EMISSIONS TEST REPORT 

BIG BEND STATION 

FACILITY ID NUMBER: 0570039 

EMISSION UNIT ID NO: -004 

PARTICULATE MATTER, SULFUR DIOXIDE, 

NITROGEN OXIDE, AND 

VISIBLE EMISSIONS EVALUATION 

September 11, 2007 

AMMONIA SLIP, SULFUR DIOXIDE, AND 

NITROGEN OXIDE 

September 12, 2007 

Prepared For: 

Tampa Electric Company 

Big Bend Station 

P.O. Box 111 

Tampa, Florida 33601-0111 

Prepared By: 

Tampa Electric Company 

Environmental, Health & Safety 

Air Services Group 

Air Services Group 

5010 Causeway Boulevard 

Tampa, Florida 33619- 6130 
REPORT CERTIFICATION 

 The sampling and subsequent data entry/reduction detailed in this report 

was conducted at my direction, and I hereby certify that this test report is 

authentic and accurate to the best of my knowledge. 

Signature:__________________________ 

Jorge A. Varino 

Environmental Technician 

Test Team Lead 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the test performance, associated quality assurance 

activities, the resultant calculations, and the contents of this report, and certify 

that all project quality objectives have been met. This report is approved for 

submittal. 

Signature:__________________________ 

Raymond A. McDarby, Jr. 

Senior Environmental Technician 

Quality Assurance/Quality Control Specialist 

Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 

 I have reviewed the testing details and results submitted in this report, 

and hereby certify that this test report is authentic and accurate to the best of 

my knowledge. 

Signature:__________________________ 

David A. Smith 

Coordinator – Air Services Group 

Environmental Health & Safety 

Tampa Electric Company 
TABLE OF CONTENTS

SECTION PAGE

1.0 INTRODUCTION 1 

2.0 DISCUSSION OF RESULTS / EXECUTIVE SUMMARY 2 

3.0 SOURCE DESCRIPTION / TEST PROCEDURES 3 

4.0 TEST RESULTS 

 PARTICULATE MATTER TEST SUMMARY 8 

 SULFUR DIOXIDE AND NITROGEN OXIDES 11-SEP-2007 9 

 VISIBLE EMISSIONS DATA FROM OPACITY MONITOR 10 

 HEAT INPUT CALCULATIONS 11-SEP-2007 11 

 AMMONIA SLIP TEST SUMMARY 12-SEP-2007 12 

 SULFUR DIOXIDE AND NITROGEN OXIDES 12-SEP-2007 13 

 HEAT INPUT CALCULATIONS 12-SEP-2007 14 

5.0 FIGURES 

PARTICULATE SAMPLING TRAVERSE POINTS 16 

APPENDICES

A PARTICULATE MATTER TEST DATA 

A-1 RUN CALCULATIONS 

A-2 LABORATORY ANALYTICAL DATA 

A-3 CALIBRATION DATA 

A-4 FIELD DATA SHEETS 

A-5 CHAIN OF CUSTODY 

B CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007 

C OPERATIONS DATA 11-SEP-2007 

D AMMONIA SLIP TEST DATA (TRIGON ENGINEERING) 

D-1 FTIR SPECTROMETER DATA 

D-2 FTIR QUALITY ASSURANCE 

D-3 FTIR METHOD MAP 

E CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007 

F OPERATIONS DATA 12-SEP-2007 
G FUEL INFORMATION 

G-1 BUNKERING INFORMATION 11-SEP-2007 

G-2 FUEL ANALYSIS 

G-3 PRECIPITATOR LOGS 11-SEP-2007 

G-4 BUNKERING INFORMATION 12 SEP-2007 

H TEST PARTICIPANTS 
1

1.0 INTRODUCTION

On September 11, 2007, Tampa Electric Company’s, Environmental, Health, & 

Safety, Air Services Group, performed particulate matter (PM) tests at the Big 

Bend Station (Facility ID No.: 0570039), Boiler No. 4, (E.U. ID No.: -004). 

Testing was conducted according to procedures stipulated by the Florida 

Department of Environmental Protection (FDEP) for fossil fuel steam generators, 

and requirements in Title V Permit # 0570039-021-AV, Compliance determination 

procedures and methods, §B.26 through §B.30. 

On September 12, 2007, Trigon Engineering, under contract to Tampa Electric 

Company, performed ammonia slip tests at the same location. Testing was 

conducted according to Air Construction Permit 0570039-026-AC, COMPLIANCE 

DETERMINATION, §A.19. 
2

2.0 DISCUSSION OF RESULTS

Executive Summary 

Tampa Electric Company 

Big Bend Station 

Dry-Bottom Tangentially Fired Utility Boiler 

Emission Unit ID -004 

Coal/Petroleum Coke/Polk Residual 

Compliance Parameter Test Result FDEP Permit Limit 

September 11, 2007

Particulate, lb/mmBtu 0.01 0.01 

Particulate, lbs/hr 33.2 43.3 

SO2, lb/mmBtu 0.34 0.821

SO2, lbs/hr 1441 35511

NOX, lb/mmBtu 0.07 0.102

NOX, lbs/hr 304 4332,5

VE, % opacity 5 203

Heat Input, mmBtu/hr 4257 43304

Unit Load (% of permit) 98% 90 – 100% 

September 12, 2007

Ammonia, ppmv 1 10 

SO2, lb/mmBtu 0.12 0.821

SO2, lbs/hr 515 35511

NOX, lb/mmBtu 0.07 0.102

NOX, lbs/hr 303 4332,5

Heat Input, mmBtu/hr 4157 43304

Unit Load (% of permit) 96% 90 – 100% 

1

 Based on a 30-day rolling average. 

2

 Based on a heat input weighted 30-day rolling average. 

3

 6-minute average. 

4 Permitting Note: The heat input has been placed in the permit to identify the capacity of the 

unit for purposes of confirming that emissions testing is conducted within the 90 – 100% of the 

unit’s rated capacity (or to limit future operation to 110% of the test load), to establish 

appropriate emission limits and to aid in determining future rule applicability. 

5 This limit is based on a heat input of 4330 mmBtu/hr. 

The average particulate matter emissions were derived by performing three, 2-

hour United States Environmental Protection Agency (USEPA) reference method 

5B test runs. The average emission rates were calculated as 0.01 lb/mmBtu, 

and 33.2 lbs/hr. The FDEP Title V permitted emission rates are 0.01 lb/mmBtu 

and 43.3 lbs/hr (§ B.5.i (a) & (b)). 
3

During the particulate matter test the Sulfur Dioxide (SO2) emission rates were 

determined to be 0.34 lb/mmBtu and 1441 lbs/hr. The FDEP Title V permitted 

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling 

average (§ B.7 (a) & (b)). 

During the particulate matter test the nitrogen dioxide (NO2) emission rates (as 

total oxides) were determined to be 0.07 lb/mmBtu and 304 lbs/hr. The FDEP 

AC permitted emission rate is 0.10 lb/mmBtu and 433 lbs/hr, based on a 30-day 

rolling average (§A.16). 

Visible emissions were determined to be 5%, maximum 6-minute average, during 

a one-hour test conducted under soot blowing conditions. The FDEP Title V 

permitted emission rate is 20 percent opacity (6-minute average) except for one 

6-minute period per hour of not more than 27 (twenty-seven) percent (§B.6). 

During the particulate matter test performed on September 11, 2007 Boiler No. 4 

was operated at an average heat input rate of 4257 mmBtu/hr and an average 

load of 420 megawatts. The average quantity of fuel burned was 180.9 tons per 

hour. 

On September 12, 2007, the average ammonia slip concentration was derived by 

performing three, 1-hour USEPA reference method 320 test runs. The average 

concentration was calculated as 1 ppmv. The FDEP AC permitted concentration 

is 10 ppmv (§A.17). 

During the ammonia slip test the Sulfur Dioxide (SO2) emission rates were 

determined to be 0.12 lb/mmBtu and 515 lbs/hr. The FDEP Title V permitted 

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling 

average (§ B.7 (a) & (b)). 

During the ammonia slip test the nitrogen dioxide (NO2) emission rates (as total 

oxides) were determined to be 0.07 lb/mmBtu and 303 lbs/hr. The FDEP AC 
4

permitted emission rate is 0.10 lb/mmBtu and 433 lbs/hr, based on a 30-day 

rolling average (§A.16). 

During the ammonia slip test performed on September 12, 2007 Boiler No. 4 was 

operated at an average heat input rate of 4157 mmBtu/hr and an average load of 

410 megawatts. 
5

3.0 SOURCE DESCRIPTION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM 

coordinates East 361.9 North 3075.0. Boiler No. 4 source sampling location 

consists of a circular stack 28.83 feet in diameter with four sample ports located 

90 degrees apart on the stack circumference. Upstream and downstream gas 

flow disturbances were determined to be 8.51 and 2.99 stack diameters from the 

test ports, respectively. Using these criteria, a total of 24 sampling points were 

chosen for particulate sampling for each stack, as stipulated in the U.S. EPA 

Method 1 test procedure. A diagram of the stack sampling location is included in 

Figure 1 along with other pertinent information on the test site. 

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash 

emissions, a selective catalytic reduction (SCR) system for control of nitrogen 

oxides emissions, an ammonia injection system to control sulfur trioxide 

formation, and a flue gas desulfurization (FGD) system for control of sulfur 

dioxide emissions. 

On September 11, 2007, the boiler was fired with a solid fuel matrix comprised of 

90% coal, 9% petroleum coke, and 1% Polk residual. On September 12, 2007, 

the boiler was fired with a solid fuel matrix comprised of 87% coal, 10 % 

petroleum coke, and 3% Polk residual. 

Particulate sampling was performed according to USEPA Method 5-B 

"Determination of Nonsulfuric Acid Particulate Matter from Stationary Sources". 

Particulate matter was collected on a high purity, glass micro fiber filter 

measuring 8.26 cm in diameter. 

Sulfur Dioxide and Nitrogen Oxide data was supplied by the installed Continuous 

Emissions Monitoring systems (CEMs), Data Acquisition and Handling System 

(DAHS) as one minute averages for the duration of the particulate matter test. 
6

Visible emissions compliance was assessed using the installed Continuous 

Opacity Monitor (COM) as recorded by the DAHS as one minute averages during 

the soot blowing portion of the particulate matter test. 

Ammonia slip testing was performed using USEPA Method 320 “Measurement of 

Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform 

Infrared (FTIR) Spectroscopy”. Details of this test performed by Trigon 

Engineering are submitted as an attachment to this report. 
7

4.0 TEST RESULTS
BIG BEND STATION

PARTICULATE MATTER DATA SUMMARY

Run 1 Run 2* Run 3 Test Summary

Vm(std), scf 78.418 79.117 80.300 79.278

Bws, ratio 0.14771 0.14568 0.14582 0.146404

O2, % volume 8 8 8 8.00

Md, lb/lb - mole 30.24 30.24 30.32 30.267

Ms, lb/lb - mole 28.43 28.46 28.52 28.471

Qs, acf/min 1390398.5 1415991.4 1427357.0 1411248.96

Qs(std), dscf/min 1059791.9 1074230.2 1089264.6 1074428.88

I, % 101.2 100.8 100.9 100.97

C, lbs/dscf 5.54E-07 5.13E-07 4.79E-07 5.1521E-07

Em, lbs/hr 35.2 33.0 31.3 33.2

Er, lb/mmBtu 0.009 0.008 0.008 0.01

Mass emissions (Em), lbs/hr, calculated as: C x Qs(std) x 60 minutes/hour

Emission rate (Er), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O2))

*

Run 2 was a soot blowing run

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 11, 2007

8
BIG BEND STATION

SULFUR DIOXIDE and NITROGEN OXIDES DATA

Outlet SO2 Data

Average SO2 Concentration, ppmvw: 125.23

Average CO2 Concentration, % volume wet: 11.052

Calculated SO2 Emission Rate, lb/mmBtu: 0.34

Calculated SO2 Emission Rate, lbs/hr: 1441

Unit #4 NOx Data

Average NOx concentration, ppmvw: 40.13

Average CO2 Concentration, % volume wet: 12.065

Calculated NOx Emission Rate, lb/mmBtu: 0.07

Calculated NOx Emission Rate, lbs/hr: 304

SO2 Emission Rate, lb(s)/mmBtu is calculated as:

SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw)

NOx Emission Rate, lb/mmBtu is calculated as:

NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw)

Emission Rates in lbs/hr are calculated as:

Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr

Average Concentration values were taken from 9:45 to 17:26 EST.

Heat Input Calculated for this test was 4257 mmBtu/hr

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 11, 2007

9
BIG BEND STATION

VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

Record# DATE TIME OPACITY4 Record# DATE TIME OPACITY4

1 09/11/2007 12:27 3.88 31 09/11/2007 12:57 4.45

2 09/11/2007 12:28 3.80 32 09/11/2007 12:58 4.77

3 09/11/2007 12:29 4.07 33 09/11/2007 12:59 4.94

4 09/11/2007 12:30 3.77 34 09/11/2007 13:00 4.38

5 09/11/2007 12:31 3.75 35 09/11/2007 13:01 4.16

6 09/11/2007 12:32 3.84 36 09/11/2007 13:02 4.15

7 09/11/2007 12:33 3.82 37 09/11/2007 13:03 4.18

8 09/11/2007 12:34 3.96 38 09/11/2007 13:04 4.33

9 09/11/2007 12:35 3.80 39 09/11/2007 13:05 4.26

10 09/11/2007 12:36 3.99 40 09/11/2007 13:06 4.01

11 09/11/2007 12:37 4.22 41 09/11/2007 13:07 4.27

12 09/11/2007 12:38 4.15 42 09/11/2007 13:08 3.89

13 09/11/2007 12:39 3.87 43 09/11/2007 13:09 4.11

14 09/11/2007 12:40 3.95 44 09/11/2007 13:10 4.21

15 09/11/2007 12:41 4.06 45 09/11/2007 13:11 4.08

16 09/11/2007 12:42 3.98 46 09/11/2007 13:12 3.97

17 09/11/2007 12:43 4.17 47 09/11/2007 13:13 3.77

18 09/11/2007 12:44 4.03 48 09/11/2007 13:14 3.74

19 09/11/2007 12:45 3.91 49 09/11/2007 13:15 3.90

20 09/11/2007 12:46 3.81 50 09/11/2007 13:16 3.96

21 09/11/2007 12:47 4.06 51 09/11/2007 13:17 3.52

22 09/11/2007 12:48 3.76 52 09/11/2007 13:18 3.83

23 09/11/2007 12:49 3.92 53 09/11/2007 13:19 3.77

24 09/11/2007 12:50 4.01 54 09/11/2007 13:20 3.63

25 09/11/2007 12:51 4.19 55 09/11/2007 13:21 3.45

26 09/11/2007 12:52 4.24 56 09/11/2007 13:22 3.90

27 09/11/2007 12:53 4.24 57 09/11/2007 13:23 3.96

28 09/11/2007 12:54 4.09 58 09/11/2007 13:24 3.27

29 09/11/2007 12:55 4.57 59 09/11/2007 13:25 3.59

30 09/11/2007 12:56 4.34 60 09/11/2007 13:26 3.79

Test Average: 4.008 %

Minimum One Minute Average: 3.270 %

Maximum One Minute Average: 4.940 %

Maximum Six Minute Average: 4.575 %

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

SOOTBLOWING CONDITIONS

10
BIG BEND STATION

HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (August): 10137 KMBtu/MWh

1.0137E+07 mmBtu/MWh

Testing Start Time: 9:45

Testing End Time: 17:26

Total Test Time: 7.68 hours

Average Unit Load, MWe: 420 MW

Heat Input, mmBtu/h = mmBtu/MWh x MW: 4257 mmBtu/hr

Laboratory Sample ID: AA90279

Btu as received: 11769 Btu/lb

Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 180.9 Tons/hour

Unit #4

Test Time Information

Calculated Heat Input

Fuel Consumption Calculation

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 11, 2007

11
BIG BEND STATION

AMMONIA SLIP DATA

Run NH3

Number Start Stop ppmvw

1 11:30 12:30 1.24

2 13:11 14:11 0.747

3 14:37 15:37 0.755

Average: 1

Test Data Provided by Trigon Engineering.

