-05

Chromium compounds PER 009 5.05E-04 1.15E-04 5.05E-04

1,4-Dichlorobenzene PER 009 4.33E-04 9.88E-05 4.33E-04

Formaldehyde PER 009 2.71E-02 6.18E-03 2.71E-02

Hexane PER 009 6.49E-01 1.48E-01 6.49E-01

Naphthalene PER 009 2.20E-04 5.02E-05 2.20E-04

HAPs - Total PER 009 6.81E-01 1.55E-01 6.81E-01

Mercury Compounds PER 009 9.38E-05 2.14E-05 9.38E-05

Toluene PER 009 1.23E-03 2.80E-04 1.23E-03

Manganese compounds PER 009 1.37E-04 3.13E-05 1.37E-04

Nitrous Oxide PER 009 4.87E-01 1.11E-01 4.87E-01

Nickel compounds PER 009 7.57E-04 1.73E-04 7.57E-04

Nitrogen Oxides PER 009 2.94E+01 6.72E+00 2.94E+01

PM < 2.5 micron PER 009 2.74E+00 6.26E-01 2.74E+00

Lead PER 009 1.80E-04 4.12E-05 1.80E-04

PM < 10 micron PER 009 2.74E+00 6.26E-01 2.74E+00

Polycyclic organic matter PER 009 3.18E-05 7.26E-06 3.18E-05

Total Particulate Matter PER 009 2.74E+00 6.26E-01 2.74E+00

Selenium compounds PER 009 8.66E-06 1.98E-06 8.66E-06

Sulfur Dioxide PER 009 2.84E+01 6.48E+00 2.84E+01

Volatile Organic Compounds PER 009 1.98E+00 4.53E-01 1.98E+00

EU 051

Benzene PER 009 7.57E-04 1.73E-04 7.57E-04

Page 12 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 051

A rsenic compounds PER 009 7.21E-05 1.65E-05 7.21E-05

Beryllium Compounds PER 009 4.33E-06 9.88E-07 4.33E-06

Carbon Dioxide Equivalent PER 010 4.55E+04 1.04E+04 4.55E+04

Cadmium compounds PER 009 3.97E-04 9.06E-05 3.97E-04

Methane PER 010 2.43E+00 5.56E-01 2.43E+00

Carbon Monoxide PER 009 3.70E+00 6.92E+00 3.03E+01

Carbon Dioxide PER 010 4.53E+04 1.03E+04 4.53E+04

Cobalt compounds PER 009 3.03E-05 6.92E-06 3.03E-05

Chromium compounds PER 009 5.05E-04 1.15E-04 5.05E-04

1,4-Dichlorobenzene PER 009 4.33E-04 9.88E-05 4.33E-04

Formaldehyde PER 009 2.71E-02 6.18E-03 2.71E-02

Hexane PER 009 6.49E-01 1.48E-01 6.49E-01

Naphthalene PER 009 2.20E-04 5.02E-05 2.20E-04

HAPs - Total PER 009 6.81E-01 1.55E-01 6.81E-01

Mercury Compounds PER 009 9.38E-05 2.14E-05 9.38E-05

Toluene PER 009 1.23E-03 2.80E-04 1.23E-03

Manganese compounds PER 009 1.37E-04 3.13E-05 1.37E-04

Nitrous Oxide PER 010 4.87E-01 1.11E-01 4.87E-01

Nickel compounds PER 009 7.57E-04 1.73E-04 7.57E-04

Nitrogen Oxides PER 009 2.94E+01 6.72E+00 2.94E+01

PM < 2.5 micron PER 009 2.74E+00 6.26E-01 2.74E+00

Lead PER 009 1.80E-04 4.12E-05 1.80E-04

PM < 10 micron PER 009 2.74E+00 6.26E-01 2.74E+00

Polycyclic organic matter PER 009 3.18E-05 7.26E-06 3.18E-05

Total Particulate Matter PER 009 2.74E+00 6.26E-01 2.74E+00

Selenium compounds PER 009 8.66E-06 1.98E-06 8.66E-06

Sulfur Dioxide PER 009 2.84E+01 6.48E+00 2.84E+01

Volatile Organic Compounds PER 009 1.98E+00 4.53E-01 1.98E+00

EU 052

Benzene PER 009 7.21E-03 1.65E-03 7.21E-03

A rsenic compounds PER 009 6.87E-04 1.57E-04 6.87E-04

Beryllium Compounds PER 009 4.12E-05 9.41E-06 4.12E-05

Carbon Dioxide Equivalent PER 010 4.33E+05 9.88E+04 4.33E+05

Cadmium compounds PER 009 3.78E-03 8.63E-04 3.78E-03

Methane PER 010 2.32E+01 5.29E+00 2.32E+01

Carbon Monoxide PER 009 6.31E+01 6.59E+01 2.89E+02

Carbon Dioxide PER 010 4.31E+05 9.84E+04 4.31E+05

Cobalt compounds PER 009 2.89E-04 6.59E-05 2.89E-04

Chromium compounds PER 009 4.81E-03 1.10E-03 4.81E-03

1,4-Dichlorobenzene PER 009 4.12E-03 9.41E-04 4.12E-03

Formaldehyde PER 009 2.58E-01 5.88E-02 2.58E-01

Hexane PER 009 6.18E+00 1.41E+00 6.18E+00

Naphthalene PER 009 2.10E-03 4.78E-04 2.10E-03

HAPs - Total PER 009 6.48E+00 1.48E+00 6.48E+00

Mercury Compounds PER 009 8.93E-04 2.04E-04 8.93E-04

Toluene PER 009 1.17E-02 2.67E-03 1.17E-02

Page 13 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 052

Manganese compounds PER 009 1.31E-03 2.98E-04 1.31E-03

Nitrous Oxide PER 010 4.63E+00 1.06E+00 4.63E+00

Nickel compounds PER 009 7.21E-03 1.65E-03 7.21E-03

Nitrogen Oxides PER 009 3.50E+02 8.00E+01 3.50E+02

PM < 2.5 micron PER 009 2.61E+01 5.96E+00 2.61E+01

Lead PER 009 1.72E-03 3.90E-04 1.72E-03

PM < 10 micron PER 009 9.15E+00 5.96E+00 2.61E+01

Polycyclic organic matter PER 009 3.03E-04 6.92E-05 3.03E-04

Total Particulate Matter PER 009 9.15E+00 5.96E+00 2.61E+01

Selenium compounds PER 009 8.24E-05 1.88E-05 8.24E-05

Sulfur Dioxide PER 009 2.71E+02 6.18E+01 2.71E+02

Volatile Organic Compounds PER 006 1.89E+01 4.31E+00 1.89E+01

EU 053

Benzene PER 009 3.07E-04 7.00E-05 3.07E-04

A rsenic compounds PER 009 2.92E-05 6.67E-06 2.92E-05

Beryllium Compounds PER 009 1.75E-06 4.00E-07 1.75E-06

Carbon Dioxide Equivalent PER 010 1.84E+04 4.20E+03 1.84E+04

Cadmium compounds PER 009 1.61E-04 3.67E-05 1.61E-04

Methane PER 009 9.85E-01 2.25E-01 9.85E-01

Carbon Monoxide PER 001 1.23E+01 2.80E+00 1.23E+01

Carbon Dioxide PER 010 1.83E+04 4.18E+03 1.83E+04

Cobalt compounds PER 009 1.23E-05 2.80E-06 1.23E-05

Chromium compounds PER 009 2.04E-04 4.67E-05 2.04E-04

1,4-Dichlorobenzene PER 009 1.75E-04 4.00E-05 1.75E-04

Formaldehyde PER 009 1.10E-02 2.50E-03 1.10E-02

Hexane PER 009 2.63E-01 6.00E-02 2.63E-01

Naphthalene PER 009 8.91E-05 2.03E-05 8.91E-05

HAPs - Total PER 009 2.76E-01 6.29E-02 2.76E-01

Mercury Compounds PER 009 3.80E-05 8.67E-06 3.80E-05

Toluene PER 009 4.96E-04 1.13E-04 4.96E-04

Manganese compounds PER 009 5.55E-05 1.27E-05 5.55E-05

Nitrous Oxide PER 009 1.97E-01 4.50E-02 1.97E-01

Nickel compounds PER 009 3.07E-04 7.00E-05 3.07E-04

Nitrogen Oxides PER 009 2.08E+01 4.76E+00 2.08E+01

PM < 2.5 micron PER 009 1.11E+00 2.53E-01 1.11E+00

Lead PER 009 7.30E-05 1.67E-05 7.30E-05

PM < 10 micron PER 009 1.11E+00 2.53E-01 1.11E+00

Polycyclic organic matter PER 009 1.29E-05 2.94E-06 1.29E-05

Total Particulate Matter PER 009 1.11E+00 2.53E-01 1.11E+00

Selenium compounds PER 009 3.50E-06 8.00E-07 3.50E-06

Sulfur Dioxide PER 009 1.15E+01 2.62E+00 1.15E+01

Volatile Organic Compounds PER 009 8.03E-01 1.83E-01 8.03E-01

EU 054

Benzene PER 009 2.07E-04 4.74E-05 2.07E-04

A rsenic compounds PER 009 1.98E-05 4.51E-06 1.98E-05

Beryllium Compounds PER 009 1.19E-06 2.71E-07 1.19E-06

Page 14 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 054

Carbon Dioxide Equivalent PER 010 1.37E+04 3.12E+03 1.37E+04

Cadmium compounds PER 009 1.09E-04 2.48E-05 1.09E-04

Methane PER 009 6.66E-01 1.52E-01 6.66E-01

Carbon Monoxide PER 001 8.30E+00 1.89E+00 8.30E+00

Carbon Dioxide PER 010 1.36E+04 3.11E+03 1.36E+04

Cobalt compounds PER 009 8.30E-06 1.89E-06 8.30E-06

Chromium compounds PER 009 1.38E-04 3.16E-05 1.38E-04

1,4-Dichlorobenzene PER 009 1.19E-04 2.71E-05 1.19E-04

Formaldehyde PER 009 7.41E-03 1.69E-03 7.41E-03

Hexane PER 009 1.78E-01 4.06E-02 1.78E-01

Naphthalene PER 009 6.02E-05 1.38E-05 6.02E-05

HAPs - Total PER 009 1.86E-01 4.26E-02 1.86E-01

Mercury Compounds PER 009 2.57E-05 5.86E-06 2.57E-05

Toluene PER 009 3.36E-04 7.67E-05 3.36E-04

Manganese compounds PER 009 3.75E-05 8.57E-06 3.75E-05

Nitrous Oxide PER 009 1.33E-01 3.04E-02 1.33E-01

Nickel compounds PER 009 2.07E-04 4.74E-05 2.07E-04

Nitrogen Oxides PER 001 2.77E+01 6.33E+00 2.77E+01

PM < 2.5 micron PER 009 7.51E-01 1.71E-01 7.51E-01

Lead PER 009 4.94E-05 1.13E-05 4.94E-05

PM < 10 micron PER 009 7.51E-01 1.71E-01 7.51E-01

Polycyclic organic matter PER 009 8.71E-06 1.99E-06 8.71E-06

Total Particulate Matter PER 009 7.51E-01 1.71E-01 7.51E-01

Selenium compounds PER 009 2.37E-06 5.41E-07 2.37E-06

Sulfur Dioxide PER 009 2.30E+00 9.73E-01 2.30E+00

Volatile Organic Compounds PER 009 5.43E-01 1.24E-01 5.43E-01

EU 055

Benzene PER 009 1.98E-05 4.74E-05 1.98E-05

A rsenic compounds PER 009 1.98E-05 4.51E-06 1.98E-05

Beryllium Compounds PER 009 1.19E-06 2.71E-07 1.19E-06

Carbon Dioxide Equivalent PER 010 2.15E+04 4.91E+03 2.15E+04

Cadmium compounds PER 009 1.09E-04 2.48E-05 1.09E-04

Methane PER 009 1.05E+00 2.39E-01 1.05E+00

Carbon Monoxide PER 001 8.30E+00 1.89E+00 8.30E+00

Carbon Dioxide PER 010 2.14E+04 4.89E+03 2.14E+04

Cobalt compounds PER 009 8.30E-06 1.89E-06 8.30E-06

Chromium compounds PER 009 1.38E-04 3.16E-05 1.38E-04

1,4-Dichlorobenzene PER 009 1.19E-04 2.71E-05 1.19E-04

Formaldehyde PER 009 7.41E-03 1.69E-03 7.41E-03

Hexane PER 009 1.78E-01 4.06E-02 1.78E-01

Naphthalene PER 009 6.02E-05 1.38E-05 6.02E-05

HAPs - Total PER 009 1.86E-01 4.26E-02 1.86E-01

Mercury Compounds PER 009 2.57E-05 5.86E-06 2.57E-05

Toluene PER 009 3.36E-04 7.67E-05 3.36E-04

Manganese compounds PER 009 3.75E-05 8.57E-06 3.75E-05

Nitrous Oxide PER 009 2.10E-01 4.79E-02 2.10E-01

Page 15 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 055

Nickel compounds PER 009 2.07E-04 4.74E-05 2.07E-04

Nitrogen Oxides PER 001 2.77E+01 6.33E+00 2.77E+01

PM < 2.5 micron PER 009 7.51E-01 1.71E-01 7.51E-01

Lead PER 009 4.94E-05 1.13E-05 4.94E-05

PM < 10 micron PER 009 7.51E-01 1.71E-01 7.51E-01

Polycyclic organic matter PER 009 8.71E-06 1.99E-06 8.71E-06

Total Particulate Matter PER 009 7.51E-01 1.71E-01 7.51E-01

Selenium compounds PER 009 2.37E-06 5.41E-07 2.37E-06

Sulfur Dioxide PER 009 5.43E-01 1.24E-01 5.43E-01

Volatile Organic Compounds PER 001 5.40E-01 1.20E-01 5.40E-01

EU 056

Benzene PER 009 6.40E-04 1.46E-04 6.40E-04

A rsenic compounds PER 009 6.10E-05 1.39E-05 6.10E-05

Beryllium Compounds PER 009 3.66E-06 8.35E-07 3.66E-06

Carbon Dioxide Equivalent PER 010 4.22E+04 9.62E+03 4.22E+04

Cadmium compounds PER 009 3.35E-04 7.66E-05 3.35E-04

Methane PER 009 2.06E+00 4.70E-01 2.06E+00

Carbon Monoxide PER 001 2.56E+01 5.85E+00 2.56E+01

Carbon Dioxide PER 010 4.20E+04 9.59E+03 4.20E+04

Cobalt compounds PER 009 2.56E-05 5.85E-06 2.56E-05

Chromium compounds PER 009 4.27E-04 9.75E-05 4.27E-04

1,4-Dichlorobenzene PER 009 3.66E-04 8.35E-05 3.66E-04

Formaldehyde PER 009 2.29E-02 5.22E-03 2.29E-02

Hexane PER 009 5.49E-01 1.25E-01 5.49E-01

Naphthalene PER 009 1.86E-04 4.25E-05 1.86E-04

HAPs - Total PER 009 5.75E-01 1.31E-01 5.75E-01

Mercury Compounds PER 009 7.93E-05 1.81E-05 7.93E-05

Toluene PER 009 1.04E-03 2.37E-04 1.04E-03

Manganese compounds PER 009 1.16E-04 2.65E-05 1.16E-04

Nitrous Oxide PER 009 4.11E-01 9.39E-02 4.11E-01

Nickel compounds PER 009 6.40E-04 1.46E-04 6.40E-04

Nitrogen Oxides PER 009 1.40E+01 3.20E+00 1.40E+01

PM < 2.5 micron PER 009 2.32E+00 5.29E-01 2.32E+00

Lead PER 009 1.52E-04 3.48E-05 1.52E-04

PM < 10 micron PER 009 2.32E+00 5.29E-01 2.32E+00

Polycyclic organic matter PER 009 2.69E-05 6.14E-06 2.69E-05

Total Particulate Matter PER 009 2.32E+00 5.29E-01 2.32E+00

Selenium compounds PER 009 7.32E-06 1.67E-06 7.32E-06

Sulfur Dioxide PER 001 7.10E+00 3.00E+00 7.10E+00

Volatile Organic Compounds PER 009 1.68E+00 3.83E-01 1.68E+00

EU 057

Benzene PER 009 9.02E-05 2.06E-05 9.02E-05

A rsenic compounds PER 009 8.59E-06 1.96E-06 8.59E-06

Beryllium Compounds PER 009 5.15E-07 1.18E-07 5.15E-07

Carbon Dioxide Equivalent PER 010 5.94E+03 1.36E+03 5.94E+03

Cadmium compounds PER 009 4.72E-05 1.08E-05 4.72E-05

Page 16 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 057

Methane PER 009 2.90E-01 6.61E-02 2.90E-01

Carbon Monoxide PER 009 3.61E+00 8.24E-01 3.61E+00

Carbon Dioxide PER 010 5.91E+03 1.35E+03 5.91E+03

Cobalt compounds PER 009 3.61E-06 8.24E-07 3.61E-06

Chromium compounds PER 009 6.01E-05 1.37E-05 6.01E-05

1,4-Dichlorobenzene PER 009 5.15E-05 1.18E-05 5.15E-05

Formaldehyde PER 009 3.22E-03 7.35E-04 3.22E-03

Hexane PER 009 7.73E-02 1.76E-02 7.73E-02

Naphthalene PER 009 2.62E-05 5.98E-06 2.62E-05

HAPs - Total PER 009 8.10E-02 1.85E-02 8.10E-02

Mercury Compounds PER 009 1.12E-05 2.55E-06 1.12E-05

Toluene PER 009 1.46E-04 3.33E-05 1.46E-04

Manganese compounds PER 009 1.63E-05 3.73E-06 1.63E-05

Nitrous Oxide PER 009 5.79E-02 1.32E-02 5.79E-02

Nickel compounds PER 009 9.02E-05 2.06E-05 9.02E-05

Nitrogen Oxides PER 009 1.20E+01 2.75E+00 1.20E+01

PM < 2.5 micron PER 009 3.26E-01 7.45E-02 3.26E-01

Lead PER 009 2.15E-05 4.90E-06 2.15E-05

PM < 10 micron PER 009 3.26E-01 7.45E-02 3.26E-01

Polycyclic organic matter PER 009 3.79E-06 8.65E-07 3.79E-06

Total Particulate Matter PER 009 3.26E-01 7.45E-02 3.26E-01

Selenium compounds PER 009 1.03E-06 2.35E-07 1.03E-06

Sulfur Dioxide PER 009 1.00E+00 4.23E-01 1.00E+00

Volatile Organic Compounds PER 009 2.36E-01 5.39E-02 2.36E-01

EU 058

Benzene PER 009 5.14E-04 1.17E-04 5.14E-04

A rsenic compounds PER 009 4.90E-05 1.12E-05 4.90E-05

Beryllium Compounds PER 009 2.94E-06 6.71E-07 2.94E-06

Carbon Dioxide Equivalent PER 010 3.38E+04 7.73E+03 3.38E+04

Cadmium compounds PER 009 2.69E-04 6.15E-05 2.69E-04

Methane PER 009 1.65E+00 3.77E-01 1.65E+00

Carbon Monoxide PER 009 2.06E+01 4.69E+00 2.06E+01

Carbon Dioxide PER 010 3.37E+04 7.70E+03 3.37E+04

Cobalt compounds PER 009 2.06E-05 4.69E-06 2.06E-05

Chromium compounds PER 009 3.43E-04 7.82E-05 3.43E-04

1,4-Dichlorobenzene PER 009 2.94E-04 6.71E-05 2.94E-04

Formaldehyde PER 009 1.84E-02 4.19E-03 1.84E-02

Hexane PER 009 4.41E-01 1.01E-01 4.41E-01

Naphthalene PER 009 1.49E-04 3.41E-05 1.49E-04

HAPs - Total PER 009 4.62E-01 1.05E-01 4.62E-01

Mercury Compounds PER 009 6.36E-05 1.45E-05 6.36E-05

Toluene PER 009 8.32E-04 1.90E-04 8.32E-04

Manganese compounds PER 009 9.30E-05 2.12E-05 9.30E-05

Nitrous Oxide PER 009 3.30E-01 7.54E-02 3.30E-01

Nickel compounds PER 009 5.14E-04 1.17E-04 5.14E-04

Nitrogen Oxides PER 009 6.87E+01 1.57E+01 6.87E+01

Page 17 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 058

PM < 2.5 micron PER 009 1.86E+00 4.25E-01 1.86E+00

Lead PER 009 1.22E-04 2.79E-05 1.22E-04

PM < 10 micron PER 009 1.86E+00 4.25E-01 1.86E+00

Polycyclic organic matter PER 009 2.16E-05 4.93E-06 2.16E-05

Total Particulate Matter PER 009 1.86E+00 4.25E-01 1.86E+00

Selenium compounds PER 009 5.87E-06 1.34E-06 5.87E-06

Sulfur Dioxide PER 009 5.70E+00 2.41E+00 5.70E+00

Volatile Organic Compounds PER 009 1.35E+00 3.07E-01 1.35E+00

EU 059

Benzene PER 009 3.52E-04 8.03E-05 3.52E-04

A rsenic compounds PER 009 3.35E-05 7.65E-06 3.35E-05

Beryllium Compounds PER 009 2.01E-06 4.59E-07 2.01E-06

Carbon Dioxide Equivalent PER 010 2.32E+04 5.29E+03 2.32E+04

Cadmium compounds PER 009 1.84E-04 4.21E-05 1.84E-04

Methane PER 009 1.13E+00 2.58E-01 1.13E+00

Carbon Monoxide PER 009 1.41E+01 3.21E+00 1.41E+01

Carbon Dioxide PER 010 2.31E+04 5.27E+03 2.31E+04

Cobalt compounds PER 009 1.41E-05 3.21E-06 1.41E-05

Chromium compounds PER 009 2.34E-04 5.35E-05 2.34E-04

1,4-Dichlorobenzene PER 009 2.01E-04 4.59E-05 2.01E-04

Formaldehyde PER 009 1.26E-02 2.87E-03 1.26E-02

Hexane PER 009 3.01E-01 6.88E-02 3.01E-01

Naphthalene PER 009 1.02E-04 2.33E-05 1.02E-04

HAPs - Total PER 009 3.16E-01 7.22E-02 3.16E-01

Mercury Compounds PER 009 4.35E-05 9.94E-06 4.35E-05

Toluene PER 009 5.69E-04 1.30E-04 5.69E-04

Manganese compounds PER 009 6.36E-05 1.45E-05 6.36E-05

Nitrous Oxide PER 009 2.26E-01 5.16E-02 2.26E-01

Nickel compounds PER 009 3.52E-04 8.03E-05 3.52E-04

Nitrogen Oxides PER 009 4.70E+01 1.07E+01 4.70E+01

PM < 2.5 micron PER 009 1.27E+00 2.91E-01 1.27E+00

Lead PER 009 8.37E-05 1.91E-05 8.37E-05

PM < 10 micron PER 009 1.27E+00 2.91E-01 1.27E+00

Polycyclic organic matter PER 009 1.48E-05 3.37E-06 1.48E-05

Total Particulate Matter PER 009 1.27E+00 2.91E-01 1.27E+00

Selenium compounds PER 009 4.02E-06 9.18E-07 4.02E-06

Sulfur Dioxide PER 009 3.90E+00 1.65E+00 3.90E+00

Volatile Organic Compounds PER 009 9.21E-01 2.10E-01 9.21E-01

EU 060

Benzene PER 009 3.52E-04 8.03E-05 3.52E-04

A rsenic compounds PER 009 3.35E-05 7.65E-06 3.35E-05

Beryllium Compounds PER 009 2.01E-06 4.59E-07 2.01E-06

Carbon Dioxide Equivalent PER 010 2.32E+04 5.29E+03 2.32E+04

Cadmium compounds PER 009 1.84E-04 4.21E-05 1.84E-04

Methane PER 009 1.13E+00 2.58E-01 1.13E+00

Carbon Monoxide PER 009 1.41E+01 3.21E+00 1.41E+01

Page 18 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 060

Carbon Dioxide PER 010 2.31E+04 5.27E+03 2.31E+04

Cobalt compounds PER 009 1.41E-05 3.21E-06 1.41E-05

Chromium compounds PER 009 2.34E-04 5.35E-05 2.34E-04

1,4-Dichlorobenzene PER 009 2.01E-04 4.59E-05 2.01E-04

Formaldehyde PER 009 1.26E-02 2.87E-03 1.26E-02

Hexane PER 009 3.01E-01 6.88E-02 3.01E-01

Naphthalene PER 009 1.02E-04 2.33E-05 1.02E-04

HAPs - Total PER 009 3.16E-01 7.22E-02 3.16E-01

Mercury Compounds PER 009 4.35E-05 9.94E-06 4.35E-05

Toluene PER 009 5.69E-04 1.30E-04 5.69E-04

Manganese compounds PER 009 6.36E-05 1.45E-05 6.36E-05

Nitrous Oxide PER 009 2.26E-01 5.16E-02 2.26E-01

Nickel compounds PER 009 3.52E-04 8.03E-05 3.52E-04

Nitrogen Oxides PER 009 4.70E+01 1.07E+01 4.70E+01

PM < 2.5 micron PER 009 1.27E+00 2.91E-01 1.27E+00

Lead PER 009 8.37E-05 1.91E-05 8.37E-05

PM < 10 micron PER 009 1.27E+00 2.91E-01 1.27E+00

Polycyclic organic matter PER 009 1.48E-05 3.37E-06 1.48E-05

Total Particulate Matter PER 009 1.27E+00 2.91E-01 1.27E+00

Selenium compounds PER 009 4.02E-06 9.18E-07 4.02E-06

Sulfur Dioxide PER 009 3.90E+00 1.65E+00 3.90E+00

Volatile Organic Compounds PER 009 9.21E-01 2.10E-01 9.21E-01

EU 061

Benzene PER 009 2.71E-04 6.18E-05 2.71E-04

A rsenic compounds PER 009 2.58E-05 5.88E-06 2.58E-05

Beryllium Compounds PER 009 1.55E-06 3.53E-07 1.55E-06

Carbon Dioxide Equivalent PER 010 1.78E+04 4.07E+03 1.78E+04

Cadmium compounds PER 009 1.42E-04 3.24E-05 1.42E-04

Methane PER 009 8.69E-01 1.98E-01 8.69E-01

Carbon Monoxide PER 009 1.08E+01 2.47E+00 1.08E+01

Carbon Dioxide PER 010 1.77E+04 4.05E+03 1.77E+04

Cobalt compounds PER 009 1.08E-05 2.47E-06 1.08E-05

Chromium compounds PER 009 1.80E-04 4.12E-05 1.80E-04

1,4-Dichlorobenzene PER 009 1.55E-04 3.53E-03 1.55E-04

Formaldehyde PER 009 9.66E-03 2.21E-03 9.66E-03

Hexane PER 009 2.32E-01 5.29E-02 2.32E-01

Naphthalene PER 009 7.86E-05 1.79E-05 7.86E-05

HAPs - Total PER 009 2.43E-01 5.55E-02 2.43E-01

Mercury Compounds PER 009 3.35E-05 7.65E-06 3.35E-05

Toluene PER 009 4.38E-04 1.00E-04 4.38E-04

Manganese compounds PER 009 4.90E-05 1.12E-05 4.90E-05

Nitrous Oxide PER 009 1.74E-01 3.97E-02 1.74E-01

Nickel compounds PER 009 2.71E-04 6.18E-05 2.71E-04

Nitrogen Oxides PER 009 3.61E+01 8.25E+00 3.61E+01

PM < 2.5 micron PER 009 9.79E-01 2.24E-01 9.79E-01

Lead PER 009 6.44E-05 1.47E-05 6.44E-05

Page 19 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 061

PM < 10 micron PER 009 9.79E-01 2.24E-01 9.79E-01

Polycyclic organic matter PER 009 1.14E-05 2.59E-06 1.14E-05

Total Particulate Matter PER 009 9.79E-01 2.24E-01 9.79E-01

Selenium compounds PER 009 3.09E-06 7.06E-07 3.09E-06

Sulfur Dioxide PER 009 3.00E+00 1.27E+00 3.00E+00

Volatile Organic Compounds PER 009 7.09E-01 1.62E-01 7.09E-01

EU 073

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 009

Cadmium compounds PER 009

Methane PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Cobalt compounds PER 009

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

PM < 2.5 micron PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Selenium compounds PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 074

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 009

Cadmium compounds PER 009

Methane PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Cobalt compounds PER 009

Page 20 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 074

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Selenium compounds PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 075

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 010 8.02E+04 1.83E+04 8.02E+04

Cadmium compounds PER 009

Methane PER 010 3.91E+00 8.93E-01 3.91E+00

Carbon Monoxide PER 009

Carbon Dioxide PER 010 7.98E+04 1.82E+04 7.98E+04

Cobalt compounds PER 009

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 010 7.82E-01 1.79E-01 7.82E-01

Nickel compounds PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Selenium compounds PER 009

Page 21 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 075

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 076

Benzene PER 009 8.12E-05 1.85E-05 8.12E-05

A rsenic compounds PER 009 7.73E-06 1.76E-06 7.73E-06

Beryllium Compounds PER 009 4.64E-07 1.06E-07 4.64E-07

Carbon Dioxide Equivalent PER 010 5.34E+03 1.22E+03 5.34E+03

Cadmium compounds PER 009 4.25E-05 9.71E-06 4.25E-05

Methane PER 009 2.61E-01 5.95E-02 2.61E-01

Carbon Monoxide PER 009 3.25E+00 7.41E-01 3.25E+00

Carbon Dioxide PER 010 5.32E+03 1.22E+03 5.32E+03

Cobalt compounds PER 009 3.25E-06 7.41E-07 3.25E-06

Chromium compounds PER 009 5.41E-05 1.24E-05 5.41E-05

1,4-Dichlorobenzene PER 009 4.64E-05 1.06E-05 4.64E-05

Formaldehyde PER 009 2.90E-03 6.62E-04 2.90E-03

Hexane PER 009 6.96E-02 1.59E-02 6.96E-02

Naphthalene PER 009 2.36E-05 5.38E-06 2.36E-05

HAPs - Total PER 009 7.29E-02 1.67E-02 7.29E-02

Mercury Compounds PER 009 1.00E-05 2.29E-06 1.00E-05

Toluene PER 009 1.31E-04 3.00E-05 1.31E-04

Manganese compounds PER 009 1.47E-05 3.35E-06 1.47E-05

Nitrous Oxide PER 009 5.21E-02 1.19E-02 5.21E-02

Nickel compounds PER 009 8.12E-05 1.85E-05 8.12E-05

Nitrogen Oxides PER 001 1.08E+01 2.48E+00 1.08E+01

PM < 2.5 micron PER 009 2.94E-01 6.71E-02 2.94E-01

Lead PER 009 1.93E-05 4.41E-06 1.93E-05

PM < 10 micron PER 009 2.94E-01 6.71E-02 2.94E-01

Polycyclic organic matter PER 009 3.41E-06 7.78E-07 3.41E-06

Total Particulate Matter PER 009 2.94E-01 6.71E-02 2.94E-01

Selenium compounds PER 009 9.28E-07 2.12E-07 9.28E-07

Sulfur Dioxide PER 009 9.00E-01 3.81E-01 9.00E-01

Volatile Organic Compounds PER 009 2.13E-01 4.85E-02 2.13E-01

EU 077

Carbon Dioxide Equivalent PER 009

Methane PER 009

Carbon Dioxide PER 009

Nitrous Oxide PER 009

EU 084

Benzene PER 009 1.06E-03 2.43E-04 1.06E-03

A rsenic compounds PER 009 1.01E-04 2.31E-05 1.01E-04

Beryllium Compounds PER 009 6.08E-06 1.39E-06 6.08E-06

Carbon Dioxide Equivalent PER 010 7.01E+04 1.60E+04 7.01E+04

Cadmium compounds PER 009 5.57E-04 1.27E-04 5.57E-04

Methane PER 009 3.42E+00 7.81E-01 3.42E+00

Carbon Monoxide PER 009 2.07E+01 4.72E+00 2.07E+01

Carbon Dioxide PER 010 6.98E+04 1.59E+04 6.98E+04

Page 22 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 084

Cobalt compounds PER 009 4.26E-05 9.72E-06 4.26E-05

Chromium compounds PER 009 7.09E-04 1.62E-04 7.09E-04

1,4-Dichlorobenzene PER 009 6.08E-04 1.39E-04 6.08E-04

Formaldehyde PER 009 3.80E-02 8.68E-03 3.80E-02

Hexane PER 009 9.12E-01 2.08E-01 9.12E-01

Naphthalene PER 009 3.09E-04 7.06E-05 3.09E-04

HAPs - Total PER 009 9.56E-01 2.18E-01 9.56E-01

Mercury Compounds PER 009 1.32E-04 3.01E-05 1.32E-04

Toluene PER 009 1.72E-03 3.93E-04 1.72E-03

Manganese compounds PER 009 1.93E-04 4.40E-05 1.93E-04

Nitrous Oxide PER 009 6.84E-01 1.56E-01 6.84E-01

Nickel compounds PER 009 1.06E-03 2.43E-04 1.06E-03

Nitrogen Oxides PER 009 2.28E+01 5.31E+00 2.33E+01

PM < 2.5 micron PER 009 3.85E+00 8.79E-01 3.85E+00

Lead PER 009 2.53E-04 5.78E-05 2.53E-04

PM < 10 micron PER 009 3.85E+00 8.79E-01 3.85E+00

Polycyclic organic matter PER 009 4.47E-05 1.02E-05 4.47E-05

Total Particulate Matter PER 009 3.85E+00 8.79E-01 3.85E+00

Selenium compounds PER 009 1.22E-05 2.78E-06 1.22E-05

Sulfur Dioxide PER 009 1.65E+02 9.11E+00 3.99E+01

Volatile Organic Compounds PER 009 2.79E+00 6.36E-01 2.79E+00

EU 085

Benzene PER 009 1.16E-03 2.65E-04 1.16E-03

A rsenic compounds PER 009 1.11E-04 2.53E-05 1.11E-04

Beryllium Compounds PER 009 6.64E-06 1.52E-06 6.64E-06

Carbon Dioxide Equivalent PER 010 6.97E+04 1.59E+04 6.97E+04

Cadmium compounds PER 009 6.08E-04 1.39E-04 6.08E-04

Methane PER 010 3.73E+00 8.52E-01 3.73E+00

Carbon Monoxide PER 001 2.26E+01 5.15E+00 2.26E+01

Carbon Dioxide PER 010 6.94E+04 1.58E+04 6.94E+04

Cobalt compounds PER 009 4.65E-05 1.06E-05 4.65E-05

Chromium compounds PER 009 7.74E-04 1.77E-04 7.74E-04

1,4-Dichlorobenzene PER 009 6.64E-04 1.52E-04 6.64E-04

Formaldehyde PER 009 4.15E-02 9.47E-03 4.15E-02

Hexane PER 009 9.96E-01 2.27E-01 9.96E-01

Naphthalene PER 009 3.37E-04 7.70E-05 3.37E-04

HAPs - Total PER 009 1.04E+00 2.38E-01 1.04E+00

Mercury Compounds PER 009 1.44E-04 3.28E-05 1.44E-04

Toluene PER 009 1.88E-03 4.29E-04 1.88E-03

Manganese compounds PER 009 2.10E-04 4.80E-05 2.10E-04

Nitrous Oxide PER 010 7.46E-01 1.70E-01 7.46E-01

Nickel compounds PER 009 1.16E-03 2.65E-04 1.16E-03

Nitrogen Oxides PER 001 2.54E+01 5.80E+00 2.54E+01

PM < 2.5 micron PER 009 4.20E+00 9.60E-01 4.20E+00

Lead PER 009 2.77E-04 6.31E-05 2.77E-04

PM < 10 micron PER 009 4.20E+00 9.60E-01 4.20E+00

Page 23 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 085

Polycyclic organic matter PER 009 4.88E-05 1.11E-05 4.88E-05

Total Particulate Matter PER 009 4.20E+00 9.60E-01 4.20E+00

Selenium compounds PER 009 1.33E-05 3.03E-06 1.33E-05

Sulfur Dioxide PER 009 1.68E+02 9.94E+00 4.36E+01

Volatile Organic Compounds PER 009 3.04E+00 6.95E-01 3.04E+00

EU 093

Benzene PER 009 2.16E-04 4.94E-05 2.16E-04

A rsenic compounds PER 009 2.06E-05 4.71E-06 2.06E-05

Beryllium Compounds PER 009 1.24E-06 2.82E-07 1.24E-06

Carbon Dioxide Equivalent PER 010 1.30E+04 2.97E+03 1.30E+04

Cadmium compounds PER 009 1.13E-04 2.59E-05 1.13E-04

Methane PER 009 6.95E-01 1.59E-01 6.95E-01

Carbon Monoxide PER 001 8.66E+00 1.98E+00 8.66E+00

Carbon Dioxide PER 010 1.29E+04 2.95E+03 1.29E+04

Cobalt compounds PER 009 8.66E-06 1.98E-06 8.66E-06

Chromium compounds PER 009 1.40E-04 3.29E-05 1.44E-04

1,4-Dichlorobenzene PER 009 1.24E-04 2.82E-05 1.24E-04

Formaldehyde PER 009 7.73E-03 1.76E-03 7.73E-03

Hexane PER 009 1.86E-01 4.24E-02 1.86E-01

Naphthalene PER 009 6.29E-05 1.44E-05 6.29E-05

HAPs - Total PER 009 1.95E-01 4.44E-02 1.95E-01

Mercury Compounds PER 009 2.68E-05 6.12E-06 2.68E-05

Toluene PER 009 3.50E-04 8.00E-05 3.50E-04

Manganese compounds PER 009 3.92E-05 8.94E-06 3.92E-05

Nitrous Oxide PER 009 1.39E-01 3.17E-02 1.39E-01

Nickel compounds PER 009 2.16E-04 4.94E-05 2.16E-04

Nitrogen Oxides PER 009 1.26E+01 2.88E+00 1.26E+01

PM < 2.5 micron PER 009 7.83E-01 1.79E-01 7.83E-01

Lead PER 009 5.15E-05 1.18E-05 5.15E-05

PM < 10 micron PER 009 7.83E-01 1.79E-01 7.83E-01

Polycyclic organic matter PER 009 9.09E-06 2.08E-06 9.09E-06

Total Particulate Matter PER 009 7.83E-01 1.79E-01 7.83E-01

Selenium compounds PER 009 2.47E-06 5.65E-07 2.47E-06

Sulfur Dioxide PER 009 8.12E+00 1.85E+00 8.12E+00

Volatile Organic Compounds PER 009 5.67E-01 1.29E-01 5.67E-01

EU 094

Benzene PER 009 2.98E-04 6.79E-05 2.98E-04

A rsenic compounds PER 009 2.83E-05 6.47E-06 2.83E-05

Beryllium Compounds PER 009 1.70E-06 3.88E-07 1.70E-06

Carbon Dioxide Equivalent PER 010 2.00E+04 4.57E+03 2.00E+04

Cadmium compounds PER 009 1.56E-04 3.56E-05 1.56E-04

Methane PER 010 1.07E+00 2.45E-01 1.07E+00

Carbon Monoxide PER 001 1.19E+01 2.72E+00 1.19E+01

Carbon Dioxide PER 010 1.99E+04 4.55E+03 1.99E+04

Cobalt compounds PER 009 1.19E-05 2.72E-06 1.19E-05

Chromium compounds PER 009 1.98E-04 4.53E-05 1.98E-04

Page 24 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 094

1,4-Dichlorobenzene PER 009 1.70E-04 3.88E-05 1.70E-04

Formaldehyde PER 009 1.06E-02 2.43E-03 1.06E-02

Hexane PER 009 2.55E-01 5.82E-02 2.55E-01

Naphthalene PER 009 8.64E-05 1.97E-05 8.64E-05

HAPs - Total PER 009 2.67E-01 6.11E-02 2.67E-01

Mercury Compounds PER 009 3.68E-05 8.41E-06 3.68E-05

Toluene PER 009 4.82E-04 1.10E-04 4.82E-04

Manganese compounds PER 009 5.38E-05 1.23E-05 5.38E-05

Nitrous Oxide PER 010 2.14E-01 4.89E-02 2.14E-01

Nickel compounds PER 009 2.98E-04 6.79E-05 2.98E-04

Nitrogen Oxides PER 009 6.50E+00 1.49E+00 6.50E+00

PM < 2.5 micron PER 009 1.08E+00 2.46E-01 1.08E+00

Lead PER 009 7.09E-05 1.62E-05 7.09E-05

PM < 10 micron PER 009 1.08E+00 2.46E-01 1.08E+00

Polycyclic organic matter PER 009 1.25E-05 2.85E-06 1.25E-05

Total Particulate Matter PER 009 1.08E+00 2.46E-01 1.08E+00

Selenium compounds PER 009 3.40E-06 7.76E-07 3.40E-06

Sulfur Dioxide PER 009 1.12E+01 2.55E+00 1.12E+01

Volatile Organic Compounds PER 009 7.79E-01 1.78E-01 7.79E-01

EU 095

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 009

Cadmium compounds PER 009

Methane PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Cobalt compounds PER 009

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

PM < 2.5 micron PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Page 25 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 095

Selenium compounds PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 096

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 009

Cadmium compounds PER 009

Methane PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Cobalt compounds PER 009

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

PM < 2.5 micron PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Selenium compounds PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 097

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Carbon Dioxide Equivalent PER 009

Cadmium compounds PER 009

Methane PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Cobalt compounds PER 009

Chromium compounds PER 009

1,4-Dichlorobenzene PER 009

Formaldehyde PER 009

Page 26 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 097

Hexane PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

Nitrous Oxide PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

PM < 2.5 micron PER 009

Lead PER 009

PM < 10 micron PER 009

Polycyclic organic matter PER 009

Total Particulate Matter PER 009

Selenium compounds PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 098

Benzene PER 009 2.98E-04 6.79E-05 2.98E-04

A rsenic compounds PER 009 2.83E-05 6.47E-06 2.83E-05

Beryllium Compounds PER 009 1.70E-06 3.88E-07 1.70E-06

Carbon Dioxide Equivalent PER 010 1.79E+04 4.08E+03 1.79E+04

Cadmium compounds PER 009 1.56E-04 3.56E-05 1.56E-04

Methane PER 009 9.56E-01 2.18E-01 9.56E-01

Carbon Monoxide PER 001 1.19E+01 2.72E+00 1.19E+01

Carbon Dioxide PER 010 1.78E+04 4.06E+03 1.78E+04

Cobalt compounds PER 009 1.19E-05 2.72E-06 1.19E-05

Chromium compounds PER 009 1.98E-04 4.53E-05 1.98E-04

1,4-Dichlorobenzene PER 009 1.70E-04 3.88E-05 1.70E-04

Formaldehyde PER 009 1.06E-02 2.43E-03 1.06E-02

Hexane PER 009 2.55E-01 5.82E-02 2.55E-01

Naphthalene PER 009 8.64E-05 1.97E-05 8.64E-05

HAPs - Total PER 009 2.67E-01 6.11E-02 2.67E-01

Mercury Compounds PER 009 3.68E-05 8.41E-06 3.68E-05

Toluene PER 009 4.82E-04 1.10E-04 4.82E-04

Manganese compounds PER 009 5.38E-05 1.23E-05 5.38E-05

Nitrous Oxide PER 009 1.91E-01 4.37E-02 1.91E-01

Nickel compounds PER 009 2.98E-04 6.79E-05 2.98E-04

Nitrogen Oxides PER 009 6.50E+00 1.49E+00 6.50E+00

PM < 2.5 micron PER 009 1.08E+00 2.46E-01 1.08E+00

Lead PER 009 7.09E-05 1.62E-05 7.09E-05

PM < 10 micron PER 009 1.08E+00 2.46E-01 1.08E+00

Polycyclic organic matter PER 009 1.25E-05 2.85E-06 1.25E-05

Total Particulate Matter PER 009 1.08E+00 2.46E-01 1.08E+00

Selenium compounds PER 009 3.40E-06 7.76E-07 3.40E-06

Sulfur Dioxide PER 009 1.12E+01 2.55E+00 1.12E+01

Page 27 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 098

Volatile Organic Compounds PER 009 7.79E-01 1.78E-01 7.79E-01

EU 099

Carbon Dioxide Equivalent PER 009 1.45E+03 3.32E+02 1.45E+03

Methane PER 009 4.25E-02 9.69E-03 4.25E-02

Carbon Dioxide PER 009 1.45E+03 3.31E+02 1.45E+03

Hydrochloric acid PER 009 2.22E-03 5.07E-04 2.22E-03

Nitrous Oxide PER 009 8.49E-03 1.94E-03 8.49E-03

Sulfur Dioxide PER 009 3.07E-02 7.00E-03 3.07E-02

EU 100

A cetaldehyde PER 001 5.67E-04 1.29E-04 5.67E-04

A crolein PER 001 1.77E-04 4.05E-05 1.77E-04

Benzene PER 001 1.75E-02 3.99E-03 1.75E-02

A rsenic compounds PER 001 9.45E-05 2.16E-05 9.45E-05

Beryllium Compounds PER 001 5.63E-05 1.28E-05 5.63E-05

Carbon Dioxide Equivalent PER 009 4.20E+02 8.41E+02 3.68E+03

Cadmium compounds PER 001 2.48E-04 5.65E-05 2.48E-04

Methane PER 009 1.70E-02 3.40E-02 1.49E-01

Carbon Monoxide PER 001 1.65E+01 3.77E+00 1.65E+01

Carbon Dioxide PER 009 4.19E+02 8.38E+02 3.67E+03

Chromium compounds PER 001 1.51E-03 3.44E-04 1.51E-03

Formaldehyde PER 001 1.78E-03 4.05E-04 1.78E-03

Naphthalene PER 001 2.93E-03 6.68E-04 2.93E-03

HAPs - Total PER 001 3.97E-02 9.06E-03 3.97E-02

Mercury Compounds PER 001 6.75E-05 1.54E-05 6.75E-05

Toluene PER 001 6.32E-03 1.44E-03 6.32E-03

Xylenes (mixed isomers) PER 009 4.34E-03 9.92E-04 4.34E-03

Manganese compounds PER 001 3.15E-04 7.19E-05 3.15E-04

Nitrous Oxide PER 009 3.40E-03 6.80E-03 2.98E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.83E-03 8.73E-04 3.83E-03

Nitrogen Oxides PER 001 7.20E+01 1.64E+01 7.20E+01

PM < 2.5 micron PER 009 2.10E+00 4.80E-01 2.10E+00

PM < 10 micron PER 001 2.10E+00 4.80E-01 2.10E+00

Total Particulate Matter PER 001 2.10E+00 4.80E-01 2.10E+00

Sulfur Dioxide PER 009 1.20E+00 2.74E-01 1.20E+00

Volatile Organic Compounds PER 009 1.92E+00 4.38E-01 1.92E+00

EU 102

Benzene PER 009 2.86E-04 6.53E-05 2.86E-04

A rsenic compounds PER 009 2.72E-05 6.22E-06 2.72E-05

Beryllium Compounds PER 009 1.63E-06 3.73E-07 1.63E-06

Carbon Dioxide Equivalent PER 010 1.72E+04 3.92E+03 1.72E+04

Cadmium compounds PER 009 1.50E-04 3.42E-05 1.50E-04

Methane PER 010 9.18E-01 2.10E-01 9.18E-01

Carbon Monoxide PER 009 1.14E+01 2.61E+00 1.14E+01

Carbon Dioxide PER 010 1.71E+04 3.90E+03 1.71E+04

Cobalt compounds PER 009 1.14E-05 2.61E-06 1.14E-05

Page 28 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 102

Chromium compounds PER 009 1.91E-04 4.35E-05 1.91E-04

1,4-Dichlorobenzene PER 009 1.63E-04 3.73E-05 1.63E-04

Formaldehyde PER 009 1.02E-02 2.33E-03 1.02E-02

Hexane PER 009 2.45E-01 5.59E-02 2.45E-01

Naphthalene PER 009 8.30E-05 1.90E-05 8.30E-05

HAPs - Total PER 009 2.57E-01 5.87E-02 2.57E-01

Mercury Compounds PER 009 3.54E-05 8.08E-06 3.54E-05

Toluene PER 009 4.63E-04 1.06E-04 4.63E-04

Manganese compounds PER 009 5.17E-05 1.18E-05 5.17E-05

Nitrous Oxide PER 010 1.84E-01 4.19E-02 1.84E-01

Nickel compounds PER 009 2.86E-04 6.53E-05 2.86E-04

Nitrogen Oxides PER 009 1.67E+01 3.80E+00 1.67E+01

PM < 2.5 micron PER 009 1.03E+00 2.36E-01 1.03E+00

Lead PER 009 6.81E-05 1.55E-05 6.81E-05

PM < 10 micron PER 009 1.03E+00 2.36E-01 1.03E+00

Polycyclic organic matter PER 009 1.20E-05 2.74E-06 1.20E-05

Total Particulate Matter PER 009 1.03E+00 2.36E-01 1.03E+00

Selenium compounds PER 009 3.27E-06 7.46E-07 3.27E-06

Sulfur Dioxide PER 009 1.07E+01 2.45E+00 1.07E+01

Volatile Organic Compounds PER 009 7.49E-01 1.71E-01 7.49E-01

EU 103

Benzene PER 009 2.74E-04 6.26E-05 2.74E-04

A rsenic compounds PER 009 2.61E-05 5.96E-06 2.61E-05

Beryllium Compounds PER 009 1.57E-06 3.58E-07 1.57E-06

Carbon Dioxide Equivalent PER 010 1.65E+04 3.76E+03 1.65E+04

Cadmium compounds PER 009 1.44E-04 3.28E-05 1.44E-04

Methane PER 010 8.81E-01 2.01E-01 8.81E-01

Carbon Monoxide PER 009 1.10E+01 2.50E+00 1.10E+01

Carbon Dioxide PER 010 1.64E+04 3.74E+03 1.64E+04

Cobalt compounds PER 009 1.10E-05 2.50E-06 1.10E-05

Chromium compounds PER 009 1.83E-04 4.17E-05 1.83E-04

1,4-Dichlorobenzene PER 009 1.57E-04 3.58E-05 1.57E-04

Formaldehyde PER 009 9.79E-03 2.24E-03 9.79E-03

Hexane PER 009 2.35E-01 5.36E-02 2.35E-01

Naphthalene PER 009 7.96E-05 1.82E-05 7.96E-05

HAPs - Total PER 009 2.46E-01 5.63E-02 2.46E-01

Mercury Compounds PER 009 3.39E-05 7.75E-06 3.39E-05

Toluene PER 009 4.44E-04 1.01E-04 4.44E-04

Manganese compounds PER 009 4.96E-05 1.13E-05 4.96E-05

Nitrous Oxide PER 010 1.76E-01 4.02E-02 1.76E-01

Nickel compounds PER 009 2.74E-04 6.26E-05 2.74E-04

Nitrogen Oxides PER 009 1.60E+01 3.65E+00 1.60E+01

PM < 2.5 micron PER 009 9.92E-01 2.27E-01 9.92E-01

Lead PER 009 6.53E-05 1.49E-05 6.53E-05

PM < 10 micron PER 009 9.92E-01 2.27E-01 9.92E-01

Polycyclic organic matter PER 009 1.15E-05 2.63E-06 1.15E-05

Page 29 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 103

Total Particulate Matter PER 009 9.92E-01 2.27E-01 9.92E-01

Selenium compounds PER 009 3.13E-06 7.15E-07 3.13E-06

Sulfur Dioxide PER 009 1.03E+01 2.35E+00 1.03E+01

Volatile Organic Compounds PER 009 7.18E-01 1.64E-01 7.18E-01

EU 104

Benzene PER 009 5.05E-04 1.15E-04 5.05E-04

A rsenic compounds PER 009 4.81E-05 1.10E-05 4.81E-05

Beryllium Compounds PER 009 2.89E-06 6.59E-07 2.89E-06

Carbon Dioxide Equivalent PER 010 3.03E+04 6.92E+03 3.03E+04

Cadmium compounds PER 009 2.65E-04 6.04E-05 2.65E-04

Methane PER 010 1.62E+00 3.70E-01 1.62E+00

Carbon Monoxide PER 001 2.02E+01 4.61E+00 2.02E+01

Carbon Dioxide PER 010 3.02E+04 6.89E+03 3.02E+04

Cobalt compounds PER 009 2.02E-05 4.61E-06 2.02E-05

Chromium compounds PER 009 3.37E-04 7.69E-05 3.37E-04

1,4-Dichlorobenzene PER 009 2.89E-04 6.59E-05 2.89E-04

Formaldehyde PER 009 1.80E-02 4.12E-03 1.80E-02

Hexane PER 009 4.33E-01 9.88E-02 4.33E-01

Naphthalene PER 009 1.47E-04 3.35E-05 1.47E-04

HAPs - Total PER 009 4.54E-01 1.04E-01 4.54E-01

Mercury Compounds PER 009 6.25E-05 1.43E-05 6.25E-05

Toluene PER 009 8.18E-04 1.87E-04 8.18E-04

Manganese compounds PER 009 9.14E-05 2.09E-05 9.14E-05

Nitrous Oxide PER 010 3.24E-01 7.41E-02 3.24E-01

Nickel compounds PER 009 5.05E-04 1.15E-04 5.05E-04

Nitrogen Oxides PER 009 1.22E+01 2.52E+00 1.10E+01

PM < 2.5 micron PER 009 1.83E+00 4.17E-01 1.83E+00

Lead PER 009 1.20E-04 2.75E-05 1.20E-04

PM < 10 micron PER 009 1.83E+00 4.17E-01 1.83E+00

Polycyclic organic matter PER 009 2.12E-05 4.84E-06 2.12E-05

Total Particulate Matter PER 009 1.83E+00 4.17E-01 1.83E+00

Selenium compounds PER 009 5.77E-06 1.32E-06 5.77E-06

Sulfur Dioxide PER 009 1.89E+01 4.32E+00 1.89E+01

Volatile Organic Compounds PER 009 1.32E+00 3.02E-01 1.32E+00

EU 111

A cetaldehyde PER 009

Carbon disulfide PER 009

Carbonyl sulfide PER 009

Carbon Dioxide Equivalent PER 009

Cyanide compounds PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Formaldehyde PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

Page 30 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 111

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 112

A cetaldehyde PER 009

Carbon disulfide PER 009

Carbonyl sulfide PER 009

Carbon Dioxide Equivalent PER 009

Cyanide compounds PER 009

Carbon Monoxide PER 009

Carbon Dioxide PER 009

Formaldehyde PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 121

Carbon Monoxide PER 007

HAPs - Total PER 007

Nitrogen Oxides PER 007

Lead PER 007

PM < 10 micron PER 007

Total Particulate Matter PER 007

Sulfur Dioxide PER 007

Volatile Organic Compounds PER 007

EU 122

Carbon Monoxide PER 007

HAPs - Total PER 007

Nitrogen Oxides PER 007

Lead PER 007

PM < 10 micron PER 007

Total Particulate Matter PER 007

Sulfur Dioxide PER 007

Volatile Organic Compounds PER 007

EU 123

Carbon Monoxide PER 007

HAPs - Total PER 007

Nitrogen Oxides PER 007

Lead PER 007

PM < 10 micron PER 007

Total Particulate Matter PER 007

Sulfur Dioxide PER 007

Page 31 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 123

Volatile Organic Compounds PER 007

EU 124

Carbon Monoxide PER 007

HAPs - Total PER 007

Nitrogen Oxides PER 007

Lead PER 007

PM < 10 micron PER 007

Total Particulate Matter PER 007

Sulfur Dioxide PER 007

Volatile Organic Compounds PER 007

EU 126

Benzene PER 009 1.08E-03 2.47E-04 1.08E-03

A rsenic compounds PER 009 1.03E-04 2.35E-05 1.03E-04

Beryllium Compounds PER 009 6.18E-06 1.41E-06 6.18E-06

Carbon Dioxide Equivalent PER 010 7.12E+04 1.63E+04 7.12E+04

Cadmium compounds PER 009 5.67E-04 1.29E-04 5.67E-04

Methane PER 009 3.48E+00 7.94E-01 3.48E+00

Carbon Monoxide PER 009 4.33E+01 9.88E+00 4.33E+01

Carbon Dioxide PER 010 7.10E+04 1.62E+04 7.10E+04

Cobalt compounds PER 009 4.33E-05 9.88E-06 4.33E-05

Chromium compounds PER 009 7.21E-04 1.65E-04 7.21E-04

1,4-Dichlorobenzene PER 009 6.18E-04 1.41E-04 6.18E-04

Formaldehyde PER 009 3.86E-02 8.82E-03 3.86E-02

Hexane PER 009 9.28E-01 2.12E-01 9.28E-01

Naphthalene PER 009 3.14E-04 7.18E-05 3.14E-04

HAPs - Total PER 009 9.73E-01 2.22E-01 9.73E-01

Mercury Compounds PER 009 1.34E-04 3.06E-05 1.34E-04

Toluene PER 009 1.75E-03 4.00E-04 1.75E-03

Manganese compounds PER 009 1.96E-04 4.47E-05 1.96E-04

Nitrous Oxide PER 009 6.95E-01 1.59E-01 6.95E-01

Nickel compounds PER 009 1.08E-03 2.47E-04 1.08E-03

Nitrogen Oxides PER 009 2.37E+01 5.40E+00 2.37E+01

PM < 2.5 micron PER 009 3.92E+00 8.94E-01 3.92E+00

Lead PER 009 2.58E-03 5.88E-04 2.58E-03

PM < 10 micron PER 009 3.92E+00 8.94E-01 3.92E+00

Polycyclic organic matter PER 009 4.54E-05 1.04E-05 4.54E-05

Total Particulate Matter PER 009 3.92E+00 8.94E-01 3.92E+00

Selenium compounds PER 009 1.24E-05 2.82E-06 1.24E-05

Sulfur Dioxide PER 009 1.90E+02 5.08E+00 1.20E+01

Volatile Organic Compounds PER 009 2.83E+00 6.47E-01 2.83E+00

EU 127

A cetaldehyde PER 001 5.84E-04 1.33E-04 5.84E-04

A crolein PER 001 1.82E-04 4.17E-05 1.82E-04

Benzene PER 001 1.80E-02 4.10E-03 1.80E-02

A rsenic compounds PER 001 9.73E-05 2.22E-05 9.73E-05

Beryllium Compounds PER 001 5.79E-05 1.32E-05 5.79E-05

Page 32 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 127

Carbon Dioxide Equivalent PER 009 3.79E+03 8.65E+02 3.79E+03

Cadmium compounds PER 001 2.55E-04 5.82E-05 2.55E-04

Methane PER 009 1.53E-01 3.50E-02 1.53E-01

Carbon Monoxide PER 001 1.70E+01 3.88E+00 1.70E+01

Carbon Dioxide PER 009 3.78E+03 8.62E+02 3.78E+03

Chromium compounds PER 001 1.55E-03 3.54E-04 1.55E-03

Formaldehyde PER 001 1.83E-03 4.17E-04 1.83E-03

Naphthalene PER 001 3.01E-03 6.87E-04 3.01E-03

HAPs - Total PER 001 4.08E-02 9.33E-03 4.08E-02

Mercury Compounds PER 001 6.95E-05 1.59E-05 6.95E-05

Toluene PER 001 6.51E-03 1.49E-03 6.51E-03

Xylenes (mixed isomers) PER 009 4.47E-03 1.02E-03 4.47E-03

Manganese compounds PER 001 3.24E-04 7.40E-05 3.24E-04

Nitrous Oxide PER 009 3.06E-02 6.99E-03 3.06E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.94E-03 8.99E-04 3.94E-03

Nitrogen Oxides PER 009 2.18E+01 1.74E+01 7.62E+01

PM < 2.5 micron PER 009 2.16E+00 4.94E-01 2.16E+00

PM < 10 micron PER 009 2.16E+00 4.94E-01 2.16E+00

Total Particulate Matter PER 009 2.16E+00 4.94E-01 2.16E+00

Sulfur Dioxide PER 009 1.24E+00 2.82E-01 1.24E+00

Volatile Organic Compounds PER 009 1.98E+00 4.51E-01 1.98E+00

EU 128

A cetaldehyde PER 001 5.22E-04 1.19E-04 5.22E-04

A crolein PER 001 1.63E-04 3.72E-05 1.63E-04

Benzene PER 001 1.61E-02 3.67E-03 1.61E-02

A rsenic compounds PER 001 8.69E-05 1.98E-05 8.69E-05

Beryllium Compounds PER 001 5.17E-05 1.18E-05 5.17E-05

Carbon Dioxide Equivalent PER 009 3.87E+02 7.73E+02 3.39E+03

Cadmium compounds PER 001 2.28E-04 5.20E-05 2.28E-04

Methane PER 009 1.56E-02 3.13E-02 1.37E-01

Carbon Monoxide PER 001 1.52E+01 3.47E+00 1.52E+01

Carbon Dioxide PER 009 3.85E+02 7.70E+02 3.37E+03

Chromium compounds PER 001 1.39E-03 3.17E-04 1.39E-03

Formaldehyde PER 001 1.63E-03 3.73E-04 1.63E-03

Naphthalene PER 001 2.69E-03 6.14E-04 2.69E-03

HAPs - Total PER 001 3.65E-02 8.33E-03 3.65E-02

Mercury Compounds PER 001 6.21E-05 1.42E-05 6.21E-05

Toluene PER 001 5.82E-03 1.33E-03 5.82E-03

Xylenes (mixed isomers) PER 009 3.99E-03 9.12E-04 3.99E-03

Manganese compounds PER 001 2.90E-04 6.62E-05 2.90E-04

Nitrous Oxide PER 009 3.13E-03 6.25E-03 2.74E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.52E-03 8.03E-04 3.52E-03

Nitrogen Oxides PER 001 6.62E+01 1.51E+01 6.62E+01

PM < 2.5 micron PER 009 1.93E+00 4.41E-01 1.93E+00

Page 33 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 128

PM < 10 micron PER 009 1.93E+00 4.41E-01 1.93E+00

Total Particulate Matter PER 009 1.93E+00 4.41E-01 1.93E+00

Sulfur Dioxide PER 009 1.10E+00 2.52E-01 1.10E+00

Volatile Organic Compounds PER 009 1.77E+00 4.03E-01 1.77E+00

EU 129

A cetaldehyde PER 009 2.69E-04 6.14E-05 2.69E-04

A crolein PER 009 8.41E-05 1.92E-05 8.41E-05

Benzene PER 009 8.28E-03 1.89E-03 8.28E-03

A rsenic compounds PER 009 4.48E-05 1.02E-05 4.48E-05

Beryllium Compounds PER 009 2.67E-05 6.09E-06 2.67E-05

Carbon Dioxide Equivalent PER 009 1.99E+02 3.99E+02 1.75E+03

Cadmium compounds PER 009 1.17E-04 2.68E-05 1.17E-04

Methane PER 009 8.06E-03 1.61E-02 7.06E-02

Carbon Monoxide PER 009 7.83E+00 1.79E+00 7.83E+00

Carbon Dioxide PER 009 1.99E+02 3.97E+02 1.74E+03

Chromium compounds PER 009 7.15E-04 1.63E-04 7.15E-04

Formaldehyde PER 009 8.42E-04 1.92E-04 8.42E-04

Naphthalene PER 009 1.39E-03 3.17E-04 1.39E-03

HAPs - Total PER 009 1.88E-02 4.30E-03 1.88E-02

Mercury Compounds PER 009 3.20E-05 7.31E-06 3.20E-05

Toluene PER 009 3.00E-03 6.85E-04 3.00E-03

Xylenes (mixed isomers) PER 009 2.06E-03 4.70E-04 2.06E-03

Manganese compounds PER 009 1.49E-04 3.41E-05 1.49E-04

Nitrous Oxide PER 009 1.61E-03 3.22E-03 1.41E-02

o-Xylenes PER 009

Nickel compounds PER 009 1.81E-03 4.14E-04 1.81E-03

Nitrogen Oxides PER 009 3.42E+01 7.80E+00 3.42E+01

PM < 2.5 micron PER 009 9.96E-01 2.28E-01 9.96E-01

PM < 10 micron PER 009 9.96E-01 2.28E-01 9.96E-01

Total Particulate Matter PER 009 9.96E-01 2.28E-01 9.96E-01

Sulfur Dioxide PER 009 5.69E-01 1.30E-01 5.69E-01

Volatile Organic Compounds PER 009 9.11E-01 2.08E-01 9.11E-01

EU 130

A cetaldehyde PER 009 4.52E-04 1.03E-04 4.52E-04

A crolein PER 009 1.41E-04 3.23E-05 1.41E-04

Benzene PER 009 1.39E-02 3.18E-03 1.39E-02

A rsenic compounds PER 009 7.53E-05 1.72E-05 7.53E-05

Beryllium Compounds PER 009 4.48E-05 1.02E-05 4.48E-05

Carbon Dioxide Equivalent PER 009 3.35E+02 6.70E+02 2.93E+03

Cadmium compounds PER 009 1.97E-04 4.50E-05 1.97E-04

Methane PER 009 1.35E-02 2.71E-02 1.19E-01

Carbon Monoxide PER 009 1.32E+01 3.00E+00 1.32E+01

Carbon Dioxide PER 009 3.34E+02 6.68E+02 2.92E+03

Chromium compounds PER 009 1.20E-03 2.74E-04 1.20E-03

Formaldehyde PER 009 1.42E-03 3.23E-04 1.42E-03

Naphthalene PER 009 2.33E-03 5.32E-04 2.33E-03

Page 34 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 130

HAPs - Total PER 009 3.16E-02 7.22E-03 3.16E-02

Mercury Compounds PER 009 5.38E-05 1.23E-05 5.38E-05

Toluene PER 009 5.04E-03 1.15E-03 5.04E-03

Xylenes (mixed isomers) PER 009 3.46E-03 7.90E-04 3.46E-03

Manganese compounds PER 009 2.51E-04 5.73E-05 2.51E-04

Nitrous Oxide PER 009 2.71E-03 5.42E-03 2.37E-02

o-Xylenes PER 009

Nickel compounds PER 009 3.05E-03 6.96E-04 3.05E-03

Nitrogen Oxides PER 009 5.74E+01 1.31E+01 5.74E+01

PM < 2.5 micron PER 009 1.67E+00 3.82E-01 1.67E+00

PM < 10 micron PER 009 1.67E+00 3.82E-01 1.67E+00

Total Particulate Matter PER 009 1.67E+00 3.82E-01 1.67E+00

Sulfur Dioxide PER 009 9.57E-01 2.18E-01 9.57E-01

Volatile Organic Compounds PER 009 1.53E+00 3.49E-01 1.53E+00

EU 131

A cetaldehyde PER 009 1.45E-04 3.31E-05 1.45E-04

A crolein PER 009 4.53E-05 1.03E-05 4.53E-05

Benzene PER 009 4.46E-03 1.02E-03 4.46E-03

A rsenic compounds PER 009 2.41E-05 5.51E-06 2.41E-05

Beryllium Compounds PER 009 1.44E-05 3.28E-06 1.44E-05

Carbon Dioxide Equivalent PER 009 1.07E+02 2.15E+02 9.41E+02

Cadmium compounds PER 009 6.32E-05 1.44E-05 6.32E-05

Methane PER 009 4.34E-03 8.68E-03 3.80E-02

Carbon Monoxide PER 009 4.22E+00 9.63E-01 4.22E+00

Carbon Dioxide PER 009 1.07E+02 2.14E+02 9.37E+02

Chromium compounds PER 009 3.85E-04 8.79E-05 3.85E-04

Formaldehyde PER 009 4.54E-04 1.04E-04 4.54E-04

Naphthalene PER 009 7.47E-04 1.71E-04 7.47E-04

HAPs - Total PER 009 1.01E-02 2.31E-03 1.01E-02

Mercury Compounds PER 009 1.72E-05 3.94E-06 1.72E-05

Toluene PER 009 1.62E-03 3.69E-04 1.62E-03

Xylenes (mixed isomers) PER 009 2.53E-01 1.11E-03

Manganese compounds PER 009 8.05E-05 1.84E-05 8.05E-05

Nitrous Oxide PER 009 8.68E-04 1.74E-03 7.60E-03

o-Xylenes PER 009

Nickel compounds PER 009 9.77E-04 2.23E-04 9.77E-04

Nitrogen Oxides PER 009 1.84E+01 4.20E+00 1.84E+01

PM < 2.5 micron PER 009 5.37E-01 1.23E-01 5.37E-01

PM < 10 micron PER 009 5.37E-01 1.23E-01 5.37E-01

Total Particulate Matter PER 009 5.37E-01 1.23E-01 5.37E-01

Sulfur Dioxide PER 009 3.07E-01 7.00E-02 3.07E-01

Volatile Organic Compounds PER 009 4.91E-01 1.12E-01 4.91E-01

EU 132

A cetaldehyde PER 009 4.14E-04 9.45E-05 4.14E-04

A crolein PER 009 1.29E-04 2.96E-05 1.29E-04

Benzene PER 009 1.27E-02 2.91E-03 1.27E-02

Page 35 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 132

A rsenic compounds PER 009 6.90E-05 1.58E-05 6.90E-05

Beryllium Compounds PER 009 4.11E-05 9.38E-06 4.11E-05

Carbon Dioxide Equivalent PER 009 3.07E+02 6.14E+02 2.69E+03

Cadmium compounds PER 009 1.81E-04 4.13E-05 1.81E-04

Methane PER 009 1.24E-02 2.48E-02 1.09E-01

Carbon Monoxide PER 009 1.20E+01 2.75E+00 1.20E+01

Carbon Dioxide PER 009 3.06E+02 6.11E+02 2.68E+03

Chromium compounds PER 009 1.10E-03 2.51E-04 1.10E-03

Formaldehyde PER 009 1.30E-03 2.96E-04 1.30E-03

Naphthalene PER 009 2.14E-03 4.88E-04 2.14E-03

HAPs - Total PER 009 2.90E-02 6.61E-03 2.90E-02

Mercury Compounds PER 009 4.93E-05 1.13E-05 4.93E-05

Toluene PER 009 4.62E-03 1.05E-03 4.62E-03

Xylenes (mixed isomers) PER 009 3.17E-03 7.24E-04 3.17E-03

Manganese compounds PER 009 2.30E-04 5.25E-05 2.30E-04

Nitrous Oxide PER 009 2.48E-03 4.96E-03 2.17E-02

o-Xylenes PER 009

Nickel compounds PER 009 2.79E-03 6.38E-04 2.79E-03

Nitrogen Oxides PER 009 5.26E+01 1.20E+01 5.26E+01

PM < 2.5 micron PER 009 1.53E+00 3.50E-01 1.53E+00

PM < 10 micron PER 009 1.53E+00 3.50E-01 1.53E+00

Total Particulate Matter PER 009 1.53E+00 3.50E-01 1.53E+00

Sulfur Dioxide PER 009 8.76E-01 2.00E-01 8.76E-01

Volatile Organic Compounds PER 009 1.40E+00 3.20E-01 1.40E+00

EU 133

A cetaldehyde PER 009

A crolein PER 009

Benzene PER 009

A rsenic compounds PER 009

Beryllium Compounds PER 009

Cadmium compounds PER 009

Carbon Monoxide PER 009

Chromium compounds PER 009

Formaldehyde PER 009

Naphthalene PER 009

HAPs - Total PER 009

Mercury Compounds PER 009

Toluene PER 009

Manganese compounds PER 009

o-Xylenes PER 009

Nickel compounds PER 009

Nitrogen Oxides PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

Page 36 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 144

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 145

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 146

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 147

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 148

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 149

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Page 37 of 70MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 149

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 152

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 153

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 154

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 155

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 156

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 157

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Page 38 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 157

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 158

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 159

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 160

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 161

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 162

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

Page 39 of 70MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 163

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 164

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 165

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 166

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 167

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 168

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Page 40 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 168

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 169

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 170

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 171

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 172

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 173

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 198

A cetaldehyde PER 001 5.38E-04 1.23E-04 5.38E-04

A crolein PER 001 1.68E-04 3.84E-05 1.68E-04

Page 41 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 198

Benzene PER 001 1.66E-02 3.78E-03 1.66E-02

A rsenic compounds PER 001 8.97E-05 2.05E-05 8.97E-05

Beryllium Compounds PER 001 5.34E-05 1.22E-05 5.34E-05

Carbon Dioxide Equivalent PER 009 3.99E+02 7.98E-02 3.49E+03

Cadmium compounds PER 001 2.35E-04 5.36E-05 2.35E-04

Methane PER 009 1.61E-02 3.22E-02 1.41E-01

Carbon Monoxide PER 001 1.57E+01 3.58E+00 1.57E+01

Carbon Dioxide PER 009 3.97E+02 7.95E+02 3.48E+03

Chromium compounds PER 001 1.43E-03 3.27E-04 1.43E-03

Formaldehyde PER 001 1.68E-03 3.85E-04 1.68E-03

Naphthalene PER 001 2.78E-03 6.34E-04 2.78E-03

HAPs - Total PER 001 3.77E-02 8.60E-03 3.77E-02

Mercury Compounds PER 001 6.41E-05 1.46E-05 6.41E-05

Toluene PER 001 6.00E-03 1.37E-03 6.00E-03

Xylenes (mixed isomers) PER 009 4.12E-03 9.41E-04 4.12E-03

Manganese compounds PER 001 2.99E-04 6.83E-05 2.99E-04

Nitrous Oxide PER 009 3.22E-03 6.45E-03 2.82E-02

o-Xylenes PER 009

Nickel compounds PER 001 3.63E-03 8.29E-04 3.63E-03

Nitrogen Oxides PER 001 6.83E+01 1.56E+01 6.83E+01

PM < 2.5 micron PER 009 1.99E+00 4.55E-01 1.99E+00

PM < 10 micron PER 009 1.99E+00 4.55E-01 1.99E+00

Total Particulate Matter PER 009 1.99E+00 4.55E-01 1.99E+00

Sulfur Dioxide PER 009 1.14E+00 2.60E-01 1.14E+00

Volatile Organic Compounds PER 009 1.82E+00 4.16E-01 1.82E+00

EU 199

A cetaldehyde PER 001 5.38E-04 1.23E-04 5.38E-04

A crolein PER 001 1.68E-04 3.84E-05 1.68E-04

Benzene PER 001 1.66E-02 3.78E-03 1.66E-02

A rsenic compounds PER 001 8.97E-05 2.05E-05 8.97E-05

Beryllium Compounds PER 001 5.34E-05 1.22E-05 5.34E-05

Carbon Dioxide Equivalent PER 009 3.99E+02 7.98E+02 3.49E+03

Cadmium compounds PER 001 2.35E-04 5.36E-05 2.35E-04

Methane PER 009 1.61E-02 3.22E-02 1.41E-01

Carbon Monoxide PER 001 1.57E+01 3.58E+00 1.57E+01

Carbon Dioxide PER 009 3.97E+02 7.95E+02 3.48E+03

Chromium compounds PER 001 1.43E-03 3.27E-04 1.43E-03

Formaldehyde PER 001 1.68E-03 3.85E-04 1.68E-03

Naphthalene PER 001 2.78E-03 6.34E-04 2.78E-03

HAPs - Total PER 001 3.77E-02 8.60E-03 3.77E-02

Mercury Compounds PER 001 6.41E-05 1.46E-05 6.41E-05

Toluene PER 001 6.00E-03 1.37E-03 6.00E-03

Xylenes (mixed isomers) PER 009 4.12E-03 9.41E-04 4.12E-03

Manganese compounds PER 001 2.99E-04 6.83E-05 2.99E-04

Nitrous Oxide PER 009 3.22E-03 6.45E-03 2.82E-02

o-Xylenes PER 009

Page 42 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 199

Nickel compounds PER 001 3.63E-03 8.29E-04 3.63E-03

Nitrogen Oxides PER 001 6.83E+01 1.56E+01 6.83E+01

PM < 2.5 micron PER 009 1.99E+00 4.55E-01 1.99E+00

PM < 10 micron PER 009 1.99E+00 4.55E-01 1.99E+00

Total Particulate Matter PER 009 1.99E+00 4.55E-01 1.99E+00

Sulfur Dioxide PER 009 1.14E+00 2.60E-01 1.14E+00

Volatile Organic Compounds PER 009 1.82E+00 4.16E-01 1.82E+00

EU 204

Benzene PER 001 1.67E-03 3.81E-04 1.67E-03

A rsenic compounds PER 001 1.59E-04 3.63E-05 1.59E-04

Beryllium Compounds PER 001 9.53E-06 2.18E-06 9.53E-06

Carbon Dioxide Equivalent PER 009 7.14E+04 2.16E+04 9.48E+04

Cadmium compounds PER 001 8.74E-04 2.00E-04 8.74E-04

Methane PER 009 1.35E+00 4.08E-01 1.79E+00

Carbon Monoxide PER 001 6.67E+01 1.52E+01 6.67E+01

Carbon Dioxide PER 009 7.14E+04 2.16E+04 9.47E+04

Cobalt compounds PER 001 6.67E-05 1.52E-05 6.67E-05

Chromium compounds PER 001 1.11E-03 2.54E-04 1.11E-03

1,4-Dichlorobenzene PER 009 9.53E-04 2.18E-04 9.53E-04

Formaldehyde PER 001 5.96E-02 1.36E-02 5.96E-02

Hexane PER 001 1.43E+00 3.26E-01 1.43E+00

Naphthalene PER 001 4.85E-04 1.11E-04 4.85E-04

HAPs - Total PER 001 1.50E+00 3.42E-01 1.50E+00

Mercury Compounds PER 001 2.07E-04 4.72E-05 2.07E-04

Toluene PER 001 2.70E-03 6.17E-04 2.70E-03

Manganese compounds PER 001 3.02E-04 6.89E-05 3.02E-04

Nitrous Oxide PER 009 1.35E-01 4.08E-02 1.79E-01

Nickel compounds PER 001 1.67E-03 3.81E-04 1.67E-03

Nitrogen Oxides PER 009 3.99E+01 3.70E+01 1.62E+02

PM < 2.5 micron PER 009 6.04E+00 1.38E+00 6.04E+00

Lead PER 001 3.97E-04 9.07E-05 3.97E-04

PM < 10 micron PER 001 6.04E+00 1.38E+00 6.04E+00

Polycyclic organic matter PER 001 7.01E-05 1.60E-05 7.01E-05

Total Particulate Matter PER 001 6.04E+00 1.38E+00 6.04E+00

Selenium compounds PER 001 1.91E-05 4.35E-06 1.91E-05

Sulfur Dioxide PER 009 5.32E-01 1.22E-01 5.32E-01

Volatile Organic Compounds PER 009 4.37E+00 9.98E-01 4.37E+00

EU 209

Carbon Dioxide Equivalent PER 009 1.43E+04 3.26E+03 1.43E+04

Methane PER 009 4.89E-01 1.12E-01 4.89E-01

Carbon Monoxide PER 009 6.13E+00 1.40E+00 6.13E+00

Carbon Dioxide PER 009 1.43E+04 3.26E+03 1.43E+04

Nitrous Oxide PER 009 2.69E-02 6.15E-03 2.69E-02

Nitrogen Oxides PER 009 2.04E+01 4.67E+00 2.04E+01

PM < 2.5 micron PER 009 5.55E-01 1.27E-01 5.55E-01

Lead PER 009 3.65E-05 8.33E-06 3.65E-05

Page 43 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 209

PM < 10 micron PER 009 5.55E-01 1.27E-01 5.55E-01

Total Particulate Matter PER 009 5.55E-01 1.27E-01 5.55E-01

Sulfur Dioxide PER 009 4.89E-02 1.12E-02 4.89E-02

Volatile Organic Compounds PER 009 4.02E-01 9.17E-02 4.02E-01

EU 212

Benzene PER 010 3.70E-03 8.44E-04 3.70E-03

A rsenic compounds PER 010 3.52E-04 8.04E-05 3.52E-04

Beryllium Compounds PER 010 2.11E-05 4.82E-06 2.11E-05

Carbon Dioxide Equivalent PER 010 2.32E+05 5.29E+04 2.32E+05

Cadmium compounds PER 010 1.94E-03 4.42E-04 1.94E-03

Methane PER 010 1.19E+01 2.71E+00 1.19E+01

Carbon Monoxide PER 010 1.00E+01 4.10E+00 1.80E+01

Carbon Dioxide PER 010 2.31E+05 5.27E+04 2.31E+05

Cobalt compounds PER 010 1.48E-04 3.38E-05 1.48E-04

Chromium compounds PER 010 2.46E-03 5.63E-04 2.46E-03

1,4-Dichlorobenzene PER 010 2.11E-03 4.82E-04 2.11E-03

Formaldehyde PER 010 1.32E-01 3.00E-02 1.32E-01

Hexane PER 010 3.17E+00 7.24E-01 3.17E+00

Naphthalene PER 010 1.07E-03 2.45E-04 1.07E-03

HAPs - Total PER 010 3.32E+00 7.59E-01 3.32E+00

Mercury Compounds PER 010 4.58E-04 1.05E-04 4.58E-04

Toluene PER 010 5.99E-03 1.37E-03 5.99E-03

Manganese compounds PER 010 6.69E-04 1.53E-04 6.69E-04

Nitrous Oxide PER 010 2.38E+00 5.42E-01 2.38E+00

Nickel compounds PER 010 3.70E-03 8.44E-04 3.70E-03

Nitrogen Oxides PER 010 1.65E+01 1.85E+01 8.08E+01

PM < 2.5 micron PER 010 1.34E+01 3.05E+00 1.34E+01

Lead PER 010 8.80E-04 2.01E-04 8.80E-04

PM < 10 micron PER 010 1.34E+01 3.05E+00 1.34E+01

Polycyclic organic matter PER 010 1.55E-04 3.55E-05 1.55E-04

Total Particulate Matter PER 010 1.34E+01 3.05E+00 1.34E+01

Selenium compounds PER 010 4.23E-05 9.65E-06 4.23E-05

Sulfur Dioxide PER 010 2.52E+01 1.73E+01 4.10E+01

Volatile Organic Compounds PER 010 9.68E+00 2.21E+00 9.68E+00

EU 213

Benzene PER 009 4.30E-03 9.78E-04 4.28E-03

A rsenic compounds PER 009 4.08E-04 9.31E-05 4.08E-04

Beryllium Compounds PER 009 2.45E-05 5.59E-06 2.45E-05

Carbon Dioxide Equivalent PER 010 2.57E+05 5.87E+04 2.57E+05

Cadmium compounds PER 009 2.24E-03 5.12E-04 2.24E-03

Methane PER 010 1.38E+01 3.14E+00 1.38E+01

Carbon Monoxide PER 001 2.08E+01 4.75E+00 2.08E+01

Carbon Dioxide PER 010 2.56E+05 5.84E+04 2.56E+05

Cobalt compounds PER 009 1.71E-04 3.91E-05 1.71E-04

Chromium compounds PER 009 2.86E-03 6.52E-04 2.86E-03

1,4-Dichlorobenzene PER 009 2.45E-03 5.59E-04 2.45E-03

Page 44 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 213

Formaldehyde PER 009 1.53E-01 3.49E-02 1.53E-01

Hexane PER 009 3.67E+00 8.38E-01 3.67E+00

Naphthalene PER 009 1.24E-03 2.84E-04 1.24E-03

HAPs - Total PER 009 3.85E+00 8.79E-01 3.85E+00

Mercury Compounds PER 009 5.30E-04 1.21E-04 5.30E-04

Toluene PER 009 6.94E-03 1.58E-03 6.94E-03

Manganese compounds PER 009 7.75E-04 1.77E-04 7.75E-04

Nitrous Oxide PER 010 2.75E+00 6.28E-01 2.75E+00

Nickel compounds PER 009 4.28E-03 9.78E-04 4.28E-03

Nitrogen Oxides PER 009 7.49E+01 2.00E+01 7.49E+01

PM < 2.5 micron PER 009 1.55E+01 3.54E+00 1.55E+01

Lead PER 009 1.02E-03 2.33E-04 1.02E-03

PM < 10 micron PER 009 1.55E+01 3.54E+00 1.55E+01

Polycyclic organic matter PER 009 1.80E-04 4.11E-05 1.80E-04

Total Particulate Matter PER 001 1.55E+01 3.54E+00 1.55E+01

Selenium compounds PER 009 4.90E-05 1.12E-05 4.90E-05

Sulfur Dioxide PER 009 1.61E+02 3.67E+01 1.61E+02

Volatile Organic Compounds PER 009 3.54E+00 8.08E-01 3.54E+00

EU 228

A rsenic compounds PER 009 1.05E-03 8.00E-04 3.50E-03

Beryllium Compounds PER 009 1.71E-04 1.30E-04 5.69E-04

Carbonyl sulfide PER 001 3.42E-01 7.80E-02 3.42E-01

Carbon Dioxide Equivalent PER 010 1.17E+06 2.66E+05 1.17E+06

Chlorine PER 009 2.26E-02 1.72E-02 7.53E-02

Methane PER 009 4.03E+01 9.20E+00 4.03E+01

Cyanide compounds PER 001 1.51E+01 3.44E+00 1.51E+01

Carbon Monoxide PER 001 6.00E+01 5.37E+02 2.35E+03

Carbon Dioxide PER 010 1.16E+06 2.65E+05 1.16E+06

Cobalt compounds PER 009 1.45E-02 1.10E-02 4.82E-02

Chromium compounds PER 009 2.42E-01 1.84E-01 8.06E-01

Hydrogen Sulfide PER 009 1.42E+00 3.25E-01 1.42E+00

HAPs - Total PER 009 1.74E+01 4.26E+00 1.87E+01

Mercury Compounds PER 009 2.63E-03 2.00E-03 8.76E-03

Manganese compounds PER 009 1.29E-01 9.80E-02 4.29E-01

Benzo(a)pyrene PER 009 5.47E-04 1.25E-04 5.47E-04

Nitrous Oxide PER 009 8.06E+00 1.84E+00 8.06E+00

Nickel compounds PER 009 1.12E-01 8.50E-02 3.72E-01

Nitrogen Oxides PER 009 5.00E+02 8.59E+02 3.76E+03

PM < 2.5 micron PER 009 2.63E+02 2.00E+02 8.77E+02

Lead PER 009 1.58E-02 1.20E-02 5.26E-02

PM < 10 micron PER 009 1.85E+00 4.23E-01 1.85E+00

Polycyclic organic matter PER 009 4.60E-03 1.05E-03 4.60E-03

Total Particulate Matter PER 009 1.69E+02 2.00E+02 8.77E+02

A ntimony compounds PER 009 5.12E-04 3.90E-04 1.71E-03

Selenium compounds PER 009 5.39E-03 4.10E-03 1.80E-02

Sulfur Dioxide PER 001 8.00E+02 1.50E+03 6.57E+03

Page 45 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 228

Volatile Organic Compounds PER 001 1.31E+01 3.00E+00 1.31E+01

EU 240

Benzene PER 009 8.12E-05 1.85E-05 8.12E-05

A rsenic compounds PER 009 7.73E-06 1.76E-06 7.73E-06

Beryllium Compounds PER 009 4.64E-07 1.06E-07 4.64E-07

Carbon Dioxide Equivalent PER 010 4.87E+03 1.11E+03 4.87E+03

Cadmium compounds PER 009 4.25E-05 9.71E-06 4.25E-05

Methane PER 009 2.61E-01 5.95E-02 2.61E-01

Carbon Monoxide PER 009 3.25E+00 7.42E-01 3.25E+00

Carbon Dioxide PER 010 4.85E+03 1.11E+03 4.85E+03

Cobalt compounds PER 009 3.25E-06 7.41E-07 3.25E-06

Chromium compounds PER 009 5.41E-05 1.24E-05 5.41E-05

1,4-Dichlorobenzene PER 009 4.64E-05 1.06E-05 4.64E-05

Formaldehyde PER 009 2.90E-03 6.62E-04 2.90E-03

Hexane PER 009 6.96E-02 1.59E-02 6.96E-02

Naphthalene PER 009 2.36E-05 5.38E-06 2.36E-05

HAPs - Total PER 009 7.29E-02 1.67E-02 7.29E-02

Mercury Compounds PER 009 1.00E-05 2.29E-06 1.00E-05

Toluene PER 009 1.31E-04 3.00E-05 1.31E-04

Manganese compounds PER 009 1.47E-05 3.35E-06 1.47E-05

Nitrous Oxide PER 009 5.21E-02 1.19E-02 5.21E-02

Nickel compounds PER 009 8.12E-05 1.85E-05 8.12E-05

Nitrogen Oxides PER 001 1.08E+01 2.48E+00 1.08E+01

PM < 2.5 micron PER 009 2.94E-01 6.71E-02 2.94E-01

Lead PER 009 1.93E-05 4.41E-06 1.93E-05

PM < 10 micron PER 009 2.94E-01 6.71E-02 2.94E-01

Polycyclic organic matter PER 009 3.41E-06 7.78E-07 3.41E-06

Total Particulate Matter PER 009 2.94E-01 6.71E-02 2.94E-01

Selenium compounds PER 009 9.28E-07 2.12E-07 9.28E-07

Sulfur Dioxide PER 009 3.04E+00 6.95E-01 3.04E+00

Volatile Organic Compounds PER 009 2.12E-01 4.85E-02 2.12E-01

EU 241

Benzene PER 009 1.35E-03 3.09E-04 1.35E-03

A rsenic compounds PER 009 1.29E-04 2.94E-05 1.29E-04

Beryllium Compounds PER 009 7.72E-06 1.76E-06 7.72E-06

Carbon Dioxide Equivalent PER 010 8.11E+04 1.85E+04 8.11E+04

Cadmium compounds PER 009 7.08E-04 1.62E-04 7.08E-04

Methane PER 009 4.34E+00 9.91E-01 4.34E+00

Carbon Monoxide PER 009 5.41E+01 1.24E+01 5.41E+01

Carbon Dioxide PER 010 8.08E+04 1.84E+04 8.08E+04

Cobalt compounds PER 009 5.41E-05 1.23E-05 5.41E-05

Chromium compounds PER 009 9.01E-04 2.06E-04 9.01E-04

1,4-Dichlorobenzene PER 009 7.72E-04 1.76E-04 7.72E-04

Formaldehyde PER 009 4.83E-02 1.10E-02 4.83E-02

Hexane PER 009 1.16E+00 2.65E-01 1.16E+00

Naphthalene PER 009 3.93E-04 8.96E-05 3.93E-04

Page 46 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 241

HAPs - Total PER 009 1.21E+00 2.77E-01 1.21E+00

Mercury Compounds PER 009 1.67E-04 3.82E-05 1.67E-04

Toluene PER 009 2.19E-03 5.00E-04 2.19E-03

Manganese compounds PER 009 2.45E-04 5.58E-05 2.45E-04

Nitrous Oxide PER 009 8.68E-01 1.98E-01 8.68E-01

Nickel compounds PER 009 1.35E-03 3.09E-04 1.35E-03

Nitrogen Oxides PER 009 1.81E+02 4.12E+01 1.81E+02

PM < 2.5 micron PER 009 4.89E+00 1.12E+00 4.89E+00

Lead PER 009 3.22E-04 7.35E-05 3.22E-04

PM < 10 micron PER 009 4.89E+00 1.12E+00 4.89E+00

Polycyclic organic matter PER 009 5.68E-05 1.30E-05 5.68E-05

Total Particulate Matter PER 009 4.89E+00 1.12E+00 4.89E+00

Selenium compounds PER 009 1.54E-05 3.53E-06 1.54E-05

Sulfur Dioxide PER 009 5.07E+01 1.16E+01 5.07E+01

Volatile Organic Compounds PER 009 3.54E+00 8.08E-01 3.54E+00

EU 245

Carbon Dioxide Equivalent PER 010 1.57E+04 3.58E+03 1.57E+04

Carbon Dioxide Equivalent PER 012

Carbon Monoxide PER 001 9.52E+00 2.17E+00 9.52E+00

Carbon Monoxide PER 012

Carbon Dioxide PER 010 1.56E+04 3.56E+03 1.56E+04

Carbon Dioxide PER 012

Nitrogen Oxides PER 001 3.17E+01 7.25E+00 3.17E+01

Nitrogen Oxides PER 012

PM < 2.5 micron PER 009 8.62E-01 1.97E-01 8.62E-01

PM < 2.5 micron PER 012

Lead PER 009 5.67E-05 1.29E-05 5.67E-05

Lead PER 012

PM < 10 micron PER 009 8.62E-01 1.97E-01 8.62E-01

PM < 10 micron PER 012

Total Particulate Matter PER 009 8.62E-01 1.97E-01 8.62E-01

Total Particulate Matter PER 012

Sulfur Dioxide PER 001 1.01E+03 2.30E+02 1.01E+03

Sulfur Dioxide PER 012

Volatile Organic Compounds PER 009 4.99E+00 1.14E+00 4.99E+00

Volatile Organic Compounds PER 012

EU 254

Carbon Dioxide Equivalent PER 009 5.27E+04 1.20E+04 5.27E+04

Methane PER 009 4.94E+00 1.13E+00 4.94E+00

Carbon Dioxide PER 009 5.26E+04 1.20E+04 5.26E+04

Nitrous Oxide PER 009 9.92E-02 2.26E-02 9.92E-02

EU 268

PM < 2.5 micron PER 009 6.49E-03 1.48E-03 6.49E-03

PM < 10 micron PER 009 1.45E+00 3.32E-01 1.45E+00

Total Particulate Matter PER 009 3.09E+00 7.06E-01 3.09E+00

Volatile Organic Compounds PER 009 7.41E+00 1.69E+00 7.41E+00

Page 47 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 269

PM < 2.5 micron PER 009 7.70E-03 1.76E-03 7.70E-03

PM < 10 micron PER 009 1.72E+00 3.93E-01 1.72E+00

Total Particulate Matter PER 009 3.67E+00 8.37E-01 3.67E+00

Volatile Organic Compounds PER 009 8.79E+00 2.01E+00 8.79E+00

EU 270

PM < 2.5 micron PER 009 5.99E-03 1.37E-03 5.99E-03

PM < 10 micron PER 009 1.34E+00 3.06E-01 1.34E+00

Total Particulate Matter PER 009 2.85E+00 6.52E-01 2.85E+00

Volatile Organic Compounds PER 009 6.84E+00 1.56E+00 6.84E+00

EU 271

PM < 2.5 micron PER 009 5.99E-03 1.37E-03 5.99E-03

PM < 10 micron PER 009 1.34E+00 3.06E-01 1.34E+00

Total Particulate Matter PER 009 2.85E+00 6.52E-01 2.85E+00

Volatile Organic Compounds PER 009 6.84E+00 1.56E+00 6.84E+00

EU 272

PM < 2.5 micron PER 010 8.90E-03 2.03E-03 8.90E-03

PM < 10 micron PER 010 1.99E+00 4.55E-01 1.99E+00

Total Particulate Matter PER 010 4.24E+00 9.68E-01 4.24E+00

Volatile Organic Compounds PER 010 1.20E+01 2.73E+00 1.20E+01

EU 274

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 275

Carbon Monoxide PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

EU 276

Benzene PER 009 4.08E+00 1.86E+01 8.16E+01

Carbon Dioxide Equivalent PER 009 6.98E+03 1.59E+03 6.98E+03

Methane PER 009 7.28E+00 1.66E+00 7.28E+00

Carbon Monoxide PER 009 2.60E+00 5.93E-01 2.60E+00

Carbon Dioxide PER 009 6.83E+03 1.56E+03 6.83E+03

Ethylbenzene PER 009 2.04E+00 9.32E+00 4.08E+01

HAPs - Total PER 009 3.06E+01 1.40E+02 6.12E+02

Toluene PER 009 6.12E+00 2.79E+01 1.22E+02

Xylenes (mixed isomers) PER 009 1.84E+01 8.38E+01 3.67E+02

Page 48 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 276

Nitrous Oxide PER 009 1.29E-02 2.94E-03 1.29E-02

Nitrogen Oxides PER 001 8.66E+00 1.98E+00 8.66E+00

PM < 2.5 micron PER 009 2.35E-01 5.36E-02 2.35E-01

Lead PER 009 1.55E-05 3.53E-06 1.55E-05

PM < 10 micron PER 009 2.35E-01 5.36E-02 2.35E-01

Total Particulate Matter PER 009 2.35E-01 5.36E-02 2.35E-01

Sulfur Dioxide PER 009 2.07E-02 4.73E-03 2.07E-02

Volatile Organic Compounds PER 009 2.94E+02 1.34E+03 5.88E+03

EU 277

Benzene PER 009 2.53E+00 1.16E+01 5.06E+01

Carbon Dioxide Equivalent PER 009 4.77E+03 1.09E+03 4.77E+03

Methane PER 009 2.43E+00 5.54E-01 2.43E+00

Carbon Monoxide PER 009 2.60E+00 5.93E-01 2.60E+00

Carbon Dioxide PER 009 4.71E+03 1.08E+03 4.71E+03

Ethylbenzene PER 009 2.53E+00 1.16E+01 5.06E+01

HAPs - Total PER 009 2.15E+01 9.85E+01 4.30E+02

Toluene PER 009 5.06E+00 2.31E+01 1.01E+02

Xylenes (mixed isomers) PER 009 1.14E+01 5.20E+01 2.28E+02

Nitrous Oxide PER 009 8.89E-03 2.03E-03 8.89E-03

Nitrogen Oxides PER 001 8.66E+00 1.98E+00 8.66E+00

PM < 2.5 micron PER 009 2.35E-01 5.36E-02 2.35E-01

Lead PER 009 1.55E-05 3.53E-06 1.55E-05

PM < 10 micron PER 009 2.35E-01 5.36E-02 2.35E-01

Total Particulate Matter PER 009 2.35E-01 5.36E-02 2.35E-01

Sulfur Dioxide PER 009 2.07E-02 4.73E-03 2.07E-02

Volatile Organic Compounds PER 009 6.22E+01 2.83E+02 1.24E+03

EU 282

Benzene PER 009 1.36E+00 3.11E-01 1.36E+00

Biphenyl PER 009 3.35E-03 7.64E-04 3.35E-03

Carbon Monoxide PER 009 2.63E+01 8.24E+00 2.63E+01

Cobalt compounds PER 009

Formaldehyde PER 009 2.73E-01 6.22E-02 2.73E-01

Naphthalene PER 009 6.39E-04 1.46E-04 6.39E-04

HAPs - Total PER 009 2.66E+00 6.08E-01 2.66E+00

Toluene PER 009 6.74E-01 1.54E-01 6.74E-01

Fluoranthene PER 009 3.64E-03 8.30E-04 3.64E-03

Nitrogen Oxides PER 009 8.77E+01 2.75E+01 8.77E+01

PM < 2.5 micron PER 009 2.38E+00 7.45E-01 2.38E+00

Lead PER 009 1.56E-04 4.90E-05 1.56E-04

PM < 10 micron PER 009 2.38E+00 7.45E-01 2.38E+00

Total Particulate Matter PER 009 2.38E+00 7.45E-01 2.38E+00

Sulfur Dioxide PER 009 3.80E+01 5.07E+01 2.22E+02

Volatile Organic Compounds PER 001 1.50E+01 3.42E+00 1.50E+01

EU 294

Benzene PER 009 2.17E-03 4.96E-04 2.17E-03

A rsenic compounds PER 009 2.07E-04 4.73E-05 2.07E-04

Page 49 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 294

Beryllium Compounds PER 009 1.24E-05 2.84E-06 1.24E-05

Carbon Dioxide Equivalent PER 010 1.30E+05 2.98E+04 1.30E+05

Cadmium compounds PER 009 1.14E-03 2.60E-04 1.14E-03

Methane PER 009 6.98E+00 1.59E+00 6.98E+00

Carbon Monoxide PER 009 8.69E+01 1.98E+01 8.69E+01

Carbon Dioxide PER 010 1.30E+05 2.96E+04 1.30E+05

Cobalt compounds PER 009 8.69E-05 1.98E-05 8.69E-05

Chromium compounds PER 009 1.45E-03 3.31E-04 1.45E-03

1,4-Dichlorobenzene PER 009 1.24E-03 2.84E-04 1.24E-03

Formaldehyde PER 009 7.76E-02 1.77E-02 7.76E-02

Hexane PER 009 1.86E+00 4.25E-01 1.86E+00

Naphthalene PER 009 6.31E-04 1.44E-04 6.31E-04

HAPs - Total PER 009 1.95E+00 4.46E-01 1.95E+00

Mercury Compounds PER 009 2.69E-04 6.14E-05 2.69E-04

Toluene PER 009 3.52E-03 8.03E-04 3.52E-03

Manganese compounds PER 009 3.93E-04 8.98E-05 3.93E-04

Nitrous Oxide PER 009 1.40E+00 3.19E-01 1.40E+00

Nickel compounds PER 009 2.17E-03 4.96E-04 2.17E-03

Nitrogen Oxides PER 009 4.75E+01 1.08E+01 4.75E+01

PM < 2.5 micron PER 009 7.87E+00 1.80E+00 7.87E+00

Lead PER 009 5.17E-04 1.18E-04 5.17E-04

PM < 10 micron PER 009 7.87E+00 1.80E+00 7.87E+00

Polycyclic organic matter PER 009 9.13E-05 2.08E-05 9.13E-05

Total Particulate Matter PER 009 7.87E+00 1.80E+00 7.87E+00

Selenium compounds PER 009 2.48E-05 5.67E-06 2.48E-05

Sulfur Dioxide PER 009 8.15E+01 1.86E+01 8.15E+01

Volatile Organic Compounds PER 009 5.69E+00 1.30E+00 5.69E+00

EU 296

Benzene PER 009 8.12E-03 1.85E-03 8.12E-03

A rsenic compounds PER 009 7.73E-04 1.76E-04 7.73E-04

Beryllium Compounds PER 009 4.64E-05 1.06E-05 4.64E-05

Carbon Dioxide Equivalent PER 010 4.87E+05 1.11E+05 4.87E+05

Cadmium compounds PER 009 4.25E-03 9.71E-04 4.25E-03

Methane PER 009 2.61E+01 5.95E+00 2.61E+01

Carbon Monoxide PER 009 3.25E+02 7.41E+01 3.25E+02

Carbon Dioxide PER 010 4.85E+05 1.11E+05 4.85E+05

Cobalt compounds PER 009 3.25E-04 7.41E-05 3.25E-04

Chromium compounds PER 009 5.41E-03 1.24E-03 5.41E-03

1,4-Dichlorobenzene PER 009 4.64E-03 1.06E-03 4.64E-03

Formaldehyde PER 009 2.90E-01 6.62E-02 2.90E-01

Hexane PER 009 6.96E+00 1.59E+00 6.96E+00

Naphthalene PER 009 2.36E-03 5.38E-04 2.36E-03

HAPs - Total PER 009 7.29E+00 1.67E+00 7.29E+00

Mercury Compounds PER 009 1.00E-03 2.29E-04 1.00E-03

Toluene PER 009 1.31E-02 3.00E-03 1.31E-02

Manganese compounds PER 009 1.47E-03 3.35E-04 1.47E-03

Page 50 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 296

Nitrous Oxide PER 009 5.21E+00 1.19E+00 5.21E+00

Nickel compounds PER 009 8.12E-03 1.85E-03 8.12E-03

Nitrogen Oxides PER 009 1.58E+02 4.05E+01 1.77E+02

PM < 2.5 micron PER 009 2.94E+01 6.71E+00 2.94E+01

Lead PER 009 1.93E-03 4.41E-04 1.93E-03

PM < 10 micron PER 009 2.94E+01 6.71E+00 2.94E+01

Polycyclic organic matter PER 009 3.41E-04 7.78E-05 3.41E-04

Total Particulate Matter PER 009 2.94E+01 6.71E+00 2.94E+01

Selenium compounds PER 009 9.28E-05 2.12E-05 9.28E-05

Sulfur Dioxide PER 009 3.04E+02 6.95E+01 3.04E+02

Volatile Organic Compounds PER 009 2.13E+01 4.85E+00 2.13E+01

EU 301

Carbon Dioxide Equivalent PER 009 1.30E+03 2.97E+02 1.30E+03

Methane PER 009 2.45E-02 5.60E-03 2.45E-02

Carbon Monoxide PER 009 9.17E-01 2.09E-01 9.17E-01

Carbon Dioxide PER 009 1.30E+03 2.97E+02 1.30E+03

Nitrous Oxide PER 009 2.45E-03 5.60E-04 2.45E-03

Nitrogen Oxides PER 009 1.09E+00 2.49E-01 1.09E+00

PM < 2.5 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Lead PER 009 5.46E-06 1.25E-06 5.46E-06

PM < 10 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Total Particulate Matter PER 009 8.30E-02 1.89E-02 8.30E-02

Sulfur Dioxide PER 009 7.31E-03 1.67E-03 7.31E-03

Volatile Organic Compounds PER 009 6.00E-02 1.37E-02 6.00E-02

EU 302

Carbon Dioxide Equivalent PER 009 1.30E+03 2.97E+02 1.30E+03

Methane PER 009 2.45E-02 5.60E-03 2.45E-02

Carbon Monoxide PER 009 9.17E-01 2.09E-01 9.17E-01

Carbon Dioxide PER 009 1.30E+03 2.97E+02 1.30E+03

Nitrous Oxide PER 009 2.45E-03 5.60E-04 2.45E-03

Nitrogen Oxides PER 009 1.09E+00 2.49E-01 1.09E+00

PM < 2.5 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Lead PER 009 5.46E-06 1.25E-06 5.46E-06

PM < 10 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Total Particulate Matter PER 009 8.30E-02 1.89E-02 8.30E-02

Sulfur Dioxide PER 009 7.31E-03 1.67E-03 7.31E-03

Volatile Organic Compounds PER 009 6.00E-02 1.37E-02 6.00E-02

EU 303

Carbon Dioxide Equivalent PER 009 1.30E+03 2.97E+02 1.30E+03

Methane PER 009 2.45E-02 5.60E-03 2.45E-02

Carbon Monoxide PER 009 9.17E-01 2.09E-01 9.17E-01

Carbon Dioxide PER 009 1.30E+03 2.97E+02 1.30E+03

Nitrous Oxide PER 009 2.45E-03 5.60E-04 2.45E-03

Nitrogen Oxides PER 009 1.09E+00 2.49E-01 1.09E+00

PM < 2.5 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Lead PER 009 5.46E-06 1.25E-06 5.46E-06

Page 51 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 303

PM < 10 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Total Particulate Matter PER 009 8.30E-02 1.89E-02 8.30E-02

Sulfur Dioxide PER 009 7.31E-03 1.67E-03 7.31E-03

Volatile Organic Compounds PER 009 6.00E-02 1.37E-02 6.00E-02

EU 304

Carbon Dioxide Equivalent PER 009 1.30E+03 2.97E+02 1.30E+03

Methane PER 009 2.45E-02 5.60E-03 2.45E-02

Carbon Monoxide PER 009 9.17E-01 2.09E-01 9.17E-01

Carbon Dioxide PER 009 1.30E+03 2.97E+02 1.30E+03

Nitrous Oxide PER 009 2.45E-03 5.60E-04 2.45E-03

Nitrogen Oxides PER 001 1.09E+00 2.49E-01 1.09E+00

PM < 2.5 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Lead PER 009 5.46E-06 1.25E-06 5.46E-06

PM < 10 micron PER 009 8.30E-02 1.89E-02 8.30E-02

Total Particulate Matter PER 009 8.30E-02 1.89E-02 8.30E-02

Sulfur Dioxide PER 009 7.31E-03 1.67E-03 7.31E-03

Volatile Organic Compounds PER 001 6.00E-02 1.37E-02 6.00E-02

EU 312

A cetaldehyde PER 009 9.56E-04 2.18E-04 9.56E-04

A crolein PER 009 2.99E-04 6.83E-05 2.99E-04

Benzene PER 009 2.94E-02 6.72E-03 2.94E-02

A rsenic compounds PER 009 1.59E-04 3.64E-05 1.59E-04

Beryllium Compounds PER 009 9.49E-05 2.17E-05 9.49E-05

Carbon Dioxide Equivalent PER 009 7.09E+02 1.42E+03 6.21E+03

Cadmium compounds PER 009 4.17E-04 9.53E-05 4.17E-04

Methane PER 009 2.86E-02 5.73E-02 2.51E-01

Carbon Monoxide PER 009 2.78E+01 6.35E+00 2.78E+01

Carbon Dioxide PER 009 7.06E+02 1.41E+03 6.19E+03

Chromium compounds PER 009 2.54E-03 5.80E-04 2.54E-03

Formaldehyde PER 009 2.99E-03 6.83E-04 2.99E-03

Naphthalene PER 009 4.93E-03 1.13E-03 4.93E-03

HAPs - Total PER 009 6.69E-02 1.53E-02 6.69E-02

Mercury Compounds PER 009 1.14E-04 2.60E-05 1.14E-04

Toluene PER 009 1.07E-02 2.43E-03 1.07E-02

Xylenes (mixed isomers) PER 009 7.32E-03 1.67E-03 7.32E-03

Manganese compounds PER 009 5.31E-04 1.21E-04 5.31E-04

Nitrous Oxide PER 009 5.73E-03 1.15E-02 5.02E-02

Nickel compounds PER 009 6.45E-03 1.47E-03 6.45E-03

Nitrogen Oxides PER 009 1.21E+02 2.77E+01 1.21E+02

PM < 2.5 micron PER 009 3.54E+00 8.09E-01 3.54E+00

PM < 10 micron PER 009 3.54E+00 8.09E-01 3.54E+00

Total Particulate Matter PER 009 3.54E+00 8.09E-01 3.54E+00

Sulfur Dioxide PER 009 2.02E+00 4.60E-01 2.02E+00

Volatile Organic Compounds PER 009 3.24E+00 7.39E-01 3.24E+00

EU 313

Benzene PER 009 2.12E-03 4.84E-04 2.12E-03

Page 52 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 313

A rsenic compounds PER 009 2.02E-04 4.61E-05 2.02E-04

Beryllium Compounds PER 009 1.21E-05 2.76E-06 1.21E-05

Carbon Dioxide Equivalent PER 010 1.40E+05 3.19E+04 1.40E+05

Cadmium compounds PER 009 1.11E-03 2.53E-04 1.11E-03

Methane PER 009 6.81E+00 1.55E+00 6.81E+00

Carbon Monoxide PER 009 4.12E+01 9.40E+00 4.12E+01

Carbon Dioxide PER 010 1.39E+05 3.17E+04 1.39E+05

Cobalt compounds PER 009 8.48E-05 1.94E-05 8.48E-05

Chromium compounds PER 009 1.41E-03 3.23E-04 1.41E-03

1,4-Dichlorobenzene PER 009 1.21E-03 2.76E-04 1.21E-03

Formaldehyde PER 009 7.57E-02 1.73E-02 7.57E-02

Hexane PER 009 1.82E+00 4.15E-01 1.82E+00

Naphthalene PER 009 6.16E-04 1.41E-04 6.16E-04

HAPs - Total PER 009 1.90E+00 4.35E-01 1.90E+00

Mercury Compounds PER 009 2.62E-04 5.99E-05 2.62E-04

Toluene PER 009 3.43E-03 7.83E-04 3.43E-03

Manganese compounds PER 009 3.83E-04 8.75E-05 3.83E-04

Nitrous Oxide PER 009 1.36E+00 3.11E-01 1.36E+00

Nickel compounds PER 009 2.12E-03 4.84E-04 2.12E-03

Nitrogen Oxides PER 009 4.63E+01 1.06E+01 4.63E+01

PM < 2.5 micron PER 009 7.67E+00 1.75E+00 7.67E+00

Lead PER 009 5.05E-04 1.15E-04 5.05E-04

PM < 10 micron PER 009 7.67E+00 1.75E+00 7.67E+00

Polycyclic organic matter PER 009 8.90E-05 2.03E-05 8.90E-05

Total Particulate Matter PER 009 7.67E+00 1.75E+00 7.67E+00

Selenium compounds PER 009 2.42E-05 5.53E-06 2.42E-05

Sulfur Dioxide PER 009 1.31E+01 9.94E+00 1.31E+01

Volatile Organic Compounds PER 009 5.55E+00 1.27E+00 5.55E+00

EU 324

Benzene PER 009 1.47E-03 3.36E-04 1.47E-03

A rsenic compounds PER 009 1.40E-04 3.20E-05 1.40E-04

Beryllium Compounds PER 009 8.40E-06 1.92E-06 8.40E-06

Carbon Dioxide Equivalent PER 010 8.82E+04 2.01E+04 8.82E+04

Cadmium compounds PER 009 7.70E-04 1.76E-04 7.70E-04

Methane PER 009 4.72E+00 1.08E+00 4.72E+00

Carbon Monoxide PER 009 7.10E+00 1.63E+01 7.14E+01

Carbon Dioxide PER 010 8.78E+04 2.00E+04 8.78E+04

Cobalt compounds PER 009 5.88E-05 1.34E-05 5.88E-05

Chromium compounds PER 009 9.80E-04 2.24E-04 9.80E-04

1,4-Dichlorobenzene PER 009 8.40E-04 1.92E-04 8.40E-04

Formaldehyde PER 009 5.25E-02 1.20E-02 5.25E-02

Hexane PER 009 1.26E+00 2.88E-01 1.26E+00

Naphthalene PER 009 4.24E-04 9.75E-05 4.24E-04

HAPs - Total PER 009 1.32E+00 3.02E-01 1.32E+00

Mercury Compounds PER 009 1.82E-04 4.15E-05 1.82E-04

Toluene PER 009 2.38E-03 5.43E-04 2.38E-03

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 324

Manganese compounds PER 009 2.66E-04 6.07E-05 2.66E-04

Nitrous Oxide PER 009 9.44E-01 2.16E-01 9.44E-01

Nickel compounds PER 009 1.47E-03 3.36E-04 1.47E-03

Nitrogen Oxides PER 009 3.21E+01 7.34E+00 3.21E+01

PM < 2.5 micron PER 009 5.32E+00 1.21E+00 5.32E+00

Lead PER 009 3.50E-04 7.99E-05 3.50E-04

PM < 10 micron PER 009 5.32E+00 1.21E+00 5.32E+00

Polycyclic organic matter PER 009 6.17E-05 1.41E-05 6.17E-05

Total Particulate Matter PER 009 5.32E+00 1.21E+00 5.32E+00

Selenium compounds PER 009 1.68E-05 3.84E-06 1.68E-05

Sulfur Dioxide PER 009 5.51E+01 1.26E+01 5.51E+01

Volatile Organic Compounds PER 009 3.85E+00 8.79E-01 3.85E+00

EU 325

PM < 2.5 micron PER 008 1.97E+00 9.00E-01 1.97E+00

PM < 10 micron PER 008 1.97E+00 9.00E-01 1.97E+00

Total Particulate Matter PER 008 6.57E+00 3.00E+00 6.57E+00

EU 326

PM < 2.5 micron PER 008 1.31E+00 6.00E-01 1.31E+00

PM < 10 micron PER 008 1.31E+00 6.00E-01 1.31E+00

Total Particulate Matter PER 008 4.38E+00 2.00E+00 4.38E+00

EU 334

Carbon Dioxide Equivalent PER 009 1.91E+03 4.37E+02 1.91E+03

Methane PER 009 9.12E+01 2.08E+01 9.12E+01

Carbon Monoxide PER 009 6.85E-01 1.56E-01 6.85E-01

Hydrogen Sulfide PER 009 8.79E+00 2.01E+00 8.79E+00

PM < 2.5 micron PER 009 6.35E+00 1.45E+00 6.35E+00

PM < 10 micron PER 009 6.35E+00 1.45E+00 6.35E+00

Volatile Organic Compounds PER 009 1.75E+01 3.99E+00 1.75E+01

EU 335

Carbon Dioxide Equivalent PER 009 1.91E+03 4.37E+02 1.91E+03

Methane PER 009 9.12E+01 2.08E+01 9.12E+01

Carbon Monoxide PER 009 6.85E-01 1.56E-01 6.85E-01

Hydrogen Sulfide PER 009 8.79E+00 2.01E+00 8.79E+00

PM < 2.5 micron PER 009 6.35E+00 1.45E+00 6.35E+00

PM < 10 micron PER 009 6.35E+00 1.45E+00 6.35E+00

Volatile Organic Compounds PER 009 1.75E+01 3.99E+00 1.75E+01

EU 336

Carbon Dioxide Equivalent PER 009 3.03E+03 6.93E+02 3.03E+03

Methane PER 009 1.44E+02 3.30E+01 1.44E+02

Carbon Monoxide PER 009 1.09E+00 2.48E-01 1.09E+00

Hydrogen Sulfide PER 009 1.38E+01 3.16E+00 1.38E+01

PM < 2.5 micron PER 009 1.01E+01 2.30E+00 1.01E+01

PM < 10 micron PER 009 1.01E+01 2.30E+00 1.01E+01

Volatile Organic Compounds PER 009 2.75E+01 6.29E+00 2.75E+01

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 337

Carbon Dioxide Equivalent PER 009

Methane PER 009

Carbon Dioxide PER 009

Nitrous Oxide PER 009

EU 347

Volatile Organic Compounds PER 009 4.33E+00 2.38E+00 4.33E+00

EU 348

Carbon Dioxide Equivalent PER 010 2.79E+04 6.37E+03 2.79E+04

Methane PER 009 1.36E+00 3.11E-01 1.36E+00

Carbon Monoxide PER 009 1.70E+01 3.87E+00 1.70E+01

Carbon Dioxide PER 010 2.78E+04 6.35E+03 2.78E+04

Nitrous Oxide PER 009 2.72E-01 6.22E-02 2.72E-01

Nitrogen Oxides PER 009 5.66E+01 1.29E+01 5.66E+01

PM < 2.5 micron PER 009 1.53E+00 3.50E-01 1.53E+00

Lead PER 009 1.01E-03 2.30E-04 1.01E-03

PM < 10 micron PER 009 1.53E+00 3.50E-01 1.53E+00

Total Particulate Matter PER 009 1.53E+00 3.50E-01 1.53E+00

Sulfur Dioxide PER 009 5.15E+00 2.18E+00 5.15E+00

Volatile Organic Compounds PER 009 1.11E+00 2.53E-01 1.11E+00

EU 350

Volatile Organic Compounds PER 010 4.40E+00 2.21E+01

EU 351

Carbon Dioxide Equivalent PER 010 1.69E+03 3.62E+03

Carbon Monoxide PER 010 8.00E-01 5.90E-01

Nitrogen Oxides PER 010 1.00E+00 9.30E-01

PM < 2.5 micron PER 010 6.50E-02 1.50E-02

Lead PER 010 9.83E-06 2.90E-05

PM < 10 micron PER 010 7.30E-02 5.40E-02

Sulfur Dioxide PER 010 2.00E-02 7.90E-02

EU 352

Benzene PER 010 2.38E-03 5.44E-04 2.38E-03

A rsenic compounds PER 010 2.27E-04 5.18E-05 2.27E-04

Beryllium PER 010 1.36E-05 3.11E-06 1.36E-05

Carbon Dioxide Equivalent PER 010 1.36E+05 3.10E+04 1.36E+05

Cadmium compounds PER 010 1.25E-03 2.85E-04 1.25E-03

Methane PER 010 7.65E+00 1.75E+00 7.65E+00

Carbon Monoxide PER 010 1.16E+01 2.64E+00 1.16E+01

Carbon Dioxide PER 010 1.35E+05 3.09E+04 1.35E+05

Cobalt compounds PER 010 9.52E-05 2.17E-05 9.52E-05

Chromium compounds PER 010 1.59E-03 3.62E-04 1.59E-03

1,4-Dichlorobenzene PER 010 1.36E-03 3.11E-04 1.36E-03

Formaldehyde PER 010 8.50E-02 1.94E-02 8.50E-02

Hexane PER 010 2.04E+00 4.66E-01 2.04E+00

Naphthalene PER 010 6.92E-04 1.58E-04 6.92E-04

HAPs - Total PER 010 2.14E+00 4.89E-01 2.14E+00

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 352

Mercury PER 010 2.95E-04 6.73E-05 2.95E-04

Toluene PER 010 3.85E-03 8.80E-04 3.85E-03

Manganese compounds PER 010 4.31E-04 9.84E-05 4.31E-04

Nitrous Oxide PER 010 1.53E+00 3.49E-01 1.53E+00

Nickel compounds PER 010 2.38E-03 5.44E-04 2.38E-03

Nitrogen Oxides PER 010 1.10E+01 1.06E+01 4.63E+01

PM < 2.5 micron PER 010 8.62E+00 1.97E+00 8.62E+00

Lead PER 010 5.67E-04 1.29E-04 5.67E-04

PM < 10 micron PER 010 8.62E+00 1.97E+00 8.62E+00

Polycyclic organic matter PER 010 1.00E-04 2.28E-05 1.00E-04

Total Particulate Matter PER 010 8.62E+00 1.97E+00 8.62E+00

Sulfuric Acid Mist PER 010 8.51E-03 1.94E-03 8.51E-03

Selenium compounds PER 010 2.72E-05 6.21E-06 2.72E-05

Sulfur Dioxide PER 010 1.00E+01 1.22E+01 5.35E+01

Volatile Organic Compounds PER 010 5.78E+00 1.32E+00 5.78E+00

EU 353

Benzene PER 010 2.94E-03 6.71E-04 2.94E-03

A rsenic compounds PER 010 2.80E-04 6.39E-05 2.80E-04

Beryllium PER 010 1.68E-05 3.84E-06 1.68E-05

Carbon Dioxide Equivalent PER 010 1.67E+05 3.81E+04 1.67E+05

Cadmium compounds PER 010 1.54E-03 3.52E-04 1.54E-03

Methane PER 010 3.15E+00 7.19E-01 3.15E+00

Carbon Monoxide PER 010 1.43E+01 3.26E+00 1.43E+01

Carbon Dioxide PER 010 1.67E+05 3.81E+04 1.67E+05

Cobalt compounds PER 010 1.18E-04 2.68E-05 1.18E-04

Chromium compounds PER 010 1.96E-03 4.47E-04 1.96E-03

1,4-Dichlorobenzene PER 010 1.68E-03 3.84E-04 1.68E-03

Formaldehyde PER 010 1.05E-01 2.40E-02 1.05E-01

Hexane PER 010 2.52E+00 5.75E-01 2.52E+00

Naphthalene PER 010 8.54E-04 1.95E-04 8.54E-04

HAPs - Total PER 010 2.64E+00 6.03E-01 2.64E+00

Mercury PER 010 3.64E-04 8.31E-05 3.64E-04

Toluene PER 010 4.76E-03 1.09E-03 4.76E-03

Manganese compounds PER 010 5.32E-04 1.21E-04 5.32E-04

Nitrous Oxide PER 010 3.15E-01 7.19E-02 3.15E-01

Nickel compounds PER 010 2.94E-03 6.71E-04 2.94E-03

Nitrogen Oxides PER 010 1.09E+01 1.30E+01 5.71E+01

PM < 2.5 micron PER 010 1.06E+01 2.43E+00 1.06E+01

Lead PER 010 7.00E-04 1.60E-04 7.00E-04

PM < 10 micron PER 010 1.06E+01 2.43E+00 1.06E+01

Polycyclic organic matter PER 010 1.23E-04 2.82E-05 1.23E-04

Total Particulate Matter PER 010 1.06E+01 2.43E+00 1.06E+01

Sulfuric Acid Mist PER 010 1.05E-02 2.40E-03 1.05E-02

Selenium compounds PER 010 3.36E-05 7.67E-06 3.36E-05

Sulfur Dioxide PER 010 9.38E-01 2.14E-01 9.38E-01

Volatile Organic Compounds PER 010 7.70E+00 1.76E+00 7.70E+00

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 354

PM < 2.5 micron PER 010 3.22E-03 7.36E-04 3.22E-03

PM < 10 micron PER 010 7.21E-01 1.65E-01 7.21E-01

Total Particulate Matter PER 010 1.53E+00 3.50E-01 1.53E+00

Volatile Organic Compounds PER 010 7.36E+00 1.68E+00 7.36E+00

EU 355

A cetaldehyde PER 011 5.24E-04 2.09E-03 5.24E-04

A crolein PER 011 4.94E-04 1.97E-03 4.94E-04

Benzene PER 011 2.97E-04 1.19E-03 2.97E-04

1,3-Butadiene PER 011 1.24E-04 4.98E-04 1.24E-04

Carbon tetrachloride PER 011 3.32E-06 1.33E-05 3.32E-06

Carbon Dioxide Equivalent PER 011 2.61E+01 1.05E+02 2.61E+01

Chlorobenzene PER 011 2.42E-06 9.69E-06 2.42E-06

Chloroform PER 011 2.57E-06 1.03E-05 2.57E-06

Methane PER 011 1.00E-03 5.00E-03 1.00E-03

Carbon Monoxide PER 011 5.08E+00 2.03E+01 5.08E+00

Carbon Dioxide PER 011 2.60E+01 1.04E+02 2.60E+01

1,1-Dichloroethane PER 011 2.12E-06 8.48E-06 2.12E-06

1,2-Dichloroethane PER 011 2.12E-06 8.48E-06 2.12E-06

1,2-Dichloropropane PER 011 2.44E-06 9.76E-06 2.44E-06

1,3-Dichloropropene PER 011 2.38E-06 9.54E-06 2.38E-06

Ethylbenzene PER 011 4.66E-06 1.86E-05 4.66E-06

Formaldehyde PER 011 3.85E-03 1.54E-02 3.85E-03

Methanol PER 011 5.74E-04 2.30E-03 5.74E-04

Naphthalene PER 011 1.82E-05 7.29E-05 1.82E-05

HAPs - Total PER 011 6.09E-03 2.43E-02 6.09E-03

Styrene PER 011 2.23E-06 8.93E-06 2.23E-06

1,1,2,2-Tetrachloroethane PER 011 4.75E-06 1.90E-05 4.75E-06

Toluene PER 011 1.05E-04 4.19E-04 1.05E-04

1,1,2-Trichloroethane PER 011 2.87E-06 1.15E-05 2.87E-06

Vinyl chloride PER 011 1.35E-06 5.39E-06 1.35E-06

Xylenes (mixed isomers) PER 011 3.66E-05 1.46E-04 3.66E-05

Ethylene dibromide (dibromoeth PER 011 4.00E-06 1.60E-05 4.00E-06

Nitrous Oxide PER 011 2.48E-04 9.93E-04 2.48E-04

Methylene chloride (dichlorome PER 011 7.73E-06 3.09E-05 7.73E-06

Total Polycyclic aromatic hydr PER 011 2.65E-05 1.06E-04 2.65E-05

Nitrogen Oxides PER 011 1.60E-01 6.30E-01 1.60E-01

PM < 2.5 micron PER 011 3.60E-03 1.46E-02 3.60E-03

PM < 10 micron PER 011 3.60E-03 1.46E-02 3.60E-03

Total Particulate Matter PER 011 3.60E-03 1.46E-02 3.60E-03

Sulfur Dioxide PER 011 1.10E-04 4.41E-04 1.10E-04

Volatile Organic Compounds PER 011 6.00E-02 2.20E-01 6.00E-02

EU 356

A cetaldehyde PER 011 5.24E-04 2.09E-03 5.24E-04

A crolein PER 011 4.94E-04 1.97E-03 4.94E-04

Benzene PER 011 2.97E-04 1.19E-03 2.97E-04

1,3-Butadiene PER 011 1.24E-04 4.98E-04 1.24E-04

Page 57 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 356

Carbon tetrachloride PER 011 3.32E-06 1.33E-05 3.32E-06

Carbon Dioxide Equivalent PER 011 2.61E+01 1.05E+02 2.61E+01

Chlorobenzene PER 011 2.42E-06 9.69E-06 2.42E-06

Chloroform PER 011 2.57E-06 1.03E-05 2.57E-06

Methane PER 011 1.00E-03 5.00E-03 1.00E-03

Carbon Monoxide PER 011 5.08E+00 2.03E+01 5.08E+00

Carbon Dioxide PER 011 2.60E+01 1.04E+02 2.60E+01

1,1-Dichloroethane PER 011 2.12E-06 8.48E-06 2.12E-06

1,2-Dichloroethane PER 011 2.12E-06 8.48E-06 2.12E-06

1,2-Dichloropropane PER 011 2.44E-06 9.76E-06 2.44E-06

1,3-Dichloropropene PER 011 2.38E-06 9.54E-06 2.38E-06

Ethylbenzene PER 011 4.66E-06 1.86E-05 4.66E-06

Formaldehyde PER 011 3.85E-03 1.54E-02 3.85E-03

Methanol PER 011 5.74E-04 2.30E-03 5.74E-04

Naphthalene PER 011 1.82E-05 7.29E-05 1.82E-05

HAPs - Total PER 011 6.09E-03 2.43E-02 6.09E-03

Styrene PER 011 2.23E-06 8.93E-06 2.23E-06

1,1,2,2-Tetrachloroethane PER 011 4.75E-06 1.90E-05 4.75E-06

Toluene PER 011 1.05E-04 4.19E-04 1.05E-04

1,1,2-Trichloroethane PER 011 2.87E-06 1.15E-05 2.87E-06

Vinyl chloride PER 011 1.35E-06 5.39E-06 1.35E-06

Xylenes (mixed isomers) PER 011 3.66E-05 1.46E-04 3.66E-05

Ethylene dibromide (dibromoeth PER 011 4.00E-06 1.60E-05 4.00E-06

Nitrous Oxide PER 011 2.48E-04 9.93E-04 2.48E-04

Methylene chloride (dichlorome PER 011 7.73E-06 3.09E-05 7.73E-06

Total Polycyclic aromatic hydr PER 011 2.65E-05 1.06E-04 2.65E-05

Nitrogen Oxides PER 011 1.60E-01 6.30E-01 1.60E-01

PM < 2.5 micron PER 011 3.60E-03 1.46E-02 3.60E-03

PM < 10 micron PER 011 3.60E-03 1.46E-02 3.60E-03

Total Particulate Matter PER 011 3.60E-03 1.46E-02 3.60E-03

Sulfur Dioxide PER 011 1.10E-04 4.41E-04 1.10E-04

Volatile Organic Compounds PER 011 6.00E-02 2.20E-01 6.00E-02

EU 357

A cetaldehyde PER 011 1.35E-03 5.41E-03 1.35E-03

A crolein PER 011 1.28E-03 5.10E-03 1.28E-03

Benzene PER 011 7.66E-04 3.07E-03 7.66E-04

1,3-Butadiene PER 011 3.22E-04 1.29E-03 3.22E-04

Carbon tetrachloride PER 011 8.59E-06 3.43E-05 8.59E-06

Carbon Dioxide Equivalent PER 011 6.75E+01 2.70E+02 6.75E+01

Chlorobenzene PER 011 6.26E-06 2.50E-05 6.26E-06

Chloroform PER 011 6.65E-06 2.66E-05 6.65E-06

Methane PER 011 3.00E-03 1.30E-02 3.00E-03

Carbon Monoxide PER 011 2.20E-01 8.78E-01 8.81E+00

Carbon Dioxide PER 011 6.72E+01 2.69E+02 6.72E+01

1,1-Dichloroethane PER 011 5.48E-06 2.19E-05 5.48E-06

1,2-Dichloroethane PER 011 5.48E-06 2.19E-05 5.48E-06

Page 58 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 357

1,2-Dichloropropane PER 011 6.31E-06 2.52E-05 6.31E-06

1,3-Dichloropropene PER 011 6.16E-06 2.46E-05 6.16E-06

Ethylbenzene PER 011 1.20E-05 4.81E-05 1.20E-05

Formaldehyde PER 011 9.94E-03 3.98E-02 9.94E-03

Methanol PER 011 1.48E-03 5.94E-03 1.48E-03

Naphthalene PER 011 4.71E-05 1.88E-04 4.71E-05

HAPs - Total PER 011 1.57E-02 6.29E-02 1.57E-02

Styrene PER 011 5.77E-06 2.31E-05 5.77E-06

1,1,2,2-Tetrachloroethane PER 011 1.23E-05 4.91E-05 1.23E-05

Toluene PER 011 2.71E-04 1.08E-03 2.71E-04

1,1,2-Trichloroethane PER 011 7.42E-06 2.97E-05 7.42E-06

Vinyl chloride PER 011 3.48E-06 1.39E-05 3.48E-06

Xylenes (mixed isomers) PER 011 9.46E-05 3.78E-04 9.46E-05

Ethylene dibromide (dibromoeth PER 011 1.03E-05 4.13E-05 1.03E-05

Nitrous Oxide PER 011 6.42E-04 2.57E-03 6.42E-04

Methylene chloride (dichlorome PER 011 2.00E-05 7.99E-05 2.00E-05

Total Polycyclic aromatic hydr PER 011 6.84E-05 2.74E-04 6.84E-05

Nitrogen Oxides PER 011 7.61E-02 3.04E-01 7.61E-02

PM < 2.5 micron PER 011 9.40E-03 3.77E-02 9.40E-03

PM < 10 micron PER 011 9.40E-03 3.77E-02 9.40E-03

Total Particulate Matter PER 011 9.40E-03 3.77E-02 9.40E-03

Sulfur Dioxide PER 011 2.85E-04 1.14E-03 2.85E-04

Volatile Organic Compounds PER 011 3.81E-03 1.52E-02 1.00E-01

EU 358

Benzene PER 011 3.61E-04 8.24E-05 3.61E-04

A rsenic compounds PER 011 3.44E-05 7.84E-06 3.44E-05

Barium PER 011 7.56E-04 1.73E-04 7.56E-04

Beryllium PER 011 2.06E-06 4.71E-07 2.06E-06

Carbon Dioxide Equivalent PER 011 2.43E+04 5.56E+03 2.43E+04

Cadmium compounds PER 011 1.89E-04 4.31E-05 1.89E-04

Methane PER 011 1.16E+00 2.60E-01 1.16E+00

Carbon Monoxide PER 011 1.44E+01 3.28E+00 1.44E+01

Carbon Dioxide PER 011 2.42E+04 5.53E+03 2.42E+04

Cobalt compounds PER 011 1.44E-05 3.29E-06 1.44E-05

Chromium compounds PER 011 2.40E-04 5.49E-05 2.40E-04

Copper PER 011 1.46E-04 3.33E-05 1.46E-04

1,4-Dichlorobenzene PER 011 2.06E-04 4.71E-05 2.06E-04

Formaldehyde PER 011 1.29E-02 2.94E-03 1.29E-02

Hexane PER 011 3.09E-01 7.06E-02 3.09E-01

Naphthalene PER 011 1.05E-04 2.39E-05 1.05E-04

HAPs - Total PER 011 3.31E-01 7.55E-02 3.31E-01

Mercury PER 011 4.47E-05 1.02E-05 4.47E-05

Toluene PER 011 5.84E-04 1.33E-04 5.84E-04

7,12-Dimethylbenz(a)anthracen e PER 011 2.75E-06 6.27E-07 2.75E-06

3-Methylchloranthrene PER 011 3.09E-07 7.06E-08 3.09E-07

2-Methylnaphthalene PER 011 4.12E-06 9.41E-07 4.12E-06

Page 59 of 70MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 358

Manganese compounds PER 011 6.53E-05 1.49E-05 6.53E-05

Molybdenum PER 011 1.89E-04 4.31E-05 1.89E-04

A cenaphthene PER 011 3.09E-07 7.06E-08 3.09E-07

A cenaphthylene PER 011 3.09E-07 7.06E-08 3.09E-07

A nthracene PER 011 4.12E-07 9.41E-08 4.12E-07

Benz(a)anthracene PER 011 3.09E-07 7.06E-08 3.09E-07

Benzo(a)pyrene PER 011 2.06E-07 4.71E-08 2.06E-07

Benzo(b)fluoranthene PER 011 3.09E-07 7.06E-08 3.09E-07

Benzo(ghi)perylene PER 011 2.06E-07 4.71E-08 2.06E-07

Benzo(k)fluoranthene PER 011 3.09E-07 7.06E-08 3.09E-07

Chrysene PER 011 3.09E-07 7.06E-08 3.09E-07

Dibenz(a,h)anthracene PER 011 2.06E-07 4.71E-08 2.06E-07

Fluoranthene PER 011 5.15E-07 1.18E-07 5.15E-07

Fluorene PER 011 4.81E-07 1.10E-07 4.81E-07

Nitrous Oxide PER 011 2.30E-01 5.00E-02 2.30E-01

Indeno(1,2,3-cd)pyrene PER 011 3.09E-07 7.06E-08 3.09E-07

Phenanthrene PER 011 2.92E-06 6.67E-07 2.92E-06

Pyrene PER 011 8.59E-07 1.96E-07 8.59E-07

Nickel compounds PER 011 3.61E-04 8.24E-05 3.61E-04

Nitrogen Oxides PER 011 2.49E+01 5.68E+00 2.49E+01

PM < 2.5 micron PER 011 1.34E+00 3.10E-01 1.34E+00

Lead PER 011 8.59E-05 1.96E-05 8.59E-05

PM < 10 micron PER 011 1.34E+00 3.10E-01 1.34E+00

Total Particulate Matter PER 011 1.34E+00 3.10E-01 1.34E+00

Selenium compounds PER 011 4.12E-06 9.41E-07 4.12E-06

Sulfur Dioxide PER 011 5.07E+00 1.16E+00 1.32E+02

Volatile Organic Compounds PER 011 1.91E+00 4.40E-01 1.91E+00

Zinc PER 011 4.98E-03 1.14E-03 4.98E-03

EU 359

A cetaldehyde PER 012 3.30E-01 7.60E-02 3.30E-01

A crolein PER 012 6.90E-03 1.60E-03 6.90E-03

Benzene PER 012 6.20E-03 1.40E-03 6.20E-03

A rsenic compounds PER 012 3.70E-04 8.50E-05 3.70E-04

1,3-Butadiene PER 012 8.20E-04 1.90E-04 8.20E-04

Beryllium PER 012 2.20E-05 5.10E-06 2.20E-05

Carbon Dioxide Equivalent PER 012 2.23E+05 5.08E+04 2.23E+05

Cadmium compounds PER 012 2.10E-03 4.70E-04 2.10E-03

Methane PER 012 4.20E+00 9.60E-01 4.20E+00

Carbon Monoxide PER 012 3.79E+01 8.65E+00 1.84E+02

Carbon Dioxide PER 012 2.22E+05 5.08E+04 2.22E+05

Cobalt compounds PER 012 1.60E-04 3.60E-05 1.60E-04

Chromium compounds PER 012 2.60E-03 6.00E-04 2.60E-03

1,4-Dichlorobenzene PER 012 2.20E-03 5.10E-04 2.20E-03

Ethylbenzene PER 012 6.10E-02 1.40E-02 6.10E-02

Formaldehyde PER 012 6.90E-01 1.60E-01 6.90E-01

Hexane PER 012 3.40E+00 7.70E-01 3.40E+00

Page 60 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 359

Naphthalene PER 012 2.50E-03 5.60E-04 2.50E-03

HAPs - Total PER 012 4.90E+00 1.12E+00 4.90E+00

Mercury PER 012 4.90E-04 1.10E-04 4.90E-04

Propylene oxide PER 012 5.50E-02 1.30E-02 5.50E-02

Toluene PER 012 2.50E-01 5.60E-02 2.50E-01

Xylenes (mixed isomers) PER 012 1.20E-01 2.80E-02 1.20E-01

Manganese compounds PER 012 7.10E-04 1.60E-04 7.10E-04

Nitrous Oxide PER 012 4.20E-01 9.58E-02 4.20E-01

Nickel compounds PER 012 3.90E-03 8.90E-04 3.90E-03

Nitrogen Oxides PER 012 1.57E+01 3.58E+00 1.04E+02

PM < 2.5 micron PER 012 1.09E+01 2.48E+00 1.09E+01

Lead PER 012 9.33E-04 2.13E-04 9.33E-04

PM < 10 micron PER 012 1.09E+01 2.48E+00 1.09E+01

Polycyclic organic matter PER 012 4.20E-03 9.60E-04 4.20E-03

Total Particulate Matter PER 012 1.09E+01 2.48E+00 1.09E+01

Selenium compounds PER 012 4.50E-05 1.00E-05 4.50E-05

Sulfur Dioxide PER 012 2.66E+00 6.10E-01 2.66E+00

Volatile Organic Compounds PER 012 1.77E+01 4.05E+00 3.61E+01

EU 360

Benzene PER 012 2.20E-03 4.90E-04 2.20E-03

A rsenic compounds PER 012 2.10E-04 4.70E-05 2.10E-04

Beryllium PER 012 1.20E-05 2.80E-06 1.20E-05

Carbon Dioxide Equivalent PER 012 1.23E+05 2.80E+04 1.23E+05

Cadmium compounds PER 012 1.10E-03 2.60E-04 1.10E-03

Methane PER 012 2.31E+00 5.30E-01 2.31E+00

Carbon Monoxide PER 012 2.90E+01 6.62E+00 8.38E+01

Carbon Dioxide PER 012 1.22E+05 2.79E+04 1.22E+05

Cobalt compounds PER 012 8.60E-05 2.00E-05 8.60E-05

Chromium compounds PER 012 1.40E-03 3.30E-04 1.40E-03

1,4-Dichlorobenzene PER 012 1.20E-03 2.80E-04 1.20E-03

Formaldehyde PER 012 7.70E-02 1.80E-02 7.70E-02

Hexane PER 012 1.80E+00 4.20E-01 1.80E+00

Naphthalene PER 012 6.30E-04 1.40E-04 6.30E-04

HAPs - Total PER 012 1.90E+00 4.30E-01 1.90E+00

Mercury PER 012 2.70E-04 6.10E-05 2.70E-04

Toluene PER 012 3.50E-03 8.00E-04 3.50E-03

Manganese compounds PER 012 3.90E-04 8.90E-05 3.90E-04

Nitrous Oxide PER 012 2.30E-01 5.27E-02 2.30E-01

Nickel compounds PER 012 2.20E-03 4.90E-04 2.20E-03

Nitrogen Oxides PER 012 1.20E+01 2.74E+00 8.38E+01

PM < 2.5 micron PER 012 5.97E+00 1.36E+00 5.97E+00

Lead PER 012 5.13E-04 1.17E-04 5.13E-04

PM < 10 micron PER 012 5.97E+00 1.36E+00 5.97E+00

Polycyclic organic matter PER 012 9.10E-05 2.10E-05 9.10E-05

Total Particulate Matter PER 012 5.97E+00 1.36E+00 5.97E+00

Selenium compounds PER 012 2.50E-05 5.60E-06 2.50E-05

Page 61 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 360

Sulfur Dioxide PER 012 1.47E+00 3.30E-01 1.47E+00

Volatile Organic Compounds PER 012 1.03E+01 2.35E+00 2.10E+01

EU 361

Benzene PER 012 3.95E-04 9.02E-05 3.95E-04

A rsenic compounds PER 012 3.76E-05 8.59E-06 3.76E-05

Beryllium Compounds PER 012 2.26E-06 5.16E-07 2.26E-06

Carbon disulfide PER 012 2.08E+00 4.80E-01 2.08E+00

Carbonyl sulfide PER 012 6.90E-01 1.60E-01 6.90E-01

Carbon Dioxide Equivalent PER 012 3.30E+04 7.53E+03 3.30E+04

Cadmium compounds PER 012 2.07E-04 4.73E-05 2.07E-04

Methane PER 012 4.20E-01 9.66E-02 4.20E-01

Carbon Monoxide PER 012 7.60E+00 1.74E+00 7.60E+00

Carbon Dioxide PER 012 3.30E+04 7.53E+03 3.30E+04

Cobalt compounds PER 012 1.58E-05 3.61E-06 1.58E-05

Chromium compounds PER 012 2.63E-04 6.02E-05 2.63E-04

1,4-Dichlorobenzene PER 012 2.26E-04 5.16E-05 2.26E-04

Formaldehyde PER 012 1.41E-02 3.22E-03 1.41E-02

Hexane PER 012 3.40E-01 7.73E-02 3.40E-01

Hydrogen Sulfide PER 012 1.38E+00 3.10E-01 1.38E+00

Naphthalene PER 012 1.15E-04 2.62E-05 1.15E-04

HAPs - Total PER 012 3.13E+00 7.10E-01 3.13E+00

Mercury Compounds PER 012 4.89E-05 1.12E-05 4.89E-05

Toluene PER 012 6.40E-04 1.46E-04 6.40E-04

Manganese compounds PER 012 7.15E-05 1.63E-05 7.15E-05

Nitrous Oxide PER 012 4.23E-02 9.66E-03 4.23E-02

Lead Compounds PER 012 9.41E-05 2.15E-05 9.41E-05

Nickel compounds PER 012 3.95E-04 9.02E-05 3.95E-04

Nitrogen Oxides PER 012 3.35E+01 7.66E+00 3.35E+01

PM < 2.5 micron PER 012 5.89E+00 1.35E+00 6.55E+00

PM < 10 micron PER 012 5.89E+00 1.35E+00 2.36E+01

Polycyclic organic matter PER 012 1.66E-05 3.79E-06 1.66E-05

Total Particulate Matter PER 012 2.11E+00 4.80E-01 2.11E+01

Selenium compounds PER 012 4.52E-06 1.03E-06 4.52E-06

Sulfur Dioxide PER 012 1.97E+01 5.00E+00 1.97E+01

Volatile Organic Compounds PER 012 1.97E+00 4.50E-01 1.97E+00

EU 362

A cetaldehyde PER 012 5.27E+00 1.20E+00 5.27E+00

A crolein PER 012 1.65E+00 3.76E-01 1.65E+00

Benzene PER 012 1.62E+02 3.71E+01 1.62E+02

A rsenic compounds PER 012 8.79E-01 2.01E-01 8.79E-01

Beryllium Compounds PER 012 5.23E-01 1.19E-01 5.23E-01

Carbon Dioxide Equivalent PER 012 3.91E+03 8.92E+02 3.91E+03

Cadmium compounds PER 012 2.30E+00 5.25E-01 2.30E+00

Methane PER 012 1.58E-01 3.61E-02 1.58E-01

Carbon Monoxide PER 012 2.13E+01 4.86E+00 2.13E+01

Carbon Dioxide PER 012 3.89E+03 8.89E+02 3.89E+03

Page 62 of 70MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

EU 362

Chromium compounds PER 012 1.40E+01 3.20E+00 1.40E+01

Formaldehyde PER 012 1.65E+01 3.77E+00 1.65E+01

Naphthalene PER 012 2.72E+01 6.21E+00 2.72E+01

HAPs - Total PER 012 3.69E+02 8.43E+01 3.69E+02

Mercury Compounds PER 012 6.28E-01 1.43E-01 6.28E-01

Toluene PER 012 5.88E+01 1.34E+01 5.88E+01

Xylenes (mixed isomers) PER 012 4.04E+01 9.22E+00 4.04E+01

Manganese compounds PER 012 2.93E+00 6.69E-01 2.93E+00

Nitrous Oxide PER 012 3.16E-02 7.21E-03 3.16E-02

Nickel compounds PER 012 3.56E+01 8.12E+00 3.56E+01

Nitrogen Oxides PER 012 9.87E+01 2.25E+01 9.87E+01

PM < 2.5 micron PER 012 7.01E+00 1.60E+00 7.01E+00

PM < 10 micron PER 012 7.01E+00 1.60E+00 7.01E+00

Total Particulate Matter PER 012 7.01E+00 1.60E+00 7.01E+00

Sulfur Dioxide PER 012 6.53E+00 1.49E+00 6.53E+00

Volatile Organic Compounds PER 012 7.99E+00 1.82E+00 7.99E+00

FS 009

PM < 2.5 micron PER 010 1.32E+01 4.62E+00 2.02E+01

Lead PER 010 3.79E-02 8.65E-03 3.79E-02

PM < 10 micron PER 010 1.19E+02 8.30E+01 3.63E+02

Total Particulate Matter PER 010 3.79E+02 2.86E+02 1.25E+03

FS 141

Benzene PER 012 2.56E+00 5.84E-01 2.56E+00

Biphenyl PER 012 6.11E-01 1.39E-01 6.11E-01

Carbon Dioxide Equivalent PER 012 1.39E+03 3.17E+02 1.39E+03

Methane PER 012 5.56E+01 1.27E+01 5.56E+01

Ethylbenzene PER 012 1.56E+01 3.57E+00 1.56E+01

Hexane PER 012 3.88E+01 8.87E+00 3.88E+01

Naphthalene PER 012 6.21E+00 1.42E+00 6.21E+00

HAPs - Total PER 012 2.23E+02 5.10E+01 2.23E+02

Toluene PER 012 4.96E+01 1.13E+01 4.96E+01

Xylenes (mixed isomers) PER 012 9.48E+01 2.16E+01 9.48E+01

Polycyclic organic matter PER 012 1.51E+01 3.46E+00 1.51E+01

Volatile Organic Compounds PER 012 1.33E+03 3.04E+02 1.33E+03

GP 005

Benzene PER 009 2.56E+00 5.84E-01 2.56E+00

Benzene PER 012

Biphenyl PER 009 6.11E-01 1.39E-01 6.11E-01

Biphenyl PER 012

Ethylbenzene PER 009 1.56E+01 3.57E+00 1.56E+01

Ethylbenzene PER 012

Hexane PER 009 3.88E+01 8.87E+00 3.88E+01

Hexane PER 012

Naphthalene PER 009 6.21E+00 1.42E+00 6.21E+00

Naphthalene PER 012

HAPs - Total PER 009 2.23E+02 5.10E+01 2.23E+02

Page 63 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

GP 005

HAPs - Total PER 012

Toluene PER 009 4.96E+01 1.13E+01 4.96E+01

Toluene PER 012

Xylenes (mixed isomers) PER 009 9.48E+01 2.16E+01 9.48E+01

Xylenes (mixed isomers) PER 012

Polycyclic organic matter PER 009 1.51E+01 3.46E+00 1.51E+01

Polycyclic organic matter PER 012

Volatile Organic Compounds PER 010 1.33E+03 3.06E+02 1.33E+03

Volatile Organic Compounds PER 012

GP 009

Benzene PER 009 1.08E+01 2.47E+00 1.08E+01

1,3-Butadiene PER 009 4.11E-04 9.38E-05 4.11E-04

Chlorobenzene PER 009 4.11E-02 9.38E-03 4.11E-02

Cumene PER 009 3.08E-02 7.04E-03 3.08E-02

1,2-Dichloroethane PER 009 4.81E-02 1.10E-02 4.81E-02

Ethylbenzene PER 009 4.40E+00 1.00E+00 4.40E+00

Hexane PER 009 2.55E+01 5.82E+00 2.55E+01

Hydrogen Sulfide PER 009 7.53E+00 1.72E+00 7.53E+00

Naphthalene PER 009 3.68E+00 8.40E-01 3.68E+00

HAPs - Total PER 009 9.25E+01 2.11E+01 9.25E+01

Phenol PER 009 1.37E+00 3.12E-01 1.37E+00

Toluene PER 009 2.35E+01 5.36E+00 2.35E+01

1,1,2-Trichloroethane PER 009 4.11E-02 9.38E-03 4.11E-02

Xylenes (mixed isomers) PER 009 2.21E+01 5.05E+00 2.21E+01

2,2,4-trimethylpentane PER 009 1.01E+00 2.30E-01 1.01E+00

Ethylene dibromide (dibromoeth PER 009 4.73E-03 1.08E-03 4.73E-03

Volatile Organic Compounds PER 009 4.11E+02 9.38E+01 4.11E+02

GP 012

A cetaldehyde PER 009 5.27E+00 1.20E+00 5.27E+00

A cetaldehyde PER 012

A crolein PER 009 1.65E+00 3.76E-01 1.65E+00

A crolein PER 012

Benzene PER 009 1.62E+02 3.71E+01 1.62E+02

Benzene PER 012

A rsenic compounds PER 009 8.79E-01 2.01E-01 8.79E-01

A rsenic compounds PER 012

Beryllium Compounds PER 009 5.23E-01 1.19E-01 5.23E-01

Beryllium Compounds PER 012

Carbon Dioxide Equivalent PER 009 3.91E+03 8.92E+02 3.91E+03

Carbon Dioxide Equivalent PER 012

Cadmium compounds PER 009 2.30E+00 5.25E-01 2.30E+00

Cadmium compounds PER 012

Methane PER 009 1.58E-01 3.61E-02 1.58E-01

Methane PER 012

Carbon Monoxide PER 009 2.13E+01 2.13E+01 2.13E+01

Carbon Monoxide PER 012

Page 64 of 70MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 11 December, 2014 16:09



# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

GP 012

Carbon Dioxide PER 009 3.89E+03 8.89E+02 3.89E+03

Carbon Dioxide PER 012

Chromium compounds PER 009 1.40E+01 3.20E+00 1.40E+01

Chromium compounds PER 012

Formaldehyde PER 009 1.65E+01 3.77E+00 1.65E+01

Formaldehyde PER 012

Naphthalene PER 009 2.72E+01 6.21E+00 2.72E+01

Naphthalene PER 012

HAPs - Total PER 009 3.69E+02 8.43E+01 3.69E+02

HAPs - Total PER 012

Mercury Compounds PER 009 6.28E-01 1.43E-01 6.28E-01

Mercury Compounds PER 012

Toluene PER 009 5.88E+01 1.34E+01 5.88E+01

Toluene PER 012

Xylenes (mixed isomers) PER 009 4.04E+01 9.22E+00 4.04E+01

Xylenes (mixed isomers) PER 012

Manganese compounds PER 009 2.93E+00 6.69E-01 2.93E+00

Manganese compounds PER 012

Nitrous Oxide PER 009 3.16E-02 7.21E-03 3.16E-02

Nitrous Oxide PER 012

Nickel compounds PER 009 3.56E+01 8.12E+00 3.56E+01

Nickel compounds PER 012

Nitrogen Oxides PER 009 9.87E+01 2.25E+01 9.87E+01

Nitrogen Oxides PER 012

PM < 2.5 micron PER 009 7.01E+00 7.01E+00 7.01E+00

PM < 2.5 micron PER 012

PM < 10 micron PER 009 7.01E+00 7.01E+00 7.01E+00

PM < 10 micron PER 012

Total Particulate Matter PER 009 7.01E+00 7.01E+00 7.01E+00

Total Particulate Matter PER 012

Sulfur Dioxide PER 009 6.53E+00 6.53E+00 6.53E+00

Sulfur Dioxide PER 012

Volatile Organic Compounds PER 009 7.99E+00 7.99E+00 7.99E+00

Volatile Organic Compounds PER 012

GP 015

PM < 10 micron PER 001 1.53E+00 5.50E+01 2.41E+02

Total Particulate Matter PER 001 2.88E+00 6.85E+01 3.00E+02

GP 017

Benzene PER 009 2.13E+00 7.46E-01 2.13E+00

Carbon Dioxide Equivalent PER 009 2.10E+03 4.79E+02 2.10E+03

Chlorobenzene PER 009 1.00E-02 3.50E-03 1.00E-02

Methane PER 009 1.00E+02 2.28E+01 1.00E+02

1,2-Dibromo-3-chloropropane PER 009 1.72E-04 6.02E-05 1.72E-04

1,2-Dichloroethane PER 009 4.38E-03 1.53E-03 4.38E-03

Ethylbenzene PER 009 1.28E+00 4.48E-01 1.28E+00

Hexane PER 009 4.87E+00 1.70E+00 4.87E+00

Page 65 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

GP 017

Hydrogen Sulfide PER 009 3.68E-01 8.41E-02 3.68E-01

Naphthalene PER 009 3.10E+01 1.09E+01 3.10E+01

HAPs - Total PER 009 3.21E+01 1.12E+01 3.21E+01

Phenol PER 009 1.16E+00 4.06E-01 1.16E+00

Toluene PER 009 2.53E+01 8.86E+00 2.53E+01

1,2,4-Trichlorobenzene PER 009 3.55E-01 1.24E-01 3.55E-01

Xylenes (mixed isomers) PER 009 5.70E+00 2.00E+00 5.70E+00

2,2,4-trimethylpentane PER 009 3.31E-01 1.16E-01 3.31E-01

Volatile Organic Compounds PER 009 1.00E+02 3.50E+01 1.00E+02

GP 115

Hydrogen Sulfide PER 009 1.00E+01 3.98E+00 1.74E+01

GP 129

Carbon Dioxide Equivalent PER 009 2.23E+02 5.08E+01 2.23E+02

Carbon Dioxide Equivalent PER 012

Methane PER 009 1.06E+01 2.42E+00 1.06E+01

Methane PER 012

GP 130

Carbon Dioxide Equivalent PER 009 1.03E+03 2.35E+02 1.03E+03

Carbon Dioxide Equivalent PER 012

Methane PER 009 4.89E+01 1.12E+00 4.89E+01

Methane PER 012

GP 136

Hydrogen Sulfide PER 012 3.10E-01 7.10E-02 3.10E-01

Volatile Organic Compounds PER 012 2.80E+01 6.39E+00 3.69E+01

SV 042

A cetaldehyde PER 007 3.63E-03 8.29E-04 3.63E-03

A cetaldehyde PER 012 4.58E-03 1.04E-03 4.58E-03

Carbon disulfide PER 007 3.61E+00 8.25E-01 3.61E+00

Carbon disulfide PER 012 1.27E+01 2.90E+00 1.27E+01

Carbonyl sulfide PER 007 7.51E-01 1.72E-01 7.51E-01

Carbonyl sulfide PER 012 4.23E+00 9.67E-01 4.23E+00

Carbon Dioxide Equivalent PER 010 1.23E+05 2.81E+04 1.23E+05

Methane PER 010 2.43E+00 5.55E-01 2.43E+00

Cyanide compounds PER 007 6.75E-04 1.54E-04 6.75E-04

Carbon Monoxide PER 009 1.21E+02 2.38E+01 1.04E+02

Carbon Monoxide PER 012 1.21E+02 2.63E+01 1.15E+02

Carbon Dioxide PER 010 1.23E+05 2.80E+04 1.23E+05

Formaldehyde PER 007 9.87E-03 2.25E-03 9.87E-03

Formaldehyde PER 012 1.24E-02 2.84E-03 1.24E-02

Hydrogen Sulfide PER 009 5.61E+00 1.28E+00 5.61E+00

HAPs - Total PER 007 4.38E+00 1.00E+00 4.38E+00

HAPs - Total PER 012 1.70E+01 3.87E+00 1.70E+01

Nitrous Oxide PER 010 4.71E-01 1.08E-01 4.71E-01

Nitrogen Oxides PER 010 4.21E+01 9.61E+00 4.21E+01

PM < 2.5 micron PER 010 2.49E+01 5.69E+00 2.49E+01

Page 66 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

SV 042

PM < 2.5 micron PER 012 2.75E+01 6.28E+00 2.75E+01

Lead PER 010 1.69E-04 3.86E-05 1.69E-04

PM < 10 micron PER 010 2.49E+01 5.69E+00 2.49E+01

PM < 10 micron PER 012 2.75E+01 6.28E+00 2.75E+01

Total Particulate Matter PER 010 2.49E+01 5.69E+00 2.49E+01

Total Particulate Matter PER 012 2.75E+01 6.28E+00 2.75E+01

Sulfur Dioxide PER 009 4.10E+02 4.61E+03 2.02E+04

Sulfur Dioxide PER 012 4.10E+02 5.09E+03 2.23E+04

Volatile Organic Compounds PER 010 1.86E+00 4.25E-01 1.86E+00

SV 047

Methanol PER 009 1.23E+01 2.81E+00 1.23E+01

Volatile Organic Compounds PER 009 1.23E+01 2.81E+00 1.23E+01

SV 066

Benzene PER 009 1.22E-03 2.78E-04 1.22E-03

A rsenic compounds PER 009 1.16E-04 2.65E-05 1.16E-04

Beryllium Compounds PER 009 6.96E-06 1.59E-06 6.96E-06

Cadmium compounds PER 009 6.38E-04 1.46E-04 6.38E-04

Carbon Monoxide PER 009 2.37E+01 1.11E+01 4.87E+01

Cobalt compounds PER 009 4.87E-05 1.11E-05 4.87E-05

Chromium compounds PER 009 8.12E-04 1.85E-04 8.12E-04

1,4-Dichlorobenzene PER 009 6.96E-04 1.59E-04 6.96E-04

Formaldehyde PER 009 4.35E-02 9.93E-03 4.35E-02

Hexane PER 009 1.04E+00 2.38E-01 1.04E+00

Naphthalene PER 009 3.54E-04 8.07E-05 3.54E-04

HAPs - Total PER 009 1.09E+00 2.50E-01 1.09E+00

Mercury Compounds PER 009 1.51E-04 3.44E-05 1.51E-04

Toluene PER 009 1.97E-03 4.50E-04 1.97E-03

Manganese compounds PER 009 2.20E-04 5.03E-05 2.20E-04

Nickel compounds PER 009 1.22E-03 2.78E-04 1.22E-03

Nitrogen Oxides PER 009 2.96E+01 6.08E+00 2.66E+01

PM < 2.5 micron PER 009 4.41E+00 1.01E+00 4.41E+00

Lead PER 009 2.90E-04 6.62E-05 2.90E-04

PM < 10 micron PER 009 4.41E+00 1.01E+00 4.41E+00

Polycyclic organic matter PER 009 5.11E-05 1.17E-05 5.11E-05

Total Particulate Matter PER 009 4.41E+00 1.01E+00 4.41E+00

Selenium compounds PER 009 1.39E-05 3.18E-06 1.39E-05

Sulfur Dioxide PER 009 1.35E+01 5.71E+00 1.35E+01

Volatile Organic Compounds PER 009 3.19E+00 7.28E-01 3.19E+00

SV 073

Methanol PER 009 3.59E+00 8.20E-01 3.59E+00

Volatile Organic Compounds PER 009 3.59E+00 8.20E-01 3.59E+00

SV 083

Benzene PER 009 3.53E-03 8.05E-04 3.53E-03

A rsenic compounds PER 009 3.36E-04 7.67E-05 3.36E-04

Beryllium Compounds PER 009 2.01E-05 4.60E-06 2.01E-05

Carbon Dioxide Equivalent PER 010 2.12E+05 4.83E+04 2.12E+05

Page 67 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

SV 083

Cadmium compounds PER 009 1.85E-03 4.22E-04 1.85E-03

Methane PER 009 1.13E+01 2.59E+00 1.13E+01

Carbon Monoxide PER 009 5.00E+01 3.22E+01 1.41E+02

Carbon Dioxide PER 010 2.11E+05 4.81E+04 2.11E+05

Cobalt compounds PER 009 1.41E-04 3.22E-05 1.41E-04

Chromium compounds PER 009 2.35E-03 5.37E-04 2.35E-03

1,4-Dichlorobenzene PER 009 2.01E-03 4.60E-04 2.01E-03

Formaldehyde PER 009 1.26E-01 2.88E-02 1.26E-01

Hexane PER 009 3.02E+00 6.90E-01 3.02E+00

Naphthalene PER 009 1.02E-03 2.34E-04 1.02E-03

HAPs - Total PER 009 3.17E+00 7.23E-01 3.17E+00

Mercury Compounds PER 009 4.37E-04 9.97E-05 4.37E-04

Toluene PER 009 5.71E-03 1.30E-03 5.71E-03

Manganese compounds PER 009 6.38E-04 1.46E-04 6.38E-04

Nitrous Oxide PER 009 2.27E+00 5.17E-01 2.27E+00

Nickel compounds PER 009 3.53E-03 8.05E-04 3.53E-03

Nitrogen Oxides PER 009 7.71E+01 1.76E+01 7.71E+01

PM < 2.5 micron PER 009 1.28E+01 2.91E+00 1.28E+01

Lead PER 009 8.40E-04 1.92E-04 8.40E-04

PM < 10 micron PER 009 1.28E+01 2.91E+00 1.28E+01

Polycyclic organic matter PER 009 1.48E-04 3.38E-05 1.48E-04

Total Particulate Matter PER 009 1.28E+01 2.91E+00 1.28E+01

Selenium compounds PER 009 4.03E-05 9.20E-06 4.03E-05

Sulfur Dioxide PER 009 1.32E+02 3.02E+01 1.32E+02

Volatile Organic Compounds PER 009 9.23E+00 2.11E+00 9.23E+00

SV 093

A cetaldehyde PER 009 4.26E-03 9.73E-04 4.26E-03

A cetaldehyde PER 012 4.69E-03 1.07E-03 4.69E-03

Carbon disulfide PER 009 2.88E+00 6.58E-01 2.88E+00

Carbon disulfide PER 012 1.30E+01 2.98E+00 1.30E+01

Carbonyl sulfide PER 009 5.99E-01 1.37E-01 5.99E-01

Carbonyl sulfide PER 012 4.34E+00 9.92E-01 4.34E+00

Carbon Dioxide Equivalent PER 010 1.23E+05 2.81E+04 1.23E+05

Methane PER 010 2.34E+00 5.34E-01 2.34E+00

Cyanide compounds PER 009 5.39E-04 1.23E-04 5.39E-04

Carbon Monoxide PER 009 6.04E+02 1.38E+02 6.04E+02

Carbon Monoxide PER 012 6.66E+02 1.52E+02 6.66E+02

Carbon Dioxide PER 010 1.23E+05 2.80E+04 1.23E+05

Formaldehyde PER 009 1.16E-02 2.65E-03 1.16E-02

Formaldehyde PER 012 1.28E-02 2.92E-03 1.28E-02

Hydrogen Sulfide PER 009 7.05E+00 1.61E+00 7.05E+00

HAPs - Total PER 009 3.50E+00 7.99E-01 3.50E+00

HAPs - Total PER 012 1.74E+01 3.98E+00 1.74E+01

Nitrous Oxide PER 010 4.51E-01 1.03E-01 4.51E-01

Nitrogen Oxides PER 009 9.02E+01 2.06E+01 9.02E+01

PM < 2.5 micron PER 010 2.56E+01 5.85E+00 2.56E+01

Page 68 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

SV 093

PM < 2.5 micron PER 012 2.82E+01 6.45E+00 2.82E+01

Lead PER 009 1.61E-04 3.68E-05 1.61E-04

PM < 10 micron PER 010 2.56E+01 5.85E+00 2.56E+01

PM < 10 micron PER 012 2.82E+01 6.45E+00 2.82E+01

Total Particulate Matter PER 010 2.56E+01 5.85E+00 2.56E+01

Total Particulate Matter PER 012 2.82E+01 6.45E+00 2.82E+01

Sulfur Dioxide PER 009 3.24E+02 4.74E+03 2.08E+04

Sulfur Dioxide PER 012 3.24E+02 5.22E+03 2.29E+04

Volatile Organic Compounds PER 009 1.77E+00 4.04E-01 1.77E+00

SV 104

Carbon Monoxide PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

SV 105

Carbon Monoxide PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

SV 106

Carbon Monoxide PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

SV 107

Carbon Monoxide PER 009

HAPs - Total PER 009

Nitrogen Oxides PER 009

Lead PER 009

PM < 10 micron PER 009

Total Particulate Matter PER 009

Sulfur Dioxide PER 009

Volatile Organic Compounds PER 009

Page 69 of 70MINNESOTA POLLUTION CONTROL AGENCY

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# FACILITY DESCRIPTION: Potential-to-emit (by item)

Show: Active and Pending Records

AQD Facility ID:

Facility Name: 03700011

Flint Hills Resources Pine Bend Refinery

Item Unrestricted

Potential (tons per yr) Limited

Potential (tons per yr) Actual

Emissions (tons per yr) Pollutant Added By (Action) Retired By (Action) Hourly

Potential (lbs per hr)

