# EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -004

PARTICULATE MATTER, SULFUR DIOXIDE, NITROGEN OXIDE, AND VISIBLE EMISSIONS EVALUATION September 11, 2007

AMMONIA SLIP, SULFUR DIOXIDE, AND NITROGEN OXIDE September 12, 2007

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Air Services Group

Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Jorge A. Varino Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1

2.0 DISCUSSION OF RESULTS / EXECUTIVE SUMMARY 2

3.0 SOURCE DESCRIPTION / TEST PROCEDURES 3

4.0 TEST RESULTS

PARTICULATE MATTER TEST SUMMARY 8

SULFUR DIOXIDE AND NITR OGEN OXIDES 11-SEP-2007 9

VISIBLE EMISSIONS DATA FR OM OPACITY MONITOR 10

HEAT INPUT CALCULATIONS 11-SEP-2007 11

AMMONIA SLIP TEST SUMMARY 12-SEP-2007 12

SULFUR DIOXIDE AND NITROGEN OXIDES 12-SEP-2007 13

HEAT INPUT CALCULATIONS 12-SEP-2007 14

5.0 FIGURES

PARTICULATE SAMPLING TRAVERSE POINTS 16

APPENDICES A PARTICULATE MATTER TEST DATA A-1 RUN CALCULATIONS A-2 LABORATORY ANALYTICAL DATA A-3 CALIBRATION DATA A-4 FIELD DATA SHEETS A-5 CHAIN OF CUSTODY

B CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007

C OPERATIONS DATA 11-SEP-2007

D AMMONIA SLIP TEST DATA (TRIGON ENGINEERING) D-1 FTIR SPECTROMETER DATA D-2 FTIR QUALITY ASSURANCE D-3 FTIR METHOD MAP

E CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007

F OPERATIONS DATA 12-SEP-2007

### G FUEL INFORMATION G-1 BUNKERING INFO RMATION 11-SEP-2007 G-2 FUEL ANALYSIS G-3 PRECIPITATOR LOGS 11-SEP-2007 G-4 BUNKERING INFO RMATION 12 SEP-2007

H TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On September 11, 2007, Tampa Electric Company’s, Environmental, Health, & Safety, Air Services Group, performed par ticulate matter (PM) tests at the Big Bend Station (Facility ID No.: 0570039), Boile r No. 4, (E.U. ID No.: -004). Testing was conducted according to pr ocedures stipulated by the Florida Department of Environmental Protection (FDEP) for fo ssil fuel steam generators, and requirements in Titl e V Permit # 0570039-021-AV, Compliance determination procedures and methods , §B.26 through §B.30.

On September 12, 2007, Tri gon Engineering, under contract to Tampa Electric Company, performed ammonia slip tests at the same location. Testing was conducted according to Air Construction Permit 0570039-026-AC, COMPLIANCE

DETERMINATION , §A.19.

### 2 

## 2.0 DISCUSSION OF RESULTS Executive Summary Tampa Electric Company Big Bend Station Dry-Bottom Tangentially Fired Utility Boiler Emission Unit ID -004

Coal/Petroleum Coke/Polk Residual Compliance Parameter Test Result FDEP Permit Limit September 11, 2007 Particulate, lb/mmBtu 0.01 0.01 Particulate, lbs/hr 33.2 43.3 SO 2 

### , lb/mmBtu 0.34 0.82 1


### SO 2 

### , lbs/hr 1441 3551 1


### NO X 

### , lb/mmBtu 0.07 0.10 2


### NO X 

### , lbs/hr 304 433 2,5 

### VE, % opacity 5 20 3 

### Heat Input, mmBtu/hr 4257 4330 4 

### Unit Load (% of permit) 98% 90 – 100% September 12, 2007 Ammonia, ppmv 1 10 SO 2 

### , lb/mmBtu 0.12 0.82 1


### SO 2 

### , lbs/hr 515 3551 1


### NO X 

### , lb/mmBtu 0.07 0.10 2


### NO X 

### , lbs/hr 303 433 2,5 

### Heat Input, mmBtu/hr 4157 4330 4 

### Unit Load (% of permit) 96% 90 – 100%

1 Based on a 30-day rolling average.

2 Based on a heat input weighted 30-day rolling average.
3 6-minute average.

4 Permitting Note: The heat input has been placed in the permit to identify the capacity of the unit for purposes of confirming that emissions testing is conducted within the 90 – 100% of the unit’s rated capacity (or to limit future operat ion to 110% of the test load), to establish appropriate emission limits and to aid in determining future rule applicability.

5 This limit is based on a heat input of 4330 mmBtu/hr.


### The average particulate matter emissions were derived by performing three, 2-

hour United States Envir onmental Protection Agency (USEPA) reference method 5B test runs. The average emission rates were calculated as 0.01 lb/mmBtu, and 33.2 lbs/hr. The FDEP Title V permitt ed emission rates are 0.01 lb/mmBtu and 43.3 lbs/hr (§ B.5.i (a) & (b)).

### 3 

### During the particulate matter test the Sulfur Dioxide (SO 2 

### ) emission rates were

determined to be 0.34 lb/mmBtu and 1441 lb s/hr. The FDEP Title V permitted

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling average (§ B.7 (a) & (b)).

During the particulate matter test the nitrogen dioxide (NO 2 

### ) emission rates (as total oxides) were determined to be 0. 07 lb/mmBtu and 304 lbs/hr. The FDEP AC permitted emission rate is 0.10 lb /mmBtu and 433 lbs/hr, based on a 30-day rolling average (§A.16).

Visible emissions were determined to be 5%, maximum 6-minute average, during

a one-hour test conducted under soot bl owing conditions. The FDEP Title V permitted emission rate is 20 percent opacity (6-minute average) except for one 6-minute period per hour of not more than 27 (twenty-seven) percent (§B.6).

During the particulate matter test perfo rmed on September 11, 2007 Boiler No. 4 was operated at an average heat input rate of 4257 mmBtu/hr and an average load of 420 megawatts. The average quantit y of fuel burned was 180.9 tons per

hour.

On September 12, 2007, the average amm onia slip concentration was derived by performing three, 1-hour USEPA referenc e method 320 test runs. The average concentration was calculated as 1 ppmv. The FDEP AC permitted concentration is 10 ppmv (§A.17).

During the ammonia slip test the Sulfur Dioxide (SO 2 

### ) emission rates were

determined to be 0.12 lb/mmBtu and 515 lb s/hr. The FDEP Title V permitted

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling average (§ B.7 (a) & (b)).

During the ammonia slip test the nitrogen dioxide (NO 2 

### ) emission rates (as total oxides) were determined to be 0.07 lb /mmBtu and 303 lbs/hr. The FDEP AC

### 4 

### permitted emission rate is 0.10 lb/ mmBtu and 433 lbs/hr, based on a 30-day rolling average (§A.16).

During the ammonia slip test perform ed on September 12, 2007 Boiler No. 4 was operated at an average heat input rate of 4157 mmBtu/hr and an average load of 410 megawatts.

### 5 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM

coordinates East 361.9 No rth 3075.0. Boiler No. 4 source sampling location

consists of a circular sta ck 28.83 feet in diam eter with four sample ports located 90 degrees apart on the stack circumference. Upstream and downstream gas

flow disturbances were determined to be 8.51 and 2.99 stack di ameters from the test ports, respectively. Using these cr iteria, a total of 24 sampling points were chosen for particulate sampling for each stack, as stipulat ed in the U.S. EPA Method 1 test procedure. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash emissions, a selective catalytic reducti on (SCR) system for control of nitrogen oxides emissions, an ammonia injecti on system to control sulfur trioxide formation, and a flue gas desulfurization (FGD) system for control of sulfur

dioxide emissions.

On September 11, 2007, the boiler was fired with a solid fuel matrix comprised of 90% coal, 9% petroleum coke, and 1% Po lk residual. On September 12, 2007,

the boiler was fired with a solid fuel matrix comprised of 87% coal, 10 % petroleum coke, and 3% Polk residual.

Particulate sampling was perform ed according to USEPA Method 5-B

"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".

Particulate matter was collected on a hi gh purity, glass micro fiber filter measuring 8.26 cm in diameter.

Sulfur Dioxide and Nitrogen Ox ide data was supplied by the installed Continuous Emissions Monitoring systems (CEMs), Data Acquisition and Handling System (DAHS) as one minute averages for the duration of the particulate matter test.

### 6 

### Visible emissions compliance was asse ssed using the installed Continuous Opacity Monitor (COM) as recorded by the DAHS as one minute averages during the soot blowing portion of the particulate matter test.

Ammonia slip testing was performed using USEPA Method 320 “Measurement of Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy”. Deta ils of this test performed by Trigon Engineering are submitted as an attachment to this report.

### 7 

## 4.0 TEST RESULTS

## BIG BEND STATIO N PARTICULATE MATTER DATA SUMMAR Y

Run 1 Run 2 * 

### Run 3 T est Summar y V m(std) 

### , scf 78.418 79.117 80.300 79.278

B ws 

### , ratio 0.14771 0.14568 0.14582 0.146404

O 2 

### , % volume 8 8 8 8.00

M

d 

### , lb/lb - mole 30.24 30.24 30.32 30.267

M

s 

### , lb/lb - mole 28.43 28.46 28.52 28.471

Q s 

### , acf/min 1390398.5 1415991.4 1427357.0 1411248.96

Q s(std) 

### , dscf/min 1059791.9 1074230.2 1089264.6 1074428.88

I, % 101.2 100.8 100.9 100.97

C, lbs/dscf 5.54E-07 5.13E-07 4.79E-07 5.1521E-07

E m 

### , lbs/hr 35.2 33.0 31.3 33.2

E r 

### , lb/mmBtu 0.009 0.008 0.008 0.01

Mass emissions (E m ), lbs/hr, calculated as: C x Q s ( std ) x 60 minutes/hour Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 ))

* Run 2 was a soot blowing run 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILER September 11, 2007

8

## BIG BEND STATIO N SULFUR DIOXIDE and NITROGEN OXIDES DAT A

Outlet SO 2 

### Data Average SO 2 

### Concentration, ppmvw: 125.23 Average CO 2 

### Concentration, % volume wet: 11.052
Calculated SO 2 

### Emission Rate, lb/mmBtu: 0.34
Calculated SO 2 

### Emission Rate, lbs/hr: 1441



### Unit #4 NO x 

### Data Average NO x 

### concentration, ppmvw: 40.13 Average CO 2 

### Concentration, % volume wet: 12.065
Calculated NO x 

### Emission Rate, lb/mmBtu: 0.07
Calculated NO x 

### Emission Rate, lbs/hr: 304

SO2 Emission Rate, lb(s)/mmBtu is calculated as: SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw) NOx Emission Rate, lb/mmBtu is calculated as: NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw) Emission Rates in lbs/hr are calculated as: Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr Average Concentration values were taken from 9:45 to 17:26 EST. Heat Input Calculated for this test was 4257 mmBtu/hr 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R September 11, 2007

9

## BIG BEND STATIO N V ISIBLE EMISSIONS DATA FROM OPACITY MONITO R

Record# DATE T IME OPACITY4 Record# DATE T IME OPACITY4 1 09/11/2007 12:27 3.88 31 09/11/2007 12:57 4.45 2 09/11/2007 12:28 3.80 32 09/11/2007 12:58 4.77 3 09/11/2007 12:29 4.07 33 09/11/2007 12:59 4.94 4 09/11/2007 12:30 3.77 34 09/11/2007 13:00 4.38 5 09/11/2007 12:31 3.75 35 09/11/2007 13:01 4.16 6 09/11/2007 12:32 3.84 36 09/11/2007 13:02 4.15 7 09/11/2007 12:33 3.82 37 09/11/2007 13:03 4.18 8 09/11/2007 12:34 3.96 38 09/11/2007 13:04 4.33 9 09/11/2007 12:35 3.80 39 09/11/2007 13:05 4.26 10 09/11/2007 12:36 3.99 40 09/11/2007 13:06 4.01 11 09/11/2007 12:37 4.22 41 09/11/2007 13:07 4.27 12 09/11/2007 12:38 4.15 42 09/11/2007 13:08 3.89 13 09/11/2007 12:39 3.87 43 09/11/2007 13:09 4.11 14 09/11/2007 12:40 3.95 44 09/11/2007 13:10 4.21 15 09/11/2007 12:41 4.06 45 09/11/2007 13:11 4.08 16 09/11/2007 12:42 3.98 46 09/11/2007 13:12 3.97 17 09/11/2007 12:43 4.17 47 09/11/2007 13:13 3.77 18 09/11/2007 12:44 4.03 48 09/11/2007 13:14 3.74 19 09/11/2007 12:45 3.91 49 09/11/2007 13:15 3.90 20 09/11/2007 12:46 3.81 50 09/11/2007 13:16 3.96 21 09/11/2007 12:47 4.06 51 09/11/2007 13:17 3.52 22 09/11/2007 12:48 3.76 52 09/11/2007 13:18 3.83 23 09/11/2007 12:49 3.92 53 09/11/2007 13:19 3.77 24 09/11/2007 12:50 4.01 54 09/11/2007 13:20 3.63 25 09/11/2007 12:51 4.19 55 09/11/2007 13:21 3.45 26 09/11/2007 12:52 4.24 56 09/11/2007 13:22 3.90 27 09/11/2007 12:53 4.24 57 09/11/2007 13:23 3.96 28 09/11/2007 12:54 4.09 58 09/11/2007 13:24 3.27 29 09/11/2007 12:55 4.57 59 09/11/2007 13:25 3.59 30 09/11/2007 12:56 4.34 60 09/11/2007 13:26 3.79

T est Avera g e: 4.008 % Minimum One Minute Avera g e: 3.270 % Maximum One Minute Avera g e: 4.940 %

Maximum Six Minute Avera g e: 4.575 % 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R SOOTBLOWING CONDITIONS

10

## BIG BEND STATIO N HEAT INPUT CALCULATION S

Gross Heat Rate, Previous Month ( Au g ust ) : 10137 KMBtu/MWh 1.0137E+07 mmBtu/MWh

Testing Start Time: 9:45

Testing End Time: 17:26

Total Test Time: 7.68 hours

Average Unit Load, MWe: 420 MW Heat Input, mmBtu/h = mmBtu/MWh x MW: 4257 mmBtu/hr

Laboratory Sample ID: AA90279 Btu as received: 11769 

### Btu/lb Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 180.9 Tons/hour 

### Unit #4

T est Time Information

Calculated Heat Input

Fuel Consumption Calculation DRY-BOTTOM TANGENTIALLY FIRED BOILE R September 11, 2007

11

## BIG BEND STATIO N AMMONIA SLIP DAT A

Run NH 3 

### Number Start Stop ppmvw 1 11:30 12:30 1.24 2 13:11 14:11 0.747 3 14:37 15:37 0.755 Average: 1

T est Data Provided b y Tri g on En g ineerin g

.