Test Times

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 12, 2007

12
BIG BEND STATION

SULFUR DIOXIDE and NITROGEN OXIDES DATA

Outlet SO2 Data

Average SO2 Concentration, ppmvw: 45.24

Average CO2 Concentration, % volume wet: 10.917

Calculated SO2 Emission Rate, lb/mmBtu: 0.12

Calculated SO2 Emission Rate, lbs/hr: 515

Unit #4 NOx Data

Average NOx concentration, ppmvw: 41.31

Average CO2 Concentration, % volume wet: 12.179

Calculated NOx Emission Rate, lb/mmBtu: 0.07

Calculated NOx Emission Rate, lbs/hr: 303

SO2 Emission Rate, lb(s)/mmBtu is calculated as:

SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw)

NOx Emission Rate, lb/mmBtu is calculated as:

NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw)

Emission Rates in lbs/hr are calculated as:

Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr

Average Concentration values were taken from 10:30 to 14:37 EST.

Heat Input Calculated for this test was 4157 mmBtu/hr

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 12, 2007

13
BIG BEND STATION

HEAT INPUT CALCULATIONS

Gross Heat Rate, Previous Month (August): 10137 KMBtu/MWh

1.0137E+07 mmBtu/MWh

Testing Start Time: 11:30

Testing End Time: 15:37

Total Test Time: 4.12 hours

Average Unit Load, MWe: 410 MW

Heat Input, mmBtu/h = mmBtu/MWh x MW: 4157 mmBtu/hr

Calculated Heat Input

Unit #4

DRY-BOTTOM TANGENTIALLY FIRED BOILER

September 12, 2007

Test Time Information

14
15

5.0 FIGURES
FIGURE 1

EXHAUST STACK

245 FT.

BIG BEND STATION CS003

PARTICULATE TRAVERSE POINTS

OUTLET

N

A

B C

D

PORT LOCATION

REVISED 12-31-96

BOILER NO. 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM

FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM

FROM DISTURBANCE = 8.5

STACK DIAMETER = 28.8333 FT.

STACK AREA = 652.948 SQ.

PORT LENGTH’S = 14 IN.

TRAVERSE

 POINT

 1

 2

 3

 4

 5

 6

 % OF

STACK DIAMETER

 IN. FROM

STACK WALL

 2.1%

 6.7%

11.8%

17.7%

25.0%

35.6%

 7.27 IN.

 23.18 IN.

 40.83 IN.

 61.24 IN.

 86.50 IN.

123.18 IN.

499 FT.

254 FT.

168 FT.

86 FT.

FGD

PRESSURIZED

 ANNULUS

16
APPENDIX A 

PARTICULATE MATTER TEST DATA 
A-1 

RUN CALCULATIONS 
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 1

Date: September 11, 2007

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.270 inches

Barometric Pressure, Pb: 30.00 "Hg Nozzle Area, An: 0.000398 ft2

Stack Pressure, Ps: 29.92 "Hg Average Orifice Meter, ΔH: 1.437 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 84.100 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 101.8 o

F

Gas Analysis: 12.0 % CO2 Average Stack Temp., Ts: 130.4 o

F

8.0 % O2 Average √Δp: 0.593 "H2O

0.0 % CO Condensate Volume, Vlc: 288.3 ml

80.0 % N2 Meter Box Y: 0.986 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.590 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 78.418 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.148 %

FDA = 1.0 - Bws 0.852 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.24 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.43 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 35.49 ft/second

Qs = vs x As x 60 1390398.5 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1059791.9 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 101.2 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01970 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.004 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 5.538E-07 lbs/dscf

EM = C x Qs(std) x 60 35.2 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.009 lbs/MMBtu
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded, Sootblowing

Run Number: 2 - S

Date: September 11, 2007

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.270 inches

Barometric Pressure, Pb: 29.90 "Hg Nozzle Area, An: 0.000398 ft2

Stack Pressure, Ps: 29.82 "Hg Average Orifice Meter, ΔH: 1.476 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 85.023 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 101.1 o

F

Gas Analysis: 12.0 % CO2 Average Stack Temp., Ts: 132.6 o

F

8.0 % O2 Average √Δp: 0.602 "H2O

0.0 % CO Condensate Volume, Vlc: 286.2 ml

80.0 % N2 Meter Box Y: 0.986 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.491 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 79.117 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.146 %

FDA = 1.0 - Bws 0.854 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.24 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.46 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 36.14 ft/second

Qs = vs x As x 60 1415991.4 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1074230.2 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.8 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01840 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.004 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.003 grains/acf

C = cs / 7000 5.127E-07 lbs/dscf

EM = C x Qs(std) x 60 33.0 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.008 lbs/MMBtu
Environmental Services

Air Services Group

40 CFR 60, Appendix A - Test Methods

Reference Method 5/17

Particulate Test Calculations

Customer: Tampa Electric Company

Facility: Big Bend Station

Sampling Location: Common Stack 3 (CS003)

Unit Under Test: Boiler Number 4

Operating Conditions: Base Loaded

Run Number: 3

Date: September 11, 2007

Sample Time, θ: 120 minutes Nozzle Diameter, Dn: 0.270 inches

Barometric Pressure, Pb: 29.90 "Hg Nozzle Area, An: 0.000398 ft2

Stack Pressure, Ps: 29.82 "Hg Average Orifice Meter, ΔH: 1.521 "H2O

Effective Stack Area, As: 652.945 ft2 Sample Volume, Vm: 86.310 ft3

Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., Tm: 101.3 o

F

Gas Analysis: 12.5 % CO2 Average Stack Temp., Ts: 129.0 o

F

8.0 % O2 Average √Δp: 0.610 "H2O

0.0 % CO Condensate Volume, Vlc: 290.8 ml

79.5 % N2 Meter Box Y: 0.986 dimensionless

F-factor, Fd, for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:

Vw(std) = 4.714E-02 x Vlc 13.708 scf

Vm(std) = 17.647 x Vm x Y x (Pb + (ΔH / 13.6)) / (Tm +460) 80.300 dscf

Bws = Vw(std) / (Vm(std) + Vw(std)) 0.146 %

FDA = 1.0 - Bws 0.854 %

Md = (0.44 x %CO2) + (0.32 x %O2) + (0.28 x (%N2 + % CO)) 30.32 lb./lb. mole

Ms = (Md x FDA) + (18.0 x Bws) 28.52 lb./lb. mole

vs = 85.49 x Cp x (√Δp) x (√(Ts + 460) / (Ms x Ps)) 36.43 ft/second

Qs = vs x As x 60 1427357.0 acf/minute

Qs(std) = Qs x FDA x (528 / (Ts + 460)) x (Ps / 29.92)) 1089264.6 dscf/minute

I = (Ts + 460) x ((2.67E-03 x Vlc) + (Vm(std) / 17.647)) x 100 / (θ x Ps x An x vs x 60) 100.9 %

Data from Laboratory Analysis:

Total Particulate Weight From Laboratory Analysis: 0.01745 grams

Calculated Concentration and Emission Rate Data:

cs = (15.432 x grams) / Vm(std) 0.0034 grains/dscf

grains/acf = cs x 17.647 x Ps x (FDA / (Ts + 460) 0.0026 grains/acf

C = cs / 7000 4.791E-07 lbs/dscf

EM = C x Qs(std) x 60 31.3 lbs/hr

ER = C x Fd x (20.9 /(20.9 - %O2) 0.008 lbs/MMBtu
A-2 

LABORATORY ANALYTICAL DATA 
Customer AIR SERVICES Plant BIG BEND Unit 4

Method 5-B Stack Test Completion Date 09/11/2007Analyst SS AA90279

ACETONE BEAKER 1st weighing Date 09/14/2007 Time 11:10 % RH 45.0%

2nd weighing Date 09/17/2007 Time 15:15 % RH 45.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

***Blank*** Run 1 Run 2 Run 3 Run 1S Run 2S Run 3

Acetone Container ID AIR AF AIR AC AIR AE AIR AD

Acetone Rinse Vol.(Va), mls 150.0000 150 Enter Container ID 150 Enter Container ID 150 Enter Conta

1st Gross Wt., grams 99.9387 103.6531 101.8631 108.5861

2nd Gross Wt., grams 99.9386 103.6533 101.8634 108.5862

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 99.93865 103.65320 Enter Gross Wts. 101.86325 Enter Gross Wts. 108.58615 Enter Gros

Tare Wt., grams 99.93905 103.63815 101.84885 108.57130

Acetone Blank Wt., mg -0.40 -0.40 -0.40 -0.40

Acetone Particulate Wt., mg 15.45 14.80 15.25

Acetone Residue, mg/g -0.0034

Acetone Blank Criteria OK to subtract acetone blank

 FILTER 1st weighing Date 09/14/2007 Time 11:00 % RH 45.0%

Date 09/17/2007 Time 15:15 % RH 45.0%

3rd weighing Date Time % RH

4th weighing Date Time % RH

Filter/Thimble ID 203072 203070 203052 203056

1st Gross Wt., grams 0.2518 0.2550 0.2523 0.2561

2nd Gross Wt., grams 0.2518 0.2550 0.2524 0.2561

3rd Gross Wt., grams

4th Gross Wt., grams

Avg. Gross Wt., grams 0.25180 0.25500 Enter Gross Wts. 0.25235 Enter Gross Wts. 0.25610 Enter Gros

Tare Wt., grams 0.25140 0.25075 0.24970 0.25295

Filter Particulate Wt., mg 4.25 2.65 3.15

Difference, milligrams 0.4

Total Sample Particulate Wt., mg 19.70 17.45 18.40
A-3 

CALIBRATION DATA 
SUMMARY OF EQUIPMENT CALIBRATIONS

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 07)

INITIAL 07/19/2007 USEPA RM 5 0.986

POST TEST 09/20/2007 (ORIFICE) 0.992

NOZZLE (SN09)

INITIAL 07/19/2007 CALIPER 0.270

POST TEST 09/20/2007 MEASUREMENTS 0.270

PYROMETER (PY 09) 07/19/2007 ASTM THERMOMETER + 2o

 F

PITOT TUBE (PT 10) 07/19/2007 USEPA RM 2 Cp = 0.84

BAROMETER (BR 07) 08/16/2007 NWS COMPARISON + 0.01" Hg
Environmental Services

Air Services Group

Blue Team

Manufacturer: Thermo Anderson Calibration Date:

Model Number:MST-C1 Barometric Pressure: 30.09 "Hg

Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.19 "Hg

LabWorks Sample Number: Calibrated By:

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

0.60 15 250.900 257.837 6.937 80 76 80 75

1.10 15 239.900 249.116 9.216 82 77 81 76

1.90 15 225.100 236.979 11.879 86 78 84 77

3.50 15 204.600 220.776 16.176 90 78 91 78

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

48 0.3455 23.5 72 72 72.0

55 0.4592 22.0 72 72 72.0

63 0.5877 20.0 72 72 72.0

73 0.8022 17.0 72 72 72.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

6.857 6.761 6.776 0.986 0.000 1.640 -0.079

9.100 8.986 9.006 0.987 0.002 1.699 -0.021

11.703 11.500 11.527 0.983 -0.003 1.784 0.065

15.911 15.698 15.734 0.987 0.001 1.754 0.035

Averages: 0.986 1.719

Review/Approval:

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

Quarterly Calibration

07/19/2007

SEG

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

The Critical Orifice Coefficient, K', should be in English units.

IMPORTANT

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice Readings

Ambient Temperatures

CALCULATED DATA

Critical Orifice
Environmental Services

Air Services Group

Manufacturer: Thermo Calibration Date:

Model Number:MST Barometric Pressure: 29.82 "Hg

Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.07 "Hg

LabWorks Sample Number: Calibrated By:

Associated Test: Team: BLUE

Initial Final Total

ΔH Time Volume Volume Volume Inlet Outlet Inlet Outlet

"H2O Minutes ft3 ft3 ft3

oF oF oF oF

1.1 10 13.600 19.675 6.075 77 74 77 74

1.1 10 19.675 25.745 6.070 77 74 77 74

1.1 10 25.745 31.820 6.075 77 74 77 74

Orifice K' Actual

Serial Orifice Vacuum Initial Final Average

Number Coefficient "Hg oF oF oF

55 0.4592 20.5 72 72 72.0

55 0.4592 20.5 72 72 72.0

55 0.4592 20.5 72 72 72.0

Dry Gas Meter Calibration Calibration

Volume Volume Volume Y ΔHα

Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm(std), ft3 Vcr(std), ft3 Vcr(std), ft3 (ratio) + 0.02 "H2O + 0.2

5.984 5.937 6.004 0.992 0.000 1.725 0.000

5.979 5.937 6.004 0.993 0.001 1.725 0.000

5.984 5.937 6.004 0.992 0.000 1.725 0.000

Averages: 0.992 1.725

Prior Y: 0.986

% Difference: -0.65%

Review/Approval: Date:

BB unit 4- 09-11-07

IMPORTANT

IMPORTANT

For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.

Ambient Temperatures

Dry Gas Meter Readings

Initial Temperatures Final Tempertures

Critical Orifice Readings

USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

SEG

09/20/2007

POST - TEST CALIBRATION CHECK

21-Sep-07

CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.

For Calibration ΔHα, the acceptable tolerance of individual values from the average is + 0.2.

