# Patent

## Title
Zoned catalyst for treating exhaust gas

## Abstract

Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system. Also provided is a method for using the system to treat exhaust gas.

## Background
CROSS-REFERENCE TO RELATED APPLICATIONS
This application claims the priority benefit of U.S. Provisional Application No. 62/037,939, filed Aug. 5, 2014, which is incorporated herein by reference.


BACKGROUND
Field of Invention
The present invention relates to a system of zoned catalysts and methods for treating combustion exhaust gas.
Description of Related Art
Combustion of hydrocarbon-based fuel in engines produces exhaust gas that contains, in large part, relatively benign nitrogen (N2), water vapor (H2O), and carbon dioxide (CO2). But the exhaust gases also contain, in relatively small part, noxious and/or toxic substances, such as carbon monoxide (CO) from incomplete combustion, hydrocarbons (HC) from un-burnt fuel, nitrogen oxides (NOx) from excessive combustion temperatures, and particulate matter (mostly soot). To mitigate the environmental impact of flue and exhaust gas released into the atmosphere, it is desirable to eliminate or reduce the amount of the undesirable components, preferably by a process that, in turn, does not generate other noxious or toxic substances.
Typically, exhaust gases from lean burn gas engines have a net oxidizing effect due to the high proportion of oxygen that is provided to ensure adequate combustion of the hydrocarbon fuel. In such gases, one of the most burdensome components to remove is NOx, which includes nitric oxide (NO), nitrogen dioxide (NO2), and nitrous oxide (N2O). The reduction of NOx to N2 is particularly problematic because the exhaust gas contains enough oxygen to favor oxidative reactions instead of reduction. Notwithstanding, NOx can be reduced by a process commonly known as Selective Catalytic Reduction (SCR). An SCR process involves the conversion of NOx, in the presence of a catalyst and with the aid of a reducing agent, such as ammonia, into elemental nitrogen (N2) and water. In an SCR process, a gaseous reductant such as ammonia is added to an exhaust gas stream prior to contacting the exhaust gas with the SCR catalyst. The reductant is absorbed onto the catalyst and the NOx reduction reaction takes place as the gases pass through or over the catalyzed substrate. The chemical equation for stoichiometric SCR reactions using ammonia is:

4NO+4NH3+O2→4N2+6H2O

2NO2+4NH3+O2→3N2+6H2O

NO+NO2+2NH3→2N2+3H2O

Zeolites having an exchanged transition metal are known to be useful as SCR catalysts. Conventional small pore zeolites exchanged with copper are particularly useful in achieving high NOx conversion at low temperatures. However, the interaction of NH3 with NO absorbed onto the transition metal of an exchanged zeolite can lead to an undesirable side reaction that produces N2O. This N2O is particularly problematic to remove from the exhaust stream. Accordingly, there remains a need for improved methods that result in a high conversion of NOx with minimal N2O production. The present invention satisfies this need amongst others.
SUMMARY OF THE INVENTION
Applicants have found that the combination of at least two SCR catalytic zones, one of which contains a vanadium based catalyst and the other of which contains a copper loaded molecular sieve, can substantially reduce the undesirable production of N2O while maintaining overall high N2 selectivity in an SCR reaction, provided that the vanadium-based catalyst is upstream of the copper loaded molecular sieve. For example, high N2 selectivity and low N2O byproduct can be achieved by a metal oxide loaded with about 0.5-4 weight percent vanadium, based on the total weight of the metal oxide, and a downstream small pore molecular sieve loaded with about 1-4 weight percent copper, based on the total weight of the molecular sieve. In certain embodiments, the upstream vanadium-based catalyst is present at a higher washcoat loading relative to the downstream copper-based catalyst.
Accordingly, in one aspect provided is a system for treating an exhaust gas comprising (a) a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3; and (b) a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system.
In another aspect of the invention, provided is a method for treating an exhaust gas comprising the step of contacting, in series, a mixture of ammonia and exhaust gas derived from an internal combustion engine with (a) a first SCR zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3, and (b) a second SCR zone comprising a copper-loaded small pore molecular sieve.



BRIEF DESCRIPTION OF THE FIGURES
FIG. 1 is a diagram showing an embodiment of the invention with an arrangement of zoned SCR catalysts;
FIG. 2 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts;
FIG. 3 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts;
FIG. 4 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts;
FIG. 4A is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts;
FIG. 5 is a diagram showing an embodiment of the invention with arrangement of zoned SCR catalysts and an ammonia oxidation catalyst;
FIG. 6 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts comprising two substrates;
FIG. 6A is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts comprising two substrates and an ASC zone;
FIG. 7 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts, wherein one of the zones is in an extruded catalyst body;
FIG. 7A is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts, wherein one of the zones is in an extruded catalyst body;
FIG. 8 is a diagram showing an embodiment of the invention with another arrangement of zoned SCR catalysts, wherein the zones are on an extruded catalyst body;
FIG. 9 is a diagram of a flow-through honeycomb substrate comprising zoned SCR catalysts;
FIG. 9A is a diagram of a cell of a flow-through honeycomb substrate;
FIG. 10 is a diagram of a system for treating exhaust gas according to an embodiment of the invention;
FIG. 11A is a diagram of a system for treating exhaust gas according to an embodiment of the invention; and
FIG. 11B is diagram of another system for treating exhaust gas according to an embodiment of the invention.



DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS OF THE INVENTION
Provided is a system and method for improving environmental air quality, and in particular for treating exhaust gas emissions generated by power plants, gas turbines, lean burn internal combustion engines, and the like. Exhaust gas emissions are improved, at least in part, by reducing NOx concentrations over a broad operational temperature range. The conversion of NOx is accomplished by contacting the exhaust gas with two or more specific NH3—SCR catalysts arranged in zones.
In part, the system comprises two NH3—SCR catalyst zones: a first SCR catalyst zone comprising (a) a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3; and (b) a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system. In one example, the vanadium-based catalyst is coated on and/or within the channel walls of the flow-through monolith in a first zone and the copper loaded small-pore molecular sieve is coated on and/or within the channel walls of the flow-through monolith in a second zone, the first zone being upstream of the second zone. In certain embodiments, the first SCR catalyst zone can be in the form of an extruded catalyst body (e.g., a honeycomb) and the second SCR catalyst zone is a coating on the body. In another example, the vanadium-based catalyst is coated on and/or within a wall-flow filter and the copper loaded small-pore molecular sieve is coated on and/or within the channel walls of the flow-through monolith disposed downstream of the filter.
Turning to FIG. 1, shown is an embodiment of the invention in which a flow-through honeycomb substrate 10 has a first catalyst zone 20 and a second catalyst zone 30, wherein the first and second catalyst zones are consecutive and in contact. The terms “first zone” and “second zone”, as used herein, are indicative of the zone's orientation on the substrate. More specifically, the zones are oriented in series so that under normal operating conditions, the exhaust gas to be treated contacts the first zone prior to contacting the second zone. In one embodiment, the first and second SCR catalyst zones are arranged consecutively, so that one follows the other in an uninterrupted succession (i.e., there is no catalyst or other exhaust gas treatment operation such as a filter between the first and second SCR catalyst zones). Therefore, in certain embodiments the first SCR catalyst zone is upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through or over a substrate or series of substrates.
Differences in the catalyst materials of the first and second SCR catalyst zones result in different treatment of the exhaust gas. For example, the first SCR catalyst zone reduces NOx with lower selectivity to by-products (including N2O at low temperature), and the second SCR catalyst zone efficiently reduces NOx at a higher efficiency relative to the first SCR catalyst zone. The synergistic effect of the combination of the two SCR catalyst zones improves the overall performance of the catalyst compared to single catalyst systems or other zoned arrangements. Preferably, the first and second zones are in contact (i.e., there are no intervening catalytically active layers between the first and second SCR catalyst zones).
In FIG. 9, a zoned catalytic substrate 2 is shown wherein the substrate is a honeycomb flow-through monolith 100 having an inlet end 110 and an outlet end 120, relative to the normal direction of exhaust gas flow 1 through the substrate. The substrate has an axial length 190 that extends from the inlet end 110 to the outlet end 120. FIG. 10 shows a single cell 200 of a honeycomb substrate having channel walls 110 that define open channels 120 through which exhaust gas can flow. The channel walls are preferable porous or semi-porous. The catalyst of each zone can be a coating on the surface of the walls, a coating that permeates partially or fully into the walls, incorporated directly into the wall as an extruded body, or some combination thereof.
In FIG. 1, the first SCR catalyst zone 20 extends from the inlet end 110 to a first end point 29. The first end point is positioned about 10 to 90 percent, for example about 80-90 percent, about 10 to 25 percent or about 20-30 percent, of the axial length 190. The second SCR catalyst zone 120 extends from the outlet end 120 for a certain distance along axial length 190, for example about 20 to 90 percent, for example about 60 to about 80 percent or about 50 to about 75 percent, of the axial length 190. Preferably, the second SCR catalyst zone extends to at least the first end point so that the first and second SCR catalyst zones are in contact. The axial length is preferably less than 24 inches, such as about 1 to about 24 inches, about 3 to about 12 inches, or about 3 to about 8 inches.
In FIG. 2 a preferred embodiment is shown in which the first SCR catalyst zone 20 partially overlaps the second SCR catalyst zone 30. In FIG. 3, the second SCR catalyst zone 30 partially overlaps the first SCR catalyst zone 20. The overlap is preferably less than 90 percent of the axial length of the substrate, for example about 80 to about 90 percent, less than about 40, about 40 to about 60 about 10 to about 15 percent, or about 10 to about 25 percent. For embodiments in which the second SCR catalyst zone overlaps the first SCR catalyst zone the overlap can be greater than 50 percent of the axial length, such as 80-90 percent. For embodiments in which the first SCR catalyst zone overlaps the second SCR catalyst zone, the overlap is preferably less than 50 percent of the axial length, for example about 10-20 percent.
In FIG. 4, the first SCR catalyst zone 20 completely overlaps the second SCR catalyst zone 30. For such embodiments, exhaust gas first contacts, and is at least partially treated by, the first SCR catalyst zone. At least a portion of the exhaust gas permeates through the first SCR catalyst zone where it contacts the second SCR catalyst zone and is further treated. A least a portion of the treated exhaust gas permeates back through the first SCR catalyst zone, enters the open channel, and exits the substrate. FIG. 4 shows an embodiment in which both the first and second SCR catalyst zones extend the entire axial length of the substrate. FIG. 4A shows an alternative embodiment in which the second SCR catalyst zone extends from the outlet end to less than the full axial length of the substrate and the first SCR catalyst zone extends the entire axial length of the substrate, thus completely overlapping the second SCR catalyst zone.
FIG. 5 shows another embodiment of the invention. Here, a third catalyst zone is proximal to, and preferably extends from, the outlet end of the substrate. The third catalyst zone comprises an oxidation catalyst, preferably a catalyst effective to oxidize ammonia. In certain embodiments, the catalyst comprises one or more platinum group metals (PGM), such as Pt, Pd, or a combination thereof, preferably on a metal oxide support, such as alumina. The oxidation catalyst can include a zeolite, such as FER or BEA, optionally loaded with a metal including iron or a PGM, such as palladium. The combination of the second and third catalyst zones in a layered arrangement serves as an ammonia slip catalyst, wherein at least a portion of the excess ammonia not consumed by the upstream SCR reaction passes through the second zone to the third catalyst zone where it is oxidized into H2O and secondary NOx. The H2O and secondary NOx pass back through the second catalyst zone where at least a portion of the secondary NOx is reduced to N2 and H2O via an SCR-type reaction.
Preferably, the first and second SCR catalyst zones are consecutively arranged so that the first SCR catalyst zone contacts the second SCR catalyst zone. In certain embodiments the first and second SCR catalyst zones are coated or otherwise incorporated on separate substrates which are arranged in an exhaust gas treatment system so that the first and second SCR catalyst zones are in series and are either in contact or separated by a short distance with no intervening exhaust gas treatment catalyst. Where two substrates are used, the substrates can be the same or different substrates. For example, the first substrate can be a wall-flow filter and the second substrate can be a flow-through honeycomb, the first and second substrates can have different porosities, the first and second substrates can be different compositions or have a different cell density, and/or the first and second substrates can be different lengths. In FIG. 6, the first and second SCR catalyst zones are arranged on separate substrates which are arranged in an exhaust gas treatment system so that the first and second SCR catalyst zones are in series and are adjacent, but are not in direct contact. In certain embodiments, the maximum distance between the first and second substrates is preferably less than 2 inches, more preferably less than 1 inch, and preferably there are no intervening substrates, filters, or catalyst materials between the first and second SCR catalyst zones and/or between the first and second substrates. In FIG. 6A, the second substrate further comprises an ammonia oxidation catalyst under-layer 40 that extends from the outlet end of the substrate to a length less than the total length of substrate. The second SCR catalyst zone completely covers the oxidative catalyst and preferably extends the length of the substrate.