Test Times Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R September 12, 2007

12

## BIG BEND STATIO N SULFUR DIOXIDE and NITROGEN OXIDES DAT A

Outlet SO 2 

### Data Average SO 2 

### Concentration, ppmvw: 45.24 Average CO 2 

### Concentration, % volume wet: 10.917
Calculated SO 2 

### Emission Rate, lb/mmBtu: 0.12
Calculated SO 2 

### Emission Rate, lbs/hr: 515



### Unit #4 NO x 

### Data Average NO x 

### concentration, ppmvw: 41.31 Average CO 2 

### Concentration, % volume wet: 12.179
Calculated NO x 

### Emission Rate, lb/mmBtu: 0.07
Calculated NO x 

### Emission Rate, lbs/hr: 303

SO2 Emission Rate, lb(s)/mmBtu is calculated as: SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw) NOx Emission Rate, lb/mmBtu is calculated as: NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw) Emission Rates in lbs/hr are calculated as: Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr Average Concentration values were taken from 10:30 to 14:37 EST. Heat Input Calculated for this test was 4157 mmBtu/hr 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R September 12, 2007

13

## BIG BEND STATIO N HEAT INPUT CALCULATION S

Gross Heat Rate, Previous Month ( Au g ust ) : 10137 KMBtu/MWh 1.0137E+07 mmBtu/MWh

Testing Start Time: 11:30

Testing End Time: 15:37

Total Test Time: 4.12 hours

Average Unit Load, MWe: 410 MW Heat Input, mmBtu/h = mmBtu/MWh x MW: 4157 mmBtu/hr 

### Calculated Heat Input Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILER September 12, 2007

T est Time Information

14

### 15 

## 5.0 FIGURESFIGURE 1 EXHAUST STACK 245 FT. BIG BEND STATION CS003

PARTICULATE TRAVERSE POINTS

OUTLET 

# N A

B C D

PORT LOCATION

REVISED 12-31-96 BOILER NO. 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 8.5

STACK DIAMETER = 28.8333 FT. STACK AREA = 652.948 SQ.

PORT LENGTH’S = 14 IN. TRAVERSE POINT

1

2

3

4

5

6 % OF STACK DIAMETER IN. FROM STACK WALL

2.1%

6.7%

11.8%

17.7%

25.0%

35.6% 7.27 IN.

23.18 IN.

40.83 IN.

61.24 IN.

86.50 IN.

123.18 IN. 499 FT.

254 FT.

168 FT. 86 FT.

FGD

PRESSURIZED ANNULUS



### 16

# APPENDIX A

PARTICULATE MATTER TEST DATA

# A-1

RUN CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 1 Date: September 11, 2007

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.270 inches Barometric Pressure, P b : 30.00 "Hg Nozzle Area, A n : 0.000398 ft 2
Stack Pressure, P s : 29.92 "Hg Average Orifice Meter, Δ H: 1.437 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 84.100 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 101.8 o F Gas Analysis: 12.0 % CO 2 Average Stack Temp., T s : 130.4 o F
8.0 % O 2 Average √ Δ p: 0.593 "H 2 O
0.0 % CO Condensate Volume, V l c : 288.3 ml
80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.590 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 78.418 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.148 %
FDA = 1.0 - B ws 0.852 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.24 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.43 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 35.49 ft/second
Q s = v s x A s x 60 1390398.5 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1059791.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 101.2 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01970 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.004 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.003 grains/acf
C = c s / 7000 5.538E-07 lbs/dscf
E M = C x Q s(std) x 60 35.2 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.009 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded, Sootblowing
Run Number: 2 - S
Date: September 11, 2007

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.270 inches Barometric Pressure, P b : 29.90 "Hg Nozzle Area, A n : 0.000398 ft 2
Stack Pressure, P s : 29.82 "Hg Average Orifice Meter, Δ H: 1.476 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 85.023 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 101.1 o F Gas Analysis: 12.0 % CO 2 Average Stack Temp., T s : 132.6 o F
8.0 % O 2 Average √ Δ p: 0.602 "H 2 O
0.0 % CO Condensate Volume, V l c : 286.2 ml
80.0 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.491 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 79.117 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.146 %
FDA = 1.0 - B ws 0.854 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.24 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.46 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 36.14 ft/second
Q s = v s x A s x 60 1415991.4 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1074230.2 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01840 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.004 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.003 grains/acf
C = c s / 7000 5.127E-07 lbs/dscf
E M = C x Q s(std) x 60 33.0 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.008 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 3 Date: September 11, 2007

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.270 inches Barometric Pressure, P b : 29.90 "Hg Nozzle Area, A n : 0.000398 ft 2
Stack Pressure, P s : 29.82 "Hg Average Orifice Meter, Δ H: 1.521 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 86.310 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 101.3 o F Gas Analysis: 12.5 % CO 2 Average Stack Temp., T s : 129.0 o F
8.0 % O 2 Average √ Δ p: 0.610 "H 2 O
0.0 % CO Condensate Volume, V l c : 290.8 ml
79.5 % N 2 Meter Box Y: 0.986 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 13.708 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 80.300 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.146 %
FDA = 1.0 - B ws 0.854 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.32 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.52 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 36.43 ft/second
Q s = v s x A s x 60 1427357.0 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1089264.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.9 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01745 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0034 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0026 grains/acf
C = c s / 7000 4.791E-07 lbs/dscf
E M = C x Q s(std) x 60 31.3 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.008 lbs/MMBtu

# A-2

LABORATORY ANALYTICAL DATACustomerAIR SERVICESPlantBIG BENDUnit4Method5-BStack Test Completion Date09/11/2007AnalystSSAA90279ACETONE BEAKER1st weighingDate09/14/2007Time11:10% RH45.0%2nd weighingDate09/17/2007Time15:15% RH45.0%3rd weighingDateTime% RH4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR AFAIR ACAIR AEAIR ADAcetone Rinse Vol.(Va), mls150.0000150Enter Container ID150Enter Container ID150Enter Container ID1st Gross Wt., grams99.9387103.6531101.8631108.58612nd Gross Wt., grams99.9386103.6533101.8634108.58623rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams99.93865103.65320Enter Gross Wts.101.86325Enter Gross Wts.108.58615Enter Gross Wts.Tare Wt., grams99.93905103.63815101.84885108.57130Acetone Blank Wt.,mg-0.40-0.40-0.40-0.40Acetone Particulate Wt.,mg15.4514.8015.25Acetone Residue, mg/g-0.0034Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate09/14/2007Time11:00% RH45.0%Date09/17/2007Time15:15% RH45.0%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID2030722030702030522030561st Gross Wt., grams0.25180.25500.25230.25612nd Gross Wt., grams0.25180.25500.25240.25613rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.251800.25500Enter Gross Wts.0.25235Enter Gross Wts.0.25610Enter Gross Wts.Tare Wt., grams0.251400.250750.249700.25295Filter Particulate Wt.,mg4.252.653.15Difference, milligrams0.4Total Sample Particulate Wt.,mg19.7017.4518.40

# A-3

CALIBRATION DATA

## SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 07) INITIA L 07/19/2007 USEPA RM 5 0.986 POST TEST 09/20/2007 (ORIFICE) 0.992

NOZZLE (SN09) INITIA L 07/19/2007 CALIPER 0.270 POST TEST 09/20/2007 MEASUREMENTS 0.270

PYROMETER (PY 09) 07/19/2007 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 10) 07/19/2007 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 08/16/2007 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Blue Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30.09 "Hg Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.19 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF
0.60 15 250.900 257.837 6.937 80 76 80 75 1.10 15 239.900 249.116 9.216 82 77 81 76 1.90 15 225.100 236.979 11.879 86 78 84 77 3.50 15 204.600 220.776 16.176 90 78 91 78

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3455 23.5 72 72 72.0 55 0.4592 22.0 72 72 72.0 63 0.5877 20.0 72 72 72.0 73 0.8022 17.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.857 6.761 6.776 0.986 0.000 1.640 -0.079 9.100 8.986 9.006 0.987 0.002 1.699 -0.021 11.703 11.500 11.527 0.983 -0.003 1.784 0.065 15.911 15.698 15.734 0.987 0.001 1.754 0.035 Averages: 0.986 1.719

Review/Approval: 

### USEPA Reference Method 5 Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

07/19/2007

SEG

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice

### Environmental Services Air Services Group

Manufacturer: Thermo Calibration Date: Model Number:MST Barometric Pressure: 29.82 "Hg Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.07 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: BLUE

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.1 10 13.600 19.675 6.075 77 74 77 74 1.1 10 19.675 25.745 6.070 77 74 77 74 1.1 10 25.745 31.820 6.075 77 74 77 74

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4592 20.5 72 72 72.0 55 0.4592 20.5 72 72 72.0 55 0.4592 20.5 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

5.984 5.937 6.004 0.992 0.000 1.725 0.000 5.979 5.937 6.004 0.993 0.001 1.725 0.000 5.984 5.937 6.004 0.992 0.000 1.725 0.000 Averages: 0.992 1.725 Prior Y: 0.986 % Difference: -0.65%

Review/Approval: Date: BB unit 4- 09-11-07

IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

SEG 09/20/2007 

### POST - TEST CALIBRATION CHECK

21-Sep-07 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET Calibration Date: 07/19/2007 Responsible Party: SEG

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average

I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

^SN01 0.289 0.292 0.292 0.001 0.115 ^SN04 0.319 0.318 0.319 0.000 0.125 ^SN05 0.377 0.378 0.375 0.001 0.148 ^SN06 0.492 0.492 0.496 0.002 0.194 ^SN09 0.689 0.686 0.685 0.002 0.270 ^SN10 0.750 0.754 0.753 0.002 0.296 ^SN12 0.985 0.984 0.986 0.001 0.388 ^SN15 0.417 0.415 0.415 0.001 0.164 ^SN16 0.502 0.499 0.502 0.001 0.197 ^SN19 0.707 0.708 0.708 0.000 0.279 ^SN22 0.933 0.933 0.933 0.000 0.367 ^SN30 0.792 0.792 0.793 0.000 0.312 ^SN36 0.470 0.474 0.472 0.002 0.186 ^SN37 0.527 0.529 0.533 0.002 0.209 ^SN38 0.632 0.629 0.633 0.002 0.249 ^SN46 0.481 0.480 0.480 0.000 0.189 ^SN47 0.515 0.513 0.512 0.001 0.202 ^SN48 0.632 0.634 0.634 0.001 0.249 ^SN50 0.783 0.788 0.789 0.002 0.310 ^SN58 0.611 0.608 0.614 0.002 0.241 ^SN68 0.622 0.626 0.628 0.002 0.246 ^SN69 0.947 0.949 0.949 0.001 0.373 ^SN70 1.562 1.562 1.561 0.000 0.615 ^SN71 1.552 1.555 1.555 0.001 0.612 ^SN72 0.954 0.954 0.953 0.000 0.375 ^SN73 1.279 1.283 1.281 0.002 0.504 ^SN74 1.241 1.240 1.242 0.001 0.489 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by:

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 09/20/2007 

### Calibration Personnel: JAV 

### Test Designation: Big Bend Unit 4



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average
Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN09 0.681 0.686 0.690 0.004 0.270

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN09 was 0.270

Difference (Pre-test/Post-test) is: 0.000

QA/QC Review by: 21-Sep-07

### Environmental Services A ir Services Group Pyrometer Calibration Blue Team Pyrometer Under Tes t Pyrometer Number: ^PY09 Labworks Sample # 0 Calibration Date: 07/19/2007

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 04/17/2007 Calibration Personnel (Typed and Signature): SEG

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 402 -2
2 

### 212 212 0
3 

### 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass
2 

### Pass
3 

### Pass

Reviewer: 23-Jul-07Environmental Services Air Services Group

_ _

s PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT10 Calibration Date 07/19/2007 Operating Quarter/Year: Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.1 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.1 degrees Pass α < 10 degrees β 1 0.5 degrees Pass ( α 1 measured across top impact openings) β 2 0.2 degrees Pass ( α 2 measured across bottom impact openings)
β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α

, Ζ

, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.3 degrees Ζ < 0.32 cm ( Α sin ψ )

Α 2.428 cm W < 0.08 cm (Asin ο )

Ζ 0.013 cm Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.1 degrees ψ angle between tips
W 0.004 cm Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.