Critical Orifice
Environmental Services

Air Services Group

QUARTERLY NOZZLE CALIBRATIONS

Shared Resource

STEEL NOZZLE SET

Calibration Date: 07/19/2007 Responsible Party: SEG

Nozzle Nozzle Diameter, Dn (cm) Maximum Average

I.D. D1 D2 D3 Difference, " Dn, inches

^SN01 0.289 0.292 0.292 0.001 0.115

^SN04 0.319 0.318 0.319 0.000 0.125

^SN05 0.377 0.378 0.375 0.001 0.148

^SN06 0.492 0.492 0.496 0.002 0.194

^SN09 0.689 0.686 0.685 0.002 0.270

^SN10 0.750 0.754 0.753 0.002 0.296

^SN12 0.985 0.984 0.986 0.001 0.388

^SN15 0.417 0.415 0.415 0.001 0.164

^SN16 0.502 0.499 0.502 0.001 0.197

^SN19 0.707 0.708 0.708 0.000 0.279

^SN22 0.933 0.933 0.933 0.000 0.367

^SN30 0.792 0.792 0.793 0.000 0.312

^SN36 0.470 0.474 0.472 0.002 0.186

^SN37 0.527 0.529 0.533 0.002 0.209

^SN38 0.632 0.629 0.633 0.002 0.249

^SN46 0.481 0.480 0.480 0.000 0.189

^SN47 0.515 0.513 0.512 0.001 0.202

^SN48 0.632 0.634 0.634 0.001 0.249

^SN50 0.783 0.788 0.789 0.002 0.310

^SN58 0.611 0.608 0.614 0.002 0.241

^SN68 0.622 0.626 0.628 0.002 0.246

^SN69 0.947 0.949 0.949 0.001 0.373

^SN70 1.562 1.562 1.561 0.000 0.615

^SN71 1.552 1.555 1.555 0.001 0.612

^SN72 0.954 0.954 0.953 0.000 0.375

^SN73 1.279 1.283 1.281 0.002 0.504

^SN74 1.241 1.240 1.242 0.001 0.489

Data Notations: All micometer readings are converted from cm to inches by multiplying by

0.393700787. Maximum Difference must be < 0.004".

QA/QC Review by:
Environmental Services

Air Services Group

POST TEST NOZZLE CALIBRATION 

Shared Resource

Calibration Date: 09/20/2007

Calibration Personnel: JAV

Test Designation: Big Bend Unit 4

Nozzle Nozzle Diameter, Dn (cm) Maximum Average

Identifier D1 D2 D3 Difference, " Dn, inches

SN09 0.681 0.686 0.690 0.004 0.270

Data Notations: All micometer readings are converted from cm to inches by multiplying by

0.393700787. Maximum Difference must be < 0.004".

Quarterly (pre-test) value for nozzle ID SN09 was 0.270

Difference (Pre-test/Post-test) is: 0.000

QA/QC Review by: 21-Sep-07
Environmental Services

Air Services Group

Pyrometer Calibration

Blue Team

Pyrometer Under Test

Pyrometer Number: ^PY09

Labworks Sample # 0

Calibration Date: 07/19/2007

Calibrator Information

Calibrator Type/Manufacturer: Hart Scientific

Calibrator Serial Number: AOA024

Date of Last Calibration: 04/17/2007

Calibration Personnel (Typed and Signature): SEG

Calibration Data

Calibration Reference Pyrometer

Point Temperature Indication Difference

1 400 402 -2

2 212 212 0

3 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points

should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit.

Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration

Point Difference

1 Pass

2 Pass

3 Pass

Reviewer: 23-Jul-07
Environmental Services

Air Services Group

_ _

s

PITOT TUBE CALIBRATION

DATA SHEET

Pitot Tube ID # PT10

Calibration Date 07/19/2007 Operating Quarter/Year: Shared Resource

Openings Damaged? ___ Y __ N Repaired? ___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.1 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.1 degrees Pass α < 10 degrees

β 1 0.5 degrees Pass (α1 measured across top impact openings)

β 2 0.2 degrees Pass (α2 measured across bottom impact openings)

β1 < 5 degrees (alongside top impact openings)

Gamma, Theta, Α, Ζ, and W Determination β2 < 5 degrees (alongside bottom impact openings)

ψ 0.3 degrees Ζ < 0.32 cm (Αsinψ)

Α 2.428 cm W < 0.08 cm (Asinο)

Ζ 0.013 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.1 degrees ψ angle between tips

W 0.004 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, 

Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement

details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems:

Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: SEG

Quality Assurance Review / Approval:
Environmental Services

Air Services Group

BAROMETER CALIBRATION

Blue Team

Instrument Number: ^BR07

Calibration Date: 08/16/2007

Calibration Personnel: SEG

Labworks #:

Barometer Reading Reference Reading Difference

Time Inches Mercury Inches Mercury "Hg

10:00 30.08 30.06 0.02

12:00 30.09 30.08 0.01

13:00 30.12 30.07 0.05

Average Difference: 0.027

Note: Barometric readings must agree within ± 0.1 "Hg.

Current Reference is National Weather Service, TIA.

Current Conditions at Tampa International Airport

Comments (Note any adjustments):

QA/QC Review by: Date: 17-Aug-07
A-4 

FIELD DATA SHEETS 



A-5 

CHAIN OF CUSTODY 

APPENDIX B 

CONTINUOUS EMISSIONS MONITORING DATA 

11-SEP-2007 
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 9:45 39.8 12.12 134.7 11.14

09/11/2007 9:46 39.6 12.14 137 11.18

09/11/2007 9:47 39.5 12.2 135.6 11.22

09/11/2007 9:48 38.6 12.17 141.4 11.17

09/11/2007 9:49 38.5 12.16 142.4 11.17

09/11/2007 9:50 39 12.14 139.2 11.17

09/11/2007 9:51 40.1 12.17 134.6 11.18

09/11/2007 9:52 40.6 12.14 133.2 11.18

09/11/2007 9:53 40.4 12.13 138.1 11.2

09/11/2007 9:54 40.4 12.12 136.2 11.14

09/11/2007 9:55 41.8 12.15 134.9 11.29

09/11/2007 9:56 42.2 12.36 121 11.4

09/11/2007 9:57 42.1 12.41 114.2 11.4

09/11/2007 9:58 40 12.41 119.4 11.33

09/11/2007 9:59 38.6 12.35 133.2 11.41

09/11/2007 10:00 39.1 12.4 130.2 11.41

09/11/2007 10:01 39.5 12.47 126.9 11.38

09/11/2007 10:02 16.7 9.03 67.9 5.2

09/11/2007 10:03 0.2 1.54 64.9 3.16

09/11/2007 10:04 13 0.5 130.6 9.59

09/11/2007 10:05 41.5 8.28 135.2 10.65

09/11/2007 10:06 41.2 11.73 139.9 10.79

09/11/2007 10:07 42.2 11.99 139 10.85

09/11/2007 10:08 42.4 11.98 139.2 10.95

09/11/2007 10:09 43.6 11.94 140.8 11

09/11/2007 10:10 44.9 11.98 145.3 11.12

09/11/2007 10:11 45.6 12.07 147.3 11.11

09/11/2007 10:12 45.7 12.05 141 11.08

09/11/2007 10:13 44.5 12.07 136.6 11.12

09/11/2007 10:14 42.8 12.09 136.4 11.11

09/11/2007 10:15 41.8 12.12 138.1 11.1

09/11/2007 10:16 40.8 12.11 142.1 11.08

09/11/2007 10:17 40.9 12.04 146 11.14

09/11/2007 10:18 41.7 12.1 141 11.2

09/11/2007 10:19 41.7 12.22 126.8 11.22

09/11/2007 10:20 40.1 12.19 119.3 11.19

09/11/2007 10:21 38.2 12.18 117.6 11.12

09/11/2007 10:22 37.1 12.09 132.2 11.1

09/11/2007 10:23 37.9 12.04 142.8 11.13

09/11/2007 10:24 39.9 12.08 140.1 11.22

09/11/2007 10:25 41.4 12.19 131.5 11.18

09/11/2007 10:26 40.7 12.14 125 11.07

09/11/2007 10:27 40.4 12.05 124.8 11.12

Page 1 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 10:28 41.1 12.13 129.6 11.17

09/11/2007 10:29 41 12.15 129.9 11.11

09/11/2007 10:30 41 12.15 124.1 11.21

09/11/2007 10:31 41.2 12.16 129.2 11.2

09/11/2007 10:32 40.2 12.15 129.8 11.12

09/11/2007 10:33 41.2 12.11 134.5 11.18

09/11/2007 10:34 42.6 12.14 143.9 11.26

09/11/2007 10:35 43 12.23 144.7 11.23

09/11/2007 10:36 42.7 12.19 136.7 11.13

09/11/2007 10:37 42.6 12.09 125.9 11.22

09/11/2007 10:38 42.6 12.17 124.9 11.22

09/11/2007 10:39 42.4 12.17 123.2 11.24

09/11/2007 10:40 43.3 12.26 120.5 11.28

09/11/2007 10:41 42.1 12.24 123.6 11.22

09/11/2007 10:42 41.6 12.2 128.1 11.3

09/11/2007 10:43 41.3 12.25 125.4 11.23

09/11/2007 10:44 40.4 12.23 125.6 11.19

09/11/2007 10:45 40.6 12.19 124.5 11.21

09/11/2007 10:46 40 12.15 128.7 11.19

09/11/2007 10:47 40.3 12.15 131.3 11.08

09/11/2007 10:48 40.7 12.03 138.1 11.01

09/11/2007 10:49 41.1 12 147.1 11.03

09/11/2007 10:50 42.7 12 155.3 11.1

09/11/2007 10:51 44 12.05 149.8 11.09

09/11/2007 10:52 44.1 12.05 143.1 11.13

09/11/2007 10:53 43.6 12.12 139.9 11.02

09/11/2007 10:54 42.6 11.99 143.2 11.02

09/11/2007 10:55 42.6 11.96 144 11.05

09/11/2007 10:56 41.8 12.05 137.1 11.1

09/11/2007 10:57 41.1 12.06 134.6 11.13

09/11/2007 10:58 41 12.1 128.9 11.16

09/11/2007 10:59 40.2 12.17 127.7 11.24

09/11/2007 11:00 40 12.19 124 11.14

09/11/2007 11:01 40.3 12.14 127.8 11.27

09/11/2007 11:02 40.4 12.27 127.8 11.32

09/11/2007 11:03 40.1 12.32 118.1 11.23

09/11/2007 11:04 38.7 12.24 112.9 11.28

09/11/2007 11:05 38.3 12.2 118.4 11.23

09/11/2007 11:06 38.6 12.15 125.8 11.28

09/11/2007 11:07 40.9 12.27 124.2 11.39

09/11/2007 11:08 41 12.34 116.3 11.3

09/11/2007 11:09 40.5 12.3 112.7 11.27

09/11/2007 11:10 39.6 12.23 121.7 11.18

Page 2 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 11:11 39.2 12.19 135.1 11.27

09/11/2007 11:12 40.3 12.31 136.5 11.26

09/11/2007 11:13 40.9 12.23 141.9 11.27

09/11/2007 11:14 41.7 12.28 138 11.22

09/11/2007 11:15 41.5 12.21 130.3 11.16

09/11/2007 11:16 41.5 12.17 149.6 11.08

09/11/2007 11:17 41.8 12.07 179.7 11.06

09/11/2007 11:18 42.3 12.05 173.3 11.05

09/11/2007 11:19 43 12.01 124.3 11.12

09/11/2007 11:20 43.2 12.09 106.8 11.08

09/11/2007 11:21 43.2 12.05 92.2 11.05

09/11/2007 11:22 43.5 12.09 88.6 11.11

09/11/2007 11:23 44 12.14 83.1 11.11

09/11/2007 11:24 43.7 12.11 82.2 11.08

09/11/2007 11:25 42.8 12.04 91.4 11.08

09/11/2007 11:26 42 12.14 98.1 11.18

09/11/2007 11:27 41.7 12.26 97.7 11.17

09/11/2007 11:28 40.8 12.25 96.1 11.11

09/11/2007 11:29 40.2 12.19 102.7 11.09

09/11/2007 11:30 39.4 12.14 105.3 11.17

09/11/2007 11:31 40.6 12.25 106.2 11.26

09/11/2007 11:32 41.1 12.34 104.8 11.28

09/11/2007 11:33 40.7 12.29 101.1 11.18

09/11/2007 11:34 39 12.23 107.6 11.17

09/11/2007 11:35 37.9 12.25 113.2 11.21

09/11/2007 11:36 37.8 12.29 110.2 11.26

09/11/2007 11:37 38.4 12.29 111.6 11.2

09/11/2007 11:38 38.6 12.2 109 11.07

09/11/2007 11:39 39.7 12.07 107.5 11.07

09/11/2007 11:40 41.3 12.07 106.9 11.19

09/11/2007 11:41 42.3 12.15 101.7 11.07

09/11/2007 11:42 41.4 12.03 101.3 11

09/11/2007 11:43 41.9 11.93 100.3 11

09/11/2007 11:44 41.9 11.95 99.8 11.03

09/11/2007 11:45 42.6 11.99 103.7 11.05

09/11/2007 11:46 42.8 12.03 110.2 11.09

09/11/2007 11:47 42.2 12.05 115.6 11.1

09/11/2007 11:48 41.6 12.04 120.1 11.14

09/11/2007 11:49 41.3 12.09 126.1 11.24

09/11/2007 11:50 40.2 12.21 129.1 11.13

09/11/2007 11:51 39.2 12.12 131.6 11.18

09/11/2007 11:52 38 12.15 136.1 11.17

09/11/2007 11:53 37.6 12.11 137.5 11.12

Page 3 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 11:54 39 12.05 138.4 11.06

09/11/2007 11:55 39.2 12.05 145.8 11.07

09/11/2007 11:56 39.9 12.01 133.6 11.05

09/11/2007 11:57 40.1 12.01 122.8 11.06

09/11/2007 11:58 40.8 12.02 116.4 11.05

09/11/2007 11:59 41.1 12.07 121.4 11.15

09/11/2007 12:00 40.7 12.14 125.7 11.14

09/11/2007 12:01 39.1 12.12 124.2 11.07

09/11/2007 12:02 38.2 12.07 118.7 11.07

09/11/2007 12:03 38.7 12.1 115.1 11.07

09/11/2007 12:04 39.2 12.05 116.5 11.08

09/11/2007 12:05 40.3 12.07 114.1 11.08

09/11/2007 12:06 40.4 12.08 110.7 11.03

09/11/2007 12:07 40.3 12.03 107.4 11.02

09/11/2007 12:08 41 11.98 112.4 11.01

09/11/2007 12:09 41.2 12.05 116.7 11.13

09/11/2007 12:10 41.9 12.15 117.7 11.14

09/11/2007 12:11 41.3 12.15 118.5 11.15

09/11/2007 12:12 40.4 12.09 119.6 11.15

09/11/2007 12:13 39.7 12.11 116.1 11.05

09/11/2007 12:14 38.2 12.06 108 11.03

09/11/2007 12:15 38.9 12.03 113 11.15

09/11/2007 12:16 39.6 12.1 119.3 11.15

09/11/2007 12:17 39.5 12.17 118.8 11.19

09/11/2007 12:18 38.9 12.15 114 11.15

09/11/2007 12:19 38.6 12.14 111.9 11.18

09/11/2007 12:20 38.6 12.21 112.9 11.18

09/11/2007 12:21 38.8 12.16 112.5 11.11

09/11/2007 12:22 39.1 12.09 114 11.05

09/11/2007 12:23 40.1 12.08 115.5 11.06

09/11/2007 12:24 41.7 12.09 116.4 11.13

09/11/2007 12:25 42 12.16 114.1 11.09

09/11/2007 12:26 42.2 12.1 115.6 11

09/11/2007 12:27 41.5 12.03 115.1 11.01

09/11/2007 12:28 41.8 12.05 120.3 11.09

09/11/2007 12:29 42.9 12.18 120.3 11.2

09/11/2007 12:30 42.9 12.25 122.6 11.18

09/11/2007 12:31 42.4 12.22 119.7 11.06

09/11/2007 12:32 40.3 12.09 120.5 11.05

09/11/2007 12:33 39.6 12.08 123.1 11.11

09/11/2007 12:34 39.2 12.16 123.1 11.06

09/11/2007 12:35 38.9 12.12 118.7 11.08

09/11/2007 12:36 38 12.04 118 11.03

Page 4 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 12:37 38.4 12.03 115.2 11.01