SV 134

Methanol PER 009 2.04E+01 4.66E+00 2.04E+01

Volatile Organic Compounds PER 009 2.04E+01 4.66E+00 2.04E+01

SV 166

Methanol PER 009 2.79E+01 6.37E+00 2.79E+01

Volatile Organic Compounds PER 009 2.79E+01 6.37E+00 2.79E+01

TK 328

Sulfur Dioxide PER 009 4.94E+00 2.03E+00 4.94E+00

TK 329

Sulfur Dioxide PER 009 4.94E+00 2.03E+00 4.94E+00

TK 367

Hydrogen Sulfide PER 009

Sulfur - Total Reduced PER 009

Volatile Organic Compounds PER 009

TK 368

Hydrogen Sulfide PER 009

Sulfur - Total Reduced PER 009

Volatile Organic Compounds PER 009

TK 515

Hydrogen Sulfide PER 009

Sulfur - Total Reduced PER 009

Volatile Organic Compounds PER 009

TK 517

Carbon Dioxide Equivalent PER 009 5.23E+02 1.19E+02 5.23E+02

Methane PER 009 9.85E-03 2.25E-03 9.85E-03

Carbon Monoxide PER 009 3.68E-01 8.40E-02 3.68E-01

Carbon Dioxide PER 009 5.22E+02 1.19E+02 5.22E+02

Nitrous Oxide PER 009 9.85E-04 2.25E-04 9.85E-04

Nitrogen Oxides PER 001 1.23E+00 2.80E-01 1.23E+00

PM < 2.5 micron PER 009 3.33E-02 7.60E-03 3.33E-02

Lead PER 009 2.19E-06 5.00E-07 2.19E-06

PM < 10 micron PER 009 3.33E-02 7.60E-03 3.33E-02

Total Particulate Matter PER 009 3.33E-02 7.60E-03 3.33E-02

Sulfur Dioxide PER 009 2.93E-03 6.70E-04 2.93E-03

Volatile Organic Compounds PER 009 2.41E-02 5.50E-03 2.41E-02

TK 589

Carbon Dioxide Equivalent PER 012 2.65E+02 6.05E+01 2.65E+02

Methane PER 012 1.06E+01 2.42E+00 1.06E+01

Page 70 of 7011 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

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Acetaldehyde

PER 001 EU 007 1.140E-04 4.990E-04 4.990E-04

PER 001 EU 024 1.140E-04 4.990E-04 4.990E-04

PER 001 EU 036 1.290E-04 5.670E-04 5.670E-04

PER 009 EU 042 1.130E-04 4.970E-04 4.970E-04

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 100 1.290E-04 5.670E-04 5.670E-04

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 127 1.330E-04 5.840E-04 5.840E-04

PER 001 EU 128 1.190E-04 5.220E-04 5.220E-04

PER 009 EU 129 6.140E-05 2.690E-04 2.690E-04

PER 009 EU 130 1.030E-04 4.520E-04 4.520E-04 0.000E+00

PER 009 EU 131 3.310E-05 1.450E-04 1.450E-04

PER 009 EU 132 9.450E-05 4.140E-04 4.140E-04

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 1.230E-04 5.380E-04 5.380E-04

PER 001 EU 199 1.230E-04 5.380E-04 5.380E-04

PER 009 EU 312 2.180E-04 9.560E-04 9.560E-04

PER 011 EU 355 2.090E-03 5.240E-04 5.240E-04

PER 011 EU 356 2.090E-03 5.240E-04 5.240E-04

PER 011 EU 357 5.410E-03 1.350E-03 1.350E-03

PER 012 EU 359 7.600E-02 3.300E-01 3.300E-01

PER 012 EU 362 1.200E+00 5.270E+00 5.270E+00

PER 009 GP 012 1.200E+00 5.270E+00 5.270E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 007 SV 042 8.290E-04 3.630E-03 3.630E-03

PER 012 SV 042 1.040E-03 4.580E-03 4.580E-03

PER 009 SV 093 9.730E-04 4.260E-03 4.260E-03

PER 012 SV 093 1.070E-03 4.690E-03 4.690E-03

Totals 5.619E+00 5.619E+00 0.000E+00

Acrolein

PER 001 EU 007 3.560E-05 1.560E-04 1.560E-04

PER 001 EU 024 3.560E-05 1.560E-04 1.560E-04

PER 001 EU 036 4.050E-05 1.770E-04 1.770E-04

PER 001 EU 042 3.550E-05 1.550E-04 1.550E-04

Page 1 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Acrolein

PER 001 EU 100 4.050E-05 1.770E-04 1.770E-04

PER 001 EU 127 4.170E-05 1.820E-04 1.820E-04

PER 001 EU 128 3.720E-05 1.630E-04 1.630E-04

PER 009 EU 129 1.920E-05 8.410E-05 8.410E-05

PER 009 EU 130 3.230E-05 1.410E-04 1.410E-04

PER 009 EU 131 1.030E-05 4.530E-05 4.530E-05

PER 009 EU 132 2.960E-05 1.290E-04 1.290E-04

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 3.840E-05 1.680E-04 1.680E-04

PER 001 EU 199 3.840E-05 1.680E-04 1.680E-04

PER 009 EU 312 6.830E-05 2.990E-04 2.990E-04

PER 011 EU 355 1.970E-03 4.940E-04 4.940E-04

PER 011 EU 356 1.970E-03 4.940E-04 4.940E-04

PER 011 EU 357 5.100E-03 1.280E-03 1.280E-03

PER 012 EU 359 1.600E-03 6.900E-03 6.900E-03

PER 012 EU 362 3.760E-01 1.650E+00 1.650E+00

PER 009 GP 012 3.760E-01 1.650E+00 1.650E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

Totals 1.661E+00 1.661E+00 0.000E+00

Benzene

PER 009 EU 005 2.470E-04 1.080E-03 1.080E-03

PER 009 EU 006 1.170E-04 5.140E-04 5.140E-04

PER 001 EU 007 3.510E-03 1.540E-02 1.540E-02

PER 009 EU 016 2.850E-04 1.250E-03 1.250E-03

PER 009 EU 019 4.880E-04 2.140E-03 2.140E-03

PER 001 EU 024 3.510E-03 1.540E-02 1.540E-02

PER 009 EU 026 3.010E-04 1.320E-03 1.320E-03

PER 009 EU 028 3.040E+04 1.330E-03 1.330E-03

PER 009 EU 030 3.040E-04 1.330E-03 1.330E-03

PER 009 EU 034 3.400E-04 1.490E-03 1.490E-03

PER 009 EU 035 2.510E-04 1.100E-03 1.100E-03

PER 001 EU 036 3.990E-03 1.750E-02 1.750E-02

PER 009 EU 040 5.210E-04 2.280E-03 2.280E-03

PER 009 EU 041 4.240E-04 1.860E-03 1.860E-03

PER 001 EU 042 3.490E-03 1.530E-02 1.530E-02

Page 2 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Benzene

PER 009 EU 050 1.730E-04 7.570E-04 7.570E-04

PER 009 EU 051 1.730E-04 7.570E-04 7.570E-04

PER 009 EU 052 1.650E-03 7.210E-03 7.210E-03

PER 009 EU 053 7.000E-05 3.070E-04 3.070E-04

PER 009 EU 054 4.740E-05 2.070E-04 2.070E-04

PER 009 EU 055 4.740E-05 1.980E-05 1.980E-05

PER 009 EU 056 1.460E-04 6.400E-04 6.400E-04

PER 009 EU 057 2.060E-05 9.020E-05 9.020E-05

PER 009 EU 058 1.170E-04 5.140E-04 5.140E-04

PER 009 EU 059 8.030E-05 3.520E-04 3.520E-04

PER 009 EU 060 8.030E-05 3.520E-04 3.520E-04

PER 009 EU 061 6.180E-05 2.710E-04 2.710E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.850E-05 8.120E-05 8.120E-05

PER 009 EU 084 2.430E-04 1.060E-03 1.060E-03

PER 009 EU 085 2.650E-04 1.160E-03 1.160E-03

PER 009 EU 093 4.940E-05 2.160E-04 2.160E-04

PER 009 EU 094 6.790E-05 2.980E-04 2.980E-04

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 6.790E-05 2.980E-04 2.980E-04

PER 001 EU 100 3.990E-03 1.750E-02 1.750E-02

PER 009 EU 102 6.530E-05 2.860E-04 2.860E-04

PER 009 EU 103 6.260E-05 2.740E-04 2.740E-04

PER 009 EU 104 1.150E-04 5.050E-04 5.050E-04

PER 009 EU 126 2.470E-04 1.080E-03 1.080E-03

PER 001 EU 127 4.100E-03 1.800E-02 1.800E-02

PER 001 EU 128 3.670E-03 1.610E-02 1.610E-02

PER 009 EU 129 1.890E-03 8.280E-03 8.280E-03

PER 009 EU 130 3.180E-03 1.390E-02 1.390E-02

PER 009 EU 131 1.020E-03 4.460E-03 4.460E-03

PER 009 EU 132 2.910E-03 1.270E-02 1.270E-02

Page 3 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Benzene

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 3.780E-03 1.660E-02 1.660E-02

PER 001 EU 199 3.780E-03 1.660E-02 1.660E-02

PER 001 EU 204 3.810E-04 1.670E-03 1.670E-03

PER 010 EU 212 8.440E-04 3.700E-03 3.700E-03

PER 009 EU 213 9.780E-04 4.280E-03 4.300E-03

PER 009 EU 240 1.850E-05 8.120E-05 8.120E-05

PER 009 EU 241 3.090E-04 1.350E-03 1.350E-03

PER 009 EU 276 1.860E+01 8.160E+01 4.080E+00

PER 009 EU 277 1.160E+01 5.060E+01 2.530E+00

PER 009 EU 282 3.110E-01 1.360E+00 1.360E+00

PER 009 EU 294 4.960E-04 2.170E-03 2.170E-03

PER 009 EU 296 1.850E-03 8.120E-03 8.120E-03

PER 009 EU 312 6.720E-03 2.940E-02 2.940E-02

PER 009 EU 313 4.840E-04 2.120E-03 2.120E-03

PER 009 EU 324 3.360E-04 1.470E-03 1.470E-03

PER 010 EU 352 5.440E-04 2.380E-03 2.380E-03

PER 010 EU 353 6.710E-04 2.940E-03 2.940E-03

PER 011 EU 355 1.190E-03 2.970E-04 2.970E-04

PER 011 EU 356 1.190E-03 2.970E-04 2.970E-04

PER 011 EU 357 3.070E-03 7.660E-04 7.660E-04

PER 011 EU 358 8.240E-05 3.610E-04 3.610E-04

PER 012 EU 359 1.400E-03 6.200E-03 6.200E-03

PER 012 EU 360 4.900E-04 2.200E-03 2.200E-03

PER 012 EU 361 9.020E-05 3.950E-04 3.950E-04

PER 012 EU 362 3.710E+01 1.620E+02 1.620E+02

PER 012 FS 141 5.840E-01 2.560E+00 2.560E+00

PER 009 GP 005 5.840E-01 2.560E+00 2.560E+00

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 2.470E+00 1.080E+01 1.080E+01

PER 009 GP 012 3.710E+01 1.620E+02 1.620E+02

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 7.460E-01 2.130E+00 2.130E+00

PER 009 SV 066 2.780E-04 1.220E-03 1.220E-03

Page 4 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Benzene

PER 009 SV 083 8.050E-04 3.530E-03 3.530E-03

Totals 3.113E+02 1.858E+02 0.000E+00

Arsenic compounds

PER 009 EU 005 2.350E-05 1.030E-04 1.030E-04

PER 009 EU 006 1.120E-05 4.900E-05 4.900E-05

PER 001 EU 007 1.900E-05 8.320E-05 8.320E-05

PER 009 EU 016 2.710E-05 1.190E-04 1.190E-04

PER 009 EU 019 4.650E-05 2.040E-04 2.040E-04

PER 001 EU 024 1.900E-05 8.320E-05 8.320E-05

PER 009 EU 026 2.860E-05 1.250E-04 1.250E-04

PER 009 EU 028 2.890E-05 1.270E-04 1.270E-04

PER 009 EU 030 2.900E-05 1.270E-04 1.270E-04

PER 009 EU 034 3.240E-05 1.420E-04 1.420E-04

PER 009 EU 035 2.390E-05 1.050E-04 1.050E-04

PER 001 EU 036 2.160E-05 9.450E-05 9.450E-05

PER 009 EU 040 4.960E-05 2.170E-04 2.170E-04

PER 009 EU 041 4.040E-05 1.770E-04 1.770E-04

PER 001 EU 042 1.890E-05 8.280E-05 8.280E-05

PER 009 EU 050 1.650E-05 7.210E-05 7.210E-05

PER 009 EU 051 1.650E-05 7.210E-05 7.210E-05

PER 009 EU 052 1.570E-04 6.870E-04 6.870E-04

PER 009 EU 053 6.670E-06 2.920E-05 2.920E-05

PER 009 EU 054 4.510E-06 1.980E-05 1.980E-05

PER 009 EU 055 4.510E-06 1.980E-05 1.980E-05

PER 009 EU 056 1.390E-05 6.100E-05 6.100E-05

PER 009 EU 057 1.960E-06 8.590E-06 8.590E-06

PER 009 EU 058 1.120E-05 4.900E-05 4.900E-05

PER 009 EU 059 7.650E-06 3.350E-05 3.350E-05

PER 009 EU 060 7.650E-06 3.350E-05 3.350E-05

PER 009 EU 061 5.880E-06 2.580E-05 2.580E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.760E-06 7.730E-06 7.730E-06

PER 009 EU 084 2.310E-05 1.010E-04 1.010E-04

Page 5 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Arsenic compounds

PER 009 EU 085 2.530E-05 1.110E-04 1.110E-04

PER 009 EU 093 4.710E-06 2.060E-05 2.060E-05

PER 009 EU 094 6.470E-06 2.830E-05 2.830E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 6.470E-06 2.830E-05 2.830E-05

PER 001 EU 100 2.160E-05 9.450E-05 9.450E-05

PER 009 EU 102 6.220E-06 2.720E-05 2.720E-05

PER 009 EU 103 5.960E-06 2.610E-05 2.610E-05

PER 009 EU 104 1.100E-05 4.810E-05 4.810E-05

PER 009 EU 126 2.350E-05 1.030E-04 1.030E-04

PER 001 EU 127 2.220E-05 9.730E-05 9.730E-05

PER 001 EU 128 1.980E-05 8.690E-05 8.690E-05

PER 009 EU 129 1.020E-05 4.480E-05 4.480E-05

PER 009 EU 130 1.720E-05 7.530E-05 7.530E-05

PER 009 EU 131 5.510E-06 2.410E-05 2.410E-05

PER 009 EU 132 1.580E-05 6.900E-05 6.900E-05

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 2.050E-05 8.970E-05 8.970E-05

PER 001 EU 199 2.050E-05 8.970E-05 8.970E-05

PER 001 EU 204 3.630E-05 1.590E-04 1.590E-04

PER 010 EU 212 8.040E-05 3.520E-04 3.520E-04

PER 009 EU 213 9.310E-05 4.080E-04 4.080E-04

PER 009 EU 228 8.000E-04 3.500E-03 1.050E-03

PER 009 EU 240 1.760E-06 7.730E-06 7.730E-06

PER 009 EU 241 2.940E-05 1.290E-04 1.290E-04

PER 009 EU 294 4.730E-05 2.070E-04 2.070E-04

PER 009 EU 296 1.760E-04 7.730E-04 7.730E-04

PER 009 EU 312 3.640E-05 1.590E-04 1.590E-04

PER 009 EU 313 4.610E-05 2.020E-04 2.020E-04

PER 009 EU 324 3.200E-05 1.400E-04 1.400E-04

PER 010 EU 352 5.180E-05 2.270E-04 2.270E-04

PER 010 EU 353 6.390E-05 2.800E-04 2.800E-04

PER 011 EU 358 7.840E-06 3.440E-05 3.440E-05

Page 6 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Arsenic compounds

PER 012 EU 359 8.500E-05 3.700E-04 3.700E-04

PER 012 EU 360 4.700E-05 2.100E-04 2.100E-04

PER 012 EU 361 8.590E-06 3.760E-05 3.760E-05

PER 012 EU 362 2.010E-01 8.790E-01 8.790E-01

PER 009 GP 012 2.010E-01 8.790E-01 8.790E-01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 2.650E-05 1.160E-04 1.160E-04

PER 009 SV 083 7.670E-05 3.360E-04 3.360E-04

Totals 8.908E-01 8.883E-01 0.000E+00

Biphenyl

PER 009 EU 282 7.640E-04 3.350E-03 3.350E-03

PER 012 FS 141 1.390E-01 6.110E-01 6.110E-01

PER 009 GP 005 1.390E-01 6.110E-01 6.110E-01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

Totals 6.144E-01 6.144E-01 0.000E+00

1,3-Butadiene

PER 011 EU 355 4.980E-04 1.240E-04 1.240E-04

PER 011 EU 356 4.980E-04 1.240E-04 1.240E-04

PER 011 EU 357 1.290E-03 3.220E-04 3.220E-04

PER 012 EU 359 1.900E-04 8.200E-04 8.200E-04

PER 009 GP 009 9.380E-05 4.110E-04 4.110E-04

Totals 1.801E-03 1.801E-03 0.000E+00

Barium

PER 011 EU 358 1.730E-04 7.560E-04 7.560E-04

Totals 7.560E-04 7.560E-04 0.000E+00

Beryllium

PER 009 EU 006 6.710E-07 2.940E-06 2.940E-06

PER 010 EU 352 3.110E-06 1.360E-05 1.360E-05

PER 010 EU 353 3.840E-06 1.680E-05 1.680E-05

PER 011 EU 358 4.710E-07 2.060E-06 2.060E-06

PER 012 EU 359 5.100E-06 2.200E-05 2.200E-05

PER 012 EU 360 2.800E-06 1.200E-05 1.200E-05

Totals 6.940E-05 6.940E-05 0.000E+00

Beryllium Compounds

PER 009 EU 005 1.410E-06 6.180E-06 6.180E-06

PER 001 EU 007 1.130E-05 4.950E-05 4.950E-05

Page 7 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Beryllium Compounds

PER 009 EU 016 1.630E-06 7.120E-06 7.120E-06

PER 009 EU 019 2.790E-06 1.220E-05 1.220E-05

PER 001 EU 024 1.130E-05 4.950E-05 4.950E-05

PER 009 EU 026 1.720E-06 7.520E-06 7.520E-06

PER 009 EU 028 1.740E-06 7.610E-06 7.610E-06

PER 009 EU 030 1.740E-06 7.620E-06 7.620E-06

PER 009 EU 034 1.940E-06 8.500E-06 8.500E-06

PER 009 EU 035 1.440E-06 6.290E-06 6.290E-06

PER 001 EU 036 1.280E-05 5.630E-05 5.630E-05

PER 009 EU 040 2.980E-06 1.300E-05 1.300E-05

PER 009 EU 041 2.420E-06 1.060E-05 1.060E-05

PER 001 EU 042 1.130E-05 4.930E-05 4.930E-05

PER 009 EU 050 9.880E-07 4.330E-06 4.330E-06

PER 009 EU 051 9.880E-07 4.330E-06 4.330E-06

PER 009 EU 052 9.410E-06 4.120E-05 4.120E-05

PER 009 EU 053 4.000E-07 1.750E-06 1.750E-06

PER 009 EU 054 2.710E-07 1.190E-06 1.190E-06

PER 009 EU 055 2.710E-07 1.190E-06 1.190E-06

PER 009 EU 056 8.350E-07 3.660E-06 3.660E-06

PER 009 EU 057 1.180E-07 5.150E-07 5.150E-07

PER 009 EU 058 6.710E-07 2.940E-06 2.940E-06

PER 009 EU 059 4.590E-07 2.010E-06 2.010E-06

PER 009 EU 060 4.590E-07 2.010E-06 2.010E-06

PER 009 EU 061 3.530E-07 1.550E-06 1.550E-06

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.060E-07 4.640E-07 4.640E-07

PER 009 EU 084 1.390E-06 6.080E-06 6.080E-06

PER 009 EU 085 1.520E-06 6.640E-06 6.640E-06

PER 009 EU 093 2.820E-07 1.240E-06 1.240E-06

PER 009 EU 094 3.880E-07 1.700E-06 1.700E-06

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

Page 8 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Beryllium Compounds

PER 009 EU 098 3.880E-07 1.700E-06 1.700E-06

PER 001 EU 100 1.280E-05 5.630E-05 5.630E-05

PER 009 EU 102 3.730E-07 1.630E-06 1.630E-06

PER 009 EU 103 3.580E-07 1.570E-06 1.570E-06

PER 009 EU 104 6.590E-07 2.890E-06 2.890E-06

PER 009 EU 126 1.410E-06 6.180E-06 6.180E-06

PER 001 EU 127 1.320E-05 5.790E-05 5.790E-05

PER 001 EU 128 1.180E-05 5.170E-05 5.170E-05

PER 009 EU 129 6.090E-06 2.670E-05 2.670E-05

PER 009 EU 130 1.020E-05 4.480E-05 4.480E-05

PER 009 EU 131 3.280E-06 1.440E-05 1.440E-05

PER 009 EU 132 9.380E-06 4.110E-05 4.110E-05

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 1.220E-05 5.340E-05 5.340E-05

PER 001 EU 199 1.220E-05 5.340E-05 5.340E-05

PER 001 EU 204 2.180E-06 9.530E-06 9.530E-06

PER 010 EU 212 4.820E-06 2.110E-05 2.110E-05

PER 009 EU 213 5.590E-06 2.450E-05 2.450E-05

PER 009 EU 228 1.300E-04 5.690E-04 1.710E-04

PER 009 EU 240 1.060E-07 4.640E-07 4.640E-07

PER 009 EU 241 1.760E-06 7.720E-06 7.720E-06

PER 009 EU 294 2.840E-06 1.240E-05 1.240E-05

PER 009 EU 296 1.060E-05 4.640E-05 4.640E-05

PER 009 EU 312 2.170E-05 9.490E-05 9.490E-05

PER 009 EU 313 2.760E-06 1.210E-05 1.210E-05

PER 009 EU 324 1.920E-06 8.400E-06 8.400E-06

PER 012 EU 361 5.160E-07 2.260E-06 2.260E-06

PER 012 EU 362 1.190E-01 5.230E-01 5.230E-01

PER 009 GP 012 1.190E-01 5.230E-01 5.230E-01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 1.590E-06 6.960E-06 6.960E-06

PER 009 SV 083 4.600E-06 2.010E-05 2.010E-05

Totals 5.246E-01 5.242E-01 0.000E+00

Carbon disulfide

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

Page 9 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon disulfide

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 012 EU 361 4.800E-01 2.080E+00 2.080E+00

PER 007 SV 042 8.250E-01 3.610E+00 3.610E+00

PER 012 SV 042 2.900E+00 1.270E+01 1.270E+01

PER 009 SV 093 6.580E-01 2.880E+00 2.880E+00

PER 012 SV 093 2.980E+00 1.303E+01 1.303E+01

Totals 2.781E+01 2.781E+01 0.000E+00

Carbon tetrachloride

PER 011 EU 355 1.330E-05 3.320E-06 3.320E-06

PER 011 EU 356 1.330E-05 3.320E-06 3.320E-06

PER 011 EU 357 3.430E-05 8.590E-06 8.590E-06

Totals 1.523E-05 1.523E-05 0.000E+00

Carbonyl sulfide

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 228 7.800E-02 3.420E-01 3.420E-01

PER 012 EU 361 1.600E-01 6.900E-01 6.900E-01

PER 007 SV 042 1.720E-01 7.510E-01 7.510E-01

PER 012 SV 042 9.670E-01 4.230E+00 4.230E+00

PER 009 SV 093 1.370E-01 5.990E-01 5.990E-01

PER 012 SV 093 9.920E-01 4.340E+00 4.340E+00

Totals 9.602E+00 9.602E+00 0.000E+00

Carbon Dioxide Equivalent

PER 009 EU 004 2.470E+03 1.080E+04 1.080E+04

PER 010 EU 005 1.630E+04 7.120E+04 7.120E+04

PER 010 EU 006 7.730E+03 3.380E+04 3.380E+04

PER 009 EU 007 7.400E+02 3.240E+03 3.700E+02

PER 010 EU 016 1.870E+04 8.200E+04 8.200E+04

PER 010 EU 019 3.210E+04 1.410E+05 1.410E+05

PER 009 EU 024 7.400E+02 3.240E+03 3.700E+02

PER 010 EU 026 1.980E+04 8.670E+04 8.670E+04

PER 010 EU 028 2.000E+04 8.760E+04 8.760E+04

PER 010 EU 030 2.000E+04 8.770E+04 8.770E+04

Page 10 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Dioxide Equivalent

PER 010 EU 032 1.660E+03 7.270E+03 3.580E+02

PER 010 EU 033 1.660E+03 7.270E+03 3.580E+02

PER 010 EU 034 2.040E+04 8.930E+04 8.930E+04

PER 010 EU 035 1.510E+04 6.600E+04 6.600E+04

PER 009 EU 036 8.400E+02 3.680E+03 4.203E+02

PER 010 EU 037 6.610E+02 2.900E+03 1.430E+02

PER 010 EU 038 6.610E+02 2.900E+03 1.430E+02

PER 010 EU 040 3.130E+04 1.370E+05 1.370E+05

PER 010 EU 041 2.550E+04 1.110E+05 1.110E+05

PER 009 EU 042 7.360E+02 3.220E+03 3.680E+02

PER 009 EU 045 1.650E+04 7.250E+04 7.250E+04

PER 010 EU 050 1.040E+04 4.550E+04 4.550E+04

PER 010 EU 051 1.040E+04 4.550E+04 4.550E+04

PER 010 EU 052 9.880E+04 4.330E+05 4.330E+05

PER 010 EU 053 4.200E+03 1.840E+04 1.840E+04

PER 010 EU 054 3.120E+03 1.370E+04 1.370E+04

PER 010 EU 055 4.910E+03 2.150E+04 2.150E+04

PER 010 EU 056 9.620E+03 4.220E+04 4.220E+04

PER 010 EU 057 1.360E+03 5.940E+03 5.940E+03

PER 010 EU 058 7.730E+03 3.380E+04 3.380E+04

PER 010 EU 059 5.290E+03 2.320E+04 2.320E+04

PER 010 EU 060 5.290E+03 2.320E+04 2.320E+04

PER 010 EU 061 4.070E+03 1.780E+04 1.780E+04

PER 009 EU 073 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00

PER 010 EU 075 1.830E+04 8.020E+04 8.020E+04

PER 010 EU 076 1.220E+03 5.340E+03 5.340E+03

PER 009 EU 077 0.000E+00 0.000E+00

PER 010 EU 084 1.600E+04 7.010E+04 7.010E+04

PER 010 EU 085 1.590E+04 6.970E+04 6.970E+04

PER 010 EU 093 2.970E+03 1.300E+04 1.300E+04

PER 010 EU 094 4.570E+03 2.000E+04 2.000E+04

PER 009 EU 095 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00

Page 11 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Dioxide Equivalent

PER 010 EU 098 4.080E+03 1.790E+04 1.790E+04

PER 009 EU 099 3.320E+02 1.450E+03 1.450E+03

PER 009 EU 100 8.410E+02 3.680E+03 4.200E+02

PER 010 EU 102 3.920E+03 1.720E+04 1.720E+04

PER 010 EU 103 3.760E+03 1.650E+04 1.650E+04

PER 010 EU 104 6.920E+03 3.030E+04 3.030E+04

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 010 EU 126 1.630E+04 7.120E+04 7.120E+04

PER 009 EU 127 8.650E+02 3.790E+03 3.790E+03

PER 009 EU 128 7.730E+02 3.390E+03 3.870E+02

PER 009 EU 129 3.990E+02 1.750E+03 1.990E+02

PER 009 EU 130 6.700E+02 2.930E+03 3.350E+02

PER 009 EU 131 2.150E+02 9.410E+02 1.070E+02

PER 009 EU 132 6.140E+02 2.690E+03 3.070E+02

PER 009 EU 198 7.980E-02 3.490E+03 3.990E+02

PER 009 EU 199 7.980E+02 3.490E+03 3.990E+02

PER 009 EU 204 2.160E+04 9.480E+04 7.140E+04

PER 009 EU 209 3.260E+03 1.430E+04 1.430E+04

PER 010 EU 212 5.290E+04 2.320E+05 2.320E+05

PER 010 EU 213 5.870E+04 2.570E+05 2.570E+05

PER 010 EU 228 2.660E+05 1.170E+06 1.170E+06

PER 010 EU 240 1.110E+03 4.870E+03 4.870E+03

PER 010 EU 241 1.850E+04 8.110E+04 8.110E+04

PER 010 EU 245 3.580E+03 1.570E+04 1.570E+04

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 254 1.200E+04 5.270E+04 5.270E+04

PER 009 EU 276 1.590E+03 6.980E+03 6.980E+03

PER 009 EU 277 1.090E+03 4.770E+03 4.770E+03

PER 010 EU 294 2.980E+04 1.300E+05 1.300E+05

PER 010 EU 296 1.110E+05 4.870E+05 4.870E+05

PER 009 EU 301 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 302 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 303 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 304 2.970E+02 1.300E+03 1.300E+03

Page 12 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Dioxide Equivalent

PER 009 EU 312 1.420E+03 6.210E+03 7.090E+02

PER 010 EU 313 3.190E+04 1.400E+05 1.400E+05

PER 010 EU 324 2.010E+04 8.820E+04 8.820E+04

PER 009 EU 334 4.370E+02 1.914E+03 1.914E+03

PER 009 EU 335 4.370E+02 1.914E+03 1.914E+03

PER 009 EU 336 6.930E+02 3.034E+03 3.034E+03

PER 009 EU 337 0.000E+00 0.000E+00

PER 010 EU 348 6.370E+03 2.790E+04 2.790E+04

PER 010 EU 351 3.617E+03 1.692E+03

PER 010 EU 352 3.100E+04 1.358E+05 1.358E+05

PER 010 EU 353 3.814E+04 1.671E+05 1.671E+05

PER 011 EU 355 1.045E+02 2.613E+01 2.613E+01

PER 011 EU 356 1.045E+02 2.613E+01 2.613E+01

PER 011 EU 357 2.701E+02 6.751E+01 6.751E+01

PER 011 EU 358 5.555E+03 2.433E+04 2.433E+04

PER 012 EU 359 5.084E+04 2.227E+05 2.227E+05

PER 012 EU 360 2.798E+04 1.225E+05 1.225E+05

PER 012 EU 361 7.533E+03 3.299E+04 3.299E+04

PER 012 EU 362 8.920E+02 3.910E+03 3.910E+03

PER 012 FS 141 3.171E+02 1.389E+03 1.389E+03

PER 009 GP 012 8.920E+02 3.910E+03 3.910E+03

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 4.790E+02 2.100E+03 2.100E+03

PER 009 GP 129 5.080E+01 2.230E+02 2.230E+02

PER 012 GP 129 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 130 2.350E+02 1.030E+03 1.030E+03

PER 012 GP 130 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 2.810E+04 1.230E+05 1.230E+05

PER 010 SV 083 4.830E+04 2.120E+05 2.120E+05

PER 010 SV 093 2.810E+04 1.230E+05 1.230E+05

PER 009 TK 517 1.190E+02 5.230E+02 5.230E+02

PER 012 TK 589 6.050E+01 2.650E+02 2.650E+02

Totals 6.255E+06 6.177E+06 0.000E+00

Page 13 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Chlorine

PER 009 EU 228 1.720E-02 7.530E-02 2.260E-02

Totals 7.530E-02 2.260E-02 0.000E+00

Chlorobenzene

PER 011 EU 355 9.690E-06 2.420E-06 2.420E-06

PER 011 EU 356 9.690E-06 2.420E-06 2.420E-06

PER 011 EU 357 2.500E-05 6.260E-06 6.260E-06

PER 009 GP 009 9.380E-03 4.110E-02 4.110E-02

PER 009 GP 017 3.500E-03 1.000E-02 1.000E-02

Totals 5.111E-02 5.111E-02 0.000E+00

Chloroform

PER 011 EU 355 1.030E-05 2.570E-06 2.570E-06

PER 011 EU 356 1.030E-05 2.570E-06 2.570E-06

PER 011 EU 357 2.660E-05 6.650E-06 6.650E-06

Totals 1.179E-05 1.179E-05 0.000E+00

Cadmium compounds

PER 009 EU 005 1.290E-04 5.660E-04 5.660E-04

PER 009 EU 006 6.150E-05 2.690E-04 2.690E-04

PER 001 EU 007 4.970E-05 2.180E-04 2.180E-04

PER 009 EU 016 1.490E-04 6.530E-04 6.530E-04

PER 009 EU 019 2.560E-04 1.120E-03 1.120E-03

PER 001 EU 024 4.970E-05 2.180E-04 2.180E-04

PER 009 EU 026 1.570E-04 6.900E-04 6.900E-04

PER 009 EU 028 1.590E-04 6.970E-04 6.970E-04

PER 009 EU 030 1.590E-04 6.980E-04 6.980E-04

PER 009 EU 034 1.780E-04 7.790E-04 7.790E-04

PER 009 EU 035 1.320E-04 5.760E-04 5.760E-04

PER 001 EU 036 5.650E-05 2.480E-04 2.480E-04

PER 009 EU 040 2.730E-04 1.200E-03 1.200E-03

PER 009 EU 041 2.220E-04 9.730E-04 9.730E-04

PER 001 EU 042 4.950E-05 2.170E-04 2.170E-04

PER 009 EU 050 9.060E-05 3.970E-04 3.970E-04

PER 009 EU 051 9.060E-05 3.970E-04 3.970E-04

PER 009 EU 052 8.630E-04 3.780E-03 3.780E-03

PER 009 EU 053 3.670E-05 1.610E-04 1.610E-04

PER 009 EU 054 2.480E-05 1.090E-04 1.090E-04

Page 14 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Cadmium compounds

PER 009 EU 055 2.480E-05 1.090E-04 1.090E-04

PER 009 EU 056 7.660E-05 3.350E-04 3.350E-04

PER 009 EU 057 1.080E-05 4.720E-05 4.720E-05

PER 009 EU 058 6.150E-05 2.690E-04 2.690E-04

PER 009 EU 059 4.210E-05 1.840E-04 1.840E-04

PER 009 EU 060 4.210E-05 1.840E-04 1.840E-04

PER 009 EU 061 3.240E-05 1.420E-04 1.420E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 9.710E-06 4.250E-05 4.250E-05

PER 009 EU 084 1.270E-04 5.570E-04 5.570E-04

PER 009 EU 085 1.390E-04 6.080E-04 6.080E-04

PER 009 EU 093 2.590E-05 1.130E-04 1.130E-04

PER 009 EU 094 3.560E-05 1.560E-04 1.560E-04

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 3.560E-05 1.560E-04 1.560E-04

PER 001 EU 100 5.650E-05 2.480E-04 2.480E-04

PER 009 EU 102 3.420E-05 1.500E-04 1.500E-04

PER 009 EU 103 3.280E-05 1.440E-04 1.440E-04

PER 009 EU 104 6.040E-05 2.650E-04 2.650E-04

PER 009 EU 126 1.290E-04 5.670E-04 5.670E-04

PER 001 EU 127 5.820E-05 2.550E-04 2.550E-04

PER 001 EU 128 5.200E-05 2.280E-04 2.280E-04

PER 009 EU 129 2.680E-05 1.170E-04 1.170E-04

PER 009 EU 130 4.500E-05 1.970E-04 1.970E-04

PER 009 EU 131 1.440E-05 6.320E-05 6.320E-05

PER 009 EU 132 4.130E-05 1.810E-04 1.810E-04

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 5.360E-05 2.350E-04 2.350E-04

PER 001 EU 199 5.360E-05 2.350E-04 2.350E-04

PER 001 EU 204 2.000E-04 8.740E-04 8.740E-04

PER 010 EU 212 4.420E-04 1.940E-03 1.940E-03

Page 15 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Cadmium compounds

PER 009 EU 213 5.120E-04 2.240E-03 2.240E-03

PER 009 EU 240 9.710E-06 4.250E-05 4.250E-05

PER 009 EU 241 1.620E-04 7.080E-04 7.080E-04

PER 009 EU 294 2.600E-04 1.140E-03 1.140E-03

PER 009 EU 296 9.710E-04 4.250E-03 4.250E-03

PER 009 EU 312 9.530E-05 4.170E-04 4.170E-04

PER 009 EU 313 2.530E-04 1.110E-03 1.110E-03

PER 009 EU 324 1.760E-04 7.700E-04 7.700E-04

PER 010 EU 352 2.850E-04 1.250E-03 1.250E-03

PER 010 EU 353 3.520E-04 1.540E-03 1.540E-03

PER 011 EU 358 4.310E-05 1.890E-04 1.890E-04

PER 012 EU 359 4.700E-04 2.100E-03 2.100E-03

PER 012 EU 360 2.600E-04 1.100E-03 1.100E-03

PER 012 EU 361 4.730E-05 2.070E-04 2.070E-04

PER 012 EU 362 5.250E-01 2.300E+00 2.300E+00

PER 009 GP 012 5.250E-01 2.300E+00 2.300E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 1.460E-04 6.380E-04 6.380E-04

PER 009 SV 083 4.220E-04 1.850E-03 1.850E-03

Totals 2.342E+00 2.342E+00 0.000E+00

Methane

PER 009 EU 004 1.320E-01 5.790E-01 5.790E-01

PER 009 EU 005 7.930E-01 3.470E+00 3.470E+00

PER 009 EU 006 3.770E-01 1.650E+00 1.650E+00

PER 009 EU 007 2.990E-02 1.310E-01 1.500E-02

PER 009 EU 016 9.140E-01 4.000E+00 4.000E+00

PER 009 EU 019 1.570E+00 6.870E+00 6.870E+00

PER 009 EU 024 2.990E-02 1.310E-01 1.500E-02

PER 010 EU 026 9.660E-01 4.230E+00 4.230E+00

PER 009 EU 028 9.760E-01 4.280E+00 4.280E+00

PER 009 EU 030 9.780E-01 4.280E+00 4.880E+00

PER 010 EU 032 4.910E+00 2.150E+01 1.060E+00

PER 010 EU 033 4.910E+00 2.150E+01 1.060E+00

PER 009 EU 034 1.090E+00 4.780E+00 4.780E+00

PER 009 EU 035 8.070E-01 3.530E+00 3.340E+00

Page 16 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Methane

PER 009 EU 036 3.400E-02 1.490E-01 1.700E-02

PER 010 EU 037 2.440E+00 1.070E+01 5.270E-01

PER 010 EU 038 2.440E+00 1.070E+01 5.270E-01

PER 009 EU 040 1.670E+00 7.330E+00 7.330E+00

PER 009 EU 041 1.360E+00 5.970E+00 5.970E+00

PER 009 EU 042 2.980E-02 1.300E-01 1.490E-02

PER 009 EU 050 5.560E-01 2.430E+00 2.430E+00

PER 010 EU 051 5.560E-01 2.430E+00 2.430E+00

PER 010 EU 052 5.290E+00 2.320E+01 2.320E+01

PER 009 EU 053 2.250E-01 9.850E-01 9.850E-01

PER 009 EU 054 1.520E-01 6.660E-01 6.660E-01

PER 009 EU 055 2.390E-01 1.050E+00 1.050E+00

PER 009 EU 056 4.700E-01 2.060E+00 2.060E+00

PER 009 EU 057 6.610E-02 2.900E-01 2.900E-01

PER 009 EU 058 3.770E-01 1.650E+00 1.650E+00

PER 009 EU 059 2.580E-01 1.130E+00 1.130E+00

PER 009 EU 060 2.580E-01 1.130E+00 1.130E+00

PER 009 EU 061 1.980E-01 8.690E-01 8.690E-01

PER 009 EU 073 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00

PER 010 EU 075 8.930E-01 3.910E+00 3.910E+00

PER 009 EU 076 5.950E-02 2.610E-01 2.610E-01

PER 009 EU 077 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 084 7.810E-01 3.420E+00 3.420E+00

PER 010 EU 085 8.520E-01 3.730E+00 3.730E+00

PER 009 EU 093 1.590E-01 6.950E-01 6.950E-01

PER 010 EU 094 2.450E-01 1.070E+00 1.070E+00

PER 009 EU 095 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00

PER 009 EU 098 2.180E-01 9.560E-01 9.560E-01

PER 009 EU 099 9.690E-03 4.250E-02 4.250E-02

PER 009 EU 100 3.400E-02 1.490E-01 1.700E-02

PER 010 EU 102 2.100E-01 9.180E-01 9.180E-01

PER 010 EU 103 2.010E-01 8.810E-01 8.810E-01

Page 17 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Methane

PER 010 EU 104 3.700E-01 1.620E+00 1.620E+00

PER 009 EU 126 7.940E-01 3.480E+00 3.480E+00

PER 009 EU 127 3.500E-02 1.530E-01 1.530E-01

PER 009 EU 128 3.130E-02 1.370E-01 1.560E-02

PER 009 EU 129 1.610E-02 7.060E-02 8.060E-03

PER 009 EU 130 2.710E-02 1.190E-01 1.350E-02

PER 009 EU 131 8.680E-03 3.800E-02 4.340E-03

PER 009 EU 132 2.480E-02 1.090E-01 1.240E-02

PER 009 EU 198 3.220E-02 1.410E-01 1.610E-02

PER 009 EU 199 3.220E-02 1.410E-01 1.610E-02

PER 009 EU 204 4.080E-01 1.790E+00 1.350E+00

PER 009 EU 209 1.120E-01 4.890E-01 4.890E-01

PER 010 EU 212 2.710E+00 1.187E+01 1.187E+01

PER 010 EU 213 3.140E+00 1.380E+01 1.380E+01

PER 009 EU 228 9.200E+00 4.030E+01 4.030E+01

PER 009 EU 240 5.950E-02 2.610E-01 2.610E-01

PER 009 EU 241 9.910E-01 4.340E+00 4.340E+00

PER 009 EU 254 1.130E+00 4.940E+00 4.940E+00

PER 009 EU 276 1.660E+00 7.280E+00 7.280E+00

PER 009 EU 277 5.540E-01 2.430E+00 2.430E+00

PER 009 EU 294 1.590E+00 6.980E+00 6.980E+00

PER 009 EU 296 5.950E+00 2.610E+01 2.610E+01

PER 009 EU 301 5.600E-03 2.450E-02 2.450E-02

PER 009 EU 302 5.600E-03 2.450E-02 2.450E-02

PER 009 EU 303 5.600E-03 2.450E-02 2.450E-02

PER 009 EU 304 5.600E-03 2.450E-02 2.450E-02

PER 009 EU 312 5.730E-02 2.510E-01 2.860E-02

PER 009 EU 313 1.550E+00 6.810E+00 6.810E+00

PER 009 EU 324 1.080E+00 4.720E+00 4.720E+00

PER 009 EU 334 2.080E+01 9.116E+01 9.116E+01

PER 009 EU 335 2.080E+01 9.116E+01 9.116E+01

PER 009 EU 336 3.300E+01 1.440E+02 1.440E+02

PER 009 EU 337 0.000E+00 0.000E+00

PER 009 EU 348 3.110E-01 1.360E+00 1.360E+00

PER 010 EU 352 1.750E+00 7.650E+00 7.650E+00

Page 18 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Methane

PER 010 EU 353 7.190E-01 3.150E+00 3.150E+00

PER 011 EU 355 5.000E-03 1.000E-03 1.000E-03

PER 011 EU 356 5.000E-03 1.000E-03 1.000E-03

PER 011 EU 357 1.300E-02 3.000E-03 3.000E-03

PER 011 EU 358 2.600E-01 1.160E+00 1.160E+00

PER 012 EU 359 9.600E-01 4.200E+00 4.200E+00

PER 012 EU 360 5.300E-01 2.310E+00 2.310E+00

PER 012 EU 361 9.660E-02 4.200E-01 4.200E-01

PER 012 EU 362 3.610E-02 1.580E-01 1.580E-01

PER 012 FS 141 1.268E+01 5.556E+01 5.556E+01

PER 009 GP 012 3.610E-02 1.580E-01 1.580E-01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 2.280E+01 1.000E+02 1.000E+02

PER 009 GP 129 2.420E+00 1.060E+01 1.060E+01

PER 012 GP 129 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 130 1.120E+00 4.890E+01 4.890E+01

PER 012 GP 130 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 5.550E-01 2.430E+00 2.430E+00

PER 009 SV 083 2.590E+00 1.130E+01 1.130E+01

PER 010 SV 093 5.340E-01 2.340E+00 2.340E+00

PER 009 TK 517 2.250E-03 9.850E-03 9.850E-03

PER 012 TK 589 2.420E+00 1.060E+01 1.060E+01

Totals 8.373E+02 7.745E+02 0.000E+00

Cyanide compounds

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 228 3.440E+00 1.510E+01 1.510E+01

PER 007 SV 042 1.540E-04 6.750E-04 6.750E-04

PER 009 SV 093 1.230E-04 5.390E-04 5.390E-04

Totals 1.510E+01 1.510E+01 0.000E+00

Carbon Monoxide

PER 001 EU 005 4.800E+00 2.101E+01 2.101E+01

PER 001 EU 006 4.690E+00 2.056E+01 2.056E+01

PER 001 EU 007 3.320E+00 1.453E+01 1.453E+01

Page 19 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Monoxide

PER 009 EU 016 1.140E+01 4.980E+01 4.980E+01

PER 001 EU 019 9.480E+00 4.150E+01 4.150E+01

PER 001 EU 024 3.320E+00 1.453E+01 1.453E+01

PER 009 EU 026 1.199E+01 5.270E+01 5.270E+01

PER 009 EU 028 1.216E+01 5.324E+01 5.324E+01

PER 009 EU 030 1.217E+01 5.331E+01 5.331E+01

PER 009 EU 032 1.070E+01 2.310E+00 2.310E+00

PER 009 EU 033 1.070E+01 2.310E+00 2.310E+00

PER 001 EU 034 1.359E+01 5.952E+01 5.952E+01

PER 009 EU 035 1.220E+01 5.344E+01 5.344E+01

PER 001 EU 036 3.770E+00 1.650E+01 1.650E+01

PER 009 EU 037 2.144E+01 4.630E+00 4.630E+00

PER 009 EU 038 2.144E+01 4.630E+00 4.630E+00

PER 009 EU 040 2.530E+01 1.108E+02 1.110E+01

PER 009 EU 041 2.060E+01 9.023E+01 9.900E+00

PER 001 EU 042 3.300E+00 1.445E+01 1.445E+01

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.921E+00 3.030E+01 3.700E+00

PER 009 EU 051 6.920E+00 3.030E+01 3.700E+00

PER 009 EU 052 6.588E+01 2.886E+02 6.310E+01

PER 001 EU 053 2.800E+00 1.226E+01 1.226E+01

PER 001 EU 054 1.890E+00 8.300E+00 8.300E+00

PER 001 EU 055 1.890E+00 8.300E+00 8.300E+00

PER 001 EU 056 5.850E+00 2.561E+01 2.561E+01

PER 009 EU 057 8.240E-01 3.610E+00 3.610E+00

PER 009 EU 058 4.690E+00 2.056E+01 2.056E+01

PER 009 EU 059 3.210E+00 1.407E+01 1.407E+01

PER 009 EU 060 3.210E+00 1.407E+01 1.407E+01

PER 009 EU 061 2.470E+00 1.082E+01 1.082E+01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 7.410E-01 3.250E+00 3.250E+00

PER 009 EU 084 4.720E+00 2.067E+01 2.067E+01

PER 001 EU 085 5.150E+00 2.257E+01 2.257E+01

Page 20 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Monoxide

PER 001 EU 093 1.980E+00 8.660E+00 8.660E+00

PER 001 EU 094 2.720E+00 1.190E+01 1.190E+01

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 098 2.720E+00 1.190E+01 1.190E+01

PER 001 EU 100 3.770E+00 1.650E+01 1.650E+01

PER 009 EU 102 2.610E+00 1.143E+01 1.143E+01

PER 009 EU 103 2.500E+00 1.097E+01 1.097E+01

PER 001 EU 104 4.610E+00 2.020E+01 2.020E+01

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 9.880E+00 4.328E+01 4.328E+01

PER 001 EU 127 3.880E+00 1.698E+01 1.698E+01

PER 001 EU 128 3.470E+00 1.518E+01 1.518E+01

PER 009 EU 129 1.790E+00 7.830E+00 7.830E+00

PER 009 EU 130 3.000E+00 1.320E+01 1.320E+01

PER 009 EU 131 9.630E-01 4.220E+00 4.220E+00

PER 009 EU 132 2.750E+00 1.200E+01 1.200E+01

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

Page 21 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Monoxide

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 3.580E+00 1.566E+01 1.566E+01

PER 001 EU 199 3.580E+00 1.566E+01 1.566E+01

PER 001 EU 204 1.524E+01 6.673E+01 6.673E+01

PER 009 EU 209 1.400E+00 6.130E+00 6.130E+00

PER 010 EU 212 4.100E+00 1.796E+01 1.000E+01

PER 001 EU 213 4.750E+00 2.081E+01 2.081E+01

PER 001 EU 228 5.370E+02 2.352E+03 6.000E+01

PER 009 EU 240 7.420E-01 3.250E+00 3.250E+00

PER 009 EU 241 1.235E+01 5.410E+01 5.410E+01

PER 001 EU 245 2.170E+00 9.520E+00 9.520E+00

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 5.930E-01 2.600E+00 2.600E+00

PER 009 EU 277 5.930E-01 2.600E+00 2.600E+00

PER 009 EU 282 8.240E+00 2.630E+01 2.630E+01

PER 009 EU 294 1.980E+01 8.693E+01 8.693E+01

PER 009 EU 296 7.412E+01 3.250E+02 3.250E+02

Page 22 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Monoxide

PER 009 EU 301 2.090E-01 9.170E-01 9.170E-01

PER 009 EU 302 2.090E-01 9.170E-01 9.170E-01

PER 009 EU 303 2.090E-01 9.170E-01 9.170E-01

PER 009 EU 304 2.090E-01 9.170E-01 9.170E-01

PER 009 EU 312 6.350E+00 2.780E+01 2.780E+01

PER 009 EU 313 9.400E+00 4.117E+01 4.117E+01

PER 009 EU 324 1.630E+01 7.139E+01 7.100E+00

PER 009 EU 334 1.560E-01 6.846E-01 6.846E-01

PER 009 EU 335 1.560E-01 6.846E-01 6.846E-01

PER 009 EU 336 2.480E-01 1.087E+00 1.087E+00

PER 009 EU 348 3.870E+00 1.695E+01 1.695E+01

PER 010 EU 351 5.900E-01 8.000E-01

PER 010 EU 352 2.640E+00 1.156E+01 1.156E+01

PER 010 EU 353 3.260E+00 1.428E+01 1.428E+01

PER 011 EU 355 2.032E+01 5.080E+00 5.080E+00

PER 011 EU 356 2.032E+01 5.080E+00 5.080E+00

PER 011 EU 357 8.780E-01 8.810E+00 2.200E-01

PER 011 EU 358 3.280E+00 1.436E+01 1.436E+01

PER 012 EU 359 8.650E+00 1.841E+02 3.787E+01

PER 012 EU 360 6.620E+00 8.378E+01 2.899E+01

PER 012 EU 361 1.740E+00 7.600E+00 7.600E+00

PER 012 EU 362 4.860E+00 2.130E+01 2.130E+01

PER 009 GP 012 2.130E+01 2.130E+01 2.130E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 042 2.380E+01 1.040E+02 1.210E+02

PER 012 SV 042 2.630E+01 1.153E+02 1.210E+02

PER 009 SV 066 1.110E+01 4.870E+01 2.370E+01

PER 009 SV 083 3.220E+01 1.410E+02 5.000E+01

PER 009 SV 093 1.380E+02 6.040E+02 6.040E+02

PER 012 SV 093 1.520E+02 6.660E+02 6.660E+02

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

Page 23 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Monoxide

PER 009 TK 517 8.400E-02 3.680E-01 3.680E-01

Totals 5.884E+03 2.742E+03 0.000E+00

Carbon Dioxide

PER 009 EU 004 2.470E+03 1.080E+04 1.080E+04

PER 010 EU 005 1.620E+04 7.090E+04 7.090E+04

PER 010 EU 006 7.700E+03 3.370E+04 3.370E+04

PER 009 EU 007 7.370E+02 3.230E+03 3.690E+02

PER 010 EU 016 1.870E+04 8.170E+04 8.170E+04

PER 010 EU 019 3.200E+04 1.400E+05 1.400E+05

PER 009 EU 024 7.370E+02 3.230E+03 3.690E+02

PER 010 EU 026 1.970E+04 8.630E+04 8.630E+04

PER 010 EU 028 1.990E+04 8.730E+04 8.730E+04

PER 010 EU 030 2.000E+04 8.740E+04 8.740E+04

PER 010 EU 032 1.550E+03 6.780E+03 3.340E+02

PER 010 EU 033 1.550E+03 6.780E+03 3.340E+02

PER 010 EU 034 2.030E+04 8.890E+04 8.890E+04

PER 010 EU 035 1.500E+04 6.570E+04 6.570E+04

PER 009 EU 036 8.380E+02 3.670E+03 4.190E+02

PER 010 EU 037 6.070E+02 2.660E+03 1.310E+02

PER 010 EU 038 6.070E+02 2.660E+03 1.310E+02

PER 010 EU 040 3.110E+04 1.360E+05 1.360E+05

PER 010 EU 041 2.530E+04 1.110E+05 1.110E+05

PER 009 EU 042 7.340E+02 3.210E+03 3.670E+02

PER 009 EU 045 1.650E+04 7.250E+04 7.250E+04

PER 010 EU 050 1.030E+04 4.530E+04 4.530E+04

PER 010 EU 051 1.030E+04 4.530E+04 4.530E+04

PER 010 EU 052 9.840E+04 4.310E+05 4.310E+05

PER 010 EU 053 4.180E+03 1.830E+04 1.830E+04

PER 010 EU 054 3.110E+03 1.360E+04 1.360E+04

PER 010 EU 055 4.890E+03 2.140E+04 2.140E+04

PER 010 EU 056 9.590E+03 4.200E+04 4.200E+04

PER 010 EU 057 1.350E+03 5.910E+03 5.910E+03

PER 010 EU 058 7.700E+03 3.370E+04 3.370E+04

PER 010 EU 059 5.270E+03 2.310E+04 2.310E+04

PER 010 EU 060 5.270E+03 2.310E+04 2.310E+04

Page 24 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Dioxide

PER 010 EU 061 4.050E+03 1.770E+04 1.770E+04

PER 009 EU 073 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 010 EU 075 1.820E+04 7.980E+04 7.980E+04

PER 010 EU 076 1.220E+03 5.320E+03 5.320E+03

PER 009 EU 077 0.000E+00 0.000E+00

PER 010 EU 084 1.590E+04 6.980E+04 6.980E+04

PER 010 EU 085 1.580E+04 6.940E+04 6.940E+04

PER 010 EU 093 2.950E+03 1.290E+04 1.290E+04

PER 010 EU 094 4.550E+03 1.990E+04 1.990E+04

PER 009 EU 095 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00

PER 010 EU 098 4.060E+03 1.780E+04 1.780E+04

PER 009 EU 099 3.310E+02 1.450E+03 1.450E+03

PER 009 EU 100 8.380E+02 3.670E+03 4.190E+02

PER 010 EU 102 3.900E+03 1.710E+04 1.710E+04

PER 010 EU 103 3.740E+03 1.640E+04 1.640E+04

PER 010 EU 104 6.890E+03 3.020E+04 3.020E+04

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 010 EU 126 1.620E+04 7.100E+04 7.100E+04

PER 009 EU 127 8.620E+02 3.780E+03 3.780E+03

PER 009 EU 128 7.700E+02 3.370E+03 3.850E+02

PER 009 EU 129 3.970E+02 1.740E+03 1.990E+02

PER 009 EU 130 6.680E+02 2.920E+03 3.340E+02

PER 009 EU 131 2.140E+02 9.370E+02 1.070E+02

PER 009 EU 132 6.110E+02 2.680E+03 3.060E+02

PER 009 EU 198 7.950E+02 3.480E+03 3.970E+02

PER 009 EU 199 7.950E+02 3.480E+03 3.970E+02

PER 009 EU 204 2.160E+04 9.470E+04 7.140E+04

PER 009 EU 209 3.260E+03 1.430E+04 1.430E+04

PER 010 EU 212 5.270E+04 2.310E+05 2.310E+05

PER 010 EU 213 5.840E+04 2.560E+05 2.560E+05

PER 010 EU 228 2.650E+05 1.160E+06 1.160E+06

Page 25 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Carbon Dioxide

PER 010 EU 240 1.110E+03 4.850E+03 4.850E+03

PER 010 EU 241 1.840E+04 8.080E+04 8.080E+04

PER 010 EU 245 3.560E+03 1.560E+04 1.560E+04

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 254 1.200E+04 5.260E+04 5.260E+04

PER 009 EU 276 1.560E+03 6.830E+03 6.830E+03

PER 009 EU 277 1.080E+03 4.710E+03 4.710E+03

PER 010 EU 294 2.960E+04 1.300E+05 1.300E+05

PER 010 EU 296 1.110E+05 4.850E+05 4.850E+05

PER 009 EU 301 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 302 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 303 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 304 2.970E+02 1.300E+03 1.300E+03

PER 009 EU 312 1.410E+03 6.190E+03 7.060E+02

PER 010 EU 313 3.170E+04 1.390E+05 1.390E+05

PER 010 EU 324 2.000E+04 8.780E+04 8.780E+04

PER 009 EU 337 0.000E+00 0.000E+00

PER 010 EU 348 6.350E+03 2.780E+04 2.780E+04

PER 010 EU 352 3.086E+04 1.352E+05 1.352E+05

PER 010 EU 353 3.811E+04 1.669E+05 1.669E+05

PER 011 EU 355 1.041E+02 2.602E+01 2.602E+01

PER 011 EU 356 1.041E+02 2.602E+01 2.602E+01

PER 011 EU 357 2.690E+02 6.724E+01 6.724E+01

PER 011 EU 358 5.533E+03 2.423E+04 2.423E+04

PER 012 EU 359 5.079E+04 2.225E+05 2.225E+05

PER 012 EU 360 2.795E+04 1.224E+05 1.224E+05

PER 012 EU 361 7.528E+03 3.297E+04 3.297E+04

PER 012 EU 362 8.890E+02 3.890E+03 3.890E+03

PER 009 GP 012 8.890E+02 3.890E+03 3.890E+03

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 2.800E+04 1.230E+05 1.230E+05

PER 010 SV 083 4.810E+04 2.110E+05 2.110E+05

PER 010 SV 093 2.800E+04 1.230E+05 1.230E+05

PER 009 TK 517 1.190E+02 5.220E+02 5.220E+02

Totals 6.214E+06 6.136E+06 0.000E+00

Page 26 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Cobalt compounds

PER 009 EU 005 9.870E-06 4.320E-05 4.320E-05

PER 009 EU 006 4.690E-06 2.060E-05 2.060E-05

PER 009 EU 016 1.140E-05 4.980E-05 4.980E-05

PER 009 EU 019 1.950E-05 8.550E-05 8.550E-05

PER 009 EU 026 1.200E-05 5.270E-05 5.270E-05

PER 009 EU 028 1.220E-05 5.320E-05 5.320E-05

PER 009 EU 030 1.220E-05 5.330E-05 5.330E-05

PER 009 EU 034 1.360E-05 5.950E-05 5.950E-05

PER 009 EU 035 1.000E-05 4.400E-05 4.400E-05

PER 009 EU 040 2.080E-05 9.130E-05 9.130E-05

PER 009 EU 041 1.700E-05 7.430E-05 7.430E-05

PER 009 EU 050 6.920E-06 3.030E-05 3.030E-05

PER 009 EU 051 6.920E-06 3.030E-05 3.030E-05

PER 009 EU 052 6.590E-05 2.890E-04 2.890E-04

PER 009 EU 053 2.800E-06 1.230E-05 1.230E-05

PER 009 EU 054 1.890E-06 8.300E-06 8.300E-06

PER 009 EU 055 1.890E-06 8.300E-06 8.300E-06

PER 009 EU 056 5.850E-06 2.560E-05 2.560E-05

PER 009 EU 057 8.240E-07 3.610E-06 3.610E-06

PER 009 EU 058 4.690E-06 2.060E-05 2.060E-05

PER 009 EU 059 3.210E-06 1.410E-05 1.410E-05

PER 009 EU 060 3.210E-06 1.410E-05 1.410E-05

PER 009 EU 061 2.470E-06 1.080E-05 1.080E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 7.410E-07 3.250E-06 3.250E-06

PER 009 EU 084 9.720E-06 4.260E-05 4.260E-05

PER 009 EU 085 1.060E-05 4.650E-05 4.650E-05

PER 009 EU 093 1.980E-06 8.660E-06 8.660E-06

PER 009 EU 094 2.720E-06 1.190E-05 1.190E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.720E-06 1.190E-05 1.190E-05

Page 27 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Cobalt compounds

PER 009 EU 102 2.610E-06 1.140E-05 1.140E-05

PER 009 EU 103 2.500E-06 1.100E-05 1.100E-05

PER 009 EU 104 4.610E-06 2.020E-05 2.020E-05

PER 009 EU 126 9.880E-06 4.330E-05 4.330E-05

PER 001 EU 204 1.520E-05 6.670E-05 6.670E-05

PER 010 EU 212 3.380E-05 1.480E-04 1.480E-04

PER 009 EU 213 3.910E-05 1.710E-04 1.710E-04

PER 009 EU 228 1.100E-02 4.820E-02 1.450E-02

PER 009 EU 240 7.410E-07 3.250E-06 3.250E-06

PER 009 EU 241 1.230E-05 5.410E-05 5.410E-05

PER 009 EU 282 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 294 1.980E-05 8.690E-05 8.690E-05

PER 009 EU 296 7.410E-05 3.250E-04 3.250E-04

PER 009 EU 313 1.940E-05 8.480E-05 8.480E-05

PER 009 EU 324 1.340E-05 5.880E-05 5.880E-05

PER 010 EU 352 2.170E-05 9.520E-05 9.520E-05

PER 010 EU 353 2.680E-05 1.180E-04 1.180E-04

PER 011 EU 358 3.290E-06 1.440E-05 1.440E-05

PER 012 EU 359 3.600E-05 1.600E-04 1.600E-04

PER 012 EU 360 2.000E-05 8.600E-05 8.600E-05

PER 012 EU 361 3.610E-06 1.580E-05 1.580E-05

PER 009 SV 066 1.110E-05 4.870E-05 4.870E-05

PER 009 SV 083 3.220E-05 1.410E-04 1.410E-04

Totals 5.118E-02 1.748E-02 0.000E+00

Chromium compounds

PER 009 EU 005 1.650E-04 7.210E-04 7.210E-04

PER 009 EU 006 7.820E-05 3.430E-04 3.430E-04

PER 009 EU 007 3.030E-04 1.330E-03 1.330E-03

PER 009 EU 016 1.900E-04 8.310E-04 8.310E-04

PER 009 EU 019 3.250E-04 1.420E-03 1.420E-03

PER 001 EU 024 3.030E-04 1.330E-03 1.330E-03

PER 009 EU 026 2.000E-04 8.780E-04 8.780E-04

PER 009 EU 028 2.030E-04 8.870E-04 8.870E-04

PER 009 EU 030 2.030E-04 8.890E-04 8.890E-04

PER 009 EU 034 2.260E-04 9.920E-04 9.920E-04

Page 28 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Chromium compounds

PER 009 EU 035 1.670E-04 7.330E-04 7.330E-04

PER 001 EU 036 3.440E-04 1.510E-03 1.510E-03

PER 009 EU 040 3.470E-04 1.520E-03 1.520E-03

PER 009 EU 041 2.830E-04 1.240E-03 1.240E-03

PER 001 EU 042 3.020E-04 1.320E-03 1.320E-03

PER 009 EU 050 1.150E-04 5.050E-04 5.050E-04

PER 009 EU 051 1.150E-04 5.050E-04 5.050E-04

PER 009 EU 052 1.100E-03 4.810E-03 4.810E-03

PER 009 EU 053 4.670E-05 2.040E-04 2.040E-04

PER 009 EU 054 3.160E-05 1.380E-04 1.380E-04

PER 009 EU 055 3.160E-05 1.380E-04 1.380E-04

PER 009 EU 056 9.750E-05 4.270E-04 4.270E-04

PER 009 EU 057 1.370E-05 6.010E-05 6.010E-05

PER 009 EU 058 7.820E-05 3.430E-04 3.430E-04

PER 009 EU 059 5.350E-05 2.340E-04 2.340E-04

PER 009 EU 060 5.350E-05 2.340E-04 2.340E-04

PER 009 EU 061 4.120E-05 1.800E-04 1.800E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.240E-05 5.410E-05 5.410E-05

PER 009 EU 084 1.620E-04 7.090E-04 7.090E-04

PER 009 EU 085 1.770E-04 7.740E-04 7.740E-04

PER 009 EU 093 3.290E-05 1.440E-04 1.400E-04

PER 009 EU 094 4.530E-05 1.980E-04 1.980E-04

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 4.530E-05 1.980E-04 1.980E-04

PER 001 EU 100 3.440E-04 1.510E-03 1.510E-03

PER 009 EU 102 4.350E-05 1.910E-04 1.910E-04

PER 009 EU 103 4.170E-05 1.830E-04 1.830E-04

PER 009 EU 104 7.690E-05 3.370E-04 3.370E-04

PER 009 EU 126 1.650E-04 7.210E-04 7.210E-04

PER 001 EU 127 3.540E-04 1.550E-03 1.550E-03

Page 29 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Chromium compounds

PER 001 EU 128 3.170E-04 1.390E-03 1.390E-03

PER 009 EU 129 1.630E-04 7.150E-04 7.150E-04

PER 009 EU 130 2.740E-04 1.200E-03 1.200E-03

PER 009 EU 131 8.790E-05 3.850E-04 3.850E-04

PER 009 EU 132 2.510E-04 1.100E-03 1.100E-03

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 3.270E-04 1.430E-03 1.430E-03

PER 001 EU 199 3.270E-04 1.430E-03 1.430E-03

PER 001 EU 204 2.540E-04 1.110E-03 1.110E-03

PER 010 EU 212 5.630E-04 2.460E-03 2.460E-03

PER 009 EU 213 6.520E-04 2.860E-03 2.860E-03

PER 009 EU 228 1.840E-01 8.060E-01 2.420E-01

PER 009 EU 240 1.240E-05 5.410E-05 5.410E-05

PER 009 EU 241 2.060E-04 9.010E-04 9.010E-04

PER 009 EU 294 3.310E-04 1.450E-03 1.450E-03

PER 009 EU 296 1.240E-03 5.410E-03 5.410E-03

PER 009 EU 312 5.800E-04 2.540E-03 2.540E-03

PER 009 EU 313 3.230E-04 1.410E-03 1.410E-03

PER 009 EU 324 2.240E-04 9.800E-04 9.800E-04

PER 010 EU 352 3.620E-04 1.590E-03 1.590E-03

PER 010 EU 353 4.470E-04 1.960E-03 1.960E-03

PER 011 EU 358 5.490E-05 2.400E-04 2.400E-04

PER 012 EU 359 6.000E-04 2.600E-03 2.600E-03

PER 012 EU 360 3.300E-04 1.400E-03 1.400E-03

PER 012 EU 361 6.020E-05 2.630E-04 2.630E-04

PER 012 EU 362 3.200E+00 1.400E+01 1.400E+01

PER 009 GP 012 3.200E+00 1.400E+01 1.400E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 1.850E-04 8.120E-04 8.120E-04

PER 009 SV 083 5.370E-04 2.350E-03 2.350E-03

Totals 1.487E+01 1.431E+01 0.000E+00

Copper

PER 011 EU 358 3.330E-05 1.460E-04 1.460E-04

Totals 1.460E-04 1.460E-04 0.000E+00

Page 30 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Cumene

PER 009 GP 009 7.040E-03 3.080E-02 3.080E-02

Totals 3.080E-02 3.080E-02 0.000E+00

1,2-Dibromo-3-chloropropane

PER 009 GP 017 6.020E-05 1.720E-04 1.720E-04

Totals 1.720E-04 1.720E-04 0.000E+00

1,4-Dichlorobenzene

PER 009 EU 005 1.410E-04 6.180E-04 6.180E-04

PER 009 EU 006 6.710E-05 2.940E-04 2.940E-04

PER 009 EU 016 1.630E-04 7.120E-04 7.120E-04

PER 009 EU 019 2.790E-04 1.220E-03 1.220E-03

PER 009 EU 026 1.720E-04 7.520E-04 7.520E-04

PER 009 EU 028 1.740E-04 7.610E-04 7.610E-04

PER 009 EU 030 1.740E-04 7.620E-04 7.620E-04

PER 009 EU 034 1.940E-04 8.500E-04 8.500E-04

PER 009 EU 035 1.440E-04 6.290E-04 6.290E-04

PER 009 EU 040 2.980E-04 1.300E-03 1.300E-03

PER 009 EU 041 2.420E-04 1.060E-03 1.060E-03

PER 009 EU 050 9.880E-05 4.330E-04 4.330E-04

PER 009 EU 051 9.880E-05 4.330E-04 4.330E-04

PER 009 EU 052 9.410E-04 4.120E-03 4.120E-03

PER 009 EU 053 4.000E-05 1.750E-04 1.750E-04

PER 009 EU 054 2.710E-05 1.190E-04 1.190E-04

PER 009 EU 055 2.710E-05 1.190E-04 1.190E-04

PER 009 EU 056 8.350E-05 3.660E-04 3.660E-04

PER 009 EU 057 1.180E-05 5.150E-05 5.150E-05

PER 009 EU 058 6.710E-05 2.940E-04 2.940E-04

PER 009 EU 059 4.590E-05 2.010E-04 2.010E-04

PER 009 EU 060 4.590E-05 2.010E-04 2.010E-04

PER 009 EU 061 3.530E-03 1.550E-04 1.550E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.060E-05 4.640E-05 4.640E-05

PER 009 EU 084 1.390E-04 6.080E-04 6.080E-04

PER 009 EU 085 1.520E-04 6.640E-04 6.640E-04

Page 31 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

1,4-Dichlorobenzene

PER 009 EU 093 2.820E-05 1.240E-04 1.240E-04

PER 009 EU 094 3.880E-05 1.700E-04 1.700E-04

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 3.880E-05 1.700E-04 1.700E-04

PER 009 EU 102 3.730E-05 1.630E-04 1.630E-04

PER 009 EU 103 3.580E-05 1.570E-04 1.570E-04

PER 009 EU 104 6.590E-05 2.890E-04 2.890E-04

PER 009 EU 126 1.410E-04 6.180E-04 6.180E-04

PER 009 EU 204 2.180E-04 9.530E-04 9.530E-04

PER 010 EU 212 4.820E-04 2.110E-03 2.110E-03

PER 009 EU 213 5.590E-04 2.450E-03 2.450E-03

PER 009 EU 240 1.060E-05 4.640E-05 4.640E-05

PER 009 EU 241 1.760E-04 7.720E-04 7.720E-04

PER 009 EU 294 2.840E-04 1.240E-03 1.240E-03

PER 009 EU 296 1.060E-03 4.640E-03 4.640E-03

PER 009 EU 313 2.760E-04 1.210E-03 1.210E-03

PER 009 EU 324 1.920E-04 8.400E-04 8.400E-04

PER 010 EU 352 3.110E-04 1.360E-03 1.360E-03

PER 010 EU 353 3.840E-04 1.680E-03 1.680E-03

PER 011 EU 358 4.710E-05 2.060E-04 2.060E-04

PER 012 EU 359 5.100E-04 2.200E-03 2.200E-03

PER 012 EU 360 2.800E-04 1.200E-03 1.200E-03

PER 012 EU 361 5.160E-05 2.260E-04 2.260E-04

PER 009 SV 066 1.590E-04 6.960E-04 6.960E-04

PER 009 SV 083 4.600E-04 2.010E-03 2.010E-03

Totals 4.247E-02 4.247E-02 0.000E+00

1,1-Dichloroethane

PER 011 EU 355 8.480E-06 2.120E-06 2.120E-06

PER 011 EU 356 8.480E-06 2.120E-06 2.120E-06

PER 011 EU 357 2.190E-05 5.480E-06 5.480E-06

Totals 9.720E-06 9.720E-06 0.000E+00

1,2-Dichloroethane

PER 011 EU 355 8.480E-06 2.120E-06 2.120E-06

Page 32 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

1,2-Dichloroethane

PER 011 EU 356 8.480E-06 2.120E-06 2.120E-06

PER 011 EU 357 2.190E-05 5.480E-06 5.480E-06

PER 009 GP 009 1.100E-02 4.810E-02 4.810E-02

PER 009 GP 017 1.530E-03 4.380E-03 4.380E-03

Totals 5.249E-02 5.249E-02 0.000E+00

1,2-Dichloropropane

PER 011 EU 355 9.760E-06 2.440E-06 2.440E-06

PER 011 EU 356 9.760E-06 2.440E-06 2.440E-06

PER 011 EU 357 2.520E-05 6.310E-06 6.310E-06

Totals 1.119E-05 1.119E-05 0.000E+00

1,3-Dichloropropene

PER 011 EU 355 9.540E-06 2.380E-06 2.380E-06

PER 011 EU 356 9.540E-06 2.380E-06 2.380E-06

PER 011 EU 357 2.460E-05 6.160E-06 6.160E-06

Totals 1.092E-05 1.092E-05 0.000E+00

Ethylbenzene

PER 009 EU 276 9.320E+00 4.080E+01 2.040E+00

PER 009 EU 277 1.160E+01 5.060E+01 2.530E+00

PER 011 EU 355 1.860E-05 4.660E-06 4.660E-06

PER 011 EU 356 1.860E-05 4.660E-06 4.660E-06

PER 011 EU 357 4.810E-05 1.200E-05 1.200E-05

PER 012 EU 359 1.400E-02 6.100E-02 6.100E-02

PER 012 FS 141 3.570E+00 1.560E+01 1.560E+01

PER 009 GP 005 3.570E+00 1.560E+01 1.560E+01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 1.000E+00 4.400E+00 4.400E+00

PER 009 GP 017 4.480E-01 1.280E+00 1.280E+00

Totals 1.127E+02 2.591E+01 0.000E+00

Formaldehyde

PER 009 EU 005 8.820E-03 3.860E-02 3.860E-02

PER 009 EU 006 4.190E-03 1.840E-02 1.840E-02

PER 001 EU 007 3.570E-04 1.560E-03 1.560E-03

PER 009 EU 016 1.020E-02 4.450E-02 4.450E-02

PER 009 EU 019 1.740E-02 7.630E-02 7.630E-02

PER 001 EU 024 3.570E-04 1.560E-03 1.560E-03

PER 009 EU 026 1.070E-02 4.700E-02 4.700E-02

Page 33 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Formaldehyde

PER 009 EU 028 1.090E-02 4.750E-02 4.750E-02

PER 009 EU 030 1.090E-02 4.760E-02 4.760E-02

PER 009 EU 034 1.210E-02 5.310E-02 5.310E-02

PER 009 EU 035 8.970E-03 3.930E-02 3.930E-02

PER 001 EU 036 4.050E-04 1.780E-03 1.780E-03

PER 009 EU 040 1.860E-02 8.150E-02 8.150E-02

PER 009 EU 041 1.510E-02 6.630E-02 6.630E-02

PER 001 EU 042 3.550E-04 1.560E-03 1.560E-03

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.180E-03 2.710E-02 2.710E-02

PER 009 EU 051 6.180E-03 2.710E-02 2.710E-02

PER 009 EU 052 5.880E-02 2.580E-01 2.580E-01

PER 009 EU 053 2.500E-03 1.100E-02 1.100E-02

PER 009 EU 054 1.690E-03 7.410E-03 7.410E-03

PER 009 EU 055 1.690E-03 7.410E-03 7.410E-03

PER 009 EU 056 5.220E-03 2.290E-02 2.290E-02

PER 009 EU 057 7.350E-04 3.220E-03 3.220E-03

PER 009 EU 058 4.190E-03 1.840E-02 1.840E-02

PER 009 EU 059 2.870E-03 1.260E-02 1.260E-02

PER 009 EU 060 2.870E-03 1.260E-02 1.260E-02

PER 009 EU 061 2.210E-03 9.660E-03 9.660E-03

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 6.620E-04 2.900E-03 2.900E-03

PER 009 EU 084 8.680E-03 3.800E-02 3.800E-02

PER 009 EU 085 9.470E-03 4.150E-02 4.150E-02

PER 009 EU 093 1.760E-03 7.730E-03 7.730E-03

PER 009 EU 094 2.430E-03 1.060E-02 1.060E-02

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.430E-03 1.060E-02 1.060E-02

PER 001 EU 100 4.050E-04 1.780E-03 1.780E-03

PER 009 EU 102 2.330E-03 1.020E-02 1.020E-02

Page 34 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Formaldehyde

PER 009 EU 103 2.240E-03 9.790E-03 9.790E-03

PER 009 EU 104 4.120E-03 1.800E-02 1.800E-02

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 8.820E-03 3.860E-02 3.860E-02

PER 001 EU 127 4.170E-04 1.830E-03 1.830E-03

PER 001 EU 128 3.730E-04 1.630E-03 1.630E-03

PER 009 EU 129 1.920E-04 8.420E-04 8.420E-04

PER 009 EU 130 3.230E-04 1.420E-03 1.420E-03

PER 009 EU 131 1.040E-04 4.540E-04 4.540E-04

PER 009 EU 132 2.960E-04 1.300E-03 1.300E-03

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 3.850E-04 1.680E-03 1.680E-03

PER 001 EU 199 3.850E-04 1.680E-03 1.680E-03

PER 001 EU 204 1.360E-02 5.960E-02 5.960E-02

PER 010 EU 212 3.000E-02 1.320E-01 1.320E-01

PER 009 EU 213 3.490E-02 1.530E-01 1.530E-01

PER 009 EU 240 6.620E-04 2.900E-03 2.900E-03

PER 009 EU 241 1.100E-02 4.830E-02 4.830E-02

PER 009 EU 282 6.220E-02 2.730E-01 2.730E-01

PER 009 EU 294 1.770E-02 7.760E-02 7.760E-02

PER 009 EU 296 6.620E-02 2.900E-01 2.900E-01

PER 009 EU 312 6.830E-04 2.990E-03 2.990E-03

PER 009 EU 313 1.730E-02 7.570E-02 7.570E-02

PER 009 EU 324 1.200E-02 5.250E-02 5.250E-02

PER 010 EU 352 1.940E-02 8.500E-02 8.500E-02

PER 010 EU 353 2.400E-02 1.050E-01 1.050E-01

PER 011 EU 355 1.540E-02 3.850E-03 3.850E-03

PER 011 EU 356 1.540E-02 3.850E-03 3.850E-03

PER 011 EU 357 3.980E-02 9.940E-03 9.940E-03

PER 011 EU 358 2.940E-03 1.290E-02 1.290E-02

PER 012 EU 359 1.600E-01 6.900E-01 6.900E-01

PER 012 EU 360 1.800E-02 7.700E-02 7.700E-02

PER 012 EU 361 3.220E-03 1.410E-02 1.410E-02

PER 012 EU 362 3.770E+00 1.650E+01 1.650E+01

Page 35 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Formaldehyde

PER 009 GP 012 3.770E+00 1.650E+01 1.650E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 007 SV 042 2.250E-03 9.870E-03 9.870E-03

PER 012 SV 042 2.840E-03 1.240E-02 1.240E-02

PER 009 SV 066 9.930E-03 4.350E-02 4.350E-02

PER 009 SV 083 2.880E-02 1.260E-01 1.260E-01

PER 009 SV 093 2.650E-03 1.160E-02 1.160E-02

PER 012 SV 093 2.920E-03 1.280E-02 1.280E-02

Totals 2.005E+01 2.005E+01 0.000E+00

Hexane

PER 009 EU 005 2.120E-01 9.270E-01 9.270E-01

PER 009 EU 006 1.010E-01 4.410E-01 4.410E-01

PER 009 EU 016 2.440E-01 1.070E+00 1.070E+00

PER 009 EU 019 4.180E-01 1.830E+00 1.830E+00

PER 009 EU 026 2.580E-01 1.130E+00 1.130E+00

PER 009 EU 028 2.600E-01 1.140E+00 1.140E+00

PER 009 EU 030 2.610E-01 1.140E+00 1.140E+00

PER 009 EU 034 2.910E-01 1.280E+00 1.280E+00

PER 009 EU 035 2.150E-01 9.430E-01 9.430E-01

PER 009 EU 040 4.460E-01 1.960E+00 1.960E+00

PER 009 EU 041 3.640E-01 1.590E+00 1.590E+00

PER 009 EU 050 1.480E-01 6.490E-01 6.490E-01

PER 009 EU 051 1.480E-01 6.490E-01 6.490E-01

PER 009 EU 052 1.410E+00 6.180E+00 6.180E+00

PER 009 EU 053 6.000E-02 2.630E-01 2.630E-01

PER 009 EU 054 4.060E-02 1.780E-01 1.780E-01

PER 009 EU 055 4.060E-02 1.780E-01 1.780E-01

PER 009 EU 056 1.250E-01 5.490E-01 5.490E-01

PER 009 EU 057 1.760E-02 7.730E-02 7.730E-02

PER 009 EU 058 1.010E-01 4.410E-01 4.410E-01

PER 009 EU 059 6.880E-02 3.010E-01 3.010E-01

PER 009 EU 060 6.880E-02 3.010E-01 3.010E-01

PER 009 EU 061 5.290E-02 2.320E-01 2.320E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

Page 36 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Hexane

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.590E-02 6.960E-02 6.960E-02

PER 009 EU 084 2.080E-01 9.120E-01 9.120E-01

PER 009 EU 085 2.270E-01 9.960E-01 9.960E-01

PER 009 EU 093 4.240E-02 1.860E-01 1.860E-01

PER 009 EU 094 5.820E-02 2.550E-01 2.550E-01

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 5.820E-02 2.550E-01 2.550E-01

PER 009 EU 102 5.590E-02 2.450E-01 2.450E-01

PER 009 EU 103 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 104 9.880E-02 4.330E-01 4.330E-01

PER 009 EU 126 2.120E-01 9.280E-01 9.280E-01

PER 001 EU 204 3.260E-01 1.430E+00 1.430E+00

PER 010 EU 212 7.240E-01 3.170E+00 3.170E+00

PER 009 EU 213 8.380E-01 3.670E+00 3.670E+00

PER 009 EU 240 1.590E-02 6.960E-02 6.960E-02

PER 009 EU 241 2.650E-01 1.160E+00 1.160E+00

PER 009 EU 294 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 296 1.590E+00 6.960E+00 6.960E+00

PER 009 EU 313 4.150E-01 1.820E+00 1.820E+00

PER 009 EU 324 2.880E-01 1.260E+00 1.260E+00

PER 010 EU 352 4.660E-01 2.040E+00 2.040E+00

PER 010 EU 353 5.750E-01 2.520E+00 2.520E+00

PER 011 EU 358 7.060E-02 3.090E-01 3.090E-01

PER 012 EU 359 7.700E-01 3.400E+00 3.400E+00

PER 012 EU 360 4.200E-01 1.800E+00 1.800E+00

PER 012 EU 361 7.730E-02 3.400E-01 3.400E-01

PER 012 FS 141 8.870E+00 3.880E+01 3.880E+01

PER 009 GP 005 8.870E+00 3.880E+01 3.880E+01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 5.820E+00 2.550E+01 2.550E+01

PER 009 GP 017 1.700E+00 4.870E+00 4.870E+00

PER 009 SV 066 2.380E-01 1.040E+00 1.040E+00

Page 37 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Hexane

PER 009 SV 083 6.900E-01 3.020E+00 3.020E+00

Totals 1.330E+02 1.330E+02 0.000E+00

Methanol

PER 011 EU 355 2.300E-03 5.740E-04 5.740E-04

PER 011 EU 356 2.300E-03 5.740E-04 5.740E-04

PER 011 EU 357 5.940E-03 1.480E-03 1.480E-03

PER 009 SV 047 2.810E+00 1.230E+01 1.230E+01

PER 009 SV 073 8.200E-01 3.590E+00 3.590E+00

PER 009 SV 134 4.660E+00 2.040E+01 2.040E+01

PER 009 SV 166 6.370E+00 2.790E+01 2.790E+01

Totals 6.419E+01 6.419E+01 0.000E+00

Hydrogen Sulfide

PER 009 EU 004 2.842E-02 1.245E-01 1.245E-01

PER 009 EU 032 1.500E+01 3.672E-01 3.672E-01

PER 009 EU 033 1.500E+01 3.672E-01 3.672E-01

PER 009 EU 037 1.310E+01 3.326E-01 3.326E-01

PER 009 EU 038 1.310E+01 3.326E-01 3.326E-01

PER 009 EU 228 3.250E-01 1.420E+00 1.420E+00

PER 009 EU 334 2.010E+00 8.788E+00 8.788E+00

PER 009 EU 335 2.010E+00 8.788E+00 8.788E+00

PER 009 EU 336 3.160E+00 1.380E+01 1.380E+01

PER 012 EU 361 3.100E-01 1.380E+00 1.380E+00

PER 009 GP 009 1.720E+00 7.534E+00 7.534E+00

PER 009 GP 017 8.410E-02 3.680E-01 3.680E-01

PER 009 GP 115 3.976E+00 1.741E+01 1.000E+01

PER 012 GP 136 7.100E-02 3.100E-01 3.100E-01

PER 009 SV 042 1.280E+00 5.606E+00 5.606E+00

PER 009 SV 093 1.610E+00 7.052E+00 7.052E+00

PER 009 TK 367 0.000E+00 0.000E+00

PER 009 TK 368 0.000E+00 0.000E+00

PER 009 TK 515 0.000E+00 0.000E+00

Totals 7.398E+01 6.657E+01 0.000E+00

Naphthalene

PER 009 EU 005 7.170E-05 3.140E-04 3.140E-04

PER 009 EU 006 3.410E-05 1.490E-04 1.490E-04

Page 38 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Naphthalene

PER 001 EU 007 5.880E-04 2.580E-03 2.580E-03

PER 009 EU 016 8.260E-05 3.620E-04 3.620E-04

PER 009 EU 019 1.420E-04 6.210E-04 6.210E-04

PER 001 EU 024 5.880E-04 2.580E-03 2.580E-03

PER 009 EU 026 8.730E-05 3.820E-04 3.820E-04

PER 009 EU 028 8.830E-05 3.870E-04 3.870E-04

PER 009 EU 030 8.840E-05 3.870E-04 3.870E-04

PER 009 EU 034 9.870E-05 4.320E-04 4.320E-04

PER 009 EU 035 7.300E-05 3.200E-04 3.200E-04

PER 001 EU 036 6.680E-04 2.930E-03 2.930E-03

PER 009 EU 040 1.510E-04 6.630E-04 6.630E-04

PER 009 EU 041 1.230E-04 5.400E-04 5.400E-04

PER 001 EU 042 5.850E-04 2.560E-03 2.560E-03

PER 009 EU 050 5.020E-05 2.200E-04 2.200E-04

PER 009 EU 051 5.020E-05 2.200E-04 2.200E-04

PER 009 EU 052 4.780E-04 2.100E-03 2.100E-03

PER 009 EU 053 2.030E-05 8.910E-05 8.910E-05

PER 009 EU 054 1.380E-05 6.020E-05 6.020E-05

PER 009 EU 055 1.380E-05 6.020E-05 6.020E-05

PER 009 EU 056 4.250E-05 1.860E-04 1.860E-04

PER 009 EU 057 5.980E-06 2.620E-05 2.620E-05

PER 009 EU 058 3.410E-05 1.490E-04 1.490E-04

PER 009 EU 059 2.330E-05 1.020E-04 1.020E-04

PER 009 EU 060 2.330E-05 1.020E-04 1.020E-04

PER 009 EU 061 1.790E-05 7.860E-05 7.860E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 5.380E-06 2.360E-05 2.360E-05

PER 009 EU 084 7.060E-05 3.090E-04 3.090E-04

PER 009 EU 085 7.700E-05 3.370E-04 3.370E-04

PER 009 EU 093 1.440E-05 6.290E-05 6.290E-05

PER 009 EU 094 1.970E-05 8.640E-05 8.640E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

Page 39 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Naphthalene

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 1.970E-05 8.640E-05 8.640E-05

PER 001 EU 100 6.680E-04 2.930E-03 2.930E-03

PER 009 EU 102 1.900E-05 8.300E-05 8.300E-05

PER 009 EU 103 1.820E-05 7.960E-05 7.960E-05

PER 009 EU 104 3.350E-05 1.470E-04 1.470E-04

PER 009 EU 126 7.180E-05 3.140E-04 3.140E-04

PER 001 EU 127 6.870E-04 3.010E-03 3.010E-03

PER 001 EU 128 6.140E-04 2.690E-03 2.690E-03

PER 009 EU 129 3.170E-04 1.390E-03 1.390E-03

PER 009 EU 130 5.320E-04 2.330E-03 2.330E-03

PER 009 EU 131 1.710E-04 7.470E-04 7.470E-04

PER 009 EU 132 4.880E-04 2.140E-03 2.140E-03

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 6.340E-04 2.780E-03 2.780E-03

PER 001 EU 199 6.340E-04 2.780E-03 2.780E-03

PER 001 EU 204 1.110E-04 4.850E-04 4.850E-04

PER 010 EU 212 2.450E-04 1.070E-03 1.070E-03

PER 009 EU 213 2.840E-04 1.240E-03 1.240E-03

PER 009 EU 240 5.380E-06 2.360E-05 2.360E-05

PER 009 EU 241 8.960E-05 3.930E-04 3.930E-04

PER 009 EU 282 1.460E-04 6.390E-04 6.390E-04

PER 009 EU 294 1.440E-04 6.310E-04 6.310E-04

PER 009 EU 296 5.380E-04 2.360E-03 2.360E-03

PER 009 EU 312 1.130E-03 4.930E-03 4.930E-03

PER 009 EU 313 1.410E-04 6.160E-04 6.160E-04

PER 009 EU 324 9.750E-05 4.240E-04 4.240E-04

PER 010 EU 352 1.580E-04 6.920E-04 6.920E-04

PER 010 EU 353 1.950E-04 8.540E-04 8.540E-04

PER 011 EU 355 7.290E-05 1.820E-05 1.820E-05

PER 011 EU 356 7.290E-05 1.820E-05 1.820E-05

PER 011 EU 357 1.880E-04 4.710E-05 4.710E-05

PER 011 EU 358 2.390E-05 1.050E-04 1.050E-04

PER 012 EU 359 5.600E-04 2.500E-03 2.500E-03

PER 012 EU 360 1.400E-04 6.300E-04 6.300E-04

Page 40 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Naphthalene

PER 012 EU 361 2.620E-05 1.150E-04 1.150E-04

PER 012 EU 362 6.210E+00 2.720E+01 2.720E+01

PER 012 FS 141 1.420E+00 6.210E+00 6.210E+00

PER 009 GP 005 1.420E+00 6.210E+00 6.210E+00

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 8.400E-01 3.680E+00 3.680E+00

PER 009 GP 012 6.210E+00 2.720E+01 2.720E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 1.090E+01 3.100E+01 3.100E+01

PER 009 SV 066 8.070E-05 3.540E-04 3.540E-04

PER 009 SV 083 2.340E-04 1.020E-03 1.020E-03

Totals 6.815E+01 6.815E+01 0.000E+00

HAPs - Total

PER 009 EU 005 2.220E-01 9.720E-01 9.720E-01

PER 009 EU 006 1.050E-01 4.620E-01 4.620E-01

PER 001 EU 007 7.980E-03 3.490E-02 3.490E-02

PER 009 EU 016 2.560E-01 1.120E+00 1.120E+00

PER 009 EU 019 4.390E-01 1.920E+00 1.920E+00

PER 001 EU 024 7.980E-03 3.490E-02 3.490E-02

PER 009 EU 026 2.700E-01 1.180E+00 1.180E+00

PER 009 EU 028 2.730E-01 1.200E+00 1.200E+00

PER 009 EU 030 2.730E-04 1.200E+00 1.200E+00

PER 009 EU 034 3.050E-04 1.340E+00 1.340E+00

PER 009 EU 035 2.260E-01 9.890E-01 9.890E-01

PER 001 EU 036 9.060E-03 3.970E-02 3.970E-02

PER 009 EU 040 4.680E-01 2.050E+00 2.050E+00

PER 009 EU 041 3.810E-01 1.670E+00 1.670E+00

PER 001 EU 042 7.940E-03 3.480E-02 3.480E-02

PER 007 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 1.550E-01 6.810E-01 6.810E-01

PER 009 EU 051 1.550E-01 6.810E-01 6.810E-01

PER 009 EU 052 1.480E+00 6.480E+00 6.480E+00

PER 009 EU 053 6.290E-02 2.760E-01 2.760E-01

PER 009 EU 054 4.260E-02 1.860E-01 1.860E-01

PER 009 EU 055 4.260E-02 1.860E-01 1.860E-01

Page 41 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

HAPs - Total

PER 009 EU 056 1.310E-01 5.750E-01 5.750E-01

PER 009 EU 057 1.850E-02 8.100E-02 8.100E-02

PER 009 EU 058 1.050E-01 4.620E-01 4.620E-01

PER 009 EU 059 7.220E-02 3.160E-01 3.160E-01

PER 009 EU 060 7.220E-02 3.160E-01 3.160E-01

PER 009 EU 061 5.550E-02 2.430E-01 2.430E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.670E-02 7.290E-02 7.290E-02

PER 009 EU 084 2.180E-01 9.560E-01 9.560E-01

PER 009 EU 085 2.380E-01 1.040E+00 1.040E+00

PER 009 EU 093 4.440E-02 1.950E-01 1.950E-01

PER 009 EU 094 6.110E-02 2.670E-01 2.670E-01

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 6.110E-02 2.670E-01 2.670E-01

PER 001 EU 100 9.060E-03 3.970E-02 3.970E-02

PER 009 EU 102 5.870E-02 2.570E-01 2.570E-01

PER 009 EU 103 5.630E-02 2.460E-01 2.460E-01

PER 009 EU 104 1.040E-01 4.540E-01 4.540E-01

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 2.220E-01 9.730E-01 9.730E-01

PER 001 EU 127 9.330E-03 4.080E-02 4.080E-02

PER 001 EU 128 8.330E-03 3.650E-02 3.650E-02

PER 009 EU 129 4.300E-03 1.880E-02 1.880E-02

PER 009 EU 130 7.220E-03 3.160E-02 3.160E-02

PER 009 EU 131 2.310E-03 1.010E-02 1.010E-02

PER 009 EU 132 6.610E-03 2.900E-02 2.900E-02

Page 42 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

HAPs - Total

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 8.600E-03 3.770E-02 3.770E-02

PER 001 EU 199 8.600E-03 3.770E-02 3.770E-02

PER 001 EU 204 3.420E-01 1.500E+00 1.500E+00

PER 010 EU 212 7.590E-01 3.320E+00 3.320E+00

PER 009 EU 213 8.790E-01 3.850E+00 3.850E+00

PER 009 EU 228 4.260E+00 1.870E+01 1.740E+01

PER 009 EU 240 1.670E-02 7.290E-02 7.290E-02

PER 009 EU 241 2.770E-01 1.210E+00 1.210E+00

PER 009 EU 276 1.400E+02 6.120E+02 3.060E+01

PER 009 EU 277 9.850E+01 4.300E+02 2.152E+01

PER 009 EU 282 6.080E-01 2.660E+00 2.660E+00

PER 009 EU 294 4.460E-01 1.950E+00 1.950E+00

PER 009 EU 296 1.670E+00 7.290E+00 7.290E+00

PER 009 EU 312 1.530E-02 6.690E-02 6.690E-02

PER 009 EU 313 4.350E-01 1.900E+00 1.900E+00

PER 009 EU 324 3.020E-01 1.320E+00 1.321E+00

PER 010 EU 352 4.890E-01 2.140E+00 2.140E+00

PER 010 EU 353 6.030E-01 2.640E+00 2.640E+00

PER 011 EU 355 2.430E-02 6.090E-03 6.090E-03

PER 011 EU 356 2.430E-02 6.090E-03 6.090E-03

PER 011 EU 357 6.290E-02 1.570E-02 1.570E-02

PER 011 EU 358 7.550E-02 3.310E-01 3.310E-01

PER 012 EU 359 1.120E+00 4.900E+00 4.900E+00

PER 012 EU 360 4.300E-01 1.900E+00 1.900E+00

PER 012 EU 361 7.100E-01 3.130E+00 3.130E+00

PER 012 EU 362 8.430E+01 3.690E+02 3.690E+02

PER 012 FS 141 5.100E+01 2.230E+02 2.230E+02

PER 009 GP 005 5.100E+01 2.230E+02 2.230E+02

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 2.110E+01 9.249E+01 9.249E+01

PER 009 GP 012 8.430E+01 3.690E+02 3.690E+02

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 1.120E+01 3.210E+01 3.210E+01

PER 007 SV 042 1.000E+00 4.380E+00 4.380E+00

Page 43 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

HAPs - Total

PER 012 SV 042 3.870E+00 1.695E+01 1.695E+01

PER 009 SV 066 2.500E-01 1.090E+00 1.090E+00

PER 009 SV 083 7.230E-01 3.170E+00 3.170E+00

PER 009 SV 093 7.990E-01 3.500E+00 3.500E+00

PER 012 SV 093 3.980E+00 1.741E+01 1.741E+01

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

Totals 1.886E+03 8.947E+02 0.000E+00

Mercury

PER 009 EU 006 1.450E-05 6.360E-05 6.360E-05

PER 010 EU 352 6.730E-05 2.950E-04 2.950E-04

PER 010 EU 353 8.310E-05 3.640E-04 3.640E-04

PER 011 EU 358 1.020E-05 4.470E-05 4.470E-05

PER 012 EU 359 1.100E-04 4.900E-04 4.900E-04

PER 012 EU 360 6.100E-05 2.700E-04 2.700E-04

Totals 1.527E-03 1.527E-03 0.000E+00

Mercury Compounds

PER 009 EU 005 3.060E-05 1.340E-04 1.340E-04

PER 001 EU 007 1.360E-05 5.940E-05 5.940E-05

PER 009 EU 016 3.520E-05 1.540E-04 1.540E-04

PER 009 EU 019 6.040E-05 2.650E-04 2.650E-04

PER 001 EU 024 1.360E-05 5.940E-05 5.940E-05

PER 009 EU 026 3.720E-05 1.630E-04 1.630E-04

PER 009 EU 028 3.760E-05 1.650E-04 1.650E-04

PER 009 EU 030 3.770E-05 1.650E-04 1.650E-04

PER 009 EU 034 4.210E-05 1.840E-04 1.840E-04

PER 009 EU 035 3.110E-05 1.360E-04 1.360E-04

PER 001 EU 036 1.540E-05 6.750E-05 6.750E-05

PER 009 EU 040 6.450E-05 2.820E-04 2.820E-04

PER 009 EU 041 5.250E-05 2.300E-04 2.300E-04

PER 001 EU 042 1.350E-05 5.910E-05 5.910E-05

PER 009 EU 050 2.140E-05 9.380E-05 9.380E-05

PER 009 EU 051 2.140E-05 9.380E-05 9.380E-05

Page 44 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Mercury Compounds

PER 009 EU 052 2.040E-04 8.930E-04 8.930E-04

PER 009 EU 053 8.670E-06 3.800E-05 3.800E-05

PER 009 EU 054 5.860E-06 2.570E-05 2.570E-05

PER 009 EU 055 5.860E-06 2.570E-05 2.570E-05

PER 009 EU 056 1.810E-05 7.930E-05 7.930E-05

PER 009 EU 057 2.550E-06 1.120E-05 1.120E-05

PER 009 EU 058 1.450E-05 6.360E-05 6.360E-05

PER 009 EU 059 9.940E-06 4.350E-05 4.350E-05

PER 009 EU 060 9.940E-06 4.350E-05 4.350E-05

PER 009 EU 061 7.650E-06 3.350E-05 3.350E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 2.290E-06 1.000E-05 1.000E-05

PER 009 EU 084 3.010E-05 1.320E-04 1.320E-04

PER 009 EU 085 3.280E-05 1.440E-04 1.440E-04

PER 009 EU 093 6.120E-06 2.680E-05 2.680E-05

PER 009 EU 094 8.410E-06 3.680E-05 3.680E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 8.410E-06 3.680E-05 3.680E-05

PER 001 EU 100 1.540E-05 6.750E-05 6.750E-05

PER 009 EU 102 8.080E-06 3.540E-05 3.540E-05

PER 009 EU 103 7.750E-06 3.390E-05 3.390E-05

PER 009 EU 104 1.430E-05 6.250E-05 6.250E-05

PER 009 EU 126 3.060E-05 1.340E-04 1.340E-04

PER 001 EU 127 1.590E-05 6.950E-05 6.950E-05

PER 001 EU 128 1.420E-05 6.210E-05 6.210E-05

PER 009 EU 129 7.310E-06 3.200E-05 3.200E-05

PER 009 EU 130 1.230E-05 5.380E-05 5.380E-05

PER 009 EU 131 3.940E-06 1.720E-05 1.720E-05

PER 009 EU 132 1.130E-05 4.930E-05 4.930E-05

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 1.460E-05 6.410E-05 6.410E-05

Page 45 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Mercury Compounds

PER 001 EU 199 1.460E-05 6.410E-05 6.410E-05

PER 001 EU 204 4.720E-05 2.070E-04 2.070E-04

PER 010 EU 212 1.050E-04 4.580E-04 4.580E-04

PER 009 EU 213 1.210E-04 5.300E-04 5.300E-04

PER 009 EU 228 2.000E-03 8.760E-03 2.630E-03

PER 009 EU 240 2.290E-06 1.000E-05 1.000E-05

PER 009 EU 241 3.820E-05 1.670E-04 1.670E-04

PER 009 EU 294 6.140E-05 2.690E-04 2.690E-04

PER 009 EU 296 2.290E-04 1.000E-03 1.000E-03

PER 009 EU 312 2.600E-05 1.140E-04 1.140E-04

PER 009 EU 313 5.990E-05 2.620E-04 2.620E-04

PER 009 EU 324 4.150E-05 1.820E-04 1.820E-04

PER 012 EU 361 1.120E-05 4.890E-05 4.890E-05

PER 012 EU 362 1.430E-01 6.280E-01 6.280E-01

PER 009 GP 012 1.430E-01 6.280E-01 6.280E-01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 3.440E-05 1.510E-04 1.510E-04

PER 009 SV 083 9.970E-05 4.370E-04 4.370E-04

Totals 6.453E-01 6.392E-01 0.000E+00

Phenol

PER 009 GP 009 3.120E-01 1.370E+00 1.370E+00

PER 009 GP 017 4.060E-01 1.160E+00 1.160E+00

Totals 2.530E+00 2.530E+00 0.000E+00

Propylene oxide

PER 012 EU 359 1.300E-02 5.500E-02 5.500E-02

Totals 5.500E-02 5.500E-02 0.000E+00

Styrene

PER 011 EU 355 8.930E-06 2.230E-06 2.230E-06

PER 011 EU 356 8.930E-06 2.230E-06 2.230E-06

PER 011 EU 357 2.310E-05 5.770E-06 5.770E-06

Totals 1.023E-05 1.023E-05 0.000E+00

1,1,2,2-Tetrachloroethane

PER 011 EU 355 1.900E-05 4.750E-06 4.750E-06

PER 011 EU 356 1.900E-05 4.750E-06 4.750E-06

PER 011 EU 357 4.910E-05 1.230E-05 1.230E-05

Totals 2.180E-05 2.180E-05 0.000E+00

Page 46 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Toluene

PER 009 EU 005 4.000E-04 1.750E-03 1.750E-03

PER 009 EU 006 1.900E-04 8.320E-04 8.320E-04

PER 001 EU 007 1.270E-03 5.570E-03 5.570E-03

PER 009 EU 016 4.610E-04 2.020E-03 2.020E-03

PER 009 EU 019 7.900E-04 3.460E-03 3.460E-03

PER 001 EU 024 1.270E-03 5.570E-03 5.570E-03

PER 009 EU 026 4.870E-04 2.130E-03 2.130E-03

PER 009 EU 028 4.920E-04 2.150E-03 2.150E-03

PER 009 EU 030 4.930E-04 2.160E-03 2.160E-03

PER 009 EU 034 5.500E-04 2.410E-03 2.410E-03

PER 009 EU 035 4.070E-04 1.780E-03 1.780E-03

PER 001 EU 036 1.440E-03 6.320E-03 6.320E-03

PER 009 EU 040 8.430E-04 3.690E-03 3.690E-03

PER 009 EU 041 6.870E-04 3.010E-03 3.010E-03

PER 001 EU 042 1.260E-03 5.540E-03 5.540E-03

PER 009 EU 050 2.800E-04 1.230E-03 1.230E-03

PER 009 EU 051 2.800E-04 1.230E-03 1.230E-03

PER 009 EU 052 2.670E-03 1.170E-02 1.170E-02

PER 009 EU 053 1.130E-04 4.960E-04 4.960E-04

PER 009 EU 054 7.670E-05 3.360E-04 3.360E-04

PER 009 EU 055 7.670E-05 3.360E-04 3.360E-04

PER 009 EU 056 2.370E-04 1.040E-03 1.040E-03

PER 009 EU 057 3.330E-05 1.460E-04 1.460E-04

PER 009 EU 058 1.900E-04 8.320E-04 8.320E-04

PER 009 EU 059 1.300E-04 5.690E-04 5.690E-04

PER 009 EU 060 1.300E-04 5.690E-04 5.690E-04

PER 009 EU 061 1.000E-04 4.380E-04 4.380E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 3.000E-05 1.310E-04 1.310E-04

PER 009 EU 084 3.930E-04 1.720E-03 1.720E-03

PER 009 EU 085 4.290E-04 1.880E-03 1.880E-03

PER 009 EU 093 8.000E-05 3.500E-04 3.500E-04

PER 009 EU 094 1.100E-04 4.820E-04 4.820E-04

Page 47 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Toluene

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 1.100E-04 4.820E-04 4.820E-04

PER 001 EU 100 1.440E-03 6.320E-03 6.320E-03

PER 009 EU 102 1.060E-04 4.630E-04 4.630E-04

PER 009 EU 103 1.010E-04 4.440E-04 4.440E-04

PER 009 EU 104 1.870E-04 8.180E-04 8.180E-04

PER 009 EU 126 4.000E-04 1.750E-03 1.750E-03

PER 001 EU 127 1.490E-03 6.510E-03 6.510E-03

PER 001 EU 128 1.330E-03 5.820E-03 5.820E-03

PER 009 EU 129 6.850E-04 3.000E-03 3.000E-03

PER 009 EU 130 1.150E-03 5.040E-03 5.040E-03

PER 009 EU 131 3.690E-04 1.620E-03 1.620E-03

PER 009 EU 132 1.050E-03 4.620E-03 4.620E-03

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 1.370E-03 6.000E-03 6.000E-03

PER 001 EU 199 1.370E-03 6.000E-03 6.000E-03

PER 001 EU 204 6.170E-04 2.700E-03 2.700E-03

PER 010 EU 212 1.370E-03 5.990E-03 5.990E-03

PER 009 EU 213 1.580E-03 6.940E-03 6.940E-03

PER 009 EU 240 3.000E-05 1.310E-04 1.310E-04

PER 009 EU 241 5.000E-04 2.190E-03 2.190E-03

PER 009 EU 276 2.790E+01 1.220E+02 6.120E+00

PER 009 EU 277 2.310E+01 1.010E+02 5.060E+00

PER 009 EU 282 1.540E-01 6.740E-01 6.740E-01

PER 009 EU 294 8.030E-04 3.520E-03 3.520E-03

PER 009 EU 296 3.000E-03 1.310E-02 1.310E-02

PER 009 EU 312 2.430E-03 1.070E-02 1.070E-02

PER 009 EU 313 7.830E-04 3.430E-03 3.430E-03

PER 009 EU 324 5.430E-04 2.380E-03 2.380E-03

PER 010 EU 352 8.800E-04 3.850E-03 3.850E-03

PER 010 EU 353 1.090E-03 4.760E-03 4.760E-03

PER 011 EU 355 4.190E-04 1.050E-04 1.050E-04

PER 011 EU 356 4.190E-04 1.050E-04 1.050E-04

Page 48 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Toluene

PER 011 EU 357 1.080E-03 2.710E-04 2.710E-04

PER 011 EU 358 1.330E-04 5.840E-04 5.840E-04

PER 012 EU 359 5.600E-02 2.500E-01 2.500E-01

PER 012 EU 360 8.000E-04 3.500E-03 3.500E-03

PER 012 EU 361 1.460E-04 6.400E-04 6.400E-04

PER 012 EU 362 1.340E+01 5.880E+01 5.880E+01

PER 012 FS 141 1.130E+01 4.960E+01 4.960E+01

PER 009 GP 005 1.130E+01 4.960E+01 4.960E+01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 5.360E+00 2.350E+01 2.350E+01

PER 009 GP 012 1.340E+01 5.880E+01 5.880E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 8.860E+00 2.530E+01 2.530E+01

PER 009 SV 066 4.500E-04 1.970E-03 1.970E-03

PER 009 SV 083 1.300E-03 5.710E-03 5.710E-03

Totals 3.813E+02 1.695E+02 0.000E+00

1,2,4-Trichlorobenzene

PER 009 GP 017 1.240E-01 3.550E-01 3.550E-01

Totals 3.550E-01 3.550E-01 0.000E+00

1,1,2-Trichloroethane

PER 011 EU 355 1.150E-05 2.870E-06 2.870E-06

PER 011 EU 356 1.150E-05 2.870E-06 2.870E-06

PER 011 EU 357 2.970E-05 7.420E-06 7.420E-06

PER 009 GP 009 9.380E-03 4.110E-02 4.110E-02

Totals 4.111E-02 4.111E-02 0.000E+00

Vinyl chloride

PER 011 EU 355 5.390E-06 1.350E-06 1.350E-06

PER 011 EU 356 5.390E-06 1.350E-06 1.350E-06

PER 011 EU 357 1.390E-05 3.480E-06 3.480E-06

Totals 6.180E-06 6.180E-06 0.000E+00

Xylenes (mixed isomers)

PER 009 EU 007 8.730E-04 3.820E-03 3.820E-03

PER 009 EU 024 8.730E-04 3.820E-03 3.820E-03

PER 009 EU 036 9.920E-04 4.340E-03 4.340E-03

PER 009 EU 042 8.690E-04 3.800E-03 3.800E-03

PER 009 EU 100 9.920E-04 4.340E-03 4.340E-03

Page 49 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Xylenes (mixed isomers)

PER 009 EU 127 1.020E-03 4.470E-03 4.470E-03

PER 009 EU 128 9.120E-04 3.990E-03 3.990E-03

PER 009 EU 129 4.700E-04 2.060E-03 2.060E-03

PER 009 EU 130 7.900E-04 3.460E-03 3.460E-03

PER 009 EU 131 2.530E-01 1.110E-03

PER 009 EU 132 7.240E-04 3.170E-03 3.170E-03

PER 009 EU 198 9.410E-04 4.120E-03 4.120E-03

PER 009 EU 199 9.410E-04 4.120E-03 4.120E-03

PER 009 EU 276 8.380E+01 3.670E+02 1.836E+01

PER 009 EU 277 5.200E+01 2.280E+02 1.139E+01

PER 009 EU 312 1.670E-03 7.320E-03 7.320E-03

PER 011 EU 355 1.460E-04 3.660E-05 3.660E-05

PER 011 EU 356 1.460E-04 3.660E-05 3.660E-05

PER 011 EU 357 3.780E-04 9.460E-05 9.460E-05

PER 012 EU 359 2.800E-02 1.200E-01 1.200E-01

PER 012 EU 362 9.220E+00 4.040E+01 4.040E+01

PER 012 FS 141 2.160E+01 9.480E+01 9.480E+01

PER 009 GP 005 2.160E+01 9.480E+01 9.480E+01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 5.050E+00 2.210E+01 2.210E+01

PER 009 GP 012 9.220E+00 4.040E+01 4.040E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 2.000E+00 5.700E+00 5.700E+00

Totals 7.582E+02 1.929E+02 0.000E+00

2,2,4-trimethylpentane

PER 009 GP 009 2.300E-01 1.010E+00 1.010E+00

PER 009 GP 017 1.160E-01 3.310E-01 3.310E-01

Totals 1.341E+00 1.341E+00 0.000E+00

Hydrochloric acid

PER 009 EU 099 5.070E-04 2.220E-03 2.220E-03

Totals 2.220E-03 2.220E-03 0.000E+00

7,12-Dimethylbenz(a)anthracene

PER 011 EU 358 6.270E-07 2.750E-06 2.750E-06

Totals 0.000E+00 0.000E+00 0.000E+00

Page 50 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

3-Methylchloranthrene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

2-Methylnaphthalene

PER 011 EU 358 9.410E-07 4.120E-06 4.120E-06

Totals 4.120E-06 4.120E-06 0.000E+00

Manganese compounds

PER 009 EU 005 4.470E-05 1.960E-04 1.960E-04

PER 009 EU 006 2.120E-05 9.300E-05 9.300E-05

PER 001 EU 007 6.330E-05 2.770E-04 2.770E-04

PER 009 EU 016 5.150E-05 2.260E-04 2.260E-04

PER 009 EU 019 8.830E-05 3.870E-04 3.870E-04

PER 001 EU 024 6.330E-05 2.770E-04 2.770E-04

PER 009 EU 026 5.440E-05 2.380E-04 2.380E-04

PER 009 EU 028 5.500E-05 2.410E-04 2.410E-04

PER 009 EU 030 5.510E-05 2.410E-04 2.410E-04

PER 009 EU 034 6.150E-05 2.690E-04 2.690E-04

PER 009 EU 035 4.550E-05 1.990E-04 1.990E-04

PER 001 EU 036 7.190E-05 3.150E-04 3.150E-04

PER 009 EU 040 9.430E-05 4.130E-04 4.130E-04

PER 009 EU 041 7.670E-05 3.360E-04 3.360E-04

PER 001 EU 042 6.300E-05 2.760E-04 2.760E-04

PER 009 EU 050 3.130E-05 1.370E-04 1.370E-04

PER 009 EU 051 3.130E-05 1.370E-04 1.370E-04

PER 009 EU 052 2.980E-04 1.310E-03 1.310E-03

PER 009 EU 053 1.270E-05 5.550E-05 5.550E-05

PER 009 EU 054 8.570E-06 3.750E-05 3.750E-05

PER 009 EU 055 8.570E-06 3.750E-05 3.750E-05

PER 009 EU 056 2.650E-05 1.160E-04 1.160E-04

PER 009 EU 057 3.730E-06 1.630E-05 1.630E-05

PER 009 EU 058 2.120E-05 9.300E-05 9.300E-05

PER 009 EU 059 1.450E-05 6.360E-05 6.360E-05

PER 009 EU 060 1.450E-05 6.360E-05 6.360E-05

PER 009 EU 061 1.120E-05 4.900E-05 4.900E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

Page 51 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Manganese compounds

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 3.350E-06 1.470E-05 1.470E-05

PER 009 EU 084 4.400E-05 1.930E-04 1.930E-04

PER 009 EU 085 4.800E-05 2.100E-04 2.100E-04

PER 009 EU 093 8.940E-06 3.920E-05 3.920E-05

PER 009 EU 094 1.230E-05 5.380E-05 5.380E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 1.230E-05 5.380E-05 5.380E-05

PER 001 EU 100 7.190E-05 3.150E-04 3.150E-04

PER 009 EU 102 1.180E-05 5.170E-05 5.170E-05

PER 009 EU 103 1.130E-05 4.960E-05 4.960E-05

PER 009 EU 104 2.090E-05 9.140E-05 9.140E-05

PER 009 EU 126 4.470E-05 1.960E-04 1.960E-04

PER 001 EU 127 7.400E-05 3.240E-04 3.240E-04

PER 001 EU 128 6.620E-05 2.900E-04 2.900E-04

PER 009 EU 129 3.410E-05 1.490E-04 1.490E-04

PER 009 EU 130 5.730E-05 2.510E-04 2.510E-04

PER 009 EU 131 1.840E-05 8.050E-05 8.050E-05

PER 009 EU 132 5.250E-05 2.300E-04 2.300E-04

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 6.830E-05 2.990E-04 2.990E-04

PER 001 EU 199 6.830E-05 2.990E-04 2.990E-04

PER 001 EU 204 6.890E-05 3.020E-04 3.020E-04

PER 010 EU 212 1.530E-04 6.690E-04 6.690E-04

PER 009 EU 213 1.770E-04 7.750E-04 7.750E-04

PER 009 EU 228 9.800E-02 4.290E-01 1.290E-01

PER 009 EU 240 3.350E-06 1.470E-05 1.470E-05

PER 009 EU 241 5.580E-05 2.450E-04 2.450E-04

PER 009 EU 294 8.980E-05 3.930E-04 3.930E-04

PER 009 EU 296 3.350E-04 1.470E-03 1.470E-03

PER 009 EU 312 1.210E-04 5.310E-04 5.310E-04

PER 009 EU 313 8.750E-05 3.830E-04 3.830E-04

PER 009 EU 324 6.070E-05 2.660E-04 2.660E-04

Page 52 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Manganese compounds

PER 010 EU 352 9.840E-05 4.310E-04 4.310E-04

PER 010 EU 353 1.210E-04 5.320E-04 5.320E-04

PER 011 EU 358 1.490E-05 6.530E-05 6.530E-05

PER 012 EU 359 1.600E-04 7.100E-04 7.100E-04

PER 012 EU 360 8.900E-05 3.900E-04 3.900E-04

PER 012 EU 361 1.630E-05 7.150E-05 7.150E-05

PER 012 EU 362 6.690E-01 2.930E+00 2.930E+00

PER 009 GP 012 6.690E-01 2.930E+00 2.930E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 5.030E-05 2.200E-04 2.200E-04

PER 009 SV 083 1.460E-04 6.380E-04 6.380E-04

Totals 3.376E+00 3.076E+00 0.000E+00

Molybdenum

PER 011 EU 358 4.310E-05 1.890E-04 1.890E-04

Totals 0.000E+00 0.000E+00 0.000E+00

Acenaphthene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Acenaphthylene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Anthracene

PER 011 EU 358 9.410E-08 4.120E-07 4.120E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Benz(a)anthracene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 3.090E-07 3.090E-07 0.000E+00

Benzo(a)pyrene

PER 009 EU 228 1.250E-04 5.470E-04 5.470E-04

PER 011 EU 358 4.710E-08 2.060E-07 2.060E-07

Totals 5.470E-04 5.470E-04 0.000E+00

Benzo(b)fluoranthene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Page 53 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Benzo(ghi)perylene

PER 011 EU 358 4.710E-08 2.060E-07 2.060E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Benzo(k)fluoranthene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Chrysene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 0.000E+00 0.000E+00 0.000E+00

Dibenz(a,h)anthracene

PER 011 EU 358 4.710E-08 2.060E-07 2.060E-07

Totals 2.060E-07 2.060E-07 0.000E+00

Ethylene dibromide (dibromoeth

PER 011 EU 355 1.600E-05 4.000E-06 4.000E-06

PER 011 EU 356 1.600E-05 4.000E-06 4.000E-06

PER 011 EU 357 4.130E-05 1.030E-05 1.030E-05

PER 009 GP 009 1.080E-03 4.730E-03 4.730E-03

Totals 4.748E-03 4.748E-03 0.000E+00

Fluoranthene

PER 009 EU 282 8.300E-04 3.640E-03 3.640E-03

PER 011 EU 358 1.180E-07 5.150E-07 5.150E-07

Totals 3.640E-03 3.640E-03 0.000E+00

Fluorene

PER 011 EU 358 1.100E-07 4.810E-07 4.810E-07

Totals 4.810E-07 4.810E-07 0.000E+00

Nitrous Oxide

PER 009 EU 004 4.650E-03 2.040E-02 2.040E-02

PER 009 EU 005 1.590E-01 6.950E-01 6.950E-01

PER 009 EU 006 7.540E-02 3.300E-01 3.300E-01

PER 009 EU 007 5.980E-03 2.620E-02 2.990E-03

PER 009 EU 016 1.830E-01 8.010E-01 8.010E-01

PER 009 EU 019 3.130E-01 1.370E+00 1.370E+00

PER 009 EU 024 5.980E-03 2.620E-02 2.990E-03

PER 010 EU 026 1.930E-01 8.460E-01 8.460E-01

PER 009 EU 028 1.950E-01 8.550E-01 8.550E-01

PER 009 EU 030 1.960E-01 8.560E-01 8.560E-01

PER 010 EU 032 2.420E-02 1.060E-01 5.220E-03

Page 54 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrous Oxide

PER 010 EU 033 2.420E-02 1.060E-01 5.220E-03

PER 009 EU 034 2.180E-01 9.560E-01 9.560E-01

PER 009 EU 035 1.610E-01 7.070E-01 6.680E-01

PER 009 EU 036 6.800E-03 2.980E-02 3.400E-03

PER 010 EU 037 9.490E-03 4.160E-02 2.050E-03

PER 010 EU 038 9.490E-03 4.160E-02 2.050E-03

PER 009 EU 040 3.350E-01 1.470E+00 1.470E+00

PER 009 EU 041 2.720E-01 1.190E+00 1.190E+00

PER 009 EU 042 5.950E-03 2.610E-02 2.980E-03

PER 009 EU 050 1.110E-01 4.870E-01 4.870E-01

PER 010 EU 051 1.110E-01 4.870E-01 4.870E-01

PER 010 EU 052 1.060E+00 4.630E+00 4.630E+00

PER 009 EU 053 4.500E-02 1.970E-01 1.970E-01

PER 009 EU 054 3.040E-02 1.330E-01 1.330E-01

PER 009 EU 055 4.790E-02 2.100E-01 2.100E-01

PER 009 EU 056 9.390E-02 4.110E-01 4.110E-01

PER 009 EU 057 1.320E-02 5.790E-02 5.790E-02

PER 009 EU 058 7.540E-02 3.300E-01 3.300E-01

PER 009 EU 059 5.160E-02 2.260E-01 2.260E-01

PER 009 EU 060 5.160E-02 2.260E-01 2.260E-01

PER 009 EU 061 3.970E-02 1.740E-01 1.740E-01

PER 009 EU 073 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00

PER 010 EU 075 1.790E-01 7.820E-01 7.820E-01

PER 009 EU 076 1.190E-02 5.210E-02 5.210E-02

PER 009 EU 077 0.000E+00 0.000E+00

PER 009 EU 084 1.560E-01 6.840E-01 6.840E-01

PER 010 EU 085 1.700E-01 7.460E-01 7.460E-01

PER 009 EU 093 3.170E-02 1.390E-01 1.390E-01

PER 010 EU 094 4.890E-02 2.140E-01 2.140E-01

PER 009 EU 095 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00

PER 009 EU 098 4.370E-02 1.910E-01 1.910E-01

PER 009 EU 099 1.940E-03 8.490E-03 8.490E-03

Page 55 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrous Oxide

PER 009 EU 100 6.800E-03 2.980E-02 3.400E-03

PER 010 EU 102 4.190E-02 1.840E-01 1.840E-01

PER 010 EU 103 4.020E-02 1.760E-01 1.760E-01

PER 010 EU 104 7.410E-02 3.240E-01 3.240E-01

PER 009 EU 126 1.590E-01 6.950E-01 6.950E-01

PER 009 EU 127 6.990E-03 3.060E-02 3.060E-02

PER 009 EU 128 6.250E-03 2.740E-02 3.130E-03

PER 009 EU 129 3.220E-03 1.410E-02 1.610E-03

PER 009 EU 130 5.420E-03 2.370E-02 2.710E-03

PER 009 EU 131 1.740E-03 7.600E-03 8.680E-04

PER 009 EU 132 4.960E-03 2.170E-02 2.480E-03

PER 009 EU 198 6.450E-03 2.820E-02 3.220E-03

PER 009 EU 199 6.450E-03 2.820E-02 3.220E-03

PER 009 EU 204 4.080E-02 1.790E-01 1.350E-01

PER 009 EU 209 6.150E-03 2.690E-02 2.690E-02

PER 010 EU 212 5.420E-01 2.380E+00 2.380E+00

PER 010 EU 213 6.280E-01 2.750E+00 2.750E+00

PER 009 EU 228 1.840E+00 8.060E+00 8.060E+00

PER 009 EU 240 1.190E-02 5.210E-02 5.210E-02

PER 009 EU 241 1.980E-01 8.680E-01 8.680E-01

PER 009 EU 254 2.260E-02 9.920E-02 9.920E-02

PER 009 EU 276 2.940E-03 1.290E-02 1.290E-02

PER 009 EU 277 2.030E-03 8.890E-03 8.890E-03

PER 009 EU 294 3.190E-01 1.400E+00 1.400E+00

PER 009 EU 296 1.190E+00 5.210E+00 5.210E+00

PER 009 EU 301 5.600E-04 2.450E-03 2.450E-03

PER 009 EU 302 5.600E-04 2.450E-03 2.450E-03

PER 009 EU 303 5.600E-04 2.450E-03 2.450E-03

PER 009 EU 304 5.600E-04 2.450E-03 2.450E-03

PER 009 EU 312 1.150E-02 5.020E-02 5.730E-03

PER 009 EU 313 3.110E-01 1.360E+00 1.360E+00

PER 009 EU 324 2.160E-01 9.440E-01 9.440E-01

PER 009 EU 337 0.000E+00 0.000E+00

PER 009 EU 348 6.220E-02 2.720E-01 2.720E-01

PER 010 EU 352 3.490E-01 1.530E+00 1.530E+00

Page 56 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrous Oxide

PER 010 EU 353 7.190E-02 3.150E-01 3.150E-01

PER 011 EU 355 9.930E-04 2.480E-04 2.480E-04

PER 011 EU 356 9.930E-04 2.480E-04 2.480E-04

PER 011 EU 357 2.570E-03 6.420E-04 6.420E-04

PER 011 EU 358 5.000E-02 2.300E-01 2.300E-01

PER 012 EU 359 9.580E-02 4.200E-01 4.200E-01

PER 012 EU 360 5.270E-02 2.300E-01 2.300E-01

PER 012 EU 361 9.660E-03 4.230E-02 4.230E-02

PER 012 EU 362 7.210E-03 3.160E-02 3.160E-02

PER 009 GP 012 7.210E-03 3.160E-02 3.160E-02

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 1.080E-01 4.710E-01 4.710E-01

PER 009 SV 083 5.170E-01 2.270E+00 2.270E+00

PER 010 SV 093 1.030E-01 4.510E-01 4.510E-01

PER 009 TK 517 2.250E-04 9.850E-04 9.850E-04

Totals 5.215E+01 5.149E+01 0.000E+00

Indeno(1,2,3-cd)pyrene

PER 011 EU 358 7.060E-08 3.090E-07 3.090E-07

Totals 3.090E-07 3.090E-07 0.000E+00

Lead Compounds

PER 012 EU 361 2.150E-05 9.410E-05 9.410E-05

Totals 9.410E-05 9.410E-05 0.000E+00

Methylene chloride (dichlorome

PER 011 EU 355 3.090E-05 7.730E-06 7.730E-06

PER 011 EU 356 3.090E-05 7.730E-06 7.730E-06

PER 011 EU 357 7.990E-05 2.000E-05 2.000E-05

Totals 3.546E-05 3.546E-05 0.000E+00

o-Xylenes

PER 009 EU 007 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 024 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 036 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 042 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 100 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 127 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 128 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 129 0.000E+00 0.000E+00 0.000E+00

Page 57 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

o-Xylenes

PER 009 EU 130 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 131 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 132 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 198 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 199 0.000E+00 0.000E+00 0.000E+00

Totals 0.000E+00 0.000E+00 0.000E+00

Phenanthrene

PER 011 EU 358 6.670E-07 2.920E-06 2.920E-06

Totals 0.000E+00 0.000E+00 0.000E+00

Pyrene

PER 011 EU 358 1.960E-07 8.590E-07 8.590E-07

Totals 8.590E-07 8.590E-07 0.000E+00

Total Polycyclic aromatic hydr

PER 011 EU 355 1.060E-04 2.650E-05 2.650E-05

PER 011 EU 356 1.060E-04 2.650E-05 2.650E-05

PER 011 EU 357 2.740E-04 6.840E-05 6.840E-05

Totals 1.214E-04 1.214E-04 0.000E+00

Nickel compounds

PER 009 EU 005 2.470E-04 1.080E-03 1.080E-03

PER 009 EU 006 1.170E-04 5.140E-04 5.140E-04

PER 001 EU 007 7.690E-04 3.370E-03 3.370E-03

PER 009 EU 016 2.850E-04 1.250E-03 1.250E-03

PER 009 EU 019 4.880E-04 2.140E-03 2.140E-03

PER 001 EU 024 7.690E-04 3.370E-03 3.370E-03

PER 009 EU 026 3.010E-04 1.320E-03 1.320E-03

PER 009 EU 028 3.040E-04 1.330E-03 1.330E-03

PER 009 EU 030 3.040E-04 1.330E-03 1.330E-03

PER 009 EU 034 3.400E-04 1.490E-03 1.490E-03

PER 009 EU 035 2.510E-04 1.100E-03 1.100E-03

PER 001 EU 036 8.730E-04 3.830E-03 3.830E-03

PER 009 EU 040 5.210E-04 2.280E-03 2.280E-03

PER 009 EU 041 4.240E-04 1.860E-03 1.860E-03

PER 001 EU 042 7.650E-04 3.350E-03 3.350E-03

PER 009 EU 050 1.730E-04 7.570E-04 7.570E-04

PER 009 EU 051 1.730E-04 7.570E-04 7.570E-04

Page 58 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nickel compounds

PER 009 EU 052 1.650E-03 7.210E-03 7.210E-03

PER 009 EU 053 7.000E-05 3.070E-04 3.070E-04

PER 009 EU 054 4.740E-05 2.070E-04 2.070E-04

PER 009 EU 055 4.740E-05 2.070E-04 2.070E-04

PER 009 EU 056 1.460E-04 6.400E-04 6.400E-04

PER 009 EU 057 2.060E-05 9.020E-05 9.020E-05

PER 009 EU 058 1.170E-04 5.140E-04 5.140E-04

PER 009 EU 059 8.030E-05 3.520E-04 3.520E-04

PER 009 EU 060 8.030E-05 3.520E-04 3.520E-04

PER 009 EU 061 6.180E-05 2.710E-04 2.710E-04

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 1.850E-05 8.120E-05 8.120E-05

PER 009 EU 084 2.430E-04 1.060E-03 1.060E-03

PER 009 EU 085 2.650E-04 1.160E-03 1.160E-03

PER 009 EU 093 4.940E-05 2.160E-04 2.160E-04

PER 009 EU 094 6.790E-05 2.980E-04 2.980E-04

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 6.790E-05 2.980E-04 2.980E-04

PER 001 EU 100 8.730E-04 3.830E-03 3.830E-03

PER 009 EU 102 6.530E-05 2.860E-04 2.860E-04

PER 009 EU 103 6.260E-05 2.740E-04 2.740E-04

PER 009 EU 104 1.150E-04 5.050E-04 5.050E-04

PER 009 EU 126 2.470E-04 1.080E-03 1.080E-03

PER 001 EU 127 8.990E-04 3.940E-03 3.940E-03

PER 001 EU 128 8.030E-04 3.520E-03 3.520E-03

PER 009 EU 129 4.140E-04 1.810E-03 1.810E-03

PER 009 EU 130 6.960E-04 3.050E-03 3.050E-03

PER 009 EU 131 2.230E-04 9.770E-04 9.770E-04

PER 009 EU 132 6.380E-04 2.790E-03 2.790E-03

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 8.290E-04 3.630E-03 3.630E-03

Page 59 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nickel compounds

PER 001 EU 199 8.290E-04 3.630E-03 3.630E-03

PER 001 EU 204 3.810E-04 1.670E-03 1.670E-03

PER 010 EU 212 8.440E-04 3.700E-03 3.700E-03

PER 009 EU 213 9.780E-04 4.280E-03 4.280E-03

PER 009 EU 228 8.500E-02 3.720E-01 1.120E-01

PER 009 EU 240 1.850E-05 8.120E-05 8.120E-05

PER 009 EU 241 3.090E-04 1.350E-03 1.350E-03

PER 009 EU 294 4.960E-04 2.170E-03 2.170E-03

PER 009 EU 296 1.850E-03 8.120E-03 8.120E-03

PER 009 EU 312 1.470E-03 6.450E-03 6.450E-03

PER 009 EU 313 4.840E-04 2.120E-03 2.120E-03

PER 009 EU 324 3.360E-04 1.470E-03 1.470E-03

PER 010 EU 352 5.440E-04 2.380E-03 2.380E-03

PER 010 EU 353 6.710E-04 2.940E-03 2.940E-03

PER 011 EU 358 8.240E-05 3.610E-04 3.610E-04

PER 012 EU 359 8.900E-04 3.900E-03 3.900E-03

PER 012 EU 360 4.900E-04 2.200E-03 2.200E-03

PER 012 EU 361 9.020E-05 3.950E-04 3.950E-04

PER 012 EU 362 8.120E+00 3.560E+01 3.560E+01

PER 009 GP 012 8.120E+00 3.560E+01 3.560E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 2.780E-04 1.220E-03 1.220E-03

PER 009 SV 083 8.050E-04 3.530E-03 3.530E-03

Totals 3.609E+01 3.583E+01 0.000E+00

Nitrogen Oxides

PER 001 EU 005 5.400E+00 2.363E+01 2.360E+01

PER 009 EU 006 2.570E+00 1.120E+01 1.123E+01

PER 001 EU 007 1.447E+01 6.339E+01 6.339E+01

PER 009 EU 016 6.220E+00 2.720E+01 2.720E+01

PER 009 EU 019 1.070E+01 4.670E+01 4.670E+01

PER 001 EU 024 1.447E+01 6.339E+01 6.339E+01

PER 009 EU 026 6.570E+00 2.880E+01 2.870E+01

PER 009 EU 028 4.052E+01 1.775E+02 1.775E+02

PER 009 EU 030 4.057E+01 1.777E+02 1.777E+02

PER 009 EU 032 2.300E+00 4.970E-01 4.970E-01

Page 60 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrogen Oxides

PER 009 EU 033 2.300E+00 4.970E-01 4.970E-01

PER 009 EU 034 4.529E+01 1.984E+02 1.984E+02

PER 009 EU 035 1.460E+01 6.410E+01 6.410E+01

PER 001 EU 036 1.644E+01 7.201E+01 7.201E+01

PER 009 EU 037 2.290E+00 4.950E-01 4.950E-01

PER 009 EU 038 2.290E+00 4.950E-01 4.950E-01

PER 009 EU 040 1.139E+01 4.987E+01 4.987E+01

PER 009 EU 041 9.270E+00 4.060E+01 4.060E+01

PER 001 EU 042 1.440E+01 6.307E+01 6.307E+01

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.720E+00 2.943E+01 2.943E+01

PER 009 EU 051 6.720E+00 2.943E+01 2.943E+01

PER 009 EU 052 8.000E+01 3.504E+02 3.504E+02

PER 009 EU 053 4.760E+00 2.080E+01 2.080E+01

PER 001 EU 054 6.330E+00 2.770E+01 2.770E+01

PER 001 EU 055 6.330E+00 2.770E+01 2.770E+01

PER 009 EU 056 3.200E+00 1.399E+01 1.399E+01

PER 009 EU 057 2.750E+00 1.200E+01 1.200E+01

PER 009 EU 058 1.568E+01 6.866E+01 6.866E+01

PER 009 EU 059 1.073E+01 4.698E+01 4.698E+01

PER 009 EU 060 1.073E+01 4.698E+01 4.698E+01

PER 009 EU 061 8.250E+00 3.614E+01 3.614E+01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 076 2.480E+00 1.084E+01 1.084E+01

PER 009 EU 084 5.310E+00 2.326E+01 2.280E+01

PER 001 EU 085 5.800E+00 2.539E+01 2.539E+01

PER 009 EU 093 2.880E+00 1.261E+01 1.261E+01

PER 009 EU 094 1.490E+00 6.500E+00 6.500E+00

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 1.490E+00 6.500E+00 6.500E+00

PER 001 EU 100 1.644E+01 7.201E+01 7.201E+01

Page 61 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrogen Oxides

PER 009 EU 102 3.800E+00 1.666E+01 1.666E+01

PER 009 EU 103 3.650E+00 1.600E+01 1.600E+01

PER 009 EU 104 2.520E+00 1.104E+01 1.220E+01

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 5.400E+00 2.370E+01 2.370E+01

PER 009 EU 127 1.740E+01 7.621E+01 2.180E+01

PER 001 EU 128 1.512E+01 6.623E+01 6.623E+01

PER 009 EU 129 7.800E+00 3.420E+01 3.420E+01

PER 009 EU 130 1.310E+01 5.740E+01 5.740E+01

PER 009 EU 131 4.200E+00 1.840E+01 1.840E+01

PER 009 EU 132 1.200E+01 5.260E+01 5.260E+01

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

Page 62 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrogen Oxides

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 198 1.560E+01 6.833E+01 6.833E+01

PER 001 EU 199 1.560E+01 6.833E+01 6.833E+01

PER 009 EU 204 3.700E+01 1.621E+02 3.990E+01

PER 009 EU 209 4.670E+00 2.040E+01 2.040E+01

PER 010 EU 212 1.845E+01 8.081E+01 1.650E+01

PER 009 EU 213 2.000E+01 7.490E+01 7.490E+01

PER 009 EU 228 8.590E+02 3.762E+03 5.000E+02

PER 001 EU 240 2.480E+00 1.084E+01 1.084E+01

PER 009 EU 241 4.122E+01 1.806E+02 1.806E+02

PER 001 EU 245 7.250E+00 3.174E+01 3.174E+01

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 276 1.980E+00 8.660E+00 8.660E+00

PER 001 EU 277 1.980E+00 8.660E+00 8.660E+00

PER 009 EU 282 2.750E+01 8.770E+01 8.770E+01

PER 009 EU 294 1.080E+01 4.750E+01 4.750E+01

PER 009 EU 296 4.050E+01 1.774E+02 1.580E+02

PER 009 EU 301 2.490E-01 1.090E+00 1.090E+00

PER 009 EU 302 2.490E-01 1.090E+00 1.090E+00

PER 009 EU 303 2.490E-01 1.090E+00 1.090E+00

PER 001 EU 304 2.490E-01 1.090E+00 1.090E+00

PER 009 EU 312 2.772E+01 1.214E+02 1.214E+02

PER 009 EU 313 1.058E+01 4.632E+01 4.632E+01

PER 009 EU 324 7.340E+00 3.213E+01 3.210E+01

Page 63 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Nitrogen Oxides

PER 009 EU 348 1.293E+01 5.661E+01 5.661E+01

PER 010 EU 351 9.300E-01 1.000E+00

PER 010 EU 352 1.056E+01 4.625E+01 1.100E+01

PER 010 EU 353 1.304E+01 5.712E+01 1.090E+01

PER 011 EU 355 6.300E-01 1.600E-01 1.600E-01

PER 011 EU 356 6.300E-01 1.600E-01 1.600E-01

PER 011 EU 357 3.040E-01 7.610E-02 7.610E-02

PER 011 EU 358 5.680E+00 2.489E+01 2.489E+01

PER 012 EU 359 3.580E+00 1.039E+02 1.567E+01

PER 012 EU 360 2.740E+00 8.378E+01 1.200E+01

PER 012 EU 361 7.660E+00 3.353E+01 3.353E+01

PER 012 EU 362 2.250E+01 9.870E+01 9.870E+01

PER 009 GP 012 2.253E+01 9.870E+01 9.870E+01

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 9.610E+00 4.210E+01 4.210E+01

PER 009 SV 066 6.080E+00 2.660E+01 2.960E+01

PER 009 SV 083 1.760E+01 7.710E+01 7.706E+01

PER 009 SV 093 2.060E+01 9.020E+01 9.017E+01

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 001 TK 517 2.800E-01 1.230E+00 1.230E+00

Totals 8.054E+03 4.295E+03 0.000E+00

PM < 2.5 micron

PER 009 EU 005 8.930E-01 3.910E+00 3.910E+00

PER 009 EU 006 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 007 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 016 1.030E+00 4.510E+00 4.510E+00

PER 009 EU 019 1.770E+00 7.730E+00 7.730E+00

PER 009 EU 024 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 026 1.090E+00 4.760E+00 4.760E+00

PER 009 EU 028 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 030 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 032 1.210E+00 2.610E-01 2.610E-01

Page 64 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 2.5 micron

PER 009 EU 033 1.210E+00 2.610E-01 2.610E-01

PER 009 EU 034 1.230E+00 5.380E+00 5.380E+00

PER 009 EU 035 9.090E-01 3.980E+00 3.980E+00

PER 009 EU 036 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 037 4.730E-01 1.020E-01 1.020E-01

PER 009 EU 038 4.730E-01 1.020E-01 1.020E-01

PER 009 EU 040 1.890E+00 8.260E+00 8.260E+00

PER 009 EU 041 1.530E+00 6.720E+00 6.720E+00

PER 009 EU 042 4.200E-01 1.840E+00 1.840E+00

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 051 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 052 5.960E+00 2.611E+01 2.611E+01

PER 009 EU 053 2.530E-01 1.110E+00 1.110E+00

PER 009 EU 054 1.710E-01 7.510E-01 7.510E-01

PER 009 EU 055 1.710E-01 7.510E-01 7.510E-01

PER 009 EU 056 5.290E-01 2.320E+00 2.320E+00

PER 009 EU 057 7.450E-02 3.260E-01 3.260E-01

PER 009 EU 058 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 059 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 060 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 061 2.240E-01 9.790E-01 9.790E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 084 8.790E-01 3.850E+00 3.850E+00

PER 009 EU 085 9.600E-01 4.200E+00 4.200E+00

PER 009 EU 093 1.790E-01 7.830E-01 7.830E-01

PER 009 EU 094 2.460E-01 1.080E+00 1.080E+00

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.460E-01 1.080E+00 1.080E+00

PER 009 EU 100 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 102 2.360E-01 1.030E+00 1.030E+00

PER 009 EU 103 2.270E-01 9.920E-01 9.920E-01

Page 65 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 2.5 micron

PER 009 EU 104 4.170E-01 1.830E+00 1.830E+00

PER 009 EU 126 8.940E-01 3.920E+00 3.920E+00

PER 009 EU 127 4.940E-01 2.160E+00 2.160E+00

PER 009 EU 128 4.410E-01 1.930E+00 1.930E+00

PER 009 EU 129 2.280E-01 9.960E-01 9.960E-01

PER 009 EU 130 3.820E-01 1.670E+00 1.670E+00

PER 009 EU 131 1.230E-01 5.370E-01 5.370E-01

PER 009 EU 132 3.500E-01 1.530E+00 1.530E+00

PER 009 EU 198 4.550E-01 1.990E+00 1.990E+00

PER 009 EU 199 4.550E-01 1.990E+00 1.990E+00

PER 009 EU 204 1.380E+00 6.040E+00 6.040E+00

PER 009 EU 209 1.270E-01 5.550E-01 5.550E-01

PER 010 EU 212 3.050E+00 1.338E+01 1.338E+01

PER 009 EU 213 3.540E+00 1.550E+01 1.550E+01

PER 009 EU 228 2.000E+02 8.770E+02 2.630E+02

PER 009 EU 240 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 241 1.120E+00 4.890E+00 4.890E+00

PER 009 EU 245 1.970E-01 8.620E-01 8.620E-01

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 268 1.480E-03 6.490E-03 6.490E-03

PER 009 EU 269 1.760E-03 7.700E-03 7.700E-03

PER 009 EU 270 1.370E-03 5.990E-03 5.990E-03

PER 009 EU 271 1.370E-03 5.990E-03 5.990E-03

PER 010 EU 272 2.030E-03 8.900E-03 8.900E-03

PER 009 EU 276 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 277 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 282 7.450E-01 2.380E+00 2.380E+00

PER 009 EU 294 1.800E+00 7.870E+00 7.870E+00

PER 009 EU 296 6.710E+00 2.937E+01 2.937E+01

PER 009 EU 301 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 302 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 303 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 304 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 312 8.090E-01 3.540E+00 3.540E+00

PER 009 EU 313 1.750E+00 7.670E+00 7.670E+00

Page 66 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 2.5 micron

PER 009 EU 324 1.210E+00 5.320E+00 5.320E+00

PER 008 EU 325 9.000E-01 1.970E+00 1.970E+00

PER 008 EU 326 6.000E-01 1.310E+00 1.310E+00

PER 009 EU 334 1.450E+00 6.353E+00 6.353E+00

PER 009 EU 335 1.450E+00 6.353E+00 6.353E+00

PER 009 EU 336 2.300E+00 1.007E+01 1.007E+01

PER 009 EU 348 3.500E-01 1.530E+00 1.530E+00

PER 010 EU 351 1.500E-02 6.500E-02

PER 010 EU 352 1.970E+00 8.620E+00 8.620E+00

PER 010 EU 353 2.430E+00 1.064E+01 1.064E+01

PER 010 EU 354 7.360E-04 3.220E-03 3.220E-03

PER 011 EU 355 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 356 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 357 3.770E-02 9.400E-03 9.400E-03

PER 011 EU 358 3.100E-01 1.340E+00 1.340E+00

PER 012 EU 359 2.480E+00 1.085E+01 1.085E+01

PER 012 EU 360 1.360E+00 5.970E+00 5.970E+00

PER 012 EU 361 1.350E+00 6.550E+00 5.890E+00

PER 012 EU 362 1.600E+00 7.010E+00 7.010E+00

PER 010 FS 009 4.620E+00 2.020E+01 1.320E+01

PER 009 GP 012 7.010E+00 7.010E+00 7.010E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 010 SV 042 5.690E+00 2.490E+01 2.490E+01

PER 012 SV 042 6.280E+00 2.752E+01 2.752E+01

PER 009 SV 066 1.010E+00 4.410E+00 4.410E+00

PER 009 SV 083 2.910E+00 1.280E+01 1.280E+01

PER 010 SV 093 5.850E+00 2.560E+01 2.560E+01

PER 012 SV 093 6.450E+00 2.823E+01 2.823E+01

PER 009 TK 517 7.600E-03 3.330E-02 3.330E-02

Totals 1.288E+03 6.661E+02 0.000E+00

Lead

PER 009 EU 005 5.880E-05 2.570E-04 2.570E-04

PER 009 EU 006 2.790E-05 1.220E-04 1.220E-04

PER 009 EU 016 6.770E-05 2.970E-04 2.970E-04

PER 009 EU 019 1.160E-04 5.090E-04 5.090E-04

Page 67 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Lead

PER 009 EU 026 7.160E-05 3.130E-04 3.130E-04

PER 009 EU 028 7.240E-05 3.170E-04 3.170E-04

PER 009 EU 030 7.250E-05 3.170E-04 3.170E-04

PER 009 EU 032 9.280E-03 2.000E-03 2.000E-03

PER 009 EU 033 9.280E-03 2.000E-03 2.000E-03

PER 009 EU 034 8.090E-05 3.540E-04 3.540E-04

PER 009 EU 035 5.980E-05 2.620E-04 2.620E-04

PER 009 EU 037 3.640E-03 7.860E-04 7.860E-04

PER 001 EU 038 3.640E-03 7.860E-04 7.860E-04

PER 009 EU 040 1.240E-04 5.430E-04 5.430E-04

PER 009 EU 041 1.010E-04 4.420E-04 4.420E-04

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 4.120E-05 1.800E-04 1.800E-04

PER 009 EU 051 4.120E-05 1.800E-04 1.800E-04

PER 009 EU 052 3.900E-04 1.720E-03 1.720E-03

PER 009 EU 053 1.670E-05 7.300E-05 7.300E-05

PER 009 EU 054 1.130E-05 4.940E-05 4.940E-05

PER 009 EU 055 1.130E-05 4.940E-05 4.940E-05

PER 009 EU 056 3.480E-05 1.520E-04 1.520E-04

PER 009 EU 057 4.900E-06 2.150E-05 2.150E-05

PER 009 EU 058 2.790E-05 1.220E-04 1.220E-04

PER 009 EU 059 1.910E-05 8.370E-05 8.370E-05

PER 009 EU 060 1.910E-05 8.370E-05 8.370E-05

PER 009 EU 061 1.470E-05 6.440E-05 6.440E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 4.410E-06 1.930E-05 1.930E-05

PER 009 EU 084 5.780E-05 2.530E-04 2.530E-04

PER 009 EU 085 6.310E-05 2.770E-04 2.770E-04

PER 009 EU 093 1.180E-05 5.150E-05 5.150E-05

PER 009 EU 094 1.620E-05 7.090E-05 7.090E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

Page 68 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Lead

PER 009 EU 098 1.620E-05 7.090E-05 7.090E-05

PER 009 EU 102 1.550E-05 6.810E-05 6.810E-05

PER 009 EU 103 1.490E-05 6.530E-05 6.530E-05

PER 009 EU 104 2.750E-05 1.200E-04 1.200E-04

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 5.880E-04 2.580E-03 2.580E-03

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

Page 69 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Lead

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 001 EU 204 9.070E-05 3.970E-04 3.970E-04

PER 009 EU 209 8.330E-06 3.650E-05 3.650E-05

PER 010 EU 212 2.010E-04 8.800E-04 8.800E-04

PER 009 EU 213 2.330E-04 1.020E-03 1.020E-03

PER 009 EU 228 1.200E-02 5.260E-02 1.580E-02

PER 009 EU 240 4.410E-06 1.930E-05 1.930E-05

PER 009 EU 241 7.350E-05 3.220E-04 3.220E-04

PER 009 EU 245 1.290E-05 5.670E-05 5.670E-05

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 3.530E-06 1.550E-05 1.550E-05

PER 009 EU 277 3.530E-06 1.550E-05 1.550E-05

PER 009 EU 282 4.900E-05 1.560E-04 1.560E-04

PER 009 EU 294 1.180E-04 5.170E-04 5.170E-04

PER 009 EU 296 4.410E-04 1.930E-03 1.930E-03

PER 009 EU 301 1.250E-06 5.460E-06 5.460E-06

PER 009 EU 302 1.250E-06 5.460E-06 5.460E-06

PER 009 EU 303 1.250E-06 5.460E-06 5.460E-06

PER 009 EU 304 1.250E-06 5.460E-06 5.460E-06

PER 009 EU 313 1.150E-04 5.050E-04 5.050E-04

PER 009 EU 324 7.990E-05 3.500E-04 3.500E-04

PER 009 EU 348 2.300E-04 1.010E-03 1.010E-03

PER 010 EU 351 2.900E-05 9.830E-06

PER 010 EU 352 1.290E-04 5.670E-04 5.670E-04

PER 010 EU 353 1.600E-04 7.000E-04 7.000E-04

PER 011 EU 358 1.960E-05 8.590E-05 8.590E-05

PER 012 EU 359 2.130E-04 9.330E-04 9.330E-04

PER 012 EU 360 1.170E-04 5.130E-04 5.130E-04

PER 010 FS 009 8.650E-03 3.790E-02 3.790E-02

PER 010 SV 042 3.860E-05 1.690E-04 1.690E-04

Page 70 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Lead

PER 009 SV 066 6.620E-05 2.900E-04 2.900E-04

PER 009 SV 083 1.920E-04 8.400E-04 8.400E-04

PER 009 SV 093 3.680E-05 1.610E-04 1.610E-04

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 517 5.000E-07 2.190E-06 2.190E-06

Totals 1.176E-01 8.083E-02 0.000E+00

PM < 10 micron

PER 009 EU 005 8.930E-01 3.910E+00 3.910E+00

PER 009 EU 006 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 007 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 016 1.030E+00 4.510E+00 4.510E+00

PER 001 EU 019 1.770E+00 7.730E+00 7.730E+00

PER 009 EU 024 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 026 1.090E+00 4.760E+00 4.760E+00

PER 009 EU 028 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 030 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 032 1.210E+00 2.610E-01 2.610E-01

PER 009 EU 033 1.210E+00 2.610E-01 2.610E-01

PER 001 EU 034 1.230E+00 5.380E+00 5.380E+00

PER 009 EU 035 9.090E-01 3.980E+00 3.980E+00

PER 001 EU 036 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 037 4.730E-01 1.020E-01 1.020E-01

PER 009 EU 038 4.730E-01 1.020E-01 1.020E-01

PER 001 EU 040 1.890E+00 8.260E+00 8.260E+00

PER 009 EU 041 1.530E+00 6.720E+00 6.720E+00

PER 001 EU 042 4.200E-01 1.840E+00 1.840E+00

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 051 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 052 5.960E+00 2.611E+01 9.150E+00

PER 009 EU 053 2.530E-01 1.110E+00 1.110E+00

PER 009 EU 054 1.710E-01 7.510E-01 7.510E-01

Page 71 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 10 micron

PER 009 EU 055 1.710E-01 7.510E-01 7.510E-01

PER 009 EU 056 5.290E-01 2.320E+00 2.320E+00

PER 009 EU 057 7.450E-02 3.260E-01 3.260E-01

PER 009 EU 058 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 059 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 060 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 061 2.240E-01 9.790E-01 9.790E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 084 8.790E-01 3.850E+00 3.850E+00

PER 009 EU 085 9.600E-01 4.200E+00 4.200E+00

PER 009 EU 093 1.790E-01 7.830E-01 7.830E-01

PER 009 EU 094 2.460E-01 1.080E+00 1.080E+00

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.460E-01 1.080E+00 1.080E+00

PER 001 EU 100 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 102 2.360E-01 1.030E+00 1.030E+00

PER 009 EU 103 2.270E-01 9.920E-01 9.920E-01

PER 009 EU 104 4.170E-01 1.830E+00 1.830E+00

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 8.940E-01 3.920E+00 3.920E+00

PER 009 EU 127 4.940E-01 2.160E+00 2.160E+00

PER 009 EU 128 4.410E-01 1.930E+00 1.930E+00

PER 009 EU 129 2.280E-01 9.960E-01 9.960E-01

PER 009 EU 130 3.820E-01 1.670E+00 1.670E+00

PER 009 EU 131 1.230E-01 5.370E-01 5.370E-01

Page 72 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 10 micron

PER 009 EU 132 3.500E-01 1.530E+00 1.530E+00

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 198 4.550E-01 1.990E+00 1.990E+00

PER 009 EU 199 4.550E-01 1.990E+00 1.990E+00

PER 001 EU 204 1.380E+00 6.040E+00 6.040E+00

PER 009 EU 209 1.270E-01 5.550E-01 5.550E-01

PER 010 EU 212 3.050E+00 1.338E+01 1.338E+01

Page 73 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 10 micron

PER 009 EU 213 3.540E+00 1.550E+01 1.550E+01

PER 009 EU 228 4.230E-01 1.850E+00 1.850E+00

PER 009 EU 240 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 241 1.120E+00 4.890E+00 4.890E+00

PER 009 EU 245 1.970E-01 8.620E-01 8.620E-01

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 268 3.320E-01 1.450E+00 1.450E+00

PER 009 EU 269 3.930E-01 1.720E+00 1.720E+00

PER 009 EU 270 3.060E-01 1.340E+00 1.340E+00

PER 009 EU 271 3.060E-01 1.340E+00 1.340E+00

PER 010 EU 272 4.550E-01 1.990E+00 1.990E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 277 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 282 7.450E-01 2.380E+00 2.380E+00

PER 009 EU 294 1.800E+00 7.870E+00 7.870E+00

PER 009 EU 296 6.710E+00 2.937E+01 2.937E+01

PER 009 EU 301 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 302 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 303 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 304 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 312 8.090E-01 3.540E+00 3.540E+00

PER 009 EU 313 1.750E+00 7.670E+00 7.670E+00

PER 009 EU 324 1.210E+00 5.320E+00 5.320E+00

PER 008 EU 325 9.000E-01 1.970E+00 1.970E+00

PER 008 EU 326 6.000E-01 1.310E+00 1.310E+00

PER 009 EU 334 1.450E+00 6.353E+00 6.353E+00

PER 009 EU 335 1.450E+00 6.353E+00 6.353E+00

PER 009 EU 336 2.300E+00 1.007E+01 1.007E+01

PER 009 EU 348 3.500E-01 1.530E+00 1.530E+00

PER 010 EU 351 5.400E-02 7.300E-02

PER 010 EU 352 1.970E+00 8.620E+00 8.620E+00

PER 010 EU 353 2.430E+00 1.064E+01 1.064E+01

PER 010 EU 354 1.650E-01 7.210E-01 7.210E-01

Page 74 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

PM < 10 micron

PER 011 EU 355 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 356 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 357 3.770E-02 9.400E-03 9.400E-03

PER 011 EU 358 3.100E-01 1.340E+00 1.340E+00

PER 012 EU 359 2.480E+00 1.085E+01 1.085E+01

PER 012 EU 360 1.360E+00 5.970E+00 5.970E+00

PER 012 EU 361 1.350E+00 2.357E+01 5.890E+00

PER 012 EU 362 1.600E+00 7.010E+00 7.010E+00

PER 010 FS 009 8.300E+01 3.630E+02 1.192E+02

PER 009 GP 012 7.010E+00 7.010E+00 7.010E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 001 GP 015 5.500E+01 2.409E+02 1.530E+00

PER 010 SV 042 5.690E+00 2.490E+01 2.490E+01

PER 012 SV 042 6.280E+00 2.752E+01 2.752E+01

PER 009 SV 066 1.010E+00 4.410E+00 4.410E+00

PER 009 SV 083 2.910E+00 1.280E+01 1.280E+01

PER 010 SV 093 5.850E+00 2.560E+01 2.560E+01

PER 012 SV 093 6.450E+00 2.823E+01 2.823E+01

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 517 7.600E-03 3.330E-02 3.330E-02

Totals 1.022E+03 5.041E+02 0.000E+00

Polycyclic organic matter

PER 009 EU 005 1.040E-05 4.540E-05 4.540E-05

PER 009 EU 006 4.930E-06 2.160E-05 2.160E-05

PER 009 EU 016 1.200E-05 5.230E-05 5.230E-05

PER 009 EU 019 2.050E-05 8.980E-05 8.980E-05

PER 009 EU 026 1.260E-05 5.530E-05 5.530E-05

PER 009 EU 028 1.280E-05 5.590E-05 5.590E-05

PER 009 EU 030 1.280E-05 5.600E-05 5.600E-05

PER 009 EU 034 1.430E-05 6.250E-05 6.250E-05

PER 009 EU 035 1.050E-05 4.620E-05 4.620E-05

PER 009 EU 040 2.190E-05 9.580E-05 9.580E-05

Page 75 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Polycyclic organic matter

PER 009 EU 041 1.780E-05 7.800E-05 7.800E-05

PER 009 EU 050 7.260E-06 3.180E-05 3.180E-05

PER 009 EU 051 7.260E-06 3.180E-05 3.180E-05

PER 009 EU 052 6.920E-05 3.030E-04 3.030E-04

PER 009 EU 053 2.940E-06 1.290E-05 1.290E-05

PER 009 EU 054 1.990E-06 8.710E-06 8.710E-06

PER 009 EU 055 1.990E-06 8.710E-06 8.710E-06

PER 009 EU 056 6.140E-06 2.690E-05 2.690E-05

PER 009 EU 057 8.650E-07 3.790E-06 3.790E-06

PER 009 EU 058 4.930E-06 2.160E-05 2.160E-05

PER 009 EU 059 3.370E-06 1.480E-05 1.480E-05

PER 009 EU 060 3.370E-06 1.480E-05 1.480E-05

PER 009 EU 061 2.590E-06 1.140E-05 1.140E-05

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 7.780E-07 3.410E-06 3.410E-06

PER 009 EU 084 1.020E-05 4.470E-05 4.470E-05

PER 009 EU 085 1.110E-05 4.880E-05 4.880E-05

PER 009 EU 093 2.080E-06 9.090E-06 9.090E-06

PER 009 EU 094 2.850E-06 1.250E-05 1.250E-05

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.850E-06 1.250E-05 1.250E-05

PER 009 EU 102 2.740E-06 1.200E-05 1.200E-05

PER 009 EU 103 2.630E-06 1.150E-05 1.150E-05

PER 009 EU 104 4.840E-06 2.120E-05 2.120E-05

PER 009 EU 126 1.040E-05 4.540E-05 4.540E-05

PER 001 EU 204 1.600E-05 7.010E-05 7.010E-05

PER 010 EU 212 3.550E-05 1.550E-04 1.550E-04

PER 009 EU 213 4.110E-05 1.800E-04 1.800E-04

PER 009 EU 228 1.050E-03 4.600E-03 4.600E-03

PER 009 EU 240 7.780E-07 3.410E-06 3.410E-06

PER 009 EU 241 1.300E-05 5.680E-05 5.680E-05

Page 76 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Polycyclic organic matter

PER 009 EU 294 2.080E-05 9.130E-05 9.130E-05

PER 009 EU 296 7.780E-05 3.410E-04 3.410E-04

PER 009 EU 313 2.030E-05 8.900E-05 8.900E-05

PER 009 EU 324 1.410E-05 6.170E-05 6.170E-05

PER 010 EU 352 2.280E-05 1.000E-04 1.000E-04

PER 010 EU 353 2.820E-05 1.230E-04 1.230E-04

PER 012 EU 359 9.600E-04 4.200E-03 4.200E-03

PER 012 EU 360 2.100E-05 9.100E-05 9.100E-05

PER 012 EU 361 3.790E-06 1.660E-05 1.660E-05

PER 012 FS 141 3.460E+00 1.510E+01 1.510E+01

PER 009 GP 005 3.460E+00 1.510E+01 1.510E+01

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 066 1.170E-05 5.110E-05 5.110E-05

PER 009 SV 083 3.380E-05 1.480E-04 1.480E-04

Totals 1.511E+01 1.511E+01 0.000E+00

Total Particulate Matter

PER 009 EU 005 8.930E-01 3.910E+00 3.910E+00

PER 009 EU 006 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 007 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 016 1.030E+00 4.510E+00 4.510E+00

PER 001 EU 019 1.770E+00 7.730E+00 7.730E+00

PER 009 EU 024 4.220E-01 1.850E+00 1.850E+00

PER 009 EU 026 1.090E+00 4.760E+00 4.760E+00

PER 009 EU 028 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 030 1.100E+00 4.820E+00 4.820E+00

PER 009 EU 032 2.320E+00 5.010E-01 5.010E-01

PER 009 EU 033 2.320E+00 5.010E-01 5.010E-01

PER 001 EU 034 1.230E+00 5.380E+00 5.380E+00

PER 009 EU 035 9.090E-01 3.980E+00 3.980E+00

PER 001 EU 036 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 037 9.100E-01 1.970E-01 1.970E-01

PER 009 EU 038 9.100E-01 1.970E-01 1.970E-01

PER 001 EU 040 1.890E+00 8.260E+00 8.260E+00

PER 009 EU 041 1.530E+00 6.720E+00 6.720E+00

PER 001 EU 042 4.200E-01 1.840E+00 1.840E+00

Page 77 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Total Particulate Matter

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 051 6.260E-01 2.740E+00 2.740E+00

PER 009 EU 052 5.960E+00 2.611E+01 9.150E+00

PER 009 EU 053 2.530E-01 1.110E+00 1.110E+00

PER 009 EU 054 1.710E-01 7.510E-01 7.510E-01

PER 009 EU 055 1.710E-01 7.510E-01 7.510E-01

PER 009 EU 056 5.290E-01 2.320E+00 2.320E+00

PER 009 EU 057 7.450E-02 3.260E-01 3.260E-01

PER 009 EU 058 4.250E-01 1.860E+00 1.860E+00

PER 009 EU 059 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 060 2.910E-01 1.270E+00 1.270E+00

PER 009 EU 061 2.240E-01 9.790E-01 9.790E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 084 8.790E-01 3.850E+00 3.850E+00

PER 009 EU 085 9.600E-01 4.200E+00 4.200E+00

PER 009 EU 093 1.790E-01 7.830E-01 7.830E-01

PER 009 EU 094 2.460E-01 1.080E+00 1.080E+00

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.460E-01 1.080E+00 1.080E+00

PER 001 EU 100 4.800E-01 2.100E+00 2.100E+00

PER 009 EU 102 2.360E-01 1.030E+00 1.030E+00

PER 009 EU 103 2.270E-01 9.920E-01 9.920E-01

PER 009 EU 104 4.170E-01 1.830E+00 1.830E+00

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

Page 78 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Total Particulate Matter

PER 009 EU 126 8.940E-01 3.920E+00 3.920E+00

PER 009 EU 127 4.940E-01 2.160E+00 2.160E+00

PER 009 EU 128 4.410E-01 1.930E+00 1.930E+00

PER 009 EU 129 2.280E-01 9.960E-01 9.960E-01

PER 009 EU 130 3.820E-01 1.670E+00 1.670E+00

PER 009 EU 131 1.230E-01 5.370E-01 5.370E-01

PER 009 EU 132 3.500E-01 1.530E+00 1.530E+00

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

Page 79 of 9211 December, 2014 16:10

Show: Active and Pending Records 

# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Total Particulate Matter

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 198 4.550E-01 1.990E+00 1.990E+00

PER 009 EU 199 4.550E-01 1.990E+00 1.990E+00

PER 001 EU 204 1.380E+00 6.040E+00 6.040E+00

PER 009 EU 209 1.270E-01 5.550E-01 5.550E-01

PER 010 EU 212 3.050E+00 1.338E+01 1.338E+01

PER 001 EU 213 3.540E+00 1.550E+01 1.550E+01

PER 009 EU 228 2.000E+02 8.770E+02 1.690E+02

PER 009 EU 240 6.710E-02 2.940E-01 2.940E-01

PER 009 EU 241 1.120E+00 4.890E+00 4.890E+00

PER 009 EU 245 1.970E-01 8.620E-01 8.620E-01

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 268 7.060E-01 3.090E+00 3.090E+00

PER 009 EU 269 8.370E-01 3.670E+00 3.670E+00

PER 009 EU 270 6.520E-01 2.850E+00 2.850E+00

PER 009 EU 271 6.520E-01 2.850E+00 2.850E+00

PER 010 EU 272 9.680E-01 4.240E+00 4.240E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 277 5.360E-02 2.350E-01 2.350E-01

PER 009 EU 282 7.450E-01 2.380E+00 2.380E+00

PER 009 EU 294 1.800E+00 7.870E+00 7.870E+00

PER 009 EU 296 6.710E+00 2.937E+01 2.937E+01

PER 009 EU 301 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 302 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 303 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 304 1.890E-02 8.300E-02 8.300E-02

PER 009 EU 312 8.090E-01 3.540E+00 3.540E+00

PER 009 EU 313 1.750E+00 7.670E+00 7.670E+00

PER 009 EU 324 1.210E+00 5.320E+00 5.320E+00

PER 008 EU 325 3.000E+00 6.570E+00 6.570E+00

PER 008 EU 326 2.000E+00 4.380E+00 4.380E+00

PER 009 EU 348 3.500E-01 1.530E+00 1.530E+00

PER 010 EU 352 1.970E+00 8.620E+00 8.620E+00

Page 80 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Total Particulate Matter

PER 010 EU 353 2.430E+00 1.064E+01 1.064E+01

PER 010 EU 354 3.500E-01 1.530E+00 1.530E+00

PER 011 EU 355 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 356 1.460E-02 3.600E-03 3.600E-03

PER 011 EU 357 3.770E-02 9.400E-03 9.400E-03

PER 011 EU 358 3.100E-01 1.340E+00 1.340E+00

PER 012 EU 359 2.480E+00 1.085E+01 1.085E+01

PER 012 EU 360 1.360E+00 5.970E+00 5.970E+00

PER 012 EU 361 4.800E-01 2.109E+01 2.110E+00

PER 012 EU 362 1.600E+00 7.010E+00 7.010E+00

PER 010 FS 009 2.860E+02 1.251E+03 3.793E+02

PER 009 GP 012 7.010E+00 7.010E+00 7.010E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 001 GP 015 6.850E+01 3.000E+02 2.880E+00

PER 010 SV 042 5.690E+00 2.490E+01 2.490E+01

PER 012 SV 042 6.280E+00 2.752E+01 2.752E+01

PER 009 SV 066 1.010E+00 4.410E+00 4.410E+00

PER 009 SV 083 2.910E+00 1.280E+01 1.280E+01

PER 010 SV 093 5.850E+00 2.560E+01 2.560E+01

PER 012 SV 093 6.450E+00 2.823E+01 2.823E+01

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 517 7.600E-03 3.330E-02 3.330E-02

Totals 2.837E+03 9.241E+02 0.000E+00

Sulfuric Acid Mist

PER 010 EU 352 1.940E-03 8.510E-03 8.510E-03

PER 010 EU 353 2.400E-03 1.050E-02 1.050E-02

Totals 1.901E-02 1.901E-02 0.000E+00

Antimony compounds

PER 009 EU 228 3.900E-04 1.710E-03 5.120E-04

Totals 1.710E-03 5.120E-04 0.000E+00

Selenium compounds

PER 009 EU 005 2.820E-06 1.240E-05 1.240E-05

Page 81 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Selenium compounds

PER 009 EU 006 1.340E-06 5.870E-06 5.870E-06

PER 009 EU 016 3.250E-06 1.420E-05 1.420E-05

PER 009 EU 019 5.580E-06 2.440E-05 2.440E-05

PER 009 EU 026 3.440E-06 1.500E-05 1.500E-05

PER 009 EU 028 3.470E-06 1.520E-05 1.520E-05

PER 009 EU 030 3.480E-06 1.520E-05 1.520E-05

PER 009 EU 034 3.880E-06 1.700E-05 1.700E-05

PER 009 EU 035 2.870E-06 1.260E-05 1.260E-05

PER 009 EU 040 5.950E-06 2.610E-05 2.610E-05

PER 009 EU 041 4.850E-06 2.120E-05 2.120E-05

PER 009 EU 050 1.980E-06 8.660E-06 8.660E-06

PER 009 EU 051 1.980E-06 8.660E-06 8.660E-06

PER 009 EU 052 1.880E-05 8.240E-05 8.240E-05

PER 009 EU 053 8.000E-07 3.500E-06 3.500E-06

PER 009 EU 054 5.410E-07 2.370E-06 2.370E-06

PER 009 EU 055 5.410E-07 2.370E-06 2.370E-06

PER 009 EU 056 1.670E-06 7.320E-06 7.320E-06

PER 009 EU 057 2.350E-07 1.030E-06 1.030E-06

PER 009 EU 058 1.340E-06 5.870E-06 5.870E-06

PER 009 EU 059 9.180E-07 4.020E-06 4.020E-06

PER 009 EU 060 9.180E-07 4.020E-06 4.020E-06

PER 009 EU 061 7.060E-07 3.090E-06 3.090E-06

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 2.120E-07 9.280E-07 9.280E-07

PER 009 EU 084 2.780E-06 1.220E-05 1.220E-05

PER 009 EU 085 3.030E-06 1.330E-05 1.330E-05

PER 009 EU 093 5.650E-07 2.470E-06 2.470E-06

PER 009 EU 094 7.760E-07 3.400E-06 3.400E-06

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 7.760E-07 3.400E-06 3.400E-06

PER 009 EU 102 7.460E-07 3.270E-06 3.270E-06

Page 82 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Selenium compounds

PER 009 EU 103 7.150E-07 3.130E-06 3.130E-06

PER 009 EU 104 1.320E-06 5.770E-06 5.770E-06

PER 009 EU 126 2.820E-06 1.240E-05 1.240E-05

PER 001 EU 204 4.350E-06 1.910E-05 1.910E-05

PER 010 EU 212 9.650E-06 4.230E-05 4.230E-05

PER 009 EU 213 1.120E-05 4.900E-05 4.900E-05

PER 009 EU 228 4.100E-03 1.800E-02 5.390E-03

PER 009 EU 240 2.120E-07 9.280E-07 9.280E-07

PER 009 EU 241 3.530E-06 1.540E-05 1.540E-05

PER 009 EU 294 5.670E-06 2.480E-05 2.480E-05

PER 009 EU 296 2.120E-05 9.280E-05 9.280E-05

PER 009 EU 313 5.530E-06 2.420E-05 2.420E-05

PER 009 EU 324 3.840E-06 1.680E-05 1.680E-05

PER 010 EU 352 6.210E-06 2.720E-05 2.720E-05

PER 010 EU 353 7.670E-06 3.360E-05 3.360E-05

PER 011 EU 358 9.410E-07 4.120E-06 4.120E-06

PER 012 EU 359 1.000E-05 4.500E-05 4.500E-05

PER 012 EU 360 5.600E-06 2.500E-05 2.500E-05

PER 012 EU 361 1.030E-06 4.520E-06 4.520E-06

PER 009 SV 066 3.180E-06 1.390E-05 1.390E-05

PER 009 SV 083 9.200E-06 4.030E-05 4.030E-05

Totals 1.885E-02 6.242E-03 0.000E+00

Sulfur Dioxide

PER 009 EU 005 5.070E+00 1.200E+01 5.590E+01

PER 001 EU 006 2.410E+00 5.700E+00 5.700E+00

PER 009 EU 007 2.410E-01 1.060E+00 1.060E+00

PER 009 EU 016 5.850E+00 1.380E+01 1.380E+01

PER 009 EU 019 1.000E+01 2.370E+01 1.530E+01

PER 009 EU 024 2.410E-01 1.060E+00 1.060E+00

PER 009 EU 026 6.180E+00 1.457E+01 2.860E+01

PER 009 EU 028 6.240E+00 1.477E+01 2.390E+01

PER 009 EU 030 6.250E+00 1.479E+01 1.479E+01

PER 009 EU 032 8.000E+00 1.728E+00 1.728E+00

PER 009 EU 033 8.000E+00 1.728E+00 1.728E+00

PER 009 EU 034 1.274E+01 5.579E+01 4.250E+01

Page 83 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Sulfur Dioxide

PER 009 EU 035 9.420E+00 4.130E+01 4.130E+01

PER 009 EU 036 2.740E-01 1.200E+00 1.200E+00

PER 009 EU 037 1.010E+01 2.181E+00 2.181E+00

PER 009 EU 038 1.010E+01 2.181E+00 2.181E+00

PER 009 EU 040 1.953E+01 8.550E+01 8.550E+01

PER 009 EU 041 1.590E+01 6.966E+01 6.966E+01

PER 009 EU 042 2.400E-01 1.050E+00 1.050E+00

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 6.480E+00 2.840E+01 2.840E+01

PER 009 EU 051 6.480E+00 2.840E+01 2.840E+01

PER 009 EU 052 6.176E+01 2.705E+02 2.705E+02

PER 009 EU 053 2.620E+00 1.150E+01 1.150E+01

PER 009 EU 054 9.730E-01 2.300E+00 2.300E+00

PER 009 EU 055 1.240E-01 5.430E-01 5.430E-01

PER 001 EU 056 3.000E+00 7.100E+00 7.100E+00

PER 009 EU 057 4.230E-01 1.000E+00 1.000E+00

PER 009 EU 058 2.410E+00 5.700E+00 5.700E+00

PER 009 EU 059 1.650E+00 3.900E+00 3.900E+00

PER 009 EU 060 1.650E+00 3.900E+00 3.900E+00

PER 009 EU 061 1.270E+00 3.000E+00 3.000E+00

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 3.810E-01 9.000E-01 9.000E-01

PER 009 EU 084 9.110E+00 3.990E+01 1.650E+02

PER 009 EU 085 9.940E+00 4.355E+01 1.680E+02

PER 009 EU 093 1.850E+00 8.120E+00 8.120E+00

PER 009 EU 094 2.550E+00 1.116E+01 1.116E+01

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 2.550E+00 1.116E+01 1.116E+01

PER 009 EU 099 7.000E-03 3.070E-02 3.070E-02

PER 009 EU 100 2.740E-01 1.200E+00 1.200E+00

PER 009 EU 102 2.450E+00 1.072E+01 1.072E+01

Page 84 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Sulfur Dioxide

PER 009 EU 103 2.350E+00 1.028E+01 1.028E+01

PER 009 EU 104 4.320E+00 1.894E+01 1.894E+01

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 5.080E+00 1.200E+01 1.902E+02

PER 009 EU 127 2.820E-01 1.240E+00 1.240E+00

PER 009 EU 128 2.520E-01 1.100E+00 1.100E+00

PER 009 EU 129 1.300E-01 5.690E-01 5.690E-01

PER 009 EU 130 2.180E-01 9.570E-01 9.570E-01

PER 009 EU 131 7.000E-02 3.070E-01 3.070E-01

PER 009 EU 132 2.000E-01 8.760E-01 8.760E-01

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

Page 85 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Sulfur Dioxide

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 198 2.600E-01 1.140E+00 1.140E+00

PER 009 EU 199 2.600E-01 1.140E+00 1.140E+00

PER 009 EU 204 1.220E-01 5.320E-01 5.320E-01

PER 009 EU 209 1.120E-02 4.890E-02 4.890E-02

PER 010 EU 212 1.734E+01 4.102E+01 2.520E+01

PER 009 EU 213 3.667E+01 1.606E+02 1.606E+02

PER 001 EU 228 1.500E+03 6.570E+03 8.000E+02

PER 009 EU 240 6.950E-01 3.040E+00 3.040E+00

PER 009 EU 241 1.157E+01 5.069E+01 5.069E+01

PER 001 EU 245 2.300E+02 1.007E+03 1.007E+03

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 4.730E-03 2.070E-02 2.070E-02

PER 009 EU 277 4.730E-03 2.070E-02 2.070E-02

PER 009 EU 282 5.070E+01 2.220E+02 3.800E+01

PER 009 EU 294 1.861E+01 8.149E+01 8.149E+01

PER 009 EU 296 6.948E+01 3.043E+02 3.043E+02

PER 009 EU 301 1.670E-03 7.310E-03 7.310E-03

PER 009 EU 302 1.670E-03 7.310E-03 7.310E-03

PER 009 EU 303 1.670E-03 7.310E-03 7.310E-03

PER 009 EU 304 1.670E-03 7.310E-03 7.310E-03

PER 009 EU 312 4.600E-01 2.020E+00 2.020E+00

PER 009 EU 313 9.940E+00 1.306E+01 1.306E+01

PER 009 EU 324 1.258E+01 5.512E+01 5.512E+01

PER 009 EU 348 2.180E+00 5.150E+00 5.150E+00

Page 86 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Sulfur Dioxide

PER 010 EU 351 7.900E-02 2.000E-02

PER 010 EU 352 1.220E+01 5.350E+01 1.000E+01

PER 010 EU 353 2.140E-01 9.380E-01 9.380E-01

PER 011 EU 355 4.410E-04 1.100E-04 1.100E-04

PER 011 EU 356 4.410E-04 1.100E-04 1.100E-04

PER 011 EU 357 1.140E-03 2.850E-04 2.850E-04

PER 011 EU 358 1.160E+00 1.318E+02 5.070E+00

PER 012 EU 359 6.100E-01 2.660E+00 2.660E+00

PER 012 EU 360 3.300E-01 1.470E+00 1.470E+00

PER 012 EU 361 5.000E+00 1.971E+01 1.971E+01

PER 012 EU 362 1.490E+00 6.530E+00 6.530E+00

PER 009 GP 012 6.530E+00 6.530E+00 6.530E+00

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 042 4.610E+03 2.017E+04 4.098E+02

PER 012 SV 042 5.089E+03 2.229E+04 4.098E+02

PER 009 SV 066 5.710E+00 1.350E+01 1.350E+01

PER 009 SV 083 3.020E+01 1.320E+02 1.320E+02

PER 009 SV 093 4.740E+03 2.075E+04 3.243E+02

PER 012 SV 093 5.220E+03 2.286E+04 3.243E+02

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 328 2.030E+00 4.940E+00 4.940E+00

PER 009 TK 329 2.030E+00 4.940E+00 4.940E+00

PER 009 TK 517 6.700E-04 2.930E-03 2.930E-03

Totals 5.394E+04 3.854E+03 0.000E+00

Sulfur - Total Reduced

PER 009 TK 367 0.000E+00 0.000E+00

PER 009 TK 368 0.000E+00 0.000E+00

PER 009 TK 515 0.000E+00 0.000E+00

Totals 0.000E+00 0.000E+00 0.000E+00

Volatile Organic Compounds

PER 009 EU 005 6.470E-01 2.830E+00 2.830E+00

PER 009 EU 006 3.070E-01 1.350E+00 1.350E+00

Page 87 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Volatile Organic Compounds

PER 009 EU 007 3.860E-01 1.690E+00 1.690E+00

PER 009 EU 016 7.450E-01 3.260E+00 3.260E+00

PER 001 EU 019 1.280E+00 5.600E+00 5.600E+00

PER 009 EU 024 3.860E-01 1.690E+00 1.690E+00

PER 009 EU 026 7.870E-01 3.450E+00 3.450E+00

PER 009 EU 028 7.960E-01 3.490E+00 3.490E+00

PER 009 EU 030 7.970E-01 3.490E+00 3.490E+00

PER 009 EU 032 2.320E+00 5.010E-01 5.010E-01

PER 009 EU 033 2.320E+00 5.010E-01 5.010E-01

PER 001 EU 034 8.900E-01 3.900E+00 3.900E+00

PER 009 EU 035 6.580E-01 2.880E+00 2.880E+00

PER 009 EU 036 4.380E-01 1.920E+00 1.920E+00

PER 009 EU 037 9.100E-01 1.970E-01 1.970E-01

PER 009 EU 038 9.100E-01 1.970E-01 1.970E-01

PER 001 EU 040 1.360E+00 5.980E+00 5.980E+00

PER 009 EU 041 1.110E+00 4.870E+00 4.870E+00

PER 009 EU 042 3.840E-01 1.680E+00 1.680E+00

PER 009 EU 045 0.000E+00 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 050 4.530E-01 1.980E+00 1.980E+00

PER 009 EU 051 4.530E-01 1.980E+00 1.980E+00

PER 006 EU 052 4.310E+00 1.889E+01 1.889E+01

PER 009 EU 053 1.830E-01 8.030E-01 8.030E-01

PER 009 EU 054 1.240E-01 5.430E-01 5.430E-01

PER 001 EU 055 1.200E-01 5.400E-01 5.400E-01

PER 009 EU 056 3.830E-01 1.680E+00 1.680E+00

PER 009 EU 057 5.390E-02 2.360E-01 2.360E-01

PER 009 EU 058 3.070E-01 1.350E+00 1.350E+00

PER 009 EU 059 2.100E-01 9.210E-01 9.210E-01

PER 009 EU 060 2.100E-01 9.210E-01 9.210E-01

PER 009 EU 061 1.620E-01 7.090E-01 7.090E-01

PER 009 EU 073 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 074 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 075 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 076 4.850E-02 2.130E-01 2.130E-01

PER 009 EU 084 6.360E-01 2.790E+00 2.790E+00

Page 88 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Volatile Organic Compounds

PER 009 EU 085 6.950E-01 3.040E+00 3.040E+00

PER 009 EU 093 1.290E-01 5.670E-01 5.670E-01

PER 009 EU 094 1.780E-01 7.790E-01 7.790E-01

PER 009 EU 095 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 096 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 097 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 098 1.780E-01 7.790E-01 7.790E-01

PER 009 EU 100 4.380E-01 1.920E+00 1.920E+00

PER 009 EU 102 1.710E-01 7.490E-01 7.490E-01

PER 009 EU 103 1.640E-01 7.180E-01 7.180E-01

PER 009 EU 104 3.020E-01 1.320E+00 1.320E+00

PER 009 EU 111 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 112 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 121 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 122 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 123 0.000E+00 0.000E+00 0.000E+00

PER 007 EU 124 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 126 6.470E-01 2.830E+00 2.830E+00

PER 009 EU 127 4.510E-01 1.980E+00 1.980E+00

PER 009 EU 128 4.030E-01 1.770E+00 1.770E+00

PER 009 EU 129 2.080E-01 9.110E-01 9.110E-01

PER 009 EU 130 3.490E-01 1.530E+00 1.530E+00

PER 009 EU 131 1.120E-01 4.910E-01 4.910E-01

PER 009 EU 132 3.200E-01 1.400E+00 1.400E+00

PER 009 EU 133 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 144 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 145 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 146 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 147 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 148 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 149 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 152 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 153 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 154 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 155 0.000E+00 0.000E+00 0.000E+00

Page 89 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Volatile Organic Compounds

PER 009 EU 156 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 157 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 158 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 159 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 160 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 161 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 162 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 163 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 164 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 165 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 166 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 167 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 168 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 169 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 170 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 171 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 172 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 173 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 198 4.160E-01 1.820E+00 1.820E+00

PER 009 EU 199 4.160E-01 1.820E+00 1.820E+00

PER 009 EU 204 9.980E-01 4.370E+00 4.370E+00

PER 009 EU 209 9.170E-02 4.020E-01 4.020E-01

PER 010 EU 212 2.210E+00 9.680E+00 9.680E+00

PER 009 EU 213 8.080E-01 3.540E+00 3.540E+00

PER 001 EU 228 3.000E+00 1.310E+01 1.310E+01

PER 009 EU 240 4.850E-02 2.120E-01 2.120E-01

PER 009 EU 241 8.080E-01 3.540E+00 3.540E+00

PER 009 EU 245 1.140E+00 4.990E+00 4.990E+00

PER 012 EU 245 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 268 1.690E+00 7.410E+00 7.410E+00

PER 009 EU 269 2.010E+00 8.790E+00 8.790E+00

PER 009 EU 270 1.560E+00 6.840E+00 6.840E+00

PER 009 EU 271 1.560E+00 6.840E+00 6.840E+00

PER 010 EU 272 2.730E+00 1.196E+01 1.196E+01

PER 009 EU 274 0.000E+00 0.000E+00 0.000E+00

Page 90 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Volatile Organic Compounds

PER 009 EU 275 0.000E+00 0.000E+00 0.000E+00

PER 009 EU 276 1.340E+03 5.880E+03 2.940E+02

PER 009 EU 277 2.830E+02 1.240E+03 6.218E+01

PER 001 EU 282 3.420E+00 1.498E+01 1.498E+01

PER 009 EU 294 1.300E+00 5.690E+00 5.690E+00

PER 009 EU 296 4.850E+00 2.126E+01 2.126E+01

PER 009 EU 301 1.370E-02 6.000E-02 6.000E-02

PER 009 EU 302 1.370E-02 6.000E-02 6.000E-02

PER 009 EU 303 1.370E-02 6.000E-02 6.000E-02

PER 001 EU 304 1.370E-02 6.000E-02 6.000E-02

PER 009 EU 312 7.390E-01 3.240E+00 3.240E+00

PER 009 EU 313 1.270E+00 5.550E+00 5.550E+00

PER 009 EU 324 8.790E-01 3.850E+00 3.850E+00

PER 009 EU 334 3.990E+00 1.747E+01 1.747E+01

PER 009 EU 335 3.990E+00 1.747E+01 1.747E+01

PER 009 EU 336 6.290E+00 2.753E+01 2.753E+01

PER 009 EU 347 2.380E+00 4.330E+00 4.330E+00

PER 009 EU 348 2.530E-01 1.110E+00 1.110E+00

PER 010 EU 350 2.210E+01 4.400E+00

PER 010 EU 352 1.320E+00 5.780E+00 5.780E+00

PER 010 EU 353 1.760E+00 7.700E+00 7.700E+00

PER 010 EU 354 1.680E+00 7.360E+00 7.360E+00

PER 011 EU 355 2.200E-01 6.000E-02 6.000E-02

PER 011 EU 356 2.200E-01 6.000E-02 6.000E-02

PER 011 EU 357 1.520E-02 1.000E-01 3.810E-03

PER 011 EU 358 4.400E-01 1.910E+00 1.910E+00

PER 012 EU 359 4.050E+00 3.612E+01 1.774E+01

PER 012 EU 360 2.350E+00 2.095E+01 1.028E+01

PER 012 EU 361 4.500E-01 1.970E+00 1.970E+00

PER 012 EU 362 1.820E+00 7.990E+00 7.990E+00

PER 012 FS 141 3.040E+02 1.331E+03 1.331E+03

PER 010 GP 005 3.059E+02 1.326E+03 1.326E+03

PER 012 GP 005 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 009 9.380E+01 4.110E+02 4.110E+02

PER 009 GP 012 7.990E+00 7.990E+00 7.990E+00

Page 91 of 9211 December, 2014 16:10

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# FACILITY DESCRIPTION: Potential-to-emit (by pollutant)

Retired

By (Action) Added

By (Action) Item Pollutant Actual

Emissions (tons per yr) Limited

Potential (tons per yr) Unrestricted

Potential (tons per yr) Hourly

Potential (lbs per hr) AQD Facility ID: 03700011

Facility Name: Flint Hills Resources Pine Bend Refinery MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194

Volatile Organic Compounds

PER 012 GP 012 0.000E+00 0.000E+00 0.000E+00

PER 009 GP 017 3.500E+01 1.000E+02 1.000E+02

PER 012 GP 136 6.390E+00 3.694E+01 2.800E+01

PER 010 SV 042 4.250E-01 1.860E+00 1.860E+00

PER 009 SV 047 2.810E+00 1.230E+01 1.230E+01

PER 009 SV 066 7.280E-01 3.190E+00 3.190E+00

PER 009 SV 073 8.200E-01 3.590E+00 3.590E+00

PER 009 SV 083 2.110E+00 9.230E+00 9.230E+00

PER 009 SV 093 4.040E-01 1.770E+00 1.770E+00

PER 009 SV 104 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 105 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 106 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 107 0.000E+00 0.000E+00 0.000E+00

PER 009 SV 134 4.660E+00 2.040E+01 2.040E+01

PER 009 SV 166 6.370E+00 2.790E+01 2.790E+01

PER 009 TK 367 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 368 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 515 0.000E+00 0.000E+00 0.000E+00

PER 009 TK 517 5.500E-03 2.410E-02 2.410E-02

Totals 9.476E+03 2.679E+03 0.000E+00

Zinc

PER 011 EU 358 1.140E-03 4.980E-03 4.980E-03

Totals 4.980E-03 4.980E-03 0.000E+00

Page 92 of 92MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 1 of 407

Subject Item: Total Facility

NC/

CA Type Citation Requirement

CD 40 CFR Section 52.21(r)(2) and

Minn. R. 7007.3000 The Permittee is authorized to construct and modify equipment associated with the #3 Crude/Coker Improvements Permit and as described in Air Emission Permit No.