Comments: REMOVABLE

Calibrated by: SEG

Q uality Assurance Review / Approval:

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR07 Calibration Date: 08/16/2007 Calibration Personnel: SEG Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 10:00 30.08 30.06 0.02 12:00 30.09 30.08 0.01 13:00 30.12 30.07 0.05

Avera g e Difference: 0.027

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 17-Au g -07

# A-4

FIELD DATA SHEETS

# A-5

CHAIN OF CUSTODY

# APPENDIX B

CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 9:45 39.8 12.12 134.7 11.14 09/11/2007 9:46 39.6 12.14 137 11.18 09/11/2007 9:47 39.5 12.2 135.6 11.22 09/11/2007 9:48 38.6 12.17 141.4 11.17 09/11/2007 9:49 38.5 12.16 142.4 11.17 09/11/2007 9:50 39 12.14 139.2 11.17 09/11/2007 9:51 40.1 12.17 134.6 11.18 09/11/2007 9:52 40.6 12.14 133.2 11.18 09/11/2007 9:53 40.4 12.13 138.1 11.2 09/11/2007 9:54 40.4 12.12 136.2 11.14 09/11/2007 9:55 41.8 12.15 134.9 11.29 09/11/2007 9:56 42.2 12.36 121 11.4 09/11/2007 9:57 42.1 12.41 114.2 11.4 09/11/2007 9:58 40 12.41 119.4 11.33 09/11/2007 9:59 38.6 12.35 133.2 11.41 09/11/2007 10:00 39.1 12.4 130.2 11.41 09/11/2007 10:01 39.5 12.47 126.9 11.38 09/11/2007 10:02 16.7 9.03 67.9 5.2 09/11/2007 10:03 0.2 1.54 64.9 3.16 09/11/2007 10:04 13 0.5 130.6 9.59 09/11/2007 10:05 41.5 8.28 135.2 10.65 09/11/2007 10:06 41.2 11.73 139.9 10.79 09/11/2007 10:07 42.2 11.99 139 10.85 09/11/2007 10:08 42.4 11.98 139.2 10.95 09/11/2007 10:09 43.6 11.94 140.8 11 09/11/2007 10:10 44.9 11.98 145.3 11.12 09/11/2007 10:11 45.6 12.07 147.3 11.11 09/11/2007 10:12 45.7 12.05 141 11.08 09/11/2007 10:13 44.5 12.07 136.6 11.12 09/11/2007 10:14 42.8 12.09 136.4 11.11 09/11/2007 10:15 41.8 12.12 138.1 11.1 09/11/2007 10:16 40.8 12.11 142.1 11.08 09/11/2007 10:17 40.9 12.04 146 11.14 09/11/2007 10:18 41.7 12.1 141 11.2 09/11/2007 10:19 41.7 12.22 126.8 11.22 09/11/2007 10:20 40.1 12.19 119.3 11.19 09/11/2007 10:21 38.2 12.18 117.6 11.12 09/11/2007 10:22 37.1 12.09 132.2 11.1 09/11/2007 10:23 37.9 12.04 142.8 11.13 09/11/2007 10:24 39.9 12.08 140.1 11.22 09/11/2007 10:25 41.4 12.19 131.5 11.18 09/11/2007 10:26 40.7 12.14 125 11.07 09/11/2007 10:27 40.4 12.05 124.8 11.12

Page 1 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 10:28 41.1 12.13 129.6 11.17 09/11/2007 10:29 41 12.15 129.9 11.11 09/11/2007 10:30 41 12.15 124.1 11.21 09/11/2007 10:31 41.2 12.16 129.2 11.2 09/11/2007 10:32 40.2 12.15 129.8 11.12 09/11/2007 10:33 41.2 12.11 134.5 11.18 09/11/2007 10:34 42.6 12.14 143.9 11.26 09/11/2007 10:35 43 12.23 144.7 11.23 09/11/2007 10:36 42.7 12.19 136.7 11.13 09/11/2007 10:37 42.6 12.09 125.9 11.22 09/11/2007 10:38 42.6 12.17 124.9 11.22 09/11/2007 10:39 42.4 12.17 123.2 11.24 09/11/2007 10:40 43.3 12.26 120.5 11.28 09/11/2007 10:41 42.1 12.24 123.6 11.22 09/11/2007 10:42 41.6 12.2 128.1 11.3 09/11/2007 10:43 41.3 12.25 125.4 11.23 09/11/2007 10:44 40.4 12.23 125.6 11.19 09/11/2007 10:45 40.6 12.19 124.5 11.21 09/11/2007 10:46 40 12.15 128.7 11.19 09/11/2007 10:47 40.3 12.15 131.3 11.08 09/11/2007 10:48 40.7 12.03 138.1 11.01 09/11/2007 10:49 41.1 12 147.1 11.03 09/11/2007 10:50 42.7 12 155.3 11.1 09/11/2007 10:51 44 12.05 149.8 11.09 09/11/2007 10:52 44.1 12.05 143.1 11.13 09/11/2007 10:53 43.6 12.12 139.9 11.02 09/11/2007 10:54 42.6 11.99 143.2 11.02 09/11/2007 10:55 42.6 11.96 144 11.05 09/11/2007 10:56 41.8 12.05 137.1 11.1 09/11/2007 10:57 41.1 12.06 134.6 11.13 09/11/2007 10:58 41 12.1 128.9 11.16 09/11/2007 10:59 40.2 12.17 127.7 11.24 09/11/2007 11:00 40 12.19 124 11.14 09/11/2007 11:01 40.3 12.14 127.8 11.27 09/11/2007 11:02 40.4 12.27 127.8 11.32 09/11/2007 11:03 40.1 12.32 118.1 11.23 09/11/2007 11:04 38.7 12.24 112.9 11.28 09/11/2007 11:05 38.3 12.2 118.4 11.23 09/11/2007 11:06 38.6 12.15 125.8 11.28 09/11/2007 11:07 40.9 12.27 124.2 11.39 09/11/2007 11:08 41 12.34 116.3 11.3 09/11/2007 11:09 40.5 12.3 112.7 11.27 09/11/2007 11:10 39.6 12.23 121.7 11.18

Page 2 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 11:11 39.2 12.19 135.1 11.27 09/11/2007 11:12 40.3 12.31 136.5 11.26 09/11/2007 11:13 40.9 12.23 141.9 11.27 09/11/2007 11:14 41.7 12.28 138 11.22 09/11/2007 11:15 41.5 12.21 130.3 11.16 09/11/2007 11:16 41.5 12.17 149.6 11.08 09/11/2007 11:17 41.8 12.07 179.7 11.06 09/11/2007 11:18 42.3 12.05 173.3 11.05 09/11/2007 11:19 43 12.01 124.3 11.12 09/11/2007 11:20 43.2 12.09 106.8 11.08 09/11/2007 11:21 43.2 12.05 92.2 11.05 09/11/2007 11:22 43.5 12.09 88.6 11.11 09/11/2007 11:23 44 12.14 83.1 11.11 09/11/2007 11:24 43.7 12.11 82.2 11.08 09/11/2007 11:25 42.8 12.04 91.4 11.08 09/11/2007 11:26 42 12.14 98.1 11.18 09/11/2007 11:27 41.7 12.26 97.7 11.17 09/11/2007 11:28 40.8 12.25 96.1 11.11 09/11/2007 11:29 40.2 12.19 102.7 11.09 09/11/2007 11:30 39.4 12.14 105.3 11.17 09/11/2007 11:31 40.6 12.25 106.2 11.26 09/11/2007 11:32 41.1 12.34 104.8 11.28 09/11/2007 11:33 40.7 12.29 101.1 11.18 09/11/2007 11:34 39 12.23 107.6 11.17 09/11/2007 11:35 37.9 12.25 113.2 11.21 09/11/2007 11:36 37.8 12.29 110.2 11.26 09/11/2007 11:37 38.4 12.29 111.6 11.2 09/11/2007 11:38 38.6 12.2 109 11.07 09/11/2007 11:39 39.7 12.07 107.5 11.07 09/11/2007 11:40 41.3 12.07 106.9 11.19 09/11/2007 11:41 42.3 12.15 101.7 11.07 09/11/2007 11:42 41.4 12.03 101.3 11 09/11/2007 11:43 41.9 11.93 100.3 11 09/11/2007 11:44 41.9 11.95 99.8 11.03 09/11/2007 11:45 42.6 11.99 103.7 11.05 09/11/2007 11:46 42.8 12.03 110.2 11.09 09/11/2007 11:47 42.2 12.05 115.6 11.1 09/11/2007 11:48 41.6 12.04 120.1 11.14 09/11/2007 11:49 41.3 12.09 126.1 11.24 09/11/2007 11:50 40.2 12.21 129.1 11.13 09/11/2007 11:51 39.2 12.12 131.6 11.18 09/11/2007 11:52 38 12.15 136.1 11.17 09/11/2007 11:53 37.6 12.11 137.5 11.12

Page 3 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 11:54 39 12.05 138.4 11.06 09/11/2007 11:55 39.2 12.05 145.8 11.07 09/11/2007 11:56 39.9 12.01 133.6 11.05 09/11/2007 11:57 40.1 12.01 122.8 11.06 09/11/2007 11:58 40.8 12.02 116.4 11.05 09/11/2007 11:59 41.1 12.07 121.4 11.15 09/11/2007 12:00 40.7 12.14 125.7 11.14 09/11/2007 12:01 39.1 12.12 124.2 11.07 09/11/2007 12:02 38.2 12.07 118.7 11.07 09/11/2007 12:03 38.7 12.1 115.1 11.07 09/11/2007 12:04 39.2 12.05 116.5 11.08 09/11/2007 12:05 40.3 12.07 114.1 11.08 09/11/2007 12:06 40.4 12.08 110.7 11.03 09/11/2007 12:07 40.3 12.03 107.4 11.02 09/11/2007 12:08 41 11.98 112.4 11.01 09/11/2007 12:09 41.2 12.05 116.7 11.13 09/11/2007 12:10 41.9 12.15 117.7 11.14 09/11/2007 12:11 41.3 12.15 118.5 11.15 09/11/2007 12:12 40.4 12.09 119.6 11.15 09/11/2007 12:13 39.7 12.11 116.1 11.05 09/11/2007 12:14 38.2 12.06 108 11.03 09/11/2007 12:15 38.9 12.03 113 11.15 09/11/2007 12:16 39.6 12.1 119.3 11.15 09/11/2007 12:17 39.5 12.17 118.8 11.19 09/11/2007 12:18 38.9 12.15 114 11.15 09/11/2007 12:19 38.6 12.14 111.9 11.18 09/11/2007 12:20 38.6 12.21 112.9 11.18 09/11/2007 12:21 38.8 12.16 112.5 11.11 09/11/2007 12:22 39.1 12.09 114 11.05 09/11/2007 12:23 40.1 12.08 115.5 11.06 09/11/2007 12:24 41.7 12.09 116.4 11.13 09/11/2007 12:25 42 12.16 114.1 11.09 09/11/2007 12:26 42.2 12.1 115.6 11 09/11/2007 12:27 41.5 12.03 115.1 11.01 09/11/2007 12:28 41.8 12.05 120.3 11.09 09/11/2007 12:29 42.9 12.18 120.3 11.2 09/11/2007 12:30 42.9 12.25 122.6 11.18 09/11/2007 12:31 42.4 12.22 119.7 11.06 09/11/2007 12:32 40.3 12.09 120.5 11.05 09/11/2007 12:33 39.6 12.08 123.1 11.11 09/11/2007 12:34 39.2 12.16 123.1 11.06 09/11/2007 12:35 38.9 12.12 118.7 11.08 09/11/2007 12:36 38 12.04 118 11.03

Page 4 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 12:37 38.4 12.03 115.2 11.01 09/11/2007 12:38 38.6 12.06 114.6 11 09/11/2007 12:39 40.1 12.03 119.2 11.09 09/11/2007 12:40 40.3 12.08 126.9 11.2 09/11/2007 12:41 40.3 12.14 127.5 11.13 09/11/2007 12:42 39.4 12.13 127.2 11.09 09/11/2007 12:43 39.1 12.11 124 11.11 09/11/2007 12:44 37.8 12.14 123.5 11.05 09/11/2007 12:45 38.5 12.06 122 11.01 09/11/2007 12:46 39.7 12.01 118.1 10.91 09/11/2007 12:47 40.7 11.91 117.2 10.93 09/11/2007 12:48 41.4 11.95 119.9 11.01 09/11/2007 12:49 41.4 12.06 121 11.02 09/11/2007 12:50 41 12.03 118.6 10.99 09/11/2007 12:51 40.4 12.04 115.9 10.93 09/11/2007 12:52 40.5 12.01 113.4 10.96 09/11/2007 12:53 40.5 12.01 113.9 11.06 09/11/2007 12:54 41.4 12.07 115.3 11.1 09/11/2007 12:55 40.7 12.12 114 11.02 09/11/2007 12:56 39.2 12.07 114.6 11.08 09/11/2007 12:57 38 12.12 117.6 11.12 09/11/2007 12:58 37.4 12.18 114.1 11.11 09/11/2007 12:59 37 12.18 115.5 11.1 09/11/2007 13:00 37.3 12.14 120.5 11.16 09/11/2007 13:01 37.4 12.22 116.3 11.12 09/11/2007 13:02 36.5 12.15 109.5 11.15 09/11/2007 13:03 36.8 12.17 108.5 11.17 09/11/2007 13:04 36.7 12.19 113.4 11.09 09/11/2007 13:05 37.5 12.24 138.3 11.23 09/11/2007 13:06 37.9 12.27 146.3 11.23 09/11/2007 13:07 38.1 12.21 152.8 11.14 09/11/2007 13:08 38.4 12.09 164.4 11.09 09/11/2007 13:09 38.7 12.02 160.4 11.02 09/11/2007 13:10 39 11.97 164.1 11 09/11/2007 13:11 39 11.99 172 10.88 09/11/2007 13:12 39.9 11.88 178.2 10.88 09/11/2007 13:13 41.3 11.91 176.3 10.89 09/11/2007 13:14 42 11.94 171.3 10.89 09/11/2007 13:15 42.5 11.92 167.6 10.9 09/11/2007 13:16 42.1 11.9 163.2 10.91 09/11/2007 13:17 41.6 11.98 159.7 11 09/11/2007 13:18 40.6 12.06 158.5 11.01 09/11/2007 13:19 39.6 12.09 158.2 11.01

Page 5 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 13:20 38.8 12.09 162.3 11.11 09/11/2007 13:21 37.9 12.14 160.1 11.08 09/11/2007 13:22 37.7 12.1 155.6 11.09 09/11/2007 13:23 36.7 12.11 146.4 11.12 09/11/2007 13:24 36.3 12.17 149.1 11.14 09/11/2007 13:25 35.4 12.19 150.9 11.15 09/11/2007 13:26 35.2 12.18 161.4 11.1 09/11/2007 13:27 35.9 12.12 171.5 11.03 09/11/2007 13:28 36.1 12 177.7 10.96 09/11/2007 13:29 37.3 11.97 175.4 11.04 09/11/2007 13:30 39.1 12 156.8 11.09 09/11/2007 13:31 39.2 12.12 145.6 11.09 09/11/2007 13:32 38.2 12.14 146.8 11.02 09/11/2007 13:33 36.4 12.13 153.3 11 09/11/2007 13:34 36.6 12.08 164.7 11.02 09/11/2007 13:35 37.8 12.06 168.9 11.04 09/11/2007 13:36 39.4 12.07 161.7 11.05 09/11/2007 13:37 40.2 12.05 150.6 10.92 09/11/2007 13:38 39.7 11.96 145 10.92 09/11/2007 13:39 39.3 11.98 151.1 10.82 09/11/2007 13:40 39.3 11.91 151.1 10.87 09/11/2007 13:41 40.3 12.01 151.3 11.02 09/11/2007 13:42 41 12.11 160.7 11.07 09/11/2007 13:43 41.3 12.18 166.9 11.03 09/11/2007 13:44 41.3 12.14 167.8 11.01 09/11/2007 13:45 41.4 12.07 165.6 10.92 09/11/2007 13:46 41.4 11.96 167.4 10.88 09/11/2007 13:47 41.1 11.91 169.6 10.89 09/11/2007 13:48 41.1 11.95 164.6 10.99 09/11/2007 13:49 41.1 12.04 163.6 11.05 09/11/2007 13:50 40.7 12.08 161 10.96 09/11/2007 13:51 40.8 12.06 161.5 11.02 09/11/2007 13:52 40.1 12.12 162.2 11.06 09/11/2007 13:53 39.5 12.15 161.1 11.12 09/11/2007 13:54 39 12.17 152.6 11.14 09/11/2007 13:55 39 12.17 144.7 11.07 09/11/2007 13:56 38.1 12.15 145.8 11.04 09/11/2007 13:57 38.6 12.2 149.6 11.08 09/11/2007 13:58 38.2 12.15 157.3 11.04 09/11/2007 13:59 38.5 12.07 163.2 11 09/11/2007 14:00 39.9 12.1 155.5 11.14 09/11/2007 14:01 40.5 12.22 144.8 11.18 09/11/2007 14:02 40 12.25 140.9 11.15

