P.O. BOX 450499 

HOUSTON, TEXAS 77245-0499 

August 6, 2003 

U.S. EPA 

Office of Pollution Prevention and Toxics 

Document Control Office (7407M) 

1200 Pennsylvania Ave., N.W. 

Washington, D.C. 20460 

Subject: PMN TS-C02666 Sanitized Copy 

To Whom It May Concern: 

~-D3-8&6 Telephone (281) 431-2561 

Fax (281) 431-1655 

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(I) 

fT1 O;o -o \J I'Tl N -D("") 

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Enclosed is a sanitized copy of PMN TS-C02666 with confidential information deleted. 

Sincerely, 

Mel Davis 

Manager of Regulatory Affairs 

MD/Ir 

cc: File PMN TS-C02666 

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MD03-13 

, 
Form oved O.M.B. No. 2070..()012. A ires 10-31-96. 

U.S. ENVIRONMENTAL PROTECTION AGENCY AGENCY USE ONLY 

ft 

·~~PA PREMANUFACTURE 

NOTICE 

IIIIIIIJilli Iiiii IIIII illii III:IIH IH IH IJ I~J f, ,: 1.1 ·ill 

.) 1 0 -5 I) t"j {, () ,• ') ·, 

lU.ta Ul..., l.Vt.ul .u ..... u .• ._.-,.,._ ,...._ r-0 -

in the Premanufacture Notice 

Date of receipt RfCEIVFrJ 

03 SEP 2 9 AM 6: r ·J 

'S 

• You must provide all information requested in this form to the extent that it is known to or reasonably ascertainable by you. Make reasonable estimates if you do 

not have actual data. 

• Before you complete this form, you should read the "Instructions Manual for Premanufacture Notification" (the Instructions Manual is available from the Toxic 

Substances Control Act (TSCA) Information Service by calling 202-554-1404, or faxing 202-554-5603 ). 

If a user fee has been remitted for this notice (40 CFR 700.45), indicate in the boxes above the TS-user fee identification number you have generated. Remember, 

your user fee ID number must also appear on your corresponding fee remittance, which is sent to EPA, HQ Accounting Operations Branch (PM-226), P.O. 

360399M, Pittsburgh, PA 15251-6399, Attn. TSCA User fee. 

Part I-GENERAL INFORMATION 

You must provide the currently correct Chemical Abstracts (CA) N arne of the new 

chemical substance, even if you claim the identity as confidentiaL Y au may authorize 

another person to submit chemical identity information for you, but your submission will 

not be complete and the review will not begin until EPA receives this information. A 

letter in support of your submission should reference your TS user fee identification 

number. Y au must submit an original and two copies of this notice including all test data. 

If you claimed any information as confidential, a single sanitized copy must also be 

submitted. 

Part II-HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE 

If there are several manufacture, processing, or use operations to be described in Part ll, 

sections A and B of this notice, reproduce the sections as needed. 

Part HI --LIST OF ATTACHMENTS 

Attach additional sheets if there is not enough space to answer a question fully. Label 

each continuation sheet with the corresponding section heading. In Part 111, list these 

attachments, any test data or other data and any optional information included m the 

notice. 

OPTIONAL INFORMATION 

You may include any mforrnabon that you want EPA to consider in evaluating the new 

substance. On page 11 of this form, space has been provided for you to described 

pollution prevention and recycling information you may have regarding the new 

substance. 

So-called "binding" boxes are mcluded throughout this form for you to indicate your 

willingness to be bound to certain statements you make in this section, such a.' use, 

production volume, protective equipment This option IS intended to reduce delays 

that routinely accompany the development of consent orders or Significant New Use 

Rules. Except in the case of exemption applications (such as TMEA, L VE, LOREX) 

where certain information provided in such notification is binding on the submitter when 

the Agency approves the exemption application, checking a binding box in this notice 

does not by itself prohibit the submitter from later deviating from the information (except 

chemical identity) reported in tbe form 

CONFIDENTIALITY CLAIMS 

You may claim any information in this notice as confidential. To assert a claim on the 

form, mark (X) the confidential box next to the information that you claim as 

confidential. To assert a claim in an attachment, circle or bracket the information you 

claim as confidential. 1f you claim information in the notic!;S as confidential you must 

also provide a sanitize.\iyersion of the notice (including attachments) For additional 

instructions on claiming information as confidential, read the Instructions Manual 

D Mark (x) if any information in this notice 1s claimed as confidential. 

EPA FORM 7710-25 (Rev. 5-95) 

I 

TEST DATA AND OTHER DATA 

You are required to submit all test data in your possession or control and to provide 

a description of all other data known to or reasonably ascertainable by you, if these 

data are related to the health and environmental effects on the manufacture, 

processing, distribution in commerce, use, or disposal of the new chemical 

substance. Standard literalw'e citatiom may be submitted for data in the open 

scientific literalw'e. Complete test data (written in English), not summaries of data, 

must be submitted if they do not appear in the open literature. You should clearly 

identify whether test data is on the substance or on an analog. Also, the chemical 

composition of the tested material should be characterized. Fallowing are 

examples of test data and other data. Data should be submitted according to the 

requirements of §720.50 of the Premanufacture Notification Rule (40 CFR Part 

720). 

Test Data (Check Below any mcluded in this notice) 

Environmental fate data 0 

Health effects data 0 

Environmental effects data 0 

Phvsical/Chemical Properties* I&! 

Yes 

Yes 

Yes 

Yes 

Other data I&! Yes 

Risk assessments 

Structure/activity relationships 

Test data not in the possessiOn 

or control ofthe submitter 

• A physical and cherrucal properties worksheet is located on the last page of this form . 

TYPE OF NOTICE (Check Only One) 

l?3l 

D 

D 

D 

D 

D 

PMN (Premanufacture Notice) 

INTERMEDIATE PMN (subrrutted in sequence with ~roduct PMN) 

E.: 

SNUN (S1gruficant New Use Notice) 

TMEA (Test Marketing Exemption Application) 

0 ('J 

-t 

LVE (Low Volume Exemption)@ 40 CFR 723.50(c1!,J 

2:..::·r·r·J 

LOREX (Low Release/Low Exposure Exemption)~ CFlf71f5«cX2) 

D L VE Modification D 

D 

(_fl 

LOREX 1(!0lification 

IS TillS A CONSOLIDATED PMN? Yes 

# of chemicals 

(Prenotice Communication# required, enter# on page 3) 

Replaces previous editions of EPA Form 7710-25. 
Public reporting burden for this collection of infonnation is estimated to average 110 hours per response, including time for reviewing 

instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of 

infonnation. Send comments regarding the burden estimate or any other aspect of this collection of infonnation, including suggestions for 

. reducing this burden, to Chief, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 401 M. St., S.W., Washington, D.C. 