09/11/2007 12:38 38.6 12.06 114.6 11

09/11/2007 12:39 40.1 12.03 119.2 11.09

09/11/2007 12:40 40.3 12.08 126.9 11.2

09/11/2007 12:41 40.3 12.14 127.5 11.13

09/11/2007 12:42 39.4 12.13 127.2 11.09

09/11/2007 12:43 39.1 12.11 124 11.11

09/11/2007 12:44 37.8 12.14 123.5 11.05

09/11/2007 12:45 38.5 12.06 122 11.01

09/11/2007 12:46 39.7 12.01 118.1 10.91

09/11/2007 12:47 40.7 11.91 117.2 10.93

09/11/2007 12:48 41.4 11.95 119.9 11.01

09/11/2007 12:49 41.4 12.06 121 11.02

09/11/2007 12:50 41 12.03 118.6 10.99

09/11/2007 12:51 40.4 12.04 115.9 10.93

09/11/2007 12:52 40.5 12.01 113.4 10.96

09/11/2007 12:53 40.5 12.01 113.9 11.06

09/11/2007 12:54 41.4 12.07 115.3 11.1

09/11/2007 12:55 40.7 12.12 114 11.02

09/11/2007 12:56 39.2 12.07 114.6 11.08

09/11/2007 12:57 38 12.12 117.6 11.12

09/11/2007 12:58 37.4 12.18 114.1 11.11

09/11/2007 12:59 37 12.18 115.5 11.1

09/11/2007 13:00 37.3 12.14 120.5 11.16

09/11/2007 13:01 37.4 12.22 116.3 11.12

09/11/2007 13:02 36.5 12.15 109.5 11.15

09/11/2007 13:03 36.8 12.17 108.5 11.17

09/11/2007 13:04 36.7 12.19 113.4 11.09

09/11/2007 13:05 37.5 12.24 138.3 11.23

09/11/2007 13:06 37.9 12.27 146.3 11.23

09/11/2007 13:07 38.1 12.21 152.8 11.14

09/11/2007 13:08 38.4 12.09 164.4 11.09

09/11/2007 13:09 38.7 12.02 160.4 11.02

09/11/2007 13:10 39 11.97 164.1 11

09/11/2007 13:11 39 11.99 172 10.88

09/11/2007 13:12 39.9 11.88 178.2 10.88

09/11/2007 13:13 41.3 11.91 176.3 10.89

09/11/2007 13:14 42 11.94 171.3 10.89

09/11/2007 13:15 42.5 11.92 167.6 10.9

09/11/2007 13:16 42.1 11.9 163.2 10.91

09/11/2007 13:17 41.6 11.98 159.7 11

09/11/2007 13:18 40.6 12.06 158.5 11.01

09/11/2007 13:19 39.6 12.09 158.2 11.01

Page 5 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 13:20 38.8 12.09 162.3 11.11

09/11/2007 13:21 37.9 12.14 160.1 11.08

09/11/2007 13:22 37.7 12.1 155.6 11.09

09/11/2007 13:23 36.7 12.11 146.4 11.12

09/11/2007 13:24 36.3 12.17 149.1 11.14

09/11/2007 13:25 35.4 12.19 150.9 11.15

09/11/2007 13:26 35.2 12.18 161.4 11.1

09/11/2007 13:27 35.9 12.12 171.5 11.03

09/11/2007 13:28 36.1 12 177.7 10.96

09/11/2007 13:29 37.3 11.97 175.4 11.04

09/11/2007 13:30 39.1 12 156.8 11.09

09/11/2007 13:31 39.2 12.12 145.6 11.09

09/11/2007 13:32 38.2 12.14 146.8 11.02

09/11/2007 13:33 36.4 12.13 153.3 11

09/11/2007 13:34 36.6 12.08 164.7 11.02

09/11/2007 13:35 37.8 12.06 168.9 11.04

09/11/2007 13:36 39.4 12.07 161.7 11.05

09/11/2007 13:37 40.2 12.05 150.6 10.92

09/11/2007 13:38 39.7 11.96 145 10.92

09/11/2007 13:39 39.3 11.98 151.1 10.82

09/11/2007 13:40 39.3 11.91 151.1 10.87

09/11/2007 13:41 40.3 12.01 151.3 11.02

09/11/2007 13:42 41 12.11 160.7 11.07

09/11/2007 13:43 41.3 12.18 166.9 11.03

09/11/2007 13:44 41.3 12.14 167.8 11.01

09/11/2007 13:45 41.4 12.07 165.6 10.92

09/11/2007 13:46 41.4 11.96 167.4 10.88

09/11/2007 13:47 41.1 11.91 169.6 10.89

09/11/2007 13:48 41.1 11.95 164.6 10.99

09/11/2007 13:49 41.1 12.04 163.6 11.05

09/11/2007 13:50 40.7 12.08 161 10.96

09/11/2007 13:51 40.8 12.06 161.5 11.02

09/11/2007 13:52 40.1 12.12 162.2 11.06

09/11/2007 13:53 39.5 12.15 161.1 11.12

09/11/2007 13:54 39 12.17 152.6 11.14

09/11/2007 13:55 39 12.17 144.7 11.07

09/11/2007 13:56 38.1 12.15 145.8 11.04

09/11/2007 13:57 38.6 12.2 149.6 11.08

09/11/2007 13:58 38.2 12.15 157.3 11.04

09/11/2007 13:59 38.5 12.07 163.2 11

09/11/2007 14:00 39.9 12.1 155.5 11.14

09/11/2007 14:01 40.5 12.22 144.8 11.18

09/11/2007 14:02 40 12.25 140.9 11.15

Page 6 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 14:03 39.3 12.16 142.9 11.11

09/11/2007 14:04 39.1 12.2 147.2 11.12

09/11/2007 14:05 40 12.18 146.5 11.12

09/11/2007 14:06 40 12.14 149.9 11.03

09/11/2007 14:07 40.3 12.1 148.4 11

09/11/2007 14:08 40.4 12.09 144.1 11.01

09/11/2007 14:09 40.9 12.11 146.9 11.12

09/11/2007 14:10 41.4 12.16 155.2 11.16

09/11/2007 14:11 41.6 12.21 158.2 11.17

09/11/2007 14:12 41.6 12.18 151.1 11.01

09/11/2007 14:13 42 12.12 152.3 11.12

09/11/2007 14:14 41.7 12.14 152.8 11.03

09/11/2007 14:15 40.8 12.07 148.3 10.93

09/11/2007 14:16 40.8 12 153.1 10.94

09/11/2007 14:17 41.5 11.99 155.5 10.94

09/11/2007 14:18 41.8 11.95 165.3 10.95

09/11/2007 14:19 42.5 11.93 175.4 10.94

09/11/2007 14:20 42.8 11.93 176.8 10.86

09/11/2007 14:21 42.7 11.88 174.8 10.92

09/11/2007 14:22 42.5 11.95 166.2 11.06

09/11/2007 14:23 41.5 12.05 165.6 11.02

09/11/2007 14:24 40.1 12.09 166.1 11.11

09/11/2007 14:25 39.3 12.21 160.8 11.06

09/11/2007 14:26 38.5 12.11 156.6 11.02

09/11/2007 14:27 37.7 12.06 156.5 10.96

09/11/2007 14:28 37.4 11.99 160.2 10.97

09/11/2007 14:29 37.3 12.01 168.7 11.02

09/11/2007 14:30 37.5 11.99 175.4 11.08

09/11/2007 14:31 39 12.14 175.6 11.11

09/11/2007 14:32 39.2 12.1 168.4 10.96

09/11/2007 14:33 39.2 12.03 172.6 10.89

09/11/2007 14:34 39.6 11.97 174.8 10.91

09/11/2007 14:35 40.2 11.94 177.3 10.94

09/11/2007 14:36 40.6 12.01 166.3 11

09/11/2007 14:37 40.8 12 165.8 10.94

09/11/2007 14:38 40.8 11.98 170.7 11

09/11/2007 14:39 41.5 12.05 173 11.07

09/11/2007 14:40 41.6 12.05 171.9 11

09/11/2007 14:41 41.5 12 175 11.01

09/11/2007 14:42 41.2 12.02 176.8 11.03

09/11/2007 14:43 41.6 12.01 166.1 10.98

09/11/2007 14:44 41.4 12.03 157 11.09

09/11/2007 14:45 40.6 12.05 149.9 10.92

Page 7 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 14:46 40.5 12.01 153.1 10.97

09/11/2007 14:47 39.9 12.1 152.8 11.03

09/11/2007 14:48 40 12.07 156.4 11.02

09/11/2007 14:49 40.4 12.08 160.9 10.99

09/11/2007 14:50 41 12.09 160 11.07

09/11/2007 14:51 41.7 12.13 162.4 11.1

09/11/2007 14:52 41.8 12.19 158.8 11.18

09/11/2007 14:53 40.9 12.2 153.9 11.21

09/11/2007 14:54 40 12.29 145.9 11.12

09/11/2007 14:55 38 12.14 152.3 11.03

09/11/2007 14:56 37.3 12.11 160.7 11.03

09/11/2007 14:57 38 12.04 173.9 10.93

09/11/2007 14:58 39.7 11.95 185.1 10.97

09/11/2007 14:59 41.2 11.98 186.5 10.93

09/11/2007 15:00 42.8 11.97 178.1 10.94

09/11/2007 15:01 43 11.93 175.5 10.83

09/11/2007 15:02 42.8 11.88 178.8 10.86

09/11/2007 15:03 43.1 11.94 173.8 10.91

09/11/2007 15:04 42.6 12.06 170.7 11.03

09/11/2007 15:05 41.4 12.14 169.1 11.11

09/11/2007 15:06 40.5 12.17 164.6 11.13

09/11/2007 15:07 39.4 12.2 160 11.08

09/11/2007 15:08 38.5 12.14 160.7 11.09

09/11/2007 15:09 38.7 12.14 169 11.16

09/11/2007 15:10 38.5 12.21 179.2 11.14

09/11/2007 15:11 38.5 12.25 181 11.13

09/11/2007 15:12 38.6 12.22 181.9 11.17

09/11/2007 15:13 38.3 12.2 183.8 11.21

09/11/2007 15:14 38.8 12.32 178.3 11.23

09/11/2007 15:15 38.5 12.3 178.6 11.24

09/11/2007 15:16 38.2 12.31 177.7 11.22

09/11/2007 15:17 37.5 12.34 182.6 11.23

09/11/2007 15:18 37.4 12.28 190.1 11.18

09/11/2007 15:19 37.9 12.24 191.1 11.09

09/11/2007 15:20 38.8 12.15 195.5 11.11

09/11/2007 15:21 40.2 12.2 199.6 11.18

09/11/2007 15:22 40.5 12.17 208.6 11.14

09/11/2007 15:23 41.4 12.2 209 11.06

09/11/2007 15:24 42 12.12 210.8 11.04

09/11/2007 15:25 43.1 12.08 215 11.03

09/11/2007 15:26 43.5 12.06 208.6 11.1

09/11/2007 15:27 43.8 12.14 204.4 11.13

09/11/2007 15:28 43.9 12.22 203.8 11.18

Page 8 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 15:29 43.8 12.24 205.2 11.21

09/11/2007 15:30 42.7 12.29 196.1 11.21

09/11/2007 15:31 42.1 12.27 156.2 11.05

09/11/2007 15:32 41.1 12.31 102.1 10.44

09/11/2007 15:33 39.6 12.36 86.4 11

09/11/2007 15:34 38.8 12.36 77.9 11.21

09/11/2007 15:35 37.9 12.35 73.2 11.2

09/11/2007 15:36 38 12.28 70 11.14

09/11/2007 15:37 38.2 12.16 71.2 11.12

09/11/2007 15:38 39.5 12.19 65.3 11.21

09/11/2007 15:39 40.3 12.24 62.6 11.29

09/11/2007 15:40 40.6 12.27 60.8 11.31

09/11/2007 15:41 39.9 12.23 57.9 11.23

09/11/2007 15:42 40.6 12.12 57.2 11.22

09/11/2007 15:43 40.9 12.08 57.2 11.14

09/11/2007 15:44 41.7 12.01 61.5 11.1

09/11/2007 15:45 42.6 12.06 64.3 11.19

09/11/2007 15:46 43.6 12.12 63.9 11.14

09/11/2007 15:47 44.7 12.1 63.6 11.13

09/11/2007 15:48 44.8 12.13 65.3 11.1

09/11/2007 15:49 43.7 12.06 67.4 11.02

09/11/2007 15:50 43.3 11.95 65.2 10.94

09/11/2007 15:51 43 11.95 64.1 11.05

09/11/2007 15:52 43.5 12.08 66.7 11.11

09/11/2007 15:53 43 12.16 66 11.1

09/11/2007 15:54 42.4 12.14 61.8 11.07

09/11/2007 15:55 41.3 12.07 55.8 11.04

09/11/2007 15:56 40.4 12.01 57 10.97

09/11/2007 15:57 39.5 12.01 58.8 10.98

09/11/2007 15:58 39.6 12.06 60.1 11.03

09/11/2007 15:59 39.1 12.14 58.1 11

09/11/2007 16:00 38.5 12.05 58.7 10.97

09/11/2007 16:01 38.4 12.09 58.1 10.98

09/11/2007 16:02

09/11/2007 16:03

09/11/2007 16:04

09/11/2007 16:05

09/11/2007 16:06

09/11/2007 16:07

09/11/2007 16:08 34.4 12.16 69.6 11.06

09/11/2007 16:09 35.5 12.25 69.7 11.06

09/11/2007 16:10 35.8 12.22 66.5 10.97

09/11/2007 16:11 36 12.12 65.4 10.99

Page 9 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 16:12 36.3 12.17 65 10.95

09/11/2007 16:13 37 12.14 65.9 10.96

09/11/2007 16:14 37.8 12.13 67.5 11.06

09/11/2007 16:15 39.6 12.22 64.4 11.08

09/11/2007 16:16 39.7 12.2 63.6 11.01

09/11/2007 16:17 40.2 12.22 74.5 11.11

09/11/2007 16:18 40.5 12.24 86.3 10.95

09/11/2007 16:19 40.6 12.16 92.5 11.05

09/11/2007 16:20 41.2 12.13 90.5 10.96

09/11/2007 16:21 42.2 12.06 83.7 11.01

09/11/2007 16:22 43.5 12.12 72.9 10.96

09/11/2007 16:23 43.9 12.03 63.7 10.96

09/11/2007 16:24 43.9 12.06 64.5 10.93

09/11/2007 16:25 43.6 12.06 68.7 10.98

09/11/2007 16:26 43.9 12.11 68.9 11.05

09/11/2007 16:27 43.5 12.19 72.9 11.05

09/11/2007 16:28 42.8 12.23 74.5 11.12

09/11/2007 16:29 42 12.19 69.6 11.09

09/11/2007 16:30 41.1 12.2 70.2 11.13

09/11/2007 16:31 39.6 12.28 71.5 11.12

09/11/2007 16:32 38.2 12.24 75.4 11.19

09/11/2007 16:33 37.3 12.32 78.3 11.19

09/11/2007 16:34 36.5 12.36 80.6 11.19

09/11/2007 16:35 35.3 12.35 80.1 11.14

09/11/2007 16:36 35.6 12.26 81.9 11.11

09/11/2007 16:37 35.8 12.29 86.3 11.11

09/11/2007 16:38 36.1 12.23 84.9 11.01

09/11/2007 16:39 37.8 12.15 83.9 11.07

09/11/2007 16:40 38.9 12.2 80.1 11.01

09/11/2007 16:41 41.2 12.11 82.7 11.06

09/11/2007 16:42 41.7 12.19 80.3 11.08

09/11/2007 16:43 42.1 12.2 80.7 11.13

09/11/2007 16:44 42.1 12.25 81.2 11.06

09/11/2007 16:45 41.1 12.19 84 11

09/11/2007 16:46 41.4 12.17 89 11.08

09/11/2007 16:47 42 12.25 90.3 11.06

09/11/2007 16:48 42.5 12.17 92.4 11

09/11/2007 16:49 43.7 12.17 75.1 11.05

09/11/2007 16:50 44.7 12.2 73 11.12

09/11/2007 16:51 44.7 12.25 73.4 11.13

09/11/2007 16:52 44 12.29 79.1 11.16

09/11/2007 16:53 43.1 12.31 79.7 11.11

09/11/2007 16:54 41.4 12.27 82.7 11.16

Page 10 of 11
NOx and SO2 DAHS Raw Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/11/2007 16:55 41.8 12.28 88.5 11.18