Page 6 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 14:03 39.3 12.16 142.9 11.11 09/11/2007 14:04 39.1 12.2 147.2 11.12 09/11/2007 14:05 40 12.18 146.5 11.12 09/11/2007 14:06 40 12.14 149.9 11.03 09/11/2007 14:07 40.3 12.1 148.4 11 09/11/2007 14:08 40.4 12.09 144.1 11.01 09/11/2007 14:09 40.9 12.11 146.9 11.12 09/11/2007 14:10 41.4 12.16 155.2 11.16 09/11/2007 14:11 41.6 12.21 158.2 11.17 09/11/2007 14:12 41.6 12.18 151.1 11.01 09/11/2007 14:13 42 12.12 152.3 11.12 09/11/2007 14:14 41.7 12.14 152.8 11.03 09/11/2007 14:15 40.8 12.07 148.3 10.93 09/11/2007 14:16 40.8 12 153.1 10.94 09/11/2007 14:17 41.5 11.99 155.5 10.94 09/11/2007 14:18 41.8 11.95 165.3 10.95 09/11/2007 14:19 42.5 11.93 175.4 10.94 09/11/2007 14:20 42.8 11.93 176.8 10.86 09/11/2007 14:21 42.7 11.88 174.8 10.92 09/11/2007 14:22 42.5 11.95 166.2 11.06 09/11/2007 14:23 41.5 12.05 165.6 11.02 09/11/2007 14:24 40.1 12.09 166.1 11.11 09/11/2007 14:25 39.3 12.21 160.8 11.06 09/11/2007 14:26 38.5 12.11 156.6 11.02 09/11/2007 14:27 37.7 12.06 156.5 10.96 09/11/2007 14:28 37.4 11.99 160.2 10.97 09/11/2007 14:29 37.3 12.01 168.7 11.02 09/11/2007 14:30 37.5 11.99 175.4 11.08 09/11/2007 14:31 39 12.14 175.6 11.11 09/11/2007 14:32 39.2 12.1 168.4 10.96 09/11/2007 14:33 39.2 12.03 172.6 10.89 09/11/2007 14:34 39.6 11.97 174.8 10.91 09/11/2007 14:35 40.2 11.94 177.3 10.94 09/11/2007 14:36 40.6 12.01 166.3 11 09/11/2007 14:37 40.8 12 165.8 10.94 09/11/2007 14:38 40.8 11.98 170.7 11 09/11/2007 14:39 41.5 12.05 173 11.07 09/11/2007 14:40 41.6 12.05 171.9 11 09/11/2007 14:41 41.5 12 175 11.01 09/11/2007 14:42 41.2 12.02 176.8 11.03 09/11/2007 14:43 41.6 12.01 166.1 10.98 09/11/2007 14:44 41.4 12.03 157 11.09 09/11/2007 14:45 40.6 12.05 149.9 10.92

Page 7 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 14:46 40.5 12.01 153.1 10.97 09/11/2007 14:47 39.9 12.1 152.8 11.03 09/11/2007 14:48 40 12.07 156.4 11.02 09/11/2007 14:49 40.4 12.08 160.9 10.99 09/11/2007 14:50 41 12.09 160 11.07 09/11/2007 14:51 41.7 12.13 162.4 11.1 09/11/2007 14:52 41.8 12.19 158.8 11.18 09/11/2007 14:53 40.9 12.2 153.9 11.21 09/11/2007 14:54 40 12.29 145.9 11.12 09/11/2007 14:55 38 12.14 152.3 11.03 09/11/2007 14:56 37.3 12.11 160.7 11.03 09/11/2007 14:57 38 12.04 173.9 10.93 09/11/2007 14:58 39.7 11.95 185.1 10.97 09/11/2007 14:59 41.2 11.98 186.5 10.93 09/11/2007 15:00 42.8 11.97 178.1 10.94 09/11/2007 15:01 43 11.93 175.5 10.83 09/11/2007 15:02 42.8 11.88 178.8 10.86 09/11/2007 15:03 43.1 11.94 173.8 10.91 09/11/2007 15:04 42.6 12.06 170.7 11.03 09/11/2007 15:05 41.4 12.14 169.1 11.11 09/11/2007 15:06 40.5 12.17 164.6 11.13 09/11/2007 15:07 39.4 12.2 160 11.08 09/11/2007 15:08 38.5 12.14 160.7 11.09 09/11/2007 15:09 38.7 12.14 169 11.16 09/11/2007 15:10 38.5 12.21 179.2 11.14 09/11/2007 15:11 38.5 12.25 181 11.13 09/11/2007 15:12 38.6 12.22 181.9 11.17 09/11/2007 15:13 38.3 12.2 183.8 11.21 09/11/2007 15:14 38.8 12.32 178.3 11.23 09/11/2007 15:15 38.5 12.3 178.6 11.24 09/11/2007 15:16 38.2 12.31 177.7 11.22 09/11/2007 15:17 37.5 12.34 182.6 11.23 09/11/2007 15:18 37.4 12.28 190.1 11.18 09/11/2007 15:19 37.9 12.24 191.1 11.09 09/11/2007 15:20 38.8 12.15 195.5 11.11 09/11/2007 15:21 40.2 12.2 199.6 11.18 09/11/2007 15:22 40.5 12.17 208.6 11.14 09/11/2007 15:23 41.4 12.2 209 11.06 09/11/2007 15:24 42 12.12 210.8 11.04 09/11/2007 15:25 43.1 12.08 215 11.03 09/11/2007 15:26 43.5 12.06 208.6 11.1 09/11/2007 15:27 43.8 12.14 204.4 11.13 09/11/2007 15:28 43.9 12.22 203.8 11.18

Page 8 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 15:29 43.8 12.24 205.2 11.21 09/11/2007 15:30 42.7 12.29 196.1 11.21 09/11/2007 15:31 42.1 12.27 156.2 11.05 09/11/2007 15:32 41.1 12.31 102.1 10.44 09/11/2007 15:33 39.6 12.36 86.4 11 09/11/2007 15:34 38.8 12.36 77.9 11.21 09/11/2007 15:35 37.9 12.35 73.2 11.2 09/11/2007 15:36 38 12.28 70 11.14 09/11/2007 15:37 38.2 12.16 71.2 11.12 09/11/2007 15:38 39.5 12.19 65.3 11.21 09/11/2007 15:39 40.3 12.24 62.6 11.29 09/11/2007 15:40 40.6 12.27 60.8 11.31 09/11/2007 15:41 39.9 12.23 57.9 11.23 09/11/2007 15:42 40.6 12.12 57.2 11.22 09/11/2007 15:43 40.9 12.08 57.2 11.14 09/11/2007 15:44 41.7 12.01 61.5 11.1 09/11/2007 15:45 42.6 12.06 64.3 11.19 09/11/2007 15:46 43.6 12.12 63.9 11.14 09/11/2007 15:47 44.7 12.1 63.6 11.13 09/11/2007 15:48 44.8 12.13 65.3 11.1 09/11/2007 15:49 43.7 12.06 67.4 11.02 09/11/2007 15:50 43.3 11.95 65.2 10.94 09/11/2007 15:51 43 11.95 64.1 11.05 09/11/2007 15:52 43.5 12.08 66.7 11.11 09/11/2007 15:53 43 12.16 66 11.1 09/11/2007 15:54 42.4 12.14 61.8 11.07 09/11/2007 15:55 41.3 12.07 55.8 11.04 09/11/2007 15:56 40.4 12.01 57 10.97 09/11/2007 15:57 39.5 12.01 58.8 10.98 09/11/2007 15:58 39.6 12.06 60.1 11.03 09/11/2007 15:59 39.1 12.14 58.1 11 09/11/2007 16:00 38.5 12.05 58.7 10.97 09/11/2007 16:01 38.4 12.09 58.1 10.98 09/11/2007 16:02 09/11/2007 16:03 09/11/2007 16:04 09/11/2007 16:05 09/11/2007 16:06 09/11/2007 16:07 09/11/2007 16:08 34.4 12.16 69.6 11.06 09/11/2007 16:09 35.5 12.25 69.7 11.06 09/11/2007 16:10 35.8 12.22 66.5 10.97 09/11/2007 16:11 36 12.12 65.4 10.99

Page 9 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 16:12 36.3 12.17 65 10.95 09/11/2007 16:13 37 12.14 65.9 10.96 09/11/2007 16:14 37.8 12.13 67.5 11.06 09/11/2007 16:15 39.6 12.22 64.4 11.08 09/11/2007 16:16 39.7 12.2 63.6 11.01 09/11/2007 16:17 40.2 12.22 74.5 11.11 09/11/2007 16:18 40.5 12.24 86.3 10.95 09/11/2007 16:19 40.6 12.16 92.5 11.05 09/11/2007 16:20 41.2 12.13 90.5 10.96 09/11/2007 16:21 42.2 12.06 83.7 11.01 09/11/2007 16:22 43.5 12.12 72.9 10.96 09/11/2007 16:23 43.9 12.03 63.7 10.96 09/11/2007 16:24 43.9 12.06 64.5 10.93 09/11/2007 16:25 43.6 12.06 68.7 10.98 09/11/2007 16:26 43.9 12.11 68.9 11.05 09/11/2007 16:27 43.5 12.19 72.9 11.05 09/11/2007 16:28 42.8 12.23 74.5 11.12 09/11/2007 16:29 42 12.19 69.6 11.09 09/11/2007 16:30 41.1 12.2 70.2 11.13 09/11/2007 16:31 39.6 12.28 71.5 11.12 09/11/2007 16:32 38.2 12.24 75.4 11.19 09/11/2007 16:33 37.3 12.32 78.3 11.19 09/11/2007 16:34 36.5 12.36 80.6 11.19 09/11/2007 16:35 35.3 12.35 80.1 11.14 09/11/2007 16:36 35.6 12.26 81.9 11.11 09/11/2007 16:37 35.8 12.29 86.3 11.11 09/11/2007 16:38 36.1 12.23 84.9 11.01 09/11/2007 16:39 37.8 12.15 83.9 11.07 09/11/2007 16:40 38.9 12.2 80.1 11.01 09/11/2007 16:41 41.2 12.11 82.7 11.06 09/11/2007 16:42 41.7 12.19 80.3 11.08 09/11/2007 16:43 42.1 12.2 80.7 11.13 09/11/2007 16:44 42.1 12.25 81.2 11.06 09/11/2007 16:45 41.1 12.19 84 11 09/11/2007 16:46 41.4 12.17 89 11.08 09/11/2007 16:47 42 12.25 90.3 11.06 09/11/2007 16:48 42.5 12.17 92.4 11 09/11/2007 16:49 43.7 12.17 75.1 11.05 09/11/2007 16:50 44.7 12.2 73 11.12 09/11/2007 16:51 44.7 12.25 73.4 11.13 09/11/2007 16:52 44 12.29 79.1 11.16 09/11/2007 16:53 43.1 12.31 79.7 11.11 09/11/2007 16:54 41.4 12.27 82.7 11.16

Page 10 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/11/2007 16:55 41.8 12.28 88.5 11.18 09/11/2007 16:56 42 12.32 88.7 11.13 09/11/2007 16:57 41.1 12.29 89.8 11.13 09/11/2007 16:58 39.7 12.22 91.9 11.08 09/11/2007 16:59 39.6 12.16 98.4 11.09 09/11/2007 17:00 39.8 12.16 94.7 11.01 09/11/2007 17:02 41.5 12.2 71.9 11.07 09/11/2007 17:03 40.5 12.14 75.2 10.94 09/11/2007 17:04 40.6 12.03 75.1 10.98 09/11/2007 17:05 41.1 12.1 72.9 11.02 09/11/2007 17:06 42 12.2 76.3 11.12 09/11/2007 17:07 40.9 12.24 75.6 10.98 09/11/2007 17:08 40.2 12.1 76.3 10.98 09/11/2007 17:09 39.5 12.13 79.6 10.98 09/11/2007 17:10 40 12.13 81.2 11 09/11/2007 17:11 40.8 12.16 82 11 09/11/2007 17:12 40.4 12.19 80.9 11.07 09/11/2007 17:13 40.2 12.2 82.1 11.09 09/11/2007 17:14 40 12.27 86.4 11.09 09/11/2007 17:15 38.8 12.29 81.6 11.09 09/11/2007 17:16 37.5 12.17 71.2 11.01 09/11/2007 17:17 37.7 12.15 77.4 11.06 09/11/2007 17:18 38.8 12.28 80.9 11.15 09/11/2007 17:19 38.8 12.33 81.7 11.14 09/11/2007 17:20 38.3 12.26 77.3 11.09 09/11/2007 17:21 37 12.2 79.8 11 09/11/2007 17:22 37.3 12.23 78.6 11 09/11/2007 17:23 37.5 12.18 78.2 11.01 09/11/2007 17:24 38.5 12.18 81.1 11.07 09/11/2007 17:25 40.2 12.2 77.9 11.08 09/11/2007 17:26 40.4 12.24 75 11.13 NOX4 CO24 SO2_S3 CO2_S3 A vera g es: 40.13 12.065 125.23 11.052