20460; and to the Office of Management and Budget, Paperwork Reduction Act (2070-0012), Washington, D.C. 20503. 

CERTIFICATION 

I certify that to the best of my knowledge and belief: 

1. The company named in Part I, section A, subsection Ia of this notice form intends to manufacture or import for a 

commercial purpose, other than in small quantities solely for research and development, the substance identified in Part I, 

Section B. 

2. All information provided in this notice is complete and truthful as ofthe date of submission. 

3. I am submitting with this notice all test data in my possession or control and a description of all other data known to or 

reasonably ascertainable by me as required by §720.50 of the Premanufacture Notification Rnle. 

Additional Certification Statements: 

If you are submitting a PMN, Intennediate PMN, Consolidated PMN, or SNUN, check the following user fee certification 

statement that applies: 

t8J The Company named in Part I, Section A has remitted the fee of$2500 specified in 40 CFR 700.45(b), or 

D The Company named in Part I, Section A has remitted the fee of $1000 for an Intennediate PMN (defined @ 40 CFR 

700.43) in accordance with 40 CFR 700.45(b), or 

0 The Company named in Part I Section A is a small business concern under 40 CFR 700.43 and has remitted a fee of $100 

in accordance with 40 CFR 700.45(b). 

If you are submitting a low volume exemption (LVE) application in accordance with 40 CFR 723.50(c)(l) or a Low release 

and low exposure exemption (LoRex) application in accordance with 40 CFR 723.50(c)(2), check the following certification 

statements: 

0 The manufacturer submitting this notice intends to manufacture or import the new chemical substance for commercial 

purposes, other than in small quantities solely for research and development, under the tenns of 40 CFR 723.50. 

0 The manufacturer is familiar with the terms of this section and will comply with those terms; and 

0 The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

0 If this application is for an LVE in accordance with 40 CFR 723.50(c)(1), the manufacturer intends to commence 

manufacture of the exempted substance for commercial purposes within 1 year of the date of the expiration of the 30 day 

review period. 

The accancy of the statements yot~ maloe In this notice mould reflect your best predktioa of the anticipated facts rqpording the chemical substance 

described herein. Any knowing and willful misinterpretation is subject to criminal penalty JNinuant to 18 USC 1001. 

signa~:/~;T::Z:alsignatureRequired) t- So_ :;Lo cJ.3 

Virgil Seail, oir'ector of Research & Development 

Signature of agent - (if applicable) Date 

EPA FORM 7710-25 (Rev. 5-95) Page2 

Conrldential 
la. Person 

Submitting 

Notice (in U.S.) 

b. Agent(if 

applicable} 

Vi Seale 

Company 

P .0. Box 450499 

City, State, ZIP Code 

Houston Texas 77245-0499 

Name of authorized 

Company 

Mailing address (number and street) 

City, State, ZIP Code Telephone 

c. If you are submitting this notice as part of a joint submission, mark (X) this box. -----------------------+ 

Joint Submitter (if 

applicable} 

Name of authorized official 

Company 

Mailing address (number and street) 

, State, ZIP Code 

2. Technical 

Contact(in 

U.S.) 

Name of authorized official 

3. 

4 

5. 

6. 

Inc. 

Houston, Texas 77245-0499 

a prenotice communication (PC) concerning this notice 

and EPA assigned a PC Number to the notice, enter the number. 

If you previously an exemptton for the 

substance covered by this notice, enter the exemption number assigned by 

EPA. If you previously submitted a PMN for this substance enter the 

PMN number assigned by EPA (i.e. withdrawn or incomplek:}. ., 

a notice of Bona fide mtent to manufacture or import 

fOr the chemical substance covered by this notice, enter the notice number 

assigned by EPA 

1. 

Type of Notice - Mark (X) 

Manufacture 

Only 

Binding Option 

Mark 

EPA FORM 7710-25 (Rev. 5-95) 

Position 

Telephone 

Position 

Mark(X) 

if none 

Mark(X) 

if none 

52 98 00 00068 Mark(X) 

if none 

2. 

D 

Page3 

Import 

Only 

Binding Option 

Mark 

431-2561 

D 

3. D Both 

Confidential 
l. 

a. Class of substance - Mark (X) 

name correct 

For Class I substances a CA Index Name must be provided. For Class 2 substances either a CA Index Name orCA Preferred Name must X 

be provided, which ever is appropriate based on CA 9CI nomenclature rules and conventions). 

REDACTED 

c. Please identifY which method you used to develop or obtain the specified 

~ Method I (CAS Inventory Expert Service -a copy of the Identification 

report obtained from the CAS Inventory Expert Services must be 

submitted as an attachment to this 

CAS# 

REDACTED 

e. For a class 1 substance, provide a complete and correct chemical structure diagram. For a class 2 substance- (I) List 

precursor substances with their respective CAS Registry Numbers. (2) Describe the nature of the reaction or process. (3) Indicate the 

range of composition and the typical composition (where appropriate). ( 4) Provide a correct representative or partial chemical structure 

diai!Tam. as comnlete as can he known. if one can he reasonahlv ascertained. 

1. CADMA [68140-01-2] 

Acrylic Acid [79-10-7] 

Butyl Cellosove [111-76-2] 

Water [7732-18-5] 

2. Michael reaction 

4. Structure (REDACTED) 

Mark (X) this box attach a continuation sheet. 

EPA FORM 7710-25 (Rev. 5-95) Page4 

X 

X 
a. Indicate the number-average weight of the lowest molecular weight composition of the polymer you intend to manufacture. 

'Indicate maximum weight percent oflow molecular weight species (not including residual monomers, reactants, or solvents) below 500 and 

below 1,000 absolute molecular weight of that composition. 

Describe the methods of measurement or the basis for your estimates: GPC 0 

i) lowest number average molecular weight: 

ii) maximum weight %below 500 molecular weight: 

iii) maximum weight% below 1000 molecular weight: 

Other 0 (Specify) 

Confidential 

must make separate confidentiality claims for monomer or other reactant identity, composition information, and residual 

"Confidential" box next to any item you claim as confidential 

Mark(X)the 

(I) - Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used in the manufacture of 

(2) -

(3) -

(4) -

(5) -

(6) -

the polymer. 

Mark (X) this column if entry in column (I) is confidential. 

Indicate the typical weight percent of each monomer or other reactant in the polymer. 

Mark (X) the identity column if you want a monomer or other reactant used at two weight percent or less to be listed as part of the polymer 

description on the TSCA Chemical Substance Inventory. 

Mark (X) this column if entries in columns (3) and ( 4) are confidential. 

Indicate the maximum weight percent of each monomer or other reactant that may be present as a residual in the polymer as manufactured for 

commercial purposes. 