03700011-010. The Permittee must commence construction within 18 months of Stage 1 issuance of Air Emission Permit No. 03700011-010. This authorization to construct will expire February 27, 2015. 1.0

CD 40 CFR Section 52.21(r)(2) and

Minn. R. 7007.3000 The Permittee is authorized to construct the following equipment: EU359, EU360, FS139, SV189, CE078, CE079, MR202 - MR210. The construction authorization expires if construction does not commence within 18 months after receipt of such approval by Air Emissions Permit No. 03700011-012, if construction is discontinued for a period of 18 months or more, or if construction is not completed within a

reasonable time. 2.0

CD hdr STATE IMPLEMENTATION PLAN (SIP) REQUIREMENTS 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 3770 tons/year using 365-day Rolling Average 4.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Refinery Fuel Oil Restrictions: The owner or operator shall not burn refinery nos. 3, 4 or 6 fuel oil at any Refinery location. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y CHANGES NOT REQUIRING A MODIFICATION OF THE SIP: The owner or operator is authorized to begin construction of the activities listed below at the Refinery without a modification of the SIP. The Permittee may conduct activities not listed below without a modification of the SIP, if the activities do not emit sulfur dioxide, do not affect the modeling parameters assumed in Appendix C, and do not affect the continuous emission monitors (CEMs) or continuous monitoring systems (CMSs) used to demonstrate compliance with SIP. The Permittee shall, however, obtain an air emission permit prior to commencing any new activity or facility modification if one is required by Minnesota statutes, Minnesota rules or federal statutes and regulations. (continued below) 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

A fter obtaining the appropriate air emission permit (if required) but prior to a modification of the SIP, the Permittee may begin construction of a new unit or modification to an existing unit. However, the Permittee shall not operate a new emission unit and shall not operate a modified unit in a manner contrary to the modeling parameters in Appendix C for that unit until the modification to the SIP is obtained and approved by EPA.

A . The Permittee may install and operate any new SO2 process and control equipment with a maximum potential SO2 emissions rate that does not exceed 2.28 lbs/hr, except as expressly allowed elsewhere in the permit.

The Permittee may modify and operate any existing SO2 process or control equipment to increase the SO2 emission rate up to 2.28 lbs/hr over the modeled emission rate for that emission unit in Appendix C. (continued below) 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) B. The Permittee may physically and operationally modify process and control equipment if the modification do not increase the modeled sulfur dioxide emissions rate above the amount allowed in Appendix C, decrease the modeled stack emissions exit velocity, or decrease the modeled heat content of the stack exit emissions, at the emission source where the modification occurs and all other potentially affected emission points assumed in the modeling presented in

A ppendix C.

C. The Permittee may modify or replace and operate an existing sulfur dioxide emissions stack with a new stack if the height of the modified or replacement stack is not less than that of the stack assumed in the modeling presented in Appendix C, and if the exit diameter of the modified or replacement stack is not greater than that of the stack assumed in the modeling presented in Appendix C. (continued below) 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 2 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) D. The Permittee may install and operate new structures, or modify and operate existing structures if the new or modified structures do not increase the effective structural dimensions assumed in the modeling presented in Appendix C.

E. The Permittee may replace and operate replacement SIP CEMs and CMSs covered by this permit or the Permittee may install and operate additional CEMs and CMSs, so long as the new or replacement SIP CEMs and CMSs are properly certified, comply with this permit and are operated and tested as required by this permit. (continued from below) 9.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) F. The Permittee may add additional CEMs or CMSs as needed to provide redundancy, providing the Permittee notifies the Commissioner in writing at least 30 days prior to conducting any CEM or CMS certification test. The Permittee may modify the fuel gas delivery system if the following conditions are met: 1) fuel gas flow and sulfur content must be continuously measured for all heaters, either by measuring the sulfur level in the main Refinery fuel gas system and feeding the heater directly from the system, or by separately monitoring the fuel gas to or sulfur dioxide emissions from the heater; and 2) any new fuel gas monitors added to the system must be certified within 60 days of startup, must meet 40 CFR pt. 60,

A ppendix F QA/QC requirements, must have a QA/QC plan prepared and implemented within 60 days of startup, and operate in accordance with Minn. R. 7017.1090 within two quarters of startup. (continued below) 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) G. The boundaries of the Permittee owned property may be extended and existing fencing removed provided that the property excluded from the definition of ambient air, as shown in Appendix C, continues to meet the requirements in the permit. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Permittee Property and Access Restrictions:

A . The Permittee shall prevent the general public access to Permittee-owned property in order to exclude the atmosphere above the property from the definition of ambient air subject to the sulfur dioxide NAAQS.

B. Access Control The owner shall have enclosed the boundaries of the property with a continuous fence, excluding access points, and shall have installed gates at each access point. The Permittee shall therefore keep the gates closed unless: 1) a guard or other FHR employee or contractor patrols and monitors access at a gate or 2) authorized persons are entering or leaving the property through a gate. (continued below) 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) C. Inspection, Maintenance, and Repair The Permittee shall inspect the fencing and gates installed to ensure compliance with access control at least annually. The owner or operator shall maintain and repair the fencing and gates to maintain continuous compliance. The Permittee shall complete all repairs and maintenance to the fencing and gates as soon as possible, but no later than 30 days after the date the Permittee observes the need for repair or maintenance, or after the MPCA notifies the Permittee of the need for repair or maintenance. 13.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y GENERAL MONITORING REQUIREMENTS FOR THE SIP EMISSION UNITS

A . Accurate Measurements Required 1. The Permittee shall install, certify, calibrate, operate and maintain each SIP CEM and CMS, and shall conduct all non-continuous sampling and analysis as required by the permit to ensure accurate measurements of the parameters to be monitored.

2. The Permittee shall measure the stack sulfur dioxide concentration (ppm), stack velocity and stack temperature and compute the sulfur dioxide emission rate in lb/hr to determine compliance with the emission limitations listed for EU055 (31H-2), SV093 (SRU 3/4), SV042 (SRU 5), and SV019 (FCCU). The Permittee shall measure the Refinery fuel gas sulfur concentration and fuel gas flow rate to determine compliance with the emission limit for sulfur dioxide emissions from Refinery fuel gas combustion. (continued below) 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 3 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y B. Continuous Monitoring Requirements

1. General a) Compliance with Minnesota Rules and Federal Regulations. The Permittee shall meet the requirements of Minn. Rs. 7017.1002 to 7017.1020 and 40 CFR Section 60.13 with each CEM and CMS. If the requirements of Minn. Rs. 7017.1002 to 7017.1020 and 40 CFR Section 60.13 differ, the more stringent regulation shall apply.

b) Continuous Operation of CMS and CEM Systems. The Permittee shall at all times properly operate and maintain each CMS and CEM system to provide continuous, accurate, real time monitoring data for the determination of compliance with the terms and requirements of SIP requirements. In those situations where a CMS or CEM system becomes incapable of meeting the requirement of providing continuous, accurate, real time monitoring data, the Permittee shall expeditiously replace or repair the CMS or CEM system and take all other measures as necessary to meet the requirement as soon as possible. (continued below) 15.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

2. Monitor Certification a) Sulfur Dioxide CEMs. The Permittee shall certify each sulfur dioxide CEM as required by 40 CFR pt. 60, Appendix B, Performance Specification 2.

b) Emission Rate CMSs. The Permittee shall certify each continuous monitoring system as required by 40 CFR pt. 60, Appendix B, Performance Specification 6, except that the Permittee need not meet calibration drift requirements for those flow monitors that are not designed for conducting calibration drift tests (pitot tube or venturi type).

c) Total Reduced Sulfur CMSs for Fuel Gas Monitoring: The Permittee shall certify each total reduced sulfur CMS as required by 40 CFR pt. 60, Appendix B, by using the procedures specified in Performance Specification 5.

d) All CEMs and CMS. All CEMs and CMS certification shall be conducted in compliance with Minn. Rs. 7017.1050 - 7017.1080. (continued below) 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) 3. Quality Assurance The Permittee shall conduct a quality assurance and quality control (QA/QC) program as required by 40 CFR pt. 60, Appendix F, to properly maintain and calibrate each CEM and CMS. The Permittee shall develop and follow the master

QA/QC Plans for each CEM and CMS.

4. Monitoring System Uptime a) Mass Sulfur Dioxide CEM Systems. The Permittee shall operate and maintain each mass sulfur dioxide CEM system in accordance with Minn. R. 7017.1090 so that compliance with each emission limitation determined from real time certified CEM monitoring.

b) Refinery Fuel Gas Sulfur Monitoring. The Permittee shall maintain an SO2 CEMS at a representative heater which combusts 45 unit mix drum fuel gas, or maintain a CEMS which measures total sulfur in the 45 unit mix drum fuel gas stream. The SO2 CEMS shall provide a continuous record of the sulfur dioxide content of the heater exhaust in ppm. (continued below) 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) The CEMS which measures total sulfur shall provide a continuous record of the total sulfur content of the fuel gas in ppm.

The Permittee shall maintain a CEMS which measures reduced sulfur in the 41 unit mix drum fuel gas stream. The CEMS shall provide a continuous record of the reduced sulfur content of the fuel gas in ppm.

For heaters receiving commercial grade fuels directly that are neither inherently low in sulfur nor categorically exempt, contract guarantees for sulfur content and heat content shall be utilized for compliance demonstration purposes. (continued below) 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 4 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) c) Each CEM or CMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit startup, shutdown, or malfunction. This requirement to operate the monitor applies whether or not an emission limit applies during these periods.

CEM or CMS downtime is unacceptable except for reasonable periods of monitor downtime due to the following causes: (1) damage to the CEM or CMS due to acts of God such as lightning strikes, tornadoes, or floods that render the CMS inoperative; (2) sudden and not reasonably preventable CEM or CMS breakdowns; (3) scheduled maintenance based on equipment manufacturer's recommended schedule which cannot be reasonably conducted when the emission unit is not operating; or (4) unavoidable CEM or CMS downtime to conduct required checks and audits. 19.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y C. Non-Continuous Monitoring Requirements 1. The Permittee shall perform non-continuous monitoring as required by the permit ;

2. The Permittee shall conduct performance stack tests to determine compliance with the SIP emission limitations and fuel restrictions as required by the Commissioner pursuant to Minn. Rs.7017.2001 to 7017.2060. Stack tests can also be required by authorized EPA personnel. All performance tests shall be conducted in accordance with the requirements of Minn. Rs. 7017.2001 to 7017.2060. The Permittee shall submit to the MPCA performance stack test plans, protocols and schedules at least 15 days prior to the pretest meeting requirements listed below. 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Recordkeeping Requirements: The Permittee is required to keep specified records so that EPA and the MPCA can evaluate the Permittee's compliance SIP requirements for the following. 1. the Permittee must keep records on maintenance of property access controls.

2. the Permittee must keep records on the Refinery control plans and compliance

schedules.

3. the Permittee must keep records in the form and with the accessibility needed for EPA and MPCA staff inspection. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Recordkeeping for Property Boundary Fencing and Gates: The Permittee shall maintain records of each inspection of the fencing and gates as required . In addition, the Permittee shall maintain records of each maintenance activity and each repair activity as required. The Permittee shall retain each inspection, maintenance and repair record for a minimum of five years from the date the record was generated, despite any Permittee document retention policy to the contrary. These records shall be kept at the Refinery.

1. The inspection records shall include: the date of inspection; name of the person conducting the inspection; identification of each section of fence and each gate inspected; and identification of each location where repair or maintenance is required. The inspection report shall be certified as accurate in writing by the person conducting each inspection. (continued below) 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) 2. The maintenance and repair records shall include: the dates of the repairs or maintenance; a description of the repair and maintenance conducted; and the locations where they occurred. The maintenance and repair records shall be certified as accurate by the person(s) overseeing each maintenance or repair

action. 23.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Unless otherwise prohibited by a unit specific fuel restriction, any fuel gas combustion unit may burn refinery fuel gas not taken from the refinery fuel gas system provided that the Permittee install, operate, and maintain a hydrogen sulfide continuous emission monitoring system (CEMS) and flow meter at the fuel gas combustion unit in accordance with the requirements below whenever burning refinery fuel gas not taken directly from the refinery fuel gas system; or as an alternative, combustion units may burn refinery fuel gas not taken from the refinery fuel gas system if sulfur dioxide emissions are monitored under an EPA-approved

A lternative Monitoring Plan (AMP), or are categorically exempt, or are inherently low in sulfur content in accordance with NSPS J (or Ja version) 40 CFR 60.104 and/or 60.105 (40 CFR 60.102a and/or 60.107a). 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 5 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y RECORDKEEPING REQUIREMENTS FOR SIP The Permittee shall maintain for the Refinery a copy of the records required pursuant to the SIP. Records shall be retained at the Refinery.

1. Permanent Records The Permittee shall permanently maintain the following information together with all amendments, revisions, and modifications to this information. a) Design, Construction and Operation Information. The Permittee shall maintain information on the design, construction and operation of each emission facility, emission source, fuel system, stack, structures pertinent to modeling for downwash in Appendix C, and any other information required to conduct sulfur dioxide ambient air quality modeling of emissions from the Refinery. (continued below) 25.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) These records shall also include all information required to demonstrate that the equipment identified in Appendix C is installed as described in that Appendix C. Where an activity has been undertaken for changes not requiring a SIP modification, the records shall include a description of each activity and all information required to demonstrate that the activity complies with each applicable requirement pursuant to changes not requiring a SIP modification. The records shall also identify and provide information on the design, construction and operation of each modification or new installation at the Refinery as required by the SIP.

b) Information on Sulfur Dioxide Emission Limits, Operational Requirements, and Modeling Parameters. The Permittee shall maintain records at the Refinery. These records include all applicable SIP requirements. (continued below) 26.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

2. Non-Permanent Records

The Permittee shall retain the information identified below for a minimum of five years following the date on which the information was obtained, despite any document retention policy to the contrary. This retention period shall be automatically extended upon the Commissioner's written request. (continued below) 27.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) a) Monitoring, Testing, and Other Records. The Permittee shall maintain records of all measurements, including: all continuous monitoring system and continuous monitoring device measurements; all performance stack testing measurements and operating conditions during the performance stack tests; all continuous monitoring system performance evaluations; all continuous monitoring system or monitoring device calibration checks; all adjustments and maintenance performed on these systems or devices; and all other information required or applicable to verify compliance with the SIP. The Permittee shall prepare and maintain records of the one-hour averages for stack sulfur dioxide concentration (ppm); stack diameter, stack velocity and stack temperature; and the sulfur dioxide emission rate in lb/hr to determine compliance with refinery fuel gas SIP emission limitations listed in this

Permit. (continued below) 28.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) The Permittee shall prepare and maintain records of the one-hour averages of the refinery fuel gas sulfur concentration and fuel gas flow rate to determine compliance with the refinery fuel gas SIP emission limit. Using the one-hour averages, FHR shall calculate the three-hour, twenty four-hour, and annual rolling averages corresponding to the SIP emission limits referenced in the permit.

b) Sulfur Dioxide Emissions, Fuel Records and Operations Records. The Permittee shall maintain records to demonstrate compliance with the sulfur dioxide emissions limitations, and fuel use and quality restrictions and operational requirements. These records shall be designed, and the information shall be maintained in a form suitable for the Commissioner to quickly determine compliance with each of the emission limitations, fuel restrictions, and operational requirements of the SIP. (continued below) 29.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 6 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) c) Startup, Shutdown, Bypass, and Breakdown Records. The Permittee shall maintain records for each startup, shutdown, bypass and breakdown for each piece of process equipment, control equipment, fuel supply system, emission stack, monitoring system and any other piece of equipment as applicable. These records shall include the date and time of the start and stop of each event.

d) Excess Emissions, Exceedances of Fuel Usage and Quality Restrictions and Non-Compliance with Operational Requirements Records. The Permittee shall maintain a record of each exceedance of an emission limitation, fuel use restriction and fuel quality requirement, and operational requirement at the Refinery for each emission point and fuel system subject to the emission limitations, fuel restrictions, and operational requirements of the SIP. (continued below) 30.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) The record shall include for each period of exceedance a description of the exceedance, its cause, the magnitude of the exceedance, and the date and time

of commencement and cessation of the exceedance.

e) Operations Records for CEMs and CMSs. The Permittee shall maintain an operations record for each CEM and CMS used to establish compliance with the terms and conditions of this Order. The operations record shall specify each date and time the CEM or CMS was inoperative and the nature of the CEM or CMS repairs or adjustments. The operations record shall include for each calendar quarter, the percent of time the CEM or CMS was operating and the percent of time the CEM or CMS was not operating. The Permittee shall also record for each calendar quarter, the amount of time the process associated with the CEM or CMS was operated. (continued below) 31.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

C. Record Maintenance The Permittee shall maintain all required documents, records, reports and plans in a format suitable for determination of FHR's compliance with SIP requirements by

EPA or MPCA staff. The Permittee shall maintain the information in a form that is easily accessible for inspection by EPA or MPCA staff, and that is available for inspection at all reasonable times. 32.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y REPORTING REQUIREMENTS FOR SIP

A . Notifications for SIP Requirements 1. Notification of Process or Control Equipment Shutdown: The Permittee shall notify the Commissioner of shutdown of any control equipment or process equipment governed SIP in accordance with Minn. R. 7019.1000, subp

3.

2. Notification of Process or Control Equipment Breakdown: The Permitt shall notify the Commissioner of breakdowns of control equipment or process equipment governed SIP in accordance with Minn. R. 7019.1000, subp. 2. (continued below) 33.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

3. Notification of CEM or CMS Breakdown: The Permittee shall notify the Commissioner of a breakdown or malfunction of any CEM or CMS used to demonstrate compliance with the terms and conditions of this Permit in the next air quality quarterly report (NSPS excess emissions and 1989 Stipulation Agreement quarterly report) following the breakdown or

malfunction. The Permittee shall include the information identified in Minn. R. 7017.1110, subp. 2(B). (continued below) 34.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) 4. Notification of CEM or CMS Certification Test and Quality Assurance Audit Test: The Permittee shall notify the Commissioner in writing at least 30 days prior to conducting any CEM or CMS certification test for any CEM or CMS required to be certified pursuant to SIP requirements. The Permittee may request a pretest meeting with the MPCA staff by making the request at least seven days prior to conducting any CEM or CMS certification test for the CEMs or CMS required pursuant to the SIP requirements. The Permittee shall notify the Commissioner in writing at least seven days prior to conducting calendar quarter quality assurance audit test procedures for those CEMs or CMSs required. Exceptions to these deadlines may be approved by MPCA on a case-by-case basis. (continued below) 35.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 7 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above)

5. Notification of Performance Tests: The Permittee shall notify the Commissioner of its intent to conduct performance stack tests required pursuant to this Order not less than 30 days prior to conducting each performance stack test as required by Minn. R. 7017.2030. The Permittee may request a pretest meeting with the MPCA staff by making the request at least seven days prior to conducting a performance stack test. The test date is subject to the Commissioner's approval and shall be approved by the Commissioner at least 15 days before the planned test date. Exceptions to these deadlines may be approved by MPCA on a case-by-case basis.

6. Notification of Regularly Scheduled Turnaround on any Tail Gas Treating (TGTU)

Unit: The Permittee shall notify the Commissioner in writing 30 days prior to performing regularly scheduled turnaround (scheduled unit shutdown for maintenance) on any TGTU Unit. 36.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y B. Quarterly Reports The Permittee shall submit to the Commissioner each calendar quarter, a report that contains the following information: sulfur dioxide emissions, refinery fuel gas sulfur content or equivalent stack gas SO2 concentration (in a form that allows direct comparison with the requirements of the SO2 SIP); a record of each steam-air decoke event; a record of each startup, shutdown, bypass and breakdown of process and control equipment that results in a deviation from the requirements of the SO2 SIP; a summary record of excess sulfur dioxide emissions, exceedances of fuel usage and quality requirements and noncompliance with operational requirements, or the Permittee shall state if no exceedances or noncompliance conditions occurred in the quarter; a summary of CEM and CMS operation records including the amount of time the process equipment was operated; (continued below) 37.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) and, any quality assurance test results that do not meet the requirements of 40 CFR pt. 60, Appendix F (2010). Quarterly reports shall be postmarked within 30 days following the end of each calendar quarter. Upon written notification by the Commissioner, the Permittee may cease including sulfur dioxide emissions, fuel usage and quality, records of data used in calculating, and calculations of sulfur dioxide emissions, and fuel usage and quality in the quarterly reports. However, the Permittee shall submit this data within 30 days of receipt of a written request by the

Commissioner. (continued below) 38.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) C. Performance Stack Tests Reports The Permittee shall submit to the Commissioner, reports of each performance stack test conducted pursuant to this order. Performance stack test reports shall be postmarked no later than 45 days following completion of the performance stack test, unless otherwise approved by the MPCA.

D. CEM Certification Test Results The Permittee shall submit to the Commissioner, the results of each CEM certification test required pursuant to the SIP. Certification test reports shall be postmarked no later than 45 days after the CEM certification test date, unless otherwise approved by the MPCA.

E. CEM and CMS Audit Test Results The Permittee shall submit to the Commissioner, the results of quarterly cylinder gas audits and annual relative accuracy tests. Submitted results of quarterly audits and annual relative accuracy tests shall be included in the quarterly report for the quarter in which they were conducted. 39.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 8 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y GENERAL CONDITIONS FOR SIP REQUIREMENTS

A . Before the Permittee begins operation of new or modified equipment not specifically allowed by the SIP and which results in additional sulfur dioxide emissions, or changes to sulfur dioxide emission patterns assumed in the modeling presented in Appendix C, the Permittee shall obtain a modification to this Permit;

B. The SIP is meant to delineate Minnesota's strategy for attainment in the Pine Bend area from the present into the future, and is not an admission that the restrictions in 40 CFR Sections 52.24 (a) and (b) (1991) previously applied or currently apply to the Pine Bend area. (continued below) 40.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) C. This permit does not relieve FHR of the obligation in undertaking all actions required by the SIP provisions, to comply with all applicable local, State and Federal laws and regulations, including, but not limited to, federal new source performance standards, and laws and regulations related to occupational safety and health. In the event there is a conflict in applicable federal or state of local laws or regulations, the more stringent of the conflicting provisions shall apply. (continued below) 41.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) D. The MPCA, EPA or their authorized representatives shall have authority to enter all property of the Permittee in Rosemount, Minnesota, at all reasonable times for the purposes of inspecting records, operating logs and contracts related to the Permittee's compliance with SIP Conditions; reviewing the progress of the Permittee in implementing of the SIP Conditions; conducting such tests as the EPA or MPCA deem necessary to determine compliance with SIP; and verifying the data submitted to the EPA and MPCA by the Permittee. The Permittee shall honor all reasonable requests for such access by the EPA or MPCA staff, conditioned only upon presentation of proper credentials. This section does not limit any other right of entry and inspection held by the EPA and MPCA pursuant to applicable federal or state laws, rules or permits. (continued below) 42.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) E. The Title I SIP Conditions in this Permit shall be binding upon the Permittee and its respective officers, employees, successors and assigns. FHR shall provide a copy of this Permit to any successor in interest prior to transfer of that interest, and shall simultaneously inform the MPCA that this notice has been given. Should the Permittee sell or otherwise convey or assign any of its right, title or interest in the Refinery, such conveyance shall not release the Permittee from any obligation imposed SIP Conditions, unless the party to whom the right, title or interest has been transferred or assigned agrees in writing to fulfill the obligations of this Permit and the MPCA finds that the new owner has the ability to fulfill the obligations of this Permit, and approves such transfer or assignment. (continued below) 43.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y (continued from above) F. The SIP mandates actions and establishes limits necessary to attain, maintain and verify compliance with the federal sulfur dioxide NAAQS by FHR. To the extent that any federal or state statute, rule, permit, order, stipulation agreement, consent decree or schedule of compliance now in force or subsequently issued imposes limits and requires actions additional to or more stringent than those required in the Permit, FHR shall also comply with the requirements of the federal or state statute, rule, permit, order, stipulation agreement, consent decree or schedule of compliance.

G. Once US EPA approves this Permit as part of the Minnesota SIP, this Permit shall supersedes the requirements of all previous SIP revisions, as they apply to

FHR. 44.0

CD hdr SOURCE-SPECIFIC REQUIREMENTS 45.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 9 of 407

CD Minn. Stat. Section 116.07, subds. 4a & 9; Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M); Minn. R. 7007.0800, subps. 1, 2 & 4; Minn.

R. 7009.0010-7009.0080 Permit Appendices: This permit contains appendices as listed in the permit Table of Contents. The Permittee shall comply with all requirements contained in the appendices.

Notwithstanding the previous paragraph, SO2 modeling parameters in Appendix C are included in the appendices for reference only and compliance with these parameters is achieved through meeting the above SIP requirements listed in subject item "Total Facility" of this permit.

Notwithstanding the previous paragraph, PM10 modeling parameters in Appendix E are included in the appendices for reference only. 46.0

CD Minn. R. 7007.0800, subp. 2;

Minn. R. 7007.1300 List of Insignificant Activities Required to be Listed: Appendix B includes activities and sources at the facility that have been determined to be insignificant activities under Minn. R. 7007.1300. This list is subject to change. 47.0

CD 40 CFR Section 60.692-1(d)(2-4);

Minn. R. 7011.1435. C Recordkeeping for Non-Contact Cooling Water: Maintain plans and specifications showing non-contact cooling water does not contact hydrocarbons or oily water and is not recirculated through a cooling tower if excluding cooling water system from 40 CFR pt. 60, subp. QQQ requirements. 48.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Fuel Restriction: The Permittee shall not combust refinery fuel oil in any process heater or boiler located at the refinery. 49.0

CD hdr MINNESOTA AMBIENT AIR QUALITY STANDARD (MAAQS) REQUIREMENTS FOR HYDROGEN SULFIDE (H2S) 50.0

NC CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: by June 1, 2014, the Permittee shall complete engineering study for steam-air heater decoking and coker drum depressurization vent mitigation measures. This is a state only requirement and is not enforceable by the

EPA Administrator or citizens under the Clean Air Act. 51.0

CA CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: by June 1, 2014, the Permittee shall complete engineering study for steam-air heater decoking and coker drum depressurization vent mitigation measures. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. (Corrective Action) 51.1

NC CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: The Permittee shall maintain or support ambient air H2S or TRS monitoring near the facility to demonstrate compliance with the H2S MAAQS. Investigate and report any potential deviations from the H2S standard along with any needed changes to the H2S Management plan in the quarterly report that is due 3 months after receipt of qualified data. If the Permittee elects to discontinue ambient air monitoring for H2S, the Permittee shall submit a dispersion model that demonstrates compliance with the MAAQS. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. 52.0

CA CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: The Permittee shall maintain or support ambient air H2S or TRS monitoring near the facility to demonstrate compliance with the H2S MAAQS. Investigate and report any potential deviations from the H2S standard along with any needed changes to the H2S Management plan in the quarterly report that is due 3 months after receipt of qualified data. If the Permittee elects to discontinue ambient air monitoring for H2S, the Permittee shall submit a dispersion model that demonstrates compliance with the MAAQS. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. (Corrective Action) 52.1

NC CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: As soon as possible following good project management guidelines to ensure safe and reliable operation but no later than December 31, 2015, contingent upon timely receipt of any required environmental permits or SIP orders, the Permittee shall complete construction and commence operation of measures to mitigate the potential H2S impacts to the ambient air of steam-air decoking of coker heaters and coker drum depressurization vents. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under

the Clean Air Act. 53.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 10 of 407

CA CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: As soon as possible following good project management guidelines to ensure safe and reliable operation but no later than December 31, 2015, contingent upon timely receipt of any required environmental permits or SIP orders, the Permittee shall complete construction and commence operation of measures to mitigate the potential H2S impacts to the ambient air of steam-air decoking of coker heaters and coker drum depressurization vents. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. (Corrective Action) 53.1

NC CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: No later than 9 months following completion of coker H2S mitigation measures, the Permittee shall submit to the MPCA a final report that summarizes the actions taken to mitigate coker H2S sources and provides a review of the pre and post project ambient monitoring results. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the

Clean Air Act. 54.0

CA CD Minn. Stat. Sec. 116.07, subds. 4a and 9; Minn. R. 7007.0100, subps.
7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2, and 4;

Minn. R. 7009.0010-7009.0080 MAAQS Compliance: No later than 9 months following completion of coker H2S mitigation measures, the Permittee shall submit to the MPCA a final report that summarizes the actions taken to mitigate coker H2S sources and provides a review of the pre and post project ambient monitoring results. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. (Corrective Action) 54.1

CD hdr OPERATIONAL REQUIREMENTS 55.0

CD 40 CFR pt. 50; Minn. Stat. Sec.
116.07, subds. 4a and 9; Minn. R. 7007.0100, subps. 7A, 7L and 7M; Minn. R. 7007.0800, subps. 1, 2,
and 4; Minn. R.

7009.0010-7009.0080 The Permittee shall comply with National Primary and Secondary Ambient Air Quality Standards, 40 CFR pt. 50, and the Minnesota Ambient Air Quality Standards, Minn. R. 7009.0010 to 7009.0080. Compliance shall be demonstrated upon written request by the MPCA. 56.0

CD Minn. Stat. Section 116.07, subd.
4a; Minn. R. 7007.0100; Minn. R. 7007.0800, subp. 2; Minn. R.
7011.0150; Minn. R. 7009.0020 Comply with Fugitive Emission Control Plan: The Permittee shall follow the actions and recordkeeping specified in the control plan. The plan may be amended by the Permittee with the Commissioner's approval. If the Commissioner determines the Permittee is out of compliance with Minn. R. 7011.0150 or the fugitive control plan, then the Permittee may be required to amend the control plan and/or to install and operate particulate matter ambient monitors as requested by the Commissioner. This requirement applies to the paved roads at the ATS Storage Terminal only and is effective on startup of the ATS Storage Terminal. 57.0

CD Minn. R. 7011.0020 Circumvention: Do not install or use a device or means that conceals or dilutes emissions, which would otherwise violate a federal or state air pollution control rule, without reducing the total amount of pollutant emitted. 58.0

CD Minn. R. 7007.0800, subp. 2; Minn. R. 7007.0800, subp. 16(J) A ir Pollution Control Equipment: Operate all pollution control equipment whenever the corresponding process equipment and emission units are operated, unless otherwise noted in this permit. 59.0

CD Minn. R. 7007.0800, subps. 14 and 16(J) Operation and Maintenance Plan: Retain at the stationary source an operation and maintenance plan for all air pollution control equipment. At a minimum, the O & M plan shall identify all air pollution control equipment and control practices and shall include a preventative maintenance program for the equipment and practices, a description of (the minimum but not necessarily the only) corrective actions to be taken to restore the equipment and practices to proper operation to meet applicable permit conditions, a description of the employee training program for proper operation and maintenance of the control equipment and practices, and the records kept to demonstrate plan implementation.

The O & M plan may be maintained electronically as part of a task and procedure management system. O & M plans developed pursuant to MACT requirements satisfy this requirement for those units. 60.0

CD Minn. R. 7019.1000, subp. 4 Operation Changes: In any shutdown, breakdown, or deviation the Permittee shall immediately take all practical steps to modify operations to reduce the emission of any regulated air pollutant. The Commissioner may require feasible and practical modifications in the operation to reduce emissions of air pollutants. No emissions units that have an unreasonable shutdown or breakdown frequency of process or control equipment shall be permitted to operate. 61.0

CD Minn. R. 7011.0150 Fugitive Emissions: Do not cause or permit the handling, use, transporting, or storage of any material in a manner which may allow avoidable amounts of particulate matter to become airborne. Comply with all other requirements listed in

Minn. R. 7011.0150. 62.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 11 of 407

CD Minn. R. 7030.0010 - 7030.0080 Noise: The Permittee shall comply with the noise standards set forth in Minn. R. 7030.0010 to 7030.0080 at all times during the operation of any emission units. This is a state only requirement and is not enforceable by the EPA Administrator or

citizens under the Clean Air Act. 63.0

CD Minn. R. 7007.0800, subp. 9(A) Inspections: The Permittee shall comply with the inspection procedures and requirements as found in Minn. R. 7007.0800, subp. 9(A). 64.0

CD Minn. R. 7007.0800, subp. 16 The Permittee shall comply with the General Conditions listed in Minn. R. 7007.0800, subp. 16. 65.0

CD 40 CFR Section 60.2 Malfunction: Any sudden, infrequent, and not reasonably preventable failure of air pollution control equipment, process equipment, or a process to operate in a normal or usual manner. Failures that are caused in part by poor maintenance or careless operation are not malfunctions. 66.0

CD 40 CFR Section 60.11(d) Operation requirement for NSPS Sources: at all times, including periods of startup, shutdown, and malfunction, owners shall maintain and operate any affected facility in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information, which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures, and inspection of the source. 67.0

CD 40 CFR Section 61.12(c) Operation requirement for NESHAP FF Sources: at all times, including startup, shutdown, and malfunction, maintain and operate the source, including associated equipment for air pollution control, in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, review of operating and maintenance procedures, and inspection of the

source. 68.0

CD Minn. R. 7007.0800, subp 2; Minn. R. 7007.0800, subp. 16(J) A ir Pollution Control Equipment: The following control equipment downtime of CE 004, CE 005, CE 012, CE 019, CE 068, CE 015, CE 035, CE 036, CE 037, CE 038, CE 039, CE 040, CE 041, CE 042, CE 043, CE 044, CE 045 and CE 055 is not itself a deviation during downtime if the applicable permit limit requirement is met. The Permittee shall keep a record of the duration of downtime. 69.0

CD hdr PERFORMANCE TESTING 70.0

CD Minn. R. ch. 7017 Performance Testing: Conduct all performance tests in accordance with Minn. R. ch. 7017 unless otherwise noted in Tables A, B, and/or C. 71.0

CD Minn. Rs. 7017.2030, subp. 1-4,

7017.2018 and Minn. R. 7017.2035, subp. 1-2 Performance Test Notifications and Submittals:

Performance Tests are due as outlined in Tables A and B of the permit. See Table B for additional testing requirements. Performance Test Notification (written): due 30 days before each Performance Test Performance Test Plan: due 30 days before each Performance Test Performance Test Pre-test Meeting: due 7 days before each Performance Test Performance Test Report: due 45 days after each Performance Test Performance Test Report - Microfiche Copy: due 105 days after each Performance

Test

The Notification, Test Plan, and Test Report may be submitted in alternative format as allowed by Minn. R. 7017.2018. 72.0

CD Minn. R. 7017.2025 Limits set as a result of a performance test (conducted before or after permit issuance) apply until superseded as specified by Minn. R. 7017.2025 following written approval of a subsequent performance test on the same unit. 73.0

CD Minn. R. ch. 7017 Opacity Performance Testing: As provided in Minn. R. 7017.2020, subp. 2, the Permittee may conduct performance testing required by this permit as included in an approved performance test plan. The Permittee shall be certified in Method 9. The number of tests shall be determined by the Permittee and MPCA. 74.0

CD Minn. R. 7007.0800, subp. 6 Visible Emission Monitoring: The Permittee shall submit to the MPCA a 30-day notification if the Permittee has to perform a Method 9 test based on periodic visible emission monitoring unless more immediate testing is required by this permit. The

Method 9 test shall be conducted for a minimum of 1-hour. 75.0

CD hdr MONITORING REQUIREMENTS 76.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 12 of 407

CD Minn. R. 7017.1006 The Permittee is authorized to install a CEM on any emission unit subject to this permit, and, once certified, utilize that CEM to demonstrate compliance with any applicable limit. Once the CEM is installed and certified, any duty limits established pursuant to stack tests utilized to demonstrate compliance with a relevant limit shall no longer apply. For any such CEM, the Permittee shall follow the CEM requirements at Minn. Rs. 7017.1010, 7017.1090 and 7017.1160, and shall submit an administrative permit amendment to incorporate such requirements for the particular emission unit where the CEM is being utilized. 77.0

CD Minn. R. 7007.0800, subp. 4(D) Operation of Monitoring Equipment: Unless otherwise noted in Tables A, B, and/or C, monitoring a process or control equipment connected to that process is not necessary during periods when the process is shutdown, or during checks of the monitoring systems, such as calibration checks and zero and span adjustments. If monitoring records are required, they should reflect any such periods of process shutdown or checks of the monitoring system. 78.0

CD hdr RECORDKEEPING 79.0

CD Minn. R. 7007.0800, subp. 5(C) Recordkeeping: Retain all records at the stationary source for a period of five (5) years from the date of monitoring, sample, measurement, or report. Records which
must be retained at this location include all calibration and maintenance records, all original recordings for continuous monitoring instrumentation, and copies of all reports required by the permit. Records must conform to the requirements listed in Minn. R. 7007.0800, subp. 5(A).

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 80.0

CD Minn. R. 7007.1200, subp. 4 When the Permittee determines that no permit amendment or notification is required prior to making a change, the Permittee must retain records of all calculations required under Minn. R. 7007.1200. For expiring permits, these records shall be kept for a period of five years from the date the change was made or until permit reissuance, whichever is longer. For nonexpiring permits, these records shall be kept for a period of five years from the date that the change was made. The records shall be kept at the stationary source for the current calendar year of operation and may be kept at the stationary source or office of the stationary source for all other years. The records may be maintained in either electronic or paper format. 81.0

CD Minn. R. 7007.0800, subp. 5(B) Recordkeeping: Maintain records describing any insignificant modifications (as required by Minn. R. 7007.1250, subp. 3) or changes contravening permit terms (as required by Minn. R. 7007.1350, subp. 2), including records of the emissions resulting from those changes.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 82.0

CD hdr REPORTING/SUBMITTALS 83.0

CD Minn. R. 7017.1110, subps. 1 and

2 Excess Emissions/Downtime Reports (EERs): due 30 days after end of each calendar quarter following Initial Startup of the Monitor. (Submit Deviations Reporting Form DRF-1, as amended). The EER shall indicate all periods of monitor bypass and all periods of exceedances of a limit including exceedances allowed by an applicable standard, i.e. during start-up, shutdown, and malfunctions. The EER must be submitted even if there were no excess emissions, downtime or bypasses during the quarter (where applicable). 84.0

S/A Minn. R. 7007.0800, subp. 6 Quarterly Report: due 30 days after end of each calendar quarter starting 09/11/2013 applies to all quarterly reports: due January 30th, April 30th, July 30th and October 30th of each calendar year. (Air Quality and Excess Emissions) 85.0

S/A 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J, and V; 40 CFR pt. 63, subps. A and CC; 40 CFR Section 60.487a; Minn. R. 7007.0800, subp. 6 Report: due 30 days after end of each calendar half-year starting 09/11/2013 for LDAR Semiannual Report. This report is due January 30 and July 30 of each year. 86.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 13 of 407

S/A 40 CFR pt. 63, subp. CC, Table 6; 40 CFR Section 63.10(d)(5)(i)-(ii); 40 CFR Section 63.6(e)(3)(iii)-(iv); 40 CFR Section 63.6545(g);40 CFR Section 63.655(h)(1); 40 CFR pt. 63, subps. A and GGGGG; 40 CFR pt. 63, subp UUU, Table 43; 40 CFR Section 63.1575(a); 40 CFR pt. 63, subp, ZZZZ, Table 7; 40 CFR Section 63.6650(1); 40 CFR Section

63.7951 Report: due 30 days after half-year starting 09/11/2013 for MACT Semi-Annual Periodic Reports. Reports are due January 31 for the July 1-December 31 reporting period and due July 31 for January 1 - June 30 reporting period. 87.0

S/A 40 CFR Section 60.698(b)(1); 40 CFR Section 60.698(c); Minn.

R. 7011.1435 Report: due 30 days after half-year starting 09/11/2013 for NSPS QQQ Semi-Annual Report. The owner or operator shall submit to the Administrator semi-annually a certificate that all of the required inspections have been carried out

in accordance with these standards. 88.0

S/A Minn. R. 7007.0800, subp. 6(A)(2) Semiannual Deviations Report: due 30 days after end of each calendar half-year starting 10/31/2005 . The first semiannual report submitted by the Permittee shall cover the calendar half-year in which the permit is issued. The first report of each calendar year covers January 1 - June 30. The second report of each calendar year covers July 1 - December 31. If no deviations have occurred, the Permittee shall submit the report stating no deviations. 89.0

S/A Minn. R. 7007.0800, subp. 6 A nnual Report: due 30 days after 12/31/2005. The annual report applies to all annual reports: due January 30th of each year. 90.0

CD Minn. R. 7019.1000, subp. 3 Shutdown Notifications: Notify the Commissioner at least 24 hours in advance of a planned shutdown of any control equipment or process equipment if the shutdown would cause any increase in the emissions of any regulated air pollutant. If the owner or operator does not have advance knowledge of the shutdown, notification shall be made to the Commissioner as soon as possible after the shutdown. However, notification is not required in the circumstances outlined in Items A, B and C of Minn. R. 7019.1000, subp. 3.

A t the time of notification, the owner or operator shall inform the Commissioner of the cause of the shutdown and the estimated duration. The owner or operator shall notify the Commissioner when the shutdown is over. 91.0

CD Minn. R. 7019.1000, subp. 2 Breakdown Notifications: Notify the Commissioner within 24 hours of a breakdown of more than one hour duration of any control equipment or process equipment if the breakdown causes any increase in the emissions of any regulated air pollutant. The 24-hour time period starts when the breakdown was discovered or reasonably should have been discovered by the owner or operator. However, notification is not required in the circumstances outlined in Items A, B and C of Minn. R. 7019.1000, subp. 2.

A t the time of notification or as soon as possible thereafter, the owner or operator

shall inform the Commissioner of the cause of the breakdown and the estimated duration. The owner or operator shall notify the Commissioner when the

breakdown is over. 92.0

CD Minn. R. 7019.1000, subp. 1 Notification of Deviations Endangering Human Health or the Environment: As soon as possible after discovery, notify the Commissioner or the state duty officer, either orally or by facsimile, of any deviation from permit conditions which could endanger

human health or the environment. 93.0

CD Minn. R. 7019.1000, subp. 1 Notification of Deviations Endangering Human Health or the Environment Report: Within 2 working days of discovery, notify the Commissioner in writing of any deviation from permit conditions which could endanger human health or the environment. Include the following information in this written description: 1. the cause of the deviation; 2. the exact dates of the period of the deviation, if the deviation has been corrected ; 3. whether or not the deviation has been corrected; 4. the anticipated time by which the deviation is expected to be corrected, if not yet
corrected; and 5. steps taken or planned to reduce, eliminate, and prevent reoccurrence of the

deviation. 94.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 14 of 407

CD Minn. Stat. Section 116.07, subd.
4a; Minn. R. 7007.0100; Minn. R. 7007.0800, subp. 2; Minn. R.
7011.0150; Minn. R. 7009.0020 Fugitive Emissions Control Plan: The Permittee shall submit a fugitive emissions control plan for the paved roads at the ATS Storage Terminal location within 60 days of the date of permit no. 03700011-012 issuance for review and approval by the Commissioner. The plan will become effective on startup of the ATS Storage Terminal. The plan shall identify all road fugitive emission sources, primary and contingent control measures and record keeping. The Permittee shall follow the actions and record keeping specified in the control plan. The plan may be amended by the Permittee with the Commissioner's approval. If the Commissioner determines the Permittee is out of compliance with Minn. R. 7011.0150 or the fugitive emission control plan, then the Permittee may be required to amend the control plan and/or to install and operate particulate matter ambient monitors. 95.0

CD Minn. R. 7007.1150 - 7007.1500 A pplication for Permit Amendment: If a permit amendment is needed, submit an application in accordance with the requirements of Minn. Rs. 7007.1150 to 7007.1500. Submittal dates vary, depending on the type of amendment needed. 96.0

S/A Minn. R. 7007.0400, subp. 2 A pplication for Permit Reissuance: due 180 days before expiration of Existing

Permit 97.0

CD Minn. R. 7007.1400, subp. 1(H) Extension Requests: The Permittee may apply for an Administrative Amendment extend a deadline in a permit by no more than 120 days, provided that the agency may only extend a deadline established by an applicable requirement described in Minn. R. 7007.0100, subp. 7, items A to K, if the agency has been delegated authority to make such extensions by the administrator. Notwithstanding the previous sentence, the agency may do an administrative amendment to extend a testing deadline in a permit up to 365 days if the agency finds that the extension is needed to allow the permittee to test at worst case conditions as required by Minn. R. 7017.2025, subp. 2. 98.0

S/A Minn. R. 7007.0800, subp. 6(C) Compliance Certification: due 31 days after end of each calendar year starting 09/11/2013 (for the previous calendar year). The certification shall be submitted on a form approved by the Commissioner, both to the Commissioner and to the US EPA regional office in Chicago. This report covers all deviations experienced during the calendar year. 99.0

CD Minn. R. 7019.3000 - 7019.3100 Emission Inventory Report: due on or before April 1 of each calendar year following permit issuance. Submit the report on a form approved by the Commissioner. 100.0

CD Minn. R. 7007.1800 A(1) through (2) Permits: All prior Air Quality Emission Permits are rescinded and replaced by the Title V permit upon issuance. 101.0

CD Minn. R. 7002.0005 - 7002.0095 Emission Fees: due 30 days after receipt of an MPCA bill. 102.0

CD Risk Management Plan: 40 CFR pt. 68 Risk Management Plan: The Permittee is required to submit a Risk Management Plan (RMP) under the federal rule, 40 CFR pt. 68. Each owner or operator of a stationary source, at which a regulated substance is present above a threshold quantity in a process, shall design and implement an accidental release prevention program. An initial RMP must be submitted no later than the latest of the following dates: (1) June 21, 1999; (2) Three years after the date on which a regulated substance is first listed under 40 CFR Section 68.130; or (3) The date on which a regulated substance is first present above a threshold quantity in a process. A full update and resubmission of the RMP is required at least once every five years. The five-year anniversary date is reset whenever your facility fully updates and

resubmits their RMP. 103.0

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS

UNDER PART 63 104.0

CD 40 CFR pt. 63, subp. DDDDD The Permittee shall comply with the requirements of National Emission Standards for Hazardous Air Pollutants for Industrial, Commercial, and Institutional Boilers and Process Heaters, 40 CFR pt. 63, subp. DDDDD, if applicable, as specified under 40 CFR Section 63.7490, by the applicable deadlines as specified under 40 CFR Section 63.7495. Compliance date for existing sources is January 31, 2016 or as subsequently modified by applicable regulatory amendment or judicial order. 105.0

CD 40 CFR pt. 63, subp. GGGGG Equipment subject to National Emission Standards for Hazardous Air Pollutants for Site Remediation, 40 CFR pt. 63, subp. GGGGG following 40 CFR pt. 61, subp. FF for compliance is required to follow the general provisions of 40 CFR pt. 61, subp.

A , not 40 CFR pt. 63, subp. A. Such equipment is therefore exempt from Startup, Shutdown and Malfunction plans and related documentation and reporting requirements. (See 10/31/2006 email from Mr. Greg Nizich USEPA referenced in MACT GGGGG NOCS report dated 11/3/2006.) 106.0

CD 40 CFR Section 63.7936 (a) and (b) When transferring remediation material off-site you must transfer to a facility that meets the requirements in 40 CFR Section 63.7936(b). 107.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 15 of 407

CD 40 CFR Section 63.7936 (b)(3) Each shipment of remediation material that is being transferred off-site must include a notice with each shipment that states the remediation material contains organic HAP that are to be treated according to the provisions of this subpart. Receiving facility must have submitted to the EPA a written certification that the facility will manage remediation material according to the requirements of 40 CFR Sections 63.7885 through 63.7957. 108.0

CD 40 CFR Section 63.52(b)(1) and 63.52(e)(1) For changes that do not require a permit amendment but are subject to section 112(j) of the Clean Air Act:

1. The Permittee shall submit a Part 1 MACT application within 30 days of startup of any 112(j) affected source. The application shall meet the requirements of 40 CFR Section 63.53(a). 2. The Permittee shall submit a Part 2 MACT application within 90 days of startup of any 112(j) affected source. The application shall meet the requirements of 40 CFR Section 63.53(b).

The definition of a 112(j) affected source is found at 40 CFR Section 63.51. As of permit issuance, 112(j) affected sources include the following:

a. brick and structural clay products manufacturing; and b. clay ceramics manufacturing. 109.0

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS

UNDER PART 61 110.0

CD 40 CFR Section 61.342(c); 40 CFR Section 61.348(b)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Benzene Waste Streams: The Permittee shall control benzene waste streams per 40 CFR pt. 61, subp. FF standards and install, operate, and maintain a treatment process to remove or destroy benzene to less than 10 ppmw. 111.0

CD 40 CFR Section 61.355(c); 40 CFR Section 61.356(b); Minn. R. 7011.9930(E) The Permittee must determine flow-weighted annual average benzene concentration in the stream by collecting samples and analyzing waste streams or utilizing knowledge of the waste per 40 CFR Section 61.355(c). 112.0

CD 40 CFR Section 61.342(g); 40 CFR Section 61.356; Minn. R. 7011.9930(E) Records: The Permittee shall maintain records for NESHAP, Subpart FF equipment. 113.0

CD 40 CFR Section 61.05; 40 CFR

Section 61.15 Under 40 CFR pt. 61, subp. FF, the affected source is the entire facility. The Permittee may modify equipment within the facility and add/remove/modify control equipment without additional prior approval consistent with 40 CFR pt. 61, subp. FF. Note, Subpart FF does not require that all benzene waste streams be controlled as long as they are accounted for properly under the rule. 114.0

CD 40 CFR Section 61.357; 40 CFR Section 63.655; Minn. R. 7011.7280; Minn. R. 7011.9930(E) NESHAP, Subpart FF Quarterly Reports: The Permittee shall prepare and submit quarterly NESHAP inspection and certification report due 30 days after end of each calendar quarter. 115.0

CD 40 CFR Section 61.357(d)(8);
Minn. R 7011.7280; Minn. R. 7011.9930(E) NESHAP, Subpart FF Annual Corrective Report- due by April 7th of each year. 116.0

S/A 40 CFR Section 61.357(d)(2-3);
Minn. R. 7011.7280; Minn. R. 7011.9930(E) Report: due before year starting 09/11/2013 by April 7th of each year for NESHAP

A nnual TAB/2Mg Report. The Permittee shall prepare and submit NESHAP TAB/2Mg Report for the Total Facility. 117.0

CD 40 CFR Section 61.10(a) to 61.10(d) Notification: The Permittee shall notify the Administrator within 30 days of a change in the information submitted in the initial notification of applicability of 40 CFR pt. 61, subp. FF if change would affect determination of applicability. 118.0

CD 40 CFR Section 61.13(c) The owner or operator shall notify the Administrator of intent to conduct a required performance test at least 30 days before the performance test is scheduled. 119.0

CD 40 CFR Section 60.11(e)(6); 40 CFR Section 60.11(e)(7); 40 CFR Section 60.11(e)(8); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y) A final determination to deny any request for a waiver will be in writing and will set forth the specific grounds on which the denial is based. The final determination will be made within 60 days after presentation of additional information or argument; or within 60 days after the final date specified for the presentation if no presentation is

made. 120.0

CD 40 CFR Section 61.13(f) Unless otherwise specified in an applicable subpart, samples shall be analyzed and emissions determined within 30 days after each emission test has been completed. The owner or operator shall report the determinations of the emission test to the

A dministrator by a registered letter sent before the close of business on the 31st day following the completion of the emission test. 121.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 16 of 407

CD 40 CFR pt. 61, subp. FF Leaks into Cooling Towers: The Permittee shall follow the requirements set forth in Paragraphs 69 (b) and 74 (e) of the Consent Decree between FHR, EPA and MPCA (United States and State of Minnesota v. Koch Petroleum Group, L.P. (now Flint Hills Resources LP), Civil Action No. 00-2756, United States District Court for the District of Minnesota), as amended and as applicable to the Pine Bend refinery, for addressing any benzene associated with leaks of process fluids into cooling tower systems for the purpose of compliance with the Benzene Waste NESHAP. Consequently, the point of waste generation under 40 CFR Section 61.341 of any cooling tower subject to these requirements shall be the point where the water is blown down to a sewer drain or other wastewater conveyance. See Appendix D. 122.0

CD hdr DETERMINING IF A PROJECT/MODIFICATION IS SUBJECT TO NEW SOURCE REVIEW (NSR) 123.0

CD Title I Condition: 40 CFR Section 52.21(r)(6); Minn. R. 7007.3000; Minn. R. 7007.0800, subp. 2 These requirements apply if a reasonable possibility (RP) as defined in 40 CFR Section 52.21(r)(6)(vi) exists that a proposed project, analyzed using the actual-to-projected-actual (ATPA) test (either by itself or as part of the hybrid test at Section 52.21(a)(2)(iv)(f)) and found to not be part of a major modification, may result in a significant emissions increase (SEI). If the ATPA test is not used for the project, or if there is no RP that the proposed project could result in a SEI, these requirements do not apply to that project. The Permittee is only subject to the Preconstruction Documentation requirement for a project where a RP occurs only within the meaning of Section 52.2(r)(6)(vi)(a).

Even though a particular modification is not subject to NSR, or where there isn't a RP that a proposed project could result in a SEI, a permit amendment, recordkeeping, or notification may still be required by Minn. R. 7007.1150 -

7007.1500. 124.0

CD Title I Condition: 40 CFR Section 52.21(r)(6); Minn. R. 7007.3000; Minn. R. 7007.0800, subps. 4 & 5 Preconstruction Documentation -- Before beginning actual construction on a project, the Permittee shall document the following information:

1. A description of the project 2. Identification of the emission unit(s) whose emissions of an NSR pollutant could

be affected 3. The potential emissions of any existing or new emission units affected by the project. 4. A description of the applicability test used to determine that the project is not a major modification for any regulated NSR pollutant, including the baseline actual emissions, the projected actual emissions, the amount of emissions excluded due to increases not associated with the modification and that the unit(s) could have accommodated during the baseline period, an explanation of why the amounts were excluded, and any creditable contemporaneous increases and decreases that

were considered in the determination.

The Permittee shall maintain records of this documentation. 125.0

CD Title I Condition: 40 CFR Section 52.21(r)(6); Minn. R. 7007.3000; Minn. R. 7007.0800, subps. 4 & 5 The Permittee shall monitor the actual emissions of any regulated NSR pollutant that could increase as a result of the project and that were analyzed using the

A TPA test, and the potential emissions of any regulated NSR pollutant that could increase as a result of the project and that were analyzed using potential emissions in the hybrid test. The Permittee shall calculate and maintain a record of the sum of the actual and potential (if the hybrid test was used in the analysis) emissions of the regulated pollutant, in tons per year on a calendar year basis, for a period of 5 years following resumption of regular operations after the change, or for a period of 10 years following resumption of regular operations after the change if the project increases the design capacity of or potential to emit of any unit associated with the project. 126.0

CD Title I Condition: 40 CFR Section 52.21(r)(6); Minn. R. 7007.3000; Minn. R. 7007.0800, subps. 4 & 5 The Permittee must submit a report to the Agency if the annual summed (actual, plus potential if used in hybrid test) emissions differ from the preconstruction projection and exceed the baseline actual emissions by a significant amount as listed at 40 CFR Section 52.21(b)(23). Such report shall be submitted to the

A gency within 60 days after the end of the year in which the exceedances occur. The report shall contain:

a. The name and ID number of the facility, and the name and telephone number of the facility contact person b. The annual emissions (actual, plus potential if any part of the project was analyzed using the hybrid test) for each pollutant for which the preconstruction projection and significant emissions increase are exceeded. c. Any other information, such as an explanation as to why the summed emissions differ from the preconstruction projection. 127.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 17 of 407

CD hdr EMISSION LIMITS (PORTABLE DIESEL ENGINES) 128.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (Portable Diesel Engines) Power output from portable diesel engines: less than or equal to 6.3696 MMhp-hr per year using a 12-month rolling sum from the sum of all non-exempt portable diesels. 129.0

LIMIT Minn. R. 7011.2300, subp. 2 Sulfur Dioxide: less than or equal to 0.50 lbs/million Btu heat input using 3-hour Rolling Average (Compliance with the fuel sulfur content standard will demonstrate compliance with this requirement). (Portable Diesel Engines) 130.0

LIMIT Minn. R. 7011.2300, subp. 1 Opacity: less than or equal to 20 percent opacity once operating temperatures have been attained. (visible air contaminants) (Portable Diesel Engines) 131.0

CD hdr OTHER LIMITS AND REQUIREMENTS (PORTABLE DIESEL ENGINES) 132.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (Portable Diesel Engines) Diesel Engines Allowed: The Permittee may bring new portable diesels on-site, remove existing portable diesels, and modify existing portable diesels without applying for a permit amendment. (Limit for NOx Emissions) 133.0

CD Minn. R. 7007.0800, subps. 4 and

5 (Portable Diesel Engines) If and where the Permittee utilizes portable diesel engines according to the definition of nonroad engine per 40 CFR Section 89.2, and chooses not to track such engines against the 6.3696 MMhp-hr limit then: The Permittee shall keep records for each nonroad engine that will include: 1) Date that the nonroad engine is brought onsite. 2) Date that the nonroad engine is taken offsite and/or moved to a different location. 3) Identification number. 4) Rated capacity of the nonroad engine. 5) The model year and date of manufacture (as defined by the applicable nonroad engine rule). 6) Which nonroad provision that the nonroad engine is certified under. 7) Rental company information. 8) Function of the nonroad engine. While on site, each engine shall be labeled in such way that it can be determined that it is a nonroad engine and not one of the permitted engines covered by this air permit. 134.0

CD 40 CFR Section 1068.30, "Nonroad engines", (2)(iii) (Portable Diesel Engines) Unless tracked against the 6.3696 MMhp-hr limit, the Permittee shall not have nonroad engines in one location for more than 12 consecutive months. Any engine, or engines, that replaces an engine at a location and that is intended to perform the same or similar function as the engine it replaced will be included in calculating the consecutive time period. 135.0

CD 40 CFR Section 1068.101(b)(3) (Portable Diesel Engines) For a nonroad engine that is excluded from any requirements of 40 CFR pt.1068 because it is a stationary engine, the Permittee may not move it or install it in any mobile equipment, except as allowed by the provisions of 40 CFR pt. 1068. The Permittee may not circumvent or attempt to circumvent the residence-time requirements of paragraph (2)(iii) of the nonroad engine definition in 40 CFR Section 1068.30. 136.0

CD Minn. R. 7007.1150(B) (Portable Diesel Engines) Definition of Mobile Source, Construction and

Maintenance Activities: Diesel engines used to power a mobile source or used for construction or maintenance or repair activities are exempt from the 6.3696 MMhp-hr limit and the nonroad engine requirements of this permit and air permitting amendments. (continued below) 137.0

CD Minn. R. 7007.1150(B) (continued from above) (Portable Diesel Engines) Mobile Source - includes cranes, fork trucks, man lifts, trucks, back hoes, and front end loaders. A diesel located on a mobile source for which the primary activity of the engine is to power equipment other than the mobile source is not covered by this exemption.

Maintenance or Repair Activity - includes welders, light plant sandblasters, waterblasters (used to clean heat exchanger bundles), and generators/compressors that are used to operate tools to perform maintenance or repairs.

Construction Activity - diesel driven units used temporarily to construct or modify refinery equipment and structures. Diesel driven units that are hooked up to the refinery equipment in order to aid or direct the refinery process, even if it temporary action due to equipment malfunction, are not covered by this exemption. 138.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 18 of 407

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS (PORTABLE DIESEL ENGINES) 139.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (Portable Diesel Engines) Recordkeeping: The Permittee shall calculate and record the monthly and the 12-month rolling sum of the total power output from portable diesel engines (MMhp-hr/month and MMhp-hr/yr) by the 28th day of each month for the period with the preceding month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 140.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (Portable Diesel Engines) Recordkeeping: Calculate and record the monthly hours of operation in hours per month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 141.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (Portable Diesel Engines) Report: due 30 days after end of each calendar quarter following permit issuance if there are any exceedances of MMhp-hr per month and

per year. 142.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 19 of 407

Subject Item: GP 002 Cooling Towers (#1, #3, #4, #5, #6 and #7) and associated Heat Exchange Systems

Associated Items: EU 268 No 1 Cooling Tower - zFugitive

EU 269 No 3 Cooling Tower - zFugitive

EU 270 No 4 Cooling Tower - zFugitive

EU 271 No 5 Cooling Tower - zFugitive

EU 272 No 6 Cooling Tower - zFugitive

EU 354 No 7 Cooling Tower - zFugitive

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 5.5 tons/year using 365-day Rolling

Sum for EU 269. 2.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 2.4 tons/year using 365-day Rolling Sum for

EU 269. 3.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 4.3 tons/year using 365-day Rolling Sum for EU 270. This limit becomes effective upon startup of EU 296. 4.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 1.9 tons/year using 365-day Rolling Sum for EU 270. This limit becomes effective upon startup of EU 296. 5.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 4.3 tons/year using 365-day Rolling

Sum for EU 271. 6.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 1.9 tons/year using 365-day Rolling Sum for

EU 271. 7.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 5.7 tons/year using 365-day Rolling

Sum for EU 272. 8.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 2.5 tons/year using 365-day Rolling Sum for

EU 272. 9.0

LIMIT Minn. R. 7007.0800, subp. 2 Volatile Organic Compounds: less than or equal to 11.96 tons/year using 365-day Rolling Sum for EU 272, if modified as part of the #3 Crude/Coker Improvements permit. This limit is effective upon startup of EU 272 following modifications made as part of the #3 Crude/Coker Improvements permit. 10.0

LIMIT Minn. R. 7007.0800, subp. 2 Volatile Organic Compounds: less than or equal to 7.36 tons/year using 365-day Rolling Sum for EU 354, upon startup. 11.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 12.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 20 of 407

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM and PM10 Emission Calculations: For EU268, EU269, EU270, EU271 and EU272, the Permittee shall use the following to calculate PM and PM10 emissions, unless an alternative calculation method is proposed by the Permittee and approved by the MPCA in accordance with Minn. R. 7019.3100:

PM Emissions (tons/day) = [PRR x D x TDS x 60 min/hr x 8.3 lb/gal x (1 part /1,000,000 parts) x (24 hr/day)]/ (2000 lb/ton)

where

PRR = Average daily pump recirculation rate (gallons/minute) D = Drift specification in percent drift (maximum of 0.001%) TDS = Total dissolved solids concentration in cooling water in parts per million

PM10 Emissions (tons/day) = PM Emissions (tons/day) x 0.47 13.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM and PM10 Recordkeeping: For EU 268, EU 269, EU 270, EU 271 and EU 272, the Permittee shall calculate and record the daily and 365-day rolling sum PM/PM10 emissions from each cooling tower. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD 40 CFR Section 63.655(g)(9); Minn. R. 7011.7280(A) For heat exchange systems submit Periodic Reports that include the information found in 40 CFR Section 63.655(g)(9)(i) through (vi). 15.0

CD 40 CFR Section 63.655; Minn. R. 7011.7280(A) The owner operator of a heat exchange system shall comply with recordkeeping requirements of paragraphs (i)(4)(i) through (vi) of 40 CFR Section 63.655. 16.0

CD Minn. R. 7007.0800, subps. 2 and

4 The Permittee shall determine compliance with the VOC limits for EU272 and EU354 if actual emissions, as calculated using the "Air Stripping Method (Modified El Paso Method) for Determination of Volatile Organic Compound Emissions from Water Sources (January 2003)", and calculation basis from MACT CC and length of time to repair from the time of sampling, are at or below these limits. Specifically, FHR shall apply the emission rate (calculated from the sampling results and cooling tower recirculation rate) from the time sampled until the next sample that changes the Modified El Paso based emission rate. Samples shall be taken at least monthly, but may be taken more frequently at the discretion of FHR. 17.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall calculate and record the daily and 365-day Rolling Sum of VOC emissions at EU272 and EU354 by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. These records shall be maintained for at least five (5) years. This requirement is effective for EU272 upon startup following the modifications made as part of the #3 Crude/Coker Improvements permit and for EU354 upon startup. 18.0

CD Minn. R. 7007.0800, subp. 6 Reporting: The Permittee shall report, in its Quarterly Air Quality and Excess Emissions Report, the rolling 365-day average of VOC emissions at EU272 and EU354, for each day in the reporting period. This requirement is effective for EU272 upon startup following modifications made as part of the #3 Crude/Coker Improvements permit and for EU354 upon startup. 19.0

CD hdr OTHER REQUIREMENTS 20.0

CD 40 CFR Section 63.404; Minn. R.

7011.7160 The Permittee shall analyze cooling tower water for chromium if requested by the

A dministrator or the MPCA. 21.0

CD 40 CFR Section 63.10; 40 CFR Section 63.405; 40 CFR Section 63.406; 40 CFR Section 63.9;
Minn. R. 7011.7160; Minn. R.

7011.7280 The Permittee shall retain copy of Initial Notification and Notification of Compliance status on-site for a minimum of 5 years. 22.0

CD 40 CFR Section 63.654(c) Perform monthly monitoring to identify leaks of total strippable volatile organic compound (VOC) from each heat exchange system subject to the requirements of 40 CFR Section 63.654 according to the procedures in 63.654 (c)(1) and (2). 23.0

CD 40 CFR Section 63.654(d), (d)(1)-(5) If a leak is detected, the owner or operator must repair the leak to reduce the measured concentration to below the applicable action level as soon as practicable, but no later than 45 days after identifying the leak, except as specified in 40 CFR Section 63.645 (e) and (f). Alternatively the leaking exchanger may be isolated, bypassed, or otherwise removed from service until it is otherwise repaired. 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 21 of 407

CD 40 CFR Section 63.654(e) If a leak is detected when monitoring a cooling tower return line, additional monitoring may be conducted to identify leaks of total strippable VOC emissions using Modified El Paso Method from each heat exchanger or group of heat exchangers in organic HAP service associated with the heat exchange system for which the leak was detected. If the additional monitoring shows that the total strippable VOC concentration in the stripped air at the heat exchanger exit line for each heat exchanger in organic HAP service is less than 6.2 ppmv for existing sources or less than 3.1 ppmv for new sources, the heat exchange system is excluded from repair requirements. 25.0

CD 40 CFR Section 63.654(f)(1) Delay of Repair: a leaking heat exchanger may be placed on delay of repair within 45 days of leak identification if the repair is technically infeasible without a shutdown and the total strippable VOC concentration (as methane) is initially and remains less than 62 ppmv for all monthly monitoring periods during the delay of repair. Repair must be conducted during the next scheduled shutdown of the heat exchange system and within 30 days of the monitoring event in which the leak was 62 ppmv or greater total strippable VOC (as methane). 26.0

CD 40 CFR Section 63.654(f)(1) Delay of Repair: a leaking heat exchanger may be placed on delay of repair within 45 days of leak identification if the necessary equipment, parts, or personnel are not available and the total strippable VOC concentration (as methane) is initially and remains less than 62 ppmv for all monthly monitoring periods during the delay of repair. Repair must occur within 120 calendar days of being placed on Delay of Repair and within 30 days of a monitoring event in which the leak was 62 ppmv or greater total strippable VOC (as methane). 27.0

CD 40 CFR Section 63.654(f)(2) For heat exchange systems placed on Delay of Repair: Record: the reasons for delaying repair, a schedule for completing the repair as soon as practical, the date and concentration of the leak as first identified and the results of all subsequent monthly monitoring events during the delay of repair and an estimate of the potential emissions from the leaking heat exchange system or heat exchanger per 40 CFR Section 63.654(g)(4)(i) and (g)(4)(ii). 28.0

CD 40 CFR Section 63.655(f)(1) & (g)(9) Submit a Notification of Compliance Status report per the requirements specified in 40 CFR Section 63.655(f). 29.0

CD CAAA of 1990; Minn. R. 7007.0800, subp. 2 The point of waste generation under 40 CFR Section 61.431 of any of the FHR cooling tower systems affected by the Consent Decree shall be considered to the point where the water is blown down to the sewer drain or other wastewater conveyance. For the avoidance of doubt, this means that so long as the facility is complying with the monitoring and repair requirements of subparagraph (b), cooling tower water combined with process fluids that have leaked into the cooling tower system shall not be considered a waste stream until after such water has been blown down to a wastewater conveyance. (Reference 2001 Consent Decree 69(b)). 30.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Recordkeeping for EU 272 and EU 354 BACT Limits: The Permittee shall maintain cooling tower drift eliminators in accordance with good operation and maintenance practices. The cooling towers shall be inspected from safely accessible external access points not less than semiannually to inspect the drift eliminators that are visible to determine if the drift eliminators are in good working order. A complete inspection of all cooling tower drift eliminators shall be completed during scheduled internal maintenance downtime events. Limit is effective upon startup of the cooling towers following modifications made as part of the #3 Crude/Coker Improvements permit. This limit shall not apply to EU 272 if the modifications to EU 272 are not completed. (BACT Limit) 31.0

CD hdr BACT LIMITS FOR NO. 6 and NO. 7 COOLING TOWERS 32.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Design liquid drift rate shall be specified to meet 0.0005% drift. This limit is applicable to all Cooling Tower No. 7 (EU 354) cells and existing cells of Cooling Tower No. 6 (EU 272). Limit is effective upon startup of the cooling towers following modifications made as part of the #3 Crude/Coker Improvements permit. This limit shall not apply to EU 272 if the modifications to EU 272 are not completed. (BACT Limit) 33.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Design liquid drift rate shall be specified to meet 0.0050% drift. This limit is applicable to new "helper cells" of Cooling Tower No. 6 (EU 272). Limit is effective upon startup of the cooling tower following modifications made as part of the #3 Crude/Coker Improvements permit. This limit shall not apply if the modifications to EU 272 are not completed. (BACT Limit) 34.0

CD hdr NESHAP Q REQUIREMENTS FOR COOLING TOWER NO. 7 (Applicable to EU354) 35.0

S/A 40 CFR Sections 63.9(b)(1)(i) and (iii) and 63.405(a) Notification: due 365 days after Initial Startup of EU354. The notification shall provide information required in 40 CFR Section 63.405(a)(1)(i) through (a)(1)(iv). 36.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 22 of 407

S/A 40 CFR Sections 63.9(h)(3) and 63.405(b) Notification of compliance status: due 60 days after Initial Startup of EU 354 and brought into compliance with 40 CFR Section 63.402. 37.0

CD 40 CFR Section 63.405(b)(2) The Notification of Compliance Status must: i) Be signed by a responsible official who also certifies the accuracy of the report; ii) Certify that source has complied with Section 63.402 of this subpart; and iii) Include the information required in paragraph (a)(1)(iv) of this section. iv) Include the following statement: "I certify that no chromium-based water treatment chemicals have been introduced since (the initial compliance date) into any IPCT located within the facility for any purpose. 38.0

CD 40 CFR Sections 63.6(b)(2), 63.402 and 63.403(c) Upon initial startup, no chromium-based water treatment chemicals shall be used in the cooling tower. 39.0

CD 40 CFR Sections 63.10(b) and

63.404 The Permittee shall maintain files of all information required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, on computer floppy disks, on magnetic tape disks or on microfiche. 40.0

CD 40 CFR Section 63.406 To demonstrate continuing compliance with 40 CFR Section 63.402, the Permittee shall maintain copies of the initial notification and the notification of compliance status as required by 40 CFR Section 63.405 for a period of at least 5 years onsite. This requirement is applicable to EU354. 41.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 23 of 407

Subject Item: GP 003 ULSD Project CO Emissions

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

EU 296 No. 4 Hydrogen Plant Reformer - Refining Equipment

SV 167 Hydrogen Plant PSA Feed Bypass

SV 168 Hydrogen Plant PSA Purge Bypass

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 66.1 tons/year using 365-day Rolling Sum (EU 294, EU 295 and EU 296) 2.0

CD hdr MONITORING REQUIREMENTS 3.0

CD Minn. R. 7007.0800, subp. 4 CO Analyzer: The Permittee shall install, calibrate, maintain and operate an analyzer to continuously monitor the CO concentration in the Pressure Swing

A dsorption (PSA) feed stream. 4.0

CD Minn. R. 7007.0800, subp. 4 Flow Meter: The Permittee shall install, calibrate, maintain and operate one or more flow meter (s) to continuously measure the flow (s) of the "hot" and "cold" vents (upstream and downstream) of the PSA system upon startup of EU 296. 5.0

CD Minn. R. 7007.0800, subp. 4 Bypass Valve Status Monitor: The Permittee shall install, calibrate, maintain and operate monitors to determine bypass valve status and continuously determine whether the bypass valves are open or closed. 6.0

CD Minn. R. 7007.0800, subp. 4(D) Monitoring Equipment Calibration: Calibrate and/or maintain CO analyzer, flow meters and bypass valve according to manufacturer specifications. Maintain documentation showing that the calibrations and/or maintenance has been completed. 7.0

CD hdr RECORDKEEPING REQUIREMENTS 8.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 CO Calculations and Recordkeeping: The Permittee shall calculate and record the daily and 365-day rolling sum CO emissions from the listed emissions units above. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0

CD Minn. R. 7007.0800, subp. 5 CO Calculations: When a bypass valve is open, the flow meter shall be used to monitor the flow to the PSA unit and the CO analyzer shall be used to monitor the

CO concentration in the PSA feed stream. 10.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall record the daily and the 365-day rolling sum of CO emissions from the PSA bypass vents. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 24 of 407

Subject Item: GP 004 ULSD Project VOC Emissions

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

EU 296 No. 4 Hydrogen Plant Reformer - Refining Equipment

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

TK 522 Heavy Naphtha

TK 523 Heavy Naphtha

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Volatile Organic Compounds: less than or equal to 25.7 tons/year using 12-month Rolling Sum (EU 294, EU 295, EU 296, FS 133, FS 134, TK 943, TK 944, and TK 945) 2.0

CD hdr RECORDKEEPING REQUIREMENT 3.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 VOC Calculations and Recordkeeping: By the 28th day of each month, the

Permittee shall sum and record VOC emissions from the listed emission units for each preceding month and for the previous 12 months (12-month rolling sum). Emissions shall be calculated using the most current AP-42 emission factor for uncontrolled combustion of natural gas unless a different emission factor is developed by the Permittee and approved by the MPCA in accordance with Minn. Rs. 7019.3040 to 7019.3100. Fugitive emissions will be determined on a semi-annual basis after all required monitoring is completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 4.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 25 of 407

Subject Item: GP 007 Tanks subject to NSPS UU (each tank)

Associated Items: TK 019 Asphalt

TK 029 Asphalt

TK 037 Asphalt

TK 039 Asphalt

TK 411 Asphalt

TK 412 Asphalt

TK 414 Asphalt

TK 415 Asphalt

TK 416 Asphalt

TK 417 Asphalt

TK 418 Asphalt

TK 423 Asphalt

TK 424 Asphalt

NC/

CA Type Citation Requirement

CD hdr STANDARDS 1.0

CD 40 CFR Section 63, subp. CC 40 CFR Section 63.640(n)(1), NSPS Kb Overlap A fter the compliance dates specified in paragraph (h) of this section (8/18/98), a Group 1 or Group 2 storage vessel that is part of an existing source and is also subject to the provisions of 40 CFR pt. 60, subp. Kb is required to comply only with the requirements of 40 CFR pt. 60, subp. Kb. 2.0

CD 40 CFR Section 60.11(d); 40 CFR Section 60.470(a); Minn. R.

7011.0950 Standards for these tanks only apply while they are storing asphalt. 3.0

CD 40 CFR Section 60.11(c); 40 CFR Section 60.472(c); Minn. R.

7011.0950 Opacity: Within 60 days after achieving the maximum production rate at which the affected facility will be operated, but not later than 180 days after initial startup of such facility, no owner or operator subject to the provisions of this subpart shall cause to be discharged into the atmosphere from any asphalt storage tank exhaust gases with opacity greater than 0 percent, except for one consecutive 15-minute period in any 24-hour period when the transfer lines are being blown for clearing. The control device shall not be bypassed during this 15-minute period.

The Permittee is allowed to undertake preventative maintenance on tank demister control equipment while tank is in service. This is not considered a deviation as long as the opacity standard is met.

Limit does not apply during periods of startup, shutdown, and malfunction. 4.0

CD hdr PERFORMANCE TEST REQUIREMENTS 5.0

CD 40 CFR Section 60.474(b) In conducting performance tests required in 40 CFR Section 60.8(b), the owner shall use as reference methods and procedures the test methods in Appendix A of this part or other methods and procedures so specified in the section, except as provided in 40 CFR Section 60.8(b). 6.0

CD 40 CFR Section 60.474(c)(5) Method 9 and the procedures in 40 CFR Section 60.11 shall be used to determine opacity. 7.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 8.0

CD 40 CFR Section 60.473(c) A n owner or operator subject to the provisions of this subpart and using a control device not mentioned in 40 CFR Section 60.473(a) and (b) shall provide to the

A dministrator information describing the operation of the control device and the process parameter(s) which would indicate proper operation and maintenance of the device. The Administrator may require continuous monitoring and will determine the process parameters to be monitored. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 26 of 407

CD 40 CFR Section 60.473(d) The industry is exempted from the quarterly reports required under 40 CFR Section 60.7(c). The owner/operator is required to record and report the operating temperature of the control device during the performance test and, as required by 40 CFR Section 60.7(d), maintain a file of the temperature monitoring results for at least two years. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 10.0

CD 40 CFR Section 60.11(e)(6)-(8); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y) Report: May apply to change opacity standard. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 27 of 407

Subject Item: GP 009 Tanks subject to VOC Limit (CFP)

Associated Items: TK 001 Organic Liquid

TK 002 Organic Liquid

TK 003 Organic Liquid

TK 004 Organic Liquid

TK 005 Organic Liquid

TK 006 Organic Liquid

TK 007 Organic Liquid

TK 010 Organic Liquid

TK 011 Organic Liquid

TK 012 Organic Liquid

TK 013 Organic Liquid

TK 014 Organic Liquid

TK 015 Organic Liquid

TK 016 Organic Liquid

TK 017 Organic Liquid

TK 018 Organic Liquid

TK 019 Asphalt

TK 021 Organic Liquid

TK 022 Organic Liquid

TK 023 Organic Liquid

TK 024 Organic Liquid

TK 025 Organic Liquid

TK 026 Organic Liquid

TK 027 Organic Liquid

TK 028 Organic Liquid

TK 029 Asphalt

TK 030 Organic Liquid

TK 031 Organic Liquid

TK 033 Organic Liquid

TK 035 Organic Liquid

TK 037 Asphalt

TK 038 Organic Liquid

TK 039 Asphalt

TK 046 Organic Liquid

TK 047 Organic Liquid

TK 048 Organic Liquid

TK 049 Organic Liquid

TK 061 Organic Liquid

TK 062 Organic Liquid

TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

TK 065 Ethanol

TK 066 Organic LiquidMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 28 of 407

Associated Items: TK 067 Organic Liquid

TK 068 Organic Liquid

TK 080 Organic Liquid

TK 081 Organic Liquid

TK 082 Organic Liquid

TK 083 Organic Liquid

TK 084 Organic Liquid

TK 085 Organic Liquid

TK 086 Organic Liquid

TK 087 Organic Liquid

TK 088 Organic Liquid

TK 130 Organic Liquid

TK 131 Organic Liquid

TK 132 Organic Liquid

TK 133 Organic Liquid

TK 134 Organic Liquid

TK 150 Organic Liquid

TK 151 Organic Liquid

TK 152 Organic Liquid

TK 153 Organic Liquid

TK 154 Organic Liquid

TK 160 Organic Liquid

TK 161 Organic Liquid

TK 200 Organic Liquid@ 103 Unit

TK 201 Organic Liquid @ 103 Unit

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

TK 336 Organic Liquid Storage Tank

TK 411 Asphalt

TK 412 Asphalt

TK 414 Asphalt

TK 415 Asphalt

TK 416 Asphalt

TK 417 Asphalt

TK 418 Asphalt

TK 423 Asphalt

TK 424 Asphalt

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Volatile Organic Compounds: less than or equal to 411 tons/year using 12-month Rolling Sum all the tanks listed above. (Netting Limit) 2.0

CD hdr RECORDKEEPING REQUIREMENTS 3.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 29 of 407

CD Minn. R. 7007.0800, subp. 4 Recordkeeping: The Permittee shall record product throughput in barrels (bbl). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 4.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Recordkeeping: The Permittee shall record the total VOC emissions from listed tanks in tons/yr as a 12-month rolling average. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 5.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due 30 days after end of each quarter following Excess Emissions/Downtime Reports (EER's); if there are any exceedances of VOC tons/year limit per month and per year. 6.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 30 of 407

Subject Item: GP 010 Tanks/Basins subject to NESHAP FF w/vapor recovery & control device

Associated Items: EU 178 OSWTP - API Oil/Water Separator Fore Bay (94B1A & 94B1B) - Separation Equipment

EU 182 OSWTP - Sludge Basin 2A - Refining Equipment

EU 183 OSWTP - Equalization Basin 2B - Refining Equipment

EU 184 OSWTP - Equalization Basin 2C - Refining Equipment

EU 185 OSWTP-Enhanced Biological Treatm ent Basin 94B3C - Refining Equipment

EU 186 OSWTP - DAF Tank (old) - Refining Equipment

EU 187 OSWTP - DAF Tank (new) - Refining Equipment

EU 188 OSWTP - DAF Rapid Mix Tank (old) - Mixing Equipment

EU 189 OSWTP - DAF Rapid Mix Tank (new) - Mixing Equipment

EU 190 OSWTP - DAF Floc T ank (old) - Refining Equipment

EU 191 OSWTP - DAF Floc T ank (new) - Refining Equipment

EU 218 Old Oil/Water Separator at Ol d Bottom Loading Rack - Loading-Unloading Equipment

EU 222 11V-45 Sludge Recycle Tanks - Refining Equipment

EU 223 14V-22 Slop Drum - Refining Equipment

EU 278 OSWTP-API Oil/Water Separator Exit Bay (94B1A & 94B1B) - Separation Equipment

EU 280 OSWTP-Enhanced Biological Treatm ent Basin 94B3A - Refining Equipment

EU 281 OSWTP-Enhanced Biological Treatm ent Basin 94B3B - Refining Equipment

EU 289 Air Saturation Drum 94V22 - Separation Equipment

EU 290 94V-25D Wemco D Cell - Refining Equipment

EU 291 94V-25E Wemco E Cell - Refining Equipment

EU 292 94V-25F Wemco F Cell - Refining Equipment

EU 293 Air Saturation Drum 94V5 - Separation Equipment

EU 314 Oily Sludge Storage Vessel - Material Handling Equipment

EU 327 OSWTP- Dissolved Nitr ogen Floatation Unit - Dissolver

EU 345 Desalter Brine API 94ME259A - Refining Equipment

EU 346 Desalter Brine API 94ME259B - Refining Equipment

TK 336 Organic Liquid Storage Tank

TK 524 Wastewater Storage Tank 102TK12

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.343(a)(1)(i); 40 CFR Section 61.343(a)(1)(i)(B); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A ll equipment that contains waste subject to NESHAP FF standards: The cover and all openings (e.g., access hatches, sampling ports, and gauge wells) shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv above background, as determined initially and thereafter at least once per year by the methods specified in 40 CFR Section 61.355(h).

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 31 of 407

CD 40 CFR Section 61.343(a)(1); 40 CFR Section 61.343(a)(1)(i); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Install, operate, and maintain a fixed-roof and closed-vent system that routes all organic vapors vented from the tank to a control device.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0

CD 40 CFR Section 61.343(a)(1)(i)-(i)(A); 40 CFR Section 61.355(h); 40 CFR Section 61.355(h)(1)-(4); 40 CFR Section 61.355(h)(4)(i)-(ii); 40 CFR Section 61.355(h)(5)-(7); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Measuring: The Permittee shall test equipment for compliance with no detectable emissions in accordance with the following requirements: (1) Monitoring shall comply with Method 21 from appendix A of 40 CFR part 60. (2) The detection instrument shall meet the performance criteria of Method 21. (3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 4.0

CD 40 CFR Section 61.343(a)(1); 40 CFR Section 61.355(h); 40 CFR Section 61.355(h)(1)-(4); 40 CFR Section 61.355(h)(4)(i)-(ii); 40 CFR Section 61.355(h)(5)-(7); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) (4) Calibration gases shall be: (i) Zero air (less than 10 ppm of hydrocarbon in air); and (ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane. (5) The background level shall be determined as set forth in Method 21. (6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21. (7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 5.0

CD 40 CFR Section 61.343(c); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Visual Inspections: Each fixed-roof, seal, access door, and all other openings shall be checked by visual inspection initially and quarterly thereafter to ensure that no cracks or gaps occur and that access doors and other openings are closed and gasketed properly. 6.0

CD 40 CFR Section 61.351; 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Except as provided in 40 CFR Section 61.350, repair any problems found during NESHAP visual inspections per the repair deadlines for the applicable tank type in GP 039, GP 019, GP 034 and GP 026. 7.0

CD 40 CFR Section 61.350(a)-(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delay of repair of facilities or units that are subject to the provisions of this subpart

will be allowed:

(1) If the repair is technically impossible without a complete or partial facility or unit

shutdown.

(2) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 8.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Section 61.343 through 40 CFR Section 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. (continued below) 9.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 32 of 407

Subject Item: GP 011 Diesel Engines with SIP Conditions and <83.3 hr/mon

Associated Items: EU 007 Emergency generator @ #1,2 crude units - Reciprocating IC Engine

EU 024 Emergency Generator @ FCC - Reciprocating IC Engine

EU 036 Emergency Generator @ #3 Coker - Reciprocating IC Engine

EU 042 Emergency Generator @ #3 Crude Unit - Reciprocating IC Engine

EU 100 Emergency Generator at Pla tformer - Reciprocating IC Engine

EU 128 Diesel for Standby Circ Pump at #3 C ooling Tower (S end) - Reciprocating IC Engine

EU 129 Diesel for Standby Circ Pump at #3 C ooling Tower (N end) - Reciprocating IC Engine

EU 130 Diesel for Standby Circ Pump at #4 Cooling Tower - Reciprocating IC Engine

EU 131 Diesel for Fire Water Pump at #4 Cooling Tower - Reciprocating IC Engine

EU 132 Diesel for Standby Circ Pump at #5 Cooling Tower - Reciprocating IC Engine

EU 198 Diesel for Fire Water Pump at Lagoon - Reciprocating IC Engine

EU 199 Diesel for Fire Water Pump at St orm/Water Basin - Reciprocating IC Engine

EU 312 No. 6 Cooling Tower Diesel Pump - Reciprocating IC Engine

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS (APPLIES TO EACH UNIT) 1.0

LIMIT Minn. R. 7011.2300, subp. 2 Sulfur Dioxide: less than or equal to 0.50 lbs/million Btu heat input using 3-hour Rolling Average . (Compliance with the fuel sulfur content standard will demonstrate compliance with this requirement) 2.0

LIMIT Minn. R. 7011.2300, subp. 1 Opacity: less than or equal to 20 percent opacity once operating temperatures have been attained. (visible air contaminants) 3.0

CD hdr SO2 STATE IMPLEMENTATION PLAN (SIP) LIMITS (APPLIES AS LISTED) 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.002 lbs/hour using 3-hour Rolling Average . This limit applies to EU131. 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.002 lbs/hour using 24-hour Rolling Average . This limit applies to EU131. 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.009 tons/year using 12-month Rolling

A verage . This limit applies to EU131. 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.002 lbs/hour using 1-Hour Rolling Average . This limit applies to EU131. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean Air Act. 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.004 lbs/hour using 3-hour Rolling Average . This limit applies to EU129. 9.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.004 lbs/hour using 24-hour Rolling Average . This limit applies to EU129. 10.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.02 tons/year using 12-month Rolling Average . This limit applies to EU129. 11.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.004 lbs/hour using 1-Hour Rolling Average . This limit applies to EU129. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean Air Act. 12.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.016 lbs/hour using 3-hour Rolling Average . This limit applies to EU312. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 33 of 407

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.016 lbs/hour using 24-hour Rolling Average . This limit applies to EU312. 14.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.07 tons/year using 12-month Rolling Average . This limit applies to EU312. 15.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.016 lbs/hour using 1-Hour Rolling Average . This limit applies to EU312. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean Air Act. 16.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 3-hour Rolling Average . This limit applies individually to EU007, EU024, EU036, EU042, EU100, EU128,
EU130, EU132, EU198 and EU199. 17.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 24-hour Rolling Average . This limit applies individually to EU007, EU024, EU036, EU042, EU100, EU128,
EU130, EU132, EU198 and EU199. 18.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.04 tons/year using 12-month Rolling Average . This limit applies individually to EU007, EU024, EU036, EU042, EU100, EU128,
EU130, EU132, EU198 and EU199. 19.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 1-Hour Rolling Average . This limit applies individually to EU007, EU024, EU036, EU042, EU100, EU128, EU130, EU132, EU198 and EU199. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean

A ir Act. 20.0

CD hdr OTHER LIMITS AND REQUIREMENTS (APPLIES TO EACH UNIT) 21.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 1,000 hours/year using 12-month Rolling

Sum 22.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Content of Fuel: less than or equal to 0.0015 percent by weight of diesel fuel. 23.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn diesel fuel only. 24.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Total power output from GP011 diesel engines: less than or equal to 0.23 MMhp-hr per month using a 12-month rolling average. (Netting Limit for NOx) 25.0

CD hdr RECORDKEEPING REQUIREMENTS (APPLIES TO EACH UNIT) 26.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Recordkeeping of Hours of Operation: By the 28th day of each month, record the hours of operation for each engine for the previous month. Sum the hours of operation for the previous 12 months and record the 12-month rolling sum for the period ending with the preceding month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Diesel Fuel Certification:The Permittee shall retain records demonstrating sulfur content is less than 0.0015 percent by weight. Certificates of Analysis retained onsite demonstrating generally that all FHR diesel meets the federal ULSD standard satisfies this requirement. The records may be maintained in either electronic or paper format, unless it is expressly prohibited 28.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Recordkeeping for NOx Netting Limit: The Permittee shall calculate and record the monthly and the 12-month rolling average of the total power output from GP 011 engines (MMhp-hr/month) by the 28th day of each The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 29.0

CD hdr SO2 SIP RECORDKEEPING REQUIREMENTS 30.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 34 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 32.0

CD hdr REPORTING REQUIREMENTS (SEE TABLE B) 33.0

S/A Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Report: due 30 days after end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of diesel hours of operation. 34.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 35 of 407

Subject Item: GP 015 FCC Catalyst Transfers

Associated Items: EU 230 FCC Fresh Catalyst Transfer to Hopper - Material Handling Equipment

EU 231 FCC Spent Catalyst Transfer to Hopper - Material Handling Equipment

EU 232 FCC Spent Catalyst Transfer to Hopper - Material Handling Equipment

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Minn. R. 7011.0710, subp. 1(A) Total Particulate Matter: less than or equal to 0.30 grains/dry standard cubic foot of exhaust gas unless required to further reduce emissions to comply with the less stringent limit of either Minn. R. 7011.0730 or Minn. R. 7011. 0735. 2.0

LIMIT Minn. R. 7011.0710, subp. 1(B) Opacity: less than or equal to 20 percent opacity except for one six-minute period per hour of not more than 60 percent opacity. This emission limit applies to each emission unit in this group. 3.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 36 of 407

Subject Item: GP 017 Loading Rack Activities in CFP group limit

Associated Items: EU 004 Truck Bottom Loading (gas, distillate) including the trucks - Loading-Unloading Equipment

EU 205 Asphalt & Heavy Fuel Oil Truck Loading - Loading-Unloading Equipment

EU 207 Barge Loading/Unloading Heavy Pr oduct (N side) - Barge Loading Equipment

EU 208 Barge Loading/Unloading Heavy Pr oduct (S side) - Barge Loading Equipment

EU 209 Track 8 Rail Loading - Loading-Unloading Equipment

EU 216 Tracks 1-7 Rail Loading Excluding Sulfur, spent acid loading - Loading-Unloading Equipment

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Volatile Organic Compounds: less than or equal to 100 tons/year using 365-day Rolling Sum . Applies to the group of emission units listed above. (Netting Limit) 2.0

CD hdr RECORDKEEPING REQUIREMENT 3.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 VOC Recordkeeping and Calculations: The Permittee shall calculate and record the VOC emissions from the listed units above for each day and the previous 365 days (365-day rolling average). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 37 of 407

Subject Item: GP 019 External Floating Tanks NSPS Kb > 39,890 gals

Associated Items: TK 001 Organic Liquid

TK 002 Organic Liquid

TK 003 Organic Liquid

TK 004 Organic Liquid

TK 005 Organic Liquid

TK 006 Organic Liquid

TK 007 Organic Liquid

TK 061 Organic Liquid

TK 062 Organic Liquid

TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

TK 066 Organic Liquid

TK 068 Organic Liquid

TK 080 Organic Liquid

TK 083 Organic Liquid

TK 087 Organic Liquid

TK 088 Organic Liquid

TK 150 Organic Liquid

TK 151 Organic Liquid

TK 152 Organic Liquid

TK 160 Organic Liquid

TK 586 Sour Water

TK 587 Sour Water

TK 588 Sour Water

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112b(a); 40 CFR Section 61.342(c)(1)(ii) Maintain records of current applicability of NSPS, Subpart Kb control requirements and NESHAP, Subpart FF control requirements for each tank on-site. Records may

be electronic. 1.0

CD 40 CFR Section 60.112b(a) If storing VOL with max TVP equal to or greater than 0.75 psia and less than 11.1 psia, comply with the requirements listed within this group. 2.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 63.647(a); Minn. R. 7011.9930(E) If storing benzene waste as defined in 40 CFR Section 61.341 and either not exempting that waste from control under 40 CFR Section 61.342, or classifying the waste as controlled, comply with the requirements listed within this group regardless of vapor pressure. 3.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 61.351(a); Minn. R. 7011.1520, subp. C; Minn. R. 7011.9930(E) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 38 of 407

CD 40 CFR Section 60.112b(a)(2)(i)-(iii); Minn. R. 7011.1520(C) A n external floating roof. An external floating roof means a pontoon-type or double-deck type cover that rests on the liquid surface in a vessel with no fixed roof. Each external floating roof must meet the following specifications:

(i) Each external floating roof shall be equipped with a closure device between the wall of the storage vessel and the roof edge. The closure device is to consist of two seals, one above the other. The lower seal is referred to as the primary seal, and the upper seal is referred to as the secondary seal.

(A) The primary seal shall be either a mechanical shoe seal or a liquid-mounted seal. Except as provided in 60 CFR Section 113b(b)(4), the seal shall completely cover the annular space between the edge of the floating roof and tank wall. (continued below) 5.0

CD 40 CFR Section 60.112b(a)(2)(i)-(iii); Minn. R. 7011.1520(C) (continued from above) (B) The secondary seal shall completely cover the annular space between the external floating roof and the wall of the storage vessel in a continuous fashion except as allowed in 40 CFR Section 113b(b)(4). (continued below) 6.0

CD 40 CFR Section 60.112b(a)(2)(i)-(iii); Minn. R. 7011.1520(C) (continued from above) (ii) Except for automatic bleeder vents and rim space vents, each opening in a noncontact external floating roof shall provide a projection below the liquid surface. Except for automatic bleeder vents, rim space vents, roof drains, and leg sleeves, each opening in the roof is to be equipped with a gasketed cover, seal, or lid that is to be maintained in a closed position at all times (i.e., no visible gap) except when

the device is in actual use. Automatic bleeder vents are to be closed at all times when the roof is floating except when the roof is being floated off or is being landed on the roof leg supports. Rim vents are to be set to open when the roof is being floated off the roof legs supports or at the manufacturer's recommended setting.

A utomatic bleeder vents and rim space vents are to be gasketed. (continued below) 7.0

CD 40 CFR Section 60.112b(a)(2)(i)-(iii); Minn. R. 7011.1520(C) (continued from above) Each emergency roof drain is to be provided with a slotted membrane fabric cover that covers at least 90 percent of the area of the opening.

(iii) The roof shall be floating on the liquid at all times (i.e., off the roof leg supports) except during initial fill until the roof is lifted off leg supports and when the tank is completely emptied and subsequently refilled. The process of filling, emptying, or refilling when the roof is resting on the leg supports shall be continuous and shall be accomplished as rapidly as possible.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected within the time frame specified by regulation. 8.0

CD 40 CFR Section 60.113b(b)(4)(i)(A)-(B); 40 CFR Section 60.113b(b)(4)(ii)(A)-(C); Minn. R. 7011.1520(C) Make necessary repairs or empty the storage vessel within 45 days of identification in any inspection for seals not meeting the requirements listed in 40 CFR Section 60.113(b)(4) (i) and (ii).

(i) The accumulated area of gaps between the tank wall and the mechanical shoe or liquid-mounted primary seal shall not exceed 212 cm2 per meter of tank diameter, and the width of any portion of any gap shall not exceed 3.81 cm.

(A) One end of the mechanical shoe is to extend into the stored liquid, and the other end is to extend a minimum vertical distance of 61 cm above the stored liquid

surface.

(B) There are to be no holes, tears, or other openings in the shoe, seal fabric, or seal envelope.

(ii) The secondary seal is to meet the following requirements: (continued below) 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 39 of 407

CD 40 CFR Section 60.113b(b)(4)(i)(A)-(B); 40 CFR Section 60.113b(b)(4)(ii)(A)-(C); Minn. R. 7011.1520(C) (continued from above) (A) The secondary seal is to be installed above the primary seal so that it completely covers the space between the roof edge and the tank wall except as provided in 40 CFR Section 60.113(b)(b)(2)(iii).

(B) The accumulated area of gaps between the tank wall and the secondary seal shall not exceed 21.2 cm2 per meter of tank diameter, and the width of any portion of any gap shall not exceed 1.27 cm.

(C) There are to be no holes, tears, or other openings in the seal or seal fabric.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected within the time frame specified by regulation. 10.0

CD 40 CFR Section 60.113(b)(b)(1)(i)-(iii); Minn. R. 7011.1520(C) Determine the gap areas and maximum gap widths, between the primary seal and the wall of the storage vessel and between the secondary seal and the wall of the storage vessel according to the following frequency.

(i) Measurements of gaps between the tank wall and the primary seal (seal gaps) shall be performed during the hydrostatic testing of the vessel or within 60 days of the initial fill with VOL and at least once every 5 years thereafter. (continued below) 11.0

CD 40 CFR Section 60.113(b)(b)(1)(i)-(iii); Minn. R. 7011.1520(C) (continued from above) (ii) Measurements of gaps between the tank wall and the secondary seal shall be performed within 60 days of the initial fill with VOL and at least once per year

thereafter.

(iii) If any source ceases to store VOL for a period of 1 year or more, subsequent introduction of VOL into the vessel shall be considered an initial fill for the purposes of 40 CFR Section 60.113(b)(b)(1)(i) and (b)(1)(ii). 12.0

CD 40 CFR Section 60.113b(b)(2)(i)-(iii); Minn. R. 7011.1520(C) Determine gap widths and areas in the primary and secondary seals individually by the following procedures:

(i) Measure seal gaps, if any, at one or more floating roof levels when the roof is floating off the roof leg supports.

(ii) Measure seal gaps around the entire circumference of the tank in each place where a 0.32-cm diameter uniform probe passes freely (without forcing or binding against seal) between the seal and the wall of the storage vessel and measure the

circumferential distance of each such location.

(iii) The total surface area of each gap described in 40 CFR Section 60.113b(b)(2)(ii) shall be determined by using probes of various widths to measure accurately the actual distance from the tank wall to the seal and multiplying each such width by its respective circumferential distance. 13.0

CD 40 CFR Section 60.113b(b)(3); Minn. R. 7011.1520(C) A dd the gap surface area of each gap location for the primary seal and the secondary seal individually and divide the sum for each seal by the nominal diameter of the tank and compare each ratio to the respective standards in 40 CFR Section 60.113b(b)(4). 14.0

CD 40 CFR Section 60.113b(b)(6); 40 CFR Section 60.113b(b)(6)(i)-(ii); Minn. R. 7011.1520(C) Visually inspect the external floating roof, the primary seal, secondary seal, and fittings each time the vessel is emptied and degassed.

(i) If the external floating roof has defects, the primary seal has holes, tears, or other openings in the seal or the seal fabric, or the secondary seal has holes, tears, or other openings in the seal or the seal fabric, the owner or operator shall repair the items as necessary so that none of the conditions specified in this paragraph exist before filling or refilling the storage vessel with VOL.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected within the time frame specified by regulation. (continued below) 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 40 of 407

CD 40 CFR Section 60.113b(b)(6); 40 CFR Section 60.113b(b)(6)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) (ii) For all the inspections required by 40 CFR Section 60.113b(b)(6), the owner or operator shall notify the Administrator in writing at least 30 days prior to the filling or refilling of each storage vessel to afford the Administrator the opportunity to inspect the storage vessel prior to refilling. If the inspection required by 40 CFR Section 60.113b(b)(6) is not planned and the owner or operator could not have known about the inspection 30 days in advance of refilling the tank, the owner or operator shall notify the Administrator at least 7 days prior to the refilling of the storage vessel. Notification shall be made by telephone immediately followed by written documentation demonstrating why the inspection was unplanned. Alternatively, this notification including the written documentation may be made in writing and sent by express mail so that it is received by the Administrator at least 7 days prior to the refilling. 16.0

CD 40 CFR Section 63.640(n)(8)(ii); Minn. R. 7011.1520(C) If the owner or operator determines that it is unsafe to perform the seal gap measurements required in 40 CFR Section 60.113b(b) of subpart Kb or to inspect the vessel to determine compliance with 40 CFR Section 60.113b(a) of subpart Kb because the roof appears to be structurally unsound and poses an imminent danger to inspecting personnel, the owner or operator shall comply with the requirements in either 40 CFR Section 63.120(b)(7)(i) or 40 CFR Section 63.120(b)(7)(ii) of subpart G. 17.0

CD STERP Agreement March 2001 Slotted Guidepoles The sliding cover shall be in place over the slotted guidepole opening through the floating roof at all times except when the sliding cover must be removed for access. If the control technology used includes a guidepole float, the float shall be floating within the guidepole at all times except when it must be removed for access to the stored liquid or when the tank is empty.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected within the time frame specified by regulation. 18.0

CD STERP Agreement March 2001 Slotted Guidepoles Visually inspect the deck fitting for the slotted guidepole deck fitting at least once every 10 years and each time the vessel is emptied and degassed. If the slotted guidepole deck fitting or control devices have defects, or if a gap of > 1/8" exists between any gasket required for control of the slotted guidepole deck fitting and any surface it is intended to seal, such items shall be repaired before filling or refilling the storage vessel with regulated material. Tanks taken out of hydrocarbon service, for any reason, do not have to have any controls in place during the time they are out of service.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected within the time frame specified by regulation. 19.0

CD STERP Agreement March 2001 Slotted Guidepoles; 40 CFR Section 63.640(n) If the tank is in service, all slotted guidepole deck fitting or control device defects or gaps >1/8" on gaskets or seals required for control must be repaired within 45 days of inspection. If necessary, the owner or operator may utilize up to two extensions of up to 30 additional calendar days each. Pursuant to 40 CFR Section 63.640 (n)(8)(iii), the owner or operator is not required to provide a request for the

extension to the Administrator. 20.0

CD May 24, 2004, letter from James K. Jackson, U.S. EPA Double wiper seals are approved control technology for slotted ladders under FHR's Storage Tank Emission Partnership Agreement for new and existing tanks. 21.0

CD 40 CFR Section 60.116b(b); Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.110b(a) shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel. 22.0

CD 40 CFR Section 60.116b(c); Minn. R. 7011.1520(C) Except as provided in 40 CFR Section 60.116b(f) and (g), the owner or operator of each storage vessel either with a design capacity greater than or equal to 151 m3 storing a liquid with a maximum true vapor pressure greater than or equal to 3.5 kPa or with a design capacity greater than or equal to 75 m3 but less than 151 m3 storing a liquid with a maximum true vapor pressure greater than or equal to 15.0 kPa shall maintain a record of the VOL stored, the period of storage, and the maximum true vapor pressure of that VOL during the respective storage period. 23.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) A vailable data on the storage temperature may be used to determine the maximum true vapor pressure as determined below.

(1) For vessels operated above or below ambient temperatures, the maximum true vapor pressure is calculated based upon the highest expected calendar-month average of the storage temperature. For vessels operated at ambient temperatures, the maximum true vapor pressure is calculated based upon the maximum local monthly average ambient temperature as reported by the National Weather Service

. (continued below) 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 41 of 407

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) For crude oil or refined petroleum products the vapor pressure may be obtained by the following:

(i) Available data on the Reid vapor pressure and the maximum expected storage temperature based on the highest expected calendar-month average temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517 (incorporated by reference 40 CFR Section 60.17), unless the Administrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s).

(ii) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa or with physical properties that preclude determination by the

recommended method is to be determined from available data and recorded if the estimated maximum true vapor pressure is greater than 3.5 kPa. (continued below) 25.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) For other liquids, the vapor pressure:

(i) May be obtained from standard reference texts, or

(ii) Determined by ASTM D2879-83, 96, or 97 (incorporated by reference see 40 CFR Section 60.17); or

(iii) Measured by an appropriate method approved by the Administrator; or

(iv) Calculated by an appropriate method approved by the Administrator. 26.0

CD 40 CFR Section 60.115b; 40 CFR Section 60.115b(b)(3)(i)-(iii); Minn. R. 7011.1520(C) Keep a record of each gap measurement performed as required by 40 CFR Section 60.113b(b). Each record shall identify the storage vessel in which the measurement was performed and shall contain:

(i) The date of measurement.

(ii) The raw data obtained in the measurement.

(iii) The calculations described in 40 CFR Sections 60.113b (b)(2) and (b)(3). 27.0

CD 40 CFR Section 60.113b(b)(4)(iii); 40 CFR Section 60.19(b); 40 CFR Section 60.19(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); 40 CFR Section 63.640(n)(8)(iii); Minn. R. 7011.1520(C) If a failure that is detected during inspections required in paragraph (b)(1) of 40 CFR Section 60.113b(b) cannot be repaired within 45 days and if the vessel cannot be emptied within 45 days, the owner or operator may utilize up to two extensions of up to 30 additional calendar days each. Pursuant to 40 CFR Section 63.640(n)(8)(iii), the owner or operator is not required to provide a request for the

extension to the Administrator. 28.0

CD 40 CFR Section 60.113b(b)(5); 40 CFR Section 60.19(b); 40 CFR Section 60.19(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); Minn. R. 7011.1520(C) Notify the Administrator 30 days in advance of any gap measurements required by 40 CFR Section 60.113b(b)(1) to afford the Administrator the opportunity to have an observer present. 29.0

CD 40 CFR Section 60.115b(b)(1); Minn. R. 7011.1520(C) Furnish the Administrator with a report that describes the control equipment and certifies that the control equipment meets the specifications of 40 CFR Section 60.112b(a)(2) and 40 CFR Sections 60.113b(b)(2), (b)(3), and (b)(4). This report shall be an attachment to the notification required by 40 CFR Section 60.7(a)(3). 30.0

CD 40 CFR Section 60.115b(b)(2)(i)-(iii); 40 CFR Section 60.19(b); 40 CFR Section 60.19(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); Minn. R. 7011.1520(C) Within 60 days of performing the seal gap measurements required by 40 CFR Section 60.113(b)(1) furnish the Administrator with a report that contains:

(i) The date of measurement.

(ii) The raw data obtained in the measurement.

(iii) The calculations described in 40 CFR Section 60.113b (b)(2) and (b)(3). 31.0

CD 40 CFR Section 60.115b(b)(4); 40 CFR Section 60.19(b); 40 CFR Section 60.19(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); Minn. R. 7011.1520(C) A fter each seal gap measurement that detects gaps exceeding the limitations specified by 40 CFR Section 60.113b(b)(4), submit a report to the Administrator within 30 days of the inspection. The report will identify the vessel and contain the information specified in 40 CFR Section 60.115(b)(2) and the date the vessel was emptied or the repairs made and date of repair. 32.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 42 of 407

CD 40 CFR Section 60.116b(a); Minn. R. 7011.1520(C) The owner or operator shall keep copies of all records required by this section, except for the record required by 40 CFR Section 60.116b(b) for at least 2 years. The record required by 40 CFR Section 60.116(b)(b) will be kept for the life of the

source. 33.0

CD 40 CFR Section 60.116b(f); 40 CFR Section 60.116b(f)(1); 40 CFR Section 60.116b(f)(2)(i)-(iii); Minn. R. 7011.1520(C) The owner or operator of each vessel storing a waste mixture of indeterminate or variable composition shall be subject to the following requirements.

(1) Prior to the initial filling of the vessel, the highest maximum true vapor pressure for the range of anticipated liquid compositions to be stored will be determined using the methods described in 40 CFR Section 60.116b(e).

(2) For vessels in which the vapor pressure of the anticipated liquid composition is above the cutoff for monitoring but below the cutoff for controls as defined in 40 CFR Section 60.112b(a), an initial physical test of the vapor pressure is required; and a physical test at least once every 6 months thereafter is required as determined by the following methods: (i) ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or (ii) ASTM D323-82 or 94 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) As measured by an appropriate method as approved by the Administrator. 34.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 43 of 407

Subject Item: GP 023 NSPS K Tanks w/ fixed roof > 40,000 gals without CVS/CD

Associated Items: TK 500 Cooling Water @ 21 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.342(c)(1)(ii); Minn. R. 7011.1520(A) May not store benzene waste as defined in 40 CFR Section 61.341 UNLESS that waste is exempted from control under 40 CFR Section 61.342. 1.0

CD 40 CFR Section 63.641 Defn-Group 1 storage vessel; Minn. R. 7011.1520(A) May not store a material that is >4% organic HAPs (annual average) per Table 1 of 40 CFR pt. 63, subp. CC AND has an annual true vapor pressure >8.3kPA. 2.0

CD 40 CFR Section 60.112(a)(1)-(2); Minn. R. 7011.1520(A) The owner or operator of any storage vessel to which this subpart applies shall store petroleum liquids as follows:

(1) If the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 78 mm Hg (1.5 psia) but not greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a floating roof, a vapor recovery system, or their equivalents.

(2) If the true vapor pressure of the petroleum liquid as stored is greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 3.0

CD 40 CFR Section 60.113(a); Minn. R. 7011.1520(A) Except as provided in paragraph (d) of 40 CFR Section 60.113, the owner or operator shall maintain a record of the petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. 4.0

CD 40 CFR Section 60.113(b); Minn. R. 7011.1520(A) A vailable data on the typical Reid vapor pressure and the maximum expected storage temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517, unless the

A dministrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s). 5.0

CD 40 CFR Section 60.113(c); Minn. R. 7011.1520(A) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa (2.0 psia) or whose physical properties preclude determination by

the recommended method is to be determined from available data and recorded if the estimated true vapor pressure is greater than 6.9 kPa (1.0 psia). 6.0

CD 40 CFR Section 60.113(d); Minn. R. 7011.1520(A) The following are exempt from the requirements of 40 CFR Section 60.113:

(1) Each owner or operator of each affected facility which stores petroleum liquids with a Reid vapor pressure of less than 6.9 kPa (1.0 psia) provided the maximum true vapor pressure does not exceed 6.9 kPa (1.0 psia).

(2) Each owner or operator of each affected facility equipped with a vapor recovery and return or disposal system in accordance with the requirements of 40 CFR

Section 60.112. 7.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 44 of 407

Subject Item: GP 024 NSPS Ka Tanks w/fixed roof > 40,000 gals

Associated Items: TK 502 Jet Water @ 23 Unit

TK 505 Sulfur

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.342(c)(1)(ii); Minn. R. 7011.1520(B) May not store benzene waste as defined in 40 CFR Section 61.341 UNLESS that waste is exempted from control under 40 CFR Section 61.342. 1.0

CD 40 CFR Section 63.641 Defn-Group 1 storage vessel; Minn. R. 7011.1520(B) May not store a material that is >4% organic HAPs (annual average) per Table 1 of 40 CFR pt. 63, subp. CC AND has an annual true vapor pressure >8.3kPA. 2.0

CD 40 CFR Section 60.112a(a); 40 CFR Section 60.112(a)(a)(4) If a storage vessel contains a petroleum liquid which, as stored, has a true vapor pressure equal to or greater than 10.3 Kpa (1.5 psia) but not greater than 76.6 kPa (11.1 psia) the storage vessel shall be equipped with an external floating roof per 40 CFR Section 60.112a(a)(1)(i)-(iv), internal floating roof per 40 CFR Section 60.112a(a)(2), a vapor recovery system per 40 CFR Section 60.112a(a)(3) or a system equivalent to those described in paragraphs (a)(1), (a)(2) or (a)(3) of 40 CFR Section 60.112a as provided in 40 CFR Section 60.114a. 3.0

CD 40 CFR Section 60.115a(a); Minn. R. 7011.1520(B) Except as provided in 40 CFR Section 60.115a(d), the owner or operator subject to this subpart shall maintain a record of the petroleum liquid stored, the period of storage, and the maximum true vapor pressure of that liquid during the respective storage period. 4.0

CD 40 CFR Section 60.115a(b); Minn. R. 7011.1520(B) A vailable data on the typical Reid vapor pressure and the maximum expected storage temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517, unless the

A dministrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s). 5.0

CD 40 CFR Section 60.115a(c); Minn. R. 7011.1520(B) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa (2.0 psia) or whose physical properties preclude determination by

the recommended method is to be determined from available data and recorded if the estimated true vapor pressure is greater than 6.9 kPa (1.0 psia). 6.0

CD 40 CFR Section 60.115a(d)(1)-(2); Minn. R. 7011.1520(B) The following are exempt from the requirements of 40 CFR Section 60.115a:

(1) Each owner or operator of each storage vessel storing a petroleum liquid with a Reid vapor pressure of less than 6.9 kPa (1.0 psia) provided the maximum true vapor pressure does not exceed 6.9 kPa (1.0 psia).

(2) The owner or operator of each storage vessel equipped with a vapor recovery and return or disposal system in accordance with the requirements of 40 CFR Section 60.112a(a)(3) and (b), or a closed vent system and control device meeting the specifications of 40 CFR Section 65.42(b)(4), (b)(5), or (c). 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 45 of 407

Subject Item: GP 026 NSPS Kb Tanks w/fixed roof & CVS/CD 19,813-39,890 gals

Associated Items: TK 200 Organic Liquid@ 103 Unit

TK 201 Organic Liquid @ 103 Unit

TK 303 Chemical/Additive Storage Tank

TK 373 Chemical/Additive Storage Tank @ 45 Unit

TK 514 Chemical/Additive Storage Tank @ 26 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112b(a); 40 CFR Section 61.342(c)(1)(ii) Maintain records of current applicability of NSPS, Subpart Kb control requirements and NESHAP, Subpart FF control requirements for each tank on-site. Records may

be electronic. 1.0

CD 40 CFR Section 60.112b(a) If storing VOL with max TVP greater than 4.0 psia, comply with requirements listed within this group. 2.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 63.647(a); Minn. R. 7011.9930(E) If storing benzene waste as defined in 40 CFR Section 61.341 and either not exempting that waste from control under 40 CFR Section 61.342 or classifying the waste as controlled, comply with the requirements listed within this group regardless of the vapor pressure. 3.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 61.351(a); Minn. R. 7011.1520, subp. C; Minn. R. 7011.9930(E) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 4.0

CD September 2, 2004, Letter to FHR from Mr. George T. Czerniak, Chief, Air Enforcement and Compliance Assurance Branch, U.

S. EPA. Frac tanks are exempt from NSPS, subp. Kb. 5.0

CD 40 CFR Section 60.112b(a)(3)(i)-(ii); 40 CFR Section 112b(b)(1); Minn. R. 7011.1520(C); 40 CFR pt. 60, subp. VVa (i) The closed vent system shall be designed to collect all VOC vapors and gases discharged from the storage vessel and operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background and visual inspections, as determined in 40 CFR pt. 60, subpart VVa, 40 CFR Section 60.485a(b).

(ii) The control device shall be designed and operated to reduce inlet VOC emissions by 95 percent or greater. If a flare is used as the control device, it shall meet the specifications described in the general control device requirements 40

CFR Section 60.18 of the General Provisions. 6.0

CD 40 CFR Section 60.113b(c); Minn. R. 7011.1520(C) The owner or operator of each source that is equipped with a closed vent system and control device as required in 40 CFR Section 60.112b (a)(3) or (b)(2) (other than a flare) is exempt from 40 CFR Section 60.8 of the General Provisions. 7.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) Submit for approval by the Administrator as an attachment to the notification required by 40 CFR Section 60.7(a)(1) or, if the facility is exempt from 40 CFR Section 60.7(a)(1), as an attachment to the notification required by 40 CFR Section 60.7(a)(2), an operating plan containing the information listed below. (continued below) 8.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) i) Documentation demonstrating that the control device will achieve the required control efficiency during maximum loading conditions. This documentation is to include a description of the gas stream which enters the control device, including flow and VOC content under varying liquid level conditions (dynamic and static) and manufacturer's design specifications for the control device. If the control device or the closed vent capture system receives vapors, gases, or liquids other than fuels from sources that are not designated sources under this subpart, the efficiency demonstration is to include consideration of all vapors, gases, and liquids received by the closed vent capture system and control device. If an enclosed combustion device with a minimum residence time of 0.75 sec and a minimum temperature of 816 °C is used to meet the 95% requirement, documentation that those conditions will exist is sufficient to meet the requirements of this paragraph. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 46 of 407

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) (ii) A description of the parameter or parameters to be monitored to ensure that the control device will be operated in conformance with its design and an explanation of the criteria used for selection of that parameter (or parameters). 10.0

CD 40 CFR Section 60.113b(c)(2); Minn. R. 7011.1520(C) Operate the closed vent system and control device and monitor the parameters of the closed vent system and control device in accordance with the operating plan submitted to the Administrator in accordance with 40 CFR Section 60.113b(c)(1), unless the plan was modified by the Admininstrator during the review process. In this case, the modified plan applies. 11.0

CD 40 CFR Section 60.113b(d); Minn. R. 7011.1520(C) The owner or operator of each source that is equipped with a closed vent system and a flare to meet the requirements in 40 CFR Section 60.112b (a)(3) or (b)(2) shall meet the requirements as specified in the general control device requirements, 40 CFR Section 60.18 (e) and (f). 12.0

CD 40 CFR Section 60.115b; Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.112b(a) shall keep records and furnish reports as required by 40 CFR Section 60.115b(c). The owner or operator shall keep copies of all reports and records required by 40 CFR Section 60.115b, except for the record required by 40 CFR Section 60.115b(c)(1), for at least 2 years. The record required by 40 CFR Section 60.115b(c)(1) will be kept for the life of the control equipment. 13.0

CD 40 CFR Section 60.115b; 40 CFR Section 60.115b(c)(1) and (2); Minn. R. 7011.1520(C) The owner or operator shall keep the following records.

(1) A copy of the operating plan.

(2) A record of the measured values of the parameters monitored in accordance with 40 CFR Section 60.113b(c)(2). 14.0

CD 49 CFR Section 60.115b(d)(1)-(3); Minn. R. 7011.1520(C) A fter installing a closed vent system and flare to comply with 40 CFR Section 60.112b, the owner or operator shall meet the following requirements.

(1) A report containing the measurements required by 40 CFR Section 60.18(f) (1), (2), (3), (4), (5), and (6) shall be furnished to the Administrator as required by 40 CFR Section 60.8 of the General Provisions. This report shall be submitted within 6 months of the initial start-up date.

(2) Records shall be kept of all periods of operation during which the flare pilot

flame is absent.

(3) Semiannual reports of all periods recorded under 40 CFR Section 60.115b(d)(2) in which the pilot flame was absent shall be furnished to the Administrator. 15.0

CD 40 CFR Section 60.116b(a); Minn. R. 7011.1520(C) The owner or operator shall keep copies of all records required by 40 CFR Section 60.116b except for the record required by 40 CFR Section 60.116b(b), for at least 2 years. The record required by 40 CFR Section 60.116b(b) will be kept for the life of

the source. 16.0

CD 40 CFR Section 60.116b(b); Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.110b(a) shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel. 17.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) A vailable data on the storage temperature may be used to determine the maximum true vapor pressure as determined below.

(1) For vessels operated above or below ambient temperatures, the maximum true vapor pressure is calculated based upon the highest expected calendar-month average of the storage temperature. For vessels operated at ambient temperatures, the maximum true vapor pressure is calculated based upon the maximum local monthly average ambient temperature as reported by the National Weather Service

. (continued below) 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 47 of 407

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) (2) For crude oil or refined petroleum products the vapor pressure may be obtained by the following:

(i) Available data on the Reid vapor pressure and the maximum expected storage temperature based on the highest expected calendar-month average temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517 (incorporated by reference, see 40 CFR Section 60.17), unless the Administrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s).

(ii) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa or with physical properties that preclude determination by the

recommended method is to be determined from available data and recorded if the estimated maximum true vapor pressure is greater than 3.5 kPa. (continued below) 19.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) (3) For other liquids, the vapor pressure:

(i) May be obtained from standard reference texts, or

(ii) Determined by ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) Measured by an appropriate method approved by the Administrator; or

(iv) Calculated by an appropriate method approved by the Administrator. 20.0

CD 40 CFR Section 60.116b(f); 40 CFR Section 60.116b(f)(1); 40 CFR Section 60.116b(f)(2)(i)-(iii); Minn. R. 7011.1520(C) The owner or operator of each vessel storing a waste mixture of indeterminate or variable composition shall be subject to the following requirements.

(1) Prior to the initial filling of the vessel, the highest maximum true vapor pressure for the range of anticipated liquid compositions to be stored will be determined using the methods described in 40 CFR Section 60.116b(e).

(2) For vessels in which the vapor pressure of the anticipated liquid composition is above the cutoff for monitoring but below the cutoff for controls as defined in 40 CFR Section 60.112b(a), an initial physical test of the vapor pressure is required; and a physical test at least once every 6 months thereafter is required as determined by the following methods: (i) ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or (ii) ASTM D323-82 or 94 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) As measured by an appropriate method as approved by the Administrator 21.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 48 of 407

Subject Item: GP 032 NSPS K Tanks w/fixed roof & CVS/CD & > 40,000 gals

Associated Items: TK 367 Non-Phen Water @ 45 Unit

TK 368 Non-Phen Water @ 45 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112(a); 40 CFR Section 60.112(a)(1); Minn. R. 7011.1520(A) If storing a petroleum liquid, and if the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 78 mm Hg (1.5 psia) but not greater than 570 mm Hg (11.1 psia) the storage vessel shall be equipped with a floating roof, a vapor recovery system or their equivalents. 1.0

CD 40 CFR Section 60.112(a); 40 CFR Section 60.112(a)(2); Minn. R. 7011.1520(A) If storing a petroleum liquid, and if the true vapor pressure of the petroleum liquid, as stored, is greater than 570 mm Hg (11.1psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 2.0

CD 40 CFR Section 63.641 Defn-Group 1 storage vessel; Minn. R. 7011.1520(A) May not store a material that is >4% organic HAPs (annual average) per Table 1 of 40 CFR pt. 63, subp. CC AND has an annual average true vapor pressure >8.3kPa. 3.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 49 of 407

Subject Item: GP 034 NSPS Kb Tanks w/fixed roof & CVS/CD > 39,890 gals

Associated Items: TK 019 Asphalt

TK 021 Organic Liquid

TK 022 Organic Liquid

TK 029 Asphalt

TK 030 Organic Liquid

TK 031 Organic Liquid

TK 033 Organic Liquid

TK 035 Organic Liquid

TK 037 Asphalt

TK 038 Organic Liquid

TK 039 Asphalt

TK 046 Organic Liquid

TK 047 Organic Liquid

TK 081 Organic Liquid

TK 130 Organic Liquid

TK 131 Organic Liquid

TK 132 Organic Liquid

TK 133 Organic Liquid

TK 134 Organic Liquid

TK 153 Organic Liquid

TK 154 Organic Liquid

TK 336 Organic Liquid Storage Tank

TK 411 Asphalt

TK 412 Asphalt

TK 414 Asphalt

TK 415 Asphalt

TK 416 Asphalt

TK 417 Asphalt

TK 418 Asphalt

TK 423 Asphalt

TK 424 Asphalt

TK 515 Sour Water Tank @ 26 Unit

TK 516 Stripped Sour Water @ 26 Unit

TK 526 Sulfur Storage Tank

TK 528 Chemical/Additive Storage Tank 35TK4

TK 573 Chemical/Additive Storage Tank 102TK15

TK 574 Spent Sulfuric Acid Storage Tank 35TK5

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112b(a)-(b); 40 CFR Section 61.342(c)(1)(ii) Maintain records of current applicability of NSPS, Subpart Kb control requirements and NESHAP, Subpart FF control requirements for each tank on-site. Records may

be electronic. 1.0

CD 40 CFR Section 60.112b(a) If storing VOL with max TVP greater than 0.75 psia, comply with requirements listed within this group. 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 50 of 407

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 63.647(a); Minn. R. 7011.9930(E) If storing benzene waste as defined in 40 CFR Section 61.341 and either not exempting that waste from control under 40 CFR Section 61.342 or classifying the waste as controlled, comply with the requirements listed within this group regardless of vapor pressure. 3.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 61.351(a); Minn. R. 7011.1520(C); Minn. R. 7011.9930(E) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 4.0

CD 40 CFR Section 60.112b(a)(3)(i)-(ii); 40 CFR Section 112b(b)(1); Minn. R. 7011.1520(C); 40 CFR pt. 60, subp. VVa (i) The closed vent system shall be designed to collect all VOC vapors and gases discharged from the storage vessel and operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background and visual inspections, as determined in 40 CFR pt. 60, subpart VVa, 40 CFR Section 60.485a(b).

(ii) The control device shall be designed and operated to reduce inlet VOC emissions by 95 percent or greater. If a flare is used as the control device, it shall meet the specifications described in the general control device requirements 40

CFR Section 60.18 of the General Provisions. 5.0

CD 40 CFR Section 60.113b(c); Minn. R. 7011.1520(C) The owner or operator of each source that is equipped with a closed vent system and control device as required in 40 CFR Section 60.112b (a)(3) or (b)(2) (other than a flare) is exempt from 40 CFR Section 60.8 of the General Provisions. 6.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) Submit for approval by the Administrator as an attachment to the notification required by 40 CFR Section 60.7(a)(1) or, if the facility is exempt from 40 CFR Section 60.7(a)(1), as an attachment to the notification required by 40 CFR Section 60.7(a)(2), an operating plan containing the information listed below. (continued below) 7.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) (i) Documentation demonstrating that the control device will achieve the required control efficiency during maximum loading conditions. This documentation is to include a description of the gas stream which enters the control device, including flow and VOC content under varying liquid level conditions (dynamic and static) and manufacturer's design specifications for the control device. If the control device or the closed vent capture system receives vapors, gases, or liquids other than fuels from sources that are not designated sources under this subpart, the efficiency demonstration is to include consideration of all vapors, gases, and liquids received by the closed vent capture system and control device. (continued below) 8.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above)

If an enclosed combustion device with a minimum residence time of 0.75 seconds and a minimum temperature of 816 °C is used to meet the 95 percent requirement, documentation that those conditions will exist is sufficient to meet the requirements of this paragraph.

(ii) A description of the parameter or parameters to be monitored to ensure that the control device will be operated in conformance with its design and an explanation of the criteria used for selection of that parameter (or parameters). 9.0

CD 40 CFR Section 60.113b(c)(2); Minn. R. 7011.1520(C) Operate the closed vent system and control device and monitor the parameters of the closed vent system and control device in accordance with the operating plan submitted to the Administrator in accordance with 40 CFR Section 60.113b(c)(1), unless the plan was modified by the Administrator during the review process. In this case, the modified plan applies. 10.0

CD 40 CFR Section 60.113b(d); Minn. R. 7011.1520(C) The owner or operator of each source that is equipped with a closed vent system and a flare to meet the requirements in 40 CFR Section 60.112b (a)(3) or (b)(2) shall meet the requirements as specified in the general control device requirements, 40 CFR Section 60.18 (e) and (f). 11.0

CD 40 CFR Section 60.115b; Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.112b(a) shall keep records and furnish reports as required by 40 CFR Section 60.115b(c). The owner or operator shall keep copies of all reports and records required by 40 CFR Section 60.115b, except for the record required by 40 CFR Section 60.115b(c)(1), for at least 2 years. The record required by 40 CFR Section 60.115b(c)(1) will be kept for the life of the control equipment. 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 51 of 407

CD 40 CFR Section 60.115b(c)(1)-(2); Minn. R. 7011.1520(C) The owner or operator shall keep the following records.

(1) A copy of the operating plan.

(2) A record of the measured values of the parameters monitored in accordance with 40 CFR Section 60.113b(c)(2). 13.0

CD 49 CFR Section 60.115b(d)(1)-(3); Minn. R. 7011.1520(C) A fter installing a closed vent system and flare to comply with 40 CFR Section 60.112b, the owner or operator shall meet the following requirements.

(1) A report containing the measurements required by 40 CFR Section 60.18(f) (1), (2), (3), (4), (5), and (6) shall be furnished to the Administrator as required by 40 CFR Section 60.8 of the General Provisions. This report shall be submitted within 6 months of the initial start-up date.

(2) Records shall be kept of all periods of operation during which the flare pilot

flame is absent.

(3) Semiannual reports of all periods recorded under 40 CFR Section 60.115b(d)(2) in which the pilot flame was absent shall be furnished to the Administrator. 14.0

CD 40 CFR Section 60.116b(a); Minn. R. 7011.1520(C) The owner or operator shall keep copies of all records required by 40 CFR Section 60.116b except for the record required by 40 CFR Section 60.116b(b), for at least 2 years. The record required by 40 CFR Section 60.116b(b) will be kept for the life of

the source. 15.0

CD 40 CFR Section 60.116b(b); Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.110b(a) shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel. 16.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) A vailable data on the storage temperature may be used to determine the maximum true vapor pressure as determined below.

(1) For vessels operated above or below ambient temperatures, the maximum true vapor pressure is calculated based upon the highest expected calendar-month average of the storage temperature. For vessels operated at ambient temperatures, the maximum true vapor pressure is calculated based upon the maximum local monthly average ambient temperature as reported by the National Weather Service

. (continued below) 17.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) (2) For crude oil or refined petroleum products the vapor pressure may be obtained by the following:

(i) Available data on the Reid vapor pressure and the maximum expected storage temperature based on the highest expected calendar-month average temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517 (incorporated by reference, see 40 CFR Section 60.17), unless the Administrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s).

(ii) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa or with physical properties that preclude determination by the

recommended method is to be determined from available data and recorded if the estimated maximum true vapor pressure is greater than 3.5 kPa. (continued below) 18.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) (3) For other liquids, the vapor pressure:

(i) May be obtained from standard reference texts, or

(ii) Determined by ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) Measured by an appropriate method approved by the Administrator; or

(iv) Calculated by an appropriate method approved by the Administrator. 19.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 52 of 407

CD 40 CFR Section 60.116b(f); 40 CFR Section 60.116b(f)(1); 40 CFR Section 60.116b(f)(2)(i)-(iii); Minn. R. 7011.1520(C) The owner or operator of each vessel storing a waste mixture of indeterminate or variable composition shall be subject to the following requirements.

(1) Prior to the initial filling of the vessel, the highest maximum true vapor pressure for the range of anticipated liquid compositions to be stored will be determined using the methods described in 40 CFR Section 60.116b(e).

(2) For vessels in which the vapor pressure of the anticipated liquid composition is above the cutoff for monitoring but below the cutoff for controls as defined in 40 CFR Section 60.112b(a), an initial physical test of the vapor pressure is required; and a physical test at least once every 6 months thereafter is required as determined by the following methods: (i) ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or (ii) ASTM D323-82 or 94 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) As measured by an appropriate method as approved by the Administrator 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 53 of 407

Subject Item: GP 037 IFR tank/basin subject to NESHAPs FF following the requirements of Kb

Associated Items: TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.351(a); 40 CFR Section 61.351(a)(1); 40 CFR Section 61.351(b); 40 CFR Section 61.356(k); 40 CFR Section 61.357(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A s an alternative to the standards for tanks specified in 40 CFR Section 61.343; an owner or operator may elect to comply with one of the following:

(1) A fixed roof and internal floating roof meeting the requirements in 40 CFR Section 60.112b(a)(1);

(2) An external floating roof meeting the requirements of 40 CFR Section 60.112b (a)(2); or

(3) An alternative means of emission limitation as described in 40 CFR Section

60.114b.

If an owner or operator elects to comply with the provisions of this section, then the owner or operator is exempt from the provisions of 40 CFR Section 61.343 of this subpart applicable to the same facilities. 2.0

CD 40 CFR Section 61.351(a)(1); 40 CFR Section 63.640(o)(1); 40 CFR Section 63.647(a) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 3.0

CD 40 CFR Section 61.351(a); 40 CFR Section 61.351(a)(1); 40 CFR Section 61.351(b); 40 CFR Section 61.356(k); 40 CFR Section 61.357(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Comply with requirements of GP 039 (NSPS, Subpart Kb for Internal Floating Roof Tanks) 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 54 of 407

Subject Item: GP 039 NSPS Kb Tanks w/internal floating roof > 39,890 gals

Associated Items: TK 010 Organic Liquid

TK 011 Organic Liquid

TK 012 Organic Liquid

TK 013 Organic Liquid

TK 014 Organic Liquid

TK 015 Organic Liquid

TK 016 Organic Liquid

TK 017 Organic Liquid

TK 018 Organic Liquid

TK 023 Organic Liquid

TK 024 Organic Liquid

TK 025 Organic Liquid

TK 026 Organic Liquid

TK 027 Organic Liquid

TK 028 Organic Liquid

TK 048 Organic Liquid

TK 049 Organic Liquid

TK 065 Ethanol

TK 067 Organic Liquid

TK 082 Organic Liquid

TK 084 Organic Liquid

TK 085 Organic Liquid

TK 086 Organic Liquid

TK 161 Organic Liquid

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

TK 522 Heavy Naphtha

TK 523 Heavy Naphtha

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112b(a); 40 CFR Section 61.342(c)(1)(ii) Maintain records of current applicability of NSPS, Subpart Kb control requirements and NESHAP, Subpart FF control requirements for each tank on-site. Records may

be electronic. 1.0

CD 40 CFR Section 60.112b(a) If storing VOL with max TVP equal to or greater than 0.75 psia and less than 11.1 psia, comply with the requirements listed within this group. 2.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 63.647(a); Minn. R. 7011.9930(E) If storing benzene waste as defined in 40 CFR Section 61.341 and either not exempting that waste from control under 40 CFR Section 61.342, or classifying the waste as controlled, comply with the requirements listed within this group regardless of vapor pressure. 3.0

CD 40 CFR Section 61.342(c)(1)(ii); 40 CFR Section 61.351(a); Minn. R. 7011.1520, subp. C; Minn. R. 7011.9930(E) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 55 of 407

CD 40 CFR Section 60.112b(a)(1)(i); Minn. R. 7011.1520(C) The internal floating roof shall rest or float on the liquid surface (but not necessarily in complete contact with it) inside a storage vessel that has a fixed roof. The internal floating roof shall be floating on the liquid surface at all times, except during initial fill and during those intervals when the storage vessel is completely emptied or subsequently emptied and refilled. When the roof is resting on the leg supports, the process of filling, emptying, or refilling shall be continuous and shall be accomplished as rapidly as possible. 5.0

CD 40 CFR Section 60.112b(a)(1)(ii)(A)-(C); Minn. R. 7011.1520(C) Each internal floating roof shall be equipped with one of the following closure devices between the wall of the storage vessel and the edge of the internal floating

roof:

(A) A foam- or liquid-filled seal mounted in contact with the liquid (liquid-mounted seal). A liquid-mounted seal means a foam- or liquid-filled seal mounted in contact with the liquid between the wall of the storage vessel and the floating roof continuously around the circumference of the tank.

(B) Two seals mounted one above the other so that each forms a continuous closure that completely covers the space between the wall of the storage vessel and the edge of the internal floating roof. The lower seal may be vapor-mounted,

but both must be continuous. (continued below) 6.0

CD 40 CFR Section 60.112b(b)(1)(ii)(A)-(C); Minn. R. 7011.1520(C) (continued from above) (C) A mechanical shoe seal. A mechanical shoe seal is a metal sheet held vertically against the wall of the storage vessel by springs or weighted levers and is connected by braces to the floating roof. A flexible coated fabric (envelope) spans the annular space between the metal sheet and the floating roof.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 7.0

CD 40 CFR Section 60.112b(a)(1)(iii); Minn. R. 7011.1520(C) Each opening in a noncontact internal floating roof except for automatic bleeder vents (vacuum breaker vents) and the rim space vents is to provide a projection below the liquid surface.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 8.0

CD 40 CFR Section 60.112b(a)(1)(iv); Minn. R. 7011.1520(C) Each opening in the internal floating roof except for leg sleeves, automatic bleeder vents, rim space vents, column wells, ladder wells, sample wells, and stub drains is to be equipped with a cover or lid which is to be maintained in a closed position at all times (i.e., no visible gap) except when the device is in actual use. The cover or lid shall be equipped with a gasket. Covers on each access hatch and automatic gauge float well shall be bolted except when they are in use.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 9.0

CD 40 CFR Section 60.112b(a)(1)(v); Minn. R. 7011.1520(C) A utomatic bleeder vents shall be equipped with a gasket and are to be closed at all times when the roof is floating except when the roof is being floated off or is being landed on the roof leg supports.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 10.0

CD 40 CFR Section 60.112b(a)(1)(vi); Minn. R. 7011.1520(C) Rim space vents shall be equipped with a gasket and are to be set to open only when the internal floating roof is not floating or at the manufacturer's recommended setting.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 11.0

CD 40 CFR Section 60.112b(a)(1)(vii); Minn. R. 7011.1520(C) Each penetration of the internal floating roof for the purpose of sampling shall be a sample well. The sample well shall have a slit fabric cover that covers at least 90 percent of the opening.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 56 of 407

CD 40 CFR Section 60.112b(a)(1)(viii); Minn. R. 7011.1520(C) Each penetration of the internal floating roof that allows for passage of a column supporting the fixed roof shall have a flexible fabric sleeve seal or a gasketed sliding cover.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 13.0

CD 40 CFR Section 60.112b(a)(1)(ix); Minn. R. 7011.1520(C) Each penetration of the internal floating roof that allows for passage of a ladder shall have a gasketed sliding cover.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 14.0

CD 40 CFR Section 60.113b(a)(1); Minn. R. 7011.1520(C) Visually inspect the internal floating roof, the primary seal, and the secondary seal (if one is in service), prior to filling the storage vessel with VOL. If there are holes, tears, or other openings in the primary seal, the secondary seal, or the seal fabric or defects in the internal floating roof, or both, the owner or operator shall repair the items before filling the storage vessel.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 15.0

CD 40 CFR Section 60.113b(a)(2); 40 CFR Section 60.113b(a)(3)(ii); 40 CFR Section 63.640(n)(8)(iii); Minn. R. 7011.1520(C) For vessels equipped with a liquid-mounted or mechanical shoe primary seal, visually inspect the internal floating roof and the primary seal or the secondary seal (if one is in service) through manholes and roof hatches on the fixed roof at least once every 12 months after initial fill. If the internal floating roof is not resting on the surface of the VOL inside the storage vessel, or there is liquid accumulated on the roof, or the seal is detached, or there are holes or tears in the seal fabric, the owner or operator shall repair the items or empty and remove the storage vessel from service within 45 days. If a failure that is detected during inspections required in this paragraph cannot be repaired within 45 days and if the vessel cannot be emptied within 45 days, the owner or operator may utilize up to two extensions of up to 30 additional calendar days each. (continued below) 16.0

CD 40 CFR Section 60.113b(a)(2); 40 CFR Section 60.113b(a)(3)(ii); Minn. R. 7011.1520(C) (continued from above) Pursuant to 40 CFR Section 63.640 (n)(8)(iii), the owner or operator is not required to provide a request for the extension to the Administrator. Such a request for an extension must document that alternate storage capacity is unavailable and specify a schedule of actions the company will take that will assure that the control equipment will be repaired or the vessel will be emptied as soon as possible. 17.0

CD 40 CFR Section 60.113b(a)(3)(i)-(ii); 40 CFR Section 60.113b(a)(4); Minn. R. 7011.1520(C) For vessels equipped with a double seal system as specified in 40 CFR Section 60.112b(a)(1)(ii)(B)

i) visually inspect the vessel as specified in 40 CFR 60.113(b)(a)(4) at least every 5

years; or

ii) visually inspect the vessel as specified in 40 CFR Section 60. 113(b)(a)(2). 18.0

CD 40 CFR Section 60.113b(a)(4); Minn. R. 7011.1520(C) Visually inspect the internal floating roof, the primary seal, the secondary seal (if one is in service), gaskets, slotted membranes and sleeve seals (if any) each time the storage vessel is emptied and degassed. If the internal floating roof has defects, the primary seal has holes, tears, or other openings in the seal or the seal fabric, or the secondary seal has holes, tears, or other openings in the seal or the seal fabric, or the gaskets no longer close off the liquid surfaces from the atmosphere, or the slotted membrane has more than 10 percent open area, the owner or operator shall repair the items as necessary so that none of the conditions specified in this paragraph exist before refilling the storage vessel with VOL.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. (continued below) 19.0

CD 40 CFR Section 60.113b(a)(4); Minn. R. 7011.1520(C) (continued from above) In no event shall inspections conducted in accordance with this provision occur at intervals greater than 10 years in the case of vessels conducting the annual visual inspection as required by 40 CFR Section 60.113b(a)(2) and (a)(3)(ii) and at intervals no greater than 5 years in the case of vessels specified in 40 CFR Section 60.113b(a)(3)(ii). 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 57 of 407

CD STERP Agreement March 2001 Slotted Guidepoles The sliding cover shall be in place over the slotted guidepole opening through the floating roof at all times except when the sliding cover must be removed for access. If the control technology used includes a guidepole float, the float shall be floating within the guidepole at all times except when it must be removed for access to the stored liquid or when the tank is empty.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 21.0

CD STERP Agreement March 2001 Slotted Guidepoles Visually inspect the deck fitting for the slotted guidepole deck fitting at least once every 10 years and each time the vessel is emptied and degassed. If the slotted guidepole deck fitting or control devices have defects, or if a gap of > 1/8" exists between any gasket required for control of the slotted guidepole deck fitting and any surface it is intended to seal, such items shall be repaired before filling or refilling the storage vessel with regulated material. Tanks taken out of hydrocarbon service, for any reason, do not have to have any controls in place during the time they are out of service.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 22.0

CD STERP Agreement March 2001 Slotted Guidepoles If the tank is in service, all slotted guidepole deck fitting or control device defects or gaps >1/8" on gaskets or seals required for control must be repaired within 45 days of inspection. If necessary, the owner or operator may utilize up to two extensions of up to 30 additional calendar days each. Pursuant to 40 CFR Section 63.640 (n)(8)(iii), the owner or operator is not required to provide a request for the

extension to the Administrator. 23.0

CD May 24, 2004, Letter from James K. Jackson, U. S. EPA Double wiper seals are approved control technology for slotted ladders under FHR's Storage Tank Emission Partnership Agreement. 24.0

CD 40 CFR Section 60.115b; Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.112b(a) shall keep records and furnish reports as required by 40 CFR Section 60.115b(a). The owner or operator shall keep copies of all reports and records required by this section for at least 2 years. 25.0

CD 40 CFR Section 60.115b(a)(1); Minn. R. 7011.1520(C) Furnish the Administrator with a report that describes the control equipment and certifies that the control equipment meets the specifications of 40 CFR Section 60.112b(a)(1) and 40 CFR Section 60.113b(a)(1). This report shall be an attachment to the notification required by 40 CFR Section 60.7(a)(3). 26.0

CD 40 CFR Section 60.116b(a); Minn. R. 7011.1520(C) The owner or operator shall keep copies of all records required by this section, except for the record required by 40 CFR Section 60.116b(b) for at least 2 years. The record required by 40 CFR Section 60.116b(b) will be kept for the life of the

source. 27.0

CD 40 CFR Section 60.116b(b); Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.110b(a) shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel. 28.0

CD 40 CFR Section 60.116b(c); Minn. R. 7011.1520(C) Except as provided in 40 CFR Section 60.116b(f) and (g), the owner or operator of each storage vessel either with a design capacity greater than or equal to 151 m3 storing a liquid with a maximum true vapor pressure greater than or equal to 3.5 kPa or with a design capacity greater than or equal to 75 m3 but less than 151 m3 storing a liquid with a maximum true vapor pressure greater than or equal to 15.0 kPa shall maintain a record of the VOL stored, the period of storage, and the maximum true vapor pressure of that VOL during the respective storage period. 29.0

CD 40 CFR Section 60.115b(a)(2); Minn. R. 7011.1520(C) Keep a record of each inspection performed as required by 40 CFR Section 60.113b (a)(1), (a)(2), (a)(3), and (a)(4). Each record shall identify the storage vessel on which the inspection was performed and shall contain the date the vessel was inspected and the observed condition of each component of the control equipment (seals, internal floating roof, and fittings). 30.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 58 of 407

CD 40 CFR Section 60.113b(a)(5); 40 CFR Section 60.19(b)-(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); Minn. R. 7011.1520(C) Notify the Administrator in writing at least 30 days prior to the filling or refilling of each storage vessel for which an inspection is required by 40 CFR Section 60.113b(a)(1) and (a)(4) to afford the Administrator the opportunity to have an observer present. If the inspection required by 40 CFR Section 60.113b(a)(4) is not planned and the owner or operator could not have known about the inspection 30 days in advance or refilling the tank, the owner or operator shall notify the

A dministrator at least 7 days prior to the refilling of the storage vessel. Notification shall be made by telephone immediately followed by written documentation demonstrating why the inspection was unplanned. Alternatively, this notification including the written documentation may be made in writing and sent by express mail so that it is received by the Administrator at least 7 days prior to the refilling. 31.0

CD 40 CFR Section 60.115b(a)(3)-(4) 40 CFR Section 60.19(b)-(c); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); Minn. R. 7011.1520(C) If any of the conditions described in 40 CFR Section 60.113b(a)(2) are detected during the annual visual inspection required by 40 CFR Section 60.113b(a)(2), a report shall be furnished to the Administrator within 30 days of the inspection. Each report shall identify the storage vessel, the nature of the defects, and the date the storage vessel was emptied or the nature of and date the repair was made.

