Inorganic Chemicals Manufacturing Data Supporting the 2013 Annual Review Report

Data Compiled: November 2013 - March 2014

Tab Name

Summary Rankings

Top TRI Pollutants

Top TRI Pollutant Data

Inorg - 44004SCMCH2900M

Inorg - 44004SCMCH2426M

Inorg - 37134DPNTJ1PUPO
ls Manufacturing Data Supporting the 2013 Annual Review Report

ovember 2013 - March 2014

Tab Description

2013 Final Rankings for the DMR and TRI databases. Also shows what percent DMR and TRI make up for the 

category being reviewed.

Top pollutants in the 2011 TRI Database for the Inorganic Chemicals Manufacturing Category. Includes facility 

count, pounds, and TWPE for each pollutant. Highlights the pollutants that were reviewed as part of the 2013 

Annual Review. No facility corrections were identified for the Inorganic Chemicals Manufacturing Category 

during the 2013 Annual Review. 

Top facilities for each top pollutant in the 2011 TRI Database for the Inorganic Chemicals Manufacturing 

Category reviewed as part of the 2013 Annual Review. Includes facility pounds and TWPE. 

Facility-specific data on dioxin and dioxin-compound discharges and notes on Millennium Inorganic Chemicals in 

Ashtabula, OH. 

Facility-specific data on manganese and manganese-compound discharges and notes on Millennium Inorganic 

Chemicals in Ashtabula, OH.

Facility-specific data and notes on Dupont Johnsonville Plant in New Johnsonville, TN. 
2013 - Final Combined Rankings Excluding Categories Recently Reviewed

2/14/2014

Revised to incorporate PSC code changes for facilities missed as part of the change to the DMR Loading Tool

Source: DMR Loadings Tool (Everyday Searches/Top Industrial Dischargers of Toxic Rankings) - Includes Data Corrections fro

PSC Point Source Category

Total 

Count of 

Facilities

Direct 

Only

Indirect 

Only

414 Organic chemicals, plastics and synthetic fibers 631 194 380

430 Pulp, paper and paperboard 221 145 63

419 Petroleum refining 267 192 52

501 Drinking Water Treatment 2 0 0

440 Ore mining and dressing 33 29 3

420 Iron and steel manufacturing 222 118 50

418 Fertilizer manufacturing 41 32 4

415 Inorganic chemicals manufacturing 153 56 71

421 Nonferrous metals manufacturing 119 52 49

455 Pesticide chemicals 56 30 24

409 Sugar processing 14 12 2

433 Metal Finishing 1785 263 1256

451 Concentrated Aquatic Animal Production 0 0 0

434 Coal mining 17 17 0

432 Meat and Poultry Products 156 82 61

429 Timber products processing 102 67 21

435 Oil & Gas Extraction 0 0 0

463 Plastics molding and forming 114 24 71

503 Miscellaneous Foods and Beverages 131 19 109

445 Landfills 1 1 0

417 Soap and detergent manufacturing 70 4 62

424 Ferroalloy manufacturing 5 5 0

436 Mineral Mining and Processing 83 49 32

458 Carbon black manufacturing 4 4 0

464 Metal molding and casting (foundries) 199 89 72

410 Textile mills 44 4 33

471 Nonferrous metals forming and metal powders 119 28 56

428 Rubber Manufacturing 157 26 85

438 Metal Products and Machinery 74 18 45

422 Phosphate manufacturing 10 9 1

406 Grain mills 23 7 10

457 Explosives manufacturing 9 5 2

469 Electrical and electronic components 70 5 62

437 Centralized Waste Treatment 2 1 1

460 Hospital 0 0 0

468 Copper forming 109 24 41

467 Aluminum forming 114 18 60

439 Pharmaceutical manufacturing 84 9 71

411 Cement manufacturing 53 43 8

407 Canned and preserved fruits and vegetables processing 26 8 18

405 Dairy products processing 291 36 247

413 Electroplating 306 15 264

466 Porcelain Enameling 4 0 3

444 Waste combustors 2 1 0

TRI Facility Counts
508 Printing & Publishing 57

2 54

425 Leather tanning and finishing 131 11

426 Glass manufacturing 539 35

442 Transportation Equipment Cleaning110

443 Paving and roofing materials (tars and asphalt) 29 166

461 Battery manufacturing 543 35

507 Independent and Stand Alone Labs

101

408 Canned and preserved seafood processing660

427 Asbestos manufacturing

000

454 Gum and wood chemicals manufacturing 1081

465 Coil coating 371 36

446 Paint formulating 53 10 41

505 Food Service Establishments

000

506 Industrial Laundries

000

502 Tobacco Products 17

1 15

447 Ink formulating 1019

509 Photo Processing

000

459 Photographic

000
o the DMR Loading Tool

gs) - Includes Data Corrections from Preliminary Rankings Review (12/2012)