09/11/2007 16:56 42 12.32 88.7 11.13

09/11/2007 16:57 41.1 12.29 89.8 11.13

09/11/2007 16:58 39.7 12.22 91.9 11.08

09/11/2007 16:59 39.6 12.16 98.4 11.09

09/11/2007 17:00 39.8 12.16 94.7 11.01

09/11/2007 17:02 41.5 12.2 71.9 11.07

09/11/2007 17:03 40.5 12.14 75.2 10.94

09/11/2007 17:04 40.6 12.03 75.1 10.98

09/11/2007 17:05 41.1 12.1 72.9 11.02

09/11/2007 17:06 42 12.2 76.3 11.12

09/11/2007 17:07 40.9 12.24 75.6 10.98

09/11/2007 17:08 40.2 12.1 76.3 10.98

09/11/2007 17:09 39.5 12.13 79.6 10.98

09/11/2007 17:10 40 12.13 81.2 11

09/11/2007 17:11 40.8 12.16 82 11

09/11/2007 17:12 40.4 12.19 80.9 11.07

09/11/2007 17:13 40.2 12.2 82.1 11.09

09/11/2007 17:14 40 12.27 86.4 11.09

09/11/2007 17:15 38.8 12.29 81.6 11.09

09/11/2007 17:16 37.5 12.17 71.2 11.01

09/11/2007 17:17 37.7 12.15 77.4 11.06

09/11/2007 17:18 38.8 12.28 80.9 11.15

09/11/2007 17:19 38.8 12.33 81.7 11.14

09/11/2007 17:20 38.3 12.26 77.3 11.09

09/11/2007 17:21 37 12.2 79.8 11

09/11/2007 17:22 37.3 12.23 78.6 11

09/11/2007 17:23 37.5 12.18 78.2 11.01

09/11/2007 17:24 38.5 12.18 81.1 11.07

09/11/2007 17:25 40.2 12.2 77.9 11.08

09/11/2007 17:26 40.4 12.24 75 11.13

NOX4 CO24 SO2_S3 CO2_S3

Averages: 40.13 12.065 125.23 11.052

Page 11 of 11
APPENDIX C 

OPERATIONS DATA 

11-SEP-2007 
PI Load Data

Plant Information Source: bbnd-1pisrv

Start Time: 09/11/2007 10:45

End Time: 09/11/2007 18:26

Time Interval: 1 min

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

Run Average: 419.9757801

11-Sep-07 10:45:00 420.0928955

11-Sep-07 10:46:00 420.6419067

11-Sep-07 10:47:00 420.3604126

11-Sep-07 10:48:00 419.1219177

11-Sep-07 10:49:00 420.2743225

11-Sep-07 10:50:00 422.2998657

11-Sep-07 10:51:00 421.8039551

11-Sep-07 10:52:00 420.8010254

11-Sep-07 10:53:00 420.4043274

11-Sep-07 10:54:00 418.7784424

11-Sep-07 10:55:00 419.8609314

11-Sep-07 10:56:00 420.3039856

11-Sep-07 10:57:00 419.1869812

11-Sep-07 10:58:00 419.0149841

11-Sep-07 10:59:00 419.3163757

11-Sep-07 11:00:00 419.2501831

11-Sep-07 11:01:00 419.675293

11-Sep-07 11:02:00 419.1463013

11-Sep-07 11:03:00 418.7470093

11-Sep-07 11:04:00 419.5724182

11-Sep-07 11:05:00 420.0872803

11-Sep-07 11:06:00 421.0819092

11-Sep-07 11:07:00 421.2866516

11-Sep-07 11:08:00 419.7177429

11-Sep-07 11:09:00 419.7495117

11-Sep-07 11:10:00 420.5492249

11-Sep-07 11:11:00 420.1605225

11-Sep-07 11:12:00 420.6737976

11-Sep-07 11:13:00 422.4465637

11-Sep-07 11:14:00 421.4935913

11-Sep-07 11:15:00 419.2740479

11-Sep-07 11:16:00 418.0357666

11-Sep-07 11:17:00 417.9744568

11-Sep-07 11:18:00 419.9758911

11-Sep-07 11:19:00 421.2580872

11-Sep-07 11:20:00 421.155426

11-Sep-07 11:21:00 420.4804077

11-Sep-07 11:22:00 419.6214294

11-Sep-07 11:23:00 419.4616394

11-Sep-07 11:24:00 420.9723206

11-Sep-07 11:25:00 420.3009338

11-Sep-07 11:26:00 419.2797546

Page 1 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 11:27:00 419.0191345

11-Sep-07 11:28:00 419.305542

11-Sep-07 11:29:00 420.6366272

11-Sep-07 11:30:00 420.7129211

11-Sep-07 11:31:00 420.3490295

11-Sep-07 11:32:00 418.9062195

11-Sep-07 11:33:00 420.4077148

11-Sep-07 11:34:00 421.3700562

11-Sep-07 11:35:00 420.6099243

11-Sep-07 11:36:00 419.2785339

11-Sep-07 11:37:00 419.3700867

11-Sep-07 11:38:00 419.8736572

11-Sep-07 11:39:00 419.4284668

11-Sep-07 11:40:00 419.8660278

11-Sep-07 11:41:00 420.2579041

11-Sep-07 11:42:00 420.6366272

11-Sep-07 11:43:00 418.824707

11-Sep-07 11:44:00 418.7989807

11-Sep-07 11:45:00 420.9093628

11-Sep-07 11:46:00 420.9769592

11-Sep-07 11:47:00 420.2780151

11-Sep-07 11:48:00 419.309082

11-Sep-07 11:49:00 419.3853455

11-Sep-07 11:50:00 420.3314209

11-Sep-07 11:51:00 420.7071838

11-Sep-07 11:52:00 420.7504883

11-Sep-07 11:53:00 421.0069885

11-Sep-07 11:54:00 419.5750122

11-Sep-07 11:55:00 420.1848755

11-Sep-07 11:56:00 420.3139954

11-Sep-07 11:57:00 421.5598145

11-Sep-07 11:58:00 420.0048828

11-Sep-07 11:59:00 419.0328064

11-Sep-07 12:00:00 418.96875

11-Sep-07 12:01:00 420.2398682

11-Sep-07 12:02:00 421.2845154

11-Sep-07 12:03:00 421.2622375

11-Sep-07 12:04:00 419.4793091

11-Sep-07 12:05:00 418.2948914

11-Sep-07 12:06:00 419.7341614

11-Sep-07 12:07:00 420.0202637

11-Sep-07 12:08:00 420.7831116

11-Sep-07 12:09:00 420.7412415

11-Sep-07 12:10:00 418.3260803

11-Sep-07 12:11:00 418.5033569

11-Sep-07 12:12:00 419.2327576

11-Sep-07 12:13:00 419.8736572

11-Sep-07 12:14:00 420.8849182

Page 2 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 12:15:00 419.0280762

11-Sep-07 12:16:00 418.6948853

11-Sep-07 12:17:00 420.4077148

11-Sep-07 12:18:00 420.8288879

11-Sep-07 12:19:00 420.3431091

11-Sep-07 12:20:00 419.5919189

11-Sep-07 12:21:00 420.4534912

11-Sep-07 12:22:00 420.5908508

11-Sep-07 12:23:00 419.8482361

11-Sep-07 12:24:00 418.8589172

11-Sep-07 12:25:00 419.533905

11-Sep-07 12:26:00 421.5216675

11-Sep-07 12:27:00 421.7093506

11-Sep-07 12:28:00 420.9709167

11-Sep-07 12:29:00 418.5892334

11-Sep-07 12:30:00 419.0343933

11-Sep-07 12:31:00 419.9078979

11-Sep-07 12:32:00 419.637146

11-Sep-07 12:33:00 419.0849304

11-Sep-07 12:34:00 420.1712036

11-Sep-07 12:35:00 420.5474854

11-Sep-07 12:36:00 419.8883972

11-Sep-07 12:37:00 418.4469299

11-Sep-07 12:38:00 418.9127502

11-Sep-07 12:39:00 420.2297058

11-Sep-07 12:40:00 421.007782

11-Sep-07 12:41:00 420.5145264

11-Sep-07 12:42:00 419.4311218

11-Sep-07 12:43:00 419.6020508

11-Sep-07 12:44:00 421.484436

11-Sep-07 12:45:00 420.0646667

11-Sep-07 12:46:00 418.4240112

11-Sep-07 12:47:00 418.4179382

11-Sep-07 12:48:00 419.776001

11-Sep-07 12:49:00 420.8807678

11-Sep-07 12:50:00 419.28302

11-Sep-07 12:51:00 419.7546387

11-Sep-07 12:52:00 420.3863525

11-Sep-07 12:53:00 421.1859436

11-Sep-07 12:54:00 421.2927856

11-Sep-07 12:55:00 420.2703857

11-Sep-07 12:56:00 418.1864014

11-Sep-07 12:57:00 419.1625671

11-Sep-07 12:58:00 419.2327576

11-Sep-07 12:59:00 420.7199707

11-Sep-07 13:00:00 420.2519226

11-Sep-07 13:01:00 419.0335083

11-Sep-07 13:02:00 418.6681824

Page 3 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 13:03:00 421.8115845

11-Sep-07 13:04:00 421.2622375

11-Sep-07 13:05:00 420.8288879

11-Sep-07 13:06:00 420.1233521

11-Sep-07 13:07:00 419.7764893

11-Sep-07 13:08:00 418.5689697

11-Sep-07 13:09:00 419.9423218

11-Sep-07 13:10:00 420.7230835

11-Sep-07 13:11:00 420.6610413

11-Sep-07 13:12:00 421.0305786

11-Sep-07 13:13:00 419.9499512

11-Sep-07 13:14:00 418.6834412

11-Sep-07 13:15:00 419.4616699

11-Sep-07 13:16:00 420.9265442

11-Sep-07 13:17:00 420.8331909

11-Sep-07 13:18:00 420.1506958

11-Sep-07 13:19:00 420.3497314

11-Sep-07 13:20:00 419.5615234

11-Sep-07 13:21:00 419.8344116

11-Sep-07 13:22:00 419.1744995

11-Sep-07 13:23:00 421.2035522

11-Sep-07 13:24:00 421.1210938

11-Sep-07 13:25:00 421.0722961

11-Sep-07 13:26:00 419.1162415

11-Sep-07 13:27:00 419.1869812

11-Sep-07 13:28:00 419.8220215

11-Sep-07 13:29:00 418.8429565

11-Sep-07 13:30:00 419.436676

11-Sep-07 13:31:00 419.8553467

11-Sep-07 13:32:00 420.5948486

11-Sep-07 13:33:00 419.4819946

11-Sep-07 13:34:00 419.3548279

11-Sep-07 13:35:00 419.5694275

11-Sep-07 13:36:00 420.0300598

11-Sep-07 13:37:00 419.8823853

11-Sep-07 13:38:00 420.030304

11-Sep-07 13:39:00 419.0458374

11-Sep-07 13:40:00 419.1183167

11-Sep-07 13:41:00 419.2098694

11-Sep-07 13:42:00 420.177948

11-Sep-07 13:43:00 419.9194336

11-Sep-07 13:44:00 419.4556885

11-Sep-07 13:45:00 419.9461365

11-Sep-07 13:46:00 420.1559448

11-Sep-07 13:47:00 419.2066956

11-Sep-07 13:48:00 421.0191956

11-Sep-07 13:49:00 420.9646912

11-Sep-07 13:50:00 420.3175049

Page 4 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 13:51:00 419.2474365

11-Sep-07 13:52:00 420.2810059

11-Sep-07 13:53:00 420.5542297

11-Sep-07 13:54:00 419.922821

11-Sep-07 13:55:00 421.6653442

11-Sep-07 13:56:00 419.9804688

11-Sep-07 13:57:00 419.3872681

11-Sep-07 13:58:00 421.0005493

11-Sep-07 13:59:00 421.0342407

11-Sep-07 14:00:00 421.5827026

11-Sep-07 14:01:00 419.6040955

11-Sep-07 14:02:00 419.3935547

11-Sep-07 14:03:00 418.8258667

11-Sep-07 14:04:00 419.3548279

11-Sep-07 14:05:00 419.2251282

11-Sep-07 14:06:00 418.8883362

11-Sep-07 14:07:00 419.9438477

11-Sep-07 14:08:00 420.1025391

11-Sep-07 14:09:00 420.5861816

11-Sep-07 14:10:00 420.0122681

11-Sep-07 14:11:00 419.8384399

11-Sep-07 14:12:00 420.941803

11-Sep-07 14:13:00 421.1554565

11-Sep-07 14:14:00 418.9743652

11-Sep-07 14:15:00 421.0486145

11-Sep-07 14:16:00 420.7036743

11-Sep-07 14:17:00 421.4649658

11-Sep-07 14:18:00 420.2463989

11-Sep-07 14:19:00 421.0264893

11-Sep-07 14:20:00 420.3771973

11-Sep-07 14:21:00 418.8869019

11-Sep-07 14:22:00 418.3477173

11-Sep-07 14:23:00 418.6681824

11-Sep-07 14:24:00 420.9234009

11-Sep-07 14:25:00 422.1201477

11-Sep-07 14:26:00 421.6517029

11-Sep-07 14:27:00 420.4763794

11-Sep-07 14:28:00 417.6152954

11-Sep-07 14:29:00 417.9781189

11-Sep-07 14:30:00 420.1818848

11-Sep-07 14:31:00 421.5500183

11-Sep-07 14:32:00 420.8241272

11-Sep-07 14:33:00 418.6787415

11-Sep-07 14:34:00 418.2573547

11-Sep-07 14:35:00 418.4819946

11-Sep-07 14:36:00 420.7945862

11-Sep-07 14:37:00 421.2266235

11-Sep-07 14:38:00 419.9602356

Page 5 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 14:39:00 419.6651306