In certain embodiments, the first SCR catalyst zone is in the form of an extruded honeycomb body. The embodiment shown in FIG. 7, for example, comprises a second SCR catalyst zone 26 in the form of a coating on and/or within a portion of an extruded catalyst substrate. The extruded catalyst substrate, in turn, comprises the first SCR catalyst zone 16. The first and second SCR catalyst zones are arranged so that the first zone is upstream of the second zone with respect to the normal flow of exhaust gas 1. The catalytically active substrate in zone 16 comprises a catalytically active material similar to that of the other first SCR catalyst zones described herein. In FIG. 7, the second SCR catalyst zone extends from the outlet end to less than the full length of the substrate. In FIG. 7A, the second SCR catalyst zone 26 completely covers the third zone comprising an oxidation catalyst 27.
In another embodiment, the second SCR catalyst zone is in the form of an extruded honeycomb body and the first SCR catalyst zone is in the form of a washcoat disposed on the extruded honeycomb body, for example as a zone at the front of the honeycomb body.
In FIG. 8, a catalytically active substrate 300, for example a flow-through honeycomb body formed from an extruded catalytic material, is coated with a first SCR catalyst zone 310 and a second SCR catalyst zone 330. The catalytic component of the extruded body can be a passive NOx absorber, a supplemental SCR catalyst, or other catalyst for treating an exhaust gas. The first SCR catalyst zone extends from the inlet end 312 to a first end point 314 that is positioned about 10 to 80 percent, for example about 50-80 percent, about 10 to 25 percent, or about 20-30 percent, of the axial length 390. The second SCR catalyst zone extends from the outlet end 344 to a second end point 332 that is position about 20 to 80 percent, for example about 20-40 percent, about 60 to about 80 percent, or about 50 to about 75 percent, of the axial length 390. The first and second SCR catalyst zones are not in direct contact and thus a gap 320 exists between the upstream and the downstream zone. Preferably this gap does not contain a catalyst layer but instead is directly exposed to the exhaust gas to be treated. The exhaust gas contacts the catalytic body at the gap whereby the exhaust gas is treated, for example to selectively reduce a portion of NOx in the exhaust gas. The gap, which is defined by the first end point 314 and the second end point 332, is preferably less than 75 percent of the axial length, for example about 40 to about 60, about 10 to about 15 percent, or about 10 to about 25 percent of the axial length 390. An optional NH3 oxidation catalyst is coated on and/or within the substrate 300 in a zone that extends from the outlet end 344 towards the inlet end 312 for a length that is equal to or less than the length of the downstream zone. The optional NH3 oxidation catalyst is preferably an under-layer that is completely covered by the catalyst composition forming the downstream zone.
The vanadium based catalyst is preferably loaded on a metal oxide at a concentration of about 0.5 to about 4 weight percent, or about 1 to 2 weight percent, based on the total weight of the metal oxide support. Preferred vanadium components include oxides of vanadium, such as vanadia (V2O5) and metal vanadate (e.g., FeVO4) and, optionally, oxides of tungsten. In certain embodiments, the vanadium component comprises up to about 25 weight percent oxides of tungsten, preferably from about 1 to about 25 weight percent, more preferably from about 5 to about 20 weight percent, and even more preferably from about 5 to about 15 weight percent based on the total weight of the vanadium component.
Suitable metals for the metal vanadate include alkaline earth metals, transition metals, rare earth metals, or combinations thereof. For the purpose of the present specification and claims, the term “alkaline earth metal” means at least one of the elements of group II on the periodic table and “transition metal” means at least one of the elements of groups IV-XI on the periodic table and Zn. Useful alkaline earth metals include Mg, Ca, Sr, and Ba; rare earth elements include Sc, Y, and the fifteen Lanthanides, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, preferably Er; and transition metal is selected from the group consisting of Fe, Bi, Al, Ga, In, Zn, Mo, Cr, Sb and Mn. In a particularly preferred embodiment of the present invention, the vanadium component is iron (III) vanadate, that optionally includes WO3.
The type of metal oxide support is not particularly limited. Useful metal oxides include TiO2, ZrO2, SiO2, CeO2, and Al2O3. In certain embodiments, the metal oxide support and the vanadium component are present in a weight ratio of about 100:1 to about 50:1.
Typically, the vanadium component and the metal oxide support are in the form of self-supporting catalyst particles. In various embodiments, the metal oxide support will have a surface area (BET) of from about 10 to about 300 m2/g or more. In certain embodiments, metal oxide support will have an average particle size of about 10 to about 250 nanometers (nm), preferably about 10 to about 100 nm.
A preferred metal oxide is titanium dioxide (TiO2) which is also known as titania or titanium(IV) oxide, and is preferably in the anatase form. In certain embodiments, the TiO2 is at least 90 weight percent, and more preferably at least 95 weight percent, anatase form relative to the rutile form. In certain embodiments, the TiO2 is chemically stabilized and/or pre-calcined, for example as an end product of sulphate processing. Such chemically stabilized TiO2 displays the X-ray reflexes that are specific to the TiO2 lattice in X-ray diffractometry.
In another embodiment, the first SCR catalyst zone comprises a blend of vanadium supported on metal oxide and a molecular—either bare (e.g., a zeolite in H+ form) or loaded with Fe. Preferably, the blend comprises about 60 to about 99 weight percent vanadium component and about 1 to about 40 weight percent molecular sieve component, based on the total weight of catalytically active components in the blend. In certain embodiments, the catalyst composition comprises about 60 to about 70, about 75 to about 85, or about 90 to about 97 weight percent vanadium component and about 30 to about 40, about 15 to about 25, or about 3 to about 10 weight percent molecular sieve component.
Preferred vanadium and metal oxides for a blend include those described herein and can optionally include a tungsten component as described herein.
Preferably the molecular sieve for the blend is an aluminosilicate, preferably without substituted metals in the framework, or a ferrosilicate. Molecular sieves, particularly aluminosilicates, are in the H+ form or are ion exchanged with a transition metal. Preferably, the aluminosilicate is substantially free of alkali and alkaline earth metals. H+ form molecular sieves preferably are free of non-framework metals. In certain embodiments the molecular sieve in the blend is essentially free of any non-framework metal other than Fe. Preferably, the ion exchange occurs after synthesis of the molecular sieve.
Useful MFI isotypes include ZSM-5, [Fe—Si—O]-MFI, AMS-1B, AZ-1, Bor-C, Boralite, Encilite, FZ-1, LZ-105, Mutinaite, NU-4, NU-5, Silicalite, TS-1, TSZ, TSZ-III, TZ-01, USC-4, USI-108, ZBH, ZKQ-1B, and ZMQ-TB, with ZSM-5 being particularly preferred. Useful FER isotypes include Ferrierite, [Si—O]-FER, FU-9, ISI-6, Monoclinic ferrierite, NU-23, Sr-D, and ZSM-35. Useful BEA isotypes include Beta [Ti—Si—O]-*BEA, CIT-6 and Tschernichite. Typical SiO2/Al2O3 mole ratios for such materials are 30 to 100 and typical SiO2/Fe2O3 mole ratios are 20 to 300 such as 20 to 100.
Preferred molecular sieve frameworks for the blend include FER, MFI, and BEA. In certain embodiments, the molecular sieve is not a small pore molecular sieve. Preferably, the BEA framework contains either exchanged iron or is an iron isomorphous BEA molecular structure (also referred to as BEA-type ferrosilicate), with iron isomorphous BEA molecular structure being particularly preferred. In certain preferred embodiments, the BEA-type ferrosilicate molecular structure is a crystalline silicate having (1) an iron-containing BEA-framework structure that has a SiO2/Fe2O3 mol ratio of about 20 to about 300, and/or (2) at least 80% of the contained iron as isolated iron ions Fe3− in a fresh state.
Preferably, iron-containing BEA-framework structure that has a SiO2/Fe2O3 mol ratio of about 25 to about 300, about 20 to about 150, about 24 to about 150, about 25 to about 100, or about 50 to about 80. The upper limit of log (SiO2/Al2O3) by mol is not particularly limited, provided that the log(SiO2/Al2O3) by mol is at least 2 (i.e., the SiO2/Al2O3 ratio by mol is at least 100). The log(SiO2/Al2O3) by mol is preferably at least 2.5 (i.e., the SiO2/Al2O3 ratio by mol is at least 310), more preferably at least 3 (i.e., the SiO2/Al2O3 ratio by mol is at least 1000). When the log(SiO2/Al2O3) by mol exceeds 4 (i.e., the SiO2/Al2O3 ratio by mol becomes at least 10,000).
In certain embodiments, the iron is present in the molecular sieve of the blend at a concentration of about 0.1 to about 10 weight percent (wt %) based on the total weight of the molecular sieve, for example from about 0.5 wt % to about 5 wt %, from about 0.5 to about 1 wt %, from about 1 to about 5 wt %, about 2 wt % to about 4 wt %, and about 2 wt % to about 3 wt %. Iron may be incorporated into the molecular sieves for use in the present invention using techniques well known in the art, including liquid-phase exchange or solid-ion exchange or by an incipient wetness process. Such materials are referred to herein as iron-containing or iron-promoted molecular sieves.