Both 

Direct and 

Indirect TRI LBY TRI TWPE

Total 

Count of 

Facilities Majors Minors DMR LBY DMR TWPE

57 25991167.15 147675.2182 470 189 281 2738253625 1540387.114

13 17750608.67 651376.5506 234 194 40 2239681616 1034369.59

23 23589915.03 680608.0883 479 96 383 516230325.2 751580.6938

2 12810 1643 1335 20 1315 4216219611 1384298.003

1 1826546.128 1229923.39 93 53 40 698538772.3 109758.1093

54 33509051.72 82937.27287 146 83 63 1279823916 1170699.952

5 4377973.034 6667.914961 39 19 20 122486680.9 599100.4356

26 8732577.95 326863.4381 217 70 147 1532389542 142060.7974

18 4669549.932 42948.34437 57 28 29 157405728.4 382840.4371

2 2115074.33 373899.7328 33 20 13 29998642.94 19317.89791

0 487306.72 429.8574031 26 19 7 65490570.71 373178.6753

266 4300840.877 51738.65198 626 86 540 216670888.6 264963.1311

0 0 0 266 20 246 105515454.3 291885.136

0 292406.0871 563.9618167 218 13 205 8405721295 188756.1494

13 51722815.47 39117.80918 158 34 124 464043654 119028.2383

14 39325.3567 32332.84936 139 4 135 1136810374 98629.5955

0 0 0 150 14 136 5024628205 106089.5093

19 2926175.403 69161.81513 78 5 73 724327795.5 26693.83158

3 3983961.506 4901.790156 119 7 112 4247927288 57364.7284

0 19942.9 42850.60386 234 5 229 81481172.75 19311.53355

4 94322.31682 2368.142999 18 3 15 2781234.308 47123.66268

0 135757.55 8990.980096 13 2 11 13220221.92 27260.26418

2 2103016.382 2946.423878 992 27 965 3093991064 31156.47101

0 559.579 27865.49368 2 0 2 4375209.577 0.2009075

38 212440.0484 9671.857609 53 8 45 27454867.86 16283.18749

7 592379.4161 1074.029372 67 31 36 33130533.05 22342.79249

35 1340579.676 17883.4982 34 11 23 6011501.362 3438.610671

46 962717.5478 10197.31036 77 15 62 19197556.73 7322.237141

11 316649.16 7951.962317 491 76 415 230974159.8 7672.994297

0 18457.5674 193.4171027 12 8 4 23096767.64 13597.30481

6 2851270.356 10517.45364 34 7 27 55857054.6 2808.320562

2 18485.4034 17.39397107 11 4 7 104873877.7 11829.26076

3 2889479.15 3575.853324 12 5 7 80960904.97 8179.21937

0 265785.1 2353.763007 19 9 10 211936878.3 7864.421151

0 0 0 155 2 153 16801424.87 9419.724086

44 41872.93951 6178.329298 28 8 20 4005009.424 2613.052703

36 175623.3605 1303.472471 27 9 18 4106427.55 6962.480421

4 1046704.288 2347.025621 58 20 38 37208518.52 4519.197551

2 1148.100086 651.7279191 323 6 317 99524423.29 5964.807959

0 5894286.82 4420.079944 51 7 44 856519832.8 1063.841802

8 4992508.337 3766.50093 54 3 51 36114818.66 593.1695576

27 1105818.527 4097.304214 0 0 0 0 0

1 300.216 27.83928 3 0 3 579081.6817 2733.890934

1 45.5586 88.22424233 9 5 4 484441.2705 2652.262618

DMR Facility Counts
1 19936 388 12

2 10 1397612.326 1891.085596

1 218884.82 1898.084539312 52662.71522 8.195757828

9 40981.34463 246.0956356 431 42 10436822.26 1555.930967

0 11.7 0.012987 491 48 20451295.3 1697.742516

7 136.35443 1062.519238 483 45 11673576.8 581.4361552

16 16899.04192 869.8050999202 10969.23373 298.0498167

0 1.482 4.46838 33

5 28 69404043.95 756.2223126

0 99330 74.1664 538 45 68783703.06 686.4242635

00

0202 7018812.068 517.9002151

1 2733.19054 33.58020866 1239 3863729.745 360.0025889

0 19825.1946 74.98402799514 24097.81521 249.914905

2 70441.63756 86.45111028808 50775.60004 3.051504149

00

0 870 87 10346303.53 45.63688716

00

0505 380387.7176 12.62378436

1 88022.7562 12.5288154

101 5.17447E-070

0 1304.0257 3.612719447303 26080.35784 2.222387256

00

0101 21973.57197 0.06279474

00

0101 21973.57197 0.06279474

3918883.447 8932381.498
Total LBY Total TWPE

% of Total 

TWPE

Combined % 

of Total 

TWPE

TRI % of 

Total

DMR % of 

Total

2,764,244,793 1,688,062 0.13 0.13 9% 91%

2,257,432,225 1,685,746 0.13 0.26 39% 61%

539,820,240 1,432,189 0.11 0.37 48% 52%

4,216,232,421 1,385,941 0.11 0.48 0.1% 99.9%

700,365,318 1,339,681 0.10 0.59 92% 8%

1,313,332,968 1,253,637 0.10 0.68 7% 93%