A fter each inspection required by 40 CFR Section 60.113b(a)(3) that finds holes or tears in the seal or seal fabric, or defects in the internal floating roof, or other control equipment defects listed in 40 CFR 60.113b(a)(3)(ii), a report shall be furnished to the Administrator within 30 days of the inspection. The report shall identify the storage vessel and the reason it did not meet the specifications of 40 CFR Section 61.112b(a)(1) or 40 CFR Section 60.113b(a)(3) and list each repair

made. 32.0

CD 40 CFR Section 60.116b(e)1; 40 CFR Section 60.116b(e)(2)(i-ii); 40 CFR Section 60.116b(3)(i-iv); Minn. R. 7011.1520(C) A vailable data on the storage temperature may be used to determine the maximum true vapor pressure as determined below.

(1) For vessels operated above or below ambient temperatures, the maximum true vapor pressure is calculated based upon the highest expected calendar-month average of the storage temperature. For vessels operated at ambient temperatures, the maximum true vapor pressure is calculated based upon the maximum local monthly average ambient temperature as reported by the National Weather Service

. (continued below) 33.0

CD 40 CFR Section 60.116b(e)1; 40 CFR Section 60.116b(e)(2)(i-ii); 40 CFR Section 60.116b(3)(i-iv); Minn. R. 7011.1520(C) (continued from above) 2) For crude oil or refined petroleum products the vapor pressure may be obtained by the following:

(i) Available data on the Reid vapor pressure and the maximum expected storage temperature based on the highest expected calendar-month average temperature of the stored product may be used to determine the maximum true vapor pressure from monographs contained in API Bulletin 2517 (incorporated by reference, see 40 CFR Section 60.17), unless the Administrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s). (continued below) 34.0

CD 40 CFR Section 60.116b(e)1; 40 CFR Section 60.116b(e)(2)(i-ii); 40 CFR Section 60.116b(3)(i-iv); Minn. R. 7011.1520(C) (continued from above) (ii) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa or with physical properties that preclude determination by the

recommended method is to be determined from available data and recorded if the estimated maximum true vapor pressure is greater than 3.5 kPa.

(3) For other liquids, the vapor pressure:

(i) May be obtained from standard reference texts, or

(ii) Determined by ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) Measured by an appropriate method approved by the Administrator; or

(iv) Calculated by an appropriate method approved by the Administrator. 35.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 59 of 407

CD 40 CFR Section 60.116(f)(1); 40 CFR Section 60.116b(f)(2)(i-iii); Minn. R. 7011.1520(C) The owner or operator of each vessel storing a waste mixture of indeterminate or variable composition shall be subject to the following requirements. (1) Prior to the initial filling of the vessel, the highest maximum true vapor pressure for the range of anticipated liquid compositions to be stored will be determined using the methods described in 40 CFR Section 60.116b(e). (2) For vessels in which the vapor pressure of the anticipated liquid composition is above the cutoff for monitoring but below the cutoff for controls as defined in 40 CFR Section 60.112b(a), an initial physical test of the vapor pressure is required; and a physical test at least once every 6 months thereafter is required as determined by the following methods:

(i) ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or (ii) ASTM D323-82 or 94 (incorporated by reference, see 40 CFR Section 60.17); or (iii) As measured by an appropriate method as approved by the Administrator. 36.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 60 of 407

Subject Item: GP 042 MACT CC Group 1 Tank Requirements, satisfied by NSPS Kb

Associated Items: TK 001 Organic Liquid

TK 002 Organic Liquid

TK 003 Organic Liquid

TK 004 Organic Liquid

TK 005 Organic Liquid

TK 006 Organic Liquid

TK 007 Organic Liquid

TK 010 Organic Liquid

TK 011 Organic Liquid

TK 012 Organic Liquid

TK 013 Organic Liquid

TK 014 Organic Liquid

TK 015 Organic Liquid

TK 016 Organic Liquid

TK 017 Organic Liquid

TK 018 Organic Liquid

TK 024 Organic Liquid

TK 025 Organic Liquid

TK 026 Organic Liquid

TK 027 Organic Liquid

TK 028 Organic Liquid

TK 061 Organic Liquid

TK 062 Organic Liquid

TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

TK 065 Ethanol

TK 066 Organic Liquid

TK 067 Organic Liquid

TK 080 Organic Liquid

TK 082 Organic Liquid

TK 083 Organic Liquid

TK 084 Organic Liquid

TK 085 Organic Liquid

TK 086 Organic Liquid

TK 087 Organic Liquid

TK 088 Organic Liquid

TK 150 Organic Liquid

TK 151 Organic Liquid

TK 152 Organic Liquid

TK 160 Organic Liquid

TK 161 Organic Liquid

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 UnitMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 61 of 407

Associated Items: TK 367 Non-Phen Water @ 45 Unit

TK 368 Non-Phen Water @ 45 Unit

TK 515 Sour Water Tank @ 26 Unit

TK 522 Heavy Naphtha

TK 523 Heavy Naphtha

TK 586 Sour Water

TK 587 Sour Water

TK 588 Sour Water

NC/

CA Type Citation Requirement

CD 40 CFR Section 63.640(n)(1);
Minn. R. 7011.7280; Minn. R. 7019.0100, subp. 2(A) to 7019.0100, subp. 2(D) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 1.0

CD 40 CFR Section 63.640(a)(2); 40 CFR Section 63.640(c)(2) If storing HAP (per the MACT requirement) comply with the requirements listed under GP 019 for EFR tanks, GP 039 for IFR tanks, GP 034 for FR tanks except comply with GP 122 for TK 517 and associated equipment. 2.0

CD 40 CFR Section 63.6(e)(1)(i)-(iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subp. 2(A) to 7017.2015, subp. 2(B) A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 3.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii); Minn.

R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan. 4.0

CD 40 CFR pt. 63, subp. CC. Table 6; 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv);

Minn. R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or of malfunction or maintenance of air pollution control equipment. Document conformance with or deviation from startup/shutdown/malfunction plan (SSMP). 5.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date SSMP. 6.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 62 of 407

Subject Item: GP 044 Tanks MN R 1969-73 and > 65,000 gals

Associated Items: TK 039 Asphalt

TK 085 Organic Liquid

TK 086 Organic Liquid

TK 411 Asphalt

TK 412 Asphalt

TK 414 Asphalt

NC/

CA Type Citation Requirement

CD Minn. R. 7011.1505, subp. 2C(1)-(2) For tanks storing petroleum liquids listed in Minn. R. 7011.1500, subp. 8, the Permittee shall comply with the following requirements:

(1) If the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 128 mm Hg (2.5 psia) but not greater than 642 mm Hg (12.5 psia) the storage vessel shall be equipped with a floating roof, a vapor recovery system or their equivalents.

(2) If the true vapor pressure of the petroleum liquid, as stored, is greater than 642 mm Hg (12.5 psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 63 of 407

Subject Item: GP 045 Tanks MN R 1969-73 and > 2,000-65,000 gals

Associated Items: TK 201 Organic Liquid @ 103 Unit

NC/

CA Type Citation Requirement

CD Minn. R. 7011.1505, subp. 2(B); Minn. R. 7011.1500, subp. 10 For tanks storing petroleum liquids listed in Minn. R. 7011.1500, subp. 8, the Permittee shall equip the storage vessel (as defined in Minn. R. 7011.1500, subp. 10) with a permanent submerged fill pipe or comply with the following requirements:

(1) If the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 78 mm Hg (1.5 psia) but not greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a floating roof, a vapor recovery system, or their equivalents.

(2) If the true vapor pressure of the petroleum liquid as stored is greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 64 of 407

Subject Item: GP 046 Tanks MN R post 1973 and > 40,000 gals

Associated Items: TK 006 Organic Liquid

TK 007 Organic Liquid

TK 049 Organic Liquid

TK 066 Organic Liquid

TK 067 Organic Liquid

TK 068 Organic Liquid

TK 087 Organic Liquid

TK 088 Organic Liquid

TK 130 Organic Liquid

TK 131 Organic Liquid

TK 132 Organic Liquid

TK 133 Organic Liquid

TK 134 Organic Liquid

TK 150 Organic Liquid

TK 151 Organic Liquid

TK 152 Organic Liquid

TK 153 Organic Liquid

TK 154 Organic Liquid

TK 160 Organic Liquid

TK 161 Organic Liquid

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

TK 300 Water/Process Mixture Storage Tank @ 21 Unit

TK 367 Non-Phen Water @ 45 Unit

TK 368 Non-Phen Water @ 45 Unit

TK 415 Asphalt

TK 416 Asphalt

TK 417 Asphalt

TK 418 Asphalt

TK 423 Asphalt

TK 424 Asphalt

TK 500 Cooling Water @ 21 Unit

TK 502 Jet Water @ 23 Unit

TK 505 Sulfur

TK 515 Sour Water Tank @ 26 Unit

TK 516 Stripped Sour Water @ 26 Unit

TK 517 Organic Liquid Storage Tank

TK 522 Heavy Naphtha

TK 523 Heavy Naphtha

TK 526 Sulfur Storage Tank

TK 574 Spent Sulfuric Acid Storage Tank 35TK5

TK 586 Sour Water

TK 587 Sour WaterMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 65 of 407

Associated Items: TK 588 Sour Water

NC/

CA Type Citation Requirement

CD Minn. R. 7011.1500, subps. 8 and

11 The requirements in this GP 046 only apply to tanks storing petroleum liquids as defined in Minn. R. 7011.1500, subp. 8. 1.0

CD Minn. R. 7011.1510, subp. 3(C)(1)-(2) For tanks storing petroleum liquids listed in Minn. R. 7011.1500, subp. 8, the Permittee shall comply with the following requirements:

(1) If the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 78 mm Hg (1.5 psia) but not greater than 570 mm Hg (11.1 psia) the storage vessel shall be equipped with a floating roof, a vapor recovery system or their equivalents.

(2) If the true vapor pressure of the petroleum liquid, as stored, is greater than 570 mm Hg (11.1psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 2.0

CD Minn. R. 7011.1510, subp. 1(A) Records: The owner or operator shall each storage tank: maintain a file of each type of petroleum liquid stored, of the typical Reid vapor pressure of each type of petroleum liquid stored, of the dates of storage and withdrawals, and of the date on which the storage vessel is empty; 3.0

CD Minn. R. 7011.1510, subp. 1(B)(1)-(2) Records: The owner or operator shall for each storage tank: Determine and record the average monthly storage temperature and true vapor pressure of the petroleum liquid stored at such temperature if:

(1) the petroleum liquid has a true vapor pressure, as stored, greater than 26 mm Hg (0.5 psia) but less than 78 mm Hg (1.5 psia) and is stored in a storage vessel

other than one equipped with a floating roof, a vapor recovery system or their equivalents; or

(2) the petroleum liquid has a true vapor pressure, as stored, greater than 470 mm Hg (9.1 psia) and is stored in a storage vessel other than one equipped with a vapor recovery system or its equivalent. 4.0

CD Minn. R. 7011.1510, subp. 2 Calculation: The average monthly storage temperature is an arithmetic average calculated for each calendar month, or portion thereof if storage is for less than a month, from bulk liquid storage temperatures determined at least once every seven days. 5.0

CD Minn. R. 7011.1510, subp. 3 Vapor pressure determination. The true vapor pressure shall be determined by the procedure in American Petroleum Institute Bulletin 2517. This procedure is dependent upon determination of the storage temperature and the Reid vapor pressure, which requires sampling of the petroleum liquids in the storage vessels. Unless the Agency or the Commissioner requires in specific cases that the stored petroleum liquid be sampled, the true vapor pressure may be determined by using the average monthly storage temperature and the typical Reid vapor pressure. For those liquids for which certified specifications limiting the Reid vapor pressure exist, that Reid vapor pressure may be used. For other liquids, supporting analytical data must be made available on request of the Agency or the Commissioner when typical Reid vapor pressure is used. 6.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 66 of 407

Subject Item: GP 047 Tanks MN R post 1973 and >2,000 - 40,000 gals

Associated Items: TK 373 Chemical/Additive Storage Tank @ 45 Unit

TK 501 Water/Process Mixture Storage Tank

TK 514 Chemical/Additive Storage Tank @ 26 Unit

NC/

CA Type Citation Requirement

CD Minn. R. 7011.1505, subp. 3(B); Minn. R. 7011.1505, subp. 3(C)(1)-(2); Minn. R. 7011.1500, subp. 10 For tanks storing petroleum liquids listed in Minn. R. 7011.1500, subp. 8, the Permittee shall equip the storage vessel (as defined in Minn. R. 7011.1500, subp. 10) with a permanent submerged fill pipe or comply with the following requirements:

(1) If the true vapor pressure of the petroleum liquid, as stored, is equal to or greater than 78 mm Hg (1.5 psia) but not greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a floating roof, a vapor recovery system, or their equivalents.

(2) If the true vapor pressure of the petroleum liquid as stored is greater than 570 mm Hg (11.1 psia), the storage vessel shall be equipped with a vapor recovery system or its equivalent. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 67 of 407

Subject Item: GP 052 Tanks NSPS QQQ

Associated Items: TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.11(d); 40 CFR Section 60.690-60.699; 40 CFR Section 63.640(o)(1); Minn. R. 7011.1435, subp. C Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). [Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks.] 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 68 of 407

Subject Item: GP 053 EFR tank/basin subject to NESHAPs FF following the requirements of Kb

Associated Items: EU 200 OSWTP-Equalization Ba sin 7A - Refining Equipment

EU 201 OSWTP-Equalization Ba sin 7B - Refining Equipment

EU 347 Equalization Basin 94V49 - Above Ground Storage Tank

TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.351(a); 40 CFR Section 61.351(a)(1); 40 CFR Section 61.351(b); 40 CFR Section 61.356(k); 40 CFR Section 61.357(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A s an alternative to the standards for tanks specified in 40 CFR Section 61.343; an owner or operator may elect to comply with one of the following:

(1) A fixed roof and internal floating roof meeting the requirements in 40 CFR Section 60.112b(a)(1);

(2) An external floating roof meeting the requirements of 40 CFR Section 60.112b (a)(2); or

(3) An alternative means of emission limitation as described in 40 CFR Section

60.114b.

If an owner or operator elects to comply with the provisions of this section, then the owner or operator is exempt from the provisions of 40 CFR Section 61.343 of this subpart applicable to the same facilities. 2.0

CD 40 CFR Section 61.351(a)(1); 40 CFR Section 63.640(o)(1); 40 CFR Section 63.647(a) Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 3.0

CD 40 CFR Section 61.351(a); 40 CFR Section 61.351(a)(1); 40 CFR Section 61.351(b); 40 CFR Section 61.356(k); 40 CFR Section 61.357(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Comply with requirements of GP 019 (NSPS, subp. Kb for External Floating Roof Tanks) 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 69 of 407

Subject Item: GP 054 Storage Tank Heaters built before June 11, 1973

Associated Items: EU 144 Tank 19 Heater - Process Heater

EU 145 Tank 39 Heater - Process Heater

EU 146 Tank 39 Heater - Process Heater

EU 157 Tank 411 Heater - Process Heater

EU 158 Tank 411 Heater - Process Heater

EU 159 Tank 412 Heater - Process Heater

EU 160 Tank 412 Heater - Process Heater

EU 163 Tank 414 Heater - Process Heater

EU 164 Tank 414 Heater - Process Heater

EU 165 Tank 415 Heater - Process Heater

EU 166 Tank 416 Heater - Process Heater

EU 167 Tank 416 Heater - Process Heater

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS (LIMITS APPLY TO EACH UNIT.) 1.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 2.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 3.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes complaince with this limit. 4.0

CD hdr OTHER LIMITS AND REQUIREMENTS 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn natural gas only. 6.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 70 of 407

Subject Item: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

Associated Items: EU 054 #6 HDS Reactor Charge Heater - Process Heater

EU 056 HDS Heater (hot oil system) - Process Heater

EU 057 Unisar Reactor Charge Heater - Process Heater

EU 058 #5 HDS Charge Heater (naphtha) - Process Heater

EU 059 #1 HDS Reactor Charge Heater - Process Heater

EU 060 #1 HDS Fractionation H eater - Fractionation Equipment

EU 061 #2 HDS Reactor Charge Heater - Process Heater

EU 076 Powerformer Regenerator Gas Heater - Process Heater

EU 240 H2 Plant Vaporizer Heater - Process Heater

EU 241 #1 H2 Plant Reformer/Heater - Process Heater

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS (LIMITS APPLY TO EACH UNIT.) 1.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1490, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction.

(most stringent limit, meets limit set by Minn. R. 7011.1405, subp. 2) 2.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 3.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 4.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 5.0

CD hdr OTHER LIMITS AND REQUIREMENTS 6.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 7.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 71 of 407

Subject Item: GP 056 Storage Tank Heaters built after June 11, 1973

Associated Items: EU 149 Asphalt Line Heater - Process Heater

EU 168 Tank 417 Heater - Process Heater

EU 169 Tank 418 Heater - Process Heater

EU 170 Tank 423 Heater - Process Heater

EU 171 Tank 423 Heater - Process Heater

EU 172 Tank 424 Heater - Process Heater

EU 173 Tank 424 Heater - Process Heater

EU 274 Asphalt tk Heater for tk 415 - Process Heater

EU 275 Asphalt tk Heater for tk 418 - Process Heater

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS (LIMITS APPLY TO EACH UNIT.) 1.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 2.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 3.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 4.0

CD hdr OTHER LIMITS AND REQUIREMENTS 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn natural gas only. 6.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 72 of 407

Subject Item: GP 057 Emission Units subject to Minn. R. built after June 11, 1973

Associated Items: EU 055 #2 HDS Fractionation Heater (31H2) - Fractionation Equipment

EU 093 Naphtha Hydrotreater Charge Heater - Process Heater

EU 094 Naphtha Hydotreater Stripper Reboiler - Boiler

EU 095 Platformer Charge Heater (Gr ouped with EU 095/096/097) - Process Heater

EU 096 Platformer #1 Interheater(Grouped with EU 095/096/097) - Process Heater

EU 097 Platformer #2 Interheater(Grouped with EU 095/096/097) - Process Heater

EU 098 Platformer Stabilizer Reboiler Heater - Process Heater

EU 099 Platformer Catalyst Regeneration Vent - Regenerator

EU 102 Unit 38 Gasoil HDS A-Train Heater - Process Heater

EU 103 Unit 38 Gasoil HDS B-Train Heater - Process Heater

EU 104 Unit 38 Gasoil HDS Fractionation Charge Heater - Process Heater

EU 209 Track 8 Rail Loading - Loading-Unloading Equipment

MR 186 HCL adsorber inlet temperature indicator (37TC1150A)

NC/

CA Type Citation Requirement

CD Minn. R. 7007.0800, subp. 2 EU055 is subject to GP057 conditions upon completion of the Merox Incinerator (EU245) shutdown project and EU055 resumes normal operation combusting the full Merox offgas stream. Prior to this, EU055 is subject to GP055 conditions. 1.0

CD hdr EMISSION LIMITS (LIMITS APPLY TO EACH UNIT.) 2.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1490, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction.

(most stringent limit, meets limit set by Minn. R. 7011.1410, subp. 3) 3.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 4.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 5.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 6.0

CD hdr OTHER LIMITS AND REQUIREMENTS 7.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 8.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 73 of 407

Subject Item: GP 058 Equipment subject to both NESH FF controls and NSPS QQQ

Associated Items: EU 178 OSWTP - API Oil/Water Separator Fore Bay (94B1A & 94B1B) - Separation Equipment

EU 278 OSWTP-API Oil/Water Separator Exit Bay (94B1A & 94B1B) - Separation Equipment

EU 279 OSWTP-API Oil/Water Separator Mi d Bay 94B1A & 94B1B - Separation Equipment

EU 283 94S-2A/D Slop Oil Sump at API Oil/Water Separator - Separation Equipment

EU 284 Phase Separator at Alt Wast e Handling Site - Separation Equipment

EU 315 Vac Trucks at FHR - Other Emission Unit

TK 063 Organic Liquid

TK 064 Organic Liquid @ 94 Unit

TK 205 Organic Liquid @ 94 Unit

TK 206 Organic Liquid @ 94 Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.690-60.699;

40 CFR Section 60.692-3(a)(4)-(5); 40 CFR Section 60.692-3(b); 40 CFR Section 60.692-3(c)(2); 40 CFR Section 60.692-3(d)-(e); 40 CFR Section 60.692-5(a); 40 CFR Section 63.640(o)(1) Subject to 40 CFR pt. 61, subps. A and FF requirements. Compliance with 40 CFR pt. 61, subp. FF and 40 CFR pt. 61, subp. A requirements as listed in this permit fully satisfies 40 CFR pt. 60, subps. A and QQQ, 40 CFR pt. 63, subps. A and CC requirements. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 74 of 407

Subject Item: GP 059 Containers subject to NESH FF; w/vac trucks to haul NESH FF waste

Associated Items: EU 284 Phase Separator at Alt Wast e Handling Site - Separation Equipment

EU 315 Vac Trucks at FHR - Other Emission Unit

EU 345 Desalter Brine API 94ME259A - Refining Equipment

EU 346 Desalter Brine API 94ME259B - Refining Equipment

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.345(a)(1); 40 CFR Section 61.345(a)(1)(ii); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) The owner or operator shall install, operate, and maintain a cover on each container used to handle, transfer, or store waste in accordance with the following requirements: each opening shall be maintained in a closed, sealed position (e.g., covered by a lid that is gasketed and latched) at all times that waste is in the container except when it is necessary to use the opening for waste loading, removal, inspection, or sampling. 2.0

CD 40 CFR Section 61.345(a)(2); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) When a waste is transferred into a container by pumping, the owner or operator shall perform the transfer using a submerged fill pipe. The submerged fill pipe outlet shall extend to within two fill pipe diameters of the bottom of the container while the container is being loaded. During loading of the waste, the cover shall remain in place and all openings shall be maintained in a closed, sealed position except for those openings required for the submerged fill pipe, those openings required for venting of the container to prevent physical damage or permanent deformation of the container or cover, and any openings complying with 40 CFR Section 60.345(a)(4) of this section. 3.0

CD 40 CFR Section 61.345(a)(3) Treatment of a waste in a container, including aeration, thermal or other treatment, must be performed by the owner or operator in a manner such that while the waste is being treated the container meets the standards specified in 40 CFR Section 61.345(a)(3)(i) through (iii) of this section, except for covers and closed-vent systems that meet the requirements in 40 CFR Section 61.345(a)(4) of this section. 4.0

CD 40 CFR Section 61.342(f); 40 CFR Section 61.342(f)(2); 40 CFR Section 61.355(k)(2)(iii); 40 CFR Section 61.356(c); Minn. R. 7011.9930(E) The owner or operator transferring the waste offsite to another facility where the

waste is treated shall:

(1) Comply with the NESHAP FF standards for each waste management unit that receives or manages the waste prior to shipment of the waste offsite.

(2) Include with each offsite waste shipment a notice stating that the waste contains benzene which is required to be managed and treated. 5.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 6.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 75 of 407

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 7.0

CD 40 CFR Section 61.350(a)-(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delayed Repairs: Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 8.0

CD 40 CFR Section 61.345(c); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: when a broken seal or gasket or other problem is identified, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days

after identification. 9.0

CD 40 CFR Section 61.354(a)(1)(i) The cover and all openings (e.g., bungs, hatches, and sampling ports) shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 10.0

CD 40 CFR 61.345(b); 40 CFR Section 61.356 (g) 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Quarterly Inspection: Each cover and all openings shall be visually inspected quarterly to ensure that they are closed and gasketed properly. 11.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 12.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 76 of 407

Subject Item: GP 060 Oil/water separators w/floating roof subject to NSPS QQQ and NESHAP FF

Associated Items: EU 279 OSWTP-API Oil/Water Separator Mi d Bay 94B1A & 94B1B - Separation Equipment

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 60.693-2(a)(1); 40 CFR Section 60.693-2(d); 40 CFR Section 61.352(a); 40 CFR Section 61.352(a)(1); 40 CFR Section 61.352(c); 40 CFR Section 61.356(l); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Oil-water separator must have external floating roof meeting the specifications:

Each floating roof shall be equipped with a closure device between the wall of the separator and the roof edge. The closure device is to consist of a primary seal and a secondary seal.

(i) The primary seal shall be a liquid-mounted seal or a mechanical shoe seal.

(A) A liquid-mounted seal means a foam- or liquid-filled seal mounted in contact with the liquid between the wall of the separator and the floating roof. A mechanical shoe seal means a metal sheet held vertically against the wall of the separator by springs or weighted levers and is connected by braces to the floating roof. A flexible coated fabric (envelope) spans the annular space between the metal sheet and the floating roof.

(B) The gap width between the primary seal and the separator wall shall not exceed 3.8 cm (1.5 in.) at any point. (continued below) 2.0

CD 40 CFR Section 60.693-2(a)(1); 40 CFR Section 60.693-2(d); 40 CFR Section 61.352(a); 40 CFR Section 61.352(a)(1); 40 CFR Section 61.352(c); 40 CFR Section 61.356(l); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) (continued from above) C) The total gap area between the primary seal and the separator wall shall not exceed 67 cm2/m (3.2 in.2/ft) of separator wall perimeter.

(ii) The secondary seal shall be above the primary seal and cover the annular space between the floating roof and the wall of the separator.

(A) The gap width between the secondary seal and the separator wall shall not exceed 1.3 cm (0.5 in.) at any point.

(B) The total gap area between the secondary seal and the separator wall shall not exceed 6.7 cm2/m (0.32 in.2/ft) of separator wall perimeter.

(iii) The maximum gap width and total gap area shall be determined by the methods and procedures specified in 40 CFR Section 60.696(d).

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0

CD 40 CFR Section 60.693-2(a)(1)(iv); 40 CFR Section 60.693-2(a)(5)(ii) Repair: The owner or operator shall make necessary repairs within 30 calendar days of identification of seals not meeting the requirements or roof openings not meeting requirements unless delay of repair provisions are invoked. 4.0

CD 40 CFR Section 60.693-2(a)(2) Each opening in the roof shall be equipped with a gasketed cover, seal, or lid, which shall be maintained in a closed position at all times, except during inspection

and maintenance. 5.0

CD 40 CFR Section 60.693-2(a)(3) The roof shall be floating on the liquid (i.e., off the roof supports) at all times except during abnormal conditions (i.e., low flow rate). 6.0

CD 40 CFR Section 60.693-2(a)(1)(iii)(A); 40 CFR Section 60.696(d)(1)(i)-(iii); 40 CFR Section 60.696(d)(2)(i); 40 CFR Section 60.696(d)(2)(ii) Monitor: Measurement of primary seal gaps shall be performed within 60 calendar days after initial installation of the floating roof and introduction of refinery wastewater and once every 5 years thereafter. 7.0

CD 40 CFR Section 60.693-2(a)(1)(iii)(B); 40 CFR Section 60.696(d)(1)(i)-(iii); 40 CFR Section 60.696(d)(2)(ii) Monitor: Measurement of secondary seal gaps shall be performed within 60 calendar days of initial introduction of refinery wastewater and once every year

thereafter. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 77 of 407

CD 40 CFR Section 60.696(d)(1); 40 CFR Section 60.696(d)(1)(i)-(ii) The maximum gap widths and maximum gap areas between the primary seal and the separator wall and between the secondary seal and the separator wall shall be determined individually within 60 calendar days of the initial installation of the floating roof and introduction of refinery wastewater or 60 calendar days after the equipment is placed back into service using the following procedure when the separator is filled to the design operating level and when the roof is floating off the roof supports.

(i) Measure seal gaps around the entire perimeter of the separator in each place where a 0.32 cm (0.125 in.) diameter uniform probe passes freely (without forcing or binding against seal) between the seal and the wall of the separator and measure the gap width and perimetrical distance of each such location. (continued below) 9.0

CD 40 CFR Section 60.696(d)(1); 40 CFR Section 60.696(d)(1)(i)-(ii) (continued from above) (ii) The total surface area of each gap shall be determined by using probes of various widths to measure accurately the actual distance from the wall to the seal and multiplying each such width by its respective perimetrical distance.

(iii) Add the gap surface area of each gap location for the primary seal and the secondary seal individually, divide the sum for each seal by the nominal perimeter of the separator basin and compare each to the maximum gap area as specified in

40 CFR Section 60.6932.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 10.0

CD 40 CFR Section 60.693-2(a)(4) The floating roof may be equipped with one or more emergency roof drains for removal of stormwater. Each emergency roof drain shall be fitted with a slotted membrane fabric cover that covers at least 90 percent of the drain opening area or

a flexible fabric sleeve seal. 11.0

CD 40 CFR Section 60.693-2(a)(5)(i) A ccess doors and other openings shall be visually inspected initially and semiannually thereafter to ensure that there is a tight fit around the edges and to identify other problems that could result in VOC emissions. 12.0

CD 40 CFR Section 61.350(a)-(b); 40

CFR Section 60.692-6 (a) Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 13.0

CD 40 CFR Section 61.356(l)(1) Records required for visual inspections: The date, location, and corrective action for each visual inspection during which there is not a tight fit or there is a broken seal or gasket on an access door or other opening or other problem is identified

that could result in benzene emissions. 14.0

CD 40 CFR Section 61.356(l)(2) Record secondary seal measurements, location, date and corrective actions, if any, annually. 15.0

CD 40 CFR Section 61.356(l)(2) Record primary seal measurements, location, date and corrective actions, if any, every 5 years. Maintain records for at least 10 years. 16.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 78 of 407

Subject Item: GP 062 Oil/water separators w/fixed roof subject to NSPS QQQ and NESH FF w/CVS & control device

Associated Items: EU 177 OSWTP - Trash Rack & Diversi on Box (94ME16A) - Refining Equipment

EU 178 OSWTP - API Oil/Water Separator Fore Bay (94B1A & 94B1B) - Separation Equipment

EU 278 OSWTP-API Oil/Water Separator Exit Bay (94B1A & 94B1B) - Separation Equipment

EU 283 94S-2A/D Slop Oil Sump at API Oil/Water Separator - Separation Equipment

EU 290 94V-25D Wemco D Cell - Refining Equipment

EU 291 94V-25E Wemco E Cell - Refining Equipment

EU 292 94V-25F Wemco F Cell - Refining Equipment

EU 345 Desalter Brine API 94ME259A - Refining Equipment

EU 346 Desalter Brine API 94ME259B - Refining Equipment

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.347(a)(1); 40 CFR Section 61.352 (b); 40 CFR Section 63.654(a); 40 CFR Sections 60.692-3(a), 60.692-3(b); Minn. R. 7011.9930(E) The owner or operator shall install, operate, and maintain a fixed-roof and closed-vent system that routes all organic vapors vented from the oil-water separator to a control device.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0

CD 40 CFR Section 61.347(a)(1)(i), 40 CFR Section 61.347(a)(1)(i)(A), 40 CFR Section 61.347(a)(1)(i)(B) Each opening shall be maintained in a closed, sealed position (e.g., covered by a lid that is gasketed and latched) at all times that waste is in the oil-water separator except when it is necessary to use the opening for waste sampling or removal, or for equipment inspection, maintenance, or repair. 3.0

CD 40 CFR Section 61.347(a)(1)(i)(A) The cover and all openings (e.g., access hatches, sampling ports, and gauge wells shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 4.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Monitoring shall comply with Method 21 from Appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 5.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 79 of 407

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 6.0

CD 40 CFR Section 61.350(a)-(b); 40 CFR Section 63.655(a); 40 CFR Section 60.692-6; Minn. R. 7011.9930(E) Delayed Repairs: Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 7.0

CD 40 CFR Section 61.347(c); 40 CFR Section 63.655(a); 40 CFR Section 60.692-3(a)(5); Minn. R. 7011.9930(E) Repairs: when a broken seal or gasket or other problem is identified, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days after identification unless qualifying for delay or repair. 8.0

CD 40 CFR Section 61.347(b); 40 CF R Section 61.356 (g) 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); 40 CFR Section 60.692-3(a)(4); Minn. R. 7011.9930(E) Quarterly Inspection: Each cover, seal and access hatch and all other openings shall be visually inspected quarterly to ensure that no cracks or gaps occur between the cover and oil-water separator wall and that access hatches and other openings are closed and gasketed properly. 9.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(c); 40 CF R Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. (continued below) 10.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(c); 40 CF R Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 11.0

CD 40 CFR Section 61.356(l); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Maintain records of the following: (1) The date, location, and corrective action for each visual inspection required by 40 CFR Section 60.693-2(a)(5), during which a broken seal, gap, or other problem

is identified that could result in benzene emissions. (2) Results of the seal gap measurements required by 40 CFR Section 60.693-2(a). 12.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 80 of 407

Subject Item: GP 065 Treatment Processes to meet destruction req. NESH FF

Associated Items: EU 182 OSWTP - Sludge Basin 2A - Refining Equipment

EU 183 OSWTP - Equalization Basin 2B - Refining Equipment

EU 184 OSWTP - Equalization Basin 2C - Refining Equipment

EU 185 OSWTP-Enhanced Biological Treatm ent Basin 94B3C - Refining Equipment

EU 186 OSWTP - DAF Tank (old) - Refining Equipment

EU 187 OSWTP - DAF Tank (new) - Refining Equipment

EU 188 OSWTP - DAF Rapid Mix Tank (old) - Mixing Equipment

EU 189 OSWTP - DAF Rapid Mix Tank (new) - Mixing Equipment

EU 190 OSWTP - DAF Floc T ank (old) - Refining Equipment

EU 191 OSWTP - DAF Floc T ank (new) - Refining Equipment

EU 200 OSWTP-Equalization Ba sin 7A - Refining Equipment

EU 201 OSWTP-Equalization Ba sin 7B - Refining Equipment

EU 280 OSWTP-Enhanced Biological Treatm ent Basin 94B3A - Refining Equipment

EU 281 OSWTP-Enhanced Biological Treatm ent Basin 94B3B - Refining Equipment

EU 289 Air Saturation Drum 94V22 - Separation Equipment

EU 293 Air Saturation Drum 94V5 - Separation Equipment

EU 327 OSWTP- Dissolved Nitr ogen Floatation Unit - Dissolver

EU 347 Equalization Basin 94V49 - Above Ground Storage Tank

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Maintain compliance with design, equipment, work practice, operational standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.348(a); 40 CFR Section 61.348(a)(5); 40 CFR Section 61.348(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Control benzene waste streams per 40 CFR pt. 61, subp. FF standards and install, operate and maintain a treatment process to remove or destroy benzene to less than 10 ppmw. 2.0

CD 40 CFR Section 61.348(a)(2) Each treatment process shall be designed and operated in accordance with the appropriate waste management standards. 3.0

CD 40 CFR Section 61.348(g); 40 CFR Section 61.355(a); 40 CFR Section 61.354(b)(2); 40 CFR Section 61.355(g); 40 CFR Section 61.356(b)(6); 40 CFR Section 61.356(i)(4); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The owner or operator of a treatment process or wastewater treatment system unit that is used to comply with the provisions of this section shall monitor the unit in accordance with the applicable requirements in 40 CFR Section 61.354. 4.0

CD 40 CFR Section 61.348(e); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A ll openings (e.g., access doors, hatches, etc) shall be sealed (e.g., gasketed, latched, etc.) and kept closed at all times when waste is being treated, except during inspection and maintenance.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 5.0

CD 40 CFR Section 61.348(e)(1) Conduct initial and quarterly visual inspections on each seal, access door, and all other openings to ensure that no cracks or gaps occur and that openings are closed and gasketed properly. 6.0

CD 40 CFR Section 61.348(a)(2) Monitoring: Each applicable potential leak point must be monitored using Method

21 on an annual basis. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 81 of 407

CD 40 CFR Section 61.345(c); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: when a broken seal or gasket or other problem is identified, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days

after identification. 8.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Annual monitoring shall comply with Method 21 from Appendix A of 40 CFR pt.
60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 9.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 10.0

CD 40 CFR Section 61.350(a)-(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delayed Repairs: Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 11.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. (continued below) 12.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 82 of 407

Subject Item: GP 067 All equipment included in individual drain system subject to NSPS QQQ or NESHAPs FF

Associated Items: EU 316 FHR Lab Inside - Other Emission Unit

EU 317 FHR Lab Outdoors - Other Emission Unit

FS 001 Unburied Sewer Lines subject to NESHAP FF or NSPS QQQ - Material Handling/Transfer/Storage

FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 83 of 407

Associated Items: FS 130 Carbon Canisters & Associated Piping - Process Emissions

FS 132 SVE Thermal Oxidizer(86 UNIT3 and 88 UNIT2) - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 60.692-2(a)(1); 40 CFR Section 60.692-2(a)(3); 40 CFR Section 60.692-2(a)(4); Minn. R. 7011.1435(C) Drains in active service subject to 40 CFR pt. 60, subp. QQQ shall be equipped with water seal/lube oil or equivalent controls. 40 CFR pt. 60, QQQ drains out of active service may be equipped with water seal/lube oil or equivalent controls, or be equipped with a tightly sealed cap or plug. A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0

CD 40 CFR Section 61.346(b)(1) 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Drains subject to 40 CFR pt. 61, subp. FF control shall be equipped with water/lube oil seal or equivalent controls or a tightly sealed cap or plug. A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0

CD 40 CFR Section 61.346; Minn. R. 7011.9930(E) For drains subject only to 40 CFR pt. 61, subp. FF control requirements, comply with GP 120 for water/lube oil seal or equivalent seal drains and GP 068 for capped/plugged drains. 4.0

CD 40 CFR Section 60.692-2; Minn. R

. 7011.1435(C) For drains subject only to 40 CFR pt. 60, subp. QQQ requirements, comply with GP 072 for water/lube oil seal or equivalent seal drains, GP 071 for capped/plugged drains that are used infrequently, and GP 075 for inactive capped/plugged drains. 5.0

CD 40 CFR Section 61.346; 40 CFR Section 60.692-2; Minn. R. 7011.9930(E); Minn. R. 7011.1435(C) For drains subject to both 40 CFR pt. 61, subp. FF and 40 CFR pt. 60, subp. QQQ control requirements, comply with GP 069 for water/lube oil seal or equivalent seal drains and GP 121 for capped/plugged drains. 6.0

CD 40 CFR Section 61.346; 40 CFR

Section 60.692-2; Minn. R. 7011.9930(E); Minn. R. 7011.1435(C) For unburied sewer lines subject to 40 CFR pt. 61, subp. FF or 40 CFR pt. 60, subp. QQQ, comply with FS 001. 7.0

CD 40 CFR Section 61.346; Minn. R. 7011.9930(E) For junction boxes subject to 40 CFR pt. 61, subp. FF control requirements, comply

with GP 076. 8.0

CD 40 CFR Section 60.692-2; Minn. R

. 7011.1435(C) For junction boxes subject to 40 CFR pt. 60, subp. QQQ requirements, comply with

GP 077. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 84 of 407

Subject Item: GP 068 Drains subject to NESH FF equipped with plugs

Associated Items: EU 316 FHR Lab Inside - Other Emission Unit

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

NC/

CA Type Citation RequirementMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 85 of 407

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.346(b)(4)(ii); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Quarterly NESHAP visual inspection: Each drain using tightly fitting cap or plug for control shall be checked by visual or physical inspection initially and quarterly to ensure caps or plugs are in place and properly installed. 2.0

CD 40 CFR Section 61.346(b)(5); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: when a broken seal or gasket or other problem is identified, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days

after identification. 3.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delayed Repairs: Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 4.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 5.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 86 of 407

Subject Item: GP 069 Drains subject to NESH FF and also subject to NSPS QQQ (water seal; lube oil or equivalent)

Associated Items: FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD CAAA of 1990; 40 CFR Section 61.346(b)(4); 40 CFR Section .692-2(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E); Minn. R. 7011.1435(C) Monthly inspection: Visually inspect water sealed/ lube oil or equivalent sealed drains in active service. Inspect monthly for indications of low liquid levels, cracks, gaps, or leaks that could result in VOC emissions or in lieu of inspection, add water/ lube oil or equivalent to the cup. EPA approval of alternate monitoring plan dated 4/29/04. (2001 EPA Consent Decree, as amended) 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 87 of 407

CD CAAA of 1990; 40 CFR Section 61.346(b)(4); 40 CFR Section 0.692-2(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E); Minn. R. 7011.1435(C) For drains with a water seal/ lube oil or equivalent seal at the junction box, flush liquid to the affected junction box via any listed drain cup to verify a water seal/ lube oil or equivalent seal. EPA approval of alternate monitoring plan dated 4/29/04. (2001 EPA Consent Decree, as amended) 3.0

CD 40 CFR Section 61.346(b)(5); 40 CFR Section 60.692-2; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: Whenever low liquid levels are identified, water, lube oil, or equivalent shall be added or first efforts at repair shall be made within 24 hours of detection unless qualifying for delay of repair. 4.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR 60.692-6; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delay of repair will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown. Repair shall occur before the end of the next refinery or process unit shutdown. 5.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(b)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 6.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 88 of 407

Subject Item: GP 071 Drains subject to NSPS QQQ (sealed w/plug)

Associated Items: FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.692-2(a)(4); Minn. R. 7011.1435(C) Each drain must be tightly capped when not in use. May use capped/plugged drains for 40 CFR pt. 60, subp, QQQ compliance if drains are used infrequently; otherwise water/lube oil or equivalent seal drains are required. (EPA ADI 0400030 & 0400031) 1.0

CD 40 CFR Section 60.692-2(a)(4); Minn. R. 7011.1435(C) Inspect: Conduct semi-annual visually inspection of capped or plugged drains. Inspect to ensure caps or plugs are in place and properly installed. 2.0

CD 40 CFR Section 60.692-6(a); 40 CFR Section 60.692-6(b); Minn. R. 7011.1435(C) Repair: Delay of repair of facilities that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown.

Repair of such equipment shall occur before the end of the next refinery or process

unit shutdown. 3.0

CD 40 CFR Section 60.692-2(a)(5); Minn. R. 7011.1435(C) Repairs: Whenever missing or improperly installed caps or plugs are identified, first efforts at repair shall be made as soon as practicable but not later than 24 hours after detection unless qualifying for delay of repair. 4.0

CD 40 CFR Section 60.697(b)(1); Minn. R. 7011.1435(C) Record: For individual drain systems, the location, date, and corrective action shall be recorded for each drain when a drain cap or plug is missing or improperly installed, or other problem is identified that could result in VOC emissions, as determined during the periodic visual or physical inspection. 5.0

CD 40 CFR Section 60.697(f)(1)-(2); 40 CFR Section 60.697(f)(2)(i)-(ii); Minn. R. 7011.1435(C) Record: A copy of the design specifications for all equipment shall be kept for the life of the source in a readily accessible location.

The following information pertaining to the design specifications shall be kept.

(i) Detailed schematics, and piping and instrumentation diagrams and

(ii) The dates and descriptions of any changes in the design specifications. 6.0

CD 40 CFR Section 60.697(e)(1)-(4) Recordkeeping: (1) If an emission point cannot be repaired or corrected without a process unit shutdown, the expected date of a successful repair shall be recorded.

(2) The reason for the delay shall be recorded if an emission point or equipment problem is not repaired or corrected in the specified amount of time;

(3) The signature of the owner or operator (or designee) whose decision it was that repair could not be effected without refinery or process shutdown shall be recorded.

(4) The date of successful repair or corrective action shall be recorded. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 89 of 407

Subject Item: GP 072 Drains subject to NSPS QQQ active (water seal, lube oil or equivalent)

Associated Items: FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.692-2(a)(2); 40 CFR Section 60.692-2(a)(5); Minn. R. 7011.1435(C) For drains with a water seal/lube oil or equivalent seal at the junction box, flush liquid to the affected junction box via any listed drain cup to verify a water seal/lube oil or equivalent seal. (EPA Approval of Alternate Monitoring Plan dated 4/29/2004). 1.0

CD 40 CFR Section 60.692-2(a)(2); Minn. R. 7011.1435(C); Alternative Monitoring Plan for individual drains systems and junction boxes approved by EPA Region V (George T. Czerniak) 4/29/04 Monthly Inspections: Visually inspect water sealed/lube oil or equivalent sealed drains in active service. Inspect monthly for indications of low liquid levels, cracks, gaps, or leaks that could result in VOC emissions or in lieu of inspection, add water/lube oil or equivalent to the cup. (EPA Approval of Alternate Monitoring Plan dated 4/29/2004). 2.0

CD 40 CFR Section 60.692-6(a); 40 CFR Section 60.692-6(b); Minn. R. 7011.1435(C) Repair: Delay of repair of facilities that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown.

Repair of such equipment shall occur before the end of the next refinery or process

unit shutdown. 3.0

CD 40 CFR Section 60.692-2(a)(5); Minn. R. 7011.1435(C) Repairs: Whenever low liquid levels are identified, liquid shall be added or first efforts at repair shall be made as soon as practicable, but not later than 24 hours

after detection. 4.0

CD 40 CFR Section 60.697(b)(1); Minn. R. 7011.1435(C) Records: For individual drain systems; the location, date, and corrective action shall be recorded for each drain when the water seal/lube oil or equivalent seal is dry or otherwise breached, when a drain cap or plug is missing or improperly installed, or other problem is identified that could result in VOC emissions, as determined during the initial and periodic visual or physical inspection. 5.0

CD 40 CFR Section 60.697(f)(1)-(2); 40 CFR Section 60.697(f)(2)(i)-(ii); Minn. R. 7011.1435(C) Record: (1) A copy of the design specifications for all equipment used to comply with the provisions of this subpart shall be kept for the life of the source in a readily

accessible location.

(2) The following information pertaining to the design specifications shall be kept.

(i) Detailed schematics, and piping and instrumentation diagrams.

(ii) The dates and descriptions of any changes in the design specifications. 6.0

CD 40 CFR Section 60.692-2(a)(1) In lieu of using water to seal the water sealed drains referenced in GP 072, clean (new) lube oil may be utilized for repair to ensure an emission seal remains in place. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 90 of 407

Subject Item: GP 075 Drains subject to NSPS QQQ inactive (equipped with plugs water seal or equivalent)

Associated Items: FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.692-2(a)(2)- (a)(4); Minn. R. 7011.1435(C) Inspect: Each drain out of active service shall be checked by visual or physical inspection initially and weekly thereafter for indications of low water levels or other problems that could result in VOC emissions. In lieu of inspection, add water/ lube oil or equivalent to the cup. Or alternatively, install a tightly sealed cap or plug over a drain that is out of active service and conduct inspections initially and semiannually to ensure caps or plugs are in place and properly installed. (EPA

A pproval of Alternate Monitoring Plan dated 4/29/2004). 1.0

CD 40 CFR Section 60.692-2(a)(2); 40 CFR Section 60.692-2(a)(5); Minn. R. 7011.1435(C) For drains with a water seal/ lube oil or equivalent seal at the junction box, flush liquid to the affected junction box via any listed drain cup to verify a water seal/ lube oil or equivalent seal. (EPA Approval of Alternate Monitoring Plan dated 4/29/2004). 2.0

CD 40 CFR Section 60.692-6(a); 40 CFR Section 60.692-6(b); Minn. R. 7011.1435(C) Repair: Delay of repair of facilities that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown.

Repair of such equipment shall occur before the end of the next refinery or process

unit shutdown. 3.0

CD 40 CFR Section 60.697(f)(1)-(2); 40 CFR Section 60.697(f)(2)(i)-(ii); Minn. R. 7011.1435(C) Record: (1) A copy of the design specifications for all equipment used to comply with the provisions of this subpart shall be kept for the life of the source in a readily

accessible location.

(2) The following information pertaining to the design specifications shall be kept.

(i) Detailed schematics, and piping and instrumentation diagrams.

(ii) The dates and descriptions of any changes in the design specifications. 4.0

CD 40 CFR Section 60.697(b)(1); Minn. R. 7011.1435(C) Record: For individual drain systems, the location, date, and corrective action shall be recorded for each drain when a drain cap or plug is missing or improperly installed, or other problem is identified that could result in VOC emissions, as determined during the periodic visual or physical inspection. 5.0

CD 40 CFR Section 60.692-2(a)(5); Minn. R. 7011.1435(C) Repair: Whenever low liquid levels or missing or improperly installed caps or plugs are identified, water, lube oil or equivalent shall be added or first efforts at repair shall be made as soon as practicable, but not later than 24 hours after detection, unless qualifying for delay of repair. 6.0

CD 40 CFR Section 60.697(g); Minn. R. 7011.1435(C) If an owner or operator elects to install a tightly sealed cap or plug over a drain that is out of active service, the owner or operator shall keep for the life of a facility in a readily accessible location, plans or specifications which indicate the location of

such drains. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 91 of 407

Subject Item: GP 076 Junction Boxes subject to NESH FF when equipped with carbon canisters

Associated Items: EU 317 FHR Lab Outdoors - Other Emission Unit

FS 018 11-1 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.346(a)(1)(i); 40 CFR Section 61.346(a)(1)(i)(B); 40 CFR Section 63.655(a); Minn. R. 7011.9930, subp. E A ll equipment that contains waste subject to NESHAP FF standards must maintain openings (e.g. hatches, covers, lids, etc.) in a closed, sealed position.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0

CD 40 CFR Section 61.346(a)(1); 40 CFR Section 61.346(a)(1)(i); 40 CFR Section 63.655(a); 40 CFR Section 61.346(b)(2); Minn. R. 7011.9930(E) Install, operate and maintain a cover and closed vent system that routes all organic vapors vented from the waste management until to a control device or junction box vent pipe meets requirements in 40 CFR Section 61.346(b)(2).

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 92 of 407

CD 40 CFR Section 61.346(a)(1)(i); 40 CFR Section 61.349(a)(1)(i); 40

CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) The cover and all openings (e.g., access hatches, sampling ports) shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv above background, initially and annual by Method

21.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 4.0

CD 40 CFR Section 61.346(a)(1)(i)&(i)(A); 40 CFR Section 61.355(h); 40 CFR Section 61.355 (h)(1)-(4); 40 CFR Section 61.355(h)(4)(i)-(ii); 40 CFR Section 61.355(h)(5)-(7); 40 CFR Section61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 5.0

CD 40 CFR Section 61.346(a)(1); 40 CFR Section 61.355(h); 40 CFR Section 61.355 (h)(1)-(4); 40 CFR Section 61.355(h)(4)(i)-(ii); 40 CFR Section 61.355(h)(5)-(7); 40 CFR Section61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) (4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 6.0

CD 40 CFR Section 61.346(a)(2); 40 CFR Section 61.346(b)(4)(iii); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Quarterly NESHAP visual inspection: Each cover seal, access hatch and all other openings shall be checked by visual inspection initially and quarterly to ensure that no cracks or gaps occur and that access hatches and other openings are closed and gasketed properly. For junction boxes complying with 40 CFR Section 61.346(b), each junction box shall be visually inspected initially and quarterly to ensure that the cover is in place and ensure that the cover has a tight seal around the edge. 7.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delayed Repairs: Delay of repair of facilities or units that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 8.0

CD 40 CFR Section 61.346(a)(3); 40 CFR Section 61.346(b)(5); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: when a broken seal or gasket or other problem is identified, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days

after identification. 9.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(d); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Records: An owner or operator shall maintain a record for each visual inspection that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. (continued below) 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 93 of 407

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(d); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) Records: An owner or operator shall maintain a record for each test of no detectable emissions. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 94 of 407

Subject Item: GP 077 Junction Boxes receiving Wastewater from NSPS QQQ Units not subject to NESHAPs FF

Associated Items: FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.692-2(b)(2); Minn. R. 7011.1435(C) Junction box covers shall have a tight seal around the edge and shall be kept in place at all times, except during inspection and maintenance. 1.0

CD 40 CFR Section 60.692-2(b)(1); Minn. R. 7011.1435(C) Junction boxes shall be equipped with a cover and may have an open vent pipe. The vent pipe shall be at least 90 cm (3 ft) in length and shall not exceed 10.2 cm (4 in) in diameter. 2.0

CD 40 CFR Section 60.692-2(b)(3); Minn. R. 7011.1435(C) Junction boxes shall be visually inspected initially and semiannually thereafter to ensure that the cover is in place and to ensure that the cover has a tight seal around the edge. 3.0

CD 40 CFR Section 60.692-6(a); 40 CFR Section 60.692-6(b); Minn. R. 7011.1435(C) Delayed Repairs: Delay of repair of facilities that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown.

Repair of such equipment shall occur before the end of the next refinery or process

unit shutdown. 4.0

CD 40 CFR Section 60.692-2(b)(4); Minn. R. 7011.1435(C) Repair junction boxes: If a broken seal or gap is identified, first effort at repair shall be made as soon as practicable, but not later than 15 calendar days after the broken seal or gap is identified unless qualifying for delay of repair. 5.0

CD Minn. R. 7011.1435(C) Record information from drain inspections. 6.0

CD 40 CFR Section 60.697(b)(2); Minn. R. 7011.1435(C) Record: For junction boxes; the location, date, and corrective action shall be recorded for inspections when a broken seal, gap, or other problem is identified

that could result in VOC emissions. 7.0

CD 40 CFR Section 60.697(f)(1)-(2); 40 CFR Section 60.697(f)(2)(i)-(ii); Minn. R. 7011.1435(C) Recordkeeping: (1) A copy of the design specifications for all equipment used to comply with the provisions of this subpart shall be kept for the life of the source in a readily accessible location.

(2) The following information pertaining to the design specifications shall be kept.

(i) Detailed schematics, and piping and instrumentation diagrams.

(ii) The dates and descriptions of any changes in the design specifications.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 8.0

CD 40 CFR Section 60.697(e)(1)-(4); Minn. R. 7011.1435(C) Recordkeeping: (1) If an emission point cannot be repaired or corrected without a process unit shutdown, the expected date of a successful repair shall be recorded.

(2) The reason for the delay shall be recorded if an emission point or equipment problem is not repaired or corrected in the specified amount of time;

(3) The signature of the owner or operator (or designee) whose decision it was that repair could not be effected without refinery or process shutdown shall be recorded.

(4) The date of successful repair or corrective action shall be recorded.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 95 of 407

Subject Item: GP 079 Non-contact Cooling Water Systems

Associated Items: EU 319 Non Contact Cooling Water Systems - Cooler

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.697(j); Minn. R. 7011.1435(C) Record: For non-contact cooling water systems subject to the exclusion, an owner or operator shall keep for the life of the facility in a readily accessible location, plans or specifications which demonstrate that the cooling water does not contact hydrocarbons or oily wastewater and is not recirculated through a cooling tower. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 96 of 407

Subject Item: GP 080 Stormwater Sewers

Associated Items: EU 320 Storm Sewers - Other Emission Unit

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.697(h); Minn. R. 7011.1435(C) Record: For stormwater sewer systems subject to the exclusion in 40 CFR Section 60.692-1(d)(1), an owner or operator shall keep for the life of the facility in a readily accessible location, plans or specifications which demonstrate that ancillary equipment does not come in contact with or store oily wastewater. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 97 of 407

Subject Item: GP 081 Fugitive Compressors Exempt from LDAR Requirements

Associated Items: FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593a(b)(1); Minn. R. 7007.0800, subp. 2 Compressors in hydrogen service are exempt from LDAR monitoring and repair requirements, if an owner or operator demonstrates that a compressor is in hydrogen service. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593a(b)(2); Minn. R. 7007.0800, subp. 2 When an owner or operator and the Administrator do not agree on whether a piece of equipment is in hydrogen service, the procedures in paragraph 40 CFR Section 60.593a(b)(2) shall be used to resolve the disagreement. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC; 40 CFR Section 60.593a(b)(2); Minn. R. 7007.0800, subp. 2 Each compressor is presumed not to be in hydrogen service unless an owner or operator demonstrates that the piece of equipment is in hydrogen service. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593a(b)(2); Minn. R. 7007.0800, subp. 2 For a piece of equipment to be considered in hydrogen service, it must be determined that the percentage hydrogen content can be reasonably expected always to exceed 50 percent by volume. 4.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593a(b)(2); Minn. R. 7007.0800, subp. 2 For purposes of determining the percentage hydrogen content in the process fluid that is contained in or contacts a compressor, the owner or operator shall use either procedures that conform to those specified in 40 CFR Section 60.593a(b)(2) or engineering judgment provided the engineering judgment demonstrates that the content clearly exceeds 50 percent by volume. 5.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 98 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593a(b)(2); Minn. R. 7007.0800, subp. 2 Components that are integral to the compressor, are considered part of the compressor, and thus exempt from LDAR monitoring and repair requirements if the compressor is in hydrogen service. 6.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-3a(j); Minn. R. 7007.0800, subp. 2 A ny existing reciprocating compressors are exempt from seal requirements, which is, paragraphs (a) through (e) and (h) of 40 CFR Section 60.482-3a. Provided the owner or operator demonstrates that recasting the distance piece or replacing the compressor are the only options available to bring the compressor into compliance. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 99 of 407

Subject Item: GP 082 Fugitive Compressors LDAR Requirements

Associated Items: FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 128 88-Butane - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Each compressor that is not exempt from LDAR requirements in GP 081, Fugitive Compressors Exempt from LDAR Requirements must meet the requirements in GP 090, Fugitive LDAR Equipment Designated Non-detectable. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-9a(a); Minn. R. 7007.0800, subp. 2 If leak repair requires the shutdown of a compressor and no permanent spare is available, then criteria for partial unit shutdown is met, and delay of repair is

allowed. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.487a(c)(2)(v);

Minn. R. 7007.0800 Include in the semi-annual LDAR Report: Number of compressors for which leaks

were detected. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.487a(c)(2)(vi); Minn. R. 7007.0800, subp. 2 Include in the semi-annual LDAR Report: Number of compressors for which leaks were not repaired within 15 calendar days or put on the delay of repair list. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 100 of 407

Subject Item: GP 087 Fugitive LDAR All Equipment in VOC or HAP Service

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 101 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J, and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Regulated equipment in VOC or organic HAP service (>10 wt% VOC per 40 CFR Section 60.481a or >5 wt% organic HAPs listed in Table 1 of 40 CFR pt. 63, subp. CC) must comply with the leak detection and repair (LDAR) provisions of this permit. Compliance with these provisions constitutes full and complete compliance with otherwise applicable requirements of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J, and V; 40 CFR pt. 63, subps. A and CC; the LDAR provisions of the 2001 Consent Order (U.S. v. Koch Petroleum Group, Court file No. 00-CCU-2756, U.S. Dist of MN); Clean Fuels Permit 106A-92-I/O-32; and

related Minnesota rules. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.481a; Minn. R. 7007.0800, subp. 2 LDAR programs shall be implemented refinery-wide, including all components within all contiguous areas that are owned and maintained by the refinery. As referenced in this Section, "components" shall mean applicable regulated equipment as defined in 40 CFR pt. 60, subp. GGGa, and 40 CFR pt. 63, subp. CC, except that components located outside of process unit boundaries shall not be excluded from applicability by using the definition of "process unit". 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 The owner or operator shall have the option of monitoring all components within a process unit within 30 days after the startup of the process unit after the turnaround without having the results of the monitoring used in the leak rate determination. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.483-1a; 40 CFR Section 60.483-2a; Minn. R. 7007.0800, subp. 2 The owner or operator shall calculate percent leaking valves on a process unit by process unit basis. This rate is used to determine monitoring frequency for units utilizing skip monitoring frequencies.

Storage tanks are considered separate process units under the consolidated LDAR program implemented consistent with the Consent Decree, the Clean Fuels permit, and state/federal regulations. The leak rates for components in these groups are calculated separately and are not included in the leak rates calculated for other process units. 4.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Sections 60.482-2a(c); 60.482-3a(g); 60.482-7a(d); 60.482-8a(c); 60.482-10a(g); 60.482-11a(d); Minn. R. 7007.0800, subp. 2 When a leak is detected, repair as soon as practicable. Make first attempt at repair no later than 5 days after the leak is detected. Make final repair and monitoring as soon as practical but no later than 15 calendar days after it is detected unless delay of repair provisions are invoked. First attempts at repair include, but are not limited to, the best practices described under 40 CFR Section 60.482-7a(e). 5.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 102 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC; 40 CFR Section 60.482-9a; Minn. R. 7007.0800, subp. 2 Delay of repair allowed. Repair must typically be completed before the end of the next process unit shutdown and the following criteria must be met: Delay of repair of equipment will be allowed for equipment which is isolated from the process and which does not remain in VOC service. Delay of repair beyond a process unit shutdown will be allowed for a valve, if valve assembly replacement is necessary during the process unit shutdown, valve assembly supplies have been depleted, and valve assembly supplies had been sufficiently stocked before the supplies were depleted. Delay of repair beyond the next process unit shutdown will not be allowed unless the next process unit shutdown occurs sooner than 6 months after the first process unit shutdown. 6.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(b); Minn. R. 7007.0800, subp. 2 Tag leaking equipment. (1) A weatherproof and readily visible identification, marked with the equipment identification number, shall be attached to the leaking equipment. (2) The identification on non-valve equipment may be removed after it has been repaired. The identification on a valve may be removed after it has been monitored for 2 successive months as specified in 40 CFR Section 60.482-7a(c) and no leak has been detected during those 2 months. 7.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(c); Minn. R. 7007.0800, subp. 2 Record date, tag number, and leak data when a leak is detected. When each leak is detected as specified in 40 CFR Section 60.482-2a, 40 CFR Section 60.482-3a, 40 CFR Section 60.482-7a, 40 CFR Section 60.482-8a, 40 CFR Section 60.482-11a, 40 CFR Section 60.483-2a, the following information shall be recorded in a log and shall be kept for 2 years in a readily accessible location: (1) The instrument and operator identification numbers and the equipment identification number, except when indications of liquids dripping from a pump are designated as a leak. (2) The date the leak was detected and the dates of each attempt to repair the leak. (3) Repair methods applied in each attempt to repair the leak. (4) Maximum instrument reading measured by Method 21 of appendix A-7 of this part at the time the leak is successfully repaired or determined to be nonrepairable, except when a pump is repaired by eliminating indications of liquids dripping. (continued below) 8.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(c); Minn. R. 7007.0800, subp. 2 (continued from above) (5) "Repair delayed" and the reason for the delay if a leak is not repaired within 15 calendar days after discovery of the leak. (6) The signature of the owner or operator (or designate) whose decision it was that repair could not be effected without a process shutdown. (7) The expected date of successful repair of the leak if a leak is not repaired within 15 days. (8) Dates of process shutdowns that occur while the equipment is unrepaired. (9) The date of successful repair of the leak.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 9.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(e); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR equipment. The owner or operator shall demonstrate that a piece of equipment is in light liquid service by showing that all the following conditions apply: (1) The vapor pressure of one or more of the organic components is greater than 0.3 kPa at 20 Celsius, Standard reference texts or ASTM D-2879 (incorporated by reference -- see 40 CFR Section 60.17) shall be used to determine the vapor

pressures. (2) The total concentration of the pure organic components having a vapor pressure greater than 0.3 kPa at 20 Celsius is equal to or greater than 20 percent by weight. (3) The fluid is a liquid at operating conditions. 10.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(e)(4); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR equipment. Include (1) the dates of each required initial compliance test as required in 40 CFR Section 60.482-2a(e), 40 CFR Section 60.482-3a(i), 40 CFR Section 60.482-4a, and 40 CFR Section 60.482-7a(f); (2) The background level measured during each compliance test; and (3) The maximum instrument reading measured at the equipment during each compliance test. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 103 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.487a; Minn. R. 7007.0800, subp. 2 Report: Provide a listing of those units that became subject to more frequent monitoring for valves during the reporting interval. 12.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.487a(c); Minn. R. 7007.0800, subp. 2 Submit semi-annual LDAR Report to the Administrator beginning six months after the initial startup date and due 30 days after reporting period thereafter. All semi-annual reports to the Administrator shall include the following information,

summarized from the information in 40 CFR Section 60.486a: (1) Process unit identification. (2) For each month during the semi-annual reporting period: (i) Number of valves for which leaks were detected as described in 40 CFR Section 60.482-7a(b) or 40 CFR Section 60.483-2a; (ii) Number of valves for which leaks were not repaired as required in 40 CFR Section 60.482-7a(d)(1); (iii) Number of pumps for which leaks were detected as described in 40 CFR Sections 60.482-2a(b), (d)(4)(ii)(A) or (B), or (d)(5)(iii) (iv) Number of pumps for which leaks were not repaired as required in 40 CFR Section 60.482-2a(c)(1) and 40 CFR Section 60.482-2a(d)(6); (v) Number of compressors for which leaks were detected as described in 40 CFR Section 60.482-3a(f); 13.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.487a(c); Minn. R. 7007.0800, subp. 2 (continued from above) (vi) Number of compressors for which leaks were not repaired as required in 40 CFR Section 60.482-3a(g)(1); and (ix) The facts that explain each delay of repair and, where appropriate, why a process unit shutdown was technically infeasible.

(3) Dates of process unit shutdowns which occurred within the semi-annual reporting period. (4) Revisions to items reported in the initial report.

A lso include frequency of monitoring for process units utilizing skip period monitoring. Include the results of all performance tests in accordance with 40 CFR Section 60.8 of the General Provisions. The provisions of 40 CFR Section 60.8(d) do not apply to affected facilities subject to the provisions of this subpart except that an owner or operator must notify the Administrator of the schedule for the initial performance tests at least 30 days before the initial performance tests. 14.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.481a; 40 CFR Section 60.482-1a(g); 40 CFR Section 60.591a; Minn. R. 7007.0800, subp. 2 Storage tanks are considered separate process units under the consolidated LDAR program implemented consistent with the Consent Decree, the Clean Fuels permit, and state/federal regulations. Any storage tank system components must either be included in these FSs or others as referenced in 40 CFR Section 60.482-1a(g). 15.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-9a(a); Minn. R. 7007.0800, subp. 2 Monitoring to verify repair on delay-of-repair equipment must occur within 15 days after startup of the process unit. 16.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(b); Minn. R. 7007.0800, subp. 2 Use calibration gases and follow test methods and procedures as referenced in 40 CFR Section 60.458a(b) 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 104 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Sections 60.486a(a)(3); 60.486a(c); 60.486a(e)(8); 60.486a(c)(4); 60.486a(e)(7); 60.486a(e)(10); Minn. R. 7007.0800, subp. 2 Comply with recordkeeping requirements for equipment calibrations and monitoring events as referenced in 40 CFR Section 60.486a(a)(3) (i.e. instrument, equipment, operator, date, and reading), 40 CFR Section 60.486a(c) (i.e. equipment, operator, date of leak and repair, repair method, max reading, reason for delay, signature, date of repair and unit shutdown), 40 CFR Section 60.486(e)(7) (i.e. weekly visual pump inspection) , 40 CFR Section 60.486a(e)(10) (i.e. releases from PSVs), and 40 CFR Section 60.486(e)(8) (i.e. instrument calibrations)

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 105 of 407

Subject Item: GP 088 Fugitive LDAR in Vacuum Service

Associated Items: FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 048 25-Crude Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(e)(5); Minn. R. 7007.0800, subp. 2 A list of identification numbers for equipment in vacuum service shall be recorded in a log or database that is kept in a readily accessible location. 1.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 106 of 407

Subject Item: GP 089 Fugitive LDAR Emission Sources not in VOC or HAP Service

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(i)(3); Minn. R. 7007.0800, subp. 2 Information and data used to demonstrate that a piece of equipment is not in VOC service shall be recorded in a log or database that is kept in a readily accessible

location. 1.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 107 of 407

Subject Item: GP 090 Fugitive LDAR Equipment Designated Non-detectable emissions (NDE)

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 108 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a(e); 40 CFR Section 60.482-3a(i); 40 CFR Section 60.482-7a(f); Minn. R. 7007.0800, subp. 2 If an instrument reading of 500 ppm or greater is measured, a leak is detected. If a leak is detected, then follow the repair requirements in GP 087. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a(e); Minn. R. 7007.0800, subp. 2 Pumps designated for no detectable emissions must meet specifications: Any pump that is designated for no detectable emission is exempt from barrier system requirements if the pump: (1) Has no externally actuated shaft penetrating the pump housing. (2) Is demonstrated to be operating with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background as measured by

Method 21.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-3a(i); Minn. R. 7007.0800, subp. 2 Compressors designated for no detectable emissions must meet specifications. The compressor must be demonstrated to be operating with no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, as measured by Method 21.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(f); Minn. R. 7007.0800, subp. 2 Valves designated for no detectable emissions must meet specifications: The valve

must: (1) Have no external actuating mechanism in contact with the process fluid. (2) Be operated with emissions less than 500 ppm above background as determined by Method 21.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 109 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(c); Minn. R. 7007.0800, subp. 2 Measure for detectable emissions using Method 21. Test for compliance with 40 CFR Section 60.482-7a(f)(2) initially upon designation, annually, and at other times requested by the Administrator. The owner or operator shall determine compliance with the no detectable emission standards in 40 CFR Section 60.482-2a(e), 40 CFR Section 60.482-3a(i), 40 CFR Section 60.482-4a, 40 CFR Section 60.482-7a(f), and 40 CFR Section 60.482-10a(e) as follows: (1) The requirements of 40 CFR Section 60.482-7a(b) shall apply. (2) Method 21 shall be used to determine the background level. All potential leak interfaces shall be traversed as close to the interface as possible. The arithmetic difference between the maximum concentration indicates by the instrument and the background level is compared with 500 ppm for determining compliance. 5.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a(e); 40 CFR Section 60.482-3a(i); 40 CFR Section 60.482-7a(f); Minn. R. 7007.0800, subp. 2 Measure for detectable emissions upon Administrator's request. 6.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(e)(2); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR equipment in light liquid service. Include a list of identification numbers for equipment that are designated for no

detectable emissions. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 110 of 407

Subject Item: GP 091 Fugitive LDAR Open-ended Lines

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 111 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; 40 CFR Section 60.593a(f); Minn. R. 7007.0800, subp. 2 With the exception of asphalt lines, open-ended lines must be sealed by a cap, blind flange, plug or second valve at all times except during operations requiring flow through the line. Open-ended valves or lines containing materials which would autocatalytically polymerize or would present an explosion, serious overpressure, or other safety hazard if capped or equipped with a double block and bleed system as specified in paragraphs (a) through (c) of this section are exempt from the requirements of paragraphs (a) through (c) of this section. (a)(1) Each open-ended valve or line shall be equipped with a cap, blind flange, plug, or a second valve, except as provided in 40 CFR Section 60.482-1a(c), 40 CFR Section 60.482-6a(d), and 40 CFR Section 60.482-6a(e)

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by permit. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; Minn. R. 7007.0800, subp. 2 (2) The cap, blind flange, or second valve shall seal the open end at all times except during operations requiring fluid flow through the open-ended valve or line. (b) Each open-ended valve or line equipped with a second valve shall be operated in a manner such that the valve on the process fluid end is closed before the second valve is closed. (c) When a double block-and-bleed system is being used, the bleed valve or line may remain open during operations that require venting the line between the block valves but shall comply with paragraph (a) of this section at

all other times.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by permit. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 A leak is detected if an open-ended line is found and not immediately repaired. If a leak is detected, then follow the repair requirements in GP 087.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by permit. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CGR Section 60.593a(f); Minn. R. 7007.0800, subp. 2 FHR's consolidated LDAR program establishes a compliance plan which sets 5- and 15-day repair deadlines for open-ended lines and allows delay of repair for any open-ended lines that would otherwise require significant process changes or a

shutdown to fix. 4.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 112 of 407

NC CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; Minn. R. 7007.0800, subp. 2 Replace or correct remaining open-ended lines in the 23 coker identified in the January 6, 2006, correspondence from FHR to MPCA to ensure compliance with 40 CFR Section 60.482-6a by the end of the next turnaround involving replacement of the #3 coke drums, anticipated to occur in Fall 2013. 5.0

CA CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; Minn. R. 7007.0800, subp. 2 Replace or correct remaining open-ended lines in the 23 coker identified in the January 6, 2006, correspondence from FHR to MPCA to ensure compliance with 40 CFR Section 60.482-6a by the end of the next turnaround involving replacement of the #3 coke drums, anticipated to occur in Fall 2013. 5.1MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 113 of 407

Subject Item: GP 093 Fugitive LDAR PSV to Atmosphere in Gas/Vapor Service

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 114 of 407

Associated Items: FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-4a(b); Minn. R. 7007.0800, subp. 2 A fter each pressure release, the pressure relief device shall be returned to a condition of no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, as soon as practicable, but no later than 5 calendar days after the pressure release, except as provided in 40 CFR Section 60.482-9a. No later than 5 calendar days after the pressure release, the pressure

relief device shall be monitored to confirm the conditions of no detectable emissions, as indicated by an instrument reading of less than 500 ppm above background, using Method 21 per the requirements stated in GP 090. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(e)(4); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR pressure relief devices. Include a list of equipment identification numbers for pressure relief devices subject to LDAR provisions. 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 115 of 407

Subject Item: GP 094 Fugitive LDAR PSV with Upstream Rupture Disks

Associated Items: FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-4a(d)(2); Minn. R. 7007.0800, subp. 2 Per 40 CFR Section 60.482-4a(d)(2) after each pressure release, a new rupture disk shall be installed upstream of the pressure relief device as soon as practicable, but no later than 5 calendar days after each pressure release, except as provided in 40 CFR Section 60.482-9a. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 116 of 407

Subject Item: GP 095 Fugitive LDAR Pumps In Heavy Liquid Service

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 117 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 If an instrument reading of 1,000 ppm or greater is measured, a leak is detected. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-8a(a); Minn. R. 7007.0800, subp. 2 If evidence of a potential leak is found by visual, audible, olfactory, or any other detection method at pumps, valves, and connectors in heavy liquid service and pressure relief devices in light liquid or heavy liquid service, the owner or operator shall follow either one of the following procedures:

(1) The owner or operator shall monitor the equipment within 5 days by the method specified in 40 CFR Section 60.485a(b) and shall comply with the requirements of paragraphs (b) through (d) of this section.

(2) The owner or operator shall eliminate the visual, audible, olfactory, or other indication of a potential leak within 5 calendar days of detection. 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 118 of 407

Subject Item: GP 096 Fugitive LDAR Light Liquid Pumps

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 119 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a; Minn. R. 7007.0800, subp. 2 Monitor pumps for leaks using Method 21. If an instrument reading of 1000 ppm or greater is measured, a leak is detected. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a(b)(2); Minn. R. 7007.0800, subp. 2 Weekly visually inspect pumps for indications of liquids dripping from the pump seal. If there are indications of liquids dripping from the pump seal, either: (i) Monitor the pump within 5 days using Method 21 to determine whether a leak is
detected, or

(ii) Designate the visual indications of liquids dripping as a leak, and repair the leak using either the procedures in 40 CFR Section 60.482-2a(c) or by eliminating the visual indications of liquids dripping. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Reciprocating pumps in light liquid service are exempt from LDAR monitoring and repair requirements if recasting the distance piece or replacing the reciprocating pump is required to meet the standards. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(f); 40 CFR Section 60.482-2a(g)(2); Minn. R. 7007.0800, subp. 2 Monitor unsafe-to-monitor pumps per the written inspection plan. No plan is required if no components are on the unsafe-to-monitor list. Plan must require monitoring of the pump as frequently as practicable during safe-to-monitor times but not more frequently than the periodic monitoring schedule otherwise applicable, and repair of the pump if a leak is detected. 4.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-9a(d); Minn. R. 7007.0800, subp. 2 Delay of repair allowed. Repair must typically be completed before the end of the next process unit shutdown and the following criteria must be met:

(1) Repair requires the use of dual mechanical seal system that includes a barrier fluid system, and

(2) Repair is completed as soon as practicable, but not later than 6 months after the

leak was detected. 5.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 120 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-2a(a)(1); Minn. R. 7007.0800, subp. 2 A pump that begins operation in light liquid service after the initial startup date for the process unit must be monitored for the first time within 30 days after the end of its startup period, except for a pump that replaces a leaking pump. 6.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 121 of 407

Subject Item: GP 099 Fugitive LDAR Sample Stations

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 122 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-5a; Minn. R. 7007.0800, subp. 2 Sampling systems, as defined in 40 CFR Section 60.481a, except in situ sampling systems and sampling systems without purges, in VOC or HAP service shall be equipped with a closed-purged, closed-loop, or a closed-vent system. Each closed-purge, closed-loop, or closed-vent system shall comply with one of the following requirements: (1) Gases displaced during filling of the sample container are not required to be collected or captured. (2) Containers that are part of a closed-purge system must be covered or closed when not being filled or emptied. (3) Gases remaining in the tubing or piping between the closed-purge system valve(s) and sample container valve(s) after the valves are closed and the sample container is disconnected are not required to be collected or captured. (4) Each closed-purge, closed-loop, or closed-vent system shall be designed and operated to: (continued below) 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-5a; Minn. R. 7007.0800, subp. 2 (continued from above) (i) Return the purged process fluid directly to the process line. (ii) Collect and recycle the purged process fluid to a process. (iii) Capture and transport all the purged process fluid to a control device that complies with the requirements of 40 CFR Section 60.482-10a. (iv) Collect, store, and transport the purged process fluid to any of the following systems or facilities: (A) A waste management unit as defined in 40 CFR Section 63.111, if the waste management unit is subject to and operated in compliance with the provisions of 40 CFR pt. 63, subpart G, applicable to Group 1 wastewater streams; (continued below) 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-5a; Minn. R. 7007.0800, subp. 2 (continued from above) (B) A treatment, storage, or disposal facility subject to regulation under 40 CFR pts.
262, 264, 265, or 266; (C) A facility permitted, licensed, or registered by a state to manage municipal or industrial solid waste, if the process fluids are not hazardous waste as defined in 40 CFR part 261; (D) A waste management unit subject to and operated in compliance with the treatment requirements of 40 CFR Section 61.348(a), provided all waste management units that collect, store, or transport the purged process fluid to the treatment unit are subject to and operated in compliance with the management requirements of 40 CFR Sections 61.343 through 40 CFR 61.347; or (E) A device used to burn off-specification used oil for energy recovery in accordance with 40 CFR pt. 279, subp. G, provided the purged process fluid is not hazardous waste as defined in 40 CFR pt. 261. 3.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 123 of 407

Subject Item: GP 100 Fugitive LDAR Heavy Liquid Valves and PSVs (in LL/HL Service)

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 124 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-8a(a); Minn. R. 7007.0800, subp. 2 If evidence of a potential leak is found by visual, audible, olfactory, or any other detection method at pumps, valves, and connectors in heavy liquid service and pressure relief devices in light liquid or heavy liquid service, the owner or operator shall follow either one of the following procedures:

(1) The owner or operator shall monitor the equipment within 5 days by the method specified in 40 CFR Section 60.485a(b) and if an instrument reading of 500 ppm or greater is measured, a leak is detected. If a leak is detected, then follow the repair requirements in GP087

(2) The owner or operator shall eliminate the visual, audible, olfactory, or other indication of a potential leak within 5 calendar days of detection. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 125 of 407

Subject Item: GP 101 Fugitive LDAR Valves in Light Liquid Service

Associated Items: FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 102 47 H2 Recovery Gas - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 126 of 407

Associated Items: FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 137 RGP Transfer - Process Emissions

FS 138 RGP Loading Rack - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(b); Minn. R. 7007.0800, subp. 2 If an instrument reading of 500 ppm or greater is measured, a leak is detected. If a leak is detected, then follow the repair requirements in GP 087. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units that have less than 2 percent leaking valves for 2 consecutive months, owner or operator shall monitor each valve once every calendar quarter, beginning with the next quarter. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units that have less than or equal to 1 percent leaking valves for 2 consecutive quarters, owner or operator may elect to monitor each valve once every 2 calendar quarters. 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units that have less than or equal to 0.5 percent leaking valves for 3 consecutive calendar semi-annual periods, owner or operator may elect to monitor each valve once every 4 calendar quarters. 4.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units on a calendar quarterly, semiannual, or annual monitoring schedule that have greater than or equal to 2 percent leaking valves in any single detection period, the owner or operator shall monitor each valve no less than every month, but can once again elect to advance to less frequent monitoring pursuant to the schedule above. 5.0MINNESOTA POLLUTION CONTROL AGENCY

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 127 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units on a calendar semi-annual or annual monitoring schedule that have greater than or equal to 1 percent but less than 2 percent leaking valves in any single detection period, the owner or operator shall monitor each valve no less than every calendar quarter, but can again elect to advance to less frequent monitoring pursuant to the schedule above. 6.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on the Consent Decree, various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Sustainable skip period monitoring: At process units on a calendar annual monitoring schedule that have greater than or equal to 0.5 percent but less than 1 percent leaking valves in any single detection period, the owner or operator shall monitor each valve no less than semi-annually, but can again elect to advance to less frequent monitoring pursuant to the schedule above. 7.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(h); Minn. R. 7007.0800, subp. 2 Monitor difficult-to-monitor valves once per calendar year using Method 21. A valve may be designated as difficult-to-monitor if the owner or operator of the valve demonstrates that the valve cannot be monitored without elevating the monitoring personnel more than 2 meters above a support surface. 8.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(f)(2); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR difficult-to-monitor valves. Document the following information: A list of identification numbers for valves that are designated as difficult-to-monitor, an explanation for each valve stating why the

valve is difficult-to-monitor. 9.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(g); Minn. R. 7007.0800, subp. 2 Monitor unsafe-to-monitor valves per the written inspection plan. No plan is required if no components are on the unsafe-to-monitor list. Any valve that is designated, as described in 40 CFR Section 60.486a(f)(1) as an unsafe-to-monitor valve is exempt from routine monitoring requirements if: (1) The owner or operator of the valve demonstrates that the valve is unsafe to monitor because monitoring personnel would be exposed to an immediate danger as a consequence of routine monitoring and (2) The owner or operator of the valve adheres to a written plan that requires monitoring of the valve as frequently as practicable during safe-to-monitor times, if

any. 10.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.486a(f)(1); Minn. R. 7007.0800, subp. 2 Document applicability determination for all LDAR difficult-to-monitor and unsafe-to monitor valves. Document the following information: A list of identification numbers for valves that are designated as unsafe-to-monitor, and explanation for each valve stating why the valve is unsafe-to-monitor, and the plan for monitoring each valve. 11.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC) 40 CFR Section 60.487a; Minn. R. 7007.0800, subp. 2 Report: Provide a listing of those units that became subject to more frequent monitoring for valves during the reporting interval. 12.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 128 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 The owner or operator shall designate each process unit as either quarterly monitoring or part of the sustainable skip program. It is allowed to switch between quarterly monitoring and the sustainable skip period program provided that process units monitored in the skip period alternative method may not revert to quarterly monitoring if the most recent monitoring period demonstrates that more than 2% of the valves found leaking under the internal leak definition. Pursuant to 40 CFR Section 60.488(d), the Administrator shall be notified of the switch in monitoring frequency option 90 days prior to implementing the provision.

Quarterly monitoring must be followed unit-wide if selected, and must continue unless the sustainable skip monitoring is selected and implemented for that unit. Quarterly frequency does not take into account valve leak rate. 13.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(h); Minn. R. 7007.0800, subp. 2 The percent of valves leaking shall be determined using the following equation:

%VL= (VL/ VT) * 100

Where:

%VL= Percent leaking valves.

VL= Number of valves found leaking.

VT= The sum of the total number of valves monitored.

(2) The total number of valves monitored shall include difficult-to-monitor and unsafe-to-monitor valves only during the monitoring period in which those valves

are monitored.

(3) The number of valves leaking shall include valves for which repair has been delayed. (continued below) 14.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.485a(h); Minn. R. 7007.0800, subp. 2 (continued from above) (4) Any new valve that is not monitored within 30 days of being placed in service shall be included in the number of valves leaking and the total number of valves monitored for the monitoring period in which the valve is placed in service.

(5) If the process unit has been subdivided in accordance with 40 CFR Section 60.482-7a(c)(1)(ii), the sum of valves found leaking during a monitoring period includes all subgroups.

(6) The total number of valves monitored does not include a valve monitored to verify repair. 15.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Valves on the delay of repair list that are determined to be leaking greater than 50,000 ppmv will undertake one heroic repair attempt (i.e. drill and tap, wire wrap, etc.) within 45-days of detection unless there is a safety or environmental concern posed by repairing the leak in this matter. 16.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Valves on the delay of repair list shall continue to be monitored in the same frequency as the process unit. If a leak reaches 50,000 ppm, and cannot be reduced to less than 50,000 ppm, one heroic repair attempt (i.e. drill and tap, wire wrap, etc.) will be attempted within 45-days unless there is a safety or environmental concern posed by repairing the leak in this matter. 17.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 If valve is on the delay of repair list for longer than 36 months, then one heroic repair (i.e. drill and tap, wire wrap. etc.) will be attempted unless there is a safety or environmental concern posed by repairing the leak in this matter. 18.0MINNESOTA POLLUTION CONTROL AGENCY

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 129 of 407

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 If a valve underwent a legitimate repair attempt during a process unit shutdown, and if the repair attempt is unsuccessful and continues to leak after the startup of the process unit, then the leak is considered a new leak with regards to the repair

timeline. 19.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 If evidence of a potential leak is found by visual, audible, olfactory, or any other detection method at pumps, valves, and connectors in heavy liquid service and pressure relief devices in light liquid or heavy liquid service, the owner or operator shall follow either one of the following procedures: (1) The owner or operator shall monitor the equipment within 5 days by the method specified in 40 CFR Section 60.485a(b) and if an instrument reading of 500 ppm or greater is measured, a leak is detected. If a leak is detected, then follow the repair requirements in GP 087. (2) The owner or operator shall eliminate the visual, audible, olfactory, or other indication of a potential leak within 5 calendar days of detection. 20.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(a)(2); Minn. R. 7007.0800, subp. 2 A valve (not replacing a leaking valve) that begins operation in gas/vapor service or light liquid service after the initial startup date for the process unit must be monitored according to paragraphs (a)(2)(i) or (ii). (i) The valve must be monitored for the first time within 30 days after the end of its startup period to ensure proper installation. (ii) If the existing valves in the process unit are monitored in accordance with 40 CFR Section 60.483-1a or 40 CFR Section 60.483-2a, count the new valve as leaking when calculating the percentage of valves leaking as described in 40 CFR Section 60.483-2a(b)(5). If less than 2.0 percent of the valves are leaking for that process unit, the valve must be monitored for the first time during the next scheduled monitoring event for existing valves in the process unit or within 90 days,

whichever comes first. 21.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-7a(c); Minn. R. 7007.0800, subp. 2 A ny valve for which a leak is not detected for 2 successive months may be monitored quarterly, beginning with the next calendar quarter (consistent with the unit monitoring schedule), until a leak is detected. 22.0MINNESOTA POLLUTION CONTROL AGENCY

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 130 of 407

Subject Item: GP 102 Units where carbon canisters may be used to meet NESHAP FF Requirements

Associated Items: FS 001 Unburied Sewer Lines subject to NESHAP FF or NSPS QQQ - Material Handling/Transfer/Storage

FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 008 Top Loading and UC Top Loading - Ma terial Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 052 26-Sulfur Recovery Unit SRU 5, TGTU 2 - Process Emissions

FS 054 27-Distillate Hydrotreater - Process Emissions

FS 055 27- Hydrogen Plant No. 2 - Process Emissions

FS 056 27-5 Hydrogen Plant No. 3 - Process Emissions

FS 058 28-Naphtha Hydrotreater - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 079 37 Naptha Hydro-Desulfurizer - Process Emissions

FS 080 37 Platformer - Process Emissions

FS 083 38 High Pressure Gas/Oil Hydrotreater - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process EmissionsMINNESOTA POLLUTION CONTROL AGENCY

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Associated Items: FS 102 47 H2 Recovery Gas - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 106 71 Process Steam Boilers - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 117 All Tankage (including li ne pumps) 52Unit 2; 61Unit2, 86Unit2 &102Unit2 - Process Equipment

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 128 88-Butane - Process Emissions

FS 130 Carbon Canisters & Associated Piping - Process Emissions

FS 132 SVE Thermal Oxidizer(86 UNIT3 and 88 UNIT2) - Process Emissions

FS 133 Hydrocracker Feed Equipment - Process Emissions

FS 134 No. 4 Hydrogen Plant Fugiti ve Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR 61.346(a)(1)(i); 40 CFR Section 61.346(a)(1)(i)(B); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The owner or operator shall install, operate, and maintain on each drain system opening a cover and closed-vent system that routes all organic vapors vented from the drain system to a control device. Each opening shall be maintained in a closed, sealed position (e.g., covered by a lid that is gasketed and latched) at all times that waste is in the drain system except when it is necessary to use the opening for waste sampling or removal, or for equipment inspection, maintenance, or repair.

A depature from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.349(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Control device and closed vent system must be operated at all times when waste is in the waste management unit vented to the control device except when maintenance or repair of the waste management unit cannot be completed without a shutdown of the control device or during maintenance/change out of the carbon

canisters. 2.0

CD 40 CFR Section 61.349(a)(2); 40 CFR Section 61.349(a)(2)(ii); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Carbon canister control device system shall recover or control the organic emissions vented to it with an efficiency of 95 weight percent or greater, or shall recover or control the benzene emissions vented to it with an efficiency of 98 weight percent or greater. 3.0

CD 40 CFR Section 61.12(c); Minn. R.

7011.9900 A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, review of operating and maintenance procedures and inspection of the source. 4.0

CD 40 CFR Section 61.346(a)(1)(i); 40 CFR 61.349(a)(1)(i); 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Closed vent system and control device shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 5.0

CD CAAA of 1990; Minn. R. 7007.0800, subp. 2; 40 CFR Section 61.349(h); 40 CFR Section 61.354(d); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Measure VOC or benzene concentration at outlet of 1st carbon canister in carbon adsorption system when the source is connected to the carbon canister, and during periods of normal operation in accordance with the frequency specified in 40 CFR Section 61.354(d). (2001 EPA Consent Decree as amended) 6.0

CD CAAA of 1990; 40 CFR Section 61.354(d); Minn. R. 7007.0800, subp. 2 Compliance demo: Replace existing primary carbon container with fresh carbon container within 24 hours for a 2-canister system when carbon breakthrough is detected. (2001 EPA Consent Decree as amended) 7.0MINNESOTA POLLUTION CONTROL AGENCY

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Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 132 of 407

CD CAAA of 1990; Minn. R. 7007.0800, subp. 2 Install primary and secondary carbon canisters and operate them in series. (2001 EPA Consent Decree as amended) 8.0

CD CAAA of 1990; 40 CFR Section 61.354(d); Minn. R. 7007.0800, subp. 2 Breakthrough shall be defined as a condition where the outlet of the primary canister is >100 ppmv VOC or >20 ppmv benzene, and the primary canister is providing a reduction of < 95% VOC or < 98% benzene. (2001 EPA Consent Decree as amended) 9.0

CD 40 CFR Section 61.356(j)(10) Record date of carbon containers change-outs. 10.0

CD CAAA of 1990; Minn. R. 7007.0800, subp. 2 If using PID for Method 21 measurement, then follow manufacturer calibration procedures. (2001 EPA Consent Decree as amended) 11.0

CD 40 CFR Section 61.346(a)(2); 40 CFR Section 61.349(f); 40 CFR Section 61.357(d)(8); 40 CFR 63.655(a); Minn. R. 7011.9930(E) Conduct initial and quarterly visually inspections of the closed vent system and control devices. The visual inspection shall include inspection of ductwork and piping and connections to covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. 12.0

CD Minn. R. 7007.0800, subp. 2 For conservation vents located on closed vent systems in FHR's WWTP, follow the

A lternative Monitoring Plan pursuant to EPA correspondence dated 1/1/2005 which requires quarterly visual inspection and semi-annual Method 21 NDE monitoring of these components. If a defect or leak is identified, follow the repair requirements listed in this group (GP 102). (EPA ADI Z050006) 13.0

CD 40 CFR Section 61.349(g); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repair defects or other problems found during visual inspections or detectable emissions identified via Method 21 NDE monitoring. A first effort to repair must be made within 5 calendar days and final repair shall be completed within 15 calendar days of the initial inspection date unless qualifying for delay of repair 14.0

CD 40 CFR Section 61.356; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Per 40 CFR Section 61.356, maintain required records for NESHAP, Subpart FF equipment. 15.0

CD 40 CFR Section 61.349(a)(1)(ii)(B) Car seal or lock and key any bypass line that could divert stream away from carbon canister except during maintenance of carbon canister system or other safety

reason. 16.0

CD 40 CFR Section 61.349(c) Demonstrate that each control device achieves the appropriate conditions specified in paragraph 40 CFR Section 61.349(a)(2)(ii) by using engineering calculations in accordance with requirements specified in 40 CFR Section 61.356(f) 17.0

CD 40 CFR Section 61.354(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Owners or operators using a closed-vent system that contains any bypass line that could divert a vent stream from a control device shall do the following: (1) Visually inspect the bypass line valve at least once every month, checking the position of the valve and the condition of the car-seal or closure mechanism required under 40 CFR Section 61.349(a)(1)(ii) to ensure that the valve is maintained in the closed position and the vent stream is not diverted through the bypass line. 18.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. (continued below) 19.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 20.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 133 of 407

Subject Item: GP 104 Refinery Emergency Flares and Flare System (for Consent Decree Flare Policy)

Associated Items: CE 022 Flaring

CE 023 Flaring

CE 024 Flaring

CE 025 Flaring

EU 301 84ME23 E. Flare - zControl

EU 302 84ME24 W. Flare - zControl

EU 303 84ME27 U. Flare - zControl

EU 304 84ME3 N. Flare - zControl

NC/

CA Type Citation Requirement

LIMIT 40 CFR Section 60.11(c); 40 CFR Section 60.18(c); 40 CFR Section 60.482-10a(d); 40 CFR Section 60.485a(g); 40 CFR Section 60.692-5(c); 40 CFR Section 61.349(a)(2)(iii) & (d); 40 CFR Section 63.11(b)(4); Minn. R. 7011.7280; Minn. R. 7011.9930(E) Opacity: less than or equal to 0 percent opacity from flares except a total 5 minutes in any 2 consecutive hours; limit does not apply during the periods of startup, shutdown, or malfunction. 1.0

CD 40 CFR Section 60.18; 40 CFR Section 60.482-10a(d); 40 CFR Section 60.485a(g); 40 CFR Section 60.692-5(c); 40 CFR Section 61.349(a)(2)(iii); 40 CFR Section 61.349(d); Minn. R. 7011.9930(E) Operation Limit: Flares must meet maximum velocity and minimum heat content requirements. 2.0

CD 40 CFR Section 61.349(b); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Control device and closed vent system: shall be operated at all times when waste is placed in the waste management unit vented to the control device except when maintenance or repair of the waste management unit cannot be completed without

a shutdown of the control device. 3.0

CD 40 CFR Section 60.18(c)(3); 40 CFR Section 60.692-5(c); 40 CFR Section 63.11(b)(2); Minn. R.

7011.7280 A ll flares must be steam-assisted, air-assisted, or non-assisted. 4.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; TItle I Condition: 40 CFR pt. 52, subp. Y Hydrocarbon Flare Systems: The refinery flare system and associated controls, which include flare gas recovery compressors, shall be designed, maintained, and operated in accordance with a refinery flare policy for the control of refinery gases from unplanned and infrequent events (i.e., malfunctions) in a safe manner and to ensure that gases resulting from refinery operations, including gases from scheduled startups and shutdowns of refinery process units, shall not be flared except during unplanned and infrequent events. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; TItle I Condition: 40 CFR pt. 52, subp. Y The associated items of GP 104 may not receive gases from Refinery operations unless the gases are from pressure relief, are from upsets of Refinery process equipment, or are required for equipment maintenance which includes startup and shutdown. Compliance with this requirement is shown by complying with the Hydrocarbon Flare Systems requirement above. 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; TItle I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: The Permittee shall use only commercial natural gas or nitrogen for purge system and commercial natural gas at the pilot flame in all flares. 7.0

CD 40 CFR Section 60.18; 40 CFR Section 60.482-10a(d); 40 CFR Section 60.485a(g); 40 CFR Section 60.692-5(c); 40 CFR Section 61.12(a); 40 CFR Section 61.349(a)(2)(iii); 40 CFR Section 61.354(c)(3); 40 CFR Section 63.11(b)(3) &(5); Minn. R.

7011.7280 Flares shall be operated with pilot flame present at all times when emissions may

be vented to them. 8.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 134 of 407

CD CAAA of 1990; Minn. R. 7007.0800, subp. 2; 40 CFR Section 60.105(a)(4); Minn. R. 7011.1435(A) Operate the flare system in conformance with the Flare Policy. Operation of the flare system in conformance with the Flare Policy constitutes good air pollution control practices pursuant to 40 CFR Section 60.11(d) and ensures that Hydrocarbon Flaring is not subject to the emission limitation monitoring, or other requirements for refinery fuel gas found in 40 CFR Sections 60.100-60.109. (2001 EPA Consent Decree as amended) 9.0

CD 40 CFR Section 61.13 Conduct performance test if requested by Administrator per section 114 of the Clean Air Act, as amended. 10.0

CD 40 CFR Section 60.482-10a(d); 40 CFR Section 60.485a(g); 40 CFR Section 60.692-5(c); 40 CFR Section 63.11; 40 CFR 60.18(f);
Minn. R. 7011.7280; Minn. R. 7017.1010, subp. 1(A) to 7017.1010, subp. 1(C) Monitor existence of flare pilot flame with thermocouple or equivalent device to detect the presence of a flame. 11.0

CD 40 CFR Section 61.346(a)(1)(i); 40 CFR 61.349(a)(1)(i); 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Closed vent system and control device shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 12.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 13.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) (4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 14.0

CD 40 CFR Section 61.349(f); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930, subp. E; 40 CFR Section 61.356(h); 40 CFR Section 3.655(a); Minn. R. 7011.9930(E); 40 CFR Section 60.482-10a (f)(1)(ii), (g), (g)(1), (g)(2), (k)(5) Each closed-vent system and control device shall be visually inspected initially and quarterly. The visual inspection shall include inspection of ductwork and piping and

connections to covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 135 of 407

CD 40 CFR Section 61.356(j); 40 CFR Section 61.356(j)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930, subp. E For each control device, maintain documentation that includes the following information regarding the control device operation:

(1) Dates of startup and shutdown of the closed-vent system and control device;

(2) A description of the operating parameter (or parameters) to be monitored to ensure that the control device will be operated in conformance with these standards and the control device's design specifications and an explanation of the criteria used for selection of that parameter (or parameters). This documentation shall be kept for the life of the control device; and

(3) Periods when the closed-vent system and control device are not operated as designed including all periods and the duration when:

A ny valve car-seal or closure mechanism is broken or the by-pass line valve position has changed and The flow monitoring devices indicate that vapors are not routed to the control device as required. 16.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (a) Delay of repair of facilities or units will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 17.0

CD 40 CFR Section 61.349(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) If visible defects are observed during an inspection, or if other problems are identified, or if detectable emissions are measured, a first effort to repair the closed-vent system and control device shall be made as soon as practicable but no later than 5 calendar days after detection. Repair shall be completed no later than 15 calendar days after the emissions are detected or the visible defect is observed. 18.0

CD 40 CFR Section 61.13(g); 40 CFR Section 61.356; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Retain at the source and make available, upon request, for inspection by the

A dministrator, for a minimum of 2 years, records of emission test results and other

data needed to determine emissions. 19.0

CD 40 CFR Section 61.349(h); 40 CFR Section 61.354(c); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The owner or operator of a control device that is used to comply with the provisions

of this section shall monitor the control device in accordance with 40 CFR Section 61.354(c). 20.0

CD 40 CFR Section 60.18(c)(1); 40 CFR Section 60.18(c)(2); 40 CFR Section 60.4(a); 40 CFR Section 60.4(b)(Y); 40 CFR Section 60.952-5(c); Minn. R. 7007.0500, subp. 3 Submit Quarterly Air Quality and Excess Emissions Report. Cover letter, certification, and summary of exceedances shall be submitted in hardcopy or electronic format; all other information may be submitted electronically. 21.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Section 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. (continued below) 22.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 23.0

CD 40 CFR Section 61.356(i)(7); Minn. R. 7011.9930(E) Maintain continuous records of the flare pilot flame monitoring and records of all periods during which the pilot flame is absent. 24.0

CD 40 CFR Section 60.103a(a)(1) through (7) & (b)(1) through (3) Maintain and implement a written flare management plan that includes the information in 40 CFR Section 60.103a(a)(1) through (a) (7) by November 11, 2015.

Plan must be submitted to the Administrator and EPA. 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 136 of 407

CD 40 CFR Section 60.103a(c)(1) through (3) Conduct a root cause analysis and corrective action analysis for the conditions given in 40 CFR Section 60.103a(1) through (3) after November 11, 2015 for this
part. 26.0

CD 40 CFR Section 60.103a(e)(1) through (3) Implement corrective actions identified within the timeframes given after November
11, 2015. 27.0

CD 40 CFR Section 60.107a(e)(1) through (3) Determine the total reduced sulfur concentration of flare gas for applicable flares by one of the methods provided by November 11, 2015. 28.0

CD 40 CFR Section 60.107a(f)(1) through (2) Install, operate, calibrate and maintain a CPMS to measure and record the flow rate of gas discharged to the flare by November 11, 2015. 29.0

CD 40 CFR Section 60.107a(g)(1) through (7) Flares that can be classified as emergency, secondary, or are equipped with flare gas recovery to capture all flows except those resulting from startup, shutdown or malfunction, (less than five reportable events in any 365 consecutive calendar days) may use the alternative methods to sulfur and flow monitoring requirements by November 11, 2015. 30.0

CD 40 CFR Section 60.108a(c) Maintain Records and report as given per the relevant flare requirements of 40 CFR Section 60.108a(c) after November 11, 2015 31.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 137 of 407

Subject Item: GP 106 Control Equipment Used to Meet Requirements of MACT CC

Associated Items: CE 002 Flaring

CE 003 Activated Carbon Adsorption

CE 048 Other (Flare Gas Recovery Sys)

CE 050 Flaring

EU 055 #2 HDS Fractionation Heater (31H2) - Fractionation Equipment

MR 189 Temperature Indicator for 101H1

NC/

CA Type Citation Requirement

CD Minn. R. 7007.0800, subp. 2 EU 055 is subject to GP106 conditions upon completion of the Merox Incinerator (EU 245) shutdown project and EU 055 resumes normal operation combusting the full Merox offgas stream. Prior to this, EU 055 is subject to GP 055 conditions. CE 013 will be subject to GP 106 conditions up until completion of the Merox Incinerator (EU 245) shutdown project and normal operation of EU055 combusting the full Merox offgas stream. Afterward CE 013 will no longer be subject to GP1 06

conditions. 1.0

CD 40 CFR Section 63.7(a)(3); 40 CFR Section 63.7(d); 40 CFR Section 63.7(e)(1); 40 CFR Section 63.7(e)(2); 40 CFR Section 63.7(e)(4); Minn. R.
7011.7280; Minn. R. 7017.2015, subp. 3(A) Conduct performance test if requested by Administrator per section 114 of the Clean Air Act, as amended. 2.0

CD 40 CFR Section 63.6(f)(1); 40 CFR Section 63.644(e); Minn. R.

7011.7280 Operate vapor processing system in a manner not to exceed operating parameter

value. 3.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii); Minn.

R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan (SSMP). 4.0

CD 40 CFR pt. 63, subp. CC. Table 6; 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv);

Minn. R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or of malfunction or maintenance of air pollution control equipment. Document

conformance with or deviation from SSMP. 5.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date SSMP. 6.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 138 of 407

Subject Item: GP 111 Fuel Gas Supply Systems

Associated Items: EU 256 Fuel Gas Supply System (41 unit) Monitori ng Point for FG H2S and sulfur - Refining Equipment

EU 263 Fuel Gas Supply System (45 unit) Monitori ng Point for FG H2S and sulfur - Refining Equipment

MR 075 41V33 Fuel Gas Mix Drum H2S

MR 076 41V-33 Fuel Gas Mix Drum Refinery Flow Meter

MR 080 45V-39 Fuel Gas Mix Drum H2S

MR 088 45V-39 Fuel Gas Mix Drum Flow Meter

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Hydrogen Sulfide: less than or equal to 90 parts per million using 365-day Rolling

A verage by volume in refinery fuel gas measured at the 41 Unit refinery gas mix drum and at the 45 Unit refinery gas mix drum. Existing continuous monitoring systems and best engineering judgment shall be used to estimate hydrogen sulfide concentration to quantify emissions for purposes of compliance with the fuel gas concentration limits. (Limit for SO2) 2.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. Limit applies to each system. 3.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 ppm). This is a state-only requirement and, pursuant to Minn. R. 7007.1750, it is not enforceable by the EPA administrator or citizens under the Clean Air Act. Limit applies to each system. 4.0

CD hdr RECORDKEEPING REQUIREMENTS (APPLIES TO 41 Unit and 45 Unit) 5.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping of Fuel Gas Flow Rate for SO2 limit: The Permittee shall record the hourly average fuel gas flow rate. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 6.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall record and maintain the hourly, daily, and 365-day rolling average H2S concentration at the 41 Unit refinery fuel gas mix drum and at the 45 Unit refinery fuel gas mix drum. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 7.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping of the High Heating Value (HHV) for SO2 limit: The Permittee shall calculate and record daily the average HHV in BTU/SCF per mix drum. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA requirements as required by 2000 Global Consent Decree. 9.0

CD hdr CEMS REQUIREMENTS FOR H2S 10.0

CD 40 CFR pt. 60, subps. J & Ja;
Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 H2S CEMS Emissions Monitoring: The Permittee shall install, operate and use a hydrogen sulfide (H2S) CEMS to measure H2S emissions from the 41 Unit refinery fuel gas mix drum and the 45 Unit refinery fuel gas mix drum. 11.0

CD 40 CFR Section 60.105(a)(4); 40 CFR Section 60.107a(a)(2); Minn.

R. 7017.1006 H2S Content in Refinery Gas: The Permittee shall calibrate, operate and maintain a CEMS to determine the H2S content of the refinery gas. The CEMS shall provide a continuous record of H2S in ppm. 12.0

CD Minn. R. 7017.1160, subps 1,2 &3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 13.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 139 of 407

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 15.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 16.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 17.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 18.0

CD Minn. R. 7017.1180, subp. 1 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail, or

hand-delivered document. 19.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each quarter following CEMS Relative Accuracy Test Audit (RATA) 20.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 21.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 22.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 23.0

CD hdr CMS REQUIREMENT 24.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain CMS that record

the fuel flowrate for each fuel combustion devices with flowmeters. 25.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 26.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 140 of 407

Subject Item: GP 112 Sulfur Recovery Units

Associated Items: EU 045 #5 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 111 #3 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 112 #4 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

MR 036 TGTU2 SO2 Analyzer - 26H21

MR 037 TGTU2 O2 Analyzer - 26H21

MR 082 45H-6 SO2

MR 084 TGTU1 SO2 Analyzer - 45H61

MR 114 TGTU2 CO Analyzer

MR 139 45 CO ppm

SV 042 #5 SRU 26 Unit Stack

SV 093 45H61 Stack

SV 094 45H6 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than or equal to 428 tons/year using 365-day Rolling Sum . Emissions from acid gas flaring incidents are not included in the calculations of emissions against the caps.

Effective 10/2/04 and for the first 365 days after this date, SO2 emissions in tons/year are limited as determined by the following equation: E = 428[0.15 + 0.85(D/365)]

where

E = SO2 emissions in total tons since 10/2/04 D = number of days since 10/2/04 2.0

LIMIT Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 608 tons/year using 365-day Rolling Sum . Emissions from acid gas flaring incidents are not included in the calculations of emissions against the caps.

Effective 10/2/04 and for the first 365 days after this date, CO emissions in tons/year are limited as determined by the following equation: E = 608[0.15 + 0.85(D/365)]

where

E = CO emissions in total tons since 10/2/04 D = number of days since 10/2/04 3.0

CD hdr RECORDKEEPING REQUIREMENT 4.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 SO2 and CO Recordkeeping: The Permittee shall record the hourly, daily, and 365-day rolling average emission rate of SO2 and CO for No. 3, 4 and 5 sulfur recovery units and tail gas treatment units. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 5.0

CD hdr CEM REQUIREMENTS FOR CO (SEE ADDITIONAL CEM REQUIREMENTS UNDER SV 042, SV 093 and SV 094) 6.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain CO continuous emissions monitoring system (CEMS). 7.0

CD Minn. R. 7017.1006 CO Emissions Measuring: The Permittee shall use a CO CEMS to measure sulfur recovery units (No. 3, 4 and 5) emissions from SV 042 and SV 093. 8.0

CD Minn. R. 7017.1160, subps. 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 9.0

CD hdr REQUIREMENTS FOR NATIONAL EMISSION STANDARDS FOR HAZARDOUS

A IR POLLUTANTS FOR PETROLEUM REFINERIES: CATALYTIC CRACKING UNITS, CATALYTIC REFORMING UNITS, AND SULFUR RECOVERY UNITS (40 CFR pt. 63, subp. UUU) 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 141 of 407

CD 40 CFR Section 63.1569(a) & (c) The Permittee shall meet the requirements for bypass lines set forth in 40 CFR

Section 63.1569. 11.0

CD 40 CFR Section 63.1569(a)(2) Comply with the provisions of the Alternative Work Practice Plans for Bypass Lines and Sulfur Pits - Alternative Work Practice Plans approved by EPA on 5/27/2005 and 11/10/2008 or as subsequently approved. 12.0

CD 40 CFR Section 63.1568(a)(3); 40 CFR Section 63.1574(f) Prepare and implement an operation, maintenance, and monitoring plan according to the requirements in 40 CFR Section 63.1574(f) and operate at all times according to the procedures in the plan. 13.0

CD 40 CFR Section 63.6(e)(1)(i)- (iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subp. 2A-B A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 14.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii); Minn.

R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan. 15.0

CD 40 CFR Section 63.1570 (d); 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)- (iv);

Minn. R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or of malfunction or maintenance of air pollution control equipment. Document conformance with or deviation from startup/shutdown/malfunction plan. 16.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date startup, shutdown, malfunction plan (SSMP). 17.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the startup, shutdown, and malfunction plan (SSMP), revise the SSMP within 45 days after the event. 18.0

CD hdr REPORTING REQUIREMENTS 19.0

S/A 40 CFR Section 60.7(a)(4) Notification: due 60 days before Start Of Construction of any physical or operational change to EU 045, EU 111 and EU 112 or as soon as practicable before the change is commenced and shall include the information describing the precise nature of the change, present and proposed emission control systems, productive capacity of the facility before and after the change, and the expected completion date of the change. The Administrator may request additional relevant information subsequent to this notice. This notification is required by 40 CFR Section 60.7(a)(4). 20.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 142 of 407

Subject Item: GP 114 Fugitive LDAR Connectors, Misc. All FS numbers are included in this group.

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 If an instrument reading of 500 ppm or greater is measured, a leak is detected. 1.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); Minn. R. 7007.0800, subp. 2 Except for connectors in heavy liquid service, the owner or operator shall implement a program to monitor all applicable accessible connectors of 2.0 inches nominal diameter or greater once every four years, with a portion of that facility-wide monitoring to occur annually. This program does not apply to inaccessible or unsafe to monitor connectors, as defined in 40 CFR Section 63.174. 2.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-8a; Minn. R. 7007.0800, subp. 2 If evidence of a potential leak is found by visual, audible, olfactory, or any other detection method at pumps, valves, and connectors in heavy liquid service and pressure relief devices in light liquid or heavy liquid service, the owner or operator shall follow either one of the following procedures:

(1) The owner or operator shall monitor the equipment within 5 days by the method specified in 40 CFR Section 60.485a(b) and shall comply with the requirements of paragraphs (b) through (d) of this section.

(2) The owner or operator shall eliminate the visual, audible, olfactory, or other indication of a potential leak within 5 calendar days of detection. (continued below) 3.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-8a; Minn. R. 7007.0800, subp. 2 (continued from above) (b) The Company is required to meet a 500 ppm leak definition as noted in condition 1 for this group.

(c)(1) When a leak is detected, it shall be repaired as soon as practicable, but not later than 15 calendar days after it is detected, except as provided in 40 CFR

Section 60.482-9a.

(2) The first attempt at repair shall be made no later than 5 calendar days after

each leak is detected.

(d) First attempts at repair include, but are not limited to, the best practices described under 40 CFR Sections 60.482-2a(c)(2) and 60.482-7a(e). 4.0

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.593A(g); Minn. R. 7007.0800, subp. 2 Connectors in gas/vapor or light liquid service are exempt from the requirements in 40 CFR Section 60.482-11a, provided the owner or operator complies with 40 CFR Section 60.482-8a for all connectors, not just those in heavy liquid service. 5.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 143 of 407

Subject Item: GP 115 Sulfur Degassing System

Associated Items: EU 217 Sulfur Loading - Loading-Unloading Equipment

TK 505 Sulfur

TK 526 Sulfur Storage Tank

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT Title I Condition: To avoid

classification as a modification

under 40 CFR Section 52.21 &

Minn. R. 7007.3000 Hydrogen Sulfide: less than or equal to 10 tons/year using 12-month Rolling Sum 2.0

CD hdr RECORDKEEPING REQUIREMENT 3.0

CD Title I Condition: To avoid

classification as a modification

under 40 CFR Section 52.21 &

Minn. R. 7007.3000 Hydrogen Sulfide: The Permittee shall calculate and record the 12-month rolling sum H2S emissions for the listed units using engineering calculations based on degas operational parameters and annual product sulfur sampling to support these calculations. The records may be maintained in either electronic or paper format, unless electronic or paper record is expressly prohibited. 4.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 144 of 407

Subject Item: GP 116 Refinery Fuel Gas SO2 Emissions

Associated Items: MR 033 45 Drum Fuel Gas Combustion O2 Monitor at 25H3

MR 156 41 Unit Fuel Gas Mix Drum Total Sulfur

MR 161 45 Mix Drum Fuel Gas Combustion SO2 Monitor at 25H3

MR 162 45 SO2 Monitor at 29H1/2

MR 166 45 Mix Drum Fuel Gas Combustion O2 Monitor at 29H1/2

MR 196 45 Unit Fuel Gas Mix Drum Total Sulfur

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than or equal to 638 tons/year using 365-day Rolling Sum from all refinery fuel gas. This limit expires upon startup of the modified EU 212, new EU 352 or new EU 353, as part of the #3 Crude/Coker Improvements permit,

whichever is first. 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than or equal to 270 tons/year using 365-day Rolling Sum from all refinery fuel gas combustion. Effective upon startup of the modified 11H6 furnace, new 25H2 furnace or new 23H3 furnace, as part of the #3 Crude/Coker Improvements permit, whichever is first.

For the first 364 days after the reduced limit becomes effective, SO2 emissions are limited as determined by the following equation:

E=270 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after limit is effective 3.0

CD hdr CMS REQUIREMENT FOR THE 41 UNIT FUEL GAS MIX DRUM 4.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: To avoid classification as a major modification under 40

CFR Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 4 Install, operate, and maintain a Total Sulfur CEMS on the 41 unit refinery fuel gas mix drum in accordance with 40 CFR pt. 60, Appendix B and Appendix F. Install, operate, and maintain flow meters on each refinery fuel gas mix drum or each combustion device firing fuel gas from the 41 unit refinery fuel gas mix drum. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: To avoid classification as a major modification under 40

CFR Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 4 Daily Recordkeeping for 41 Unit: The Permittee shall maintain daily records of all monitoring data and calculations of SO2 to show continuous compliance with the applicable emission limits. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 6.0

CD hdr CMS REQUIREMENT FOR THE 45 UNIT FUEL GAS MIX DRUM 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: To avoid classification as a major modification under 40

CFR Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 4 Install, operate, and maintain SO2 and O2 CEMS on two heaters firing refinery fuel gas in accordance with 40 CFR pts. 60, Appendix B and Appendix F, and comply with the requirements of MR 033, MR 161, MR 162, and MR 166. Alternative to the SO2 and O2 CEMS, install, operate and maintain a total sulfur CEMS on the 45 unit refinery fuel gas mix drum in accordance with 40 CFR pt. 60, Appendix B and

A ppendix F, and comply with the requirements of MR 196. Install, operate, and maintain flow meters on each refinery fuel gas mix drum or each combustion device firing fuel gas from the 45 unit refinery fuel gas mix drum. 8.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: To avoid classification as a major modification under 40

CFR Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 4 Daily Recordkeeping for 45 Unit: The Permittee shall maintain daily records of all monitoring data and calculations of SO2 to show continuous compliance with the applicable emission limits. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 145 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: To avoid classification as a major modification under 40 CFR Section 52.21; Minn. R.

7007.3000 Recordkeeping for SO2 limit based on a 365-day Rolling Sum: The Permittee shall calculate and record the rolling sum each calendar day based on data from the refinery fuel gas flow meters and either the total sulfur CEMS or the SO2 CEMS

and O2 CEMS. 10.0

CD hdr SEE MRs 156, 162, 166 AND 196 FOR MONITORING REQUIREMENTS 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 146 of 407

Subject Item: GP 117 Limit that Applies to Gas Oil HDS Heaters (EU084 and EU085)

Associated Items: EU 084 Gas Oil HDS Charge Heater - Process Heater

EU 085 Gas Oil HDS Fractionation Charge Heater - Process Heater

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than 167.6 tons/year using 365-day Rolling Sum from both EU

084 and EU 085. 2.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 3.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions in tons/year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 4.0

CD hdr A LL OTHER REQUIREMENTS ARE LISTED UNDER EU 084 AND EU 085 5.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 147 of 407

Subject Item: GP 118 Temporary Portable Coke Crushers

Associated Items: EU 325 Temporary Coke Crusher #1 - Crusher

EU 326 Temporary Coke Crusher #2 - Crusher

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Minn. R. 7007.0800, subp. 2 Operating Hours: less than or equal to 4,380 hours/year using 12-month Rolling Sum . This limit applies individually to each associated item. 2.0

LIMIT Minn. R. 7011.0715, subp. 1(A) Total Particulate Matter: less than or equal to 38.59 lbs/hour using 1-Hour Average . This limit applies to EU 325. PTE of EU 325 is 3.00 lb/hr based on emission factors from AIRS, March 1990, EPA 450/4-90-003. Compliance is inherent to the design of the equipment. Based on published emission factors and the maximum design of the equipment, emissions will be well below the industrial process equipment rule. 3.0

LIMIT Minn. R. 7011.0715, subp. 1(A) Total Particulate Matter: less than or equal to 36.11 lbs/hour using 1-Hour Average . This limit applies to EU 326. PTE of EU 326 is 2.00 lb/hr based on emission factors from AIRS, March 1990, EPA 450/4-90-003. Compliance is inherent to the design of the equipment. Based on published emission factors and the maximum design of the equipment, emissions will be well below the industrial process equipment rule. 4.0

LIMIT Minn. R. 7011.0715, subp. 1(B) Opacity: less than or equal to 20 percent opacity . This limit applies individually to

each associated item. 5.0

CD hdr RECORDKEEPING REQUIREMENT 6.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Monthly records of hours of operation for the month and 12-month rolling sum by the 28th of the month for the previous month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 148 of 407

Subject Item: GP 122 Liquid Butane Storage Facility

Associated Items: CE 026 Direct Flame Afterburner

CE 069 Refrigerated Condenser

TK 517 Organic Liquid Storage Tank

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.112b(a)(3)(i)-(ii); 40 CFR Section 112b(b)(1); Minn. R. 7011.1520(C); 40 CFR pt. 60, subp. VVa (i) The closed vent system shall be designed to collect all VOC vapors and gases discharged from the storage vessel and operated with no detectable emissions as indicated by an instrument reading of less than 500 ppm above background and visual inspections, as determined in 40 CFR pt. 60, subp. VVa, 40 CFR Section 60.485a(b). A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation.

(ii) The control device shall be designed and operated to reduce inlet VOC emissions by 95 percent or greater. If a flare is used as the control device, it shall meet the specifications described in the general control device requirements 40

CFR Section 60.18 of the General Provisions. 1.0

CD 40 CFR Section 60.113b(c); Minn. R. 7011.1520(C) The owner or operator of each source that is equipped with a closed vent system and control device as required in 40 CFR Section 60.112b (a)(3) or (b)(2) (other than a flare) is exempt from 40 CFR Section 60.8 of the General Provisions. 2.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) Submit for approval by the Administrator as an attachment to the notification required by 40 CFR Section 60.7(a)(1) or, if the facility is exempt from 40 CFR Section 60.7(a)(1), as an attachment to the notification required by 40 CFR Section 60.7(a)(2), an operating plan containing the information listed below. (continued below) 3.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) i) Documentation demonstrating that the control device will achieve the required control efficiency during maximum loading conditions. This documentation is to include a description of the gas stream which enters the control device, including flow and VOC content under varying liquid level conditions (dynamic and static) and manufacturer's design specifications for the control device. If the control device or the closed vent capture system receives vapors, gases, or liquids other than fuels from sources that are not designated sources under this subpart, the efficiency demonstration is to include consideration of all vapors, gases, and liquids received by the closed vent capture system and control device. (continued below) 4.0

CD 40 CFR Section 60.113b(c)(1)(i)-(ii); Minn. R. 7011.1520(C) (continued from above)

If an enclosed combustion device with a minimum residence time of 0.75 seconds and a minimum temperature of 816 °C is used to meet the 95 percent requirement, documentation that those conditions will exist is sufficient to meet the requirements of this paragraph.

(ii) A description of the parameter or parameters to be monitored to ensure that the control device will be operated in conformance with its design and an explanation of the criteria used for selection of that parameter (or parameters). 5.0

CD 40 CFR Section 60.113b(c)(2); Minn. R. 7011.1520(C) Operate the closed vent system and control device and monitor the parameters of the closed vent system and control device in accordance with the operating plan submitted to the Administrator in accordance with 40 CFR Section 60.113b(c)(1), unless the plan was modified by the Administrator during the review process. In this case, the modified plan applies. 6.0

CD Minn. R. 7007.0800, subp. 2 Monitor presence of the flame and record data in a data acquisition system. In the event that the data acquisition system is down due to maintenance or malfunction, daily operator rounds to monitor the presence of the flame will be conducted to ensure a flame is present.

FHR NSPS Kb Operating Plan for Liquid Butane Storage Facility 7.0

CD 40 CFR Section 60.115b; Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.112b(a) shall keep records and furnish reports as required by 40 CFR Section 60.115b(c). The owner or operator shall keep copies of all reports and records required by 40 CFR Section 60.115b, except for the record required by 40 CFR Section 60.115b(c)(1), for at least 2 years. The record required by 40 CFR Section 60.115b(c)(1) will be kept for the life of the control equipment. 8.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 149 of 407

CD 40 CFR Section 60.115b(c)(1)-(2); Minn. R. 7011.1520(C) The owner or operator shall keep the following records. (1) A copy of the operating plan. (2) A record of the measured values of the parameters monitored in accordance with 40 CFR Section 60.113b(c)(2). 9.0

CD 40 CFR Section 60.116b(a); Minn. R. 7011.1520(C) The owner or operator shall keep copies of all records required by 40 CFR Section 60.116b except for the record required by 40 CFR Section 60.116b(b), for at least 2 years. The record required by 40 CFR Section 60.116b(b) will be kept for the life of

the source. 10.0

CD 40 CFR Section 60.116b(b); Minn. R. 7011.1520(C) The owner or operator of each storage vessel as specified in 40 CFR Section 60.110b(a) shall keep readily accessible records showing the dimension of the storage vessel and an analysis showing the capacity of the storage vessel. 11.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) A vailable data on the storage temperature may be used to determine the maximum true vapor pressure as determined below. (1) For vessels operated above or below ambient temperatures, the maximum true vapor pressure is calculated based upon the highest expected calendar-month average of the storage temperature. For vessels operated at ambient temperatures, the maximum true vapor pressure is calculated based upon the maximum local monthly average ambient temperature as reported by the National Weather Service

.

2) For crude oil or refined petroleum products the vapor pressure may be obtained by the following: (continued below) 12.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii); Minn. R. 7011.1520(C) (continued from above) (i) Available data on the Reid vapor pressure and the maximum expected storage temperature based on the highest expected calendar-month average temperature of the stored product may be used to determine the maximum true vapor pressure from nomographs contained in API Bulletin 2517 (incorporated by reference, see 40 CFR Section 60.17), unless the Administrator specifically requests that the liquid be sampled, the actual storage temperature determined, and the Reid vapor pressure determined from the sample(s).

(ii) The true vapor pressure of each type of crude oil with a Reid vapor pressure less than 13.8 kPa or with physical properties that preclude determination by the

recommended method is to be determined from available data and recorded if the estimated maximum true vapor pressure is greater than 3.5 kPa. (continued below) 13.0

CD 40 CFR Section 60.116b(e)(1); 40 CFR Section 60.116b(e)(2)(i)-(ii);

40 CFR Section 60.116b(e)(3)(i)-(iv); Minn. R. 7011.1520(C) (continued from above) (3) For other liquids, the vapor pressure: (i) May be obtained from standard reference texts, or

(ii) Determined by ASTM D2879-83, 96, or 97 (incorporated by reference, see 40 CFR Section 60.17); or

(iii) Measured by an appropriate method approved by the Administrator; or

(iv) Calculated by an appropriate method approved by the Administrator. 14.0

CD 40 CFR Section 63.640(n)(1);
Minn. R. 7011.7280; Minn. R. 7019.0100, subp. 2 Subject to 40 CFR pt. 60, subps. Kb and A (general provisions). Compliance with 40 CFR pt. 60, subps. Kb and A as listed in this permit fully satisfies the requirements of 40 CFR pt. 63, subps. A and CC, 40 CFR pt. 60, subps. K, Ka, and QQQ, 40 CFR pt. 61, subps. A and FF, as applicable, for these tanks. 15.0

CD 40 CFR Section 63.6(e)(1)(i)-(iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subp. 2(A and B) A t all times, including period of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 16.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii);

Minn. R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan (SSMP). 17.0

CD 40 CFR pt. 63, subp. CC. Table 6; 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv); Minn. R.

7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or of malfunction or maintenance of air pollution control equipment. Document

conformance with or deviation from SSMP. 18.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii);

Minn. R. 7011.7280 Maintain up-to-date SSMP. 19.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 150 of 407

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 151 of 407

Subject Item: GP 123 Equipment subject to NSPS NNN

Associated Items: EU 328 Poly Unit De-Propanizer - Other Emission Unit

EU 329 Sat Gas De-Propanizer - Other Emission Unit

EU 330 Alky Unit De-Propanizer - Separation Equipment

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.662(a) Emission Standard: Reduce emissions of TOC (less methane and ethane) by 98 weight percent, or to a TOC (less methane and ethane) concentration of 20 ppmv, on a dry basis corrected to 3 percent oxygen, whichever is less stringent. If a boiler or process heater is used to comply with this paragraph, then the vent stream shall be introduced into the flame zone of the boiler or process heater. 1.0

CD hdr MONITORING REQUIREMENT 2.0

CD 40 CFR Section 60.703(c)(1)(i-ii); 40 CFR Section 60.663(b)(2); 40 CFR Section 60.663(c)(1-3) Monitoring of emissions and operations: Follow monitoring requirements of 40 CFR pt. 60, subp. RRR as alternative means of demonstrating compliance with 40 CFR pt. 60, subp. NNN in accordance with Alternative Monitoring Plan (AMP) approval. USEPA approved the AMP dated December 21, 2009).

1. Any potential bypass lines must be car sealed/lock and key; 2. Visually inspect monthly any car seals that have been installed; 3. Introduce vent stream into boiler/process heater with the primary fuel. 3.0

CD hdr RECORDKEEPING REQUIREMENTS 4.0

CD 40 CFR Section 60.705(d)(1-2); 40 CFR Section 60.665(d) In such cases, the owner or operator shall keep up-to-date, readily accessible records of all monthly visual inspections of the seals as well as readily accessible records of all periods and the duration when the seal mechanism is broken, the bypass line valve position has changed, the serial number of the broken car-seal has changed, or when the key for a lock-and-key type configuration has been

checked out. 5.0

CD 40 CFR Section 60.705(s) Must maintain on file a schematic diagram of the affected vent streams, collection system(s), fuel system(s), control device(s), and bypass system(s) as part of the initial report. This schematic diagram must be retained for the life of the system. 6.0

CD hdr REPORTING REQUIREMENTS 7.0

CD 40 CFR Section 60.705(l)(2) and (7); 40 CFR Section 60.665(l) A ll periods and duration recorded under 40 CFR Section 60.705(d) when the vent stream is diverted from the control device to the atmosphere. 8.0

CD 40 CFR Section 60.18 Flare requirements (control device) for instances in which gas is disposed of within flare system. 9.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 152 of 407

Subject Item: GP 124 Drains subject to NESH FF only and equipped w/water seal or equivalent

Associated Items: EU 316 FHR Lab Inside - Other Emission Unit

FS 006 Bottom Loading - Material Handling/Transfer/Storage

FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 063 32 Penex - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 109 84 Flare Gas Recovery - Process Emissions

FS 110 North Flare - Process Emissions

FS 112 New Flare System and 84-Flare ( 84Unit1 and 84Unit_1) - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards. 1.0

CD CAAA of 1990; 40 CFR Section 61.346(b)(4); 40 CFR Section 0.692-2(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Monthly inspection: Visually inspect water sealed/ lube oil or equivalent sealed drains in active service. Inspect monthly for indications of low liquid levels, cracks, gaps, or leaks that could result in VOC emissions or in lieu of inspection, add water/ lube oil or equivalent to the cup. (EPA approval of alternate monitoring plan dated 4/29/04). (2001 Consent Order 71(a)). 2.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 153 of 407

CD CAAA of 1990; 40 CFR Section 61.346(b)(4); 40 CFR Section 0.692-2(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) For drains with a water seal/ lube oil or equivalent seal at the junction box, flush liquid to the affected junction box via any listed drain cup to verify a water seal/ lube oil or equivalent seal. (2001 Consent Order 71(a)). 3.0

CD CAAA of 1990; 40 CFR Section 61.346(b)(4); 40 CFR Section 0.692-2(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Conduct monthly visual inspection of water/lube/equivalent seal drains for indication of low liquid levels or other conditions that would reduce effectiveness. (2001 Consent Order 71(a)). 4.0

CD 40 CFR Section 61.346(b)(5); 40 CFR Section 60.692-2; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: Whenever low liquid levels are identified, water, lube oil, or equivalent shall be added or first efforts at repair shall be made within 24 hours of detection unless qualifying for delay of repair. 5.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR 60.692-6; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Delay of repair will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown. Repair shall occur before the end of the next refinery or process unit shutdown. 6.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(b)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 7.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 154 of 407

Subject Item: GP 125 Drains subject to NESH FF and NSPS QQQ sealed with plugs

Associated Items: FS 018 11-1 Crude Unit - Process Emissions

FS 019 11-2 Crude Unit - Process Emissions

FS 022 12 Vacuum Distillation - Process Emissions

FS 024 14-Saturate Plant - Process Emissions

FS 027 15-Coker Gasoline - Process Emissions

FS 029 16 Vacuum Distillation - Process Emissions

FS 031 17-Fluid Catalytic Cracking (FCC) Unit - Process Emissions

FS 032 17-Clarified Oil Vac uum Frac - Process Emissions

FS 035 18-1 FCC Gasoline Plant - Process Emissions

FS 036 18-2 FCC Gasoline Plant - Process Emissions

FS 039 19 Vacuum Distillation - Process Emissions

FS 041 21-1Delayed Coker - Process Emissions

FS 042 21-2 Delayed Coker - Process Emissions

FS 060 31 Product Desulfurization - Process Emissions

FS 062 32 Powerformer - Process Emissions

FS 064 32 Aviation Gasoline 0 - Process Emissions

FS 069 33-Hydrogen Plant No. 1 - Process Emissions

FS 070 33 Low Pressure GOHT - Process Emissions

FS 075 35 Alkylation - Process Emissions

FS 077 36 Dimersol - Process Emissions

FS 085 39 Oxy Fuel - Process Emissions

FS 087 41 Amine System - Process Emissions

FS 088 41 Fuel Gas Liquid Recovery - Process Emissions

FS 091 42 Caustic Treating (C3,C4) - Process Emissions

FS 093 43 Polymerization - Process Emissions

FS 095 45 Sulfur Recovery Unit 3 & 4 - Process Emissions

FS 096 45 Fuel Gas Treating - Process Emissions

FS 099 SWS/Non-Phenolic/Phenolic - Process Emissions

FS 104 Gas and Distillate Blending - Process Emissions

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

FS 140 48 ATS Process Unit - Process Emissions

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Standard: Maintain compliance with design, equipment, work practice, operational

standards. 1.0

CD 40 CFR Section 60.692-2(a)(3); 40 CFR Section 60.692-2(a)(4); Minn. R. 7011.1435(C) Each drain must be tightly capped when not in use. May use capped/plugged drains for 40 CFR pt. 60, subp. QQQ compliance if drains are used infrequently or are inactive; otherwise water/lube oil or equivalent seal drains are required. (EPA

A DI 0400030 & 0400031) 2.0

CD 40 CFR Section 61.346(b)(4)(ii); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a) Minn. R. 7011.9930, subp. E; 40 CFR Section 60.692-2(a)(4); Minn. R. 7011.1435(C) Quarterly visual inspection: Each drain using tightly fitting cap or plug for control shall be checked by visual or physical inspection initially and quarterly to ensure caps or plugs are in place and properly installed. 3.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 155 of 407

CD 40 CFR Section 61.346(b)(5); 40 CFR Section 60.692-2; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Repairs: Whenever missing or improperly installed caps or plugs are identified, first efforts at repair shall be made as soon as practicable, but not later than 24 hours after detection, unless qualifying for delay of repair. 4.0

CD 40 CFR Section 60.692-6(a); 40 CFR Section 60.692-6(b); Minn. R. 7011.1435(C) Repair: Delay of repair of facilities that are subject to the provisions of this subpart will be allowed if the repair is technically impossible without a complete or partial refinery or process unit shutdown.

Repair of such equipment shall occur before the end of the next refinery or process

unit shutdown. 5.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 60.697(b)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 6.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 156 of 407

Subject Item: GP 126 Affected Sources at the refinery under MACT GGGGG

Associated Items: CE 028 Direct Flame Afterburner w/Heat Exchanger

CE 029 Direct Flame Afterburner

CE 056 Direct Flame Afterburner

CE 057 Direct Flame Afterburner

CE 070 Activated Carbon Adsorption

EU 292 94V-25F Wemco F Cell - Refining Equipment

EU 331 Containers/Vac Trucks/Frac Tanks used for managi ng remediation wastes - Ma terial Handling Equipment

EU 332 Transfer Systems Associated with Rem ediation Systems - Material Handling Equipment

EU 333 1st & A Groundwater Remediation Knockout Pot 86V22 - Refining Equipment

SV 177 Process Vents Associated with Spring Lake Remediation System

SV 178 Process Vents Associated with Soil Extraction Units 86H41 & 88H2

SV 179 Process Vents Associated with Misc. Remediation Systems

NC/

CA Type Citation Requirement

CD 40 CFR Section 63.7885 (b)(3), 40 CFR Section 63.7886(b)(3), 40 CFR Section 63.7935(a) Comply with the applicable emissions limitations and work practice standards for NESHAP, Subpart FF controlled equipment under 40 CFR pt. 61, except during periods of start up, shutdown, and malfunction. The NESHAP, Subpart FF 2Mg uncontrolled exemption does not apply for remediation material management under 40 CFR pt. 63, subp. GGGGG. 1.0

CD 40 CFR Section 63.6(e)(1)(i)- (iii); 40 CFR Section 63.7935(b),
Minn. R. 7011.7280; Minn.R. 7017.2015, subp. 2(A and B) A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 2.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 157 of 407

Subject Item: GP 127 Stationary Diesels (Compression Ignition) Subject to MACT ZZZZ

Associated Items: EU 007 Emergency generator @ #1,2 crude units - Reciprocating IC Engine

EU 024 Emergency Generator @ FCC - Reciprocating IC Engine

EU 036 Emergency Generator @ #3 Coker - Reciprocating IC Engine

EU 042 Emergency Generator @ #3 Crude Unit - Reciprocating IC Engine

EU 100 Emergency Generator at Pla tformer - Reciprocating IC Engine

EU 127 Plant Air Compressor Diesel Engine - Reciprocating IC Engine

EU 128 Diesel for Standby Circ Pump at #3 C ooling Tower (S end) - Reciprocating IC Engine

EU 129 Diesel for Standby Circ Pump at #3 C ooling Tower (N end) - Reciprocating IC Engine

EU 130 Diesel for Standby Circ Pump at #4 Cooling Tower - Reciprocating IC Engine

EU 132 Diesel for Standby Circ Pump at #5 Cooling Tower - Reciprocating IC Engine

EU 198 Diesel for Fire Water Pump at Lagoon - Reciprocating IC Engine

EU 199 Diesel for Fire Water Pump at St orm/Water Basin - Reciprocating IC Engine

NC/

CA Type Citation Requirement

CD hdr National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines (RICE) Requirements, 40 CFR pt. 63, subp. ZZZZ - The following requirements are not effective until May 3, 2013. 1.0

CD 40 CFR Section 63.6600; 40 CFR pt. 63, subp. ZZZZ, Table 2b, 2c;

Minn. R. 7011.8150 A ny diesels in GP 127 deemed existing nonemergency stationary CI RICE greater

than 500 HP: 1. Comply with the applicable portions of 40 CFR pt. 63, subp. ZZZZ, Table 2b (applicability depends on whether or not an oxidation catalyst is used). 2. Comply with the applicable portions of 40 CFR pt. 63, subp. ZZZZ, Table 2c 2.0

CD 40 CFR Section 63.6602; 40 CFR pt. 63, subp. ZZZZ, Table 2c;

Minn. R. 7011.8150 A ny diesel engine in GP 127 deemed existing nonemergency stationary CI RICE less than 500 HP must comply with the applicable portions of 40 CFR pt. 63, subp.
ZZZZ, Table 2c. 3.0

CD 40 CFR Section 63.6604; 40 CFR Section 80.510(b); Minn. R.

7011.8150 (a) The Permittee must be in compliance with the applicable emission limitations and operating limitations at all times; and (b) At all times, the Permittee must operate and maintain the generator and any associated air pollution control equipment and monitoring equipment in a manner consistent with safety and good air pollution control practices for minimizing emissions. The general duty to minimize emissions does not require you to make any further efforts to reduce emissions if levels required by the standard have been

achieved.

Determination of whether such O&M procedures are being used will be based on information available to the Administrator, which may include, but is not limited to, monitoring results, review of O&M procedures, review of O&M records, and inspection of the source. 4.0

CD 40 CFR Section 63.6612; Minn. R.

7011.8150 Initial performance test: (Where required) due 180 days after 05/03/2013, according to the requirements of Table 4 and 5 (that apply) of 40 CFR pt. 63, subp. ZZZZ, and 40 CFR Section 63.6620(d)-(g). During the initial performance test, the Permittee must establish each applicable operating limitation in Table 2b of 40 CFR pt. 63, subp. ZZZZ. 5.0

CD 40 CFR Section 63.6615; 40 CFR Section 63.6620, Table 3; Minn.

R. 7011.8150 Subsequent Performance Tests: (Where required) Conduct subsequent performance tests semiannually (After you have demonstrated compliance for two consecutive tests, you may reduce the frequency of subsequent performance tests to annually. If the results of any subsequent annual performance test indicate the stationary RICE is not in compliance with the CO or formaldehyde emission limitation, or you deviate from any of your operating limitations, you must resume semiannual performance tests.) 6.0

CD 40 CFR Section 63.6620; Minn. R.

7011.8150 If the facility owns or operates non-operational stationary RICE that is subject to performance testing, the facility does not need to start up the engine solely to conduct the performance test. Owners and operators of a non-operational engine can conduct the performance test when the engine is started up again. 7.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 158 of 407

CD 40 CFR Section 63.6625; 40 CFR pt. 63, subp. ZZZZ, Table 5; 40 CFR Section 63.8; Minn. R.

7011.8150 Monitoring, Installation, Collection, Operation, Maintenance Requirements: By the compliance date of 5/3/2013, each diesel shall comply with the appropriate monitoring, installation, collection, operation, and maintenance requirements for the given size and operational characteristic (emergency/nonemergency) as outlined in 40 CFR Section 63.6625 and 40 CFR Section 63.8(c) through (d). 8.0

CD 40 CFR Section 63.6635; Minn. R.

7011.8150 Beginning 5/3/2013, monitor and collect data according to the following: Except for monitor malfunctions, associated repairs, and required quality assurance or control activities (including, as applicable, calibration checks and required zero and span adjustments), you must monitor continuously at all times that the stationary RICE is operating.

You may not use data recorded during monitoring malfunctions, associated repairs, and required quality assurance or control activities in data average and calculations used to report emission or operating levels. You must, however, use all the valid data collected during all other periods. 9.0

CD 40 CFR Section 63.6640(a); Minn.

R. 7011.8150 Continuous compliance demonstration: Beginning May 3, 2013, demonstrate compliance with each emission limitation and operating limitation that apply from 40 CFR pt. 63, subp. ZZZZ, Tables 2a, 2b, 2c, 2d according to applicable methods specified within Table 6. 10.0

CD 40 CFR Section 63.6640(b); Minn.

R. 7011.8150 Continuous compliance demonstration (limit deviations): Report instances in which emission limitation and operating limitations that apply from 40 CFR pt. 63, subp. ZZZZ, Tables 2a, 2b, 2c, 2d were not met, in accordance with 40 CFR Section 63.6650. If the facility changes the catalyst, the facility must reestablish the values of the operating parameters measured during the initial performance test. When the facility reestablishes the values of the operating parameters, the facility must also conduct a performance test to demonstrate that the facility is meeting the required emission limitation applicable to the stationary

RICE. 11.0

CD 40 CFR Section 63.6640(f); Minn.

R. 7011.8150 Continuous compliance demonstration (emergency RICE): If the facility owns or operates an emergency stationary RICE with a site rating of more than 500 brake HP located at a major source of HAP emissions that was installed prior to June 12, 2006, the facility must operate the engine according to the conditions described in 40 CFR Section 63.6640(f)(2)(i) through (iii). If the facility does not operate the engine according to the requirements in 40 CFR Section 63.6640 (f)(2)(i) through (iii), the engine will not be considered an emergency engine under this subpart and will need to meet all requirements for non-emergency engines. (continued below) 12.0

CD 40 CFR Section 63.6640(f); Minn.

R. 7011.8150 (continued from above) (i) There is no time limit on the use of emergency stationary RICE in emergency

situations. (ii) You may operate your emergency stationary RICE for the purpose of maintenance checks and readiness testing, provided that the tests are recommended by the manufacturer, the vendor, or the insurance company associated with the engine. Required testing of such units should be minimized, but there is no time limit on the use of emergency stationary RICE in emergency situations and for routine testing and maintenance. (iii) You may operate your emergency stationary RICE for an additional 50 hours per year in non-emergency situations. The 50 hours per year for non-emergency situations cannot be used for peak shaving or to generate income for a facility to supply power to an electric grid or otherwise supply power as part of a financial arrangement with another entity. 13.0

CD 40 CFR Section 63.6640; 40 CFR pt. 63, subp. ZZZZ, Table 6; Minn.

R. 7011.8150 By the compliance date of May 3, 2013, the Permittee must meet the requirements for continuous emission limitations, operating limitations, work practices and management practices as outlined in 40 CFR pt. 63, subp. ZZZZ, Table 6. 14.0

CD 40 CFR Section 63.6645; Minn. R.

7011.8150 Notifications: Submit all applicable notifications as listed in 40 CFR Section 63.6645(a) according to applicable status of the RICE. 15.0

CD 40 CFR Section 63.6645(a); 40 CFR Section 63.6645(g); 40 CFR Section 63.7(b); 40 CFR Section 63.8(e)(2), 40 CFR Section 63.9(e); Minn. R. 7011.8150 Notification Submittals: Submit a Notification of Intent to conduct a performance test and site-specific performance evaluation test plan at least 60 days before the performance test is scheduled to begin as required in 40 CFR Section 63.7(b)(1) or as required by delegated authority (MPCA). 16.0

CD 40 CFR Section 63.6650, Table 7;

Minn. R. 7011.8150 Reporting: By the compliance date of May 3, 2013, the Permittee must meet the requirements for reports as outlined in applicable portions of 40 CFR pt. 63, subp.
ZZZZ, Table 7. 17.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 159 of 407

CD 40 CFR Section 63.6655; 40 CFR

Section 63.6660; 40 CFR Section 63.10(b); Minn. R. 7011.8150 General Recordkeeping Requirements: The owner or operator shall maintain files of all information (including all reports and notifications) required by 40 CFR pt. 63, subp. ZZZZ, recorded in a form suitable and readily available for expeditious inspection and review including all information required by 40 CFR Section 63.10(b). The files shall be kept for at least five (5) years following the date of each occurrence, measurement, maintenance, corrective action, report or record. 18.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 160 of 407

Subject Item: GP 128 Stationary Diesels (Spark Ignition 4SRB) Subject to MACT ZZZZ

Associated Items: EU 338 Octane Comparator at Knock Engi ne Building (52ME2B) - Refining Equipment

EU 339 Octane Comparator at Knock Engi ne Building (52ME91) - Refining Equipment

EU 340 Octane Comparator at Knock Engi ne Building (52ME92) - Refining Equipment

EU 341 Octane Comparator at Knock Engi ne Building (52ME2A) - Refining Equipment

EU 342 Octane Comparator at Knock Engi ne Building (52ME65B) - Refining Equipment

EU 343 Octane Comparator at Knock Engi ne Building (52ME93) - Refining Equipment

EU 344 Octane Comparator at Knock Engi ne Building (52ME65A) - Refining Equipment

NC/

CA Type Citation Requirement

CD hdr National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines (RICE) Requirements, 40 CFR pt. 63, subp. ZZZZ - The following requirements are not effective until May 3, 2013. 1.0

CD 40 CFR Section 63.8(c); 40 CFR Section 63.6(e)(1); 40 CFR Section 63.6605; Minn. R.

7011.8150 A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 2.0

CD 40 CFR Sections 63.6600, 63.6602, and 63.6640. 40 CFR pt.
63, Table 2c; Minn. R. 7011.8150 By the compliance date of May 3, 2013, the Permittee must comply with the requirements for existing SI Stationary RICE as outlined in 40 CFR pt. 63, subp.
ZZZZ, Table 2c. 3.0

CD 40 CFR Section 63.6625(j); Minn.

R. 7011.8150 By the compliance date of May 3, 2013, the Permittee has the option of utilizing an oil analysis program rather than following the requirements in 40 CFR pt. 63, subp.
ZZZZ, Table 2c or 2d. 4.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 161 of 407

Subject Item: GP 131 RGP Vapor Combustion Unit

Associated Items: CE 071 Flaring

EU 350 RGP Railcar Loading Rack - Loading-Unloading Equipment

EU 351 RGP Vapor Combustion Unit - Other Combustion

SV 182 RGP Vapor Combustion Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

CD 40 CFR Sections 60.18 and 60.482-10a(d); Minn. R.

7011.0075 Maintain a pilot flame at all times that emissions may be vented to the VCU (EU 351). 2.0

LIMIT 40 CFR Section 60.103a(h) Hydrogen Sulfide: less than or equal to 162 parts per million using 3-hour Rolling

A verage , determined hourly. The combustion in a flare of process upset gases or fuel gas that is released to the flare as a result of relief valve leakage or other emergency malfunctions is exempt from this limit. 3.0

LIMIT 40 CFR Sections 60.18(c) and 60.482-10a(d) Opacity: less than or equal to 0 percent opacity except for periods not to exceed a total of 5 minutes during any two consecutive hours; limit does not apply during periods of startup, shutdown or malfunction. 4.0

CD 40 CFR Sections 60.18(c) and 60.482-10a(d) Operation Limit: Flares must meet maximum velocity and minimum heat content requirements. 5.0

CD 40 CFR Sections 60.18(c) and 60.482-10a(d) A ll flares must be steam-assisted, air-assisted, or non-assisted. 6.0

CD 40 CFR Sections 60.18 and 64.3(a)(2); Minn. R. 7017.0200,
Minn. R. 7011.0075, Minn. R.

7011.0080 Temperature measurements shall be maintained at temperatures indicating presence of a pilot flame (i.e. above ambient) at all times that emissions may be vented to the VCU (EU 351). 7.0

LIMIT Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot (230 mg/dscm) H2S content in the fuel. This limit does not apply during periods of startup, shutdown, or malfunction. Compliance with the flare H2S standard in 40 CFR pt. 60, subp. Ja demonstrates compliance with this limit. 8.0

CD hdr B. MONITORING REQUIREMENTS 9.0

CD 40 CFR Sections 60.18 and 64.3(b)(4)(ii); Minn. R. 7017.0200,

Minn. R. 7011.0080 Monitor and record temperature at least once every 15 minutes indicating presence or absence of a flame at all times that emissions may be vented to the VCU (EU 351). 10.0

CD 40 CFR Section 60.107a(a)(3) Combustion of streams in the VCU that are exempt from CEMS monitoring without exemption application: Streams combusted in the RGP VCU are exempt from CEMS requirements if streams are exempt per 40 CFR Section 60.102a(g)(1)(iii) describing exempt emissions including tank degassing and cleaning, exempt per 40 CFR Section 60.103a(h) describing exempt flaring including gases from process upsets, relief valve leakage, or emergency relief streams meeting one of the following requirements:

(i) Pilot gas for heaters and flares.

(ii) Fuel gas streams that meet a commercial-grade product specification for sulfur content of 30 ppmv or less. In the case of a liquefied petroleum gas (LPG) product specification in the pressurized liquid state, the gas phase sulfur content should be evaluated assuming complete vaporization of the LPG and sulfur containing-compounds at the product specification concentration. (continued below) 11.0

CD 40 CFR Section 60.107a(a)(3) (continued) (continued from above) (iii) Fuel gas streams produced in process units that are intolerant to sulfur contamination, such as fuel gas streams produced in the hydrogen plant, catalytic reforming unit, isomerization unit and HF alkylation process units. 12.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 162 of 407

CD 40 CFR Section 60.107a(b) Combustion of streams in the VCU that are exempt from CEMS monitoring requiring with an exemption application: The Permittee may also demonstrate that the stream to the RGP VCU is low-sulfur and exempt from CEMS monitoring requirements by applying for an exemption in accord with procedures in 40 CFR Section 60.107a(b). The effective date of the exemption is the date of the submission of the required information. No further action is required unless refinery operating conditions change in such a way that affects the exempt fuel gas stream/system (e.g., the stream composition changes). If such a change occurs, the Permittee shall follow the procedures in 40 CFR Section 60.107a(b)(3). 13.0

CD 40 CFR Section 60.107a(a) A lternative to low sulfur exemption: As an alternative to the planned low sulfur monitoring compliance demonstration requirements, the Permittee may demonstrate compliance with the limits in 40 CFR Section 60.103a(h) with a H2S CEMS meeting the requirements of 40 CFR Section 60.107a(a). 14.0

CD 40 CFR Section 60.107a(f) Flow Monitoring: The Permittee shall install, operate, calibrate, and maintain a CPMS to measure and record the flow rate of gas discharged to the flare in accordance with manufacturer's specifications and 40 CFR Section 60.107a(f)(1). A visual inspection shall be performed at least quarterly of all components of the monitor for physical and operational integrity and all electrical connections for oxidation and galvanic corrosion if the flow monitor is not equipped with a

redundant flow sensor. The flow meter shall be calibrated in accordance with the manufacturer's procedures and specifications biennially (every two years) or at the frequency specified by the manufacturer. 15.0

CD 40 CFR Section 64.3; Minn. R.
7017.0200, Minn. R. 7011.0075 Check daily, or as required by the manufacturing specification, monitoring equipment that is related to maintaining VCU control efficiency, for example: pressure gauges, chart recorders, temperature indicators and recorders. 16.0

CD 40 CFR Section 64.3; Minn. R.
7017.0200, Minn. R. 7011.0075 Inspect monthly, or as required by the manufacturing specification, components that are subject to wear or plugging that are related to maintaining VCU control efficiency, for example: bearings, belts, hoses, fans, nozzles, orifices and ducts. 17.0

CD 40 CFR Section 64.3; Minn. R.
7017.0200, Minn. R. 7011.0075 Inspect quarterly, or as required by the manufacturing specification, components that are not subject to wear including structural components, housings, ducts and hoods that are related to the VCU control device (CE 071). 18.0

CD 40 CFR Section 64.3; Minn. R.
7017.0200, Minn. R. 7011.0075 Thoroughly inspect the VCU (EU 351) at least annually, or as required by the manufacturing specification (this often requires shutting down temporarily). 19.0

CD 40 CFR Section 64.3; Minn. R.
7017.0200, Minn. R. 7011.0075 Calibrate once every calendar year, or as required by the manufacturing specification, all monitoring equipment that is related to maintaining control efficiency. 20.0

CD 40 CFR Section 60.13(h) The Permittee shall calculate valid 1-hour averages for the flare flow CPMS. 21.0

CD hdr C. OTHER LIMITS AND REQUIREMENTS 22.0

CD 40 CFR Sections 60.103a(c-e) and 60.107a(e)(4) RCFA and Corrective Action Requirements: The Permittee shall conduct a root cause analysis of any emission limit exceedance or process startup, shutdown, upset or malfunction that exceeds permitted SO2 emissions by 227 kilograms (kg) (500 lb) in any 24-hour period, or any discharge to the flare in excess of 14,160 standard cubic meters (m3) (500,000 standard cubic feet (scf)) above the baseline flow in any 24-hour period. Engineering calculations shall be used to calculate the SO2 emissions in the event of a discharge that may trigger a root cause analysis.

For any root cause analysis performed, the Permittee shall record the identification of the affected facility, the date and duration of the discharge, the results of the root cause analysis and the action taken as a result of the root cause analysis. (continued below) 23.0

CD 40 CFR Sections 60.103a(c-e) and 60.107a(e)(4) (continued) (continued from above)

A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix).

For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable. (continued below) 24.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Sections 60.103a(c-e) and 60.107a(e)(4) (continued) (continued from above) No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed date, and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 25.0

CD Minn. R. 7011.0075 The Permittee shall maintain an inventory of spare parts for the control equipment that are subject to frequent replacement, as required by the manufacturing specification or documented in maintenance records. 26.0

CD Minn. R. 7011.0075 The Permittee shall train staff on the operation and monitoring of control equipment and troubleshooting, and train and require staff to respond to indications of malfunctioning equipment, including alarms and other indicators of abnormal operation. 27.0

CD 40 CFR Section 60.103a(a-b) Flare Management Plan: The Permittee shall develop, implement, and submit a written flare management plan following the requirements of 40 CFR Section 60.103a(a-b) immediately upon startup of the VCU (EU 351) except as otherwise allowed by 40 CFR Section 60.103a(a-b). The flare management plan should be updated periodically for changes such as new connections to the flare or with the installation of a flare gas recovery system but the plan must be resubmitted only if the Permittee adds or revises baseline flow rates, installs a flare gas recovery system, or adopts the alternative monitoring methods of 40 CFR Section 60.107a(g) for flares with water seals. 28.0

CD hdr D. PERFORMANCE TESTING 29.0

CD 40 CFR Sections 60.8, 60.18, and 60.104a(a) Flare Initial Performance Test: Within 60 days after achieving 10,000 barrels per calendar day of propylene railcar loading, but not later than 180 days after initial startup of such facility, the Permittee shall conduct any required performance testing.

Due to inherently low sulfur content of this fuel stream, the Permittee plans to satisfy the performance test requirement for 40 CFR Section 60.8 for the flare H2S limit by applying for an exemption from monitoring and testing by applying in accord with procedures in 40 CFR Section 60.107a(b). 30.0

CD hdr E. REPORTING REQUIREMENTS 31.0

S/A 40 CFR Section 60.7(a)(1) Notification: due 30 days after Start Of Construction of the VCU (EU 351). A notification of the date construction of EU 351 commenced postmarked no later than 30 days after such date. FHR submitted the NSPS subp. Ja notification for the VCU on 12/3/2012, noting that FHR commenced construction pursuant to the NSPS definition (entered contract to fabricate the VCU offsite) but not the NSR

definition on 11/8/2012. 32.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 60.108a(b) Notification: due 15 days after Startup (actual date) of the VCU combusting gases from the operating loading rack. The notification shall include the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee seeks to comply. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 33.0

CD Minn. R. 7011.0075, subp. 5; Minn. R. 7007.0800, subp. 6(A)(2) Temperatures outside of a range indicating the presence of a flame during times when emissions are vented to the VCU shall be reported in semiannual deviation
reports. 34.0

CD hdr F. RECORDKEEPING REQUIREMENTS 35.0

CD 40 CFR Section 60.108a(c)(1) Recordkeeping for Flare Management Plan: The Permittee shall maintain a copy of the flare management plan. 36.0

CD 40 CFR Section 60.108a(c)(5) Recordkeeping for streams utilizing the low sulfur monitoring exemption: For each fuel gas stream to which one of the exemptions listed in 40 CFR Section 60.107a(a)(3) applies, records of the specific exemption determined to apply for each fuel stream. If the Permittee applies for the exemption described in 40 CFR Section 60.107a(a)(3)(iv), the Permittee must keep a copy of the application as well as the letter from the Administrator granting approval of the application. 37.0

CD 40 CFR Section 60.108a(c)(6) RCFA and Corrective Action Recordkeeping: The Permittee shall maintain records of required root cause analyses and corrective actions as required per 40 CFR Section 60.108a(c)(6). 38.0

CD Minn. R. 7011.0075 Maintain records of monitoring inspections with dates and any corrective actions. 39.0

CD Minn. R. 7011.0075 Maintain records of parts replaced, repaired or modified for the previous five years. 40.0MINNESOTA POLLUTION CONTROL AGENCY

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Subject Item: GP 132 Fugitive Equipment in Natural Gas (non-VOC) Service

Associated Items: FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

FS 048 25-Crude Unit - Process Emissions

FS 139 CHP Equipment in Natural Gas Service - Process Emissions

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT (See compliance demonstration requirements contained in the referenced subject groups listed below.) 1.0

CD Title I Condition: 40 CFR Section 52.21(j) & Minn. R. 7007.3000 For new fugitive equipment in natural gas service added to FS 045 and FS 048 authorized by the #3 Crude/Coker Improvements Permit, and FS 139, comply with the LDAR requirements in GP 087, GP 090, GP 091, GP 093, GP 101 and GP 114. (BACT Limit) 2.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 165 of 407

Subject Item: GP 133 Emergency Propane Generators

Associated Items: CE 075 Catalytic Converter

EU 355 Sump 3 Emergency Generator - Reciprocating IC Engine

EU 356 Sump 7 Emergency Generator - Reciprocating IC Engine

EU 357 Lift Station Emergency Gener ator - Reciprocating IC Engine

SV 185 Sump 3 Emergency Generator Exhaust Stack

SV 186 Sump 7 Emergency Generator Exhaust Stack

SV 187 LS Emergency Generator Exhaust Stack

NC/

CA Type Citation Requirement

CD hdr A . LIMITS APPLY TO EACH EMERGENCY ENGINE LISTED IN GP 133 (UNLESS SPECIFICALLY NOTED) 1.0

LIMIT 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 90.103 Table 1; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 Carbon Monoxide: less than or equal to 519 grams/kilowatt-hour . This limit is applicable to EU355 and EU356. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet

this limit. 2.0

CD 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 90.103 Table 1; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 HC + NOx: less than or equal to 13.4 grams/kilowatt-hour. This limit is applicable to EU355 and EU356. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet this limit. 3.0

LIMIT 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 1048.101 Table 1; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 Carbon Monoxide: less than or equal to 4.4 grams/kilowatt-hour for transient testing. This limit is applicable to EU357. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet

this limit. 4.0

CD 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 1048.101 Table 1; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 HC + NOx: less than or equal to 2.7 grams/kilowatt-hour for transient testing. This limit is applicable to EU357. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet this limit. 5.0

LIMIT 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 1048.101 Table 3; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 Carbon Monoxide: less than or equal to 6.5 grams/kilowatt-hour for field testing. This limit is applicable to EU357. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet

this limit. 6.0

CD 40 CFR Sections 60.4243(a), 60.4233(c) and 60.4231(c); 40 CFR Section 1048.101 Table 3; 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 HC + NOx: less than or equal to 3.8 grams/kilowatt-hour for field testing. This limit is applicable to EU357. Compliance with this emission limit is demonstrated by purchasing an engine that is certified by the manufacturer to meet this limit. 7.0

LIMIT Minn. R. 7011.2300, subp. 2 Sulfur Dioxide: less than or equal to 0.50 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with this limit can be demonstrated by firing strictly commercial-grade propane. 8.0

LIMIT Minn. R. 7011.2300, subp. 1 Opacity: less than or equal to 20 percent opacity once operating temperatures have been attained. Compliance with this limit can be demonstrated by firing strictly commercial-grade propane. 9.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 10.0

CD Minn. R. 7007.0800, subps. 4 and

5 The Permittee shall maintain documentation onsite that each unit listed in this group is an emergency generator by design that qualifies under the U.S. EPA memorandum entitled "Calculating Potential to Emit (PTE) for Emergency Generators" dated September 6, 1995, limiting operation to 500 hours per year using a 12-Month Rolling Sum for each individual emergency generator in GP133. 11.0

CD Minn. R. 7005.0100, subp. 35a Fuel Restriction: Authorized to burn commercial-grade propane only. 12.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 166 of 407

CD 40 CFR Section 60.4243(a)(1); 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 The Permittee shall purchase engines that are certified to the emission standards in 40 CFR Section 60.4231(a) through (c), as applicable, for the same engine class and maximum engine power. In addition, the Permittee shall keep records of conducted maintenance to demonstrate compliance and meet the requirements as specified in 40 CFR pt. 1068, subparts A through D as applicable. If the Permittee adjusts the engine settings according to and consistent with the manufacturer's instructions, the stationary SI internal combustion engine (ICE) will not be considered out of compliance. 13.0

CD 40 CFR Section 60.4243(d)(1-3); 40 CFR Section 63.6590(c)(4);
Minn. R. 7011.2310; Minn. R.

7011.8150 Operation of Emergency Stationary ICE: 1) There is no time limit on the use of emergency stationary ICE in emergency

situations. 2) The Permittee may operate the emergency stationary ICE for any combination of the purposes specified in paragraphs (d)(2)(i) through (iii) of this section for a maximum of 100 hours per calendar year. Any operation for non-emergency situations as allowed by paragraph (d)(3) of this section counts as part of the 100 hours per calendar year allowed by this paragraph (d)(2). (continued below) 14.0

CD 40 CFR Section 60.4243(d)(1-3); 40 CFR Section 63.6590(c)(4);
Minn. R. 7011.2310; Minn. R.

7011.8150 (continued from above) 2i) Emergency stationary ICE may be operated for maintenance checks and readiness testing, provided that the tests are recommended by federal, state or local government, the manufacturer, the vendor, the regional transmission organization or equivalent balancing authority and transmission operator, or the insurance company associated with the engine. The Permittee may petition the

A dministrator for approval of additional hours to be used for maintenance checks and readiness testing, but a petition is not required if the Permittee maintains records indicating that federal, state, or local standards require maintenance and testing of emergency ICE beyond 100 hours per calendar year. 2iii) Emergency stationary ICE may be operated for periods where there is a deviation of voltage or frequency of 5 percent or greater below standard voltage or frequency. (continued below) 15.0

CD 40 CFR Section 60.4243(d)(1-3); 40 CFR Section 63.6590(c)(4);
Minn. R. 7011.2310; Minn. R.

7011.8150 (continued from above) 3) Emergency stationary ICE may be operated for up to 50 hours per calendar year in non-emergency situations. The 50 hours of operation in non-emergency situations are counted as part of the 100 hours per calendar year for maintenance and testing and emergency demand response provided in paragraph (d)(2) of this section. Except as provided in paragraph (d)(3)(i) of this section, the 50 hours per year for non-emergency situations cannot be used for peak shaving or non-emergency demand response, or to generate income for a facility to an electric grid or otherwise supply power as part of a financial agreement with another entity. 16.0

CD hdr C. MONITORING AND RECORDKEEPING REQUIREMENTS 17.0

CD 40 CFR Section 60.4237; 40 CFR Section 63.6590(c)(4); Minn. R.
7011.2310; Minn. R. 7011.8150 Monitoring - Hours of Operation: The Permittee shall install non-resettable hour meters prior to startup of EU355, EU356 and EU357. 18.0

CD 40 CFR Section 60.4245(b); 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 The Permittee shall keep records of the hours of operation of EU355, EU356 and EU357 that is recorded through the non-resettable hour meters. The Permittee shall document how many hours are spent for emergency operation, including what classified the operation as emergency and how many hours are spent for non-emergency operation. This documentation shall be completed by the 28th day of each month for the preceding month. 19.0

CD 40 CFR Sections 60.4243(a)(1) and 60.4245(a)(2); 40 CFR Section 63.6590(c)(4); Minn. R.
7011.2310; Minn. R. 7011.8150 The Permittee shall keep records of conducted maintenance on each engine in GP133. This documentation shall be completed by the 28th day of each month for the preceding month. 20.0

CD 40 CFR Section 60.4245(a)(3); 40 CFR Section 63.6590(c)(4); Minn.
R. 7011.2310; Minn. R. 7011.8150 The Permittee shall keep documentation from the manufacturer that each engine in GP133 is certified to meet the emission standards and information as required in 40 CFR parts 90, 1048, 1054 and 1060, as applicable. 21.0

S/A 40 CFR Section 60.7(a)(3); 40

CFR Section 63.9 Notification: due 15 days after Startup (actual date) of EU355, EU356 and EU357.