Mark this column if in column is confidential. 

Confi- Typical 

% 

method you used to develop or obtain the specified chemical identity information reported in this notice (check one). 

(CAS Inventory Expert Service- a copy of the identification report 0 Method 2 (other source) 

obtained from CAS Inventory Expert Service must be submitted as 

as tothis 

Confi-

% 

% 

% 

% 

EPA FORM 7710-25 (Rev. 5-95) Page 5 
3. Impurities 

(a) - Identify each impurity that may be reasonably anticipated to be present in the chemical substance as manufactured for commercial purpose. Provide the 

CAS Registry Number if available. If there are unidentified impurities, enter •'unidentified." 

Estimate the · · %of each If there are unidentified · estimate their total wei o/o. 

REDACTED 

REDACTED 

REDACTED 

WATER [7732-18-5] 

REDACTED 

N-acrylic betaine, Propyl cocoamidopropyl betaine 

0 Mark (X) this box if you attach a continuation sheet. 

5. Trade identification- List trade names substance identified in subsection 1 or 2. 

0 Mark (X) this box if you attach a continuation sheet. 

Maximum 

percent 

4 "' 

1% 

49.5% 

40% 

2% 

% 

% 

6. Generic chemical name- If you claim 1dentif)' as confidential, you must provide a generic name for your substance that reveals 

the specific chemical identity of the new chemical substance to the maximum extent possible. Refer to the 

TSCA Chemical Substance Inventory, 1985 Edition, Appendix B for guidance on developing generic names. 

N-acrylic betaine 

attach a continuation sheet. 

Confidential 

X 

X 

X 

Confidential 

Describe any byproducts resulting from the manufacture, processing, use, or disposal of the new chemical substance. Provide the CAS Registry 

Number if available. 

alkyl groups based on coconut oil; n = 8, 12, 14, 16 (refer to generic 

betaine based on polymers of acrylic acid; x ~ 2 

EPA FORM 7710-25 (Rev. 5-95) Page6 

CAS Number Confidential 
SEP.29.2003 1:02PM CHAMPION FRESNO N0.847 P.2/3--

Mm-k (X) the ~confidential" bo.x next to any item you claim as confidCDtial. 

1. Production volume- Estimlllc the muim.um ptoduction volume dllring 1he fust 12 months ofp-oduetion. Also estimate the maximum 

production volume for nny consecutiv~ 12-month period during the fJISt three years ofprodpction. Estiinatcs sbould be on 100% new chemical 

substance basis. For a Low Volume Exemption application, if you choose to have your notice reviewed at a lower production volume 1l:um 

10,000 k!t/yr, specifv the voltm~e and mark.(x) in the binding box. rf ~ vou are bound to this volume 

Ma"l:imum fiiSt 12-month production (kg/yr) Maximum 12-mouth production (kglyr) ~- !3irlding 

(100% new chemical substmoe basis) (10()41.4 new chemical substance Qasis) dcotia1 Option 

M:lfk (X) 

REDACTED REDACTED X 

2. Use Info~on- You must JDDkc separate confidentiality claims for the de:scriplian ofthc category of usc,~ percent of production volume 

devoted to each category, lhc fOimulation of the new subsrance, and other usc infOrmation. Mark (X) the "'COIIlfufenti.al" Box uext to any item 

you claim as confidential. 

a. (I)- Describe each intended c:rtegocy of use of the new chcmic:ll sub&anl;c by function and appliconion .. 

(2)- Mark (X) this oolumn if entry colUmn ( l) is confJde:ntial business information ( CBl). 

(3)- Indicate your willingness to haVe the infolltllltion provided in column ( 1) binding. 

(4)- Estimate the pcrcc:nt of total production for the fizst three years devoted to esdl category of use. 

(5)- Mark (X) this column if entry in column ( 4) is confidential business information (CBl). 

(6)- Estimate the pcrccr~t of the new substance as fonnulated in mixtures, suspensions, emulsions, solqtions., or gels as manufactw'ed for 

commercial purposes at sires tmder your control :!SSocillltd with each category of use. 

(7)- Mark (X) this column if entry iD column ( 6} is confide:otial business information (CBI). 

(8)- Jndicate % of product volume ell.'})eCted for the tisted ''usc., sectors. Mmk more than one bo."( if :!Wfopriatc. Mark (X) to indicate 

your willingness to ba.ve the use type provided in (8) binding. 

(9)- Mark (X) this column if entry(ies) in column (8) is (are) confadential business information (CBI). 

Co.tegory or use (1) em Dlndin£ Produc- CHl ~'ill CBI ~o of liUbSIIUICC cxpocted per usc cur 

Oplio'l lion% FOI"'Il- (8). 

(by firlll%ion al1d Dpp1ic41ioa i.e. :a c!ispcrsi~ dye Nallc (;;) 11laliua Site- Co~~o• lodam- Com- Bindins 

for fmisbing J)Olyestc:r Jibcr,j_ (2) (l) (4) (S) {6) (7) limited snmcr trial mcrci:ll Option (9) 

Redacted X X 100% Redact X 90 10 

eel 

~~ e;.. 

_%_ ~ 

~ .. ~ 

I 

_% 0,' 

~ "' ~~ o/. 

• lC you~-& idmti6cd ~ "cocsumcr" asc, pl~e provide oo a cootiiiWI.tioo sbccu dcbilcd dcacription oflhe 11Se(s) of this ~icsl su~ in consumer products. 

I:uddition inchlde c:szimaEOS of the COIICimtrliZioa ofthc new cbGmicul !llbstaoco as e~:pecroo in COJ:lSIIDia"pracluctsancldcsaibcthc cbcnliOIIl reactions by whit:h this 

substance l01>cs i~ idenlity in the ~a produrt 

OM:Irk (X) this bo:r.:ifyou m:ach a c.:uatimwioa sheet. 

b. Generic If you cbitn any category of use description in sub!lldion 2a ~ confidential, ¢Gicr a gCDCric dcscriplioo of th3l estcgory. Ri!ll.d Pic 

use Jnslrudiapa ~uallbr c:GIIlples or~~c 1154 dcsaipliOIII. 

description Product can be used as a non-corrosive foamer in the Oil and gas ind1..1stry. Non-corrosive can be 

defined by the lack of reaction of the product with specific metallurgies used to transport the produd. 

However. use is not rrmited to the metallutgies commonly associated witJ1 the gas and oil industry. 