126,864,654 605,768 0.05 0.73 1% 99%

1,541,122,119 468,924 0.04 0.77 70% 30%

162,075,278 425,789 0.03 0.80 10% 90%

32,113,717 393,218 0.03 0.83 95% 5%

65,977,877 373,609 0.03 0.86 0% 100%

220,971,729 316,702 0.02 0.88 16% 84%

105,515,454 291,885 0.02 0.91 0% 100%

8,406,013,701 189,320 0.01 0.92 0% 100%

515,766,469 158,146 0.01 0.93 25% 75%

1,136,849,700 130,962 0.01 0.94 25% 75%

5,024,628,205 106,090 0.01 0.95 0% 100%

727,253,971 95,856 0.01 0.96 72% 28%

4,251,911,250 62,267 0.00 0.97 8% 92%

81,501,116 62,162 0.00 0.97 69% 31%

2,875,557 49,492 0.00 0.97 5% 95%

13,355,979 36,251 0.00 0.98 25% 75%

3,096,094,081 34,103 0.00 0.98 9% 91%

4,375,769 27,866 0.00 0.98 100% 0%

27,667,308 25,955 0.00 0.98 37% 63%

33,722,912 23,417 0.00 0.99 5% 95%

7,352,081 21,322 0.00 0.99 84% 16%

20,160,274 17,520 0.00 0.99 58% 42%

231,290,809 15,625 0.00 0.99 51% 49%

23,115,225 13,791 0.00 0.99 1% 99%

58,708,325 13,326 0.00 0.99 79% 21%

104,892,363 11,847 0.00 0.99 0% 100%

83,850,384 11,755 0.00 0.99 30% 70%

212,202,663 10,218 0.00 0.99 23% 77%

16,801,425 9,420 0.00 1.00 0% 100%

4,046,882 8,791 0.00 1.00 70% 30%

4,282,051 8,266 0.00 1.00 16% 84%

38,255,223 6,866 0.00 1.00 34% 66%

99,525,571 6,617 0.00 1.00 10% 90%

862,414,120 5,484 0.00 1.00 81% 19%

41,107,327 4,360 0.00 1.00 86% 14%

1,105,819 4,097 0.00 1.00 100% 0%

579,382 2,762 0.00 1.00 1% 99%

484,487 2,740 0.00 1.00 3% 97%
1,417,548 2,280 0.00 1.00 17% 83%

271,548 1,906 0.00 1.00 100% 0%

10,477,804 1,802 0.00 1.00 14% 86%

20,451,307 1,698 0.00 1.00 0% 100%

11,673,713 1,644 0.00 1.00 65% 35%

27,868 1,168 0.00 1.00 74% 26%

69,404,045 760.7 0.00 1.00 1% 99%

68,883,033 760.6 0.00 1.00 10% 90%

7,018,812 518 0.00 1.00 0% 100%

3,866,463 394 0.00 1.00 9% 91%

43,923 325 0.00 1.00 23% 77%

121,217 90 0.00 1.00 97% 3%

10,346,304 46 0.00 1.00 0% 100%

380,388 13 0.00 1.00 0% 100%

88,023 13 0.00 1.00 100% 0%

27,3846 0.00 1.00 62% 38%

21,9740 0.00 1.00 0% 100%

21,9740 0.00 1.00 0% 100%

12,851,265
Top Pollutants in Inorganic Manufacturing (40 CFR Part 415) from TRI2011

11/25/2013

Table from TRI Database: TSD 02 - Top Pollutants by PSC

Note: No facility corrections were identified for the Inorganic Chemicals Manufacturing category as part of the 2013 Annual Revi

Pollutants Reviewed as part of the 2013 ARR

PSC Code PSC Description

Fac 

Count

415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 21

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 49

415 Inorganic chemicals manufacturing 13

415 Inorganic chemicals manufacturing 30

415 Inorganic chemicals manufacturing 31

415 Inorganic chemicals manufacturing 38

415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 37

415 Inorganic chemicals manufacturing 53

415 Inorganic chemicals manufacturing 7

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 30

415 Inorganic chemicals manufacturing 16

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 19

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 3

415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 18

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 8

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 3

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 6

415 Inorganic chemicals manufacturing 7

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 2

415 Inorganic chemicals manufacturing 5

415 Inorganic chemicals manufacturing 1

415 Inorganic chemicals manufacturing 5
415 Inorganic chemicals manufacturing

1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing2

415 Inorganic chemicals manufacturing3

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing2

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing2

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1

415 Inorganic chemicals manufacturing1
rt 415) from TRI2011

c Chemicals Manufacturing category as part of the 2013 Annual Review.