Page 11 of 11

# APPENDIX C

OPERATIONS DATA 11-SEP-2007PI Load Data

Plant Information Source: bbnd-1pisr v Start Time: 09/11/2007 10:45

End Time: 09/11/2007 18:26 T ime Interval: 1 min

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe Run Avera g e: 419.9757801 11-Sep-07 10:45:00 420.0928955 11-Sep-07 10:46:00 420.6419067 11-Sep-07 10:47:00 420.3604126 11-Sep-07 10:48:00 419.1219177 11-Sep-07 10:49:00 420.2743225 11-Sep-07 10:50:00 422.2998657 11-Sep-07 10:51:00 421.8039551 11-Sep-07 10:52:00 420.8010254 11-Sep-07 10:53:00 420.4043274 11-Sep-07 10:54:00 418.7784424 11-Sep-07 10:55:00 419.8609314 11-Sep-07 10:56:00 420.3039856 11-Sep-07 10:57:00 419.1869812 11-Sep-07 10:58:00 419.0149841 11-Sep-07 10:59:00 419.3163757 11-Sep-07 11:00:00 419.2501831 11-Sep-07 11:01:00 419.675293 11-Sep-07 11:02:00 419.1463013 11-Sep-07 11:03:00 418.7470093 11-Sep-07 11:04:00 419.5724182 11-Sep-07 11:05:00 420.0872803 11-Sep-07 11:06:00 421.0819092 11-Sep-07 11:07:00 421.2866516 11-Sep-07 11:08:00 419.7177429 11-Sep-07 11:09:00 419.7495117 11-Sep-07 11:10:00 420.5492249 11-Sep-07 11:11:00 420.1605225 11-Sep-07 11:12:00 420.6737976 11-Sep-07 11:13:00 422.4465637 11-Sep-07 11:14:00 421.4935913 11-Sep-07 11:15:00 419.2740479 11-Sep-07 11:16:00 418.0357666 11-Sep-07 11:17:00 417.9744568 11-Sep-07 11:18:00 419.9758911 11-Sep-07 11:19:00 421.2580872 11-Sep-07 11:20:00 421.155426 11-Sep-07 11:21:00 420.4804077 11-Sep-07 11:22:00 419.6214294 11-Sep-07 11:23:00 419.4616394 11-Sep-07 11:24:00 420.9723206 11-Sep-07 11:25:00 420.3009338 11-Sep-07 11:26:00 419.2797546

Page 1 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 11:27:00 419.0191345 11-Sep-07 11:28:00 419.305542 11-Sep-07 11:29:00 420.6366272 11-Sep-07 11:30:00 420.7129211 11-Sep-07 11:31:00 420.3490295 11-Sep-07 11:32:00 418.9062195 11-Sep-07 11:33:00 420.4077148 11-Sep-07 11:34:00 421.3700562 11-Sep-07 11:35:00 420.6099243 11-Sep-07 11:36:00 419.2785339 11-Sep-07 11:37:00 419.3700867 11-Sep-07 11:38:00 419.8736572 11-Sep-07 11:39:00 419.4284668 11-Sep-07 11:40:00 419.8660278 11-Sep-07 11:41:00 420.2579041 11-Sep-07 11:42:00 420.6366272 11-Sep-07 11:43:00 418.824707 11-Sep-07 11:44:00 418.7989807 11-Sep-07 11:45:00 420.9093628 11-Sep-07 11:46:00 420.9769592 11-Sep-07 11:47:00 420.2780151 11-Sep-07 11:48:00 419.309082 11-Sep-07 11:49:00 419.3853455 11-Sep-07 11:50:00 420.3314209 11-Sep-07 11:51:00 420.7071838 11-Sep-07 11:52:00 420.7504883 11-Sep-07 11:53:00 421.0069885 11-Sep-07 11:54:00 419.5750122 11-Sep-07 11:55:00 420.1848755 11-Sep-07 11:56:00 420.3139954 11-Sep-07 11:57:00 421.5598145 11-Sep-07 11:58:00 420.0048828 11-Sep-07 11:59:00 419.0328064 11-Sep-07 12:00:00 418.96875 11-Sep-07 12:01:00 420.2398682 11-Sep-07 12:02:00 421.2845154 11-Sep-07 12:03:00 421.2622375 11-Sep-07 12:04:00 419.4793091 11-Sep-07 12:05:00 418.2948914 11-Sep-07 12:06:00 419.7341614 11-Sep-07 12:07:00 420.0202637 11-Sep-07 12:08:00 420.7831116 11-Sep-07 12:09:00 420.7412415 11-Sep-07 12:10:00 418.3260803 11-Sep-07 12:11:00 418.5033569 11-Sep-07 12:12:00 419.2327576 11-Sep-07 12:13:00 419.8736572 11-Sep-07 12:14:00 420.8849182

Page 2 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 12:15:00 419.0280762 11-Sep-07 12:16:00 418.6948853 11-Sep-07 12:17:00 420.4077148 11-Sep-07 12:18:00 420.8288879 11-Sep-07 12:19:00 420.3431091 11-Sep-07 12:20:00 419.5919189 11-Sep-07 12:21:00 420.4534912 11-Sep-07 12:22:00 420.5908508 11-Sep-07 12:23:00 419.8482361 11-Sep-07 12:24:00 418.8589172 11-Sep-07 12:25:00 419.533905 11-Sep-07 12:26:00 421.5216675 11-Sep-07 12:27:00 421.7093506 11-Sep-07 12:28:00 420.9709167 11-Sep-07 12:29:00 418.5892334 11-Sep-07 12:30:00 419.0343933 11-Sep-07 12:31:00 419.9078979 11-Sep-07 12:32:00 419.637146 11-Sep-07 12:33:00 419.0849304 11-Sep-07 12:34:00 420.1712036 11-Sep-07 12:35:00 420.5474854 11-Sep-07 12:36:00 419.8883972 11-Sep-07 12:37:00 418.4469299 11-Sep-07 12:38:00 418.9127502 11-Sep-07 12:39:00 420.2297058 11-Sep-07 12:40:00 421.007782 11-Sep-07 12:41:00 420.5145264 11-Sep-07 12:42:00 419.4311218 11-Sep-07 12:43:00 419.6020508 11-Sep-07 12:44:00 421.484436 11-Sep-07 12:45:00 420.0646667 11-Sep-07 12:46:00 418.4240112 11-Sep-07 12:47:00 418.4179382 11-Sep-07 12:48:00 419.776001 11-Sep-07 12:49:00 420.8807678 11-Sep-07 12:50:00 419.28302 11-Sep-07 12:51:00 419.7546387 11-Sep-07 12:52:00 420.3863525 11-Sep-07 12:53:00 421.1859436 11-Sep-07 12:54:00 421.2927856 11-Sep-07 12:55:00 420.2703857 11-Sep-07 12:56:00 418.1864014 11-Sep-07 12:57:00 419.1625671 11-Sep-07 12:58:00 419.2327576 11-Sep-07 12:59:00 420.7199707 11-Sep-07 13:00:00 420.2519226 11-Sep-07 13:01:00 419.0335083 11-Sep-07 13:02:00 418.6681824

Page 3 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 13:03:00 421.8115845 11-Sep-07 13:04:00 421.2622375 11-Sep-07 13:05:00 420.8288879 11-Sep-07 13:06:00 420.1233521 11-Sep-07 13:07:00 419.7764893 11-Sep-07 13:08:00 418.5689697 11-Sep-07 13:09:00 419.9423218 11-Sep-07 13:10:00 420.7230835 11-Sep-07 13:11:00 420.6610413 11-Sep-07 13:12:00 421.0305786 11-Sep-07 13:13:00 419.9499512 11-Sep-07 13:14:00 418.6834412 11-Sep-07 13:15:00 419.4616699 11-Sep-07 13:16:00 420.9265442 11-Sep-07 13:17:00 420.8331909 11-Sep-07 13:18:00 420.1506958 11-Sep-07 13:19:00 420.3497314 11-Sep-07 13:20:00 419.5615234 11-Sep-07 13:21:00 419.8344116 11-Sep-07 13:22:00 419.1744995 11-Sep-07 13:23:00 421.2035522 11-Sep-07 13:24:00 421.1210938 11-Sep-07 13:25:00 421.0722961 11-Sep-07 13:26:00 419.1162415 11-Sep-07 13:27:00 419.1869812 11-Sep-07 13:28:00 419.8220215 11-Sep-07 13:29:00 418.8429565 11-Sep-07 13:30:00 419.436676 11-Sep-07 13:31:00 419.8553467 11-Sep-07 13:32:00 420.5948486 11-Sep-07 13:33:00 419.4819946 11-Sep-07 13:34:00 419.3548279 11-Sep-07 13:35:00 419.5694275 11-Sep-07 13:36:00 420.0300598 11-Sep-07 13:37:00 419.8823853 11-Sep-07 13:38:00 420.030304 11-Sep-07 13:39:00 419.0458374 11-Sep-07 13:40:00 419.1183167 11-Sep-07 13:41:00 419.2098694 11-Sep-07 13:42:00 420.177948 11-Sep-07 13:43:00 419.9194336 11-Sep-07 13:44:00 419.4556885 11-Sep-07 13:45:00 419.9461365 11-Sep-07 13:46:00 420.1559448 11-Sep-07 13:47:00 419.2066956 11-Sep-07 13:48:00 421.0191956 11-Sep-07 13:49:00 420.9646912 11-Sep-07 13:50:00 420.3175049

Page 4 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 13:51:00 419.2474365 11-Sep-07 13:52:00 420.2810059 11-Sep-07 13:53:00 420.5542297 11-Sep-07 13:54:00 419.922821 11-Sep-07 13:55:00 421.6653442 11-Sep-07 13:56:00 419.9804688 11-Sep-07 13:57:00 419.3872681 11-Sep-07 13:58:00 421.0005493 11-Sep-07 13:59:00 421.0342407 11-Sep-07 14:00:00 421.5827026 11-Sep-07 14:01:00 419.6040955 11-Sep-07 14:02:00 419.3935547 11-Sep-07 14:03:00 418.8258667 11-Sep-07 14:04:00 419.3548279 11-Sep-07 14:05:00 419.2251282 11-Sep-07 14:06:00 418.8883362 11-Sep-07 14:07:00 419.9438477 11-Sep-07 14:08:00 420.1025391 11-Sep-07 14:09:00 420.5861816 11-Sep-07 14:10:00 420.0122681 11-Sep-07 14:11:00 419.8384399 11-Sep-07 14:12:00 420.941803 11-Sep-07 14:13:00 421.1554565 11-Sep-07 14:14:00 418.9743652 11-Sep-07 14:15:00 421.0486145 11-Sep-07 14:16:00 420.7036743 11-Sep-07 14:17:00 421.4649658 11-Sep-07 14:18:00 420.2463989 11-Sep-07 14:19:00 421.0264893 11-Sep-07 14:20:00 420.3771973 11-Sep-07 14:21:00 418.8869019 11-Sep-07 14:22:00 418.3477173 11-Sep-07 14:23:00 418.6681824 11-Sep-07 14:24:00 420.9234009 11-Sep-07 14:25:00 422.1201477 11-Sep-07 14:26:00 421.6517029 11-Sep-07 14:27:00 420.4763794 11-Sep-07 14:28:00 417.6152954 11-Sep-07 14:29:00 417.9781189 11-Sep-07 14:30:00 420.1818848 11-Sep-07 14:31:00 421.5500183 11-Sep-07 14:32:00 420.8241272 11-Sep-07 14:33:00 418.6787415 11-Sep-07 14:34:00 418.2573547 11-Sep-07 14:35:00 418.4819946 11-Sep-07 14:36:00 420.7945862 11-Sep-07 14:37:00 421.2266235 11-Sep-07 14:38:00 419.9602356

Page 5 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 14:39:00 419.6651306 11-Sep-07 14:40:00 420.9479065 11-Sep-07 14:41:00 419.2081299 11-Sep-07 14:42:00 418.4218445 11-Sep-07 14:43:00 420.7536011 11-Sep-07 14:44:00 420.3857727 11-Sep-07 14:45:00 420.9379883 11-Sep-07 14:46:00 420.0868225 11-Sep-07 14:47:00 420.5420227 11-Sep-07 14:48:00 421.1928711 11-Sep-07 14:49:00 421.4318237 11-Sep-07 14:50:00 420.7129211 11-Sep-07 14:51:00 418.8055115 11-Sep-07 14:52:00 418.6594543 11-Sep-07 14:53:00 419.0060425 11-Sep-07 14:54:00 418.7940674 11-Sep-07 14:55:00 420.1642761 11-Sep-07 14:56:00 421.23172 11-Sep-07 14:57:00 421.146698 11-Sep-07 14:58:00 419.2680054 11-Sep-07 14:59:00 419.7493896 11-Sep-07 15:00:00 419.5701599 11-Sep-07 15:01:00 419.095459 11-Sep-07 15:02:00 419.9499512 11-Sep-07 15:03:00 420.332428 11-Sep-07 15:04:00 420.8197327 11-Sep-07 15:05:00 419.2327576 11-Sep-07 15:06:00 419.2968445 11-Sep-07 15:07:00 419.977417 11-Sep-07 15:08:00 420.4077148 11-Sep-07 15:09:00 419.5074463 11-Sep-07 15:10:00 418.7056274 11-Sep-07 15:11:00 419.1963196 11-Sep-07 15:12:00 420.1213989 11-Sep-07 15:13:00 418.6834412 11-Sep-07 15:14:00 418.7139587 11-Sep-07 15:15:00 418.3091125 11-Sep-07 15:16:00 420.0476074 11-Sep-07 15:17:00 420.8296204 11-Sep-07 15:18:00 420.0923767 11-Sep-07 15:19:00 420.6885071 11-Sep-07 15:20:00 422.0128479 11-Sep-07 15:21:00 420.2246094 11-Sep-07 15:22:00 419.2480164 11-Sep-07 15:23:00 418.2103882 11-Sep-07 15:24:00 420.1669617 11-Sep-07 15:25:00 421.1635132 11-Sep-07 15:26:00 420.1869507