A notification of the dates of startup of each individual emission unit (EU355, EU356 and EU357) postmarked no later than 15 days after such date. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 22.0

CD hdr D. NESHAP SUBP. ZZZZ REQUIREMENT 23.0MINNESOTA POLLUTION CONTROL AGENCY

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Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 167 of 407

CD 40 CFR Section 63.6590(c)(4);

Minn. R. 7011.8150 The Permittee shall meet the requirements of 40 CFR pt. 63, subp. ZZZZ by meeting the requirements of 40 CFR pt. 60, subp. JJJJ, as a new or reconstructed spark ignition 4 stroke rich burn (4SRB) stationary RICE with a site rating of less than or equal to 500 brake HP located at a major source of HAP emissions. 24.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 168 of 407

Subject Item: GP 134 Temporary TK002 Thermal Oxidizers

Associated Items: CE 076 Thermal Oxidizer

CE 077 Gas Scrubber (General, Not Classified)

EU 358 Temporary Portable Therma l Oxidizer(s) - Other Combustion

MR 201 Temporary TK2 SO2 CEM

SV 188 Temporary Portable TO Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS (LIMITS EXPIRE AT COMPLETION OF 2014 TK002 TURNAROUND) 1.0

LIMIT 40 CFR Section 60.102a(g)(1)(i) Sulfur Dioxide: less than or equal to 20 parts per million using 3-hour Rolling

A verage (dry basis, corrected to 0 percent excess air, determined hourly). Limit applies to each portable thermal oxidizer in EU358 in this group and is effective when specified by 40 CFR Section 60.102a(a). Limit does not apply during periods of startup, shutdown and malfunction. 2.0

LIMIT 40 CFR Section 60.102a(g)(1)(i) Sulfur Dioxide: less than or equal to 8.0 parts per million using 365-day Rolling

A verage (dry basis, corrected to 0 percent excess air, determined daily). Limit applies to each portable thermal oxidizer in EU358 in this group and is effective when specified by 40 CFR Section 60.102a(a). Limit does not apply during periods of startup, shutdown and malfunction. 3.0

LIMIT Minn. R. 7011.0110 Opacity: less than or equal to 20 percent opacity . Limit applies to each portable thermal oxidizer in EU358 in this group. 4.0

CD hdr B. OTHER REQUIREMENTS (THESE EXPIRE AT COMPLETION OF 2014 TK002 TURNAROUND) 5.0

LIMIT Minn. R. 7007.0800, subp. 2 Heat Input: less than or equal to 40.0 million Btu/hour from the temporary, portable thermal oxidizer(s). The Permittee may operate one thermal oxidizer with a maximum heat input of 40.0 mmBtu/hr, or multiple thermal oxidizers that combine for up to 40.0 mmBtu/hr heat input. In no case shall the total heat input capacity of the equipment exceed 40.0 mmBtu/hr. 6.0

CD 40 CFR Section 61.349(a)(1) When operated as a BWON control device per 40 CFR Section 61.349, the closed-vent system shall: i) Be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv above background, as determined initially and thereafter at least once per year by the methods specified in 40 CFR Section 61.355(h). ii) Vent systems that contain any bypass line that could divert the vent stream away from a control device used to comply with the provisions of this subpart shall install, maintain, and operate according to the manufacturer's specifications a flow indicator that provides a record of vent stream flow away from the control device at least once every 15 minutes, except as provided in paragraph (a)(1)(ii)(B) of this

section. (A) The flow indicator shall be installed at the entrance to any bypass line that could divert the vent stream away from the control device to the atmosphere. (continued below) 7.0

CD 40 CFR Section 61.349(a)(1) (continued from above) (B) Where the bypass line valve is secured in the closed position with a car-seal or lock-and-key type configuration, a flow indicator is not required. iii) All gauging and sampling devices shall be gas-tight except when gauging or sampling is taking place. iv) For each closed-vent system complying with paragraph (a) of this section, one or more devices which vent directly to the atmosphere may be used on the closed-vent system provided each device remains in a closed, sealed position during normal operations except when the device needs to open to prevent physical damage or permanent deformation of the closed-vent system resulting from malfunction of the unit in accordance with good engineering and safety practices for handling flammable, explosive, or other hazardous materials. 8.0

CD 40 CFR Sections 61.349(a)(2)(i)(C) and 61.354(c) When operated as a BWON control device per 40 CFR Section 61.349, the Permittee shall provide a minimum residence time of 0.5 seconds at a minimum temperature of 1400 deg F as monitored in accordance with 40 CFR Section 61.354(c). 9.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 61.349(f) and (g) Upon startup of EU358 as a BWON control device, each closed-vent system and control device shall be visually inspected initially and quarterly thereafter. The visual inspection shall include inspection of ductwork and piping and connections to

covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. Except as provided in 40 CFR Section 61.350 of this subpart, if visible defects are observed during an inspection, or if other problems are identified, or if detectable emissions are measured, a first effort to repair the closed-vent system and control device shall be made as soon as practicable but no later than 5 calendar days after detection. Repair shall be completed no later than 15 calendar days after the emissions are detected or the

visible defect is observed. 10.0

CD 40 CFR Section 61.357 When operated as a BWON control device per 40 CFR Section 61.349, the Permittee shall submit quarterly reports including the following information and as required by the NESHAP FF requirements in the Total Facility section of this permit: 1) Total annual benzene quantity from facility waste determined in accordance with 40 CFR Section 61.355(a). 2) A table identifying each waste stream and whether or not the waste stream will be controlled for benzene emissions in accordance with the requirements of this subpart. 3) For each waste stream identified as not being controlled for benzene emissions in accordance with the requirements of this subpart the following information shall

be added to the table: i) Whether or not the water content of the waste stream is greater than 10 percent; ii) Whether or not the waste stream is a process wastewater stream, product tank drawdown, or landfill leachate; iii) Annual waste quantity for the waste stream; (continued below) 11.0

CD 40 CFR Section 61.357 (continued from above) iv) Range of benzene concentrations for the waste stream; v) Annual average flow-weighted benzene concentration for the waste stream; and vi) Annual benzene quantity for the waste stream. 4) The information required in paragraphs (a)(1), (2), and (3) of this section should represent the waste stream characteristics based on current configuration and operating conditions. The Permittee only needs to list in the report those waste streams that contact materials containing benzene. The report does not need to include a description of the controls to be installed to comply with the standard or other information required in 40 CFR Section 61.10(a). 12.0

CD hdr C. MONITORING REQUIREMENTS (THESE EXPIRE AT COMPLETION OF 2014 TK002 TURNAROUND) 13.0

CD 40 CFR Sections 60.13 and 60.107a(a)(1) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0-percent excess air) of SO2 emissions into the atmosphere. The monitor must include an O2 monitor for correcting the data for excess air. Monitoring for each EU may be performed at only one representative location if each EU has a common source of fuel gas. As an alternative to a CEMS, the Permittee shall demonstrate compliance through following the monitoring and recordkeeping requirements of an EPA approved Alternative Monitoring Plan (AMP). This requirement applies to each EU in this group. 14.0

CD hdr D. REPORTING AND RECORDKEEPING REQUIREMENTS (THESE EXPIRE AT COMPLETION OF 2014 TK002 TURNAROUND, ALSO SEE TABLE B) 15.0

CD 40 CFR Sections 60.13 and
60.108a; Minn. R. 7017.1110 SO2 CEMS: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of SO2 emissions in the units and basis of the emission limit and shall report any excess emissions in the facility's Quarterly Air Quality and Excess Emissions Report. Alternatively, the Permittee shall follow the reporting and recordkeeping requirements of an EPA approved Alternative Monitoring Plan (AMP). 16.0

CD 40 CFR Sections 60.103a and

60.108a The Permittee shall comply with the applicable fuel gas combustion device SO2 Root Cause Analysis in 40 CFR Section 60.103a and the recordkeeping requirements and reporting procedures of 40 CFR Section 60.108a for any discharges of SO2 in any 24 hour period that are greater than 500 lbs SO2 in excess of the allowable limit(s). 17.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 60.108a(b) Notification: due 15 days after Startup (actual date) of each thermal oxidizer in EU358. The notification shall include specific monitoring provisions of 40 CFR Section 60.107a with which the Permittee seeks to comply. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 18.0MINNESOTA POLLUTION CONTROL AGENCY

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Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 170 of 407

S/A Minn. R. 7017.1040, subp. 1 Notification: due 60 days before Install ation of CEMS. The notification shall include plans and drawings of the proposed system which show the configuration of the monitoring system including any monitor bypass routes. 19.0

S/A 40 CFR Section 60.7(a)(5); Minn.

R. 7017.1060 Notification: due 30 days before CEM Certification Test, if required. This notification is required under 40 CFR Section 60.7(a)(5) and Minn. R. 7017.1060. 20.0

CD hdr E. PERFORMANCE TESTING (THESE EXPIRE AT COMPLETION OF 2014 TK002 TURNAROUND) 21.0

S/A 40 CFR Sections 60.8 and
60.104a; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 60 days after achieving maximum capacity rate at which the affected facility will be operated, but not later than 180 days after initial startup of such facility, the Permittee shall conduct performance test(s) for SO2 emissions. Performance tests shall be performed following the methods specified in 40 CFR Section 60.104a unless otherwise approved in accord with 40 CFR Section 60.8. If a performance test waiver is granted pursuant to 40 CFR Section 60.8, the Permittee shall meet any conditions of that waiver in lieu of performance test requirements. 22.0MINNESOTA POLLUTION CONTROL AGENCY

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Subject Item: GP 135 Combustion Turbine and Duct Burners

Associated Items: CE 078 Catalytic Oxidizer

CE 079 SCR (Selective Catalytic Reduction)

EU 359 Combustion Turbine - Turbine

EU 360 Duct Burners - Duct Burner

FS 139 CHP Equipment in Natural Gas Service - Process Emissions

MR 202 75 Unit NOx

MR 203 75 Unit CO

MR 204 75 Unit O2

MR 205 75 Unit Stack Flow

MR 206 Combustion Turbine Fuel Flow Meter

MR 207 Duct Burners Fuel Flow Meter

MR 208 CHP Facility Electricity Generation 1

MR 209 CHP Facility Electricity Generation 2

MR 210 CHP Facility Steam Delivery

MR 216 Ambient Air Monitor

SV 189 HRSG Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 27.7 tons/year using 365-day Rolling Sum . For the first 364 days after initial certification of the NOx CEMS, NOx emissions are limited as determined by the following equation:

E = 27.7 x [0.15 + 0.85(D/365)]

where

E = NOx emissions in total tons D = number of days after limit is effective 2.0

LIMIT 40 CFR Sections 60.4320(a), 60.4380(b)(1) and 60.4380(b)(3) and 40 CFR pt. 60, subp. KKKK,

Table 1 Nitrogen Oxides: less than or equal to 25 parts per million using 30-day Rolling

A verage at 15 percent O2 or 150 ng/J of useful output (1.2 lb/MWh). when EU359 is operating at 75% load or greater and at temperatures greater than 0 degrees F. For purposes of determining compliance with the NOx limits on a ppm basis, the procedures specified in 40 CFR pt. 60, subp. KKKK shall be used. The Permittee shall calculate a new 30-day average for each unit operating day which is the average of all hourly NOx emissions rates for the preceding 30 unit operating days in which a valid NOx emission rate is obtained for at least 75 percent of all operating hours. For operating periods during which the two different limits apply, the allowable emission rate is the average of the applicable limit during each hour. The higher limit applies for the hour if any point in the hour, the unit was subject to the higher limit. 3.0

LIMIT 40 CFR Section 60.4320(a), 60.4380(b)(1) and 60.4380(b)(3) and 40 CFR pt. 60, subp. KKKK,

Table1 Nitrogen Oxides: less than or equal to 96 parts per million using 30-day Rolling

A verage at 15 percent O2 or 590 ng/J of useful output (4.7 lb/MWh) when EU359 is operating at less than 75% load or less than 0 degrees F. For purposes of determining compliance with the NOx limits on a ppm basis, the procedures specified in 40 CFR pt. 60, subp. KKKK shall be used. The Permittee shall calculate a new 30-day average for each unit operating day which is the average of all hourly NOx emissions rates for the preceding 30 unit operating days in which a valid NOx emission rate is obtained for at least 75 percent of all operating hours. For operating periods during which the two different limits apply, the allowable emission rate is the average of the applicable limit during each hour. The higher limit applies for the hour if any point in the hour, the unit was subject to the higher

limit. 4.0MINNESOTA POLLUTION CONTROL AGENCY

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LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 66.9 tons/year using 365-day Rolling Sum . For the first 364 days after initial certification of the CO CEMS, CO emissions are limited as determined by the following equation:

E = 66.9 x [0.15 + 0.85(D/365)]

where

E = CO emissions in total tons D = number of days after limit is effective 5.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Volatile Organic Compounds: less than or equal to 28.0 tons/year using 365-day Rolling Sum 6.0

LIMIT Title I Condition: 40 CFR Section 52.21(j) and Minn. R. 7007.3000 PM < 10 micron: less than or equal to 0.0057 lbs/million Btu heat input using 3-hour

A verage as demonstrated by the performance test requirements set forth below in Section G of the Subject Item (GP135). (BACT Limit) 7.0

LIMIT Title I Condition: 40 CFR Section 52.21(j) and Minn. R. 7007.3000 PM < 10 micron: less than or equal to 3.8 lbs/hour using 3-hour Average measured as filterable and condensable PM using Method 5 and 201A for filterable PM and Method 202 for condensable PM as demonstrated by the performance test requirements set forth below in Section G of the Subject Item (GP135). (BACT Limit) 8.0

LIMIT Title I Condition: 40 CFR Section 52.21(j) and Minn. R. 7007.3000 PM < 2.5 micron: less than or equal to 0.0057 lbs/million Btu heat input using 3-hour Average as demonstrated by the performance test requirements set forth below in Section G of the Subject Item (GP135). (BACT Limit) 9.0

LIMIT Title I Condition: 40 CFR Section 52.21(j) and Minn. R. 7007.3000 PM < 2.5 micron: less than or equal to 3.8 lbs/hour using 3-hour Average measured as filterable and condensable PM using Method 5 and 201A for filterable PM and Method 202 for condensable PM as demonstrated by the performance test requirements set forth below in Section G of the Subject Item (GP135). (BACT Limit) 10.0

LIMIT Title I Condition: 40 CFR Section 52.21(j) and Minn. R. 7007.3000 Carbon Dioxide Equivalent: less than or equal to 1000 lbs/megawatt-hour using 12-month Rolling Average gross output, where gross output is determined by the following equation:

Pgross = (Pect + Pest) / 0.95 + 0.75 * Pt

where Pect = electric output of combustion turbine in MWh Pest = electric output of steam turbine in MWh Pt = useful thermal energy output in MWh The first full compliance period will be 365 days after initial startup of EU359 and

EU360. (BACT Limit) 11.0

LIMIT 40 CFR Section 60.4330(a) Sulfur Dioxide: less than or equal to 110 nanograms/joule heat input (0.90 lb/MWh) gross output or the Permittee must not burn any fuel in EU359 which contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. 12.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The PTE of this source is 0.0014 lb/mmBtu. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

LIMIT Minn. R. 7011.1410, subp. 3(C)(1) Total Particulate Matter: less than or equal to 0.1 lbs/million Btu heat input using 3-hour Rolling Average (0.18 grams per million cal). The PTE of this source is 0.0057 lb/mmBtu. Compliance with the fuel restriction requirement constitutes compliance with this limit. 14.0

LIMIT Minn. R. 7011.1410, subp. 3(C)(2) Opacity: less than or equal to 20 percent opacity except for one six-minute period per hour of not more than 27 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 15.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section
52.21 and Minn. R. 7007.3000; 40 CFR pt. 98, subp. C Use methods in 40 CFR pt. 98, subp. C including flow monitoring of fuel usage and fuel gas analysis. Calculate emissions following procedures specified in 40 CFR pt. 98, subp. C with a conversion from metric tons to short tons. The Permittee shall calculate and record the monthly and 12-month Rolling Sum of CO2e emissions and gross output by the 28th day of each month for the 12-month Rolling Sum periods ending on the last day of the preceding month. 17.0

CD Title I Condition: 40 CFR Section

52.21 and Minn. R. 7007.3000 Fuel Restriction: Authorized to burn pipeline natural gas as defined in 40 CFR Section 72.2 only. (BACT Limit) 18.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Fuel Flowrate: The Permittee shall calibrate, operate and maintain a continuous monitoring system (CMS) that records the fuel flowrate to EU359 and EU360. 19.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Recordkeeping for NOx Emissions: The Permittee shall calculate and record the daily and 365-day Rolling Sum of NOx emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 20.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Recordkeeping for CO Emissions: The Permittee shall calculate and record the daily and 365-day Rolling Sum of CO emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 21.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Compliance with the CO limit indicated by the CO CEMS demonstrates compliance with the VOC limit. The Permittee shall record and compare CO CEMS emissions data during VOC performance testing of GP135, with results of the VOC testing. This compliance demonstration method shall be valid only if testing demonstrates that VOC emissions comply with the applicable VOC limit at the same time that CO emissions (measured by the CO CEMS) comply with the applicable CO limit, and the CO CEMS certification testing has been satisfactorily completed. 22.0

CD Title I Condition: 40 CFR Section
52.21 and Minn. R. 7007.3000; 40

CFR Section 72.2 Recordkeeping: The Permittee shall maintain records verifying use of pipeline natural gas as defined in 40 CFR Section 72.2. Normal business records may be utilized for this purpose. 23.0

CD 40 CFR Section 63.6095(d); Minn.

R. 7011.8120 The Permittee must comply with the Initial Notification requirements set forth in 40 CFR Section 63.6145 but need not comply with any other requirements of 40 CFR pt. 63, subp. YYYY until EPA takes final action to require compliance and publishes a document in the Federal Register. 24.0

CD hdr C. CEMS REQUIREMENTS FOR CO AND NOx 25.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R. 7007.3000; 40 CFR Section 60.4340(b)(1) The Permittee shall install, calibrate, operate and maintain NOx and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and Appendix F. 26.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 The Permittee shall install, operate, and maintain CO and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and Appendix F. 27.0

CD CAAA of 1990; Minn. R.
7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a NOx continuous emissions monitoring system (CEMS). 28.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a CO continuous emissions monitoring system (CEMS). 29.0

CD Minn. R. 7017.1006 CO and NOx Emissions Measuring: The Permittee shall use a CO CEMS and NOx

CEMS to measure CO and NOx emissions from SV 189. 30.0

CD Minn. R. 7017.1160, subps. 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 31.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 32.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 33.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix B and Appendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 34.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 35.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 36.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 37.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 38.0

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp 10(A)-(C) Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 39.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 40.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 41.0

CD hdr D. CMS REQUIREMENT 42.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 43.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 44.0

CD hdr E. O2 MONITOR REQUIREMENTS 45.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 46.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 47.0

CD hdr F. MONITORING REQUIREMENTS 48.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.4345(a) Each NOx diluent CEMS must be installed and certified according to Performance Specification 2 (PS 2) in 40 CFR pt. 60, Appendix B, except the 7-day calibration drift is based on unit operating days, not calendar days. With state approval, Procedure 1 in 40 CFR pt. 60, Appendix F is not required. Alternatively, a NOx diluent CEMS that is installed and certified according to 40 CFR pt. 75, Appendix A is acceptable for use. The relative accuracy test audit (RATA) of the CEMS shall be performed on a lb/mmBtu basis. 49.0

CD 40 CFR Section 60.4345(b) A s specified in 40 CFR Section 60.13(e)(2), during each full unit operating hour, both the NOx monitor and the diluent monitor must complete a minimum of one cycle of operation (sampling, analyzing and data recording) for each 15-minute quadrant of the hour, to validate the hour. For partial unit operating hours, at least one valid data point must be obtained with each monitor for each quadrant of the hour in which the unit operates. For unit operating hours in which required quality assurance and maintenance activities are performed on the CEMS, a minimum of two valid data points (one in each of two quadrants) are required for each monitor

to validate the NOx emission rate for the hour. 50.0

CD 40 CFR Section 60.4345(c) Each fuel flowmeter shall be installed, calibrated, maintained and operated according to the manufacturer's instructions. Alternatively, with state approval, fuel flowmeters that meet the installation, certification and quality assurance requirements of 40 CFR pt. 75, Appendix D are acceptable for use. 51.0

CD 40 CFR Section 60.4345(d) Each watt meter, steam flow meter and each pressure or temperature measurement device shall be installed, calibrated, maintained and operated according to the manufacturer's instructions. 52.0

CD 40 CFR Section 60.4345(e) The Permittee shall develop and keep on-site a quality assurance (QA) plan for all of the continuous monitoring equipment described in 40 CFR Section 60.4345(a), (c) and (d). For the CEMS and fuel flow meters, the Permittee may, with state approval, satisfy the requirements of 40 CFR Section 60.4345(e) by implementing the QA program and plan described in section 1 of 40 CFR pt. 75, Appendix B. 53.0

CD 40 CFR Section 60.4350(h) For combined cycle and combined heat and power units with heat recovery, use the calculated hourly average emission rates from 40 CFR Section 60.4350(f) to assess excess emissions on a 30 unit operating day rolling average basis, as described in 40 CFR Section 60.4380(b)(1). 54.0

CD 40 CFR Section 60.4360 The Permittee must monitor the total sulfur content of the fuel being fired in EU359, except as provided in 40 CFR Section 60.4365. The sulfur content of the fuel must be determined using total sulfur methods described in 40 CFR Section 60.4415.

A lternatively, if the total sulfur content of the gaseous fuel during the most recent performance test was less than half the applicable limit, ASTM D4084, D4810, D5504 or D6228, or Gas Processors Association Standard 2377 (all of which are incorporated by reference, see 40 CFR Section 60.17), which measure the major sulfur compounds, may be used. 55.0

CD 40 CFR Section 60.4365 The Permittee may elect not to monitor the total sulfur content of the fuel combusted in EU359, if the fuel is demonstrated not to exceed potential sulfur emissions of 26 ng SO2/J (0.060 lb SO2/mmBtu) heat input for units located in continental areas and 180 ng SO2/J (0.42 lb SO2/mmBtu) heat input for units

located in noncontinental areas or a continental area that the Administrator determines does not have access to natural gas and that the removal of sulfur compounds would cause more environmental harm than benefit. The Permittee must use one of the following sources of information to make the required

demonstration: (continued below) 56.0

CD 40 CFR Section 60.4365(a) (continued from above) (a) The fuel quality characteristics in a current, valid purchase contract, tariff sheet or transportation contract for the fuel, specifying that the maximum total sulfur content for oil use in continental areas is 0.05 weight percent (500 ppmw) or less and 0.4 weight percent (4000 ppmw) or less for noncontinental areas, the total sulfur content for natural gas use in continental areas is 20 grains of sulfur or less per 100 standard cubic feet and 140 grains of sulfur or less per 100 standard cubic feet for noncontinental areas, has potential sulfur emissions of less than 26 ng SO2/J (0.060 lb SO2/mmBtu) heat input for continental areas and has potential sulfur emissions of less than 180 ng SO2/J (0.42 lb SO2/mmBtu) heat input for
noncontinental areas; or (continued below) 57.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.4365(b) (continued from above) (b) Representative fuel sampling data which show that the sulfur content of the fuel does not exceed 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input for continental areas or 180 ng SO2/J (0.42 lb SO2/MMBtu) heat input for noncontinental areas. At a minimum, the amount of fuel sampling data specified in section 2.3.1.4 or 2.3.2.4 of appendix D to part 75 of this chapter is required. 58.0

CD 40 CFR pt. 60, subp. KKKK Table

1 The Permittee shall install, calibrate and maintain an ambient temperature monitor per manufacturer's instruction. Alternatively, the Permittee may rely on National Weather Service temperature data from Minneapolis St. Paul International Airport to determine applicable NOx concentration requirement under 40 CFR pt. 60, subp.

KKKK Table 1. 59.0

CD 40 CFR Section 60.13(a); Minn. R.

7017.1010 A ll continuous monitoring systems (CMS) required under 40 CFR pt. 60, subp. KKKK shall be subject to the provisions of this section upon promulgation of performance specifications for CMS under 40 CFR pt. 60, Appendix B and, if the CMS is used to demonstrate compliance with emission limits on a continuous basis, 40 CFR pt. 60, Appendix F, unless otherwise specified in an applicable subpart or by the Administrator. 60.0

CD 40 CFR Section 60.13(b); Minn. R.

7017.1010 A ll continuous monitoring systems and monitoring devices shall be installed and operational prior to conducting performance tests under 40 CFR Section 60.8. Verification of operational status shall, as a minimum, include completion of the manufacturer's written requirements or recommendations for installation, operation

and calibration of the device. 61.0

CD 40 CFR Section 60.13(c)(2); Minn.

R. 7017.1010 Except as provided in 40 CFR Section 60.13(c)(1), the Permittee shall furnish the

A dministrator within 60 days of completion two or, upon request, more copies of a written report of the results of the performance evaluation. 62.0

CD 40 CFR Section 60.13(d)(1); Minn.

R. 7017.1010 The Permittee must check the zero (or low level value between 0 and 20% of span value) and span (50 to 100% of span value) calibration drifts at least once daily in accordance with a written procedure. The zero and span must, as a minimum, be adjusted whenever either the 24-hour zero drift or the 24-hour span drift exceeds two times the limit of the applicable performance specification in 40 CFR pt. 60,

A ppendix B. The system must allow the amount of excess zero and span drift to be recorded and quantified whenever specified. The Permittee must automatically, intrinsic to the opacity monitor, check the zero and upscale (span) calibration drifts at least once daily. For a particular COMS, the acceptable range of zero and upscale calibration materials is as defined in the applicable versions of PS-1 in 40 CFR pt. 60, Appendix B. (continued below) 63.0

CD 40 CFR Section 60.13(d)(1); Minn.

R. 7017.1010 (continued from above) For a COMS, the optical surfaces, exposed to the effluent gases, must be cleaned before performing the zero and upscale drift adjustments, except for systems using automatic zero adjustments. The optical surfaces must be cleaned when the cumulative automatic zero compensation exceeds 4% opacity. 64.0

CD 40 CFR Section 60.13(e); Minn. R.

7017.1010 Except for system breakdowns, repairs, calibration checks and zero and span adjustments required under 40 CFR Section 60.13(d), all continuous monitoring systems shall be in continuous operation and shall meet minimum frequency of operation requirements as follows:

A ll CMS referenced by 40 CFR Section 60.13(c) for measuring emissions, except opacity, shall complete a minimum of one cycle of operation (sampling, analyzing and data recording) for each successive 15-minute period. 65.0

CD 40 CFR Section 60.13(f); Minn. R.

7017.1010 A ll continuous monitoring systems or monitoring devices shall be installed such that representative measurements of emissions or process parameters from the affected facility are obtained. Additional procedures for location of continuous monitoring systems contained in the applicable Performance Specifications of 40 CFR pt. 60, Appendix B shall be used. 66.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.13(h)(2)(i)-(iii);

Minn. R. 7017.1010 i) Except as provided under 40 CFR Section 60.13(h)(2)(iii), for a full operating hour (any clock hour with 60 minutes of unit operation), at least four valid data points are required to calculate the hourly average, i.e. one data point in each of the 15-minute quadrants of the hour. ii) Except as provided under 40 CFR Section 60.13(h)(2)(iii), for a partial operating hour (any clock hour with less than 60 minutes of unit operation), at least one valid data point in each 15-minute quadrant of the hour in which the unit operates is required to calculate the hourly average. iii) For any operating hour in which required maintenance or quality assurance activities are performed:

A ) If the unit operates in two or more quadrants of the hour, a minimum of two valid data points, separated by at least 15 minutes, is required to calculate the hourly

average, or B) If the unit operates in only one quadrant of the hour, at least one valid data point is required to calculate the hourly average. 67.0

CD 40 CFR Section 60.13(h)(2)(iv)-(vii); Minn. R.

7017.1010 iv) If a daily calibration error check is failed during any operating hour, all data for that hour shall be invalidated, unless a subsequent calibration error test is passed in the same hour and the requirements of 40 CFR Section 60.13(h)(2)(iii) are met, based solely on valid data recorded after the successful calibration. v) For each full or partial operating hour, all valid data points shall be used to calculate the hourly average. vi) Except as provided under 40 CFR Section 60.13(h)(2)(vii), data recorded during periods of continuous monitoring system breakdown, repair, calibration checks and zero and span adjustments shall not be included in the data averages computed under this paragraph. vii) Permittees complying with the requirements of 40 CFR Section 60.7(f)(1) or (2) must include any data recorded during periods of monitor breakdown or malfunction in the data averages. 68.0

CD 40 CFR Section 60.13(h)(2)(viii)-(ix); Minn. R.

7017.1010 viii) When specified in an applicable subpart, hourly averages for certain partial operating hours shall not be computed or included in the emission averages (e.g. hours with < 30 minutes of unit operation under 40 CFR Section 60.47b(d)). ix) Either arithmetic or integrated averaging of all data may be used to calculate the hourly averages. The data may be recorded in reduced or nonreduced form (e.g. ppm pollutant and percent O2 or ng/J of pollutant). 69.0

CD 40 CFR Section 60.13(h)(3); Minn.

R. 7017.1010 A ll excess emissions shall be converted into units of the standard using the applicable conversion procedures specified in the applicable subpart. After conversion into units of the standard, the data may be rounded to the same number of significant digits used in the applicable subpart to specify the emission limit. 70.0

CD hdr G. PERFORMANCE TESTING REQUIREMENTS 71.0

S/A Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.
7007.3000; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to measure VOC emissions. The performance test shall establish a lb/mmBtu emission factor for VOC to calculate annual emissions for emissions inventory purposes. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 18, 25A or 320, or other method approved by MPCA in the performance test plan approval. 72.0

S/A Title I Condition: 40 CFR Section
52.21 and Minn. R. 7007.3000; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to measure PM10 emissions. The test shall occur at or near maximum heat input and load conditions, consisting of at least 3 test runs each with a duration of at least 60 minutes. The number and duration of the test runs may be extended at the Permittee's discretion to a maximum of 6 test runs and 240 minutes per run to account for variability in test results from low PM concentrations in exhaust gas stream. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. 73.0

S/A Title I Condition: 40 CFR Section
52.21 and Minn. R. 7007.3000; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to measure PM2.5 emissions. The test shall occur at or near maximum heat input and load conditions, consisting of at least 3 test runs each with a duration of at least 60 minutes. The number and duration of the test runs may be extended at the Permittee's discretion to a maximum of 6 test runs and 240 minutes per run to account for variability in test results from low PM concentrations in exhaust gas stream. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. 74.0MINNESOTA POLLUTION CONTROL AGENCY

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S/A 40 CFR Section 60.8(a); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to measure NOx

emissions. If a NOx-diluent CEMS is installed and certified under 40 CFR Section 60.4345, the initial performance test required under 40 CFR Section 60.8 may be performed in an alternative manner as described in 40 CFR Section 60.4405. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 7E, or other method approved by MPCA in the performance test plan approval. 75.0

CD 40 CFR Section 60.4405 The initial performance test required under 40 CFR Section 60.8 may be performed in the following alternative manner: a) Perform a minimum of nine RATA reference method runs, with a minimum time per run of 21 minutes, at a single load level, within plus or minus 25% of 100% peak load. The ambient temperature must be greater than 0 deg F during the RATA

runs. b) For each RATA run, concurrently measure the heat input to the unit using a fuel flow meter (or flow meters) and measure the electrical and thermal output from the

unit. c) Use the test data both to demonstrate compliance with the applicable NOx emission limit under 40 CFR Section 60.4320 and to provide the required reference

method data for the RATA of the CEMS described under 40 CFR Section 60.4335. d) Compliance with the applicable emission limit in 40 CFR Section 60.4320 is achieved if the arithmetic average of all of the NOx emission rates for the RATA runs, expressed in ppm or lb/MWh, does not exceed the emission limit. 76.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for VOC emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 77.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for PM10 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 78.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 79.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for NOx emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 80.0

CD hdr H. REPORTING REQUIREMENTS 81.0

CD 40 CFR Section 60.4375 The Permittee must submit reports of excess emissions and monitor downtime, in accordance with 40 CFR Section 60.7(c). Excess emissions must be reported for all periods of unit operation, including start-up, shutdown and malfunction. 82.0

S/A 40 CFR Section 60.7(a)(1); 40 CFR Section 63.9(b)(5)(i); Minn. R. 7019.0100, subp. 1 Notification: due 30 days after Start Of Construction of EU359. A notification of the date construction of EU359 commenced postmarked no later than 30 days after such date. Notification of start of construction is required by 40 CFR Section 60.7(a)(1). 83.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 63.9(b)(5)(ii); Minn. R. 7019.0100, subp. 1 Notification: due 15 days after Startup (actual date) of EU359. 84.0

CD 40 CFR Section 60.7(a)(4); Minn. R. 7019.0100, subp. 1 The Permittee shall submit a notification of any physical or operational change to EU359 or EU360 which increases emission rate: due 60 days (or as soon as practical) before the change is commenced. 85.0

S/A 40 CFR Sections 60.7(a)(5) and 60.13(c); Minn. R. 7019.0100, subp. 1; Minn. R. 7017.1010 Notification: due 30 days before Startup of the continuous monitoring system (CMS) in accordance with 40 CFR Section 60.13(c). 86.0

CD 40 CFR Section 60.7(b); Minn. R. 7019.0100, subp. 1 The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 87.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 179 of 407

CD 40 CFR Section 60.7(c); 40 CFR Section 60.4395; Minn. R. 7019.0100, subp. 1 The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and shall include the information in 40 CFR Section 60.7(c)(1) through (4). 88.0

CD 40 CFR Section 60.7(d); Minn. R. 7019.0100, subp. 1 The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted.

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 89.0

CD 40 CFR Section 60.7(f); Minn. R. 7019.0100, subp. 1 The Permittee shall maintain a file of all measurements, including continuous monitoring system, monitoring device and performance testing measurements; all continuous monitoring system performance evaluations; all continuous monitoring system or monitoring device calibration checks; adjustments and maintenance performed on these systems or devices; and all other information required by 40 CFR pt. 60 recorded in a permanent form suitable for inspection. The file shall be retained for at least two years following the date of such measurements, maintenance, reports and records except as described in paragraphs (1) and (2) of 40 CFR Section 60.7(f). 90.0

CD 40 CFR Section 60.7(g); Minn. R. 7019.0100, subp. 1 If notification substantially similar to that in 40 CFR Section 60.7(a) is required by any other State or local agency, sending the Administrator a copy of that notification will satisfy the requirements of 40 CFR Section 60.7(a). 91.0

CD 40 CFR Section 60.7(h); Minn. R. 7019.0100, subp. 1 Individual subparts of 40 CFR pt. 60 may include specific provisions which clarify or make inapplicable the provisions set forth in this section. 92.0

CD 40 CFR Section 60.11(d); Minn. R.

7017.2015 A t all times, including periods of startup, shutdown and malfunction, the Permittee shall, to the extent possible, maintain and operate any affected facility including associated air pollution control equipment in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures and inspection of the source. 93.0

CD 40 CFR Section 60.11(g); Minn. R.

7017.2015 For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any standard in this part, nothing in this part shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. 94.0

CD 40 CFR Section 63.9(b)(5)(iii);

Minn. R. 7019.0100 Unless the Permittee has requested and received prior permission from the

A dministrator to submit less than the information in 40 CFR Section 63.5(d), the notification must include the information required on the application for approval of construction as specified in 40 CFR Section 63.5(d)(1)(i). 95.0

CD 40 CFR Section 63.10(b); Minn. R.

7019.0100 The Permittee shall maintain files of all information required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, on computer floppy disks, on magnetic tape disks or on microfiche. 96.0

CD 40 CFR Section 63.6145(a); Minn.

R. 7011.8120 The Permittee must submit all of the notifications in 40 CFR Sections 63.7(b) and (c), 63.8(e), 63.8(f)(4) and 63.9(b) and (h) that apply by the dates specified. 97.0

CD 40 CFR Section 63.6145(c); Minn.

R. 7011.8120 A s specified in 40 CFR Section 63.9(b), the Permittee must submit an Initial Notification not later than 120 days after becoming subject to 40 CFR pt. 63, subp.

YYYY. 98.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 180 of 407

Subject Item: GP 136 Sour Water Tanks

Associated Items: TK 586 Sour Water

TK 587 Sour Water

TK 588 Sour Water

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Volatile Organic Compounds: less than or equal to 28.0 tons/year using 12-month Rolling Sum effective upon startup of TK586, TK587 or 588, whichever is first, as part of the Tier 3 Clean Fuels Projects permit.

For the first 11 months after the limit is effective, VOC emissions are limited as determined by the following equation:

E = 28.0 x [0.15 + 0.85(M/12)]

where

E = emissions in tons

M = number of months after limit is effective 2.0

CD hdr CALCULATIONS AND RECORDKEEPING 3.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Emissions at these tanks shall be calculated both for normal operations with the floating roof and for planned maintenance and cleaning activities when the floating roof is not resting on the liquid surface. If a carbon adsorption system is used to control VOC emissions during periods of planned maintenance or cleaning activities and if the Permittee complies with the carbon system breakthrough demonstration requirements in GP102, then actual emissions calculated during these periods for purposes of compliance with the limit above shall be reduced to reflect a level of control consistent with 40 CFR pt. 61, subp. FF, although these tank controls are not required by 40 CFR pt. 61, subp. FF. 4.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the 12-month Rolling Sum of VOC emissions by the 28th day of each month for the preceding month. Unless a different emission factor is developed by the Permittee and approved by the MPCA in accordance with Minn. R. 7019.3040 - 7019-3100, emissions shall be

calculated as follows:

1) During normal operation with the floating roof and during planned standing idle and filling/refilling activities when the roof is not resting on the liquid surface, emissions shall be calculated using the equations in EPA AP-42, Chapter 7,

November 2006. (continued below) 5.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 and Minn. R.

7007.3000 (continued from above) 2) During planned tank degassing activities when the roof is not resting on the liquid surface, emissions shall be calculated using the equations in the American Petroleum Institute (API) Technical Report 2568, Evaporative Loss from the Cleaning of Storage Tanks, November 2007. If a carbon system is used for emissions control and the Permittee demonstrates compliance with the carbon system breakthrough requirements in GP102, then the calculated emissions shall be reduced to a level of control consistent with 40 CFR pt. 61, subp. FF. 6.0

CD hdr REPORTING REQUIREMENTS (See Table B) 7.0

S/A 40 CFR Section 60.7(a)(1); Minn.

R. 7019.0100 Notification: due 30 days after Start Of Construction of TKs 586, 587 and 588. A notification of the date construction of TKs 586, 587 and 588 commenced postmarked no later than 30 days after such date. Notification of start of construction is required by 40 CFR Section 60.7(a)(1). 8.0

S/A 40 CFR Section 60.7(a)(3); Minn.

R. 7019.0100 Notification: due 15 days after Startup (actual date) of TKs 586, 587 and 588. A notification of the date of startup of TKs 586, 587 and 588 postmarked no later than 15 days after such date. Notification of startup is required by 40 CFR Section 60.7(a)(3). 9.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 181 of 407

Subject Item: SV 042 #5 SRU 26 Unit Stack

Associated Items: EU 045 #5 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 047 SRU 5 Sulfur Pit - Sulfur Recovery Unit

EU 235 26H21 Standby Incinerator for TGTU #2 By passes & SRU5 Sulfur Degassing - Incinerator

EU 236 26H40 TGTU #2 - Refining Equipment

EU 237 26H41 TGTU #2 Incinerator - Incinerator

GP 112 Sulfur Recovery Units

MR 036 TGTU2 SO2 Analyzer - 26H21

MR 037 TGTU2 O2 Analyzer - 26H21

MR 040 Flow for Meter TGTU2 - 26H21

MR 041 26H-21 Fuel Gas Flow

MR 042 EMRC Temperature Thermocouple for TGTU2

MR 114 TGTU2 CO Analyzer

NC/

CA Type Citation Requirement

CD Minn. R. 7007.0800, subp. 2 Requirements from 40 CFR pt. 60, subp. Ja become effective upon startup of

EU361. 1.0

CD hdr EMISSION LIMITS AND OPERATING REQUIREMENTS 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 170.8 lbs/hour using 3-hour Rolling Average .

The Permittee shall use CEMS to monitor the sulfur dioxide emissions in order to calculate pounds of sulfur dioxide per hour (lb/hr). 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 93.6 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 409.8 tons/year using 12-month Rolling

A verage 5.0

LIMIT 40 CFR Section 63.1568(a)(1); 40 CFR Section 63.1568(c)(1); Minn.

R. 7011.7280 Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry, 0% oxygen), using 12-hour Rolling Average. Limit does not apply during periods of startup, shutdown, or malfunction. Applicability of NSPS subp. J and Minn. R. 7011.1435 expires after startup of EU361. 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 170.8 lbs/hour using 1-Hour Average . This is a state-only requirement and pursuant to the Minn. R. 7007.1750, it is not enforceable by the EPA administrator or citizens under the Clean Air Act. 7.0

LIMIT 40 CFR Section 60.102a(f)(1)(i) Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry basis) at zero percent excess air, using 12-hour Rolling Average. 8.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 9.70 lbs/hour using 365-day Rolling Average for SV 042 (BACT Limit) 9.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 50 parts per million using 24-hour Rolling

A verage by volume dry corrected to 7 percent oxygen for SV 042. The limit does not apply during periods of startup or shutdown. (BACT Limit) 10.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 121.0 tons/year using 365-day Rolling Sum . Emissions from acid gas flaring incidents are not included in the calculation of emissions against this limit. 11.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies only to fuel gas combusted in the SRU/TGTU, not to SRU process/waste gases per EPA guidance. This limit does not apply during periods of startup, shutdown, or

malfunction. 12.0

LIMIT Minn. R. 7011.0715, subp. 1(B) Opacity: less than or equal to 20 percent opacity 13.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 182 of 407

CD 40 CFR Section 60.102a(f)(3) Periods of maintenance of the sulfur pit, during which the emission limits in 40 CFR Section 60.102a(f)(1) shall not apply, shall not exceed 240 hours per year. The Permittee must document the time periods during which the sulfur pit vents were not controlled and measures taken to minimize emissions during these periods. Examples of these measures include not adding fresh sulfur or shutting off vent

fans. 14.0

CD 40 CFR Section 60.103a(e)(1) A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). 15.0

CD 40 CFR Section 60.103a(e)(2) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable. 16.0

CD hdr MONITORING REQUIREMENTS 17.0

CD 40 CFR Section 60.106a(a)(1)(i)-(ii) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0% excess air) of any SO2 emissions into the atmosphere. The monitor shall include an oxygen monitor for correcting the data for excess air. i) The span values for this monitor are two times the applicable SO2 emission limit

and between 10 and 25% O2 inclusive. ii) The Permittee shall install, operate and maintain each SO2 CEMS according to Performance Specification 2 of 40 CFR pt. 60, appendix B. 18.0

CD 40 CFR Section 60.106a(a)(1)(iii) iii) The Permittee shall conduct performance evaluations of each SO2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of 40 CFR pt. 60, appendix B. The Permittee shall use Method 6 or 6C of appendix A-4 and Method 3 or 3A of appendix A-2 to 40 CFR pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6. 19.0

CD hdr CALCULATIONS AND RECORDKEEPING REQUIREMENTS 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SIP SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SIP SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 22.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 BACT NOx Emission Calculations and Recordkeeping: The Permittee shall calculate and record the SV 042 24-hour rolling average NOx emissions in ppmvd, and the SV 042 365-day rolling average NOx emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 23.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 CO Emission Calculation and Recordkeeping: The Permittee shall maintain record and calculate the 365-day rolling sum CO emissions of total stack emissions in tons/year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD 40 CFR Section 60.107 SO2 Concentration Recordkeeping for NSPS Limit: The Permittee shall record on an hourly average of SO2 in ppm (dry, 0% oxygen). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 25.0

CD 40 CFR Section 60.103a(c)(3) The Permittee shall conduct a root cause analysis and a corrective action analysis each time the SO2 emissions are more than 227 kg (500 lb) greater than the

amount that would have been emitted if the SO2 or reduced sulfur concentration was equal to the applicable emissions limit in 40 CFR Section 60.102a(f)(1) during one or more consecutive periods of excess emissions or any 24-hour period,

whichever is shorter. 26.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 183 of 407

CD 40 CFR Section 60.103a(e)(3) No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed to date, and for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 27.0

CD 40 CFR Section 60.108a(a) The Permittee shall comply with the notification, recordkeeping and reporting requirements in 40 CFR Section 60.7. 28.0

CD 40 CFR Section 60.108a(b) The Permittee shall notify the Administrator of the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee intends to comply. The Permittee shall submit to the Administrator documentation showing that the process heater meets the definition of a co-fired process heater in 40 CFR Section 60.101a. Notifications required by this paragraph shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 29.0

CD 40 CFR Section 60.108a(c)(6) The Permittee shall maintain the following records: Records of discharges greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant in any 24-hour period as required by 40 CFR Section 60.103a(c). The following information shall be recorded no later than 45 days following the end of a discharge exceeding the thresholds: i) A description of the discharge. ii) The date and time the discharge was first identified and the duration of the discharge. iii) The measured or calculated cumulative quantity of gas discharged over the discharge duration. If the discharge duration exceeds 24 hours, record the discharge quantity for each 24-hour period. vi) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, either the measured concentration of reduced sulfur or SO2 discharged to the atmosphere. (continued below) 30.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) vii) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, the cumulative quantity of H2S and SO2 released into the atmosphere. viii) The steps that the Permittee took to limit the emissions during the discharge. ix) The root cause analysis and corrective action analysis conducted as required in 40 CFR Section 60.103a(d), including an identification of the affected facility, the date and duration of the discharge, a statement noting whether the discharge resulted from the same root cause(s) identified in a previous analysis and either a description of the recommended corrective action(s) or an explanation of why corrective action is not necessary under 40 CFR Section 60.103a(e). (continued below) 31.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) x) For any corrective action analysis for which corrective actions are required in 40 CFR Section 60.103a(e), a description of the corrective action(s) completed within the first 45 days following the discharge and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion

dates. 32.0

CD 40 CFR Section 60.108a(d) The Permittee shall submit and excess emissions report for all periods of excess emissions according to the requirements of 40 CFR Section 60.7(c) except that the report shall contain the information specified in 40 CFR Section 60.108a(d)(1) - (7). 1) The date that the exceedance occurred; 2) An explanation of the exceedance; 3) Whether the exceedance was concurrent with a startup, shutdown or malfunction of an affected facility or control system; and 4) A description of the actions taken, if any. 5) The information described in 40 CFR Section 60.108a(c)(6) for all discharges listed in 40 CFR Section 60.108a(c)(6). (continued below) 33.0

CD 40 CFR Section 60.108a(d) (continued from above) 6) For any periods for which monitoring data are not available, any changes made in operation of the emission control system during the period of data unavailability which could affect the ability of the system to meet the applicable emission limit. Operations of the control system and affected facility during periods of data unavailability are to be compared with operation of the control system and affected facility before and following the period of data unavailability. 7) A written statement, signed by a responsible official, certifying the accuracy and completeness of the information contained in the report. 34.0

CD hdr OTHER REQUIREMENTS 35.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 184 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y The Permittee may use SV 042 during periods when tail gas from SRU 5 (EU 045) is bypassing the Tail Gas Recovery Unit #2 (TGTU #2, EU 236 and EU 237). The Permittee shall not shut down the TGTU #2 except as necessary for maintenance or repair. The Permittee shall not bypass the TGTU #2 with tail gas from SRU 5
except: 1) during periods of startup, shutdown, or breakdown (as governed by 40 CFR pt. 60, subp. A) of SRU 5, the TGTU #2 or TGTU #2 incinerator (EU 237), or

2) to prevent a breakdown of the TGTU #2. Sulfur degassing gas may be combusted in the SRU 5 startup incinerator and omitted from SV 042. 36.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 4;

Minn. R. 7011.1435 Monitoring SO2 concentration: The Permittee shall monitor and record the total SRU SO2 emissions (including sulfur degassing and bypasses) at stack ppm (at 0% oxygen). (2001 EPA Consent Decree, as amended) 37.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA as required by 2000 Global Consent Decree. 38.0

CD hdr CEM REQUIREMENTS (SO2, NOx, and CO) 39.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; CAAA of 1990; 40 CFR Section 63.1568(b)(1); Minn. R.

7017.1006 SO2 Emissions Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). 40.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000;

Minn. R. 7017.1006 NOx Emissions Monitoring: The Permittee shall calibrate, operate and maintain NOx Continuous Emissions Monitoring System (CEMS). 41.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7017.1006 CO Emissions Monitoring: The Permittee shall calibrate, operate and maintain CO Continuous Emissions Monitoring System (CEMS). 42.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The Permittee of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60,

A ppendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 43.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 44.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 45.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 46.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 47.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 48.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 49.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2. 50.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 185 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers the CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR 60, App. F, section 3. The plan shall include or reference the manufacturer's spare parts list for the monitor and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 51.0

CD Minn. R. 7007.1130 Recordkeeping: The Permittee must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 52.0

CD hdr O2 MONITOR REQUIREMENTS 53.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for the monitor and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 54.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 55.0

CD hdr PERFORMANCE TESTING REQUIREMENTS 56.0

S/A 40 CFR Section 60.104a(a) and (c); 40 CFR Section 60.8; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup of EU361 to demonstrate initial compliance with each applicable emissions limit in 40 CFR Section 60.102a. The notification requirements of 40 CFR Section 60.8(d) apply to the initial performance test and subsequent performance tests.

Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified in 40 CFR Section 60.104a, except as provided in 40 CFR Section 60.8(b). 57.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for SO2 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 58.0

CD 40 CFR Section 60.104a(h)(1)-(5) The Permittee shall determine compliance with the SO2 emissions limits using the following methods and procedures: 1) Method 1 of 40 CFR pt. 60, Appendix A-1 for sample and velocity traverses. 2) Method 2 of 40 CFR pt. 60, Appendix A-1 for velocity and volumetric flow rate. 3) Method 3, 3A or 3B of 40 CFR pt. 60, Appendix A-2 for gas analysis. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 3B of 40 CFR pt. 60, Appendix A-2. 4) Method 6, 6A or 6C of 40 CFR pt. 60, Appendix A-4 to determine the SO2 concentration. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6 or 6A of 40 CFR pt. 60, Appendix A-4. (continued below) 59.0MINNESOTA POLLUTION CONTROL AGENCY

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 186 of 407

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) 5) Method 15 or 15A of 40 CFR pt. 60, Appendix A-5 or Method 16 of 40 CFR pt. 60, Appendix A-6 to determine the reduced sulfur compounds and H2S concentrations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 15A of 40 CFR pt. 60, Appendix A-5. i) Each run consists of 16 samples taken over a minimum of 3 hours. ii) The Permittee shall calculate the average H2S concentration after correcting for moisture and O2 as the arithmetic average of the H2S concentration for each sample during the run (ppmv, dry basis, corrected to 0% excess air). iii) The Permittee shall calculate the SO2 equivalent for each run after correcting for moisture and O2 as the arithmetic average of the SO2 equivalent of reduced sulfur compounds for each sample during the run (ppmv, dry basis, corrected to 0% excess air). (continued below) 60.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) iv) The Permittee shall use Equation 8 of 40 CFR Section 60.104a(h) to adjust pollutant concentrations to 0% O2 or 0% excess air. 61.0

CD hdr REPORTING REQUIREMENTS 62.0

CD 40 CFR Section 60.103a(d) The Permittee shall conduct a root cause analysis and corrective action analysis as soon as possible, but no later than 45 days after a discharge exceeding 500 lb greater than the permit limit. 63.0

CD 40 CFR Section 60.103a(d)(1) If a single continuous discharge exceeds 500 lb greater than the permit limit for 2 or more consecutive 24-hour periods, a single root cause analysis and corrective action analysis may be conducted. 64.0

CD 40 CFR Section 60.106a(b)(1) Excess emissions reports required for all 12-hour periods during which the average concentration of SO2 as measured by the SO2 continuous monitoring system required under 40 CFR Section 60.106a(a)(1) exceeds the applicable emission limit (dry basis, 0% excess air). 65.0

CD 40 CFR Section 60.7(b); Minn. R.

7019.0100 The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 66.0

CD 40 CFR Section 60.7(c); Minn. R.

7019.0100 The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 67.0

CD 40 CFR Section 60.7(d); Minn. R.

7019.0100 The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 68.0

CD 40 CFR Section 60.7(f); Minn. R.

7019.0100 The Permittee shall maintain a file of all measurements, including continuous monitoring system (CMS), monitoring device and performance testing measurements; all CMS performance evaluations; all CMS or monitoring device calibration checks; adjustments and maintenance performed on these systems or devices; and all other information required by 40 CFR pt. 60 recorded in a permanent form suitable for inspection. The file shall be retained for at least two years following the date of such measurements, maintenance, reports and records, except as follows: 69.0

CD 40 CFR Section 60.7(f)(1); Minn.

R. 7019.0100 A n automated CEMS records and reduces the measured data to the form of the pollutant emission standard through the use of a computerized data acquisition system. In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain the most recent consecutive three averaging periods of subhourly measurements and a file that contains a hard copy of the data acquisition system algorithm used to reduce the measured data into the reportable form of the standard. 70.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 187 of 407

CD 40 CFR Section 60.7(f)(2); Minn.

R. 7019.0100 In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain all subhourly measurements for the most recent reporting period. The subhourly measurements shall be retained for 120 days from the date of the most recent summary or excess emission report

submitted to the Administrator. 71.0

CD 40 CFR Section 60.7(g); Minn. R.

7019.0100 If notification substantially similar to that in 40 CFR Section 60.7(a) is required by any other State or local agency, sending the Administrator a copy of that notification will satisfy the requirements of 40 CFR Section 60.7(a). 72.0

CD 40 CFR Section 60.7(h); Minn. R.

7019.0100 Individual subparts of 40 CFR pt. 60 may include specific provisions which clarify or make inapplicable the provisions set forth in this section. 73.0

CD 40 CFR Section 60.11(d); Minn. R.

7017.2015 A t all times, including periods of startup, shutdown and malfunction, the Permittee shall, to the extent possible, maintain and operate any affected facility including associated air pollution control equipment in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures and inspection of the source. 74.0

CD 40 CFR Section 60.11(g); Minn. R.

7017.2015 For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any standard in this part, nothing in this part shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. 75.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 188 of 407

Subject Item: SV 066 32H5 6 7 Stack

Associated Items: EU 073 Powerformer Reactor Charge Heater (Grouped with EU 073/074/075) - Process Heater

EU 074 Powerformer Reactor #1 Reheat Heater(Grouped with EU 073/074/075) - Process Heater

EU 075 Powerformer Reactor #2 Reheat Heater( (Grouped with EU 073/074/075) - Process Heater

MR 064 32H5,6,7 O2 Analyzer for NOx

MR 125 32H-5 Fuel Gas Flowmeter

MR 126 32H-6 Fuel Gas Flowmeter

MR 127 32H-7 Fuel Gas Flowmeter

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 16.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 29.6 tons/year using 365-day Rolling Sum (EU 073, EU 074 and EU 075) 6.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended). Although, the limit applies to each heater, compliance demonstration will be determined at the stack

level. 7.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 23.7 tons/year using 365-day Rolling Sum 8.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1490, subp. 2; (most stringent; meet limits set by Minn. R. 7011.1410, subp. 3) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (Limit applies to each unit) 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average (limit applies to each unit). Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average , except for one six-minute period per hour of not more than 60 percent opacity (limit applies to each unit). Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 189 of 407

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 117.6 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher heat input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in each unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD hdr MONITORING REQUIREMENTS 17.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 4 Monitoring for NOx and CO emissions: The Permittee shall continuously monitor

fuel combustion rate and stack O2. The Permittee shall use the most recent performance test correlation to determine NOx and CO lb/MMBtu emissions on an hourly basis. 18.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 19.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 3-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 3-hour period. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 20.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 NOx and CO Calculations and Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling sum NOx and CO emissions from EU 073, EU 074 and EU 075. NOx emissions shall be calculated using 0.045 lb/mmBtu, unless a different emission factor is developed by the Permittee and approved by the MPCA

in accordance with Minn. Rs. 7019.3040 to 7019.3100. CO emissions shall be based on fuel combustion rate and lb/MMBtu emissions. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, it is not enforceable by the EPA administrator or citizens under the

Clean Air Act. 23.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD hdr CMS REQUIREMENTS 25.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall operate, and maintain continuous monitoring system (CMS) that record the fuel flowrate at each fuel combustion device. 26.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 27.0

CD hdr O2 MONITOR REQUIREMENTS 28.0

CD Minn. R. 7007.0800, subp. 4 QA Plan Firebox O2: The Permittee shall operate, and maintain a CMS that

records the O2 in the common convection section at 32H-5/6/7. 29.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability, including but not limited to annual calibrations. 30.0

CD hdr PERFORMANCE TEST REQUIREMENTS 31.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 190 of 407

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 03/03/2014 for NOx emissions. Testing conducted during the two months prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required by: 1) this permit, 2) by the most recently approved Performance Test Frequency Plan, or 3) if specified within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date does not satisfy this test due date requirement and will

be considered an additional test.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 32.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 03/03/2014 for CO emissions. Testing conducted during the two months prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required by: 1) this permit, 2) by the most recently approved Performance Test Frequency Plan, or 3) if specified within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date does not satisfy this test due date requirement and will

be considered an additional test.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 33.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 191 of 407

Subject Item: SV 082 37H1 2 6 Stack

Associated Items: EU 093 Naphtha Hydrotreater Charge Heater - Process Heater

EU 094 Naphtha Hydotreater Stripper Reboiler - Boiler

EU 098 Platformer Stabilizer Reboiler Heater - Process Heater

MR 133 37H-1 Fuel Gas Flowmeter

MR 134 37H-2 Fuel Gas Flowmeter

MR 138 37H6 Fuel Gas Flowmeter

MR 169 37H1 2 6 O2 Analyzer for NOx

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 17.7 tons/year using 365-day Rolling Sum effective upon startup of EU 324 (25H-4). 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.9 lbs/hour using 3-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.9 lbs/hour using 24-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 24.3 tons/year using 12-month Rolling Average 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 6.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 7.0

CD hdr OTHER LIMITS AND REQUIREMENTS 8.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery fuel gas and natural gas only. 9.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 65.5 million Btu/hour using 8-hour Block Average for NOx emissions based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher heat input unless a performance test is conducted at a higher rate and MPCA staff determine compliance at that rate for

the emission unit. 10.0

CD Minn. R. 7007.0800, subp. 5 Daily Recordkeeping: Record and maintain records of the type and amount of each fuel combusted in each heater on a daily basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0

CD hdr MONITORING REQUIREMENT 12.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Monitoring for NOx Emissions: The Permittee shall continuously monitor fuel combustion rate. The Permittee shall use the most recent performance test to demonstrate compliance with the lb/MMBtu and tons/year emission limits. 13.0

CD hdr RECORDKEEPING 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 192 of 407

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 NOx Calculations and Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling sum NOx emissions from EU 093, EU 094 and EU 098.

NOx emissions based on fuel combustion rate and lb/MMBtu emissions. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr CMS REQUIREMENTS 18.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall operate, and maintain a continuous monitoring system (CMS) at each fuel combustion device that records the fuel flow rate. 19.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 20.0

CD hdr PERFORMANCE TESTING REQUIREMENT 21.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 06/19/2012 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 22.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 193 of 407

Subject Item: SV 083 37H3 4 5 Stack

Associated Items: EU 095 Platformer Charge Heater (Gr ouped with EU 095/096/097) - Process Heater

EU 096 Platformer #1 Interheater(Grouped with EU 095/096/097) - Process Heater

EU 097 Platformer #2 Interheater(Grouped with EU 095/096/097) - Process Heater

MR 130 37H-3/4/5 NOx Analyzer

MR 131 37H-3/4/5 CO Analyzer

MR 132 37 O2 Percent

MR 135 37H4 Fuel Gas Flowmeter

MR 136 37H5 Fuel Gas Flowmeter

MR 137 37H3 Fuel Gas Flowmeter

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 50 tons/year using 365-day Rolling Sum 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 30.1 lbs/hour using 3-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 30.1 lbs/hour using 24-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 105.6 tons/year using 12-month Rolling

A verage 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 30.1 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 7.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R.

7011.1435 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE of each heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction constitutes compliance with

this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity ; except for one six-minute period per hour of not more than 60 percent opacity. (Limit applies to each unit). Compliance with the fuel restriction requirement constitutes compliance with this

limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery fuel gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 194 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 15.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 16.0

CD hdr CEM REQUIREMENTS FOR NOx 17.0

CD Title I Condition: CAAA of 1990;
Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain NOx continuous emissions monitoring system (CEMS). 18.0

CD Minn. R. 7017.1160, subps 1,2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 19.0

CD hdr CEM REQUIREMENTS FOR CO 20.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain CO continuous emissions monitoring system (CEMS). 21.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Measuring: The Permittee shall use a CO CEMS to measure CO

emissions from SV 083. 22.0

CD Minn. R. 7017.1160, subps 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 23.0

CD hdr REQUIREMENTS FOR ALL CEMS 24.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 25.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 26.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 27.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar half-year following Cylinder Gas Audit 28.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 29.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 30.0

CD Minn. R. 7017.1090, subps. 1 and

2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 195 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 32.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 33.0

CD hdr O2 MONITOR REQUIREMENTS 34.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix. F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 35.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 36.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 196 of 407

Subject Item: SV 093 45H61 Stack

Associated Items: EU 111 #3 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 112 #4 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 113 SRU 3 Sulfur Pit - Sulfur Recovery Unit

EU 114 SRU 4 Sulfur Pit - Sulfur Recovery Unit

EU 260 Incinerator for SRU4 Bypasses of TGTU1 SRU3 /4 Sulfur Degassing SW TK Purge Gassing - Incinerator

GP 112 Sulfur Recovery Units

MR 078 EMRC Temperature Thermocouple for TGTU1

MR 083 TGTU1 O2 Analyzer - 45H61

MR 084 TGTU1 SO2 Analyzer - 45H61

MR 087 45H61 Fuel Gas Flow

MR 090 Flow Meter for TGTU1

MR 139 45 CO ppm

NC/

CA Type Citation Requirement

CD Minn. R. 7007.0800, subp. 2 Requirements from 40 CFR pt. 60, subp. Ja become effective upon startup of

EU361. 1.0

CD hdr EMISSION LIMITS 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 149.0 lbs/hour using 3-hour Rolling Average . The company shall use CEMS to monitor the sulfur dioxide emissions in order to calculate pounds of sulfur dioxide per hour (lb/hr). 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 86.5 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 324.3 tons/year using 12-month Rolling

A verage 5.0

LIMIT 40 CFR Sections 60.8(c), 60.104 and 60.105; 40 CFR Section 63.1568(a)(1); 40 CFR Section 63.1568(c)(1); Minn. R. 7011.1435(A); Minn. R. 7011.7280 Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry, 0% oxygen), using 12-hour Rolling Average. Limit does not apply during periods of startup, shutdown, or malfunction. Applicability of NSPS subp. J and Minn. R. 7011.1435 expires after startup of EU361. 6.0

LIMIT Title I Condition: 40 CFR pt. 51,

A ppendix S Sulfur Dioxide: less than or equal to 200 parts per million (dry, at 0% oxygen) using 12-hour Rolling Average when SRU #3 and SRU #4 operate together or when only SRU #4 operates. This limit was consolidated based on previous limits. While the limit is a LAER limit, the Permittee will comply with the requirements listed in 40 CFR pt. 60, subp. J (or Ja when applicable) for these units (monitoring, recordkeeping and reporting). 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 149.0 lbs/hour using 1-Hour Average . This is a state-only requirement and it is not enforceable by the EPA administrator or

citizens under the Clean Air Act. 8.0

LIMIT 40 CFR Section 60.102a(f)(1)(i) Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry basis) at zero percent excess air, using 12-hour Rolling Average. 9.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 10.0

LIMIT Minn. R. 7011.0715, subp. 1(B) Opacity: less than or equal to 20 percent opacity 11.0

CD 40 CFR Section 60.102a(f)(3) Periods of maintenance of the sulfur pit, during which the emission limits in 40 CFR Section 60.102a(f)(1) shall not apply, shall not exceed 240 hours per year. The Permittee must document the time periods during which the sulfur pit vents were not controlled and measures taken to minimize emissions during these periods. Examples of these measures include not adding fresh sulfur or shutting off vent

fans. 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 197 of 407

CD 40 CFR Section 60.103a(e)(1) A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). 13.0

CD 40 CFR Section 60.103a(e)(2) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable. 14.0

CD hdr MONITORING REQUIREMENTS 15.0

CD 40 CFR Section 60.106a(a)(1)(i)-(ii) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0% excess air) of any SO2 emissions into the atmosphere. The monitor shall include an oxygen monitor for correcting the data for excess air. i) The span values for this monitor are two times the applicable SO2 emission limit

and between 10 and 25% O2 inclusive. ii) The Permittee shall install, operate and maintain each SO2 CEMS according to Performance Specification 2 of 40 CFR pt. 60, appendix B. 16.0

CD 40 CFR Section 60.106a(a)(1)(iii) iii) The Permittee shall conduct performance evaluations of each SO2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of 40 CFR pt. 60, appendix B. The Permittee shall use Method 6 or 6C of appendix A-4 and Method 3 or 3A of appendix A-2 to 40 CFR pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6. 17.0

CD hdr RECORDKEEPING REQUIREMENTS 18.0

CD Title I Condition: 40 CFR pt. 51,

A ppendix S LAER SO2 Concentration Recordkeeping: The Permittee shall record on an hourly average of SO2 in ppm (dry, 0% oxygen). The records may be maintained in either electronic or paper format unless it is expressly prohibited. 19.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SIP SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 20.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5; Minn. R. 7011.1435(A) Total SO2 Emissions Recordkeeping: The Permittee shall calculate and record the total SO2 emissions (including sulfur degassing and bypasses) at stack in ppm (at 0% oxygen). The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SIP SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 22.0

CD 40 CFR Section 60.103a(c)(3) The Permittee shall conduct a root cause analysis and a corrective action analysis each time the SO2 emissions are more than 227 kg (500 lb) greater than the

amount that would have been emitted if the SO2 or reduced sulfur concentration was equal to the applicable emissions limit in 40 CFR Section 60.102a(f)(1) during one or more consecutive periods of excess emissions or any 24-hour period,

whichever is shorter. 23.0

CD 40 CFR Section 60.103a(e)(3) No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed to date, and for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 24.0

CD 40 CFR Section 60.108a(a) The Permittee shall comply with the notification, recordkeeping and reporting requirements in 40 CFR Section 60.7. 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 198 of 407

CD 40 CFR Section 60.108a(b) The Permittee shall notify the Administrator of the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee intends to comply. The Permittee shall submit to the Administrator documentation showing that the process heater meets the definition of a co-fired process heater in 40 CFR Section 60.101a. Notifications required by this paragraph shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 26.0

CD 40 CFR Section 60.108a(c)(6) The Permittee shall maintain the following records: Records of discharges greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant in any 24-hour period as required by 40 CFR Section 60.103a(c). The following information shall be recorded no later than 45 days following the end of a discharge exceeding the thresholds: i) A description of the discharge. ii) The date and time the discharge was first identified and the duration of the discharge. iii) The measured or calculated cumulative quantity of gas discharged over the discharge duration. If the discharge duration exceeds 24 hours, record the discharge quantity for each 24-hour period. vi) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, either the measured concentration of reduced sulfur or SO2 discharged to the atmosphere. (continued below) 27.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) vii) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, the cumulative quantity of H2S and SO2 released into the atmosphere. viii) The steps that the Permittee took to limit the emissions during the discharge. ix) The root cause analysis and corrective action analysis conducted as required in 40 CFR Section 60.103a(d), including an identification of the affected facility, the date and duration of the discharge, a statement noting whether the discharge resulted from the same root cause(s) identified in a previous analysis and either a description of the recommended corrective action(s) or an explanation of why corrective action is not necessary under 40 CFR Section 60.103a(e). (continued below) 28.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) x) For any corrective action analysis for which corrective actions are required in 40 CFR Section 60.103a(e), a description of the corrective action(s) completed within the first 45 days following the discharge and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion

dates. 29.0

CD 40 CFR Section 60.108a(d) The Permittee shall submit and excess emissions report for all periods of excess emissions according to the requirements of 40 CFR Section 60.7(c) except that the report shall contain the information specified in 40 CFR Section 60.108a(d)(1) - (7). 1) The date that the exceedance occurred; 2) An explanation of the exceedance; 3) Whether the exceedance was concurrent with a startup, shutdown or malfunction of an affected facility or control system; and 4) A description of the actions taken, if any. 5) The information described in 40 CFR Section 60.108a(d)(6) for all discharges listed in 40 CFR Section 60.108a(c)(6). (continued below) 30.0

CD 40 CFR Section 60.108a(d) (continued from above) 6) For any periods for which monitoring data are not available, any changes made in operation of the emission control system during the period of data unavailability which could affect the ability of the system to meet the applicable emission limit. Operations of the control system and affected facility during periods of data unavailability are to be compared with operation of the control system and affected facility before and following the period of data unavailability. 7) A written statement, signed by a responsible official, certifying the accuracy and completeness of the information contained in the report. 31.0

CD hdr CEM REQUIREMENTS FOR SO2 AND CO 32.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I Condition: CAAA of 1990; 40 CFR Section 63.1568(b)(1); Minn. R.

7017.1006 SO2 Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 199 of 407

CD 40 CFR Section 63.1568(b)(1);

Minn. R. 7017.1006 CO Emissions Monitoring: The Permittee shall calibrate, operate and maintain CO Continuous Emissions Monitoring System (CEMS). 34.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I Condition CAAA of 1990; 40 CFR Section 63.1568(b)(1); Minn. R.

7017.1006 SO2 Emissions Measuring: The Permittee shall use a SO2 CEMS to measure SO2

emissions from SV 093. 35.0

CD 40 CFR Section 63.1568(b)(1);

Minn. R. 7017.1006 CO Emissions Measuring: The Permittee shall use a CO CEMS to measure CO

emissions from SV 093. 36.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 37.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 38.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 39.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 40.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 41.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 42.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 43.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 44.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 45.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 46.0

CD hdr OTHER REQUIREMENTS 47.0MINNESOTA POLLUTION CONTROL AGENCY

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Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 200 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y The Permittee shall not emit SRU 3 (EU 111) tail gas at SV 094 unless tail gas from SRU 3 is bypassing the SCOT/TGTU #1 Unit (EU 261 and EU 262). The Permittee may use SV 093 during periods when tail gas from SRU 4 (EU 112) is bypassing the SCOT Unit/TGTU #1. The Permittee shall not shut down the SCOT Unit except as necessary for maintenance or repair. The Permittee shall not bypass the SCOT Unit with tailgas from SRU 3 (EU 111) or SRU 4 (EU 112) except:

(1) during periods of startup, shutdown, or breakdown of SRU 3, SRU 4, the SCOT/TGTU #1 Unit, or SCOT incinerator (EU 262); or

(2) to prevent a breakdown of the SCOT Unit. 48.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur degassing gas may be combusted in the SRU 4 (EU 112) startup/bypass incinerator and emitted from SV 094 during instances of startup, shutdown, or

malfunction. 49.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA as required by 2000 Global Consent Decree. 50.0

CD hdr O2 MONITOR REQUIREMENTS 51.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for the monitor and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 52.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 53.0

CD hdr PERFORMANCE TESTING REQUIREMENTS 54.0

S/A 40 CFR Section 60.104a(a) and (c); 40 CFR Section 60.8; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to demonstrate initial compliance with each applicable emissions limit in 40 CFR Section 60.102a. The notification requirements of 40 CFR Section 60.8(d) apply to the initial performance test and subsequent performance tests. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified in 40 CFR Section 60.104a, except as provided in 40 CFR Section 60.8(b). 55.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for SO2 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 56.0

CD 40 CFR Section 60.104a(h)(1)-(5) The Permittee shall determine compliance with the SO2 emissions limits using the following methods and procedures: 1) Method 1 of 40 CFR pt. 60, Appendix A-1 for sample and velocity traverses. 2) Method 2 of 40 CFR pt. 60, Appendix A-1 for velocity and volumetric flow rate. 3) Method 3, 3A or 3B of 40 CFR pt. 60, Appendix A-2 for gas analysis. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 3B of 40 CFR pt. 60, Appendix A-2. 4) Method 6, 6A or 6C of 40 CFR pt. 60, Appendix A-4 to determine the SO2 concentration. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6 or 6A of 40 CFR pt. 60, Appendix A-4. (continued below) 57.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 201 of 407

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) 5) Method 15 or 15A of 40 CFR pt. 60, Appendix A-5 or Method 16 of 40 CFR pt. 60, Appendix A-6 to determine the reduced sulfur compounds and H2S concentrations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 15A of 40 CFR pt. 60, Appendix A-5. i) Each run consists of 16 samples taken over a minimum of 3 hours. ii) The Permittee shall calculate the average H2S concentration after correcting for moisture and O2 as the arithmetic average of the H2S concentration for each sample during the run (ppmv, dry basis, corrected to 0% excess air). iii) The Permittee shall calculate the SO2 equivalent for each run after correcting for moisture and O2 as the arithmetic average of the SO2 equivalent of reduced sulfur compounds for each sample during the run (ppmv, dry basis, corrected to 0% excess air). (continued below) 58.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) iv) The Permittee shall use Equation 8 of 40 CFR Section 60.104a(h) to adjust pollutant concentrations to 0% O2 or 0% excess air. 59.0

CD hdr REPORTING REQUIREMENTS 60.0

CD 40 CFR Section 60.103a(d) The Permittee shall conduct a root cause analysis and corrective action analysis as soon as possible, but no later than 45 days after a discharge exceeding 500 lb greater than the permit limit. 61.0

CD 40 CFR Section 60.103a(d)(1) If a single continuous discharge exceeds 500 lb greater than the permit limit for 2 or more consecutive 24-hour periods, a single root cause analysis and corrective action analysis may be conducted. 62.0

CD 40 CFR Section 60.106a(b)(1) Excess emissions reports required for all 12-hour periods during which the average concentration of SO2 as measured by the SO2 continuous monitoring system required under 40 CFR Section 60.106a(a)(1) exceeds the applicable emission limit (dry basis, 0% excess air). 63.0

CD 40 CFR Section 60.7(b); Minn. R.

7019.0100 The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 64.0

CD 40 CFR Section 60.7(c); Minn. R.

7019.0100 The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 65.0

CD 40 CFR Section 60.7(d); Minn. R.

7019.0100 The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 66.0

CD 40 CFR Section 60.7(f); Minn. R.

7019.0100 The Permittee shall maintain a file of all measurements, including continuous monitoring system (CMS), monitoring device and performance testing measurements; all CMS performance evaluations; all CMS or monitoring device calibration checks; adjustments and maintenance performed on these systems or devices; and all other information required by 40 CFR pt. 60 recorded in a permanent form suitable for inspection. The file shall be retained for at least two years following the date of such measurements, maintenance, reports and records, except as follows: 67.0

CD 40 CFR Section 60.7(f)(1); Minn.

R. 7019.0100 A n automated CEMS records and reduces the measured data to the form of the pollutant emission standard through the use of a computerized data acquisition system. In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain the most recent consecutive three averaging periods of subhourly measurements and a file that contains a hard copy of the data acquisition system algorithm used to reduce the measured data into the reportable form of the standard. 68.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 202 of 407

CD 40 CFR Section 60.7(f)(2); Minn.

R. 7019.0100 In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain all subhourly measurements for the most recent reporting period. The subhourly measurements shall be retained for 120 days from the date of the most recent summary or excess emission report

submitted to the Administrator. 69.0

CD 40 CFR Section 60.7(g); Minn. R.

7019.0100 If notification substantially similar to that in 40 CFR Section 60.7(a) is required by any other State or local agency, sending the Administrator a copy of that notification will satisfy the requirements of 40 CFR Section 60.7(a). 70.0

CD 40 CFR Section 60.7(h); Minn. R.

7019.0100 Individual subparts of 40 CFR pt. 60 may include specific provisions which clarify or make inapplicable the provisions set forth in this section. 71.0

CD 40 CFR Section 60.11(d); Minn. R.

7017.2015 A t all times, including periods of startup, shutdown and malfunction, the Permittee shall, to the extent possible, maintain and operate any affected facility including associated air pollution control equipment in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures and inspection of the source. 72.0

CD 40 CFR Section 60.11(g); Minn. R.

7017.2015 For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any standard in this part, nothing in this part shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. 73.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 203 of 407

Subject Item: SV 094 45H6 Stack

Associated Items: EU 111 #3 Sulfur Recovery Unit (SRU) - Sulfur Recovery Unit

EU 113 SRU 3 Sulfur Pit - Sulfur Recovery Unit

EU 260 Incinerator for SRU4 Bypasses of TGTU1 SRU3 /4 Sulfur Degassing SW TK Purge Gassing - Incinerator

GP 112 Sulfur Recovery Units

MR 079 45H6 Stack Temp

MR 081 45H-6 O2

MR 082 45H-6 SO2

MR 089 45H6 Stack Flow

NC/

CA Type Citation Requirement

CD hdr Requirements from 40 CFR pt. 60, subp. Ja become effective upon startup of

EU361. 1.0

CD hdr EMISSION LIMITS 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 4.5 tons/year using 12-month Rolling Average 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

LIMIT 40 CFR Section 63.1568(a)(1); 40 CFR Section 63.1568(c)(1); Minn.

R. 7011.7280 Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry, 0% oxygen), using 12-hour Rolling Average. Limit does not apply during periods of startup, shutdown or malfunction. Applicability of NSPS subp. J and Minn. R. 7011.1435 expires after startup of EU361. 7.0

LIMIT 40 CFR Section 60.102a(f)(1)(i) Sulfur Dioxide: less than or equal to 250 parts per million by volume (dry basis) at zero percent excess air, using 12-hour Rolling Average. 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; 40 CFR Section 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (Supplemental Fuel Gas) (230 mg/dscm [162ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 9.0

LIMIT Minn. R. 7011.0715, subp. 1(B) Opacity: less than or equal to 20 percent opacity 10.0

CD 40 CFR Section 60.102a(f)(3) Periods of maintenance of the sulfur pit, during which the emission limits in 40 CFR Section 60.102a(f)(1) shall not apply, shall not exceed 240 hours per year. The Permittee must document the time periods during which the sulfur pit vents were not controlled and measures taken to minimize emissions during these periods. Examples of these measures include not adding fresh sulfur or shutting off vent

fans. 11.0

CD 40 CFR Section 60.103a(e)(1) A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). 12.0

CD 40 CFR Section 60.103a(e)(2) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable. 13.0

CD hdr MONITORING REQUIREMENTS 14.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 204 of 407

CD 40 CFR Section 60.106a(a)(1)(i)-(ii) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0% excess air) of any SO2 emissions into the atmosphere. The monitor shall include an oxygen monitor for correcting the data for excess air. i) The span values for this monitor are two times the applicable SO2 emission limit

and between 10 and 25% O2 inclusive. ii) The Permittee shall install, operate and maintain each SO2 CEMS according to Performance Specification 2 of 40 CFR pt. 60, appendix B. 15.0

CD 40 CFR Section 60.106a(a)(1)(iii) iii) The Permittee shall conduct performance evaluations of each SO2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of 40 CFR pt. 60, appendix B. The Permittee shall use Method 6 or 6C of appendix A-4 and Method 3 or 3A of appendix A-2 to 40 CFR pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6. 16.0

CD hdr RECORDKEEPING REQUIREMENTS 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 18.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 19.0

CD Minn. R. 7007.0800, subp. 5 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 20.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5;

Minn. R. 7011.1435.A. Total SO2 Emissions Recordkeeping: The Permittee shall calculate and record the total SO2 emissions (including sulfur degassing and bypasses) at the stack in ppm (at 0% oxygen). The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. (2001 EPA Consent Decree, as amended) 21.0

CD Minn. R. 7007.0800, subp. 5 SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 22.0

CD 40 CFR Section 60.103a(c)(3) The Permittee shall conduct a root cause analysis and a corrective action analysis each time the SO2 emissions are more than 227 kg (500 lb) greater than the

amount that would have been emitted if the SO2 or reduced sulfur concentration was equal to the applicable emissions limit in 40 CFR Section 60.102a(f)(1) during one or more consecutive periods of excess emissions or any 24-hour period,

whichever is shorter. 23.0

CD 40 CFR Section 60.103a(e)(3) No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed to date, and for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 24.0

CD 40 CFR Section 60.108a(a) The Permittee shall comply with the notification, recordkeeping and reporting requirements in 40 CFR Section 60.7. 25.0

CD 40 CFR Section 60.108a(b) The Permittee shall notify the Administrator of the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee intends to comply. The Permittee shall submit to the Administrator documentation showing that the process heater meets the definition of a co-fired process heater in 40 CFR Section 60.101a. Notifications required by this paragraph shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 26.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 205 of 407

CD 40 CFR Section 60.108a(c)(6) The Permittee shall maintain the following records: Records of discharges greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant in any 24-hour period as required by 40 CFR Section 60.103a(c). The following information shall be recorded no later than 45 days following the end of a discharge exceeding the thresholds: i) A description of the discharge. ii) The date and time the discharge was first identified and the duration of the discharge. iii) The measured or calculated cumulative quantity of gas discharged over the discharge duration. If the discharge duration exceeds 24 hours, record the discharge quantity for each 24-hour period. vi) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, either the measured concentration of reduced sulfur or SO2 discharged to the atmosphere. (continued below) 27.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) vii) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, the cumulative quantity of H2S and SO2 released into the atmosphere. viii) The steps that the Permittee took to limit the emissions during the discharge. ix) The root cause analysis and corrective action analysis conducted as required in 40 CFR Section 60.103a(d), including an identification of the affected facility, the date and duration of the discharge, a statement noting whether the discharge resulted from the same root cause(s) identified in a previous analysis and either a description of the recommended corrective action(s) or an explanation of why corrective action is not necessary under 40 CFR Section 60.103a(e). (continued below) 28.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) x) For any corrective action analysis for which corrective actions are required in 40 CFR Section 60.103a(e), a description of the corrective action(s) completed within the first 45 days following the discharge and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion

dates. 29.0

CD 40 CFR Section 60.108a(d) The Permittee shall submit and excess emissions report for all periods of excess emissions according to the requirements of 40 CFR Section 60.7(c) except that the report shall contain the information specified in 40 CFR Section 60.108a(d)(1) - (7). 1) The date that the exceedance occurred; 2) An explanation of the exceedance; 3) Whether the exceedance was concurrent with a startup, shutdown or malfunction of an affected facility or control system; and 4) A description of the actions taken, if any. 5) The information described in 40 CFR Section 60.108a(c)(6) for all discharges listed in 40 CFR Section 60.108a(c)(6). (continued below) 30.0

CD 40 CFR Section 60.108a(d) (continued from above) 6) For any periods for which monitoring data are not available, any changes made in operation of the emission control system during the period of data unavailability which could affect the ability of the system to meet the applicable emission limit. Operations of the control system and affected facility during periods of data unavailability are to be compared with operation of the control system and affected facility before and following the period of data unavailability. 7) A written statement, signed by a responsible official, certifying the accuracy and completeness of the information contained in the report. 31.0

CD hdr CEM REQUIREMENTS FOR SO2 32.0

CD 40 CFR Section 63.1568(b)(1); 40 CFR Section 60.105; Minn. R.
7017.1006; Minn. R. 7011.1435 SO2 Emissions Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). 33.0

CD 40 CFR Section 63.1568(b)(1); 40 CFR Section 60.105; Minn. R.
7017.1006; Minn. R. 7011.1435 SO2 Emissions Measuring: The Permittee shall use a SO2 CEMS to measure SO2

emissions from SV 094. 34.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate and maintain the CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 35.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 206 of 407

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 36.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 37.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 38.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 39.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 40.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 41.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 42.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 43.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format unless it is expressly prohibited. 44.0

CD hdr OTHER REQUIREMENTS 45.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA as required by 2000 Global Consent Decree. 46.0

CD CAAA of 1990; Minn. R. 7007.0800, subp. 5; Minn. R.

7011.1435 Monitoring SRU 3 SO2 concentration: The Permittee shall monitor and record the total SRU 3 SO2 emissions (including sulfur degassing and bypasses) at stack ppm (at 0% oxygen). 47.0

CD hdr O2 MONITOR REQUIREMENTS 48.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for the monitor and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 49.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 207 of 407

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 50.0

CD hdr PERFORMANCE TESTING REQUIREMENTS 51.0

S/A 40 CFR Section 60.104a(a) and (c); 40 CFR Section 60.8; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to demonstrate initial compliance with each applicable emissions limit in 40 CFR Section 60.102a. The notification requirements of 40 CFR Section 60.8(d) apply to the initial performance test and subsequent performance tests. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified in 40 CFR Section 60.104a, except as provided in 40 CFR Section 60.8(b). 52.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for SO2 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the

MPCA. 53.0

CD 40 CFR Section 60.104a(h)(1)-(5) The Permittee shall determine compliance with the SO2 emissions limits using the following methods and procedures: 1) Method 1 of 40 CFR pt. 60, Appendix A-1 for sample and velocity traverses. 2) Method 2 of 40 CFR pt. 60, Appendix A-1 for velocity and volumetric flow rate. 3) Method 3, 3A or 3B of 40 CFR pt. 60, Appendix A-2 for gas analysis. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 3B of 40 CFR pt. 60, Appendix A-2. 4) Method 6, 6A or 6C of 40 CFR pt. 60, Appendix A-4 to determine the SO2 concentration. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6 or 6A of 40 CFR pt. 60, Appendix A-4. (continued below) 54.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) 5) Method 15 or 15A of 40 CFR pt. 60, Appendix A-5 or Method 16 of 40 CFR pt. 60, Appendix A-6 to determine the reduced sulfur compounds and H2S concentrations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 15A of 40 CFR pt. 60, Appendix A-5. i) Each run consists of 16 samples taken over a minimum of 3 hours. ii) The Permittee shall calculate the average H2S concentration after correcting for moisture and O2 as the arithmetic average of the H2S concentration for each sample during the run (ppmv, dry basis, corrected to 0% excess air). iii) The Permittee shall calculate the SO2 equivalent for each run after correcting for moisture and O2 as the arithmetic average of the SO2 equivalent of reduced sulfur compounds for each sample during the run (ppmv, dry basis, corrected to 0% excess air). (continued below) 55.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) iv) The Permittee shall use Equation 8 of 40 CFR Section 60.104a(h) to adjust pollutant concentrations to 0% O2 or 0% excess air. 56.0

CD hdr REPORTING REQUIREMENTS 57.0

CD 40 CFR Section 60.103a(d) The Permittee shall conduct a root cause analysis and corrective action analysis as soon as possible, but no later than 45 days after a discharge exceeding 500 lb greater than the permit limit. 58.0

CD 40 CFR Section 60.103a(d)(1) If a single continuous discharge exceeds 500 lb greater than the permit limit for 2 or more consecutive 24-hour periods, a single root cause analysis and corrective action analysis may be conducted. 59.0

CD 40 CFR Section 60.106a(b)(1) Excess emissions reports required for all 12-hour periods during which the average concentration of SO2 as measured by the SO2 continuous monitoring system required under 40 CFR Section 60.106a(a)(1) exceeds the applicable emission limit (dry basis, 0% excess air). 60.0

CD 40 CFR Section 60.7(b); Minn. R.

7019.0100 The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 61.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 208 of 407

CD 40 CFR Section 60.7(c); Minn. R.

7019.0100 The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 62.0

CD 40 CFR Section 60.7(d); Minn. R.

7019.0100 The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 63.0

CD 40 CFR Section 60.7(f); Minn. R.

7019.0100 The Permittee shall maintain a file of all measurements, including continuous monitoring system (CMS), monitoring device and performance testing measurements; all CMS performance evaluations; all CMS or monitoring device calibration checks; adjustments and maintenance performed on these systems or devices; and all other information required by 40 CFR pt. 60 recorded in a permanent form suitable for inspection. The file shall be retained for at least two years following the date of such measurements, maintenance, reports and records, except as follows: 64.0

CD 40 CFR Section 60.7(f)(1); Minn.

R. 7019.0100 A n automated CEMS records and reduces the measured data to the form of the pollutant emission standard through the use of a computerized data acquisition system. In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain the most recent consecutive three averaging periods of subhourly measurements and a file that contains a hard copy of the data acquisition system algorithm used to reduce the measured data into the reportable form of the standard. 65.0

CD 40 CFR Section 60.7(f)(2); Minn.

R. 7019.0100 In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain all subhourly measurements for the most recent reporting period. The subhourly measurements shall be retained for 120 days from the date of the most recent summary or excess emission report

submitted to the Administrator. 66.0

CD 40 CFR Section 60.7(g); Minn. R.

7019.0100 If notification substantially similar to that in 40 CFR Section 60.7(a) is required by any other State or local agency, sending the Administrator a copy of that notification will satisfy the requirements of 40 CFR Section 60.7(a). 67.0

CD 40 CFR Section 60.7(h); Minn. R.

7019.0100 Individual subparts of 40 CFR pt. 60 may include specific provisions which clarify or make inapplicable the provisions set forth in this section. 68.0

CD 40 CFR Section 60.11(d); Minn. R.

7017.2015 A t all times, including periods of startup, shutdown and malfunction, the Permittee shall, to the extent possible, maintain and operate any affected facility including associated air pollution control equipment in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures and inspection of the source. 69.0

CD 40 CFR Section 60.11(g); Minn. R.

7017.2015 For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any standard in this part, nothing in this part shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. 70.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 209 of 407

Subject Item: SV 165 Hydrocracker Feed Heater and Reboiler

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

MR 166 45 Mix Drum Fuel Gas Combustion O2 Monitor at 29H1/2

MR 179 29H-1/2 NOx Monitor

MR 180 29H-1/2 CO Monitor

MR 181 29H-1/2 O2 Monitor

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 46.5 tons/year using 365-day Rolling Sum (based on maximum duty of 141 mmBtu/hr on EU 294 and 100 mmbtu/hr on EU 295). 2.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Emissions Monitoring: The owner or operator shall use a NOx CEMS to measure NOx emissions from SV 165. Monitoring requirements are located under the subject item MR 179. 3.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Average (230 mg/dscm [162 ppm]). This limit applies to the hydrogen sulfide content of fuel gas burned in the units. Existing continuous H2S monitoring systems on the existing refinery gas mix drums will be used to demonstrate compliance with this limit. This limit applies individually to EU 294 and EU 295. (This limit is most stringent, meets the limit set by Minn. R. 7011.1410, subp. 3(A)). 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 17.0 lbs/hour using 3-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 17.0 lbs/hour using 24-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 59.5 tons/year using 12-month Rolling Average 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 17.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The total emissions of sulfur dioxide from all existing and new fuel gas combustion devices and indirect heating equipment shall be divided by the total heat input of all such devices and equipment to determine compliance with this part; provided that no owner or operator shall cause to be discharged from any one unit of new indirect heating equipment any gases which contain sulfur dioxide in excess of 3.0 pounds per million Btu heat input. This limit applies individually to

EU 294 and EU 295. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.0074 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. This limit applies individually to EU 294 and EU 295. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity ; except for one six-minute period per hour of not more than 60% opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. This limit applies individually to

EU 294 and EU 295. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 210 of 407

CD Minn. R. 7007.0800, subps. 4 and

5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 15.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 NOx Recordkeeping: The Permittee shall record the daily and 365-day rolling sum NOx emissions from EU 294 and EU 295 using the NOx The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 211 of 407

Subject Item: EU 004 Truck Bottom Loading (gas, distillate) includi ng the trucks - Loading-Unloading Equipment

Associated Items: CE 003 Activated Carbon Adsorption

CE 050 Flaring

CE 058 Other (CVS)

GP 017 Loading Rack Activities in CFP group limit

MR 004 VOC Monitor at Bottom Loading Unit

SV 003 BT Load VRU Stack

SV 159 Stack Vent at the Enclosed Flare at Bottom Loading

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT 40 CFR Section 63.422(b); Minn.

R. 7011.7180 Volatile Organic Compounds: less than or equal to 10 milligrams/liter of total organic compounds per liter gasoline loaded. 2.0

CD 40 CFR Section 63.422(b); Minn.

R. 7011.7180 Total VOC concentration: equal to 2350 parts per million by volume (ppmv) using a 6-hour Average at the vapor recovery unit outlet which demonstrate compliance with the emission standard at 40 CFR Section 63.422(b). 3.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR 52.21&

Minn. R. 7007.3000 Volatile Organic Compounds: less than or equal to 50.2 tons/year using 12-month Rolling Sum 4.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies to the hydrogen sulfide content of fuel gases burned in the enclosed flare. 5.0

LIMIT Minn. R. 7011.0110;

Minn. R. 7011.0120 Opacity: less than or equal to 20 percent opacity 6.0

CD hdr RECORDKEEPING AND CALCULATION REQUIREMENTS 7.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Calculation of VOC Emissions from the Loading Rack: By the 28th day of each month, the Permittee shall calculate and record VOC emissions from the loading rack for the previous month using the following equation:

VOC Emissions = Q x 42 gal/bbl x LL x (1-CE/100) x (1 ton/2000 lbs)

where: Q = product throughput (thousand barrels per month) LL = 12.46 x S x P x M/T = factor for barge loading of distillate and all truck and rail loading (AP-42, 5th Edition) (continued below) 8.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 (continued from above)

where:

S = saturation factor 0.6 for Tank Trucks - Submerged Loading, dedicated normal service (AP-42 factor) P = true vapor pressure of product loaded, psia M = molecular weight of vapors, lb/lb-mol T = temperature of product loaded, degree R CE = control efficiency of control equipment (98.2 % for the VRU [CE 003] or 97.2% for the enclosed flare [CE 050])

The Permittee shall use the most recent AP-42 emission factors to calculate

emissions.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 9.0

CD Title I Condition: To avoid classification as major source and

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping of VOC Emissions from the Loading Rack: By the 28th day of each month, the Permittee shall record the following:

Total VOC emissions from the loading rack for the previous month; and The 12-month rolling sum of VOC emissions from the loading rack for the previous 12-month period. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 10.0

CD hdr CAM AND POLLUTION CONTROL EQUIPMENT REQUIREMENTS 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 212 of 407

CD Minn. R. 7007.0800, subps. 2 and

14 The Permittee shall operate and maintain the enclosed flare (CE 050) during loading any time that the vapor recovery unit (CE 003) is not being operated to control emissions from the Bottom Loading Rack (EU 004). 12.0

CD Minn. R. 7007.0800, subp. 4 See Monitoring Requirements for CAM and Pollution Control Equipment under CE

003 and CE 050. 13.0

CD hdr PERFORMANCE TEST REQUIREMENT 14.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 03/27/2013 for VOCs in lbs/hr and milligrams of total organic compounds per liter gasoline loaded.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 213 of 407

Subject Item: EU 005 #1 Crude Heater atmospheric distillation - Distillation Equipment

Associated Items: MR 009 11H1 Fuel Gas Flowmeter

SV 004 11H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 16.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 6.8 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 23.6 tons/year using 365-day Rolling Sum (Netting Limit) 6.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 7.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 ppm). This is a state-only requirement and it is not enforceable by the EPA Administrator and citizens under the Clean Air Act 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 14.0

CD hdr RECORDKEEPING REQUIREMENTS 15.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping Associated with Netting Limit: The Permittee shall calculate and record daily and 365-day rolling sum NOx emissions

from EU 005. The Permittee shall use 0.045 lb/mmBtu as the emission factor to calculate NOx emissions. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 214 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 18.0

CD hdr PERFORMANCE TEST REQUIREMENT 19.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 06/27/2013 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 20.0

CD hdr CMS REQUIREMENTS 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 22.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 23.0

CD hdr REPORTING REQUIREMENT 24.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter starting 02/01/2006 if there are any exceedances. (For netting limit) 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 215 of 407

Subject Item: EU 006 #1 Crude Heater crude preflash - Process Heater

Associated Items: MR 105 11H2 Fuel Gas Flowmeter

SV 005 11H2 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.4 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.4 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.7 tons/year using 12-month Rolling Average 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

LIMIT 40 CFR 60.104(a); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230mg/dscm [162ppm). This limit does not apply during periods of startup, shutdown or malfunction. 7.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1405, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 10.0

CD hdr OTHER LIMITS AND REQUIREMENTS 11.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 12.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 13.0

LIMIT Minn. R. 7017.2025 Fuel Usage: less than or equal to 57 million Btu/hour using 8-hour Block Average based on the higher heating value of fuel burned. Downtime of 15 or more minutes is not to be included as operating time.

The unit may not be operated at a higher heat input unless a performance test is conducted at a higher rate and MPCA staff determine compliance at that rate for

the emission unit. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 216 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 18.0

CD hdr CMS REQUIREMENT 19.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that record the fuel flowrate at each fuel combustion

device. 20.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 21.0

CD hdr PERFORMANCE TEST REQUIREMENT 22.0

S/A Title I Condition: CAAA of 1990; Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 11/17/2012 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 23.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 217 of 407

Subject Item: EU 016 Vacuum Pre-Strip Heater - Process Heater

Associated Items: MR 010 12H4 Firebox O2

MR 011 12H4 Fuel Gas Flowmeter

SV 015 12H4 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.3 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.3 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 15.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 6.3 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 27.2 tons/year using 365-day Rolling Sum (Netting Limit for Nox) 6.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R.

7011.1435 A Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (Most stringent; meet the limit set by Minn. R. 7011.1410, subp. 3). 7.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 pppm). This is a state-only requirement and is not enforceable by the EPA Administrator and citizens under the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD Minn. R. 7017.2025, subp. 3 Emission Correlation Factor Threshold: less than or equal to 137.9 million Btu/hour on an instantaneous basis. Emission correlation factor threshold is calculated using the higher heating value (HHV) of fuel burned.

The emission correlation factor threshold (ECFT) may not be operated at a higher heat input rate unless a performance test is conducted at a higher rate and the

Permittee receives written verification of the test results from the MPCA. The ECFT is for calculating NOx and CO emissions from this unit. NOx and CO emissions from operations at or below the ECFT are calculated using factors measured during the most recent emissions factor performance test. NOx and CO emissions from operations above the ECFT are calculated using the emission factor in AP-42 chapter 1.4 table 1.4-1 for large wall-fired pre-NSPS boilers (corrected to the HHV for fuel type). (continued below) 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 218 of 407

CD Minn. R. 7017.2025, subp. 3 (continued from above) The Permittee may also use other factors after receipt of written MPCA approval from the MPCA Emission Inventory program for use of such factors. The emission factor threshold applies unless the Permittee installs and certifies CEMS to directly

measure NOx. 16.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr MONITORING REQUIREMENT 18.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; Minn. R. 7007.0800, subp. 4 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis. 19.0

CD hdr PERFORMANCE TEST REQUIREMENT 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 11/02/2011 to

measure NOx emissions from SV 015.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

CD hdr CMS REQUIREMENT 22.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that record the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0

CD hdr O2 MONITOR REQUIREMENTS 25.0

CD Minn. R. 7007.0800, subp. 4 Firebox O2: The Permittee shall operate, and maintain a CMS that records the

firebox O2. 26.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability, including but not limited to annual calibrations. 27.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 28.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling average NOx emissions from EU 016. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 29.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 30.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 31.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 32.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 219 of 407

Subject Item: EU 019 #2 Vac Heater - Process Heater

Associated Items: MR 013 16H1 O2 Monitor

MR 014 16H1 CO Monitor

MR 015 16H1 NOx Monitor

MR 016 16H1 Fuel Gas Flowmeter

SV 017 16H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 10.0 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 10.0 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 23.7 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 10.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Sulfur Dioxide: less than or equal to 15.3 tons/year using 365-day Rolling Sum (Netting Limit) 6.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 46.7 tons/year using 365-day Rolling Sum (Netting Limit) 7.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (Most stringent limit, meets limit set by Minn. R. 7011.1410, subp. 3) 8.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 ppm). This is a state-only requirement and it is not enforceable by the EPA administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

CD hdr OTHER LIMITS AND REQUIREMENTS 13.0

CD Minn. R 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 14.0

CD Minn. R. 7007.0800, subps. 4 and

5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 SO2 Emission Calculation and Recordkeeping for Netting Limit: The Permittee shall calculate and record daily and 365-day rolling sum SO2 emissions from EU 019. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 220 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 18.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD hdr CEMS REQUIREMENTS FOR CO AND NOx 20.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000;
Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain NOx

CEMS 21.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain CO

CEMS 22.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000;

Minn. R. 7017.1006 NOx Emissions Measuring: The Permittee shall use a NOx CEMS to measure NOx

emissions from SV 017. 23.0

CD Minn. R. 7017.1006 CO Emissions Measuring: The Permittee shall use a CO CEMS to measure CO

emissions from SV 017. 24.0

CD Minn. R. 7017.1160, subps. 1,2

and 3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS 25.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 26.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 27.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 28.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 29.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 30.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each quarter following CEMS Relative Accuracy Test Audit (RATA) 31.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 32.0

CD Minn. R. 7017.1090, subps. 1 and

2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 221 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 34.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 35.0

CD hdr CMS REQUIREMENT 36.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 37.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 38.0

CD hdr O2 MONITOR REQUIREMENTS 39.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 40.0

CD hdr REPORTING REQUIREMENT 41.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of the SO2 or NOx limit. 42.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 222 of 407

Subject Item: EU 026 #1 Vac Heater - Process Heater

Associated Items: MR 026 19H1 Fuel Gas Meter

SV 025 19H1 Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 7.3 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than 7.3 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 17.3 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 7.3 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 28.7 tons/year using 365-day Rolling Sum (Netting Limit) 6.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 7.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 ppm). This is a state-only requirement and pursuant to the Minn. R. 7007.1750, it is not enforceable by the EPA administrator or citizens under

the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 135.1 million Btu/hour using 8-hour Block Average For NOx emissions based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not to be included as operating time.

The unit may not be operated at a higher heat input unless a performance test is conducted at a higher rate and MPCA staff determine compliance at that rate for

the emission unit. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr C. RECORDKEEPING REQUIREMENTS 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 223 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emissions Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emissions Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping for Netting Limit: The Permittee shall calculate and record daily and 365-day rolling sum NOx emissions from EU 026. NOx emissions shall be calculated using 0.045 lbs/mmBtu. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD hdr D. PERFORMANCE TEST REQUIREMENTS 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 03/22/2012 to

measure NOx emissions from SV 019.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

CD hdr E. CMS REQUIREMENTS 22.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0

CD hdr E. REPORTING REQUIREMENT 25.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: 40 CFR Section 52.21

& Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of the SO2 or NOx limit. 26.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 224 of 407

Subject Item: EU 028 #1 Coker Heater - Process Heater

Associated Items: MR 108 21H-1 West Fuel Gas Flowmeter

MR 109 21H-1 East Fuel Gas Flowmeter

SV 027 21H1S Stack

SV 028 21H1N Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 3-hour Rolling Average (most stringent; meets the limit set by Minn. R. 7011.1410, subp. 3 A). 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 13.2 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 6.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 7.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 11.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

CD Minn. R. 7007.0800, subp. 2 Emission Factor Threshold: less than or equal to 106.5 million Btu/hour on an instantaneous basis. Emission factor threshold is calculated using the higher heating value (HHV) of fuel burned.

The emission factor threshold (EFT) may not be operated a higher heat input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. The EFT is for calculating NOx and CO emissions from this unit. NOx and CO emissions from operations at or below the EFT are calculated using factors measured during the most recent emissions factor performance test. NOx and CO emissions from operations above the EFT are calculated using the emission factor in AP-42 chapter 1.4 table 1.4-1 for large wall-fired pre-NSPS boilers (corrected to the HHV for fuel type). The Permittee may also use other factors after receipt of written MPCA approval from the MPCA Emission Inventory program for use of such factors. (continued below) 13.0

CD Minn. R. 7007.0800, subp. 2 (continued from above) This emission factor threshold applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 225 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: When the unit is operating the Permittee shall record heat input at intervals no greater than 15 minutes. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD hdr PERFORMANCE TEST REQUIREMENT 19.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/04/2013 to measure NOx from SV 027/028. This is the emissions factor performance test for determining the NOx emission factor and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/04/2023 to retain use of stack test-based

factor. 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/04/2013 to measure CO emissions from SV 027/028. This is the emissions factor performance test for determining the CO emission factor and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/04/2023 to retain use of stack test-based

factor.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

CD hdr CMS REQUIREMENTS 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 226 of 407

Subject Item: EU 030 #2 Coker Heater - Process Heater

Associated Items: MR 110 21H-2 West Fuel Gas Flowmeter

MR 111 21H-2 East Fuel Gas Flowmeter

SV 029 21H2S Stack

SV 030 21H2N Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 3-hour Rolling Average (most stringent; meets the limit set by Minn. R. 7011.1410, subp. 3 A). 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 13.2 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 5.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 6.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 7.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 11.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

CD Minn. R. 7007.0800, subp. 2 Emission Factor Threshold: less than or equal to 124.4 million Btu/hour on an instantaneous basis. Emission factor threshold is calculated using the higher heating value (HHV) of fuel burned.

The emission factor threshold (EFT) may not be operated at a higher heat input rate unless a performance test is conducted at a higher rate and the Permittee

receives written verification of the test results from the MPCA. The EFT is for calculating NOx and CO emissions from this unit. NOx and CO emissions from operations at or below the EFT are calculated using factors measured during the most recent emissions factor performance test. NOx and CO emissions from operations above the EFT are calculated using the emission factor in AP-42 chapter 1.4 table 1.4-1 for large wall-fired pre-NSPS boilers (corrected to the HHV for fuel type). The Permittee may also use other factors after receipt of written MPCA approval from the MPCA Emission Inventory program for use of such factors (continued below) 13.0

CD Minn. R. 7007.0800, subp. 2 (continued from above) This emission factor threshold applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 227 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: When the unit is operating the Permittee shall record heat input at intervals no greater than 15 minutes. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD hdr PERFORMANCE TEST REQUIREMENT 19.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/03/2013 to measure CO emissions from SV 029/030. This is the emissions factor performance test for determining the CO emission factor and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/03/2023 to retain use of stack test-based

factor.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/03/2013 to measure NOx from SV 029/030. This is the emissions factor performance test for determining the NOx emission factor and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/03/2023 to retain use of stack test-based

factor. 21.0

CD hdr CMS REQUIREMENTS 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 228 of 407

Subject Item: EU 032 Steam/Air Heater Decoking - 21H-1 - Process Heater

Associated Items: CE 007 Gas Scrubber (General, Not Classified)

SV 031 21H1 Decoke Pit Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION AND OPERATIONAL LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.73 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Decoking shall occur in one of the three following scenarios for any 1-, 3- or 24-hour period: 1. EU 032 (21H1) only, or; 2. EU 033 (21H2) only, or; 3. EU 037 (23H1) and EU 038 (23H2) may be steam air decoked simultaneously but not during steam air decoking of EU 032 or EU 033. 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 432 hours/year using 12-month Rolling Sum for steam-air decoking operation. 7.0

CD hdr RECORDKEEPING REQUIREMENTS 8.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 9.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall monitor the start and stop times for heater decoking and compute the hours of heater decoking operations. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 229 of 407

Subject Item: EU 033 Steam/Air Heater Decoking - 21H-2 - Process Heater

Associated Items: CE 007 Gas Scrubber (General, Not Classified)

SV 031 21H1 Decoke Pit Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION AND OPERATIONAL LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.73 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 8.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Decoking shall occur in one of the three following scenarios for any 1-, 3- or 24-hour period: 1. EU 032 (21H1) only, or; 2. EU 033 (21H2) only, or; 3. EU 037 (23H1) and EU 038 (23H2) may be steam air decoked simultaneously but not during steam air decoking of EU 032 or EU 033. 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 432 hours/year using 12-month Rolling Sum for steam-air decoking operation. 7.0

CD hdr RECORDKEEPING REQUIREMENTS 8.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 9.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall monitor the start and stop times for heater decoking and compute the hours of heater decoking operations. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 230 of 407

Subject Item: EU 034 #3 Coker Heater - Process Heater

Associated Items: MR 112 23H-1 South Fuel Gas Flowmeter

MR 113 23H-1 North Fuel Gas Flowmeter

SV 032 23H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 12.7 lbs/hour using 3-hour Rolling Average (most stringent; meets the limit set by Minn. R. 7011.1410, subp. 3 (A)). 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 12.7 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 44.6 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 12.7 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 6.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 7.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 11.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

CD Minn. R. 7007.0800, subp. 2 Emission Factor Threshold: less than or equal to 135.8 million Btu/hour on an instantaneous basis. Emission factor threshold is calculated using the higher heating value (HHV) of fuel burned.

The emission factor threshold (EFT) may not be used at a higher heat input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. The EFT is for calculating NOx and CO emissions from this unit. NOx and CO emissions from operations at or below the EFT are calculated using factors measured during the most recent emissions factor performance test. NOx and CO emissions from operations above the EFT are calculated using the emission factor in AP-42 chapter 1.4 table 1.4-1 for large wall-fired pre-NSPS boilers (corrected to the HHV for fuel type). The Permittee may also use other factors after receipt of written MPCA approval from the MPCA Emission Inventory program for use of such factors. (continued below) 13.0

CD Minn. R. 7007.0800, subp. 2 (continued from above) This emission factor threshold applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 231 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: When the unit is operating the Permittee shall record heat input at intervals no greater than 15 minutes. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD hdr PERFORMANCE TEST REQUIREMENT 19.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/05/2013 to measure NOx emissions from SV 032. This is the emissions factor performance test for determining the NOx emission factors and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/05/2023 to retain use of stack test-based

factors. 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due 3,652 days after 12/05/2013 to measure CO emissions from SV 032. This is the emissions factor performance test for determining the CO emission factors and the EFT. The EFT is calculated as 110% of the average mmBtu/hr operating rate of all test runs. The next performance test required under this condition must be completed by 12/05/2023 to retain use of stack test-based

factors.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

CD hdr CMS REQUIREMENTS 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of the SO2 limits. 25.0

CD hdr SHUTDOWN REQUIREMENTS 26.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall permanently shutdown EU 034 within 180 days after EU 352 begins normal operation. The conditions in the permit applicable to this emission

unit and associated items remain effective until shutdown of the unit occurs. 27.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall submit a written notification to the MPCA of permanent shutdown of EU 034. The notification shall be postmarked within 30 days of permanent shutdown. 28.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 232 of 407

Subject Item: EU 035 #3 Coker Heater - Process Heater

Associated Items: MR 027 23H-2 O2 Analyzer

MR 028 23H-2 Fuel Gas Flow Meter pass 1

MR 029 23H-2 Fuel Gas Flow Meter pass 2

MR 030 23H-2 Fuel Gas Flow Meter pass 3

MR 031 23H-2 Fuel Gas Flow Meter pass 4

SV 033 23H2 Stack

NC/

CA Type Citation Requirement

CD hdr POLLUTANT LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.12 lbs/million Btu heat input using 365-day Rolling Average (BACT Limit) 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Carbon Monoxide: less than or equal to 0.10 lbs/million Btu heat input using 1-Hour

A verage (BACT Limit) 3.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (Most stringent limit, meets limit set by Minn. R. 7011.1410, subp. 3) 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.4 lbs/hour using 3-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.4 lbs/hour using 24-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 13.4 tons/year using 12-month Rolling Average 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 9.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subps. 4 and

5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 14.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 108.4 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher heat input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 233 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in each 8-hour block. Downtime of 15 or more minutes is not included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD hdr MONITORING REQUIREMENTS 17.0

CD Title I Condition: 40 CFR Section 52.21(j)(3) Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis. 18.0

CD Title I Condition: 40 CFR Section 52.21(j)(3) Monitoring for CO emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine CO lb/MMBtu emissions on an hourly basis. 19.0

CD hdr PERFORMANCE TEST REQUIREMENTS 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 11/21/2013 to measure NOx emissions from SV 033 for verifying the NOx/O2 emissions

correlations.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 11/21/2013 to measure CO emissions from SV 033 for verifying the CO/O2 emissions correlations

.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 22.0

CD hdr RECORDKEEPING REQUIREMENTS 23.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 365-day average (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 365-day period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 CO Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 1-hour average (arithmetic mean) lb/MMBtu for CO emissions. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 25.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 26.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 27.0

CD hdr CMS REQUIREMENT 28.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that record the fuel flowrate at each fuel combustion

device. 29.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 30.0

CD hdr O2 MONITOR REQUIREMENTS 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 234 of 407

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 32.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. This condition expires upon certification

of the CEMS. 33.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 34.0

CD hdr SHUTDOWN REQUIREMENTS 35.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall permanently shutdown EU 035 within 180 days after EU 352 begins normal operation. The conditions in the permit applicable to this emission

unit and associated items remain effective until shutdown of the unit occurs. 36.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall submit a written notification to the MPCA of permanent shutdown of EU 035. The notification shall be postmarked within 30 days of permanent shutdown. 37.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 235 of 407

Subject Item: EU 037 Steam/Air Heater Decoking 23H-1 - Process Heater

Associated Items: CE 030 Gas Scrubber (General, Not Classified)

SV 035 P20 Decoke Pit Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION AND OPERATIONAL LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 20.2 lbs/hour using 3-hour Rolling Average . This limit applies to EU 037 and EU 038. 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 20.2 lbs/hour using 24-hour Rolling Average . This limit applies to EU 037 and EU 038. 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 4.36 tons/year using 12-month Rolling Average . This limit applies to EU 037 and EU 038. 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 20.2 lbs/hour using 1-Hour Rolling Average . This limit applies to EU 037 and EU 038. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean

A ir Act. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Decoking shall occur in one of the three following scenarios for any 1-, 3- or 24-hour period: 1. EU 032 (21H1) only, or; 2. EU 033 (21H2) only, or; 3. EU 037 (23H1) and EU 038 (23H2) may be steam air decoked simultaneously but not during steam air decoking of EU 032 or EU 033. 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 432 hours/year using 12-month Rolling Sum for steam-air decoking operation. 7.0

CD hdr RECORDKEEPING REQUIREMENTS 8.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 9.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall monitor the start and stop times for heater decoking and compute the hours of heater decoking operations. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0

CD hdr SHUTDOWN REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall permanently shutdown EU 037 within 180 days after EU 352 begins normal operation. The conditions in the permit applicable to this emission

unit and associated items remain effective until shutdown of the unit occurs. 13.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall submit a written notification to the MPCA of permanent shutdown of EU 037. The notification shall be postmarked within 30 days of permanent shutdown. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 236 of 407

Subject Item: EU 038 Steam/Air Heater Decoking 23H-2 - Process Heater

Associated Items: CE 030 Gas Scrubber (General, Not Classified)

SV 036 25V53 Deaerator Vent Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION AND OPERATIONAL LIMITS 1.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Decoking shall occur in one of the three following scenarios for any 1-, 3- or 24-hour period: 1. EU 032 (21H1) only, or; 2. EU 033 (21H2) only, or; 3. EU 037 (23H1) and EU 038 (23H2) may be steam air decoked simultaneously but not during steam air decoking of EU 032 or EU 033. 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 432 hours/year using 12-month Rolling Sum for steam-air decoking operation. 3.0

CD hdr RECORDKEEPING REQUIREMENT 4.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall monitor the start and stop times for heater decoking and compute the hours of heater decoking operations. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 5.0

CD hdr SHUTDOWN REQUIREMENTS 6.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall permanently shutdown EU 038 within 180 days after EU 352 begins normal operation. The conditions in the permit applicable to this emission

unit and associated items remain effective until shutdown of the unit occurs. 7.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall submit a written notification to the MPCA of permanent shutdown of EU 038. The notification shall be postmarked within 30 days of permanent shutdown. 8.0

CD hdr SEE EU 037 FOR SO2 SIP LIMITS 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 237 of 407

Subject Item: EU 040 #3 Crude Unit Charge Heater - Process Heater

Associated Items: MR 032 25H-1 or 25H-2 O2 Analyzer

MR 034 25H-1 Fuel Gas Flow Meter

MR 150 NOx Monitor at 25H1 or 25H2

MR 151 CO Monitor at 25H1 or 25H2

SV 037 25H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.12 lbs/million Btu heat input using 365-day Rolling Average . This limit is less stringent than the effective Consent Decree limit of 0.045 lb/mmBtu NOx. (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Carbon Monoxide: less than or equal to 0.10 lbs/million Btu heat input using 1-Hour

A verage (BACT Limit) 4.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 11.1 tons/year using 365-day Rolling Sum 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 19.5 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 19.5 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 54.3 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 19.5 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 10.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

CD hdr OTHER LIMITS AND REQUIREMENTS 14.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 15.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD hdr MONITORING REQUIREMENTS 17.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis until the NOx CEMS is certified. 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 238 of 407

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 Monitoring for CO emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine CO lb/MMBtu emissions on an hourly basis until the CO CEMS is certified. 19.0

CD hdr E. RECORDKEEPING AND REPORTING REQUIREMENTS 20.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 365-day average (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 365-day period until the NOx CEMS is certified. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 CO Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 1-hour average (arithmetic mean) lb/MMBtu for CO emissions until the CO CEMS is certified. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 22.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due 30 days after end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 23.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 24.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 25.0

CD hdr CEM REQUIREMENTS FOR CO and NOx 26.0

CD Title I Condition: CAAA of 1990;
Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring for NOx: The Permittee shall install, operate and use a nitrogen oxides (NOx) CEM to measure NOx emissions from SV 037. (2001 EPA Consent Decree, as amended) 27.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emission Monitoring for CO: The Permittee shall install, operate and use CO CEM

to measure CO from SV 037 28.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 29.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 30.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 31.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 32.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar half-year following Cylinder Gas Audit 33.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 34.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 35.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 239 of 407

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp. 10.

A .-C Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 36.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 37.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 38.0

CD hdr CMS REQUIREMENT 39.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 40.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 41.0

CD hdr O2 MONITOR REQUIREMENTS 42.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 43.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 44.0

CD hdr SHUTDOWN REQUIREMENTS 45.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall permanently shutdown EU 040 within 180 days after EU 353 begins normal operation. The conditions in the permit applicable to EU 040 and

associated items remains effective until shutdown of the unit occurs. 46.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall submit a written notification to the MPCA of permanent shutdown of EU 040. The notification shall be postmarked within 30 days of permanent shutdown. 47.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 240 of 407

Subject Item: EU 041 #3 Crude Unit Vac Pre-Fractionator Heater - Process Heater

Associated Items: MR 033 45 Drum Fuel Gas Combustion O2 Monitor at 25H3

MR 035 25H-3 Fuel Gas Flow Meter

MR 148 NOx Monitor at 25H3

MR 149 CO Monitor at 25H3

MR 161 45 Mix Drum Fuel Gas Combustion SO2 Monitor at 25H3

SV 038 25H3 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.12 lbs/million Btu heat input using 365-day Rolling Average . This limit is less stringent than the effective Consent Decree limit of 0.045 lb/mmBtu NOx. (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Carbon Monoxide: less than or equal to 0.10 lbs/million Btu heat input using 1-Hour

A verage (BACT Limit) 4.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 9.9 tons/year using 365-day Rolling Sum 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 17.5 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 17.5 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 48.8 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 17.5 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 10.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

CD hdr OTHER LIMITS AND REQUIREMENTS 14.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 15.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 16.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 241 of 407

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 365-day average (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 365-day period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 CO Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 1-hour average (arithmetic mean) lb/MMBtu of CO until the CO CEMS is certified. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 22.0

CD hdr CEM REQUIREMENTS FOR CO AND NOx 23.0

CD Title I Condition: CAAA of 1990;
R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall install, operate and use a nitrogen oxides (NOx) CEM to measure NOx emissions from SV 038. (2001 EPA Consent Decree, as amended) 24.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emission Monitoring for CO: The Permittee shall install, operate and use CO CEM

to measure CO from SV 037 25.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 26.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 27.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 28.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 29.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar half-year following Cylinder Gas Audit 30.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 31.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 32.0

CD Minn. R. 7017.1090, subps. 1 and

2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 242 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 34.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 35.0

CD hdr CMS REQUIREMENT 36.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 37.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 38.0

CD hdr O2 MONITOR REQUIREMENTS 39.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 40.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 41.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 243 of 407

Subject Item: EU 050 Distillate HDS Recycle Hydrogen Charge Heater - Process Heater

Associated Items: MR 051 27H-101 Natural Gas Supply Flow Meter

MR 052 27H-101 Fuel Gas Supply Flow Meter 2

MR 057 27H-101 Fuel Gas Supply Flow Meter 1

MR 167 27H-101 CO Monitor

MR 168 27H-101 NOx Monitor

MR 182 27H-101 O2 Monitor

SV 044 27H101 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classifcation as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 3.7 tons/year using 365-day Rolling Sum 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 4.80 lbs/hour using 24-hour Rolling Average (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.080 lbs/million Btu heat input using 24-hour Rolling Average (BACT Limit). 4.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1490, subp. 2 [most stringent, meets limit set by Minn. R. 7011.1410, subp. 3] Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm[162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.5 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.5 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 22.7 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 6.5 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction and hydrogen sulfide requirements constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

CD hdr OTHER LIMITS AND REQUIREMENTS 13.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 14.0

CD Minn. R. 7007.0800, subps. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr MONITORING REQUIREMENT 16.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 Monitoring for NOx emissions associated with the BACT limit: Install, operate, and maintain NOx and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and

A ppendix F. See MR 167 for additional monitoring requirements, 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 244 of 407

CD Title I Condition: To avoid classifcation as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7017.1006 Monitoring of CO emissions: Install, operate, and maintain CO and O2 CEMs in accordance with 40 CFR pt. 60, Appendix B and Appendix F. See MR 168 for additional monitoring requirements. 18.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 19.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping associated with the BACT limit: The Permittee shall calculate and record the 24-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 24-hour period. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 22.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. (reporting associated with the BACT limit). 23.0

CD hdr CMS REQUIREMENT 24.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 25.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 26.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 245 of 407

Subject Item: EU 051 Distillate Hydrotreater Fractntr Htr - Distillation Equipment

Associated Items: MR 047 27H-102 O2 Analyzer

MR 053 27H-102 Fuel Gas Supply Flow Meter

MR 056 27H-102 Natural Gas Supply Flow Meter

SV 045 27H102 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 3.7 tons/year using 365-day Rolling Sum 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 4.80 lbs/hour using 24-hour Rolling Average (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.080 lbs/million Btu heat input using 24-hour Rolling Average (BACT Limit). 4.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 7.3 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 7.3 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 25.7 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 7.3 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

CD hdr OTHER LIMITS AND REQUIREMENTS 13.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 76.1 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx and CO. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 246 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr MONITORING REQUIREMENTS 18.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis. 19.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7017.1006 Monitoring for CO emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine CO lb/MMBtu emissions on an hourly basis. 20.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 21.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 24-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 24-hour period. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 23.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 24.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. 25.0

CD hdr PERFORMANCE TEST REQUIREMENT 26.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 01/31/2012 to

measure NOx emissions from SV 045.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 27.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 01/31/2012 to

measure CO emissions from SV 045.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 28.0

CD hdr CMS REQUIREMENT 29.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 30.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 31.0

CD hdr O2 MONITOR REQUIREMENTS 32.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 247 of 407

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 33.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 34.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 248 of 407

Subject Item: EU 052 #2 H2 Plant Reformer Heater - Process Heater

Associated Items: MR 045 27H-1 O2 Analyzer

MR 049 27H-1 Fuel Gas Supply Flow Meter

MR 054 27H-1 PSA Gas Supply Flow Meter

MR 055 27H-1 Natural Gas Supply Flow Meter

SV 046 27H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 2.09 lbs/hour using 365-day Rolling

A verage (limit is most stringent, meets the limit set by: Minn. R. 7011.1410, subp. 3(B)). 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 6.0 lbs/hour using 365-day Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 47.5 lbs/hour using 24-hour Rolling Average (BACT Limit) 4.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.10 lbs/million Btu heat input using 24-hour Rolling Average (BACT Limit) 5.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 14.4 lbs/hour using 365-day Rolling

A verage 6.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction.

(limit is most stringent, meets the limit set by: Minn. R. 7011.1410, subp. 3(B)). 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 61.7 lbs/hour using 3-hour Rolling Average 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 61.7 lbs/hour using 24-hour Rolling Average 9.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 216.3 tons/year using 12-month Rolling

A verage 10.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 61.7 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 12.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 14.0

CD hdr OTHER LIMITS AND REQUIREMENTS 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 249 of 407

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 800 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test

results from the MPCA. 16.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. he records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn purge gas, refinery fuel gas and natural gas only. 18.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD hdr MONITORING REQUIREMENTS 20.0

CD Title I Condition: 40 CFR Section 52.21(j)(3) Monitoring for BACT NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation to determine NOx lb/MMBtu emissions on an hourly basis. 21.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Monitoring for CO emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation to determine CO lb/MMBtu emissions on an hourly basis. 22.0

CD hdr RECORDKEEPING REQUIREMENTS 23.0

CD Title I Condition: 40 CFR Section

52.21 and Minn. R. 7007.3000 BACT NOx Emission Recordkeeping: The Permittee shall maintain records of the calculated NOx emissions hourly average of NOx emissions in lb/hr based on the most recent performance test. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 CO Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated CO emissions hourly average of CO emissions in lb/hr based on the most recent performance test. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 25.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 BACT NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 24-hour average lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 24-hour period based on the most recent performance test. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 26.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM/PM10 Emission Calculations and Recordkeeping: The Permittee shall calculate and record the daily and 365-day rolling average PM/PM10 emissions based on the most recent performance test. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 28.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 29.0

CD hdr REPORTING REQUIREMENTS 30.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of NOx emission limits. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 250 of 407

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of CO and PM/PM10 emission limit. 32.0

CD hdr PERFORMANCE TEST REQUIREMENT 33.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 03/04/2010 to measure PM emissions from SV 046. The performance test under this condition must be completed by 03/04/2015.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 34.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 03/04/2010 to measure PM10 emissions from SV 046. The performance test under this condition must be completed by 03/04/2015.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 35.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 01/25/2012 to

measure NOx emissions from SV 046.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 36.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 01/25/2012 to

measure CO emissions from SV 046.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 37.0

CD hdr CMS REQUIREMENT 38.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 39.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 40.0

CD hdr O2 MONITOR REQUIREMENTS 41.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 42.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 43.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 251 of 407

Subject Item: EU 053 Naphtha Hydrotreater Reactor Chg Htr - Reactor

Associated Items: MR 061 28H-1 O2 Analyzer

MR 062 28H-1 Fuel Gas Supply Flow Meter

MR 063 28H-1 Natural Gas Supply Flow Meter

SV 047 28H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 3.0 lbs/hour using 24-hour Rolling Average (BACT Limit) 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.14 lbs/million Btu heat input using 24-hour Rolling Average when heater is firing less than or equal to 90% of maximum rating. The limit does not apply during startup or shutdown (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.10 lbs/million Btu heat input using 24-hour Rolling Average when heater is firing greater than 90% of maximum rating. The limit does not apply during startup or shutdown (BACT Limit) 4.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2; Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.6 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.6 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.2 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

CD hdr OTHER LIMITS AND REQUIREMENTS 13.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 34.0 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 252 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr MONITORING REQUIREMENTS 18.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 Monitoring for NOx emissions associated with the BACT limit: The Permittee shall continuously monitor fuel combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis. 19.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 20.0

CD Title I Condition: 40 CFR Section 52.21(j)(3); Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping associated with the BACT limit: The Permittee shall calculate and record the 24-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 24-hour period. Performance test results shall be used for calculating emissions. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 23.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. (reporting associated with the BACT limit). 24.0

CD hdr PERFORMANCE TEST REQUIREMENT 25.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 11/16/2013 to

measure NOx emissions from SV 047.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 26.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 11/16/2013 to

measure CO emissions from SV 047.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 27.0

CD hdr CMS REQUIREMENT 28.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 29.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 30.0

CD hdr O2 MONITOR REQUIREMENTS 31.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 32.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 253 of 407

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 254 of 407

Subject Item: EU 054 #6 HDS Reactor Charge Heater - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 116 31H1 Fuel Gas Flowmeter

SV 048 31H1 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.0 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.0 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.3 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 1.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD hdr RECORDKEEPING REQUIREMENTS 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 255 of 407

Subject Item: EU 055 #2 HDS Fractionation Heater (31H2) - Fractionation Equipment

Associated Items: GP 057 Emission Units subject to Minn. R. built after June 11, 1973

GP 106 Control Equipment Used to Meet Requirements of MACT CC

MR 069 31H2 SO2 Analyzer

MR 117 31H2 Fuel Gas Flowmeter

MR 184 31H2 Flow Meter for Exhaust Gases

SV 049 31H2 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 66.4 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 66.4 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 290.8 tons/year using 365-day Rolling Average . This limit is effective upon the date of SIP approval. 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 66.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD 40 CFR Section 60.102a(g)(1) The Permittee shall comply with either the emission limit in paragraph (i) or the fuel gas concentration limit in paragraph (ii) of 40 CFR Section 60.102a(g)(1). 6.0

LIMIT 40 CFR Section 60.102a(g)(1)(i) Sulfur Dioxide: less than or equal to 20 parts per million using 3-hour Rolling

A verage (by volume ppmv, dry basis, corrected to 0 percent excess air, determined hourly) and, 7.0

LIMIT 40 CFR Section 60.102a(g)(1)(i) Sulfur Dioxide: less than or equal to 8.0 parts per million using 365-day Rolling

A verage (by volume ppmv, dry basis, corrected to 0 percent excess air, determined daily) or; 8.0

LIMIT 40 CFR Section 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 162 parts per million using 3-hour Rolling

A verage (by volume ppmv, determined hourly) and, 9.0

LIMIT 40 CFR Section 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 60 parts per million using 365-day Rolling

A verage (by volume ppmv, determined daily). 10.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average 12.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity , except for one six-minute period per hour of not more than 60 percent opacity. 13.0

CD hdr OTHER LIMITS 14.0

CD 40 CFR Section 60.103a(b) The Permittee shall conduct a root cause analysis of any emission limit exceedance or process startup, shutdown, upset, or malfunction that causes a discharge to the atmosphere in excess of 227 kilograms per day (kg/day) (500 lb per day (lb/day)) in excess of permitted levels of SO2. For any root cause analysis performed, the Permittee shall record the identification of the affected facility, the date and duration of the discharge, the results of the root cause analysis, and the action taken as a result of the root cause analysis. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 256 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD 40 CFR Section 60.108a(c)(6) Record and maintain records of excess emissions greater than 500 lb/day SO2. 19.0

CD hdr MONITORING REQUIREMENTS 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I Condition: CAAA of 1990; Minn.

R. 7017.1006 SO2 Emissions Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). See additional CEMS requirements under MR 069. 21.0

CD Minn. R. 7017.1006 SO2 Emissions Measuring: The Permittee shall use a sulfur dioxide CEMS to

measure sulfur dioxide emissions from SV049. 22.0

CD hdr PERFORMANCE TEST REQUIREMENT 23.0

CD 40 CFR Section 60.107a(b) Due to the inherently low levels of H2S present in the Merox Treatment Unit offgas stream, EU 055 is exempt from H2S monitoring of the Merox Treating Unit offgas stream per EPA Region V letter of approval dated 11/15/2010. 24.0

CD hdr REPORTING REQUIREMENTS (SEE TABLE B) 25.0

S/A 40 CFR Sections 60.7(a)(3) and

60.108a Notification: due 15 days after Startup (actual date) of EU 055 combusting the full Merox offgas stream. 26.0

S/A 40 CFR Sections 60.7(a)(4) and

60.108a Notification: due 60 days before Startup modification to EU 055. Notification shall be postmarked 60 days or as soon as practicable before the change is commenced and shall include information describing the precise nature of the change, present and proposed emission control systems, productive capacity of the facility before and after the change, and the expected completion date of the change. 27.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 257 of 407

Subject Item: EU 056 HDS Heater (hot oil system) - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 123 31H4 Fuel Gas Flowmeter

SV 050 31H4 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 3.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 3.0 lbs/hour using 3-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 3.0 lbs/hour using 24-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 7.1 tons/year using 12-month Rolling Average 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 3.0 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes complaince with this limit. 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 11.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 12.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 43.1 lbs/million Btu heat input using 8-hour Block

A verage based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test

results from the MPCA. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 258 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 16.0

CD hdr CMS REQUIREMENT 17.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 18.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 19.0

CD hdr PERFORMANCE TEST REQUIREMENT 20.0

S/A Title I Condition: CAAA of 1990; Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 02/05/2014 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 259 of 407

Subject Item: EU 057 Unisar Reactor Charge Heater - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 122 31H-5 Fuel Gas Flowmeter

SV 051 31H5 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD hdr RECORDKEEPING REQUIREMENTS 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 260 of 407

Subject Item: EU 058 #5 HDS Charge Heater (naphtha) - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 118 31H7 Fuel Gas Flowmeter

SV 052 31H7 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 6.8 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 6.0

LIMIT Minn. R. 7011.1405, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 7.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

CD hdr OTHER LIMITS AND REQUIREMENTS 9.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 10.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 13.0

CD hdr CMS REQUIREMENT 14.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 15.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 261 of 407

Subject Item: EU 059 #1 HDS Reactor Charge Heater - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 119 31H8 Fuel Gas Flowmeter

SV 053 31H8 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 3.9 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 1.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD hdr RECORDKEEPING REQUIREMENTS 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 262 of 407

Subject Item: EU 060 #1 HDS Fractionation Heater - Fractionation Equipment

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 120 31H9 Fuel Gas Flowmeter

SV 054 31H9 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.1 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.1 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.1 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 6.0

LIMIT Minn. R. 7011.1405, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 7.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

CD hdr OTHER LIMITS AND REQUIREMENTS 9.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 10.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 13.0

CD hdr CMS REQUIREMENT 14.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 15.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 263 of 407

Subject Item: EU 061 #2 HDS Reactor Charge Heater - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 121 31H10 Fuel Gas Flowmeter

SV 055 31H10 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.3 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 1.3 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 3.0 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 1.3 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD hdr RECORDKEEPING REQUIREMENTS 6.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 7.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 264 of 407

Subject Item: EU 077 Powerformer Catalyst Regeneration - Refining Equipment

Associated Items: CE 022 Flaring

CE 023 Flaring

CE 024 Flaring

CE 025 Flaring

CE 066 Packed-Gas Adsorption Column

MR 185 HCL adsorber inlet temperature indicator (32TI01110)

SV 068 Powerform Cat Reg Stack

NC/

CA Type Citation Requirement

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR PETROLEUM REFINERIES: CATALYTIC CRACKING UNITS, CATALYTIC REFORMING UNITS, AND SULFUR RECOVERY UNITS 1.0

CD 40 CFR Section 63.1566(a)(5); 40 CFR Section 63.1567(a)(3) Prepare and implement an operation, maintenance, and monitoring plan according to the requirements in 40 CFR Section 63.1574(f) and operate at all times according to the procedures in the plan. 2.0

CD 40 CFR Section 63.6(e)(1)(i)-(iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subp. A and B A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 3.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii);

Minn. R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan (SSMP). 4.0

CD 40 CFR pt. 63, subp. CC, Table 6; 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv);

Minn. R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or malfunction or maintenance of air pollution control equipment. Document

conformance with or deviation from SSMP 5.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date startup, shutdown, malfunction plan (SSMP). 6.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 7.0

CD 40 CFR Section 63.1566(a)(1)(i); Table 15, option 1 or 2; 40 CFR Section 63.1566 (c) Vent emissions to a flare that meets the requirements for control devices in 40 CFR Section 63.11(b). Visible emissions from a flare must not exceed a total of 5 minutes during any 2-hour operating period for this source. Note: Vent gas routed to the flare system normally is recovered by flare gas recovery and returned to the refinery fuel gas system. These flare control requirements do not apply to recovered flare gas. 8.0

CD 40 CFR Section 63.1566(a)(2) For combustion control, the flare pilot light must be present at all times and the flare must be operating (in a ready status) at all times that emissions may be vented to it

from this source. 9.0

CD 40 CFR Section 63.1566(b)(1) The Permittee must install and operate a monitoring device such as a thermocouple, an ultraviolet beam sensor, or infrared sensor to continuously detect the presence of a pilot flame. 10.0

CD 40 CFR Section 63.1566(c) When emissions are routed to a flare for control, collect flare monitoring data according to 40 CFR Section 63.1572 and record each 1-hour period whether the monitor was continuously operating and the pilot light was contrinuously present during each 1-hour period. 11.0

CD 40 CFR Section 63.1567(a)(1); 40 CFR Section 63.1567(c) Reduce uncontrolled emissions of hydrogen chloride by 97 percent by weight or to a concentration of 10 ppmv (dry basis), corrected to 3 percent oxygen. 12.0

CD 40 CFR Section 63.1567(a)(2); 40 CFR Section 63.1567(c); 40 CFR Section 63.1572; Fixed bed gas-solid adsorption system: The daily average temperature of the gas entering or exiting the adsorption system must not exceed the limit established during the performance test; and the HCl concentration in the adsorption system exhaust gas must not exceed the limit established during the performance test. Collect the hourly and daily average temperature monitoring data according to 40 CFR Section 63.1572 during regeneration. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 265 of 407

CD 40 CFR Section 63.1567(c); 40

CFR Section 63.1572 Continuous Compliance: Average daily temperature must be less than 370 degrees

F and measured at the adsorber inlet. 14.0

CD 40 CFR Section 63.1567(c) Continuous Compliance for HCl concentration: Measure and record the concentration of the HCl weekly or during each regeneration cycle, whichever is less frequent. HCl must be <10 ppm. 15.0

CD 40 CFR Section 63.1567(b)(1) Fixed-bed gas-solid adsorption system: Must have a continuous parameter monitoring system to measure and record the temperature of the gas entering or exiting the adsorption system during coke burn-off and catalyst rejuvenation; and colormetric tube sampling system to measure the gaseous HCl concentration in the adsorption system exhaust and at a point within the adsorbent bed not to exceed 90 percent of the total length of the absorbent bed during coke burn-off and catalyst rejuvenation. The colormetric tube sampling system must meet the requirements of Table 41 of 40 CFR pt. 63, subp. CC. 16.0

CD 40 CFR Section 63.1575 The compliance report must include a statement that there were no deviations from any emission limitation or work practice standards during the reporting period or the information in 40 CFR Section 63.1575 (d) or (e) if applicable The Permittee may submit reports required by other regulations in place of or as part of the compliance report if the report contains the required information. 17.0

CD 40 CFR Section 63.1569(a) and (c ) Meet the requirements for bypass lines set forth in 40 CFR Section 63.1569. 18.0

CD hdr EMISSION LIMITS (FOR EU076 and EU077) 19.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 3-hour Rolling Average 20.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 24-hour Rolling Average 21.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.9 tons/year using 12-month Rolling Average 22.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 23.0

CD hdr RECORDKEEPING REQUIREMENTS (FOR EU076 and EU077) 24.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 25.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 26.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 266 of 407

Subject Item: EU 084 Gas Oil HDS Charge Heater - Process Heater

Associated Items: GP 117 Limit that Applies to Gas Oil HDS Heaters (EU084 and EU085)

MR 066 33H31 Firebox O2

MR 068 33H31 Fuel Gas Flow

SV 074 33H31 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 22.8 tons/year using 365-day Rolling Sum 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 13.4 lbs/hour using 3-hour Rolling Average Compliance with the fuel restriction constitutes compliance with this limit. 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 13.4 lbs/hour using 24-hour Rolling Average Compliance with the fuel restriction constitutes compliance with this limit. 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 10.7 lbs/hour using 12-month Rolling Average Compliance with the fuel restriction constitutes compliance with this limit. 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 13.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 7.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (most stringent limit) 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average ; except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this

limit. 10.0

CD hdr OTHER LIMITS AND REQUIREMENTS 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: Authorized to burn refinery gas and natural gas only. 12.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 118.0 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 267 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD hdr MONITORING REQUIREMENTS 16.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 4 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on the performance test results to determine NOx lb/MMBtu emissions on an hourly basis. (2001 EPA Consent Decree, as amended) 17.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 18.0

CD Title Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall calculate and record the hourly, daily, and 365-day rolling sum emission rate of nitrogen oxides. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 3-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 3-hour period. (2001 EPA Consent Decree, as amended).

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emissions Calculations and Recordkeeping for SIP Limits: The Permittee shall maintain records of the calculated SO2 emissions in lb/hr and tons/year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 22.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. (2001 EPA Consent Decree, as amended). 23.0

CD hdr PERFORMANCE TEST REQUIREMENT 24.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 02/09/2013 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 25.0

CD hdr CMS REQUIREMENTS 26.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Flowrate: The Permittee shall operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion device. 27.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 28.0

CD hdr O2 MONITOR REQUIREMENTS 29.0

CD Minn. R. 7007.0800, subp. 4 Firebox O2: The Permittee shall operate, and maintain a CMS that records the

firebox O2 at 33H31. 30.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability, including but not limited to annual calibrations. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 268 of 407

Subject Item: EU 085 Gas Oil HDS Fractionation Charge Heater - Process Heater

Associated Items: GP 117 Limit that Applies to Gas Oil HDS Heaters (EU084 and EU085)

MR 065 33H32 Firebox O2

MR 067 33H32 Fuel Gas Flow

SV 075 33H32 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 25.4 tons/year using 365-day Rolling Sum 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 3-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 24-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 34.8 tons/year using 12-month Rolling Average 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 7.0

LIMIT Minn. R. 7007.0800, subp. 2 Carbon Monoxide: less than or equal to 0.040 lbs/million Btu heat input using 365-day Rolling Average 8.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm[162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (most stringent limit) 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average , except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 107.8 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 15.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 269 of 407

CD hdr MONITORING REQUIREMENTS 17.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 4 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on performance test results to determine NOx lb/MMBtu emissions on an hourly basis. (2001 EPA Consent Decree, as amended) 18.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 19.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 NOx Emission Calculation and Recordkeeping: On an hourly basis, the Permittee shall calculate and record the 3-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 3-hour period. (2001 EPA Consent Decree, as amended)

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 20.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall calculate and record the hourly, daily, and 365-day rolling sum emission rate of NOx. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly averages of total SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by the

EPA administrator or citizens under the Clean Air Act. 22.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total SO2 in tons per year. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 23.0

CD Minn. R. 7007.0800, subp. 5 CO Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 3-hour (arithmetic mean) lb/MMBtu of CO using all of the 1-hour averages obtained during the previous 3-hour period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's); if there are any exceedances. (2001 EPA Consent Decree, as amended). 25.0

CD hdr PERFORMANCE TEST REQUIREMENT 26.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 02/06/2013 for NOx

emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 27.0

CD hdr CMS REQUIREMENT 28.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion device. 29.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 30.0

CD hdr O2 MONITOR REQUIREMENTS 31.0

CD Minn. R. 7007.0800, subp. 4 Firebox O2: The Permittee shall operate, and maintain a CMS that records the

firebox O2 at 33H32. 32.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability, including but not limited to annual calibrations. 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 270 of 407

Subject Item: EU 099 Platformer Catalyst Regeneration Vent - Regenerator

Associated Items: CE 022 Flaring

CE 023 Flaring

CE 024 Flaring

CE 025 Flaring

CE 067 Packed-Gas Adsorption Column

GP 057 Emission Units subject to Minn. R. built after June 11, 1973

MR 186 HCL adsorber inlet temperature indicator (37TC1150A)

SV 084 Plat Cat Reg Stack

NC/

CA Type Citation Requirement

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR PETROLEUM REFINERIES: CATALYTIC CRACKING UNITS, CATALYTIC REFORMING UNITS, AND SULFUR RECOVERY UNITS 1.0

CD 40 CFR Section 63.1566(a)(5); 40 CFR Section 63.1567(a)(3); Minn.

R. 7011.7280 Prepare and implement an operation, maintenance, and monitoring plan according to the requirements in 40 CFR Section 63.1574(f) and operate at all times according to the procedures in the plan. 2.0

CD 40 CFR Section 63.6(e)(1)(i)-(iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subps. A and B A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 3.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii);

Minn. R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the startup, shutdown, and malfunction plan (SSMP). 4.0

CD 40 CFR pt. 63, subp. CC, Table 6; 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv);

Minn. R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or malfunction or maintenance of air pollution control equipment. Document

conformance with or deviation from SSMP. 5.0

CD 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date SSMP. 6.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 7.0

CD 40 CFR Section 63.1566(a)(1); 40 CFR Section 63.1566(c); Minn. R.

7011.7280 Reduce uncontrolled emissions of total organic compounds (TOC) or nonmethane TOC from your process vent by 98% by weight using a control device or to a concentration of 20 ppmv (dry basis as hexane), corrected to 3% oxygen, whichever is less stringent. If you vent emissions to a boiler or process heater to comply with the percent reduction or concentration emission limitation, the vent stream must be introduced into the flame zone, or any other location that achieves the percent reduction or concentration standard. Or as an alternate control method, Vent emissions to a flare that meets the requirements for control devices in 40 CFR Section 63.11(b). Visible emissions from a flare must not exceed a total of 5 minutes during any 2 hour operating period for this source. Note: Vent gas routed to the flare system normally is recovered by flare gas recovery and returned to the refinery fuel gas system. These flare control requirements do not apply to recovered flare gas. 8.0

CD 40 CFR Section 63.1566(a)(2);

Minn. R. 7011.7280 For combustion control, the flare pilot light must be present at all times and the flare must be operating (in a ready status) at all times that emissions may be vented to it

from this source. 9.0

CD 40 CFR Section 63.1566(b)(1);

Minn. R. 7011.7280 The Permittee must install and operate a monitoring device such as a thermocouple, an ultraviolet beam sensor, or infrared sensor to continuously detect the presence of a pilot flame. 10.0

CD 40 CFR Section 63.1566(c); Minn.

R. 7011.7280 When emissions are routed to a flare for control, collect flare monitoring data according to 40 CFR Section 63.1572 and record each 1-hour period whether the monitor was continuously operating and the pilot light was continuously present during each 1-hour period. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 271 of 407

CD 40 CFR Section 63.1567(a)(1); 40 CFR Section 63.1567(c); Minn. R.

7011.7280 Reduce uncontrolled emissions of hydrogen chloride by 97 percent by weight or to a concentration of 10 ppmv (dry basis), corrected to 3 percent oxygen 12.0

CD 40 CFR Section 63.1567(a)(2); 40 CFR Section 63.1567(c); 40 CFR Section 63.1572; Minn. R.

7011.7280 Fixed bed gas-solid adsorption system: The daily average temperature of the gas entering or exiting the adsorption system must not exceed the limit established during the performance test; and the HCl concentration in the adsorption system exhaust gas must not exceed the limit established during the performance test. Collect the hourly and daily average temperature monitoring data according to 40 CFR Section 63.1572 during regeneration. 13.0

CD 40 CFR Section 63.1567(c); 40 CFR Section 63.1572; Minn. R.

7011.7280 Continuous Compliance: Average daily temperature must be less than 370 degrees

F and measured at the adsorber inlet. 14.0

CD 40 CFR Section 63.1567(c); Minn.

R. 7011.7280 Continuous Compliance for HCl concentration: Measure and record the concentration of the HCl weekly or during each regeneration cycle, whichever is less frequent. HCl must be <10 ppm. 15.0

CD 40 CFR Section 63.1567(b)(1);

Minn. R. 7011.7280 Fixed-bed gas-solid adsorption system: Must have a continuous parameter monitoring system to measure and record the temperature of the gas entering or exiting the adsorption system during coke burn-off and catalyst rejuvenation; and colormetric tube sampling system to measure the gaseous HCl concentration in the adsorption system exhaust and at a point within the adsorbent bed not to exceed 90 percent of the total length of the absorbent bed during coke burn-off and catalyst rejuvenation. The colormetric tube sampling system must meet the requirements of Table 41 of 40 CFR pt. 63, subp. CC. 16.0

CD 40 CFR Section 63.1575; Minn. R.

7011.7280 The compliance report must include a statement that there were no deviations from any emission limitation or work practice standards during the reporting period or the information in 40 CFR Section 63.1575 (d) or (e) if applicable the Permittee may submit reports required by other regulations in place of or as part of the compliance report if the report contains the required information. 17.0

CD 40 CFR Section 63.1569(a) and (c); Minn. R. 7011.7280 Meet the requirements for bypass lines set forth in 40 CFR Section 63.1569. 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 272 of 407

Subject Item: EU 102 Unit 38 Gasoil HDS A-Train Heater - Process Heater

Associated Items: GP 057 Emission Units subject to Minn. R. built after June 11, 1973

MR 074 38H1A Fuel Gas Flow

SV 087 38H1A Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.12 lbs/million Btu heat input using 3-hour

A verage (BACT LIMIT) 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 10.3 tons/year using 12-month Rolling Average 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

CD hdr OTHER LIMITS AND REQUIREMENTS 7.0

LIMIT Minn. R. 7017.2025 Oxygen: less than or equal to 5.49 percent using 3-hour Rolling Average (Wet) excluding periods of startup and shutdown. 8.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 30.7 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 9.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 12.0

CD hdr PERFORMANCE TEST REQUIREMENT 13.0

S/A Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 04/09/2014 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 14.0

CD hdr CMS REQUIREMENTS 15.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 273 of 407

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 274 of 407

Subject Item: EU 103 Unit 38 Gasoil HDS B-Train Heater - Process Heater

Associated Items: GP 057 Emission Units subject to Minn. R. built after June 11, 1973

MR 072 38H1B Fuel Gas Flow

SV 088 38H1B Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.12 lbs/million Btu heat input using 3-hour Rolling Average (BACT LIMIT) 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 10.3 tons/year using 12-month Rolling Average 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 2.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

CD hdr OTHER LIMITS AND REQUIREMENTS 7.0

LIMIT Minn. R. 7017.2025 Oxygen: less than or equal to 4.90 percent using 3-hour Rolling Average (Wet) excluding periods of startup and shutdown. 8.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 28.9 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 9.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 12.0

CD hdr PERFORMANCE TEST REQUIREMENT 13.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000: Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 04/10/2014 to

measure NOx emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 14.0

CD hdr CMS REQUIREMENTS 15.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 275 of 407

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 276 of 407

Subject Item: EU 104 Unit 38 Gasoil HDS Fractionation Charge Heater - Process Heater

Associated Items: GP 057 Emission Units subject to Minn. R. built after June 11, 1973

MR 073 38H2 Fuel Gas Flow

SV 089 38H2 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 12.2 tons/year using 365-day Rolling Sum 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 4.8 lbs/hour using 3-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 4.8 lbs/hour using 24-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 16.8 tons/year using 12-month Rolling Average 6.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 4.8 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 7.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (most stringent, meets the limit set by Minn. R. 7011.1410, subp. 3(A)) 8.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction and H2S requirements constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 13.0

CD Minn. R. 7007.0800, subps. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 14.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 Calculations and Recordkeeping for NOx Emissions: The Permittee shall calculate and record the hourly, daily, and 365-day rolling sum emission rate of nitrogen oxides. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 277 of 407

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 56.0 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 16.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 18.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 19.0

CD hdr PERFORMANCE TEST REQUIREMENT 20.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 02/05/2013 for NOx

emissions.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 21.0

CD hdr CMS REQUIREMENT 22.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 23.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 24.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 278 of 407

Subject Item: EU 126 Steam Boiler No. 6 at Boilerhouse - Boiler

Associated Items: MR 170 71B6 NOx Monitor

MR 171 71B6 CO Monitor

MR 172 71B6 O2 Monitor

SV 164 71B6 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT 40 CFR Section 60.44b(a); Minn.

R. 7011.0565 Nitrogen Oxides: less than or equal to 0.20 lbs/million Btu heat input using 30-day Rolling Average (expressed as NO2), if the unit is a high heat release rate unit. A "high heat release rate" is defined as a heat release rate greater than 70,000

Btu/hour-cubic foot.

The 30-day rolling average emission rate is calculated as the average of all hourly emissions data recorded by the monitoring 3.0

LIMIT 40 CFR Section 60.44b(a); Minn.

R. 7011.0565 Nitrogen Oxides: less than or equal to 0.10 lbs/million Btu heat input using 30-day Rolling Average (expressed as NO2), if the unit is a low heat release rate unit. A "low heat release rate" is defined as a heat release rate of 70,000 Btu/hr-cubic foot

or less.

The 30-day rolling average emission rate is calculated as the average of all hourly emissions data recorded by the monitoring system during the 30 day period. A new 30 day rolling average emission rate is calculated each steam generating unit operating day. 4.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 2 Hydrogen Sulfide: less than or equal to 90 parts per million using 365-day Rolling

A verage by volume. 5.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies to the hydrogen sulfide content of fuel gas burned in the units. Existing continuous H2S monitoring systems on the existing refinery gas mix drums will be used to demonstrate compliance with this limit. (most stringent limit for H2S) 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.1 lbs/hour using 3-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.1 lbs/hour using 24-hour Rolling Average 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 12.0 tons/year using 12-month Rolling Average 9.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 5.1 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 10.0

LIMIT 40 CFR Section 60.42b(k) Sulfur Dioxide: less than or equal to 0.20 lbs/million Btu heat input using 30-day Rolling Average . This limit applies at all times, including periods of startup, shutdown, and malfunction. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 279 of 407

LIMIT 40 CFR Section 60.43b(h)(1); Minn. R. 7011.1410, subp. 3(B)(1) Total Particulate Matter: less than or equal to 0.030 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. This limit is more stringent than Minn. R. 7011.1410, subp.3(B)(1). 13.0

LIMIT Minn. R. 7011.1410, subp. 3(B)(2) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 14.0

CD hdr OTHER LIMITS AND REQUIREMENTS 15.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery fuel gas and natural gas only. 16.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr CEM REQUIREMENTS FOR NOx (see also MR 170) 18.0

CD 40 CFR Section 60.48b; Minn. R.

7017.1006 Emissions Monitoring: The Permittee shall use a nitrogen oxides (NOx) CEMS to measure NOx emissions from EU 126. Specifications for the operation of the monitoring equipment are in 40 CFR Section 60.48b(c), (d), (e), (f), and Appendix

B. 19.0

CD Minn. R. 7017.1006 Installation of CEMS: The Permittee shall install and operate a NOx CEMS. The installation and operation of the CEMS will meet the performance requirements as specified in 40 CFR Section 60.46b. 20.0

CD 40 CFR Section 60.7(b) Records of Startup, Shutdown, or Malfunction: Any owner or operator subject to the provisions of 40 CFR pt. 60, subp. Db, shall maintain records of the occurrence and duration of any startup, shutdown, or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system or monitoring device is inoperative. 21.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 22.0

CD 40 CFR Section 60.49b(g) Maintain records of the following information: (1) Calendar date. (2) The average hourly nitrogen oxides emission rates (expressed as NO2) (ng/J or lb/million Btu heat input) measured or predicted. (3) The 30-day average nitrogen oxides emission rates (lb/mmBtu heat input) calculated at the end of each steam generating unit operating day from the measured or predicted hourly nitrogen oxide emission rates for the preceding 30 steam generating unit operating days. (4) Identification of the steam generating unit operating days when the calculated 30-day average nitrogen oxides emission rates are in excess of the nitrogen oxides emissions standards under 40 CFR Section 60.44b, with the reasons for such excess emissions as well as a description of corrective actions taken. (continued below) 23.0

CD 40 CFR Section 60.49b(g) (continued from above) (5) Identification of the steam generating unit operating days for which pollutant data have not been obtained, including reasons for not obtaining sufficient data and a description of corrective actions taken.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD 40 CFR Section 60.49b(v); Minn.

R. 7011.0565 The owner or operator of an affected facility may submit electronic quarterly reports for NOx in lieu of submitting the written reports. The format of each quarterly electronic report shall be coordinated with the MPCA. The electronic report(s) shall be submitted no later than 30 days after the end of the calendar quarter and shall be accompanied by a certification statement from the owner or operator, indicating whether compliance with the applicable emission standards and minimum data requirements of 40 CFR pt. 60, subp. Db was achieved during the reporting period. Before submitting reports in the electronic format, the owner or operator shall coordinate with the MPCA to obtain their agreement to submit reports in this

alternative format. 25.0

CD 40 CFR Section 60.49b(d); Minn.

R. 7011.0565 The Permittee shall record and maintain records of the amounts of each fuel combusted during each day and calculate the annual capacity factor individually for each fuel combusted for the reporting period. The annual capacity factor is determined on a 12-month rolling average basis with a new annual capacity factor calculated at the end of each calendar month. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 26.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 280 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 27.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 28.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 281 of 407

Subject Item: EU 127 Plant Air Compressor Diesel Engine - Reciprocating IC Engine

Associated Items: GP 127 Stationary Diesels (Compre ssion Ignition) Subject to MACT ZZZZ

SV 097 71C11 Diesel Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 17.4 lbs/hour using 24-hour Rolling Average (BACT Limit) 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 0.04 tons/year using 12-month Rolling Average 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 0.008 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

LIMIT Minn. R. 7011.2300, subp. 2 Sulfur Dioxide: less than or equal to 0.50 lbs/million Btu heat input using 3-hour Rolling Average (Compliance with the fuel sulfur content standard set forth below will demonstrate compliance with this requirement.) 7.0

LIMIT Minn. R. 7011.2300, subp. 1 Opacity: less than or equal to 20 percent opacity once operating temperatures have been attained. (visible air contaminants) 8.0

CD hdr OTHER LIMITS AND REQUIREMENTS 9.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operating Hours: less than or equal to 2,500 hours/year using 12-month Rolling

Sum 10.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Content of Fuel: less than or equal to 0.0015 percent by weight of diesel fuel. Certificate of Analysis retained onsite to meet ULSD standard satisfies this requirement. 11.0

CD hdr RECORDKEEPING REQUIREMENTS 12.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Emission Calculation and Recordkeeping for NOx BACT Limit: The Permittee shall calculate and record the 1-hour average (arithmetic mean) in 24-hour period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 13.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 14.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 15.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Recordkeeping of Hours of Operation for SO2 SIP Limit: By the 28th day of each month, the Permittee shall record and sum the hours of operation for EU 127 for each month and for the previous 12 months and record the 12-month rolling sum. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 282 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R. 7007.0800, subp. 5 Diesel Fuel Certification: The Permittee shall retain written documentation of each shipment of diesel fuel oil received for the diesel engine. The Permittee shall retain records demonstrating sulfur contents is less than 0.0015 percent by weight. Certificates of Analysis retained onsite to meet demonstrating generally that all FHR diesel meets the federal ULSD standard satisfies this requirement. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD hdr REPORTING REQUIREMENTS 18.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of NOx lb/hr limit. 19.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of diesel hours of operation. 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 283 of 407

Subject Item: EU 204 Steam Boiler #8 - Boiler

Associated Items: MR 093 71B8 O2 Analyzer to Monitor NOx Emissions

MR 094 71B8 Natural Gas Supply Flow Meter

SV 132 71B8 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21& Minn. R.

7007.3000 Nitrogen Oxides: less than 39.9 tons/year using 365-day Rolling Sum 2.0

LIMIT 40 CFR Section 60.40b; 40 CFR Section 60.44b; Minn. R.

7011.0565 Nitrogen Oxides: less than or equal to 0.20 lbs/million Btu heat input using 30-day Rolling Average including periods of startup, shutdown or malfunction. 3.0

LIMIT 40 CFR Section 60.40b(c); 40 CFR Section 104(a)(1); 40 CFR Section 60.8(c); Minn. R.

7011.0565 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average . Limit does not apply during startup, shutdown, or malfunction. (most stringent, meets limit set by Minn. R. 7011.1410, subp. 3(A)) 4.0

LIMIT 40 CFR Section 60.43b(h)(1); Minn. R. 7011.1410, subp. 3(B)(1) Total Particulate Matter: less than or equal to 0.030 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. This limit is more stringent than Minn. R. 7011.1410, subp. 3(B)(1). 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 14.3 lbs/hour using 3-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 14.3 lbs/hour using 24-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 50.0 tons/year using 12-month Rolling Average 8.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 14.3 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average ; except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this

limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn natural gas only. 13.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 158.5 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 14.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 284 of 407

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD hdr MONITORING REQUIREMENT 17.0

CD 40 CFR Section 60.13; 40 CFR Section 60.46b; 40 CFR Section
60.49b; Minn. R. 7011.0565; Minn. R. 7017.1010, subp. 1 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2 and use the most recent correlation based on performance test results to determine NOx lb/mmBtu emissions. 18.0

CD hdr RECORDKEEPING REQUIREMENTS 19.0

CD Title I Condition: To avoid classification as a major source

under 40 CFR Section 52.21 &

Minn. R. 7007.3000 NOx Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling sum NOx emissions in tons/yr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 20.0

CD 40 CFR Section 60.48b; 40 CFR Section 60.49b; Minn. R.

7011.0565 Recordkeeping: The Permittee shall record daily total amounts of each fuel combusted in the unit. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD 40 CFR Section 60.49b(d); Minn.

R. 7011.0565 Recordkeeping of the Annual Capacity Factor: The Permittee shall record and maintain records of the amounts of each fuel combusted during each day and calculate the annual capacity factor individually for natural gas for the reporting period. The annual capacity factor is determined on a 12-month rolling average basis with a new annual capacity factor calculated at the end of each calendar month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 22.0

CD 40 CFR Section 60.13(i); 40 CFR Section 60.46b; 40 CFR Section
60.49b; Minn. R. 7011.0565 NOx Recordkeeping: The Permittee shall calculate and record the daily and 30-day rolling average NOx emissions in lb/MMBtu. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 23.0

CD 40 CFR Section 60.13(i); 40 CFR Section 60.46b; 40 CFR Section
60.49b; Minn. R. 7011.0565 Recordkeeping: The Permittee shall record average hourly NOx emissions in lb/MMBtu for each steam operating day. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 24.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 25.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 26.0

CD hdr REPORTING REQUIREMENTS 27.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of NOx emission limits. 28.0

CD 40 CFR Section 60.19; 40 CFR Section 60.4; 40 CFR Section 60.49; Minn. R. 7007.0500, subp.
3; Minn. R. 7011.0565 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's). Cover letter certification, and summary of exceedances shall be submitted in hardcopy or electronic format; all other information may be submitted electronically. The report shall be certified per Minn. R. 7007.0500, subp. 3. 29.0

CD hdr PERFORMANCE TEST REQUIREMENTS 30.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 05/20/2012 to

measure NOx emissions from SV 132.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 285 of 407

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 05/20/2012 to

determine emission factor for CO.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 32.0

CD hdr CMS REQUIREMENT 33.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 34.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 35.0

CD hdr O2 MONITOR REQUIREMENTS 36.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 37.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 38.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 286 of 407

Subject Item: EU 209 Track 8 Rail Loading - Loading-Unloading Equipment

Associated Items: CE 002 Flaring

GP 017 Loading Rack Activities in CFP group limit

GP 057 Emission Units subject to Minn. R. built after June 11, 1973

MR 001 Pilot indicator for ZTOF at rail loading

MR 189 Temperature Indicator for 101H1

SV 001 RR Load to Stack

NC/

CA Type Citation Requirement

CD hdr SEE CAM AND POLLUTION CONTROL EQUIPMENT REQUIREMENTS UNDER

CE 002 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 287 of 407

Subject Item: EU 212 11H-6 - Refining Equipment

Associated Items: CE 074 SCR (Selective Catalytic Reduction)

MR 005 11H-6 CO Monitor

MR 006 11H6 NOx Monitor

MR 007 O2 Monitor for 11H6

MR 008 11H6 Fuel Gas Flowmeter

MR 198 11H6 Stack Temperature

SV 131 11H6 Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Carbon Dioxide Equivalent: less than or equal to 219,660 tons/year using 365-day Rolling Sum . For the first 364 days after start-up following modifications to the heater made as part of the #3 Crude/Coker Improvements permit, CO2e emissions are limited as determined by the following equation:

E=219,660 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after limit is effective (BACT Limit) 2.0

LIMIT Minn. R. 7007.0800, subp. 2 Carbon Dioxide Equivalent: less than or equal to 124.3 lbs/million Btu heat input using 12-month Rolling Average . This limit is effective following modifications to EU212 as part of the #3 Crude/Coker Improvements permit. Compliance with this limit can be demonstrated by firing strictly natural gas or by quantifying the average lb/mmBtu of the gaseous fuels fired over the operating period. 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Total Particulate Matter: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. (BACT Limit) 4.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 10 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour

A verage measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. (BACT Limit) 5.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 2.5 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. (BACT Limit) 6.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn R. 7007.3000 Sulfur Dioxide: less than or equal to 25.2 tons/year using 365-day Rolling Sum (Netting Limit). (most stringent, meets the limit set by Minn. R. 7011.1410, subp. 3(A)) 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 16.5 lbs/hour using 3-hour Rolling Average 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 16.5 lbs/hour using 24-hour Rolling Average 9.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 39.0 tons/year using 12-month Rolling Average 10.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 16.5 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 288 of 407

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21& Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 76.9 tons/year using 365-day Rolling Sum . This limit expires upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit. 12.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 16.5 tons/year using 365-day Rolling Sum . This limit is effective upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit.

For the first 364 days after start-up following modifications to the heater, NOx emissions are limited as determined by the following equation:

E=16.5 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after the limit is effective 13.0

LIMIT 40 CFR Section 60.102a(g)(2)(ii)(A) Nitrogen Oxides: less than or equal to 60 parts per million using 30-day Rolling

A verage (dry basis, corrected to 0 percent excess air) determined daily; or 14.0

LIMIT 40 CFR Section 60.102a(g)(2)(ii)(B) Nitrogen Oxides: less than or equal to 0.060 lbs/million Btu heat input using 30-day Rolling Average based on higher heating value (HHV), determined daily. This and the preceding NOx limit from 40 CFR pt. 60, subp. Ja are effective after start up following modifications to the heater made as part of the #3 Crude/Coker Improvements Permit. 15.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 10.0 tons/year using 365-day Rolling Sum , effective upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit.

For the first 364 days after start-up following modifications to the heater, CO emissions are limited as determined by the following equation:

E=10.0 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after limit is effective 16.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit does not apply during periods of startup, shutdown, or malfunction. (most stringent, meets the limit set by Minn. R. 7011.1410, subp. 3). This limit expires upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit. 17.0

LIMIT Minn. R. 7009.0080 Hydrogen Sulfide: less than or equal to 0.186 grains/dry standard cubic foot using 1-Hour Average (300 ppm). This is a state-only requirement and it is not enforceable by the EPA administrator or citizens under the Clean Air Act. 18.0

LIMIT 40 CFR Sections 60.8(c) and 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 162 parts per million using 3-hour Rolling

A verage , determined hourly. This limit does not apply during periods of startup, shutdown or malfunction. Limit is effective upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit; and, 19.0

LIMIT 40 CFR Sections 60.8(c) and 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 60 parts per million using 365-day Rolling

A verage , determined daily. This limit does not apply during periods of startup, shutdown or malfunction. Limit is effective upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit. 20.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 21.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.0075 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 22.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average ; except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this

limit. 23.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 289 of 407

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature: less than 350 degrees F using 365-day Rolling Average basis, excluding hourly periods of startup, shutdown, and low firing rates less than 246 mmBtu/hr HHV input (< 60% of maximum design capacity). This limit is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. (BACT Limit) 24.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 25.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 26.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the daily and 365-day Rolling Sum of NOx emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 28.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the daily and 365-day Rolling Sum of CO emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. This recordkeeping is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. 29.0

CD Title I Condition: 40 CFR Section 52.21(j)(3) & Minn. R. 7007.3000 SO2 Emission Calculation and Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling sum SO2 emissions from EU 212. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 30.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 31.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 32.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR pt. 98, subp. C Use methods in 40 CFR pt. 98, subp. C including flow monitoring of fuel usage and fuel gas analysis. Calculate emissions following procedures specified in 40 CFR pt. 98, subp. C with a conversion from metric tons to short tons. The Permittee shall calculate and record the daily and 365-day Rolling Sum of CO2e emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. This calculation and recordkeeping of daily and 365-day Rolling Sum of CO2e emissions in short tons is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. 33.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR Section 63.7540(a)(10)(i-vi) & (12) The Permittee shall conduct tune-ups in accordance with 40 CFR pt. 63, subp. DDDDD. Actions taken during each tune-up (burner inspection and cleaning, flame inspection and optimization, air-to-fuel ratio, CO optimization) will follow the schedule specified in Subpart DDDDD. The Permittee shall maintain records of annual heater tuning performed for compliance and may utilize normal business records for this purpose. This requirement is effective upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit. (BACT Limit) The initial tune-up shall be performed within 365 days of the effective date of this requirement. 34.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall record and maintain records of each fuel combusted in the unit on a monthly basis. For lbs CO2e/mmBtu heat input, use fuel gas analysis to calculate, record, and maintain the CO2e emissions value on a monthly average and 12-month rolling average basis, unless natural gas is fired strictly during the 12-month period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 35.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 290 of 407

CD 40 CFR Section 60.103a(c-e) RCFA and Corrective Action Requirements: The Permittee shall conduct a root cause analysis of any emission limit exceedance or process startup, shutdown, upset or malfunction that exceeds permitted SO2 emissions by 227 kilograms (kg) (500 lb) in any 24-hour period. For any root cause analysis performed, the Permittee shall record the identification of the affected facility, the date and duration of the discharge, the results of the root cause analysis and the action taken as a result of the root cause analysis.

A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). (continued below) 36.0

CD 40 CFR Section 60.103a(c-e) (continued from above) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable.