CHEMICAL_NAME LBY TWPE

% of Total 

TWPE

DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.008259 279154 85.4%

MANGANESE AND MANGANESE COMPOUNDS 201071.1 14074.98 4.3%

POLYCHLORINATED BIPHENYLS 0.20607 7013.304 2%

NITRATE COMPOUNDS 6792119 5071.449 2%

MERCURY AND MERCURY COMPOUNDS 36.2521 4245.483 1%

CHROMIUM AND CHROMIUM COMPOUNDS 53254.93 3727.845 1%

COPPER AND COPPER COMPOUNDS 4535.092 2857.108 1%

ZINC AND ZINC COMPOUNDS 55323.6 2212.944 1%

ARSENIC AND ARSENIC COMPOUNDS 398.5 1609.94 0%

LEAD AND LEAD COMPOUNDS 711.4445 1593.636 0%

AMMONIA 960606.6 1066.273 0%

VANADIUM AND VANADIUM COMPOUNDS 35275.36 1058.261 0%

CADMIUM AND CADMIUM COMPOUNDS 34.2 790.362 0%

BERYLLIUM AND BERYLLIUM COMPOUNDS 743 780.15 0%

NICKEL AND NICKEL COMPOUNDS 4257.127 425.7127 0%

COBALT AND COBALT COMPOUNDS 2173.759 239.1135 0%

HEXACHLOROBENZENE 0.110781 215.7696 0%

CARBON DISULFIDE 55 154 0%

BARIUM AND BARIUM COMPOUNDS 66300.28 131.9878 0%

ACRYLONITRILE 54.75 124.2825 0%

SILVER AND SILVER COMPOUNDS 5.46 89.9262 0%

SODIUM NITRITE 20941.24 67.01197 0%

THALLIUM AND THALLIUM COMPOUNDS 35 35.7 0%

DIBUTYL PHTHALATE 2464 24.64 0%

SELENIUM AND SELENIUM COMPOUNDS 14.7 16.464 0%

POLYCYCLIC AROMATIC COMPOUNDS 0.152 15.30032 0%

1,4-DIOXANE 20400 12.64479 0%

CYANIDE COMPOUNDS 1533.6 8.28144 0%

MOLYBDENUM TRIOXIDE 10232.23 8.185784 0%

HEXACHLOROETHANE 30.82 5.5476 0%

METHANOL 378444.4 5.517656 0%

NAPHTHALENE 453.3 4.533 0%

ANTIMONY AND ANTIMONY COMPOUNDS 426.844 4.26844 0%

ACETONITRILE 14042.54 2.991602 0%

1,1,1-TRICHLOROETHANE 610 2.866812 0%

CERTAIN GLYCOL ETHERS 21325.76 2.274845 0%

ANILINE 328.65 2.254121 0%

ETHYLENE GLYCOL 1649.288 2.210596 0%

NITRIC ACID 1514.2 1.130603 0%

DIETHANOLAMINE 603 1.05525 0%

PENTACHLOROBENZENE 0.2 0.752 0%

TOLUENE 102 0.574038 0%

FORMALDEHYDE 221.88 0.517125 0%

1,2,4-TRIMETHYLBENZENE 22.8 0.456 0%

HYDROGEN FLUORIDE 70783.93 0.39639 0%
1,2-DICHLOROETHANE 23 0.23 0%

TRICHLOROETHYLENE 22 0.22 0%

PHENOL 10.5 0.21 0%

FORMIC ACID 507.12 0.187893 0%

DICHLOROMETHANE 181 0.183331 0%

PHOSPHINE3 0.09 0%

TERT-BUTYL ALCOHOL 1910.15 0.060434 0%

BENZENE2 0.06 0%

EPICHLOROHYDRIN 5.4 0.03751 0%

XYLENE (MIXED ISOMERS) 3.2 0.013839

N-BUTYL ALCOHOL 108.8 0.011134

CHLOROMETHANE2 0.010718

CHLOROETHANE2 0.006378

N-HEXANE 0.15 0.0045

CUMENE 0.8 0.002703

2-METHOXYETHANOL4 0.001131

PROPYLENE 0.1 7.03E-05

2-ETHOXYETHANOL1 8.27E-06

326863.4
40 CFR Part 415 - Inorganic Chemicals

From TRI Database: TSD 04 - Facility Discharges

Facilities Reviewed as part of the 2013 ARR

Dioxin and Dioxin-like Compounds

PSC Code TRI ID Facility Name City

415 44004SCMCH2900M

MILLENNIUM INORGANIC CHEMICALS A 

CRISTAL CO ASHTABULA

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT

NEW

JOHNSONVILLE

415 70669KRNSL3300B LOUISIANA PIGMENT CO LP WESTLAKE

415 44004SCMCH2426M

MILLENNIUM INORGANIC CHEMICALS A 

CRISTAL CO ASHTABULA

415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR

415 39571DPNTD7685K DUPONT DELISLE PLANT PASS CHRISTIAN

Manganese and Manganese Compounds

PSC Code TRI ID Facility Name City

415 44004SCMCH2426M

MILLENNIUM INORGANIC CHEMICALS A 

CRISTAL CO ASHTABULA