Page 6 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 15:27:00 420.2490234 11-Sep-07 15:28:00 419.1717224 11-Sep-07 15:29:00 418.9089355 11-Sep-07 15:30:00 419.8818054 11-Sep-07 15:31:00 421.302948 11-Sep-07 15:32:00 419.7439575 11-Sep-07 15:33:00 419.5450745 11-Sep-07 15:34:00 419.7319641 11-Sep-07 15:35:00 419.4902649 11-Sep-07 15:36:00 419.916687 11-Sep-07 15:37:00 419.6690979 11-Sep-07 15:38:00 419.5318298 11-Sep-07 15:39:00 420.8052368 11-Sep-07 15:40:00 420.5139771 11-Sep-07 15:41:00 419.0038757 11-Sep-07 15:42:00 419.2807007 11-Sep-07 15:43:00 418.6834412 11-Sep-07 15:44:00 420.1623535 11-Sep-07 15:45:00 419.2785339 11-Sep-07 15:46:00 420.8216248 11-Sep-07 15:47:00 420.9036255 11-Sep-07 15:48:00 420.4972534 11-Sep-07 15:49:00 419.5335999 11-Sep-07 15:50:00 418.5079651 11-Sep-07 15:51:00 418.6654053 11-Sep-07 15:52:00 419.5888367 11-Sep-07 15:53:00 419.7073059 11-Sep-07 15:54:00 420.5145569 11-Sep-07 15:55:00 419.8177185 11-Sep-07 15:56:00 419.1816101 11-Sep-07 15:57:00 420.304718 11-Sep-07 15:58:00 420.639679 11-Sep-07 15:59:00 420.3288879 11-Sep-07 16:00:00 421.4300842 11-Sep-07 16:01:00 419.8126221 11-Sep-07 16:02:00 419.9499512 11-Sep-07 16:03:00 419.4946899 11-Sep-07 16:04:00 419.8278809 11-Sep-07 16:05:00 420.868042 11-Sep-07 16:06:00 420.7892151 11-Sep-07 16:07:00 420.651886 11-Sep-07 16:08:00 421.0028381 11-Sep-07 16:09:00 420.7767334 11-Sep-07 16:10:00 419.9153748 11-Sep-07 16:11:00 419.2535706 11-Sep-07 16:12:00 420.1254272 11-Sep-07 16:13:00 418.8818054 11-Sep-07 16:14:00 419.4067383

Page 7 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 16:15:00 419.7668457 11-Sep-07 16:16:00 420.1442871 11-Sep-07 16:17:00 419.7454834 11-Sep-07 16:18:00 419.1488342 11-Sep-07 16:19:00 419.1412354 11-Sep-07 16:20:00 420.2366028 11-Sep-07 16:21:00 421.1767883 11-Sep-07 16:22:00 420.6824036 11-Sep-07 16:23:00 420.901886 11-Sep-07 16:24:00 421.4873352 11-Sep-07 16:25:00 420.7700195 11-Sep-07 16:26:00 419.9906616 11-Sep-07 16:27:00 420.1680908 11-Sep-07 16:28:00 419.9804688 11-Sep-07 16:29:00 419.0710144 11-Sep-07 16:30:00 419.3375854 11-Sep-07 16:31:00 419.5623474 11-Sep-07 16:32:00 420.7129211 11-Sep-07 16:33:00 419.5379639 11-Sep-07 16:34:00 419.4260559 11-Sep-07 16:35:00 419.5770874 11-Sep-07 16:36:00 419.801178 11-Sep-07 16:37:00 418.8480225 11-Sep-07 16:38:00 418.9091492 11-Sep-07 16:39:00 419.916748 11-Sep-07 16:40:00 420.5157471 11-Sep-07 16:41:00 420.6700745 11-Sep-07 16:42:00 418.7139587 11-Sep-07 16:43:00 419.6066284 11-Sep-07 16:44:00 419.8736572 11-Sep-07 16:45:00 419.6295166 11-Sep-07 16:46:00 420.5603027 11-Sep-07 16:47:00 420.2649536 11-Sep-07 16:48:00 420.178833 11-Sep-07 16:49:00 419.368103 11-Sep-07 16:50:00 419.1819153 11-Sep-07 16:51:00 420.4077148 11-Sep-07 16:52:00 420.098175 11-Sep-07 16:53:00 420.098175 11-Sep-07 16:54:00 418.8665466 11-Sep-07 16:55:00 420.413269 11-Sep-07 16:56:00 421.8747864 11-Sep-07 16:57:00 421.9554443 11-Sep-07 16:58:00 418.9530029 11-Sep-07 16:59:00 418.4240112 11-Sep-07 17:00:00 419.1930847 11-Sep-07 17:01:00 420.3421021 11-Sep-07 17:02:00 419.9324951

Page 8 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 17:03:00 421.9290771 11-Sep-07 17:04:00 419.6607666 11-Sep-07 17:05:00 419.5654297 11-Sep-07 17:06:00 419.1320496 11-Sep-07 17:07:00 419.2327576 11-Sep-07 17:08:00 421.3808289 11-Sep-07 17:09:00 420.4229736 11-Sep-07 17:10:00 420.8720398 11-Sep-07 17:11:00 419.3853455 11-Sep-07 17:12:00 419.1361084 11-Sep-07 17:13:00 419.3650208 11-Sep-07 17:14:00 419.5603943 11-Sep-07 17:15:00 420.3212585 11-Sep-07 17:16:00 419.6701965 11-Sep-07 17:17:00 419.4006042 11-Sep-07 17:18:00 419.125946 11-Sep-07 17:19:00 419.9470825 11-Sep-07 17:20:00 420.0476074 11-Sep-07 17:21:00 420.6881104 11-Sep-07 17:22:00 421.7522278 11-Sep-07 17:23:00 420.4382324 11-Sep-07 17:24:00 421.2406311 11-Sep-07 17:25:00 420.3687744 11-Sep-07 17:26:00 420.1063538 11-Sep-07 17:27:00 421.4949646 11-Sep-07 17:28:00 419.8761902 11-Sep-07 17:29:00 419.3744812 11-Sep-07 17:30:00 419.7210693 11-Sep-07 17:31:00 419.2098694 11-Sep-07 17:32:00 419.4268799 11-Sep-07 17:33:00 419.7317505 11-Sep-07 17:34:00 421.015564 11-Sep-07 17:35:00 419.7341614 11-Sep-07 17:36:00 419.8965454 11-Sep-07 17:37:00 420.8738403 11-Sep-07 17:38:00 418.7139587 11-Sep-07 17:39:00 419.6112061 11-Sep-07 17:40:00 420.0930786 11-Sep-07 17:41:00 419.9613953 11-Sep-07 17:42:00 419.7821045 11-Sep-07 17:43:00 419.9499512 11-Sep-07 17:44:00 419.5074463 11-Sep-07 17:45:00 421.0791321 11-Sep-07 17:46:00 419.415863 11-Sep-07 17:47:00 420.7940979 11-Sep-07 17:48:00 419.1315002 11-Sep-07 17:49:00 420.9723206 11-Sep-07 17:50:00 421.0606079

Page 9 of 10PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 11-Sep-07 17:51:00 418.9447937 11-Sep-07 17:52:00 417.6254578 11-Sep-07 17:53:00 418.3477173 11-Sep-07 17:54:00 420.8850708 11-Sep-07 17:55:00 420.4534912 11-Sep-07 17:56:00 418.5929565 11-Sep-07 17:57:00 418.0372314 11-Sep-07 17:58:00 419.4006042 11-Sep-07 17:59:00 421.5181274 11-Sep-07 18:00:00 421.3461914 11-Sep-07 18:01:00 418.0940552 11-Sep-07 18:02:00 418.7347412 11-Sep-07 18:03:00 419.6250305 11-Sep-07 18:04:00 420.4534912 11-Sep-07 18:05:00 421.6132202 11-Sep-07 18:06:00 419.8126221 11-Sep-07 18:07:00 421.7886963 11-Sep-07 18:08:00 421.2927551 11-Sep-07 18:09:00 420.2457581 11-Sep-07 18:10:00 418.8068848 11-Sep-07 18:11:00 418.6498718 11-Sep-07 18:12:00 418.6529236 11-Sep-07 18:13:00 420.1221619 11-Sep-07 18:14:00 422.3853149 11-Sep-07 18:15:00 421.3414001 11-Sep-07 18:16:00 418.8818054 11-Sep-07 18:17:00 418.4179382 11-Sep-07 18:18:00 419.0242004 11-Sep-07 18:19:00 420.2352905 11-Sep-07 18:20:00 421.1734619 11-Sep-07 18:21:00 421.1353455 11-Sep-07 18:22:00 419.6520996 11-Sep-07 18:23:00 420.4268188 11-Sep-07 18:24:00 419.7564697 11-Sep-07 18:25:00 419.8253479 11-Sep-07 18:26:00 420.2477417

Page 10 of 10

# APPENDIX D

AMMONIA SLIP TEST DATA (TRIGON ENGINEERING)

# D-1

FTIR SPECTROMETER DATA

# D-2

FTIR QUALITY ASSURANCE

# D-3

FTIR METHOD MAP

# APPENDIX E

CONTINUOUS EMISSIONS MONITORING DATA 11-SEP-2007Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 10:30 42.7 12.19 42.9 11.1 09/12/2007 10:31 42.8 12.3 45.7 11.18 09/12/2007 10:32 42 12.39 45.3 11.16 09/12/2007 10:33 40.8 12.26 44.5 10.99 09/12/2007 10:34 39.2 12.11 44.7 10.93 09/12/2007 10:35 40.3 12.06 48.5 10.98 09/12/2007 10:36 41.5 12.09 51.4 11.05 09/12/2007 10:37 42.7 12.26 49.5 11.1 09/12/2007 10:38 42.1 12.3 49.6 11.11 09/12/2007 10:39 40.3 12.18 51.1 11 09/12/2007 10:40 40 12.11 52 10.93 09/12/2007 10:41 39.9 12.1 53.3 10.96 09/12/2007 10:42 40.5 12.17 55.5 11.11 09/12/2007 10:43 41.3 12.26 54.4 11.12 09/12/2007 10:44 40.7 12.24 46.3 11.01 09/12/2007 10:45 39.8 12.11 40 10.98 09/12/2007 10:46 41 12.13 39.1 11.01 09/12/2007 10:47 42.5 12.18 40.5 11.08 09/12/2007 10:48 42.7 12.21 40.8 11.11 09/12/2007 10:49 44.1 12.26 40.5 11.14 09/12/2007 10:50 43 12.31 42.3 11.09 09/12/2007 10:51 42.7 12.26 43 11.14 09/12/2007 10:52 42.1 12.29 44.9 11.06 09/12/2007 10:53 41.2 12.29 46.4 11.1 09/12/2007 10:54 39.7 12.31 45.3 11.04 09/12/2007 10:55 38.8 12.17 46.7 10.97 09/12/2007 10:56 38.3 12.06 47.4 10.84 09/12/2007 10:57 39 12 49.5 10.88 09/12/2007 10:58 40.2 12.09 51 10.92 09/12/2007 10:59 41.1 12.04 53.9 10.85 09/12/2007 11:00 42.2 11.98 56.9 10.91 09/12/2007 11:01 43.4 12.03 57.1 10.89 09/12/2007 11:02 43.5 12.05 54.6 10.96 09/12/2007 11:03 43.8 12.12 48.9 11.02 09/12/2007 11:04 43 12.16 45 11.03 09/12/2007 11:05 42.5 12.11 44.4 11 09/12/2007 11:06 42.9 12.17 45.3 11.09 09/12/2007 11:07 42.9 12.25 45.6 11.09 09/12/2007 11:08 42.7 12.23 45.2 11.08 09/12/2007 11:09 41.2 12.2 46.1 11.02 09/12/2007 11:10 40.3 12.16 45.9 11.02 09/12/2007 11:11 40.3 12.16 42.5 11.04 09/12/2007 11:12 40.6 12.17 39.9 10.97

Page 1 of 6Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 11:13 40.2 12.16 37.8 10.91 09/12/2007 11:14 40.1 12.04 40.1 10.98 09/12/2007 11:15 40.7 12.16 41.6 11.01 09/12/2007 11:16 41.5 12.16 42.1 10.99 09/12/2007 11:17 41.3 12.16 43.1 10.98 09/12/2007 11:18 41.5 12.17 44.5 10.94 09/12/2007 11:19 41.5 12.06 46.6 10.89 09/12/2007 11:20 41.9 12.09 48.8 10.98 09/12/2007 11:21 41.2 12.19 49.1 10.96 09/12/2007 11:22 40 12.11 50.4 10.91 09/12/2007 11:23 40.3 12.14 51.8 10.99 09/12/2007 11:24 40.5 12.17 53.1 10.98 09/12/2007 11:25 40.2 12.16 52.8 10.96 09/12/2007 11:26 39.5 12.19 51.7 10.92 09/12/2007 11:27 39.4 12.11 50.5 10.93 09/12/2007 11:28 39.3 12.09 50.3 10.84 09/12/2007 11:29 40.5 12.03 50.7 10.89 09/12/2007 11:30 41.7 12.11 51.7 11.05 09/12/2007 11:31 42.3 12.25 45.5 11.02 09/12/2007 11:32 42.5 12.22 39.5 11.12 09/12/2007 11:33 41.6 12.22 37.1 10.97 09/12/2007 11:34 40.4 12.17 39.2 11.02 09/12/2007 11:35 42 12.27 41.6 11.14 09/12/2007 11:36 41.1 12.34 41.1 11.09 09/12/2007 11:37 39.8 12.29 41.2 11.02 09/12/2007 11:38 39.2 12.23 42.8 11.04 09/12/2007 11:39 38.4 12.19 46.2 10.94 09/12/2007 11:40 38.7 12.16 47.1 10.96 09/12/2007 11:41 39.5 12.16 47.3 10.99 09/12/2007 11:42 40.4 12.24 48.1 11.04 09/12/2007 11:43 40.6 12.26 49.6 11.05 09/12/2007 11:44 39.8 12.2 50 10.98 09/12/2007 11:45 39.8 12.16 51.9 10.95 09/12/2007 11:46 40.3 12.12 55.1 10.92 09/12/2007 11:47 42 12.15 57.5 10.99 09/12/2007 11:48 42.3 12.19 55.2 11.06 09/12/2007 11:49 42.6 12.23 51.9 11.08 09/12/2007 11:50 43.2 12.2 49.8 11.09 09/12/2007 11:51 42.6 12.23 44.9 11.08 09/12/2007 11:52 42.2 12.21 40.5 11.07 09/12/2007 11:53 41.4 12.26 38.6 11.06 09/12/2007 11:54 40.8 12.21 39.5 11.02 09/12/2007 11:55 40.1 12.15 40.9 10.94