11-Sep-07 14:40:00 420.9479065

11-Sep-07 14:41:00 419.2081299

11-Sep-07 14:42:00 418.4218445

11-Sep-07 14:43:00 420.7536011

11-Sep-07 14:44:00 420.3857727

11-Sep-07 14:45:00 420.9379883

11-Sep-07 14:46:00 420.0868225

11-Sep-07 14:47:00 420.5420227

11-Sep-07 14:48:00 421.1928711

11-Sep-07 14:49:00 421.4318237

11-Sep-07 14:50:00 420.7129211

11-Sep-07 14:51:00 418.8055115

11-Sep-07 14:52:00 418.6594543

11-Sep-07 14:53:00 419.0060425

11-Sep-07 14:54:00 418.7940674

11-Sep-07 14:55:00 420.1642761

11-Sep-07 14:56:00 421.23172

11-Sep-07 14:57:00 421.146698

11-Sep-07 14:58:00 419.2680054

11-Sep-07 14:59:00 419.7493896

11-Sep-07 15:00:00 419.5701599

11-Sep-07 15:01:00 419.095459

11-Sep-07 15:02:00 419.9499512

11-Sep-07 15:03:00 420.332428

11-Sep-07 15:04:00 420.8197327

11-Sep-07 15:05:00 419.2327576

11-Sep-07 15:06:00 419.2968445

11-Sep-07 15:07:00 419.977417

11-Sep-07 15:08:00 420.4077148

11-Sep-07 15:09:00 419.5074463

11-Sep-07 15:10:00 418.7056274

11-Sep-07 15:11:00 419.1963196

11-Sep-07 15:12:00 420.1213989

11-Sep-07 15:13:00 418.6834412

11-Sep-07 15:14:00 418.7139587

11-Sep-07 15:15:00 418.3091125

11-Sep-07 15:16:00 420.0476074

11-Sep-07 15:17:00 420.8296204

11-Sep-07 15:18:00 420.0923767

11-Sep-07 15:19:00 420.6885071

11-Sep-07 15:20:00 422.0128479

11-Sep-07 15:21:00 420.2246094

11-Sep-07 15:22:00 419.2480164

11-Sep-07 15:23:00 418.2103882

11-Sep-07 15:24:00 420.1669617

11-Sep-07 15:25:00 421.1635132

11-Sep-07 15:26:00 420.1869507

Page 6 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 15:27:00 420.2490234

11-Sep-07 15:28:00 419.1717224

11-Sep-07 15:29:00 418.9089355

11-Sep-07 15:30:00 419.8818054

11-Sep-07 15:31:00 421.302948

11-Sep-07 15:32:00 419.7439575

11-Sep-07 15:33:00 419.5450745

11-Sep-07 15:34:00 419.7319641

11-Sep-07 15:35:00 419.4902649

11-Sep-07 15:36:00 419.916687

11-Sep-07 15:37:00 419.6690979

11-Sep-07 15:38:00 419.5318298

11-Sep-07 15:39:00 420.8052368

11-Sep-07 15:40:00 420.5139771

11-Sep-07 15:41:00 419.0038757

11-Sep-07 15:42:00 419.2807007

11-Sep-07 15:43:00 418.6834412

11-Sep-07 15:44:00 420.1623535

11-Sep-07 15:45:00 419.2785339

11-Sep-07 15:46:00 420.8216248

11-Sep-07 15:47:00 420.9036255

11-Sep-07 15:48:00 420.4972534

11-Sep-07 15:49:00 419.5335999

11-Sep-07 15:50:00 418.5079651

11-Sep-07 15:51:00 418.6654053

11-Sep-07 15:52:00 419.5888367

11-Sep-07 15:53:00 419.7073059

11-Sep-07 15:54:00 420.5145569

11-Sep-07 15:55:00 419.8177185

11-Sep-07 15:56:00 419.1816101

11-Sep-07 15:57:00 420.304718

11-Sep-07 15:58:00 420.639679

11-Sep-07 15:59:00 420.3288879

11-Sep-07 16:00:00 421.4300842

11-Sep-07 16:01:00 419.8126221

11-Sep-07 16:02:00 419.9499512

11-Sep-07 16:03:00 419.4946899

11-Sep-07 16:04:00 419.8278809

11-Sep-07 16:05:00 420.868042

11-Sep-07 16:06:00 420.7892151

11-Sep-07 16:07:00 420.651886

11-Sep-07 16:08:00 421.0028381

11-Sep-07 16:09:00 420.7767334

11-Sep-07 16:10:00 419.9153748

11-Sep-07 16:11:00 419.2535706

11-Sep-07 16:12:00 420.1254272

11-Sep-07 16:13:00 418.8818054

11-Sep-07 16:14:00 419.4067383

Page 7 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 16:15:00 419.7668457

11-Sep-07 16:16:00 420.1442871

11-Sep-07 16:17:00 419.7454834

11-Sep-07 16:18:00 419.1488342

11-Sep-07 16:19:00 419.1412354

11-Sep-07 16:20:00 420.2366028

11-Sep-07 16:21:00 421.1767883

11-Sep-07 16:22:00 420.6824036

11-Sep-07 16:23:00 420.901886

11-Sep-07 16:24:00 421.4873352

11-Sep-07 16:25:00 420.7700195

11-Sep-07 16:26:00 419.9906616

11-Sep-07 16:27:00 420.1680908

11-Sep-07 16:28:00 419.9804688

11-Sep-07 16:29:00 419.0710144

11-Sep-07 16:30:00 419.3375854

11-Sep-07 16:31:00 419.5623474

11-Sep-07 16:32:00 420.7129211

11-Sep-07 16:33:00 419.5379639

11-Sep-07 16:34:00 419.4260559

11-Sep-07 16:35:00 419.5770874

11-Sep-07 16:36:00 419.801178

11-Sep-07 16:37:00 418.8480225

11-Sep-07 16:38:00 418.9091492

11-Sep-07 16:39:00 419.916748

11-Sep-07 16:40:00 420.5157471

11-Sep-07 16:41:00 420.6700745

11-Sep-07 16:42:00 418.7139587

11-Sep-07 16:43:00 419.6066284

11-Sep-07 16:44:00 419.8736572

11-Sep-07 16:45:00 419.6295166

11-Sep-07 16:46:00 420.5603027

11-Sep-07 16:47:00 420.2649536

11-Sep-07 16:48:00 420.178833

11-Sep-07 16:49:00 419.368103

11-Sep-07 16:50:00 419.1819153

11-Sep-07 16:51:00 420.4077148

11-Sep-07 16:52:00 420.098175

11-Sep-07 16:53:00 420.098175

11-Sep-07 16:54:00 418.8665466

11-Sep-07 16:55:00 420.413269

11-Sep-07 16:56:00 421.8747864

11-Sep-07 16:57:00 421.9554443

11-Sep-07 16:58:00 418.9530029

11-Sep-07 16:59:00 418.4240112

11-Sep-07 17:00:00 419.1930847

11-Sep-07 17:01:00 420.3421021

11-Sep-07 17:02:00 419.9324951

Page 8 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 17:03:00 421.9290771

11-Sep-07 17:04:00 419.6607666

11-Sep-07 17:05:00 419.5654297

11-Sep-07 17:06:00 419.1320496

11-Sep-07 17:07:00 419.2327576

11-Sep-07 17:08:00 421.3808289

11-Sep-07 17:09:00 420.4229736

11-Sep-07 17:10:00 420.8720398

11-Sep-07 17:11:00 419.3853455

11-Sep-07 17:12:00 419.1361084

11-Sep-07 17:13:00 419.3650208

11-Sep-07 17:14:00 419.5603943

11-Sep-07 17:15:00 420.3212585

11-Sep-07 17:16:00 419.6701965

11-Sep-07 17:17:00 419.4006042

11-Sep-07 17:18:00 419.125946

11-Sep-07 17:19:00 419.9470825

11-Sep-07 17:20:00 420.0476074

11-Sep-07 17:21:00 420.6881104

11-Sep-07 17:22:00 421.7522278

11-Sep-07 17:23:00 420.4382324

11-Sep-07 17:24:00 421.2406311

11-Sep-07 17:25:00 420.3687744

11-Sep-07 17:26:00 420.1063538

11-Sep-07 17:27:00 421.4949646

11-Sep-07 17:28:00 419.8761902

11-Sep-07 17:29:00 419.3744812

11-Sep-07 17:30:00 419.7210693

11-Sep-07 17:31:00 419.2098694

11-Sep-07 17:32:00 419.4268799

11-Sep-07 17:33:00 419.7317505

11-Sep-07 17:34:00 421.015564

11-Sep-07 17:35:00 419.7341614

11-Sep-07 17:36:00 419.8965454

11-Sep-07 17:37:00 420.8738403

11-Sep-07 17:38:00 418.7139587

11-Sep-07 17:39:00 419.6112061

11-Sep-07 17:40:00 420.0930786

11-Sep-07 17:41:00 419.9613953

11-Sep-07 17:42:00 419.7821045

11-Sep-07 17:43:00 419.9499512

11-Sep-07 17:44:00 419.5074463

11-Sep-07 17:45:00 421.0791321

11-Sep-07 17:46:00 419.415863

11-Sep-07 17:47:00 420.7940979

11-Sep-07 17:48:00 419.1315002

11-Sep-07 17:49:00 420.9723206

11-Sep-07 17:50:00 421.0606079

Page 9 of 10
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

11-Sep-07 17:51:00 418.9447937

11-Sep-07 17:52:00 417.6254578

11-Sep-07 17:53:00 418.3477173

11-Sep-07 17:54:00 420.8850708

11-Sep-07 17:55:00 420.4534912

11-Sep-07 17:56:00 418.5929565

11-Sep-07 17:57:00 418.0372314

11-Sep-07 17:58:00 419.4006042

11-Sep-07 17:59:00 421.5181274

11-Sep-07 18:00:00 421.3461914

11-Sep-07 18:01:00 418.0940552

11-Sep-07 18:02:00 418.7347412

11-Sep-07 18:03:00 419.6250305

11-Sep-07 18:04:00 420.4534912

11-Sep-07 18:05:00 421.6132202

11-Sep-07 18:06:00 419.8126221

11-Sep-07 18:07:00 421.7886963

11-Sep-07 18:08:00 421.2927551

11-Sep-07 18:09:00 420.2457581

11-Sep-07 18:10:00 418.8068848

11-Sep-07 18:11:00 418.6498718

11-Sep-07 18:12:00 418.6529236

11-Sep-07 18:13:00 420.1221619

11-Sep-07 18:14:00 422.3853149

11-Sep-07 18:15:00 421.3414001

11-Sep-07 18:16:00 418.8818054

11-Sep-07 18:17:00 418.4179382

11-Sep-07 18:18:00 419.0242004

11-Sep-07 18:19:00 420.2352905

11-Sep-07 18:20:00 421.1734619

11-Sep-07 18:21:00 421.1353455

11-Sep-07 18:22:00 419.6520996

11-Sep-07 18:23:00 420.4268188

11-Sep-07 18:24:00 419.7564697

11-Sep-07 18:25:00 419.8253479

11-Sep-07 18:26:00 420.2477417

Page 10 of 10
APPENDIX D 

AMMONIA SLIP TEST DATA (TRIGON ENGINEERING) 
D-1 

FTIR SPECTROMETER DATA 











D-2 

FTIR QUALITY ASSURANCE 





D-3 

FTIR METHOD MAP 







APPENDIX E 

CONTINUOUS EMISSIONS MONITORING DATA 

11-SEP-2007 
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 10:30 42.7 12.19 42.9 11.1

09/12/2007 10:31 42.8 12.3 45.7 11.18

09/12/2007 10:32 42 12.39 45.3 11.16

09/12/2007 10:33 40.8 12.26 44.5 10.99

09/12/2007 10:34 39.2 12.11 44.7 10.93

09/12/2007 10:35 40.3 12.06 48.5 10.98

09/12/2007 10:36 41.5 12.09 51.4 11.05

09/12/2007 10:37 42.7 12.26 49.5 11.1

09/12/2007 10:38 42.1 12.3 49.6 11.11

09/12/2007 10:39 40.3 12.18 51.1 11

09/12/2007 10:40 40 12.11 52 10.93

09/12/2007 10:41 39.9 12.1 53.3 10.96

09/12/2007 10:42 40.5 12.17 55.5 11.11

09/12/2007 10:43 41.3 12.26 54.4 11.12

09/12/2007 10:44 40.7 12.24 46.3 11.01

09/12/2007 10:45 39.8 12.11 40 10.98

09/12/2007 10:46 41 12.13 39.1 11.01

09/12/2007 10:47 42.5 12.18 40.5 11.08

09/12/2007 10:48 42.7 12.21 40.8 11.11

09/12/2007 10:49 44.1 12.26 40.5 11.14

09/12/2007 10:50 43 12.31 42.3 11.09

09/12/2007 10:51 42.7 12.26 43 11.14

09/12/2007 10:52 42.1 12.29 44.9 11.06

09/12/2007 10:53 41.2 12.29 46.4 11.1

09/12/2007 10:54 39.7 12.31 45.3 11.04

09/12/2007 10:55 38.8 12.17 46.7 10.97

09/12/2007 10:56 38.3 12.06 47.4 10.84

09/12/2007 10:57 39 12 49.5 10.88

09/12/2007 10:58 40.2 12.09 51 10.92

09/12/2007 10:59 41.1 12.04 53.9 10.85

09/12/2007 11:00 42.2 11.98 56.9 10.91

09/12/2007 11:01 43.4 12.03 57.1 10.89

09/12/2007 11:02 43.5 12.05 54.6 10.96

09/12/2007 11:03 43.8 12.12 48.9 11.02

09/12/2007 11:04 43 12.16 45 11.03

09/12/2007 11:05 42.5 12.11 44.4 11

09/12/2007 11:06 42.9 12.17 45.3 11.09

09/12/2007 11:07 42.9 12.25 45.6 11.09

09/12/2007 11:08 42.7 12.23 45.2 11.08

09/12/2007 11:09 41.2 12.2 46.1 11.02

09/12/2007 11:10 40.3 12.16 45.9 11.02

09/12/2007 11:11 40.3 12.16 42.5 11.04

09/12/2007 11:12 40.6 12.17 39.9 10.97

Page 1 of 6
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 11:13 40.2 12.16 37.8 10.91

09/12/2007 11:14 40.1 12.04 40.1 10.98

09/12/2007 11:15 40.7 12.16 41.6 11.01

09/12/2007 11:16 41.5 12.16 42.1 10.99

09/12/2007 11:17 41.3 12.16 43.1 10.98

09/12/2007 11:18 41.5 12.17 44.5 10.94

09/12/2007 11:19 41.5 12.06 46.6 10.89

09/12/2007 11:20 41.9 12.09 48.8 10.98

09/12/2007 11:21 41.2 12.19 49.1 10.96

09/12/2007 11:22 40 12.11 50.4 10.91

09/12/2007 11:23 40.3 12.14 51.8 10.99

09/12/2007 11:24 40.5 12.17 53.1 10.98

09/12/2007 11:25 40.2 12.16 52.8 10.96

09/12/2007 11:26 39.5 12.19 51.7 10.92

09/12/2007 11:27 39.4 12.11 50.5 10.93

09/12/2007 11:28 39.3 12.09 50.3 10.84

09/12/2007 11:29 40.5 12.03 50.7 10.89

09/12/2007 11:30 41.7 12.11 51.7 11.05

09/12/2007 11:31 42.3 12.25 45.5 11.02

09/12/2007 11:32 42.5 12.22 39.5 11.12

09/12/2007 11:33 41.6 12.22 37.1 10.97

09/12/2007 11:34 40.4 12.17 39.2 11.02

09/12/2007 11:35 42 12.27 41.6 11.14

09/12/2007 11:36 41.1 12.34 41.1 11.09

09/12/2007 11:37 39.8 12.29 41.2 11.02

09/12/2007 11:38 39.2 12.23 42.8 11.04

09/12/2007 11:39 38.4 12.19 46.2 10.94

09/12/2007 11:40 38.7 12.16 47.1 10.96

09/12/2007 11:41 39.5 12.16 47.3 10.99

09/12/2007 11:42 40.4 12.24 48.1 11.04

09/12/2007 11:43 40.6 12.26 49.6 11.05

09/12/2007 11:44 39.8 12.2 50 10.98

09/12/2007 11:45 39.8 12.16 51.9 10.95

09/12/2007 11:46 40.3 12.12 55.1 10.92

09/12/2007 11:47 42 12.15 57.5 10.99

09/12/2007 11:48 42.3 12.19 55.2 11.06

09/12/2007 11:49 42.6 12.23 51.9 11.08

09/12/2007 11:50 43.2 12.2 49.8 11.09

09/12/2007 11:51 42.6 12.23 44.9 11.08

09/12/2007 11:52 42.2 12.21 40.5 11.07

09/12/2007 11:53 41.4 12.26 38.6 11.06

09/12/2007 11:54 40.8 12.21 39.5 11.02

09/12/2007 11:55 40.1 12.15 40.9 10.94

Page 2 of 6
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 11:56 40.8 12.11 42.7 10.96