0 Mak (:\)this box if youllU:Icl\ ~ coatinuatioo shoet. 

3. ~ lnro~U~~tten •• lndudc in tho notice a copy of reasooablc lacsimilo of any lmzard ~ sUttc:mcnt, label, IDlllc:Ml sqfety cmta sbcet, or olhc:r llill<ling 

Ud'orma.tioa wbida will be ~to aay pc:r501t a•!Jo is n:asooably l.i.kdy to be C'--po$Cd to this .subsWic:o ~ pr"O!Celtive cquipmc:nc <lr pn&C(jc:c:s Op!ign 

fortbc s:tf'o bmdius, 1J':l11Spol'l. u:sc, or disposal ofthc IICWsubstomc:c. List in pat! 01 baz:lrd information you iw:Nd.e. !.f.uk(l<) 

~ MarJe (X) this box if you .11Qeh h42.1rd iofoma.1tioo. X 

Part D- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE 

Sect;on A INDUSTRIAL SITES CONTROLLED B'\' THE SUBMITTER Mark (X) tho "CO!!Ifidc:nti:ll'' bas nen to :any item you 

claim ~ confide-ntial 

li.PA FORM 7710-25 (Rov. 5·95) hsc7 
Complete section A type of processing, or use operation involving the new chemical substance at industrial sites you 

control. hnporters do not have to complete this section tor operations outside the U.S.; however, you may still have reporting requirements if 

there are further industrial or use after You must describe these See instructions manual 

of the site at which the will occur. 

Name 

Champion Technologies, Inc. 

street) 

3130 FM 521 

County, State, ZIP code 

Fresno (Fort Bend county}, Texas 77545 

same operation will occur at more than one site, enter the number of sites. Identity the 

additional sites on a continuation sheet, and if any of the sites have significantly different 

production rates or operations, include all the information requested in this section for those 

sites as attaclnnents. 

1. Batch 

2. Continuous 

13,000 

Maximum kglbatch (l OO"Io new chemical Hours/batch 

substance) 

12 

d. Process description Mark (X) to indicate your willingness to have your process description binding. 

Batches/year 

150 

Batches/year 

Confidential 

( 1) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specifY- e.g. 5 gallon pails, 55 gallon 

dnun, rail car, tank truck, etc.). 

(2) Provide the identity . the approximate weight (by kg! day or kg/batch on a l 00% new chemical substance basis), and entry point of all starting materials and 

feedstocks (including reactants, solvents, catalysts, etc.). and of all products, recycle streams, and wastes. Include cleaning chemicals (note frequency if not 

used daily or per batch.). 

(3) Identify by number the points of release. including small or intermittent releases, to the environment of the new chemical substance. 

EPA FORM 7710-25 (Rev. 5-95) Page 8 
PART II- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE- 1(d)- contin

CADMA 

ACRYLIC ACID 

BUTYL CELLOSOL VE 

H20 

CODE 2666 

20%-40% ... 

5.15-10.3% ... DRUMS 

35%-49.7% ... REACTOR I ... BULK CONTAINERS IIJo USE IN GA

39.85%-0% ... TANKER TRUCKS 

S(a) 
' 

PART II- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE- 1(d) -continuation 

--

«S 

l 

.! 

c 

Gas Out--...., 

se\lara\Of 

· Below Grade · 

'0 

••• 

' 0 

0. 0 

. 

.... 

' 

'' 

-

-

-

<:) 

• 

0 • 

• 0 

Q'' •• 

Drum, truck or 

bulk container 

Chemical 

reservoir 

'· 
2. Occupational Exposure-- You must make separate confidentiality claims for the description of worker activity, physical form of the new chemical substance, 

number of works exposed, and duration of activity. Mark (X) the "Confidential" box next to any item you claim as confidential. 

(1) --Describe the activities (i.e. bag dumping, tote filling, unloading drums, sampling, cleaning, etc.) in which workers may be exposed to the substance. 

(2) --Mark (X) this column if entry in column ( l) is confidential business information (CBI). 

(3) --Describe any protective equipment and engineering controls used to protect workers. 

(4) and (6) --Indicate your willingness to have the information provided in column (3) or (5) binding. 

(5) -~Indicate the physical form(s) of the new chemical substance (e.g., solid: crystal, granule. powder. or dust) and% new chemical substance (if part of a mixture) 

at the time of exposure. 

(7) --Mark (X) this column if entry in column (5) is confidential business information (CBI). 

(8) --Estimate the maximum number of workers involved in each activity for all sites combined. 

(9) -- Mark (X) this column if entry in column (8) is confidential business information ( CBI). 

(1 0) and (II)-- Estimate the maximum duration ofthe activity for any worker in hours per day and days per year. 

(12) -- Mark (X) this column if entries in columns (l 0) and (II) are confidential business information (CBI). 

Worker activity CBI Protective Equipment! Bindmg Physical form•(s) Bindmg CBI #of CB! Maxirnu duration CBI 

m 

(i.e., bag dumping, filling drums) Engineering Controls Option and %new Option Workers Hrslday Dayslyr 

Mark (x) substance Mark (x) Exposed 

(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (II) (12) 

Manufacture Goggles and Liquid 2 3 2 

a loves 

Transfer to holding Goggles and Liquid 2 3 2 

facilities a loves 

0 Mark (X) this box if you attach a continuation sheet. 

3. Environmental Release and Disposal -- You must make separate confidentiality claims for the release number and the amount of the new chemical substance 

released and other release and disposal information. Mark (X) the "Cortfidential" box next to each item you claim as confidential. 

(I)-- Enter the number of each release point identified in the process description. part II, section A subsection ld(3). 

(2) -- Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch). 

(3) --Mark (X) this column if entries in columns (I) and (2) are cortfidential business information (CBI). 

( 4) --Identify the media (stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration, POTW. or other (specify)) to 

which the new substance will be released from that release point. 

(5) --a. Describe control technology, if any, and control efficiency that will be used to limit the release of the new substance to the environment. For releases 

disposed of on land, characterize the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a continuation sheet, for 

each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or tertiary on-site treatment. b. Estimate 

the amount released to the environment after control technology (in kg/day). 

(6) --Mark (X) this column if entries in columns ( 4) and (5) are confidential business information (CBI). 

(7) --Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct discharges or 

NPDES numbers of the POTW (Publici Owned Treatment Works). Mark (X) if the POTW name or NPDES #is confidential business information (CBI). 

Release Amount of new substance CBI Media of Control technology and efficiency (you may wish to optionally attach efficiency data) CBl 

Number released release 

(1) (2a) (2b) e..g. stack air Bindmg 

(3) (4) (Sa) Mark (X) (5b) (6) 

1 0 N/A Load reactor with reactants Pipes & pumps 

from tanks to 

reactor 

2 0 N/A React to produce product - vent gases to Scrubber 

scrubber. 

3 0 N/A Product loadout to storage facilities Scales/drumming 

equipment 

(7) Mark (X) the 0 POTW provide name(s) below: CBI 0 Navigable 0 Other- SpecifY provide NPDES # CBI 

destination(s) of f-- waterway 

releases to water. 