The catalyst composition of the present invention can be prepared by blending the vanadium component and the molecular sieve component. The type blending technique is not particularly limited. In certain embodiments a TiO2/WO3 suspension is prepared to which V2O5 powder and iron-promoted molecular sieve powder are added. The resulting suspension can be formulated as a washcoat or can be dried and calcined in a powder form which is then used to prepare a washcoat or an extrudable material.
The second catalytic zone comprises a second NH3—SCR catalyst composition that include a copper loaded small pore molecular sieve as a catalytically active component and optionally other components, particularly catalytically inactive components such as binders. As used herein, a “catalytically active” component is one that directly participates in the catalytic reduction of NOx and/or oxidization of NH3 or other nitrogenous-based SCR reductants. By corollary, a “catalytically inactive” component is one which does not directly participate in the catalytic reduction of NOx and/or oxidization of NH3 or other nitrogenous-based SCR reductants.
Useful molecular sieves are crystalline or quasi-crystalline materials which can be, for example aluminosilicates (zeolites) or silicoaluminophosphates (SAPOs). Such molecular sieves are constructed of repeating SiO4, AlO4, and optionally PO4 tetrahedral units linked together, for example in rings, to form frameworks having regular intra-crystalline cavities and channels of molecular dimensions. The specific arrangement of tetrahedral units (ring members) gives rise to the molecular sieve's framework, and by convention, each unique framework is assigned a unique three-letter code (e.g., “CHA”) by the International Zeolite Association (IZA). The molecular sieve can also be an intergrowth of two or more frameworks, such as AEI and CHA. In certain embodiments, the second zone can comprise a blend of two or more molecular sieves. Preferred blends have at least one molecular sieve having a CHA framework, and more preferably a majority of the CHA framework.
Particularly useful molecular sieves are small pore zeolites. As used herein, the term “small pore zeolite” means a zeolite framework having a maximum ring size of eight tetrahedral atoms. Preferably, the primary crystalline phase of the molecular sieve is constructed of one or more small pore frameworks, although other molecular sieve crystalline phases may also be present. Preferably, the primary crystalline phase comprises at least about 90 weight percent, more preferably at least about 95 weight percent, and even more preferably at least about 98 or at least about 99 weight percent small pore molecular sieve framework, based on the total amount of molecular sieve material.
In some examples, the small pore zeolite for use in the present invention have a pore size in at least one dimension of less than 4.3 Å. In one embodiment, the small pore zeolite has a framework selected from the group of consisting of: ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, CHA, DDR, DFT, EAB, EDI, EPI, ERI, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, RTH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG and ZON. Preferred zeolite frameworks are selected from AEI, AFT, AFX, CHA, DDR, ERI, LEV, KFI, RHO, and UEI. For certain applications, preferred zeolite frameworks are selected from AEI, AFT, and AFX particularly AEI. In certain application, a preferred zeolite framework is CHA. In certain applications, an ERI framework is preferred. Particular zeolites that are useful for the present invention include SSZ-39, Mu-10, SSZ-16, SSZ-13, Sigma-1, ZSM-34, NU-3, ZK-5, and MU-18. Other useful molecular sieves include SAPO-34 and SAPO-18.
Preferred aluminosilicates have a silica-to-alumina ratio (SAR) of about 10 to about 50, for example about 15 to about 30, about 10 to about 15, 15 to about 20, about 20 to about 25, about 15 to about 18, or about 20 to about 30. Preferred SAPOs have an SAR of less than 2, for example about 0.1 to about 1.5 or about 0.5 to about 1.0. The SAR of a molecular sieve may be determined by conventional analysis. This ratio is meant to represent, as closely as possible, the ratio in the rigid atomic framework of the molecular sieve crystal and to exclude silicon or aluminum in the binder or in cationic or other form within the channels. Since it may be difficult to directly measure the SAR of the molecular sieve after it has been combined with a binder material, particularly an alumina binder the SAR value described herein is expressed in terms of the SAR of the molecular sieve per se, i.e., prior to the combination of the zeolite with the other catalyst components.
In another example, the second zone molecular sieve is a SAPO having a SAR of less than 1.
The molecular sieve may include framework metals other than aluminum (i.e., metal-substituted zeolites). As used herein, the term “metal substituted” with respect to a molecular sieve means a molecular sieve framework in which one or more aluminum or silicon framework atoms has been replaced by the substituting metal. In contrast, the term “metal exchanged” means a molecular sieve in which one or more ionic species associated with the zeolite (e.g., H+, NH4+, Na+, etc.) has been replaced by a metal (e.g., a metal ion or free metal, such as metal oxide), wherein the metal is not incorporated as a molecular sieve framework atom (e.g., T-atom), but instead is incorporated into the molecular pores or on the external surface of the molecular sieve framework. The exchanged metal is a type of “extra-framework metal”, that is a metal that resides within the molecular sieve and/or on at least a portion of the molecular sieve surface, preferably as an ionic species, does not include aluminum, and does not include atoms constituting the framework of the molecular sieve. The terms “metal-loaded molecular sieve” means a molecular sieve that includes one or more extra-framework metals. As used herein, the terms “aluminosilicate” and “silicoaluminophosphate” are exclusive of metal-substituted molecular sieves.
The copper-loaded molecular sieves of the present invention comprise the metal disposed on and/or within the molecular sieve material as an extra-framework metal. Preferably the presence and concentration of the copper facilitates the treatment of exhaust gases, such as exhaust gas from a diesel engine, including processes such as NOx reduction, NH3 oxidation, and NOx storage, while also suppressing the formation of N2O. Unless otherwise specified, the amount of copper loaded onto a molecular sieve and the copper concentration in the catalyst is referenced in terms of the copper per total weight of the corresponding molecular sieve, and is thus independent of the amount of catalyst washcoat loading on the substrate or the presence of other materials in the catalyst washcoat.
In certain embodiments, the extra-framework copper is present in the molecular sieve of the second zone at a concentration of about 0.1 to about 10 weight percent (wt %) based on the total weight of the molecular sieve, for example from about 0.5 wt % to about 5 wt %, from about 0.5 to about 1 wt %, from about 1 to about 5 wt %, about 2.5 wt % to about 3.5 wt %, and about 3 wt % to about 3.5 wt %.
In addition copper, the molecular sieve can further comprise one or more additional extra-framework metals, provided that the additional extra-framework metal is present in a minority amount (i.e., <50 mol. %, such as about 1 to 30 mol. %, about 1-10 mol. % or about 1-5 mol. %) relative to the copper and is not inclusive of iron. The additional extra-framework metal may be any of the recognized catalytically active metals that are used in the catalyst industry to form metal-exchanged molecular sieves, particularly those metals that are known to be catalytically active for treating exhaust gases derived from a combustion process. Particularly preferred are metals useful in NOx reduction and storage processes. Examples of such metals include metal nickel, zinc, tungsten, molybdenum, cobalt, titanium, zirconium, manganese, chromium, vanadium, niobium, as well as tin, bismuth, and antimony; platinum group metals, such as ruthenium, rhodium, palladium, indium, platinum, and precious metals such as gold and silver. Preferred transition metals are base metals, and preferred base metals include those selected from the group consisting of chromium, manganese, cobalt, nickel, and mixtures thereof.
In certain examples of the invention, the copper-loaded molecular sieves are free of platinum group metals. In certain examples of the invention, the copper-loaded molecular sieves are free of alkali and alkaline earth metals. In certain examples of the invention, the copper-loaded molecular sieve is free of transition metals except copper.
Preferably, the copper is highly dispersed within the molecular sieve crystals. The transition metal loading is preferably fully ion exchanges and/or is preferably less than can be accommodated by the exchange sites of the molecular sieve support. Preferably, the catalyst is free or substantially free of bulk copper oxide, free or substantially free of species of copper on external molecular sieve crystal surfaces, and/or free or substantially free of copper metal clusters as measured by temperature programmed reduction (TPR) analysis and/or UV-vis analysis.