415 70734RCDNCHIGHW PCS NITROGEN FERTILIZER LP GEISMAR

415 70669KRNSL3300B LOUISIANA PIGMENT CO LP WESTLAKE

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT

NEW

JOHNSONVILLE

415 44004SCMCH2900M

MILLENNIUM INORGANIC CHEMICALS A 

CRISTAL CO ASHTABULA

415 37134CHMTLFOOTE ERACHEM COMILOG

NEW

JOHNSONVILLE

415 21226SCMCH3901G

MILLENNIUM INORGANIC CHEMICALS INC 

HAWKINS POINT PLANT BALTIMORE

415 21226CHMTL711PI

ERACHEM COMILOG INC - BALTIM ORE 

PLANT BALTIMORE

415 08865JTBKR600NO MALLINCKRODT BAKER INC PHILLIPSBURG

415 45246THSHP4539D THE SHEPHERD COLOR CO CINCINNATI

415 39571DPNTD7685K DUPONT DELISLE PLANT PASS CHRISTIAN

415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR

415 62301PRNCMONEPR PRINCE MINERALS INC QUINCY

415 18071HRSHDDELAW HORSEHEAD CORP PALMERTON

415 40210NTDCT1227S SUD-CHEMIE INC 12TH STREET F ACILITY LOUISVILLE

415 15301DRKNFWESTW FERRO CORP WASHINGTON

415 44035NGLHR120PI BASF CORP ELYRIA

415 20705MNRLP7011M

ROCKWOOD PIGMENTS NORTH AMERICA 

INC BELTSVILLE

415 38401CCDNTBOX59 OCCIDENTAL CHEMICAL CORP COLUMBIA

415 83276MNSNTHIGHW P4 PRODUCTION LLC SODA SPRINGS

415 44667FRRCR1560N FERRO CORP ORRVILLE

PCB Discharges
PSC Code TRI ID Facility Name City

415 37134DPNTJ1DUPO DUPONT JOHNSONVILLE PLANT

NEW

JOHNSONVILLE

415 19809DPNTD104HA DUPONT EDGE MOOR EDGEMOOR
State Chem ID Chemical LBY TWPE

OH N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.002453 273040.2

TN N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.002313 3102.609

LA N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.000136 1627.675

OH N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.000115 799.6382

DE N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 0.003146 492.9589

MS N150 DIOXIN AND DIOXIN-LIKE COMPOUNDS 9.57E-05 90.95447

279154

State Chem ID Chemical LBY TWPE

OH N450 MANGANESE AND MANGANESE COMPOUNDS 79000 5530

LA N450 MANGANESE AND MANGANESE COMPOUNDS 39934 2795.38

LA N450 MANGANESE AND MANGANESE COMPOUNDS 26270 1838.9

TN N450 MANGANESE AND MANGANESE COMPOUNDS 21685 1517.95

OH N450 MANGANESE AND MANGANESE COMPOUNDS 11300 791

TN N450 MANGANESE AND MANGANESE COMPOUNDS 5160 361.2

MD N450 MANGANESE AND MANGANESE COMPOUNDS 5103 357.21

MD N450 MANGANESE AND MANGANESE COMPOUNDS 4567.8 319.746

NJ N450 MANGANESE AND MANGANESE COMPOUNDS 3657 255.99

OH N450 MANGANESE AND MANGANESE COMPOUNDS 1594.2 111.594

MS N450 MANGANESE AND MANGANESE COMPOUNDS 976 68.32

DE N450 MANGANESE AND MANGANESE COMPOUNDS 958 67.06

IL N450 MANGANESE AND MANGANESE COMPOUNDS 520 36.4

PA N450 MANGANESE AND MANGANESE COMPOUNDS 244.8 17.136

KY N450 MANGANESE AND MANGANESE COMPOUNDS 57 3.99

PA N450 MANGANESE AND MANGANESE COMPOUNDS 23.12 1.6184

OH N450 MANGANESE AND MANGANESE COMPOUNDS 8 0.56

MD N450 MANGANESE AND MANGANESE COMPOUNDS 5 0.35

TN N450 MANGANESE AND MANGANESE COMPOUNDS 4.41 0.3087

ID N450 MANGANESE AND MANGANESE COMPOUNDS 2.2 0.154

OH N450 MANGANESE AND MANGANESE COMPOUNDS 1.6 0.112

14074.98
State Chem ID Chemical LBY TWPE

TN 1336363 POLYCHLORINATED BIPHENYLS 0.2 6806.72

DE 1336363 POLYCHLORINATED BIPHENYLS 0.00607 206.584

7013.304
% of Total 

TWPE

98%