] Mark (X) this box if you attach a continuation sheet. 

EPA FORM 7710-25 (Rev. 5-95) Page9 

JJ 
SEP.29.2003 1:03PM CHAMPION FRESNO 

N0.847 -P.3/3 ___ ·-· 

Part D- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE- Continued 

Section B -INDUSTRIAL SITES CONTROU.ED BY OTHERS 

Compldc ~ lllOr typical proccssing ar 11$0 OpcralioaS involving 1ho llOW dlcmicall~Ub:~t~Aco II site& you do DOt conll'ol. 1mpol1cts dG Dot have tO c:orvpJete this 

9cction tor opcAlions outside the U.S.; howover, yw must report any proc:CPiot or usc activities afia- import. Sec lho l:mtmctiloos MmuaL Complete a separore ~pn B for each lype ofproccszing, or u:tc operQlfon invol~ rhc new cl1emical rubnoncc. fftho same opcr:llioa ill pen~ aL more thaD one 4il0 describe the 

typical opl!l':\tion CCINDOII to thcso sites. ldcmif v additional sites 011 a canlinwdiM sheet. 

1. Openlioq Desaiptian- To clsiDl information .ill this soc:tioll a:r confideolilll, cin:lo 01 bnlc:J.:or tbe specific inJ.~tion Wit you claim ss confJdcntinl. 

(1)-· DiAgnun tbc nnjorunit opcrmon steps and chcmiQJ conversions, illcludiJie ilurim m:ocageiiDd=aspon cOill:liD«s 1:spcc:ifjr- e.g. 5 gallon pails, 55 ~on 

drt!lll$, mil c:.us, tank ttucks, etc). On the cliat;r.un. ideutify by ffner a!ld bridly dcscribo cacb workllr :ldivity. (2)- PrOYi(fo !he idcutity. ~ nppro~ weight 

(by Jc&'cl.'Y or Jc&'b.Ucb, on :m l ~• n::w cbemiCIIlBUbs=lee basis). :md Clllry poilll of all f~oc:k& (including~ St~ .lOd c:atalysts, cr.c:) and .111 

products, reeycl~: 111raams, 1111d W3.StOS. lnclu4o clemins c:bemicala (note ftcqucacy it' DOt 1111cd daily or per ~cb). (3) •• Id~ by numb« tho poiD.ts ofrcliJUo, 

including small or intc:nnittcnt rclc:uc:s, 10 tbe cavironment of the aew cbanic::al substance. ( 4) Plc:uc CJUr the #of siles (rr.mcmbcr 10 identify the locatiaos of 

those sites on a ooatiDU.\tion sbcet): 

0 Mart (:X) this ~" ifyou ataclt a coatimwiOB shed. 

2. Worm Expoll'llt'~ Re1ea.-.e 

(I) -From tbo dillgJum 3boVe, provide the Idler for eae4 worka- activity. Compldc U for aadt \wricer aeli\lity described. 

(2) ·-Estimate tho~ ofworken Qt)losod for all ws combined. 

>100 

fl of sites 

(4)-Estimal.e the typiCl\1 dwation of O..'qiOSUI"C: par wod:cr in (a) hour& per cby :md (b) days per yov. 

(6) - Doscribe physical funn of o:~:posurc ADd% new chemical Stlbcncc (if in mi).1urc), ~ my prvtc:ctive equi.pDICIIt 3nd CllgineeriJis co111rols, if ;my, used to 

protect wQrkers. 

(7)- Estimate ~he paTCCU oftbo now sub~ 3S f'omml;lrcd wbca pWilgal or used'" :r f~ produd. 

(9)-From the p!'OC\.'SS di.1gtam. :tbovo, ealc..T the niUDbtr of C3Ch rclcuc poinz. Complete 9-13 for each rclcaso point identified. 

(10) - Estinuto the .:uoountofthcnow subslaaccrclc:ascd(3)~tothc mvironmem or (b) U.o COiltroi1AlabDoJogy10thcowirownent (~kg/day orJcWb=h). 

(12) •• Desc:ribc ~ ofrclwe i.o.lil.l¥:k ~.fugitive ait(optior141...sec lmtnsctioas Manual).~ tater, on-.dc or off-sl~ bod or in<:itlerAtioa, POTW, or other 

(spDCify) and control technology, ifaay, "Wl will be used to limit~ n::Jc:aso oftbc new sublllallcc 10 the cnviroruncnl. 

I .cncr # ot Cl:H Duntion CB! Protective F. quip. I o/o in CUJ Rcl~...c AmoliiDt of 

c! Workctl> of f.ntineerins Con&rolsl Fonn- Number Ne>or 

AC'!- B:qt~ f~-posurc Physical Fcmn =% W..JOn ~r.e ivity Rd--d IIOW~SI::IIlce _, 

(14) •· Identifybyproducls wbichmayrcsultbmtho~OD. 

. 0). (5), (8). (ll), (13) and (1 S} - Mark (X} this eoi"UD:I.n if:u"(Y oflbe proceedi11g entries arc confideatinl business informati011 (CBI). 

(I) (2) (3) (4a) (4b) (S) (6) (7) (&) (9) (lOs) (lOb) 

A 1-2 0.5 75 jGoggles and gloves Rectaclecl X 0 0 o 

14)- Byprod11cts: 

F.PA FORM 7710.25 (Rev. 5-9S) Pttgc 10 

t2. 

car Mcdi• of ltclc'~ 

& CODJ:rDI 

T L'duiology 

CBl 

(II) (1~ (13) 

Closed piping 

system, 

'njection well 

(lS) 
0 Mark (X) this box if you attach a continuation sheet. 

OPTIONAL POLLUTION PREVENTION INFORMATION 

To claim information in this section as confidential circle or bracket the specific information that you claim as confidential. 

In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce 

or minimize potential risks associated with activities surrounding manufacturing, processing, use and disposal 

of the PMN substance. Please include new information pertinent to pollution prevention, including source 

reduction, recycling activities and safer processes or products available due to the new chemical substance. 

Source reduction includes the reduction in the amount or toxicity of chemical wastes by technological 

modification, process and procedure modification, product reformulation, raw materials substitution, and/or 

inventory control. Recycling refers to the reclamation of useful chemical components from wastes that would 

otherwise be treated or released as air emissions or water discharges, or land disposal. Descriptions of pollution 

prevention, source reduction and recycling should emphasize potential risk reduction subsequent to compliance 

with existing regulatory requirements and can be either quantitative or qualitative. The EPA is interested in the 

information to assess overall net reductions in toxicity or environmental releases and exposures, not the shifting 

of risks to other environmental media or non-environmental areas (e.g., occupational or consumer exposure). In 

addition, information on the relative cost or performance characteristics of the PMN substance to potential 

alternatives may be provided. 