No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed date, and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). This requirement is effective upon startup of EU212 following modifications made as part of the #3 Crude/Coker Improvements permit. 37.0

CD hdr C. CEMS REQUIREMENTS FOR CO AND NOx 38.0

CD CAAA of 1990; Minn. R.
7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a NOx continuous emissions monitoring system (CEMS). 39.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a CO continuous emissions monitoring system (CEMS). 40.0

CD Minn. R. 7017.1006 CO and NOx Emissions Measuring: The Permittee shall use a CO CEMS and NOx

CEMS to measure CO and NOx emissions from SV 131. 41.0

CD Minn. R. 7017.1160, subps. 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 42.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 43.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 44.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix B and Appendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 45.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 46.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 47.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 48.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 49.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 291 of 407

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp 10(A)-(C) Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 50.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 51.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 52.0

CD hdr D. CMS REQUIREMENT 53.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 54.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 55.0

CD hdr E. O2 MONITOR REQUIREMENTS 56.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 57.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 58.0

CD hdr F. H2S MONITOR REQUIREMENTS (SEE GP 111) 59.0

CD hdr G. REPORTING REQUIREMENTS 60.0

CD Minn. R. 7017.1110, subps. 1 and

2 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of SO2 limit. 61.0

S/A 40 CFR Section 60.7(a)(4) Notification: due 60 days before Start Of Construction of any physical or operational change to EU 212 or as soon as practicable before the change is commenced and shall include the information describing the precise nature of the change, present and proposed emission control systems, productive capacity of the facility before and after the change, and the expected completion date of the change. The

A dministrator may request additional relevant information subsequent to this notice. This notification is required by 40 CFR Section 60.7(a)(4). 62.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 60.108a(b) Notification: due 15 days after Startup (actual date) of EU 212 following modifications made as part of the #3 Crude/Coker Improvements Permit. The notification shall include the specific monitoring provisions of Sections 60.105a, 60.106a and 60.107a with which the Permittee intends to comply. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 63.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 292 of 407

S/A 40 CFR Section 60.7(a)(5) Notification: due 30 days before Startup of the continuous monitoring system (CMS) following modifications made as part of the #3 Crude/Coker Improvements Permit. This notification is in accordance with 40 CFR Section 60.13(c). 64.0

CD 40 CFR Section 60.7(b) The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 65.0

CD 40 CFR Section 60.7(c) The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 66.0

CD 40 CFR Section 60.7(d) The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 67.0

CD hdr H. PERFORMANCE TESTING 68.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup following modifications to the furnace as part of the #3 Crude/Coker Improvements permit for PM emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 69.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup following modifications to the furnace as part of the #3 Crude/Coker Improvements permit for PM10 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 70.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c);Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup following modifications to the furnace as part of the #3 Crude/Coker Improvements permit for PM2.5 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 71.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for PM, PM10 and PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. 72.0

CD 40 CFR Section 60.104a(i)(1-8) The Permittee shall conduct an initial compliance performance demonstration for the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) following approved methods in

A ppendix A. The Permittee shall determine initial compliance with the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) according to the following test methods and procedures:

1) Method 1 of Appendix A-1 to pt. 60 for sample and velocity traverses; 2) Method 2 of Appendix A-1 to pt. 60 for velocity and volumetric flow rate; 3) Method 3, 3A or 3B of Appendix A-2 to pt. 60 for gas analysis. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60; (continued below) 73.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 293 of 407

CD 40 CFR Section 60.104a(i)(1-8) (continued from above) 5) Method 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for moisture content and for the concentration of NOx calculated as NO2; the duration of each test run must be no less than 4 hours. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 7 or 7C of

A ppendix A-4 to pt. 60. 7) The Permittee that elects to demonstrate continuous compliance with a maximum excess O2 limit shall determine heat input in mmBtu/hr during each performance test run by measuring fuel gas flow rate and heating value content. 8) The Permittee shall use Equation 8 of this section to adjust pollutant

concentrations to 0% O2 or 0% excess air. 74.0

CD 40 CFR Section 60.104a(j)(1-4) The Permittee shall determine compliance with the applicable H2S emissions limit in 40 CFR Section 60.103a(g)(1)(ii) according to the following test methods and procedures:

1) Method 1 of Appendix A-1 to pt. 60 for sample and velocity traverses; 2) Method 2 of Appendix A-1 to pt. 60 for velocity and volumetric flow rate; 3) Method 3, 3A or 3B of Appendix A-2 to pt. 60 for gas analysis. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60; 4)(iv) If monitoring is conducted at a single point in a common source of fuel gas as allowed under 40 CFR Section 60.107a(a)(2)(iv), only one performance test is required. That is, performance tests are not required when a new affected fuel gas combustion device or flare is added to a common source of fuel gas that previously demonstrated compliance. 75.0

CD hdr I. MONITORING REQUIREMENTS 76.0

CD 40 CFR Section 60.107a(a)(2) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration by volume (dry basis) of H2S in the fuel gases before being burned in any fuel gas combustion device or

flare.

i) Install, operate and maintain each H2S monitor according to Performance Specification 7 of Appendix B to pt. 60. The span value is 300 ppmv H2S. ii) Conduct performance evaluations for each H2S monitor according to the requirements of 40 CFR Section 60.13(c) and Performance Specification 7 of

A ppendix B to pt. 60. Use Method 11, 15 or 15A of Appendix A-5 to pt. 60 or Method 16 of Appendix A-6 to pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses" is an acceptable alternative to EPA Method 15A of Appendix A-5 to pt.

60. iii) Comply with the applicable quality assurance procedures in Appendix F to pt. 60

for each H2S monitor. (continued below) 77.0

CD 40 CFR Section 60.107a(a)(2) (continued from above) iv) Fuel gas combustion devices having a common source of fuel gas may be monitored at only one location, if monitoring at this location accurately represents the concentration of H2S in the fuel gas being burned in the respective fuel gas

combustion devices. 78.0

CD 40 CFR Section 60.107a(c) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0 percent excess air) of NOx emissions into the atmosphere according to the requirements below. The monitor must include an O2 monitor for correcting the data for excess

air.

1) Except as provided in paragraph (c)(6), the Permittee shall install, operate and maintain each NOx monitor according to Performance Specification 2 of Appendix B to pt. 60. The span value of this NOx monitor must be between 2 and 3 times the applicable emissions limit, inclusive. 2)The Permittee shall conduct performance evaluations of each NOx monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of Appendix B to pt. 60. The Permittee shall use Methods 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for conducting the relative accuracy evaluations. (continued below) 79.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 294 of 407

CD 40 CFR Section 60.107a(c) (continued from above) 2 (cont'd) The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60

. 3) The Permittee shall install, operate and maintain each O2 monitor according to Performance Specification 3 of Appendix B to pt. 60. The span value of this O2 monitor must be selected between 10 and 25 percent, inclusive. 4)The Permittee shall conduct performance evaluations of each O2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 3 of Appendix B to pt. 60. Method 3, 3A or 3B of Appendix A-2 to pt. 60 shall be used for conducting the relative accuracy evaluations. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60. (continued below) 80.0

CD 40 CFR Section 60.107a(c) (continued from above) 5) The Permittee shall comply with the quality assurance requirements in Procedure 1 of Appendix F to pt. 60 for each NOx and O2 monitor, including quarterly accuracy demonstrations for NOx monitors, annual accuracy determinations for O2 monitors and daily calibration drift tests. 81.0

CD 40 CFR Section 60.107a(d)(1-2) Except as provided in paragraph (d)(8), the Permittee shall install, operate and maintain each NOx monitor according to the requirements in paragraphs (c)(1) through (5). The monitor must include an O2 monitor for correcting the data for

excess air. Except as provided in paragraph (d)(3) the Permittee shall sample and analyze each fuel stream fed to the process heater using methods and equations in section 12.3.2 of EPA Method 19 of Appendix A-7 to pt. 60 to determine the F factor on a dry basis. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). 82.0

CD 40 CFR Section 60.107a(d)(3) and (7) A s an alternative to paragraph (d)(2), the Permittee shall install, operate and maintain a gas composition analyzer and determine the average F factor of the fuel gas using the factors in Table 1 and Equation 10 of this section. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). The Permittee shall determine the HHV of each fuel fed to the process heater using any of the applicable methods included in paragraphs (d)(7)(i)-(ix). If a common fuel supply system provides fuel gas to several heaters the HHV of the fuel in each fuel supply system may be determined at a single location in the fuel supply system provided it is representative of the fuel gas fed to the affected process heater(s). The HHV of each fuel must be determined no less frequently than once per day except as provided in paragraph (d)(7)(x). 83.0

CD 40 CFR Section 60.107a(i)(1)(ii) and (3) Excess Emissions: Excess emissions are defined as specified in paragraphs (i)(1) through (5) of this section. Determine a rolling 3-hour or a rolling daily average as the arithmetic average of the applicable 1-hour averages. Determine a rolling 30-day or a rolling 365-day average as the arithmetic average of the applicable daily averages.

For H2S limits in Section 60.102a(g)(1)(ii), each rolling 3-hour period during which the average H2S concentration as measured by the CMS required under paragraph (a)(2) exceeds 162 ppmv and each rolling 365-day period during which the average H2S concentration as measured by the CMS required under paragraph (a)(2) exceeds 60 ppmv.

Each rolling 30-day period during which the average NOx concentration as measured by the NOx CMS required under paragraph (c) or (d) exceeds:

ii) for a forced draft process heater, 60 ppmv and, if monitored, 0.060 lb/mmBtu

iv) the site-specific limit determined by the Administrator under Section 60.102a(i). 84.0

CD 40 CFR Section 60.107a(i)(4-5) Each day during which the concentration of NOx as measured by the NOx CMS required under paragraph (d) exceeds the daily average emissions limit calculated using Equation 3 in Section 60.102a(g)(2)(iii)(B) or Equation 4 in Section 60.102a(g)(2)(iv)(B).

Each day during which the concentration of O2 as measured by the O2 CMS required under paragraph (c)(6) exceeds the O2 operating limit or operating curve determined during the most recent biennial performance test. 85.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 295 of 407

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature Monitoring for SV 131 BACT Limit: Upon startup of EU 212 following modifications made as part of the #3 Crude/Coker Improvements permit, the Permittee shall monitor stack temperature by doing all of the following:

1) Continuously monitor the stack exit temperature; 2) Consider a stack exit temperature above 350 degrees F on a 24-hour average basis, excluding hourly periods of startup, shutdown and low firing rates less than 246 mmBtu/hr HHV input (< 60% of maximum design capacity), as an excursion that requires corrective action; (continued below) 86.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 (continued from above) 3) Upon detecting a stack exit temperature above 350 degrees F on a 24-hour average basis, FHR shall restore operation of the heater to its normal or usual manner of operation as expeditiously as practicable in accordance with good air pollution control practices for minimizing the period of any excursion and taking any necessary corrective actions to restore normal operation. Such actions may include heater adjustments or equipment maintenance; 4) Keep records of the continuous stack temperature measurements for at least five years and report excursions and a summary of response actions in FHR's Quarterly

A ir Quality and Excess Emissions Report. (continued below) 87.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 (continued from above) Excursions are events that require a response. Excursions are not violations and FHR shall not be considered out of compliance with the limit unless the stack exit temperature is above 350 degrees F on a 365-day rolling average basis, excluding hourly periods of startup, shutdown and low firing rates less than 246 mmBtu/hr HHV input (< 60% of maximum design capacity). 88.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 296 of 407

Subject Item: EU 213 #3 H2 Heater - Process Heater

Associated Items: MR 043 27H-501 NOx Analyzer

MR 044 27H-501 CO Analyzer

MR 048 27H501 Firebox O2 Analyzer

MR 050 27H-501 Natural Gas Supply Flow Meter

MR 058 27H501 PSA Purge Gas Flow

MR 115 Natural Gas Flowmeter to Pilots

SV 136 27H501 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 19.95 lbs/hour using 30-day Rolling Average . This limit applies at all times. (BACT Limit) 2.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.036 lbs/million Btu heat input using 30-day Rolling Average . This limit does not apply during periods of startup, shutdown, or during periods when the PSA purge gas is not available. (BACT Limit) 3.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 0.042 lbs/million Btu heat input using 24-hour Block Average . This limit does not apply during periods of startup, shutdown, or during periods when the PSA purge gas is not available. (BACT Limit) 4.0

LIMIT Title I Condition: To avoid classification as a major modification for NOx, 40 CFR

Section 52.21& Minn. R.

7007.3000 PM < 10 micron: less than or equal to 3.13 lbs/hour using 30-day Rolling Average 5.0

LIMIT Title I Condition: To avoid classification as a major modification, 40 CFR Section

52.21 & Minn. R. 7007.3000 Sulfur Dioxide: less than or equal to 4.54 lbs/hour using 30-day Rolling Average (most stringent limit, meets the limit set by Minn. R. 7011.1410, subp, 3) 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 36.6 lbs/hour using 3-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 36.6 lbs/hour using 24-hour Rolling Average 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 128.4 tons/year using 12-month Rolling

A verage 9.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 36.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 10.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm). This limit does not apply during periods of startup, shutdown, or malfunction. 11.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than 1.75 lbs/million Btu heat input using 3-hour Rolling

A verage . Compliance with the fuel restriction requirement constitutes compliance

with this limit. 12.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average ; except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this

limit. 14.0

CD hdr OTHER LIMITS AND REQUIREMENTS 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 297 of 407

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn PSA purge gas, refinery fuel gas and natural gas only. 16.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 449.5 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test

results from the MPCA. 17.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD hdr MONITORING REQUIREMENTS 20.0

CD Title Condition: 40 CFR Section 52.21(j)(3) & Minn. R. 7007.3000 Weekly Measurement of PSA Purge Gas: The Permittee shall measure higher heating value (HHV) of PSA purge gas during the initial testing schedule. If the standard deviation in HHV content is less than 10% after 3 months of sampling, the Permittee shall go to monthly sampling. 21.0

CD Title Condition: 40 CFR Section 52.21(j)(3) & Minn. R. 7007.3000 Monthly Measurement of PSA Purge Gas: The Permittee shall measure higher heating value (HHV) of PSA purge gas. If the standard deviation in HHV content is less than 10% after 3 months of weekly sampling and if the standard deviation in HHV content is less than 10% after 12 months of monthly sampling, go to semi-annual sampling. 22.0

CD Title Condition: 40 CFR Section 52.21(j)(3) & Minn. R. 7007.3000 Every Six (6) months Measurement of PSA Purge Gas: The Permittee shall measure higher heating value (HHV) of PSA purge gas during the final testing schedule. After 12 months of monthly sampling, if the standard deviation in HHV content is less than 10%, the Permittee shall use semi-annual sampling thereafter. 23.0

CD hdr RECORDKEEPING REQUIREMENTS 24.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emission Recordkeeping: The Permittee shall maintain records of the calculated NOx emissions hourly average of NOx emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 25.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 24-hour average lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 24-hour period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 26.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM10 Emission Calculation and Recordkeeping: The Permittee shall calculate and record daily PM10 emissions in lb/hr using performance test results. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 SO2 Emission Calculation and Recordkeeping: The Permittee shall calculate and record daily SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 28.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 29.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 30.0

CD hdr CEMS REQUIREMENTS FOR NOX AND CO 31.0MINNESOTA POLLUTION CONTROL AGENCY

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 298 of 407

CD CAAA of 1990; Minn. R.
7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a NOx continuous emissions monitoring system (CEMS). 32.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a CO continuous emissions monitoring system (CEMS). 33.0

CD Minn. R. 7017.1006 CO and NOx Emissions Measuring: The Permittee shall use a CO CEMS and NOx

CEMS to measure CO and NOx emissions from SV 136. 34.0

CD Minn. R. 7017.1160, subps. 1,2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 35.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 36.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 37.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 38.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 39.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 40.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 41.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 42.0

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp. 10(A)-(C) Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 43.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 44.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 45.0

CD hdr PERFORMANCE TEST REQUIREMENT 46.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 299 of 407

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 01/17/2012 for PM10 emissions. The next performance test required under this condition is to be completed by 01/17/2017.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 47.0

CD hdr O2 MONITOR REQUIREMENTS 48.0

CD Minn. R. 7007.0800, subp. 4 Firebox O2: The Permittee shall operate and maintain a CMS that records the firebox O2 at 27H501. Alternatively, FHR may install, certify, and operate a stack O2 CEMS in accordance with all requirements under MN Rules and Appendix B and Appendix F of 40 CFR pt. 60. 49.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The Permittee shall follow manufacturer's recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability including but not limited to annual calibrations. 50.0

CD hdr REPORTING REQUIREMENTS 51.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of NOx emission limits. 52.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of PM10 emission limit. 53.0

CD hdr CMS REQUIREMENTS 54.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 55.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer's recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 56.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 300 of 407

Subject Item: EU 228 FCCU - Refining Equipment

Associated Items: CE 004 Direct Flame Afterburner w/Heat Exchanger

CE 005 Direct Flame Afterburner w/Heat Exchanger

CE 006 Electrostatic Precip itator - Medium Efficiency

CE 068 Selective Noncatalytic Reduction for NOX

MR 017 17ME-187 FCC Common Stack Opacity Analyzer

MR 018 FCC Common Stack NOx Analyzer

MR 019 FCC Common Stack SO2 Analyzer

MR 021 FCC CO(%) in Flue Gas Monitor

MR 022 17H-2 Fuel Gas Flow Meter

MR 023 17H-4 Fuel Gas Flow Meter

MR 024 EMRC Flow for 17ME-187

MR 025 EMRC Temperature Thermocouple for 17ME-187

MR 106 FCC O2 Dry Percent

MR 107 FCC CO Low

MR 183 NH3 Slip CMS

SV 019 FCC Main Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Minn. Stat. Section 116.07, subds.
4a & 9; Minn. R. 7007.0100, subps. 7(A), 7(L), & 7(M); Minn. R. 7007.0800, subps. 1, 2 & 4; Minn. R. 7009.0010-7009.0080; SO2

MAAQS Sulfur Dioxide: less than or equal to 182.6 lbs/hour using 1-Hour Average . This is a state-only requirement and, pursuant to Minn. R. 7007.1750, it is not enforceable by the EPA administrator or citizens under the Clean Air Act. 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 182.6 lbs/hour using 3-hour Rolling Average .

The Permittee shall use CEMS to monitor the sulfur dioxide emissions in order to calculate pounds of sulfur dioxide per hour (lb/hr). 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 182.6 lbs/hour using 24-hour Rolling Average .

The Permittee shall use CEMS to monitor the sulfur dioxide emissions in order to calculate pounds of sulfur dioxide per hour (lb/hr). 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 800 tons/year using 12-month Rolling Average (This requirement is met by complying with the more stringent requirement of 800 tons/year using a 365-day rolling average.) 5.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than or equal to 800 tons/year using 365-day Rolling Sum 6.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Sulfur Dioxide: less than or equal to 25 parts per million by volume (at 0% oxygen) using 365-day Rolling Average. This limit was effective on December 31, 2003, with the initial calculation for compliance with the 365-day limit to be performed on December 30, 2004. (2001 EPA Consent Decree, as amended) 7.0

LIMIT Title I Condition: CAAA of 1990; 40 CFR Section 60.104(b)(1); Minn. R. 7007.0800, subp. 2 Sulfur Dioxide: less than or equal to 50 parts per million by volume (at 0% oxygen) using 7-day Rolling Average. This limit does not apply during periods of startup, shutdown, or malfunction. This limit replaces the requirement for daily samples for feed sulfur analysis to the FCCU or calculation of pounds of SO2 per 1000 pounds of coke burned. The compliance option under 40 CFR Section 60.104(b) may be changed at any time as long as the switch is carried out in accordance with 40 CFR Section 60.108(e) including required notification under 40 CFR Section 60.107(e) and beginning daily compliance tests under 40 CFR Section 60.106 at least 7 days prior to the change. (2001 EPA Consent Decree, as amended) 8.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 301 of 407

LIMIT 40 CFR Section 60.102(a)(1); 40 CFR Section 60.8(c); 40 CFR Section 63.1564(a)(1); 40 CFR Section 63.1564(c)(1); Minn. R. 7011.1410, subp. 1(A) Total Particulate Matter: less than or equal to 1.0 lbs/1000 lbs as demonstrated through stack test weighted average PM results relative to 40 CFR pt. 60, subp. J calculated coke burn-off in the catalyst regenerator during the test period. This limit does not apply during periods of startup, shutdown, or malfunction. Compliance with the most recent stack test for PM constitutes compliance with this limit. 9.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 169 tons/year using 365-day Rolling

Sum 10.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 142 tons/year using 365-day Rolling Sum 11.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 60 tons/year using 365-day Rolling Sum 12.0

LIMIT 40 CFR Section 60.103; 40 CFR Section 60.105; 40 CFR Section 60.8; Minn. R. 7011.1435; 40 CFR Section 63.1565(a)(1); 40 CFR Section 63.1565(c)(1) Carbon Monoxide: less than or equal to 500 parts per million by volume (dry basis) using a 1-hour Average. This limit does not apply during periods of startup, shutdown, or malfunction. 13.0

LIMIT Minn. R. 4410.4300, subp. 15. A., To avoid exceeding the mandatory

Environmental Assessment Worksheet Category for air

emissions Nitrogen Oxides: less than or equal to 500 tons/year using 365-day Rolling Sum . This is a state only requirement and is not enforceable by the EPA administrator or

citizens under the Clean Air Act. 14.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 450 parts per million using 24-hour Rolling

A verage (BACT Limit) 15.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Nitrogen Oxides: less than or equal to 859 lbs/hour using 24-hour Rolling Average (BACT Limit) 16.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 692 tons/year using 365-day Rolling Sum 17.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 27.5 parts per million using 365-day Rolling

A verage (operating day), by dry volume (at 0% oxygen). (2001 EPA Consen t Decree, as amended) 18.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1490, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies to the H2S content of fuel gas burned in Boiler 17H-2 (CE-004) and Boiler 17H-4 (CE 005) and does not apply during periods of startup, shutdown, or malfunction. Existing continuous H2S monitoring systems on the existing refinery fuel gas mix drums will be used to demonstrate compliance with this limit for refinery gas combusted in the

boilers. 19.0

LIMIT 40 CFR Section 60.102; 40 CFR Section 60.105; 40 CFR Section
60.11; Minn. R. 7011.1410; Minn. R. 7011.1435; 40 CFR Section 63.1564(a)(1); 40 CFR Section 63.1564(c)(1) Opacity: less than or equal to 30 percent opacity , except for one six-minute average opacity reading in any one hour period. Limit does not apply during periods of startup, shutdown, or malfunction. 20.0

CD hdr CEM REQUIREMENTS FOR SO2 21.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I Condition: CAAA of 1990; Minn.

R. 7017.1006 SO2 Emissions Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). (2001 EPA Consent Decree, as amended) 22.0

CD Title I Condition: CAAA of 1990;

Minn. R. 7017.1006 SO2 Emissions Measuring: The Permittee shall use a sulfur dioxide CEMS to measure sulfur dioxide emissions from SV 019. (2001 EPA Consent Decree, as amended) 23.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 302 of 407

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Title I

Condition: 40 CFR Section 52.21
& Minn. R. 7007.3000; Minn. R.

7017.1006 SO2 Emissions Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of the following:

1. The Permittee shall use the SO2 CEMS to calculate and record each 1-hour average concentration (dry, 0% oxygen, ppmv of SO2 from the FCCU);

2. The Permittee shall calculate and record the 7-day average (arithmetic mean) concentration of SO2 using all of the 1-hour average concentration values obtained during the previous seven successive 24-hour periods; and

3. The Permittee shall calculate and record the 365-day average (arithmetic mean) concentration of SO2 using all of the 1-hour average concentration values obtained during the previous 365-day period.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 24.0

CD hdr COMS REQUIREMENTS 25.0

CD 40 CFR Section 60.105(a); 40 CFR Section 63.1564(b)(1); Minn. R. 7011.1435(A); Minn. R. 7017.1010, subp. 1(A)-(C); Minn. R. 7011.1420, subp. 1(A)(1) Continuous Opacity Monitoring System (COMS): The Permittee shall calibrate, operate and maintain a continuous monitoring system for the measurement of opacity. 26.0

CD 40 CFR Section 63.1564(b)(1); Minn. R. 7017.1006; 40 CFR Section 64.6(c); 40 CFR Section 64.7(b); Minn. R. 7017.0200 Emissions Monitoring: The owner or operator shall use a COMS to measure opacity emissions from SV 019. 27.0

CD 40 CFR Section 64.6(c); Minn. R.

7017.1210 QA Plan Required: Develop and implement a written quality assurance plan that covers each COMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain the written procedures listed in Minn. R. 7017.1210, subp. 1. The plan shall include or reference the manufacturer's spare parts list for each COMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 28.0

CD Minn. R. 7017.1090, subp. 1; 40 CFR Section 60.13(e); 40 CFR Section 64.6(c); 40 CFR Section 64.7(c); Minn. R. 7017.0200 Continuous Operation: COMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A COMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 29.0

CD 40 CFR Section 60.13(d); 40 CFR Section 64.6(c); Minn. R. 7017.1210, subp 2 COMS Daily Calibration Drift (CD) Check: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) opacity at least once daily. The COMS must be adjusted whenever the calibration drift (CD) exceeds twice the specification of PS-1 of 40 CFR pt. 60, Appendix B. 30.0

S/A 40 CFR pt. 60, Appendix B; Minn. R. 7017.1210, subp. 3; 40 CFR Section 64.6(c) COMS Calibration Error Audit: due before end of each half-year starting 03/25/2008 Conduct three point calibration error audits at least 3 months apart but no greater than 8 months apart. Filter values used shall be determined in accordance with 40 CFR pt. 60, Appendix B. 31.0

S/A Minn. R. 7017.1220 COMS Calibration Error Audit Results Summary: due 30 days after end of each calendar half-year following COMS Calibration Error Audit 32.0

CD Minn. R. 7017.1200, subp. 1, 2 & 3; 40 CFR Section 60.13(e)(1); 40 CFR Section 60.13(h) A ll COMS shall complete a minimum of one cycle of sampling and analyzing for each successive 10-second period and one cycle of data for each successive 6-minute period. 33.0

CD 40 CFR Section 64.9(b); Minn. R.
7017.0200; Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all COMS monitoring data and supporting information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 34.0

CD hdr CEM REQUIREMENTS FOR CO 35.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 303 of 407

CD 40 CFR Section 63.1565(b)(1);

Minn. R. 7017.1006 Continuous Emission Monitoring System (CEMS): The Permittee shall calibrate, operate and maintain a continuous emissions monitoring system for the

measurement of CO emissions from SV 019. 36.0

CD Minn. R. 7017.1006 CO Calculations and Recordkeeping: The Permittee shall maintain records of the calculated CO emissions in pounds per hour (lb/hr). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 37.0

CD 40 CFR Section 60.105(a)(2); 40 CFR Section 63.1565(c)(1); Minn.

R. 7011.1435 CO Recordkeeping: The Permittee shall maintain records of the calculated hourly average of CO in ppm, on a dry basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 38.0

CD hdr CMS REQUIREMENTS FOR CO 39.0

CD 40 CFR Section 63.1565(b)(1);

Minn. R. 7017.1006 Continuous Monitoring System (CMS): The Permittee shall calibrate, operate and maintain a CMS for the measurement of CO emissions from the FCC Regenerator. 40.0

CD 40 CFR Section 63.1565(b)(1);

Minn. R. 7017.1006 FCC Regenerator Monitoring: The Permittee shall monitor the CO in FCC flue gas at outlet of the FCC Regenerator whenever the FCC CO boilers are bypassed. 41.0

CD 40 CFR Section 63.1565(b)(1);

Minn. R. 7017.1006 CMS QA/QC: Twice a week, the Permittee shall validate and, if necessary, calibrate CO flue gas analyzer installed at the outlet duct of the FCC Regenerator. 42.0

CD 40 CFR Section 63.1565(b)(1);

Minn. R. 7017.1006 CMS QA/QC: On an annual basis, the Permittee shall conduct a simple test to compare data from the flue gas analyzer whenever a relative accuracy test is

conducted on the CO CEMS on the ESP stack. The test shall consist of an instrumental (analyzer) method or and Orsat test depending on the concentration of

CO. 43.0

CD hdr CEM REQUIREMENTS FOR NOX 44.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Continuous Emission Monitoring System (CEMS): The Permittee shall calibrate, operate and maintain a continuous monitoring system for the measurement of nitrogen oxide (NOx). 45.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 NOx Emissions Measuring: The Permittee shall use NOx CEMS to measure nitrogen oxide emissions from SV 019. 46.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Emissions Calculation and Recordkeeping for BACT Limit: The Permittee

shall use the NOx CEMS to calculate and record NOx emissions from SV 019 in units of parts per million (ppm) and in units of pounds of NOx per hour (lb/hr). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 47.0

CD Minn. R. 7007.0800, subp. 5 NOx Emissions Recordkeeping: The Permittee shall record the daily and 365-day rolling average of NOx emissions for EU 228. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 48.0

CD hdr GENERAL REQUIREMENTS FOR ALL CEMS 49.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 50.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 51.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 52.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 53.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 54.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 55.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 304 of 407

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 56.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2. 57.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 58.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. 59.0

CD hdr PERFORMANCE TESTING REQUIREMENTS 60.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 60 months starting 11/03/2011 to measure PM emissions. The next performance test is due by 11/03/2016.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 61.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 11/03/2011 to measure PM10 emissions. The next performance test is due by 11/03/2014.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 62.0

CD Minn. R. 7007.0800, subp. 4 FCCU ESP (CE 006) Particulate Matter: FHR uses de-SOx catalyst at the FCCU. During PM10 stack testing at the FCCU (EU 228), which will occur at the intervals specified by MPCA guidance, FHR will apply de-SOx catalyst at an annualized average rate representative of normal operating conditions. FHR shall include the operating parameters used during normal operating conditions of the de-SOx catalyst system with all submitted PM10 performance test plans. 63.0

CD hdr OTHER REQUIREMENTS 64.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA as required by 2000 Global Consent Decree. 65.0

CD 40 CFR Section 60.105(a)(13); 40 CFR Section 60.106; Minn. R.

7011.1435 Monitoring FCC for ppm SO2 limit: If the Permittee is complying with FCC 50 ppmv SO2 limit, when FCC SO2 or O2 emissions data is not obtained because of CMS system breakdowns, repairs, calibration checks and zero and span adjustments, the Permittee shall obtain emissions data via alternate means to provide a minimum of 18 hours per day in at least 22 out of 30 rolling successive calendar days: i) The test methods as described in 40 CFR Section 60.106(k); ii) A spare continuous monitoring system; or iii) Other monitoring systems as approved by the MPCA. 66.0

CD CAAA of 1990; Minn. R. 7007.0800, subp. 5; Minn. R.

7011.1435 Monitoring FCC SO2 concentration: If the Permittee is complying with FCC SO2 concentration limit of 50 ppmv (dry, 0% oxygen), the Permittee shall monitor SO2 emissions in ppmvd SO2 (dry, 0% oxygen). (2001 EPA Consent Decree, as amended) 67.0

CD 40 CFR Section 60.108; Minn. R.
7011.1425; Minn. R. 7011.1430;

Minn. R. 7011.1435 Testing to Change Compliance Option: If the Permittee is changing FCC SO2 compliance option, the Permittee shall begin conducting daily tests as specified under 40 CFR Section 60.108(d) immediately upon electing to become subject to a different provision of 40 CFR Section 60.104(b). 68.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 305 of 407

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 5 PM10 Calculations and Recordkeeping: The Permittee shall calculate and record the 365-day rolling sum PM10 emissions using the most recent stack test emission factor until an MPCA approved ammonia slip versus PM10 correlation using the ammonia CMS in accordance with Minn. Rs. 7019.3040 to 7019.3100 is approved. The records may be maintained in either electronic or paper format, unless electronic or paper reports are expressly prohibited. 69.0

CD Minn. R. 7007.0800, subp. 2 The Permittee shall be allowed to propose an ammonia CMS correlation to quantify PM10 emissions in lieu of using a stack test emission factor. 70.0

CD Minn. R. 7007.0800, subp. 2; Minn. R. 7007.0800, subp. 16(J) A ir Pollution Control Equipment: Downtime of CE 004, CE 005, and/or CE 068 is not itself a deviation if the applicable permit limit requirement is met. 71.0

CD hdr O2 MONITOR REQUIREMENTS 72.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 73.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 74.0

CD hdr BYPASS MONITORING FOR PM EMISSIONS 75.0

CD A lternative Monitoring Plan to Comply with 40 CFR Section

60.13 CO Bypassed Emissions Recordkeeping: The Permittee shall record that the FCCU emissions exceed 1.0 lbs PM/1000 lb coke burn, when the FCCU CO boilers are bypassed.

The records may be maintained in either electronic or paper format, unless electronic or paper reports are expressly prohibited. 76.0

CD A lternative Monitoring Plan to Comply with 40 CFR Section

60.13 CO Bypassed Emissions Report: The Permittee shall submit a report to the MPCA, that the FCCU emission exceed 1.0 lbs PM/1000 lbs coke burn, that emissions are approximately 3 lbs PM/1000 lbs coke burn and that emissions exceed 30% opacity, when the FCCU CO boilers are bypassed. 77.0

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS 78.0

CD 40 CFR Section 63.1565(a); 40 CFR Section 63.1574(f); 40 CFR Section 63.1569(a); 40 CFR Section 63.1564(a)(3) The Permittee shall prepare and implement an operation, maintenance, and monitoring (OM&M) plan according to the requirements in 40 CFR Section 63.1574(f) and operate at all times according to the procedures in the plan. 79.0

CD hdr A MMONIA SLIP MONITOR REQUIREMENTS 80.0

CD Minn. R. 7007.0800, subp. 4 Stack Ammonia: When utilizing the approved ammonia slip correlation for compliance demonstration, the Permittee shall operate and maintain CMS that records the ammonia slip in the FCCU stack (SV 019). 81.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability. 82.0

CD hdr SEE COMPLIANCE ASSURANCE MONITORING REQUIREMENTS UNDER

CE006 83.0

CD hdr STARTUP, SHUTDOWN, AND MALFUNCTION PLAN (SSMP) REQUIREMENTS 84.0

CD 40 CFR Section 63.6(e)(1)(i)-(iii);
Minn. R. 7011.7280; Minn. R. 7017.2015, subp. 2(A)-(B) A t all times, including period of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 85.0

CD 40 CFR Section 63.6(e)(1)(ii); 40 CFR Section 63.6(e)(1)(iii); Minn.

R. 7011.7280 Correct malfunctions as soon as practicable in accordance with the SSMP. 86.0

CD 40 CFR Section 63.1570(d); 40 CFR Section 63.10(b)(2)(i)-(v); 40 CFR Section 63.6(e)(3)(iii)-(iv);

Minn R. 7011.7280 Record occurrence of startup, shutdown, and malfunction of process equipment or of malfunction or maintenance of air pollution control equipment. Document

conformance with or deviation from SSMP. 87.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 306 of 407

CD 40 CFR Section 63.1570(d); 40 CFR Section 63.6(e)(1)(iii); 40 CFR Section 63.6(e)(2); 40 CFR Section 63.6(e)(3)(i)-(ii); 40 CFR Section 63.6(e)(3)(v)-(vii); Minn. R.

7011.7280 Maintain up-to-date SSMP. 88.0

CD 40 CFR Section 63.6(e)(3)(viii);

Minn. R. 7011.7280 If a malfunction occurs that was not addressed in the SSMP, revise the SSMP within 45 days after the event. 89.0

CD 40 CFR Section 63.1569(a) & (c) Meet the requirements for bypass lines set forth in 40 CFR Section 63.1569. 90.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 307 of 407

Subject Item: EU 241 #1 H2 Plant Reformer/Heater - Process Heater

Associated Items: GP 055 Emission Units subject to Minn. R. built before June 11, 1973

MR 129 33H2 Fuel Gas Flowmeter

SV 073 33H1 2 Stack (33H4)

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 0.045 lbs/million Btu heat input using 3-hour Rolling Average (2001 EPA Consent Decree, as amended) 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 14.1 lbs/hour using 3-hour Rolling Average . This limit is applicable to EU240 and EU241. 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 14.1 lbs/hour using 24-hour Rolling Average . This limit is applicable to EU240 and EU241. 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 49.4 tons/year using 12-month Rolling Average . This limit is applicable to EU240 and EU241. 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 14.1 lbs/hour using 1-Hour Rolling Average . This limit is applicable to EU240 and EU241. The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA administrator or citizens under the Clean

A ir Act. 6.0

LIMIT Minn. R. 7011.1405, subp. 3(A) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 7.0

LIMIT Minn. R. 7011.1405, subp. 3(B) Opacity: less than or equal to 20 percent opacity using 6-minute Average except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1405, subp. 2 Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery gas and natural gas only. 11.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

LIMIT Minn. R. 7017.2025, subp. 3 Heat Input: less than or equal to 121.1 million Btu/hour using 8-hour Block Average based on the higher heating value (HHV) of fuel burned. Downtime of 15 or more minutes is not included as operating time.

The unit may not be operated at a higher input rate unless a performance test is conducted at a higher rate and the Permittee receives written verification of the test results from the MPCA. This limit applies unless the Permittee installs and certifies CEMS to directly measure NOx. 13.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping of Heat Input: The Permittee shall calculate the average heat input for each 8-hour block by dividing the total heat input by the total operating time in

each 8-hour block. Downtime of 15 or more minutes is not to be included as operating time. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD hdr MONITORING REQUIREMENTS 15.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 4 Monitoring for NOx emissions: The Permittee shall continuously monitor fuel

combustion rate and stack O2. The Permittee shall use the most recent correlation based on the performance test results to determine NOx lb/MMBtu emissions on an hourly basis. (2001 EPA Consent Decree, as amended) 16.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 17.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 308 of 407

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 NOx Emission Calculation and Recordkeeping: The Permittee shall calculate and record the 3-hour (arithmetic mean) lb/MMBtu of NOx using all of the 1-hour averages obtained during the previous 3-hour period. (2001 EPA Consent Decree, as amended).

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD Title I Condition: CAAA of 1990; Minn. R. 7007.0800, subp. 5 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances. (2001 EPA Consent Decree, as amended). 19.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 20.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 21.0

CD hdr PERFORMANCE TEST REQUIREMENT 22.0

S/A Minn. R. 7017.2020, subp. 1 Performance Test: due before end of each 36 months starting 11/09/2014 to

measure NOx emissions from SV 073.

For additional applicable performance test requirements see "General Performance Test Requirements" in Table A, subject item "Total Facility". 23.0

CD hdr CMS REQUIREMENTS 24.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 25.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 26.0

CD hdr O2 MONITOR REQUIREMENTS 27.0

CD Minn. R. 7007.0800, subp. 4 Firebox O2: The Permittee shall operate and maintain a CMS that records the

firebox O2. 28.0

CD Minn. R. 7007.0800, subp. 4 Monitor QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure analyzer reliability, including but not limited to annual calibrations. 29.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 309 of 407

Subject Item: EU 254 Unit 94H3-Thermal Oxidizer Back-up - Other Combustion

Associated Items: CE 029 Direct Flame Afterburner

CE 051 Other

MR 144 94H3 SO2 Analyzer

SV 146 94H3 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7007.0800, subp. 2 LIMIT APPLIES TO THE OSWTP DURING OPERATION OF EITHER EU 254 OR EU 282). EU 282 IS THE PRIMARY OSWTP OXIDIZER; EU 254 IS THE BACKUP.)

SEE ALL REQUIREMENTS UNDER EU 282. 1.0MINNESOTA POLLUTION CONTROL AGENCY

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Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 310 of 407

Subject Item: EU 276 Central Buffer Zone Offgas (86H41) - Refining Equipment

Associated Items: CE 057 Direct Flame Afterburner

MR 002 Natural Gas Flow to 86H41

MR 099 SVE System: Temperature Monitor for Central Buffer at 86H41

SV 143 86H41 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average . Limit does not apply during periods of startup, shutdown,

or malfunction. 2.0

CD hdr SEE POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS UNDER

CE 057. 3.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 311 of 407

Subject Item: EU 277 West Buffer Zone Offgas (88H2) - Refining Equipment

Associated Items: CE 033 Other (88H2)

CE 056 Direct Flame Afterburner

MR 100 SVE System: Temperature Monitor for West Buffer (88H2)

MR 140 Natural Gas 88H-2 SVE Oxidizer

SV 142 88H2 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMIT 1.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average . Limit does not apply during periods of startup, shutdown,

or malfunction. 2.0

CD hdr SEE POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS UNDER

CE 056. 3.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 312 of 407

Subject Item: EU 282 OSWTP - Thermal Oxidizer - Other Combustion

Associated Items: CE 028 Direct Flame Afterburner w/Heat Exchanger

CE 029 Direct Flame Afterburner

CE 051 Other

MR 101 94H1 & 94H3 Natural Gas Flow

MR 102 94H-1 Thermocouple for Fire Box Temperature

MR 103 Temperature Monitor (Stack) for 94H-3 Thermal Oxidizer

MR 104 94H1 SO2 Analyzer

MR 144 94H3 SO2 Analyzer

MR 145 Flow Meter for 94H1 Exhaust Gases

MR 146 Flow Meter for 94H3 Exhaust Gases

SV 125 94H1 Stack

SV 146 94H3 Stack

NC/

CA Type Citation Requirement

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y EMISSION LIMITS (LIMITS APPLY TO THE OSWTP DURING OPERATION OF EITHER EU 254 OR EU 282). EU 282 IS THE PRIMARY OSWTP OXIDIZER; EU 254 IS THE BACKUP.)

Except when switching WWTP gases from one oxidizer to the other, only one oxidizer may combust gases from OSWTP equipment at a time. The other oxidizer may be fired concurrently with natural gas for standby purposes. 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 50.71 lbs/hour using 3-hour Rolling Average 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 50.71 lbs/hour using 24-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 39.4 tons/year using 12-month Rolling Average 4.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 50.71 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 5.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Operational Restriction: The Permittee shall only operate one oxidizer at a time. 6.0

LIMIT Title I Condition: Limit to avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Dioxide: less than or equal to 38.0 tons/year using 365-day Rolling Sum for emissions from the combustion of waste gas. This limit shall be effective upon the completion of initial certification of the SO2 CEMS.

For the first 365 days after initial certification of the SO2 CEMS, SO2 emissions in tons/year are limited as determined by the following equation: E = 38.0 [0.15 + 0.85(D/365)]

where E = SO2 emissions in total tons since startup D = number of day after startup 7.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Volatile Organic Compounds: less than or equal to 3.42 lbs/hour using 365-day Rolling Average . This limit includes VOC emissions from the API separator, basins 7A and 7B, and the thermal oxidizers. (Netting Limit) 8.0

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.105(e)(3)(ii); 40 CFR Section 60.8(c); Minn. R. 7011.1420, subp. 2; Minn. R. 7011.1435(A) Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm[162 ppm]). This limit applies to the H2S content of fuel gas burned in CE 028 and CE 029 and does not apply during periods of startup, shutdown, upset and malfunction provided that during such periods good air pollution control practices are implemented. 9.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 313 of 407

LIMIT Minn. R. 7011.0110; Minn. R.

7011.0120 Opacity: less than or equal to 20 percent opacity 10.0

LIMIT Title I Condition: Limit to avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Fuel Usage: less than or equal to 625 million cubic feet/year using 365-day Rolling Sum of natural gas consumption. 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Fuel Restriction: The Permittee shall burn natural gas in conjunction with oxidation of gases from OSWTP equipment. 12.0

CD hdr RECORDKEEPING AND CALCULATIONS REQUIREMENTS 13.0

CD Minn. R. 7007.0800, subp. 5 Hourly SO2 Emissions: The Permittee shall use the SO2 CEMS and the stack gas flow meters to calculate and record each 1-hour average SO2 lb/hr emission rate from EU 282 OR EU 254. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 14.0

CD Minn. R. 7007.0800, subp. 5 Daily SO2 Emissions: The Permittee shall calculate and record daily and a 365-day rolling average of the SO2 emissions from EU 282 OR EU 254 for the previous 365-day period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 15.0

CD Minn. R. 7007.0800, subp. 5 Monthly SO2 Emissions: The Permittee shall calculate and record the monthly and 12-month rolling average SO2 emissions from EU 282 OR EU 254. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 18.0

CD Minn. R. 7007.0800, subp. 5 Fuel Usage Recordkeeping: The Permittee shall calculate and record daily and 365-day rolling sum of the total natural gas consumption from EU 282 OR EU 254 for the previous 365-day period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 19.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 VOC Recordkeeping Associated with Netting Limit: The Permittee shall record the daily VOC emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 20.0

CD hdr OTHER REQUIREMENT 21.0

CD Minn. R. 7007.0800, subp. 2 Conduct Root Cause Failure Analysis (RCFA): The Permittee shall comply with the RCFA as required by 2000 Global Consent Decree. 22.0

CD 40 CFR Section 61.349(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Control device and closed vent system must be operated at all times when waste is in the waste management unit vented to the control device. 23.0

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Maintain compliance with design, equipment, work practice, operational standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 24.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 314 of 407

CD 40 CFR Section 61.349(a)(2); 40 CFR 60.692-5(a); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The control device shall be designed and operated in accordance with the following

conditions:

(i) An enclosed combustion device (e.g., a vapor incinerator, boiler, or process heater) shall meet one of the following conditions:

(A) Reduce the organic emissions vented to it by 95 weight percent or greater;

(B) Achieve a total organic compound concentration of 20 ppmv (as the sum of the concentrations for individual compounds using Method 18) on a dry basis corrected to 3 percent oxygen; or

(C) Provide a minimum residence time of 0.5 seconds at a minimum temperature of 760 °C (1,400 °F). If a boiler or process heater issued as the control device, then the vent stream shall be introduced into the flame zone of the boiler or process

heater. 25.0

CD 40 CFR Section 61.349(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) If visible defects are observed during an inspection, or if other problems are identified, or if detectable emissions are measured, a first effort to repair the closed-vent system and control device shall be made as soon as practicable but no later than 5 calendar days after detection. Repair shall be completed no later than 15 calendar days after the emissions are detected or the visible defect is observed. 26.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR 60.692-6; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) a) Delay of repair of facilities or units will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 27.0

CD hdr MONITORING REQUIREMENTS 28.0

CD 40 CFR Section 61.349(a)(1)(i); 40 CFR 60.692-5(e)(1). Closed vent system and control device shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring. Closed vent systems and control devices subject to NSPS QQQ (e.g. the oil-water separator closed vent system piping to the thermal oxidizers and the thermal oxidizer control devices) shall be monitored semi-annually.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 29.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR 60.696(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements:

(1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 30.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR 60.696(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be:

(i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 31.0

CD 40 CFR Section 61.349(f); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Each closed-vent system and control device shall be visually inspected quarterly. The visual inspection shall include inspection of ductwork and piping and

connections to covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. 32.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 315 of 407

CD 40 CFR Section 61.349(a)(1); 40 CFR Section 61.355(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Vent systems that contain any bypass line that could divert the vent stream away from a control device shall install, maintain, and operate according to the manufacturer's specifications a flow indicator that provides a record of vent stream flow away from the control device at least once every 15 minutes OR ensure the bypass line valve is closed by securing with a car-seal or lock-and-key type device. Exception is for a vent to atmosphere that remains in a closed, sealed position during normal operations except when the device needs to open to prevent physical damage or permanent deformation of the closed-vent system resulting from malfunction of the unit in accordance with good engineering and safety practices for handling flammable, explosive, or other hazardous materials. 33.0

CD 40 CFR Section 61.354(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Owners or operators using a closed-vent system that contains any bypass line that could divert a vent stream from a control device shall do the following: (1) Visually inspect the bypass line valve at least once every month, checking the position of the valve and the condition of the car-seal or closure mechanism required under 40 CFR Section 61.349(a)(1)(ii) to ensure that the valve is maintained in the closed position and the vent stream is not diverted through the bypass line.

(2) Visually inspect the readings from each flow monitoring device required by 40 CFR Section 61.349(a)(1)(ii) at least once each operating day to check that vapors are being routed to the control device as required. 34.0

CD 40 CFR Section 61.349(h); 40 CFR Section 61.354(c); 40 CFR Section 61.354(c)(1); 40 CFR 60.695(a)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified below, unless alternative monitoring procedures or requirements are approved. Inspect at least once each operating day the data recorded by the monitoring equipment to ensure that the control device is operating properly.

(1) For a thermal vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The device shall have an accuracy of ±1 percent of the temperature being monitored in °C or ±0.5 °C, whichever is greater. The temperature sensor shall be installed at a representative location in the combustion

chamber. 35.0

CD hdr CEM REQUIREMENTS FOR SO2 36.0

CD 40 CFR Section 60.105(a)(4); Minn. R. 7007.0800, subp. 4 SO2 Emissions: The Permittee shall use the combination of the stack flow meter(s)

and SO2 CEMS to measure SO2 emissions from SV 125 or SV 146. 37.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 38.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 39.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 40.0

S/A Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS Relative Accuracy Test Audit (RATA) 41.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 42.0

CD Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 43.0

CD 40 CFR pt. 60, Appendix F, Section 4.1; 40 CFR 60.13(d)(1); Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 44.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 316 of 407

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2. 45.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix. F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction, the time required to obtain the part, and other pertinent factors. 46.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 47.0

CD 40 CFR Section 60.7(b) Records of Startup, Shutdown or Malfunction: Any owner or operator subject to the provisions of NSPS shall maintain records of the occurrence and duration of any startup, shutdown, or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a which a continuous monitoring system or monitoring device is inoperative. 48.0

CD hdr SEE POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS UNDER

CE 028. 49.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 317 of 407

Subject Item: EU 296 No. 4 Hydrogen Plant Reformer - Refining Equipment

Associated Items: GP 003 ULSD Project CO Emissions

GP 004 ULSD Project VOC Emissions

SV 166 New Hydrogen Plant Reformer Furnace

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 157.7 tons/year using 365-day Rolling Sum 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 69.4 lbs/hour using 3-hour Rolling Average 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 69.4 lbs/hour using 24-hour Rolling Average 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 243.3 tons/year using 12-month Rolling

A verage 5.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 69.4 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 6.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The total emissions of sulfur dioxide from all existing and new fuel gas combustion devices and indirect heating equipment shall be divided by the total heat input of all such devices and equipment to determine compliance with this part; provided that no owner or operator shall cause to be discharged from any one unit of new indirect heating equipment any gases which contain sulfur dioxide in excess of 3.0 pounds per million Btu heat input. 7.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity ; except for one six-minute period per hour of not more than 60% opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 9.0

CD hdr OTHER LIMITS AND REQUIREMENTS 10.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21& Minn. R.

7007.3000 Fuel Restriction: Burn refinery fuel gas, natural gas or PSA purge gas only in the

unit. 11.0

CD Minn. R. 7007.0800, subp. 2 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

CD hdr CEM REQUIREMENTS FOR NOx 13.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 5 Emissions Monitoring: The Permittee shall use a nitrogen oxides (NOx) CEMS to

measure NOx emissions from SV 166. 14.0

CD 40 CFR Section 63.8(d) CMS Quality Control (QC) Program: The Permittee shall development and implement a CEMS QC program and keep records of such procedures of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F shall be used to determine out-of-control periods for CEMS. 15.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 318 of 407

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 16.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 17.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 18.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 19.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar half-year following Cylinder Gas Audit 20.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 21.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 22.0

CD Minn. R. 7017.1090, subps. 1 and

2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2 23.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 24.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 25.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 26.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 NOx Calculation and Recordkeeping: The Permittee shall calculate and record the daily and 365-day rolling sum NOx emissions from EU 296 and EU 295. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 28.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 29.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 319 of 407

Subject Item: EU 312 No. 6 Cooling Tower Diesel Pump - Reciprocating IC Engine

Associated Items: GP 011 Diesel Engines with SIP Conditions and <83.3 hr/mon

MR 187 Catalyst Inlet temperature for #6 CT Diesel Pump (81TI8210)

MR 188 Catalyst Bed Differential Pressure for #6 CT Diesel Pump (81PDT8211)

SV 171 No. 6 Cooling Tower Diesel Pump

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Minn. R. 7011.2300, subp. 2 Sulfur Dioxide: less than or equal to 0.50 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the fuel sulfur content standard set forth below will demonstrate compliance with this requirement. 2.0

LIMIT Minn. R. 7011.2300, subp. 1 Opacity: less than or equal to 20 percent opacity once operating temperatures have been attained. (visible air contaminants) 3.0

CD hdr OTHER LIMITS AND REQUIREMENTS 4.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Operating Hours: less than or equal to 1,000 hours/year using 12-month Rolling

Sum 5.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Sulfur Content of Fuel: less than or equal to 0.050 percent by weight of diesel fuel. Certificate of Analysis retained onsite demonstrating generally that all FHR diesel meets the federal ULSD standard satisfies this requirement. 6.0

CD hdr RECORDKEEPING RQUIREMENTS 7.0

CD Minn. R. 7007.0800, subp. 5 Diesel Fuel Certification: The Permittee shall retain records demonstrating sulfur contents is less than 0.050 percent by weight. Certificates of Analysis retained onsite demonstrating generally that all FHR diesel meets the federal ULSD standard satisfies this requirement. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited 8.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping of Hours of Operation: By the 28th day of each month, the Permittee shall record the hours of operation and 12-month rolling sum for the previous month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0

CD hdr NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS 10.0

CD 40 CFR Section 63.6600(d); 40 CFR pt. 63, subp. ZZZZ,Tables 2c and 5b; 40 CFR Section 63.6640(a); 40 CFR pt. 63, subp.
ZZZZ, Tables 2a and 3a; Minn. R.

7011.8150 Emissions Limitations: Reduce CO emissions by 70 percent or more. 11.0

CD 40 CFR Section 63.6600(d); 40 CFR pt. 63, subp. ZZZZ, Tables 1a and 2b; 40 CFR Section 63.6630(b); Minn. R. 7011.8150 Operating Limitations: Maintain the catalyst so that the pressure drop across the catalyst does not change by more than 2 inches of water at 100 percent load (plus or minus 10 percent load) from the pressure drop across the catalyst that was measured during the initial performance test. 12.0

CD 40 CFR Section 63.6600(d); Tables 1b and 2b; 40 CFR Section 63.6630(b); Minn. R. 7011.8150 Operating Limitations: Maintain the temperature of the stationary RICE exhaust so that the catalyst inlet temperature is greater than or equal to 450 degrees F and less than or equal to 1350 degrees F. 13.0

CD 40 CFR Section 63.6604; 40 CFR Section 80.510(b); Minn. R.

7011.8150 Diesel Fuel Requirements: Sulfur content 500 ppm maximum and Cetane index or aromatic content as follows: (I) a minimum cetane index of 40 or (ii) a maximum aromatic content of 35 volume percent. Compliance with this requirement can be demonstrated by retaining FHR Certificate of Analysis generally demonstrating that diesel fuel produced by FHR meets this requirement. 14.0

CD 40 CFR Section 63.6615; 40 CFR pt. 63, subp. ZZZZ, Table 3.1
Footnote 1; Minn. R. 7011.8150 Conduct performance tests annually. If the results of any subsequent annual performance test indicate the stationary RICE is not in compliance with the CO emission limitation, or the Permittee deviates from any of the operating limitations, the Permittee must resume semiannual performance tests. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 320 of 407

CD 40 CFR Section 63.6620; Table 4.1(i) and (ii); Footnote a Performance Tests: Measure the O2 at the inlet and outlet of the control device and measure the CO at the inlet and the outlet of the control device using portable CO and O2 analyzers: following the methods listed in Table 4. 16.0

CD 40 CFR Section 63.8(c)(1) Operation and maintenance of continuous monitoring systems: Maintain and operate each CMS/CPMS as specified in 40 CFR Section 63.6(e)(1); Must keep the necessary parts for routine repairs of the CMS equipment readily available. 17.0

CD 40 CFR Section 63.6625(b); 40 CFR pt. 63, subp. ZZZZ, Table 5; 40 CFR Section 63.8; Minn. R.

7011.8150 Monitoring Requirements: Maintain a site-specific monitoring plan that addresses the monitoring system design, data collection and the quality assurance and quality control elements as outlined in 40 CFR Section 63.6625 (b)(1)(i) through (v) and in 40 CFR Section 63.8 (d). The applicable date for the requirement to prepare a site-specific monitoring plan was September 6, 2011, and completed by FHR. 18.0

CD 40 CFR Section 63.6625(b)(3);

40 CFR Section 63.6635 Monitoring Requirements: The CPMS must collect data at least once every 15

minutes. 19.0

CD 40 CFR Section 63.6625(b)(4) Monitoring Requirements: For a CPMS for measuring temperature range, the temperature sensor must have a minimum tolerance (maximum inaccuracy) of 5 degrees F or 1 percent of the measurement range, whichever is larger. 20.0

CD 40 CFR Section 63.6625(b)(5) and (6) Conduct the CPMS equipment performance evaluation, system accuracy audits, or other audit procedures specified in the site-specific monitoring plan at least annually. 21.0

CD 40 CFR Section 63.6640(a); 40 CFR pt. 63, subp. ZZZZ, Table
6.1; Minn. R. 7011.8150 Collect the catalyst inlet temperature data and reduce data to 4 hour rolling averages and maintain the 4 hour rolling averages within the operating limitations for the catalyst inlet temperature. 22.0

CD 40 CFR Section 63.6640 (a); 40 CFR pt. 63, subp. ZZZZ, Table
6.1; Minn. R. 7011.8150 Measure the pressure drop across the catalyst at least once per month and demonstrate that the pressure drop across the catalyst is within the operating limitation established during the performance test. 23.0

CD 40 CFR Section 63.6640(b); Minn.

R. 7011.8150 If the Permittee changes the catalyst, the facility must reestablish the values of the operating parameters measured during the initial performance test. When the facility reestablishes the values of the operating parameters, the facility must also conduct a performance test to demonstrate that the facility is meeting the required emission limitation applicable to the stationary RICE. 24.0

CD 40 CFR Section 63.6625(g); Minn.

R. 7011.8150 Install closed crankcase ventilation system or open crankcase filtration emission control system to filter oil mist, particulates and metals. Must follow manufacturer's instructions for maintenance of the appropriate crankcase. 25.0

CD 40 CFR Section 63.6625(h); Minn.

R. 7011.8150 Minimize the engine's time spent at idle during startup and minimize the engine's startup time to a period needed for appropriate and safe loading of the engine, not to exceed 30 minutes, after which the emission standards applicable to all times other than startup apply. 26.0

CD 40 CFR Section 63.6645(a); 40 CFR Section 63.6645 (g); 40 CFR Section 63.7 (b); 40 CFR Section 63.8(e)(2), 40 CFR Section 63.9(e); Minn. R. 7011.8150 Notification Submittals: Submit a Notification of Intent to conduct a performance test and site-specific performance evaluation test plan at least 60 days before the performance test is scheduled to begin as required in 40 CFR Section 63.7(b)(1) or as required by delegated authority (MPCA). 27.0

CD 40 CFR Section 63.6650(c) throug h (e); 40 CFR pt. 63. subp. ZZZZ,

Table 7.1. 40 CFR Section 63.6640 (e); Minn. R. 7011.8150 Compliance report must contain all the information as described in 40 CFR Section 63.6650(c) through (e) as applicable. Report each instance in which the Permittee did not meet the requirements of the general provisions in 40 CFR pt. 63, subp. ZZZZ, Table 8 that applies. 28.0

CD 40 CFR Section 63.10(d)(2) Submit performance test results within 60 days following the completion of the performance test, or sooner, if required by delegated authority. 29.0

CD 40 CFR Section 63.6655; 40 CFR Section 63.10(b); Minn. R.

7011.8150 General Recordkeeping Requirements: The owner or operator shall maintain files of all information (including all reports and notifications) required by 40 CFR pt. 63 subp. ZZZZ, recorded in a form suitable and readily available for expeditious inspection and review including all information required by 40 CFR Section 63.10(b). The files shall be kept for at least five (5) years following the date of each occurrence, measurement, maintenance, corrective action, report or record. 30.0

CD 40 CFR Section 63.8 (c); 40 CFR Section 63.6 (e) (1); 40 CFR Section 63.6605; Minn. R.

7011.8150 A t all times, including periods of startup, shutdown, and malfunction, operate and maintain equipment and associated air pollution control equipment, in a manner consistent with good air pollution control practices for minimizing emissions. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 321 of 407

Subject Item: EU 313 Steam Boiler No. 9 - Boiler

Associated Items: SV 173 Boiler No. 9 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 2 Nitrogen Oxides: less than or equal to 46.3 tons/year using 365-day Rolling Sum 2.0

LIMIT 40 CFR Section 60.44b(a) Nitrogen Oxides: less than or equal to 0.20 lbs/million Btu heat input using 30-day Rolling Average (expressed as NO2), if the unit is a high heat release rate unit. A "high heat release rate" is defined as a heat release rate greater than 70,000

Btu/hour-cubic foot. 3.0

LIMIT 40 CFR Section 60.44b(a) Nitrogen Oxides: less than or equal to 0.10 lbs/million Btu heat input using 30-day Rolling Average (expressed as NO2), if the unit is a low heat release rate unit. A "low heat release rate" is defined as a heat release rate of 70,000 Btu/hr-cubic foot

or less.

The 30-day rolling average emission rate is calculated as the average of all hourly emissions data recorded by the monitoring system during the 30 day period. A new 30 day rolling average emission rate is calculated each steam generating unit operating day. 4.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7007.0800, subp. 2 Hydrogen Sulfide: less than or equal to 90 parts per million using 365-day Rolling

A verage by volume. 5.0

LIMIT 40 CFR Section 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm[162 ppm]). This limit applies to the hydrogen sulfide content of fuel gas burned in the units. Existing continuous H2S monitoring systems on the existing refinery gas mix drums will be used to demonstrate compliance with this limit. 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 3-hour Rolling Average 7.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 24-hour Rolling Average 8.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 23.5 tons/year using 12-month Rolling Average 9.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 9.9 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The total emissions of sulfur dioxide from all existing and new fuel gas combustion devices and indirect heating equipment shall be divided by the total heat input of all such devices and equipment to determine compliance with this part; provided that no owner or operator shall cause to be discharged from any one unit of new indirect heating equipment any gases which contain sulfur dioxide in excess of 3.0 pounds per million Btu heat input. 11.0

LIMIT 40 CFR Section 60.43b(h)(1); Minn. R. 7011.1410, subp. 3(B)(1) Total Particulate Matter: less than or equal to 0.030 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lb/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. This limit is more stringent than Minn. R. 7011.1410, subp. 3(B)(1). 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 322 of 407

LIMIT Minn. R. 7011.1410, subp. 3(B)(2) Opacity: less than or equal to 20 percent opacity ; except for one six-minute period per hour of not more than 60% opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

CD hdr OTHER LIMITS AND REQUIREMENTS 14.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Fuel Restriction: Burn refinery fuel gas or natural gas only in the unit. 15.0

CD Minn. R. 7007.0800, subp. 2 Recordkeeping: Record and maintain records of each type of fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD hdr CEM REQUIREMENTS FOR NOx 17.0

CD 40 CFR Section 60.48b; Minn. R.

7017.1006 Emissions Monitoring: The Permittee shall use a nitrogen oxides (NOx) CEMS to measure NOx emissions from SV 173. Specifications for the operation of the monitoring equipment are in 40 CFR Section 60.48b(c), (d), (e), (f), and Appendix

B. 18.0

CD Minn. R. 7017.1006 The Permittee shall operate a NOx CEMS. The operation of the CEMs will meet the performance requirements as specified in 40 CFR Section 60.46b. 19.0

CD 40 CFR Section 60.7(b) Records of Startup, Shutdown, or Malfunction: Any owner or operator subject to the provisions of 40 CFR pt. 60, subp. Db, shall maintain records of the occurrence and duration of any startup, shutdown, or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system or monitoring device is inoperative. 20.0

CD 40 CFR Section 63.8(d) CMS Quality Control (QC) Program: The Permittee shall development and implement a CEMS QC program and keep records of such procedures of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F shall be used to determine out-of-control periods for CEMS. 21.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 22.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 23.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 24.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 25.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar half-year following Cylinder Gas Audit 26.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 27.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 28.0

CD 40 CFR Section 63.8(c)(1); 40 CFR Section 60.13(e); Minn. R. 7017.1090, subps. 1 and 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2. 29.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 323 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 30.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 31.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 32.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 NOx Calculation and Recordkeeping: The Permittee shall calculate and record the daily NOx emissions and 365-day rolling sum of NOx emissions. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 33.0

CD 40 CFR Section 60.49b(g) Maintain records of the following information: (1) Calendar date. (2) The average hourly nitrogen oxides emission rates (expressed as NO2) (ng/J or lb/million Btu heat input) measured or predicted. (3) The 30-day average nitrogen oxides emission rates (lb/mmBtu heat input) calculated at the end of each steam generating unit operating day from the measured or predicted hourly nitrogen oxide emission rates for the preceding 30 steam generating unit operating days. (4) Identification of the steam generating unit operating days when the calculated 30-day average nitrogen oxides emission rates are in excess of the nitrogen oxides emissions standards under Section 60.44b, with the reasons for such excess emissions as well as a description of corrective actions taken. (5) Identification of the steam generating unit operating days for which pollutant data have not been obtained, including reasons for not obtaining sufficient data and a description of corrective actions taken. 34.0

CD 40 CFR Section 60.49b(v) The owner or operator of an affected facility may submit electronic quarterly reports for NOx in lieu of submitting the written reports. The format of each quarterly electronic report shall be coordinated with the MPCA. The electronic report(s) shall be submitted no later than 30 days after the end of the calendar quarter and shall be accompanied by a certification statement from the owner or operator, indicating whether compliance with the applicable emission standards and minimum data requirements of 40 CFR pt. 60, subp. Db was achieved during the reporting period. Before submitting reports in the electronic format, the owner or operator shall coordinate with the MPCA to obtain their agreement to submit reports in this

alternative format. 35.0

CD 40 CFR Section 60.49b(d) The Permittee shall record and maintain records of the amounts of each fuel combusted during each day and calculate the annual capacity factor individually for each fuel combusted for the reporting period. The annual capacity factor is determined on a 12-month rolling average basis with a new annual capacity factor calculated at the end of each calendar month. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 36.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 37.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 38.0

CD hdr CMS REQUIREMENTS 39.0MINNESOTA POLLUTION CONTROL AGENCY

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ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 324 of 407

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 40.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 41.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 325 of 407

Subject Item: EU 324 #3 Crude Unit Vacuum Heater - Process Heater

Associated Items: MR 152 NOx Monitor at 25H4

MR 153 CO Monitor at 25H4

MR 154 O2 Monitor at 25H4

MR 155 Fuel Gas Flow Meter at 25H4

SV 176 25H4 Stack

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 32.1 tons/year using 365-day Rolling Sum 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Carbon Monoxide: less than or equal to 7.1 tons/year using 365-day Rolling Sum . 3.0

LIMIT 40 CFR 60.104(a)(1); Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies to the H2S content of the fuel gas burned in the unit. Compliance determined with the H2S monitor at the 45 unit refinery fuel gas mix drum (see GP 111). 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 12.6 lbs/hour using 3-hour Rolling Average 5.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 12.6 lbs/hour using 24-hour Rolling Average 6.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 44.1 tons/year using 12-month Rolling Average 7.0

LIMIT Minn. R. 7009.0080 Sulfur Dioxide: less than or equal to 12.6 lbs/hour using 1-Hour Rolling Average . The 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and, pursuant to Minn. R. 7007.1750, is not enforceable by the EPA

administrator or citizens under the Clean Air Act. 8.0

LIMIT Minn. R. 7011.1410, subp. 3(A); Minn. R. 7011.1420, subp. 2(B) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . Compliance with the hydrogen sulfide limit constitutes compliance with this limit. 9.0

LIMIT Minn. R. 7011.1410, subp. 3(B)(1) Total Particulate Matter: less than or equal to 0.40 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.00745 lbs/million Btu heat imput based on the AP-42 emission factor for natural gas. Compliance with the fuel restriction constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B)(2) Opacity: less than or equal to 20 percent using 6-minute Average exept for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0

CD hdr OTHER LIMITS AND REQUIREMENTS 12.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery fuel gas and natural gas only. 13.0

CD hdr CONTINUOUS EMISSION MONITORING SYSTEMS (CEMS) 14.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn R. 7017.1006 Install, operate, and maintain NOx, CO, and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and Appendix F. See additional CEMS requirements under MR
152, 153, and 154. 15.0

CD hdr RECORDKEEPING REQUIREMENTS 16.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Daily Recordkeeping: The Permittee shall maintain daily records of all monitoring data and calculations for nitrogen oxides, carbon monoxide, oxygen, and type and amount of each fuel combusted to show continuous compliance with the applicable emission limits. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. The calculation and recordkeeping requirements associated with the 1-hr emission limitations for fuel gas combustion sources is a state-only requirement and is not enforceable by

the EPA administrator or citizens under the Clean Air Act. 18.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SO2 Emission Calculations and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of total stack SO2 emissions in tons/year. The records may be maintained in either electronic or paper format unless electronic or paper records are expressly prohibited. 19.0

CD hdr CMS REQUIREMENTS 20.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain a continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion device. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability including, but not limited to, annual calibrations of fuel gas flow meters. 22.0MINNESOTA POLLUTION CONTROL AGENCY

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Subject Item: EU 336 Coke Drum System E and F - Coke Handling Equipment

NC/

CA Type Citation Requirement

CD hdr A . OPERATIONAL STANDARDS 1.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Pressure: less than or equal to 2.0 psi (gauge) using 365-day Rolling Average, effective upon initial startup of the new 25H2 (EU 353) furnace or new 23H3 (EU 352) furnace, whichever is first, as part of the #3 Crude/Coker Improvements permit. The first full compliance period will be 365 days after initial startup of EU 353 or EU 352, whichever is first, as part of the #3 Crude/Coker Improvements permit. The coke drums at the 23 Unit shall be managed in an enclosed blowdown system and the uncondensed vapor must either be recovered (e.g., sent to the delayed coking unit fractionators) or vented to the fuel gas system, a fuel gas combustion device or a flare, until the coke drum pressure reaches 2.0 psig or less. 2.0

CD 40 CFR Section 60.103a(i) Pressure: less than or equal to 5.0 psi (gauge) prior to discharging the coke drum steam exhaust to the atmosphere. This limit is effective upon initial startup of the new 25H2 (EU353) furnace or new 23H3 (EU352) furnace, whichever is first, as part of the #3 Crude/Coker Improvements permit. Until the coke drum pressure reaches 5.0 psig, the coke drum steam exhaust must be managed in an enclosed blowdown system and the uncondensed vapor must either be recovered (e.g., sent to the delayed coking unit fractionators) or vented to the fuel gas system, a fuel gas

combustion device or a flare. 3.0

CD hdr B. RECORDKEEPING AND REPORTING REQUIREMENTS 4.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the pressure reading to which the coke drum is depressured prior to opening the coke drum steam exhaust to the atmosphere. If more than one monitor is used to measure pressure for compliance, the value shall be based on the median of readings taken from the multiple monitors. The average of the pressure readings for each 365-day Rolling

A verage shall be calculated from the reading for each coke drum depressuring event, as provided above, and recorded by the 28th day of each month for the 365-day Rolling Average periods ending on the last day of the preceding month. 5.0

S/A 40 CFR Section 60.7(a)(4) Notification: due 60 days before Start Of Construction of any physical or operational change to EU 336 or as soon as practicable before the change is commenced and shall include the information describing the precise nature of the change, present and proposed emission control systems, productive capacity of the facility before and after the change, and the expected completion date of the change. The

A dministrator may request additional relevant information subsequent to this notice. This notification is required by 40 CFR Section 60.7(a)(4). For the purposes of this requirement, where FHR is taking voluntary applicability of an NSPS standard, the start of the operational change in question is defined to be when the Coke Drums E & F are subject to the 5.0 psig depressure standard. 6.0

S/A 40 CFR Section 60.7(a)(3) Notification: due 15 days after Startup (actual date) of EU 352 or EU 353, whichever is sooner. Notification of initial startup is required by 40 CFR Section 60.7(a)(3). 7.0

CD Minn. R. 7007.0800, subp. 4 Monitoring Equipment: The Permittee shall install and maintain a pressure monitor or multiple monitors on each coke drum to conduct pressure monitoring required by this permit. The monitoring equipment must be installed, in use, and properly

maintained. 8.0MINNESOTA POLLUTION CONTROL AGENCY

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Subject Item: EU 352 23H3 Heater - Process Heater

Associated Items: CE 072 SCR (Selective Catalytic Reduction)

MR 191 23H-3 O2 Monitor

MR 192 23H-3 NOx Monitor

MR 193 23H-3 CO Monitor

MR 194 23H-3 Fuel Flowmeter

MR 199 23H3 Stack Temperature

SV 183 23H3 #3 Coker Heater Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 11.0 tons/year using 365-day Rolling Sum . For the first 364 days after initial certification of the NOx CEMS, NOx emissions are limited as determined by the following equation:

E=11.0 x [0.15 + 0.85(D/365)]

where

E=NOx emissions in total tons D=number of days after limit is effective 2.0

LIMIT 40 CFR Section 60.102a(g)(2)(i)(A) Nitrogen Oxides: less than or equal to 40 parts per million using 30-day Rolling

A verage (dry basis, corrected to 0 percent excess air) determined daily; or 3.0

LIMIT 40 CFR Section 60.102a(g)(2)(i)(B) Nitrogen Oxides: less than or equal to 0.040 lbs/million Btu heat input using 30-day Rolling Average based on higher heating value (HHV), determined daily. 4.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Carbon Dioxide Equivalent: less than or equal to 135,795 tons/year using 365-day Rolling Sum . For the first 364 days after initial start-up of the heater, CO2e emissions are limited as determined by the following equation:

E=135,795 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after limit is effective (BACT Limit) 5.0

LIMIT Minn. R. 7007.0800, subp. 2 Carbon Dioxide Equivalent: less than or equal to 117.4 lbs/million Btu heat input using 12-month Rolling Average . Compliance with this limit can be demonstrated by firing strictly natural gas or by quantifying the average lb/mmBtu of the gaseous fuels fired over the operating period. 6.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Total Particulate Matter: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 352. (BACT Limit) 7.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 10 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour

A verage measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 352. (BACT Limit) 8.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 2.5 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 352. (BACT Limit) 9.0

LIMIT 40 CFR Sections 60.8(c) and 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 162 parts per million using 3-hour Rolling

A verage , determined hourly. This limit does not apply during periods of startup, shutdown or malfunction; and, 10.0

LIMIT 40 CFR Sections 60.8(c) and 60.102a(g)(1)(ii) Hydrogen Sulfide: less than or equal to 60 parts per million using 365-day Rolling

A verage , determined daily. This limit does not apply during periods of startup,

shutdown or malfunction. 11.0

LIMIT Minn. R. 7011.1410, subp. 2 Hydrogen Sulfide: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average (230 mg/dscm [162 ppm]). This limit applies to the hydrogen sulfide content of fuel gas burned in EU 352. Existing continuous H2S monitoring systems (MR 075 and MR 080) on the refinery gas mix drums will be used to demonstrate compliance with this limit. 12.0MINNESOTA POLLUTION CONTROL AGENCY

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LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The total emissions of sulfur dioxide from all existing and new fuel gas combustion devices and indirect heating equipment shall be divided by the total heat input of all such devices and equipment to determine compliance with this part; provided that no owner or operator shall cause to be discharged from any one unit of new indirect heating equipment any gases which contain sulfur dioxide in excess of 3.0 lbs/million Btu heat input. Compliance with the fuel restriction requirement constitutes compliance with this limit. 13.0

LIMIT Title I Condition: To avoid

modification to SIP for SO2 NAAQS; 40 CFR pt. 50, 40 CFR pt. 52, subp. Y, MN SIP Sulfur Dioxide: less than or equal to 2.28 lbs/hour using 1-Hour Average , effective upon initial start-up of EU352. 14.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.4 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.0075 lbs/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 15.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 16.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature: less than 350 degrees F using 365-day Rolling Average basis, excluding hourly periods of startup, shutdown, and low firing rates less than 158 mmBtu/hr HHV input (< 60% of maximum design capacity). (BACT Limit) 17.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 18.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn refinery fuel gas and natural gas only. 19.0

CD Title I Condition: To avoid

modification to SIP for SO2 NAAQS; 40 CFR pt. 50, 40 CFR pt. 52, subp. Y, MN SIP Recordkeeping: The Permittee shall calculate and record the hourly SO2 emissions from refinery fuel gas and natural gas combustion by the 28th day of each month for the hourly periods ending on the last day of the preceding month. This requirement applies for hourly periods when any amount of refinery fuel gas is combusted. For hourly periods when only natural gas is fired, combustion of natural gas only shall constitute compliance with this requirement. 20.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Fuel Flowrate: The Permittee shall calibrate, operate and maintain a continuous monitoring system (CMS) that records the fuel flowrate. 22.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the daily and 365-day Rolling Sum of NOx emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 23.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR pt. 98, subp. C Use methods in 40 CFR pt. 98, subp. C including flow monitoring of fuel usage and fuel gas analysis. Calculate emissions following procedures specified in 40 CFR pt. 98, subp. C with a conversion from metric tons to short tons. The Permittee shall calculate and record the daily and 365-day Rolling Sum of CO2e emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 24.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR Section 63.7540(a)(10)(i-vi) & (12) The Permittee shall conduct tune-ups in accordance with 40 CFR pt. 63, subp. DDDDD. Actions taken during each tune-up (burner inspection and cleaning, flame inspection and optimization, air-to-fuel ratio, CO optimization) will follow the schedule specified in Subpart DDDDD. The Permittee shall maintain records of annual heater tuning performed for compliance and may utilize normal business records for this purpose. This requirement is effective upon startup. (BACT Limit) The initial tune-up shall be performed within 365 days of startup. 25.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: The Permittee shall record and maintain records of each fuel combusted in the unit on a monthly basis. For lbs CO2e/mmBtu heat input, use fuel gas analysis to calculate, record, and maintain the CO2e emissions value on a monthly average and 12-month rolling average basis, unless natural gas is fired strictly during the 12-month period. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 26.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.103a(c-e) RCFA and Corrective Action Requirements: The Permittee shall conduct a root cause analysis of any emission limit exceedance or process startup, shutdown, upset or malfunction that exceeds permitted SO2 emissions by 227 kilograms (kg) (500 lb) in any 24-hour period. For any root cause analysis performed, the Permittee shall record the identification of the affected facility, the date and duration of the discharge, the results of the root cause analysis and the action taken as a result of the root cause analysis.

A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). (continued below) 27.0

CD 40 CFR Section 60.103a(c-e) (continued from above) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable.

No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed date, and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 28.0

CD hdr C. CEMS REQUIREMENTS FOR CO AND NOx 29.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 The Permittee shall install, operate and maintain NOx and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and Appendix F. 30.0

CD CAAA of 1990; Minn. R.
7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a NOx continuous emissions monitoring system (CEMS). 31.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a CO continuous emissions monitoring system (CEMS). 32.0

CD Minn. R. 7017.1006 CO and NOx Emissions Measuring: The Permittee shall use a CO CEMS and NOx

CEMS to measure CO and NOx emissions from SV 183. 33.0

CD Minn. R. 7017.1160, subps. 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 34.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 35.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 36.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix B and Appendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 37.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 38.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 39.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 40.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 41.0

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp 10(A)-(C) Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 42.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 43.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 44.0

CD hdr D. CMS REQUIREMENT 45.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 46.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 47.0

CD hdr E. O2 MONITOR REQUIREMENTS 48.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 49.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 50.0

CD hdr F. H2S MONITOR REQUIREMENTS (SEE GP 111) 51.0

CD hdr G. PERFORMANCE TESTING 52.0

S/A Title I Condition: 40 CFR Section

52.21 and Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup for PM emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 53.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup for PM10 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 54.0MINNESOTA POLLUTION CONTROL AGENCY

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S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp 1 Initial Performance Test: due 180 days after Initial Startup for PM2.5 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 55.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for PM, PM10 and PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. 56.0

CD 40 CFR Section 60.104a(i)(1-8) The Permittee shall conduct an initial compliance performance demonstration for the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) following approved methods in

A ppendix A. The Permittee shall determine initial compliance with the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) according to the following test methods and procedures:

1) Method 1 of Appendix A-1 to pt. 60 for sample and velocity traverses; 2) Method 2 of Appendix A-1 to pt. 60 for velocity and volumetric flow rate; 3) Method 3, 3A or 3B of Appendix A-2 to pt. 60 for gas analysis. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60; (continued below) 57.0

CD 40 CFR Section 60.104a(i)(1-8) (continued from above) 5) Method 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for moisture content and for the concentration of NOx calculated as NO2; the duration of each test run must be no less than 4 hours. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 7 or 7C of

A ppendix A-4 to pt. 60. 7) The Permittee that elects to demonstrate continuous compliance with a maximum excess O2 limit shall determine heat input in mmBtu/hr during each performance test run by measuring fuel gas flow rate and heating value content. 8) The Permittee shall use Equation 8 of this section to adjust pollutant

concentrations to 0% O2 or 0% excess air. 58.0

CD 40 CFR Section 60.104a(j)(1-4) The Permittee shall determine compliance with the applicable H2S emissions limit in 40 CFR Section 60.103a(g)(1)(ii) according to the following test methods and procedures:

1) Method 1 of Appendix A-1 to pt. 60 for sample and velocity traverses; 2) Method 2 of Appendix A-1 to pt. 60 for velocity and volumetric flow rate; 3) Method 3, 3A or 3B of Appendix A-2 to pt. 60 for gas analysis. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60; 4)(iv) If monitoring is conducted at a single point in a common source of fuel gas as allowed under 40 CFR Section 60.107a(a)(2)(iv), only one performance test is required. That is, performance tests are not required when a new affected fuel gas combustion device or flare is added to a common source of fuel gas that previously demonstrated compliance. 59.0

CD hdr H. MONITORING REQUIREMENTS 60.0

CD 40 CFR Section 60.107a(a)(2) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration by volume (dry basis) of H2S in the fuel gases before being burned in any fuel gas combustion device.

i) Install, operate and maintain each H2S monitor according to Performance Specification 7 of Appendix B to pt. 60. The span value is 300 ppmv H2S. ii) Conduct performance evaluations for each H2S monitor according to the requirements of 40 CFR Section 60.13(c) and Performance Specification 7 of

A ppendix B to pt. 60. Use Method 11, 15 or 15A of Appendix A-5 to pt. 60 or Method 16 of Appendix A-6 to pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses" is an acceptable alternative to EPA Method 15A of Appendix A-5 to pt.

60. iii) Comply with the applicable quality assurance procedures in Appendix F to pt. 60

for each H2S monitor. (continued below) 61.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.107a(a)(2) (continued from above) iv) Fuel gas combustion devices having a common source of fuel gas may be monitored at only one location, if monitoring at this location accurately represents the concentration of H2S in the fuel gas being burned in the respective fuel gas

combustion devices. 62.0

CD 40 CFR Section 60.107a(c) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0 percent excess air) of NOx emissions into the atmosphere according to the requirements below. The monitor must include an O2 monitor for correcting the data for excess

air.

1) Except as provided in paragraph (c)(6), the Permittee shall install, operate and maintain each NOx monitor according to Performance Specification 2 of Appendix B to pt. 60. The span value of this NOx monitor must be between 2 and 3 times the applicable emissions limit, inclusive. 2)The Permittee shall conduct performance evaluations of each NOx monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of Appendix B to pt. 60. The Permittee shall use Methods 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for conducting the relative accuracy evaluations. (continued below) 63.0

CD 40 CFR Section 60.107a(c) (continued from above) 2 (cont'd) The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60

. 3) The Permittee shall install, operate and maintain each O2 monitor according to Performance Specification 3 of Appendix B to pt. 60. The span value of this O2 monitor must be selected between 10 and 25 percent, inclusive. 4)The Permittee shall conduct performance evaluations of each O2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 3 of Appendix B to pt. 60. Method 3, 3A or 3B of Appendix A-2 to pt. 60 shall be used for conducting the relative accuracy evaluations. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60. (continued below) 64.0

CD 40 CFR Section 60.107a(c) (continued from above) 5) The Permittee shall comply with the quality assurance requirements in Procedure 1 of Appendix F to pt. 60 for each NOx and O2 monitor, including quarterly accuracy demonstrations for NOx monitors, annual accuracy determinations for O2 monitors and daily calibration drift tests. 65.0

CD 40 CFR Section 60.107a(d)(1-2) Except as provided in paragraph (d)(8), the Permittee shall install, operate and maintain each NOx monitor according to the requirements in paragraphs (c)(1) through (5). The monitor must include an O2 monitor for correcting the data for

excess air. Except as provided in paragraph (d)(3) the Permittee shall sample and analyze each fuel stream fed to the process heater using methods and equations in section 12.3.2 of EPA Method 19 of Appendix A-7 to pt. 60 to determine the F factor on a dry basis. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). 66.0

CD 40 CFR Section 60.107a(d)(3) and (7) A s an alternative to paragraph (d)(2), the Permittee shall install, operate and maintain a gas composition analyzer and determine the average F factor of the fuel gas using the factors in Table 1 and Equation 10 of this section. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). The Permittee shall determine the HHV of each fuel fed to the process heater using any of the applicable methods included in paragraphs (d)(7)(i)-(ix). If a common fuel supply system provides fuel gas to several heaters the HHV of the fuel in each fuel supply system may be determined at a single location in the fuel supply system provided it is representative of the fuel gas fed to the affected process heater(s). The HHV of each fuel must be determined no less frequently than once per day except as provided in paragraph (d)(7)(x). 67.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.107a(i)(1)(ii) and (3) Excess Emissions: Excess emissions are defined as specified in paragraphs (i)(1) through (5) of this section. Determine a rolling 3-hour or a rolling daily average as the arithmetic average of the applicable 1-hour averages. Determine a rolling 30-day or a rolling 365-day average as the arithmetic average of the applicable daily averages.

For H2S limits in Section 60.102a(g)(1)(ii), each rolling 3-hour period during which the average H2S concentration as measured by the CMS required under paragraph (a)(2) exceeds 162 ppmv and each rolling 365-day period during which the average H2S concentration as measured by the CMS required under paragraph (a)(2) exceeds 60 ppmv.

Each rolling 30-day period during which the average NOx concentration as measured by the NOx CMS required under paragraph (c) or (d) exceeds:

i) for a natural draft process heater, 40 ppmv and, if monitored, 0.040 lb/mmBtu

iv) the site-specific limit determined by the Administrator under Section 60.102a(i). 68.0

CD 40 CFR Section 60.107a(i)(4-5) Each day during which the concentration of NOx as measured by the NOx CMS required under paragraph (d) exceeds the daily average emissions limit calculated using Equation 3 in Section 60.102a(g)(2)(iii)(B) or Equation 4 in Section 60.102a(g)(2)(iv)(B).

Each day during which the concentration of O2 as measured by the O2 CMS required under paragraph (c)(6) exceeds the O2 operating limit or operating curve determined during the most recent biennial performance test. 69.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature Monitoring for SV 183 BACT Limit: The Permittee shall monitor stack temperature by doing all of the following:

1) Continuously monitor the stack exit temperature; 2) Consider a stack exit temperature above 350 degrees F on a 24-hour average basis, excluding hourly periods of startup, shutdown and low firing rates less than 158 mmBtu/hr HHV input (< 60% of maximum design capacity), as an excursion that requires corrective action; 3) Upon detecting a stack exit temperature above 350 degrees F on a 24-hour average basis, FHR shall restore operation of the heater to its normal or usual manner of operation as expeditiously as practicable in accordance with good air pollution control practices for minimizing the period of any excursion and taking any necessary corrective actions to restore normal operation. Such actions may include heater adjustments or equipment maintenance; (continued below) 70.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 (continued from above) 4) Keep records of the continuous stack temperature measurements for at least five years and report excursions and a summary of response actions in FHR's Quarterly

A ir Quality and Excess Emissions Report.

Excursions are events that require a response. Excursions are not violations and FHR shall not be considered out of compliance with the limit unless the stack exit temperature is above 350 degrees F on a 365-day rolling average basis, excluding hourly periods of startup, shutdown and low firing rates less than 158 mmBtu/hr HHV input (< 60% of maximum design capacity). 71.0

CD hdr I. 40 CFR PT. 63, SUBP. DDDDD REQUIREMENTS 72.0

CD 40 CFR Sections 63.6(b)(2) and

63.7495 EU 352 shall be in compliance with all applicable requirements of 40 CFR pt. 63, subp. DDDDD upon the date of startup. 73.0

CD 40 CFR Section 63.7500(a)(3) A t all times, the Permittee must operate and maintain any affected source (as defined in 40 CFR Section 63.7490), including associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation and maintenance procedures are being used will be based on information available to the Administrator that may include, but is not limited to, monitoring results, review of operation and maintenance procedures, review of operation and maintenance records and inspection of the source. 74.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 63.7540(a)(10) The Permittee must conduct an annual tune-up of the boiler or process heater to demonstrate continuous compliance as specified in paragraphs (a)(10)(i) through (vi) of this section. This frequency does not apply to limited-use boilers and process heaters, as defined in 40 CFR Section 63.7575, or units with continuous oxygen trim systems that maintain an optimum air to fuel ratio.

(i) As applicable, inspect the burner, and clean or replace any components of the burner as necessary (you may delay the burner inspection until the next scheduled shutdown). Units that produce electricity for sale may delay the burner inspection until the first outage, not to exceed 36 months from the previous inspection. At units where entry into a piece of process equipment or into a storage vessel is required to complete the tune-up inspections, inspections are required only during planned entries into the storage vessel or process equipment; (continued below) 75.0

CD 40 CFR Section 63.7540(a)(10) (continued from above) (ii) Inspect the flame pattern, as applicable, and adjust the burner as necessary to optimize the flame pattern. The adjustment should be consistent with the manufacturer's specifications, if available; (iii) Inspect the system controlling the air-to-fuel ratio, as applicable, and ensure that it is correctly calibrated and functioning properly (you may delay the inspection until the next scheduled unit shutdown). Units that produce electricity for sale may delay the inspection until the first outage, not to exceed 36 months from the previous inspection; (iv) Optimize total emissions of CO. This optimization should be consistent with the manufacturer's specifications, if available, and with any NOx requirement to which the unit is subject; (continued below) 76.0

CD 40 CFR Section 63.7540(a)(10) (continued from above) (v) Measure the concentrations in the effluent stream of CO in parts per million, by volume, and oxygen in volume percent, before and after the adjustments are made (measurements may be either on a dry or wet basis, as long as it is the same basis before and after the adjustments are made). Measurements may be taken using a portable CO analyzer; and (vi) Maintain on-site and submit, if requested by the Administrator, an annual report containing the information in paragraphs (a)(10)(vi)(A) through (C) of this section,

(A) The concentrations of CO in the effluent stream in parts per million by volume, and oxygen in volume percent, measured at high fire or typical operating load, before and after the tune-up of the boiler or process heater; (B) A description of any corrective actions taken as part of the tune-up; and (continued below) 77.0

CD 40 CFR Section 63.7540(a)(10) (continued from above) (C) The type and amount of fuel used over the 12 months prior to the tune-up, but only if the unit was physically and legally capable of using more than one type of fuel during that period. Units sharing a fuel meter may estimate the fuel used by

each unit. 78.0

CD 40 CFR Section 63.7450(a)(12) If EU 352 has a continuous oxygen trim system that maintains an optimum air-to-fuel ratio, or a heat input capacity of less than or equal to 5 million Btu per hour and the unit is in the units designed to burn gas 1; units designed to burn gas 2 (other); or units designed to burn light liquid subcategories, or meets the definition of limited-use boiler or process heater in 40 CFR Section 63.7575, you must conduct a tune-up of the boiler or process heater every 5 years as specified in paragraphs (a)(10)(i) through (vi) of this section to demonstrate continuous compliance. You may delay the burner inspection specified in paragraph (a)(10)(i) of this section until the next scheduled or unscheduled unit shutdown, but you must inspect each burner at least once every 72 months. 79.0

CD 40 CFR Section 63.7540(a)(13) If EU 352 is not operating on the required date for a tune-up, the tune-up must be conducted within 30 calendar days of startup. 80.0

CD 40 CFR Section 63.7540(b) The Permittee shall report each instance in which the Permittee did not meet each emission limit and operating limit in Tables 1 through 4 or 11 through 13 to this subpart that are applicable. These instances are deviations from the emission limits or operating limits, respectively, in this subpart. These deviations must be reported according to the requirements in 40 CFR Section 63.7550. 81.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD Unless the EPA Administrator has approved a different schedule for submission of reports under 40 CFR Section 63.10(a), the Permittee must submit each report, according to paragraph (h) of this section, by the date in Table 9 to this subpart and according to the requirements in paragraphs (b)(1) through (4) of this section. For units that are subject only to a requirement to conduct an annual, biennial, or 5-year tune-up according to 40 CFR Section 63.7540(a)(10), (11), or (12), respectively, and not subject to emission limits or operating limits, you may submit only an annual, biennial, or 5-year compliance report, as applicable, as specified in paragraphs (b)(1) through (4) of this section, instead of a semiannual compliance
report. (continued below) 82.0

CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD (continued from above) 1) The first compliance report must cover the period beginning on the compliance date that is specified for each boiler or process heater in 40 CFR Section 63.7495 and ending on July 31 or January 31, whichever date is the first date that occurs at least 180 days (or 1, 2, or 5 years, as applicable, if submitting an annual, biennial, or 5-year compliance report) after the compliance date that is specified for your

source in 40 CFR Section 63.7495. 2) The first compliance report must be postmarked or submitted no later than July 31 or January 31, whichever date is the first date following the end of the first calendar half after the compliance date that is specified for each boiler or process heater in 40 CFR Section 63.7495. The first annual, biennial, or 5-year compliance report must be postmarked or submitted no later than January 31. (continued below) 83.0

CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD (continued from above) 3) Each subsequent compliance report must cover the semiannual reporting period from January 1 through June 30 or the semiannual reporting period from July 1 through December 31. Annual, biennial, and 5-year compliance reports must cover the applicable 1-, 2-, or 5-year periods from January 1 to December 31. 4) Each subsequent compliance report must be postmarked or submitted no later than July 31 or January 31, whichever date is the first date following the end of the semiannual reporting period. Annual, biennial, and 5-year compliance reports must be postmarked or submitted no later than January 31. 84.0

CD 40 CFR Section 63.7550(c) The compliance report must contain the following information in 40 CFR Section 63.7550(c)(5)(i) through (iv) and (xiv):

1) Company and Facility name and address; 2) Process unit information, emissions limitations, and operating parameter

limitations. 3) Date of report and beginning and ending dates of the reporting period. 4) The total operating time during the reporting period. 5) Include the date of the most recent tune-up for each unit subject to only the requirement to conduct an annual, biennial, or 5-year tune-up according to 40 CFR Section 63.7540(a)(10), (11), or (12), respectively. Include the date of the most recent burner inspection if it was not done annually, biennially, or on a 5-year period and was delayed until the next scheduled or unscheduled unit shutdown. 85.0

CD 40 CFR Section 63.7555 The Permittee shall keep the following records:

(1) A copy of each notification and report submitted to comply with this subpart, including all documentation supporting any Initial Notification or Notification of Compliance Status or semiannual compliance report submitted, according to the requirements in 40 CFR Section 63.10(b)(2)(xiv). (2) Records of performance tests, fuel analyses or other compliance demonstrations and performance evaluations as required in 40 CFR Section 63.10(b)(2)(viii). 86.0

CD 40 CFR Sections 63.10(b);

63.7560 and 63.7565 The Permittee shall maintain files of all information (including all reports and notifications) required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, or computer floppy disks, on magnetic tape disks or on microfiche. 87.0

CD hdr J. REPORTING REQUIREMENTS 88.0MINNESOTA POLLUTION CONTROL AGENCY

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S/A 40 CFR Section 60.7(a)(1) Notification: due 30 days after Start Of Construction of EU 352. A notification of the date construction of EU 352 commenced postmarked no later than 30 days after such date. Notification of start of construction is required by 40 CFR Section 60.7(a)(1). 89.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 60.108a(b) Notification: due 15 days after Startup (actual date) of EU 352. The notification shall include the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee seeks to comply. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 90.0

S/A 40 CFR Section 60.7(a)(5) Notification: due 30 days before Startup of the continuous monitoring system (CMS) in accordance with 40 CFR Section 60.13(c). 91.0

CD 40 CFR Section 60.7(b) The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 92.0

CD 40 CFR Section 60.7(c) The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 93.0

CD 40 CFR Section 60.7(d) The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 94.0

S/A 40 CFR Sections 63.9(b)(1)(i) and (iii); 63.7495(d); 63.7545(a) and (c) and 63.7565 Notification: due 15 days after Initial Startup of EU352. The notification must include the information listed in 40 CFR Section 63.9(b)(4) and (b)(5). 95.0

S/A 40 CFR Sections 63.9(h)(3) and 63.7495(d) Notification of compliance status: due 60 days after Initial Startup and brought into compliance with 40 CFR pt. 63, subp. DDDDD. 96.0

CD 40 CFR Sections 60.10(b) The Permittee shall maintain files of all information required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, on computer floppy disks, on magnetic tape disks or on microfiche. 97.0

CD 40 CFR Sections 63.10(d) The Permittee shall submit reports to the Administrator in accordance with the reporting requirements in the relevant standard(s). 98.0MINNESOTA POLLUTION CONTROL AGENCY

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Subject Item: EU 353 25H2 Heater - Process Heater

Associated Items: CE 073 SCR (Selective Catalytic Reduction)

MR 032 25H-1 or 25H-2 O2 Analyzer

MR 150 NOx Monitor at 25H1 or 25H2

MR 151 CO Monitor at 25H1 or 25H2

MR 195 25H-2 Fuel Flowmeter

MR 200 25H2 Stack Temperature

SV 184 25H2 #3 Crude Heater Stack

NC/

CA Type Citation Requirement

CD hdr A . EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Nitrogen Oxides: less than or equal to 10.9 tons/year using 365-day Rolling Sum . For the first 364 days after initial certification of the NOx CEMS, NOx emissions are limited as determined by the following equation:

E=10.9 x [0.15 + 0.85(D/365)]

where

E=NOx emissions in total tons D=number of days after limit is effective 2.0

LIMIT 40 CFR Section 60.102a(g)(2)(ii)(A) Nitrogen Oxides: less than or equal to 60 parts per million using 30-day Rolling

A verage (dry basis, corrected to 0 percent excess air) determined daily; or 3.0

LIMIT 40 CFR Section 60.102a(g)(2)(ii)(B) Nitrogen Oxides: less than or equal to 0.060 lbs/million Btu heat input using 30-day Rolling Average based on higher heating value (HHV), determined daily. 4.0

LIMIT Title I Condition: 40 CFR Section

52.21 and Minn. R. 7007.3000 Carbon Dioxide Equivalent: less than or equal to 167,066 tons/year using 365-day Rolling Sum . For the first 364 days after initial start-up of the heater, CO2e emissions are limited as determined by the following equation:

E=167,066 x [0.15 + 0.85(D/365)]

where

E=emissions in total tons D=number of days after limit is effective (BACT Limit) 5.0

LIMIT Minn. R. 7007.0800, subp. 2 Carbon Dioxide Equivalent: less than or equal to 117.0 lbs/million Btu heat input using 12-month Rolling Average . Compliance with this limit can be demonstrated by firing strictly natural gas. 6.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Total Particulate Matter: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 353. (BACT Limit) 7.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 10 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour

A verage measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 353. (BACT Limit) 8.0

LIMIT Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 PM < 2.5 micron: less than or equal to 0.0075 lbs/million Btu heat input using 3-hour Average measured as filterable and condensable PM using Methods 5 or 5B for filterable and Method 202 for condensable PM. This limit is effective upon startup of EU 353. (BACT Limit) 9.0

LIMIT Minn. R. 7011.1410, subp. 3(A) Sulfur Dioxide: less than or equal to 1.75 lbs/million Btu heat input using 3-hour Rolling Average . The total emissions of sulfur dioxide from all existing and new fuel gas combustion devices and indirect heating equipment shall be divided by the total heat input of all such devices and equipment to determine compliance with this part; provided that no owner or operator shall cause to be discharged from any one unit of new indirect heating equipment any gases which contain sulfur dioxide in excess of 3.0 lbs/million Btu heat input. Compliance with the fuel restriction requirement constitutes compliance with this limit. 10.0

LIMIT Minn. R. 7011.1410, subp. 3(B) Total Particulate Matter: less than or equal to 0.4 lbs/million Btu heat input using 3-hour Rolling Average . The PTE for this heater is 0.0075 lbs/mmBtu heat input at maximum capacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 11.0MINNESOTA POLLUTION CONTROL AGENCY

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LIMIT Minn. R. 7011.1410, subp. 3(B) Opacity: less than or equal to 20 percent opacity except for one six-minute period per hour of not more than 60 percent opacity. Compliance with the fuel restriction requirement constitutes compliance with this limit. 12.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature: less than 350 degrees F using 365-day Rolling Average basis, excluding hourly periods of startup, shutdown, and low firing rates less than 196 mmBtu/hr HHV input (< 60% of maximum design capacity). (BACT Limit) 13.0

CD hdr B. OTHER LIMITS AND REQUIREMENTS 14.0

CD Minn. R. 7007.0800, subp. 2 Fuel Restriction: Authorized to burn natural gas only. 15.0

CD Minn. R. 7007.0800, subp. 5 Recordkeeping: Record and maintain records of each fuel combusted in the unit on a monthly basis. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 16.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Fuel Flowrate: The Permittee shall calibrate, operate and maintain a continuous monitoring system (CMS) that records the fuel flowrate. 17.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the daily and 365-day Rolling Sum of NOx emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 18.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR pt. 98, subp. C Use methods in 40 CFR pt. 98, subp. C including flow monitoring of fuel usage and fuel gas analysis. Calculate emissions following procedures specified in 40 CFR pt. 98, subp. C with a conversion from metric tons to short tons. The Permittee shall calculate and record the daily and 365-day Rolling Sum of CO2e emissions by the 28th day of each month for the 365-day Rolling Sum periods ending on the last day of the preceding month. 19.0

CD Title I Condition: 40 CFR Section
52.21 & Minn. R. 7007.3000; 40 CFR Section 63.7540(a)(10)(i-vi) & (12) The Permittee shall conduct tune-ups in accordance with 40 CFR pt. 63, subp. DDDDD. Actions taken during each tune-up (burner inspection and cleaning, flame inspection and optimization, air-to-fuel ratio, CO optimization) will follow the schedule specified in Subpart DDDDD. The Permittee shall maintain records of annual heater tuning performed for compliance and may utilize normal business records for this purpose. This requirement is effective upon startup. (BACT Limit) The initial tune-up shall be performed within 365 days of startup. 20.0

CD hdr C. CEMS REQUIREMENTS FOR CO AND NOx 21.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 The Permittee shall install, operate and maintain NOx and O2 CEMS in accordance with 40 CFR pt. 60, Appendix B and Appendix F. 22.0

CD CAAA of 1990; Minn. R.
7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a NOx continuous emissions monitoring system (CEMS). 23.0

CD Minn. R. 7017.1006; Minn. R. 7007.0800, subp. 4 Emissions Monitoring: The Permittee shall calibrate, operate and maintain a CO continuous emissions monitoring system (CEMS). 24.0

CD Minn. R. 7017.1006 CO and NOx Emissions Measuring: The Permittee shall use a CO CEMS and NOx

CEMS to measure CO and NOx emissions from SV 184. 25.0

CD Minn. R. 7017.1160, subps. 1, 2 &

3 Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 26.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 27.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 28.0

CD CAAA of 1990; 40 CFR pt. 60,

A ppendix B and Appendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 29.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 30.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 31.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 32.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 33.0

CD Minn. R. 7017.1090, subps. 1 and 2; Minn. R. 7017.1002, subp 10(A)-(C) Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 34.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 35.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 36.0

CD hdr D. CMS REQUIREMENT 37.0

CD Minn. R. 7007.0800, subp. 4 Fuel Flowrate: The Permittee shall calibrate, operate, and maintain continuous monitoring system (CMS) that records the fuel flowrate at each fuel combustion

device. 38.0

CD Minn. R. 7007.0800, subp. 4 CMS QA/QC: The Permittee shall follow manufacturer recommendations for preventative maintenance and periodic monitoring to ensure CMS reliability, including but not limited to annual calibrations for fuel gas flow meters. 39.0

CD hdr E. O2 MONITOR REQUIREMENTS 40.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 41.0

CD Minn. R. 7007.0800, subp. 4 O2 QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain the O2 monitor according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 42.0

CD hdr F. PERFORMANCE TESTING 43.0MINNESOTA POLLUTION CONTROL AGENCY

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S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup for PM emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 44.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup for PM10 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 45.0

S/A Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 and 40 CFR Sections 60.8(a), 60.102a(a) and 60.104a(c); Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup for PM2.5 emissions. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified except as provided in 40 CFR Section 60.8(b). 46.0

S/A Minn. R. 7017.2020, subp. 1 Testing Frequency Plan: due 60 days after Initial Performance Test for PM, PM10 and PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. 47.0

CD 40 CFR Section 60.104a(i)(1-8) The Permittee shall conduct an initial compliance performance demonstration for the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) following approved methods in

A ppendix A. The Permittee shall determine initial compliance with the NOx limits in 40 CFR Section 60.102a(g)(2)(ii) according to the following test methods and procedures:

1) Method 1 of Appendix A-1 to pt. 60 for sample and velocity traverses; 2) Method 2 of Appendix A-1 to pt. 60 for velocity and volumetric flow rate; 3) Method 3, 3A or 3B of Appendix A-2 to pt. 60 for gas analysis. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60; (continued below) 48.0

CD 40 CFR Section 60.104a(i)(1-8) (continued from above) 5) Method 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for moisture content and for the concentration of NOx calculated as NO2; the duration of each test run must be no less than 4 hours. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" is an acceptable alternative to EPA Method 7 or 7C of

A ppendix A-4 to pt. 60. 7) The Permittee that elects to demonstrate continuous compliance with a maximum excess O2 limit shall determine heat input in mmBtu/hr during each performance test run by measuring fuel gas flow rate and heating value content. 8) The Permittee shall use Equation 8 of this section to adjust pollutant

concentrations to 0% O2 or 0% excess air. 49.0

CD hdr G. MONITORING REQUIREMENTS 50.0

CD 40 CFR Section 60.107a(c) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0 percent excess air) of NOx emissions into the atmosphere according to the requirements below. The monitor must include an O2 monitor for correcting the data for excess

air.

1) Except as provided in paragraph (c)(6), the Permittee shall install, operate and maintain each NOx monitor according to Performance Specification 2 of Appendix B to pt. 60. The span value of this NOx monitor must be between 2 and 3 times the applicable emissions limit, inclusive. 2)The Permittee shall conduct performance evaluations of each NOx monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of Appendix B to pt. 60. The Permittee shall use Methods 7, 7A, 7C, 7D or 7E of Appendix A-4 to pt. 60 for conducting the relative accuracy evaluations. (continued below) 51.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 60.107a(c) (continued from above) 2 (cont'd) The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60

. 3) The Permittee shall install, operate and maintain each O2 monitor according to Performance Specification 3 of Appendix B to pt. 60. The span value of this O2 monitor must be selected between 10 and 25 percent, inclusive. 4)The Permittee shall conduct performance evaluations of each O2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 3 of Appendix B to pt. 60. Method 3, 3A or 3B of Appendix A-2 to pt. 60 shall be used for conducting the relative accuracy evaluations. The method

A NSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", is an acceptable alternative to EPA Method 3B of Appendix A-2 to pt. 60. (continued below) 52.0

CD 40 CFR Section 60.107a(c) (continued from above) 5) The Permittee shall comply with the quality assurance requirements in Procedure 1 of Appendix F to pt. 60 for each NOx and O2 monitor, including quarterly accuracy demonstrations for NOx monitors, annual accuracy determinations for O2 monitors and daily calibration drift tests. 53.0

CD 40 CFR Section 60.107a(d)(1-2) Except as provided in paragraph (d)(8), the Permittee shall install, operate and maintain each NOx monitor according to the requirements in paragraphs (c)(1) through (5). The monitor must include an O2 monitor for correcting the data for

excess air. Except as provided in paragraph (d)(3) the Permittee shall sample and analyze each fuel stream fed to the process heater using methods and equations in section 12.3.2 of EPA Method 19 of Appendix A-7 to pt. 60 to determine the F factor on a dry basis. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). 54.0

CD 40 CFR Section 60.107a(d)(3) and (7) A s an alternative to paragraph (d)(2), the Permittee shall install, operate and maintain a gas composition analyzer and determine the average F factor of the fuel gas using the factors in Table 1 and Equation 10 of this section. If a single fuel gas system provides fuel gas to several process heaters, the F factor may be determined at a single location in the fuel gas system provided it is representative of the fuel gas fed to the affected process heater(s). The Permittee shall determine the HHV of each fuel fed to the process heater using any of the applicable methods included in paragraphs (d)(7)(i)-(ix). If a common fuel supply system provides fuel gas to several heaters the HHV of the fuel in each fuel supply system may be determined at a single location in the fuel supply system provided it is representative of the fuel gas fed to the affected process heater(s). The HHV of each fuel must be determined no less frequently than once per day except as provided in paragraph (d)(7)(x). 55.0

CD 40 CFR Section 60.107a(i)(3) and (4) Excess Emissions: Excess emissions are defined as specified in paragraphs (i)(1) through (5) of this section. Determine a rolling 3-hour or a rolling daily average as the arithmetic average of the applicable 1-hour averages. Determine a rolling 30-day or a rolling 365-day average as the arithmetic average of the applicable daily averages.

Each rolling 30-day period during which the average NOx concentration as measured by the NOx CMS required under paragraph (c) or (d) exceeds:

ii) for a forced draft process heater, 60 ppmv and, if monitored, 0.060 lb/mmBtu

iv) the site-specific limit determined by the Administrator under Section 60.102a(i).

Each day during which the concentration of NOx as measured by the NOx CMS required under paragraph (d) exceeds the daily average emissions limit calculated using Equation 3 in Section 60.102a(g)(2)(iii)(B) or Equation 4 in Section 60.102a(g)(2)(iv)(B). 56.0

CD 40 CFR Section 60.107a(i)(5) Each day during which the concentration of O2 as measured by the O2 CMS required under paragraph (c)(6) exceeds the O2 operating limit or operating curve determined during the most recent biennial performance test. 57.0MINNESOTA POLLUTION CONTROL AGENCY

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CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Stack Temperature Monitoring for SV 184 BACT Limit: The Permittee shall monitor stack temperature by doing all of the following:

1) Continuously monitor the stack exit temperature; 2) Consider a stack exit temperature above 350 degrees F on a 24-hour average basis, excluding hourly periods of startup, shutdown and low firing rates less than 196 mmBtu/hr HHV input (< 60% of maximum design capacity), as an excursion that requires corrective action; 3) Upon detecting a stack exit temperature above 350 degrees F on a 24-hour average basis, FHR shall restore operation of the heater to its normal or usual manner of operation as expeditiously as practicable in accordance with good air pollution control practices for minimizing the period of any excursion and taking any necessary corrective actions to restore normal operation. Such actions may include heater adjustments or equipment maintenance; (continued below) 58.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 (continued from above) 4) Keep records of the continuous stack temperature measurements for at least five years and report excursions and a summary of response actions in FHR's Quarterly

A ir Quality and Excess Emissions Report.

Excursions are events that require a response. Excursions are not violations and FHR shall not be considered out of compliance with the limit unless the stack exit temperature is above 350 degrees F on a 365-day rolling average basis, excluding hourly periods of startup, shutdown and low firing rates less than 196 mmBtu/hr HHV input (< 60% of maximum design capacity). 59.0

CD hdr H. 40 CFR PT. 63, SUBP. DDDDD REQUIREMENTS 60.0

CD 40 CFR Sections 63.6(b)(2)

63.7495 EU 353 shall be in compliance with all applicable requirements of 40 CFR pt. 63, subp. DDDDD upon the date of startup. 61.0

CD 40 CFR Section 63.7500(a)(3) A t all times, the Permittee must operate and maintain any affected source (as defined in 40 CFR Section 63.7490), including associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation and maintenance procedures are being used will be based on information available to the Administrator that may include, but is not limited to, monitoring results, review of operation and maintenance procedures, review of operation and maintenance records and inspection of the source. 62.0

CD 40 CFR Section 63.7540(a)(10) The Permittee must conduct an annual tune-up of the boiler or process heater to demonstrate continuous compliance as specified in paragraphs (a)(10)(i) through (vi) of this section. This frequency does not apply to limited-use boilers and process heaters, as defined in 40 CFR Section 63.7575, or units with continuous oxygen trim systems that maintain an optimum air to fuel ratio.

(i) As applicable, inspect the burner, and clean or replace any components of the burner as necessary (you may delay the burner inspection until the next scheduled unit shutdown). Units that produce electricity for sale may delay the burner inspection until the first outage, not to exceed 36 months from the previous inspection. At units where entry into a piece of process equipment or into a storage vessel is required to complete the tune-up inspections, inspections are required only during planned entries into the storage vessel or process equipment; (continued below) 63.0

CD 40 CFR Section 63.7540(a)(10) (continued from above) (ii) Inspect the flame pattern, as applicable, and adjust the burner as necessary to optimize the flame pattern. The adjustment should be consistent with the manufacturer's specifications, if available; (iii) Inspect the system controlling the air-to-fuel ratio, as applicable, and ensure that it is correctly calibrated and functioning properly (you may delay the inspection until the next scheduled unit shutdown). Units that produce electricity for sale may delay the inspection until the first outage, not to exceed 36 months from the previous inspection; (iv) Optimize total emissions of CO. This optimization should be consistent with the manufacturer's specifications, if available, and with any NOx requirement to which the unit is subject; (continued below) 64.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 63.7540(a)(10) (continued from above) (v) Measure the concentrations in the effluent stream of CO in parts per million, by volume, and oxygen in volume percent, before and after the adjustments are made (measurements may be either on a dry or wet basis, as long as it is the same basis before and after the adjustments are made). Measurements may be taken using a portable CO analyzer; and (vi) Maintain on-site and submit, if requested by the Administrator, an annual report containing the information in paragraphs (a)(10)(vi)(A) through (C) of this section,

(A) The concentrations of CO in the effluent stream in parts per million by volume, and oxygen in volume percent, measured at high fire or typical operating load, before and after the tune-up of the boiler or process heater; (B) A description of any corrective actions taken as part of the tune-up; and (continued below) 65.0

CD 40 CFR Section 63.7540(a)(10) (continued from above) (C) The type and amount of fuel used over the 12 months prior to the tune-up, but only if the unit was physically and legally capable of using more than one type of fuel during that period. Units sharing a fuel meter may estimate the fuel used by

each unit. 66.0

CD 40 CFR Section 63.7540(a)(12) If EU 353 has a continuous oxygen trim system that maintains an optimum air to fuel ratio, or a heat input capacity of less than or equal to 5 million Btu per hour and the unit is in the units designed to burn gas 1; units designed to burn gas 2 (other); or units designed to burn light liquid subcategories, or meets the definition of limited-use boiler or process heater in 40 CFR Section 63.7575, you must conduct a tune-up of the boiler or process heater every 5 years as specified in paragraphs (a)(10)(i) through (vi) of this section to demonstrate continuous compliance. You may delay the burner inspection specified in paragraph (a)(10)(i) of this section until the next scheduled or unscheduled unit shutdown, but you must inspect each burner at least once every 72 months. 67.0

CD 40 CFR Section 63.7540(a)(13) If EU 353 is not operating on the required date for a tune-up, the tune-up must be conducted within 30 calendar days of startup. 68.0

CD 40 CFR Section 63.7540(b) The Permittee shall report each instance in which the Permittee did not meet each emission limit and operating limit in Tables 1 through 4 or 11 through 13 to this subpart that are applicable. These instances are deviations from the emission limits or operating limits, respectively, in this subpart. These deviations must be reported according to the requirements in 40 CFR Section 63.7550. 69.0

CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD Unless the EPA Administrator has approved a different schedule for submission of reports under 40 CFR Section 63.10(a), the Permittee must submit each report, according to paragraph (h) of this section, by the date in Table 9 to this subpart and according to the requirements in paragraphs (b)(1) through (4) of this section. For units that are subject only to a requirement to conduct an annual, biennial, or 5-year tune-up according to 40 CFR Section 63.7540(a)(10), (11), or (12), respectively, and not subject to emission limits or operating limits, you may submit only an annual, biennial, or 5-year compliance report, as applicable, as specified in paragraphs (b)(1) through (4) of this section, instead of a semiannual compliance
report. (continued below) 70.0

CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD (continued from above) 1) The first compliance report must cover the period beginning on the compliance date that is specified for each boiler or process heater in 40 CFR Section 63.7495 and ending on July 31 or January 31, whichever date is the first date that occurs at least 180 days (or 1, 2, or 5 years, as applicable, if submitting an annual, biennial, or 5-year compliance report) after the compliance date that is specified for your

source in 40 CFR Section 63.7495. 2) The first compliance report must be postmarked or submitted no later than July 31 or January 31, whichever date is the first date following the end of the first calendar half after the compliance date that is specified for each boiler or process heater in 40 CFR Section 63.7495. The first annual, biennial, or 5-year compliance report must be postmarked or submitted no later than January 31. (continued below) 71.0MINNESOTA POLLUTION CONTROL AGENCY

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CD 40 CFR Section 63.7550(b) and Table 9 of 40 CFR pt. 63, subp.

DDDDD (continued from above) 3) Each subsequent compliance report must cover the semiannual reporting period from January 1 through June 30 or the semiannual reporting period from July 1 through December 31. Annual, biennial, and 5-year compliance reports must cover the applicable 1-, 2-, or 5-year periods from January 1 through December 31. 4) Each subsequent compliance report must be postmarked or submitted no later than July 31 or January 31, whichever date is the first date following the end of the semiannual reporting period. Annual, biennial, and 5-year compliance reports must be postmarked or submitted no later than January 31. 72.0

CD 40 CFR Section 63.7550(c) The compliance report must contain the following information in 40 CFR Section 63.7550(c)(5)(i) through (iv) and (xiv):

1) Company and Facility name and address; 2) Process unit information, emissions limitations, and operating parameter

limitations. 3) Date of report and beginning and ending dates of the reporting period. 4) The total operating time during the reporting period. 5) Include the date of the most recent tune-up for each unit subject to only the requirement to conduct an annual, biennial, or 5-year tune-up according to 40 CFR Section 63.7540(a)(10), (11), or (12), respectively. Include the date of the most recent burner inspection if it was not done annually, biennially, or on a 5-year period and was delayed until the next scheduled or unscheduled unit shutdown. 73.0

CD 40 CFR Section 63.7555 The Permittee shall keep the following records:

(1) A copy of each notification and report submitted to comply with this subpart, including all documentation supporting any Initial Notification or Notification of Compliance Status or semiannual compliance report submitted, according to the requirements in 40 CFR Section 63.10(b)(2)(xiv). (2) Records of performance tests, fuel analyses or other compliance demonstrations and performance evaluations as required in 40 CFR Section 63.10(b)(2)(viii). 74.0

CD 40 CFR Sections 63.10(b);

63.7560 and 63.7565 The Permittee shall maintain files of all information (including all reports and notifications) required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, or computer floppy disks, on magnetic tape disks or on microfiche. 75.0

CD hdr I. REPORTING REQUIREMENTS 76.0

S/A 40 CFR Section 60.7(a)(1) Notification: due 30 days after Start Of Construction of EU 353. A notification of the date construction of EU 353 commenced postmarked no later than 30 days after such date. Notification of start of construction is required by 40 CFR Section 60.7(a)(1). 77.0

S/A 40 CFR Section 60.7(a)(3); 40 CFR Section 60.108a(b) Notification: due 15 days after Startup (actual date) of EU 353. The notification shall include the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee seeks to comply. This information shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 78.0

S/A 40 CFR Section 60.7(a)(5) Notification: due 30 days before Startup of the continuous monitoring system (CMS) in accordance with 40 CFR Section 60.13(c). 79.0

CD 40 CFR Section 60.7(b) The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 80.0

CD 40 CFR Section 60.7(c) The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 81.0MINNESOTA POLLUTION CONTROL AGENCY

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Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 346 of 407

CD 40 CFR Section 60.7(d) The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 82.0

S/A 40 CFR Sections 63.9(b)(1)(i) and (iii); 63.7495(d); 63.7545(a) and (c) and 63.7565 Notification: due 15 days after Initial Startup of EU353. The notification must include the information listed in 40 CFR Section 63.9(b)(4) and (b)(5). 83.0

S/A 40 CFR Sections 63.9(h)(3) and 63.7495(d) Notification of compliance status: due 60 days after Initial Startup and brought into compliance with 40 CFR pt. 63, subp. DDDDD. 84.0

CD 40 CFR Sections 60.10(b) The Permittee shall maintain files of all information required by this part recorded in a form suitable and readily available for expeditious inspection and review. The files shall be retained for at least 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. At a minimum, the most recent 2 years of data shall be retained on site. The remaining 3 years of data may be retained off site. Such files may be maintained on microfilm, on a computer, on computer floppy disks, on magnetic tape disks or on microfiche. 85.0

CD 40 CFR Sections 63.10(d) The Permittee shall submit reports to the Administrator in accordance with the reporting requirements in the relevant standard(s). 86.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

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# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 347 of 407

Subject Item: EU 361 ATS Process Unit - Refining Equipment

Associated Items: CE 080 Mist Eliminator - High Velocity, i.e., V>250 Ft/Min

MR 211 ATS SO2 Analyzer

MR 212 ATS O2 Analyzer

MR 213 ATS Air Flow Monitor

MR 214 ATS NOx Analyzer

MR 215 ATS CO Analyzer

SV 190 ATS Process Unit

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y; Minn. R.

7009.0080 Sulfur Dioxide: less than or equal to 5.0 lbs/hour using 1-Hour Average effective upon initial start-up of EU361. This is a state only requirement pursuant to Minn. R. 7007.1750, it is not enforceable by the EPA Administrator or citizens under the

Clean Air Act. 2.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.0 lbs/hour using 3-hour Rolling Average effective upon initial start-up of EU361. 3.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 5.0 lbs/hour using 24-hour Rolling Average effective upon initial start-up of EU361. 4.0

LIMIT Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Sulfur Dioxide: less than or equal to 19.71 tons/year using 12-month Rolling

A verage effective upon initial start-up of EU361. 5.0

LIMIT Minn. R. 7011.0715, subp. 1(B) Opacity: less than or equal to 20 percent opacity 6.0

LIMIT 40 CFR Section 60.102a(f)(1)(i) Sulfur Dioxide: less than or equal to 250 parts per million using 12-Hour Rolling

A verage by volume (dry basis) at zero percent excess air. 7.0

CD 40 CFR Section 60.103a(e)(1) A ll corrective action(s) must be implemented within 45 days of the discharge for which the root cause and corrective action analyses were required or as soon thereafter as practicable. If the Permittee concludes that corrective action should not be conducted, the Permittee shall record and explain the basis for that conclusion no later than 45 days following the discharge as specified in 40 CFR Section 60.108a(c)(6)(ix). 8.0

CD 40 CFR Section 60.103a(e)(2) For corrective actions that cannot be fully implemented within 45 days following the discharge for which the root cause and corrective action analyses were required, the Permittee shall develop an implementation schedule to complete the corrective action(s) as soon as practicable. 9.0

CD hdr MONITORING REQUIREMENTS 10.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Emissions Monitoring: The Permittee shall calibrate, operate and maintain an SO2

CEMS 11.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y The Permittee shall use CEMS to monitor the sulfur dioxide emissions in order to calculate pounds of sulfur dioxide per hour (lb/hr) from SV190. 12.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y Calculation: The Permittee shall calculate valid hourly average emissions from

CEMS. 13.0

CD 40 CFR Section 60.106a(a)(1)(i)-(ii) The Permittee shall install, operate, calibrate and maintain an instrument for continuously monitoring and recording the concentration (dry basis, 0% excess air) of any SO2 emissions into the atmosphere. The monitor shall include an oxygen monitor for correcting the data for excess air. i) The span values for this monitor are two times the applicable SO2 emission limit

and between 10 and 25% O2 inclusive. ii) The Permittee shall install, operate and maintain each SO2 CEMS according to Performance Specification 2 of 40 CFR pt. 60, appendix B. 14.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 348 of 407

CD 40 CFR Section 60.106a(a)(1)(iii) iii) The Permittee shall conduct performance evaluations of each SO2 monitor according to the requirements in 40 CFR Section 60.13(c) and Performance Specification 2 of 40 CFR pt. 60, appendix B. The Permittee shall use Method 6 or 6C of appendix A-4 and Method 3 or 3A of appendix A-2 to 40 CFR pt. 60 for conducting the relative accuracy evaluations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses" (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6. 15.0

CD Minn. R. 7007.0800, subp. 8 The Permittee shall operate the demister system (CE080) whenever the ATS Process Unit (EU361) is in operation. 16.0

CD hdr RECORDKEEPING REQUIREMENTS 17.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; Title I Condition: 40 CFR pt. 52, subp. Y SIP SO2 Emission Calculation and Recordkeeping: The Permittee shall maintain records of the calculated SO2 emissions of hourly average of total stack SO2 emissions in lb/hr. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 18.0

CD 40 CFR Section 60.103a(c)(3) The Permittee shall conduct a root cause analysis and a corrective action analysis each time the SO2 emissions are more than 227 kg (500 lb) greater than the

amount that would have been emitted if the SO2 or reduced sulfur concentration was equal to the applicable emissions limit in 40 CFR Section 60.102a(f)(1) during one or more consecutive periods of excess emissions or any 24-hour period,

whichever is shorter. 19.0

CD 40 CFR Section 60.103a(e)(3) No later than 45 days following the discharge for which a root cause and corrective action analyses were required, the Permittee shall record the corrective action(s) completed to date, and for action(s) not already completed, a schedule for implementation, including proposed commencement and completion dates as specified in 40 CFR Section 60.108a(c)(6)(x). 20.0

CD 40 CFR Section 60.108a(a) The Permittee shall comply with the notification, recordkeeping and reporting requirements in 40 CFR Section 60.7. 21.0

CD 40 CFR Section 60.108a(b) The Permittee shall notify the Administrator of the specific monitoring provisions of 40 CFR Sections 60.105a, 60.106a and 60.107a with which the Permittee intends to comply. The Permittee shall submit to the Administrator documentation showing that the process heater meets the definition of a co-fired process heater in 40 CFR Section 60.101a. Notifications required by this paragraph shall be submitted with the notification of initial startup required by 40 CFR Section 60.7(a)(3). 22.0

CD 40 CFR Section 60.108a(c)(6) The Permittee shall maintain the following records: Records of discharges greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant in any 24-hour period as required by 40 CFR Section 60.103a(c). The following information shall be recorded no later than 45 days following the end of a discharge exceeding the thresholds: i) A description of the discharge. ii) The date and time the discharge was first identified and the duration of the discharge. iii) The measured or calculated cumulative quantity of gas discharged over the discharge duration. If the discharge duration exceeds 24 hours, record the discharge quantity for each 24-hour period. vi) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, either the measured concentration of reduced sulfur or SO2 discharged to the atmosphere. (continued below) 23.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) vii) For each discharge greater than 500 lb SO2 in excess of the allowable limits from a sulfur recovery plant, the cumulative quantity of H2S and SO2 released into the atmosphere. viii) The steps that the Permittee took to limit the emissions during the discharge. ix) The root cause analysis and corrective action analysis conducted as required in 40 CFR Section 60.103a(d), including an identification of the affected facility, the date and duration of the discharge, a statement noting whether the discharge resulted from the same root cause(s) identified in a previous analysis and either a description of the recommended corrective action(s) or an explanation of why corrective action is not necessary under 40 CFR Section 60.103a(e). (continued below) 24.0

CD 40 CFR Section 60.108a(c)(6) (continued from above) x) For any corrective action analysis for which corrective actions are required in 40 CFR Section 60.103a(e), a description of the corrective action(s) completed within the first 45 days following the discharge and, for action(s) not already completed, a schedule for implementation, including proposed commencement and completion

dates. 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 349 of 407

CD 40 CFR Section 60.108a(d) The Permittee shall submit and excess emissions report for all periods of excess emissions according to the requirements of 40 CFR Section 60.7(c) except that the report shall contain the information specified in 40 CFR Section 60.108a(d)(1) - (7). 1) The date that the exceedance occurred; 2) An explanation of the exceedance; 3) Whether the exceedance was concurrent with a startup, shutdown or malfunction of an affected facility or control system; and 4) A description of the actions taken, if any. 5) The information described in 40 CFR Section 60.108a(c)(6) for all discharges listed in 40 CFR Section 60.108a(c)(6). (continued below) 26.0

CD 40 CFR Section 60.108a(d) (continued from above) 6) For any periods for which monitoring data are not available, any changes made in operation of the emission control system during the period of data unavailability which could affect the ability of the system to meet the applicable emission limit. Operations of the control system and affected facility during periods of data unavailability are to be compared with operation of the control system and affected facility before and following the period of data unavailability. 7) A written statement, signed by a responsible official, certifying the accuracy and completeness of the information contained in the report. 27.0

CD hdr PERFORMANCE TESTING REQUIREMENTS 28.0

S/A 40 CFR Section 60.104a(a) and (c); 40 CFR Section 60.8; Minn. R. 7017.2020, subp. 1 Initial Performance Test: due 180 days after Initial Startup to demonstrate initial compliance with each applicable emissions limit in 40 CFR Section 60.102a. The notification requirements of 40 CFR Section 60.8(d) apply to the initial performance test and subsequent performance tests. Use test methods in 40 CFR pt. 60, Appendices A-1 through A-8 or other methods as specified in 40 CFR Section 60.104a, except as provided in 40 CFR Section 60.8(b). 29.0

CD 40 CFR Section 60.104a(h)(1)-(5) The Permittee shall determine compliance with the SO2 emissions limits using the following methods and procedures: 1) Method 1 of 40 CFR pt. 60, Appendix A-1 for sample and velocity traverses. 2) Method 2 of 40 CFR pt. 60, Appendix A-1 for velocity and volumetric flow rate. 3) Method 3, 3A or 3B of 40 CFR pt. 60, Appendix A-2 for gas analysis. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas Analyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 3B of 40 CFR pt. 60, Appendix A-2. 4) Method 6, 6A or 6C of 40 CFR pt. 60, Appendix A-4 to determine the SO2 concentration. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 6 or 6A of 40 CFR pt. 60, Appendix A-4. (continued below) 30.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) 5) Method 15 or 15A of 40 CFR pt. 60, Appendix A-5 or Method 16 of 40 CFR pt. 60, Appendix A-6 to determine the reduced sulfur compounds and H2S concentrations. The method ANSI/ASME PTC 19.10-1981, "Flue and Exhaust Gas

A nalyses", (incorporated by reference - see 40 CFR Section 60.17) is an acceptable alternative to EPA Method 15A of 40 CFR pt. 60, Appendix A-5. i) Each run consists of 16 samples taken over a minimum of 3 hours. ii) The Permittee shall calculate the average H2S concentration after correcting for moisture and O2 as the arithmetic average of the H2S concentration for each sample during the run (ppmv, dry basis, corrected to 0% excess air). iii) The Permittee shall calculate the SO2 equivalent for each run after correcting for moisture and O2 as the arithmetic average of the SO2 equivalent of reduced sulfur compounds for each sample during the run (ppmv, dry basis, corrected to 0% excess air). (continued below) 31.0

CD 40 CFR Section 60.104a(h)(1)-(5) (continued from above) iv) The Permittee shall use Equation 8 of 40 CFR Section 60.104a(d) to adjust pollutant concentrations to 0% O2 or 0% excess air. 32.0

CD hdr REPORTING REQUIREMENTS 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 350 of 407

S/A 40 CFR Section 60.7(a)(1); Minn.

R. 7019.0100 Notification: due 30 days after Start Of Construction of EU 361 as a modification to the SRP (including GP112 and EU361). A notification of any physical or operational change to an existing facility which may increase the emission rate of any air pollutant to which a standard applies, unless that change is specifically exempted under an applicable subpart or in 40 CFR Section 60.14(e). This notice shall be postmarked 60 days or as soon as practicable before the change is commenced and shall incude information describing the precise nature of the change, present and proposed emission control systems, productive capacityof the facility before and after the change, and the expected completion date of the change. The

A dministrator may request additional relevant information subsequent to this notice. 34.0

S/A 40 CFR Section 60.8; Minn. R.

7019.0100 Notification: due 15 days after Startup (actual date) of EU 361. A notification of the date of startup of EU 361 postmarked no later than 15 days after such date. Notification of startup is required in association with the initial performance test requirements under 40 CFR Section 60.8. 35.0

S/A 40 CFR Section 60.7(a)(5); Minn.

R. 7019.0100 Notification: due 30 days before Startup of the continuous monitoring system performance in accordance with 40 CFR Section 60.13(c). Notification shall be postmarked no less than 30 days prior to such date. 36.0

CD 40 CFR Section 60.7(b); Minn. R.

7019.0100 The Permittee shall maintain records of the occurrence and duration of any startup, shutdown or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system (CMS) or monitoring device is inoperative. 37.0

CD 40 CFR Section 60.7(c); Minn. R.

7019.0100 The Permittee shall submit excess emissions and monitoring systems performance report and/or summary form to the Administrator semiannually, except when: more frequent reporting is required by an applicable subpart; or the Administrator on a case-by-case basis, determines that more frequent reporting is necessary. All reports shall be postmarked by the 30th day following the end of each six-month period and include the information in 40 CFR Section 60.7(c)(1) through (4). 38.0

CD 40 CFR Section 60.7(d); Minn. R.

7019.0100 The summary report form shall contain the information in figure 1 of 40 CFR Section 60.7. One summary report form shall be submitted for each pollutant monitored at each affected facility.

If the total duration of excess emissions is less than 1% of the total operating time and CMS downtime is less than 5% of the total operating time, only the summary report form shall be submitted

If the total duration of excess emissions is 1% or greater of the total operating time or CMS downtime is 5% or greater of the total operating time, the summary report form and the excess emission report described in 40 CFR Section 60.7(c) shall

both be submitted. 39.0

CD 40 CFR Section 60.7(f); Minn. R.

7019.0100 The Permittee shall maintain a file of all measurements, including continuous monitoring system (CMS), monitoring device and performance testing measurements; all CMS performance evaluations; all CMS or monitoring device calibration checks; adjustments and maintenance performed on these systems or devices; and all other information required by 40 CFR pt. 60 recorded in a permanent form suitable for inspection. The file shall be retained for at least two years following the date of such measurements, maintenance, reports and records, except as follows: 40.0

CD 40 CFR Section 60.7(f)(1); Minn.

R. 7019.0100 A n automated CEMS records and reduces the measured data to the form of the pollutant emission standard through the use of a computerized data acquisition system. In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain the most recent consecutive three averaging periods of subhourly measurements and a file that contains a hard copy of the data acquisition system algorithm used to reduce the measured data into the reportable form of the standard. 41.0

CD 40 CFR Section 60.7(f)(2); Minn.

R. 7019.0100 In lieu of maintaining a file of all CEMS subhourly measurements as required under 40 CFR Section 60.7(f), the Permittee shall retain all subhourly measurements for the most recent reporting period. The subhourly measurements shall be retained for 120 days from the date of the most recent summary or excess emission report

submitted to the Administrator. 42.0

CD 40 CFR Section 60.7(g); Minn. R.

7019.0100 If notification substantially similar to that in 40 CFR Section 60.7(a) is required by any other State or local agency, sending the Administrator a copy of that notification will satisfy the requirements of 40 CFR Section 60.7(a). 43.0

CD 40 CFR Section 60.7(h); Minn. R.

7019.0100 Individual subparts of 40 CFR pt. 60 may include specific provisions which clarify or make inapplicable the provisions set forth in this section. 44.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 351 of 407

CD 40 CFR Section 60.11(d); Minn. R.

7017.2015 A t all times, including periods of startup, shutdown and malfunction, the Permittee shall, to the extent possible, maintain and operate any affected facility including associated air pollution control equipment in a manner consistent with good air pollution control practice for minimizing emissions. Determination of whether acceptable operating and maintenance procedures are being used will be based on information available to the Administrator which may include, but is not limited to, monitoring results, opacity observations, review of operating and maintenance procedures and inspection of the source. 45.0

CD 40 CFR Section 60.11(g); Minn. R.

7017.2015 For the purpose of submitting compliance certifications or establishing whether or not a person has violated or is in violation of any standard in this part, nothing in this part shall preclude the use, including the exclusive use, of any credible evidence or information, relevant to whether a source would have been in compliance with applicable requirements if the appropriate performance or compliance test or procedure had been performed. 46.0

CD 40 CFR Section 60.103a(d) The Permittee shall conduct a root cause analysis and corrective action analysis as soon as possible, but no later than 45 days after a discharge exceeding 500 lb greater than the permit limit. 47.0

CD 40 CFR Section 60.103a(d)(1) If a single continuous discharge exceeds 500 lb greater than the permit limit for 2 or more consecutive 24-hour periods, a single root cause analysis and corrective action analysis may be conducted. 48.0

CD 40 CFR Section 60.106a(b)(1) Excess emissions reports required for all 12-hour periods during which the average concentration of SO2 as measured by the SO2 continuous monitoring system required under 40 CFR Section 60.106a(a)(1) exceeds the applicable emission limit (dry basis, 0% excess air). 49.0

CD hdr CEMS REQUIREMENTS 50.0

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 51.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 52.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 53.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 54.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 55.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 56.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 57.0

CD Minn. R. 7017.1090, subps. 1 and

2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown or malfunction except for periods of acceptable monitor downtime. The requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 58.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 352 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 59.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 60.0

CD hdr A IR FLOW MONITORING REQUIREMENTS 61.0

CD Minn. R. 7007.0800, subp. 4 Stack Air Flow: The Permittee shall calibrate, operate and maintain a continuous air

flow monitor that records the stack air flow for SV 190. 62.0

CD hdr O2 MONITOR REQUIREMENT 63.0

CD Minn. R. 7007.0800, subp. 4 QA Plan: Develop and implement a written quality assurance plan that covers the O2 Monitor. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent factors. 64.0

CD hdr REPORTING REQUIREMENT 65.0

CD Title I Condition: 40 CFR Section

52.21 & Minn. R. 7007.3000 Report: due before end of each quarter following Excess Emissions/Downtime Reports (EER's) if there are any exceedances of the SO2 limits. 66.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 353 of 407

Subject Item: CE 002 Flaring

Associated Items: EU 209 Track 8 Rail Loading - Loading-Unloading Equipment

FS 002 Track 8 Load and Uncontrolled Rail - Material Handling/Transfer/Storage

GP 106 Control Equipment Used to Meet Requirements of MACT CC

MR 189 Temperature Indicator for 101H1

NC/

CA Type Citation Requirement

LIMIT 40 CFR Section 60.104(a)(1); 40 CFR Section 60.8(c); Minn. R. 7011.1435(A) Fuel Usage: less than or equal to 0.10 grains/dry standard cubic foot using 3-hour Rolling Average . Limit does not apply during periods of startup, shutdown, or

malfunction. 1.0

CD 40 CFR Section 63.427(b); 40 CFR Section 63.6(f)(1); 40 CFR Section 63.650(a); Minn. R. 7007.0800, subps. 2 & 14 Operating Parameter: shall operate the vapor processing system in a manner not to exceed the operating parameter value for the parameter or to go below the operating parameter value for the parameter and established using the procedures in 40 CFR Section 63.425(b). In cases where an alternative parameter is approved, each owner or operator shall operate the vapor processing system in a manner not to exceed or not to go below, as appropriate, the alternative operating parameter value. Operation of the vapor processing system in a manner exceeding or going below the operating parameter value shall constitute a violation of the emission standard in 40 CFR Section 63.422(b). 2.0

CD 40 CFR Section 63.422(a) Follow the design requirements of 40 CFR Section 502(a), (d). Follow the design requirements of 40 CFR Section 502(h), (i) or alternatively as listed in 40 CFR Section 63.425(e). 3.0

CD 40 CFR Section 63.422(b) Emissions to the atmosphere from the vapor collection and processing systems due to the loading of gasoline cargo tanks shall not exceed 10 milligrams of total organic compounds per liter of gasoline loaded as defined in 40 CFR Section

60.503. 4.0

CD 40 CFR Section 63.422(a) & (c); 40 CFR Section 60.502(e) Loadings of liquid product into gasoline cargo tanks shall be limited to vapor-tight gasoline cargo tanks using the procedures as listed in 40 CFR Section 60.502(e). 5.0

CD 40 CFR Section 63.422(c); 40 CFR Section 60.502(e) The terminal owner or operator shall take steps assuring that the nonvapor-tight gasoline cargo tank (i.e., cargo tanks initially loaded without proper vapor tightness documentation) will not be reloaded at the facility until vapor proper vapor tightness documentation for that gasoline cargo tank is obtained. 6.0

CD 40 CFR Section 63.422(a); 40 CFR Section 60.502(g) The owner or operator shall act to assure that the gasoline cargo tank's vapor collection systems are connected during each loading of a gasoline cargo tank at the affected facility. 7.0

CD 40 CFR Section 63.425(a) Compliance Requirement: Each owner or operator subject to the emission standard in 40 CFR Section 63.422(b) shall conduct a performance test on the vapor processing system according to the test methods and procedures of 40 CFR Section 60.503 except that a reading of 500 ppm shall be used to determine the level of leaks to be repaired under 40 CFR Sections 60.503(b) or 63.425(a)(1)(ii). 8.0

CD 40 CFR Section 63.425(b) Performance Test Requirement: For each performance test conducted under 40 CFR Section 63.425(a), the owner or operator shall determine a monitored operating parameter value for the vapor processing system by continuously recording the operating parameter during the performance test and determining operating parameter values based on the results of the test; a rationale for selecting the parameter values shall be provided to the Administrator. 9.0

CD 40 CFR Section 63.425(c) Recordkeeping Requirement: For performance tests performed after the initial test, the owner or operator shall document the reasons for any change in the operating parameter value since the previous performance test. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 10.0

CD 40 CFR Section 63.425(e); 40 CFR Section 63.425(i) A nnual Certification Test: Follow one of the test methods and procedures listed in 40 CFR Section 63.425(e) or as an alternative to 40 CFR Section 63.425(e), FHR may also alternatively comply with 40 CFR Section 63.425(i), railcar bubble leak test procedures. 11.0

CD hdr COMPLIANCE ASSURANCE MONITORING (CE002) 12.0

CD Minn. R. 7007.0800, subps. 2 and

14 The Permittee shall operate and maintain the afterburner (CE 002) at all times that any emission unit controlled by the afterburner (EU 209) is in operation. The Permittee shall document periods of non-operation of the control equipment. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 354 of 407

CD 40 CFR Section 63.8(c)(3); Minn. R. 7007.0800, subp. 14 Operation and maintenance of continuous monitoring systems: All CMS shall be installed, operational, and the data verified as specified in the relevant standard either prior to or in conjunction with conducting performance tests under 40 CFR Section 63.7. Verification of operational status shall, at a minimum, include completion of the manufacturer's written specifications or recommendations for installation, operation, and calibration of the system. 14.0

CD 40 CFR Section 63.427(a)(3); Minn. R. 7007.0800, subps. 2 and

14 Monitoring Requirement: Install, calibrate, certify, operate and maintain according to the manufacturer's specification a CPMS capable of measuring temperature. The CPMS must be installed in the firebox or in the ductwork immediately downstream from the firebox in a position before any substantial heat exchange occurs. 15.0

CD 40 CFR Section 63.427(b); Minn. R. 7007.0800, subps. 2 and 14 Operation Requirement: Operation of air pollution control system to achieve emission limit or operational parameter at or above the temperature requirement of 187.3 degrees F. 16.0

CD 40 CFR Section 63.8(c)(2); Minn. R. 7007.0800, subps. 2 and 14 Operation and maintenance of continuous monitoring systems: All CMS shall be installed such that representative measurements of emissions or process parameters from the affected source are obtained. 17.0

CD 40 CFR Section 63.8(c)(4); Minn. R. 7007.0800, subps. 2 and 14 Operation and maintenance of continuous monitoring systems: Except for system breakdowns, out-of-control periods, repairs, maintenance periods, calibration checks, and zero (low-level) and high-level calibration drift adjustments, all CMS shall be in continuous operation. 18.0

CD 40 CFR Section 63.8(c)(1)(i); Minn. R. 7007.0800, subps. 2 and

14 Operation and maintenance of continuous monitoring systems: The owner or operator shall ensure the immediate repair or replacement of CMS parts to correct routine" or otherwise predictable CMS malfunctions as defined in the source's startup, shutdown, and malfunction plan required by 40 CFR Section 63.6(e)(3). The owner or operator shall keep the necessary parts for routine repairs of the affected equipment readily available. If the plan is followed and the CMS is repaired immediately, this action shall be reported in the semiannual startup, shutdown, and malfunction report required under 40 CFR Section 63.10(d)(5)(i). 19.0

CD 40 CFR Section 64.3(b); Minn. R.

7017.0200 Daily Monitoring: The Permittee shall physically verify the operation of the temperature recording device at least once each operating day to verify that it is working and recording properly. The Permittee shall maintain a written record of the daily verifications. 20.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Periodic Inspections: Conduct periodic inspections in accordance with the CAM Plan for the control equipment. 21.0

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: If the temperature is below the minimum specified by this permit or if the thermal oxidizer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the temperature to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the thermal oxidizer. The Permittee shall keep a record of the type and date of any corrective action taken. 22.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing minimum combustion chamber temperature(s), the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 23.0

CD 40 CFR Section 64.9(a)(2); Minn.

R. 7017.0200 CAM Excursions Reporting: As required by 40 CFR Section 64.9(a)(2), for the Quarterly Report listed in Table B of this permit and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in Table A of this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. The Permittee shall report all excursions in the quarterly report required by this permit. 24.0

CD 40 CFR Section 64.6(c); Minn. R.

7017.0200 The Permittee shall comply with the monitoring, recordkeeping, and reporting requirements contained in the CAM plan submitted to the MPCA effective on the permit issuance date. 25.0

CD hdr RECORDKEEPING AND REPORTING REQUIREMENTS 26.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 355 of 407

CD 40 CFR Section 63.428(b); 40 CFR Section 63.428(k) Recordkeeping Requirement: Records of the annual tests of gasoline cargo tanks to be conducted as specified in 40 CFR Section 63.425(e)-(h). The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 27.0

CD 40 CFR Section 63.428(c) Recordkeeping Requirement: Records of continuous monitoring data required by 40 CFR Section 63.427(a), or of the alternative parameter if approved under 40 CFR Section 63.427(b) shall be kept in a readily accessible location. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 28.0

CD 40 CFR Section 63.428(g) Semi-Annual report must include each loading of a gasoline cargo tank for which vapor tightness documentation had not been previously obtained by the facility. 29.0

CD 40 CFR Section 63.428(h) Reporting and Recordkeeping: Submit 1) an excess emissions report in accordance with 40 CFR Section 63.10(e)(3), each exceedance or failure to maintain the monitored operating parameter value determined in 40 CFR Section 63.425(b); 2) Each instance of a nonvapor-tight gasoline cargo tank loading at the facility in which the operator failed to take steps to assure that such cargo tank would not be reloaded at the facility before vapor tightness documentation for the cargo tank
was obtained; and 3) Each reloading or a nonvapor-tight gasoline cargo tank at the facility before vapor tightness documentation for that cargo tank is obtained by the facility. 30.0

CD 40 CFR Section 60.7(b) Recordkeeping Requirement: Record each startup, shutdown or malfunction of the air pollution control equipment or any periods during which a continuous monitoring system or monitoring device is inoperative. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 31.0

CD 40 CFR Section 63.10(b) General Recordkeeping Requirements: The owner or operator shall maintain files of all information (including all reports and notifications) required by 40 CFR pt. 63 recorded in a form suitable and readily available for expeditious inspection and review including all information required by 40 CFR Section 63.10(b). The files shall be kept for at least five (5) years following the date of each occurrence, measurement, maintenance, corrective action, report or record. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 32.0

CD 40 CFR Section 63.6(e)(3)(i) 40 CFR Section 63.8(c)(1)(iiii) Startup, Shutdown, and Malfunction Plan: The owner or operator shall develop and implement a written startup, shutdown, and malfunction plan that describes, in detail, procedures for operating and maintaining the source during periods of startup, shutdown, and malfunction and a program of corrective action for malfunctioning process and air pollution control, and monitoring equipment used to comply with the relevant standard. As required under 40 CFR Section 63.8(c)(1)(i), the plan shall identify all routine or otherwise predictable CMS malfunctions. The plan shall be developed by the compliance date and shall meet the purposes specified in 40 CFR Section 63.6(e)(3)(i)(A) through (C). 33.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 356 of 407

Subject Item: CE 003 Activated Carbon Adsorption

Associated Items: EU 004 Truck Bottom Loading (gas, distillate) including the trucks - Loading-Unloading Equipment

FS 006 Bottom Loading - Material Handling/Transfer/Storage

GP 106 Control Equipment Used to Meet Requirements of MACT CC

MR 004 VOC Monitor at Bottom Loading Unit

NC/

CA Type Citation Requirement

CD hdr CAM REQUIREMENTS FOR CE 003 1.0

CD Minn. R. 7007.0800, subp. 14 The Permittee shall operate and maintain the carbon adsorption in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. 2.0

CD 40 CFR Section 63.427(b); Minn. R. 7007.0800, subps. 2 and 14 Operation Requirement: Operation of air pollution control system to achieve emission limit or operational parameter. 3.0

CD 40 CFR Section 63.427(a)(1); 40 CFR Section 64.3(b); Minn. R.

7017.0200 Monitoring Requirement: Install, calibrate, certify, operate and maintain according to the manufacturer's specification a CEMS capable of measuring organic compounds concentration. 4.0

CD 40 CFR Section 64.3(b); Minn. R.

7017.0200 Daily Monitoring: The Permittee shall physically verify the operation of the VOC analyzer at least once each operating day to verify that it is working and recording properly. The Permittee shall maintain a written record of the daily verifications. 5.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Quarterly Inspections: At least once per calendar quarter, the Permittee shall inspect the control equipment internal and external system components. The Permittee shall maintain a written record of the inspection and any corrective actions taken resulting from the inspection. 6.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 A nnual Inspection: At least once per calendar year, the Permittee shall conduct an internal inspection of the control device that includes all operating systems of the control device. The Permittee shall maintain a written record of the inspection and any action resulting from the inspection. 7.0

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: If VOC analyzer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the outlet VOC concentration to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the activated carbon adsorption. The Permittee shall keep a record of the type and date of any corrective action taken. 8.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing minimum combustion chamber temperature(s), the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 9.0

CD 40 CFR Section 64.9(a)(2); Minn.

R. 7017.0200 CAM Excursions Reporting: As required by 40 CFR Section 64.9(a)(2), for the Quarterly Report listed in Table B of this permit and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in Table A of this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. The Permittee shall report all excursions in the quarterly report required by this permit. 10.0

CD 40 CFR Section 64.9(b); Minn. R.

7017.0200 The Permittee shall maintain records of monitoring data, monitor performance data, corrective actions taken, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. 11.0

CD hdr OPERATIONAL, RECORDKEEPING AND REPORTING REQUIREMENTS 12.0

CD 40 CFR Section 60.502(f); 40 CFR Section 63.422(a); 40 CFR Section 64.3; Minn. R. 7017.0200 Operation Requirement: the owner or operator shall act to assure that loadings of gasoline tank trucks at the affected facility are made into tanks equipped with vapor collection equipment that is compatible with the terminals vapor collection system. 13.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 357 of 407

CD 40 CFR Section 60.502(g); 40 CFR Section 63.422(a); 40 CFR Section 64.3; Minn. R. 7017.0200 Operation Requirement: the owner or operator shall act to assure that the terminals and the tank trucks vapor collection systems are connected during each loading of a gasoline tank truck at the affected facility. 14.0

CD 40 CFR Section 60.502(d); 40 CFR Section 63.422(a) Construction/Design Requirement: each vapor collection system shall be designed to prevent any total organic compound vapors from passing to another loading

rack. 15.0

CD 40 CFR Section 60.502(h); 40 CFR Section 63.422(a) Design/Construction Requirement: the vapor collection and liquid loading equipment shall be designed and operated to prevent gauge pressure in the delivery tank from exceeding 450 mm of water during product loading. 16.0

CD 40 CFR Section 60.502(e); 40 CFR Section 63.422(a) Compliance Requirement: loadings of liquid product into gasoline tank trucks shall be limited to vapor tight gasoline tank trucks using the procedures in 40 CFR Section 60.502(e)(1)-(5). 17.0

CD 40 CFR Section 60.502(e)(1); 40 CFR Section 63.422(a) Recordkeeping Requirement: the owner or operator shall obtain documentation that states that the truck to be gasoline loaded is vapor tight. 18.0

CD 40 CFR Section 60.502(e)(2); 40 CFR Section 63.422(a) Recordkeeping Requirement: the owner or operator shall require the tank ID number to be recorded as each gasoline tank truck is loaded at the affected facility. 19.0

CD 40 CFR Section 60.502(e)(3); 40 CFR Section 63.422(a) Compliance Requirement: the owner or operator shall cross check each tank ID number obtained in paragraph (e)(2) with the file of tank vapor tightness documentation within 2 weeks after the corresponding tank is loaded. 20.0

CD 40 CFR Section 60.502(e)(4); 40 CFR Section 63.422(a) Reporting Requirement: the owner or operator shall notify the owner or operator of each non-vapor-tight gasoline tank truck within one (1) week after the loading has

occurred. 21.0

CD 40 CFR Section 60.502(e)(5); 40 CFR Section 63.422(a) Compliance Requirement: the owner or operator shall take steps assuring that the non-vapor-tight gasoline tank truck will not be reloaded until vapor tightness

documentation for that tank is obtained. 22.0

CD 40 CFR Section 60.502(i); 40 CFR Section 63.422(a) Design/Construction Requirement: no pressure-vacuum vent in the bulk gasoline terminals vapor collection system shall begin to open at a system pressure less

than 450 mm of water. 23.0

CD 40 CFR Section 60.503(a); 40 CFR Section 63.422(a) Performance Test Requirement: in conducting the performance tests required by this subpart, the owner or operator shall use the test methods in Appendix A of this part, except as provided in 40 CFR Section 60.8(b); the three-run requirement of 40 CFR Section 60.8(f) does not apply to this subpart. 24.0

CD 40 CFR Section 63.425(a) Compliance Requirement: Each owner or operator subject to the emission standard in 40 CFR Section 63.422(b) shall conduct a performance test on the vapor processing system according to the test methods and procedures of 40 CFR Section 60.503 except that a reading of 500 ppm shall be used to determine the level of leaks to be repaired under 40 CFR Section 60.503(b). 25.0

CD 40 CFR Section 60.7(b) Recordkeeping Requirement: Record each startup, shutdown or malfunction of the air pollution control equipment. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 26.0

CD 40 CFR Section 63.425(b) Performance Test Requirement: For each performance test conducted under 40 CFR Section 63.425(a), the owner or operator shall determine a monitored operating parameter value for the vapor processing system by continuously recording the operating parameter during the performance test and determining operating parameter values based on the results of the test; a rationale for selecting the parameter values shall be provided to the Administrator. 27.0

CD 40 CFR Section 63.425(c) Recordkeeping Requirement: For performance tests performed after the initial test, the owner or operator shall document the reasons for any change in the operating parameter value since the previous performance test. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 28.0

CD 40 CFR Section 63.425(e) A nnual Certification Test: Follow one of the test methods and procedures listed in 40 CFR Section 63.425(e). 29.0

CD 40 CFR Section 63.428(b); 40 CFR Section 63.428(k) Recordkeeping Requirement: Records of the annual tests of gasoline cargo tanks to be conducted as specified in 40 CFR Section 63.425(e)-(h). The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 30.0

CD 40 CFR Section 63.428(c) Recordkeeping Requirement: Records of continuous monitoring data required by 40 CFR Section 63.427(a), or of the alternative parameter if approved under 40 CFR Section 63.427(b) shall be kept in a readily accessible location. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 31.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 358 of 407

CD 40 CFR Section 63.428(g) Semi-Annual report must include each loading of a gasoline cargo tank for which vapor tightness documentation had not been previously obtained by the facility. 32.0

CD 40 CFR Section 63.428(h) Reporting and Recordkeeping: Submit 1) an excess emissions report in accordance with 40 CFR Section 63.10 (e)(3)- each exceedance or failure to maintain the monitored operating parameter value determined in 40 CFR Section 63.425(b). 2) Each instance of a nonvapor-tight gasoline cargo tank loading at the facility in which the operator failed to take steps to assure that such cargo tank would not be reloaded at the facility before vapor tightness documentation for the cargo tank was
obtained; and 3) Each reloading or a nonvapor-tight gasoline cargo tank at the facility before vapor tightness documentation for that cargo tank is obtained by the facility. 33.0

CD 40 CFR Section 63.6(e)(3)(i); 40 CFR Section 63.8(c)(1)(iii) Startup, Shutdown, and Malfunction Plan: The owner or operator shall develop and implement a written startup, shutdown, and malfunction plan that describes, in detail, procedures for operating and maintaining the source during periods of startup, shutdown, and malfunction and a program of corrective action for malfunctioning process and air pollution control equipment used to comply with the relevant standard. As required under 40 CFR Section 63.8(c)(1)(i), the plan shall identify all routine or otherwise predictable CMS malfunctions. The plan shall be developed by the compliance date and shall meet the purposes specified in 40 CFR Section 63.6(e)(3)(i)(A) through (C). 34.0

CD 40 CFR Section 63.8(c)(1)(i) Operation and maintenance of continuous monitoring systems: The owner or operator shall ensure the immediate repair or replacement of CMS parts to correct "routine" or otherwise predictable CMS malfunctions as defined in the source's startup, shutdown, and malfunction plan required by 40 CFR Section 63.6(e)(3). The owner or operator shall keep the necessary parts for routine repairs of the affected equipment readily available. If the plan is followed and the CMS is repaired immediately, this action shall be reported in the semiannual startup, shutdown, and malfunction report required under 40 CFR Section 63.10(d)(5)(i). 35.0

CD 40 CFR Section 63.8(c)(2) Operation and maintenance of continuous monitoring systems: All CMS shall be installed such that representative measurements of emissions or process parameters from the affected source are obtained. In addition, CEMS shall be located according to procedures contained in the applicable performance specification(s). 36.0

CD 40 CFR Section 63.8(c)(3) Operation and maintenance of continuous monitoring systems: All CMS shall be installed, operational, and the data verified as specified in the relevant standard either prior to or in conjunction with conducting performance tests under 40 CFR Section 63.7. Verification of operational status shall, at a minimum, include completion of the manufacturer's written specifications or recommendations for installation, operation, and calibration of the system. 37.0

CD 40 CFR Section 63.8(c)(4) Operation and maintenance of continuous monitoring systems: Except for system breakdowns, out-of-control periods, repairs, maintenance periods, calibration checks, and zero (low-level) and (high-level) calibration drift adjustments, the CEMS, shall be in continuous operation and shall meet minimum frequency of operation requirements by completing a minimum of one cycle of operation (sampling, analyzing, and data recording) for each successive 15-minute period. 38.0

CD Minn. R. 7007.0800, subp. 2 Quality Control Program: The owner or operator shall develop a quality control program meeting the requirements of 40 CFR Section 63.8(d)(2) and (3) within 60 days of the effective date. The program shall follow the procedures of 40 CFR pt. 60, Appendix F. 39.0

CD 40 CFR Section 63.10(b) General Recordkeeping Requirements: The owner or operator shall maintain files of all information (including all reports and notifications) required by 40 CFR pt. 63 recorded in a form suitable and readily available for expeditious inspection and review including all information required by 40 CFR Section 63.10(b). The files shall be kept for at least five (5) years following the date of each occurrence, measurement, maintenance, corrective action, report or record. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 40.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 359 of 407

Subject Item: CE 006 Electrostatic Precipitator - Medium Efficiency

Associated Items: EU 228 FCCU - Refining Equipment

MR 017 17ME-187 FCC Common Stack Opacity Analyzer

MR 018 FCC Common Stack NOx Analyzer

MR 019 FCC Common Stack SO2 Analyzer

MR 021 FCC CO(%) in Flue Gas Monitor

MR 022 17H-2 Fuel Gas Flow Meter

MR 023 17H-4 Fuel Gas Flow Meter

MR 024 EMRC Flow for 17ME-187

MR 025 EMRC Temperature Thermocouple for 17ME-187

MR 106 FCC O2 Dry Percent

MR 107 FCC CO Low

NC/

CA Type Citation Requirement

CD hdr COMPLIANCE ASSURANCE MONITORING (CE 006) 1.0

CD Title I Condition: To avoid classification as a major source

and modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Compliance Assurance Monitoring: The Permittee shall operate and maintain the ESP (CE 006) at any time that the process equipment controlled by the ESP (EU 228) is in operation. The Permittee shall document periods of non-operation of the control equipment. 2.0

LIMIT Title I Condition: To avoid classification as a major source

and modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 The Permittee shall operate and maintain control equipment such that it achieves a control efficiency for PM < 10 micron: greater than or equal to 70 percent control efficiency 3.0

LIMIT Title I Condition: To avoid classification as a major source

and modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 The Permittee shall operate and maintain control equipment such that it achieves a control efficiency for Total Particulate Matter: greater than or equal to 70 percent control efficiency 4.0

CD Minn. R. 7007.0800; subps. 2 and

14 Operation and Maintenance of ESP: The Permittee shall operate and maintain the ESP in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and review by MPCA staff. Following the NESHAP, Subpart UUU Operations, Maintenance, and Monitoring (OM&M) Plan satisfies this requirement. 5.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R. 7007.3000; 40 CFR Section 64.3 The Permittee shall operate CE 006 with no less than the minimum number of fields (TR sets) online during the most recent performance test that measured PM and PM10 emissions and showed compliance with the applicable limit under EU

228. 6.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R. 7007.3000; 40 CFR Section 64.3 The Permittee shall record the minimum number of fields (TR sets) online in CE 006 once each day of operation of EU 228. If the minimum number of fields are found to not be online, commence corrective action (as outlined in the operation and maintenance plan for the facility) within 24-hours of discovery to return the

minimum number of fields online. This is considered an excursion as defined in 40

CFR Section 64.1. Make a record of all corrective actions taken. 7.0

CD 40 CFR Section 64.3(a)(2); Minn.

R. 7017.0200 Opacity: Corrective action (as outlined in the CAM plan) is required as soon as possible if opacity is greater than 20% using a daily average as measured using the COMS located on SV 019. As indicated in the CAM plan, opacity in excess of 20% shall be considered an excursion under 40 CFR Section 64.6(c)(2) for purposes of CAM requirements, but is not an indication of an exceedance of the applicable emission limitation and shall not be considered a permit deviation if the response and reporting requirements of the CAM plan and this permit are met. 8.0

CD 40 CFR Section 64.3(b)(4)(ii);

Minn. R. 7017.0200 Continuous Monitoring: The Permittee shall continuously, or at a minimum once every 15 minutes, monitor the opacity of the ESP exhaust. [See Subject Item EU 228, section C for specific COMS operating requirements.] 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 360 of 407

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Response to excursions: (1) Upon detecting an excursion, the owner or operator shall restore operation of the pollutant-specific emissions unit (including the control device and associated capture system) to its normal or usual manner of operation as expeditiously as practicable in accordance with good air pollution control practices for minimizing the period of any startup, shutdown or malfunction and taking any necessary corrective actions to restore normal operation and prevent the likely recurrence of the cause of an excursion (other than those caused by excused startup or shutdown conditions). Such actions may include initial inspection and evaluation, recording that operations returned to normal without operator action (such as through response by a computerized distribution control system), or any necessary follow-up actions to return operation to within the indicator range, designated condition, or below the applicable emission limitation or standard, as applicable. 10.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Periodic Inspections: At least once per calendar quarter, or more frequently if required by the manufacturer, the Permittee shall inspect the control equipment components that are subject to wear or plugging, for example: bearings, belts, hoses, fans, nozzles, orifices, and ducts. The Permittee shall maintain a written record of the inspection and any corrective actions taken resulting from the inspection. 11.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 A nnual Inspections: At least once per calendar year, or more frequently if required by the manufacturer, the Permittee shall perform an in-service inspection to inspect the control equipment components not covered by the quarterly inspections. This includes, but is not limited to, components that are not subject to wear or plugging including structural components, housings, and hoods. The Permittee shall maintain a written record of the inspection and any corrective actions taken resulting from the inspection. 12.0

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: The Permittee shall take corrective action as soon as possible if any of the following occur: - the recorded daily average of opacity is outside the required operating range; or - the ESP or any of its components are found during the inspections to need repair. Corrective actions shall return operation to within the permitted range and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the OM&M Plan for the FCCU. The Permittee shall keep a record of the type and date of any corrective action taken for the FCCU. 13.0

CD 40 CFR Section 64.6(c); Minn. R.

7017.0200 Opacity CAM Performance Criteria: 1. Opacity is measured using a COMS on the SV 019. 2. Conduct daily validation and semi-annual calibration error audits. Visual confirmation from data recording verifies operation twice per day. 3. Follow the QA/QC plan developed for the COMS. 4. The opacity is measured continuously. 5. The daily average opacity is calculated and recorded. 6. The averaging period is a daily average. 14.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing opacity which is considered an excursion, the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 15.0

CD 40 CFR Section 64.9(a)(2); Minn.

R. 7017.0200 CAM Excursions Reporting: As required by 40 CFR Section 64.9(a)(2), for the Quarterly Report listed in Table B of this permit and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in Table A of this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. The Permittee shall report all CE 006 and EU 228 opacity excursions in the quarterly report required by this permit. 16.0

CD 40 CFR Section 64.6(c); Minn. R.

7017.0200 The Permittee will comply with the monitoring, recordkeeping and reporting requirements contained in the CAM plan submitted to the MPCA effective on the permit issuance date. 17.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 361 of 407

Subject Item: CE 028 Direct Flame Afterburner w/Heat Exchanger

Associated Items: EU 178 OSWTP - API Oil/Water Separator Fore Bay (94B1A & 94B1B) - Separation Equipment

EU 182 OSWTP - Sludge Basin 2A - Refining Equipment

EU 183 OSWTP - Equalization Basin 2B - Refining Equipment

EU 184 OSWTP - Equalization Basin 2C - Refining Equipment

EU 185 OSWTP-Enhanced Biological Treatm ent Basin 94B3C - Refining Equipment

EU 186 OSWTP - DAF Tank (old) - Refining Equipment

EU 187 OSWTP - DAF Tank (new) - Refining Equipment

EU 188 OSWTP - DAF Rapid Mix Tank (old) - Mixing Equipment

EU 189 OSWTP - DAF Rapid Mix Tank (new) - Mixing Equipment

EU 190 OSWTP - DAF Floc T ank (old) - Refining Equipment

EU 191 OSWTP - DAF Floc T ank (new) - Refining Equipment

EU 192 OSWTP - Aerobic Digester - Digester

EU 197 OSWTP - Oily Sludge Dewateri ng (Centrifuge) - Refining Equipment

EU 282 OSWTP - Thermal Oxidizer - Other Combustion

FS 119 OSWTP Fugitive Emissions Includes Non-vented Equipment - Process Emissions

GP 126 Affected Sources at the refinery under MACT GGGGG

MR 101 94H1 & 94H3 Natural Gas Flow

MR 102 94H-1 Thermocouple for Fire Box Temperature

MR 104 94H1 SO2 Analyzer

MR 145 Flow Meter for 94H1 Exhaust Gases

TK 336 Organic Liquid Storage Tank

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.11(d); 40 CFR Section 60.690-60.699; 40 CFR Section 60.692-5(e)(4)-(5); 40 CFR Section 60.697(f); 40 CFR Section 63.640(o)(1); Minn. R. 7011.1435(C) Subject to 40 CFR pt. 61, subps. A and FF requirements. Compliance with 40 CFR pt. 61, subp. FF and 40 CFR pt. 61, subp. A requirements as listed in this permit fully satisfies 40 CFR pt. 60, subps. A and QQQ; 40 CFR pt. 63, subps. A and CC requirements. 1.0

CD hdr POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS 2.0

CD Minn. R. 7007.0800, subps. 2 and

14 The Permittee shall operate and maintain the thermal oxidizer (CE 028 or CE 029 (backup) at all times that any emission unit controlled by the thermal oxidizer ( EU
178, EUs 182- 191, EU 197, EU 278, EU 280, EU 281, EU 289, EUs 290- 293; EU 293, EU 314, EU 254, EU 282 and TK 336) is in operation. The Permittee shall document periods of non-operation of the control equipment. 3.0

CD Minn. R. 7007.0800, subps. 2 &

14 Operation and Maintenance of the Thermal Oxidizer: The Permittee shall operate and maintain the thermal oxidizer in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. 4.0

CD 40 CFR Section 61.354(c)(1); 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E); Minn. R.