1%

1%

0%

0%

0%

% of Total 

TWPE

39.3%

20%

13%

11%

6%

3%

3%

2%

2%

1%

0%

0%

0%

0%

0%

0%

0%

0%

0%

0%
% of Total 

TWPE

97%

3%
415 - Inorganic Chemicals

Millennium Inorganic Chemicals A Cristal Co

Ashtabula, OH

44004SCMCH2900M

(NPDES ID: OH0000523)

NOTES: 

Indicates value contains loads that are calculated using data that has been flagged a

Indicates there was one or more discharge in excess of permit effluent limits for this 

RECOMMENDATION:

All 2011 dioxin and dioxin-like compound discharges are below EPA's Method 1613B ML. 

No corrections to 2011 facility data.

TRI Data from DMR Loading Tool

Pollutants Identified for Further Review Based on High TWPE.

Direct TRI

(lbs‐eq/yr)

Dioxin and dioxin-like compounds 273,040

Manganese and manganese compounds 791

Carbon disulfide

Carbonyl sulfide

Hydrochloric acid (1995 and after "acid 

aerosols" only)

Sulfuric acid (1994 and after "acid 

aerosols" only)

Titanium tetrachloride

Toluene

Dioxin Discharges

From TRI data in the DMR Loading Tool:

Reporting Year Grams

2007 0

2008 0

2009 0.034926654

2010 0.16

2011 1.09

2012 0.14

Dioxin Distribution from tri_data_20120823.xlsx

Congener Number CAS#

1 001746016

2 040321764

3 039227286

Contacted facility, contact stated that the formation of dioxin compounds occurs within an extremely narrow temperature range 

the final effluent. In 2011, the non-detect data were inadvertently reported using the minimum detection limit. For other years, th

EPA used the 2011 flow provided by the facility contact and the facility's TRI reported 2011 congener distribution to calculate its 

Chemical Name

Top Chemicals by Toxic-Weighted Pounds (TWPE)

(TRI, 2011)
4 057653857

5 019408743

6 035822469

7 003268879

8 051207319

9 057117416

10 057117314

11 070648269

12 057117449

13 072918219

14 060851345

15 067562394

16 055673897

17 039001020

Discharge comparison to 1613 Minimum Level

Congener Number CASNU

1 1746016

2 40321764

3 39227286

4 57653857

5 19408743

6 35822469

7 3268879

8 51207319

9 57117416

10 57117314

11 70648269

12 57117449

13 72918219

14 60851345

15 67562394

16 55673897

17 39001020

Flow from facility: 
ue contains loads that are calculated using data that has been flagged as potential outliers or data errors.

re was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

e below EPA's Method 1613B ML. 

Indirect TRI

(lbs‐eq/yr)

0

0

0

0

0

0

Pounds TWPE

0 0

0 0

0.000077 0.76

0.00035 2,396

0.0024 273,040

0.00032

Congener Name Unit

2,3,7,8-Tetrachlorodibenzo- p-dioxin Grams

1,2,3,7,8-Pentachlorodibenzo- p-dioxin Grams

1,2,3,4,7,8-Hexachlorodibenzo- p-dioxin Grams

oxin compounds occurs within an extremely narrow temperature range immediately following the chlorination process. The dioxin discharges 

vertently reported using the minimum detection limit. For other years, the facility reported non-detect data as zero. This is the cause of the in

and the facility's TRI reported 2011 congener distribution to calculate its dioxin and dioxin-like compound discharge concentrations (see belo
1,2,3,6,7,8-Hexachlorodibenzo- p-dioxin Grams