In one example, a metal-exchanged molecular sieve is created by mixing the molecular sieve, for example an H-form molecular sieve or an NH4-form molecular sieve, into a solution containing soluble precursors of the catalytically active metal(s). The pH of the solution may be adjusted to induce precipitation of the catalytically active metal cations onto or within the molecular sieve structure (but not including the molecular sieve framework. For example, in a preferred embodiment, a molecular sieve material is immersed in a solution containing a metal nitrate or metal acetate for a time sufficient to allow incorporation of the catalytically active metal cations into the molecular sieve structure by ion exchange. Un-exchanged metal ions are precipitated out. Depending on the application, a portion of the un-exchanged ions can remain in the molecular sieve material as free metals. The metal-exchanged molecular sieve may then be washed, dried, and calcined. The calcined material may include a certain percentage of copper as copper oxide, respectfully, residing on the surface of the molecular sieve or within the molecular sieve cavities.
Generally, ion exchange of the catalytic metal cation into or on the molecular sieve may be carried out at room temperature or at a temperature up to about 80° C. over a period of about 1 to 24 hours at a pH of about 7. The resulting catalytic molecular sieve material is preferably dried and then calcined at a temperature of at least about 500° C.
In certain embodiments, the catalyst composition comprises the combination of copper and at least one alkali or alkaline earth metal, wherein the copper and alkali or alkaline earth metal(s) are disposed on or within the molecular sieve material. The alkali or alkaline earth metal can be selected from sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium, or some combination thereof. Preferred alkali or alkaline earth metals include calcium, potassium, barium, and combinations thereof.
In certain embodiments, the catalyst composition is essentially free of magnesium and/or barium. In certain embodiments, the catalyst is essentially free of any alkali or alkaline earth metal except calcium and potassium. In certain embodiments, the catalyst is essentially free of any alkali or alkaline earth metal except calcium. In certain embodiments, the catalyst is essentially free of any alkali or alkaline earth metal except barium. And in certain other embodiments, the catalyst is essentially free of any alkali or alkaline earth metal except potassium. As used herein, the term “essentially free” means that the material does not have an appreciable amount of the particular metal. That is, the particular metal is not present in amount that would affect the basic physical and/or chemical properties of the material, particularly with respect to the material's capacity to selectively reduce or store NOx. In certain embodiments, the molecular sieve material has an alkali content of less than 3 weight percent, more preferably less than 1 weight percent, and even more preferably less than 0.1 weight percent.
The alkali/alkaline earth metal can be added to the molecular sieve via any known technique such as ion exchange, impregnation, isomorphous substitution, etc. The copper and the alkali or alkaline earth metal can be added to the molecular sieve material in any order (e.g., the metal can be exchanged before, after, or concurrently with the alkali or alkaline earth metal) but preferably the alkali or alkaline earth metal is added prior to or concurrently with the copper.
The catalytic articles of the present invention are applicable for heterogeneous catalytic reaction systems (i.e., solid catalyst in contact with a gas reactant). To improve contact surface area, mechanical stability, and/or fluid flow characteristics, the SCR catalysts are disposed on and/or within a substrate such as honeycomb cordierite brick. In certain embodiments, one or more of the catalyst compositions is applied to the substrate as a washcoat(s). Alternatively, one or more of the catalyst compositions is kneaded along with other components such as fillers, binders and reinforcing agents into an extrudable paste which is then extruded through a die to form a honeycomb brick.
Certain aspects of the invention provide a catalytic washcoat. The washcoat comprising a copper-loaded molecular sieve catalyst described herein is preferably a solution, suspension, or slurry. Suitable coatings include surface coatings, coatings that penetrate a portion of the substrate, coatings that permeate the substrate, or some combination thereof.
A washcoat can also include non-catalytic components, such as fillers, binders, stabilizers, rheology modifiers, and other additives, including one or more of alumina, silica, non-molecular sieve silica alumina, titania, zirconia, ceria. In certain embodiments, the washcoat composition may comprise pore-forming agents such as graphite, cellulose, starch, polyacrylate, and polyethylene, and the like. These additional components do not necessarily catalyze the desired reaction, but instead improve the catalytic material's effectiveness, for example, by increasing its operating temperature range, increasing contact surface area of the catalyst, increasing adherence of the catalyst to a substrate, etc. In certain embodiments, the washcoat loading of the copper-catalyst is >0.3 g/in3, such as >1.2 g/in3, >1.5 g/in3, >1.7 g/in3 or >2.00 g/in3, and <4.5 g/in3, such as 2-4 g/in3. In certain embodiments, the copper-catalyst washcoat is applied to a substrate in a loading of about 0.8 to 1.0 g/in3, 1.0 to 1.5 g/in3, 1.5 to 2.5 g/in3, or 2.5 to 4.5 g/in3. In certain embodiments, the washcoat loading of the vanadium-catalyst is >0.5 g/in3, such as >1.5 g/in3, >3 g/in3, and preferably <6 g/in3, such as 2-5 g/in3. In certain embodiments, the vandaium-catalyst washcoat is applied to a substrate in a loading of about 1-2 g/in3, 2-3 g/in3, 3-5 g/in3, or 5-6 g/in3. In certain embodiments, the washcoat containing the vanadium catalyst is applied to substrate at a higher concentration relative to the copper-catalyst washcoat loading. More preferably, the catalyst article has higher vanadium-catalyst washcoat concentration than the corresponding copper-catalyst washcoat, but also has a higher overall copper-loading relative to the vanadium-loading. Such embodiments can be achieved, for example, by disposing a high washcoat loading of vanadium catalyst on a smaller section of the substrate relative to the copper catalyst washcoat.
Preferred substrates, particularly for mobile applications, include flow-through monoliths having a so-called honeycomb geometry that comprise multiple adjacent, parallel channels that are open on both ends and generally extend from the inlet face to the outlet face of the substrate and result in a high-surface area-to-volume ratio. For certain applications, the honeycomb flow-through monolith preferably has a high cell density, for example about 600 to 1000 cells per square inch, and/or an average internal wall thickness of about 0.18-0.35 mm, preferably about 0.20-0.25 mm. For certain other applications, the honeycomb flow-through monolith has a low cell density of about 150-600 cells per square inch, such as about 200-400 cells per square inch. Preferably, the honeycomb monoliths are porous. In addition to cordierite, silicon carbide, silicon nitride, ceramic, and metal, other materials that can be used for the substrate include aluminum nitride, silicon nitride, aluminum titanate, α-alumina, mullite, e.g., acicular mullite, pollucite, a thermet such as Al2OsZFe, Al2O3/Ni or B4CZFe, or composites comprising segments of any two or more thereof. Preferred materials include cordierite, silicon carbide, and alumina titanate.
Preferred filter substrates include diesel particulate filters, and preferred diesel particulate filters for use in mobile applications include wall-flow filters, such as wall-flow ceramic monoliths. Other filter substrates include flow through filters, such as metal or ceramic foam or fibrous filters. In addition to cordierite, silicon carbide, and ceramic, other materials that can be used for the porous substrate include, but are not limited to, alumina silica, aluminum nitride, silicon nitride, aluminum titanate, α-alumina, mullite, pollucite, zircon, zirconia, spinel, borides, feldspar, titania, fused silica, borides, ceramic fiber composites, mixtures of any of these, or composites comprising segments of any two or more thereof. Particularly preferred substrate include cordierite, silicon carbide, and aluminum titanate (AT), wherein AT is the predominate crystalline phase.
The porous walls of a wall-flow filter have an inlet side and an outlet side relative to the typical direction of exhaust gas flow through the walls. The inlet side has an inlet surface that is exposed to the channels open to the front of the substrate, and the outlet side has an outlet surface that is exposed to the channels open to the rear of the substrate.
Wall-flow filter substrates for diesel engines typically contain about 100-800 cpsi (channels per square inch), for example about 100 to about 400 cpsi, about 200 to about 300 cpsi, or about 500 to about 600 cps. In certain embodiments, the walls have an average wall thickness of about 0.1 to about 1.5 mm, for example about 0.15 to about 0.25 mm, about 0.25 to about 0.35 mm, or about 0.25 to about 0.50 mm.
Wall flow filters for use with the present invention preferably have an efficiency of at least 70%, at least about 75%, at least about 80%, or at least about 90%. In certain embodiments, the efficiency will preferably be from about 75 to about 99%, about 75 to about 90%, about 80 to about 90%, or about 85 to about 95%.
The filter's useful range of porosity and mean pore size are not particularly limited but are correlated to, or are used to determine, the particle size and viscosity of the catalyst coating. As described herein, the filter substrate's porosity and mean pore size are determined based on a bare filter (e.g., without a catalyst coating). In general, the porosity of the substrate is at least about 40%, more preferably at least about 50%, for example about 50 to about 80%, about 50 to about 70 percent, or about 55 to about 65 percent. Porosity may be measure by any suitable means, including mercury porosimetry. In general, the mean pore size of the substrate is about 8 to about 40 μm, for example about 8 to about 12 μm, about 12 to about 20 μm, or about 15 to about 25 μm. In certain embodiments, at least about 50%, and more preferably at least about 75% of the pores are within these ranges, based on the total pore volume and/or total number of pores. Mean pore size can be determined by any acceptable means, including by mercury porosimetry. In certain embodiments, the filter substrate has a mean pore size of about 12 to about 15 μm and a porosity of about 50 to about 55%. In preferred embodiments, the filter substrate has a mean pore size of about 18 to about 20 μm and a porosity of about 55 to about 65%.
The catalyst washcoat of first SCR catalyst zone can be loaded on the inlet side of the filter walls, the outlet side of the filter walls, partially or fully permeate the filter walls, or some combination thereof. In certain embodiments, the filter is the substrate for the first or second SCR catalyst zone as described herein. For example, a wall flow filter can be used as a substrate for the first zone and a flow-through honeycomb can be used as the substrate for the second zone. In another example, a flow-through honeycomb can be used as the substrate for the first zone and a wall-flow filter can be used as the substrate for the second zone. In such embodiments in which the second substrate is a wall-flow filter, the wall flow filter may further comprise an NH3 oxidation catalyst to form an ASC zone, preferably on the outlet side of the filter.
In certain embodiments, the invention is a catalyst article made by a process described herein. In a particular embodiment, the catalyst article is produced by a process that includes the steps of applying the first SCR catalyst composition, preferably as a washcoat to a substrate as a layer either before or after the second SCR catalyst composition, preferably as a washcoat, has been applied to the substrate.
In certain embodiments, the second SCR catalyst composition is disposed on the substrate as a top layer and another composition, such as an oxidation catalyst, reduction catalyst, scavenging component, or NOx storage component, is disposed on the substrate as a bottom layer.
In general, the production of an extruded solid body containing the first SCR catalyst composition involves blending the vanadium component, the metal oxide support, optionally WO3, a binder, an optional organic viscosity-enhancing compound into an homogeneous paste which is then added to a binder/matrix component or a precursor thereof and optionally one or more of stabilized ceria, and inorganic fibers. The blend is compacted in a mixing or kneading apparatus or an extruder. The mixtures have organic additives such as binders, pore formers, plasticizers, surfactants, lubricants, dispersants as processing aids to enhance wetting and therefore produce a uniform batch. The resulting plastic material is then molded, in particular using an extrusion press or an extruder including an extrusion die, and the resulting moldings are dried and calcined. The organic additives are “burnt out” during calcinations of the extruded solid body. Preferably, the vanadium component is dispersed throughout, and preferably evenly throughout, the entire extruded catalyst body.
Extruded catalyst bodies according to the present invention generally comprise a unitary structure in the form of a honeycomb having uniform-sized and parallel channels extending from a first end to a second end thereof. Channel walls defining the channels are porous. Typically, an external “skin” surrounds a plurality of the channels of the extruded solid body. The extruded solid body can be formed from any desired cross section, such as circular, square or oval. Individual channels in the plurality of channels can be square, triangular, hexagonal, circular etc.
The catalytic article described herein can promote the reaction of a nitrogenous reductant preferably ammonia, with nitrogen oxides to selectively form elemental nitrogen (N2) and water (H2O). Examples of such nitrogenous reductants include ammonia and ammonia hydrazine or any suitable ammonia precursor, such as urea ((NH2)2CO) ammonium carbonate, ammonium carbamate, ammonium hydrogen carbonate or ammonium formate. The SCR process of the present method can result in a NOx (NO and/or NO2) conversion of at least 75%, preferably at least 80%, and more preferably at least 90% over a broad temperature range (e.g., about 150-700° C., about 200-350° C., about 350-550° C., or about 450-550° C.).
The exhaust gas treatment system can comprise an NAC and/or an external source of nitrogenous reductant (e.g., an ammonia or urea injector) disposed upstream of the catalytic article. The system can include a controller for the metering the external nitrogenous reductant into the flowing exhaust gas only when it is determined that the SCR catalyst zones are capable of catalyzing NOx reduction at or above a desired efficiency, such as at above 100° C., above 150° C. or above 175° C. The metering of the nitrogenous reductant can be arranged such that 60% to 200% of theoretical ammonia is present in exhaust gas entering the SCR catalyst calculated at 1:1 NH3/NO and 4:3 NH3/NO2.
Importantly, the use of zoned catalysts according to the present invention generates low amounts of N2O byproduct compared to conventional SCR catalysts. That is, the SCR process of the present method can result in low N2O generation based on NO and/or NO2 at the SCR inlet. For example, the relative ratio of inlet NO concentration at the SCR catalyst compared to outlet N2O concentration after the SCR catalyst is greater than about 25, greater than about 30 (for example about 30 to about 40), greater than about 50, greater than about 80, or greater than about 100 over a broad temperature range (e.g., about 150-700° C., about 200-350° C., about 350-550° C. or about 450-550° C.). In another example, the relative ratio of inlet NO2 concentration at the SCR catalyst compared to outlet N2O concentration after the SCR catalyst is greater than about 50, greater than about 80, or greater than about 100 over a broad temperature range (e.g., about 150-700° C., about 200-350° C., about 350-550° C., or about 450-550° C.).
The metal-loaded molecular sieve catalyst described herein can promote the storage or oxidation of ammonia or can be coupled with an oxidation catalyst, such as a platinum and/or palladium supported on alumina, can also promote the oxidation of ammonia and limit the undesirable formation of NOx by the oxidation process (i.e., an ammonia slip catalyst (ASC)). In certain embodiments, the catalytic article of the present invention contains an ASC zone at the outlet end of the substrate. In other embodiments, an ammonia slip catalyst disposed on a separate brick downstream of the zoned SCR catalysts. These separate bricks can be adjacent to, and in contact with, each other or separated by a specific distance, provided that they are in fluid communication with each other and provided that the SCR catalyst brick is disposed upstream of the ammonia slip catalyst brick.
In certain embodiments, the SCR and/or ASC process is performed at a temperature of at least 100° C. In another embodiment, the process(es) occur at a temperature from about 150° C. to about 750° C. In a particular embodiment, the temperature range is from about 175 to about 550° C. In another embodiment, the temperature range is from 175 to 400° C. In yet another embodiment, the temperature range is 450 to 900° C., preferably 500 to 750° C., 500 to 650° C., 450 to 550° C., or 650 to 850° C.
According to another aspect of the invention, provided is a method for the reduction of NOx compounds and/or oxidation of NH3 in a gas which comprises contacting the gas with a catalyst described herein for a time sufficient to reduce the level of NOx compounds in the gas. Methods of the present invention may comprise one or more of the following steps: (a) accumulating and/or combusting soot that is in contact with the inlet of a filter; (b) introducing a nitrogenous reducing agent into the exhaust gas stream prior to contacting the SCR catalyst, preferably with no intervening catalytic steps involving the treatment of NOx and the reductant; (c) generating NH3 over a NOx adsorber catalyst or lean NOx trap, and preferably using such NH3 as a reductant in a downstream SCR reaction: (d) contacting the exhaust gas stream with a DOC to oxidize hydrocarbon based soluble organic fraction (SOF) and/or carbon monoxide into CO2, and/or oxidize NO into NO2, which in turn, may be used to oxidize particulate matter in particulate filter; and/or reduce the particulate matter (PM) in the exhaust gas; (e) contacting the exhaust gas with one or more downstream SCR catalyst device(s) (filter or flow-through substrate) in the presence of a reducing agent to reduce the NOx concentration in the exhaust gas; and (f) contacting the exhaust gas with an ammonia slip catalyst, preferably downstream of the SCR catalyst to oxidize most, if not all, of the ammonia prior to emitting the exhaust gas into the atmosphere or passing the exhaust gas through a recirculation loop prior to exhaust gas entering/re-entering the engine.
The systems described herein can at least one additional component for treating the exhaust gas, wherein the first and second SCR zones and at least one additional component are designed to function as a coherent unit. The zoned SCR catalytic article and at least one additional component are in fluid communication, optionally by one or more sections of conduit for channeling exhaust gas through the system.