7017.2025 Temperature: Maintain temperature within 50 degree F of temperature established in most recent destruction efficiency performance test using a 3-hour Rolling

A verage. The temperature shall be measured in a representative location in or near

the firebox of the oxidizer. 5.0

CD 40 CFR Section 64.3; Minn. R. 7017.0200; 40 CFR Section

60.692-5 A flow indicator shall be installed on a vent stream to a control device to ensure that the vapors are being routed to the control device. 6.0

CD 40 CFR Section 64.3(b); Minn. R.
7017.0200; Minn. R. 7007.0800, subps. 4 and 5 Daily Monitoring: The Permittee shall verify the operation of the temperature recording device at least once each operating day to verify that it is working and recording properly. The Permittee shall maintain a written or electronic record of the daily verifications. 7.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 362 of 407

CD 40 CFR Section 64.3; Minn. R.
7017.0200; Minn. R. 7007.0800, subps. 4, 5, and 14 Inspections: Conduct periodic inspections in accordance with the CAM Plan. 8.0

CD 40 CFR Section 64.7(d); Minn. R.
7017.0200; Minn. R. 7007.0800, subps. 4, 5, and 14 Corrective Actions: If the temperature is below the minimum specified by this permit or if the thermal oxidizer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the temperature to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the thermal oxidizer. The Permittee shall keep a record of the type and date of any corrective action taken. 9.0

CD 40 CFR Section 64.6(c); Minn. R. 7017.0200; 40 CFR Section 61.356(j); 40 CFR Section 61.356(j)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) For each control device, maintain documentation that includes the following information regarding the control device operation:

(1) Dates of startup and shutdown of the closed-vent system and control device;

(2) A description of the operating parameter (or parameters ) to be monitored to ensure that the control device will be operated in conformance with these standards and the control device's design specifications and an explanation of the criteria used for selection of that parameter (or parameters). This documentation shall be kept for the life of the control device; and

(3) Periods when the closed-vent system and control device are not operated as designed including all periods and the duration when: Any valve car-seal or closure mechanism is broken or the by-pass line valve position has changed and The flow monitoring devices indicate that vapors are not routed to the control device as required. 10.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR 60.697(d); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. (continued below) 11.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR 60.697(d); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 12.0

CD 40 CFR Section 64.9(b); Minn. R. 7017.0200; 40 CFR Section 61.356(j)(4); 40 CFR 60.697(f)(3)(viii); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Maintain continuous records of the temperature of the gas stream in the combustion zone of the incinerator and records of all 3-hour periods of operation during which the average temperature of the gas stream in the combustion zone is more than 28 °C (50 °F) below the temperature established in most recent destruction efficiency performance test. 13.0

CD 40 CFR Section 64.9(b); Minn. R.

7017.0200 The Permittee shall maintain records of monitoring data, monitor performance data, corrective actions taken, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. 14.0

CD 40 CFR Section 64.9(a)(2); Minn.

R. 7017.0200 CAM Excursions Reporting: As required by 40 CFR Section 64.9(a)(2), for the Quarterly Report listed in Table B of this permit and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in Table A of this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. The Permittee shall report all CEs 028 and 029 excursions in the quarterly report required by this permit. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 363 of 407

CD 40 CFR Section 61.13(g); 40 CFR Section 61.356; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Retain at the source and make available, upon request, for inspection by the

A dministrator, for a minimum of 2 years, records of emission test results and other

data needed to determine emissions. 16.0

CD hdr REPORTING 17.0

CD 40 CFR Section 61.13(c) The owner or operator shall notify the Administrator of intent to conduct a required performance test at least 30 days before the performance test is scheduled. 18.0

CD 40 CFR Section 61.13(f) Unless otherwise specified in an applicable subpart, samples shall be analyzed and emissions determined within 30 days after each emission test has been completed. The owner or operator shall report the determinations of the emission test to the

A dministrator by a registered letter sent before the close of business on the 31st day following the completion of the emission test. 19.0

CD 40 CFR Section 63.640(o)(1); Minn. R. 7011.1435(C) Subject to 40 CFR pt. 61 subps. A and FF requirements. Compliance with 40 CFR pt. 61, subp. FF and 40 CFR pt. 61, subp. A requirements as listed in this permit fully satisfies 40 CFR pt. 63, subps. A and CC requirements. 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 364 of 407

Subject Item: CE 029 Direct Flame Afterburner

Associated Items: EU 254 Unit 94H3-Thermal Oxid izer Back-up - Other Combustion

EU 282 OSWTP - Thermal Oxidizer - Other Combustion

GP 126 Affected Sources at the refinery under MACT GGGGG

MR 101 94H1 & 94H3 Natural Gas Flow

MR 103 Temperature Monitor (Stack) for 94H-3 Thermal Oxidizer

MR 144 94H3 SO2 Analyzer

MR 146 Flow Meter for 94H3 Exhaust Gases

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.11(d); 40 CFR Section 60.690-60.699; 40 CFR Section 60.692-5(e)(4)-(5); 40 CFR Section 60.697(f); 40 CFR Section 63.640(o)(1); Minn. R. 7011.1435(C) Subject to 40 CFR pt. 61, subps. A and FF requirements. Compliance with 40 CFR pt. 61, subp. FF and 40 CFR pt. 61, subp. A requirements as listed in this permit fully satisfies 40 CFR pt. 60, subps. A and QQQ; 40 CFR pt. 63, subps. A and CC requirements. 1.0

CD hdr SEE CAM AND POLLUTION CONTROL EQUIPMENT REQUIREMENTS UNDER

CE 028. 2.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 365 of 407

Subject Item: CE 050 Flaring

Associated Items: EU 004 Truck Bottom Loading (gas, distillate) including the trucks - Loading-Unloading Equipment

GP 106 Control Equipment Used to Meet Requirements of MACT CC

NC/

CA Type Citation Requirement

CD hdr CAM REQUIREMENTS FOR CE 050 1.0

CD 40 CFR Section 63.8(c) Operation and Maintenance: The Permittee shall maintain and operate the continuous parameter monitoring system in a manner consistent with good air pollution control practices and shall meet all applicable requirements of 40 CFR Section 63.8(c). 2.0

CD Minn. R. 7007.0800, subp. 14 The Permittee shall operate and maintain the flare in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. 3.0

CD Minn. R. 7007.0800, subps. 2 and

14 The Permittee shall operate and maintain the enclosed flare during fuel loading any time that the vapor recovery unit (CE 003) is not being operated to control emissions from the Bottom Loading Rack (EU 004). 4.0

CD 40 CFR Section 63.425(b); 40 CFR Section 64.3; Minn. R.

7017.0200 Enclosed Flare Minimum Temperature: For each performance test conducted under 40 CFR Section 63.425(a) when operating the enclosed flare, the Permittee shall determine a minimum temperature for the enclosed flare using the following procedure:

(1) During the performance test, continuously record the enclosed flare operating
temperature;

(2) Determine a minimum enclosed flare operating temperature based on the parameter data monitored during the performance test, supplemented by engineering assessments and the manufacturer's recommendations; and

(3) Provide for the MPCA's approval the rationale for the selected minimum enclosed flare operating temperature, and monitoring frequency and averaging time including data and calculations used to develop the value and a description of why the minimum enclosed flare operating temperature, monitoring frequency, and averaging time demonstrate continuous compliance with the emission standard in 40 CFR Section 63.422(b). 5.0

LIMIT MInn. R. 7007.0800, subp. 2 Temperature: greater than or equal to 300 degrees F using an 1-hour Block

A verage. Downtime of 15 minutes or less is not to be included as operating time. During all gasoline loading procedures, the flame stack temperature indicator may not operate at a lower temperature as listed, unless a performance test is conducted at a different temperature and the MPCA staff determines compliance at that new temperature. 6.0

CD 40 CFR Section 63.427(a); 40 CFR Section 64.3(b)(4)(ii); Minn.

R. 7017.0200 Continuous Monitoring: For the enclosed flare (CE 050), the Permittee shall install, calibrate, certify, operate, and maintain, according to the manufacturer's specifications, a continuous parameter monitoring system (CPMS) capable of measuring temperature in the fire box or in the duct work immediately downstream from the fire box in a position before any substantial heat exchange occurs. 7.0

CD 40 CFR Section 63.8(c)(4) CPMS Continuous Operation: Except for system breakdowns, repairs, and calibration checks, the CPMS shall be in continuous operation whenever the enclosed flare is operating. 8.0

CD 40 CFR Section 64.3(b); Minn. R.

7017.0200 Daily Monitoring: The Permittee shall physically verify the operation of the temperature recording device at least once each operating day to verify that it is working and recording properly. The Permittee shall maintain a written record of the daily verifications. 9.0

CD 40 CFR Section 64.7(b); Minn. R.

7017.0200 Monitoring Equipment: The Permittee shall install and maintain thermocouples to conduct temperature monitoring required by this permit. The monitoring equipment must be installed, in use, and properly maintained whenever operation of the monitored control equipment is required. 10.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Periodic Inspections: Conduct periodic inspections in accordance with the CAM

Plan. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 366 of 407

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: If the temperature is below the minimum specified by this permit or if the thermal oxidizer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the temperature to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the thermal oxidizer. The Permittee shall keep a record of the type and date of any corrective action taken. 12.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing minimum combustion chamber temperature(s), the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 13.0

CD 40 CFR Section 64.9(a)(2); Minn.

R. 7017.0200 CAM Excursions Reporting: As required by 40 CFR Section 64.9(a)(2), for the Quarterly Report listed in Table B of this permit and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in Table A of this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. The Permittee shall report all excursions in the quarterly report required by this permit. 14.0

CD 40 CFR Section 64.9(b); Minn. R.

7017.0200 The Permittee shall maintain records of monitoring data, monitor performance data, corrective actions taken, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. 15.0

CD 40 CFR Section 63.427(b) Enclosed Flare Operation: The Permittee shall operate the enclosed flare to ensure that the enclosed flare operating temperature is greater than or equal to the minimum enclosed flare operating temperature established using the procedures in 40 CFR Section 63.425(b). Operation of the enclosed flare at a temperature below the minimum enclosed flare operating temperature shall constitute a violation of the emission standard in 40 CFR Section 63.422(b). 16.0

CD 40 CFR Section 63.428(c); 40 CFR Section 63.10(b)(1) Recordkeeping and Reporting: (1) Keep an up-to-date, readily accessible record of the enclosed flare operating temperature. This record shall indicate the time intervals during which loadings of gasoline cargo tanks have occurred or, alternatively, shall record the operating parameter data only during such loadings. The date and time of day shall also be

indicated at reasonable intervals on this record.

(2) Record and report, simultaneously with the notification of compliance status required under 40 CFR Section 63.9(h), all data and calculations, engineering assessments, and manufacturer's recommendations used in determining the operating parameter value under 40 CFR Section 63.425(b).

Records shall be maintained for a period of at least 5 years.

The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 17.0

CD 40 CFR Section 63.8(d)(2) and (d)(3) Quality Control Program: The Permittee shall develop and implement a quality control program for the continuous parameter monitoring system used to measure the enclosed flare operating temperature. The quality control program shall meet all applicable requirements of 40 CFR Section 63.8(d)(2) and (d)(3). 18.0

CD 40 CFR Section 63.6(e)(3) Startup, Shutdown, and Malfunction Plan: Develop and implement a written startup, shutdown, and malfunction plan which complies with 40 CFR Section 63.6(e)(3). 19.0

CD Minn. R. 7007.0800, subps. 2 and

14 The Permittee shall record all times during which the enclosed flare is operated. These records shall be retained for a period of 5 years. 20.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 367 of 407

Subject Item: CE 056 Direct Flame Afterburner

Associated Items: EU 277 West Buffer Zone Offgas (88H2) - Refining Equipment

GP 126 Affected Sources at the refinery under MACT GGGGG

MR 100 SVE System: Temperature Monitor for West Buffer (88H2)

MR 140 Natural Gas 88H-2 SVE Oxidizer

NC/

CA Type Citation Requirement

CD hdr POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS 1.0

LIMIT Minn. R. 7017.2025, subp. 3 Temperature: greater than or equal to 1278 degrees F using 3-hour Rolling

A verage 2.0

LIMIT 40 CFR Section 61.349(a)(2)(i)(A);
Minn. R. 7017.2025; Minn. R. 7011.9930(E) Total Organic Compounds: greater than or equal to 95 percent destruction efficiency (by weight) as demonstrated by performance test. 3.0

CD 40 CFR Section 61.354(c)(1); 40 CFR Section 61.356(j)(4); Minn. R. 7017.2025; Minn. R. 7011.9930(E) Temperature: Maintain temperature no greater than 28 degree Celsius (50 degree F) below the most recent performance test design temperature as a 3-hour rolling

average. 4.0

CD 40 CFR Section 61.349(a)(2)(i)(A); Minn. R. 7011.9930(E) The Permittee must design the control device to meet performance standard: Reduce the organic emissions vented to it by 95 weight percent or greater. 5.0

CD 40 CFR Section 64.3; Minn. R. 7017.0200; 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) Daily Records: The Permittee shall maintain continuous records of the temperature of the gas stream in the combustion zone of the incinerator and records of all 3-hour periods of operation during which the average temperature of the gas stream in the combustion zone is more than 28 °C (50 °F) below the design combustion zone temperature. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 6.0

CD 40 CFR Section 64.3(b); Minn. R. 7017.0200; 40 CFR Section 61.354(c)(1); Minn. R. 7011.9930.(E) The Permittee shall install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified in 40 CFR Section 61.354(c)(1), unless alternative monitoring procedures or requirements are approved for that facility by the

A dministrator. The Permittee shall inspect at least once each operating day the data recorded by the monitoring equipment (e.g., temperature monitor or flow indicator) to ensure that the control device is operating properly. 7.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Inspections: Conduct periodic inspections in accordance with the CAM Plan. 8.0

CD 40 CFR Section 64.3(a)(2); Minn. R. 7017.0200; 40 CFR Section 61.349(h); 40 CFR Section 61.354(c); 40 CFR Section 61.354(c)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified below, unless alternative monitoring procedures or requirements are approved. Inspect at least once each operating day the data recorded by the monitoring equipment to ensure that the control device is operating properly.

For a thermal vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The device shall have an accuracy of ±1 percent of the temperature being monitored in °C or ±0.5 °C, whichever is greater. The temperature sensor shall be installed at a representative location in the combustion

chamber. 9.0

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: The Permittee shall follow the corrective actions, as outlined in the CAM Plan. If the temperature is below the minimum specified by this permit or if the thermal oxidizer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the temperature to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the thermal oxidizer. The Permittee shall keep a record of the type and date of any corrective action taken. 10.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing minimum combustion chamber temperature(s), the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 368 of 407

CD 40 CFR Section 64.9(b); Minn. R.

7017.0200 The Permittee shall maintain records of monitoring data, monitor performance data, corrective actions taken, and other supporting information required to be maintained in accordance with the CAM Plan. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. 12.0

CD 40 CFR Section 61.349(a)(1)(i) Closed vent system and control device shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 13.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements: (1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 14.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be: (i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 15.0

CD CD 40 CFR Section 61.349(f); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Each closed-vent system and control device shall be visually inspected quarterly. The visual inspection shall include inspection of ductwork and piping and

connections to covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. 16.0

CD 40 CFR Section 61.349(a)(1); 40 CFR Section 61.355(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Vent systems that contain any bypass line that could divert the vent stream away from a control device shall install, maintain, and operate according to the manufacturer's specifications a flow indicator that provides a record of vent stream flow away from the control device at least once every 15 minutes OR ensure the bypass line valve is closed by securing with a car-seal or lock-and-key type device. Exception is for a vent to atmosphere that remains in a closed, sealed position during normal operations except when the device needs to open to prevent physical damage or permanent deformation of the closed-vent system resulting from malfunction of the unit in accordance with good engineering and safety practices for handling flammable, explosive, or other hazardous materials. 17.0

CD 40 CFR Section 61.349(h); 40 CFR Section 61.354(c); 40 CFR Section 61.354(c)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified below, unless alternative monitoring procedures or requirements are approved. Inspect at least once each operating day the data recorded by the monitoring equipment to ensure that the control device is operating properly.

For a thermal vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The device shall have an accuracy of ±1 percent of the temperature being monitored in °C or ±0.5 °C, whichever is greater. The temperature sensor shall be installed at a representative location in the combustion

chamber. 18.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 369 of 407

CD 40 CFR Section 61.354(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Owners or operators using a closed-vent system that contains any bypass line that could divert a vent stream from a control device shall do the following:

(1) Visually inspect the bypass line valve at least once every month, checking the position of the valve and the condition of the car-seal or closure mechanism required under 40 CFR Section 61.349(a)(1)(ii) to ensure that the valve is maintained in the closed position and the vent stream is not diverted through the bypass line.

(2) Visually inspect the readings from each flow monitoring device required by 40 CFR Section 61.349(a)(1)(ii) at least once each operating day to check that vapors are being routed to the control device as required. 19.0

CD hdr RECORDKEEPING REQUIREMENTS 20.0

CD 40 CFR Section 61.14(f); Minn. R.

7011.9900 CMS Records: The Permittee shall maintain records of monitoring data, monitoring system calibration checks, and the occurrence and duration of any period during which the monitoring system is malfunctioning or inoperative. These records shall be maintained at the source for a minimum of 2 years and made available, upon request, for inspection by the Administrator. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 21.0

CD 40 CFR Section 61.356(f)(3)(i-iv); 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) Performance test was used to determine control device performance; therefore, the Permittee will maintain the following records:

(i) A description of how it is determined that the test is conducted when the waste management unit or treatment process is operating at the highest load or capacity level. This description shall include the estimated or design flow rate and organic content of each vent stream and definition of the acceptable operating ranges of key process and control parameters during the test program.

(ii) A description of the control device including the type of control device, control device manufacturer's name and model number, control device dimensions, capacity, and construction materials. (continued below) 22.0

CD 40 CFR Section 61.356(f)(3)(i-iv); 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) (continued from above) (iii) A detailed description of sampling and monitoring procedures, including sampling and monitoring locations in the system, the equipment to be used, sampling and monitoring frequency, and planned analytical procedures for sample analysis

(iv) All test results.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 23.0

CD 40 CFR Section 61.356(j); 40 CFR Section 61.356(j)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) For each control device, maintain documentation that includes the following information regarding the control device operation: (1) Dates of startup and shutdown of the closed-vent system and control device;

(2) A description of the operating parameter (or parameters) to be monitored to ensure that the control device will be operated in conformance with these standards and the control device's design specifications and an explanation of the criteria used for selection of that parameter (or parameters). This documentation shall be kept for the life of the control device; and

(3) Periods when the closed-vent system and control device are not operated as designed including all periods and the duration when: Any valve car-seal or closure mechanism is broken or the by-pass line valve position has changed and the flow monitoring devices indicate that vapors are not routed to the control device as required. 24.0

CD 40 CFR Section 61.13(g); 40 CFR Section 61.356; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Retain at the source and make available, upon request, for inspection by the

A dministrator, for a minimum of 2 years, records of emission test results and other

data needed to determine emissions. 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 370 of 407

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. (continued below) 26.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 27.0

CD 40 CFR Section 61.356(j)(4); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Maintain continuous records of the temperature of the gas stream in the combustion zone of the incinerator and records of all 3-hour periods of operation during which the average temperature of the gas stream in the combustion zone is more than 28 °C (50 °F) below the temperature established in most recent destruction efficiency performance test. 28.0

CD hdr REPORTING REQUIREMENTS 29.0

CD 40 CFR Section 61.357(d)(7)(iv)(A); Minn. R. 7011.9930(E); Minn. R. 7017.1010, subp. 3 Quarterly Report: The Permittee shall prepare and submit quarterly reports for each 3-hour period of operation during which the average temperature of the gas stream in the combustion zone of a thermal vapor incinerator, as measured by the temperature monitoring device, is more than 28 °C (50 °F) below the design combustion zone temperature. 30.0

S/A 40 CFR Section 60.105(e)(3)(ii) Excess Emissions/Downtime Reports (EER's): due 30 days after end of each calendar quarter starting 01/31/2006. Cover letter, certification, and summary of exceedances shall be submitted in hardcopy or electronic format; all other information may be submitted electronically. The reports shall be certified per Minn. R. 7007.0500, subp. 3. 31.0

CD 40 CFR Section 61.13(c) The owner or operator shall notify the Administrator of intent to conduct a required performance test at least 30 days before the performance test is scheduled. 32.0

CD 40 CFR Section 61.13(f) Unless otherwise specified in an applicable subpart, samples shall be analyzed and emissions determined within 30 days after each emission test has been completed. The owner or operator shall report the determinations of the emission test to the

A dministrator by a registered letter sent before the close of business on the 31st day following the completion of the emission test. 33.0

CD hdr OTHER REQUIREMENTS 34.0

CD 40 CFR Section 61.349(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Control device and closed vent system must be operated at all times when waste is in the waste management unit vented to the control device. 35.0

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Maintain compliance with design, equipment, work practice, operational standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 36.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 371 of 407

CD 40 CFR Section 61.349(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The control device shall be designed and operated in accordance with the following

conditions: (i) An enclosed combustion device (e.g., a vapor incinerator, boiler, or process heater) shall meet one of the following conditions: (A) Reduce the organic emissions vented to it by 95 weight percent or greater;

(B) Achieve a total organic compound concentration of 20 ppmv (as the sum of the concentrations for individual compounds using Method 18) on a dry basis corrected to 3 percent oxygen; or

(C) Provide a minimum residence time of 0.5 seconds at a minimum temperature of 760 °C (1,400 °F). If a boiler or process heater issued as the control device, then the vent stream shall be introduced into the flame zone of the boiler or process

heater. 37.0

CD 40 CFR Section 61.349(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) If visible defects are observed during an inspection, or if other problems are identified, or if detectable emissions are measured, a first effort to repair the closed-vent system and control device shall be made as soon as practicable but no later than 5 calendar days after detection. Repair shall be completed no later than 15 calendar days after the emissions are detected or the visible defect is observed. 38.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) a) Delay of repair of facilities or units will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 39.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 372 of 407

Subject Item: CE 057 Direct Flame Afterburner

Associated Items: EU 276 Central Buffer Zone Offgas (86H41) - Refining Equipment

GP 126 Affected Sources at the refinery under MACT GGGGG

NC/

CA Type Citation Requirement

CD hdr POLLUTION CONTROL EQUIPMENT AND CAM REQUIREMENTS 1.0

LIMIT Minn. R. 7017.2025, subp. 3 Temperature: greater than or equal to 1279 degrees F using 3-hour Rolling

A verage 2.0

LIMIT 40 CFR Section 61.349(a)(2)(i)(A);
Minn. R. 7017.2025; Minn. R. 7011.9930(E) Total Organic Compounds: greater than or equal to 95 percent destruction efficiency (by weight) as demonstrated by performance test. 3.0

CD 40 CFR Section 61.354(c)(1); 40 CFR Section 61.356(j)(4); Minn. R. 7017.2025; Minn. R. 7011.9930(E) Temperature: Maintain temperature no greater than 28 degree Celsius (50 degree F) below the most recent performance test design temperature as a 3-hour rolling

average. 4.0

CD 40 CFR Section 61.349(a)(2)(i)(A); Minn. R. 7011.9930(E) The Permittee must design the control device to meet performance standard: Reduce the organic emissions vented to it by 95 weight percent or greater. 5.0

CD 40 CFR Section 64.3; Minn. R. 7017.0200; 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) Daily Records: The Permittee shall maintain continuous records of the temperature of the gas stream in the combustion zone of the incinerator and records of all 3-hour periods of operation during which the average temperature of the gas stream in the combustion zone is more than 28 °C (50 °F) below the design combustion zone temperature. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 6.0

CD 40 CFR Section 64.3(b); Minn. R. 7017.0200; 40 CFR Section 61.354(c)(1); Minn. R. 7011.9930.(E) The Permittee shall install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified in 40 CFR Section 61.354(c)(1), unless alternative monitoring procedures or requirements are approved for that facility by the

A dministrator. The Permittee shall inspect at least once each operating day the data recorded by the monitoring equipment (e.g., temperature monitor or flow indicator) to ensure that the control device is operating properly. 7.0

CD 40 CFR Section 64.3; Minn. R.

7017.0200 Inspections: Conduct periodic inspections in accordance with the CAM Plan. 8.0

CD 40 CFR Section 64.3(a)(2); Minn. R. 7017.0200; 40 CFR Section 61.349(h); 40 CFR Section 61.354(c); 40 CFR Section 61.354(c)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Install, calibrate, maintain, and operate according to the manufacturer's specifications a device to continuously monitor the control device operation as specified below, unless alternative monitoring procedures or requirements are approved. Inspect at least once each operating day the data recorded by the monitoring equipment to ensure that the control device is operating properly.

For a thermal vapor incinerator, a temperature monitoring device equipped with a continuous recorder. The device shall have an accuracy of ±1 percent of the temperature being monitored in °C or ±0.5 °C, whichever is greater. The temperature sensor shall be installed at a representative location in the combustion

chamber. 9.0

CD 40 CFR Section 64.7(d); Minn. R.

7017.0200 Corrective Actions: The Permittee shall follow the corrective actions, as outlined in the CAM Plan. If the temperature is below the minimum specified by this permit or if the thermal oxidizer or any of its components are found during the inspections to need repair, the Permittee shall take corrective action as soon as possible. Corrective actions shall return the temperature to at least the permitted minimum and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the thermal oxidizer. The Permittee shall keep a record of the type and date of any corrective action taken. 10.0

CD 40 CFR Section 64.7(e); Minn. R.

7017.0200 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing minimum combustion chamber temperature(s), the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 373 of 407

CD 40 CFR Section 64.9(b); Minn. R.

7017.0200 The Permittee shall maintain records of monitoring data, monitor performance data, corrective actions taken, and other supporting information required to be maintained in accordance with the CAM Plan. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. 12.0

CD 40 CFR Section 61.349(a)(1)(i) Closed vent system and control device shall be designed to operate with no detectable emissions as indicated by an instrument reading of less than 500 ppmv initially and annually by Method 21 monitoring.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 13.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) A n owner or operator shall test equipment for compliance with no detectable emissions as required in accordance with the following requirements: (1) Monitoring shall comply with Method 21 from appendix A of 40 CFR pt. 60;

(2) The detection instrument shall meet the performance criteria of Method 21.

(3) The instrument shall be calibrated before use on each day of its use by the procedures specified in Method 21. (continued below) 14.0

CD 40 CFR Section 61.355(h); 40 CFR Section 61.356(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above) 4) Calibration gases shall be: (i) Zero air (less than 10 ppm of hydrocarbon in air); and

(ii) A mixture of methane or n-hexane and air at a concentration of approximately, but less than, 10,000 ppm methane or n-hexane.

(5) The background level shall be determined as set forth in Method 21.

(6) The instrument probe shall be traversed around all potential leak interfaces as close as possible to the interface as described in Method 21.

(7) The arithmetic difference between the maximum concentration indicated by the instrument and the background level is compared to 500 ppm for determining compliance. 15.0

CD CD 40 CFR Section 61.349(f); 40 CFR Section 61.356(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Each closed-vent system and control device shall be visually inspected quarterly. The visual inspection shall include inspection of ductwork and piping and

connections to covers and control devices for evidence of visible defects such as holes in ductwork or piping and loose connections. 16.0

CD 40 CFR Section 61.349(a)(1); 40 CFR Section 61.355(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Vent systems that contain any bypass line that could divert the vent stream away from a control device shall install, maintain, and operate according to the manufacturer's specifications a flow indicator that provides a record of vent stream flow away from the control device at least once every 15 minutes OR ensure the bypass line valve is closed by securing with a car-seal or lock-and-key type device. Exception is for a vent to atmosphere that remains in a closed, sealed position during normal operations except when the device needs to open to prevent physical damage or permanent deformation of the closed-vent system resulting from malfunction of the unit in accordance with good engineering and safety practices for handling flammable, explosive, or other hazardous materials. 17.0

CD 40 CFR Section 61.354(f); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Owners or operators using a closed-vent system that contains any bypass line that could divert a vent stream from a control device shall do the following:

(1) Visually inspect the bypass line valve at least once every month, checking the position of the valve and the condition of the car-seal or closure mechanism required under 40 CFR Section 61.349(a)(1)(ii) to ensure that the valve is maintained in the closed position and the vent stream is not diverted through the bypass line.

(2) Visually inspect the readings from each flow monitoring device required by 40 CFR Section 61.349(a)(1)(ii) at least once each operating day to check that vapors are being routed to the control device as required. 18.0

CD hdr RECORDKEEPING REQUIREMENTS 19.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 374 of 407

CD 40 CFR Section 61.14(f); Minn. R.

7011.9900 CMS Records: The Permittee shall maintain records of monitoring data, monitoring system calibration checks, and the occurrence and duration of any period during which the monitoring system is malfunctioning or inoperative. These records shall be maintained at the source for a minimum of 2 years and made available, upon request, for inspection by the Administrator. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 20.0

CD 40 CFR Section 61.356(f)(3)(i-iv); 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) Performance test was used to determine control device performance; therefore, the Permittee will maintain the following records:

(i) A description of how it is determined that the test is conducted when the waste management unit or treatment process is operating at the highest load or capacity level. This description shall include the estimated or design flow rate and organic content of each vent stream and definition of the acceptable operating ranges of key process and control parameters during the test program.

(ii) A description of the control device including the type of control device, control device manufacturer's name and model number, control device dimensions, capacity, and construction materials. (continued below) 21.0

CD 40 CFR Section 61.356(f)(3)(i-iv); 40 CFR Section 61.356(j)(4); Minn. R. 7011.9930(E) (continued from above) (iii) A detailed description of sampling and monitoring procedures, including sampling and monitoring locations in the system, the equipment to be used, sampling and monitoring frequency, and planned analytical procedures for sample analysis

(iv) All test results.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 22.0

CD 40 CFR Section 61.356(j); 40 CFR Section 61.356(j)(1); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) For each control device, maintain documentation that includes the following information regarding the control device operation: (1) Dates of startup and shutdown of the closed-vent system and control device;

(2) A description of the operating parameter (or parameters) to be monitored to ensure that the control device will be operated in conformance with these standards and the control device's design specifications and an explanation of the criteria used for selection of that parameter (or parameters). This documentation shall be kept for the life of the control device; and

(3) Periods when the closed-vent system and control device are not operated as designed including all periods and the duration when: Any valve car-seal or closure mechanism is broken or the by-pass line valve position has changed and the flow monitoring devices indicate that vapors are not routed to the control device as required. 23.0

CD 40 CFR Section 61.13(g); 40 CFR Section 61.356; 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Retain at the source and make available, upon request, for inspection by the

A dministrator, for a minimum of 2 years, records of emission test results and other

data needed to determine emissions. 24.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Recordkeeping: An owner or operator shall maintain a record for each visual inspection required by 40 CFR Sections 61.343 through 61.347 that identifies a problem (such as a broken seal, gap or other problem) which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. (continued below) 25.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 375 of 407

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) (continued from above)

A n owner or operator shall maintain a record for each test of no detectable emissions required. The record shall include the following information: date the test is performed, background level measured during test, and maximum concentration indicated by the instrument reading measured for each potential leak interface. If detectable emissions are measured at a leak interface, then the record shall also include the waste management unit, control equipment, and leak interface location where detectable emissions were measured, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed.

The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 26.0

CD 40 CFR Section 61.356(j)(4); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Maintain continuous records of the temperature of the gas stream in the combustion zone of the incinerator and records of all 3-hour periods of operation during which the average temperature of the gas stream in the combustion zone is more than 28 °C (50 °F) below the temperature established in most recent destruction efficiency performance test. 27.0

CD hdr REPORTING REQUIREMENTS 28.0

CD 40 CFR Section 61.357(d)(7)(iv)(A); Minn. R. 7011.9930(E); Minn. R. 7017.1010, subp. 3 Quarterly Report: The Permittee shall prepare and submit quarterly reports for each 3-hour period of operation during which the average temperature of the gas stream in the combustion zone of a thermal vapor incinerator, as measured by the temperature monitoring device, is more than 28 °C (50 °F) below the design combustion zone temperature. 29.0

S/A 40 CFR Section 60.105(e)(3)(ii) Excess Emissions/Downtime Reports (EER's): due 30 days after end of each calendar quarter starting 01/31/2006. Cover letter, certification, and summary of exceedances shall be submitted in hardcopy or electronic format; all other information may be submitted electronically. The reports shall be certified per Minn. R. 7007.0500, subp. 3. 30.0

CD 40 CFR Section 61.13(c) The owner or operator shall notify the Administrator of intent to conduct a required performance test at least 30 days before the performance test is scheduled. 31.0

CD 40 CFR Section 61.13(f) Unless otherwise specified in an applicable subpart, samples shall be analyzed and emissions determined within 30 days after each emission test has been completed. The owner or operator shall report the determinations of the emission test to the

A dministrator by a registered letter sent before the close of business on the 31st day following the completion of the emission test. 32.0

CD hdr OTHER REQUIREMENTS 33.0

CD 40 CFR Section 61.349(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) Control device and closed vent system must be operated at all times when waste is in the waste management unit vented to the control device. 34.0

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Maintain compliance with design, equipment, work practice, operational standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 35.0

CD 40 CFR Section 61.349(a)(2); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) The control device shall be designed and operated in accordance with the following

conditions: (i) An enclosed combustion device (e.g., a vapor incinerator, boiler, or process heater) shall meet one of the following conditions: (A) Reduce the organic emissions vented to it by 95 weight percent or greater;

(B) Achieve a total organic compound concentration of 20 ppmv (as the sum of the concentrations for individual compounds using Method 18) on a dry basis corrected to 3 percent oxygen; or

(C) Provide a minimum residence time of 0.5 seconds at a minimum temperature of 760 °C (1,400 °F). If a boiler or process heater issued as the control device, then the vent stream shall be introduced into the flame zone of the boiler or process

heater. 36.0

CD 40 CFR Section 61.349(g); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) If visible defects are observed during an inspection, or if other problems are identified, or if detectable emissions are measured, a first effort to repair the closed-vent system and control device shall be made as soon as practicable but no later than 5 calendar days after detection. Repair shall be completed no later than 15 calendar days after the emissions are detected or the visible defect is observed. 37.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 376 of 407

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 63.655(a); Minn. R. 7011.9930(E) a) Delay of repair of facilities or units will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown. 38.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 377 of 407

Subject Item: FS 001 Unburied Sewer Lines subject to NESHAP FF or NSPS QQQ - Material Handling/Transfer/Storage

Associated Items: GP 067 All equipment included in individual drai n system subject to NSPS QQQ or NESHAPs FF

GP 102 Units where carbon canisters may be used to meet NESHAP FF Requirements

NC/

CA Type Citation Requirement

CD 40 CFR Section 61.346(a)(1)(i); 40 CFR Section 61.346(a)(1)(i)(B); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Each opening shall be maintained in a closed, sealed position (e.g., covered by a lid that is gasketed and latched) at all times that waste is in the drain system except when it is necessary to use the opening for waste sampling or removal, or for equipment inspection, maintenance, or repair.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 1.0

CD 40 CFR Section 61.12(b); Minn. R.

7011.9900 Maintain compliance with design, equipment, work practice, operational standards.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 2.0

CD 40 CFR Section 61.346(b)(3); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Each sewer line shall not be open to the atmosphere and shall be covered or enclosed in a manner so as to have no visual gaps or cracks in joints, seals, or

other emission interfaces.

A departure from this equipment specification is not considered a permit deviation as long as it is corrected (or properly qualified for delay of repair) within the time frame specified by regulation. 3.0

CD 40 CFR Section 61.346(b)(4)(iv); Minn. R. 7011.9930(E) For NESHAP, Subpart FF controlled sewers, the unburied portion of each sewer line shall be visually inspected initially and quarterly for indication of cracks, gaps, or other problems that could result in benzene emissions. 4.0

CD 40 CFR Section 61.350(a); 40 CFR Section 61.350(b); 40 CFR Section 60.692-6(a); 40 CFR Section 60.697(e)(1)-(4); Minn. R. 7011.1435(C); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) a) Delay of repair of facilities or units will be allowed if the repair is technically impossible without a complete or partial facility or unit shutdown.

(b) Repair of such equipment shall occur before the end of the next facility or unit

shutdown 5.0

CD 40 CFR Section 61.346(a)(3); 40 CFR Section 61.346(b)(5); 40 CFR Section 61.357(d)(8); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) Repair problems found during NESHAP visual inspections: When a broken seal or gasket or other problem is identified, or when detectable emissions are measured, first efforts at repair shall be made as soon as practicable, but not later than 15 calendar days after identification unless qualifying for delay of repair. 6.0

CD 40 CFR Section 61.356(g)-(h); 40 CFR Section 63.654(a); Minn. R. 7011.9930(E) For NESHAP, Subpart FF Records: Maintain a record for each visual inspection required that identifies a problem (such as a broken seal, gap or other problem)

which could result in benzene emissions. The record shall include the date of the inspection, waste management unit and control equipment location where the problem is identified, a description of the problem, a description of the corrective action taken, and the date the corrective action was completed. 7.0

CD 40 CFR Section 60.692-2(c)(1)-(2); Minn. R. 7011.1435(C) For NSPS, Subpart QQQ sewers, sewer lines shall not be open to the atmosphere and shall be covered or enclosed in a manner so as to have no visual gaps or cracks in joints, seals, or other emission interfaces.

The portion of each unburied sewer line shall be visually inspected initially and semiannually thereafter for indication of cracks, gaps, or other problems that could

result in VOC emissions. 8.0

CD 40 CFR Section 60.697(b)(3); Minn. R. 7011.1435(C) For NSPS, Subpart QQQ Records: The location, date, and corrective action shall be recorded for inspections when a problem is identified that could result in VOC

emissions. 9.0

CD 40 CFR Section 60.697(f)(1)-(2); 40 CFR Section 60.697(f)(2)(i)-(ii); Minn. R. 7011.1435(C) For NSPS, Subpart QQQ Records: A copy of the design specifications for all equipment shall be kept for the life of the source in a readily accessible location.

(2) The following information pertaining to the design specifications shall be kept. (i) Detailed schematics, and piping and instrumentation diagrams. (ii) The dates and descriptions of any changes in the design specifications. 10.0MINNESOTA POLLUTION CONTROL AGENCY

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 378 of 407

Subject Item: FS 009 Coke Pile - Piles

NC/

CA Type Citation Requirement

CD hdr EMISSION LIMITS 1.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Total Particulate Matter: less than or equal to 379.3 tons/year using 12-month Rolling Sum , effective upon startup of the modified 11H6 furnace (EU 212), new 25H2 furnace (EU 353) or new 23H3 furnace (EU 352), whichever is first, as part of the #3 Crude/Coker Improvements permit.

For the first 11 months after the limit is effective, PM emissions are limited as determined by the following equation:

E=379.3 x [0.15 + 0.85(M/12)]

where

E=emissions in total tons

M=number of months after limit is effective 2.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 10 micron: less than or equal to 119.2 tons/year using 12-month Rolling Sum , effective upon startup of the modified 11H6 furnace (EU 212), new 25H2 furnace (EU 353) or new 23H3 furnace (EU 352), whichever is first, as part of the #3 Crude/Coker Improvements permit.

For the first 11 months after the limit is effective, PM10 emissions are limited as determined by the following equation:

E=119.2 x [0.15 + 0.85(M/12)]

where

E=emissions in total tons

M=number of months after limit is effective 3.0

LIMIT Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 PM < 2.5 micron: less than or equal to 13.2 tons/year using 12-month Rolling Sum , effective upon startup of the modified 11H6 furnace (EU 212), new 25H2 furnace (EU 353) or new 23H3 furnace (EU 352), whichever is first, as part of the #3 Crude/Coker Improvements permit.

For the first 11 months after the limit is effective, PM2.5 emissions are limited as determined by the following equation:

E=13.2 x [0.15 + 0.85(M/12)]

where

E=emissions in total tons

M=number of months after limit is effective 4.0

CD hdr RECORDKEEPING & OTHER REQUIREMENTS 5.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.

7007.3000 Recordkeeping: The Permittee shall calculate and record the 12-month Rolling Sum of PM, PM10 and PM2.5 emissions by the 28th day of each month for the preceding month. Emissions shall be calculated using the equations in Appendix G of the facility Pt. 70 permit unless a different emissions factor is developed by the Permittee and approved by the MPCA in accordance with Minn. R. 7019.3040 - 7019.3100. This requirement is effective upon startup of the modified 11H6 furnace (EU 212), new 25H2 furnace (EU 353), or new 23H3 furnace (EU 352), whichever is first, as part of the #3 Crude/Coker Improvements permit. 6.0

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7011.0150 Coke Fugitive Dust Control Plan: The plan shall include a statement of objectives, identify the roads associated with transporting petroleum coke, describe primary and contingent control measures and practices, describe the employee training program and identify the records to be kept to demonstrate plan implementation. The Commissioner may require additions or changes to the plan when granting approval. The Permittee will be given an opportunity to comment on any required addition or change. The plan may be amended by the Permittee with the Commissioner's approval. If the Commissioner determines that the Permittee is out of compliance with Minn. R. 7011.0150, 40 CFR Section 52.21 and/or the coke fugitive dust control plan, then the Permittee may be required to amend the control plan. 7.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 379 of 407

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7011.0150 Comply with the Coke Fugitive Dust Control Plan: Prior to the MPCA approval of the Coke Fugitive Dust Control Plan (control plan), the Permittee shall follow the actions and recordkeeping in the control plan as proposed. Upon approval of the control plan, the Permittee shall follow the actions and recordkeeping specified in the control plan as approved. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 380 of 407

Subject Item: FS 027 15-Coker Gasoline - Process Emissions

Associated Items: GP 067 All equipment included in individual drai n system subject to NSPS QQQ or NESHAPs FF

GP 068 Drains subject to NESH FF equipped with plugs

GP 069 Drains subject to NESH FF and also subject to NSPS QQQ (wat er seal; lube oil or equivalent)

GP 076 Junction Boxes subject to N ESH FF when equipped with carbon canisters

GP 082 Fugitive Compressors LDAR Requirements

GP 087 Fugitive LDAR All Equipment in VOC or HAP Service

GP 090 Fugitive LDAR Equipment De signated Non-detectable emissions (NDE)

GP 091 Fugitive LDAR Open-ended Lines

GP 093 Fugitive LDAR PSV to Atmosphere in Gas/Vapor Service

GP 095 Fugitive LDAR Pumps In Heavy Liquid Service

GP 096 Fugitive LDAR Light Liquid Pumps

GP 099 Fugitive LDAR Sample Stations

GP 100 Fugitive LDAR Heavy Liqui d Valves and PSVs (in LL/HL Service)

GP 101 Fugitive LDAR Valv es in Light Liquid Service

GP 102 Units where carbon canisters may be used to meet NESHAP FF Requirements

GP 124 Drains subject to NESH FF only and equipped w/water seal or equivalent

GP 125 Drains subject to N ESH FF and NSPS QQQ sealed with plugs

NC/

CA Type Citation Requirement

CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGG; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 61.242-7; Minn. R. 7007.0800, subp. 2 Each valve that is in VHAP service subject to NESHAPs J/V shall be monitored monthly to detect leaks by Method 21. Leak detection and followup to leak detection shall follow refinery consolidated LDAR program. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 381 of 407

Subject Item: FS 045 23- Delayed Coker & Gasoline Plant - Process Emissions

Associated Items: GP 067 All equipment included in individual drai n system subject to NSPS QQQ or NESHAPs FF

GP 076 Junction Boxes subject to N ESH FF when equipped with carbon canisters

GP 077 Junction Boxes receiving Wastewater from NSPS QQQ Units not subject to NESHAPs FF

GP 082 Fugitive Compressors LDAR Requirements

GP 087 Fugitive LDAR All Equipment in VOC or HAP Service

GP 090 Fugitive LDAR Equipment De signated Non-detectable emissions (NDE)

GP 091 Fugitive LDAR Open-ended Lines

GP 093 Fugitive LDAR PSV to Atmosphere in Gas/Vapor Service

GP 094 Fugitive LDAR PSV with Upstream Rupture Disks

GP 095 Fugitive LDAR Pumps In Heavy Liquid Service

GP 096 Fugitive LDAR Light Liquid Pumps

GP 099 Fugitive LDAR Sample Stations

GP 100 Fugitive LDAR Heavy Liqui d Valves and PSVs (in LL/HL Service)

GP 101 Fugitive LDAR Valv es in Light Liquid Service

GP 102 Units where carbon canisters may be used to meet NESHAP FF Requirements

GP 132 Fugitive Equipment in Natural Gas (non-VOC) Service

NC/

CA Type Citation Requirement

NC CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; Minn. R. 7007.0800, subp. 2 Replace or correct remaining open-ended lines in the 23 coker identified in the January 6, 2006, correspondence from FHR to MPCA to ensure compliance with 40 CFR Section 60.482-6a by the end of the next turnaround involving replacement of the #3 coke drums, anticipated to occur in Fall 2013. 1.0

CA CD 40 CFR pt. 70 (consolidated LDAR requirements based on various applicable provisions of 40 CFR pt. 60, subps. A and GGGa; 40 CFR pt. 61, subps. A, J and V; 40 CFR pt. 63, subps. A and CC); 40 CFR Section 60.482-6a; Minn. R. 7007.0800, subp. 2 Replace or correct remaining open-ended lines in the 23 coker identified in the January 6, 2006, correspondence from FHR to MPCA to ensure compliance with 40 CFR Section 60.482-6a by the end of the next turnaround involving replacement of the #3 coke drums, anticipated to occur in Fall 2013. 1.1MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 382 of 407

Subject Item: FS 136 25 Unit Drains Requiring Emission Controls - Process Emissions

NC/

CA Type Citation Requirement

CD Title I Condition: To avoid classification as a major

modification under 40 CFR

Section 52.21 & Minn. R.
7007.3000; Minn. R. 7011.0150 Comply with the requirements in GP 071, GP 072, or GP 075, as applicable. 1.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 383 of 407

Subject Item: MR 027 23H-2 O2 Analyzer

Associated Items: CM 013 #3 Coker Heater: 0.12 lbs NOx/mmBtu (365-day ave.) EU 035

CM 014 #3 Coker Heater: 0.10 lbs CO/mmBtu (1-hr ave.) EU 035

EU 035 #3 Coker Heater - Process Heater

SV 033 23H2 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 1.0

CD Minn. R. 7017.1160, subps. 1 & 2 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points:

A . four data points, equally spaced, if the emission unit operated during the entire
hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration
or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the

hour. 2.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 3.0

CD Minn. R. 7017.1170, subp. 3 Requirement: CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3 and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 5.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following Cylinder Gas Audit 6.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 7.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 8.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 384 of 407

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 9.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. 10.0MINNESOTA POLLUTION CONTROL AGENCY

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520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 385 of 407

Subject Item: MR 033 45 Drum Fuel Gas Combustion O2 Monitor at 25H3

Associated Items: CM 017 #3 Crude Unit Vac Distillate Heater: 0.12 lbs NOx/mmBtu (365-day ave.); 0.10 lbs CO/mmBtu (1-hr ave.); E U

EU 041 #3 Crude Unit Vac Pre-Frac tionator Heater - Process Heater

GP 116 Refinery Fuel Gas SO2 Emissions

SV 038 25H3 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

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# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 386 of 407

Subject Item: MR 069 31H2 SO2 Analyzer

Associated Items: CM 055 31H2: 66.4 lbs SO2/hr (3-hr avg) EU 055

EU 055 #2 HDS Fractionation Heater (31H2) - Fractionation Equipment

SV 049 31H2 Stack

NC/

CA Type Citation Requirement

CD hdr CEM REQUIREMENTS FOR SO2 1.0

CD Title I Condition: 40 CFR Section 50.4, SO2 SIP; TItle I Condition: 40 CFR pt. 52, subp. Y; Title I Condition: CAAA of 1990; Minn.

R. 7017.1006 SO2 Emissions Monitoring: The Permittee shall calibrate, operate and maintain SO2 Continuous Emissions Monitoring System (CEMS). 2.0

CD Minn. R. 7017.1006 SO2 Emissions Measuring: The Permittee shall use a sulfur dioxide CEMS to

measure sulfur dioxide emissions from SV049. 3.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 4.0

S/A 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 Cylinder Gas Audit: due before end of each calendar half-year following CEM Certification Test. Conduct CGAs at least 3 months apart, but not greater than 8 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 5.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 6.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 7.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 8.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 9.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit startup, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C, and D of Minn. R. 7017.1090, subp. 2. 10.0

CD Minn. R. 7007.1130 Recordkeeping: The Permittee must retain records of all CEMS monitoring data and supporting information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. 11.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 12.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 387 of 407

CD 40 CFR pt. 60, Appendix F; 40 CFR Section 60.13(a) CEMS QA/QC: The Permittee of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60,

A ppendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. 13.0

CD 40 CFR pt. 60, Appendix F; Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 14.0

CD 40 CFR pt. 60, Appendix B and

A ppendix F; Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due at least once every four calendar quarters after CEMS certification. Follow the procedures in 40 CFR pt. 60,

A ppendix B and Appendix F. 15.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 388 of 407

Subject Item: MR 152 NOx Monitor at 25H4

Associated Items: EU 324 #3 Crude Unit Vacuum Heater - Process Heater

SV 176 25H4 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 389 of 407

Subject Item: MR 153 CO Monitor at 25H4

Associated Items: EU 324 #3 Crude Unit Vacuum Heater - Process Heater

SV 176 25H4 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 390 of 407

Subject Item: MR 154 O2 Monitor at 25H4

Associated Items: EU 324 #3 Crude Unit Vacuum Heater - Process Heater

SV 176 25H4 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 391 of 407

Subject Item: MR 156 41 Unit Fuel Gas Mix Drum Total Sulfur

Associated Items: GP 116 Refinery Fuel Gas SO2 Emissions

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F, using certified reference materials since EPA Protocol 1 gases do not exist. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3.The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 392 of 407

Subject Item: MR 161 45 Mix Drum Fuel Gas Combustion SO2 Monitor at 25H3

Associated Items: EU 041 #3 Crude Unit Vac Pre-Frac tionator Heater - Process Heater

GP 116 Refinery Fuel Gas SO2 Emissions

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 393 of 407

Subject Item: MR 162 45 SO2 Monitor at 29H1/2

Associated Items: GP 116 Refinery Fuel Gas SO2 Emissions

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 394 of 407

Subject Item: MR 166 45 Mix Drum Fuel Gas Combustion O2 Monitor at 29H1/2

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

GP 116 Refinery Fuel Gas SO2 Emissions

SV 165 Hydrocracker Feed Heater and Reboiler

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 395 of 407

Subject Item: MR 167 27H-101 CO Monitor

Associated Items: EU 050 Distillate HDS Recycle Hydrogen Charge Heater - Process Heater

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 396 of 407

Subject Item: MR 168 27H-101 NOx Monitor

Associated Items: EU 050 Distillate HDS Recycle Hydrogen Charge Heater - Process Heater

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 397 of 407

Subject Item: MR 170 71B6 NOx Monitor

Associated Items: EU 126 Steam Boiler No. 6 at Boilerhouse - Boiler

NC/

CA Type Citation Requirement

CD 40 CFR Section 60.48b; Minn. R.

7017.1006 Emissions Monitoring: The Permittee shall use a nitrogen oxides (NOx) CEMS to measure NOx emissions from EU 126. Specifications for the operation of the monitoring equipment are in 40 CFR Section 60.48b(c), (d), (e), (f), and Appendix

B. 1.0

CD 40 CFR Section 60.7(b) Records of Startup, Shutdown, or Malfunction: Any owner or operator subject to the provisions of 40 CFR pt. 60, subp. Db, shall maintain records of the occurrence and duration of any startup, shutdown, or malfunction in the operation of an affected facility; any malfunction of the air pollution control equipment; or any periods during which a continuous monitoring system or monitoring device is inoperative. 2.0

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 3.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 5.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 6.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 7.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 8.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 9.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 10.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 11.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 398 of 407

Subject Item: MR 171 71B6 CO Monitor

Associated Items: EU 126 Steam Boiler No. 6 at Boilerhouse - Boiler

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix

F. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of EU126 operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 399 of 407

Subject Item: MR 179 29H-1/2 NOx Monitor

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

SV 165 Hydrocracker Feed Heater and Reboiler

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 1.0

CD Minn. R. 7017.1160, subps. 1 & 2 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points:

A . four data points, equally spaced, if the emission unit operated during the entire
hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration
or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the

hour. 2.0

CD Minn. R. 7017.1170, subp. 3 Requirement: CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3 and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. 3.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following Cylinder Gas Audit 5.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 6.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 7.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 8.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 400 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 401 of 407

Subject Item: MR 180 29H-1/2 CO Monitor

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

SV 165 Hydrocracker Feed Heater and Reboiler

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 1.0

CD Minn. R. 7017.1160, subps. 1 & 2 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points:

A . four data points, equally spaced, if the emission unit operated during the entire
hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration
or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the

hour. 2.0

CD Minn. R. 7017.1170, subp. 3 Requirement: CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3 and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. 3.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following Cylinder Gas Audit 5.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 6.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 7.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 8.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless it is expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 402 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 403 of 407

Subject Item: MR 181 29H-1/2 O2 Monitor

Associated Items: EU 294 Hydrocracker Feed Heater - Process Heater

EU 295 Hydrocracker Reboiler - Boiler

SV 165 Hydrocracker Feed Heater and Reboiler

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 1.0

CD Minn. R. 7017.1160, subps. 1 & 2 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points:

A . four data points, equally spaced, if the emission unit operated during the entire
hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration
or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the

hour. 2.0

CD Minn. R. 7017.1170, subp. 3 Requirement: CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3 and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. 3.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 5.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 6.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 7.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 8.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 404 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 405 of 407

Subject Item: MR 182 27H-101 O2 Monitor

Associated Items: EU 050 Distillate HDS Recycle Hydrogen Charge Heater - Process Heater

SV 044 27H101 Stack

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 1.0

CD Minn. R. 7017.1160, subps. 1 & 2 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points:

A . four data points, equally spaced, if the emission unit operated during the entire
hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration
or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the

hour. 2.0

CD Minn. R. 7017.1170, subp. 3 Requirement: CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3 and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. 3.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 4.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 5.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 6.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 7.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 8.0

CD Minn. R. 7017.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 9.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 406 of 407

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 10.0MINNESOTA POLLUTION CONTROL AGENCY

AIR QUALITY

520 LAFAY ETTE ROAD

ST. PAUL, MN 55155-4194 

# COMPLIANCE PLAN 

# CD-01

Facility Name: Flint Hills Resources Pine Bend Refinery

Permit Number: 03700011 - 012 12 Dec, 2014 10:01 Page 407 of 407

Subject Item: MR 196 45 Unit Fuel Gas Mix Drum Total Sulfur

Associated Items: GP 116 Refinery Fuel Gas SO2 Emissions

NC/

CA Type Citation Requirement

CD Minn. R. 7017.1170, subp. 3 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F, using certified reference materials since EPA Protocol 1 gases do not exist. 1.0

CD Minn. R. 7017.1170, subp. 4 CEMS Cylinder Gas Audit (CGA): due before end of each calendar quarter in which a Relative Accuracy Test Audit (RATA) is not conducted. Conduct CGAs at least 2 months apart. Follow the procedures in 40 CFR pt. 60, Appendix F. 2.0

S/A Minn. R. 7017.1180, subp. 1 Cylinder Gas Audit (CGA) Results Summary: due 30 days after end of each calendar quarter following end of the calendar quarter in which the Audit was performed 3.0

CD Minn. R. 7017.1170, subp. 5 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following CEM Certification Test. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart according to 40 CFR pt. 60, Appendix F, section

5.1.1. 4.0

CD Minn. R. 7017.1180, subp. 2 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. The notification may be made by facsimile, mail, electronic mail or

hand-delivered document. 5.0

S/A Minn. R. 7017.1180, subp. 3 Relative Accuracy Test Audit (RATA) Results Summary: due 30 days after end of each calendar quarter following CEMS Relative Accuracy Test Audit (RATA) 6.0

CD Minn. R. 7017.1090, subps. 1 & 2 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. Acceptable monitor downtime includes reasonable periods as listed in Items A, B, C and D of Minn. R. 7017.1090, subp. 2. 7.0

CD Minn. R. 7007.1130 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. The records may be maintained in either electronic or paper format, unless electronic or paper records are expressly prohibited. 8.0

CD Minn. R. 7017.1170, subp. 2 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include or reference the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. The Commissioner may approve requested exclusions if the Commissioner determines that it is not reasonable to keep a specific part on site after consideration of the consequences of a malfunction of the part, the likelihood of a malfunction, the time required to obtain the part, and other pertinent

factors. 9.0

# Attachment 2:

Calculation SpreadsheetsAttachment 1: Table 1PSD Applicability DeterminationNOXSO2COPM1PM101PM2.51VOCSAM2Pb CO2CH4N2OEmission Unit MPCA ID tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy mass tpy CO2eNew EU CTG – Combustion Turbine4(EU CTG) 15.7 2.7 37.9 10.8 10.8 10.8 17.7 3.1 9.3E-04 222,4534.2 0.4 222,457 222,682New EU HRSGDB – Duct Burners4(EU HRSGDB) 12.0 1.5 29.0 6.0 6.0 6.0 10.3 1.7 5.1E-04 122,414 2.3 0.2 122,417 122,541New FS CHP – Equipment in Natural Gas Service(FS CHP) -- -- -- -- -- -- -- -- -- -- 1.6 -- 2 4027.7 4.1 66.9 16.8 16.8 16.8 28.0 4.7 1.4E-03 344,8678.1 0.7 344,875345,26340 40 100 25 15 10 40 7 0.6 -- -- -- 0 75,000No No No NoYes YesNo No No -- -- --Yes Yes1PM is defined to include the filterable fraction only, excluding condensable particulate matter (see 77 Fed. Reg. 65118). Condensable particulate matter is included within the definition of PM10and PM2.5in 40 CFR § 52.21(b)(50). For NSR applicability analysis for this project, FHR did not differentiate filterable from condensable fractions and therefore PM includes filterable and condensable.2Sulfuric acid mist (SAM)3Greenhouse gases are defined as the aggregate group of six greenhouse gases: carbon dioxide, nitrous oxide, methane, hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride. The procedures in40 CFR § 52.21(b)(49) are followed to calculate the CO2equivalent (CO2e) emissions. Greenhouse gases are considered a regulated pollutant for this project if the refinery emits or has the potentialto emit 100,000tpy CO2e, and the project is a physical change or change in the method of operation that results in an emissions increase of CO2e of 75,000 tpy or more.4Presented for informational purposes. Emissions from the CTG and duct burners are commingled prior to control and only the combined, controlled emissions will be monitored.Project Emissions IncreaseGHG3Total Project Emission IncreasePrevention of Significant Deterioration (PSD) Significant Emission Rate(SER)Is Project Emission Increase Greater than PSD Significant EmissionRate?AppendixA,Attachment1‐1Attachment 1: Table 2QuantityValueUnitsReferencePotential FiringRate: 434.5 MMBtu/hrEngineeringestimate for worst case conditions: Full CT load, Fired, WinterHours of Normal Operation: 8712.0 hr/yr8,760 less startup/shutdown hoursStartup/shutdown:48.0 hr/yrAssumed 12 cold startups peryear, 2 hours per startup, 2 hours per shutdownPollutantOperatingConditionEmissionFactorUnitsPotential toEmit(lb/hr) [1]Potential toEmit(tpy) [2]ControlEfficiency [3]ControlledPotential toEmit (lb/hr)[4]ControlledPotential toEmit (tpy) [4]Normal 23.65 lb/hr23.65 103.02 86% 3.39 14.77SU/SD 37.77 lb/hr37.77 0.91 0% 37.77 0.91Total-- -- --103.93-- --15.67SO2[5]All 0.0014 lb/MMBtu 0.61 2.66 0% 0.61 2.66Normal 41.87 lb/hr41.87 182.39 80% 8.31 36.19SU/SD 70.21 lb/hr70.21 1.69 0% 70.21 1.69Total-- -- --184.07-- --37.87PM [6]All 2.48 lb/hr2.48 10.85 0% 2.48 10.85PM10[6]All 2.48 lb/hr 2.48 10.85 0% 2.48 10.85PM2.5[6]All 2.48 lb/hr 2.48 10.85 0% 2.48 10.85VOC [3]All 8.25 lb/hr8.25 36.12 51% 4.05 17.74SAM [7]All 0.0016 lb/MMBtu 0.70 3.06 0% 0.70 3.06Pb All 4.90E-07 lb/MMBtu 2.13E-04 9.33E-04 0% 2.13E-04 9.33E-04CO2[8]All 116.89 lb/MMBtu 50,788 222,453 0% 50,788 222,453CH4[9]All 2.20E-03 lb/MMBtu 0.96 4.20 0% 0.96 4.20N2O [10]All 2.20E-04 lb/MMBtu 9.58E-02 0.42 0% 9.58E-02 0.42CO2e [11]All 117.01 lb/MMBtu 50,841 222,682 0% 50,841 222,682[1] Potential to Emit(lb/hr)= Emission Factor(lb/MMBtu)x Design FiringRate at Normal Operation(MMBtu/hr)orPotential to Emit(lb/hr)= Emission Factor(lb/hr)[2]Potential to Emit (tpy) = Potential to Emit (lb/hr) x Respective Hours of Operation (hr/yr) / 2000 lb/ton[3] Uncontrolled emission factors for NOX, CO, and VOC are based on turbine manufacturer guarantees (for normal operation) and turbine manufacturer estimates (for startup/shutdown);Controlled emission rates are derived from design basis specifications provided to SCR and catalytic oxidation vendors of2.5 ppm NOX, 10 ppm CO, 7.5 ppm VOC, corrected to 15% O2;Control efficiencies are derived from the uncontrolled and controlled emission rates described above. Theyare not proposed permit limits but provided for informational purposes only[4] Presented for informational purposes. Emissions from the CTG are commingled with those from the duct burner prior to control and onlythe combined, controlled emissions will be monitoredSee Table 1 for total controlled emission rate at the compliance point(stack)[5] Emissions based on sulfur content of 0.5gr/100 scf consistent with the definition of pipeline naturalgas as specified in 40 CFR 72.2:(0.5 gr S / 100 scf) / (1020 Btu/scf) * (10^6 Btu/MMBtu) / (7000 gr / lb) * (64 lb SO2/lbmol) / (32 lb S/lbmol) = 0.0014 lb/MMBtu[6] Emission factors for PM/PM10/PM2.5are based on proposed BACT limit.All particulate matter is conservativelyassume to be filterable for the purposes of estimatingPM emissions[7] Emissions based on SO2emission rate and conservative engineering estimate that 75% of SO2is converted to SO3, 100% of which is converted to sulfuric acid mist (H2SO4)Calculation adjusts for the H2SO4's proportionally higher molecular weight of 98 lb/lbmol relative to SO2's molecular weight of 64 lb/lbmol.[8] Emission Factor = 53.02 kg CO2/MMBtu per Table C-1 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[9] Emission Factor = 0.001 kg CH4/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[10] Emission Factor = 0.0001 kg N2O/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[11] As CO2e; Global Warming Potentials of 1 for CO2, 25 for CH4, and 298 for N2O per Table A-1 of 40 CFR 98Consistent with PM 10/2.5 BACT LimitsPotential to Emit for CTGEmission Factor ReferenceNOX[3]Equipment specificationVendor estimate--40 CFR 72.2CO [3]Equipment specificationVendor estimate--40 CFR 98 Subpart C40 CFR 98 Subpart C40 CFR 98 Subpart ABACT limitBACT limitEquipment specificationSee footnotesAP-42 Table 1.4-240 CFR 98 Subpart CAppendixA,Attachment1‐1Attachment 1: Table 3QuantityValueUnitsReferencePotential Firing Rate: 239.1 MMBtu/hr Engineering estimate for worst case conditions: Full CT load, Fired, WinterHours of Operation: 8760 hr/yrPollutantEmissionFactor UnitsPotential toEmit(lb/hr) [1]Potential toEmit(tpy) [2]ControlEfficiency [3]ControlledPotential toEmit (lb/hr)[4]ControlledPotential toEmit (tpy) [4]NOX[3]0.08 lb/MMBtu 19.13 83.78 86% 2.74 12.00SO2[5]0.0014 lb/MMBtu 0.33 1.47 0% 0.33 1.47CO [3] 0.08 lb/MMBtu 19.13 83.78 65% 6.62 28.99PM [6] 0.0057 lb/MMBtu 1.36 5.97 0% 1.36 5.97PM10[6]0.0057 lb/MMBtu 1.36 5.97 0% 1.36 5.97PM2.5[6]0.0057 lb/MMBtu 1.36 5.97 0% 1.36 5.97VOC [3] 0.02 lb/MMBtu 4.78 20.95 51% 2.35 10.28SAM [7] 0.0016 lb/MMBtu 0.38 1.68 0% 0.38 1.68Pb 4.90E-07 lb/MMBtu 1.17E-04 5.13E-04 0% 1.17E-04 5.13E-04CO2[8]116.89 lb/MMBtu 27,948 122,414 0% 27,948 122,414CH4[9]2.20E-03 lb/MMBtu 0.53 2.31 0% 0.53 2.31N2O [10]2.20E-04 lb/MMBtu 5.27E-02 0.23 0% 5.27E-02 0.23CO2e [11]117.01 lb/MMBtu 27,977 122,541 0% 27,977 122,541[1] Potential to Emit (lb/hr) = Emission Factor (lb/MMBtu) x Design Firing Rate at Normal Operation (MMBtu/hr)[2]Potential to Emit (tpy) = Potential to Emit (lb/hr) x Hours of Operation (hr/yr) / 2000 lb/ton[3] Uncontrolled emission factors for NOX, CO, and VOC are based on typically expected duct burner manufacturer guarantees;Controlled emission rates are derived from design basis specifications provided to SCR and catalytic oxidation vendorsof 2.5 ppm NOX, 10 ppm CO, 7.5 ppm VOC,corrected to 15% O2. Control efficiencies are derived from the uncontrolled and controlled emission rates described above. They are not proposed permit limits butprovided for informational purposes only.[4] Presented for informational purposes. Emissions from the duct burners are commingled with those from the CTG prior to control and only the combined, controlledemissions will be monitored. See Table 1 for total controlled emission rate at the compliance point (stack).[5] Emissions based on sulfur content of 0.5 gr/100 scf consistent with the definition of pipeline natural gas as specified in40 CFR 72.2:(0.5 gr S / 100 scf) / (1020 Btu/scf) * (10^6 Btu/MMBtu) / (7000 gr / lb) * (64 lb SO2/lbmol) / (32 lb S/lbmol) = 0.0014 lb/MMBtu[6] Emission factors for PM/PM10/PM2.5are based on proposed BACT limit.All particulate matter is conservatively assume to be filterable for the purposes of estimating PM emissions.[7] Emissions based on SO2emission rate and conservative engineering estimate that 75% of SO2is converted to SO3, 100% of which is converted to SAM (H2SO4)Calculation adjusts for the H2SO4's proportionally higher molecular weight of 98 lb/lbmol relative to SO2's molecular weight of 64 lb/lbmol.[8] Emission Factor = 53.02 kg CO2/MMBtu per Table C-1 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[9] Emission Factor = 0.001 kg CH4/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[10] Emission Factor = 0.0001 kg N2O/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg[11] As CO2e; Global Warming Potentials of 1 for CO2, 25 for CH4, and 298 for N2O per Table A-1 of 40 CFR 98Consistent with PM 10/2.5 BACT LimitsPotential to Emit for Duct BurnersEmission Factor ReferenceEquipment specification40 CFR 72.2Equipment specification40 CFR 98 Subpart C40 CFR 98 Subpart C40 CFR 98 Subpart ABACT limitBACT limitEquipment specificationSee footnotesAP-42 Table 1.4-240 CFR 98 Subpart CAppendixA,Attachment1‐1Attachment 1: Table 4Potential to Emit for New Equipment in Natural Gas Service at Combined Heat and Power Cogeneration FacilityPotential toEmit(tpy) [4]Valves/all0.15Other (Relief Valves, etc.)0.01Flanges1.36Other (compressors)0.02Pump seals/all0.07Process Drains--Total Project Emissions (tpy): --1.6039.94[1] Total number of components estimated based on similar previous projects (75), plus a 33% margin for conservatism.[2] Leak rate is based on LDAR program requirements require additional monitoring if more than 2% of the components are leaking,and no more than 2% can be categorized as difficult to monitor or unsafe to monitor.[3] Emission rate based on RTI International. “Emission Estimation Protocol for Petroleum Refineries.” May 2011.Available at: http://www.epa.gov/ttnchie1/efpac/protocol/Emission_Estimation_Protocol_for_Petroleum_Refinerie_052011.pdf. See Table 2-2.[4] Emissions factor methdology is described in more detail in Section 3.3.3 of Appendix A.[5] These fugitive components are not in VOC service; natural gas contains negligible non-methane non-ethane organic compounds[6] All natural gas is conservatively assumed to be methane (CH4). Global warming potential of 25 used to convert methane to CO2e.Component TypeProjectNumber notleaking [2]Number leaking/non-repairable/Leak rate(non-leakers)Leak ratetotalCount [1] unsafe to monitor [2] (kg/hr) [3] (kg/hr) [3] (kg/hr)Leak rate(leakers)1.06E-03100 96 4 6.83E-03 8.83E-03 1.57E-022 2 0 1.06E-03 --1.59E-03300 288 12 1.05E-01 3.59E-02 1.41E-012 2 -- 1.59E-03 ----2 2 -- 6.80E-03 -- 6.80E-03-- -- -- -- --VOC [5]CH4[6]CO2e [6]AppendixA,Attachment1‐1Attachment 1: Table 5GT Pro Model Outputs and Emission Calculations - Duct Fired CasesGeneralInfoCaseNumber FullCTload,Fired,Summer FullCTload,Fired,ISO FullCTload,Fired,Winter FullCTload,Fired,Winter 75%CTload,Fired,Summer 75%CTload,Fired,ISO 75%CTload,Fired,Winter 75%CTload,Fired,Winter 50%CTload,Fired,Summer 50%CTload,Fired,ISO 50%CTload,Fired,Winter 50%CTload,Fired,WinterCTModel LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PF LM60000PFFuelType NG NG NG NG NG NG NG NG NG NG NG NGCTLoad 100% 100% 100% 100% 75% 75% 75% 75% 50% 50% 50% 50%DuctFiring Y Y Y Y Y Y Y Y Y Y Y YAmbientTemperature,F 88 59 40‐16 88 59 40‐16 88 59 40‐16AmbientPressure,psia 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19AmbientRelativeHumidity,% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60%Elevation 965 965 965 965 965 965 965 965 965 965 965 965Performance&Fuel1Generation,gross(kW) 44,650 51,428 51,425 51,368 35,977 46,409 51,041 51,353 27,383 35,590 38,891 41,457Generation,net(kW) 43,261 49,955 49,909 49,956 34,688 45,022 49,603 49,981 26,168 34,310 37,581 40,160CTHeatInput(MMBtu/hr)(HHV) 314 372 407 435 262 303 332 352 224 248 264 271DBHeatInput(MMBtu/hr)(HHV) 163 201 224 239 129 159 180 189 114 130 141 153HeatRate(HHV)(Btu/kWh)(Gross) 10,682 11,150 12,269 13,125 10,865 9,970 10,042 10,533 12,320 10,638 10,443 10,228HeatRate(HHV)(Btu/kWh)(Net) 11,025 11,479 12,642 13,495 11,269 10,276 10,333 10,823 12,893 11,035 10,807 10,557ExportSteamEnergy(MMBtu/hr) 142 212 244 290 101 91 110 146 84 61 70 76StackParameters1StackHeight(ft) 170 170 170 170 170 170 170 170 170 170 170 170StackDiameter(ft) 12 12 12 12 12 12 12 12 12 12 12 12FlowRate(ft3/s)4,281 5,054 5,500 5,787 3,526 4,027 4,377 4,534 3,219 3,419 3,562 3,634Temperature(F) 250.0 256.2 259.8 268.6 238.2 231.0 228.8 233.9 232.7 220.4 213.9 200.9CTShortTermEmissions(ppmvd)PMPM10PM2.5NOx215 15 15 15 15 15 15 15 15 15 25 15CO225 25 25 25 25 25 25 25 70 70 70 70VOC215.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0CTEmissions(lb/MMBtuHHV)PM30.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM1030.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM2.530.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057NOXSO240.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014COVOCCTEmissions(lb/hr)PM 1.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54PM101.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54PM2.51.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54NOX117.09 20.26 22.12 23.65 14.25 16.48 18.06 19.15 12.16 13.49 14.38 14.74SO240.44 0.52 0.57 0.61 0.37 0.42 0.46 0.49 0.31 0.35 0.37 0.38CO117.34 20.56 22.45 24.00 14.46 16.73 18.33 19.43 34.54 38.32 40.86 41.87VOC15.96 7.07 7.71 8.25 4.97 5.75 6.30 6.68 4.24 4.70 5.02 5.14DBEmissions(lb/MMBtuHHV)PM30.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM1030.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM2.530.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057NOX20.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08SO230.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014CO20.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.08VOC20.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02DBEmissions(lb/hr)PM50.93 1.14 1.28 1.36 0.73 0.91 1.03 1.08 0.65 0.74 0.81 0.87PM1050.93 1.14 1.28 1.36 0.73 0.91 1.03 1.08 0.65 0.74 0.81 0.87PM2.550.93 1.14 1.28 1.36 0.73 0.91 1.03 1.08 0.65 0.74 0.81 0.87NOX113.00 16.04 17.91 19.12 10.30 12.75 14.40 15.09 9.08 10.42 11.31 12.21SO240.23 0.28 0.31 0.33 0.18 0.22 0.25 0.26 0.16 0.18 0.20 0.21CO113.00 16.04 17.91 19.12 10.30 12.75 14.41 15.09 9.08 10.42 11.31 12.21VOC13.25 4.01 4.48 4.78 2.58 3.19 3.60 3.77 2.27 2.61 2.83 3.05HRSGGasComposition(%)1N272.64 73.84 74.18 74.44 72.71 73.92 74.26 74.53 72.91 74.09 74.42 74.77O210.81 10.89 10.84 10.65 11.01 11.11 11.07 10.91 11.59 11.61 11.53 11.60CO24.427 4.547 4.621 4.749 4.333 4.444 4.514 4.632 4.065 4.218 4.302 4.317H2O11.250 9.830 9.468 9.259 11.070 9.631 9.259 9.031 10.550 9.191 8.846 8.415Ar 0.8738 0.8883 0.8923 0.8954 0.8747 0.8892 0.8933 0.8965 0.8772 0.8913 0.8953 0.8995ControlledEmissionRateCalculationsTempRankine 709.67 715.87 719.47 728.27 697.87 690.67 688.47 693.57 692.37 680.07 673.57 660.57%H2O11.3% 9.8% 9.5% 9.3% 11.1% 9.6% 9.3% 9.0% 10.6% 9.2% 8.8% 8.4%%O2dry12.2% 12.1% 12.0% 11.7% 12.4% 12.3% 12.2% 12.0% 13.0% 12.8% 12.6% 12.7%Exhaustflow,acfm 256860 303240 330000 347220 211560 241620 262620 272040 193140 205140 213720 218040Exhaustflow,dscfm 164285 195345 212369 221261 137878 161685 177025 182484 127615 140092 147920 154607NOX,ppmvd@15%O262.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5NOX,ppmvd,actualO23.69 3.74 3.78 3.88 3.61 3.65 3.69 3.77 3.37 3.44 3.50 3.49NOX,lb/hr4.33 5.21 5.73 6.13 3.55 4.21 4.66 4.91 3.06 3.44 3.69 3.85CO,ppmvd@15%O2610.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0CO,ppmvd,actualO214.78 14.95 15.13 15.53 14.44 14.59 14.75 15.10 13.46 13.75 13.98 13.96CO,lb/hr 10.55 12.69 13.96 14.93 8.65 10.24 11.34 11.97 7.46 8.37 8.98 9.37VOC,ppmvd@15%O267.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5VOC,ppmvd,actualO211.08 11.22 11.35 11.65 10.83 10.94 11.06 11.32 10.10 10.32 10.49 10.47VOC,lb/hr 4.52 5.44 5.98 6.40 3.71 4.39 4.86 5.13 3.20 3.59 3.85 4.02TotalPM,lb/hr 2.72 3.26 3.59 3.84 2.23 2.64 2.92 3.08 1.92 2.16 2.31 2.41TotalPM,lb/MMBtu 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057TotalPM,gr/dscf 0.0019 0.0019 0.0020 0.0020 0.0019 0.0019 0.0019 0.0020 0.0018 0.0018 0.0018 0.0018CO2e,lb/hr55,755 67,023 73,763 78,818 45,692 54,094 59,921 63,221 39,432 44,253 47,483 49,554CO2e,lb/MWhgross713.7 664.8 684.2 668.5 761.7 784.9 769.6 734.4 833.5 871.8 843.7 821.51)DatafromGTProModel2)Manufacturerguarantee3)ProposedPM10/PM2.5BACTlimit;PMconservativelyassumedequaltoPM10/PM2.54)Emissionsbasedonsulfurcontentof0.5gr/100scfasspecifiedbynaturalgassupplycontractand40CFR72.2definitionofpipelinenaturalgas:(0.5grS/100scf)/(1020Btu/scf)*(10^6Btu/MMBtu)/(7000gr/lb)*(64lbSO2/lbmol)/(32lbS/lbmol)=0.0014lb/MMBtu5)Calculation6)DesignbasisspecificationprovidedtoSCRand/orcatalyticoxidizervendorAttachment 1: Table 6GT Pro Model Outputs and Emission Calculations - Non-Duct Fired CasesGeneralInfoCaseNumber FullCTload,Unfired,Summer FullCTload,Unfired,ISO FullCTload,Unfired,Winter FullCTload,Unfired,Winter 75%CTload,Unfired,Summer 75%CTload,Unfired,ISO 75%CTload,Unfired,Winter 75%CTload,Fired,Winter 50%CTload,Unfired,Summer 50%CTload,Unfired,ISO 50%CTload,Unfired,Winter 50%CTload,Fired,WinterCTModel LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PF LM6000PFFuelType NG NG NG NG NG NG NG NG NG NG NG NGCTLoad 100% 100% 100% 100% 75% 75% 75% 75% 50% 50% 50% 50%DuctFiring N N N N N N N N N N N NAmbientTemperature,F 88 59 40‐16 88 59 40‐16 88 59 40‐16AmbientPressure,psia 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19 14.19AmbientRelativeHumidity,% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60% 60%Elevation 965 965 965 965 965 965 965 965 965 965 965 965Performance&Fuel1Generation,gross(kW) 39,968 49,056 51,329 51,224 31,356 38,143 42,033 44,732 23,131 27,732 30,307 31,956Generation,net(kW) 38,679 47,685 49,932 49,929 30,153 36,880 40,735 43,491 21,998 26,564 29,118 30,870CTHeatInput(MMBtu/hr)(HHV) 314 372 407 435 262 303 332 352 224 248 264 271DBHeatInput(MMBtu/hr)(HHV)HeatRate(HHV)(Btu/kWh)(Gross) 7,865 7,599 7,928 8,492 8,358 7,950 7,905 7,873 9,675 8,953 8,733 8,489HeatRate(HHV)(Btu/kWh)(Net) 8,127 7,817 8,150 8,712 8,691 8,222 8,157 8,097 10,173 9,346 9,091 8,789ExportSteamEnergy(MMBtu/hr) 0 0 34 66 0 0 0 0 0 0 0 12StackParameters1StackHeight(ft) 170 170 170 170 170 170 170 170 170 170 170 170StackDiameter(ft) 12.33 12.33 12.33 12.33 12.33 12.33 12.33 12.33 12.33 12.33 12.33 12.33FlowRate(ft3/s) 5,075 5,833 6,458 6,825 4,050 4,719 5,178 5,344 3,678 3,982 4,193 4,567Temperature(F) 372.3 379.8 399.3 414.0 353.7 362.4 367.8 371.3 342.4 344.0 345.3 383.6CTShortTermEmissions(ppmvd)PMPM10PM2.5NOx215 15 15 15 15 15 15 15 15 15 15 15CO225 25 25 25 25 25 25 25 70 70 70 70VOC215.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0CTEmissions(lb/MMBtuHHV)PM30.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM1030.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057PM2.530.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057NOXSO240.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014 0.0014COVOCCTEmissions(lb/hr)PM 1.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54PM101.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54PM2.51.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54NOX117.09 20.26 22.12 23.65 14.25 16.48 18.06 19.15 12.16 13.49 14.38 14.74SO240.44 0.52 0.57 0.61 0.37 0.42 0.46 0.49 0.31 0.35 0.37 0.38CO117.34 20.56 22.45 24.00 14.46 16.73 18.33 19.43 34.54 38.32 40.86 41.87VOC15.96 7.07 7.71 8.25 4.97 5.75 6.30 6.68 4.24 4.70 5.02 5.14DBEmissions(lb/MMBtuHHV)PM3PM103PM2.53NOX2SO23CO2VOC2DBEmissions(lb/hr)PM5PM105PM2.55NOX1SO24CO1VOC1HRSGGasComposition(%)1N273.73 75.00 75.39 75.65 73.74 75.04 75.43 75.72 73.90 75.15 75.53 75.92O213.97 14.23 14.28 14.19 14.00 14.33 14.41 14.30 14.47 14.66 14.68 14.87CO22.972 3.014 3.040 3.126 2.956 2.968 2.983 3.075 2.743 2.816 2.856 2.816H2O8.444 6.847 6.384 6.086 8.413 6.759 6.274 5.986 8.002 6.465 6.026 5.480Ar 0.8872 0.9026 0.9072 0.9108 0.8874 0.9030 0.9077 0.9112 0.8893 0.9044 0.9089 0.9137ControlledEmissionRateCalculationsTempRankine 831.97 839.47 858.97 873.67 813.37 822.07 827.47 830.97 802.07 803.67 804.97 843.27%H2O8.4% 6.8% 6.4% 6.1% 8.4% 6.8% 6.3% 6.0% 8.0% 6.5% 6.0% 5.5%%O2dry15.3% 15.3% 15.3% 15.1% 15.3% 15.4% 15.4% 15.2% 15.7% 15.7% 15.6% 15.7%Exhaustflow,acfm 304500 349980 387480 409500 243000 283140 310680 320640 220680 238920 251580 274020Exhaustflow,dscfm 171378 198620 215978 225126 139940 164243 179974 185530 129455 142212 150208 157083NOX,ppmvd@15%O262.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5NOX,ppmvd,actualO22.39 2.38 2.39 2.45 2.38 2.34 2.34 2.41 2.19 2.21 2.24 2.19NOX,lb/hr2.92 3.38 3.69 3.94 2.38 2.75 3.01 3.19 2.02 2.25 2.40 2.45CO,ppmvd@15%O2610.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0 10.0CO,ppmvd,actualO29.56 9.53 9.57 9.81 9.52 9.37 9.37 9.64 8.77 8.86 8.95 8.76CO,lb/hr 7.12 8.22 8.98 9.60 5.78 6.69 7.32 7.77 4.93 5.47 5.84 5.98VOC,ppmvd@15%O267.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5VOC,ppmvd,actualO27.17 7.15 7.18 7.36 7.14 7.03 7.02 7.23 6.57 6.64 6.71 6.57VOC,lb/hr 3.05 3.52 3.85 4.11 2.48 2.87 3.14 3.33 2.11 2.35 2.50 2.56TotalPM,lb/hr 1.79 2.12 2.32 2.48 1.49 1.73 1.89 2.00 1.27 1.41 1.51 1.54TotalPM,lb/MMBtu 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057 0.0057TotalPM,gr/dscf 0.0012 0.0012 0.0013 0.0013 0.0012 0.0012 0.0012 0.0013 0.0011 0.0012 0.0012 0.0011CO2e,lb/hr36,741 43,563 47,565 50,841 30,633 35,441 38,836 41,152 26,152 29,007 30,937 31,698CO2e,lb/MWhgross873.3 843.6 773.6 743.7 928.1 882.7 877.7 874.0 1074.1 993.7 969.8 875.91)DatafromGTProModel2)Manufacturerguarantee3)ProposedPM10/PM2.5BACTlimit;PMconservativelyassumedequaltoPM10/PM2.54)Emissionsbasedonsulfurcontentof0.5gr/100scfasspecifiedbynaturalgassupplycontractand40CFR72.2definitionofpipelinenaturalgas:(0.5grS/100scf)/(1020Btu/scf)*(10^6Btu/MMBtu)/(7000gr/lb)*(64lbSO2/lbmol)/(32lbS/lbmol)=0.0014lb/MMBtu5)Calculation6)DesignbasisspecificationprovidedtoSCRand/orcatalyticoxidizervendor

# Attachment 1: Table 7

GE LM6000 Performance Test Data and Statistical Analysis

PM PM FH PM BH Front Back Reported PM

Facilit y Date Source lb/hr lb/hr lb/hr % % lb/MMBtu Creed Energy Center 1/31/2003 S-1 2.18 1.05 1.13 48.2 51.8 0.0047 Creed Energy Center 7/6/2006 S-1 1.363 0.553 0.81 40.6 59.4 0.0028 Creed Energy Center 5/7/2009 S-1 0.6746 0.1948 0.4798 28.9 71.1 0.0012 Lambie Energy Center 1/16/2003 S-1 1.9 0.56 1.34 29.5 70.5 0.0042 Lambie Energy Center 5/5/2006 S-1 2.104 1.429 0.674 67.9 32.0 0.0039 Lambie Energy Center 5/11/2009 S-1 0.83 0.3488 0.4807 42.0 57.9 0.0016 Los Esteros Energy 7/26-7/27/ 0 S-1 2.266 1.016 1.25 44.8 55.2 0.0042 Los Esteros Energy 7/26-7/27/ 0 S-2 0.896 0.363 0.533 40.5 59.5 0.0016 Los Esteros Energy 7/28/2005 S-3 1.44 0.578 0.862 40.1 59.9 0.0025 Los Esteros Energy 7/27-7/29/ 0 S-4 0.915 0.326 0.589 35.6 64.4 0.0016 Los Esteros Energy 9/8/2006 S-1 0.775 0.307 0.468 39.6 60.4 0.0015 Los Esteros Energy 9/8/2006 S-2 0.871 0.331 0.54 38.0 62.0 0.0015 Los Esteros Energy 9/6-9/7/06 S-3 1.805 0.398 1.407 22.0 78.0 0.0033 Los Esteros Energy 9/6-9/7/06 S-4 0.904 0.318 0.586 35.2 64.8 0.0017 Los Esteros Energy 7/25-7/26/ 0 S-1 1.672 0.967 0.705 57.8 42.2 0.0030 Los Esteros Energy 7/25-7/26/ 0 S-2 1.429 0.541 0.888 37.9 62.1 0.0025 Los Esteros Energy 7/24-7/25/ 0 S-3 1.456 0.666 0.79 45.7 54.3 0.0025 Los Esteros Energy 7/24-7/25/ 0 S-4 1.646 0.973 0.673 59.1 40.9 0.0027 Los Esteros Energy 5/29-5/30/ 0 S-1 1.4145 0.6957 0.7189 49.2 50.8 0.0026 Los Esteros Energy 5/28-5/29/ 0 S-2 0.9769 0.3191 0.6578 32.7 67.3 0.0018 Los Esteros Energy 5/28-5/29/ 0 S-3 1.49 0.4393 1.0555 29.5 70.8 0.0027 Los Esteros Energy 5/29-5/30/ 0 S-4 2.21 1.345 0.8629 60.9 39.0 0.0041 Los Esteros Energy 5/13/2009 S-1 1.16 0.4811 0.68 41.5 58.6 0.0020 Los Esteros Energy 5/14-5/15/ 0 S-2 0.969 0.4702 0.4983 48.5 51.4 0.0018 Los Esteros Energy 5/14-5/15/ 0 S-3 0.864 0.4082 0.4561 47.2 52.8 0.0016 Los Esteros Energy 5/13-5/14/ 0 S-4 1.04 0.3226 0.7186 31.0 69.1 0.0019

Riverview 5/8/2009 S-1 1.469 0.789 0.68 53.7 46.3 0.0030

Wolfskill 6/2/2004 S-1 2.15 1.3 0.85 60.5 39.5 0.0047

Wolfskill 7/5/2006 S-1 1.9 0.582 1.319 30.6 69.4 0.0034

Wolfskill 5/4/2009 S-1 0.81 0.29 0.52 35.8 64.2 0.0010 Gilroy Energy Center 7/19/2005 S-3 1.9 0.0029 Gilroy Energy Center 7/21/2005 S-4 1.7 0.0022 Gilroy Energy Center 7/21/2005 S-5 1 0.0016 Gilroy Energy Center 5/23/2006 S-3 1.69 0.0020 Gilroy Energy Center 5/24/2006 S-4 0.95 0.0010 Gilroy Energy Center 5/22/2006 S-5 1.41 0.0020 Gilroy Energy Center 5/23/2007 S-3 1.6 0.6132 0.9856 38.3 61.6 0.0030 Gilroy Energy Center 5/24/2007 S-4 1.25 0.5443 0.7016 43.5 56.1 0.0019 Gilroy Energy Center 5/25/2007 S-5 1.6 0.6769 0.9193 42.3 57.5 0.0027

Goosehaven 1/23/2003 S-1 2.44 0.0047

Goosehaven 7/6/2006 S-1 2.438 1.327 1.112 54.4 45.6 0.0040

Goosehaven 5/6/2009 S-1 0.9716 0.1481 0.8235 15.2 84.8 0.0017 Average: 1.44 0.0026

Standard Deviation: 0.50 0.0010 95% Upper Control Limit plus 20% margin: 2.93 0.0056 99.7% Upper Control Limit: 2.94 0.0057 Source: Bay Area Air Quality Management District. “Final Determination of Compliance – Mariposa Energy Project.”
November, 2010. See Table 26.GI-07Facility Emissions SummaryAir Quality Permit ProgramDoc Type: Permit Application1) AQ FacilityID No.:037000111b) AQ File No.:106A2) FacilityName:Flint Hills Resources Pine Bend Refinery3a)3b)3c)CAS #:NA3c)CAS #:NA3c)CAS #:NA3d)Pollutant Name:PM3d)Pollutant Name:PM103d)Pollutant Name:PM2.5Emission Emission 3e)Potential 3f)Actual 3e)Potential 3f)Actual 3e)Potential 3f)ActualSource Source Unrestricted Limited Unrestricted Limited Unrestricted LimitedType ID No. lb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrEU EU CTG2.5 10.8 10.8 0.0 2.5 10.8 10.8 0.0 2.5 10.8 10.8 0.0EU EU HRSGDB 1.4 6.0 6.0 0.0 1.4 6.0 6.0 0.0 1.4 6.0 6.0 0.0FS FS CHP 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.04)PotentialActual PotentialActual PotentialActualUnrestricted Limited YrUnrestricted Limited YrUnrestricted Limited YrTotal Facility:16.8 16.8 0.0 16.8 16.8 0.0 16.8 16.8 0.03a)3b)3c)CAS #:630-08-03c)CAS #:NA3c)CAS #:NA3d) Pollutant Name:CO3d) Pollutant Name:NOX3d) Pollutant Name:SO2Emission Emission 3e)Potential 3f)Actual 3e)Potential 3f)Actual 3e)Potential 3f)ActualSource Source Unrestricted Limited Unrestricted Limited Unrestricted LimitedType ID No. lb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrEU EU CTG41.9 183.4 37.9 0.0 23.7 103.6 15.7 0.0 0.61 2.7 2.7 0.0EU EU HRSGDB 19.1 83.8 29.0 0.0 19.1 83.8 12.0 0.0 0.33 1.5 1.5 0.0FS FS CHP 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.00 0.0 0.0 0.04)PotentialActual PotentialActual PotentialActualUnrestricted Limited YrUnrestricted Limited YrUnrestricted Limited YrTotal Facility:267.2 66.9 0.0 187.4 27.7 0.0 4.1 4.1 0.0File:H:\Worksheetinole_mainSheet:GI07Page1of23a)3b)3c)CAS #:NA3c)CAS #:NA3c)CAS #:NA3d) Pollutant Name:CO23d) Pollutant Name:CH43d) Pollutant Name:N2OEmission Emission 3e)Potential 3f)Actual 3e)Potential 3f)Actual 3e)Potential 3f)ActualSource Source Unrestricted Limited Unrestricted Limited Unrestricted LimitedType ID No. lb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrEU EU CTG50,788 222,453 222,453 0.96 4.2 4.2 0.0 0.10 0.42 0.4 0.0EU EU HRSGDB 27,948 122,413 122,413 0.53 2.3 2.3 0.0 0.05 0.23 0.2 0.0FS FS CHP 0.00 0.0 0.0 0.0 0.00 0.0 0.0 0.0 0.00 0.0 0.0 0.04)PotentialActual PotentialActual PotentialActualUnrestricted Limited YrUnrestricted Limited YrUnrestricted Limited YrTotal Facility:344,865 344,865 0.0 6.5 6.5 0.0 0.7 0.7 0.03a)3b)3c)CAS #:NA3c)CAS #:NA3c)CAS #:NA3d) Pollutant Name:GHG (CO2e)3d) Pollutant Name:VOC3d) Pollutant Name:Total HAP [1]Emission Emission 3e)Potential 3f)Actual 3e)Potential 3f)Actual 3e)Potential 3f)ActualSource Source Unrestricted Limited Unrestricted Limited Unrestricted LimitedType ID No. lb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrlb/hrtons/yrtons/yrtons/yrEU EU CTG222,682 222,682 0.0 8.25 36.1 17.7 0.0 1.12 4.9 4.9 0.0EU EU HRSGDB 122,539 122,539 0.0 4.78 20.9 10.3 0.0 0.44 1.9 1.9 0.0FS FS CHP 39.9 39.9 0.0 0.00 0.0 0.0 0.0 0.00 0.0 0.0 0.04)PotentialActual PotentialActual PotentialActualUnrestricted Limited YrUnrestricted Limited YrUnrestricted Limited YrTotal Facility:345,262 345,262 0.0 57.1 28.0 0.0 6.8 6.8 0.05)Application is beingsubmitted on a compact disc(CD), and the editable calculation spreadsheet(s)are included on the CD.FHR will be submittingthe application,includingspreadsheets,electronically(via e-mail or CD)Application is beingsubmitted onpaper only, so editable calculation spreadsheet(s)will be e-mailed to the MPCA upon request or are included on an enclosed CD.Notes:[1]Please refer to EC-08 and EC-13 forms for individual HAP calculations.File:H:\Worksheetinole_mainSheet:GI07Page2of2

# EC-08

Facility Emissions Summary

Air Quality Permit Program



## Instructions on Page 2

1a) AQ Facility ID No.: 

### 03700011 1b) AQ File No.: 

### 106A

2) Facility Name: 

### Flint Hills Resources Pine Bend Refinery

Items 3a) through f) see EC forms by unit

4) Facility Summary 

### Emissions reflect worst case of primary or backup fuel for units with duel fuels.

Maximum Limited Actual

Uncontrolled Controlled Controlled

Emissions Emissions Emissions

(tons/yr) (tons/yr) (tons/yr)



### Criteria 16.8 16.8 NA

Criteria 16.8 16.8 NA

Criteria 16.8 16.8 NA

Criteria 4.1 4.1 NA

Criteria 187.4 27.7 NA

Criteria 57.1 28.0 NA

Criteria 267.2 66.9 NA

Criteria 1.4E-03 1.4E-03 NA

GHG 3.4E+05 3.4E+05 NA

GHG 1.6E+02 1.6E+02 NA

GHG 1.9E+02 1.9E+02 NA

GHG NA NA NA

GHG NA NA NA

GHG NA NA NA

GHG 3.5E+05 3.5E+05 NA

HAP 

### 8.2E-04 8.2E-04 NA

HAP 

### 3.3E-01 3.3E-01 NA

HAP 

### 6.9E-03 6.9E-03 NA

HAP 

### 8.4E-03 8.4E-03 NA

HAP 

### 3.5E-03 3.5E-03 NA

HAP 

### 6.1E-02 6.1E-02 NA

HAP 

### 7.6E-01 7.6E-01 NA

HAP 

### 5.2E+00 5.2E+00 NA

HAP 

### 3.1E-03 3.1E-03 NA

HAP 

### 4.3E-03 4.3E-03 NA

HAP 

### 5.5E-02 5.5E-02 NA

HAP 

### 2.5E-01 2.5E-01 NA

HAP 

### 1.2E-01 1.2E-01 NA

HAP 

### 5.8E-04 5.8E-04 NA

HAP 

### 3.5E-05 3.5E-05 NA

HAP 

### 3.2E-03 3.2E-03 NA

HAP 

### 4.0E-03 4.0E-03 NA

HAP 

### 2.4E-04 2.4E-04 NA

HAP 

### 1.1E-03 1.1E-03 NA

HAP 

### 7.5E-04 7.5E-04 NA CO 2 Doc Type: Permit Application



### Pollutant
Category Pollutant ID

PM

PM 10


### PM 2.5 

### SO 2 

### NO

x 

### VOC

CO

Lead

Ethylbenzene (100-41-4) CH 4


### N 2 

### O

HFCs

PFCs

SF 6 

### Total GHG (CO 2 

### e)

1,3 Butadiene (106-99-0)
Acetaldehyde (75-07-0)
Acrolein (107-02-8)
Benzene (71-43-2)
Dichlorobenzene (25321-22-6)

Cobalt (7440-48-4) Formaldehyde (50-00-0)
Hexane (110-54-3)
Naphthalene (91-20-3)
Polycyclic organic matter (POM) (N/A)
Propylene oxide (75-56-9)
Toluene (108-88-3)
Xylenes (1330-20-7)
Arsenic (7440-38-2)
Beryllium (7440-41-7)
Cadmium (7440-43-9)
Chromium (7440-47-3)

Manganese (7439-96-5)
Mercury (7439-97-6)

Form aq-f1-gi07 (version 2/29/2012) 

## Page 1

# EC-08

Facility Emissions Summary

Air Quality Permit Program



## Instructions on Page 2

1a) AQ Facility ID No.: 

### 03700011 1b) AQ File No.: 

### 106A

2) Facility Name: 

### Flint Hills Resources Pine Bend Refinery

Items 3a) through f) see EC forms by unit

4) Facility Summary 

### Emissions reflect worst case of primary or backup fuel for units with duel fuels.

Maximum Limited Actual

Uncontrolled Controlled Controlled

Emissions Emissions Emissions

(tons/yr) (tons/yr) (tons/yr) Doc Type: Permit Application



### Pollutant
Category Pollutant ID

HAP 

### 6.1E-03 6.1E-03 NA

HAP 

### 6.9E-05 6.9E-05 NA

HAP 

### 6.8 6.8 NA Nickel (7440-02-0)
Selenium (7782-49-2)

Total HAP

Form aq-f1-gi07 (version 2/29/2012) 

## Page 2EC-03Internal Combustion Engine (Single Fuel) CalculationsAir Quality Permit ProgramInstructions on Page 41a)AQD Facility ID No.:037000111b)AQ File No.:106A2)Facility Name:Flint Hills Resources Pine Bend RefineryFill out Part 1 of this form for each fuel burned in each engine, orattach sheets with equivalent information. Also complete and attach Form EC-13C for Hazardous Air Pollutants (HAP), and Form EC-17for Greenhouse Gas (GHG) emissions.Fill out Part 2 of this form only if you are installing a generator to be used for other than emergencies.Part 13)Emission Unit Identification Number:EU-CTG: CTG (New MPCA EU)4)Stack/Vent Designation Number:SV-CHP (New MPCA SV)5)Control Equipment Identification Number:CE-CHPSCR, CE-CHPCATOX (New MPCA CEs)6)Engine type:7)Engine is used for:(If you check this box, you must complete Part 2)8)Rated heat input:434.5MMBtu/hr (million British thermal units/hour)9)Rated mechanical output:57,530HP @3,600RPM10)Fuel type:Pipeline natural gas@< 0.5 gr/100 cf% Sulfur11)Fuel consumption rate:425980 ft3/hr(gallons/hour or cubic feet/hour)12)Calculations Summary:12a) 12b) 12c) 12d) 12e) 12f) 12g) 12h)Maximum Pollution Maximum Limited ActualPollutant Emission Emission Uncontrolled Control Controlled Controlled ControlledFactor Rate Emissions Efficiency Emissions Emissions Emissions(lbs/unit)(lbs/hr) (tons/yr)(%)5(tons/yr)6(tons/yr)6(tons/yr)PM12.5 2.5 10.8 0.0% 10.8 10.8 NAPM1012.5 2.5 10.8 0.0% 10.8 10.8 NAPM2.512.5 2.5 10.8 0.0% 10.8 10.8 NASO220.0014 0.61 2.7 0.0% 2.7 2.7 NANOx323.7 23.7 103.6 84.9% 15.7 15.7 NAVOC38.2 8.2 36.1 50.9% 17.7 17.7 NACO341.9 41.9 183.4 79.3% 37.9 37.9 NALead44.9E-07 2.1E-04 9.3E-04 0.0% 9.3E-04 9.3E-04 NA1Emission factors for PM10/PM2.5are based on proposed BACT limit.All particulate matter is conservatively assume to befilterable for the purposesof estimating PM emissions.2Emissions based on sulfur content of 0.5 gr/100 scf as specified by 40 CFR 72.2 definition of pipeline natural gas:(0.5 gr S / 100 scf) / (1020 Btu/scf) * (10^6 Btu/MMBtu) / (7000 gr / lb) * (64 lb SO2/lbmol) / (32 lb S/lbmol) = 0.0014 lb/MMBtu3Uncontrolled emission factors for NOX, CO, and VOC are based on turbine manufacturer guarantees (for normal operation) and turbine manufacturer estimates (for startup/shutdown);Controlled emission rates are derived from design basis specifications provided to SCR and catalytic oxidation vendors.4Emission factors from AP-42, Section 1.4 "Natural Gas Combustion" (7/98) and the AP-42 heat value of 1,020 Btu/scf.5Control efficiencies are derived from the uncontrolled and controlled emission rates described above. They are not proposed permit limits but provided for informational purposes only.6Emission rates presented for informational purposes only. Emissions from the CTG are commingled with those from the duct burner prior to control and only the combined, controlled emissions will be monitored.13)Operating Limitations, if applicable:Not ApplicableDoc Type: Permit ApplicationEmissions factor unitsand sourcelb/hr, specification to vendorlb/MMBtu, AP-42lb/hr, BACT limitlb/hr, BACT limitlb/hr, BACT limitlb/MMBtu, definition of pipeline nat gaslb/hr, specification to vendorlb/hr, specification to vendorReciprocatingTurbineOther:Non-Emergency useEmergency use onlyaq-f1-ec08 • 10/22/10Page 1PERMIT APPLICATION FORMEC-13CHAZARDOUS AIR POLLUTANTSCALCULATION FORM (FUEL COMBUSTION HAPS)5/26/2006- Instructions begin on Page 6.1)AQ Facility ID No.:037000112)Facility Name:Flint Hills Resources Pine Bend Refinery3)Emission Unit Identification No.:EU-CTG: CTG (New MPCA EU)4)Stack/Vent Designation No.:SV-CHP (New MPCA SV)5)Maximum Rated Boiler Capacity:434.5million BTU/hr6)Control Equipment:CE-CHPSCR, CE-CHPCATOX (New MPCA CEs)7)Fuel Parameters7a) 7b) 7c) 7d) 7e)Fuel Type % Sulfur % Ash Heat Value Units Maximum Fuel Consumption Rate UnitsNatural Gas < 0.5 gr/100 scf (1.4 lb/mmscf) negligible 1,020.0 Btu/cf 425,980 cf/hrNANA- Duplicate this form as necessary, or attach sheets with equivalent information.aq-f1-ec13c.docPage 1When calculating Potential Emissions, use items 8a, 8b, 8d, 8e, 8g, 8h, and 8i (if a limit is proposed in item 12).When calculating Actual Emissions, use items 8a, 8b, 8c, 8f, 8g, and 8j.8)Calculations Summary - Primary Fuel : Natural Gas8b 8c 8d 8e 8f 8g 8h 8i 8jEmission Actual Emission Maximum Actual Pollution Maximum Limited ActualFactor1Annual Fuel Rate Uncontrolled Uncontrolled Control Controlled Controlled ControlledUse Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/MMBtu) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)4.3E-07 NA 1.9E-04 8.2E-04 NA 0.0 8.2E-04 8.2E-04 NA1.8E-04 NA 7.6E-02 3.3E-01 NA 0.0 3.3E-01 3.3E-01 NA3.6E-06 NA 1.6E-03 6.9E-03 NA 0.0 6.9E-03 6.9E-03 NA3.3E-06 NA 1.4E-03 6.2E-03 NA 0.0 6.2E-03 6.2E-03 NA1.2E-06 NA 5.1E-04 2.2E-03 NA 0.0 2.2E-03 2.2E-03 NA3.2E-05 NA 1.4E-02 6.1E-02 NA 0.0 6.1E-02 6.1E-02 NA3.6E-04 NA 1.6E-01 6.9E-01 NA 0.0 6.9E-01 6.9E-01 NA1.8E-03 NA 7.7E-01 3.4E+00 NA 0.0 3.4E+00 3.4E+00 NA1.3E-06 NA 5.6E-04 2.5E-03 NA 0.0 2.5E-03 2.5E-03 NA2.2E-06 NA 9.6E-04 4.2E-03 NA 0.0 4.2E-03 4.2E-03 NA2.9E-05 NA 1.3E-02 5.5E-02 NA 0.0 5.5E-02 5.5E-02 NA1.3E-04 NA 5.6E-02 2.5E-01 NA 0.0 2.5E-01 2.5E-01 NA6.4E-05 NA 2.8E-02 1.2E-01 NA 0.0 1.2E-01 1.2E-01 NA2.0E-07 NA 8.5E-05 3.7E-04 NA 0.0 3.7E-04 3.7E-04 NA1.2E-08 NA 5.1E-06 2.2E-05 NA 0.0 2.2E-05 2.2E-05 NA1.1E-06 NA 4.7E-04 2.1E-03 NA 0.0 2.1E-03 2.1E-03 NA1.4E-06 NA 6.0E-04 2.6E-03 NA 0.0 2.6E-03 2.6E-03 NA8.2E-08 NA 3.6E-05 1.6E-04 NA 0.0 1.6E-04 1.6E-04 NA3.7E-07 NA 1.6E-04 7.1E-04 NA 0.0 7.1E-04 7.1E-04 NA2.5E-07 NA 1.1E-04 4.9E-04 NA 0.0 4.9E-04 4.9E-04 NA2.1E-06 NA 8.9E-04 3.9E-03 NA 0.0 3.9E-03 3.9E-03 NA2.4E-08 NA 1.0E-05 4.5E-05 NA 0.0 4.5E-05 4.5E-05 NA1Emission factors from AP-42 Section 3.1 Background Document, Table 3.4-1 with CO catalyst and AP-42, Section 1.4 "Natural GasCombustion" (7/98) and the AP-42 heat value of 1,020 Btu/scf.2Naphthalene is included in the Polycyclic Organic Matter (POM) emissions and is not double-counted in the total HAPs.3Total POM emission factor is equal to the sum of the individual POM compounds.Ethylbenzene (100-41-4)8aHAP Name(CAS)1,3 Butadiene (106-99-0)Acetaldehyde (75-07-0)Acrolein (107-02-8)Benzene (71-43-2)Dichlorobenzene (25321-22-6)Cobalt (7440-48-4)Formaldehyde (50-00-0)Hexane (110-54-3)Naphthalene (91-20-3) [2]Polycyclic organic matter (POM) [3]Propylene oxide (75-56-9)Toluene (108-88-3)Xylenes (1330-20-7)Arsenic (7440-38-2)Beryllium (7440-41-7)Cadmium (7440-43-9)Chromium (7440-47-3)Manganese (7439-96-5)Mercury (7439-97-6)Nickel (7440-02-0)Selenium (7782-49-2)aq-f1-ec13c.docPage 2When calculating Potential Emissions, use items 9a, 9b, 9d, 9e, 9g, 9h, and 9i (if a limit is proposed in item 12).When calculating Actual Emissions, use items 9a, 9b, 9c, 9f, 9g, and 9j.9)Calculations Summary - Secondary Fuel : N/A9b 9c 9d 9e 9f 9g 9h 9i 9jEmission Actual Emission Maximum Actual Pollution Maximum Limited ActualFactor Annual Fuel Rate Uncontrolled Uncontrolled Control Controlled Controlled ControlledUse Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/MMBtu) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)NA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NA9aHAP Name(CAS)aq-f1-ec13c.docPage 311)Worse-Case Potential-to-Emit Summary: (Ignore this item if filling out this form for a Registration Permit Option D)11a) 11b) 11a) 11b)Before After Before AfterOperating Operating Operating OperatingLimits Limits Limits Limits(ton/yr) (ton/yr) (ton/yr) (ton/yr)8.2E-04 8.2E-04 2.5E-01 2.5E-013.3E-01 3.3E-01 1.2E-01 1.2E-016.9E-03 6.9E-03 3.7E-04 3.7E-046.2E-03 6.2E-03 2.2E-05 2.2E-052.2E-03 2.2E-03 2.1E-03 2.1E-036.1E-02 6.1E-02 2.6E-03 2.6E-036.9E-01 6.9E-01 1.6E-04 1.6E-043.4E+00 3.4E+00 7.1E-04 7.1E-042.5E-03 2.5E-03 4.9E-04 4.9E-044.2E-03 4.2E-03 3.9E-03 3.9E-035.5E-02 5.5E-02 4.5E-05 4.5E-05Totals4.9 ton/yr1Nahpthalene is included in the Polycyclic Organic Matter (POM) emissions and is not double-counted in the total HAPs.12)Operating Limitations, if applicable: (Ignore this item if filling out this form for a Registration Permit Option D):Not ApplicableHAP Name (CAS) HAP Name (CAS)1,3 Butadiene (106-99-0) Toluene (108-88-3)Acetaldehyde (75-07-0) Xylenes (1330-20-7)Acrolein (107-02-8) Arsenic (7440-38-2)Benzene (71-43-2) Beryllium (7440-41-7)Dichlorobenzene (25321-22-6) Cadmium (7440-43-9)Ethylbenzene (100-41-4) Chromium (7440-47-3)Formaldehyde (50-00-0) Cobalt (7440-48-4)Hexane (110-54-3) Manganese (7439-96-5)Naphthalene (91-20-3) [2] Mercury (7439-97-6)Polycyclic organic matter (POM) [3] Nickel (7440-02-0)Propylene oxide (75-56-9) Selenium (7782-49-2)aq-f1-ec13c.docPage 4EC‐17GreenhouseGasEmissionsAirQualityPermitProgramDocType:PermitApplicationInstructionsonPage2.7a) 7b) 7c) 7e)EmissionFactorPollutionControlEfficiency(lb/unit) (lb/hr) (tpy)CO2e(tpy)(%) (lb/hr) (tpy)CO2e(tpy)(lb/hr) (tpy)CO2e(tpy)(tpy)CO2e(tpy)CO2111.2E+02 5.1E+04 2.2E+05 2.2E+05 0.0E+00 5.1E+04 2.2E+05 2.2E+05 5.1E+04 2.2E+05 2.2E+05 NA NACH42252.2E-03 9.6E-01 4.2E+00 1.0E+02 0.0E+00 9.6E-01 4.2E+00 1.0E+02 9.6E-01 4.2E+00 1.0E+02 NA NAN2O32982.2E-04 9.6E-02 4.2E-01 1.3E+02 0.0E+00 9.6E-02 4.2E-01 1.3E+02 9.6E-02 4.2E-01 1.3E+02 NA NAHFCsNA NA NA NA NA NA NA NA NA NA NA NAPFCsNA NA NA NA NA NA NA NA NA NA NA NASF623,900NA NA NA NA NA NA NA NA NA NA NA NA NATotalGHG(CO2e)2.2E+05 2.2E+05 2.2E+05 NA1Emission Factor = 53.02 kg CO2/MMBtu per Table C-1 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg2Emission Factor = 0.001 kg CH4/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg3Emission Factor = 0.0001 kg N2O/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg2)Facility Name:Flint Hills Resources Pine Bend RefineryUse this form to summarize the potential and actual greenhouse gas (GHG) emissions for each operation contributing to GHG emissions. Continue to use the other emission forms (EC01 though EC-16) as applicable for other regulated air pollutants. Follow the guidance on calculation of greenhouse gas (GHG)emissions. Attach a separate spreadsheet showing allcalculations.1a)AQ Facility ID No.:037000111b)AQ File No.:106A3)Emisson unit ID number:EU-CTG: CTG (New MPCA EU)4)Stack/Vent designation number(s):SV-CHP (New MPCA SV)5)Control equipment number(s):CE-CHPSCR and CE-CHPCATOX (New MPCA CEs)ActualControlledEmissionRate6)Operating Limitations, if applicable:7)Greenhouse Gas Emissions Summary. Use this table to document GHG emissions from the unit or operation listed above. You must provide mass emissions of each pollutant, aswell as carbon dioxide equivalents (CO2e). For hydroflourocarbons (HFCs) and perfluorocarbons (PFCs), you will have to calculate emissions of individual compounds onthe seperatespreadsheet and report the total HFCs and PFCs in the table below. Instructions are provided starting on page 2. Please report all numbers using three (3) scientific notation ifnecessary (for example, report 379,355 tons as 3.79E5").7d) 7f) 7g) 7h)GHGPollutantGWPUncontrolledEmissionRate ControlledEmissionRateLimitedandControlledEmissionRateaq-f1-ec17 • 7/30/10Page 1EC-08External Combustion (Ovens, Dryers, Furnaces, etc.) Calculation FormAir Quality Permit ProgramInstructions on Page 4Use this form to calculate combustion emissions for each furnace, over, or dryer, or attach sheets with equivalent information.Use Form EC-13C to calculate emissions of hazardous air pollutants (HAP) from external combustion of fuels.Instructions begin on Page 4.1a)AQD Facility ID No.:037000111b)AQ File No.:106A2)Facility Name:Flint Hills Resources Pine Bend Refinery3)Emission Unit Identification No.:EU-HRSGDB: HRSG Duct Burner (New MPCA EU)4)Stack/Vent Designation No.:SV-CHP (New MPCA SV)5)Maximum Rated Boiler Capacity:239.1million BTU/hr6)Control Equipment:CE-CHPSCR and CE-CHPCATOX (New MPCA CEs)7)Fuel Parameters:7b) 7c) 7d) 7e)Fuel Type %Sulfur % Ash Heat Value Units Fuel Consumption Rate UnitsNatural Gas0.5 gr/100 scf (1.4 lb/mmscf) negligible 1,020.0 Btu/cf 234,412 cf/hrNANANADoc Type: Permit Application7a)aq-f1-ec08 • 10/22/10Page 18)Calculations Summary – Primary Fuel: Natural GasWhen calculating Potential Emissions, use items 8a, 8b, 8d, 8e, 8g-i. When calculating Actual Emissions, use items 8a, 8b, 8c,8f, 8g, and 8j.8a 8b 8c 8d 8e 8f 8g 8h 8i 8jActual Maximum Actual Pollution Maximum Limited ActualPollutant Emission Annual Emission Uncontrolled Uncontrolled Control Controlled Controlled ControlledFactor Fuel Usage Rate Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/MMBtu) (MMBtu/yr)(lbs/hr) (tons/yr) (tons/yr)(%)5(tons/yr)6(tons/yr)6(tons/yr)PM10.0057 NA 1.4 6.0 NA 0.0% 6.0 6.0 NAPM1010.0057 NA 1.4 6.0 NA 0.0% 6.0 6.0 NAPM2.510.0057 NA 1.4 6.0 NA 0.0% 6.0 6.0 NASO220.0014 NA 0.3 1.5 NA 0.0% 1.5 1.5 NANOx30.08 NA 19.1 83.8 NA 85.7% 12.0 12.0 NAVOC30.02 NA 4.8 20.9 NA 50.9% 10.3 10.3 NACO30.08 NA 19.1 83.8 NA 65.4% 29.0 29.0 NALead44.9E-07 NA 1.2E-04 5.1E-04 NA 0.0% 0.0 0.0 NA1Emission factors for PM10/PM2.5are based on proposed BACT limit.All particulate matter is conservatively assume to be filterable for the purposes of estimating PM emissions.2Emissions based on sulfur content of 0.5 gr/100 scf as specified by natural gas supply contract and 40 CFR 72.2 definition of pipeline natural gas:(0.5 gr S / 100 scf) / (1020 Btu/scf) * (10^6 Btu/MMBtu) / (7000 gr / lb) * (64 lb SO2/lbmol) / (32 lb S/lbmol) = 0.0014 lb/MMBtu3Uncontrolled emission factors for NOX, CO, and VOC are based on typical duct burner manufacturer guarantees;Controlled emission rates are derived from design basis specifications provided to SCR and catalytic oxidation vendors.4Emission factors from AP-42, Section 1.4 "Natural Gas Combustion" (7/98) and the AP-42 heat value of 1,020 Btu/scf.5Control efficiencies are derived from the uncontrolled and controlled emission rates described above. They are not proposed permit limits but provided for informational purposes only.6Emission rates presented for informational purposes only. Emissions from the CTG are commingled with those from the duct burner prior to control and only the combined, controlled emissions will be monitored.9)Calculations Summary – Back-up Fuel.When calculating Potential Emissions, use items 9a, 9b, 9d, 9e, 9g-i. When calculating Actual Emissions, use items 9a, 9b, 9c,9f, 9g, and 9j.9a 9b 9c 9d 9e 9f 9g 9h 9i 9jActual Maximum Actual Pollution Maximum Limited ActualPollutant Emission Annual Emission Uncontrolled Uncontrolled Control Controlled Controlled ControlledFactor Fuel Usage Rate Emissions Emissions Efficiency Emissions Emissions Emissions(lb/MMBtu) (MMBtu)(lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)PM1PM101PM2.51SO21NOx2VOC1CO3Lead1aq-f1-ec08 • 10/22/10Page 210)Calculations Summary – Back-up Fuel.When calculating Potential Emissions, use items 10a, 10b, 10d, 10e, 10g-i. When calculating Actual Emissions, use items 10a, 10b, 10c, 10f, 10g, and 10j.10a 10b 10c 10d 10e 10f 10g 10h 10i 10jActual Maximum Actual Pollution Maximum Limited ActualPollutant Emission Annual Emission Uncontrolled Uncontrolled Control Controlled Controlled ControlledFactor Fuel Usage Rate Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/cf) (cf/yr)(lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)PMPM10PM2.5SO2NOxVOCCOLead11)Worse-Case Potential-to-Emit Summary: (Ignore this item if filling out this form for a Registration Permit Option D)11a 11b 11c 11a 11b 11cBefore AfterBefore AfterPollutant Operating Operating Pollutant Operating OperatingLimits LimitsLimits Limits(tons/yr) (tons/yr)(tons/yr) (tons/yr)PM6.0 NANOx12.0 12.00PM106.0 NAVOC10.3 NAPM2.56.0 NACO29.0 NASOx1.5 NALead5.1E-04 NA12)Operating Limitations, if applicable: (Ignore this item if filling out this form for a Registration Permit Option D):aq-f1-ec08 • 10/22/10Page 3PERMIT APPLICATION FORMEC-13CHAZARDOUS AIR POLLUTANTSCALCULATION FORM (FUEL COMBUSTION HAPS)5/26/2006- Instructions begin on Page 6.1)AQ Facility ID No.:037000112)Facility Name:Flint Hills Resources Pine Bend Refinery3)Emission Unit Identification No.:EU-HRSGDB: HRSG Duct Burner (New MPCA EU)4)Stack/Vent Designation No.:SV-CHP (New MPCA SV)5)Maximum Rated Boiler Capacity:239.1million BTU/hr6)Control Equipment:CE-CHPSCR and CE-CHPCATOX (New MPCA CEs)7)Fuel Parameters7a) 7b) 7c) 7d) 7e)Fuel Type % Sulfur % Ash Heat Value Units Maximum Fuel Consumption Rate UnitsNatural Gas < 0.5 gr/100 scf (1.4 lb/mmscf) negligible 1,020.0 Btu/cf 234,412 cf/hrNANA- Duplicate this form as necessary, or attach sheets with equivalent information.aq-f1-ec13c.docPage 1When calculating Potential Emissions, use items 8a, 8b, 8d, 8e, 8g, 8h, and 8i (if a limit is proposed in item 12).When calculating Actual Emissions, use items 8a, 8b, 8c, 8f, 8g, and 8j.8)Calculations Summary - Primary Fuel : Natural Gas8b 8c 8d 8e 8f 8g 8h 8i 8jEmission Actual Emission Maximum Actual Pollution Maximum Limited ActualFactor1Annual Fuel Rate Uncontrolled Uncontrolled Control Controlled Controlled ControlledUse Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/MMBtu) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)2.1E-06 NA 4.9E-04 2.2E-03 NA 0.0 2.2E-03 2.2E-03 NA1.2E-06 NA 2.8E-04 1.2E-03 NA 0.0 1.2E-03 1.2E-03 NA7.4E-05 NA 1.8E-02 7.7E-02 NA 0.0 7.7E-02 7.7E-02 NA1.8E-03 NA 4.2E-01 1.8E+00 NA 0.0 1.8E+00 1.8E+00 NA6.0E-07 NA 1.4E-04 6.3E-04 NA 0.0 6.3E-04 6.3E-04 NA8.6E-08 NA 2.1E-05 9.1E-05 NA 0.0 9.1E-05 9.1E-05 NA3.3E-06 NA 8.0E-04 3.5E-03 NA 0.0 3.5E-03 3.5E-03 NA2.0E-07 NA 4.7E-05 2.1E-04 NA 0.0 2.1E-04 2.1E-04 NA1.2E-08 NA 2.8E-06 1.2E-05 NA 0.0 1.2E-05 1.2E-05 NA1.1E-06 NA 2.6E-04 1.1E-03 NA 0.0 1.1E-03 1.1E-03 NA1.4E-06 NA 3.3E-04 1.4E-03 NA 0.0 1.4E-03 1.4E-03 NA8.2E-08 NA 2.0E-05 8.6E-05 NA 0.0 8.6E-05 8.6E-05 NA3.7E-07 NA 8.9E-05 3.9E-04 NA 0.0 3.9E-04 3.9E-04 NA2.5E-07 NA 6.1E-05 2.7E-04 NA 0.0 2.7E-04 2.7E-04 NA2.1E-06 NA 4.9E-04 2.2E-03 NA 0.0 2.2E-03 2.2E-03 NA2.4E-08 NA 5.6E-06 2.5E-05 NA 0.0 2.5E-05 2.5E-05 NA1Emission factors from AP-42, Section 1.4 "Natural Gas Combustion" (7/98) and the AP-42 heat value of 1,020 Btu/scf.2Naphthalene is included in the Polycyclic Organic Matter (POM) emissions and is not double-counted in the total HAPs.3Total POM emission factor is equal to the sum of the individual POM compounds.8aHAP Name(CAS)Cobalt (7440-48-4)Benzene (71-43-2)Dichlorobenzene (25321-22-6)Formaldehyde (50-00-0)Hexane (110-54-3)Naphthalene (91-20-3) [2]Polycyclic organic matter (POM) [3]Toluene (108-88-3)Arsenic (7440-38-2)Beryllium (7440-41-7)Cadmium (7440-43-9)Chromium (7440-47-3)Manganese (7439-96-5)Mercury (7439-97-6)Nickel (7440-02-0)Selenium (7782-49-2)aq-f1-ec13c.docPage 2When calculating Potential Emissions, use items 9a, 9b, 9d, 9e, 9g, 9h, and 9i (if a limit is proposed in item 12).When calculating Actual Emissions, use items 9a, 9b, 9c, 9f, 9g, and 9j.9)Calculations Summary - Secondary Fuel : N/A9b 9c 9d 9e 9f 9g 9h 9i 9jEmission Actual Emission Maximum Actual Pollution Maximum Limited ActualFactor1Annual Fuel Rate Uncontrolled Uncontrolled Control Controlled Controlled ControlledUse Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/MMBtu) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)NA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NANA 0.0E+00 0.0E+00 NA 0.0 0.0E+00 NA NA9aHAP Name(CAS)aq-f1-ec13c.docPage 311)Worse-Case Potential-to-Emit Summary: (Ignore this item if filling out this form for a Registration Permit Option D)11a) 11b) 11a) 11b)Before After Before AfterOperating Operating Operating OperatingLimits Limits Limits Limits(ton/yr) (ton/yr) (ton/yr) (ton/yr)2.2E-03 2.2E-03 Beryllium (7440-43-0-9) 1.2E-05 1.2E-051.2E-03 1.2E-03 Cadmium (7440-43-9) 1.1E-03 1.1E-037.7E-02 7.7E-02 Chromium (7440-47-3) 1.4E-03 1.4E-031.8E+00 1.8E+00 Cobalt (7440-48-4) 8.6E-05 8.6E-056.3E-04 6.3E-04 Manganese (74439-96-5) 3.9E-04 3.9E-049.1E-05 9.1E-05 Mercury (7439-97-6) 2.7E-04 2.7E-043.5E-03 3.5E-03 Nickel (7440-02-0) 2.2E-03 2.2E-03Arsenic (7440-38-2) 2.1E-04 2.1E-04 Selenium (7782-49-2) 2.5E-05 2.5E-05Totals1.9 ton/yr1Nahpthalene is included in the Polycyclic Organic Matter (POM) emissions and is not double-counted in the total HAPs.12)Operating Limitations, if applicable: (Ignore this item if filling out this form for a Registration Permit Option D):Not ApplicableHAP Name (CAS) HAP Name (CAS)Naphthalene (91-20-3)1POMToluene (108-88-3)Benzene (71-43-2)Dichlorobenzene (25321-22-6)Formaldehyde (50-00-0)Hexane (110-54-3)aq-f1-ec13c.docPage 4EC‐17GreenhouseGasEmissionsAirQualityPermitProgramDocType:PermitApplicationInstructionsonPage2.7a) 7b) 7c) 7e)EmissionFactorPollutionControlEfficiency(lb/unit) (lb/hr) (tpy)CO2e(tpy)(%) (lb/hr) (tpy)CO2e(tpy)(lb/hr) (tpy)CO2e(tpy)(tpy)CO2e(tpy)CO2111.2E+02 2.8E+04 1.2E+05 1.2E+05 0.0E+00 2.8E+04 1.2E+05 1.2E+05 2.8E+04 1.2E+05 1.2E+05 NA NACH42252.2E-03 5.3E-01 2.3E+00 5.8E+01 0.0E+00 5.3E-01 2.3E+00 5.8E+01 5.3E-01 2.3E+00 5.8E+01 NA NAN2O22982.2E-04 5.3E-02 2.3E-01 6.9E+01 0.0E+00 5.3E-02 2.3E-01 6.9E+01 5.3E-02 2.3E-01 6.9E+01 NA NAHFCsNA NA NA NA NA NA NA NA NA NA NA NAPFCsNA NA NA NA NA NA NA NA NA NA NA NASF623,900NA NA NA NA NA NA NA NA NA NA NA NA NATotalGHG(CO2e)1.2E+05 1.2E+05 1.2E+05 NA1Emission Factor = 53.02 kg CO2/MMBtu per Table C-1 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg2Emission Factor = 0.001 kg CH4/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg3Emission Factor = 0.0001 kg N2O/MMBtu per Equation C-10 and Table C-2 of 40 CFR 98 for natural gas, converted to lb/MMBtu using 2.20462 lb/kg2)Facility Name:Flint Hills Resources Pine Bend RefineryUse this form to summarize the potential and actual greenhouse gas (GHG) emissions for each operation contributing to GHG emissions. Continue to use the other emission forms (EC01 though EC-16) as applicable for other regulated air pollutants. Follow the guidance on calculation of greenhouse gas (GHG)emissions. Attach a separate spreadsheet showing allcalculations.1a)AQ Facility ID No.:037000111b)AQ File No.:106A3)Emisson unit ID number:EU-HRSGDB: HRSG Duct Burner (New MPCA EU)4)Stack/Vent designation number(s):SV-CHP (New MPCA SV)5)Control equipment number(s):CE-CHPSCR and CE-CHPCATOX (New MPCA CEs)ActualControlledEmissionRate6)Operating Limitations, if applicable:7)Greenhouse Gas Emissions Summary. Use this table to document GHG emissions from the unit or operation listed above. You must provide mass emissions of each pollutant, aswell as carbon dioxide equivalents (CO2e). For hydroflourocarbons (HFCs) and perfluorocarbons (PFCs), you will have to calculate emissions of individual compounds onthe seperatespreadsheet and report the total HFCs and PFCs in the table below. Instructions are provided starting on page 2. Please report all numbers using three (3) scientific notation ifnecessary (for example, report 379,355 tons as 3.79E5").7d) 7f) 7g) 7h)GHGPollutantGWPUncontrolledEmissionRate ControlledEmissionRateLimitedandControlledEmissionRateaq-f1-ec17 • 7/30/10Page 1AP-42 Section 3.1Background Document,Table 3.4-1EmissionFactor(lb/mmscf)EmissionFactorRatingEmissionFactor(lb/106 scf)EmissionFactorRatingEmission Factor withCO catalyst (lb/mmscf)106-99-01,3 Butadiene 4.38E-04 D 4.39E-0475-07-0Acetaldehyde 4.10E-02 C 1.80E-01107-02-8Acrolein 6.49E-03 C 3.69E-0371-43-2 Benzene 2.10E-03B1.20E-02 A 3.33E-0325321-22-6 Dichlorobenzene 1.20E-03E100-41-4 Ethylbenzene 3.26E-02 C 3.26E-0250-00-0 Formaldehyde 7.50E-02B7.23E-01 A 3.67E-01110-54-3 Hexane 1.8E91-20-3 Naphthalene 6.10E-04E1.30E-03 C 1.33E-03N/A Polycyclic organic matter (POM) 8.82E-05E2.27E-03 C 2.24E-0375-56-9 Propylene oxide 2.92E-02 D 2.96E-02108-88-3 Toluene 3.40E-03C1.37E-01 C 1.33E-011330-20-7 Xylenes 6.51E-02 C 6.53E-027440-38-2 Arsenic2.00E-04E7440-41-7 Beryllium1.20E-05E*7440-43-9 Cadmium1.10E-03D7440-47-3 Chromium1.40E-03D7440-48-4 Cobalt8.40E-05D7439-96-5 Manganese3.80E-04D7439-97-6 Mercury2.60E-04D7440-02-0 Nickel2.10E-03C7782-49-2 Selenium2.40E-05E*AP-42 HAP Emission FactorsCAS No. PollutantAP-42 Table 1.4-3 AP-42 Table 3.1-3Mandatory EAW Applicability DeterminationNOXSO2CO PM PM10PM2.5VOC GHG Carbon Disulfide Carbonyl Sulfide Benzene Formaldehyde Acetaldehyde CombustionEmission Unit MPCA ID tpy tpy tpy tpy tpy tpy tpy tpy CO2e tpy tpy tpy tpy tpy tpyATS Process Unit(EU 361) 33.53 19.71 7.60 2.11 5.89 5.89 1.97 32,994 2.08 0.69 0 0 0 0.36Sour Water Tanks (GP 136) 0 0000028.00 0New Equipment at ATS Process Unit(FS 140) 0 000000.82 23 4.42E-05New Equipment at FS 052 FS 052 0 000001.12 28 1.92E-03New Equipment at FS 095 FS 095 0 000001.12 28New Equipment at FS 117FS 1170 0 00001.92 4826 Unit Sulfur Recovery Unit EU 045, EU 047 0 0 0 0.60 0.60 0.60 0 0 1.20 0.40 0.00118 0.0004345 Unit Sulfur Recovery UnitEU 111, EU 112,EU 113, EU 1140 0 0 0.60 0.60 0.60 0 0 1.20 0.40 0.00118 0.00043Haul Road Truck Traffic IA 060 0 0 0 7.23 1.45 0.35 0 033.53 19.71 7.60 10.53 8.53 7.44 34.96 33,121 4.49 1.50 1.97E-03 0.002360.00087 0.36250 250 250 250 250 250 250 100,000No No No No No No No NoPollutantTotal Refinery Pre-Project (tpy)Tier 3CleanFuelsProjects(tpy)TotalRefineryPostProjects(tpy)PercentChangedue toProjects(%)Nitrogen Oxides (NOx) 3927.3 33.53 3,960.8 0.85%Sulfur Dioxide (SO2)3770.0 19.71 3,770 0.00%Carbon Monoxide (CO) 2366.3 7.60 2,373.9 0.32%Particulate Matter (PM) 1031.3 10.53 1,041.8 1.02%Particulate Matter <10 Microns (PM10)639.7 8.53 648.2 1.33%Particulate Matter <2.5 Microns (PM2.5)626.2 7.44 633.6 1.19%Volatile Organic Compounds(VOC) 2608.4 34.96 2,643.4 1.34%Greenhouse Gases (GHGs) 7,813,086 33,121 7,846,207 0.42%Hazardous Air Pollutants (HAPs) 854.2 6.35 860.5 0.74%Individual HAPsPotential Emissions IncreaseTotal Project Emission IncreaseMandatory EAW ThresholdIs Project Emission Increase Greater than Mandatory EAW Threshold?AppendixA,Attachment1‐1Attachment 1: Table 1PSD Applicability DeterminationNOXSO2CO PM PM10PM2.5VOC SAM H2STRS RSCPb GHGEmission Unit MPCA IDtpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy CO2eATS Process Unit (EU 361) 33.53 19.71 7.60 2.11 5.89 5.89 1.97 0.05 1.38 1.38 4.15 9.4E-05 32,994Sour Water Tanks (GP 136) 0.00 0.00 0.00 0.00 0.00 0.00 28.00 0.00 0.31 0.59 0.31 0.0E+00 0Fugitive Equipment at ATS Process Unit (FS 140) 0.00 0.00 0.00 0.00 0.00 0.00 0.82 0.00 0.14 0.14 0.14 0.0E+00 23New Equipment at 26 Sulfur Recovery Unit FS 052 0.00 0.00 0.00 0.00 0.00 0.00 1.12 0.00 0.05 0.05 0.05 0.0E+00 28New Equipment at 45 Sulfur Recovery Unit FS 095 0.00 0.00 0.00 0.00 0.00 0.00 1.12 0.00 0.05 0.05 0.05 0.0E+00 28New Equipment at Tank FarmFS 1170.00 0.00 0.00 0.00 0.00 0.00 1.92 0.00 0.03 0.03 0.03 0.0E+00 4826 Unit Sulfur Recovery Unit EU 045, EU 047 0.00 9.76 3.78 1.01 1.01 1.01 0.00 0.02 0.31 0.31 0.93 0.0E+00 2,87045 Unit Sulfur Recovery UnitEU 111, EU 112,EU 113, EU 1140.00 6.94 7.03 1.12 1.12 1.12 0.00 0.02 0.34 0.34 1.03 0.0E+00 3,173Sulfur Degassing SystemGP 1150.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.17 1.17 1.17 0.0E+00 0Cooling Towers GP 002 0.00 0.00 0.00 0.23 0.11 0.00 0.55 0.00 0.00 0.00 0.00 0.0E+00 0Haul Road Truck TrafficIA 060 0.00 0.00 0.00 7.23 1.45 0.35 0.00 0.00 0.00 0.00 0.00 0.0E+00 033.53 36.41 18.41 11.70 9.58 8.38 35.51 0.09 3.77 4.06 7.86 9.4E-05 39,16440 40 100 25 15 10 40 7 10 10 10 0.6 75,000No No No No No No No No No No No No-- -- -- -- -- -- -- -- -- -- -- ---- -- -- -- -- -- -- -- -- -- -- ---- -- -- -- -- -- -- -- -- -- -- --RSC = Reduced sulfur compounds (RSC), consisting of H2S, carbonyl sulfide, and carbon disulfide SAM = Sulfuric acid mistGHG = Greenhouse gas, reported as CO2e, consisting of CO2, CH4, and N2OTRS = Total reduced sulfur, consisting of H2S, dimethyl sulfide, dimethyl disulfide, and methyl mercaptanNOx SO2 CO PM PM10 PM2.5 VOC SAM H2STRS RSCPbtpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy CO2eProject Emission Increase(tpy)36.41 18.41 11.70 9.58 8.38 0.09 3.77 4.06 7.86Demand Growth Exclusion(tpy)18.66 48.96 22.33 22.33 22.33 0.04 0.38 1.15 1.15Project Emission Increase + Demand Growth Exclusion(tpy)55.07 67.38 34.04 31.91 30.72 0.13 4.15 5.21 9.01PSD Significant Emission Rate(SER)(tpy)40 100 25 15 10 7 10 10 10Yes Yes Yes Yes YesNo NoYes YesIs Preconstruction Documentation Required?Yes Yes Yes Yes YesNo NoYes YesYesNo NoYes YesNo No NoYesYesNo NoYes YesNo No NoYesN/AIs Project Emission Increase + Demand Growth Exclusion Greater than 50 %of the PSD Significant Emission Rate?Is Project Emission Increase Greater than 50 % of the PSD SignificantEmission Rate?Is Recordkeeping of Post-project Annual Actual Emissions Required?N/A N/A N/ANet Emissions Increase [Project Emissions Increase + Netting AnalysisCCI/CCD] (tpy)--Is Net Emissions Increase Greater than PSD SER?--Reasonable Possibility RequirementsGHGNetting Analysis: Sum of Contemporaneous Creditable Increases andDecreases ExcludingProject Emissions Increase(tpy)--Project Emissions IncreaseTotal Project Emission IncreasePSD Significant Emission Rate (SER)Is Project Emission Increase Greater than PSD Significant Emission Rate?NoAppendixA,Attachment1‐1

## Attachment 1: Table 2

Quantit y Value Units Reference Startup Burner Heat Input: 43.8 MMBtu/hr Vendor estimate

Production Rate: 364.0 LTPD ATS solution Vendor estimate 95.0 LTPD sulfur processing Vendor estimate
132,860 LTPY ATS solution Calculated

Exhaust Flow Rate: 8014.8 scfm Vendor estimate

7694.2 dscfm Vendor estimate

1738.1 ft/min Calculated
34,720 lb/hr Vendor estimate Flue Gas Molecular Weight: 27.82 lb/lb-mol Vendor estimate Sour Gas Throughput: 347.7 Mscf/hr Vendor estimate Hours of Operation: 8760 hr/yr

Pollutant Emission

Factor Units P otent i a l to

Emit
(lb/hr) [1] P otent i a l to

Emit
(tpy) [2] Emission Factor

Reference

NO x 133 ppmv (wet) 7.66 33.53 [3]

SO 2 

### 63 ppmv (wet) 5.00 19.71 [4]
CO 50 ppmw (wet) 1.74 7.60 [5] PM 0.0073 gr/dsc f 0.48 2.11 [6]

PM 10 

### 0.0204 gr/dscf 1.35 5.89 [7]

PM 2.5 

### 0.0204 gr/dscf 1.35 5.89 [7]
VOC 20 ppmv (wet) 0.45 1.97 [8] SAM 0.23% lb/lb SO2 1.15E-02 5.04E-02 [9]

H 2 

### S/TRS 7.95E-02 lb/LT S processing 0.31 1.38 [9]

RSC 2.40E-01 lb/LT S processing 0.95 4.15 [10]

Pb 4.90E-07 lb/MMBtu 2.15E-05 9.41E-05 [11]

CO 2 

### 21.65 lb/Mscf sour gas 7,528 32,970 [9]

CH 4 

### 2.20E-03 lb/MMBtu 9.66E-02 0.42 [11]

N 2 

### O 2.20E-04 lb/MMBtu 9.66E-03 4.23E-02 [12]

CO 2 

### e 7,533 32,994 [13]

[2] Potential to Emit (tpy) = Potential to Emit (lb/hr) x Hours of Operation (hr/yr) / 2000 lb/ton [3] Engineering estimate based upon vendor information.

[5] Engineering estimate based upon vendor information. [6] Based on 99% UCL of Ponca City test data (filterable only). [7] Based on 99% UCL of Ponca City test data (total PM). [8] Engineering estimate based upon vendor information. [9] Emission factors based upon calculations for Sulfur Recovery Units. (see Attachment 1: Table 9).
[10] Emission factors based upon Refinery ICR Protocol for CS 2 

### and COS, plus the emission factor for H 2 

### S.

[11] Based on EPA's AP-42 Section 1.4 for natural gas firing.

[14] As CO 2 

### e; Global Warming Potentials of 1 for CO 2 

### , 25 for CH 4 

### , and 298 for N 2 

### O per Table A-1 of 40 CFR 98 

## Potential to Emit for ATS Process Unit (EU 361)

[1] Potential to Emit (lb/hr) = Emission Factor (lb/MMBtu ) x Design Firing Rate at Norm al Operation (MMBtu/hr) or

= Emission Factor (ppmv) / 10 6 

### x Exhaust Flow (scfm) x 60 min/hr x Molecu lar Weight (lb/lb-mol) / 385.326 ft3/lb-mol (at 68 F) or

= Emission Factor (ppmw) / 10 6 

### x Exhaust Flow (lb/hr) or = Emission Factor (gr/dscf) / 7000 gr/lb x Exhaust Flow (dscfm) x 60 min/hr = Emission Factor (lb/lb SO 2 

### ) x SO2 emission rate (lb/hr)
= Emission Factor (lb/LT ) x Production Rate (LTPD) / 24 hr/day = Emission Factor (lb/Mscf sour gas) x Sour Gas Throughput (Mdscf/hr)

[4] Engineering estimate based upon vendor information. The hourly PTE refl ects normal operations and planned startup

conditions. The annual PTE reflects ex pected maximum annual emissions assuming 90% utilization. These limits are

consistent with the SO2 SIP modification.

[12] Emission Factor = 0.003 kg/MMBtu * HHV * 2.2 lb/kg per Equation C-8 of 40 CFR 98 (assume worst case factor for fuel gas, Tier 3) [13] Emission Factor = 0.0006 kg/MMBtu * HHV * 2.2 lb/kg per Equation C-8 of 40 CFR 98 (assume worst case factor for fuel gas, Tier 3)



### Appendix A, Attachment 1

‐ 1

# Attachment 1: Table 2 Potential to Emit for ATS Process Unit (EU 361)

Pollutant Emission

Facto r Units Potential to

Emit
(lb/hr) [1] Potential to

Emit
(tpy) [2] Emission Factor

Reference Carbon Disulfide 0.12 lb/LT 0.48 2.08 [10] Carbonyl Sulfide 0.04 lb/LT 0.16 0.69 [10] Arsenic Compounds 1.96E-07 lb/MMBtu 8.59E-06 3.76E-05 [8] Benzene 2.06E-06 lb/MMBtu 9.02E-05 3.95E-04 [8] Beryllium Compounds 1.18E-08 lb/MMBtu 5.16E-07 2.26E-06 [8] Cadmium Compounds 1.08E-06 lb/MMBtu 4.73E-05 2.07E-04 [8] Chromium Compounds 1.37E-06 lb/MMBtu 6.02E-05 2.63E-04 [8] Cobalt Compounds 8.24E-08 lb/MMBtu 3.61E-06 1.58E-05 [8] Dichlorobenzenes 1.18E-06 lb/MMBtu 5.16E-05 2.26E-04 [8] Formaldehyde 7.35E-05 lb/MMBtu 3.22E-03 1.41E-02 [8] Hexane 1.76E-03 lb/MMBtu 7.73E-02 0.34 [8] Lead Compounds 4.90E-07 lb/MMBtu 2.15E-05 9.41E-05 [8] Manganese Compounds 3.73E-07 lb/MMBtu 1.63E-05 7.15E-05 [8] Mercury Compounds 2.55E-07 lb/MMBtu 1.12E-05 4.89E-05 [8] Naphthalene 5.98E-07 lb/MMBtu 2.62E-05 1.15E-04 [8] Nickel Compounds 2.06E-06 lb/MMBtu 9.02E-05 3.95E-04 [8] POM 8.65E-08 lb/MMBtu 3.79E-06 1.66E-05 [8] Selenium Compounds 2.35E-08 lb/MMBtu 1.03E-06 4.52E-06 [8] Toluene 3.33E-06 lb/MMBtu 1.46E-04 6.40E-04 [8]

Pollutant Emission

Facto r Units Potential to

Emit
(lb/hr) [1] Potential to

Emit
(tpy) [2] Emission Factor

Reference Ammonia 50 ppmv 2.84 12.42 [3]

Pollutant Control

Efficienc y Controlled Emissions
(tpy) Uncontrolled

Emissions
(tpy)

PM 90 2.11 21.09

PM 10 

### 75 5.89 23.57

PM 2.5 

### 10 5.89 6.55

Control efficiencies from AP-42 Table B. 2-3 for AIRS Code 014 (high efficiency mi st eliminators with velocity > 250 fpm).

Note that the controlled PTE calculations do not direc tly rely upon the control efficiencies stated above. 

# Other Pollutant Emission Calculations

Uncontrolled PM, PM10, and PM2.5 Emissions (CAM Applicability) HAP Emission Calculations

Appendix A, Attachment 1

‐ 1Attachment 1: Table 3QuantityValueUnitsReferenceDesign Flow Rate: 1500 gpm Design valueTank Volume: 5,000,000 gal Engineering estimateAnnual Throughput: 788,400,000 gal/year CalculatedAnnual Turnovers: 158 turnovers/year CalculatedHours of Operation: 8760 hr/yrNormal OperationsPollutantStandingLosses(tpy)Withdrawal Losses(tpy)Total Losses(tpy)Total Losses(lb/hr)VOC 7.19 0.86 8.05 1.84H2S/RSC0.01 0.00 0.01 0.002Methyl Mercaptan 0.07 0.01 0.08 0.02TRS 0.08 0.01 0.09 0.02Ammonia 0.09 0.01 0.10 0.02Tank Landing and CleaningTank turnarounds for inspections are estimated to take 6-9 months. Tank cleaning is estimated at 3-4 months per tank.There are three activities:(1) Landing of the floating roof - emissions are standing idle losses.(2) Cleaning of the tank - emissions are from the ventilation system.(3) Refilling of the tank with diesel - emissions are refilling losses.Potential to Emit for Sour Water Storage Tanks TK 586, TK 587, TK 588 (GP 136)Emissions derived from TANKS 4.09d for sour water storage, assuming a maximum true vapor pressure of 6 psi. Emissions of H2Sestimated using measured concentration of 0.1112% from existing sour water tank system. Methyl Mercaptan content of 1% isestimated based on sour water MSDS. These contents are then multiplied by the calculated VOC emissions.AppendixA,Attachment1‐1Attachment 1: Table 3Potential to Emit for Sour Water Storage Tanks TK 586, TK 587, TK 588 (GP 136)(1) Standing Idle Losses (Equation 2-19 of AP-42 Chapter 7.1)LSLwind = 0.57 nd D P* MVnd: 5 number of days standing idleD: 110 Tank Diameter (ft)P*: 0.229 vapor pressure function Equation (2-18)Pa: 14.3 atmospheric pressure, psiaP: 6 true vapor pressure of sour waterMw: 50 Vapor molecular weight of crude as proxy, Table 7.1-2Losses: 3596.74 standing idle VOC emissions (lbs)(2) Cleaning LossesLclean = (C/10^6) x F x 60 min/hr x Mw / 385.326 ft3/lb-mol * HC: 100F: 3801 scfm, exhaust flow based on 4 displacements per hourMw: 50 Vapor molecular weight of crude as proxy, Table 7.1-2H: 4380 hours per year (assumes 1 event/year)Losses: 12962.90 cleaning VOC emissions (lbs)(3) Refill Losses (Equation 2-26 of AP-42 Chapter 7.1)LFL = (PVv/RT)*Mv*Csf*SP: 0.022 true vapor pressure of dieselVv: 57,020 vapor space volume under landed floating roof, ft3R 10.731 ideal gas constant, 10.731T 530 refill temp, RMV 130 Molecular weight of vaporCsf*S 0.58 Saturation constantLosses: 16.53 refilling VOC emissions (lbs)ppmv, average concentration of exhaust gases based upon previous sour water tankcleaning eventsAppendixA,Attachment1‐2Attachment 1: Table 3Potential to Emit for Sour Water Storage Tanks TK 586, TK 587, TK 588 (GP 136)PollutantTotal Losses(tpy)VOC 8.29H2S/RSC0.09Methyl Mercaptan 0.08TRS 0.18Ammonia 0.11Total Emissions (GP TKS)Total VOC emissions for one tank during normal operations: 8.05 tpyTotal VOC emissions during a calendar year with a turnaround for 6 months: 12.31 tpyEmissions from normal operation for 6 months: 4.03 tpyEmissions from tank landing and cleaning: 8.29 tpyTotal VOC emissions from the worst case (per tank): 12.31 tpyTotal VOC emissions from GP TKS (unrestricted): 36.94 tpyProposed VOC emissions cap: 28.00 tpyTotal H2S/RSC emissions from the sum of the 3 storage tanks:0.31 tpyTotal TRS emissions from the sum of the 3 storage tanks: 0.59 tpyRefer to Form CD-01 for the proposed GK TKS for additional information regarding the emissions cap and proposedcompliance demonstration methodology.AppendixA,Attachment1‐3Attachment 1: Table 4Potential to Emit for Fugitive Equipment at the ATSProcess Unit (FS 140)Fugitive equipment are in sour water, clean acid gas, ammonia acid gas, or natural gas service within the ATS Process Unit.Sour Water ServiceProjectNumber leaking/non-repairable/Leak rate(non-leakers)Leak rate(leakers)Leak ratetotalPotential toEmitCount [1] unsafe to monitor (kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 25 24 1 1.71E-03 2.21E-03 3.91E-03 0.04Other (Relief Valves, etc.) 0 0 0 -- -- -- --Flanges 55 53 2 1.93E-02 5.98E-03 2.53E-02 0.24Other (compressors) 0 0 0 -- -- -- --Pumps/all 4 4 0 1.36E-02 -- 1.36E-02 0.13Process Drains 2 N/A N/A N/A N/A 3.09E-03 0.03Total Emissions (tpy):VOC 0.44CH4[3] 0.44CO2e [3]11.05[1] Equipment count totals frompreliminary engineering estimates.[2] Emissions factor methodology is described in Appendix A.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential toEmit for New EquipmentPotential toEmit Potential to Emit(lb/hr) (tpy)Ammonia 3.5% 3.53E-03 1.55E-02Benzene 0.01% 1.01E-05 4.42E-05Ethyl Mercaptan 1.3% 1.31E-03 5.75E-03Hydrogen Sulfide 1% 1.01E-03 4.42E-03Methyl Mercaptan 1% 1.01E-03 4.42E-03Ammonia and ethyl mercaptan are not criteria or hazardous air pollutants and are provided for informational purposes only.Methyl mercaptan and hydrogen sulfide are components of TRS.Hydrogen sulfide is a component of RSC.Component TypeNumber notleakingChemical NameWeightPercentageof VOCAppendixA,Attachment1‐1Attachment 1: Table 4Potential to Emit for Fugitive Equipment at the ATSProcess Unit (FS 140)Clean Acid Gas ServiceProjectLeak rate(non-leakers) Potential to EmitCount [1] (kg/hr) (tpy) [2]Valves/all 15 1.07E-03 0.01Other (Relief Valves, etc.) 1 5.29E-04 0.01Flanges 33 1.20E-02 0.12Other (compressors) 0 -- --Pumps/all 0 -- --Process Drains 0 N/A N/ATotal Emissions (tpy):VOC 0.13CH4[3] 0.13CO2e [3]3.28[1] Equipment count totals frompreliminary engineering estimates.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential toEmit for New EquipmentPotential toEmit Potential to Emit(lb/hr) (tpy)Benzene 0.01% 2.99E-06 1.31E-05Hydrogen Sulfide 100% 2.99E-02 0.13Hydrogen sulfide is a component of TRS and RSC.Chemical NameWeightPercentageof VOC[2] Emissions factor methodology is described in Appendix A. Equipment will not be in VOC service or subject to LDAR requirements. Due to the highconcentration of H2S in the clean acid gas, leaks will be detectableat very low levels. FHR has conservatively assumed emission rates consistent with nonleaking components under the LDAR program.Component TypeAppendixA,Attachment1‐2Attachment 1: Table 4Potential to Emit for Fugitive Equipment at the ATSProcess Unit (FS 140)Ammonia Acid Gas ServiceProjectNumber leaking/non-repairable/Leak rate(non-leakers)Leak rate(leakers)Leak ratetotalPotential toEmitCount [1] unsafe to monitor (kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 20 19 1 1.35E-03 2.21E-03 3.56E-03 0.03Other (Relief Valves, etc.) 1 1 0 5.29E-04 -- 5.29E-04 0.01Flanges 43 41 2 1.49E-02 5.98E-03 2.09E-02 0.20Other (compressors) 1 1 0 7.95E-04 -- 7.95E-04 0.01Pumps/all 0 0 0 -- -- -- --Process Drains 0 N/A N/A N/A N/A -- --Total Emissions (tpy):VOC 0.25CH4[3] 0.25CO2e [3]6.21[1] Equipment count totals frompreliminary engineering estimates.[2] Emissions factor methodology is described in Appendix A.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential toEmit for New EquipmentPotential toEmit Potential to Emit(lb/hr) (tpy)Ammonia 40% 2.27E-02 0.10Hydrogen Sulfide 2% 1.13E-03 4.97E-03Ammonia is not a criteria or hazardous air pollutant and is provided for informational purposes only.Hydrogen sulfide is a component of TRS and RSC.Component TypeNumber notleakingChemical NameWeightPercentageof VOCAppendixA,Attachment1‐3Attachment 1: Table 4Potential to Emit for Fugitive Equipment at the ATSProcess Unit (FS 140)Natural Gas ServiceProjectNumber leaking/non-repairable/Leak rate(non-leakers)Leak rate(leakers)Leak ratetotalPotential toEmitCount [1] unsafe to monitor (kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 10 10 0 7.11E-04 -- 7.11E-04 0.01Other (Relief Valves, etc.) 0 0 0 -- -- -- --Flanges 20 19 1 6.92E-03 2.99E-03 9.91E-03 0.10Other (compressors) 0 0 0 -- -- -- --Pumps/all 0 0 0 -- -- -- --Process Drains 0 N/A N/A N/A N/A -- --Total Emissions (tpy):VOC [3] --CH4[4] 0.10CO2e [4]2.56[1] Equipment count totals frompreliminary engineering estimates.[2] Emissions factor methodology is described in Appendix A.[3] These fugitive components are not in VOC service; natural gas contains negligible non-methane non-ethane organic compounds.[4] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Total EmissionsPollutantEmissions(tpy)VOC 0.82CH4 0.92CO2e 23.10H2S0.14TRS 0.14RSC 0.14Ammonia 0.11Benzene 4.42E-05Ethyl Mercaptan 5.75E-03Methyl Mercaptan 4.42E-03Component TypeNumber notleakingAppendixA,Attachment1‐4Attachment 1: Table 5Potential to Emit for New Equipment at FS 052 (26 Unit)Amine System at26 Unit [1]leaking/non-(nonleakers)Leak rate(leakers) Leak rate total Potential to EmitFS 052nsafe to monito(kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 100 96 4 6.83E-03 8.83E-03 1.57E-02 0.15Other (Relief Valves, etc.) 4 4 0 2.11E-03 -- 2.11E-03 0.02Flanges 200 192 8 6.99E-02 2.39E-02 9.38E-02 0.90Other (compressors) 0 0 0 -- -- -- --Pumps/all 0 0 0 -- -- -- --Process Drains 3 N/A N/A N/A N/A 4.64E-03 0.04Total Project Emissions (tpy):VOC 1.12CH4[3] 1.12CO2e [3]28.00[1] Equipment count totals from preliminary engineering estimates.[2] Emissions factor methdology is described in Appendix A.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential to Emit for New Equipment at FS 052 (26 Unit)Potential to EmitPotential toEmit(lb/hr) (tpy)Ammonia 1.0% 2.56E-03 0.01Hydrogen Sulfide4.2% 1.07E-02 0.05Speciation is estimated assuming components are in rich amine service.Ammonia is not a criteria or hazardous air pollutant and is provided for informational purposes only.Hydrogen sulfide is a component of RSC and TRS.Component TypeNumber notleakingChemical NameWeightPercentage ofVOCAppendixA,Attachment1‐1Attachment 1: Table 6Potential to Emit for New Equipment at FS 095 (45 Unit)Amine System at45 Unit [1]leaking/non-(nonleakers)Leak rate(leakers) Leak rate total Potential to EmitFS 095nsafe to monito(kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 100 96 4 6.83E-03 8.83E-03 1.57E-02 0.15Other (Relief Valves, etc.) 4 4 0 2.11E-03 -- 2.11E-03 0.02Flanges 200 192 8 6.99E-02 2.39E-02 9.38E-02 0.90Other (compressors) 0 0 0 -- -- -- --Pumps/all 0 0 0 -- -- -- --Process Drains 3 N/A N/A N/A N/A 4.64E-03 0.04Total Project Emissions (tpy):VOC 1.12CH4[3] 1.12CO2e [3]28.00[1] Equipment count totals from preliminary engineering estimates.[2] Emissions factor methdology is described in Appendix A.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential to Emit for New Equipment at FS 095 (45 Unit)Potential to EmitPotential toEmit(lb/hr) (tpy)Ammonia 1.00% 2.56E-03 0.01Hydrogen Sulfide4.20% 1.07E-02 0.05Speciation is estimated assuming components are in rich amine service.Ammonia is not a criteria or hazardous air pollutant and is provided for informational purposes only.Hydrogen sulfide is a component of RSC and TRS.Component TypeNumber notleakingChemical NameWeightPercentage ofVOCAppendixA,Attachment1‐1Attachment 1: Table 7Potential to Emit for New Equipment at FS 117 (Tank Farm - Slop Oil System)All Tankage [1]leaking/non-(nonleakers)Leak rate(leakers) Leak rate total Potential to EmitFS 117nsafe to monito(kg/hr) (kg/hr) (kg/hr) (tpy) [2]Valves/all 132 127 5 9.03E-03 1.10E-02 2.01E-02 0.19Other (Relief Valves, etc.) 3 3 0 1.59E-03 -- 1.59E-03 0.02Flanges 284 273 11 9.94E-02 3.29E-02 1.32E-01 1.27Other (compressors) 2 2 0 1.59E-03 -- 1.59E-03 0.02Pumps/all 8 7 1 2.38E-02 1.39E-02 3.77E-02 0.36Process Drains 4 N/A N/A N/A N/A 6.18E-03 0.06Total Project Emissions (tpy):VOC 1.92CH4[3] 1.92CO2e [3]48.02[1] Equipment count totals from preliminary engineering estimates.[2] Emissions factor methdology is described in Appendix A.[3] All VOC is conservatively assumed to be methane (CH4). Global warming potential of 25 use to convert methane to CO2e.Speciated Potential to Emit for New Equipment at FS 117 (Tank Farm - Slop Oil System)Potential to EmitPotential toEmit(lb/hr) (tpy)Benzene 0.10% 4.39E-04 1.92E-03Hydrogen Sulfide1.50% 6.58E-03 0.03Speciation is estimated assuming components are in slop oil service.Benzene is a hazardous air pollutant.Hydrogen sulfide is a component of RSC and TRS.Component TypeNumber notleakingChemical NameWeightPercentage ofVOCAppendixA,Attachment1‐1

## Attachment 1: Table 8

SO 2 CO PM PM 10 PM 2.5 SAM H 2 S/TRS RSC CO 2 GHG Sulfur

Feed Rate

tons tons tons tons tons t ons tons tons tons tons CO 2 e LT
Date [1] [1] [2] [2] [2] [3] [4] [5] [6] [7] [8]

Jul-11 17.87 4.37 0.89 0.89 0.89 0.04 0.54 1.64 5,027 5,032 13,660

A u g -11 16.87 4.13 0.99 0.99 0.99 0.04 0.60 1.82 5,595 5,600 15,201 Sep-11 8.94 3.63 0.67 0.67 0.67 0.02 0.41 1.24 3,813 3,818 10,360

Oct-11 16.90 4.53 0.92 0.92 0.92 0.04 0.56 1.69 5,187 5,192 14,093

Nov-11 14.60 4.17 0.87 0.87 0.87 0.03 0.53 1.60 4,919 4,925 13,366

Dec-11 18.81 6.27 0.87 0.87 0.87 0.04 0.53 1.60 4,924 4,930 13,379

Jan-12 18.81 6.27 0.96 0.96 0.96 0.04 0.59 1.77 5,451 5,456 14,809

Feb-12 18.12 6.26 0.88 0.88 0.88 0.04 0.54 1.62 4,972 4,977 13,510

Mar-12 17.47 4.58 0.81 0.81 0.81 0.04 0.49 1.49 4,574 4,579 12,427

A pr-12 16.61 4.52 0.83 0.83 0.83 0.04 0.51 1.53 4,697 4,703 12,763

Ma y -12 15.32 4.59 0.85 0.85 0.85 0.04 0.52 1.56 4,798 4,804 13,038

Jun-12 14.16 4.15 0.78 0.78 0.78 0.03 0.48 1.43 4,406 4,411 11,972

Jul-12 17.00 4.87 0.89 0.89 0.89 0.04 0.54 1.64 5,044 5,049 13,705

A u g -12 16.34 4.95 0.86 0.86 0.86 0.04 0.53 1.59 4,888 4,893 13,281 Sep-12 14.56 8.04 0.76 0.76 0.76 0.03 0.47 1.41 4,331 4,336 11,768

Oct-12 13.83 5.00 0.83 0.83 0.83 0.03 0.51 1.52 4,683 4,688 12,724

Nov-12 13.32 4.74 0.73 0.73 0.73 0.03 0.45 1.35 4,157 4,162 11,295

Dec-12 15.29 6.04 0.81 0.81 0.81 0.04 0.50 1.50 4,601 4,607 12,500

Jan-13 17.54 5.79 0.80 0.80 0.80 0.04 0.49 1.47 4,528 4,533 12,301

Feb-13 12.74 4.88 0.71 0.71 0.71 0.03 0.44 1.32 4,045 4,050 10,990

Mar-13 15.20 5.21 0.83 0.83 0.83 0.03 0.51 1.53 4,706 4,711 12,785

A pr-13 13.00 4.90 0.69 0.69 0.69 0.03 0.42 1.28 3,934 3,939 10,689

Ma y -13 11.42 4.04 0.66 0.66 0.66 0.03 0.40 1.21 3,723 3,727 10,114

Jun-13 18.92 4.33 0.78 0.78 0.78 0.04 0.48 1.44 4,416 4,421 11,998

Baseline

Period

Ends: Jun-13 Jun-13 Jun-13 Jun-13 Jun- 13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13

-- B ase li ne

Actual

Emissions: 186.83 60.13 9.84 9.84 9.84 0. 43 6.02 18.13 55,709.51 55,773

--

Emission Factor References
[ 1 ] Based on CEMS data.
[ 2 ]
[3] SAM emissions are a function of SO 2 emissions. Emission factor based on ratio of 0.23% from SO 2

. [4] Emission factor of 0.08 lb H 2 S/LT produced based on emission limit from the existing Title V Permit.

[5] Emission factor of 0.24 lb/LT based on factors for COS and CS 2 from Refinery ICR Protocol plus emissions of H 2 S.

[7] Emissions based on factor of 0.0005 lb/MMscf per AP-42 Table 1.4-2 and actual refiner y fuel g as firin g rates.
[6] CO 2 process emissions calculated using Equation Y-8 of 40 CFR 98. Combustion CO2 emissions are not included in this quantity.

[7] As CO 2 e; Global Warming Potentials of 1 for CO 2 , 25 for CH 4 , and 298 for N 2 O per Table A-1 of 40 CFR 98 

## Baseline Actual Emission Calculations for EU-26UNIT_1 SRU #5 (MPCA EU 045), EU-26ME22 SRU #5
Sulfur Pit (MPCA EU 047)

Emissions based on factor of 0.13 lb/LT sulfur, which is based upon engineering stack test data.



### Appendix A, Attachment 1

‐ 1Attachment 1: Table 9QuantityValueUnitsReferenceProjected SRU Rate: 456 LTD Engineering estimateSour Gas Production: 34.0 Mscf/LT Engineering estimateHours of Operation: 8760 hr/yrExcludable Throughput:158,623LT/yr224,207MMBtu/yr5,393,165 Mscf sour gas/yrPollutantEmissionFactor UnitsProjectedEmissions(lb/hr) [1]ProjectedEmissions(tpy) [2]Emission FactorReferenceNOXNo increase pursuant to project because firing will not increase.SO22.504 lb/LT 47.57 208.36 [3]CO 0.970 lb/LT 18.43 80.71 [3]PM 0.26 lb/LT 4.94 21.63 [4]PM100.26 lb/LT 4.94 21.63 [4]PM2.50.26 lb/LT 4.94 21.63 [4]VOC No increase pursuant to project because firing will not increase.SAM 5.76E-03 lb/LT 1.09E-01 4.79E-01 [5]H2S/TRS0.08 lb/LT 1.51 6.62[6]RSC 0.24 lb/LT 4.55 19.93 [7]Pb No increase pursuant to project because firing will not increase.CO221.65 lb/Mscf sour gas 13,984.2 61,251.0 [8]CH4No increase pursuant to project because firing will not increase.N2ONo increase pursuant to project because firing will not increase.GHG 13,984.2 61,251.0 [9][1] Projected Emissions (lb/hr) = Emission Factor (lb/LT) x Projected Rate (LT/yr) orProjected Emissions (lb/hr) = Emission Factor (lb/MMscf) x Projected Firing Rate (Mscf/hr) / 1000 Mscf/MMscf[2]Emission Increase (tpy) = Projected Emissions (lb/hr) x Hours of Operation (hr/yr) / 2000 lb/tonProjected Actual Emission Calculations for EU-26UNIT_1 SRU #5 (MPCA EU 045),EU-26ME22 SRU #5 Sulfur Pit (MPCA EU 047)AppendixA,Attachment1‐1Attachment 1: Table 9NOx SO2CO PM PM10PM2.5VOC SAM H2S/TRSRSCPb GHGtpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy tpy CO2e ReferenceA. Baseline Actual Emissions N/A 186.83 60.13 9.84 9.84 9.84 N/A 0.43 6.02 18.13 N/A 55,710 Attachment 1: Table 8B. Excludable Emissions N/A 198.60 76.93 20.62 20.62 20.62 N/A 0.46 6.31 19.00 N/A 58,381 See below.C. Projected Emissions N/A 208.36 80.71 21.63 21.63 21.63 N/A 0.48 6.62 19.93 N/A 61,251D. Demand Growth (D=B-A) N/A 11.77 16.80 10.78 10.78 10.78 N/A 0.03 0.29 0.87 N/A 2,672E. Projected Actual Emissions (E=C-D) N/A 196.59 63.91 10.85 10.85 10.85 N/A 0.45 6.33 19.06 N/A 58,579F. Emission Increase (F=E-A) 0.00 9.76 3.78 1.01 1.01 1.01 0.00 0.02 0.31 0.93 0.00 2,870B. Calculation of Excludable Emissions NOx SO2CO PM PM10PM2.5VOC SAM H2S/TRSRSCPbGHG(CO2e) NotesAnnual Emission Limits (ton/yr) N/A 409.8 121 N/A N/A N/A N/A N/A N/A N/A N/A N/A Limits for SV 042[3] Emission factor based on average performance during baseline period plus one standard deviation.[4] Emissions based on factor of 0.26 lb/LT sulfur, which is a conservative estimate based upon Hyperion's 2011 application and consistent with the Crude-Coker permitting.[5] SAM emissions are a function of SO2emissions. Emission factor based on ratio of 0.23% from SO2.[6] Emission factor of 0.08 lb H2S/LT produced based on emission limit from the existing Title V Permit.[7] Emission factor of 0.24 lb/LT based on factors for COS and CS2from Refinery ICR Protocol plus emissions of H2S.[8] CO2process emissions calculated using Equation Y-8 of 40 CFR 98.[9] As CO2e; Global Warming Potentials of 1 for CO2, 25 for CH4, and 298 for N2O per Table A-1 of 40 CFR 9858,3810.46 6.31 19.00 N/AFactors and unitsconsistent with PAE.Excludable Emissions (ton/yr) N/A 198.60 76.93 20.62 20.620.006 0.080 0.240 N/A20.62 N/AProjected Actual Emission Calculations for EU-26UNIT_1 SRU #5 (MPCA EU 045), EU-26ME22 SRU #5 Sulfur Pit (MPCA EU047)Representative Emission Factor N/A 2.504 0.970 0.260 0.260 0.260 N/A 21.65AppendixA,Attachment1‐2

## Attachment 1: Table 10

SO 2 CO PM PM 10 PM 2.5 SAM H 2 S/TRS RSC CO 2 GHG Sulfur

Feed Rate

tons tons tons tons tons tons tons tons tons tons CO 2 e LT
Date [1] [1] [2] [2] [2] [3] [4] [5] [6] [7] [8]

Jul-11 11.28 6.81 0.93 0.93 0.93 0.03 0.57 1.71 5,245 5,252 14,251

A ug-11 11.98 7.02 1.00 1.00 1.00 0.03 0.61 1.85 5,672 5,680 15,412 Sep-11 6.96 6.09 0.65 0.65 0.65 0.02 0.40 1.20 3,687 3,691 10,016
Oct-11 11.69 10.72 1.06 1.06 1.06 0.03 0.65 1.95 5,987 5,995 16,268
Nov-11 11.47 9.64 1.02 1.02 1.02 0.03 0.62 1.88 5,763 5,770 15,658
Dec-11 10.20 10.11 0.99 0.99 0.99 0.02 0.60 1.82 5,584 5,591 15,171
Jan-12 12.85 8.38 0.99 0.99 0.99 0.03 0.61 1.83 5,617 5,624 15,261
Feb-12 11.22 8.78 0.94 0.94 0.94 0.03 0.58 1.74 5,349 5,356 14,533
Mar-12 11.34 11.18 0.95 0.95 0.95 0.03 0.58 1.76 5,394 5,401 14,656

A pr-12 11.16 11.12 0.98 0.98 0.98 0.03 0.60 1.81 5,569 5,576 15,131 May-12 11.35 8.34 0.88 0.88 0.88 0.03 0.54 1.62 4,970 4,977 13,504
Jun-12 10.15 8.54 0.96 0.96 0.96 0.02 0.59 1.78 5,461 5,467 14,838
Jul-12 12.31 7.37 0.97 0.97 0.97 0.03 0.59 1.79 5,488 5,495 14,910

A ug-12 12.66 7.54 0.45 0.45 0.45 0.03 0.27 0.82 2,526 2,533 6,863 Sep-12 5.11 6.89 1.01 1.01 1.01 0.01 0.62 1.86 5,722 5,726 15,546
Oct-12 11.70 8.02 0.95 0.95 0.95 0.03 0.58 1.75 5,368 5,375 14,584
Nov-12 11.41 10.18 1.01 1.01 1.01 0.03 0.62 1.85 5,696 5,703 15,477
Dec-12 12.98 12.98 1.04 1.04 1.04 0.03 0.64 1.91 5,882 5,890 15,982
Jan-13 13.47 12.55 0.93 0.93 0.93 0.03 0.57 1.72 5,290 5,298 14,374
Feb-13 13.47 11.64 1.08 1.08 1.08 0.03 0.66 1.99 6,106 6,113 16,589
Mar-13 13.06 11.77 0.88 0.88 0.88 0.03 0.54 1.62 4,964 4,972 13,488

A pr-13 9.83 9.87 0.86 0.86 0.86 0.02 0.52 1.58 4,850 4,856 13,177 May-13 9.46 6.38 0.99 0.99 0.99 0.02 0.61 1.83 5,626 5,632 15,285
Jun-13 11.26 9.56 0.98 0.98 0.98 0.03 0.60 1.80 5,540 5,547 15,051

Baseline

Period Ends: Jun-13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13 Jun-13

-- B ase li ne

Actual

Emissions: 134.19 110.75 11.25 11.25 11.25 0.31 6.88 20.72 63,677.44 63,759

--

Emission Factor References
[ 1 ] Based on CEMS data.
[2]

[3] SAM emissions are a function of SO 2 emissions. Emission factor based on ratio of 0.23% from SO 2

. [4] Emission factor of 0.08 lb H 2 S/LT produced based on emission limit from the existing Title V Permit.