All information provided in this section will be taken into consideration during the review of this 

substance. See Instructions Manual and Pollution Prevention Guidance manual for guidance and 

examples. 

Describe the expected net benefits, such as (1) an overall reduction in risk to human health or the environment; (2) a reduction in the 

volume manufactured; (3) a reduction in the generation of waste materials through recycling, source reduction or other means; (4) a 

reduction in potential toxicity or human exposure and/or environmental release; (5) an increase in product performance, a decrease in 

the cost of production and/or improved operation efficiency of the new chemical substance in comparison to existing chemical 

substances used in similar application; or (6) the extent to which the new chemical substance may be a substitute for an existing 

substance that poses a greater overall risk to human health or the environment. 

All ingredients become part of the product. There are no by-products or discharges. All product is 

transferred to storage facilities immediately after manufacture. 

Product can be blended directly from storage facilities in designated blend facilities. There are no 

discharges from this process. 

Product or blended product is injected directly into producing gas and oil facilities. Treated fluids are 

not discharged. Separated water carrying product is re-injected in appropriate wells or treated to 

appropriate standards. 

EPA FORM 7710-25 (Rev. 5-95) Page II 
[ ] Mark (X) this box if you attach a continuation sheet. 

Part III-- LIST OF ATTACHMENTS 

Attach continuation sheets for sections of the form and test data and other data (including physical/chemical properties and 

structure/activity information), and optional information after this page. Clearly identify the attachment and the section of the form to 

which it relates, if appropriate. Number consecutively the pages of the attachments. In the column below, enter the inclusive page 

numbers of each attachment. 

Mark (X) the "Confidential" box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on 

how to claim any information in an attachment as confidential. You must include with the sanitized copy of the notice form a sanitized 

version of any attachment in which you claim intormation as confidential. 

Attachment name Attachment Contipage number( s) dential 

Material Safetv Data Sheet (MSDS) 

Attachment I Physical and chemical properties worksheet 14 

Attachment II Material Safety Data Sheet 15 

Attachment Ill REDACTED X 

Attachment IV REDACTED X 

Attachment V REDACTED X 

Attachment VI Log Pow report 21 

Attachment VII REDACTED X 

Attachment VIII REDACTED X 

Attachment IX Comparison of Toxicological Properties to other similar compounds 67 

EPA FORM 7710-25 (Rev. 5-95) Page 12 

Jt.l 
D Mark (X) this box if you attach a continuation sheet. Enter the attachment name and number. I I 

EPA FORM 7710-25 (Rev. 5-95) Page 13 
PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET 

To assist EPA's review of physical and chemical properties data, please complete the following wodsheet for data you provide and 

include it in the notice. Identify the property measured, the page of the notice on which the property appears, the value of the property, 

the units in which the property is measured (as necessary), and whether or not the property is claimed as confidential. The physical 

state of the neat substance should be provided. These measured properties should be for the neat (I 00% pure) chemical substance . 

. Properties that are measured for mixtures or formulations should be so noted(% PMN substance in~)- You are not required to 

submit this worksheet; however, EPA strongly recommends that you do so, as it wi II simplifY review and ensure that confidential 

information is properly protected. You should submit this worksheet as a supplement to your submission of test data This worksheet 

is not a substitute for submission oftest data. 

Property Mark Page Value jMeasured o Confidential 

(a) 

Physical state of neat substance 

Vapor pressure 

(j/J Temperature c 

Density/relative density @ 15.5 C 

Solubility 

@ Temperature 25 oc 

Solvent water 

Solubility in water @ Temperature oc 

Melting temperature 

Boiling I sublimation temperature@ torr pressure 

Spectra (REDACTED) 

Dissociation constant 

Particle size distribution 

Octanol I water partition coefficient (report attached) 

Henry's Law constant 

Volitalization from water 

Volitalization from soil 

pH@ concentration 100% 

Flammability 

Explodability 

Adsorption I coefficient 

Pour Point 

Viscosity, Brookfield @ 25 C 

(X) tf number 

provided (b) 

X 

X 13 

X 13 

X 

X 

X 13 

X 13 

/£. 

(c) 

(s) X (l) (g) 

Torr 

0.99 +/- 0.2 g!cm3 

Soluble in all proportions 

giL 

oc 

oc 

FTIR 

Log Pow= 0.4 

4.0-6.0 

Flash Point> 62.5 C 

< -23 c 

15 +/- 5 cps 

Estimate 

Mark(X) 

(MorE) (d) 

X 

ATTACHMENT 

PAGE 14 
A ""~~W\e~-\- " 

{>-..,..\ \ - (;•-A«t'•\ \t1 ~l,..w..-\-\OK- ~«:~~\0"'\ C - 3- CoWI~\'If'LichM MATERIAL SAFETY DATA SHEET 

VP8-37 

--------------------------------------------------------------------------~--

SECTION 1 - IDENTIFICATION IBM VP8-37 

-----------------------------------------------------------------------------

Champion Technologies, Inc. 

3130 FM 521 Fresno, TX 77545 

PO. BOX 450499 Houston, TX 77245 

EMERGENCY TELEPHONE NUMBERS 

1-281-431-2561 

1-800-424-9300 CHEMTREC 

1-703-527-3887 CHEMTREC -

Trade Name: VP8-37 International 

Chemical Family: BETAINES 

CAS No.: PROPRIETARY Current as of: 8/26/02 By: L. ORESCHNIGG 

-----------------------------------------------------------------------------

SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY 

----------------------------------------------------------------------~------

Hazardous Components 

2-BUTOXYETHANOL 

CAS No. 

111-76-2 

Wt .% 

35 

PEL/STEL 

50 ppm/NO 

ff Denotes a chemical subject to the reporting requirements of SARA Title III 

section 313 of 1986 and 40 CFR part 372. 

SARA Title III Hazard Catagories: 1,3 

The components_ of this product are listed on the EPA/TSCA Inventory 

SECTION 3 - PHYSICAL & ~HEMICAL CHARACTERISTICS 

Boiling Point, F: 

Vapor Pressure (mm Hg) : 

Vapor Density {Air=1) : 

pH: 

Solubility in Water: 

Appearance and Odor: 

ND 

ND 

ND 

4-5 

SOLUBLE 

CLEAR YELLOW 

Specific Gravity (H20=1): 

Evaporation Rate: 

{butyl acetate=1) 

Viscosity: 

LIQUID 

SECTION 4 - FIRE & EXPLOSION DATA 

Flash Point, F & Method Flammable Limits: 

165 PMCC Based on: 2-BUTOXYETHANOL 

FIRE HAZARDS: 

0:9876 

ND 

ND 

LEL,% 1.1 

UEL,% 12.5 

Flammable materials may be ignited by heat, sparks or flames. Vapors may 

travel to a source of ignition and flash back. Containers may rupture in 

heat or fire. Vapors are an ignitability hazard indoors, outdoors, or in 

sewers. Runoff to a sewer may create a fire hazard. 