1,2,3,7,8,9-Hexachlorodibenzo- p-dioxin Grams

1,2,3,4,6,7,8-Heptachlorodibenzo- p-dioxin Grams

1,2,3,4,6,7,8,9-Octachlorodibenzo- p-dioxin Grams

2,3,7,8-Tetrachlorodibenzofuran 2,3,7,8-TCDF Grams

1,2,3,7,8-Pentachlorodibenzofuran 1,2,3,7,8-PeCDF Grams

2,3,4,7,8-Pentachlorodibenzofuran 2,3,4,7,8-PeCDF Grams

1,2,3,4,7,8-Hexachlorodibenzofuran 1,2,3,4,7,8-HxCDF Grams

1,2,3,6,7,8-Hexachlorodibenzofuran 1,2,3,6,7,8-HxCDF Grams

1,2,3,7,8,9-Hexachlorodibenzofuran 1,2,3,7,8,9-HxCDF Grams

2,3,4,6,7,8-Hexachlorodibenzofuran 2,3,4,6,7,8-HxCDF Grams

1,2,3,4,6,7,8-Heptachlorodibenzofuran 1,2,3,4,6,7,8-HpCDF Grams

1,2,3,4,7,8,9-Heptachlorodibenzofuran 1,2,3,4,7,8,9-HpCDF Grams

1,2,3,4,6,7,8,9-Octachlorodibenzofuran 1,2,3,4,6,7,8,9-OCDF Grams

Grams

Pounds

TWF

Congener Name

Congener 

Number

Tetrachlorodibenzo-p-dioxin, 2,3,7,8- 1

Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- 2

Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- 3

Hexachlorodibenzo-p-dioxin, 1,2,3,6,7,8- 4

Hexachlorodibenzo-p-dioxin, 1,2,3,7,8,9- 5

Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- 6

Octachlorodibenzo-p-dioxin 7

Tetrachlorodibenzofuran, 2,3,7,8- 8

Pentachlorodibenzofuran, 1,2,3,7,8- 9

Pentachlorodibenzofuran, 2,3,4,7,8- 10

Hexachlorodibenzofuran, 1,2,3,4,7,8- 11

Hexachlorodibenzofuran, 1,2,3,6,7,8- 12

Hexachlorodibenzofuran, 1,2,3,7,8,9- 13

Hexachlorodibenzofuran, 2,3,4,6,7,8- 14

Heptachlorodibenzofuran, 1,2,3,4,6,7,8- 15

Heptachlorodibenzofuran, 1,2,3,4,7,8,9- 16

Octachlorodibenzofuran 17

867.5 MGY

812.7 MGY
ntial outliers or data errors.

ant sometime during the year.

Direct TRI Indirect TRI

(lbs/yr) (lbs/yr)

Manganese and manganese compounds 11,300 0

Dioxin and dioxin-like compounds 0.0024 0

Carbon disulfide 0

Carbonyl sulfide 0

Hydrochloric acid (1995 and after "acid 

aerosols" only)

0

Sulfuric acid (1994 and after "acid 

aerosols" only)

0

Titanium tetrachloride 0

Toluene 0

TWF

 9,870

 6,845,714

 113,766,667

Data from facility contact (Schmude, 2014)

Loads

Facility Confirmed 

Distribution

0.01617 0.016

0.07804 0.078

0.07892 0.078

diately following the chlorination process. The dioxin discharges are based on quarterly sampling at 

ity reported non-detect data as zero. This is the cause of the increase in dioxin discharges in 2011. 

n and dioxin-like compound discharge concentrations (see below). 

Chemical Name

Top Chemicals by Pounds

(TRI, 2011)
0.07907 0.079

0.08016 0.08

0.0804 0.0804

0.02145 0.021

0.01561 0.015

0.07804 0.078

0.07889 0.078

0.0794 0.079

0.08012 0.08

0.07895 0.078

0.07978 0.079

0.08583 0.085

0.07973 0.079

0.02228 0.022

1.11284 1.1054

0.0024534

 111,290,938.49 (TWPE divided by lbs - 273,040/0.0024534)

Current TWF % discharged lbs discharged

grams 

discharged

703584000 1.453039071 3.56487E-05 0.01617

692928000 7.012688257 0.000172049 0.07804

23498240 7.091765213 0.000173989 0.07892

9556480 7.10524424 0.000174319 0.07907

10595840 7.203191834 0.000176722 0.08016

411136 7.224758276 0.000177251 0.0804

6585.6 1.927500809 4.72891E-05 0.02145

43819553.68 1.402717372 3.44141E-05 0.01561

7632640 7.012688257 0.000172049 0.07804

557312000 7.089069408 0.000173922 0.07889

5760000 7.134898099 0.000175047 0.0794

14109440 7.199597426 0.000176634 0.08012

47308800 7.094461019 0.000174055 0.07895

51204160 7.169044966 0.000175885 0.07978

85760 7.71269904 0.000189223 0.08583

3033984 7.164551957 0.000175774 0.07973

2020.96 2.002084756 4.91189E-05 0.02228

Total 100

Total lbs released 0.0024534

for 2011

for 2012

pg pg/L

1613 ML 

(pg/L)

16170000000 4.9 10

78040000000 23.8 50

78920000000 24.0 50

79070000000 24.1 50

80160000000 24.4 50

80400000000 24.5 50

21450000000 6.5 100

15610000000 4.8 10

78040000000 23.8 50

78890000000 24.0 50

79400000000 24.2 50

80120000000 24.4 50

78950000000 24.0 50

79780000000 24.3 50

85830000000 26.1 50

79730000000 24.3 50

22280000000 6.8 100
415 - Inorganic Chemicals

Millennium Inorganic Chemicals A Cristal Co

Ashtabula, OH

44004SCMCH2426M

(NPDES ID: OH0000493)

Recommendation:

Facility confirmed manganese discharges (79,000 lbs). 