Page 2 of 6Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 11:56 40.8 12.11 42.7 10.96 09/12/2007 11:57 41.4 12.19 43.6 11 09/12/2007 11:58 41.3 12.17 44.8 10.95 09/12/2007 11:59 42.5 12.24 47.1 11.12 09/12/2007 12:00 42.9 12.35 47.6 11.21 09/12/2007 12:01 42.5 12.4 45.6 11.24 09/12/2007 12:02 40.2 12.38 45.6 11.14 09/12/2007 12:03 38.3 12.27 48.6 11.09 09/12/2007 12:04 37.9 12.28 52 11.1 09/12/2007 12:05 37.6 12.32 51.9 11.01 09/12/2007 12:06 37.2 12.16 52.1 10.92 09/12/2007 12:07 38.1 12.01 52.8 10.82 09/12/2007 12:08 39.7 11.95 53.6 10.73 09/12/2007 12:09 41.6 11.91 53.2 10.69 09/12/2007 12:10 44.2 11.9 53.1 10.84 09/12/2007 12:11 46.4 11.95 50 10.83 09/12/2007 12:12 47.5 11.94 44.5 10.89 09/12/2007 12:13 47.5 11.96 41.1 10.93 09/12/2007 12:14 47 12 41.2 10.95 09/12/2007 12:15 46.6 12.04 41.6 10.96 09/12/2007 12:16 45.7 12.12 41.8 10.99 09/12/2007 12:17 44.6 12.14 43.7 11.01 09/12/2007 12:18 43.2 12.18 45.7 11.04 09/12/2007 12:19 42.3 12.19 49 11.09 09/12/2007 12:20 40.6 12.27 50.8 11.07 09/12/2007 12:21 39.1 12.23 50.7 10.99 09/12/2007 12:22 38.7 12.17 51.9 10.98 09/12/2007 12:23 39 12.21 54.1 11.05 09/12/2007 12:24 38.5 12.22 54.8 11.04 09/12/2007 12:25 39.2 12.19 49.6 11.06 09/12/2007 12:26 38.4 12.27 45.2 11.08 09/12/2007 12:27 38.3 12.28 43.7 11.06 09/12/2007 12:28 38.1 12.28 43.5 11.06 09/12/2007 12:29 37.3 12.26 43.2 11.04 09/12/2007 12:30 37.2 12.19 44.2 11.05 09/12/2007 12:31 37.6 12.22 45.6 11.11 09/12/2007 12:32 38.2 12.19 47.5 10.98 09/12/2007 12:33 39.8 12.2 48.2 11.04 09/12/2007 12:34 40 12.21 45.4 11.04 09/12/2007 12:35 40.9 12.23 42.2 11.02 09/12/2007 12:36 40.5 12.17 42.1 10.98 09/12/2007 12:37 40.8 12.14 44.9 11 09/12/2007 12:38 41.4 12.18 45.9 11.01

Page 3 of 6Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 12:39 41.7 12.23 47 10.99 09/12/2007 12:40 42.1 12.2 49.5 10.98 09/12/2007 12:41 42.1 12.19 50.9 10.93 09/12/2007 12:42 42.5 12.13 51.1 10.96 09/12/2007 12:43 43.3 12.1 52.1 10.97 09/12/2007 12:44 43.8 12.16 55.2 10.98 09/12/2007 12:45 44.9 12.24 51.3 10.98 09/12/2007 12:46 43.7 12.19 45.4 11.01 09/12/2007 12:47 43.6 12.28 43.7 11.06 09/12/2007 12:48 42.1 12.22 43.1 11.01 09/12/2007 12:49 42.3 12.2 43.4 11.08 09/12/2007 12:50 41.6 12.29 43.2 11.09 09/12/2007 12:51 40.8 12.28 43.7 11.05 09/12/2007 12:52 40.1 12.22 45.8 11.07 09/12/2007 12:53 40.7 12.24 44.5 11.06 09/12/2007 12:54 41.1 12.26 42 11 09/12/2007 12:55 41.2 12.11 41.2 10.96 09/12/2007 12:56 42.1 12.13 43.2 10.97 09/12/2007 12:57 43.1 12.19 45.7 10.98 09/12/2007 12:58 42.5 12.2 46.1 10.97 09/12/2007 12:59 42 12.2 48.5 10.99 09/12/2007 13:00 41.8 12.27 49.6 11.01 09/12/2007 13:01 41.9 12.22 50.8 11.06 09/12/2007 13:02 41.7 12.28 50.4 11 09/12/2007 13:03 41.1 12.18 51.3 10.9 09/12/2007 13:04 41.4 12.11 54.1 10.92 09/12/2007 13:05 42 12.17 57.1 10.99 09/12/2007 13:06 42.4 12.17 57.7 10.91 09/12/2007 13:07 43.3 12.09 52.1 10.93 09/12/2007 13:08 43.4 12.1 44.5 10.97 09/12/2007 13:09 43.3 12.11 41.9 10.94 09/12/2007 13:10 43 12.02 35.9 10.85 09/12/2007 13:11 43.9 11.93 30.1 10.77 09/12/2007 13:12 44.1 12.05 28.4 10.82 09/12/2007 13:13 43.8 12.09 28.7 10.75 09/12/2007 13:14 43.8 12.09 29.5 10.73 09/12/2007 13:15 43.6 12.04 30.3 10.68 09/12/2007 13:16 44 12.03 31.3 10.73 09/12/2007 13:17 43.6 12.11 32.8 10.81 09/12/2007 13:18 43 12.21 33.8 10.81 09/12/2007 13:19 42.3 12.25 34.5 10.82 09/12/2007 13:20 41.7 12.21 36.5 10.87 09/12/2007 13:21 40.6 12.25 37.5 10.84

Page 4 of 6Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 13:22 39.9 12.2 40.9 10.85 09/12/2007 13:23 41.5 12.27 42.3 10.92 09/12/2007 13:24 40.8 12.4 40.9 10.9 09/12/2007 13:25 39.4 12.3 36 10.84 09/12/2007 13:26 38.3 12.18 33.4 10.46 09/12/2007 13:27 38.3 12.17 32.6 10.29 09/12/2007 13:28 39.2 12.14 32.1 10.11 09/12/2007 13:29 39.6 12.17 31.1 10.01 09/12/2007 13:30 40.7 12.19 31.9 9.93 09/12/2007 13:31 41 12.19 32 9.92 09/12/2007 13:32 41 12.11 33.4 9.77 09/12/2007 13:33 41.2 12.07 35.5 9.82 09/12/2007 13:34 41.9 12.03 35.7 9.9 09/12/2007 13:35 42.2 12.09 36.1 9.93 09/12/2007 13:36 42.2 12.18 36.1 10.01 09/12/2007 13:37 42.8 12.13 37.1 9.96 09/12/2007 13:38 43.2 12.22 37.4 10.04 09/12/2007 13:39 42.3 12.22 36.1 10 09/12/2007 13:40 42.1 12.17 35.5 10 09/12/2007 13:41 41.5 12.19 36.1 10.11 09/12/2007 13:42 40.9 12.23 33.9 10.33 09/12/2007 13:43 41.5 12.29 32.8 10.63 09/12/2007 13:44 41.5 12.36 33.2 10.83 09/12/2007 13:45 40.6 12.35 33.3 10.85 09/12/2007 13:46 39.3 12.33 31.1 10.83 09/12/2007 13:47 38.2 12.21 32.6 10.83 09/12/2007 13:48 38.6 12.21 41.1 10.84 09/12/2007 13:49 39 12.2 46.1 10.91 09/12/2007 13:50 40.6 12.09 49 10.92 09/12/2007 13:51 42.4 12.19 50 11.05 09/12/2007 13:52 43.4 12.3 48 11.05 09/12/2007 13:53 43.6 12.23 48.5 11.07 09/12/2007 13:54 43 12.29 48.9 11.03 09/12/2007 13:55 42.2 12.23 51.5 10.94 09/12/2007 13:56 41 12.19 51.2 10.99 09/12/2007 13:57 41.5 12.22 52.4 10.97 09/12/2007 13:58 41.3 12.24 51.6 11.04 09/12/2007 13:59 41 12.26 51.6 11 09/12/2007 14:00 41.5 12.15 54 10.97 09/12/2007 14:01 41.9 12.12 54.1 11 09/12/2007 14:02 42.1 12.08 53.8 10.98 09/12/2007 14:03 43.6 12.14 50.4 11.01 09/12/2007 14:04 44.3 12.13 43.5 11.01

Page 5 of 6Ammonia CEMS Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 09/12/2007 14:05 43.8 12.17 39.1 10.99 09/12/2007 14:06 42.7 12.02 39.4 10.93 09/12/2007 14:07 42.7 12.1 41.1 10.98 09/12/2007 14:08 42.8 12.19 44 11.04 09/12/2007 14:09 42.2 12.24 45.5 11.07 09/12/2007 14:10 41.3 12.25 46.4 11.05 09/12/2007 14:11 40.3 12.27 46.8 11.06 09/12/2007 14:12 39.6 12.23 49.8 11.01 09/12/2007 14:13 39.8 12.28 48.6 11.07 09/12/2007 14:14 39.1 12.23 46.2 10.91 09/12/2007 14:15 39.5 12.11 46.7 10.93 09/12/2007 14:16 40.8 12.12 47.7 10.91 09/12/2007 14:17 42.4 12.12 50.5 10.93 09/12/2007 14:18 42.8 12.15 49.9 10.93 09/12/2007 14:19 42.8 12.1 50.2 10.93 09/12/2007 14:20 43 12.05 50.1 10.84 09/12/2007 14:21 42.6 11.97 49.8 10.87 09/12/2007 14:22 42.7 12.03 41.8 10.92 09/12/2007 14:23 43 12.05 39.1 10.89 09/12/2007 14:24 43.8 12.11 40.5 11.03 09/12/2007 14:25 43.2 12.22 40.4 11.05 09/12/2007 14:26 42.5 12.23 42.2 11.1 09/12/2007 14:27 41.9 12.34 43.3 11.11 09/12/2007 14:28 39.8 12.3 44.8 11.04 09/12/2007 14:29 38.9 12.29 47.3 11.1 09/12/2007 14:30 37.8 12.39 49.9 11.06 09/12/2007 14:31 36.8 12.33 51.4 11.03 09/12/2007 14:32 36.1 12.26 51 10.95 09/12/2007 14:33 37.2 12.23 48.9 10.95 09/12/2007 14:34 37.2 12.18 49.2 10.93 09/12/2007 14:35 38.5 12.15 51.8 10.94 09/12/2007 14:36 39.5 12.21 53.2 10.92 09/12/2007 14:37 40 12.16 53.7 10.93 41.3065 12.179 45.23831 10.91706

Page 6 of 6

# APPENDIX F

OPERATIONS DATA 12-SEP-2007PI Load Data

Plant Information Source: bbnd-1pisr v Start Time: 09/12/2007 11:30

End Time: 09/12/2007 15:37 T ime Interval: 1 min

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe Run Avera g e: 410.051045 12-Sep-07 11:30:00 409.828369 12-Sep-07 11:31:00 410.450043 12-Sep-07 11:32:00 411.259796 12-Sep-07 11:33:00 410.753906 12-Sep-07 11:34:00 410.204193 12-Sep-07 11:35:00 409.387512 12-Sep-07 11:36:00 409.535522 12-Sep-07 11:37:00 410.153503 12-Sep-07 11:38:00 411.368134 12-Sep-07 11:39:00 410.748077 12-Sep-07 11:40:00 408.400024 12-Sep-07 11:41:00 408.490234 12-Sep-07 11:42:00 410.565521 12-Sep-07 11:43:00 411.158783 12-Sep-07 11:44:00 411.21405 12-Sep-07 11:45:00 410.041321 12-Sep-07 11:46:00 409.921417 12-Sep-07 11:47:00 409.390564 12-Sep-07 11:48:00 409.745667 12-Sep-07 11:49:00 409.214386 12-Sep-07 11:50:00 410.174133 12-Sep-07 11:51:00 409.10498 12-Sep-07 11:52:00 409.634705 12-Sep-07 11:53:00 409.438019 12-Sep-07 11:54:00 409.461121 12-Sep-07 11:55:00 410.275574 12-Sep-07 11:56:00 410.405273 12-Sep-07 11:57:00 410.357605 12-Sep-07 11:58:00 410.361267 12-Sep-07 11:59:00 409.822632 12-Sep-07 12:00:00 409.858032 12-Sep-07 12:01:00 410.130859 12-Sep-07 12:02:00 410.956696 12-Sep-07 12:03:00 410.236084 12-Sep-07 12:04:00 409.431244 12-Sep-07 12:05:00 409.511658 12-Sep-07 12:06:00 410.142365 12-Sep-07 12:07:00 409.809082 12-Sep-07 12:08:00 409.998871 12-Sep-07 12:09:00 409.270233 12-Sep-07 12:10:00 409.789551 12-Sep-07 12:11:00 410.207672

Page 1 of 6PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 12-Sep-07 12:12:00 409.725708 12-Sep-07 12:13:00 410.248108 12-Sep-07 12:14:00 409.908722 12-Sep-07 12:15:00 410.512268 12-Sep-07 12:16:00 410.519714 12-Sep-07 12:17:00 410.016174 12-Sep-07 12:18:00 410.30838 12-Sep-07 12:19:00 410.009644 12-Sep-07 12:20:00 410.458679 12-Sep-07 12:21:00 409.375275 12-Sep-07 12:22:00 408.828491 12-Sep-07 12:23:00 409.81723 12-Sep-07 12:24:00 410.298981 12-Sep-07 12:25:00 411.252167 12-Sep-07 12:26:00 410.873047 12-Sep-07 12:27:00 410.742767 12-Sep-07 12:28:00 409.35495 12-Sep-07 12:29:00 409.624512 12-Sep-07 12:30:00 410.408325 12-Sep-07 12:31:00 410.901215 12-Sep-07 12:32:00 410.118622 12-Sep-07 12:33:00 409.043274 12-Sep-07 12:34:00 408.433563 12-Sep-07 12:35:00 409.295929 12-Sep-07 12:36:00 411.106293 12-Sep-07 12:37:00 411.174988 12-Sep-07 12:38:00 411.590942 12-Sep-07 12:39:00 410.458679 12-Sep-07 12:40:00 408.937744 12-Sep-07 12:41:00 408.948029 12-Sep-07 12:42:00 410.306091 12-Sep-07 12:43:00 411.54718 12-Sep-07 12:44:00 411.103943 12-Sep-07 12:45:00 409.616028 12-Sep-07 12:46:00 409.454437 12-Sep-07 12:47:00 409.661133 12-Sep-07 12:48:00 410.867493 12-Sep-07 12:49:00 409.861298 12-Sep-07 12:50:00 409.546112 12-Sep-07 12:51:00 410.00177 12-Sep-07 12:52:00 410.15271 12-Sep-07 12:53:00 410.479462 12-Sep-07 12:54:00 410.370514 12-Sep-07 12:55:00 411.656921 12-Sep-07 12:56:00 412.563843 12-Sep-07 12:57:00 410.307556 12-Sep-07 12:58:00 408.024261 12-Sep-07 12:59:00 408.733643