EXTINGUISHING MEDIA: 

Dry chemical, C02, water spray or regular foam. Move container from fire 

area if you can do it without risk. Apply cooling water to sides of 

containers that are exposed to flames until well after the fire is out. 

Stay away from ends of containers. 

Abbreviations: NA=not applicable, ND=not determined, NE=not established 

15 11 
Page 2 of 3 

VPB-37 

--------------------------------------------------------------------------~--

SECTION 5 - PHYSICAL HAZARDS (REACTIVITY DATA) 

-----------------------------------------------------------------------------

Chemical Stability: STABLE 

Conditions To Avoid: OPEN FLAMES 

Incompatibility (materials to avoid) : 

STRONG OXIDIZERS 

Hazardous Decomposition/Byproducts: 

OXIDES OF CARBON 

Hazardous Polymerization: WILL NOT OCCUR 

Hazard Rating Scale: HEALTH: 2 FIRE: 2 REACTIVITY: 0 

(4=severe, 3=serious, 2=moderate, l=slight, O=minimal) 

SECTION 6 - HEALTH HAZARDS 

PRIMARY ROUTES OF ENTRY 

Inhalation: X Absorption: X Ingestion: X Injection: NA 

HBALTII HAZARDS: 

May be hazardous if inhaled, ingested or absorbed through the skin. 

Direct contact with eyes and skin may cause irritation. Ingestion and 

inhalation may cause headaches, nausea, dizziness and other symptoms 

of central nervous system depression. Repeated and prolonged exposure 

to skin may cause defatting, which may lead to dryness, cracking, 

blistering, or dermatitis. SKIN AND EYE CONTACT SHOULD BE AVOIDED. 

AVOID BREATHING VAPORS. DO NOT INGEST. 

EMERGENCY & FIRST AID PROCEDURES: 

INGESTION Contact physician. Give water to drink and induce vomiting 

if directed by a physician. 

INHALATION: Remove to fresh air. If.not breathing, give artificial 

respiration. If breathing is difficult, oxygen may be given 

by qualified personnel. 

SKIN Remove contaminated clothing and wash skin with soap and 

water. Obtain medical attention if irritation persists. 

EYES Immediately flush eyes with running water and continue 

washing for at least 15 minutes. 

IF CONDITIONS PERSIST, SEEK MEDICAL ATTENTION. 

Carcinogenicity? NO NTP? NO !ARC Monograph? ND OSHA Regulated? NO 
Page 3 of 3 

VPB-37 

-----------------------------------------------------------------------------

SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES 

-----------------------------------------------------------------------------

STEPS TO BB TAKEN IN CASH MATERIAL IS RBLRASBD OR SPILLED: 

Shut off ignition sources. No flares, smoking or flames in hazard area. 

Stop leak if you can do it without risk. Water spray may reduce vapor; but 

it may not prevent ignition in closed areas. Take up spill with sand or 

other noncombustible absorbent material and place in containers for later 

disposal. ALWAYS WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT WHEN ADDRESSING 

SPILL OR LEAK. 

WASTE DISPOSAL MBTHOD: 

Contact an EPA or State Approved Disposal Facility. 

. . -----------------------------------------------------------------------------

SECTION 8 - SPECIAL PROTECTION INFORMATION/CONTROL MEASURES 

Respiratory Protection (Specify Type) : 

USE NIOSH APPROVED RESPIRATOR WHEN PEL IS EXCEEDED 

Venti~ation:. L.oca~ .Exhaust: .Recommended ... GeneraL Exhaust: Recommended 

Special: USE SCBA WHEN ENTERING TANKS 

Protective Gloves: Chemically Resistant I Non-Slip 

Eye Protection: Chemical Safety Goggles I Safety Glasses 

Other Protective Clothing or Equipment: 

Work/Hygenic Practices: 

Coveralls, Splash Aprons, 

Eye Wash, and Safety Shower 

Clean up Spills Promptly, Wash Contaminated Clothing. 

SECTION 9 - SHIPPING DATA 

Hazard Classification: NOT-REGULATED 

Labels Required: NONE 

Proper Shipping Name/Description: 

NOT REGULATED 

DOT RQ in Lbs: NA 

DOT RQ in Gal: NA 

Flash Point, F: 165 

pH: 4-5 

DOT ER Guide No. : NONE 

UN/NA No.: NONE 

Pkg. Group: NONE 

IMDG Pg. No. : NONE 

This information is based on data believed by Champion Technologies, Inc. 

to be accurate, but no warranty, express or implied is made. 

17 I 'I 
~TechnolOgies ~~ 

Committed To Improvement 

~¥leal Services LaboratoiJ' 

Report No. AS2003082 

3130 FM 521 Fresno, Texas n545, USA Phone: 281-431-2561 Fax: 281-431-1655 emaU: NeRie.Chu@champ-tech.com 

To: V. Panchalingam 

From: Nellie Chu 

Date: February 27, 2003 

Cc: Virgil Seale 

Adelina Son 

Mike Rudel 

Steve Davis 

Rajan George 

Analytical File 

Determination ofLogPow by High Performance Liquid Chromatography 

Executive Summary 

Three samples were submitted by Paraffin laboratory for analysis. The purpose of this 

project is to determine LogPow value so Champion can file pre-manufacture notification. 

The samples were analyzed by Liquid Chromatography. The LogPow was found to be 

around 0 to 0.39. The data are summarized in Table I. 

Sample Identification 

I. Code 2666 

2. Commercial Betaine, N-Cocoacyl type 

3. Commercial Betaine, N-Oleylacyl type 

Analysis and Results 

Determination of LogPow by Liquid Chromatography: A HP-II 00 series Liquid 

Chromatograph with RI detector was utilized to analyze LogPow of the sample. The 

HPLC method is based on OECD Guideline II7:"Determination of the n-octanoVwater 

partition coefficient by HPLC." A HPLC determination ofLogPow was based on the 

correlation established between Log K and Log Pow· Two standards, each with four 

different chemicals, were used to do the calibration. Samples were dissolved in 60:40 

(v/v) Phosphate Buffer: Methanol and analyzed using CI8 reverse phase column (25 em 

x0.4mm1D). 