The facility is one of the few remaining US facilities that manufacture titanium dioxide - discharges do not represent discharges 

Facility contact provided 2012 discharge quantities for comparison.

TRI Data from DMR Loading Tool

Pollutants Identified for Further Review Based on High TWPE.

Top Chemical

Direct TRI TWPE 

(lbs-eq/yr)

Indirect 

TRI TWPE 

(lbseq/yr)

Manganese and manganese compounds 5,530.00 0

Chemical Name

Direct TRI (lbseq/year)

Indirect 

TRI (lbseq/year)

Manganese and manganese compounds 5,530 0

Dioxin and dioxin-like compounds 800 0

Dioxin Discharges

From TRI data in the DMR Loading Tool:

Reporting Year Grams Pounds TWPE TWF

2007 16329344.74 36,000 2,520 0.07

2008 24947610.02 55,000 3,850 0.07

2009 10432636.92 23,000 1,610 0.07

2010 17236530.56 38,000 2,660 0.07

2011 35,833,839.85 79,000 5,530 0.07

2012 24250437.72 53,463 3,742 0.07

The facility calculated manganese discharges based off of direct sampling at the NPDES compliance point (final effluent). The s

samples.

The facility contact stated that the increase in the manganese and manganese compound discharge in 2011 was due to a slight 

as process rate, process conditions, and volume of stormwater. 
es do not represent discharges across the category as a whole.

From facility contact - Schmude, 2014

ance point (final effluent). The samples are taken once per week and they are 24 hour composite 

arge in 2011 was due to a slight increase in flow. The increase in flow resulted from many factors such 
415 - Inorganic Chemicals

Dupont Johnsonville Plant

New Johnsonville, TN

37134DPNTJ1DUPO

(NPDES ID: TN0001465)

NOTES: 

Indicates value contains loads that are calculated using data that has been flagged as potential outliers or data errors.

Indicates there was one or more discharge in excess of permit effluent limits for this pollutant sometime during the year.

RECOMMENDATION:

Discharges have doubled from 2010 to 2011.

TRI Data from DMR Loading Tool

Direct TRI Indirect TRI

(lbs‐eq/yr) (lbs‐eq/yr)

Polychlorinated biphenyls 6,807 0 Manganese and manganese compounds

Dioxin and dioxin-like compounds 3,103 0 Barium and barium compounds

Manganese and manganese compounds 1,518 0 Cobalt and cobalt compounds

Arsenic and arsenic compounds 1,277 0 Zinc and zinc compounds

Lead and lead compounds 354 0 Arsenic and arsenic compounds

Cobalt and cobalt compounds 57.86 0 Chromium and chromium compounds

Zinc and zinc compounds 21.04 0 Lead and lead compounds

Chromium and chromium compounds 16.94 0 Polychlorinated biphenyls

Barium and barium compounds 10.2 0 Pentachlorobenzene

Pentachlorobenzene 0.37 0 Dioxin and dioxin-like compounds

PCB Discharges

From TRI data in the DMR Loading Tool:

Reporting Year Grams Pounds TWPE TWF

2007 45.35929094 0.1 3,403 34,030.000

2008 45.35929094 0.1 3,403 34,030.000

2009 0 0 0

2010 45.36 0.1 3,403 34,030.000

2011 90.72 0.2 6,807 34,035.000

Facility was contacted as part of the screening-level outlier reviews and the contact confirmed the PCB discharges. Contact stated that the PCB discharges are a result 

resulting from the chlorination process. 

Chemical Name Chemical Name

Top Chemicals by Toxic-Weighted Pounds (TWPE) Top Chemicals by Pounds

(TRI, 2011) (TRI, 2011)

Pollutants Identified for Further Review Based on High TWPE.
s potential outliers or data errors.

pollutant sometime during the year.

Direct TRI Indirect TRI

(lbs/yr) (lbs/yr)

21,685 0

5,158 0

526 0

526 0

316 0

242 0

158 0

0.2 0

0.1 0

0.0023 0

hat the PCB discharges are a result of small amounts of fine solids in the wastewater discharge