Page 2 of 6PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 12-Sep-07 13:00:00 409.706207 12-Sep-07 13:01:00 409.253204 12-Sep-07 13:02:00 408.626434 12-Sep-07 13:03:00 408.9617 12-Sep-07 13:04:00 409.297089 12-Sep-07 13:05:00 409.822906 12-Sep-07 13:06:00 410.090302 12-Sep-07 13:07:00 410.359497 12-Sep-07 13:08:00 411.122009 12-Sep-07 13:09:00 410.860535 12-Sep-07 13:10:00 410.368011 12-Sep-07 13:11:00 409.973267 12-Sep-07 13:12:00 410.709381 12-Sep-07 13:13:00 410.420807 12-Sep-07 13:14:00 410.771332 12-Sep-07 13:15:00 410.193634 12-Sep-07 13:16:00 409.34549 12-Sep-07 13:17:00 410.16571 12-Sep-07 13:18:00 410.611298 12-Sep-07 13:19:00 410.473938 12-Sep-07 13:20:00 410.224243 12-Sep-07 13:21:00 410.104675 12-Sep-07 13:22:00 411.191132 12-Sep-07 13:23:00 410.293457 12-Sep-07 13:24:00 409.434143 12-Sep-07 13:25:00 408.937866 12-Sep-07 13:26:00 409.453918 12-Sep-07 13:27:00 409.320343 12-Sep-07 13:28:00 410.500458 12-Sep-07 13:29:00 410.91748 12-Sep-07 13:30:00 411.042053 12-Sep-07 13:31:00 410.107727 12-Sep-07 13:32:00 409.344757 12-Sep-07 13:33:00 410.026337 12-Sep-07 13:34:00 410.739655 12-Sep-07 13:35:00 408.917511 12-Sep-07 13:36:00 408.734406 12-Sep-07 13:37:00 409.334595 12-Sep-07 13:38:00 409.461334 12-Sep-07 13:39:00 409.985657 12-Sep-07 13:40:00 410.926422 12-Sep-07 13:41:00 410.271515 12-Sep-07 13:42:00 409.018768 12-Sep-07 13:43:00 409.646149 12-Sep-07 13:44:00 411.402069 12-Sep-07 13:45:00 409.914856 12-Sep-07 13:46:00 410.153503 12-Sep-07 13:47:00 409.284332

Page 3 of 6PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 12-Sep-07 13:48:00 409.969086 12-Sep-07 13:49:00 409.909363 12-Sep-07 13:50:00 409.790344 12-Sep-07 13:51:00 410.214539 12-Sep-07 13:52:00 410.084839 12-Sep-07 13:53:00 410.802246 12-Sep-07 13:54:00 409.509796 12-Sep-07 13:55:00 409.376373 12-Sep-07 13:56:00 409.999207 12-Sep-07 13:57:00 410.857788 12-Sep-07 13:58:00 409.691925 12-Sep-07 13:59:00 409.505005 12-Sep-07 14:00:00 411.114838 12-Sep-07 14:01:00 409.860809 12-Sep-07 14:02:00 409.733887 12-Sep-07 14:03:00 409.896271 12-Sep-07 14:04:00 409.649963 12-Sep-07 14:05:00 410.290833 12-Sep-07 14:06:00 409.945343 12-Sep-07 14:07:00 410.27948 12-Sep-07 14:08:00 410.931732 12-Sep-07 14:09:00 409.627075 12-Sep-07 14:10:00 409.653351 12-Sep-07 14:11:00 409.879547 12-Sep-07 14:12:00 411.180969 12-Sep-07 14:13:00 411.123352 12-Sep-07 14:14:00 410.972412 12-Sep-07 14:15:00 409.936066 12-Sep-07 14:16:00 409.415497 12-Sep-07 14:17:00 410.456055 12-Sep-07 14:18:00 411.358978 12-Sep-07 14:19:00 410.996277 12-Sep-07 14:20:00 410.530823 12-Sep-07 14:21:00 408.945679 12-Sep-07 14:22:00 409.512634 12-Sep-07 14:23:00 409.283722 12-Sep-07 14:24:00 410.154694 12-Sep-07 14:25:00 410.266418 12-Sep-07 14:26:00 410.412903 12-Sep-07 14:27:00 409.164703 12-Sep-07 14:28:00 409.009064 12-Sep-07 14:29:00 410.439484 12-Sep-07 14:30:00 410.153503 12-Sep-07 14:31:00 410.683777 12-Sep-07 14:32:00 410.28067 12-Sep-07 14:33:00 410.724091 12-Sep-07 14:34:00 410.042267 12-Sep-07 14:35:00 409.833069

Page 4 of 6PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 12-Sep-07 14:36:00 410.061951 12-Sep-07 14:37:00 410.370331 12-Sep-07 14:38:00 410.865265 12-Sep-07 14:39:00 410.715576 12-Sep-07 14:40:00 411.343719 12-Sep-07 14:41:00 409.787292 12-Sep-07 14:42:00 408.261353 12-Sep-07 14:43:00 409.151886 12-Sep-07 14:44:00 408.970917 12-Sep-07 14:45:00 409.955139 12-Sep-07 14:46:00 409.496033 12-Sep-07 14:47:00 410.606201 12-Sep-07 14:48:00 411.090424 12-Sep-07 14:49:00 410.458679 12-Sep-07 14:50:00 408.663361 12-Sep-07 14:51:00 409.291351 12-Sep-07 14:52:00 411.008026 12-Sep-07 14:53:00 410.204895 12-Sep-07 14:54:00 411.062683 12-Sep-07 14:55:00 409.716248 12-Sep-07 14:56:00 408.766083 12-Sep-07 14:57:00 409.629608 12-Sep-07 14:58:00 410.200653 12-Sep-07 14:59:00 410.537537 12-Sep-07 15:00:00 410.269043 12-Sep-07 15:01:00 408.856476 12-Sep-07 15:02:00 409.158142 12-Sep-07 15:03:00 410.63092 12-Sep-07 15:04:00 411.282684 12-Sep-07 15:05:00 410.641815 12-Sep-07 15:06:00 411.174805 12-Sep-07 15:07:00 409.461975 12-Sep-07 15:08:00 410.138245 12-Sep-07 15:09:00 409.360046 12-Sep-07 15:10:00 409.384674 12-Sep-07 15:11:00 409.222717 12-Sep-07 15:12:00 410.261688 12-Sep-07 15:13:00 410.44342 12-Sep-07 15:14:00 411.08432 12-Sep-07 15:15:00 409.138763 12-Sep-07 15:16:00 408.596283 12-Sep-07 15:17:00 409.105316 12-Sep-07 15:18:00 409.572266 12-Sep-07 15:19:00 410.827698 12-Sep-07 15:20:00 411.474548 12-Sep-07 15:21:00 411.175873 12-Sep-07 15:22:00 410.997681 12-Sep-07 15:23:00 410.904602

Page 5 of 6PI Load Data

T a g Name: 4spuw501 g T a g Explanation: Unit Load T a g Units: Mwe 12-Sep-07 15:24:00 408.449554 12-Sep-07 15:25:00 408.807556 12-Sep-07 15:26:00 409.569855 12-Sep-07 15:27:00 409.092133 12-Sep-07 15:28:00 409.673676 12-Sep-07 15:29:00 410.018341 12-Sep-07 15:30:00 409.24884 12-Sep-07 15:31:00 409.360046 12-Sep-07 15:32:00 410.155792 12-Sep-07 15:33:00 410.042328 12-Sep-07 15:34:00 411.191132 12-Sep-07 15:35:00 410.95755 12-Sep-07 15:36:00 410.763885 12-Sep-07 15:37:00 409.92099

Page 6 of 6

# APPENDIX G

FUEL INFORMATION

# G-1

BUNKERING INFORMATION 11-SEP-2007BIG BEND STATIO N FUEL BUNKERING INFORMATIO NTOTALRUN TIME Tons % Tons % Tons % Tons9/10/07 9:58 PM 103 12.4% 4 0.5% 726 87.2% 8339/11/07 1:00 AM 31 9.6% 0 0.0% 291 90.4% 3229/11/07 4:35 AM 34 9.8% 9 2.6% 304 87.6% 3479/11/07 11:15 AM 129 10.8% 29 2.4% 1035 86.8% 11939/11/07 5:13 PM 0 0.0% 2 0.3% 781 99.7% 783TOTAL297 8.5% 44.0 1.3% 3137.0 90.2%3478Note: Last test run, run #3, was completed at 6:28 PMPET COKE POLK RESIDUAL COAL STANDARD COAL

# G-2

FUEL ANALYSIS

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For:


## Laboratory ID: AA90279

Date and Time Collected: Sampled By: 

### Sample Information

ASG Description 

### Location Code: 10/19/2007 Report Date:

Big Bend 4 Compliance 

### TE_BB_4_COMP_COAL

Project Account Code:
9/12/2007 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 9/11/2007 12:00:00 AM

Result PARAMETER Qualifier Code Test

Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower

Limit

60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 4.28 9/19/2007 11:26:00 AM

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 8.91 9/20/2007 11:10:00 AM

Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 9.95 9/20/2007 11:10:00 AM

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 11769 9/20/2007 11:09:00 AM

BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 13139 9/20/2007 11:09:00 AM

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14591 9/20/2007 11:10:00 AM

Carbon, as Received % 0.5 ASTM D-5373 KASZS 66.81 9/26/2007 9:46:00 AM

Carbon, Dry Basis % 0.5 ASTM D-5373 KASZS 74.59 9/26/2007 9:46:00 AM

Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.15 9/26/2007 9:51:00 AM

Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.17 9/26/2007 9:51:00 AM

Hydrogen, as Received % 0.14 ASTM D-5373 KASZS 4.33 9/26/2007 9:46:00 AM

Hydrogen, Dry Basis % 0.14 ASTM D-5373 KASZS 4.83 9/26/2007 9:46:00 AM

Nitrogen, as Received % 0.10 ASTM D-5373 KASZS 1.41 9/26/2007 9:46:00 AM

Nitrogen, Dry Basis % 0.10 ASTM D-5373 KASZS 1.57 9/26/2007 9:46:00 AM

NOx emission rate, lb/mmBtu lb/mmBtu EPA RM-7E KARAM 0.07 9/19/2007 9:06:00 AM

NOx emission rate, lbs/hr lbs/hr EPA RM-7E KARAM 305 9/19/2007 9:06:00 AM

Oxygen, as Received % ASTM D-5373 KASZS 5.04 9/26/2007 9:46:00 AM

Oxygen, Dry Basis % Calculated KASZS 5.63 9/26/2007 9:46:00 AM

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 15.45 9/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 14.80 9/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 15.25 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 4.25 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 2.65 9/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 3.15 9/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 1 mg 0.0001 EPA Method 5B/17 KARAM 19.70 9/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 2 mg 0.0001 EPA Method 5B/17 KARAM 17.45 9/19/2007 9:06:00 AM

Report Number: Page 1 of 2 "General Report"

AA90279-101907-09

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test

Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower

Limit
Particulate Wt., Total Sample, Run 3 mg 0.0001 EPA Method 5B/17 KARAM 18.40 9/19/2007 9:06:00 AM

PM, lb/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.01 9/19/2007 9:06:00 AM

Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated KAPXJ 4.71 9/19/2007 12:57:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KARAM 1445 9/19/2007 9:06:00 AM

SO2 emission rate, lbs/mmBtu lbs/mmBtu EPA - RM6C KARAM 0.34 9/19/2007 9:06:00 AM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 2.92 9/20/2007 11:09:00 AM

Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.26 9/20/2007 11:09:00 AM

Total Moisture % 0.1 ASTM D-3173 KAPXJ 10.43 9/20/2007 11:08:00 AM



### Comments

Designee for Peggy Penner, Manager, Laboratory Services All results calculated on a wet to wet basis, unless otherwise indicated.
Should there be any questions regarding this report, please contact:

(813) 630-7490 Mirey A. Makaryus,

Report Number: Page 2 of 2 "General Report"

AA90279-101907-09

# G-3

PRECIPITATOR LOGS 11-SEP-2007

# G-4

BUNKERING INFORMATION 12 SEP-2007BIG BEND STATIO N FUEL BUNKERING INFORMATIO NPET COKEPOLK RESIDUAL COALSTANDARD COALTOTALBUNKER RUN TIMETons%Tons%Tons%Tons9/11/07 10:00 PM81.610.4%20.3%697.489.3%7819/12/07 1:15 AM77.410.4%30.64.1%636.185.5%744.19/12/07 4:40 AM64.910.0%29.14.5%553.185.5%647.19/12/07 12:45 PM142.710.9%41.73.2%1121.785.9%1306.1TOTAL366.610.5%103.43.0%3008.386.5%3478.3Test was completed by 3:45 PM

# APPENDIX H

TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL SERVICES AIR SERVICES GROUP – TEST TEAM Jorge Varino Environmental Technician – Team Lead Gary Barber Associate Technician Scott Given Associate Technician

TRIGON ENGINEERING –TEST TEAM Bryan Starnes Project Manager Joshua Jones Assistant Project Manager Larry Reynolds Senior Scientist Dr. Grant Plummer FTIR Analys t – Enthalpy Analytical, Inc.

PROCESS DATA Curtis Seebaran Engin eer – Big Bend Station R.A. McDarby Senior Environmental Technician

FUEL ANALYSIS Patrice Jackson Envi ronmental Technician Sam Soth Environmental Technician

PARTICULATE LABORATORY Sam Soth Environmental Technician

ANCILLARY DATA COLL ECTION AND ANALYSIS R.A. McDarby Senior Environmental Technician

PROJECT QUALITY OBJECTIVES & REPORTING R.A. McDarby Senior Environmental Technician W. Quentin Best Quality Assura nce Manager – Trigon Engineering

TEST COORDINATION Curtis Seebaran Engin eer – Big Bend Station David A. Smith Coordinator –Air Services Group