In an embodiment, all or at least a portion of the nitrogen-based reductant, particularly NH3, for consumption in the SCR process can be supplied by a NOx adsorber catalyst (NAC), a lean NOx trap (LNT), or a NOx storage/reduction catalyst (NSRC), (collectively NAC) disposed upstream of the SCR catalyst. In certain embodiments, the NAC is coated on the same flow-through substrate as the zoned SCR catalyst. in such embodiments, the NAC and SCR catalysts are coated in series with the NAC being upstream of the SCR zones.
NAC components useful in the present invention include a catalyst combination of a basic material (such as alkali metal, alkaline earth metal or a rare earth metal, including oxides of alkali metals, oxides of alkaline earth metals, and combinations thereof), and a precious metal (such as platinum), and optionally a reduction catalyst component, such as rhodium. Specific types of basic material useful in the NAC include cesium oxide, potassium oxide magnesium oxide, sodium oxide, calcium oxide, strontium oxide, barium oxide, and combinations thereof. The precious metal is preferably present at about 10 to about 200 g/ft3, such as 20 to 60 g/ft3. Alternatively, the precious metal of the catalyst is characterized by the average concentration which may be from about 40 to about 100 grams/ft3.
Under certain conditions, during the periodically rich regeneration events, NH3 may be generated over a NOx adsorber catalyst. The SCR catalyst downstream of the NOx adsorber catalyst may improve the overall system NOx reduction efficiency. In the combined system, the SCR catalyst is capable of storing the released NH3 from the NAC catalyst during rich regeneration events and utilizes the stored NH3 to selectively reduce some or all of the NOx that slips through the NAC catalyst during the normal lean operation conditions.
The exhaust gas treatment system can comprise an oxidation catalyst (e.g., a diesel oxidation catalyst (DOC)) for oxidizing nitrogen monoxide in the exhaust gas to nitrogen dioxide can be located upstream of a point of metering the nitrogenous reductant into the exhaust gas. In one embodiment, the oxidation catalyst is adapted to yield a gas stream entering the SCR zeolite catalyst having a ratio of NO to NO2 of from about 20:1 to about 1:10 by volume, e.g. at an exhaust gas temperature at oxidation catalyst inlet of 200° C. to 550° C. The oxidation catalyst can include at least one platinum group metal (or some combination of these), such as platinum, palladium, or rhodium, coated on a flow-through monolith substrate. In one embodiment, the at least one platinum group metal is platinum, palladium or a combination of both platinum and palladium. The platinum group metal can be supported on a high surface area washcoat component such as alumina, a zeolite such as an aluminosilicate zeolite, silica, non-zeolite silica alumina, ceria, zirconia, titania or a mixed or composite oxide containing both ceria and zirconia.
The exhaust gas treatment system can comprise an additional SCR catalyst on a second flow-through monolith or a wall-flow filter, wherein the second flow-through monolith or wall-flow filter containing the additional SCR is positioned upstream or downstream of, and in fluid communication with, the first and second SCR catalyst zones described herein. The additional SCR catalyst is preferably a metal-exchanged zeolite, such as Fe-Beta, Fe-iron-isomorphous Beta, Fe-ZSM5, Fe-CHA, Fe-ZSM-34, Fe-AEI, Cu-Beta, Cu-ZSM5, Cu-CHA, Cu-ZSM-34, or Cu-AEI.
The exhaust gas treatment system can comprise a suitable particulate filter, such as a wall-flow filter. Suitable filters include those useful in removing soot from an exhaust gas stream. The filter can be bare and passively regenerated, or can contain a soot combustion catalyst or a hydrolysis catalyst. A filter can be positioned in the exhaust gas treatment system either upstream or downstream of the SCR catalysts. Preferably, the filter is positioned downstream of the DOC if a DOC is present. For embodiments comprising a bare filter (i.e. having no catalyst coating) and an ammonia injector upstream of the zoned SCR catalyst, the injector can be positioned upstream or downstream of the filter provided that it is positioned upstream of the zoned SCR catalyst. For embodiments having a filter containing a hydrolysis catalyst and downstream zoned SCR catalyst, an ammonia injector is preferable positioned upstream of the filter.
Turning to FIG. 10, shown is an exhaust gas treatment system comprising an internal combustion engine 501, an exhaust gas treatment system 502, a direction of exhaust gas flow through the system 1, an optional DOC 510 and/or an optional NAC 520, an optional particulate filter 570, an optional external source of ammonia and injector 530, a zoned SCR catalyst 540 comprising the first and second SCR catalyst zones, an optional additional SCR catalyst 550, and an optional ASC 560.
FIG. 11A shows an exhaust gas treatment system comprising a passive NOx absorber (PNA) 610 upstream of a wall-flow filter 620 containing the first SCR catalyst zone, which is preferably coated from the outlet side of the filter. The PNA may contain an alkali and/or alkaline earth metals such as barium, strontium, potassium and a metal oxide such as BaO, TiO2, ZrO2, CeO2, and Al2O3. Preferably, the PNA contains one or more of a PGM, such as rhodium, palladium, platinum, or a combination of metals such as palladium and platinum; a zeolite, including those having small pore frameworks or large pore frameworks, with specific examples being CHA, AEI, AFX, BEA, MOR, FER, LEV, and ERI; metal oxide such as barium oxide cerium oxide, or a mixed metal oxide containing cerium or barium; and transition metal. Preferably, the PGM or transition metal is supported by the metal oxide or the zeolite. In certain embodiments, the PNA includes a PGM such as Pd supported on a small pore zeolite and a metal such as Fe supported on a zeolite, such as FER. Suitable PGM loadings can be, for example, 1-120 g/ft3. The individual components of the PNA may be layered or combined into a single washcoat.
The system shown in FIG. 11A further comprises a flow through substrate containing the second SCR catalyst zone which is positioned downstream of the filter. The system preferably includes an ammonia slip catalyst as a separate brick downstream of the flow through substrate or on the rear of the flow through substrate, similar to the arrangement shown in FIG. 6A. The system may optionally include a source of SCR reductant 620, such as an injector for introducing ammonia or an ammonia precursor into the system.
The wall-flow filter in FIG. 11A is preferably proximal to the flow-through substrate, but the distance between the two is not particularly limited. Preferably, there are no intervening catalysts or filters between units 630 and 640 or between 610 and 630. Preferably, there are no intervening catalysts between the second SCR catalyst zone and the ASC. Preferably, there are no intervening exhaust gas treatment catalysts between the engine and the PNA or downstream of the second SCR catalyst zone or ASC.
Another configuration is shown in FIG. 11B wherein the PNA and first SCR catalyst zone are coated on a wall-flow filter 635. Here, the PNA is coated from the inlet side of the filter as a washcoat on the wall surface and/or partially permeating the wall and the first SCR catalyst zone is coated from outlet side of the filter as a washcoat on the wall surface and/or partially permeating the wall. The system further comprises a flow through substrate containing the second SCR catalyst zone which is positioned downstream of the filter. The system preferably includes an ammonia slip catalyst on a separate substrate downstream of the first and second SCR catalyst zones or on the rear of the flow through substrate containing the second SCR catalyst zone, similar to the arrangement shown in FIG. 6A. A first reductant supply (e.g., an injector) is positioned upstream of the filter and supplies reductant to the system under conditions that would not lead to oxidation of the reductant by the PNA (e.g., at temperatures less than 400° C.). An optional second reductant supply (e.g., an injector) is positioned between the first SCR catalyst zone and the second SCR catalyst zone and operates either independently of, or in conjunction with the first reductant supply.
The wall-flow filter in FIG. 11B is preferably proximal to the flow-through substrate, but the distance between the two is not particularly limited. Preferably, there are no intervening catalysts or filters between units 635 and 640. Preferably, there are no intervening catalysts between the second SCR catalyst zone and the ASC. Preferably, there are no intervening exhaust gas treatment catalysts between the engine and the PNA or downstream of the second SCR catalyst zone or ASC.
The method for treating exhaust gas as described herein can be performed on an exhaust gas derived from a combustion process, such as from an internal combustion engine (whether mobile or stationary), a gas turbine and coal or oil fired power plants. The method may also be used to treat gas from industrial processes such as refining, from refinery heaters and boilers, furnaces, the chemical processing industry, coke ovens, municipal waste plants and incinerators, etc. In a particular embodiment the method is used for treating exhaust gas from a vehicular lean burn internal combustion engine, such as a diesel engine, a lean-burn gasoline engine or an engine powered by liquid petroleum gas or natural gas.

