DRAFT

INITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285 ENGINEER: Prothero/JFC PV (kg/yr): 11,000 SUBMITTER: Eastman Kodak Company

USE:

OTHER USES:

MSDS: Yes Label: No General Eqp.: Safety glasses with side shields or goggles; impervious gloves and protective clothing. Respirator: NIOSH-approved with an APF of greater than or equal to 10. Health Effects: Harmful if inhaled, absorbed through skin, or swallowed; may be irritating to eyes; may cause nervous system damage based on animal data; the toxicological properties of this material have not been fully investigated. TLV/PEL (PMN or raw materials): Not given

CRSS: Chemical Category: 1H-Benz[e]indolium, 1,1,2,3-tetramethyl, salt with 4-methylbenzenesulfonic acid (1:1)

VP: <1E-06 torr @25 E C

S-H 2 O: <1 g/L
MW: 395.5 Phys State: NEAT: Solid (purple); MFG: Solid; PROC/FORM: NA; END USE: Destroyed.

Consumer Use: No

SAT (concerns): Migration to Groundwater = Anion rapid; Cation negl-slow
PBT Potential = P2B1T2 Health: 2: Moderate concern (Inhalation only)
Eco: 2: All releases to water

OCCUPATIONAL EXPOSURE RATING: 1-2INITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285

ASSUMPTIONS:

POLLUTION PREVENTION CONSIDERATIONS:

EXPOSURE-BASED REVIEW: NoINITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285

MFG:

Site/Location: 1 submitter site (Rochester, NY 14652) Days/yr: 58 (submission reports 58 batches/yr @ 24 hours/batch)

Process Description:

ENVIRONMENTAL RELEASES (Eqpt. cleaning, container residue, etc.):

WATER: 0.6 to 1.9 kg/site-day over 58 Days/year
from:

to: Basis:

AIR: Negligible Basis: Solid PMN, VP < 0.01 torr

INCINERATION: <PV NOTE: Submission estimates <1 kg/batch incinerated (<58 kg/yr).

LANDFILL: Not required, per SATINITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285

MFG: continued

OCCUPATIONAL EXPOSURE Tot. # of workers: 15 (submission) Days/yr: 58 (see above)

Inhalation: particulate (Class I respirator): up to 150 mg/day Basis: OSHA PEL for nuisance dust = 15 mg/m3. Breathing rate = 1.25 m3/hr over 8 hours/day. 100% PMN
concentration

Number of workers with inhalation exposure: 12

Inhalation Monitoring Data Review 1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): YES 2)a) Exposure level > 1 mg/day? YES b) Hazard rating for health of 2 or greater? YES

Inhalation Monitoring data desired? YES

Dermal: contact with solids: up to 3,100 mg/day
100% concentration Basis:INITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285

USE: Site-limited intermediate

Site/Location: 1 submitter site (Rochester, NY 16452) Days/yr: 45 (submission)

Process Description:

ENVIRONMENTAL RELEASES (Eqpt. cleaning, container residue, etc.):

WATER: Not expected Basis:

AIR: Negligible Basis: Solid PMN, VP < 0.01 torr

INCINERATION: <PV
NOTE:

LANDFILL: Not required, per SATINITIAL REVIEW ENGINEERING REPORT

PMN: 03-0285

USE: continued

OCCUPATIONAL EXPOSURE Tot. # of workers: 6 (submission) Days/yr: 45 (submission)

Inhalation: particulate (Class I respirator): up to 150 mg/day Basis: OSHA PEL for nuisance dust = 15 mg/m3. Breathing rate = 1.25 m3/hr over 8 hours/day. 100% PMN
concentration

Number of workers with inhalation exposure: 6

Inhalation Monitoring Data Review 1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): YES 2)a) Exposure level > 1 mg/day? YES c) Hazard rating for health of 2 or greater? YES

Inhalation Monitoring data desired? YES

Dermal: contact with solids: up to 3,100 mg/day
100% concentration Basis: