### Instructions for filling Fuel Material Analysis Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Data for multiple boilers should be handled by using separate spreadsheets. Fields that are highlighted in yellow are required fields. Green highlighted cells should be filled using the drop

- down boxes, included. Gray fields are automatically filled from other fields.

Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

Please refer to the following steps when using these spreadsheets.

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the test date on the Boiler Information worksheet. 3. Please choose the type of fuel being sampled using the drop

- down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865

- 04". 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. 6. Please fill in the EIA Facility Code, Facility Name, and Boiler ID using the drop

- down boxes provided on the Fuels Sample Results worksheet. 7. Provide the Sample Number and Sample date on the Fuels Sample Results worksheet. You must provide a minimum of 9 samples, but you are not limited to that number if you have collected more. 8. Provide the results of the analyses for each constituent requested. Use the drop

- down boxes to fill in the units of

measure.

### Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being Fields that are highlighted in down boxes, included. Gray fields are

[FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet.

down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM

5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. boxes provided on the Fuels

7. Provide the Sample Number and Sample date on the Fuels Sample Results worksheet. You must provide a minimum of

down boxes to fill in the units ofEIA

Facility Code Facility Name Boiler ID Test Date

8223 Springerville Generation Station 4 5/6/2010Fuel Type 1 Fuel Type 2 Fuel Type 3

bitum inousOther Fuel DescriptionEIA

Facility Code Facility Name Boiler ID Basis An alyte

8223 Springerville Generation Station 4 As Received Higher Heating Value 8223 Springerville Generation Station 4 As Received % Moisture 8223 Springerville Generation Station 4 As Received % Ash 8223 Springerville Generation Station 4 As Received % Sulfur 8223 Springerville Generation Station 4 Dry basis Higher Heating Value 8223 Springerville Generation Station 4 Dry basis % Moisture 8223 Springerville Generation Station 4 Dry basis % Ash 8223 Springerville Generation Station 4 Dry basis % Sulfur 8223 Springerville Generation Station 4 Dry basis Antim ony 8223 Springerville Generation Station 4 Dry basis Arsenic 8223 Springerville Generation Station 4 Dry basis Bery llium 8223 Springerville Generation Station 4 Dry basis Cadmium 8223 Springerville Generation Station 4 Dry basis Chlorine 8223 Springerville Generation Station 4 Dry basis Chromium 8223 Springerville Generation Station 4 Dry basis Cobalt 8223 Springerville Generation Station 4 Dry basis Fluorine 8223 Springerville Generation Station 4 Dry basis Lead 8223 Springerville Generation Station 4 Dry basis Manganese 8223 Springerville Generation Station 4 Dry basis Mercury 8223 Springerville Generation Station 4 Dry basis Nickel 8223 Springerville Generation Station 4 Dry basis SeleniumAn alysis M ethod for each A nalyte

(example: ASTM D5865-04) ASTM D6865 ASTM D3302 ASTM D3174 ASTM D4239 ASTM D6865

ASTM D5142 ASTM D4239 ASTM D6357 ASTM D6357 ASTM D6357 ASTM D6357 ASTM D6721 ASTM D6357 ASTM D6357 ASTM D3761 ASTM D6357 ASTM D6357 ASTM D6722 ASTM D6357 SW 7740EIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 M29

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/5/2010 8982.00 Btu/lb 24.21 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.74 0.22 11851 Btu/lb 7.57 0.29Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 11 ug/g 0.04 ug/g 1 ug/g 0.3 ug/g 0.2Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 6 ug/g 2 ug/g 7 ug/g 6 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 58 ug/g 2 ug/gEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 OTM27, M29, M30B

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/6/2010 8985.00 Btu/lb 24.74 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.47 0.23 11939 Btu/lb 7.27 0.31Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 10 ug/g 0.08 ug/g 1 ug/g 0.3 ug/g 0.2Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 5 ug/g 2 ug/g 8 ug/g 5 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 53 ug/g 2 ug/gEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 OTM27, M25A

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/7/2010 8959.00 Btu/lb 24.18 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.98 0.23 11816 Btu/lb 7.89 0.3Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 10 ug/g 0.1 ug/g 1 ug/g 0.3 ug/g 0.2Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 6 ug/g 2 ug/g 6 ug/g 6 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 68 ug/g 2 ug/gEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 M25A, M320

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/8/2010 8956.00 Btu/lb 24.82 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.61 0.25 11913 Btu/lb 7.46 0.33Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 10 ug/g 0.08 ug/g 1 ug/g 0.3 ug/g 0.2Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 5 ug/g 2 ug/g 8 ug/g 5 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 59 ug/g 2 ug/gEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 M320

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/9/2010 8904.00 Btu/lb 25.27 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.61 0.24 11915 Btu/lb 7.51 0.32Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 10 ug/g 0.06 ug/g 1 ug/g 0.3 ug/g 0.2Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 5 ug/g 2 ug/g 11 ug/g 5 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 59 ug/g 2 ug/gEIA Facility Code Facility

Name Boiler ID Emissions test method(s) conducted at time of fuel sample collection (e.g., M3 0B, M26A, M0031 with SW-846 M6 260B) 8223 Springerville Generation Station 4 OTM27

Sample Number (minimum of 9 samples) Sample Date

(MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units % Moisture (as received) Continuous 5/10/2010 9093.00 Btu/lb 23.9 Fuel Testing Results% A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) % Sulfur

(Dry Basis) 5.44 0.24 11949 Btu/lb 7.15 0.32Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units Arsenic (Dry

Basis) Arsenic Units Beryllium (Dry Basis) Beryllium

Units Cadmium

(Dry Basis) 13 ug/g 0.07 ug/g 1 ug/g 0.3 ug/g 1Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) Manganese

Units Nickel (Dry

Basis) Nickel Units ug/g 5 ug/g 2 ug/g 6 ug/g 5 ug/gSelenium

(Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units 1 ug/g 56 ug/g 2 ug/gUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the

Fuel Units of Measure - HHV anthracite Btu/lb bitum inous Btu/gallon subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) Units of Measure - Metals sy nfuel mg /g petroleum coke μg/g other mg /KgUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the orangehightlighted cell, if necessary

.

Units of Measure - Cl, Fl % ppm ug/g