Table 1: Lo~Pow Analysis 

Sample LogPow 

Code2666 0.39 

Commercial Betaine N-Cocoacyl type 0 

Commercial Betaine N-Oleylacyl type 0 

Confidential Page 1 of4 (2..\) 2003082 

:lrl 
~Chanpi9n ~TechnolOgies 

Committed To lmpfovement 

~\ytical Services Laboraby 

Report No. AS2003082 

3130 FM 521 Fresno. Texas 77545, USA Phone: 281-431-2561 Fax: 281-431-1655 eman: Nellie.Chu@champ-tech.com 

Summary and Conclusion 

The expected LogPow value for the samples is less than 3, which was confllllled by 

HPLC analysis. The correlation graph between LogK and LogPow is shown in Figure 1 

and the chromatograms of the samples are shown in Figure 2 thru Figure 4. The detailed 

calculations are included for your references. All the chromatograms are also attached to 

the hardcopy of this report in Analytical Report Folder. 

Figure 1: LogPow vs. Log K 

•.• 

.. 

'.• 

.. 

--~ 

-~ 

J ..... ..... ~ .. nc 

nn 

Figure 2: Code 2666 

"'""" 

""""" 

...... 

Confidential 

loa P_ VS log k 

-

~ 

Ia.. ~ 

..... ~ 

.. ,. 

__. 

y = 2.4923x + 1.4075 

R2 = 0.9795 

__. ~ 

__. ~ 

~ 

Page 2 of4 (22; 

j.J 

2003082 
~TechnolOgies ~~ 

CommHted To tmproyement 

~¥ical Services Laboraro, 

Report No. AS2003082 

3130 FM 521 Fresno. Texas 77545, USA Phone: 281-431-2561 Fax: 281-431-1655 email: Nellie.Chu@cllam~tecll.com 

Figure 3: Commercial Betaine, N-Cocoacyl type 

RD1 A, Rtlr8dtW Index~ (20031CJ8VrfC033120.0) 

,....,. 

Commercial 8etaln!. N=Coco!cyltype 

,....., 

-

.. 

Figure 4: Commercial Betaine, N-Oieylacyl type 

Rl[)1 A. RefractiVe Index S~gnat (2003108\NC033123 D) 

nRU 

150000 

Commercial Betaine. JH)!ey!acy! type 

125000 

100000 

75000 

50000 

25000 

Confidential Page 3 of4 2003082 
~Cha . ~Tech~ ~ytica\ Services Labora~ CommJited To lmpfovemenf Report No. AS2003082 

3130 FM 521 Fresno, Texas n545, USA Phone: 281-431-2561 Fax: 281-431-1655 

Detailed Calculation 

Standards 

Aniline 

Benzyl Alcohol 

Acetophenone 

Benzene 

Toluene 

Chlorobenzene 

Benzophenone 

Naphthalene 

LogPow 

0.90 

1.10 

1.70 

2.10 

2.70 

2.80 

3.20 

3.60 

LogK 

-0.183 

-0.179 

0.1137 

0.3393 

0.5872 

0.5937 

0.6352 

0.8383 

Dead volumeffhio Urea 2.26 

Code 2666 (ti),214 om LogPow 

Peak #1 0.00 

Peak #2 0.00 

Peak#3 1.18 

Weighted Average 0.39 

N~Cocoag:l @214nm LogPow 

Peak#2 0.00 

Peak #3 0.00 

Weighted Average 0.00 

N~Oleilag:l @214nm LogPow 

Peak#2 0.00 

Peak#3 0.00 

Weighted Average 0.00 

Logk 

-1.33 

-0.68 

-0.09 

Logk 

-1.25 

-0.68 

Logk 

-1.22 

-0.68 

Rt 

3.741 

3.754 

5.197 

7.197 

10.996 

11.129 

12.018 

17.834 

Rt 

2.366 

2.731 

4.092 

Rt 

2.386 

2.731 

Rt 

2.396 

2.730 

Confidential Page4of4 (2 4) 

email: Nellie.Chu@champ-tech.com 

Area% @214nm 

7.59 

79.28 

12.13 

Areao/o @214nm 

12.2053 

82.6144 

Area% @214nm 

14.6032 

76.2365 

2003082 
\.., 

} c'''o 

\ ,, ' 

Comparison of Data for Code 2666 with similar Compounds 

Anaeroorc 

LC50 crustacean; Biodegradability; Biodegradability; 1 

LC50 ftsh; time IC50 algae; time time OECD301 ISO 11734 I Product CAS number 

c12-14 alkyldimethyl -, 

betaine (Iaury! betaine) 66455-29-6 21.9; 96-hr[3] 2.5; 72-hr[3] 

Cocoamidopropyl betaine 61789-40-0 2; 96-hr{4] 1.84; 96-hr [4] 

Code 2666 19857 4-04-8 n/d 6.28; 72-hr 

Cocoamidopropyl betaine is not listed as carcinogenic by IARC, NTP, OSHA, ACGIH 

Cocoamidopropyl betaine is not considered to be mutagenic. 

n/d >60% [1] 

6.5; 48-hr [4] 90-94% [1] 

20.9; 96-hr n/d 

According to the US EPA, the estimated toxicity of cocoamidopropyl betaine is> 10 mg/L for fish, Dsphnei sp., and algae.[5] 

The concern concentration for the cocoamidopropyl betaine is 0.2 mg/L with a hazard rank of moderate.[5] 

n/d = not determined 

75% [2] 75% [2] 

n/d 

1. Dormsch, A., Karsa, D. R. and M.R. Porter (ed.), Biodegradability of Surfactants, Blackie Academic and Professional, Glasgow, 1995; pp 231-254 

2. Madsen, T. et.e/., Environmental and Health Assessment of Substance in Household Detergents and Cosmetic Detergent Products. Rapport til Milj0styre

3. Data published by Danish EPA; see www.fi.dk.hjemmet/rengoeringllndholdsstoffer/alkyldimethyllalkyldimethylbetainc1214/ 

4. Data from European Chemicals Bureau, IUCLID-CD Version 1.0, Environment Institute, lspra 

5. "Cleaner Technologies Substitutes Assessment: Professional Fabricare Processes"'; US EPA, Office of Pollution Prevention and Taxies, EPA 744-B-98-0

Based on this data, CTI makes the following claims: " 

Claim 1: Based on similarity in structure to other betaines, the OECD 301 biodegradability of C-2666 is expected to be 60-90%. Claim 2: Based on the similarity in structure to other betaines, the ISO 11734 biodegradability of C-2666 is expected to be 70-80%. Claim 3: The 96-hr LC50 for fish will be 2-30 mg/L Claim 4: Based on the SAR Assessment of the US EPA, C-2666 will have a risk and concern concentration similar to that of cocoamidopropyl betaine. Claim 5: Based on the similarity in structure and toxicity to cocoamidopropyl betaine, C-2666 should not be carcinogenic or mutagenic.