09/12/2007 11:57 41.4 12.19 43.6 11

09/12/2007 11:58 41.3 12.17 44.8 10.95

09/12/2007 11:59 42.5 12.24 47.1 11.12

09/12/2007 12:00 42.9 12.35 47.6 11.21

09/12/2007 12:01 42.5 12.4 45.6 11.24

09/12/2007 12:02 40.2 12.38 45.6 11.14

09/12/2007 12:03 38.3 12.27 48.6 11.09

09/12/2007 12:04 37.9 12.28 52 11.1

09/12/2007 12:05 37.6 12.32 51.9 11.01

09/12/2007 12:06 37.2 12.16 52.1 10.92

09/12/2007 12:07 38.1 12.01 52.8 10.82

09/12/2007 12:08 39.7 11.95 53.6 10.73

09/12/2007 12:09 41.6 11.91 53.2 10.69

09/12/2007 12:10 44.2 11.9 53.1 10.84

09/12/2007 12:11 46.4 11.95 50 10.83

09/12/2007 12:12 47.5 11.94 44.5 10.89

09/12/2007 12:13 47.5 11.96 41.1 10.93

09/12/2007 12:14 47 12 41.2 10.95

09/12/2007 12:15 46.6 12.04 41.6 10.96

09/12/2007 12:16 45.7 12.12 41.8 10.99

09/12/2007 12:17 44.6 12.14 43.7 11.01

09/12/2007 12:18 43.2 12.18 45.7 11.04

09/12/2007 12:19 42.3 12.19 49 11.09

09/12/2007 12:20 40.6 12.27 50.8 11.07

09/12/2007 12:21 39.1 12.23 50.7 10.99

09/12/2007 12:22 38.7 12.17 51.9 10.98

09/12/2007 12:23 39 12.21 54.1 11.05

09/12/2007 12:24 38.5 12.22 54.8 11.04

09/12/2007 12:25 39.2 12.19 49.6 11.06

09/12/2007 12:26 38.4 12.27 45.2 11.08

09/12/2007 12:27 38.3 12.28 43.7 11.06

09/12/2007 12:28 38.1 12.28 43.5 11.06

09/12/2007 12:29 37.3 12.26 43.2 11.04

09/12/2007 12:30 37.2 12.19 44.2 11.05

09/12/2007 12:31 37.6 12.22 45.6 11.11

09/12/2007 12:32 38.2 12.19 47.5 10.98

09/12/2007 12:33 39.8 12.2 48.2 11.04

09/12/2007 12:34 40 12.21 45.4 11.04

09/12/2007 12:35 40.9 12.23 42.2 11.02

09/12/2007 12:36 40.5 12.17 42.1 10.98

09/12/2007 12:37 40.8 12.14 44.9 11

09/12/2007 12:38 41.4 12.18 45.9 11.01

Page 3 of 6
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 12:39 41.7 12.23 47 10.99

09/12/2007 12:40 42.1 12.2 49.5 10.98

09/12/2007 12:41 42.1 12.19 50.9 10.93

09/12/2007 12:42 42.5 12.13 51.1 10.96

09/12/2007 12:43 43.3 12.1 52.1 10.97

09/12/2007 12:44 43.8 12.16 55.2 10.98

09/12/2007 12:45 44.9 12.24 51.3 10.98

09/12/2007 12:46 43.7 12.19 45.4 11.01

09/12/2007 12:47 43.6 12.28 43.7 11.06

09/12/2007 12:48 42.1 12.22 43.1 11.01

09/12/2007 12:49 42.3 12.2 43.4 11.08

09/12/2007 12:50 41.6 12.29 43.2 11.09

09/12/2007 12:51 40.8 12.28 43.7 11.05

09/12/2007 12:52 40.1 12.22 45.8 11.07

09/12/2007 12:53 40.7 12.24 44.5 11.06

09/12/2007 12:54 41.1 12.26 42 11

09/12/2007 12:55 41.2 12.11 41.2 10.96

09/12/2007 12:56 42.1 12.13 43.2 10.97

09/12/2007 12:57 43.1 12.19 45.7 10.98

09/12/2007 12:58 42.5 12.2 46.1 10.97

09/12/2007 12:59 42 12.2 48.5 10.99

09/12/2007 13:00 41.8 12.27 49.6 11.01

09/12/2007 13:01 41.9 12.22 50.8 11.06

09/12/2007 13:02 41.7 12.28 50.4 11

09/12/2007 13:03 41.1 12.18 51.3 10.9

09/12/2007 13:04 41.4 12.11 54.1 10.92

09/12/2007 13:05 42 12.17 57.1 10.99

09/12/2007 13:06 42.4 12.17 57.7 10.91

09/12/2007 13:07 43.3 12.09 52.1 10.93

09/12/2007 13:08 43.4 12.1 44.5 10.97

09/12/2007 13:09 43.3 12.11 41.9 10.94

09/12/2007 13:10 43 12.02 35.9 10.85

09/12/2007 13:11 43.9 11.93 30.1 10.77

09/12/2007 13:12 44.1 12.05 28.4 10.82

09/12/2007 13:13 43.8 12.09 28.7 10.75

09/12/2007 13:14 43.8 12.09 29.5 10.73

09/12/2007 13:15 43.6 12.04 30.3 10.68

09/12/2007 13:16 44 12.03 31.3 10.73

09/12/2007 13:17 43.6 12.11 32.8 10.81

09/12/2007 13:18 43 12.21 33.8 10.81

09/12/2007 13:19 42.3 12.25 34.5 10.82

09/12/2007 13:20 41.7 12.21 36.5 10.87

09/12/2007 13:21 40.6 12.25 37.5 10.84

Page 4 of 6
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 13:22 39.9 12.2 40.9 10.85