## Claims

1. A system for treating an exhaust gas comprising:
a. a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3; and
b. a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system.

2. The system of claim 1 wherein the first SCR catalyst zone has a higher washcoat loading relative to the second SCR catalyst zone and the overall copper loading is higher than the overall vanadium loading.

3. The system of claim 1, wherein the first SCR catalyst zone comprises about 0.5-4 weight percent vanadium (based on the total weight of the metal oxide) and the second SCR catalyst zone comprises about 1-4 weight percent copper (based on the total weight of the molecular sieve).

4. The system of claim 1 wherein the second SCR catalyst zone is free of iron.

5. The system of claim 1, wherein the second SCR catalyst zone is free of transition metals other than copper.

6. The system of claim 1, wherein the first and second SCR catalyst zones are free of platinum group metals.

7. The system of claim 1, wherein the first SCR catalyst zone comprises an iron vanadate.

8. The system of claim 7, wherein the first SCR catalyst zone further comprises tungsten.

9. The system of claim 1, wherein the system is free of any exhaust gas treatment catalysts disposed between the first and second SCR catalyst zones.

10. The system of claim 1, wherein the second SCR catalyst zone comprises a copper loaded molecular sieve having a framework selected from CHA, AEI, AFX and AFT.

11. The system of claim 1, wherein the first and second SCR catalyst zones are coated on a flow-through honeycomb substrate having an inlet end, an outlet end, and an axial length measured from the inlet end to the outlet end, and the first and second SCR catalyst zones are adjacent or at least partially overlapping.

12. The system of claim 11, wherein first zone extends from the inlet end to a first end point that is position about 10 to 40 percent of the axial length and wherein the second zone is about 20 to 90 percent of the axial length, provided that the first and second zones are adjacent or overlap by less than 90 percent of the axial length.

13. The system of claim 11, further comprising an oxidation catalyst zone downstream of the second SCR catalyst zone.

14. The system of claim 13, wherein the second SCR catalyst zone completely overlaps the oxidation catalyst zone.

15. The system of claim 1, wherein the first SCR catalyst zone is an extruded vanadium catalyst honeycomb having an axial length and the second SCR zone is a washcoat that covers about 10 to 90 percent of the axial length.

16. The system of claim 15, wherein the second SCR zone washcoat that covers about 60 to 90 percent of the axial length of the honeycomb.

17. The system of claim 1, wherein the first SCR catalyst zone is on a wall-flow filter having an inlet side and an outlet side, and the second SCR catalyst zone is on a flow-through honeycomb substrate, provided that there are no intervening catalyst between the first SCR catalyst zone and the second SCR catalyst zone.

18. The system of claim 17, further comprising a partial NOx absorber disposed upstream of the first SCR catalyst zone.

19. The system of claim 17, further comprising an ammonia slip catalyst coated on the flow-through substrate downstream of the second SCR catalyst zone.

20. A method for treating an exhaust gas comprising the step of contacting, in series, a mixture of ammonia and exhaust gas derived from an internal combustion engine with (a) a first SCR zone comprising vanadium loaded on a metal oxide selected from TiO2, ZrO2, SiO2, CeO2, and Al2O3, and (b) a second SCR zone comprising a copper-loaded small pore molecular sieve.