[5] Emission factor of 0.24 lb/LT based on factors for COS and CS 2 from Refinery ICR Protocol plus emissions of H2 S

. [6] CO 2 process emissions calculated using Equation Y-8 of 40 CFR 98. Combustion CO2 emissions are not included in this quantity.

[7] As CO2e; Global Warming Potentials of 1 for CO 2 , 25 for CH 4 , and 298 for N 2 O per Table A-1 of 40 CFR 98

[8] A ctual process rates.

## Baseline Actual Emission Calculations for EU-45UNIT2_1 SRU #3, EU-45ME114A SRU #3 Sulfur Pit, EU45UNIT3_1 SRU #4, EU-45ME210A SRU #4 Sulfur Pit (MPCA EU 111, 112, 113, 114)

Emissions based on factor of 0.13 lb/LT sulfur, which is based upon engineering stack test data.

Appendix A, Attachment 1

‐ 1Attachment 1: Table 11QuantityValueUnitsReferenceProjected SRU Rate: 504 LTD Engineering estimateSour Gas Production: 34.0 Mscf/LTEngineering estimateHours of Operation: 8760 hr/yrExcludable Throughput:175,359LT/yr291,244MMBtu/yr5,962,214 Mscf sour gas/yrPollutantEmissionFactorUnitsProjectedEmissions(lb/hr) [1]ProjectedEmissions(tpy) [2]Emission FactorReferenceNOXNo increase pursuant to project because firing will not increase.SO21.609 lb/LT 33.79 148.01 [3]CO 1.630 lb/LT 34.23 149.94 [3]PM 0.26 lb/LT 5.46 23.92 [4]PM100.26 lb/LT 5.46 23.92 [4]PM2.50.26 lb/LT 5.46 23.92 [4]VOC No increase pursuant to project because firing will not increase.SAM 3.70E-03 lb/LT 7.77E-02 3.40E-01 [5]H2S/TRS0.08 lb/LT 1.67 7.31[6]RSC 0.24 lb/LT 5.03 22.03 [7]Pb No increase pursuant to project because firing will not increase.CO221.65 lb/Mscf sour gas 15459.8 67,713.7 [8]CH4No increase pursuant to project because firing will not increase.N2ONo increase pursuant to project because firing will not increase.GHG 15,459.8 67,713.7 [9][1] Projected Emissions (lb/hr) = Emission Factor (lb/LT) x Projected Rate (LT/yr) orProjected Emissions (lb/hr) = Emission Factor (lb/MMscf) x Projected Firing Rate (Mscf/hr) / 1000 Mscf/MMsc[2]Emission Increase (tpy) = Projected Emissions (lb/hr) x Hours of Operation (hr/yr) / 2000 lb/tonProjected Actual Emission Calculations for EU-45UNIT2_1 SRU #3, EU-45ME114ASRU #3 Sulfur Pit, EU-45UNIT3_1 SRU #4, EU-45ME210A SRU #4 Sulfur Pit(MPCAAppendixA,Attachment1‐1Attachment 1: Table 11NOx SO2 CO PM PM10 PM2.5VOC SAM H2S/TRS RSC Pb GHGtpytpytpytpytpytpytpytpytpytpytpytpy CO2eReferenceA. Baseline Actual Emissions N/A 134.19 110.75 11.25 11.25 11.25 N/A 0.31 6.88 20.72 N/A 63,759 Attachment 1: Table 10B. Excludable Emissions N/A 141.08 142.92 22.80 22.80 22.80 N/A 0.32 6.97 21.00 N/A 64,541 See below.C. Projected Emissions N/A 148.01 149.94 23.92 23.92 23.92 N/A 0.34 7.31 22.03 N/A 67,714D. Demand Growth (D=B-A)N/A 6.89 32.16 11.55 11.55 11.55 N/A 0.02 0.09 0.28 N/A 782E. Projected Actual Emissions (E=C-D) N/A 141.12 117.78 12.37 12.37 12.37 N/A 0.32 7.22 21.75 N/A 66,932F. Emission Increase (F=E-A)0.00 6.94 7.03 1.12 1.12 1.12 0.00 0.02 0.34 1.03 0.00 3,173B. Calculation of Excludable Emissions NOx SO2 CO PM PM10 PM2.5 VOC SAM H2S RSC PbGHG(CO2e) NotesAnnual Emission Limits (ton/yr) N/A 324.3 608 N/A N/A N/A N/A N/A N/A N/A N/A N/A Limits for SV 093 or GP 112[3] Emission factor based on average performance during baseline period plus one standard deviation[4] Emissions based on factor of 0.26 lb/LT sulfur, which is a conservative estimate based upon Hyperion's 2011 application and consistent with the Crude-Coker permitting.[5] SAM emissions are a function of SO2emissions. Emission factor based on ratio of 0.23% from SO2.[6] Emission factor of 0.08 lb H2S/LT produced based on emission limit from the existing Title V Permit.[7] Emission factor of 0.24 lb/LT based on factors for COS and CS2from Refinery ICR Protocol plus emissions of H2S.[8] CO2process emissions calculated using Equation Y-8 of 40 CFR 98.[9] As CO2e; Global Warming Potentials of 1 for CO2, 25 for CH4, and 298 for N2O per Table A-1 of 40 CFR 9864,5410.32 6.97 21.00 N/AFactors and units consistentwith PAE.Excludable Emissions (ton/yr) N/A 141.08 142.92 22.80 22.800.004 0.080 0.240 N/A22.80 N/AProjected Actual Emission Calculations for EU-45UNIT2_1 SRU #3, EU-45ME114A SRU #3 Sulfur Pit, EU-45UNIT3_1 SRU#4, EU-45ME210A SRU #4 Sulfur Pit(MPCA EU 111, 112, 113, 114)Representative Emission Factor N/A 1.609 1.630 0.260 0.260 0.260 N/A 22AppendixA,Attachment1‐2Attachment 1: Table 12QuantityValueUnitsReferenceDesign TDS: 3,500 mg/L Title V permitIncremental Circulation Rate: 3,000 gpm Design rateDrift: 0.001% Title V permitHours of Operation: 8760 hr/yrPollutantEmissionFactor UnitsProjectedEmissions(lb/hr) [1]ProjectedEmissions(tpy) [2]NOX0 -- 0 0SO20 -- 0 0CO 0 -- 0 0PM 0.29 lb/MMgal 5.25E-02 0.23PM10[3]0.14 lb/MMgal 2.47E-02 0.11PM2.5[3]6.13E-04 lb/MMgal 1.10E-04 4.83E-04VOC 0.70 lb/MMgal 0.13 0.55SAM 0 -- 0 0H2S/TRS/RSC0 -- 0 0CO20 -- 0 0CH40 -- 0 0N2O0 -- 0 0CO2e0 -- 0 0[1]Projected Emissions (lb/hr) = Emission Factor (lb/MMGal) x Circulation Rate (gpm) x 60 min/hr/10^6[2]Emission Increase (tpy) = Projected Emissions (lb/hr) x Hours of Operation (hr/yr) / 2000 lb/ton----GHG emissions are negligible[3]Fraction of total PM that is PM10 is 47%, and PM2.5 is 0.21% based on Reisman and Frisbie, Calculating Realistic PM10Emissions from Cooling Towers, Proceedings of 2001 A&WMA ACE.AP-42 Section 13.4AP-42 Section 13.4AP-42 Section 13.4------AP-42 Section 13.4Incremental Emissions Increase Calculations for Cooling Towers (MPCA GP 002)Emission Factor Reference------AppendixA,Attachment1‐1Attachment 1: Table 13Potential to Emit for Haul Road Truck Traffic at ATS Storage and Loadout Area (IA 060)Paved RoadsEmissions calculated using equation in January 2011 AP-42 Section 13.2.1, Paved Roads.E =k(sL)0.91x (W)1.02x (1-P/4N)Variable Description PMPM10PM2.5Referencek = particle size multiplier 0.011 0.0022 0.00054 from AP-42 Table 13.2.1-1sL =Road surface silt loading, g/m2, annual average10 10 10 MPCA default factorW = Average weight (tons) of the vehicles traveling the road 27.5 27.5 27.5 Engineering estimateP = days per year with at least 0.254 mm precipitation 110 110 110 Estimated from AP-42 Figure 13.2.1-2N = number of days in the averaging period 365 365 365Emission Factor = Emission Factor (lb/vehicle miles traveled (VMT)) 2.429 0.486 0.119ActivityAnnualThroughputTrucked(tons/yr)TruckCapacity(tons)Number ofTrucks perYearMilesTraveled perTruckMileage(VMT)PMEmissions(tons/year)PM10Emissions(tons/year)PM2.5Emissions(tons/year)ATS Loadout 148,803 25 5,952 1.00 5,952 7.23 1.45 0.35Total Paved Road Truck Traffic Emissions7.23 1.45 0.35Maximum Hourly EmissionsActivityMaximumHourlyThroughputTrucked(tons/hr)TruckCapacity(tons)Number ofTrucks perHourMilesTraveled perTruckMileage(VMT)PMEmissions(lb/hr)PM10Emissions(lb/hr)PM2.5Emissions(lb/hr)ATS Loadout 200 25 8 1.00 8.00 19.43 3.89 0.95Total Paved Road Truck Traffic Emissions19.43 3.89 0.95AppendixA,Attachment1‐1

# Attachment 1: Table 14

Incremental Emissions Increase for Sulfur Degassing System (Storage and Loading, MPCA GP115)

Incremental H2S Emissions from TK505 & 526

Tanks 505 and 526 store product sulfur at the facility. Sulfur degassing, inherent to the process, is done to reduce H2S
content in the sulfur and meet a maximum product specification of 50 ppm H2S. To calculate H2S emissions from sulfur storage t anks,
a site-specific correlation developed in 2005 is utilized which relates the lb/day H2S emissions per TPD sulfur. This correlat ion
equation is as follows consistent with the April 2010 approved modeling protocol: 

### lb/day H2S per TPD = 0.0008 x Sulfur Tank H2S content

Sulfur tank H2S content Product spec for H2S concentration in sulfur product = 50 ppm H2S

TPD Sulfur Incremental Operating Rate Sulfur processing rate during baseline period: 889 long tons S/da y Projected actual sulfur processing rate: 960 long tons S/da y Increased sulfur processing rate: 71 Units: long tons S/da y (EU45002: 45 SRU and EU26001: 26 SRU) 79.9 tons S/da y

Total incremental operating rate (tons S/day) 79.9 TPD

H2S Emissions Increase

lb/day H2S = 3.2 from TK505 & TK526 tpy H2S = 0.6 from TK505 & TK526

H2S Emissions from Sulfur Rail Loading

H2S PTE Unrestricted H2S PTE

(lb/day) (tpy) Rail Loading 3.2 0.6

H2S PTE Unrestricted H2S/TRS/RSC PTE

(lb/hr) (tpy)

GP 115 0.3 1.2 The unrestricted PTE calculation for sulfur rail loading very conservatively assumes the same emissions as the sulfur tanks, wh ich may overstate the emissions because some of the tank emissions were released prior to rail loading.



### Appendix A, Attachment 1

‐ 1

## Attachment 2: Table 1

Change in Potential to Emit for Sulfur Recovery Units

26 Unit (SV 042)

Pollutant Increase (lb/hr) Comments

NO X 

### 0 Emissions are proportional to firing rate, which will not change as part of the Project.

SO 2 

### 0 No changes proposed to 1-hr, 3-hr, 24-hr, and annual emissions limits contained in Title V permit.
CO 0 No changes proposed to annual emissions limit contained in Title V permit. PM 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.

PM 10 

### 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.

PM 2.5 

### 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.
VOC 0 Emissions are proportional to firing rate, which will not change as part of the Project. SAM 0 Emissions are proportional to SO2 emissions, which will not change as part of the Project.

H 2 

### S 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project.
TRS 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project. RSC 0.37 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.16 lb/LT factor.

Pb 0 Emissions are proportional to firing rate, which will not change as part of the Project.

CO 2 

### 0 No increase in the maximum sour gas feed rate to the SRUs as a result of the Project.

CH 4 

### 0 No change because emissions are proportional to firing rate, which will not change as part of the Project.

N 2 

### O 0 No change because emissions are proportional to firing rate, which will not change as part of the Project.
GHG 0 No increase in the maximum sour gas feed rate to the SRUs as a result of the Project. Formaldehyde 0.00027 Increase calculated based upon increase in sulfur processing rate (62 STD) and 1.05E-04 lb/ST increase. Acetaldehyde 0.00010 Increase calculated based upon increase in sulfur processing rate (62 STD) and 3.86E-05 lb/ST increase. Carbon Disulfide 0.28 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.12 lb/LT factor. Carbonyl Sulfide 0.09 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.04 lb/LT factor. Cyanide Compounds 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project.

45 Unit (SV 093)

Pollutant Increase (lb/hr) Comments

NO X 

### 0 Emissions are proportional to firing rate, which will not change as part of the Project.

SO 2 

### 0 No changes proposed to 1-hr, 3-hr, 24-hr, and annual emissions limits contained in Title V permit.
CO 0 No changes proposed to annual emissions limit contained in Title V permit. PM 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.

PM 10 

### 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.

PM 2.5 

### 0.60 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.26 lb/LT factor.
VOC 0 Emissions are proportional to firing rate, which will not change as part of the Project. SAM 0 Emissions are proportional to SO2 emissions, which will not change as part of the Project.

H 2 

### S 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project.
TRS 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project. RSC 0.37 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.16 lb/LT factor.

Pb 0 Emissions are proportional to firing rate, which will not change as part of the Project.

CO 2 

### 0 No increase in the maximum sour gas feed rate to the SRUs as a result of the Project.

CH 4 

### 0 No change because emissions are proportional to firing rate, which will not change as part of the Project.

N 2 

### O 0 No change because emissions are proportional to firing rate, which will not change as part of the Project.
GHG 0 No increase in the maximum sour gas feed rate to the SRUs as a result of the Project. Formaldehyde 0.00027 Increase calculated based upon increase in sulfur processing rate (62 STD) and 1.05E-04 lb/ST increase. Acetaldehyde 0.00010 Increase calculated based upon increase in sulfur processing rate (62 STD) and 3.86E-05 lb/ST increase. Carbon Disulfide 0.28 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.12 lb/LT factor. Carbonyl Sulfide 0.09 Increase calculated based upon increase in sulfur processing rate (55 LTD) and 0.04 lb/LT factor. Cyanide Compounds 0 No increase in the maximum tail gas exhaust rate from the SRUs as a result of the Project.

To be clear, there is no physical change occurring in the 26 or 45 SRUs. This potential change in capacity is as a result of t he expected change in overall feed composition. The units individually always have had the ability to run in this manner. Thus, this is more a change in pr oduction capability than an actual change in physical design capacity. This estimated change in sulfur production capability also does not reflect other p otential constraints within the units that may preclude reaching those levels.

### Attachment 2: Table 2

General Emissions Calculation Form for SRU #5 (26 Unit)

This form is based off of the historical MPCA Form EC-01. Shaded cells indicate changes in values from the current representation in the Title V permit. This table updates the values for the overall unit. Refer to Attachment 2: Table 1 for changes specific to the Tier 3 Clean Fue ls Projects.

Use this form to calculate actual emissions for processes or units that cannot be accounted for in the process/unit specific em ission calculation forms. Duplicate this form as necessary to identify all emission units, or attach sheets with equivalent information.

1a) AQD Facility ID No.: 03700011 1b) AQ File No.: 2) Facility Name: Flint Hills Resources, LP 3) Emission Unit Identification No.: EU-26UNIT_1 SRU #5 (MPCA EU 045), EU-26ME22 SRU #5 Sulfur Pit (MPCA EU 045, 047) 4) Stack/Vent Designation No.: SV-26H21 (MPCA SV 042) 5) Pollution control equipment identification number(s): CE-26H40, CE-26H21 (MPCA CE-008, CE-009) 6) Process Type: Batch Process Continuous Process 7) Operating capacity: 580 Units: long tons S/day

650 tons S/day

78.8 MMBtu/hr 8) Source of emission factors used in table below: 9) Calculation summary:
9a) 9b) 9c) 9d) 9e) 9f) 9g) 9h) 9i)

Maximum Actual Pollution Maximum Limited Actual

Pollutant Emission Emission Uncontrolled Uncontrolled Control Controlled Controlled Controlled
Factor Rate Emissions Emissions Efficiency Emissions Emissions Emissions
(lbs/MMBtu or ton) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)

PM 2 0.26 6.28 27.52 N A 0.00% 27.52 N A N A

PM 10 2 0.26 6.28 27.52 NA 0.00% 27.52 NA NA

PM 2.5 2 0.26 6.28 27.52 NA 0.00% 27.52 NA NA

SO

x 3 188 5,089 22,288 NA 95.60% 981 409.8 NA

NOx 4 0.122 9.61 42.11 N A 0.00% 42.11 N A N A

VOC 2 0.005 0.42 1.86 N A 0.00% 1.86 N A N A

CO 5 1.089 26.3 115.3 N A 0.00% 115.3 121 N A

Lead 2 4.90E-07 3.86E-05 1.69E-04 N A 0.00% 1.69E-04 N A N A

H 2 S 6 NA 1.28 5.6 NA 0.00% 5.6 NA NA

1 The maximum heater dut y for the purpose of calculatin g potential air emissions for SRU #5 is based on the combined maximum dut y for the tail g as treatment unit incinerator (H41) at a maximum heater duty of 36.8 MMBtu/hr and the by-pass incinerator (H21) at a maximum heater duty o f 42.0 MMBtu/hr.

2 Conservative estimate; two times H y perion's 2011 value.

3 This emission factor represents the lb SO2 per Lton of sulfur produced and was derived based on the past actual SRU #5 avera g e stack flow rate and sulfur production rate. Controlled SO2 emissions assume a 95.6 percent control efficiency at the TGTU, which is equal to a 99.8 percent control efficiency for the SRU unit collectively (Claus Unit + TGTU).

4 Emission factor and potential lb/hr emissions for NOx are based on a BACT limit in the Title V Permit.

5 Potential CO emissions were derived based on an en g ineerin g estimate of actual CO emissions from results of actual stack test data. This emission factor represents the lb CO per Lton of sulfur produced and was derived based on the past actual SRU#5 average stack flow rate and s ulfur production rate and assumes an emission rate of 100 ppmv CO.

6 1.28 lb/hr emission rate based on the approved April 2010 H2S modelin g protocol. Annual emissions are based on continuous operation.

10) Check all of the following that are appropriate: This process/unit combusts fuel. Include fuel combustion emissions on Form EC-02 (boilers), EC-03 (Internal Combustion Engines), or EC-08 (Ovens, Dryers, Furnaces), as appropriate. This process/unit uses clean-up solvents in addition to the process described by the emissions above. Include clean-up

solvent emissions on Form EC-12 This process/unit emits Hazardous Air Pollutants (HAPs). Include HAP emissions on Form EC-13A (VOC HAPs), EC-13B ( Particulate HAPs), or EC-13C (Combustion HAPs), as appropriate

11) Operating limitations, if applicable:

### Attachment 2: Table 3

Hazardous Air Pollutants Calculation Form for SRU #5 (26 Unit)

This form is based off of the historical MPCA Form EC-13a.
Shaded cells indicate changes in values from the current representation in the Title V permit.
This table updates the values for the overall unit. Refer to Attachment 2: Table 1 for changes specific to the Tier 3 Clean Fue ls Projects.

-Duplicate this form as necessary, or attach sheets with equivalent information
-Instructions begin on Page 4. 1) AQD Facility ID No.: 03700011 2) Facility Name: Flint Hills Resources, LP 3) Emission Unit Identification No.: EU-26UNIT_1 SRU #5, EU-26ME22 SRU #5 Sulfur Pit (MPCA EU 045, 047) 4) Stack/Vent Designation No.: SV-26H21 (MPCA SV 042) 5) Control Equipment Designation Number: CE-26H40, CE-26H21 (MPCA CE-008, CE-009) Complete item 6 or 7, not both

6) Calculations Summary using Material Content: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 6. )
6a) 6b) 6c) 6d) 6e) 6f) 6g) 6h)

Volatile HAP Name (CAS) Maximum HAP

Content Maximum
Material Usage

Rate Maximum

Uncontrolled

HAP Emission

Rate Maximum

Uncontrolled

HAP Emissions Pollution Control
Efficiency Maximum

Controlled HAP

Emissions Actual HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
Not Applicable

Actual Emissions
6a) 6i) 6j) 6k) 6l) 6f) 6m)

Volatile HAP Name (CAS) Actual HAP

Content Actual Material
Usage Rate Actual

Uncontrolled

HAP Emission

Rate Actual

Uncontrolled

HAP Emissions Pollution Control
Efficiency Actual

Controlled HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr)

7) Calculations Summary using Emission Factors: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 7. )
7a) 7b) 7c) 7d) 7e) 7f) 7g) 7h)
Volatile HAP Name (CAS) Maximum

Emission

Factor1 Maximum Hourly

Production or

Material Use Maximum

HAP Emission

Rate Maximum

Uncontrolled

HAP

Emissions Pollution Control
Efficiency Maximum

Controlled HAP

Emissions Actual

HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
(lb/short ton S) (short ton S/day) Formaldehyde (50-00-0) 1.05E-04 649.6 2.84E-03 1.24E-02 Acetaldehyde (75-07-0) 3.86E-05 649.6 1.04E-03 4.58E-03 (lb/long ton S) (long ton S/day) Carbon Disulfide (75-15-0) 1.20E-01 580.0 2.90E+00 1.27E+01 Carbonyl Sulfide (463-58-1) 4.00E-02 580.0 9.67E-01 4.23E+00 (lb/scf tail gas) (scf tail gas/hr) Cyanide Compounds (not Na or K) 7.10E-11 2.2E+06 1.5E-04 6.7E-04

7a) 7i) 7j) 7k) 7l) 7f) 7m)
Volatile HAP Name (CAS) Actual Emission

Factor Actual Hourly

Production or

Material Use A ctual HAP

Emission

Rate Actual

Uncontrolled

HAP

Emissions Pollution Control
Efficiency Actual

Controlled HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr)

8) Operating Limitations, if applicable: (ignore this item if using form for Registration Permit Option D).

### Attachment 2: Table 4

General Emissions Calculation Form for SRU #5 (26 Unit)

This form is based off of the historical MPCA Form EC-01.

Use this form to calculate actual emissions for processes or units that cannot be accounted for in the process/unit specific em ission calculation forms.
Duplicate this form as necessary to identify all emission units, or attach sheets with equivalent information.

1a) AQD Facility ID No.: 03700011 1b) AQ File No.:
2) Facility Name: Flint Hills Resources, LP
3) Emission Unit Identification No.: EU-45UNIT2_1 SRU #3, EU-45ME114A SRU #3 Sulfur Pit, EU-45UNIT3_1 SRU #4,
EU-45ME210A SRU #4 Sulfur Pit (MPCA EU 111, 112, 113, 114)
4) Stack/Vent Designation No.: SV-45H61 (MPCA SV 093)
5) Pollution control equipment identification number(s): CE-45H 7, CE-45H61, CE-45H6, CE-45CVS001, CE-45CVS002(MPCA CE-016 - CE- 020)
6) Process Type: Batch Process Continuous Process
7) Operating capacity: 595 Units: long tons S/day

666 tons S/day

75.0 MMBtu/hr
8) Source of emission factors used in table below:
9) Calculation summary:
9a) 9b) 9c) 9d) 9e) 9f) 9g) 9h) 9i)

Maximum Actual Pollution Maximum Limited Actual

Pollutant Emission Emission Uncontrolled Uncontrolled Control Controlled Controlled Controlled
Factor Rate Emissions Emissions Efficiency Emissions Emissions Emissions
(lbs/MMBtu or ton) (lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)

PM 2 0.26 6.45 28.23 NA 0.00% 28.23 NA NA

PM 10 2 0.26 6.45 28.23 NA 0.00% 28.23 NA NA

PM 2.5 2 0.26 6.45 28.23 NA 0.00% 28.23 NA NA

SO

x 3 188 5,220 22,864 NA 95.60% 1006 324.3 NA

NOx 2 0.275 20.59 90.17 NA 0.00% 90.2 NA NA

VOC 2 0.005 0.40 1.77 NA 0.00% 1.77 NA NA

CO 5 6.1 152.0 665.9 NA 0.00% 666 NA NA

Lead 2 4.90E-07 3.68E-05 1.61E-04 NA 0.00% 1.61E-04 NA NA

H 2 S 6 NA 1.61 7.1 NA 0.00% 7.1 NA NA

1 The maximum heater duty for the purpose of calculating potential air emissions for SRU #3/SRU#4 is based on the combined maximu m duty for the tail gas treatment
unit incinerator (H8) at a maximum heater duty of 30.0 MMBtu/hr and the SRU#4 by-pass incinerator (H61) at a maximum heater d uty of 45.0 MMBtu/hr.

2 Conservative estimate; two times Hyperion's 2011 value.

3 This emission factor represents the lb SO2 per Lton of sulfur produced and was derived based on the past actual SRU#5 average stack flow rate
and sulfur production rate . Controlled SO2 emissions assume a 95.6 percent control efficiency at the TGTU, which is equal to a 99.8 percent control
efficiency for the SRU unit collectively (Claus Unit + TGTU).

5 Potential CO emissions were derived based on an engineering estimate of actual CO emissions from results of actual stack test data. This emission factor
represents the lb CO per Lton of sulfur produced and was derived based on the past actual SRU#5 average stack flow rate and s ulfur production rate
and assumes an emission rate of 100 ppmv CO.

6 1.61 lb/hr emission rate based on the approved April 2010 H2S modeling protocol. A nnual emissions are based on continuous operation.

10) Check all of the following that are appropriate:
This process/unit combusts fuel. Include fuel combustion emissions on Form EC-02 (boilers), EC-03 (Internal
Combustion Engines), or EC-08 (Ovens, Dryers, Furnaces), as appropriate.
This process/unit uses clean-up solvents in addition to the process described by the emissions above. Include clean-up

solvent emissions on Form EC-12
This process/unit emits Hazardous Air Pollutants (HAPs). Include HAP emissions on Form EC-13A (VOC HAPs), EC-13B (
Particulate HAPs), or EC-13C (Combustion HAPs), as appropriate

11) Operating limitations, if applicable:

### Attachment 2: Table 5

Hazardous Air Pollutants Calculation Form for SRU #5 (26 Unit)

This form is based off of the historical MPCA Form EC-13a.

-Duplicate this form as necessary, or attach sheets with equivalent information -Instructions begin on Page 4. 1) AQD Facility ID No.: 03700011 2) Facility Name: Flint Hills Resources, LP 3) Emission Unit Identification No.: EU-45UNIT2_1 SRU #3, EU-45ME114A SRU #3 Sulfur Pit, EU-45UNIT3_1 SRU #4, EU-45ME210A SRU #4 Sulfur Pit (MPCA EU 111, 113, 112,114) 4) Stack/Vent Designation No.: SV-45H61 (MPCA SV 093) 5) Control Equipment Designation Number: CE-45H7, CE-45H61, CE-45H6, CE-45CVS001, CE-45CVS002(MPCA CE-016 - CE-020) Complete item 6 or 7, not both 6) Calculations Summary using Material Content: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 6.)
6a) 6b) 6c) 6d) 6e) 6f) 6g) 6h)

Volatile HAP Name (CAS) Maximum HAP

Content Maximum
Material Usage

Rate Maximum

Uncontrolled

HAP Emission

Rate Maximum

Uncontrolled

HAP Emissions Pollution

Control
Efficiency Maximum

Controlled HAP

Emissions Actual HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
Not Applicabl e

Actual Emissions
6a) 6i) 6j) 6k) 6l) 6f) 6m)

Volatile HAP Name (CAS) Actual HAP

Content Actual Material
Usage Rate Actual

Uncontrolled

HAP Emission

Rate Actual

Uncontrolled

HAP Emissions Pollution

Control
Efficiency Actual

Controlled HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr)

7) Calculations Summary using Emission Factors: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 7.)
7a) 7b) 7c) 7d) 7e) 7f) 7g) 7h)
Volatile HAP Name (CAS) Maximum

Emission

Factor1 Maximum
Hourly

Production or

Material Use Maximum

HAP Emission

Rate Maximum

Uncontrolled

HAP

Emissions Pollution

Control
Efficiency Maximum

Controlled HAP

Emissions A ctual

HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
(lbshort ton S) (short ton S/day) Formaldehyde (50-00-0) 1.05E-04 666.4 2.92E-03 1.28E-02 Acetaldehyde (75-07-0) 3.86E-05 666.4 1.07E-03 4.69E-03 (lb/long ton S) (long ton S/day) Carbon Disulfide (75-15-0) 1.20E-01 595.0 2.98E+00 1.30E+01 Carbonyl Sulfide (463-58-1) 4.00E-02 595.0 9.92E-01 4.34E+00 (lb/scf tail gas) (scf tail gas/hr) Cyanide Compounds (not Na or K) 7.10E-11 1.7E+06 1.2E-04 5.4E-04

7a) 7i) 7j) 7k) 7l) 7f) 7m)
Volatile HAP Name (CAS) Actual Emission

Factor Actual Hourly

Production or

Material Use Actual HAP

Emission Rate Actual

Uncontrolled

HAP

Emissions Pollution

Control
Efficiency Actual

Controlled HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr)

8) Operating Limitations, if applicable: (ignore this item if using form for Registration Permit Option D).3a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 7.66 33.53 33.53 4.50 19.71 19.71 1.74 7.60 7.60GP TKS 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00FS 48UNIT 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.004)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 33.53 33.53 19.71 19.71 7.60 7.605) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.Unrestricted Unrestricted Unrestricted33.53 19.71 7.600.00 0.00 0.00Potential Potential Potential33.53 19.71 7.600.00 0.00 0.00UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per HrPotential Potential Potential3d) Pollutant Name: NOX Pollutant Name: SO2 Pollutant Name: CO3c) CAS#: CAS#: CAS#:3e) 3e) 3e)aq-f1-gi07 • 10/17/13Page793a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 0.48 2.11 2.11 1.35 5.89 5.89 1.35 5.89 5.89GP TKS 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00FS 48UNIT 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.004)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 2.11 2.11 5.89 5.89 5.89 5.895) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.Unrestricted Unrestricted Unrestricted2.11 5.89 5.890.00 0.00 0.00Potential Potential Potential2.11 5.89 5.890.00 0.00 0.00UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per Hr3e) 3e) 3e)Potential Potential Potential3d) Pollutant Name: PM Pollutant Name: PM10 Pollutant Name: PM2.53c) CAS#: CAS#: CAS#:aq-f1-gi07 • 10/17/13Page803a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 0.45 1.97 1.97 0.31 1.38 1.38 2.15E-05 9.41E-05 9.41E-05GP TKS 8.43 28.00 28.00 0.07 0.31 0.31 0.00E+00 0.00E+00 0.00E+00FS 48UNIT 0.19 0.82 0.82 0.03 0.14 0.14 0.00E+00 0.00E+00 0.00E+004)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 30.79 30.79 1.83 1.83 9.41E-05 9.41E-055) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.Unrestricted Unrestricted Unrestricted39.74 1.83 9.41E-050.82 0.14 0.00E+00Potential Potential Potential1.97 1.38 9.41E-0536.94 0.31 0.00E+00UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per Hr3e) 3e) 3e)Potential Potential Potential3d) Pollutant Name: VOC Pollutant Name: H2S Pollutant Name: Pb3c) CAS#: CAS#: CAS#:aq-f1-gi07 • 10/17/13Page813a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 0.01 0.05 0.05 0.05 0.31 1.38 1.38 9.48E-01 4.15E+00 4.15E+00GP TKS 0.00 0.00 0.00 0.00 0.14 0.59 0.59 7.11E-02 3.11E-01 3.11E-01FS 48UNIT 0.00 0.00 0.00 0.00 0.03 0.14 0.14 3.21E-02 1.41E-01 1.41E-014)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 0.05 0.05 2.11 2.11 4.60E+00 4.60E+005) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.0.05 2.11 4.60E+00Potential Potential PotentialUnrestricted Unrestricted Unrestricted1.38 4.15E+000.59 3.11E-010.14 1.41E-01UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per Hr3e) 3e) 3e)Potential Potential Potential3d) Pollutant Name: SAM Pollutant Name: TRS Pollutant Name: RSC3c) CAS#: CAS#: CAS#:aq-f1-gi07 • 10/17/13Page823a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 7533 32994 32994 0.00 0.00 0.00 4.75E-01 2.08E+00 2.08E+00GP TKS 0 0 0 0.00 0.00 0.00 0.00E+00 0.00E+00 0.00E+00FS 48UNIT 5 23 23 0.00 0.00 0.00 0.00E+00 0.00E+00 0.00E+004)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 33017 33017 0.000 0.00 2.08E+00 2.08E+005) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.Unrestricted Unrestricted Unrestricted33017 4.42E-05 2.08E+0023 4.42E-05 0.00E+00Potential Potential Potential32994 0.00E+00 2.08E+000 0.00E+00 0.00E+00UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per Hr3e) 3e) 3e)Potential Potential Potential3d) Pollutant Name: GHGe Pollutant Name: Benzene Pollutant Name: Carbon Disulfide3c) CAS#: CAS#: CAS#:aq-f1-gi07 • 10/17/13Page833a) 3b)Emission EmissionSource Source 3f) 3f) 3f)Type ID No. Actual Actual ActualLimited Limited Limitedtpy tpy tpyEU ATS 1.58E-01 6.94E-01 6.94E-01 0.00E+00 0.00E+00 0.00E+00GP TKS 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00FS 48UNIT 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+004)Actual Actual ActualTotal Limited Tons/year Limited Tons/year Limited Tons/yearFacility 6.94E-01 6.94E-01 0.00E+00 0.00E+00 0.00E+00 0.00E+005) Application is being submitted on acompact disc (CD), and the editable calculation spreadsheet(s) are included on the CD.(see file “Tier 3 Emission Calculations.xlsx”)Application is being submitted on paper only, so editable calculation spreadsheet(s) will be e-mailed to the MPCA upon requestor are includedon an enclosed CD.Unrestricted Unrestricted Unrestricted6.94E-01 0.00E+00 0.00E+000.00E+00 0.00E+00 0.00E+00Potential Potential Potential6.94E-01 0.00E+000.00E+00 0.00E+00 0.00E+00UnrestrictedTons per yr Lbs per HrUnrestrictedTons per yrtpy tpy tpyLbs per HrUnrestrictedTons per yr Lbs per Hr3e) 3e) 3e)Potential Potential Potential3d) Pollutant Name: Carbonyl Sulfide Pollutant Name: Pollutant Name:3c) CAS#: CAS#: CAS#:aq-f1-gi07 • 10/17/13Page84

# EC-08

Facility Emissions Summary

Air Quality Permit Program



### Instructions on Page 2

1a) AQ Facility ID No.: 

### 03700011 1b) AQ File No.: 

### 106A

2) Facility Name: 

### Flint Hills Resources Pine Bend Refinery

Items 3a) through f) see EC forms by unit

4) Facility Summary 

### Emissions reflect new equipment installed.

Maximum Limited Actual

Uncontrolled Controlled Controlled

Emissions Emissions Emissions
(tons/yr) (tons/yr) (tons/yr)



### Criteria 2.11 2.11 NA

Criteria 5.89 5.89 NA

Criteria 5.89 5.89 NA

Criteria 19.71 19.71 NA

Criteria 33.53 33.53 NA

Criteria 30.79 30.79 NA

Criteria 7.60 7.60 NA

Criteria 9.41E-05 9.41E-05 NA

Criteria 1.83 1.83 NA

Criteria 2.11 2.11 NA

Criteria 4.60 4.60 NA

GHG 32,970 32,970 NA

GHG 1.35 1.35 NA

GHG 0.04 0.04 NA

GHG 0 0 NA

GHG 0 0 NA

GHG 0 0 NA

GHG 33,017 33,017 NA

HAP 

### 4.42E-05 0.000 NA

HAP 

### 2.08 2.08 NA

HAP 

### 0.69 0.69 NA

HAP 

### 2.77 2.77 NA Total HAP Carbonyl Sulfide TRS

RSC

CO 2 CH 4
N 2 O

HFCs

PFCs

SF 6 Total GHG (CO 2 e)

Benzene

Carbon Disulfide H 2 S Doc Type: Permit Application

Pollutant
Category Pollutant ID

PM

PM 10
PM 2.5 SO 2 NO

x VOC

CO

Lead

Form aq-f1-gi07 (version 2/29/2012) 

### Page 85General Emissions Calculation Form for ATS Process Unit (EU ATS)This form is based off of the historical MPCA Form EC-01.Use this form to calculate actual emissions for processes orunits that cannot be accounted for in the process/unit specific emission calculation forms.Duplicate this form as necessary to identify all emission units, or attach sheetswith equivalent information.1a) AQD Facility ID No.: 03700011 1b) AQ File No.:2) Facility Name: Flint Hills Resources, LP3) Emission Unit Identification No.: (EU 361): ATS Process Unit4) Stack/Vent Designation No.: (SV 190)5) Pollution control equipment identification number(s): (CE 080)6) Process Type: Batch Process Continuous Process7) Operating capacity: 364 Units: long tons S/day400 tons S/day43.8 MMBtu/hr8) Source of emission factors used in table below:9) Calculation summary:9a) 9b) 9c) 9d) 9e) 9f) 9g) 9h) 9i)Maximum Actual Pollution Maximum Limited ActualPollutant Emission Emission Uncontrolled Uncontrolled Control Controlled Controlled ControlledFactor Rate Emissions Emissions Efficiency Emissions Emissions Emissions(lbs/hr) (tons/yr) (tons/yr) (%) (tons/yr) (tons/yr) (tons/yr)PM 0.01 0.48 21.09 21.09 90% 2.11 2.11 2.11PM100.02 1.35 23.57 23.57 75% 5.89 5.89 5.89PM2.50.02 1.35 6.55 6.55 10% 5.89 5.89 5.89SOx63 0.45 1.97 1.97 0.00% 1.97 1.97 1.97NOx 133 0.01 0.05 0.05 0.00% 0.05 0.05 0.05VOC 20.000 0.31 1.38 1.38 0.00% 1.38 1.38 1.38CO 50.000 0.95 4.15 4.15 0.00% 4.15 4.15 4.15Lead 4.90E-07 0.00 0.00 0.00 0.00% 0.00 0.00 0.00H2S0.080 0.31 1.38 1.38 0.00% 1.38 1.38 1.38Refer to Attachment 1: Table 2for detailed emission calculations.10) Check all of the following that are appropriate:This process/unit combusts fuel. Include fuel combustion emissions on Form EC-02 (boilers), EC-03 (InternalCombustion Engines), or EC-08 (Ovens, Dryers, Furnaces), as appropriate.This process/unit uses clean-up solvents in addition to the process described by the emissions above. Include clean-upsolvent emissions on Form EC-12This process/unit emits Hazardous Air Pollutants (HAPs). Include HAP emissions on Form EC-13A (VOC HAPs), EC-13B (Particulate HAPs), or EC-13C (Combustion HAPs), as appropriate11) Operating limitations, if applicable:Page87Hazardous Air Pollutants Calculation Form for ATS Process Unit (EU ATS)

This form is based off of the historical MPCA Form EC-13a.

-Duplicate this form as necessary, or attach sheets with equivalent information -Instructions begin on Page 4. 1) AQD Facility ID No.: 03700011 2) Facility Name: Flint Hills Resources, LP 3) Emission Unit Identification No.: EU 361 4) Stack/Vent Designation No.: SV 190 5) Control Equipment Designation Number: CE 080 Complete item 6 or 7, not both

6) Calculations Summary using Material Content: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 6.)
6a) 6b) 6c) 6d) 6e) 6f) 6g) 6h)

Volatile HAP Name (CAS) Maximum HAP

Content Maximum
Material Usage

Rate Maximum

Uncontrolled

HAP Emission

Rate Maximum

Uncontrolled

HAP Emissions Pollution

Control
Efficiency Maximum

Controlled HAP

Emissions Actual HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
Not Applicable

Actual Emissions
6a) 6i) 6j) 6k) 6l) 6f) 6m)

Volatile HAP Name (CAS) Actual HAP

Content Actual Material
Usage Rate Actual

Uncontrolled

HAP Emission

Rate Actual

Uncontrolled

HAP Emissions Pollution

Control
Efficiency Actual

Controlled HAP

Emissions

(lb/MMGal) (gal/hr) (lbs/hr) (tons/yr) (%) (tons/yr)

7) Calculations Summary using Emission Factors: Potential Emissions (Do not complete this table if using this form for Registration Permit Option D. Go to Actual Emissions Table in item 7.)
7a) 7b) 7c) 7d) 7e) 7f) 7g) 7h)
Volatile HAP Name (CAS) Maximum

Emission

Factor1 Maximum Hourly

Production or

Material Use Maximum

HAP Emission

Rate Maximum

Uncontrolled

HAP

Emissions Pollution

Control
Efficiency Maximum

Controlled HAP

Emissions Actual

HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr) (tons/yr)
lb/LT (short ton S/day)

Carbon Disulfide 1.20E-01 9.50E+01 4.75E-01 2.08E+00 Carbonyl Sulfide 4.00E-02 9.50E+01 1.58E-01 6.94E-01

lb/MMBtu mmbtu/hr Arsenic Compounds 1.96E-07 4.38E+01 8.59E-06 3.76E-05

Benzene 2.06E-06 4.38E+01 9.02E-05 3.95E-04 Beryllium Compounds 1.18E-08 4.38E+01 5.16E-07 2.26E-06 Cadmium Compounds 1.08E-06 4.38E+01 4.73E-05 2.07E-04 Chromium Compounds 1.37E-06 4.38E+01 6.02E-05 2.63E-04

Cobalt Compounds 8.24E-08 4.38E+01 3.61E-06 1.58E-05

Dichlorobenzenes 1.18E-06 4.38E+01 5.16E-05 2.26E-04

Formaldehyde 7.35E-05 4.38E+01 3.22E-03 1.41E-02

Hexane 1.76E-03 4.38E+01 7.73E-02 3.39E-01 Lead Compounds 4.90E-07 4.38E+01 2.15E-05 9.41E-05 Manganese Compounds 3.73E-07 4.38E+01 1.63E-05 7.15E-05

Mercury Compounds 2.55E-07 4.38E+01 1.12E-05 4.89E-05
Naphthalene 5.98E-07 4.38E+01 2.62E-05 1.15E-04 Nickel Compounds 2.06E-06 4.38E+01 9.02E-05 3.95E-04

POM 8.65E-08 4.38E+01 3.79E-06 1.66E-05 Selenium Compounds 2.35E-08 4.38E+01 1.03E-06 4.52E-06

Toluene 3.33E-06 4.38E+01 1.46E-04 6.40E-04

7a) 7i) 7j) 7k) 7l) 7f) 7m)
Volatile HAP Name (CAS) Actual Emission

Factor Actual Hourly

Production or

Material Use A ctual

HAP Emission

Rate Actual

Uncontrolled

HAP

Emissions Pollution

Control
Efficiency Actual

Controlled HAP

Emissions

(lbs/hr) (tons/yr) (%) (tons/yr)

8) Operating Limitations, if applicable: (ignore this item if using form for Registration Permit Option D).

Page 89Greenhouse Gas Emissions Calculation Form for ATS Process Unit (EU ATS)This form is based off of the historical MPCA Form EC-17.7a) 7b) 7c) 7e)EmissionFactorPollutionControlEfficiency(lb/unit) (lb/hr) (tpy)CO2e(tpy)(%) (lb/hr) (tpy)CO2e(tpy)(lb/hr) (tpy)CO2e(tpy)(tpy)CO2e(tpy)CO2112.17E+01 7.53E+03 3.30E+04 3.30E+04 0.00E+00 7.53E+03 3.30E+04 3.30E+04 7.53E+03 3.30E+04 3.30E+043.30E+04 3.30E+04CH42252.20E‐03 9.66E‐02 4.23E‐01 1.06E+01 0.00E+00 9.66E‐02 4.23E‐01 1.06E+01 9.66E‐02 4.23E‐01 1.06E+014.23E‐01 1.06E+01N2O32982.20E‐04 9.66E‐03 4.23E‐02 1.26E+01 0.00E+00 9.66E‐03 4.23E‐02 1.26E+01 9.66E‐03 4.23E‐02 1.26E+014.23E‐02 1.26E+01HFCsX X NA NA NA NA NA NA NA NA NA NA NA NAPFCsX X NA NA NA NA NA NA NA NA NA NA NA NASF623,900NA NA NA NA NA NA NA NA NA NA NA NA NATotalGHG(CO2e)X X X 3.30E+04 X X X 3.30E+04 X X 3.30E+04 X 3.30E+04[1]EmissionfactorsbaseduponcalculationsforSulfurRecoveryUnits.(seeAttachment1:Table9).[2]BasedonEPA'sAP‐42Section1.4fornaturalgasfiring.[3]EmissionFactor=0.003kg/MMBtu*HHV*2.2lb/kgperEquationC‐8of40CFR98(assumeworstcasefactorforfuelgas,Tier3)GHGPollutantGWPUncontrolledEmissionRate ControlledEmissionRateLimitedandControlledEmissionRateActualControlledEmissionRate6)Operating Limitations, if applicable:7)Greenhouse Gas Emissions Summary. Use this table to document GHG emissions from the unit or operation listed above. You must provide mass emissions of each pollutant, aswell as carbon dioxide equivalents (CO2e). For hydroflourocarbons (HFCs) and perfluorocarbons (PFCs), you will have to calculate emissions of individual compounds onthe seperatespreadsheet and report the total HFCs and PFCs in the table below. Instructions are provided starting on page 2. Please report all numbers using three (3) scientific notation ifnecessary (for example, report 379,355 tons as 3.79E5").7d) 7f) 7g) 7h)3)Emisson unit ID number:EU 3614)Stack/Vent designation number(s):SV 1905)Control equipment number(s):CE 0802)Facility Name:Flint Hills Resources, LPUse this form to summarize the potential and actual greenhouse gas (GHG) emissions for each operation contributing to GHG emissions. Continue to use the other emission forms (EC01 though EC-16) as applicable for other regulated air pollutants. Follow the guidance on calculation of greenhouse gas (GHG)emissions. Attach a separate spreadsheet showing allcalculations.1a)AQ Facility ID No.:037000111b)AQ File No.:106APage91

# Attachment 3:

BACT Analysis for PM 10 

# , PM 2.5 

# and GHG

(BACT Analysis labeled Appendix B to the permit application is Attachment 3 to the TSD)

# 


	






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 AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONAKͲ0062 BADAMIDEVELOPMENTFACILITY BPEXPLORATIONALASKA8/19/2005 SOLARMARS90TURBINE 16.11 NATURALGAS 11.86 MW Particulatematter,filterable<10ђ(FPM10)GOODOPERATIONPRACTICES 10 %OPACITY3MINUTESIN1HOURAKͲ0071 INTERNATIONALSTATIONPOWERPLANTCHUGACHELECTRICASSOCIATION,INC.12/20/2010 GELM6000PFͲ25Turbines(4) 15.21 NaturalGas 59900 hpISO Particulatematter,total(TPM)GoodCombustionPractices 0.0066 LB/MMBTU3ͲHOURAVERAGEAKͲ0071 INTERNATIONALSTATIONPOWERPLANTCHUGACHELECTRICASSOCIATION,INC.12/20/2010 GELM6000PFͲ25Turbines(4) 15.21 NaturalGas 59900 hpISO Particulatematter,total<10ђ(TPM10)GoodCombustionPractices 0.0066 LB/MMBTU3ͲHOURAVERAGEAKͲ0071 INTERNATIONALSTATIONPOWERPLANTCHUGACHELECTRICASSOCIATION,INC.12/20/2010 GELM6000PFͲ25Turbines(4) 15.21 NaturalGas 59900 hpISO Particulatematter,total<2.5ђ(TPM2.5)GoodCombustionPractices 0.0066 LB/MMBTU3ͲHOURAVERAGEAKͲ0073 INTERNATIONALSTATIONPOWERPLANTCHUGACHELECTRICASSOCIATION12/20/2010 FuelCombustion 15.21 NaturalGas 59900 HP Particulatematter,filterable<10ђ(FPM10)CombustionTurbinesEUIDs5Ͳ8usegoodcombustionpracticesinvolveincreasingtheresidencetimeandexcessoxygentoensurecompletecombustionwhichinturnminimizeparticulateswithoutanaddͲoncontroltechnology.0.0066 LB/MMBTU3ͲHOURAKͲ0080 ANCHORAGEMUNICIPALLIGHT&POWERMUNICIPALITYOFANCHORAGE6/6/2013 Combustion 16.11 NaturalGas 408 MMBtu/hr Particulatematter,total<2.5ђ(TPM2.5)Goodoperationandcombustionpractices0.0066 LB/MMBTUAKͲ0081 POINTTHOMSONPRODUCTIONFACILITYEXXONMOBILCORPORATION6/12/2013 Combustion 16.11 NaturalGas 7520 kW Particulatematter,total<2.5ђ(TPM2.5)Goodcombustionandoperatingpractices 0.0066 LB/MMBTUALͲ0251 HILLABEEENERGYCENTER CERGENERATION 9/24/2008 COMBUSTIONTURBINE 16.11 NATURALGAS 2142 MMBTU/H Particulatematter,total(TPM)GOODCOMBUSTIONPRACTICES 27.5 LB/HAZͲ0047 WELLTONMOHAWKGENERATINGSTATIONDOMEVALLEYENERGYPARTNERS12/1/2004 COMBUSTIONTURBINEGENERATORSANDHEATRECOVERYSTEAMGENERATORSͲSW501FTURBINESOPTION15.21 NATURALGAS 180 MW Particulatematter,filterable<10ђ(FPM10)33.1 LB/H3ͲHOURAVERAGEAZͲ0047 WELLTONMOHAWKGENERATINGSTATIONDOMEVALLEYENERGYPARTNERS12/1/2004 COMBUSTIONTURBINEGENERATORSANDHEATRECOVERYSTEAMGENERATORSͲGE7FATURBINESOPTION15.21 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)29.8 LB/H3ͲHOURAVERAGECAͲ1143 SUTTERPOWERPLANT CALPINECORPORATION 8/16/2004 2COMBUSTIONTURBINES 15.21 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)11.5 LB/HCAͲ1144 BLYTHEENERGYPROJECTII CAITHNESSBLYTHEII,LLC4/25/2007 2COMBUSTIONTURBINES 15.21 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)USEPUBLICUTILITYCOMMISSIONQUALITYNATURALGASW/SULFURCONTENTLESSTHANOREQUALTO0.5GRAINSPER100SCF6 LB/HCAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#2(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total(TPM)PUCQUALITYNATURALGAS 12 LB/H12ͲMONTHROLLINGAVG(NODUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#2(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total<2.5ђ(TPM2.5)PUCQUALITYNATURALGAS 12 LB/HPUCQUALITYNATURALGASCAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#2(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total(TPM)PUCQUALITYNATURALGAS 18 LB/H12ͲMONTHROLLINGAVG(W/DUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#2(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total<2.5ђ(TPM2.5)PUCQUALITYNATURALGAS 18 LB/H12ͲMONTHROLLINGAVG(W/DUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#1(NORMALOPERATION,NODUCTBURNING)15.21 NaturalGas 154 MW Particulatematter,total(TPM)PUCQUALITYNATURALGAS 12 LB/H12ͲMONTHROLLINGAVG(NODUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#1(NORMALOPERATION,NODUCTBURNING)15.21 NaturalGas 154 MW Particulatematter,total<2.5ђ(TPM2.5)PUCQUALITYNATURALGAS 12 LB/H12ͲMONTHROLLINGAVG(NODUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#1(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 18 LB/H12ͲMONTHROLLINGAVG(W/DUCTBURNING)CAͲ1191 VICTORVILLE2HYBRIDPOWERPROJECTCITYOFVICTORVILLE 3/11/2010 COMBUSTIONTURBINE#1(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 154 MW Particulatematter,total<2.5ђ(TPM2.5)PUCQUALITYNATURALGAS 18 LB/H12ͲMONTHROLLINGAVG(W/DUCTBURNING)Page1of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#1(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 8.91 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#1(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPUCQUALITYNATURALGAS 8.91 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#1(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 11.78 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#1(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPUCQUALITYNATURALGAS 11.78 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#2(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 8.91 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#2(NORMALOPERATION,NODUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPUCQUALITYNATURALGAS 8.91 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#2(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 11.78 LB/H12ͲMONTHROLLINGAVGCAͲ1192 AVENALENERGYPROJECT AVENALPOWERCENTERLLC6/21/2011 COMBUSTIONTURBINE#2(NORMALOPERATION,WITHDUCTBURNING)15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPUCQUALITYNATURALGAS 11.78 LB/H12ͲMONTHROLLINGAVGCAͲ1198 MORROBAYPOWERPLANT DYNERGYMORROBAYLLC9/25/2008 COMBUSTIONTURBINEGENERATOR 15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPIPELINEQUALITYNATURALGAS,OPERATEDUCTBURNERSNOMORETHAN4000HRSPERYEAR(12ͲMONTHROLLINGAVGBASIS)11 LB/H6ͲHRROLLINGAVG(NODUCTBURNING)CAͲ1198 MORROBAYPOWERPLANT DYNERGYMORROBAYLLC9/25/2008 COMBUSTIONTURBINEGENERATOR 15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPIPELINEQUALITYNATURALGAS,OPERATEDUCTBURNERSNOMORETHAN4000HRSPERYEAR(12ͲMONTHROLLINGAVGBASIS)11 LB/H6ͲHRROLLINGAVG(NODUCTBURNING)CAͲ1198 MORROBAYPOWERPLANT DYNERGYMORROBAYLLC9/25/2008 COMBUSTIONTURBINEGENERATOR 15.21 NATURALGAS 180 MW Particulatematter,total<10ђ(TPM10)USEPIPELINEQUALITYNATURALGAS,OPERATEDUCTBURNERSNOMORETHAN4000HRSPERYEAR(12ͲMONTHROLLINGAVGBASIS)11 LB/H6ͲHRROLLINGAVG(NODUCTBURNING)CAͲ1198 MORROBAYPOWERPLANT DYNERGYMORROBAYLLC9/25/2008 COMBUSTIONTURBINEGENERATOR 15.21 NATURALGAS 180 MW Particulatematter,total(TPM)USEPIPELINEQUALITYNATURALGAS,OPERATEDUCTBURNERSNOMORETHAN4000HRSPERYEAR(12ͲMONTHROLLINGAVGBASIS)11 LB/H6ͲHRROLLINGAVG(NODUCTBURNING)CAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(WARMSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total(TPM)USENATURALGAS 12 LB/HWARMSTARTUPPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(WARMSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)USENATURALGAS 12 LB/HWARMSTARTUPPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(HOTSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total(TPM)USENATURALGAS 12 LB/HHOTSTARTUPPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(HOTSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)USENATURALGAS 12 LB/HHOTSTARTUPPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(SHUTDOWNPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total(TPM)USENATURALGAS 6 LB/HTURBINESHUTDOWNPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(SHUTDOWNPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)USENATURALGAS 6 LB/HTURBINESHUTDOWNPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)USENATURALGAS 13.5 LB/HSTACKTESTCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 172 MW Particulatematter,filterable(FPM)USENATURALGAS 13.5 LB/HSTACKTESTCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(COLDSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,filterable(FPM)USENATURALGAS 12 LB/HCOLDSTARTUPPERIODSCAͲ1211 COLUSAGENERATINGSTATION PACIFICGAS&ELECTRICCOMPANY3/11/2011 COMBUSTIONTURBINES(COLDSTARTUPPERIODS)15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)USENATURALGAS 12 LB/HCOLDSTARTUPPERIODSCAͲ1212 PALMDALEHYBRIDPOWERPROJECT CITYOFPALMDALE 10/18/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 154 MW Particulatematter,total(TPM)USEPUCQUALITYNATURALGAS 0.0048 LB/MMBTU9ͲHRAVG(NODUCTBURNING)CAͲ1212 PALMDALEHYBRIDPOWERPROJECT CITYOFPALMDALE 10/18/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 154 MW Particulatematter,total<10ђ(TPM10)USEPUCQUALITYNATURALGAS 0.0048 LB/MMBTU9ͲHRAVG(NODUCTBURNING)Page2of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONCAͲ1212 PALMDALEHYBRIDPOWERPROJECT CITYOFPALMDALE 10/18/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 154 MW Particulatematter,total<2.5ђ(TPM2.5)USEPUCQUALITYNATURALGAS 0.0048 LB/MMBTU9ͲHRAVG(NODUCTBURNING)CAͲ1223 PIOPICOENERGYCENTER PIOPICOENERGYCENTER,LLC11/19/2012 COMBUSTIONTURBINES(NORMALOPERATION)15.11 NATURALGAS 300 MW Particulatematter,total(TPM)PUCͲQUALITYNATURALGAS 0.0065 LB/MMBTU(HHV)ATLOADSOF80%ORHIGHERCAͲ1223 PIOPICOENERGYCENTER PIOPICOENERGYCENTER,LLC11/19/2012 COMBUSTIONTURBINES(NORMALOPERATION)15.11 NATURALGAS 300 MW Particulatematter,total<10ђ(TPM10)PUCͲQUALITYNATURALGAS 0.0065 LB/MMBTU(HHV)ATLOADSOF80%ORHIGHERCAͲ1223 PIOPICOENERGYCENTER PIOPICOENERGYCENTER,LLC11/19/2012 COMBUSTIONTURBINES(NORMALOPERATION)15.11 NATURALGAS 300 MW Particulatematter,filterable<2.5ђ(FPM2.5)PUCͲQUALITYNATURALGAS 0.0065 LB/MMBTU(HHV)ATLOADSOF80%ORHIGHERCOͲ0056 ROCKYMOUNTAINENERGYCENTER,LLCCALPINECORP. 5/2/2006 NATURALͲGASFIRED,COMBINEDͲCYCLETURBINE15.21 NATURALGAS 300 MW Particulatematter,filterable<10ђ(FPM10)NATURALGASQUALITYFUELONLYANDGOODCOMBUSTIONCONTROLPRACTICES.0.0074 LB/MMBTUCOͲ0064 RAWHIDEENERGYSTATION PLATTERIVERPOWERAUTHORITY8/31/2007 UNITFCOMBUSTIONTURBINE 15.11 NATURALGAS 1400 MMBTU/H ParticulateMatter(PM)USEOFPIPELINEQUALITYNATURALGAS 18 LB/HCOͲ0064 RAWHIDEENERGYSTATION PLATTERIVERPOWERAUTHORITY8/31/2007 UNITFCOMBUSTIONTURBINE 15.11 NATURALGAS 1400 MMBTU/H Particulatematter,filterable<10ђ(FPM10)USEOFPIPELINEQUALITYNATURALGAS. 18 LB/HCTͲ0151 KLEENENERGYSYSTEMS,LLC KLEENENERGYSYSTEMS,LLC2/25/2008 SIEMENSSGT6Ͳ5000FCOMBUSTIONTURBINE#1AND#2(NATURALGASFIRED)WITH445MMBTU/HRNATURALGASDUCTBURNER15.21 NATURALGAS 2.1 MMCF/H Particulatematter,filterable<10ђ(FPM10)11 LB/HW/OUTDUCTBURNERDEͲ0024 GARRISONENERGYCENTER GARRISONENERGYCENTER,LLC/CALPINECORPORATION1/30/2013 Unit1 15.21 NaturalGas 2260 millionBTUs Particulatematter,total(TPM)FuelUsageRestrictiontonaturalgasandlowsulfurdistillateoil120.4 TONS12MONTHROLLINGAVERAGEFLͲ0261 ARVAHB.HOPKINSGENERATINGSTATIONCITYOFTALLAHASSEE 10/26/2004 TURBINE,SIMPLECYCLE,NATURALGAS,(2)15.11 NATURALGAS 50 mw Particulatematter,filterable<10ђ(FPM10)CLEANFUELS 2.45 LB/HFLͲ0263 FPLTURKEYPOINTPOWERPLANT FLORIDAPOWERANDLIGHT2/8/2005 170MWCOMBUSTIONTURBINE,4UNITS15.21 NATURALGAS 170 MW ParticulateMatter(PM)PM/PM10WILLBEMINIMIZEDBYTHEEFFICIENTCOMBUSTIONOFNATURALGASANDDISTILLATEOILATHIGHTEMPERATURES.0SEENOTEFLͲ0265 HINESPOWERBLOCK4 PROGRESSENERGY 6/8/2005 COMBINEDCYCLETURBINE 15.21 NATURALGAS 530 MW Particulatematter,filterable<10ђ(FPM10)CLEANFUELS 10 %OPACITY6MIMBLOCKAVERAGEFLͲ0266 PAYNECREEKGENERATINGSTATION/SEMINOLEELECTRICSEMINOLEELECTRICCOMPANY6/29/2005 SIMPLECYCLECOMBUSTIONTURBINES16.11 NATURALGAS 30 MW Particulatematter,filterable<10ђ(FPM10)CLEANFUELS 10 %OPACITY6MINUTESAVERAGEFLͲ0279 TEC/POLKPOWERENERGYSTATION TAMPAELECTRICCOMPANY(TEC)4/28/2006 SIMPLECYCLEGASTURBINE 15.11 NATURALGAS 1834 MMBTU/H Particulatematter,filterable<10ђ(FPM10)FIRINGOFNATURALGASGOODCOMBUSTIONPRACTICES10 %OPACITYFLͲ0280 TREASURECOASTENERGYCENTER FLORIDAMUNICIPALPOWERAGENCY5/30/2006 COMBINEDCYCLECOMBUSTIONTURBINE15.2 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)FUELSPECIFICATIONS 2 GRAINSS/100SCFNATURALGASSPECIFICATIONFLͲ0286 FPLWESTCOUNTYENERGYCENTER FLORIDAPOWERANDLIGHTCOMPANY1/10/2007 COMBINEDCYCLECOMBUSTIONGASTURBINESͲ6UNITS15.21 NATURALGAS 2333 MMBTU/H Particulatematter,filterable<10ђ(FPM10)2 GS/100SCFGASFLͲ0287 OLEANDERPOWERPROJECT OLEANDERPOWERPROJECT,L.P11/17/2006 SIMPLECYCLECOMBUSTIONTURBINE 15.11 NATURALGAS 190 MW Particulatematter,filterable<10ђ(FPM10)CLEANFUELS 1.5 GRS/100SCFNATURALGASFLͲ0300 JACKSONVILLEELECTRICAUTHORITY/JEAJACKSONVILLEELECTRICAUTHORITY12/22/2006 SIMPLECYCLETURBINE172MW 15.11 NATURALGAS 1804 MMBTU/H Particulatematter,filterable<10ђ(FPM10)NATURALGASASPRIMARYFUELWITH0.05%SULFURDISTILLATEFUELOILASBACKUP.USEWATERINJECTIONWHENFIRINGOIL0SEENOTEFLͲ0303 FPLWESTCOUNTYENERGYCENTERUNIT3FLORIDAPOWERANDLIGHTCOMPANY(FP&L)7/30/2008 THREENOMINAL250MWCTG(EACH)WITHSUPPLEMENTARYͲFIREDHRSG15.21 NATURALGAS 2333 MMBTU/H ParticulateMatter(PM)2 GR/100SCFGASFLͲ0304 CANEISLANDPOWERPARK FLORIDAMUNICIPALPOWERAGENCY(FMPA9/8/2008 300MWCOMBINEDCYCLECOMBUSTIONTURBINE15.21 NATURALGAS 1860 MMBTU/H Particulatematter,total<10ђ(TPM10)FUELSPECIFICATIONS:2GRS/100SCFOFGAS2 GRS/100SCFGASFLͲ0305 OUCCURTISH.STANTONENERGYCENTERORLANDOUTILITIESCOMMISSION(OUC)5/12/2008 300MWCOMBINEDCYCLECOMBUSTIONTURBINE15.11 NATURALGAS 1765 MMBTU/H Particulatematter,total<10ђ(TPM10)NATURALGASANULTRALOWSULFURFUELOIL2 GRS/100DSCFOFGASFLͲ0310 SHADYHILLSGENERATINGSTATION SHADYHILLSPOWERCOMPANY1/12/2009 TWOSIMPLECYCLECOMBUSTIONTURBINEͲMODEL7FA15.11 NATURALGAS 170 MW Particulatematter,total<10ђ(TPM10)10 %OPACITY6ͲMINUTEBLOCKBYEPAMETHOD9Page3of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITION*FLͲ0337 POLKPOWERSTATION TAMPAELECTRICCOMPANY10/14/2012 Combinecyclepowerblock(4on1) 15.21 naturalgas 1160 MW Particulatematter,filterable<10ђ(FPM10)2 GRS/100SCFOFGASGAͲ0139 DAHLBERGCOMBUSDTIONTURBINEELECTRICGENERATINGFACILITY(PSOUTHERNPOWERCOMPANY5/14/2010 SIMPLECYCLECOMBUSTIONTURBINEͲELECTRICGENERATINGPLANT15.11 NATURALGASE1530 MW Particulatematter,total<10ђ(TPM10)GOODCOMBUSTIONPRACTICESPIPELINEQUALITYNATURALGAS,ULTRALOWSULFURDISTILLATEFUEL9.1 LB/H3HOURAVERAGE/CONDITION3.3.23IDͲ0018 LANGLEYGULCHPOWERPLANT IDAHOPOWERCOMPANY6/25/2010 COMBUSTIONTURBINE,COMBINEDCYCLEW/DUCTBURNER15.21 NATURALGAS(ONLY)2375.28 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICES(GCP) 0SEENOTE*ILͲ0112 NELSONENERGYCENTER INVENERGYNELSON,LLC12/28/2010 ElectricGenerationFacility 15.21 NaturalGas 220 MWeeach Particulatematter,total<10ђ(TPM10)0.012 LB/MMBTUHOURLYAVERAGE*ILͲ0112 NELSONENERGYCENTER INVENERGYNELSON,LLC12/28/2010 ElectricGenerationFacility 15.21 NaturalGas 220 MWeeach Particulatematter,total<2.5ђ(TPM2.5)0.006 LB/MMBTUHOURLYAVERAGE*INͲ0158 ST.JOSEPHENEGRYCENTER,LLC ST.JOSEPHENERGYCENTER,LLC12/3/2012 FOUR(4)NATURALGASCOMBINEDCYCLECOMBUSTIONTURBINES15.21 NATURALGAS 2300 MMBTU/H Particulatematter,filterable(FPM)GOODCUMBUSTIONPRACTICEANDFUELSPECIFICATION18 LB/H3HOURS*INͲ0158 ST.JOSEPHENEGRYCENTER,LLC ST.JOSEPHENERGYCENTER,LLC12/3/2012 FOUR(4)NATURALGASCOMBINEDCYCLECOMBUSTIONTURBINES15.21 NATURALGAS 2300 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCUMBUSTIONPRACTICEANDFUELSPECIFICATION18 LB/H3HOURS*INͲ0158 ST.JOSEPHENEGRYCENTER,LLC ST.JOSEPHENERGYCENTER,LLC12/3/2012 FOUR(4)NATURALGASCOMBINEDCYCLECOMBUSTIONTURBINES15.21 NATURALGAS 2300 MMBTU/H Particulatematter,filterable<2.5ђ(FPM2.5)GOODCOMBUSTIONPRACTICEANDFUELSPECIFICATION18 LB/H3HOURSKSͲ0028 NEARMANCREEKPOWERSTATION KANSASCITYBOARDOFPUBLICUTILITIES10/18/2005 COMBUSTIONTURBINE#4FACILITY 15.1 NATURALGAS 955 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICES/DESIGN 10 LB/HFIRINGNATURALGASATFULLLOADLAͲ0136 PLAQUEMINECOGENERATIONFACILITYTHEDOWCHEMICALCOMPANY7/23/2008 (4)GASTURBINES/DUCTBURNERS 15.21 NATURALGAS 2876 MMBTU/H Particulatematter,filterable<10ђ(FPM10)USEOFCLEANBURNINGFUELS 33.5 LB/HHOURLYMAXIMUMLAͲ0224 ARSENALHILLPOWERPLANT SOUTHWESTELECTRICPOWERCOMPANY(SWEPCO)3/20/2008 TWOCOMBINEDCYCLEGASTURBINES 15.21 NATURALGAS 2110 MMBTU/H ParticulateMatter(PM)GOODCOMBUSTIONDESIGN/PROPEROPERATINGPRACTICES/PIPELINEQUALITYNATURALGASASFUEL24.23 LB/HMAXLAͲ0254 NINEMILEPOINTELECTRICGENERATINGPLANTENTERGYLOUISIANALLC8/16/2011 COMBINEDCYCLETURBINEGENERATORS(UNITS6A&6B)15.21 NATURALGAS 7146 MMBTU/H Particulatematter,total<2.5ђ(TPM2.5)WHILEFIRINGNATURALGAS:USEOFPIPELINEQUALITYNATURALGASANDGOODCOMBUSTIONPRACTICESWHILEFIRINGFUELOIL:USEOFULTRALOWSULFURFUELOILANDGOODCOMBUSTIONPRACTICES26.23 LB/HHOURLYAVERAGEW/ODUCTBURNERLAͲ0254 NINEMILEPOINTELECTRICGENERATINGPLANTENTERGYLOUISIANALLC8/16/2011 COMBINEDCYCLETURBINEGENERATORS(UNITS6A&6B)15.21 NATURALGAS 7146 MMBTU/H Particulatematter,total<10ђ(TPM10)WHILEFIRINGNATURALGAS:USEOFPIPELINEQUALITYNATURALGASANDGOODCOMBUSTIONPRACTICESWHILEFIRINGFUELOIL:USEOFULTRALOWSULFURFUELOILANDGOODCOMBUSTIONPRACTICES26.23 LB/HHOURLYAVERAGEW/ODUCTBURNERLAͲ0256 COGENERATIONPLANT WESTLAKEVINYLSCOMPANYLP12/6/2011 COGENERATIONTRAINS1Ͳ3(1Ͳ10,2Ͳ10,3Ͳ10)15.21 NATURALGAS 475 MMBTU/H TotalSuspendedParticulatesUSEOFNATURALGASASFUELANDGOODCOMBUSTIONPRACTICES3.72 LB/HHOURLYMAXIMUMLAͲ0256 COGENERATIONPLANT WESTLAKEVINYLSCOMPANYLP12/6/2011 COGENERATIONTRAINS1Ͳ3(1Ͳ10,2Ͳ10,3Ͳ10)15.21 NATURALGAS 475 MMBTU/H Particulatematter,total<10ђ(TPM10)USEOFNATURALGASASFUELANDGOODCOMBUSTIONPRACTICES3.72 LB/HHOURLYMAXIMUMLAͲ0256 COGENERATIONPLANT WESTLAKEVINYLSCOMPANYLP12/6/2011 COGENERATIONTRAINS1Ͳ3(1Ͳ10,2Ͳ10,3Ͳ10)15.21 NATURALGAS 475 MMBTU/H Particulatematter,total<2.5ђ(TPM2.5)USEOFNATURALGASASFUELANDGOODCOMBUSTIONPRACTICES3.72 LB/HHOURLYMAXIMUMLAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 SimpleCycleRefrigerationCompressorTurbines(16)15.11 NaturalGas 286 MMBTU/H Particulatematter,total(TPM)Goodcombustionpracticesandfueledbynaturalgas2.08 LB/HHOURLYMAXIMUMLAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 CombinedCycleRefrigerationCompressorTurbines(8)15.21 naturalgas 286 MMBTU/H Particulatematter,total(TPM)Goodcombustionpracticesandfueledbynaturalgas2.08 LB/HHOURLYMAXIMUMLAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 SimpleCycleGenerationTurbines(2) 15.11 NaturalGas 286 MMBTU/H Particulatematter,total(TPM)Goodcombustionpracticesandfueledbynaturalgas2.08 LB/HHOURLYMAXIMUMLAͲ0258 CALCASIEUPLANT ENTERGYGULFSTATESLALLC12/21/2011 TURBINEEXHAUSTSTACKNO.1&NO.215.11 NATURALGAS 1900 MMBTU/HEACHParticulatematter,total<2.5ђ(TPM2.5)USEOFPIPELINENATURALGAS 17 LB/HHOURLYMAXIMUMPage4of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONLAͲ0258 CALCASIEUPLANT ENTERGYGULFSTATESLALLC12/21/2011 TURBINEEXHAUSTSTACKNO.1&NO.215.11 NATURALGAS 1900 MMBTU/HEACHParticulatematter,total<10ђ(TPM10)USEOFPIPELINENATURALGAS 17 LB/HHOURLYMAXIMUMMAͲ0035 THOMASH.WATSONGENERATINGSTATIONBRAINTREEELECTRICLIGHTDEPARTMENT4/4/2008 SIMPLEͲCYCLEGASTURBINE 15.19 NATURALGAS 9519 BTU/KWͲH Particulatematter,total<10ђ(TPM10)0.02 LB/MMBTU1ͲHOURMAͲ0037 CENTRALHEATINGPLANT:AMHERSTCAMPUSUNIVERSITYOFMASSACHUSETTSBUILDINGAUTHORITY10/29/2008 COMBUSTIONTURBINE 16.2 NATURALGAS 137 MMBTU/H Particulatematter,total<10ђ(TPM10)0.03 LB/MMBTU1ͲHOURMDͲ0031 CHALKPOINT MIRANTMIDͲATLANTIC,LLC4/1/2005 GE7EACOMBUSTIONTURBINEͲNG,SCONLY15.1 NATURALGAS 85 MW Particulatematter,filterable<10ђ(FPM10)USEOFLOWSULFURFUELS 5 LB/H3ͲHRAVGFIRINGNATURALGASMDͲ0032 DICKERSON MIRANTMIDͲATLANTIC,LLC11/05/2004 ESTUNIT4ͲGEFRAME7FCOMB.TURBINESW/HRSGͲNGCC15.21 NATURALGAS 196 MW Particulatematter,filterable<10ђ(FPM10)26 LB/H3ͲHRAVGFIRINGNGW/DBINCOMB.CYCLEMDͲ0032 DICKERSON MIRANTMIDͲATLANTIC,LLC11/05/2004 ESTUNIT4ͲGEFRAME7FCOM.TURBINESW/HRSGͲNGSC15.11 NATURALGAS 196 MW Particulatematter,filterable<10ђ(FPM10)21 LB/H3HRAVGFIRINGNGW/ODBINSIMP.CYCLEMDͲ0032 DICKERSON MIRANTMIDͲATLANTIC,LLC11/05/2004 ESTUNIT5ͲGEFRAME7FCOMB.TURBINESW/HRSGͲNGCC15.21 NATURALGAS 196 MW Particulatematter,filterable<10ђ(FPM10)15 LB/H3ͲHRAVGFIRINGNGW/DBINCOMBCYCLEMDͲ0035 DOMINION DOMINIONCOVEPOINTLNG,L.P.8/12/2005 COMBUSTIONTURBINE 16.11 NATURALGAS ParticulateMatter(PM)0.0066 LB/MMBTUMDͲ0036 DOMINION DOMINIONCOVEPOINTLNG,L.P.3/10/2006 COMBUSTIONTURBINE 16.11 NATURALGAS Particulatematter,filterable<10ђ(FPM10)USEOFLNGQUALITY,LOWSULFURNATURALGAS0.0066 LB/MMBTU3ͲHOURAVERAGEMDͲ0040 CPVSTCHARLES COMPETITIVEPOWERVENTURES,INC./CPVMARYLAND,LLC11/12/2008 COMBUSTIONTURBINES(2) 15.11 NATURALGAS ParticulateMatter(PM)0.012 LB/MMBTU@15%O23ͲHRAVERAGEMDͲ0040 CPVSTCHARLES COMPETITIVEPOWERVENTURES,INC./CPVMARYLAND,LLC11/12/2008 COMBUSTIONTURBINES(2) 15.11 NATURALGAS Particulatematter,filterable<10ђ(FPM10)0.012 LB/MMBTU@15%O23ͲHRAVERAGEMDͲ0040 CPVSTCHARLES COMPETITIVEPOWERVENTURES,INC./CPVMARYLAND,LLC11/12/2008 COMBUSTIONTURBINES(2) 15.11 NATURALGAS Particulatematter,filterable<2.5ђ(FPM2.5)0.012 LB/MMBTU@15%O23ͲHRAVERAGEMIͲ0327 INDECKͲNILES,LLC INDECKENERGY 4/21/2004 4GASTURBINESWITHHEATRECOVERYSTEAMGENERATORS15.11 NATURALGAS 163 MW Particulatematter,filterable<10ђ(FPM10)USEOFNATURALGAS. 8.5 LB/H24ͲHOURROLLINGAVGMIͲ0366 BERRIENENERGY,LLC BERRIENENERGY,LLC 4/13/2005 3COMBUSTIONTURBINESANDDUCTBURNERS15.21 NATURALGAS 1584 MMBTU/H Particulatematter,filterable<10ђ(FPM10)STATEOFTHEARTCOMBUSTIONTECHNIQUESANDUSEOFNATURALGASAREBACTFORPM10.19 LB/H*MIͲ0402 SUMPTERPOWERPLANT WOLVERINEPOWERSUPPLYCOOPERATIVEINC.11/17/2011 Combinedcyclecombustionturbinew/HRSG15.21 Naturalgas 130 MWelectricaloutputParticulatematter,total<10ђ(TPM10)0.0066 LB/MMBTUTEST*MIͲ0402 SUMPTERPOWERPLANT WOLVERINEPOWERSUPPLYCOOPERATIVEINC.11/17/2011 Combinedcyclecombustionturbinew/HRSG15.21 Naturalgas 130 MWelectricaloutputParticulatematter,total<2.5ђ(TPM2.5)0.0066 LB/MMBTUTEST*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSG15.21 Naturalgas 2237 MMBtu/hour Particulatematter,total(TPM)Goodcombustionpractices 0.006 LB/MMBTUEACHCTG;TESTPROTOCOL*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSG15.21 Naturalgas 2237 MMBtu/hour Particulatematter,total<10ђ(TPM10)Goodcombustionpractices 0.006 LB/MMBTUEACHCTG;TESTPROTOCOL*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSG15.21 Naturalgas 2237 MMBtu/hour Particulatematter,total<2.5ђ(TPM2.5)Goodcombustionpractices 0.006 LB/MMBTUEACHCTG;TESTPROTOCOL*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSGandductburner(DB)15.21 Naturalgas 2486 MMBTU/H Particulatematter,total(TPM)Goodcombustionpractices 0.004 LB/MMBTUTESTPROTOCOL*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSGandductburner(DB)15.21 Naturalgas 2486 MMBTU/H Particulatematter,total<10ђ(TPM10)Goodcombustionpractices 0.008 LB/MMBTUTESTPROTOCOLPage5of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITION*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSGandductburner(DB)15.21 Naturalgas 2486 MMBTU/H Particulatematter,total<2.5ђ(TPM2.5)Goodcombustionpractices 0.008 LB/MMBTUTESTPROTOCOLMNͲ0053 FAIRBAULTENERGYPARK MNMUNICIPALPOWERAGENCY7/15/2004 TURBINE,SIMPLECYCLE,NATURALGAS(1)15.11 NATURALGAS 1663 MMBTU/H Particulatematter,filterable<10ђ(FPM10)CLEANFUELANDGOODCOMBUSTIONPRACTICES.0.01 LB/MMBTU3HOURAVERAGEMNͲ0053 FAIRBAULTENERGYPARK MNMUNICIPALPOWERAGENCY7/15/2004 TURBINE,COMBINEDCYCLE,NATURALGAS(1)15.21 NATURALGAS 1876 MMBTU/H ParticulateMatter(PM)CLEANFUELANDGOODCOMBUSTIONPRACTICES.0.01 LB/MMBTU3HOURAVERAGEMNͲ0071 FAIRBAULTENERGYPARK MINNESOTAMUNICIPALPOWERAGENCY6/5/2007 COMBINEDCYCLECOMBUSTIONTURBINEW/DUCTBURNER15.21 NATURALGAS 1758 MMBTU/H Particulatematter,filterable<10ђ(FPM10)0.01 LB/MMBTUCTGNGORCTG&DBNGMNͲ0075 GREATRIVERENERGYͲELKRIVERSTATIONGREATRIVERENERGY 7/1/2008 COMBUSTIONTURBINEGENERATOR 15.11 NATURALGAS 2169 MMBTU/H Particulatematter,filterable<10ђ(FPM10)FUELLIMITEDTONATURALGASANDULTRAͲLOWSULFURFUELOIL0SEENOTEMNͲ0075 GREATRIVERENERGYͲELKRIVERSTATIONGREATRIVERENERGY 7/1/2008 COMBUSTIONTURBINEGENERATOR 15.11 NATURALGAS 2169 MMBTU/H ParticulateMatter(PM)FUELLIMITEDTONATURALGASANDULTRAͲLOWSULFURFUELOIL0SEENOTEMNͲ0075 GREATRIVERENERGYͲELKRIVERSTATIONGREATRIVERENERGY 7/1/2008 COMBUSTIONTURBINEGENERATOR 15.11 NATURALGAS 2169 MMBTU/H Particulatematter,filterable<10ђ(FPM10)FUELLIMITEDTONATURALGASANDULTRAͲLOWSULFURFUELOIL0SEENOTEMOͲ0067 SOUTHHARPERPEAKINGFACILITY AQUILA,INC. 12/29/2004 TURBINES,SIMPLECYCLE,NATURALGAS,(3)15.11 NATURALGAS 1455 mmBtu/h Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICES 15.25 LB/HSEENOTESMSͲ0072 TVAͲKEMPERCOMBUSTIONTURBINEPLANT12/10/2004 EMISSIONPOINTAAͲ001 15.11 NATURALGAS ParticulateMatter(PM)7.35 LB/HNATURALGASMSͲ0072 TVAͲKEMPERCOMBUSTIONTURBINEPLANT12/10/2004 EMISSIONPOINTAAͲ002 15.11 NATURALGAS ParticulateMatter(PM)7.35 LB/HMSͲ0072 TVAͲKEMPERCOMBUSTIONTURBINEPLANT12/10/2004 EMISSIONPOINTAAͲ003 15.11 NATURALGAS ParticulateMatter(PM)7.35 LB/HNATURALGASMSͲ0072 TVAͲKEMPERCOMBUSTIONTURBINEPLANT12/10/2004 EMISSIONPOINTAAͲ004 15.11 NATURALGAS ParticulateMatter(PM)7.35 LB/HNATURALGASMSͲ0073 RELIANTENERGYCHOCTAWCOUNTY,LLC11/23/2004 EMISSIONPOINTAAͲ001GEN.ELEC.COMBUST.TURBINE15.21 NATURALGAS 230 MW Particulatematter,filterable<10ђ(FPM10)20.59 LB/HMSͲ0074 MOSELLEPLANT SOUTHMISSISSIPPIELECTRICPOWERASSOCIATION12/10/2004 COMBUSTIONTURBINE,GASͲFIRED,SIMPLEͲCYCLE15.11 NATURALGAS 1143.3 MMBTU/H Particulatematter,filterable<10ђ(FPM10)10 LB/HNCͲ0101 FORSYTHENERGYPLANT FORSYTHENERGYPROJECTS,LLC9/29/2005 TURBINE,COMBINEDCYCLE,NATURALGAS,(3)15.21 NATURALGAS 1844.3 MMBTU/H Particulatematter,filterable<10ђ(FPM10)USEOFONLYCLEANͲBURNINGLOWͲSULFURFUELSANDGOODCOMBUSTIONPRACTICES.0.019 LB/MMBTUbasedon3ͲhouraverageNCͲ0101 FORSYTHENERGYPLANT FORSYTHENERGYPROJECTS,LLC9/29/2005 TURBINE&DUCTBURNER,COMBINEDCYCLE,NATGAS,315.21 NATURALGAS 1844.3 MMBTU/H Particulatematter,filterable<10ђ(FPM10)CLEANBURNINGLOWͲSULFURFUELSANDGOODCOMBUSTIONPRACTICES0.021 LB/MMBTU3Ͳhravg*NDͲ0028 R.M.HESKETTSTATION MONTANAͲDAKOTAUTILITIESCO.2/22/2013 CombustionTurbine 15.11 Naturalgas 986 MMBtu/hr Particulatematter,total<10ђ(TPM10)GoodCombustionPractices 7.3 LB/HAVERAGEOF3TESTRUNS*NDͲ0028 R.M.HESKETTSTATION MONTANAͲDAKOTAUTILITIESCO.2/22/2013 CombustionTurbine 15.11 Naturalgas 986 MMBtu/hr Particulatematter,total<2.5ђ(TPM2.5)Goodcombustionpractices. 7.3 LB/HAVERAGEOFTHREETESTRUNS*NDͲ0029 PIONEERGENERATINGSTATION BASINELECTRICPOWERCOOPERATIVE5/14/2013 NaturalgasͲfiredturbines 15.11 Naturalgas 451 MMBtu/hr Particulatematter,total<2.5ђ(TPM2.5)5.4 LB1HOUR*NDͲ0030 LONESOMECREEKGENERATINGSTATIONBASINELECTRICPOWERCOOP.9/16/2013 NaturalGasFiredSimpleCycleTurbines15.11 Naturalgas 412 MMBtu/hr Particulatematter,total<2.5ђ(TPM2.5)5 LB/HAVERAGEOFTHREETESTRUNSNEͲ0021 CASSCOUNTYPOWERPLANT OmahaPublicPower 6/22/2004 2Ͳ173MWCOMBUSTIONTURBINES 15.11 NATURALGAS 173 MW Particulatematter,filterable<2.5ђ(FPM2.5)0.12 LB/MMBTUNEͲ0022 C.W.BURDICKGENERATINGSTATION GrandIslandUtilities 6/22/2004 GASͲFIREDCOMBUSTIONTURBINE 15.11 NATURALGAS 1 MILLIONSCF/HParticulatematter,filterable<10ђ(FPM10)LOWASHCONTENTNG 10 LB/HNJͲ0066 AESREDOAKLLC AESREDOAKLLC 2/16/2006 COMBINEDCYCLENATURALGASFIREDCOMBUSTIONTURBINES(3)15.2 NATURALGAS 63122 MMSCF/YR TotalSuspendedParticulatesTHEUSEOFONLYNATURALGAS,ACLEANBURNINGFUELISCONSIDEREDBACT.29.43 LB/HPage6of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONNJͲ0066 AESREDOAKLLC AESREDOAKLLC 2/16/2006 COMBINEDCYCLENATURALGASFIREDCOMBUSTIONTURBINES(3)15.2 NATURALGAS 63122 MMSCF/YR Particulatematter,filterable<10ђ(FPM10)THEUSEOFONLYNATURALGAS,ACLEANBURNINGFUELISCONSIDEREDBACT.29.43 LB/HNJͲ0074 WESTDEPTFORDENERGY LSPOWER 5/6/2009 TURBINE,COMBINEDCYCLE 15.2 NATURALGAS 17298 MMFT3/YR Particulatematter,filterable<10ђ(FPM10)CLEANFUELSͲNATURALGASANDULTRALOWSULFUR(15PPMSULFUR)DISTILLATEOIL18.66 LB/HNJͲ0074 WESTDEPTFORDENERGY LSPOWER 5/6/2009 TURBINE,COMBINEDCYCLE 15.2 NATURALGAS 17298 MMFT3/YR Particulatematter,filterable<2.5ђ(FPM2.5)USEOFCLEANFUELS,NATURALGASANDULTRALOWSULFURDISTILLATEOIL18.66 LB/HNJͲ0075 BAYONNEENERGYCENTER BAYONNEENERGYCENTER,LLC9/24/2009 COMBUSTIONTURBINES,SIMPLECYCLE,ROLLSROYCE,815.11 NATURALGAS 603 MMBTU/H Particulatematter,filterable<10ђ(FPM10)BURNINGCLEANFUELS,NATURALGASANDULTRALOWSULFURDISTILLATEOILWITHSULFURCONTENTOF15PPM.5 LB/HNJͲ0075 BAYONNEENERGYCENTER BAYONNEENERGYCENTER,LLC9/24/2009 COMBUSTIONTURBINES,SIMPLECYCLE,ROLLSROYCE,815.11 NATURALGAS 603 MMBTU/H Particulatematter,filterable<2.5ђ(FPM2.5)BURNINGCLEANFUELS,NATURALGASANDULTRALOWSULFURDISTILLATEOILWITHSULFURCONTENTOF15PPM.5 LB/HNJͲ0076 PSEGFOSSILLLCKEARNYGENERATINGSTATIONPSEGFOSSILLLC 10/27/2010 SIMPLECYCLETURBINE 15.11 NaturalGas 8940000 MMBtu/year(HHV)Particulatematter,total<10ђ(TPM10)Goodcombustionpractice,UseofCleanBurningFuel:Naturalgas6 LB/HAVERAGEOFTHREETESTSNJͲ0076 PSEGFOSSILLLCKEARNYGENERATINGSTATIONPSEGFOSSILLLC 10/27/2010 SIMPLECYCLETURBINE 15.11 NaturalGas 8940000 MMBtu/year(HHV)Particulatematter,total<2.5ђ(TPM2.5)Goodcombustionpractice,UseofCleanBurningFuel:Naturalgas6 LB/HAVERGEOFTHREETESTSNJͲ0076 PSEGFOSSILLLCKEARNYGENERATINGSTATIONPSEGFOSSILLLC 10/27/2010 SIMPLECYCLETURBINE 15.11 NaturalGas 8940000 MMBtu/year(HHV)Particulatematter,filterable(FPM)Goodcombustionpractice,UseofCleanBurningFuel:Naturalgas6 LB/HAVERAGEOFTHREETESTSNJͲ0077 HOWARDDOWNSTATION VINELANDMUNICIPALELECTRICUTILITY(VMEU)9/16/2010 SIMPLECYCLE(NOWASTEHEATRECOVERY)(>25MW)15.11 NATURALGAS 5000 MMFT3/YR Particulatematter,filterable<10ђ(FPM10)USEOFCLEANBURNINGFUELS;NATURALGASASPRIMARYFUELANDULTRALOWSULFURDISTILLATEOILWITH15PPMSULFURBYWEIGHTASBACKUPFUEL5 LB/HAVERAGEOFTHREETESTSNJͲ0077 HOWARDDOWNSTATION VINELANDMUNICIPALELECTRICUTILITY(VMEU)9/16/2010 SIMPLECYCLE(NOWASTEHEATRECOVERY)(>25MW)15.11 NATURALGAS 5000 MMFT3/YR Particulatematter,filterable<2.5ђ(FPM2.5)USEOFCLEANBURNINGFUELS;NATURALGASASPRIMARYFUELANDULTRALOWSULFURDISTILLATEOILWITH15PPMSULFURBYWEIGHTASBACKUPFUEL5 LB/HAVERAGEOFTHREETESTSNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinewithDuctBurner16.21 Naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable(FPM)GoodCombustionPracticesanduseofNaturalgas,acleanburningfuel.8.2 LB/HAVERAGEOFTHREETESTS.NJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinewithDuctBurner16.21 Naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable<10ђ(FPM10)GoodCombustionPracticesanduseofNaturalgas,acleanburningfuel.19.1 LB/HAVERAGEOFTHREETESTSNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinewithDuctBurner16.21 Naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable<2.5ђ(FPM2.5)GoodCombustionPracticesanduseofNaturalgas,acleanburningfuel.19.1 LB/HAVERAGEOFTHREETESTSNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinew/oductburner16.21 naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable(FPM)useofnaturalgasonlywhichisacleanburningfuel4.8 LB/HAVERAGEOFTHREETESTSNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinew/oductburner16.21 naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable<10ђ(FPM10)UseofNaturalgas,acleanburningfuel. 12.1 LB/HAVERAGEOFTHREETESTSNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinew/oductburner16.21 naturalgas 40297.6 mmcubicft/yearParticulatematter,filterable<2.5ђ(FPM2.5)useofnaturalgasonlywhichisacleanburningfuel12.1 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 Combinedcylceturbinewithductburner16.21 naturalgas 39463 mmcubicft/year*Particulatematter,filterable<10ђ(FPM10)Useofnaturalgasacleanburningfuel 13.2 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 Combinedcylceturbinewithductburner16.21 naturalgas 39463 mmcubicft/year*Particulatematter,filterable<2.5ђ(FPM2.5)Useofnaturalgasacleanburningfuel 13.2 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 Combinedcylceturbinewithductburner16.21 naturalgas 39463 mmcubicft/year*Particulatematter,filterable(FPM)Useofnaturalgasacleanburningfuel 7.9 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 CombinedCycleCombustionTurbine 16.21 naturalgas 39463 MMCubicft/yrParticulatematter,filterable(FPM)GoodcombustionPracticesanduseofnaturalgasacleanburningfuel6.6 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 CombinedCycleCombustionTurbine 16.21 naturalgas 39463 MMCubicft/yrParticulatematter,filterable<10ђ(FPM10)Useofnaturalgasacleanburningfuel 11 LB/HAVERAGEOFTHREETESTSNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 CombinedCycleCombustionTurbine 16.21 naturalgas 39463 MMCubicft/yrParticulatematter,filterable<2.5ђ(FPM2.5)UseofNaturalGasacleanburningfuel 11 LB/HAVERAGEOFTHREETESTSPage7of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONNMͲ0051 CUNNINGHAMPOWERPLANT SOUTHWESTERNPUBLICSERVICECO.5/2/2011 NormalMode(withoutPowerAugmentation)15.11 naturalgas 0 Particulatematter,filterable<10ђ(FPM10)GoodCombustionPracticesasdescribedinthepermit.5.4 LB/HHOURLYNMͲ0051 CUNNINGHAMPOWERPLANT SOUTHWESTERNPUBLICSERVICECO.5/2/2011 PowerAugmentation 15.11 naturalgas 0 Particulatematter,filterable<10ђ(FPM10)Goodcombustionpracticesasdefinedinthepermit.5.4 LB/HHOURLYNVͲ0033 ELDORADOENERGY,LLC ELDORADOENERGY,LLC8/19/2004 COMBUSTIONTURBINE,COMBINEDCYCLE&COGEN(2)15.21 NATURALGAS 475 MW Particulatematter,filterable<10ђ(FPM10)9 LB/HForeachCTGNVͲ0035 TRACYSUBSTATIONEXPANSIONPROJECTSIERRAPACIFICPOWERCOMPANY8/16/2005 TURBINE,COMBINEDCYCLECOMBUSTION#2WITHHRSGANDDUCTBURNER.15.21 NATURALGAS 306 MW Particulatematter,filterable<10ђ(FPM10)BESTCOMBUSTIONPRACTICES. 0.011 LB/MMBTU3ͲHOURROLLINGNVͲ0035 TRACYSUBSTATIONEXPANSIONPROJECTSIERRAPACIFICPOWERCOMPANY8/16/2005 TURBINE,COMBINEDCYCLECOMBUSTION#1WITHHRSGANDDUCTBURNER.15.21 NATURALGAS 306 MW Particulatematter,filterable<10ђ(FPM10)BESTCOMBUSTIONPRACTICES. 0.011 LB/MMBTU3ͲHOURROLLINGNVͲ0037 COPPERMOUNTAINPOWER SEMPRAENERGYRESOURCES5/14/2004 LARGECOMBUSTIONTURBINES,COMBINEDCYCLE&COGENERATION15.21 NATURALGAS 600 MW Particulatematter,filterable<10ђ(FPM10)USEOFLOWͲSULFURNATURALGAS 21.3 LB/HNVͲ0046 GOODSPRINGSCOMPRESSORSTATIONKERNRIVERGASTRANSMISSIONCOMPANY5/16/2006 LARGECOMBUSTIONTURBINEͲSIMPLECYCLE15.11 NATURALGAS 97.81 MMBTU/H Particulatematter,filterable<10ђ(FPM10)NATURALGASISTHEONLYFUELFORTHEPROCESS.0.0066 LB/MMBTUNVͲ0048 GOODSPRINGSCOMPRESSORSTATIONKERNRIVERGASTRANSMISSIONCOMPANY5/16/2006 SIMPLEͲCYCLESMALLCOMBUSTIONTURBINES(<25MW)16.11 NATURALGAS 11.5 MW Particulatematter,filterable<10ђ(FPM10)PROPEROPERATIONOFTHETURBINE 0.0066 LB/MMBTUNVͲ0050 MGMMIRAGE MGMMIRAGE 11/30/2009 TURBINEGENERATORSͲUNITSCC007ANDCC008ATCITYCENTER16.11 NATURALGAS 4.6 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICESANDLIMITINGTHEFUELTONATURALGASONLY0.202 LB/MMBTUNYͲ0093 TRIGENͲNASSAUENERGYCORPORATIONTRIGENͲNASSAUENERGYCORPORATION3/31/2005 TURBINE,COMBINEDCYCLE 15.11 NATURALGAS 79.9 mw Particulatematter,filterable<10ђ(FPM10)4.66 LB/H75TO100%TURBINEONLYNYͲ0093 TRIGENͲNASSAUENERGYCORPORATIONTRIGENͲNASSAUENERGYCORPORATION3/31/2005 TURBINE,COMBINEDCYCLE,DUCTBURNER15.11 NATURALGAS 79.9 mw Particulatematter,filterable<10ђ(FPM10)8.42 LB/H1NYͲ0095 CAITHNESBELLPORTENERGYCENTER CAITHNESSBELLPORT,LLC5/10/2006 COMBUSTIONTURBINE 15.21 NATURALGAS 2221 MMBUT/H Particulatematter,filterable<10ђ(FPM10)LOWSULFURFUEL 0.0055 LB/MMBTUNODUCTBURNINGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES2 16.21 NATURALGAS 155 MMBTU/H ParticulateMatter(PM)SULFURINGASASSUMEDMAX.1.2GR/100SCF;WORKPRACTICETOMINIMIZENH3SLIP.3.9 LB/HABOVE/BELOW0F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES2 16.21 NATURALGAS 155 MMBTU/H Particulatematter,filterable<10ђ(FPM10)SULFURINGASASSUMEDMAX1.2GR/100SCF;WORKPRACTICETOMINIMIZENH3SLIP.4.1 LB/HBELOW0F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES2 16.21 NATURALGAS 155 MMBTU/H Particulatematter,filterable<2.5ђ(FPM2.5)SULFURINGASASSUMEDMAX1.2GR/100SCF;WORKPRACTICETOMINIMIZENH3SLIP.3.9 LB/HABOVEO'F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES3 16.21 NATURALGAS 155 MMBTU/H Particulatematter,filterable<10ђ(FPM10)ULTRALOWSULFURDIESELAT15PPM;WORKPRACTICETOMINIMIZENH3SLIP.6.3 LB/HABOVE0'F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES3 16.21 NATURALGAS 155 MMBTU/H Particulatematter,filterable<2.5ђ(FPM2.5)ULTRALOWSULFURDIESELAT15PPM,WORKPRACTICETOMINIMIZENH3SLIP.6.3 LB/HAVOVE0'F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES3 16.21 NATURALGAS 155 MMBTU/H ParticulateMatter(PM)ULTRALOWSULFURDIESELAT15PPM;WORKPRACTICETOMINIMIZENH3SLIP.6.3 LB/HABOVE0'F,1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES1 16.21 NATURALGAS 155 MMBTU/HEACHParticulateMatter(PM)SULFURINGASASSIGNEDMAX1.2GR/100SCF;WORKPRACTICETOMINIMIZENHZSLIP.6.5 LB/HABOV1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES1 16.21 NATURALGAS 155 MMBTU/HEACHParticulatematter,filterable<2.5ђ(FPM2.5)SULFURINGASASSIGNEDMAX1.2GR/100SCF;WORKPRACTICETOMINIMIZENHZSLIP6.7 LB/HABOVE/BELOW1HOURAVGNYͲ0101 CORNELLCOMBINEDHEAT&POWERPROJECTCORNELLUNIVERSITY 3/12/2008 COMBUSTIONTURBINES1 16.21 NATURALGAS 155 MMBTU/HEACHParticulatematter,filterable<10ђ(FPM10)SULFURINGASASSIGNEDMAX1.2GR/100SCF;WORKPRACTICETOMINIMIZENHZSLIP6.7 LB/HABOVE/BELOW1HOURAVGOHͲ0252 DUKEENERGYHANGINGROCKENERGYFACILITYDUKEENERGYHANGINGROCK,LLC12/28/2004 TURBINES(4)(MODELGE7FA),DUCTBURNERSON15.21 NATURALGAS 172 MW Particulatematter,filterable<10ђ(FPM10)23.3 LB/HEACHTURBINEPage8of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONOHͲ0252 DUKEENERGYHANGINGROCKENERGYFACILITYDUKEENERGYHANGINGROCK,LLC12/28/2004 TURBINES(4)(MODELGE7FA),DUCTBURNERSOFF15.21 NATURALGAS 172 MW Particulatematter,filterable<10ђ(FPM10)15 LB/HEACHTURBINEOHͲ0253 DAYTONPOWERANDLIGHTCOMPANYDAYTONPOWERANDLIGHTCOMPANY3/7/2006 COMBUSTIONTURBINE(1),SIMPLECYCLE15.11 NATURALGAS 1115 MMBTU/H Particulatematter,filterable<10ђ(FPM10)8 LB/HFROMNATURALGASOHͲ0253 DAYTONPOWERANDLIGHTCOMPANYDAYTONPOWERANDLIGHTCOMPANY3/7/2006 COMBUSTIONTURBINES(2),SIMPLECYCLE15.11 NATURALGAS 1115 MMBTU/H Particulatematter,filterable<10ђ(FPM10)8 LB/HFROMNATURALGASOHͲ0275 PSIENERGYͲMADISONSTATION CINERGY 8/24/2004 677MWPOWERPLANT,8SIMPLEͲCYCLECOMBTURB,FIREDW/NATGAS15.1 NATURALGAS 84.65 MW Particulatematter,filterable<10ђ(FPM10)LOWASHFUELANDEFFICIENTCOMBUSTION0.008 LB/MMBTUOHͲ0291 OHIOEDISONCO.ͲWESTLORAINPLANTFIRSTENERGY 11/17/2004 SIMPLECYCLECOMBUSTIONTURBINES(5)W/DISTILLATEOIL15.19 NATURALGAS,FUELOIL,KEROSENE85 MW Particulatematter,filterable<10ђ(FPM10)10 LB/HEACHTURBINEOHͲ0291 OHIOEDISONCO.ͲWESTLORAINPLANTFIRSTENERGY 11/17/2004 SIMPLECYCLECOMBUSTIONTURBINES(5)W/NATURALGAS15.11 NATURALGAS,FUELOIL,KEROSENE85 MW Particulatematter,filterable<10ђ(FPM10)5 LB/HEACHTURBINEOHͲ0304 ROLLINGHILLSGENERATINGPLANT ROLLINGHILLSGENERATING,LLC1/17/2006 NATURALGASFIREDTURBINES(5) 15.11 NATURALGAS 209 MW ParticulateMatter(PM)17.3 LB/HOHͲ0304 ROLLINGHILLSGENERATINGPLANT ROLLINGHILLSGENERATING,LLC1/17/2006 NATURALGASFIREDTURBINES(5) 15.11 NATURALGAS 209 MW Particulatematter,filterable<10ђ(FPM10)17.3 LB/HOHͲ0333 DAYTONPOWER&LIGHTENERGYLLC DAYTONPOWER&LIGHTCOMPANY12/3/2009 Turbines(4),simplecycle,naturalgas 15.11 NATURALGAS 15020 H/YR Particulatematter,filterable(FPM)0.013 LB/MMBTUACTUALHEATINPUTOHͲ0333 DAYTONPOWER&LIGHTENERGYLLC DAYTONPOWER&LIGHTCOMPANY12/3/2009 Turbines(4),simplecycle,naturalgas 15.11 NATURALGAS 15020 H/YR Particulatematter,filterable<10ђ(FPM10)0.013 LB/MMBTUACTUALHEATINPUT*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲSiemens,withoutductburners15.21 NaturalGas 515600 MMSCF/rolling12ͲmonthsParticulatematter,total<10ђ(TPM10)cleanburningfuel,onlynaturalgas 13.3 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲSiemens,withductburners15.21 NaturalGas 51560 MMSCF/rolling12ͲMOParticulatematter,total<10ђ(TPM10)cleanburningfuel,onlynaturalgas 14 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲMitsubishi,withoutductburners15.21 NaturalGas 47917 MMSCF/rolling12ͲMOParticulatematter,total<10ђ(TPM10)cleanburningfuel,onlynaturalgas 11.3 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲMitsubishi,withductburners15.21 NaturalGas 47917 MMSCF/rolling12ͲMOParticulatematter,total<10ђ(TPM10)cleanburningfuel,onlynaturalgas 10.1 LB/H*OHͲ0356 DUKEENERGYHANGINGROCKENERGYDUKEENERGYHANGINGROCK,LLC12/18/2012 Turbines(4)(modelGE7FA)DuctBurnersOff15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)Burningnaturalgasinanefficientcombustionturbine15 LB/H*OHͲ0356 DUKEENERGYHANGINGROCKENERGYDUKEENERGYHANGINGROCK,LLC12/18/2012 Turbines(4)(modelGE7FA)DuctBurnersOn15.21 NATURALGAS 172 MW Particulatematter,total<10ђ(TPM10)Burningnaturalgasinanefficientcombustionturbine19.9 LB/HOKͲ0127 WESTERNFARMERSELECTRICANADARKOWESTERNFARMERSELECTRICCOOPERATIVE6/13/2008 COMBUSTIONTURBINEPEAKINGUNIT(S)15.11 NATURALGAS 462.7 MMBTU/H Particulatematter,filterable<10ђ(FPM10)NOCONTROLSFEASIBLE. 4 LB/H2,500HR/YEAROKͲ0129 CHOUTEAUPOWERPLANT ASSOCIATEDELECTRICCOOPERATIVEINC1/23/2009 COMBINEDCYCLECOGENERATION>25MW15.21 NATURALGAS 1882 MMBTU/H Particulatematter,total<10ђ(TPM10)NATURALGASFUEL 6.59 LB/H3ͲHAVGORͲ0041 WANAPAENERGYCENTER DIAMONDWANAPAI,L.P.8/8/2005 COMBUSTIONTURBINE&HEATRECOVERYSTEAMGENERATOR15.21 NATURALGAS 2384.1 MMBTU/H ParticulateMatter(PM)0SEEPOLUTANTNOTEORͲ0043 UMATILLAGENERATINGCOMPANY,L.P.UMATILLAGENERATINGCOMPANY,L.P.5/11/2004 TURBINE,COMBINEDCYCLE&DUCTBURNER,NATGAS(2)15.11 NATURALGAS 2007 MMBTU/H ParticulateMatter(PM)GOODCOMBUSTIONANDFIRINGNATURALGAS0.1 GR/DSCFORͲ0043 UMATILLAGENERATINGCOMPANY,L.P.UMATILLAGENERATINGCOMPANY,L.P.5/11/2004 TURBINE,COMBINEDCYCLE&DUCTBURNER,NATGAS(2)15.11 NATURALGAS 2007 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONANDFIRINGNATURALGAS0.0042 LB/MMBTU3ͲhrblockavgORͲ0048 CARTYPLANT PORTLANDGENERALELECTRIC12/29/2010 COMBINEDCYCLENATURALGASͲFIREDELECTRICGENERATINGUNIT15.21 NATURALGAS 2866 MMBTU/H Particulatematter,filterable<10ђ(FPM10)CLEANFUEL 2.5 LB/MMCFPage9of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITION*PAͲ0276 YORKGENERATIONFACILITY YORKPLANTHOLDINGS,LLC3/1/2012 COMBUSTIONTURBINE,DUALFUEL,T01andT02(2Units)15 NaturalGas 634 MMBtu/Hr Particulatematter,filterable(FPM)NaturalGasͲPilineQualityNaturalGasOilͲUltralowsulfurdiesel5.9 LB/H*PAͲ0276 YORKGENERATIONFACILITY YORKPLANTHOLDINGS,LLC3/1/2012 COMBUSTIONTURBINE,DUALFUEL,T01andT02(2Units)15 NaturalGas 634 MMBtu/Hr Particulatematter,total<2.5ђ(TPM2.5)CleanFuelsandCombustionControlincluding:a.CombustingonlyNaturalGasorULSDfuelsb.EfficientCombustion5.9 LB/H*PAͲ0276 YORKGENERATIONFACILITY YORKPLANTHOLDINGS,LLC3/1/2012 COMBUSTIONTURBINE,DUALFUEL,T01andT02(2Units)15 NaturalGas 634 MMBtu/Hr Particulatematter,total<10ђ(TPM10)5.9 LB/H1ͲHR,PIPELINEQUALITYNGFUELONLY*PAͲ0278 MOXIELIBERTYLLC/ASYLUMPOWERPLTMOXIEENERGYLLC 10/10/2012 CombinedͲcycleTurbines(2)ͲNaturalgasfired15.2 NaturalGas 3277 MMBtu/hr Particulatematter,total(TPM)Usingfuelwithlittleornoashandsulfurcontent.0.004 LB/MMBTUFOR468MWPOWERBLOCK*PAͲ0281 TEXASEASTERNTRANSLP/HOLBROOKSTATIONTEXASEASTERNTRANSLP2/23/2010 SOLARMARSTURBINE#2100Ͳ150002SIII(15,000HP)16 NaturalGas 0 Particulatematter,total(TPM)0.02 GR/DSCF*PAͲ0286 MOXIEENERGYLLC/PATRIOTGENERATIONPLTMOXIEENERGYLLC 1/31/2013 CombinedCyclePowerBlocks472MWͲ(2)15.21 NaturalGas 0 Particulatematter,total(TPM)0.0057 LB/MMBTU*PAͲ0286 MOXIEENERGYLLC/PATRIOTGENERATIONPLTMOXIEENERGYLLC 1/31/2013 CombinedCyclePowerBlocks472MWͲ(2)15.21 NaturalGas 0 Particulatematter,total<10ђ(TPM10)0.0057 LB/MMBTU*PAͲ0286 MOXIEENERGYLLC/PATRIOTGENERATIONPLTMOXIEENERGYLLC 1/31/2013 CombinedCyclePowerBlocks472MWͲ(2)15.21 NaturalGas 0 Particulatematter,total<2.5ђ(TPM2.5)0.0057 LB/MMBTU*PAͲ0288 SUNBURYGENERATIONLP/SUNBURYSESSUNBURYGENERATIONLP4/1/2013 CombinedCycleCombustionTurbineANDDUCTBURNER(3)15.2 NaturalGas 2538000 MMBtu/hr Particulatematter,total(TPM)0.0088 LBS/MMBTU*PAͲ0291 HICKORYRUNENERGYSTATION HICKORYRUNENERGYLLC4/23/2013 COMBINEDCYCLEUNITS#1and#2 15.21 NaturalGas 3.4 MMCF/HR Particulatematter,fugitive18.5 LB/HRW/DUCTBURNER11.0LB/HRWITHOUTSCͲ0116 CYTECCARBONFIBERS,LLC CYTECCARBONFIBERSLLCACRYLONITRILEBASEDCARBON4/30/2008 UTILITIES;2BOILERSNATURALGAS 15.19 NATURALGAS/NO.2FUELOIL50 MMBTU/H ParticulateMatter(PM)GOODCOMBUSTIONPRACTICESFORDESIGN0SCͲ0116 CYTECCARBONFIBERS,LLC CYTECCARBONFIBERSLLCACRYLONITRILEBASEDCARBON4/30/2008 UTILITIES;2BOILERSNATURALGAS 15.19 NATURALGAS/NO.2FUELOIL50 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICESFORDESIGN0SCͲ0122 CYTECCARBONFIBERS,LLC CYTECCARBONFIBERSLLCACRYLONITRILEBASEDCARBON4/30/2008 UTILITIES,4BOILERSNATURALGAS 15.19 NATURALGAS 50 MMBTU/H ParticulateMatter(PM)GOODCOMBUSTIONPRACTICESFORDESIGN0SCͲ0122 CYTECCARBONFIBERS,LLC CYTECCARBONFIBERSLLCACRYLONITRILEBASEDCARBON4/30/2008 UTILITIES,4BOILERSNATURALGAS 15.19 NATURALGAS 50 MMBTU/H Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICESFORDESIGN0*SDͲ0005 DEERCREEKSTATION BASINELECTRICPOWERCOOPERATIVE6/29/2010 Combustionturbine/heatrecoverysteamgenerator16.21 NaturalGas 300 Megawatts Particulatematter,total<10ђ(TPM10)GoodCombustion 23.2 POUNDSPERHOUR3ͲHOUR/WITHDUCTFIRINGTXͲ0487 ROHMANDHAASCHEMICALSLLCLONESTARPLANTROHMANDHAASTEXASINCORPORATION3/24/2005 LͲAREAGASTURBINE 15.11 NATURALGAS Particulatematter,filterable<10ђ(FPM10)2.09 LB/HTXͲ0497 INEOSCHOCOLATEBAYOUFACILITY INEOSUSALLC 8/29/2006 COGENERATIONTRAIN2AND3(TURBINEANDDUCTBURNEREMISSIONS)15.21 NATURALGAS 35 MW Particulatematter,filterable<10ђ(FPM10)THEUSEOFPROPERCOMBUSTIONCONTROLANDFIRINGONLYGASEOUSFUELSCONTAININGNOASHISBACTFORPARTICULATEMATTERFROMTHEGASFIREDTURBINESANDDUCTBURNERS.10.03 LB/HTXͲ0498 SIGNALHILLSWICHITAFALLSPOWERLPSIGNALHILLS 5/8/2006 TURBINES(3) 16.21 NATURALGAS 20 MW ParticulateMatter(PM)1.04 LB/HTXͲ0502 NACOGDOCHESPOWERSTERNEGENERATINGFACILITYNACOGDOCHESPOWERLLC6/5/2006 WESTINGHOUSE/SIEMENSMODELSW501FGASTURBINEW/416.5MMBTUDUCTBURNERS15.21 NATURALGAS 190 MW Particulatematter,filterable<10ђ(FPM10)STEAGPOWERLLCREPRESENTSTHEFIRINGOFPIPELINENATURALGASINTHECOMBUSTIONTURBINESANDDUCTFIREDHRSGSASBACTFORPM10.26.9 LB/HTXͲ0504 NAVASOTAPOWERGENERATIONFACILITYNAVASOTAODESSAENERGY4/20/2006 TURBINESWITH165MMBTU/HRDUCTBURNERS15.11 NATURALGAS 75 MW ParticulateMatter(PM)USEOFNATURALGAS 12.4 LB/HTXͲ0504 NAVASOTAPOWERGENERATIONFACILITYNAVASOTAODESSAENERGY4/20/2006 TURBINESWITHOUT165MMBTU/HRDUCTBURNERS15.11 NATURALGAS 75 MW ParticulateMatter(PM)10.4 LB/HPage10of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONTXͲ0504 NAVASOTAPOWERGENERATIONFACILITYNAVASOTAODESSAENERGY4/20/2006 STARTUP,SHUTDOWN,MAINTENANCE15.11 NATURALGAS 75 MW ParticulateMatter(PM)10.5 LB/HTXͲ0506 NRGTEXASELECTRICPOWERGENERATIONNRGTEXAS 4/19/2006 ANNUALLIMITS 15.9 NATURALGASANDFUELOILParticulateMatter(PM)50.9 T/YRTXͲ0509 PONDEROSAPINEENERGYPARTNERSCOGENERATIONFACILITYPONDEROSAPINEENERGYPARTNERS3/15/2006 TURBINEAND375MMBTU/HRHEATRECOVERYSTEAMSYSTEM15.11 NATURALGAS 250 MW ParticulateMatter(PM)57.8 LB/HTXͲ0509 PONDEROSAPINEENERGYPARTNERSCOGENERATIONFACILITYPONDEROSAPINEENERGYPARTNERS3/15/2006 TURBINEAND375MMBTU/HRHEATRECOVERYSTEAMSYSTEM15.11 NATURALGAS 250 MW Particulatematter,filterable<10ђ(FPM10)57 LB/HTXͲ0525 TEXASGENCOUNITS1AND2 TEXASGENCO 9/13/2005 80MWGASTURBINE 15.11 NATURALGAS 550 MMBTU/H Particulatematter,filterable<10ђ(FPM10)7 LB/HTXͲ0540 BOSQUECOUNTYPOWERPLANT BOSQUEPOWERCOMPANYLLC2/27/2009 ELECTRICALGENERATION 15.11 NATURALGAS 170 MW ParticulateMatter(PM)BACTISTHEUSEOFPIPELINEͲQUALITYNATURALGASANDTHEAPPLICATIONOFGOODCOMBUSTIONCONTROLS.WITHTHISMETHODOFCONTROL,PM/PM10EMISSIONSSHOULDNOTEXCEED0.01LB/MMBTUFORA3ͲHOURROLLINGPERIOD.0.01 LB/MMBTU3HRROLLINGPERIODTXͲ0542 PEARSALLPOWERPLANT SOUTHTEXASELECTRICCOOPERATIVEINC.1/23/2009 ELECTRICALGENERATION 15.21 NATURALGAS 8.44 MW ParticulateMatter(PM)TCEQ¿SCURRENTBACTGUIDELINESPROVIDENOGUIDANCEFORPMEMISSIONSFORTHISTYPEOFENGINE.LOWASHFUELANDCOMBUSTIONCONTROLSAREUSEDASTHECONTROLMETHOD.STECWILLUSEGOODCOMBUSTIONCONTROL.0SEENOTETXͲ0588 PORTARTHURREFINERY MOTIVAENTERPRISESLLC8/4/2010 PowerStation 15.25 NaturalGasandrefineryfuel0 Particulatematter,total(TPM)NoaddͲoncontrolwasrequiredforPMcontrolfromtheturbinesandtheHRSG(HeatRecoverySteamGenerator).BACTismetforPMcontrolandRBLCshowednofurthercontrolisnecessary.2.07 T/YRINITIALCAPFORPMTXͲ0590 KINGPOWERSTATION PONDERACAPITALMANAGEMENTGPINC8/5/2010 Turbine 15.21 naturalgas 1350 MW Particulatematter,total(TPM)uselowashfuel(naturalgasorlowsulfurdieselasabackup)andgoodcombustionpractices11.1 LB/HTXͲ0590 KINGPOWERSTATION PONDERACAPITALMANAGEMENTGPINC8/5/2010 Turbine 15.21 naturalgas 1350 MW Particulatematter,total<10ђ(TPM10)useoflowashfuel(naturalgasorlowsulfurdieselasabackup)11.1 LB/HTXͲ0590 KINGPOWERSTATION PONDERACAPITALMANAGEMENTGPINC8/5/2010 Turbine 15.21 naturalgas 1350 MW Particulatematter,total<2.5ђ(TPM2.5)useoflowashfuel(naturalgasorlowsulfurdieselasabackup)11.1 LB/HTXͲ0600 THOMASC.FERGUSONPOWERPLANT LOWERCOLORADORIVERAUTHORITY9/1/2011 NaturalgasͲfiredturbines 15.21 naturalgas 390 MW Particulatematter,total<2.5ђ(TPM2.5)pipelinequalitynaturalgas 33.43 LB/H1ͲHTXͲ0618 CHANNELENERGYCENTERLLC CHANNELENERGYCENTERLLC10/15/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total(TPM)Goodcombustionandtheuseofgaseousfuel27 LB/HTXͲ0618 CHANNELENERGYCENTERLLC CHANNELENERGYCENTERLLC10/15/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total<10ђ(TPM10)goodcombustionandtheuseofgaseousfuel27 LB/HTXͲ0618 CHANNELENERGYCENTERLLC CHANNELENERGYCENTERLLC10/15/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total<2.5ђ(TPM2.5)goodcombustionandtheuseofgaseousfuel27 LB/HTXͲ0619 DEERPARKENERGYCENTER DEERPARKENERGYCENTERLLC9/26/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total(TPM)goodcombustionanduseofnaturalgas 27 LB/HTXͲ0619 DEERPARKENERGYCENTER DEERPARKENERGYCENTERLLC9/26/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total<10ђ(TPM10)goodcombustionandtheuseofnaturalgas27 LB/HTXͲ0619 DEERPARKENERGYCENTER DEERPARKENERGYCENTERLLC9/26/2012 CombinedCycleTurbine 15.21 naturalgas 180 MW Particulatematter,total<2.5ђ(TPM2.5)27 LB/HTXͲ0620 ESJOSLINPOWERPLANT CALHOUNPORTAUTHORITY9/12/2012 Combinedcyclegasturbine 15.21 naturalgas 195 MW Particulatematter,total<2.5ђ(TPM2.5)18 LB/HPERTURBINEPage11of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable1:NaturalGasCombustionTubines/DuctBurnersͲPM/PM10/PM2.5RBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONTXͲ0620 ESJOSLINPOWERPLANT CALHOUNPORTAUTHORITY9/12/2012 Combinedcyclegasturbine 15.21 naturalgas 195 MW Particulatematter,total<10ђ(TPM10)goodcombustionandnaturalgasasfuel 18 LB/HPERTURBINETXͲ0620 ESJOSLINPOWERPLANT CALHOUNPORTAUTHORITY9/12/2012 Combinedcyclegasturbine 15.21 naturalgas 195 MW Particulatematter,total(TPM)goodcombustionandnaturalgasasfuel 18 LB/HPERTURBINETXͲ0625 WAPARISHELECTRICGENERATINGSTATIONͲDEMONSTRATIONPROJECTNRGTEXASPOWERLLC 12/19/2012 Cogenerationturbine 16.21 naturalgas 80 MW Particulatematter,total<10ђ(TPM10)goodcombustionanduseofnaturalgas 16.58 LB/H1HRTXͲ0625 WAPARISHELECTRICGENERATINGSTATIONͲDEMONSTRATIONPROJECTNRGTEXASPOWERLLC 12/19/2012 Cogenerationturbine 16.21 naturalgas 80 MW Particulatematter,total<2.5ђ(TPM2.5)goodcombustionanduseofnaturalgas 16.58 LB/H1HR*TXͲ0641 PINECRESTENERGYCENTER PINECRESTENERGYCENTERLLC11/12/2013 combinedcycleturbine 15.21 naturalgas 700 MW Particulatematter,total<2.5ђ(TPM2.5)pipelinequalitynaturalgasandgoodcombustionpractices26.2 LB/HUTͲ0066 CURRANTCREEK PACIFICORP 5/17/2004 NATURALGASFIREDTURBINESANDHEATRECOVERYSTEAMGENERATORS15.21 NATURALGAS Particulatematter,filterable<10ђ(FPM10)0.066 LB/MMBTU18ͲHOUR/TESTEDANNUALLYUTͲ0067 LAKESIDEPOWERPLANT SUMMITVINEYARD 1/6/2005 NATURALGASFIREDCOMBINEDCYCLEELETRICPOWERGENERATIONPLANT15.11 NATURALGAS 560 MW Particulatematter,filterable<10ђ(FPM10)10.8 LB/H24ͲHOURROLLING(TURBINEͲHRSG)VAͲ0289 DUKEENERGYWYTHE,LLC DUKEENERGYWYTHE,LLC2/5/2004 TURBINE,COMBINEDCYCLE,NATURALGAS15.21 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICES. 17.5 LB/HVAͲ0289 DUKEENERGYWYTHE,LLC DUKEENERGYWYTHE,LLC2/5/2004 TURBINE,COMBINEDCYCLE,DUCTBURNER,NATURALGAS15.21 NATURALGAS 170 MW Particulatematter,filterable<10ђ(FPM10)GOODCOMBUSTIONPRACTICES 23.7 LB/H*VAͲ0315 WARRENCOUNTYPOWERPLANTͲDOMINIONVIRGINIAELECTRICANDPOWERCOMPANY12/17/2010 COMBINEDCYCLETURBINE&DUCTBURNER,315.21 NaturalGas 2996 MMBTU/H Particulatematter,total<10ђ(TPM10)NaturalGasonly,fuelhasmaximumsulfurcontentof0.0003%byweight.8 LB/H3HRAVG.(WITHOUTDUCTBURNERFIRING)*VAͲ0315 WARRENCOUNTYPOWERPLANTͲDOMINIONVIRGINIAELECTRICANDPOWERCOMPANY12/17/2010 COMBINEDCYCLETURBINE&DUCTBURNER,315.21 NaturalGas 2996 MMBTU/H Particulatematter,total<2.5ђ(TPM2.5)NaturalGasonly,fuelhasmaximumsulfurcontentof0.0003%byweight.8 LB/H3HRAVG.(WITHOUTDUCTBURNERFIRING)*VAͲ0319 GATEWAYCOGENERATION1,LLCͲSMARTWATERPROJECTGATEWAYGREENENERGY8/27/2012 COMBUSTIONTURBINES,(2) 15.21 NaturalGas 593 MMBTU/H Particulatematter,total<2.5ђ(TPM2.5)Cleanburningfuelsandgoodcombustionpractices.5 LB/H3HAVG*VAͲ0319 GATEWAYCOGENERATION1,LLCͲSMARTWATERPROJECTGATEWAYGREENENERGY8/27/2012 COMBUSTIONTURBINES,(2) 15.21 NaturalGas 593 MMBTU/H Particulatematter,total<10ђ(TPM10)CleanͲburningfuelsandgoodcombustionpractices.5 LB/H3HAVGWAͲ0328 BPCHERRYPOINTCOGENERATIONPROJECTBPWESTCOASTPRODUCTS,LLC1/11/2005 GE7FACOMBUSTIONTURBINE&HEATRECOVERYSTEAMGENERATOR15.21 NATURALGAS 174 MW Particulatematter,filterable<10ђ(FPM10)LIMITFUELTYPETONATURALGAS 0WIͲ0227 PORTWASHINGTONGENERATINGSTATIONWEENERGIES(WEPCO) 10/13/2004 COMBINEDCYCLECOMBUSTIONTURBINES(4W/DUCTBURNER,HRSG)16.21 NATURALGAS 2096 MMBTU/H Particulatematter,filterable<10ђ(FPM10)NATURALGAS;GOODCOMBUSTIONPRACTICES33 LB/H(EACHUNIT)WIͲ0240 WEENERGIESCONCORD WISCONSINELECTRICPOWER1/26/2006 COMBUSTIONTURBINE,100MW,NATURALGAS15.11 NATURALGAS 100 mw ParticulateMatter(PM)39 LB/HHOURLY*WYͲ0070 CHEYENNEPRAIRIEGENERATINGSTATIONBLACKHILLSPOWER,INC.8/28/2012 SimpleCycleTurbine(EP03) 15.11 NaturalGas 40 MW Particulatematter,total(TPM)goodcombustionpractices 4 LB/H3ͲHOURAVERAGE*WYͲ0070 CHEYENNEPRAIRIEGENERATINGSTATIONBLACKHILLSPOWER,INC.8/28/2012 CombinedCycleTurbine(EP01) 15.21 NaturalGas 40 MW Particulatematter,total(TPM)goodcombustionpractices 4 LB/H3ͲHOURAVERAGE*WYͲ0070 CHEYENNEPRAIRIEGENERATINGSTATIONBLACKHILLSPOWER,INC.8/28/2012 CombinedCycleTurbine(EP02) 15.21 NaturalGas 40 MW Particulatematter,total(TPM)goodcombustionpractices 4 LB/H3ͲHOURAVERAGE*WYͲ0070 CHEYENNEPRAIRIEGENERATINGSTATIONBLACKHILLSPOWER,INC.8/28/2012 SimpleCycleTrubine(EP04) 15.11 NaturalGas 40 MW Particulatematter,total(TPM)goodcombustionpractices 4 LB/H3ͲHOURAVERAGE*WYͲ0070 CHEYENNEPRAIRIEGENERATINGSTATIONBLACKHILLSPOWER,INC.8/28/2012 SimpleCycleTurbine(EP05) 15.11 NaturalGas 40 MW Particulatematter,total(TPM)goodcombustionpractices 4 LB/H3ͲHOURAVERAGEPage12of12AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable2:NaturalGasCombustionTubines/DuctBurnersͲGHGRBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITIONCAͲ1212 PALMDALEHYBRIDPOWERPROJECT CITYOFPALMDALE 10/18/2011 COMBUSTIONTURBINES(NORMALOPERATION)15.21 NATURALGAS 154 MW CarbonDioxideEquivalent(CO2e)774 LB/MWͲH365ͲDAYROLLINGAVG(FACILITYWIDE)CAͲ1223 PIOPICOENERGYCENTER PIOPICOENERGYCENTER,LLC11/19/2012 COMBUSTIONTURBINES(NORMALOPERATION)15.11 NATURALGAS 300 MW CarbonDioxideEquivalent(CO2e)1328 LB/MWͲHGROSSOUTPUT*DEͲ0023 NRGENERGYCENTERDOVER NRGENERGYCENTERDOVERLLC10/31/2012 UNIT2ͲKD1 15.21 NaturalGas 655 MMBTU/H CarbonDioxideEquivalent(CO2e)1085 LB/GROSSMWH12MONTHROLLINGAVERAGEDEͲ0024 GARRISONENERGYCENTER GARRISONENERGYCENTER,LLC/CALPINECORPORATION1/30/2013 Unit1 15.21 NaturalGas 2260 millionBTUs CarbonDioxideEquivalent(CO2e)FuelUsageRestrictiontonaturalgasandlowsulfurdistillatefuel1006304 TONS12MONTHROLLINGAVERAGE*INͲ0158 ST.JOSEPHENEGRYCENTER,LLC ST.JOSEPHENERGYCENTER,LLC12/3/2012 FOUR(4)NATURALGASCOMBINEDCYCLECOMBUSTIONTURBINES15.21 NATURALGAS 2300 MMBTU/H CarbonDioxideEquivalent(CO2e)HIGHTHERMALEFFICIENCYDESIGN 7646 BTU/KWͲHLAͲ0256 COGENERATIONPLANT WESTLAKEVINYLSCOMPANYLP12/6/2011 COGENERATIONTRAINS1Ͳ3(1Ͳ10,2Ͳ10,3Ͳ10)15.21 NATURALGAS 475 MMBTU/H CarbonDioxideEquivalent(CO2e)USEOFNATURALGASASFUELANDGOODCOMBUSTIONPRACTICES55576.77 LB/HHOURLYMAXIMUMLAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 SimpleCycleRefrigerationCompressorTurbines(16)15.11 NaturalGas 286 MMBTU/H CarbonDioxideEquivalent(CO2e)Goodcombustion/operatingpracticesandfueledbynaturalgasͲuseGELM2500+G4turbines4872107 TONS/YRANNUALMAXIMUMFROMTHEFACILITYWIDELAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 CombinedCycleRefrigerationCompressorTurbines(8)15.21 naturalgas 286 MMBTU/H CarbonDioxideEquivalent(CO2e)Goodcombustion/operatingpracticesandfueledbynaturalgasͲuseGELM2500+G4turbines4872107 TONS/YEARANNUALMAXIMUMFROMTHEFACILITYWIDELAͲ0257 SABINEPASSLNGTERMINAL SABINEPASSLNG,LP&SABINEPASSLIQUEFACTION,LL12/6/2011 SimpleCycleGenerationTurbines(2) 15.11 NaturalGas 286 MMBTU/H CarbonDioxideEquivalent(CO2e)Goodcombustion/operatingpracticesandfueledbynaturalgasͲuseGELM2500+G4turbines4872107 TONS/YRANNUALMAXIMUMFROMTHEFACILITYWIDE*MIͲ0402 SUMPTERPOWERPLANT WOLVERINEPOWERSUPPLYCOOPERATIVEINC.11/17/2011 Combinedcyclecombustionturbinew/HRSG15.21 Naturalgas 130 MWelectricaloutputCarbonDioxideEquivalent(CO2e)954 LB/MWͲH12ͲMONTHROLLINGAVERAGE*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSG15.21 Naturalgas 2237 MMBtu/hour CarbonDioxideEquivalent(CO2e)Goodcombustionpracticesandenergyefficiency.995 LB/MWͲH12ͲMO.ROLLINGAVERAGE*MIͲ0405 MIDLANDCOGENERATIONVENTURE MIDLANDCOGENERATIONVENTURE4/23/2013 Naturalgasfueledcombinedcyclecombustionturbinegenerators(CTG)withHRSGandductburner(DB)15.21 Naturalgas 2486 MMBTU/H CarbonDioxideEquivalent(CO2e)Goodcombustionpracticesandenergyefficiency1071 LB/MWͲH12ͲMONTHROLLINGAVG.*NDͲ0028 R.M.HESKETTSTATION MONTANAͲDAKOTAUTILITIESCO.2/22/2013 CombustionTurbine 15.11 Naturalgas 986 MMBtu/hr CarbonDioxideEquivalent(CO2e)413198 TONS12MONTHROLLINGTOTAL*NDͲ0029 PIONEERGENERATINGSTATION BASINELECTRICPOWERCOOPERATIVE5/14/2013 NaturalgasͲfiredturbines 15.11 Naturalgas 451 MMBtu/hr CarbonDioxideEquivalent(CO2e)243147 TONS12MONTHROLLINGTOTAL/EACHUNIT*NDͲ0030 LONESOMECREEKGENERATINGSTATIONBASINELECTRICPOWERCOOP.9/16/2013 NaturalGasFiredSimpleCycleTurbines15.11 Naturalgas 412 MMBtu/hr CarbonDioxideEquivalent(CO2e)Highefficiencyturbines 220122 TONS12MONTHROLLINGTOTALNJͲ0079 WOODBRIDGEENERGYCENTER CPVSHORE,LLC 7/25/2012 CombinedCycleCombustionTurbinewithDuctBurner16.21 Naturalgas 40297.6 mmcubicft/yearCarbonDioxideEquivalent(CO2e)Goodcombustionpractices 925 LB/MWͲHBASEDON12MONTHPERIOD,ROLLING1MNTHNJͲ0080 HESSNEWARKENERGYCENTER HESSNEWARKENERGYCENTER,LLC11/1/2012 Combinedcylceturbinewithductburner16.21 naturalgas 39463 mmcubicft/year*CarbonDioxideEquivalent(CO2e)GoodCombustionPractices 887 LB/MWͲHCONSCUTV12MONTHPERIODROLLING1MONTH*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲSiemens,withoutductburners15.21 NaturalGas 515600 MMSCF/rolling12ͲmonthsCarbonDioxideEquivalent(CO2e)stateͲofͲtheͲarthighefficiencycombustiontechnology318404 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲSiemens,withductburners15.21 NaturalGas 51560 MMSCF/rolling12ͲMOCarbonDioxideEquivalent(CO2e)stateͲofͲtheͲarthighefficiencycombustiontechnology318404 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲMitsubishi,withoutductburners15.21 NaturalGas 47917 MMSCF/rolling12ͲMOCarbonDioxideEquivalent(CO2e)stateͲofͲtheͲarthighefficiencycombustiontechnology318404 LB/H*OHͲ0352 OREGONCLEANENERGYCENTER ARCADIS,US,INC. 6/18/2013 2CombinedCycleCombustionTurbinesͲMitsubishi,withductburners15.21 NaturalGas 47917 MMSCF/rolling12ͲMOCarbonDioxideEquivalent(CO2e)stateͲofͲtheͲarthighefficiencycombustiontechnology318404 LB/H*PAͲ0276 YORKGENERATIONFACILITY YORKPLANTHOLDINGS,LLC3/1/2012 COMBUSTIONTURBINE,DUALFUEL,T01andT02(2Units)15 NaturalGas 634 MMBtu/Hr CarbonDioxideEquivalent(CO2e)1330 LB/MWHR30DAYROLLING*PAͲ0278 MOXIELIBERTYLLC/ASYLUMPOWERPLTMOXIEENERGYLLC 10/10/2012 CombinedͲcycleTurbines(2)ͲNaturalgasfired15.2 NaturalGas 3277 MMBtu/hr CarbonDioxideEquivalent(CO2e)Goodcombustionpractices. 1480086 TPY468MWPOWERBLOCKPage1of2AttachmentAͲRACT/BACT/LAERClearinghouseSummaryTablesTable2:NaturalGasCombustionTubines/DuctBurnersͲGHGRBLCID FACILITYNAME CORPORATEORCOMPANYNAMEPERMITISSUANCEDATEPROCESSNAME PROCCESSTYPEPRIMARYFUELTHROUGHPUTTHROUGHPUTUNITPOLLUTANT CONTROLMETHODDESCRIPTION EMISSIONLIMIT1EMISSIONLIMIT1UNITEMISSIONLIMIT1AVGTIMECONDITION*PAͲ0288 SUNBURYGENERATIONLP/SUNBURYSESSUNBURYGENERATIONLP4/1/2013 CombinedCycleCombustionTurbineANDDUCTBURNER(3)15.2 NaturalGas 2538000 MMBtu/hr CarbonDioxideEquivalent(CO2e)281727 LBS/HRWHENDUCTBURNERSOPERATING*PAͲ0291 HICKORYRUNENERGYSTATION HICKORYRUNENERGYLLC4/23/2013 COMBINEDCYCLEUNITS#1and#2 15.21 NaturalGas 3.4 MMCF/HR CarbonDioxideEquivalent(CO2e)3665974 TPY12ͲMONTHROLLINGTOTALFORBOTHUNITSTXͲ0612 THOMASC.FERGUSONPOWERPLANT LOWERCOLORADORIVERAUTHORITY11/10/2011 COMBINEDCYCLETURBINEGENERATORU1ͲSTK15.21 NaturalGas 1746 MMBTU/H CarbonDioxideEquivalent(CO2e)GoodCombustionPractices 908957.6 LB/H30ͲDAYROLLINGAVERAGETXͲ0612 THOMASC.FERGUSONPOWERPLANT LOWERCOLORADORIVERAUTHORITY11/10/2011 COMBINEDCYCLETURBINEGENERATORU1ͲSTK15.21 NaturalGas 1746 MMBTU/H Methane 16.8 T/YR365ͲDAYROLLINGAVERAGETXͲ0612 THOMASC.FERGUSONPOWERPLANT LOWERCOLORADORIVERAUTHORITY11/10/2011 COMBINEDCYCLETURBINEGENERATORU1ͲSTK15.21 NaturalGas 1746 MMBTU/H NitrousOxide(N2O) 1.7 T/YR360DAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD3ͲSeries) 15.21 NaturalGas 0 CarbonDioxide 1062627 T/YR365ͲDAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD3ͲSeries) 15.21 NaturalGas 0 Methane 19.67 T/YR365ͲDAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD3ͲSeries) 15.21 NaturalGas 0 NitrousOxide(N2O) 1.97 T/YR365ͲDAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD2ͲSeries) 15.21 naturalgas 0 CarbonDioxide 0.46 T/MWͲH30ͲDAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD2ͲSeries) 15.21 naturalgas 0 NitrousOxide(N2O) 1.93 T/YR365ͲDAYROLLINGAVERAGETXͲ0632 DEERPARKENERGYCENTERLLC CALPIINECOͲDEERPARKENERGYCENTER(DPEC)LLC11/29/2012 CTG5/HRSG5(FD2ͲSeries) 15.21 naturalgas 0 Methane 19.34 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD2ͲSeries)ͲInitialPhase 15.21 NaturalGas 0 Methane 18.22 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD2ͲSeries)ͲInitialPhase 15.21 NaturalGas 0 NitrousOxide(N2O) 1.82 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD2ͲSeries)ͲInitialPhase 15.21 NaturalGas 0 CarbonDioxide 984393 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD3ͲSeries)ͲFinalPhase 15.21 NaturalGas 0 CarbonDioxide 10020391 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD3ͲSeries)ͲFinalPhase 15.21 NaturalGas 0 Methane 18.55 T/YR365ͲDAYROLLINGAVERAGETXͲ0633 CHANNELENERGYENERGYCENTER,LLCCALPINECORPORATIONͲCHANNELENERGYCENTER,LLC11/29/2012 CTG3/HRSG3(FD3ͲSeries)ͲFinalPhase 15.21 NaturalGas 0 NitrousOxide(N2O) 1.86 T/YR365ͲDAYROLLINGAVERAGETXͲ0636 HOUSTONCENTRALGASPLANT COPANOPROCESSINGL.P3/8/2013 SupplementalHeaters 16.11 naturalgas 25 MMBTU/H CarbonDioxide 876 T/YR12MONTHROLLINGAVGTXͲ0636 HOUSTONCENTRALGASPLANT COPANOPROCESSINGL.P3/8/2013 SupplementalHeaters 16.11 naturalgas 25 MMBTU/H CarbonDioxideEquivalent(CO2e)877 T/YR12MONTHROLLINGAVGTXͲ0636 HOUSTONCENTRALGASPLANT COPANOPROCESSINGL.P3/8/2013 RegenerativeThermalOxidizer(RTO)(CombustionUnit).16.15 naturalgas 0 CarbonDioxide 69452 T/YR12MONTHROLLINGAVGTXͲ0636 HOUSTONCENTRALGASPLANT COPANOPROCESSINGL.P3/8/2013 RegenerativeThermalOxidizer(RTO)(CombustionUnit).16.15 naturalgas 0 CarbonDioxideEquivalent(CO2e)69459 T/YR12MONTHROLLINGAVG*VAͲ0319 GATEWAYCOGENERATION1,LLCͲSMARTWATERPROJECTGATEWAYGREENENERGY8/27/2012 COMBUSTIONTURBINES,(2) 15.21 NaturalGas 593 MMBTU/H CarbonDioxideEquivalent(CO2e)Controlledbytheuseoflowcarbonfuelsandhighefficiencydesign.Theheatrateshallbenogreaterthan8,983Btu/kWͲh(HHV,gross).295961 T/YR12MOROLLINGAVGPage2of2

#  



# Flint Hills Resources - Pine Bend Refinery BACT Report - Attachment B - Table B-1 - CCS Capital Cost Pipeline to Nearest Sequestration Site and Injection Well

CO 2 

## Capture Equipment Capital Cost

Basis NETL Cost and Performance Baseline for Fossil Energy Plants, Updated Costs August 201 2 http://www.netl.doe.gov/energy-analyses/baseline_studies.html
NETL Study Baseline NGCC Plant CO 2 

### Uncontrolled Emission Rate 446,629 lb/hr

Total Capital Costs for NGCC Power Plant without CO 2 

### Capture $531.7 Million

Total Capital Costs for NGCC Power Plant with CO 2 

### Capture $940.5 Million

Incremental Capital Cost for CO 2 

### Capture $408.8 Million

FHR Combined Heat and Power Cogeneration Facility CO 2 

### PTE 78,737 lb/hr

Maximum Estimate: $408.8M*(78737/446629)^0.6 $187.7 Million



## CO 2 

### Pipeline Capital Cost
Basis "Carbon Dioxide Transport and Storage Costs in NETL Studies." Exhibit 2 NETL Mar 2013 http://www.netl.doe.gov/energy-analyses/pubs/QGESS_CO2T%26S_Rev2_20130408.pdf

Pipeline Minimum Length (L) 1 

### 325 miles

Pipeline Diameter (D) 2 

### 6 inches Materials Cost = 64632+1.85*L*(330.5*D^2+686.7*D+26960) $28.1 Million Labor Cost = 341627+1.85*L*(343.2*D^2+2074*D+170013) $127.6 Million Miscellaneous = 150166+1.58*D17*(8417*D18+7234) $29.2 Million Right of Way = 150166+1.58*D17*(8417*D18+7234) $13.9 Million
CO2 Surge Tank $1.2 Million
Pipeline Control System $0.1 Million

Total CO 2 

### Pipeline Cost $200.2 Million

[1]

[2]



## CO 2 

## Injection Well Capital Cost NA



## CCS Estimated Total Capital Cost

Estimated Total for CCS $387.9 Million Massachusetts Institute of Technology. “Carbon Management GIS: CO2 Pipeline Transport Cost Estimate.” Updated June 2009. Available at: http://www.canadiancleanpowercoalition.com/pdf/CTS12%20- %20Transport.pdf. See Table 1, where a 6-inch diameter pipeline can accommodate annual flows of 190,000 to 540,000 tons/year. Approximate distance from FHR Pine Bend to the nearest potential geologic storage site, located in western

Illinois.

Page 1 of 1

# 




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is why 

## we are committed to 

## providing a flexible portfolio of products to 

## support a full spectrum



## of operating needs: from fast starts 

## and load following to 

## get peak customers on the grid quickly,

to 

## high availability and reliability to 

## keep base load customers online for the long haul. Whatever

your scenario, we can tailor a solution to meet your needs.

Operational flexibility is inherent to 

## GE's portfolio of aeroderivative gas turbines and a critical

component of our customers' success. We understand the importance of speed and flexibility

when it comes to 

## responding to power demands. Our gas turbines are designed to meet these

challenges with efficiency and cost effectiveness.



# Fast Installation with Less Interruption

GE is committed to maintaining short manufacturing cycles supported by dependable,

predictable delivery times and a robust supply chain. Our modular package designs and

on-going interconnect innovation allow for shorter manufacturing cycles and faster installation

times with less installed and operational costs than field erected units. All 

## of our units undergo

rigorous factory testing after assembly and are ready for operation soon after arriving on
site-translating into lower installation costs, shorter project schedules, and reduced financial

risk for our customers.

The integration of skid-mounted support systems requires less installation work, time and

expense. Fewer materials are shipped directly to 

## the site, reducing the amount of civil works,

utilizing package support systems and less foundation work than alternate generation.

Our compact, lightweight package design allows for installation flexibility and less

process interruption.



# Products known for operational flexibility, high
efficiency, superb reliability and fast installations

Providing diverse solutions for various industries

• Utilities- peak power, combined cycle, distributed generation, grid stability

• Oil & Gas- mechanical drive, power generation

• FPSO

- offshore power with our compact 538 and 538e packages

• Industrial- combined heat and power

• Mobile power- emergency power, peak demand, mining and O&G applications

• Marine

- power and propulsion

4 FAST, FLEXIBLE POWER

# Fast Starts and Cycling Capability

The ability to go from cold iron to full power in just 10 minutes and the ability to start and stop in short, 15-minute cycles

(several times per day if necessary) without impacting maintenance intervals make GE's aeroderivative gas turbines

exceptionally adept at accommodating fluctuating demand with increasing efficiency across multiple industry segments.

GE's aeroderivative gas turbines can be the first to respond to a peak power demand opportunity, without the costs of

a spinning reserve.



# Load Following

Thanks to a two-rotor design, GE's aeroderivative portfolio provides higher part power efficiency and faster response to load

changes than other similar gas turbines in the industry. This load matching allows for greater grid stability of voltage and

frequency, and provides greater starting torque for mechanical drive applications.



# High Availability/Reliability

By utilizing aircraft experience and design, our aeroderivative design approach incorporates features such as split casings,

modular construction, individual replacement of internal and external parts, and GE's "lease pool" engine program. Our extensive

use of high quality components common with parent aircraft engines validates engine reliability and offers reduced parts cost.

Various inspections and hot section repairs can be performed on the gas turbine at site within the turbine enclosure. The

"Hot Section," HPT and combustor can be removed/replaced in the field within 72 hours, allowing for greater availability during

planned maintenance. Greater availability is achieved by the on-condition maintenance program, which inspects and repairs

only as necessary to desired operational condition.



# Wide Fuel Range

At GE, we understand flexibility in fuel choices is a high priority. Our Alternate Fuels Center of Excellence is leading the industry in

identifying, designing, and delivering fuel flexibility options-all with the high reliability, availability, and maintainability standards

you expect from GE.

Our experience on liquid biofuels is proven and growing. In addition to conventional turbine fuels such as #2 diesel, jet fuel, and

kerosene, aeroderivative gas turbines are designed to run on a range of alternates-from light distillates like naphtha, to greener

fuels such as biodiesels and ethanol derived from various feedstocks. Our package and engine systems have over 450,000 hours

of successful operations on naphtha fuel, and over 23,000 hours of operation using biodiesel.

Examples of fuel versatility for our gas turbine and package products include:

Gaseous fuel Liquid fuel



### • Pipeline and liquefied natural gas (LNG) • #2 Diesel

• Syngas (low and medium BTU) • Jet fuel, kerosene

• Propane, high hydrocarbon gas • Naphtha

• Wellhead, associated gas • Biodiesel

• Coal bed methane (CBM) • Ethanol

• Landfill gas (LFG) • Liquid blends

• Coke oven gas (COG) • Butane

• Refinery/process flare gas

• LNG for marine propulsion

FAST,**FLEXIBL~'"** 

### POWER 5

# Aero Energy Services

GE customers benefit from a wellspring of operating experience and service expertise that is

unmatched in the industry. Our service offerings are designed to help customers meet their

operational goals, utilizing field expertise and unique technologies to deliver 

## key results. From

simple maintenance services to sophisticated technology upgrades to end-to-end outage

services. 

## we can help you keep your equipment operating reliably and efficiently.



# Reduced Maintenance Costs

GE's on-condition maintenance philosophy allows the condition of your engine to dictate

maintenance activities. Our aeroderivative packages are designed with a high degree of

accessibility for easy maintenance including:

• Modular construction permits component inspection/replacement without

total disassembly

• Approximately 40 different 

## ports for conclusive on-site borescope inspections

• High pressure compressor split case design

• Individually replaceable compressor blades, stator vanes, and HPT rotor blades

• Horizontally split casings allow detailed inspection and partial blade replacement on-site

• Externally replaceable gearbox and seals

• Externally mounted accessories for easy replacement

• Lightweight aeroderivative design allows fast, on-site engine exchange

• Pre-installed crones to handle the lightweight oeroderivotive gas turbines,

allowing for fast engine exchanges



# Engine Repair Capability

Our world-doss and worldwide network of Service Centers provides our customers with quick

turnarounds and convenience. Our Centers of Excellence have the capability to overhaul and

repair G E units with quick turnarounds. We ore the only LM service centers globally certified to

the Aerospace Quality standard AS9100.



# Re-energize Your Plant with GE's Repower Program

GE's Repower program provides the option of 

### replacing older gas and steam turbine equipment



## with new LM gas turbine technology as an alternative to 

### purchasing a completely new gas

turbine package and balance of plant equipment.

Repowering existing gas turbine equipment allows retention of existing plant infrastructure to



### reduce costs while achieving substantial improvements in thermal efficiency. power output,

availability, emissions, fuel efficiency and capital cost savings.

6 FAST, FLEXIBLE POWER

## Contractual Service Agreements (CSAsl

Our contractual service agreements (CSAs) create a customized maintenance solution by integrating OEM technical

knowledge and remote monitoring and diagnostics with field service, parts, and repairs to protect your investment,

improve operational productivity and reduce costs. The CSA is a highly customizable product designed for the wide range

of aeroderivative applications, packaging designs, operational demands and geographic locations. Options include full

or partial maintenance cost risk transfer, engine-only up to full plant coverage, thermal and operational performance

guarantees, integrated access to lease and ratable assets, onsite technical support, comprehensive maintenance

planning and a full range of remote services support.



## Field Services

GE's aeroderivative Global Field Services network offers world-class service and support that can anticipate and respond

to customer needs throughout the product life of their GE LM engines and packages. Offering the highest quality parts,

tools and technical support, these teams are dedicated to reducing downtime and achieving a lower cost of operation.

Field Service offerings include periodic inspections of the engine and package, hot sections, generator test and inspection,

trim balances, vibration surveys, performance testing, controls calibration, and all Levell and 2 maintenance.



## Asset Management

GE's aeroderivative lease pool program is designed to help customers reduce overall life cycle costs and provide a low cost

method for maintaining unit availability. Customers can improve site availability by leasing equipment from GE when their

own equipment is at a depot for repair, or when equipment is being repaired on site. This program allows lease customers

to continue operations to serve their customers and meet their business objectives.

Lease assets are provided under member or non-member lease agreement concepts. Member and non-member rates and

options are structured to cover the actual and opportunity costs to GE for every operating and non-operating hour.



## Aeroderivative Field Services Locations

Bakersfield

Level2-- \.syracuse
Level2

Houston / 

### 1--....

Level4 "'

Petropolis----:e

Level4

Level 2: A center that performs basic field and module repairs

Level4: A center that performs component repairs Kollsnes Kaluga

- Rheden /Level 2 /Level 2

Level4

Lincoln___.\

Level2

Madrid___.

Level2



# I

Port Harcourt
Level 2 tooling

# Perth2012~ Level2



### FAST,**FLEXIBL~'"** 

### POWER 7

# Product Directory

LM60QQ®

GE's LM6000 gas turbine family employs proven advanced emissions technology, package

flexibility and diverse fuel capabilities that 

### differentiate its ability to serve a broad spectrum of

energy users. The LM6000 offers 40 MW to 

### over 50 MW with up to 42% efficiency and 99% fleet

reliability in a flexible. compact package design for utility, industrial and oil and gas applications.

With fast romp rates, 10-minute starts, cycling and load following capability, high efficiency

and modular maintenance, the LM6000 has been one of the top selling gas turbines in its

class for the last 10 years.

Expanding global heritage



### Based on the CF6-80C2® aircraft engine. the LM6000 has achieved over 21 million operating

hours with over 1,000 units shipped to customers globally-over 

## four 

## times more experience

than all other competing gas turbines in its class combined. A global network of over 240

LM6000 owners paired with GE's broad energy solutions portfolio yields an expansive source

of operating expertise and e><perience unique to GE.

Imagination 

## at work



### GE's aeroderivative gas turbine business invests in diversified, efficient, reliable products and

services that enhance customer operability and availability while addressing global energy

concerns. Since its commercial introduction in 1992, the LM6000 engine and package design

has continued to 

### grow in its capacity to 

### meet a broad spectrum 

## of customer needs through

technology developments like 15 ppm Dry Low NOx combustion, spray intercooling for power

enhancement, fiber optic distributed controls and off-gas/liquid fuel fle><ibility.

GE introduced the latest enhancement 

## of its proven LM6000 product line in June 

## of 2008 with

the launch of the LM6000-PG with single annular combustor (SAC) and its dry low emissions

equivalent, the LM6000-PH. The enhancements include increased power and e><haust energy

in the same size gas turbine. The power increase comes from the same 4.5 m X 21.5 m package

footprint as existing SO Hz LM6000 technology, yielding a power density improvement of nearly

20%. The LM6000-PG and LM6000-PH provide combined cycle power in the range of 65 MW to

125 MW 12-on-1 combined cycle configuration) with efficiencies ranging from 52% to close to



### 55%, depending on selected emissions control methods.

The improved combined cycle efficiency of the LM6000-PG and LM6000-PH can reduce fuel

consumption 

## by the equivalent 

## of 33,000 barrels of oil per year; when compared to other similar

aeroderivative solutions in its class. GE's LM6000 uprate also reduces carbon dioxide emissions

by 6,500 tons over the course of a typical operating year-the same emissions reduction

achieved by removing 2,500 cars from the road annually.

10 FAST, FLEXIBLE POWER

### MODEL OutputMW Heat Rate Pressure Power Turbine Exhaust Flow Exhaust Temp.

Btu/kWh kJ/kWh Ratio Speed (RPM) lb/sec kg/sec 

## Of 

# oc

60HZ

LM6000-PCM 43.8 8,519 8,988 29.0 3,600 283 129 809 432

LM6000-PCM Sprint®t 50.3 8,466 8,932 31 3,600 296 134 839 448

LM6000-PDTM 43 8,180 8,630 29.1 3,600 275 125 851 455

LM6000-PD 1 

### M Sprint® 47.3 8,170 8,620 30.8 3,600 290 132 838 448

LM6000-PPM 43 8,180 8,630 29.1 3,600 275 125 851 455

LM6000-PPM Sprint® 47.3 8,170 8,620 30.8 3,600 290 132 838 448

LM6000-PGTM 54.1 8,546 9,017 33.1 3,905 318 144 861 461

LM6000-PG 1 

### M Sprint® 56.2 8,580 9,052 33.8 3,905 322 146 868 464

LM6000-PH'M 49.4 8,217 8,669 31.9 3,905 303 138 885 474

LM6000-PH'M Sprint® 51.7 8,205 8,657 32.6 3,905 306 139 880 471



### 50 HZ

LM6000-PCMt 43.3 8,571 9,043 29.1 3,627 285 129 803 428

LM6000-PCM Sprint®t 50.6 8,485 8,952 31.3 3,627 299 136 835 446

LM6000-PDTM 42.7 8,222 29.3 3,627 277 126 843 451

LM6000-PD 1 

### M Sprint® 47.5 8,198 8,649 31.1 3,627 293 133 835 446

LM6000-PPM 42.7 8,227 8,675 29.3 3,627 277 126 843 451

LM6000-PPM Sprint® 47.5 8,198 8,649 31.1 3,627 293 133 835 446

LM6000-PGTM 54.1 8,543 9,013 33.2 3,911 318 144 860 460

LM6000-PG 1 

### M Sprint® 56.3 8,577 9,049 33.8 3,911 322 146 867 464

LM6000-PH'M 48.8 8,321 8,779 32 3,911 304 138 885 474

LM6000-PH'M Sprint® 51.2 8,306 8,763 32.7 3,911 307 139 879 471



### Mechanical Drive

MODEL Power Rating ISO Heat Rate Pressure Power Turbine Exhaust Flow Exhaust Temp.

Baseload (hpl Btu/kWh kJ/kWh Ratio Speed (RPM) lb/sec kg/sec 

## Of 

# oc

LM6000-PPM 58,969 5,981 8,469 29.1 3,600 275 125 851 455

LM6000-PCM 59,914 5,944 8,409 28.8 3,600 278 126 848 453

LM6000-PGTM * * * 

## * * * * * *

LM6000-PH'M 64,698 6,057 8,381 30.3 3,743 282 128 917 492

Notes: Performance based on sg•F ambient temperature. 60% RH. sea level. no inlet/exhaust losses on natural gas fuel with no NOx media. unless

otherwise specified. Turbine inlet temperature, exhaust flow and exhaust temperature at ISO rating conditions.



### t With water injection for NOx control to 25 ppm.



### * Please contact your local GE representative for additional information.**FAS~,** 

### FltXIBLt POWeR 11

# Facts and Figures

• Headquarters in Houston, Texas

• Major manufactur i ng fac il it i es :

Houston, T exas and Veresegyhaz, Hungary

• Number of employees worldw i de : -1,600

14 AST, FLEXIBLE POWfR 

### • App li cat i ons i n over 55 countr i es

• Tota l turb i nes manufactured: 3

, 700

• Tota l operat in g hours : over 

### 100 mi lli on



## Density of GE's

aero d e r iva t ive
installed base

# Attachment 4:

ESA Consult Letter

# United States Department of the Interior

Ms. Genevieve Damico

Chief, Air Permits Section

Air and Radiation Division FISH AND WILDLIFE SERVICE

Twin Cities Field Office

4101 American Blvd 

## E.

Bloomington, Minnesota 55425-1665



## August 7, 2014

U.S. Environmental Protection Agency

77 West Jackson Boulevard, A-18J
Chicago, Illinois 60604

RE: Prevention of Significant Deterioration Permit

Flint Hills Resources

Dear Ms. Damico:

This is in response to your July 22, 2014, email in which the Environmental Protection Agency
(EPA) requested concurrence that the issuance of a Prevention of Significant Deterioration
permit for a proposed project by Flint Hills Resources (Flint Hills), near Rosemount, Minnesota,

may affect but is not likely to adversely affect two freshwater mussels that are listed as endangered under the Endangered Species Act of 1973, as amended

- Higgins eye (Lam psi/is
higginsii) 

## and sheepnose (Plethobasus cyphyus)

.



## As stated in your letter, Flint Hills is planning to construct a combined-cycle, natural gas
combined heat and power (CHP) facility that will be located in the southeast portion of the refinery property and will generate electricity and steam for the facility. Barr Engineering
completed an analysis of impacts from the proposed project for Flint Hills on April 9, 2014.

The EPA defined the action area to be a three-kilometer radius surrounding the emission stacks,

since that is where the maximum deposit of pollutants is likely to occur. The EPA contacted the

U.S. Fish and Wildlife Service (Service) on May 13, 2014, requesting information on listed species and critical habitats known to be present within the action area.

The Service responded that there are no records to indicate that any listed species occur within

three kilometers of the proposed project. However, the Mississippi River is within the action

area and Higgins eye and sheepnose may be present in the river within a reasonable distance

downstream of the action area. Higgins eye have been recorded approximately four miles

downstream of the three-kilometer radius boundary. Sheepnose may be present as near as five

miles downstream ofthe defined action area (downstream of Lock and Dam No.2).

## Flint Hills and EPA considered the possibility that some pollutants could be deposited in the Mississippi River and be transported downstream to the area where Higgins eye and sheepnose

may be present, by conducting a screening-level assessment. All calculated ecological screening quotients indicated no adverse effects to ecological receptors (i.e., federally-listed freshwater
mussels)

.

We concur that the proposed permit issuance may affect, but will not likely adversely affect Higgins eye or sheepnose in the Mississippi River downstream of the action area. Although

there is a possibility that Higgins eye and sheepnose in the Mississippi River would be exposed

to pollutants discharged by the facility, it is not likely

.

If further coordination on the proposed action is necessary, please contact Elissa Buttermore at 612-725-3548, extension 2205, or at e/issa_buttermore@fws.gov.

Sincerely,

Lisa Mandell Acting Field Supervisor

# Attachment 5:

NHPA Consult Letter

# 1 k

Minnesota 

# 1' _I_ Historical Society

STATE 

### HISTORIC PRESERVATION OFFICE



### May7, 2014

Mr. Greg 

## F. Myers

Sr. Air Permit Engineer

Flint Hills Resources Pine Bend

PO Box64596

St. Paul, MN 55164 U&lng th e Power of History to TransfOrm Lives

P RE SERV ING S HAR IN G CO NN ECT I NG



### RE: 

## EPA air permit to allow construction of a Combined Heat and Power Cogeneration Facility at the

Rosemount refinery



## T115 R19 524 NE

Rosemount, Dakota County

SHPO Number: 2014·1580

Dear Mr. Myers:

Thank you for the opportunity to comment on the above project. It has been reviewed pursuant to the

responsibilities given the State Historic Preservation Officer by the National Historic Preservation Act of 1966

and implementing federal regulations at 36 CFR 800, and to the responsibilities given the Minnesota Historical

Society by the Minnesota Historic Sites Act and the Minnesota Field Archaeology Act.

Based on available information, we conclude that no historic properties listed in or eligible for the National

Register of Historic Places will be affected by the proposed project.

Please contact our Compliance Section at (651) 259-3455 if you have any questions regarding our review of

this project.

Sincerely,

Sarah 

## J. Beimers, Manager

Government Programs and Compliance

Minnesota Historical Society

, 345 Kellogg Boulevard West

, Saint Paul, Minnesota 55102

651-259-3000 • 888-727·8386 • www.mnhs.org

# Attachment 6:

Points CalculatorPoints Calculator

1) AQ Facility ID No.: 03700011 Total Points 280
2) Facility Name: Flint Hills Resources Pine Bend Refinery 3) Small business? y/n? n 4) DQ Numbers (including all rolled) : 4744, 4761 5) Date of each Application Received: 4/7/14, 4/23/14
6) Final Permit No. 03700011-012
7) Permit Staf f Tarik Hanaf y
8) "Work completed" in which .xls file (i.e. unit 2b, unit 1a, biofuels)? NA

Total
Application Type DQ No. Qty. Points Points Details

Administrative Amendment 1 0

Minor Amendment 4 0
Applicability Request 1 0 0

Moderate Amendment 15 0
Major Amendment 4744, 4761 2 25 50
Individual State Permit (not reissuance) 5 0 0

Individual Part 70 Perm it (not reissuance) 75 0

Additional Points
Modeling Review 4744, 4761 2 15 30 modeling for both

BACT Review 4744 3 15 45 PM10, PM2.5, GHG

LAER Review 15 0
CAIR/Part 75 CEM analysis 1 0 0

NSPS Review 4744, 4761 2 1 0 20 subps. Ja & KKKK

NESHAP Review 4744 1 1 0 10 subp. YYYY
Case-by-case MACT Review 2 0 0

Netting 1 0 0

Limits to remain below threshold 4744, 4761 2 1 0 20 to avoid PSD major mod (both)
Plantwide Applicability Limit (PAL) 2 0 0

AERA review 15 0
Variance request under 7000.7000 35 0
Confidentiality request under 7000.1300 2 0

EAW review

Part 4410.4300, subparts 18, item A; and 29 15 0

Part 4410.4300, subparts 8, items A & B; 10, items

A to C; 16, items A & D; 17, items A to C & E to G;

and 18, items B & C 4761 1 35 35 subp. 10 (> 1 million gal storage)

Part 4410.4300, subparts 4; 5 items A & B; 13; 15;

16, items B & C; and 17 item D 4744 1 70 70 subp. 15B (100,000 tpy GHG increase)

Add'l Points 230

NOTES:

NESHAP subp. CC applicable to DQ 4761 but requirements already in permit, NSPS subps. Kb, GGGa and QQQ already in permit

(DQ DQ#)