09/12/2007 13:23 41.5 12.27 42.3 10.92

09/12/2007 13:24 40.8 12.4 40.9 10.9

09/12/2007 13:25 39.4 12.3 36 10.84

09/12/2007 13:26 38.3 12.18 33.4 10.46

09/12/2007 13:27 38.3 12.17 32.6 10.29

09/12/2007 13:28 39.2 12.14 32.1 10.11

09/12/2007 13:29 39.6 12.17 31.1 10.01

09/12/2007 13:30 40.7 12.19 31.9 9.93

09/12/2007 13:31 41 12.19 32 9.92

09/12/2007 13:32 41 12.11 33.4 9.77

09/12/2007 13:33 41.2 12.07 35.5 9.82

09/12/2007 13:34 41.9 12.03 35.7 9.9

09/12/2007 13:35 42.2 12.09 36.1 9.93

09/12/2007 13:36 42.2 12.18 36.1 10.01

09/12/2007 13:37 42.8 12.13 37.1 9.96

09/12/2007 13:38 43.2 12.22 37.4 10.04

09/12/2007 13:39 42.3 12.22 36.1 10

09/12/2007 13:40 42.1 12.17 35.5 10

09/12/2007 13:41 41.5 12.19 36.1 10.11

09/12/2007 13:42 40.9 12.23 33.9 10.33

09/12/2007 13:43 41.5 12.29 32.8 10.63

09/12/2007 13:44 41.5 12.36 33.2 10.83

09/12/2007 13:45 40.6 12.35 33.3 10.85

09/12/2007 13:46 39.3 12.33 31.1 10.83

09/12/2007 13:47 38.2 12.21 32.6 10.83

09/12/2007 13:48 38.6 12.21 41.1 10.84

09/12/2007 13:49 39 12.2 46.1 10.91

09/12/2007 13:50 40.6 12.09 49 10.92

09/12/2007 13:51 42.4 12.19 50 11.05

09/12/2007 13:52 43.4 12.3 48 11.05

09/12/2007 13:53 43.6 12.23 48.5 11.07

09/12/2007 13:54 43 12.29 48.9 11.03

09/12/2007 13:55 42.2 12.23 51.5 10.94

09/12/2007 13:56 41 12.19 51.2 10.99

09/12/2007 13:57 41.5 12.22 52.4 10.97

09/12/2007 13:58 41.3 12.24 51.6 11.04

09/12/2007 13:59 41 12.26 51.6 11

09/12/2007 14:00 41.5 12.15 54 10.97

09/12/2007 14:01 41.9 12.12 54.1 11

09/12/2007 14:02 42.1 12.08 53.8 10.98

09/12/2007 14:03 43.6 12.14 50.4 11.01

09/12/2007 14:04 44.3 12.13 43.5 11.01

Page 5 of 6
Ammonia CEMS Data

Date Time NOX4 CO24 SO2_S3 CO2_S3

09/12/2007 14:05 43.8 12.17 39.1 10.99

09/12/2007 14:06 42.7 12.02 39.4 10.93

09/12/2007 14:07 42.7 12.1 41.1 10.98

09/12/2007 14:08 42.8 12.19 44 11.04

09/12/2007 14:09 42.2 12.24 45.5 11.07

09/12/2007 14:10 41.3 12.25 46.4 11.05

09/12/2007 14:11 40.3 12.27 46.8 11.06

09/12/2007 14:12 39.6 12.23 49.8 11.01

09/12/2007 14:13 39.8 12.28 48.6 11.07

09/12/2007 14:14 39.1 12.23 46.2 10.91

09/12/2007 14:15 39.5 12.11 46.7 10.93

09/12/2007 14:16 40.8 12.12 47.7 10.91

09/12/2007 14:17 42.4 12.12 50.5 10.93

09/12/2007 14:18 42.8 12.15 49.9 10.93

09/12/2007 14:19 42.8 12.1 50.2 10.93

09/12/2007 14:20 43 12.05 50.1 10.84

09/12/2007 14:21 42.6 11.97 49.8 10.87

09/12/2007 14:22 42.7 12.03 41.8 10.92

09/12/2007 14:23 43 12.05 39.1 10.89

09/12/2007 14:24 43.8 12.11 40.5 11.03

09/12/2007 14:25 43.2 12.22 40.4 11.05

09/12/2007 14:26 42.5 12.23 42.2 11.1

09/12/2007 14:27 41.9 12.34 43.3 11.11

09/12/2007 14:28 39.8 12.3 44.8 11.04

09/12/2007 14:29 38.9 12.29 47.3 11.1

09/12/2007 14:30 37.8 12.39 49.9 11.06

09/12/2007 14:31 36.8 12.33 51.4 11.03

09/12/2007 14:32 36.1 12.26 51 10.95

09/12/2007 14:33 37.2 12.23 48.9 10.95

09/12/2007 14:34 37.2 12.18 49.2 10.93

09/12/2007 14:35 38.5 12.15 51.8 10.94

09/12/2007 14:36 39.5 12.21 53.2 10.92

09/12/2007 14:37 40 12.16 53.7 10.93

41.3065 12.179 45.23831 10.91706

Page 6 of 6
APPENDIX F 

OPERATIONS DATA 

12-SEP-2007 
PI Load Data

Plant Information Source: bbnd-1pisrv

Start Time: 09/12/2007 11:30

End Time: 09/12/2007 15:37

Time Interval: 1 min

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

Run Average: 410.051045

12-Sep-07 11:30:00 409.828369

12-Sep-07 11:31:00 410.450043

12-Sep-07 11:32:00 411.259796

12-Sep-07 11:33:00 410.753906

12-Sep-07 11:34:00 410.204193

12-Sep-07 11:35:00 409.387512

12-Sep-07 11:36:00 409.535522

12-Sep-07 11:37:00 410.153503

12-Sep-07 11:38:00 411.368134

12-Sep-07 11:39:00 410.748077

12-Sep-07 11:40:00 408.400024

12-Sep-07 11:41:00 408.490234

12-Sep-07 11:42:00 410.565521

12-Sep-07 11:43:00 411.158783

12-Sep-07 11:44:00 411.21405

12-Sep-07 11:45:00 410.041321

12-Sep-07 11:46:00 409.921417

12-Sep-07 11:47:00 409.390564

12-Sep-07 11:48:00 409.745667

12-Sep-07 11:49:00 409.214386

12-Sep-07 11:50:00 410.174133

12-Sep-07 11:51:00 409.10498

12-Sep-07 11:52:00 409.634705

12-Sep-07 11:53:00 409.438019

12-Sep-07 11:54:00 409.461121

12-Sep-07 11:55:00 410.275574

12-Sep-07 11:56:00 410.405273

12-Sep-07 11:57:00 410.357605

12-Sep-07 11:58:00 410.361267

12-Sep-07 11:59:00 409.822632

12-Sep-07 12:00:00 409.858032

12-Sep-07 12:01:00 410.130859

12-Sep-07 12:02:00 410.956696

12-Sep-07 12:03:00 410.236084

12-Sep-07 12:04:00 409.431244

12-Sep-07 12:05:00 409.511658

12-Sep-07 12:06:00 410.142365

12-Sep-07 12:07:00 409.809082

12-Sep-07 12:08:00 409.998871

12-Sep-07 12:09:00 409.270233

12-Sep-07 12:10:00 409.789551

12-Sep-07 12:11:00 410.207672

Page 1 of 6
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

12-Sep-07 12:12:00 409.725708

12-Sep-07 12:13:00 410.248108

12-Sep-07 12:14:00 409.908722

12-Sep-07 12:15:00 410.512268

12-Sep-07 12:16:00 410.519714

12-Sep-07 12:17:00 410.016174

12-Sep-07 12:18:00 410.30838

12-Sep-07 12:19:00 410.009644

12-Sep-07 12:20:00 410.458679

12-Sep-07 12:21:00 409.375275

12-Sep-07 12:22:00 408.828491

12-Sep-07 12:23:00 409.81723

12-Sep-07 12:24:00 410.298981

12-Sep-07 12:25:00 411.252167

12-Sep-07 12:26:00 410.873047

12-Sep-07 12:27:00 410.742767

12-Sep-07 12:28:00 409.35495

12-Sep-07 12:29:00 409.624512

12-Sep-07 12:30:00 410.408325

12-Sep-07 12:31:00 410.901215

12-Sep-07 12:32:00 410.118622

12-Sep-07 12:33:00 409.043274

12-Sep-07 12:34:00 408.433563

12-Sep-07 12:35:00 409.295929

12-Sep-07 12:36:00 411.106293

12-Sep-07 12:37:00 411.174988

12-Sep-07 12:38:00 411.590942

12-Sep-07 12:39:00 410.458679

12-Sep-07 12:40:00 408.937744

12-Sep-07 12:41:00 408.948029

12-Sep-07 12:42:00 410.306091

12-Sep-07 12:43:00 411.54718

12-Sep-07 12:44:00 411.103943

12-Sep-07 12:45:00 409.616028

12-Sep-07 12:46:00 409.454437

12-Sep-07 12:47:00 409.661133

12-Sep-07 12:48:00 410.867493

12-Sep-07 12:49:00 409.861298

12-Sep-07 12:50:00 409.546112

12-Sep-07 12:51:00 410.00177

12-Sep-07 12:52:00 410.15271

12-Sep-07 12:53:00 410.479462

12-Sep-07 12:54:00 410.370514

12-Sep-07 12:55:00 411.656921

12-Sep-07 12:56:00 412.563843

12-Sep-07 12:57:00 410.307556

12-Sep-07 12:58:00 408.024261

12-Sep-07 12:59:00 408.733643

Page 2 of 6
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

12-Sep-07 13:00:00 409.706207

12-Sep-07 13:01:00 409.253204

12-Sep-07 13:02:00 408.626434

12-Sep-07 13:03:00 408.9617

12-Sep-07 13:04:00 409.297089

12-Sep-07 13:05:00 409.822906

12-Sep-07 13:06:00 410.090302

12-Sep-07 13:07:00 410.359497

12-Sep-07 13:08:00 411.122009

12-Sep-07 13:09:00 410.860535

12-Sep-07 13:10:00 410.368011

12-Sep-07 13:11:00 409.973267

12-Sep-07 13:12:00 410.709381

12-Sep-07 13:13:00 410.420807

12-Sep-07 13:14:00 410.771332

12-Sep-07 13:15:00 410.193634

12-Sep-07 13:16:00 409.34549

12-Sep-07 13:17:00 410.16571

12-Sep-07 13:18:00 410.611298

12-Sep-07 13:19:00 410.473938

12-Sep-07 13:20:00 410.224243

12-Sep-07 13:21:00 410.104675

12-Sep-07 13:22:00 411.191132

12-Sep-07 13:23:00 410.293457

12-Sep-07 13:24:00 409.434143

12-Sep-07 13:25:00 408.937866

12-Sep-07 13:26:00 409.453918

12-Sep-07 13:27:00 409.320343

12-Sep-07 13:28:00 410.500458

12-Sep-07 13:29:00 410.91748

12-Sep-07 13:30:00 411.042053

12-Sep-07 13:31:00 410.107727

12-Sep-07 13:32:00 409.344757

12-Sep-07 13:33:00 410.026337

12-Sep-07 13:34:00 410.739655

12-Sep-07 13:35:00 408.917511

12-Sep-07 13:36:00 408.734406

12-Sep-07 13:37:00 409.334595

12-Sep-07 13:38:00 409.461334

12-Sep-07 13:39:00 409.985657

12-Sep-07 13:40:00 410.926422

12-Sep-07 13:41:00 410.271515

12-Sep-07 13:42:00 409.018768

12-Sep-07 13:43:00 409.646149

12-Sep-07 13:44:00 411.402069

12-Sep-07 13:45:00 409.914856

12-Sep-07 13:46:00 410.153503

12-Sep-07 13:47:00 409.284332

Page 3 of 6
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

12-Sep-07 13:48:00 409.969086

12-Sep-07 13:49:00 409.909363

12-Sep-07 13:50:00 409.790344

12-Sep-07 13:51:00 410.214539

12-Sep-07 13:52:00 410.084839

12-Sep-07 13:53:00 410.802246

12-Sep-07 13:54:00 409.509796

12-Sep-07 13:55:00 409.376373

12-Sep-07 13:56:00 409.999207

12-Sep-07 13:57:00 410.857788

12-Sep-07 13:58:00 409.691925

12-Sep-07 13:59:00 409.505005

12-Sep-07 14:00:00 411.114838

12-Sep-07 14:01:00 409.860809

12-Sep-07 14:02:00 409.733887

12-Sep-07 14:03:00 409.896271

12-Sep-07 14:04:00 409.649963

12-Sep-07 14:05:00 410.290833

12-Sep-07 14:06:00 409.945343

12-Sep-07 14:07:00 410.27948

12-Sep-07 14:08:00 410.931732

12-Sep-07 14:09:00 409.627075

12-Sep-07 14:10:00 409.653351

12-Sep-07 14:11:00 409.879547

12-Sep-07 14:12:00 411.180969

12-Sep-07 14:13:00 411.123352

12-Sep-07 14:14:00 410.972412

12-Sep-07 14:15:00 409.936066

12-Sep-07 14:16:00 409.415497

12-Sep-07 14:17:00 410.456055

12-Sep-07 14:18:00 411.358978

12-Sep-07 14:19:00 410.996277

12-Sep-07 14:20:00 410.530823

12-Sep-07 14:21:00 408.945679

12-Sep-07 14:22:00 409.512634

12-Sep-07 14:23:00 409.283722

12-Sep-07 14:24:00 410.154694

12-Sep-07 14:25:00 410.266418

12-Sep-07 14:26:00 410.412903

12-Sep-07 14:27:00 409.164703

12-Sep-07 14:28:00 409.009064

12-Sep-07 14:29:00 410.439484

12-Sep-07 14:30:00 410.153503

12-Sep-07 14:31:00 410.683777

12-Sep-07 14:32:00 410.28067

12-Sep-07 14:33:00 410.724091

12-Sep-07 14:34:00 410.042267

12-Sep-07 14:35:00 409.833069

Page 4 of 6
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

12-Sep-07 14:36:00 410.061951

12-Sep-07 14:37:00 410.370331

12-Sep-07 14:38:00 410.865265

12-Sep-07 14:39:00 410.715576

12-Sep-07 14:40:00 411.343719

12-Sep-07 14:41:00 409.787292

12-Sep-07 14:42:00 408.261353

12-Sep-07 14:43:00 409.151886

12-Sep-07 14:44:00 408.970917

12-Sep-07 14:45:00 409.955139

12-Sep-07 14:46:00 409.496033

12-Sep-07 14:47:00 410.606201

12-Sep-07 14:48:00 411.090424

12-Sep-07 14:49:00 410.458679

12-Sep-07 14:50:00 408.663361

12-Sep-07 14:51:00 409.291351

12-Sep-07 14:52:00 411.008026

12-Sep-07 14:53:00 410.204895

12-Sep-07 14:54:00 411.062683

12-Sep-07 14:55:00 409.716248

12-Sep-07 14:56:00 408.766083

12-Sep-07 14:57:00 409.629608

12-Sep-07 14:58:00 410.200653

12-Sep-07 14:59:00 410.537537

12-Sep-07 15:00:00 410.269043

12-Sep-07 15:01:00 408.856476

12-Sep-07 15:02:00 409.158142

12-Sep-07 15:03:00 410.63092

12-Sep-07 15:04:00 411.282684

12-Sep-07 15:05:00 410.641815

12-Sep-07 15:06:00 411.174805

12-Sep-07 15:07:00 409.461975

12-Sep-07 15:08:00 410.138245

12-Sep-07 15:09:00 409.360046

12-Sep-07 15:10:00 409.384674

12-Sep-07 15:11:00 409.222717

12-Sep-07 15:12:00 410.261688

12-Sep-07 15:13:00 410.44342

12-Sep-07 15:14:00 411.08432

12-Sep-07 15:15:00 409.138763

12-Sep-07 15:16:00 408.596283

12-Sep-07 15:17:00 409.105316

12-Sep-07 15:18:00 409.572266

12-Sep-07 15:19:00 410.827698

12-Sep-07 15:20:00 411.474548

12-Sep-07 15:21:00 411.175873

12-Sep-07 15:22:00 410.997681

12-Sep-07 15:23:00 410.904602

Page 5 of 6
PI Load Data

Tag Name: 4spuw501g

Tag Explanation: Unit Load

Tag Units: Mwe

12-Sep-07 15:24:00 408.449554

12-Sep-07 15:25:00 408.807556

12-Sep-07 15:26:00 409.569855

12-Sep-07 15:27:00 409.092133

12-Sep-07 15:28:00 409.673676

12-Sep-07 15:29:00 410.018341

12-Sep-07 15:30:00 409.24884

12-Sep-07 15:31:00 409.360046

12-Sep-07 15:32:00 410.155792

12-Sep-07 15:33:00 410.042328

12-Sep-07 15:34:00 411.191132

12-Sep-07 15:35:00 410.95755

12-Sep-07 15:36:00 410.763885

12-Sep-07 15:37:00 409.92099

Page 6 of 6
APPENDIX G 

FUEL INFORMATION 
G-1 

BUNKERING INFORMATION 11-SEP-2007 
BIG BEND STATION

FUEL BUNKERING INFORMATION

RUN TIME Tons % Tons % Tons % 

9/10/07 9:58 PM 103 12.4% 4 0.5% 726 87.2% 9/11/07 1:00 AM 31 9.6% 0 0.0% 291 90.4% 9/11/07 4:35 AM 34 9.8% 9 2.6% 304 87.6% 

9/11/07 11:15 AM 129 10.8% 29 2.4% 1035 86.8% 

9/11/07 5:13 PM 0 0.0% 2 0.3% 781 99.7% 

TOTAL 297 8.5% 44.0 1.3% 3137.0 90.2% 

Note: Last test run, run #3, was completed at 6:28 PM

PET COKE POLK RESIDUAL COAL STANDARD COAL
G-2 

FUEL ANALYSIS 
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Report For:

Laboratory ID: AA90279

Date and Time Collected:

Sampled By:

Sample Information

Description ASG

Location Code:

Report Date: 10/19/2007

Big Bend 4 Compliance

TE_BB_4_COMP_COAL

Project Account Code:

Sample Collection Method: Date of Sample Receipt: 9/12/2007

Laboratory Results

9/11/2007 12:00:00 AM

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

60 Mesh Residual Moisture, Coal 4.28 % ASTM D-5142 KAPXJ 9/19/2007 11:26:00 AM

Ash, as Received 8.91 % 0.01 ASTM D-3174 KAPXJ 9/20/2007 11:10:00 AM

Ash, Dry Basis 9.95 % 0.01 ASTM D-3174 KAPXJ 9/20/2007 11:10:00 AM

BTU, as Received 11769 BTU/Lb 100 ASTM D-5865 KAPXJ 9/20/2007 11:09:00 AM

BTU, Dry Basis 13139 BTU/Lb. 100 ASTM D-5865 KAPXJ 9/20/2007 11:09:00 AM

BTU, Moisture-Ash Free 14591 BTU/Lb. 100 ASTM D-5865 KAPXJ 9/20/2007 11:10:00 AM

Carbon, as Received 66.81 % 0.5 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Carbon, Dry Basis 74.59 % 0.5 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Chlorine as Cl, as Received 0.15 % 0.01 ASTM4208/300 KASZS 9/26/2007 9:51:00 AM

Chlorine as Cl, Dry Basis 0.17 % 0.01 ASTM4208/300 KASZS 9/26/2007 9:51:00 AM

Hydrogen, as Received 4.33 % 0.14 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Hydrogen, Dry Basis 4.83 % 0.14 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Nitrogen, as Received 1.41 % 0.10 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Nitrogen, Dry Basis 1.57 % 0.10 ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

NOx emission rate, lb/mmBtu 0.07 lb/mmBtu EPA RM-7E KARAM 9/19/2007 9:06:00 AM

NOx emission rate, lbs/hr 305 lbs/hr EPA RM-7E KARAM 9/19/2007 9:06:00 AM

Oxygen, as Received 5.04 % ASTM D-5373 KASZS 9/26/2007 9:46:00 AM

Oxygen, Dry Basis 5.63 % Calculated KASZS 9/26/2007 9:46:00 AM

Particulate Wt., Acetone Beaker, Run 1 15.45 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 2 14.80 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 3 15.25 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 1 4.25 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 2 2.65 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 3 3.15 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 1 19.70 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 2 17.45 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

Report Number: Page 1 of 2 "General Report" AA90279-101907-09
Laboratory Services

5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

PARAMETER Result

Qualifier

Code

Test

Method Analyst Units

Upper

MDL Limit

Violation

Check

Analysis

Date & Time

Lower

Limit

Particulate Wt., Total Sample, Run 3 18.40 mg 0.0001 EPA Method 5B/17KARAM 9/19/2007 9:06:00 AM

PM, lb/mmBtu 0.01 lb/mmBtu EPA RM-5/17 KARAM 9/19/2007 9:06:00 AM

Pounds SO2 / Million BTU Lbs. 

SO2/MMBTU

4.71 Calculated KAPXJ 9/19/2007 12:57:00 PM

SO2 emission rate, lbs/hr 1445 lbs/hr EPA - RM6C KARAM 9/19/2007 9:06:00 AM

SO2 emission rate, lbs/mmBtu 0.34 lbs/mmBtu EPA - RM6C KARAM 9/19/2007 9:06:00 AM

Sulfur, as Received 2.92 % 0.02 ASTM D-4239 KAPXJ 9/20/2007 11:09:00 AM

Sulfur, Dry Basis 3.26 % 0.08 ASTM D-4239 KAPXJ 9/20/2007 11:09:00 AM

Total Moisture 10.43 % 0.1 ASTM D-3173 KAPXJ 9/20/2007 11:08:00 AM

Comments

Designee for Peggy Penner,

Manager, Laboratory Services

All results calculated on a wet to wet basis, unless otherwise indicated.

Should there be any questions regarding this report, please contact:

(813) 630-7490

Mirey A. Makaryus,

Report Number: Page 2 of 2 "General Report" AA90279-101907-09
G-3 

PRECIPITATOR LOGS 11-SEP-2007 




G-4 

BUNKERING INFORMATION 12 SEP-2007 
BIG BEND STATION

FUEL BUNKERING INFORMATION

PET COKE POLK RESIDUAL COAL STANDARD COAL 

BUNKER RUN TIME Tons % Tons % Tons % 

9/11/07 10:00 PM 81.6 10.4% 2 0.3% 697.4 89.3% 

9/12/07 1:15 AM 77.4 10.4% 30.6 4.1% 636.1 85.5% 9/12/07 4:40 AM 64.9 10.0% 29.1 4.5% 553.1 85.5% 

9/12/07 12:45 PM 142.7 10.9% 41.7 3.2% 1121.7 85.9% 

TOTAL 366.6 10.5% 103.4 3.0% 3008.3 86.5% 

Test was completed by 3:45 PM
APPENDIX H 

TEST PARTICIPANTS 
TEST PARTICIPANTS

ENVIRONMENTAL SERVICES 

AIR SERVICES GROUP – TEST TEAM

Jorge Varino Environmental Technician – Team Lead 

Gary Barber Associate Technician 

Scott Given Associate Technician 

TRIGON ENGINEERING –TEST TEAM

Bryan Starnes Project Manager 

Joshua Jones Assistant Project Manager 

Larry Reynolds Senior Scientist 

Dr. Grant Plummer FTIR Analyst – Enthalpy Analytical, Inc. 

PROCESS DATA

Curtis Seebaran Engineer – Big Bend Station 

R.A. McDarby Senior Environmental Technician 

FUEL ANALYSIS

Patrice Jackson Environmental Technician 

Sam Soth Environmental Technician 

PARTICULATE LABORATORY

Sam Soth Environmental Technician 

ANCILLARY DATA COLLECTION AND ANALYSIS

R.A. McDarby Senior Environmental Technician 

PROJECT QUALITY OBJECTIVES & REPORTING

R.A. McDarby Senior Environmental Technician 

W. Quentin Best Quality Assurance Manager – Trigon Engineering 

TEST COORDINATION

Curtis Seebaran Engineer – Big Bend Station 

David A. Smith Coordinator –Air Services Group